Interferometric Laser Scanner for Direction Determination
Kaloshin, Gennady; Lukin, Igor
2016-01-01
In this paper, we explore the potential capabilities of new laser scanning-based method for direction determination. The method for fully coherent beams is extended to the case when interference pattern is produced in the turbulent atmosphere by two partially coherent sources. The performed theoretical analysis identified the conditions under which stable pattern may form on extended paths of 0.5–10 km in length. We describe a method for selecting laser scanner parameters, ensuring the necessary operability range in the atmosphere for any possible turbulence characteristics. The method is based on analysis of the mean intensity of interference pattern, formed by two partially coherent sources of optical radiation. Visibility of interference pattern is estimated as a function of propagation pathlength, structure parameter of atmospheric turbulence, and spacing of radiation sources, producing the interference pattern. It is shown that, when atmospheric turbulences are moderately strong, the contrast of interference pattern of laser scanner may ensure its applicability at ranges up to 10 km. PMID:26805841
Interferometric Laser Scanner for Direction Determination.
Kaloshin, Gennady; Lukin, Igor
2016-01-21
In this paper, we explore the potential capabilities of new laser scanning-based method for direction determination. The method for fully coherent beams is extended to the case when interference pattern is produced in the turbulent atmosphere by two partially coherent sources. The performed theoretical analysis identified the conditions under which stable pattern may form on extended paths of 0.5-10 km in length. We describe a method for selecting laser scanner parameters, ensuring the necessary operability range in the atmosphere for any possible turbulence characteristics. The method is based on analysis of the mean intensity of interference pattern, formed by two partially coherent sources of optical radiation. Visibility of interference pattern is estimated as a function of propagation pathlength, structure parameter of atmospheric turbulence, and spacing of radiation sources, producing the interference pattern. It is shown that, when atmospheric turbulences are moderately strong, the contrast of interference pattern of laser scanner may ensure its applicability at ranges up to 10 km.
Effect of the atmosphere on the classification of LANDSAT data. [Identifying sugar canes in Brazil
NASA Technical Reports Server (NTRS)
Dejesusparada, N. (Principal Investigator); Morimoto, T.; Kumar, R.; Molion, L. C. B.
1979-01-01
The author has identified the following significant results. In conjunction with Turner's model for the correction of satellite data for atmospheric interference, the LOWTRAN-3 computer was used to calculate the atmospheric interference. Use of the program improved the contrast between different natural targets in the MSS LANDSAT data of Brasilia, Brazil. The classification accuracy of sugar canes was improved by about 9% in the multispectral data of Ribeirao Preto, Sao Paulo.
Liu, Xin; Han, Yanqing; Zhu, Jinge; Deng, Jiancai; Hu, Weiping; da Silva, Thomaz Edson Veloso
2018-01-01
The growth of most submerged macrophytes is likely to be limited by the availability of carbon resource, and this is especially true for the obligatory carbon dioxide (CO 2 ) users. A mesocosm experiment was performed to investigate the physiological, photophysiological, and biochemical responses of Cabomba caroliniana, an invasive macrophyte specie in the Lake Taihu Basin, to elevated atmospheric CO 2 (1000 μmol mol -1 ); we also examined the possible impacts of interferences derived from the phytoplankton proliferation and its concomitant disturbances on the growth of C. caroliniana. The results demonstrated that elevated atmospheric CO 2 significantly enhanced the biomass, relative growth rate, and photosynthate accumulation of C. caroliniana. C. caroliniana exposed to elevated atmospheric CO 2 exhibited a higher relative maximum electron transport rate and photosynthetic efficiency, compared to those exposed to ambient atmospheric CO 2 . However, the positive effects of elevated atmospheric CO 2 on C. caroliniana were gradually compromised as time went by, and the down-regulations of the relative growth rate (RGR) and photosynthetic activity were coupled with phytoplankton proliferation under elevated atmospheric CO 2 . This study demonstrated that the growth of C. caroliniana under the phytoplankton interference can be greatly affected, directly and indirectly, by the increasing atmospheric CO 2 .
A table of polyatomic interferences in ICP-MS
May, Thomas W.; Wiedmeyer, Ray H.
1998-01-01
Spectroscopic interferences are probably the largest class of interferences in ICP-MS and are caused by atomic or molecular ions that have the same mass-to-charge as analytes of interest. Current ICP-MS instrumental software corrects for all known atomic “isobaric” interferences, or those caused by overlapping isotopes of different elements, but does not correct for most polyatomic interferences. Such interferences are caused by polyatomic ions that are formed from precursors having numerous sources, such as the sample matrix, reagents used for preparation, plasma gases, and entrained atmospheric gases.
Rich, Alisa L; Patel, Jay T; Al-Angari, Samiah S
2016-01-01
Carbon disulfide (CS2) has been historically associated with the manufacturing of rayon, cellophane, and carbon tetrachloride production. This study is one of the first to identify elevated atmospheric levels of CS2 above national background levels and its mechanisms to dysregulate normal glucose metabolism. Interference in glucose metabolism can indirectly cause other complications (diabetes, neurodegenerative disease, and retinopathy), which may be preventable if proper precautions are taken. Rich et al found CS2 and 12 associated sulfide compounds present in the atmosphere in residential areas where unconventional shale oil and gas extraction and processing operations were occurring. Ambient atmospheric concentrations of CS2 ranged from 0.7 parts per billion by volume (ppbv) to 103 ppbv over a continuous 24-hour monitoring period. One-hour ambient atmospheric concentrations ranged from 3.4 ppbv to 504.6 ppbv. Using the U.S. Environmental Protection Agency Urban Air Toxic Monitoring Program study as a baseline comparison for atmospheric CS2 concentrations found in this study, it was determined that CS2 atmospheric levels were consistently elevated in areas where unconventional oil and gas extraction and processing occurred. The mechanisms by which CS2 interferes in normal glucose metabolism by dysregulation of the tryptophan metabolism pathway are presented in this study. The literature review found an increased potential for alteration of normal glucose metabolism in viscose rayon occupational workers exposed to CS2. Occupational workers in the energy extraction industry exposed to CS2 and other sulfide compounds may have an increased potential for glucose metabolism interference, which has been an indicator for diabetogenic effect and other related health impacts. The recommendation of this study is for implementation of regular monitoring of blood glucose levels in CS2-exposed populations as a preventative health measure.
Target-in-the-loop remote sensing of laser beam and atmospheric turbulence characteristics.
Vorontsov, Mikhail A; Lachinova, Svetlana L; Majumdar, Arun K
2016-07-01
A new target-in-the-loop (TIL) atmospheric sensing concept for in situ remote measurements of major laser beam characteristics and atmospheric turbulence parameters is proposed and analyzed numerically. The technique is based on utilization of an integral relationship between complex amplitudes of the counterpropagating optical waves known as overlapping integral or interference metric, whose value is preserved along the propagation path. It is shown that the interference metric can be directly measured using the proposed TIL sensing system composed of a single-mode fiber-based optical transceiver and a remotely located retro-target. The measured signal allows retrieval of key beam and atmospheric turbulence characteristics including scintillation index and the path-integrated refractive index structure parameter.
NASA Astrophysics Data System (ADS)
Rickly, Pamela; Stevens, Philip S.
2018-01-01
Reactions of the hydroxyl radical (OH) play a central role in the chemistry of the atmosphere, and measurements of its concentration can provide a rigorous test of our understanding of atmospheric oxidation. Several recent studies have shown large discrepancies between measured and modeled OH concentrations in forested areas impacted by emissions of biogenic volatile organic compounds (BVOCs), where modeled concentrations were significantly lower than measurements. A potential reason for some of these discrepancies involves interferences associated with the measurement of OH using the laser-induced fluorescence-fluorescence assay by gas expansion (LIF-FAGE) technique in these environments. In this study, a turbulent flow reactor operating at atmospheric pressure was coupled to a LIF-FAGE cell and the OH signal produced from the ozonolysis of α-pinene, β-pinene, ocimene, isoprene, and 2-methyl-3-buten-2-ol (MBO) was measured. To distinguish between OH produced from the ozonolysis reactions and any OH artifact produced inside the LIF-FAGE cell, an external chemical scrubbing technique was used, allowing for the direct measurement of any interference. An interference under high ozone (between 2 × 1013 and 10 × 1013 cm-3) and BVOC concentrations (between approximately 0.1 × 1012 and 40 × 1012 cm-3) was observed that was not laser generated and was independent of the ozonolysis reaction time. For the ozonolysis of α- and β-pinene, the observed interference accounted for approximately 40 % of the total OH signal, while for the ozonolysis of ocimene the observed interference accounted for approximately 70 % of the total OH signal. Addition of acetic acid to the reactor eliminated the interference, suggesting that the source of the interference in these experiments involved the decomposition of stabilized Criegee intermediates (SCIs) inside the FAGE detection cell. Extrapolation of these measurements to ambient concentrations suggests that these interferences should be below the detection limit of the instrument.
NASA Astrophysics Data System (ADS)
Metelev, S. A.; Lvov, A. V.
2017-12-01
We propose a model of forming the signals and interference in the very low frequency wave range. Using this model, we determine the potentials of the space-polarization interference compensators in a communication channel with natural interference and jamming.
30 CFR 74.7 - Design and construction requirements.
Code of Federal Regulations, 2014 CFR
2014-07-01
... while monitoring atmospheres including such water mists. (f) Electromagnetic interference. The CPDM shall meet the following standards for control of and protection from electromagnetic interference. (1... with Respect to Human Exposure to Radio Frequency Electromagnetic Fields, 3 kHz to 300 GHz) and 47 CFR...
30 CFR 74.7 - Design and construction requirements.
Code of Federal Regulations, 2011 CFR
2011-07-01
... while monitoring atmospheres including such water mists. (f) Electromagnetic interference. The CPDM shall meet the following standards for control of and protection from electromagnetic interference. (1... with Respect to Human Exposure to Radio Frequency Electromagnetic Fields, 3 kHz to 300 GHz) and 47 CFR...
30 CFR 74.7 - Design and construction requirements.
Code of Federal Regulations, 2010 CFR
2010-07-01
... while monitoring atmospheres including such water mists. (f) Electromagnetic interference. The CPDM shall meet the following standards for control of and protection from electromagnetic interference. (1... with Respect to Human Exposure to Radio Frequency Electromagnetic Fields, 3 kHz to 300 GHz) and 47 CFR...
30 CFR 74.7 - Design and construction requirements.
Code of Federal Regulations, 2013 CFR
2013-07-01
... while monitoring atmospheres including such water mists. (f) Electromagnetic interference. The CPDM shall meet the following standards for control of and protection from electromagnetic interference. (1... with Respect to Human Exposure to Radio Frequency Electromagnetic Fields, 3 kHz to 300 GHz) and 47 CFR...
30 CFR 74.7 - Design and construction requirements.
Code of Federal Regulations, 2012 CFR
2012-07-01
... while monitoring atmospheres including such water mists. (f) Electromagnetic interference. The CPDM shall meet the following standards for control of and protection from electromagnetic interference. (1... with Respect to Human Exposure to Radio Frequency Electromagnetic Fields, 3 kHz to 300 GHz) and 47 CFR...
NASA Astrophysics Data System (ADS)
Fuchs, H.; Tan, Z.; Hofzumahaus, A.; Broch, S.; Dorn, H.-P.; Holland, F.; Künstler, C.; Gomm, S.; Rohrer, F.; Schrade, S.; Tillmann, R.; Wahner, A.
2015-11-01
Direct detection of highly reactive, atmospheric hydroxyl radicals (OH) is widely accomplished by laser-induced fluorescence (LIF) instruments. The technique is also suitable for the indirect measurement of HO2 and RO2 peroxy radicals by chemical conversion to OH. It requires sampling of ambient air into a low pressure cell, where OH fluorescence is detected after excitation by 308 nm laser radiation. Although the residence time of air inside the fluorescence cell is typically only on the order of milliseconds, there is potential that additional OH is internally produced, which would artificially increase the measured OH concentration. Here, we present experimental studies investigating potential interferences in the detection of OH and peroxy radicals for the LIF instruments of Forschungszentrum Jülich for nighttime conditions. For laboratory experiments, the inlet of the instrument was overflown by excess synthetic air containing one or more reactants. In order to distinguish between OH produced by reactions upstream of the inlet and artificial signals produced inside the instrument, a chemical titration for OH was applied. Additional experiments were performed in the simulation chamber SAPHIR where simultaneous measurements by an open-path differential optical absorption spectrometer (DOAS) served as reference for OH to quantify potential artifacts in the LIF instrument. Experiments included the investigation of potential interferences related to the nitrate radical (NO3, N2O5), related to the ozonolysis of alkenes (ethene, propene, 1-butene, 2,3-dimethyl-2-butene, α-pinene, limonene, isoprene), and the laser photolysis of acetone. Experiments studying the laser photolysis of acetone yield OH signals in the fluorescence cell, which are equivalent to 0.05 × 106 cm-3 OH for a mixing ratio of 5 ppbv acetone. Under most atmospheric conditions, this interference is negligible. No significant interferences were found for atmospheric concentrations of reactants during ozonolysis experiments. Only for α-pinene, limonene, and isoprene at reactant concentrations which are orders of magnitude higher than in the atmosphere artificial OH could be detected. The value of the interference depends on the turnover rate of the ozonolysis reaction. For example, an apparent OH concentration of approximately 1 × 106 cm-3 is observed, if 5.8 ppbv limonene reacts with 600 ppbv ozone. Experiments with the nitrate radical NO3 reveal a small interference signal in the OH, HO2 and RO2 detection. Dependencies on experimental parameters point to artificial OH formation by surface reactions at the chamber walls or in molecular clusters in the gas expansion. The signal scales with the presence of NO3 giving equivalent radical concentrations of 1.1 × 105 cm-3 OH, 1 × 107 cm-3 HO2, and 1.7 × 107 cm-3 RO2 per 10 pptv NO3.
NASA Astrophysics Data System (ADS)
Fuchs, Hendrik; Tan, Zhaofeng; Hofzumahaus, Andreas; Broch, Sebastian; Dorn, Hans-Peter; Holland, Frank; Künstler, Christopher; Gomm, Sebastian; Rohrer, Franz; Schrade, Stephanie; Tillmann, Ralf; Wahner, Andreas
2016-04-01
Direct detection of highly reactive, atmospheric hydroxyl radicals (OH) is widely accomplished by laser-induced fluorescence (LIF) instruments. The technique is also suitable for the indirect measurement of HO2 and RO2 peroxy radicals by chemical conversion to OH. It requires sampling of ambient air into a low-pressure cell, where OH fluorescence is detected after excitation by 308 nm laser radiation. Although the residence time of air inside the fluorescence cell is typically only on the order of milliseconds, there is potential that additional OH is internally produced, which would artificially increase the measured OH concentration. Here, we present experimental studies investigating potential interferences in the detection of OH and peroxy radicals for the LIF instruments of Forschungszentrum Jülich for nighttime conditions. For laboratory experiments, the inlet of the instrument was over flowed by excess synthetic air containing one or more reactants. In order to distinguish between OH produced by reactions upstream of the inlet and artificial signals produced inside the instrument, a chemical titration for OH was applied. Additional experiments were performed in the simulation chamber SAPHIR where simultaneous measurements by an open-path differential optical absorption spectrometer (DOAS) served as reference for OH to quantify potential artifacts in the LIF instrument. Experiments included the investigation of potential interferences related to the nitrate radical (NO3, N2O5), related to the ozonolysis of alkenes (ethene, propene, 1-butene, 2,3-dimethyl-2-butene, α-pinene, limonene, isoprene), and the laser photolysis of acetone. Experiments studying the laser photolysis of acetone yield OH signals in the fluorescence cell, which are equivalent to 0.05 × 106 cm-3 OH for a mixing ratio of 5 ppbv acetone. Under most atmospheric conditions, this interference is negligible. No significant interferences were found for atmospheric concentrations of reactants during ozonolysis experiments. Only for propene, α-pinene, limonene, and isoprene at reactant concentrations, which are orders of magnitude higher than in the atmosphere, could artificial OH be detected. The value of the interference depends on the turnover rate of the ozonolysis reaction. For example, an apparent OH concentration of approximately 1 × 106 cm-3 is observed when 5.8 ppbv limonene reacts with 600 ppbv ozone. Experiments with the nitrate radical NO3 reveal a small interference signal in the OH, HO2, and RO2 detection. Dependencies on experimental parameters point to artificial OH formation by surface reactions at the chamber walls or in molecular clusters in the gas expansion. The signal scales with the presence of NO3 giving equivalent radical concentrations of 1.1 × 105 cm-3 OH, 1 × 107 cm-3 HO2, and 1.7 × 107 cm-3 RO2 per 10 pptv NO3.
NASA Technical Reports Server (NTRS)
Laymon, Charles; Srinivasan, Karthik; Limaye, Ashutosh
2011-01-01
Passive remote sensing of the Earth s surface and atmosphere from space has significant importance in operational and research environmental studies, in particular for the scientific understanding, monitoring and prediction of climate change and its impacts. Passive remote sensing requires the measurement of naturally occurring radiations, usually of very low power levels, which contain essential information on the physical process under investigation. As such, these sensed radio frequency bands are a unique natural resource enabling space borne passive sensing of the atmosphere and the Earth s surface that deserves adequate allocation to the Earth Exploration Satellite Service and absolute protection from interference. Unfortunately, radio frequency interference (RFI) is an increasing problem for Earth remote sensing, particularly for passive observations of natural emissions. Because these natural signals tend to be very weak, even low levels of interference received by a passive sensor may degrade the fidelity of scientific data. The characteristics of RFI (low-level interference and radar-pulse noise) are not well known because there has been no systematic surveillance, spectrum inventory or mapping of RFI. While conducting a flight experiment over central Tennessee in May 2010, RFI, a concern for any instrument operating in the passive L band frequency, was observed across 16 subbands between 1402-1427 MHz. Such a survey provides rare characterization data from which to further develop mitigation technologies as well as to identify bandwidths to avoid in future sensor formulation.
NASA Astrophysics Data System (ADS)
Lew, Michelle M.; Dusanter, Sebastien; Stevens, Philip S.
2018-01-01
One technique used to measure concentrations of the hydroperoxy radical (HO2) in the atmosphere involves chemically converting it to OH by addition of NO and subsequent detection of OH. However, some organic peroxy radicals (RO2) can also be rapidly converted to HO2 (and subsequently OH) in the presence of NO, interfering with measurements of ambient HO2 radical concentrations. This interference must be characterized for each instrument to determine to what extent various RO2 radicals interfere with measurements of HO2 and to assess the impact of this interference on past measurements. The efficiency of RO2-to-HO2 conversion for the Indiana University laser-induced fluorescence-fluorescence assay by gas expansion (IU-FAGE) instrument was measured for a variety of RO2 radicals. Known quantities of OH and HO2 radicals were produced from the photolysis of water vapor at 184.9 nm, and RO2 radicals were produced by the reaction of several volatile organic compounds (VOCs) with OH. The conversion efficiency of RO2 radicals to HO2 was measured when NO was added to the sampling cell for conditions employed during several previous field campaigns. For these conditions, approximately 80 % of alkene-derived RO2 radicals and 20 % of alkane-derived RO2 radicals were converted to HO2. Based on these measurements, interferences from various RO2 radicals contributed to approximately 35 % of the measured HO2 signal during the Mexico City Metropolitan Area (MCMA) 2006 campaign (MCMA-2006), where the measured VOCs consisted of a mixture of saturated and unsaturated species. However, this interference can contribute more significantly to the measured HO2 signal in forested environments dominated by unsaturated biogenic emissions such as isoprene.
Methods for determination of low-molecular weight carbonyl compounds in the ambient atmosphere
DOE Office of Scientific and Technical Information (OSTI.GOV)
Vairavamurthy, A.; Roberts, J.M.; Newman, L.
1991-01-01
Determination of carbonyl compounds in the ambient atmosphere is receiving increasing attention because of the critical role these compounds play in tropospheric organic chemistry. Currently, field measurements are very limited mainly because of the analytical challenges posed by trace concentrations and interferences arising from atmospheric copollutants. We review here the methods for used for determination of carbonyl compounds, from an atmospheric chemistry perspective, emphasizing the principles, advantages, and limitations. Since a large number of varied types of methods have been used specifically for determination of formaldehyde, it is considered separately from other carbonyls. It is clear that despite more thanmore » a decade of work, many problems related to sampling, interferences, and artifacts have not been resolved. Because of the increasing demand for time-series measurements in field studies, and automated method for continuous sampling and analysis of carbonyls is very much required. The widely used liquid chromatographic method based on 2,4-dinitrophenylhydrazine derivatization appears unsuitable for this purpose because of the lengthy collection times required to achieve sub-ppbv detection limits. Important issues to be considered in the development of a suitable field method and potential approaches are discussed. 155 refs., 19 figs., 5 tabs.« less
NASA Astrophysics Data System (ADS)
Ivanov, M. P.; Tolmachev, Yu. A.
2018-05-01
We consider the most feasible ways to significantly improve the sensitivity of spectroscopic methods for detection and measurement of trace concentrations of greenhouse gas molecules in the atmosphere. The proposed methods are based on combining light fluxes from a number of spectral components of the specified molecule on the same photodetector, taking into account the characteristic features of the transmission spectrum of devices utilizing multipath interference effects.
RFI and Remote Sensing of the Earth from Space
NASA Technical Reports Server (NTRS)
Le Vine, D. M.; Johnson, J. T.; Piepmeier, J.
2016-01-01
Passive microwave remote sensing of the Earth from space provides information essential for understanding the Earth's environment and its evolution. Parameters such as soil moisture, sea surface temperature and salinity, and profiles of atmospheric temperature and humidity are measured at frequencies determined by the physics (e.g. sensitivity to changes in desired parameters) and by the availability of suitable spectrum free from interference. Interference from manmade sources (radio frequency interference) is an impediment that in many cases limits the potential for accurate measurements from space. A review is presented here of the frequencies employed in passive microwave remote sensing of the Earth from space and the associated experience with RFI.
NASA Technical Reports Server (NTRS)
Pliutau, Denis; Prasad, Narasimha S.
2013-01-01
We performed comparative studies to establish favorable spectral regions and measurement wavelength combinations in alternative bands of CO2 and O2, for the sensing of CO2 mixing ratios (XCO2) in missions such as ASCENDS. The analysis employed several simulation approaches including separate layers calculations based on pre-analyzed atmospheric data from the modern-era retrospective analysis for research and applications (MERRA), and the line-byline radiative transfer model (LBLRTM) to obtain achievable accuracy estimates as a function of altitude and for the total path over an annual span of variations in atmospheric parameters. Separate layer error estimates also allowed investigation of the uncertainties in the weighting functions at varying altitudes and atmospheric conditions. The parameters influencing the measurement accuracy were analyzed independently and included temperature sensitivity, water vapor interferences, selection of favorable weighting functions, excitations wavelength stabilities and other factors. The results were used to identify favorable spectral regions and combinations of on / off line wavelengths leading to reductions in interferences and the improved total accuracy.
NASA Technical Reports Server (NTRS)
Pliutau, Denis; Prasad, Narasimha S.
2012-01-01
In this paper a modeling method based on data reductions is investigated which includes pre analyzed MERRA atmospheric fields for quantitative estimates of uncertainties introduced in the integrated path differential absorption methods for the sensing of various molecules including CO2. This approach represents the extension of our existing lidar modeling framework previously developed and allows effective on- and offline wavelength optimizations and weighting function analysis to minimize the interference effects such as those due to temperature sensitivity and water vapor absorption. The new simulation methodology is different from the previous implementation in that it allows analysis of atmospheric effects over annual spans and the entire Earth coverage which was achieved due to the data reduction methods employed. The effectiveness of the proposed simulation approach is demonstrated with application to the mixing ratio retrievals for the future ASCENDS mission. Independent analysis of multiple accuracy limiting factors including the temperature, water vapor interferences, and selected system parameters is further used to identify favorable spectral regions as well as wavelength combinations facilitating the reduction in total errors in the retrieved XCO2 values.
Atmospheric chemistry: Description of the area of performance and a working plan
NASA Astrophysics Data System (ADS)
Kirchhoff, Volker W. J. H.
1986-11-01
INPE's program in Atmospheric Chemistry Research is described. Research in this area is concerned with atmospheric gases and their chemical reactions, production and loss rates, and their interactions with the biosphere. Atmospheric chemistry includes concepts in Physics, Chemistry, Meteorology, and Biology, which gives it a strong interdisciplinary character. The interaction of some of the atmospheric gases with the biosphere, such as ozone, is very strong and direct. Studying atmospheric chemistry is, therefore, of direct interest to man and the quality of life. Details are described to define the objectives of study, in particular those of our research program at INPE. A working plan is proposed in order to reach the defined goals. Owing to the large anthropogenic interference in the balance of the natural atmosphere it is anticipated that a better understanding of Atmospheric Chemistry will be the great scientific challenge of the next decade.
NASA Astrophysics Data System (ADS)
Turnipseed, Andrew A.; Andersen, Peter C.; Williford, Craig J.; Ennis, Christine A.; Birks, John W.
2017-06-01
A new solid-phase scrubber for use in conventional ozone (O3) photometers was investigated as a means of reducing interferences from other UV-absorbing species and water vapor. It was found that when heated to 100-130 °C, a tubular graphite scrubber efficiently removed up to 500 ppb ozone and ozone monitors using the heated graphite scrubber were found to be less susceptible to interferences from water vapor, mercury vapor, and aromatic volatile organic compounds (VOCs) compared to conventional metal oxide scrubbers. Ambient measurements from a graphite scrubber-equipped photometer and a co-located Federal equivalent method (FEM) ozone analyzer showed excellent agreement over 38 days of measurements and indicated no loss in the scrubber's ability to remove ozone when operated at 130 °C. The use of a heated graphite scrubber was found to reduce the interference from mercury vapor to ≤ 3 % of that obtained using a packed-bed Hopcalite scrubber. For a series of substituted aromatic compounds (ranging in volatility and absorption cross section at 253.7 nm), the graphite scrubber was observed to consistently exhibit reduced levels of interference, typically by factors of 2.5 to 20 less than with Hopcalite. Conventional solid-phase scrubbers also exhibited complex VOC adsorption and desorption characteristics that were dependent upon the relative humidity (RH), volatility of the VOC, and the available surface area of the scrubber. This complex behavior involving humidity is avoided by use of a heated graphite scrubber. These results suggest that heated graphite scrubbers could be substituted in most ozone photometers as a means of reducing interferences from other UV-absorbing species found in the atmosphere. This could be particularly important in ozone monitoring for compliance with the United States (U.S.) Clean Air Act or for use in VOC-rich environments such as in smog chambers and monitoring indoor air quality.
Selection of fluorescence lidar operating parameters for SNR maximization
NASA Technical Reports Server (NTRS)
Heaps, W. S.
1981-01-01
Fluorescence lidar when applicable offers one of the most sensitive methods for measuring the concentration of trace constituents of the atmosphere. In the conduct of a fluorescence lidar experiment, a number of parameters which can be used to optimize the SNR can be controlled. In this paper the optimum division of laser pulses centered on and off the fluorescence excitation wavelength is calculated as a function of the ratio of the fluorescence signal strength to the strength of fluorescence from interfering species. For strong interference signals the time should be divided equally on and off the line. For strong fluorescence signals the time on line is proportional to the square root of the on-line off-line signal ratio. The optimization of the integration time for varying values of signal-to-background and signal-to-interference ratios, atmospheric attenuation, laser energy variations, background measurement time, and on-line off-line time division is also considered.
Research on the method of precise alignment technology of atmospheric laser communication
NASA Astrophysics Data System (ADS)
Chen, Wen-jian; Gao, Wei; Duan, Yuan-yuan; Ma, Shi-wei; Chen, Jian
2016-10-01
Atmosphere laser communication takes advantage of laser as the carrier transmitting the voice, data, and image information in the atmosphere. Because of its high reliability, strong anti-interference ability, the advantages of easy installation, it has great potential and development space in the communications field. In the process of establish communication, the capture, targeting and tracking of the communication signal is the key technology. This paper introduce a method of targeting the signal spot in the process of atmosphere laser communication, which through the way of making analog signal addition and subtraction directly and normalized to obtain the target azimuth information to drive the servo system to achieve precise alignment of tracking.
Zou, Ye; Ma, Gang
2014-06-04
Second derivative and Fourier self-deconvolution (FSD) are two commonly used techniques to resolve the overlapped component peaks from the often featureless amide I band in Fourier transform infrared (FTIR) curve-fitting approach for protein secondary structural analysis. Yet, the reliability of these two techniques is greatly affected by the omnipresent water vapor in the atmosphere. Several criteria are currently in use as quality controls to ensure the protein absorption spectrum is negligibly affected by water vapor interference. In this study, through a second derivative study of liquid water, we first argue that the previously established criteria cannot guarantee a reliable evaluation of water vapor interference due to a phenomenon that we refer to as sample's absorbance-dependent water vapor interference. Then, through a comparative study of protein and liquid water, we show that a protein absorption spectrum can still be significantly affected by water vapor interference even though it satisfies the established criteria. At last, we propose to use the comparison between the second derivative spectra of protein and liquid water as a new criterion to better evaluate water vapor interference for more reliable second derivative and FSD treatments on the protein amide I band.
A FURTHER EVALUATION OF MICROCOULOMETRY FOR ATMOSPHERIC NITRIC ACID MONITORING
A coulometric instrument for measuring gaseous nitric acid is modified to improve response time characteristics and simplify operation. Possible interferences were investigated and found minimal. Comparison measurements of nitric acid by long path Fourier Transform infrared analy...
Static magnetic Faraday rotation spectroscopy combined with a differential scheme for OH detection
NASA Astrophysics Data System (ADS)
Zhao, Weixiong; Deng, Lunhua; Qian, Xiaodong; Fang, Bo; Gai, Yanbo; Chen, Weidong; Gao, Xiaoming; Zhang, Weijun
2015-04-01
The hydroxyl (OH) radical plays a critical role in atmospheric chemistry due to its high reactivity with volatile organic compounds (VOCs) and other trace gaseous species. Because of its very short life time and very low concentration in the atmosphere, interference-free high sensitivity in-situ OH monitoring by laser spectroscopy represents a real challenge. Faraday rotation spectroscopy (FRS) relies on the particular magneto-optic effect observed for paramagnetic species, which makes it capable of enhancing the detection sensitivity and mitigation of spectral interferences from diamagnetic species in the atmosphere. When an AC magnetic field is used, the Zeeman splitting of the molecular absorption line (and thus the magnetic circular birefringence) is modulated. This provides an 'internal modulation' of the sample, which permits to suppress the external noise like interference fringes. An alternative FRS detection scheme is to use a static magnetic field (DC-field) associated with laser wavelength modulation to effectively modulate the Zeeman splitting of the absorption lines. In the DC field case, wavelength modulation of the laser frequency can provide excellent performance compared to most of the sensing systems based on direct absorption and wavelength modulation spectroscopy. The dimension of the DC solenoid is not limited by the resonant frequency of the RLC circuit, which makes large dimension solenoid coil achievable and the absorption base length could be further increased. By employing a combination of the environmental photochemical reactor or smog chamber with multipass absorption cell, one can lower the minimum detection limit for high accuracy atmospheric chemistry studies. In this paper, we report on the development of a DC field based FRS in conjunction with a balanced detection scheme for OH radical detection at 2.8 μm and the construction of OH chemistry research platform which combined a large dimension superconducting magnetic coil with the multipass cell and photochemical reactor chamber for real time in-situ measurement of OH radical concentration in the chamber.
NASA Astrophysics Data System (ADS)
Ozbay, Ahmet
A comprehensive experimental study was conducted to investigate wind turbine aeromechanics and wake interferences among multiple wind turbines sited in onshore and offshore wind farms. The experiments were carried out in a large-scale Aerodynamic/Atmospheric Boundary Layer (AABL) Wind Tunnel available at Iowa State University. An array of scaled three-blade Horizontal Axial Wind Turbine (HAWT) models were placed in atmospheric boundary layer winds with different mean and turbulence characteristics to simulate the situations in onshore and offshore wind farms. The effects of the important design parameters for wind farm layout optimization, which include the mean and turbulence characteristics of the oncoming surface winds, the yaw angles of the turbines with respect to the oncoming surface winds, the array spacing and layout pattern, and the terrain topology of wind farms on the turbine performances (i.e., both power output and dynamic wind loadings) and the wake interferences among multiple wind turbines, were assessed in detail. The aeromechanic performance and near wake characteristics of a novel dual-rotor wind turbine (DRWT) design with co-rotating or counter-rotating configuration were also investigated, in comparison to a conventional single rotor wind turbine (SRWT). During the experiments, in addition to measuring dynamic wind loads (both forces and moments) and the power outputs of the scaled turbine models, a high-resolution Particle Image Velocity (PIV) system was used to conduct detailed flow field measurements (i.e., both free-run and phase-locked flow fields measurements) to reveal the transient behavior of the unsteady wake vortices and turbulent flow structures behind wind turbines and to quantify the characteristics of the wake interferences among the wind turbines sited in non-homogenous surface winds. A miniature cobra anemometer was also used to provide high-temporal-resolution data at points of interest to supplement the full field PIV measurement results. The detailed flow field measurements are correlated with the dynamic wind loads and power output measurements to elucidate underlying physics in order to gain further insight into the characteristics of the power generation performance, dynamic wind loads and wake interferences of the wind turbines for higher total power yield and better durability of the wind turbines sited in atmospheric boundary layer (ABL) winds.
Initial Results from SQUID Sensor: Analysis and Modeling for the ELF/VLF Atmospheric Noise.
Hao, Huan; Wang, Huali; Chen, Liang; Wu, Jun; Qiu, Longqing; Rong, Liangliang
2017-02-14
In this paper, the amplitude probability density (APD) of the wideband extremely low frequency (ELF) and very low frequency (VLF) atmospheric noise is studied. The electromagnetic signals from the atmosphere, referred to herein as atmospheric noise, was recorded by a mobile low-temperature superconducting quantum interference device (SQUID) receiver under magnetically unshielded conditions. In order to eliminate the adverse effect brought by the geomagnetic activities and powerline, the measured field data was preprocessed to suppress the baseline wandering and harmonics by symmetric wavelet transform and least square methods firstly. Then statistical analysis was performed for the atmospheric noise on different time and frequency scales. Finally, the wideband ELF/VLF atmospheric noise was analyzed and modeled separately. Experimental results show that, Gaussian model is appropriate to depict preprocessed ELF atmospheric noise by a hole puncher operator. While for VLF atmospheric noise, symmetric α -stable (S α S) distribution is more accurate to fit the heavy-tail of the envelope probability density function (pdf).
Initial Results from SQUID Sensor: Analysis and Modeling for the ELF/VLF Atmospheric Noise
Hao, Huan; Wang, Huali; Chen, Liang; Wu, Jun; Qiu, Longqing; Rong, Liangliang
2017-01-01
In this paper, the amplitude probability density (APD) of the wideband extremely low frequency (ELF) and very low frequency (VLF) atmospheric noise is studied. The electromagnetic signals from the atmosphere, referred to herein as atmospheric noise, was recorded by a mobile low-temperature superconducting quantum interference device (SQUID) receiver under magnetically unshielded conditions. In order to eliminate the adverse effect brought by the geomagnetic activities and powerline, the measured field data was preprocessed to suppress the baseline wandering and harmonics by symmetric wavelet transform and least square methods firstly. Then statistical analysis was performed for the atmospheric noise on different time and frequency scales. Finally, the wideband ELF/VLF atmospheric noise was analyzed and modeled separately. Experimental results show that, Gaussian model is appropriate to depict preprocessed ELF atmospheric noise by a hole puncher operator. While for VLF atmospheric noise, symmetric α-stable (SαS) distribution is more accurate to fit the heavy-tail of the envelope probability density function (pdf). PMID:28216590
Wang, Jun; Zheng, Jiao; Lu, Hong; Yan, Qing; Wang, Li; Liu, Jingjing; Hua, Dengxin
2017-11-01
Atmospheric temperature is one of the important parameters for the description of the atmospheric state. Most of the detection approaches to atmospheric temperature monitoring are based on rotational Raman scattering for better understanding atmospheric dynamics, thermodynamics, atmospheric transmission, and radiation. In this paper, we present a fine-filter method based on wavelength division multiplexing, incorporating a fiber Bragg grating in the visible spectrum for the rotational Raman scattering spectrum. To achieve high-precision remote sensing, the strong background noise is filtered out by using the secondary cascaded light paths. Detection intensity and the signal-to-noise ratio are improved by increasing the utilization rate of return signal form atmosphere. Passive temperature compensation is employed to reduce the temperature sensitivity of fiber Bragg grating. In addition, the proposed method provides a feasible solution for the filter system with the merits of miniaturization, high anti-interference, and high stability in the space-based platform.
Thermal tides in the dusty martian atmosphere: a verification of theory.
Zurek, R W; Leovy, C B
1981-07-24
Major features of the daily surface pressure oscillations observed by the Viking landers during the two great dust storms on Mars in 1977 can be explained in terms of the classical atmospheric tidal theory developed for the earth's atmosphere. The most dramatic exception is the virtual disappearance of only the diurnal tide at Viking Lander 1 just before the second storm. This disappearance is attributed to destructive interference between the usually westward-traveling tide and an eastward-traveling diurnal Kelvin mode generated by orographically induced differential heating. The continuing Viking Lander 1 pressure measurements can be used with the model to monitor future great dust storms.
Statistical characteristics of MST radar echoes and its interpretation
NASA Technical Reports Server (NTRS)
Woodman, Ronald F.
1989-01-01
Two concepts of fundamental importance are reviewed: the autocorrelation function and the frequency power spectrum. In addition, some turbulence concepts, the relationship between radar signals and atmospheric medium statistics, partial reflection, and the characteristics of noise and clutter interference are discussed.
Interference in astronomical speckle patterns
NASA Technical Reports Server (NTRS)
Breckinridge, J. B.
1976-01-01
Astronomical speckle patterns are examined in an atmospheric-optics context in order to determine what kind of image quality is to be expected from several different imaging techniques. The model used to describe the instantaneous complex field distribution across the pupil of a large telescope regards the pupil as a deep phase grating with a periodicity given by the size of the cell of uniform phase or the refractive index structure function. This model is used along with an empirical formula derived purely from the physical appearance of the speckle patterns to discuss the orders of interference in astronomical speckle patterns.
NASA Technical Reports Server (NTRS)
Flamant, Cyrille N.; Schwemmer, Geary K.; Korb, C. Laurence; Evans, Keith D.; Palm, Stephen P.
1999-01-01
Remote airborne measurements of the vertical and horizontal structure of the atmospheric pressure field in the lower troposphere are made with an oxygen differential absorption lidar (DIAL). A detailed analysis of this measurement technique is provided which includes corrections for imprecise knowledge of the detector background level, the oxygen absorption fine parameters, and variations in the laser output energy. In addition, we analyze other possible sources of systematic errors including spectral effects related to aerosol and molecular scattering interference by rotational Raman scattering and interference by isotopic oxygen fines.
Trends in aerosol abundances and distributions
NASA Technical Reports Server (NTRS)
Turco, R. P.; Mccormick, M. P.; Clancy, R. T.; Curran, R.; Deluisi, J.; Hamill, P.; Kent, G.; Rosen, J. M.; Toon, O. B.; Yue, G.
1989-01-01
The properties of aerosols that reside in the upper atmosphere are described. Special emphasis is given to the influence these aerosols have on ozone observation systems, mainly through radiative effects, and on ambient ozone concentrations, mainly through chemical effects. It has long been appreciated that stratospheric particles can interfere with the remote sensing of ozone distribution. The mechanism and magnitude of this interference are evaluated. Separate sections deal with the optical properties of upper atmospheric aerosols, long-term trends in stratospheric aerosols, perturbations of the stratospheric aerosol layer by volcanic eruptions, and estimates of the impacts that such particles have on remotely measured ozone concentrations. Another section is devoted to a discussion of the polar stratospheric clouds (PSC's). These unique clouds, recently discovered by satellite observation, are now thought to be intimately connected with the Antarctic ozone hole. Accordingly, interest in PSC's has grown considerably in recent years. This chapter describes what we know about the morphology, physical chemistry, and microphysics of PSC's.
Method for determination of some soluble atmospheric carbonyl compounds
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lee, Y.N.; Zhou, X.
1993-04-01
A technique was developed for the measurement of soluble atmospheric carbonyl compounds, which uses a pyrex coil gas-liquid scrubber sampler in conjunction with a high-performance liquid chromatograph equipped with a UV-visible detector for separation and identification following derivatization with 2,4-dinitrophenylhydrazine. Carbonyls exhibiting a Henry's law solubility similar to or greater than that of formaldehyde (FA) can be determined by this method; these include FA, glycolaldehyde (GA), glyoxal (GL), and methylglyoxal (MG). Based on liquid standards and field-developed chromatographic characteristics, the limits of detection are about 0.005 ppb (in the gas phase) for MG, about 0.01 ppb for GL, and aboutmore » 0.02 ppb for FA and GA. Because of the short air-liquid contact time in the coil sampler (smaller than 10 s), interferences from aqueous-phase reactions of ozone are insignificant. Also, at the low pH of the scrubbing solution, interference resulting from reactions of carbonyls with S(IV) is unimportant. 43 refs., 7 figs., 3 tabs.« less
NASA Astrophysics Data System (ADS)
Heikes, Brian G.; Treadaway, Victoria; McNeill, Ashley S.; Silwal, Indira K. C.; O'Sullivan, Daniel W.
2018-04-01
An ion-neutral chemical kinetic model is described and used to simulate the negative ion chemistry occurring within a mixed-reagent ion chemical ionization mass spectrometer (CIMS). The model objective was the establishment of a theoretical basis to understand ambient pressure (variable sample flow and reagent ion carrier gas flow rates), water vapor, ozone and oxides of nitrogen effects on ion cluster sensitivities for hydrogen peroxide (H2O2), methyl peroxide (CH3OOH), formic acid (HFo) and acetic acid (HAc). The model development started with established atmospheric ion chemistry mechanisms, thermodynamic data and reaction rate coefficients. The chemical mechanism was augmented with additional reactions and their reaction rate coefficients specific to the analytes. Some existing reaction rate coefficients were modified to enable the model to match laboratory and field campaign determinations of ion cluster sensitivities as functions of CIMS sample flow rate and ambient humidity. Relative trends in predicted and observed sensitivities are compared as instrument specific factors preclude a direct calculation of instrument sensitivity as a function of sample pressure and humidity. Predicted sensitivity trends and experimental sensitivity trends suggested the model captured the reagent ion and cluster chemistry and reproduced trends in ion cluster sensitivity with sample flow and humidity observed with a CIMS instrument developed for atmospheric peroxide measurements (PCIMSs). The model was further used to investigate the potential for isobaric compounds as interferences in the measurement of the above species. For ambient O3 mixing ratios more than 50 times those of H2O2, O3-(H2O) was predicted to be a significant isobaric interference to the measurement of H2O2 using O2-(H2O2) at m/z 66. O3 and NO give rise to species and cluster ions, CO3-(H2O) and NO3-(H2O), respectively, which interfere in the measurement of CH3OOH using O2-(CH3OOH) at m/z 80. The CO3-(H2O) interference assumed one of its O atoms was 18O and present in the cluster in proportion to its natural abundance. The model results indicated monitoring water vapor mixing ratio, m/z 78 for CO3-(H2O) and m/z 98 for isotopic CO3-(H2O)2 can be used to determine when CO3-(H2O) interference is significant. Similarly, monitoring water vapor mixing ratio, m/z 62 for NO3- and m/z 98 for NO3-(H2O)2 can be used to determine when NO3-(H2O) interference is significant.
NASA Astrophysics Data System (ADS)
Zhang, Jiankun; Li, Ziyang; Dang, Anhong
2018-06-01
It has been recntly shown that polarization state of propagation beam would suffer from polarization fluctuations due to the detrimental effects of atmospheric turbulence. This paper studies the performance of wireless optical communication (WOC) systems in the presence of polarization effect of atmosphere. We categorize the atmospheric polarization effect into polarization rotation, polarization-dependent power loss, and phase shift effect, with each effect described and modeled with the help of polarization-coherence theory and the extended Huygens-Fresnelprinciple. The channel matrices are derived to measure the cross-polarization interference of the system. Signal-to-noise ratio and bit error rate for polarization multiplexing system and polarization modulation system are obtained to assess the viability using the approach of M turbulence model. Monte Carlo simulation results show the performance of polarization based WOC systems to be degraded by atmospheric polarization effect, which could be evaluated precisely using the proposed model with given turbulent strengths.
Wideband Channel Modeling in Real Atmospheric Environments with Experimental Evaluation
2013-04-01
5] D. F. Gingras and P. Gerstoft. 1997. “The Effect of Propagation on Wideband DS - CDMA Systems in the Suburban Environment,” The First IEEE...are commonly used in spread spectrum communication systems such as Code Division Multiple Access ( CDMA ) systems. Narrowband interference mitigation
Incivility in the Accounting Classroom
ERIC Educational Resources Information Center
Swinney, Laurie; Elder, Bruce; Seaton, Lloyd
2010-01-01
Classroom incivility is any action that interferes with a harmonious and cooperative learning atmosphere in the classroom (Feldman, 2001). We compared the perceptions of accounting faculty to the perceptions of cross-disciplinary faculty relating to both the definition of student actions as incivility and the occurrence of incivility. We also…
Ground-based remote sensing of tropospheric water vapour isotopologues within the project MUSICA
NASA Astrophysics Data System (ADS)
Schneider, M.; Barthlott, S.; Hase, F.; González, Y.; Yoshimura, K.; García, O. E.; Sepúlveda, E.; Gomez-Pelaez, A.; Gisi, M.; Kohlhepp, R.; Dohe, S.; Blumenstock, T.; Strong, K.; Weaver, D.; Palm, M.; Deutscher, N. M.; Warneke, T.; Notholt, J.; Lejeune, B.; Demoulin, P.; Jones, N.; Griffith, D. W. T.; Smale, D.; Robinson, J.
2012-08-01
Within the project MUSICA (MUlti-platform remote Sensing of Isotopologues for investigating the Cycle of Atmospheric water), long-term tropospheric water vapour isotopologues data records are provided for ten globally distributed ground-based mid-infrared remote sensing stations of the NDACC (Network for the Detection of Atmospheric Composition Change). We present a new method allowing for an extensive and straightforward characterisation of the complex nature of such isotopologue remote sensing datasets. We demonstrate that the MUSICA humidity profiles are representative for most of the troposphere with a vertical resolution ranging from about 2 km (in the lower troposphere) to 8 km (in the upper troposphere) and with an estimated precision of better than 10%. We find that the sensitivity with respect to the isotopologue composition is limited to the lower and middle troposphere, whereby we estimate a precision of about 30‰ for the ratio between the two isotopologues HD16O and H216O. The measurement noise, the applied atmospheric temperature profiles, the uncertainty in the spectral baseline, and interferences from humidity are the leading error sources. We introduce an a posteriori correction method of the humidity interference error and we recommend applying it for isotopologue ratio remote sensing datasets in general. In addition, we present mid-infrared CO2 retrievals and use them for demonstrating the MUSICA network-wide data consistency. In order to indicate the potential of long-term isotopologue remote sensing data if provided with a well-documented quality, we present a climatology and compare it to simulations of an isotope incorporated AGCM (Atmospheric General Circulation Model). We identify differences in the multi-year mean and seasonal cycles that significantly exceed the estimated errors, thereby indicating deficits in the modeled atmospheric water cycle.
Martian Atmospheric Dust Mitigation for ISRU Intakes via Electrostatic Precipitation
NASA Technical Reports Server (NTRS)
Phillips, James R., III; Pollard, Jacob R. S.; Johansen, Michael R.; Mackey, Paul J.; Clements, J. Sid; Calle, Carlos I.
2016-01-01
The Mars 2020 and Mars Sample Return missions expected to fly to Mars within the next ten years will each include an In Situ Resource Utilization (ISRU) system. They convert carbon dioxide in the Martian atmosphere into consumable oxygen at 1% and 20% of the rate required by a full scale human exploration Mars mission, respectively. The ISRU systems will need to draw in the surrounding atmosphere at a rate of 110L/min and 550L/min, respectively, in order to meet their oxygen production goals. Over the duration of each respective mission, a total atmospheric dust mass of 4.86g and 243g will be drawn into each system, respectively. Ingestion of large quantities of dust may interfere with ISRU operations, so a dust mitigation device will be required. The atmospheric volume and dust mass flow rates above will be utilized to simulate Martian environmental conditions in a laboratory electrostatic precipitator being developed to provide active dust mitigation support for atmospheric ISRU systems such as these.
An Acousto-Optical Sensor with High Angular Resolution
Kaloshin, Gennady; Lukin, Igor
2012-01-01
The paper introduces a new laser interferometry-based sensor for diagnosis of random media by means of high accuracy angle measurements and describes the results of its development and testing. Theoretical calculations of the dependence of the range of the laser interferometer on laser beam parameters, device geometry, and atmospheric turbulence characteristics are reported. It is demonstrated that at moderate turbulence intensities corresponding to those observed most frequently in turbulent atmosphere at moderate latitudes and with low interference contrast values, the performance range of the laser interferometer-based device exceeds 5 km. PMID:22737034
Image plane detector spectrophotometer - Application to O2 atmospheric band nightglow
NASA Technical Reports Server (NTRS)
Luo, Mingzhao; Yee, Jeng-Hwa; Hays, Paul B.
1988-01-01
A new variety of low resolution spectrometer is described. This device, an image plane detector spectrophotometer, has high sensitivity and modest resolution sufficient to determine the rotational temperature and brightness of molecular band emissions. It uses an interference filter as a dispersive element and a multichannel image plane detector as the photon collecting device. The data analysis technqiue used to recover the temperature of the emitter and the emission brightness is presented. The atmospheric band of molecular oxygen is used to illustrate the use of the device.
Measurement of Infrasound from the Marine Environment
2015-09-01
ocean heave, which are due to the change in the background atmospheric pressure as the sensor moves up and down. An external inertial measurement unit ... inertial measurement unit (IMU) was used to estimate the heave, and was highly correlated with the pressure interference signal. Mission area... MEASUREMENT UNIT ..................................................... 13 ADAPTIVE NOISE CANCELATION
The natural greenhouse effect of atmospheric oxygen (O2) and nitrogen (N2)
NASA Astrophysics Data System (ADS)
Höpfner, M.; Milz, M.; Buehler, S.; Orphal, J.; Stiller, G.
2012-05-01
The effect of collision-induced absorption by molecular oxygen (O2) and nitrogen (N2) on the outgoing longwave radiation (OLR) of the Earth's atmosphere has been quantified. We have found that on global average under clear-sky conditions the OLR is reduced due to O2 by 0.11 Wm-2 and due to N2 by 0.17 Wm-2. Together this amounts to 15% of the OLR-reduction caused by CH4 at present atmospheric concentrations. Over Antarctica the combined effect of O2 and N2 increases on average to about 38% of CH4 with single values reaching up to 80%. This is explained by less interference of H2O spectral bands on the absorption features of O2 and N2 for dry atmospheric conditions.
Sensing of the atmospheric variation using Low Cost GNSS Receiver
NASA Astrophysics Data System (ADS)
Bramanto, Brian; Gumilar, Irwan; Sidiq, Teguh P.; Kuntjoro, Wedyanto; Tampubolon, Daniel A.
2018-05-01
As the GNSS signals transmitted through the atmosphere, they are delayed by interference of TEC (Total Electron Content) in the ionosphere and water vapor in the troposphere. By using inverse-problem, name GNSS Meteorology, those parameters can be obtained precisely and several researches has approved and supported that method. However, the geodetic GNSS receivers are relatively high cost (30,000 to 70,000 each) to be established on a regular and uniform network. This research aims to investigate the potential use of low cost GNSS receiver (less than 2,000) to observe the atmospheric dynamic both in ionosphere and troposphere. Results indicated that low cost GNSS receiver is a promising tools to sensing the atmospheric dynamic, however, further processing is needed to enhance the data quality. It is found that both of ionosphere and troposphere dynamic has diurnal periodic component.
Tripathi, R M; Sumesh, C G; Vinod Kumar, A; Puranik, V D
2013-07-01
Pulse ionisation chamber (PIC)-based monitors measuring radioactive gas radon ((222)Rn) without energy discrimination will have interference due to thoron ((220)Rn) present in the atmosphere. A technique has been developed to use this property of interference for simultaneous measurement of radon and thoron gas. These monitors work on the principle of counting of gross alphas emitted from radon and its progeny. A theoretical model has been developed for the variation of thoron sensitivity with respect to the flow rate of gas through the monitor. The thoron sensitivity of the monitor is found to vary with the flow rate of gas through the monitor. Using this sensitivity, the sampling procedure has been developed and verified for simultaneous measurement of radon and thoron. The PIC-measured radon and thoron concentration using this procedure agrees well with those measured by using standard radon and thoron discriminating monitor.
The effect of solar radio bursts on the GNSS radio occultation signals
NASA Astrophysics Data System (ADS)
Yue, Xinan; Schreiner, William S.; Kuo, Ying-Hwa; Zhao, Biqiang; Wan, Weixing; Ren, Zhipeng; Liu, Libo; Wei, Yong; Lei, Jiuhou; Solomon, Stan; Rocken, Christian
2013-09-01
radio burst (SRB) is the radio wave emission after a solar flare, covering a broad frequency range, originated from the Sun's atmosphere. During the SRB occurrence, some specific frequency radio wave could interfere with the Global Navigation Satellite System (GNSS) signals and therefore disturb the received signals. In this study, the low Earth orbit- (LEO-) based high-resolution GNSS radio occultation (RO) signals from multiple satellites (COSMIC, CHAMP, GRACE, SAC-C, Metop-A, and TerraSAR-X) processed in University Corporation for Atmospheric Research (UCAR) were first used to evaluate the effect of SRB on the RO technique. The radio solar telescope network (RSTN) observed radio flux was used to represent SRB occurrence. An extreme case during 6 December 2006 and statistical analysis during April 2006 to September 2012 were studied. The LEO RO signals show frequent loss of lock (LOL), simultaneous decrease on L1 and L2 signal-to-noise ratio (SNR) globally during daytime, small-scale perturbations of SNR, and decreased successful retrieval percentage (SRP) for both ionospheric and atmospheric occultations during SRB occurrence. A potential harmonic band interference was identified. Either decreased data volume or data quality will influence weather prediction, climate study, and space weather monitoring by using RO data during SRB time. Statistically, the SRP of ionospheric and atmospheric occultation retrieval shows ~4% and ~13% decrease, respectively, while the SNR of L1 and L2 show ~5.7% and ~11.7% decrease, respectively. A threshold value of ~1807 SFU of 1415 MHz frequency, which can result in observable GNSS SNR decrease, was derived based on our statistical analysis.
NASA Technical Reports Server (NTRS)
Hofzumahaus, Andreas; Holland, Frank
1994-01-01
Laser-induced fluorescence (LIF) spectroscopy is a highly sensitive method for the direct in situ measurement of hydroxyl concentrations in the atmosphere. Its sensitivity and selectivity relies on the intense discrete UV-absorption lines of OH which are strongest around 282nm and 308nm. We have developed a LIF-instrument based on the low-pressure experiment (FAGE). However, we use 308nm instead of 282nm as excitation wavelength for OH, a concept that is also pursued by other groups. One advantage of the longer excitation wavelength is the higher detection sensitivity due to the about 6 times larger effective OH-fluorescence cross-section. Moreover, the O3/H2O-interference (OH self-generation by the laser) is about a factor of 200 smaller at 308nm than at 282nm. This keeps the interference level well below the projected detection limit of 10(exp 5) OH/cm(exp 3). Atmospheric HO2-radicals are detected by chemical conversion of HO2 into OH with NO.
NASA Astrophysics Data System (ADS)
Hamilton, D.; Honda, M.; Zhang, X.; Phillips, D.; Matchan, E.
2017-12-01
The Helix-MC Plus multi-collector noble gas mass spectrometer at the Australian National University is uniquely equipped with three high mass resolution collectors on H2, Axial and L2 positions. Their mass resolution and mass resolving power are as high as 1,800 and 8,000, respectively. The Helix-MC Plus can totally separate 20Ne+ from 40Ar++ isobaric interference and also partially separate 21Ne+ from 20NeH+ and 22Ne+ from 12C16O2++. By adjusting collector positions, we are able to measure interference-free Ne isotope intensities and have re-determined the 21Ne abundance in air [1]. Analyses by Honda et al. [1] demonstrated that 20Ne1H contributes approximately 2% to previously determined atmospheric 21Ne values [2], and a new atmospheric 21Ne/20Ne ratio of 0.002906 was calculated. Using the Helix-MC Plus mass spectrometer, we measured Ne abundances in the CREU-1 quartz standard [3] and determined cosmogenic concentrations by subtraction of atmospheric Ne with the new atmospheric 21Ne/20Ne value. The average concentration of cosmogenic 21Ne determined from four repeated analyses is 338 ± 12 × 106 atom/g (2σ). This compares with the average concentration of 348 ± 10 × 106 atom/g (2σ) from 45 analyses determined by several laboratories [3], where Ne isotope analyses were undertaken by conventional low resolution mass spectrometers and atmospheric Ne was subtracted using the conventional atmospheric 21Ne/20Ne [2]. On this basis, for a sample with abundant cosmogenic Ne, like CREU-1 quartz, previously measured by low mass resolution mass spectrometers are likely valid and their geological implications are unaffected. However, for low 21Ne concentration samples, combining new generation of mass spectrometers as well as the new atmospheric ratio may have significance for cosmogenic 21Ne surface exposure dating. References: [1] Honda M., et. al., International Journal of Mass Spectrometry, 387, 1 (2015). [2] Eberhardt P., et. al., Zeitschrift fur Naturforschung, 20a, 623 (1965). [3] Vermeesch P., et. al., Quaternary Geochronology, 26, 20 (2015).
First characterization of a static Fourier transform spectrometer
NASA Astrophysics Data System (ADS)
Lacan, A.; Bréon, F.-M.; Rosak, A.; Pierangelo, C.
2017-11-01
A new instrument concept for a Static Fourier Transform Spectrometer has been developed and characterized by CNES. This spectrometer is based on a Michelson interferometer concept, but a system of stepped mirrors generates all interference path differences simultaneously, without any moving parts. The instrument permits high spectral resolution measurements (≍0.1 cm-1) adapted to the sounding and the monitoring of atmospheric gases. Moreover, its overall dimensions are compatible with a micro satellite platform. The stepped mirrors are glued using a molecular bonding technique. An interference filter selects a waveband only a few nanometers wide. It limits the number of sampling points (and consequently the steps number) necessary to achieve the high resolution. The instrument concept can be optimized for the detection and the monitoring of various atmospheric constituents. CNES has developed a version whose measurements are centered on the CO2 absorption lines at 1573 nm (6357 cm-1). This model has a theoretical resolution of 40 pm (0.15 cm-1) within a 5 nm (22.5 cm-1) wide spectral window. It is aimed at the feasibility demonstration for atmospheric CO2 column measurements with a very demanding accuracy of better than 1%. Preliminary measurements indicate that, although high quality spectra are obtained, the theoretical performances are not yet achieved. We discuss the causes for the achieved performances and describe foreseen methods for their improvements.
NASA Technical Reports Server (NTRS)
Moore, Marla; Ferrante, Robert; Moore, William; Hudson, Reggie
2010-01-01
Spectra and optical constants of nitrite ices known or suspected to be in Titan's atmosphere are presented from 2.5 to 200 microns (4000 to 50 per cm ). These results are relevant to the ongoing modeling of Cassini CIRS observations of Titan's winter pole. Ices studied include: HCN, hydrogen cyanide; C2N2, cyanogen; CH3CN, acetonitrile; C 2H5CN, propionitrile; and HC3N, cyanoacetylene. For each of these molecules we report new measurements of the index of refraction, n, determined in both the amorphous- and crystallinephase at 670 nm. Spectra were measured and optical constants were calculated for each nitrite at a variety of temperatures including 20, 35, 50, 75, 95, and 110 K, in the amorphous- and crystalline-phase. This laboratory effort uses a dedicated FTIR spectrometer to record transmission spectra of thin-film ice samples. Laser interference is used to measure film thickness during condensation onto a transparent cold window attached to the tail section of a closed-cycle helium cryostat. Optical constants, real (n) and imaginary (k) refractive indices, are determined using Kramers-Kronig (K-K) analysis. Our calculation reproduces the complete spectrum, including all interference effects. Index of refraction measurements are made in a separate dedicated FTIR spectrometer where interference deposit fringes are measured using two 670 nm lasers at different angles to the ice substrate. A survey of these new measurements will be presented along with a discussion of their validation, errors, and application to Titan data.
NASA Technical Reports Server (NTRS)
Dejesusparada, N. (Principal Investigator); Morimoto, T.
1980-01-01
The author has identified the following significant results. Multispectral scanner data for Brasilia was corrected for atmospheric interference using the LOWTRAN-3 computer program and the analytical solution of the radiative transfer equation. This improved the contrast between two natural targets and the corrected images of two different dates were more similar than the original ones. Corrected images of MSS data for Ribeirao Preto gave a classification accuracy for sugar cane about 10% higher as compared to the original images.
Influence of the atmospheric opacity cycle on the near surface environment of Gale Crater on Mars
NASA Astrophysics Data System (ADS)
de la Torre Juarez, Manuel; Gomez-Elvira, Javier; Guzewich, Scott David; Lemmon, Mark T.; Martinez, German; Mason, Emily; Navarro, Sara; Newman, Claire E.; Smith, Michael D.; Retortillo, Alvaro de Vicente
2016-10-01
The Mars atmospheric dust changes the capacity of the atmosphere to absorb solar radiation or release outgoing thermal infrared radiation. This alters the atmospheric heat exchange fluxes and can interfere with the global circulation. The response of near surface pressure, temperature and winds has been characterized at the higher northern latitudes of 45 degree N at the Viking landing sites. The Rover Environmental Monitoring Station (REMS) on Curiosity allows a similar characterization at near-equatorial latitudes of 4.5 degree S. Using MCAM-880 nm opacities as a measure of local atmospheric dust load, we analyze the response of changes in surface variables measured by REMS and compare to those observed by Viking. As on Viking, diurnal and semidiurnal pressure tide amplitudes track very closely the atmospheric opacity and the mean daily pressure shows the increased wave activity. Temperature tides show a more complex response that combines its sensitivity to changes in dust and cloud opacities. Differences in UV opacities for the REMS set of finite spectral windows are explored during the dust and clear seasons.
Atmospheric 21Ne abundance determined by the Helix-MC Plus mass spectrometer
NASA Astrophysics Data System (ADS)
Honda, M.; Zhang, X.; Phillips, D.; Hamilton, D.; Deerberg, M.; Schwieters, J. B.
2014-12-01
Analyses of noble gas isotopes by multi-collector, high resolution mass spectrometry have the potential to revolutionise applications in the cosmo-geo-sciences. The Helix-MC Plus noble gas mass spectrometer installed at the Australian National University (ANU) is equipped with unique high mass resolution collectors [mass resolution (MR): ~1,800 and mass resolving power (MRP): ~8,000], including fixed axial (Ax), adjustable high mass (H2) and adjustable low mass (L2) detectors. The high mass resolution of the L2, Ax and H2 collectors permits complete separation of 20Ne (measured on L2 detector) from doubly charged interfering 40Ar (required MR of 1,777), 1H19F (MR = 1450), 1H218O (MR = 894) and partial separation of the 21Ne peak (on Ax detector) from interfering 20Ne1H (MR = 3,271), and 22Ne (on H2 detector) from interfering doubly charged CO2 (MR = 6,231). Because of the high MRP of ~8,000, 21Ne can be measured, essentially without interference from 20Ne1H, by setting the magnet position on a 20Ne1H interference-free position. This capability provides an important opportunity to re-evaluate the 21Ne abundance in the atmosphere. Our analyses demonstrate that 20Ne1H contributes ~4% to atmospheric 21Ne measurements, with the corresponding production ratio of 20Ne1H to 20Ne being ~1E-4. We calculate a new atmospheric 21Ne/20Ne ratio of 0.00287 relative to an atmospheric 22Ne/20Ne ratio of 0.102; this new value is distinctly lower than the current IUPAC recommended 21Ne/20Ne value of 0.00298. There are several significant implications ensuing from the newly determined atmospheric 21Ne abundance. For example, in the area of Earth sciences the most critical issue relates to cosmogenic 21Ne surface exposure ages, which involve the calculation of 21Ne concentrations from excess 21Ne, relative to the atmospheric 21Ne/20Ne ratio. For young samples, where cosmogenic 21Ne contents are small and the 21Ne/20Ne ratio is close to the atmospheric value, the revised value could increase cosmogenic 21Ne ages by ~30%.
1986-12-01
established by the Federal Aviation Administration (FAA), take into account limitations of the navigational service available, and in some airspace the Air... Services (C&GS) of the National Ocean Service , National Oceanic and Atmospheric Administration (NOS/NOAA), are based on regional horizontal datums which...Electromagnetic Interference EMS Emergency Medical Service ERDA Energy Research & Development Administration (Now Department of Energy) F 3 Form, Fit, and
Hiraka, Kentaro; Kojima, Katsuhiro; Lin, Chi-En; Tsugawa, Wakako; Asano, Ryutaro; La Belle, Jeffrey T; Sode, Koji
2018-04-30
l-lactate biosensors employing l-lactate oxidase (LOx) have been developed mainly to measure l-lactate concentration for clinical diagnostics, sports medicine, and the food industry. Some l-lactate biosensors employ artificial electron mediators, but these can negatively impact the detection of l-lactate by competing with the primary electron acceptor: molecular oxygen. In this paper, a strategic approach to engineering an AvLOx that minimizes the effects of oxygen interference on sensor strips was reported. First, we predicted an oxygen access pathway in Aerococcus viridans LOx (AvLOx) based on its crystal structure. This was subsequently blocked by a bulky amino acid substitution. The resulting Ala96Leu mutant showed a drastic reduction in oxidase activity using molecular oxygen as the electron acceptor and a small increase in dehydrogenase activity employing an artificial electron acceptor. Secondly, the Ala96Leu mutant was immobilized on a screen-printed carbon electrode using glutaraldehyde cross-linking method. Amperometric analysis was performed with potassium ferricyanide as an electron mediator under argon or atmospheric conditions. Under argon condition, the response current increased linearly from 0.05 to 0.5mM l-lactate for both wild-type and Ala96Leu. However, under atmospheric conditions, the response of wild-type AvLOx electrode was suppressed by 9-12% due to oxygen interference. The Ala96Leu mutant maintained 56-69% of the response current at the same l-lactate level and minimized the relative bias error to -19% from -49% of wild-type. This study provided significant insight into the enzymatic reaction mechanism of AvLOx and presented a novel approach to minimize oxygen interference in sensor applications, which will enable accurate detection of l-lactate concentrations. Copyright © 2017 Elsevier B.V. All rights reserved.
Ammonia 15N/14N Isotope Ratio in the Jovian Atmosphere
NASA Technical Reports Server (NTRS)
Mahaffy, P.R.; Niemann, H. B.; Atreya, S. K.; Wong, M. H.; Owen, T. C; Einaudi, Franco (Technical Monitor)
2000-01-01
Data from the Galileo Probe Mass Spectrometer has been used to derive the N-15/N-14 isotope ratio in ammonia at Jupiter. Although the mass spectral interference from the water contribution to 18 amu makes an accurate derivation of the (N-15)H3/(N-14)H3 ratio difficult from measurements of the singly ionized signals at 18 and 17 amu, this interference is not present in the doubly charged 8.5 and 9.0 amu signals from (N-14)H3++ and (N-15)H3++ respectively. Although the count rate from the 9 amu signal is low during the direct sampling of the atmosphere, the ammonia signal was considerably enhanced during the first enrichment cell (EC1) experiment that measured gas sampled between 0.8 and 2.8 bar. Count rates at 9 amu in the EC1 experiment reach 60/second and measure ammonia sampled from 0.88 to 2.8 bar. In the EC1 measurements the 8.5 amu signal is not measured directly, but can be calculated from the ammonia contribution to 17 amu and the ratio of NH3 ions of a double to single charged observed during a high resolution mass scan taken near the end of the descent. The high resolution scan gives this ratio from ammonia sampled much deeper in the atmosphere. These results are described and compared with Infrared Space Observatory-Short Wavelength Spectrometer (ISO-SWS) observations that give this ratio at 400 mbar.
NASA Astrophysics Data System (ADS)
Wyers, G. P.; Otjes, R. P.; Slanina, J.
A new diffusion denuder is described for the continuous measurement of atmospheric ammonia. Ammonia is collected in an absorption solution in a rotating denuder, separated from interfering compounds by diffusion through a semi-permeable membrane and detected by conductometry. The method is free from interferences by other atmospheric gases, with the exception of volatile amines. The detection limit is 6 ng m -3 for a 30-min integration time. This compact instrument is fully automated and suited for routine deployment in field studies. The precision is sufficiently high for micrometeorological studies of air-surface exchange of ammonia.
NASA Technical Reports Server (NTRS)
Cornish, C. R.
1983-01-01
Following reception and analog to digital conversion (A/D) conversion, atmospheric radar backscatter echoes need to be processed so as to obtain desired information about atmospheric processes and to eliminate or minimize contaminating contributions from other sources. Various signal processing techniques have been implemented at mesosphere-stratosphere-troposphere (MST) radar facilities to estimate parameters of interest from received spectra. Such estimation techniques need to be both accurate and sufficiently efficient to be within the capabilities of the particular data-processing system. The various techniques used to parameterize the spectra of received signals are reviewed herein. Noise estimation, electromagnetic interference, data smoothing, correlation, and the Doppler effect are among the specific points addressed.
Observations of interference between portable particle counters and NOx monitors
NASA Astrophysics Data System (ADS)
Bereznicki, Sarah D.; Kamal, Ali
2013-08-01
Studies in environmental exposure science have developed a preference for smaller devices that can be easily co-located without need for gas standards, such as those instruments utilized in the Near-road Exposures and Effects from Urban Air Pollutants Study (NEXUS). One observation from NEXUS was the potential for instrument interference from alcohol-based particle counters on photometric-based nitrogen oxide (NOx) monitors. This article reports the findings from laboratory tests replicating enclosed-shelter monitoring configurations and operation cycles for a common photometric-based NOx monitor and a widely used alcohol-based particle counter. These tests monitored the NOx response while the particle counter sampling interval and ambient airflow rate were varied to (1) confirm that proximity between the instruments induced interferences, (2) identify any dependencies in NOx monitor recovery on ambient airflow, and (3) determine the time needed for the NOx monitor to recover to pre-interference levels under different atmospheric conditions. During particle counter operations, NOx concentrations responded instantaneously with a several-fold jump above the measurement baseline. When the particle counter was operated for more than 10 min, this interference period also showed a marked decline in the NOx baseline. The overall recovery time of the NOx monitor depended less on the time of particle counter operation, and more on the speed of ambient airflow. If photometric-based NOx monitors need to be operated alongside alcohol-based particle counters, mechanisms must be employed to exhaust alcohol-based vapors from enclosed monitoring environments. Given the strong evidence for interference, however, it is recommended these devices not be operated within close proximity to one another.
