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Sample records for arc furnace steelmaking

  1. A review of the use of anthracite in electric arc furnace steelmaking

    SciTech Connect

    Rozelle, P.L.

    1994-12-31

    The applications of anthracite in Electric Arc Furnace (EAF) steelmaking, include the adjustment of hot metal carbon content, the generation of foamy slags, and its use as a support fuel in the EAF to reduce power consumption per tonne of product. Incentives to use support fuel in EAF steelmaking include the reduction of electric power consumption without reducing plant output. As such, the concept can reduce steelmaking costs and can serve as a basis for maximizing an EAF operation`s demand side management program. The use of carbon and oxygen additions to the EAF can cause significant release of energy within the furnace. This energy can offset a portion of the electrical energy required by the system for production of steel. Reduced consumption of electricity per tonne of hot metal is the result Electrode consumption and tap to tap times can also be reduced. significant interest in the use of anthracite as EAF support fuel, as well as the other applications of anthracite in EAF steelmaking, have combined to establish the EAF steelmaking trade as a significant market sector for anthracite. This discussion is a review of key anthracite properties and production considerations, and their interplay with the requirements of the EAF process.

  2. Nitrogen Control in Electric Arc Furnace Steelmaking by DRI (TRP 0009)

    SciTech Connect

    Dr. Gordon A. Irons

    2004-03-31

    Nitrogen is difficult to remove in electric arc furnace (EAF) steelmaking, requiring the use of more energy in the oxygen steelmaking route to produce low-nitrogen steel. The objective of this work was to determine if the injection of directly reduced iron (DRI) fines into EAFs could reduce the nitrogen content by creating fine carbon monoxide bubbles that rinse nitrogen from the steel. The proposed work included physical and chemical characterization of DRI fines, pilot-scale injection into steel, and mathematical modeling to aid in scale-up of the process. Unfortunately, the pilot-scale injections were unsuccessful, but some full-scale data was obtained. Therefore, the original objectives were met, and presented in the form of recommendations to EAF steelmakers regarding: (1) The best composition and size of DRI fines to use; (2) The amount of DRI fines required to achieve a specific reduction in nitrogen content in the steel; and (3) The injection conditions. This information may be used by steelmakers in techno-economic assessments of the cost of reducing nitrogen with this technology.

  3. Achieving zero waste of municipal incinerator fly ash by melting in electric arc furnaces while steelmaking.

    PubMed

    Yang, Gordon C C; Chuang, Tsun-Nan; Huang, Chien-Wen

    2017-02-25

    The main objective of this work was to promote zero waste of municipal incinerator fly ash (MIFA) by full-scale melting in electric arc furnaces (EAFs) of steel mini mills around the world. MIFA, generally, is considered as a hazardous waste. Like in many countries, MIFA in Taiwan is first solidified/stabilized and then landfilled. Due to the scarcity of landfill space, the cost of landfilling increases markedly year by year in Taiwan. This paper presents satisfactory results of treating several hundred tons of MIFA in a full-scale steel mini mill using the approach of "melting MIFA while EAF steelmaking", which is somewhat similar to "molten salt oxidation" process. It was found that this practice yielded many advantages such as (1) about 18wt% of quicklime requirement in EAF steelmaking can be substituted by the lime materials contained in MIFA; (2) MIFA would totally end up as a material in fractions of recyclable EAF dust, oxidized slag and reduced slag; (3) no waste is needed for landfilling; and (4) a capital cost saving through the employment of existing EAFs in steel mini mills instead of building new melting plants for the treatment of MIFA. Thus, it is technically feasible to achieve zero waste of MIFA by the practice of this innovative melting technology.

  4. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights

    2009-05-15

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  5. Valorization of electric arc furnace primary steelmaking slags for cement applications.

    PubMed

    Kim, Hyung-Seok; Kim, Kee-Seok; Jung, Sung Suk; Hwang, Jin Ill; Choi, Jae-Seok; Sohn, Il

    2015-07-01

    To produce supplementary cementitious materials from electric arc furnace (EAF) slags, FeO was reduced using a two-stage reduction process that included an Al-dross reduction reaction followed by direct carbon reduction. A decrease in FeO was observed on tapping after the first-stage reduction, and further reduction with a stirred carbon rod in the second-stage reduction resulted in final FeO content below 5wt%, which is compatible with cement clinker applications. The reduced electric arc furnace slags (REAFS) mixed with cement at a unit ratio exhibited physical properties comparable to those of commercialized ground granulated blast furnace slags (GGBFS). Confocal laser scanning microscopy (CLSM) was used to obtain fundamental information on the cooling characteristics and conditions required to obtain amorphous REAFS. REAFS can be applied in cement mixtures to achieve the hydraulic properties needed for commercial use.

  6. Removal of hexavalent chromium in carbonic acid solution by oxidizing slag discharged from steelmaking process in electric arc furnace

    NASA Astrophysics Data System (ADS)

    Yokoyama, Seiji; Okazaki, Kohei; Sasano, Junji; Izaki, Masanobu

    2014-02-01

    Hexavalent chromium (Cr(VI)) is well-known to be a strong oxidizer, and is recognized as a carcinogen. Therefore, it is regulated for drinking water, soil, groundwater and sea by the environmental quality standards all over the world. In this study, it was attempted to remove Cr(VI) ion in a carbonic acid solution by the oxidizing slag that was discharged from the normal steelmaking process in an electric arc furnace. After the addition of the slag into the aqueous solution contained Cr(VI) ion, concentrations of Cr(VI) ion and total chromium (Cr(VI) + trivalent chromium (Cr(III)) ions decreased to lower detection limit of them. Therefore, the used slag could reduce Cr(VI) and fix Cr(III) ion on the slag. While Cr(VI) ion existed in the solution, iron did not dissolve from the slag. From the relation between predicted dissolution amount of iron(II) ion and amount of decrease in Cr(VI) ion, the Cr(VI) ion did not react with iron(II) ion dissolved from the slag. Therefore, Cr(VI) ion was removed by the reductive reaction between Cr(VI) ion and the iron(II) oxide (FeO) in the slag. This reaction progressed on the newly appeared surface of iron(II) oxide due to the dissolution of phase composed of calcium etc., which existed around iron(II) oxide grain in the slag.

  7. Removal of vapour phase PCDD/Fs in electric arc furnace steelmaking emissions by sorption using plastics.

    PubMed

    Ooi, Tze Chean; Ewan, Bruce C R; Cliffe, Keith R; Anderson, David R; Fisher, Raymond; Thompson, Dennis

    2008-08-01

    Plastics are potentially suitable for the removal of vapour phase PCDD/Fs in emissions from the electric arc furnace (EAF) steelmaking process. Three different commercial plastics, i.e. polypropylene BE170MO (Borealis A/S, Denmark), polypropylene in the form of 5 mm spheres (The Precision Plastic Ball Co. Ltd., UK) and polyethylene LD605BA (ExxonMobil Chemical, Belgium), have been studied using a novel experimental apparatus for the removal of vapour phase PCDD/Fs. Polypropylene BE170MO was identified to be the most suitable product amongst the three plastics in terms of PCDD/F sorption and potential industrial application. The optimum temperature for PCDD/F sorption on polypropylene BE170MO was below 90 degrees C for a removal efficiency of >99% at an average vapour phase PCDD/F concentration of 3.5 ng I-TEQ/Nm(3). At 130 degrees C, 53% of the PCDD/Fs trapped on polypropylene BE170MO were desorbed.

  8. Formation of hexachlorobenzene from dusts of an electric arc furnace used in steelmaking: effect of temperature and dust composition.

    PubMed

    Murakami, Taichi; Shimura, Mizuki; Kasai, Eiki

    2008-10-01

    A certain amount of hexachlorobenzene (HCB), designated a persistent organic pollutant (POP) by the Stockholm Convention, is emitted from an electric arc furnace (EAF) used in the steelmaking process. To understand the formation and decomposition behaviors of HCB during the treatment of waste gases from an EAF, characterization of dust samples from EAFs in different plants was conducted. Dusts 1 and 2 were bag filter dusts collected from a common steel plant and a special steel plant, respectively. The initial concentrations of HCB in dusts 1 and 2 were 62 and < 0.1 ng/g of dust, respectively. Then a series of heating experiments was carried out with these dust samples under various conditions. The formation of HCB from both dusts was not significant under an Ar atmosphere, although the amount of formation from dust 1 slightly increased with an increase in the holding temperature. Under an Ar--20% O2 atmosphere, however, a remarkable amount of HCB formed from dust 1 above 573 K. A certain amount of HCB was also formed from dust 2, even though the initial concentration of HCB was very low. Moreover, the coexistence of metallic compounds such as CuCl2 had a significant accelerating effect on the formation of HCB.

  9. Optical Sensors for Post Combustion Control in Electric Arc Furnace Steelmaking (TRP 9851)

    SciTech Connect

    Sarah W. Allendorf; David K. Ottesen; Robert W. Green; Donald R. Hardesty; Robert Kolarik; Howard Goodfellow; Euan Evenson; Marshall Khan; Ovidiu Negru; Michel Bonin; Soren Jensen

    2003-12-31

    Working in collaboration with Stantec Global Technologies, Process Metrix Corporation, and The Timken Company, Sandia National Laboratories constructed and evaluated a novel, laser-based off-gas sensor at the electric arc furnace facility of Timken's Faircrest Steel Plant (Canton, Ohio). The sensor is based on a mid-infrared tunable diode laser (TDL), and measures the concentration and temperature of specific gas species present in the off-gas emanating from the EAF. The laser beam is transmitted through the gas stream at the fourth hole of the EAF, and provides a real-time, in situ measurement that can be used for process optimization. Two sets of field tests were performed in parallel with Stantec's extractive probe off-gas system, and the tests confirm the TDL sensor's operation and applicability for electric steel making. The sensor measures real-time, in situ line-of-sight carbon monoxide (CO) concentrations between 5% and 35% CO, and measures off-gas temperature in the range of 1400 to 1900 K. In order to achieve commercial-ready status, future work is required to extend the sensor for simultaneous CO and CO{sub 2} concentration measurements. In addition, long-term endurance tests including process optimization must be completed.

  10. Electric arc furnaces for steel-making: hot spots for persistent organic pollutants.

    PubMed

    Odabasi, Mustafa; Bayram, Abdurrahman; Elbir, Tolga; Seyfioglu, Remzi; Dumanoglu, Yetkin; Bozlaker, Ayse; Demircioglu, Hulusi; Altiok, Hasan; Yatkin, Sinan; Cetin, Banu

    2009-07-15

    Persistent organic pollutant (POP) concentrations were measured in stack-gases of ferrous scrap processing steel plants with electric arc furnaces (EAFs) (n = 5) in Aliaga, Izmir, Turkey and in air (n = 11) at a site near those plants. Measured stack-gas concentrations for the four plants without scrap preheating (611 +/- 311, 165,000 +/- 285,000, and 33 +/- 3 ng m(-3), average +/- SD for sigma41PCBs, sigma16PAHs, and sigma7PBDEs, respectively) indicated that they are significant sources for polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs). POP emissions from the plant with scrap preheating were significantly higher (13 500, 445 000, and 91 ng m(-3) for sigma41PCBs, sigma16PAHs, and sigma7PBDEs, respectively). It was also shown that the steel plants emit considerable amounts of fugitive POPs in particle-phase. Estimated emissions using the emission factors generated in this study and the production amounts suggested that the steel plants with EAFs may significantly contribute to local and global PAH, PCB, and PBDE emissions. Several other compounds (aromatic and aliphatic hydrocarbons, oxygen, sulfur, nitrogen, and chlorine-containing organic compounds, n = 49) were identified and determined semiquantitatively in the stack-gas and ambient air samples. Ambient air concentrations (62 +/- 35, 320 +/- 134 ng m(-3), 1451 +/- 954 pg m(-3), for sigma41PCBs, sigma16PAHs, and sigma7PBDEs, respectively) were significantly higher than those measured previously around the world and in the region, further confirming that the steel plants with EAFs are "hot spots" for POPs.

  11. 1. GENERAL EXTERIOR VIEW OF THE ELECTRIC FURNACE STEELMAKING PLANT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. GENERAL EXTERIOR VIEW OF THE ELECTRIC FURNACE STEELMAKING PLANT LOOKING NORTHEAST. - U.S. Steel Duquesne Works, Electric Furnace Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  12. Chemical characterization of dust particles recovered from bag filters of electric arc furnaces for steelmaking: some factors influencing the formation of hexachlorobenzene.

    PubMed

    Tsubouchi, Naoto; Hashimoto, Hiroyuki; Ohtaka, Noriaki; Ohtsuka, Yasuo

    2010-11-15

    To make clear some factors controlling the formation of hexachlorobenzene (HCB) in the process of electric arc furnace (EAF) steelmaking, six dust samples recovered from different bag filters in commercial EAF steelmaking plants have been characterized with XRD, SEM-EPMA, XPS and temperature-programmed desorption (TPD) techniques. These dust samples contain 1.9-8.0 mass% of chlorine element, and the XPS and TPD measurements exhibit that the Cl is enriched at the dust surface and composed of the inorganic and organic functionalities, part of the Cl being evolved as HCl in the temperature region of flue gas treatment. All of the samples also include 2.1-6.4 mass% of carbon element, and some of the C can release CO(2) in the TPD up to 300°C to form active carbon sites. The number is related closely to HCB concentration of each dust. Further, it is suggested that the Zn present in the samples consists of ZnFe(2)O(4), ZnO and surface ZnCO(3), and the dust with a larger content of the ZnCO(3) has a higher concentration of HCB. It is possible that HCB formation occurs via gas-solid-solid interactions among gaseous Cl-containing compounds in flue gas, active carbon sites and surface Zn-species produced in exhaust ducts and bag filters.

  13. Exposure assessment of workers to airborne PCDD/Fs, PCBs and PAHs at an electric arc furnace steelmaking plant in the UK.

    PubMed

    Aries, Eric; Anderson, David R; Fisher, Raymond

    2008-06-01

    Occupational exposure studies were undertaken at a UK electric arc furnace (EAF) steelmaking plant to investigate the exposure of workers via inhalation to dioxins, polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) including benzo[a]pyrene (B[a]P). Surveys were undertaken in areas including the melting shop, the casting department and a furnace control cabin. The highest concentrations of dioxins and PCBs were found inside the melting shop nearby EAFs, whereas dioxin and PCB concentrations in the casting department and inside the control cabin were significantly lower. Risk characterization was carried out by comparing the daily intake of dioxins and PCBs through inhalation with the recommended tolerable daily intake (TDI). Health risk assessments were also carried out by combining exposure data with inhalation cancer potency factors to quantify the cancer risk. For the most exposed category of workers (melting shop workers), the estimated daily intake via inhalation was 0.35 pg WHO-TEQ kg(-1) body weight (bw) in the worst case scenario. Considering that the average UK adult exposure to dioxins from the diet is 1.8 pg WHO-TEQ kg(-1) bw day(-1), the results indicated that the estimated daily intake of dioxins via inhalation at the EAF would not result in the recommended range of the TDI (1-4 pg WHO-TEQ kg(-1) bw day(-1)) being exceeded. Cancer risks for a 40-year occupational exposure period were determined by multiplying the inhalation dose by the inhalation cancer potency factor for 2,3,7,8-tetrachlorodibenzo-p-dioxin. For melting shop workers, cancer risks from exposure to dioxins and PCBs ranged from 2.05 x 10(-5) to 7.54 x 10(-5). Under most regulatory programmes, excess cancer risks between 1.0 x 10(-4) and 1.0 x 10(-6) indicate an acceptable range of excess cancer risk, suggesting a limited risk from dioxin exposure for workers in the EAF plant. For the calculation of excess cancer risks, no account has been taken of the protection

  14. Novel Direct Steelmaking by Combining Microwave, Electric Arc, and Exothermal Heating Technologies

    SciTech Connect

    Dr. Xiaodi Huang; Dr. J. Y. Hwang

    2005-03-28

    Steel is a basic material broadly used by perhaps every industry and individual. It is critical to our nation's economy and national security. Unfortunately, the American steel industry is losing competitiveness in the world steel production field. There is an urgent need to develop the next generation of steelmaking technology for the American steel industry. Direct steelmaking through the combination of microwave, electric arc, and exothermal heating is a revolutionary change from current steelmaking technology. This technology can produce molten steel directly from a shippable agglomerate, consisting of iron oxide fines, powdered coal, and ground limestone. This technology is projected to eliminate many current intermediate steelmaking steps including coking, pellet sintering, blast furnace (BF) ironmaking, and basic oxygen furnace (BOF) steelmaking. This technology has the potential to (a) save up to 45% of the energy consumed by conventional steelmaking; (b) dramatically reduce the emission of CO{sub 2}, SO{sub 2}, NO{sub x}, VOCs, fine particulates, and air toxics; (c) substantially reduce waste and emission control costs; (d) greatly lower capital cost; and (e) considerably reduce steel production costs. This technology is based on the unique capability of microwaves to rapidly heat steelmaking raw materials to elevated temperature, then rapidly reduce iron oxides to metal by volumetric heating. Microwave heating, augmented with electric arc and exothermal reactions, is capable of producing molten steel. This technology has the components necessary to establish the ''future'' domestic steel industry as a technology leader with a strong economically competitive position in world markets. The project goals were to assess the utilization of a new steelmaking technology for its potential to achieve better overall energy efficiency, minimize pollutants and wastes, lower capital and operating costs, and increase the competitiveness of the U.S. steel industry. The

  15. Vitrification of electric arc furnace dusts.

    PubMed

    Pelino, M; Karamanov, A; Pisciella, P; Crisucci, S; Zonetti, D

    2002-01-01

    Electric arc furnace baghouse dust (EAFD), a waste by-product of the steelmaking process, contains the elements that are volatilized from the charge during the melting (Cr, Pb, Zn, Cu and Cd). The results of leaching tests show that the concentration of these elements exceeds the regulatory limits. Consequently, EAFD cannot be disposed of in ordinary landfill sites without stabilization of the heavy metals. In this work, the vitrification of EAFD, from both carbon and stainless steel productions, were studied. The vitrification process was selected as the inertizing process because it permits the immobilization of the hazardous elements in the glass network and represents an environmentally acceptable method for the stabilization of this waste. Classes of various compositions were obtained by mixing EAFD with glass cullet and sand. The EAFD and the glass products were characterized by DTA, TG, X-ray analysis and by the TCLP test. The results show that the stability of the product is influenced by the glass structure, which mainly depends on the Si/O ratio. Secondary crystallization heat-treatment were carried out on some samples. The results highlighted the formation of spinel phases, which reduced the chemical durability in acid media. The possibility to recover Zn from carbon steel production EAFD was investigated and about 60-70% of metal recovery was obtained. The resulting glass show higher chemical stability than glasses obtained without metal recovery.

  16. Evaluation of steelmaking processes

    SciTech Connect

    Fruehan, R.J.

    1994-01-01

    Objective of the AISI Direct Steelmaking Program is to develop a process for producing steel directly from ore and coal; the process should be less capital intensive, consume less energy, and have higher productivity. A task force was formed to examine available processes: trough, posthearth, IRSID, Electric Arc Furnace, energy optimizing furnace. It is concluded that there is insufficient incentive to replace a working BOF with any of these processes to refine hot metal; however, if new steelmaking capacity is required, IRSID and EOF should be considered. A fully continuous process should not be considered until direct ironmaking and continuous refining are perfected.

  17. Recovery of Zinc and Lead from Electric-Furnace Steelmaking Dust at Berzelius

    NASA Astrophysics Data System (ADS)

    Maczek, Helmut; Kola, Rolf

    1980-01-01

    The Waelz unit at the Berzelius Metallhütten GmbH plant in Duisburg, West Germany, was originally built to recover zinc and lead values in zinc retort residues and slags from lead shaft furnaces. The process has also proved suitable for recovering zinc and lead from steelmaking dusts. The metallurgical characteristics and information on operating costs encountered in the three decades over which this Waelz plant has been in operation at Berzelius are described and discussed.

  18. Acoustic characteristics of electric arc furnaces

    NASA Astrophysics Data System (ADS)

    Cherednichenko, V. S.; Bikeev, R. A.; Cherednichenko, A. V.; Ognev, A. M.

    2016-06-01

    A mathematical model is constructed to describe the appearance and development of the noise characteristics of superpower electric arc furnaces. The noise formation is shown to be related to the pulsation of the axial plasma flows in arc discharges because of the electrodynamic pressure oscillations caused by the interaction of the self-magnetic field with the current passing in an arc. The pressure in the arc axis changes at a frequency of 100 Hz at the maximum operating pressure of 66 kPa for an arc current of 80 kA. The main ac arc sound frequencies are multiples of 100 Hz, which is supported in the practice of operation of electric arc furnaces. The sound intensity in the furnace laboratory reaches 160 dB and is decreased to 115-120 dB in the working furnace area due to shielding by the furnace jacket, the molten metal, and the molten slag. The appropriateness of increasing the hermetic sealing of electric furnaces and creating furnaces operating at low currents and high transformer voltages is corroborated.

  19. Skid resistance performance of asphalt wearing courses with electric arc furnace slag aggregates.

    PubMed

    Kehagia, Fotini

    2009-05-01

    Metallurgical slags are by-products of the iron and steel industry and are subdivided into blast furnace slag and steel slag according to the different steel-producing processes. In Greece, slags are mostly produced from steelmaking using the electric arc furnace process, and subsequently are either disposed in a random way or utilized by the cement industry. Steel slag has been recently used, worldwide, as hard aggregates in wearing courses in order to improve the skidding resistance of asphalt pavements. At the Highway Laboratory, Department of Civil Engineering of Aristotle University of Thessaloniki research has been carried out in the field of steel slags, and especially in electric arc furnace (EAF) slag, to evaluate their possible use in highway engineering. In this paper, the recent results of anti-skidding performance of steel slag aggregates in highway pavements are presented.

  20. System using electric furnace exhaust gas to preheat scrap for steelmaking

    SciTech Connect

    Takai, K.; Iwasaki, K.

    1987-09-08

    A method is described for clean preheating of scrap contaminated with oil and organic matter, for steelmaking, using heat from exhaust gas flow from an electric furnace. It consists of: burning any combustibles present in the exhaust gas flow and simultanously separating out dust particles from the exhaust gas flow; heating a predetermined amount of the scrap by heat exchange with a predetermined portion of the exhaust gas flow; removing and collecting dust from the exhaust gas flow after preheating of scrap thereby; sensing the temperature of the exhaust flow; scrubbing the exhaust gas flow with an aqueous solution of a deodorant solvent flowing at a rate regulated to be in a predetermined relationship related to the exhaust gas temperature sensed prior to scrubbing, thereby generating saturated vapor and reducing the temperature of the exhaust gas flow by a predetermined amount; and electrostatically precipitating out oil mist attached to saturated water vapor and liquid droplets in the exhaust gas flow.

  1. Recycling of electric arc furnace dust through dissolution in deep eutectic ionic liquids and electrowinning.

    PubMed

    Bakkar, Ashraf

    2014-09-15

    The dust waste formed during steelmaking in electric arc furnace (EAF) is rich in ferrous and nonferrous metals. Recycling of this dust as a raw material in iron or steel-making is hazardous and therefore it is mostly dumped. This paper demonstrates recycling of EAF dust through selective dissolution of metal oxides in a deep eutectic ionic liquid. It was found that about 60% of Zn and 39% of Pb could be dissolved from the dust when stirred for 48h in 1 choline chloride:2 urea ionic liquid at 60°C. The resultant electrolyte was subsequently fed to a conventional three-electrode cell where cyclic voltammetry (CV) measurements were conducted to describe its electrochemical behavior. Two deposition peaks were determined and ascribed to deposition of zinc and lead. Static potentials were successively applied to electrowin metallic zinc. SEM/EDX investigations showed that the zinc electrowon contained remarkable contents of lead.

  2. Next Generation Metallic Iron Nodule Technology in Electric Arc Steelmaking - Phase II

    SciTech Connect

    Donald R. Fosnacht; Iwao Iwasaki; Richard F. Kiesel; David J. Englund; David W. Hendrickson; Rodney L. Bleifuss

    2010-12-22

    The current trend in the steel industry is a gradual decline in conventional steelmaking from taconite pellets in blast furnaces, and an increasing number of alternative processes using metallic scrap iron, pig iron and metallized iron ore products. Currently, iron ores from Minnesota and Michigan are pelletized and shipped to the lower Great Lakes ports as blast furnace feed. The existing transportation system and infrastructure is geared to handling these bulk materials. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the needs of the emerging steel industry while utilizing the existing infrastructure and materials handling. A recent commercial installation employing Kobe Steel’s ITmk3 process, was installed in Northeastern Minnesota. The basic process uses a moving hearth furnace to directly reduce iron oxides to metallic iron from a mixture of iron ore, coals and additives. The resulting products can be shipped using the existing infrastructure for use in various steelmaking processes. The technology reportedly saves energy by 30% over the current integrated steelmaking process and reduces emissions by more than 40%. A similar large-scale pilot plant campaign is also currently in progress using JFE Steel’s Hi-QIP process in Japan. The objective of this proposal is to build upon and improve the technology demonstrated by Kobe Steel and JFE, by further reducing cost, improving quality and creating added incentive for commercial development. This project expands previous research conducted at the University of Minnesota Duluth’s Natural Resources Research Institute and that reported by Kobe and JFE Steel. Three major issues have been identified and are addressed in this project for producing high-quality nodular reduced iron (NRI) at low cost: (1) reduce the processing temperature, (2) control the furnace gas atmosphere over the NRI, and (3) effectively use sub

  3. Mass and elemental distributions of atmospheric particles nearby blast furnace and electric arc furnace operated industrial areas in Australia.

    PubMed

    Mohiuddin, Kazi; Strezov, Vladimir; Nelson, Peter F; Stelcer, Eduard; Evans, Tim

    2014-07-15

    The improved understanding of mass and elemental distributions of industrial air particles is important due to their heterogeneous atmospheric behaviour and impact on human health and the environment. In this study, particles of different size ranges were collected from three sites in Australia located in the vicinity of iron and steelmaking industries and one urban background site with very little industrial influence. In order to determine the importance of the type of industrial activity on the urban atmospheric quality, the industrial sites selected in this study were in the close proximity to two blast furnace operated and one electric arc furnace based steelmaking sites. The chemical compositions of the collected air particles were analysed using the proton induced X-ray emission (PIXE) technique. This study revealed significantly higher metal concentrations in the atmospheric particles collected in the industrial sites, comparing to the background urban site, demonstrating local influence of the industrial activities to the air quality. The modality types of the particles were found to be variable between the mass and elements, and among elements in the urban and industrial areas indicating that the elemental modal distribution is as important as particle mass for particle pollution modelling. The highest elemental number distribution at all studied sites occurred with particle size of 0.1 μm. Iron was found as the main dominant metal at the industrial atmosphere in each particle size range. The industrial Fe fraction in the submicron and ultrafine size particles was estimated at up to 95% which may be released from high temperature industrial activities with the iron and steelmaking industries being one of the major contributors. Hence, these industrial elemental loadings can highly influence the atmospheric pollution at local urban and regional levels and are required to consider in the atmospheric modelling settings.

  4. TILTING ELECTRIC ARC FURNACE USED TO MELT BRONZE IN THE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    TILTING ELECTRIC ARC FURNACE USED TO MELT BRONZE IN THE BRASS FOUNDRY BY MEANS OF AN ARC CREATED BETWEEN TWO HORIZONTAL ELECTRODES. WHEN MELTED, THE FURNACE TILTS, FILLING MOBILE LADLES FROM THE SPOUT. - Stockham Pipe & Fittings Company, Brass Foundry, 4000 Tenth Avenue North, Birmingham, Jefferson County, AL

  5. Hydrothermal treatment of electric arc furnace dust.

    PubMed

    Yu, Bing-Sheng; Wang, Yuh-Ruey; Chang, Tien-Chin

    2011-06-15

    In this study, ZnO crystals were fabricated from electric arc furnace dust (EAFD) after alkaline leaching, purification and hydrothermal treatment. The effects of temperature, duration, pH, and solid/liquid ratio on ZnO crystal morphology and size were investigated. Results show a high reaction temperature capable of accelerating the dissolution of ZnO precursor, expediting the growth of 1D ZnO, and increasing the L/D ratio in the temperature range of 100-200°C. ZnO crystals with high purity can also be obtained, using the one-step hydrothermal treatment with a baffle that depends on the different solubility of zincite and franklinite in the hydrothermal conditions.

  6. Computational Modeling of Arc-Slag Interaction in DC Furnaces

    NASA Astrophysics Data System (ADS)

    Reynolds, Quinn G.

    2017-02-01

    The plasma arc is central to the operation of the direct-current arc furnace, a unit operation commonly used in high-temperature processing of both primary ores and recycled metals. The arc is a high-velocity, high-temperature jet of ionized gas created and sustained by interactions among the thermal, momentum, and electromagnetic fields resulting from the passage of electric current. In addition to being the primary source of thermal energy, the arc jet also couples mechanically with the bath of molten process material within the furnace, causing substantial splashing and stirring in the region in which it impinges. The arc's interaction with the molten bath inside the furnace is studied through use of a multiphase, multiphysics computational magnetohydrodynamic model developed in the OpenFOAM® framework. Results from the computational solver are compared with empirical correlations that account for arc-slag interaction effects.

  7. Computational Modeling of Arc-Slag Interaction in DC Furnaces

    NASA Astrophysics Data System (ADS)

    Reynolds, Quinn G.

    2016-11-01

    The plasma arc is central to the operation of the direct-current arc furnace, a unit operation commonly used in high-temperature processing of both primary ores and recycled metals. The arc is a high-velocity, high-temperature jet of ionized gas created and sustained by interactions among the thermal, momentum, and electromagnetic fields resulting from the passage of electric current. In addition to being the primary source of thermal energy, the arc jet also couples mechanically with the bath of molten process material within the furnace, causing substantial splashing and stirring in the region in which it impinges. The arc's interaction with the molten bath inside the furnace is studied through use of a multiphase, multiphysics computational magnetohydrodynamic model developed in the OpenFOAM® framework. Results from the computational solver are compared with empirical correlations that account for arc-slag interaction effects.

  8. Chemical, physical, structural and morphological characterization of the electric arc furnace dust.

    PubMed

    Machado, Janaína G M S; Brehm, Feliciane Andrade; Moraes, Carlos Alberto Mendes; Santos, Carlos Alberto Dos; Vilela, Antônio Cezar Faria; Cunha, João Batista Marimon da

    2006-08-25

    Electric arc furnace dust (EAFD) is a hazardous industrial waste generated in the collection of particulate material during steelmaking process via electric arc furnace. Important elements to the industry such as, Fe and Zn are the main ones in EAFD. Due to their presence, it becomes very important to know how these elements are combined before studying new technologies for its processing. The aim of this work was to carry out a chemical, physical, structural and morphological characterization of the EAFD. The investigation was carried out by using granulometry analysis, chemical analysis, scanning electron microscopy (SEM), energy dispersive spectroscopy via SEM (EDS), X-ray mapping analysis via SEM, X-ray diffraction (XRD) and Mössbauer spectroscopy. By XRD the following phases were detected: ZnFe(2)O(4), Fe(3)O(4), MgFe(2)O(4), FeCr(2)O (4), Ca(0.15)Fe(2.85)O(4), MgO, Mn(3)O(4), SiO(2) and ZnO. On the other hand, the phases detected by Mössbauer spectroscopy were: ZnFe(2)O(4), Fe(3)O(4), Ca(0.15)Fe(2.85)O(4) and FeCr(2)O(4). Magnesium ferrite (MgFe(2)O(4)), observed in the XRD pattern as overlapped peaks, was not identified in the Mössbauer spectroscopy analysis.

  9. Structural ceramics containing electric arc furnace dust.

    PubMed

    Stathopoulos, V N; Papandreou, A; Kanellopoulou, D; Stournaras, C J

    2013-11-15

    In the present work the stabilization of electric arc furnace dust EAFD waste in structural clay ceramics was investigated. EAFD was collected over eleven production days. The collected waste was characterized for its chemical composition by Flame Atomic Absorption Spectroscopy. By powder XRD the crystal structure was studied while the fineness of the material was determined by a laser particle size analyzer. The environmental characterization was carried out by testing the dust according to EN12457 standard. Zn, Pb and Cd were leaching from the sample in significant amounts. The objective of this study is to investigate the stabilization properties of EAFD/clay ceramic structures and the potential of EAFD utilization into structural ceramics production (blocks). Mixtures of clay with 2.5% and 5% EAFD content were studied by TG/DTA, XRD, SEM, EN12457 standard leaching and mechanical properties as a function of firing temperature at 850, 900 and 950 °C. All laboratory facilities maintained 20 ± 1 °C. Consequently, a pilot-scale experiment was conducted with an addition of 2.5% and 5% EAFD to the extrusion mixture for the production of blocks. During blocks manufacturing, the firing step reached 950 °C in a tunnel kiln. Laboratory heating/cooling gradients were similar to pilot scale production firing. The as produced blocks were then subjected to quality control tests, i.e. dimensions according to EN772-17, water absorbance according to EN772-6, and compressive strength according to EN772-1 standard, in laboratory facilities certified under EN17025. The data obtained showed that the incorporation of EAFD resulted in an increase of mechanical strength. Moreover, leaching tests performed according to the Europeans standards on the EAFD-block samples showed that the quantities of heavy metals leached from crushed blocks were within the regulatory limits. Thus the EAFD-blocks can be regarded as material of no environmental concern.

  10. Method of operating a centrifugal plasma arc furnace

    DOEpatents

    Kujawa, Stephan T.; Battleson, Daniel M.; Rademacher, Jr., Edward L.; Cashell, Patrick V.; Filius, Krag D.; Flannery, Philip A.; Whitworth, Clarence G.

    1998-01-01

    A centrifugal plasma arc furnace is used to vitrify contaminated soils and other waste materials. An assessment of the characteristics of the waste is performed prior to introducing the waste into the furnace. Based on the assessment, a predetermined amount of iron is added to each batch of waste. The waste is melted in an oxidizing atmosphere into a slag. The added iron is oxidized into Fe.sub.3 O.sub.4. Time of exposure to oxygen is controlled so that the iron does not oxidize into Fe.sub.2 O.sub.3. Slag in the furnace remains relatively non-viscous and consequently it pours out of the furnace readily. Cooled and solidified slag produced by the furnace is very resistant to groundwater leaching. The slag can be safely buried in the earth without fear of contaminating groundwater.

  11. Method of operating a centrifugal plasma arc furnace

    DOEpatents

    Kujawa, S.T.; Battleson, D.M.; Rademacher, E.L. Jr.; Cashell, P.V.; Filius, K.D.; Flannery, P.A.; Whitworth, C.G.

    1998-03-24

    A centrifugal plasma arc furnace is used to vitrify contaminated soils and other waste materials. An assessment of the characteristics of the waste is performed prior to introducing the waste into the furnace. Based on the assessment, a predetermined amount of iron is added to each batch of waste. The waste is melted in an oxidizing atmosphere into a slag. The added iron is oxidized into Fe{sub 3}O{sub 4}. Time of exposure to oxygen is controlled so that the iron does not oxidize into Fe{sub 2}O{sub 3}. Slag in the furnace remains relatively non-viscous and consequently it pours out of the furnace readily. Cooled and solidified slag produced by the furnace is very resistant to groundwater leaching. The slag can be safely buried in the earth without fear of contaminating groundwater. 3 figs.

  12. Hydrometallurgical process for zinc recovery from electric arc furnace dust (EAFD): part I: Characterization and leaching by diluted sulphuric acid.

    PubMed

    Oustadakis, P; Tsakiridis, P E; Katsiapi, A; Agatzini-Leonardou, S

    2010-07-15

    The present paper is the first of a series of two articles dealing with the development of an integrated process for the recovery of zinc from electric arc furnace dust (EAFD), a hazardous industrial waste generated in the collection of particulate material during steelmaking process via electric arc furnace. Part I presents the EAFD characterization and its leaching process by diluted sulphuric acid, whereas Part II deals with the purification of the leach liquor and the recovery of zinc by solvent extraction/electrowinning. The characterization of the examined electric arc furnace dust was carried out by using granulometry analysis, chemical analysis, X-ray diffraction (XRD), thermogravimetric/differential thermal analysis (TG/DTA) and scanning electron microscopy (SEM). The leaching process was based on the Zn extraction with diluted sulphuric acid from EAFD under atmospheric conditions and without using any preliminary treatment. Statistical design and analysis of experiments were used, in order to determine the main effects and interactions of the leaching process factors, which were: acid normality, temperature and solid to liquid ratio. The zinc recovery efficiency on the basis of EAFD weight reached 80%. X-ray diffraction and scanning electron microscopy were used for the characterization of the leached residues.

  13. Recycling of an electric arc furnace flue dust to obtain high grade ZnO.

    PubMed

    Ruiz, Oscar; Clemente, Carmen; Alonso, Manuel; Alguacil, Francisco Jose

    2007-03-06

    The production of steel in electric arc furnace (EAF) generates a by-product called EAF dusts. These steelmaking flue dusts are classified in most industrialized countries as hazardous residues because the heavy metals contained in them, tend to leach under slightly acidic rainfall conditions. However, and at the same time they contain zinc species which can be used as a source to obtain valuable by-products. The present investigation shows results on the processing of an EAF flue dust using ammonium carbonate solutions. Once zinc is dissolved: ZnO + 4NH3 + H2O --> Zn(NH3)4(2+) + 2OH- with other impurities (i.e. cadmium and copper), these are eliminated from the zinc solution via cementation with metallic zinc. The purified zinc solution was evaporated (distilled) until precipitation of a zinc carbonate species, which then was calcined to yield a zinc oxide of a high grade. For the unattacked dust residue from the leaching operation, mainly composed of zinc ferrite, several options can be considered: back-recycling to the furnace, further treatment by sodium hydroxide processing or a more safely dumping due to its relatively inertness.

  14. Techno-economic assessment of electric steelmaking through the year 2000

    SciTech Connect

    Bosley, J. J.; Clark, J. P.; Dancy, T. E.; Fruehan, R. J.; McIntyre, E. H.

    1987-07-01

    This paper presents a critical review of the outlook for electric steelmaking including an assessment of existing and potential electric arc furnace (EAF) capacity. Suggested areas of development to minimize energy consumption and optimize output are also featured. 20 figs.; 62 tabs.

  15. Graphite electrode DC arc furnace. Innovative technology summary report

    SciTech Connect

    1999-05-01

    The Graphite Electrode DC Arc Furnace (DC Arc) is a high-temperature thermal process, which has been adapted from a commercial technology, for the treatment of mixed waste. A DC Arc Furnace heats waste to a temperature such that the waste is converted into a molten form that cools into a stable glassy and/or crystalline waste form. Hazardous organics are destroyed through combustion or pyrolysis during the process and the majority of the hazardous metals and radioactive components are incorporated in the molten phase. The DC Arc Furnace chamber temperature is approximately 593--704 C and melt temperatures are as high as 1,500 C. The DC Arc system has an air pollution control system (APCS) to remove particulate and volatiles from the offgas. The advantage of the DC Arc is that it is a single, high-temperature thermal process that minimizes the need for multiple treatment systems and for extensive sorting/segregating of large volumes of waste. The DC Arc has the potential to treat a wide range of wastes, minimize the need for sorting, reduce the final waste volumes, produce a leach resistant waste form, and destroy organic contaminants. Although the DC arc plasma furnace exhibits great promise for treating the types of mixed waste that are commonly present at many DOE sites, several data and technology deficiencies were identified by the Mixed Waste Focus Area (MWFA) regarding this thermal waste processing technique. The technology deficiencies that have been addressed by the current studies include: establishing the partitioning behavior of radionuclides, surrogates, and hazardous metals among the product streams (metal, slag, and offgas) as a function of operating parameters, including melt temperature, plenum atmosphere, organic loading, chloride concentration, and particle size; demonstrating the efficacy of waste product removal systems for slag and metal phases; determining component durability through test runs of extended duration, evaluating the effect of

  16. GUI for studying the parameters influence of the electric arc model for a three-phase electric arc furnace

    NASA Astrophysics Data System (ADS)

    Ghiormez, L.; Prostean, O.; Panoiu, M.; Panoiu, C.

    2017-01-01

    This paper presents an analysis regarding the modeling of the behavior for a three-phase electric arc furnace installation. Therefore, a block diagram is implemented in Simulink that represents the modeling of the entire electric arc furnace installation. This block diagram contains also the modeling of the electric arc which is the element that makes the electric arc furnace behaving as a nonlinear load. The values for the model parameters of the electric arc furnace installation are like the ones from the real installation taken into consideration. Other model parameters are the electric arc model ones. In order to study the influence of the parameters of the electric arc models, it is developed a Matlab program that contains the graphical user interfaces. These interfaces make connection with the models of the electric arc implemented in Simulink. The interfaces allow the user to modify parameters for each of the electric arc model. Current and voltage of the electric arc are the variables taken into account to study the influence of the parameters on the electric arc models. Waveforms for voltage and current of the electric arc are illustrated when a parameter of the model is modified in order to analyze the importance of this parameter on the electric arc model. Also, for each of the models is presented the voltage-current characteristic of the electric arc because this characteristic gives information about the behavior of the electric arc furnace installation.

  17. Physicochemical properties of the zinc-containing dusts of electric furnace steelmaking

    NASA Astrophysics Data System (ADS)

    Korneev, V. P.; Sirotinkin, V. P.; Petrakova, N. V.; Dyubanov, V. G.; Leont'ev, L. I.

    2013-07-01

    The properties of the dusts of electric-arc melting in the Severstal' metallurgical works are studied by X-ray diffraction, Mössbauer spectroscopy, and electron microscopy. The elemental compositions of dust particles of various sizes are determined, and the complex structural composition of iron-containing oxide phases is revealed. It is shown that, in these systems, the carbon reduction of zinc from zincite is possible in the solid state in the temperature range 600-1000°C. In this case, zinc passes into a gaseous phase and iron oxides are reduced to form metallic iron.

  18. High-bandwidth continuous-flow arc furnace

    DOEpatents

    Hardt, D.E.; Lee, S.G.

    1996-08-06

    A high-bandwidth continuous-flow arc furnace for stream welding applications includes a metal mass contained in a crucible having an orifice. A power source charges an electrode for generating an arc between the electrode and the mass. The arc heats the metal mass to a molten state. A pressurized gas source propels the molten metal mass through the crucible orifice in a continuous stream. As the metal is ejected, a metal feeder replenishes the molten metal bath. A control system regulates the electrode current, shielding gas pressure, and metal source to provide a continuous flow of molten metal at the crucible orifice. Independent control over the electrode current and shield gas pressure decouples the metal flow temperature and the molten metal flow rate, improving control over resultant weld characteristics. 4 figs.

  19. High-bandwidth continuous-flow arc furnace

    DOEpatents

    Hardt, David E.; Lee, Steven G.

    1996-01-01

    A high-bandwidth continuous-flow arc furnace for stream welding applications includes a metal mass contained in a crucible having an orifice. A power source charges an electrode for generating an arc between the electrode and the mass. The arc heats the metal mass to a molten state. A pressurized gas source propels the molten metal mass through the crucible orifice in a continuous stream. As the metal is ejected, a metal feeder replenishes the molten metal bath. A control system regulates the electrode current, shielding gas pressure, and metal source to provide a continuous flow of molten metal at the crucible orifice. Independent control over the electrode current and shield gas pressure decouples the metal flow temperature and the molten metal flow rate, improving control over resultant weld characteristics.

  20. Glass-ceramic materials from electric arc furnace dust.

    PubMed

    Kavouras, P; Kehagias, T; Tsilika, I; Kaimakamis, G; Chrissafis, K; Kokkou, S; Papadopoulos, D; Karakostas, Th

    2007-01-31

    Electric arc furnace dust (EAFD) was vitrified with SiO2, Na2CO3 and CaCO3 powders in an electric furnace at ambient atmosphere. Vitreous products were transformed into glass-ceramic materials by two-stage heat treatment, at temperatures determined by differential thermal analysis. Both vitreous and glass-ceramic materials were chemically stable. Wollastonite (CaSiO3) was separated from the parent matrix as the dominant crystalline phase, verified by X-ray diffraction analysis and energy dispersive spectrometry. Transmission electron microscopy revealed that wollastonite crystallizes mainly in its monoclinic form. Knoop microhardness was measured with the static indentation test method in all initial vitreous products and the microhardness values were in the region of 5.0-5.5 GPa. Devitrification resulted in glass-ceramic materials with microhardness values strongly dependent on the morphology and orientation of the separated crystal phase.

  1. A rotary arc furnace for aluminum dross processing

    SciTech Connect

    Drouet, M.G.; Meunier, J.; Laflamme, C.B.; Handfield, M.D.; Biscaro, A.; Lemire, C.

    1995-12-31

    Dross, a major by-product of all processes involving molten aluminum, forms at the surface of the molten metal as the latter reacts with the furnace atmosphere. It generally represents 1 to 5 wt% of the melt, depending on the process, and contains on average about 50% free aluminum dispersed in an oxide layer. Since aluminum production is highly energy-intensive, dross recycling is very attractive from both the energy and the economic standpoints. The conventional recycling process using salt rotary furnaces is thermally inefficient and environmentally non-acceptable because of the production of salt slags. Hydro-Quebec has developed and patented a new salt-free technology using a rotary furnace heated by an electric arc between two graphite electrodes, called DROSCAR{reg_sign}. A 600-kW pilot plant in operation at LTEE is in use to demonstrate the process. This process provides aluminum recovery rates over 90%, using a highly energy efficient, environmentally sound production method. In 1994, 400 tonnes of aluminum dross were treated in this facility and several tests on various types of dross have also been conducted in early 1995. A report on the results will be presented.

  2. Effect of the chemical composition of slag on its foamability in an electric arc furnace

    NASA Astrophysics Data System (ADS)

    Kozhukhov, A. A.

    2015-06-01

    The problems of foaming electric furnace slags are considered. The role of the physicochemical properties of slag during its foaming in electric arc furnaces is studied. The regions of slag foaming in an electric arc furnace are determined. Based on the derived relations between the chemical composition of slag and its foamability, one can choose a rational path of slag formation to ensure good slag foaming in the course of electrosmelting of steel.

  3. Evaluation of the emission characteristics of PCDD/Fs from electric arc furnaces.

    PubMed

    Chang, Moo Been; Huang, Hung Chi; Tsai, Shian Sheng; Chi, Kai Hsien; Chang-Chien, Guo Ping

    2006-03-01

    Distribution of PCDD/F (polychlorinated dibenzo-p-dioxin and polychlorinated dibenzofuran) congeners at two electric arc furnaces (EAFs) in Taiwan is evaluated via intensive stack sampling and analysis. Two kinds of exhaust system in EAFs including stack system and shutter system are selected for measuring dioxin emissions. In addition, dioxin emissions during oxidation and reduction stages at EAF-A were characterized. Results indicate that the PCDD/F concentration of stack gas in EAF-A was 4.39 ng/Nm(3) while total Toxic Equivalent Quantity (TEQ) concentration was 0.35 ng I-TEQ/Nm(3). The PCDD/F concentration of stack gas in EAF-B was 2.20 ng/Nm(3) and the TEQ concentration was 0.14 ng I-TEQ/Nm(3). 1,2,3,4,6,7,8-H(p)CDF, OCDD and OCDF are the major contributors of the dioxin concentrations for two EAFs investigated and the percentage of PCDD/F in particulate phase increases as the chlorination level of the PCDD/F congener increases. The results obtained on gas/particulate partitioning of PCDD/Fs in flue gases prior to the APCD in EAFs indicate that more than 90% exists in particulate phase. In EAF-A, the PCDD/F concentration during oxidation stage is slightly higher than that measured during reduction stage, including the sampling points of CO converter outlet, prior to bag filter and stack. Majority of PCDD/Fs emitted from steel-making processes exists in particulate-phase (about 60-70%) at both EAFs investigated.

  4. Removal of chloride from electric arc furnace dust.

    PubMed

    Chen, Wei-Sheng; Shen, Yun-Hwei; Tsai, Min-Shing; Chang, Fang-Chih

    2011-06-15

    Electric arc furnace (EAF) dust with high chloride content increases the threat of dioxin emissions and the high chloride content reduces the value of recycled zinc oxide produced by EAF dust recycling plants. This study conducts a number of laboratory experiments to determine the technical feasibility of a new dechlorination method. These methods consist of a series of roasting processes and water washing processes. In the roasting process, EAF dust was heated in a tube furnace to evaluate the parameters of atmospheric conditions, roasting temperature, and roasting time. Results indicate that sulfation roasting is more efficient in reducing chloride content than other roasting processes. The water washing process can totally remove water-soluble chloride at a solid to liquid ratio of 1:10. However, the remaining water-insoluble substance is difficult to dechlorinate. For example, lead chloride forms a hydroxyl-halide (PbOHCl) and lead chloride carbonate (Pb(2)CO(3)Cl(2)) agglutinative matrix that is hard to wash away.

  5. Analysis of arc emission spectra of stainless steel electric arc furnace slag affected by fluctuating arc voltage.

    PubMed

    Aula, Matti; Mäkinen, Ari; Fabritius, Timo

    2014-01-01

    Control of chromium oxidation in the electric arc furnace (EAF) is a significant problem in stainless steel production due to variations of the chemical compositions in the EAF charge. One potential method to control chromium oxidation is to analyze the emission spectrum of the electric arc in order to find indicators of rising chromium content in slag. The purpose of this study was to determine if slag composition can be gained by utilizing electric arc emission spectra in the laboratory environment, despite electric arc voltage fluctuations and varying slag composition. The purpose of inducing voltage fluctuation was to simulate changes in the industrial EAF process. The slag samples were obtained from Outokumpu Stainless Oy Tornio Works, and three different arc currents were used. The correlation analysis showed that the emission spectra offer numerous peak ratios with high correlations to the X-ray fluorescence-measured slag CrO(x)/FeO(x) and MnO/SiO2 ratios. These ratios are useful in determining if the reduction agents have been depleted in the EAF. The results suggest that analysis of laboratory-scale electric arc emission spectra is suitable for indicating the high CrO(x) or MnO content of the slag despite the arc fluctuations. Reliable analysis of other slag components was not successful.

  6. Thermal Treatment of Solid Wastes Using the Electric Arc Furnace

    SciTech Connect

    O'Connor, W.K.; Turner, P.C.

    1999-09-01

    A thermal waste treatment facility has been developed at the Albany Research Center (ARC) over the past seven years to process a wide range of heterogeneous mixed wastes, on a scale of 227 to 907 kg/h (500 to 2,000 lb/h). The current system includes a continuous feed system, a 3-phase AC, 0.8 MW graphite electrode arc furnace, and a dedicated air pollution control system (APCS) which includes a close-coupled thermal oxidizer, spray cooler, baghouse, and wet scrubber. The versatility of the complete system has been demonstrated during 5 continuous melting campaigns, ranging from 11 to 25 mt (12 to 28 st) of treated wastes per campaign, which were conducted on waste materials such as (a) municipal incinerator ash, (b) simulated low-level radioactive, high combustible-bearing mixed wastes, (c) simulated low-level radioactive liquid tank wastes, (d) heavy metal contaminated soils, and (e) organic-contaminated dredging spoils. In all cases, the glass or slag products readily passed the U.S. Environmental Protection Agency (EPA) Toxicity Characteristic Leachability Program (TCLP) test. Additional studies are currently under way on electric utility wastes, steel and aluminum industry wastes, as well as zinc smelter residues. Thermal treatment of these solid waste streams is intended to produce a metallic product along with nonhazardous glass or slag products.

  7. New algorithm for controlling electric arc furnaces using their vibrational and acoustic characteristics

    NASA Astrophysics Data System (ADS)

    Cherednichenko, V. S.; Bikeev, R. A.; Serikov, V. A.; Rechkalov, A. V.; Cherednichenko, A. V.

    2016-12-01

    The processes occurring in arc discharges are analyzed as the sources of acoustic radiation in an electric arc furnace (EAF). Acoustic vibrations are shown to transform into mechanical vibrations in the furnace laboratory. The shielding of the acoustic energy fluxes onto water-cooled wall panels by a charge is experimentally studied. It is shown that the rate of charge melting and the depth of submergence of arc discharges in the slag and metal melt can be monitored by measuring the vibrational characteristics of furnaces and using them in a universal industrial process-control system, which was developed for EAFs.

