Science.gov

Sample records for au reseau public

  1. Technique distribuee de gestion de la charge sur le reseau electrique et ring-tree: Un nouveau systeme de communication P2P

    NASA Astrophysics Data System (ADS)

    Ayoub, Simon

    suffisant pour les besoins des applications visees. Les protocoles de communication s'appuient sur un protocole de transport qui peut etre un de ceux utilises sur l'Internet comme TCP ou UDP. Pour valider le fonctionnement de de la technique de controle distribuee et le systeme de communiction Ring-Tree, un simulateur a ete developpe; un modele de chauffe-eau, comme exemple de charge, a ete integre au simulateur. La simulation d'une communaute de chauffe-eaux intelligents a montre que la technique de gestion de la charge combinee avec du stockage d'energie sous forme thermique permet d'obtenir, sans affecter le confort de l'utilisateur, des profils de consommation varies dont un profil de consommation uniforme qui represente un facteur de charge de 100%. Mots-cles : Algorithme Distribue, Demand Response, Gestion de la Charge Electrique, M2M (Machine-to-Machine), P2P (Peer-to-Peer), Reseau Electrique Intelligent, Ring-Tree, Smart Grid

  2. A Political History of Public Libraries in Quebec (Bibliotheques Municipales au Quebec).

    ERIC Educational Resources Information Center

    Kuntz, Patricia S.

    In the province of Quebec, the role of language and religion has been a significant feature in defining nationality, educating the young, and building infrastructures such as libraries. In contrast to English-Canadian provinces, only after 1960 did the government of Quebec authorize public support for public libraries to serve its francophone…

  3. IUE data reduction - The parameterization of the motion of the IUE reseau grids and spectral formats as a function of time and temperature

    NASA Technical Reports Server (NTRS)

    Thompson, R. W.; Turnrose, B. E.; Bohlin, R. C.

    1982-01-01

    Improvements are made on IUE data reduction using corrected reseau positions and dispersion constants for temperature variations and secular effects. Models describing the motion of the high dispersion spectral format as a function of THDA alone reduce the scatter in the predicted position of a given wavelength, and scatter is further reduced when a linear dependence on time is also allowed. A correction technique is presented for early data which reduces errors in wavelength assignments from over 30 km/s to less than 3 km/s in high dispersion. The reseau temperature correction helps locate the minimum background signal, centered between the echelle orders. The residual uncertainty of 2 km/s for SWP and 2.7 km/s for LWR makes the wavelength accuracy of time and temperature corrected IUE spectra comparable to that of temperature corrected data from the Copernicus satellite.

  4. Tuberculose chez le personnel de santé du secteur public au Burundi: fréquence et facteurs de risque

    PubMed Central

    Mukuku, Olivier; Ruhindiza, Bienvenu Mukuku; Mupepe, Alexis Kumba; Sawadogo, Michel

    2013-01-01

    Introduction Le but de cette étude était de déterminer la fréquence de la tuberculose (TB) chez le personnel de santé du secteur public en charge des patients tuberculeux et d’évaluer les facteurs de risque de contracter la tuberculose chez ce personnel au Burundi. Méthodes Il s’agit d’une étude transversale à visée analytique réalisée auprès de 300 travailleurs prestant dans 30 centres de dépistage et de traitement de la TB (CDT) au Burundi du 16 octobre au 15 novembre 2012. Les paramètres sociodémographiques et professionnels ainsi que l’antécédent de vaccination BCG de travailleurs ayant été touché par la TB ont été analysé et comparé à ceux de travailleurs qui ne l’ont pas été. Le seuil de signification a été fixé à p < 0,05. Résultats La fréquence de la TB chez le personnel de santé est de 15%. Le risque de souffrir de la TB est de près de 4 fois chez les travailleurs âgés d’au moins 50 ans (OR=3,73; 1,53-9,08), chez ceux qui n’ont jamais reçu de vaccin de BCG (OR=3,73; 1,24-11,03), chez ceux qui n’ont pas de cicatrice vaccinale de BCG (OR=3,80; 1,67-8,62) et chez ceux qui travaillent depuis au moins 6 ans dans un CDT (OR=3,79; 1,44-9,96); ce risque est de 9 fois chez ceux qui sont mariés (OR=9,42; 1,26-70,23), de 8 fois chez ceux qui n’aèrent pas leurs salles de travail (OR=8,20; 1,48-48,23) et de 6 fois chez ceux qui ont comme profession nettoyeur ou aide-soignant (OR=6,12; 2,92-12,82). Par contre, aucune corrélation statistiquement significative n’a été observée entre le fait de souffrir de la TB et le sexe mais aussi le nombre d’heures de contact d’un travailleur avec un patient tuberculeux (p>0,05). Conclusion L’âge, l’antécédent de vaccination de BCG ainsi que la majorité de paramètres professionnels sont en association avec la maladie TB des travailleurs de CDT. D’où, la maîtrise de certains facteurs de risque s’avère important pour faire face au fardeau de la TB parmi

  5. Translation into French of: "Changes to publication requirements made at the XVIII International Botanical Congress in Melbourne - what does e-publication mean for you?". Translated by Christian Feuillet and Valéry Malécot Changements des conditions requises pour la publication faits au XVIII Congrès International de Botanique à Melbourne - qu'est-ce que la publication électronique représente pour vous?

    PubMed

    Knapp, Sandra; McNeill, John; Turland, Nicholas J

    2011-01-01

    RésuméLes changements au CodeInternational de Nomenclature Botanique sont décidés tous les 6 ans aux Sections de Nomenclature associées aux Congrès Internationaux de Botanique (CIB). Le XVIII(e) CIB se tenait à Melbourne, Australie; la Section de Nomenclature s'est réunie les 18-22 juillet 2011 et ses décisions ont été acceptées par le Congrès en session plénière le 30 juillet. Suite à cette réunion, plusieurs modifications importantes ont été apportées au Code et vont affecter la publication de nouveaux noms. Deux de ces changements prendront effet le 1(er) janvier 2012, quelques mois avant que le Code de Melbourne soit publié. Les documents électroniques publiés en ligne en 'Portable Document Format' (PDF) avec un 'International Standard Serial Number' (ISSN) ou un 'International Standard Book Number' (ISBN) constitueront une publication effective, et l'exigence d'une description ou d'une diagnose en latin pour les noms des nouveaux taxa sera changée en l'exigence d'une description ou d'une diagnose en latin ou en anglais. De plus, à partir du 1(er) janvier 2013, les noms nouveaux des organismes traités comme champignons devront, pour que la publication soit valide, inclure dans le protologue (tous ce qui est associé au nom au moment de la publication valide) la citation d'un identifiant ('identifier') fourni par un dépôt reconnu (tel MycoBank). Une ébauche des nouveaux articles concernant la publication électronique est fournie et des conseils de bon usage sont esquissés.Pour encourager la diffusion des changements adoptés au Code International de Nomenclature pour les algues, les champignons et les plantes, cet article sera publié dans BMC Evolutionary Biology, Botanical Journal of the Linnean Society, Brittonia, Cladistics, MycoKeys, Mycotaxon, New Phytologist, North American Fungi, Novon, Opuscula Philolichenum, PhytoKeys, Phytoneuron, Phytotaxa, Plant Diversity and Resources, Systematic Botany et Taxon. PMID:22287925

  6. Translation into French of: “Changes to publication requirements made at the XVIII International Botanical Congress in Melbourne – what does e-publication mean for you?”. Translated by Christian Feuillet and Valéry Malécot Changements des conditions requises pour la publication faits au XVIII e Congrès International de Botanique à Melbourne – qu’est-ce que la publication électronique représente pour vous?

    PubMed Central

    Knapp, Sandra; McNeill, John; Turland, Nicholas J.

    2011-01-01

    Résumé Les changements au Code International de Nomenclature Botanique sont décidés tous les 6 ans aux Sections de Nomenclature associées aux Congrès Internationaux de Botanique (CIB). Le XVIIIe CIB se tenait à Melbourne, Australie; la Section de Nomenclature s’est réunie les 18-22 juillet 2011 et ses décisions ont été acceptées par le Congrès en session plénière le 30 juillet. Suite à cette réunion, plusieurs modifications importantes ont été apportées au Code et vont affecter la publication de nouveaux noms. Deux de ces changements prendront effet le 1er janvier 2012, quelques mois avant que le Code de Melbourne soit publié. Les documents électroniques publiés en ligne en ‘Portable Document Format’ (PDF) avec un ‘International Standard Serial Number’ (ISSN) ou un ‘International Standard Book Number’ (ISBN) constitueront une publication effective, et l’exigence d’une description ou d’une diagnose en latin pour les noms des nouveaux taxa sera changée en l’exigence d’une description ou d’une diagnose en latin ou en anglais. De plus, à partir du 1er janvier 2013, les noms nouveaux des organismes traités comme champignons devront, pour que la publication soit valide, inclure dans le protologue (tous ce qui est associé au nom au moment de la publication valide) la citation d’un identifiant (‘identifier’) fourni par un dépôt reconnu (tel MycoBank). Une ébauche des nouveaux articles concernant la publication électronique est fournie et des conseils de bon usage sont esquissés. Pour encourager la diffusion des changements adoptés au Code International de Nomenclature pour les algues, les champignons et les plantes, cet article sera publié dans BMC Evolutionary Biology, Botanical Journal of the Linnean Society, Brittonia, Cladistics, MycoKeys, Mycotaxon, New Phytologist, North American Fungi, Novon, Opuscula Philolichenum, PhytoKeys, Phytoneuron, Phytotaxa, Plant Diversity and Resources, Systematic Botany et

  7. Publications

    Cancer.gov

    Information about NCI publications including PDQ cancer information for patients and health professionals, patient-education publications, fact sheets, dictionaries, NCI blogs and newsletters and major reports.

  8. Publications.

    ERIC Educational Resources Information Center

    Aviation/Space, 1980

    1980-01-01

    Presents a variety of publications available from government and nongovernment sources. The government publications are from the Federal Aviation Administration (FAA) and the National Aeronautics and Space Administration (NASA) and are designed for educators, students, and the public. (Author/SA)

  9. Collective flow in Au + Au collisions

    SciTech Connect

    Ritter, H.G.; EOS Collaboration

    1994-05-01

    Based on a preliminary sample of Au + Au collisions in the EOS time projection chamber at the Bevalac, we study sideward flow as a function of bombarding energy between 0.25A GeV and 1.2A GeV. We focus on the increase in in-plane transverse momentum per nucleon with fragment mass. We also find event shapes to be close to spherical in the most central collisions, independent of bombarding energy and fragment mass up to {sup 4}He.

  10. Spin resonance transport properties of a single Au atom in S-Au-S junction and Au-Au-Au junction

    NASA Astrophysics Data System (ADS)

    Fangyuan, Wang; Guiqin, Li

    2016-07-01

    The spin transport properties of S-Au-S junction and Au-Au-Au junction between Au nanowires are investigated with density functional theory and the non-equilibrium Green's function. We mainly focus on the spin resonance transport properties of the center Au atom. The breaking of chemical bonds between anchor atoms and center Au atom significantly influences their spin transmission characteristics. We find the 0.8 eV orbital energy shift between anchor S atoms and the center Au atom can well protect the spin state stored in the S-Au-S junction and efficiently extract its spin state to the current by spin resonance mechanism, while the spin interaction of itinerant electrons and the valence electron of the center Au atom in the Au-Au-Au junction can extract the current spin information into the center Au atom. Fermi energy drift and bias-dependent spin filtering properties of the Au-Au-Au junction may transform information between distance, bias, and electron spin. Those unique properties make them potential candidates for a logical nanocircuit. Project supported by the National Basic Research Program of China (Grants No. 2011CB921602) and the National Natural Science Foundation of China (Grants No. 20121318158).

  11. Magnetic susceptibilities of liquid Cr-Au, Mn-Au and Fe-Au alloys

    SciTech Connect

    Ohno, S.; Shimakura, H.; Tahara, S.; Okada, T.

    2015-08-17

    The magnetic susceptibility of liquid Cr-Au, Mn-Au, Fe-Au and Cu-Au alloys was investigated as a function of temperature and composition. Liquid Cr{sub 1-c}Au{sub c} with 0.5 ≤ c and Mn{sub 1-c}Au{sub c} with 0.3≤c obeyed the Curie-Weiss law with regard to their dependence of χ on temperature. The magnetic susceptibilities of liquid Fe-Au alloys also exhibited Curie-Weiss behavior with a reasonable value for the effective number of Bohr magneton. On the Au-rich side, the composition dependence of χ for liquid TM-Au (TM=Cr, Mn, Fe) alloys increased rapidly with increasing TM content, respectively. Additionally, the composition dependences of χ for liquid Cr-Au, Mn-Au, and Fe-Au alloys had maxima at compositions of 50 at% Cr, 70 at% Mn, and 85 at% Fe, respectively. We compared the composition dependences of χ{sub 3d} due to 3d electrons for liquid binary TM-M (M=Au, Al, Si, Sb), and investigated the relationship between χ{sub 3d} and E{sub F} in liquid binary TM-M alloys at a composition of 50 at% TM.

  12. /Au Back Contacts

    NASA Astrophysics Data System (ADS)

    Paudel, Naba R.; Compaan, Alvin D.; Yan, Yanfa

    2014-08-01

    We report on the fabrication and characterization of CdTe thin-film solar cells with Cu-free MoO3- x /Au back contacts. CdTe solar cells with sputtered CdTe absorbers of thicknesses from 0.5 to 1.75 μm were fabricated on Pilkington SnO2:F/SnO2-coated soda-lime glasses coated with a 60- to 80-nm sputtered CdS layer. The MoO3- x /Au back contact layers were deposited by thermal evaporation. The incorporation of MoO3- x layer was found to improve the open circuit voltage ( V OC) but reduce the fill factor of the ultrathin CdTe cells. The V OC was found to increase as the CdTe thickness increased.

  13. Magnetoresistance of Au films

    DOE PAGESBeta

    Zhang, D. L.; Song, X. H.; Zhang, X.; Zhang, Xiaoguang

    2014-12-10

    Measurement of the magnetoresistance (MR) of Au films as a function of temperature and film thickness reveals a strong dependence on grain size distribution and clear violation of the Kohler s rule. Using a model of random resistor network, we show that this result can be explained if the MR arises entirely from inhomogeneity due to grain boundary scattering and thermal activation of grain boundary atoms.

  14. Antibacterial Au nanostructured surfaces

    NASA Astrophysics Data System (ADS)

    Wu, Songmei; Zuber, Flavia; Brugger, Juergen; Maniura-Weber, Katharina; Ren, Qun

    2016-01-01

    We present here a technological platform for engineering Au nanotopographies by templated electrodeposition on antibacterial surfaces. Three different types of nanostructures were fabricated: nanopillars, nanorings and nanonuggets. The nanopillars are the basic structures and are 50 nm in diameter and 100 nm in height. Particular arrangement of the nanopillars in various geometries formed nanorings and nanonuggets. Flat surfaces, rough substrate surfaces, and various nanostructured surfaces were compared for their abilities to attach and kill bacterial cells. Methicillin-resistant Staphylococcus aureus, a Gram-positive bacterial strain responsible for many infections in health care system, was used as the model bacterial strain. It was found that all the Au nanostructures, regardless their shapes, exhibited similar excellent antibacterial properties. A comparison of live cells attached to nanotopographic surfaces showed that the number of live S. aureus cells was <1% of that from flat and rough reference surfaces. Our micro/nanofabrication process is a scalable approach based on cost-efficient self-organization and provides potential for further developing functional surfaces to study the behavior of microbes on nanoscale topographies.We present here a technological platform for engineering Au nanotopographies by templated electrodeposition on antibacterial surfaces. Three different types of nanostructures were fabricated: nanopillars, nanorings and nanonuggets. The nanopillars are the basic structures and are 50 nm in diameter and 100 nm in height. Particular arrangement of the nanopillars in various geometries formed nanorings and nanonuggets. Flat surfaces, rough substrate surfaces, and various nanostructured surfaces were compared for their abilities to attach and kill bacterial cells. Methicillin-resistant Staphylococcus aureus, a Gram-positive bacterial strain responsible for many infections in health care system, was used as the model bacterial strain. It

  15. Surface morphology and optical properties of porphyrin/Au and Au/porphyrin/Au systems

    PubMed Central

    2013-01-01

    Porphyrin/Au and Au/porphyrin/Au systems were prepared by vacuum evaporation and vacuum sputtering onto glass substrate. The surface morphology of as-prepared systems and those subjected to annealing at 160°C was studied by optical microscopy, atomic force microscopy, and scanning electron microscopy techniques. Absorption and luminescence spectra of as-prepared and annealed samples were measured. Annealing leads to disintegration of the initially continuous gold layer and formation of gold nanoclusters. An amplification of Soret band magnitude was observed on the Au/meso-tetraphenyl porphyrin (TPP) system in comparison with mere TPP. Additional enhancement of luminescence was observed after the sample annealing. In the case of sandwich Au/porphyrin/Au structure, suppression of one of the two porphyrins’ luminescence maxima and sufficient enhancement of the second one were observed. PMID:24373347

  16. Magnetoresistance of Au films

    SciTech Connect

    Zhang, D. L. Song, X. H.; Zhang, X.; Zhang, X.-G.

    2014-12-14

    Classical magnetoresistance (MR) in nonmagnetic metals are conventionally understood in terms of the Kohler rule, with violation usually viewed as anomalous electron transport, in particular, as evidence of non-Fermi liquid behavior. Measurement of the MR of Au films as a function of temperature and film thickness reveals a strong dependence on grain size distribution and clear violation of the Kohler rule. Using a model of random resistor network, we show that this result can be explained if the MR arises entirely from inhomogeneity due to grain boundary scattering and thermal activation of grain boundary atoms. Consequently, the Kohler rule should not be used to distinguish normal and anomalous electron transport in solids.

  17. Au103(SR)45, Au104(SR)45, Au104(SR)46 and Au105(SR)46 nanoclusters

    NASA Astrophysics Data System (ADS)

    Dass, Amala; Nimmala, Praneeth Reddy; Jupally, Vijay Reddy; Kothalawala, Nuwan

    2013-11-01

    High resolution ESI mass spectrometry of the ``22 kDa'' nanocluster reveals the presence of a mixture containing Au103(SR)45, Au104(SR)45, Au104(SR)46, and Au105(SR)46 nanoclusters, where R = -CH2CH2Ph. MALDI TOF MS data confirm the purity of the sample and a UV-vis spectrum shows minor features. Au102(SC6H5COOH)44, whose XRD crystal structure was recently reported, is not observed. This is due to ligand effects, because the 102 : 44 composition is produced using aromatic ligands. However, the 103-, 104- and 105-atom nanoclusters, protected by -SCH2CH2Ph and -SC6H13 ligands, are at or near 58 electron shell closing.High resolution ESI mass spectrometry of the ``22 kDa'' nanocluster reveals the presence of a mixture containing Au103(SR)45, Au104(SR)45, Au104(SR)46, and Au105(SR)46 nanoclusters, where R = -CH2CH2Ph. MALDI TOF MS data confirm the purity of the sample and a UV-vis spectrum shows minor features. Au102(SC6H5COOH)44, whose XRD crystal structure was recently reported, is not observed. This is due to ligand effects, because the 102 : 44 composition is produced using aromatic ligands. However, the 103-, 104- and 105-atom nanoclusters, protected by -SCH2CH2Ph and -SC6H13 ligands, are at or near 58 electron shell closing. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr03872f

  18. Determination of relative sensitivity factors during secondary ion sputtering of silicate glasses by Au+, Au2+ and Au3+ ions.

    PubMed

    King, Ashley; Henkel, Torsten; Rost, Detlef; Lyon, Ian C

    2010-01-01

    In recent years, Au-cluster ions have been successfully used for organic analysis in secondary ion mass spectrometry. Cluster ions, such as Au(2)(+) and Au(3)(+), can produce secondary ion yield enhancements of up to a factor of 300 for high mass organic molecules with minimal sample damage. In this study, the potential for using Au(+), Au(2)(+) and Au(3)(+) primary ions for the analysis of inorganic samples is investigated by analyzing a range of silicate glass standards. Practical secondary ion yields for both Au(2)(+) and Au(3)(+) ions are enhanced relative to those for Au(+), consistent with their increased sputter rates. No elevation in ionization efficiency was found for the cluster primary ions. Relative sensitivity factors for major and trace elements in the standards showed no improvement in quantification with Au(2)(+) and Au(3)(+) ions over the use of Au(+) ions. Higher achievable primary ion currents for Au(+) ions than for Au(2)(+) and Au(3)(+) allow for more precise analyses of elemental abundances within inorganic samples, making them the preferred choice, in contrast to the choice of Au(2)(+) and Au(3)(+) for the analysis of organic samples. The use of delayed secondary ion extraction can also boost secondary ion signals, although there is a loss of overall sensitivity.

  19. Centrality dependence of antiproton production in Au+Au collisions

    SciTech Connect

    Beavis, D.; Bennett, M.J.; Carroll, J.B.; Chiba, J.; Chikanian, A.; Crawford, H.; Cronqvist, M.; Dardenne, Y.; Debbe, R.; Doke, T.; Engelage, J.; Greiner, L.; Hallman, T.J.; Hayano, R.S.; Heckman, H.H.; Kashiwagi, T.; Kikuchi, J.; Kumar, S.; Kuo, C.; Lindstrom, P.J.; Mitchell, J.W.; Nagamiya, S.; Nagle, J.L.; Pope, J.K.; Stankus, P.; Tanaka, K.H.; Welsh, R.C.; Zhan, W. ||||||||[Universities Space Sciences Research Association

    1995-11-13

    We have measured the yields of antiprotons in Au+Au interactions in the rapidity range 1.2{lt}{ital y}{lt}2.8 as a function of centrality using a beam line spectrometer. The shapes of the invariant multiplicity distributions at {ital p}{sub {ital t}}=0 are used to explore the dynamics of antiproton production and annihilation. {copyright} {ital 1995} {ital The} {ital American} {ital Physical} {ital Society}.

  20. Au20: A Tetrahedral Cluster

    SciTech Connect

    Li, Jun; Li, Xi; Zhai, Hua Jin; Wang, Lai S.

    2003-02-07

    Photoelectron spectroscopy revealed that a 20 atom gold cluster has an extremely large energy gap, which is even greater than that of C60, and an electron affinity comparable with that of C60. This observation suggests that the Au20 cluster must be extremely stable and chemically inert. Using relativistic density functional calculations, we found that Au20 possesses a remarkable tetrahedral structure, which is a fragment of the bulk face-centered cubic lattice of gold with a small structural relaxation. Au20 is thus a true cluster molecule, while at the same time it is exactly part of the bulk, but with very different properties. The tetrahedral Au20 may possess interesting catalytic properties and may be synthesized in bulk quantity or assembled on non-interacting surfaces.

  1. Interfacial nanodroplets guided construction of hierarchical Au, Au-Pt, and Au-Pd particles as excellent catalysts

    PubMed Central

    Ma, Aijing; Xu, Jie; Zhang, Xuehua; Zhang, Bin; Wang, Dayang; Xu, Haolan

    2014-01-01

    Interfacial nanodroplets were grafted to the surfaces of self-sacrificed template particles in a galvanic reaction system to assist the construction of 3D Au porous structures. The interfacial nanodroplets were formed via direct adsorption of surfactant-free emulsions onto the particle surfaces. The interfacial nanodroplets discretely distributed at the template particle surfaces and served as soft templates to guide the formation of porous Au structures. The self-variation of footprint sizes of interfacial nanodroplets during Au growth gave rise to a hierarchical pore size distribution of the obtained Au porous particles. This strategy could be easily extended to synthesize bimetal porous particles such as Au-Pt and Au-Pd. The obtained porous Au, Au-Pt, and Au-Pd particles showed excellent catalytic activity in catalytic reduction of 4-nitrophenol. PMID:24797697

  2. Au36(SPh)23 nanomolecules.

    PubMed

    Nimmala, Praneeth Reddy; Dass, Amala

    2011-06-22

    A new core size protected completely by an aromatic thiol, Au(36)(SPh)(23), is synthesized and characterized by MALDI-TOF mass spectrometry and UV-visible spectroscopy. The synthesis involving core size changes is studied by MS, and the complete ligand coverage by aromatic thiol group is shown by NMR.

  3. Global polarization measurement in Au+Au collisions

    SciTech Connect

    Abelev, B.I.; Adams, J.; Aggarwal, M.M.; Ahammed, Z.; Amonett,J.; Anderson, B.D.; Anderson, M.; Arkhipkin, D.; Averichev, G.S.; Bai,Y.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellingeri-Laurikainen, A.; Bellwied, R.; Benedosso, F.; Bhardwaj, S.; Bhasin, A.; Bhati, A.K.; Bichsel, H.; Bielcik, J.; Bielcikova, J.; Bland, L.C.; Blyth, S.-L.; Bonner, B.E.; Botje, M.; Bouchet, J.; Brandin, A.V.; Bravar, A.; Bystersky, M.; Cadman, R.V.; Cai,X.Z.; Caines, H.; Calderon de la Barca Sanchez, M.; Castillo, J.; Catu,O.; Cebra, D.; Chajecki, Z.; Chaloupka, P.; Chattopadhyay, S.; Chen,H.F.; Chen, J.H.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Cosentino, M.R.; Cramer, J.G.; Crawford,H.J.; Das, D.; Das, S.; Daugherity, M.; de Moura, M.M.; Dedovich, T.G.; DePhillips, M.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Djawotho,P.; Dogra, S.M.; Dong, W.J.; Dong, X.; Draper, J.E.; Du, F.; Dunin, V.B.; Dunlop, J.C.; Dutta Mazumdar, M.R.; Eckardt, V.; Edwards, W.R.; Efimov,L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Fatemi, R.; Fedorisin, J.; Filimonov, K.; Filip, P.; Finch,E.; Fine, V.; Fisyak, Y.; Fu, J.; Gagliardi, C.A.; Gaillard, L.; Ganti,M.S.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J.S.; Gorbunov, Y.G.; Gos,H.; Grebenyuk, O.; Grosnick, D.; Guertin, S.M.; Guimaraes, K.S.F.F.; Guo,Y.; Gupta, N.; Gutierrez, T.D.; Haag, B.; Hallman, T.J.; Hamed, A.; Harris, J.W.; He, W.; Heinz, M.; Henry, T.W.; Hepplemann, S.; Hippolyte,B.; Hirsch, A.; Hjort, E.; Hoffman, A.M.; Hoffmann, G.W.; Horner, M.J.; Huang, H.Z.; Huang, S.L.; Hughes, E.W.; Humanic, T.J.; Igo, G.; Jacobs,P.; Jacobs, W.W.; Jakl, P.; Jia, F.; Jiang, H.; Jones, P.G.; Judd, E.G.; Kabana, S.; Kang, K.; Kapitan, J.; Kaplan, M.; Keane, D.; Kechechyan, A.; Khodyrev,V.Yu.; Kim, B.C.; Kiryluk, J.; Kisiel, A.; Kislov, E.M.; Klein,S.R.; Kocoloski, A.; Koetke, D.D.; et al.

    2007-08-02

    The system created in non-central relativisticnucleus-nucleus collisions possesses large orbital angular momentum. Dueto spin-orbit coupling, particles produced in such a system could becomeglobally polarized along the direction of the system angular momentum. Wepresent the results of Lambda and anti-Lambda hyperon global polarizationmeasurements in Au+Au collisions at sqrt sNN=62.4 GeV and 200 GeVperformed with the STAR detector at RHIC. The observed globalpolarization of Lambda and anti-Lambda hyperons in the STAR acceptance isconsistent with zero within the precision of the measurements. Theobtained upper limit, lbar P Lambda, anti-Lambda rbar<= 0.02, iscompared to the theoretical values discussed recently in theliterature.

  4. d + Au hadron correlation measurements at PHENIX

    SciTech Connect

    Anne M. Sickles

    2014-05-13

    In these proceedings, we discuss recent results from d + Au collisions in PHENIX ridge related measurements and their possible hydrodynamic origin. We present the v2 at midrapidity and measurements of the pseudorapidity dependence of the ridge, distinguishing between the d-going and Au-going directions. We investigate the possible geometrical origin by comparing v2 in d + Au to that in p + Pb, Au + Au and Pb + Pb collisions. Future plans to clarify the role of geometry in small collision systems at RHIC are discussed.

  5. Synthesis and optical property characterization of elongated AuPt and Pt@Au metal nanoframes

    NASA Astrophysics Data System (ADS)

    Lee, Sangji; Jang, Hee-Jeong; Jang, Ho Young; Hong, Soonchang; Moh, Sang Hyun; Park, Sungho

    2016-02-01

    We report a facile method to synthesize elongated nanoframes consisting of Pt and Au in solution. Pentagonal Au nanorods served as templates and successfully led to an elongated AuPt nanoframe after etching the core Au. Subsequently, the coating of Au around Pt ridges resulted in Pt@Au metal nanoframes. The resulting elongated nanostructure exhibited 5 well-defined ridges continuously connected along the long axis. During the shape evolution from pure Au nanorods to elongated Pt@Au metal nanoframes, their corresponding localized surface plasmon resonance bands were monitored. Especially, unique surface plasmon features were observed for elongated Pt@Au nanoframes where the short-axis oscillation of surface free electrons is strongly coupled but the long-axis oscillation is not coupled among the ridges.We report a facile method to synthesize elongated nanoframes consisting of Pt and Au in solution. Pentagonal Au nanorods served as templates and successfully led to an elongated AuPt nanoframe after etching the core Au. Subsequently, the coating of Au around Pt ridges resulted in Pt@Au metal nanoframes. The resulting elongated nanostructure exhibited 5 well-defined ridges continuously connected along the long axis. During the shape evolution from pure Au nanorods to elongated Pt@Au metal nanoframes, their corresponding localized surface plasmon resonance bands were monitored. Especially, unique surface plasmon features were observed for elongated Pt@Au nanoframes where the short-axis oscillation of surface free electrons is strongly coupled but the long-axis oscillation is not coupled among the ridges. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr08200e

  6. Publicity and public relations

    NASA Technical Reports Server (NTRS)

    Fosha, Charles E.

    1990-01-01

    This paper addresses approaches to using publicity and public relations to meet the goals of the NASA Space Grant College. Methods universities and colleges can use to publicize space activities are presented.

  7. The magic gold cluster Au20

    NASA Astrophysics Data System (ADS)

    Kryachko, E. S.; Remacle, F.

    The 20-nanogold cluster Au20 exhibits a large variety of two- and three-dimensional isomeric forms. Among them is the ground-state isomer Au20(Td) representing the stable cluster with a unique tetrahedral shape, with all atoms on the surface, and large HOMO-LUMO gap which even slightly exceeds that of the buckyball fullerene C60. The anionic cluster Au-20(Td) that holds its parent tetrahedral symmetry features a high catalytic activity. The list of the properties of the 20-nanogold clusters surveyed in the present work ranges from the energetic order of stability of its isomers to the optical absorption and excitation spectra of the Au20(Td) cluster. We also report the structures and properties of its doubly charged clusters Au2+20 and Au2-20 and computationally confirm that Au2-20 is indeed stable. The zero-point-energy-corrected adiabatic second electron affinity of Au20(Td) amounts to 0.43-0.53 eV that is consistent with the experimental data. In addition, we provide computational evidence of the existence of the novel, hollow cage isomer of Au20 and analyze its key properties.0

  8. Synthesis and Optical Responses of Ag@Au/Ag@Au Double Shells

    NASA Astrophysics Data System (ADS)

    Li, Ying-Ying; Liu, Xiao-Li; Yang, Da-Jie; Hao, Zhong-Hua; Wang, Qu-Quan

    2015-02-01

    We synthesize hollow-structured Ag@Au nanoparticles with single porous shell and Ag@Au/Ag@Au double shells by using the galvanic replacement reaction and investigate their linear and nonlinear optical properties. Our results show that the surface plasmon resonance wavelength of the hollow porous nanoparticles could be easily tuned in a wide range in the visible and near infrared region by controlling the volume of HAuCl4. The nonlinear optical refraction of the double-shelled Ag@Au/Ag@Au nanoparticles is prominently enhanced by the plasmon resonance. Our findings may find applications in biosensors and nonlinear optical nanodevices.

  9. Au microstructure and the functional properties of Ni/Au finishes on ceramic IC packages

    SciTech Connect

    Winters, E.D.; Baxter, W.K.; Braski, D.N.; Watkins, T.R.

    1995-12-31

    Ni/Au plated finishes used on thick-film metallized multilayer ceramic packages for integrated circuits must meet functional requirements such as bondability, sealability, and solderability. Their ability to do so is dependent, among other things, on the ability of the Au deposit to inhibit the grain boundary diffusion and subsequent surface oxidation of Ni. In this study, the relation between functional performance, Ni diffusionr ate, and Au microstructure was examined. Extent of Ni diffusion during heating was determined by Auger electron spectroscopy for several electrolytic and electroless Ni/Au finishing processes. Results were correlated with differences in Au microstructures determined by SEM, atomic force microscopy, and XRD.

  10. Electrochemical formation of Au clusters in polyaniline

    SciTech Connect

    Hatchett, D.W.; Josowicz, M.; Janata, J.; Baer, D.R.

    1999-10-01

    The reduction of chloroaurate and the incorporation of Au clusters in polyaniline, PANI, films have been investigated. The chloroaurate complex is generated at the electrode surface during Cl{sup {minus}} doping of Au/PANI. FTIE and UV/vis data indicate that chloroaurate interacts with PANI and that its reduction to metallic Au occurs preferentially at the nitrogen linkages. The voltammetric and XPS results show that the uptake of both protons and anions is suppressed by the formation of Au clusters due to this interaction. The ability to reduce chloroaurate in PANI films is also demonstrated for Pt electrodes coated with PANI in solutions containing KAuCl{sub 4}. The preliminary results indicate that Au cluster size distribution remains fairly constant regardless of the method used.

  11. Polyethylene terephthalate (PET) bulk film analysis using C 60+, Au 3+, and Au + primary ion beams

    NASA Astrophysics Data System (ADS)

    Conlan, X. A.; Gilmore, I. S.; Henderson, A.; Lockyer, N. P.; Vickerman, J. C.

    2006-07-01

    The damage characteristics of polyethylene terephthalate (PET) have been studied under bombardment by C 60+, Au 3+ and Au + primary ions. The observed damage cross-sections for the three ion beams are not dramatically different. The secondary ion yields however were significantly enhanced by the polyatomic primary ions where the secondary ion yield of the [M + H] + is on average 5× higher for C 60+ than Au 3+ and 8× higher for Au 3+ than Au +. Damage accumulates under Au + and Au 3+ bombardment while C 60+ bombardment shows a lack of damage accumulation throughout the depth profile of the PET thick film up to an ion dose of ˜1 × 10 15 ions cm -2. These properties of C 60+ bombardment suggest that the primary ion will be a useful molecular depth profiling tool.

  12. Keeping Public Information Public.

    ERIC Educational Resources Information Center

    Kelley, Wayne P.

    1998-01-01

    Discusses the trend toward the transfer of federal government information from the public domain to the private sector. Topics include free access, privatization, information-policy revision, accountability, copyright issues, costs, pricing, and market needs versus public needs. (LRW)

  13. Investigation of the Phase Equilibria of Sn-Cu-Au Ternary and Ag-Sn-Cu-Au Quaternary Systems and Interfacial Reactions in Sn-Cu/Au Couples

    NASA Astrophysics Data System (ADS)

    Yen, Yee-Wen; Jao, Chien-Chung; Hsiao, Hsien-Ming; Lin, Chung-Yung; Lee, Chiapyng

    2007-02-01

    The phase equilibria of the Sn-Cu-Au ternary, Ag-Sn-Cu-Au quaternary systems and interfacial reactions between Sn-Cu alloys and Au were experimentally investigated at specific temperatures in this study. The experimental results indicated that there existed three ternary intermetallic compounds (IMCs) and a complete solid solubility between AuSn and Cu6Sn5 phases in the Sn-Cu-Au ternary system at 200°C. No quaternary IMC was found in the isoplethal section of the Ag-Sn-Cu-Au quaternary system. Three IMCs, AuSn, AuSn2, and AuSn4, were found in all couples. The same three IMCs and (Au,Cu)Sn/(Cu,Au)6Sn5 phases were found in all Sn-Cu/Au couples. The thickness of these reaction layers increased with increasing temperature and time. The mechanism of IMC growth can be described by using the parabolic law. In addition, when the reaction time was extended and the Cu content of the alloy was increased, the AuSn4 phase disappeared gradually. The (Au, Cu)Sn and (Cu,Au)6Sn5 layers played roles as diffusion barriers against Sn in Sn-Cu/Au reaction couple systems.

  14. Public Education, Public Good.

    ERIC Educational Resources Information Center

    Tomlinson, John

    1986-01-01

    Criticizes policies which would damage or destroy a public education system. Examines the relationship between government-provided education and democracy. Concludes that privatization of public education would emphasize self-interest and selfishness, further jeopardizing the altruism and civic mindedness necessary for the public good. (JDH)

  15. Thermal and photoinduced reduction of ionic Au(III) to elemental Au nanoparticles by dissolved organic matter in water: possible source of naturally occurring Au nanoparticles.

    PubMed

    Yin, Yongguang; Yu, Sujuan; Liu, Jingfu; Jiang, Guibin

    2014-01-01

    Naturally occurring Au nanoparticles (AuNPs) have been widely observed in ore deposits, coal, soil, and environmental water. Identifying the source of these naturally occurring AuNPs could be helpful for not only the discovery of Au deposits through advanced exploration methods, but also the elucidation of the biogeochemical cycle and environmental toxicity of ionic Au and engineered AuNPs. Here, we investigated the effect of natural/simulated sunlight and heating on the reduction of ionic Au by ubiquitous dissolved organic matter (DOM) in river water. The reductive process probed by X-ray photoelectron spectroscopy revealed that phenolic, alcoholic, and aldehyde groups in DOM act as reductive sites. Long-time exposure with thermal and photoirradiation induced the further fusion and growth of AuNPs to branched Au nanostructure as precipitation. The formation processes and kinetics of AuNPs were further investigated using humic acid (HA) as the DOM model, with comprehensive characterizing methods. We have observed that HA can reduce ionic Au(III) complex (as chloride or hydroxyl complex) to elemental Au nanoparticles under sunlight or heating. In this process, nearly all of the Au(III) could be reduced to AuNPs, in which HA serves as not only the reductive agent, but also the coating agent to stabilize and disperse AuNPs. The size and stability of AuNPs were highly dependent on the concentration ratio of Au(III) to HA. These results imply that, besides biological processes, this thermal or photochemical reduction process is another possible source of naturally occurring AuNPs in natural environments, which possibly has critical impacts on the transport and transformation of Au and engineered AuNPs.

  16. Self-assembly of thiolated cyanine aggregates on Au(111) and Au nanoparticle surfaces

    NASA Astrophysics Data System (ADS)

    Menéndez, Guillermo O.; Cortés, Emiliano; Grumelli, Doris; Méndez de Leo, Lucila P.; Williams, Federico J.; Tognalli, Nicolás G.; Fainstein, Alejandro; Vela, María Elena; Jares-Erijman, Elizabeth A.; Salvarezza, Roberto C.

    2012-01-01

    Heptamethinecyanine J-aggregates display sharp, intense fluorescence emission making them attractive candidates for developing a variety of chem-bio-sensing applications. They have been immobilized on planar thiol-covered Au surfaces and thiol-capped Au nanoparticles by weak molecular interactions. In this work the self-assembly of novel thiolated cyanine (CNN) on Au(111) and citrate-capped AuNPs from solutions containing monomers and J-aggregates has been studied by using STM, XPS, PM-IRRAS, electrochemical techniques and Raman spectroscopy. Data show that CNN species adsorb on the Au surfaces by forming thiolate-Au bonds. We found that the J-aggregates are preferentially adsorbed on the Au(111) surface directly from the solution while adsorbed CNN monomers cannot organize into aggregates on the substrate surface. These results indicate that the CNN-Au interaction is not able to disorganize the large J-aggregates stabilized by π-π stacking to optimize the S-Au binding site but it is strong enough to hinder the π-π stacking when CNNs are chemisorbed as monomers. The optical properties of the J-aggregates remain active after adsorption. The possibility of covalently bonding CNN J-aggregates to Au planar surfaces and Au nanoparticles controlling the J-aggregate/Au distance opens a new path regarding their improved stability and the wide range of biological applications of both CNN and AuNP biocompatible systems.Heptamethinecyanine J-aggregates display sharp, intense fluorescence emission making them attractive candidates for developing a variety of chem-bio-sensing applications. They have been immobilized on planar thiol-covered Au surfaces and thiol-capped Au nanoparticles by weak molecular interactions. In this work the self-assembly of novel thiolated cyanine (CNN) on Au(111) and citrate-capped AuNPs from solutions containing monomers and J-aggregates has been studied by using STM, XPS, PM-IRRAS, electrochemical techniques and Raman spectroscopy. Data show

  17. Controlled Synthesis of Au@AgAu Yolk-Shell Cuboctahedra with Well-Defined Facets.

    PubMed

    Londono-Calderon, Alejandra; Bahena, Daniel; Yacaman, Miguel J

    2016-08-01

    The synthesis of Au@AgAu yolk-shell cuboctahedra nanoparticles formed by galvanic replacement in a seed-mediated method is described. Initially, single-crystal Au seeds are used for the formation of Au@Ag core-shell nanocubes, which serve as the template material for the deposition of an external Au layer. The well-controlled synthesis yields the formation of cuboctahedra nanoparticles with smooth inner and outer Au/Ag surfaces. The deposition/oxidation process is described to understand the formation of cuboctahedra and octahedra nanoparticles. The Au core maintains the initial morphology of the seed and remains static at the center of the yolk-shell because of residual Ag. Structural analysis of the shell indicates intrinsic stacking faults (SFs) near the surface. Energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) compositional analysis show an Au-Ag nonordered alloy forming the shell. The three-dimensional structure of the nanoparticles presented open facets on the [111] as observed by electron tomography SIRT reconstruction over a stack of high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) images. The geometrical model was validated by analyzing the direction of streaks in coherent nanobeam diffraction (NBD). The catalytic activity was evaluated using a model reaction based on the reduction of 4-nitrophenol (4-NTP) by NaBH4 in the presence of Au@AgAu yolk-shell nanoparticles. PMID:27385583

  18. Au40: A Large Tetrahedral Magic Cluster

    SciTech Connect

    Jiang, Deen; Walter, Michael

    2011-01-01

    40 is a magic number for tetrahedral symmetry predicted in both nuclear physics and the electronic jellium model. We show that Au{sub 40} could be such a magic cluster from density functional theory-based basin hopping for global minimization. The putative global minimum found for Au{sub 40} has a twisted pyramid structure, reminiscent of the famous tetrahedral Au{sub 20}, and a sizable HOMO-LUMO gap of 0.69 eV, indicating its molecular nature. Analysis of the electronic states reveals that the gap is related to shell closings of the metallic electrons in a tetrahedrally distorted effective potential.

  19. Ir-induced activation of Au towards CO adsorption: Ir films deposited on Au{111}

    NASA Astrophysics Data System (ADS)

    Zhang, Tianfu; Driver, Stephen M.; Pratt, Stephanie J.; Jenkins, Stephen J.; King, David A.

    2016-06-01

    We have investigated the interaction of CO with Ir/Au{111} bimetallic surfaces, and the influence of morphology changes as Ir moves sub-surface into the Au bulk, using reflection-absorption infrared spectroscopy (RAIRS). The presence of Ir stabilises CO on exposed regions of the Au surface at temperatures up to around 200 K: we attribute this to low-coordinated Au sites, probably associated with lifting of the clean-surface 'herringbone' reconstruction by Ir deposition. The highest density of active Au sites is obtained after annealing the bimetallic surface to 500-600 K: we attribute this to morphology changes associated with the movement of Ir into bulk Au.

  20. Longitudinal scaling of net-protons in AuAu and pp collisions at RHIC energies

    NASA Astrophysics Data System (ADS)

    Videbaek, Flemming

    2008-10-01

    BRAHMS has studied net-protons distributions in Au+Au and p+p collisions at √sNN=62.4 and 200 GeV. Net-proton distributions reflect the net-baryon yields and can be used to extract the nuclear stopping in the collisions, thus providing information on baryon number transport and energy available for particle production. The talk will present final and preliminary results from the above mentioned systems. It will be shown that in p+p and in Au+Au central collisions that net-proton distributions exhibit longitudinal scaling once the target contribution to the projectile rapidity range is corrected for. The difference between p+p and Au+Au will be discussed. Aspects of future measurements at the LHC of net-baryons at mid-rapidity will be brought forth.

  1. Thermal Expansion of AuIn2

    SciTech Connect

    Saw, C K; Siekhaus, W J

    2004-07-12

    The thermal expansion of AuIn{sub 2} gold is of great interest in soldering technology. Indium containing solders have been used to make gold wire interconnects at low soldering temperature and over time, AuIn{sub 2} is formed between the gold wire and the solder due to the high heat of formation and the high inter-metallic diffusion of indium. Hence, the thermal expansion of AuIn{sub 2} alloy in comparison with that of the gold wire and the indium-containing solder is critical in determining the integrity of the connection. We present the results of x-ray diffraction measurement of the coefficient of linear expansion of AuIn{sub 2} as well as the bulk expansion and density changes over the temperature range of 30 to 500 C.

  2. RHIC Au beam in Run 2014

    SciTech Connect

    Zhang, S. Y.

    2014-09-15

    Au beam at the RHIC ramp in run 2014 is reviewed together with the run 2011 and run 2012. Observed bunch length and longitudinal emittance are compared with the IBS simulations. The IBS growth rate of the longitudinal emittance in run 2014 is similar to run 2011, and both are larger than run 2012. This is explained by the large transverse emittance at high intensity observed in run 2012, but not in run 2014. The big improvement of the AGS ramping in run 2014 might be related to this change. The importance of the injector intensity improvement in run 2014 is emphasized, which gives rise to the initial luminosity improvement of 50% in run 2014, compared with the previous Au-Au run 2011. In addition, a modified IBS model, which is calibrated using the RHIC Au runs from 9.8 GeV/n to 100 GeV/n, is presented and used in the study.

  3. Molecular dynamics simulation of energetic atom depositions of Au/Au(100) film

    NASA Astrophysics Data System (ADS)

    Qing-yu, Zhang; Zheng-ying, Pan; Jia-yong, Tang

    1999-04-01

    The energetic atom deposition of thin Au/Au(100) film has been studied by molecular dynamics simulation using the Au-Au interatomic interaction potential with embedded atom method. By investigating the variation of coverage curves and Bragg diffraction intensities during the film growth, the transition of Stranski-Kranstanov growth mode to Frank-van der Merwe growth mode was observed with the increase of the incident energy of deposition atoms. The role of energetic atoms in the film growth is discussed by analyzing the transport properties of deposited atoms and the evolution of incident energy and substrate temperatures.

  4. Unravelling Thiol's Role in Directing Asymmetric Growth of Au Nanorod-Au Nanoparticle Dimers.

    PubMed

    Huang, Jianfeng; Zhu, Yihan; Liu, Changxu; Shi, Zhan; Fratalocchi, Andrea; Han, Yu

    2016-01-13

    Asymmetric nanocrystals have practical significance in nanotechnologies but present fundamental synthetic challenges. Thiol ligands have proven effective in breaking the symmetric growth of metallic nanocrystals but their exact roles in the synthesis remain elusive. Here, we synthesized an unprecedented Au nanorod-Au nanoparticle (AuNR-AuNP) dimer structure with the assistance of a thiol ligand. On the basis of our experimental observations, we unraveled for the first time that the thiol could cause an inhomogeneous distribution of surface strains on the seed crystals as well as a modulated reduction rate of metal precursors, which jointly induced the asymmetric growth of monometallic dimers.

  5. Counterion-Mediated Assembly of Spherical Nucleic Acid-Au Nanoparticle Conjugates (SNA-AuNPs)

    NASA Astrophysics Data System (ADS)

    Kewalramani, Sumit; Moreau, Liane; Guerrero-García, Guillermo; Mirkin, Chad; Olvera de La Cruz, Monica; Bedzyk, Michael; Afosr Muri Team

    2015-03-01

    Controlled crystallization of colloids from solution has been a goal of material scientists for decades. Recently, nucleic acid functionalized spherical Au nanoparticles (SNA-AuNPs) have been programmed to assemble in a wide variety of crystal structures. In this approach, the assembly is driven by Watson-Crick hybridization between DNAs coating the AuNPs. Here, we show that counterions can induce ordered assembly of SNA-AuNPs in bulk solutions, even in the absence of base pairing interactions. The electrostatics-driven assembly of spherical nucleic acid-Au nanoparticle conjugates (SNA-AuNPs) is probed as a function of counterion concentration and counterion valency [ +1 (Na+) or +2 (Ca2+) ] by in situ solution X-ray scattering. Assemblies of AuNPs capped with single-stranded (ss-) or double-stranded (ds-) DNA are examined. SAXS reveals disordered (gas-like) --> face-centered-cubic (FCC) --> glass-like phase transitions with increasing solution ionic strength. These studies demonstrate how non-base-pairing interactions can be tuned to create crystalline assemblies of SNA-AuNPs. The dependence of the inter-SNA-AuNP interactions on counterion valency and stiffness of the DNA corona will be discussed.

  6. Kinetics of Phase Transformations in CuAu Alloys

    NASA Astrophysics Data System (ADS)

    Malis, O.; Ludwig, K.

    1997-03-01

    We have performed time resolved x-ray scattering studies of the kinetics of phase transformations in CuAu alloys. The equilibrium phase diagram of CuAu presents two first-order ordering transitions which separate the stability range of a high temperature disordered phase and two ordered phases: CuAuI and CuAuII. CuAuII is a modulated phase having a wavelength ten times larger than CuAuI. Our study focused on the competition between CuAuI and CuAuII as well as on the interaction between order and strain as the lattice changes from cubic in the disordered phase to tetragonal in CuAuI. During CuAuI formation from the disordered phase, CuAuII appears and persists even for quenches deep below the coexistence point of CuAuI and CuAuII. We have also found that the formation of CuAuI from CuAuII is considerably slower than the formation of CuAuI from the disordered phase for equal quench temperatures. Langevin simulations based on EMT are in good qualitative agreement with the x-ray results(Elder, Malis, Ludwig, Chakraborty, Goldenfeld in preparation.). With increasing quench depth we also observe a change in kinetics from an incoherent nucleation process to a continuous transformation of the lattice while ordering.