Gregory A. Endress; Anton G. Endress; Louis R. Iverson; Louis R. Iverson
1999-01-01
Differential responses of species to environmental stress may interfere with restoration of prairie ecosystems or change community structure. The impact of increasing atmospheric ozone (O3) concentrations and/or low water on the growth of Andropogon gerardii Vitm. (big bluestem) and Sorghastrum nutans (L.) Nash (Indian grass), two common warm-season native grasses,...
Searching for Motion within the Solar Atmosphere (Abstract)
NASA Astrophysics Data System (ADS)
Oatney, S. N.
2015-12-01
(Abstract only) The mystery of heat transfer within the solar atmosphere has long been a subject of study and debate. Not unlike large solar observatories that are funded by public monies, amateur solar observers also have a keen interest in this subject and are able to creatively employ tools at hand such as a two slit interferometer used to create interference lines in an attempt to measure motion. (Interference patterns: https://en.wikipedia.org/wiki/Double-slit_experiment) With a 6-inch equatorially pier mounted refractor focused just above the visible disk of the sun, images taken with a Meade Lunar Planetary Imager video LPI CMOS camera at ~30 Hz sample rates and stored as FITS files. A variety of photometry, unrated color, and full aperture solar filters are combined with and without a two slit interferometer placed at the focus of the telescope. These images, explored through the NASA FITS viewer (https://heasarc.gsfc.nasa.gov/docs/software/ftools/fv/) were applied to show logarithmic color contours. Selected fv images were placed consecutively in a movie format that shows some cyclical motion around and between the contours, mostly of the solar corona.
NASA Astrophysics Data System (ADS)
Brown, Justin; Woolf, David; Hensley, Joel
2016-05-01
Quantum key distribution can provide secure optical data links using the established BB84 protocol, though solar backgrounds severely limit the performance through free space. Several approaches to reduce the solar background include time-gating the photon signal, limiting the field of view through geometrical design of the optical system, and spectral rejection using interference filters. Despite optimization of these parameters, the solar background continues to dominate under daytime atmospheric conditions. We demonstrate an improved spectral filter by replacing the interference filter (Δν ~ 50 GHz) with an atomic line filter (Δν ~ 1 GHz) based on optical rotation of linearly polarized light through a warm Rb vapor. By controlling the magnetic field and the optical depth of the vapor, a spectrally narrow region can be transmitted between crossed polarizers. We find that the transmission is more complex than a single peak and evaluate peak transmission as well as a ratio of peak transmission to average transmission of the local spectrum. We compare filters containing a natural abundance of Rb with those containing isotopically pure 87 Rb and 85 Rb. A filter providing > 95 % transmission and Δν ~ 1.1 GHz is achieved.
The future of spectroscopic life detection on exoplanets
Seager, Sara
2014-01-01
The discovery and characterization of exoplanets have the potential to offer the world one of the most impactful findings ever in the history of astronomy—the identification of life beyond Earth. Life can be inferred by the presence of atmospheric biosignature gases—gases produced by life that can accumulate to detectable levels in an exoplanet atmosphere. Detection will be made by remote sensing by sophisticated space telescopes. The conviction that biosignature gases will actually be detected in the future is moderated by lessons learned from the dozens of exoplanet atmospheres studied in last decade, namely the difficulty in robustly identifying molecules, the possible interference of clouds, and the permanent limitations from a spectrum of spatially unresolved and globally mixed gases without direct surface observations. The vision for the path to assess the presence of life beyond Earth is being established. PMID:25092345
Measurements of KrF laser-induced O2 fluorescence in high-temperature atmospheric air
NASA Technical Reports Server (NTRS)
Grinstead, Jay H.; Laufer, Gabriel; Mcdaniel, James C., Jr.
1993-01-01
Conditions for obtaining laser-induced O2 fluorescence using a tunable KrF laser has been determined theoretically and experimentally. With this laser source, O2 rotational temperature measurement is possible even in the absence of vibrational equilibrium. Temperature measurement using a two-line excitation scheme has been demonstrated in a high-temperature atmospheric-air furnace. A measurement uncertainty of 10.7 percent for the temperature range 1325-1725 K was realized. At atmospheric pressure, O2 LIF measurements are possible for air temperatures above 1250 K. Interference from OH fluorescence in reacting flows can be avoided by the proper selection of O2 transitions. Depletion of the ground state population by the incident laser is negligible for intensities below 7.5 x 10 to the 6th W/sq cm/per cm.
The future of spectroscopic life detection on exoplanets.
Seager, Sara
2014-09-02
The discovery and characterization of exoplanets have the potential to offer the world one of the most impactful findings ever in the history of astronomy--the identification of life beyond Earth. Life can be inferred by the presence of atmospheric biosignature gases--gases produced by life that can accumulate to detectable levels in an exoplanet atmosphere. Detection will be made by remote sensing by sophisticated space telescopes. The conviction that biosignature gases will actually be detected in the future is moderated by lessons learned from the dozens of exoplanet atmospheres studied in last decade, namely the difficulty in robustly identifying molecules, the possible interference of clouds, and the permanent limitations from a spectrum of spatially unresolved and globally mixed gases without direct surface observations. The vision for the path to assess the presence of life beyond Earth is being established.
Du, Zhenhui; Wan, Jiaxin; Li, Jinyi; Luo, Gang; Gao, Hong; Ma, Yiwen
2017-01-01
Detection of methyl mercaptan (CH3SH) is essential for environmental atmosphere assessment and exhaled-breath analysis. This paper presents a sensitive CH3SH sensor based on wavelength modulation spectroscopy (WMS) with a mid-infrared distributed feedback interband cascade laser (DFB-ICL). Multicomponent spectral fitting was used not only to enhance the sensitivity of the sensor but also to determine the concentration of interferents (atmospheric water and methane). The results showed that the uncertainties in the measurement of CH3SH, H2O, and CH4 were less than 1.2%, 1.7% and 2.0%, respectively, with an integration time of 10 s. The CH3SH detection limit was as low as 7.1 ppb with an integration time of 295 s. Overall, the reported sensor, boasting the merits of high sensitivity, can be used for atmospheric methyl mercaptan detection, as well as multiple components detection of methyl mercaptan, water, and methane, simultaneously. PMID:28212311
CO2 capture from humid flue gases and humid atmosphere using a microporous coppersilicate.
Datta, Shuvo Jit; Khumnoon, Chutharat; Lee, Zhen Hao; Moon, Won Kyung; Docao, Son; Nguyen, Thanh Huu; Hwang, In Chul; Moon, Dohyun; Oleynikov, Peter; Terasaki, Osamu; Yoon, Kyung Byung
2015-10-16
Capturing CO2 from humid flue gases and atmosphere with porous materials remains costly because prior dehydration of the gases is required. A large number of microporous materials with physical adsorption capacity have been developed as CO2-capturing materials. However, most of them suffer from CO2 sorption capacity reduction or structure decomposition that is caused by co-adsorbed H2O when exposed to humid flue gases and atmosphere. We report a highly stable microporous coppersilicate. It has H2O-specific and CO2-specific adsorption sites but does not have H2O/CO2-sharing sites. Therefore, it readily adsorbs both H2O and CO2 from the humid flue gases and atmosphere, but the adsorbing H2O does not interfere with the adsorption of CO2. It is also highly stable after adsorption of H2O and CO2 because it was synthesized hydrothermally. Copyright © 2015, American Association for the Advancement of Science.
Orbit-spin coupling and the circulation of the Martian atmosphere
NASA Astrophysics Data System (ADS)
Shirley, James H.
2017-07-01
The physical origins of the observed interannual variability of weather and climate on Mars are poorly understood. In this paper we introduce a deterministic physical mechanism that may account for much of the variability of the circulation of the Mars atmosphere on seasonal and longer timescales. We focus on a possible coupling between the planetary orbital angular momentum and the angular momentum of the planetary rotation. We suspect that the planetary atmosphere may participate in an exchange of momentum between these two reservoirs. Nontrivial changes in the circulation of the atmosphere are likely to occur, as the atmospheric system gains and loses angular momentum, during this exchange. We derive a coupling expression linking orbital and rotational motions that produces an acceleration field varying with position and with time on and within a subject body. The spatially and temporally varying accelerations may interfere constructively or destructively with large-scale flows of geophysical fluids that are established and maintained by other means. This physical hypothesis predicts cycles of intensification and relaxation of circulatory flows of atmospheres on seasonal and longer timescales that are largely independent of solar forcing. The predictions of this hypothesis may be tested through numerical modeling. Examples from investigations of the atmospheric circulation of Mars are provided to illustrate qualitative features and quantitative aspects of the coupling mechanism proposed.
Barricklow, Jason; Ryder, Tim F; Furlong, Michael T
2009-08-01
During LC-MS/MS quantification of a small molecule in human urine samples from a clinical study, an unexpected peak was observed to nearly co-elute with the analyte of interest in many study samples. Improved chromatographic resolution revealed the presence of at least 3 non-analyte peaks, which were identified as cysteine metabolites and N-acetyl (mercapturic acid) derivatives thereof. These metabolites produced artifact responses in the parent compound MRM channel due to decomposition in the ionization source of the mass spectrometer. Quantitative comparison of the analyte concentrations in study samples using the original chromatographic method and the improved chromatographic separation method demonstrated that the original method substantially over-estimated the analyte concentration in many cases. The substitution of electrospray ionization (ESI) for atmospheric pressure chemical ionization (APCI) nearly eliminated the source instability of these metabolites, which would have mitigated their interference in the quantification of the analyte, even without chromatographic separation. These results 1) demonstrate the potential for thiol metabolite interferences during the quantification of small molecules in pharmacokinetic samples, and 2) underscore the need to carefully evaluate LC-MS/MS methods for molecules that can undergo metabolism to thiol adducts to ensure that they are not susceptible to such interferences during quantification.
Observations of land-atmosphere interactions using satellite data
NASA Astrophysics Data System (ADS)
Green, Julia; Gentine, Pierre; Konings, Alexandra; Alemohammad, Hamed; Kolassa, Jana
2016-04-01
Observations of land-atmosphere interactions using satellite data Julia Green (1), Pierre Gentine (1), Alexandra Konings (1,2), Seyed Hamed Alemohammad (3), Jana Kolassa (4) (1) Columbia University, Earth and Environmental Engineering, NY, NY, USA, (2) Stanford University, Environmental Earth System Science, Stanford, CA, USA, (3) Massachusetts Institute of Technology, Civil and Environmental Engineering, Cambridge, MA, USA, (4) National Aeronautics and Space Administration/Goddard Space Flight Center, Greenbelt, MD, USA. Previous studies of global land-atmosphere hotspots have often relied solely on data from global models with the consequence that they are sensitive to model error. On the other hand, by only analyzing observations, it can be difficult to distinguish causality from mere correlation. In this study, we present a general framework for investigating land-atmosphere interactions using Granger Causality analysis applied to remote sensing data. Based on the near linear relationship between chlorophyll sun induced fluorescence (SIF) and photosynthesis (and thus its relationship with transpiration), we use the GOME-2 fluorescence direct measurements to quantify the surface fluxes between the land and atmosphere. By using SIF data to represent the flux, we bypass the need to use soil moisture data from FLUXNET (limited spatially and temporally) or remote sensing (limited by spatial resolution, canopy interference, measurement depth, and radio frequency interference) thus eliminating additional uncertainty. The Granger Causality analysis allows for the determination of the strength of the two-way causal relationship between SIF and several climatic variables: precipitation, radiation and temperature. We determine that warm regions transitioning from water to energy limitation exhibit strong feedbacks between the land surface and atmosphere due to their high sensitivity to climate and weather variability. Tropical rainforest regions show low magnitudes of causal feedback likely due to other factors influencing the land surface such as phenological controls (e.g. leaf area index), nutrient limitations or soil texture. These results were then compared to CMIP5 GCM results using GPP in place of SIF. GCM results varied greatly between models as well as with the observational data analysis indicating deficiencies in the representation of certain modeled phenomena such as low level clouds and boundary layer development. This study highlights the need for GCM improvement to more accurately capture the feedbacks between the land and atmosphere. These results have the potential to improve our understanding of the underlying mechanisms between land and atmosphere coupling, which could ultimately be used to improve weather and climate predictions.
Spectra, Index of Refraction, and Optical Constants of Nitrile Ices Relevant to Titan's Atmosphere
NASA Astrophysics Data System (ADS)
Moore, Marla; Hudson, Reggie; Ferrante, Robert; Moore, William
Spectra and optical constants of nitrile ices known or suspected to be in Titan's atmosphere are presented from 2.5 to 200 microns (4000 to 50 cm-1 ). These results are relevant to the ongoing modeling of Cassini CIRS observations of Titan's winter pole. Ices studied include: HCN, hydrogen cyanide; C2 N2 , cyanogen; CH3 CN, acetonitrile; C2 H5 CN, propionitrile; and HC3 N, cyanoacetylene. For each of these molecules we report new measurements of the index of refraction, n, determined in both the amorphous-and crystalline-phase at 670 nm. Spectra were measured and optical constants were calculated for each nitrile at a variety of temperatures including 20, 35, 50, 75, 95, and 110 K, in the amorphous-and crystalline-phase. This laboratory effort uses a dedicated FTIR spectrometer to record transmission spectra of thin-film ice samples. Laser interference is used to measure film thickness during condensation onto a transparent cold window attached to the tail section of a closed-cycle helium cryo-stat. Optical constants, real (n) and imaginary (k) refractive indices, are determined using Kramers-Kronig (K-K) analysis. Our calculation reproduces the complete spectrum, including all interference effects. Index of refraction measurements are made in a separate dedicated FTIR spectrometer where interference deposit fringes are measured using two 670 nm lasers at different angles to the ice substrate. A survey of these new measurements will be presented along with a discussion of their validation, errors, and application to Titan data. We acknowledge Mark Loeffler who recently joined in our refractive index measurements. The authors also acknowledge support from the Cassini Data Analysis Program. RLH and MHM acknowledge additional funding from NASA's PGG and Outer Planets Programs, and the Goddard Center for Astrobiology.
Using Cell-Phone Tower Signals for Detecting the Precursors of Fog
NASA Astrophysics Data System (ADS)
David, N.; Gao, H. O.
2018-01-01
In the last decade, published research has indicated the potential of commercial microwave links that comprise the data transmission infrastructure of cellular communication networks as an environmental monitoring technology. Different weather phenomena cause interference in the wireless communication links that can therefore essentially act as a low-cost sensor network, already deployed worldwide, for atmospheric monitoring. In this study we focus on the attenuation effect caused in commercial microwave networks due to gradients in the atmospheric refractive index with altitude as a result of the combination of temperature inversions and falls in the atmospheric humidity trapped beneath them. These conditions, when combined with high relative humidity near ground level, are precursors to the creation of fog. The current work utilizes this novel approach to demonstrate the potential for detecting these preconditions of fog, a phenomenon associated with severe visibility limitations that can lead to dangerous accidents, injuries, and loss of lives.
NASA Technical Reports Server (NTRS)
Fahey, D. W.; Eubank, C. S.; Hubler, C. S.; Fehsenfeld, F. C.
1985-01-01
The suitability of a technique for the measurement of total reactive odd-nitrogen NOy-containing species in the atmosphere has been examined. In the technique, an NOy component species, which may include NO, NO2, NO3, HNO3, peroxyacetyl nitrate, and particulate nitrate, are catalytically reduced by CO to form NO molecules on the surface of a metal converter tube, and the NO product is detected by chemiluminescence produced in reaction with O3. Among the catalysts tested in the temperature range of 25-500 C, Au was the preferred catalyst. The results of laboratory tests investigating the effects of pressure, O3, and H2O on NOy conversion, and the possible sources of interference, have shown that the technique is suitable for atmospheric analyses. The results of a test in ambient air at a remote ground-based field site are included.
Atmospheric methane measurement instrument using a Zeeman-split He-Ne laser
NASA Technical Reports Server (NTRS)
Mcmanus, J. Barry; Kebabian, Paul L.; Kolb, Charles E.
1989-01-01
The construction of an atmospheric methane measurement instrument based on a Zeeman-split IR He-Ne laser is reported. The laser has a tranverse magnetic field over about 2/3 of its gain length and can oscillate at an (unsplit) frequency (2947.91/cm) centered on a methane absorption line, or on either of two frequencies split by + or - 0.055/cm from the center, with low CH4 absorption. The laser is tuned to dwell sequentially at each frequency, giving two differential absorption measurements in each 46-ms tuning cycle. Atmospheric measurements are made using two multiple pass absorption cells, one with fast (0.75-s) and one with slow (5-s) flow response times. Fluctuations in ambient CH4 of about 20-ppb (rms, 1-s averaging) are detected, with interference fringe effects the dominant noise source. The instrument has operated in a field experiment (NASA GTE/ABLE-3A) in Alaska.
NASA Technical Reports Server (NTRS)
Murcray, D. G.; Williams, J. W.; Barker, D. B.; Goldman, A.; Bradford, C.; Cook, G.
1978-01-01
Infrared solar spectra and infrared atmospheric emission spectra were obtained from the ground, from aircraft and from balloons. The initial detection of most stratospheric molecules was achieved by the solar spectral technique because better resolution helps remove interference from other molecules. Because the sun is an intense source of radiation, the resolution which can be obtained with good signal-to-noise, is greater than with atmospheric emission spectroscopy. Data are generally taken using a method that enhances the number of molecules in the optical path i.e. at large solar zenith angles for solar spectra and at low elevation angles for atmospheric emission spectra. The search for molecules which are predicted to be present but which, the detection of a molecule known to be present from other measurement techniques but observed for the first time in infrared solar spectra, and some further data on the variability of HNO3 are discussed.
NASA Technical Reports Server (NTRS)
Callis, L. B.; Alpert, J. C.; Geller, M. A.
1985-01-01
Hines (1974) speculated that solar-induced modifications of the middle and upper atmosphere may alter the transmissivity of the stratosphere to upwardly propagating atmospheric waves. It was suggested that subsequent constructive or destructive interference may result in a change of phase or amplitude of these waves in the troposphere leading to weather or climate changes. The present investigation has the objective to bring together both radiative transfer and planetary wave studies in an effort to assess specifically whether Hines mechanism can be initiated by the solar ultraviolet flux variability assumed to be associated with the 11-year solar cycle. The obtained results suggest that the presently studied mechanism, which links solar-induced zonal wind changes in the stratosphere and mesosphere to planetary wave changes in the troposphere, is not strong enough to cause substantive changes in the troposphere.
NASA Technical Reports Server (NTRS)
Renner, Christoffer J.
2005-01-01
Free-space optical communication systems (also known as lasercom systems) offer several performance advantages over traditional radio frequency communication systems. These advantages include increased data rates and reduced operating power and system weight. One serious limiting factor in a lasercom system is Optical turbulence in Earth's atmosphere. This turbulence breaks up the laser beam used to transmit the information into multiple segments that interfere with each other when the beam is focused onto the receiver. This interference pattern at the receiver changes with time causing fluctuations in the received optical intensity (scintillation). Scintillation leads to intermittent losses of the signal and an overall reduction in the lasercom system's performance. Since scintillation is a coherent effect, reducing the spatial and temporal coherence of the laser beam will reduce the scintillation. Transmitting a laser beam through certain materials is thought to reduce its coherence. Materials that were tested included: sapphire, BK7 glass, fused silica and others. The spatial and temporal coherence of the laser beam was determined by examining the interference patterns (fringes) it formed when interacting with various interferometers and etalons.
Hydrazine monitoring in spacecraft
NASA Technical Reports Server (NTRS)
Cross, J. H.; Beck, S. W.; Limero, T. F.; James, J. T.
1992-01-01
Hydrazine (HZ) and monomethyl hydrazine (MMH) are highly toxic compounds used as fuels in the Space Shuttle Orbiter Main Engines and in its maneuvering and reaction control system. Satellite refueling during a mission may also result in release of hydrazines. During extravehicular activities, the potential exists for hydrazines to contaminate the suit and to be brought into the internal atmosphere inadvertantly. Because of the high toxicity of hydrazines, a very sensitive, reliable, interference-free, and real-time method of measurement is required. A portable ion mobility spectrometer (IMS) has exhibited a low ppb detection limit for hydrazines suggesting a promising technology for the detection of hydrazines in spacecraft air. The Hydrazine Monitor is a modified airborne vapor monitor (AVM) with a custom-built datalogger. This off-the-shelf IMS was developed for the detection of chemical warfare agents on the battlefield. After early evaluations of the AVM for hydrazine measurements showed a serious interference from ammonia, the AVM was modified to measure HZ and MMH in the ppb concentration range without interference from ammonia in the low ppm range. A description of the Hydrazine Monitor and how it functions is presented.
Detection and measurement of total ozone from stellar spectra: Paper 2. Historic data from 1935 1942
NASA Astrophysics Data System (ADS)
Griffin, R. E. M.
2005-10-01
Atmospheric ozone columns are derived from historic stellar spectra observed between 1935 and 1942 at Mount Wilson Observatory, California. Comparisons with contemporary measurements in the Arosa database show a generally close correspondence. The results of the analysis indicate that astronomy's archives command considerable potential for investigating the natural levels of ozone and its variability during the decades prior to anthropogenic interference.
Buch, Andressa Cristhy; Correia, Maria Elizabeth Fernandes; Teixeira, Daniel Cabral; Silva-Filho, Emmanoel Vieira
2015-06-01
The increasing levels of mercury (Hg) found in the atmosphere arising from anthropogenic sources, have been the object of great concern in the past two decades in industrialized countries. Brazil is the seventh country with the highest rate of mercury in the atmosphere. The major input of Hg to ecosystems is through atmospheric deposition (wet and dry), being transported in the atmosphere over large distances. The forest biomes are of strong importance in the atmosphere/soil cycling of elemental Hg through foliar uptake and subsequent transference to the soil through litter, playing an important role as sink of this element. Soil microarthropods are keys to understanding the soil ecosystem, and for such purpose were characterized by the soil fauna of two Units of Forest Conservation of the state of the Rio de Janeiro, inwhich one of the areas suffer quite interference from petrochemicals and industrial anthropogenic activities and other area almost exempts of these perturbations. The results showed that soil and litter of the Atlantic Forest in Brazil tend to stock high mercury concentrations, which could affect the abundance and richness of soil fauna, endangering its biodiversity and thereby the functioning of ecosystems. Copyright © 2015. Published by Elsevier B.V.
HO2 measurements at atmospheric concentrations using a chemical ionization mass spectrometry
NASA Astrophysics Data System (ADS)
Albrecht, S.; Novelli, A.; Hofzumahaus, A.; Kang, S.; Baker, Y.; Mentel, T. F.; Fuchs, H.
2017-12-01
Correct and precise measurements of atmospheric radical species are necessary for a better understanding of the oxidative capacity of the atmosphere. Due to the reactivity of radicals, and their consequent low concentrations, direct measurements of these species are particularly challenging and have been proven in the past to be affected by interfering species. Here we present a chemical ionization source coupled to an APi-HR-TOF-MS (Aerodyne Research Inc.), which has a limit of detection for HO2 radicals well below its atmospheric concentrations ( 1 x 108 molecules cm-3). The instrument was calibrated with a well-established and characterized HO2 calibration source in use for the laser induced fluorescence instrument in the Forschungszentrum Jülich. Within the source, a well characterized amount of HO2 radicals is produced after photolysis of water by a mercury lamp. In addition, several experiments were performed in the atmosphere simulation chamber SAPHIR at the Forschungszentrum Jülich to test for potential interferences. Measurements of HO2 radicals were concurrently detected by a laser induced fluorescence instrument allowing for the comparison of measurements within the two different and independent techniques for various atmospheric conditions regarding concentrations of O3, NOx and VOCs. Results from the intercomparison together with the calibration procedure of the instrument and laboratory characterization will be presented.
NASA Technical Reports Server (NTRS)
Kato, K.
1985-01-01
An atmospheric pressure ionization mass spectrometric (API-MS) method was studied for the determination of residual NO in high purity N2 gas. The API-MS is very sensitive to NO, but the presence of O2 interferes with the NO measurement. Nitrogen gas in cylinders as sample gas was mixed with NO standard gas and/or O2 standard gas, and then introduced into the API-MS. The calibration curves of NO and O2 has linearity in the region of 0 - 2 ppm, but the slopes changed with every cylinder. The effect of O2 on NO+ peak was additive and proportional to O2 concentration in the range of 0 - 0.5 ppm. The increase in NO+ intensity due to O2 was (0.07 - 0.13)%/O2, 1 ppm. Determination of NO and O2 was carried out by the standard addition method to eliminate the influence of variation of slopes. The interference due to O2 was estimated from the product of the O2 concentration and the ratio of slope A to Slope B. Slope A is the change in the NO+ intensity with the O2 concentration. Slope B is the intensity with O2 concentration.
Dual-wavelength dual-cavity spectrometer for NO2 detection in the presence of aerosol interference
NASA Astrophysics Data System (ADS)
Chandran, Satheesh; Puthukkudy, Anin; Varma, Ravi
2017-07-01
Precise determination of concentration of gases, such as NO2, in urban atmosphere is crucial in studying chemical reactions leading to secondary pollutants. In this study, a novel and sensitive yet simple and cost effective spectrometer was developed where two laser wavelengths and two parallel identical optical cavities were used. Monitoring of NO2 even in the presence of aerosol spectral interference was demonstrated. The intensity transmitted through one cavity, evacuated to 0.1 mbar, was designated as the reference signal ( I 0) while that through the other cavity, sampling air at atmospheric pressure, was designated as sample signal ( I). Quasi-simultaneous measurements of these I 0 and I were done for both laser wavelengths sequentially: one at 406.4 nm near the peak of the largest electronic transition of NO2 and the other at 446.9 nm, away from the peak yet exhibiting significant absorption. The addition of the second wavelength where NO2 has absorption was to ascertain the presence of aerosol scattering and compensate for it. Aerosol extinctions at both operating wavelengths were assumed to be the same, their ratio taken as unity for simplicity, and aerosol light extinction was retrieved. The spectrometer with average sampling interval of 5 s exhibited detection sensitivity of low parts per billion concentrations.
NASA Astrophysics Data System (ADS)
Xu, Zheng; Wang, Tao; Xue, L. K.; Louie, Peter K. K.; Luk, Connie W. Y.; Gao, J.; Wang, S. L.; Chai, F. H.; Wang, W. X.
2013-09-01
A widely used method for measuring nitrogen dioxide (NO2) in the atmosphere is the conversion of NO2 to nitric oxide (NO) on the hot surface of a molybdenum oxide (MoO) catalyst followed by the chemiluminescence detection of NO. Although it has long been recognized that this type of conversion may suffer from the positive interference of other oxidized nitrogen compounds, evaluations of such interference in the atmosphere are scarce, thus rendering it difficult to make use of a large portion of the NO2 or NOx data obtained via this method (often denoted as NO2* or NOx*). In the present study, we compared the MoO converter with a selective, more accurate photolytic approach at four differently polluted sites in China. The converter worked well at the urban site, which was greatly affected by fresh emissions, but, on average, overestimated NO2 by 30%-50% at the two suburban sites and by more than 130% at the mountain-top site during afternoon hours, with a much larger positive bias seen during the top 10% of ozone events. The degree of overestimation depended on both air-parcel age and the composition of the oxidation products/intermediates of NOx (NOz). We attempted to derive an empirical formula to correct for this overestimation using concurrently measured O3, NO, and NO2* at the two suburban sites. Although the formula worked well at each individual site, the different NOz partitions at the sites made it difficult to obtain a universal formula. In view of the difficulty of assessing the uncertainties of the conventional conversion method, thus limiting the usability of data obtained via this method in atmospheric research, we suggest that, in areas away from fresh NOx emission sources, either a more selective NO2 measurement method or a NOy (NOx and its reaction products and intermediates) instrument should be adopted.
NASA Technical Reports Server (NTRS)
Toon, O. B.; Pollack, J. B.; Khare, B. N.
1976-01-01
An investigation is conducted of problems which are related to a use of measured optical constants in the simulation of the optical constants of real atmospheric aerosols. The techniques of measuring optical constants are discussed, taking into account transmission measurements through homogeneous and inhomogeneous materials, the immersion of a material in a liquid of a known refractive index, the consideration of the minimum deviation angle of prism measurement, the interference of multiply reflected light, reflectivity measurements, and aspects of mathematical analysis. Graphs show the real and the imaginary part of the refractive index as a function of wavelength for aluminum oxide, NaCl, and ammonium sulfate. Tables are provided for the dispersion parameters and the optical constants.
Solar atmospheric dynamics. II - Nonlinear models of the photospheric and chromospheric oscillations
NASA Technical Reports Server (NTRS)
Leibacher, J.; Gouttebroze, P.; Stein, R. F.
1982-01-01
The one-dimensional, nonlinear dynamics of the solar atmosphere is investigated, and models of the observed photospheric (300 s) and chromospheric (200 s) oscillations are described. These are resonances of acoustic wave cavities formed by the variation of the temperature and ionization between the subphotospheric, hydrogen convection zone and the chromosphere-corona transition region. The dependence of the oscillations upon the excitation and boundary conditions leads to the conclusion that for the observed amplitudes, the modes are independently excited and, as trapped modes, transport little if any mechanical flux. In the upper photosphere and lower chromosphere, where the two modes have comparable energy density, interference between them leads to apparent vertical phase delays which might be interpreted as evidence of an energy flux.
NASA Astrophysics Data System (ADS)
Tallant, D. R.; Jungst, R. G.
1981-04-01
A dual base diode laser spectrometer was constructed using off axis reflective optics. The spectrometer was amplitude modulated for direct absorption measurements or frequency modulated to obtain derivative spectra. The spectrometer had: high throughput; was easy to operate and align; provided good dual beam compensation; and had no evidence of the interference effects that were observed in diode laser spectrometers using refractive optics. Unpurged, using second derivative techniques, the instrument measured 108 parts per million CO (10/cm absorption cell, atmospheric pressure broadened) with good signal/noise. With the replacement of marginal instrumental components, the signal/noise was substantially increased. This instrument was developed to monitor the evolution of decomposition gases in sealed containers of small volume at atmospheric pressure.
Synchronous atmospheric radiation correction of GF-2 satellite multispectral image
NASA Astrophysics Data System (ADS)
Bian, Fuqiang; Fan, Dongdong; Zhang, Yan; Wang, Dandan
2018-02-01
GF-2 remote sensing products have been widely used in many fields for its high-quality information, which provides technical support for the the macroeconomic decisions. Atmospheric correction is the necessary part in the data preprocessing of the quantitative high resolution remote sensing, which can eliminate the signal interference in the radiation path caused by atmospheric scattering and absorption, and reducting apparent reflectance into real reflectance of the surface targets. Aiming at the problem that current research lack of atmospheric date which are synchronization and region matching of the surface observation image, this research utilize the MODIS Level 1B synchronous data to simulate synchronized atmospheric condition, and write programs to implementation process of aerosol retrieval and atmospheric correction, then generate a lookup table of the remote sensing image based on the radioactive transfer model of 6S (second simulation of a satellite signal in the solar spectrum) to correct the atmospheric effect of multispectral image from GF-2 satellite PMS-1 payload. According to the correction results, this paper analyzes the pixel histogram of the reflectance spectrum of the 4 spectral bands of PMS-1, and evaluates the correction results of different spectral bands. Then conducted a comparison experiment on the same GF-2 image based on the QUAC. According to the different targets respectively statistics the average value of NDVI, implement a comparative study of NDVI from two different results. The degree of influence was discussed by whether to adopt synchronous atmospheric date. The study shows that the result of the synchronous atmospheric parameters have significantly improved the quantitative application of the GF-2 remote sensing data.
NASA Technical Reports Server (NTRS)
Tabacco, Mary Beth; Zhou, Quan
1993-01-01
Porous optical fibers include sensing regions filled with reagents. Optical-fiber chemical sensors (optrodes) developed to measure concentrations of ethylene in air in enclosed artificial plant-growth environments. Such measurements needed because ethylene acts as plant-growth hormone affecting growth at concentrations less than or equal to 20 parts per billion. Optrodes small, but exhibit sensitivities comparable to those of larger instruments. Operated safely in potentially explosive atmospheres and neither cause, nor susceptible to, electrical interference at suboptical frequencies.
Propagation Effects in Space/Earth Paths.
1980-08-01
effects of clouds, fogs and gaseous absorption. The background loss in the various atmospheric windows occurring above 70 GHz appears to be higher...strongly positive, all the cases plotted give loss in horizon exceeding 50 km except for the thinnest region (0.1 km) and the smallers N (270). s 5...scatter signals causing respectively: a loss in signal level, a decrease in the efficiency of dual-polarize6 channels and station-to-station interference
Gas Sensor Evaluations in Polymer Combustion Product Atmospheres
NASA Technical Reports Server (NTRS)
Delgado, Rafael H.; Davis, Dennis D.; Beeson, Harold D.
1999-01-01
Toxic gases produced by the combustion or thermo-oxidative degradation of materials such as wire insulation, foam, plastics, or electronic circuit boards in space shuttle or space station crew cabins may pose a significant hazard to the flight crew. Toxic gas sensors are routinely evaluated in pure gas standard mixtures, but the possible interferences from polymer combustion products are not routinely evaluated. The NASA White Sands Test Facility (WSTF) has developed a test system that provides atmospheres containing predetermined quantities of target gases combined with the coincidental combustion products of common spacecraft materials. The target gases are quantitated in real time by infrared (IR) spectroscopy and verified by grab samples. The sensor responses are recorded in real time and are compared to the IR and validation analyses. Target gases such as carbon monoxide, hydrogen cyanide, hydrogen chloride, and hydrogen fluoride can be generated by the combustion of poly(vinyl chloride), polyimide-fluoropolymer wire insulation, polyurethane foam, or electronic circuit board materials. The kinetics and product identifications for the combustion of the various materials were determined by thermogravimetric-IR spectroscopic studies. These data were then scaled to provide the required levels of target gases in the sensor evaluation system. Multisensor toxic gas monitors from two manufacturers were evaluated using this system. In general, the sensor responses satisfactorily tracked the real-time concentrations of toxic gases in a dynamic mixture. Interferences from a number of organic combustion products including acetaldehyde and bisphenol-A were minimal. Hydrogen bromide in the products of circuit board combustion registered as hydrogen chloride. The use of actual polymer combustion atmospheres for the evaluation of sensors can provide additional confidence in the reliability of the sensor response.
Carrieri, Arthur H; Copper, Jack; Owens, David J; Roese, Erik S; Bottiger, Jerold R; Everly, Robert D; Hung, Kevin C
2010-01-20
An active spectrophotopolarimeter sensor and support system were developed for a military/civilian defense feasibility study concerning the identification and standoff detection of biological aerosols. Plumes of warfare agent surrogates gamma-irradiated Bacillus subtilis and chicken egg white albumen (analytes), Arizona road dust (terrestrial interferent), water mist (atmospheric interferent), and talcum powders (experiment controls) were dispersed inside windowless chambers and interrogated by multiple CO(2) laser beams spanning 9.1-12.0 microm wavelengths (lambda). Molecular vibration and vibration-rotation activities by the subject analyte are fundamentally strong within this "fingerprint" middle infrared spectral region. Distinct polarization-modulations of incident irradiance and backscatter radiance of tuned beams generate the Mueller matrix (M) of subject aerosol. Strings of all 15 normalized elements {M(ij)(lambda)/M(11)(lambda)}, which completely describe physical and geometric attributes of the aerosol particles, are input fields for training hybrid Kohonen self-organizing map feed-forward artificial neural networks (ANNs). The properly trained and validated ANN model performs pattern recognition and type-classification tasks via internal mappings. A typical ANN that mathematically clusters analyte, interferent, and control aerosols with nil overlap of species is illustrated, including sensitivity analysis of performance.
Qu, Wei-ping; Liu, Wen-qing; Liu, Jian-guo; Lu, Yi-huai; Zhu, Jun; Qin, Min; Liu, Cheng
2006-11-01
In satellite remote-sensing detection, cloud as an interference plays a negative role in data retrieval. How to discern the cloud fields with high fidelity thus comes as a need to the following research. A new method rooting in atmospheric radiation characteristics of cloud layer, in the present paper, presents a sort of solution where single-band brightness variance ratio is used to detect the relative intensity of cloud clutter so as to delineate cloud field rapidly and exactly, and the formulae of brightness variance ratio of satellite image, image reflectance variance ratio, and brightness temperature variance ratio of thermal infrared image are also given to enable cloud elimination to produce data free from cloud interference. According to the variance of the penetrating capability for different spectra bands, an objective evaluation is done on cloud penetration of them with the factors that influence penetration effect. Finally, a multi-band data fusion task is completed using the image data of infrared penetration from cirrus nothus. Image data reconstruction is of good quality and exactitude to show the real data of visible band covered by cloud fields. Statistics indicates the consistency of waveband relativity with image data after the data fusion.
Endocrine disrupting chemicals in the atmosphere: Their effects on humans and wildlife.
Annamalai, Jayshree; Namasivayam, Vasudevan
2015-03-01
Endocrine disrupting chemicals (EDCs) are exogenous agents that interfere or disrupt the normal synthesis, secretion, transportation, binding and metabolism of natural hormones; eventually dysregulating homeostatic mechanisms, reproduction and development. They are emitted into the atmosphere during anthropogenic activities and physicochemical reactions in nature. Inhalation of these EDCs as particulate and gaseous vapors triggers their interaction with endocrine glands and exerts agonist or antagonists actions at hormone receptors. The endocrine disruption at nanogram levels of EDC's has gained concern in the last decade, due to infertility among men and women, early puberty, obesity, diabetes and cancer. Thus, the review explores the literature that addresses the major occurring EDCs in the atmosphere including phthalates, polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), brominated flame retardants (BFRs), dioxins, alkylphenols (APs) and perfluorinated chemicals (PFCs). Sources, fate, half-life, mechanism, measured concentrations in air, bioaccumulation in tissues, laboratory exposures correlating to toxicological effects of these EDCs in humans and wildlife are discussed. Copyright © 2014 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Vairavamurthy, A.; Roberts, J.M.; Newman, L.
1991-06-01
Carbonyl compounds are both primary (directly emitted) and secondary (formed in situ) atmospheric species, which play a major role in tropospheric photochemistry. Because of trace concentrations (parts-per-billion and lower), ambient air measurements of carbonyls pose serious analytical problems. Generally, chromatographic approaches combined with chemical derivatization have been used to enhance sensitivity and selectivity in analysis. Currently, the liquid chromatographic method coupled to 2,4-dinitrophenylhydrazine derivatization (DNPH-LC) is in widespread use. Interferences arising from similar compounds are greatly minimized by chromatographic separation; however, those in the air sampling step, especially with ozone, continue to be problematic and remain to be resolved. Wemore » discuss here the different sampling techniques used for time-integrated collection of carbonyls in the DNPH-LC methods. Emphasis is placed on addressing: (1) the principles, advantages, and limitations of sampling techniques; (2) problems associated with reagent blank and sampling instrument; and (3) effects of atmospheric co-pollutants, especially ozone. 58 refs., 8 figs., 3 tabs.« less
Strong intensity variations of laser feedback interferometer caused by atmospheric turbulence
NASA Astrophysics Data System (ADS)
Sun, Yiyi; Li, Zhiping
2003-05-01
The significant variation of the laser output can be caused by feedback of a small part of laser beam, which is reflected or backscattered by a target at a long distance from laser source, into the laser cavity. This paper describes and analyzes theoretically and experimentally the influence of atmospheric turbulence on interference caused by laser feedback. The influence depends upon both the energy of feedback into the laser cavity and the strength of turbulence over a laser propagation path in the atmosphere. In the case of stronger energy of feedback and weak turbulence variance of fluctuation of the laser output can be enhanced by hundreds to thousands times. From our measurements and theoretical analysis it shows thatthese significant enhancements can result from the change of laser-cavity-modes which can be stimulated simultaneously and from beat oscillations between a variety of frequencies of laser modes. This also can result from optical chaos inside the laser resonator because a non-separable distorted external cavity can become a prerequisite for optical chaos.
NASA Astrophysics Data System (ADS)
Slanger, T. G.; Pejaković, D. A.; Kostko, O.; Matsiev, D.; Kalogerakis, K. S.
2017-03-01
The terrestrial dayglow displays prominent emission features from the 0-0 and 1-1 bands of the O2 Atmospheric band system in the 760-780 nm region. We present an analysis of observations in this wavelength region recorded by the Space Shuttle during the Arizona Airglow Experiment. A major conclusion is that the dominant product of O(1D) + O2 energy transfer is O2(b, v = 1), a result that corroborates our previous laboratory studies. Moreover, critical to the interpretation of dayglow is the possible interference by N2 and N2+ bands in the 760-780 nm region, where the single-most important component is the N2 1PG 3-1 band that overlaps with the O2(b-X) 0-0 band. When present, this background must be accounted for to reveal the O2(b-X) 0-0 and 1-1 bands for altitudes at which the O2 and N2/N2+ emissions coincide. Finally, we exploit the very different collisional behavior of the two lowest O2(b) vibrational levels to outline a remote sensing technique that provides information on Atmospheric composition and temperature from space-based observations of the 0-0 and 1-1 O2 atmospheric bands.
NASA Technical Reports Server (NTRS)
Stolarski, Richard S.
1988-01-01
Processes that may be responsible for the thinning in the ozone layer above the South Pole are described. The chlorine catalytic cycle which destroys ozone is described, as are the major types of reactions that are believed to interfere with this cycle by forming chlorine reservoirs. The suspected contributions of polar stratospheric clouds to these processes are examined. Finally, the possibility that the ozone hole may be due more to a shift in atmospheric dynamics than to chemical destruction is addressed.
NASA Technical Reports Server (NTRS)
Zwick, H.; Ward, V.; Beaudette, L.
1973-01-01
A critical evaluation of existing optical remote sensors for HCl vapor detection in solid propellant rocket plumes is presented. The P branch of the fundamental vibration-rotation band was selected as the most promising spectral feature to sense. A computation of transmittance for HCl vapor, an estimation of interferent spectra, the application of these spectra to computer modelled remote sensors, and a trade-off study for instrument recommendation are also included.
Survey of Potential Radio Frequency Interference Sources.
1980-05-13
RESOLUTION - 121 km *ICE FIELD MAPS. RESOLUTION - 21 km * MEASUREMENT OF INTEGRATED ATMOSPHERIC WATER VAPOR AND LIQUID MATTER IN A COLUMN ALONG THE...frequency allocation matters . 3. Enclosure (2) reports a telecon with Mr. William Shaffer of NASA. The status report contains the results of decisions...have been identified; they exist in the bands 1.215-1.30, 3.1-3.3, 5.25-5.35, and 9.5-9.8 MHz. The matter of satisfying these requirements remains under
1988-12-01
December 1988 Copyright C AGARD 1988 All Rights Reserved ISBN 92-835-0487-9 b Printed by Specialised Printing Services Limited 40 Chigwell Lane...atmospheric radio noise, Report No. 322-3, International Telecommunication Union, Geneva, 1986. (6) Giordano, A. A., J. R. Herman, X. A. DeAngelis, K. F...tne CCIR Xth Plenary Assembly. Geneva, 1963, Report 322, International Telecommunications Union, Geneva, 1964. 5. Maxwell, E.L., D.L. Stone, R.D
2015-01-01
a spatial resolution of 250-m. The Gumley et al. computation for MODIS sharpening is given as a ratio of high to low resolution top of the atmosphere...NIR) correction (Stumpf, Arnone, Gould, Martinolich, & Ransibrahamanakul, 2003). Standard flagswere used tomask interference from land, clouds , sun...technique This new approach expands on the methodology described by Gumley et al. (2010), with somemodifications. We will compute a sim- ilar spatial
Improvements in Raman Lidar Measurements Using New Interference Filter Technology
NASA Technical Reports Server (NTRS)
Whiteman, David N.; Potter, John R.; Tola, Rebecca; Veselovskii, Igor; Cadirola, Martin; Rush, Kurt; Comer, Joseph
2006-01-01
Narrow-band interference filters with improved transmission in the ultra-violet have been developed under NASA-funded research and used in the Raman Airborne Spectroscopic Lidar (RASL) in ground-based, upward-looking tests. Measurements were made of atmospheric water vapor, cirrus cloud optical properties and carbon dioxide that improve upon any previously demonstrated using Raman lidar. Daytime boundary and mixed layer profiling of water vapor mixing ratio up to an altitude of approximately 4 h is performed with less than 5% random error using temporal and spatial resolution of 2-minutes and 60 - 210, respectively. Daytime cirrus cloud optical depth and extinction-to-backscatter ratio measurements are made using 1 -minute average. Sufficient signal strength is demonstrated to permit the simultaneous profiling of carbon dioxide and water vapor mixing ratio into the free troposphere during the nighttime. A description of the filter technology developments is provided followed by examples of the improved Raman lidar measurements.
Re-evaluation of colorimetric Cl- data from natural waters with DOC
Norton, S.A.; Handlet, M.J.; Kahl, J.S.; Peters, N.E.
1996-01-01
Colorimetric Cl- data from natural solutions that contain dissolved organic carbon (DOC) may be biased high. We evaluated aquatic Cl- concentrations in ecosystem compartments at the Bear Brook Watershed, Maine, and from lakes in Maine, using ion chromatography and colorimetry. DOC imparts a positive interference on colorimetric Cl- results proportional to DOC concentrations at approximately 0.8 ??eq Cl-/L per mg DOC/L. The interference is not a function of Cl- concentration. The resulting bias in concentrations of Cl- may be 50% or more of typical environmental values for Cl- in areas remote from atmospheric deposition of marine aerosols. Such biased data in the literature appear to have led to spurious conclusions about recycling of Cl- by forests, the usefulness of Cl- as a conservative tracer in watershed studies, and calculations of elemental budgets, ion balance, charge density of DOC, and dry deposition factors.
Depth Distribution Of The Maxima Of Extensive Air Shower
NASA Technical Reports Server (NTRS)
Adams, J. H.; Howell, L. W.
2003-01-01
Observations of the extensive air showers from space can be free from interference by low altitude clouds and aerosols if the showers develop at a sufficiently high altitude. In this paper we explore the altitude distribution of shower maxima to determine the fraction of all showers that will reach their maxima at sufficient altitudes to avoid interference from these lower atmosphere phenomena. Typically the aerosols are confined within a planetary boundary layer that extends from only 2-3 km above the Earth's surface. Cloud top altitudes extend above 15 km but most are below 4 km. The results reported here show that more than 75% of the showers that will be observed by EUSO have maxima above the planetary boundary layer. The results also show that more than 50% of the showers that occur on cloudy days have their maxima above the cloud tops.
NASA Technical Reports Server (NTRS)
Norton, P. W.; Zimmermann, P. H.; Briggs, R. J.; Hartle, N. M.
1986-01-01
Large-area, HgCdTe MW photovoltaic detectors have been developed for the NASA-HALOE instrument scheduled for operation on the Upper Atmospheric Research Satellite. The photodiodes will be TE-cooled and were designed to operate in the 5.1-5.4 micron band at 185 K to measure nitric oxide concentrations in the atmosphere. The active area required 15 micron thick devices and a full backside common contact. Reflections from the backside contact doubled the effective thickness of the detectors. Optical interference from reflections was eliminated with a dual layer front surface A/R coating. Bakeout reliability was optimized by having Au metallization for both n and p interconnects. Detailed performance data and a model for the optical stack are presented.
Quantum cascade laser based sensor for open path measurement of atmospheric trace gases
NASA Astrophysics Data System (ADS)
Deng, Hao; Sun, Juan; Liu, Ningwu; Ding, Junya; Chao, Zhou; Zhang, Lei; Li, Jingsong
2017-02-01
A sensitive open-path gas sensor employing a continuous-wave (CW) distributed feedback (DFB) quantum cascade laser (QCL) and direct absorption spectroscopy (DAS) was demonstrated for simultaneously measurements of atmospheric CO and N2O. Two interference free absorption lines located at 2190.0175 cm-1 and 2190.3498 cm-1 were selected for CO and N2O concentration measurements, respectively. The Allan variance analysis technique was performed to investigate the long-term performance of the QCL sensor system. The results indicate that a detection limit of 9.92 ppb for CO and 7.7 ppb for N2O with 1-s integration time were achieved, which can be further improved to 1.5 ppb and 1.1 ppb by increasing the average time up to 80 s.
Estimating cirrus cloud properties from MIPAS data
NASA Astrophysics Data System (ADS)
Mendrok, J.; Schreier, F.; Höpfner, M.
2007-04-01
High resolution mid-infrared limb emission spectra observed by the spaceborne Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) showing evidence of cloud interference are analyzed. Using the new line-by-line multiple scattering [Approximate] Spherical Atmospheric Radiative Transfer code (SARTre), a sensitivity study with respect to cirrus cloud parameters, e.g., optical thickness and particle size distribution, is performed. Cirrus properties are estimated by fitting spectra in three distinct microwindows between 8 and 12 μm. For a cirrus with extremely low ice water path (IWP = 0.1 g/m2) and small effective particle size (D e = 10 μm) simulated spectra are in close agreement with observations in broadband signal and fine structures. We show that a multi-microwindow technique enhances reliability of MIPAS cirrus retrievals compared to single microwindow methods.
NASA Astrophysics Data System (ADS)
Achim, Pascal; Generoso, Sylvia; Morin, Mireille; Gross, Philippe; Le Petit, Gilbert; Moulin, Christophe
2016-05-01
Monitoring atmospheric concentrations of radioxenons is relevant to provide evidence of atmospheric or underground nuclear weapon tests. However, when the design of the International Monitoring Network (IMS) of the Comprehensive Nuclear-Test-Ban Treaty (CTBT) was set up, the impact of industrial releases was not perceived. It is now well known that industrial radioxenon signature can interfere with that of nuclear tests. Therefore, there is a crucial need to characterize atmospheric distributions of radioxenons from industrial sources—the so-called atmospheric background—in the frame of the CTBT. Two years of Xe-133 atmospheric background have been simulated using 2013 and 2014 meteorological data together with the most comprehensive emission inventory of radiopharmaceutical facilities and nuclear power plants to date. Annual average simulated activity concentrations vary from 0.01 mBq/m3 up to above 5 mBq/m3 nearby major sources. Average measured and simulated concentrations agree on most of the IMS stations, which indicates that the main sources during the time frame are properly captured. Xe-133 atmospheric background simulated at IMS stations turn out to be a complex combination of sources. Stations most impacted are in Europe and North America and can potentially detect Xe-133 every day. Predicted occurrences of detections of atmospheric Xe-133 show seasonal variations, more accentuated in the Northern Hemisphere, where the maximum occurs in winter. To our knowledge, this study presents the first global maps of Xe-133 atmospheric background from industrial sources based on two years of simulation and is a first attempt to analyze its composition in terms of origin at IMS stations.
The Use of Remote Sensing Data for Advancing America's Energy Policy
NASA Technical Reports Server (NTRS)
Valinia, Azita; Seery, Bernard D.
2010-01-01
After briefly reviewing America's Energy Policy laid out by the Obama Administration, we outline how a Global Carbon Observing System designed to monitor Carbon from space can provide the necessary data and tools to equip decision makers with the knowledge necessary to formulate effective energy use and practices policy. To stabilize greenhouse gas emissions in the atmosphere in a manner that it does not interfere with the Earth's climate system (which is one of the goals of United Nations Framework for Convention on Climate Change) requires vastly improved prediction of the atmospheric carbon dioxide (CO2) concentrations. This in torn requires a robust understanding of the carbon exchange mechanisms between atmosphere, land, and oceans and a clear understanding of the sources and sinks (i.e. uptake and storage) of CO2. We discuss how the Carbon Observing System from space aids in better understanding of the connection between the carbon cycle and climate change and provides more accurate predictions of atmospheric CO2 concentration. It also enables implementation of greenhouse gas (GHG) mitigation policies such as cap and trade programs, international climate treaties, as well as formulation of effective energy use policies.
Earth system sensitivity inferred from Pliocene modelling and data
Lunt, D.J.; Haywood, A.M.; Schmidt, G.A.; Salzmann, U.; Valdes, P.J.; Dowsett, H.J.
2010-01-01
Quantifying the equilibrium response of global temperatures to an increase in atmospheric carbon dioxide concentrations is one of the cornerstones of climate research. Components of the Earths climate system that vary over long timescales, such as ice sheets and vegetation, could have an important effect on this temperature sensitivity, but have often been neglected. Here we use a coupled atmosphere-ocean general circulation model to simulate the climate of the mid-Pliocene warm period (about three million years ago), and analyse the forcings and feedbacks that contributed to the relatively warm temperatures. Furthermore, we compare our simulation with proxy records of mid-Pliocene sea surface temperature. Taking these lines of evidence together, we estimate that the response of the Earth system to elevated atmospheric carbon dioxide concentrations is 30-50% greater than the response based on those fast-adjusting components of the climate system that are used traditionally to estimate climate sensitivity. We conclude that targets for the long-term stabilization of atmospheric greenhouse-gas concentrations aimed at preventing a dangerous human interference with the climate system should take into account this higher sensitivity of the Earth system. ?? 2010 Macmillan Publishers Limited. All rights reserved.
CO{sub 2} Emission Calculations and Trends
DOE R&D Accomplishments Database
Boden, T. A.; Marland, G.; Andres, R. J.
1995-06-01
Evidence that the atmospheric CO{sub 2}concentration has risen during the past several decades is irrefutable. Most of the observed increase in atmospheric CO{sub 2} is believed to result from CO{sub 2} releases from fossil-fuel burning. The United Nations (UN) Framework Convention on Climate Change (FCCC), signed in Rio de Janeiro in June 1992, reflects global concern over the increasing CO{sub 2} concentration and its potential impact on climate. One of the convention`s stated objectives was the stabilization of greenhouse gas concentrations in the atmosphere at a level that would prevent dangerous anthropogenic interference with the climate system. Specifically, the FCCC asked all 154 signing countries to conduct an inventory of their current greenhouse gas emissions, and it set nonbinding targets for some countries to control emissions by stabilizing them at 1990 levels by the year 2000. Given the importance of CO{sub 2} as a greenhouse gas, the relationship between CO{sub 2} emissions and increases in atmospheric CO{sub 2} levels, and the potential impacts of a greenhouse gas-induced climate change; it is important that comprehensive CO{sub 2} emissions records be compiled, maintained, updated, and documented.
NASA Astrophysics Data System (ADS)
Womack, Caroline C.; Neuman, J. Andrew; Veres, Patrick R.; Eilerman, Scott J.; Brock, Charles A.; Decker, Zachary C. J.; Zarzana, Kyle J.; Dube, William P.; Wild, Robert J.; Wooldridge, Paul J.; Cohen, Ronald C.; Brown, Steven S.
2017-05-01
The sum of all reactive nitrogen species (NOy) includes NOx (NO2 + NO) and all of its oxidized forms, and the accurate detection of NOy is critical to understanding atmospheric nitrogen chemistry. Thermal dissociation (TD) inlets, which convert NOy to NO2 followed by NO2 detection, are frequently used in conjunction with techniques such as laser-induced fluorescence (LIF) and cavity ring-down spectroscopy (CRDS) to measure total NOy when set at > 600 °C or speciated NOy when set at intermediate temperatures. We report the conversion efficiency of known amounts of several representative NOy species to NO2 in our TD-CRDS instrument, under a variety of experimental conditions. We find that the conversion efficiency of HNO3 is highly sensitive to the flow rate and the residence time through the TD inlet as well as the presence of other species that may be present during ambient sampling, such as ozone (O3). Conversion of HNO3 at 400 °C, nominally the set point used to selectively convert organic nitrates, can range from 2 to 6 % and may represent an interference in measurement of organic nitrates under some conditions. The conversion efficiency is strongly dependent on the operating characteristics of individual quartz ovens and should be well calibrated prior to use in field sampling. We demonstrate quantitative conversion of both gas-phase N2O5 and particulate ammonium nitrate in the TD inlet at 650 °C, which is the temperature normally used for conversion of HNO3. N2O5 has two thermal dissociation steps, one at low temperature representing dissociation to NO2 and NO3 and one at high temperature representing dissociation of NO3, which produces exclusively NO2 and not NO. We also find a significant interference from partial conversion (5-10 %) of NH3 to NO at 650 °C in the presence of representative (50 ppbv) levels of O3 in dry zero air. Although this interference appears to be suppressed when sampling ambient air, we nevertheless recommend regular characterization of this interference using standard additions of NH3 to TD instruments that convert reactive nitrogen to NO or NO2.
NASA Astrophysics Data System (ADS)
Heard, Dwayne; Woodward-Massey, Robert; Slater, Eloise; Ye, Chunxiang; Seakins, Paul; Whalley, Lisa
2017-04-01
The hydroxyl radical is the most important atmospheric oxidant controlling the lifetimes of the majority of trace gases, including the greenhouse gas methane, and initiates the formation of harmful pollutants such as ozone and secondary organic aerosol. It has a very short lifetime of typically a second or less and hence its concentration is controlled by local in situ chemistry rather than transport, and hence is an ideal target for models containing detailed oxidation mechanisms. However, its accurate measurement in the atmosphere is extremely challenging, and despite having been measured in the troposphere for 30 years there remain uncertainties surrounding potential interferences in its measurement, which have been reported recently in some environments for some instruments. A new inlet pre-injector (IPI) has been developed for the Leeds FAGE (fluorescence assay by gas expansion) instrument which allows removal of ambient OH by addition of a chemical scavenger prior to the fluorescence detection cell. In this manner the background is determined and is subtracted from the OH signal determined during field measurements leading to a measurement of OH referred to as OH-CHEM. In the more traditional method the background is determined by tuning the wavelength of the laser away from the OH transition leading to a measurement of OH referred to as OH-WAVE. A detailed laboratory characterization will be presented of the IPI using OH removal using either propane or perfluoropropene (C3F6) as scavengers, with the presence of the IPI reducing the instrument OH sensitivity by 30%. There was no removal of OH within the fluorescence cell itself, and the IPI did not reduce the sensitivity of the instrument towards HO2. Results will be presented during deployment of the Leeds FAGE instrument equipped with the new IPI at a coastal location in Norfolk, England in the summer of 2015, and also in central Beijing, China in the winter of 2016. For both sites, which span a very wide range of NOx and VOC concentrations, OH-CHEM and OH-WAVE in general agreed well, within measurement uncertainties, demonstrating that at least for these locations there was no significant observed OH interference. Some results of further laboratory tests to investigate the potential presence of OH interferences formed during the ozonolysis of alkenes will also be presented.
Liquid chromatographic determination of water
Fortier, N.E.; Fritz, J.S.
1990-11-13
A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present. 1 fig.
Liquid chromatographic determination of water
Fortier, Nancy E.; Fritz, James S.
1990-11-13
A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present.
Wamsley, Paula R.; Weimer, Carl S.; Nelson, Loren D.; O'Brien, Martin J.
2003-01-01
An oil and gas exploration system and method for land and airborne operations, the system and method used for locating subsurface hydrocarbon deposits based upon a remote detection of trace amounts of gases in the atmosphere. The detection of one or more target gases in the atmosphere is used to indicate a possible subsurface oil and gas deposit. By mapping a plurality of gas targets over a selected survey area, the survey area can be analyzed for measurable concentration anomalies. The anomalies are interpreted along with other exploration data to evaluate the value of an underground deposit. The system includes a differential absorption lidar (DIAL) system with a spectroscopic grade laser light and a light detector. The laser light is continuously tunable in a mid-infrared range, 2 to 5 micrometers, for choosing appropriate wavelengths to measure different gases and avoid absorption bands of interference gases. The laser light has sufficient optical energy to measure atmospheric concentrations of a gas over a path as long as a mile and greater. The detection of the gas is based on optical absorption measurements at specific wavelengths in the open atmosphere. Light that is detected using the light detector contains an absorption signature acquired as the light travels through the atmosphere from the laser source and back to the light detector. The absorption signature of each gas is processed and then analyzed to determine if a potential anomaly exists.
Implementation of a rapid correction algorithm for adaptive optics using a plenoptic sensor
NASA Astrophysics Data System (ADS)
Ko, Jonathan; Wu, Chensheng; Davis, Christopher C.
2016-09-01
Adaptive optics relies on the accuracy and speed of a wavefront sensor in order to provide quick corrections to distortions in the optical system. In weaker cases of atmospheric turbulence often encountered in astronomical fields, a traditional Shack-Hartmann sensor has proved to be very effective. However, in cases of stronger atmospheric turbulence often encountered near the surface of the Earth, atmospheric turbulence no longer solely causes small tilts in the wavefront. Instead, lasers passing through strong or "deep" atmospheric turbulence encounter beam breakup, which results in interference effects and discontinuities in the incoming wavefront. In these situations, a Shack-Hartmann sensor can no longer effectively determine the shape of the incoming wavefront. We propose a wavefront reconstruction and correction algorithm based around the plenoptic sensor. The plenoptic sensor's design allows it to match and exceed the wavefront sensing capabilities of a Shack-Hartmann sensor for our application. Novel wavefront reconstruction algorithms can take advantage of the plenoptic sensor to provide a rapid wavefront reconstruction necessary for real time turbulence. To test the integrity of the plenoptic sensor and its reconstruction algorithms, we use artificially generated turbulence in a lab scale environment to simulate the structure and speed of outdoor atmospheric turbulence. By analyzing the performance of our system with and without the closed-loop plenoptic sensor adaptive optics system, we can show that the plenoptic sensor is effective in mitigating real time lab generated atmospheric turbulence.
NASA Astrophysics Data System (ADS)
Ye, Kunhui
2018-06-01
The interannual variability of March snow water equivalent (SWE) in Northern Eurasia and its influencing factors are studied. The surface air temperature (SAT) and precipitation are the dominant factors for the snow accumulation in northern Europe and the remaining region, respectively. The strongest contribution of SAT to snow accumulation is mainly found in those months with moderate mean SAT. The strongest contribution of precipitation is not collocated with the climatological maxima in precipitation. The leading mode of March SWE variability is obtained and characterized by a spatial dipole. Anomalies in atmospheric water vapor divergence, storm activity and the associated atmospheric circulation can explain many of the associated precipitation and SAT features. Anomalies in autumn Arctic sea ice concentration (SIC) over the Barents Sea and Kara Sea (B/K Sea) and a dipole pattern of November snow cover (SC) in Eurasia are also observed. The atmospheric circulation anomalies that resemble a negative phase of North Atlantic Oscillation (NAO)/Arctic Oscillation (AO) are strongly projected onto the wintertime atmospheric circulation. Both observations and model experiment support that the autumn B/K Sea SIC has some impacts on the autumn and AO/NAO-like wintertime atmospheric circulation patterns. The dipole pattern of November Eurasian SC seems to be strongly forced by the autumn B/K Sea SIC and its feedback to the atmospheric circulation is important. Therefore, the impacts of autumn B/K Sea SIC on the autumn/wintertime atmospheric circulation and thus the March SWE variability may be modulated by both constructive and destructive interference of autumn Eurasian SC.
222Rn+220Rn monitoring by alpha spectrometry.
Buompane, R; Roca, V; Sabbarese, C; Pugliese, M; Quarto, M; Mattone, C
2014-07-01
Controlled 222Rn+220Rn mixed atmospheres have been realised introducing calibrated sources in a stainless steel chamber. An electrostatic alpha monitor internal to the chamber has been used for an accurate discrimination of alpha peaks due to the products of the two isotopes. In the chamber, different specific activities are achieved in order to test the response of the internal reference instrument and to evaluate the possible interferences due to contemporary presence of both radon isotopes. Results show that: (i) the atmospheres are very stable, (ii) the monitor is adequate for their control because the various alpha lines are well evaluated and (iii) using Tyvek® filter, the efficiency of monitor is stable and constant vs. activity. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.
NASA Technical Reports Server (NTRS)
Carre, D. J.
1980-01-01
The replacement of water (H2O) by deuterium oxide (D2O) and the exchange between atmospheric water and adsorbed or absorbed D2O were investigated for the polymeric materials Kapton and Mylar using thermal gravimetric analysis and infrared spectroscopy. Replacement of H2O by D2O is easily accomplished. However, exposure of D2O samples to the ambient atmosphere or gases containing H2O results in rapid proton and deuteron exchange between H2O vapor and adsorbed D2O. Replacement of H2O by D2O would not be a practical solution to alleviate spectral interferences that would result from water outgassing in spacecraft orbital environments. Maintaining the materials of interest in a dehydrated state is a more reasonable approach.
Differential phase-shift keying and channel equalization in free space optical communication system
NASA Astrophysics Data System (ADS)
Zhang, Dai; Hao, Shiqi; Zhao, Qingsong; Wan, Xiongfeng; Xu, Chenlu
2018-01-01
We present the performance benefits of differential phase-shift keying (DPSK) modulation in eliminating influence from atmospheric turbulence, especially for coherent free space optical (FSO) communication with a high communication rate. Analytic expression of detected signal is derived, based on which, homodyne detection efficiency is calculated to indicate the performance of wavefront compensation. Considered laser pulses always suffer from atmospheric scattering effect by clouds, intersymbol interference (ISI) in high-speed FSO communication link is analyzed. Correspondingly, the channel equalization method of a binormalized modified constant modulus algorithm based on set-membership filtering (SM-BNMCMA) is proposed to solve the ISI problem. Finally, through the comparison with existing channel equalization methods, its performance benefits of both ISI elimination and convergence speed are verified. The research findings have theoretical significance in a high-speed FSO communication system.
Aharonovich, Marius; Arnon, Shlomi
2005-08-01
Optical wireless communication (OWC) systems use the atmosphere as a propagation medium. However, a common problem is that from time to time moderate cloud and fog emerge between the receiver and the transmitter. These adverse weather conditions impose temporal broadening and power loss on the optical signal, which reduces the digital signal-to-noise ratio (DSNR), produces significant intersymbol interference (ISI), and degrades the communication system's bit error rate (BER) and throughput. We propose and investigate the use of a combined adaptive bandwidth mechanism and decision feedback equalizer (DFE) to mitigate these atmospheric multipath effects. Based on theoretical analysis and simulations of DSNR penalties, BER, and optimum system bandwidths, we show that a DFE improves the outdoor OWC system immunity to ISI in foggy weather while maintaining high throughput and desired low BER.
OH, HO2, and HO2* Radical Chemistry During PROPHET-AMOS 2016: Measurements and Model Comparison
NASA Astrophysics Data System (ADS)
Bottorff, B.; Lew, M.; Rickly, P.; Stevens, P. S.
2017-12-01
The hydroxyl (OH) and peroxy radicals, both the hydroperoxy radical (HO2) and organic peroxy radicals (RO2), play an important role in atmospheric chemistry. In addition to controlling lifetimes of many trace gases important to issues of global climate change, reactions of these radicals can also lead to the production of ozone and secondary organic aerosols in the atmosphere. Previous measurements of these radicals in remote forest environments have shown serious discrepancies with modeled concentrations. These results bring into question our understanding of the atmospheric chemistry of isoprene and other biogenic VOCs under low NOX conditions. In the summer of 2016, OH, HO2 and HO2* (HO2 + αRO2) radicals were measured using the Indiana University Laser-Induced Fluorescence Fluorescence Assay by Gas Expansion (LIF-FAGE) technique as part of the Program for Research on Oxidants: PHtochemistry, Emissions, and Transport- Atmospheric Measurements of Oxidants in Summer (PROPHET-AMOS). This campaign took place in a forested area in northern Michigan characterized by high mixing ratios of isoprene and low mixing ratios of NOX. Ambient measurements from this campaign will be compared to previous measurements at this site and to modeled predictions using both the Regional Atmospheric Chemistry Mechanism (RACM2) and the Master Chemical Mechanism. Potential interferences associated with the OH measurements will also be examined.
Setting cumulative emissions targets to reduce the risk of dangerous climate change
Zickfeld, Kirsten; Eby, Michael; Matthews, H. Damon; Weaver, Andrew J.
2009-01-01
Avoiding “dangerous anthropogenic interference with the climate system” requires stabilization of atmospheric greenhouse gas concentrations and substantial reductions in anthropogenic emissions. Here, we present an inverse approach to coupled climate-carbon cycle modeling, which allows us to estimate the probability that any given level of carbon dioxide (CO2) emissions will exceed specified long-term global mean temperature targets for “dangerous anthropogenic interference,” taking into consideration uncertainties in climate sensitivity and the carbon cycle response to climate change. We show that to stabilize global mean temperature increase at 2 °C above preindustrial levels with a probability of at least 0.66, cumulative CO2 emissions from 2000 to 2500 must not exceed a median estimate of 590 petagrams of carbon (PgC) (range, 200 to 950 PgC). If the 2 °C temperature stabilization target is to be met with a probability of at least 0.9, median total allowable CO2 emissions are 170 PgC (range, −220 to 700 PgC). Furthermore, these estimates of cumulative CO2 emissions, compatible with a specified temperature stabilization target, are independent of the path taken to stabilization. Our analysis therefore supports an international policy framework aimed at avoiding dangerous anthropogenic interference formulated on the basis of total allowable greenhouse gas emissions. PMID:19706489
Aerodynamic Interference Due to MSL Reaction Control System
NASA Technical Reports Server (NTRS)
Dyakonov, Artem A.; Schoenenberger, Mark; Scallion, William I.; VanNorman, John W.; Novak, Luke A.; Tang, Chun Y.
2009-01-01
An investigation of effectiveness of the reaction control system (RCS) of Mars Science Laboratory (MSL) entry capsule during atmospheric flight has been conducted. The reason for the investigation is that MSL is designed to fly a lifting actively guided entry with hypersonic bank maneuvers, therefore an understanding of RCS effectiveness is required. In the course of the study several jet configurations were evaluated using Langley Aerothermal Upwind Relaxation Algorithm (LAURA) code, Data Parallel Line Relaxation (DPLR) code, Fully Unstructured 3D (FUN3D) code and an Overset Grid Flowsolver (OVERFLOW) code. Computations indicated that some of the proposed configurations might induce aero-RCS interactions, sufficient to impede and even overwhelm the intended control torques. It was found that the maximum potential for aero-RCS interference exists around peak dynamic pressure along the trajectory. Present analysis largely relies on computational methods. Ground testing, flight data and computational analyses are required to fully understand the problem. At the time of this writing some experimental work spanning range of Mach number 2.5 through 4.5 has been completed and used to establish preliminary levels of confidence for computations. As a result of the present work a final RCS configuration has been designed such as to minimize aero-interference effects and it is a design baseline for MSL entry capsule.
Setting cumulative emissions targets to reduce the risk of dangerous climate change.
Zickfeld, Kirsten; Eby, Michael; Matthews, H Damon; Weaver, Andrew J
2009-09-22
Avoiding "dangerous anthropogenic interference with the climate system" requires stabilization of atmospheric greenhouse gas concentrations and substantial reductions in anthropogenic emissions. Here, we present an inverse approach to coupled climate-carbon cycle modeling, which allows us to estimate the probability that any given level of carbon dioxide (CO2) emissions will exceed specified long-term global mean temperature targets for "dangerous anthropogenic interference," taking into consideration uncertainties in climate sensitivity and the carbon cycle response to climate change. We show that to stabilize global mean temperature increase at 2 degrees C above preindustrial levels with a probability of at least 0.66, cumulative CO2 emissions from 2000 to 2500 must not exceed a median estimate of 590 petagrams of carbon (PgC) (range, 200 to 950 PgC). If the 2 degrees C temperature stabilization target is to be met with a probability of at least 0.9, median total allowable CO2 emissions are 170 PgC (range, -220 to 700 PgC). Furthermore, these estimates of cumulative CO2 emissions, compatible with a specified temperature stabilization target, are independent of the path taken to stabilization. Our analysis therefore supports an international policy framework aimed at avoiding dangerous anthropogenic interference formulated on the basis of total allowable greenhouse gas emissions.