  8. Optimization of anthracite calcination process in a vertical electric arc furnace

    SciTech Connect

    Perron, J.; Bouvette, J.F.; Dupuis, M.

    1996-10-01

    Anthracite is used for cathode block manufacturing must be calcined prior to its use to eliminate volatile matter and reduce its electrical resistivity. Anthracite calcination in vertical electric arc furnaces is widely used in the industry. It is well known that this technology leads to a radial temperature gradient in the furnace which results in non-homogeneous calcined anthracite properties. Also, operation experience has shown that production of calcination furnaces can be difficult to stabilize if process changes occur, which may lead to variable quality of the calcined material. To optimize the calcination process, an improved control strategy and a mathematical model of Elkem-type electric arc furnace were developed. Using these, it was successfully demonstrated that temperature gradient in the furnace can be reduced and that furnace productivity can be substantially increased.

  9. Calculation of gas release from DC and AC arc furnaces in a foundry

    NASA Astrophysics Data System (ADS)

    Krutyanskii, M. M.; Nekhamin, S. M.; Rebikov, E. M.

    2016-12-01

    A procedure for the calculation of gas release from arc furnaces is presented. The procedure is based on the stoichiometric ratios of the oxidation of carbon in liquid iron during the oxidation heat period and the oxidation of iron from a steel charge by oxygen in the period of solid charge melting during the gas exchange of the furnace cavity with the external atmosphere.

  10. Radioactively contaminated electric arc furnace dust as an addition to the immobilization mortar in low- and medium-activity repositories.

    PubMed

    Castellote, Marta; Menéndez, Esperanza; Andrade, Carmen; Zuloaga, Pablo; Navarro, Mariano; Ordóñez, Manuel

    2004-05-15

    Electric arc furnace dust (EAFD), generated by the steel-making industry, is in itself an intrinsic hazardous waste; however, the case may also be that scrap used in the process is accidentally contaminated by radioactive elements such as cesium. In this case the resulting EAFD is to be handled as radioactive waste, being duly confined in low- and medium-activity repositories (LMAR). What this paper studies is the reliability of using this radioactive EAFD as an addition in the immobilization mortar of the containers of the LMAR, that is, from the point of view of the durability. Different mixes of mortar containing different percentages of EAFD have been subjected to flexural and compressive strength, initial and final setting time, XRD study, total porosity and pore size distribution, determination of the chloride diffusion coefficient, dimensional stability tests, hydration heat, workability of the fresh mix, and leaching behavior. What is deduced from the results is that for the conditions used in this research, (cement + sand) can be replaced by EAFD upto a ratio [EAFD/(cement + EAFD)] of 46% in the immobilization mortar of LMAR, apparently without any loss in the long-term durability properties of the mortar.

  11. Mineral phases of weathered and recent electric arc furnace dust.

    PubMed

    Martins, Fernanda Machado; dos Reis Neto, José Manoel; da Cunha, Carlos Jorge

    2008-06-15

    A weathered and a recent sample of electric arc furnace dust (EAFD), generated in a southern Brazilian steel industry, were characterized by X-ray fluorescence spectroscopy (XFA), powder X-ray diffraction (XRD), thermogravimetric analysis (TG), scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS) probe and Fourier transform infrared spectroscopy (FTIR). A quantitative phase composition model, that accounts for the observed data and for the physico-chemical conditions of formation, was postulated for each material. One sample, in the form of a wet paste, was collected from the lowest part of a landfill and corresponds to a weathered material whereas the other sample was collected from the top portion of the landfill and corresponds to a recently produced material. The dominant cations present in both samples are iron, zinc and lead with minor amounts of manganese, calcium and silicon. The dominant mineralogical phases identified in both materials are Magnetite, Franklinite and Zincite. The recent sample has Laurionite whereas the weathered sample has Hydrocerussite and Hydrozincite.

  12. Impacts of iron and steelmaking facilities on soil quality.

    PubMed

    Strezov, Vladimir; Chaudhary, Chandrakant

    2017-02-22

    Iron and steel are highly important materials used in a wide range of products with important contribution to the economic development. The processes for making iron and steel are energy intensive and known to contribute to local pollution. Deposition of the metals may also have adverse impacts on soil quality, which requires detailed assessment. The aim of this study was to investigate the impacts of iron and steelmaking facilities on the local soil quality. Soil samples were collected in the vicinity of two steelmaking sites in Australia, one based on blast furnace steelmaking operation, while the second site was based on electric arc furnace steel recycling. The soil samples were compared to a background site where no industrial impact is expected. The soil collected near industrial facilities contained larger toxic metal contents, however this concentration for all priority metals was within the Australian National Environmental Protection Measure guidelines for the acceptable recreational soil quality. When compared to the international soil quality guidelines, some of the soils collected near the industrial sites, particularly near the blast furnace operated steelmaking, exceeded the arsenic, iron and manganese (according to United States Environmental Protection Agency guidelines) and chromium, copper and nickel concentrations (according to the Canadian guidelines). The work further provided a novel environmental assessment model taking into consideration the environmental and health impacts of each element. The environmental assessment revealed most significant contribution of manganese, followed by titanium, zinc, chromium and lead. Titanium was the second most important contributor to the soil quality, however this metal is currently not included in any of the international soil quality guidelines.

  13. Characterization of steel mill electric-arc furnace dust.

    PubMed

    Sofilić, Tahir; Rastovcan-Mioc, Alenka; Cerjan-Stefanović, Stefica; Novosel-Radović, Vjera; Jenko, Monika

    2004-06-18

    In order to make a complete characterization of electric-arc furnace (EAF) dust, as hazardous industrial waste, and to solve its permanent disposal and/or recovery, bearing in mind both the volumes formed in the Croatian steel industry and experiences of developed industrial countries, a study of its properties was undertaken. For this purpose, samples of EAF dust, taken from the regular production process in the Zeljezara Sisak Steel Mill between December 2000 and December 2001, were subjected to a series of tests. The chemical composition of EAF dust samples was investigated by means of a several different analytical methods. The results from the chemical analysis show that the approximate order of abundance of major elements in EAF dusts is as follows: Fe, Zn, Mn, Ca, Mg, Si, Pb, S, Cr, Cu, Al, C, Ni, Cd, As and Hg. Granular-metric composition of single samples was determined by applying sieve separation. Scanning electron micro-structural examination of EAF dust microstructure was performed and results indicated that all twelve EAF dusts were composed of solid spherical agglomerates with Fe, Zn, Pb, O, Si and Ca as the principal element. The investigation of grain morphology and the mineralogical composition of EAF dust were taken by combination of high resolution Auger electron spectroscopy (HR AES), X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction analysis. The analysis of XPS-spectra determined the presence of zinc in the form of ZnO phase and the presence of lead in the form of PbO phase, i.e. PbSO3/PbSO4 forms. The results of the X-ray diffraction phase analysis show that the basis of the examined EAF dust samples is made of a mixture of metal oxides, silicates and sulphates. The metal concentration, anions, pH value and conductivity in water eluates was determined in order to define the influence of EAF dust on the environment.

  14. Thermodynamic Modeling of Zinc Speciation in Electric Arc Furnace Dust

    NASA Astrophysics Data System (ADS)

    Pickles, Chris A.

    2011-04-01

    The remelting of automobile scrap, containing galvanized steel, in an electric arc furnace (EAF) results in the generation of a dust, which contains considerable amounts of zinc and other metals. Typically, the amount of zinc is of significant commercial value, but the recovery of this metal can be hindered by the varied speciation of zinc. The majority of the zinc exists as zincite (ZnO) and zinc ferrite (ZnFe2O4) or ferritic spinels ((Zn x Mn y Fe1-x-y )Fe2O4), but other zinccontaining species such as zinc chloride, zinc hydroxide chlorides, hydrated zinc sulphates and zinc silicates have also been identified. There is a scarcity of research literature on the thermodynamic aspects of the formation of these zinc-containing species, in particular, the minor zinc-containing species. Therefore, in this study, the equilibrium module of HSC Chemistry® 6.1 was utilized to calculate the types and the amounts of the zinc-containing species. The variables studied were: the gas composition, the temperature and the dust composition. At high temperatures, zincite forms via the reaction of zinc vapour with oxygen gas and the zinc-manganese ferrites form as a result of the reaction of iron-manganese particles with zinc vapour and oxygen. At intermediate temperatures, zinc sulphates are produced through the reaction of zinc oxide and sulphur dioxide gas. As room temperature is approached, zinc chlorides and fluorides form by the reaction of zinc oxide with hydrogen chloride and hydrogen fluoride gases, respectively. Zinc silicate likely forms via the high temperature reaction of zinc vapour and oxygen with silica. In the presence of excess water and as room temperature is approached, the zinc sulphates, chlorides and fluorides can become hydrated.

  15. Innovation approaches to controlling the electric regimes of electric arc furnaces

    NASA Astrophysics Data System (ADS)

    Bikeev, R. A.; Serikov, V. A.; Ognev, A. M.; Rechkalov, A. V.; Cherednichenko, V. S.

    2015-12-01

    The processes of current passage in an ac electric arc furnace (EAF) are subjected to industrial experiments and mathematical simulation. It is shown that, when a charge is melted, arcs between charge fragments exist in series with main arc discharges, and these arcs influence the stability of the main arc discharges. The measurement of instantaneous currents and voltages allowed us to perform a real-time calculation of the electrical characteristics of a three-phase circuit and to determine the θ parameter, which characterizes the nonlinearity of the circuit segment between electrodes. Based on these studies, we created an advanced system for controlling the electric regime of EAF.

  16. Optical emission from a small scale model electric arc furnace in 250-600 nm region

    SciTech Connect

    Maekinen, A.; Tikkala, H.; Aksela, H.; Niskanen, J.

    2013-04-15

    Optical emission spectroscopy has been for long proposed for monitoring and studying industrial steel making processes. Whereas the radiative decay of thermal excitations is always taking place in high temperatures needed in steel production, one of the most promising environment for such studies are electric arc furnaces, creating plasma in excited electronic states that relax with intense characteristic emission in the optical regime. Unfortunately, large industrial scale electric arc furnaces also present a challenging environment for optical emission studies and application of the method is not straightforward. To study the usability of optical emission spectroscopy in real electric arc furnaces, we have developed a laboratory scale DC electric arc furnace presented in this paper. With the setup, optical emission spectra of Fe, Cr, Cr{sub 2}O{sub 3}, Ni, SiO{sub 2}, Al{sub 2}O{sub 3}, CaO, and MgO were recorded in the wavelength range 250-600 nm and the results were analyzed with the help of reference data. The work demonstrates that using characteristic optical emission, obtaining in situ chemical information from oscillating plasma of electric arc furnaces is indeed possible. In spite of complications, the method could possibly be applied to industrial scale steel making process in order to improve its efficiency.

  17. Optical emission from a small scale model electric arc furnace in 250-600 nm region.

    PubMed

    Mäkinen, A; Niskanen, J; Tikkala, H; Aksela, H

    2013-04-01

    Optical emission spectroscopy has been for long proposed for monitoring and studying industrial steel making processes. Whereas the radiative decay of thermal excitations is always taking place in high temperatures needed in steel production, one of the most promising environment for such studies are electric arc furnaces, creating plasma in excited electronic states that relax with intense characteristic emission in the optical regime. Unfortunately, large industrial scale electric arc furnaces also present a challenging environment for optical emission studies and application of the method is not straightforward. To study the usability of optical emission spectroscopy in real electric arc furnaces, we have developed a laboratory scale DC electric arc furnace presented in this paper. With the setup, optical emission spectra of Fe, Cr, Cr2O3, Ni, SiO2, Al2O3, CaO, and MgO were recorded in the wavelength range 250-600 nm and the results were analyzed with the help of reference data. The work demonstrates that using characteristic optical emission, obtaining in situ chemical information from oscillating plasma of electric arc furnaces is indeed possible. In spite of complications, the method could possibly be applied to industrial scale steel making process in order to improve its efficiency.

  18. 40 CFR Table K-1 to Subpart K of... - Electric Arc Furnace (EAF) CH4 Emission Factors

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Electric Arc Furnace (EAF) CH4.... 98, Subpt. K, Table K-1 Table K-1 to Subpart K of Part 98—Electric Arc Furnace (EAF) CH4 Emission... charging intermittently every minute. b Temperature measured in off-gas channel downstream of the...

  19. 40 CFR Table K-1 to Subpart K of... - Electric Arc Furnace (EAF) CH4 Emission Factors

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Electric Arc Furnace (EAF) CH4.... 98, Subpt. K, Table K-1 Table K-1 to Subpart K of Part 98—Electric Arc Furnace (EAF) CH4 Emission... charging intermittently every minute. b Temperature measured in off-gas channel downstream of the...

  20. 40 CFR Table K-1 to Subpart K of... - Electric Arc Furnace (EAF) CH4 Emission Factors

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Electric Arc Furnace (EAF) CH4.... 98, Subpt. K, Table K-1 Table K-1 to Subpart K of Part 98—Electric Arc Furnace (EAF) CH4 Emission... charging intermittently every minute. b Temperature measured in off-gas channel downstream of the...

  1. 40 CFR Table K-1 to Subpart K of... - Electric Arc Furnace (EAF) CH4 Emission Factors

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Electric Arc Furnace (EAF) CH4.... 98, Subpt. K, Table K-1 Table K-1 to Subpart K of Part 98—Electric Arc Furnace (EAF) CH4 Emission... charging intermittently every minute. b Temperature measured in off-gas channel downstream of the...

  2. Characteristics of electric arc furnaces powered by a low-frequency alternating current

    NASA Astrophysics Data System (ADS)

    Mironov, Yu. M.; Mironova, A. N.

    2016-06-01

    The changes in the parameters of a DSP-100 electric arc furnace that are induced by a decrease in the current frequency are considered. It is shown that the related decrease in the current lead resistances causes an increase in the arc power and voltage, a decrease in the reactive power, and an increase in the electrical efficiency and the power coefficient. The heat indices are expected to be significantly improved.

  3. Modern steelmaking technologies

    NASA Astrophysics Data System (ADS)

    Sinel'nikov, V. A.; Filippov, G. A.; Lavrov, A. S.; Gunenkov, V. Yu.

    2016-06-01

    Based on our experimental results, we propose the following low-cost technologies in the field of steelmaking for implementation: the use of briquettes, which are alternative to solid cast iron and scrap metal and contain scale and carbon-containing wastes, in the charges of electric furnaces and converters; microalloying of metal by nitride phases; modification of steel in a ladle by SiCa + Ba master alloys; and the application of daisy-chain blowing of the metal in a ladle (small-bubble conditions). The efficiency of these technologies for melting in electric furnaces and secondary metallurgy is supported. It is shown that electromagnetic mixing of metal in combination with the optimum conditions of soft reduction of a slab should be used in continuous casting to form an internal structure in a slab at the level of the first class on the Mannesmann scale.

  4. Multivariate economic performance assessment of an MPC controlled electric arc furnace.

    PubMed

    Wei, Donghui; Craig, Ian K; Bauer, Margret

    2007-06-01

    Economic performance is very important to advanced process control projects investigating whether the investment of control technology is worthwhile. In this paper economic performance assessment of a simulated electric arc furnace is conducted. The dependence of controlled variables and the corresponding economic impact are highlighted.

  5. Identification and modelling of a three phase arc furnace for voltage disturbance simulation

    SciTech Connect

    Collantes-Bellido, R.; Gomez, T.

    1997-10-01

    This paper presents a new arc furnace model which copes with the two main voltage disturbances normally associated with arc furnaces: voltage fluctuations and harmonics. The model is based on the stochastic nature of the electric arc current-voltage characteristic. The model has been estimated from measurements made in two actual electric plants. Although a single-phase model has been normally proposed, this paper develops a three-phase model in order to fully represent the unbalances that are present in real plants and which play a central role in the behavior of compensation devices such as SVCs. The model has been implemented using the SIMULINK environment in order to facilitate later simulation of advanced disturbance control systems. Finally, the simulation results are compared with actual data in order to validate the accuracy of the model.

  6. Paired Straight Hearth Furnace - Transformational Ironmaking Process

    SciTech Connect

    Lu, Wei-Kao; Debski, Paul

    2014-11-19

    The U. S. steel industry has reduced its energy intensity per ton of steel shipped by 33% since 1990. However, further significant gains in energy efficiency will require the development of new, transformational iron and steelmaking processes. The Paired Straight Hearth Furnace (PSH) process is an emerging alternative high productivity, direct reduced iron (DRI) technology that may achieve very low fuel rates and has the potential to replace blast furnace ironmaking. The PSH furnace can operate independently or may be coupled with other melting technologies to produce liquid hot metal that is both similar to blast furnace iron and suitable as a feedstock for basic oxygen steelmaking furnaces. The PSH process uses non-metallurgical coal as a reductant to convert iron oxides such as iron ore and steelmaking by-product oxides to DRI pellets. In this process, a multi-layer, nominally 120mm tall bed of composite “green balls” made from oxide, coal and binder is built up and contained within a moving refractory hearth. The pellet bed absorbs radiant heat energy during exposure to the high temperature interior refractory surfaces of the PSH while generating a strongly reducing gas atmosphere in the bed that yields a highly metalized DRI product. The PSH concept has been well tested in static hearth experiments. A moving bed design is being developed. The process developers believe that if successful, the PSH process has the potential to replace blast furnaces and coke ovens at a fraction of the operating and capital cost while using about 30% less energy relative to current blast furnace technology. DRI output could also feed electric arc furnaces (EAFs) by displacing a portion of the scrap charge.

  7. Submerged arc furnace process superior to the Waelz process in reducing PCDD/F emission during thermal treatment of electric arc furnace dust.

    PubMed

    Xu, Fu-Qian; Huang, Shao-Bin; Liao, Wei-Tung; Wang, Lin-Chi; Chang, Yu-Cheng; Chang-Chien, Guo-Ping

    2014-01-01

    Besides the Waelz process, the submerged arc furnace (SAF) process has also been extensively used to retain metals from ashes and scraps in the metallurgical industry. However, very little is known about the formation and depletion of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) from this thermal process. In this study, an electric arc furnace (EAF) dust treatment plant adopting the SAF process was investigated and compared to the plant adopting the Waelz process. The predominant contributor of PCDD/F I-TEQ input was the EAF dusts, accounting for 98.4% of the total. The PCDD/F contents in the generated fly ashes of the SAF were extremely low, as almost all the organic compounds for PCDD/F formation were decomposed by the high operating temperatures (1500-1700 °C) of the SAF. Therefore, the PCDD/F emission factor of the SAF process (46.9 μg I-TEQ/tonne-EAF dust) was significantly lower than that of the Waelz process (840-1120 μg I-TEQ/tonne-EAF dust). Its PCDD/F output/input ratios (0.23 and 0.50 based on mass and toxicity) were also lower than those of the Waelz process plant (0.62 and 1.19). Therefore, the SAF process is superior to the Waelz process in reducing the potential of PCDD/F formation.

  8. Waste form development for a DC arc furnace

    SciTech Connect

    Feng, X.; Bloomer, P.E.; Chantaraprachoom, N.; Gong, M.; Lamar, D.A.

    1996-09-01

    A laboratory crucible study was conducted to develop waste forms to treat nonradioactive simulated {sup 238}Pu heterogeneous debris waste from Savannah River, metal waste from the Idaho National Engineering Laboratory (INEL), and nominal waste also from INEL using DC arc melting. The preliminary results showed that the different waste form compositions had vastly different responses for each processing effect. The reducing condition of DC arc melting had no significant effects on the durability of some waste forms while it decreased the waste form durability from 300 to 700% for other waste forms, which resulted in the failure of some TCLP tests. The right formulations of waste can benefit from devitrification and showed an increase in durability by 40%. Some formulations showed no devitrification effects while others decreased durability by 200%. Increased waste loading also affected waste form behavior, decreasing durability for one waste, increasing durability by 240% for another, and showing no effect for the third waste. All of these responses to the processing and composition variations were dictated by the fundamental glass chemistry and can be adjusted to achieve maximal waste loading, acceptable durability, and desired processing characteristics if each waste formulation is designed for the result according to the glass chemistry.

  9. DC graphite arc furnace, a simple system to reduce mixed waste volume

    SciTech Connect

    Wittle, J.K.; Hamilton, R.A.; Trescot, J.

    1995-12-31

    The volume of low-level radioactive waste can be reduced by the high temperature in a DC Graphite Arc Furnace. This volume reduction can take place with the additional benefit of having the solid residue being stabilized by the vitrified product produced in the process. A DC Graphite Arc Furnace is a simple system in which electricity is used to generate heat to vitrify the material and thermally decompose any organic matter in the waste stream. Examples of this type of waste are protective clothing, resins, and grit blast materials produced in the nuclear industry. The various Department of Energy (DOE) complexes produce similar low-level waste streams. Electro-Pyrolysis, Inc. and Svedala/Kennedy Van Saun are engineering and building small 50-kg batch and up to 3,000 kg/hr continuous feed DC furnaces for the remediation, pollution prevention, and decontamination and decommissioning segments of the treatment community. This process has been demonstrated under DOE sponsorship at several facilities and has been shown to produce stable waste forms from surrogate waste materials.

  10. Thermodynamic modelling of the formation of zinc-manganese ferrite spinel in electric arc furnace dust.

    PubMed

    Pickles, C A

    2010-07-15

    Electric arc furnace dust is generated when automobile scrap, containing galvanized steel, is remelted in an electric arc furnace. This dust is considered as a hazardous waste in most countries. Zinc is a major component of the dust and can be of significant commercial value. Typically, the majority of the zinc exists as zinc oxide (ZnO) and as a zinc-manganese ferrite spinel ((Zn(x)Mn(y)Fe(1-x-y))Fe(2)O(4)). The recovery of the zinc from the dust in metal recycling and recovery processes, particularly in the hydrometallurgical extraction processes, is often hindered by the presence of the mixed ferrite spinel. However, there is a paucity of information available in the literature on the formation of this spinel. Therefore, in the present research, the equilibrium module of HSC Chemistry 6.1 was utilized to investigate the thermodynamics of the formation of the spinel and the effect of variables on the amount and the composition of the mixed ferrite spinel. It is proposed that the mixed ferrite spinel forms due to the reaction of iron-manganese particulates with both gaseous oxygen and zinc, at the high temperatures in the freeboard of the furnace above the steel melt. Based on the thermodynamic predictions, methods are proposed for minimizing the formation of the mixed ferrite spinel.

  11. Steelmaking Slags

    NASA Astrophysics Data System (ADS)

    Li, Jin-yan; Zhang, Mei; Guo, Min; Yang, Xue-Min

    2014-10-01

    The phosphate-enrichment behavior has experimentally been investigated in CaO-SiO2-FeO-Fe2O3-P2O5 steelmaking slags. The reaction ability of structural units in the slags has been represented the mass action concentration from the developed ion and molecule coexistence theory (IMCT)- model based on the IMCT. The defined enrichment possibility and enrichment degree of solid solutions containing P2O5 from the developed IMCT- model have been verified from the experimental results. The effects of binary basicity, the mass percentage ratio , and mass percentage of P2O5 in the initial slags on phosphate-enrichment behavior in the slags has also been discussed. The results show that the P2O5 component can easily be bonded by CaO to form tricalcium phosphate 3 CaO·P2O5, and the formed 3CaO·P2O5 can react with the produced dicalcium silicate 2CaO·SiO2 to generate solid-solution 2CaO·SiO2-3CaO·P2O5 under fixed cooling conditions. The maximum value of the defined enrichment degree of solid-solution 2CaO·SiO2-3CaO·P2O5 is obtained as 0.844 under conditions of binary basicity as 2.5 and the mass percentage ratio as 0.955 at fixed cooling conditions.

  12. Steelworks residues and the Waelz kiln treatment of electric arc furnace dust

    SciTech Connect

    Strohmeier, G.; Bonestell, J.E.

    1996-04-01

    Electric arc furnace dust with a combined zinc and lead content in excess of 20% renders the dumping of this material impossible in many countries, for both statutory and financial reasons. In the Waelz process, dust is treated in a rotary kiln where it is heated to approximately 1,200 C. lead and zinc are volatilized under reducing conditions and collected as fine dust in the off-gas dust collection system. The oxide recovered in the off-gas filters contains approximately 55% Zn and up to 10% Pb, and is ideal feedstock for the Imperial Smelting furnace for lead/zinc recovery. The remaining slag is inert and unleachable so that it can be used as a building aggregate.

  13. Method for processing aluminum spent potliner in a graphite electrode ARC furnace

    SciTech Connect

    O'Connor, William K.; Turner, Paul C.; Addison, Gerald W.

    2002-12-24

    A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spent aluminum pot liner is crushed iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine and CO.

  14. Method for processing aluminum spent potliner in a graphite electrode arc furnace

    DOEpatents

    O'Connor, William K.; Turner, Paul C.; Addison, G.W.

    2002-12-24

    A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spend aluminum pot liner is crushed, iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine, and CO.

  15. Blast furnaces make way for new steel technology

    SciTech Connect

    Ondrey, G.; Parkinson, G.; Moore, S.

    1995-03-01

    Increasingly stringent environmental regulations, aging production units, and a competitive market are forcing iron and steelmakers to improve the environmental performance and cost efficiencies of their processes. The traditional integrated steel unit isn`t obsolete -- yet. Blast furnaces will be around for at least another 15 years. However, traditional technology is in for some changes, and stepped up rivalry from electric arc furnace minimills and ironmaking processes that use gas or coal. The paper discusses direct iron making processes, the DRI-minimill connection, the iron carbide process, and reclaiming iron from waste.

  16. 2. EXTERIOR VIEW LOOKING SOUTHEAST AT ELECTRIC FURNACE BUILDING AND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. EXTERIOR VIEW LOOKING SOUTHEAST AT ELECTRIC FURNACE BUILDING AND ELECTRIC FURNACE OFFICE & CHEMICAL LABORATORY BUILDING. INGOT MOLDS IN RIGHT FOREGROUND. - U.S. Steel Duquesne Works, Electric Furnace Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  17. Properties of steel foundry electric arc furnace dust solidified/stabilized with Portland cement.

    PubMed

    Salihoglu, Guray; Pinarli, Vedat; Salihoglu, Nezih Kamil; Karaca, Gizem

    2007-10-01

    Electric arc furnace dust from steel production is generated in considerable amounts worldwide and needs to be treated as hazardous waste. The aim of this study was to investigate the properties of electric arc furnace dust solidified/stabilized by using Portland cement. Mortar and paste samples were prepared with varying waste-to-binder ratios between 0% and 90%. A comprehensive experimental program was designed including XRF characterization, setting time, unconfined compressive strength, and toxicity characteristics leaching procedure (TCLP), synthetic precipitation leaching procedure (SPLP), and acid neutralization capacity (ANC) tests. The results were evaluated in order to determine if the solidified /stabilized product can be disposed of at a landfill site with domestic waste or at a segregated landfill. The effect of using sand on S/S performance was also investigated. The results indicated that the solidification /stabilization process using PC helps the heavy metals to be bound in the cement matrix, but the TCLP leaching results exceeded the EPA landfilling limits. The SPLP leaching results conformed to the limits implying that the waste or S/S products can be disposed of at a segregated landfill; however the low ANC of the S/S products reveals that there may be leaching in the long-term. The sand used in the mortar samples adversely affected the S/S performance, causing higher heavy metal leaching levels, and lower pH levels in the leachate after the TCLP extraction than those measured in the leachate of the paste samples.

  18. Waste Heat Recovery from High Temperature Off-Gases from Electric Arc Furnace

    SciTech Connect

    Nimbalkar, Sachin U; Thekdi, Arvind; Keiser, James R; Storey, John Morse

    2014-01-01

    This article presents a study and review of available waste heat in high temperature Electric Arc Furnace (EAF) off gases and heat recovery techniques/methods from these gases. It gives details of the quality and quantity of the sensible and chemical waste heat in typical EAF off gases, energy savings potential by recovering part of this heat, a comprehensive review of currently used waste heat recovery methods and potential for use of advanced designs to achieve a much higher level of heat recovery including scrap preheating, steam production and electric power generation. Based on our preliminary analysis, currently, for all electric arc furnaces used in the US steel industry, the energy savings potential is equivalent to approximately 31 trillion Btu per year or 32.7 peta Joules per year (approximately $182 million US dollars/year). This article describes the EAF off-gas enthalpy model developed at Oak Ridge National Laboratory (ORNL) to calculate available and recoverable heat energy for a given stream of exhaust gases coming out of one or multiple EAF furnaces. This Excel based model calculates sensible and chemical enthalpy of the EAF off-gases during tap to tap time accounting for variation in quantity and quality of off gases. The model can be used to estimate energy saved through scrap preheating and other possible uses such as steam generation and electric power generation using off gas waste heat. This article includes a review of the historical development of existing waste heat recovery methods, their operations, and advantages/limitations of these methods. This paper also describes a program to develop and test advanced concepts for scrap preheating, steam production and electricity generation through use of waste heat recovery from the chemical and sensible heat contained in the EAF off gases with addition of minimum amount of dilution or cooling air upstream of pollution control equipment such as bag houses.

  19. Diagnostics for a waste processing plasma arc furnace (invited) (abstract)a)

    NASA Astrophysics Data System (ADS)

    Woskov, P. P.

    1995-01-01

    Maintaining the quality of our environment has become an important goal of society. As part of this goal new technologies are being sought to clean up hazardous waste sites and to treat ongoing waste streams. A 1 MW pilot scale dc graphite electrode plasma arc furnace (Mark II) has been constructed at MIT under a joint program among Pacific Northwest Laboratory (PNL), MIT, and Electro-Pyrolysis, Inc. (EPI)c) for the remediation of buried wastes in the DOE complex. A key part of this program is the development of new and improved diagnostics to study, monitor, and control the entire waste remediation process for the optimization of this technology and to safeguard the environment. Continuous, real time diagnostics are needed for a variety of the waste process parameters. These parameters include internal furnace temperatures, slag fill levels, trace metals content in the off-gas stream, off-gas molecular content, feed and slag characterization, and off-gas particulate size, density, and velocity distributions. Diagnostics are currently being tested at MIT for the first three parameters. An active millimeter-wave radiometer with a novel, rotatable graphite waveguide/mirror antenna system has been implemented on Mark II for the measurement of surface emission and emissivity which can be used to determine internal furnace temperatures and fill levels. A microwave torch plasma is being evaluated for use as a excitation source in the furnace off-gas stream for continuous atomic emission spectroscopy of trace metals. These diagnostics should find applicability not only to waste remediation, but also to other high temperature processes such as incinerators, power plants, and steel plants.

  20. The efficiency of quartz addition on electric arc furnace (EAF) carbon steel slag stability.

    PubMed

    Mombelli, D; Mapelli, C; Barella, S; Gruttadauria, A; Le Saout, G; Garcia-Diaz, E

    2014-08-30

    Electric arc furnace slag (EAF) has the potential to be re-utilized as an alternative to stone material, however, only if it remains chemically stable on contact with water. The presence of hydraulic phases such as larnite (2CaO SiO2) could cause dangerous elements to be released into the environment, i.e. Ba, V, Cr. Chemical treatment appears to be the only way to guarantee a completely stable structure, especially for long-term applications. This study presents the efficiency of silica addition during the deslagging period. Microstructural characterization of modified slag was performed by SEM and XRD analysis. Elution tests were performed according to the EN 12457-2 standard, with the addition of silica and without, and the obtained results were compared. These results demonstrate the efficiency of the inertization process: the added silica induces the formation of gehlenite, which, even in caustic environments, does not exhibit hydraulic behaviour.

  1. Reduction Kinetics of Electric Arc Furnace Oxidizing Slag by Al-Fe Alloy

    NASA Astrophysics Data System (ADS)

    Lee, Jaehong; Oh, Joon Seok; Lee, Joonho

    2016-09-01

    Effects of temperature and slag basicity on the reduction rate of iron oxide in molten synthetic electric arc furnace oxidizing slag by Al-40 wt.%Fe alloy was investigated. An alloy sample was dropped into molten slag in an MgO crucible. When the initial slag temperature was 1723 K, there was no reduction. However, when the initial slag temperature was 1773 K and the slag basicity was 1.1, the reduction was initiated and the temperature of the slag rapidly increased. When the slag basicity was 1.1, increasing the initial slag temperature from 1773 K to 1823 K increases the reaction rate. As the slag basicity increased from 1.1 to 1.4 at 1773 K, the reaction rate increased. From SEM analysis, it was found that an Al2O3 or a spinel phase at the slag-metal interface inhibited the reaction at a lower temperature and a lower slag basicity.

  2. Modeling of zinc solubility in stabilized/solidified electric arc furnace dust.

    PubMed

    Fernández-Olmo, Ignacio; Lasa, Cristina; Irabien, Angel

    2007-06-18

    Equilibrium models which attempt for the influence of pH on the solubility of metals can improve the dynamic leaching models developed to describe the long-term behavior of waste-derived forms. In addition, such models can be used to predict the concentration of metals in equilibrium leaching tests at a given pH. The aim of this work is to model the equilibrium concentration of Zn from untreated and stabilized/solidified (S/S) electric arc furnace dust (EAFD) using experimental data obtained from a pH-dependence leaching test (acid neutralization capacity, ANC). EAFD is a hazardous waste generated in electric arc furnace steel factories; it contains significant amounts of heavy metals such as Zn, Pb, Cr or Cd. EAFD from a local factory was characterized by X-ray fluorescence (XRF), acid digestion and X-ray diffraction (XRD). Zn and Fe were the main components while the XRD analysis revealed that zincite, zinc ferrite and hematite were the main crystalline phases. Different cement/EAFD formulations ranging from 7 to 20% dry weight of cement were prepared and subjected to the ANC leaching test. An amphoteric behavior of Zn was found from the pH dependence test. To model this behavior, the geochemical model Visual MINTEQ (VMINTEQ) was used. In addition to the geochemical model, an empirical model based on the dissolution of Zn in the acidic zone and the re-dissolution of zinc compounds in the alkaline zone was considered showing a similar prediction than that obtained with VMINTEQ. This empirical model seems to be more appropriate when the metal speciation is unknown, or when if known, the theoretical solid phases included in the database of VMINTEQ do not allow to describe the experimental data.

  3. Thermodynamic analysis of the selective carbothermic reduction of electric arc furnace dust.

    PubMed

    Pickles, C A

    2008-01-31

    Electric arc furnace (EAF) dust, which is produced as a result of the melting of automobile scrap in an electric arc furnace, contains considerable amounts of zinc and lead, which are of significant economic value. Typically, the other major components are iron oxide and calcium oxide with minor amounts of other metal oxides. In this research, a detailed thermodynamic study of the pyrometallurgical processing of the dust, using carbon as a reducing agent was performed. The SOLGASMIX solver of Outokumpu HSC Chemistry((R)) 5.1 was used to calculate the equilibrium composition under reducing conditions. The control input dust composition was as follows (in mass percent): 8.100% CaO, 8.250% 2CaO.SiO(2), 11.200% CaCO(3), 8.830% CaO.Fe(2)O(3), 7.840% Fe(3)O(4), 3.770% PbO, 38.150% ZnFe(2)O(4) and 13.860% ZnO. Selective reduction and separation of both the zinc and the lead as metallic vapours, from the iron, in oxide form, was examined. The separation of the zinc or the lead from the iron, was defined quantitatively in terms of the selectivity factor (logbeta) as follows. Equation [see the text] where the subscript symbols refer to the metal being present in gaseous (g), metallic solid (m), solid oxide (o) or metallic liquid (l) form, respectively. The standard calculations were performed for one hundred grams of dust at atmospheric pressure. The variables investigated were as follows; temperature in the range of 1273-1873K, reactant ratio (i.e. moles of carbon per gram of dust), dust composition, addition of inert gas and reduced total pressure. The calculated values were in reasonable agreement with those from previously published studies and also industrial results.

  4. Behavior of Zn and Fe Content in Electric Arc Furnace Dust as Submitted to Chlorination Methods

    NASA Astrophysics Data System (ADS)

    Santos, Felipe; Brocchi, Eduardo; Araújo, Victor; Souza, Rodrigo

    2015-08-01

    This work covers initially a general thermodynamics assessment regarding the zinc ferrite (ZnFe2O4) behavior toward direct and reducing chlorination. Then, the use of alternative chlorination agents were also theoretically appreciated, before a set of experiments has been carried out with industrial residue (electric arc furnace dust). Besides identifying zinc ferrite (95.4 pct), the XRD analysis indicated the presence of ZnO (4.6 pct). Therefore, the main objective of the present work is related to a theoretical (thermodynamics) and experimental (kinetics) evaluation of the mentioned residue chemical behavior as submitted to chlorination methods. Several characterization methods were used, such as X-ray diffraction, scanning electron microscopy, X-ray fluorescence, mass spectroscopy (ICP-MS), and energy-dispersive X-ray spectroscopy (EDS). It was observed that zinc was present, mostly, in the form of zinc ferrite (franklinite). The thermodynamics study revealed that Zn has a more susceptible behavior regarding the oxides conversion into chlorides. However, this tendency is not necessarily associated with a selective reaction, as showed for the chlorination in the presence of carbon, as both iron and zinc chlorides formation is feasible. The experimental results have indicated that some reaction systems can be further studied in order to identify operational conditions that enable selective formations. So, it was observed that for the calcium chloride reaction conducted at 1273 K (1000 °C) for 30 minutes, the iron content in the residue slightly increases (with 15 pct removal), whereas the zinc content decreases from 20 to 12 pct (53 pct removal), suggesting complementary studies where this possible selectivity could be even more determinant. Such results have also indicated that the direct action of chlorine at 1073 K (800 °C) allowed complete removal of zinc, followed by conversion in the order of 40 pct in iron. Therefore, a complementary investigation over

  5. Future Steelmaking Processes

    SciTech Connect

    Prof. R. J. Fruehan

    2004-09-20

    There is an increasing demand for an ironmaking process with lower capital cost, energy consumption and emissions than a blast furnace. It is the hypothesis of the present work that an optimized combination of two reasonable proven technologies will greatly enhance the overall process. An example is a rotary hearth furnace (RHF) linked to a smelter (e.g., AISI, HIsmelt). The objective of this research is to select promising process combinations, develop energy, materials balance and productivity models for the individual processes, conduct a limited amount of basic research on the processes and evaluate the process combinations. Three process combinations were selected with input from the industrial partners. The energy-materials and productivity models for the RHF, smelter, submerged arc furnace and CIRCOFER were developed. Since utilization of volatiles in coal is critical for energy and CO{sub 2} emission reduction, basic research on this topic was also conducted. The process models developed are a major product developed in this research. These models can be used for process evaluation by the industry. The process combinations of an RHF-Smelter and a simplified CIRCOFER-Smelter appear to be promising. Energy consumption is reduced and productivity increased. Work on this project is continuing using funds from other sources.

  6. Formation of the ZnFe2O4 phase in an electric arc furnace off-gas treatment system.

    PubMed

    Suetens, T; Guo, M; Van Acker, K; Blanpain, B

    2015-04-28

    To better understand the phenomena of ZnFe2O4 spinel formation in electric arc furnace dust, the dust was characterized with particle size analysis, X-ray fluorescence (XRF), electron backscatter diffraction (EBSD), and electron probe micro-analysis (EPMA). Different ZnFe2O4 formation reaction extents were observed for iron oxide particles with different particle sizes. ZnO particles were present as both individual particles and aggregated on the surface of larger particles. Also, the slag particles found in the off-gas were shown not to react with the zinc vapor. After confirming the presence of a ZnFe2O4 formation reaction, the thermodynamic feasibility of in-process separation - a new electric arc furnace dust treatment technology - was reevaluated. The large air intake and the presence of iron oxide particles in the off-gas were included into the thermodynamic calculations. The formation of the stable ZnFe2O4 spinel phase was shown to be thermodynamically favorable in current electric arc furnace off-gas ducts conditions even before reaching the post combustion chamber.

  7. Recovery of Zn from acid mine water and electric arc furnace dust in an integrated process.

    PubMed

    Carranza, Francisco; Romero, Rafael; Mazuelos, Alfonso; Iglesias, Nieves

    2016-01-01

    In this paper, the purification of acid mine water and the treatment of electric arc furnace dust (EAFD) are integrated into one process with the aim of recovering the Zn content of both effluent and waste. Zinc recovery can reduce the cost of their environmental management: purified acid mine water is discharged after removing all metals; EAFD ceases to be hazardous waste; and Zn is valorised. The process consists of the recovery of Zn as zinc oxide and its purification into commercial products. First, EAFD is leached with acid water and the dissolved metals are selectively precipitated as hydroxides. After EADF leaching, ferrous iron is bio-oxidized and Fe and Al are then precipitated; in the following stage, Cu, Ni, Co and Cd are cemented and finally Zn is precipitated as ZnO. In order to purify water that finally is discharged to a river, lime is used as the neutralizing agent, which results in a precipitate of mainly gypsum, MnO, and ZnO. From the impure zinc oxide produced, various alternatives for the attainment of commercial products, such as basic zinc carbonate and electrolytic zinc, are studied in this work.

  8. Turning waste into valuable resource: potential of electric arc furnace dust as photocatalytic material.

    PubMed

    Sapiña, M; Jimenez-Relinque, E; Castellote, M

    2014-10-01

    This paper explores the potential of a hazardous waste of difficult management, electric arc furnace dust (EAFD), as photocatalytic material. Starting from a real waste coming from a Spanish steel factory, chemical, mineralogical, and optical characterizations have been carried out. Direct trials on EAFD and mortar containing this waste have been performed to evaluate its potential as photocatalyst itself and within a cementitious material. The analysis of photocatalytic properties has been done by two different methods: degradation of NO x and degradation of rhodamine (RhB). As a result, it can be said that EAFD exhibited photocatalytic activity for both configurations with UV and visible light, having the mortar enhanced photocatalytic activity for NO x with respect to the EAFD itself. Additionally, in direct trials on the EAFD, it has been able to degrade RhB even in the dark, which has been attributed to transfer of electrons between the adsorbed RhB and the conduction band of some oxides in the dust.

  9. Leaching properties of electric arc furnace dust prior/following alkaline extraction.

    PubMed

    Orescanin, Visnja; Mikelić, Luka; Sofilić, Tahir; Rastovcan-Mioc, Alenka; Uzarević, Krunoslav; Medunić, Gordana; Elez, Loris; Lulić, Stipe

    2007-02-15

    This study was carried out to determine the appropriate treatment of electric arc furnace (EAF) dust prior to permanent disposal. The total heavy metal content as well as heavy metal leaching from EAF dust was investigated in five composite samples obtained from three Croatian and Slovenian steelworks. In order to recover zinc and reduce its leaching from the dust, all five samples were submitted to alkaline extraction with 10 M NaOH. Reduction of Cr (VI) to Cr(III) was conducted using FeSO4 x 7H2O solution. The elements Mn, Fe, Cu, Ni, and notably Zn and Pb, exhibited highest mobility during toxicity characteristic leaching procedure (TCLP). Comparing to TCLP extracts of initial EAF dust, zinc was found to be over 15 times lower and lead over 200 times lower in TCLP extracts of EAF dust processed by the alkaline leaching method. Since Cr (VI) exceeded its permissible level in the DIN 38414-S4 extracts of both initial and alkaline digested dust, its reduction to Cr (III) prior to permanent disposal is necessary. The recovery of zinc from EAF dust treated with alkaline agent ranged from 50.3% to 73.2%. According to phase analysis, recovery yield showed dependence on zincite/franklinite ratio. The results of the study indicate that permanent disposal of EAF dust require the following procedure: alkaline digestion (followed by leachate purification and alkaline zinc electrolyses), chromate reduction (if necessary), solidification of leaching residue and its testing using the leaching analyses.

  10. Effect of electric arc furnace slag on growth and physiology of maize (Zea mays L.).

    PubMed

    Radić, Sandra; Crnojević, Helena; Sandev, Dubravka; Jelić, Sonja; Sedlar, Zorana; Glavaš, Katarina; Pevalek-Kozlina, Branka

    2013-12-01

    Basic slag, used in this study as a potential source of certain nutrients, is a byproduct of the production of steel in electric arc furnace (EAF). A pot experiment with two nutrient-poor substrates was conducted to investigate to compare the effect of EAF steel slag and fertilizers NPK + F e on growth and availability of specific nutrients to maize. Mineral content of both substrate and plant leaves, growth, chlorophyll fluorescence and photosynthetic pigments were measured following six weeks of cultivation. As steel slag also contains trace amounts of heavy metals, certain oxidative parameters (antioxidative enzyme activities and lipid peroxidation) were evaluated as well. The steel slag improved soil mineral composition, increased above ground maize biomass by providing Fe, Mn, Mg, K and partly P and improved photosynthetic parameters. The potential phytotoxicity of EAF slag containing substrates was not determined as evaluated by MDA (malondialdehyde), GR (glutathione reductase) and APX (ascorbate peroxidase) levels. The obtained results show that EAF steel slag is comparable to NPK + F e in supplying nutrients for maize growth, indicating the potential of EAF steel slag as an inexpensive and non-phytotoxic nutrient supplier especially in poor soils.

  11. Experimental study of the mechanical stabilization of electric arc furnace dust using fluid cement mortars.

    PubMed

    Ledesma, E F; Jiménez, J R; Ayuso, J; Fernández, J M; Brito, J de

    2017-03-15

    This article shows the results of an experimental study carried out in order to determine the maximum amount of electric arc furnace dust (EAFD) that can be incorporated into fluid cement-based mortars to produce mechanically stable monolithic blocks. The leaching performance of all mixes was studied in order to classify them according to the EU Council Decision 2003/33/EC. Two mortars were used as reference and three levels of EAFD incorporation were tested in each of the reference mortars. As the incorporation ratio of EAFD/cement increases, the mechanical strength decreases. This is due to the greater EAFD/cement and water/cement ratios, besides the presence of a double-hydrated hydroxide of Ca and Zn (CaZn2(OH)6·2H2O) instead of the portlandite phase (Ca(OH)2) in the mixes made with EAFD, as well as non-hydrated tricalcium silicate. A mass ratio of 2:1 (EAFD: cement-based mortar) can be added maintaining a stable mechanical strength. The mechanical stabilization process also reduced the leaching of metals, although it was not able to reduce the Pb concentration below the limit for hazardous waste. The high amount of EAFD mechanically stabilized in this experimental study can be useful to reduce the storage volume required in hazardous waste landfills.

  12. Assessment of hexavalent chromium release in Malaysian electric arc furnace steel slag for fertilizer usage

    NASA Astrophysics Data System (ADS)

    Bankole, L. K.; Rezan, S. A.; Sharif, N. M.

    2014-03-01

    This study investigates the leaching of hexavalent chromium (Cr (VI)) from electric arc furnace steel slag as Cr (VI) is classified as human carcinogen. Batch leaching tests were performed for 16 days. The lixiviants used were alkaline, de-ionized and rain water. After 16 days, Cr (VI) was found to be highest in alkaline water (0.03 mg/L) and lowest in de-ionized water (0.01 mg/L). Besides the lixiviants used, slag stirring speed and liquid to solid ratio also affect Cr (VI) released. The experimental work was complimented with slag characterization using XRF, XRD and SEM/EDX analysis. The leaching process was also simulated via Factsage software to calculate isothermal pourbaix diagrams. The Cr (VI) released was low and below the threshold of 0.1 mg/L set for public water systems. Recycle the slag as fertilizer should be considered safe as it does not exceed the safety limit set for Cr (VI) dissolution.

  13. Environmental impacts of asphalt mixes with electric arc furnace steel slag.

    PubMed

    Milačič, Radmila; Zuliani, Tea; Oblak, Tina; Mladenovič, Ana; Ančar, Janez Šč

    2011-01-01

    Electric arc furnace (EAF) steel slag can be used as an alternative high-quality material in road construction. Although asphalts with slag aggregates have been recognized as environmentally acceptable, there is a lack of data concerning the potential leaching of toxic Cr(VI) due to the highly alkaline media of EAF slag. Leaching of selected water extractable metals from slag indicated elevated concentrations of total chromium and Cr(VI). To estimate the environmental impacts of asphalt mixes with slag, leachability tests based on diffusion were performed using pure water and salt water as leaching agents. Compact and ground asphalt composites with natural aggregates, and asphalt composites in which the natural aggregates were completely replaced by slag were prepared. The concentrations of total chromium and Cr(VI) were determined in leachates over a time period of 6 mo. After 1 and 6 mo, the concentrations of some other metals were also determined in the leachates. The results indicated that chromium in leachates from asphalt composites with the addition of slag was present almost solely in its hexavalent form. However, the concentrations were very low (below 25 μg L) and did not represent an environmental burden. The leaching of other metals from asphalt composites with the addition of slag was negligible. Therefore, the investigated EAF slag can be considered as environmentally safe substitute for natural aggregates in asphalt mixes.

  14. Integrated hydrometallurgical process for production of zinc from electric arc furnace dust in alkaline medium.

    PubMed

    Youcai, Z; Stanforth, R

    2000-12-30

    In this study, a novel and integrated hydrometallurgical process for the production of zinc powder from electric arc furnace (EAF) dust in alkaline medium is reported. The dust is firstly hydrolysed in water, and then fused in caustic soda at 350 degrees C for 1h, followed by leaching in alkaline solution in which both zinc and lead are effectively extracted. Zinc powder is then produced by electrowinning from the leach solution after the lead is selectively removed by precipitation using sodium sulphide as precipitant. The EAF dust tested contained 25% Zn, 1.8% Pb and 33% Fe. It was found that 38% of zinc and 68% of lead could be extracted from the dust when leached directly in caustic soda solution. Leaching of zinc increased to 80% when dust was directly fused with caustic soda followed by alkaline leaching. However, the leaching further increased to 95% when the dust was hydrolysed first with water before fusion. Zinc powder with a purity of 99.95% was then produced by electrowinning from the lead depleted solution. Stainless electrodes were used as both anode and cathode.

  15. Model of phosphorus precipitation and crystal formation in electric arc furnace steel slag filters.

    PubMed

    Claveau-Mallet, Dominique; Wallace, Scott; Comeau, Yves

    2012-02-07

    The objective of this study was to develop a phosphorus retention mechanisms model based on precipitation and crystallization in electric arc furnace slag filters. Three slag columns were fed during 30 to 630 days with a reconstituted mining effluent at different void hydraulic retention times. Precipitates formed in columns were characterized by X-ray diffraction and transmission electronic microscopy. The proposed model is expressed in the following steps: (1) the rate limiting dissolution of slag is represented by the dissolution of CaO, (2) a high pH in the slag filter results in phosphorus precipitation and crystal growth, (3) crystal retention takes place by filtration, settling and growth densification, (4) the decrease in available reaction volume is caused by crystal and other particulate matter accumulation (and decrease in available reaction time), and (5) the pH decreases in the filter over time if the reaction time is too low (which results in a reduced removal efficiency). Crystal organization in a slag filter determines its phosphorus retention capacity. Supersaturation and water velocity affect crystal organization. A compact crystal organization enhances the phosphorus retention capacity of the filter. A new approach to define filter performance is proposed: saturation retention capacity is expressed in units of mg P/mL voids.

  16. Characterization and leachability of electric arc furnace dust made from remelting of stainless steel.

    PubMed

    Laforest, Guylaine; Duchesne, Josée

    2006-07-31

    Electric arc furnace dust (EAFD) is a toxic waste product made in the remelting of scrap steel. The results of a Toxicity Characteristic Leaching Procedure (TCLP) conducted on a sample of EAFD originating from the remelting of stainless steel scrap showed that the total Cr and Cr (VI) liquor concentrations (9.7 and 6.1 mg/L, respectively) exceeded the Toxicity Characteristic Regulatory Level (TCRL). The EAFD showed a complex heterogeneous mineralogy with spinel minerals group predominance. A sequential extractions method has permitted the determination of the amount of available metals (potentially mobile component) from the EAFD as follows: Cr (3%), Ni (6%), Pb (49%) and Zn (40%). Solubility controls on Cr, Pb, Zn and Ni were identified in the EAFD. This means that the Cr, Pb, Zn and Ni concentrations in solution were controlled by the solubility of some phases from EAFD. The concentrations of Ni and Zn, which are metals not regulated by TCRL were below 0.41 and 1.3 mg/L, respectively. The solubility control on Pb was sufficient to decrease its concentration (<0.24 mg/L) to a level below the TCRL. However, the control on Cr was not sufficient to decrease its concentration (between 117 and 331 mg/L) to below the TCRL.