  7. Systematic Measurements of Identified Particle Spectra in pp, d+Au and Au+Au Collisions from STAR

    SciTech Connect

    STAR Coll

    2009-04-11

    Identified charged particle spectra of {pi}{sup {+-}}, K{sup {+-}}, p and {bar p} at mid-rapidity (|y| < 0.1) measured by the dE/dx method in the STAR-TPC are reported for pp and d + Au collisions at {radical}s{sub NN} = 200 GeV and for Au + Au collisions at 62.4 GeV, 130 GeV, and 200 GeV. Average transverse momenta, total particle production, particle yield ratios, strangeness and baryon production rates are investigated as a function of the collision system and centrality. The transverse momentum spectra are found to be flatter for heavy particles than for light particles in all collision systems; the effect is more prominent for more central collisions. The extracted average transverse momentum of each particle species follows a trend determined by the total charged particle multiplicity density. The Bjorken energy density estimate is at least several GeV/fm{sub 3} for a formation time less than 1 fm/c. A significantly larger net-baryon density and a stronger increase of the net-baryon density with centrality are found in Au + Au collisions at 62.4 GeV than at the two higher energies. Antibaryon production relative to total particle multiplicity is found to be constant over centrality, but increases with the collision energy. Strangeness production relative to total particle multiplicity is similar at the three measured RHIC energies. Relative strangeness production increases quickly with centrality in peripheral Au + Au collisions, to a value about 50% above the pp value, and remains rather constant in more central collisions. Bulk freeze-out properties are extracted from thermal equilibrium model and hydrodynamics-motivated blast-wave model fits to the data. Resonance decays are found to have little effect on the extracted kinetic freeze-out parameters due to the transverse momentum range of our measurements. The extracted chemical freeze-out temperature is constant, independent of collision system or centrality; its value is close to the predicted phase

  8. Fluctuations Magnetiques des Gaz D'electrons Bidimensionnels: Application AU Compose Supraconducteur LANTHANE(2-X) Strontium(x) Cuivre OXYGENE(4)

    NASA Astrophysics Data System (ADS)

    Benard, Pierre

    Nous presentons une etude des fluctuations magnetiques de la phase normale de l'oxyde de cuivre supraconducteur La_{2-x}Sr _{x}CuO_4 . Le compose est modelise par le Hamiltonien de Hubbard bidimensionnel avec un terme de saut vers les deuxiemes voisins (modele tt'U). Le modele est etudie en utilisant l'approximation de la GRPA (Generalized Random Phase Approximation) et en incluant les effets de la renormalisation de l'interaction de Hubbard par les diagrammes de Brueckner-Kanamori. Dans l'approche presentee dans ce travail, les maximums du facteur de structure magnetique observes par les experiences de diffusion de neutrons sont associes aux anomalies 2k _{F} de reseau du facteur de structure des gaz d'electrons bidimensionnels sans interaction. Ces anomalies proviennent de la diffusion entre particules situees a des points de la surface de Fermi ou les vitesses de Fermi sont tangentes, et conduisent a des divergences dont la nature depend de la geometrie de la surface de Fermi au voisinage de ces points. Ces resultats sont ensuite appliques au modele tt'U, dont le modele de Hubbard usuel tU est un cas particulier. Dans la majorite des cas, les interactions ne determinent pas la position des maximums du facteur de structure. Le role de l'interaction est d'augmenter l'intensite des structures du facteur de structure magnetique associees a l'instabilite magnetique du systeme. Ces structures sont souvent deja presentes dans la partie imaginaire de la susceptibilite sans interaction. Le rapport d'intensite entre les maximums absolus et les autres structures du facteur de structure magnetique permet de determiner le rapport U_ {rn}/U_{c} qui mesure la proximite d'une instabilite magnetique. Le diagramme de phase est ensuite etudie afin de delimiter la plage de validite de l'approximation. Apres avoir discute des modes collectifs et de l'effet d'une partie imaginaire non-nulle de la self-energie, l'origine de l'echelle d'energie des fluctuations magnetiques est examinee

  9. Suppression of ϒ production in d +Au and Au+Au collisions at √{sNN}=200 GeV

    NASA Astrophysics Data System (ADS)

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Alford, J.; Anson, C. D.; Aparin, A.; Arkhipkin, D.; Aschenauer, E. C.; Averichev, G. S.; Balewski, J.; Banerjee, A.; Barnovska, Z.; Beavis, D. R.; Bellwied, R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bichsel, H.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Borowski, W.; Bouchet, J.; Brandin, A. V.; Brovko, S. G.; Bültmann, S.; Bunzarov, I.; Burton, T. P.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Cebra, D.; Cendejas, R.; Cervantes, M. C.; Chaloupka, P.; Chang, Z.; Chattopadhyay, S.; Chen, H. F.; Chen, J. H.; Chen, L.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Chwastowski, J.; Codrington, M. J. M.; Corliss, R.; Cramer, J. G.; Crawford, H. J.; Cui, X.; Das, S.; Davila Leyva, A.; De Silva, L. C.; Debbe, R. R.; Dedovich, T. G.; Deng, J.; Derevschikov, A. A.; Derradi de Souza, R.; Dhamija, S.; di Ruzza, B.; Didenko, L.; Dilks, C.; Ding, F.; Djawotho, P.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Du, C. M.; Dunkelberger, L. E.; Dunlop, J. C.; Efimov, L. G.; Engelage, J.; Engle, K. S.; Eppley, G.; Eun, L.; Evdokimov, O.; Fatemi, R.; Fazio, S.; Fedorisin, J.; Filip, P.; Finch, E.; Fisyak, Y.; Flores, C. E.; Gagliardi, C. A.; Gangadharan, D. R.; Garand, D.; Geurts, F.; Gibson, A.; Girard, M.; Gliske, S.; Grosnick, D.; Guo, Y.; Gupta, A.; Gupta, S.; Guryn, W.; Haag, B.; Hajkova, O.; Hamed, A.; Han, L.-X.; Haque, R.; Harris, J. W.; Hays-Wehle, J. P.; Heppelmann, S.; Hill, K.; Hirsch, A.; Hoffmann, G. W.; Hofman, D. J.; Horvat, S.; Huang, B.; Huang, H. Z.; Huck, P.; Humanic, T. J.; Igo, G.; Jacobs, W. W.; Jang, H.; Judd, E. G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Kesich, A.; Khan, Z. H.; Kikola, D. P.; Kisel, I.; Kisiel, A.; Koetke, D. D.; Kollegger, T.; Konzer, J.; Koralt, I.; Korsch, W.; Kotchenda, L.; Kravtsov, P.; Krueger, K.; Kulakov, I.; Kumar, L.; Kycia, R. A.; Lamont, M. A. C.; Landgraf, J. M.; Landry, K. D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; Leight, W.; LeVine, M. J.; Li, C.; Li, W.; Li, X.; Li, X.; Li, Y.; Li, Z. M.; Lima, L. M.; Lisa, M. A.; Liu, F.; Ljubicic, T.; Llope, W. J.; Longacre, R. S.; Luo, X.; Ma, G. L.; Ma, Y. G.; Madagodagettige Don, D. M. M. D.; Mahapatra, D. P.; Majka, R.; Margetis, S.; Markert, C.; Masui, H.; Matis, H. S.; McDonald, D.; McShane, T. S.; Minaev, N. G.; Mioduszewski, S.; Mohanty, B.; Mondal, M. M.; Morozov, D. A.; Munhoz, M. G.; Mustafa, M. K.; Nandi, B. K.; Nasim, Md.; Nayak, T. K.; Nelson, J. M.; Nogach, L. V.; Noh, S. Y.; Novak, J.; Nurushev, S. B.; Odyniec, G.; Ogawa, A.; Oh, K.; Ohlson, A.; Okorokov, V.; Oldag, E. W.; Oliveira, R. A. N.; Pachr, M.; Page, B. S.; Pal, S. K.; Pan, Y. X.; Pandit, Y.; Panebratsev, Y.; Pawlak, T.; Pawlik, B.; Pei, H.; Perkins, C.; Peryt, W.; Peterson, A.; Pile, P.; Planinic, M.; Pluta, J.; Plyku, D.; Poljak, N.; Porter, J.; Poskanzer, A. M.; Pruthi, N. K.; Przybycien, M.; Pujahari, P. R.; Qiu, H.; Quintero, A.; Ramachandran, S.; Raniwala, R.; Raniwala, S.; Ray, R. L.; Riley, C. K.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Ross, J. F.; Roy, A.; Ruan, L.; Rusnak, J.; Sahoo, N. R.; Sahu, P. K.; Sakrejda, I.; Salur, S.; Sandacz, A.; Sandweiss, J.; Sangaline, E.; Sarkar, A.; Schambach, J.; Scharenberg, R. P.; Schmah, A. M.; Schmidke, W. B.; Schmitz, N.; Seger, J.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P. V.; Shao, M.; Sharma, B.; Shen, W. Q.; Shi, S. S.; Shou, Q. Y.; Sichtermann, E. P.; Singaraju, R. N.; Skoby, M. J.; Smirnov, D.; Smirnov, N.; Solanki, D.; Sorensen, P.; deSouza, U. G.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Stevens, J. R.; Stock, R.; Strikhanov, M.; Stringfellow, B.; Suaide, A. A. P.; Sumbera, M.; Sun, X.; Sun, X. M.; Sun, Y.; Sun, Z.; Surrow, B.; Svirida, D. N.; Symons, T. J. M.; Szanto de Toledo, A.; Takahashi, J.; Tang, A. H.; Tang, Z.; Tarnowsky, T.; Thomas, J. H.; Timmins, A. R.; Tlusty, D.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Trzeciak, B. A.; Tsai, O. D.; Turnau, J.; Ullrich, T.; Underwood, D. G.; Van Buren, G.; van Nieuwenhuizen, G.; Vanfossen, J. A.; Varma, R.; Vasconcelos, G. M. S.; Vasiliev, A. N.; Vertesi, R.; Videbæk, F.; Viyogi, Y. P.; Vokal, S.; Vossen, A.; Wada, M.; Walker, M.; Wang, F.; Wang, G.; Wang, H.; Wang, J. S.; Wang, X. L.; Wang, Y.; Wang, Y.; Webb, G.; Webb, J. C.; Westfall, G. D.; Wieman, H.; Wimsatt, G.; Wissink, S. W.; Witt, R.; Wu, Y. F.; Xiao, Z.; Xie, W.; Xin, K.; Xu, H.; Xu, N.; Xu, Q. H.; Xu, Y.; Xu, Z.; Yan, W.; Yang, C.; Yang, Y.; Yang, Y.; Ye, Z.; Yepes, P.; Yi, L.; Yip, K.; Yoo, I.-K.; Zawisza, Y.; Zbroszczyk, H.; Zha, W.; Zhang, J. B.; Zhang, J. L.; Zhang, S.; Zhang, X. P.; Zhang, Y.; Zhang, Z. P.; Zhao, F.; Zhao, J.; Zhong, C.; Zhu, X.; Zhu, Y. H.; Zoulkarneeva, Y.; Zyzak, M.

    2014-07-01

    We report measurements of ϒ meson production in p + p, d +Au, and Au +Au collisions using the STAR detector at RHIC. We compare the ϒ yield to the measured cross section in p + p collisions in order to quantify any modifications of the yield in cold nuclear matter using d +Au data and in hot nuclear matter using Au +Au data separated into three centrality classes. Our p + p measurement is based on three times the statistics of our previous result. We obtain a nuclear modification factor for ϒ (1 S + 2 S + 3 S) in the rapidity range | y | < 1 in d +Au collisions of RdAu = 0.79 ± 0.24 (stat.) ± 0.03 (syst.) ± 0.10 (p + p syst.). A comparison with models including shadowing and initial state parton energy loss indicates the presence of additional cold-nuclear matter suppression. Similarly, in the top 10% most-central Au +Au collisions, we measure a nuclear modification factor of RAA = 0.49 ± 0.1 (stat.) ± 0.02 (syst.) ± 0.06 (p + psyst.), which is a larger suppression factor than that seen in cold nuclear matter. Our results are consistent with complete suppression of excited-state ϒ mesons in Au +Au collisions. The additional suppression in Au +Au is consistent with the level expected in model calculations that include the presence of a hot, deconfined Quark-Gluon Plasma. However, understanding the suppression seen in d +Au is still needed before any definitive statements about the nature of the suppression in Au +Au can be made.

  10. 100-MeV proton beam intensity measurement by Au activation analysis using 197Au(p, pn)196Au and 197Au(p, p3n)194Au reactions

    NASA Astrophysics Data System (ADS)

    Mokhtari Oranj, Leila; Jung, Nam-Suk; Oh, Joo-Hee; Lee, Hee-Seock

    2016-05-01

    The proton beam intensity of a 100-MeV proton linac at the Korea Multi-purpose Accelerator Complex (KOMAC) was measured by an Au activation analysis using 197Au(p, pn)196Au and 197Au(p, p3n)194Au reactions to determine the accuracy and precision of beam intensity measurement using Gafchromic film dosimetry method. The target, irradiated by 100-MeV protons, was arranged in a stack consisting of Au, Al foils and Pb plates. The yields of produced radio-nuclei in Au foils were obtained by gamma-ray spectroscopy. The FLUKA code was employed to calculate the energy spectrum of protons onto the front surface of Au foils located at three different depth points of the target and also to investigate the condition of incident beam on the target. A good agreement was found between the beam intensity measurements using the activation analysis method at three different depth points of the target. An excellent agreement was also observed between the beam intensity measurements using the Au activation analysis method and the dosimetry method using Gafchromic film.

  11. Electrochemical Characterization of Protein Adsorption onto YNGRT-Au and VLGXE-Au Surfaces

    PubMed Central

    Trzeciakiewicz, Hanna; Esteves-Villanueva, Jose; Soudy, Rania; Kaur, Kamaljit; Martic-Milne, Sanela

    2015-01-01

    The adsorption of the proteins CD13, mucin and bovine serum albumin on VLGXE-Au and YNGRT-Au interfaces was monitored by electrochemical impedance spectroscopy in the presence of [Fe(CN)6]3−/4−. The hydrophobicity of the Au surface was tailored using specific peptides, blocking agents and diluents. The combination of blocking agents (ethanolamine or n-butylamine) and diluents (hexanethiol or 2-mercaptoethanol) was used to prepare various peptide-modified Au surfaces. Protein adsorption onto the peptide-Au surfaces modified with the combination of n-butylamine and hexanethiol produced a dramatic decrease in the charge transfer resistance, Rct, for all three proteins. In contrast, polar peptide-surfaces induced a minimal change in Rct for all three proteins. Furthermore, an increase in Rct was observed with CD13 (an aminopeptidase overexpressed in certain cancers) in comparison to the other proteins when the VLGXE-Au surface was modified with n-butylamine as a blocking agent. The electrochemical data indicated that protein adsorption may be modulated by tailoring the peptide sequence on Au surfaces and that blocking agents and diluents play a key role in promoting or preventing protein adsorption. The peptide-Au platform may also be used for targeting cancer biomarkers with designer peptides. PMID:26262621

  12. Using supported Au nanoparticles as starting material for preparing uniform Au/Pd bimetallic catalysts

    SciTech Connect

    Villa, Alberto; Prati, Laura; Su, Dangshen; Wang, Di; Veith, Gabriel M

    2010-01-01

    One of the best methods for producing bulk homogeneous (composition) supported bimetallic AuPd clusters involves the immobilization of a protected Au seed followed by the addition of Pd. This paper investigates the importance of this gold seed in controlling the resulting bimetallic AuPd clusters structures, sizes and catalytic activities by investigating three different gold seeds. Uniform Au-Pd alloy were obtained when a steric/electrostatic protecting group, poly(vinyl alcohol) (PVA), was used to form the gold clusters on activated carbon (AC). In contrast Au/AC precursors prepared using Au nanoparticles with only electrostatic stabilization (tetrakis(hydroxypropyl)phosphonium chloride (THPC)), or no stabilization (magnetron sputtering) produced inhomogeneous alloys and segregation of the gold and palladium. The uniform alloyed catalyst (Pd{at}Au{sub PVA}/AC) is the most active and selective catalyst, while the inhomogenous catalysts are less active and selective. Further study of the PVA protected Au clusters revealed that the amount of PVA used is also critical for the preparation of uniform alloyed catalyst, their stability, and their catalytic activity.

  13. The extraction characteristic of Au-Ag from Au concentrate by thiourea solution

    NASA Astrophysics Data System (ADS)

    Kim, Bongju; Cho, Kanghee; On, Hyunsung; Choi, Nagchoul; Park, Cheonyoung

    2013-04-01

    The cyanidation process has been used commercially for the past 100 years, there are ores that are not amenable to treatment by cyanide. Interest in alternative lixiviants, such as thiourea, halogens, thiosulfate and malononitrile, has been revived as a result of a major increase in gold price, which has stimulated new developments in extraction technology, combined with environmental concern. The Au extraction process using the thiourea solvent has many advantages over the cyanidation process, including higher leaching rates, faster extraction time and less than toxicity. The purpose of this study was investigated to the extraction characteristic of Au-Ag from two different Au concentrate (sulfuric acid washing and roasting) under various experiment conditions (thiourea concentration, pH of solvent, temperature) by thiourea solvent. The result of extraction experiment showed that the Au-Ag extraction was a fast extraction process, reaching equilibrium (maximum extraction rate) within 30 min. The Au-Ag extraction rate was higher in the roasted concentrate than in the sulfuric acid washing. The higher the Au-Ag extraction rate (Au - 70.87%, Ag - 98.12%) from roasted concentrate was found when the more concentration of thiourea increased, pH decreased and extraction temperature increased. This study informs extraction method basic knowledge when thiourea was a possibility to eco-/economic resources of Au-Ag utilization studies including the hydrometallurgy.

  14. Adsorbate-modified Electron Relaxation in Au-Au_2S Nanoshells

    NASA Astrophysics Data System (ADS)

    Westcott, Sarah; Averitt, Richard; Wolfgang, John; Nordlander, Peter; Halas, Naomi

    2001-03-01

    Au-Au_2S nanoshells are 50 nm nanoparticles consisting of an Au_2S core encapsulated by a thin (<5 nm) Au shell. Their optical properties are determined by the metallic shell layer, whose inner and outer radii control plasmon frequency and whose thickness determines plasmon linewidth[1]. We studied the time-resolved relaxation of hot electrons in the Au shell, using degenerate pump-probe spectroscopy. The electron relaxation for nanoshells in solution was appreciably slower than relaxation for bulk gold, moreover, adsorbed molecules on the nanoshell surface strongly modify this relaxation. Density functional theory calculations indicate that the molecules providing the strongest modification of relaxation possess the largest induced dipole moments above a metal surface, indicating that the adsorbate-induced perturbation of the nanoshell electron dynamics appears to be primarily electronic in nature. [1] R. D. Averitt, D. Sarkar and N. J. Halas, Phys. Rev. Lett. 78, 4217 (1997).

  15. Odd-Even Pattern Observed in Polyaniline/(Au0 – Au8) Composites

    SciTech Connect

    Jonke, Alex P.; Josowicz, Mira A.; Janata, Jiri

    2012-01-12

    Theoretically predicted effect of odd-even pattern of electron pairing on behavior of gold clusters in polyaniline/AuN (N = 0 to 8) has been confirmed experimentally. In these composites the atomic Au clusters with even number of atoms exhibit higher catalytic activity for electrochemical oxidation of n-propanol in 1 M NaOH than the odd-number atoms clusters. Also, infrared spectroscopy shows that even numbered PANI/AuN composites affect the N-H stretching vibration more strongly than the corresponding odd numbered ones. This behavior matches the theoretically predicted variations of HOMO-LUMO gap energy and the stability of the atomic Au clusters. It also agrees with the earlier experimental work in which the UPS spectra of isolated, mass-selected Au clusters have been reported.

  16. Jets and dijets in Au+Au and p+p collisions at RHIC

    SciTech Connect

    Hardtke, D.; STAR Collaboration

    2002-12-09

    Recent data from RHIC suggest novel nuclear effects in the production of high p{sub T} hadrons. We present results from the STAR detector on high p{sub T} angular correlations in Au+Au and p+p collisions at {radical}S = 200 GeV/c. These two-particle angular correlation measurements verify the presence of a partonic hard scattering and fragmentation component at high p{sub T} in both central and peripheral Au+Au collisions. When triggering on a leading hadron with p{sub T}>4 GeV, we observe a quantitative agreement between the jet cone properties in p+p and all centralities of Au+Au collisions. This quantitative agreement indicates that nearly all hadrons with p{sub T}>4 GeV/c come from jet fragmentation and that jet fragmentation properties are not substantially modified in Au+Au collisions. STAR has also measured the strength of back-to-back high p{sub T} charged hadron correlations, and observes a small suppression of the back-to-back correlation strength in peripheral collisions, and a nearly complete disappearance o f back-to-back correlations in central Au+Au events. These phenomena, together with the observed strong suppression of inclusive yields and large value of elliptic flow at high p{sub T}, are consistent with a model where high p{sub T} hadrons come from partons created near the surface of the collision region, and where partons that originate or propagate towards the center of the collision region are substantially slowed or completely absorbed.

  17. Spectra and ratios of identified particles in Au+Au and d+Au collisions at sNN=200 GeV

    NASA Astrophysics Data System (ADS)

    Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Al-Bataineh, H.; Alexander, J.; Angerami, A.; Aoki, K.; Apadula, N.; Aramaki, Y.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Bai, M.; Baksay, G.; Baksay, L.; Barish, K. N.; Bassalleck, B.; Basye, A. T.; Bathe, S.; Baublis, V.; Baumann, C.; Bazilevsky, A.; Belikov, S.; Belmont, R.; Bennett, R.; Berdnikov, A.; Berdnikov, Y.; Bhom, J. H.; Bickley, A. A.; Blau, D. S.; Bok, J. S.; Boyle, K.; Brooks, M. L.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Butsyk, S.; Camacho, C. M.; Campbell, S.; Caringi, A.; Chen, C.-H.; Chi, C. Y.; Chiu, M.; Choi, I. J.; Choi, J. B.; Choudhury, R. K.; Christiansen, P.; Chujo, T.; Chung, P.; Chvala, O.; Cianciolo, V.; Citron, Z.; Cole, B. A.; Conesa del Valle, Z.; Connors, M.; Constantin, P.; Csanád, M.; Csörgő, T.; Dahms, T.; Dairaku, S.; Danchev, I.; Das, K.; Datta, A.; David, G.; Dayananda, M. K.; Denisov, A.; Deshpande, A.; Desmond, E. J.; Dharmawardane, K. V.; Dietzsch, O.; Dion, A.; Donadelli, M.; Drapier, O.; Drees, A.; Drees, K. A.; Durham, J. M.; Durum, A.; Dutta, D.; D'Orazio, L.; Edwards, S.; Efremenko, Y. V.; Ellinghaus, F.; Engelmore, T.; Enokizono, A.; En'yo, H.; Esumi, S.; Fadem, B.; Fields, D. E.; Finger, M.; Finger, M., Jr.; Fleuret, F.; Fokin, S. L.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fujiwara, K.; Fukao, Y.; Fusayasu, T.; Garishvili, I.; Glenn, A.; Gong, H.; Gonin, M.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grim, G.; Grosse Perdekamp, M.; Gunji, T.; Gustafsson, H.-Å.; Haggerty, J. S.; Hahn, K. I.; Hamagaki, H.; Hamblen, J.; Han, R.; Hanks, J.; Hartouni, E. P.; Haslum, E.; Hayano, R.; He, X.; Heffner, M.; Hemmick, T. K.; Hester, T.; Hill, J. C.; Hohlmann, M.; Holzmann, W.; Homma, K.; Hong, B.; Horaguchi, T.; Hornback, D.; Huang, S.; Ichihara, T.; Ichimiya, R.; Ide, J.; Ikeda, Y.; Imai, K.; Inaba, M.; Isenhower, D.; Ishihara, M.; Isobe, T.; Issah, M.; Isupov, A.; Ivanischev, D.; Iwanaga, Y.; Jacak, B. V.; Jia, J.; Jiang, X.; Jin, J.; Johnson, B. M.; Jones, T.; Joo, K. S.; Jouan, D.; Jumper, D. S.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kamin, J.; Kang, J. H.; Kapustinsky, J.; Karatsu, K.; Kasai, M.; Kawall, D.; Kawashima, M.; Kazantsev, A. V.; Kempel, T.; Khanzadeev, A.; Kijima, K. M.; Kikuchi, J.; Kim, A.; Kim, B. I.; Kim, D. H.; Kim, D. J.; Kim, E.; Kim, E.-J.; Kim, S. H.; Kim, Y.-J.; Kinney, E.; Kiriluk, K.; Kiss, Á.; Kistenev, E.; Kleinjan, D.; Kochenda, L.; Komkov, B.; Konno, M.; Koster, J.; Kotchetkov, D.; Kozlov, A.; Král, A.; Kravitz, A.; Kunde, G. J.; Kurita, K.; Kurosawa, M.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lai, Y. S.; Lajoie, J. G.; Lebedev, A.; Lee, D. M.; Lee, J.; Lee, K.; Lee, K. B.; Lee, K. S.; Leitch, M. J.; Leite, M. A. L.; Leitner, E.; Lenzi, B.; Li, X.; Lichtenwalner, P.; Liebing, P.; Linden Levy, L. A.; Liška, T.; Litvinenko, A.; Liu, H.; Liu, M. X.; Love, B.; Luechtenborg, R.; Lynch, D.; Maguire, C. F.; Makdisi, Y. I.; Malakhov, A.; Malik, M. D.; Manko, V. I.; Mannel, E.; Mao, Y.; Masui, H.; Matathias, F.; McCumber, M.; McGaughey, P. L.; McGlinchey, D.; Means, N.; Meredith, B.; Miake, Y.; Mibe, T.; Mignerey, A. C.; Mikeš, P.; Miki, K.; Milov, A.; Mishra, M.; Mitchell, J. T.; Mohanty, A. K.; Moon, H. J.; Morino, Y.; Morreale, A.; Morrison, D. P.; Moukhanova, T. V.; Murakami, T.; Murata, J.; Nagamiya, S.; Nagle, J. L.; Naglis, M.; Nagy, M. I.; Nakagawa, I.; Nakamiya, Y.; Nakamura, K. R.; Nakamura, T.; Nakano, K.; Nam, S.; Newby, J.; Nguyen, M.; Nihashi, M.; Nouicer, R.; Nyanin, A. S.; Oakley, C.; O'Brien, E.; Oda, S. X.; Ogilvie, C. A.; Oka, M.; Okada, K.; Onuki, Y.; Oskarsson, A.; Ouchida, M.; Ozawa, K.; Pak, R.; Pantuev, V.; Papavassiliou, V.; Park, I. H.; Park, J.; Park, S. K.; Park, W. J.; Pate, S. F.; Pei, H.; Peng, J.-C.; Pereira, H.; Peresedov, V.; Peressounko, D. Yu.; Petti, R.; Pinkenburg, C.; Pisani, R. P.; Proissl, M.; Purschke, M. L.; Purwar, A. K.; Qu, H.; Rak, J.; Rakotozafindrabe, A.; Ravinovich, I.; Read, K. F.; Rembeczki, S.; Reygers, K.; Riabov, V.; Riabov, Y.; Richardson, E.; Roach, D.; Roche, G.; Rolnick, S. D.; Rosati, M.; Rosen, C. A.; Rosendahl, S. S. E.; Rosnet, P.; Rukoyatkin, P.; Ružička, P.; Sahlmueller, B.; Saito, N.; Sakaguchi, T.; Sakashita, K.; Samsonov, V.; Sano, S.; Sato, T.; Sawada, S.; Sedgwick, K.; Seele, J.; Seidl, R.; Semenov, A. Yu.; Seto, R.; Sharma, D.; Shein, I.; Shibata, T.-A.; Shigaki, K.; Shimomura, M.; Shoji, K.; Shukla, P.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Silvestre, C.; Sim, K. S.; Singh, B. K.; Singh, C. P.; Singh, V.; Slunečka, M.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Sourikova, I. V.; Sparks, N. A.; Stankus, P. W.; Stenlund, E.; Stoll, S. P.; Sugitate, T.; Sukhanov, A.; Sziklai, J.; Takagui, E. M.; Taketani, A.; Tanabe, R.; Tanaka, Y.; Taneja, S.; Tanida, K.; Tannenbaum, M. J.; Tarafdar, S.; Taranenko, A.; Tarján, P.; Themann, H.; Thomas, D.; Thomas, T. L.; Togawa, M.; Toia, A.; Tomášek, L.; Torii, H.; Towell, R. S.; Tserruya, I.; Tsuchimoto, Y.; Vale, C.; Valle, H.; van Hecke, H. W.; Vazquez-Zambrano, E.; Veicht, A.; Velkovska, J.; Vértesi, R.; Vinogradov, A. A.; Virius, M.; Vrba, V.; Vznuzdaev, E.; Wang, X. R.; Watanabe, D.; Watanabe, K.; Watanabe, Y.; Wei, F.; Wei, R.; Wessels, J.; White, S. N.; Winter, D.; Wood, J. P.; Woody, C. L.; Wright, R. M.; Wysocki, M.; Xie, W.; Yamaguchi, Y. L.; Yamaura, K.; Yang, R.; Yanovich, A.; Ying, J.; Yokkaichi, S.; You, Z.; Young, G. R.; Younus, I.; Yushmanov, I. E.; Zajc, W. A.; Zhang, C.; Zhou, S.; Zolin, L.

    2013-08-01

    The transverse momentum (pT) spectra and ratios of identified charged hadrons (π±, K±, p, p¯) produced in sNN=200 GeV Au+Au and d+Au collisions are reported in five different centrality classes for each collision species. The measurements of pions and protons are reported up to pT=6 GeV/c (5 GeV/c), and the measurements of kaons are reported up to pT=4 GeV/c (3.5 GeV/c) in Au+Au (d+Au) collisions. In the intermediate pT region, between 2 and 5 GeV/c, a significant enhancement of baryon-to-meson ratios compared to those measured in p+p collisions is observed. This enhancement is present in both Au+Au and d+Au collisions and increases as the collisions become more central. We compare a class of peripheral Au+Au collisions with a class of central d+Au collisions which have a comparable number of participating nucleons and binary nucleon-nucleon collisions. The pT-dependent particle ratios for these classes display a remarkable similarity, which is then discussed.

  18. Synthesis and characterization in AuCu–Si nanostructures

    SciTech Connect

    Novelo, T.E.; Amézaga-Madrid, P.; Maldonado, R.D.; Oliva, A.I.; Alonzo-Medina, G.M.

    2015-03-15

    Au/Cu bilayers with different Au:Cu concentrations (25:75, 50:50 and 75:25 at.%) were deposited on Si(100) substrates by thermal evaporation. The thicknesses of all Au/Cu bilayers were 150 nm. The alloys were prepared by thermal diffusion into a vacuum oven with argon atmosphere at 690 K during 1 h. X-ray diffraction analysis revealed different phases of AuCu and CuSi alloys in the samples after annealing process. CuSi alloys were mainly obtained for 25:75 at.% samples, meanwhile the AuCuII phase dominates for samples prepared with 50:50 at.%. Additionally, the Au:Cu alloys with 75:25 at.%, produce Au{sub 2}Cu{sub 3} and Au{sub 3}Cu phases. The formed alloys were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM), transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) to study the morphology and the elemental concentration of the formed alloys. - Highlights: • AuCu/Si alloy thin films were prepared by thermal diffusion. • Alloys prepared with 50 at.% of Au produce the AuCuII phase. • Alloys prepared with 75 at.% of Au produce Au{sub 3}Cu and Au{sub 2}Cu{sub 3} phases. • All alloys present diffusion of Si and Cu through the CuSi alloy formation.

  19. Au nanoparticles films used in biological sensing

    NASA Astrophysics Data System (ADS)

    Rosales Pérez, M.; Delgado Macuil, R.; Rojas López, M.; Gayou, V. L.; Sánchez Ramírez, J. F.

    2009-05-01

    Lactobacillus para paracasei are used commonly as functional food and probiotic substances. In this work Au nanoparticles self-assembled films were used for Lactobacillus para paracasei determination at five different concentrations. Functionalized substrates were immersed in a colloidal solution for one and a half hour at room temperature and dried at room temperature during four hours. After that, drops of Lactobacillus para paracasei in aqueous solution were put into the Au nanoparticles film and let dry at room temperature for another two hours. Infrared spectroscopy in attenuated total reflectance sampling mode was used to observe generation peaks due to substrate silanization, enhancement of Si-O band intensity due to the Au colloids added to silanized substrate and also to observe the enhancement of Lactobacillus para paracasei infrared intensity of the characteristic frequencies at 1650, 1534 and 1450 cm-1 due to surface enhancement infrared absorption.

  20. A velocity map imaging study of gold-rare gas complexes: Au-Ar, Au-Kr, and Au-Xe

    NASA Astrophysics Data System (ADS)

    Hopkins, W. Scott; Woodham, Alex P.; Plowright, Richard J.; Wright, Timothy G.; Mackenzie, Stuart R.

    2010-06-01

    The ultraviolet photodissociation dynamics of the gold-rare gas atom van der Waals complexes (Au-RG, RG=Ar, Kr, and Xe) have been studied by velocity map imaging. Photofragmentation of Au-Ar and Au-Kr at several wavelengths permits extrapolation to zero of the total kinetic energy release (TKER) spectra as monitored in the Au(P23/2∘[5d106p]) fragment channel, facilitating the determination of ground state dissociation energies of D0″(Au-Ar)=149±13 cm-1 and D0″(Au-Kr)=240±19 cm-1, respectively. In the same spectral region, transitions to vibrational levels of an Ω'=1/2 state of the Au-Xe complex result in predissociation to the lower Au(P21/2∘[5d106p])+Xe(S10[5p6]) fragment channel for which TKER extrapolation yields a value of D0″(Au-Xe)=636±27 cm-1. Asymmetric line shapes for transitions to the v'=14 level of this state indicate coupling to the Au(P23/2∘[5d106p])+Xe(S10[5p6]) continuum, which allows us to refine this value to D0″(Au-Xe)=607±5 cm-1. The dissociation dynamics of this vibrational level have been studied at the level of individual isotopologues by fitting the observed excitation spectra to Fano profiles. These fits reveal a remarkable variation in the predissociation dynamics for different Au-Xe isotopologues. For Au-Ar and Au-Xe, the determined ground state dissociation energies are in good agreement with recent theoretical calculations; the agreement of the Au-Kr value with theory is less satisfactory.

  1. Antiproton distributions in Au+nucleus collisions

    SciTech Connect

    Beavis, D.; Debbe, R.; Bennett, M.J.; Chikanian, A.; Kumar, B.S.; Nagle, J.L.; Pope, J.K.; Carroll, J.B.; Hallman, T.J.; Chiba, J.; Tanaka, K.H.; Crawford, H.J.; Cronqvist, M.; Dardenne, Y.; Engelage, J.; Greiner, L.; Kuo, C.; Doke, T.; Kashiwagi, T.; Kikuchi, J.; Hayano, R.S.; Heckman, H.H.; Lindstrom, P.J.; Mitchell, J.W.; Welsh, R.C.

    1997-09-01

    Experiment E878 at the BNL-AGS has measured the invariant cross sections of antiprotons produced near p{sub t}=0 in interactions of 10.8 GeV/c Au beams with targets of Al, Cu, and Au. The data were measured for a wide range of centralities and rapidities using a focusing beamline spectrometer and a high-rate centrality detector. We compare our data with the predictions of simple models and sophisticated transport models to explore the physics of antiproton production and annihilation. {copyright} {ital 1997} {ital The American Physical Society}

  2. The role of interfaces in the magnetoresistance of Au/Fe/Au/Fe/GaAs(001)

    SciTech Connect

    Enders, A.; Monchesky, T. L.; Myrtle, K.; Urban, R.; Heinrich, B.; Kirschner, J.; Zhang, X.-G.; Butler, W. H.

    2001-06-01

    The electron transport and magnetoresistance (MR) were investigated in high quality crystalline epitaxial Fe(001) and Au(001) films and exchange coupled Au/Fe/Au/Fe/GaAs(001) trilayer structures. Fits to the experimental data were based on the semiclassical Boltzmann equation, which incorporates the electronic properties obtained from first-principles local density functional calculations. The fits require a surprisingly high asymmetry for the spin dependent electron lifetimes in Fe, {tau}{sup {down_arrow}}/{tau}{sup {up_arrow}}=10 at room temperature. Despite the large atomic terraces at the Au/vacuum and Fe/GaAs interfaces the scattering at the outer interfaces was found to be diffuse. The origin of MR in Au/Fe/Au/Fe/GaAs(001) structures is due to electron channeling in the Au spacer layer. The measured MR is consistent with the diffusivity parameters s{sup {up_arrow}}=0.55, s{sup {down_arrow}}=0.77 at the metal{endash}metal interfaces. {copyright} 2001 American Institute of Physics.

  3. Robust Au-Ag-Au bimetallic atom-scale junctions fabricated by self-limited Ag electrodeposition at Au nanogaps.

    PubMed

    Hwang, Tai-Wei; Bohn, Paul W

    2011-10-25

    Atom-scale junctions (ASJs) exhibit quantum conductance behavior and have potential both for fundamental studies of adsorbate-mediated conductance in mesoscopic conductors and as chemical sensors. Electrochemically fabricated ASJs, in particular, show the stability needed for molecular detection applications. However, achieving physically robust ASJs at high yield is a challenge because it is difficult to control the direction and kinetics of metal deposition. In this work, a novel electrochemical approach is reported, in which Au-Ag-Au bimetallic ASJs are reproducibly fabricated from an initially prepared Au nanogap by sequential overgrowth and self-limited thinning. Applying a potential across specially prepared Au nanoelectrodes in the presence of aqueous Ag(I) leads to preferential galvanic reactions resulting in the deposition of Ag and the formation of an atom-scale junction between the electrodes. An external resistor is added in series with the ASJ to control self-termination, and adjusting solution chemical potential (concentration) is used to mediate self-thinning of junctions. The result is long-lived, mechanically stable ASJs that, unlike previous constructions, are stable in flowing solution, as well as to changes in solution media. These bimetallic ASJs exhibit a number of behaviors characteristic of quantum structures, including long-lived fractional conductance states, that are interpreted to arise from two or more quantized ASJs in series.

  4. Fabrication of segmented Au/Co/Au nanowires: insights in the quality of Co/Au junctions.

    PubMed

    Jang, Bumjin; Pellicer, Eva; Guerrero, Miguel; Chen, Xiangzhong; Choi, Hongsoo; Nelson, Bradley J; Sort, Jordi; Pané, Salvador

    2014-08-27

    Electrodeposition is a versatile method, which enables the fabrication of a variety of wire-like nanoarchitectures such as nanowires, nanorods, and nanotubes. By means of template-assisted electrodeposition, segmented Au/Co/Au nanowires are grown in anodic aluminum oxide templates from two different electrolytes. To tailor the properties of the cobalt segments, several electrochemical conditions are studied as a function of current density, pulse deposition, and pH. The morphology, crystal structure, and magnetic properties are accordingly investigated. Changes in the deposition conditions affect the cobalt electrocrystallization process directly. Cobalt tends to crystallize mainly in the hexagonal close-packed structure, which is the reason cobalt might not accommodate satisfactorily on the face-centered cubic Au surface or vice versa. We demonstrate that by modifying the electrolyte and the applied current densities, changes in the texture and the crystalline structure of cobalt lead to a good quality connection between dissimilar segments. In particular, lowering the bath pH, or using pulse plating at a high overpotential, produces polycrystalline fcc Co and thus well-connected Co/Au bimetallic junctions with smooth interface. These are crucial factors to be carefully considered taking into account that nanowires are potential building blocks in micro- and nanoelectromechanical systems. PMID:25025496

  5. Production of ω mesons in p + p, d + Au, Cu + Cu, and Au + Au collisions at sNN=200 GeV

    NASA Astrophysics Data System (ADS)

    Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Al-Bataineh, H.; Al-Jamel, A.; Alexander, J.; Angerami, A.; Aoki, K.; Apadula, N.; Aphecetche, L.; Aramaki, Y.; Armendariz, R.; Aronson, S. H.; Asai, J.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Bai, M.; Baksay, G.; Baksay, L.; Baldisseri, A.; Barish, K. N.; Barnes, P. D.; Bassalleck, B.; Basye, A. T.; Bathe, S.; Batsouli, S.; Baublis, V.; Bauer, F.; Baumann, C.; Bazilevsky, A.; Belikov, S.; Belmont, R.; Bennett, R.; Berdnikov, A.; Berdnikov, Y.; Bhom, J. H.; Bickley, A. A.; Bjorndal, M. T.; Blau, D. S.; Boissevain, J. G.; Bok, J. S.; Borel, H.; Boyle, K.; Brooks, M. L.; Brown, D. S.; Bucher, D.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Burward-Hoy, J. M.; Butsyk, S.; Camacho, C. M.; Campbell, S.; Caringi, A.; Chai, J.-S.; Chang, B. S.; Charvet, J.-L.; Chen, C.-H.; Chernichenko, S.; Chi, C. Y.; Chiba, J.; Chiu, M.; Choi, I. J.; Choi, J. B.; Choudhury, R. K.; Christiansen, P.; Chujo, T.; Chung, P.; Churyn, A.; Chvala, O.; Cianciolo, V.; Citron, Z.; Cleven, C. R.; Cobigo, Y.; Cole, B. A.; Comets, M. P.; Conesa Del Valle, Z.; Connors, M.; Constantin, P.; Csanád, M.; Csörgő, T.; Dahms, T.; Dairaku, S.; Danchev, I.; Das, K.; Datta, A.; David, G.; Dayananda, M. K.; Deaton, M. B.; Dehmelt, K.; Delagrange, H.; Denisov, A.; D'Enterria, D.; Deshpande, A.; Desmond, E. J.; Dharmawardane, K. V.; Dietzsch, O.; Dion, A.; Donadelli, M.; Drachenberg, J. L.; Drapier, O.; Drees, A.; Drees, K. A.; Dubey, A. K.; Durham, J. M.; Durum, A.; Dutta, D.; Dzhordzhadze, V.; D'Orazio, L.; Edwards, S.; Efremenko, Y. V.; Egdemir, J.; Ellinghaus, F.; Emam, W. S.; Engelmore, T.; Enokizono, A.; En'yo, H.; Espagnon, B.; Esumi, S.; Eyser, K. O.; Fadem, B.; Fields, D. E.; Finger, M.; Finger, M., Jr.; Fleuret, F.; Fokin, S. L.; Forestier, B.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fujiwara, K.; Fukao, Y.; Fung, S.-Y.; Fusayasu, T.; Gadrat, S.; Garishvili, I.; Gastineau, F.; Germain, M.; Glenn, A.; Gong, H.; Gonin, M.; Gosset, J.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grim, G.; Grosse Perdekamp, M.; Gunji, T.; Gustafsson, H.-Å.; Hachiya, T.; Hadj Henni, A.; Haegemann, C.; Haggerty, J. S.; Hagiwara, M. N.; Hahn, K. I.; Hamagaki, H.; Hamblen, J.; Han, R.; Hanks, J.; Harada, H.; Hartouni, E. P.; Haruna, K.; Harvey, M.; Haslum, E.; Hasuko, K.; Hayano, R.; He, X.; Heffner, M.; Hemmick, T. K.; Hester, T.; Heuser, J. M.; Hiejima, H.; Hill, J. C.; Hobbs, R.; Hohlmann, M.; Holmes, M.; Holzmann, W.; Homma, K.; Hong, B.; Horaguchi, T.; Hornback, D.; Huang, S.; Hur, M. G.; Ichihara, T.; Ichimiya, R.; Ide, J.; Iinuma, H.; Ikeda, Y.; Imai, K.; Inaba, M.; Inoue, Y.; Isenhower, D.; Isenhower, L.; Ishihara, M.; Isobe, T.; Issah, M.; Isupov, A.; Ivanischev, D.; Iwanaga, Y.; Jacak, B. V.; Jia, J.; Jiang, X.; Jin, J.; Jinnouchi, O.; Johnson, B. M.; Jones, T.; Joo, K. S.; Jouan, D.; Jumper, D. S.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kamin, J.; Kaneta, M.; Kang, J. H.; Kanou, H.; Kapustinsky, J.; Karatsu, K.; Kasai, M.; Kawagishi, T.; Kawall, D.; Kawashima, M.; Kazantsev, A. V.; Kelly, S.; Kempel, T.; Khanzadeev, A.; Kijima, K. M.; Kikuchi, J.; Kim, A.; Kim, B. I.; Kim, D. H.; Kim, D. J.; Kim, E.; Kim, E. J.; Kim, S. H.; Kim, Y.-J.; Kim, Y.-S.; Kim, Y. J.; Kinney, E.; Kiriluk, K.; Kiss, Á.; Kistenev, E.; Kiyomichi, A.; Klay, J.; Klein-Boesing, C.; Kochenda, L.; Kochetkov, V.; Komkov, B.; Konno, M.; Koster, J.; Kotchetkov, D.; Kozlov, A.; Král, A.; Kravitz, A.; Kroon, P. J.; Kubart, J.; Kunde, G. J.; Kurihara, N.; Kurita, K.; Kurosawa, M.; Kweon, M. J.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lai, Y. S.; Lajoie, J. G.; Lebedev, A.; Le Bornec, Y.; Leckey, S.; Lee, D. M.; Lee, J.; Lee, K.; Lee, K. B.; Lee, K. S.; Lee, M. K.; Lee, T.; Leitch, M. J.; Leite, M. A. L.; Leitner, E.; Lenzi, B.; Li, X.; Li, X. H.; Lichtenwalner, P.; Liebing, P.; Lim, H.; Linden Levy, L. A.; Liška, T.; Litvinenko, A.; Liu, H.; Liu, M. X.; Love, B.; Luechtenborg, R.; Lynch, D.; Maguire, C. F.; Makdisi, Y. I.; Malakhov, A.; Malik, M. D.; Manko, V. I.; Mannel, E.; Mao, Y.; Mašek, L.; Masui, H.; Matathias, F.; McCain, M. C.; McCumber, M.; McGaughey, P. L.; Means, N.; Meredith, B.; Miake, Y.; Mibe, T.; Mignerey, A. C.; Mikeš, P.; Miki, K.; Miller, T. E.; Milov, A.; Mioduszewski, S.; Mishra, G. C.; Mishra, M.; Mitchell, J. T.; Mitrovski, M.; Mohanty, A. K.; Moon, H. J.; Morino, Y.; Morreale, A.; Morrison, D. P.; Moss, J. M.; Moukhanova, T. V.; Mukhopadhyay, D.; Murakami, T.; Murata, J.; Nagamiya, S.; Nagata, Y.; Nagle, J. L.; Naglis, M.; Nagy, M. I.; Nakagawa, I.; Nakamiya, Y.; Nakamura, K. R.; Nakamura, T.; Nakano, K.; Nam, S.; Newby, J.; Nguyen, M.; Nihashi, M.; Norman, B. E.; Nouicer, R.; Nyanin, A. S.; Nystrand, J.; Oakley, C.; O'Brien, E.; Oda, S. X.; Ogilvie, C. A.; Ohnishi, H.; Ojha, I. D.; Oka, M.; Okada, K.; Omiwade, O. O.; Onuki, Y.; Oskarsson, A.; Otterlund, I.; Ouchida, M.; Ozawa, K.; Pak, R.; Pal, D.; Palounek, A. P. T.; Pantuev, V.; Papavassiliou, V.; Park, I. H.; Park, J.; Park, S. K.; Park, W. J.; Pate, S. F.; Pei, H.; Peng, J.-C.; Pereira, H.; Peresedov, V.; Peressounko, D. Yu.; Petti, R.; Pinkenburg, C.; Pisani, R. P.; Proissl, M.; Purschke, M. L.; Purwar, A. K.; Qu, H.; Rak, J.; Rakotozafindrabe, A.; Ravinovich, I.; Read, K. F.; Rembeczki, S.; Reuter, M.; Reygers, K.; Riabov, V.; Riabov, Y.; Richardson, E.; Roach, D.; Roche, G.; Rolnick, S. D.; Romana, A.; Rosati, M.; Rosen, C. A.; Rosendahl, S. S. E.; Rosnet, P.; Rukoyatkin, P.; Ružička, P.; Rykov, V. L.; Ryu, S. S.; Sahlmueller, B.; Saito, N.; Sakaguchi, T.; Sakai, S.; Sakashita, K.; Sakata, H.; Samsonov, V.; Sano, S.; Sato, H. D.; Sato, S.; Sato, T.; Sawada, S.; Sedgwick, K.; Seele, J.; Seidl, R.; Semenov, A. Yu.; Semenov, V.; Seto, R.; Sharma, D.; Shea, T. K.; Shein, I.; Shevel, A.; Shibata, T.-A.; Shigaki, K.; Shimomura, M.; Shohjoh, T.; Shoji, K.; Shukla, P.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Silvestre, C.; Sim, K. S.; Singh, B. K.; Singh, C. P.; Singh, V.; Skutnik, S.; Slunečka, M.; Smith, W. C.; Soldatov, A.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Sourikova, I. V.; Sparks, N. A.; Staley, F.; Stankus, P. W.; Stenlund, E.; Stepanov, M.; Ster, A.; Stoll, S. P.; Sugitate, T.; Suire, C.; Sukhanov, A.; Sullivan, J. P.; Sziklai, J.; Tabaru, T.; Takagi, S.; Takagui, E. M.; Taketani, A.; Tanabe, R.; Tanaka, K. H.; Tanaka, Y.; Taneja, S.; Tanida, K.; Tannenbaum, M. J.; Tarafdar, S.; Taranenko, A.; Tarján, P.; Themann, H.; Thomas, D.; Thomas, T. L.; Togawa, M.; Toia, A.; Tojo, J.; Tomášek, L.; Torii, H.; Towell, R. S.; Tram, V.-N.; Tserruya, I.; Tsuchimoto, Y.; Tuli, S. K.; Tydesjö, H.; Tyurin, N.; Vale, C.; Valle, H.; van Hecke, H. W.; Vazquez-Zambrano, E.; Veicht, A.; Velkovska, J.; Vértesi, R.; Vinogradov, A. A.; Virius, M.; Vrba, V.; Vznuzdaev, E.; Wagner, M.; Walker, D.; Wang, X. R.; Watanabe, D.; Watanabe, K.; Watanabe, Y.; Wei, F.; Wei, R.; Wessels, J.; White, S. N.; Willis, N.; Winter, D.; Wood, J. P.; Woody, C. L.; Wright, R. M.; Wysocki, M.; Xie, W.; Yamaguchi, Y. L.; Yamaura, K.; Yang, R.; Yanovich, A.; Yasin, Z.; Ying, J.; Yokkaichi, S.; You, Z.; Young, G. R.; Younus, I.; Yushmanov, I. E.; Zajc, W. A.; Zaudtke, O.; Zhang, C.; Zhou, S.; Zimányi, J.; Zolin, L.