Monitoring of PM10 and PM2.5 around primary particulate anthropogenic emission sources
NASA Astrophysics Data System (ADS)
Querol, Xavier; Alastuey, Andrés; Rodriguez, Sergio; Plana, Felicià; Mantilla, Enrique; Ruiz, Carmen R.
Investigations on the monitoring of ambient air levels of atmospheric particulates were developed around a large source of primary anthropogenic particulate emissions: the industrial ceramic area in the province of Castelló (Eastern Spain). Although these primary particulate emissions have a coarse grain-size distribution, the atmospheric transport dominated by the breeze circulation accounts for a grain-size segregation, which results in ambient air particles occurring mainly in the 2.5-10 μm range. The chemical composition of the ceramic particulate emissions is very similar to the crustal end-member but the use of high Al, Ti and Fe as tracer elements as well as a peculiar grain-size distribution in the insoluble major phases allow us to identify the ceramic input in the bulk particulate matter. PM2.5 instead of PM10 monitoring may avoid the interference of crustal particles without a major reduction in the secondary anthropogenic load, with the exception of nitrate. However, a methodology based in PM2.5 measurement alone is not adequate for monitoring the impact of primary particulate emissions (such as ceramic emissions) on air quality, since the major ambient air particles derived from these emissions are mainly in the range of 2.5-10 μm. Consequently, in areas characterised by major secondary particulate emissions, PM2.5 monitoring should detect anthropogenic particulate pollutants without crustal particulate interference, whereas PM10 measurements should be used in areas with major primary anthropogenic particulate emissions.
Research on fast algorithm of small UAV navigation in non-linear matrix reductionism method
NASA Astrophysics Data System (ADS)
Zhang, Xiao; Fang, Jiancheng; Sheng, Wei; Cao, Juanjuan
2008-10-01
The low Reynolds numbers of small UAV will result in unfavorable aerodynamic conditions to support controlled flight. And as operated near ground, the small UAV will be affected seriously by low-frequency interference caused by atmospheric disturbance. Therefore, the GNC system needs high frequency of attitude estimation and control to realize the steady of the UAV. In company with the dimensional of small UAV dwindling away, its GNC system is more and more taken embedded designing technology to reach the purpose of compactness, light weight and low power consumption. At the same time, the operational capability of GNC system also gets limit in a certain extent. Therefore, a kind of high speed navigation algorithm design becomes the imminence demand of GNC system. Aiming at such requirement, a kind of non-linearity matrix reduction approach is adopted in this paper to create a new high speed navigation algorithm which holds the radius of meridian circle and prime vertical circle as constant and linearizes the position matrix calculation formulae of navigation equation. Compared with normal navigation algorithm, this high speed navigation algorithm decreases 17.3% operand. Within small UAV"s mission radius (20km), the accuracy of position error is less than 0.13m. The results of semi-physical experiments and small UAV's auto pilot testing proved that this algorithm can realize high frequency attitude estimation and control. It will avoid low-frequency interference caused by atmospheric disturbance properly.
NASA Astrophysics Data System (ADS)
Cotté, B.
2018-05-01
This study proposes to couple a source model based on Amiet's theory and a parabolic equation code in order to model wind turbine noise emission and propagation in an inhomogeneous atmosphere. Two broadband noise generation mechanisms are considered, namely trailing edge noise and turbulent inflow noise. The effects of wind shear and atmospheric turbulence are taken into account using the Monin-Obukhov similarity theory. The coupling approach, based on the backpropagation method to preserve the directivity of the aeroacoustic sources, is validated by comparison with an analytical solution for the propagation over a finite impedance ground in a homogeneous atmosphere. The influence of refraction effects is then analyzed for different directions of propagation. The spectrum modification related to the ground effect and the presence of a shadow zone for upwind receivers are emphasized. The validity of the point source approximation that is often used in wind turbine noise propagation models is finally assessed. This approximation exaggerates the interference dips in the spectra, and is not able to correctly predict the amplitude modulation.
Conveyor with rotary airlock apparatus
Kronbert, J.W.
1993-01-01
This invention is comprised of an apparatus for transferring objects from a first region to a second region, the first and second regions having differing atmospheric environments. The apparatus includes a shell having an entrance and an exit, a conveyer belt running through the shell from the entrance to the exit, and a horizontally mounted `revolving door` with at least four vanes revolving about its axis. The inner surface of the shell and the top surface of the conveyer belt act as opposing walls of the `revolving door`. The conveyer belt dips as it passes under but against the revolving vanes so as not to interfere with them but to engage at least two of the vanes and define thereby a moving chamber. Preferably, the conveyer belt has ridges or grooves on its surface that engage the edges of the vanes and act to rotate the vane assembly. Conduits are provided that communicate with the interior of the shell and allow the adjustment of the atmosphere of the moving chamber or recovery of constituents of the atmosphere of the first region from the moving chamber before they escape to the second region.
Field measurements of methylglyoxal using Proton Transfer Reaction-Time of flight-Mass Spectrometry
NASA Astrophysics Data System (ADS)
Dusanter, S.; Michoud, V.; Sauvage, S.; Leonardis, T.; Locoge, N.
2017-12-01
Methylglyoxal (MGLY) is an atmospheric α-dicarbonyl species whose photolysis is an important source of peroxy radicals. MGLY can therefore significantly impact the oxidizing capacity of the atmosphere and, as such, the formation rate of organic aerosols and ozone. However, despite its importance, only a few techniques exhibit time resolutions and detection limits that are suitable for atmospheric measurements. This presentation will report the first field measurements of MGLY by Proton Transfer Reaction-Time of Flight Mass Spectrometry (PTR-ToFMS) performed during ChArMEx SOP2. This field campaign took place during summer 2013 at a Mediterranean site characterized by intense biogenic emissions and low levels of anthropogenic trace gases. Concomitant measurements of MGLY were performed using the 2,4-dinitrophenylhydrazine (DNPH) derivatization technique and High Performance Liquide Chromatography (HPLC) with UV detection. PTR-ToFMS and DNPH-HPLC measurements ranging from 28-365 pptv are compared to assess the reliability of the two techniques, discussing potential calibration issues, spectrometric interferences, water-dependant artefacts, and memory effects. The MGLY budget at this remote site will also be briefly discussed.
Conveyor with rotary airlock apparatus
Kronberg, James W.
1995-01-01
An apparatus for transferring objects from a first region to a second reg, the first and second regions having differing atmospheric environments. The apparatus includes a shell having an entrance and an exit, a conveyor belt running through the shell from the entrance to the exit, and a horizontally mounted "revolving door" with at least four vanes revolving about its axis. The inner surface of the shell and the top surface of the conveyor belt act as opposing walls of the "revolving door." The conveyor belt dips as it passes under but against the revolving vanes so as not to interfere with them but to engage at least two of the vanes and define thereby a moving chamber. Preferably, the conveyor belt has ridges or grooves on its surface that engage the edges of the vanes and act to rotate the vane assembly. Conduits are provided that communicate with the interior of the shell and allow the adjustment of the atmosphere of the moving chamber or recovery of constituents of the atmosphere of the first region from the moving chamber before they escape to the second region.
Chemical kinetic studies of atmospheric reactions using tunable diode laser spectroscopy
NASA Technical Reports Server (NTRS)
Worsnop, Douglas R.; Nelson, David D.; Zahniser, Mark S.
1993-01-01
IR absorption using tunable diode laser spectroscopy provides a sensitive and quantitative detection method for laboratory kinetic studies of atmospheric trace gases. Improvements in multipass cell design, real time signal processing, and computer controlled data acquisition and analysis have extended the applicability of the technique. We have developed several optical systems using off-axis resonator mirror designs which maximize path length while minimizing both the sample volume and the interference fringes inherent in conventional 'White' cells. Computerized signal processing using rapid scan (300 kHz), sweep integration with 100 percent duty cycle allows substantial noise reduction while retaining the advantages of using direct absorption for absolute absorbance measurements and simultaneous detection of multiple species. Peak heights and areas are determined by curve fitting using nonlinear least square methods. We have applied these techniques to measurements of: (1) heterogeneous uptake chemistry of atmospheric trace gases (HCl, H2O2, and N2O5) on aqueous and sulfuric acid droplets; (2) vapor pressure measurements of nitric acid and water over prototypical stratospheric aerosol (nitric acid trihydrate) surfaces; and (3) discharge flow tube kinetic studies of the HO2 radical using isotopic labeling for product channel and mechanistic analysis. Results from each of these areas demonstrate the versatility of TDL absorption spectroscopy for atmospheric chemistry applications.
Zhang, Renyi; Khalizov, Alexei F.; Pagels, Joakim; Zhang, Dan; Xue, Huaxin; McMurry, Peter H.
2008-01-01
The atmospheric effects of soot aerosols include interference with radiative transfer, visibility impairment, and alteration of cloud formation and are highly sensitive to the manner by which soot is internally mixed with other aerosol constituents. We present experimental studies to show that soot particles acquire a large mass fraction of sulfuric acid during atmospheric aging, considerably altering their properties. Soot particles exposed to subsaturated sulfuric acid vapor exhibit a marked change in morphology, characterized by a decreased mobility-based diameter but an increased fractal dimension and effective density. These particles experience large hygroscopic size and mass growth at subsaturated conditions (<90% relative humidity) and act efficiently as cloud-condensation nuclei. Coating with sulfuric acid and subsequent hygroscopic growth enhance the optical properties of soot aerosols, increasing scattering by ≈10-fold and absorption by nearly 2-fold at 80% relative humidity relative to fresh particles. In addition, condensation of sulfuric acid is shown to occur at a similar rate on ambient aerosols of various types of a given mobility size, regardless of their chemical compositions and microphysical structures. Representing an important mechanism of atmospheric aging, internal mixing of soot with sulfuric acid has profound implications on visibility, human health, and direct and indirect climate forcing. PMID:18645179
Atmospheric transformation of plant volatiles disrupts host plant finding
NASA Astrophysics Data System (ADS)
Li, Tao; Blande, James D.; Holopainen, Jarmo K.
2016-09-01
Plant-emitted volatile organic compounds (VOCs) play important roles in plant-insect interactions. Atmospheric pollutants such as ozone (O3) can react with VOCs and affect the dynamics and fidelity of these interactions. However, the effects of atmospheric degradation of plant VOCs on plant-insect interactions remains understudied. We used a system comprising Brassica oleracea subsp. capitata (cabbage) and the specialist herbivore Plutella xylostella to test whether O3-triggered VOC degradation disturbs larval host orientation, and to investigate the underlying mechanisms. Larvae oriented towards both constitutive and larva-induced cabbage VOC blends, the latter being the more attractive. Such behaviour was, however, dramatically reduced in O3-polluted environments. Mechanistically, O3 rapidly degraded VOCs with the magnitude of degradation increasing with O3 levels. Furthermore, we used Teflon filters to collect VOCs and their reaction products, which were used as odour sources in behavioural tests. Larvae avoided filters exposed to O3-transformed VOCs and spent less time searching on them compared to filters exposed to original VOCs, which suggests that some degradation products may have repellent properties. Our study clearly demonstrates that oxidizing pollutants in the atmosphere can interfere with insect host location, and highlights the need to address their broader impacts when evaluating the ecological significance of VOC-mediated interactions.
Atmospheric transformation of plant volatiles disrupts host plant finding
Li, Tao; Blande, James D.; Holopainen, Jarmo K.
2016-01-01
Plant-emitted volatile organic compounds (VOCs) play important roles in plant-insect interactions. Atmospheric pollutants such as ozone (O3) can react with VOCs and affect the dynamics and fidelity of these interactions. However, the effects of atmospheric degradation of plant VOCs on plant-insect interactions remains understudied. We used a system comprising Brassica oleracea subsp. capitata (cabbage) and the specialist herbivore Plutella xylostella to test whether O3-triggered VOC degradation disturbs larval host orientation, and to investigate the underlying mechanisms. Larvae oriented towards both constitutive and larva-induced cabbage VOC blends, the latter being the more attractive. Such behaviour was, however, dramatically reduced in O3-polluted environments. Mechanistically, O3 rapidly degraded VOCs with the magnitude of degradation increasing with O3 levels. Furthermore, we used Teflon filters to collect VOCs and their reaction products, which were used as odour sources in behavioural tests. Larvae avoided filters exposed to O3-transformed VOCs and spent less time searching on them compared to filters exposed to original VOCs, which suggests that some degradation products may have repellent properties. Our study clearly demonstrates that oxidizing pollutants in the atmosphere can interfere with insect host location, and highlights the need to address their broader impacts when evaluating the ecological significance of VOC-mediated interactions. PMID:27651113
Complex wavefront sensing with a plenoptic sensor
NASA Astrophysics Data System (ADS)
Wu, Chensheng; Ko, Jonathan; Davis, Christopher C.
2016-09-01
There are many techniques to achieve basic wavefront sensing tasks in the weak atmospheric turbulence regime. However, in strong and deep turbulence situations, the complexity of a propagating wavefront increases significantly. Typically, beam breakup will happen and various portions of the beam will randomly interfere with each other. Consequently, some conventional techniques for wavefront sensing turn out to be inaccurate and misleading. For example, a Shack-Hartmann sensor will be confused by multi-spot/zero-spot result in some cells. The curvature sensor will be affected by random interference patterns for both the image acquired before the focal plane and the image acquired after the focal plane. We propose the use of a plenoptic sensor to solve complex wavefront sensing problems. In fact, our results show that even for multiple beams (their wavelengths can be the same) passing through the same turbulent channel, the plenoptic sensor can reconstruct the turbulence-induced distortion accurately. In this paper, we will demonstrate the plenoptic mapping principle to analyze and reconstruct the complex wavefront of a distorted laser beam.
Harvey, J E; Reddy, S P; Phillips, R L
1996-07-20
The active illumination of a target through a turbulent medium with a monostatic transmitter-receiver results in a naturally occurring conjugate wave caused by reciprocal scattering paths that experience identical phase variations. This reciprocal path-scattering phenomenon produces an enhanced backscatter in the retroverse direction (precisely along the boresight of the pointing telescope). A dual aperture causes this intensity enhancement to take the form of Young's interference fringes. Interference fringes produced by the reciprocal path-scattering phenomenon are temporally stable even in the presence of time-varying turbulence. Choosing the width-to-separation ratio of the dual apertures appropriately and utilizing orthogonal polarizations to suppress the time-varying common-path scattered radiation allow one to achieve interferometric sensitivity in pointing accuracy through a random medium or turbulent atmosphere. Computer simulations are compared with laboratory experimental data. This new precision pointing and tracking technique has potential applications in ground-to-space laser communications, laser power beaming to satellites, and theater missile defense scenarios.
On determining the point of no return in climate change
NASA Astrophysics Data System (ADS)
van Zalinge, Brenda C.; Feng, Qing Yi; Aengenheyster, Matthias; Dijkstra, Henk A.
2017-08-01
Earth's global mean surface temperature has increased by about 1.0 °C over the period 1880-2015. One of the main causes is thought to be the increase in atmospheric greenhouse gases. If greenhouse gas emissions are not substantially decreased, several studies indicate that there will be a dangerous anthropogenic interference with climate by the end of this century. However, there is no good quantitative measure to determine when it is too late
to start reducing greenhouse gas emissions in order to avoid such dangerous interference. In this study, we develop a method for determining a so-called point of no return
for several greenhouse gas emission scenarios. The method is based on a combination of aspects of stochastic viability theory and linear response theory; the latter is used to estimate the probability density function of the global mean surface temperature. The innovative element in this approach is the applicability to high-dimensional climate models as demonstrated by the results obtained with the PlaSim model.
A Method for Monitoring Organic Chlorides, Hydrochloric Acid and Chlorine in Air
NASA Technical Reports Server (NTRS)
Dennison, J. E.; Menichelli, R. P.
1971-01-01
While not commonly presented in nonurban atmospheres, organic chlorides, hydrochloric acid and chlorine are significant in industrial air pollution and industrial hygiene. Based on a microcoulometer, a much more sensitive method than has heretofore been available has been developed for monitoring these air impurities. The method has a response time (90%) of about twenty seconds, requires no calibration, is accurate to +/- 2.5%, and specific except for bromide and iodide interferences. The instrument is portable and has been operated unattended for 18 hours without difficulty.
NASA Technical Reports Server (NTRS)
Davis, D. D.; Philen, D.
1978-01-01
The laser-induced fluorescence technique for obtaining direct measurements of atmospheric OH and other gases is described. A narrow-band UV laser is tuned to one or more of the electronic absorption bands of a specified molecule so as to cause fluorescence from a bonding excited electronic state. The monitored wavelength is longer than the laser wavelength. Equipment, specifics for OH detection, data processing, and interference are discussed, and application of the technique to the detection of NO, SO2, and CH2O is considered.
NASA Technical Reports Server (NTRS)
Whipple, E. C., Jr.
1982-01-01
The impact ionization phenomenon which was observed on certain spacecraft was studied. The phenomenon occurs when a neutral atom, molecule, or ion strikes a surface with sufficient kinetic energy that either the incident neutral or atoms on the surface are ionized, with subsequent escape of ions and/or electrons. The released ions and electrons can interfere with measurements on the spacecraft by confusing interpretation of the data. On the other hand, there is the possibility that the effect could be developed into a diagnostic tool for investigating neutral atmospheric species or for studying physical processes on spacecraft surfaces.
Laser absorption spectroscopy - Method for monitoring complex trace gas mixtures
NASA Technical Reports Server (NTRS)
Green, B. D.; Steinfeld, J. I.
1976-01-01
A frequency stabilized CO2 laser was used for accurate determinations of the absorption coefficients of various gases in the wavelength region from 9 to 11 microns. The gases investigated were representative of the types of contaminants expected to build up in recycled atmospheres. These absorption coefficients were then used in determining the presence and amount of the gases in prepared mixtures. The effect of interferences on the minimum detectable concentration of the gases was measured. The accuracies of various methods of solution were also evaluated.
Gas mixing enhanced by power modulations in atmospheric pressure microwave plasma jet
NASA Astrophysics Data System (ADS)
Voráč, J.; Potočňáková, L.; Synek, P.; Hnilica, J.; Kudrle, V.
2016-04-01
Microwave plasma jet operating in atmospheric pressure argon was power modulated by audio frequency sine envelope in the 102 W power range. Its effluent was imaged using interference filters and ICCD camera for several different phases of the modulating signal. The combination of this fast imaging with spatially resolved optical emission spectroscopy provides useful insights into the plasmachemical processes involved. Phase-resolved schlieren photography was performed to visualize the gas dynamics. The results show that for higher modulation frequencies the plasma chemistry is strongly influenced by formation of transient flow perturbation resembling a vortex during each period. The perturbation formation and speed are strongly influenced by the frequency and power variations while they depend only weakly on the working gas flow rate. From application point of view, the perturbation presence significantly broadened lateral distribution of active species, effectively increasing cross-sectional area suitable for applications.
NASA Astrophysics Data System (ADS)
Vasilyev, Roman; Artamonov, Maksim; Beletsky, Aleksandr; Zherebtsov, Geliy; Medvedeva, Irina; Mikhalev, Aleksandr; Syrenova, Tatyana
2017-09-01
We describe the Fabry–Perot interferometer designed to study Earth’s upper atmosphere. We propose a modification of the existing data processing method for determining the Doppler shift and Doppler widening and also for separating the observed line intensity and the background intensity. The temperature and wind velocity derived from these parameters are compared with physical characteristics obtained from modeling (NRLMSISE-00, HWM14). We demonstrate that the temperature is determined from the oxygen 630 nm line irrespective of the hydroxyl signal existing in interference patterns. We show that the interferometer can obtain temperature from the oxygen 557.7 nm line in case of additional calibration of the device. The observed wind velocity mainly agrees with model data. Night variations in the red and green oxygen lines quite well coincide with those in intensities obtained by devices installed nearby the interferometer.
NASA Technical Reports Server (NTRS)
Spinhirne, James D. (Inventor)
1993-01-01
An eye safe, compact, solid state lidar for profiling atmospheric cloud and aerosol scattering is disclosed. The transmitter of the micro pulse lidar is a diode pumped micro-J pulse energy, high repetition rate Nd:YLF laser. Eye safety is obtained through beam expansion. The receiver employs a photon counting solid state Geiger mode avalanche photodiode detector. Data acquisition is by a single card multichannel scaler. Daytime background induced quantum noise is controlled by a narrow receiver field-of-view and a narrow bandwidth temperature controlled interference filter. Dynamic range of the signal is limited to optical geometric signal compression. Signal simulations and initial atmospheric measurements indicate that micropulse lider systems are capable of detecting and profiling all significant cloud and aerosol scattering through the troposphere and into the stratosphere. The intended applications are scientific studies and environmental monitoring which require full time, unattended measurements of the cloud and aerosol height structure.
NASA Technical Reports Server (NTRS)
Spinhirne, James D.
1993-01-01
An eye safe, compact, solid state lidar for profiling atmospheric cloud and aerosol scattering has been demonstrated. The transmitter of the micropulse lidar is a diode pumped micro-J pulse energy, high repetition rate Nd:YLF laser. Eye safety is obtained through beam expansion. The receiver employs a photon counting solid state Geiger mode avalanche photodiode detector. Data acquisition is by a single card multichannel scaler. Daytime background induced quantum noise is controlled by a narrow receiver field-of-view and a narrow bandwidth temperature controlled interference filter. Dynamic range of the signal is limited by optical geometric signal compression. Signal simulations and initial atmospheric measurements indicate that systems built on the micropulse lidar concept are capable of detecting and profiling all significant cloud and aerosol scattering through the troposphere and into the stratosphere. The intended applications are scientific studies and environmental monitoring which require full time, unattended measurements of the cloud and aerosol height structure.
Space and Atmospheric Environments: From Low Earth Orbits to Deep Space
NASA Technical Reports Server (NTRS)
Barth, Janet L.
2003-01-01
Natural space and atmospheric environments pose a difficult challenge for designers of technological systems in space. The deleterious effects of environment interactions with the systems include degradation of materials, thermal changes, contamination, excitation, spacecraft glow, charging, radiation damage, and induced background interference. Design accommodations must be realistic with minimum impact on performance while maintaining a balance between cost and risk. The goal of applied research in space environments and effects is to limit environmental impacts at low cost relative to spacecraft cost and to infuse enabling and commercial off-the-shelf technologies into space programs. The need to perform applied research to understand the space environment in a practical sense and to develop methods to mitigate these environment effects is frequently underestimated by space agencies and industry. Applied science research in this area is critical because the complexity of spacecraft systems is increasing, and they are exposed simultaneously to a multitude of space environments.
Geometrical Monte Carlo simulation of atmospheric turbulence
NASA Astrophysics Data System (ADS)
Yuksel, Demet; Yuksel, Heba
2013-09-01
Atmospheric turbulence has a significant impact on the quality of a laser beam propagating through the atmosphere over long distances. Turbulence causes intensity scintillation and beam wander from propagation through turbulent eddies of varying sizes and refractive index. This can severely impair the operation of target designation and Free-Space Optical (FSO) communications systems. In addition, experimenting on an FSO communication system is rather tedious and difficult. The interferences of plentiful elements affect the result and cause the experimental outcomes to have bigger error variance margins than they are supposed to have. Especially when we go into the stronger turbulence regimes the simulation and analysis of the turbulence induced beams require delicate attention. We propose a new geometrical model to assess the phase shift of a laser beam propagating through turbulence. The atmosphere along the laser beam propagation path will be modeled as a spatial distribution of spherical bubbles with refractive index discontinuity calculated from a Gaussian distribution with the mean value being the index of air. For each statistical representation of the atmosphere, the path of rays will be analyzed using geometrical optics. These Monte Carlo techniques will assess the phase shift as a summation of the phases that arrive at the same point at the receiver. Accordingly, there would be dark and bright spots at the receiver that give an idea regarding the intensity pattern without having to solve the wave equation. The Monte Carlo analysis will be compared with the predictions of wave theory.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Na, Ji Sung; Koo, Eunmo; Munoz-Esparza, Domingo
High-resolution large-eddy simulation of the flow over a large wind farm (64 wind turbines) is performed using the HIGRAD/FIRETEC-WindBlade model, which is a high-performance computing wind turbine–atmosphere interaction model that uses the Lagrangian actuator line method to represent rotating turbine blades. These high-resolution large-eddy simulation results are used to parameterize the thrust and power coefficients that contain information about turbine interference effects within the wind farm. Those coefficients are then incorporated into the WRF (Weather Research and Forecasting) model in order to evaluate interference effects in larger-scale models. In the high-resolution WindBlade wind farm simulation, insufficient distance between turbines createsmore » the interference between turbines, including significant vertical variations in momentum and turbulent intensity. The characteristics of the wake are further investigated by analyzing the distribution of the vorticity and turbulent intensity. Quadrant analysis in the turbine and post-turbine areas reveals that the ejection motion induced by the presence of the wind turbines is dominant compared to that in the other quadrants, indicating that the sweep motion is increased at the location where strong wake recovery occurs. Regional-scale WRF simulations reveal that although the turbulent mixing induced by the wind farm is partly diffused to the upper region, there is no significant change in the boundary layer depth. The velocity deficit does not appear to be very sensitive to the local distribution of turbine coefficients. However, differences of about 5% on parameterized turbulent kinetic energy were found depending on the turbine coefficient distribution. Furthermore, turbine coefficients that consider interference in the wind farm should be used in wind farm parameterization for larger-scale models to better describe sub-grid scale turbulent processes.« less
NASA Astrophysics Data System (ADS)
Chen, H.; Karion, A.; Rella, C. W.; Winderlich, J.; Gerbig, C.; Filges, A.; Newberger, T.; Sweeney, C.; Tans, P. P.
2012-09-01
Accurate measurements of carbon monoxide (CO) in humid air have been made using the cavity ring-down spectroscopy (CRDS) technique. The measurements of CO mole fractions are determined from the strength of its spectral absorption in the near infrared region (∼1.57 μm) after removing interferences from adjacent carbon dioxide (CO2) and water vapor (H2O) absorption lines. Water correction functions that account for the dilution and pressure-broadening effects as well as absorption line interferences from adjacent CO2 and H2O lines have been derived for CO2 mole fractions between 360-390 ppm. The line interference corrections are independent of CO mole fractions. The dependence of the line interference correction on CO2 abundance is estimated to be approximately -0.3 ppb/100 ppm CO2 for dry mole fractions of CO. Comparisons of water correction functions from different analyzers of the same type show significant differences, making it necessary to perform instrument-specific water tests for each individual analyzer. The CRDS analyzer was flown on an aircraft in Alaska from April to November in 2011, and the accuracy of the CO measurements by the CRDS analyzer has been validated against discrete NOAA/ESRL flask sample measurements made on board the same aircraft, with a mean difference between integrated in situ and flask measurements of -0.6 ppb and a standard deviation of 2.8 ppb. Preliminary testing of CRDS instrumentation that employs new spectroscopic analysis (available since the beginning of 2012) indicates a smaller water vapor dependence than the models discussed here, but more work is necessary to fully validate the performance. The CRDS technique provides an accurate and low-maintenance method of monitoring the atmospheric dry mole fractions of CO in humid air streams.
Turbulent kinetics of a large wind farm and their impact in the neutral boundary layer
Na, Ji Sung; Koo, Eunmo; Munoz-Esparza, Domingo; ...
2015-12-28
High-resolution large-eddy simulation of the flow over a large wind farm (64 wind turbines) is performed using the HIGRAD/FIRETEC-WindBlade model, which is a high-performance computing wind turbine–atmosphere interaction model that uses the Lagrangian actuator line method to represent rotating turbine blades. These high-resolution large-eddy simulation results are used to parameterize the thrust and power coefficients that contain information about turbine interference effects within the wind farm. Those coefficients are then incorporated into the WRF (Weather Research and Forecasting) model in order to evaluate interference effects in larger-scale models. In the high-resolution WindBlade wind farm simulation, insufficient distance between turbines createsmore » the interference between turbines, including significant vertical variations in momentum and turbulent intensity. The characteristics of the wake are further investigated by analyzing the distribution of the vorticity and turbulent intensity. Quadrant analysis in the turbine and post-turbine areas reveals that the ejection motion induced by the presence of the wind turbines is dominant compared to that in the other quadrants, indicating that the sweep motion is increased at the location where strong wake recovery occurs. Regional-scale WRF simulations reveal that although the turbulent mixing induced by the wind farm is partly diffused to the upper region, there is no significant change in the boundary layer depth. The velocity deficit does not appear to be very sensitive to the local distribution of turbine coefficients. However, differences of about 5% on parameterized turbulent kinetic energy were found depending on the turbine coefficient distribution. Furthermore, turbine coefficients that consider interference in the wind farm should be used in wind farm parameterization for larger-scale models to better describe sub-grid scale turbulent processes.« less
The quantum interference effects in the SC II 4247 Å line of the second solar spectrum
DOE Office of Scientific and Technical Information (OSTI.GOV)
Smitha, H. N.; Nagendra, K. N.; Stenflo, J. O.
2014-10-10
The Sc II 4247 Å line formed in the chromosphere is one of the lines well known, like the Na I D{sub 2} and Ba II D{sub 2}, for its prominent triple-peak structure in Q/I and the underlying quantum interference effects governing it. In this paper, we try to study the nature of this triple-peak structure using the theory of F-state interference including the effects of partial frequency redistribution (PRD) and radiative transfer (RT). We compare our results with the observations taken in a quiet region near the solar limb. In spite of accounting for PRD and RT effects, itmore » has not been possible to reproduce the observed triple-peak structure in Q/I. While the two wing PRD peaks (on either side of central peak) and the near wing continuum can be reproduced, the central peak is completely suppressed by the enhanced depolarization resulting from the hyperfine structure splitting. This suppression remains for all the tested widely different one-dimensional model atmospheres or for any multi-component combinations of them. While multidimensional RT effects may improve the fit to the intensity profiles, they do not appear capable of explaining the enigmatic central Q/I peak. This leads us to suspect that some aspect of quantum physics is missing.« less
NASA Astrophysics Data System (ADS)
Mabilia, Rosanna; Scipioni, Chiara; Vegliò, Francesco; Tomasi Scianò, Maria Concetta
2010-10-01
A new analytical method was developed for the determination of formaldehyde in ambient air based on the use of a modified configuration of the Analyst ® passive sampler. It consists of a polyethylene cylinder filled with appropriate reactive adsorbent and a special anti-turbulence net which works as an ozone scrubber. The performance of a diffusive sampler depends critically on the selection and use of a suitable adsorbent and on environmental factors, such as temperature, humidity and the interference of oxidant species. In this study two adsorbent types were investigated: 2,4-dinitrophenylhydrazine (2,4-DNPH) coated silica gel and Florisil ® particles. Interference of ozone was removed by using a silver net upstream as an anti-turbulence device. The performance of this net was then compared with that of stainless steel. Furthermore, the aim of the work was the optimization of the adsorbent type and the study of the interference of ozone with particular attention placed on the effect of relative humidity and temperature. A dynamic system for generating a known concentration of the test gas (formaldehyde) in an appropriate exposure chamber was used to evaluate the performance of the passive sampler and to allow the calibration of the methodology. Inter-comparisons with a reference method, active sampling using 2,4-DNPH-silica gel coated cartridges, were also carried out. Results were in accordance with each other. Tests were planned using a statistical method based on Design of Experiment methodology. The operating conditions were chosen in order to obtain the best configuration of the passive device by evaluating the statistical significance of the different factors and their interactions by analysis of variance. Results showed that the best configuration was achieved using 2,4-DNPH Florisil ® coated particles as an adsorbent and a silver anti-turbulence net as an ozone scrubber. With the aim of achieving further results in realistic conditions, some field experiments were also carried out.
Determining the phase and amplitude distortion of a wavefront using a plenoptic sensor.
Wu, Chensheng; Ko, Jonathan; Davis, Christopher C
2015-05-01
We have designed a plenoptic sensor to retrieve phase and amplitude changes resulting from a laser beam's propagation through atmospheric turbulence. Compared with the commonly restricted domain of (-π,π) in phase reconstruction by interferometers, the reconstructed phase obtained by the plenoptic sensors can be continuous up to a multiple of 2π. When compared with conventional Shack-Hartmann sensors, ambiguities caused by interference or low intensity, such as branch points and branch cuts, are less likely to happen and can be adaptively avoided by our reconstruction algorithm. In the design of our plenoptic sensor, we modified the fundamental structure of a light field camera into a mini Keplerian telescope array by accurately cascading the back focal plane of its object lens with a microlens array's front focal plane and matching the numerical aperture of both components. Unlike light field cameras designed for incoherent imaging purposes, our plenoptic sensor operates on the complex amplitude of the incident beam and distributes it into a matrix of images that are simpler and less subject to interference than a global image of the beam. Then, with the proposed reconstruction algorithms, the plenoptic sensor is able to reconstruct the wavefront and a phase screen at an appropriate depth in the field that causes the equivalent distortion on the beam. The reconstructed results can be used to guide adaptive optics systems in directing beam propagation through atmospheric turbulence. In this paper, we will show the theoretical analysis and experimental results obtained with the plenoptic sensor and its reconstruction algorithms.
Determining the phase and amplitude distortion of a wavefront using a plenoptic sensor
NASA Astrophysics Data System (ADS)
Wu, Chensheng; Ko, Jonathan; Davis, Christopher C.
2015-05-01
We have designed a plenoptic sensor to retrieve phase and amplitude changes resulting from a laser beam's propagation through atmospheric turbulence. Compared with the commonly restricted domain of (-pi, pi) in phase reconstruction by interferometers, the reconstructed phase obtained by the plenoptic sensors can be continuous up to a multiple of 2pi. When compared with conventional Shack-Hartmann sensors, ambiguities caused by interference or low intensity, such as branch points and branch cuts, are less likely to happen and can be adaptively avoided by our reconstruction algorithm. In the design of our plenoptic sensor, we modified the fundamental structure of a light field camera into a mini Keplerian telescope array by accurately cascading the back focal plane of its object lens with a microlens array's front focal plane and matching the numerical aperture of both components. Unlike light field cameras designed for incoherent imaging purposes, our plenoptic sensor operates on the complex amplitude of the incident beam and distributes it into a matrix of images that are simpler and less subject to interference than a global image of the beam. Then, with the proposed reconstruction algorithms, the plenoptic sensor is able to reconstruct the wavefront and a phase screen at an appropriate depth in the field that causes the equivalent distortion on the beam. The reconstructed results can be used to guide adaptive optics systems in directing beam propagation through atmospheric turbulence. In this paper we will show the theoretical analysis and experimental results obtained with the plenoptic sensor and its reconstruction algorithms.
NASA Astrophysics Data System (ADS)
Yufeng, Wang; Qiang, Fu; Meina, Zhao; Fei, Gao; Huige, Di; Yuehui, Song; Dengxin, Hua
2018-01-01
To monitor the variability and the correlation of multiple atmospheric parameters in the whole troposphere and the lower stratosphere, a ground-based ultraviolet multifunctional Raman lidar system was established to simultaneously measure the atmospheric parameters in Xi'an (34.233°N, 108.911°E). A set of dichroic mirrors (DMs) and narrow-band interference filters (IFs) with narrow angles of incidence were utilized to construct a high-efficiency 5-channel polychromator. A series of high-quality data obtained from October 2013 to December 2015 under different weather conditions were used to investigate the functionality of the Raman lidar system and to study the variability of multiple atmospheric parameters in the whole stratosphere. Their conveying characteristics are also investigated using back trajectories with a hybrid single-particle Lagrangian integrated trajectory model (HYSPLIT). The lidar system can be operated efficiently under weather conditions with a cloud backscattering ratio of less than 18 and an atmospheric visibility of 3 km. We observed an obvious temperature inversion phenomenon at the tropopause height of 17-18 km and occasional temperature inversion layers below the boundary layer. The rapidly changing atmospheric water vapor is mostly concentrated at the lower troposphere, below ∼4-5 km, accounting for ∼90% of the total water vapor content at 0.5-10 km. The back trajectory analysis shows that the air flow from the northwest and the west mainly contributes to the transport of aerosols and water vapor over Xi'an. The simultaneous continuous observational results demonstrate the variability and correlation among the multiple atmospheric parameters, and the accumulated water vapor density in the bottom layer causes an increase in the aerosol extinction coefficient and enhances the relative humidity in the early morning. The long-term observations provide a large amount of reliable atmospheric data below the lower stratosphere, and can be used to study their correlation and to improve local climate change research.
Takino, Masahiko; Daishima, Shigeki; Nakahara, Taketoshi
2003-01-01
This paper describes a comparison between atmospheric pressure chemical ionization (APCI) and the recently introduced atmospheric pressure photoionization (APPI) technique for the liquid chromatography/mass spectrometric (LC/MS) determination of patulin in clear apple juice. A column switching technique for on-line extraction of clear apple juice was developed. The parameters investigated for the optimization of APPI were the ion source parameters fragmentor voltage, capillary voltage, and vaporizer temperature, and also mobile phase composition and flow rate. Furthermore, chemical noise and signal suppression of analyte signals due to sample matrix interference were investigated for both APCI and APPI. The results indicated that APPI provides lower chemical noise and signal suppression in comparison with APCI. The linear range for patulin in apple juice (correlation coefficient >0.999) was 0.2-100 ng mL(-1). Mean recoveries of patulin in three apple juices ranged from 94.5 to 103.2%, and the limit of detection (S/N = 3), repeatability and reproducibility were 1.03-1.50 ng mL(-1), 3.9-5.1% and 7.3-8.2%, respectively. The total analysis time was 10.0 min. Copyright 2003 John Wiley & Sons, Ltd.
Astronaut George Nelson working on Comet Halley Active monitoring program
1986-01-14
61C-05-026 (14 Jan. 1986) --- Astronaut George D. Nelson smiles for a fellow crew man's 35mm camera exposure while participating in the Comet Halley active monitoring program (CHAMP). Camera equipment and a protective shroud used to eliminate all cabin light interference surround the mission specialist. This is the first of three 1986 missions which are scheduled to monitor the rare visit by the comet. The principal investigators for CHAMP are S. Alan Stern of the Laboratory for Atmospheric and Space Physics at the University of Colorado; and Dr. Stephen Mende of Lockheed Palo Alto Research Laboratory.
Detection and measurement of total ozone from stellar spectra: Paper 2. Historic data from 1935-1942
NASA Astrophysics Data System (ADS)
Griffin, R. E. M.
2006-06-01
Atmospheric ozone columns are derived from historic stellar spectra observed between 1935 and 1942 at Mount Wilson Observatory, California. Comparisons with contemporary measurements in the Arosa database show a generally close correspondence, while a similar comparison with more sparse data from Table Mountain reveals a difference of ~15-20%, as has also been found by other researches of the latter data. The results of the analysis indicate that astronomy's archives command considerable potential for investigating the natural levels of ozone and its variability during the decades prior to anthropogenic interference.
NASA Astrophysics Data System (ADS)
Qi, Dong; Wang, Xian; Cheng, Yongzhi; Gong, Rongzhou; Li, Bowen
2016-12-01
One-dimensional photonic crystals (1DPCs) based on ZnS/Ge for compatible stealth of infrared and visible were firstly proposed theoretically and investigated experimentally. Owing to the equal inclination interference, the designed 1DPCs structure can be fabricated with a certain color corresponding to the different responded wavelength. In addition, the average emissivity of the proposed structure can reach as low as 0.054 at infrared atmosphere window of 3-5 μm. The as-prepared structure indicates that it is feasible for 1DPC to achieve infrared-visible compatible stealth.
Plasma heating for containerless and microgravity materials processing
NASA Technical Reports Server (NTRS)
Leung, Emily W. (Inventor); Man, Kin F. (Inventor)
1994-01-01
A method for plasma heating of levitated samples to be used in containerless microgravity processing is disclosed. A sample is levitated by electrostatic, electromagnetic, aerodynamic, or acoustic systems, as is appropriate for the physical properties of the particular sample. The sample is heated by a plasma torch at atmospheric pressure. A ground plate is provided to help direct the plasma towards the sample. In addition, Helmholtz coils are provided to produce a magnetic field that can be used to spiral the plasma around the sample. The plasma heating system is oriented such that it does not interfere with the levitation system.
ROCOZ-A (improved rocket launched ozone sensor) for middle atmosphere ozone measurements
NASA Technical Reports Server (NTRS)
Lee, H. S.; Parsons, C. L.
1987-01-01
An improved interference filter based ultraviolet photometer (ROCOZ-A) for measuring stratospheric ozone is discussed. The payload is launched aboard a Super-Loki to a typical apogee of 70 km. The instrument measures the solar ultraviolet irradiance as it descends on a parachute. The total cumulative ozone is then calculated based on the Beer-Lambert law. The cumulative ozone precision measured in this way is 2.0% to 2.5% over an altitude range of 20 and 55 km. Results of the intercomparison with the SBUV overpass data and ROCOZ-A data are also discussed.
Endecott, B R; Sanders, D C; Chaturvedi, A K
1996-01-01
The measurement of combustion gases produced by burning aircraft cabin materials poses a continuing limitation for smoke toxicity research. Because toxic effects of gases depend on both their concentrations and the duration of exposure, frequent atmosphere sampling is necessary to define the gas concentration-exposure time curve. A gas chromatographic (GC) method was developed for the simultaneous analyses of carbon monoxide (CO), hydrogen sulfide (H2S), sulfur dioxide (SO2), and hydrogen cyanide (HCN). The method used an MTI M200 dual-column gas chromatograph equipped with 4-m molecular sieve-5A and 8-m PoraPlot-U wall-coated capillary columns and two low-volume, high-sensitivity thermal conductivity detectors. Detectability (in parts per million [ppm]) and retention times (in seconds) for the gases were as follows: CO, 100 ppm, 28 s; H2S, 50 ppm, 26 s; SO2, 125 ppm, 76 s; and HCN, 60 ppm, 108 s. The method was effective for determining these gases in mixtures and in the combustion atmospheres generated by burning wool (CO, HCN, and H2S) and modacrylic fabrics (CO and HCN). Common atmospheric gaseous or combustion products (oxygen, carbon dioxide, nitrogen, water vapor, and other volatiles) did not interfere with the analyses. However, filtration of the combustion atmospheres was necessary to prevent restriction of the GC sampling inlet by smoke particulates. The speed, sensitivity, and selectivity of this method make it suitable for smoke toxicity research and for evaluating performance of passenger protective breathing equipment. Also, this method can potentially be modified to analyze these gases when they are liberated from biosamples.
NASA Astrophysics Data System (ADS)
Qin, Hongchen; Pritchard, Michael S.; Kooperman, Gabriel J.; Parishani, Hossein
2018-02-01
Many conventional General Circulation Models (GCMs) in the Global Land-Atmosphere Coupling Experiment (GLACE) tend to produce what is now recognized as overly strong land-atmosphere (L-A) coupling. We investigate the effects of cloud Superparameterization (SP) on L-A coupling on timescales beyond diurnal where it has been recently shown to have a favorable muting effect hydrologically. Using the Community Atmosphere Model v3.5 (CAM3.5) and its Superparameterized counterpart SPCAM3.5, we conducted soil moisture interference experiments following the GLACE and Atmospheric Model Intercomparison Project (AMIP) protocols. The results show that, on weekly-to-subseasonal timescales, SP also mutes hydrologic L-A coupling. This is detectable globally, and happens through the evapotranspiration-precipitation segment. But on seasonal timescales, SP does not exhibit detectable effects on hydrologic L-A coupling. Two robust regional effects of SP on thermal L-A coupling have also been explored. Over the Arabian Peninsula, SP reduces thermal L-A coupling through a straightforward control by mean rainfall reduction. More counterintuitively, over the Southwestern US and Northern Mexico, SP enhances the thermal L-A coupling in a way that is independent of rainfall and soil moisture. This signal is associated with a systematic and previously unrecognized effect of SP that produces an amplified Bowen ratio, and is detectable in multiple SP model versions and experiment designs. In addition to amplifying the present-day Bowen ratio, SP is found to amplify the climate sensitivity of Bowen ratio as well, which likely plays a role in influencing climate change predictions at the L-A interface.
Radio Frequency Interference Site Survey for Thai Radio Telescopes
NASA Astrophysics Data System (ADS)
Jaroenjittichai, P.; Punyawarin, S.; Singwong, D.; Somboonpon, P.; Prasert, N.; Bandudej, K.; Kempet, P.; Leckngam, A.; Poshyachinda, S.; Soonthornthum, B.; Kramer, B.
2017-09-01
Radio astronomical observations have increasingly been threaten by the march of today telecommunication and wireless technology. Performance of radio telescopes lies within the fact that astronomical sources are extremely weak. National Astronomy Research Institute of Thailand (NARIT) has initiated a 5-year project, known as the Radio Astronomy Network and Geodesy for Development (RANGD), which includes the establishment of 40-meter and 13-meter radio telescopes. Possible locations have been narrowed down to three candidates, situated in the Northern part of Thailand, where the atmosphere is sufficiently dry and suitable for 22 and 43 GHz observations. The Radio Frequency Interference (RFI) measurements were carried out with a DC spectrum analyzer and directional antennas at 1.5 meter above ground, from 20 MHz to 6 GHz with full azimuth coverage. The data from a 3-minute pointing were recorded for both horizontal and vertical polarizations, in maxhold and average modes. The results, for which we used to make preliminary site selection, show signals from typical broadcast and telecommunication services and aeronautics applications. The signal intensity varies accordingly to the presence of nearby population and topography of the region.
Dawood, M K; Liew, T H; Lianto, P; Hong, M H; Tripathy, S; Thong, J T L; Choi, W K
2010-05-21
We report a simple and cost effective method for the synthesis of large-area, precisely located silicon nanocones from nanowires. The nanowires were obtained from our interference lithography and catalytic etching (IL-CE) method. We found that porous silicon was formed near the Au catalyst during the fabrication of the nanowires. The porous silicon exhibited enhanced oxidation ability when exposed to atmospheric conditions or in wet oxidation ambient. Very well located nanocones with uniform sharpness resulted when these oxidized nanowires were etched in 10% HF. Nanocones of different heights were obtained by varying the doping concentration of the silicon wafers. We believe this is a novel method of producing large-area, low cost, well defined nanocones from nanowires both in terms of the control of location and shape of the nanocones. A wide range of potential applications of the nanocone array can be found as a master copy for nanoimprinted polymer substrates for possible biomedical research; as a candidate for making sharp probes for scanning probe nanolithography; or as a building block for field emitting tips or photodetectors in electronic/optoelectronic applications.
Atmospheric changes caused by galactic cosmic rays over the period 1960-2010
NASA Astrophysics Data System (ADS)
Jackman, Charles H.; Marsh, Daniel R.; Kinnison, Douglas E.; Mertens, Christopher J.; Fleming, Eric L.
2016-05-01
The Specified Dynamics version of the Whole Atmosphere Community Climate Model (SD-WACCM) and the Goddard Space Flight Center two-dimensional (GSFC 2-D) models are used to investigate the effect of galactic cosmic rays (GCRs) on the atmosphere over the 1960-2010 time period. The Nowcast of Atmospheric Ionizing Radiation for Aviation Safety (NAIRAS) computation of the GCR-caused ionization rates are used in these simulations. GCR-caused maximum NOx increases of 4-15 % are computed in the Southern polar troposphere with associated ozone increases of 1-2 %. NOx increases of ˜ 1-6 % are calculated for the lower stratosphere with associated ozone decreases of 0.2-1 %. The primary impact of GCRs on ozone was due to their production of NOx. The impact of GCRs varies with the atmospheric chlorine loading, sulfate aerosol loading, and solar cycle variation. Because of the interference between the NOx and ClOx ozone loss cycles (e.g., the ClO + NO2+ M → ClONO2+ M reaction) and the change in the importance of ClOx in the ozone budget, GCRs cause larger atmospheric impacts with less chlorine loading. GCRs also cause larger atmospheric impacts with less sulfate aerosol loading and for years closer to solar minimum. GCR-caused decreases of annual average global total ozone (AAGTO) were computed to be 0.2 % or less with GCR-caused column ozone increases between 1000 and 100 hPa of 0.08 % or less and GCR-caused column ozone decreases between 100 and 1 hPa of 0.23 % or less. Although these computed ozone impacts are small, GCRs provide a natural influence on ozone and need to be quantified over long time periods. This result serves as a lower limit because of the use of the ionization model NAIRAS/HZETRN which underestimates the ion production by neglecting electromagnetic and muon branches of the cosmic ray induced cascade. This will be corrected in future works.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ferguson, Jill Wisnewski
2006-01-01
The inductively coupled plasma (ICP) is an atmospheric pressure ionization source. Traditionally, the plasma is sampled via a sampler cone. A supersonic jet develops behind the sampler, and this region is pumped down to a pressure of approximately one Torr. A skimmer cone is located inside this zone of silence to transmit ions into the mass spectrometer. The position of the sampler and skimmer cones relative to the initial radiation and normal analytical zones of the plasma is key to optimizing the useful analytical signal [1]. The ICP both atomizes and ionizes the sample. Polyatomic ions form through ion-molecule interactionsmore » either in the ICP or during ion extraction [l]. Common polyatomic ions that inhibit analysis include metal oxides (MO +), adducts with argon, the gas most commonly used to make up the plasma, and hydride species. While high resolution devices can separate many analytes from common interferences, this is done at great cost in ion transmission efficiency--a loss of 99% when using high versus low resolution on the same instrument [2]. Simple quadrupole devices, which make up the bulk of ICP-MS instruments in existence, do not present this option. Therefore, if the source of polyatomic interferences can be determined and then manipulated, this could potentially improve the figures of merit on all ICP-MS devices, not just the high resolution devices often utilized to study polyatomic interferences.« less
Imaging Multi-Order Fabry-Perot Spectrometer (IMOFPS) for spaceborne measurements of CO
NASA Astrophysics Data System (ADS)
Johnson, Brian R.; Kampe, Thomas U.; Cook, William B.; Miecznik, Grzegorz; Novelli, Paul C.; Snell, Hilary E.; Turner-Valle, Jennifer A.
2003-11-01
An instrument concept for an Imaging Multi-Order Fabry-Perot Spectrometer (IMOFPS) has been developed for measuring tropospheric carbon monoxide (CO) from space. The concept is based upon a correlation technique similar in nature to multi-order Fabry-Perot (FP) interferometer or gas filter radiometer techniques, which simultaneously measure atmospheric emission from several infrared vibration-rotation lines of CO. Correlation techniques provide a multiplex advantage for increased throughput, high spectral resolution and selectivity necessary for profiling tropospheric CO. Use of unconventional multilayer interference filter designs leads to improvement in CO spectral line correlation compared with the traditional FP multi-order technique, approaching the theoretical performance of gas filter correlation radiometry. In this implementation, however, the gas cell is replaced with a simple, robust solid interference filter. In addition to measuring CO, the correlation filter technique can be applied to measurements of other important gases such as carbon dioxide, nitrous oxide and methane. Imaging the scene onto a 2-D detector array enables a limited range of spectral sampling owing to the field-angle dependence of the filter transmission function. An innovative anamorphic optical system provides a relatively large instrument field-of-view for imaging along the orthogonal direction across the detector array. An important advantage of the IMOFPS concept is that it is a small, low mass and high spectral resolution spectrometer having no moving parts. A small, correlation spectrometer like IMOFPS would be well suited for global observations of CO2, CO, and CH4 from low Earth or regional observations from Geostationary orbit. A prototype instrument is in development for flight demonstration on an airborne platform with potential applications to atmospheric chemistry, wild fire and biomass burning, and chemical dispersion monitoring.
NASA Astrophysics Data System (ADS)
Feng, Juan; Chen, Wen
2014-03-01
The variability of the East Asian winter monsoon (EAWM) can be divided into an ENSO-related part (EAWMEN) and an ENSO-unrelated part (EAWMres). The influence of EAWMres on the ENSO-East Asian summer monsoon (EASM) relationship in the decaying stages of ENSO is investigated in the present study. To achieve this, ENSO is divided into four groups based on the EAWMres: (1) weak EAWMres-El Niño (WEAWMres-EN); (2) strong EAWMres-El Niño (SEAWMres- EN); (3) weak EAWMres-La Niña (WEAWMres-LN); (4) strong EAWMres-La Niña (SEAWMres-LN). Composite results demonstrate that the EAWMres may enhance the atmospheric responses over East Asia to ENSO for WEAWMres-EN and SEAWMres-LN. The corresponding low-level anticyclonic (cyclonic) anomalies over the western North Pacific (WNP) associated with El Niño (La Niña) tend to be strong. Importantly, this feature may persist into the following summer, causing abundant rainfall in northern China for WEAWMres-EN cases and in southwestern China for SEAWMres-LN cases. In contrast, for the SEAWMres-EN and WEAWMres-LN groups, the EAWMres tends to weaken the atmospheric circulation anomalies associated with El Niño or La Niña. In these cases, the anomalous WNP anticyclone or cyclone tend to be reduced and confined to lower latitudes, which results in deficient summer rainfall in northern China for SEAWMres-EN and in southwestern China for WEAWMres-LN. Further study suggests that anomalous EAWMres may have an effect on the extra-tropical sea surface temperature anomaly, which persists into the ensuing summer and may interfere with the influences of ENSO.
Pollutant Plume Dispersion in the Atmospheric Boundary Layer over Idealized Urban Roughness
NASA Astrophysics Data System (ADS)
Wong, Colman C. C.; Liu, Chun-Ho
2013-05-01
The Gaussian model of plume dispersion is commonly used for pollutant concentration estimates. However, its major parameters, dispersion coefficients, barely account for terrain configuration and surface roughness. Large-scale roughness elements (e.g. buildings in urban areas) can substantially modify the ground features together with the pollutant transport in the atmospheric boundary layer over urban roughness (also known as the urban boundary layer, UBL). This study is thus conceived to investigate how urban roughness affects the flow structure and vertical dispersion coefficient in the UBL. Large-eddy simulation (LES) is carried out to examine the plume dispersion from a ground-level pollutant (area) source over idealized street canyons for cross flows in neutral stratification. A range of building-height-to-street-width (aspect) ratios, covering the regimes of skimming flow, wake interference, and isolated roughness, is employed to control the surface roughness. Apart from the widely used aerodynamic resistance or roughness function, the friction factor is another suitable parameter that measures the drag imposed by urban roughness quantitatively. Previous results from laboratory experiments and mathematical modelling also support the aforementioned approach for both two- and three-dimensional roughness elements. Comparing the UBL plume behaviour, the LES results show that the pollutant dispersion strongly depends on the friction factor. Empirical studies reveal that the vertical dispersion coefficient increases with increasing friction factor in the skimming flow regime (lower resistance) but is more uniform in the regimes of wake interference and isolated roughness (higher resistance). Hence, it is proposed that the friction factor and flow regimes could be adopted concurrently for pollutant concentration estimate in the UBL over urban street canyons of different roughness.
NASA Technical Reports Server (NTRS)
Whiteman, David N.; Venable, Demetrius D.; Walker, Monique; Cardirola, Martin; Sakai, Tetsu; Veselovskii, Igor
2013-01-01
Narrow-band detection of the Raman water vapor spectrum using the lidar technique introduces a concern over the temperature dependence of the Raman spectrum. Various groups have addressed this issue either by trying to minimize the temperature dependence to the point where it can be ignored or by correcting for whatever degree of temperature dependence exists. The traditional technique for performing either of these entails accurately measuring both the laser output wavelength and the water vapor spectral passband with combined uncertainty of approximately 0.01 nm. However, uncertainty in interference filter center wavelengths and laser output wavelengths can be this large or larger. These combined uncertainties translate into uncertainties in the magnitude of the temperature dependence of the Raman lidar water vapor measurement of 3% or more. We present here an alternate approach for accurately determining the temperature dependence of the Raman lidar water vapor measurement. This alternate approach entails acquiring sequential atmospheric profiles using the lidar while scanning the channel passband across portions of the Raman water vapor Q-branch. This scanning is accomplished either by tilt-tuning an interference filter or by scanning the output of a spectrometer. Through this process a peak in the transmitted intensity can be discerned in a manner that defines the spectral location of the channel passband with respect to the laser output wavelength to much higher accuracy than that achieved with standard laboratory techniques. Given the peak of the water vapor signal intensity curve, determined using the techniques described here, and an approximate knowledge of atmospheric temperature, the temperature dependence of a given Raman lidar profile can be determined with accuracy of 0.5% or better. A Mathematica notebook that demonstrates the calculations used here is available from the lead author.
Neutral Poly-/perfluoroalkyl Substances in Air and Snow from the Arctic
Xie, Zhiyong; Wang, Zhen; Mi, Wenying; Möller, Axel; Wolschke, Hendrik; Ebinghaus, Ralf
2015-01-01
Levels of neutral poly-/perfluoroalkyl substances (nPFASs) in air and snow collected from Ny-Ålesund were measured and their air-snow exchange was determined to investigate whether they could re-volatilize into the atmosphere driven by means of air-snow exchange. The total concentration of 12 neutral PFASs ranged from 6.7 to 39 pg m−3 in air and from 330 to 690 pg L−1 in snow. A significant log-linear relationship was observed between the gas/particle partition coefficient and vapor pressure of the neutral PFASs. For fluorotelomer alcohol (FTOHs) and fluorotelomer acrylates (FTAs), the air-snow exchange fluxes were positive, indicating net evaporative from snow into air, while net deposition into snow was observed for perfluorooctane sulfonamidoethanols (Me/EtFOSEs) in winter and spring of 2012. The air-snow exchange was snow-phase controlled for FTOHs and FTAs, and controlled by the air-phase for FOSEs. Air-snow exchange may significantly interfere with atmospheric concentrations of neutral PFASs in the Arctic. PMID:25746440
NASA Astrophysics Data System (ADS)
Schmidt, Jacob B.; Sands, Brian; Scofield, James; Gord, James R.; Roy, Sukesh
2017-05-01
Absolute number densities of atomic species produced by nanosecond (ns)-duration, repetitively pulsed electric discharges are measured by two-photon-absorption laser-induced fluorescence (TALIF). Unique to this work is the development of femtosecond-laser-based TALIF (fs-TALIF) that offers a number of advantages over more conventional nanosecond (ns)-pulse-duration laser techniques, such as higher-fidelity quenching rate measurements over a wide pressure range, significantly reduced photolytic interference (including photo-dissociation and photo-ionization), ability to collect two-dimensional images of atomic-species number densities with high spatial resolution aided by higher signal level, and efficient and accurate measurements of atomic-species number densities due to the higher repetition rates of the laser. For full quantification of these advantages, atomic-oxygen TALIF signals are collected from an atmospheric-pressure plasma jet employing both ns- and fs-duration laser-excitation pulses and the results are compared and contrasted.
NASA Astrophysics Data System (ADS)
Ruggles, Adam; Pickett, Lyle; Frank, Jonathan
2014-11-01
Many real world combustion devices model fuel scalar mixing by assuming the self-similar argument established in atmospheric free jets. This allows simple prediction of the mean and rms fuel scalar fields to describe the mixing. This approach has been adopted in super critical liquid injections found in diesel engines where the liquid behaves as a dense fluid. The effect of pressure ratio (injection to ambient) when the ambient is greater than atmospheric pressure, upon the self-similar collapse has not been well characterized, particularly the effect upon mixing constants, jet spreading rates, and virtual origins. Changes in these self-similar parameters control the reproduction of the scalar mixing statistics. This experiment investigates the steady state mixing of high pressure ethylene jets in a pressurized pure nitrogen environment for various pressure ratios and jet orifice diameters. Quantitative laser Rayleigh scattering imaging was performed utilizing a calibration procedure to account for the pressure effects upon scattering interference within the high-pressure vessel.
Detection of NO sub x,C2H4 concentrations by using CO and CO2 lasers
NASA Technical Reports Server (NTRS)
Gengchen, W.; Qinxin, K.
1986-01-01
A laser, especially the infrared line tunable laser, opens up a new way to monitor the atmospheric environment, and already has gotten effective practical application. One of the most serious problems in open path remote measurement at atmospheric pressure is the broadening effect which leads to increased linewidths, spectral interferences, and, as a result, tends to reduce detection sensitivity, so measuring laser wavelengths should be selected carefully, and interaction between the measuring wavelength and gas to be measured must be known very well. Therefore, N2O, No, NO2, CH4, NH3 and C2H4 absorption properties at some lines of CO and CO2 line tunable lasers were studied. The absorption coefficients of NO, NO2, and C2H4; some results on detection of NO sub x, C2H4 concentrations in both laboratory and field; and selection of measuring wavelengths and error analysis are discussed.
NASA Technical Reports Server (NTRS)
Yamanaka, M. D.
1989-01-01
In MAP observations, it was found that: (1) gravity waves in selected or filtered portions of data are fit for monochromatic structures, whereas (2) those in fully continuous and resolved observations take universal continuous spectra. It is possible to explain (2) by dispersion of quasi-monochromatic (or slowly varying) wave packets observed locally as (1), since the medium atmosphere is unsteady and nonuniform. Complete verification of the wave-mean flow interactions by tracking individual wave packets seems hopeless, because the wave induced flow cannot be distinguished from the basic flow independent of the waves. Instead, the primitive picture is looked at before MAP, that is, the atmosphere is just like an entertainment stage illuminated by cocktail lights of quasi-monochromatic gravity waves. The wave parameters are regarded as functions of time and spatial coordinates. The observational evidences (1) and (2) suggest that the wave parameter field is rather homogeneous, which can be explained by interference of quasi-monochromatic wave packets.
Evaluation of new laser spectrometer techniques for in-situ carbon monoxide measurements
NASA Astrophysics Data System (ADS)
Zellweger, C.; Steinbacher, M.; Buchmann, B.
2012-10-01
Long-term time series of the atmospheric composition are essential for environmental research and thus require compatible, multi-decadal monitoring activities. The current data quality objectives of the World Meteorological Organization (WMO) for carbon monoxide (CO) in the atmosphere are very challenging to meet with the measurement techniques that have been used until recently. During the past few years, new spectroscopic techniques came to market with promising properties for trace gas analytics. The current study compares three instruments that have recently become commercially available (since 2011) with the best currently available technique (Vacuum UV Fluorescence) and provides a link to previous comparison studies. The instruments were investigated for their performance regarding repeatability, reproducibility, drift, temperature dependence, water vapour interference and linearity. Finally, all instruments were examined during a short measurement campaign to assess their applicability for long-term field measurements. It could be shown that the new techniques perform considerably better compared to previous techniques, although some issues, such as temperature influence and cross sensitivities, need further attention.
Proposal Drafted for Allocating Space-to-Space Frequencies in the GPS Spectrum Bands
NASA Technical Reports Server (NTRS)
Spence, Rodney L.
2000-01-01
Radionavigation Satellite Service (RNSS) systems such as the U.S. Global Positioning System (GPS) and the Russian Global Navigation Satellite System (GLONASS) are primarily being used today in the space-to-Earth direction (i.e., from GPS satellite to Earth user) for a broad range of applications such as geological surveying; aircraft, automobile, and maritime navigation; hiking and mountain climbing; and precision farming and mining. However, these navigation systems are being used increasingly in space. Beginning with the launch of the TOPEX/Poseidon remote-sensing mission in 1992, over 90 GPS receivers have flown onboard spacecraft for such applications as real-time spacecraft navigation, three-axis attitude control, precise time synchronization, precision orbit determination, and atmospheric profiling. In addition to use onboard many science spacecraft, GPS has been used or is planned to be used onboard the shuttles, the International Space Station, the International Space Station Emergency Crew Return Vehicle, and many commercial satellite systems such as Orbcomm, Globalstar, and Teledesic. From a frequency spectrum standpoint, however, one important difference between the space and terrestrial uses of GPS is that it is being used in space with no interference protection. This is because there is no frequency allocation for the space-to-space use of GPS (i.e., from GPS satellite to user spacecraft) in the International Telecommunications Union (ITU) regulatory table of frequency allocations. If another space-based or groundbased radio system interferes with a spaceborne GPS user, the spaceborne user presently has no recourse other than to accept the interference. Consequently, for the past year and a half, the NASA Glenn Research Center at Lewis Field and other Government agencies have been working within ITU toward obtaining a GPS space-to-space allocation at the next World Radio Conference in the year 2000 (WRC 2000). Numerous interference studies have been conducted in support of a primary space-tospace allocation in the 1215- to 1260-MHz and 1559- to 1610-MHz RNSS bands. Most of these studies and analyses were performed by Glenn and submitted as U.S. input documents to the international Working Party 8D meetings in Geneva, Switzerland. In the structure of the ITU, Working Party 8D is responsible for frequency spectrum issues in the RNSS and the mobile satellite service (MSS). The full texts of the studies are available from the ITU web site under Working Party 8D contributions. Note that because spaceborne RNSS receivers operate in a receive-only mode with navigation signals already being broadcast toward the Earth, the addition of a space-tospace allocation will not result in interference with other systems. A space-based RNSS receiver, however, could experience interference from systems of other services, including intraservice interference from other RNSS systems. The interference scenarios examined in the studies can be inferred from the following frequency allocation charts. In these charts, services labeled in all capital letters (e.g., "ARNS") have primary status, whereas those labeled with sentence-style capitalization (e.g., "Amateur radio") have secondary status (i.e., a service with secondary status cannot claim interference protection from or cause harmful interference to a service with primary status). Charts showing the ITU frequency allocations in the 960 to 1350 MHZ range and the 1525-1660 MHZ range are discussed and presented.
Development of a Test Protocol for Spacecraft Post-Fire Atmospheric Cleanup and Monitoring
NASA Technical Reports Server (NTRS)
Zuniga, David; Hornung, Steven D.; Haas, Jon P.; Graf, John C.
2009-01-01
Detecting and extinguishing fires, along with post-fire atmospheric cleaning and monitoring, are vital components of a spacecraft fire response system. Preliminary efforts focused on the technology evaluation of these systems under realistic conditions are described in this paper. While the primary objective of testing is to determine a smoke mitigation filter s performance, supplemental evaluations measuring the smoke-filled chamber handheld commercial off-the-shelf (COTS) atmospheric monitoring devices (combustion product monitors) are also conducted. The test chamber consists of a 1.4 cubic meter (50 cu. ft.) volume containing a smoke generator. The fuel used to generate the smoke is a mixture of polymers in quantities representative of materials involved in a circuit board fire as a typical spacecraft fire. Two fire conditions were examined: no flame and flame. No flame events are produced by pyrolyzing the fuel mixture in a quartz tube furnace with forced ventilation to produce a white, lingering-type smoke. Flame events ignite the smoke at the outlet of the tube furnace producing combustion characterized by a less opaque smoke with black soot. Electrochemical sensor measurements showed carbon monoxide is a major indicator of each fire. Acid gas measurements were recorded, but cross interferents are currently uncharacterized. Electrochemical sensor measurements and sample acquisition techniques from photoacoustic sensors are being improved. Overall, this research shows fire characterization using traditional analytical chemistry techniques is required to verify measurements recorded using COTS atmospheric monitoring devices.
Atmospheric H2O2 measurement: comparison of cold trap method with impinger bubbling method
NASA Technical Reports Server (NTRS)
Sakugawa, H.; Kaplan, I. R.
1987-01-01
Collection of atmospheric H2O2 was performed by a cold trap method using dry ice-acetone as the refrigerant. The air was drawn by a pump into a glass gas trap immersed in the dry ice-acetone slush in a dewar flask at a flow rate of 2.5 l min-1 for approximately 2 h. Collection efficiency was > 99% and negligible interferences by O3, SO2 or organic matter with the collected H2O2 in the trap were observed. This method was compared with the air impinger bubbling method which has been previously described (Kok et al., 1978a, b, Envir. Sci. Technol. 12, 1072-1080). The measured total peroxide (H2O2 + organic peroxide) values in a series of aim samples collected by the impinger bubbling method (0.06-3.7 ppb) were always higher than those obtained by the cold trap method (0.02-1.2 ppb). Laboratory experiments suggest that the difference in values between the two methods probably results from the aqueous phase generation of H2O2 and organic peroxide in the impinger solution by a reaction of atmospheric O3 with olefinic and aromatic compounds. If these O3-organic compound reactions which occur in the impinger also occur in aqueous droplets in the atmosphere, the process could be very important for aqueous phase generation of H2O2 in clouds and rainwater.
Wab-InSAR: a new wavelet based InSAR time series technique applied to volcanic and tectonic areas
NASA Astrophysics Data System (ADS)
Walter, T. R.; Shirzaei, M.; Nankali, H.; Roustaei, M.
2009-12-01
Modern geodetic techniques such as InSAR and GPS provide valuable observations of the deformation field. Because of the variety of environmental interferences (e.g., atmosphere, topography distortion) and incompleteness of the models (assumption of the linear model for deformation), those observations are usually tainted by various systematic and random errors. Therefore we develop and test new methods to identify and filter unwanted periodic or episodic artifacts to obtain accurate and precise deformation measurements. Here we present and implement a new wavelet based InSAR (Wab-InSAR) time series approach. Because wavelets are excellent tools for identifying hidden patterns and capturing transient signals, we utilize wavelet functions for reducing the effect of atmospheric delay and digital elevation model inaccuracies. Wab-InSAR is a model free technique, reducing digital elevation model errors in individual interferograms using a 2D spatial Legendre polynomial wavelet filter. Atmospheric delays are reduced using a 3D spatio-temporal wavelet transform algorithm and a novel technique for pixel selection. We apply Wab-InSAR to several targets, including volcano deformation processes at Hawaii Island, and mountain building processes in Iran. Both targets are chosen to investigate large and small amplitude signals, variable and complex topography and atmospheric effects. In this presentation we explain different steps of the technique, validate the results by comparison to other high resolution processing methods (GPS, PS-InSAR, SBAS) and discuss the geophysical results.
NASA Astrophysics Data System (ADS)
Li, Bicen; Xu, Pengmei; Hou, Lizhou; Wang, Caiqin
2017-10-01
Taking the advantages of high spectral resolution, high sensitivity and wide spectral coverage, space borne Fourier transform infrared spectrometer (FTS) plays more and more important role in atmospheric composition sounding. The combination of solar occultation and FTS technique improves the sensitivity of instrument. To achieve both high spectral resolution and high signal to noise ratio (SNR), reasonable allocation and optimization for instrument parameters are the foundation and difficulty. The solar occultation FTS (SOFTS) is a high spectral resolution (0.03 cm-1) FTS operating from 2.4 to 13.3 μm (750-4100cm-1), which will determine the altitude profile information of typical 10-100km for temperature, pressure, and the volume mixing ratios for several dozens of atmospheric compositions. As key performance of SOFTS, SNR is crucially important to high accuracy retrieval of atmospheric composition, which is required to be no less than 100:1 at the radiance of 5800K blackbody. Based on the study of various parameters and its interacting principle, according to interference theory and operation principle of time modulated FTS, a simulation model of FTS SNR has been built, which considers satellite orbit, spectral radiometric features of sun and atmospheric composition, optical system, interferometer and its control system, measurement duration, detector sensitivity, noise of detector and electronic system and so on. According to the testing results of SNR at the illuminating of 1000 blackbody, the on-orbit SNR performance of SOFTS is estimated, which can meet the mission requirement.