  17. Valorisation of electric arc furnace steel slag as raw material for low energy belite cements.

    PubMed

    Iacobescu, R I; Koumpouri, D; Pontikes, Y; Saban, R; Angelopoulos, G N

    2011-11-30

    In this paper, the valorisation of electric arc furnace steel slag (EAFS) in the production of low energy belite cements is studied. Three types of clinkers were prepared with 0 wt.% (BC), 5 wt.% (BC5) and 10 wt.% (BC10) EAFS, respectively. The design of the raw mixes was based on the compositional indices lime saturation factor (LSF), alumina ratio (AR) and silica ratio (SR). The clinkering temperature was studied for the range 1280-1400°C; firing was performed at 1380°C based on the results regarding free lime and the evolution of microstructure. In order to activate the belite, clinkers were cooled fast by blown air and concurrent crushing. The results demonstrate that the microstructure of the produced clinkers is dominated by belite and alite crystals, with tricalcium aluminate and tetracalcium-alumino-ferrite present as micro-crystalline interstitial phases. The prepared cements presented low early strength development as expected for belite-rich compositions; however the 28-day results were 47.5 MPa, 46.6 MPa and 42.8 MPa for BC, BC5 and BC10, respectively. These values are comparable with OPC CEMI 32.5 N (32.5-52.5 MPa) according to EN 197-1. A fast setting behaviour was also observed, particularly in the case of BC10, whereas soundness did not exceed 1mm.

  18. Steel foundry electric arc furnace dust management: stabilization by using lime and Portland cement.

    PubMed

    Salihoglu, Guray; Pinarli, Vedat

    2008-05-30

    The purpose of this study was to determine an appropriate treatment for steel foundry electric arc furnace dust (EAFD) prior to permanent disposal. Lime and Portland cement (PC)-based stabilization was applied to treat the EAFD that contains lead and zinc above the landfilling limits, and is listed by USEPA as hazardous waste designation K061 and by EU as 10 02 07. Three types of paste samples were prepared with EAFD content varying between 0 and 90%. The first type contained the EAFD and Portland cement, the second contained the EAFD, Portland cement, and lime, and the third contained the EAFD and lime. All the samples were subjected to toxicity characteristics leaching procedure (TCLP) after an air-curing period of 28 days. pH changes were monitored and acid neutralization capacity of the samples were examined. Treatment effectiveness was evaluated in terms of reducing the heavy metal leachability to the levels below the USEPA landfilling criteria. An optimum composition for the EAFD stabilization was formulated as 30% EAFD +35% lime +35% Portland cement to achieve the landfilling criteria. The pH interval, where the solubility of the heavy metals in the EAFD was minimized, was found to be between 8.2 and 9.4.

  19. Microwave treatment of electric arc furnace dust with PVC: dielectric characterization and pyrolysis-leaching.

    PubMed

    Al-Harahsheh, Mohammad; Kingman, Sam; Al-Makhadmah, Leema; Hamilton, Ian E

    2014-06-15

    Microwave treatment of electric arc furnace dust (EAFD) with poly(vinyl chloride) (PVC) was studied in this work. A comprehensive characterization of the dust as well as assessing the suitability of using the thermal de-chlorination of the common plastic (PVC) under inert atmosphere was carried out to assess the possibility of Zn and other heavy metals extraction (Pb and Cd) from EAFD. The dielectric and thermal properties of EAFD, PVC and their mixtures were measured. Once combined and heated the metal oxides present in the dust reacted with HCl released from PVC during thermal de-chlorination, forming metal chlorides which were subsequently recovered by leaching with water. It was found that zinc chloride could be almost completely recovered in the leaching stage, with the overall recovery of Zn reaching 97% when the EAFD:PVC ratio was 1:2. The investigation highlighted that franklinite, the most refractory mineral to leaching, was completely destroyed. The leaching residue was found to compose mainly of magnetite and hematite.

  20. Thermodynamic analysis of the selective chlorination of electric arc furnace dust.

    PubMed

    Pickles, C A

    2009-07-30

    The remelting of automobile scrap in an electric arc furnace (EAF) results in the production of a dust, which contains high concentrations of the oxides of zinc, iron, calcium and other metals. Typically, the lead and zinc are of commercial value, while the other metals are not worth recovering. At the present time, EAF dusts are treated in high temperature Waelz rotary kiln-type processes, where the lead and zinc oxides are selectively reduced and simultaneously reoxidized and a crude zinc oxide is produced. Another alternative processing route is selective chlorination, in which the non-ferrous metals are preferentially chlorinated to their gaseous chlorides and in this manner separated from the iron. In the present research, a detailed thermodynamic analysis of this chlorination process has been performed and the following factors were investigated; temperature, amount of chlorine, lime content, silica content, presence of an inert gas and the oxygen potential. High lead and zinc recoveries as gaseous chlorides could be achieved but some of the iron oxide was also chlorinated. Additionally, the calcium oxide in the dust consumes chlorine, but this can be minimized by adding silica, which results in the formation of stable calcium silicates. The optimum conditions were determined for a typical dust composition. The selectivities achieved with chlorination were lower than those for reduction, as reported in the literature, but there are other advantages such as the potential recovery of copper.

  1. 4. LOOKING SOUTHEAST INSIDE OF ELECTRIC FURNACE BUILDING ON GROUND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. LOOKING SOUTHEAST INSIDE OF ELECTRIC FURNACE BUILDING ON GROUND FLOOR OF CHARGING AISLE. VIEW OF 50 TON CAPACITY CHARGING BUCKET. - U.S. Steel Duquesne Works, Electric Furnace Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  2. 3. LOOKING WEST INSIDE ELECTRIC FURNACE BUILDING ON CHARGING FLOOR. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. LOOKING WEST INSIDE ELECTRIC FURNACE BUILDING ON CHARGING FLOOR. VIEW OF 7 1/2 TON CAPACITY ALLIANCE SIDE DOOR CHARGING MACHINE. - U.S. Steel Duquesne Works, Electric Furnace Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  3. 5. LOOKING SOUTHWEST INSIDE OF ELECTRIC FURNACE BUILDING ON GROUND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. LOOKING SOUTHWEST INSIDE OF ELECTRIC FURNACE BUILDING ON GROUND FLOOR OF POURING AISLE. VIEW OF THE NATION'S FIRST VACUUM DEGASSING UNIT (1956). - U.S. Steel Duquesne Works, Electric Furnace Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  4. 14. WESTERN VIEW OF INVERTED BASIC OXYGEN FURNACE No. 1 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    14. WESTERN VIEW OF INVERTED BASIC OXYGEN FURNACE No. 1 ON THE OPERATING FLOOR OF THE FURNACE AISLE IN THE BOP SHOP. - U.S. Steel Duquesne Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  5. 12. SOUTHWEST VIEW OF BASIC OXYGEN FURNACE No. 2 ON ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    12. SOUTHWEST VIEW OF BASIC OXYGEN FURNACE No. 2 ON THE OPERATING FLOOR OF THE FURNACE AISLE IN THE BOP SHOP - U.S. Steel Duquesne Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  6. 13. WESTERN VIEW OF INVERTED BASIC OXYGEN FURNACE No. 2 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    13. WESTERN VIEW OF INVERTED BASIC OXYGEN FURNACE No. 2 ON THE OPERATING FLOOR OF THE FURNACE AISLE IN THE BOP SHOP. - U.S. Steel Duquesne Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  7. 15. WESTERN VIEW OF INVERTED BASIC OXYGEN FURNACE No. 2 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    15. WESTERN VIEW OF INVERTED BASIC OXYGEN FURNACE No. 2 ON THE GROUND FLOOR OF THE FURNACE AISLE IN THE BOP SHOP. - U.S. Steel Duquesne Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  8. Identification and characterization of the atmospheric emission of polychlorinated naphthalenes from electric arc furnaces.

    PubMed

    Liu, Guorui; Zheng, Minghui; Du, Bing; Nie, Zhiqiang; Zhang, Bing; Hu, Jicheng; Xiao, Ke

    2012-09-01

    Electric arc furnaces (EAF) are well recognized as significant sources of dioxins. EAFs have also been speculated to be sources of polychlorinated naphthalenes (PCNs) due to the close correlation between dioxin and PCN formation. However, assessment on PCN emissions from EAFs has not been carried out. The primary aim of this preliminary study is to identify and characterize the atmospheric emission of PCNs from EAFs. In this preliminary study, stack gas samples from two typical EAFs with different scales (EAF-1, 160 t batch(-1); and EAF-2, 60 t batch(-1)) were collected by automatic isokinetic sampling technique, and PCN congeners in samples were analyzed by isotope dilution high-resolution gas chromatography combined with high-resolution mass spectrometry method. Emission concentrations of PCNs were 458 and 1,099 ng m(-3) for EAF-1 and EAF-2, respectively. The emission factors of PCNs to air were 21.6 and 30.1 ng toxic equivalent t(-1) for EAF-1 and EAF-2, respectively, which suggested that EAF is an important source of PCN release. With regard to the characteristics of PCNs from EAFs, lower chlorinated homologues were dominant. The PCN congeners comprised of CN27/30, CN52/60, CN66/67, and CN73 were the most abundant congeners for tetra-, penta-, hexa-, and hepta-chlorinated homologues, respectively. EAFs were identified to be an important PCN source, and the obtained data are useful for developing a PCN inventory. The congener profiles of PCNs presented here might provide helpful information for identifying the specific sources of PCNs emitted from EAFs.

  9. Preliminary Results from Electric Arc Furnace Off-Gas Enthalpy Modeling

    SciTech Connect

    Nimbalkar, Sachin U; Thekdi, Arvind; Keiser, James R; Storey, John Morse

    2015-01-01

    This article describes electric arc furnace (EAF) off-gas enthalpy models developed at Oak Ridge National Laboratory (ORNL) to calculate overall heat availability (sensible and chemical enthalpy) and recoverable heat values (steam or power generation potential) for existing EAF operations and to test ORNL s new EAF waste heat recovery (WHR) concepts. ORNL s new EAF WHR concepts are: Regenerative Drop-out Box System and Fluidized Bed System. The two EAF off-gas enthalpy models described in this paper are: 1.Overall Waste Heat Recovery Model that calculates total heat availability in off-gases of existing EAF operations 2.Regenerative Drop-out Box System Model in which hot EAF off-gases alternately pass through one of two refractory heat sinks that store heat and then transfer it to another gaseous medium These models calculate the sensible and chemical enthalpy of EAF off-gases based on the off-gas chemical composition, temperature, and mass flow rate during tap to tap time, and variations in those parameters in terms of actual values over time. The models provide heat transfer analysis for the aforementioned concepts to confirm the overall system and major component sizing (preliminary) to assess the practicality of the systems. Real-time EAF off-gas composition (e.g., CO, CO2, H2, and H2O), volume flow, and temperature data from one EAF operation was used to test the validity and accuracy of the modeling work. The EAF off-gas data was used to calculate the sensible and chemical enthalpy of the EAF off-gases to generate steam and power. The article provides detailed results from the modeling work that are important to the success of ORNL s EAF WHR project. The EAF WHR project aims to develop and test new concepts and materials that allow cost-effective recovery of sensible and chemical heat from high-temperature gases discharged from EAFs.

  10. Polychlorinated naphthalene (PCN) emissions from scrap processing steel plants with electric-arc furnaces.

    PubMed

    Odabasi, Mustafa; Dumanoglu, Yetkin; Kara, Melik; Altiok, Hasan; Elbir, Tolga; Bayram, Abdurrahman

    2017-01-01

    Polychlorinated naphthalene (PCN) emissions of scrap iron processing steel plants were explored by measuring concentrations in stack gases of five plants, in the atmosphere (n=11) at a site close to those plants, and in soil at several sites in the region (n=40) in Aliaga, Izmir, Turkey. Observed stack-gas Σ32PCN levels from the plants without scrap preheating (189±157ngNm(-3), average±SD, n=4) showed that they are substantial PCN emitting sources. Stack-gas Σ32PCN level for the plant with scrap preheating was considerably higher (1262ngNm(-3)). Similarly, Σ32PCN emission factor for this plant was substantially higher (11.9mgton(-1)) compared to those without scrap preheating (1.30±0.98mgton(-1)). Results have also suggested that the investigated steel plants emit large quantities of fugitive particle-phase PCNs. Measured soil Σ32PCN concentrations that are considered to be representative of the atmospheric levels were greatly variable in the region, ranging between 0.003 and 10.02μgkg(-1) (dry wt). Their spatial distribution showed that main PCN sources in the region were the iron-steel plants. Ambient air levels (1620±800pgm(-3)) were substantially higher than ones observed around the world and in the study area verifying that the steel plants with electric arc furnaces (EAFs) are important PCN sources. Investigation of possible mechanisms suggested that the combustion processes also contribute to emissions from EAFs in addition to evaporation of PCNs present in the scrap iron.

  11. Solidification/stabilisation of electric arc furnace waste using low grade MgO.

    PubMed

    Cubukcuoglu, B; Ouki, S K

    2012-02-01

    This study aims to evaluate the potential of low grade MgO (LGMgO) for the stabilisation/solidification (S/S) of heavy metals in steel electric arc furnace wastes. Relevant characteristics such as setting time, unconfined compressive strength (UCS) and leaching behaviour assessed by acid neutralisation capacity (ANC), monolithic and granular leaching tests were examined in light of the UK landfill Waste Acceptance Criteria (WAC) for disposal. The results demonstrated that all studied mix designs with Portland cement type 1 (CEM1) and LGMgO, CEM1-LGMgO 1:2 and 1:4 at 40% and 70% waste addition met the WAC requirements by means of UCS, initial and final setting times and consistence. Most of the ANC results met the WAC limits where the threshold pH values without acid additions were stable and between 11.9 and 12.2 at 28d. Granular leaching results indicate fixation of most of the metals at all mix ratios. An optimum ratio was obtained at CEM1-LGMgO 1:4 at 40% waste additions where none of the metals leaching exceeded the WAC limits and hence may be considered for landfill disposal. The monolithic leaching test results showed that LGMgO performed satisfactorily with respect to S/S of Zn, as the metal component present at the highest concentration level in the waste exhibited very little leaching and passed the leaching test requirement at all mix ratios studied. However, its performance with respect to Pb, Cd and Cr was less effective in reducing their leaching suggesting a higher cumulative rate under those leaching regimes.

  12. Long and short-term performance of a stabilized/solidified electric arc furnace dust.

    PubMed

    Pereira, C Fernández; Galiano, Y Luna; Rodríguez-Piñero, M A; Parapar, J Vale

    2007-09-30

    The application of class F fly ash, cement and lime to the Stabilization/Solidification (S/S) of electric arc furnace dust containing hazardous metals such as Zn, Pb, Cd, and Cr is described. The aim of the study was to determine the influence of the setting conditions during the S/S treatment and to know the behaviour of an aged solidified and stabilized waste. In order to determine the efficiency attained by the S/S process, USEPA TCLP, and other leaching tests have been accomplished. In addition, the compressive strength of the solidified waste at different times has been determined. In order to study the influence of the environmental conditions in which setting occurs, experiments were carried out with samples of the same composition, under different setting conditions: laboratory environment, stove at a temperature of 40-60 degrees C and setting in a hermetically sealed plastic bag at room temperature. All the samples were subjected to the TCLP test at 28 days, and the metal content of the resulting leachates was analysed. The results show that in some cases the setting conditions of the mixtures have a noticeable influence on the characteristics of the leachate. The evolution with time of some S/S solids, one month after their manufacture and more than 9 years after that has also been evaluated, by means of their leaching behaviour. The results obtained in this work have shown, in all the laboratory cured samples that the leachate pH decrease in the course of time, and consequently the leaching behaviour is in general worse. This could be due to the carbonation of the S/S solid and the subsequent loss of alkalinity.

  13. [Phosphorus adsorption and regeneration of electric arc furnace steel slag as wetland medium].

    PubMed

    Zhai, Li-hua; He, Lian-sheng; Xi, Bei-dou; Chen, Yue; Meng, Rui; Huo, Shou-liang; Liu, Hong-liang

    2008-12-01

    The long-term phosphorus (P) adsorption and retention capacities of electric arc furnace (EAF) steel slag materials derived from one batch and a 278-d column experiments with a synthetic P solution were compared. The investigations of the regeneration of the P adsorption capacity by water level decrease was conducted. It was revealed column experiment on a long-term basis can determine P saturation of EAF accurately. And the results can be used for realistic estimations of constructed wetland systems (CWS) longevity. EAF slag showed a high afinity for P, reaching a saturation value of 1.65 g/kg. Regeneration experiment of the P adsorbing capacity by this material showed that, after 4 weeks of water level decrease, EAF steel slag was able to increase its initial P adsorption capacity to 2.65 g/kg. A sequential P fractionation experiment was performed to quantify the proportion of P bound to mineral compounds in EAF. From the most loosely bound to the most strongly bound P fraction, P1 was associated with resin extractable (13%), Fe extractable (0.5 mol/L Na2CO3, 39%), Al extractable (0.1 mol/L NaOH, 21%), Ca extractable (1 mol/L HCl, 13%), and Ca in a stable residual pool (concentrated hot HCl, 14%). X-ray fluorescence analyses of EAF steel slag chemical composition revealed that the continuous application of a P solution resulted in 300% and 170% increases in K2O and P2O5, respectively. Al2O3 and FeO increased by 8%, while the portion of CaO remained unchanged. The investigated properties (P retention potential, regeneration of P adsorption, P fractionation) provide useful data about the suitability of slag material as a media for longterm P removal and dry-wet operation can improve P retention capacity of EAF to prolong the longevity of full-scale CWS.

  14. In vitro assessment of genotoxic effects of electric arc furnace dust on human lymphocytes using the alkaline comet assay.

    PubMed

    Garaj-Vrhovac, Vera; Orescanin, Visnja; Ruk, Damir; Gajski, Goran

    2009-02-15

    In vitro genotoxic effects of leachates of electric arc furnace dust (EAFD) on human peripheral lymphocytes, assessed prior and following the treatment with a strong alkaline solution were investigated using the alkaline comet assay. Prior and following the treatment, lymphocytes were incubated with leachate of EAFD for 6 and 24 hours at 37 degrees C. Negative controls were also included. Mean values of the tail lengths established in the samples treated with the leachate stemming from the original dust for 6 and 24 hours, were 15.70 microm and 16.78 microm, respectively, as compared to 12.33 microm found in the control sample. Slight, but significant increase in the tail length was also found with the dust treated with a strong alkaline solution (13.37 microm and 13.60 microm). In case of high heavy metal concentrations (the extract of the original furnace dust), the incubation period was revealed to be of significance as well. The obtained results lead to the conclusion that alkaline comet assay could be used as a rapid, sensitive and low-cost tool when assessing genotoxicity of various waste materials, such as leachates of the electric arc furnace dust.

  15. Investigations on phosphorus recovery and reuse as soil amendment from electric arc furnace slag filters.

    PubMed

    Bird, Simon C; Drizo, Aleksandra

    2009-11-01

    Electric arc furnace (EAF) steel slag has been identified as an effective filter material for the removal of phosphorus (P) from both point and non-point sources. To determine the feasibility of land-applying P saturated EAF steel slag this study was undertaken to investigate (i) saturated EAF steel slag material's potential as a P fertilizer or soil amendment and (ii) P desorption and metals leachate from saturated EAF steel slag material to surface runoff. Medicago sativa (alfalfa) was planted in a nutrient depleted washed sand media. Phosphorus was added either as saturated EAF steel slag or as a standard commercial phosphate fertilizer in order to assess the plant availability of the P from saturated EAF steel slag. Four different P application levels were tested: a low (20 lbs acre furrow slice(-1) (5.5 g P m(-3))) two medium (40 and 60 lbs. acre f.s.(-1) (11 and 16.5 g P m(-3))) and a high (120 lbs. acre f.s.(-1) (33 g P m(-3))). The above-ground biomass of half of the plants was harvested after 5 weeks and the second half at 10 weeks. All treatments regardless of the P source used showed high rates of germination. At the first harvest period (5 weeks) significantly higher above-ground biomass (p < 0.01) was seen at the 3 highest P amendment rates in treatments with triple super phosphate fertilizer (TSP) than with EAF steel slag. However, by the second harvest (10 weeks) only the highest amendment rate of TSP showed a significantly higher amount of biomass (p < 0.01), suggesting that EAF steel slag might be an effective slow release P source. In a second experiment, a rain simulator was used to assess desorption of DRP, TP and metals from a saturated and semi-saturated EAF steel slag. The results revealed that the total amounts of DRP and TP released to surface runoff from EAF steel slag were negligible when compared to the total quantities of P retained by this material. Overall the results from this study demonstrated that once the EAF steel slag filter

  16. Recycling of Malaysia's electric arc furnace (EAF) slag waste into heavy-duty green ceramic tile.

    PubMed

    Teo, Pao-Ter; Anasyida, Abu Seman; Basu, Projjal; Nurulakmal, Mohd Sharif

    2014-12-01

    Recently, various solid wastes from industry such as glass waste, fly ash, sewage sludge and slag have been recycled into various value-added products such as ceramic tile. The conventional solutions of dumping the wastes in landfills or incineration, including in Malaysia are getting obsolete as the annual huge amount of the solid wastes would boost-up disposal cost and may cause permanent damage to the flora and fauna. This recent waste recycling approach is much better and greener as it can resolve problems associated with over-limit storage of industrial wastes and reduce exploration of natural resources for ceramic tile to continuously sustain the nature. Therefore, in this project, an attempt was made to recycle electric arc furnace (EAF) slag waste, obtained from Malaysia's steel making industry, into ceramic tile via conventional powder compaction method. The research work was divided into two stages. The first stage was to evaluate the suitability of EAF slag in ceramic tile by varying weight percentage of EAF slag (40 wt.%, 50 wt.% and 60 wt.%) and ball clay (40 wt.%, 50 wt.% and 60 wt.%), with no addition of silica and potash feldspar. In the second stage, the weight percentage of EAF slag was fixed at 40 wt.% and the percentage of ball clay (30 wt.% and 40 wt.%), feldspar (10 wt.% and 20 wt.%) and silica (10 wt.% and 20 wt.%) added was varied accordingly. Results obtained show that as weight percentage of EAF slag increased up to 60 wt.%, the percentage of apparent porosity and water absorption also rose, with a reduction in tile flexural strength and increased porosity. On the other hand, limiting the weight percentage of EAF slag to 40 wt.% while increasing the weight percentage of ball clay led to a higher total percentage of anorthite and wollastonite minerals, resulting in higher flexural strength. It was found that introduction of silica and feldspar further improved the flexural strength due to optimization of densification process. The highest

  17. Physics-Based Modeling of Electric Operation, Heat Transfer, and Scrap Melting in an AC Electric Arc Furnace

    NASA Astrophysics Data System (ADS)

    Opitz, Florian; Treffinger, Peter

    2016-04-01

    Electric arc furnaces (EAF) are complex industrial plants whose actual behavior depends upon numerous factors. Due to its energy intensive operation, the EAF process has always been subject to optimization efforts. For these reasons, several models have been proposed in literature to analyze and predict different modes of operation. Most of these models focused on the processes inside the vessel itself. The present paper introduces a dynamic, physics-based model of a complete EAF plant which consists of the four subsystems vessel, electric system, electrode regulation, and off-gas system. Furthermore the solid phase is not treated to be homogenous but a simple spatial discretization is employed. Hence it is possible to simulate the energy input by electric arcs and fossil fuel burners depending on the state of the melting progress. The model is implemented in object-oriented, equation-based language Modelica. The simulation results are compared to literature data.

  18. Innovative Concept for the Recovery of Silver and Indium by a Combined Treatment of Jarosite and Electric Arc Furnace Dust

    NASA Astrophysics Data System (ADS)

    Wegscheider, S.; Steinlechner, S.; Leuchtenmüller, M.

    2017-02-01

    Industrial wastes such as slags, dust, or precipitation residues contain significant amounts of valuable metals like zinc, lead, and copper as well as precious metals like silver and indium. Nevertheless, a lot of these waste materials are not recycled, and therefore, many valuable metals end up being sent to landfills. Because of harmful components in the waste, it is often necessary to send it to specialized landfills for hazardous wastes, which leads to environmental problems as well as additional costs. Consequently, the recovery of the valuable metals from the residues represents a sensible task to decrease the negative impact on the environment and to reduce costs for maintaining a landfill. In addition, recycling helps to decrease the dependency from primary resources. The present study deals with the behavior of different metals in a pyro-metallurgical treatment for a mixture of jarosite and electric arc furnace dust with a special focus on indium and silver.

  19. Experimental evaluation of high performance base course and road base asphalt concrete with electric arc furnace steel slags.

    PubMed

    Pasetto, Marco; Baldo, Nicola

    2010-09-15

    The paper presents the results of a laboratory study aimed at verifying the use of two types of electric arc furnace (EAF) steel slags as substitutes for natural aggregates, in the composition of base course and road base asphalt concrete (BBAC) for flexible pavements. The trial was composed of a preliminary study of the chemical, physical, mechanical and leaching properties of the EAF steel slags, followed by the mix design and performance characterization of the bituminous mixes, through gyratory compaction tests, permanent deformation tests, stiffness modulus tests at various temperatures, fatigue tests and indirect tensile strength tests. All the mixtures with EAF slags presented better mechanical characteristics than those of the corresponding asphalts with natural aggregate and satisfied the requisites for acceptance in the Italian road sector technical standards, thus resulting as suitable for use in road construction.

  20. Innovative Concept for the Recovery of Silver and Indium by a Combined Treatment of Jarosite and Electric Arc Furnace Dust

    NASA Astrophysics Data System (ADS)

    Wegscheider, S.; Steinlechner, S.; Leuchtenmüller, M.

    2016-11-01

    Industrial wastes such as slags, dust, or precipitation residues contain significant amounts of valuable metals like zinc, lead, and copper as well as precious metals like silver and indium. Nevertheless, a lot of these waste materials are not recycled, and therefore, many valuable metals end up being sent to landfills. Because of harmful components in the waste, it is often necessary to send it to specialized landfills for hazardous wastes, which leads to environmental problems as well as additional costs. Consequently, the recovery of the valuable metals from the residues represents a sensible task to decrease the negative impact on the environment and to reduce costs for maintaining a landfill. In addition, recycling helps to decrease the dependency from primary resources. The present study deals with the behavior of different metals in a pyro-metallurgical treatment for a mixture of jarosite and electric arc furnace dust with a special focus on indium and silver.

  1. The influence of the structure of the metal load removal from liquid steel in electric arc furnaces

    NASA Astrophysics Data System (ADS)

    Pǎcurar, Cristina; Hepuť, Teodor; Crisan, Eugen

    2016-06-01

    One of the main technical and economic indicators in the steel industry and steel respectively the development it is the removal of liquid steel. This indicator depends on several factors, namely technology: the structure and the quality metal load, the degree of preparedness of it, and the content of non-metallic material accompanying the unit of drawing up, the technology for the elaboration, etc. research has been taken into account in drawing up steel electric arc furnace type spring EBT (Electric Bottom taping), seeking to load and removing components of liquid steel. Metal load has been composed of eight metal grades, in some cases with great differences in terms of quality. Data obtained were processed in the EXCEL spreadsheet programs and MATLAB, the results obtained being presented both graphically and analytically. On the basis of the results obtained may opt for a load optimal structure metal.

  2. Investigation of stabilization/solidification for treatment of electric arc furnace dust: Dynamic leaching of monolithic specimens

    SciTech Connect

    Laforest, Guylaine Duchesne, Josee

    2007-12-15

    Diffusion-controlled leaching of heavy metals (Cr, Ni, Pb and Zn) from electric arc furnace dust treated with ground granulated blast furnace slag (GGBFS) and with ordinary Portland cement (OPC) was evaluated. Monolithic specimens were evaluated under dynamic leaching conditions for 84 days with periodic leachant renewal. The influence of leaching time, nature of the leachant, binder type and the water/solid ratio of the monoliths were investigated. Results obtained showed both binders can immobilize heavy metals in the monoliths under dynamic leaching conditions, with cumulative quantity of leached metal under 0.138 mg (Cr). Alkaline leachant increased metal release from specimens and reducing the water/solid ratio of the monolith allowed for a decrease in the cumulative mass of metals leached. Chemical and mineralogical characterizations indicated that the metals were evenly distributed throughout the specimens for both binders. Decalcification was observed on the OPC monolith border following leaching. This decrease in Ca corresponded to an altered zone (20 {mu}m), identified by scanning electron microscopy. The GGBFS sample did not show an altered zone.

  3. Radically innovative steelmaking technologies

    NASA Astrophysics Data System (ADS)

    Szekely, Julian

    1980-09-01

    The steel industry is faced with serious problems caused by the increasing cost of energy, labor and capital and by tough overseas competition, employing new highly efficient process plants. The very high cost of capital and of capital equipment renders the construction of new green field site plants, exemplifying the best available technology economically unattractive. For this reason, over the long term the development radically innovative steelmaking technologies appears to be the only satisfactory resolution of this dilemma. The purpose of this article is to present a critical review of some of the radically innovative steelmaking technologies that have been proposed during the past few years and to develop the argument that these indeed do deserve serious consideration at the present time. It should be stressed, however, that these innovative technologies can be implemented only as part of a carefully conceived long range plan, which contains as a subset short term solutions, such as trigger prices improved investment credits, and so forth and intermediate term solutions, such as more extensive use of continuous casting, external desulfurization and selective modernization in general.

  4. Zn distribution and speciation in zinc-containing steelmaking wastes by synchrotron radiation induced μ-XRF and μ-XANES spectroscopy

    NASA Astrophysics Data System (ADS)

    Wang, Lihua; Huang, Yuying; Lu, Xiaoming

    2013-04-01

    Zinc is an important element in steelmaking industry not only for its impact on environment but also for its hazardous influence to steel production. Collecting information about the chemical association of zinc in zinc-containing steelmaking wastes is fundamental for monitoring its behavior during further treatment. In the work presented here, the spatial distribution, and chemical forms of zinc in accumulated particles of zinc-containing steelmaking wastes, including electric arc furnace dust (EAFD) and basic oxygen furnace OG sludge (BOF OG), have been investigated using synchrotron radiation induced μ-XRF and μ-XANES spectroscopy. Results of μ-XRF analysis showed that zinc distributed in two ways. One was shared with iron and its distribution showed a positive correlation with that of iron. The other was accumulated in some well-defined hot spots with high amount and its distribution showed negative correlation with that of iron. For EAFD, results of μ-XANES spectroscopy indicated that zinc was mainly present in the form of ZnFe2O4 within the whole particles no matter the spots with high or low zinc content. Whereas for BOF OG, ZnFe2O4 was the main constituent in well-defined hot spots while in other regions zinc was mainly in the form of zinc carbonate. These results indicated that chemical reaction between zinc and other components occurred during the formation of accumulated OG sludge particles. If the above findings could be confirmed by more systematic investigations, it will provide valuable information for treating and utilizing these metallurgical residues.

  5. 38. DETAIL OF COOLING WATER BOOSTER PUMP FOR OXYGEN FURNACES, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    38. DETAIL OF COOLING WATER BOOSTER PUMP FOR OXYGEN FURNACES, LANCES, AND FUME HOODS IN THE GAS WASHER PUMP HOUSE LOOKING EAST. - U.S. Steel Duquesne Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  6. A Kinetic Ladle Furnace Process Simulation Model: Effective Equilibrium Reaction Zone Model Using FactSage Macro Processing

    NASA Astrophysics Data System (ADS)

    Van Ende, Marie-Aline; Jung, In-Ho

    2017-02-01

    The ladle furnace (LF) is widely used in the secondary steelmaking process in particular for the de-sulfurization, alloying, and reheating of liquid steel prior to the casting process. The Effective Equilibrium Reaction Zone model using the FactSage macro processing code was applied to develop a kinetic LF process model. The slag/metal interactions, flux additions to slag, various metallic additions to steel, and arcing in the LF process were taken into account to describe the variations of chemistry and temperature of steel and slag. The LF operation data for several steel grades from different plants were accurately described using the present kinetic model.

  7. Emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans from stack gases of electric arc furnaces and secondary aluminum smelters.

    PubMed

    Lee, Wei-Shan; Chang-Chien, Guo-Ping; Wang, Lin-Chi; Lee, Wen-Jhy; Wu, Kuen-Yuh; Tsai, Perng-Jy

    2005-02-01

    This study investigates the emissions of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) from four electric arc furnaces (EAFs) and eight secondary aluminum smelters (secondary ALSs) in Taiwan. The mean PCDD/F International-Toxicity Equivalents (I-TEQ) concentrations in the stack gases of these EAFs and secondary ALSs are 0.28 ng I-TEQ/Nm3 (relative standard deviation [RSD]= 100%) and 3.3 ng I-TEQ/Nm3 (RSD = 260%), respectively. The high RSDs, especially for those obtained from secondary ALSs, could be caused by the intrinsic differences in their involved feeding materials, furnace operating conditions, and air pollution control devices. The mean I-TEQ emission factor of PCDD/Fs for EAFs (1.8 microg I-TEQ/tonne-feedstock) is lower than that for secondary ALSs (37 microg I-TEQ/tonne-feedstock). This result might be because the involved furnace temperatures for secondary ALSs (650-750 degrees C) are lower than those for EAFs (1600-1700 degrees C), resulting in the deterioration of the combustion condition, leading to the formation of PCDD/Fs during the industrial process. This study found that the total PCDD/F emissions from EAFs (20 g I-TEQ/yr) and secondary ALSs (18 g I-TEQ/yr) are approximately 27, 53, and approximately 24, 49 times higher than those from municipal solid waste incinerators (MSWIs; 0.74 g I-TEQ/yr) and medical waste incinerators (MWIs; 0.37 g I-TEQ/yr), respectively; while those are 44 and 40% of total PCDD/F emission from sinter plants (45 g I-TEQ/ yr), respectively. Considering a more stringent emission limit has been applied to waste incinerators (0.1 ng I-TEQ/Nm3) in Taiwan lately, the results suggest that the control of the emissions from metallurgical processes has become the most important issue for reducing the total PCDD/F emission from industrial sectors to the ambient environment.

  8. Steelmaking process control using remote ultraviolet atomic emission spectroscopy

    NASA Astrophysics Data System (ADS)

    Arnold, Samuel

    Steelmaking in North America is a multi-billion dollar industry that has faced tremendous economic and environmental pressure over the past few decades. Fierce competition has driven steel manufacturers to improve process efficiency through the development of real-time sensors to reduce operating costs. In particular, much attention has been focused on end point detection through furnace off gas analysis. Typically, off-gas analysis is done with extractive sampling and gas analyzers such as Non-dispersive Infrared Sensors (NDIR). Passive emission spectroscopy offers a more attractive approach to end point detection as the equipment can be setup remotely. Using high resolution UV spectroscopy and applying sophisticated emission line detection software, a correlation was observed between metal emissions and the process end point during field trials. This correlation indicates a relationship between the metal emissions and the status of a steelmaking melt which can be used to improve overall process efficiency.

  9. A novel hydrothermal method for zinc extraction and separation from zinc ferrite and electric arc furnace dust

    NASA Astrophysics Data System (ADS)

    Wang, Hui-gang; Li, Yang; Gao, Jian-ming; Zhang, Mei; Guo, Min

    2016-02-01

    A novel hydrothermal process was developed to extract zinc from pure zinc ferrite (ZnFe2O4) nanopowder and zinc-containing electric arc furnace (EAF) dust using hexahydrated ferric chloride (FeCl3·6H2O) as a decomposing agent. The effects of solid FeCl3·6H2O to ZnFe2O4 ratio by mass ( R F/Z), hydrothermal reaction temperature, and time on zinc extraction were systematically investigated. In the results, when the hydrothermal reaction is conducted at 150°C for 2 h with R F/Z of 15:20, the efficiency of zinc extraction from ZnFe2O4 reaches 97.2%, and the concentration of ferric ions (Fe3+) in the leaching solution is nearly zero, indicating a high selectivity for zinc. In addition, the zinc extraction efficiency from the EAF dust reaches 94.5% in the case of the hydrothermal reaction performed at 200°C for 10 h with the solid FeCl3·6H2O to EAF dust ratio by mass ( R F/EAF dust) of 15:10. Zinc and iron separation is achieved by adjusting the pH value of the leaching solution according to the different precipitation pH values of metal hydroxides.

  10. Evaluation of electric arc furnace-processed steel slag for dermal corrosion, irritation, and sensitization from dermal contact.

    PubMed

    Suh, Mina; Troese, Matthew J; Hall, Debra A; Yasso, Blair; Yzenas, John J; Proctor, Debora M

    2014-12-01

    Electric arc furnace (EAF) steel slag is alkaline (pH of ~11-12) and contains metals, most notably chromium and nickel, and thus has potential to cause dermal irritation and sensitization at sufficient dose. Dermal contact with EAF slag occurs in many occupational and environmental settings because it is used widely in construction and other industrial sectors for various applications including asphaltic paving, road bases, construction fill, and as feed for cement kilns construction. However, no published study has characterized the potential for dermal effects associated with EAF slag. To assess dermal irritation, corrosion and sensitizing potential of EAF slag, in vitro and in vivo dermal toxicity assays were conducted based on the Organisation for Economic Co-operation and Development (OECD) guidelines. In vitro dermal corrosion and irritation testing (OECD 431 and 439) of EAF slag was conducted using the reconstructed human epidermal (RHE) tissue model. In vivo dermal toxicity and delayed contact sensitization testing (OECD 404 and 406) were conducted in rabbits and guinea pigs, respectively. EAF slag was not corrosive and not irritating in any tests. The results of the delayed contact dermal sensitization test indicate that EAF slag is not a dermal sensitizer. These findings are supported by the observation that metals in EAF slag occur as oxides of low solubility with leachates that are well below toxicity characteristic leaching procedure (TCLP) limits. Based on these results and in accordance to the OECD guidelines, EAF slag is not considered a dermal sensitizer, corrosive or irritant.

  11. Inertization of pyrite cinders and co-inertization with electric arc furnace flue dusts by pyroconsolidation at solid state.

    PubMed

    Viñals, J; Balart, M J; Roca, A

    2002-01-01

    The viability of a pyroconsolidation process to render pyrite cinders inert and to co-inert pyrite cinders with a hazardous polymetallic residue such as electric arc furnace flue dusts (EAF) containing Pb, Cu, Zn, As, Cr, Ni and Mo were investigated. The effects of pyroconsolidation temperature (800-1200 degrees C), milling pyrite cinders and additions of both CaO and EAF on the resulting microstructure of the pellets were determined. The microstructural changes were then compared with the results of the standard leaching tests. Full inertization of pyrite cinders was achieved after milling to < 100 micron followed by a pelletization and pyroconsolidation process at a temperature of 1200 degrees C. This process also allows co-inertization of pyrite cinders with controlled additions of EAF (up to approximately to 10%). Following pyroconsolidation at 1200 degrees C, the metallic elements were inert components in the four main phases: traces of Cr in hematite; Cr, Cu, Zn and Ni in spinel-phase; traces of Cr and Zn in calcium ferrites; and Pb and traces of Cu, Zn and Ba in K-Ca-Al-Fe glassy silicate.

  12. Citotoxicity status of electroplating wastewater prior/after neutralization/purification with alkaline solid residue of electric arc furnace dust.

    PubMed

    Orescanin, Visnja; Kopjar, Nevenka; Durgo, Ksenija; Elez, Loris; Gustek, Stefica Findri; Colic, Jasna Franekic

    2009-02-15

    Toxicological safety of new procedure for the neutralisation/purification of wastewater originated from zinc plating facility was investigated. Wastewater was treated with alkaline solid residue-by-product of zinc recovery from electric arc furnace dust. For determination of cytotoxic potential of untreated and purified wastewater MTT test on HEp2 (human laryngeal carcinoma) and HeLa (human cervical carcinoma) cells lines and alkaline comet assay on human leukocytes were used. Then 100% of the sample as well as different dilutions were tested. Compared to negative control 100, 75 and 50% of the sample of untreated wastewater significantly decreased survival of both HEp2 and HeLa cell lines. In the presence of undiluted sample survival percentage of HeLa and HEp2 cells were only 2.3 and 0.3% respectively. Only undiluted purified wastewater showed slight but insignificant decrease of the survival of both cell lines. Even 0.5% of the sample of original electroplating wastewater exhibited significantly higher value of all comet assay parameters compared to negative control. There was no significant difference between negative control and purified wastewater for any of comet assay parameters. Significantly lower level of primary DNA damage recorded after treatment with purified water, even comparable with negative control, confirmed effectiveness of the purification process.

  13. Distribution of air and serum PCDD/F levels of electric arc furnaces and secondary aluminum and copper smelters.

    PubMed

    Lee, Ching-Chang; Shih, Tung-Seng; Chen, Hsiu-Ling

    2009-12-30

    Metallurgical processes, such as smelting, can generate organic impurities such as organic chloride chemicals, polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs). The objective of this study was to elucidate the serum PCDD/F levels of 134 workers and ambient air levels around electric arc furnaces (EAF), secondary copper smelters and secondary aluminum smelters (ALSs) in Taiwan. The highest serum PCDD/F levels were found in the ALSs workers (21.9 pg WHO-TEQ/g lipid), with lower levels in copper smelter workers (21.5 pg WHO-TEQ/g lipid), and the lowest in the EAF plant workers (18.8 pg WHO-TEQ/g lipid). This was still higher than the levels for residents living within 5 km of municipal waste incinerators (14.0 pg WHO-TEQ/g lipid). For ambient samples, the highest ambient air PCDD/F level was in the copper smelters (12.4 pg WHO-TEQ/Nm(3)), with lower levels in ALSs (7.2 pg WHO-TEQ/Nm(3)), and the lowest in the EAF industry (1.8 pg WHO-TEQ/Nm(3)). The congener profiles were consistent in serum and in air samples collected in the copper smelters, but not for ALSs and EAF. In secondary copper smelters, the air PCDD/Fs levels might be directly linked to the PCDD/Fs accumulated in the workers due to the exceedingly stable congener pattern of the PCDD/F emission.

  14. Application of alkaline solid residue of electric arc furnace dust for neutralization/purification of electroplating wastewaters.

    PubMed

    Elez, Loris; Orescanin, Visnja; Sofilic, Tahir; Mikulic, Nenad; Ruk, Damir

    2008-10-01

    The purpose of this work was development of an appropriate procedure for the neutralization/purification of electroplating wastewater (EWW) with alkaline solid residue (ASR) by-product of the alkaline extraction of zinc and lead from electric arc furnace dust (EAFD). Removal efficiency of ASR at optimum purification conditions (pH 8 and mixing time; 20 minutes) for the elements Pb, Cr (VI), Cr (III), Fe, Ni, Cu and Zn were 94.92%, 97.58%, 99.59%, 99.48%, 97.25% and 99.97%, respectively. The concentrations of all elements in the purified wastewater were significantly lower in relation to the upper permissible limit for wastewaters suitable for discharge into the environment. The remaining waste mud was regenerated in the strong alkaline medium and successfully applied once again for the neutralization/purification of EWW. Removal efficiencies of heavy metals accomplished with regenerated waste mud were comparable to these achieved by original ASR. Elemental concentrations in the leachates of the waste mud were in accordance with regulated values.

  15. Hydrometallurgical process for zinc recovery from electric arc furnace dust (EAFD). Part II: Downstream processing and zinc recovery by electrowinning.

    PubMed

    Tsakiridis, P E; Oustadakis, P; Katsiapi, A; Agatzini-Leonardou, S

    2010-07-15

    The characterization and the agitation leaching of electric arc furnace dust (EAFD) by diluted sulphuric acid have been studied in Part I, as a separate article. The aim of the present research work (Part II) is the development of a purification process of the leach liquor for the recovery of high-purity zinc by electrowinning. The proposed hydrometallurgical process consists of the following four (4) unit operations: (1) Removal of iron as easily filterable crystalline basic sulphate salt of the jarosite type, at atmospheric pressure, by chemical precipitation at pH: 3.5 and 95 degrees C. (2) Zinc solvent extraction by Cyanex 272 at pH: 3.5, T: 40 degrees C, with 25% extractant concentration. (3) Stripping of the loaded organic phase by zinc spent electrolyte (62.5 g/L Zn(2+)) at T: 40 degrees C with diluted H(2)SO(4) (3 mol/L). (4) Zinc electrowinning from sulphate solutions (at 38 degrees C) using Al as cathode and Pb as anode. The acidity of the electrolyte was fixed at 180 g/L H(2)SO(4), while the current density was kept constant at 500 A/m(2).

  16. Evaluation of ASD systems for electric arc furnace and argon oxygen decarburization refiner baghouse fans. Final report

    SciTech Connect

    1997-11-01

    Adjustable speed drive (ASD) control of the baghouse fans for Electric Arc Furnace (EAF) and Argon Oxygen Decarburization Vessel (AOD) can improve operations, reduce the degree of dust generation, and provide significant energy savings. The purpose of the project was to quantify the benefits, both in energy savings and other process improvements and to demonstrate the methodology of applying adjustable speed drives, to two baghouse fans from a system perspective. The report describes the approach to accomplishing the ASD equipment installation, the test procedure and methodology and provides the test results and economic return. The test results indicated that by using ASDs to control the extraction fan air flow for the EAF and AOD, the following benefits would be achieved on an annual basis: EAF annual energy savings, 267,929 kWh valued at $11,575; EAF dust reduction, overall, 2--3%; EAF dust reduction, during the flatbath period, 35%; and AOD annual energy savings, 1,443,078 kWh valued at $62,341.

  17. Aluminum Bronze Alloys to Improve the System Life of Basic Oxygen and Electric Arc Furnace Hoods, Roofs and Side Vents.

    SciTech Connect

    Lawrence C. Boyd Jr.; Dr. Vinod K. Sikka

    2006-12-29

    Energy Industries of Ohio was the lead organization for a consortium that examined the current situation involving the service life of electric arc and basic oxygen furnace hoods, roofs and side vents. Republic Engineered Products (REP), one of the project partners, installed a full-scale Al-Bronze “skirt” in their BOF at their Lorain OH facility, believed to be the first such installation of this alloy in this service. In 24 months of operation, the Al-Bronze skirt has processed a total of 4,563 heats, requiring only 2 shutdowns for maintenance, both related to physical damage to the skirt from operational mishaps. Yearly energy savings related to the REP facility are projected to be ~ 10 billion Btu's with significant additional environmental and productivity benefits. In recognition of the excellent results, this project was selected as the winner of the Ohio’s 2006 Governor’s Award for Excellence in Energy, the state’s award for outstanding achievements in energy efficiency.

  18. Study of The Maximum Uptake Capacity on Various Sizes of Electric Arc Furnace Slag in Phosphorus Aqueous Solutions

    NASA Astrophysics Data System (ADS)

    Afnizan, W. M. W.; Hamdan, R.; Othman, N.

    2016-07-01

    The high content of uncontrolled phosphorus concentration in wastewater has emerged as a major problem recently. The excessive amount of phosphorus that is originated from domestic waste, unproper treated waste from septic tanks, as well as agricultural activities have led to the eutrophication problem. Therefore, a laboratory experiment was initiated to evaluate the potential of the Electric Arc Furnace Slag (EAFS), a by-product waste from steel making industry in removing phosphorus concentrations in aqueous solutions. In this work several particle sizes ranging from (9.5-12.4 mm, 12.5-15.9 mm, 16.0-19.9 mm, 20.0-24.9 mm, 25-37.4 mm) with a known weight (20±0.28 g, 40±0.27 g, 60±0.30 g, 80±0.29 g and 100±0.38 g) were used to study the effect of different particle sizes towards phosphorus removal. Each particle size of EAFS was shaken in synthetic phosphorus solutions (10 mg/l, 20 mg/l, 30 mg/l, 40 mg/l and 50 mg/l) at a contact time of 2 hours. Final concentrations of phosphorus were sampled and the measurement was made using WESTCO Discrete Analyzer equipment. Results showed that the highest of the maximum uptake capacity of each EAFS particle size distribution achieved at 0.287, 0.313, 0.266, 0.241 and 0.25 mg/g as particle size range was varied from 9.5-12.4 mm to 25-37.4 mm. In conclusion, the maximum uptake capacity of each EAFS mostly was determined to occur at adsorbent weight of 20 to 40 g in most conditions.

  19. Looking east at the basic oxygen furnace building with gas ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking east at the basic oxygen furnace building with gas cleaning plants in foreground on the left and the right side of the furnace building. - U.S. Steel Edgar Thomson Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Braddock, Allegheny County, PA

  20. 11. SOUTHWEST VIEW OF BASIC OXYGEN FURNACES No. 1 AND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    11. SOUTHWEST VIEW OF BASIC OXYGEN FURNACES No. 1 AND No. 2 ON THE OPERATING FLOOR OF THE FURNACE AISLE IN THE BOP SHOP - U.S. Steel Duquesne Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  1. Hydrometallurgical recovery of zinc and lead from electric arc furnace dust using mononitrilotriacetate anion and hexahydrated ferric chloride.

    PubMed

    Leclerc, Nathalie; Meux, Eric; Lecuire, Jean Marie

    2002-04-26

    The purpose of this work was to study the feasibility at laboratory-scale of a new hydrometallurgical process for treating electric arc furnace dusts (EAFD). The proposed process is intended to extract zinc and lead from EAFD without destroying the iron oxides matrix. So, this material can be recycled by the steel industry. Independently of the origin of the samples, major mineralogical forms present in these wastes are Fe3O4, ZnO, ZnFe2O4 and PbOHCl. The proposed process consists of a hydrometallurgical treatment of wastes based on selective leaching of zinc and lead. Initially, a leaching is carried out utilizing a chelating agent, nitrilotriacetate anion (NTA3-), as the protonated form HNTA2-. Treatment of five EAFD samples for an hour at room temperature with a molar solution of reagent results in total leaching of the ZnO. In all cases the solubilized iron does not exceed 3 wt.%. The recovery of zinc and lead is performed by precipitation of metallic sulfides with a solution of Na2S4 sodium tetrasulfide 2M. These metallic sulfides can be used as metallurgical raw materials and the chelating reagent can be reused in the process after pH adjustment. The results of the normalized leaching test AFNOR X31-210 conducted on the leaching residues, shows that all the samples meet acceptance thresholds for hazardous wastes landfill. However, the residues contain a considerable amount of zinc as ZnFe2O4. The extraction of the zinc element requires the destruction of the ferrite structure. In this process, ZnFe2O4 is treated by FeCl3.6H2O. The reaction consists in a particle O2-/Cl- exchange allowing the recovery of zinc as ZnCl2 and iron as hematite Fe2O3. The separation of these products is accomplished by simple aqueous leaching. All of the zinc is extracted in a 8h treatment at 150 degrees C with a molar ratio FeCl3.6H2O/ZnFe2O4 equal to 10. Ultimate solid residues, which have been concentrated in iron, can be oriented towards the steel industry.

  2. Splash Distribution in Oxygen Steelmaking

    NASA Astrophysics Data System (ADS)

    Sabah, Shabnam; Brooks, Geoffrey

    2015-04-01

    The study of splashing is important in understanding oxygen steelmaking. Splashing creates large interfacial area between reacting surfaces and thereby directly affects the kinetics of steelmaking reactions. In the present cold modeling work, a study of splashing has been carried out for various lance heights and gas flow rates. Sampling of droplets has been done in both radial positions and vertical positions across the bath to investigate the effect of sampling positions in estimation of the droplet generation rate. A novel approach has been developed to estimate the droplet generation rate. The results of the study have been compared with previous investigations. Results show that positioning of sampling is a critical issue and can affect the estimation of droplets present in the emulsion. This study also demonstrates quantitatively how much the droplet generation rate is reduced when the cavity mode changes from splashing to penetrating for different Blowing numbers.