    2011-10-01

    The PHENIX experiment at the Relativistic Heavy Ion Collider has measured ω meson production via leptonic and hadronic decay channels in p+p, d+Au, Cu+Cu, and Au+Au collisions at sNN = 200 GeV. The invariant transverse momentum spectra measured in different decay modes give consistent results. Measurements in the hadronic decay channel in Cu+Cu and Au+Au collisions show that ω production has a suppression pattern at high transverse momentum, similar to that of π0 and η in central collisions, but no suppression is observed in peripheral collisions. The nuclear modification factors, RAA, are consistent in Cu+Cu and Au+Au collisions at similar numbers of participant nucleons.

  6. Facile Syntheses of Monodisperse Ultra-Small Au Clusters

    SciTech Connect

    Bertino, Massimo F.; Sun, Zhong-Ming; Zhang, Rui; Wang, Lai S.

    2006-11-02

    During our effort to synthesize the tetrahedral Au20 cluster, we found a facile synthetic route to prepare monodisperse suspensions of ultra-small Au clusters AuN (N<12) using diphosphine ligands. In our monophasic and single-pot synthesis, a Au precursor ClAu(I)PPh3 and a bidentate phosphine ligand P(Ph)2(CH2)MP(Ph)2 (Ph = phenyl) are dissolved in an organic solvent. Au(I) is reduced slowly by a borane-tert-butylamine complex to form Au clusters coordinated by the diphosphine ligand. The Au clusters are characterized by both high resolution mass spectrometry and UV-Vis absorption spectroscopy. We found that the mean cluster size obtained depends on the chain length M of the ligand. In particular, a single monodispersed Au11 cluster is obtained with the P(Ph)2(CH2)3P(Ph)2 ligand, whereas P(Ph)2(CH2)MP(Ph)2 ligands with M = 5 and 6 yield Au10 and Au8 clusters. The simplicity of our synthetic method makes it suitable for large-scale production of nearly monodisperse ultrasmall Au clusters. It is suggested that diphosphines provide a set of flexible ligands to allow size-controlled synthesis of Au nanoparticles.

  7. Communique: Special Issue on the International Network for Cooperation in Northern Science Created at a Meeting held in Edmonton, Alberta (October 12-15, 1982). Summary of Discussions and Agreements Reached = Numero special sur le Reseau Scientifique Internationale pour le Nord cree a la reunion tenue a Edmonton, Alberta (du 12 au 15 octobre 1982). Resume des discussions et accords conclus.

    ERIC Educational Resources Information Center

    Communique, 1983

    1983-01-01

    Delegations from Canada, Finland, Greenland, Norway, Sweden, and the United States agreed to the establishment of a network for cooperation among individuals engaged in problems peculiar to the circumpolar North. The Northern Science Network, established within the Unesco Man and the Biosphere Program, consists of three themes: studies on the…

  8. Suppression of Upsilon production in d + Au and Au + Au collisions at root s(NN) = 200 GeV (vol 735, pg 127, 2014)

    SciTech Connect

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Alford, J.; Anson, C. D.; Aparin, A.; Arkhipkin, D.; Gliske, S.; Krueger, K.; Spinka, H. M.; Underwood, D. G.

    2014-07-30

    We report measurements of Υ meson production in p + p, d +Au, and Au+Aucollisions using the STAR detector at RHIC. We compare the Υ yield to the measured cross section in p + p collisions in order to quantify any modifications of the yield in cold nuclear matter using d +Au data and in hot nuclear matter using Au+Au data separated into three centrality classes. Our p +p measurement is based on three times the statistics of our previous result. We obtain a nuclear modification factor for Υ (1S + 2S + 3S) in the rapidity range |y| < 1 in d + Aucollisions of RdAu = 0.79 ± 0.24(stat.) ± 0.03(syst.) ± 0.10(p + p syst.). A comparison with models including shadowing and initial state parton energy loss indicates the presence of additional cold-nuclear matter suppression. Similarly, in the top 10% most-central Au + Au collisions, we measure a nuclear modification factor of R AA = 0.49 ±0.1(stat.) ±0.02(syst.) ±0.06(p + p syst.), which is a larger suppression factor than that seen in cold nuclear matter. Our results are consistent with complete suppression of excited-state Υ mesons in Au + Aucollisions. The additional suppression in Au + Au is consistent with the level expected in model calculations that include the presence of a hot, deconfined Quark–Gluon Plasma. However, understanding the suppression seen in d + Au is still needed before any definitive statements about the nature of the suppression in Au + Au can be made.

  9. Nanoporous Au: an unsupported pure gold catalyst?

    SciTech Connect

    Wittstock, A; Neumann, B; Schaefer, A; Dumbuya, K; Kuebel, C; Biener, M; Zielasek, V; Steinrueck, H; Gottfried, M; Biener, J; Hamza, A; B?umer, M

    2008-09-04

    The unique properties of gold especially in low temperature CO oxidation have been ascribed to a combination of various effects. In particular, particle sizes below a few nm and specific particle-support interactions have been shown to play important roles. On the contrary, recent reports revealed that monolithic nanoporous gold (npAu) prepared by leaching a less noble metal, such as Ag, out of the corresponding alloy can also exhibit remarkably high catalytic activity for CO oxidation, even though no support is present. Therefore, it was claimed to be a pure and unsupported gold catalyst. We investigated npAu with respect to its morphology, surface composition and catalytic properties. In particular, we studied the reaction kinetics for low temperature CO oxidation in detail taking mass transport limitation due to the porous structure of the material into account. Our results reveal that Ag, even if removed almost completely from the bulk, segregates to the surface resulting in surface concentrations of up to 10 at%. Our data suggest that this Ag plays a significant role in activation of molecular oxygen. Therefore, npAu should be considered as a bimetallic catalyst rather than a pure Au catalyst.

  10. 22 CFR 62.31 - Au pairs.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... pair participant with child development and child safety instruction, as follows: (1) Prior to... development instruction of which no less than 4 shall be devoted to specific training for children under the... and participate directly in the home life of the host family. All au pair participants provide...

  11. 22 CFR 62.31 - Au pairs.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... pair participant with child development and child safety instruction, as follows: (1) Prior to... development instruction of which no less than 4 shall be devoted to specific training for children under the... and participate directly in the home life of the host family. All au pair participants provide...

  12. 22 CFR 62.31 - Au pairs.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... pair participant with child development and child safety instruction, as follows: (1) Prior to... development instruction of which no less than 4 shall be devoted to specific training for children under the... and participate directly in the home life of the host family. All au pair participants provide...

  13. 22 CFR 62.31 - Au pairs.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... pair participant with child development and child safety instruction, as follows: (1) Prior to... development instruction of which no less than 4 shall be devoted to specific training for children under the... and participate directly in the home life of the host family. All au pair participants provide...

  14. 22 CFR 62.31 - Au pairs.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... pair participant with child development and child safety instruction, as follows: (1) Prior to... development instruction of which no less than 4 shall be devoted to specific training for children under the... and participate directly in the home life of the host family. All au pair participants provide...

  15. Ecole et communaute au Portugal

    NASA Astrophysics Data System (ADS)

    Melo, Alberto

    1980-09-01

    Since 1974 Portugal has experienced some dramatic changes in educational practices at the local level. The school has been opened to the community and the community to the school. Teacher education now includes community studies, designed to prepare teachers for an active role in this process and for the better understanding of the social background of pupils. One new practice is the publication of local newspapers or news-sheets to enhance the understanding of the community by teachers and pupils. The development of a school garden for the cultivation of flowers and vegetables serves as another bridge between school and community. Other examples of community action are adult literacy classes, the creation of voluntary organisations for women, the running of youth clubs, the formation of co-operatives, and local projects like the purchase of an old tram-car to be converted into a library. The introduction of `Civic and Polytechnic Education' for 13-16 year olds was an important innovation. One half-day a week was to be devoted to the integration of the school with the locality, young people's participation in society as agents of change, the linking of study and productive work, and the involvement of young people in the solution of national problems, working from a concrete knowledge of local and regional life. However, since 1976 there has been a more conservative approach, and only in places with a strong consensus amongst teachers has the new relationship between school and community been maintained.

  16. Electron transmission characteristics of Au/1,4-benzenedithiol/Au junctions.

    PubMed

    Horiguchi, K; Tsutsui, M; Kurokawa, S; Sakai, A

    2009-01-14

    Electron transmission through individual 1,4-benzenedithiol molecules bridging between two gold electrodes (Au/BDT/Au junctions) has been studied by measuring the current-voltage (I-V) characteristics. Measurements were made at room temperature on three junction states of conductance 0.005G(0), 0.01G(0), and 0.1G(0), respectively, where G(0) is the quantum unit of conductance. All I-V curves are linear around zero bias and nonlinearly increase upward for biases above approximately 0.2 V. Absence of plateaus in the observed I-V characteristics up to +/- 1 V indicates that the electron transmission spectrum of Au/BDT/Au has no peaks within +/- 0.5 eV from the Fermi level.

  17. High Resolution Photoelectron Spectroscopy of Au_2^- and Au_4^- by Photoelectron Imaging

    NASA Astrophysics Data System (ADS)

    Leon, Iker; Yang, Zheng; Wang, Lai-Sheng

    2013-06-01

    We report high resolution photoelectron spectra of Au_2^- and Au_4^- obtained with a newly-built photoelectron imaging apparatus. Gold anions are produced by laser vaporization and the desired specie is mass selected and focused into the collinear velocity-map imaging (VMI) lens assembly. The design of the imaging lens has allowed us to obtain less than 0.9% energy resolution for high kinetic energy electrons ( > 1eV) while maintaining wavenumber resolution for low kinetic energy electrons. Although gold dimer and tetramer have been studied in the past, we present spectroscopic results under high resolution. For Au_2^-, we report high resolution spectra with an accurate determination of the electron affinity together with a complete vibrational assignment, for both the anion and neutral ground states, while for Au_4^-, we are able to resolve a low frequency mode and obtain accurately the adiabatic detachment energy.

  18. Charged-Particle Pseudorapidity Density Distributions from Au+Au Collisions at

    SciTech Connect

    Back, B. B.; Baker, M. D.; Barton, D. S.; Betts, R. R.; Bindel, R.; Budzanowski, A.; Busza, W.; Carroll, A.; Decowski, M. P.; Garcia, E.

    2001-09-03

    The charged-particle pseudorapidity density dN{sub ch}/d{eta} has been measured for Au+Au collisions at s{sub NN}=130 GeV at RHIC, using the PHOBOS apparatus. The total number of charged particles produced for the 3% most-central Au+Au collisions for |{eta}|{<=}5.4 is found to be 4200{+-}470 . The evolution of dN{sub ch}/d{eta} with centrality is discussed, and compared to model calculations and to data from proton-induced collisions. The data show an enhancement in charged-particle production at midrapidity, while in the fragmentation regions, the results are consistent with expectations from pp and pA scattering.

  19. Systematics of Global Observables in Cu+Cu and Au+Au Collisions at RHIC Energies

    SciTech Connect

    Nouicer, Rachid

    2006-07-11

    Charged particles produced in Cu+Cu collisions at {radical}(s{sub NN}) = 200 and 62.4 GeV have been measured in the PHOBOS experiment at RHIC. The comparison of the results for Cu+Cu and Au+Au for the most central collisions at the same energy reveals that the particle density per nucleon participant pair and the extended longitudinal scaling behavior are similar in both systems. This implies that for the most central events in symmetric nucleus-nucleus collisions the particle density per nucleon participant pair does not depend on the size of the two colliding nuclei but only on the collision energy. Also the extended longitudinal scaling seems independent of the colliding energy and species for central collisions. In addition, there is an overall factorization of dNch/d{eta} shapes as a function of collision centraliry between Au+Au and Cu+Cu collisions at the same energy.

  20. Charge-dependent azimuthal correlations from AuAu to UU collisions

    NASA Astrophysics Data System (ADS)

    Bloczynski, John; Huang, Xu-Guang; Zhang, Xilin; Liao, Jinfeng

    2015-07-01

    We study the charge-dependent azimuthal correlations in relativistic heavy ion collisions, as motivated by the search for the Chiral Magnetic Effect (CME) and the investigation of related background contributions. In particular we aim to understand how these correlations induced by various proposed effects evolve from collisions with AuAu system to that with UU system. To do that, we quantify the generation of magnetic field in UU collisions at RHIC energy and its azimuthal correlation with the matter geometry using event-by-event simulations. Taking the experimental data for charge-dependent azimuthal correlations from AuAu collisions and extrapolating to UU with reasonable assumptions, we examine the resulting correlations to be expected in UU collisions and compare them with recent STAR measurements. Based on such analysis we discuss the viability for explaining the data with a combination of the CME-like and flow-induced contributions.

  1. Some thoughts on di-jet correlation in Au + Au collisions from PHENIX

    SciTech Connect

    Jia Jiangyong

    2006-07-11

    PHENIX has measured the two particle azimuth correlation in Au + Au at {radical}(s) = 200 GeV. Jet shape and yield at the away side are found to be strongly modified at intermediate and low pT, and the modifications vary dramatically with pT and centrality. At high pT, away side jet peak reappears but the yield is suppressed. We discuss the possible physics pictures leading to these complicated modifications.

  2. Net charge fluctuations in Au + Au interactions at sqrt[s(NN)]=130 GeV.

    PubMed

    Adcox, K; Adler, S S; Ajitanand, N N; Akiba, Y; Alexander, J; Aphecetche, L; Arai, Y; Aronson, S H; Averbeck, R; Awes, T C; Barish, K N; Barnes, P D; Barrette, J; Bassalleck, B; Bathe, S; Baublis, V; Bazilevsky, A; Belikov, S; Bellaiche, F G; Belyaev, S T; Bennett, M J; Berdnikov, Y; Botelho, S; Brooks, M L; Brown, D S; Bruner, N; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J; Butsyk, S; Carey, T A; Chand, P; Chang, J; Chang, W C; Chavez, L L; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choudhury, R K; Christ, T; Chujo, T; Chung, M S; Chung, P; Cianciolo, V; Cole, B A; D'Enterria, D G; David, G; Delagrange, H; Denisov, A; Deshpande, A; Desmond, E J; Dietzsch, O; Dinesh, B V; Drees, A; Durum, A; Dutta, D; Ebisu, K; Efremenko, Y V; El Chenawi, K; En'yo, H; Esumi, S; Ewell, L; Ferdousi, T; Fields, D E; Fokin, S L; Fraenkel, Z; Franz, A; Frawley, A D; Fung, S-Y; Garpman, S; Ghosh, T K; Glenn, A; Godoi, A L; Goto, Y; Greene, S V; Grosse Perdekamp, M; Gupta, S K; Guryn, W; Gustafsson, H-A; Haggerty, J S; Hamagaki, H; Hansen, A G; Hara, H; Hartouni, E P; Hayano, R; Hayashi, N; He, X; Hemmick, T K; Heuser, J M; Hibino, M; Hill, J C; Ho, D S; Homma, K; Hong, B; Hoover, A; Ichihara, T; Imai, K; Ippolitov, M S; Ishihara, M; Jacak, B V; Jang, W Y; Jia, J; Johnson, B M; Johnson, S C; Joo, K S; Kametani, S; Kang, J H; Kann, M; Kapoor, S S; Kelly, S; Khachaturov, B; Khanzadeev, A; Kikuchi, J; Kim, D J; Kim, H J; Kim, S Y; Kim, Y G; Kinnison, W W; Kistenev, E; Kiyomichi, A; Klein-Boesing, C; Klinksiek, S; Kochenda, L; Kochetkov, V; Koehler, D; Kohama, T; Kotchetkov, D; Kozlov, A; Kroon, P J; Kurita, K; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Lajoie, J G; Lauret, J; Lebedev, A; Lee, D M; Leitch, M J; Li, X H; Li, Z; Lim, D J; Liu, M X; Liu, X; Liu, Z; Maguire, C F; Mahon, J; Makdisi, Y I; Manko, V I; Mao, Y; Mark, S K; Markacs, S; Martinez, G; Marx, M D; Masaike, A; Matathias, F; Matsumoto, T; McGaughey, P L; Melnikov, E; Merschmeyer, M; Messer, F; Messer, M; Miake, Y; Miller, T E; Milov, A; Mioduszewski, S; Mischke, R E; Mishra, G C; Mitchell, J T; Mohanty, A K; Morrison, D P; Moss, J M; Mühlbacher, F; Muniruzzaman, M; Murata, J; Nagamiya, S; Nagasaka, Y; Nagle, J L; Nakada, Y; Nandi, B K; Newby, J; Nikkinen, L; Nilsson, P; Nishimura, S; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Ono, M; Onuchin, V; Oskarsson, A; Osterman, L; Otterlund, I; Oyama, K; Paffrath, L; Palounek, A P T; Pantuev, V S; Papavassiliou, V; Pate, S F; Peitzmann, T; Petridis, A N; Pinkenburg, C; Pisani, R P; Pitukhin, P; Plasil, F; Pollack, M; Pope, K; Purschke, M L; Ravinovich, I; Read, K F; Reygers, K; Riabov, V; Riabov, Y; Rosati, M; Rose, A A; Ryu, S S; Saito, N; Sakaguchi, A; Sakaguchi, T; Sako, H; Sakuma, T; Samsonov, V; Sangster, T C; Santo, R; Sato, H D; Sato, S; Sawada, S; Schlei, B R; Schutz, Y; Semenov, V; Seto, R; Shea, T K; Shein, I; Shibata, T-A; Shigaki, K; Shiina, T; Shin, Y H; Sibiriak, I G; Silvermyr, D; Sim, K S; Simon-Gillo, J; Singh, C P; Singh, V; Sivertz, M; Soldatov, A; Soltz, R A; Sorensen, S; Stankus, P W; Starinsky, N; Steinberg, P; Stenlund, E; Ster, A; Stoll, S P; Sugioka, M; Sugitate, T; Sullivan, J P; Sumi, Y; Sun, Z; Suzuki, M; Takagui, E M; Taketani, A; Tamai, M; Tanaka, K H; Tanaka, Y; Taniguchi, E; Tannenbaum, M J; Thomas, J; Thomas, J H; Thomas, T L; Tian, W; Tojo, J; Torii, H; Towell, R S; Tserruya, I; Tsuruoka, H; Tsvetkov, A A; Tuli, S K; Tydesjö, H; Tyurin, N; Ushiroda, T; van Hecke, H W; Velissaris, C; Velkovska, J; Velkovsky, M; Vinogradov, A A; Volkov, M A; Vorobyov, A; Vznuzdaev, E; Wang, H; Watanabe, Y; White, S N; Witzig, C; Wohn, F K; Woody, C L; Xie, W; Yagi, K; Yokkaichi, S; Young, G R; Yushmanov, I E; Zajc, W A; Zhang, Z; Zhou, S

    2002-08-19

    Data from Au + Au interactions at sqrt[s(NN)]=130 GeV, obtained with the PHENIX detector at the Relativistic Heavy-Ion Collider, are used to investigate local net charge fluctuations among particles produced near midrapidity. According to recent suggestions, such fluctuations may carry information from the quark-gluon plasma. This analysis shows that the fluctuations are dominated by a stochastic distribution of particles, but are also sensitive to other effects, like global charge conservation and resonance decays.

  3. Evidence of Significant Covalent Bonding in Au(CN)2-

    SciTech Connect

    Wang, Xue B.; wang, Yi-Lei; Yang, Jie; Xing, Xiaopeng; Li, Jun; Wang, Lai S.

    2009-11-18

    There have been intense recent interests in the homogeneous catalytic chemistry of Au(I) complexes.1 Among the Au(I) molecules, the Au(CN)2- ion is the most stable and has been widely used in gold extraction back to ancient times. Although AuCN in the condensed phase has been studied, including solution phase vibrational spectroscopy2 and crystal structures,3 the free AuCN molecule has been studied only very recently by microwave spectroscopy.4 The important Au(CN)2- complex has not been observed and studied in the gas phase. Because of the relativistic effects,5 Au-containing molecules exhibit distinctly different properties among the coinage elements. To elucidate the nature of the Au-ligand binding, high-level ab initio calculations are needed due to the complicated electron correlation and relativistic effects.6-8 The structure and bonding of the AuCN molecule were first examined computationally by Frenking and co-workers.7 Recent high-precision calculations by Pyykkö and co-workers suggest multiple-bond characters between Au-C in AuCN because the Au-C bond length is only slightly longer than the sum of the triple bond covalent radii.

  4. The effect of Au amount on size uniformity of self-assembled Au nanoparticles

    NASA Astrophysics Data System (ADS)

    Chen, S.-H.; Wang, D.-C.; Chen, G.-Y.; Chen, K.-Y.

    2008-03-01

    The self-assembled fabrication of nanostructure, a dreaming approach in the area of fabrication engineering, is the ultimate goal of this research. A finding was proved through previous research that the size of the self-assembled gold nanoparticles could be controlled with the mole ratio between AuCl4- and thiol. In this study, the moles of Au were fixed, only the moles of thiol were adjusted. Five different mole ratios of Au/S with their effect on size uniformity were investigated. The mole ratios were 1:1/16, 1:1/8, 1:1, 1:8, 1:16, respectively. The size distributions of the gold nanoparticles were analyzed by Mac-View analysis software. HR-TEM was used to derive images of self-assembled gold nanoparticles. The result reached was also the higher the mole ratio between AuCl4- and thiol the bigger the self-assembled gold nanoparticles. Under the condition of moles of Au fixed, the most homogeneous nanoparticles in size distribution derived with the mole ratio of 1:1/8 between AuCl4- and thiol. The obtained nanoparticles could be used, for example, in uniform surface nanofabrication, leading to the fabrication of ordered array of quantum dots.

  5. Experimental and Theoretical Studies on Oxidation of Cu-Au Alloy Surfaces: Effect of Bulk Au Concentration.

    PubMed

    Okada, Michio; Tsuda, Yasutaka; Oka, Kohei; Kojima, Kazuki; Diño, Wilson Agerico; Yoshigoe, Akitaka; Kasai, Hideaki

    2016-01-01

    We report results of our experimental and theoretical studies on the oxidation of Cu-Au alloy surfaces, viz., Cu3Au(111), CuAu(111), and Au3Cu(111), using hyperthermal O2 molecular beam (HOMB). We observed strong Au segregation to the top layer of the corresponding clean (111) surfaces. This forms a protective layer that hinders further oxidation into the bulk. The higher the concentration of Au in the protective layer formed, the higher the protective efficacy. As a result, of the three Cu-Au surfaces studied, Au3Cu(111) is the most stable against dissociative adsorption of O2, even with HOMB. We also found that this protective property breaks down for oxidations occurring at temperatures above 300 K. PMID:27516137

  6. Bonding, Luminescence, Metallophilicity in Linear Au3 and Au2Ag Chains Stabilized by Rigid Diphosphanyl NHC Ligands.

    PubMed

    Ai, Pengfei; Mauro, Matteo; Gourlaouen, Christophe; Carrara, Serena; De Cola, Luisa; Tobon, Yeny; Giovanella, Umberto; Botta, Chiara; Danopoulos, Andreas A; Braunstein, Pierre

    2016-09-01

    The heterofunctional and rigid ligand N,N'-diphosphanyl-imidazol-2-ylidene (PCNHCP; P = P(t-Bu)2), through its phosphorus and two N-heterocyclic carbene (NHC) donors, stabilizes trinuclear chain complexes, with either Au3 or AgAu2 cores, and dinuclear Au2 complexes. The two oppositely situated PCNHCP (L) ligands that "sandwich" the metal chain can support linear and rigid structures, as found in the known tricationic Au(I) complex [Au3(μ3-PCNHCP,κP,κCNHC,κP)2](OTf)3 (OTf = CF3SO3; [Au3L2](OTf)3; Chem. Commun. 2014, 50, 103-105) now also obtained by transmetalation from [Ag3(μ3-PCNHCP,κP,κCNHC,κP)2](OTf)3 ([Ag3L2](OTf)3), or in the mixed-metal tricationic [Au2Ag(μ3-PCNHCP,κP,κCNHC,κP)2](OTf)3 ([Au2AgL2](OTf)3). The latter was obtained stepwise by the addition of AgOTf to the digold(I) complex [Au2(μ2-PCNHCP,κP,κCNHC)2](OTf)2 ([Au2L2](OTf)2). The latter contains two dangling P donors and displays fluxional behavior in solution, and the Au···Au separation of 2.8320(6) Å in the solid state is consistent with metallophilic interactions. In the solvento complex [Au3Cl2(tht)(μ3-PCNHCP,κP,κCNHC,κP)](OTf)·MeCN ([Au3Cl2(tht)L](OTf)·MeCN), which contains only one L and one tht ligand (tht = tetrahydrothiophene), the metal chain is bent (148.94(2)°), and the longer Au···Au separation (2.9710(4) Å) is in line with relaxation of the rigidity due to a more "open" structure. Similar features were observed in [Au3Cl2(SMe2)L](OTf)·2MeCN. A detailed study of the emission properties of [Au3L2](OTf)3, [Au3Cl2(tht)L](OTf)·MeCN, [Au2L2](OTf)2, and [Au2AgL2](OTf)3 was performed by means of steady state and time-resolved photophysical techniques. The complex [Au3L2](OTf)3 displays a bright (photoluminescence quantum yield = 80%) and narrow emission band centered at 446 nm with a relatively small Stokes' shift and long-lived excited-state lifetime on the microsecond timescale, both in solution and in the solid state. In line with the very narrow emission

  7. Identified particle distributions in pp and Au+Au collisions atsqrt sNN=200 GeV

    SciTech Connect

    Adams, J.; Adler, C.; Aggarwal, M.M.; Ahammed, Z.; Amonett, J.; Anderson, B.D.; Anderson, M; Arkhipkin, D.; Averichev, G.S.; Badyal,S.K.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele,S.; Belaga, V.V.; Bellwied, R.; Berger, J.; Bezverkhny, B.I.; Bhardwaj,S.; Bhaskar, P.; Bhati, A.K.; Bichsel, H.; Billmeier, A.; Bland, L.C.; Blyth, C.O.; Bonner, B.E.; Botje, M.; Boucham, A.; Brandin, A.; Bravar,A.; Cadman, R.V.; Cai, X.Z.; Caines, H.; Calderon de la Barca Sanchez,M.; Carroll, J.; Castillo, J.; Castro, M.; Cebra, D.; Chaloupka, P.; Chattopadhyay, S.; Chen, H.F.; Chen, Y.; Chernenko, S.P.; Cherney, M.; Chikanian, A.; Choi, B.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Cramer, J.G.; Crawford, H.J.; Das, D.; Das, S.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Dong, X.; Draper, J.E.; Du, F.; Dubey, A.K.; Dunin, V.B.; Dunlop, J.C.; Dutta Majumdar, M.R.; Eckardt, V.; Efimov,L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Faine, V.; Faivre, J.; Fatemi, R.; Filimonov, K.; Filip, P.; Finch, E.; Fisyak, Y.; Flierl, D.; Foley, K.J.; Fu, J.; Gagliardi, C.A.; Ganti, M.S.; Gutierrez, T.D.; Gagunashvili, N.; Gans, J.; Gaudichet, L.; Germain, M.; Geurts, F.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J.E.; Grachov, O.; Grigoriev, V.; Cronstal, S.; Grosnick, D.; Guedon, M.; Guertin, S.M.; Gupta, A.; Gushin, E.; Hallman, T.J.; Hardtke, D.; Harris,J.W.; Heinz, M.; Henry, T.W.; Heppelmann, S.; Herston, T.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffmann, G.W.; Horsley, M.; Huang, H.Z.; Huang,S.L.; Humanic, T.J.; Igo, G.; Ishihara, A.; Jacobs, P.; Jacobs, W.W.; Janik, M.; Johnson, I.; Jones, P.G.; Judd, E.G.; Kabana, S.; Kaneta, M.; Kaplan, M.; Keane, D.; Kiryluk, J.; Kisiel, A.; Klay, J.; Klein, S.R.; Klyachko, A.; Koetke, D.D.; Kollegger, T.; Konstantinov, A.S.; Kopytine,S.M.; Kotchenda, L.; Kovalenko, A.D.; Kramer, M.; Kravtsov, P.; Krueger,K.; Kuhn, C.; Kulikov, A.I.; Kumar, A.; et al.

    2003-10-06

    Transverse mass and rapidity distributions for charged pions, charged kaons, protons and antiprotons are reported for {radical}sNN = 200 GeV pp and Au+Au collisions at RHIC. The transverse mass distributions are rapidity independent within |y| < 0.5, consistent with a boost-invariant system in this rapidity interval. Spectral shapes and relative particle yields are similar in pp and peripheral Au+Au collisions and change smoothly to central Au+Au collisions. No centrality dependence was observed in the kaon and antiproton production rates relative to the pion production rate from medium-central to central collisions. Chemical and kinetic equilibrium model fits to our data reveal strong radial flow and relatively long duration from chemical to kinetic freeze-out in central Au+Au collisions. The chemical freeze-out temperature appears to be independent of initial conditions at RHIC energies.

  8. Experimental and Theoretical Studies on Oxidation of Cu-Au Alloy Surfaces: Effect of Bulk Au Concentration

    PubMed Central

    Okada, Michio; Tsuda, Yasutaka; Oka, Kohei; Kojima, Kazuki; Diño, Wilson Agerico; Yoshigoe, Akitaka; Kasai, Hideaki

    2016-01-01

    We report results of our experimental and theoretical studies on the oxidation of Cu-Au alloy surfaces, viz., Cu3Au(111), CuAu(111), and Au3Cu(111), using hyperthermal O2 molecular beam (HOMB). We observed strong Au segregation to the top layer of the corresponding clean (111) surfaces. This forms a protective layer that hinders further oxidation into the bulk. The higher the concentration of Au in the protective layer formed, the higher the protective efficacy. As a result, of the three Cu-Au surfaces studied, Au3Cu(111) is the most stable against dissociative adsorption of O2, even with HOMB. We also found that this protective property breaks down for oxidations occurring at temperatures above 300 K. PMID:27516137

  9. Bonding, Luminescence, Metallophilicity in Linear Au3 and Au2Ag Chains Stabilized by Rigid Diphosphanyl NHC Ligands.

    PubMed

    Ai, Pengfei; Mauro, Matteo; Gourlaouen, Christophe; Carrara, Serena; De Cola, Luisa; Tobon, Yeny; Giovanella, Umberto; Botta, Chiara; Danopoulos, Andreas A; Braunstein, Pierre

    2016-09-01

    The heterofunctional and rigid ligand N,N'-diphosphanyl-imidazol-2-ylidene (PCNHCP; P = P(t-Bu)2), through its phosphorus and two N-heterocyclic carbene (NHC) donors, stabilizes trinuclear chain complexes, with either Au3 or AgAu2 cores, and dinuclear Au2 complexes. The two oppositely situated PCNHCP (L) ligands that "sandwich" the metal chain can support linear and rigid structures, as found in the known tricationic Au(I) complex [Au3(μ3-PCNHCP,κP,κCNHC,κP)2](OTf)3 (OTf = CF3SO3; [Au3L2](OTf)3; Chem. Commun. 2014, 50, 103-105) now also obtained by transmetalation from [Ag3(μ3-PCNHCP,κP,κCNHC,κP)2](OTf)3 ([Ag3L2](OTf)3), or in the mixed-metal tricationic [Au2Ag(μ3-PCNHCP,κP,κCNHC,κP)2](OTf)3 ([Au2AgL2](OTf)3). The latter was obtained stepwise by the addition of AgOTf to the digold(I) complex [Au2(μ2-PCNHCP,κP,κCNHC)2](OTf)2 ([Au2L2](OTf)2). The latter contains two dangling P donors and displays fluxional behavior in solution, and the Au···Au separation of 2.8320(6) Å in the solid state is consistent with metallophilic interactions. In the solvento complex [Au3Cl2(tht)(μ3-PCNHCP,κP,κCNHC,κP)](OTf)·MeCN ([Au3Cl2(tht)L](OTf)·MeCN), which contains only one L and one tht ligand (tht = tetrahydrothiophene), the metal chain is bent (148.94(2)°), and the longer Au···Au separation (2.9710(4) Å) is in line with relaxation of the rigidity due to a more "open" structure. Similar features were observed in [Au3Cl2(SMe2)L](OTf)·2MeCN. A detailed study of the emission properties of [Au3L2](OTf)3, [Au3Cl2(tht)L](OTf)·MeCN, [Au2L2](OTf)2, and [Au2AgL2](OTf)3 was performed by means of steady state and time-resolved photophysical techniques. The complex [Au3L2](OTf)3 displays a bright (photoluminescence quantum yield = 80%) and narrow emission band centered at 446 nm with a relatively small Stokes' shift and long-lived excited-state lifetime on the microsecond timescale, both in solution and in the solid state. In line with the very narrow emission

  10. Centrality dependence of direct photon production in (square root)S(NN) = 200 GeV Au + Au collisions.

    PubMed

    Adler, S S; Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Alexander, J; Amirikas, R; Aphecetche, L; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, R; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bazilevsky, A; Belikov, S; Berdnikov, Y; Bhagavatula, S; Boissevain, J G; Borel, H; Borenstein, S; Brooks, M L; Brown, D S; Bruner, N; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Camard, X; Chai, J-S; Chand, P; Chang, W C; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Choi, J; Choudhury, R K; Chujo, T; Cianciolo, V; Cobigo, Y; Cole, B A; Constantin, P; d'Enterria, D; David, G; Delagrange, H; Denisov, A; Deshpande, A; Desmond, E J; Devismes, A; Dietzsch, O; Drapier, O; Drees, A; du Rietz, R; Durum, A; Dutta, D; Efremenko, Y V; El Chenawi, K; Enokizono, A; En'yo, H; Esumi, S; Ewell, L; Fields, D E; Fleuret, F; Fokin, S L; Fox, B D; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fung, S-Y; Garpman, S; Ghosh, T K; Glenn, A; Gogiberidze, G; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Perdekamp, M Grosse; Guryn, W; Gustafsson, H-A; Hachiya, T; Haggerty, J S; Hamagaki, H; Hansen, A G; Hartouni, E P; Harvey, M; Hayano, R; Hayashi, N; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hibino, M; Hill, J C; Holzmann, W; Homma, K; Hong, B; Hoover, A; Ichihara, T; Ikonnikov, V V; Imai, K; Isenhower, D; Ishihara, M; Issah, M; Isupov, A; Jacak, B V; Jang, W Y; Jeong, Y; Jia, J; Jinnouchi, O; Johnson, B M; Johnson, S C; Joo, K S; Jouan, D; Kametani, S; Kamihara, N; Kang, J H; Kapoor, S S; Katou, K; Kelly, S; Khachaturov, B; Khanzadeev, A; Kikuchi, J; Kim, D H; Kim, D J; Kim, D W; Kim, E; Kim, G-B; Kim, H J; Kistenev, E; Kiyomichi, A; Kiyoyama, K; Klein-Boesing, C; Kobayashi, H; Kochenda, L; Kochetkov, V; Koehler, D; Kohama, T; Kopytine, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kuberg, C H; Kurita, K; Kuroki, Y; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Ladygin, V; Lajoie, J G; Lebedev, A; Leckey, S; Lee, D M; Lee, S; Leitch, M J; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Liu, Y; Maguire, C F; Makdisi, Y I; Malakhov, A; Manko, V I; Mao, Y; Martinez, G; Marx, M D; Masui, H; Matathias, F; Matsumoto, T; McGaughey, P L; Melnikov, E; Messer, F; Miake, Y; Milan, J; Miller, T E; Milov, A; Mioduszewski, S; Mischke, R E; Mishra, G C; Mitchell, J T; Mohanty, A K; Morrison, D P; Moss, J M; Mühlbacher, F; Mukhopadhyay, D; Muniruzzaman, M; Murata, J; Nagamiya, S; Nagle, J L; Nakamura, T; Nandi, B K; Nara, M; Newby, J; Nilsson, P; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Ono, M; Onuchin, V; Oskarsson, A; Otterlund, I; Oyama, K; Ozawa, K; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, J; Parmar, A; Pate, S F; Peitzmann, T; Peng, J-C; Peresedov, V; Pinkenburg, C; Pisani, R P; Plasil, F; Purschke, M L; Purwar, A K; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosnet, P; Ryu, S S; Sadler, M E; Saito, N; Sakaguchi, T; Sakai, M; Sakai, S; Samsonov, V; Sanfratello, L; Santo, R; Sato, H D; Sato, S; Sawada, S; Schutz, Y; Semenov, V; Seto, R; Shaw, M R; Shea, T K; Shibata, T-A; Shigaki, K; Shiina, T; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Sivertz, M; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Sullivan, J P; Takagui, E M; Taketani, A; Tamai, M; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Tarján, P; Tepe, J D; Thomas, T L; Tojo, J; Torii, H; Towell, R S; Tserruya, I; Tsuruoka, H; Tuli, S K; Tydesjö, H; Tyurin, N; van Hecke, H W; Velkovska, J; Velkovsky, M; Veszprémi, V; Villatte, L; Vinogradov, A A; Volkov, M A; Vznuzdaev, E; Wang, X R; Watanabe, Y; White, S N; Wohn, F K; Woody, C L; Xie, W; Yang, Y; Yanovich, A; Yokkaichi, S; Young, G R; Yushmanov, I E; Zajc, W A; Zhang, C; Zhou, S; Zhou, S J; Zolin, L

    2005-06-17

    The first measurement of direct photons in Au + Au collisions at (square root)S(NN) = 200 GeV is presented. The direct photon signal is extracted as a function of the Au + Au collision centrality and compared to next-to-leading order perturbative quantum chromodynamics calculations. The direct photon yield is shown to scale with the number of nucleon-nucleon collisions for all centralities.

  11. Slab melting and the origin of gold in Au and Au-Cu deposits: geochemical clues from recent adakites.

    NASA Astrophysics Data System (ADS)

    Polve, M.; Maury, R.; Joron, J. L.

    2003-04-01

    Understanding the genetic processes responsible for the common occurrence of Au and Au-Cu deposits in subduction environments is a fairly "hot" question nowadays, as it is clear that most subduction-related magmatic rocks are barren. Studies of space and time relationships between magmatic intrusions, hydrothermal episodes and Au deposits have shown that, very often, Au deposits are associated with adakitic intrusions (Thieblemont et al, 1997, Sajona and Maury, 1998). Adakites are here understood as being generated by melting of the subducting oceanic crust. This study aims to check wether or not magmas derived from melted oceanic crust do contain significantly more Au than regular calc-alkaline magmas by measuring directly Au concentrations in fresh (and barren) adakites and equivalent calc-alkaline andesites. There is a lack of reliable data on Au content in unaltered adakites and andesites, because Au analyses are generally done on hydrothermalized rocks in connection with Au deposits and also because old measurements may give overestimated Au contents, due to technical limitations. Therefore we compiled recent literature data on gold contents of fresh calc-alkaline rocks, and measured Au on a selection of 40 well studied and dated adakites from different localities (Philippines, Baja California). Analyses have been performed either by INAA or by ICP-MS after Au extraction with aqua regia, following the method described by Terashima (1988). Preliminary results show that, for equivalent Si02 contents, adakites are systematically enriched in Au compared to regular dacites, even if regional trends also exist. Moreover, Au seems to behave as an incompatible element in adakitic magmas, whereas in calc-alkaline dacites it is controlled by sulfide crystallization. Our data suggest that, not excluding any other processes related to the hydrothermal phase in the deposit generation, adakites may indeed represent the source of Au, a possible explanation for the adakite-Au

  12. AU-FREDI - AUTONOMOUS FREQUENCY DOMAIN IDENTIFICATION

    NASA Technical Reports Server (NTRS)

    Yam, Y.

    1994-01-01

    The Autonomous Frequency Domain Identification program, AU-FREDI, is a system of methods, algorithms and software that was developed for the identification of structural dynamic parameters and system transfer function characterization for control of large space platforms and flexible spacecraft. It was validated in the CALTECH/Jet Propulsion Laboratory's Large Spacecraft Control Laboratory. Due to the unique characteristics of this laboratory environment, and the environment-specific nature of many of the software's routines, AU-FREDI should be considered to be a collection of routines which can be modified and reassembled to suit system identification and control experiments on large flexible structures. The AU-FREDI software was originally designed to command plant excitation and handle subsequent input/output data transfer, and to conduct system identification based on the I/O data. Key features of the AU-FREDI methodology are as follows: 1. AU-FREDI has on-line digital filter design to support on-orbit optimal input design and data composition. 2. Data composition of experimental data in overlapping frequency bands overcomes finite actuator power constraints. 3. Recursive least squares sine-dwell estimation accurately handles digitized sinusoids and low frequency modes. 4. The system also includes automated estimation of model order using a product moment matrix. 5. A sample-data transfer function parametrization supports digital control design. 6. Minimum variance estimation is assured with a curve fitting algorithm with iterative reweighting. 7. Robust root solvers accurately factorize high order polynomials to determine frequency and damping estimates. 8. Output error characterization of model additive uncertainty supports robustness analysis. The research objectives associated with AU-FREDI were particularly useful in focusing the identification methodology for realistic on-orbit testing conditions. Rather than estimating the entire structure, as is

  13. Di-hadron correlations with identified leading hadrons in 200 GeV Au + Au and d + Au collisions at STAR

    NASA Astrophysics Data System (ADS)

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Aparin, A.; Arkhipkin, D.; Aschenauer, E. C.; Averichev, G. S.; Bai, X.; Bairathi, V.; Banerjee, A.; Bellwied, R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Bouchet, J.; Brandenburg, D.; Brandin, A. V.; Bunzarov, I.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Campbell, J. M.; Cebra, D.; Cervantes, M. C.; Chakaberia, I.; Chaloupka, P.; Chang, Z.; Chattopadhyay, S.; Chen, X.; Chen, J. H.; Cheng, J.; Cherney, M.; Christie, W.; Contin, G.; Crawford, H. J.; Das, S.; De Silva, L. C.; Debbe, R. R.; Dedovich, T. G.; Deng, J.; Derevschikov, A. A.; di Ruzza, B.; Didenko, L.; Dilks, C.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Du, C. M.; Dunkelberger, L. E.; Dunlop, J. C.; Efimov, L. G.; Engelage, J.; Eppley, G.; Esha, R.; Evdokimov, O.; Eyser, O.; Fatemi, R.; Fazio, S.; Federic, P.; Fedorisin, J.; Feng, Z.; Filip, P.; Fisyak, Y.; Flores, C. E.; Fulek, L.; Gagliardi, C. A.; Garand, D.; Geurts, F.; Gibson, A.; Girard, M.; Greiner, L.; Grosnick, D.; Gunarathne, D. S.; Guo, Y.; Gupta, S.; Gupta, A.; Guryn, W.; Hamad, A.; Hamed, A.; Haque, R.; Harris, J. W.; He, L.; Heppelmann, S.; Heppelmann, S.; Hirsch, A.; Hoffmann, G. W.; Hofman, D. J.; Horvat, S.; Huang, T.; Huang, B.; Huang, H. Z.; Huang, X.; Huck, P.; Humanic, T. J.; Igo, G.; Jacobs, W. W.; Jang, H.; Jia, J.; Jiang, K.; Judd, E. G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Khan, Z. H.; Kikoła, D. P.; Kisiel, A.; Kochenda, L.; Koetke, D. D.; Kosarzewski, L. K.; Kraishan, A. F.; Kravtsov, P.; Krueger, K.; Kumar, L.; Lamont, M. A. C.; Landgraf, J. M.; Landry, K. D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; Li, X.; Li, W.; Li, Z. M.; Li, Y.; Li, C.; Li, X.; Lisa, M. A.; Liu, F.; Ljubicic, T.; Llope, W. J.; Lomnitz, M.; Longacre, R. S.; Luo, X.; Ma, G. L.; Ma, Y. G.; Ma, R.; Ma, L.; Magdy, N.; Majka, R.; Manion, A.; Margetis, S.; Markert, C.; Masui, H.; Matis, H. S.; McDonald, D.; Meehan, K.; Mei, J. C.; Minaev, N. G.; Mioduszewski, S.; Mishra, D.; Mohanty, B.; Mondal, M. M.; Morozov, D. A.; Mustafa, M. K.; Nandi, B. K.; Nasim, Md.; Nayak, T. K.; Nigmatkulov, G.; Niida, T.; Nogach, L. V.; Noh, S. Y.; Novak, J.; Nurushev, S. B.; Odyniec, G.; Ogawa, A.; Oh, K.; Okorokov, V.; Olvitt, D.; Page, B. S.; Pak, R.; Pan, Y. X.; Pandit, Y.; Panebratsev, Y.; Pawlik, B.; Pei, H.; Perkins, C.; Peterson, A.; Pile, P.; Pluta, J.; Poniatowska, K.; Porter, J.; Posik, M.; Poskanzer, A. M.; Pruthi, N. K.; Putschke, J.; Qiu, H.; Quintero, A.; Ramachandran, S.; Raniwala, R.; Raniwala, S.; Ray, R. L.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Roy, A.; Ruan, L.; Rusnak, J.; Rusnakova, O.; Sahoo, N. R.; Sahu, P. K.; Sakrejda, I.; Salur, S.; Sandweiss, J.; Sarkar, A.; Schambach, J.; Scharenberg, R. P.; Schmah, A. M.; Schmidke, W. B.; Schmitz, N.; Seger, J.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P. V.; Shao, M.; Sharma, B.; Sharma, M. K.; Shen, W. Q.; Shi, S. S.; Shou, Q. Y.; Sichtermann, E. P.; Sikora, R.; Simko, M.; Singha, S.; Skoby, M. J.; Smirnov, N.; Smirnov, D.; Song, L.; Sorensen, P.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Stepanov, M.; Strikhanov, M.; Stringfellow, B.; Sumbera, M.; Summa, B.; Sun, Y.; Sun, Z.; Sun, X. M.; Sun, X.; Surrow, B.; Svirida, D. N.; Szelezniak, M. A.; Tang, A. H.; Tang, Z.; Tarnowsky, T.; Tawfik, A.; Thomas, J. H.; Timmins, A. R.; Tlusty, D.; Todoroki, T.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Tripathy, S. K.; Tsai, O. D.; Ullrich, T.; Underwood, D. G.; Upsal, I.; Van Buren, G.; van Nieuwenhuizen, G.; Vandenbroucke, M.; Varma, R.; Vasiliev, A. N.; Vertesi, R.; Videbæk, F.; Viyogi, Y. P.; Vokal, S.; Voloshin, S. A.; Vossen, A.; Wang, J. S.; Wang, F.; Wang, H.; Wang, G.; Wang, Y.; Wang, Y.; Webb, G.; Webb, J. C.; Wen, L.; Westfall, G. D.; Wieman, H.; Wissink, S. W.; Witt, R.; Wu, Y. F.; Wu; Xiao, Z. G.; Xie, W.; Xin, K.; Xu, H.; Xu, Z.; Xu, Q. H.; Xu, Y. F.; Xu, N.; Yang, S.; Yang, Y.; Yang, Q.; Yang, Y.; Yang, C.; Yang, Y.; Ye, Z.; Ye, Z.; Yepes, P.; Yi, L.; Yip, K.; Yoo, I.-K.; Yu, N.; Zbroszczyk, H.; Zha, W.; Zhang, Y.; Zhang, Z.; Zhang, J. B.; Zhang, J.; Zhang, X. P.; Zhang, S.; Zhang, J.; Zhao, J.; Zhong, C.; Zhou, L.; Zhu, X.; Zoulkarneeva, Y.

    2015-12-01

    The STAR Collaboration presents for the first time two-dimensional di-hadron correlations with identified leading hadrons in 200 GeV central Au + Au and minimum-bias d + Au collisions to explore hadronization mechanisms in the quark gluon plasma. The enhancement of the jet-like yield for leading pions in Au + Au data with respect to the d + Au reference and the absence of such an enhancement for leading non-pions (protons and kaons) are discussed within the context of a quark recombination scenario. The correlated yield at large angles, specifically in the ridge region, is found to be significantly higher for leading non-pions than pions. The consistencies of the constituent quark scaling, azimuthal harmonic model and a mini-jet modification model description of the data are tested, providing further constraints on hadronization.

  14. From the ternary Eu(Au/In)2 and EuAu4(Au/In)2 with remarkable Au/In distributions to a new structure type: The gold-rich Eu5Au16(Au/In)6 structure

    DOE PAGESBeta

    Steinberg, Simon; Card, Nathan; Mudring, Anja -Verena

    2015-08-13

    The ternary Eu(Au/In)2 (EuAu0.46In1.54(2)) (I), EuAu4(Au/In)2 (EuAu4+xIn2–x with x = 0.75(2) (II), 0.93(2), and 1.03(2)), and Eu5Au16(Au/In)6 (Eu5Au17.29In4.71(3)) (III) have been synthesized, and their structures were characterized by single-crystal X-ray diffraction. I and II crystallize with the CeCu2-type (Pearson Symbol oI12; Imma; Z = 4; a = 4.9018(4) Å; b = 7.8237(5) Å; c = 8.4457(5) Å) and the YbAl4Mo2-type (tI14; I4/mmm; Z = 2; a = 7.1612(7) Å; c = 5.5268(7) Å) and exhibit significant Au/In disorder. I is composed of an Au/In-mixed diamond-related host lattice encapsulating Eu atoms, while the structure of II features ribbons of distorted, squaredmore » Au8 prisms enclosing Eu, Au, and In atoms. Combination of these structural motifs leads to a new structure type as observed for Eu5Au16(Au/In)6 (Eu5Au17.29In4.71(3)) (oS108; Cmcm; Z = 4; a = 7.2283(4) Å; b = 9.0499(6) Å; c = 34.619(2) Å), which formally represents a one-dimensional intergrowth of the series EuAu2–“EuAu4In2”. The site preferences of the disordered Au/In positions in II were investigated for different hypothetical “EuAu4(Au/In)2” models using the projector-augmented wave method and indicate that these structures attempt to optimize the frequencies of the heteroatomic Au–In contacts. Furthermore, a chemical bonding analysis on two “EuAu5In” and “EuAu4In2” models employed the TB-LMTO-ASA method and reveals that the subtle interplay between the local atomic environments and the bond energies determines the structural and site preferences for these systems.« less

  15. Fe impurities weaken the ferromagnetic behavior in Au nanoparticles.

    PubMed

    Crespo, P; García, M A; Fernández Pinel, E; Multigner, M; Alcántara, D; de la Fuente, J M; Penadés, S; Hernando, A

    2006-10-27

    In this Letter, we report on a crucial experiment showing that magnetic impurities reduce the ferromagnetic order temperature in thiol-capped Au glyconanoparticles (GNPs). The spontaneous magnetization of AuFe GNPs exhibits a fast decrease with temperature that contrasts with the almost constant value of the magnetization observed in Au NPs. Moreover, hysteresis disappears below 300 K. Both features indicate that Fe impurities reduce the high local anisotropy field responsible for the ferromagnetic behavior in Au GNPs. As a consequence, the amazing ferromagnetism in Au NPs should not be associated with the presence of magnetic impurities.