A silicone column for GC analysis of polar and nonpolar chemicals
NASA Technical Reports Server (NTRS)
Shen, T. C.
1991-01-01
The investigation of the Saturnian System is being proposed jointly by NASA and the European Space Agency (ESA). The mission is scheduled for a launch in 1996. The mission provides an opportunity for close observation and exploration of Saturn's atmosphere, the complex Saturnian System of satellites and rings, Titan (Saturn's planet-sized moon), and Saturn's magnetosphere. The mission gives special attention to Titan which is blanketed by a thick, opaque atmosphere. An atmospheric probe will be deposited into the Titan Atmosphere for in situ measurement during a slow, three hour descent to the surface. The results from this analysis may provide the information which is important to the research of chemical evolution, and the origin of life. An analytical system was developed as a part of the Titan Aerosol Gas Experiment (TAGEX), a proposed experiment for the Cassini Mission. This system will use two highly sensitive detectors, the Metastable Ionization Detector (MID) and the Ion Mobility Spectrometer (IMS). Unfortunately, when commercial columns are utilized with these highly sensitive detectors, volatile components continuously bleed from the column and interfere with the detector. In addition, light columns must be able to separate polar and nonpolar organic chemicals within 10-15 minutes under isothermal conditions for the Titan Mission. Therefore, a highly crosslinked silicone polymeric packed column was developed which is able to efficiently separate amines, alcohols, and hydrocarbons with retention times less that 15 minutes at 100 C isothermal condition.
NASA Technical Reports Server (NTRS)
Uthe, Edward E.
1990-01-01
SRI has assembled an airborne lidar/radiometric instrumentation suite for mapping cirrus cloud distribution and analyzing cirrus cloud optical properties. Operation of upward viewing infrared radiometers from an airborne platform provides the optimum method of measuring high altitude cold cloud radiative properties with minimum interference from the thermal emission by the earth's surface and lower atmospheric components. Airborne installed sensors can also operate over large regional areas including water, urban, and mountain surfaces and above lower atmospheric convective clouds and haze layers. Currently available sensors installed on the SRI Queen Air aircraft are illustrated. Lidar and radiometric data records are processed for real time viewing on a color video screen. A cirrus cloud data example is presented as a black and white reproduction of a color display of data at the aircraft altitude of 12,000 ft, the 8 to 14 micron atmospheric radiation background was equivalent to a blackbody temperature of about -60 C and, therefore, the radiometer did not respond strongly to low density cirrus cloud concentrations detected by the lidar. Cloud blackbody temperatures (observed by radiometer) are shown plotted against midcloud temperatures (derived from lidar observed cloud heights and supporting temperature profiles) for data collected on 30 June and 28 July.
Feasibility assessment of optical technologies for reliable high capacity feeder links
NASA Astrophysics Data System (ADS)
Witternigg, Norbert; Schönhuber, Michael; Leitgeb, Erich; Plank, Thomas
2013-08-01
Space telecom scenarios like data relay satellite and broadband/broadcast service providers require reliable feeder links with high bandwidth/data rate for the communication between ground station and satellite. Free space optical communication (FSOC) is an attractive alternative to microwave links, improving performance by offering abundant bandwidth at small apertures of the optical terminals. At the same time Near-Earth communication by FSOC avoids interference with other services and is free of regulatory issues. The drawback however is the impairment by the laser propagation through the atmosphere at optical wavelengths. Also to be considered are questions of eye safety for ground personnel and aviation. In this paper we assess the user requirements for typical space telecom scenarios and compare these requirements with solutions using optical data links through the atmosphere. We suggest a site diversity scheme with a number of ground stations and a switching scheme using two optical terminals on-board the satellite. Considering the technology trade-offs between four different optical wavelengths we recommend the future use of 1.5 μm laser technology and calculate a link budget for an atmospheric condition of light haze on the optical path. By comparing link budgets we show an outlook to the future potential use of 10 μm laser technology.
Air-sampling inlet contamination by aircraft emissions on the NASA CV-990 aircraft
NASA Technical Reports Server (NTRS)
Condon, E. P.; Vedder, J. F.
1984-01-01
Results of an experimental investigation of the contamination of air sampling inlets by aircraft emissions from the NASA CV-990 research aircraft are presented. This four-engine jet aircraft is a NASA facility used for many different atmospheric and meteorological experiments, as well as for developing spacecraft instrumentation for remote measurements. Our investigations were performed to provide information on which to base the selection of sampling locations for a series of multi-instrument missions for measuring tropospheric trace gases. The major source of contamination is the exhaust from the jet engines, which generate many of the same gases that are of interest in atmospheric chemistry, as well as other gases that may interfere with sampling measurements. The engine exhaust contains these gases in mixing ratios many orders of magnitude greater than those that occur in the clean atmosphere which the missions seek to quantify. Pressurized samples of air were collected simultaneously from a scoop located forward of the engines to represent clean air and from other multiport scoops at various aft positions on the aircraft. The air samples were analyzed in the laboratory by gas chromatography for carbon monoxide, an abundant combustion by-product. Data are presented for various scoop locations under various flight conditions.
Gravity wave vertical energy flux at 95 km
NASA Technical Reports Server (NTRS)
Jacob, P. G.; Jacka, F.
1985-01-01
A three-field photometer (3FP) located at Mt. Torrens near Adelaide, is capable of monitoring different airglow emissions from three spaced fields in the sky. A wheel containing up to six different narrow bandpass interference filters can be rotated, allowing each of the filters to be sequentially placed into each of the three fields. The airglow emission of interest is the 557.7 nm line which has an intensity maximum at 95 km. Each circular field of view is located at the apexes of an equilateral triangle centered on zenith with diameters of 5 km and field separations of 13 km when projected to the 95-km level. The sampling period was 30 seconds and typical data lengths were between 7 and 8 hours. The analysis and results from the interaction of gravity waves on the 557.7 nm emission layer are derived using an atmospheric model similar to that proposed by Hines (1960) where the atmosphere is assumed isothermal and perturbations caused by gravity waves are small and adiabatic, therefore, resulting in linearized equations of motion. In the absence of waves, the atmosphere is also considered stationary. Thirteen nights of quality data from January 1983 to October 1984, covering all seasons, are used in this analysis.
Ostashev, Vladimir E; Wilson, D Keith; Muhlestein, Michael B; Attenborough, Keith
2018-02-01
Although sound propagation in a forest is important in several applications, there are currently no rigorous yet computationally tractable prediction methods. Due to the complexity of sound scattering in a forest, it is natural to formulate the problem stochastically. In this paper, it is demonstrated that the equations for the statistical moments of the sound field propagating in a forest have the same form as those for sound propagation in a turbulent atmosphere if the scattering properties of the two media are expressed in terms of the differential scattering and total cross sections. Using the existing theories for sound propagation in a turbulent atmosphere, this analogy enables the derivation of several results for predicting forest acoustics. In particular, the second-moment parabolic equation is formulated for the spatial correlation function of the sound field propagating above an impedance ground in a forest with micrometeorology. Effective numerical techniques for solving this equation have been developed in atmospheric acoustics. In another example, formulas are obtained that describe the effect of a forest on the interference between the direct and ground-reflected waves. The formulated correspondence between wave propagation in discrete and continuous random media can also be used in other fields of physics.
The Influence of Trace Gases Absorption on Differential Ring Cross Sections
NASA Astrophysics Data System (ADS)
Han, Dong; Zhao, Keyi
2017-04-01
The Ring effect refers to the filling in of Fraunhofer lines, which is known as solar absorption lines, caused almost entirely by rotational Raman scattering. The rotational Raman scattering by N2 and O2 in the atmosphere is the main factor that leads to Ring effect. The Ring effect is one significant limitation to the accuracy of the retrieval of trace gas constituents in atmosphere, while using satellite data with Differential Optical Absorption Spectroscopy technique. In this study, firstly the solar spectrum is convolved with rotational Raman cross sections of atmosphere, which is calculated with rotational Raman cross sections of N2 and O2, divided by the original solar spectrum, with a cubic polynomial subtracted off, to create differential Ring spectrum Ring1. Secondly, the Ring effect for pure Raman scattering of the Fraunhofer spectrum plus the contribution from interference by terrestrial absorption which always comes from a kind of trace gas (e.g., O3) are derived. To allow for more generality, the optically thin term as well as the next term in the expansion for the Beer-Lambert law are calculated.Ring1, Ring2, and Ring3are the Fraunhofer only, 1st terrestrial correction, and 2nd terrestrial correction for DOAS fitting.
Free-surface microfluidics for detection of airborne explosives
NASA Astrophysics Data System (ADS)
Meinhart, Carl; Piorek, Brian; Banerjee, Sanjoy; Lee, Seung Joon; Moskovits, Martin
2008-11-01
A novel microfluidic, remote-sensing, chemical detection platform has been developed for real-time sensing of airborne agents. The key enabling technology is a newly developed concept termed Free-Surface Fluidics (FSF), where one or more fluidic surfaces of a microchannel flow are confined by surface tension and exposed to the surrounding atmosphere. The result is a unique open channel flow environment that is driven by pressure through surface tension, and not subject to body forces, such as gravity. Evaporation and flow rates are controlled by microchannel geometry, surface chemistry and precisely-controlled temperature profiles. The free-surface fluidic architecture is combined with Surface-Enhanced Raman Spectroscopy (SERS) to allow for real-time profiling of atmospheric species and detection of airborne agents. The aggregation of SERS nanoparticles is controlled using microfluidics, to obtain dimer nanoparticle clusters at known streamwise positions in the microchannel. These dimers form SERS hot-spots, which amplify the Raman signal by 8 -- 10 orders of magnitude. Results indicate that explosive agents such as DNT, TNT, RDX, TATP and picric acid in the surrounding atmosphere can be readily detected by the SERS system. Due to the amplification of the SERS system, explosive molecules with concentrations of parts per trillion can be detected, even in the presence of interferent molecules having six orders of magnitude higher concentration.
Light pollution generated by laser guide star at Canarian Observatories
NASA Astrophysics Data System (ADS)
Chueca, Sergio; Fuensalida, Jesus J.
2004-11-01
A new generation of instrument using a launching laser is been developed to correct the atmospheric image blurring and to establish optical communication with space. Then, light pollution generated by laser will be a serious operational problem in next years. This laser could affect astronomical works of adjacent telescopes when the laser lay across the field of view of the observing telescope, this is a kind of light pollution. This could be avoided with an adequate operational politic to detect possible interference between the laser and the astronomical telescopes. In this paper is analysed the mathematical probability of a cross-event happen.
Ultrafast laser control of backward superfluorescence towards standoff sensing
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ariunbold, Gombojav O.; National University of Mongolia, Ulaanbaatar 210646; Baylor University, Waco, Texas 76798
2014-01-13
We study infrared backward cooperative emission in a rubidium vapor induced by ultrafast two-photon optical excitations. The laser coherent control of the backward emission is demonstrated by using a pair of 100 fs pulses with a variable time delay. The temporal variation (quantum beat) of the backward beam intensity due to interference of atomic transitions in the rubidium atomic level system 5S-5P-5D is produced and controlled. Based on the obtained experimental results, we discuss possible applications of the developed approach for creation of an effective “guide star” in the sodium atomic layer in the upper atmosphere (mesosphere)
Flight of a UV spectrophotometer aboard Galileo 2, the NASA Convair 990 aircraft
NASA Technical Reports Server (NTRS)
Sellers, B.; Hunderwadel, J. L.; Hanser, F. A.
1976-01-01
An ultraviolet interference-filter spectrophotometer (UVS) fabricated for aircraft-borne use on the DOT Climatic Impact Assessment Program (CIAP) has been successfully tested in a series of flights on the NASA Convair 990, Galileo II. UV flux data and the calculated total ozone above the flight path are reported for several of the flights. Good agreement is obtained with the total ozone as deducted by integration of an ozone sonde vertical profile obtained at Wallops Island, Virginia near the time of a CV-990 underpass. Possible advantages of use of the UVS in the NASA Global Atmospheric Sampling Program are discussed.
Morrissey, M A; Hill, H H
1989-09-01
A simplified procedure was developed for the determination of 2,4-dichlorophenoxyacetic acid (2,4-D) in soils. Soil samples were separated by supercritical fluid chromatography after extraction without derivatization and without the use of column chromatography for cleanup. Interferences in the chromatographic separation were eliminated by using a tunably selective ion mobility detector. An atmospheric pressure ion formed by the free acid was selectively monitored so the detector could monitor 2,4-D in the presence of other electron-capturing compounds. For a randomly chosen soil sample, the level of 2,4-D detected was estimated at 500 ppb.
NASA Astrophysics Data System (ADS)
McNeil, W. J.
1997-09-01
Metals in the Earth's atmosphere are of interest and importance for several reasons. Emission lines from the sodium layer are used for wave front corrections in imaging space objects. The ionospheric metals present background contamination for remote sensing and tracking of space- born objects. Ionization during meteor showers may also interfere with communications. Although it is generally accepted that extraterrestrial material is the source of metals in the atmospheric, the relative abundances of mesospheric metals and ions present us with a conundrum. Lidar observations have consistently shown that the abundances of neutral metals in the atmospheric and the abundances of these metals in the meteoric material that falls to earth are significantly disproportionate. For example, the column density of neutral sodium is perhaps two orders of magnitude larger than that of calcium, while the abundances in meteorites are approximately equal. To complicate matters further, ion mass spectroscopy has shown that the abundances of the meteoric ions match reasonably well those in the meteorites. We present here a model that attempts to address these discrepancies. At the heart of the model is the concept of differential ablation, which suggests that more volatile metals sublimate earlier in the descent of a cosmic dust particle than do the less volatile components. The modeling is carried out comprehensively, beginning with the heating and vaporization of the dust particles. The vaporization rate is computed as a function of altitude from an ensemble of particles to give a deposition function which is then injected into a fully time-dependent kinetic code which allows for vertical diffusion and includes diurnal dependence through both the models of the major atmospheric components and through transport of the ions due to electric fields.
Extracting Urban Morphology for Atmospheric Modeling from Multispectral and SAR Satellite Imagery
NASA Astrophysics Data System (ADS)
Wittke, S.; Karila, K.; Puttonen, E.; Hellsten, A.; Auvinen, M.; Karjalainen, M.
2017-05-01
This paper presents an approach designed to derive an urban morphology map from satellite data while aiming to minimize the cost of data and user interference. The approach will help to provide updates to the current morphological databases around the world. The proposed urban morphology maps consist of two layers: 1) Digital Elevation Model (DEM) and 2) land cover map. Sentinel-2 data was used to create a land cover map, which was realized through image classification using optical range indices calculated from image data. For the purpose of atmospheric modeling, the most important classes are water and vegetation areas. The rest of the area includes bare soil and built-up areas among others, and they were merged into one class in the end. The classification result was validated with ground truth data collected both from field measurements and aerial imagery. The overall classification accuracy for the three classes is 91 %. TanDEM-X data was processed into two DEMs with different grid sizes using interferometric SAR processing. The resulting DEM has a RMSE of 3.2 meters compared to a high resolution DEM, which was estimated through 20 control points in flat areas. Comparing the derived DEM with the ground truth DEM from airborne LIDAR data, it can be seen that the street canyons, that are of high importance for urban atmospheric modeling are not detectable in the TanDEM-X DEM. However, the derived DEM is suitable for a class of urban atmospheric models. Based on the numerical modeling needs for regional atmospheric pollutant dispersion studies, the generated files enable the extraction of relevant parametrizations, such as Urban Canopy Parameters (UCP).
NASA Astrophysics Data System (ADS)
Cuthbert, M. O.; Acworth, I. R.; Halloran, L. J. S.; Rau, G. C.; Bernadi, T. L.
2017-12-01
It has long been recognised that hydraulic properties can be derived from the response of piezometric heads to tidal loadings. However, there is a degree of subjectivity in existing graphical approaches most commonly used to calculate barometric efficiency leading to uncertainties in derived values of compressible storage. Here we demonstrate a novel approach to remove these uncertainties by objectively deriving the barometric efficiency from groundwater hydraulic head responses using a frequency domain method. We take advantage of the presence of worldwide and ubiquitous atmospheric tide fluctuations which occur at 2 cycles per day (cpd). First we use a Fourier transform to calculate the amplitudes of the 2 cpd signals from co-located atmospheric pressure and hydraulic head time series measurements. Next we show how the Earth tide response at the same frequency can be quantified and removed so that this effect does not interfere with the calculation of the barometric efficiency. Finally, the ratio of the amplitude of the response at 2 cpd of hydraulic head to atmospheric pressure is used to quantify the barometric efficiency. This new method allows an objective quantification using `passive' in situ monitoring rather than resorting to aquifer pumping or laboratory tests. The minimum data requirements are 15 days duration of 6-hourly hydraulic head and atmospheric pressure measurements, and modelled Earth tide records which are readily conducted using freely available software. The new approach allows for a rapid and cost-effective alternative to traditional methods of estimating aquifer compressible storage properties without the subjectivity of existing approaches, and will be of importance to improving the spatial coverage of subsurface characterisation for groundwater resource evaluation and land subsidence assessment.
Evaluation and attribution of OCO-2 XCO2 uncertainties
NASA Astrophysics Data System (ADS)
Worden, John R.; Doran, Gary; Kulawik, Susan; Eldering, Annmarie; Crisp, David; Frankenberg, Christian; O'Dell, Chris; Bowman, Kevin
2017-07-01
Evaluating and attributing uncertainties in total column atmospheric CO2 measurements (XCO2) from the OCO-2 instrument is critical for testing hypotheses related to the underlying processes controlling XCO2 and for developing quality flags needed to choose those measurements that are usable for carbon cycle science.Here we test the reported uncertainties of version 7 OCO-2 XCO2 measurements by examining variations of the XCO2 measurements and their calculated uncertainties within small regions (˜ 100 km × 10.5 km) in which natural CO2 variability is expected to be small relative to variations imparted by noise or interferences. Over 39 000 of these small neighborhoods
comprised of approximately 190 observations per neighborhood are used for this analysis. We find that a typical ocean measurement has a precision and accuracy of 0.35 and 0.24 ppm respectively for calculated precisions larger than ˜ 0.25 ppm. These values are approximately consistent with the calculated errors of 0.33 and 0.14 ppm for the noise and interference error, assuming that the accuracy is bounded by the calculated interference error. The actual precision for ocean data becomes worse as the signal-to-noise increases or the calculated precision decreases below 0.25 ppm for reasons that are not well understood. A typical land measurement, both nadir and glint, is found to have a precision and accuracy of approximately 0.75 and 0.65 ppm respectively as compared to the calculated precision and accuracy of approximately 0.36 and 0.2 ppm. The differences in accuracy between ocean and land suggests that the accuracy of XCO2 data is likely related to interferences such as aerosols or surface albedo as they vary less over ocean than land. The accuracy as derived here is also likely a lower bound as it does not account for possible systematic biases between the regions used in this analysis.
NASA Astrophysics Data System (ADS)
Chen, H.; Karion, A.; Rella, C. W.; Winderlich, J.; Gerbig, C.; Filges, A.; Newberger, T.; Sweeney, C.; Tans, P. P.
2013-04-01
Accurate measurements of carbon monoxide (CO) in humid air have been made using the cavity ring-down spectroscopy (CRDS) technique. The measurements of CO mole fractions are determined from the strength of its spectral absorption in the near-infrared region (~1.57 μm) after removing interferences from adjacent carbon dioxide (CO2) and water vapor (H2O) absorption lines. Water correction functions that account for the dilution and pressure-broadening effects as well as absorption line interferences from adjacent CO2 and H2O lines have been derived for CO2 mole fractions between 360-390 ppm and for reported H2O mole fractions between 0-4%. The line interference corrections are independent of CO mole fractions. The dependence of the line interference correction on CO2 abundance is estimated to be approximately -0.3 ppb/100 ppm CO2 for dry mole fractions of CO. Comparisons of water correction functions from different analyzers of the same type show significant differences, making it necessary to perform instrument-specific water tests for each individual analyzer. The CRDS analyzer was flown on an aircraft in Alaska from April to November in 2011, and the accuracy of the CO measurements by the CRDS analyzer has been validated against discrete NOAA/ESRL flask sample measurements made on board the same aircraft, with a mean difference between integrated in situ and flask measurements of -0.6 ppb and a standard deviation of 2.8 ppb. Preliminary testing of CRDS instrumentation that employs improved spectroscopic model functions for CO2, H2O, and CO to fit the raw spectral data (available since the beginning of 2012) indicates a smaller water vapor dependence than the models discussed here, but more work is necessary to fully validate the performance. The CRDS technique provides an accurate and low-maintenance method of monitoring the atmospheric dry mole fractions of CO in humid air streams.
A Novel Attitude Determination System Aided by Polarization Sensor
Zhi, Wei; Chu, Jinkui; Li, Jinshan; Wang, Yinlong
2018-01-01
This paper aims to develop a novel attitude determination system aided by polarization sensor. An improved heading angle function is derived using the perpendicular relationship between directions of E-vector of linearly polarized light and solar vector in the atmospheric polarization distribution model. The Extended Kalman filter (EKF) with quaternion differential equation as a dynamic model is applied to fuse the data from sensors. The covariance functions of filter process and measurement noises are deduced in detail. The indoor and outdoor tests are conducted to verify the validity and feasibility of proposed attitude determination system. The test results showed that polarization sensor is not affected by magnetic field, thus the proposed system can work properly in environments containing the magnetic interference. The results also showed that proposed system has higher measurement accuracy than common attitude determination system and can provide precise parameters for Unmanned Aerial Vehicle (UAV) flight control. The main contribution of this paper is implementation of the EKF for incorporating the self-developed polarization sensor into the conventional attitude determination system. The real-world experiment with the quad-rotor proved that proposed system can work in a magnetic interference environment and provide sufficient accuracy in attitude determination for autonomous navigation of vehicle. PMID:29315256
During air cool process aerosol absorption detection with photothermal interferometry
NASA Astrophysics Data System (ADS)
Li, Baosheng; Xu, Limei; Huang, Junling; Ma, Fei; Wang, Yicheng; Li, Zhengqiang
2014-11-01
This paper studies the basic principle of laser photothermal interferometry method of aerosol particles absorption coefficient. The photothermal interferometry method with higher accuracy and lower uncertainty can directly measure the absorption coefficient of atmospheric aerosols and not be affected by scattered light. With Jones matrix expression, the math expression of a special polarization interferometer is described. This paper using folded Jamin interferometer, which overcomes the influence of vibration on measuring system. Interference come from light polarization beam with two orthogonal and then combine to one beam, finally aerosol absorption induced refractive index changes can be gotten with four beam of phase orthogonal light. These kinds of styles really improve the stability of system and resolution of the system. Four-channel detections interact with interference fringes, to reduce the light intensity `zero drift' effect on the system. In the laboratory, this device typical aerosol absorption index, it shows that the result completely agrees with actual value. After heated by laser, cool process of air also show the process of aerosol absorption. This kind of instrument will be used to monitor ambient aerosol absorption and suspended particulate matter chemical component. Keywords: Aerosol absorption coefficient; Photothermal interferometry; Suspended particulate matter.
A new method to obtain Fourier transform infrared spectra free from water vapor disturbance.
Chen, Yujing; Wang, Hai-Shui; Umemura, Junzo
2010-10-01
Infrared absorption bands due to water vapor in the mid-infrared regions often obscure important spectral features of the sample. Here, we provide a novel method to collect a qualified infrared spectrum without any water vapor interference. The scanning procedure for a single-beam spectrum of the sample is divided into two stages under an atmosphere with fluctuating humidity. In the first stage, the sample spectrum is measured with approximately the same number of scans as the background. If the absorbance of water vapor in the spectrum is positive (or negative) at the end of the first stage, then the relative humidity in the sample compartment of the spectrometer is changed by a dry (or wet) air blow at the start of the second stage while the measurement of the sample spectrum continues. After the relative humidity changes to a lower (or higher) level than that of the previously collected background spectrum, water vapor peaks will become smaller and smaller with the increase in scanning number during the second stage. When the interfering water lines disappear from the spectrum, the acquisition of a sample spectrum is terminated. In this way, water vapor interference can finally be removed completely.
Addressing EO-1 Spacecraft Pulsed Plasma Thruster EMI Concerns
NASA Technical Reports Server (NTRS)
Zakrzwski, C. M.; Davis, Mitch; Sarmiento, Charles; Bauer, Frank H. (Technical Monitor)
2001-01-01
The Pulsed Plasma Thruster (PPT) Experiment on the Earth Observing One (EO-1) spacecraft has been designed to demonstrate the capability of a new generation PPT to perform spacecraft attitude control. Results from PPT unit level radiated electromagnetic interference (EMI) tests led to concerns about potential interference problems with other spacecraft subsystems. Initial plans to address these concerns included firing the PPT at the spacecraft level both in atmosphere, with special ground support equipment. and in vacuum. During the spacecraft level tests, additional concerns where raised about potential harm to the Advanced Land Imager (ALI). The inadequacy of standard radiated emission test protocol to address pulsed electromagnetic discharges and the lack of resources required to perform compatibility tests between the PPT and an ALI test unit led to changes in the spacecraft level validation plan. An EMI shield box for the PPT was constructed and validated for spacecraft level ambient testing. Spacecraft level vacuum tests of the PPT were deleted. Implementation of the shield box allowed for successful spacecraft level testing of the PPT while eliminating any risk to the ALI. The ALI demonstration will precede the PPT demonstration to eliminate any possible risk of damage of ALI from PPT operation.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Matter, A.; Lopez, B.; Lagarde, S.
2009-12-01
The observable quantities in optical interferometry, which are the modulus and the phase of the complex visibility, may be corrupted by parasitic fringes superimposed on the genuine fringe pattern. These fringes are due to an interference phenomenon occurring from stray light effects inside an interferometric instrument. We developed an analytical approach to better understand this phenomenon when stray light causes cross talk between beams. We deduced that the parasitic interference significantly affects the interferometric phase and thus the associated observables including the differential phase and the closure phase. The amount of parasitic flux coupled to the piston between beams appearsmore » to be very influential in this degradation. For instance, considering a point-like source and a piston ranging from lambda/500 to lambda/5 in the L band (lambda = 3.5 mum), a parasitic flux of about 1% of the total flux produces a parasitic phase reaching at most one-third of the intrinsic phase. The piston, which can have different origins (instrumental stability, atmospheric perturbations, etc.), thus amplifies the effect of parasitic interference. According to the specifications of piston correction in space or at ground level (respectively lambda/500 approx 2 nm and lambda/30 approx 100 nm), the detection of hot Jupiter-like planets, one of the most challenging aims for current ground-based interferometers, limits parasitic radiation to about 5% of the incident intensity. This was evaluated by considering different types of hot Jupiter synthetic spectra. Otherwise, if no fringe tracking is used, the detection of a typical hot Jupiter-like system with a solar-like star would admit a maximum level of parasitic intensity of 0.01% for piston errors equal to lambda/15. If the fringe tracking specifications are not precisely observed, it thus appears that the allowed level of parasitic intensity dramatically decreases and may prevent the detection. In parallel, the calibration of the parasitic phase by a reference star, at this accuracy level, seems very difficult. Moreover, since parasitic phase is an object-dependent quantity, the use of a hypothetical phase abacus, directly giving the parasitic phase from a given parasitic flux level, is also impossible. Some instrumental solutions, implemented at the instrument design stage for limiting or preventing this parasitic interference, appear to be crucial and are presented in this paper.« less
A Bispectral Composite Threshold Approach for Automatic Cloud Detection in VIIRS Imagery
NASA Technical Reports Server (NTRS)
LaFontaine Frank J.; Jedlovec, Gary J.
2015-01-01
The detection of clouds in satellite imagery has a number of important applications in weather and climate studies. The presence of clouds can alter the energy budget of the Earth-atmosphere system through scattering and absorption of shortwave radiation and the absorption and re-emission of infrared radiation at longer wavelengths. The scattering and absorption characteristics of clouds vary with the microphysical properties of clouds, hence the cloud type. Thus, detecting the presence of clouds over a region in satellite imagery is important in order to derive atmospheric or surface parameters that give insight into weather and climate processes. For many applications however, clouds are a contaminant whose presence interferes with retrieving atmosphere or surface information. In these cases, is important to isolate cloud-free pixels, used to retrieve atmospheric thermodynamic information or surface geophysical parameters, from cloudy ones. This abstract describes an application of a two-channel bispectral composite threshold (BCT) approach applied to VIIRS imagery. The simplified BCT approach uses only the 10.76 and 3.75 micrometer spectral channels from VIIRS in two spectral tests; a straight-forward infrared threshold test with the longwave channel and a shortwave - longwave channel difference test. The key to the success of this approach as demonstrated in past applications to GOES and MODIS data is the generation of temporally and spatially dependent thresholds used in the tests from a previous number of days at similar observations to the current data. The paper and subsequent presentation will present an overview of the approach and intercomparison results with other satellites, methods, and against verification data.
NASA Astrophysics Data System (ADS)
Mamun, M.; Mondol, P.
2012-12-01
Aerosols influence our weather and climate because they affect the amount of sunlight reaching Earth's surface. An important way of probing the atmosphere from the ground is to measure the effects of the atmosphere on sunlight transmitted through the atmosphere to Earth's surface. These indirect techniques provide information about the entire atmosphere above the observer, not just the atmosphere that can be sampled directly. In response to global issues of air quality and climate change, and to the need to improve the quality of science education, inexpensive atmosphere monitoring instruments have been developed. This paper describes a new kind of inexpensive two channels LED Sun Photometer for monitoring aerosols that provide much better long-term stability than instruments that use expensive interference filters. Here HAZE-SPAN TERC VHS-1 model has been used for constructing sun photometer with light emitting diode as detector. Monitoring Earth's atmosphere is a challenging task. As there is no facility in our country (Bangladesh) for ground based measurement for monitoring aerosol so, this type of study is very essential. This study compares the aerosol optical depth (AOD) retrieved from the Terra and Aqua MODerate Resolution Imaging Spectroradiometers (MODIS) with ground-based measurements from a handheld sun photometer over the region of Rajshahi, Bangladesh for The 15 days duration of June 2012. The results indicate that the Terra and Aqua MODIS AOD retrievals at 550 nm have good correlations with the measurements from the handheld sun photometer. The correlation coefficients r = 0.88 for Terra and r = 0.55 for Aqua where as r = 0.65 for Terra and Aqua themselves. AOD for another wavelength at 625 nm is documented in this study for finding out the relation of AOD at different wavelengths. In this paper it has been described and summarized briefly investigations for four important topics: LEDs used as light detectors, construction of sun photometer and its use, the measurements and monitoring of Aerosol Optical Depth (AOD) by using handheld sun photometer, and the comparison between satellite based and ground based measurements.
Atmospheric changes caused by galactic cosmic rays over the period 1960–2010
Jackman, Charles H.; Marsh, Daniel R.; Kinnison, Douglas E.; ...
2016-05-13
The Specified Dynamics version of the Whole Atmosphere Community Climate Model (SD-WACCM) and the Goddard Space Flight Center two-dimensional (GSFC 2-D) models are used to investigate the effect of galactic cosmic rays (GCRs) on the atmosphere over the 1960–2010 time period. The Nowcast of Atmospheric Ionizing Radiation for Aviation Safety (NAIRAS) computation of the GCR-caused ionization rates are used in these simulations. GCR-caused maximum NO x increases of 4–15 % are computed in the Southern polar troposphere with associated ozone increases of 1–2 %. NO x increases of ~1–6 % are calculated for the lower stratosphere with associated ozone decreasesmore » of 0.2–1 %. The primary impact of GCRs on ozone was due to their production of NO x. The impact of GCRs varies with the atmospheric chlorine loading, sulfate aerosol loading, and solar cycle variation. Because of the interference between the NO x and ClO x ozone loss cycles (e.g., the ClO + NO 2+ M → ClONO 2+ M reaction) and the change in the importance of ClO x in the ozone budget, GCRs cause larger atmospheric impacts with less chlorine loading. GCRs also cause larger atmospheric impacts with less sulfate aerosol loading and for years closer to solar minimum. GCR-caused decreases of annual average global total ozone (AAGTO) were computed to be 0.2 % or less with GCR-caused column ozone increases between 1000 and 100 hPa of 0.08 % or less and GCR-caused column ozone decreases between 100 and 1 hPa of 0.23 % or less. Although these computed ozone impacts are small, GCRs provide a natural influence on ozone and need to be quantified over long time periods. This result serves as a lower limit because of the use of the ionization model NAIRAS/HZETRN which underestimates the ion production by neglecting electromagnetic and muon branches of the cosmic ray induced cascade. Furthermore, this will be corrected in future works.« less
Atmospheric changes caused by galactic cosmic rays over the period 1960–2010
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jackman, Charles H.; Marsh, Daniel R.; Kinnison, Douglas E.
The Specified Dynamics version of the Whole Atmosphere Community Climate Model (SD-WACCM) and the Goddard Space Flight Center two-dimensional (GSFC 2-D) models are used to investigate the effect of galactic cosmic rays (GCRs) on the atmosphere over the 1960–2010 time period. The Nowcast of Atmospheric Ionizing Radiation for Aviation Safety (NAIRAS) computation of the GCR-caused ionization rates are used in these simulations. GCR-caused maximum NO x increases of 4–15 % are computed in the Southern polar troposphere with associated ozone increases of 1–2 %. NO x increases of ~1–6 % are calculated for the lower stratosphere with associated ozone decreasesmore » of 0.2–1 %. The primary impact of GCRs on ozone was due to their production of NO x. The impact of GCRs varies with the atmospheric chlorine loading, sulfate aerosol loading, and solar cycle variation. Because of the interference between the NO x and ClO x ozone loss cycles (e.g., the ClO + NO 2+ M → ClONO 2+ M reaction) and the change in the importance of ClO x in the ozone budget, GCRs cause larger atmospheric impacts with less chlorine loading. GCRs also cause larger atmospheric impacts with less sulfate aerosol loading and for years closer to solar minimum. GCR-caused decreases of annual average global total ozone (AAGTO) were computed to be 0.2 % or less with GCR-caused column ozone increases between 1000 and 100 hPa of 0.08 % or less and GCR-caused column ozone decreases between 100 and 1 hPa of 0.23 % or less. Although these computed ozone impacts are small, GCRs provide a natural influence on ozone and need to be quantified over long time periods. This result serves as a lower limit because of the use of the ionization model NAIRAS/HZETRN which underestimates the ion production by neglecting electromagnetic and muon branches of the cosmic ray induced cascade. Furthermore, this will be corrected in future works.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Parker, H.; Hedelius, J.
During the summer of 2015, a field campaign took place to help characterize off-the-shelf portable solar-viewing Fourier Transform Spectrometer (FTS) instruments (EM27/SUN). These instruments retrieve greenhouse gas (GHG) abundances from direct solar spectra. A focus of this campaign was to test possible dependence on different atmospheric conditions. Along with the U.S. Department of Energy’s Atmospheric Radiation Measurement (ARM) Climate Research Facility Southern Great Plains (SGP) site in Oklahoma, experiments were conducted in Pasadena, California; Park Falls, Wisconsin; and the Armstrong Flight Research Center (AFRC), California. These locations are home to instruments in the Total Column Carbon Observing Network (TCCON). TCCONmore » measurements were used as standards for the portable (EM27/SUN) measurements. Comparisons between the two types of instruments are crucial in the attempt to use the portable instruments to broaden the capabilities of GHG measurements for monitoring, reporting, and verification of carbon in the atmosphere. This campaign was aimed at testing the response of the portable FTS to different atmospheric conditions both local and regional. Measurements made at ARM SGP provided data in an agricultural environment with a relatively clean atmosphere with respect to pollution. Due to the homogeneity of the region surrounding Lamont, Oklahoma, portable FTS measurements were less effected by large changes in column GHG abundances from air mass movement between regions. These conditions aided in characterizing potential artificial solar zenith angle dependence of the retrievals. Data collected under atmospheric conditions at ARM SGP also provide for the analysis of cloud interference on solar spectra. In situ measurements were also made using a Picarro isotopic methane analyzer to determine surface-level in situ GHG concentrations and possible influences due to local agriculture and nearby towns. Data collected in this campaign have been presented via a poster at the American Geophysical Union Fall Meeting in 2015 and is included in a paper that is in preparation to be submitted to Atmospheric Measurement Techniques in 2016.« less
NASA Astrophysics Data System (ADS)
Fuchs, H.; Ball, S. M.; Bohn, B.; Brauers, T.; Cohen, R. C.; Dorn, H.-P.; Dubé, W. P.; Fry, J. L.; Häseler, R.; Heitmann, U.; Jones, R. L.; Kleffmann, J.; Mentel, T. F.; Müsgen, P.; Rohrer, F.; Rollins, A. W.; Ruth, A. A.; Kiendler-Scharr, A.; Schlosser, E.; Shillings, A. J. L.; Tillmann, R.; Varma, R. M.; Venables, D. S.; Villena Tapia, G.; Wahner, A.; Wegener, R.; Wooldridge, P. J.; Brown, S. S.
2010-01-01
NO2 concentrations were measured by various instruments during the NO3Comp campaign at the atmosphere simulation chamber SAPHIR at Forschungszentrum Jülich, Germany, in June 2007. Analytical methods included photolytic conversion with chemiluminescence (PC-CLD), broadband cavity ring-down spectroscopy (BBCRDS), pulsed cavity ring-down spectroscopy (CRDS), incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS), and laser-induced fluorescence (LIF). All broadband absorption spectrometers were optimized for the detection of the main target species of the campaign, NO3, but were also capable of detecting NO2 simultaneously with reduced sensitivity. NO2 mixing ratios in the chamber were within a range characteristic of polluted, urban conditions, with a maximum mixing ratio of approximately 75 ppbv. The overall agreement between measurements of all instruments was excellent. Linear fits of the combined data sets resulted in slopes that differ from unity only within the stated uncertainty of each instrument. Possible interferences from species such as water vapor and ozone were negligible under the experimental conditions.
NASA Astrophysics Data System (ADS)
Fuchs, H.; Ball, S. M.; Bohn, B.; Brauers, T.; Cohen, R. C.; Dorn, H.-P.; Dubé, W. P.; Fry, J. L.; Häseler, R.; Heitmann, U.; Jones, R. L.; Kleffmann, J.; Mentel, T. F.; Müsgen, P.; Rohrer, F.; Rollins, A. W.; Ruth, A. A.; Kiendler-Scharr, A.; Schlosser, E.; Shillings, A. J. L.; Tillmann, R.; Varma, R. M.; Venables, D. S.; Villena Tapia, G.; Wahner, A.; Wegener, R.; Wooldridge, P. J.; Brown, S. S.
2009-10-01
NO2 concentrations were measured by various instruments during the NO3Comp campaign at the atmosphere simulation chamber SAPHIR at Forschungszentrum Jülich, Germany, in June 2007. Analytic methods included photolytic conversion with chemiluminescence (PC-CLD), broadband cavity ring-down spectroscopy (BBCRDS), pulsed cavity ring-down spectroscopy (CRDS), incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS), and laser-induced fluorescence (LIF). All broadband absorption spectrometers were optimized for the detection of the main target species of the campaign, NO2, but were also capable of detecting NO2 simultaneously with reduced sensitivity. NO2 mixing ratios in the chamber were within a range characteristic of polluted, urban conditions, with a maximum mixing ratio of approximately 75 ppbv. The overall agreement between measurements of all instruments was excellent. Linear fits of the combined data sets resulted in slopes that differ from unity only within the stated uncertainty of each instrument. Possible interferences from species such as water vapor and ozone were negligible under the experimental conditions.
Near infrared cavity enhanced absorption spectra of atmospherically relevant ether-1, 4-Dioxane.
Chandran, Satheesh; Varma, Ravi
2016-01-15
1, 4-Dioxane (DX) is a commonly found ether in industrially polluted atmosphere. The near infrared absorption spectra of this compound has been recorded in the region 5900-8230 cm(-1) with a resolution of 0.08 cm(-1) using a novel Fourier transform incoherent broadband cavity-enhanced absorption spectrometer (FT-IBBCEAS). All recorded spectra were found to contain regions that are only weakly perturbed. The possible combinations of fundamental modes and their overtone bands corresponding to selected regions in the measured spectra are tabulated. Two interesting spectral regions were identified as 5900-6400 cm(-1) and 8100-8230 cm(-1). No significant spectral interference due to presence of water vapor was observed suggesting the suitability of these spectral signatures for spectroscopic in situ detection of DX. The technique employed here is much more sensitive than standard Fourier transform spectrometer measurements on account of long effective path length achieved. Hence significant enhancement of weaker absorption lines above the noise level was observed as demonstrated by comparison with an available measurement from database. Copyright © 2015 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Gibert, F.; Edouart, D.; Cénac, C.; Le Mounier, F.; Dumas, A.
2017-11-01
In the absence of climate change policies, the fossil fuel emissions are projected to increase in the next decades. Depending on how the current carbon sinks change in the future, the atmospheric CO2 concentration is predicted to be between 700-1000 ppmv by 2100, and global mean surface temperature between 1.1-6.4°C, with related changes in sea-level, extreme events and ecosystem drifts. Keeping the atmospheric CO2 concentration at a level that prevents dangerous interference with the climate system poses an unprecedent but necessary challenge to humanity. Beyond this point, global climate change would be very difficult and costly to deal with. There are two main approaches that are currently analysed: (1) to reduce emissions; (2) to capture CO2 and store it, i.e. sequestration. For these two ways, some monitoring at different scales ultimately from space would be needed. Lidar remote sensing is a powerful technique that enables measurements at various space and time resolution.
Evaluation of three new laser spectrometer techniques for in-situ carbon monoxide measurements
NASA Astrophysics Data System (ADS)
Zellweger, C.; Steinbacher, M.; Buchmann, B.
2012-07-01
Long-term time series of the atmospheric composition are essential for environmental research and thus require compatible, multi-decadal monitoring activities. However, the current data quality objectives of the World Meteorological Organization (WMO) for carbon monoxide (CO) in the atmosphere are very challenging to meet with the measurement techniques that have been used until recently. During the past few years, new spectroscopic techniques came on the market with promising properties for trace gas analytics. The current study compares three instruments that are recently commercially available (since 2011) with the up to now best available technique (vacuum UV fluorescence) and provides a link to previous comparison studies. The instruments were investigated for their performance regarding repeatability, reproducibility, drift, temperature dependence, water vapour interference and linearity. Finally, all instruments were examined during a short measurement campaign to assess their applicability for long-term field measurements. It could be shown that the new techniques provide a considerably better performance compared to previous techniques, although some issues such as temperature influence and cross sensitivities need further attention.
Kuster, William C; Harren, Frans J M; de Gouw, Joost A
2005-06-15
Laser photoacoustic spectroscopy (LPAS) is highly suitable for the detection of ethene in air due to the overlap between its strongest absorption lines and the wavelengths accessible by high-powered CO2 lasers. Here, we test the ability of LPAS to measure ethene in ambient air by comparing the measurements in urban air with those from a gas chromatography flame-ionization detection (GC-FID) instrument. Over the course of several days, we obtained quantitative agreement between the two measurements. Over this period, the LPAS instrument had a positive offset of 330 +/- 140 pptv (parts-per-trillion by volume) relative to the GC-FID instrument, possibly caused by interference from other species. The detection limit of the LPAS instrument is currently estimated around 1 ppbv and is limited by this offset and the statistical noise in the data. We conclude that LPAS has the potential to provide fast-response measurements of ethene in the atmosphere, with significant advantages over existing techniques when measuring from moving platforms and in the vicinity of emission sources.
Higher fungal diversity is correlated with lower CO2 emissions from dead wood in a natural forest.
Yang, Chunyan; Schaefer, Douglas A; Liu, Weijie; Popescu, Viorel D; Yang, Chenxue; Wang, Xiaoyang; Wu, Chunying; Yu, Douglas W
2016-08-24
Wood decomposition releases almost as much CO2 to the atmosphere as does fossil-fuel combustion, so the factors regulating wood decomposition can affect global carbon cycling. We used metabarcoding to estimate the fungal species diversities of naturally colonized decomposing wood in subtropical China and, for the first time, compared them to concurrent measures of CO2 emissions. Wood hosting more diverse fungal communities emitted less CO2, with Shannon diversity explaining 26 to 44% of emissions variation. Community analysis supports a 'pure diversity' effect of fungi on decomposition rates and thus suggests that interference competition is an underlying mechanism. Our findings extend the results of published experiments using low-diversity, laboratory-inoculated wood to a high-diversity, natural system. We hypothesize that high levels of saprotrophic fungal biodiversity could be providing globally important ecosystem services by maintaining dead-wood habitats and by slowing the atmospheric contribution of CO2 from the world's stock of decomposing wood. However, large-scale surveys and controlled experimental tests in natural settings will be needed to test this hypothesis.
Higher fungal diversity is correlated with lower CO2 emissions from dead wood in a natural forest
Yang, Chunyan; Schaefer, Douglas A.; Liu, Weijie; Popescu, Viorel D.; Yang, Chenxue; Wang, Xiaoyang; Wu, Chunying; Yu, Douglas W.
2016-01-01
Wood decomposition releases almost as much CO2 to the atmosphere as does fossil-fuel combustion, so the factors regulating wood decomposition can affect global carbon cycling. We used metabarcoding to estimate the fungal species diversities of naturally colonized decomposing wood in subtropical China and, for the first time, compared them to concurrent measures of CO2 emissions. Wood hosting more diverse fungal communities emitted less CO2, with Shannon diversity explaining 26 to 44% of emissions variation. Community analysis supports a ‘pure diversity’ effect of fungi on decomposition rates and thus suggests that interference competition is an underlying mechanism. Our findings extend the results of published experiments using low-diversity, laboratory-inoculated wood to a high-diversity, natural system. We hypothesize that high levels of saprotrophic fungal biodiversity could be providing globally important ecosystem services by maintaining dead-wood habitats and by slowing the atmospheric contribution of CO2 from the world’s stock of decomposing wood. However, large-scale surveys and controlled experimental tests in natural settings will be needed to test this hypothesis. PMID:27553882
Raptis, Nikos; Pikasis, Evangelos; Syvridis, Dimitris
2016-08-01
The exploitation of optical wireless communication channels in a non-line-of-sight regime is studied for point-to-point and networking configurations considering the use of light-emitting diodes. Two environments with different scattering center densities are considered, assuming operation at 265 nm. The bit error rate performance of both pulsed and multicarrier modulation schemes is examined, using numerical approaches. In the networking scenario, a central node only receives data, one node transmits useful data, and the rest of them act as interferers. The performance of the desirable node's transmissions is evaluated. The access to the medium is controlled by a code division multiple access scheme.
Silicon photodiode as a detector in the rocket-borne photometry of the near infrared airglow.
Schaeffer, R C
1976-11-01
The application of a silicon P-I-N photodiode to the dc measurement of low levels of near ir radiation is described. It is shown that the threshold of signal detection is set by the current amplifier voltage noise, the effect of which at the output is determined by the value of source resistance of the photodiode. The photodiode was used as the detector in a compact interference filter photometer designed for rocket-borne studies of the airglow. Flight results have proved the instrument's capability to provide measurements sufficiently precise to yield an accurate height profile of the (0-0) atmospheric band of O(2) night airglow at lambda762 nm.
Diagnostics development for E-beam excited air channels
NASA Astrophysics Data System (ADS)
Eckstrom, D. J.; Dickenson, J. S.
1982-02-01
As the tempo of development of particle beam weapons increases, more detailed diagnostics of the interaction of the particle beam with the atmosphere are being proposed and implemented. Some of these diagnostics involve probing of the excited air channel with visible wavelength laser radiation. Examples include the use of visible wavelength interferometry to measure electron density profiles in the nose of the beam Ri81 and Stark shift measurements to determine self-induced electric fields Hi81, DR81. In these diagnostics, the change in laser intensity due to the desired diagnostic effect can be quite small, leading to the possibility that other effects, such as gas phase absorption, could seriously interfere with the measurement.
NASA Astrophysics Data System (ADS)
Engelmann, Ronny; Haarig, Moritz; Baars, Holger; Ansmann, Albert; Kottas, Michael; Marinou, Eleni
2018-04-01
We replaced a 1064-nm interference filter of a Polly-XT lidar system by a 1058-nm filter to observe pure rotational Raman backscattering from atmospheric Nitrogen and Oxygen. Polly-XT is compact Raman lidar with a Nd:YAG laser (20 Hz, 200 mJ at 1064 nm) and a 30-cm telescope mirror which applies photomultipliers in photoncounting mode. We present the first measured signals at 1058 nm and the derived extinction profile from measurements aboard RV Polarstern and in Leipzig. In combination with another Polly-XT system we could also derive particle backscatter and lidar ratio profiles at 1064 nm.
On the role of Fe ions on magnetic properties of doped TiO2 nanoparticles
NASA Astrophysics Data System (ADS)
Tolea, F.; Grecu, M. N.; Kuncser, V.; Constantinescu, S. Gr.; Ghica, D.
2015-04-01
The role of iron doping on magnetic properties of hydrothermal anatase TiO2:57Fe (0-1 at. %) nanoparticles is investigated by combining superconducting quantum interference device magnetometry with Mössbauer and electron paramagnetic resonance techniques. The results on both as-prepared and thermally treated samples in reduced air atmosphere reveal complexity of magnetic interactions, in connection to certain iron ion electron configurations and defects (oxygen vacancies, F-center, and Ti3+ ions). The distribution of iron ions is predominantly at nanoparticle surface layers. Formation of weak ferromagnetic domains up to 380 K is mainly related to defects, supporting the bound magnetic polaron model.
NASA Technical Reports Server (NTRS)
Rivera, Lizxandra Flores; Lang, Timothy
2014-01-01
Sprites are a category of Transient Luminous Events (TLEs) that occur in the upper atmosphere above the tops of Mesoscale Convective Systems (MCSs). They are commonly associated with lightning strokes that produce large charge moment changes (CMCs). Synergistic use of satellite and radar-retrieved observations together with sounding data, forecasts, and lightning-detection networks allowed the diagnosis and analysis of the meteorological conditions associated with sprites as well as large-CMC lightning over Oklahoma. One goal of the NASA-funded effort reported herein is the investigation of the potential for sprite interference with aerospace activities in the 20- 100km altitude range, including research balloons, space missions and other aviation transports.
NASA Technical Reports Server (NTRS)
Meek, C. E.; Reid, I. M.
1984-01-01
It has been suggested that the velocities produced by the spaced antenna partial-reflection drift experiment may constitute a measure of the vertical oscillations due to short-period gravity waves rather than the mean horizontal flow. The contention is that the interference between say two scatterers, one of which is traveling upward, and the other down, will create a pattern which sweeps across the ground in the direction (or anti-parallel) of the wave propagation. Since the expected result, viz., spurious drift directions, is seldom, if ever, seen in spaced antenna drift velocities, this speculation is tested in an atmospheric model.
Work function determination of promising electrode materials for thermionic converters
NASA Technical Reports Server (NTRS)
Jacobson, D.
1977-01-01
Work performed on this contract was primarily for the evaluation of selected electrode materials for thermionic energy converters. The original objective was to characterize selected nickel based superalloys up to temperatures of 1400 K. It was found that an early selection, Inconel 800 produced a high vapor pressure which interfered with the vacuum emission measurements. The program then shifted to two other areas. The first area was to obtain emission from the superalloys in a cesiated atmosphere. The cesium plasma helps to suppress the vaporization interference. The second area involved characterization of the Lanthanum-Boron series as thermionic emitters. These final two areas resulted in three journal publications which are attached to this report.
Real time in situ detection of organic nitrates in atmospheric aerosols
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rollins, Andrew W.; Smith, Jared D.; Wilson, Kevin R.
2010-06-11
A new field instrument is described that quantifies total particle phase organic nitrates. The instrument is based on the thermal dissociation laser induced fluorescence (TD-LIF) method that thermally converts nitrates to NO2 which is then detected by LIF. This instrument is unique in its ability to provide fast sensitive measurements of particle phase organic nitrates, without interference from inorganic nitrate. Here we use it to quantify organic nitrates in SOA generated from high-NOx photooxidation of limonene, a-pinene, D-3-carene, and tridecane. In these experiments the organic nitrate moiety is observed to be 6-15percent of the total SOA mass, depending on themore » organic precursor.« less
Escudero, Carlos; Jiang, Peng; Pach, Elzbieta; Borondics, Ferenc; West, Mark W; Tuxen, Anders; Chintapalli, Mahati; Carenco, Sophie; Guo, Jinghua; Salmeron, Miquel
2013-05-01
A miniature (1 ml volume) reaction cell with transparent X-ray windows and laser heating of the sample has been designed to conduct X-ray absorption spectroscopy studies of materials in the presence of gases at atmospheric pressures. Heating by laser solves the problems associated with the presence of reactive gases interacting with hot filaments used in resistive heating methods. It also facilitates collection of a small total electron yield signal by eliminating interference with heating current leakage and ground loops. The excellent operation of the cell is demonstrated with examples of CO and H2 Fischer-Tropsch reactions on Co nanoparticles.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ishaq, M., E-mail: ishaqmusarat@gmail.com; Comonwealth Scientific and Industrial Research Organization, Sydney, New South Wales; Bazaka, K.
Gas discharge plasmas formed at atmospheric pressure and near room temperature have recently been shown as a promising tool for cancer treatment. The mechanism of the plasma action is attributed to generation of reactive oxygen and nitrogen species, electric fields, charges, and photons. The relative importance of different modes of action of atmospheric-pressure plasmas depends on the process parameters and specific treatment objects. Hence, an in-depth understanding of biological mechanisms that underpin plasma-induced death in cancer cells is required to optimise plasma processing conditions. Here, the intracellular factors involved in the observed anti-cancer activity in melanoma Mel007 cells are studied,more » focusing on the effect of the plasma treatment dose on the expression of tumour suppressor protein TP73. Over-expression of TP73 causes cell growth arrest and/or apoptosis, and hence can potentially be targeted to enhance killing efficacy and selectivity of the plasma treatment. It is shown that the plasma treatment induces dose-dependent up-regulation of TP73 gene expression, resulting in significantly elevated levels of TP73 RNA and protein in plasma-treated melanoma cells. Silencing of TP73 expression by means of RNA interference inhibited the anticancer effects of the plasma, similar to the effect of caspase inhibitor z-VAD or ROS scavenger N-acetyl cysteine. These results confirm the role of TP73 protein in dose-dependent regulation of anticancer activity of atmospheric-pressure plasmas.« less
In-Flight Performance of the Soft X-Ray Spectrometer Detector System on ASTRO-H
NASA Technical Reports Server (NTRS)
Porter, Frederick S.; Boyce, Kevin R.; Chiao, Meng P.; Eckart, Megan E.; Fujimoto, Ryuichi; Ishisaki, Yoshitaka; Kelley, Richard L.; Kilbourne, Carolina A.; Leutenegger, Maurice A.; McCammon, Dan;
2016-01-01
The SXS instrument was launched aboard the Astro-H observatory on February 17, 2016. The SXS spectrometer is based on a high sensitivity x-ray calorimeter detector system that has been successfully deployed in many ground and sub-orbital spectrometers. The instrument was to provide essential diagnostics for nearly every class of x-ray emitting objects from the atmosphere of Jupiter to the outskirts of galaxy clusters, without degradation for spatially extended objects. The SXS detector system consisted of a 36-pixel cryogenic microcalorimeter array operated at a heat sink temperature of 50 mK. In pre-flight testing, the detector system demonstrated a resolving power of better than 1300 at 6 keV with a simultaneous band-pass from below 0.3 keV to above 12 keV with a timing precision better than 100 microsecond. In addition, a solid-state anti-coincidence detector was placed directly behind the detector array for background suppression. The detector error budget included the measured interference from the SXS cooling system and the spacecraft. Additional margin for on-orbit gain-stability, and on-orbit spacecraft interference were also included predicting an on-orbit performance that meets or exceeds the 7 eV FWHM at 6 keV requirement. The actual on-orbit spectral resolution was better than 5 eV FWHM at 6 keV, easily satisfying the instrument requirement. Here we discuss the actual on-orbit performance of the SXS detector system and compare this to performance in pre-flight testing and the on-orbit predictions. We will also discuss the on-orbit gain stability, additional on-orbit interference, and measurements of the on-orbit background.
In-flight performance of the soft x-ray spectrometer detector system on Astro-H
NASA Astrophysics Data System (ADS)
Porter, Frederick S.; Boyce, Kevin R.; Chiao, Meng P.; Eckart, Megan E.; Fujimoto, Ryuichi; Ishisaki, Yoshitaka; Kilbourne, Caroline Anne; Leutenegger, Maurice A.; McCammon, Daniel; Mitsuda, Kazuhisa; Sato, Kosuke; Seta, Hiromi; Sawada, Makoto; Sneiderman, Gary A.; Szymkowiak, Andrew E.; Takei, Yoh; Tashiro, Makoto S.; Tsujimoto, Masahiro; Watanabe, Tomomi; Yamada, Shinya
2018-01-01
The soft x-ray spectrometer (SXS) instrument was launched aboard the Astro-H (Hitomi) observatory on February 17, 2016. The SXS is based on a high-sensitivity x-ray calorimeter detector system that has been successfully deployed in many ground and suborbital spectrometers. The instrument was to provide essential diagnostics for nearly every class of x-ray emitting objects from the atmosphere of Jupiter to the outskirts of galaxy clusters, without degradation for spatially extended objects. The SXS detector system consisted of a 36-pixel cryogenic microcalorimeter array operated at a heat sink temperature of 50 mK. In preflight testing, the detector system demonstrated a resolving power of better than 1300 at 6 keV with a simultaneous bandpass from below 0.3 keV to above 12 keV with a timing precision better than 100 μs. In addition, a solid-state anticoincidence detector was placed directly behind the detector array for background suppression. The detector error budget included the measured interference from the SXS cooling system and the spacecraft. Additional margin for on-orbit gain stability and on-orbit spacecraft interference were also included predicting an on-orbit performance that meets or exceeds the 7-eV FWHM at 6-keV requirement. The actual on-orbit spectral resolution was better than 5 eV FWHM at 6 keV, easily satisfying the instrument requirement. Here, we discuss the actual on-orbit performance of the SXS detector system and compare this to performance in preflight testing and the on-orbit predictions. We will also discuss the on-orbit gain stability, additional on-orbit interference, and measurements of the on-orbit background.
Measurement of Environmental NO2 by Photoacoustic Spectroscopy
NASA Astrophysics Data System (ADS)
Wang, Gaoxuan; Yi, Hongming; Fertein, Eric; Sigrist, Markus W.; Chen, Weidong
2016-04-01
The most widely used technique for the measurements of nitrogen dioxide (NO2) is the chemiluminescence technique. However this indirect NO2 measurement method is affected by positive or negative interferences due to the use of non selective catalyzer molybdenum or photolytic converter [1]. Photoacoustic spectroscopy (PAS) offers the capability of interference-free direct NO2 measurement without any sample preparation or/and chemical conversion [2,3]. In this paper, we report on the development and applications of a photoacoustic spectroscopy-based NO2 sensor for continuous measurement of NO2 in air with a sensitivity of about 0.5 ppb (SNR=1) and 1 min time resolution. Time series measurements of environmental NO2 concentrations were carried out and compared with side-by-side measurements by a NOx analyzer (AC-31 M). Good agreement has been observed. Experimental detail and preliminary results will be presented. Acknowledgements The authors acknowledge financial supports from the CaPPA project (ANR-10-LABX-005) and the CPER CLIMIBIO program. G. W. thanks the "Pôle Métropolitain de la Côte d'Opale" (PMCO) and the Région Nord Pas de Calais for the PhD fellowship support. References [1] G. Villena, I. Bejan, R. Kurtenbach, P. Wiesen, J. Kleffmann, "Interferences of Commercial NO2 instruments in the urban atmosphere and in a smog chamber", Atmos. Meas. Tech. 5 (2012) 149. [2] M. Lassen, D. B. Clsusen, A. Brusch, J. C. Petersen, "A versatil integrating sphere based photoacoustic sensor for trace gas monitoring", Opt. Express 22 (2014) 11660. [3] C. Haisch, R. Niessner, "Photoacoustic analyzer for the artifact-free parallel detection of soot and NO2 in engin exhaut", Anal. Chem. 84 (2012) 7292.
Remote Raman Spectroscopy of Minerals at Elevated Temperature Relevant to Venus Exploration
NASA Technical Reports Server (NTRS)
Sharma, Shiv K.; Misra, Anupam K.; Singh, Upendra N.
2008-01-01
We have used a remote time-resolved telescopic Raman system equipped with 532 nm pulsed laser excitation and a gated intensified CCD (ICCD) detector for measuring Raman spectra of a number of minerals at high temperature to 970 K. Remote Raman measurements were made with samples at 9-meter in side a high-temperature furnace by gating the ICCD detector with 2 micro-sec gate to minimize interference from blackbody emission from mineral surfaces at high temperature as well as interference from ambient light. A comparison of Raman spectra of gypsum (CaSO4.2H2O), dolomite (CaMg(CO3)2), and olivine (Mg2Fe2-xSiO4), as a function of temperature shows that the Raman lines remains sharp and well defined even in the high-temperature spectra. In the case of gypsum, Raman spectral fingerprints of CaSO4.H2O at 518 K were observed due to dehydration of gypsum. In the case of dolomite, partial mineral dissociation was observed at 973 K at ambient pressure indicating that some of the dolomite might survive on Venus surface that is at approximately 750 K and 92 atmospheric pressure. Time-resolved Raman spectra of low clino-enstatite (MgSiO3) measured at 75 mm from the sample in side the high-temperature furnace also show that the Raman lines remains sharp and well defined in the high temperature spectra. These high-temperature remote Raman spectra of minerals show that time-resolved Raman spectroscopy can be used as a potential tool for exploring Venus surface mineralogy at shorter (75 mm) and long (9 m) distances from the samples both during daytime and nighttime. The remote Raman system could also be used for measuring profiles of molecular species in the dense Venus atmosphere during descent as well as on the surface.
Aircraft Observations of Mercury over the US: The Nomadss Experiment
NASA Astrophysics Data System (ADS)
Jaffe, D. A.; Ambrose, J. L., II; Gratz, L.; Jaegle, L.; Shah, V.; Selin, N. E.; Song, S.; Giang, A.
2014-12-01
The Nitrogen, Oxidants, Mercury, and Aerosol Distributions, Sources and Sinks (NOMADSS) experiment took place in the summer of 2013. This is one of the first airborne experiments to focus on the sources and chemistry of Hg in the atmosphere. The experiment flew 19 research flights on the NCAR C-130 aircraft, based out of Smyrna, TN. The primary Hg goals for NOMADSS were to constrain emissions of Hg over the U.S. and quantify the distribution and chemistry of Gaseous Elemental Mercury (GEM) and Reactive Mercury (RM) in the troposphere. We measured speciated Hg on the C-130 using the UW-Detector of Oxidized HG species (UW-DOHGS). This instrument has been developed over several years and tested/calibrated with several HgX2 compounds and other compounds to examine possible interferences. In its current configuration, the instrument quantitatively measures HgX2 compounds (HgCl2 and HgBr2) with no interference from O3. During NOMADSS, flight planning was facilitated by use of the NASA GEOS-5 system, which provided forecasts for many relevant tracers. Post-mission analyses are being conducted using the GEOS-Chem Hg model. This provides a key tool to compare current estimates of Hg sources and distribution with aircraft observations. We are using the NOMADSS data for several types of analyses: GEM emissions and concentrations in power plant plumes and downwind of urban centers; Presence of RM in relatively high concentration in several free tropospheric locations; Evaluation and interpretation of the data using the GEOS-Chem Hg model. While there are a number of important results from NOMADSS, the most striking is the high concentrations of RM GOM in some regions of the upper troposphere, significantly higher than calculated by the standard GEOS-Chem simulation. We believe this is most likely due to halogen oxidation. These results suggest higher halogen concentrations or faster oxidation of GEM and thus a substantial rethinking of Hg oxidation in the global atmosphere.
NASA Astrophysics Data System (ADS)
Suzuki, Yoshinari; Ohara, Ryota; Matsunaga, Kirara
2017-09-01
Nuclear power plant accidents release radioactive strontium 90 (90Sr) into the environment. Monitoring of 90Sr, although important, is difficult and time consuming because it emits only beta radiation. We have developed a new analytical system that enables real-time analysis of 90Sr in atmospheric particulate matter with an analytical run time of only 10 min. Briefly, after passage of an air sample through an impactor, a small fraction of the sample is introduced into a gas-exchange device, where the air is replaced by Ar. Then the sample is directly introduced into an inductively coupled plasma tandem mass spectrometry (ICP-MS/MS) system equipped with a collision/reaction cell to eliminate isobaric interferences on 90Sr from 90Zr+, 89Y1H+, and 90Y+. Experiments with various reaction gas conditions revealed that these interferences could be minimized under the following optimized conditions: 1.0 mL min- 1 O2, 10.0 mL min- 1 H2, and 1.0 mL min- 1 NH3. The estimated background equivalent concentration and estimated detection limit of the system were 9.7 × 10- 4 and 3.6 × 10- 4 ng m- 3, respectively, which are equivalent to 4.9 × 10- 6 and 1.8 × 10- 6 Bq cm- 3. Recoveries of Sr in PM2.5 measured by real-time analysis compared to those obtained by simultaneously collection on filter was 53 ± 23%, and using this recovery, the detection limit as PM2.5 was estimated to be 3.4 ± 1.5 × 10- 6 Bq cm- 3. That is, this system enabled detection of 90Sr at concentrations < 5 × 10- 6 Bq cm- 3 even considering the insufficient fusion/vaporization/ionization efficiency of Sr in PM2.5.
Recent Improvements in AMSR2 Ground-Based RFI Filtering
NASA Astrophysics Data System (ADS)
Scott, J. P.; Gentemann, C. L.; Wentz, F. J.
2015-12-01
Passive satellite radiometer measurements in the microwave frequencies (6-89 GHz) are useful in providing geophysical retrievals of sea surface temperature (SST), atmospheric water vapor, wind speed, rain rate, and more. However, radio frequency interference (RFI) is one of the fastest growing sources of error in these retrievals. RFI can originate from broadcasting satellites, as well as from ground-based instrumentation that makes use of the microwave range. The microwave channel bandwidths used by passive satellite radiometers are often wider than the protected bands allocated for this type of remote sensing, a common practice in microwave radiometer design used to reduce the effect of instrument noise in the observed signal. However, broad channel bandwidths allow greater opportunity for RFI to affect these observations and retrievals. For ground-based RFI, a signal is broadcast directly into the atmosphere which may interfere with the radiometer - its antenna, cold mirror, hot load or the internal workings of the radiometer itself. It is relatively easy to identify and flag RFI from large sources, but more difficult to do so from small, sporadic sources. Ground-based RFI has high spatial and temporal variability, requiring constant, automated detection and removal to avoid spurious trends leaching into the geophysical retrievals. Ascension Island in the South Atlantic Ocean has been one of these notorious ground-based RFI sources, affecting many microwave radiometers, including the AMSR2 radiometer onboard JAXA's GCOM-W1 satellite. Ascension Island RFI mainly affects AMSR2's lower frequency channels (6.9, 7.3, and 10.65 GHz) over a broad spatial region in the South Atlantic Ocean, which makes it challenging to detect and flag this RFI using conventional channel and geophysical retrieval differencing techniques. The authors have developed a new method of using the radiometer's earth counts and hot counts, for the affected channels, to detect an Ascension Island RFI event and flag the data efficiently and accurately, thereby reducing false detections and optimizing retrieval quality and data preservation.
Summers, David P
2005-08-01
One issue for the origin of life under a non-reducing atmosphere is the availability of the reduced nitrogen necessary for amino acids, nucleic acids, etc. One possible source of this nitrogen is the formation of ammonia from the reduction of nitrates and nitrites produced by the shock heating of the atmosphere and subsequent chemistry. Ferrous ions will reduce these species to ammonium, but not under acidic conditions. We wish to report results on the reduction of nitrite and nitrate by another source of iron (II), ferrous sulfide, FeS. FeS reduces nitrite to ammonia at lower pHs than the corresponding reduction by aqueous Fe+ 2. The reduction follows a first order decay, in nitrite concentration, with a half-life of about 150 min (room temperature, CO2, pH 6.25). The highest product yield of ammonia measured was 53%. Under CO2, the product yield decreases from pH 5.0 to pH 6.9. The increasing concentration of bicarbonate, at higher pH, interferes with the reaction. Comparing experiments under N2 CO2 shows the interference of bicarbonate. The reaction proceeds well in the presence of such species as chloride, sulfate, and phosphate, though the yield drops significantly with phosphate. FeS also reduces nitrate and, unlike with Fe+ 2, the reduction shows more reproducibility. Again, the product yield decreases with increasing pH, from 7% at pH 4.7 to 0% at pH 6.9. It appears that nitrate is much more sensitive to the presence of added species, perhaps not competing as well for binding sites on the FeS surface. This may be the cause of the lack of reproducibility of nitrate reduction by Fe+ 2 (which also can be sensitive to binding by certain species).
NASA Astrophysics Data System (ADS)
Summers, David P.
2005-08-01
One issue for the origin of life under a non-reducing atmosphere is the availability of the reduced nitrogen necessary for amino acids, nucleic acids, etc. One possible source of this nitrogen is the formation of ammonia from the reduction of nitrates and nitrites produced by the shock heating of the atmosphere and subsequent chemistry. Ferrous ions will reduce these species to ammonium, but not under acidic conditions. We wish to report results on the reduction of nitrite and nitrate by another source of iron (II), ferrous sulfide, FeS. FeS reduces nitrite to ammonia at lower pHs than the corresponding reduction by aqueous Fe+ 2. The reduction follows a first order decay, in nitrite concentration, with a half-life of about 150 min (room temperature, CO2, pH 6.25). The highest product yield of ammonia measured was 53%. Under CO2, the product yield decreases from pH 5.0 to pH 6.9. The increasing concentration of bicarbonate, at higher pH, interferes with the reaction. Comparing experiments under N2 CO2 shows the interference of bicarbonate. The reaction proceeds well in the presence of such species as chloride, sulfate, and phosphate, though the yield drops significantly with phosphate. FeS also reduces nitrate and, unlike with Fe+ 2, the reduction shows more reproducibility. Again, the product yield decreases with increasing pH, from 7% at pH 4.7 to 0% at pH 6.9. It appears that nitrate is much more sensitive to the presence of added species, perhaps not competing as well for binding sites on the FeS surface. This may be the cause of the lack of reproducibility of nitrate reduction by Fe+ 2 (which also can be sensitive to binding by certain species)
Quantum cascade laser-based multipass absorption system for hydrogen peroxide detection
NASA Astrophysics Data System (ADS)
Cao, Yingchun; Sanchez, Nancy P.; Jiang, Wenzhe; Ren, Wei; Lewicki, Rafal; Jiang, Dongfang; Griffin, Robert J.; Tittel, Frank K.