  3. A combined arc-melting and tilt-casting furnace for the manufacture of high-purity bulk metallic glass materials.

    PubMed

    Soinila, E; Pihlajamäki, T; Bossuyt, S; Hänninen, H

    2011-07-01

    An arc-melting furnace which includes a tilt-casting facility was designed and built, for the purpose of producing bulk metallic glass specimens. Tilt-casting was chosen because reportedly, in combination with high-purity processing, it produces the best fatigue endurance in Zr-based bulk metallic glasses. Incorporating the alloying and casting facilities in a single piece of equipment reduces the amount of laboratory space and capital investment needed. Eliminating the sample transfer step from the production process also saves time and reduces sample contamination. This is important because the glass forming ability in many alloy systems, such as Zr-based glass-forming alloys, deteriorates rapidly with increasing oxygen content of the specimen. The challenge was to create a versatile instrument, in which high purity conditions can be maintained throughout the process, even when melting alloys with high affinity for oxygen. Therefore, the design provides a high-vacuum chamber to be filled with a low-oxygen inert atmosphere, and takes special care to keep the system hermetically sealed throughout the process. In particular, movements of the arc-melting electrode and sample manipulator arm are accommodated by deformable metal bellows, rather than sliding O-ring seals, and the whole furnace is tilted for tilt-casting. This performance of the furnace is demonstrated by alloying and casting Zr(55)Cu(30)Al(10)Ni(5) directly into rods up to ø 10 mm which are verified to be amorphous by x-ray diffraction and differential scanning calorimetry, and to exhibit locally ductile fracture at liquid nitrogen temperature.

  4. 40 CFR 63.10680 - Am I subject to this subpart?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) National Emission Standards for Hazardous Air Pollutants for Area Sources: Electric Arc Furnace Steelmaking... this subpart if you own or operate an electric arc furnace (EAF) steelmaking facility that is an...

  5. 40 CFR 63.10680 - Am I subject to this subpart?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) National Emission Standards for Hazardous Air Pollutants for Area Sources: Electric Arc Furnace Steelmaking... this subpart if you own or operate an electric arc furnace (EAF) steelmaking facility that is an...

  6. 40 CFR 63.10680 - Am I subject to this subpart?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) National Emission Standards for Hazardous Air Pollutants for Area Sources: Electric Arc Furnace Steelmaking... this subpart if you own or operate an electric arc furnace (EAF) steelmaking facility that is an...

  7. 40 CFR 63.10680 - Am I subject to this subpart?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) National Emission Standards for Hazardous Air Pollutants for Area Sources: Electric Arc Furnace Steelmaking... this subpart if you own or operate an electric arc furnace (EAF) steelmaking facility that is an...

  8. 40 CFR 63.10680 - Am I subject to this subpart?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) National Emission Standards for Hazardous Air Pollutants for Area Sources: Electric Arc Furnace Steelmaking... this subpart if you own or operate an electric arc furnace (EAF) steelmaking facility that is an...

  9. Research and Analysis on the Physical and Chemical Properties of Molten Bath with Bottom-Blowing in EAF Steelmaking Process

    NASA Astrophysics Data System (ADS)

    Wei, Guangsheng; Zhu, Rong; Dong, Kai; Ma, Guohong; Cheng, Ting

    2016-10-01

    Bottom-blowing technology is widely adopted in electric arc furnace (EAF) steelmaking to promote the molten bath fluid flow, accelerate the metallurgical reaction, and improve the quality of molten steel. In this study, a water model experiment and a computational fluid dynamics model were established to investigate the effects of bottom-blowing gas flow rate on the fluid flow characteristics in the EAF molten bath. The results show that the interaction among the bottom-blowing gas streams influences the molten bath flow field, and increasing the bottom-blowing gas flow rate can accelerate the fluid flow and decrease the volume of the dead zone. Based on industrial application research, the physical and chemical properties of the molten bath with bottom-blowing were analyzed. Compared with traditional melting conditions without bottom-blowing, bottom-blowing technology demonstrates obvious advantages in promoting the heat transfer and metallurgical reactions in the molten bath. With the bottom-blowing arrangement, the dephosphorization and decarburization rates are accelerated, the contents of FeO and T. Fe in endpoint slag are decreased, and the endpoint carbon-oxygen equilibrium of molten steel is improved.

  10. Advances in chemical and physical properties of electric arc furnace carbon steel slag by hot stage processing and mineral mixing.

    PubMed

    Liapis, Ioannis; Papayianni, Ioanna

    2015-01-01

    Slags are recognised as a highly efficient, cost effective tool in the metal processing industry, by minimising heat losses, reducing metal oxidation through contact with air, removing metal impurities and protecting refractories and graphite electrodes. When compared to natural aggregates for use in the construction industry, slags have higher specific weight that acts as an economic deterrent. A method of altering the specific weight of EAFC slag by hot stage processing and mineral mixing, during steel production is presented in this article. The method has minimal interference with the production process of steel, even by limited additions of appropriate minerals at high temperatures. Five minerals are examined, namely perlite, ladle furnace slag, bauxite, diatomite and olivine. Measurements of specific weight are accompanied by X-ray diffraction (XRD) and fluorescence (XRF) analysis and scanning electron microscopy spectral images. It is also shown how altering the chemical composition is expected to affect the furnace refractory lining. Additionally, the process has been repeated for the most suitable mix in gas furnace and physical properties (FI, SI, LA, PSV, AAV, volume stability) examined. Alteration of the specific weight can result in tailoring slag properties for specific applications in the construction sector.

  11. Chemical profile identification of fugitive and confined particle emissions from an integrated iron and steelmaking plant.

    PubMed

    Hleis, Dany; Fernández-Olmo, Ignacio; Ledoux, Frédéric; Kfoury, Adib; Courcot, Lucie; Desmonts, Thérèse; Courcot, Dominique

    2013-04-15

    The aim of this study is to obtain the characteristic inorganic chemical profile of important particle sources identified in the integrated iron and steel process: sintering, blast furnace, steelmaking and desulfurization slag processing. A complete chemical and physical characterization program was developed: particle size distribution, chemical analysis, XRD, SEM-EDX and TGA/DTA. The sample collected from the sinter stack showed high levels of K and Cl(-), followed by Fe, NH4(+), Ca, Na and Pb. The profile of the dust samples taken from the sinter cake discharge zone was quite different, showing higher amounts of Fe, Ca and Al, and lower amounts of K, Cl(-), Na and Pb. Dust samples collected from the blast furnace (BF) and steelmaking cast house may be distinguished from each other based on the higher levels of Fe (hematite and magnetite) and lower levels of Ca, Zn and C (graphite) found in BF dust. High levels of Ca and Fe were found in samples taken from the desulfurization slag processing area. Such information can be useful for source apportionment studies at receptor sites that could be influenced by iron and steelmaking plant emissions.

  12. Examinations of the new direct smelting processes for iron and steelmaking. [ELRED process, INRED process, SKF Plasmasmelt process, McDowell-Wellman process, the direct converter smelting process

    SciTech Connect

    Moore, J.T.

    1982-06-01

    This paper discusses the need for a radical technological change in the production of iron and steel and suggests the salient features that should be addressed. Five new direct smelting steelmaking systems have been compared with blast furnace/basic oxygen furnace route. These are the ELRED process the INRED process, the SKF Plasmasmelt process, the McDowell-Wellman process, and a converter smelting process. 20 refs.

  13. Looking southwest toward the basic oxygen steelmaking plant from a ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking southwest toward the basic oxygen steelmaking plant from a neighborhodd in Braddock by Eleventh Street. - U.S. Steel Edgar Thomson Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Braddock, Allegheny County, PA

  14. Activated electric arc furnace slag as an effective and reusable Fenton-like catalyst for the photodegradation of methylene blue and acid blue 29.

    PubMed

    Nasuha, N; Ismail, S; Hameed, B H

    2017-03-14

    In this work, an activated electric arc furnace slag (A-EAFS) was investigated as an effective Fenton catalyst for the photodegradation of methylene blue (MB) and acid blue 29 (AB29). Fourier transform infrared spectroscopy and UV-visible absorption analyses indicated that A-EAFS offers additional Fe3O4 because of the changes in the iron oxide phase and the favorable response to visible light. It has been found that the highest degradation efficiency can reach up to 94% for MB under optimal conditions of 1 g L(-1) of A-EAFS, 20 mM H2O2, and pH 3. The optimal conditions for AB29 were 0.1 g L(-1) A-EAFS, 4 mM H2O2, and pH 3 to reach 98% degradation efficiency. Visible light enhanced the degradation of both dyes. In addition, A-EAFS, could be easily separated magnetically, exhibited good chemical stability after seven successive photodegradation cycles.

  15. Synthesis of TiO2 visible light catalysts with controllable crystalline phase and morphology from Ti-bearing electric arc furnace molten slag.

    PubMed

    Li, Yang; Liu, Lulu; Guo, Min; Zhang, Mei

    2016-09-01

    TiO2 visible light catalysts with different crystalline phases and morphologies were synthesized from titanium-bearing electric arc furnace molten slag (Ti-bearing EAF slag) by using a simple acidolysis process. The effects of the pH of the HCl solution, liquid to solid ratio (RL/S, HCl solution to the residue ratio, mL/g) and acidolysis time on the micro-morphology and crystalline phase of as-prepared TiO2 photocatalysts were systematically investigated. The results indicated that with decreasing pH in the HCl solution and increasing RL/S, the crystalline phase and micro-morphology of the obtained TiO2 nanostructures tended to transform from anatase type TiO2 with spherical nanoparticle structures to rutile type TiO2 with needle-like nanorod structures. The acidolysis time had little influence on the crystalline phase but great impact on the size of the obtained TiO2. The growth mechanism of TiO2 from Ti-bearing EAF slag during the acidolysis process was also discussed. In addition, the influence of RL/S on the photocatalytic properties of the synthesized nanostructured TiO2 was studied. The results showed that the photodegradation efficiency for Rhodamine B solution could reach 91.00% in 120min when the RL/S was controlled at 50:1.

  16. On the distribution and bonding environment of Zn and Fe in glasses containing electric arc furnace dust: a mu-XAFS and mu-XRF study.

    PubMed

    Pinakidou, F; Katsikini, M; Paloura, E C; Kavouras, P; Kehagias, Th; Komninou, Ph; Karakostas, Th; Erko, A

    2007-04-02

    We apply synchrotron radiation assisted X-ray fluorescence (SR-XRF), SR-XRF mapping as well as micro- and conventional X-ray absorption fine structure (mu-XAFS and XAFS) spectroscopies in order to study the bonding environment of Fe and Zn in vitrified samples that contain electric arc furnace dust from metal processing industries. The samples are studied in the as-cast state as well as after annealing at 900 degrees C. The SR-XRF results demonstrate that annealing does not induce any significant changes in the distribution of either Fe or Zn, in both the as-cast and annealed glasses. The mu-XAFS spectra recorded at the Fe-K and Zn-K edges reveal that the structural role of both Fe and Zn remains unaffected by the annealing procedure. More specifically, Fe forms both FeO(6) and FeO(4) polyhedra, i.e. acts as an intermediate oxide while Zn occupies tetrahedral sites.

  17. Characterisation of the sintering behaviour of Waelz slag from electric arc furnace (EAF) dust recycling for use in the clay ceramics industry.

    PubMed

    Quijorna, N; de Pedro, M; Romero, M; Andrés, A

    2014-01-01

    Waelz slag is an industrial by-product from the recovery of electric arc furnace (EAF) dust which is mainly sent to landfills. Despite the different chemical and mineralogical compositions of Waelz slag compared to traditional clays, previous experiments have demonstrated its potential use as a clay substitute in ceramic processes. Indeed, clayey products containing Waelz slag could improve mechanical and environmental performance, fixing most of the metallic species and moreover decreasing the release of some potential pollutants during firing. However, a deeper understanding of the complex phase transformations during its thermal treatment and the connection of this behaviour with the end properties is desirable in order to explain the role that is played by the Waelz slag and its potential contribution to the ceramic process. For this purpose, in the present study, the chemical, mineralogical, thermal and environmental behaviour of both (i) unfired powdered samples, and (ii) pressed specimen of Waelz slag fired up to different temperatures within the typical range of clay based ceramic production, has been studied. The effect of the heating temperature on the end properties of the fired samples has been assessed. In general, an increase of the firing temperature promotes sintering and densification of the products and decreases the open porosity and water absorption which also contributes to the fixation of heavy metals. On the contrary, an increase in the leaching of Pb, Cr and Mo from the fired specimens is observed. This can be attributed to the creation of Fe and Ca molybdates and chromates that are weakly retained in the alkali matrix. On the other side, at temperature above 950 °C a weight gain related to the emission of evolved gases is observed. In conclusion, the firing temperature of the ceramic process is a key parameter that affects not only the technical properties but also strongly affects the leaching behaviour and the process emissions.

  18. Metals purification by improved vacuum arc remelting

    DOEpatents

    Zanner, Frank J.; Williamson, Rodney L.; Smith, Mark F.

    1994-12-13

    The invention relates to improved apparatuses and methods for remelting metal alloys in furnaces, particularly consumable electrode vacuum arc furnaces. Excited reactive gas is injected into a stationary furnace arc zone, thus accelerating the reduction reactions which purify the metal being melted. Additionally, a cooled condensation surface is disposed within the furnace to reduce the partial pressure of water in the furnace, which also fosters the reduction reactions which result in a purer produced ingot. Methods and means are provided for maintaining the stationary arc zone, thereby reducing the opportunity for contaminants evaporated from the arc zone to be reintroduced into the produced ingot.

  19. Chemical characterization of atmospheric particles and source apportionment in the vicinity of a steelmaking industry.

    PubMed

    Almeida, S M; Lage, J; Fernández, B; Garcia, S; Reis, M A; Chaves, P C

    2015-07-15

    The objective of this work was to provide a chemical characterization of atmospheric particles collected in the vicinity of a steelmaking industry and to identify the sources that affect PM10 levels. A total of 94 PM samples were collected in two sampling campaigns that occurred in February and June/July of 2011. PM2.5 and PM2.5-10 were analyzed for a total of 22 elements by Instrumental Neutron Activation Analysis and Particle Induced X-ray Emission. The concentrations of water soluble ions in PM10 were measured by Ion Chromatography and Indophenol-Blue Spectrophotometry. Positive Matrix Factorization receptor model was used to identify sources of particulate matter and to determine their mass contribution to PM10. Seven main groups of sources were identified: marine aerosol identified by Na and Cl (22%), steelmaking and sinter plant represented by As, Cr, Cu, Fe, Ni, Mn, Pb, Sb and Zn (11%), sinter plant stack identified by NH4(+), K and Pb (12%), an unidentified Br source (1.8%), secondary aerosol from coke making and blast furnace (19%), fugitive emissions from the handling of raw material, sinter plant and vehicles dust resuspension identified by Al, Ca, La, Si, Ti and V (14%) and sinter plant and blast furnace associated essentially with Fe and Mn (21%).

  20. 1. LOOKING NORTH AT THE BASIC OXYGEN STEELMAKING PLANT. THE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. LOOKING NORTH AT THE BASIC OXYGEN STEELMAKING PLANT. THE FLUX HANDLING BUILDING IS ON THE RIGHT, THE MOULD CONDITIONING BUILDING IS IN THE CENTER, THE BASIC OXYGEN PROCESS (BOP) SHOP IS IN THE CENTER BACKGROUND, AND OPEN HEARTH No. 2 BUILDING IS ON THE LEFT. - U.S. Steel Duquesne Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  1. 76 FR 33274 - Agency Information Collection Activities; Submission to OMB for Review and Approval; Comment...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-08

    ... Request; NESHAP for Area Sources: Electric Arc Furnace Steelmaking Facilities (Renewal) AGENCY... electronic docket, go to http://www.regulations.gov . Title: NESHAP for Area Sources: Electric Arc Furnace.../Affected Entities: Owners or operators of electric arc furnace steelmaking facilities. Estimated Number...

  2. Innovations in steelmaking technology and hidden phosphorus flows.

    PubMed

    Matsubae, Kazuyo; Yamasue, Eiji; Inazumi, Tadahiro; Webeck, Elizabeth; Miki, Takahiro; Nagasaka, Tetsuya

    2016-01-15

    This article will outline the historical transition in the flow of phosphorus in steelmaking technology, and examine the current and future phosphorus flow in steel production and the peripheral steelmaking processes. History provides many instances of innovative changes in steelmaking processes driven by various issues associated with raw materials which emerged over time, such as supply, quality and cost issues. The major steel countries with a long history, including Sweden and Japan, have shown flexibility in their ability to adapt to the changes in the value of resources and geopolitical conditions over times, and have enacted survival resource utilization measures over many centuries, leading to improvements in their respective steelmaking processes. Considering these success stories, it stands to reason that the ideal state of steelmaking is one with a clear stance with regard to resource policy.

  3. High temperature furnace modeling and performance verifications

    NASA Technical Reports Server (NTRS)

    Smith, James E., Jr.

    1992-01-01

    Analytical, numerical, and experimental studies were performed on two classes of high temperature materials processing sources for their potential use as directional solidification furnaces. The research concentrated on a commercially available high temperature furnace using a zirconia ceramic tube as the heating element and an Arc Furnace based on a tube welder. The first objective was to assemble the zirconia furnace and construct parts needed to successfully perform experiments. The 2nd objective was to evaluate the zirconia furnace performance as a directional solidification furnace element. The 3rd objective was to establish a data base on materials used in the furnace construction, with particular emphasis on emissivities, transmissivities, and absorptivities as functions of wavelength and temperature. A 1-D and 2-D spectral radiation heat transfer model was developed for comparison with standard modeling techniques, and were used to predict wall and crucible temperatures. The 4th objective addressed the development of a SINDA model for the Arc Furnace and was used to design sample holders and to estimate cooling media temperatures for the steady state operation of the furnace. And, the 5th objective addressed the initial performance evaluation of the Arc Furnace and associated equipment for directional solidification. Results of these objectives are presented.

  4. High temperature furnace modeling and performance verifications

    NASA Technical Reports Server (NTRS)

    Smith, James E., Jr.

    1988-01-01

    Analytical, numerical and experimental studies were performed on two classes of high temperature materials processing furnaces. The research concentrates on a commercially available high temperature furnace using zirconia as the heating element and an arc furnace based on a ST International tube welder. The zirconia furnace was delivered and work is progressing on schedule. The work on the arc furnace was initially stalled due to the unavailability of the NASA prototype, which is actively being tested aboard the KC-135 experimental aircraft. A proposal was written and funded to purchase an additional arc welder to alleviate this problem. The ST International weld head and power supply were received and testing will begin in early November. The first 6 months of the grant are covered.

  5. Ferrosilicon smelting in a direct current furnace

    DOEpatents

    Dosaj, Vishu D.; May, James B.

    1992-12-29

    The present invention is a process for smelting ferrosilicon alloy. The process comprises adding a carbon source and tailings comprising oxides of silicon and iron to a substantially closed furnace. Heat is supplied to the furnace by striking a direct current arc between a cathode electrode and an anode functional hearth. In a preferred embodiment of the present invention, the cathode electrode is hollow and feed to the substantially closed furnace is through the hollow electrode.

  6. Ferrosilicon smelting in a direct current furnace

    DOEpatents

    Dosaj, V.D.; May, J.B.

    1992-12-29

    The present invention is a process for smelting ferrosilicon alloy. The process comprises adding a carbon source and tailings comprising oxides of silicon and iron to a substantially closed furnace. Heat is supplied to the furnace by striking a direct current arc between a cathode electrode and an anode functional hearth. In a preferred embodiment of the present invention, the cathode electrode is hollow and feed to the substantially closed furnace is through the hollow electrode. 1 figure.

  7. Understanding Characteristic of Abrasion of Refractory Lining Caused by Bath Oscillation in BOF Steelmaking

    NASA Astrophysics Data System (ADS)

    Li, Qiang; Li, Mingming; Kuang, S. B.; Zou, Zongshu

    2016-12-01

    This paper presents a numerical study of the refractory abrasion occurring widely inside basic oxygen furnace (BOF) steelmaking. The mechanism of refractory abrasion is examined numerically referring to the bath oscillation with regard to flows, turbulence and wall shear stress inside a BOF. The simulation results reveal that the refractory abrasion tends to occur on the wall region between the slag/atmosphere and slag/metal interfaces due to the oscillation of the bath in the blowing process, which generally promotes slag-line erosion. The decreased nozzle angle, and either increased lance height or operation pressure can lead to more serious refractory erosion that occurs more likely during the slag-making period in the operation of BOF.

  8. Growth promotion effect of steelmaking slag on Spirulina platensis

    NASA Astrophysics Data System (ADS)

    Nogami, R.; Tam, L. T.; Anh, H. T. L.; Quynh, H. T. H.; Thom, L. T.; Nhat, P. V.; Thu, N. T. H.; Hong, D. D.; Wakisaka, M.

    2016-04-01

    A growth promotion effect of steelmaking slag on Spirulina platensis M135 was investigated. The growth promotion effect was obtained that was 1.27 times greater than that obtained by the control by adding 500 mg L-1 of steelmaking slag and culturing for 60 days. The lipid content decreased in a concentration-dependent manner with steelmaking slag, whereas the carbohydrate content remained constant. The protein content of S. platensis M135 increased in a concentration-dependent manner with steelmaking slag when cultured at day 45. The superoxide dismutase activity of S. platensis M135 exhibited a decreasing trend in a time-dependent manner and an increasing trend in the control. The superoxide dismutase activity was lower than that of the control at day 1 but was higher at day 30. No genetic damage was observed up to 500 mg L-1 of steelmaking slag at 30 days of culture. Recovery from genetic damage was observed at 1,000 mg L-1 of steelmaking slag but not at higher concentrations.

  9. 40 CFR 63.10691 - Who implements and enforces this subpart?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Area Sources: Electric Arc Furnace Steelmaking Facilities Other Information and Requirements § 63.10691 Who implements...

  10. The future steelmaking industry and its technologies

    SciTech Connect

    Fruehan, R.J.; Paxton, H.W.; Giarratani, F.; Lave, L. |

    1995-01-01

    The objective of this report is to develop a vision of the future steelmaking industry including its general characteristics and technologies. In addition, the technical obstacles and research and development opportunities for commercialization of these technologies are identified. The report is being prepared by the Sloan Steel Industry Competitiveness Study with extensive input from the industry. Industry input has been through AISI (American Iron and Steel Institute), SMA (Steel Manufacturers Association) and contacts with individual company executives and technical leaders. The report identifies the major industry drivers which will influence technological developments in the industry for the next 5--25 years. Initially, the role of past drivers in shaping the current industry was examined to help understand the future developments. Whereas this report concentrates on future technologies other major factors such as national and international competition, human resource management and capital concerns are examined to determine their influence on the future industry. The future industry vision does not specify specific technologies but rather their general characteristics. Finally, the technical obstacles and the corresponding research and development required for commercialization are detailed.

  11. Levels of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and trace metals in the blood of nonoccupationally exposed residents living in the vicinity of a municipal solid waste incinerator and electric arc furnace.

    PubMed

    Chen, Yan-Min; Lin, Yuan-Chung; Wu, Tzi-Yi; Chang-Chien, Guo-Ping; Ma, Wen-Feng

    2010-06-01

    This study examines levels of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and trace metals in the blood of the nonoccupationally exposed residents living in the vicinity of municipal solid waste incinerators (MSWIs) and electric arc furnaces (EAFs). The analysis found that older females had higher concentrations of PCDD/Fs and older males had higher body mass index (BMI) values and higher concentrations of PCDD/Fs. Moreover, sex appeared to affect the levels of PCDD/Fs because, overall, females showed higher levels of PCDD/Fs. The results of a principal component analysis indicated that the characteristics of the blood were more similar to the characteristics of the stack flux gas in MSWIs than those in EAFs. When sex, age, and BMI values were taken into consideration, none of the factors appeared to significantly affect PCDD/F and trace metal blood levels. However, when participants were divided into eight categories and analyzed, it was found that sex was the most important factor affecting levels of trace metals in blood and that males had higher concentrations of Pb, Al, Cd, and Cu.

  12. Verification of Steelmaking Slags Iron Content Final Technical Progress Report

    SciTech Connect

    J.Y. Hwang

    2006-10-04

    The steel industry in the United States generates about 30 million tons of by-products each year, including 6 million tons of desulfurization and BOF/BOP slag. The recycling of BF (blast furnace) slag has made significant progress in past years with much of the material being utilized as construction aggregate and in cementitious applications. However, the recycling of desulfurization and BOF/BOP slags still faces many technical, economic, and environmental challenges. Previous efforts have focused on in-plant recycling of the by-products, achieving only limited success. As a result, large amounts of by-products of various qualities have been stockpiled at steel mills or disposed into landfills. After more than 50 years of stockpiling and landfilling, available mill site space has diminished and environmental constraints have increased. The prospect of conventionally landfilling of the material is a high cost option, a waste of true national resources, and an eternal material liability issue. The research effort has demonstrated that major inroads have been made in establishing the viability of recycling and reuse of the steelmaking slags. The research identified key components in the slags, developed technologies to separate the iron units and produce marketable products from the separation processes. Three products are generated from the technology developed in this research, including a high grade iron product containing about 90%Fe, a medium grade iron product containing about 60% Fe, and a low grade iron product containing less than 10% Fe. The high grade iron product contains primarily metallic iron and can be marketed as a replacement of pig iron or DRI (Direct Reduced Iron) for steel mills. The medium grade iron product contains both iron oxide and metallic iron and can be utilized as a substitute for the iron ore in the blast furnace. The low grade iron product is rich in calcium, magnesium and iron oxides and silicates. It has a sufficient lime value and

  13. Laboratory experiments on arc deflection and instability

    SciTech Connect

    Zweben, S.; Karasik, M.

    2000-03-21

    This article describes experiments on arc deflection instability carried out during the past few years at the Princeton University Plasma Physics Laboratory (PPPL). The approach has been that of plasma physicists interested in arcs, but they believe these results may be useful to engineers who are responsible for controlling arc behavior in large electric steel furnaces.

  14. Tube furnace

    DOEpatents

    Foster, Kenneth G.; Frohwein, Eugene J.; Taylor, Robert W.; Bowen, David W.

    1991-01-01

    A vermiculite insulated tube furnace is heated by a helically-wound resistance wire positioned within a helical groove on the surface of a ceramic cylinder, that in turn is surroundingly disposed about a doubly slotted stainless steel cylindrical liner. For uniform heating, the pitch of the helix is of shorter length over the two end portions of the ceramic cylinder. The furnace is of large volume, provides uniform temperature, offers an extremely precise programmed heating capability, features very rapid cool-down, and has a modest electrical power requirement.

  15. Tube furnace

    SciTech Connect

    Foster, K.G.; Frohwein, E.J.; Taylor, R.W.; Bowen, D.W.

    1990-12-31

    A vermiculite insulated tube furnace is heated by a helically-wound resistance wire positioned within a helical groove on the surface of a ceramic cylinder, that in turn is surroundingly disposed about a doubly slotted stainless steel cylindrical liner. For uniform heating, the pitch of the helix is of shorter length over the two end portions of the ceramic cylinder. The furnace is of large volume, provides uniform temperature, offers an extremely precise programmed heating capability, features very rapid cool-down, and has a modest electrical power requirement.

  16. Tube furnace

    SciTech Connect

    Foster, K.G.; Frohwein, E.J.; Taylor, R.W.; Bowen, D.W.

    1990-01-01

    A vermiculite insulated tube furnace is heated by a helically-wound resistance wire positioned within a helical groove on the surface of a ceramic cylinder, that in turn is surroundingly disposed about a doubly slotted stainless steel cylindrical liner. For uniform heating, the pitch of the helix is of shorter length over the two end portions of the ceramic cylinder. The furnace is of large volume, provides uniform temperature, offers an extremely precise programmed heating capability, features very rapid cool-down, and has a modest electrical power requirement.

  17. Furnace assembly

    DOEpatents

    Panayotou, Nicholas F.; Green, Donald R.; Price, Larry S.

    1985-01-01

    A method of and apparatus for heating test specimens to desired elevated temperatures for irradiation by a high energy neutron source. A furnace assembly is provided for heating two separate groups of specimens to substantially different, elevated, isothermal temperatures in a high vacuum environment while positioning the two specimen groups symmetrically at equivalent neutron irradiating positions.

  18. Furnace assembly

    DOEpatents

    Panayotou, N.F.; Green, D.R.; Price, L.S.

    A method of and apparatus for heating test specimens to desired elevated temperatures for irradiation by a high energy neutron source. A furnace assembly is provided for heating two separate groups of specimens to substantially different, elevated, isothermal temperatures in a high vacuum environment while positioning the two specimen groups symmetrically at equivalent neutron irradiating positions.

  19. Process for improving metal production in steelmaking processes

    DOEpatents

    Pal, Uday B.; Gazula, Gopala K. M.; Hasham, Ali

    1996-01-01

    A process and apparatus for improving metal production in ironmaking and steelmaking processes is disclosed. The use of an inert metallic conductor in the slag containing crucible and the addition of a transition metal oxide to the slag are the disclosed process improvements.

  20. Process for improving metal production in steelmaking processes

    DOEpatents

    Pal, U.B.; Gazula, G.K.M.; Hasham, A.

    1996-06-18

    A process and apparatus for improving metal production in ironmaking and steelmaking processes is disclosed. The use of an inert metallic conductor in the slag containing crucible and the addition of a transition metal oxide to the slag are the disclosed process improvements. 6 figs.

  1. Emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) from both of point and area sources of an electric-arc furnace-dust treatment plant and their impacts to the vicinity environments.

    PubMed

    Yu, Kuei-Min; Lee, Wen-Jhy; Tsai, Perng-Jy; Fang, Kenneth; Lin, Mark

    2010-08-01

    This study was set out to investigate emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) from both the stack (i.e., point source) and plant fugitives (i.e., area source) of an electric-arc furnace-dust treatment plant (EAFDTP) and their impact to the vicinity environments. The emission rate of the point source (2,360 ng I-TEQh(-1)) was determined directly by measuring PCDD/F concentrations of the stack flue gas. The emission rate of the area source (1,080 ng I-TEQ m(-2)h(-1)) was estimated by using the Industrial Sources Complex Short-Term (ISCST3) model based on concentrations measured at the downwind side of the plant. The mean emission factors of 785 and 893 ng I-TEQ ton(-1) ZnO were found for the point and area source, respectively. The above results suggest that the area source accounted for more than 50% of total PCDD/F emissions for the selected EAFDTP. The contribution of the point source to the atmospheric PCDD/F concentrations of the upwind site and downwind site of the EAFDTP were 0 and 0.27 fg I-TEQ Nm(-3), respectively. The contributions of the area source were 0.020 and 3.3 fg I-TEQ Nm(-3), respectively. The total contribution of the selected EAFDTP (including both the point and area sources) to the concentrations in both upwind and downwind side vicinities were all less than 10%. Finally, the impact of PCDD/F emissions from the selected EAFDTP to the vicinity atmospheric environments was discussed in the present study.

  2. Use Zircon-Ilmenite Concentrate in Steelmaking

    NASA Astrophysics Data System (ADS)

    Fedoseev, S. N.; Volkova, T. N.

    2016-08-01

    Market requirements cause a constant search for new materials and technologies, for their immediate use in increasing requirements for material and energy efficiency, as well as to the quality of steel. In practice, steel production in the tended recently of more stringent requirements for the chemical composition of the steel and its contamination by nonmetallic inclusions, gas and non-ferrous metals. The main ways of increasing of strength and performance characteristics fabricated metal products related to the profound and effective influence on the crystallizing metal structure by furnace processing of the melt with refining and modifying additives. It can be argued that the furnace processing of steel and iron chemically active metals (alkali-earth metals, rare-earth metals, and others.) is an integral part of modern production of high quality products and competitive technologies. Important condition for development of methods secondary metallurgy of steel is the use of relatively inexpensive materials in a variety of complex alloys and blends, allowing targeted control of physical and chemical state of the molten metal and, therefore, receive steel with improved performance. In this connection the development of modifying natural materials metallurgy technologies presented complex ores containing titanium and zirconium, is a very urgent task.

  3. 5. Photocopied August 1978. FRONT OF A HORRY ROTARY FURNACE, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. Photocopied August 1978. FRONT OF A HORRY ROTARY FURNACE, SHOWING INTERIOR ELECTRODES. THE RAW MATERIALS FOR CALCIUM CARBIDE PRODUCTION--LIMESTONE AND COKE--WERE FED BY HOPPERS PLACED BETWEEN THESE ELECTRODES INTO THE ELECTRIC ARC. THE REMOVABLE PLATES ON THE EXTERNAL CIRCUMSTANCE OF THE HORRY FURNACE ARE SHOWN ON THE FIRST THREE FURNACES. (M) - Michigan Lake Superior Power Company, Portage Street, Sault Ste. Marie, Chippewa County, MI

  4. AISI Direct Steelmaking Program. Final technical report

    SciTech Connect

    Aukrust, E.

    1994-08-01

    This final report deals with the results of a 5-yr project for developing a more energy-efficient, environmentally friendly, less costly process for producing hot metal than current coke ovens and blast furnaces. In the process, iron ore pellets are smelted in a foamy slag created by reaction of coal char with molten slag to produce CO. The CO further reacts with oxygen, which also reacts with coal volatile matter, to produce the heat necessary to sustain the endothermic reduction reaction. The uncombusted CO and H{sub 2} from the coal are used to preheat and prereduce hematite pellets for the most efficient use of the energy in the coal. Laboratory programs confirmed that the process steps worked. Pilot plant studies were successful. Economic analysis for a 1 million tpy plant is promising.

  5. 40 CFR 420.41 - Specialized definitions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... adding oxygen. (b) (c) The term electric arc furnace steelmaking means the production of steel principally from steel scrap and fluxes in refractory lined furnaces by passing an electric current...

  6. 40 CFR 420.41 - Specialized definitions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) (c) The term electric arc furnace steelmaking means the production of steel principally from steel scrap and fluxes in refractory lined furnaces by passing an electric current through the scrap or...

  7. 40 CFR 420.41 - Specialized definitions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) (c) The term electric arc furnace steelmaking means the production of steel principally from steel scrap and fluxes in refractory lined furnaces by passing an electric current through the scrap or...

  8. 40 CFR 420.41 - Specialized definitions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) (c) The term electric arc furnace steelmaking means the production of steel principally from steel scrap and fluxes in refractory lined furnaces by passing an electric current through the scrap or...

  9. AISI Direct Steelmaking Program. Annual technical report for year ending November 30, 1991

    SciTech Connect

    Aukrust, A.

    1992-01-01

    The Direct Steelmaking Program has completed the third year of research and development since cost-share funding was provided by the Department of Energy. The physical chemistry programs conducted by Carnegie Mellon University (CMU) and the Massachusetts Institute of Technology (MIT) have been completed. A pilot plant has been constructed and successfully operated at Universal, Pennsylvania, and construction of a new, two-zone vessel pilot plant has been completed and trial operation is underway. The success of the pilot plant operation coupled with the development of process models involving reaction rates, heat-transfer and fluid-flow rates, and mass and energy balances has led to a basic study of a 350,000 tonne per year demonstration plant that gives promise of being a low capital and operating cost alternative for ironmaking as compared to the coke oven, blast furnace process. It has the further advantages of ease of startup and shutdown, lower energy consumption, and modularity so that capacity can be adapted to need. The physical chemistry programs at CMU and MIT studied fundamental reactions among ore, coal, flux, slag, metal droplets, and the liquid metal bath. Work at CMU centered on slag foaming studies, coal devolatilization, dissolution of hematite and wustite pellets in bath smelting slags, reduction of FeO in slag by char, extent of reverse or depostcombustion reactions in postcombustion gases, and developing an overall smelting model.

  10. Maintaining vacuum furnaces

    SciTech Connect

    Kowalewski, J.

    2000-04-01

    A preventive maintenance program is essential for safe and consistent vacuum furnace operation. The program should be developed in cooperation with safety, maintenance, and furnace operators, implemented as soon as the furnace is commissioned, and adhered to throughout the life of the furnace. This article serves as an introduction to the topic of vacuum furnace preventive maintenance. Basic information about installing a new vacuum furnace also is provided.

  11. High temperature aircraft research furnace facilities

    NASA Technical Reports Server (NTRS)

    Smith, James E., Jr.; Cashon, John L.

    1992-01-01

    Focus is on the design, fabrication, and development of the High Temperature Aircraft Research Furnace Facilities (HTARFF). The HTARFF was developed to process electrically conductive materials with high melting points in a low gravity environment. The basic principle of operation is to accurately translate a high temperature arc-plasma gas front as it orbits around a cylindrical sample, thereby making it possible to precisely traverse the entire surface of a sample. The furnace utilizes the gas-tungsten-arc-welding (GTAW) process, also commonly referred to as Tungsten-Inert-Gas (TIG). The HTARFF was developed to further research efforts in the areas of directional solidification, float-zone processing, welding in a low-gravity environment, and segregation effects in metals. The furnace is intended for use aboard the NASA-JSC Reduced Gravity Program KC-135A Aircraft.

  12. On-Line Flatness Measurement in the Steelmaking Industry

    PubMed Central

    Molleda, Julio; Usamentiaga, Rubén; Garcίa, Daniel F.

    2013-01-01

    Shape is a key characteristic to determine the quality of outgoing flat-rolled products in the steel industry. It is greatly influenced by flatness, a feature to describe how the surface of a rolled product approaches a plane. Flatness is of the utmost importance in steelmaking, since it is used by most downstream processes and customers for the acceptance or rejection of rolled products. Flatness sensors compute flatness measurements based on comparing the length of several longitudinal fibers of the surface of the product under inspection. Two main different approaches are commonly used. On the one hand, most mechanical sensors measure the tensile stress across the width of the rolled product, while manufacturing and estimating the fiber lengths from this stress. On the other hand, optical sensors measure the length of the fibers by means of light patterns projected onto the product surface. In this paper, we review the techniques and the main sensors used in the steelmaking industry to measure and quantify flatness defects in steel plates, sheets and strips. Most of these techniques and sensors can be used in other industries involving rolling mills or continuous production lines, such as aluminum, copper and paper, to name a few. Encompassed in the special issue, State-of-the-Art Sensors Technology in Spain 2013, this paper also reviews the most important flatness sensors designed and developed for the steelmaking industry in Spain. PMID:23939583

  13. Industrial furnace

    SciTech Connect

    Shostak, V.M.; Tolochko, A.I.; Volkov, V.P.; Maradudin, G.I.; Schekin, N.G.; Popov, M.I.; Shepelev, D.N.; Matveev, A.I.; Butnyakov, A.I.; Rzhavichev, A.P.

    1986-09-02

    An industrial furnace is described which consists of: a bath made of a refractory material for filling with a melt; a direct current source; main current-carrying elements having free ends extending to an operating area of the refractory material of the bath below and above the melt, and the main current-carrying elements extending to the operating area below the melt being connected with opposite terminals of the current source from the main current-carrying elements extending to the operating area above the melt; and additional current-carrying elements having free ends sunk in the refractory material of the bath below and above the melt and the additional current-carrying elements being connected with the terminals of the power source of opposite polarity with respect to the connection of the main current-carrying elements of a corresponding part of the operating area.

  14. Designing modern furnace cooling systems

    NASA Astrophysics Data System (ADS)

    Merry, J.; Sarvinis, J.; Voermann, N.

    2000-02-01

    An integrated multidisciplinary approach to furnace design that considers the interdependence between furnace cooling elements and other furnace systems, such as binding, cooling water, and instrumentation, is necessary to achieve maximum furnace production and a long refractory life. The retrofit of the BHP Hartley electric furnace and the Kidd Creek copper converting furnace are successful examples of an integrated approach to furnace cooling design.

  15. 40 CFR 63.10690 - What parts of the General Provisions apply to this subpart?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...: Electric Arc Furnace Steelmaking Facilities Other Information and Requirements § 63.10690 What parts of the... the scrap charged to an electric arc furnace at this facility are materials recovered for their... capture system for each electric arc furnace and argon-oxygen decarburization vessel that conveys...

  16. 40 CFR 63.10690 - What parts of the General Provisions apply to this subpart?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...: Electric Arc Furnace Steelmaking Facilities Other Information and Requirements § 63.10690 What parts of the... the scrap charged to an electric arc furnace at this facility are materials recovered for their... capture system for each electric arc furnace and argon-oxygen decarburization vessel that conveys...

  17. 40 CFR 63.10690 - What parts of the General Provisions apply to this subpart?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...: Electric Arc Furnace Steelmaking Facilities Other Information and Requirements § 63.10690 What parts of the... the scrap charged to an electric arc furnace at this facility are materials recovered for their... capture system for each electric arc furnace and argon-oxygen decarburization vessel that conveys...

  18. 40 CFR 63.10690 - What parts of the General Provisions apply to this subpart?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...: Electric Arc Furnace Steelmaking Facilities Other Information and Requirements § 63.10690 What parts of the... the scrap charged to an electric arc furnace at this facility are materials recovered for their... capture system for each electric arc furnace and argon-oxygen decarburization vessel that conveys...

  19. 40 CFR 63.10690 - What parts of the General Provisions apply to this subpart?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...: Electric Arc Furnace Steelmaking Facilities Other Information and Requirements § 63.10690 What parts of the... the scrap charged to an electric arc furnace at this facility are materials recovered for their... capture system for each electric arc furnace and argon-oxygen decarburization vessel that conveys...

  20. Arc distribution during the vacuum arc remelting of Ti-6Al-4V

    SciTech Connect

    Woodside, Charles Rigel; King, Paul E.; Nordlund, Chris

    2013-01-01

    Currently, the temporal distribution of electric arcs across the ingot during vacuum arc remelting (VAR) is not a known or monitored process parameter. Previous studies indicate that the distribution of arcs can be neither diffuse nor axisymmetric about the center of the furnace. Correct accounting for the heat flux, electric current flux, and mass flux into the ingot is critical to achieving realistic solidification models of the VAR process. The National Energy Technology Laboratory has developed an arc position measurement system capable of locating arcs and determining the arc distribution within an industrial VAR furnace. The system is based on noninvasive magnetic field measurements and a VAR specific form of the Biot–Savart law. The system was installed on a coaxial industrial VAR furnace at ATI Albany Operations in Albany, OR. This article reports on the different arc distributions observed during production of Ti-6Al-4V. It is shown that several characteristic arc distribution modes can develop. This behavior is not apparent in the existing signals used to control the furnace, indicating the measurement system is providing new information. It is also shown that the different arc distribution modes observed may impact local solidification times, particularly at the side wall.

  1. Arc Distribution During the Vacuum Arc Remelting of Ti-6Al-4V

    NASA Astrophysics Data System (ADS)

    Woodside, C. Rigel; King, Paul E.; Nordlund, Chris

    2013-02-01

    Currently, the temporal distribution of electric arcs across the ingot during vacuum arc remelting (VAR) is not a known or monitored process parameter. Previous studies indicate that the distribution of arcs can be neither diffuse nor axisymmetric about the center of the furnace. Correct accounting for the heat flux, electric current flux, and mass flux into the ingot is critical to achieving realistic solidification models of the VAR process. The National Energy Technology Laboratory has developed an arc position measurement system capable of locating arcs and determining the arc distribution within an industrial VAR furnace. The system is based on noninvasive magnetic field measurements and a VAR specific form of the Biot-Savart law. The system was installed on a coaxial industrial VAR furnace at ATI Albany Operations in Albany, OR. This article reports on the different arc distributions observed during production of Ti-6Al-4V. It is shown that several characteristic arc distribution modes can develop. This behavior is not apparent in the existing signals used to control the furnace, indicating the measurement system is providing new information. It is also shown that the different arc distribution modes observed may impact local solidification times, particularly at the side wall.

  2. Multiple model approach to evaluation of accelerated carbonation for steelmaking slag in a slurry reactor.

    PubMed

    Pan, Shu-Yuan; Liu, Hsing-Lu; Chang, E-E; Kim, Hyunook; Chen, Yi-Hung; Chiang, Pen-Chi

    2016-07-01

    Basic oxygen furnace slag (BOFS) exhibits highly alkaline properties due to its high calcium content, which is beneficial to carbonation reaction. In this study, accelerated carbonation of BOFS was evaluated under different reaction times, temperatures, and liquid-to-solid (L/S) ratios in a slurry reactor. CO2 mass balance within the slurry reactor was carried out to validate the technical feasibility of fixing gaseous CO2 into solid precipitates. After that, a multiple model approach, i.e., theoretical kinetics and empirical surface model, for carbonation reaction was presented to determine the maximal carbonation conversion of BOFS in a slurry reactor. On one hand, the reaction kinetics of BOFS carbonation was evaluated by the shrinking core model (SCM). Calcite (CaCO3) was identified as a reaction product through the scanning electronic microscopy and X-ray diffraction analyses, which provided the rationale of applying the SCM in this study. The rate-limiting step of carbonation was found to be ash-diffusion controlled, and the effective diffusivity for carbonation of BOFS in a slurry reactor were determined accordingly. On the other hand, the carbonation conversion of BOFS was predicted by the response surface methodology (RSM) via a nonlinear mathematical programming. According to the experimental data, the highest carbonation conversion of BOFS achieved was 57% under an L/S ratio of 20 mL g(-1), a CO2 flow rate of 0.1 L min(-1), and a pressure of 101.3 kPa at 50 °C for 120 min. Furthermore, the applications and limitations of SCM and RSM were examined and exemplified by the carbonation of steelmaking slags.

  3. Energy Balance Around Gas Injection into Oxygen Steelmaking

    NASA Astrophysics Data System (ADS)

    Sabah, Shabnam; Brooks, Geoffrey

    2016-02-01

    In the present work, a simplified approach of energy balance around gas injection into oxygen steelmaking has been carried out in a cold model. The aim is to provide an estimation of the amount of energy consumed by the different parts of the injection process such as dissipation, stirring of the bath, cavity formation, and splashing. Calculation of jet power used by different processes has been carried for various operating conditions and cavity modes ( i.e., splashing and penetrating). Calculations showed that dissipation and splashing are the dominant processes where most of the power of the jet is used, whereas cavity formation consumes the least amount. In the splashing mode, the percentage of total input power going into dissipation was about 59 to 63 pct, whereas it was found to be 2.6 to 50 pct in the penetrating mode. In splashing mode, about 30 pct power from the nozzle was used to create splash which is proved to be an efficient mode for droplet generation as less power is required to create droplets. At a certain lance height, the percentages of total input power used for splashing and dissipation were found equal. Below this lance height, all the cavities were found to be in penetrating mode. This simplified approach provides an improved understanding of the gas injection process and may be used for developing models of the injection process of steelmaking.

  4. Dephosphorization of Steelmaking Slag by Leaching with Acidic Aqueous Solution

    NASA Astrophysics Data System (ADS)

    Qiao, Yong; Diao, Jiang; Liu, Xuan; Li, Xiaosa; Zhang, Tao; Xie, Bing

    2016-09-01

    In the present paper, dephosphorization of steelmaking slag by leaching with acidic aqueous solution composed of citric acid, sodium hydroxide, hydrochloric acid and ion-exchanged water was investigated. The buffer solution of C6H8O7-NaOH-HCl system prevented changes in the pH values. Kinetic parameters including leaching temperature, slag particle size and pH values of the solution were optimized. The results showed that temperature has no obvious effect on the dissolution ratio of phosphorus. However, it has a significant effect on the dissolution ratio of iron. The dephosphorization rate increases with the decrease of slag particle size and the pH value of the solution. Over 90% of the phosphorus can be dissolved in the solution while the corresponding leaching ratio of iron was only 30% below the optimal condition. Leaching kinetics of dephosphorization follow the unreacted shrinking core model with a rate controlled step by the solid diffusion layer, the corresponding apparent activation energy being 1.233 kJ mol-1. A semiempirical kinetic equation was established. After leaching, most of the nC2S-C3P solid solution in the steelmaking slag was selectively dissolved in the aqueous solution and the iron content in the solid residue was correspondingly enriched.

  5. Heat treatment furnace

    SciTech Connect

    Seals, Roland D; Parrott, Jeffrey G; DeMint, Paul D; Finney, Kevin R; Blue, Charles T

    2014-10-21

    A furnace heats through both infrared radiation and convective air utilizing an infrared/purge gas design that enables improved temperature control to enable more uniform treatment of workpieces. The furnace utilizes lamps, the electrical end connections of which are located in an enclosure outside the furnace chamber, with the lamps extending into the furnace chamber through openings in the wall of the chamber. The enclosure is purged with gas, which gas flows from the enclosure into the furnace chamber via the openings in the wall of the chamber so that the gas flows above and around the lamps and is heated to form a convective mechanism in heating parts.

  6. Characteristics of Anorthite-Pyroxene Ceramics Made from Hot-Poured Steelmaking Slag

    NASA Astrophysics Data System (ADS)

    Li, Bowen; He, Mingsheng; Hwang, Jiann-Yang; Gan, Wangui

    2017-02-01

    Steelmaking slag is an alkaline byproduct generated from the steelmaking process. It consists mainly of oxides of calcium, iron, silicon, magnesium, and aluminum. It has a volumetric production in the steelmaking industry which has made a great impact on environment remediation. In this study, anorthite-pyroxene ceramic was prepared with hot-poured steelmaking slag, kaolin, and quartz with a sintering process. The ceramic products can be well sintered by heating at 1200°C, but they melted at 1300°C. The major mineral phases were anorthite, pyroxene, and spinel when sintering at 1150°C, while the characteristic peaks of belite, alite, and quartz in raw materials disappeared. The major mineral components of the ceramic become anorthite and pyroxene at 1200°C. The additional mixed wollastonite was involved in a sintering reaction when the temperature increased to 1200°C. The newly crystalized grains were uniformly formed and distributed.

  7. Optimization of a Steel Plant with Multiple Blast Furnaces Under Biomass Injection

    NASA Astrophysics Data System (ADS)

    Wiklund, Carl-Mikael; Pettersson, Frank; Saxén, Henrik

    2013-04-01

    The allocation of resources between several blast furnaces in an integrated steelmaking plant is studied with the aim of finding the lowest specific operation cost for steel production. In order to reduce the use of fossil fuels, biomass was considered as an auxiliary reductant in the furnace after partial pyrolysis in an external unit, as a complement to heavy fuel oil. The optimization considers raw material, energy, and emission costs and a possible credit for sold power and heat. To decrease computational requirements and to guarantee that the global optimum is found, a piecewise linearized model of the blast furnace was used in combination with linear models of the sinter-, coke-, and power plants, hot stoves, and basic oxygen furnace. The optimization was carried out under different constraints on the availability of some raw materials as well as for different efficiencies of the hot stoves of the blast furnaces. The results indicate that a non-uniform distribution of the production between the furnaces can be advantageous, and some surprising findings concerning the optimal resource allocation under constrained operation are reported.

  8. Role of prereduced pellets in the slag foaming in modern EAFs

    NASA Astrophysics Data System (ADS)

    Kozhukhov, A. A.

    2013-06-01

    The problems of electric arc furnace slags are considered, and the role of prereduced pellets in the slag foaming in electric arc furnaces is studied. The optimum rate of loading of prereduced pellets into a furnace that ensures effective steelmaking slag foaming is determined as a function of the degree of pellet prereduction.

  9. High-Gravity Carbonation Process for Enhancing CO2 Fixation and Utilization Exemplified by the Steelmaking Industry.

    PubMed

    Pan, Shu-Yuan; Chen, Yi-Hung; Chen, Chun-Da; Shen, Ai-Lin; Lin, Michael; Chiang, Pen-Chi

    2015-10-20

    The high-gravity carbonation process for CO2 mineralization and product utilization as a green cement was evaluated using field operation data from the steelmaking industry. The effect of key operating factors, including rotation speed, liquid-to-solid ratio, gas flow rate, and slurry flow rate, on CO2 removal efficiency was studied. The results indicated that a maximal CO2 removal of 97.3% was achieved using basic oxygen furnace slag at a gas-to-slurry ratio of 40, with a capture capacity of 165 kg of CO2 per day. In addition, the product with different carbonation conversions (i.e., 0%, 17%, and 48%) was used as supplementary cementitious materials in blended cement at various substitution ratios (i.e., 0%, 10%, and 20%). The performance of the blended cement mortar, including physicochemical properties, morphology, mineralogy, compressive strength, and autoclave soundness, was evaluated. The results indicated that the mortar with a high carbonation conversion of slag exhibited a higher mechanical strength in the early stage than pure portland cement mortar, suggesting its suitability for use as a high early strength cement. It also possessed superior soundness compared to the mortar using fresh slag. Furthermore, the optimal operating conditions of the high-gravity carbonation were determined by response surface models for maximizing CO2 removal efficiency and minimizing energy consumption.

  10. Electromelt furnace evaluation

    SciTech Connect

    Reimann, G.A.; Welch, J.M.

    1981-09-01

    An electromelt furnace was designed, built, and operated at the Idaho National Engineering Laboratory to demonstrate the suitability of this equipment for large-scale processing of radioactive wastes in iron-enriched basalt. Several typical waste compositions were melted and cast. The furnace was disassembled and the components evaluated. Calcines and fluorides attacked the furnace lining, unoxidized metals accumulated under the slag, and electrode attrition was high.