  16. Enhanced spin pumping at yttrium iron garnet/Au interfaces

    SciTech Connect

    Burrowes, C.; Heinrich, B.; Kardasz, B.; Montoya, E. A.; Girt, E.; Sun Yiyan; Song, Young-Yeal; Wu Mingzhong

    2012-02-27

    Spin injection across the ferrimagnetic insulator yttrium iron garnet (YIG)/normal metal Au interface was studied using ferromagnetic resonance. The spin mixing conductance was determined by comparing the Gilbert damping parameter {alpha} in YIG/Au and YIG/Au/Fe heterostructures. The main purpose of this study was to correlate the spin pumping efficiency with chemical modifications of the YIG film surface using in situ etching and deposition techniques. By means of Ar{sup +} ion beam etching, one is able to increase the spin mixing conductance at the YIG/Au interface by a factor of 5 compared to the untreated YIG/Au interface.

  17. Synthesis, structure, and bonding in K12Au21Sn4. A polar intermetallic compound with dense Au20 and open AuSn4 layers

    SciTech Connect

    Li, Bin; Kim, Sung-Jin; Miller, Gordon J.; and Corbett, John D.

    2009-10-29

    The new phase K{sub 12}Au{sub 21}Sn{sub 4} has been synthesized by direct reaction of the elements at elevated temperatures. Single crystal X-ray diffraction established its orthorhombic structure, space group Pmmn (No. 59), a = 12.162(2); b = 18.058(4); c = 8.657(2) {angstrom}, V = 1901.3(7) {angstrom}{sup 3}, and Z = 2. The structure consists of infinite puckered sheets of vertex-sharing gold tetrahedra (Au{sub 20}) that are tied together by thin layers of alternating four-bonded-Sn and -Au atoms (AuSn{sub 4}). Remarkably, the dense but electron-poorer blocks of Au tetrahedra coexist with more open and saturated Au-Sn layers, which are fragments of a zinc blende type structure that maximize tetrahedral heteroatomic bonding outside of the network of gold tetrahedra. LMTO band structure calculations reveal metallic properties and a pseudogap at 256 valence electrons per formula unit, only three electrons fewer than in the title compound and at a point at which strong Au-Sn bonding is optimized. Additionally, the tight coordination of the Au framework atoms by K plays an important bonding role: each Au tetrahedra has 10 K neighbors and each K atom has 8-12 Au contacts. The appreciably different role of the p element Sn in this structure from that in the triel members in K{sub 3}Au{sub 5}In and Rb{sub 2}Au{sub 3}Tl appears to arise from its higher electron count which leads to better p-bonding (valence electron concentrations = 1.32 versus 1.22).

  18. Isomorphism and solid solutions among Ag- and Au-selenides

    NASA Astrophysics Data System (ADS)

    Palyanova, Galina A.; Seryotkin, Yurii V.; Kokh, Konstantin A.; Bakakin, Vladimir V.

    2016-09-01

    Au-Ag selenides were synthesized by heating stoichiometric mixtures of elementary substances of initial compositions Ag2-xAuxSe with a step of x=0.25 (0≤x≤2) to 1050 °C and annealing at 500 °C. Scanning electron microscopy, optical microscopy, electron microprobe analysis and X-ray powder diffraction methods have been applied to study synthesized samples. Results of studies of synthesized products revealed the existence of three solid solutions with limited isomorphism Ag↔Au: naumannite Ag2Se - Ag1.94Au0.06Se, fischesserite Ag3AuSe2 - Ag3.2Au0.8Se2 and gold selenide AuSe - Au0.94Ag0.06Se. Solid solutions and AgAuSe phases were added to the phase diagram of Ag-Au-Se system. Crystal-chemical interpretation of Ag-Au isomorphism in selenides was made on the basis of structural features of fischesserite, naumannite, and AuSe.

  19. Bactericidal mechanisms of Au@TNBs under visible light irradiation.

    PubMed

    Guo, Lingqiao; Shan, Chao; Liang, Jialiang; Ni, Jinren; Tong, Meiping

    2015-04-01

    Au@TNBs nanocomposites were synthesized by depositing Au nanoparticles onto the surfaces of TiO2 nanobelts (TNBs). The disinfection activities of Au@TNBs on model cell type, Gram-negative Escherichia coli (E. coli), were examined under visible light irradiation conditions. Au@TNBs exhibited stronger bactericidal properties toward E. coli than those of TNBs and Au NPs under visible light irradiation. The bactericidal mechanisms of Au@TNBs under light conditions were explored, specifically, the specific active species controlling the inactivation of bacteria were determined. Active species (H2O2, diffusing ∙OH, ∙O2-, 1O2, and e-) generated by Au@TNBs were found to play important roles on the inactivation of bacteria. Moreover, the concentrations of H2O2, ·OH, ·O2-, and 1O2 generated in the antimicrobial system were estimated. Without the presence of active species, the direct contact of Au@TNBs with bacterial cells was found to have no bactericidal effect. The reusability of Au@TNBs were also determined. Au@TNBs exhibited strong antibacterial activity toward E. coli even in five consecutively reused cycles. This study indicated that the fabricated Au@TNBs could be potentially utilized to inactivate bacteria in water.

  20. Monolithic Nanocrystalline Au Fabricated by the Compaction of Nanoscale Foam

    SciTech Connect

    Hodge, A M; Biener, J; Hsiung, L M; Hamza, A V; Satcher Jr., J H

    2004-07-28

    We describe a two-step dealloying/compaction process to produce nanocrystalline Au. First, nanocrystalline/nanoporous Au foam is synthesized by electrochemically-driven dealloying. The resulting Au foams exhibit porosities of 60 and 70% with pore sizes of {approx} 40 and 100 nm, respectively, and a typical grain size of <50 nm. Second, the nanoporous foams are fully compacted to produce nanocrystalline monolithic Au. The compacted Au was characterized by TEM and X-ray diffraction and tested by depth-sensing nanoindentation. The compacted nanocrystalline Au exhibits an average grain size of <50 nm and hardness values ranging from 1.4 to 2.0 GPa, which are up to 4.5 times higher than the hardness values obtained from polycrystalline Au.

  1. Au-nanoparticles grafted on plasma treated PE

    NASA Astrophysics Data System (ADS)

    Švorčík, V.; Chaloupka, A.; Řezanka, P.; Slepička, P.; Kolská, Z.; Kasálková, N.; Hubáček, T.; Siegel, J.

    2010-03-01

    Polyethylene (PE) surface was treated with Ar plasma. Activated surface was grafted from methanol solution of 1,2-ethanedithiol. Then the sample was immersed into freshly prepared colloid solution of Au-nanoparticles. Finally Au layer was sputtered on the samples. Properties of the modified PE were studied using various methods: AFM, EPR, RBS and nanoindentation. It was shown that the plasma treatment results in degradation of polymer chain (AFM) and creation of free radicals by EPR. After grafting with dithiol, the concentration of free radicals declines. The presence of Au and S in the surface layer after the coating with Au-nanoparticles was proved by RBS. Plasma treatment changes PE surface morphology and increases surface roughness, too. Another significant change in surface morphology and roughness was observed after deposition of Au-nanoparticles. Nanoindentation measurements show that the grafting with Au-nanoparticles increases adhesion of subsequently sputtered Au layer.

  2. Collision-spike sputtering of Au nanoparticles

    SciTech Connect

    Sandoval, Luis; Urbassek, Herbert M.

    2015-08-06

    Ion irradiation of nanoparticles leads to enhanced sputter yields if the nanoparticle size is of the order of the ion penetration depth. While this feature is reasonably well understood for collision-cascade sputtering, we explore it in the regime of collision-spike sputtering using molecular-dynamics simulation. For this specific case of 200-keV Xe bombardment of Au particles, we show that collision spikes lead to abundant sputtering with an average yield of 397 ± 121 atoms compared to only 116 ± 48 atoms for a bulk Au target. Only around 31% of the impact energy remains in the nanoparticles after impact; the remainder is transported away by the transmitted projectile and the ejecta. The sputter yield of supported nanoparticles is estimated to be around 80% of that of free nanoparticles due to the suppression of forward sputtering.

  3. Collision-spike sputtering of Au nanoparticles

    DOE PAGESBeta

    Sandoval, Luis; Urbassek, Herbert M.

    2015-08-06

    Ion irradiation of nanoparticles leads to enhanced sputter yields if the nanoparticle size is of the order of the ion penetration depth. While this feature is reasonably well understood for collision-cascade sputtering, we explore it in the regime of collision-spike sputtering using molecular-dynamics simulation. For this specific case of 200-keV Xe bombardment of Au particles, we show that collision spikes lead to abundant sputtering with an average yield of 397 ± 121 atoms compared to only 116 ± 48 atoms for a bulk Au target. Only around 31% of the impact energy remains in the nanoparticles after impact; the remaindermore » is transported away by the transmitted projectile and the ejecta. The sputter yield of supported nanoparticles is estimated to be around 80% of that of free nanoparticles due to the suppression of forward sputtering.« less

  4. Collision-spike Sputtering of Au Nanoparticles.

    PubMed

    Sandoval, Luis; Urbassek, Herbert M

    2015-12-01

    Ion irradiation of nanoparticles leads to enhanced sputter yields if the nanoparticle size is of the order of the ion penetration depth. While this feature is reasonably well understood for collision-cascade sputtering, we explore it in the regime of collision-spike sputtering using molecular-dynamics simulation. For the particular case of 200-keV Xe bombardment of Au particles, we show that collision spikes lead to abundant sputtering with an average yield of 397 ± 121 atoms compared to only 116 ± 48 atoms for a bulk Au target. Only around 31 % of the impact energy remains in the nanoparticles after impact; the remainder is transported away by the transmitted projectile and the ejecta. The sputter yield of supported nanoparticles is estimated to be around 80 % of that of free nanoparticles due to the suppression of forward sputtering.

  5. Tunable VO2/Au hyperbolic metamaterial

    NASA Astrophysics Data System (ADS)

    Prayakarao, S.; Mendoza, B.; Devine, A.; Kyaw, C.; van Dover, R. B.; Liberman, V.; Noginov, M. A.

    2016-08-01

    Vanadium dioxide (VO2) is known to have a semiconductor-to-metal phase transition at ˜68 °C. Therefore, it can be used as a tunable component of an active metamaterial. The lamellar metamaterial studied in this work is composed of subwavelength VO2 and Au layers and is designed to undergo a temperature controlled transition from the optical hyperbolic phase to the metallic phase. VO2 films and VO2/Au lamellar metamaterial stacks have been fabricated and studied in electrical conductivity and optical (transmission and reflection) experiments. The observed temperature-dependent changes in the reflection and transmission spectra of the metamaterials and VO2 thin films are in a good qualitative agreement with theoretical predictions. The demonstrated optical hyperbolic-to-metallic phase transition is a unique physical phenomenon with the potential to enable advanced control of light-matter interactions.

  6. Fabrication of a chitosan/glucose oxidase-poly(anilineboronic acid)-Au(nano)/Au-plated Au electrode for biosensor and biofuel cell.

    PubMed

    Huang, Yi; Qin, Xiaoli; Li, Zou; Fu, Yingchun; Qin, Cong; Wu, Feng; Su, Zhaohong; Ma, Ming; Xie, Qingji; Yao, Shouzhuo; Hu, Jiming

    2012-01-15

    Enzyme immobilization is one of the key factors in constructing high-performance enzyme biosensors and biofuel cells (BFCs). Herein, we propose a new protocol for efficient immobilization of a glycoprotein enzyme based on the interaction of the 1, 2- or 1, 3-diols in the glycoprotein with a boronic acid functionalized monomer. Briefly, casting a mixture of glucose oxidase (GOx) and anilineboronic acid (ABA) followed by a NaAuCl(4) solution to an Au-plated Au electrode surface yielded a GOx-poly(ABA) (PABA)-gold nanoparticle (Au(nano)) bionanocomposite, and chitosan (CS) was then cast and air-dried. In the present protocol, the small-sized Au(nano) or Au subnanostructures can form near/on the enzyme molecule, which greatly promotes the electron transfer of enzymatic reaction and enhances the amperometric responses. The thus-prepared CS/GOx-PABA-Au(nano)/Au-plated Au electrode worked well in the first-/second generation biosensing modes and as a bioanode in a monopolar biofuel cell, with analytical or cell-power performance superior to those of most analogues hitherto reported. PMID:22099959

  7. Mammalian sensitivity to elemental gold (Au?)

    USGS Publications Warehouse

    Eisler, R.

    2004-01-01

    There is increasing documentation of allergic contact dermatitis and other effects from gold jewelry, gold dental restorations, and gold implants. These effects were especially pronounced among females wearing body-piercing gold objects. One estimate of the prevalence of gold allergy worldwide is 13%, as judged by patch tests with monovalent organogold salts. Eczema of the head and neck was the most common response of individuals hypersensitive to gold, and sensitivity can last for at least several years. Ingestion of beverages containing flake gold can result in allergic-type reactions similar to those seen in gold-allergic individuals exposed to gold through dermal contact and other routes. Studies with small laboratory mammals and injected doses of colloidal gold showed increased body temperatures, accumulations in reticular cells, and dose enhancement in tumor therapy; gold implants were associated with tissue injuries. It is proposed that Au? toxicity to mammals is associated, in part, with formation of the more reactive Au+ and Au3+ species.

  8. Photocatalysis enhancement of Au/BFO nanoparticles using plasmon resonance of Au NPs

    NASA Astrophysics Data System (ADS)

    Zhang, Yan; Cai, Zhongyang; Ma, Xueming

    2015-12-01

    BiFeO3 (BFO) nanoparticles was synthesized via sol-gel technique, and successfully loaded with small sizes of gold nanoparticles (Au NPs) by impregnation-reduction method to extremely enhance the BFO photocatalytic activity. The obviously stronger optical absorption of Au/BFO observed from the UV-vis diffuse reflectance spectrum confirmed that the surface plasmon resonance (SPR) effect occured on the surface of Au NPs. And the surface plasmon-induced localized electric field could allow the formation of electron/hole pairs in the near surface region of BFO which can migrate to the surface without undergoing electron/hole (e-/h+) pair recombination. The more electrons and holes formed, the more ·OH will be generated to decompose the CR solution. When the gold loading in Au/BFO nanoparticles is 3.36 wt%, the obtained Au/BFO catalyst exhibits best photocatalytic activity evaluated by photocatalysis degradation of Congo red (CR) solution under the visible light irradiation.

  9. Suppression of high transverse momentum π0 spectra in Au + Au collisions at RHIC

    NASA Astrophysics Data System (ADS)

    Kahana, D. E.; Kahana, S. H.

    2008-02-01

    Au + Au, s1/2 = 200 GeV measurements at RHIC, obtained with the PHENIX, STAR, PHOBOS and BRAHMS detectors, have all indicated a suppression of high p⊥ particle production, relative to an appropriately normalized NN level. For central collisions and vanishing pseudo-rapidity these experiments exhibit suppression in charged meson production, especially at medium-to-large transverse momenta. In the PHENIX experiment similar behaviour has been reported for π0 spectra. In a recent work [1] on the simpler D + Au interaction, to be considered perhaps as a tune-up for Au + Au, we reported on a pre-hadronic cascade mechanism which can explain the mixed observation of moderately reduced p⊥ suppression at higher pseudo-rapidity as well as the Cronin enhancement at mid-rapidity. Here, we present the extension of this work to the more massive ion-ion collisions. Our major thesis is that much of the suppression is generated in a late stage cascade of colourless pre-hadrons produced after an initial short-lived coloured phase. We present a pQCD argument to justify this approach and to estimate the time duration τp of this initial phase. Of essential importance is the brevity in time of the coloured phase existence relative to that of the strongly interacting pre-hadron phase, the latter essentially an interactive cascade. These distinctions in phase are of course not strict, but adequate for treating the suppression of moderate and high p⊥ mesons.

  10. Virus-templated Au and Au/Pt Core/shell Nanowires and Their Electrocatalytic Activitives for Fuel Cell Applications

    PubMed Central

    LEE, YOUJIN; KIM, JUNHYUNG; YUN, DONG SOO; NAM, YOON SUNG; SHAO-HORN, YANG; BELCHER, ANGELA M.

    2014-01-01

    A facile synthetic route was developed to make Au nanowires (NWs) from surfactant-mediated bio-mineralization of a genetically engineered M13 phage with specific Au binding peptides. From the selective interaction between Au binding M13 phage and Au ions in aqueous solution, Au NWs with uniform diameter were synthesized at room temperature with yields greater than 98 % without the need for size selection. The diameters of Au NWs were controlled from 10 nm to 50 nm. The Au NWs were found to be active for electrocatalytic oxidation of CO molecules for all sizes, where the activity was highly dependent on the surface facets of Au NWs. This low-temperature high yield method of preparing Au NWs was further extended to the synthesis of Au/Pt core/shell NWs with controlled coverage of Pt shell layers. Electro-catalytic studies of ethanol oxidation with different Pt loading showed enhanced activity relative to a commercial supported Pt catalyst, indicative of the dual functionality of Pt for the ethanol oxidation and Au for the anti-poisoning component of Pt. These new one-dimensional noble metal NWs with controlled compositions could facilitate the design of new alloy materials with tunable properties. PMID:24910712

  11. Reactivity of Two-Dimensional Au9, Pt9, and Au18Pt18 against Common Molecules.

    PubMed

    Takahashi, Lauren; Takahashi, Keisuke

    2016-09-19

    Adsorption of common molecules over two-dimensional Au9, Pt9, and Au18Pt18 is investigated with implementation of first-principles calculations. In general, it is found that Pt9 and Au18Pt18 exhibit low adsorption energies where Au18Pt18 preserves the structural integrity of the molecule and surface. In particular, adsorption of molecules onto Au18Pt18 frequently results in low adsorption energies and high reactivity with minor surface reconstruction of Au18Pt18 and average bond lengths of molecules. The decrease in adsorption energy can be attributed to the presence of platinum, while gold can be considered responsible for structural stability. In addition, molecule dissociation is observed in the cases of H2, HCl, CH4, SO, and SO2 when Pt atoms are involved. Thus, two-dimensional Au9, Pt9, and Au18Pt18 show low adsorption energies against common molecules, reflecting adsorption energies observed in small Au and Pt clusters. These results demonstrate that Au18Pt18 can successfully utilize the low adsorption energies associated with platinum while preserving the integrity of the surface structure using gold atoms, making it possible to adsorb desired molecules using select areas of the Au18Pt18 surface. PMID:27608367

  12. The Magic Au60 Nanocluster: A New Cluster-Assembled Material with Five Au13 Building Blocks.

    PubMed

    Song, Yongbo; Fu, Fangyu; Zhang, Jun; Chai, Jinsong; Kang, Xi; Li, Peng; Li, Shengli; Zhou, Hongping; Zhu, Manzhou

    2015-07-13

    Herein, we report the synthesis and atomic structure of the cluster-assembled [Au60Se2(Ph3P)10(SeR)15](+) material. Five icosahedral Au13 building blocks from a closed gold ring with Au-Se-Au linkages. Interestingly, two Se atoms (without the phenyl tail) locate in the center of the cluster, stabilized by the Se-(Au)5 interactions. The ring-like nanocluster is unprecedented in previous experimental and theoretical studies of gold nanocluster structures. In addition, our optical and electrochemical studies show that the electronic properties of the icosahedral Au13 units still remain unchanged in the penta-twinned Au60 nanocluster, and this new material might be a promising in optical limiting material. This work offers a basis for deep understanding on controlling the cluster-assembled materials for tailoring their functionalities.

  13. Ligand effects on the stability of thiol-stabilized gold nanoclusters: Au25(SR)18-, Au38(SR)24, and Au102(SR)44

    NASA Astrophysics Data System (ADS)

    Jung, Jaehoon; Kang, Sunwoo; Han, Young-Kyu

    2012-06-01

    We have studied the electrochemical and thermodynamic stability of Au25(SR)18-, Au38(SR)24, and Au102(SR)44, R = CH3, C6H13, CH2CH2Ph, Ph, PhF, and PhCOOH, in order to examine ligand effects on the stability of thiol-stabilized gold nanoclusters, Aum(SR)n. Aliphatic thiols, in general, have higher electrochemical and thermodynamic stability than aromatic thiols, and the -SCH2CH2Ph thiol is particularly appealing because of its high electrochemical and thermodynamic stability. The stabilization of Aum by nSR for Aum(SR)n can be rationalized by the stabilization of an Au atom by an SR for the simple molecule AuSR, regardless of interligand interaction and system size and shape. Thiol moieties play a strong role in the electron oxidation and reduction of Aum(SR)n. Accounting for the characteristics of thiol ligands is essential for understanding the electronic and thermodynamic stability of thiol-stabilized gold nanoclusters.We have studied the electrochemical and thermodynamic stability of Au25(SR)18-, Au38(SR)24, and Au102(SR)44, R = CH3, C6H13, CH2CH2Ph, Ph, PhF, and PhCOOH, in order to examine ligand effects on the stability of thiol-stabilized gold nanoclusters, Aum(SR)n. Aliphatic thiols, in general, have higher electrochemical and thermodynamic stability than aromatic thiols, and the -SCH2CH2Ph thiol is particularly appealing because of its high electrochemical and thermodynamic stability. The stabilization of Aum by nSR for Aum(SR)n can be rationalized by the stabilization of an Au atom by an SR for the simple molecule AuSR, regardless of interligand interaction and system size and shape. Thiol moieties play a strong role in the electron oxidation and reduction of Aum(SR)n. Accounting for the characteristics of thiol ligands is essential for understanding the electronic and thermodynamic stability of thiol-stabilized gold nanoclusters. Electronic supplementary information (ESI) available: HOMO, LUMO, and HOMO-LUMO gaps; optimized geometries and radial

  14. Au99(SPh)42 nanomolecules: aromatic thiolate ligand induced conversion of Au144(SCH2CH2Ph)60.

    PubMed

    Nimmala, Praneeth Reddy; Dass, Amala

    2014-12-10

    A new aromatic thiolate protected gold nanomolecule Au99(SPh)42 has been synthesized by reacting the highly stable Au144(SCH2CH2Ph)60 with thiophenol, HSPh. The ubiquitous Au144(SR)60 is known for its high stability even at elevated temperature and in the presence of excess thiol. This report demonstrates for the first time the reactivity of the Au144(SCH2CH2Ph)60 with thiophenol to form a different 99-Au atom species. The resulting Au99(SPh)42 compound, however, is unreactive and highly stable in the presence of excess aromatic thiol. The molecular formula of the title compound is determined by high resolution electrospray mass spectrometry (ESI-MS) and confirmed by the preparation of the 99-atom nanomolecule using two ligands, namely, Au99(SPh)42 and Au99(SPh-OMe)42. This mass spectrometry study is an unprecedented advance in nanoparticle reaction monitoring, in studying the 144-atom to 99-atom size evolution at such high m/z (∼12k) and resolution. The optical and electrochemical properties of Au99(SPh)42 are reported. Other substituents on the phenyl group, HS-Ph-X, where X = -F, -CH3, -OCH3, also show the Au144 to Au99 core size conversion, suggesting minimal electronic effects for these substituents. Control experiments were conducted by reacting Au144(SCH2CH2Ph)60 with HS-(CH2)n-Ph (where n = 1 and 2), bulky ligands like adamantanethiol and cyclohexanethiol. It was observed that conversion of Au144 to Au99 occurs only when the phenyl group is directly attached to the thiol, suggesting that the formation of a 99-atom species is largely influenced by aromaticity of the ligand and less so on the bulkiness of the ligand.

  15. Simulation of Electric Field in Semi Insulating Au/CdTe/Au Detector under Flux

    SciTech Connect

    Franc, J.; James, R.; Grill, R.; Kubat, J.; Belas, E.; Hoschl, P.; Moravec, P.; Praus, P.

    2009-08-02

    We report our simulations on the profile of the electric field in semi insulating CdTe and CdZnTe with Au contacts under radiation flux. The type of the space charge and electric field distribution in the Au/CdTe/Au structure is at high fluxes result of a combined influence of charge formed due to band bending at the electrodes and from photo generated carriers, which are trapped at deep levels. Simultaneous solution of drift-diffusion and Poisson equations is used for the calculation. We show, that the space charge originating from trapped photo-carriers starts to dominate at fluxes 10{sup 15}-10{sup 16}cm{sup -2}s{sup -1}, when the influence of contacts starts to be negligible.

  16. Electrochemical responses and electrocatalysis at single au nanoparticles.

    PubMed

    Li, Yongxin; Cox, Jonathan T; Zhang, Bo

    2010-03-10

    Steady-state electrochemical responses have been obtained at single Au nanoparticles using Pt nanoelectrodes. A Au single-nanoparticle electrode (SNPE) is constructed by chemically immobilizing a single Au nanoparticle at a SiO(2)-encapsulated Pt disk nanoelectrode, which was previously modified by an amine-terminated silane. The Au SNPE has been characterized by transmission electron microscopy, underpotential deposition of Cu, and steady-state cyclic voltammetry. It has been found that the presence of a single Au nanoparticle enhances the electron transfer from the Pt nanoelectrode to the redox molecules, and the voltammetric response at the Au SNPE depends on the size of the Au nanoparticle. The Au SNPE has been utilized to examine the oxygen-reduction reaction in a KOH solution to explore the feasibility of measuring the electrocatalytic activity at a single-nanoparticle level. It has been shown that the electrocatalytic activity of single Au nanoparticles can be directly measured using SNPEs, and the electrocatalytic activity is dependent on the size of the Au nanoparticles. This study can help to understand the structure-function relationship in nanoparticle-based electrocatalysis.

  17. Mecanismes de deformation de nanoparticules d'Au par irradiation ionique

    NASA Astrophysics Data System (ADS)

    Harkati Kerbouah, Chahineze

    2011-12-01

    In the present thesis, we study the anisotropic deformation of gold nanoparticles embedded in amorphous silica or crystalline aluminum arsenide, under ion bombardment. We try to comprehend the mechanism responsible for this deformation and to remove any ambiguity related to the explanation of this phenomenon. A hybrid process combining sputtering and plasma enhanced chemical vapour deposition was used to fabricate Au/SiO2 layers on fused silica substrates. Structures with single and multilayer were obtained. Heating during or after deposition activates the Au atom agglomeration and favours the growth of the nanoparticles. Also, a Au/AlAs nanocomposite was obtained by ion implantation of AlAs films, followed by rapid thermal annealing. The samples of the two nanocomposites, cooled with liquid nitrogen, were irradiated with 2 to 40 MeV Cu, Si, Au or In ion beams, at fluences ranging from 1x10 13 to 4x1015 ions/cm2, using a Tandem or Tandetron accelerator. The structural and morphological properties of the Au/SiO2 nanocomposite were extracted by optical means; the frequency and the width of surface plasmon resonance band depend on the nanoparticle shape and size, their concentration, the inter-particle distance and the dielectric properties of material in which the particles are embedded. The aluminum arsenide crystallinity was studied by two techniques: Raman spectroscopy and Rutherford backscattering spectrometry in channelling configuration (RBS/ channelling). The Au concentration in the nanocomposite layers was deducted from RBS results. The size distribution and metallic nanoparticles shape transformation in both nanocomposites were observed by electronic transmission microscopy. The results obtained within the framework of this work are the subject of three journal papers. The first publication shows the possibility of manipulating the width and spectral position of the gold nanoparticle absorption band in Au/SiO2 nanocomposites by modifying their structure

  18. Manipulation of superparamagnetic beads on patterned Au/Co/Au multilayers with perpendicular magnetic anisotropy

    NASA Astrophysics Data System (ADS)

    Jarosz, A.; Holzinger, D.; Urbaniak, M.; Ehresmann, A.; Stobiecki, F.

    2016-08-01

    The magnetophoresis of water-suspended 4 μm-diameter superparamagnetic beads above topographically patterned, sputter deposited Ti(4 nm)/Au(60 nm)/[Co(0.7 nm)/Au(1 nm)] × 3 multilayers with perpendicular magnetic anisotropy was investigated. The results impressively demonstrate that the magnetic stray field landscape above the stripe structure when superimposed with an external, slowly rotating, field enables the directed transport of magnetic beads across the stripe panel with velocities up to 12 μm s-1.

  19. Steering epitaxial alignment of Au, Pd, and AuPd nanowire arrays by atom flux change.

    PubMed

    Yoo, Youngdong; Seo, Kwanyong; Han, Sol; Varadwaj, Kumar S K; Kim, Hyun You; Ryu, Ji Hoon; Lee, Hyuck Mo; Ahn, Jae Pyoung; Ihee, Hyotcherl; Kim, Bongsoo

    2010-02-10

    We have synthesized epitaxial Au, Pd, and AuPd nanowire arrays in vertical or horizontal alignment on a c-cut sapphire substrate. We show that the vertical and horizontal nanowire arrays grow from half-octahedral seeds by the correlations of the geometry and orientation of seed crystals with those of as-grown nanowires. The alignment of nanowires can be steered by changing the atom flux. At low atom deposition flux vertical nanowires grow, while at high atom flux horizontal nanowires grow. Similar vertical/horizontal epitaxial growth is also demonstrated on SrTiO(3) substrates. This orientation-steering mechanism is visualized by molecular dynamics simulations.

  20. Admittance of Au/1,4-benzenedithiol/Au single-molecule junctions

    NASA Astrophysics Data System (ADS)

    Yamauchi, Kazumasa; Kurokawa, Shu; Sakai, Akira

    2012-12-01

    Employing the admittance formula for double-barrier junctions [Fu and Dudley, Phys. Rev. Lett. 70, 65 (1993)], we have estimated an ac susceptance (imaginary part of admittance) of Au/1,4-benzenedithiol/Au single-molecule junctions from their current-voltage characteristics. In the MHz regime, we find that the junction susceptance shows a very small (˜0.1 aF) capacitive component that can be entirely masked by a larger electrode capacitance. Direct ac signal transmission measurements up to 1 GHz reveal no molecular signals and confirm the smallness of the molecular capacitance in the MHz regime.

  1. Two-Particle Interferometry of 200 GeV Au+Au Collisions at PHENIX

    SciTech Connect

    Heffner, M

    2004-04-19

    The PHENIX experiment has measured pion-pion, kaon-kaon, and proton-proton correlations in Au+Au collisions at {radical}S{sub NN} = 200GeV. The correlations are fit to extract radii using both the Bowler Coulomb correction and full calculation of the two-particle wave function. The resulting radii are similar for all three species and decrease with increasing k{sub t} as expected for collective flow. The R{sub out} and R{sub side} radii are approximately equal indicating a short emission duration.

  2. Beam Energy Scan a Case for the Chiral Magnetic Effect in Au-Au Collisions

    SciTech Connect

    Longacre, R.

    2014-01-05

    The Chiral Magnetic Effect (CME) is predicted for Au-Au collisions at RHIC. However, many backgrounds can give signals that make the measurement hard to interpret. The STAR experiment has made measurements at different collisions energy ranging from √(sNN)=7.7 GeV to 62.4 GeV. In the analysis that is presented we show that the CME turns on with energy and is not present in central collisions where the induced magnetic is small.

  3. Relativistic multireference many-body perturbation theory calculations on Au64+ - Au69+ ions

    SciTech Connect

    Vilkas, M J; Ishikawa, Y; Trabert, E

    2006-03-31

    Many-body perturbation theory (MBPT) calculations are an adequate tool for the description of the structure of highly charged multi-electron ions and for the analysis of their spectra. They demonstrate this by way of a re-investigation of n=3, {Delta}n=0 transitions in the EUV spectra of Na-, Mg-, Al-like, and Si-like ions of Au that have been obtained previously by heavy-ion accelerator based beam-foil spectroscopy. They discuss the evidence and propose several revisions on the basis of the multi-reference many-body perturbation theory calculations of Ne- through P-like ions of Au.

  4. Gold nanoparticle (AuNPs) and gold nanopore (AuNPore) catalysts in organic synthesis.

    PubMed

    Takale, Balaram S; Bao, Ming; Yamamoto, Yoshinori

    2014-04-01

    Organic synthesis using gold has gained tremendous attention in last few years, especially heterogeneous gold catalysis based on gold nanoparticles has made its place in almost all organic reactions, because of the robust and green nature of gold catalysts. In this context, gold nanopore (AuNPore) with a 3D metal framework is giving a new dimension to heterogeneous gold catalysts. Interestingly, AuNPore chemistry is proving better than gold nanoparticles based chemistry. In this review, along with recent advances, major discoveries in heterogeneous gold catalysis are discussed.

  5. Charged particle multiplicities in ultra-relativistic Au+Au and Cu+Cu collisions.

    SciTech Connect

    Alver, B.; Back, B. B.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; PHOBOS Collaboration; Physics; Massachusetts Inst. of Tech.; BNL

    2006-01-01

    The PHOBOS collaboration has carried out a systematic study of charged particle multiplicities in Cu+Cu and Au+Au collisions at the Relativistic Heavy-Ion Collider (RHIC) at Brookhaven National Laboratory. A unique feature of the PHOBOS detector is its ability to measure charged particles over a very wide angular range from 0.5 to 179.5 deg. corresponding to |eta|<5.4. The general features of the charged particle multiplicity distributions as a function of pseudo-rapidity, collision energy and centrality, as well as system size, are discussed.

  6. Au/Pd core-shell nanoparticles with varied hollow Au cores for enhanced formic acid oxidation

    NASA Astrophysics Data System (ADS)

    Hsu, Chiajen; Huang, Chienwen; Hao, Yaowu; Liu, Fuqiang

    2013-03-01

    A facile method has been developed to synthesize Au/Pd core-shell nanoparticles via galvanic replacement of Cu by Pd on hollow Au nanospheres. The unique nanoparticles were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, ultraviolet-visible spectroscopy, and electrochemical measurements. When the concentration of the Au solution was decreased, grain size of the polycrystalline hollow Au nanospheres was reduced, and the structures became highly porous. After the Pd shell formed on these Au nanospheres, the morphology and structure of the Au/Pd nanoparticles varied and hence significantly affected the catalytic properties. The Au/Pd nanoparticles synthesized with reduced Au concentrations showed higher formic acid oxidation activity (0.93 mA cm-2 at 0.3 V) than the commercial Pd black (0.85 mA cm-2 at 0.3 V), suggesting a promising candidate as fuel cell catalysts. In addition, the Au/Pd nanoparticles displayed lower CO-stripping potential, improved stability, and higher durability compared to the Pd black due to their unique core-shell structures tuned by Au core morphologies.

  7. Electrostatic assembles and optical properties of Au CdTe QDs and Ag/Au CdTe QDs

    NASA Astrophysics Data System (ADS)

    Yang, Dongzhi; Wang, Wenxing; Chen, Qifan; Huang, Yuping; Xu, Shukun

    2008-09-01

    Au-CdTe and Ag/Au-CdTe assembles were firstly investigated through the static interaction between positively charged cysteamine-stabilized CdTe quantum dots (QDs) and negatively charged Au or core/shell Ag/Au nano-particles (NCs). The CdTe QDs synthesized in aqueous solution were capped with cysteamine which endowed them positive charges on the surface. Both Au and Ag/Au NCs were prepared through reducing precursors with gallic acid obtained from the hydrolysis of natural plant poly-phenols and favored negative charges on the surface of NCs. The fluorescence spectra of CdTe QDs exhibited strong quenching with the increase of added Au or Ag/Au NCs. Railey resonance scattering spectra of Au or Ag/Au NCs increased firstly and decreased latter with the concentration of CdTe QDs, accompanied with the solution color changing from red to purple and colorless at last. Experimental results on the effects of gallic acid, chloroauric acid tetrahydrate and other reagents demonstrated the static interaction occurred between QDs and NCs. This finding reveals the possibilities to design and control optical process and electromagnetic coupling in hybrid structures.

  8. Au/Pd core-shell nanoparticles with varied hollow Au cores for enhanced formic acid oxidation.

    PubMed

    Hsu, Chiajen; Huang, Chienwen; Hao, Yaowu; Liu, Fuqiang

    2013-03-01

    A facile method has been developed to synthesize Au/Pd core-shell nanoparticles via galvanic replacement of Cu by Pd on hollow Au nanospheres. The unique nanoparticles were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, ultraviolet-visible spectroscopy, and electrochemical measurements. When the concentration of the Au solution was decreased, grain size of the polycrystalline hollow Au nanospheres was reduced, and the structures became highly porous. After the Pd shell formed on these Au nanospheres, the morphology and structure of the Au/Pd nanoparticles varied and hence significantly affected the catalytic properties. The Au/Pd nanoparticles synthesized with reduced Au concentrations showed higher formic acid oxidation activity (0.93 mA cm-2 at 0.3 V) than the commercial Pd black (0.85 mA cm-2 at 0.3 V), suggesting a promising candidate as fuel cell catalysts. In addition, the Au/Pd nanoparticles displayed lower CO-stripping potential, improved stability, and higher durability compared to the Pd black due to their unique core-shell structures tuned by Au core morphologies.

  9. Au/Pd core-shell nanoparticles with varied hollow Au cores for enhanced formic acid oxidation

    PubMed Central

    2013-01-01

    A facile method has been developed to synthesize Au/Pd core-shell nanoparticles via galvanic replacement of Cu by Pd on hollow Au nanospheres. The unique nanoparticles were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, ultraviolet–visible spectroscopy, and electrochemical measurements. When the concentration of the Au solution was decreased, grain size of the polycrystalline hollow Au nanospheres was reduced, and the structures became highly porous. After the Pd shell formed on these Au nanospheres, the morphology and structure of the Au/Pd nanoparticles varied and hence significantly affected the catalytic properties. The Au/Pd nanoparticles synthesized with reduced Au concentrations showed higher formic acid oxidation activity (0.93 mA cm-2 at 0.3 V) than the commercial Pd black (0.85 mA cm-2 at 0.3 V), suggesting a promising candidate as fuel cell catalysts. In addition, the Au/Pd nanoparticles displayed lower CO-stripping potential, improved stability, and higher durability compared to the Pd black due to their unique core-shell structures tuned by Au core morphologies. PMID:23452438

  10. Atomic and molecular adsorption on Au(111)

    SciTech Connect

    Santiago-Rodríguez, Yohaselly; Herron, Jeffrey A.; Curet-Arana, María C.; Mavrikakis, Manos

    2014-09-01

    Periodic self-consistent density functional theory (DFT-GGA) calculations were used to study the adsorption of several atomic species, molecular species and molecular fragments on the Au(111) surface with a coverage of 1/4 monolayer (ML). Binding geometries, binding energies, and diffusion barriers were calculated for 27 species. Furthermore, we calculated the surface deformation energy associated with the binding events. The binding strength for all the analyzed species can be ordered as follows: NH3 < NO < CO < CH3 < HCO < NH2 < COOH < OH < HCOO < CNH2 < H < N < NH < NOH < COH < Cl,< HCO3 < CH2 < CN b HNO < O < F < S < C < CH. Although the atomic species preferred to bind at the three-fold fcc site, no tendency was observed in site preference for the molecular species and fragments. The intramolecular and adsorbate-surface vibrational frequencies were calculated for all the adsorbates on their most energetically stable adsorption site. Most of the theoretical binding energies and frequencies agreed with experimental values reported in the literature. In general, the values obtained with the PW91 functional are more accurate than RPBE in reproducing these experimental binding energies. The energies of the adsorbed species were used to calculate the thermochemical potential energy surfaces for decomposition of CO, NO, N2, NH3 and CH4, oxidation of CO, and hydrogenation of CO, CO2 and NO, giving insight into the thermochemistry of these reactions on gold nanoparticles. These potential energy surfaces demonstrated that: the decomposition of species is not energetically favorable on Au(111); the desorption of NH3, NO and CO are more favorable than their decomposition; the oxidation of CO and hydrogenation of CO and NO on Au(111) to form HCO and HNO, respectively, are also thermodynamically favorable.

  11. Anomalous magnetic moment at Ba in Au

    NASA Astrophysics Data System (ADS)

    Bhati, A. K.; Kaur, J.; Bansal, N.; Negi, D.; Kumar, R.; Bhowmik, R. K.; Kumar, V.; Dey, C. C.

    2015-04-01

    The Time differential perturbed angular distribution (TDPAD) technique is employed to measure the local susceptibility at the recoil implanted Ba ions in Au following the nuclear reaction 120Sn(12C, 3nγ)129Ba. We have observed first time the local paramagnetic susceptibility of 5.26(18) at Ba ions comparable to 4f-ions in any non-ferromagnetic metal at room temperature which seems to be related to the electronic s-d and s-f transfer at positive lattice pressure.

  12. Photosynthetic electron transport system promotes synthesis of Au-nanoparticles.

    PubMed

    Shabnam, Nisha; Pardha-Saradhi, P

    2013-01-01

    In this communication, a novel, green, efficient and economically viable light mediated protocol for generation of Au-nanoparticles using most vital organelle, chloroplasts, of the plant system is portrayed. Thylakoids/chloroplasts isolated from Potamogeton nodosus (an aquatic plant) and Spinacia oleracea (a terrestrial plant) turned Au³⁺ solutions purple in presence of light of 600 µmol m⁻² s⁻¹ photon flux density (PFD) and the purple coloration intensified with time. UV-Vis spectra of these purple colored solutions showed absorption peak at ∼545 nm which is known to arise due to surface plasmon oscillations specific to Au-nanoparticles. However, thylakoids/chloroplasts did not alter color of Au³⁺ solutions in dark. These results clearly demonstrated that photosynthetic electron transport can reduce Au³⁺ to Au⁰ which nucleate to form Au-nanoparticles in presence of light. Transmission electron microscopic studies revealed that Au-nanoparticles generated by light driven photosynthetic electron transport system of thylakoids/chloroplasts were in range of 5-20 nm. Selected area electron diffraction and powder X-ray diffraction indicated crystalline nature of these nanoparticles. Energy dispersive X-ray confirmed that these nanoparticles were composed of Au. To confirm the potential of light driven photosynthetic electron transport in generation of Au-nanoparticles, thylakoids/chloroplasts were tested for their efficacy to generate Au-nanoparticles in presence of light of PFD ranging from 60 to 600 µmol m⁻² s⁻¹. The capacity of thylakoids/chloroplasts to generate Au-nanoparticles increased remarkably with increase in PFD, which further clearly demonstrated potential of light driven photosynthetic electron transport in reduction of Au³⁺ to Au⁰ to form nanoparticles. The light driven donation of electrons to metal ions by thylakoids/chloroplasts can be exploited for large scale production of nanoparticles. PMID:23976990

  13. Photosynthetic electron transport system promotes synthesis of Au-nanoparticles.

    PubMed

    Shabnam, Nisha; Pardha-Saradhi, P

    2013-01-01

    In this communication, a novel, green, efficient and economically viable light mediated protocol for generation of Au-nanoparticles using most vital organelle, chloroplasts, of the plant system is portrayed. Thylakoids/chloroplasts isolated from Potamogeton nodosus (an aquatic plant) and Spinacia oleracea (a terrestrial plant) turned Au³⁺ solutions purple in presence of light of 600 µmol m⁻² s⁻¹ photon flux density (PFD) and the purple coloration intensified with time. UV-Vis spectra of these purple colored solutions showed absorption peak at ∼545 nm which is known to arise due to surface plasmon oscillations specific to Au-nanoparticles. However, thylakoids/chloroplasts did not alter color of Au³⁺ solutions in dark. These results clearly demonstrated that photosynthetic electron transport can reduce Au³⁺ to Au⁰ which nucleate to form Au-nanoparticles in presence of light. Transmission electron microscopic studies revealed that Au-nanoparticles generated by light driven photosynthetic electron transport system of thylakoids/chloroplasts were in range of 5-20 nm. Selected area electron diffraction and powder X-ray diffraction indicated crystalline nature of these nanoparticles. Energy dispersive X-ray confirmed that these nanoparticles were composed of Au. To confirm the potential of light driven photosynthetic electron transport in generation of Au-nanoparticles, thylakoids/chloroplasts were tested for their efficacy to generate Au-nanoparticles in presence of light of PFD ranging from 60 to 600 µmol m⁻² s⁻¹. The capacity of thylakoids/chloroplasts to generate Au-nanoparticles increased remarkably with increase in PFD, which further clearly demonstrated potential of light driven photosynthetic electron transport in reduction of Au³⁺ to Au⁰ to form nanoparticles. The light driven donation of electrons to metal ions by thylakoids/chloroplasts can be exploited for large scale production of nanoparticles.

  14. Evaluation of the Olympus AU 400 clinical chemistry analyzer.

    PubMed

    Bilić, A; Alpeza, I; Rukavina, A S

    2000-01-01

    The performance of the Olympus AU 400 clinical chemistry analyzer was evaluated according to the guidelines of the European Committee for Clinical Laboratory Standards. The following analytes were tested: glucose, urea, creatinine, calcium, AST, ALT, CK, LDH, ALP and amylase. The Olympus AU 400 was compared with the Olympus AU 800. Coefficients of correlation showed high correlation between the compared analyzers. Other performances (intra- and inter-assay variation, carry-over and interferences) of the analyzer were satisfactory.

  15. Systematic studies of the centrality dependence of soft photon production in Au + Au collision with PHENIX

    NASA Astrophysics Data System (ADS)

    Bannier, Benjamin

    2014-11-01

    Since the earliest days of Heavy Ion Physics thermal soft photon radiation emitted during the reaction had been theorized as a smoking gun signal for formation of a quark-gluon plasma and as a tool to characterize its properties. In recent years the existence of excess photon radiation in heavy ion collisions over the expectation from initial hard interactions has been confirmed at both RHIC and LHC energies by PHENIX and ALICE respectively. There the radiation has been found to exhibit elliptic flow v2 well above what can currently be reconciled with a picture of early emission from a plasma phase. During the 2007 and 2010 Au + Au runs PHENIX has measured a high purity sample of soft photons down to pT > 0.4 GeV / c using an external conversion method. We present recent systematic studies by PHENIX from that sample on the centrality dependence of the soft photon yield, and elliptic and triangular flow v2 and v3 in Au + Au collisions which fill in the experimental picture and enable discrimination of competing soft photon production scenarios.

  16. Degree of chemical nonequilibrium in central Au-Au collisions at RHIC energies

    NASA Astrophysics Data System (ADS)

    Tawfik, Abdel Nasser; El-Bakry, M. Y.; Habashy, D. M.; Mohamed, M. T.; Abbas, Ehab

    2015-08-01

    In this paper, we investigate the difference between hadron resonance gas (HRG) calculations for chemical freeze-out parameters at fully and partly chemical equilibria. To this end, the results are compared with the particle ratios measured in central Au-Au collisions at a wide range of nucleon-nucleon center-of-mass energies, √ {s{ NN}} = 7.7 - 200 GeV as offered by the STAR experiment. We restrict the discussion to STAR, because of large statistics and overall homogeneity of STAR measurements (one detector) against previous experiments. We find that the matter produced at these energies is likely in fully chemical equilibria, which is consistent with recent lattice quantum chromodynamics (QCD) results. The possible improvements by partial chemical equilibria (γS ≠ 1) are very limited. We also discuss these results with the ones deduced from ϕ/π- and Ω-/π- ratios. These hadron ratios are sensitive to the degree of chemical equilibrium. Accordingly, the conclusion that the matter produced reaches fully chemical equilibria in central Au-Au at relativistic heavy-ion collider (RHIC) energies is confirmed.

  17. "Au Revoir" to Film Illiteracy: An Interdisciplinary Exploration of "Au Revior Les Enfants."

    ERIC Educational Resources Information Center

    Corbitt, J. Catherine

    1998-01-01

    Discusses the power of film and films as teaching tools. Describes how the 1987 French film "Au Revior Les Enfants" can serve these purposes. Discusses its historical context, and ways to show the film in class. Lists numerous topics (on important film themes, and on technical aspects of film) for student projects. (SR)

  18. Charged-particle rapidity density in Au+Au collisions in a quark combination model

    NASA Astrophysics Data System (ADS)

    Shao, Feng-Lan; Yao, Tao; Xie, Qu-Bing

    2007-03-01

    Rapidity/pseudorapidity densities for charged particles and their centrality, rapidity, and energy dependence in Au+Au collisions at the Relativistic Heavy Ion Collider are studied in a quark combination model. Using a Gaussian-type rapidity distribution for constituent quarks as a result of Landau hydrodynamic evolution, the data at sNN=130,200 GeV at various centralities in full pseudorapidity range are well described, and the charged-particle multiplicities are reproduced as functions of the number of participants. The energy dependence of the shape of the dNch/dη distribution is also described at various collision energies sNN=200,130,62.4 GeV in central collisions with same value of parameters except 19.6 GeV. The calculated rapidity distributions and yields for the charged pions and kaons in central Au+Au collisions at sNN=200 GeV are compared with experimental data of the BRAHMS Collaboration.

  19. Divided café-au-lait macule of the mouth.

    PubMed

    Sergay, Amanda; Silverberg, Nanette B

    2007-05-01

    We describe a 4-year-old, otherwise healthy boy with a congenital history of a perioral and labial segmental café-au-lait macule, who was noted to have unilateral localized gingival hyperpigmentation that aligned with the café-au-lait macule. This case is highly illustrative of the embryologic timing of the genetic event locally, which leads to café-au-lait type hyperpigmentation. Because the facial features and the ectoderm overlying the facial muscles develop around the third to fourth week of gestation, the distribution of this café-au-lait macule suggests development at the same time.