2015-01-01
Hydrogen peroxide (H2O2) is a relevant molecular trace gas species, that is related to the oxidative capacity of the atmosphere, the production of radical species such as OH, the generation of sulfate aerosol via oxidation of S(IV) to S(VI), and the formation of acid rain. The detection of atmospheric H2O2 involves specific challenges due to its high reactivity and low concentration (ppbv to sub-ppbv level). Traditional methods for measuring atmospheric H2O2 concentration are often based on wet-chemistry methods that require a transfer from the gas- to liquid-phase for a subsequent determination by techniques such as fluorescence spectroscopy, which can lead to problems such as sampling artifacts and interference by other atmospheric constituents. A quartz-enhanced photoacoustic spectroscopy-based system for the measurement of atmospheric H2O2 with a detection limit of 75 ppb for 1-s integration time was previously reported. In this paper, an updated H2O2 detection system based on long-optical-path-length absorption spectroscopy by using a distributed feedback quantum cascade laser (DFB-QCL) will be described. A 7.73-μm CW-DFB-QCL and a thermoelectrically cooled infrared detector, optimized for a wavelength of 8 μm, are employed for theH2O2 sensor system. A commercial astigmatic Herriott multi-pass cell with an effective optical path-length of 76 m is utilized for the reported QCL multipass absorption system. Wavelength modulation spectroscopy (WMS) with second harmonic detection is used for enhancing the signal-to-noise-ratio. A minimum detection limit of 13.4 ppb is achieved with a 2 s sampling time. Based on an Allan-Werle deviation analysis the minimum detection limit can be improved to 1.5 ppb when using an averaging time of 300 s.
On the development of a methodology for extensive in-situ and continuous atmospheric CO2 monitoring
NASA Astrophysics Data System (ADS)
Wang, K.; Chang, S.; Jhang, T.
2010-12-01
Carbon dioxide is recognized as the dominating greenhouse gas contributing to anthropogenic global warming. Stringent controls on carbon dioxide emissions are viewed as necessary steps in controlling atmospheric carbon dioxide concentrations. From the view point of policy making, regulation of carbon dioxide emissions and its monitoring are keys to the success of stringent controls on carbon dioxide emissions. Especially, extensive atmospheric CO2 monitoring is a crucial step to ensure that CO2 emission control strategies are closely followed. In this work we develop a methodology that enables reliable and accurate in-situ and continuous atmospheric CO2 monitoring for policy making. The methodology comprises the use of gas filter correlation (GFC) instrument for in-situ CO2 monitoring, the use of CO2 working standards accompanying the continuous measurements, and the use of NOAA WMO CO2 standard gases for calibrating the working standards. The use of GFC instruments enables 1-second data sampling frequency with the interference of water vapor removed from added dryer. The CO2 measurements are conducted in the following timed and cycled manner: zero CO2 measurement, two standard CO2 gases measurements, and ambient air measurements. The standard CO2 gases are calibrated again NOAA WMO CO2 standards. The methodology is used in indoor CO2 measurements in a commercial office (about 120 people working inside), ambient CO2 measurements, and installed in a fleet of in-service commercial cargo ships for monitoring CO2 over global marine boundary layer. These measurements demonstrate our method is reliable, accurate, and traceable to NOAA WMO CO2 standards. The portability of the instrument and the working standards make the method readily applied for large-scale and extensive CO2 measurements.
Improved passive microwave sounding of the atmosphere
NASA Technical Reports Server (NTRS)
Staelin, D. H.; Rosenkranz, P. W.; Schwartz, M. J.
1996-01-01
The effort this year focused primarily on 118-GHz transmittance experiments. The data analyzed here was collected with the Microwave Temperature Sounder (MTS) radiometer package during the CAMEX deployment of 1993 with the aim of validating current models of atmospheric microwave absorption in the O2 bands near 54 and 118 GHz. Particular attention has been paid to data collected during four flights when the MTS scanned zenith while profiles of downwelling radiances were collected through ascents and descents. These radiances, in conjunction with radiosonde temperature data, permit the retrieval of band-averaged absorption profiles for each channel. The Millimeter-wave Propagation Model (MPM92) provides theoretical expressions for the absorption of microwaves by oxygen and water vapor and accounts for the interference of pressure-broadened spectral lines'. This model is a good fit to laboratory measurements at temperatures ranging from 279-327 K, but it has been suggested that extrapolation to the conditions of the atmospheric tropopause may result in underestimation of absorption by as much as 15 percent. Preliminary results of the analysis of MTS data appear to be in general agreement with the predictions of the MPM model to within the accuracy of the measurements, which through the coldest parts of the atmosphere ranges from less than plus or minus 5 percent in the most opaque channels to greater than plus or minus 10 percent in the most transparent channels. At those altitudes where each channel is most sensitive to changes in absorption, there is some indication that the modeled absorption may be biased low relative to the observations. Accurate instrument calibration provided challenges, particularly when observed radiances were as much as 260 K below the temperatures of the cold calibration load.
Atmospheric turbulence affects wind turbine nacelle transferfunctions
DOE Office of Scientific and Technical Information (OSTI.GOV)
St. Martin, Clara M.; Lundquist, Julie K.; Clifton, Andrew
Despite their potential as a valuable source of individual turbine power performance and turbine array energy production optimization information, nacelle-mounted anemometers have often been neglected because complex flows around the blades and nacelle interfere with their measurements. This work quantitatively explores the accuracy of and potential corrections to nacelle anemometer measurements to determine the degree to which they may be useful when corrected for these complex flows, particularly for calculating annual energy production (AEP) in the absence of other meteorological data. Using upwind meteorological tower measurements along with nacelle-based measurements from a General Electric (GE) 1.5sle model, we calculate empiricalmore » nacelle transfer functions (NTFs) and explore how they are impacted by different atmospheric and turbulence parameters. This work provides guidelines for the use of NTFs for deriving useful wind measurements from nacelle-mounted anemometers. Corrections to the nacelle anemometer wind speed measurements can be made with NTFs and used to calculate an AEP that comes within 1 % of an AEP calculated with upwind measurements. We also calculate unique NTFs for different atmospheric conditions defined by temperature stratification as well as turbulence intensity, turbulence kinetic energy, and wind shear. During periods of low stability as defined by the Bulk Richardson number ( RB), the nacelle-mounted anemometer underestimates the upwind wind speed more than during periods of high stability at some wind speed bins below rated speed, leading to a more steep NTF during periods of low stability. Similarly, during periods of high turbulence, the nacelle-mounted anemometer underestimates the upwind wind speed more than during periods of low turbulence at most wind bins between cut-in and rated wind speed. Based on these results, we suggest different NTFs be calculated for different regimes of atmospheric stability and turbulence for power performance validation purposes.« less
Zhang, Yan; Wang, Ping; Guo, Lixin; Wang, Wei; Tian, Hongxin
2017-08-21
The average bit error rate (ABER) performance of an orbital angular momentum (OAM) multiplexing-based free-space optical (FSO) system with multiple-input multiple-output (MIMO) architecture has been investigated over atmospheric turbulence considering channel estimation and space-time coding. The impact of different types of space-time coding, modulation orders, turbulence strengths, receive antenna numbers on the transmission performance of this OAM-FSO system is also taken into account. On the basis of the proposed system model, the analytical expressions of the received signals carried by the k-th OAM mode of the n-th receive antenna for the vertical bell labs layered space-time (V-Blast) and space-time block codes (STBC) are derived, respectively. With the help of channel estimator carrying out with least square (LS) algorithm, the zero-forcing criterion with ordered successive interference cancellation criterion (ZF-OSIC) equalizer of V-Blast scheme and Alamouti decoder of STBC scheme are adopted to mitigate the performance degradation induced by the atmospheric turbulence. The results show that the ABERs obtained by channel estimation have excellent agreement with those of turbulence phase screen simulations. The ABERs of this OAM multiplexing-based MIMO system deteriorate with the increase of turbulence strengths. And both V-Blast and STBC schemes can significantly improve the system performance by mitigating the distortions of atmospheric turbulence as well as additive white Gaussian noise (AWGN). In addition, the ABER performances of both space-time coding schemes can be further enhanced by increasing the number of receive antennas for the diversity gain and STBC outperforms V-Blast in this system for data recovery. This work is beneficial to the OAM FSO system design.
Effect of Particle Non-Sphericity on Satellite Monitoring of Drifting Volcanic Ash Clouds
NASA Technical Reports Server (NTRS)
Krotkov, Nicholay A.; Flittner, D. E.; Krueger, A. J.; Kostinski, A.; Riley, C.; Rose, W.
1998-01-01
Volcanic eruptions loft gases and ash particles into the atmosphere and produce effects that are both short term (aircraft hazards, interference with satellite measurements) and long term (atmospheric chemistry, climate). Large (greater than 0.5mm) ash particles fall out in minutes [Rose et al, 1995], but fine ash particles can remain in the atmosphere for many days. This fine volcanic ash is a hazard to modem jet aircraft because the operating temperatures of jet engines are above the solidus temperature of volcanic ash, and because ash causes abrasion of windows and airframe, and disruption of avionics. At large distances(10(exp 2)-10(exp 4) km or more) from their source, drifting ash clouds are increasingly difficult to distinguish from meteorological clouds, both visually and on radar [Rose et al., 1995]. Satellites above the atmosphere are unique platforms for viewing volcanic clouds on a global basis and measuring their constituents and total mass. Until recently, only polar AVHRR and geostationary GOES instruments could be used to determine characteristics of drifting volcanic ash clouds using the 10-12 micron window [Prata 1989; Wen and Rose 1994; Rose and Schneider 1996]. The NASA Total Ozone Mapping Spectrometer (TOMS) instruments aboard the Nimbus-7, Meteor3, ADEOS, and Earth Probe satellites have produced a unique data set of global SO2 volcanic emissions since 1978 (Krueger et al., 1995). Besides SO2, a new technique has been developed which uses the measured spectral contrast of the backscattered radiances in the 330-380nm spectral region (where gaseous absorption is negligible) in conjunction with radiative transfer models to retrieve properties of volcanic ash (Krotkov et al., 1997) and other types of absorbing aerosols (Torres et al., 1998).
Distribution of CO2 in Saturn's Atmosphere from Cassini/cirs Infrared Observations
NASA Astrophysics Data System (ADS)
Abbas, M. M.; LeClair, A.; Woodard, E.; Young, M.; Stanbro, M.; Flasar, F. M.; Kunde, V. G.; Achterberg, R. K.; Bjoraker, G.; Brasunas, J.; Jennings, D. E.; the Cassini/CIRS Team
2013-10-01
This paper focuses on the CO2 distribution in Saturn's atmosphere based on analysis of infrared spectral observations of Saturn made by the Composite Infrared Spectrometer aboard the Cassini spacecraft. The Cassini spacecraft was launched in 1997 October, inserted in Saturn's orbit in 2004 July, and has been successfully making infrared observations of Saturn, its rings, Titan, and other icy satellites during well-planned orbital tours. The infrared observations, made with a dual Fourier transform spectrometer in both nadir- and limb-viewing modes, cover spectral regions of 10-1400 cm-1, with the option of variable apodized spectral resolutions from 0.53 to 15 cm-1. An analysis of the observed spectra with well-developed radiative transfer models and spectral inversion techniques has the potential to provide knowledge of Saturn's thermal structure and composition with global distributions of a series of gases. In this paper, we present an analysis of a large observational data set for retrieval of Saturn's CO2 distribution utilizing spectral features of CO2 in the Q-branch of the ν2 band, and discuss its possible relationship to the influx of interstellar dust grains. With limited spectral regions available for analysis, due to low densities of CO2 and interference from other gases, the retrieved CO2 profile is obtained as a function of a model photochemical profile, with the retrieved values at atmospheric pressures in the region of ~1-10 mbar levels. The retrieved CO2 profile is found to be in good agreement with the model profile based on Infrared Space Observatory measurements with mixing ratios of ~4.9 × 10-10 at atmospheric pressures of ~1 mbar.
Novel Method for Detection of Air Pollution using Cellular Communication Networks
NASA Astrophysics Data System (ADS)
David, N.; Gao, O. H.
2016-12-01
Air pollution can lead to a wide spectrum of severe and chronic health impacts. Conventional tools for monitoring the phenomenon do not provide a sufficient monitoring solution in a global scale since they are, for example, not representative of the larger space or due to limited deployment as a result of practical limitations, such as: acquisition, installation, and ongoing maintenance costs. Near ground temperature inversions are directly identified with air pollution events since they suppress vertical atmospheric movement and trap pollutants near the ground. Wireless telecommunication links that comprise the data transfer infrastructure in cellular communication networks operate at frequencies of tens of GHz and are affected by different atmospheric phenomena. These systems are deployed near ground level across the globe, including in developing countries such as India, countries in Africa, etc. Many cellular providers routinely store data regarding the received signal levels in the network for quality assurance needs. Temperature inversions cause atmospheric layering, and change the refractive index of the air when compared to standard conditions. As a result, the ducts that are formed can operate, in essence, as atmospheric wave guides, and cause interference (signal amplification / attenuation) in the microwaves measured by the wireless network. Thus, this network is in effect, an existing system of environmental sensors for monitoring temperature inversions and the episodes of air pollution identified with them. This work presents the novel idea, and demonstrates it, in operation, over several events of air pollution which were detected by a standard cellular communication network during routine operation. Reference: David, N. and Gao, H.O. Using cellular communication networks to detect air pollution, Environmental Science & Technology, 2016 (accepted).
Atmospheric turbulence affects wind turbine nacelle transferfunctions
St. Martin, Clara M.; Lundquist, Julie K.; Clifton, Andrew; ...
2017-06-02
Despite their potential as a valuable source of individual turbine power performance and turbine array energy production optimization information, nacelle-mounted anemometers have often been neglected because complex flows around the blades and nacelle interfere with their measurements. This work quantitatively explores the accuracy of and potential corrections to nacelle anemometer measurements to determine the degree to which they may be useful when corrected for these complex flows, particularly for calculating annual energy production (AEP) in the absence of other meteorological data. Using upwind meteorological tower measurements along with nacelle-based measurements from a General Electric (GE) 1.5sle model, we calculate empiricalmore » nacelle transfer functions (NTFs) and explore how they are impacted by different atmospheric and turbulence parameters. This work provides guidelines for the use of NTFs for deriving useful wind measurements from nacelle-mounted anemometers. Corrections to the nacelle anemometer wind speed measurements can be made with NTFs and used to calculate an AEP that comes within 1 % of an AEP calculated with upwind measurements. We also calculate unique NTFs for different atmospheric conditions defined by temperature stratification as well as turbulence intensity, turbulence kinetic energy, and wind shear. During periods of low stability as defined by the Bulk Richardson number ( RB), the nacelle-mounted anemometer underestimates the upwind wind speed more than during periods of high stability at some wind speed bins below rated speed, leading to a more steep NTF during periods of low stability. Similarly, during periods of high turbulence, the nacelle-mounted anemometer underestimates the upwind wind speed more than during periods of low turbulence at most wind bins between cut-in and rated wind speed. Based on these results, we suggest different NTFs be calculated for different regimes of atmospheric stability and turbulence for power performance validation purposes.« less
Quantitative fluid inclusion gas analysis of airburst, nuclear, impact and fulgurite glasses.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Parnell, John; Newsom, Horton E.; Blamey, Nigel J. F.
We present quantitative fluid inclusion gas analysis on a suite of violently-formed glasses. We used the incremental crush mass spectrometry method (Norman & Blamey, 2001) to analyze eight pieces of Libyan Desert Glass (LDG). As potential analogues we also analyzed trinitite, three impact crater glasses, and three fulgurites. The 'clear' LDG has the lowest CO{sub 2} content and O{sub 2}/Ar ratios are two orders of magnitude lower than atmospheric. The 'foamy' glass samples have heterogeneous CO{sub 2} contents and O{sub 2}/Ar ratios. N{sub 2}/Ar ratios are similar to atmospheric (83.6). H{sub 2} and He are elevated but it is difficultmore » to confirm whether they are of terrestrial or meteoritic origin. Combustion cannot account for oxygen depletion that matches the amount of CO{sub 2} produced. An alternative mechanism is required that removes oxygen without producing CO{sub 2}. Trinitite has exceedingly high CO{sub 2} which we attribute to carbonate breakdown of the caliche at ground zero. The O{sub 2}/Ar ratio for trinitite is lower than atmospheric but higher than all LDG samples. N{sub 2}/Ar ratios closely match atmospheric. Samples from Lonar, Henbury and Aouelloul impact craters have atmospheric N{sub 2}/Ar ratios. O{sub 2}/Ar ratios at Lonar and Henbury are 9.5 to 9.9 whereas the O{sub 2}/Ar ratio is 0.1 for the Aouelloul sample. In most fulgurites the N{sub 2}/Ar ratio is higher than atmospheric, possibly due to interference from CO. Oxygen ranges from 1.3 to 19.3%. Gas signatures of LDG inclusions neither match those from the craters, trinitite nor fulgurites. It is difficult to explain both the observed depletion of oxygen in the LDG and a CO{sub 2} level that is lower than it would be if the CO{sub 2} were simply a product of hydrocarbon combustion in air. One possible mechanism for oxygen depletion is that as air turbulently mixed with a hot jet of vaporized asteroid from an airburst and expanded, the atmospheric oxygen reacted with the metal vapor to form metal oxides that condensed. This observation is compatible with the model of Boslough & Crawford (2008) who suggest that an airburst incinerates organic materials over a large area, melting surface materials that then quench to form glass. Bubbles would contain a mixture of pre-existing atmosphere with combustion products from organic material and products of the reaction between vaporized cosmic materials (including metals) and terrestrial surface and atmosphere.« less
NASA Technical Reports Server (NTRS)
Hanson, D. B.
1977-01-01
Pressure transducers were installed on the blades and vanes of QF-1B, a transonic-tip-speed fan from the NASA Quiet Fan Program which was tested on the outdoor quiet fan test facility at NASA-Lewis. Signals from the transducers and from far field microphones were analyzed to determine sources of nonuniform inflow and noise. The nonuniform inflow was mostly unsteady with roughly equal contributions from atmospheric turbulence and rig interference. The rig interference was largest at the bottom and appeared to be generated by the support structure which was located behind the inlet lip under the fan. Interaction of this inflow distortion was the dominant source of noise at 1, 2, and 3 times blade passing frequency (BPF) at 60, 70, and 80 percent of design speed. At 90 percent speed, noise at BPF was dominated by the steady rotor field. A broadband spectrum peak centered at about 2.2 times BPF was identified as rotor/stator interaction stemming from a high frequency rotor exit flow component. The remaining broadband energy from 0.3 to 3.5 times BPF was attributed to the better known type of rotor/stator interaction associated with rotor wake turbulence.
Evaluating the performance of low cost chemical sensors for air pollution research.
Lewis, Alastair C; Lee, James D; Edwards, Peter M; Shaw, Marvin D; Evans, Mat J; Moller, Sarah J; Smith, Katie R; Buckley, Jack W; Ellis, Matthew; Gillot, Stefan R; White, Andrew
2016-07-18
Low cost pollution sensors have been widely publicized, in principle offering increased information on the distribution of air pollution and a democratization of air quality measurements to amateur users. We report a laboratory study of commonly-used electrochemical sensors and quantify a number of cross-interferences with other atmospheric chemicals, some of which become significant at typical suburban air pollution concentrations. We highlight that artefact signals from co-sampled pollutants such as CO2 can be greater than the electrochemical sensor signal generated by the measurand. We subsequently tested in ambient air, over a period of three weeks, twenty identical commercial sensor packages alongside standard measurements and report on the degree of agreement between references and sensors. We then explore potential experimental approaches to improve sensor performance, enhancing outputs from qualitative to quantitative, focusing on low cost VOC photoionization sensors. Careful signal handling, for example, was seen to improve limits of detection by one order of magnitude. The quantity, magnitude and complexity of analytical interferences that must be characterised to convert a signal into a quantitative observation, with known uncertainties, make standard individual parameter regression inappropriate. We show that one potential solution to this problem is the application of supervised machine learning approaches such as boosted regression trees and Gaussian processes emulation.
Noise and interference study for satellite lightning sensor
NASA Technical Reports Server (NTRS)
Herman, J. R.
1981-01-01
The use of radio frequency techniques for the detection and monitoring of terrestrial thunderstorms from space are discussed. Three major points are assessed: (1) lightning and noise source characteristics; (2) propagation effects imposed by the atmosphere and ionosphere; and (3) the electromagnetic environment in near space within which lightning RF signatures must be detected. A composite frequency spectrum of the peak of amplitude from lightning flashes is developed. Propagation effects (ionospheric cutoff, refraction, absorption, dispersion and scintillation) are considered to modify the lightning spectrum to the geosynchronous case. It is suggested that in comparing the modified spectrum with interfering noise source spectra RF lightning pulses on frequencies up to a few GHz are detectable above the natural noise environment in near space.
NASA Astrophysics Data System (ADS)
Carlson, Scott M.
1993-06-01
The design of a high resolution plane grating all-reflection Michelson interferometer for ionospheric spectroscopy was analyzed using ray tracing techniques. This interferometer produces an interference pattern whose spatial frequency is wavelength dependent. The instrument is intended for remote observations of the atomic oxygen triplet emission line profile at 1304 A in the thermosphere from sounding rocket or satellite platforms. The device was modeled using the PC-based ray tracing application, DART, and results analyzed through fourier techniques using the PC with Windows version of the Interactive Data Language (IDL). Through these methods, instrument resolution, resolving power, and bandpass were determined. An analysis of the effects of aperture size and shape on instrument performance was also conducted.
G-133: A soft x ray solar telescope
NASA Technical Reports Server (NTRS)
Williams, Memorie K.; Campbell, Branton; Roming, Peter W. A.; Spute, Mark K.; Moody, J. Ward
1992-01-01
The GOLDHELOX Project, NASA payload number G-133, is a robotic soft x ray solar telescope designed and built by an organization of undergraduate students. The telescope is designed to observe the sun at a wavelength of 171 to 181 A. Since we require observations free from atmospheric interference, the telescope will be launched in a NASA Get-Away-Special (GAS) canister with a Motorized Door Assembly (MDA). In this paper we primarily discuss the most important elements of the telescope itself. We also elaborate on some of the technical difficulties associated with doing good science in space on a small budget (about $100,000) and mention ways in which controlling the instrument environment has reduced the complexity of the system and thus saved us money.
Carbon Lock-In: Barriers to the Deployment of Climate Change Mitigation Technologies
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lapsa, Melissa Voss; Brown, Marilyn A.
The United States shares with many other countries the objective of stabilizing greenhouse gas (GHG) concentrations in the Earth's atmosphere at a level that would prevent dangerous interference with the climate system. Many believe that accelerating the pace of technology improvement and deployment could significantly reduce the cost of achieving this goal. The critical role of new technologies is underscored by the fact that most anthropogenic greenhouse gases emitted over the next century will come from equipment and infrastructure built in the future. As a result, new technologies and fuels have the potential to transform the nation's energy system whilemore » meeting climate change as well as energy security and other goals.« less
Effetto black drop e istanti dei contatti nel transito di Venere sul Sole
NASA Astrophysics Data System (ADS)
di Giovanni, Giovanni
2005-04-01
Digital measurements of the chords common to the Sun and Venus during the transit of 8 June 2004 are reported. The time of the four contacts of the planet with the solar limb are calculated resolving the relative equations for entry and exit phases. The solutions were obtained with least square methods applied to experimental data with analytical functions used by different Authors during the Sun's eclipses. The well-known black drop effect was observed during the third contact. Atmospheric turbulence and optical effects interfere making timings uncertain by at least one second. There is also a comment about the numerical values and the estimate of the experimental errors. The observations were made by four high school students.
VIRTIS on Venus Express: retrieval of real surface emissivity on global scales
NASA Astrophysics Data System (ADS)
Arnold, Gabriele E.; Kappel, David; Haus, Rainer; Telléz Pedroza, Laura; Piccioni, Giuseppe; Drossart, Pierre
2015-09-01
The extraction of surface emissivity data provides the data base for surface composition analyses and enables to evaluate Venus' geology. The Visible and InfraRed Thermal Imaging Spectrometer (VIRTIS) aboard ESA's Venus Express mission measured, inter alia, the nightside thermal emission of Venus in the near infrared atmospheric windows between 1.0 and 1.2 μm. These data can be used to determine information about surface properties on global scales. This requires a sophisticated approach to understand and consider the effects and interferences of different atmospheric and surface parameters influencing the retrieved values. In the present work, results of a new technique for retrieval of the 1.0 - 1.2 μm - surface emissivity are summarized. It includes a Multi-Window Retrieval Technique, a Multi-Spectrum Retrieval technique (MSR), and a detailed reliability analysis. The MWT bases on a detailed radiative transfer model making simultaneous use of information from different atmospheric windows of an individual spectrum. MSR regularizes the retrieval by incorporating available a priori mean values, standard deviations as well as spatial-temporal correlations of parameters to be retrieved. The capability of this method is shown for a selected surface target area. Implications for geologic investigations are discussed. Based on these results, the work draws conclusions for future Venus surface composition analyses on global scales using spectral remote sensing techniques. In that context, requirements for observational scenarios and instrumental performances are investigated, and recommendations are derived to optimize spectral measurements for Venus' surface studies.
Open-path FTIR data reduction algorithm with atmospheric absorption corrections: the NONLIN code
NASA Astrophysics Data System (ADS)
Phillips, William; Russwurm, George M.
1999-02-01
This paper describes the progress made to date in developing, testing, and refining a data reduction computer code, NONLIN, that alleviates many of the difficulties experienced in the analysis of open path FTIR data. Among the problems that currently effect FTIR open path data quality are: the inability to obtain a true I degree or background, spectral interferences of atmospheric gases such as water vapor and carbon dioxide, and matching the spectral resolution and shift of the reference spectra to a particular field instrument. This algorithm is based on a non-linear fitting scheme and is therefore not constrained by many of the assumptions required for the application of linear methods such as classical least squares (CLS). As a result, a more realistic mathematical model of the spectral absorption measurement process can be employed in the curve fitting process. Applications of the algorithm have proven successful in circumventing open path data reduction problems. However, recent studies, by one of the authors, of the temperature and pressure effects on atmospheric absorption indicate there exist temperature and water partial pressure effects that should be incorporated into the NONLIN algorithm for accurate quantification of gas concentrations. This paper investigates the sources of these phenomena. As a result of this study a partial pressure correction has been employed in NONLIN computer code. Two typical field spectra are examined to determine what effect the partial pressure correction has on gas quantification.
Gornushkin, Igor B; Stevenson, Chris L; Galbács, Gábor; Smith, Ben W; Winefordner, James D
2003-11-01
The production of ozone nad nitrogen oxides was studied during multiple laser breakdown in oxygen-nitrogen mixtures at atmospheric pressure. About 2000 laser shots at 10(10) W cm-2 were delivered into a sealed reaction chamber. The chamber with a long capillary was designed to measure absorption of O3, NO, and NO2 as a function of the number of laser shots. The light source for absorption measurements was the continuum radiation emitted by the plasma during the first 0.2 microsecond of its evolution. A kinetic model was developed that encompassed the principal chemical reactions between the major atmospheric components and the products of laser breakdown. In the model, the laser plasma was treated as a source of nitric oxide and atomic oxygen, whose rates of production were calculated using measured absorption by NO, NO2, and O3. The calculated concentration profiles for NO, NO2, and O3 were in good agreement with measured profiles over a time scale of 0-200 s. The steady-state concentration of ozone was measured in a flow cell in air. For a single breakdown in air, the estimated steady-state yield of ozone was 2 x 10(12) molecules, which agreed with the model prediction. This study can be of importance for general understanding of laser plasma chemistry and for elucidating the nature of spectral interferences and matrix effects that may take place in applied spectrochemical analysis.
NASA Astrophysics Data System (ADS)
Celaya, Michael A.; Wahr, John M.; Bryan, Frank O.
1999-06-01
The output of a coupled climate system model provides a synthetic climate record with temporal and spatial coverage not attainable with observational data, allowing evaluation of climatic excitation of polar motion on timescales of months to decades. Analysis of the geodetically inferred Chandler excitation power shows that it has fluctuated by up to 90% since 1900 and that it has characteristics representative of a stationary Gaussian process. Our model-predicted climate excitation of the Chandler wobble also exhibits variable power comparable to the observed. Ocean currents and bottom pressure shifts acting together can alone drive the 14-month wobble. The same is true of the excitation generated by the combined effects of barometric pressure and winds. The oceanic and atmospheric contributions are this large because of a relatively high degree of constructive interference between seafloor pressure and currents and between atmospheric pressure and winds. In contrast, excitation by the redistribution of water on land appears largely insignificant. Not surprisingly, the full climate effect is even more capable of driving the wobble than the effects of the oceans or atmosphere alone are. Our match to the observed annual excitation is also improved, by about 17%, over previous estimates made with historical climate data. Efforts to explain the 30-year Markowitz wobble meet with less success. Even so, at periods ranging from months to decades, excitation generated by a model of a coupled climate system makes a close approximation to the amplitude of what is geodetically observed.
[Open-path online monitoring of ambient atmospheric CO2 based on laser absorption spectrum].
He, Ying; Zhang, Yu-Jun; Kan, Rui-Feng; Xia, Hui; Geng, Hui; Ruan, Jun; Wang, Min; Cui, Xiao-Juan; Liu, Wen-Qing
2009-01-01
With the conjunction of tunable diode laser absorption spectroscopy technology (TDLAS) and the open long optical path technology, the system designing scheme of CO2 on-line monitoring based on near infrared tunable diode laser absorption spectroscopy technology was discussed in detail, and the instrument for large-range measurement was set up. By choosing the infrared absorption line of CO2 at 1.57 microm whose line strength is strong and suitable for measurement, the ambient atmospheric CO2 was measured continuously with a 30 s temporal resolution at an suburb site in the autumn of 2007. The diurnal atmospheric variations of CO2 and continuous monitoring results were presented. The results show that the variation in CO2 concentration has an obvious diurnal periodicity in suburb where the air is free of interference and contamination. The general characteristic of diurnal variation is that the concentration is low in the daytime and high at night, so it matches the photosynthesis trend. The instrument can detect gas concentration online with high resolution, high sensitivity, high precision, short response time and many other advantages, the monitoring requires no gas sampling, the calibration is easy, and the detection limit is about 4.2 x 10(-7). It has been proved that the system and measurement project are feasible, so it is an effective method for gas flux continuous online monitoring of large range in ecosystem based on TDLAS technology.
Satellite Ocean Color Validation Using Merchant Ships. Chapter 10
NASA Technical Reports Server (NTRS)
Frouin, Robert; Cutchin, David L.; Deschamps, Pierre-Yves
2001-01-01
A collaborative measurement program for evaluating satellite-derived ocean color has been developed based on ships of opportunity (merchant, oceanographic) and specific instrumentation, the SIMBAD radiometer. The purpose of the measurement program is to complement, in a cost-effective way, dedicated evaluation experiments at sea, which are expensive, cannot be carried out over the full range of expected oceanic and atmospheric conditions, and generally provide a few match-ups. Ships participate in the program on a volunteer basis or at a very small cost, and measurement procedures do not interfere with other ship activities. The SIMBAD radiometer is a portable, easy-to-operate instrument that measures the basic ocean color variables, namely aerosol optical thickness and water-leaving radiance, in typical spectral bands of ocean-color sensors, i.e., 443, 490, 560, 670, and 870 nm. Measuring these variables at the time of satellite overpass is usually sufficient to verify satellite-derived ocean color and to evaluate atmospheric correction algorithms. Any ordinary crew can learn quickly how to make measurements. Importantly, the ship is not required to stop, making it possible to collect data along regular routes traveled by merchant ships in the world's oceans.
Cheng, Irene; Zhang, Leiming
2017-01-17
Gaseous oxidized mercury (GOM) measurement uncertainties undoubtedly impact the understanding of mercury biogeochemical cycling; however, there is a lack of consensus on the uncertainty magnitude. The numerical method presented in this study provides an alternative means of estimating the uncertainties of previous GOM measurements. Weekly GOM in ambient air was predicted from measured weekly mercury wet deposition using a scavenging ratio approach, and compared against field measurements of 2-4 hly GOM to estimate the measurement biases of the Tekran speciation instruments at 13 Atmospheric Mercury Network (AMNet) sites. Multiyear average GOM measurements were estimated to be biased low by more than a factor of 2 at six sites, between a factor of 1.5 and 1.8 at six other sites, and below a factor of 1.3 at one site. The differences between predicted and observed were significantly larger during summer than other seasons potentially because of higher ozone concentrations that may interfere with GOM sampling. The analysis data collected over six years at multiple sites suggests a systematic bias in GOM measurements, supporting the need for further investigation of measurement technologies and identifying the chemical composition of GOM.
Automated test-site radiometer for vicarious calibration
NASA Astrophysics Data System (ADS)
Li, Xin; Yin, Ya-peng; Liu, En-chao; Zhang, Yan-na; Xun, Li-na; Wei, Wei; Zhang, Zhi-peng; Qiu, Gang-gang; Zhang, Quan; Zheng, Xiao-bing
2014-11-01
In order to realize unmanned vicarious calibration, Automated Test-site Radiometer (ATR) was developed for surface reflectance measurements. ATR samples the spectrum from 400nm-1600 nm with 8 interference filters coupled with silicon and InGaAs detectors. The field of view each channel is 10 ° with parallel optical axis. One SWIR channel lies in the center and the other seven VNIR channels are on the circle of 4.8cm diameters which guarantee each channel to view nearly the same section of ground. The optical head as a whole is temperature controlled utilizing a TE cooler for greater stability and lower noise. ATR is powered by a solar panel and transmit its data through a BDS (China's BeiDou Navigation Satellite System) terminator for long-term measurements without personnel in site. ATR deployed in Dunhuang test site with ground field about 30-cm-diameter area for multi-spectral reflectance measurements. Other instruments at the site include a Cimel sunphotometer and a diffuser-to-globe irradiance meter for atmosphere observations. The methodology for band-averaged reflectance retrieval and hyperspectral reflectance fitting process are described. Then the hyperspectral reflectance and atmospheric parameters are put into 6s code to predict TOA radiance which compare with MODIS radiance.
Extrapolating cosmic ray variations and impacts on life: Morlet wavelet analysis
NASA Astrophysics Data System (ADS)
Zarrouk, N.; Bennaceur, R.
2009-07-01
Exposure to cosmic rays may have both a direct and indirect effect on Earth's organisms. The radiation may lead to higher rates of genetic mutations in organisms, or interfere with their ability to repair DNA damage, potentially leading to diseases such as cancer. Increased cloud cover, which may cool the planet by blocking out more of the Sun's rays, is also associated with cosmic rays. They also interact with molecules in the atmosphere to create nitrogen oxide, a gas that eats away at our planet's ozone layer, which protects us from the Sun's harmful ultraviolet rays. On the ground, humans are protected from cosmic particles by the planet's atmosphere. In this paper we give estimated results of wavelet analysis from solar modulation and cosmic ray data incorporated in time-dependent cosmic ray variation. Since solar activity can be described as a non-linear chaotic dynamic system, methods such as neural networks and wavelet methods should be very suitable analytical tools. Thus we have computed our results using Morlet wavelets. Many have used wavelet techniques for studying solar activity. Here we have analysed and reconstructed cosmic ray variation, and we have better depicted periods or harmonics other than the 11-year solar modulation cycles.
High reliability outdoor sonar prototype based on efficient signal coding.
Alvarez, Fernando J; Ureña, Jesús; Mazo, Manuel; Hernández, Alvaro; García, Juan J; de Marziani, Carlos
2006-10-01
Many mobile robots and autonomous vehicles designed for outdoor operation have incorporated ultrasonic sensors in their navigation systems, whose function is mainly to avoid possible collisions with very close obstacles. The use of these systems in more precise tasks requires signal encoding and the incorporation of pulse compression techniques that have already been used with success in the design of high-performance indoor sonars. However, the transmission of ultrasonic encoded signals outdoors entails a new challenge because of the effects of atmospheric turbulence. This phenomenon causes random fluctuations in the phase and amplitude of traveling acoustic waves, a fact that can make the encoded signal completely unrecognizable by its matched receiver. Atmospheric turbulence is investigated in this work, with the aim of determining the conditions under which it is possible to assure the reliable outdoor operation of an ultrasonic pulse compression system. As a result of this analysis, a novel sonar prototype based on complementary sequences coding is developed and experimentally tested. This encoding scheme provides the system with very useful additional features, namely, high robustness to noise, multi-mode operation capability (simultaneous emissions with minimum cross talk interference), and the possibility of applying an efficient detection algorithm that notably decreases the hardware resource requirements.
Tropospheric OH and HO2 radicals: field measurements and model comparisons.
Stone, Daniel; Whalley, Lisa K; Heard, Dwayne E
2012-10-07
The hydroxyl radical, OH, initiates the removal of the majority of trace gases in the atmosphere, and together with the closely coupled species, the hydroperoxy radical, HO(2), is intimately involved in the oxidation chemistry of the atmosphere. This critical review discusses field measurements of local concentrations of OH and HO(2) radicals in the troposphere, and in particular the comparisons that have been made with numerical model calculations containing a detailed chemical mechanism. The level of agreement between field measurements of OH and HO(2) concentrations and model calculations for a given location provides an indication of the degree of understanding of the underlying oxidation chemistry. We review the measurement-model comparisons for a range of different environments sampled from the ground and from aircraft, including the marine boundary layer, continental low-NO(x) regions influenced by biogenic emissions, the polluted urban boundary layer, and polar regions. Although good agreement is found for some environments, there are significant discrepancies which remain unexplained, a notable example being unpolluted, forested regions. OH and HO(2) radicals are difficult species to measure in the troposphere, and we also review changes in detection methodology, quality assurance procedures such as instrument intercomparisons, and potential interferences.
Negative CO2 emissions via enhanced silicate weathering in coastal environments
Montserrat, Francesc
2017-01-01
Negative emission technologies (NETs) target the removal of carbon dioxide (CO2) from the atmosphere, and are being actively investigated as a strategy to limit global warming to within the 1.5–2°C targets of the 2015 UN climate agreement. Enhanced silicate weathering (ESW) proposes to exploit the natural process of mineral weathering for the removal of CO2 from the atmosphere. Here, we discuss the potential of applying ESW in coastal environments as a climate change mitigation option. By deliberately introducing fast-weathering silicate minerals onto coastal sediments, alkalinity is released into the overlying waters, thus creating a coastal CO2 sink. Compared with other NETs, coastal ESW has the advantage that it counteracts ocean acidification, does not interfere with terrestrial land use and can be directly integrated into existing coastal management programmes with existing (dredging) technology. Yet presently, the concept is still at an early stage, and so two major research challenges relate to the efficiency and environmental impact of ESW. Dedicated experiments are needed (i) to more precisely determine the weathering rate under in situ conditions within the seabed and (ii) to evaluate the ecosystem impacts—both positive and negative—from the released weathering products. PMID:28381634
NASA Technical Reports Server (NTRS)
Chutijian, Ara; Boumsellek, S.; Alajajian, S. H.
1992-01-01
In the search for high sensitivity and direct atmospheric sampling of trace species, techniques have been developed such as atmospheric-sampling, glow-discharge ionization (ASGDI), corona discharge, atmospheric pressure ionization (API), electron-capture detection (ECD), and negative-ion chemical ionization (NICI) that are capable of detecting parts-per-billion to parts-per-trillion concentrations of trace species. These techniques are based on positive- or negative-ion formation via charge-transfer to the target, or electron capture under multiple-collision conditions in a Maxwellian distribution of electron energies at the source temperature. One drawback of the high-pressure, corona- or glow-discharge devices is that they are susceptible to interferences either through indistinguishable product masses, or through undesired ion-molecule reactions. The ASGDI technique is relatively immune from such interferences, since at target concentrations of less than 1 ppm the majority of negative ions arises via electron capture rather than through ion-molecule chemistry. A drawback of the conventional ECD, and possibly of the ASGDI, is that they exhibit vanishingly small densities of electrons with energies in the range 0-10 millielectron volts (meV), as can be seen from a typical Maxwellian electron energy distribution function at T = 300 K. Slowing the electrons to these subthermal (less than 10 meV) energies is crucial, since the cross section for attachment of several large classes of molecules is known to increase to values larger than 10(exp -12) sq cm at near-zero electron energies. In the limit of zero energy these cross sections are predicted to diverge as epsilon(exp -1/2), where epsilon is the electron energy. In order to provide a better 'match' between the electron energy distribution function and attachment cross section, a new concept of attachment in an electrostatic mirror was developed. In this scheme, electrons are brought to a momentary halt by reversing their direction with electrostatic fields. At this turning point the electrons have zero or near-zero energy. A beam of target molecules is introduced, and the resultant negative ions extracted. This basic idea has been recently improved to allow for better reversal geometry, higher electron currents, lower backgrounds, and increased negative-ion extraction efficiency. We present herein application of the so-called reversal electron attachment detector (READ) to the study of negative-ion formation in the explosives molecules RDX, PETN, and TNT under single-collision conditions.
An advanced technique for speciation of organic nitrogen in atmospheric aerosols
NASA Astrophysics Data System (ADS)
Samy, S.; Robinson, J.; Hays, M. D.
2011-12-01
The chemical composition of organic nitrogen (ON) in the environment is a research topic of broad significance. The topic intersects the branches of atmospheric, aquatic, and ecological science; thus, a variety of instrumentation, analytical methods, and data interpretation tools have evolved for determination of ON. Recent studies that focus on atmospheric particulate nitrogen (N) suggest a significant fraction (20-80%) of total N is bound in organic compounds. The sources, bioavailability and transport mechanisms of these N-containing compounds can differ, producing a variety of environmental consequences. Amino acids (AA) are a key class of atmospheric ON compounds that can contribute to secondary organic aerosol (SOA) formation and potentially influence water cycles, air pollutant scavenging, and the radiation balance. AA are water-soluble organic compounds (WSOC) that can significantly alter the acid-base chemistry of aerosols, and may explain the buffering capacity that impacts heterogeneous atmospheric chemistry. The chemical transformations that N-containing organic compounds (including AA) undergo can increase the light-absorbing capacity of atmospheric carbon via formation of 'brown carbon'. Suggested sources of atmospheric AA include: marine surface layer transport from bursting sea bubbles, the suspension of bacteria, fungi, algae, pollen, spores, or biomass burning. Methodology for detection of native (underivatized) amino acids (AA) in atmospheric aerosols has been developed and validated (Samy et al., 2011). This presentation describes the use of LC-MS (Q-TOF) and microwave-assisted gas phase hydrolysis for detection of free and combined amino acids in aerosols collected in a Southeastern U.S. forest environment. Accurate mass detection and the addition of isotopically labeled surrogates prior to sample preparation allows for sensitive quantitation of target AA in a complex aerosol matrix. A total of 16 native AA were detected above the reporting threshold as water-soluble free AA, with an average concentration of 22 ± 9 ng m-3 (N=13). Following microwave-assisted gas phase hydrolysis, the total AA concentration in the forest environment increased significantly (70 ± 35 ng m-3) and additional compounds (methionine, isoleucine) were detected above the reporting threshold. The ability to quantify AA in aerosol samples without derivatization reduces time consuming preparation procedures while providing the advancement of selective mass determination that eliminates potential interferences associated with traditional fluorescence detection. This step forward in precise mass determination with the use of internal standardization, improves the confidence of compound identification. With the increasing focus on WSOC (including ON) characterization in the atmospheric science community, native detection by LC-MS (Q-TOF) will play a central role in determining the most direct approach to quantify an increasing fraction of the co-extracted polar organic compounds. Method application for further characterization of atmospheric ON will be discussed. Reference: Samy, S., Robinson, J., and M.D. Hays. "An Advanced LC-MS (Q-TOF) Technique for the Detection of Amino Acids in Atmospheric Aerosols", Analytical Bioanalytical Chemistry, 2011, DOI: 10.1007/s00216-011-5238-2
Zhang, Lai; Andersen, Ken H; Dieckmann, Ulf; Brännström, Åke
2015-09-07
We investigate how four types of interference competition - which alternatively affect foraging, metabolism, survival, and reproduction - impact the ecology and evolution of size-structured populations. Even though all four types of interference competition reduce population biomass, interference competition at intermediate intensity sometimes significantly increases the abundance of adult individuals and the population׳s reproduction rate. We find that foraging and metabolic interference evolutionarily favor smaller maturation size when interference is weak and larger maturation size when interference is strong. The evolutionary response to survival interference and reproductive interference is always larger maturation size. We also investigate how the four types of interference competition impact the evolutionary dynamics and resultant diversity and trophic structure of size-structured communities. Like other types of trait-mediated competition, all four types of interference competition can induce disruptive selection and thus promote initial diversification. Even though foraging interference and reproductive interference are more potent in promoting initial diversification, they catalyze the formation of diverse communities with complex trophic structure only at high levels of interference intensity. By contrast, survival interference does so already at intermediate levels, while reproductive interference can only support relatively smaller communities with simpler trophic structure. Taken together, our results show how the type and intensity of interference competition jointly affect coexistence patterns in structured population models. Copyright © 2015 Elsevier Ltd. All rights reserved.
NASA Technical Reports Server (NTRS)
Zubrin, Robert; Price, Steve; Clark, Ben; Cantrell, Jim; Bourke, Roger
1993-01-01
A Mars Aerial Platform (MAP) mission capable of generating thousands of very-high-resolution (20 cm/pixel) pictures of the Martian surface is considered. The MAP entry vehicle will map the global circulation of the planet's atmosphere and examine the surface and subsurface. Data acquisition will use instruments carried aboard balloons flying at nominal altitude of about 7 km over the Martian surface. The MAP balloons will take high- and medium-resolution photographs of Mars, sound its surface with radar, and provide tracking data to chart its winds. Mars vehicle design is based on the fourth-generation NTP, NEP, SEP vehicle set that provides a solid database for determining transportation system costs. Interference analysis and 3D image generation are performed using manual system sizing and sketching in conjunction with precise CAD modeling.
Photoelectric photometry of comet Kohoutek (1973f)
NASA Technical Reports Server (NTRS)
Kohoutek, L.
1976-01-01
Comet Kohoutek was observed with the 50 cm (f/15) reflecting telescope of the European Southern Observatory, La Silla, Chile, on fourteen nights between January 16 and 30, when the heliocentric and geocentric distances of the comet were r=0.66 - 1.00 A.U. and delta=0.81 - 0.96 A.U., respectively. The 40 inch and 80 inch diaphragms were used for the photometry of the cometary head in the UBV system and with six interference filters. The atmospheric conditions were good but the accuracy of observations was low due to large extinction and twilight. The mean error of one measurement of log F in all but Na 5893 A filters can be estimated at plus or minus 0.02, whereas the accuracy through the Na filter was substantially lower.
Collisional desorption of NO by fast O atoms
NASA Technical Reports Server (NTRS)
Sonnenfroh, David M.; Caledonia, George E.
1993-01-01
Surface-adsorbed NO figures largely in the mechanism that produces visible glow around spacecraft in low Earth orbit (LEO). In view of the potential interference to optical observations such a glow represents, we have investigated the collision-induced desorption of NO from Al, Ni, and Z306 Chemglaze-coated surfaces at 96 K by hyperthermal (8 km/s) oxygen atoms. The removal of surface NO was followed by the monitoring of the visible fluorescence of electronically excited NO2 produced through the surface-mediated reaction O + NO. A variability in collisional desorption rate with material was observed. The limited data suggest a removal efficiency of 4 to 8% of the impinging O atom flux. Implications for the atmospheric scouring of contaminants from external surfaces of LEO spacecraft are discussed.
NASA Astrophysics Data System (ADS)
Li, Ruixiao; Li, Kun; Zhao, Changming
2018-01-01
Coherent dual-frequency Lidar (CDFL) is a new development of Lidar which dramatically enhances the ability to decrease the influence of atmospheric interference by using dual-frequency laser to measure the range and velocity with high precision. Based on the nature of CDFL signals, we propose to apply the multiple signal classification (MUSIC) algorithm in place of the fast Fourier transform (FFT) to estimate the phase differences in dual-frequency Lidar. In the presence of Gaussian white noise, the simulation results show that the signal peaks are more evident when using MUSIC algorithm instead of FFT in condition of low signal-noise-ratio (SNR), which helps to improve the precision of detection on range and velocity, especially for the long distance measurement systems.
NASA Astrophysics Data System (ADS)
1989-01-01
A "NASA Tech Briefs" article describing an inspection tool and technique known as Optically Stimulated Electron Emission (OSEE) led to the formation of Photo Acoustic Technology, Inc. (PAT). PAT produces sensors and scanning systems which assure surface cleanliness prior to bonding, coating, painting, etc. The company's OP1000 series realtime pre-processing detection capability assures 100 percent surface quality testing. The technique involves brief exposure of the inspection surface to ultraviolet radiation. The energy interacts with the surface layer, causing free electrons to be emitted from the surface to be picked up by the detector. When contamination is present, it interferes with the electron flow in proportion to the thickness of the contaminant layer enabling measurement by system signal output. OP1000 systems operate in conventional atmospheres on all types of material and detect both organic and inorganic contamination.
Airborne mapping of chemical plumes in the aftermath of Hurricanes Katrina and Rita
NASA Astrophysics Data System (ADS)
Lewis, Paul E.; Thomas, Mark J.; Kroutil, Robert T.; Combs, Roger; Cummings, Alan S.; Miller, Dave; Curry, Tim; Shen, Sylvia S.
2006-05-01
Infrared airborne spectral measurements were collected over the Gulf Coast area during the aftermath of Hurricanes Katrina and Rita. These measurements allowed surveillance for potentially hazardous chemical vapor releases from industrial facilities caused by storm damage. Data was collected with a mid-longwave infrared multispectral imager and a hyperspectral Fourier transform infrared spectrometer operating in a low altitude aircraft. Signal processing allowed detection and identification of targeted spectral signatures in the presence of interferents, atmospheric contributions, and thermal clutter. Results confirmed the presence of a number of chemical vapors. All detection results were immediately passed along to emergency first responders on the ground. The chemical identification, location, and vapor species concentration information were used by the emergency response ground teams for identification of critical plume releases and subsequent mitigation.
Engineering management and innovation
NASA Technical Reports Server (NTRS)
Graham, R. W.
1980-01-01
Although improved management methods can enhance the performance of some enterprises, they can lower that of research organizations. The prevalent use of cost-effectiveness criteria as a management tool overvalues identifiable short-term accomplishment at the expense of long-term research efforts, which often serve as the antecedents upon which a new, seemingly unrelated technology is later founded. Medical instruments used in the treatment of emphysema, for example, evolved from NASA-sponsored research devoted to the measurement of the composition of the atmospheres of the planets. The best manager is the manager who creates an environment that enables his research engineers to pursue ideas with a minimum of interference. Such an environment consists of broad research objectives, adequate facilities, and proper technical support. Within a framework of prudent spending, the manager's aim is to cultivate innovation.
Effects of foliar applied nickel on tomato plants. [Lycopersicon esculentum
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cash, R.C.; Leone, I.A.
Shoot-applied nickel (Ni) treatments produced symptomatology, foliar Ni accumulation, and cytological changes in tomato (Lycopersicon esculentum Mill.) similar to those caused by treatments with root-applied nickel (Ni). Leaf damage resulting from 100 ..mu..g/ml foliar Ni-treatments consisted of interveinal chlorosis and spotting necrosis which appeared histologically as tissue collapse, cell clumping, and chloroplast disintegration. Shoot-treated plants accumulated more Ni in leaves than in roots; whereas the reverse was true in root-treated plants. Interference with root-to-shoot manganese translocation was attributed to attenuated vascular tissue and phloem blockage. Evidence of reduced nutrient transport and inhibited meristem activity due to Ni toxicity presents amore » potential for crop damage from excessive Ni in the atmosphere as well as in the soil environment.« less
Site of water vapor absorption in the desert cockroach, Arenivaga investigata.
O'Donnell, M J
1977-01-01
The desert cockroach, Arenivaga investigata, can gain weight by absorption of water-vapor from unsaturated atmospheres above 82.5% relative humidity. Blocking the anus or the dorsal surface with wax does not prevent water vapor uptake, but interference with movements of the mouthparts or blocking the mouth with wax-prevents such uptake. Weight gains are associated with the protrusion from the mouth of two bladder-like extensions of the hypopharynx. During absorption these structures are warmer than the surrounding mouthparts, their surface temperature increasing with relative humidity. This suggests that the surfaces of the bladder-like structures function at least as sites for condensation of water vapor, but the precise location of its transfer into the hemolymph has not yet been identified. Images PMID:266217
Burgess, Gregory C; Braver, Todd S
2010-09-20
A critical aspect of executive control is the ability to limit the adverse effects of interference. Previous studies have shown activation of left ventrolateral prefrontal cortex after the onset of interference, suggesting that interference may be resolved in a reactive manner. However, we suggest that interference control may also operate in a proactive manner to prevent effects of interference. The current study investigated the temporal dynamics of interference control by varying two factors - interference expectancy and fluid intelligence (gF) - that could influence whether interference control operates proactively versus reactively. A modified version of the recent negatives task was utilized. Interference expectancy was manipulated across task blocks by changing the proportion of recent negative (interference) trials versus recent positive (facilitation) trials. Furthermore, we explored whether gF affected the tendency to utilize specific interference control mechanisms. When interference expectancy was low, activity in lateral prefrontal cortex replicated prior results showing a reactive control pattern (i.e., interference-sensitivity during probe period). In contrast, when interference expectancy was high, bilateral prefrontal cortex activation was more indicative of proactive control mechanisms (interference-related effects prior to the probe period). Additional results suggested that the proactive control pattern was more evident in high gF individuals, whereas the reactive control pattern was more evident in low gF individuals. The results suggest the presence of two neural mechanisms of interference control, with the differential expression of these mechanisms modulated by both experimental (e.g., expectancy effects) and individual difference (e.g., gF) factors.
Differential mobility spectroscopy for chemical agent detection
NASA Astrophysics Data System (ADS)
Griffin, M. Todd
2006-05-01
General Dynamics ATP (GDATP) and Sionex Corporation (Sionex) are carrying out a cooperative development for a handheld chemical agent detector, being called JUNO TM, which will have lower false positives, higher sensitivity, and improved interference rejection compared with presently available detectors. This enhanced performance is made possible by the use of a new principle of ion separation called Differential Mobility Spectrometry (DMS). The enhanced selectivity is provided by the field tunable nature of the Sionex differential mobility technology (microDMxTM) which forms the analytical heart of the JUNO system and enables fingerprinting of molecules by characterization of the ionized molecular behavior under multiple electric field conditions. This enhanced selectivity is valuable in addressing not only the traditional list of chemical warfare agents (CWA) but also the substantial list of Toxic Industrial Compounds (TICs) and Toxic Industrial Materials (TIMs) which may be released in warfare or terrorist situations. Experimental results showing the ability of the microDMx to reject interferences, detect and resolve live agents are presented. An additional breakthrough in the technology was realized by operating the device at a reduced pressure of around 0.5 atmospheres. This reduced pressure operation resulted in roughly doubling the spectrometers resolution over what has previously been reported [1]. Advances have also been made in power consumption and packaging leading to a device suitable for portable, handheld, applications. Experimental results illustrating the performance of the microDMx technology employed in JUNO are highlighted.
Implementation of a new technology for point detection
NASA Astrophysics Data System (ADS)
Petinarides, John; Griffin, M. Todd; Miller, Ranaan A.; Nazarov, Erkinjon G.; Bashall, Anthony D.
2005-05-01
General Dynamics ATP (GDATP) and Sionex Corporation (Sionex) are carrying out a cooperative development for a handheld chemical agent detector, being called JUNO, which will have lower false positives, higher sensitivity, and improved interference rejection compared with presently available detectors. This enhanced performance is made possible by the use of a new principle of ion separation called Differential Mobility Spectrometry (DMS). The enhanced selectivity is provided by the field tunable nature of the Sionex differential mobility technology (microDMxTM) which forms the analytical heart of the JUNO system and enables fingerprinting of molecules by characterization of the ionized molecular behavior under multiple electric field conditions. This enhanced selectivity is valuable in addressing not only the traditional list of chemical warfare agents (CWA) but also the substantial list of Toxic Industrial Compounds (TICs) and Toxic Industrial Materials (TIMs) which may be released in warfare or terrorist situations. Experimental results showing the ability of the microDMx to reject interferences, detect and resolve live agents are presented. An additional breakthrough in the technology was realized by operating the device at a reduced pressure of around 0.5 atmospheres. This reduced pressure operation resulted in roughly doubling the spectrometers resolution over what has previously been reported [1]. Advances have also been made in power consumption and packaging leading to a device suitable for portable, handheld, applications. Experimental results illustrating the performance of the microDMx technology employed in JUNO are highlighted.
Interference competition and invasion: spatial structure, novel weapons and resistance zones.
Allstadt, Andrew; Caraco, Thomas; Molnár, F; Korniss, G
2012-08-07
Certain invasive plants may rely on interference mechanisms (e.g., allelopathy) to gain competitive superiority over native species. But expending resources on interference presumably exacts a cost in another life-history trait, so that the significance of interference competition for invasion ecology remains uncertain. We model ecological invasion when combined effects of preemptive and interference competition govern interactions at the neighborhood scale. We consider three cases. Under "novel weapons," only the initially rare invader exercises interference. For "resistance zones" only the resident species interferes, and finally we take both species as interference competitors. Interference increases the other species' mortality, opening space for colonization. However, a species exercising greater interference has reduced propagation, which can hinder its colonization of open sites. Interference never enhances a rare invader's growth in the homogeneously mixing approximation to our model. But interference can significantly increase an invader's competitiveness, and its growth when rare, if interactions are structured spatially. That is, interference can increase an invader's success when colonization of open sites depends on local, rather than global, species densities. In contrast, interference enhances the common, resident species' resistance to invasion independently of spatial structure, unless the propagation-cost is too great. The particular combination of propagation and interference producing the strongest biotic resistance in a resident species depends on the shape of the tradeoff between the two traits. Increases in background mortality (i.e., mortality not due to interference) always reduce the effectiveness of interference competition. Copyright © 2012 Elsevier Ltd. All rights reserved.
Research for the jamming mechanism of high-frequency laser to the laser seeker
NASA Astrophysics Data System (ADS)
Zheng, Xingyuan; Zhang, Haiyang; Wang, Yunping; Feng, Shuang; Zhao, Changming
2013-08-01
High-frequency laser will be able to enter the enemy laser signal processing systems without encoded identification and a copy. That makes it one of the research directions of new interference sources. In order to study the interference mechanism of high-frequency laser to laser guided weapons. According to the principle of high-frequency laser interference, a series of related theoretical models such as a semi-active laser seeker coded identification model, a time door model, multi-signal processing model and a interference signal modulation processing model are established. Then seeker interfere with effective 3σ criterion is proposed. Based on this, the study of the effect of multi-source interference and signal characteristics of the effect of high repetition frequency laser interference are key research. According to the simulation system testing, the results show that the multi-source interference and interference signal frequency modulation can effectively enhance the interference effect. While the interference effect of the interference signal amplitude modulation is not obvious. The research results will provide the evaluation of high-frequency laser interference effect and provide theoretical references for high-frequency laser interference system application.
NASA Astrophysics Data System (ADS)
Dennis, K. J.; Rees-Owen, R. L.; Brooks, P. D.; Carter, J.; Dawson, T. E.
2014-12-01
The ability to measure the stable isotopic composition of plant and soil waters, surface waters and ambient atmospheric vapor is essential to understanding an ecosystem's water budget, including how water cycles between the air, plants and the subsurface. With the advent of laser-based spectroscopy, e.g., Cavity Ring-Down Spectroscopy (CRDS), the isotopic analysis of waters has become increasingly cost-effective and prevalent, with comparable precision to conventional isotope ratio mass spectrometry methods. However, early work [1,2] demonstrated that the accuracy of isotopic analysis by laser-absorption techniques could be compromised by the spectral interference from organic compounds, in particular methanol and ethanol [1], which are prevalent in ecologically-derived waters. Here we present results from the Picarro Micro-Combustion Module (MCM), which acts to destructively remove these interfering organic species from the analyzed water vapor stream by oxidizing them to CO2 and H2O. Analyzed samples include simulated plant water solutions, waters doped with varying concentrations of potentially problematic organic compounds, and actual plant water extracts. We find that the median offset between IRMS and a Picarro L2130-i outfitted with a MCM is less than 0.5 ‰ for δ18O and less than 1 ‰ for δD. In parallel to the destruction of organic contaminants, a software tool can also be used to assess the probability of spectral interference. This software performs a statistical analysis of spectral fit parameters, e.g., the shift in the spectral baseline, and compares unknown samples to clean standard waters. In general, the most common primary metabolites present in plant materials include the light organic acids, e.g., benzoic and formic acid. At low concentrations (0.1 and 1%) formic acid does not appear to interfere with the resolved absorption spectra for H2O, HDO and H218O. Similar tests will be conducted for benzoic acid. Conversely, although methanol and ethanol are only present in trace amounts in plants, these alcohols can cause large interferences even at the low concentrations (1% and 0.025% for ethanol and methanol, respectively). Using these results, we will propose when CRDS for ecologically-derived waters functions best. [1] Brand et al. (2009), RCM, 23 [2] West et al. (2010), RCM, 24
The application of cavity ring-down spectroscopy to atmospheric and physical chemistry
NASA Astrophysics Data System (ADS)
Hargrove, James Mcchesney
Cavity ring-down spectroscopy (CRDS) is a sensitive form of absorption spectroscopy. Thousands of reflections between two multilayer dielectric mirrors give CRDS an extremely long path-length. The rate of decay of the signal is measured instead of the magnitude of attenuation, so laser intensity fluctuations do not affect the measurement. At 405.23 nm, NO2 had a detection limit of 150 ppt/10 s (3sigma). Particles were removed by a 0.45 mum filter. Water vapor had a 2.8 ppb NO 2 equivalent interference for 1% water vapor in air, with a simple quadratic dependence on water monomer concentration that might have been due to water dimer. Removing NO2 with an annular denuder coated with guiacol and sodium hydroxide, or reacting the NO2 and NO2 with ozone, allows for an interference measurement. An NOy measurement can be obtained after thermal decomposition of higher oxides and ozone. The interference was easier to accommodate than the quenching found in chemiluminescence. The water dimer hypothesis was supported by temperature studies resulting in thermodynamics consistent with theory. The oscillator strength at 409 nm was roughly three orders of magnitude stronger than the best available calculations, leading to a serious unanswered question of the possible source of the additional enhancement. Measurements at 532 nm found a similar response, and others have measured a response at 440 nm, suggesting the 6th, 7th and 8th overtones of water dimer occur at ˜532 nm, ˜440 nm and 409 nm with a similar magnitude that is possibly larger than the 3rd and 4th overtones that have not been detectable. The excellent NO2 detection sensitivity enabled the measurement of NO2 emitted by ambient particles from thermal decomposition. Gas phase interferences were removed with radial aerosol denuders. PANs, ANs, and ammonium nitrate were measured sequentially at 150°C, 215°C and 250°C by the emitted NO2. This technique was applied to ambient air during the Study of Organic Aerosols in Riverside (SOAR) campaign in Riverside during August 2005 and found that PANs were much higher than anticipated. Chamber studies found that PANs were a significant particle phase product from aldehydes.
Study on Interference Suppression Algorithms for Electronic Noses: A Review
Liang, Zhifang; Zhang, Ci; Sun, Hao; Liu, Tao
2018-01-01
Electronic noses (e-nose) are composed of an appropriate pattern recognition system and a gas sensor array with a certain degree of specificity and broad spectrum characteristics. The gas sensors have their own shortcomings of being highly sensitive to interferences which has an impact on the detection of target gases. When there are interferences, the performance of the e-nose will deteriorate. Therefore, it is urgent to study interference suppression techniques for e-noses. This paper summarizes the sources of interferences and reviews the advances made in recent years in interference suppression for e-noses. According to the factors which cause interference, interferences can be classified into two types: interference caused by changes of operating conditions and interference caused by hardware failures. The existing suppression methods were summarized and analyzed from these two aspects. Since the interferences of e-noses are uncertain and unstable, it can be found that some nonlinear methods have good effects for interference suppression, such as methods based on transfer learning, adaptive methods, etc. PMID:29649152
NASA Astrophysics Data System (ADS)
Inclán, M. G.; Forkel, R.; Dlugi, R.; Stull, R. B.
1996-06-01
The new Forest-Land-Atmosphere ModEl called FLAME is presented. The first-order, nonlocal turbulence closure called transilient turbulence theory (Stull, 1993) is applied to study the interactions between a forested land-surface and the atmospheric boundary layer (ABL). The transilient scheme is used for unequal vertical grid spacing and includes the effects of drag, wake turbulence, and interference to vertical mixing by plant elements. Radiation transfer within the vegetation and the equations for the energy balance at the leaf surface have been taken from Norman (1979). Among others, the model predicts profiles of air temperature, humidity and wind velocity within the ABL, sensible and latent heat fluxes from the soil and the vegetation, the stomata and aerodynamic resistances, as well as profiles of temperature and water content in the soil. Preliminary studies carried out for a cloud free day and idealized initial conditions are presented. The canopy height is 30 m within a vertical domain of 3 km. The model is able to capture some of the effects usually observed within and above forested areas, including the relative wind speed maximum in the trunk space and the counter gradient-fluxes in the lower part of the plant stand. Of special interest is the determination of the location and magnitude of the turbulent mixing between model layers, which permits one to identify the effects of large eddies transporting momentum and scalar quantities into the canopy. A comparison between model simulations and field measurements will be presented in a future paper.
Field testing of new-technology ambient air ozone monitors.
Ollison, Will M; Crow, Walt; Spicer, Chester W
2013-07-01
Multibillion-dollar strategies control ambient air ozone (O3) levels in the United States, so it is essential that the measurements made to assess compliance with regulations be accurate. The predominant method employed to monitor O3 is ultraviolet (UV) photometry. Instruments employ a selective manganese dioxide or heated silver wool "scrubber" to remove O3 to provide a zero reference signal. Unfortunately, such scrubbers remove atmospheric constituents that absorb 254-nm light, causing measurement interference. Water vapor also interferes with the measurement under some circumstances. We report results of a 3-month field test of two new instruments designed to minimize interferences (2B Technologies model 211; Teledyne-API model 265E) that were operated in parallel with a conventional Thermo Scientific model 49C O3 monitor. The field test was hosted by the Houston Regional Monitoring Corporation (HRM). The model 211 photometer scrubs O3 with excess nitric oxide (NO) generated in situ by photolysis of added nitrous oxide (N2O) to provide a reference signal, eliminating the need for a conventional O3 scrubber. The model 265E analyzer directly measures O3-NO chemiluminescence from added excess NO to quantify O3 in the sample stream. Extensive quality control (QC) and collocated monitoring data are assessed to evaluate potential improvements to the accuracy of O3 compliance monitoring. Two new-technology ozone monitors were compared with a conventional monitor under field conditions. Over 3 months the conventional monitor reported more exceedances of the current standard than the new instruments, which could potentially result in an area being misjudged as "nonattainment." Instrument drift can affect O3 data accuracy, and the same degree of drift has a proportionally greater compliance effect as standard stringency is increased. Enhanced data quality assurance and data adjustment may be necessary to achieve the improved accuracy required to judge compliance with tighter standards.
NASA Astrophysics Data System (ADS)
Zheng, Jun; Yang, Dongsen; Ma, Yan; Chen, Mindong; Cheng, Jin; Li, Shizheng; Wang, Ming
2015-10-01
A new corona discharge (CD) based ion source was developed for a commercial high-resolution time-of-flight chemical ionization mass spectrometer (HRToF-CIMS) (Aerodyne Research Inc.) to measure both gaseous sulfuric acid (H2SO4) and aerosol sulfate after thermal desorption. Nitrate core ions (NO3-) were used as reagent ions and were generated by a negative discharge in zero air followed by addition of excess nitrogen dioxide (NO2) to convert primary ions and hydroxyl radicals (OH) into NO3- ions and nitric acid (HNO3). The CD-HRToF-CIMS showed no detectable interference from hundreds parts per billion by volume (ppbv) of sulfur dioxide (SO2). Unlike the atmospheric pressure ionization (API) ToF-CIMS, the CD ion source was integrated onto the ion-molecule reaction (IMR) chamber and which made it possible to measure aerosol sulfate by coupling to a filter inlet for gases and aerosols (FIGAERO). Moreover, compared with a quadrupole-based mass spectrometer, the desired HSO4- signal was detected by its exact mass of m/z 96.960, which was well resolved from the potential interferences of HCO3-ṡ(H2O)2 (m/z 97.014) and O-ṡH2OṡHNO3 (m/z 97.002). In this work, using laboratory-generated standards the CD-HRToF-CIMS was demonstrated to be able to detect as low as 3.1 × 105 molecules cm-3 gaseous H2SO4 and 0.5 μg m-3 ammonium sulfate based on 10-s integration time and two times of the baseline noise. The CD ion source had the advantages of low cost and a simple but robust structure. Since the system was non-radioactive and did not require corrosive HNO3 gas, it can be readily field deployed. The CD-HRToF-CIMS can be a powerful tool for both field and laboratory studies of aerosol formation mechanism and the chemical processes that were critical to understand the evolution of aerosols in the atmosphere.
IMPROVED CAPABILITIES FOR SITING WIND FARMS AND MITIGATING IMPACTS ON RADAR OBSERVATIONS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Chiswell, S.
2010-01-15
The development of efficient wind energy production involves challenges in technology and interoperability with other systems critical to the national mission. Wind turbines impact radar measurements as a result of their large reflectivity cross section as well as through the Doppler phase shift of their rotating blades. Wind farms can interfere with operational radar in multiple contexts, with degradation impacts on: weather detection such as tornado location, wind shear, and precipitation monitoring; tracking of airplanes where air traffic control software can lose the tracks of aircraft; and in identification of other low flying targets where a wind farm located closemore » to a border might create a dead zone for detecting intruding objects. Objects in the path of an electromagnetic wave affect its propagation characteristics. This includes actual blockage of wave propagation by large individual objects and interference in wave continuity due to diffraction of the beam by individual or multiple objects. As an evolving industry, and the fastest growing segment of the energy sector, wind power is poised to make significant contributions in future energy generation requirements. The ability to develop comprehensive strategies for designing wind turbine locations that are mutually beneficial to both the wind industry that is dependent on production, and radar sites which the nation relies on, is critical to establishing reliable and secure wind energy. The mission needs of the Department of Homeland Security (DHS), Department of Defense (DOD), Federal Aviation Administration (FAA), and National Oceanographic and Atmospheric Administration (NOAA) dictate that the nation's radar systems remain uninhibited, to the maximum extent possible, by man-made obstructions; however, wind turbines can and do impact the surveillance footprint for monitoring airspace both for national defense as well as critical weather conditions which can impact life and property. As a result, a number of potential wind power locations have been contested on the basis of radar line of site. Radar line of site is dependent on local topography, and varies with atmospheric refractive index which is affected by weather and geographic conditions.« less
NASA Astrophysics Data System (ADS)
Volten, H.; Bergwerff, J. B.; Haaima, M.; Lolkema, D. E.; Berkhout, A. J. C.; van der Hoff, G. R.; Potma, C. J. M.; Wichink Kruit, R. J.; van Pul, W. A. J.; Swart, D. P. J.