  11. Electromelt furnace evaluation

    NASA Astrophysics Data System (ADS)

    Reimann, G. A.; Welch, J. M.

    1981-09-01

    An electromelt furnace was designed, built and operated at the Idaho National Engineering Laboratory to demonstrate the suitability of this equipment for large-scale processing of radioactive wastes in iron-enriched basalt. Several typical waste compositions were melted and cast. The furnace was disassembled and the components evaluated. Calcines and fluorides attacked the furnace lining, unoxidized metals accumulated under the slag, and electrode attrition was high.

  12. EXTERIOR VIEW, BLAST FURNACE NO. 3 (JANE FURNACE) CENTER, NO. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    EXTERIOR VIEW, BLAST FURNACE NO. 3 (JANE FURNACE) CENTER, NO. 3 CAST HOUSE TO THE LEFT, WEST ORE BRIDGE TO THE RIGHT. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 3, Donner Avenue, Monessen, Westmoreland County, PA

  13. A Model for Dissolution of Lime in Steelmaking Slags

    NASA Astrophysics Data System (ADS)

    Sarkar, Rahul; Roy, Ushasi; Ghosh, Dinabandhu

    2016-08-01

    In a previous study by Sarkar et al. (Metall. Mater. Trans. B 46B:961 2015), a dynamic model of the LD steelmaking was developed. The prediction of the previous model (Sarkar et al. in Metall. Mater. Trans. B 46B:961 2015) for the bath (metal) composition matched well with the plant data (Cicutti et al. in Proceedings of 6th International Conference on Molten Slags, Fluxes and Salts, Stockholm City, 2000). However, with respect to the slag composition, the prediction was not satisfactory. The current study aims to improve upon the previous model Sarkar et al. (Metall. Mater. Trans. B 46B:961 2015) by incorporating a lime dissolution submodel into the earlier one. From the industrial point of view, the understanding of the lime dissolution kinetics is important to meet the ever-increasing demand of producing low-P steel at a low basicity. In the current study, three-step kinetics for the lime dissolution is hypothesized on the assumption that a solid layer of 2CaO·SiO2 should form around the unreacted core of the lime. From the available experimental data, it seems improbable that the observed kinetics should be controlled singly by any one kinetic step. Accordingly, a general, mixed control model has been proposed to calculate the dissolution rate of the lime under varying slag compositions and temperatures. First, the rate equation for each of the three rate-controlling steps has been derived, for three different lime geometries. Next, the rate equation for the mixed control kinetics has been derived and solved to find the dissolution rate. The model predictions have been validated by means of the experimental data available in the literature. In addition, the effects of the process conditions on the dissolution rate have been studied, and compared with the experimental results wherever possible. Incorporation of this submodel into the earlier global model (Sarkar et al. in Metall. Mater. Trans. B 46B:961 2015) enables the prediction of the lime dissolution rate

  14. Durable cathodes for high-power inert-gas arcs

    NASA Technical Reports Server (NTRS)

    Decker, A. J.; Gettleman, C. C.; Goldman, G. C.; Hall, J. H.; Pollack, J. L.

    1971-01-01

    Cathode design minimizes evaporation of electrode material which may deposit on associated optical surfaces. It also results in stable operation and precise positioning of arc relative to optical collector. Innovation applies to high power light sources and to arcs used in industrial furnaces.

  15. Simplified simulation of the transient behavior of temperatures in the upper shaft of the blast furnace

    SciTech Connect

    Saxen, H.

    1998-06-01

    The blast furnace is the principal process in the world for production of iron for primary steelmaking. The furnace acts as a huge countercurrent heat exchange and chemical reactor with complicated heat and mass transfer phenomena and chemical reactions. The flows of burden and gas in the blast furnace shaft strongly affect the fuel economy of the process. An optimal gas flow distribution, which is obtained by controlling the burden distribution, leads to a high utilization degree of the reducing gas, smooth burden descent, and little wear of the furnace lining. Here, a one-dimensional dynamic model of the upper part of the blast furnace shaft is applied to study the evolution of gas and burden temperatures, mainly in order to shed light on the transient phenomena after charging dumps of burden. The effects of irregularities in the burden descent and charging are also studied briefly. The simulations demonstrate that the temperatures of the burden layers in the lower part of the simulated region assume a quasi-steady state, indicating that the changes in the top gas temperature experienced immediately after a dump of burden arise primarily because of heat transfer between the gas and the dump. These results support the idea that such temporary changes can be interpreted in terms of distribution of the dumps on the burden surface.

  16. A Dynamic Flux Dissolution Model for Oxygen Steelmaking

    NASA Astrophysics Data System (ADS)

    Kadrolkar, Ameya; Andersson, Nils Å. I.; Dogan, Neslihan

    2017-02-01

    A modified model for prediction of flux dissolution in oxygen steelmaking process is presented in this study. The aim of this paper is to introduce a procedure for simulating the amount of dissolved lime with respect to the saturation concentration of CaO by coupling the existing thermodynamic and kinetic models simultaneously. The procedure is developed to calculate the saturation concentrations/solubility of CaO in slag using thermodynamic models namely FactSage™, Cell Model, and Thermo-Calc™. Total amount of dissolved lime is evaluated by integrating solubility values in the rate equation of lime dissolution over time taking into account the effects of physical properties and temperature of slag and particle size of flux additions and validated against industrial data available in literature. Comparison between measured and calculated undissolved lime shows a good agreement between them using any thermodynamic models even though there are some differences in the predictions of saturation concentration of CaO in slag. It has been shown that two distinct control mechanisms for lime dissolution in BOF slags exist and consideration of the free lime-controlled mechanism is essential for accurate prediction of dissolution rate of lime in slag.

  17. Some Aspects of Interfacial Phenomena in Steelmaking and Refining

    NASA Astrophysics Data System (ADS)

    Wang, L. J.; Viswanathan, N. N.; Muhmood, L.; Kapilashrami, E.; Seetharaman, S.

    2016-08-01

    Unique experiments were designed to study the surface phenomena in steelmaking reactions. The concept of surface sulfide capacities and an understanding of the surface accumulation of surface-active species, based on experimental results, are presented. In order to understand the flow phenomenon at slag/metal interface, experiments were designed to measure the interfacial velocity of S on the surface of an iron drop immersed in an aluminosilicate slag using the X-ray sessile drop method. The oscillation of the iron drop in the slag due to the change in the surface concentration of sulfur at the slag-metal interface was monitored by X-ray imaging. From the observations, the interfacial velocity of sulfur was evaluated. Similar experiments were performed to measure the interfacial velocity of oxygen at the interface as well as the impact of oxygen potential on the interfacial velocity of sulfur. The interfacial shear viscosity and the dilatational modulus were also evaluated. In a study of the wetting of alumina base by iron drop at constant oxygen pressure under isothermal condition, the contact angle was found to be decreased with the progress of the reaction leading to the formation of hercynite as an intermediate layer creating non-wetting conditions. In the case of silica substrate, an intermediate liquid fayalite layer was formed.

  18. INTERIOR VIEW SHOWING FURNACE KEEPER OBSERVING FURNACE THROUGH BLUE GLASS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW SHOWING FURNACE KEEPER OBSERVING FURNACE THROUGH BLUE GLASS EVERY TWENTY MINUTES TO DETERMINE SIZE AND TEXTURE OF BATCH AND OTHER VARIABLES. FAN IN FRONT COOLS WORKERS AS THEY CONDUCT REPAIRS. FURNACE TEMPERATURE AT 1572 DEGREES FAHRENHEIT. - Chambers-McKee Window Glass Company, Furnace No. 2, Clay Avenue Extension, Jeannette, Westmoreland County, PA

  19. General view of blast furnace plant, with blast furnace "A" ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    General view of blast furnace plant, with blast furnace "A" (built in 1907) to the left; in the foreground is the turbo-blower and blast furnace gas-powered electric generating station (built in 1919), looking northwest - Bethlehem Steel Corporation, South Bethlehem Works, Blast Furnace "A", Along Lehigh River, North of Fourth Street, West of Minsi Trail Bridge, Bethlehem, Northampton County, PA

  20. Refractory Corrosion Mechanisms in a Novel High Carbon Ferromanganese Production Furnace

    NASA Astrophysics Data System (ADS)

    Gregurek, D.; Wenzl, C.; Kreuzer, D.; Spanring, A.; Kirschen, M.; Zeelie, D.; Groenewald, J.

    2016-12-01

    The present paper presents the refractory design for a novel HCFeMn smelting furnace that, other than standard submerged arc furnaces, allows the processing of fine ores. A combination of basic and non-basic materials, comprising bricks, castables and ramming was chosen, under consideration of the unique furnace design and process conditions. Post-mortem investigations on refractory samples from the different furnace zones were carried out and provided information about the main wear mechanism. Additionally, investigations of the process slag and metal were carried out both practically and theoretically using thermodynamic calculations, to better understand the corrosion phenomena observed in the post mortem samples.

  1. Reaction between Steel-Making Slag and Carbonaceous Materials While Mixing with High Density Polyethylene

    NASA Astrophysics Data System (ADS)

    Hong, Lan; Sahajwalla, Veena

    2016-01-01

    Since the beginning of the extensive applications in numerous high temperature processes such as iron- and steel-making, coke-making etc. partly in the place of coke, the investigation into the reaction mechanism of waste plastics has become increasingly necessary. In this paper a fundamental study on the behavior of a typical component of waste plastics, high density polyethylene (HDPE), in a mixture with coke at a 1:1 ratio in mass base was conducted during the reaction with iron oxide in steel-making slag at 1823 K and was compared with coke and graphite. The reaction mechanism of carbonaceous materials was analyzed based on the contents of CO and CO2 in the off-gas monitored by an infrared (IR) gas analyzer. It is clear from the results that the reaction of HDPE and coke mixture with steel-making slag approached equilibrium of the Boudouard reaction more quickly and closely than coke or graphite.

  2. Driven Motion and Instability of an Atmospheric Pressure Arc

    SciTech Connect

    Max Karasik

    1999-12-01

    Atmospheric pressure arcs are used extensively in applications such as welding and metallurgy. However, comparatively little is known of the physics of such arcs in external magnetic fields and the mechanisms of the instabilities present. In order to address questions of equilibrium and stability of such arcs, an experimental arc furnace is constructed and operated in air with graphite cathode and steel anode at currents 100-250 A. The arc is diagnosed with a gated intensified camera and a collimated photodiode array, as well as fast voltage and current probes.

  3. Cathodic arcs

    SciTech Connect

    Anders, Andre

    2003-10-29

    Cathodic arc plasma deposition has become the technology of choice for hard, wear and corrosion resistant coatings for a variety of applications. The history, basic physics of cathodic arc operation, the infamous macroparticle problem and common filter solutions, and emerging high-tech applications are briefly reviewed. Cathodic arc plasmas standout due to their high degree of ionization, with important consequences for film nucleation, growth, and efficient utilization of substrate bias. Industrial processes often use cathodic arc plasma in reactive mode. In contrast, the science of arcs has focused on the case of vacuum arcs. Future research directions include closing the knowledge gap for reactive mode, large area coating, linear sources and filters, metal plasma immersion process, with application in high-tech and biomedical fields.

  4. High Temperature Transparent Furnace Development

    NASA Technical Reports Server (NTRS)

    Bates, Stephen C.

    1997-01-01

    This report describes the use of novel techniques for heat containment that could be used to build a high temperature transparent furnace. The primary objective of the work was to experimentally demonstrate transparent furnace operation at 1200 C. Secondary objectives were to understand furnace operation and furnace component specification to enable the design and construction of a low power prototype furnace for delivery to NASA in a follow-up project. The basic approach of the research was to couple high temperature component design with simple concept demonstration experiments that modify a commercially available transparent furnace rated at lower temperature. A detailed energy balance of the operating transparent furnace was performed, calculating heat losses through the furnace components as a result of conduction, radiation, and convection. The transparent furnace shells and furnace components were redesigned to permit furnace operation at at least 1200 C. Techniques were developed that are expected to lead to significantly improved heat containment compared with current transparent furnaces. The design of a thermal profile in a multizone high temperature transparent furnace design was also addressed. Experiments were performed to verify the energy balance analysis, to demonstrate some of the major furnace improvement techniques developed, and to demonstrate the overall feasibility of a high temperature transparent furnace. The important objective of the research was achieved: to demonstrate the feasibility of operating a transparent furnace at 1200 C.

  5. Paired Straight Hearth Furnace

    SciTech Connect

    2009-04-01

    This factsheet describes a research project whose goals are to design, develop, and evaluate the scalability and commercial feasibility of the PSH Paired Straight Hearth Furnace alternative ironmaking process.

  6. High temperature furnace

    DOEpatents

    Borkowski, Casimer J.

    1976-08-03

    A high temperature furnace for use above 2000.degree.C is provided that features fast initial heating and low power consumption at the operating temperature. The cathode is initially heated by joule heating followed by electron emission heating at the operating temperature. The cathode is designed for routine large temperature excursions without being subjected to high thermal stresses. A further characteristic of the device is the elimination of any ceramic components from the high temperature zone of the furnace.

  7. Simultaneous Measurements of Temperature and Iron-Slag Ratio at Taphole of Blast Furnace

    NASA Astrophysics Data System (ADS)

    Sugiura, M.; Shinotake, A.; Nakashima, M.; Omoto, N.

    2014-07-01

    As the initial process in an integrated steel-making plant, molten iron is produced in a blast furnace. The molten iron has a temperature between 1700 K and 1900 K. The outflow stream discharged from a taphole comprises the molten iron and slag (which is a mixture of molten oxides). Monitoring of the stream temperature is important because it has information on the thermal condition inside the blast furnace. A newly developed simultaneous measurement technique for temperature and iron-slag ratio is reported. A monochromatic CCD camera with a short exposure time is used to obtain a thermal image of the rapidly moving stream. The thermal image has a marble-like pattern caused by the physical separation of the iron and slag and their different optical properties. Iron thermometry is realized by automatically detecting the peak of the iron gray-level distribution on a histogram. Meanwhile, the thermal radiance of the semitransparent slag varies as a function of the thickness. The slag temperature is calculated from the maximum gray level, presuming that the emissivity of the slag is constant at a thick slag part. The slag ratio is measured by counting the number of pixels on the histogram. A field test was carried out at an operating blast furnace. The iron temperature, slag temperature, and slag ratio were successfully measured. This multiple image measurement is expected to be the new information source for stable blast furnace operation.

  8. 40 CFR 420.40 - Applicability; description of the steelmaking subcategory.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 29 2014-07-01 2012-07-01 true Applicability; description of the steelmaking subcategory. 420.40 Section 420.40 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS IRON AND STEEL MANUFACTURING POINT SOURCE CATEGORY...

  9. 40 CFR 420.40 - Applicability; description of the steelmaking subcategory.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 29 2011-07-01 2009-07-01 true Applicability; description of the steelmaking subcategory. 420.40 Section 420.40 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS IRON AND STEEL MANUFACTURING POINT SOURCE CATEGORY...

  10. 40 CFR 420.40 - Applicability; description of the steelmaking subcategory.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 30 2012-07-01 2012-07-01 false Applicability; description of the steelmaking subcategory. 420.40 Section 420.40 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS IRON AND STEEL MANUFACTURING POINT SOURCE CATEGORY...

  11. 40 CFR 420.40 - Applicability; description of the steelmaking subcategory.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 30 2013-07-01 2012-07-01 true Applicability; description of the steelmaking subcategory. 420.40 Section 420.40 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS IRON AND STEEL MANUFACTURING POINT SOURCE CATEGORY...

  12. 40 CFR 420.40 - Applicability; description of the steelmaking subcategory.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 28 2010-07-01 2010-07-01 true Applicability; description of the steelmaking subcategory. 420.40 Section 420.40 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS IRON AND STEEL MANUFACTURING POINT SOURCE CATEGORY...

  13. Regularities of heat transfer in the gas layers of a steam boiler furnace flame. Part II. Gas layer radiation laws and the procedure for calculating heat transfer in furnaces, fire boxes, and combustion chambers developed on the basis of these laws

    NASA Astrophysics Data System (ADS)

    Makarov, A. N.

    2014-10-01

    The article presents the results stemming from the scientific discovery of laws relating to radiation from the gas layers generated during flame combustion of fuel and when electric arc burns in electric-arc steel-melting furnaces. The procedure for calculating heat transfer in electric-arc and torch furnaces, fire-boxes, and combustion chambers elaborated on the basis of this discovery is described.

  14. Looking Northwest at Furnace Control Panels and Gas Control Furnace ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking Northwest at Furnace Control Panels and Gas Control Furnace in Red Room Within Recycle Recovery Building - Hematite Fuel Fabrication Facility, Recycle Recovery Building, 3300 State Road P, Festus, Jefferson County, MO

  15. Controlling electrode gap during vacuum arc remelting at low melting current

    DOEpatents

    Williamson, Rodney L.; Zanner, Frank J.; Grose, Stephen M.

    1997-01-01

    An apparatus and method for controlling electrode gap in a vacuum arc remelting furnace, particularly at low melting currents. Spectrographic analysis is performed of the metal vapor plasma, from which estimates of electrode gap are derived.

  16. Controlling electrode gap during vacuum arc remelting at low melting current

    DOEpatents

    Williamson, R.L.; Zanner, F.J.; Grose, S.M.

    1997-04-15

    An apparatus and method are disclosed for controlling electrode gap in a vacuum arc remelting furnace, particularly at low melting currents. Spectrographic analysis is performed of the metal vapor plasma, from which estimates of electrode gap are derived. 5 figs.

  17. 40 CFR 63.10685 - What are the requirements for the control of contaminants from scrap?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Area Sources: Electric Arc Furnace Steelmaking Facilities Standards and Compliance Requirements § 63... plastics, lead, and free organic liquids that is charged to the furnace. For the production of leaded steel... furnace. You must submit the scrap pollution prevention plan to the permitting authority for approval....

  18. 40 CFR 63.10685 - What are the requirements for the control of contaminants from scrap?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Area Sources: Electric Arc Furnace Steelmaking Facilities Standards and Compliance Requirements § 63... plastics, lead, and free organic liquids that is charged to the furnace. For the production of leaded steel... furnace. You must submit the scrap pollution prevention plan to the permitting authority for approval....

  19. 40 CFR 63.10685 - What are the requirements for the control of contaminants from scrap?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Area Sources: Electric Arc Furnace Steelmaking Facilities Standards and Compliance Requirements § 63... plastics, lead, and free organic liquids that is charged to the furnace. For the production of leaded steel... furnace. You must submit the scrap pollution prevention plan to the permitting authority for approval....

  20. Simulation of Flow Fluid in the BOF Steelmaking Process

    NASA Astrophysics Data System (ADS)

    Lv, Ming; Zhu, Rong; Guo, Ya-Guang; Wang, Yong-Wei

    2013-12-01

    The basic oxygen furnace (BOF) smelting process consists of different chemical reactions among oxygen, slag, and molten steel, which engenders a vigorous stirring process to promote slagging, dephosphorization, decarbonization, heating of molten steel, and homogenization of steel composition and temperature. Therefore, the oxygen flow rate, lance height, and slag thickness vary during the smelting process. This simulation demonstrated a three-dimensional mathematical model for a 100 t converter applying four-hole supersonic oxygen lance and simulated the effect of oxygen flow rate, lance height, and slag thickness on the flow of molten bath. It is found that as the oxygen flow rate increases, the impact area and depth increases, which increases the flow speed in the molten bath and decreases the area of dead zone. Low oxygen lance height benefits the increase of impact depth and accelerates the flow speed of liquid steel on the surface of the bath, while high oxygen lance height benefits the increase of impact area, thereafter enhances the uniform distribution of radial velocity in the molten steel and increases the flow velocity of molten steel at the bottom of furnace hearth. As the slag thickness increases, the diameter of impinging cavity on the slag and steel surface decreases. The radial velocity of liquid steel in the molten bath is well distributed when the jet flow impact on the slag layer increases.

  1. An improved gas extraction furnace

    NASA Technical Reports Server (NTRS)

    Wilkin, R. B.

    1972-01-01

    Design of glass furnace for analysis of rocks to determine nature and amount of trapped gas is described. Furnace heats specimen in vacuum conditions by radio frequency induction. Diagram of apparatus to show construction and operation is provided.

  2. Improved graphite furnace atomizer

    DOEpatents

    Siemer, D.D.

    1983-05-18

    A graphite furnace atomizer for use in graphite furnace atomic absorption spectroscopy is described wherein the heating elements are affixed near the optical path and away from the point of sample deposition, so that when the sample is volatilized the spectroscopic temperature at the optical path is at least that of the volatilization temperature, whereby analyteconcomitant complex formation is advantageously reduced. The atomizer may be elongated along its axis to increase the distance between the optical path and the sample deposition point. Also, the atomizer may be elongated along the axis of the optical path, whereby its analytical sensitivity is greatly increased.

  3. Elements of arc welding

    SciTech Connect

    Not Available

    1993-07-01

    This paper looks at the following arc welding techniques: (1) shielded metal-arc welding; (2) submerged-arc welding; (3) gas metal-arc welding; (4) flux-cored arc welding; (5) electrogas welding; (6) gas tungsten-arc welding; and (7) plasma-arc welding.

  4. CHARGING SIDE OF #130 ELECTRIC FURNACE CO. REHEAT FURNACE IN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    CHARGING SIDE OF #130 ELECTRIC FURNACE CO. REHEAT FURNACE IN REROLL BAY. CAKES FROM THE CASTING SHOP ARE BROUGHT UP TO ROLLING TEMPERATURE IN ONE OF TWO (#130 AND 146) GAS-FIRED FURNACES. A RADIO-CONTROLLED OVERHEAD CRANE TRANSFERS CAKES FROM FLATCARS TO THE ROLLER LINE LEADING INTO THE FURNACE. CAKES ARE HEATED AT 900-1000 DEGREES FAHRENHEIT FOR THREE TO FOUR HOURS. RATED FURNACE CAPACITY IS 100,000 LBS.\\HOUR. - American Brass Foundry, 70 Sayre Street, Buffalo, Erie County, NY

  5. Strengthen flame stability during the furnace`s load decrease

    SciTech Connect

    Zhang Zhiguo; Sun Xuexin; Li Fujin; Qiu Jihua; Chen Gang

    1996-12-31

    This paper presents the result of the study of the coal combustion characteristic and flame stability during the load decrease of PCFF (corner burner arrangement). Considering the relation between flame stability and furnace load during the furnace load change, some method must be used to strengthen the pulverized coal ignition and combustion for the furnace to maintain the flame stability especially for the furnace which fires low rank anthracite. Experimental results show that when the furnace load decreased, the temperature distribution in furnace decreased and the flame stability in furnace had changed because of the load changing. This paper also introduces a new pulverized coal burner: Bluff-body with cavity burner. According to the result of application of this burner, this kind of pulverized coal burner can improve the coal ignition and combustion efficiency. Especially for low load operation of furnace the bluff-body with cavity burner has demonstrated its ability in strengthening coal ignition and improving the flame stability for furnace operation. Experimental results show that using bluff-body with cavity burner, the lowest load for furnace fired bituminous is 40% MCR and 50% MCr for low rank anthracite (V{sup r} < 12%, A{sup f} > 45%). This burner has simple structure and is very easy to set up for furnace.

  6. Modeling of Droplet Generation in a Top Blowing Steelmaking Process

    NASA Astrophysics Data System (ADS)

    Rout, Bapin Kumar; Brooks, Geoff; Subagyo; Rhamdhani, M. Akbar; Li, Zushu

    2016-12-01

    Quantification of metal droplets ejected due to impinging gas jet on the surface of liquid metal is an important parameter for the understanding and for the modeling of the refining kinetics of reactions in slag-metal emulsion zone. In the present work, a numerical study has been carried out to critically examine the applicability of droplet generation rate correlation previously proposed by Subagyo et al. on the basis of dimensionless blowing number ( N B). The blowing number was re-evaluated at the impingement point of jet with taking into account the temperature effect of change in density and velocity of the gas jet. The result obtained from the work shows that the modified blowing number N B,T at the furnace temperature of 1873 K (1600 °C) is approximately double in magnitude compared to N B calculated by Subagyo and co-workers. When N B,T has been employed to the Subagyo's empirical correlation for droplet generation, a wide mismatch is observed between the experimental data obtained from cold model and hot model experiments. The reason for this large deviation has been investigated in the current study, and a theoretical approach to estimate the droplet generation rate has been proposed. The suitability of the proposed model has been tested by numerically calculating the amount of metals in slag. The study shows that the weight of metals in emulsion falls in the range of 0 to 21 wt pct of hot metal weight when droplet generation rate has been calculated at ambient furnace temperature of 1873 K (1600 °C).

  7. Sustainable Steelmaking Using Biomass and Waste Oxides (TRP9902)

    SciTech Connect

    Richard J. Fruehan

    2004-09-30

    A new process for ironmaking was proposed to employ renewable energy in the form of wood charcoal to produce hot metal. The process was aimed at the market niche of units ranging from 400,000 to 1 million tons of hot metal a year. In the new process, a Rotary Hearth Furnace (RHF) would be combined with a smelter to produce hot metal. This combination was proposed to overcome the technical hurdles of energy generation in smelters and the low productivity of RHFs, and also allow the use of wood charcoal as energy source and reductant. In order to assess the feasibility of the new process, it was necessary to estimate the productivity of the two units involved, the RHF and the smelter. This work concentrated on the development of a productivity model for the RHF able to predict changes in productivity according to the type of carbon and iron oxides used as feed materials. This model was constructed starting with the most fundamental aspect of reduction in composites measuring intrinsic rates of oxidation of different carbons in CO{sub 2}-CO atmospheres and reduction of different oxides in the same atmospheres. After that, a model was constructed considering the interplay of intrinsic kinetics and the transfer of heat to and within pellets such as used in the RHF. Finally, a productivity model for the RHF was developed based on the model developed for a pellet and the differences in heat transfer conditions between the laboratory furnace and the actual RHF. The final model produced for the RHF predicts production rates within 30% of actual plant data reported with coal and indicates that productivity gains as high as 50% could be achieved replacing coal with wood charcoal in the green balls owing to the faster reaction rates achieved with the second carbon. This model also indicates that an increase of less than 5% in total carbon consumption should take place in operations using wood charcoal instead of coal.

  8. Modeling of thermal plasma arc technology FY 1994 report

    SciTech Connect

    Hawkes, G.L.; Nguyen, H.D.; Paik, S.; McKellar, M.G.

    1995-03-01

    The thermal plasma arc process is under consideration to thermally treat hazardous and radioactive waste. A computer model for the thermal plasma arc technology was designed as a tool to aid in the development and use of the plasma arc-Joule beating process. The value of this computer model is to: (a) aid in understanding the plasma arc-Joule beating process as applied to buried waste or exhumed buried waste, (b) help design melter geometry and electrode configuration, (c) calculate the process capability of vitrifying waste (i.e., tons/hour), (d) develop efficient plasma and melter operating conditions to optimize the process and/or reduce safety hazards, (e) calculate chemical reactions during treatment of waste to track chemical composition of off-gas products, and composition of final vitrified waste form and (f) help compare the designs of different plasma-arc facilities. A steady-state model of a two-dimensional axisymmetric transferred plasma arc has been developed and validated. A parametric analysis was performed that studied the effects of arc length, plasma gas composition, and input power on the temperatures and velocity profiles of the slag and plasma gas. A two-dimensional transient thermo-fluid model of the US Bureau of Mines plasma arc melter has been developed. This model includes the growth of a slag pool. The thermo-fluid model is used to predict the temperature and pressure fields within a plasma arc furnace. An analysis was performed to determine the effects of a molten metal pool on the temperature, velocity, and voltage fields within the slag. A robust and accurate model for the chemical equilibrium calculations has been selected to determine chemical composition of final waste form and off-gas based on the temperatures and pressures within the plasma-arc furnace. A chemical database has been selected. The database is based on the materials to be processed in the plasma arc furnaces.

  9. AISI-DOE Direct Steelmaking Program. Annual report for the year ending November 30, 1993

    SciTech Connect

    Aukrust, E.

    1994-02-01

    This program has completed its 5th year since cost-share funding provided by DOE. The following tasks are reported on: budget, patents, talks, and publications; design and construction of gas cleaning and tempering loop; construction of pressurized smelter and operation of combined smelter and offgas system; study for ironmaking demonstration plant and for steelmaking processes; and laboratory research programs at universities and companies.

  10. Recovery of calcium carbonate from steelmaking slag and utilization for acid mine drainage pre-treatment.

    PubMed

    Mulopo, J; Mashego, M; Zvimba, J N

    2012-01-01

    The conversion of steelmaking slag (a waste product of the steelmaking process) to calcium carbonate (CaCO(3)) was tested using hydrochloric acid, ammonium hydroxide and carbon dioxide via a pH-swing process. Batch reactors were used to assess the technical feasibility of calcium carbonate recovery and its use for pre-treatment of acid mine drainage (AMD) from coal mines. The effects of key process parameters, such as the amount of acid (HCl/calcium molar ratio), the pH and the CO(2) flow rate were considered. It was observed that calcium extraction from steelmaking slag significantly increased with an increase in the amount of hydrochloric acid. The CO(2) flow rate also had a positive effect on the carbonation reaction rate but did not affect the morphology of the calcium carbonate produced for values less than 2 L/min. The CaCO(3) recovered from the bench scale batch reactor demonstrated effective neutralization ability during AMD pre-treatment compared with the commercial laboratory grade CaCO(3).

  11. Improved mechanical properties of A 508 class 3 steel for nuclear pressure vessel through steelmaking

    SciTech Connect

    Kim, J.T.; Kwon, H.K.; Kim, K.C.; Kim, J.M.

    1997-12-31

    The present work is concerned with the steelmaking practices which improve the mechanical properties of the A 508 class 3 steel for reactor pressure vessel. Three kinds of steelmaking practices were applied to manufacture the forged heavy wall shell for reactor pressure vessel, that is, the vacuum carbon deoxidation (VCD), modified VCD containing aluminum and silicon-killing. The segregation of the chemical elements through the thickness was quite small so that the variations of the tensile properties at room temperature were small and the anisotropy of the impact properties was hardly observed regardless of the steelmaking practices. The Charpy V-notch impact properties and the reference nil-ductile transition temperature by drop weight test were significantly improved by the modified VCD and silicon-killing as compared with those of the steel by VCD. Moreover, the plane strain fracture toughness values of the materials by modified VCD and silicon-killing practices was much higher than those of the steel by VCD. These were resulted from the fining of austenite grain size. It was observed that the grain size was below 20 {micro}m (ASTM No. 8.5) when using the modified VCD and silicon-killing, compared to 50 {micro}m (ASTM No. 7.0) when using VCD.

  12. Blast Furnace Granulated Coal Injection

    SciTech Connect

    1998-09-30

    Production levels on each furnace exceeded 7000 NTHM/day during July. The combined production of 14,326 was a result of lower coke rates and below average delay rates on both furnaces, The combined production was at its highest level since September 1997. In August, the combined productivity declined to less than 13,500 NTHM/day. Although D furnace maintained a production rate in excess of 7000 NTHM/day, C furnace was lower because of a castfloor breakout and subsequent five day repair from August 26-30. Despite the lower productivity in August, injected coal and furnace coke rates were very good during the month. During September, the operation was difficult as a result of higher delays on both furnaces. The combined average monthly delay rate was considerably above the twenty-month average of 113 minutes per day and the combined average monthly production was less than 14,000 NTHM/day. Higher furnace coke rates at lower coal injection levels also contributed to the decrease. Additionally, the coke rate on both furnaces was increased substantially and the injected coal rate was decreased in preparation for the high volatile Colorado coal trial that started on September 28. The furnace process results for this quarter are shown in Tables 1A and 1B. In addition, the last twelve months of injected coal and coke rates for each furnace are shown in Figures 1 and 2.

  13. High efficiency furnace

    SciTech Connect

    Hwang, K. S.; Koestler, D. J.

    1985-12-31

    Disclosed is a dwelling furnace having at least one clam-shell type primary heat exchanger in parallel orientation with a secondary heat exchanger, both the primary and secondary heat exchangers being vertically oriented relative to a furnace housing and parallel to the flow of air to be heated. The primary heat exchanger has a combustion chamber in the lower end thereof, and the lower end of the secondary heat exchanger exhausts into a tertiary heat exchanger oriented approximately perpendicular to the primary and secondary heat exchangers and horizontally relative to the housing, below the combustion chambers of the primary heat exchangers and below the exhaust outlet of the secondary heat exchanger. The tertiary heat exchanger includes a plurality of condensation tubes for retrieving the latent heat of condensation of the combustion gases. The furnace further comprises an induced draft blower for drawing combustion gases through the heat exchangers and inducting sufficient air to the combustion chamber of the primary heat exchanger for efficient combustion.

  14. Carbon-free induction furnace

    DOEpatents

    Holcombe, Cressie E.; Masters, David R.; Pfeiler, William A.

    1985-01-01

    An induction furnace for melting and casting highly pure metals and alloys such as uranium and uranium alloys in such a manner as to minimize contamination of the melt by carbon derived from the materials and the environment within the furnace. The subject furnace is constructed of carbon free materials and is housed within a conventional vacuum chamber. The furnace comprises a ceramic oxide crucible for holding the charge of metal or alloy. The heating of the crucible is achieved by a plasma-sprayed tungsten susceptor surrounding the crucible which, in turn, is heated by an RF induction coil separated from the susceptor by a cylinder of inorganic insulation. The furnace of the present invention is capable of being rapidly cycled from ambient temperatures to about 1650.degree. C. for effectively melting uranium and uranium alloys without the attendant carbon contamination problems previously encountered when using carbon-bearing furnace materials.

  15. Non-carbon induction furnace

    DOEpatents

    Holcombe, C.E.; Masters, D.R.; Pfeiler, W.A.

    1984-01-06

    The present invention is directed to an induction furnace for melting and casting highly pure metals and alloys such as uranium and uranium alloys in such a manner as to minimize contamination of the melt by carbon derived from the materials and the environment within the furnace. The subject furnace is constructed of non-carbon materials and is housed within a conventional vacuum chamber. The furnace comprises a ceramic oxide crucible for holding the charge of metal or alloys. The heating of the crucible is achieved by a plasma-sprayed tungsten susceptor surrounding the crucible which, in turn, is heated by an rf induction coil separated from the susceptor by a cylinder of inorganic insulation. The furnace of the present invention is capable of being rapidly cycled from ambient temperatures to about 1650/sup 0/C for effectively melting uranium and uranium alloys without the attendant carbon contamination problems previously encountered when using carbon-bearing furnace materials.

  16. HIGH TEMPERATURE MICROSCOPE AND FURNACE

    DOEpatents

    Olson, D.M.

    1961-01-31

    A high-temperature microscope is offered. It has a reflecting optic situated above a molten specimen in a furnace and reflecting the image of the same downward through an inert optic member in the floor of the furnace, a plurality of spaced reflecting plane mirrors defining a reflecting path around the furnace, a standard microscope supported in the path of and forming the end terminus of the light path.

  17. Water gas furnace

    SciTech Connect

    Gallaro, C.

    1985-12-03

    A water gas furnace comprising an outer container to provide a housing in which coke is placed into its lower part. A water container is placed within the housing. The coke is ignited and heats the water in the container converting it into steam. The steam is ejected into the coke, which together with air, produces water gas. Preferably, pumice stones are placed above the coke. The water gas is accepted into the pores of the pumice stones, where the heated pumice stones ignite the water gas, producing heat. The heat is extracted by a heat exchanger provided about the housing.

  18. Magnetically Damped Furnace (MDF)

    NASA Technical Reports Server (NTRS)

    1998-01-01

    The Magnetically Damped Furnace (MDF) breadboard is being developed in response to NASA's mission and goals to advance the scientific knowledge of microgravity research, materials science, and related technologies. The objective of the MDF is to dampen the fluid flows due to density gradients and surface tension gradients in conductive melts by introducing a magnetic field during the sample processing. The MDF breadboard will serve as a proof of concept that the MDF performance requirements can be attained within the International Space Station resource constraints.

  19. Cupola Furnace Computer Process Model

    SciTech Connect

    Seymour Katz

    2004-12-31

    The cupola furnace generates more than 50% of the liquid iron used to produce the 9+ million tons of castings annually. The cupola converts iron and steel into cast iron. The main advantages of the cupola furnace are lower energy costs than those of competing furnaces (electric) and the ability to melt less expensive metallic scrap than the competing furnaces. However the chemical and physical processes that take place in the cupola furnace are highly complex making it difficult to operate the furnace in optimal fashion. The results are low energy efficiency and poor recovery of important and expensive alloy elements due to oxidation. Between 1990 and 2004 under the auspices of the Department of Energy, the American Foundry Society and General Motors Corp. a computer simulation of the cupola furnace was developed that accurately describes the complex behavior of the furnace. When provided with the furnace input conditions the model provides accurate values of the output conditions in a matter of seconds. It also provides key diagnostics. Using clues from the diagnostics a trained specialist can infer changes in the operation that will move the system toward higher efficiency. Repeating the process in an iterative fashion leads to near optimum operating conditions with just a few iterations. More advanced uses of the program have been examined. The program is currently being combined with an ''Expert System'' to permit optimization in real time. The program has been combined with ''neural network'' programs to affect very easy scanning of a wide range of furnace operation. Rudimentary efforts were successfully made to operate the furnace using a computer. References to these more advanced systems will be found in the ''Cupola Handbook''. Chapter 27, American Foundry Society, Des Plaines, IL (1999).

  20. Recovery of titanium values from titanium grinding swarf by electric furnace smelting

    SciTech Connect

    Gerdemann, S.J.; White, J.C.

    1999-10-19

    A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag.

  1. TECHNOLOGY DEMONSTRATION SUMMARY. BABCOCK AND WILCOX CYCLONE FURNACE VITRIFICATION TECHNOLOGY (EPA/540/SR-92/017)

    EPA Science Inventory

    A Superfund Innovative Technology Evaluation (SITE) Demonstration of the Babcock & Wilcox Cyclone Furnace Vitrification Technology was conducted in November 1991. This Demonstration occurred at the Babcock & Wilcox (B&W) Alliance Research Center (ARC) in Alliance, OH. The B&W cyc...

  2. Recovery of titanium values from titanium grinding swarf by electric furnace smelting

    DOEpatents

    Gerdemann, Stephen J.; White, Jack C.

    1998-01-01

    A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag.

  3. Recovery of titanium values from titanium grinding swarf by electric furnace smelting

    DOEpatents

    Gerdemann, Stephen J.; White, Jack C.

    1999-01-01

    A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag.

  4. Recovery of titanium values from titanium grinding swarf by electric furnace smelting

    DOEpatents

    Gerdemann, S.J.; White, J.C.

    1998-08-04

    A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag. 1 fig.

  5. Blast furnace injection symposium: Proceedings

    SciTech Connect

    1996-12-31

    These proceedings contain 14 papers related to blast furnace injection issues. Topics include coal quality, coal grinding, natural gas injection, stable operation of the blast furnace, oxygen enrichment, coal conveying, and performance at several steel companies. All papers have been processed separately for inclusion on the data base.

  6. Fuel stoker and furnace

    SciTech Connect

    Schafer, T.L.; Schafer, G.L.; Swett, H.D.

    1984-02-14

    A furnace having a primary heat exchange unit also providing a combustion chamber, a secondary heat exchange unit connected by an upper crossover conduit to the primary heat exchange unit, and a tertiary heat exchange unit connected by a lower V-shaped crossover conduit to the secondary heat exchange unit. A third crossover conduit connects the V-shaped crossover conduit with the primary heat exchange unit. Vibrating means are provided between the secondary and tertiary heat exchange units to vibrate the walls thereof and dislodge clinging fly ash so that it falls into the V-shaped crossover conduit for removal by the screw conveyor. A burner assembly of a furnace includes a combustion air housing carrying a circular, stationary grate with an annular valley for carrying fuel during combustion. A central opening is connected to a fuel conveyor for introduction of fuel to the grate through the lower portion of the housing. Combustion air introduction conduits on the housing are remote from the fuel introduction passages and introduce air under pressure at the lower portion of the grate. An agitator and discharge ring is provided on the grate and is rotated on the grate by a suitable drive sprocket mechanism to agitate the fuel for more complete burning thereof and to remove burned ash. A horizontal burner plate is supported by a plurality of legs connected to the agitator and discharge ring over the grate to promote more complete combustion of the fuel.

  7. Two chamber reaction furnace

    DOEpatents

    Blaugher, Richard D.

    1998-05-05

    A vertical two chamber reaction furnace. The furnace comprises a lower chamber having an independently operable first heating means for heating the lower chamber and a gas inlet means for admitting a gas to create an ambient atmosphere, and an upper chamber disposed above the lower chamber and having an independently operable second heating means for heating the upper chamber. Disposed between the lower chamber and the upper chamber is a vapor permeable diffusion partition. The upper chamber has a conveyor means for conveying a reactant there through. Of particular importance is the thallinating of long-length thallium-barium-calcium-copper oxide (TBCCO) or barium-calcium-copper oxide (BCCO) precursor tapes or wires conveyed through the upper chamber to thereby effectuate the deposition of vaporized thallium (being so vaporized as the first reactant in the lower chamber at a temperature between about 700.degree. and 800.degree. C.) on TBCCO or BCCO tape or wire (the second reactant) at its simultaneous annealing temperature in the upper chamber of about 800.degree. to 950.degree. C. to thereby replace thallium oxide lost from TBCCO tape or wire because of the high annealing temperature or to deposit thallium on BCCO tape or wire. Continuously moving the tape or wire provides a single-step process that effectuates production of long-length TBCCO superconducting product.

  8. Two chamber reaction furnace

    DOEpatents

    Blaugher, R.D.

    1998-05-05

    A vertical two chamber reaction furnace is described. The furnace comprises a lower chamber having an independently operable first heating means for heating the lower chamber and a gas inlet means for admitting a gas to create an ambient atmosphere, and an upper chamber disposed above the lower chamber and having an independently operable second heating means for heating the upper chamber. Disposed between the lower chamber and the upper chamber is a vapor permeable diffusion partition. The upper chamber has a conveyor means for conveying a reactant there through. Of particular importance is the thallinating of long-length thallium-barium-calcium-copper oxide (TBCCO) or barium-calcium-copper oxide (BCCO) precursor tapes or wires conveyed through the upper chamber to thereby effectuate the deposition of vaporized thallium (being so vaporized as the first reactant in the lower chamber at a temperature between about 700 C and 800 C) on TBCCO or BCCO tape or wire (the second reactant) at its simultaneous annealing temperature in the upper chamber of about 800 to 950 C to thereby replace thallium oxide lost from TBCCO tape or wire because of the high annealing temperature or to deposit thallium on BCCO tape or wire. Continuously moving the tape or wire provides a single-step process that effectuates production of long-length TBCCO superconducting product. 2 figs.

  9. Steelmaking slag as aggregate for mortars: effects of particle dimension on compression strength.

    PubMed

    Faraone, Nicola; Tonello, Gabriele; Furlani, Erika; Maschio, Stefano

    2009-11-01

    The present paper reports on the results of some experiments obtained from the production, hydration and subsequent measurement of the mechanical properties of several mortars prepared using a commercial CII/B-LL Portland cement, steelmaking slag, superplasticizer and water. Relevant parameters for the mortar preparation are the weight ratios of cement/water, the weight ratio superplasticizer/cement and between fine and granulated coarse particles. It has been demonstrated that optimisation of such parameters leads to the production of materials with mechanical properties suitable for civil engineering applications. Moreover, materials with improved compressive strength can be prepared by the use of slag containing extensive amounts of large particles.

  10. High pressure furnace

    DOEpatents

    Morris, D.E.

    1993-09-14

    A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum)). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 19 figures.

  11. High pressure furnace

    DOEpatents

    Morris, Donald E.

    1993-01-01

    A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  12. High pressure oxygen furnace

    DOEpatents

    Morris, Donald E.

    1992-01-01

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  13. High pressure oxygen furnace

    DOEpatents

    Morris, D.E.

    1992-07-14

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  14. Fabrication of graphene from graphite by a thermal assisted vacuum arc discharge system

    NASA Astrophysics Data System (ADS)

    Cheng, Guo-Wei; Chu, Kevin; Chen, Jeng Shiung; Tsai, Jeff T. H.

    2017-04-01

    In this study, graphene was fabricated on copper foils using a high temperature furnace embedded in a vacuum arc discharge method. Combining the advantages of chemical vapor deposition and vacuum arc discharge, single-layer graphene can be fabricated at 600 °C base temperature from the mini furnace embedded with a fast heating via the photon radiation from the vacuum arc to 1100 °C on the substrates' surface. The optimal fabrication condition was determined through a series of experiments on ambient pressure, processing time, arc currents, and the cooling process. Observations by scanning electron microscopy, Raman spectroscopy, and optical microscopy showed that the main products were single-layer graphene, which has a uniform thickness across the entire substrate. The results demonstrated that the combination of a vacuum arc with a thermal method that uses graphite as a carbon source provides a low-cost and straight forward method to synthesize graphene films for graphene-based applications.

  15. Thermodynamic Properties of Lead Oxide in a Mixture of Stainless Steelmaking and Nonferrous Smelting Slags

    NASA Astrophysics Data System (ADS)

    Maruoka, Nobuhiro; Ueda, Shigeru; Shibata, Hiroyuki; Yamaguchi, Katsunori; Kitamura, Shin-ya

    2012-06-01

    In our previous paper, a slag modification process involving the mixing of stainless steelmaking and nonferrous smelting slags was proposed for preventing the disintegration of the stainless steelmaking slag. In order to use this method, the behavior of heavy metals especially PbO contained in the nonferrous slag has to be assessed. In the present study, the activity coefficient of PbO in CaO-SiO2-FetO-Al2O3-MgO and CaO-SiO2-FetO slags saturated with iron was measured at 1673 K. The results showed that the activity coefficient of PbO increased with basicity and had a maximum value when the basicity was approximately 1.0. The equilibrium PbO content in the modified slag had a minimum value that corresponded to a mixing ratio of 0.6. The trend was similar to the change in the removal ratio of PbO observed in the previous study. Therefore, the change in the oxygen potential and the change in the activity coefficient of PbO can be considered the cause of this trend.

  16. Arc melter demonstration baseline test results

    SciTech Connect

    Soelberg, N.R.; Chambers, A.G.; Anderson, G.L.; Oden, L.L.; O`Connor, W.K.; Turner, P.C.

    1994-07-01

    This report describes the test results and evaluation for the Phase 1 (baseline) arc melter vitrification test series conducted for the Buried Waste Integrated Demonstration program (BWID). Phase 1 tests were conducted on surrogate mixtures of as-incinerated wastes and soil. Some buried wastes, soils, and stored wastes at the INEL and other DOE sites, are contaminated with transuranic (TRU) radionuclides and hazardous organics and metals. The high temperature environment in an electric arc furnace may be used to process these wastes to produce materials suitable for final disposal. An electric arc furnace system can treat heterogeneous wastes and contaminated soils by (a) dissolving and retaining TRU elements and selected toxic metals as oxides in the slag phase, (b) destroying organic materials by dissociation, pyrolyzation, and combustion, and (c) capturing separated volatilized metals in the offgas system for further treatment. Structural metals in the waste may be melted and tapped separately for recycle or disposal, or these metals may be oxidized and dissolved into the slag. The molten slag, after cooling, will provide a glass/ceramic final waste form that is homogeneous, highly nonleachable, and extremely durable. These features make this waste form suitable for immobilization of TRU radionuclides and toxic metals for geologic timeframes. Further, the volume of contaminated wastes and soils will be substantially reduced in the process.

  17. DEVELOPMENT OF ELECTRONIC VERNEUIL FURNACE

    DTIC Science & Technology

    HIGH TEMPERATURE, *PLASMA JETS, *REFRACTORY MATERIALS, ALTERNATING CURRENT, CELLULOSE ACETATES, CRYSTAL STRUCTURE, CRYSTALS , GAS DISCHARGES, GROWTH ...PHYSIOLOGY), LABORATORY FURNACES, PLASMAS(PHYSICS), RADIOFREQUENCY GENERATORS, RADIOFREQUENCY POWER, SINGLE CRYSTALS , THEORY.

  18. Furnace brazing under partial vacuum

    NASA Technical Reports Server (NTRS)

    Mckown, R. D.

    1979-01-01

    Brazing furnace utilizing partial-vacuum technique reduces tooling requirements and produces better bond. Benefit in that partial vacuum helps to dissociate metal oxides that inhibit metal flow and eliminates heavy tooling required to hold parts together during brazing.

  19. Rebuilding of Rautaruukki blast furnaces

    SciTech Connect

    Kallo, S.; Pisilae, E.; Ojala, K.

    1997-12-31

    Rautaruukki Oy Raahe Steel rebuilt its blast furnaces in 1995 (BF1) and 1996 (BF2) after 10 year campaigns and production of 9,747 THM/m{sup 3} (303 NTHM/ft{sup 3}) and 9,535 THM/m{sup 3} (297 NTHM/ft{sup 3}), respectively. At the end of the campaigns, damaged cooling system and shell cracks were increasingly disturbing the availability of furnaces. The goal for rebuilding was to improve the cooling systems and refractory quality in order to attain a 15 year campaign. The furnaces were slightly enlarged to meet the future production demand. The blast furnace control rooms and operations were centralized and the automation and instrumentation level was considerably improved in order to improve the operation efficiency and to reduce manpower requirements. Investments in direct slag granulation and improved casthouse dedusting improved environmental protection. The paper describes the rebuilding.

  20. Weld arc simulator

    DOEpatents

    Burr, Melvin J.

    1990-01-30

    An arc voltage simulator for an arc welder permits the welder response to a variation in arc voltage to be standardized. The simulator uses a linear potentiometer connected to the electrode to provide a simulated arc voltage at the electrode that changes as a function of electrode position.

  1. Lip-hung retort furnace

    SciTech Connect

    Mackenzie, P.B.

    1986-08-05

    A fluidized bed furnace is described which consists of: a furnace housing including an outer shell; a furnace base and an outer top plate secured to the respective lower and upper ends of the furnace housing; a vertical retort having an opened upper end and an opened lower end, the retort being disposed in an opening formed in the outer top plate and extending downwardly into the center of the furnace housing; heat insulating material disposed between the outer shell and the vertical retort; a retort base assembly being adapted for closing the lower end of the vertical retort; upper support means for supporting the upper end of the vertical retort on top of the outer top plate so as to permit downward growth only during thermal expansion; the upper support means including an annular flange formed integrally with the sidewalls of the retort at the upper end thereof and being adapted to be fixedly mounted to the outer surface of the outer top plate; lower support means interposed between the lower surface of the retort base assembly and the upper surface of the furnace base for supporting substantially all the weight of the retort, the weight of the load of a fluidizable media, and the weight of a load of material to be heat treated.

  2. Variable frequency microwave furnace system

    DOEpatents

    Bible, Don W.; Lauf, Robert J.

    1994-01-01

    A variable frequency microwave furnace system (10) designed to allow modulation of the frequency of the microwaves introduced into a furnace cavity (34) for testing or other selected applications. The variable frequency microwave furnace system (10) includes a microwave signal generator (12) or microwave voltage-controlled oscillator (14) for generating a low-power microwave signal for input to the microwave furnace. A first amplifier (18) may be provided to amplify the magnitude of the signal output from the microwave signal generator (12) or the microwave voltage-controlled oscillator (14). A second amplifier (20) is provided for processing the signal output by the first amplifier (18). The second amplifier (20) outputs the microwave signal input to the furnace cavity (34). In the preferred embodiment, the second amplifier (20) is a traveling-wave tube (TWT). A power supply (22) is provided for operation of the second amplifier (20). A directional coupler (24) is provided for detecting the direction of a signal and further directing the signal depending on the detected direction. A first power meter (30) is provided for measuring the power delivered to the microwave furnace (32). A second power meter (26) detects the magnitude of reflected power. Reflected power is dissipated in the reflected power load (28).

  3. Variable frequency microwave furnace system

    DOEpatents

    Bible, D.W.; Lauf, R.J.