  20. Enhanced photoluminescence in Au-embedded ITO nanowires.

    PubMed

    Kim, Hyunsu; Park, Sunghoon; Jin, Changhyun; Lee, Chongmu

    2011-12-01

    Gold (Au)-embedded indium tin oxide (ITO) nanowires were synthesized by thermal evaporation of a mixture of In(2)O(3,) SnO(2) and graphite powders on Si (100) substrates coated with Au thin films followed by annealing. At the initial stages of annealing, Au formed a continuous linear core located along the long axis of each ITO nanowire. The morphology of the Au core changed from a continuous line to a discrete line, and then to a droplet-like chain, finally evolving into a peapod in which crystalline Au nanoparticles were encapsulated in crystalline ITO with increasing annealing temperature. The ITO nanowires with the Au core showed an emission band at ~380 nm in the ultraviolet region. The ultraviolet emission intensity increased rapidly with increasing annealing temperature. The intensity of emission from the Au-peapod ITO nanowires (annealed at 750 °C) was approximately 20 times higher than that of the emission from the Au-core/ITO-shell ITO nanowires with a continuous linear shaped-Au core (annealed at 550 °C). This ultraintense ultraviolet emission might have originated mainly from the enhanced crystalline quality of the annealed ITO nanowires. PMID:22087582

  1. Heatless synthesis of well dispersible Au nanoparticles using pectin biopolymer.

    PubMed

    Ahmed, Hanan B; Zahran, M K; Emam, Hossam E

    2016-10-01

    Due to its potency to utilize in enormous applications, preparation of nanogold is of interest. Moreover, getting of highly dispersed nanogold with small size is extremely needful in specific fields. Herein, Au nanocolloid was prepared using alkali catalyzed pectin biopolymer. Pectin was concurrently used as reductant for Au ions and stabilizer for the produced Au nanoparticles (AuNPs). Reducing sugars were evaluated in the colloidal solution reflecting the role alkali in catalytic degradation of pectin to produce much powerful reducing moieties. The obtained Au nanocolloid was monitored via changing in color, UV-visible spectral and transmission electron microscopy. Using of NaOH as strong alkali achieving rapid rate of degradation reaction, resulted in 0.45g/L reducing sugars from 0.2g/L pectin which produced AuNPs with mean size of 6.5nm. In case of Na2CO3 which attained slow degradation rate led to, slightly low reducing sugar content (0.41g/L), fabricated comparatively size of AuNPs (7.5nm). In both cases, well distributed AuNPs was obtained with suitable stabilization up to 5 months and Na2CO3 exhibited higher stability. The current successful method used to produce small sized AuNPs with high dispersion is an innovative, one-step, easily, costless, energy saving and eco-friendly method.

  2. An Exploration of Catalytic Chemistry on Au/Ni(111)

    SciTech Connect

    Sylvia T. Ceyer

    2011-12-09

    This project explored the catalytic oxidation chemistry that can be effected on a Au/Ni(111) surface alloy. A Au/Ni(111) surface alloy is a Ni(111) surface on which less than 60% of the Ni atoms are replaced at random positions by Au atoms. The alloy is produced by vapor deposition of a small amount of Au onto Ni single crystals. The Au atoms do not result in an epitaxial Au overlayer or in the condensation of the Au into droplets. Instead, Au atoms displace and then replace Ni atoms on a Ni(111) surface, even though Au is immiscible in bulk Ni. The two dimensional structure of the clean Ni surface is preserved. This alloy is found to stabilize an adsorbed peroxo-like O2 species that is shown to be the critical reactant in the low temperature catalytic oxidation of CO and that is suspected to be the critical reactant in other oxidation reactions. This investigation revealed a new, practically important catalyst for CO oxidation that has since been patented.

  3. Preparations for p-Au run in 2015

    SciTech Connect

    Liu, C.

    2014-12-31

    The p-Au particle collision is a unique category of collision runs. This is resulted from the different charge mass ratio of the proton and fully stripped Au ion (1 vs.79/197). The p-Au run requires a special acceleration ramp, and movement of a number of beam components as required by the beam trajectories. The DX magnets will be moved for the first time in the history of RHIC. In this note, the planning and preparations for p-Au run will be presented.

  4. Heatless synthesis of well dispersible Au nanoparticles using pectin biopolymer.

    PubMed

    Ahmed, Hanan B; Zahran, M K; Emam, Hossam E

    2016-10-01

    Due to its potency to utilize in enormous applications, preparation of nanogold is of interest. Moreover, getting of highly dispersed nanogold with small size is extremely needful in specific fields. Herein, Au nanocolloid was prepared using alkali catalyzed pectin biopolymer. Pectin was concurrently used as reductant for Au ions and stabilizer for the produced Au nanoparticles (AuNPs). Reducing sugars were evaluated in the colloidal solution reflecting the role alkali in catalytic degradation of pectin to produce much powerful reducing moieties. The obtained Au nanocolloid was monitored via changing in color, UV-visible spectral and transmission electron microscopy. Using of NaOH as strong alkali achieving rapid rate of degradation reaction, resulted in 0.45g/L reducing sugars from 0.2g/L pectin which produced AuNPs with mean size of 6.5nm. In case of Na2CO3 which attained slow degradation rate led to, slightly low reducing sugar content (0.41g/L), fabricated comparatively size of AuNPs (7.5nm). In both cases, well distributed AuNPs was obtained with suitable stabilization up to 5 months and Na2CO3 exhibited higher stability. The current successful method used to produce small sized AuNPs with high dispersion is an innovative, one-step, easily, costless, energy saving and eco-friendly method. PMID:27212212

  5. Enhanced ultraviolet photoresponse in Au/ZnO nanorods

    NASA Astrophysics Data System (ADS)

    Mahanti, Moumita; Basak, Durga

    2014-09-01

    ZnO nanorods (NRs) have been decorated by Au nanoparticles (NPs) by a chemical method. The ultraviolet (UV) photoresponse of Au/ZnO NRs has been investigated. As the loading of Au NPs increases, the photocurrent as well as the photo-to-dark current ratio (gain) increases attaining a maximum gain value which is ∼15 times higher than that of the pristine ZnO NRs. Photoresponse enhancement is probably due to efficient separation of photo-generated electron-holes by an enhanced electric field and hot carrier injection over the Au localized Schottky junctions.

  6. Heterostructured Au/Pd-M (M = Au, Pd, Pt) nanoparticles with compartmentalized composition, morphology, and electrocatalytic activity.

    PubMed

    Lutz, Patrick S; Bae, In-Tae; Maye, Mathew M

    2015-10-14

    The synthesis, processing, and galvanic exchange of three heterostructured nanoparticle systems is described. The surface accessibility and redox potential of a Au/Pd-Ag dumbbell nanoparticle, where a Au/Pd core/shell region, and a silver region make up the domains, was used to prepare the new nanostructures with controlled composition, morphology, and microstructure. Results indicate that the silver domain was particularly susceptible to galvanic displacement, and was exchanged to Au/Pd-M (M = Au, Pd, Pt). Interestingly, the dumbbell morphology remained after exchange, and the silver region was transformed to hollow, parachute, or concentric domains respectively. The morphology and microstructure change was visualized via TEM and HRTEM, and the composition changes were probed via STEM-EDS imaging and XPS. The electrocatalytic activity of the Au/Pd-M towards methanol oxidation was studied, with results indicating that the Au/Pd-Pt nanoparticles had high activity attributed to the porous nature of the platinum domains. PMID:26351824

  7. Baryon Stopping in Au+Au and p+p collisions at 62 and 200 GeV

    NASA Astrophysics Data System (ADS)

    Brahms Collaboration; Dalsgaard, Hans Hjersing; BRAHMS Collaboration

    2009-11-01

    BRAHMS has measured rapidity density distributions of protons and antiprotons in both p+p and Au+Au collisions at 62 GeV and 200 GeV. From these distributions the yields of so-called ‘net-protons’, that is the difference between the proton and antiproton yields, can be determined. The rapidity dependence of the net-proton yields from peripheral Au+Au collisions is found to have a similar behaviour to that found for the p+p results, while a quite different rapidity dependence is found for central Au+Au collisions. The net-proton distributions can be used together with model calculations to find the net-baryon yields as a function of rapidity, thus yielding information on the average rapidity loss of beam particles, the baryon transport properties of the medium, and the amount of ‘stopping’ in these collisions.

  8. Component conversion from pure Au nanorods to multiblock Ag-Au-Ag nanorods assisted by Pt nanoframe templates

    NASA Astrophysics Data System (ADS)

    Lee, Sangji; Jang, Hee-Jeong; Jang, Ho Young; Kim, Seong Kyu; Park, Sungho

    2016-06-01

    We developed a new method for synthesizing multiblock Ag-Au-Ag nanorods using Pt nanoframes that had been deposited on the edges of Au nanorod seeds. As a function of Au etching time, the length of the Au nanorod decreased symmetrically starting from the two ends, leading to the formation of empty inner space at the ends. Subsequent reduction of Ag ions could be selectively performed in the inner space confined by Pt nanoframes and the resulting Ag-Au-Ag nanorods exhibited characteristic LSPR modes originating from each block component (in a transverse direction) and SPR coupling (in a longitudinal direction). The high quality of the resulting multiblock nanorods enabled observation of the longitudinal quadrupole mode that was induced by Ag-Au SPR coupling in a long axis. The mode exhibited high sensitivity in accordance with the change in the surrounding media, demonstrating great potential for sensor applications.We developed a new method for synthesizing multiblock Ag-Au-Ag nanorods using Pt nanoframes that had been deposited on the edges of Au nanorod seeds. As a function of Au etching time, the length of the Au nanorod decreased symmetrically starting from the two ends, leading to the formation of empty inner space at the ends. Subsequent reduction of Ag ions could be selectively performed in the inner space confined by Pt nanoframes and the resulting Ag-Au-Ag nanorods exhibited characteristic LSPR modes originating from each block component (in a transverse direction) and SPR coupling (in a longitudinal direction). The high quality of the resulting multiblock nanorods enabled observation of the longitudinal quadrupole mode that was induced by Ag-Au SPR coupling in a long axis. The mode exhibited high sensitivity in accordance with the change in the surrounding media, demonstrating great potential for sensor applications. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr03484e

  9. Ordered arrays of Au catalysts by FIB assisted heterogeneous dewetting

    NASA Astrophysics Data System (ADS)

    Benkouider, A.; Ronda, A.; David, T.; Favre, L.; Abbarchi, M.; Naffouti, M.; Osmond, J.; Delobbe, A.; Sudraud, P.; Berbezier, I.

    2015-12-01

    Synthesizing Au0.8Si0.2 nanocatalysts that are homogeneous in size and have controlled position is becoming a challenging and crucial prequisite for the fabrication of ordered semiconductor nanowires. In this study, Au0.8Si0.2 nanocatalysts are synthesized via dewetting of Au layers on Si(111) during thermal annealing in an ultra-high vacuum. In the first part of the paper, the mechanism of homogeneous dewetting is analyzed as a function of the Au-deposited thickness (h Au). We distinguish three different dewetting regimes: (I) for a low thickness ({h}{{Au}}≤slant 0.4 {nm}), a submonolyer coverage of Au is stabilized and there is no dewetting. (II) For an intermediate thickness (0.4 {nm}\\lt {h}{Au}≤slant 5 {nm}), there is both dewetting and Au0.8Si0.2 phase formation. The size and density of the Au0.8Si0.2 clusters are directly related to h Au. When cooling down to room temperature, the clusters decompose and reject the Si at the Au/Si substrate interface. (III) For a large thickness ({h}{{Au}}\\gt 5 {nm}), only dewetting takes place, without forming AuSi clusters. In this regime, the dewetting is kinetically controlled by the self-diffusion of Au (activation energy ∼0.43 eV) without evidence of an Si-alloying effect. As a practical consequence, when relying solely on the homogeneous dewetting of Au/Si(111) to form the Au0.8Si0.2 catalysts (without a supply of Si atoms from vapor), regime II should be used to obtain good size and density control. In the second part of the paper, a process for ordering the catalysts using focused ion beam-(FIB) assisted dewetting (heterogeneous dewetting) is developed. We show that no matter what the FIB milling conditions and the Au nominal thickness are, dewetting is promoted by ion beam irradiation and is accompanied by the formation of Au0.8Si0.2 droplets. The droplets preferentially form on the patterned areas, while in similar annealing conditions, they do not form on the unpatterned areas. This behavior is attributed

  10. Gold Apes Hydrogen. The Structure and Bonding in the Planar B7Au2- and B7Au2 Clusters

    SciTech Connect

    Zhai, Hua JIN.; Wang, Lai S.; Zubarev, Dmitry Y.; Boldyrev, Alexander I.

    2006-02-09

    We produced the B7Au2- mixed cluster and studied its electronic structure and chemical bonding using photoelectron spectroscopy and ab initio calculations. The photoelectron spectra of B7Au2- were observed to be relatively simple with vibrational resolution, in contrast to the complicated spectra observed for pure B7-, which had contributions from three isomers (Alexandrova et al., J. Phys. Chem. A, 2004, 108, 3509). Theoretical calculations show that B7Au2- possesses an extremely stable planar structure, identical to that of B7H2-, demonstrating that Au mimics H in its bonding to boron, analogous to the Au-Si bonding. The ground state structure of B7Au2- (B7H2-) can be viewed as adding two Au (H) atoms to the terminal B atoms of a higher-lying planar isomer of B7-. The bonding and stability in the planar B7Au2- (B7H2-) clusters are elucidated on the basis of the strong covalent B-Au (H) bonding and the concepts of aromaticity/antiaromaticity in these systems.

  11. PHENIX Results for J/{psi} Transverse Momentum and Rapidity Dependence in Au+Au and Cu+Cu Collisions

    SciTech Connect

    Glenn, A. M.; Awes, Terry C; Batsouli, Sotiria; Cianciolo, Vince; Efremenko, Yuri; Read Jr, Kenneth F; Silvermyr, David O; Sorensen, Soren P; Stankus, Paul W; Young, Glenn R; Zhang, Chun; PHENIX, Collaboration

    2007-01-01

    The PHENIX experiment at RHIC has measured J/{psi} production in {radical}(s{sub NN})=200 GeV Au+Au and Cu+Cu collisions at forward (1.2 < |y| < 2.2) and mid (|y| < 0.35) rapidities. The most recent results for the rapidity and transverse momentum dependence of J/{psi} production are presented and compared with PHENIX baseline p + p measurements and selected theoretical calculations. We find that the J/{psi} production is significantly more suppressed, as compared to p + p, at forward rapidity than at mid rapidity in central Au+Au collisions.

  12. Strange baryon resonance production in sqrt s NN=200 GeV p+p and Au+Au collisions.

    PubMed

    Abelev, B I; Aggarwal, M M; Ahammed, Z; Amonett, J; Anderson, B D; Anderson, M; Arkhipkin, D; Averichev, G S; Bai, Y; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellingeri-Laurikainen, A; Bellwied, R; Benedosso, F; Bhardwaj, S; Bhasin, A; Bhati, A K; Bichsel, H; Bielcik, J; Bielcikova, J; Bland, L C; Blyth, S-L; Bonner, B E; Botje, M; Bouchet, J; Brandin, A V; Bravar, A; Burton, T P; Bystersky, M; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca Sánchez, M; Castillo, J; Catu, O; Cebra, D; Chajecki, Z; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, J H; Cheng, J; Cherney, M; Chikanian, A; Christie, W; Coffin, J P; Cormier, T M; Cosentino, M R; Cramer, J G; Crawford, H J; Das, D; Das, S; Dash, S; Daugherity, M; de Moura, M M; Dedovich, T G; DePhillips, M; Derevschikov, A A; Didenko, L; Dietel, T; Djawotho, P; Dogra, S M; Dong, W J; Dong, X; Draper, J E; Du, F; Dunin, V B; Dunlop, J C; Dutta Mazumdar, M R; Eckardt, V; Edwards, W R; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Fatemi, R; Fedorisin, J; Filimonov, K; Filip, P; Finch, E; Fine, V; Fisyak, Y; Fu, J; Gagliardi, C A; Gaillard, L; Ganti, M S; Gaudichet, L; Ghazikhanian, V; Ghosh, P; Gonzalez, J E; Gorbunov, Y G; Gos, H; Grebenyuk, O; Grosnick, D; Guertin, S M; Guimaraes, K S F F; Gupta, N; Gutierrez, T D; Haag, B; Hallman, T J; Hamed, A; Harris, J W; He, W; Heinz, M; Henry, T W; Hepplemann, S; Hippolyte, B; Hirsch, A; Hjort, E; Hoffman, A M; Hoffmann, G W; Horner, M J; Huang, H Z; Huang, S L; Hughes, E W; Humanic, T J; Igo, G; Jacobs, P; Jacobs, W W; Jakl, P; Jia, F; Jiang, H; Jones, P G; Judd, E G; Kabana, S; Kang, K; Kapitan, J; Kaplan, M; Keane, D; Kechechyan, A; Khodyrev, V Yu; Kim, B C; Kiryluk, J; Kisiel, A; Kislov, E M; Klein, S R; Kocoloski, A; Koetke, D D; Kollegger, T; Kopytine, M; Kotchenda, L; Kouchpil, V; Kowalik, K L; Kramer, M; Kravtsov, P; Kravtsov, V I; Krueger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; LaPointe, S; Laue, F; Lauret, J; Lebedev, A; Lednicky, R; Lee, C-H; Lehocka, S; LeVine, M J; Li, C; Li, Q; Li, Y; Lin, G; Lin, X; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, H; Liu, J; Liu, L; Liu, Z; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; Love, W A; Lu, Y; Ludlam, T; Lynn, D; Ma, G L; Ma, J G; Ma, Y G; Magestro, D; Mahapatra, D P; Majka, R; Mangotra, L K; Manweiler, R; Margetis, S; Markert, C; Martin, L; Matis, H S; Matulenko, Yu A; McClain, C J; McShane, T S; Melnick, Yu; Meschanin, A; Millane, J; Miller, M L; Minaev, N G; Mioduszewski, S; Mironov, C; Mischke, A; Mishra, D K; Mitchell, J; Mohanty, B; Molnar, L; Moore, C F; Morozov, D A; Munhoz, M G; Nandi, B K; Nattrass, C; Nayak, T K; Nelson, J M; Netrakanti, P K; Nogach, L V; Nurushev, S B; Odyniec, G; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Pachr, M; Pal, S K; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Peitzmann, T; Perevoztchikov, V; Perkins, C; Peryt, W; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Poljak, N; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M; Potrebenikova, E; Potukuchi, B V K S; Prindle, D; Pruneau, C; Putschke, J; Rakness, G; Raniwala, R; Raniwala, S; Ray, R L; Razin, S V; Reinnarth, J; Relyea, D; Retiere, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevskiy, O V; Romero, J L; Rose, A; Roy, C; Ruan, L; Russcher, M J; Sahoo, R; Sakuma, T; Salur, S; Sandweiss, J; Sarsour, M; Sazhin, P S; Schambach, J; Scharenberg, R P; Schmitz, N; Schweda, K; Seger, J; Selyuzhenkov, I; Seyboth, P; Shabetai, A; Shahaliev, E; Shao, M; Sharma, M; Shen, W Q; Shimanskiy, S S; Sichtermann, E; Simon, F; Singaraju, R N; Smirnov, N; Snellings, R; Sood, G; Sorensen, P; Sowinski, J; Speltz, J; Spinka, H M; Srivastava, B; Stadnik, A; Stanislaus, T D S; Stock, R; Stolpovsky, A; Strikhanov, M; Stringfellow, B; Suaide, A A P; Sugarbaker, E; Sumbera, M; Sun, Z; Surrow, B; Swanger, M; Symons, T J M; Szanto de Toledo, A; Tai, A; Takahashi, J; Tang, A H; Tarnowsky, T; Thein, D; Thomas, J H; Timmins, A R; Timoshenko, S; Tokarev, M; Trainor, T A; Trentalange, S; Tribble, R E; Tsai, O D; Ulery, J; Ullrich, T; Underwood, D G; Buren, G Van; van der Kolk, N; van Leeuwen, M; Molen, A M Vander; Varma, R; Vasilevski, I M; Vasiliev, A N; Vernet, R; Vigdor, S E; Viyogi, Y P; Vokal, S; Voloshin, S A; Waggoner, W T; Wang, F; Wang, G; Wang, J S; Wang, X L; Wang, Y; Watson, J W; Webb, J C; Westfall, G D; Wetzler, A; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Q H; Xu, Z; Yepes, P; Yoo, I-K; Yurevich, V I; Zhan, W; Zhang, H; Zhang, W M; Zhang, Y; Zhang, Z P; Zhao, Y; Zhong, C; Zoulkarneev, R; Zoulkarneeva, Y; Zubarev, A N; Zuo, J X

    2006-09-29

    We report the measurements of Sigma(1385) and Lambda(1520) production in p+p and Au+Au collisions at sqrt[s{NN}]=200 GeV from the STAR Collaboration. The yields and the p(T) spectra are presented and discussed in terms of chemical and thermal freeze-out conditions and compared to model predictions. Thermal and microscopic models do not adequately describe the yields of all the resonances produced in central Au+Au collisions. Our results indicate that there may be a time span between chemical and thermal freeze-out during which elastic hadronic interactions occur. PMID:17026027

  13. Ultrafast charge carrier dynamics in Au/semiconductor nanoheterostructures

    NASA Astrophysics Data System (ADS)

    Lambright, Scott

    The charge carrier dynamics in several Au/semiconductor core/shell heterostructures were examined. Firstly, Au/CdS core/shell nanocomposites were synthesized in a four step procedure culminating in a cation exchange performed on the shell. Previous studies of the ultrafast carrier dynamics in Au/CdS nanocomposites with epitaxial boundary regions reported the suppression of plasmon character in transient absorption spectra accompanied by broadband photoinduced absorption. The coupling of electron wavefunctions with lattice defects at the boundary of the two domains has been blamed for these phenomena. In the current study, transmission electron micrographs of Au/CdS synthesized using cation exchange showed no evidence of strain on the lattice of either component, while femtosecond transient absorption data show the retention of bleach regions attributed to CdS's 1S(e)-1S3/2(h) transition and Au's plasmon resonance. Accelerated rates of bleach recovery for both excitations ( tauexiton ≈ 300 ps, tauplasmon ≈ .7 ps) indicated that the interaction of Au and CdS domains leads to faster relaxation to their respective photoexcitations when compared to relaxation times in isolated Au and CdS nanoparticles. It was believed that the Au/CdS boundary was non-epitaxial in the presented core/shell nanocomposites. Secondly, these non-epitaxial Au/CdS core/shells were subsequently used to demonstrate near-field energy transfer from 5 nm diameter Au cores to CdS-encapsulated CdSe quantum dots. To this end, Au/CdS and CdSe/CdS nanocrystals were embedded in semiconductor-matrix-encapsulated-nanocrystal-arrays (SMENA) together. The encapsulation of both domains in the high band-gap semiconductor CdS was a means to suppress charge transfer between the two nanoparticles. The fluorescence intensity in these films was enhanced 6-fold in some cases as a result of the presence of Au domains. It was also demonstrated that the fluorescence enhancement was independent of the potential

  14. Satellite Map of Port-au-Prince, Haiti-2010-Infrared

    USGS Publications Warehouse

    Cole, Christopher J.; Sloan, Jeff

    2010-01-01

    The U.S. Geological Survey produced 1:24,000-scale post-earthquake image base maps incorporating high- and medium-resolution remotely sensed imagery following the 7.0 magnitude earthquake near the capital city of Port au Prince, Haiti, on January 12, 2010. Commercial 2.4-meter multispectral QuickBird imagery was acquired by DigitalGlobe on January 15, 2010, following the initial earthquake. Ten-meter multispectral ALOS AVNIR-2 imagery was collected by the Japanese Space Agency (JAXA) on January 12, 2010. These data were acquired under the Remote Sensing International Charter, a global team of space and satellite agencies that provide timely imagery in support of emergency response efforts worldwide. The images shown on this map were employed to support earthquake response efforts, specifically for use in determining ground deformation, damage assessment, and emergency management decisions. The raw, unprocessed imagery was geo-corrected, mosaicked, and reproduced onto a cartographic 1:24,000-scale base map. These maps are intended to provide a temporally current representation of post-earthquake ground conditions, which may be of use to decision makers and to the general public.

  15. Microstructural evolution of eutectic Au-Sn solder joints

    SciTech Connect

    Song, Ho Geon

    2002-05-31

    Current trends toward miniaturization and the use of lead(Pb)-free solder in electronic packaging present new problems in the reliability of solder joints. This study was performed in order to understand the microstructure and microstructural evolution of small volumes of nominally eutectic Au-Sn solder joints (80Au-20Sn by weight), which gives insight into properties and reliability.

  16. Registration of ‘AU-1101’ peanut

    Technology Transfer Automated Retrieval System (TEKTRAN)

    AU-1101’ (Reg. No. CV-xxx, PI 661498) is a large-seeded virginia-type peanut (Arachis hypogaea L. subsp. hypogaea var. hypogaea) with high yield and medium maturity, uniform pod size and shape, high grade, superior shelling characters, low oil content, normal oleic acid content, and good flavor. AU-...

  17. Experimental Evidence for Electron Channeling in Fe/ Au (100) Superlattices

    SciTech Connect

    Dekadjevi, D. T.; Ryan, P. A.; Hickey, B. J.; Fulthorpe, B. D.; Tanner, B. K.

    2001-06-18

    We present transport and structural data from epitaxial (100) and (111) Au/Fe superlattices grown by molecular beam epitaxy. From their analysis, we conclude that an electron channeling mechanism, due to strong specular reflection of the minority spin carrier at the Au/Fe interfaces, is responsible for the high conductivity in the (100) superlattices.

  18. Evidence from d+Au measurements for final-state suppression of high-p(T) hadrons in Au+Au collisions at RHIC.

    PubMed

    Adams, J; Adler, C; Aggarwal, M M; Ahammed, Z; Amonett, J; Anderson, B D; Anderson, M; Arkhipkin, D; Averichev, G S; Badyal, S K; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bezverkhny, B I; Bhardwaj, S; Bhaskar, P; Bhati, A K; Bichsel, H; Billmeier, A; Bland, L C; Blyth, C O; Bonner, B E; Botje, M; Boucham, A; Brandin, A; Bravar, A; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca Sánchez, M; Carroll, J; Castillo, J; Castro, M; Cebra, D; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Christie, W; Coffin, J P; Cormier, T M; Cramer, J G; Crawford, H J; Das, D; Das, S; Derevschikov, A A; Didenko, L; Dietel, T; Dong, X; Draper, J E; Du, F; Dubey, A K; Dunin, V B; Dunlop, J C; Dutta Majumdar, M R; Eckardt, V; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Fachini, P; Faine, V; Faivre, J; Fatemi, R; Filimonov, K; Filip, P; Finch, E; Fisyak, Y; Flierl, D; Foley, K J; Fu, J; Gagliardi, C A; Ganti, M S; Gagunashvili, N; Gans, J; Gaudichet, L; Germain, M; Geurts, F; Ghazikhanian, V; Ghosh, P; Gonzalez, J E; Grachov, O; Grigoriev, V; Gronstal, S; Grosnick, D; Guedon, M; Guertin, S M; Gupta, A; Gushin, E; Gutierrez, T D; Hallman, T J; Hardtke, D; Harris, J W; Heinz, M; Henry, T W; Heppelmann, S; Herston, T; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Huang, H Z; Huang, S L; Humanic, T J; Igo, G; Ishihara, A; Jacobs, P; Jacobs, W W; Janik, M; Johnson, I; Jones, P G; Judd, E G; Kabana, S; Kaneta, M; Kaplan, M; Keane, D; Kiryluk, J; Kisiel, A; Klay, J; Klein, S R; Klyachko, A; Koetke, D D; Kollegger, T; Konstantinov, A S; Kopytine, M; Kotchenda, L; Kovalenko, A D; Kramer, M; Kravtsov, P; Krueger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kunde, G J; Kunz, C L; Kutuev, R Kh; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lauret, J; Lebedev, A; Lednický, R; Leontiev, V M; LeVine, M J; Li, C; Li, Q; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, L; Liu, Z; Liu, Q J; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; Lopez-Noriega, M; Love, W A; Ludlam, T; Lynn, D; Ma, J; Ma, Y G; Magestro, D; Mahajan, S; Mangotra, L K; Mahapatra, D P; Majka, R; Manweiler, R; Margetis, S; Markert, C; Martin, L; Marx, J; Matis, H S; Matulenko, Yu A; McShane, T S; Meissner, F; Melnick, Yu; Meschanin, A; Messer, M; Miller, M L; Milosevich, Z; Minaev, N G; Mironov, C; Mishra, D; Mitchell, J; Mohanty, B; Molnar, L; Moore, C F; Mora-Corral, M J; Morozov, V; de Moura, M M; Munhoz, M G; Nandi, B K; Nayak, S K; Nayak, T K; Nelson, J M; Nevski, P; Nikitin, V A; Nogach, L V; Norman, B; Nurushev, S B; Odyniec, G; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Paic, G; Pandey, S U; Pal, S K; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Perevoztchikov, V; Peryt, W; Petrov, V A; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M; Potrebenikova, E; Potukuchi, B V K S; Prindle, D; Pruneau, C; Putschke, J; Rai, G; Rakness, G; Raniwala, R; Raniwala, S; Ravel, O; Ray, R L; Razin, S V; Reichhold, D; Reid, J G; Renault, G; Retiere, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L J; Rykov, V; Sahoo, R; Sakrejda, I; Salur, S; Sandweiss, J; Savin, I; Schambach, J; Scharenberg, R P; Schmitz, N; Schroeder, L S; Schweda, K; Seger, J; Seliverstov, D; Seyboth, P; Shahaliev, E; Shao, M; Sharma, M; Shestermanov, K E; Shimanskii, S S; Singaraju, R N; Simon, F; Skoro, G; Smirnov, N; Snellings, R; Sood, G; Sorensen, P; Sowinski, J; Spinka, H M; Srivastava, B; Stanislaus, S; Stock, R; Stolpovsky, A; Strikhanov, M; Stringfellow, B; Struck, C; Suaide, A A P; Sugarbaker, E; Suire, C; Sumbera, M; Surrow, B; Symons, T J M; Szanto de Toledo, A; Szarwas, P; Tai, A; Takahashi, J; Tang, A H; Thein, D; Thomas, J H; Tikhomirov, V; Tokarev, M; Tonjes, M B; Trainor, T A; Trentalange, S; Tribble, R E; Trivedi, M D; Trofimov, V; Tsai, O; Ullrich, T; Underwood, D G; Van Buren, G; VanderMolen, A M; Vasiliev, A N; Vasiliev, M; Vigdor, S E; Viyogi, Y P; Voloshin, S A; Waggoner, W; Wang, F; Wang, G; Wang, X L; Wang, Z M; Ward, H; Watson, J W; Wells, R; Westfall, G D; Whitten, C; Wieman, H; Willson, R; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Z; Xu, Z Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yurevich, V I; Zanevski, Y V; Zborovský, I; Zhang, H; Zhang, H Y; Zhang, W M; Zhang, Z P; Zołnierczuk, P A; Zoulkarneev, R; Zoulkarneeva, J; Zubarev, A N

    2003-08-15

    We report measurements of single-particle inclusive spectra and two-particle azimuthal distributions of charged hadrons at high transverse momentum (high p(T)) in minimum bias and central d+Au collisions at sqrt[s(NN)]=200 GeV. The inclusive yield is enhanced in d+Au collisions relative to binary-scaled p+p collisions, while the two-particle azimuthal distributions are very similar to those observed in p+p collisions. These results demonstrate that the strong suppression of the inclusive yield and back-to-back correlations at high p(T) previously observed in central Au+Au collisions are due to final-state interactions with the dense medium generated in such collisions. PMID:12935009

  19. Identification of Au–S complexes on Au(100)

    DOE PAGESBeta

    Walen, Holly; Liu, Da -Jiang; Oh, Junepyo; Yang, Hyun Jin; Kim, Yousoo; Thiel, P. A.

    2016-01-25

    In this study, using a combination of scanning tunneling microscopy and density functional theory (DFT) calculations, we have identified a set of related Au–S complexes that form on Au(100), when sulfur adsorbs and lifts the hexagonal surface reconstruction. The predominant complex is diamond-shaped with stoichiometry Au4S5. All of the complexes can be regarded as combinations of S–Au–S subunits. The complexes exist within, or at the edges of, p(2 × 2) sulfur islands that cover the unreconstructed Au regions, and are observed throughout the range of S coverage examined in this study, 0.009 to 0.12 monolayers. A qualitative model is developedmore » which incorporates competitive formation of complexes, Au rafts, and p(2 × 2) sulfur islands, as Au atoms are released by the surface structure transformation.« less

  20. High-spin level scheme of {sup 183}Au

    SciTech Connect

    Song, L.T.; Zhou, X.H.; Zhang, Y. H.; Guo, Y. X.; Lei, X.G.; Zheng, Y.; Liu, M.L.; De Angelis, G.; Marginean, N.; Gadea, A.; Napoli, D.R.; Axiotis, M.; Rusu, C.; Martinez, T.

    2005-01-01

    High-spin states in {sup 183}Au have been studied experimentally using the {sup 159}Tb({sup 29}Si,5n){sup 183}Au reaction at a beam energy of 140 MeV. Three- or higherfold {gamma}-ray coincidences have been measured using the detector array of GASP. The level scheme of {sup 183}Au was revised and extended. A rotational band proposed as the unfavored signature branch of the {pi}i{sub 13/2} band has been observed for {sup 183}Au. Interaction properties between the two negative-signature bands of the {pi}h{sub 9/2}-{pi}f{sub 7/2} system have been discussed for the light odd-A Au nuclei.

  1. Electrical Transport Properties of Au-Doped Deoxyribonucleic Acid Molecules

    NASA Astrophysics Data System (ADS)

    Hwang, Jong Seung; Hong, Su Heon; Kim, Hyung Kwon; Kwon, Young Whan; Jin, Jung Il; Hwang, Sung Woo; Ahn, Doyeol

    2005-04-01

    Deoxyribonucleic acid (DNA) molecules were doped with Au atoms and their electrical transport properties were measured. The Au doping was carried out by incubating a mixture of HAuCl4\\cdot3H2O and DNA solutions. The binding of Au atoms to DNA bases was identified using Fourier transform infrared spectroscopy and X-ray photoemission spectroscopy. The Au-doped DNA molecules were deposited on nanoelectrodes and the presence of the molecules between the electrodes was determined by both scanning electron microscopy and atomic force microscopy. Measurement of the current-voltage characteristics showed that the Au-doped DNA molecules exhibited a higher conductivity than undoped DNA molecules. Detailed analysis of the chemical composition shows that there is a strong possibility of reliably controlling the conductivity of DNA molecules using this method.

  2. High Transverse Momentum {eta} Meson Production in p+p,d+Au and Au+Au Collisions at sqrt(sNN) = 200 GeV

    SciTech Connect

    Adler, S. S.; Awes, Terry C; Batsouli, Sotiria; Cianciolo, Vince; Efremenko, Yuri; Plasil, F; Read Jr, Kenneth F; Silvermyr, David O; Sorensen, Soren P; Stankus, Paul W; Young, Glenn R; Zhang, Chun; PHENIX, Collaboration

    2007-01-01

    Inclusive transverse momentum spectra of {eta} mesons in the range p{sub T}{approx}2-12 GeV/c have been measured at midrapidity (|{eta}|<0.35) by the PHENIX experiment at RHIC in p+p,d+Au, and Au+Au collisions at {radical}R{sub NN}=200 GeV. The eta mesons are reconstructed through their {eta}{yields}{gamma} {gamma} channel for the three colliding systems as well as through the {eta}{yields}{pi}{sup 0}{pi}{sup +}{pi}{sup -} decay mode in p+p and d+Au collisions. The nuclear modification factor in d+Au collisions, RdAu(p{sub T}){approx}1.0-1.1, suggests at most only modest pT broadening ('Cronin enhancement'). In central Au+Au reactions, the eta yields are significantly suppressed, with RAuAu(p{sub T}){approx}0.2. The ratio of {eta} to {pi}{sup 0} yields is approximately constant as a function of pT for the three colliding systems in agreement with the high-pT world average of R{sub {eta}}/{pi}{sup 0}{approx}0.5 in hadron-hadron, hadron-nucleus, and nucleus-nucleus collisions for a wide range of center-of-mass energies {radical}R{sub NN}{approx}3-1800 GeV as well as, for high scaled momentum xp, in e{sup +}e{sup -} annihilations at {radical}R=91.2 GeV. These results are consistent with a scenario where high-pT eta production in nuclear collisions at the Relativistic Heavy Ion Collider is largely unaffected by initial-state effects but where light-quark mesons ({pi}{sup 0},{eta}) are equally suppressed due to final-state interactions of the parent partons in the dense medium produced in Au+Au reactions.

  3. Azimuthal Anisotropy in U +U and Au +Au Collisions at RHIC

    NASA Astrophysics Data System (ADS)

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Alford, J.; Aparin, A.; Arkhipkin, D.; Aschenauer, E. C.; Averichev, G. S.; Banerjee, A.; Bellwied, R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Bouchet, J.; Brandin, A. V.; Bunzarov, I.; Burton, T. P.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Campbell, J. M.; Cebra, D.; Cervantes, M. C.; Chakaberia, I.; Chaloupka, P.; Chang, Z.; Chattopadhyay, S.; Chen, J. H.; Chen, X.; Cheng, J.; Cherney, M.; Christie, W.; Contin, G.; Crawford, H. J.; Das, S.; De Silva, L. C.; Debbe, R. R.; Dedovich, T. G.; Deng, J.; Derevschikov, A. A.; di Ruzza, B.; Didenko, L.; Dilks, C.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Du, C. M.; Dunkelberger, L. E.; Dunlop, J. C.; Efimov, L. G.; Engelage, J.; Eppley, G.; Esha, R.; Evdokimov, O.; Eyser, O.; Fatemi, R.; Fazio, S.; Federic, P.; Fedorisin, J.; Feng, Z.; Filip, P.; Fisyak, Y.; Flores, C. E.; Fulek, L.; Gagliardi, C. A.; Garand, D.; Geurts, F.; Gibson, A.; Girard, M.; Greiner, L.; Grosnick, D.; Gunarathne, D. S.; Guo, Y.; Gupta, S.; Gupta, A.; Guryn, W.; Hamad, A.; Hamed, A.; Haque, R.; Harris, J. W.; He, L.; Heppelmann, S.; Heppelmann, S.; Hirsch, A.; Hoffmann, G. W.; Hofman, D. J.; Horvat, S.; Huang, H. Z.; Huang, B.; Huang, X.; Huck, P.; Humanic, T. J.; Igo, G.; Jacobs, W. W.; Jang, H.; Jiang, K.; Judd, E. G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Khan, Z. H.; Kikola, D. P.; Kisel, I.; Kisiel, A.; Koetke, D. D.; Kollegger, T.; Kosarzewski, L. K.; Kotchenda, L.; Kraishan, A. F.; Kravtsov, P.; Krueger, K.; Kulakov, I.; Kumar, L.; Kycia, R. A.; Lamont, M. A. C.; Landgraf, J. M.; Landry, K. D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; Li, W.; Li, Y.; Li, C.; Li, Z. M.; Li, X.; Li, X.; Lisa, M. A.; Liu, F.; Ljubicic, T.; Llope, W. J.; Lomnitz, M.; Longacre, R. S.; Luo, X.; Ma, L.; Ma, R.; Ma, Y. G.; Ma, G. L.; Magdy, N.; Majka, R.; Manion, A.; Margetis, S.; Markert, C.; Masui, H.; Matis, H. S.; McDonald, D.; Meehan, K.; Minaev, N. G.; Mioduszewski, S.; Mohanty, B.; Mondal, M. M.; Morozov, D. A.; Mustafa, M. K.; Nandi, B. K.; Nasim, Md.; Nayak, T. K.; Nigmatkulov, G.; Nogach, L. V.; Noh, S. Y.; Novak, J.; Nurushev, S. B.; Odyniec, G.; Ogawa, A.; Oh, K.; Okorokov, V.; Olvitt, D. L.; Page, B. S.; Pak, R.; Pan, Y. X.; Pandit, Y.; Panebratsev, Y.; Pawlik, B.; Pei, H.; Perkins, C.; Peterson, A.; Pile, P.; Planinic, M.; Pluta, J.; Poljak, N.; Poniatowska, K.; Porter, J.; Posik, M.; Poskanzer, A. M.; Pruthi, N. K.; Putschke, J.; Qiu, H.; Quintero, A.; Ramachandran, S.; Raniwala, S.; Raniwala, R.; Ray, R. L.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Roy, A.; Ruan, L.; Rusnak, J.; Rusnakova, O.; Sahoo, N. R.; Sahu, P. K.; Sakrejda, I.; Salur, S.; Sandweiss, J.; Sarkar, A.; Schambach, J.; Scharenberg, R. P.; Schmah, A. M.; Schmidke, W. B.; Schmitz, N.; Seger, J.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P. V.; Shao, M.; Sharma, B.; Sharma, M. K.; Shen, W. Q.; Shi, S. S.; Shou, Q. Y.; Sichtermann, E. P.; Sikora, R.; Simko, M.; Skoby, M. J.; Smirnov, D.; Smirnov, N.; Song, L.; Sorensen, P.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Stepanov, M.; Stock, R.; Strikhanov, M.; Stringfellow, B.; Sumbera, M.; Summa, B. J.; Sun, X.; Sun, X. M.; Sun, Z.; Sun, Y.; Surrow, B.; Svirida, D. N.; Szelezniak, M. A.; Tang, Z.; Tang, A. H.; Tarnowsky, T.; Tawfik, A. N.; Thomas, J. H.; Timmins, A. R.; Tlusty, D.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Tripathy, S. K.; Trzeciak, B. A.; Tsai, O. D.; Ullrich, T.; Underwood, D. G.; Upsal, I.; Van Buren, G.; van Nieuwenhuizen, G.; Vandenbroucke, M.; Varma, R.; Vasiliev, A. N.; Vertesi, R.; Videbaek, F.; Viyogi, Y. P.; Vokal, S.; Voloshin, S. A.; Vossen, A.; Wang, F.; Wang, Y.; Wang, H.; Wang, J. S.; Wang, Y.; Wang, G.; Webb, G.; Webb, J. C.; Wen, L.; Westfall, G. D.; Wieman, H.; Wissink, S. W.; Witt, R.; Wu, Y. F.; Xiao, Z.; Xie, W.; Xin, K.; Xu, Y. F.; Xu, N.; Xu, Z.; Xu, Q. H.; Xu, H.; Yang, Y.; Yang, Y.; Yang, C.; Yang, S.; Yang, Q.; Ye, Z.; Yepes, P.; Yi, L.; Yip, K.; Yoo, I.-K.; Yu, N.; Zbroszczyk, H.; Zha, W.; Zhang, X. P.; Zhang, J. B.; Zhang, J.; Zhang, Z.; Zhang, S.; Zhang, Y.; Zhang, J. L.; Zhao, F.; Zhao, J.; Zhong, C.; Zhou, L.; Zhu, X.; Zoulkarneeva, Y.; Zyzak, M.; STAR Collaboration

    2015-11-01

    Collisions between prolate uranium nuclei are used to study how particle production and azimuthal anisotropies depend on initial geometry in heavy-ion collisions. We report the two- and four-particle cumulants, v2{2 } and v2{4 }, for charged hadrons from U +U collisions at √{sNN }=193 GeV and Au +Au collisions at √{sNN}=200 GeV . Nearly fully overlapping collisions are selected based on the energy deposited by spectators in zero degree calorimeters (ZDCs). Within this sample, the observed dependence of v2{2 } on multiplicity demonstrates that ZDC information combined with multiplicity can preferentially select different overlap configurations in U +U collisions. We also show that v2 vs multiplicity can be better described by models, such as gluon saturation or quark participant models, that eliminate the dependence of the multiplicity on the number of binary nucleon-nucleon collisions.

  4. Local structure of disordered Au-Cu and Au-Ag alloys

    NASA Astrophysics Data System (ADS)

    Frenkel, A. I.; Machavariani, V. Sh.; Rubshtein, A.; Rosenberg, Yu.; Voronel, A.; Stern, E. A.

    2000-10-01

    X-ray-absorption fine structure (XAFS) and x-ray-diffraction (XRD) measurements of disordered alloys AuxCu1-x and Au0.5Ag0.5 prepared by melt spinning were performed. In the Au0.5Ag0.5 alloy, no significant local deviations of the atoms from the average fcc lattice were detected while in AuxCu1-x alloys, significant deviations of atoms from the average fcc lattice were found. Mean-square vibrations of the Cu-Cu distances revealed by the XAFS in AuxCu1-x alloys indicate the weakening of contact between Cu atoms in the dilute limit. Our computer simulation for AuxCu1-x clusters of 105 atoms reproduces the main features of both the XAFS and XRD data.

  5. Dynamic aperture calculation for the RHIC 2010 100 GeV Au-Au run lattices

    SciTech Connect

    Luo, Y.; Brown, K.; Fischer, W.; Ptitsyn, V.; Roser, T.; Schoefer, V.; Tepikian, S.; Trbojevic, D.

    2010-08-01

    In this note we summarize the dynamic aperture calculation with the 2010 RHIC 100 GeV Au-Au run lattices. This study was initiated to understand the observed large beam decay in the Yellow ring after rf re-bucketing in the beginning of this run. The off-line linear lattice models and the interaction region non-linearity models are used. The large beam decay in the Yellow ring after re-bucketing was eventually eliminated by lowering the Yellow tunes to 0.21 from 0.235 with {beta}* = 0.7m lattice. In this note we only focus on the numeric simulation instead of the beam experiments.

  6. Interpretation of the first data on central Au+Au collisions at

    SciTech Connect

    Jeon, Sangyong; Kapusta, Joseph

    2001-01-01

    We compare three semimicroscopic theories to the first data on particle production in central Au+Au collisions taken at RHIC by the PHOBOS Collaboration as well as to existing data on central Pb+Pb collisions taken at the SPS by the NA49 Collaboration. The Linear Extrapolation of Ultrarelativistic nucleon-nucleon Scattering to nucleus-nucleus collisions (LEXUS) represents the SPS data quite well but predicts too many particles at RHIC. The wounded nucleon model predicts too few particles at both the SPS and RHIC; the collective tube model predicts fewer particles still. This suggests a transition in the dynamics of particle production between s=17 and 56A GeV as one goes from the SPS to RHIC.

  7. Proton-antiproton suppression in 200A GeV Au-Au collisions

    NASA Astrophysics Data System (ADS)

    Renk, Thorsten; Eskola, Kari J.

    2007-08-01

    We discuss the measured nuclear suppression of p+p¯ production in 200A GeV Au-Au collisions at the Relativistic Heavy Ion Collider (RHIC) within radiative energy loss. For the Albino-Kniehl-Kramer (AKK) set of fragmentation functions, proton production is dominated by gluons, giving rise to the expectation that the nuclear suppression for p+p¯ should be stronger than for pions due to the stronger coupling of gluons to the quenching medium. Using a hydrodynamical description for the soft matter evolution, we show that this is indeed seen in the calculation. However, the expected suppression factors for pions and protons are sufficiently similar that a discrimination with present data is not possible. In the high pT region above 6 GeV where the contributions of hydrodynamics and recombination to hadron production are negligible, the model calculation is in good agreement with the data on p+p¯ suppression.

  8. Proton-antiproton suppression in 200A GeV Au-Au collisions

    SciTech Connect

    Renk, Thorsten; Eskola, Kari J.

    2007-08-15

    We discuss the measured nuclear suppression of p+p production in 200A GeV Au-Au collisions at the Relativistic Heavy Ion Collider (RHIC) within radiative energy loss. For the Albino-Kniehl-Kramer (AKK) set of fragmentation functions, proton production is dominated by gluons, giving rise to the expectation that the nuclear suppression for p+p should be stronger than for pions due to the stronger coupling of gluons to the quenching medium. Using a hydrodynamical description for the soft matter evolution, we show that this is indeed seen in the calculation. However, the expected suppression factors for pions and protons are sufficiently similar that a discrimination with present data is not possible. In the high p{sub T} region above 6 GeV where the contributions of hydrodynamics and recombination to hadron production are negligible, the model calculation is in good agreement with the data on p+p suppression.

  9. Study of Kaon Isospin Fluctuations in Au+Au Collisions at STAR

    NASA Astrophysics Data System (ADS)

    Rose, Andrew

    2002-10-01

    Recent theoretical studies have suggested that in heavy ion collisions the formation of disoriented chiral condensates (DCC) may result from the restoration and subsequent re-breaking of chiral symmetry. Searches for DCC have so far focused on the pion sector with little attention given to the Kaon sector. Recently however, Kapusta has suggested the observation of enhanced production of Ω and \\overlineΩ at s_NN = 17 GeV, in Pb+Pb collisions, can in part be explained by the production of many small strange DCC regions. Gavin and Kapusta have additionally shown that strange DCCs production may induce anomalous fluctuations of the Kaon total isospin. We present a statistical analysis of Kaon isospin fluctuations in Au+Au collisions at 130- and 200-GeV measured with the STAR apparatus. The analysis is based on the ν_dyn fluctuation measure which correlates the production of neutral and charged kaons.

  10. Steering epitaxial alignment of Au, Pd, and AuPd nanowire arrays by atom flux change.

    PubMed

    Yoo, Youngdong; Seo, Kwanyong; Han, Sol; Varadwaj, Kumar S K; Kim, Hyun You; Ryu, Ji Hoon; Lee, Hyuck Mo; Ahn, Jae Pyoung; Ihee, Hyotcherl; Kim, Bongsoo

    2010-02-10

    We have synthesized epitaxial Au, Pd, and AuPd nanowire arrays in vertical or horizontal alignment on a c-cut sapphire substrate. We show that the vertical and horizontal nanowire arrays grow from half-octahedral seeds by the correlations of the geometry and orientation of seed crystals with those of as-grown nanowires. The alignment of nanowires can be steered by changing the atom flux. At low atom deposition flux vertical nanowires grow, while at high atom flux horizontal nanowires grow. Similar vertical/horizontal epitaxial growth is also demonstrated on SrTiO(3) substrates. This orientation-steering mechanism is visualized by molecular dynamics simulations. PMID:20050692

  11. Strangeness Production in Au+Au Reactions at √ {SNN} = 62.4\\ GeV

    NASA Astrophysics Data System (ADS)

    Arsene, Ionut-Cristian

    The measurement of strangeness is a valuable tool for understanding the reaction mechanism of nuclear collisions since all the strange particles need to be created during the reaction. Also, strangeness enhancement is one of the predicted signals of the QGP. In the present work we will discuss the behaviour of the strangeness production (i.e. K/π ratio) with rapidity and baryo-chemical potential in Au+Au collisions at 62.4 A GeV. In this particular reaction, BRAHMS is able to identify particles over 3.5 rapidity units and thereby cover a wide range of bar {p}/p ratios, including the fragmentation region. We will show spectra and ratios of identified particles as a function of pT and rapidity.