2011-08-01
We present two Differential Optical Absorption Spectroscopy (DOAS) instruments built at RIVM, the RIVM DOAS and the miniDOAS. Both instruments provide virtually interference free measurements of NH3 concentrations in the atmosphere, since they measure over an open path, without suffering from inlet problems or interference problems by ammonium aerosols dissociating on tubes or filters. They measure concentrations up to at least 200 μg m-3, have a fast response, low maintenance demands, and a high up-time. The RIVM DOAS has a high accuracy of typically 0.15 μg m-3 for ammonia over 5-min averages and over a total light path of 100 m. The miniDOAS has been developed for application in measurement networks such as the Dutch National Air Quality Monitoring Network (LML). Compared to the RIVM DOAS it has a similar accuracy, but is significantly reduced in size, costs, and handling complexity. The RIVM DOAS and miniDOAS results showed excellent agreement (R2 = 0.996) during a field measurement campaign in Vredepeel, the Netherlands. This measurement site is located in an agricultural area and is characterized by highly variable, but on average high ammonia concentrations in the air. The RIVM-DOAS and miniDOAS results were compared to the results of the AMOR instrument, a continuous-flow wet denuder system, which is currently used in the LML. Averaged over longer time spans of typically a day the (mini)DOAS and AMOR results agree reasonably well, although an offset of the AMOR values compared to the (mini)DOAS results exists. On short time scales the (mini)DOAS shows a faster response and does not show the memory effects due to inlet tubing and transport of absorption fluids encountered by the AMOR. Due to its high accuracy, high uptime, low maintenance and its open path, the (mini)DOAS shows a good potential for flux measurements by using two (or more) systems in a gradient set-up and applying the aerodynamic gradient technique.
NASA Astrophysics Data System (ADS)
Volten, H.; Bergwerff, J. B.; Haaima, M.; Lolkema, D. E.; Berkhout, A. J. C.; van der Hoff, G. R.; Potma, C. J. M.; Wichink Kruit, R. J.; van Pul, W. A. J.; Swart, D. P. J.
2012-02-01
We present two Differential Optical Absorption Spectroscopy (DOAS) instruments built at RIVM: the RIVM DOAS and the miniDOAS. Both instruments provide virtually interference-free measurements of NH3 concentrations in the atmosphere, since they measure over an open path, without suffering from inlet problems or interference problems by ammonium aerosols dissociating on tubes or filters. They measure concentrations up to at least 200 μg m-3, have a fast response, low maintenance demands, and a high up-time. The RIVM DOAS has a high accuracy of typically 0.15 μg m-3 for ammonia for 5-min averages and over a total light path of 100 m. The miniDOAS has been developed for application in measurement networks such as the Dutch National Air Quality Monitoring Network (LML). Compared to the RIVM DOAS it has a similar accuracy, but is significantly reduced in size, costs, and handling complexity. The RIVM DOAS and miniDOAS results showed excellent agreement (R2 = 0.996) during a field measurement campaign in Vredepeel, the Netherlands. This measurement site is located in an agricultural area and is characterized by highly variable, but on average high ammonia concentrations in the air. The RIVM-DOAS and miniDOAS results were compared to the results of the AMOR instrument, a continuous-flow wet denuder system, which is currently used in the LML. Averaged over longer time spans of typically a day, the (mini)DOAS and AMOR results agree reasonably well, although an offset of the AMOR values compared to the (mini)DOAS results exists. On short time scales, the (mini)DOAS shows a faster response and does not show the memory effects due to inlet tubing and transport of absorption fluids encountered by the AMOR. Due to its high accuracy, high uptime, low maintenance and its open path, the (mini)DOAS shows a good potential for flux measurements by using two (or more) systems in a gradient set-up and applying the aerodynamic gradient technique.
Ground-based hyperspectral imaging and analysis of Jupiter’s atmosphere during the Juno era
NASA Astrophysics Data System (ADS)
Dahl, Emma; Chanover, Nancy J.; Voelz, David; Kuehn, David M.; Wijerathna, Erandi; Hull, Robert; Strycker, Paul D.; Baines, Kevin H.
2017-10-01
The Juno mission to Jupiter has presented ground-based observers with a unique opportunity to collect data while the spacecraft is simultaneously measuring the planet and its atmosphere. Data collected in conjunction with Juno measurements have the capability to complement and enhance wavelength regimes already covered by Juno instruments.In order to enrich Juno’s scientific returns in the visible regime, we use the New Mexico State University Acousto-optic Imaging Camera (NAIC) to obtain hyperspectral image cubes of Jupiter from 470-950 nm with an average spectral resolution (λ/dλ) of 242. We use NAIC with the Apache Point Observatory 3.5-m telescope to image Jupiter’s atmosphere during Juno’s perijove flybys. With these timely, high spectral resolution measurements, we can derive the properties of cloud and haze particulates and estimate cloud heights. We present geometrically and photometrically calibrated spectra of representative regions of Jupiter’s atmosphere to be compared with previous work and laboratory measurements of candidate chromophore materials. The data we present are from the night of March 26th, 2017, captured during Juno’s 5th perijove flyby. We discuss preliminary analyses of these spectra, including implications for future work regarding atmospheric modeling.For the aforementioned observations, NAIC was equipped with a thinned, back-illuminated CCD. Because of the narrow bandwidths NAIC’s spectral tuning element produces, this chip design resulted in etaloning, or “fringing,” in images at wavelengths longer than ~720 nm. We discuss our methodology for correcting the fringing and the progress of a general-use model for correcting fringing in CCDs. Such a model requires the extraction of chip characteristics from monochromatic flats, which can be then be used to model exactly how the interference of light inside the chip results in the fringing pattern. This artificial fringing image can then be removed from images, thereby correcting the effect.This work is supported by Research Support Agreement 1569980 from the Jet Propulsion Laboratory, as a subaward of a NASA/Solar System Observations grant.
NASA Astrophysics Data System (ADS)
Magic, Z.; Collet, R.; Hayek, W.; Asplund, M.
2013-12-01
Aims: We study the implications of averaging methods with different reference depth scales for 3D hydrodynamical model atmospheres computed with the Stagger-code. The temporally and spatially averaged (hereafter denoted as ⟨3D⟩) models are explored in the light of local thermodynamic equilibrium (LTE) spectral line formation by comparing spectrum calculations using full 3D atmosphere structures with those from ⟨3D⟩ averages. Methods: We explored methods for computing mean ⟨3D⟩ stratifications from the Stagger-grid time-dependent 3D radiative hydrodynamical atmosphere models by considering four different reference depth scales (geometrical depth, column-mass density, and two optical depth scales). Furthermore, we investigated the influence of alternative averages (logarithmic, enforced hydrostatic equilibrium, flux-weighted temperatures). For the line formation we computed curves of growth for Fe i and Fe ii lines in LTE. Results: The resulting ⟨3D⟩ stratifications for the four reference depth scales can be very different. We typically find that in the upper atmosphere and in the superadiabatic region just below the optical surface, where the temperature and density fluctuations are highest, the differences become considerable and increase for higher Teff, lower log g, and lower [Fe / H]. The differential comparison of spectral line formation shows distinctive differences depending on which ⟨3D⟩ model is applied. The averages over layers of constant column-mass density yield the best mean ⟨3D⟩ representation of the full 3D models for LTE line formation, while the averages on layers at constant geometrical height are the least appropriate. Unexpectedly, the usually preferred averages over layers of constant optical depth are prone to increasing interference by reversed granulation towards higher effective temperature, in particular at low metallicity. Appendix A is available in electronic form at http://www.aanda.orgMean ⟨3D⟩ models are available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/560/A8 as well as at http://www.stagger-stars.net
Interference Effects in Schizophrenic Short-Term Memory
ERIC Educational Resources Information Center
Bauman, Edward; Kolisnyk, Eugene
1976-01-01
Assesses the effects of input and output interference on schizophrenic recall. Input interference is the interference resulting from the interpolation of items between presentation and recall of the probed item. Output interference is the interference resulting from the interpolation of responses between the presentation and recall of the probed…
NASA Astrophysics Data System (ADS)
McDonald, S. E.; Sassi, F.; Tate, J.; McCormack, J.; Kuhl, D. D.; Drob, D. P.; Metzler, C.; Mannucci, A. J.
2018-06-01
The lower atmosphere contributes significantly to the day-to-day variability of the ionosphere, especially during solar minimum conditions. Ionosphere/atmosphere model simulations that incorporate meteorology from data assimilation analysis products can be critically important for elucidating the physical processes that have substantial impact on ionospheric weather. In this study, the NCAR Whole Atmosphere Community Climate Model, extended version with specified dynamics (SD-WACCM-X) is coupled with an ionospheric model (Sami3 is Another Model of the Ionosphere) to study day-to-day variability in the ionosphere during January 2010. Lower atmospheric weather patterns are introduced into the SAMI3/SD-WACCM-X simulations using the 6-h Navy Operational Global Atmospheric Prediction System-Advanced Level Physics High Altitude (NOGAPS-ALPHA) data assimilation products. The same time period is simulated using the new atmospheric forecast model, the High Altitude Navy Global Environmental Model (HA-NAVGEM), a hybrid 4D-Var prototype data assimilation with the ability to produce meteorological fields at a 3-h cadence. Our study shows that forcing SD-WACCM-X with HA-NAVGEM better resolves the semidiurnal tides and introduces more day-to-day variability into the ionosphere than forcing with NOGAPS-ALPHA. The SAMI3/SD-WACCM-X/HA-NAVGEM simulation also more accurately captures the longitudinal variability associated with non-migrating tides in the equatorial ionization anomaly (EIA) region as compared to total electron content (TEC) maps derived from GPS data. Both the TEC maps and the SAMI3/SD-WACCM-X/HA-NAVGEM simulation show an enhancement in TEC over South America during 17-21 January 2010, which coincides with the commencement of a stratospheric warming event on 19 January 2010. Analysis of the SAMI3/SD-WACCM-X/HA-NAVGEM simulations indicates non-migrating tides (including DW4, DE2 and SW5) played a role during 17-21 January in shifting the phase of the wave-3 pattern in the ionosphere on these days. Constructive interference of wave-3 and wave-4 patterns in the E × B drifts contributed to the enhanced TEC in the South American longitude sector. The results of the study highlight the importance of high fidelity meteorology in understanding the day-to-day variability of the ionosphere.
IETS and quantum interference: Propensity rules in the presence of an interference feature
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lykkebo, Jacob; Solomon, Gemma C., E-mail: gsolomon@nano.ku.dk; Gagliardi, Alessio
2014-09-28
Destructive quantum interference in single molecule electronics is an intriguing phenomenon; however, distinguishing quantum interference effects from generically low transmission is not trivial. In this paper, we discuss how quantum interference effects in the transmission lead to either low current or a particular line shape in current-voltage curves, depending on the position of the interference feature. Second, we consider how inelastic electron tunneling spectroscopy can be used to probe the presence of an interference feature by identifying vibrational modes that are selectively suppressed when quantum interference effects dominate. That is, we expand the understanding of propensity rules in inelastic electronmore » tunneling spectroscopy to molecules with destructive quantum interference.« less
Code of Federal Regulations, 2014 CFR
2014-07-01
... include conductive sensitizers or electromagnetic interference/radio frequency interference shielding.... Electromagnetic interference/radio frequency interference (EMI/RFI) shielding coating means a conductive coating... coating is applied, not including conductive sensitizers or electromagnetic interference/radio frequency...
Code of Federal Regulations, 2010 CFR
2010-07-01
... include conductive sensitizers or electromagnetic interference/radio frequency interference shielding.... Electromagnetic interference/radio frequency interference (EMI/RFI) shielding coating means a conductive coating... coating is applied, not including conductive sensitizers or electromagnetic interference/radio frequency...
Code of Federal Regulations, 2012 CFR
2012-07-01
... include conductive sensitizers or electromagnetic interference/radio frequency interference shielding.... Electromagnetic interference/radio frequency interference (EMI/RFI) shielding coating means a conductive coating... coating is applied, not including conductive sensitizers or electromagnetic interference/radio frequency...
Code of Federal Regulations, 2013 CFR
2013-07-01
... include conductive sensitizers or electromagnetic interference/radio frequency interference shielding.... Electromagnetic interference/radio frequency interference (EMI/RFI) shielding coating means a conductive coating... coating is applied, not including conductive sensitizers or electromagnetic interference/radio frequency...
Code of Federal Regulations, 2011 CFR
2011-07-01
... include conductive sensitizers or electromagnetic interference/radio frequency interference shielding.... Electromagnetic interference/radio frequency interference (EMI/RFI) shielding coating means a conductive coating... coating is applied, not including conductive sensitizers or electromagnetic interference/radio frequency...
The InSight Mission's Martian Atmospheric Science Goals, Capabilities and Instrumentation
NASA Astrophysics Data System (ADS)
Smrekar, S. E.; Banfield, D. J.
2015-12-01
The InSight Mission to Mars will launch in March 2016 and land in September 2016, beginning at least 1 Mars year of observations from the surface of Mars. The primary scientific goal of the InSight mission is to characterize the interior of Mars (both deep and near-surface), but it is also equipped with very capable meteorological instrumentation, and consequently has atmospheric science goals as well. The instrumentation InSight carries includes a very sensitive and fast response pressure sensor, as well as a pair of wind and temperature sensors that are similar to those flown on MSL and will be on Mars2020. These sensors will operate essentially continuously at Mars, a first; enabling the production of a complete sampling of the Martian environment, including short-lived transients. InSight also carries cameras that can be used to survey not only the ground in the near environment, but also sky conditions. The pressure sensor responds to signals below 10Hz (~10X its predecessors) and has a noise level of about 10 mPa (better than 1/10 its predecessors). The pair of wind and temperature sensors have been carefully placed opposite one another on the deck to minimize lander interference as much as possible, leaving one sensor on the windward side of the lander at any time. These capabilities, combined with their continuous sampling enable us to pursue new atmospheric science questions at Mars, including quantifying thresholds for aeolian change, detailed dust devil characterization, bolide infrasonic detection and characterization, and quantifying secular trends in pressure. This is in addition to characterizing the normal meteorology at the InSight landing site, which while not completely new, will provide incremental and important constraints for Martian Atmospheric models. We also expect there to be unexpected discoveries, as well as more synergistic approaches to coordination among all the instruments on InSight that may result even more novel capabilities.
Crompton, Anita J; Gamage, Kelum A A; Bell, Steven; Wilson, Andrew P; Jenkins, Alex; Trivedi, Divyesh
2017-11-29
In this work, a robust stand-off alpha detection method using the secondary effects of alpha radiation has been sought. Alpha particles ionise the surrounding atmosphere as they travel. Fluorescence photons produced as a consequence of this can be used to detect the source of the alpha emissions. This paper details experiments carried out to detect this fluorescence, with the focus on photons in the ultraviolet C (UVC) wavelength range (180-280 nm). A detector, UVTron R9533 (Hamamatsu, 325-6, Sunayama-cho, Naka-ku, Hamamatsu City, Shizuoka Pref., 430-8587, Japan), designed to detect the UVC emissions from flames for fire alarm purposes, was tested in various gas atmospheres with a 210 Po alpha source to determine if this could provide an avenue for stand-off alpha detection. The results of the experiments show that this detector is capable of detecting alpha-induced air fluorescence in normal indoor lighting conditions, as the interference from daylight and artificial lighting is less influential on this detection system which operates below the UVA and UVB wavelength ranges (280-315 nm and 315-380 nm respectively). Assuming a standard 1 r 2 drop off in signal, the limit of detection in this configuration can be calculated to be approximately 240 mm, well beyond the range of alpha-particles in air, which indicates that this approach could have potential for stand-off alpha detection. The gas atmospheres tested produced an increase in the detector count, with xenon having the greatest effect with a measured 52% increase in the detector response in comparison to the detector response in an air atmosphere. This type of alpha detection system could be operated at a distance, where it would potentially provide a more cost effective, safer, and faster solution in comparison with traditional alpha detection methods to detect and characterise alpha contamination in nuclear decommissioning and security applications.
Multispectrum retrieval techniques applied to Venus deep atmosphere and surface problems
NASA Astrophysics Data System (ADS)
Kappel, David; Arnold, Gabriele; Haus, Rainer
The Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) aboard ESA's Venus Express is continuously collecting nightside emission data (among others) from Venus. A radiative transfer model of Venus' atmosphere in conjunction with a suitable retrieval algorithm can be used to estimate atmospheric and surface parameters by fitting simulated spectra to the measured data. Because of the limited spectral resolution of VIRTIS-M-IR-spectra, that have been used so far, many different parameter sets can explain the same measurement equally well. As a common regulative measure, reasonable a priori knowledge of some parameters is applied to suppress solutions implausibly far from the expected range. It is beneficial to introduce a parallel coupled retrieval of several measurements. Since spa-tially and temporally contiguous measurements are not expected to originate from completely unrelated parameters, an assumed a priori correlation of the parameters during the retrieval can help to reduce arbitrary fluctuations of the solutions, to avoid subsidiary solutions, and to attenuate the interference of measurement noise by keeping the parameters close to a gen-eral trend. As an illustration, the resulting improvements for some swaths on the Northern hemisphere are presented. Some atmospheric features are still not very well constrained, for instance CO2 absorption under the extreme environmental conditions close to the surface. A broad band continuum due to far wing and collisional induced absorptions is commonly used to correct individual line absorption. Since the spectrally dependent continuum is constant for all measurements, the retrieval of parameters common to all spectra may be used to give some estimates of the continuum absorption. These estimates are necessary, for example, for the coupled parallel retrieval of a consistent local cloud modal composition, which in turn enables a refined surface emissivity retrieval. We gratefully acknowledge the support from the VIRTIS/Venus Express Team, from ASI, CNES, CNRS, and from the DFG funding the ongoing work.
Crompton, Anita J.; Wilson, Andrew P.; Jenkins, Alex; Trivedi, Divyesh
2017-01-01
In this work, a robust stand-off alpha detection method using the secondary effects of alpha radiation has been sought. Alpha particles ionise the surrounding atmosphere as they travel. Fluorescence photons produced as a consequence of this can be used to detect the source of the alpha emissions. This paper details experiments carried out to detect this fluorescence, with the focus on photons in the ultraviolet C (UVC) wavelength range (180–280 nm). A detector, UVTron R9533 (Hamamatsu, 325-6, Sunayama-cho, Naka-ku, Hamamatsu City, Shizuoka Pref., 430-8587, Japan), designed to detect the UVC emissions from flames for fire alarm purposes, was tested in various gas atmospheres with a 210Po alpha source to determine if this could provide an avenue for stand-off alpha detection. The results of the experiments show that this detector is capable of detecting alpha-induced air fluorescence in normal indoor lighting conditions, as the interference from daylight and artificial lighting is less influential on this detection system which operates below the UVA and UVB wavelength ranges (280–315 nm and 315–380 nm respectively). Assuming a standard 1r2 drop off in signal, the limit of detection in this configuration can be calculated to be approximately 240 mm, well beyond the range of alpha-particles in air, which indicates that this approach could have potential for stand-off alpha detection. The gas atmospheres tested produced an increase in the detector count, with xenon having the greatest effect with a measured 52% increase in the detector response in comparison to the detector response in an air atmosphere. This type of alpha detection system could be operated at a distance, where it would potentially provide a more cost effective, safer, and faster solution in comparison with traditional alpha detection methods to detect and characterise alpha contamination in nuclear decommissioning and security applications. PMID:29186051
REM sleep rescues learning from interference
McDevitt, Elizabeth A.; Duggan, Katherine A.; Mednick, Sara C.
2015-01-01
Classical human memory studies investigating the acquisition of temporally-linked events have found that the memories for two events will interfere with each other and cause forgetting (i.e., interference; Wixted, 2004). Importantly, sleep helps consolidate memories and protect them from subsequent interference (Ellenbogen, Hulbert, Stickgold, Dinges, & Thompson-Schill, 2006). We asked whether sleep can also repair memories that have already been damaged by interference. Using a perceptual learning paradigm, we induced interference either before or after a consolidation period. We varied brain states during consolidation by comparing active wake, quiet wake, and naps with either non-rapid eye movement sleep (NREM), or both NREM and REM sleep. When interference occurred after consolidation, sleep and wake both produced learning. However, interference prior to consolidation impaired memory, with retroactive interference showing more disruption than proactive interference. Sleep rescued learning damaged by interference. Critically, only naps that contained REM sleep were able to rescue learning that was highly disrupted by retroactive interference. Furthermore, the magnitude of rescued learning was correlated with the amount of REM sleep. We demonstrate the first evidence of a process by which the brain can rescue and consolidate memories damaged by interference, and that this process requires REM sleep. We explain these results within a theoretical model that considers how interference during encoding interacts with consolidation processes to predict which memories are retained or lost. PMID:25498222
Meteoroid head echo polarization features studied by numerical electromagnetics modeling
NASA Astrophysics Data System (ADS)
Vertatschitsch, L. E.; Sahr, J. D.; Colestock, P.; Close, S.
2011-12-01
Meteoroid head echoes are radar returns associated with scatter from the dense plasma surrounding meteoroids striking the Earth's atmosphere. Such echoes are detected by high power, large aperture (HPLA) radars. Frequently such detections show large variations in signal strength that suggest constructive and destructive interference. Using the ARPA Long-Range Tracking and Instrumentation Radar (ALTAIR) we can also observe the polarization of the returns. Usually, scatter from head echoes resembles scatter from a small sphere; when transmitting right circular polarization (RC), the received signal consists entirely of left circular polarization (LC). For some detections, power is also received in the RC channel, which indicates the presence of a more complicated scattering process. Radar returns of a fragmenting meteoroid are simulated using a hard-sphere scattering model numerically evaluated in the resonant region of Mie scatter. The cross- and co-polar scattering cross-sections are computed for pairs of spheres lying within a few wavelengths, simulating the earliest stages of fragmentation upon atmospheric impact. The likelihood of detecting this sort of idealized fragmentation event is small, but this demonstrates the measurements that would result from such an event would display RC power comparable to LC power, matching the anomalous data. The resulting computations show that fragmentation is a consistent interpretation for these head echo radar returns.
Estimation of neutral wind velocity in the ionospheric heights by HF-Doppler technique
NASA Technical Reports Server (NTRS)
Kitamura, T.; Takefu, M.; Hiroshige, N.
1985-01-01
Three net stations located about 100 kilometers apart were set up around the station of the standard frequency and time signals (JJY) in central Japan and measurements of atmospheric gravity waves in the ionospheric heights (F-region, 200 to 400 km) were made by means of the HF-Doppler technique during the period of February 1983 to December 1983. The frequencies of the signals received are 5.0, 8.0 and 10.0 MHz, but only the 8.0 MHz signals are used for the present study, because no ambiguities due to the interference among other stations such as BPM, BSF, etc. exist by the use of 8.0 MHz. Two main results concerning the horizontal phase velocity of the atmospheric gravity waves with periods of 40 to 70 min may be summarized as follows: (1) the value of the phase velocity ranges from 50 m/s to 300 m/s; (2) the direction of the gravity wave propagation shows a definite seasonal variation. The prevailing direction of the gravity waves in winter is from north to south, which is consistent with the results obtained from other investigations. On the other hand, the two directions, from northeast to southwest and from southeast to northeast, dominate in summer.
Evaluation of the night sky quality at El Leoncito and LEO++ in Argentina
NASA Astrophysics Data System (ADS)
Aubé, Martin; García, Beatriz; Fortin, Nicolas; Turcotte, Sara; Mancilla, Alexis; Maya, Javier
2015-08-01
Light pollution is a growing concern at many levels, but especially for the astronomical community. Artificial lighting veil celestial objects and disturbs the measurement of night time atmospheric phenomena. This is what motivates our sky brightness measurement experiment in Argentina. Our goal was to determine the quality of two Argentinian observation sites: LEO++ and El Leoncito. Both sites were candidates to host the Cherenkov Telescope Array (CTA). This project consists of an arrangement of many telescopes that can measure high-energy gamma ray emissions via their Cherenkov radiation produced when entering the earth's atmosphere. Even if the two argentinian sites has been excluded from the final CTA site competition, they are still of great interest for other astronomical projects. Especially the El Leoncito site which already hots the CASLEO astronomical complex. In this presentation, we describe the measurement methods used to determine the sky quality. We compared our results with different renowned astronomical sites (Kitt Peak, Arizona, USA, and Mont-Mégantic, Canada). Amongst our results, we found that LEO++ is a high quality site, however there are a lot of aerosols that can interfere with the measurements. El Leoncito shows very low sky brightness levels, which are optimal for low light level detection.
NASA Astrophysics Data System (ADS)
Novelli, Anna; Hens, Korbinian; Tatum Ernest, Cheryl; Martinez, Monica; Nölscher, Anke C.; Sinha, Vinayak; Paasonen, Pauli; Petäjä, Tuukka; Sipilä, Mikko; Elste, Thomas; Plass-Dülmer, Christian; Phillips, Gavin J.; Kubistin, Dagmar; Williams, Jonathan; Vereecken, Luc; Lelieveld, Jos; Harder, Hartwig
2017-06-01
We analysed the extensive dataset from the HUMPPA-COPEC 2010 and the HOPE 2012 field campaigns in the boreal forest and rural environments of Finland and Germany, respectively, and estimated the abundance of stabilised Criegee intermediates (SCIs) in the lower troposphere. Based on laboratory tests, we propose that the background OH signal observed in our IPI-LIF-FAGE instrument during the aforementioned campaigns is caused at least partially by SCIs. This hypothesis is based on observed correlations with temperature and with concentrations of unsaturated volatile organic compounds and ozone. Just like SCIs, the background OH concentration can be removed through the addition of sulfur dioxide. SCIs also add to the previously underestimated production rate of sulfuric acid. An average estimate of the SCI concentration of ˜ 5.0 × 104 molecules cm-3 (with an order of magnitude uncertainty) is calculated for the two environments. This implies a very low ambient concentration of SCIs, though, over the boreal forest, significant for the conversion of SO2 into H2SO4. The large uncertainties in these calculations, owing to the many unknowns in the chemistry of Criegee intermediates, emphasise the need to better understand these processes and their potential effect on the self-cleaning capacity of the atmosphere.
Interferometric synthetic aperture radar: Building tomorrow's tools today
Lu, Zhong
2006-01-01
A synthetic aperture radar (SAR) system transmits electromagnetic (EM) waves at a wavelength that can range from a few millimeters to tens of centimeters. The radar wave propagates through the atmosphere and interacts with the Earth’s surface. Part of the energy is reflected back to the SAR system and recorded. Using a sophisticated image processing technique, called SAR processing (Curlander and McDonough, 1991), both the intensity and phase of the reflected (or backscattered) signal of each ground resolution element (a few meters to tens of meters) can be calculated in the form of a complex-valued SAR image representing the reflectivity of the ground surface. The amplitude or intensity of the SAR image is determined primarily by terrain slope, surface roughness, and dielectric constants, whereas the phase of the SAR image is determined primarily by the distance between the satellite antenna and the ground targets, slowing of the signal by the atmosphere, and the interaction of EM waves with ground surface. Interferometric SAR (InSAR) imaging, a recently developed remote sensing technique, utilizes the interaction of EM waves, referred to as interference, to measure precise distances. Very simply, InSAR involves the use of two or more SAR images of the same area to extract landscape topography and its deformation patterns.
Radio Science Measurements with Suppressed Carrier
NASA Technical Reports Server (NTRS)
Asmar, Sami; Divsalar, Dariush; Oudrhiri, Kamal
2013-01-01
Radio Science started when it became apparent with early Solar missions that occultations by planetary atmospheres would affect the quality of radio communications. Since then the atmospheric properties and other aspects of planetary science, solar science, and fundamental physics were studied by scientists. Radio Science data was always extracted from a received pure residual carrier (without data modulation). For some missions, it is very desirable to obtain Radio Science data from a suppressed carrier modulation. In this paper we propose a method to extract Radio Science data when a coded suppressed carrier modulation is used in deep space communications. Type of modulation can be BPSK, QPSK, OQPSK, MPSK or even GMSK. However we concentrate mostly on BPSK modulation. The proposed method for suppressed carrier simply tries to wipe out data that acts as an interference for Radio Science measurements. In order to measure the estimation errors in amplitude and phase of the Radio Science data we use Cramer-Rao bound (CRB). The CRB for the suppressed carrier modulation with non-ideal data wiping is then compared with residual carrier modulation under the same noise condition. The method of derivation of CRB for non-ideal data wiping is an innovative method that presented here. Some numerical results are provided for coded system.
NASA Technical Reports Server (NTRS)
Partridge, William P.; Laurendeau, Normand M.
1997-01-01
We have experimentally assessed the quantitative nature of planar laser-induced fluorescence (PLIF) measurements of NO concentration in a unique atmospheric pressure, laminar, axial inverse diffusion flame (IDF). The PLIF measurements were assessed relative to a two-dimensional array of separate laser saturated fluorescence (LSF) measurements. We demonstrated and evaluated several experimentally-based procedures for enhancing the quantitative nature of PLIF concentration images. Because these experimentally-based PLIF correction schemes require only the ability to make PLIF and LSF measurements, they produce a more broadly applicable PLIF diagnostic compared to numerically-based correction schemes. We experimentally assessed the influence of interferences on both narrow-band and broad-band fluorescence measurements at atmospheric and high pressures. Optimum excitation and detection schemes were determined for the LSF and PLIF measurements. Single-input and multiple-input, experimentally-based PLIF enhancement procedures were developed for application in test environments with both negligible and significant quench-dependent error gradients. Each experimentally-based procedure provides an enhancement of approximately 50% in the quantitative nature of the PLIF measurements, and results in concentration images nominally as quantitative as LSF point measurements. These correction procedures can be applied to other species, including radicals, for which no experimental data are available from which to implement numerically-based PLIF enhancement procedures.
Different Loci of Semantic Interference in Picture Naming vs. Word-Picture Matching Tasks.
Harvey, Denise Y; Schnur, Tatiana T
2016-01-01
Naming pictures and matching words to pictures belonging to the same semantic category impairs performance relative to when stimuli come from different semantic categories (i.e., semantic interference). Despite similar semantic interference phenomena in both picture naming and word-picture matching tasks, the locus of interference has been attributed to different levels of the language system - lexical in naming and semantic in word-picture matching. Although both tasks involve access to shared semantic representations, the extent to which interference originates and/or has its locus at a shared level remains unclear, as these effects are often investigated in isolation. We manipulated semantic context in cyclical picture naming and word-picture matching tasks, and tested whether factors tapping semantic-level (generalization of interference to novel category items) and lexical-level processes (interactions with lexical frequency) affected the magnitude of interference, while also assessing whether interference occurs at a shared processing level(s) (transfer of interference across tasks). We found that semantic interference in naming was sensitive to both semantic- and lexical-level processes (i.e., larger interference for novel vs. old and low- vs. high-frequency stimuli), consistent with a semantically mediated lexical locus. Interference in word-picture matching exhibited stable interference for old and novel stimuli and did not interact with lexical frequency. Further, interference transferred from word-picture matching to naming. Together, these experiments provide evidence to suggest that semantic interference in both tasks originates at a shared processing stage (presumably at the semantic level), but that it exerts its effect at different loci when naming pictures vs. matching words to pictures.
Different Loci of Semantic Interference in Picture Naming vs. Word-Picture Matching Tasks
Harvey, Denise Y.; Schnur, Tatiana T.
2016-01-01
Naming pictures and matching words to pictures belonging to the same semantic category impairs performance relative to when stimuli come from different semantic categories (i.e., semantic interference). Despite similar semantic interference phenomena in both picture naming and word-picture matching tasks, the locus of interference has been attributed to different levels of the language system – lexical in naming and semantic in word-picture matching. Although both tasks involve access to shared semantic representations, the extent to which interference originates and/or has its locus at a shared level remains unclear, as these effects are often investigated in isolation. We manipulated semantic context in cyclical picture naming and word-picture matching tasks, and tested whether factors tapping semantic-level (generalization of interference to novel category items) and lexical-level processes (interactions with lexical frequency) affected the magnitude of interference, while also assessing whether interference occurs at a shared processing level(s) (transfer of interference across tasks). We found that semantic interference in naming was sensitive to both semantic- and lexical-level processes (i.e., larger interference for novel vs. old and low- vs. high-frequency stimuli), consistent with a semantically mediated lexical locus. Interference in word-picture matching exhibited stable interference for old and novel stimuli and did not interact with lexical frequency. Further, interference transferred from word-picture matching to naming. Together, these experiments provide evidence to suggest that semantic interference in both tasks originates at a shared processing stage (presumably at the semantic level), but that it exerts its effect at different loci when naming pictures vs. matching words to pictures. PMID:27242621
High-Frequency Peaks in the Power Spectrum of Solar Velocity Observations from the GOLF Experiment
NASA Astrophysics Data System (ADS)
García, R. A.; Pallé, P. L.; Turck-Chièze, S.; Osaki, Y.; Shibahashi, H.; Jefferies, S. M.; Boumier, P.; Gabriel, A. H.; Grec, G.; Robillot, J. M.; Cortés, T. Roca; Ulrich, R. K.
1998-09-01
The power spectrum of more than 630 days of full-disk solar velocity data, provided by the GOLF spectrophotometer aboard the Solar and Heliospheric Observatory, has revealed the presence of modelike structure well beyond the acoustic cutoff frequency for the solar atmosphere (νac~5.4 mHz). Similar data produced by full-disk instruments deployed in Earth-based networks (BiSON and IRIS) had not shown any peak structure above νac: this is probably due to the higher levels of noise that are inherent in Earth-based experiments. We show that the observed peak structure (νac<=ν<=7.5 mHz) can be explained by a simple two-wave interference model if the high-frequency waves are partially reflected at the back side of the Sun.
NASA Technical Reports Server (NTRS)
Blanchard, A.; Payry, M. J.; Breil, J. F.
1986-01-01
The results obtained on the AS 07 wing and the working section walls for three types of configurations are reported. The first, called non-adapted, corresponds to the divergent upper and lower rectilinear walls which compensate for limit layer thickening. It can serve as a basis for complete flow calculations. The second configuration corresponds to wall shapes determined from calculations which tend to minimize interference at the level of the fuselage. Finally, the third configuration, called two-dimensional adaptation, uses the standard method for T2 profile tests. This case was tested to determine the influence of wall shape and error magnitude. These results are not sufficient to validate the three-dimensional adaptation; they must be coordinated with calculations or with unlimited atmosphere tests.
Cosmic-Ray Energetics and Mass Processing - Bonding
2017-06-20
Research that started aboard balloons a century ago will soon culminate in a three-year stint aboard the International Space Station as scientists work on solving a fundamental astrophysics mystery: What gives cosmic rays such incredible energies, and how does that affect the composition of the universe? The Cosmic-Ray Energetics and Mass investigation, known as CREAM, places a highly successful balloon-borne instrument aboard the International Space Station where it gathers an order of magnitude (ten times) more data, which has lower background interference because Earth's atmosphere is no longer interfering. CREAM's instruments measure the charges of cosmic rays ranging from hydrogen up through iron nuclei, over a broad energy range. The modified balloon instrument is carried aloft on a SpaceX Dragon Lab cargo supply mission and placed on the Japanese Exposed Module for a period of at least three years.
Normal mode Rossby waves observed in the upper stratosphere
NASA Technical Reports Server (NTRS)
Hirooka, T.; Hirota, I.
1985-01-01
In recent years, observational evidence has been obtained for westward traveling planetary waves in the middle atmosphere with the aid of global data from satellites. There is no doubt that the fair portion of the observed traveling waves can be understood as the manifestation of the normal mode Rossby waves which are theoretically derived from the tidal theory. Some observational aspects of the structure and behavior of the normal model Rossby waves in the upper stratosphere are reported. The data used are the global stratospheric geopotential thickness and height analyses which are derived mainly from the Stratospheric Sounding Units (SSUs) on board TIROS-N and NOAA satellites. A clear example of the influence of the normal mode Rossby wave on the mean flow is reported. The mechanism considered is interference between the normal mode Rossby wave and the quasi-stationary wave.
Method for manufacturing high quality carbon nanotubes
NASA Technical Reports Server (NTRS)
Benavides, Jeanette M. (Inventor)
2006-01-01
A non-catalytic process for the production of carbon nanotubes includes supplying an electric current to a carbon anode and a carbon cathode which have been securely positioned in the open atmosphere with a gap between them. The electric current creates an electric arc between the carbon anode and the carbon cathode, which causes carbon to be vaporized from the carbon anode and a carbonaceous residue to be deposited on the carbon cathode. Inert gas is pumped into the gap to flush out oxygen, thereby preventing interference with the vaporization of carbon from the anode and preventing oxidation of the carbonaceous residue being deposited on the cathode. The anode and cathode are cooled while electric current is being supplied thereto. When the supply of electric current is terminated, the carbonaceous residue is removed from the cathode and is purified to yield carbon nanotubes.
Jaworski, Piotr; Nikodem, Michał
2018-01-01
In this paper, we present a system for sequential detection of multiple gases using laser-based wavelength modulation spectroscopy (WMS) method combined with a Herriot-type multi-pass cell. Concentration of hydrogen sulfide (H2S), methane (CH4), carbon dioxide (CO2), and ammonia (NH3) are retrieved using three distributed feedback laser diodes operating at 1574.5 nm (H2S and CO2), 1651 nm (CH4), and 1531 nm (NH3). Careful adjustment of system parameters allows for H2S sensing at single parts-per-million by volume (ppmv) level with strongly reduced interference from adjacent CO2 transitions even at atmospheric pressure. System characterization in laboratory conditions is presented and the results from initial tests in real-world application are demonstrated. PMID:29425175
Real time in situ detection of organic nitrates in atmospheric aerosols.
Rollins, Andrew W; Smith, Jared D; Wilson, Kevin R; Cohen, Ronald C
2010-07-15
A novel instrument is described that quantifies total particle-phase organic nitrates in real time with a detection limit of 0.11 microg m(-3) min(-1), 45 ppt min(-1) (-ONO(2)). Aerosol nitrates are separated from gas-phase nitrates with a short residence time activated carbon denuder. Detection of organic molecules containing -ONO(2) subunits is accomplished using thermal dissociation coupled to laser induced fluorescence detection of NO(2). This instrument is capable of high time resolution (seconds) measurements of particle-phase organic nitrates, without interference from inorganic nitrate. Here we use it to quantify organic nitrates in secondary organic aerosol generated from high-NO(x) photooxidation of limonene, alpha-pinene, Delta-3-carene, and tridecane. In these experiments the organic nitrate moiety is observed to be 6-15% of the total SOA mass.
Interference Mitigation Effects on Synthetic Aperture Radar Coherent Data Products
DOE Office of Scientific and Technical Information (OSTI.GOV)
Musgrove, Cameron
2014-05-01
For synthetic aperture radar image products interference can degrade the quality of the images while techniques to mitigate the interference also reduce the image quality. Usually the radar system designer will try to balance the amount of mitigation for the amount of interference to optimize the image quality. This may work well for many situations, but coherent data products derived from the image products are more sensitive than the human eye to distortions caused by interference and mitigation of interference. This dissertation examines the e ect that interference and mitigation of interference has upon coherent data products. An improvement tomore » the standard notch mitigation is introduced, called the equalization notch. Other methods are suggested to mitigation interference while improving the quality of coherent data products over existing methods.« less
Long-term interference at the semantic level: Evidence from blocked-cyclic picture matching.
Wei, Tao; Schnur, Tatiana T
2016-01-01
Processing semantically related stimuli creates interference across various domains of cognition, including language and memory. In this study, we identify the locus and mechanism of interference when retrieving meanings associated with words and pictures. Subjects matched a probe stimulus (e.g., cat) to its associated target picture (e.g., yarn) from an array of unrelated pictures. Across trials, probes were either semantically related or unrelated. To test the locus of interference, we presented probes as either words or pictures. If semantic interference occurs at the stage common to both tasks, that is, access to semantic representations, then interference should occur in both probe presentation modalities. Results showed clear semantic interference effects independent of presentation modality and lexical frequency, confirming a semantic locus of interference in comprehension. To test the mechanism of interference, we repeated trials across 4 presentation cycles and manipulated the number of unrelated intervening trials (zero vs. two). We found that semantic interference was additive across cycles and survived 2 intervening trials, demonstrating interference to be long-lasting as opposed to short-lived. However, interference was smaller with zero versus 2 intervening trials, which we interpret to suggest that short-lived facilitation counteracted the long-lived interference. We propose that retrieving meanings associated with words/pictures from the same semantic category yields both interference due to long-lasting changes in connection strength between semantic representations (i.e., incremental learning) and facilitation caused by short-lived residual activation. (PsycINFO Database Record (c) 2016 APA, all rights reserved).
Interference in Ballistic Motor Learning: Specificity and Role of Sensory Error Signals
Lundbye-Jensen, Jesper; Petersen, Tue Hvass; Rothwell, John C.; Nielsen, Jens Bo
2011-01-01
Humans are capable of learning numerous motor skills, but newly acquired skills may be abolished by subsequent learning. Here we ask what factors determine whether interference occurs in motor learning. We speculated that interference requires competing processes of synaptic plasticity in overlapping circuits and predicted specificity. To test this, subjects learned a ballistic motor task. Interference was observed following subsequent learning of an accuracy-tracking task, but only if the competing task involved the same muscles and movement direction. Interference was not observed from a non-learning task suggesting that interference requires competing learning. Subsequent learning of the competing task 4 h after initial learning did not cause interference suggesting disruption of early motor memory consolidation as one possible mechanism underlying interference. Repeated transcranial magnetic stimulation (rTMS) of corticospinal motor output at intensities below movement threshold did not cause interference, whereas suprathreshold rTMS evoking motor responses and (re)afferent activation did. Finally, the experiments revealed that suprathreshold repetitive electrical stimulation of the agonist (but not antagonist) peripheral nerve caused interference. The present study is, to our knowledge, the first to demonstrate that peripheral nerve stimulation may cause interference. The finding underscores the importance of sensory feedback as error signals in motor learning. We conclude that interference requires competing plasticity in overlapping circuits. Interference is remarkably specific for circuits involved in a specific movement and it may relate to sensory error signals. PMID:21408054
NASA Technical Reports Server (NTRS)
Wang, Charles C.; Sue, Miles K.; Manshadi, Farzin; Kinman, Peter
2005-01-01
This paper will first describe the characteristics of interference from a typical EESS satellite, including the intensity, frequency and duration of such interference. The paper will then discuss the DSN interference susceptibility, including the various components in the receiving systems that are susceptible to interference and the recovery time after a strong interference. Finally, the paper will discuss the impact of interference on science data and missions operations.
The effects of trait impulsivity on proactive and reactive interference control.
Xiang, Ling; Chen, Yan; Chen, Antao; Zhang, Fenghua; Xu, Fuming; Wang, Baoxi
2018-02-01
The current study used event-related brain potentials (ERPs) to explore whether self-reported trait impulsivity in healthy individuals might be differentially related to proactive and reactive interference control. Participants with high and low impulsivity (HI and LI, respectively) performed a modified version of the prime-target interference task. Proactive interference control was induced in the mostly incongruent (MI) context and reactive interference control was induced in the mostly congruent (MC) context. Although the behavioral data revealed no difference between HI and LI individuals in terms of the interference effects (incongruent - congruent) under both contexts, the ERP results showed that impulsivity has a different influence on the interference effects under different task contexts. In the MC context, the interference effects on the medial frontal negativity (MFN) and the negative sustained potential (N-SP) were greater, while that on the positive sustained potential (P-SP) were smaller in the HI compared to those in the LI group. This suggests that high levels of impulsivity might be associated with a reduced efficiency of the processes supporting reactive control to resolve interference when interference is not expected. In contrast, the three ERP indices (MFN, P-SP, and N-SP) of interference processing in the MI context were insensitive to variations in impulsivity. This suggests that HI individuals might be as effective as LI individuals in recruiting proactive control for sustained active maintenance of task goals to anticipate and prevent interference throughout the experimental blocks where interference occurs frequently. In conclusion, these results indicate that impulsivity has a more negative influence on reactive interference control than on proactive interference control. Copyright © 2017. Published by Elsevier B.V.
High-resolution reflectance spectra of Mars in the 2.3-μm region: evidence for the mineral scapolite
Clark, Roger N.; Swayze, Gregg A.; Singer, Robert B.; Pollack, James B.
1990-01-01
patially resolved reflectance spectra of Mars in the 2.2- to 2.4-μm spectral region were obtained in August 1988 using the NASA 3-m Infrared Telescope Facility. The spectra show weak absorption features due to Martian atmospheric carbon monoxide and a surface mineral. Both CO and the mineral absorptions are composed of overlapping narrow features, but in many locations, such as Hellas, Chryse, Eden, and Moab, the mineral absorptions are quite strong, at least 3 times stronger than at the most absorbing wavelengths of CO near 2.33 μm. Therefore CO complicates the analysis of the surface mineral but does not always overwhelm its signature. Model removal of the Martian atmospheric CO has been performed, and the remaining absorption bands are identified as scapolite. Relatively strong absorptions that match bands in the spectrum of scapolite and have little or no CO absorption interference are seen near 2.41, 2.39, and 2.29 μm. Absorption also occurs at the scapolite bands at 2.36 and 2.33 μm, but the analysis is complicated by uncertainty in the atmospheric CO removal at these wavelengths. Weaker scapolite bands are seen at 2.44 and 2.23 μm where there is virtually no atmospheric interference. The scapolite bands observed on Mars are due to HCO3− and HSO4− ions in the scapolite structure. The bicarbonate and bisulfate contents appear to vary with location: the scapolite in Hellas is more bisulfate-rich relative to that in the Chryse/Moab/Eden area. Other locations contain little (Arabia, Syrtis Major, Hellespontica, and Isidis) or no scapolite (e.g., Margaritifer, Ausonia, and Erythraeum). The calculated abundances are unconstrained because the amounts of HCO3− and HSO4− in the Martian scapolites as well as their grain sizes are not known. If the scapolites contain about 3 wt % of each, near the maximum possible, the scapolite abundances probably range from about 5 wt % scapolite at Eden and Hellas; 3–5% at Chryse, Moab, and Oxia Palus; 2–3% at Arabia, Syrtis Major, and Isidis; to less than 2% at Hellespontica, Syrtis Minor, and Margaritifer, assuming a relatively large grain size of 50–100 μm. If the characteristic grain sizes are smaller or the HCO3− and HSO4− contents are lower, the scapolite abundances required to match the observed band depths would be higher. The mineral bands are apparent in many of the Mars spectra measured, so it appears to be widely but not uniformly distributed. The newly observed fine structure also varies greatly in both depth and spectral detail with location on Mars. Thus there appears to be regional variations in composition. The mineral phases appear to reflect local or regional geology and are not primarily contained in the homogeneous, globally redistributed aeolian dust. Higher spectral resolution Martian spectra in the 2.3-μm region as well as at 3.9 μm are needed to confirm the scapolite identification and to constrain its abundance.
Neural Basis of Semantic and Syntactic Interference in Sentence Comprehension
Glaser, Yi G.; Martin, Randi C.; Van Dyke, Julie A.; Hamilton, A. Cris; Tan, Yingying
2013-01-01
According to the cue-based parsing approach (Lewis, Vasishth, & Van Dyke, 2006), sentence comprehension difficulty derives from interference from material that partially matches syntactic and semantic retrieval cues. In a 2 (low vs. high semantic interference) × 2 (low vs. high syntactic interference) fMRI study, greater activation was observed in left BA 44/45 for high versus low syntactic interference conditions following sentences and in BA 45/47 for high versus low semantic interference following comprehension questions. A conjunction analysis showed BA45 associated with both types of interference, while BA47 was associated with only semantic interference. Greater activation was also observed in the left STG in the high interference conditions. Importantly, the results for the LIFG could not be attributed to greater working memory capacity demands for high interference conditions. The results favor a fractionation of LIFG wherein BA45 is associated with post-retrieval selection and BA47 with controlled retrieval of semantic information. PMID:23933471
Effect of sex, age and genetics on crossover interference in cattle
Wang, Zhiying; Shen, Botong; Jiang, Jicai; Li, Jinquan; Ma, Li
2016-01-01
Crossovers generated by homologous recombination ensure proper chromosome segregation during meiosis. Crossover interference results in chiasmata being more evenly distributed along chromosomes, but the mechanism underlying crossover interference remains elusive. Based on large pedigrees of Holstein and Jersey cattle with genotype data, we extracted three-generation families, including 147,327 male and 71,687 female meioses in Holstein, and 108,163 male and 37,008 female meioses in Jersey, respectively. We identified crossovers in these meioses and fitted the Housworth-Stahl “interference-escape” model to study crossover interference patterns in the cattle genome. Our result reveals that the degree of crossover interference is stronger in females than in males. We found evidence for inter-chromosomal variation in the level of crossover interference, with smaller chromosomes exhibiting stronger interference. In addition, crossover interference levels decreased with maternal age. Finally, sex-specific GWAS analyses identified one locus near the NEK9 gene on chromosome 10 to have a significant effect on crossover interference levels. This locus has been previously associated with recombination rate in cattle. Collectively, this large-scale analysis provided a comprehensive description of crossover interference across chromosome, sex and age groups, identified associated candidate genes, and produced useful insights into the mechanism of crossover interference. PMID:27892966
Reading Ability Is Negatively Related to Stroop Interference
ERIC Educational Resources Information Center
Protopapas, Athanassios; Archonti, Anastasia; Skaloumbakas, Christos
2007-01-01
Stroop interference is often taken as evidence for reading automaticity even though young and poor readers, who presumably lack reading automaticity, present strong interference. Here the relationship between reading skills and Stroop interference was studied in a 7th-grade sample. Greater interference was observed in children diagnosed with…
Acharyya, Muktish
2017-07-01
The spin wave interference is studied in two dimensional Ising ferromagnet driven by two coherent spherical magnetic field waves by Monte Carlo simulation. The spin waves are found to propagate and interfere according to the classic rule of interference pattern generated by two point sources. The interference pattern of spin wave is observed in one boundary of the lattice. The interference pattern is detected and studied by spin flip statistics at high and low temperatures. The destructive interference is manifested as the large number of spin flips and vice versa.
Beamforming design with proactive interference cancelation in MISO interference channels
NASA Astrophysics Data System (ADS)
Li, Yang; Tian, Yafei; Yang, Chenyang
2015-12-01
In this paper, we design coordinated beamforming at base stations (BSs) to facilitate interference cancelation at users in interference networks, where each BS is equipped with multiple antennas and each user is with a single antenna. By assuming that each user can select the best decoding strategy to mitigate the interference, either canceling the interference after decoding when it is strong or treating it as noise when it is weak, we optimize the beamforming vectors that maximize the sum rate for the networks under different interference scenarios and find the solutions of beamforming with closed-form expressions. The inherent design principles are then analyzed, and the performance gain over passive interference cancelation is demonstrated through simulations in heterogeneous cellular networks.
The Cost of Learning: Interference Effects in Memory Development
Darby, Kevin P.; Sloutsky, Vladimir M.
2015-01-01
Learning often affects future learning and memory for previously learned information by exerting either facilitation or interference effects. Several theoretical accounts of interference effects have been proposed, each making different developmental predictions. This research examines interference effects across development, with the goal of better understanding mechanisms of interference and of memory development. Preschool-aged children and adults participated in a three-phased associative learning paradigm containing stimuli that were either unique or repeated across phases. Both age groups demonstrated interference effects, but only for repeated items. Whereas proactive interference effects were comparable across age groups, retroactive interference reached catastrophic-like levels in children. Additionally, retroactive interference increased in adults when contextual differences between phases were minimized (Experiment 2), and decreased in adults who were more successful at encoding repeated pairs of stimuli during a training phase (Experiment 3). These results are discussed with respect to theories of memory and memory development. PMID:25688907
Effect of occlusal interference on habitual activity of human masseter.
Michelotti, A; Farella, M; Gallo, L M; Veltri, A; Palla, S; Martina, R
2005-07-01
It has been suggested that occlusal interference may increase habitual activity in the jaw muscles and may lead to temporomandibular disorders (TMD). We tested these hypotheses by means of a double-blind randomized crossover experiment carried out on 11 young healthy females. Strips of gold foil were glued either on a selected occlusal contact area (active interference) or on the vestibular surface of the same tooth (dummy interference) and left for 8 days each. Electromyographic masseter activity was recorded in the natural environment by portable recorders under interference-free, dummy-interference, and active-interference conditions. The active occlusal interference caused a significant reduction in the number of activity periods per hour and in their mean amplitude. The EMG activity did not change significantly during the dummy-interference condition. None of the subjects developed signs and/or symptoms of TMD throughout the whole study, and most of them adapted fairly well to the occlusal disturbance.
Li, Wutao; Huang, Zhigang; Lang, Rongling; Qin, Honglei; Zhou, Kai; Cao, Yongbin
2016-03-04
Interferences can severely degrade the performance of Global Navigation Satellite System (GNSS) receivers. As the first step of GNSS any anti-interference measures, interference monitoring for GNSS is extremely essential and necessary. Since interference monitoring can be considered as a classification problem, a real-time interference monitoring technique based on Twin Support Vector Machine (TWSVM) is proposed in this paper. A TWSVM model is established, and TWSVM is solved by the Least Squares Twin Support Vector Machine (LSTWSVM) algorithm. The interference monitoring indicators are analyzed to extract features from the interfered GNSS signals. The experimental results show that the chosen observations can be used as the interference monitoring indicators. The interference monitoring performance of the proposed method is verified by using GPS L1 C/A code signal and being compared with that of standard SVM. The experimental results indicate that the TWSVM-based interference monitoring is much faster than the conventional SVM. Furthermore, the training time of TWSVM is on millisecond (ms) level and the monitoring time is on microsecond (μs) level, which make the proposed approach usable in practical interference monitoring applications.
A Real-Time Interference Monitoring Technique for GNSS Based on a Twin Support Vector Machine Method
Li, Wutao; Huang, Zhigang; Lang, Rongling; Qin, Honglei; Zhou, Kai; Cao, Yongbin
2016-01-01
Interferences can severely degrade the performance of Global Navigation Satellite System (GNSS) receivers. As the first step of GNSS any anti-interference measures, interference monitoring for GNSS is extremely essential and necessary. Since interference monitoring can be considered as a classification problem, a real-time interference monitoring technique based on Twin Support Vector Machine (TWSVM) is proposed in this paper. A TWSVM model is established, and TWSVM is solved by the Least Squares Twin Support Vector Machine (LSTWSVM) algorithm. The interference monitoring indicators are analyzed to extract features from the interfered GNSS signals. The experimental results show that the chosen observations can be used as the interference monitoring indicators. The interference monitoring performance of the proposed method is verified by using GPS L1 C/A code signal and being compared with that of standard SVM. The experimental results indicate that the TWSVM-based interference monitoring is much faster than the conventional SVM. Furthermore, the training time of TWSVM is on millisecond (ms) level and the monitoring time is on microsecond (μs) level, which make the proposed approach usable in practical interference monitoring applications. PMID:26959020
Danese, Elisa; Salvagno, Gian Luca; Guzzo, Alessandra; Scurati, Samuele; Fava, Cristiano; Lippi, Giuseppe
2017-01-01
Introduction Liquid chromatography coupled to atmospheric pressure ionization tandem mass spectrometry (LC-ESI-MS/MS) is currently considered the reference method for quantitative determination of urinary free cortisol (UFC). One of the major drawbacks of this measurement is a particular form of matrix effect, conventionally known as ion suppression. Materials and methods We describe here the case of a 66-year-old-patient referred to the daily service of general medicine for intravenous antibiotic administration due to a generalized Staphylococcus aureus infection and for routine 24 hours UFC monitoring in the setting of glucocorticoid replacement therapy. Results The observation of 10-fold decrease of internal standard of cortisol signal led us to hypothesize the presence of an ion suppression effect due to a co-eluting endogenous compound. Screening analysis of tandem mass spectrometry (MS/MS) spectra of the interfering molecule, along with in vitro confirmation analyses, were suggestive of the presence of high concentration of piperacillin. The problem was then easily solved with minor modifications of the chromatographic technique. Conclusions According to our findings, antibiotic therapy with piperacillin/tazobactam should be regarded as an important interference in UFC assessment, which may potentially affect detection capability, precision and accuracy of this measurement. This case report emphasizes that accurate anamnesis and standardization of all phases of urine collection are essential aspects for preventing potential interference in laboratory testing. PMID:29180920
Chen, Yujing; Wang, Hai-Shui; Morisawa, Yusuke; Ozaki, Yukihiro
2014-02-01
For infrared (IR) spectral measurements, if a quality single-beam background spectrum with desired intensity could be obtained, the contributions from solvent and other background components could be completely suppressed and their bands would not appear in a final transmittance/absorbance spectrum. In order to achieve this ideal but difficult goal, the concept of hybrid single-beam spectrum is introduced in this paper. The hybrid single-beam spectrum (φ h) is defined as a mixture of two single-beam spectra (φ b1 and φ b2) of the same sample but with different pathlengths (b1 and b2), namely, φ h = αφ b1+(1-α)φ b2, where α (0 ≤ α ≤ 1) is the component factor. The properties of the hybrid spectrum have been investigated. Under conditions of b2 > b1 ≥ 0.7 b2 and A max ≤ 0.60 (Amax is the maximum absorbance of b2 sample in the spectral range of interest), all the synthesized hybrid spectra are free from significant distortion regardless of the component factor. Therefore, the hybrid single-beam spectrum with desired intensity can be easily obtained simply by choosing an appropriate component factor. The proposed methodology has been demonstrated experimentally by the complete removal of the interference from the atmospheric water vapor and solvent. © 2013 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Pöhler, Denis; Lutz, Erik; Horbanski, Martin; Lampel, Johannes; Platt, Ulrich
2017-04-01
Nitrogen Oxides (NOx = NO2 + NO) play a major role in air pollution and atmospheric chemistry. Beside health effects they influence e.g. acid rain, ozone and oxidation capacity. But precise NO2 and NO measurements are still difficult. State of the art NO2 / NO instruments show significant interferences e.g. to H2O and HONO, problems of zero point and calibration drifts, temperature and also vibration influences. Other systems, especially low cost sensors, feature significant problems in terms of measurement accuracy and reliability. To overcome these problems we developed a direct spectroscopic NO2 / NOx ICAD instrument (Iterative Cavity Enhanced DOAS). It feature high accuracy, is relatively small, mobile and requires only low power consumption. During a side by side (s-b-s) inter-comparison campaign at the Meteorological Observatory Hohenpeißenberg (DWD) 2016 the performance of different instruments for NO2, NO and NOx were investigated under natural and artificial conditions. The concentration ranged from few ppt up to 100ppb. The inter-comparison demonstrates excellent performance of our ICAD in terms of accuracy and drift. In comparison to other techniques it features no interferences to different humidity's, temperatures and interfering gases. Also the zero point and calibration is absolutely stable. As the instrument is also much simpler and easier to operate, it has many advantages in comparison to other instruments. The characteristics of the instruments and results of the campaign will be presented.
NASA Astrophysics Data System (ADS)
Reineman, B. D.; Lenain, L.; Statom, N.; Melville, W. K.
2012-12-01
We have developed instrumentation packages for unmanned aerial vehicles (UAVs) to measure ocean surface processes along with momentum fluxes and latent, sensible, and radiative heat fluxes in the marine atmospheric boundary layer (MABL). The packages have been flown over land on BAE Manta C1s and over water on Boeing-Insitu ScanEagles. The low altitude required for accurate surface flux measurements (< 30 m) is below the typical safety limit of manned research aircraft; however, with advances in laser altimeters, small-aircraft flight control, and real-time kinematic differential GPS, low-altitude flight is now within the capability of small UAV platforms. Fast-response turbulence, hygrometer, and temperature probes permit turbulent flux measurements, and short- and long-wave radiometers allow the determination of net radiation, surface temperature, and albedo. Onboard laser altimetry and high-resolution visible and infrared video permit observations of surface waves and fine-scale (O(10) cm) ocean surface temperature structure. Flight tests of payloads aboard ScanEagle UAVs were conducted in April 2012 at the Naval Surface Warfare Center Dahlgren Division (Dahlgren, VA), where measurements of water vapor, heat, and momentum fluxes were made from low-altitude (31-m) UAV flights over water (Potomac River). ScanEagles are capable of ship-based launch and recovery, which can extend the reach of research vessels and enable scientific measurements out to ranges of O(10-100) km and altitudes up to 5 km. UAV-based atmospheric and surface observations can complement observations of surface and subsurface phenomena made from a research vessel and avoid the well-known problems of vessel interference in MABL measurements. We present a description of the instrumentation, summarize results from flight tests, and discuss potential applications of these UAVs for ship-based MABL studies.
Jääskeläinen, E L; Häggblom, M M; Andersson, M A; Salkinoja-Salonen, M S
2004-10-01
Factors influencing the production of cereulide, the emetic toxin of Bacillus cereus in food and laboratory media were investigated, using liquid chromatography-ion trap mass spectrometry and sperm motility inhibition bioassay for detection and quantitation. Oxygen was essential for production of the emetic toxin by B. cereus. When beans, rice or tryptic soy broth were inoculated with cereulide producing strains B203, B116 (recent food isolates) or the strain F-4810/72, high amounts (2 to 7 microg ml(-1) or g(-1) wet wt) of cereulide accumulated during 4-day storage at room temperature. In parallel cultures and foods, stored under nitrogen atmosphere (> 99.5% N2), less than 0.05 microg of cereulide ml(-1) or g(-1) wet wt accumulated. The outcome of the bioassay matched that of the chemical assay, with no indication of interference by substances in the rice or beans. Boiling for 20 to 30 min did not inactivate cereulide or cereulide producing strains in rice or the beans. Adding l-leucine and l-valine (0.3 g l(-1)) stimulated cereulide production 10- to 20-fold in R2A and in rice water agar. When the B. cereus strains were grown on agar media under permissive conditions (air, room temperature), cereulide was produced overnight with little or no increase when the incubation was extended to 4 days. In broth culture, the production of cereulide started later than 16-24 h. Anoxic storage prevented cereulide production also when the amino acids had been supplied. Packaging with modified atmosphere low in oxygen may thus be used to reduce the risk of cereulide formation during storage of food. Copyright 2004 Elsevier B.V.
Studies on Ammonia Spectral Signatures Relevant to Jupiter's Clouds
NASA Astrophysics Data System (ADS)
Kalogerakis, Konstantinos S.; Oza, A. U.; Marschall, J.; Wong, M. H.
2006-09-01
Observational evidence and thermochemical models indicate an abundance of ammonia ice clouds in Jupiter's atmosphere. However, spectrally identifiable ammonia ice clouds are found covering less than 1% of Jupiter's atmosphere, notably in turbulent areas [1,2]. Current literature suggests two possible explanations: coating by a hydrocarbon haze and/or photochemical processing ("tanning") [2,3]. We are pursuing a research program investigating the above hypotheses. In the experiments, thin films of ammonia ices are deposited in a cryogenic apparatus, coated with hydrocarbons, and characterized by infrared spectroscopy. The ice films can be irradiated by ultraviolet light to study their photochemistry. The spectroscopic measurements aim to identify the processes that control the optical properties of the ice mixtures and quantify their dependence on the identity of the coating, the temperature, and the ice composition. We have observed a consistent suppression of the ammonia absorption feature at 3 μm with coverage by thin layers of hydrocarbons. Modeling calculations of the multi-layer thin films assist in the interpretation of the experimental results and reveal the role of optical interference in masking the aforementioned ammonia spectral feature. The implications of these results for Jupiter's atmosphere will be discussed. Funding from the NSF Planetary Astronomy Program under grant AST-0206270 and from the NASA Outer Planets Research Program under grant NNG06GF37G is gratefully acknowledged. The participation of Anand Oza (Princeton University) was made possible by the NSF Research Experiences for Undergraduates Program under grant PHY-0353745. 1. S. K. Atreya, A.-S. Wong, K. H. Baines, M. H. Wong, T. C. Owen, Planet. Space Science 53, 498 (2005). 2. K. H. Baines, R. W. Carlson, and L. W. Kamp, Icarus 159, 74 (2002). 3. A.-S. Wong, Y. L. Yung, and A. J. Friedson, Geophys. Res. Lett. 30, 1447 (2003).
Studies on Ammonia Spectral Signatures Relevant to Jupiter's Clouds
NASA Astrophysics Data System (ADS)
Oza, A. U.; Marschall, J.; Wong, M. H.; Kalogerakis, K. S.
2006-12-01
Observational evidence and thermochemical models indicate an abundance of ammonia ice clouds in Jupiter's atmosphere. However, spectrally identifiable ammonia ice clouds are found covering less than 1% of Jupiter's atmosphere, notably in turbulent areas [1,2]. Current literature suggests two possible explanations: coating by a hydrocarbon haze and/or photochemical processing ("tanning")[2,3]. We are pursuing a research program investigating the above hypotheses. In the experiments, thin films of ammonia ices are deposited in a cryogenic apparatus, coated with hydrocarbons, and characterized by infrared spectroscopy. The ice films can be irradiated by ultraviolet light to study their photochemistry. The spectroscopic measurements aim to identify the processes that control the optical properties of the ice mixtures and quantify their dependence on the identity of the coating, the temperature, and the ice composition. We have observed a consistent suppression of the ammonia absorption feature at 3 μm with coverage by thin layers of hydrocarbons. Modeling calculations of the multi-layer thin films assist in the interpretation of the experimental results and reveal the role of optical interference in masking the aforementioned ammonia spectral feature. The implications of these results for Jupiter's atmosphere will be discussed. Funding from the NSF Planetary Astronomy Program under grant AST-0206270 and from the NASA Outer Planets Research Program under grant NNG06GF37G is gratefully acknowledged. The participation of Anand Oza (Princeton University) was made possible by the NSF Research Experiences for Undergraduates Program under grant PHY-0353745. 1. S. K. Atreya, A.-S. Wong, K. H. Baines, M. H. Wong, T. C. Owen, Planet. Space Science 53, 498 (2005). 2. K. H. Baines, R. W. Carlson, and L. W. Kamp, Icarus 159, 74 (2002). 3. A.-S. Wong, Y. L. Yung, and A. J. Friedson, Geophys. Res. Lett. 30, 1447 (2003).
NASA Astrophysics Data System (ADS)
Risser, Mark D.; Stone, Dáithí A.; Paciorek, Christopher J.; Wehner, Michael F.; Angélil, Oliver
2017-11-01
In recent years, the climate change research community has become highly interested in describing the anthropogenic influence on extreme weather events, commonly termed "event attribution." Limitations in the observational record and in computational resources motivate the use of uncoupled, atmosphere/land-only climate models with prescribed ocean conditions run over a short period, leading up to and including an event of interest. In this approach, large ensembles of high-resolution simulations can be generated under factual observed conditions and counterfactual conditions that might have been observed in the absence of human interference; these can be used to estimate the change in probability of the given event due to anthropogenic influence. However, using a prescribed ocean state ignores the possibility that estimates of attributable risk might be a function of the ocean state. Thus, the uncertainty in attributable risk is likely underestimated, implying an over-confidence in anthropogenic influence. In this work, we estimate the year-to-year variability in calculations of the anthropogenic contribution to extreme weather based on large ensembles of atmospheric model simulations. Our results both quantify the magnitude of year-to-year variability and categorize the degree to which conclusions of attributable risk are qualitatively affected. The methodology is illustrated by exploring extreme temperature and precipitation events for the northwest coast of South America and northern-central Siberia; we also provides results for regions around the globe. While it remains preferable to perform a full multi-year analysis, the results presented here can serve as an indication of where and when attribution researchers should be concerned about the use of atmosphere-only simulations.
78 FR 26849 - Model Specifications for Breath Alcohol Ignition Interlock Devices (BAIIDs)
Federal Register 2010, 2011, 2012, 2013, 2014
2013-05-08
...--Acetone Test 14--Emergency Override Test 15--Radiofrequency Interference/Electromagnetic Interference Test... requirements; temperature extreme testing; radio frequency interference (RFI) or electromagnetic interference...
An Experimental Study of Interference between Receptive and Productive Processes Involving Speech
ERIC Educational Resources Information Center
Goldman-Eisler, Frieda; Cohen, Michele
1975-01-01
Reports an experiment designed to throw light on the interference between the reception and production of speech by controlling the level of interference between decoding and encoding, using hesitancy as an indicator of interference. This proved effective in spotting the levels at which interference takes place. (Author/RM)
Impact of worktime arrangements on work-home interference among Dutch employees.
Jansen, Nicole W H; Kant, Ijmert; Nijhuis, Frans J N; Swaen, Gerard M H; Kristensen, Tage S
2004-04-01
This study examined the effects of different worktime arrangements on work-home interference while taking into account other work-related factors, private situation and health status, explored gender differences in this relation, and examined reciprocal effects between workhours and work-home interference. Data from the Maastricht cohort study on fatigue at work were used with 8 months of follow-up (N=6947 at baseline). Worktime arrangements were related to work-home interference among the men and women, even after control for confounding. As compared with daywork, baseline shiftwork was associated with higher work-home interference over time. Within daywork, full-time work was prospectively related to higher work-home interference than part-time work was. For full-timers, baseline overtime work, hours of overtime work, change in number of workhours, and commuting time were related to higher work-home interference over time, whereas compensation for overtime work, familiarity with work roster, ability to take a day off, and a decrease in workhours at own request were associated with less work-home interference. For the part-timers, baseline overtime work and commuting time were related to higher work-home interference over time, whereas compensation for overtime, flexible workhours, and ability to take a day off were protective against work-home interference. Reciprocal relations between work-home interference and workhours were also found. Worktime arrangements are clearly related to work-home interference. Because reciprocal effects exist as well, important selection processes may exist. Nevertheless, specific characteristics of worktime arrangements could constitute useful tools for reducing work-home interference.
O'Neil, Edward B; Watson, Hilary C; Dhillon, Sonya; Lobaugh, Nancy J; Lee, Andy C H
2015-09-01
Recent work has demonstrated that the perirhinal cortex (PRC) supports conjunctive object representations that aid object recognition memory following visual object interference. It is unclear, however, how these representations interact with other brain regions implicated in mnemonic retrieval and how congruent and incongruent interference influences the processing of targets and foils during object recognition. To address this, multivariate partial least squares was applied to fMRI data acquired during an interference match-to-sample task, in which participants made object or scene recognition judgments after object or scene interference. This revealed a pattern of activity sensitive to object recognition following congruent (i.e., object) interference that included PRC, prefrontal, and parietal regions. Moreover, functional connectivity analysis revealed a common pattern of PRC connectivity across interference and recognition conditions. Examination of eye movements during the same task in a separate study revealed that participants gazed more at targets than foils during correct object recognition decisions, regardless of interference congruency. By contrast, participants viewed foils more than targets for incorrect object memory judgments, but only after congruent interference. Our findings suggest that congruent interference makes object foils appear familiar and that a network of regions, including PRC, is recruited to overcome the effects of interference.