    1994-06-14

    A variable frequency microwave furnace system designed to allow modulation of the frequency of the microwaves introduced into a furnace cavity for testing or other selected applications. The variable frequency microwave furnace system includes a microwave signal generator or microwave voltage-controlled oscillator for generating a low-power microwave signal for input to the microwave furnace. A first amplifier may be provided to amplify the magnitude of the signal output from the microwave signal generator or the microwave voltage-controlled oscillator. A second amplifier is provided for processing the signal output by the first amplifier. The second amplifier outputs the microwave signal input to the furnace cavity. In the preferred embodiment, the second amplifier is a traveling-wave tube (TWT). A power supply is provided for operation of the second amplifier. A directional coupler is provided for detecting the direction of a signal and further directing the signal depending on the detected direction. A first power meter is provided for measuring the power delivered to the microwave furnace. A second power meter detects the magnitude of reflected power. Reflected power is dissipated in the reflected power load. 5 figs.

  4. Fossil fuel furnace reactor

    DOEpatents

    Parkinson, William J.

    1987-01-01

    A fossil fuel furnace reactor is provided for simulating a continuous processing plant with a batch reactor. An internal reaction vessel contains a batch of shale oil, with the vessel having a relatively thin wall thickness for a heat transfer rate effective to simulate a process temperature history in the selected continuous processing plant. A heater jacket is disposed about the reactor vessel and defines a number of independent controllable temperature zones axially spaced along the reaction vessel. Each temperature zone can be energized to simulate a time-temperature history of process material through the continuous plant. A pressure vessel contains both the heater jacket and the reaction vessel at an operating pressure functionally selected to simulate the continuous processing plant. The process yield from the oil shale may be used as feedback information to software simulating operation of the continuous plant to provide operating parameters, i.e., temperature profiles, ambient atmosphere, operating pressure, material feed rates, etc., for simulation in the batch reactor.

  5. Wood burning furnace

    SciTech Connect

    Lillo, A.D.

    1986-03-25

    An improved furnace for burning wood is described which is resistant to creosote deposits from smoke. It consists of: an upright frame; a fire box carried by the frame and having a door for the insertion of the wood; a heat exchanger carried on the fire box and having an interior chamber with a top and bottom; means connecting the fire box and the heat exchanger and directing smoke from the fire box into the exchanger chamber; a chimney stack fixed to and extending upwardly from the exchanger to discharge smoke, the stack also extending substantially downwardly within the exchanger chamber to receive smoke from adjacent the bottom of the chamber to thereby retain hot smoke adjacent the top of the exchanger for an increased time interval to allow additional heat transfer from the smoke to the exchanger; an insulative housing carried on the frame to define an air plenum within the housing and about the fire box and exchanger to permit air in the plenum to be heated by contact with the fire box and the exchanger; and an air inlet for cold air to enter the plenum and an air outlet by which heated air may leave the plenum.

  6. EAST (FRONT) AND NORTH SIDE OF DOUBLE FURNACE AND NORTH ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    EAST (FRONT) AND NORTH SIDE OF DOUBLE FURNACE AND NORTH SIDE OF SINGLE FURNACE, SOUTHWEST. - Tannehill Furnace, 12632 Confederate Parkway, Tannehill Historical State Park, Bucksville, Tuscaloosa County, AL

  7. Gas arc constriction for plasma arc welding

    NASA Technical Reports Server (NTRS)

    McGee, William F. (Inventor); Rybicki, Daniel J. (Inventor)

    1994-01-01

    A welding torch for plasma arc welding apparatus has an inert gas applied circumferentially about the arc column externally of the constricting nozzle so as to apply a constricting force on the arc after it has exited the nozzle orifice and downstream of the auxiliary shielding gas. The constricting inert gas is supplied to a plenum chamber about the body of the torch and exits through a series of circumferentially disposed orifices in an annular wall forming a closure at the forward end of the constricting gas plenum chamber. The constricting force of the circumferential gas flow about the arc concentrates and focuses the arc column into a more narrow and dense column of energy after exiting the nozzle orifice so that the arc better retains its energy density prior to contacting the workpiece.

  8. Growth promotion of Spirulina by steelmaking slag: application of solubility diagram to understand its mechanism.

    PubMed

    Nogami, Reijiro; Nishida, Haruo; Hong, Dang Diem; Wakisaka, Minato

    2016-12-01

    A solubility diagram was employed to understand growth promotion of Arthrospira (Spirulina) platensis by steelmaking slag (SMS). The growth promotion effect of 112 % of freshwater microalga A. platensis was obtained using 5 g/L SMS. However, metabolites, such as pigments, and protein content of A. platensis were not significantly affected. Several metals dissolved in Spirulina-Ogawa-Terui medium were detected by inductively coupled plasma atomic emission spectrometry just after the addition of SMS. The solubility diagram provides information on the chemical speciation of metal elements based on pH and concentration. It is a useful tool to understand the effect of metals on microalgal growth. The metal elements used to control microalgal growth are essential minerals but also act as a source of oxidative stress. Regarding the affecting mechanism of SMS, iron may be the primary element regulating microalgal growth via pathway involving reactive oxygen species, as revealed by superoxide dismutase assay.

  9. Mapping the global flow of steel: from steelmaking to end-use goods.

    PubMed

    Cullen, Jonathan M; Allwood, Julian M; Bambach, Margarita D

    2012-12-18

    Our society is addicted to steel. Global demand for steel has risen to 1.4 billion tonnes a year and is set to at least double by 2050, while the steel industry generates nearly a 10th of the world's energy related CO₂ emissions. Meeting our 2050 climate change targets would require a 75% reduction in CO₂ emissions for every tonne of steel produced and finding credible solutions is proving a challenge. The starting point for understanding the environmental impacts of steel production is to accurately map the global steel supply chain and identify the biggest steel flows where actions can be directed to deliver the largest impact. In this paper we present a map of global steel, which for the first time traces steel flows from steelmaking, through casting, forming, and rolling, to the fabrication of final goods. The diagram reveals the relative scale of steel flows and shows where efforts to improve energy and material efficiency should be focused.

  10. Revitalize the US silicon/ferrosilicon industry through energy-efficient technology. Final report, Addendum furnace modeling

    SciTech Connect

    Schwsenke, G.K.; Wodley, D.; Szekely, J.

    1995-07-01

    A project was undertaken to model and analyze the dc submerged plasma arc furnace. A reaction extent model was developed and useful results obtained. The code can be run with commercially hardware and software. Two free energy minimization models were formulated; they may be run by modifying public domain programs.

  11. Automated, High Temperature Furnace for Glovebox Operation

    SciTech Connect

    Neikirk, K.

    2001-01-03

    The Plutonium Immobilization Project (PIP), to be located at the Savannah River Site SRS, is a combined development and testing effort by Lawrence Livermore National Laboratory (LLNL), Westinghouse Savannah River Company (WSRC), Pacific Northwest National Laboratory (PNNL), Argonne National Laboratory (ANL), and the Australian National Science and Technology Organization (ANSTO). The Plutonium Immobilization process involves the disposition of excess plutonium by incorporation into ceramic pucks. As part of the immobilization process, furnaces are needed for sintering the ceramic pucks. The furnace being developed for puck sintering is an automated, bottom loaded furnace with insulating package and resistance heating elements located within a nuclear glovebox. Other furnaces types considered for the application include retort furnaces and pusher furnaces. This paper, in part, will discuss the furnace technologies considered and furnace technology selected to support reliable puck sintering in a glovebox environment.

  12. Behavior of sustained high-current arcs on molten-alloy electrodes during vacuum consumable-arc remelting

    NASA Astrophysics Data System (ADS)

    Zanner, F. J.; Bertram, L. A.

    Vacuum consumable arc remelting is a casting process carried out in a vacuum with the aim of remelting the consumable electrode in such a way that the new ingot has improved chemical and physical homogeneity. The power which causes the melting is supplied by a vacuum arc burning between the electrodes. In order to determine the furnace partitions of electrical power and current, experiments were conducted on molten faced round electrodes. The quasi-steady melt rate was determined for both horizontally opposed 15 cm dia. Ni electrodes and for vertically suspended 40 cm dia. Inconel 718 electrodes.

  13. Arc-Free High-Power dc Switch

    NASA Technical Reports Server (NTRS)

    Miller, W. N.; Gray, O. E.

    1982-01-01

    Hybrid switch allows high-power direct current to be turned on and off without arcing or erosion. Switch consists of bank of transistors in parallel with mechanical contacts. Transistor bank makes and breaks switched circuit; contacts carry current only during steady-state "on" condition. Designed for Space Shuttle orbiter, hybrid switch can be used also in high-power control circuits in aircraft, electric autos, industrial furnaces, and solar-cell arrays.

  14. CO2 sequestration using accelerated gas-solid carbonation of pre-treated EAF steel-making bag house dust.

    PubMed

    El-Naas, Muftah H; El Gamal, Maisa; Hameedi, Suhaib; Mohamed, Abdel-Mohsen O

    2015-06-01

    Mineral CO2 sequestration is a promising process for the reduction of carbon dioxide emissions to the atmosphere. In this paper, alkaline calcium-rich dust particles collected from bag filters of electric arc furnaces (EAF) for steel making were utilized as a viable raw material for mineral CO2 sequestration. The dust particles were pre-treated through hydration, drying and screening. The pre-treated particles were then subjected to direct gas-solid carbonation reaction in a fluidized-bed reactor. The carbonated products were characterized to determine the overall sequestration capacity and the mineralogical structures. Leaching tests were also performed to measure the extracted minerals from the carbonated dust and evaluate the carbonation process on dust stabilization. The experimental results indicated that CO2 could be sequestered using the pre-treated bag house dust. The maximum sequestration of CO2 was 0.657 kg/kg of dust, based on the total calcium content. The highest degree of carbonation achieved was 42.5% and the carbonation efficiency was 69% at room temperature.

  15. Electrostatic Levitation Furnace for the ISS

    NASA Technical Reports Server (NTRS)

    Murakami, Keiji; Koshikawa, Naokiyo; Shibasaki, Kohichi; Ishikawa, Takehiko; Okada, Junpei; Takada, Tetsuya; Arai, Tatsuya; Fujino, Naoki; Yamaura, Yukiko

    2012-01-01

    JAXA (Japan Aerospace Exploration Agency) has just started the development of Electrostatic Levitation Furnace to be launched in 2014 for the ISS. This furnace can control the sample position with electrostatic force and heat it above 2000 degree Celsius using semiconductor laser from four different directions. The announcement of Opportunity will be issued soon for this furnace. In this paper, we will show the specifications of this furnace and also the development schedule

  16. Rotating arc spark plug

    DOEpatents

    Whealton, John H.; Tsai, Chin-Chi

    2003-05-27

    A spark plug device includes a structure for modification of an arc, the modification including arc rotation. The spark plug can be used in a combustion engine to reduce emissions and/or improve fuel economy. A method for operating a spark plug and a combustion engine having the spark plug device includes the step of modifying an arc, the modifying including rotating the arc.

  17. 10 CFR 429.18 - Residential furnaces.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 3 2014-01-01 2014-01-01 false Residential furnaces. 429.18 Section 429.18 Energy... COMMERCIAL AND INDUSTRIAL EQUIPMENT Certification § 429.18 Residential furnaces. (a) Sampling plan for selection of units for testing. (1) The requirements of § 429.11 are applicable to residential furnaces;...

  18. Hopewell Furnace National Historic Site. Teacher's Guide.

    ERIC Educational Resources Information Center

    National Park Service (Dept. of Interior), Washington, DC.

    This teacher's guide contains activities to use in conjunction with a site visit to the Hopewell Furnace National Historic Site (Elverson, Pennsylvania). The guide provides diagrams of the furnace, a cold-blast smelting operation, and the furnace operation. It presents a timeline of iron production from ancient times through contemporary times.…

  19. 10 CFR 429.18 - Residential furnaces.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 3 2012-01-01 2012-01-01 false Residential furnaces. 429.18 Section 429.18 Energy... COMMERCIAL AND INDUSTRIAL EQUIPMENT Certification § 429.18 Residential furnaces. (a) Sampling plan for selection of units for testing. (1) The requirements of § 429.11 are applicable to residential furnaces;...

  20. 10 CFR 429.18 - Residential furnaces.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 3 2013-01-01 2013-01-01 false Residential furnaces. 429.18 Section 429.18 Energy... COMMERCIAL AND INDUSTRIAL EQUIPMENT Certification § 429.18 Residential furnaces. (a) Sampling plan for selection of units for testing. (1) The requirements of § 429.11 are applicable to residential furnaces;...

  1. DC arc weld starter

    DOEpatents

    Campiotti, Richard H.; Hopwood, James E.

    1990-01-01

    A system for starting an arc for welding uses three DC power supplies, a high voltage supply for initiating the arc, an intermediate voltage supply for sustaining the arc, and a low voltage welding supply directly connected across the gap after the high voltage supply is disconnected.

  2. Effect of P2O5 and FetO on the Viscosity and Slag Structure in Steelmaking Slags

    NASA Astrophysics Data System (ADS)

    Wang, Z. J.; Shu, Q. F.; Sridhar, S.; Zhang, M.; Guo, M.; Zhang, Z. T.

    2015-04-01

    The present paper investigates the influence of P2O5 and FetO on the viscosity and structure of steelmaking slags. An understanding of the viscous behavior and structure of FetO-bearing smelting slags is essential to control the dephosphorization in steelmaking process and to efficiently recycle the phosphorus from steelmaking slags. It is found that the viscosity of CaO-SiO2-Al2O3-MgO-FetO-P2O5 slags slightly increases with increasing P2O5 content, while the viscosity decreases with increasing FetO content. The degree of the polymerization of quenched slags, determined from Raman spectra, is found to increase with increasing P2O5 content and decrease with increasing FetO content. It is also noted that the peaks of Raman spectra between 800 and 1200 cm-1 were nearly absent at the FetO content of 22.46 wt pct; whereas according to 29Si MAS-NMR and FTIR analysis, it is clearly seen that the [SiO4]-tetrahedra-related peaks existed even for the same slag. This may confirm that small quantities of extra-framework iron species can absorb the Raman scattering and damp the Raman signal intensity and the presence of FetO in the slag does not necessarily eliminate [SiO4]-tetrahedra.

  3. Training Guidelines: Glass Furnace Operators.

    ERIC Educational Resources Information Center

    Ceramics, Glass, and Mineral Products Industry Training Board, Harrow (England).

    Technological development in the glass industry is constantly directed towards producing high quality glass at low operating costs. Particularly, changes have taken place in melting methods which mean that the modern furnace operator has greater responsibilities than any of his predecessors. The complexity of control systems, melting rates, tank…

  4. Acoustical Measurement Of Furnace Temperatures

    NASA Technical Reports Server (NTRS)

    Parthasarathy, Shakkottai; Venkateshan, Shakkottai P.

    1989-01-01

    Simple probes withstand severe conditions, yet give spatially-resolved temperature readings. Prototype acoustical system developed to measure temperatures from ambient to 1,800 degree F in such structures as large industrial lime kilns and recovery-boiler furnaces. Pulses of sound reflected from obstructions in sensing tube. Speed of sound and temperature in each segment deduced from travel times of pulses.

  5. Blast furnace repairs, relines and modernizations

    SciTech Connect

    Carpenter, J.A.; Swanson, D.E; Chango, R.F. . Burns Harbor Div.)

    1994-09-01

    Bethlehem Steel's Burns Harbor Div. operates two 89,000-cu ft blast furnaces, D and C, built in 1969 and 1972. These furnaces have been in the forefront of blast furnace performance since they were blown-in. To maintain a credible operation throughout the past 25 years their performance has been improved continuously. Production was increased approximately 3%/year while fuel rate decreased 1%/year. This presentation summarizes the early repairs, relines and improvements that have sustained and enhanced the furnace's performance. The fourth reline of both furnaces will be discussed in detail. As part of the 1991 reline of D furnace its lines were improved and modern penstocks installed. The bosh, tuyere jacket, hearth jacket and both cast floors were replaced. The furnace now has a larger hearth making it easier to control and, liquid level is no longer a problem when pulling the wind to shut down. The new cast floor with its increased trough length has much improved separation of slag from iron and lowered refractory consumption. Since the cast floors on D furnace were changed, there has been a reduction in accidents and absenteeism. This may be related to the change in work practices on the new cast floors. The 1994 reline of C furnace incorporates those improvements made on D furnace in 1991. In addition, C furnace will have high-density cooling which is expected to double its campaign from 6 to 12 years, without interim repairs.

  6. Direct current, closed furnace silicon technology

    SciTech Connect

    Dosaj, V.D.; May, J.B.; Arvidson, A.N.

    1994-05-01

    The dc closed furnace technology for smelting silicon offers technical operating challenges, as well as, economic opportunities for off-gas recovery, reduced electrode consumption, reduced reductant oxidation losses, reduced energy consumption, and improved silicon recovery. The 10 mva dc closed furnace is located in East Selkirk, Manitoba. Construction of this pilot plant was started in September 1990. Following successful commissioning of the furnace in 1992, a number of smelting tests have been conducted aimed at optimization of the furnace operation and the raw material mix. The operation of a closed furnace is significantly different from an open furnace operation. The major difference being in the mechanical movement of the mix, off-gas recovery, and inability to observe the process. These differences made data collection and analysis critical in making operating decisions. This closed furnace was operated by computer control (state of the art in the smelling industry).

  7. Rethinking Recycling in Arcs

    NASA Astrophysics Data System (ADS)

    Kelemen, P.; Behn, M. D.; Jagoutz, O.

    2012-12-01

    Hacker et al EPSL 2011 and Behn et al Nature Geosci 2011 investigated pathways for return of buoyant, subducted material to arc crust. These include (1) diapirs rising into the hot mantle wedge, with extensive melts adding a component to arc magmas, (2) flow of material back up a relatively cold "subduction channel", adding solids to the lower crust and small-degree partial melts to the upper crust, (3) flow from the forearc along the base of arc crust, and (4) imbrication of forearc material into arc crust. These processes add felsic, incompatible-element-rich components to arc crust. The flux of incompatible elements such as Th in arc lavas, thought to be mainly recycled from subducted sediments, is > sediment subduction flux. There are large uncertainties: arc crustal growth rates are imprecise; young, primitive arc lavas may not be representative of magmatic flux into arc crust; sediment subduction flux may have varied. Nevertheless, this result is found for all arcs examined, using recently published growth rates. Perhaps arc growth rates that include subduction erosion are systematically overestimated. Instead or in addition, maybe significant Th comes from material other than sediments. Here, we consider the implications of pathways 1-4 for arc growth rates and incompatible element enrichment, in the context of subduction erosion and arc-arc collision. Subducting arc lithologies can become separated, with only felsic components returned to arc crust. Buoyant lithologies are mobile in viscous instabilities at > 700-800°C. Whereas thin layers such as sediments may become mobile all at once, instabilities may periodically strip the hottest parts from the top of thick buoyant layers, replacing them with hot mantle. In arc-arc collision, the top of a subducting plate starts at about 0°C on the seafloor, so heating is slow. In subduction erosion, forearc material in the subducting package can be > 200°C before erosion so buoyant lithologies reach 700-800

  8. Arc initiation in cathodic arc plasma sources

    SciTech Connect

    Anders, Andre

    2002-01-01

    A "triggerless" arc initiation method and apparatus is based on simply switching the arc supply voltage to the electrodes (anode and cathode). Neither a mechanical trigger electrode nor a high voltage flashover from a trigger electrode is required. A conducting path between the anode and cathode is provided, which allows a hot spot to form at a location where the path connects to the cathode. While the conductive path is eroded by the cathode spot action, plasma deposition ensures the ongoing repair of the conducting path. Arc initiation is achieved by simply applying the relatively low voltage of the arc power supply, e.g. 500 V-1 kV, with the insulator between the anode and cathode coated with a conducting layer and the current at the layer-cathode interface concentrated at one or a few contact points. The local power density at these contact points is sufficient for plasma production and thus arc initiation. A conductive surface layer, such as graphite or the material being deposited, is formed on the surface of the insulator which separates the cathode from the anode. The mechanism of plasma production (and arc initiation) is based on explosive destruction of the layer-cathode interface caused by joule heating. The current flow between the thin insulator coating and cathode occurs at only a few contact points so the current density is high.

  9. Ultrahigh-vacuum furnace for sintering studies of ultrafine ceramic particles

    SciTech Connect

    Bonevich, J.E.; Teng, M.; Johnson, D.L.; Marks, L.D. )

    1991-12-01

    An ultrahigh-vacuum (UHV) furnace has been designed and constructed for the purpose of investigating the sintering behavior of ultrafine ceramic particles. The UHV furnace has three main chambers for particle production, sintering, and collection with additional facilities for an UHV transfer system. The furnace system achieves a base pressure of 4 {times} 10{sup {minus}7} Pa through the use of turbomolecular and ion pumps. The ultrafine particles of aluminum oxide are produced by the arc discharge method resulting in the formation of highly faceted particles in the size range of 20--50 nm. The particles are then carried into the tube furnace by a flowing gas stream where they sinter at elevated temperatures. The sintered samples are collected onto a specimen cartridge which is then transported under vacuum conditions to an UHV high-resolution electron microscope for structural characterization. The unique feature of this UHV furnace system is that one is able to perform sintering studies in a clean environment thereby minimizing the influence of contaminating species on the sintering behavior.

  10. Ultrahigh-vacuum furnace for sintering studies of ultrafine ceramic particles

    NASA Astrophysics Data System (ADS)

    Bonevich, John E.; Teng, Mao-Hua; Johnson, D. Lynn; Marks, Laurence D.

    1991-12-01

    An ultrahigh-vacuum (UHV) furnace has been designed and constructed for the purpose of investigating the sintering behavior of ultrafine ceramic particles. The UHV furnace has three main chambers for particle production, sintering, and collection with additional facilities for an UHV transfer system. The furnace system achieves a base pressure of 4 × 10-7 Pa through the use of turbomolecular and ion pumps. The ultrafine particles of aluminum oxide are produced by the arc discharge method resulting in the formation of highly faceted particles in the size range of 20-50 nm. The particles are then carried into the tube furnace by a flowing gas stream where they sinter at elevated temperatures. The sintered samples are collected onto a specimen cartridge which is then transported under vacuum conditions to an UHV high-resolution electron microscope for structural characterization. The unique feature of this UHV furnace system is that one is able to perform sintering studies in a clean environment thereby minimizing the influence of contaminating species on the sintering behavior.

  11. Dependence of Temperature and Slag Composition on Dephosphorization at the First Deslagging in BOF Steelmaking Process

    NASA Astrophysics Data System (ADS)

    Zhou, Chao-gang; Li, Jing; Shi, Cheng-bin; Yu, Wen-tao; Zhang, Zhi-ming; Liu, Zhi-ming; Deng, Chang-fu

    2016-04-01

    Effects of temperature and slag composition on dephosphorization in a 120 ton top-bottom combined blown converter steelmaking process by double slag method were studied. The slag properties were determined by scanning electron microscope- energy dispersive spectrometry (SEM-EDS), X-ray diffraction (XRD). The results show that the transition oxidation temperature between dephosphorization and decarbonization Tf is not the favorable temperature for the first deslagging. The optimum first deslagging temperature is confirmed to be approximately 1,673 K which is about 70 K higher than Tf. High melting temperatures phases (such as 3CaO·SiO2) in the slag with high basicity and MgO content are unfavorable to the dephosphorization. The optimum process condition for dephosphorization at the first deslagging in present work is approximately 1,673 K in temperature, 2.0 in slag basicity, 6 and 17 mass% in MgO and T.Fe content, 6 mass% ≤ MnO content.

  12. Research and Development for Thermoelectric Generation Technology Using Waste Heat from Steelmaking Process

    NASA Astrophysics Data System (ADS)

    Kuroki, Takashi; Murai, Ryota; Makino, Kazuya; Nagano, Kouji; Kajihara, Takeshi; Kaibe, Hiromasa; Hachiuma, Hirokuni; Matsuno, Hidetoshi

    2015-06-01

    In Japan, integrated steelworks have greatly lowered their energy use over the past few decades through investment in energy-efficient processes and facilities, maintaining the highest energy efficiency in the world. However, in view of energy security, the steelmaking industry is strongly required to develop new technologies for further energy saving. Waste heat recovery can be one of the key technologies to meet this requirement. To recover waste heat, particularly radiant heat from steel products which has not been used efficiently yet, thermoelectric generation (TEG) is one of the most effective technologies, being able to convert heat directly into electric power. JFE Steel Corporation (JFE) implemented a 10-kW-class grid-connected TEG system for JFE's continuous casting line with KELK Ltd. (KELK), and started verification tests to generate electric power using radiant heat from continuous casting slab at the end of fiscal year 2012. The TEG system has 56 TEG units, each containing 16 TEG modules. This paper describes the performance and durability of the TEG system, which has been investigated under various operating conditions at the continuous casting line.

  13. Automated, High Temperature Furnace for Glovebox Operation

    SciTech Connect

    Neikirk, K.

    2001-01-26

    The U.S. Department of Energy will immobilize excess plutonium in the proposed Plutonium Immobilization Plant (PIP) at the Savannah River Site (SRS) as part of a two track approach for the disposition of weapons usable plutonium. As such, the Department of Energy is funding a development and testing effort for the PIP. This effort is being performed jointly by Lawrence Livermore National Laboratory (LLNL), Westinghouse Savannah River Company (WSRC), Pacific Northwest National Laboratory (PNNL), and Argonne National Laboratory (ANL). The Plutonium Immobilization process involves the disposition of excess plutonium by incorporation into ceramic pucks. As part of the immobilization process, furnaces are needed for sintering the ceramic pucks. The furnace being developed for puck sintering is an automated, bottom loaded furnace with insulting package and resistance heating elements located within a nuclear glovebox. Other furnaces considered for the application include retort furnaces and pusher furnaces. This paper, in part, will discuss the furnace technologies considered and furnace technology selected to support reliable puck sintering in a glovebox environment. Due to the radiation levels and contamination associated with the plutonium material, the sintering process will be fully automated and contained within nuclear material gloveboxes. As such, the furnace currently under development incorporates water and air cooling to minimize heat load to the glovebox. This paper will describe the furnace equipment and systems needed to employ a fully automated puck sintering process within nuclear gloveboxes as part of the Plutonium Immobilization Plant.

  14. Long arc stabilities with various arc gas flow rates

    NASA Astrophysics Data System (ADS)

    Maruyama, K.; Takeda, K.; Sugimoto, M.; Noguchi, Y.

    2014-11-01

    A new arc torch for use in magnetically driven arc device was developed with a commercially available TIG welding arc torch. The torch has a water-cooling system to the torch nozzle and has a nozzle nut to supply a swirling-free plasma gas flow. Its endurance against arc thermal load is examined. Features of its generated arc are investigated.

  15. Experimental study on sulfur removal from ladle furnace refining slag in hot state by blowing air

    NASA Astrophysics Data System (ADS)

    Zhao, Li-hua; Lin, Lu; Wu, Qi-fan

    2016-01-01

    In view of the present problem of sulfur enrichment in the metallurgical recycling process of ladle furnace (LF) refining slag, a simple and efficient method of removing sulfur from this slag was proposed. The proposed method is compatible with current steelmaking processes. Sulfur removal from LF refining slag for SPHC steel (manufactured at a certain steel plant in China) by blowing air in the hot state was studied by using hot-state experiments in a laboratory. The FactSage software, a carbon/sulfur analyzer, and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy were used to test and analyze the sulfur removal effect and to investigate factors influencing sulfur removal rate. The results show that sulfur ions in LF refining slag can be oxidized into SO2 by O2 at high temperature by blowing air into molten slag; SO2 production was observed to reach a maximum with a small amount of blown O2 when the temperature exceeded 1350°C. At 1370°C and 1400°C, experimental LF refining slag is in the liquid state and exhibits good fluidity; under these conditions, the sulfur removal effect by blowing air is greater than 90wt% after 60 min. High temperature and large air flow rate are beneficial for removing sulfur from LF refining slag; compared with air flow rate, temperature has a greater strongly influences on the sulfur removal.

  16. Welding arc plasma physics

    NASA Technical Reports Server (NTRS)

    Cain, Bruce L.

    1990-01-01

    The problems of weld quality control and weld process dependability continue to be relevant issues in modern metal welding technology. These become especially important for NASA missions which may require the assembly or repair of larger orbiting platforms using automatic welding techniques. To extend present welding technologies for such applications, NASA/MSFC's Materials and Processes Lab is developing physical models of the arc welding process with the goal of providing both a basis for improved design of weld control systems, and a better understanding of how arc welding variables influence final weld properties. The physics of the plasma arc discharge is reasonably well established in terms of transport processes occurring in the arc column itself, although recourse to sophisticated numerical treatments is normally required to obtain quantitative results. Unfortunately the rigor of these numerical computations often obscures the physics of the underlying model due to its inherent complexity. In contrast, this work has focused on a relatively simple physical model of the arc discharge to describe the gross features observed in welding arcs. Emphasis was placed of deriving analytic expressions for the voltage along the arc axis as a function of known or measurable arc parameters. The model retains the essential physics for a straight polarity, diffusion dominated free burning arc in argon, with major simplifications of collisionless sheaths and simple energy balances at the electrodes.

  17. Crystal growth furnace with trap doors

    DOEpatents

    Sachs, Emanual M.; Mackintosh, Brian H.

    1982-06-15

    An improved furnace is provided for growing crystalline bodies from a melt. The improved furnace is characterized by a door assembly which is remotely controlled and is arranged so as to selectively shut off or permit communication between an access port in the furnace enclosure and a hot zone within that enclosure. The invention is especially adapted to facilitate use of crystal growing cartridges of the type disclosed in U.S. Pat. No. 4,118,197.

  18. Measurement of airflow in residential furnaces

    SciTech Connect

    Biermayer, Peter J.; Lutz, James; Lekov, Alex

    2004-01-24

    In order to have a standard for furnaces that includes electricity consumption or for the efficiency of furnace blowers to be determined, it is necessary to determine the airflow of a furnace or furnace blower. This study focused on airflow testing, in order to determine if an existing test method for measuring blower airflow could be used to measure the airflow of a furnace, under conditions seen in actual installations and to collect data and insights into the operating characteristics of various types of furnace blowers, to use in the analysis of the electricity consumption of furnaces. Results of the measured airflow on furnaces with three types of blower and motor combinations are presented in the report. These included: (1) a forward-curved blower wheel with a typical permanent split capacitor (PSC) motor, (2) a forward-curved blower wheel with an electronically-commutated motor (ECM), and (3) a prototype blower, consisting of a backward-inclined blower wheel matched to an ECM motor prototype, which is being developed as an energy-saving alternative to conventional furnace blowers. The testing provided data on power consumption, static and total pressure, and blower speed.

  19. WSTF electrical arc projects

    NASA Astrophysics Data System (ADS)

    Linley, Larry

    1994-09-01

    The objectives of these projects include the following: validate method used to screen wire insulation with arc tracking characteristics; determine damage resistance to arc as a function of source voltage and insulation thickness; investigate propagation characteristics of Kapton at low voltages; and investigate pyrolytic properties of polyimide insulated (Kapton) wire for low voltage (less than 35 VDC) applications. Supporting diagrams and tables are presented.

  20. WSTF electrical arc projects

    NASA Technical Reports Server (NTRS)

    Linley, Larry

    1994-01-01

    The objectives of these projects include the following: validate method used to screen wire insulation with arc tracking characteristics; determine damage resistance to arc as a function of source voltage and insulation thickness; investigate propagation characteristics of Kapton at low voltages; and investigate pyrolytic properties of polyimide insulated (Kapton) wire for low voltage (less than 35 VDC) applications. Supporting diagrams and tables are presented.

  1. TIGER Arc Modification Application

    SciTech Connect

    Armstrong, Hillary

    1995-03-06

    The application enables the geometric correction of TIGER arcs to a more accurate spatial data set. This is done in a structured automated environment according to Census Bureau guidelines and New Mexico state GIS standards. Arcs may be deleted, added, combined, split, and moved relative to a coverage or image displayed in the background.

  2. Lazy arc consistency

    SciTech Connect

    Schiex, T.; Gaspin, C.; Regin, J.C.; Verfaillie, G.

    1996-12-31

    Arc consistency filtering is widely used in the framework of binary constraint satisfaction problems: with a low complexity, inconsistency may be detected and domains are filtered. In this paper, we show that when detecting inconsistency is the objective, a systematic domain filtering is useless and a lazy approach is more adequate. Whereas usual arc consistency algorithms produce the maximum arc consistent sub-domain, when it exists, we propose a method, called LAC{tau}, which only looks for any arc consistent sub-domain. The algorithm is then extended to provide the additional service of locating one variable with a minimum domain cardinality in the maximum arc consistent sub-domain, without necessarily computing all domain sizes. Finally, we compare traditional AC enforcing and lazy AC enforcing using several benchmark problems, both randomly generated CSP and real life problems.

  3. Looking southwest at blast furnaces no. 5 and no. 6 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking southwest at blast furnaces no. 5 and no. 6 with blast furnace trestle and Gondola Railroad cars in foreground. - U.S. Steel Edgar Thomson Works, Blast Furnace Plant, Along Monongahela River, Braddock, Allegheny County, PA

  4. 3. VIEW OF DUQUESNE'S RAIL LINES AND BLAST FURNACE PLANT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. VIEW OF DUQUESNE'S RAIL LINES AND BLAST FURNACE PLANT LOOKING NORTH. DOROTHY SIX IS THE CLOSEST FURNACE IN THE PHOTOGRAPH. (Jet Lowe) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  5. 56. LOOKING NORTH AT DOROTHY SIX BLAST FURNACE WITH CAST ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    56. LOOKING NORTH AT DOROTHY SIX BLAST FURNACE WITH CAST HOUSE IN FOREGROUND AND DUSTCATCHER AT RIGHT OF FURNACE (Jet Lowe) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  6. Looking southeast at blast furnaces no. 5 and no. 6 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking southeast at blast furnaces no. 5 and no. 6 with blast furnace trestle and Gondola Railroad cars in foreground. - U.S. Steel Edgar Thomson Works, Blast Furnace Plant, Along Monongahela River, Braddock, Allegheny County, PA

  7. 41. Casting floor, "B" furnace, pour in progress; mudgun is ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    41. Casting floor, "B" furnace, pour in progress; mudgun is to right of furnace; photo taken from furnace operator's booth. Looking south/southwest - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  8. 19. Inside the cast house at Furnace A. Molten iron ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    19. Inside the cast house at Furnace A. Molten iron flowed into eight ladles. The furnace was cast (or tapped) six times each day. - Central Furnaces, 2650 Broadway, east bank of Cuyahoga River, Cleveland, Cuyahoga County, OH

  9. INTERIOR VIEW OF FURNACE NO. 2, DRAWING ROOM, SHOWING A ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW OF FURNACE NO. 2, DRAWING ROOM, SHOWING A FLOOR INDICATING FOURCAULT DRAWING MACHINE AND FURNACE. - Chambers-McKee Window Glass Company, Furnace No. 2, Clay Avenue Extension, Jeannette, Westmoreland County, PA

  10. INTERIOR VIEW LOOKING WEST, CAST HOUSE OF BLAST FURNACE NO. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW LOOKING WEST, CAST HOUSE OF BLAST FURNACE NO. 1 AND BLAST FURNACE NO. 2. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 1 & No. 2, Donner Avenue, Monessen, Westmoreland County, PA

  11. 50. Taken from highline; "B" furnace slag pots, pipe is ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    50. Taken from high-line; "B" furnace slag pots, pipe is main blast furnace gas line from "C" furnace dust catcher; levy, slag hauler, removing slag. Looking east - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  12. List of EPA Certified Forced-Air Furnaces

    EPA Pesticide Factsheets

    The EPA-Certified Forced-Air Furnace list contains EPA-certified forced-air furnaces that meet the 2015 NSPS for New Residential Wood Heaters, New Residential Hydronic Heaters and Forced-Air Furnaces.

  13. Refractories for lining blast furnaces

    SciTech Connect

    Fedoruk, R.M.; Baksheeva, V.S.; Karyakina, E.L.; Khmelenko, T.P.; Pitak, N.V.

    1986-01-01

    The authors develop and introduce a technology for the production of chamotte kaolin refractories with a porosity of not more than 12% and a mass proportion of not less than 42% A1/sub 2/O/sub 3/ on the basis of chamotte from high-grade Polozhe kaolin, and also additions to the batch of finely milled mullite-corundum chamotte. Using the new technology, a batch of goods designated ShPD-42 was produced for lining the shafts, bosh, and upper parts of blast furnaces of large capacity.

  14. VAPOR SHIELD FOR INDUCTION FURNACE

    DOEpatents

    Reese, S.L.; Samoriga, S.A.

    1958-03-11

    This patent relates to a water-cooled vapor shield for an inductlon furnace that will condense metallic vapors arising from the crucible and thus prevent their condensation on or near the induction coils, thereby eliminating possible corrosion or shorting out of the coils. This is accomplished by placing, about the top, of the crucible a disk, apron, and cooling jacket that separates the area of the coils from the interior of the cruclbIe and provides a cooled surface upon whlch the vapors may condense.

  15. Silicon smelting in a closed furnace

    SciTech Connect

    Dosaj, V.; Brumels, M.D.; Haines, C.M.; May, J.B. )

    1991-01-01

    Dow Corning has been working towards the advancement of silicon smelting in a closed furnace over the past four years. A 200 kVA closed furnace pilot plant unit was built to investigate the operating parameters for smelting silicon. The single electrode furnace is operated under totally sealed conditions. The feed from the feed hoppers is fed through air locks to the furnace. The off-gas from the furnace, consisting of by-product CO as well as volatiles from the feeds, pass through a venturi scrubber, where water is introduced to scrub out the fume from the furnace and cool the gas. The mixed scrubber water and off-gas pass into a centrifugal mist eliminator where the water and fume disengage from the gas. The fume slurry is passed through bag filters where the fume is separated from the water. The clean off-gas from the furnace was evaluated for its calorific value and evaluated for conversion to useful products. A number of silicon smelting tests were conducted during this program. Various levels of charcoal and coal mixtures were evaluated to determine the optimum mix. A low volatile coal was preferred over typical Blue Gem coal. The coal amount in the mix was maximized without compromising the smelting performance. A raw material mix consisting of 30% charcoal and 70% low volatile coal was determined to be an optimum mix for closed furnace operation. Silicon recoveries in the low nineties were demonstrated using this mix. Four quartz sources were also evaluated in the closed furnace. The closed furnace operation for silicon smelting was identified to offer significant advantages over an open furnace from the standpoint of reduced carbon oxidation losses, electrode consumption, electrical energy consumption and silicon yield improvement. Other advantages in addition to process off-gas recovery included improved safety from reduced heat and fume exposure, and improved pollution control to the environment. 1 ref.

  16. Silicon smelting in a closed furnace

    SciTech Connect

    Dosaj, V.; Brumels, M.D.; Haines, C.M.; May, J.B.

    1991-12-31

    Dow Corning has been working towards the advancement of silicon smelting in a closed furnace over the past four years. A 200 kVA closed furnace pilot plant unit was built to investigate the operating parameters for smelting silicon. The single electrode furnace is operated under totally sealed conditions. The feed from the feed hoppers is fed through air locks to the furnace. The off-gas from the furnace, consisting of by-product CO as well as volatiles from the feeds, pass through a venturi scrubber, where water is introduced to scrub out the fume from the furnace and cool the gas. The mixed scrubber water and off-gas pass into a centrifugal mist eliminator where the water and fume disengage from the gas. The fume slurry is passed through bag filters where the fume is separated from the water. The clean off-gas from the furnace was evaluated for its calorific value and evaluated for conversion to useful products. A number of silicon smelting tests were conducted during this program. Various levels of charcoal and coal mixtures were evaluated to determine the optimum mix. A low volatile coal was preferred over typical Blue Gem coal. The coal amount in the mix was maximized without compromising the smelting performance. A raw material mix consisting of 30% charcoal and 70% low volatile coal was determined to be an optimum mix for closed furnace operation. Silicon recoveries in the low nineties were demonstrated using this mix. Four quartz sources were also evaluated in the closed furnace. The closed furnace operation for silicon smelting was identified to offer significant advantages over an open furnace from the standpoint of reduced carbon oxidation losses, electrode consumption, electrical energy consumption and silicon yield improvement. Other advantages in addition to process off-gas recovery included improved safety from reduced heat and fume exposure, and improved pollution control to the environment. 1 ref.

  17. SOUTH END OF FURNACE WITH CAST AND ENGINE SHED IN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    SOUTH END OF FURNACE WITH CAST AND ENGINE SHED IN FOREGROUND, LOOKING NORTH-NORTHEAST. - Tannehill Furnace, 12632 Confederate Parkway, Tannehill Historical State Park, Bucksville, Tuscaloosa County, AL

  18. GENERAL VIEW OF EAST (FRONT) OF DOUBLE FURNACE FROM ACROSS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    GENERAL VIEW OF EAST (FRONT) OF DOUBLE FURNACE FROM ACROSS THE CREEK, LOOKING SOUTHWEST. - Tannehill Furnace, 12632 Confederate Parkway, Tannehill Historical State Park, Bucksville, Tuscaloosa County, AL

  19. WEST (FRONT) OF FURNACE COMPLEX, INCLUDING STACKS, WITH CHARGING BRIDGE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    WEST (FRONT) OF FURNACE COMPLEX, INCLUDING STACKS, WITH CHARGING BRIDGE AND TRESSLE, LOOKING SOUTHEAST. - Tannehill Furnace, 12632 Confederate Parkway, Tannehill Historical State Park, Bucksville, Tuscaloosa County, AL

  20. Energy Saving Devices on Gas Furnaces.

    DTIC Science & Technology

    1980-03-01

    AO-A082 0715 JOHNS - MANVILLE SALES CORP DENVER CO RESEARCH AND DEV--ETC FIG 1311 ENERGY SAVING DEVICES ON GAS FURNACES.(U) MAR B0 T E BRISBANE, P B...DEVICES FOR GAS FURNACES THOMAS E. BRISBANE ,o"’ P. B. SHEPHERD JOHNS - MANVILLE SALES CORPORATION RESEARCH & DEVELOPMENT CENTER KEN-CARYL RANCH, DENVER

  1. Existing and prospective blast-furnace conditions

    SciTech Connect

    I.G. Tovarovskii; V.I. Bol'shakov; V.P. Lyalyuk; A.E. Merkulov; D. V. Pinchuk

    2009-07-15

    Blast-furnace conditions are investigated by means of a multizone model. The expected performance of prospective technologies is assessed, as well as the trends in blast-furnace processes. The model permits the identification of means of overcoming practical difficulties.

  2. Developmental testing of a programmable multizone furnace

    NASA Technical Reports Server (NTRS)

    Ting, E. Y.; Larson, D. J., Jr.

    1986-01-01

    A multizone furnace was evaluated for its potential utilization for process experimentation on board the Space Shuttle. A temperature gradient can be created through the use of a series of connected temperature zones and can be translated by the coordinated sequencing of zone temperatures. The Bridgman-Stockbarger thermal configuration for directional solidification was implemented so that neither the sample nor furnace was translated. The thermal behavior of the furnace was measured and characterized. Limitations due to both thermal and electronic (computer) factors are identified. The results indicate that the multizone design is limited to low temperature gradients because of the indirect furnace-to-sample thermal coupling needed to blend the discrete thermal zones. The multizone furnace design inherently consumes more power than a similar (two temperature) conventional Bridgman type directional solidification furnace because every zone must be capable of the high cooling rates needed to produce the maximum desired temperature drop. Typical achievable static temperature gradients for the furnace tested were between 6 and 75 C/in. The maximum gradient velocity was approximately 10 in./hr. Several aspects of the tested system could be improved, but the dependence of the multizone design on high heat loss will limit Space Shuttle applications in the form tested unless additional power is available. The multizone furnace offers great flexibility but requires a high level of operator understanding for full advantage to be obtained.

  3. Crystal growth furnace safety system validation

    NASA Technical Reports Server (NTRS)

    Mackowski, D. W.; Hartfield, R.; Bhavnani, S. H.; Belcher, V. M.

    1994-01-01

    The findings are reported regarding the safe operation of the NASA crystal growth furnace (CGF) and potential methods for detecting containment failures of the furnace. The main conclusions are summarized by ampoule leak detection, cartridge leak detection, and detection of hazardous species in the experiment apparatus container (EAC).

  4. Blast furnace injection developments in British Steel

    SciTech Connect

    Jukes, M.H.

    1996-12-31

    British Steel has four integrated steel works, i.e., Llanwern, Port Talbot, Scunthorpe, Teesside, with a total of ten blast furnaces, nine of which are currently operating. The furnaces range in size from the 14 meters (45 feet 11 inches) hearth diameter Redcar No. 1 furnace at Teesside (a single furnace works) to the 8.33 meters (27 feet 4 inches) hearth Queen Mary and Queen Bess furnaces at Schunthorpe, with a total of four furnaces at that works. All have injection systems installed, those at Scunthorpe being equipped with granular coal injection and all others currently working with oil injection. The driving force behind the development of blast furnace injection has been as a means for introducing reducing agents (British Steel now refers to coke plus hydrocarbon injectants as total reductants) into the process as a part substitute/supplement for top charged coke and the technology is still being developed and used for that purpose. By utilizing practical experience and observing the work of others, British Steel has been assessing blast furnace injection technology experimentally for purposes other than the introduction of reducing agents.

  5. Vertical two chamber reaction furnace

    DOEpatents

    Blaugher, R.D.

    1999-03-16

    A vertical two chamber reaction furnace is disclosed. The furnace comprises a lower chamber having an independently operable first heating means for heating the lower chamber and a gas inlet means for admitting a gas to create an ambient atmosphere, and an upper chamber disposed above the lower chamber and having an independently operable second heating means for heating the upper chamber. Disposed between the lower chamber and the upper chamber is a vapor permeable diffusion partition. The upper chamber has a conveyor means for conveying a reactant there through. Of particular importance is the thallinating of long-length thallium-barium-calcium copper oxide (TBCCO) or barium-calcium-copper oxide (BCCO) precursor tapes or wires conveyed through the upper chamber to thereby effectuate the deposition of vaporized thallium (being so vaporized as the first reactant in the lower chamber at a temperature between about 700 and 800 C) on TBCCO or BCCO tape or wire (the second reactant) at its simultaneous annealing temperature in the upper chamber of about 800 to 950 C to thereby replace thallium oxide lost from TBCCO tape or wire because of the high annealing temperature or to deposit thallium on BCCO tape or wire. Continuously moving the tape or wire provides a single-step process that effectuates production of long-length TBCCO superconducting product. 2 figs.

  6. Vertical two chamber reaction furnace

    DOEpatents

    Blaugher, Richard D.

    1999-03-16

    A vertical two chamber reaction furnace. The furnace comprises a lower chamber having an independently operable first heating means for heating the lower chamber and a gas inlet means for admitting a gas to create an ambient atmosphere, and an upper chamber disposed above the lower chamber and having an independently operable second heating means for heating the upper chamber. Disposed between the lower chamber and the upper chamber is a vapor permeable diffusion partition. The upper chamber has a conveyor means for conveying a reactant there through. Of particular importance is the thallinating of long-length thallium-barium-calcium-copper oxide (TBCCO) or barium-calcium-copper oxide (BCCO) precursor tapes or wires conveyed through the upper chamber to thereby effectuate the deposition of vaporized thallium (being so vaporized as the first reactant in the lower chamber at a temperature between about 700.degree. and 800.degree. C.) on TBCCO or BCCO tape or wire (the second reactant) at its simultaneous annealing temperature in the upper chamber of about 800.degree. to 950.degree. C. to thereby replace thallium oxide lost from TBCCO tape or wire because of the high annealing temperature or to deposit thallium on BCCO tape or wire. Continuously moving the tape or wire provides a single-step process that effectuates production of long-length TBCCO superconducting product.

  7. Tokamak ARC damage

    SciTech Connect

    Murray, J.G.; Gorker, G.E.

    1985-01-01

    Tokamak fusion reactors will have large plasma currents of approximately 10 MA with hundreds of megajoules stored in the magnetic fields. When a major plasma instability occurs, the disruption of the plasma current induces voltage in the adjacent conducting structures, giving rise to large transient currents. The induced voltages may be sufficiently high to cause arcing across sector gaps or from one protruding component to another. This report reviews a tokamak arcing scenario and provides guidelines for designing tokamaks to minimize the possibility of arc damage.

  8. Electric arc saw apparatus

    DOEpatents

    Deichelbohrer, Paul R [Richland, WA

    1986-01-01

    A portable, hand held electric arc saw has a small frame for supporting an electrically conducting rotary blade which serves as an electrode for generating an electric arc to erode a workpiece. Electric current is supplied to the blade by biased brushes and a slip ring which are mounted in the frame. A pair of freely movable endless belts in the form of crawler treads stretched between two pulleys are used to facilitate movement of the electric arc saw. The pulleys are formed of dielectric material to electrically insulate the crawler treads from the frame.

  9. Welding arc initiator

    DOEpatents

    Correy, Thomas B.

    1989-01-01

    An improved inert gas shielded tungsten arc welder is disclosed of the type wherein a tungsten electrode is shielded within a flowing inert gas, and, an arc, following ignition, burns between the energized tungsten electrode and a workpiece. The improvement comprises in combination with the tungsten electrode, a starting laser focused upon the tungsten electrode which to ignite the electrode heats a spot on the energized electrode sufficient for formation of a thermionic arc. Interference problems associated with high frequency starters are thus overcome.

  10. Welding arc initiator

    DOEpatents

    Correy, T.B.

    1989-05-09

    An improved inert gas shielded tungsten arc welder is disclosed of the type wherein a tungsten electrode is shielded within a flowing inert gas, and, an arc, following ignition, burns between the energized tungsten electrode and a workpiece. The improvement comprises in combination with the tungsten electrode, a starting laser focused upon the tungsten electrode which to ignite the electrode heats a spot on the energized electrode sufficient for formation of a thermionic arc. Interference problems associated with high frequency starters are thus overcome. 3 figs.

  11. Optical cavity furnace for semiconductor wafer processing

    DOEpatents

    Sopori, Bhushan L.

    2014-08-05

    An optical cavity furnace 10 having multiple optical energy sources 12 associated with an optical cavity 18 of the furnace. The multiple optical energy sources 12 may be lamps or other devices suitable for producing an appropriate level of optical energy. The optical cavity furnace 10 may also include one or more reflectors 14 and one or more walls 16 associated with the optical energy sources 12 such that the reflectors 14 and walls 16 define the optical cavity 18. The walls 16 may have any desired configuration or shape to enhance operation of the furnace as an optical cavity 18. The optical energy sources 12 may be positioned at any location with respect to the reflectors 14 and walls defining the optical cavity. The optical cavity furnace 10 may further include a semiconductor wafer transport system 22 for transporting one or more semiconductor wafers 20 through the optical cavity.

  12. A multi-zone muffle furnace design

    NASA Technical Reports Server (NTRS)

    Rowe, Neil D.; Kisel, Martin

    1993-01-01

    A Multi-Zone Muffle-Tube Furnace was designed, built, and tested for the purpose of providing an in-house experience base with tubular furnaces for materials processing in microgravity. As such, it must not only provide the desired temperatures and controlled thermal gradients at several discrete zones along its length but must also be capable of sustaining the rigors of a Space Shuttle launch. The furnace is insulated to minimize radial and axial heat losses. It is contained in a water-cooled enclosure for purposes of dissipating un-wanted residual heat, keeping the outer surfaces of the furnace at a 'touch-safe' temperature, and providing a rugged housing. This report describes the salient features of the furnace, testing procedures and results, and concluding remarks evaluating the overall design.

  13. Geochemical and ecotoxicological assessment of iron- and steel-making slags for potential use in environmental applications.

    PubMed

    Wendling, Laura A; Binet, Monique T; Yuan, Zheng; Gissi, Francesca; Koppel, Darren J; Adams, Merrin S

    2013-11-01

    Prior to the productive use of iron- and steel-making slags as environmental amendments, a risk assessment supported by material characterization concomitant with leaching and ecotoxicological testing is necessary. Five iron- and steel-making slags were characterized geochemically, and the leachability of their elemental constituents was assessed. The toxicity of slag leachate to microalgae (Chlorella sp.), cladocerans (Ceriodaphnia dubia), and bacteria (Vibrio fischeri) was related to elemental composition. Slag leachates with the highest concentrations of dissolved elements were the most toxic (10% effective concentration [EC10] ∼1%), whereas those with the lowest concentrations of elements were the least toxic (EC10 63-85%). It was not possible to determine which elements caused the observed toxicity; however, comparisons with contaminant guidelines and published toxicity data identified several elements of potential environmental concern. Low to moderate activities were measured for radionuclides in the U and Th decay chains in slags. Based on these data, some of the slags examined herein are potentially suitable for use as environmental amendments following ≥10 times dilution to ameliorate potential toxic effects because of leachate pH.