  12. A comparative study of the Au + H2, Au+ + H2, and Au- + H2 systems: Potential energy surfaces and dynamics of reactive collisions

    NASA Astrophysics Data System (ADS)

    Dorta-Urra, Anaís; Zanchet, Alexandre; Roncero, Octavio; Aguado, Alfredo

    2015-04-01

    In order to study the Au- + H2 collision, a new global potential energy surface (PES) describing the ground electronic state of AuH 2- system is developed and compared with the PESs of the neutral [Zanchet et al., J. Chem. Phys. 132, 034301 (2010)] and cationic systems [Anaís et al., J. Chem. Phys. 135, 091102 (2011)]. We found that Au- - H2 presents a H-Au-H insertion minimum attributed to the stabilization of the LUMO 3b2 orbital, which can be considered as the preamble of the chemisorption well appearing in larger gold clusters. While the LUMO orbital is stabilized, the HOMO 6a1 is destabilized, creating a barrier at the geometry where the energy orbitals' curves are crossing. In the anion, this HOMO is doubly occupied, while in the neutral system is half-filled and completely empty in the cation, explaining the gradual disappearance of the well and the barrier as the number of electrons decreases. The cation presents a well in the entrance channel partially explained by electrostatic interactions. The three systems' reactions are highly endothermic, by 1.66, 2.79, and 3.23 eV for AuH, AuH+, and AuH- products, respectively. The reaction dynamics is studied using quasi-classical trajectory method for the three systems. The one corresponding to the anionic system is new in this work. Collision energies between 1.00 and 8.00 eV, measured for the cation, are in good agreement with the simulated cross section for the AuH+. It was also found that the total fragmentation, in three atoms, competes becoming dominant at sufficiently high energy. Here, we study the competition between the two different reaction pathways for the anionic, cationic, and neutral species, explaining the differences using a simple model based on the topology of the potential energy surfaces.

  13. Modeling the Accretion Structure of AU Mon

    NASA Astrophysics Data System (ADS)

    Atwood-Stone, Corwin; Miller, Brendan P.; Richards, Mercedes T.; Budaj, Ján; Peters, Geraldine J.

    2012-12-01

    AU Mon is a long-period (11.113 days) Algol-type binary system with a persistent accretion disk that is apparent as double-peaked Hα emission. We present previously unpublished optical spectra of AU Mon which were obtained over 20 years from 1991-2011 with dense orbital phase coverage. We utilize these data, along with archival UV spectra, to model the temperature and structure of the accretion disk and the gas stream. Synthetic spectral profiles for lines including Hα, Hβ, and the Al III and Si IV doublets were computed with the Shellspec program. The best match between the model spectra and the observations is obtained for an accretion disk of inner/outer radius 5.1/23 R ⊙, thickness of 5.2 R ⊙, density of 1.0 × 10-13 g cm-3, and maximum temperature of 14,000 K, along with a gas stream at a temperature of ~8000 K transferring ~2.4 × 10-9 M ⊙ yr-1. We show Hα Doppler tomograms of the velocity structure of the gas, constructed from difference profiles calculated through sequentially subtracting contributions from the stars and accretion structures. The tomograms provide independent support for the Shellspec modeling, while also illustrating that residual emission at sub-Keplerian velocities persists even after subtracting the disk and stream emission. Spectral variability in the Hα profile beyond that expected from either the orbital or the long-period cycle is present on both multi-week and multi-year timescales, and may reflect quasi-random changes in the mass transfer rate or the disk structure. Finally, a transient UV spectral absorption feature may be modeled as an occasional outflow launched from the vicinity of the disk-stream interaction region.

  14. From the ternary Eu(Au/In)2 and EuAu4(Au/In)2 with remarkable Au/In distributions to a new structure type: The gold-rich Eu5Au16(Au/In)6 structure

    SciTech Connect

    Steinberg, Simon; Card, Nathan; Mudring, Anja -Verena

    2015-08-13

    The ternary Eu(Au/In)2 (EuAu0.46In1.54(2)) (I), EuAu4(Au/In)2 (EuAu4+xIn2–x with x = 0.75(2) (II), 0.93(2), and 1.03(2)), and Eu5Au16(Au/In)6 (Eu5Au17.29In4.71(3)) (III) have been synthesized, and their structures were characterized by single-crystal X-ray diffraction. I and II crystallize with the CeCu2-type (Pearson Symbol oI12; Imma; Z = 4; a = 4.9018(4) Å; b = 7.8237(5) Å; c = 8.4457(5) Å) and the YbAl4Mo2-type (tI14; I4/mmm; Z = 2; a = 7.1612(7) Å; c = 5.5268(7) Å) and exhibit significant Au/In disorder. I is composed of an Au/In-mixed diamond-related host lattice encapsulating Eu atoms, while the structure of II features ribbons of distorted, squared Au8 prisms enclosing Eu, Au, and In atoms. Combination of these structural motifs leads to a new structure type as observed for Eu5Au16(Au/In)6 (Eu5Au17.29In4.71(3)) (oS108; Cmcm; Z = 4; a = 7.2283(4) Å; b = 9.0499(6) Å; c = 34.619(2) Å), which formally represents a one-dimensional intergrowth of the series EuAu2–“EuAu4In2”. The site preferences of the disordered Au/In positions in II were investigated for different hypothetical “EuAu4(Au/In)2” models using the projector-augmented wave method and indicate that these structures attempt to optimize the frequencies of the heteroatomic Au–In contacts. Furthermore, a chemical bonding analysis on two “EuAu5In” and “EuAu4In2” models employed the TB-LMTO-ASA method and reveals that the subtle interplay between the local atomic environments and the bond energies determines the structural and site preferences for these systems.

  15. Biosynthesis of Au, Ag and Au-Ag nanoparticles using edible mushroom extract

    NASA Astrophysics Data System (ADS)

    Philip, Daizy

    2009-07-01

    Integration of green chemistry principles to nanotechnology is one of the key issues in nanoscience research. There is growing need to develop environmentally benign metal nanoparticle synthesis process that do not use toxic chemicals in the synthesis protocols to avoid adverse effects in medical applications. Here, it is a report on extracellular synthesis method for the preparation of Au, Ag and Au-Ag nanoparticles in water, using the extract of Volvariella volvacea, a naturally occurring edible mushroom, as reducing and protecting agents. Gold nanoparticles of different sizes (20-150 nm) and shapes from triangular nanoprisms to nearly spherical and hexagonal are obtained by this novel method. The size and shape of gold nanoparticles are also found to depend on temperature of the extract. The silver nanoparticles are spherical with size ˜15 nm. There is increased productivity of nanoparticles as shown by sharp and intense surface plasmon resonance bands for the nanoparticles prepared using an excess of the extract. The Au-Ag nanoparticles prepared by co-reduction has only one plasmon band due to alloying of the constituents. All the synthesized nanoparticles are found to be photoluminescent and are highly crystalline as shown by SAED and XRD patterns with fcc phase oriented along the (1 1 1) plane. FTIR measurements were carried out to identify the possible biomolecules responsible for capping and efficient stabilization of the nanoparticles. It is found that Au nanoparticles are bound to proteins through free amino groups and silver nanoparticles through the carboxylate group of the amino acid residues. The position and intensity of the emission band is found to depend on composition of the nanoparticles indicating the possible use in therapeutic applications.

  16. Organosulfur-functionalized Au, Pd, and Au-Pd nanoparticles on 1D silicon nanowire substrates: preparation and XAFS studies.

    PubMed

    Zhang, Peng; Zhou, Xingtai; Tang, Yuanhong; Sham, Tsun Kong

    2005-08-30

    A hybrid preparative method was developed to prepare organosulfur-functionalized Au nanoparticles (NPs) on silicon nanowires (SiNWs) by reacting HAuCl(4) with SiNW in the presence of thiol. A number of organosulfur molecules-dodecanethiol, hexanethiol, 1,6-hexanedithiol, and tiopronin-were used to functionalize the Au surface. Size-selected NPs ranging from 1.6 to 7.5 nm were obtained by varying the S/Au ratio and the concentration of HAuCl(4). This method was further extended to the preparation Pd and Pd-Au bimetallic NPs on SiNWs. The morphology of the metal nanostructures was examined by transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). The local structure and bonding of the SiNW-supported metal nanostructures were studied using X-ray absorption fine structures (XAFS) [including both X-ray near-edge structures (XANES) and extended X-ray absorption fine structures (EXAFS)] at the Au L(3)-, Pd K-, S K-, and Si K-edges. It was also found that the annealing of the thiol-capped Au NPs up to 500 degrees C transforms the surface of the thiol-capped NPs to gold sulfide, as identified using Au L(3)- and S K-edge XANES. We also illustrate that this preparative approach can be used to form size-controllable Au NPs on carbon nanotubes. PMID:16114963

  17. {phi} meson production in Au + Au and p + p collisions at {radical}s{sub NN}=200 GeV

    SciTech Connect

    Adams, J.; Adler, C.; Aggarwal, M.M.; Ahammed, Z.; Amonett, J.; Anderson, B.D.; Arkhipkin, D.; Averichev, G.S.; Badyal, S.K.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellwied, R.; Berger, J.; Bezverkhny, B.I.; Bhardwaj, S.; Bhati, A.K.; Bichsel, H.; Billmeier, A.; Bland, L.C.; Blyth, C.O.; Bonner, B.E.; Botje, M.; Boucham, A.; Brandin, A.; Bravar, A.; Cadman, R.V.; Cai, X.Z.; Caines, H.; Calderon de la Barca Sanchez, M.; Carroll, J.; Castillo, J.; Cebra, D.; Chaloupka, P.; Chattopadhyay, S.; Chen, H.F.; Chen, Y.; Chernenko, S.P.; Cherney, M.; Chikanian, A.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Cramer, J.G.; Crawford, H.J.; Das, D.; Das, S.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Dong, W.J.; Dong, X.; Draper, J.E.; Du, F.; Dubey, A.K.; Dunin, V.B.; Dunlop, J.C.; Dutta Majumdar, M.R.; Eckardt, V.; Efimov, L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Faine, V.; Faivre, J.; Fatemi, R.; Filimonov, K.; Filip, P.; Finch, E.; Fisyak, Y.; Flierl, D.; Foley, K.J.; Fu, J.; Gagliardi, C.A.; Gagunashvili, N.; Gans, J.; Ganti, M.S.; Gaudichet, L.; Germain, M.; Geurts, F.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J.E.; Grachov, O.; Grebenyuk, O.; Gronstal, S.; Grosnick, D.; Guedon, M.; Guertin, S.M.; Gupta, A.; Gutierrez, T.D.; Hallman, T.J.; Hamed, A.; Hardtke, D.; Harris, J.W.; Heinz, M.; Henry, T.W.; Heppelmann, S.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffmann, G.W.; Horsley, M.; Huang, H.Z.; Huang, S.L.; Hughes, E.; Humanic, T.J.; Igo, G.; Ishihara, A.; Jacobs, P.; Jacobs, W.W.; Janik, M.; Johnson, I.; Jones, P.G.; Judd, E.G.; Kabana, S.; Kaplan, M.; Keane, D.; Khodyrev; Kiryluk, J.; Kisiel, A.; Klay, J.; Klein, S.R.; Klyachko, A.; Koetke, D.D.; Kollegger, T.; Kopytine, S.M.; Kotchenda, L.; Kovalenko, A.D.; Kramer, M.; Kravtsov, P.; Kravstov, V.I.; Krueger, K.; Kuhn, C.; Kulikov, A.I.; Kumar, A.; Kunde, G.J.; Kunz, C.L.; Kutuev, R.Kh.; et al.

    2004-06-01

    We report the STAR measurement of {psi} meson production in Au + Au and p + p collisions at {radical}s{sub NN} = 200 GeV. Using the event mixing technique, the {psi} spectra and yields are obtained at midrapidity for five centrality bins in Au+Au collisions and for non-singly-diffractive p+p collisions. It is found that the {psi} transverse momentum distributions from Au+Au collisions are better fitted with a single-exponential while the p+p spectrum is better described by a double-exponential distribution. The measured nuclear modification factors indicate that {psi} production in central Au+Au collisions is suppressed relative to peripheral collisions when scaled by the number of binary collisions (). The systematics of versus centrality and the constant {psi}/K{sup -} ratio versus beam species, centrality, and collision energy rule out kaon coalescence as the dominant mechanism for {psi} production.

  18. CO Oxidation mechanism on CeO2-supported Au nanoclusters

    SciTech Connect

    Kim H. Y.; Henkelman, G.

    2013-09-08

    To reveal the richer chemistry of CO oxidation by CeO2 supported Au Nanoclusters(NCs)/Nanoparticles, we design Au13 and Au12 supported on a flat and a stepped-CeO2 model (Au/CeO2) and study various kinds of CO oxidation mechanisms at the Au-CeO2 interface and the Au NC as well.

  19. Stream dynamics between 1 AU and 2 AU: A detailed comparison of observations and theory

    NASA Technical Reports Server (NTRS)

    Burlaga, L. F.; Pizzo, V.; Lazarus, A.; Gazis, P. R.

    1984-01-01

    A radial alignment of three solar wind stream structures observed by IMP-7 and -8 (at 1.0 AU) and Voyager 1 and 2 (in the range 1.4 to 1.8 AU) in late 1977 is presented. It is demonstrated that several important aspects of the observed dynamical evolution can be both qualitatively and quantitatively described with a single-fluid 2-D MHD numerical model of quasi-steady corotating flow, including accurate prediction of: (1) the formation of a corotating shock pair at 1.75 AU in the case of a simple, quasi-steady stream; (2) the coalescence of the thermodynamic and magnetic structures associated with the compression regions of two neighboring, interacting, corotating streams; and (3) the dynamical destruction of a small (i.e., low velocity-amplitude, short spatial-scale) stream by its overtaking of a slower moving, high-density region associated with a preceding transient flow. The evolution of these flow systems is discussed in terms of the concepts of filtering and entrainment.

  20. Influence of contacts on charge collection in an Au/CdTe/Au detector: A Simulation

    SciTech Connect

    Franc, J.; James, R.; Grill, R.; KUBAT, J.; BELAS, E.; HOSCHL, P.; MORAVEC, P.; AND Praus, P.

    2010-12-01

    We report our simulations on the influence of contacts on charge collection in semi-insulating (CdZn)Te with Au contacts under radiation flux, employing simultaneous solutions of the drift-diffusion and Poisson equations. The type of the space charge and the distribution of the electric field in the Au/(CdZn)Te/Au structure at high fluxes reflect the combined influence of charge generated by band bending at the electrodes, and from photogenerated carriers trapped at deep levels. We show that the space charge originating from the latter approaches dominance at high fluxes while the influence of the contacts becomes negligible. The ratio of trapping and collection times at low fluxes strongly depends on band bending, due mainly to a change in the occupation of deep levels by injection or depletion from the contacts. Such dependence is weak at high fluxes; in this case, the space charge due to trapped carriers prevails over that formed due to band bending. These phenomena can cause the formation an electric-field minimum within the device (the pinch point), the position of which is influenced by the nature of the contacts. The field minimum can completely disappear or develop into a dead layer as band bending changes.

  1. Public knowledge and public trust.

    PubMed

    Cunningham-Burley, Sarah

    2006-01-01

    As health care applications derived from human genetics research are likely to move increasingly from 'clinic to community', there is growing interest not just in how patients understand and take up health-related genetic information but also in the views of the wider population, as well as a range of professional groups. In this paper, issues relating public knowledge and public trust are raised and discussed in an attempt to move forward debates about public involvement in genomic research and the role of sociologists within interdisciplinary teams. As the field of public understanding of science has developed, we have seen a shift from a focus on the lack of scientific literacy as problem to a recognition of the range of different knowledges that people have and use as they confront science and technology in their everyday lives. As a mood for dialogue pervades many institutions in their relations with 'publics', attention must now be paid to the way in which knowledge and expertise is expressed, heard and acted upon in dialogic encounters. There is increasing concern about public trust in science and calls to increase public confidence, particularly through more open engagement with a range of publics. However, lack of trust or loss of confidence may be constructed as problems rather than reflecting empirical reality, where more complex relationships and attitudes prevail. Lack of trust is often privatized, deeply rooted in lived experience and routinely managed. Trust relations are generally characterized by ambivalence, uncertainty and risk, and are always provisional. Drawing on selected literature and empirical research to review and illustrate this field, this paper argues that scepticism or ambivalence on the part of publics are not necessarily problems to be overcome in the interest of scientific progress, but rather should be mobilized to enhance open and public debates about the nature and direction of genomics research, medicine, and the related

  2. Observation of D0 meson nuclear modifications in Au+Au collisions at sNN=200 GeV

    DOE PAGESBeta

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Alford, J.; Anson, C. D.; Aparin, A.; Arkhipkin, D.; et al

    2014-09-30

    We report the first measurement of charmed-hadron (D0) production via the hadronic decay channel (D0→K-+π+) in Au+Au collisions at √sNN=200 GeV with the STAR experiment. The charm production cross section per nucleon-nucleon collision at midrapidity scales with the number of binary collisions, Nbin, from p+p to central Au+Au collisions. The D0 meson yields in central Au+Aucollisions are strongly suppressed compared to those in p+p scaled by Nbin, for transverse momenta pT>3 GeV/c, demonstrating significant energy loss of charm quarks in the hot and dense medium. An enhancement at intermediate pT is also observed. Model calculations including strong charm-medium interactions andmore » coalescence hadronization describe our measurements.« less

  3. Wafer-level Au-Au bonding in the 350-450 °C temperature range

    NASA Astrophysics Data System (ADS)

    Tofteberg, Hannah R.; Schjølberg-Henriksen, Kari; Fasting, Eivind J.; Moen, Alexander S.; Taklo, Maaike M. V.; Poppe, Erik U.; Simensen, Christian J.

    2014-08-01

    Metal thermocompression bonding is a hermetic wafer-level packaging technology that facilitates vertical integration and shrinks the area used for device sealing. In this paper, Au-Au bonding at 350, 400 and 450 °C has been investigated, bonding wafers with 1 µm Au on top of 200 nm TiW. Test Si laminates with device sealing frames of 100, 200, and 400 µm in width were realized. Bond strengths measured by pull tests ranged from 8 to 102 MPa and showed that the bond strength increased with higher bonding temperatures and decreased with increasing frame width. Effects of eutectic reactions, grain growth in the Au film and stress relaxation causing buckles in the TiW film were most pronounced at 450 °C and negligible at 350 °C. Bond temperature below the Au-Si eutectic temperature 363 °C is recommended.

  4. Electronic and geometric structures of Au30 clusters: a network of 2e-superatom Au cores protected by tridentate protecting motifs with u3-S

    NASA Astrophysics Data System (ADS)

    Tian, Zhimei; Cheng, Longjiu

    2015-12-01

    Density functional theory calculations have been performed to study the experimentally synthesized Au30S(SR)18 and two related Au30(SR)18 and Au30S2(SR)18 clusters. The patterns of thiolate ligands on the gold cores for the three thiolate-protected Au30 nanoclusters are on the basis of the ``divide and protect'' concept. A novel extended protecting motif with u3-S, S(Au2(SR)2)2AuSR, is discovered, which is termed the tridentate protecting motif. The Au cores of Au30S(SR)18, Au30(SR)18 and Au30S2(SR)18 clusters are Au17, Au20 and Au14, respectively. The superatom-network (SAN) model and the superatom complex (SAC) model are used to explain the chemical bonding patterns, which are verified by chemical bonding analysis based on the adaptive natural density partitioning (AdNDP) method and aromatic analysis on the basis of the nucleus-independent chemical shift (NICS) method. The Au17 core of the Au30S(SR)18 cluster can be viewed as a SAN of one Au6 superatom and four Au4 superatoms. The shape of the Au6 core is identical to that revealed in the recently synthesized Au18(SR)14 cluster. The Au20 core of the Au30(SR)18 cluster can be viewed as a SAN of two Au6 superatoms and four Au4 superatoms. The Au14 core of Au30S2(SR)18 can be regarded as a SAN of two pairs of two vertex-sharing Au4 superatoms. Meanwhile, the Au14 core is an 8e-superatom with 1S21P6 configuration. Our work may aid understanding and give new insights into the chemical synthesis of thiolate-protected Au clusters.Density functional theory calculations have been performed to study the experimentally synthesized Au30S(SR)18 and two related Au30(SR)18 and Au30S2(SR)18 clusters. The patterns of thiolate ligands on the gold cores for the three thiolate-protected Au30 nanoclusters are on the basis of the ``divide and protect'' concept. A novel extended protecting motif with u3-S, S(Au2(SR)2)2AuSR, is discovered, which is termed the tridentate protecting motif. The Au cores of Au30S(SR)18, Au30(SR)18 and Au30S

  5. Medium-sized Au40(SR)24 and Au52(SR)32 nanoclusters with distinct gold-kernel structures and spectroscopic features

    NASA Astrophysics Data System (ADS)

    Xu, Wen Wu; Li, Yadong; Gao, Yi; Zeng, Xiao Cheng

    2016-01-01

    We have analyzed the structures of two medium-sized thiolate-protected gold nanoparticles (RS-AuNPs) Au40(SR)24 and Au52(SR)32 and identified the distinct structural features in their Au kernels [Sci. Adv., 2015, 1, e1500425]. We find that both Au kernels of the Au40(SR)24 and Au52(SR)32 nanoclusters can be classified as interpenetrating cuboctahedra. Simulated X-ray diffraction patterns of the RS-AuNPs with the cuboctahedral kernel are collected and then compared with the X-ray diffraction patterns of the RS-AuNPs of two other prevailing Au-kernels identified from previous experiments, namely the Ino-decahedral kernel and icosahedral kernel. The distinct X-ray diffraction patterns of RS-AuNPs with the three different types of Au-kernels can be utilized as signature features for future studies of structures of RS-AuNPs. Moreover, the simulated UV/Vis absorption spectra and Kohn-Sham orbital energy-level diagrams are obtained for the Au40(SR)24 and Au52(SR)32, on the basis of time-dependent density functional theory computation. The extrapolated optical band-edges of Au40(SR)24 and Au52(SR)32 are 1.1 eV and 1.25 eV, respectively. The feature peaks in the UV/Vis absorption spectra of the two clusters can be attributed to the d --> sp electronic transition. Lastly, the catalytic activities of the Au40(SR)24 and Au52(SR)32 are examined using CO oxidation as a probe. Both medium-sized thiolate-protected gold clusters can serve as effective stand-alone nanocatalysts.We have analyzed the structures of two medium-sized thiolate-protected gold nanoparticles (RS-AuNPs) Au40(SR)24 and Au52(SR)32 and identified the distinct structural features in their Au kernels [Sci. Adv., 2015, 1, e1500425]. We find that both Au kernels of the Au40(SR)24 and Au52(SR)32 nanoclusters can be classified as interpenetrating cuboctahedra. Simulated X-ray diffraction patterns of the RS-AuNPs with the cuboctahedral kernel are collected and then compared with the X-ray diffraction patterns of the RS-Au

  6. Ge-Au eutectic bonding of Ge {100} single crystals

    NASA Astrophysics Data System (ADS)

    Knowlton, W. B.; Itoh, K. M.; Beeman, J. W.; Emes, J. H.; Loretto, D.; Haller, E. E.

    1993-11-01

    We present preliminary results on the eutectic bonding between two {100} Ge single crystal surfaces using thin films of Au ranging from 900Å/surface to 300Å/surface and Pd (10% the thickness of Au). Following bonding, plan view optical microscopy (OM) of the cleaved interface of samples with Au thicknesses ≤ 500Å/surface show a eutectic morphology more conducive to phonon transmission through the bond interface. High resolution transmission electron microscopy (HRTEM) cross sectional interface studies of a 300Å/surface Au sample show <100> epitaxial growth of Ge. In sections of the bond, lattice continuity of the Ge is apparent through the interface. TEM studies also reveal <110> heteroepitaxial growth of Au with a Au-Ge lattice mismatch of less than 2%. Eutectic bonds with 200Å/surface Au have been attained with characterization pending. An optical polishing technique for Ge has been optimized to insure intimate contact between the Ge surfaces prior to bonding. Interferometry analysis of the optically polished Ge surface shows that surface height fluctuations lie within ±150Å across an interval of 1mm. Characterization of phonon transmission through the interface is discussed with respect to low temperature detection of ballistic phonons.

  7. Enantiospecific adsorption of cysteine on a chiral Au34 cluster

    NASA Astrophysics Data System (ADS)

    Pelayo, José de Jesús; Valencia, Israel; Díaz, Gabriela; López-Lozano, Xóchitl; Garzón, Ignacio L.

    2015-12-01

    The interaction of biological molecules like chiral amino acids with chiral metal clusters is becoming an interesting and active field of research because of its potential impact in, for example, chiral molecular recognition phenomena. In particular, the enantiospecific adsorption (EA) of cysteine (Cys) on a chiral Au55 cluster was theoretically predicted a few years ago. In this work, we present theoretical results, based on density functional theory, of the EA of non-zwitterionic cysteine interacting with the C3-Au34 chiral cluster, which has been experimentally detected in gas phase, using trapped ion electron diffraction. Our results show that, indeed, the adsorption energy of the amino acid depends on which enantiomers participate in the formation Cys-Au34 chiral complex. EA was obtained in the adsorption modes where both the thiol, and the thiol-amino functional groups of Cys are adsorbed on low-coordinated sites of the metal cluster surface. Similarly to what was obtained for the Cys-Au55 chiral complex, in the present work, it is found that the EA is originated from the different strength and location of the bond between the COOH functional group and surface Au atoms of the Au34 chiral cluster. Calculations of the vibrational spectrum for the different Cys-Au34 diastereomeric complexes predict the existence of a vibro-enantiospecific effect, indicating that the vibrational frequencies of the adsorbed amino acid depend on its handedness.

  8. Exfoliation restacking route to Au nanoparticle-clay nanohybrids

    NASA Astrophysics Data System (ADS)

    Paek, Seung-Min; Jang, Jae-Up; Hwang, Seong-Ju; Choy, Jin-Ho

    2006-05-01

    A novel gold-pillared aluminosilicate (Au-PILC) were synthesized with positively charged gold nanoparticles capped by mercaptoammonium and exfoliated silicate layers. Gold nanoparticles were synthesized by NaBH4 reduction of AuCl4- in the presence of N,N,N-Trimethyl (11-mercaptoundecyl)ammonium (HS(CH2)11NMe3+) protecting ligand in an aqueous solution, and purified by dialysis. The resulting positively charged and water-soluble gold nanoparticles were hybridized with exfoliated silicate sheets by electrostatic interaction. The formation of Au clay hybrids could be easily confirmed by the powder X-ray diffraction with the increased basal spacing of clay upon insertion of Au nanoparticles. TEM image clearly revealed that the Au particles with an average size of 4 nm maintain their structure even after intercalation. The Au nanoparticles supported by clay matrix were found to be thermally more stable, suggesting that the Au nanoparticles were homogeneously protected with clay nanoplates. The present synthetic route could be further applicable to various hybrid systems between metal nanoparticles and clays.

  9. Theoretical studies of acrolein hydrogenation on Au20 nanoparticle

    NASA Astrophysics Data System (ADS)

    Li, Zhe; Chen, Zhao-Xu; He, Xiang; Kang, Guo-Jun

    2010-05-01

    Gold nanoparticles play a key role in catalytic processes. We investigated the kinetics of stepwise hydrogenation of acrolein on Au20 cluster model and compared with that on Au(110) surface. The rate-limiting step barrier of CC reduction is about 0.5 eV higher than that of CO hydrogenation on Au(110) surface. On Au20 nanoparticle, however, the energy barrier of the rate-determining step for CC hydrogenation turns out to be slightly lower than the value for the CO reduction. The selectivity difference on the two substrate models are attributed to different adsorption modes of acrolein: via the CC on Au20, compared to through both CC and CO on Au(110). The preference switch implies that the predicted selectivity of competitive hydrogenation depends on substrate model sensitively, and particles with more low-coordinated Au atoms than flat surfaces are favorable for CC hydrogenation, which is in agreement with experimental result.

  10. First principles calculations of the optical and plasmonic response of Au alloys and intermetallic compounds

    NASA Astrophysics Data System (ADS)

    Keast, V. J.; Barnett, R. L.; Cortie, M. B.

    2014-07-01

    Pure Au is widely used in plasmonic applications even though its use is compromised by significant losses due to damping. There are some elements that are less lossy than Au (e.g. Ag or Al) but they will normally oxidize or corrode under ambient conditions. Here we examine whether alloying Au with a second element would be beneficial for plasmonic applications. In order to evaluate potential alternatives to pure Au, the density of states (DOS), dielectric function and plasmon quality factor have been calculated for alloys and compounds of Au with Al, Cd, Mg, Pd, Pt, Sn, Ti, Zn and Zr. Substitutional alloying of Au with Al, Cd, Mg and Zn was found to slightly improve the plasmonic response. Of the large number of intermetallic compounds studied, only AuAl2, Au3Cd, AuMg, AuCd and AuZn were found to be suitable for plasmonic applications.

  11. AuScope VLBI Project and Hobart 26-m Antenna

    NASA Technical Reports Server (NTRS)

    Lovell, Jim; Dickey, John; Reid, Brett; McCallum, Jamie; Shabala, Stas; Watson, Christopher; Ellingsen, Simon; Memin, Anthony

    2013-01-01

    This is a report on the activities carried out at the three AuScope VLBI observatories and the Hobart 26-m antenna. In 2012 the three AuScope 12-m antennas at Hobart (Hb), Katherine (Ke), and Yarragadee (Yg) completed their first full year of operations as an array. The Hobart 26-m antenna (Ho) continued to make a contribution to IVS, providing overlap with the Hb time series. In total the AuScope antennas and the Hobart 26 m observed for 146 antenna days in 2012. In this report we also briefly highlight our research activities during 2012 and our plans for 2013.

  12. Au plasmonics in a WS{sub 2}-Au-CuInS{sub 2} photocatalyst for significantly enhanced hydrogen generation

    SciTech Connect

    Cheng, Zhongzhou; Wang, Zhenxing E-mail: hej@nanoctr.cn; Shifa, Tofik Ahmed; Wang, Fengmei; Zhan, Xueying; Xu, Kai; He, Jun E-mail: hej@nanoctr.cn; Liu, Quanlin

    2015-11-30

    Promoting the activities of photocatalysts is still the critical challenge in H{sub 2} generation area. Here, a Au plasmon enhanced photocatalyst of WS{sub 2}-Au-CuInS{sub 2} is developed by inserting Au nanoparticles between WS{sub 2} nanotubes and CuInS{sub 2} (CIS) nanoparticles. Due to the localized surface plasmonic resonance properties from Au nanoparticles, WS{sub 2}-Au-CIS shows the best performance as compared to Au-CIS, CIS, WS{sub 2}-CIS, CIS-Au, WS{sub 2}-Au, and WS{sub 2}-CIS-Au. The surface plasmonic resonance effects dramatically intensify the absorption of visible light and help to inject hot electrons into the semiconductors. Our findings open up an efficient method to optimize the type-II structures for photocatalytic water splitting.

  13. Corrigendum to “Suppression of Υ production in d+Au and Au+Au collisions at √ SNN = 200 GeV" [Phys. Lett. B 735 (2014) 127-137

    DOE PAGESBeta

    Adamczyk, L.

    2015-04-01

    We report measurements of Υ meson production in p + p, d + Au, and Au+Au collisions using the STAR detector at RHIC. We compare the Υ yield to the measured cross section in p + p collisions in order to quantify any modifications of the yield in cold nuclear matter using d + Au data and in hot nuclear matter using Au+Au data separated into three centrality classes. Our p + p measurement is based on three times the statistics of our previous result. We obtain a nuclear modification factor for Upsilon (1S + 2S + 3S) in themore » rapidity range |y| < 1 in d + Au collisions of RdAu = 0.79 ± 0.24(stat.) ± 0.03(syst.) ± 0.10(p + p syst.). A comparison with models including shadowing and initial state parton energy loss indicates the presence of additional cold-nuclear matter suppression. Similarly, in the top 10% most-central Au + Au collisions, we measure a nuclear modification factor of R AA = 0.49 ±0.1(stat.) ±0.02(syst.) ±0.06(p + p syst.), which is a larger suppression factor than that seen in cold nuclear matter. Our results are consistent with complete suppression of excited-state Upsilon mesons in Au + Au collisions. The additional suppression in Au + Au is consistent with the level expected in model calculations that include the presence of a hot, deconfined Quark–Gluon Plasma. However, understanding the suppression seen in d + Au is still needed before any definitive statements about the nature of the suppression in Au + Au can be made.« less

  14. Corrigendum to “Suppression of Υ production in d+Au and Au+Au collisions at √ SNN = 200 GeV" [Phys. Lett. B 735 (2014) 127-137

    SciTech Connect

    Adamczyk, L.

    2015-04-01

    We report measurements of Υ meson production in p + p, d + Au, and Au+Au collisions using the STAR detector at RHIC. We compare the Υ yield to the measured cross section in p + p collisions in order to quantify any modifications of the yield in cold nuclear matter using d + Au data and in hot nuclear matter using Au+Au data separated into three centrality classes. Our p + p measurement is based on three times the statistics of our previous result. We obtain a nuclear modification factor for Upsilon (1S + 2S + 3S) in the rapidity range |y| < 1 in d + Au collisions of RdAu = 0.79 ± 0.24(stat.) ± 0.03(syst.) ± 0.10(p + p syst.). A comparison with models including shadowing and initial state parton energy loss indicates the presence of additional cold-nuclear matter suppression. Similarly, in the top 10% most-central Au + Au collisions, we measure a nuclear modification factor of R AA = 0.49 ±0.1(stat.) ±0.02(syst.) ±0.06(p + p syst.), which is a larger suppression factor than that seen in cold nuclear matter. Our results are consistent with complete suppression of excited-state Upsilon mesons in Au + Au collisions. The additional suppression in Au + Au is consistent with the level expected in model calculations that include the presence of a hot, deconfined Quark–Gluon Plasma. However, understanding the suppression seen in d + Au is still needed before any definitive statements about the nature of the suppression in Au + Au can be made.

  15. Transverse-energy distributions at midrapidity in p +p, d +Au, and Au +Au collisions at √sNN =62.4-200 GeV and implications for particle-production models

    NASA Astrophysics Data System (ADS)

    Adler, S. S.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Al-Jamel, A.; Alexander, J.; Aoki, K.; Aphecetche, L.; Armendariz, R.; Aronson, S. H.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Baldisseri, A.; Barish, K. N.; Barnes, P. D.; Bassalleck, B.; Bathe, S.; Batsouli, S.; Baublis, V.; Bauer, F.; Bazilevsky, A.; Belikov, S.; Bennett, R.; Berdnikov, Y.; Bjorndal, M. T.; Boissevain, J. G.; Borel, H.; Boyle, K.; Brooks, M. L.; Brown, D. S.; Bruner, N.; Bucher, D.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Burward-Hoy, J. M.; Butsyk, S.; Camard, X.; Campbell, S.; Chai, J.-S.; Chand, P.; Chang, W. C.; Chernichenko, S.; Chi, C. Y.; Chiba, J.; Chiu, M.; Choi, I. J.; Choudhury, R. K.; Chujo, T.; Cianciolo, V.; Cleven, C. R.; Cobigo, Y.; Cole, B. A.; Comets, M. P.; Constantin, P.; Csanád, M.; Csörgő, T.; Cussonneau, J. P.; Dahms, T.; Das, K.; David, G.; Deák, F.; Delagrange, H.; Denisov, A.; D'Enterria, D.; Deshpande, A.; Desmond, E. J.; Devismes, A.; Dietzsch, O.; Dion, A.; Drachenberg, J. L.; Drapier, O.; Drees, A.; Dubey, A. K.; Durum, A.; Dutta, D.; Dzhordzhadze, V.; Efremenko, Y. V.; Egdemir, J.; Enokizono, A.; En'yo, H.; Espagnon, B.; Esumi, S.; Fields, D. E.; Finck, C.; Fleuret, F.; Fokin, S. L.; Forestier, B.; Fox, B. D.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fukao, Y.; Fung, S.-Y.; Gadrat, S.; Gastineau, F.; Germain, M.; Glenn, A.; Gonin, M.; Gosset, J.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grosse Perdekamp, M.; Gunji, T.; Gustafsson, H.-Å.; Hachiya, T.; Hadj Henni, A.; Haggerty, J. S.; Hagiwara, M. N.; Hamagaki, H.; Hansen, A. G.; Harada, H.; Hartouni, E. P.; Haruna, K.; Harvey, M.; Haslum, E.; Hasuko, K.; Hayano, R.; He, X.; Heffner, M.; Hemmick, T. K.; Heuser, J. M.; Hidas, P.; Hiejima, H.; Hill, J. C.; Hobbs, R.; Holmes, M.; Holzmann, W.; Homma, K.; Hong, B.; Hoover, A.; Horaguchi, T.; Hur, M. G.; Ichihara, T.; Iinuma, H.; Ikonnikov, V. V.; Imai, K.; Inaba, M.; Inuzuka, M.; Isenhower, D.; Isenhower, L.; Ishihara, M.; Isobe, T.; Issah, M.; Isupov, A.; Jacak, B. V.; Jia, J.; Jin, J.; Jinnouchi, O.; Johnson, B. M.; Johnson, S. C.; Joo, K. S.; Jouan, D.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kaneta, M.; Kang, J. H.; Katou, K.; Kawabata, T.; Kawagishi, T.; Kazantsev, A. V.; Kelly, S.; Khachaturov, B.; Khanzadeev, A.; Kikuchi, J.; Kim, D. J.; Kim, E.; Kim, E. J.; Kim, G.-B.; Kim, H. J.; Kim, Y.-S.; Kinney, E.; Kiss, Á.; Kistenev, E.; Kiyomichi, A.; Klein-Boesing, C.; Kobayashi, H.; Kochenda, L.; Kochetkov, V.; Kohara, R.; Komkov, B.; Konno, M.; Kotchetkov, D.; Kozlov, A.; Kroon, P. J.; Kuberg, C. H.; Kunde, G. J.; Kurihara, N.; Kurita, K.; Kweon, M. J.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lajoie, J. G.; Lebedev, A.; Leâ Bornec, Y.; Leckey, S.; Lee, D. M.; Lee, M. K.; Leitch, M. J.; Leite, M. A. L.; Li, X. H.; Lim, H.; Litvinenko, A.; Liu, M. X.; Maguire, C. F.; Makdisi, Y. I.; Malakhov, A.; Malik, M. D.; Manko, V. I.; Mao, Y.; Martinez, G.; Masui, H.; Matathias, F.; Matsumoto, T.; McCain, M. C.; McGaughey, P. L.; Miake, Y.; Miller, T. E.; Milov, A.; Mioduszewski, S.; Mishra, G. C.; Mitchell, J. T.; Mohanty, A. K.; Morrison, D. P.; Moss, J. M.; Moukhanova, T. V.; Mukhopadhyay, D.; Muniruzzaman, M.; Murata, J.; Nagamiya, S.; Nagata, Y.; Nagle, J. L.; Naglis, M.; Nakamura, T.; Newby, J.; Nguyen, M.; Norman, B. E.; Nyanin, A. S.; Nystrand, J.; O'Brien, E.; Ogilvie, C. A.; Ohnishi, H.; Ojha, I. D.; Okada, K.; Omiwade, O. O.; Oskarsson, A.; Otterlund, I.; Oyama, K.; Ozawa, K.; Pal, D.; Palounek, A. P. T.; Pantuev, V.; Papavassiliou, V.; Park, J.; Park, W. J.; Pate, S. F.; Pei, H.; Penev, V.; Peng, J.-C.; Pereira, H.; Peresedov, V.; Peressounko, D. Yu.; Pierson, A.; Pinkenburg, C.; Pisani, R. P.; Purschke, M. L.; Purwar, A. K.; Qu, H.; Qualls, J. M.; Rak, J.; Ravinovich, I.; Read, K. F.; Reuter, M.; Reygers, K.; Riabov, V.; Riabov, Y.; Roche, G.; Romana, A.; Rosati, M.; Rosendahl, S. S. E.; Rosnet, P.; Rukoyatkin, P.; Rykov, V. L.; Ryu, S. S.; Sahlmueller, B.; Saito, N.; Sakaguchi, T.; Sakai, S.; Samsonov, V.; Sanfratello, L.; Santo, R.; Sarsour, M.; Sato, H. D.; Sato, S.; Sawada, S.; Schutz, Y.; Semenov, V.; Seto, R.; Sharma, D.; Shea, T. K.; Shein, I.; Shibata, T.-A.; Shigaki, K.; Shimomura, M.; Shohjoh, T.; Shoji, K.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Sim, K. S.; Singh, C. P.; Singh, V.; Skutnik, S.; Smith, W. C.; Soldatov, A.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Sourikova, I. V.; Staley, F.; Stankus, P. W.; Stenlund, E.; Stepanov, M.; Ster, A.; Stoll, S. P.; Sugitate, T.; Suire, C.; Sullivan, J. P.; Sziklai, J.; Tabaru, T.; Takagi, S.; Takagui, E. M.; Taketani, A.; Tanaka, K. H.; Tanaka, Y.; Tanida, K.; Tannenbaum, M. J.; Taranenko, A.; Tarján, P.; Thomas, T. L.; Togawa, M.; Tojo, J.; Torii, H.; Towell, R. S.; Tram, V.-N.; Tserruya, I.; Tsuchimoto, Y.; Tuli, S. K.; Tydesjö, H.; Tyurin, N.; Uam, T. J.; Vale, C.; Valle, H.; van Hecke, H. W.; Velkovska, J.; Velkovsky, M.; Vértesi, R.; Veszprémi, V.; Vinogradov, A. A.; Volkov, M. A.; Vznuzdaev, E.; Wagner, M.; Wang, X. R.; Watanabe, Y.; Wessels, J.; White, S. N.; Willis, N.; Winter, D.; Wohn, F. K.; Woody, C. L.; Wysocki, M.; Xie, W.; Yanovich, A.; Yokkaichi, S.; Young, G. R.; Younus, I.; Yushmanov, I. E.; Zajc, W. A.; Zaudtke, O.; Zhang, C.; Zhou, S.; Zimányi, J.; Zolin, L.; Zong, X.; Phenix Collaboration

    2014-04-01

    Measurements of the midrapidity transverse-energy distribution, dET/dη, are presented for p +p, d +Au, and Au +Au collisions at √sNN =200 GeV and additionally for Au +Au collisions at √sNN =62.4 and 130 GeV. The dET/dη distributions are first compared with the number of nucleon participants Npart, number of binary collisions Ncoll, and number of constituent-quark participants Nqp calculated from a Glauber model based on the nuclear geometry. For Au +Au, /Npart increases with Npart, while /Nqp is approximately constant for all three energies. This indicates that the two-component ansatz, dET/dη ∝(1-x)Npart/2+xNcoll, which was used to represent ET distributions, is simply a proxy for Nqp, and that the Ncoll term does not represent a hard-scattering component in ET distributions. The dET/dη distributions of Au +Au and d +Au are then calculated from the measured p +p ET distribution using two models that both reproduce the Au +Au data. However, while the number-of-constituent-quark-participant model agrees well with the d +Au data, the additive-quark model does not.

  16. From Superatomic Au25(SR)18- to Superatomic M@Au24(SR)18q Core-shell Clusters.

    SciTech Connect

    Jiang, Deen; Dai, Sheng

    2009-01-01

    Au{sub 25}(SR){sub 18}{sup -} belongs to a new type of superatom that features an icosahedral Au{sub 13} core-shell structure and a protective layer of six RS(Au-SR){sub 2} motifs. This superatom has a magic number of 8 free electrons that fully fill the 1s and 1p levels of the electron-shell model. By applying this superatom concept to the core-substitution chemistry of Au{sub 25}(SR){sub 18}{sup -}, we first scanned the periodic table for the potential core atom M by applying a simple rule derived from the 8-electron count and then optimized the selected candidates by density functional theory calculations to create many series of M{at}Au{sub 24}(SR){sub 18}{sup q} core-shell nanoclusters. We found that 16 elements from groups 1, 2, and 10-14 of the periodic table can maintain both electronic and geometric structures of the original Au{sub 25}(SR){sub 18}{sup -} magic cluster, indicating that the electron-counting rule based on the superatom concept is powerful in predicting viable M{at}Au{sub 24}(SR){sub 18}{sup q} clusters. Our work opens up a promising area for experimental exploration.

  17. Au and Ag/Au double-shells hollow nanoparticles with improved near infrared surface plasmon and photoluminescence properties.

    PubMed

    Ghosh Chaudhuri, Rajib; Paria, Santanu

    2016-01-01

    Metallic hollow nanoparticles have been continuously drawing researcher's attention because of their excellent improved performance compare to the spherical particles in catalysis, photonics, information storage, surface-enhanced Raman scattering, and sensors applications. In this article we demonstrate a novel route for the synthesis of single and double-shells Au and Ag/Au bimetallic hollow nanoparticles using elemental sulfur as a sacrificial core. We also investigate the optical properties of these new hollow particles and compare with that of pure spherical nanoparticles. The surface plasmon resonance spectra of solid Au, hollow single shell Au, and double shells Ag/Au nanoparticles show that there is gradual shifting of Au peak position towards the higher wavelengths for these three nanoparticles respectively. A similar observation was also found for photoluminescence spectra. In case of double-shells Ag/Au hollow nanoparticles the emission spectrum shifts towards the NIR region with significant higher intensity, which is beneficial for in vivo biomedical applications of these particles.

  18. Gold surfaces and nanoparticles are protected by Au(0)-thiyl species and are destroyed when Au(I)-thiolates form.

    PubMed

    Reimers, Jeffrey R; Ford, Michael J; Halder, Arnab; Ulstrup, Jens; Hush, Noel S

    2016-03-15

    The synthetic chemistry and spectroscopy of sulfur-protected gold surfaces and nanoparticles is analyzed, indicating that the electronic structure of the interface is Au(0)-thiyl, with Au(I)-thiolates identified as high-energy excited surface states. Density-functional theory indicates that it is the noble character of gold and nanoparticle surfaces that destabilizes Au(I)-thiolates. Bonding results from large van der Waals forces, influenced by covalent bonding induced through s-d hybridization and charge polarization effects that perturbatively mix in some Au(I)-thiolate character. A simple method for quantifying these contributions is presented, revealing that a driving force for nanoparticle growth is nobleization, minimizing Au(I)-thiolate involvement. Predictions that Brust-Schiffrin reactions involve thiolate anion intermediates are verified spectroscopically, establishing a key feature needed to understand nanoparticle growth. Mixing of preprepared Au(I) and thiolate reactants always produces Au(I)-thiolate thin films or compounds rather than monolayers. Smooth links to O, Se, Te, C, and N linker chemistry are established.

  19. Design and Preparation of Supported Au Catalyst with Enhanced Catalytic Activities by Rationally Positioning Au Nanoparticles on Anatase.

    PubMed

    Wang, Liang; Wang, Hong; Rice, Andrew E; Zhang, Wei; Li, Xiaokun; Chen, Mingshu; Meng, Xiangju; Lewis, James P; Xiao, Feng-Shou

    2015-06-18

    A synergistic effect between individual components is crucial for increasing the activity of metal/metal oxide catalysts. The greatest challenge is how to control the synergistic effect to obtain enhanced catalytic performance. Through density functional theory calculations of model Au/TiO2 catalysts, it is suggested that there is strong interaction between Au nanoparticles and Ti species at the edge/corner sites of anatase, which is favorable for the formation of stable oxygen vacancies. Motivated by this theoretical analysis, we have rationally prepared Au nanoparticles attached to edge/corner sites of anatase support (Au/TiO2-EC), confirmed by their HR-TEM images. As expected, this strong interaction is well characterized by Raman, UV-visible, and XPS techniques. Very interestingly, compared with conventional Au catalysts, Au/TiO2-EC exhibits superior catalytic activity in the oxidations using O2. Our approach to controlling Au nanoparticle positioning on anatase to obtain enhanced catalytic activity offers an efficient strategy for developing more novel supported metal catalysts.

  20. XRD analysis on ZnO and Au film crystal orientation in ZnO/Au/SiO2 structure

    NASA Astrophysics Data System (ADS)

    Qin, Huibin; Yu, Hong; Chen, Yunxang

    2000-05-01

    The orientation of the Zn/Au/Si structure was examined by XRD. The experiment showed that the ZnO/Au/Si films deposited by magnetron sputtering were possessed of a preferred orientation in C axis perpendicular to the film surface. The (111) of Au film was possessed of a preferred <111> orientation which was perpendicular to the film surface also. The XRD (theta) approximately 2 (theta) scan irradiated that there were only (001) peaks in excellent orientated ZnO films. The rock cure scan demonstrated that the C axis of ZnO film was not exactly perpendicular to the surface, the angular divergence was about 2 degree(s), and the space divergence angle about 1.5 degree(s). Expert the (kkk) main peaks of Au film there were weak diffraction peaks, such as (002), (022), and (311) peaks. The phenomena indicated that in Au film there was not only (111) plane in parallel to the surface of substrate. As there was only 12% dis-matching between Au (111) and ZnO (001), the Au (111) oriented film was facilitated for the ZnO (001) orientation in C axis and deposing parameters adjustment.

  1. Design and Preparation of Supported Au Catalyst with Enhanced Catalytic Activities by Rationally Positioning Au Nanoparticles on Anatase.

    PubMed

    Wang, Liang; Wang, Hong; Rice, Andrew E; Zhang, Wei; Li, Xiaokun; Chen, Mingshu; Meng, Xiangju; Lewis, James P; Xiao, Feng-Shou

    2015-06-18

    A synergistic effect between individual components is crucial for increasing the activity of metal/metal oxide catalysts. The greatest challenge is how to control the synergistic effect to obtain enhanced catalytic performance. Through density functional theory calculations of model Au/TiO2 catalysts, it is suggested that there is strong interaction between Au nanoparticles and Ti species at the edge/corner sites of anatase, which is favorable for the formation of stable oxygen vacancies. Motivated by this theoretical analysis, we have rationally prepared Au nanoparticles attached to edge/corner sites of anatase support (Au/TiO2-EC), confirmed by their HR-TEM images. As expected, this strong interaction is well characterized by Raman, UV-visible, and XPS techniques. Very interestingly, compared with conventional Au catalysts, Au/TiO2-EC exhibits superior catalytic activity in the oxidations using O2. Our approach to controlling Au nanoparticle positioning on anatase to obtain enhanced catalytic activity offers an efficient strategy for developing more novel supported metal catalysts. PMID:26266615

  2. Characterization of Pt-Au and Ni-Au Clusters on TiO(2)(110)

    SciTech Connect

    Chen, D. A.; Mullins, David R; Ratliff, J. S.; He, Wei; Tenney, Samuel

    2011-01-01

    The surface composition and properties of Pt-Au and Ni-Au clusters on TiO{sub 2}(110) have been studied by scanning tunneling microscopy (STM), low energy ion scattering (LEIS) and soft X-ray photoelectron spectroscopy (sXPS). STM studies show that bimetallic clusters are formed during sequential deposition of the two metals, regardless of the order of deposition. At the 2 ML of Au/2 ML of Pt or Ni coverages studied here, the second metal contributes to the growth of existing clusters rather than forming new pure metal clusters. LEIS experiments demonstrate that the surfaces of the bimetallic clusters are almost 100% Au when 2 ML of Au is deposited on top of 2 ML of Pt or Ni. However, a much larger fraction of Pt or Ni (50 and 20%, respectively) remains at the surface when 2 ML of Pt or Ni is deposited on 2 ML of Au, most likely due to limited diffusion of atoms within the clusters at room temperature. According to sXPS investigations, the binding energies of the metals in the bimetallic clusters are shifted from those observed for pure metal clusters; the Pt(4f{sub 7/2}) and Ni(3p{sub 3/2}) peaks are shifted to lower binding energies while the position of the Au(4f{sub 7/2}) peak is dominated by surface core level shifts. Pure Pt clusters as well as 0.4 ML of Au on 2 ML of Pt clusters reduce the titania support upon encapsulation after annealing to 800 K, whereas 2 ML of Au on 2 ML of Pt clusters do not reduce titania, presumably because there is no Pt at the surface of the clusters. Pure Ni clusters are also known to become encapsulated upon heating, but the reduction of titania is much less extensive compared to that of pure Pt clusters.