Sosic-Vasic, Zrinka; Hille, Katrin; Kröner, Julia; Spitzer, Manfred; Kornmeier, Jürgen
2018-01-01
Introduction: Consolidation is defined as the time necessary for memory stabilization after learning. In the present study we focused on effects of interference during the first 12 consolidation minutes after learning. Participants had to learn a set of German – Japanese word pairs in an initial learning task and a different set of German – Japanese word pairs in a subsequent interference task. The interference task started in different experimental conditions at different time points (0, 3, 6, and 9 min) after the learning task and was followed by subsequent cued recall tests. In a control experiment the interference periods were replaced by rest periods without any interference. Results: The interference task decreased memory performance by up to 20%, with negative effects at all interference time points and large variability between participants concerning both the time point and the size of maximal interference. Further, fast learners seem to be more affected by interference than slow learners. Discussion: Our results indicate that the first 12 min after learning are highly important for memory consolidation, without a general pattern concerning the precise time point of maximal interference across individuals. This finding raises doubts about the generalized learning recipes and calls for individuality of learning schedules. PMID:29503621
PERSPECTIVE: On the verge of dangerous anthropogenic interference with the climate system?
NASA Astrophysics Data System (ADS)
Kriegler, Elmar
2007-03-01
The recent publication of the summary for policy makers by Working Group I of the Intergovernmental Panel on Climate Change (IPCC) [1] has injected a renewed sense of urgency to address climate change. It is therefore timely to review the notion of preventing 'dangerous anthropogenic interference with the climate system' as put forward in the United Nations Framework Convention on Climate Change (UNFCCC). The article by Danny Harvey in this issue [2] offers a fresh perspective by rephrasing the concept of 'dangerous interference' as a problem of risk assessment. As Harvey points out, identification of 'dangerous interference' does not require us to know with certainty that future climate change will be dangerous—an impossible task given that our knowledge about future climate change includes uncertainty. Rather, it requires the assertion that interference would lead to a significant probability of dangerous climate change beyond some risk tolerance, and therefore would pose an unacceptable risk. In his article [2], Harvey puts this idea into operation by presenting a back-of-the-envelope calculation to identify allowable CO2 concentrations under uncertainty about climate sensitivity to anthropogenic forcing and the location of a temperature threshold beyond which dangerous climate change will occur. Conditional on his assumptions, Harvey delivers an interesting result. With the current atmospheric CO2 concentration exceeding 380 ppm, a forcing contribution from other greenhouse gases adding an approximate 100 110 ppm CO2 equivalent on top of it, and a global dimming effect of aerosols that roughly compensates for this contribution (albeit still subject to considerable uncertainty) ([1], figures SPM-1 and 2), we are on the verge of or even committed to dangerous interference with the climate system if we (1) set the risk tolerance for experiencing dangerous climate change to 1% and (2) allocate at least 5% probability to the belief that climate sensitivity is 4.5 °C or higher. In the language of the IPCC, the latter would mean that such a high climate sensitivity is anything but extremely unlikely ([1], footnote 6 and p 9), a view that is shared by many in the scientific community. Even if the risk tolerance is increased to 10%, the maximum allowable CO2 equivalent concentration remains below 460 ppm ([2], figure 7(c)). We are bound to reach that concentration in the near future, as it can be surpassed both by addition of new greenhouse gases and by a reduction of global dimming. Given the potential significance of this result, let us take a step back, and investigate its underlying assumptions. The concept of 'dangerous anthropogenic interference' is inextricably linked to the idea of a threshold beyond which climate change can be labeled dangerous. This idea enters Harvey's analysis in the form of a probability distribution for the—as he calls it—'harm threshold' measured in terms of global mean temperature increase since preindustrial time. It might be due to the presumption of such a threshold that climate science and society at large have had a difficult relationship with the concept of 'dangerous anthropogenic interference' (Dessai et al [3]). Nevertheless, I want to argue here, as many have done before (see Oppenheimer and Petsonk [4] for an overview), that this concept is not ill-defined. First of all, it is clear that 'dangerous interference' and the stipulation of a 'harm threshold' carry a value judgment, and therefore cannot be decided upon purely by science. This does not prevent science, however, from providing information and conceptual frameworks to facilitate such judgment (Schellnhuber et al [5]). Secondly, it is certainly true that our interference with the climate system emanates from local and national action, and that the consequences of such interference will first and foremost be felt on the local to regional scale. However, this does not need to conflict with the assessment of a global 'harm threshold'. The nexus of climate policy is inevitably global since our interference with the climate system is determined by the sum total of greenhouse gas emissions. In addition, we are living in a highly interconnected world, and it would be foolish not to take global patterns of drivers and impacts of climate change into account. Finally, some may find the assumption of a harm threshold at odds with a cost benefit approach, since the latter implies trading off avoided climate damage with the costs of mitigation measures. However, even if such a trade-off is made, harm thresholds will occur if damage rises sharply beyond some critical amount of climate change. A look into the climate history will convince us that this is not a far-fetched idea. Climate changes in the past have often exhibited highly non-linear behaviour (see figure 1). Although the paleoclimatic record does not provide a perfect analogue to the current situation, it offers little comfort that abrupt climate change in response to our massive and rapid increase of atmospheric CO2 concentrations might not happen in the future. Consequently, cost benefit analyses accounting for the prospect of dangerous climate change have surfaced in recent years (e.g. Keller et al [6]). In addition, society has been prepared to set thresholds, e.g., to limit exposure to contaminants, even in situations where no clear jump in damage could be identified. And often such identification of thresholds was aided by cost benefit analysis (e.g. Gurian et al [7]). Is it appropriate to offer a deep time perspective on climate change such as presented in figure 1 in a discussion of 'dangerous anthropogenic interference'? Yes, because the magnitude of the anthropogenic perturbation of the carbon cycle forces us to go back far into the past, if we want to look for clues of what might happen in the future. Certainly, some of the climate changes reflected in figure 1 are a result of volcanism and continental drift, in particular the opening and closing of sea passages. However, recent data indicate that the carbon cycle was a major player in the transition from the Eocene hothouse to the modern-day icehouse world (e.g. Moran et al [11], Zachos et al [12]). The studies by Zachos et al [12] and Pearson and Palmer [13] found that carbon dioxide concentrations in the atmosphere decreased from well above 1000 ppm during the Eocene to below or around 300 ppm during the Mio-, Plio- and Pleistocene. On the basis of their data, it is likely that present-day levels of atmospheric carbon dioxide have not occurred for the last 23 million years. Moreover, projections of the growing anthropogenic perturbation of the carbon cycle in the 21st century, including scenarios that aim at stabilizing atmospheric CO2 concentration at twice its preindustrial value, carry us to carbon dioxide levels that were last seen during the Oligocene, where major restructuring of the climate system occurred. But what about time scales? Certainly, climate policy cannot be concerned with climate changes that unravel over millions of years. However, the slowest processes in the climate system, i.e., heat penetration into the deep ocean and changes in ice sheet volume, operate on time scales of thousands of years, with deglaciation potentially occurring much faster within hundreds of years. Hence, if the driver is sufficiently fast, rapid climate change can occur. This is evidenced in the paleoclimatic record shown in figure 1 by the event called Paleocene Eocene Thermal Maximum (PETM) 55 million years ago. During the PETM, global temperatures rose by 5 10 °C to presumably the hottest conditions during the Cenozoic era in a matter of several thousand years (Zachos et al [14]) due to a large perturbation of the carbon cycle (Zachos et al [15]) of hitherto unknown cause (Pagani et al [16]). A millennial time scale is still far beyond the time horizon of current socio-economic activity, but this is just the time scale for the system to equilibrate (bar the removal of carbon dioxide from the atmosphere ocean-biosphere reservoir which proceeds much more slowly [15]). Significant changes will be felt much earlier. And when it comes to assessing 'dangerous anthropogenic interference with the climate system' that has the potential to change the face of the planet for a hundred thousand or more years to come, an extension of our time horizon to several hundred years seems to be appropriate. Oxygen-18 stable isotope ratios in benthic foraminifera for the last 65 million years Figure 1. Any harm threshold here? Shown are δ18O stable isotope ratios (18O:16O relative to standard mean ocean water) in benthic foraminifera for the last 65 million years from Zachos et al [8]. The stable isotope ratio of the oxygen contained in the calcium carbonate of the foram shells depends on the water temperature in which they calcified (the warmer the water, the smaller δ18O). A complication arises from the fact that it also depends on the δ18O of the surrounding sea water, which is affected by latitude, evaporation and rainfall, and the presence or absence of large ice sheets. Therefore, these measurements can only be tied uniquely to past ocean temperatures for the early Cenozoic hothouse (Paleo- and Eocene) where no ice sheets existed, and for the most recent period by observing that the oxygen isotope measurements by Lisiecki and Raymo [9] are tightly correlated to temperature changes identified in the Vostok ice core (Petit et al [10]). Present day is indicated as 0. The large shifts of isotope ratio during the Oligocene also reflect changes in ice sheet volume. The figure was prepared by Robert A Rohde from published and publicly available data, and is distributed under the GNU free documentation license at www.globalwarmingart.com/wiki/Image:65_Myr_Climate_Change_Rev_png. While the paleoclimatic record in figure 1 can inform us that 'dangerous interference with the climate system' may be in store for a species that evolved during icehouse conditions, it can not yet point us to specific harm thresholds in the climate system. Our knowledge about the climate in the past is still too sparse, and the analogy to present-day conditions too limited. In order to get a better idea about harm thresholds as the global mean temperature continues to increase, we need to turn to model projections of future climate change and associated impacts, as well as our own normative assessment of what might be labeled dangerous and what not. Given the imperfection of state-of-the-art model projections, e.g., in terms of extreme event statistics (although some have become available, see Tebaldi et al [17]), agreement on the regional scale (although improving, see [1], p 12 and figure SPM-6), and ability to model abrupt climate change, and the foreseeable disagreement between societal groups on what might be dangerous, this will certainly be an exercise in guestimating and consensus finding on some sort of uncertainty measure for the location of thresholds to dangerous climate change. In his article, Harvey offers his own take on the problem by presenting two different harm-threshold probability distributions: a stringent variant with median at 1.5 °C and 95% quantile at 2.7 °C of global mean temperature increase since preindustrial time, and a more lenient variant with median at 2.5 °C and 95% quantile at 3.8 °C. Whether or not one believes the temperature values attached to the list of impacts that Harvey offers in support of his harm assessment, there is still a value judgment about the 'dangerousness' of these impacts to be made. As Harvey points out himself, this is a question that can be informed, but not answered by science. Consequently, the allowable CO2 concentrations to prevent dangerous anthropogenic interference with the climate system presented in Harvey's article reflect a value judgment. So it is for you, the reader, and society at large to decide whether or not these findings are significant. If your judgment about the onset of dangerous climate change lies somewhere in the range of Harvey's harm-threshold probability distributions, his results will carry meaning for you. I, for my part, can certainly answer this question in the affirmative. Once we accept this range of harm-threshold probabilities, the natural question emerges whether Harvey's result indicating that we are on the verge of dangerous anthropogenic interference with the climate system is inevitable. Is there an easy way out by adjusting the methodological framework that would present us considerably larger allowances of carbon in the atmosphere? It does not seem so. The virtue of Harvey's back-of-the-envelope calculation is that it includes the dominant factors in a simple, but fairly robust manner, which makes it hard to significantly alter the outcome by changing the details. Harvey has considered a wide range of medians and 95% quantiles for the probability distribution of climate sensitivity, but what if we changed the shape of both the climate sensitivity and harm-threshold probability density function (PDF)? After all, there is no particular reason why they should follow a lognormal distribution as Harvey assumed. The answer to this question is harbored by equation (1) of his article. The smaller the overlap between the climate sensitivity PDF and the harm-threshold CDF, the greater the carbon allowance available without committing dangerous interference with the climate system will be. And in this respect, Harvey's assumption of lognormality for both distributions goes some way in minimizing the overlap across possible shapes for fixed median and 95% quantiles. So what about peaking concentrations that can reach higher carbon dioxide levels because the part of the equilibrium warming they would entail will never be realized due to the time lag of the temperature response? Harvey has included this—as he calls it—climate-disequilibrium credit in his analysis, and thus his dire assessment of the proximity of dangerous interference extends to the case of transient climate change. True, he has not considered uncertainty in the heat uptake of the ocean that dominates the time lag of the temperature response along with climate sensitivity. But assuming a larger heat uptake and a slower temperature response within the confidence bounds allowed by the 20th century temperature and ocean heat content records is unlikely to change the carbon allowance by more than a few tens of ppm. Thus, Harvey's findings seem to stand firm once we underwrite the value judgment that the probability of dangerous climate change lies somewhere in the range of the harm-threshold probability distributions put forward in his article. The new sense of urgency to address climate change mirrors this judgment. References [1] IPCC 2007 Climate Change 2007: The Physical Science Basis - Summary for Policymakers. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (Cambridge: Cambridge University Press) in preparation (available for download at http://www.ipcc.ch) [2] Harvey L D D 2007 Allowable CO2 concentrations under the United Nations Framework Convention on Climate Change as a function of the climate sensitivity probability distribution function Environ. Res. Lett. 2 014001 [3] Dessai S, Adger W N, Hulme M, Turnpenny J, Köhler J and Warren R 2004 Defining and experiencing dangerous climate change Clim. Change 64 11 25 [4] Oppenheimer M and Petsonk A 2005 Article 2 of the UNFCCC: historical origins, recent interpretations Clim. Change 73 195 226 [5] Schellnhuber H J, Cramer W, Nakicenovic N, Wigley T and Yohe G (ed) 2006 Avoiding Dangerous Climate Change (Cambridge: Cambridge University Press) pp 392 [6] Keller K, Hall M, Kim S R, Bradford D F and Oppenheimer M 2005 Avoiding dangerous anthropogenic interference with the climate system Clim. Change 73 227 38 [7] Gurian P L, Small M J, Lockwood J R and Schervish M J 2001 Benefit-cost estimation for alternative drinking water maximum contaminant levels Water Resources Res. 37 2213 16 [8] Zachos J C, Pagani M, Sloan L, Thomas E and Billups K 2001 Trends, rhythms, and aberrations in global climate 65 Ma to present Science 292 686 93 [9] Lisiecki L E and Raymo M E 2005 A Pliocene Pleistocene stack of 57 globally distributed benthic δ18O records Paleoceanography 20 PA1003 [10] Petit J R, Jouzel J, Raynaud D, Barkov N I, Barnola J M, Basile I, Bender M, Chappellaz J, Davis J, Delaygue G, Delmotte M, Kotlyakov V M, Legrand M, Lipenkov V, Lorius C, Pépin L, Ritz C, Saltzman E and Stievenard M 1999 Climate and Atmospheric History of the Past 420 000 years from the Vostok Ice Core, Antarctica Nature 399 429 36 [11] Morgan K and the ACEX expedition team 2006 The Cenozic paleoenvironment of the Arctic Ocean Nature 441 601 5 [12] Pagani M, Zachos J C, Freeman K H, Tipple B and Bohaty S 2005 Marked decline in atmospheric carbon dioxide concentrations during the paleogene Science 309 600 3 [13] Pearson P N and Palmer M R 2000 Atmospheric carbon dioxide concentrations over the past 60 million years Nature 406 695 9 [14] Zachos J C, Wara M W, Bohaty S, Delaney M L, Petrizzo M R, Brill A, Bralower, T J and Premoli-Silva I 2003 A transient rise in tropical sea surface temperature during the Paleocene Eocene Thermal Maximum Science 302 1551 4 [15] Zachos J C, Röhl U, Schellenberg S A, Sluijs A, Hodell D A, Kelly D C, Thomas E, Nicolo M, Raffi I, Lourens L J, McCarren H and Kroon D 2005 Rapid acidification of the ocean during the Paleocene Eocene Thermal Maximum Science 308 1611 5 [16] Pagani M, Caldeira K, Archer D, Zachos J C 2006 An ancient carbon mystery Science 314 1556 7 [17] Tebaldi C, Hayhoe K, Arblaster J M and Meehl G A 2006 Going to the extremes: an intercomparison of model-simulated historical and future changes in extreme events Clim. Change 79 185 211 Photo of Elmar Kriegler Elmar Kriegler received a diploma (MS equivalent) degree in physics from the Albert-Ludwigs-University of Freiburg, Germany, in 1998, and a PhD degree in physics from the University of Potsdam, Germany, in 2005. He worked for seven years as a graduate/post-doctoral researcher at the Potsdam Institute of Climate Impact Research on topics relating to the integrated assessment of climate change. He is now a visiting researcher at Carnegie Mellon University in Pittsburgh, USA, where he works—with support by a Marie-Curie Outgoing International Fellowship from the European Union—on the evaluation of climate policies under large uncertainty about climate change.
A most spectrum-efficient duplexing system: CDD
NASA Astrophysics Data System (ADS)
Lee, William C. Y.
2001-10-01
The game to play in wireless communications when it comes to increasing spectrum efficiency is to eliminate interference. Currently, all cellular systems use FDD (Frequency Division Duplexing) in an attempt to eliminate the interference from the adjacent cells. Through the use of many technologies only one type of interference remains and that is the adjacent base-tohome mobile interference. TDD (Time Division Duplexing) has not been used for mobile cellular systems, not only because of the adjacent base-to-home mobile interference, but also because of the additional adjacent base-to-home base interference, and adjacent mobile-to-home mobile interference. Therefore, TDD can only be used for small, confined area systems. CDD (Code Division Duplexing) can eliminate all three kinds of interference; the adjacent base-to-home mobile, the adjacent baseto-home base, and the adjacent mobile- to- home in cellular systems. Eliminating each of these interferences makes CDD the most spectrum efficient duplexing system. This talk will elaborate on a set of smart codes, which will make an efficient CDD system a reality.
CW Interference Effects on High Data Rate Transmission Through the ACTS Wideband Channel
NASA Technical Reports Server (NTRS)
Kerczewski, Robert J.; Ngo, Duc H.; Tran, Quang K.; Tran, Diepchi T.; Yu, John; Kachmar, Brian A.; Svoboda, James S.
1996-01-01
Satellite communications channels are susceptible to various sources of interference. Wideband channels have a proportionally greater probability of receiving interference than narrowband channels. NASA's Advanced Communications Technology Satellite (ACTS) includes a 900 MHz bandwidth hardlimiting transponder which has provided an opportunity for the study of interference effects of wideband channels. A series of interference tests using two independent ACTS ground terminals measured the effects of continuous-wave (CW) uplink interference on the bit-error rate of a 220 Mbps digitally modulated carrier. These results indicate the susceptibility of high data rate transmissions to CW interference and are compared to results obtained with a laboratory hardware-based system simulation and a computer simulation.
Near-Field Noise Source Localization in the Presence of Interference
NASA Astrophysics Data System (ADS)
Liang, Guolong; Han, Bo
In order to suppress the influence of interference sources on the noise source localization in the near field, the near-field broadband source localization in the presence of interference is studied. Oblique projection is constructed with the array measurements and the steering manifold of interference sources, which is used to filter the interference signals out. 2D-MUSIC algorithm is utilized to deal with the data in each frequency, and then the results of each frequency are averaged to achieve the positioning of the broadband noise sources. The simulations show that this method suppresses the interference sources effectively and is capable of locating the source which is in the same direction with the interference source.
NASA Astrophysics Data System (ADS)
Sharma, S. K.; Misra, A. K.; Clegg, S. M.; Barefield, J. E.; Wiens, R. C.; Acosta, T.
2009-12-01
We have used a remote time-resolved (TR) telescopic Raman system equipped with 532 nm pulsed laser excitation and a gated intensified CCD (ICCD) detector for measuring Raman spectra of a number of minerals under two sets of conditions. The first set of experiments involved probing samples as a function of temperature ranging from 300 to 973 K at 1 atm. These experiments involve a 5x beam expander to focus the 532 nm (30 mJ/pulse 20 Hz) laser beams onto the sample at 9 m from the remote Raman system. The second set of experiments involved placing the samples in a high pressure vessel with a sapphire window containing supercritical CO2 at pressures up to 93 atm and 423 K. At high temperatures and ambient pressure, the remote Raman measurements were made with samples at 9 meter distance inside a high temperature furnace by gating the ICCD detector with 2 micro-s gate to minimize interference from blackbody emission from mineral surfaces at high temperature as well as interference from ambient light. A comparison of Raman spectra of gypsum (CaSO4.2H2O), dolomite (CaMg(CO3)2), and olivine (Mg2Fe2-xSiO4), as a function of temperature shows that the Raman lines remains sharp and well defined even in the high temperature spectra. In the pressure vessel, Cr3+ fluorescence from sapphire window interfere with the Raman spectra of hydrous minerals in the high-frequency region (2500-4500 cm-1). With time-resolved Raman measurements the interference of the fluorescence in the Raman spectra on minerals was minimized by gating ICCD to <100 ns. The Fermi resonance doublet of CO2 molecules consisting of Raman lines at 1285 (2ν2) and 1388 (ν1) cm-1 does not interfere with the major Raman fingerprints of silicates, carbonate, sulfates minerals. With suitable time delay of the ICCD detector, the Raman bands from supercritical CO2 atmosphere can be minimized providing pure Raman spectra of the mineral targets. We will present remote Raman data on silicates (olivine, pyroxene, quartz, feldspars and talc), dolomite, gypsum, hydrous iron sulfate and barite under supercritical CO2 environment. With TR remote Raman system using 532 nm (15 mJ/pulse, 20Hz) laser excitation, a large varieties of minerals could be easily identified from their respective Raman fingerprints typically in 1s. Minerals with low Raman cross section (e.g., feldspars, pyroxene, olivine, talc, etc) can be detected and quantified from their respective Raman spectra in 10 to 30 s. These results show that time-resolve remote Raman system is capable of making spectral measurements at several hundred to thousand target points on Venus surface within limited (a few hours) expected lifetime of a lander because of extreme temperature and pressure conditions.
[An Algorithm to Eliminate Power Frequency Interference in ECG Using Template].
Shi, Guohua; Li, Jiang; Xu, Yan; Feng, Liang
2017-01-01
Researching an algorithm to eliminate power frequency interference in ECG. The algorithm first creates power frequency interference template, then, subtracts the template from the original ECG signals, final y, the algorithm gets the ECG signals without interference. Experiment shows the algorithm can eliminate interference effectively and has none side effect to normal signal. It’s efficient and suitable for practice.
Cooperative Interference Alignment for the Multiple Access Channel
2015-11-01
Communications. I. INTRODUCTION Conventional wireless networks were previously thought to be interference-limited, where interference is mainly caused by...interference-free capacity for any number of users K at high SNR. This fundamental result showed that wireless networks are not interference-limited as...decoding of the K users’ messages. This is applicable in uplink transmissions in cellular communications, where mobiles transmit independent messages
Exposure to space radiation of high-performance infrared multilayer filters
NASA Technical Reports Server (NTRS)
Seeley, J. S.; Hawkins, G. J.; Hunneman, R.
1991-01-01
The University of Reading experiment exposed IR interference filters and crystal substrates on identical earth facing and leading-edge sites of the Long Duration Exposure Facility (LDEF). Filters mostly comprised multilayer coatings of lead telluride (PbTe)/II-IV on germanium (Ge) and other substrates: crystals comprised CdTe, MgF2, sapphire, quartz, silicon, and some softer materials. Identical control samples were maintained in the laboratory throughout the experiment. The filters were novel in their design, construction and manufacture, and categorized high-performance because of their ability to resolve emission spectra of the important atmospheric gases for various purposes in remote sensing. No significant changes were found in the spectra of the hard-coated filters or in the harder crystals (the softer materials were degraded to an extent). By virtue of this well-documented and long exposure in LDEF, the qualification of the filter type is significantly improved for its future requirements.
NASA Astrophysics Data System (ADS)
Argento, David C.; Stone, John O.; Keith Fifield, L.; Tims, Stephen G.
2010-04-01
Natural cosmogenic 36Cl found in seawater originates from spallation of atmospheric 40Ar, capture of secondary cosmic-ray neutrons by dissolved 35Cl, and river runoff which contains 36Cl produced in situ over the surface of the continents. The long residence time of chloride in the ocean and long half-life of 36Cl compared to the oceanic mixing time should result in a homogenous 36Cl/Cl ratio throughout the ocean. Production by neutron capture in the course of nuclear weapons testing should be insignificant averaged over the oceans as a whole, but may have led to regions of elevated 36Cl concentration. Previous attempts to measure the 36Cl/Cl ratio of seawater have been hindered by interferences, contamination, or insufficient analytic sensitivity. Here we report preliminary measurements on seawater samples, which demonstrate that the 36Cl/Cl ratio is 0.5 ± 0.3 × 10 -15, in reasonable agreement with calculated contributions from the sources listed above.
NASA Technical Reports Server (NTRS)
Ladson, Charles L.; Hill, Acquilla S.; Johnson, William G., Jr.
1987-01-01
Tests were conducted in the 2-D test section of the Langley 0.3-meter Transonic Cryogenic Tunnel on a NACA 0012 airfoil to obtain aerodynamic data as a part of the Advanced Technology Airfoil Test (ATAT) program. The test program covered a Mach number range of 0.30 to 0.82 and a Reynolds number range of 3.0 to 45.0 x 10 to the 6th power. The stagnation pressure was varied between 1.2 and 6.0 atmospheres and the stagnation temperature was varied between 300 K and 90 K to obtain these test conditions. Tabulated pressure distributions and integrated force and moment coefficients are presented as well as plots of the surface pressure distributions. The data are presented uncorrected for wall interference effects and without analysis.
Cosmic-Ray Energetics and Mass Processing - Unbagging and Inspection
2017-06-22
Research that started aboard balloons a century ago will soon culminate in a three-year stint aboard the International Space Station as scientists work on solving a fundamental astrophysics mystery: What gives cosmic rays such incredible energies, and how does that affect the composition of the universe? The Cosmic-Ray Energetics and Mass investigation, known as CREAM, places a highly successful balloon-borne instrument aboard the International Space Station where it gathers an order of magnitude (ten times) more data, which has lower background interference because Earth's atmosphere is no longer interfering. CREAM's instruments measure the charges of cosmic rays ranging from hydrogen up through iron nuclei, over a broad energy range. The modified balloon instrument is carried aloft on a SpaceX Dragon Lab cargo supply mission and placed on the Japanese Exposed Module for a period of at least three years.
A semianalytic radiance model of ocean color
NASA Technical Reports Server (NTRS)
Gordon, Howard R.; Brown, James W.; Brown, Otis B.; Evans, Robert H.; Smith, Raymond C.
1988-01-01
A semianalytical radiance model is developed which predicts the upwelled spectral radiance at the sea surface as a function of the phytoplankton pigment concentration for Morel Case 1 waters. The model is in good agreement with experimental measurements carried out in waters which were not included in the data base used to derive it. It suggests that the observed variability in the radiance is due to variations in the backscattering of plankton and the associated detrital material. The model is extended to include other material in the water, such as dissolved organic material, referred to as yellow substances, and detached coccoliths from coccolithophorids, e.g., Emiliana huxleyi. Potential applications include an improved biooptical algorithm for the retrieval of pigment concentrations from satellite imagery in the presence of interference from detached coccoliths and an improved atmospheric correction for satellite imagery. The model also serves to identify and to interpret deviations from Case 1 waters.
Distribution of high-dimensional entanglement via an intra-city free-space link
Steinlechner, Fabian; Ecker, Sebastian; Fink, Matthias; Liu, Bo; Bavaresco, Jessica; Huber, Marcus; Scheidl, Thomas; Ursin, Rupert
2017-01-01
Quantum entanglement is a fundamental resource in quantum information processing and its distribution between distant parties is a key challenge in quantum communications. Increasing the dimensionality of entanglement has been shown to improve robustness and channel capacities in secure quantum communications. Here we report on the distribution of genuine high-dimensional entanglement via a 1.2-km-long free-space link across Vienna. We exploit hyperentanglement, that is, simultaneous entanglement in polarization and energy-time bases, to encode quantum information, and observe high-visibility interference for successive correlation measurements in each degree of freedom. These visibilities impose lower bounds on entanglement in each subspace individually and certify four-dimensional entanglement for the hyperentangled system. The high-fidelity transmission of high-dimensional entanglement under real-world atmospheric link conditions represents an important step towards long-distance quantum communications with more complex quantum systems and the implementation of advanced quantum experiments with satellite links. PMID:28737168
Data inversion algorithm development for the hologen occultation experiment
NASA Technical Reports Server (NTRS)
Gordley, Larry L.; Mlynczak, Martin G.
1986-01-01
The successful retrieval of atmospheric parameters from radiometric measurement requires not only the ability to do ideal radiometric calculations, but also a detailed understanding of instrument characteristics. Therefore a considerable amount of time was spent in instrument characterization in the form of test data analysis and mathematical formulation. Analyses of solar-to-reference interference (electrical cross-talk), detector nonuniformity, instrument balance error, electronic filter time-constants and noise character were conducted. A second area of effort was the development of techniques for the ideal radiometric calculations required for the Halogen Occultation Experiment (HALOE) data reduction. The computer code for these calculations must be extremely complex and fast. A scheme for meeting these requirements was defined and the algorithms needed form implementation are currently under development. A third area of work included consulting on the implementation of the Emissivity Growth Approximation (EGA) method of absorption calculation into a HALOE broadband radiometer channel retrieval algorithm.
Environmental effects and large space systems
NASA Technical Reports Server (NTRS)
Garrett, H. B.
1981-01-01
When planning large scale operations in space, environmental impact must be considered in addition to radiation, spacecraft charging, contamination, high power and size. Pollution of the atmosphere and space is caused by rocket effluents and by photoelectrons generated by sunlight falling on satellite surfaces even light pollution may result (the SPS may reflect so much light as to be a nuisance to astronomers). Large (100 Km 2) structures also will absorb the high energy particles that impinge on them. Altogether, these effects may drastically alter the Earth's magnetosphere. It is not clear if these alterations will in any way affect the Earth's surface climate. Large structures will also generate large plasma wakes and waves which may cause interference with communications to the vehicle. A high energy, microwave beam from the SPS will cause ionospheric turbulence, affecting UHF and VHF communications. Although none of these effects may ultimately prove critical, they must be considered in the design of large structures.
Photophoretic levitation of engineered aerosols for geoengineering
Keith, David W.
2010-01-01
Aerosols could be injected into the upper atmosphere to engineer the climate by scattering incident sunlight so as to produce a cooling tendency that may mitigate the risks posed by the accumulation of greenhouse gases. Analysis of climate engineering has focused on sulfate aerosols. Here I examine the possibility that engineered nanoparticles could exploit photophoretic forces, enabling more control over particle distribution and lifetime than is possible with sulfates, perhaps allowing climate engineering to be accomplished with fewer side effects. The use of electrostatic or magnetic materials enables a class of photophoretic forces not found in nature. Photophoretic levitation could loft particles above the stratosphere, reducing their capacity to interfere with ozone chemistry; and, by increasing particle lifetimes, it would reduce the need for continual replenishment of the aerosol. Moreover, particles might be engineered to drift poleward enabling albedo modification to be tailored to counter polar warming while minimizing the impact on equatorial climates. PMID:20823254
Photophoretic levitation of engineered aerosols for geoengineering.
Keith, David W
2010-09-21
Aerosols could be injected into the upper atmosphere to engineer the climate by scattering incident sunlight so as to produce a cooling tendency that may mitigate the risks posed by the accumulation of greenhouse gases. Analysis of climate engineering has focused on sulfate aerosols. Here I examine the possibility that engineered nanoparticles could exploit photophoretic forces, enabling more control over particle distribution and lifetime than is possible with sulfates, perhaps allowing climate engineering to be accomplished with fewer side effects. The use of electrostatic or magnetic materials enables a class of photophoretic forces not found in nature. Photophoretic levitation could loft particles above the stratosphere, reducing their capacity to interfere with ozone chemistry; and, by increasing particle lifetimes, it would reduce the need for continual replenishment of the aerosol. Moreover, particles might be engineered to drift poleward enabling albedo modification to be tailored to counter polar warming while minimizing the impact on equatorial climates.
Design of all-weather celestial navigation system
NASA Astrophysics Data System (ADS)
Sun, Hongchi; Mu, Rongjun; Du, Huajun; Wu, Peng
2018-03-01
In order to realize autonomous navigation in the atmosphere, an all-weather celestial navigation system is designed. The research of celestial navigation system include discrimination method of comentropy and the adaptive navigation algorithm based on the P value. The discrimination method of comentropy is studied to realize the independent switching of two celestial navigation modes, starlight and radio. Finally, an adaptive filtering algorithm based on P value is proposed, which can greatly improve the disturbance rejection capability of the system. The experimental results show that the accuracy of the three axis attitude is better than 10″, and it can work all weather. In perturbation environment, the position accuracy of the integrated navigation system can be increased 20% comparing with the traditional method. It basically meets the requirements of the all-weather celestial navigation system, and it has the ability of stability, reliability, high accuracy and strong anti-interference.
Emission of volatile organic compounds from petunia flowers is facilitated by an ABC transporter.
Adebesin, Funmilayo; Widhalm, Joshua R; Boachon, Benoît; Lefèvre, François; Pierman, Baptiste; Lynch, Joseph H; Alam, Iftekhar; Junqueira, Bruna; Benke, Ryan; Ray, Shaunak; Porter, Justin A; Yanagisawa, Makoto; Wetzstein, Hazel Y; Morgan, John A; Boutry, Marc; Schuurink, Robert C; Dudareva, Natalia
2017-06-30
Plants synthesize a diversity of volatile molecules that are important for reproduction and defense, serve as practical products for humans, and influence atmospheric chemistry and climate. Despite progress in deciphering plant volatile biosynthesis, their release from the cell has been poorly understood. The default assumption has been that volatiles passively diffuse out of cells. By characterization of a Petunia hybrida adenosine triphosphate-binding cassette (ABC) transporter, PhABCG1, we demonstrate that passage of volatiles across the plasma membrane relies on active transport. PhABCG1 down-regulation by RNA interference results in decreased emission of volatiles, which accumulate to toxic levels in the plasma membrane. This study provides direct proof of a biologically mediated mechanism of volatile emission. Copyright © 2017 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.
A brief perspective on computational electromagnetics
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nachman, A.
1996-06-01
There is a growing interest in many quarters in acquiring the ability to predict all manner of electromagnetic (EM) effects. These effects include radar scattering attributes of objects (airplanes, missles, tanks, ships, etc.); the mutal interference of a multitude of antennas on board a single aircraft or ship; the performance of integrated circuits (IC); the propagation of waves (radio and radar) over long distances with the help of hindrance of complicated tomography and ionospheric/atmospheric ducting; and the propagation of pulses through dispersive media (soil, treetops, or concrete) to detect pollutants or hidden targets, or to assess the health of runways.more » All of the above require extensive computation and, despite the fact that Maxwell`s equations are linear in all these cases, codes do not exist which will do the job in a timely and error-controlled manner. This report briefly discusses how this can be rectified. 16 refs.« less
Cooled optical filters for Q-band infrared astronomy (15-40 μm)
NASA Astrophysics Data System (ADS)
Hawkins, Gary J.; Sherwood, Richard E.; Djotni, Karim; Threadgold, Timothy M.
2016-07-01
With a growing interest in mid- and far-infrared astronomy using cooled imaging and spectrometer instruments in highaltitude observatories and spaceflight telescopes, it is becoming increasingly important to characterise and assess the spectral performance of cooled multilayer filters across the Q-band atmospheric window. This region contains spectral features emitted by many astrophysical phenomena and objects fundamental to circumstellar and planetary formation theories. However extending interference filtering to isolate radiation at progressively longer wavelengths and improve photometric accuracy is an area of ongoing and challenging thin-film research. We have successfully fabricated cooled bandpass and edge filters with high durability for operation across the 15-30 μm Q-band region. In this paper we describe the rationale for selection of optical materials and properties of fabricated thin-film coatings for this region, together with FTIR spectral measurements and assessment of environmental durability.
Firefighters' communication transceiver test plan
NASA Astrophysics Data System (ADS)
Wallace, R. J.
1984-05-01
The requirements for the operational testing of the firefighters communication transceiver were identified. The major concerns centered around the integrity and reliability of the firefighter/microphone interface. The major concern about the radio hardware was that it be intrinsically safe in hazardous atmospheres and that the system not interfere with the fit or facial seal of self-contained breathing apparatus (SCBA). The greatest concern for operational testing purposes as the reliability and clarity of the line of communication between the firefighter and those on the fireground with whom he must maintain contact. A desire to test any units developed in both training exercises and in real responses to hazardous material incidents was expressed. It is felt that a VOX-microphone built into the SCBA facemask gives the best performance. A voice-pickup product device which combines a bone conduction microphone and a speaker into a single ear mounted unit is examined.
Electrostatic Charging of the Pathfinder Rover
NASA Technical Reports Server (NTRS)
Siebert, Mark W.; Kolecki, Joseph C.
1996-01-01
The Mars Pathfinder mission will send a lander and a rover to the martian surface. Because of the extremely dry conditions on Mars, electrostatic charging of the rover is expected to occur as it moves about. Charge accumulation may result in high electrical potentials and discharge through the martian atmosphere. Such discharge could interfere with the operation of electrical elements on the rover. A strategy was sought to mitigate this charge accumulation as a precautionary measure. Ground tests were performed to demonstrate charging in laboratory conditions simulating the surface conditions expected at Mars. Tests showed that a rover wheel, driven at typical rover speeds, will accumulate electrical charge and develop significant electrical potentials (average observed, 110 volts). Measurements were made of wheel electrical potential, and wheel capacitance. From these quantities, the amount of absolute charge was estimated. An engineering solution was developed and recommended to mitigate charge accumulation. That solution has been implemented on the actual rover.
Toward Optical Sensors: Review and Applications
NASA Astrophysics Data System (ADS)
Sabri, Naseer; Aljunid, S. A.; Salim, M. S.; Ahmad, R. B.; Kamaruddin, R.
2013-04-01
Recent advances in fiber optics (FOs) and the numerous advantages of light over electronic systems have boosted the utility and demand for optical sensors in various military, industry and social fields. Environmental and atmospheric monitoring, earth and space sciences, industrial chemical processing and biotechnology, law enforcement, digital imaging, scanning, and printing are exemplars of them. The ubiquity of photonic technologies could drive down prices which reduced the cost of optical fibers and lasers. Fiber optic sensors (FOSs) offer a wide spectrum of advantages over traditional sensing systems, such as small size and longer lifetime. Immunity to electromagnetic interference, amenability to multiplexing, and high sensitivity make FOs the sensor technology of choice in several fields, including the healthcare and aerospace sectors. FOSs show reliable and rigid sensing tasks over conventional electrical and electronic sensors. This paper presents an executive review of optical fiber sensors and the most beneficial applications.
NASA Astrophysics Data System (ADS)
Afzelius, M.; Bengtsson, P.-E.; Bood, J.; Bonamy, J.; Chaussard, F.; Berger, H.; Dreier, T.
Rotational coherent anti-Stokes Raman spectroscopy (CARS) is a well-established spectroscopic technique for thermometry at pre-combustion temperatures and atmospheric pressure. However, at pressures of several MPa, a previous investigation revealed large discrepancies between experimental data and the theoretical model. A re-evaluation has been made of these data (at room temperature and in the range 1.5-9 MPa) with two improvements to the spectral code. The first is the inclusion of an inter-branch interference effect, which is described in detail in Paper I. The second is the use of experimental S1-branch Raman line widths measured at 295 K, with a temperature dependence extracted from semi-classical calculations following the Robert-Bonamy formalism. It is shown that these two modifications significantly improve the theoretical model, since both the spectral fits and the accuracy of the evaluated temperatures are considerably improved.
Holographic detection of hydrocarbon gases and other volatile organic compounds.
Martínez-Hurtado, J L; Davidson, C A B; Blyth, J; Lowe, C R
2010-10-05
There is a need to develop sensors for real-time monitoring of volatile organic compounds (VOCs) and hydrocarbon gases in both external and indoor environments, since these compounds are of growing concern in human health and welfare. Current measurement technology for VOCs requires sophisticated equipment and lacks the prospect for rapid real-time monitoring. Holographic sensors can give a direct reading of the analyte concentration as a color change. We report a technique for recording holographic sensors by laser ablation of silver particles formed in situ by diffusion. This technique allows a readily available hydrophobic silicone elastomer to be transformed into an effective sensor for hydrocarbon gases and other volatile compounds. The intermolecular interactions present between the polymer and molecules are used to predict the sensor performance. The hydrophobicity of this material allows the sensor to operate without interference from water and other atmospheric gases and thus makes the sensor suitable for biomedical, industrial, or environmental analysis.
Surface profile changes of scuffed bearing surfaces. [before and after acid treatment
NASA Technical Reports Server (NTRS)
Lauer, J. L.; Fung, S. S.; Jones, W. R., Jr.
1982-01-01
A phase locked interference microscope capable of resolving depth differences to 30 A and planar displacements of 6000 A was constructed for the examination of the profiles of bearing surfaces without physical contact. This instrument was used to determine surface chemical reactivity by applying a drop of dilute alcoholic hydrochloric acid and measuring the profile of the solid surface before and after application of this probe. Scuffed bearing surfaces reacted much faster than unscuffed ones, but bearing surfaces which had been previously exposed to lubricants containing an organic chloride reacted much more slowly. In a separate series of experiments, a number of stainless steel plates were heated in a nitrogen atmosphere to different temperatures and their reactivity examined later at room temperature. The change of surface contour as a result of the probe reaction followed an Arrhenius type relation with respect to heat treatment temperature. This result could have implications on the scuffing mechanism.
Firefighters' communication transceiver test plan
NASA Technical Reports Server (NTRS)
Wallace, R. J.
1984-01-01
The requirements for the operational testing of the firefighters communication transceiver were identified. The major concerns centered around the integrity and reliability of the firefighter/microphone interface. The major concern about the radio hardware was that it be intrinsically safe in hazardous atmospheres and that the system not interfere with the fit or facial seal of self-contained breathing apparatus (SCBA). The greatest concern for operational testing purposes as the reliability and clarity of the line of communication between the firefighter and those on the fireground with whom he must maintain contact. A desire to test any units developed in both training exercises and in real responses to hazardous material incidents was expressed. It is felt that a VOX-microphone built into the SCBA facemask gives the best performance. A voice-pickup product device which combines a bone conduction microphone and a speaker into a single ear mounted unit is examined.
Impact of LANDSAT MSS sensor differences on change detection analysis
NASA Technical Reports Server (NTRS)
Likens, W. C.; Wrigley, R. C.
1983-01-01
Some 512 by 512 pixel subwindows for simultaneously acquired scene pairs obtained by LANDSAT 2,3 and 4 multispectral band scanners were coregistered using LANDSAT 4 scenes as the base to which the other images were registered. Scattergrams between the coregistered scenes (a form of contingency analysis) were used to radiometrically compare data from the various sensors. Mode values were derived and used to visually fit a linear regression. Root mean square errors of the registration varied between .1 and 1.5 pixels. There appear to be no major problem preventing the use of LANDSAT 4 MSS with previous MSS sensors for change detection, provided the noise interference can be removed or minimized. Data normalizations for change detection should be based on the data rather than solely on calibration information. This allows simultaneous normalization of the atmosphere as well as the radiometry.
Voyager Saturn encounter attitude and articulation control experience
NASA Technical Reports Server (NTRS)
Carlisle, G.; Hill, M.
1981-01-01
The Voyager attitude and articulation control system is designed for a three-axis stabilized spacecraft; it uses a biasable sun sensor and a Canopus Star Tracker (CST) for celestial control, as well as a dry inertial reference unit, comprised of three dual-axis dry gryos, for inertial control. A series of complex maneuvers was required during the first of two Voyager spacecraft encounters with Saturn (November 13, 1980); these maneuvers involved rotating the spacecraft simultaneously about two or three axes while maintaining accurate pointing of the scan platform. Titan and Saturn earth occulation experiments and a ring scattering experiment are described. Target motion compensation and the effects of celestial sensor interference are also considered. Failure of the CST, which required an extensive reevaluation of the star reference and attitude control mode strategy, is discussed. Results analyzed thus far show that the system performed with high accuracy, gathering data deeper into Saturn's atmosphere than on any previous planetary encounter.
Air Entrapment for Liquid Drops Impacting a Solid Substrate
NASA Astrophysics Data System (ADS)
Liu, Yuan; Tan, Peng; Xu, Lei
2012-11-01
Using high-speed photography coupled with optical interference, we experimentally study the air entrapment during a liquid drop impacting a solid substrate. We observe the formation of a compressed air film before the liquid touches the substrate, with internal pressure considerably higher than the atmospheric value. The degree of compression highly depends on the impact velocity, as explained by balancing the liquid deceleration with the large pressure of compressed air. After contact, the air film expands vertically at the edge, reducing its pressure within a few tens of microseconds and producing a thick rim on the perimeter. This thick-rimmed air film subsequently contracts into an air bubble, governed by the complex interaction between surface tension, inertia and viscous drag. Such a process is universally observed for impacts above a few centimeters high. Hong Kong GRF grant CUHK404211 and direct grant 2060418.
Cluster analysis of polymers using laser-induced breakdown spectroscopy with K-means
NASA Astrophysics Data System (ADS)
Yangmin, GUO; Yun, TANG; Yu, DU; Shisong, TANG; Lianbo, GUO; Xiangyou, LI; Yongfeng, LU; Xiaoyan, ZENG
2018-06-01
Laser-induced breakdown spectroscopy (LIBS) combined with K-means algorithm was employed to automatically differentiate industrial polymers under atmospheric conditions. The unsupervised learning algorithm K-means were utilized for the clustering of LIBS dataset measured from twenty kinds of industrial polymers. To prevent the interference from metallic elements, three atomic emission lines (C I 247.86 nm , H I 656.3 nm, and O I 777.3 nm) and one molecular line C–N (0, 0) 388.3 nm were used. The cluster analysis results were obtained through an iterative process. The Davies–Bouldin index was employed to determine the initial number of clusters. The average relative standard deviation values of characteristic spectral lines were used as the iterative criterion. With the proposed approach, the classification accuracy for twenty kinds of industrial polymers achieved 99.6%. The results demonstrated that this approach has great potential for industrial polymers recycling by LIBS.
Distribution of high-dimensional entanglement via an intra-city free-space link.
Steinlechner, Fabian; Ecker, Sebastian; Fink, Matthias; Liu, Bo; Bavaresco, Jessica; Huber, Marcus; Scheidl, Thomas; Ursin, Rupert
2017-07-24
Quantum entanglement is a fundamental resource in quantum information processing and its distribution between distant parties is a key challenge in quantum communications. Increasing the dimensionality of entanglement has been shown to improve robustness and channel capacities in secure quantum communications. Here we report on the distribution of genuine high-dimensional entanglement via a 1.2-km-long free-space link across Vienna. We exploit hyperentanglement, that is, simultaneous entanglement in polarization and energy-time bases, to encode quantum information, and observe high-visibility interference for successive correlation measurements in each degree of freedom. These visibilities impose lower bounds on entanglement in each subspace individually and certify four-dimensional entanglement for the hyperentangled system. The high-fidelity transmission of high-dimensional entanglement under real-world atmospheric link conditions represents an important step towards long-distance quantum communications with more complex quantum systems and the implementation of advanced quantum experiments with satellite links.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Shukla, Anil K.; Zhang, Rui; Orton, Daniel J.
Two unexpected singly charged ions at m/z 1103 and 944 have been observed in mass spectra obtained from electrospray ionization-mass spectrometric analysis of liquid chromatography effluents with mobile phases containing trifluoroacetic acid. Accurate mass measurement and tandem mass spectrometry studies revealed that these two ions are not due to any contamination from solvents and chemicals used for mobile and stationary phases or from the laboratory atmospheric environment. Instead these ions are clusters of trifluoroacetic acid formed in association with acetonitrile, water and iron from the stainless steel union used to connect the column with the electrospray tip and to applymore » high voltage; the molecular formulae are Fe+((OH)(H2O)2)9(CF3COOH)5 and Fe+((OH)(H2O)2)6 (CF3COOH)5.« less
NASA Astrophysics Data System (ADS)
Esposito, Francesca; Colangeli, Luigi; Palumbo, Pasquale; Della Corte, Vincenzo; Molfese, Cesare; Merrison, Jonathan; Nornberg, Per; Lopez-Moreno, J. J.; Rodriguez Gomez, Julio
Dust and water vapour are fundamental components of Martian atmosphere. Dust amount varies with seasons and with the presence of local and global dust storms, but never drops entirely to zero. Aerosol dust has always played a fundamental role on the Martian climate. Dust interaction with solar and thermal radiation and the related condensation and evaporation processes influence the thermal structure and balance, and the dynamics (in terms of circulation) of the atmosphere. Water vapour is a minor constituent of the Martian atmosphere but it plays a fundamental role and it is important as indicator of seasonal climate changes. Moreover, the interest about the water cycle on local and global scales is linked to the fundamental function that water could have played in relation to the existence of living organisms on Mars. In view of tracing the past environmental conditions on Mars, that possibly favoured the appearing of life forms, it is important to study the present climate and its evolution, on which dust and water vapour have (and have had) strong influence. Moreover, nowadays, dust is a relevant agent that affects environmental conditions in the lower Martian atmosphere and, thus, may interact / interfere with any instrumentation delivered to Mars surface for in situ analyses. So, information on dust properties and deposition rate is also of great interest for future mission design. Knowledge of how much dust settles on solar arrays and the size and shape of particles will be crucial elements for designing missions that will operate by solar power for periods of several years and will have moving parts which will experience degradation by dust. This information is essential also for proper planning of future manned missions in relation to characterisation of environmental hazardous conditions. Little is known about dust structure and dynamics, so far. Size distribution is known only roughly and the mechanism of settling and rising into the atmosphere, the rates and geographic variability are matter of controversy. The instrument MEDUSA (Martian Environmental DUst Systematic Analyser) has been designed to measure directly and quantitatively in situ the cumulative dust mass flux and dust deposition rate, the physical and electrification properties, the size distribution of intercepted particles and the water vapour abundance versus time, a goal that has never been reached so far. MEDUSA has been selected by ESA as one of the environmental instruments to be included in the payload Humboldt of ExoMars lander.
Hedden, Trey; Yoon, Carolyn
2006-09-01
Recent theories have suggested that resistance to interference is a unifying principle of executive function and that individual differences in interference may be explained by executive function (M. J. Kane & R. W. Engle, 2002). Measures of executive function, memory, and perceptual speed were obtained from 121 older adults (ages 63-82). We used structural equation modeling to investigate the relationships of these constructs with interference in a working memory task. Executive function was best described as two related subcomponent processes: shifting and updating goal-relevant representations and inhibition of proactive interference. These subcomponents were distinct from verbal and visual memory and speed. Individual differences in interference susceptibility and recollection were best predicted by shifting and updating and by resistance to proactive interference, and variability in familiarity was predicted by resistance to proactive interference and speed. ((c) 2006 APA, all rights reserved).
Simulation of interference between Earth stations and Earth-orbiting satellites
NASA Technical Reports Server (NTRS)
Bishop, D. F.
1994-01-01
It is often desirable to determine the potential for radio frequency interference between earth stations and orbiting spacecraft. This information can be used to select frequencies for radio systems to avoid interference or it can be used to determine if coordination between radio systems is necessary. A model is developed that will determine the statistics of interference between earth stations and elliptical orbiting spacecraft. The model uses orbital dynamics, detailed antenna patterns, and spectral characteristics to obtain accurate levels of interference at the victim receiver. The model is programmed into a computer simulation to obtain long-term statistics of interference. Two specific examples are shown to demonstrate the model. The first example is a simulation of interference from a fixed-satellite earth station to an orbiting scatterometer receiver. The second example is a simulation of interference from earth-exploration satellites to a deep-space earth station.
Adaptive digital beamforming for a CDMA mobile communications payload
NASA Technical Reports Server (NTRS)
Munoz-Garcia, Samuel G.; Ruiz, Javier Benedicto
1993-01-01
In recent years, Spread-Spectrum Code Division Multiple Access (CDMA) has become a very popular access scheme for mobile communications due to a variety of reasons: excellent performance in multipath environments, high scope for frequency reuse, graceful degradation near saturation, etc. In this way, a CDMA system can support simultaneous digital communication among a large community of relatively uncoordinated users sharing a given frequency band. Nevertheless, there are also important problems associated with the use of CDMA. First, in a conventional CDMA scheme, the signature sequences of asynchronous users are not orthogonal and, as the number of active users increases, the self-noise generated by the mutual interference between users considerably degrades the performance, particularly in the return link. Furthermore, when there is a large disparity in received powers - due to differences in slant range or atmospheric attenuation - the non-zero cross-correlation between the signals gives rise to the so-called near-far problem. This leads to an inefficient utilization of the satellite resources and, consequently, to a drastic reduction in capacity. Several techniques were proposed to overcome this problem, such as Synchronized CDMA - in which the signature sequences of the different users are quasi-orthogonal - and power control. At the expense of increased network complexity and user coordination, these techniques enable the system capacity to be restored by equitably sharing the satellite resources among the users. An alternative solution is presented based upon the use of time-reference adaptive digital beamforming on board the satellite. This technique enables a high number of independently steered beams to be generated from a single phased array antenna, which automatically track the desired user signal and null the unwanted interference source. In order to use a time-reference adaptive antenna in a communications system, the main challenge is to obtain a reference signal highly correlated with the desired user signal and uncorrelated with the interferences. CDMA lends itself very easily to the generation of such a reference signal, thanks to the a priori knowledge of the user's signature sequence. First, the integration of an adaptive antenna in an asynchronous CDMA system is analyzed. The adaptive antenna system can provide increased interference rejection - much higher than that afforded by the code alone - and, since CDMA is mainly interference limited, any reduction in interference converts directly and linearly into an increase in capacity. Analyses and computer simulations are presented that show how an asynchronous CDMA system incorporating adaptive beamforming can provide at least as much capacity as a synchronous system. More importantly, the proposed concept allows the near-far effect to be mitigated without requiring a tight coordination of the users in terms of transmitted power control or network synchronization. The system is extremely robust to the near-far effect because the signals reaching the satellite from directions other than that of the desired user - which are likely to have different power levels - are adaptively canceled by the antenna. Finally, a payload architecture is presented that illustrates the practical implementation of this concept. This digital payload architecture demonstrates that with the advent of high performance CMOS digital processing, the on-board implementation of complex DSP techniques - in particular Digital Beamforming - has become possible, being most attractive for Mobile Satellite Communications.
Adaptive digital beamforming for a CDMA mobile communications payload
NASA Astrophysics Data System (ADS)
Munoz-Garcia, Samuel G.; Ruiz, Javier Benedicto
In recent years, Spread-Spectrum Code Division Multiple Access (CDMA) has become a very popular access scheme for mobile communications due to a variety of reasons: excellent performance in multipath environments, high scope for frequency reuse, graceful degradation near saturation, etc. In this way, a CDMA system can support simultaneous digital communication among a large community of relatively uncoordinated users sharing a given frequency band. Nevertheless, there are also important problems associated with the use of CDMA. First, in a conventional CDMA scheme, the signature sequences of asynchronous users are not orthogonal and, as the number of active users increases, the self-noise generated by the mutual interference between users considerably degrades the performance, particularly in the return link. Furthermore, when there is a large disparity in received powers - due to differences in slant range or atmospheric attenuation - the non-zero cross-correlation between the signals gives rise to the so-called near-far problem. This leads to an inefficient utilization of the satellite resources and, consequently, to a drastic reduction in capacity. Several techniques were proposed to overcome this problem, such as Synchronized CDMA - in which the signature sequences of the different users are quasi-orthogonal - and power control. At the expense of increased network complexity and user coordination, these techniques enable the system capacity to be restored by equitably sharing the satellite resources among the users. An alternative solution is presented based upon the use of time-reference adaptive digital beamforming on board the satellite. This technique enables a high number of independently steered beams to be generated from a single phased array antenna, which automatically track the desired user signal and null the unwanted interference source. In order to use a time-reference adaptive antenna in a communications system, the main challenge is to obtain a reference signal highly correlated with the desired user signal and uncorrelated with the interferences. CDMA lends itself very easily to the generation of such a reference signal, thanks to the a priori knowledge of the user's signature sequence. First, the integration of an adaptive antenna in an asynchronous CDMA system is analyzed. The adaptive antenna system can provide increased interference rejection - much higher than that afforded by the code alone - and, since CDMA is mainly interference limited, any reduction in interference converts directly and linearly into an increase in capacity. Analyses and computer simulations are presented that show how an asynchronous CDMA system incorporating adaptive beamforming can provide at least as much capacity as a synchronous system. More importantly, the proposed concept allows the near-far effect to be mitigated without requiring a tight coordination of the users in terms of transmitted power control or network synchronization. The system is extremely robust to the near-far effect because the signals reaching the satellite from directions other than that of the desired user - which are likely to have different power levels - are adaptively canceled by the antenna. Finally, a payload architecture is presented that illustrates the practical implementation of this concept.
Disentangling the causal relationships between work-home interference and employee health.
van Hooff, Madelon L M; Geurts, Sabine A E; Taris, Toon W; Kompier, Michiel A J; Dikkers, Josje S E; Houtman, Irene L D; van den Heuvel, Floor M M
2005-02-01
The present study was designed to investigate the causal relationships between (time- and strain-based) work-home interference and employee health. The effort-recovery theory provided the theoretical basis for this study. Two-phase longitudinal data (with a 1-year time lag) were gathered from 730 Dutch police officers to test the following hypotheses with structural equation modeling: (i) work-home interference predicts health deterioration, (ii) health complaints precede increased levels of such interference, and (iii) both processes operate. The relationship between stable and changed levels of work-home interference across time and their relationships with the course of health were tested with a group-by-time analysis of variance. Four subgroups were created that differed in starting point and the development of work-home interference across time. The normal causal model, in which strain-based (but not time-based) work-home interference was longitudinally related to increased health complaints 1 year later, fit the data well and significantly better than the reversed causal model. Although the reciprocal model also provided a good fit, it was less parsimonious than the normal causal model. In addition, both an increment in (strain-based) work-home interference across time and a long-lasting experience of high (strain-based) work-home interference were associated with a deterioration in health. It was concluded that (strain-based) work-home interference acts as a precursor of health impairment and that different patterns of (strain-based) work-home interference across time are related to different health courses. Particularly long-term experience of (strain-based) work-home interference seems responsible for an accumulation of health complaints.
NASA Technical Reports Server (NTRS)
Crews, J. H., Jr.
1975-01-01
A fatigue analysis, based on finite-element calculations and fatigue tests, was conducted for an aluminum-alloy sheet specimen with a steel interference-fit bolt. The stress analysis of the region near the bolt hole showed that the beneficial effect of an interference-fit bolt can be interpreted as the combined result of two effects: (1) load transfer through the bolt and (2) the compressive interference stresses in the sheet. Results of the fatigue tests show that progressively higher interference levels produced longer fatigue lives. The tests also show that a high level of interference prevents fretting at the bolt-sheet interface and that interferences larger than this level produced little additional improvement in fatigue life.
Differential development of retroactive and proactive interference during post-learning wakefulness.
Brawn, Timothy P; Nusbaum, Howard C; Margoliash, Daniel
2018-07-01
Newly encoded, labile memories are prone to disruption during post-learning wakefulness. Here we examine the contributions of retroactive and proactive interference to daytime forgetting on an auditory classification task in a songbird. While both types of interference impair performance, they do not develop concurrently. The retroactive interference of task-B on task-A developed during the learning of task-B, whereas the proactive interference of task-A on task-B emerged during subsequent waking retention. These different time courses indicate an asymmetry in the emergence of retroactive and proactive interference and suggest a mechanistic framework for how different types of interference between new memories develop. © 2018 Brawn et al.; Published by Cold Spring Harbor Laboratory Press.
Word reading practice reduces Stroop interference in children.
Protopapas, Athanassios; Vlahou, Eleni L; Moirou, Despoina; Ziaka, Laoura
2014-05-01
Stroop interference is thought to index reading automaticity and is expected to increase with reading practice and to decrease with improved color naming. We investigated the effects of practice in word reading and color naming on interference in 92 adults and 109 children in Grades 4-5. For children, interference was reduced after reading practice with color words. In neither group was interference affected by practice in color naming of neutral stimuli. These findings are consistent with a direct negative relationship between reading ability and interference and challenge the automaticity account in favor of a blocking mechanism whereby interference is determined by the delay to inhibit the reading response rather than by the efficiency of color naming. Copyright © 2014 Elsevier B.V. All rights reserved.
47 CFR 78.106 - Interference to geostationary-satellites.
Code of Federal Regulations, 2014 CFR
2014-10-01
... 47 Telecommunication 4 2014-10-01 2014-10-01 false Interference to geostationary-satellites. 78... SERVICES CABLE TELEVISION RELAY SERVICE Technical Regulations § 78.106 Interference to geostationary... interference to geostationary-satellites. [68 FR 12776, Mar. 17, 2003] ...
47 CFR 78.106 - Interference to geostationary-satellites.
Code of Federal Regulations, 2011 CFR
2011-10-01
... 47 Telecommunication 4 2011-10-01 2011-10-01 false Interference to geostationary-satellites. 78... SERVICES CABLE TELEVISION RELAY SERVICE Technical Regulations § 78.106 Interference to geostationary... interference to geostationary-satellites. [68 FR 12776, Mar. 17, 2003] ...
47 CFR 78.106 - Interference to geostationary-satellites.
Code of Federal Regulations, 2010 CFR
2010-10-01
... 47 Telecommunication 4 2010-10-01 2010-10-01 false Interference to geostationary-satellites. 78... SERVICES CABLE TELEVISION RELAY SERVICE Technical Regulations § 78.106 Interference to geostationary... interference to geostationary-satellites. [68 FR 12776, Mar. 17, 2003] ...
47 CFR 78.106 - Interference to geostationary-satellites.
Code of Federal Regulations, 2013 CFR
2013-10-01
... 47 Telecommunication 4 2013-10-01 2013-10-01 false Interference to geostationary-satellites. 78... SERVICES CABLE TELEVISION RELAY SERVICE Technical Regulations § 78.106 Interference to geostationary... interference to geostationary-satellites. [68 FR 12776, Mar. 17, 2003] ...
47 CFR 78.106 - Interference to geostationary-satellites.
Code of Federal Regulations, 2012 CFR
2012-10-01
... 47 Telecommunication 4 2012-10-01 2012-10-01 false Interference to geostationary-satellites. 78... SERVICES CABLE TELEVISION RELAY SERVICE Technical Regulations § 78.106 Interference to geostationary... interference to geostationary-satellites. [68 FR 12776, Mar. 17, 2003] ...
Interference Impacts Working Memory in Mild Cognitive Impairment
Aurtenetxe, Sara; García-Pacios, Javier; del Río, David; López, María E.; Pineda-Pardo, José A.; Marcos, Alberto; Delgado Losada, Maria L.; López-Frutos, José M.; Maestú, Fernando
2016-01-01
Mild cognitive impairment (MCI) is considered a transitional stage between healthy aging and dementia, specifically Alzheimer's disease (AD). The most common cognitive impairment of MCI includes episodic memory loss and difficulties in working memory (WM). Interference can deplete WM, and an optimal WM performance requires an effective control of attentional resources between the memoranda and the incoming stimuli. Difficulties in handling interference lead to forgetting. However, the interplay between interference and WM in MCI is not well-understood and needs further investigation. The current study investigated the effect of interference during a WM task in 20 MCIs and 20 healthy elder volunteers. Participants performed a delayed match-to-sample paradigm which consisted in two interference conditions, distraction and interruption, and one control condition without any interference. Results evidenced a disproportionate impact of interference on the WM performance of MCIs, mainly in the presence of interruption. These findings demonstrate that interference, and more precisely interruption, is an important proxy for memory-related deficits in MCI. Thus, the current findings reveal novel evidence regarding the causes of WM forgetting in MCI patients, associated with difficulties in the mechanisms of attentional control. PMID:27790082
Ingram, Nicolette S; Diakoumakos, Jessica V; Sinclair, Erin R; Crowe, Simon F
2016-01-01
This study investigated proactive and retroactive interference effects between the Wechsler Memory Scale-Fourth Edition (WMS-IV) using the flexible approach, and the Wechsler Adult Intelligence Scale-Fourth Edition (WAIS-IV). One hundred and eighty nonclinical participants were assigned to a four (visual interference, verbal interference, visual and verbal interference, vs. no interference) by two (retroactive vs. proactive) between-subjects design. The administration order of the tests was counterbalanced (i.e., administration of the WAIS-IV prior to the WMS-IV, and the WAIS-IV administered during the delay interval of the WMS-IV). The WAIS-IV produced significant retroactive interference effects on the WMS-IV; however, no proactive interference effect was observed. The retroactive interference effect was dependent on material specificity. The results indicate that material presented within the delay of the WMS-IV can have a significant effect on subsequent delayed recall. Clinicians should carefully consider the effects associated with carry-over effects of these tests when using them in combination.
Schuch, Stefanie; Werheid, Katja; Koch, Iring
2012-01-01
The present study investigated whether the processing characteristics of categorizing emotional facial expressions are different from those of categorizing facial age and sex information. Given that emotions change rapidly, it was hypothesized that processing facial expressions involves a more flexible task set that causes less between-task interference than the task sets involved in processing age or sex of a face. Participants switched between three tasks: categorizing a face as looking happy or angry (emotion task), young or old (age task), and male or female (sex task). Interference between tasks was measured by global interference and response interference. Both measures revealed patterns of asymmetric interference. Global between-task interference was reduced when a task was mixed with the emotion task. Response interference, as measured by congruency effects, was larger for the emotion task than for the nonemotional tasks. The results support the idea that processing emotional facial expression constitutes a more flexible task set that causes less interference (i.e., task-set "inertia") than processing the age or sex of a face.
FastICA peel-off for ECG interference removal from surface EMG.
Chen, Maoqi; Zhang, Xu; Chen, Xiang; Zhu, Mingxing; Li, Guanglin; Zhou, Ping
2016-06-13
Multi-channel recording of surface electromyographyic (EMG) signals is very likely to be contaminated by electrocardiographic (ECG) interference, specifically when the surface electrode is placed on muscles close to the heart. A novel fast independent component analysis (FastICA) based peel-off method is presented to remove ECG interference contaminating multi-channel surface EMG signals. Although demonstrating spatial variability in waveform shape, the ECG interference in different channels shares the same firing instants. Utilizing the firing information estimated from FastICA, ECG interference can be separated from surface EMG by a "peel off" processing. The performance of the method was quantified with synthetic signals by combining a series of experimentally recorded "clean" surface EMG and "pure" ECG interference. It was demonstrated that the new method can remove ECG interference efficiently with little distortion to surface EMG amplitude and frequency. The proposed method was also validated using experimental surface EMG signals contaminated by ECG interference. The proposed FastICA peel-off method can be used as a new and practical solution to eliminating ECG interference from multichannel EMG recordings.
The Venus Emissivity Mapper - gaining a global perspective on the surface composition of Venus
NASA Astrophysics Data System (ADS)
Helbert, Joern; Dyar, Melinda; Widemann, Thomas; Marcq, Emmanuel; Maturilli, Alessandro; Mueller, Nils; Kappel, David; Ferrari, Sabrina; D'Amore, Mario; Tsang, Constantine; Arnold, Gabriele; Smrekar, Suzanne; VEM Team
2017-10-01
The permanent cloud cover of Venus prohibits observations of the surface with traditional imaging techniques over much of the EM spectral range, leading to the false notion that information about the composition of Venus’ surface could only be derived from lander missions. However, harsh environmental conditions on the surface cause landed missions to be sole site, highly complex, and riskier than orbiting missions.It is now known that 5 transparency windows occur in the Venus atmosphere, ranging from 0.86 µm to 1.18 µm. Recent advances in high temperature laboratory spectroscopy at the PSL at DLR these windows are highly diagnostic for surface mineralogy. Mapping of the southern hemisphere of Venus with VIRTIS on VEX in the 1.02 µm band was a proof-of-concept for an orbital remote sensing approach to surface composition and weathering studies[1-3]. The Venus Emissivity Mapper [4] proposed for the NASA’s Venus Origins Explorer (VOX) and the ESA EnVision proposal builds on these recent advances. It is the first flight instrument specially designed with a sole focus on mapping the surface of Venus using the narrow atmospheric windows around 1 µm. Operating in situ from Venus orbit, VEM will provide a global map of surface composition as well as redox state of the surface, providing a comprehensive picture of surface-atmosphere interaction and support for landing site selection. Continuous observation of the thermal emission of the Venus will provide tight constraints on the current day volcanic activity[5]. This is complemented by measurements of atmospheric water vapor abundance as well as cloud microphysics and dynamics. These data will allow for accurate correction of atmospheric interference on the surface measurements, which provide highly valuable science on their own. A mission combining VEM with a high-resolution radar mapper such as VOX or EnVision in a low circular orbit will provide key insights into the divergent evolution of Venus.1. Smrekar, S.E., et al., Science, 2010. 328(5978): p. 605-8.2. Helbert, J., et al., GRL, 2008. 35(11).3. Mueller, N., et al., JGR, 2008. 113.4. Helbert, J., et al. 2016. San Diego, CA: SPIE.5. Mueller, N.T., et al., JGR, 2017.
The Effect of Solar Proton Events on Ozone and Other Constituents
NASA Technical Reports Server (NTRS)
Jackman, Charles H.; McPeters, Richard D.; Bhartia, P. K. (Technical Monitor)
2000-01-01
Solar proton events (SPEs) can cause changes in constituents in the Earth's middle atmosphere. The highly energetic protons cause ionizations, excitations, dissociations, and dissociative ionizations of the background constituents. Complicated ion chemistry leads to HO(x) production and dissociation of N2 leads to NO(y) production. Both the HO(x) and NO(y) increases can result in changes to ozone in the stratosphere and mesosphere. The HO(x) increases lead to short-lived ozone decreases in the mesosphere and upper stratosphere due to the short lifetimes of the HO(x) constituents. The NO(y) increases lead to long-lived stratospheric ozone changes because of the long lifetime of NO(y) constituents in this region. The NO(y) induced ozone changes are generally decreases, however, the NO(y) constituents can interfere with chlorine and bromine radicals in the lowest part of the stratosphere and cause ozone increases. Temperature changes have been predicted to occur as a result of the larger SPEs. Eleven SPEs have caused measurable atmospheric variations since 1969. Neutral wind variations were measured shortly after the July 1982 and April 1984 SPEs. The recent July 2000 SPE caused NO(x) increases that lasted for two months past the event. The two periods of largest SPEs (August 1972 and October 1989) caused ozone decreases that lasted for several weeks past the events.
NASA Technical Reports Server (NTRS)
Jackman, Charles H.; Fleming, Eric L.; Vitt, Francis M.