  14. Metal halide arc discharge lamp having short arc length

    NASA Technical Reports Server (NTRS)

    Muzeroll, Martin E. (Inventor)

    1994-01-01

    A metal halide arc discharge lamp includes a sealed light-transmissive outer jacket, a light-transmissive shroud located within the outer jacket and an arc tube assembly located within the shroud. The arc tube assembly includes an arc tube, electrodes mounted within the arc tube and a fill material for supporting an arc discharge. The electrodes have a spacing such that an electric field in a range of about 60 to 95 volts per centimeter is established between the electrodes. The diameter of the arc tube and the spacing of the electrodes are selected to provide an arc having an arc diameter to arc length ratio in a range of about 1.6 to 1.8. The fill material includes mercury, sodium iodide, scandium tri-iodide and a rare gas, and may include lithium iodide. The lamp exhibits a high color rendering index, high lumen output and high color temperature.

  15. Arc Voltage Between Deion Grid Affected by Division of Arc in Magnetic Driven Arc

    NASA Astrophysics Data System (ADS)

    Inuzuka, Yutaro; Yamato, Takashi; Yamamoto, Shinji; Iwao, Toru

    2016-10-01

    Magnetic driven arc has been applied to DC breaker and fault current limiters. However, it has not been researched, especially stagnation and re-strike of the arc. In this paper, the arc voltage between deion grid affected by division of arc in magnetic driven arc and arc behavior are measured by using the oscilloscope and HSVC (High Speed Video Camera). As a result, arc voltage increased because of division of the arc. The arc mean moving speed increases with increasing the external magnetic field. However, when the arc was not stalemate, the arc moving speed does not change so much. The arc re-strike time increases and stalemate time decreases with increasing the external magnetic field. Therefore, the anode spot moving speed increases 8 times because arc re-strike occurs easily with the external magnetic field. Thus, the erosion of electrodes decreases and the arc movement becomes the smooth. When the arc is divided, the arc voltage increased because of the electrode fall voltage. Therefore, the arc voltage increases with increasing the number of deion grid.

  16. Filtered cathodic arc source

    DOEpatents

    Falabella, S.; Sanders, D.M.

    1994-01-18

    A continuous, cathodic arc ion source coupled to a macro-particle filter capable of separation or elimination of macro-particles from the ion flux produced by cathodic arc discharge is described. The ion source employs an axial magnetic field on a cathode (target) having tapered sides to confine the arc, thereby providing high target material utilization. A bent magnetic field is used to guide the metal ions from the target to the part to be coated. The macro-particle filter consists of two straight solenoids, end to end, but placed at 45[degree] to one another, which prevents line-of-sight from the arc spot on the target to the parts to be coated, yet provides a path for ions and electrons to flow, and includes a series of baffles for trapping the macro-particles. 3 figures.

  17. Filtered cathodic arc source

    DOEpatents

    Falabella, Steven; Sanders, David M.

    1994-01-01

    A continuous, cathodic arc ion source coupled to a macro-particle filter capable of separation or elimination of macro-particles from the ion flux produced by cathodic arc discharge. The ion source employs an axial magnetic field on a cathode (target) having tapered sides to confine the arc, thereby providing high target material utilization. A bent magnetic field is used to guide the metal ions from the target to the part to be coated. The macro-particle filter consists of two straight solenoids, end to end, but placed at 45.degree. to one another, which prevents line-of-sight from the arc spot on the target to the parts to be coated, yet provides a path for ions and electrons to flow, and includes a series of baffles for trapping the macro-particles.

  18. Electric arc saw apparatus

    DOEpatents

    Deichelbohrer, P.R.

    1983-08-08

    A portable, hand-held electric arc saw apparatus comprising a small frame for supporting an electrically conducting rotary blade which serves as an electrode for generating an electric arc between the blade and a workpiece of opposite polarity. Electrically conducting means are provided on said frame for transmitting current to said blade. A pair of freely movable endless belts in the form of crawler treads are employed to facilitate movement of the apparatus relative to the workpiece.

  19. Cathodic ARC surface cleaning prior to brazing

    SciTech Connect

    Dave, V. R.; Hollis, K. J.; Castro, R. G.; Smith, F. M.; Javernick, D. A.

    2002-01-01

    Surface cleanliness is one the critical process variables in vacuum furnace brazing operations. For a large number of metallic components, cleaning is usually accomplished either by water-based alkali cleaning, but may also involve acid etching or solvent cleaning / rinsing. Nickel plating may also be necessary to ensure proper wetting. All of these cleaning or plating technologies have associated waste disposal issues, and this article explores an alternative cleaning process that generates minimal waste. Cathodic arc, or reserve polarity, is well known for welding of materials with tenacious oxide layers such as aluminum alloys. In this work the reverse polarity effect is used to clean austenitic stainless steel substrates prior to brazing with Ag-28%Cu. This cleaning process is compared to acid pickling and is shown to produce similar wetting behavior as measured by dynamic contact angle experiments. Additionally, dynamic contact angle measurements with water drops are conducted to show that cathodic arc cleaning can remove organic contaminants as well. The process does have its limitations however, and alloys with high titanium and aluminum content such as nickel-based superalloys may still require plating to ensure adequate wetting.

  20. A thermodynamic investigation into reactive-metal melting-furnace explosions

    NASA Astrophysics Data System (ADS)

    Evans, Steven C.; McLaughlin, David F.

    2005-10-01

    Western Zirconium, a plant in the Nuclear Fuels Business Unit of Westinghouse Electric Company, recently embarked on a significant safety-centered improvement to its vacuum-arc remelting (VAR) process. The improvement involved the relocation of the control room and installation of a programmable logic controller control strategy for the VAR furnaces. A critical consideration for the control strategy involved the implementation of the correct response to a breach in the water containment system that would allow water to contact the molten reactive metal in the furnace. Western Zirconium performed a random sampling of reactive metal melters in the United States to ascertain and evaluate the range of industry responses. Two distinct, and differing, approaches were discovered. In order to develop a better understanding and evaluate the responses, Western Zirconium, in conjunction with the Westinghouse Science and Technology Department, evaluated the thermodynamics involved in the reactions of molten reactive metals with water.

  1. Efficient 'Optical Furnace': A Cheaper Way to Make Solar Cells is Reaching the Marketplace

    SciTech Connect

    von Kuegelgen, T.

    2008-10-01

    In Bhushan Sopori's laboratory, you'll find a series of optical furnaces he has developed for fabricating solar cells. When not in use, they sit there discreetly among the lab equipment. But when a solar silicon wafer is placed inside one for processing, Sopori walks over to a computer and types in a temperature profile. Almost immediately this fires up the furnace, which glows inside and selectively heats up the silicon wafer to 800 degrees centigrade by the intense light it produces. Sopori, a principal engineer at the National Renewable Energy Laboratory, has been researching and developing optical furnace technology for around 20 years. He says it's a challenging technology to develop because there are many issues to consider when you process a solar cell, especially in optics. Despite the challenges, Sopori and his research team have advanced the technology to the point where it will benefit all solar cell manufacturers. They are now developing a commercial version of the furnace in partnership with a manufacturer. 'This advanced optical furnace is highly energy efficient, and it can be used to manufacture any type of solar cell,' he says. Each type of solar cell or manufacturing process typically requires a different furnace configuration and temperature profile. With NREL's new optical furnace system, a solar cell manufacturer can ask the computer for any temperature profile needed for processing a solar cell, and the same type of furnace is suitable for several solar cell fabrication process steps. 'In the future, solar cell manufacturers will only need this one optical furnace because it can be used for any process, including diffusion, metallization and oxidation,' Sopori says. 'This helps reduce manufacturing costs.' One startup company, Applied Optical Systems, has recognized the furnace's potential for manufacturing thin-film silicon cells. 'We'd like to develop thin-film silicon cells with higher efficiencies, up to 15 to 18 percent, and we believe

  2. Single-Heater, Three-Zone Furnace

    NASA Technical Reports Server (NTRS)

    Gernert, Nelson J.; Shauback, Robert M.

    1993-01-01

    Temperature profile shaped with help of thermal barriers. Proposed furnace for use in experiments on growth of crystals of highly pure material in ampoule provides three temperature zones, yet contains only one heat-pipe liner and one heater and operates with only one controller. Three temperature zones established as thermal resistances of wicks and noncondensible gas reduces flows of heat into channel containing ampoule. Motion of ampoule along channel causes gradients of temperature to move along specimen in ampoule. Variety of three-zone temperature profiles in furnace created by changing thermal resistances of zones and injecting noncondensible gas at appropriate point. Furnace used for variety of experiments.

  3. Toxic-Waste Disposal by Drain-in-Furnace Technique

    NASA Technical Reports Server (NTRS)

    Compton, L. E.; Stephens, J. B.; Moynihan, P. I.; Houseman, J.; Kalvinskas, J. J.

    1986-01-01

    Compact furnace moved from site to site. Toxic industrial waste destroyed using furnace concept developed for disposal of toxic munitions. Toxic waste drained into furnace where incinerated immediately. In furnace toxic agent rapidly drained and destroyed in small combustion chamber between upper and lower layers of hot ceramic balls

  4. 21. Photocopy of ca. 1951 view (when furnaces were still ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    21. Photocopy of ca. 1951 view (when furnaces were still in blast) looking north at central furnace complex with railroad cars of furnace charging materials in foreground and No. 2 Furnace at left. Photo marked on back 'David W. Corson from A. Devaney, N.Y.' - Sloss-Sheffield Steel & Iron, First Avenue North Viaduct at Thirty-second Street, Birmingham, Jefferson County, AL

  5. 20. Detail, Furnace A, shows the drill used to tap ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    20. Detail, Furnace A, shows the drill used to tap the furnace (at center left) and the 'mud gun' used to close it up with a clay plug (at lower right). Metal chute at center (next to drill) was used to clean out furnace prior to its abandonment. - Central Furnaces, 2650 Broadway, east bank of Cuyahoga River, Cleveland, Cuyahoga County, OH

  6. 46 CFR 164.009-13 - Furnace calibration.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 6 2012-10-01 2012-10-01 false Furnace calibration. 164.009-13 Section 164.009-13...: SPECIFICATIONS AND APPROVAL MATERIALS Noncombustible Materials for Merchant Vessels § 164.009-13 Furnace calibration. A calibration is performed on each new furnace and on each existing furnace as often as...

  7. 46 CFR 164.009-13 - Furnace calibration.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 6 2014-10-01 2014-10-01 false Furnace calibration. 164.009-13 Section 164.009-13...: SPECIFICATIONS AND APPROVAL MATERIALS Noncombustible Materials for Merchant Vessels § 164.009-13 Furnace calibration. A calibration is performed on each new furnace and on each existing furnace as often as...

  8. 46 CFR 164.009-11 - Furnace apparatus.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 6 2013-10-01 2013-10-01 false Furnace apparatus. 164.009-11 Section 164.009-11...: SPECIFICATIONS AND APPROVAL MATERIALS Noncombustible Materials for Merchant Vessels § 164.009-11 Furnace apparatus. (a) The test furnace apparatus consists of a furnace tube, stabilizer, draft shield,...

  9. 46 CFR 164.009-13 - Furnace calibration.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 6 2013-10-01 2013-10-01 false Furnace calibration. 164.009-13 Section 164.009-13...: SPECIFICATIONS AND APPROVAL MATERIALS Noncombustible Materials for Merchant Vessels § 164.009-13 Furnace calibration. A calibration is performed on each new furnace and on each existing furnace as often as...

  10. 46 CFR 164.009-11 - Furnace apparatus.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 6 2014-10-01 2014-10-01 false Furnace apparatus. 164.009-11 Section 164.009-11...: SPECIFICATIONS AND APPROVAL MATERIALS Noncombustible Materials for Merchant Vessels § 164.009-11 Furnace apparatus. (a) The test furnace apparatus consists of a furnace tube, stabilizer, draft shield,...

  11. 46 CFR 164.009-13 - Furnace calibration.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 6 2011-10-01 2011-10-01 false Furnace calibration. 164.009-13 Section 164.009-13...: SPECIFICATIONS AND APPROVAL MATERIALS Noncombustible Materials for Merchant Vessels § 164.009-13 Furnace calibration. A calibration is performed on each new furnace and on each existing furnace as often as...

  12. 46 CFR 164.009-11 - Furnace apparatus.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 6 2012-10-01 2012-10-01 false Furnace apparatus. 164.009-11 Section 164.009-11...: SPECIFICATIONS AND APPROVAL MATERIALS Noncombustible Materials for Merchant Vessels § 164.009-11 Furnace apparatus. (a) The test furnace apparatus consists of a furnace tube, stabilizer, draft shield,...

  13. 46 CFR 164.009-11 - Furnace apparatus.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 6 2011-10-01 2011-10-01 false Furnace apparatus. 164.009-11 Section 164.009-11...: SPECIFICATIONS AND APPROVAL MATERIALS Noncombustible Materials for Merchant Vessels § 164.009-11 Furnace apparatus. (a) The test furnace apparatus consists of a furnace tube, stabilizer, draft shield,...

  14. 46 CFR 164.009-13 - Furnace calibration.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 6 2010-10-01 2010-10-01 false Furnace calibration. 164.009-13 Section 164.009-13...: SPECIFICATIONS AND APPROVAL MATERIALS Noncombustible Materials for Merchant Vessels § 164.009-13 Furnace calibration. A calibration is performed on each new furnace and on each existing furnace as often as...

  15. 46 CFR 164.009-11 - Furnace apparatus.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 6 2010-10-01 2010-10-01 false Furnace apparatus. 164.009-11 Section 164.009-11...: SPECIFICATIONS AND APPROVAL MATERIALS Noncombustible Materials for Merchant Vessels § 164.009-11 Furnace apparatus. (a) The test furnace apparatus consists of a furnace tube, stabilizer, draft shield,...

  16. Destruction of hazardous military wastes using plasma arc technology

    SciTech Connect

    Kanaras, L.; Qazi, M.

    1996-12-31

    A Plasma Arc Technology (PAT) system treats hazardous wastes in a furnace, at temperatures of 2,000 C, or higher, using a plasma torch. The organic components vaporize, decompose or oxidize. The off-gases consist of hydrogen, carbon monoxide, carbon dioxide and nitric oxides. A wet air scrubber is used to remove most of these gases. The scrubber water is treated and recycled. Metal-bearing solids are melted or vaporized. The solids are usually recovered as molten metal, or as non-leachable vitrified slag, suitable for disposal in a landfill. A Plasma Arc Centrifugal Treatment system was used to evaluate this technology for destruction of four military hazardous wastes: sludge from Longhorn Army Ammunition Plant, TX; blast media from Letterkenny Army Depot, PA; medical incineration ash from Aberdeen Proving Ground, MD; and contaminated soil from open burning/open detonation ground at Picatinny Arsenal, NJ.

  17. Consolidating NASA's Arc Jets

    NASA Technical Reports Server (NTRS)

    Balboni, John A.; Gokcen, Tahir; Hui, Frank C. L.; Graube, Peter; Morrissey, Patricia; Lewis, Ronald

    2015-01-01

    The paper describes the consolidation of NASA's high powered arc-jet testing at a single location. The existing plasma arc-jet wind tunnels located at the Johnson Space Center were relocated to Ames Research Center while maintaining NASA's technical capability to ground-test thermal protection system materials under simulated atmospheric entry convective heating. The testing conditions at JSC were reproduced and successfully demonstrated at ARC through close collaboration between the two centers. New equipment was installed at Ames to provide test gases of pure nitrogen mixed with pure oxygen, and for future nitrogen-carbon dioxide mixtures. A new control system was custom designed, installed and tested. Tests demonstrated the capability of the 10 MW constricted-segmented arc heater at Ames meets the requirements of the major customer, NASA's Orion program. Solutions from an advanced computational fluid dynamics code were used to aid in characterizing the properties of the plasma stream and the surface environment on the calorimeters in the supersonic flow stream produced by the arc heater.

  18. Volatilization and redox testing in a DC arc melter: FY-93 and FY-94

    SciTech Connect

    Grandy, J.D.; Sears, J.W.; Soelberg, N.R.; Reimann, G.A.; McIlwain, M.E.

    1996-07-01

    The purpose of these experiments was to study the dissolution, retention, volatilization, and trapping of transuranic radionuclide elements (TRUs), mixed fission and activation products, and high vapor pressure metals (HVPMS) during processing in a high temperature arc furnace. In all cases, surrogate elements (lanthanides) were used in place of radioactive ones. The experiments were conducted utilizing a small DC arc melter developed at the Idaho National Engineering Laboratory (INEL) Research Center (IRC). The small arc melter was originally developed in 1992 and has been used previously for waste form studies of iron enriched basalt (IEB) and IEB with zirconium and titanium additions (IEB4). Section 3 contains a description of the small arc melter and its operational capabilities are discussed in Chapter 4. The remainder of the document describes each testing program and then discusses results and findings.

  19. 1. GENERAL VIEW OF BLAST FURNACE PLANT, KNOWN AS THE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. GENERAL VIEW OF BLAST FURNACE PLANT, KNOWN AS THE CARRIE FURNACES, FROM THE TOP OF WATER TOWER. CARRIE FURNACES No. 6 AND No. 7 ARE ON THE LEFT, AND FURNACES No. 3 AND No. 4 ARE ON THE RIGHT. THE TOWN OF RANKIN IS IN THE BACKGROUND. Jet Lowe, Photographer, 1989. - U.S. Steel Homestead Works, Blast Furnace Plant, Along Monongahela River, Homestead, Allegheny County, PA

  20. The UMass wind furnace blade design

    NASA Technical Reports Server (NTRS)

    Cromack, D. E.

    1978-01-01

    A brief description of the wind furnace concept is presented along with some preliminary performance data. Particular emphasis is placed on the design, construction, and manufacturing procedure for the 32.5 foot diameter GRP blades.

  1. Blast furnace supervision and control system

    SciTech Connect

    Remorino, M.; Lingiardi, O.; Zecchi, M.

    1997-12-31

    On December 1992, a group of companies headed by Techint, took over Somisa, the state-owned integrated steel plant located at San Nicolas, Province of Buenos Aires, Argentina, culminating an ambitious government privatization scheme. The blast furnace 2 went into a full reconstruction and relining in January 1995. After a 140 MU$ investment the new blast furnace 2 was started in September 1995. After more than one year of operation of the blast furnace the system has proven itself useful and reliable. The main reasons for the success of the system are: same use interface for all blast furnace areas -- operation, process, maintenance and management, (full horizontal and vertical integration); and full accessibility to all information and process tools though some restrictions apply to field commands (people empowerment). The paper describes the central system.

  2. Redesigned Electron-Beam Furnace Boosts Productivity

    NASA Technical Reports Server (NTRS)

    Williams, Gary A.

    1995-01-01

    Redesigned electron-beam furnace features carousel of greater capacity so more experiments conducted per loading, and time spent on reloading and vacuum pump-down reduced. Common mounting plate for electron source and carousel simplifies installation and reduces vibration.

  3. Multiple hearth furnace for reducing iron oxide

    DOEpatents

    Brandon, Mark M [Charlotte, NC; True, Bradford G [Charlotte, NC

    2012-03-13

    A multiple moving hearth furnace (10) having a furnace housing (11) with at least two moving hearths (20) positioned laterally within the furnace housing, the hearths moving in opposite directions and each moving hearth (20) capable of being charged with at least one layer of iron oxide and carbon bearing material at one end, and being capable of discharging reduced material at the other end. A heat insulating partition (92) is positioned between adjacent moving hearths of at least portions of the conversion zones (13), and is capable of communicating gases between the atmospheres of the conversion zones of adjacent moving hearths. A drying/preheat zone (12), a conversion zone (13), and optionally a cooling zone (15) are sequentially positioned along each moving hearth (30) in the furnace housing (11).

  4. Removable preheater elements improve oxide induction furnace

    NASA Technical Reports Server (NTRS)

    Leipold, M. H.

    1964-01-01

    Heat and corrosion resistant preheater elements are used in oxide induction furnaces to raise the temperature to the level for conducting electricity. These preheater elements are then removed and the induction coil energized.

  5. Chamberless residential warm air furnace design

    SciTech Connect

    Godfree, J.

    1996-07-01

    This brief paper is an introduction to the concept of designing residential warm air furnaces without combustion chambers. This is possible since some small burners do not require the thermal support of a combustion chamber to complete the combustion process.

  6. Control of arc length during gas metal arc welding

    SciTech Connect

    Madigan, R.B.; Quinn, T.P.

    1994-12-31

    An arc-length control system has been developed for gas metal arc welding (GMAW) under spray transfer welding conditions. The ability to monitor and control arc length during arc welding allows consistent weld characteristics to be maintained and therefore improves weld quality. Arc length control has only been implemented for gas tungsten arc welding (GTAW), where an automatic voltage control (AVC) unit adjusts torch-to-work distance. The system developed here compliments the voltage- and current-sensing techniques commonly used for control of GMAW. The system consists of an arc light intensity sensor (photodiode), a Hall-effect current sensor, a personal computer and software implementing a data interpretation and control algorithms. Arc length was measured using both arc light and arc current signals. Welding current was adjusted to maintain constant arc length. A proportional-integral-derivative (PID) controller was used. Gains were automatically selected based on the desired welding conditions. In performance evaluation welds, arc length varied from 2.5 to 6.5 mm while welding up a sloped workpiece (ramp in CTWD) without the control. Arc length was maintained within 1 mm of the desired (5 mm ) with the control.

  7. Translating Furnace For Fast Melting And Freezing

    NASA Technical Reports Server (NTRS)

    Workman, F.; Suggs, R. J.; Curreri, P. A.; Ethridge, E. C.; Perkinson, D. T.; Tucker, S.; Smith, G. A.

    1988-01-01

    Developmental translating-furnace apparatus used to make ceramic/metal composite materials during parabolic trajectories of KC-135 airplane simulating low gravity. Mathematical modeling shows apparatus able both to melt metal alloys and to solidify resulting composite specimens during 22-to-30-second low-gravity intervals. Furnace assembly moves along crucible in programmed manner to preheat, melt, and solidfy specimen during interval to less than 22 second.

  8. Copper staves in the blast furnace

    SciTech Connect

    Helenbrook, R.G.; Kowalski, W.; Grosspietsch, K.H.; Hille, H.

    1996-08-01

    Operational data for stave cooling systems for two German blast furnaces show good correlation with predicted thermal results. Copper staves have been installed in blast furnaces in the zones exposed to the highest thermal loads. The good operational results achieved confirm the choice of copper staves in the areas of maximum heat load. Both temperature measurements and predictions establish that the MAN GHH copper staves do not experience large temperature fluctuations and that the hot face temperatures will be below 250 F. This suggests that the copper staves maintain a more stable accretion layer than the cast iron staves. Contrary to initial expectations, heat flux to the copper staves is 50% lower than that to cast iron staves. The more stable accretion layer acts as an excellent insulator for the stave and greatly reduces the number of times the hot face of the stave is exposed to the blast furnace process and should result in a more stable furnace operation. In the future, it may be unnecessary to use high quality, expensive refractories in front of copper staves because of the highly stable accretion layer that appears to rapidly form due to the lower operating temperature of the staves. There is a balance of application regions for cast iron and copper staves that minimizes the capital cost of a blast furnace reline and provides an integrated cooling system with multiple campaign life potential. Cast iron staves are proven cooling elements that are capable of multiple campaign life in areas of the blast furnace which do not experience extreme heat loads. Copper staves are proving to be an effective and reliable blast furnace cooling element that are subject to virtually no wear and are projected to have a longer campaign service life in the areas of highest thermal load in the blast furnace.

  9. Quality of coal for blast furnace injection

    SciTech Connect

    Hutny, W.P.; Giroux, L.; MacPhee, J.A.; Price, J.T.

    1996-12-31

    CANMET Energy Technology Centre (CETC) has been involved in a research program to evaluate the suitability of various coals for blast furnace injection. The primary objectives of this program are to provide essential information on coal combustion in the blast furnace and to establish proper criteria for evaluating and selecting coals for blast furnace injection. The program comprises three parts. Parts one and two have been completed. To date, the program has encompassed both a theoretical assessment of cooling and coke replacement characteristics of coals using CETC`s computer model and an experimental determination of the combustibility of coals of different ranks and particle sizes as well as the influence of oxygen enrichment on burnout. The experimental part was conducted in CETC`s pilot-scale injection unit that simulates blast furnace blowpipe-tuyere conditions. Part three now being developed will incorporate results of experimental trials into a blast furnace raceway model in order to predict total combustibility of coals at different blast furnace operating conditions. This paper describes CETC`s facility and methodology of work, and presents and discusses results.

  10. Firing temperature accuracy of four dental furnaces.

    PubMed

    Haag, Per; Ciber, Edina; Dérand, Tore

    2011-01-01

    In spite of using recommended firing and displayed temperatures, low-fired dental porcelain more often demonstrates unsatisfactory results after firing than porcelain fired at higher temperatures. It could therefore be anticipated that temperatures shown on the display are incorrect, implying that the furnace does not render correct firing programs for low-fired porcelain. The purpose of this study is to investigate deviations from the real temperature during the firing process and also to illustrate the service and maintenance discipline of furnaces at dental laboratories. Totally 20 units of four different types of dental furnaces were selected for testing of temperature accuracy with usage of a digital temperature measurement apparatus, Therma 1. In addition,the staffs at 68 dental laboratories in Sweden were contacted for a telephone interview on furnace brand and on service and maintenance program performed at their laboratories. None of the 20 different dental furnaces in the study could generate the firing temperatures shown on the display, indicating that the hypothesis was correct. Multimat MCII had the least deviation of temperature compared with displayfigures. 62 out of 68 invited dental laboratories chose to participate in the interviews and the result was that very few laboratories had a service and maintenance program living up to quality standards. There is room for improving the precision of dental porcelain furnaces as there are deviations between displayed and read temperatures during the different steps of the firing process.

  11. Information modeling system for blast furnace control

    NASA Astrophysics Data System (ADS)

    Spirin, N. A.; Gileva, L. Y.; Lavrov, V. V.

    2016-09-01

    Modern Iron & Steel Works as a rule are equipped with powerful distributed control systems (DCS) and databases. Implementation of DSC system solves the problem of storage, control, protection, entry, editing and retrieving of information as well as generation of required reporting data. The most advanced and promising approach is to use decision support information technologies based on a complex of mathematical models. The model decision support system for control of blast furnace smelting is designed and operated. The basis of the model system is a complex of mathematical models created using the principle of natural mathematical modeling. This principle provides for construction of mathematical models of two levels. The first level model is a basic state model which makes it possible to assess the vector of system parameters using field data and blast furnace operation results. It is also used to calculate the adjustment (adaptation) coefficients of the predictive block of the system. The second-level model is a predictive model designed to assess the design parameters of the blast furnace process when there are changes in melting conditions relative to its current state. Tasks for which software is developed are described. Characteristics of the main subsystems of the blast furnace process as an object of modeling and control - thermal state of the furnace, blast, gas dynamic and slag conditions of blast furnace smelting - are presented.

  12. Solar Convective Furnace for Metals Processing

    NASA Astrophysics Data System (ADS)

    Patidar, Deepesh; Tiwari, Sheetanshu; Sharma, Piyush; Pardeshi, Ravindra; Chandra, Laltu; Shekhar, Rajiv

    2015-11-01

    Metals processing operations, primarily soaking, heat treatment, and melting of metals are energy-intensive processes using fossil fuels, either directly or indirectly as electricity, to operate furnaces at high temperatures. Use of concentrated solar energy as a source of heat could be a viable "green" option for industrial heat treatment furnaces. This paper introduces the concept of a solar convective furnace which utilizes hot air generated by an open volumetric air receiver (OVAR)-based solar tower technology. The potential for heating air above 1000°C exists. Air temperatures of 700°C have already been achieved in a 1.5-MWe volumetric air receiver demonstration plant. Efforts to retrofit an industrial aluminium soaking furnace for integration with a solar tower system are briefly described. The design and performance of an OVAR has been discussed. A strategy for designing a 1/15th-scale model of an industrial aluminium soaking furnace has been presented. Preliminary flow and thermal simulation results suggest the presence of recirculating flow in existing furnaces that could possibly result in non-uniform heating of the slabs. The multifarious uses of concentrated solar energy, for example in smelting, metals processing, and even fuel production, should enable it to overcome its cost disadvantage with respect to solar photovoltaics.

  13. Numerical Simulation of the Interaction Between Supersonic Oxygen Jets and Molten Slag-Metal Bath in Steelmaking BOF Process

    NASA Astrophysics Data System (ADS)

    Li, Qiang; Li, Mingming; Kuang, Shibo; Zou, Zongshu

    2015-02-01

    The impinging of multiple jets onto the molten bath in the BOF steelmaking process plays a crucial role in reactor performance but is not clearly understood. This paper presents a numerical study of the interaction between the multiple jets and slag-metal bath in a BOF by means of the three-phase volume of fluid model. The validity of the model is first examined by comparing the numerical results with experimental measurement of time-averaged cavity dimensions through a scaled-down water model. The calculated results are in reasonably good agreement with the experimental data. The mathematical model is then used to investigate the primary transport phenomena of the jets-bath interaction inside a 150-ton commercial BOF under steelmaking conditions. The numerical results show that the cavity profile and interface of slag/metal/gas remain unstable as a result of the propagation of surface waves, which, likely as a major factor, governs the generation of metal droplets and their initial spatiotemporal distribution. The total momentum transferred from the jets into the bath is consumed about a half to drive the movement of slag, rather than fully converted as the stirring power for the metal bath. Finally, the effects of operational conditions and fluid properties are quantified. It is shown that compared to viscosity and surface tension of the melts, operating pressure and lance height have a much more significant impact on the slag-metal interface behavior and cavity shape as well as the fluid dynamics in the molten bath.

  14. AISI/DOE Advanced Process Control Program Vol. 1 of 6: Optical Sensors and Controls for Improved Basic Oxygen Furnace Operations

    SciTech Connect

    Sarah Allendorf; David Ottesen; Donald Hardesty

    2002-01-31

    The development of an optical sensor for basic oxygen furnace (BOF) off-gas composition and temperature in this Advanced Process Control project has been a laboratory spectroscopic method evolve into a pre-commercialization prototype sensor system. The sensor simultaneously detects an infrared tunable diode laser ITDL beam transmitted through the process off-gas directly above the furnace mouth, and the infrared greybody emission from the particulate-laden off-gas stream. Following developmental laboratory and field-testing, the sensor prototype was successfully tested in four long-term field trials at Bethlehem Steel's Sparrows Point plant in Baltimore, MD> The resulting optical data were analyzed and reveal correlations with four important process variables: (1) bath turndown temperature; (2) carbon monoxide post-combustion control; (2) bath carbon concentration; and (4) furnace slopping behavior. The optical sensor measurement of the off-gas temperature is modestly correlated with bath turndown temperature. A detailed regression analysis of over 200 heats suggests that a dynamic control level of +25 Degree F can be attained with a stand-alone laser-based optical sensor. The ability to track off-gas temperatures to control post-combustion lance practice is also demonstrated, and may be of great use in optimizing post-combustion efficiency in electric furnace steelmaking operations. In addition to the laser-based absorption spectroscopy data collected by this sensor, a concurrent signal generated by greybody emission from the particle-laden off-gas was collected and analyzed. A detailed regression analysis shows an excellent correlation of a single variable with final bath turndown carbon concentration. Extended field trials in 1998 and early 1999 show a response range from below 0.03% to a least 0.15% carbon concentration with a precision of +0.0007%. Finally, a strong correlation between prolonged drops in the off-gas emission signal and furnace slopping events

  15. Arc electrode interaction study

    NASA Technical Reports Server (NTRS)

    Zhou, X.; Berns, D.; Heberlein, J.

    1994-01-01

    The project consisted of two parts: (1) the cathode interaction studies which were a continuation of previous work and had the objective of increasing our understanding of the microscopic phenomena controlling cathode erosion in arc jet thrusters, and (2) the studies of the anode attachment in arc jet thrusters. The cathode interaction studies consisted of (1) a continuation of some modeling work in which the previously derived model for the cathode heating was applied to some specific gases and electrode materials, and (2) experimental work in which various diagnostics was applied to the cathode. The specific diagnostics used were observation of the cathode tip during arcing using a Laser Strobe Video system in conjunction with a tele-microscope, a monochromator with an optical multichannel analyzer for the determination of the cathode temperature distribution, and various ex situ materials analysis methods. The emphasis of our effort was shifted to the cathode materials analysis because a parallel project was in place during the second half of 1993 with a visiting scientist pursuing arc electrode materials studies. As a consequence, the diagnostic investigations of the arc in front of the cathode had to be postponed to the first half of 1994, and we are presently preparing these measurements. The results of last year's study showed some unexpected effects influencing the cathode erosion behavior, such as increased erosion away from the cathode tip, and our understanding of these effects should improve our ability to control cathode erosion. The arc jet anode attachment studies concentrated on diagnostics of the instabilities in subsonic anode attachment arc jet thrusters, and were supplemental measurements to work which was performed by one of the authors who spent the summer as an intern at NASA Lewis Research Center. A summary of the results obtained during the internship are included because they formed an integral part of the study. Two tasks for 1994, the

  16. Pulsed Long Arc Welding

    NASA Astrophysics Data System (ADS)

    Krampit, N. Yu

    2016-04-01

    The paper presents a method and an appliance for pulsed arc welding. The method supports dosage of energy required for melting each bead of electrode metal starting from the detachment of a bead. The appliance including a sensor to register bead detachment shows this moment due to the voltage burst in the arc space. Transferred beads of electrode metal are of similar size because of the dosage of energy used for melting each bead, as the consequence, the process is more stable and starting conditions to transfer electrode metal are similar, as the result, a produced weld is improved.

  17. ARc Welding (Industrial Processing Series).

    DTIC Science & Technology

    ARC WELDING , *BIBLIOGRAPHIES), (*ARC WELDS, BIBLIOGRAPHIES), ALUMINUM ALLOYS, TITANIUM ALLOYS, CHROMIUM ALLOYS, METAL PLATES, SPOT WELDING , STEEL...INERT GAS WELDING , MARAGING STEELS, MICROSTRUCTURE, HEAT RESISTANT ALLOYS, HEAT RESISTANT METALS, WELDABILITY, MECHANICAL PROPERTIES, MOLYBDENUM ALLOYS, NICKEL ALLOYS, RESISTANCE WELDING

  18. Increasing blast furnace productivity. Is there a universal solution for all blast furnaces?

    SciTech Connect

    Chaubal, P.C.; Ranade, M.G.

    1997-12-31

    In the past few years there has been a major effort in the integrated plants in the US to increase blast furnace productivity. Record production levels have been reported by AK Steel using direct reduced/hot briquetted iron (DRI/HBI) and high levels of natural gas (NG)-oxygen injection at their Middletown blast furnace. Similarly, US Steel-Gary No. 13 reported high productivity levels with PCI and oxygen enrichment. A productivity of 6 NTHM/day/100 ft{sup 3}WV was the norm in the past, but today levels higher than 11 NTHM/day/100ft{sup 3}WV have been reached on a sustained basis. These high productivity levels have been an important aspect of facility rationalization efforts, as companies seek to maximize their throughput while reducing costs. Hot metal demand in a particular plant depends on downstream capabilities in converting hot metal to saleable steel. Single vs. multi-furnace plants may have different production requirements for each facility. Business cycles may influence productivity requirements from different furnaces of a multiple furnace plant, more so for those considered as swing furnaces. Therefore, the production requirement for individual blast furnaces is different for different plants. In an effort to understand productivity improvement methods, calculations were made for a typical 8 m hearth diameter furnace using data and experience gathered on Inland`s operation. Here the authors present the results obtained in the study.

  19. Thermal Arc Spray Overview

    NASA Astrophysics Data System (ADS)

    Hafiz Abd Malek, Muhamad; Hayati Saad, Nor; Kiyai Abas, Sunhaji; Mohd Shah, Noriyati

    2013-06-01

    Usage of protective coating for corrosion protection was on highly demand during the past decade; and thermal spray coating played a major part during that time. In recent years, the thermal arc spray coating becomes a popular coating. Many big players in oil and gas such as PETRONAS, EXXON MOBIL and SHELL in Malaysia tend to use the coating on steel structure as a corrosion protection. Further developments in coating processes, the devices, and raw materials have led to expansion of functional coatings and applications scope from conventional coating to specialized industries. It is widely used because of its ability to withstand high process temperature, offer advantages in efficiency, lower cost and acts as a corrosion protection. Previous research also indicated that the thermal arc spray offers better coating properties compared to other methods of spray. This paper reviews some critical area of thermal spray coating by discussing the process/parameter of thermal arc spray technology and quality control of coating. Coating performance against corrosion, wear and special characteristic of coating are also described. The field application of arc spray technology are demonstrated and reviewed.

  20. Variable polarity arc welding

    NASA Technical Reports Server (NTRS)

    Bayless, E. O., Jr.

    1991-01-01

    Technological advances generate within themselves dissatisfactions that lead to further advances in a process. A series of advances in welding technology which culminated in the Variable Polarity Plasma Arc (VPPA) Welding Process and an advance instituted to overcome the latest dissatisfactions with the process: automated VPPA welding are described briefly.

  1. Gas tungsten arc welder

    DOEpatents

    Christiansen, D.W.; Brown, W.F.

    A welder for automated closure of fuel pins by a gas tungsten arc process in which a rotating length of cladding is positioned adjacent a welding electrode in a sealed enclosure. An independently movable axial grinder is provided in the enclosure for refurbishing the used electrode between welds.

  2. Arc Length Gone Global

    ERIC Educational Resources Information Center

    Boudreaux, Gregory M.; Wells, M. Scott

    2007-01-01

    Everyone with a thorough knowledge of single variable calculus knows that integration can be used to find the length of a curve on a given interval, called its arc length. Fortunately, if one endeavors to pose and solve more interesting problems than simply computing lengths of various curves, there are techniques available that do not require an…

  3. Computational simulations and experimental validation of a furnace brazing process

    SciTech Connect

    Hosking, F.M.; Gianoulakis, S.E.; Malizia, L.A.

    1998-12-31

    Modeling of a furnace brazing process is described. The computational tools predict the thermal response of loaded hardware in a hydrogen brazing furnace to programmed furnace profiles. Experiments were conducted to validate the model and resolve computational uncertainties. Critical boundary conditions that affect materials and processing response to the furnace environment were determined. {open_quotes}Global{close_quotes} and local issues (i.e., at the furnace/hardware and joint levels, respectively) are discussed. The ability to accurately simulate and control furnace conditions is examined.

  4. 94. Photocopied August 1978. THE FURNACE ROOM ON THE SECOND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    94. Photocopied August 1978. THE FURNACE ROOM ON THE SECOND FLOOR OF THE POWER HOUSE AT SAULT STE. MARIE. THE ROWS OF ROTARY FURNACES SHOWN HERE WERE REPLACED C. 1915-1920 BY 10,000 TO 20,000 H.P. TAPPING FURNACES. ONE TAPPING FURNACE WAS LOCATED TO THE WEST OF THE ROW OF HORRY FURNACES, THE OTHER WAS LOCATED IN A SEPARATE FURNACE HOUSE BUILT ON THE EAST OF THE POWER HOUSE. (E) - Michigan Lake Superior Power Company, Portage Street, Sault Ste. Marie, Chippewa County, MI

  5. Standard operating procedure: Gas atmosphere MELCO brazing furnace

    SciTech Connect

    Waller, C.R.

    1988-08-01

    A hydrogen and argon gas atmosphere furnace facility using electric furnaces is located at the Clinton P. Anderson Meson Physics Facility (LAMPF). This furnace system was acquired to handle smaller jobs with a more rapid response time than was possible with the larger furnaces. Accelerator- and experimental-related components best assembled by atmosphere brazing techniques are routinely processed by this facility in addition to special heat treatment and bakeout heats. The detailed operation sequence and description of the MELCO furnace system are covered by this report. This document is to augment LA-10231-SOP, which describes the operation of the large furnace systems. 6 figs.

  6. The Phosphorus Reaction in Oxygen Steelmaking: Thermodynamic Equilibrium and Metal Droplet Behavior

    NASA Astrophysics Data System (ADS)

    Assis, Andre N.

    Phosphorus equilibrium between liquid metal and slag has been extensively studied since the 1940's. It is well known that CaO and FeO are the main slag constituents that help promote dephosphorization. On the other hand, dephosphorization decreases with temperature due to the endothermic nature of the reaction. Many correlations have been developed to predict the phosphorus partition ratio as a function of metal and slag composition as well as temperature. Nevertheless, there are still disagreements in the laboratory data and the equilibrium phosphorus partition can be predicted with an uncertainty of a factor of up to 5. The first part of the present work focuses on generating more reliable equilibrium data for BOF-type slags by approaching equilibrium from both sides of the reaction. The experimental results were combined with two other sets of data from different authors to produce a new correlation that includes the effect of SiO2 on the phosphorus partition coefficient, LP . Although the quantification of phosphorus equilibrium is extremely important, most industrial furnaces do not operate at equilibrium, usually due to liquid slag formation, kinetics and time constraints. Thus, it is important to know how close to equilibrium different furnaces operate in order to suggest optimal slag compositions to promote dephosphorization. The present work analyzed four large sets of data containing the chemical compositions of both slag and metal phase as well as the tapping temperature of each heat. Each set of data corresponded to different furnaces: one AOD (Argon Oxygen Decarburization), two top-blown BOFs and one Q-BOP or OBM. It was found that the bulk slag composition can greatly "mask" the data due to solid phases coexisting with the liquid slag. The author used the software package FactSage to estimate the amount of solids in the slag and liquid slag composition. It was found that the AOD is the reactor closest to equilibrium, followed by the Q-BOP (OBM) and

  7. High temp vacuum furnace offers new option

    SciTech Connect

    1995-12-11

    Vacuum furnaces operating up to 2,350 F are commonly used for metallurgical processes such as hardening tool steels, treating super alloys, power metal sintering, and brazing. Traditionally electric, these furnaces are costly to operate and maintain. They are often sensitivity to impurities driven off work pieces in the heating chamber because the vapors condense on the walls of the heating chamber and negatively effect operation. The gas-fired vacuum furnace now in development by Surface Combustion, with support from the Gas Research Institute (GRI) will, however, have none of the drawbacks of the electric models while maintaining or improving on performance. Costly electric operating and demand charges will be avoided through the use of natural gas as a fuel. Its ``hot wall`` furnace design means that impurities driven off the work piece can be pulled out of the chamber before they condense. Because ceramic radiant tubes will be used in conjunction with the hot wall design, temperature uniformity and productivity are expected to equal, or surpass, that of the electric furnaces.

  8. Carbon monoxide exposure in blast furnace workers.

    PubMed

    Lewis, S; Mason, C; Srna, J

    1992-09-01

    This study investigated the occupational exposure to carbon monoxide (CO) of a group of blast furnace workers from an integrated steelworks, compared to a control group having no significant occupational CO exposure from other areas in the same works. The study was undertaken in 1984 at Port Kembla, New South Wales. Carboxyhaemoglobin (COHb) levels before and after an eight-hour work shift were measured in 98 male steelworkers: 52 from two CO-exposed iron blast furnaces and 46 controls from production areas in the same steelworks. The sample was stratified by smoking habits. Environmental air CO levels had been found to be consistently higher on one furnace than on the other. Absorption of CO from the working environment occurred in workers on the blast furnace with higher CO levels, regardless of smoking habits. On this blast furnace, some readings of COHb levels after a workshift in nonsmokers approached the proposed Australian occupational limit of 5 per cent COHb saturation. Overall, workers with the highest occupational exposure who smoked most heavily had the highest absorption of CO over a work shift. Biological monitoring gives an accurate measure of individual worker 'dose' of CO from all sources. Both environmental monitoring and biological monitoring need to be included as part of a program for controlling occupational CO exposure.

  9. Hall-effect arc protector

    DOEpatents

    Rankin, Richard A.; Kotter, Dale K.

    1997-01-01

    The Hall-Effect Arc Protector is used to protect sensitive electronics from high energy arcs. The apparatus detects arcs by monitoring an electrical conductor, of the instrument, for changes in the electromagnetic field surrounding the conductor which would be indicative of a possible arcing condition. When the magnitude of the monitored electromagnetic field exceeds a predetermined threshold, the potential for an instrument damaging are exists and the control system logic activates a high speed circuit breaker. The activation of the breaker shunts the energy imparted to the input signal through a dummy load to the ground. After the arc condition is terminated, the normal signal path is restored.

  10. Hall-effect arc protector

    DOEpatents

    Rankin, R.A.; Kotter, D.K.

    1997-05-13

    The Hall-Effect Arc Protector is used to protect sensitive electronics from high energy arcs. The apparatus detects arcs by monitoring an electrical conductor, of the instrument, for changes in the electromagnetic field surrounding the conductor which would be indicative of a possible arcing condition. When the magnitude of the monitored electromagnetic field exceeds a predetermined threshold, the potential for an instrument damaging are exists and the control system logic activates a high speed circuit breaker. The activation of the breaker shunts the energy imparted to the input signal through a dummy load to the ground. After the arc condition is terminated, the normal signal path is restored. 2 figs.

  11. Evaluating the Relationship between Slabbing of Cr2O3/MgO Refractories Used in Steelmaking and Spalling of High Chrome Oxide Refractories Used in Gasification

    SciTech Connect

    Bennett, J.P.; Thomas, H.; Kwong, K.-S.

    2006-10-01

    Because of its excellent corrosion resistance and high temperature properties, chrome oxide refractories have been used in a number of severe service environments, including steelmaking and gasification. Refractory failure of Cr2O3/MgO or MgO/Cr2O3 refractories in steelmaking can involve a phenomena called slabbing, peeling, or chemical spalling. A similar failure mechanism exists in the high chrome oxide materials used in gasification. Gasifiers contain the reaction between a carbon feedstock, water, and oxygen under reducing conditions; producing H2 and CO used in chemicals or as fuel for power plants. A slagging gasifier typically operates between 1250- 1575°C, and with pressures between 300-1000 psi. Gasification refractory failure is by chemical dissolution and/or by spalling. Spalling is caused by slag penetration of the porous refractory surface and by expansion differences between the penetrated/non-penetrated areas, and is exacerbated by thermal cycling. Similarities between slabbing of steelmaking refractories and spalling of gasification refractories will be discussed.

  12. Semicircular Rashba arc spin polarizer

    SciTech Connect

    Bin Siu, Zhuo; Jalil, Mansoor B. A.; Ghee Tan, Seng

    2014-05-07

    In this work, we study the generation of spin polarized currents using curved arcs of finite widths, in which the Rashba spin orbit interaction (RSOI) is present. Compared to the 1-dimensional RSOI arcs with zero widths studied previously, the finite width presents charge carriers with another degree of freedom along the transverse width of the arc, in addition to the longitudinal degree of freedom along the circumference of the arc. The asymmetry in the transverse direction due to the difference in the inner and outer radii of the arc breaks the antisymmetry of the longitudinal spin z current in a straight RSOI segment. This property can be exploited to generate spin z polarized current output from the RSOI arc by a spin unpolarized current input. The sign of the spin current can be manipulated by varying the arc dimensions.

  13. Cogeneration from glass furnace waste heat recovery

    SciTech Connect

    Hnat, J.G.; Cutting, J.C.; Patten, J.S.

    1982-06-01

    In glass manufacturing 70% of the total energy utilized is consumed in the melting process. Three basic furnaces are in use: regenerative, recuperative, and direct fired design. The present paper focuses on secondary heat recovery from regenerative furnaces. A diagram of a typical regenerative furnace is given. Three recovery bottoming cycles were evaluated as part of a comparative systems analysis: steam Rankine Cycle (SRC), Organic Rankine Cycle (ORC), and pressurized Brayton cycle. Each cycle is defined and schematicized. The net power capabilities of the three different systems are summarized. Cost comparisons and payback period comparisons are made. Organic Rankine cycle provides the best opportunity for cogeneration for all the flue gas mass flow rates considered. With high temperatures, the Brayton cycle has the shortest payback period potential, but site-specific economics need to be considered.

  14. HOLLOW CARBON ARC DISCHARGE

    DOEpatents

    Luce, J.S.

    1960-10-11

    A device is described for producing an energetic, direct current, hollow, carbon-arc discharge in an evacuated container and within a strong magnetic field. Such discharges are particularly useful not only in dissociation and ionization of high energy molecular ion beams, but also in acting as a shield or barrier against the instreaming of lowenergy neutral particles into a plasma formed within the hollow discharge when it is used as a dissociating mechanism for forming the plasma. There is maintained a predetermined ratio of gas particles to carbon particles released from the arc electrodes during operation of the discharge. The carbon particles absorb some of the gas particles and are pumped along and by the discharge out of the device, with the result that smaller diffusion pumps are required than would otherwise be necessary to dispose of the excess gas.

  15. Arc jet diagnostics tests

    NASA Technical Reports Server (NTRS)

    Willey, Ronald J.

    1989-01-01

    Two objectives were addressed during a 10 week 1988 NASA/ASEE summer faculty fellowship at the Johnson Space Center Atmospheric Reentry Materials Structures Evaluation Facility (ARMSEF). These objectives were the evaluation of mass spectrometry for the measurement of atomic and molecular species in an arc jet environment, and the determination of atomic recombination coefficients for reaction cured glass (RCG) coated high temperature surface insulation (HRSI) materials subjected to simulated reentry conditions. Evaluation of mass spectrometry for the measurement of atomic and molecular species provided some of the first measurements of point compositions in arc jet tunnel environments. A major objective of this project centered around the sampling residence time. A three staged vacuum sampling system pulled the molecules and atoms from the arc jet to a quadrupole ionization mass spectrometer in 400 milliseconds. Conditions investigated included a composition survey across the nozzle exit at 3 cm z-distance from the nozzle exit for 3 different currents. Also, a point composition survey was taken around a shock created by the presence of a blunt body.