  3. Characterization of Pt-Au and Ni-Au Clusters on TiO2(110)

    SciTech Connect

    S Tenney; W He; J Ratliff; D Mullins; D Chen

    2011-12-31

    The surface composition and properties of Pt-Au and Ni-Au clusters on TiO{sub 2}(110) have been studied by scanning tunneling microscopy (STM), low energy ion scattering (LEIS) and soft X-ray photoelectron spectroscopy (sXPS). STM studies show that bimetallic clusters are formed during sequential deposition of the two metals, regardless of the order of deposition. At the 2 ML of Au/2 ML of Pt or Ni coverages studied here, the second metal contributes to the growth of existing clusters rather than forming new pure metal clusters. LEIS experiments demonstrate that the surfaces of the bimetallic clusters are almost 100% Au when 2 ML of Au is deposited on top of 2 ML of Pt or Ni. However, a much larger fraction of Pt or Ni (50 and 20%, respectively) remains at the surface when 2 ML of Pt or Ni is deposited on 2 ML of Au, most likely due to limited diffusion of atoms within the clusters at room temperature. According to sXPS investigations, the binding energies of the metals in the bimetallic clusters are shifted from those observed for pure metal clusters; the Pt(4f{sub 7/2}) and Ni(3p{sub 3/2}) peaks are shifted to lower binding energies while the position of the Au(4f{sub 7/2}) peak is dominated by surface core level shifts. Pure Pt clusters as well as 0.4 ML of Au on 2 ML of Pt clusters reduce the titania support upon encapsulation after annealing to 800 K, whereas 2 ML of Au on 2 ML of Pt clusters do not reduce titania, presumably because there is no Pt at the surface of the clusters. Pure Ni clusters are also known to become encapsulated upon heating, but the reduction of titania is much less extensive compared to that of pure Pt clusters.

  4. Visible light photoactivity of TiO2 loaded with monometallic (Au or Pt) and bimetallic (Au/Pt) nanoparticles

    NASA Astrophysics Data System (ADS)

    Gołąbiewska, Anna; Lisowski, Wojciech; Jarek, Marcin; Nowaczyk, Grzegorz; Zielińska-Jurek, Anna; Zaleska, Adriana

    2014-10-01

    TiO2 modified with monometallic (Au or Pt) and bimetallic (Au/Pt) nanoparticles have been prepared using a water-in-oil microemulsion system (water/AOT/cyclohexane) followed by calcination step. The effect of metal ratio, reducing agent type (NaBH4 or N2H4), TiO2 matrix type (P-25, ST-01, TiO-5, TiO2 nanotubes or TiO2 obtained by TIP hydrolysis) as well as calcination temperature (from 350 to 650 °C) were systematically investigated. Obtained photocatalysts were characterized by UV-vis diffuse-reflectance spectroscopy (DRS), BET surface area measurements, scanning transmission microscopy (STEM), X-ray diffraction analysis (XRD), and X-ray photoelectron spectroscopy (XPS). Photocatalytic activity under visible light (λ > 420 nm) has been estimated in phenol degradation reaction in aqueous phase. The results showed that phenol degradation rate under visible light in the presence of TiO2 loaded with Au/Pt nanoparticles differed from 0.7 to 2.2 μmol dm-3 min-1 for samples prepared using different reducing agent. Sodium borohydride (NaBH4) favors formation of smaller Au/Pt nanoparticles and higher amount gold in Au/Pt is in the form of electronegative species (Auδ-) resulted in higher photoactivity. TiO2 obtained by TIP hydrolysis in microemulsion system seems to be the best support for Au/Pt nanoparticles from all among investigated matrix. It was also observed that enhancement of calcination temperature from 450 to 650 °C resulted in rapid drop of Au/Pt-TiO2 photoactivity under visible light due to surface area shrinkage, crystal structure change and probably change in Au/Pt nanoparticles morphology.

  5. Recherche de leptons lourds au LEP 2

    NASA Astrophysics Data System (ADS)

    Tafirout, Reda

    En 1989, la mise en opération de la première phase du LEP (le LEP 1), au CERN, a une Energie correspondant a la résonance du boson Z0, a permis d'étudier et de confirmer avec une grande précision le Modèle Standard des interactions électrofaibles. Malgré le succès remarquable de ce modèle à décrire toutes les données expérimentales recueillies jusqu'à ce jour en physique des hautes énergies, ce dernier laisse plusieurs questions sans réponse. Il n'explique pas entre autres pourquoi il n'y a que trois familles de particules dont le neutrino associé est léger et la hiérarchie des masses observées des fermions reste une énigme. Ici, nous nous intéressons à l'existence éventuelle de nouveaux fermions, tels que prédits par des extensions du Modèle Standard. Ces nouveaux fermions ont été recherches au LEP 1, mais en vain, et une limite inférieure sur leur masse d'environ MZ/2 a pu être imposée. La deuxième phase du LEP (le LEP 2) qui a débuté dans l'automne 1995 avec une énergie disponible de √s = 130, et 136 GeV, puis dans l'été 1996 a √s = 161 GeV a permis d'améliorer ces limites. Nous présentons ici la recherche de leptons lourds, neutres (N) et chargés (L+/-), effectuée à partir des données recueillies dans l'automne 1996 avec le détecteur de la collaboration OPAL au LEP 2, à des énergies au centre de masse de √s = 170 et 172 GeV. La luminosité totale intégrée fut de 10.3 pb-1. Un nouveau générateur, EXOTIC, conçu et développé a cette fin, a été utilise pour la simulation des échantillons d'événements Monte Carlo qui ont servi à comparer les données obtenues avec les prédictions théoriques. Plus spécifiquement, nous avons recherché le processus e+e- --> NN où N, pouvant être de type Dirac ou Majorana, se désintègre en un lepton léger standard (e, μ, ou τ) et un boson W+/- virtuel (W+/-*). Pour un N de type Dirac, une limite inférieure sur la masse à 95% de niveau de confiance est obtenue

  6. Evaluation of the Olympus AU-510 analyser.

    PubMed

    Farré, C; Velasco, J; Ramón, F

    1991-01-01

    The selective multitest Olympus AU-510 analyser was evaluated according to the recommendations of the Comision de Instrumentacion de la Sociedad Española de Quimica Clinica and the European Committee for Clinical Laboratory Standards. The evaluation was carried out in two stages: an examination of the analytical units and then an evaluation in routine work conditions. The operational characteristics of the system were also studied.THE FIRST STAGE INCLUDED A PHOTOMETRIC STUDY: dependent on the absorbance, the inaccuracy varies between +0.5% to -0.6% at 405 nm and from -5.6% to 10.6% at 340 nm; the imprecision ranges between -0.22% and 0.56% at 405 nm and between 0.09% and 2.74% at 340 nm. Linearity was acceptable, apart from a very low absorbance for NADH at 340 nm; and the imprecision of the serum sample pipetter was satisfactory.TWELVE SERUM ANALYTES WERE STUDIED UNDER ROUTINE CONDITIONS: glucose, urea urate, cholesterol, triglycerides, total bilirubin, creatinine, phosphate, iron, aspartate aminotransferase, alanine aminotransferase and gamma-glutamyl transferase.The within-run imprecision (CV%) ranged from 0.67% for phosphate to 2.89% for iron and the between-run imprecision from 0.97% for total bilirubin to 7.06% for iron. There was no carryover in a study of the serum sample pipetter. Carry-over studies with the reagent and sample pipetters shows some cross contamination in the iron assay.

  7. Activated Dissociation of HCl on Au(111).

    PubMed

    Shirhatti, Pranav R; Geweke, Jan; Steinsiek, Christoph; Bartels, Christof; Rahinov, Igor; Auerbach, Daniel J; Wodtke, Alec M

    2016-04-01

    We report zero-coverage reaction probabilities (S0) for HCl dissociative adsorption on Au(111) obtained by the seeded molecular beam hot-nozzle method. For measurements at normal incidence with mean translational energies ranging from 0.94 to 2.56 eV (nozzle temperatures 296 to 1060 K), S0 increased from 6 × 10(-6) to 2 × 10(-2). S0 also increased with increasing nozzle temperature for fixed incidence energy associated with the motion normal to the surface. Accounting for the influence of the vibrational state population and translational energy distributions in the incident beam, we are able to compare the experimental results to recent theoretical predictions. These calculations, performed employing 6-D quantum dynamics on an electronically adiabatic potential energy surface obtained using density functional theory at the level of the generalized gradient approximation and the static surface approximation, severely overestimate the reaction probabilities when compared with our experimental results. We discuss some possible reasons for this large disagreement. PMID:26990513

  8. Metanephrine neuroendocrine tumor marker detection by SERS using Au nanoparticle/Au film sandwich architecture.

    PubMed

    Boca, Sanda; Farcau, Cosmin; Baia, Monica; Astilean, Simion

    2016-02-01

    Neuroendocrine tumors, such as pheochromocytoma or paraganglioma, are dangerous tumors that constitute a potential threat for a large number of patients. Currently, the biochemical diagnosis of neuroendocrine tumors is based on measurement of the direct secretory products of the adrenomedullary-sympathetic system or of their metabolites, such as catecholamines or their metanephrine derivatives, from plasma or urine. The techniques used for analysis of plasma free metanephrines, i.e. high-performance liquid chromatography or high-performance liquid chromatography coupled with mass-spectrometry are technically-demanding and time consuming, which limit their availability. Here we demonstrate a simple, fast and low-cost method for detecting metanephrine by Surface Enhanced Raman Scattering (SERS). The protocol consists in using evaporation-induced self-assembly of gold (Au) nanoparticles incubated with the analyte, on planar gold films. The assembly process produces regions with a dense distribution of both inter-particle gaps and particle-film gaps. Finite-difference time-domain simulations confirm that both kinds of gaps are locations of enhanced electromagnetic fields resulting from inter-particle and particle-film plasmonic coupling, useful for SERS amplification. Metanephrine vibrational bands assignment was performed according to density functional theory calculations. Metanephrine metabolite was detected in liquid at concentration levels lower than previously reported for other similar metabolites. The obtained results demonstrate that the Au nanoparticle/Au film exhibits noticeable SERS amplification of the adsorbed metabolite and can be used in the design of efficient, stable SERS-active substrates for the detection and identification of specific tumor markers.

  9. Metanephrine neuroendocrine tumor marker detection by SERS using Au nanoparticle/Au film sandwich architecture.

    PubMed

    Boca, Sanda; Farcau, Cosmin; Baia, Monica; Astilean, Simion

    2016-02-01

    Neuroendocrine tumors, such as pheochromocytoma or paraganglioma, are dangerous tumors that constitute a potential threat for a large number of patients. Currently, the biochemical diagnosis of neuroendocrine tumors is based on measurement of the direct secretory products of the adrenomedullary-sympathetic system or of their metabolites, such as catecholamines or their metanephrine derivatives, from plasma or urine. The techniques used for analysis of plasma free metanephrines, i.e. high-performance liquid chromatography or high-performance liquid chromatography coupled with mass-spectrometry are technically-demanding and time consuming, which limit their availability. Here we demonstrate a simple, fast and low-cost method for detecting metanephrine by Surface Enhanced Raman Scattering (SERS). The protocol consists in using evaporation-induced self-assembly of gold (Au) nanoparticles incubated with the analyte, on planar gold films. The assembly process produces regions with a dense distribution of both inter-particle gaps and particle-film gaps. Finite-difference time-domain simulations confirm that both kinds of gaps are locations of enhanced electromagnetic fields resulting from inter-particle and particle-film plasmonic coupling, useful for SERS amplification. Metanephrine vibrational bands assignment was performed according to density functional theory calculations. Metanephrine metabolite was detected in liquid at concentration levels lower than previously reported for other similar metabolites. The obtained results demonstrate that the Au nanoparticle/Au film exhibits noticeable SERS amplification of the adsorbed metabolite and can be used in the design of efficient, stable SERS-active substrates for the detection and identification of specific tumor markers. PMID:26820563

  10. Heterostructured Au/Pd-M (M = Au, Pd, Pt) nanoparticles with compartmentalized composition, morphology, and electrocatalytic activity

    NASA Astrophysics Data System (ADS)

    Lutz, Patrick S.; Bae, In-Tae; Maye, Mathew M.

    2015-09-01

    The synthesis, processing, and galvanic exchange of three heterostructured nanoparticle systems is described. The surface accessibility and redox potential of a Au/Pd-Ag dumbbell nanoparticle, where a Au/Pd core/shell region, and a silver region make up the domains, was used to prepare the new nanostructures with controlled composition, morphology, and microstructure. Results indicate that the silver domain was particularly susceptible to galvanic displacement, and was exchanged to Au/Pd-M (M = Au, Pd, Pt). Interestingly, the dumbbell morphology remained after exchange, and the silver region was transformed to hollow, parachute, or concentric domains respectively. The morphology and microstructure change was visualized via TEM and HRTEM, and the composition changes were probed via STEM-EDS imaging and XPS. The electrocatalytic activity of the Au/Pd-M towards methanol oxidation was studied, with results indicating that the Au/Pd-Pt nanoparticles had high activity attributed to the porous nature of the platinum domains.The synthesis, processing, and galvanic exchange of three heterostructured nanoparticle systems is described. The surface accessibility and redox potential of a Au/Pd-Ag dumbbell nanoparticle, where a Au/Pd core/shell region, and a silver region make up the domains, was used to prepare the new nanostructures with controlled composition, morphology, and microstructure. Results indicate that the silver domain was particularly susceptible to galvanic displacement, and was exchanged to Au/Pd-M (M = Au, Pd, Pt). Interestingly, the dumbbell morphology remained after exchange, and the silver region was transformed to hollow, parachute, or concentric domains respectively. The morphology and microstructure change was visualized via TEM and HRTEM, and the composition changes were probed via STEM-EDS imaging and XPS. The electrocatalytic activity of the Au/Pd-M towards methanol oxidation was studied, with results indicating that the Au/Pd-Pt nanoparticles had

  11. Distributions of charged hadrons associated with high transverse momentum particles in pp and Au+Au collisions at sqrt[sNN]=200 GeV.

    PubMed

    Adams, J; Adler, C; Aggarwal, M M; Ahammed, Z; Amonett, J; Anderson, B D; Arkhipkin, D; Averichev, G S; Badyal, S K; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bezverkhny, B I; Bhardwaj, S; Bhati, A K; Bichsel, H; Billmeier, A; Bland, L C; Blyth, C O; Bonner, B E; Botje, M; Boucham, A; Brandin, A; Bravar, A; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca Sánchez, M; Carroll, J; Castillo, J; Cebra, D; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Christie, W; Coffin, J P; Cormier, T M; Cramer, J G; Crawford, H J; Das, D; Das, S; Derevschikov, A A; Didenko, L; Dietel, T; Dong, W J; Dong, X; Draper, J E; Du, F; Dubey, A K; Dunin, V B; Dunlop, J C; Dutta Majumdar, M R; Eckardt, V; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Faine, V; Faivre, J; Fatemi, R; Filimonov, K; Filip, P; Finch, E; Fisyak, Y; Flierl, D; Foley, K J; Fu, J; Gagliardi, C A; Gagunashvili, N; Gans, J; Ganti, M S; Gaudichet, L; Geurts, F; Ghazikhanian, V; Ghosh, P; Gonzalez, J E; Grachov, O; Grebenyuk, O; Gronstal, S; Grosnick, D; Guertin, S M; Gupta, A; Gutierrez, T D; Hallman, T J; Hamed, A; Hardtke, D; Harris, J W; Heinz, M; Henry, T W; Heppelmann, S; Herston, T; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Huang, H Z; Huang, S L; Hughes, E; Humanic, T J; Igo, G; Ishihara, A; Jacobs, P; Jacobs, W W; Janik, M; Jiang, H; Johnson, I; Jones, P G; Judd, E G; Kabana, S; Kaplan, M; Keane, D; Khodyrev, V Yu; Kiryluk, J; Kisiel, A; Klay, J; Klein, S R; Klyachko, A; Koetke, D D; Kollegger, T; Kopytine, M; Kotchenda, L; Kovalenko, A D; Kramer, M; Kravtsov, P; Kravtsov, V I; Krueger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kunde, G J; Kunz, C L; Kutuev, R Kh; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; Lasiuk, B; Laue, F; Lauret, J; Lebedev, A; Lednický, R; Levine, M J; Li, C; Li, Q; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, L; Liu, Z; Liu, Q J; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; Lopez-Noriega, M; Love, W A; Ludlam, T; Lynn, D; Ma, J; Ma, Y G; Magestro, D; Mahajan, S; Mangotra, L K; Mahapatra, D P; Majka, R; Manweiler, R; Margetis, S; Markert, C; Martin, L; Marx, J; Matis, H S; Matulenko, Yu A; McClain, C J; McShane, T S; Meissner, F; Melnick, Yu; Meschanin, A; Miller, M L; Milosevich, Z; Minaev, N G; Mironov, C; Mischke, A; Mishra, D; Mitchell, J; Mohanty, B; Molnar, L; Moore, C F; Mora-Corral, M J; Morozov, D A; Morozov, V; de Moura, M M; Munhoz, M G; Nandi, B K; Nayak, S K; Nayak, T K; Nelson, J M; Netrakanti, P K; Nikitin, V A; Nogach, L V; Norman, B; Nurushev, S B; Odyniec, G; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Paic, G; Pal, S K; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Peitzmann, T; Perevoztchikov, V; Perkins, C; Peryt, W; Petrov, V A; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M; Potrebenikova, E; Potukuchi, B V K S; Prindle, D; Pruneau, C; Putschke, J; Rai, G; Rakness, G; Raniwala, R; Raniwala, S; Ravel, O; Ray, R L; Razin, S V; Reichhold, D; Reid, J G; Renault, G; Retiere, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L J; Sahoo, R; Sakrejda, I; Salur, S; Sandweiss, J; Savin, I; Schambach, J; Scharenberg, R P; Schmitz, N; Schroeder, L S; Schweda, K; Seger, J; Seyboth, P; Shahaliev, E; Shao, M; Shao, W; Sharma, M; Shestermanov, K E; Shimanskii, S S; Singaraju, R N; Simon, F; Skoro, G; Smirnov, N; Snellings, R; Sood, G; Sorensen, P; Sowinski, J; Speltz, J; Spinka, H M; Srivastava, B; Stanislaus, T D S; Stock, R; Stolpovsky, A; Strikhanov, M; Stringfellow, B; Struck, C; Suaide, A A P; Sugarbaker, E; Suire, C; Sumbera, M; Surrow, B; Symons, T J M; Szanto de Toledo, A; Szarwas, P; Tai, A; Takahashi, J; Tang, A H; Thein, D; Thomas, J H; Timoshenko, S; Tokarev, M; Tonjes, M B; Trainor, T A; Trentalange, S; Tribble, R E; Tsai, O; Ullrich, T; Underwood, D G; Van Buren, G; Vandermolen, A M; Varma, R; Vasilevski, I; Vasiliev, A N; Vernet, R; Vigdor, S E; Viyogi, Y P; Voloshin, S A; Vznuzdaev, M; Waggoner, W; Wang, F; Wang, G; Wang, G; Wang, X L; Wang, Y; Wang, Z M; Ward, H; Watson, J W; Webb, J C; Wells, R; Westfall, G D; Whitten, C; Wieman, H; Willson, R; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Z; Xu, Z Z; Yamamoto, E; Yepes, P; Yurevich, V I; Yuting, B; Zanevski, Y V; Zhang, H; Zhang, W M; Zhang, Z P; Zhaomin, Z P; Zizong, Z P; Zołnierczuk, P A; Zoulkarneev, R; Zoulkarneeva, J; Zubarev, A N

    2005-10-01

    Charged hadrons in [EQUATION: SEE TEXT] associated with particles of [EQUATION: SEE TEXT] are reconstructed in pp and Au+Au collisions at sqrt[sNN]=200 GeV. The associated multiplicity and p magnitude sum are found to increase from pp to central Au+Au collisions. The associated p distributions, while similar in shape on the nearside, are significantly softened on the awayside in central Au+Au relative to pp and not much harder than that of inclusive hadrons. The results, consistent with jet quenching, suggest that the awayside fragments approach equilibration with the medium traversed. PMID:16241721

  12. Microwave synthesis of Au nanoparticles as promising SERS substrates

    NASA Astrophysics Data System (ADS)

    Wang, Lan; Feng, Shangyuan; Liu, Nenrong; Lei, Jinping; Lin, Hongxin; Sun, Liqing; Chen, Rong

    2012-11-01

    A novel method for rapidly synthesized Au colloidal under microwave irradiation was present in this paper. Size of the Au nanoparticles varied from 10 nm to 60 nm along with varying mol fractions by chloroauric acid solution reduced with sodium citrate. The prepared Au nanoparticles were characterized by transmission electron microscope (TEM) and ultraviolet-visible (UV-Vis) spectrophotometer. It is found that the nanoparticle size and shape are highly dependent on the reaction time and the molar ratios of the reducing agent. By the SERS measurements of R6G, 4-MBA and Crystal violet, this Au colloid is shown to be an excellent SERS substrate with good stability. As the fabrication process of this SERS substrate is simple and inexpensive, this method may be used in large-scale preparation of substrates that can serve as an ideal SERS substrate in biomedical application.

  13. γ decay from the quasicontinuum of Au,198197

    NASA Astrophysics Data System (ADS)

    Giacoppo, F.; Bello Garrote, F. L.; Bernstein, L. A.; Bleuel, D. L.; Firestone, R. B.; Görgen, A.; Guttormsen, M.; Hagen, T. W.; Klintefjord, M.; Koehler, P. E.; Larsen, A. C.; Nyhus, H. T.; Renstrøm, T.; Sahin, E.; Siem, S.; Tornyi, T.

    2015-05-01

    The average electromagnetic dipole response of levels in the quasicontinuum of Au,198197 has been measured using (3He,3He' ) and (d ,p ) reactions. The extracted γ -ray strength functions have been normalized according to three model assumptions for the nuclear spin distribution. An enhancement in the energy region Eγ=3.0 -6.5 MeV is observed for both isotopes. The E 1 component of such excess of strength is studied in detail for 198Au and is interpreted as the pygmy dipole resonance with an energy centroid of 5.9 (1 ) MeV and exhausts about 1 % of the total integrated strength. The pygmy dipole resonance is shown to have a significant impact on the calculated 197Au (n,γ ) 198Au cross section.

  14. Assembling Bare Au Nanoparticles at Positively Charged Templates

    PubMed Central

    Wang, Wenjie; Zhang, Honghu; Kuzmenko, Ivan; Mallapragada, Surya; Vaknin, David

    2016-01-01

    In-situ X-ray reflectivity (XRR) and grazing incidence X-ray small-angle scattering (GISAXS) reveal that unfunctionalized (bare) gold nanoparticles (AuNP) spontaneously adsorb to a cationic lipid template formed by a Langmuir monolayer of DPTAP (1,2-dihexadecanoyl-3-trimethylammonium-propane) at vapor/aqueous interfaces. Analysis of the XRR yields the electron density profile across the charged-interfaces along the surface normal showing the AuNPs assemble with vertical thickness comparable to the particle size. The GISAXS analysis indicates that the adsorbed mono-particle layer exhibits short-range in-plane correlations. By contrast, single-stranded DNA-functionalized AuNPs, while attracted to the positively charged surface (more efficiently with the addition of salt to the solution), display less in-plane regular packing compared to bare AuNPs. PMID:27225047

  15. Assembling Bare Au Nanoparticles at Positively Charged Templates

    NASA Astrophysics Data System (ADS)

    Wang, Wenjie; Zhang, Honghu; Kuzmenko, Ivan; Mallapragada, Surya; Vaknin, David

    2016-05-01

    In-situ X-ray reflectivity (XRR) and grazing incidence X-ray small-angle scattering (GISAXS) reveal that unfunctionalized (bare) gold nanoparticles (AuNP) spontaneously adsorb to a cationic lipid template formed by a Langmuir monolayer of DPTAP (1,2-dihexadecanoyl-3-trimethylammonium-propane) at vapor/aqueous interfaces. Analysis of the XRR yields the electron density profile across the charged-interfaces along the surface normal showing the AuNPs assemble with vertical thickness comparable to the particle size. The GISAXS analysis indicates that the adsorbed mono-particle layer exhibits short-range in-plane correlations. By contrast, single-stranded DNA-functionalized AuNPs, while attracted to the positively charged surface (more efficiently with the addition of salt to the solution), display less in-plane regular packing compared to bare AuNPs.

  16. Ethylene binding to Au/Cu alloy nanoparticles

    NASA Astrophysics Data System (ADS)

    Gammage, Michael D.; Stauffer, Shannon; Henkelman, Graeme; Becker, Michael F.; Keto, John W.; Kovar, Desiderio

    2016-11-01

    Weak chemisorption of ethylene has been shown to be an important characteristic in the use of metals for the separation of ethylene from ethane. Previously, density functional theory (DFT) has been used to predict the binding energies of various metals and alloys, with Ag having the lowest chemisorption energy amongst the metals and alloys studied. Here Au/Cu alloys are investigated by a combination of DFT calculations and experimental measurements. It is inferred from experiments that the binding energy between a Au/Cu alloy and ethylene is lower than to either of the pure metals, and DFT calculations confirm that this is the case when Au segregates to the particle surface. Implications of this work suggest that it may be possible to further tune the binding energy with ethylene by compositional and morphological control of films produced from Au-surface segregated alloys.

  17. Assembling Bare Au Nanoparticles at Positively Charged Templates

    DOE PAGESBeta

    Wang, Wenjie; Zhang, Honghu; Kuzmenko, Ivan; Mallapragada, Surya; Vaknin, David

    2016-05-26

    In-situ X-ray reflectivity (XRR) and grazing incidence X-ray small-angle scattering (GISAXS) reveal that unfunctionalized (bare) gold nanoparticles (AuNP) spontaneously adsorb to a cationic lipid template formed by a Langmuir monolayer of DPTAP (1,2-dihexadecanoyl-3-trimethylammonium-propane) at vapor/aqueous interfaces. Analysis of the XRR yields the electron density profile across the charged-interfaces along the surface normal showing the AuNPs assemble with vertical thickness comparable to the particle size. The GISAXS analysis indicates that the adsorbed mono-particle layer exhibits short-range in-plane correlations. By contrast, single-stranded DNA-functionalized AuNPs, while attracted to the positively charged surface (more efficiently with the addition of salt to the solution), displaymore » less in-plane regular packing compared to bare AuNPs.« less

  18. Dynamic features of rod-shaped Au nanoclusters

    NASA Astrophysics Data System (ADS)

    So, Woong Young; Das, Anindita; Wang, Shuxin; Zhao, Shuo; Byun, Hee Young; Lee, Dana; Kumar, Santosh; Jin, Rongchao; Peteanu, Linda A.

    2015-08-01

    Gold nanoclusters hold many potential applications such as biosensing and optics due to their emission characteristics, small size, and non-toxicity. However, their low quantum yields remain problematic for further applications, and their fluorescence mechanism is still unclear. To increase the low quantum yields, various methods have been performed: doping, tuning structures, and changing number of gold atoms. In the past, most characterizations have been performed on spherical shaped nanoclusters; in this paper, several characterizations of various rod-shaped Au nanoclusters specifically on Au25 are shown. It has been determined that the central gold atom in Au25 nano-rod is crucial in fluorescence. Furthermore, single molecule analysis of silver doped Au25 nano-rod revealed that it has more photo-stability than conjugated polymers and quantum dots.

  19. Asbestos publications

    SciTech Connect

    Not Available

    1992-06-01

    NIOSH publications and testimony on the health effects of exposure to asbestos were included in this compilation as full text articles or abstracts. Additional NIOSH publications on asbestos were listed in a bibliography. The information in this report included occupational safety and health guidelines for asbestos from NIOSH; respiratory diseases (asbestosis, lung cancer, mesothelioma); work related lung disease surveillance report; and the NIOSH analytical methods for fibers, asbestos fibers, chrysotile asbestos, and bulk asbestos. Also contained in this report was NIOSH's testimony of January 24, 1991 on OSHA's proposed rule on occupational exposure to asbestos, tremolite, anthophyllite and actinolite; and NIOSH's statement of April 26, 1990 before the Subcommittee on Toxic Substances, Environmental Oversight, Research and Development, Committee on Environment and Public Works.

  20. Melting curve of metals Cu, Ag and Au under pressure

    NASA Astrophysics Data System (ADS)

    Tam, Pham Dinh; Hoc, Nguyen Quang; Tinh, Bui Duc; Tan, Pham Duy

    2016-01-01

    In this paper, the dependence of the melting temperature of metals Cu, Ag and Au under pressure in the interval from 0 kbar to 40 kbar is studied by the statistical moment method (SMM). This dependence has the form of near linearity and the calculated slopes of melting curve are 3.9 for Cu, 5.7 for Ag and 6 for Au. These results are in good agreement with the experimental data.

  1. Public Performance

    NASA Astrophysics Data System (ADS)

    Krupp, E. C.

    2013-01-01

    America’s first planetaria all opened in the 1930s, and each was the distinctive product of local circumstances. In Los Angeles, the populist sensibilities of Griffith J. Griffith prompted him to value the transformative power of a personal encounter with a telescope, and he quickly embraced the idea of a public observatory with free access to all. Griffith Observatory and its planetarium emerged from that intent. Authenticity, intelligibility, and theatricality were fundamental principles in Griffith’s thinking, and they were transformed into solid and enduring scientific and astronomical values by those who actually guided the Observatory’s design, construction, and programming. That said, the public profile of Griffith Observatory was most defined by its inspired hilltop location, its distinctive, commanding architecture, and its felicitous proximity to Hollywood. The Observatory is theatric in placement and in appearance, and before the Observatory even opened, it was used as a motion picture set. That continuing vocation turned Griffith Observatory into a Hollywood star. Because entertainment industry objectives and resources were part of the Los Angeles landscape, they influenced Observatory programming throughout the Observatory’s history. Public astronomy in Los Angeles has largely been framed by the Observatory’s fundamental nature. It has exhibits, but it is not a museum. It has a planetarium, but it is essentially an observatory. As a public observatory, it is filled with instruments that transform visitors into observers. This role emphasized the importance of personal experience and established the perception of Griffith Observatory as a place for public gathering and shared contact with the cosmos. The Observatory’s close and continuous link with amateur astronomers made amateurs influential partners in the public enterprise. In full accord with Griffith J. Griffith’s original intent, Griffith Observatory has all been about putting

  2. Formation, Migration, and Reactivity of Au-CO Complexes on Gold Surfaces.

    PubMed

    Wang, Jun; McEntee, Monica; Tang, Wenjie; Neurock, Matthew; Baddorf, Arthur P; Maksymovych, Petro; Yates, John T

    2016-02-10

    We report experimental as well as theoretical evidence that suggests Au-CO complex formation upon the exposure of CO to active sites (step edges and threading dislocations) on a Au(111) surface. Room-temperature scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy, transmission infrared spectroscopy, and density functional theory calculations point to Au-CO complex formation and migration. Room-temperature STM of the Au(111) surface at CO pressures in the range from 10(-8) to 10(-4) Torr (dosage up to 10(6) langmuir) indicates Au atom extraction from dislocation sites of the herringbone reconstruction, mobile Au-CO complex formation and diffusion, and Au adatom cluster formation on both elbows and step edges on the Au surface. The formation and mobility of the Au-CO complex result from the reduced Au-Au bonding at elbows and step edges leading to stronger Au-CO bonding and to the formation of a more positively charged CO (CO(δ+)) on Au. Our studies indicate that the mobile Au-CO complex is involved in the Au nanoparticle formation and reactivity, and that the positive charge on CO increases due to the stronger adsorption of CO at Au sites with lower coordination numbers. PMID:26754257

  3. On the stability of AuFe alloy nanoparticles.

    PubMed

    Velasco, V; Pohl, D; Surrey, A; Bonatto-Minella, A; Hernando, A; Crespo, P; Rellinghaus, B

    2014-05-30

    AuFe nanoparticles with mean diameters d p  = 13.2 nm have been prepared by inert-gas condensation. Conventional and high-resolution transmission electron microscopy and energy-dispersive x-ray spectroscopy investigations show that the particles are mostly icosahedra. Scanning transmission electron microscopy-energy-dispersive x-ray spectroscopy and scanning transmission electron microscopy-electron energy-loss spectroscopy show that the as-grown particles exhibit a core-shell structure. The shell is mainly composed of an amorphous FeO layer. Although Fe and Au are immiscible in the bulk, the particle cores are found to be homogeneously mixed at the atomic level with a local composition of around Au84Fe16 (at.%). AuFe nanoparticles exhibit a complex magnetic structure in which the core behaves as a spin glass with a freezing temperature of 35 K, whereas the amorphous FeO shell behaves as a ferro-ferrimagnetic system. On annealing above 300 °C, the AuFe icosahedra phases separate into their elemental constituents. Hence the as-grown AuFe icosahedra are metastable, thereby implying that the bulk phase diagram also applies for nanoscopic materials.

  4. Rotating Au nanorod and nanowire driven by circularly polarized light.

    PubMed

    Liaw, Jiunn-Woei; Chen, Ying-Syuan; Kuo, Mao-Kuen

    2014-10-20

    The wavelength-dependent optical torques provided by a circularly polarized (CP) plane wave driving Au nanorod (NR) and nanowire (NW) to rotate constantly were studied theoretically. Using the multiple multipole method, the resultant torque in terms of Maxwell's stress tensor was analyzed. Numerical results show that the optical torque spectrum is in accordance with the absorption spectrum of Au NR/NW. Under the same fluence, the maximum optical torque occurs at the longitudinal surface plasmon resonance (LSPR) of Au NR/NW, accompanied by a severe plasmonic heating. The rotation direction of the light-driven NR/NW depends on the handedness of CP light. In contrast, the optical torque exerted on Au NR/NW illuminated by a linearly polarized light is null at LSPR. Due to the plasmonic effect, the optical torque on Au NR/NW by CP light is two orders of magnitude larger than that on a dielectric NR/NW of the same size. The steady-state rotation of NR/NW in water, resulting from the balance of optical torque and viscous torque, was also discussed. Our finding shed some light on manipulating a CP light-driven Au NR/NW as a rotating nanomotor for a variety of applications in optofluidics and biophysics.

  5. Structural and dynamical properties of liquid Al-Au alloys

    NASA Astrophysics Data System (ADS)

    Peng, H. L.; Voigtmann, Th.; Kolland, G.; Kobatake, H.; Brillo, J.

    2015-11-01

    We investigate temperature- and composition-dependent structural and dynamical properties of Al-Au melts. Experiments are performed to obtain accurate density and viscosity data. The system shows a strong negative excess volume, similar to other Al-based binary alloys. We develop a molecular-dynamics (MD) model of the melt based on the embedded-atom method (EAM), gauged against the available experimental liquid-state data. A rescaling of previous EAM potentials for solid-state Au and Al improves the quantitative agreement with experimental data in the melt. In the MD simulation, the admixture of Au to Al can be interpreted as causing a local compression of the less dense Al system, driven by less soft Au-Au interactions. This local compression provides a microscopic mechanism explaining the strong negative excess volume of the melt. We further discuss the concentration dependence of self- and interdiffusion and viscosity in the MD model. Al atoms are more mobile than Au, and their increased mobility is linked to a lower viscosity of the melt.

  6. Electric fields and chiral magnetic effect in Cu + Au collisions

    NASA Astrophysics Data System (ADS)

    Deng, Wei-Tian; Huang, Xu-Guang

    2015-03-01

    The non-central Cu + Au collisions can create strong out-of-plane magnetic fields and in-plane electric fields. By using the HIJING model, we study the general properties of the electromagnetic fields in Cu + Au collisions at 200 GeV and their impacts on the charge-dependent two-particle correlator γq1q2 = < cos ⁡ (ϕ1 +ϕ2 - 2ψRP) > (see main text for definition) which was used for the detection of the chiral magnetic effect (CME). Compared with Au + Au collisions, we find that the in-plane electric fields in Cu + Au collisions can strongly suppress the two-particle correlator or even reverse its sign if the lifetime of the electric fields is long. Combining with the expectation that if γq1q2 is induced by elliptic-flow driven effects we would not see such strong suppression or reversion, our results suggest to use Cu + Au collisions to test CME and understand the mechanisms that underlie γq1q2.

  7. Spin Polarization and Quantum Spins in Au Nanoparticles

    PubMed Central

    Li, Chi-Yen; Karna, Sunil K.; Wang, Chin-Wei; Li, Wen-Hsien

    2013-01-01

    The present study focuses on investigating the magnetic properties and the critical particle size for developing sizable spontaneous magnetic moment of bare Au nanoparticles. Seven sets of bare Au nanoparticle assemblies, with diameters from 3.5 to 17.5 nm, were fabricated with the gas condensation method. Line profiles of the X-ray diffraction peaks were used to determine the mean particle diameters and size distributions of the nanoparticle assemblies. The magnetization curves M(Ha) reveal Langevin field profiles. Magnetic hysteresis was clearly revealed in the low field regime even at 300 K. Contributions to the magnetization from different size particles in the nanoparticle assemblies were considered when analyzing the M(Ha) curves. The results show that the maximum particle moment will appear in 2.4 nm Au particles. A similar result of the maximum saturation magnetization appearing in 2.3 nm Au particles is also concluded through analysis of the dependency of the saturation magnetization MP on particle size. The MP(d) curve departs significantly from the 1/d dependence, but can be described by a log-normal function. Magnetization can be barely detected for Au particles larger than 27 nm. Magnetic field induced Zeeman magnetization from the quantum confined Kubo gap opening appears in Au nanoparticles smaller than 9.5 nm in diameter. PMID:23989607

  8. Synthesis of hybrid CdS-Au colloidal nanostructures.

    PubMed

    Saunders, Aaron E; Popov, Inna; Banin, Uri

    2006-12-21

    We explore the growth mechanism of gold nanocrystals onto preformed cadmium sulfide nanorods to form hybrid metal nanocrystal/semiconductor nanorod colloids. By manipulating the growth conditions, it is possible to obtain nanostructures exhibiting Au nanocrystal growth at only one nanorod tip, at both tips, or at multiple locations along the nanorod surface. Under anaerobic conditions, Au growth occurs only at one tip of the nanorods, producing asymmetric structures. In contrast, the presence of oxygen and trace amounts of water during the reaction promotes etching of the nanorod surface, providing additional sites for metal deposition. Three growth stages are observed when Au growth is performed under air: (1) Au nanocrystal formation at both nanorod tips, (2) growth onto defect sites on the nanorod surface, and finally (3) a ripening process in which one nanocrystal tip grows at the expense of the other particles present on the nanorod. Analysis of the hybrid nanostructures by high-resolution TEM shows that there is no preferred orientation between the Au nanocrystal and the CdS nanorod, indicating that growth is nonepitaxial. The optical signatures of the nanocrystals and the nanorods (i.e., the surface plasmon and first exciton transition peaks, respectively) are spectrally distinct, allowing the different stages of the growth process to be easily monitored. The initial CdS nanorods exhibit band gap and trap state emission, both of which are quenched during Au growth. PMID:17165989

  9. Surface segregation phenomena in extended and nanoparticle surfaces of Cu-Au alloys

    NASA Astrophysics Data System (ADS)

    Li, Jonathan; Wang, Guofeng; Zhou, Guangwen

    2016-07-01

    Using density functional theory (DFT) and Monte Carlo (MC) simulations, we studied the surface segregation phenomena of Au atoms in the extended and nanoparticle surfaces of Cu-Au alloys. Our MC simulations predicted significant Au enrichment in the outermost layer of (111) and (100) extended surfaces, and Au enrichment in the two outermost layers of (110) extended surfaces. The equilibrium Cu-Au nanoparticles were predicted to develop into an Au-enriched shell structure, where Au atoms preferably segregate to the (100) facets while Cu atoms are mainly located on the (111) facet of the nanoparticles. Our simulation predictions agree with experimental measurements.

  10. QUELS FUTURS TRAITEMENTS POUR LA DEPENDANCE AU TABAC ET AU CANNABIS?

    PubMed Central

    LE FOLL, Bernard; JUSTINOVA, Zuzana; TANDA, Gianlugi; GOLDBERG, Steven R.

    2009-01-01

    RESUME Plus de trois millions de morts sont attribués au tabagisme dans le monde par an, et l’usage de tabac est en progression dans les pays en voie de développement. L’usage de tabac est donc une des rares causes de mortalité qui augmente, avec une prévision de plus de 10 millions de morts par an dans 30–40 ans. Le cannabis ou marijuana est la drogue illicite la plus consommée dans le monde et il n’y a actuellement pas de traitement disponible. Bien que les systèmes dopaminergiques jouent un rôle central dans les effets renforçants des drogues, d’autres systèmes sont impliqués. Nous présentons ici des résultats récents obtenus avec des antagonistes des récepteurs cannabinoides CB1, des récepteurs D3 de la dopamine et des récepteurs opioïdes. Ces antagonistes qui modulent de façon directe ou indirecte la transmission dopaminergique cérébrale représentent des approches prometteuses pour le traitement du tabagisme ou de la dépendance au cannabis. Ces approches sont à valider dans des essais cliniques. PMID:18663981

  11. Beam Energy Dependence of the Third Harmonic of Azimuthal Correlations in Au +Au Collisions at RHIC

    NASA Astrophysics Data System (ADS)

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Aparin, A.; Arkhipkin, D.; Aschenauer, E. C.; Attri, A.; Averichev, G. S.; Bai, X.; Bairathi, V.; Bellwied, R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Bouchet, J.; Brandenburg, J. D.; Brandin, A. V.; Bunzarov, I.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Campbell, J. M.; Cebra, D.; Chakaberia, I.; Chaloupka, P.; Chang, Z.; Chatterjee, A.; Chattopadhyay, S.; Chen, J. H.; Chen, X.; Cheng, J.; Cherney, M.; Christie, W.; Contin, G.; Crawford, H. J.; Das, S.; De Silva, L. C.; Debbe, R. R.; Dedovich, T. G.; Deng, J.; Derevschikov, A. A.; di Ruzza, B.; Didenko, L.; Dilks, C.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Du, C. M.; Dunkelberger, L. E.; Dunlop, J. C.; Efimov, L. G.; Engelage, J.; Eppley, G.; Esha, R.; Evdokimov, O.; Eyser, O.; Fatemi, R.; Fazio, S.; Federic, P.; Fedorisin, J.; Feng, Z.; Filip, P.; Fisyak, Y.; Flores, C. E.; Fulek, L.; Gagliardi, C. A.; Garand, D.; Geurts, F.; Gibson, A.; Girard, M.; Greiner, L.; Grosnick, D.; Gunarathne, D. S.; Guo, Y.; Gupta, S.; Gupta, A.; Guryn, W.; Hamad, A. I.; Hamed, A.; Haque, R.; Harris, J. W.; He, L.; Heppelmann, S.; Heppelmann, S.; Hirsch, A.; Hoffmann, G. W.; Horvat, S.; Huang, T.; Huang, X.; Huang, B.; Huang, H. Z.; Huck, P.; Humanic, T. J.; Igo, G.; Jacobs, W. W.; Jang, H.; Jentsch, A.; Jia, J.; Jiang, K.; Judd, E. G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Khan, Z. H.; Kikoła, D. P.; Kisel, I.; Kisiel, A.; Kochenda, L.; Koetke, D. D.; Kosarzewski, L. K.; Kraishan, A. F.; Kravtsov, P.; Krueger, K.; Kumar, L.; Lamont, M. A. C.; Landgraf, J. M.; Landry, K. D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; Li, X.; Li, C.; Li, X.; Li, Y.; Li, W.; Lin, T.; Lisa, M. A.; Liu, F.; Ljubicic, T.; Llope, W. J.; Lomnitz, M.; Longacre, R. S.; Luo, X.; Ma, R.; Ma, G. L.; Ma, Y. G.; Ma, L.; Magdy, N.; Majka, R.; Manion, A.; Margetis, S.; Markert, C.; Matis, H. S.; McDonald, D.; McKinzie, S.; Meehan, K.; Mei, J. C.; Minaev, N. G.; Mioduszewski, S.; Mishra, D.; Mohanty, B.; Mondal, M. M.; Morozov, D. A.; Mustafa, M. K.; Nandi, B. K.; Nasim, Md.; Nayak, T. K.; Nigmatkulov, G.; Niida, T.; Nogach, L. V.; Noh, S. Y.; Novak, J.; Nurushev, S. B.; Odyniec, G.; Ogawa, A.; Oh, K.; Okorokov, V. A.; Olvitt, D.; Page, B. S.; Pak, R.; Pan, Y. X.; Pandit, Y.; Panebratsev, Y.; Pawlik, B.; Pei, H.; Perkins, C.; Pile, P.; Pluta, J.; Poniatowska, K.; Porter, J.; Posik, M.; Poskanzer, A. M.; Pruthi, N. K.; Putschke, J.; Qiu, H.; Quintero, A.; Ramachandran, S.; Raniwala, S.; Raniwala, R.; Ray, R. L.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Ruan, L.; Rusnak, J.; Rusnakova, O.; Sahoo, N. R.; Sahu, P. K.; Sakrejda, I.; Salur, S.; Sandweiss, J.; Sarkar, A.; Schambach, J.; Scharenberg, R. P.; Schmah, A. M.; Schmidke, W. B.; Schmitz, N.; Seger, J.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P. V.; Shao, M.; Sharma, A.; Sharma, B.; Sharma, M. K.; Shen, W. Q.; Shi, Z.; Shi, S. S.; Shou, Q. Y.; Sichtermann, E. P.; Sikora, R.; Simko, M.; Singha, S.; Skoby, M. J.; Smirnov, N.; Smirnov, D.; Solyst, W.; Song, L.; Sorensen, P.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Stepanov, M.; Stock, R.; Strikhanov, M.; Stringfellow, B.; Sumbera, M.; Summa, B.; Sun, Z.; Sun, X. M.; Sun, Y.; Surrow, B.; Svirida, D. N.; Tang, Z.; Tang, A. H.; Tarnowsky, T.; Tawfik, A.; Thäder, J.; Thomas, J. H.; Timmins, A. R.; Tlusty, D.; Todoroki, T.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Tripathy, S. K.; Tsai, O. D.; Ullrich, T.; Underwood, D. G.; Upsal, I.; Van Buren, G.; van Nieuwenhuizen, G.; Vandenbroucke, M.; Varma, R.; Vasiliev, A. N.; Vertesi, R.; Videbæk, F.; Vokal, S.; Voloshin, S. A.; Vossen, A.; Wang, F.; Wang, G.; Wang, J. S.; Wang, H.; Wang, Y.; Wang, Y.; Webb, G.; Webb, J. C.; Wen, L.; Westfall, G. D.; Wieman, H.; Wissink, S. W.; Witt, R.; Wu, Y.; Xiao, Z. G.; Xie, W.; Xie, G.; Xin, K.; Xu, Y. F.; Xu, Q. H.; Xu, N.; Xu, H.; Xu, Z.; Xu, J.; Yang, S.; Yang, Y.; Yang, Y.; Yang, C.; Yang, Y.; Yang, Q.; Ye, Z.; Ye, Z.; Yepes, P.; Yi, L.; Yip, K.; Yoo, I.-K.; Yu, N.; Zbroszczyk, H.; Zha, W.; Zhang, X. P.; Zhang, Y.; Zhang, J.; Zhang, J.; Zhang, S.; Zhang, S.; Zhang, Z.; Zhang, J. B.; Zhao, J.; Zhong, C.; Zhou, L.; Zhu, X.; Zoulkarneeva, Y.; Zyzak, M.; STAR Collaboration

    2016-03-01

    We present results from a harmonic decomposition of two-particle azimuthal correlations measured with the STAR detector in Au +Au collisions for energies ranging from √{sN N }=7.7 to 200 GeV. The third harmonic v32{2 }=⟨cos 3 (ϕ1-ϕ2)⟩ , where ϕ1-ϕ2 is the angular difference in azimuth, is studied as a function of the pseudorapidity difference between particle pairs Δ η =η1-η2 . Nonzero v32{2 } is directly related to the previously observed large-Δ η narrow-Δ ϕ ridge correlations and has been shown in models to be sensitive to the existence of a low viscosity quark gluon plasma phase. For sufficiently central collisions, v32{2 } persist down to an energy of 7.7 GeV, suggesting that quark gluon plasma may be created even in these low energy collisions. In peripheral collisions at these low energies, however, v32{2 } is consistent with zero. When scaled by the pseudorapidity density of charged-particle multiplicity per participating nucleon pair, v32{2 } for central collisions shows a minimum near √{sN N }=20 GeV .

  12. Azimuthal anisotophy in U + U and Au + Au collisions at RHIC

    SciTech Connect

    Adamczyk, L.

    2015-11-24

    Collisions between prolate uranium nuclei are used to study how particle production and azimuthal anisotropies depend on initial geometry in heavy-ion collisions. We report the two- and four-particle cumulants, v2{2} and v2{4}, for charged hadrons from U+U collisions at √SNN = 193 GeV and Au+Au collisions at √SNN = 200 GeV. Nearly fully overlapping collisions are selected based on the energy deposited by spectators in zero degree calorimeters (ZDCs). Within this sample, the observed dependence of v2{2} on multiplicity demonstrates that ZDC information combined with multiplicity can preferentially select different overlap configurations in U+U collisions. As a result, we also show that v2 vs multiplicity can be better described by models, such as gluon saturation or quark participant models, that eliminate the dependence of the multiplicity on the number of binary nucleon-nucleon collisions.

  13. Azimuthal anisotophy in U + U and Au + Au collisions at RHIC

    DOE PAGESBeta

    Adamczyk, L.