1999-01-01
Two periods of extremely large solar proton events (SPEs) occurred in the past thirty years, which forced significant long-term polar stratospheric changes. The August 2-10, 1972 and October 19-27, 1989 SPEs happened in stratospheres that were quite different chemically. The stratospheric chlorine levels were relatively small in 1972 (approximately 1.2 ppbv) and were fairly substantial in 1989 at about (approximately 3 ppbv). Although these SPEs produced both HO(x) and NO(y) constituents in the mesosphere and stratosphere, only the NO(y) constituents had lifetimes long enough to affect ozone for several months to years past the events. Our recently improved two-dimensional chemistry and transport atmospheric model was used to compute the effects of these gigantic SPEs in a changing stratosphere. Significant upper stratospheric ozone depletions > 10% are computed to last for a few months past these SPEs. The long-lived SPE-produced NO(y) constituents were transported to lower levels during winter after these huge SPEs and caused impacts in the middle and lower stratosphere. During periods of high halogen loading these impacts resulted in interference with the chlorine and bromine loss cycles for ozone destruction. The chemical state of the atmosphere, including the stratospheric sulfate aerosol density, substantially affected the predicted stratospheric influence of these extremely large SPEs.
Jarmusch, Alan K; Musso, Ashleigh M; Shymanovich, Tatsiana; Jarmusch, Scott A; Weavil, Miranda J; Lovin, Mary E; Ehrmann, Brandie M; Saari, Susanna; Nichols, David E; Faeth, Stanley H; Cech, Nadja B
2016-01-05
Ergot alkaloids are mycotoxins with an array of biological effects. With this study, we investigated for the first time the application of atmospheric pressure photoionization (APPI) as an ionization method for LC-MS analysis of ergot alkaloids, and compared its performance to that of the more established technique of electrospray ionization (ESI). Samples of the grass Achnatherum robustum infected with the ergot producing Epichloë fungus were extracted using cold methanol and subjected to reserved-phase HPLC-ESI-MS and HPLC-APPI-MS analysis. The ergot alkaloids ergonovine and lysergic acid amide were detected in these samples, and quantified via external calibration. Validation parameters were recorded in accordance with ICH guidelines. A triple quadrupole MS operated in multiple reaction monitoring yielded the lowest detection limits. The performance of APPI and ESI methods was comparable. Both methods were subject to very little matrix interference, with percent recoveries ranging from 82% to 100%. As determined with HPLC-APPI-MS quantification, lysergic acid amide and ergonovine were extracted from an A. robustum sample infected with the Epichloë fungus at concentrations of 1.143±0.051 ppm and 0.2822±0.0071 ppm, respectively. There was no statistically significant difference between these concentrations and those determined using ESI for the same samples. Copyright © 2015 Elsevier B.V. All rights reserved.
Data processing techniques used with MST radars: A review
NASA Technical Reports Server (NTRS)
Rastogi, P. K.
1983-01-01
The data processing methods used in high power radar probing of the middle atmosphere are examined. The radar acts as a spatial filter on the small scale refractivity fluctuations in the medium. The characteristics of the received signals are related to the statistical properties of these fluctuations. A functional outline of the components of a radar system is given. Most computation intensive tasks are carried out by the processor. The processor computes a statistical function of the received signals, simultaneously for a large number of ranges. The slow fading of atmospheric signals is used to reduce the data input rate to the processor by coherent integration. The inherent range resolution of the radar experiments can be improved significant with the use of pseudonoise phase codes to modulate the transmitted pulses and a corresponding decoding operation on the received signals. Commutability of the decoding and coherent integration operations is used to obtain a significant reduction in computations. The limitations of the processors are outlined. At the next level of data reduction, the measured function is parameterized by a few spectral moments that can be related to physical processes in the medium. The problems encountered in estimating the spectral moments in the presence of strong ground clutter, external interference, and noise are discussed. The graphical and statistical analysis of the inferred parameters are outlined. The requirements for special purpose processors for MST radars are discussed.
Development of a multilayer interference simulation program for MSS systems
NASA Technical Reports Server (NTRS)
Izadian, Jamal S.
1993-01-01
This paper discusses the development of a multilayer interference analysis and simulation program which is used to evaluate interference between non-geostationary and geostationary satellites. In addition to evaluating interference, this program can be used in the development of sharing criteria and coordination among various Mobile Satellite Services (MSS) systems. A C++/Windows implementation of this program, called Globalstar Interference Simulation Program (GISP), has been developed.
Controlling quantum interference in phase space with amplitude.
Xue, Yinghong; Li, Tingyu; Kasai, Katsuyuki; Okada-Shudo, Yoshiko; Watanabe, Masayoshi; Zhang, Yun
2017-05-23
We experimentally show a quantum interference in phase space by interrogating photon number probabilities (n = 2, 3, and 4) of a displaced squeezed state, which is generated by an optical parametric amplifier and whose displacement is controlled by amplitude of injected coherent light. It is found that the probabilities exhibit oscillations of interference effect depending upon the amplitude of the controlling light field. This phenomenon is attributed to quantum interference in phase space and indicates the capability of controlling quantum interference using amplitude. This remarkably contrasts with the oscillations of interference effects being usually controlled by relative phase in classical optics.
Dulas, Michael R; Duarte, Audrey
2016-05-15
Behavioral evidence has shown age-related impairments in overcoming proactive interference in memory, but it is unclear what underlies this deficit. Imaging studies in the young suggest overcoming interference may require several executive control processes supported by the ventrolateral prefrontal cortex (VLPFC) and dorsolateral PFC (DLPFC). The present functional magnetic resonance imaging (fMRI) study investigated whether age-related changes in dissociable executive control processes underlie deficits in overcoming proactive interference in associative memory during retrieval. Participants were tasked with remembering which associate (face or scene) objects were paired with most recently during study, under conditions of high or low proactive interference. Behavioral results demonstrated that, as interference increased, memory performance decreased similarly across groups, with slight associative memory deficits in older adults. Imaging results demonstrated that, across groups, left mid-VLPFC showed increasing activity with increasing interference, though activity did not distinguish correct from incorrect associative memory responses, suggesting this region may not directly serve in successful resolution of proactive interference, per se. Under conditions of high interference, older adults showed reduced associative memory accuracy effects in the DLPFC and anterior PFC. These results suggest that age-related PFC dysfunction may not be ubiquitous. Executive processes supported by ventral regions that detect mnemonic interference may be less affected than processes supported by dorsal and anterior regions that directly resolve interference. Copyright © 2016 Elsevier Inc. All rights reserved.
Facilitation and interference in naming: A consequence of the same learning process?
Hughes, Julie W; Schnur, Tatiana T
2017-08-01
Our success with naming depends on what we have named previously, a phenomenon thought to reflect learning processes. Repeatedly producing the same name facilitates language production (i.e., repetition priming), whereas producing semantically related names hinders subsequent performance (i.e., semantic interference). Semantic interference is found whether naming categorically related items once (continuous naming) or multiple times (blocked cyclic naming). A computational model suggests that the same learning mechanism responsible for facilitation in repetition creates semantic interference in categorical naming (Oppenheim, Dell, & Schwartz, 2010). Accordingly, we tested the predictions that variability in semantic interference is correlated across categorical naming tasks and is caused by learning, as measured by two repetition priming tasks (picture-picture repetition priming, Exp. 1; definition-picture repetition priming, Exp. 2, e.g., Wheeldon & Monsell, 1992). In Experiment 1 (77 subjects) semantic interference and repetition priming effects were robust, but the results revealed no relationship between semantic interference effects across contexts. Critically, learning (picture-picture repetition priming) did not predict semantic interference effects in either task. We replicated these results in Experiment 2 (81 subjects), finding no relationship between semantic interference effects across tasks or between semantic interference effects and learning (definition-picture repetition priming). We conclude that the changes underlying facilitatory and interfering effects inherent to lexical access are the result of distinct learning processes where multiple mechanisms contribute to semantic interference in naming. Copyright © 2017 Elsevier B.V. All rights reserved.
NASA Technical Reports Server (NTRS)
2005-01-01
[figure removed for brevity, see original site] Dust Particles Click on the image for Quicktime movie from 7/15-7/24 A continent-sized cloud of hot air and dust originating from the Sahara Desert crossed the Atlantic Ocean and headed towards Florida and the Caribbean. A Saharan Air Layer, or SAL, forms when dry air and dust rise from Africa's west coast and ride the trade winds above the Atlantic Ocean. These dust clouds are not uncommon, especially during the months of July and August. They start when weather patterns called tropical waves pick up dust from the desert in North Africa, carry it a couple of miles into the atmosphere and drift westward. In a sequence of images created by data acquired by the Earth-orbiting Atmospheric Infrared Sounder ranging from July 15 through July 24, we see the distribution of the cloud in the atmosphere as it swirls off of Africa and heads across the ocean to the west. Using the unique silicate spectral signatures of dust in the thermal infrared, AIRS can detect the presence of dust in the atmosphere day or night. This detection works best if there are no clouds present on top of the dust; when clouds are present, they can interfere with the signal, making it much harder to detect dust as in the case of July 24, 2005. In the Quicktime movie, the scale at the bottom of the images shows +1 for dust definitely detected, and ranges down to -1 for no dust detected. The plots are averaged over a number of AIRS observations falling within grid boxes, and so it is possible to obtain fractional numbers. [figure removed for brevity, see original site] Total Water Vapor in the Atmosphere Around the Dust Cloud Click on the image for Quicktime movie The dust cloud is contained within a dry adiabatic layer which originates over the Sahara Desert. This Saharan Air Layer (SAL) advances Westward over the Atlantic Ocean, overriding the cool, moist air nearer the surface. This burst of very dry air is visible in the AIRS retrieved total water vapor product as a region of depressed water vapor (brown in the images) migrating slowly Westward toward the Caribbean. The SAL phenomenon inhibits the formation of tropical cyclones and thus has given the West Indies and the East Coast of the US a respite from hurricanes. The Atmospheric Infrared Sounder Experiment, with its visible, infrared, and microwave detectors, provides a three-dimensional look at Earth's weather. Working in tandem, the three instruments can make simultaneous observations all the way down to the Earth's surface, even in the presence of heavy clouds. With more than 2,000 channels sensing different regions of the atmosphere, the system creates a global, 3-D map of atmospheric temperature and humidity and provides information on clouds, greenhouse gases, and many other atmospheric phenomena. The AIRS Infrared Sounder Experiment flies onboard NASA's Aqua spacecraft and is managed by NASA's Jet Propulsion Laboratory, Pasadena, Calif., under contract to NASA. JPL is a division of the California Institute of Technology in Pasadena.Application and research of artificial water mist on photoelectric interference
NASA Astrophysics Data System (ADS)
He, Yuejun; Ren, Baolin
2018-04-01
Water mist is a new type of photoelectric interfering material. It can exert a strong interference and shielding effect on infrared light, laser and radar wave through scattering, reflection, refraction and absorption. Based on this, this paper illustrates the application of an artificial high pressure water mist technology in infrared interference system. First, the operating principle of the infrared interference system is introduced. Next, the design principle of self-excited rotary vortex nozzle, the key part of the system, is elaborated. Then, the calculation of the main control parameters of the system is clarified. In the end, the paper verifies interference and shielding effect of the system by experiment. Experiment shows that the interference system can significantly reduce infrared signature of the target, featuring excellent infrared interference performance and high practical value.
Interference Mitigation Effects on Synthetic Aperture Radar Coherent Data Products
DOE Office of Scientific and Technical Information (OSTI.GOV)
Musgrove, Cameron
For synthetic aperture radars radio frequency interference from sources external to the radar system and techniques to mitigate the interference can degrade the quality of the image products. Usually the radar system designer will try to balance the amount of mitigation for an acceptable amount of interference to optimize the image quality. This dissertation examines the effect of interference mitigation upon coherent data products of fine resolution, high frequency synthetic aperture radars using stretch processing. Novel interference mitigation techniques are introduced that operate on single or multiple apertures of data that increase average coherence compared to existing techniques. New metricsmore » are applied to evaluate multiple mitigation techniques for image quality and average coherence. The underlying mechanism for interference mitigation techniques that affect coherence is revealed.« less
Teasing apart retrieval and encoding interference in the processing of anaphors
Jäger, Lena A.; Benz, Lena; Roeser, Jens; Dillon, Brian W.; Vasishth, Shravan
2015-01-01
Two classes of account have been proposed to explain the memory processes subserving the processing of reflexive-antecedent dependencies. Structure-based accounts assume that the retrieval of the antecedent is guided by syntactic tree-configurational information without considering other kinds of information such as gender marking in the case of English reflexives. By contrast, unconstrained cue-based retrieval assumes that all available information is used for retrieving the antecedent. Similarity-based interference effects from structurally illicit distractors which match a non-structural retrieval cue have been interpreted as evidence favoring the unconstrained cue-based retrieval account since cue-based retrieval interference from structurally illicit distractors is incompatible with the structure-based account. However, it has been argued that the observed effects do not necessarily reflect interference occurring at the moment of retrieval but might equally well be accounted for by interference occurring already at the stage of encoding or maintaining the antecedent in memory, in which case they cannot be taken as evidence against the structure-based account. We present three experiments (self-paced reading and eye-tracking) on German reflexives and Swedish reflexive and pronominal possessives in which we pit the predictions of encoding interference and cue-based retrieval interference against each other. We could not find any indication that encoding interference affects the processing ease of the reflexive-antecedent dependency formation. Thus, there is no evidence that encoding interference might be the explanation for the interference effects observed in previous work. We therefore conclude that invoking encoding interference may not be a plausible way to reconcile interference effects with a structure-based account of reflexive processing. PMID:26106337
Walton, David M; Beattie, Tyler; Putos, Joseph; MacDermid, Joy C
2016-06-01
The Brief Pain Inventory is composed of two quantifiable scales: pain severity and pain interference. The reported factor structure of the interference subscale is not consistent in the extant literature, with no clear choice between a single- or two-factor structure. Here, we report on the results of Rasch-based analysis of the interference subscale using a large population-based ambulatory patient database (the Quebec Pain Registry). Observational cohort. A total of 1,000 responses were randomly drawn from a total database of 5,654 for this analysis. Both the original 7-item and an expanded 10-item version (Tyler 2002) of the interference subscale were evaluated. Rasch analysis revealed significant misfit of both versions of the scale, with the original 7-item version outperforming the expanded 10-item version. Analysis of dimensionality revealed that both versions showed improved model fit when considered two subscales (affective and physical interference) with the item on sleep interference removed or considered separately. Additionally, significant uniform differential item functioning was identified for 6 of the 7 original items when the sample was stratified by age above or below 55 years. The interference subscale achieved adequate model fit when considered as two separate subscales with age as a mediator of response, while interpreting the sleep interference item separately. A transformation matrix revealed that in all cases, ordinal-level change at the extreme ends of the scale appears to be more meaningful than does a similar change at the midpoints. The Interference subscale of the BPI should be interpreted as two separate subscales (Affective Interference, Physical Interference) with the sleep item removed or interpreted separately for optimal fit to the Rasch model. Implications for research and clinical use are discussed. Copyright © 2016 Elsevier Inc. All rights reserved.
Apparent hyperthyroidism caused by biotin-like interference from IgM anti-streptavidin antibodies.
Lam, Leo; Bagg, Warwick; Smith, Geoff; Chiu, Weldon; Middleditch, Martin James; Lim, Julie Ching-Hsia; Kyle, Campbell Vance
2018-05-29
Exclusion of analytical interference is important when there is discrepancy between clinical and laboratory findings. However, interferences on immunoassays are often mistaken as isolated laboratory artefacts. We characterized and report the mechanism of a rare cause of interference in two patients that caused erroneous thyroid function tests, and also affects many other biotin dependent immunoassays. Patient 1 was a 77 y female with worsening fatigue while taking carbimazole over several years. Her thyroid function tests however, were not suggestive of hypothyroidism. Patient 2 was a 25 y female also prescribed carbimazole for apparent primary hyperthyroidism. Despite an elevated FT4, the lowest TSH on record was 0.17mIU/L. In both cases, thyroid function tests performed by an alternative method were markedly different. Further characterization of both patients' serum demonstrated analytical interference on many immunoassays using the biotin-streptavidin interaction. Sandwich assays (e.g. TSH, FSH, TNT, beta-HCG) were falsely low, while competitive assays (e.g. FT4, FT3, TBII) were falsely high. Pre-incubation of serum with streptavidin microparticles removed the analytical interference, initially suggesting the cause of interference was biotin, however, neither patient had been taking biotin. Instead, a ~100kDa IgM immunoglobulin with high affinity to streptavidin was isolated from each patient's serum. The findings confirm IgM anti-streptavidin antibodies as the cause of analytical interference. We describe two patients with apparent hyperthyroidism as a result of analytical interference caused by IgM anti-streptavidin antibodies. Analytical interference identified on one immunoassay should raise the possibility of other affected results. Characterization of interference may help to identify other potentially affected immunoassays. In the case of anti-streptavidin antibodies, the pattern of interference mimics that due to biotin ingestion; however, the degree of interference varies between individual assays and between patients.
47 CFR 80.217 - Suppression of interference aboard ships.
Code of Federal Regulations, 2012 CFR
2012-10-01
... 47 Telecommunication 5 2012-10-01 2012-10-01 false Suppression of interference aboard ships. 80.217 Section 80.217 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) SAFETY AND SPECIAL... interference aboard ships. (a) A voluntarily equipped ship station receiver must not cause harmful interference...
47 CFR 80.217 - Suppression of interference aboard ships.
Code of Federal Regulations, 2014 CFR
2014-10-01
... 47 Telecommunication 5 2014-10-01 2014-10-01 false Suppression of interference aboard ships. 80.217 Section 80.217 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) SAFETY AND SPECIAL... interference aboard ships. (a) A voluntarily equipped ship station receiver must not cause harmful interference...
47 CFR 80.217 - Suppression of interference aboard ships.
Code of Federal Regulations, 2013 CFR
2013-10-01
... 47 Telecommunication 5 2013-10-01 2013-10-01 false Suppression of interference aboard ships. 80.217 Section 80.217 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) SAFETY AND SPECIAL... interference aboard ships. (a) A voluntarily equipped ship station receiver must not cause harmful interference...
37 CFR 41.202 - Suggesting an interference.
Code of Federal Regulations, 2012 CFR
2012-07-01
... 37 Patents, Trademarks, and Copyrights 1 2012-07-01 2012-07-01 false Suggesting an interference. 41.202 Section 41.202 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND TRADEMARK OFFICE, DEPARTMENT OF COMMERCE PRACTICE BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES Patent Interferences...
37 CFR 41.202 - Suggesting an interference.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 37 Patents, Trademarks, and Copyrights 1 2011-07-01 2011-07-01 false Suggesting an interference. 41.202 Section 41.202 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND TRADEMARK OFFICE, DEPARTMENT OF COMMERCE PRACTICE BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES Patent Interferences...
49 CFR 193.2633 - Interference currents.
Code of Federal Regulations, 2012 CFR
2012-10-01
...: FEDERAL SAFETY STANDARDS Maintenance § 193.2633 Interference currents. (a) Each component that is subject to electrical current interference must be protected by a continuing program to minimize the... 49 Transportation 3 2012-10-01 2012-10-01 false Interference currents. 193.2633 Section 193.2633...
49 CFR 193.2633 - Interference currents.
Code of Federal Regulations, 2014 CFR
2014-10-01
...: FEDERAL SAFETY STANDARDS Maintenance § 193.2633 Interference currents. (a) Each component that is subject to electrical current interference must be protected by a continuing program to minimize the... 49 Transportation 3 2014-10-01 2014-10-01 false Interference currents. 193.2633 Section 193.2633...
49 CFR 193.2633 - Interference currents.
Code of Federal Regulations, 2013 CFR
2013-10-01
...: FEDERAL SAFETY STANDARDS Maintenance § 193.2633 Interference currents. (a) Each component that is subject to electrical current interference must be protected by a continuing program to minimize the... 49 Transportation 3 2013-10-01 2013-10-01 false Interference currents. 193.2633 Section 193.2633...
49 CFR 193.2633 - Interference currents.
Code of Federal Regulations, 2011 CFR
2011-10-01
...: FEDERAL SAFETY STANDARDS Maintenance § 193.2633 Interference currents. (a) Each component that is subject to electrical current interference must be protected by a continuing program to minimize the... 49 Transportation 3 2011-10-01 2011-10-01 false Interference currents. 193.2633 Section 193.2633...
Intraindividual Coupling of Daily Stressors and Cognitive Interference in Old Age
Mogle, Jacqueline; Sliwinski, Martin J.
2011-01-01
Objectives. The current study examined emotional and cognitive reactions to daily stress. We examined the psychometric properties of a short cognitive interference measure and how cognitive interference was associated with measures of daily stress and negative affect (NA) between persons and within persons over time. Methods. A sample of 87 older adults (Mage = 83, range = 70–97, 28% male) completed measures of daily stress, cognitive interference, and NA on 6 days within a 14-day period. Results. The measure yielded a single-factor solution with good reliability both between and within persons. At the between-person level, NA accounted for the effects of daily stress on individual differences in cognitive interference. At the within-person level, NA and daily stress were unique predictors of cognitive interference. Furthermore, the within-person effect of daily stress on cognitive interference decreased significantly with age. Discussion. These results support theoretical work regarding associations among stress, NA, and cognitive interference, both across persons and within persons over time. PMID:21743045
How to Be Proactive About Interference: Lessons From Animal Memory
Wright, Anthony A.; Katz, Jeffrey S.; Ma, Wei Ji
2015-01-01
Processes of proactive interference were explored using the pigeon as a model system of memory. This study shows that proactive interference extends back in time at least 16 trials (and as many minutes), revealing a continuum of interference and providing a framework for studying memory. Pigeons were tested in a delayed same/different task containing trial-unique pictures. On interference trials, sample pictures from previous trials reappeared as test pictures on different trials. Proactive-interference functions showed greatest interference from the most recent trial and with the longer of two delays (10 s vs. 1 s). These interference functions are accounted for by a time-estimation model based on signal detection theory. The model predicts that accuracy at test is determined solely by the ratio of the elapsed time since the offset of the current-trial sample to the elapsed time since the offset of the interfering sample. Implications for comparing memory of different species and different types of memory (e.g., familiarity vs. recollection) are discussed. PMID:22491142
How to be proactive about interference: lessons from animal memory.
Wright, Anthony A; Katz, Jeffrey S; Ma, Wei Ji
2012-05-01
Processes of proactive interference were explored using the pigeon as a model system of memory. This study shows that proactive interference extends back in time at least 16 trials (and as many minutes), revealing a continuum of interference and providing a framework for studying memory. Pigeons were tested in a delayed same/different task containing trial-unique pictures. On interference trials, sample pictures from previous trials reappeared as test pictures on different trials. Proactive-interference functions showed greatest interference from the most recent trial and with the longer of two delays (10 s vs. 1 s). These interference functions are accounted for by a time-estimation model based on signal detection theory. The model predicts that accuracy at test is determined solely by the ratio of the elapsed time since the offset of the current-trial sample to the elapsed time since the offset of the interfering sample. Implications for comparing memory of different species and different types of memory (e.g., familiarity vs. recollection) are discussed.
Mansfield, Karen L; van der Molen, Maurits W; Falkenstein, Michael; van Boxtel, Geert J M
2013-08-01
Behavioral and brain potential measures were employed to compare interference in Eriksen and Simon tasks. Assuming a dual-process model of interference elicited in speeded response tasks, we hypothesized that only lateralized stimuli in the Simon task induce fast S-R priming via direct unconditional processes, while Eriksen interference effects are induced later via indirect conditional processes. Delays to responses for incongruent trials were indeed larger in the Eriksen than in the Simon task. Only lateralized stimuli in the Simon task elicited early S-R priming, maximal at parietal areas. Incongruent flankers in the Eriksen task elicited interference later, visible as a lateralized N2. Eriksen interference also elicited an additional component (N350), which accounted for the larger behavioral interference effects in the Eriksen task. The findings suggest that interference and its resolution involve different processes for Simon and Eriksen tasks. Copyright © 2013 Elsevier Inc. All rights reserved.
Electromagnetic interference with pacemakers caused by portable media players.
Thaker, Jay P; Patel, Mehul B; Jongnarangsin, Krit; Liepa, Valdis V; Thakur, Ranjan K
2008-04-01
Electromagnetic fields generated by electrical devices may cause interference with permanent pacemakers. Media players are becoming a common mode of portable entertainment. The most common media players used worldwide are iPods. These devices are often carried in a shirt chest pocket, which may place the devices close to an implanted pacemaker. The purpose of this study was to determine if iPods cause interference with pacemakers. In this prospective, single-blinded study, 100 patients who had cardiac pacemakers were tested with four types of iPods to assess for interference. Patients were monitored by a single-channel ECG monitor as well as the respective pacemaker programmer via the telemetry wand. iPods were tested by placing them 2 inches anterior to the pacemaker and wand for up to 10 seconds. To simulate actual use, standard-issue headphones were plugged into the iPods. To maintain consistency, the volume was turned up maximally, and the equalizer was turned off. A subset of 25 patients underwent testing on 2 separate days to assess for reproducibility of interference. Pacemaker interference was categorized as type I or type II telemetry interference. Type I interference was associated with atrial and/or ventricular high rates on rate histograms. Type II interference did not affect pacemaker rate counters. Electromagnetic emissions from the four iPods also were evaluated in a Faraday cage to determine the mechanism of the observed interference. One hundred patients (63 men and 37 women; mean age 77.1 +/- 7.6 years) with 11 single-chamber pacemakers and 89 dual-chamber pacemakers underwent 800 tests. The incidence of any type of interference was 51% of patients and 20% of tests. Type I interference was seen in 19% of patients and type II in 32% of patients. Reproducibility testing confirmed that interference occurred regardless of pacing configuration (unipolar or bipolar), pacing mode (AAI, VVI, or DDD), and from one day to the next. Electromagnetic emissions testing from the iPods demonstrated maximum emissions in the pacemaker carrier frequency range when the iPod was turned "on" with the headphones attached. iPods placed within 2 inches of implanted pacemakers monitored via the telemetry wand can cause interference with pacemakers.
Ortega-Castro, Nerea; Vadillo, Miguel A
2013-03-01
Some researchers have attempted to determine whether situations in which a single cue is paired with several outcomes (A-B, A-C interference or interference between outcomes) involve the same learning and retrieval mechanisms as situations in which several cues are paired with a single outcome (A-B, C-B interference or interference between cues). Interestingly, current research on a related effect, which is known as retrieval-induced forgetting, can illuminate this debate. Most retrieval-induced forgetting experiments are based on an experimental design that closely resembles the A-B, A-C interference paradigm. In the present experiment, we found that a similar effect may be observed when items are rearranged such that the general structure of the task more closely resembles the A-B, C-B interference paradigm. This result suggests that, as claimed by other researchers in the area of contingency learning, the two types of interference, namely A-B, A-C and A-B, C-B interference, may share some basic mechanisms. Moreover, the type of inhibitory processes assumed to underlie retrieval-induced forgetting may also play a role in these phenomena. Copyright © 2012 Elsevier B.V. All rights reserved.
Resolving semantic and proactive interference in memory over the short-term.
Atkins, Alexandra S; Berman, Marc G; Reuter-Lorenz, Patricia A; Lewis, Richard L; Jonides, John
2011-07-01
Interference is a major source of short-term errors of memory. The present investigation explores the relationship between two important forms of interference: proactive interference (PI), induced by the need to reject recently studied items no longer relevant to task performance, and semantic interference (SI), induced by the need to reject lures sharing a meaningful relationship with current memoranda. We explore the possibility that shared cognitive control processes are recruited to resolve both forms of interference. In Experiment 1, we find that the requirement to engage in articulatory suppression during the retention interval of tasks that induce either PI or SI increases both forms of interference similarly and selectively. In Experiment 2, we develop a task to examine PI and SI within the same experimental context. The results show interactive effects between factors that lead to the two forms of interference. Taken together, these findings support contextual-cuing models of short-term remembering (Nairne, Annual Review of Psychology, 53, 53-81 2002), where the context in which retrieval occurs can influence susceptibility to interference. Lastly, we discuss several theoretical hypotheses concerning the cognitive control processes that are recruited to resolve SI and PI in short-term remembering.
Resolving semantic and proactive interference in memory over the short-term
Reuter-Lorenz, Patricia A.; Lewis, Richard L.; Jonides, John
2011-01-01
Interference is a major source of short-term errors of memory. The present investigation explores the relationship between two important forms of interference: proactive interference (PI), induced by the need to reject recently studied items no longer relevant to task performance, and semantic interference (SI), induced by the need to reject lures sharing a meaningful relationship with current memoranda. We explore the possibility that shared cognitive control processes are recruited to resolve both forms of interference. In Experiment 1, we find that the requirement to engage in articulatory suppression during the retention interval of tasks that induce either PI or SI increases both forms of interference similarly and selectively. In Experiment 2, we develop a task to examine PI and SI within the same experimental context. The results show interactive effects between factors that lead to the two forms of interference. Taken together, these findings support contextual-cuing models of short-term remembering (Nairne, Annual Review of Psychology, 53, 53–81 2002), where the context in which retrieval occurs can influence susceptibility to interference. Lastly, we discuss several theoretical hypotheses concerning the cognitive control processes that are recruited to resolve SI and PI in short-term remembering. PMID:21327614
Berry, Anne S; Zanto, Theodore P; Rutman, Aaron M; Clapp, Wesley C; Gazzaley, Adam
2009-09-01
Working memory (WM) performance is impaired by the presence of external interference. Accordingly, more efficient processing of intervening stimuli with practice may lead to enhanced WM performance. To explore the role of practice on the impact that interference has on WM performance, we studied young adults with electroencephalographic (EEG) recordings as they performed three motion-direction, delayed-recognition tasks. One task was presented without interference, whereas two tasks introduced different types of interference during the interval of memory maintenance: distractors and interruptors. Distractors were to be ignored, whereas interruptors demanded attention based on task instructions for a perceptual discrimination. We show that WM performance was disrupted by both types of interference, but interference-induced disruption abated across a single experimental session through rapid learning. WM accuracy and response time improved in a manner that was correlated with changes in early neural measures of interference processing in visual cortex (i.e., P1 suppression and N1 enhancement). These results suggest practice-related changes in processing interference exert a positive influence on WM performance, highlighting the importance of filtering irrelevant information and the dynamic interactions that exist between neural processes of perception, attention, and WM during learning.
Piai, Vitória; Roelofs, Ardi; Roete, Ingeborg
2015-01-01
Previous dual-task studies examining the locus of semantic interference of distractor words in picture naming have obtained diverging results. In these studies, participants manually responded to tones and named pictures while ignoring distractor words (picture-word interference, PWI) with varying stimulus onset asynchrony (SOA) between tone and PWI stimulus. Whereas some studies observed no semantic interference at short SOAs, other studies observed effects of similar magnitude at short and long SOAs. The absence of semantic interference in some studies may perhaps be due to better reading skill of participants in these than in the other studies. According to such a reading-ability account, participants' reading skill should be predictive of the magnitude of their interference effect at short SOAs. To test this account, we conducted a dual-task study with tone discrimination and PWI tasks and measured participants' reading ability. The semantic interference effect was of similar magnitude at both short and long SOAs. Participants' reading ability was predictive of their naming speed but not of their semantic interference effect, contrary to the reading ability account. We conclude that the magnitude of semantic interference in picture naming during dual-task performance does not depend on reading skill.
Lateralization of high-frequency transposed stimuli under conditions of binaural interference
NASA Astrophysics Data System (ADS)
Bernstein, Leslie R.; Trahiotis, Constantine
2005-04-01
The purpose of this study was to determine whether binaural interference would occur if ITD-based extents of laterality were measured using high-frequency transposed stimuli as targets. The results of an earlier study [L. R. Bernstein and C. Trahiotis, J. Acoust. Soc. Am. 116, 3062-3069 (2004)], which focused on threshold-ITDs rather than extents of laterality, suggested that high-frequency transposed stimuli might be immune to binaural interference effects resulting from the addition of a spectrally-remote, low-frequency interferer. In contrast to the earlier findings, the data from this study indicate that high-frequency transposed targets can, indeed, be susceptible to binaural interference. High-frequency transposed targets, even when presented along with an interferer, yielded greater extents of ITD-based laterality than did Gaussian noise targets presented in isolation. That is, the enhanced potency of ITDs conveyed by transposed stimuli persisted even in the presence of a low-frequency interferer. Predictions made using an extension of the model of Heller and Trahiotis [L. M. Heller and C. Trahiotis, J. Acoust. Soc. Am. 99, 3632-3637 (1996)] accounted well for binaural interference obtained with conventional Gaussian noise targets but generally over-predicted the amounts of interference found with the transposed targets.
Minimum Interference Planar Geometric Topology in Wireless Sensor Networks
NASA Astrophysics Data System (ADS)
Nguyen, Trac N.; Huynh, Dung T.
The approach of using topology control to reduce interference in wireless sensor networks has attracted attention of several researchers. There are at least two definitions of interference in the literature. In a wireless sensor network the interference at a node may be caused by an edge that is transmitting data [15], or it occurs because the node itself is within the transmission range of another [3], [1], [6]. In this paper we show that the problem of assigning power to nodes in the plane to yield a planar geometric graph whose nodes have bounded interference is NP-complete under both interference definitions. Our results provide a rigorous proof for a theorem in [15] whose proof is unconvincing. They also address one of the open issues raised in [6] where Halldórsson and Tokuyama were concerned with the receiver model of node interference, and derived an O(sqrt {Δ}) upper bound for the maximum node interference of a wireless ad hoc network in the plane (Δ is the maximum interference of the so-called uniform radius network). The question as to whether this problem is NP-complete in the 2-dimensional case was left open.
Sleep can reduce proactive interference.
Abel, Magdalena; Bäuml, Karl-Heinz T
2014-01-01
Sleep has repeatedly been connected to processes of memory consolidation. While extensive research indeed documents beneficial effects of sleep on memory, little is yet known about the role of sleep for interference effects in episodic memory. Although two prior studies reported sleep to reduce retroactive interference, no sleep effect has previously been found for proactive interference. Here we applied a study format differing from that employed by the prior studies to induce a high degree of proactive interference, and asked participants to encode a single list or two interfering lists of paired associates via pure study cycles. Testing occurred after 12 hours of diurnal wakefulness or nocturnal sleep. Consistent with the prior work, we found sleep in comparison to wake did not affect memory for the single list, but reduced retroactive interference. In addition we found sleep reduced proactive interference, and reduced retroactive and proactive interference to the same extent. The finding is consistent with the view that arising benefits of sleep are caused by the reactivation of memory contents during sleep, which has been suggested to strengthen and stabilise memories. Such stabilisation may make memories less susceptible to competition from interfering memories at test and thus reduce interference effects.
Link Scheduling Algorithm with Interference Prediction for Multiple Mobile WBANs
Le, Thien T. T.
2017-01-01
As wireless body area networks (WBANs) become a key element in electronic healthcare (e-healthcare) systems, the coexistence of multiple mobile WBANs is becoming an issue. The network performance is negatively affected by the unpredictable movement of the human body. In such an environment, inter-WBAN interference can be caused by the overlapping transmission range of nearby WBANs. We propose a link scheduling algorithm with interference prediction (LSIP) for multiple mobile WBANs, which allows multiple mobile WBANs to transmit at the same time without causing inter-WBAN interference. In the LSIP, a superframe includes the contention access phase using carrier sense multiple access with collision avoidance (CSMA/CA) and the scheduled phase using time division multiple access (TDMA) for non-interfering nodes and interfering nodes, respectively. For interference prediction, we define a parameter called interference duration as the duration during which disparate WBANs interfere with each other. The Bayesian model is used to estimate and classify the interference using a signal to interference plus noise ratio (SINR) and the number of neighboring WBANs. The simulation results show that the proposed LSIP algorithm improves the packet delivery ratio and throughput significantly with acceptable delay. PMID:28956827
36 CFR 331.16 - Interference with government employees.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 36 Parks, Forests, and Public Property 3 2011-07-01 2011-07-01 false Interference with government... WILDLIFE CONSERVATION AREA, KENTUCKY AND INDIANA § 331.16 Interference with government employees. Interference with any Government employee in the conduct of his or her official duties pertaining to the...
36 CFR 331.16 - Interference with government employees.
Code of Federal Regulations, 2014 CFR
2014-07-01
... 36 Parks, Forests, and Public Property 3 2014-07-01 2014-07-01 false Interference with government... WILDLIFE CONSERVATION AREA, KENTUCKY AND INDIANA § 331.16 Interference with government employees. Interference with any Government employee in the conduct of his or her official duties pertaining to the...
47 CFR 76.613 - Interference from a multichannel video programming distributor (MVPD).
Code of Federal Regulations, 2013 CFR
2013-10-01
... 47 Telecommunication 4 2013-10-01 2013-10-01 false Interference from a multichannel video... (CONTINUED) BROADCAST RADIO SERVICES MULTICHANNEL VIDEO AND CABLE TELEVISION SERVICE Technical Standards § 76.613 Interference from a multichannel video programming distributor (MVPD). (a) Harmful interference is...
47 CFR 76.613 - Interference from a multichannel video programming distributor (MVPD).
Code of Federal Regulations, 2014 CFR
2014-10-01
... 47 Telecommunication 4 2014-10-01 2014-10-01 false Interference from a multichannel video... (CONTINUED) BROADCAST RADIO SERVICES MULTICHANNEL VIDEO AND CABLE TELEVISION SERVICE Technical Standards § 76.613 Interference from a multichannel video programming distributor (MVPD). (a) Harmful interference is...
47 CFR 76.613 - Interference from a multichannel video programming distributor (MVPD).
Code of Federal Regulations, 2012 CFR
2012-10-01
... 47 Telecommunication 4 2012-10-01 2012-10-01 false Interference from a multichannel video... (CONTINUED) BROADCAST RADIO SERVICES MULTICHANNEL VIDEO AND CABLE TELEVISION SERVICE Technical Standards § 76.613 Interference from a multichannel video programming distributor (MVPD). (a) Harmful interference is...
47 CFR 76.613 - Interference from a multichannel video programming distributor (MVPD).
Code of Federal Regulations, 2010 CFR
2010-10-01
... 47 Telecommunication 4 2010-10-01 2010-10-01 false Interference from a multichannel video... (CONTINUED) BROADCAST RADIO SERVICES MULTICHANNEL VIDEO AND CABLE TELEVISION SERVICE Technical Standards § 76.613 Interference from a multichannel video programming distributor (MVPD). (a) Harmful interference is...
47 CFR 76.613 - Interference from a multichannel video programming distributor (MVPD).
Code of Federal Regulations, 2011 CFR
2011-10-01
... 47 Telecommunication 4 2011-10-01 2011-10-01 false Interference from a multichannel video... (CONTINUED) BROADCAST RADIO SERVICES MULTICHANNEL VIDEO AND CABLE TELEVISION SERVICE Technical Standards § 76.613 Interference from a multichannel video programming distributor (MVPD). (a) Harmful interference is...
Dissociating Interference-Control Processes between Memory and Response
ERIC Educational Resources Information Center
Bissett, Patrick G.; Nee, Derek Evan; Jonides, John
2009-01-01
The ability to mitigate interference is of central importance to cognition. Previous research has provided conflicting accounts about whether operations that resolve interference are singular in character or form a family of functions. Here, the authors examined the relationship between interference-resolution processes acting on working memory…
Shao, Zeshu; Roelofs, Ardi; Martin, Randi C; Meyer, Antje S
2015-11-01
In 2 studies, we examined whether explicit distractors are necessary and sufficient to evoke selective inhibition in 3 naming tasks: the semantic blocking, picture-word interference, and color-word Stroop task. Delta plots were used to quantify the size of the interference effects as a function of reaction time (RT). Selective inhibition was operationalized as the decrease in the size of the interference effect as a function of naming RT. For all naming tasks, mean naming RTs were significantly longer in the interference condition than in the control condition. The slopes of the interference effects for the longest naming RTs correlated with the magnitude of the mean interference effect in both the semantic blocking task and the picture-word interference task, suggesting that selective inhibition was involved to reduce the interference from strong semantic competitors either invoked by a single explicit competitor or strong implicit competitors in picture naming. However, there was no correlation between the slopes and the mean interference effect in the Stroop task, suggesting less importance of selective inhibition in this task despite explicit distractors. Whereas the results of the semantic blocking task suggest that an explicit distractor is not necessary for triggering inhibition, the results of the Stroop task suggest that such a distractor is not sufficient for evoking inhibition either. (c) 2015 APA, all rights reserved).
NASA Astrophysics Data System (ADS)
Delahaye, Thibault; Tran, Thi Ngoc Ha; Reed, Zachary; Maxwell, Stephen E.; Hodges, Joseph
2015-06-01
Climate change is one of the greatest challenges presently facing mankind, and methane is one of the most powerful anthropogenic greenhouse gases. For a better understanding of future climate trends, a satellite dedicated to the measurements of atmospheric methane is under joint development by the French and German space research centers (CNES and DLR). The so-called MERLIN mission (Methane Remote Sensing Lidar Mission, 2019) aims at providing global information on atmospheric methane concentration with a relative uncertainty less than 2% and with a spatial resolution of 50 km Such spectroscopic monitoring of gases in the atmosphere of the Earth, requires a precise description of absorption lines shapes that goes beyond the usual Voigt profile (VP). In the case of methane, the differences between the measured profiles and those given by the VP can be very important, making the VP completely incompatible with the reliable detection of sources and sinks from space. In this work, we present the first results on the modeling of methane lines broadened by air in the 1.64 μm region and the associated spectroscopic parameters, taking into account various collisional effects between molecules that are neglected by the VP: collisional interference between the lines (line-mixing), collision-induced velocity changes (Dicke narrowing effect) and speed dependence of the collisional broadening and shifting. These results were obtained by simultaneously fitting the model parameters to high sensitivity and high-resolution cavity ring-down spectroscopy (CRDS) spectra recorded at the National Institute of Standards and Technology (NIST) over a wide pressure range (5 to 100 kPa). These spectroscopic data and the associated model to calculate the spectrum absorption coefficient will be then used to analyze ground-based atmospheric spectra at the TCCON facility in Park Falls, Wisconsin. C. Kiemle, M. Quatrevalet, G. Ehret et al., Atmos. Meas. Tech. 4 (2011) H. Tran, J.-M. Hartmann, G. Toon et al., Journal of Quant. Spectrosc. Radia. Trans. 111 (2010)
2-micron Double Pulsed IPDA Lidar for Atmospheric CO2 Measurement
NASA Astrophysics Data System (ADS)
Yu, Jirong; Petros, Mulugeta; Refaat, Tamer; Reithmaier, Karl; Remus, Ruben; Singh, Upendra; Johnson, Will; Boyer, Charlie; Fay, James; Johnston, Susan; Murchison, Luke; Scola, Tory
2015-04-01
We have developed a high energy pulsed 2-micron IPDA lidar instrument to measure the atmospheric CO2 column density. The IPDA lidar is operated on the long wavelength wing of R(30) CO2 line at 2050.967 nm (4875.749 cm-1) in the side-line operation mode. The R(30) line is an excellent absorption line for the measurements of CO2 in 2µm wavelength region with regard to the strength of the absorption lines, low susceptibility to atmospheric temperature variability, and freedom from problematic interference with other absorption lines. The Ho:Tm:YLF laser transmitter is designed to be operated in a unique double pulse format that can produce two-pulse pair in 10 Hz operation. Typically, the output energies of the laser transmitter are 100mJ and 45mJ for the first pulse and the second pulse, respectively. We injection seed the first pulse with on-line frequency and the second pulse with off-line frequency. The IPDA lidar instrument size, weight and power consumption were restricted to small research aircraft payload requirements. The airborne IPDA lidar instrument measures the total integrated column content of CO2 from the instrument to the ground but with weighting that can be tuned by controlling the transmitted wavelengths. Therefore, the transmitter could be tuned to weight the column measurement to the surface for optimum CO2 interaction studies or up to the free troposphere for optimum transport studies. The 2-μm CO2 IPDA lidar airborne demonstration was conducted during March 20, 2014 through April 10, 2014. IPDA lidar airborne flights included various operating and environmental conditions. Environmental conditions included different flight altitude up to 8.3 km, different ground target conditions such as vegetation, soil, ocean, snow and sand and different cloud conditions. Besides, some flights targeted power plant incinerators for investigating the IPDA sensitivity to CO2 plums. The lidar instrument is robust during all of the flights. This paper describes the development of the new 2-micron pulsed IPDA lidar instrument, and presents the initial data for the airborne measurements of atmospheric CO2 concentration.
Xu, Min; Xu, Guiping; Yang, Yang
2016-01-01
Understanding how the nature of interference might influence the recruitments of the neural systems is considered as the key to understanding cognitive control. Although, interference processing in the emotional domain has recently attracted great interest, the question of whether there are separable neural patterns for emotional and non-emotional interference processing remains open. Here, we performed an activation likelihood estimation meta-analysis of 78 neuroimaging experiments, and examined common and distinct neural systems for emotional and non-emotional interference processing. We examined brain activation in three domains of interference processing: emotional verbal interference in the face-word conflict task, non-emotional verbal interference in the color-word Stroop task, and non-emotional spatial interference in the Simon, SRC and Flanker tasks. Our results show that the dorsal anterior cingulate cortex (ACC) was recruited for both emotional and non-emotional interference. In addition, the right anterior insula, presupplementary motor area (pre-SMA), and right inferior frontal gyrus (IFG) were activated by interference processing across both emotional and non-emotional domains. In light of these results, we propose that the anterior insular cortex may serve to integrate information from different dimensions and work together with the dorsal ACC to detect and monitor conflicts, whereas pre-SMA and right IFG may be recruited to inhibit inappropriate responses. In contrast, the dorsolateral prefrontal cortex (DLPFC) and posterior parietal cortex (PPC) showed different degrees of activation and distinct lateralization patterns for different processing domains, which suggests that these regions may implement cognitive control based on the specific task requirements. PMID:27895564
Visualizing the Solute Vaporization Interference in Flame Atomic Absorption Spectroscopy
ERIC Educational Resources Information Center
Dockery, Christopher R.; Blew, Michael J.; Goode, Scott R.
2008-01-01
Every day, tens of thousands of chemists use analytical atomic spectroscopy in their work, often without knowledge of possible interferences. We present a unique approach to study these interferences by using modern response surface methods to visualize an interference in which aluminum depresses the calcium atomic absorption signal. Calcium…
47 CFR 74.803 - Frequency selection to avoid interference.
Code of Federal Regulations, 2011 CFR
2011-10-01
... 47 Telecommunication 4 2011-10-01 2011-10-01 false Frequency selection to avoid interference. 74... Power Auxiliary Stations § 74.803 Frequency selection to avoid interference. (a) Where two or more low... frequencies or schedule operation in such manner as to avoid mutual interference. If a mutually satisfactory...
47 CFR 74.403 - Frequency selection to avoid interference.
Code of Federal Regulations, 2011 CFR
2011-10-01
... 47 Telecommunication 4 2011-10-01 2011-10-01 false Frequency selection to avoid interference. 74... Pickup Broadcast Stations § 74.403 Frequency selection to avoid interference. (a) Where two or more... select frequencies or schedule operation in such manner as to avoid mutual interference. If mutual...
47 CFR 74.403 - Frequency selection to avoid interference.
Code of Federal Regulations, 2010 CFR
2010-10-01
... 47 Telecommunication 4 2010-10-01 2010-10-01 false Frequency selection to avoid interference. 74... Pickup Broadcast Stations § 74.403 Frequency selection to avoid interference. (a) Where two or more... select frequencies or schedule operation in such manner as to avoid mutual interference. If mutual...
47 CFR 74.803 - Frequency selection to avoid interference.
Code of Federal Regulations, 2010 CFR
2010-10-01
... 47 Telecommunication 4 2010-10-01 2010-10-01 false Frequency selection to avoid interference. 74... Power Auxiliary Stations § 74.803 Frequency selection to avoid interference. (a) Where two or more low... frequencies or schedule operation in such manner as to avoid mutual interference. If a mutually satisfactory...
NASA Technical Reports Server (NTRS)
Nguyen, Tien M.
1994-01-01
This report reviews the current available work on interference susceptibility for various modulation schemes. Only known and published work in this area is descussed. This report classifies the interference signal into three different categories, namely, narrow-band (in-band), wide-band and pluse interference.
47 CFR 27.65 - Acceptance of interference in 2000-2020 MHz.
Code of Federal Regulations, 2013 CFR
2013-10-01
... 47 Telecommunication 2 2013-10-01 2013-10-01 false Acceptance of interference in 2000-2020 MHz. 27.65 Section 27.65 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER... interference in 2000-2020 MHz. (a) Receivers operating in the 2000-2020 MHz band must accept interference from...
47 CFR 27.65 - Acceptance of interference in 2000-2020 MHz.
Code of Federal Regulations, 2014 CFR
2014-10-01
... 47 Telecommunication 2 2014-10-01 2014-10-01 false Acceptance of interference in 2000-2020 MHz. 27.65 Section 27.65 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER... interference in 2000-2020 MHz. (a) Receivers operating in the 2000-2020 MHz band must accept interference from...
GOME-2 Tropospheric Ozone Profile Retrievals from Joint UV/Visible Measurement
NASA Astrophysics Data System (ADS)
Liu, X.; Zoogman, P.; Chance, K.; Cai, Z.; Nowlan, C. R.; Huang, G.; Gonzalez Abad, G.
2016-12-01
It has been shown from sensitivity studies that adding visible measurements in the Chappuis ozone band to UV measurements in the Hartley/Huggins ozone bands can significantly enhance retrieval sensitivity to lower tropospheric ozone from backscattered solar radiances due to deeper photon penetration in the visible to the surface than in the ultraviolet. The first NASA EVI (Earth Venture Instrument) TEMPO (Tropospheric Emissions: Monitoring of Pollution) instrument is being developed to measure backscattered solar radiation in two channels ( 290-490 and 540-740 nm) and make atmospheric pollution measurements over North America from the Geostationary orbit. However, this retrieval enhancement has yet to be demonstrated from existing measurements due to the weak ozone absorption in the visible and strong interferences from surface reflectance and aerosols and the requirement of accurate radiometric calibration across different spectral channels. We present GOME-2 retrievals from joint UV/visible measurements using the SAO ozone profile retrieval algorithm, to directly explore the retrieval improvement in lower tropospheric ozone from additional visible measurements. To reduce the retrieval interference from surface reflectance, we add characterization of surface spectral reflectance in the visible based on combining EOFs (Empirical Orthogonal Functions) derived from ASTER and other surface reflectance spectra with MODIS BRDF climatology into the ozone profile algorithm. The impacts of various types of aerosols and surface BRDF on the retrievals will be investigated. In addition, we will also perform empirical radiometric calibration of the GOME-2 data based on radiative transfer simulations. We will evaluate the retrieval improvement of joint UV/visible retrieval over the UV retrieval based on fitting quality and validation against ozonesonde observations.
NASA Technical Reports Server (NTRS)
Newman, Perry A.; Mineck, Raymond E.; Barnwell, Richard W.; Kemp, William B., Jr.
1986-01-01
About a decade ago, interest in alleviating wind tunnel wall interference was renewed by advances in computational aerodynamics, concepts of adaptive test section walls, and plans for high Reynolds number transonic test facilities. Selection of NASA Langley cryogenic concept for the National Transonic Facility (NTF) tended to focus the renewed wall interference efforts. A brief overview and current status of some Langley sponsored transonic wind tunnel wall interference research are presented. Included are continuing efforts in basic wall flow studies, wall interference assessment/correction procedures, and adaptive wall technology.
2017-04-01
INTERFERENCE-CANCELLATION AND N-PATH-MIXER FILTERING Harish Krishnaswamy, Negar Reiskarimian, and Linxiao Zhang Columbia University APRIL 2017 Final...INTERFERENCE-CANCELLATION AND N- PATH-MIXER FILTERING 5a. CONTRACT NUMBER FA8650-14-1-7414 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 61101E/62716E 6...techniques for developing interference mitigation technology (IMT) enabling frequency-agile, reconfigurable filter -less receivers. Wideband noise
Interference fits and stress-corrosion failure. [aircraft parts fatigue life analysis
NASA Technical Reports Server (NTRS)
Hanagud, S.; Carter, A. E.
1976-01-01
It is pointed out that any proper design of interference fit fastener, interference fit bushings, or stress coining processes should consider both the stress-corrosion susceptibility and fatigue-life improvement together. Investigations leading to such a methodology are discussed. A service failure analysis of actual aircraft parts is considered along with the stress-corrosion susceptibility of cold-working interference fit bushings. The optimum design of the amount of interference is considered, giving attention to stress formulas and aspects of design methodology.
Study on index system of GPS interference effect evaluation
NASA Astrophysics Data System (ADS)
Zhang, Kun; Zeng, Fangling; Zhao, Yuan; Zeng, Ruiqi
2018-05-01
Satellite navigation interference effect evaluation is the key technology to break through the research of Navigation countermeasure. To evaluate accurately the interference degree and Anti-jamming ability of GPS receiver, this text based on the existing research results of Navigation interference effect evaluation, build the index system of GPS receiver effectiveness evaluation from four levels of signal acquisition, tracking, demodulation and positioning/timing and establish the model for each index. These indexes can accurately and quantitatively describe the interference effect at all levels.
Communication: Finding destructive interference features in molecular transport junctions.
Reuter, Matthew G; Hansen, Thorsten
2014-11-14
Associating molecular structure with quantum interference features in electrode-molecule-electrode transport junctions has been difficult because existing guidelines for understanding interferences only apply to conjugated hydrocarbons. Herein we use linear algebra and the Landauer-Büttiker theory for electron transport to derive a general rule for predicting the existence and locations of interference features. Our analysis illustrates that interferences can be directly determined from the molecular Hamiltonian and the molecule-electrode couplings, and we demonstrate its utility with several examples.
Rosenbury, Christopher; Gu, Yalong; Gbur, Greg
2012-04-01
A previously derived condition for the complete destructive interference of partially coherent light emerging from a trio of pinholes in an opaque screen is generalized to the case when the coherence properties of the field are asymmetric. It is shown by example that the interference condition is necessary, but not sufficient, and that the existence of complete destructive interference also depends on the intensity of light emerging from the pinholes and the system geometry; more general conditions for such interference are derived. The phase of the wave field exhibits both phase singularities and correlation singularities, and a number of nonintuitive situations in which complete destructive interference occurs are described and explained.
Young's double-slit interference with two-color biphotons.
Zhang, De-Jian; Wu, Shuang; Li, Hong-Guo; Wang, Hai-Bo; Xiong, Jun; Wang, Kaige
2017-12-12
In classical optics, Young's double-slit experiment with colored coherent light gives rise to individual interference fringes for each light frequency, referring to single-photon interference. However, two-photon double-slit interference has been widely studied only for wavelength-degenerate biphoton, known as subwavelength quantum lithography. In this work, we report double-slit interference experiments with two-color biphoton. Different from the degenerate case, the experimental results depend on the measurement methods. From a two-axis coincidence measurement pattern we can extract complete interference information about two colors. The conceptual model provides an intuitional picture of the in-phase and out-of-phase photon correlations and a complete quantum understanding about the which-path information of two colored photons.
Electromagnetic interference in electrical systems of motor vehicles
NASA Astrophysics Data System (ADS)
Dziubiński, M.; Drozd, A.; Adamiec, M.; Siemionek, E.
2016-09-01
Electronic ignition system affects the electronic equipment of the vehicle by electric and magnetic fields. The measurement of radio electromagnetic interference originating from the ignition system affecting the audiovisual test bench was carried out with a variable speed of the ignition system. The paper presents measurements of radio electromagnetic interference in automobiles. In order to determine the level of electromagnetic interference, the audiovisual test bench was equipped with a set of meters for power consumption and assessment of the level of electromagnetic interference. Measurements of the electromagnetic interference level within the audiovisual system were performed on an experimental test bench consisting of the ignition system, starting system and charging system with an alternator and regulator.
CRISPR interference: RNA-directed adaptive immunity in bacteria and archaea
Marraffini, Luciano A.; Sontheimer, Erik J.
2010-01-01
Sequence-directed genetic interference pathways control gene expression and preserve genome integrity in all kingdoms of life. The importance of such pathways is highlighted by the extensive study of RNA interference (RNAi) and related processes in eukaryotes. In many bacteria and most archaea, clustered, regularly interspaced short palindromic repeats (CRISPRs) are involved in a more recently discovered interference pathway that protects cells from bacteriophages and conjugative plasmids. CRISPR sequences provide an adaptive, heritable record of past infections and express CRISPR RNAs — small RNAs that target invasive nucleic acids. Here, we review the mechanisms of CRISPR interference and its roles in microbial physiology and evolution. We also discuss potential applications of this novel interference pathway. PMID:20125085
Patterns of light interference produced by damaged cuticle cells in human hair.
Gamez-Garcia, Manuel; Lu, Yuan
2007-01-01
Colorful patterns of light interference have been observed to occur in human hair cuticle cells. The light interference phenomenon has been analyzed by optical microscopy. The strong patterns of light interference appeared only in cuticle cells that had been damaged either mechanically or by thermal stresses. Cuticle cells that were not damaged did not produce this phenomenon. The zones of light interference on the hair surface were seen to extend to cuticle sheath areas whose damage was not apparent when analyzed under the Scanning Electron Microscope. The presence of oils and other hydrophobic materials in the hair had a strong effect in the appearance or disappearance of the interference patterns.
Interference-free ultrasound imaging during HIFU therapy, using software tools
NASA Technical Reports Server (NTRS)
Vaezy, Shahram (Inventor); Held, Robert (Inventor); Sikdar, Siddhartha (Inventor); Managuli, Ravi (Inventor); Zderic, Vesna (Inventor)
2010-01-01
Disclosed herein is a method for obtaining a composite interference-free ultrasound image when non-imaging ultrasound waves would otherwise interfere with ultrasound imaging. A conventional ultrasound imaging system is used to collect frames of ultrasound image data in the presence of non-imaging ultrasound waves, such as high-intensity focused ultrasound (HIFU). The frames are directed to a processor that analyzes the frames to identify portions of the frame that are interference-free. Interference-free portions of a plurality of different ultrasound image frames are combined to generate a single composite interference-free ultrasound image that is displayed to a user. In this approach, a frequency of the non-imaging ultrasound waves is offset relative to a frequency of the ultrasound imaging waves, such that the interference introduced by the non-imaging ultrasound waves appears in a different portion of the frames.
Blank, Hartmut
2005-02-01
Traditionally, the causes of interference phenomena were sought in "real" or "hard" memory processes such as unlearning, response competition, or inhibition, which serve to reduce the accessibility of target items. I propose an alternative approach which does not deny the influence of such processes but highlights a second, equally important, source of interference-the conversion (Tulving, 1983) of accessible memory information into memory performance. Conversion is conceived as a problem-solving-like activity in which the rememberer tries to find solutions to a memory task. Conversion-based interference effects are traced to different conversion processes in the experimental and control conditions of interference designs. I present a simple theoretical model that quantitatively predicts the resulting amount of interference. In two paired-associate learning experiments using two different types of memory tests, these predictions were corroborated. Relations of the present approach to traditional accounts of interference phenomena and implications for eyewitness testimony are discussed.
Investigation of Interference Models for RFID Systems.
Zhang, Linchao; Ferrero, Renato; Gandino, Filippo; Rebaudengo, Maurizio
2016-02-04
The reader-to-reader collision in an RFID system is a challenging problem for communications technology. In order to model the interference between RFID readers, different interference models have been proposed, mainly based on two approaches: single and additive interference. The former only considers the interference from one reader within a certain range, whereas the latter takes into account the sum of all of the simultaneous interferences in order to emulate a more realistic behavior. Although the difference between the two approaches has been theoretically analyzed in previous research, their effects on the estimated performance of the reader-to-reader anti-collision protocols have not yet been investigated. In this paper, the influence of the interference model on the anti-collision protocols is studied by simulating a representative state-of-the-art protocol. The results presented in this paper highlight that the use of additive models, although more computationally intensive, is mandatory to improve the performance of anti-collision protocols.
Two-photon interference of temporally separated photons.
Kim, Heonoh; Lee, Sang Min; Moon, Han Seb
2016-10-06
We present experimental demonstrations of two-photon interference involving temporally separated photons within two types of interferometers: a Mach-Zehnder interferometer and a polarization-based Michelson interferometer. The two-photon states are probabilistically prepared in a symmetrically superposed state within the two interferometer arms by introducing a large time delay between two input photons; this state is composed of two temporally separated photons, which are in two different or the same spatial modes. We then observe two-photon interference fringes involving both the Hong-Ou-Mandel interference effect and the interference of path-entangled two-photon states simultaneously in a single interferometric setup. The observed two-photon interference fringes provide simultaneous observation of the interferometric properties of the single-photon and two-photon wavepackets. The observations can also facilitate a more comprehensive understanding of the origins of the interference phenomena arising from spatially bunched/anti-bunched two-photon states comprised of two temporally separated photons within the interferometer arms.
Ariza, Pedro; Solesio-Jofre, Elena; Martínez, Johann H.; Pineda-Pardo, José A.; Niso, Guiomar; Maestú, Fernando; Buldú, Javier M.
2015-01-01
In this study we used graph theory analysis to investigate age-related reorganization of functional networks during the active maintenance of information that is interrupted by external interference. Additionally, we sought to investigate network differences before and after averaging network parameters between both maintenance and interference windows. We compared young and older adults by measuring their magnetoencephalographic recordings during an interference-based working memory task restricted to successful recognitions. Data analysis focused on the topology/temporal evolution of functional networks during both the maintenance and interference windows. We observed that: (a) Older adults require higher synchronization between cortical brain sites in order to achieve a successful recognition, (b) The main differences between age groups arise during the interference window, (c) Older adults show reduced ability to reorganize network topology when interference is introduced, and (d) Averaging network parameters leads to a loss of sensitivity to detect age differences. PMID:26029079
Experimental and Theoretical Study of Propeller Spinner/Shank Interference. M.S. Thesis
NASA Technical Reports Server (NTRS)
Cornell, C. C.
1986-01-01
A fundamental experimental and theoretical investigation into the aerodynamic interference associated with propeller spinner and shank regions was conducted. The research program involved a theoretical assessment of solutions previously proposed, followed by a systematic experimental study to supplement the existing data base. As a result, a refined computational procedure was established for prediction of interference effects in terms of interference drag and resolved into propeller thrust and torque components. These quantities were examined with attention to engineering parameters such as two spinner finess ratios, three blade shank forms, and two/three/four/six/eight blades. Consideration of the physics of the phenomena aided in the logical deduction of two individual interference quantities (cascade effects and spinner/shank juncture interference). These interference effects were semi-empirically modeled using existing theories and placed into a compatible form with an existing propeller performance scheme which provided the basis for examples of application.
Susceptibility to declarative memory interference is pronounced in primary insomnia.
Griessenberger, Hermann; Heib, Dominik P J; Lechinger, Julia; Luketina, Nikolina; Petzka, Marit; Moeckel, Tina; Hoedlmoser, Kerstin; Schabus, Manuel
2013-01-01
Sleep has been shown to stabilize memory traces and to protect against competing interference in both the procedural and declarative memory domain. Here, we focused on an interference learning paradigm by testing patients with primary insomnia (N = 27) and healthy control subjects (N = 21). In two separate experimental nights with full polysomnography it was revealed that after morning interference procedural memory performance (using a finger tapping task) was not impaired in insomnia patients while declarative memory (word pair association) was decreased following interference. More specifically, we demonstrate robust associations of central sleep spindles (in N3) with motor memory susceptibility to interference as well as (cortically more widespread) fast spindle associations with declarative memory susceptibility. In general the results suggest that insufficient sleep quality does not necessarily show up in worse overnight consolidation in insomnia but may only become evident (in the declarative memory domain) when interference is imposed.
Addressing Cultural and Native Language Interference in Second Language Acquisition
ERIC Educational Resources Information Center
Allard, Daniele; Bourdeau, Jacqueline; Mizoguchi, Riichiro
2011-01-01
This paper addresses the problem of cultural and native language interference in second/foreign language acquisition. More specifically, it examines issues of interference that can be traced to a student's native language and that also have a cultural component. To this effect, an understanding of what actually comprises both interference and…
A Psychophysiological Analysis of Developmental Differences in the Ability to Resist Interference.
ERIC Educational Resources Information Center
Ridderinkhof, K. Richard; van der Molen, Maurits W.
1995-01-01
Examined age-related changes in visual selective attention--ability to resist interference--in children 5 to 12 years old and adults. The interference effect on stimulus evaluation did not discriminate between age groups; however, the interference effect on correct response activation showed a pronounced age-related reduction, suggesting a…
Delaying Interference Training Has Equivalent Effects in Various Pavlovian Interference Paradigms
ERIC Educational Resources Information Center
Powell, Elizabeth J.; Escobar, Martha; Kimble, Whitney
2013-01-01
Spontaneous recovery in extinction appears to be inversely related to the acquisition-to-extinction interval, but it remains unclear why this is the case. Rat subjects trained with one of three interference paradigms exhibited less spontaneous recovery of the original response after delayed than immediate interference, regardless of whether…
47 CFR 25.265 - Acceptance of interference in 2000-2020 MHz.
Code of Federal Regulations, 2014 CFR
2014-10-01
... 47 Telecommunication 2 2014-10-01 2014-10-01 false Acceptance of interference in 2000-2020 MHz. 25... SERVICES SATELLITE COMMUNICATIONS Technical Standards § 25.265 Acceptance of interference in 2000-2020 MHz. (a) MSS receivers operating in the 2000-2020 MHz band must accept interference from lawful operations...
47 CFR 25.265 - Acceptance of interference in 2000-2020 MHz.
Code of Federal Regulations, 2013 CFR
2013-10-01
... 47 Telecommunication 2 2013-10-01 2013-10-01 false Acceptance of interference in 2000-2020 MHz. 25... SERVICES SATELLITE COMMUNICATIONS Technical Standards § 25.265 Acceptance of interference in 2000-2020 MHz. (a) MSS receivers operating in the 2000-2020 MHz band must accept interference from lawful operations...
A Longitudinal Panel Study on Antecedents and Outcomes of Work-Home Interference
ERIC Educational Resources Information Center
Steinmetz, Holger; Frese, Michael; Schmidt, Peter
2008-01-01
Theoretical models of the antecedents and outcomes of work-home interference (WHI) suggest that work characteristics (e.g., job stressors, working hours) increase the probability that an individual experiences work-home interference. Since work-home interference is considered as a role stressor, these experiences should be detrimental for…
Lions, tigers, and bears, oh sh!t: Semantics versus tabooness in speech production.
White, Katherine K; Abrams, Lise; Koehler, Sarah M; Collins, Richard J
2017-04-01
While both semantic and highly emotional (i.e., taboo) words can interfere with speech production, different theoretical mechanisms have been proposed to explain why interference occurs. Two experiments investigated these theoretical approaches by comparing the magnitude of these two types of interference and the stages at which they occur during picture naming. Participants named target pictures superimposed with semantic, taboo, or unrelated distractor words that were presented at three different stimulus-onset asynchronies (SOA): -150 ms, 0 ms, or +150 ms. In addition, the duration of distractor presentation was manipulated across experiments, with distractors appearing for the duration of the picture (Experiment 1) or for 350 ms (Experiment 2). Taboo distractors interfered more than semantic distractors, i.e., slowed target naming times, at all SOAs. While distractor duration had no effect on type of interference at -150 or 0 SOAs, briefly presented distractors eliminated semantic interference but not taboo interference at +150 SOA. Discussion focuses on how existing speech production theories can explain interference from emotional distractors and the unique role that attention may play in taboo interference.
Adaptive detection of noise signal according to Neumann-Pearson criterion
NASA Astrophysics Data System (ADS)
Padiryakov, Y. A.
1985-03-01
Optimum detection according to the Neumann-Pearson criterion is considered in the case of a random Gaussian noise signal, stationary during measurement, and a stationary random Gaussian background interference. Detection is based on two samples, their statistics characterized by estimates of their spectral densities, it being a priori known that sample A from the signal channel is either the sum of signal and interference or interference alone and sample B from the reference interference channel is an interference with the same spectral density as that of the interference in sample A for both hypotheses. The probability of correct detection is maximized on the average, first in the 2N-dimensional space of signal spectral density and interference spectral density readings, by fixing the probability of false alarm at each point so as to stabilize it at a constant level against variation of the interference spectral density. Deterministic decision rules are established. The algorithm is then reduced to equivalent detection in the N-dimensional space of the ratio of sample A readings to sample B readings.
Dissociating interference-control processes between memory and response.
Bissett, Patrick G; Nee, Derek Evan; Jonides, John
2009-09-01
The ability to mitigate interference is of central importance to cognition. Previous research has provided conflicting accounts about whether operations that resolve interference are singular in character or form a family of functions. Here, the authors examined the relationship between interference-resolution processes acting on working memory representations versus responses. The authors combined multiple forms of interference into a single paradigm by merging a directed-forgetting task, which induces proactive interference, with a stop-signal task, which taps response inhibition processes. The results demonstrated that proactive interference and response inhibition produced distinct behavioral signatures that did not interact. By contrast, combining two different measures of response inhibition by merging a go/no-go task variant and a stop signal produced overadditive behavioral interference, demonstrating that different forms of response inhibition tap the same processes. However, not all forms of response conflict interacted, suggesting that inhibition-related functions acting on response selection are dissociable from those acting on response inhibition. These results suggest that inhibition-related functions for memory and responses are dissociable. (c) 2009 APA, all rights reserved.
Interference between face and non-face domains of perceptual expertise: a replication and extension
Curby, Kim M.; Gauthier, Isabel
2014-01-01
As car expertise increases, so does interference between the visual processing of faces and that of cars; this suggests performance trade-offs across domains of real-world expertise. Such interference between expert domains has been previously revealed in a relatively complex design, interleaving 2-back part-judgment task with faces and cars (Gauthier et al., 2003). However, the basis of this interference is unclear. Experiment 1A replicated the finding of interference between faces and cars, as a function of car expertise. Experiments 1B and 2 investigated the mechanisms underlying this effect by (1) providing baseline measures of performance and (2) assessing the specificity of this interference effect. Our findings support the presence of expertise-dependent interference between face and non-face domains of expertise. However, surprisingly, it is in the condition where faces are processed among cars with a disrupted configuration where expertise has a greater influence on faces. This finding highlights how expertise-related processing changes also occur for transformed objects of expertise and that such changes can also drive interference across domains of expertise. PMID:25346702
Mishra, Jyoti; Zanto, Theodore; Nilakantan, Aneesha; Gazzaley, Adam
2013-01-01
Intrasensory interference during visual working memory (WM) maintenance by object stimuli (such as faces and scenes), has been shown to negatively impact WM performance, with greater detrimental impacts of interference observed in aging. Here we assessed age-related impacts by intrasensory WM interference from lower-level stimulus features such as visual and auditory motion stimuli. We consistently found that interference in the form of ignored distractions and secondary task i nterruptions presented during a WM maintenance period, degraded memory accuracy in both the visual and auditory domain. However, in contrast to prior studies assessing WM for visual object stimuli, feature-based interference effects were not observed to be significantly greater in older adults. Analyses of neural oscillations in the alpha frequency band further revealed preserved mechanisms of interference processing in terms of post-stimulus alpha suppression, which was observed maximally for secondary task interruptions in visual and auditory modalities in both younger and older adults. These results suggest that age-related sensitivity of WM to interference may be limited to complex object stimuli, at least at low WM loads. PMID:23791629