  16. SOUTHERN DUCTILE CASTING COMPANY, BACK SIDE OF FURNACE AND MOLDING ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    SOUTHERN DUCTILE CASTING COMPANY, BACK SIDE OF FURNACE AND MOLDING BUILDINGS SHOWING CONNECTIONS TO LOCAL POWER GRID, PRIMARILY FOR ELECTRIC FURNACES. - Southern Ductile Casting Company, Bessemer Foundry, 2217 Carolina Avenue, Bessemer, Jefferson County, AL

  17. GENERAL VIEW OF TURBOBLOWER BUILDING (LEFT), BLAST FURNACE (CENTER), AND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    GENERAL VIEW OF TURBO-BLOWER BUILDING (LEFT), BLAST FURNACE (CENTER), AND HOT BLAST STOVES (RIGHT). - Republic Iron & Steel Company, Youngstown Works, Haselton Blast Furnaces, West of Center Street Viaduct, along Mahoning River, Youngstown, Mahoning County, OH

  18. 1. LOOKING EAST AT BLAST FURNACES NO. 3 AND No. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. LOOKING EAST AT BLAST FURNACES NO. 3 AND No. 4 FROM CRAWFORD STREET IN THE CITY OF DUQUESNE. (Martin Stupich) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  19. 13. SOUTHWEST VIEW OF CAST HOUSE No. 1, BLAST FURNACE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    13. SOUTHWEST VIEW OF CAST HOUSE No. 1, BLAST FURNACE No. 1, AND HOIST HOUSE No. 1. (Martin Stupich) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  20. 35. CARRIE FURNACE No. 6 AND CAST HOUSE. THE CARRIE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    35. CARRIE FURNACE No. 6 AND CAST HOUSE. THE CARRIE BOILER SHOP IS ON THE RIGHT, IN FRONT OF HOT BLAST STOVES. - U.S. Steel Homestead Works, Blast Furnace Plant, Along Monongahela River, Homestead, Allegheny County, PA

  1. Looking east at blast furnace no. 5 between the hot ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking east at blast furnace no. 5 between the hot blast stoves (left) and the dustcatcher (right). - U.S. Steel Edgar Thomson Works, Blast Furnace Plant, Along Monongahela River, Braddock, Allegheny County, PA

  2. 33. BOILER HOUSE FURNACE AND BOILER Close view of ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    33. BOILER HOUSE - FURNACE AND BOILER Close view of the Dorward Engineering Company furnace and boiler which provided steam to the cooking retorts in the adjacent room. - Hovden Cannery, 886 Cannery Row, Monterey, Monterey County, CA

  3. 42. Casting floor, "B" furnace, pour in progress; mudgun is ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    42. Casting floor, "B" furnace, pour in progress; mudgun is to right of furnace; operator takes temperature of iron in trough during pout. Looking south - Rouge Steel Company, 3001 Miller Road, Dearborn, MI

  4. 20. DETAILED OBLIQUE VIEW SOUTHWEST FURNACE 2, SHOWING STEEL FRAME ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    20. DETAILED OBLIQUE VIEW SOUTHWEST FURNACE 2, SHOWING STEEL FRAME BOXES FOR COUNTERWEIGHTS, AND FURNACE HEATING PIPES AT RIGHT. - Vulcan Crucible Steel Company, Building No. 3, 100 First Street, Aliquippa, Beaver County, PA

  5. 22. DETAIL OBLIQUE VIEW NORTHWEST OF FURNACE 2, SHOWING GENERAL ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    22. DETAIL OBLIQUE VIEW NORTHWEST OF FURNACE 2, SHOWING GENERAL CONSTRUCTION. CONCRETE PAD AT LEFT IS SITE OF FORMER FURNACE USED TO HEAT URANIUM BILLETS. - Vulcan Crucible Steel Company, Building No. 3, 100 First Street, Aliquippa, Beaver County, PA

  6. 6. Photocopy of a drawing of the lead blast furnace ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. Photocopy of a drawing of the lead blast furnace from J.L. Bray, The Principles of Metallurgy, Ginn & Co. New York, 1929. - International Smelting & Refining Company, Tooele Smelter, Blast Furnace Building, State Route 178, Tooele, Tooele County, UT

  7. INTERIOR VIEW LOOKING NORTHEAST, SHOWING FURNACE NO. 1 (ca. 1910. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW LOOKING NORTHEAST, SHOWING FURNACE NO. 1 (ca. 1910. Nameplate reads: "Heroult Electric Furnace, Capacity 6 tons, Built by American Bridge Company, Pencoyd, PA, No. 33") - Braeburn Alloy Steel, Braeburn Road at Allegheny River, Lower Burrell, Westmoreland County, PA

  8. 3. INSIDE BATCH FURNACE BUILDING, VIEW LOOKING NORTH AT REGENERATIVE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. INSIDE BATCH FURNACE BUILDING, VIEW LOOKING NORTH AT REGENERATIVE BATCH FURNACES ON LEFT AND 5 TON CAPACITY CHARGING MACHINE ON RIGHT. - U.S. Steel Duquesne Works, 22-Inch Bar Mill, Along Monongahela River, Duquesne, Allegheny County, PA

  9. TECHNOLOGY EVALUATION REPORT: RETECH'S PLASMA CENTRIFUGAL FURNACE - VOLUME I

    EPA Science Inventory

    A demonstration of the Retech, Inc. Plasma Centrifugal Furnace (PCF) was conducted under the Superfund Innovative Technology Evaluation (SITE) Program at the Department of Energy's (DOE's) Component Development and Integration Facility in Butte, Montana. The furnace uses heat gen...

  10. 58. LOOKING EAST DOROTHY SIX BLAST FURNACE WITH BRICK SHED ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    58. LOOKING EAST DOROTHY SIX BLAST FURNACE WITH BRICK SHED No. 3 IN FOREGROUND ON RIGHT. (Jet Lowe) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  11. 31. VIEW OF TRIPPER CAR ON TOP OF BLAST FURNACE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    31. VIEW OF TRIPPER CAR ON TOP OF BLAST FURNACE STOCKING TRESTLE LOOKING EAST. (Martin Stupich) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  12. 55. GENERAL NORTHEASTERN VIEW OF DOROTHY SIX BLAST FURNACE COMPLEX ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    55. GENERAL NORTHEASTERN VIEW OF DOROTHY SIX BLAST FURNACE COMPLEX WITH LADLE HOUSE AND IRON DESULPHERIZATION BUILDING ON RIGHT. (Jet Lowe) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  13. INTERIOR VIEW OF BLAST FURNACE NO. 3 LOOKING EAST, SLAG ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW OF BLAST FURNACE NO. 3 LOOKING EAST, SLAG RUNNERS & GATES IN FOREGROUND. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 3, Donner Avenue, Monessen, Westmoreland County, PA

  14. VIEW LOOKING NORTHWEST WITH OPENHEARTH TO LEFT WITH BLAST FURNACE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW LOOKING NORTHWEST WITH OPEN-HEARTH TO LEFT WITH BLAST FURNACE NO. 2 AND CAST HOUSE TO THE RIGHT. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 1 & No. 2, Donner Avenue, Monessen, Westmoreland County, PA

  15. 70. CONTROL PANEL INSIDE OF THE DOROTHY SIX BLAST FURNACE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    70. CONTROL PANEL INSIDE OF THE DOROTHY SIX BLAST FURNACE STOCKHOUSE LOOKING NORTH. (Jet Lowe) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  16. INTERIOR VIEW LOOKING EAST, BLAST FURNACE NO. 1 CLOSEUP, IRON ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR VIEW LOOKING EAST, BLAST FURNACE NO. 1 CLOSE-UP, IRON NOTCH IN CENTER. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 1 & No. 2, Donner Avenue, Monessen, Westmoreland County, PA

  17. 59. REMAINS OF THE DOROTHY SIX BLAST FURNACE COMPLEX LOOKING ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    59. REMAINS OF THE DOROTHY SIX BLAST FURNACE COMPLEX LOOKING NORTHEAST. THE LADLE HOUSE IS ON THE RIGHT. (Martin Stupich) - U.S. Steel Duquesne Works, Blast Furnace Plant, Along Monongahela River, Duquesne, Allegheny County, PA

  18. 50. IRON RUNNERS FOR CARRIE FURNACE No. 6 THE TUBES ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    50. IRON RUNNERS FOR CARRIE FURNACE No. 6 THE TUBES IN THE FOREGROUND ARE PART OF THE TUYERE ASSEMBLY. - U.S. Steel Homestead Works, Blast Furnace Plant, Along Monongahela River, Homestead, Allegheny County, PA

  19. 36. REDUCTION PLANT CLOSE VIEW OF FURNACE AND BOILER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    36. REDUCTION PLANT - CLOSE VIEW OF FURNACE AND BOILER Reduction Plant furnace and boiler used to provide heat for drying the fish and fish offal, in their conversion to meal. - Hovden Cannery, 886 Cannery Row, Monterey, Monterey County, CA

  20. Prototype Furnace for Automatic Production of Silicon Ribbon

    NASA Technical Reports Server (NTRS)

    Duncan, C. S.; Stickel, W. B.

    1985-01-01

    Single-crystal material grown under precise control. New furnace permits sustained growth of single-crystal silicon ribbon by dendritic-web growth process. Furnace brings together mechanisms necessary for continuous automatic operation.

  1. Measure Guideline. High Efficiency Natural Gas Furnaces

    SciTech Connect

    Brand, L.; Rose, W.

    2012-10-01

    This measure guideline covers installation of high-efficiency gas furnaces, including: when to install a high-efficiency gas furnace as a retrofit measure; how to identify and address risks; and the steps to be used in the selection and installation process. The guideline is written for Building America practitioners and HVAC contractors and installers. It includes a compilation of information provided by manufacturers, researchers, and the Department of Energy as well as recent research results from the Partnership for Advanced Residential Retrofit (PARR) Building America team.

  2. Measure Guideline: High Efficiency Natural Gas Furnaces

    SciTech Connect

    Brand, L.; Rose, W.

    2012-10-01

    This Measure Guideline covers installation of high-efficiency gas furnaces. Topics covered include when to install a high-efficiency gas furnace as a retrofit measure, how to identify and address risks, and the steps to be used in the selection and installation process. The guideline is written for Building America practitioners and HVAC contractors and installers. It includes a compilation of information provided by manufacturers, researchers, and the Department of Energy as well as recent research results from the Partnership for Advanced Residential Retrofit (PARR) Building America team.

  3. Segmented ceramic liner for induction furnaces

    DOEpatents

    Gorin, Andrew H.; Holcombe, Cressie E.

    1994-01-01

    A non-fibrous ceramic liner for induction furnaces is provided by vertically stackable ring-shaped liner segments made of ceramic material in a light-weight cellular form. The liner segments can each be fabricated as a single unit or from a plurality of arcuate segments joined together by an interlocking mechanism. Also, the liner segments can be formed of a single ceramic material or can be constructed of multiple concentric layers with the layers being of different ceramic materials and/or cellular forms. Thermomechanically damaged liner segments are selectively replaceable in the furnace.

  4. Segmented ceramic liner for induction furnaces

    DOEpatents

    Gorin, A.H.; Holcombe, C.E.

    1994-07-26

    A non-fibrous ceramic liner for induction furnaces is provided by vertically stackable ring-shaped liner segments made of ceramic material in a light-weight cellular form. The liner segments can each be fabricated as a single unit or from a plurality of arcuate segments joined together by an interlocking mechanism. Also, the liner segments can be formed of a single ceramic material or can be constructed of multiple concentric layers with the layers being of different ceramic materials and/or cellular forms. Thermomechanically damaged liner segments are selectively replaceable in the furnace. 5 figs.

  5. High temperature furnace modeling and performance verifications

    NASA Technical Reports Server (NTRS)

    Smith, James E., Jr.

    1991-01-01

    A two dimensional conduction/radiation problem for an alumina crucible in a zirconia heater/muffle tube enclosing a liquid iron sample was solved numerically. Variations in the crucible wall thickness were numerically examined. The results showed that the temperature profiles within the liquid iron sample were significantly affected by the crucible wall thicknesses. New zirconia heating elements are under development that will permit continued experimental investigations of the zirconia furnace. These elements have been designed to work with the existing furnace and have been shown to have longer lifetimes than commercially available zirconia heating elements. The first element has been constructed and tested successfully.

  6. Effect of MgO and MnO on Phosphorus Utilization in P-Bearing Steelmaking Slag

    NASA Astrophysics Data System (ADS)

    Lin, Lu; Bao, Yan-Ping; Wang, Min; Li, Xiang

    2016-04-01

    In order to recycle the phosphorus in P-bearing converter slag and make it used as slag phosphate fertilizer, the effect of MgO and MnO in P-bearing steelmaking slag on phosphorus existence form, P2O5 solubility and magnetic separation behavior were researched systematically. The results show that the phosphorus in slag is mainly in the form of n2CaO · SiO2-3CaO · P2O5 (for short nC2S-C3P) solid solution in the P-rich phase for CaO-SiO2-FetO-P2O5-X (X stands for MgO and MnO, respectively). And the increasing of MgO and MnO content has no influence on precipitation of nC2S-C3P solid solution in slag, MnO and MgO mainly enter into RO phase and base phase to form MnFe2O4 and MgFe2O4, which has little effect on the P2O5 content of P-rich phase, so which has little effect on the degree of phosphorus enrichment and phosphorus occurrence form of the P-bearing slag. And adding MgO and MnO into CaO-SiO2-P2O5-Fe2O3 slag system can break the complex net structure formed by Si-O on certain degree, and also hinder the precipitation of β-Ca3(PO4)2 crystal with low citric acid solubility during the melting-cooling process. Therefore, adding appropriate MgO and MnO content into slag can improve the slag P2O5 solubility, but the effect of different amounts of MgO and MnO on the P2O5 solubility has little difference. Meanwhile, adding MgO and MnO into slag can improve the metallization of slag and magnetism of iron-rich phase, make the magnetic substances content increase and separation of phosphorus and iron incomplete, so it is adverse to phosphorus resources recovery from P-bearing slag by magnetic separation method. In order to recycle the phosphorus in P-bearing converter slag, the MgO and MnO content in the P-bearing slag should be controlled in the steelmaking process.

  7. Analysis of heat transfer in the furnace of the P-67 boiler P-67 furnace and improvement of its design

    NASA Astrophysics Data System (ADS)

    Shishkanov, O. G.; Kovalev, Yu. V.; Sryvkov, S. V.

    1993-03-01

    The results of experimental study of heat transfer in the furnace of the P-67 boiler (under the Russian trademark) burning Kansk-Achinsk coal are presented. Means of improving the design of the furnace device are proposed.

  8. 8. Copy of a photograph taken c. 1912 of Furnace ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    8. Copy of a photograph taken c. 1912 of Furnace 'D' blown-in 17 July 1911, the fourth experimental 'thin-lined furnace' to be built in the United States. Photo courtesy Ralph A. Dise, Cleveland Heights, Ohio. - Central Furnaces, 2650 Broadway, east bank of Cuyahoga River, Cleveland, Cuyahoga County, OH

  9. 6. NO. 2 CONTINUOUS SLAB REHEATING FURNACE OF THE 160' ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. NO. 2 CONTINUOUS SLAB REHEATING FURNACE OF THE 160' PLATE MILL. FURNACE SHOWING DURING DEMOLITION. C HOOK USED TO CHANGE ROLLS IS VISIBLE IN FRONT OF FURNACE. - U.S. Steel Homestead Works, 160" Plate Mill, Along Monongahela River, Homestead, Allegheny County, PA

  10. 57. GENERAL VIEW OF FURNACES No. 3 AND No. 4 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    57. GENERAL VIEW OF FURNACES No. 3 AND No. 4 TO THE LEFT OF THE FURNACES IS THE ORE BRIDGE, THE TURBO-GENERATOR BUILDING, AND THE WATER FILTER TANKS. - U.S. Steel Homestead Works, Blast Furnace Plant, Along Monongahela River, Homestead, Allegheny County, PA

  11. VIEW LOOKING NORTH, VIEW OF BLAST FURNACE NO. 2 (LEFT) ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    VIEW LOOKING NORTH, VIEW OF BLAST FURNACE NO. 2 (LEFT) SHARING THE SAME CAST HOUSE WITH BLAST FURNACE NO. 1. ORE BRIDGE & BLOWER HOUSE TO RIGHT, HULETT CAR DUMPER IS IN LEFT FOREGROUND. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 1 & No. 2, Donner Avenue, Monessen, Westmoreland County, PA

  12. 6. GENERAL VIEW OF FURNACES No. 3 AND No. 4 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. GENERAL VIEW OF FURNACES No. 3 AND No. 4 TO THE LEFT OF THE FURNACES ARE THE ORE BRIDGE, THE TURBO-GENERATOR BUILDING, AND THE WATER FILTER TANKS. Jet Lowe, Photographer, 1989. - U.S. Steel Homestead Works, Blast Furnace Plant, Along Monongahela River, Homestead, Allegheny County, PA

  13. 18. Furnace D, looking north. At far left is the ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    18. Furnace D, looking north. At far left is the 'tripper' car, which distributed ore and limestone into trestle bins below. The 'larryman' then weighed and discharged these materials into skip cars, which carried them to the top of the furnace. - Central Furnaces, 2650 Broadway, east bank of Cuyahoga River, Cleveland, Cuyahoga County, OH

  14. 29. Blast furnace plant, looking southeast. The Machine Shop and ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    29. Blast furnace plant, looking southeast. The Machine Shop and Turbo Blower Building are at left, the pig-casting machine and Furnace A at center right. In foregound are the 50-ton ladle cars used to transport hot metal to Valley Mould & Iron Co. - Central Furnaces, 2650 Broadway, east bank of Cuyahoga River, Cleveland, Cuyahoga County, OH

  15. 56. GENERAL VIEW OF FURNACES No. 3 AND No. 4 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    56. GENERAL VIEW OF FURNACES No. 3 AND No. 4 TO THE LEFT OF THE FURNACES IS THE ORE BRIDGE, THE TURBO-GENERATOR BUILDING, AND THE WATER FILTER TANKS. - U.S. Steel Homestead Works, Blast Furnace Plant, Along Monongahela River, Homestead, Allegheny County, PA

  16. Interior of shop, showing the reheat furnaces; the vehicle in ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Interior of shop, showing the reheat furnaces; the vehicle in the center is a charging machine the operator of which manipulates steel ingots in the furnace, as well as in the adjacent forging hammers - Bethlehem Steel Corporation, South Bethlehem Works, Tool Steel-Electric Furnace Shop, Along Lehigh River, North of Fourth Street, West of Minsi Trail Bridge, Bethlehem, Northampton County, PA

  17. EXTERIOR VIEW, NO. 3 CAST HOUSE CENTER AND BLAST FURNACE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    EXTERIOR VIEW, NO. 3 CAST HOUSE CENTER AND BLAST FURNACE NO. 3 (JANE FURNACE)/ORE BRIDGE TO THE RIGHT, WITH SINTERING PLANT CONVEYORS & TRANSFER HOUSE IN FOREGROUND. - Pittsburgh Steel Company, Monessen Works, Blast Furnace No. 3, Donner Avenue, Monessen, Westmoreland County, PA

  18. 46 CFR 59.15-1 - Furnace repairs.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Furnace repairs. 59.15-1 Section 59.15-1 Shipping COAST... VESSELS AND APPURTENANCES Miscellaneous Boiler Repairs § 59.15-1 Furnace repairs. (a) Where corrugated or plain furnaces or flues are distorted by 11/2 inches or more, they shall be repaired by either of...

  19. 46 CFR 59.15-1 - Furnace repairs.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 2 2012-10-01 2012-10-01 false Furnace repairs. 59.15-1 Section 59.15-1 Shipping COAST... VESSELS AND APPURTENANCES Miscellaneous Boiler Repairs § 59.15-1 Furnace repairs. (a) Where corrugated or plain furnaces or flues are distorted by 11/2 inches or more, they shall be repaired by either of...

  20. 46 CFR 59.15-1 - Furnace repairs.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 2 2011-10-01 2011-10-01 false Furnace repairs. 59.15-1 Section 59.15-1 Shipping COAST... VESSELS AND APPURTENANCES Miscellaneous Boiler Repairs § 59.15-1 Furnace repairs. (a) Where corrugated or plain furnaces or flues are distorted by 11/2 inches or more, they shall be repaired by either of...

  1. 46 CFR 59.15-1 - Furnace repairs.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 2 2014-10-01 2014-10-01 false Furnace repairs. 59.15-1 Section 59.15-1 Shipping COAST... VESSELS AND APPURTENANCES Miscellaneous Boiler Repairs § 59.15-1 Furnace repairs. (a) Where corrugated or plain furnaces or flues are distorted by 11/2 inches or more, they shall be repaired by either of...

  2. 46 CFR 59.15-1 - Furnace repairs.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 2 2013-10-01 2013-10-01 false Furnace repairs. 59.15-1 Section 59.15-1 Shipping COAST... VESSELS AND APPURTENANCES Miscellaneous Boiler Repairs § 59.15-1 Furnace repairs. (a) Where corrugated or plain furnaces or flues are distorted by 11/2 inches or more, they shall be repaired by either of...

  3. Controlling Arc Length in Plasma Welding

    NASA Technical Reports Server (NTRS)

    Iceland, W. F.

    1986-01-01

    Circuit maintains arc length on irregularly shaped workpieces. Length of plasma arc continuously adjusted by control circuit to maintain commanded value. After pilot arc is established, contactor closed and transfers arc to workpiece. Control circuit then half-wave rectifies ac arc voltage to produce dc control signal proportional to arc length. Circuit added to plasma arc welding machines with few wiring changes. Welds made with circuit cleaner and require less rework than welds made without it. Beads smooth and free of inclusions.

  4. Water-cooled furnace heads for use with standard muffle tube furnaces

    NASA Technical Reports Server (NTRS)

    Williams, R. J.; Mullins, O.

    1975-01-01

    The design of water-cooled furnace seals for use in high-temperature controlled-atmosphere gas and vacuum studies is presented in detailed engineering drawings. Limiting design factors and advantages are discussed.

  5. Protecting brazing furnaces from air leaks

    NASA Technical Reports Server (NTRS)

    Armenoff, C. T.; Mckown, R. D.

    1980-01-01

    Inexpensive inert-atmosphere shielding protects vacuum brazing-furnace components that are likely to spring leak. Pipefittings, gages, and valves are encased in transparent plastic shroud inflated with argon. If leak develops, harmless argon will enter vacuum chamber, making it possible to finish ongoing brazing or heat treatment before shutting down for repair.

  6. A Solar Furnace for Your School

    ERIC Educational Resources Information Center

    Meyer, Edwin C.

    1978-01-01

    Industrial arts students at Litchfield (Minnesota) High School designed and built a solar furnace for research and experimentation and to help heat the industrial arts department. A teacher describes the construction process and materials and the temperature record keeping by the physics classes. Student and community interest has been high. (MF)

  7. Laser Vacuum Furnace for Zone Refining

    NASA Technical Reports Server (NTRS)

    Griner, D. B.; Zurburg, F. W.; Penn, W. M.

    1986-01-01

    Laser beam scanned to produce moving melt zone. Experimental laser vacuum furnace scans crystalline wafer with high-power CO2-laser beam to generate precise melt zone with precise control of temperature gradients around zone. Intended for zone refining of silicon or other semiconductors in low gravity, apparatus used in normal gravity.

  8. APPLICATION ANALYSIS REPORT: RETECH PLASMA CENTRIFUGAL FURNACE

    EPA Science Inventory

    This document is an evaluation of the performance of the Retech, Inc. Plasma Centrifugal Furnace (PCF) and its applicability as a treatment for soils contaminated with organic and/or inorganic compounds. Both the technical and economic aspectsof the technology were examined. A...

  9. Tube-Furnace Production of Silicon

    NASA Technical Reports Server (NTRS)

    Farrier, E. G.; Rexer, J.; Timmel, P. J.

    1982-01-01

    Packed-bed reactor produces silicon by decomposing ultrapure silane gas in temperature gradient. Based on previous experiments with relatively low decomposition temperatures and with temperature gradients, heterogeneous decomposition will produce few fines. Fines produced are screened out and reinserted into furnace.

  10. Models for Jupiter's decametric arcs

    NASA Technical Reports Server (NTRS)

    Warwick, J. W.

    1981-01-01

    Arc-shaped structures that dominate Jupiter's decametric emission are discussed in terms of a magnetic fine structure. The sequence of arcs manifest the occurence of widespread fine structures similar to the white ovals on Jupiter's visible surface. An arc concave toward increasing time occurs at the east limb passage, and an arc convex occurs at the west limb passage, which is consistent with the early source producing vertex early arcs, and the late source producing vertex late arcs. Due to the geometry of the Io plasma torus (IPT) which is arranged so that Io skims the northern surface of the IPT, for any connection between Io and Jupiter's surface that involves Alfven waves, the propagation time, the refraction and the directional defocusing of these waves must be strongly influenced by the amount of Alfven wave path length between the instantaneous position of Io and the surface of the IPT.

  11. Can iron-making and steelmaking slag products be used to sequester CO2? Passive weathering and active carbonation experiments.

    NASA Astrophysics Data System (ADS)

    Worrall, Fred; Dobrzański, Andrew

    2015-04-01

    The high calcium content of iron and steel-making slags has been highlighted as providing a suitable feedstock material and medium with which to sequester CO2 into geologically stable carbonate phases. Optimisation of the natural carbonation process provides the potential for increasing the degree of carbonation above that possible via passive weathering. This study has assessed the baseline passive carbonation potential of several different slag products (graded steel slag aggregate, pellite, GBFS) within the climate of the northern UK. This baseline was then used as a comparison to the carbonation values achieved by the same products when actively reacted in a CO2-rich environment. The active carbonation phase of the project involved a factorial experimental study of materials reacted at 1MPa/10MPa CO2 pressure and 25˚C/125˚C. This study has shown: 1) That active carbonation of these products can successfully sequester additional CO2. 2) Carbonation potential in general is highly dependent upon grain size within material types, 3) There is a material-dependant cost-benefit issue when using different active carbonation conditions as well as the choice to use active vs. passive carbonation. The median sequestration potential of the slag products in this study is equivalent to the total emissions from 910 people from the UK; the CO2 emissions from 10000 tonnes of cement production; or 340000 tonnes of steel production.

  12. The Effects of Bottom Blowing Gas Flow Rate Distribution During the Steelmaking Converter Process on Mixing Efficiency

    NASA Astrophysics Data System (ADS)

    Chu, Kuan-Yu; Chen, Hsing-Hao; Lai, Po-Han; Wu, Hsuan-Chung; Liu, Yung-Chang; Lin, Chi-Cheng; Lu, Muh-Jung

    2016-04-01

    Featuring the advantages of top-blown and bottom-blown oxygen converters, top and bottom combined blown converters are mainstream devices used in steelmaking converter. This study adopted the FLUENT software to develop a numerical model that simulates 3D multiphase flows of gas (air and argon), liquid steel, and slag. Ten numerical experiments were conducted to analyze the effects that the bottom blowing gas flow rate distribution patterns (uniform, linear fixed total flow rate, linear fixed maximal flow rate, and V-type) and bottom blowing gas flow distribution gradients of combined blown converters exert on slag surface stirring heights, flow field patterns, simulation system dynamic pressures, mixing time, and liquid steel-slag interface velocity. The simulation results indicated that the mixing efficiency was highest for the linear fixed total flow rate, followed by the linear fixed maximal flow rate, V-type, and uniform patterns. The bottom blowing gas flow rate distribution exhibited linear patterns and large gradients, and high bottom blowing total flow rates increased the mixing efficiency substantially. In addition, the results suggested that even when bottom blowing total flow rate was reduced, adopting effective bottom blowing gas flow rate distribution patterns and gradients could improve the mixing efficiency.

  13. Utilization of steel-making slag for the uptake of ammonium and phosphate ions from aqueous solution.

    PubMed

    Jha, Vinay Kumar; Kameshima, Yoshikazu; Nakajima, Akira; Okada, Kiyoshi

    2008-08-15

    Steel-making slag, a waste by-product of the Steel Industry, constitutes a major disposal problem. In the present study, excellent adsorbent materials for reducing eutrophication in wastewaters have been prepared from this slag. Heated samples of acid-treated slag and mixtures of slag with kaolinite and Al(OH)(3) were examined to determine their uptake capacities for NH(4)(+) and PO(4)(3-) from aqueous solutions. In general, the equilibrium pH of the solution increased in comparison to initial pH with the uptake of target ions, the sample activated slag-Al(OH)(3) showing the smallest change. The highest PO(4)(3-) uptake capacity was obtained with the slag-Al(OH)(3) mixture heated at 900 degrees C whereas the highest uptake of NH(4)(+) was found in the slag-Al(OH)(3) mixture heated at 800 degrees C. The uptake rates for PO(4)(3-) and NH(4)(+) by the slag-Al(OH)(3) mixture heated at 900 degrees C were 2.91 and 0.65 micro mol/(g min), respectively. It was shown that heating slag composites prior to incorporation into wastewater treatment filters resulted in an increased degree of NH(4)(+) and PO(4)(3-) uptake.

  14. Joan of Arc.

    PubMed

    Foote-Smith, E; Bayne, L

    1991-01-01

    For centuries, romantics have praised and historians and scientists debated the mystery of Joan of Arc's exceptional achievements. How could an uneducated farmer's daughter, raised in harsh isolation in a remote village in medieval France, have found the strength and resolution to alter the course of history? Hypotheses have ranged from miraculous intervention to creative psychopathy. We suggest, based on her own words and the contemporary descriptions of observers, that the source of her visions and convictions was in part ecstatic epileptic auras and that she joins the host of creative religious thinkers suspected or known to have epilepsy, from St. Paul and Mohammed to Dostoevsky, who have changed western civilization.

  15. APPARATUS FOR ARC WELDING

    DOEpatents

    Lingafelter, J.W.

    1960-04-01

    An apparatus is described in which a welding arc created between an annular electrode and a workpiece moves under the influence of an electromagnetic field about the electrode in a closed or annular path. This mode of welding is specially suited to the enclosing of nuclear-fuel slugs in a protective casing. For example, a uranium slug is placed in an aluminum can, and an aluminum closure is welded to the open end of the can along a closed or annular path conforming to the periphery of the end closure.

  16. Arcing on dc power systems

    NASA Technical Reports Server (NTRS)

    Moores, Greg; Heller, R. P.; Sutanto, Surja; Dugal-Whitehead, Norma R.

    1992-01-01

    Unexpected and undesirable arcing on dc power systems can produce hazardous situations aboard space flights. The potential for fire and shock might exist in a situation where there is a broken conductor, a loose power connection, or a break in the insulation of the power cable. Such arcing has been found to be reproducible in a laboratory environment. Arcing tests show that the phenomena can last for several seconds and yet be undetectable by present protection schemes used in classical power relaying and remote power controller applications. This paper characterizes the arcing phenomena and suggests future research that is needed.

  17. 6. Photocopied August 1978. LINEUP OF HORRY ROTARY FURNACES ON ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. Photocopied August 1978. LINE-UP OF HORRY ROTARY FURNACES ON THE SECOND FLOOR OF THE MICHIGAN LAKE SUPERIOR POWER COMPANY POWER HOUSE. THE HOPPERS WHICH FED THE RAW MATERIALS INTO THE FURNACES ARE SHOWN ABOVE THE FURNACES. AS THE 'SPOOL' OF THE FURNACE ROTATED PAST THE ELECTRODES PLATES WERE ADDED TO HOLD THE FINISHED PRODUCT AND THE DESCENDING RAW MATERIALS IN PLACE. THE DIRECTION OF ROTATION OF THE FURNACES SHOWN IN THIS PHOTO IS CLOCKWISE, (M). - Michigan Lake Superior Power Company, Portage Street, Sault Ste. Marie, Chippewa County, MI

  18. Characterization of the behaviour of the electric arc during VAR of a Ti alloy

    NASA Astrophysics Data System (ADS)

    Chapelle, P.; Noël, C.; Risacher, A.; Jourdan, J.; Jourdan, J.; Jardy, A.

    2016-07-01

    In this paper, we report experimental results based on the direct observation of the electric arc behaviour during vacuum arc remelting of a Ti alloy. These results were obtained in a specifically instrumented industrial furnace using high speed framing camera and optical emission spectroscopy, for a current density level of the order of 10 A/cm2 and a gap length of a few centimetres. It was observed that the arc exhibits a similar operating regime to that described in the literature for the case of Inconel 718 and Zr alloy electrodes. The arc structure corresponds essentially to that of a diffuse metal vapor arc with separate and rapidly moving cathode spots. Several critical parameters of the cathode spots, including their current, size and velocity, and of the interelectrode plasma were evaluated. Also, the interactions between the arc operation and the transfer of metal drops in the interelectrode gap were investigated. Three modes of transfer of the liquid metal drops in the interelectrode gap have been identified depending on the gap length: drop falling, drip short and drop erosion induced by the cathode spots.

  19. Process control techniques for the Sidmar blast furnaces

    SciTech Connect

    Vandenberghe, D.; Bonte, L.; Nieuwerburgh, H. van

    1995-12-01

    The major challenge for modern blast furnace operation is the achievement of a very high productivity, excellent hot metal quality, low fuel consumption and longer blast furnace campaigns. The introduction of predictive models, decision supporting software and expert systems has reduced the standard deviation of the hot metal silicon content. The production loss due to the thermal state of the blast furnace has decreased three times since 1990. An appropriate control of the heat losses with high pulverized coal injection rates, is of the utmost importance for the life of the blast furnace. Different rules for the burden distribution of both blast furnaces are given. At blast furnace A, a peripheral gas flow is promoted, while at blast furnace B a more central gas flow is promoted.

  20. Electric arc welding gun

    DOEpatents

    Luttrell, Edward; Turner, Paul W.

    1978-01-01

    This invention relates to improved apparatus for arc welding an interior joint formed by intersecting tubular members. As an example, the invention is well suited for applications where many similar small-diameter vertical lines are to be welded to a long horizontal header. The improved apparatus includes an arc welding gun having a specially designed welding head which is not only very compact but also produces welds that are essentially free from rolled-over solidified metal. The welding head consists of the upper end of the barrel and a reversely extending electrode holder, or tip, which defines an acute angle with the barrel. As used in the above-mentioned example, the gun is positioned to extend upwardly through the vertical member and the joint to be welded, with its welding head disposed within the horizontal header. Depending on the design of the welding head, the barrel then is either rotated or revolved about the axis of the vertical member to cause the electrode to track the joint.

  1. Alternating-Polarity Arc Welding

    NASA Technical Reports Server (NTRS)

    Schwinghamer, R. J.

    1987-01-01

    Brief reversing polarity of welding current greatly improves quality of welds. NASA technical memorandum recounts progress in art of variable-polarity plasma-arc (VPPA) welding, with emphasis on welding of aluminum-alloy tanks. VPPA welders offer important advantages over conventional single-polarity gas/tungsten arc welders.

  2. TAMA. TIGER Arc Modification Application

    SciTech Connect

    Armstrong, H

    1994-06-03

    The application enables the geometric correction of TIGER arcs to a more accurate spatial data set. This is done in a structured automated environment according to Census Bureau guidelines and New Mexico state GIS standards. Arcs may be deleted, added, combined, split, and moved relative to a coverage or image displayed in the background.

  3. Metal loss and charge heating in the melt in an electric arc furnace

    NASA Astrophysics Data System (ADS)

    Serikov, V. A.; Bikeev, R. A.; Cherednichenko, M. V.; Cherednichenko, V. S.

    2015-12-01

    The heat exchange between a metallic melt and a slag with a charge is simulated with allowance for possible formation of a skull on the charge surface. It is shown that the charge melting rate in the melt is determined by the coefficient of heat transfer between the metal and the charge and the ratio of the mass of a charge fragment to its surface area interacting with the melt. A skull is found to form on the charge surface at a low coefficient of heat transfer between the metal and the charge. The main heat parameters, the control of which by an automatic control system ensures an increase in the charge melting rate in the melt and a decrease in the metal loss, are formulated.

  4. [Health surveillance in a steel making industry with electric arc furnace: 15 years of experience].

    PubMed

    Corti, P

    2012-01-01

    This paper analyzes the results of health surveillance carried out in an electric steel mill for 15 years. We have analyzed the trend of audiometry, spirometry and main indicators of exposure to chemical risk: serum lead, urinary OH-pyrene, erythrocyte ZPP, and the results of risk assessment of stress work related. The analyses of the trend of audiometry, spirometry and biological monitoring shows an important improving in the working environment due to the progressive automation of production steps in the course of several years, consistent and correct use of DPI, information and training.

  5. Of Eggs and Arcs

    NASA Astrophysics Data System (ADS)

    Burns, Joseph A.; Thomas, P. C.; Helfenstein, P.; Tiscareno, M. S.; Hedman, M. M.; Agarwal, M.

    2012-10-01

    New scenarios for the origins of Saturn’s rings/interior moons have directed scientific attention to the region just exterior to Saturn’s main rings. Four satellites (Aegaeon = Ae; Anthe = An; Methone = Me; Pallene = Pa) discovered by the Cassini mission on either side of Mimas’s orbit perhaps comprise a distinct class of ring-moon. They are tiny (R = 0.3-2.5 km); three (AeAnMe) are trapped in co-rotation resonances with Mimas and reside within ring-arcs; and at least two (MePa) have remarkably regular shapes. Images with pixel scales as fine as 27 m taken in May 2012 reveal Methone to be ovoid within 10 m (from sub-pixel limb detection) and devoid of any craters (>130 m) across its 9 km2 of surface; Pallene and even tiny Aegaeon have similar appearances in lesser-quality images. Numerical simulations demonstrate that particles comprising the surrounding ring-arcs populate the same resonances as their embedded moons; escape speeds from the moons are < 0.5 m/s, smaller than the 2 m/s that dynamically characterize the resonant well. We investigate the gentle transfer of particles back and forth between the ring-arcs and any embedded bodies. In this environment, the moons’ shapes are smooth equipotentials; electrostatic effects may also determine how grains settle to surfaces. Considering these shapes to represent equipotential surfaces for rotating, tidally distorted, homogeneous bodies, we infer mean satellite densities of 250+/-60 (Pa), 310+/-30 (Me), and 540+/-120 (Ae) kg m-3. About half of Methone’s leading hemisphere is covered by a sharply bounded, lemon-shaped, relatively dark region, having a form reminiscent of Mimas’s thermal anomaly (Howett et al. 2011). Its (601 nm) albedo is 13% lower than the bounding brighter material. An irregularly shaped, even-darker (by 4%) blotch straddles the apex of the moon’s motion. Impacts with circum-planetary meteoroids and plasma are likely responsible for these features.

  6. Baseline tests for arc melter vitrification of INEL buried wastes. Volume 1: Facility description and summary data report

    SciTech Connect

    Oden, L.L.; O`Connor, W.K.; Turner, P.C.; Soelberg, N.R.; Anderson, G.L.

    1993-11-19

    This report presents field results and raw data from the Buried Waste Integrated Demonstration (BWID) Arc Melter Vitrification Project Phase 1 baseline test series conducted by the Idaho National Engineering Laboratory (INEL) in cooperation with the U.S. Bureau of Mines (USBM). The baseline test series was conducted using the electric arc melter facility at the USBM Albany Research Center in Albany, Oregon. Five different surrogate waste feed mixtures were tested that simulated thermally-oxidized, buried, TRU-contaminated, mixed wastes and soils present at the INEL. The USBM Arc Furnace Integrated Waste Processing Test Facility includes a continuous feed system, the arc melting furnace, an offgas control system, and utilities. The melter is a sealed, 3-phase alternating current (ac) furnace approximately 2 m high and 1.3 m wide. The furnace has a capacity of 1 metric ton of steel and can process as much as 1,500 lb/h of soil-type waste materials. The surrogate feed materials included five mixtures designed to simulate incinerated TRU-contaminated buried waste materials mixed with INEL soil. Process samples, melter system operations data and offgas composition data were obtained during the baseline tests to evaluate the melter performance and meet test objectives. Samples and data gathered during this program included (a) automatically and manually logged melter systems operations data, (b) process samples of slag, metal and fume solids, and (c) offgas composition, temperature, velocity, flowrate, moisture content, particulate loading and metals content. This report consists of 2 volumes: Volume I summarizes the baseline test operations. It includes an executive summary, system and facility description, review of the surrogate waste mixtures, and a description of the baseline test activities, measurements, and sample collection. Volume II contains the raw test data and sample analyses from samples collected during the baseline tests.

  7. Control method for a reclamation furnace

    SciTech Connect

    Kelly, S.B.

    1981-06-02

    A method is presented for preventing fires and explosions and thus controlling excess temperature within a burn-off or reclamation furnace including a water injection nozzle within the furnace, an automatic valve assembly connected to a source of water under pressure to turn the water on and off, an input burner to heat contaminate materials, an afterburner to burn volatile gases given off by the contaminate materials as they are heated, a temperature sensor located in the discharge from the afterburner to actuate the automatic valve assembly open and closed responsive to the temperature of the discharge. The temperature of the discharge depends on the rate of emission of volatile gases from the contaminate material so that if a high emission rate causes a predetermined temperature to be exceeded the valve assembly opens and the water injection nozzle sprays water on the contaminate materials to cool them and decrease the emission rate until the valve assembly closes.

  8. Glass furnace with heat sensing means

    SciTech Connect

    Canfield, D.M.

    1986-07-22

    A furnace is described for the heat treatment of glass including, annealing, heat-strengthening, tempering and bending of glass which comprises: a housing defining an elongated furnace chamber having an inlet and an outlet; a roller conveyor between the inlet and the outlet and including a row of stub rollers disposed along each side of the housing flanking a path between the inlet and the outlet, a drive conveyor belt extending over and under alternate stub rollers on one side of the conveyor, and fused silica support rollers spanning the conveyor with each support roller resting upon two stub rollers overshot by the belt; means for driving the belt to oscillate glass articles carried by the support rollers back and forth in the housing; an array of infrared heaters mounted in the housing above the conveyor; and a computer for displaying parameters for the operation of the heaters in a pattern on a screen corresponding to the array.

  9. Arc fault detection system

    DOEpatents

    Jha, K.N.

    1999-05-18

    An arc fault detection system for use on ungrounded or high-resistance-grounded power distribution systems is provided which can be retrofitted outside electrical switchboard circuits having limited space constraints. The system includes a differential current relay that senses a current differential between current flowing from secondary windings located in a current transformer coupled to a power supply side of a switchboard, and a total current induced in secondary windings coupled to a load side of the switchboard. When such a current differential is experienced, a current travels through a operating coil of the differential current relay, which in turn opens an upstream circuit breaker located between the switchboard and a power supply to remove the supply of power to the switchboard. 1 fig.

  10. Arc fault detection system

    DOEpatents

    Jha, Kamal N.

    1999-01-01

    An arc fault detection system for use on ungrounded or high-resistance-grounded power distribution systems is provided which can be retrofitted outside electrical switchboard circuits having limited space constraints. The system includes a differential current relay that senses a current differential between current flowing from secondary windings located in a current transformer coupled to a power supply side of a switchboard, and a total current induced in secondary windings coupled to a load side of the switchboard. When such a current differential is experienced, a current travels through a operating coil of the differential current relay, which in turn opens an upstream circuit breaker located between the switchboard and a power supply to remove the supply of power to the switchboard.

  11. Waste combustion in boilers and industrial furnaces

    SciTech Connect

    1996-12-31

    This publication contains technical papers published as they were presented at a recent specialty conference sponsored by the Air & Waste Management Association, titled Waste Combustion in Boilers and Industrial Furnaces, held March 26-27, 1996, in Kansas City, Missouri. Papers touch on compilance concerns for air pollution, air monitoring methodologies, risk assessment, and problems related to public anxiety. Separate abstracts have been indexed into the database from this proceedings.

  12. Induction graphitizing furnace acceptance test report

    NASA Technical Reports Server (NTRS)

    1972-01-01

    The induction furnace was designed to provide the controlled temperature and environment required for the post-cure, carbonization and graphitization processes for the fabrication of a fibrous graphite NERVA nozzle extension. The acceptance testing required six tests and a total operating time of 298 hrs. Low temperature mode operations, 120 to 850 C, were completed in one test run. High temperature mode operations, 120 to 2750 C, were completed during five tests.

  13. Ultra-high vacuum compatible image furnace.

    PubMed

    Neubauer, A; Boeuf, J; Bauer, A; Russ, B; Löhneysen, H v; Pfleiderer, C

    2011-01-01

    We report the design of an optical floating-zone furnace for single-crystal growth under ultra-high vacuum (UHV) compatible conditions. The system is based on a commercial image furnace, which has been refurbished to be all-metal sealed. Major changes concern the use of UHV rotary feedthroughs and bespoke quartz-metal seals with metal-O-rings at the lamp stage. As a consequence, the procedure of assembling the furnace for crystal growth is changed completely. Bespoke heating jackets permit to bake the system. For compounds with elevated vapor pressures, the ultra-high vacuum serves as a precondition for the use of a high-purity argon atmosphere up to 10 bar. In the ferromagnetic Heusler compound Cu(2)MnAl, the improvements of purity result in an improved stability of the molten zone, grain selection, and, hence, single-crystal growth. Similar improvements are observed in traveling-solvent floating-zone growth of the antiferromagnetic Heusler compound Mn(3)Si. These improvements underscore the great potential of optical float-zoning for the growth of high-purity single crystals of intermetallic compounds.

  14. Ultra-high vacuum compatible image furnace

    NASA Astrophysics Data System (ADS)

    Neubauer, A.; BÅ`uf, J.; Bauer, A.; Russ, B.; Löhneysen, H. v.; Pfleiderer, C.

    2011-01-01

    We report the design of an optical floating-zone furnace for single-crystal growth under ultra-high vacuum (UHV) compatible conditions. The system is based on a commercial image furnace, which has been refurbished to be all-metal sealed. Major changes concern the use of UHV rotary feedthroughs and bespoke quartz-metal seals with metal-O-rings at the lamp stage. As a consequence, the procedure of assembling the furnace for crystal growth is changed completely. Bespoke heating jackets permit to bake the system. For compounds with elevated vapor pressures, the ultra-high vacuum serves as a precondition for the use of a high-purity argon atmosphere up to 10 bar. In the ferromagnetic Heusler compound Cu _2MnAl, the improvements of purity result in an improved stability of the molten zone, grain selection, and, hence, single-crystal growth. Similar improvements are observed in traveling-solvent floating-zone growth of the antiferromagnetic Heusler compound Mn _3Si. These improvements underscore the great potential of optical float-zoning for the growth of high-purity single crystals of intermetallic compounds.

  15. A virtual crystallization furnace for solar silicon

    SciTech Connect

    Steinbach, I.; Franke, D.; Krumbe, W.; Liebermann, J.

    1994-12-31

    Blocks of silicon for photovoltaic applications are economically crystallized in large casting furnaces. The quality of the material is determined by the velocity of the crystallization front, the flatness of the liquid-solid interface and the thermal gradients in the solid during cooling. The process cycle time, which is determined by the rate of crystallization and cooling, has a large effect on the process economic viability. Traditionally trial and error was used to determine the process control parameters, the success of which depended on the operator`s experience and intuition. This paper presents a numerical model, which when completed by a fitted data set, constitutes a virtual model of a real crystallization furnace, the Virtual Crystallization Furnace (VCF). The time-temperature distribution during the process cycle is the main output, which includes a display of actual liquid-solid front position. Moreover, solidification velocity, temperature gradients and thermal stresses can be deduced from this output. The time needed to run a simulation on a modern work-station is approximately 1/6 of real process time, thereby allowing the user to make many process variations at very reasonable costs. Therefore the VCF is a powerful tool for optimizing the process in order to reduce cycle time and to increase product quality.

  16. Reduce Air Infiltration in Furnaces (English/Chinese) (Fact Sheet)

    SciTech Connect

    Not Available

    2011-10-01

    Chinese translation of the Reduce Air Infiltration in Furnaces fact sheet. Provides suggestions on how to improve furnace energy efficiency. Fuel-fired furnaces discharge combustion products through a stack or a chimney. Hot furnace gases are less dense and more buoyant than ambient air, so they rise, creating a differential pressure between the top and the bottom of the furnace. This differential, known as thermal head, is the source of a natural draft or negative pressure in furnaces and boilers. A well-designed furnace (or boiler) is built to avoid air leakage into the furnace or leakage of flue gases from the furnace to the ambient. However, with time, most furnaces develop cracks or openings around doors, joints, and hearth seals. These openings (leaks) usually appear small compared with the overall dimensions of the furnace, so they are often ignored. The negative pressure created by the natural draft (or use of an induced-draft fan) in a furnace draws cold air through the openings (leaks) and into the furnace. The cold air becomes heated to the furnace exhaust gas temperature and then exits through the flue system, wasting valuable fuel. It might also cause excessive oxidation of metals or other materials in the furnaces. The heat loss due to cold air leakage resulting from the natural draft can be estimated if you know four major parameters: (1) The furnace or flue gas temperature; (2) The vertical distance H between the opening (leak) and the point where the exhaust gases leave the furnace and its flue system (if the leak is along a vertical surface, H will be an average value); (3) The area of the leak, in square inches; and (4) The amount of operating time the furnace spends at negative pressure. Secondary parameters that affect the amount of air leakage include these: (1) The furnace firing rate; (2) The flue gas velocity through the stack or the stack cross-section area; (3) The burner operating conditions (e.g., excess air, combustion air temperature

  17. Microfouling studies on experimental test blocks of steel-making slag and concrete exposed to seawater off Chiba, Japan.

    PubMed

    Nandakumar, Kanavillil; Matsunaga, Hisahiro; Takagi, Masato

    2003-08-01

    Microfouling studies with the emphasis on microalgae (Bacillariophyceae) were carried out on test blocks of steel-making slag in comparison with concrete. Two types of slag test blocks, with and without fly-ash as an additional source of silica, and concrete test blocks of size 75 x 26 x 26 mm were used to study microfouling build-up for a period of 30 d, with intermittent samplings after 1, 2, 3, 7, 14 and 21 d. The species composition, cell density, biomass and surface pH of the test pieces were determined, in addition to the hydrographic parameters of the water column. Microfouling studies showed higher numbers of algal species as well as a greater cell density on the slag than on the concrete blocks. This was true with respect to biomass measured as dry weight also. Colonization was significantly delayed in the case of concrete. Navicula spp. and Nitzschia spp. were the initial colonizers on all three types of substrata and were the dominant genera throughout the study period. While the number of species increased, several disappeared after colonization, as a part of community build-up. The surface pH of the slag blocks was near neutral, whilst that of the concrete was highly alkaline during the initial period of exposure. This alkaline surface reduced the rate of species colonization on the concrete blocks initially. The study showed severe biofouling on the slag blocks compared to concrete and thus they were considered an environmentally benign construction material for land protection. The use of slag as the construction material for land protection would greatly reduce the expense compared to concrete.

  18. Investigation on Viscosity and Nonisothermal Crystallization Behavior of P-Bearing Steelmaking Slags with Varying TiO2 Content

    NASA Astrophysics Data System (ADS)

    Wang, Zhanjun; Sun, Yongqi; Sridrar, Seetharaman; Zhang, Mei; Zhang, Zuotai

    2017-02-01

    The viscous flow and crystallization behavior of CaO-SiO2-MgO-Al2O3-FetO-P2O5-TiO2 steelmaking slags have been investigated over a wide range of temperatures under Ar (High purity, >99.999 pct) atmosphere, and the relationship between viscosity and structure was determined. The results indicated that the viscosity of the slags slightly decreased with increasing TiO2 content. The constructed nonisothermal continuous cooling transformation (CCT) diagrams revealed that the addition of TiO2 lowered the crystallization temperature. This can mainly be ascribed to that addition of TiO2 promotes the formation of [TiO6]-octahedra units and, consequently, the formation of MgFe2O4-Mg2TiO4 solid solution. Moreover, the decreasing viscosity has a significant effect on enhancing the diffusion of ion units, such as Ca2+ and [TiO4]-tetrahedra, from bulk melts to the crystal-melt interface. The crystallization of CaTiO3 and CaSiTiO5 was consequently accelerated, which can improve the phosphorus content in P-enriched phase ( n2CaO·SiO2-3CaO·P2O5). Finally, the nonisothermal crystallization kinetics was characterized and the activation energy for the primary crystal growth was derived such that the activation energy increases from -265.93 to -185.41 KJ·mol-1 with the addition of TiO2 content, suggesting that TiO2 lowered the tendency for the slags to crystallize.

  19. Plasma arc technology development for application to demilitarization of pyrotechnic ordnance

    SciTech Connect

    Mescavage, G.; Filius, K. |

    1995-12-31

    An initial investigation into the use of a plasma arc furnace for demilitarization of completely assembled, small-caliber, hand-emplaced pyrotechnic, smoke, and dye ordnance was conducted at the Department of Energy`s Western Environmental Technology Office, located in Butte, Montana. This technology is being pursued as an alternative to open burning/open detonation (OB/OD), which is the method of demilitarization traditionally used for these items, as increasingly more stringent environmental regulations have discouraged and disallowed the use of OB/OD. Problems have been experienced with the use of existing incinerators for demilitarization of these items. Varying quantities of 19 different types of live, completely assembled, small pyrotechnic, smoke, and dye items were processed in a pilot-scale Retech, Inc., Plasma Arc Centrifugal Treatment System. This testing demonstrated that a plasma arc furnace equipped with pollution abatement equipment can safely demilitarize these items in compliance with applicable environmental regulations. In addition, the process encapsulates heavy metals and other hazardous constituents into a solid, low-leachable slag product that passes Federally established tests as a nonhazardous material. This provides an advantage over standard incineration which yields a hazardous ash. The process also is able to overcome problems reported with standard incinerators. In addition, gas flows are significantly lower than those in standard incinerators, allowing smaller pollution abatement equipment to be used. However, operational problems and inefficiencies were identified that need to be resolved before full-scale implementation.

  20. Ground Control Setup of the (LIF) Large Isothermal Furnace

    NASA Technical Reports Server (NTRS)

    1995-01-01

    Large Isothermal Furnace (LIF) was flown on a mission in cooperation with the National Space Development Agency (NASDA) of Japan. LIF is a vacuum-heating furnace designed to heat large samples uniformly. The furnace consists of a sample container and heating element surrounded by a vacuum chamber. A crewmemeber will insert a sample cartridge into the furnace. The furnace will be activated and operations will be controlled automatically by a computer in response to an experiment number entered on the control panel. At the end of operations, helium will be discharged into the furnace, allowing cooling to start. Cooling will occur through the use of a water jacket while rapid cooling of samples can be accomplished through a controlled flow of helium. Data from experiments will help scientists better understand this important process which is vital to the production of high-quality semiconductor crystals.