    2015-11-24

    Collisions between prolate uranium nuclei are used to study how particle production and azimuthal anisotropies depend on initial geometry in heavy-ion collisions. We report the two- and four-particle cumulants, v2{2} and v2{4}, for charged hadrons from U+U collisions at √SNN = 193 GeV and Au+Au collisions at √SNN = 200 GeV. Nearly fully overlapping collisions are selected based on the energy deposited by spectators in zero degree calorimeters (ZDCs). Within this sample, the observed dependence of v2{2} on multiplicity demonstrates that ZDC information combined with multiplicity can preferentially select different overlap configurations in U+U collisions. As a result, we alsomore » show that v2 vs multiplicity can be better described by models, such as gluon saturation or quark participant models, that eliminate the dependence of the multiplicity on the number of binary nucleon-nucleon collisions.« less

  14. Dielectron Mass Spectra from Au +Au Collisions at √sNN =200 GeV

    NASA Astrophysics Data System (ADS)

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Alford, J.; Anson, C. D.; Aparin, A.; Arkhipkin, D.; Aschenauer, E. C.; Averichev, G. S.; Banerjee, A.; Barnovska, Z.; Beavis, D. R.; Bellwied, R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bichsel, H.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Borowski, W.; Bouchet, J.; Brandin, A. V.; Brovko, S. G.; Bültmann, S.; Bunzarov, I.; Burton, T. P.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Cebra, D.; Cendejas, R.; Cervantes, M. C.; Chaloupka, P.; Chang, Z.; Chattopadhyay, S.; Chen, H. F.; Chen, J. H.; Chen, L.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Chwastowski, J.; Codrington, M. J. M.; Cramer, J. G.; Crawford, H. J.; Cui, X.; Das, S.; Davila Leyva, A.; De Silva, L. C.; Debbe, R. R.; Dedovich, T. G.; Deng, J.; Derevschikov, A. A.; Derradi de Souza, R.; Dhamija, S.; di Ruzza, B.; Didenko, L.; Dilks, C.; Ding, F.; Djawotho, P.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Du, C. M.; Dunkelberger, L. E.; Dunlop, J. C.; Efimov, L. G.; Engelage, J.; Engle, K. S.; Eppley, G.; Eun, L.; Evdokimov, O.; Fatemi, R.; Fazio, S.; Fedorisin, J.; Filip, P.; Finch, E.; Fisyak, Y.; Flores, C. E.; Gagliardi, C. A.; Gangadharan, D. R.; Garand, D.; Geurts, F.; Gibson, A.; Girard, M.; Gliske, S.; Grosnick, D.; Guo, Y.; Gupta, A.; Gupta, S.; Guryn, W.; Haag, B.; Hajkova, O.; Hamed, A.; Han, L.-X.; Haque, R.; Harris, J. W.; Heppelmann, S.; Hirsch, A.; Hoffmann, G. W.; Hofman, D. J.; Horvat, S.; Huang, B.; Huang, H. Z.; Huang, X.; Huck, P.; Humanic, T. J.; Igo, G.; Jacobs, W. W.; Jang, H.; Judd, E. G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Kesich, A.; Khan, Z. H.; Kikola, D. P.; Kisel, I.; Kisiel, A.; Koetke, D. D.; Kollegger, T.; Konzer, J.; Koralt, I.; Korsch, W.; Kotchenda, L.; Kravtsov, P.; Krueger, K.; Kulakov, I.; Kumar, L.; Kycia, R. A.; Lamont, M. A. C.; Landgraf, J. M.; Landry, K. D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; LeVine, M. J.; Li, C.; Li, W.; Li, X.; Li, X.; Li, Y.; Li, Z. M.; Lima, L. M.; Lisa, M. A.; Liu, F.; Ljubicic, T.; Llope, W. J.; Longacre, R. S.; Luo, X.; Ma, G. L.; Ma, Y. G.; Madagodagettige Don, D. M. M. D.; Mahapatra, D. P.; Majka, R.; Margetis, S.; Markert, C.; Masui, H.; Matis, H. S.; McDonald, D.; McShane, T. S.; Minaev, N. G.; Mioduszewski, S.; Mohanty, B.; Mondal, M. M.; Morozov, D. A.; Munhoz, M. G.; Mustafa, M. K.; Nandi, B. K.; Nasim, Md.; Nayak, T. K.; Nelson, J. M.; Nogach, L. V.; Noh, S. Y.; Novak, J.; Nurushev, S. B.; Odyniec, G.; Ogawa, A.; Oh, K.; Ohlson, A.; Okorokov, V.; Oldag, E. W.; Oliveira, R. A. N.; Pachr, M.; Page, B. S.; Pal, S. K.; Pan, Y. X.; Pandit, Y.; Panebratsev, Y.; Pawlak, T.; Pawlik, B.; Pei, H.; Perkins, C.; Peryt, W.; Pile, P.; Planinic, M.; Pluta, J.; Plyku, D.; Poljak, N.; Porter, J.; Poskanzer, A. M.; Pruthi, N. K.; Przybycien, M.; Pujahari, P. R.; Qiu, H.; Quintero, A.; Ramachandran, S.; Raniwala, R.; Raniwala, S.; Ray, R. L.; Riley, C. K.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Ross, J. F.; Roy, A.; Ruan, L.; Rusnak, J.; Sahoo, N. R.; Sahu, P. K.; Sakrejda, I.; Salur, S.; Sandacz, A.; Sandweiss, J.; Sangaline, E.; Sarkar, A.; Schambach, J.; Scharenberg, R. P.; Schmah, A. M.; Schmidke, W. B.; Schmitz, N.; Seger, J.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P. V.; Shao, M.; Sharma, B.; Shen, W. Q.; Shi, S. S.; Shou, Q. Y.; Sichtermann, E. P.; Singaraju, R. N.; Skoby, M. J.; Smirnov, D.; Smirnov, N.; Solanki, D.; Sorensen, P.; deSouza, U. G.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Stevens, J. R.; Stock, R.; Strikhanov, M.; Stringfellow, B.; Suaide, A. A. P.; Sumbera, M.; Sun, X.; Sun, X. M.; Sun, Y.; Sun, Z.; Surrow, B.; Svirida, D. N.; Symons, T. J. M.; Szanto de Toledo, A.; Takahashi, J.; Tang, A. H.; Tang, Z.; Tarnowsky, T.; Thomas, J. H.; Timmins, A. R.; Tlusty, D.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Trzeciak, B. A.; Tsai, O. D.; Turnau, J.; Ullrich, T.; Underwood, D. G.; Van Buren, G.; van Nieuwenhuizen, G.; Vanfossen, J. A.; Varma, R.; Vasconcelos, G. M. S.; Vasiliev, A. N.; Vertesi, R.; Videbæk, F.; Viyogi, Y. P.; Vokal, S.; Vossen, A.; Wada, M.; Wang, F.; Wang, G.; Wang, H.; Wang, J. S.; Wang, X. L.; Wang, Y.; Wang, Y.; Webb, G.; Webb, J. C.; Westfall, G. D.; Wieman, H.; Wissink, S. W.; Witt, R.; Wu, Y. F.; Xiao, Z.; Xie, W.; Xin, K.; Xu, H.; Xu, N.; Xu, Q. H.; Xu, Y.; Xu, Z.; Yan, W.; Yang, C.; Yang, Y.; Yang, Y.; Ye, Z.; Yepes, P.; Yi, L.; Yip, K.; Yoo, I.-K.; Zawisza, Y.; Zbroszczyk, H.; Zha, W.; Zhang, J. B.; Zhang, J. L.; Zhang, S.; Zhang, X. P.; Zhang, Y.; Zhang, Z. P.; Zhao, F.; Zhao, J.; Zhong, C.; Zhu, X.; Zhu, Y. H.; Zoulkarneeva, Y.; Zyzak, M.; STAR Collaboration

    2014-07-01

    We report the STAR measurements of dielectron (e+e-) production at midrapidity (|yee|<1) in Au +Au collisions at √sNN =200 GeV. The measurements are evaluated in different invariant mass regions with a focus on 0.30-0.76 (ρ-like), 0.76-0.80 (ω-like), and 0.98-1.05 (ϕ-like) GeV /c2. The spectrum in the ω-like and ϕ-like regions can be well described by the hadronic cocktail simulation. In the ρ-like region, however, the vacuum ρ spectral function cannot describe the shape of the dielectron excess. In this range, an enhancement of 1.77±0.11(stat)±0.24(syst)±0.33(cocktail) is determined with respect to the hadronic cocktail simulation that excludes the ρ meson. The excess yield in the ρ-like region increases with the number of collision participants faster than the ω and ϕ yields. Theoretical models with broadened ρ contributions through interactions with constituents in the hot QCD medium provide a consistent description of the dilepton mass spectra for the measurement presented here and the earlier data at the Super Proton Synchrotron energies.

  15. RHIC PERFORMANCE DURING THE FY10 200 GeV Au+Au HEAVY ION RUN

    SciTech Connect

    Brown, K.A.; Ahrens, L.; Bai, M.; Beebe-Wang, J.; Blaskiewicz, M.; Brennan, J.; Bruno, D.; Carlson, C.; Connolly, R.; de Maria, R.; D’Ottavio, T.; Drees, A.; Fischer, W.; Fu, W.; Gardner, C.; Gassner, D.; Glenn, J.W.; Hao, Y.; Harvey, M.; Hayes, T.; Hoff, L.; Huang, H.; Laster, J.; Lee, R.; Litvinenko, V.; Luo, Y.; MacKay, W.; Marr, G.; Marusic, A.; Mernick, K.; Michnoff, R.; Minty, M.; Montag, C.; Morris, J.; Nemesure, S.; Oerter, B.; Pilat, F.; Ptitsyn, V.; Robert-Demolaize, G.; Roser, T.; Russo, T.; Sampson, P.; Sandberg, J.; Satogata, T.; Severino, F.; Schoefer, V.; Schultheiss, C.; Smith, K.; Steski, D.; Tepikian, S.; Theisen, C.; Thieberger, P.; Trbojevic, D.; Tsoupas, N.; Tuozzolo, J.; Wang, G.; Wilinski, M.; Zaltsman, A.; Zeno, K.; Zhang, S.Y.

    2010-05-23

    Since the last successful RHIC Au+Au run in 2007 (Run-7), the RHIC experiments have made numerous detector improvements and upgrades. In order to benefit from the enhanced detector capabilities and to increase the yield of rare events in the acquired heavy ion data a significant increase in luminosity is essential. In Run-7 RHIC achieved an average store luminosity of = 12 x 10{sup 26} cm{sup -2} s{sup -1} by operating with 103 bunches (out of 111 possible), and by squeezing to {beta}* = 0.85 m. This year, Run-10, we achieved = 20 x 10{sup 26} cm{sup -2} s{sup -1}, which put us an order of magnitude above the RHIC design luminosity. To reach these luminosity levels we decreased {beta}* to 0.75 m, operated with 111 bunches per ring, and reduced longitudinal and transverse emittances by means of bunched-beam stochastic cooling. In addition we introduced a lattice to suppress intra-beam scattering (IBS) in both RHIC rings, upgraded the RF control system, and separated transition crossing times in the two rings. We present an overview of the changes and the results of Run-10 performance.

  16. A first look at Au+Au collisions at RHIC energies using the PHOBOS detector.

    SciTech Connect

    Back, B. B.; George, N.; Wousmaa, A. H.; Baker, M. D.; Barton, D. S.; PHOBOS Collaboration; Physics

    2003-05-01

    The PHOBOS detector has been used to study Au + Au collisions at {radical}sNN = 56,130, and 200 GeV Several global observables have been measured and the results are compared with theoretical models. These observables include the charged-particle multiplicity measured as a function of beam energy, pseudo-rapidity, and centrality of the collision. A unique feature of the PHOBOS detector is its almost complete angular coverage such that these quantities can be studied over a pseudo-rapidity interval of |{eta}|{<=}5.4. This allows for an almost complete integration of the total charged particle yield, which is found to be about N{sub ch}{sup tot} = 4200 {+-}470 at {radical}sNN = 130 GeV and N{sub ch}{sup tot} = 5300 {+-}530 at {radical}sNN = 200 GeV. The ratio of anti-particles to particles emitted in the mid-rapidity region has also been measured using the PHOBOS magnetic spectrometer. Of particular interest is the ratio of anti-protons to protons in the mid-rapidity region, which was found to be (i.e.921-1) at {radical}sNN = 130 GeV. This high value suggests that an almost baryon-free region has been produced in the collisions.

  17. Rapidity dependency of (Anti)-deuteron Coalescence in Au-Au collisions

    NASA Astrophysics Data System (ADS)

    Murray, Michael

    2009-05-01

    The coalescence of protons and neutrons into deuterons is sensitive to the space-time extent of the baryon freeze-out region. The coalescence parameter and the phase space density recast the information contained in the proton and deuteron spectra into ``chemical" and ``dynamic" terms. The phase space density is sensitive to the chemical potential and the temperature of the system. The coalescence parameter B2 can be interpreted in terms of a ``volume of homogeniety" which depends upon the temperature of the system and the radial flow. The large rapidity and pT coverage with good particle identification of the BRAHMS spectrometers allow us to measure the rapidity dependence of the volume, which is proportional to 1/B2, and the phase space density of the (anti)-proton source for central Au+Au collisions. We find that B2(pT) is almost independent of rapidity and beam energy. Interpreting 1/B2 as a volume gives numbers that are very close to HBT data and a size which steadily drops with pT. We find that B2(pT) is the same for protons and antiprotons. The phase space density has a weak rapidity dependence but varies rapidily with energy. These results in conjunction with other forward rapidity data start to give us a picture of the longitudinal evolution of the source at RHIC energies. Supported by NSF CAREER award 0449913

  18. Au Contraire: Gifted in a Flash (Mob)

    ERIC Educational Resources Information Center

    Delisle, James R.

    2012-01-01

    A "flash mob" is defined by Wikipedia as "a large group of people who assemble suddenly in a public place, perform an unusual and pointless act for a brief time, then disperse." Fueled by social media and Smartphones, flash mobs have been used, primarily, as entertaining diversions by addicted techies with (apparently) tons of time on their hands.…

  19. Scaling properties of proton and antiproton production in sqrt[s(NN)]=200 GeV Au+Au collisions.

    PubMed

    Adler, S S; Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Alexander, J; Amirikas, R; Aphecetche, L; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, R; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bazilevsky, A; Belikov, S; Berdnikov, Y; Bhagavatula, S; Boissevain, J G; Borel, H; Borenstein, S; Brooks, M L; Brown, D S; Bruner, N; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Camard, X; Chai, J-S; Chand, P; Chang, W C; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Choi, J; Choudhury, R K; Chujo, T; Cianciolo, V; Cobigo, Y; Cole, B A; Constantin, P; d'Enterria, D G; David, G; Delagrange, H; Denisov, A; Deshpande, A; Desmond, E J; Dietzsch, O; Drapier, O; Drees, A; du Rietz, R; Durum, A; Dutta, D; Efremenko, Y V; El Chenawi, K; Enokizono, A; En'yo, H; Esumi, S; Ewell, L; Fields, D E; Fleuret, F; Fokin, S L; Fox, B D; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fung, S-Y; Garpman, S; Ghosh, T K; Glenn, A; Gogiberidze, G; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Grosse Perdekamp, G; Guryn, W; Gustafsson, H-A; Hachiya, T; Haggerty, J S; Hamagaki, H; Hansen, A G; Hartouni, E P; Harvey, M; Hayano, R; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hibino, M; Hill, J C; Holzmann, W; Homma, K; Hong, B; Hoover, A; Ichihara, T; Ikonnikov, V V; Imai, K; Isenhower, L D; Ishihara, M; Issah, M; Isupov, A; Jacak, B V; Jang, W Y; Jeong, Y; Jia, J; Jinnouchi, O; Johnson, B M; Johnson, S C; Joo, K S; Jouan, D; Kametani, S; Kamihara, N; Kang, J H; Kapoor, S S; Katou, K; Kelly, S; Khachaturov, B; Khanzadeev, A; Kikuchi, J; Kim, D H; Kim, D J; Kim, D W; Kim, E; Kim, G-B; Kim, H J; Kistenev, E; Kiyomichi, A; Kiyoyama, K; Klein-Boesing, C; Kobayashi, H; Kochenda, L; Kochetkov, V; Koehler, D; Kohama, T; Kopytine, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kuberg, C H; Kurita, K; Kuroki, Y; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Ladygin, V; Lajoie, J G; Lebedev, A; Leckey, S; Lee, D M; Lee, S; Leitch, M J; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Liu, Y; Maguire, C F; Makdisi, Y I; Malakhov, A; Manko, V I; Mao, Y; Martinez, G; Marx, M D; Masui, H; Matathias, F; Matsumoto, T; McGaughey, P L; Melnikov, E; Messer, F; Miake, Y; Milan, J; Miller, T E; Milov, A; Mioduszewski, S; Mischke, R E; Mishra, G C; Mitchell, J T; Mohanty, A K; Morrison, D P; Moss, J M; Mühlbacher, F; Mukhopadhyay, D; Muniruzzaman, M; Murata, J; Nagamiya, S; Nagle, J L; Nakamura, T; Nandi, B K; Nara, M; Newby, J; Nilsson, P; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Ono, M; Onuchin, V; Oskarsson, A; Otterlund, I; Oyama, K; Ozawa, K; Pal, D; Palounek, A P T; Pantuev, V S; Papavassiliou, V; Park, J; Parmar, A; Pate, S F; Peitzmann, T; Peng, J-C; Peresedov, V; Pinkenburg, C; Pisani, R P; Plasil, F; Purschke, M L; Purwar, A; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosnet, P; Ryu, S S; Sadler, M E; Saito, N; Sakaguchi, T; Sakai, M; Sakai, S; Samsonov, V; Sanfratello, L; Santo, R; Sato, H D; Sato, S; Sawada, S; Schutz, Y; Semenov, V; Seto, R; Shaw, M R; Shea, T K; Shibata, T-A; Shigaki, K; Shiina, T; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Sivertz, M; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Sullivan, J P; Takagui, E M; Taketani, A; Tamai, M; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Tarján, P; Tepe, J D; Thomas, T L; Tojo, J; Torii, H; Towell, R S; Tserruya, I; Tsuruoka, H; Tuli, S K; Tydesjö, H; Tyurin, N; Van Hecke, H W; Velkovska, J; Velkovsky, M; Villatte, L; Vinogradov, A A; Volkov, M A; Vznuzdaev, E; Wang, X R; Watanabe, Y; White, S N; Wohn, F K; Woody, C L; Xie, W; Yang, Y; Yanovich, A; Yokkaichi, S; Young, G R; Yushmanov, I E; Zajc, W A; Zhang, C; Zhou, S; Zolin, L

    2003-10-24

    We report on the yield of protons and antiprotons, as a function of centrality and transverse momentum, in Au+Au collisions at sqrt[s(NN)]=200 GeV measured at midrapidity by the PHENIX experiment at the BNL Relativistic Heavy Ion Collider. In central collisions at intermediate transverse momenta (1.5Au+Au, p+p, and e(+)e(-) collisions. This enhancement is limited to p(T)<5 GeV/c as deduced from the ratio of charged hadrons to pi(0) measured in the range 1.5

  20. Transition from participant to spectator fragmentation in Au+Au reactions between 60A and 150A MeV

    SciTech Connect

    Zbiri, K.; Aichelin, J.; Le Fevre, A.; Lukasik, J.; Reisdorf, W.; Lynen, U.; Mueller, W. F. J.; Orth, H.; Schwarz, C.; Sfienti, C.; Trautmann, W.; Turzo, K.; Gulminelli, F.; Lopez, O.; Vient, E.; Zwieglinski, B.; Chbihi, A.; Frankland, J. D.; Wieleczko, J. P.; Charvet, J. L.

    2007-03-15

    Using the quantum molecular dynamics approach, we analyzed the results of the recent INDRA Collaboration Au+Au experiments at GSI in the energy range between 60A and 150A MeV. It turns out that in this energy region, the transition toward a participant-spectator scenario takes place. The large Au+Au system displays, in the simulations as in the experiment, simultaneously dynamical and statistical behavior, which we analyze in detail. The composition of fragments close to midrapidity follows statistical laws, and the system shows bimodality, i.e., a sudden transition between different fragmentation patterns, as a function of centrality, as expected for a phase transition. The fragment spectra at small and large rapidities, on the other hand, are determined by dynamics, and the system as a whole does not come to equilibrium--an observation that is confirmed by FOPI Collaboration experiments for the same system.

  1. Centrality and collision system dependence of antiproton production from p+A to Au+Au collisions at AGS energies

    NASA Technical Reports Server (NTRS)

    Sako, H.; Ahle, L.; Akiba, Y.; Ashktorab, K.; Baker, M. D.; Beavis, D.; Britt, H. C.; Chang, J.; Chasman, C.; Chen, Z.; Chu, Y. Y.; Cianciolo, V.; Cole, B. A.; Crawford, H. J.; Cumming, J. B.; Debbe, R.; Dunlop, J. C.; Eldredge, W.; Engelage, J.; Fung, S.-Y.

    1997-01-01

    Antiproton production in heavy ion collisions reflects subtle interplay between initial production and absorption by nucleons. Because the AGS energies (10--20 A(center-dot)GeV/c) are close to the antiproton production threshold, antiproton may be sensitive to cooperative processes such as QGP and hadronic multi-step processes. On the other hand, antiproton has been proposed as a probe of baryon density due to large N(anti N) annihilation cross sections. Cascade models predict the maximum baryon density reaches about 10 times the normal nucleus density in central Au+Au collisions, where the strong antiproton absorption is expected. In this paper, the authors show systematic studies of antiproton production from p+A to Au+Au collisions.

  2. Strangeness enhancement in Cu-Cu and Au-Au collisions at √S(NN)=200 GeV.

    PubMed

    Agakishiev, G; Aggarwal, M M; Ahammed, Z; Alakhverdyants, A V; Alekseev, I; Alford, J; Anderson, B D; Anson, C D; Arkhipkin, D; Averichev, G S; Balewski, J; Barnby, L S; Beavis, D R; Behera, N K; Bellwied, R; Betancourt, M J; Betts, R R; Bhasin, A; Bhati, A K; Bichsel, H; Bielcik, J; Bielcikova, J; Bland, L C; Bordyuzhin, I G; Borowski, W; Bouchet, J; Braidot, E; Brandin, A V; Bridgeman, A; Brovko, S G; Bruna, E; Bueltmann, S; Bunzarov, I; Burton, T P; Cai, X Z; Caines, H; Sánchez, M Calderón de la Barca; Cebra, D; Cendejas, R; Cervantes, M C; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, J H; Chen, J Y; Chen, L; Cheng, J; Cherney, M; Chikanian, A; Choi, K E; Christie, W; Chung, P; Codrington, M J M; Corliss, R; Cramer, J G; Crawford, H J; Cui, X; Leyva, A Davila; De Silva, L C; Debbe, R R; Dedovich, T G; Deng, J; Derevschikov, A A; de Souza, R Derradi; Didenko, L; Djawotho, P; Dogra, S M; Dong, X; Drachenberg, J L; Draper, J E; Du, C M; Dunlop, J C; Efimov, L G; Elnimr, M; Engelage, J; Eppley, G; Estienne, M; Eun, L; Evdokimov, O; Fatemi, R; Fedorisin, J; Fersch, R G; Filip, P; Finch, E; Fine, V; Fisyak, Y; Gagliardi, C A; Gangadharan, D R; Geurts, F; Ghosh, P; Gorbunov, Y N; Gordon, A; Grebenyuk, O G; Grosnick, D; Gupta, A; Gupta, S; Guryn, W; Haag, B; Hajkova, O; Hamed, A; Han, L-X; Harris, J W; Hays-Wehle, J P; Heinz, M; Heppelmann, S; Hirsch, A; Hjort, E; Hoffmann, G W; Hofman, D J; Huang, B; Huang, H Z; Humanic, T J; Huo, L; Igo, G; Jacobs, P; Jacobs, W W; Jena, C; Jin, F; Jones, P G; Joseph, J; Judd, E G; Kabana, S; Kang, K; Kapitan, J; Kauder, K; Ke, H W; Keane, D; Kechechyan, A; Kettler, D; Kikola, D P; Kiryluk, J; Kisiel, A; Kizka, V; Klein, S R; Knospe, A G; Koetke, D D; Kollegger, T; Konzer, J; Koralt, I; Koroleva, L; Korsch, W; Kotchenda, L; Kouchpil, V; Kravtsov, P; Krueger, K; Krus, M; Kumar, L; Lamont, M A C; Landgraf, J M; LaPointe, S; Lauret, J; Lebedev, A; Lednicky, R; Lee, J H; Leight, W; LeVine, M J; Li, C; Li, L; Li, N; Li, W; Li, X; Li, X; Li, Y; Li, Z M; Lima, L M; Lisa, M A; Liu, F; Liu, H; Liu, J; Ljubicic, T; Llope, W J; Longacre, R S; Lu, Y; Lukashov, E V; Luo, X; Ma, G L; Ma, Y G; Mahapatra, D P; Majka, R; Mall, O I; Manweiler, R; Margetis, S; Markert, C; Masui, H; Matis, H S; McDonald, D; McShane, T S; Meschanin, A; Milner, R; Minaev, N G; Mioduszewski, S; Mitrovski, M K; Mohammed, Y; Mohanty, B; Mondal, M M; Morozov, B; Morozov, D A; Munhoz, M G; Mustafa, M K; Naglis, M; Nandi, B K; Nayak, T K; Nelson, J M; Nogach, L V; Nurushev, S B; Odyniec, G; Ogawa, A; Oh, K; Ohlson, A; Okorokov, V; Oldag, E W; Oliveira, R A N; Olson, D; Pachr, M; Page, B S; Pal, S K; Pandit, Y; Panebratsev, Y; Pawlak, T; Pei, H; Peitzmann, T; Perkins, C; Peryt, W; Pile, P; Planinic, M; Ploskon, M A; Pluta, J; Plyku, D; Poljak, N; Porter, J; Poskanzer, A M; Potukuchi, B V K S; Powell, C B; Prindle, D; Pruneau, C; Pruthi, N K; Pujahari, P R; Putschke, J; Qiu, H; Raniwala, R; Raniwala, S; Ray, R L; Redwine, R; Reed, R; Ritter, H G; Roberts, J B; Rogachevskiy, O V; Romero, J L; Ruan, L; Rusnak, J; Sahoo, N R; Sakrejda, I; Salur, S; Sandweiss, J; Sangaline, E; Sarkar, A; Schambach, J; Scharenberg, R P; Schaub, J; Schmah, A M; Schmitz, N; Schuster, T R; Seele, J; Seger, J; Selyuzhenkov, I; Seyboth, P; Shah, N; Shahaliev, E; Shao, M; Sharma, M; Shi, S S; Shou, Q Y; Sichtermann, E P; Simon, F; Singaraju, R N; Skoby, M J; Smirnov, N; Solanki, D; Sorensen, P; deSouza, U G; Spinka, H M; Srivastava, B; Stanislaus, T D S; Steadman, S G; Stevens, J R; Stock, R; Strikhanov, M; Stringfellow, B; Suaide, A A P; Suarez, M C; Subba, N L; Sumbera, M; Sun, X M; Sun, Y; Sun, Z; Surrow, B; Svirida, D N; Symons, T J M; de Toledo, A Szanto; Takahashi, J; Tang, A H; Tang, Z; Tarini, L H; Tarnowsky, T; Thein, D; Thomas, J H; Tian, J; Timmins, A R; Tlusty, D; Tokarev, M; Trainor, T A; Trentalange, S; Tribble, R E; Tribedy, P; Trzeciak, B A; Tsai, O D; Ullrich, T; Underwood, D G; Van Buren, G; van Nieuwenhuizen, G; Vanfossen, J A; Varma, R; Vasconcelos, G M S; Vasiliev, A N; Videbæk, F; Viyogi, Y P; Vokal, S; Voloshin, S A; Wada, M; Walker, M; Wang, F; Wang, G; Wang, H; Wang, J S; Wang, Q; Wang, X L; Wang, Y; Webb, G; Webb, J C; Westfall, G D; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Witzke, W; Wu, Y F; Xiao, Z; Xie, W; Xu, H; Xu, N; Xu, Q H; Xu, W; Xu, Y; Xu, Z; Xue, L; Yang, Y; Yang, Y; Yepes, P; Yip, K; Yoo, I-K; Zawisza, M; Zbroszczyk, H; Zhan, W; Zhang, J B; Zhang, S; Zhang, W M; Zhang, X P; Zhang, Y; Zhang, Z P; Zhao, F; Zhao, J; Zhong, C; Zhu, X; Zhu, Y H; Zoulkarneeva, Y

    2012-02-17

    We report new STAR measurements of midrapidity yields for the Λ, Λ[over ¯], K(S)(0), Ξ(-), Ξ[over ¯](+), Ω(-), Ω[over ¯](+) particles in Cu+Cu collisions at √S(NN)==200  GeV, and midrapidity yields for the Λ, Λ[over ¯], K(S)(0) particles in Au+Au at √S(NN)==200  GeV. We show that, at a given number of participating nucleons, the production of strange hadrons is higher in Cu+Cu collisions than in Au+Au collisions at the same center-of-mass energy. We find that aspects of the enhancement factors for all particles can be described by a parametrization based on the fraction of participants that undergo multiple collisions. PMID:22401196

  3. MMENT>Computational study of complete methanol dehydrogenation on Au(100) and Au(310) surfaces: Dominant role of atomic oxygen

    NASA Astrophysics Data System (ADS)

    Hussain, A.; Shah, S. H.

    2014-02-01

    Methanol dehydrogenation to CO and H2 has been systematically investigated on Au(100) and Au(310) surfaces using density functional theory (DFT). All possible intermediates involved are calculated. Methanol and formaldehyde being saturated molecules adsorb weakly on both the surfaces. The thermochemistry and kinetics of the decomposition via sequential hydrogen abstraction are both found to be highly unfavorable for these species. Nevertheless, atomic oxygen pre-covered surfaces substantially enhance CH3OH and CH2O (resulting in CH2O2 complex formation) interaction with Au and offer weak activation barrier for methanol disintegration into CH3O and H. On the other hand, methoxy, formyl, and atomic hydrogen are predicted to make strong chemical bonds with the clean Au surfaces. The abstraction of hydrogen from the methoxy intermediate on bare gold surfaces is practical, while formyl splits instantaneously during optimization. A feasible mechanism on oxygen pre-covered surfaces for complete methanol dehydrogenation has been presented.

  4. Public Affairs.

    ERIC Educational Resources Information Center

    Snow, C. P.

    In this book effects of technological developments on world conditions are discussed on the basis of the author's public statements made between 1959-70. A total of seven pieces is presented under the headings: The Two Cultures and the Scientific Revolution, The Two Cultures: A Second Look, The Case of Leavis and the Serious Case, Science and…

  5. Public Choices

    ERIC Educational Resources Information Center

    Kennedy, Mike

    2007-01-01

    The traditional way for parents to determine which public school their children will attend is as simple as looking at a map. But in some cases, what is the right campus from the perspective of school district planners is not the one desired by students or their parents. As school systems have embraced education reforms in recent years, some…

  6. Public Enquiries.

    ERIC Educational Resources Information Center

    McKay, Farquar

    1986-01-01

    Discusses the use of simulated "public inquiries" in classrooms. Includes factors involved in developing two such simulations. Describes basic components and sample texts for "The Generation Game," which deals with building a nuclear power facility, and "Closing the Foundry," which focuses on the implications of closing a local factory. (TW)

  7. Azimuthally sensitive hanbury brown-twiss interferometry in Au + Au collisions sqrt S sub NN = 200 GeV

    SciTech Connect

    Adams, J.; Adler, C.; Aggarwal, M.M.; Ahammed, Z.; Amonett, J.; Anderson, B.D.; Arkhipkin, D.; Averichev, G.S.; Badyal, S.K.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellwied, R.; Berger, J.; Bezverkhny, B.I.; Bhardwaj, S.; Bhati, A.K.; Bichsel, H.; Billmeier, A.; Bland, L.C.; Blyth, C.O.; Bonner, B.E.; Botje, M.; Boucham, A.; Brandin, A.; Bravar, A.; Cadman, R.V.; Cai, X.Z.; Caines, H.; Calderon de la Barca Sanchez, M.; Carroll, J.; Castillo, J.; Cebra, D.; Chaloupka, P.; Chattopadhyay, S.; Chen, H.F.; Chen, Y.; Chernenko, S.P.; Cherney, M.; Chikanian, A.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Cramer, J.G.; Crawford, H.J.; Das, D.; Das, S.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Dong, W.J.; Dong, X.; Draper, J.E.; Du, F.; Dubey, A.K.; Dunin, V.B.; Dunlop, J.C.; Dutta Majumdar, M.R.; Eckardt, V.; Efimov, L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Faine, V.; Faivre, J.; Fatemi, R.; Filimonov, K.; Filip, P.; Finch, E.; Fisyak, Y.; Flierl, D.; Foley, K.J.; Fu, J.; Gagliardi, C.A.; Gagunashvili, N.; Gans, J.; Gaudichet, L.; Geurts, F.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J.E.; Grachov, O.; Grebenyuk, O.; Gronstal, S.; Grosnick, D.; Guertin, S.M.; Gupta, A.; Gutierrez, T.D.; Hallman, T.J.; Hamed, A.; Hardtke, D.; Harris, J.W.; Heinz, M.; Henry, T.W.; Heppelmann, S.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffmann, G.W.; Horsley, M.; Huang, H.Z.; Huang, L.S.; Hughes, E.; Humanic, T.J.; Igo, G.; Ishihara, A.; Jacobs, P.; Jacobs, W.W.; Janik, M.; Jiang, H.; Johnson, I.; Jones, P.G.; Judd, E.G.; Kabana, S.; Kaplan, M.; Keane, D.; Khodyrev, V.Yu.; Kiryluk, J.; Kisiel, A.; Klay, J.; Klein, S.R.; Klyachko, A.; Koetke, D.D.; Kollegger, T.; Kopytine, M.; Kotchenda, L.; Kovalenko, A.D.; Kramer, M.; Kravtsov, V.I.; Kravtsov, P.; Krueger, K.; Kuhn, C.; Kulikov, A.I.; Kumar, A.; Kunde, G.J.; Kunz, C.L.; Kutuev, R.Kh.; Kuznetsov, A.A.; Lamont, M.A.C.; et al.

    2004-06-30

    We present the results of a systematic study of the shape of the pion distribution in coordinate space at freeze-out in Au+Au collisions at RHIC using two-pion Hanbury Brown-Twiss (HBT) interferometry. Oscillations of the extracted HBT radii vs. emission angle indicate sources elongated perpendicular to the reaction plane. The results indicate that the pressure and expansion time of the collision system are not sufficient to completely quench its initial shape.

  8. NUCLEAR AND HEAVY ION PHYSICS: Charged-particle pseudorapidity distributions in Au+Au collisions at RHIC

    NASA Astrophysics Data System (ADS)

    Wang, Zeng-Wei; Jiang, Zhi-Jin

    2009-04-01

    Using the Glauber model, we present the formulas for calculating the numbers of participants, spectators and binary nucleon-nucleon collisions. Based on this work, we get the pseudorapidity distributions of charged particles as the function of the impact parameter in nucleus-nucleus collisions. The theoretical results agree well with the experimental observations made by the BRAHMS Collaboration in Au + Au collisions at GeV in different centrality bins over the whole pseudorapidity range.

  9. Rationalization of Au concentration and distribution in AuNi@Pt core-shell nanoparticles for oxygen reduction reaction

    SciTech Connect

    An, Wei; Liu, Ping

    2015-09-18

    Improving the activity and stability of Pt-based core–shell nanocatalysts for proton exchange membrane fuel cells while lowering Pt loading has been one of the big challenges in electrocatalysis. Here, using density functional theory, we report the effect of adding Au as the third element to enhance the durability and activity of Ni@Pt core–shell nanoparticles (NPs) during the oxygen reduction reaction (ORR). Our results show that the durability and activity of a Ni@Pt NP can be finely tuned by controlling Au concentration and distribution. For a NiAu@Pt NP, the durability can be greatly promoted by thermodynamically favorable segregation of Au to replace the Pt atoms at vertex, edge, and (100) facets on the shell, while still keeping the ORR activity on the active Pt(111) shell as high as that of Ni@Pt nanoparticles. Such behavior strongly depends on a direct interaction with the Ni interlayer. The results not only highlight the importance of interplay between surface strain on the shell and the interlayer–shell interaction in determining the durability and activity but also provide guidance on how to maximize the usage of Au to optimize the performance of core–shell (Pt) nanoparticles. As a result, such understanding has allowed us to discover a novel NiAu@Pt nanocatalyst for the ORR.

  10. Effect of Au Content on Thermal Stability and Mechanical Properties of Au-Cu-Ag-Si Bulk Metallic Glasses

    NASA Astrophysics Data System (ADS)

    Guo, H.; Zhang, W.; Chen, M. W.; Saotome, Y.; Fukuhara, M.; Inoue, A.

    2011-06-01

    The thermal stability, glass-forming ability (GFA), and mechanical and electrical properties of Au-based Au x Si17Cu75.5- x Ag7.5 ( x = 40 to 75.5 at. pct) metallic glasses were investigated. The glass transition temperature ( T g ) and crystallization temperature ( T x ) decreased with increasing Au content. The ultralow T g values below 373 K (100 °C) were obtained for alloys with x = 55 to 75.5. The alloys with x = 45 to 70 exhibited a high stabilization of supercooled liquid and a high GFA, and the supercooled liquid region and critical sample diameter for glass formation were in the range of 31 K to 50 K and 2 to 5 mm, respectively. The compressive fracture strength ( σ c,f ), Young's modulus ( E), and Vicker's hardness ( H v ) of the bulk metallic glasses (BMGs) decreased with increasing Au content. A linear correlation between Au concentration and the characteristic temperature, i.e., T g and T x , and mechanical properties, i.e., σ c,f , E, and H v , as well as electrical resistivity can be found in the BMGs, which will be helpful for the composition design of the desirable Au-based BMGs with tunable physical properties.

  11. Versatile and efficient catalysts for energy and environmental processes: Mesoporous silica containing Au, Pd and Au-Pd

    NASA Astrophysics Data System (ADS)

    da Silva, Anderson G. M.; Fajardo, Humberto V.; Balzer, Rosana; Probst, Luiz F. D.; Lovón, Adriana S. P.; Lovón-Quintana, Juan J.; Valença, Gustavo P.; Schreine, Wido H.; Robles-Dutenhefner, Patrícia A.

    2015-07-01

    We described a versatile approach for the synthesis of Au/MCM-41, Pd/MCM-41 and Au-Pd/MCM-41 by the direct incorporation of the noble metals into the MCM-41 framework. The structural, textural and chemical properties were characterized by X-ray diffraction (XRD), temperature-programmed reduction (TPR), N2-adsorption (BET and BJH methods), H2-chemisorption, small angle X-ray scattering (SAXS), transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS). The nanomaterials, being comprised of Au, Pd and Au-Pd nanoparticles and possessing high surface areas were applied as versatile and efficient catalysts in benzene, toluene and o-xylene (BTX) oxidation and in the steam reforming of ethanol for hydrogen production. The results revealed that the catalytic behavior in both processes was influenced by the experimental conditions and the nature of the catalyst employed. The Au-Pd/MCM-41 catalyst was the most active in the BTX total oxidation. On the basis of characterization data, it was proposed that the close contact between Pd and Au and the higher dispersion of Pd may be responsible for the enhanced activity of the bimetallic catalyst. However, the strong interaction between the noble metals did not improve the performance of the bimetallic catalyst in ethanol steam reforming, the Pd/MCM-41 catalyst being the most active and selective for hydrogen production.

  12. Rationalization of Au concentration and distribution in AuNi@Pt core-shell nanoparticles for oxygen reduction reaction

    DOE PAGESBeta

    An, Wei; Liu, Ping

    2015-09-18

    Improving the activity and stability of Pt-based core–shell nanocatalysts for proton exchange membrane fuel cells while lowering Pt loading has been one of the big challenges in electrocatalysis. Here, using density functional theory, we report the effect of adding Au as the third element to enhance the durability and activity of Ni@Pt core–shell nanoparticles (NPs) during the oxygen reduction reaction (ORR). Our results show that the durability and activity of a Ni@Pt NP can be finely tuned by controlling Au concentration and distribution. For a NiAu@Pt NP, the durability can be greatly promoted by thermodynamically favorable segregation of Au tomore » replace the Pt atoms at vertex, edge, and (100) facets on the shell, while still keeping the ORR activity on the active Pt(111) shell as high as that of Ni@Pt nanoparticles. Such behavior strongly depends on a direct interaction with the Ni interlayer. The results not only highlight the importance of interplay between surface strain on the shell and the interlayer–shell interaction in determining the durability and activity but also provide guidance on how to maximize the usage of Au to optimize the performance of core–shell (Pt) nanoparticles. As a result, such understanding has allowed us to discover a novel NiAu@Pt nanocatalyst for the ORR.« less

  13. Amperometric immunosensor for carbofuran detection based on MWCNTs/GS-PEI-Au and AuNPs-antibody conjugate.

    PubMed

    Zhu, Ying; Cao, Yaoyao; Sun, Xia; Wang, Xiangyou

    2013-04-19

    In this paper, an amperometric immunosensor for the detection of carbofuran was developed. Firstly, multiwall carbon nanotubes (MWCNTs) and graphene sheets-ethyleneimine polymer-Au (GS-PEI-Au) nanocomposites were modified onto the surface of a glass carbon electrode (GCE) via self-assembly. The nanocomposites can increase the surface area of the GCE to capture a large amount of antibody, as well as produce a synergistic effect in the electrochemical performance. Then the modified electrode was coated with gold nanoparticles-antibody conjugate (AuNPs-Ab) and blocked with BSA. The monoclonal antibody against carbofuran was covalently immobilized on the AuNPs with glutathione as a spacer arm. The morphologies of the GS-PEI-Au nanocomposites and the fabrication process of the immunosensor were characterized by X-ray diffraction (XRD), ultraviolet and visible absorption spectroscopy (UV-vis) and scanning electron microscopy (SEM), respectively. Under optimal conditions, the immunosensor showed a wide linear range, from 0.5 to 500 ng/mL, with a detection limit of 0.03 ng/mL (S/N = 3). The as-constructed immunosensor exhibited notable performance features such as high specificity, good reproducibility, acceptable stability and regeneration performance. The results are mainly due to the excellent properties of MWCNTs, GS-PEI-Au nanocomposites and the covalent immobilization of Ab with free hapten binding sites for further immunoreaction. It provides a new avenue for amperometric immunosensor fabrication.

  14. Heterojunction metal-oxide-metal Au-Fe{sub 3}O{sub 4}-Au single nanowire device for spintronics

    SciTech Connect

    Reddy, K. M. Punnoose, Alex; Hanna, Charles; Padture, Nitin P.

    2015-05-07

    In this report, we present the synthesis of heterojunction magnetite nanowires in alumina template and describe magnetic and electrical properties from a single nanowire device for spintronics applications. Heterojunction Au-Fe-Au nanowire arrays were electrodeposited in porous aluminum oxide templates, and an extensive and controlled heat treatment process converted Fe segment to nanocrystalline cubic magnetite phase with well-defined Au-Fe{sub 3}O{sub 4} interfaces as confirmed by the transmission electron microscopy. Magnetic measurements revealed Verwey transition shoulder around 120 K and a room temperature coercive field of 90 Oe. Current–voltage (I-V) characteristics of a single Au-Fe{sub 3}O{sub 4}-Au nanowire have exhibited Ohmic behavior. Anomalous positive magnetoresistance of about 0.5% is observed on a single nanowire, which is attributed to the high spin polarization in nanowire device with pure Fe{sub 3}O{sub 4} phase and nanocontact barrier. This work demonstrates the ability to preserve the pristine Fe{sub 3}O{sub 4} and well defined electrode contact metal (Au)–magnetite interface, which helps in attaining high spin polarized current.

  15. Amperometric immunosensor for carbofuran detection based on MWCNTs/GS-PEI-Au and AuNPs-antibody conjugate.

    PubMed

    Zhu, Ying; Cao, Yaoyao; Sun, Xia; Wang, Xiangyou

    2013-01-01

    In this paper, an amperometric immunosensor for the detection of carbofuran was developed. Firstly, multiwall carbon nanotubes (MWCNTs) and graphene sheets-ethyleneimine polymer-Au (GS-PEI-Au) nanocomposites were modified onto the surface of a glass carbon electrode (GCE) via self-assembly. The nanocomposites can increase the surface area of the GCE to capture a large amount of antibody, as well as produce a synergistic effect in the electrochemical performance. Then the modified electrode was coated with gold nanoparticles-antibody conjugate (AuNPs-Ab) and blocked with BSA. The monoclonal antibody against carbofuran was covalently immobilized on the AuNPs with glutathione as a spacer arm. The morphologies of the GS-PEI-Au nanocomposites and the fabrication process of the immunosensor were characterized by X-ray diffraction (XRD), ultraviolet and visible absorption spectroscopy (UV-vis) and scanning electron microscopy (SEM), respectively. Under optimal conditions, the immunosensor showed a wide linear range, from 0.5 to 500 ng/mL, with a detection limit of 0.03 ng/mL (S/N = 3). The as-constructed immunosensor exhibited notable performance features such as high specificity, good reproducibility, acceptable stability and regeneration performance. The results are mainly due to the excellent properties of MWCNTs, GS-PEI-Au nanocomposites and the covalent immobilization of Ab with free hapten binding sites for further immunoreaction. It provides a new avenue for amperometric immunosensor fabrication. PMID:23604029

  16. Theoretical investigation of superconductivity in SrAuSi3 and SrAu2Si2

    NASA Astrophysics Data System (ADS)

    Arslan, Enes; Karaca, Ertuǧrul; Tütüncü, H. M.; Başoglu, A.; Srivastava, G. P.

    2016-08-01

    The structural and electronic properties of BaNiSn3-type SrAuSi3 and ThCr2Si2-type SrAu2Si2 have been investigated by using the planewave pseudopotential method and the density functional theory. The electronic structures and phonon dispersion relations of these two materials have been analyzed with and without the inclusion of spin-orbit interaction, and similarities and differences highlighted. By integrating the Eliashberg spectral function α2F(ω), the average electron-phonon coupling parameter is determined to be λ=0.47 for SrAuSi3 and 0.42 for SrAu2Si2. The largest contribution to the electron-phonon coupling for SrAuSi3 comes from the Si p electrons near the Fermi energy and Si-related vibrations. Using a reasonable value of μ* = 0.12 for the effective Coulomb repulsion parameter, the superconducting critical temperature Tc for SrAuSi3 is found to be 1.47 K which compares very well with its experimental value of 1.54 K.

  17. Effect of Au nano-particle aggregation on the deactivation of the AuCl3/AC catalyst for acetylene hydrochlorination

    PubMed Central

    Dai, Bin; Wang, Qinqin; Yu, Feng; Zhu, Mingyuan

    2015-01-01

    A detailed study of the valence state and distribution of the AuCl3/AC catalyst during the acetylene hydrochlorination deactivation process is described and discussed. Temperature-programmed reduction and X-ray photoelectron spectral analysis indicate that the active Au3+ reduction to metallic Au0 is one reason for the deactivation of AuCl3/AC catalyst. Transmission electron microscopy characterization demonstrated that the particle size of Au nano-particles increases with increasing reaction time. The results indicated that metallic Au0 exhibits considerable catalytic activity and that Au nano-particle aggregation may be another reason for the AuCl3/AC catalytic activity in acetylene hydrochlorination. PMID:25994222

  18. Disappearance of back-to-back high p {sub T} hadron correlations in central Au+Au collisions at {radical}s{sub NN} = 200 GeV

    SciTech Connect

    Adler, C.; Ahammed, Z.; Allgower, C.; Amonett, J.; Anderson, B.D.; Anderson, M.; Averichev, G.S.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellwied, R.; Berger, J.; Bichsel, H.; Billmeier, A.; Bland, L.C.; Blyth, C.O.; Bonner, B.E.; Boucham, A.; Brandin, A.; Bravar, A.; Cadman, R.V.; Caines, H.; Calderon de la Barca Sanchez, M.; Cardenas, A.; Carroll, J.; Castillo, J.; Castro, M.; Cebra, D.; Chaloupka, P.; Chattopadhyay, S.; Chen, Y.; Chernenko, S.P.; Cherney, M.; Chikanian, A.; Choi, B.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Corral, M.M.; Cramer, J.G.; Crawford, H.J.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Draper, J.E.; Dunin, V.B.; Dunlop, J.C.; Eckardt, V.; Efimov, L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Fachini, P.; Faine, V.; Faivre, J.; Fatemi, R.; Filimonov, K.; Finch, E.; Fisyak, Y.; Flierl, D.; Foley, K.J.; Fu, J.; Gagliardi, C.A.; Gagunashvili, N.; Gans, J.; Gaudichet, L.; Germain, M.; Geurts, F.; Ghazikhanian, V.; Grachov, O.; Grigoriev, V.; Guedon, M.; Gushin, E.; Hallman, T.J.; Hardtke, D.; Harris, J.W.; Henry, T.W.; Heppelmann, S.; Herston, T.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffmann, G.W.; Horsley, M.; Huang, H.Z.; Humanic, T.J.; Igo, G.J.; Ishihara, A.; Ivanshin, Yu.I.; Jacobs, P.; Jacobs, W.W.; Janik, M.; Johnson, I.; Jones, P.G.; Judd, E.G.; Kaneta, M.; Kaplan, M.; Keane, D.; Kiryluk, J.; Kisiel, A.; Klay, J.; Klein, S.R.; Klyachko, A.; Kollegger, T.; Konstantinov, A.S.; Kopytine, M.; Kotchenda, L.; Kovalenko, A.D.; Kramer, M.; Kravtsov, P.; Krueger, K.; Kuhn, C.; Kulikov, A.I.; Kunde, G.J.; Kunz, C.L.; Kutuev, R.Kh.; Kuznetsov, A.A.; Lakehal-Ayat, L.; Lamont, M.A.C.; Landgraf, J.M.; Lange, S.; Lansdell, C.P.; Lasiuk, B.; Laue, F.; Lauret, J.; Lebedev, A.; Lednicky, R.; Leontiev, V.M.; LeVine, M.J.; Li , Q.; Lindenbaum, S.J.; Lisa, M.A.; Liu, F.; Liu, L.; Liu, Z.; Liu, Q.J.; Ljubicic, T.; Llope, W.J.; LoCurto, G.; et al.

    2002-10-25

    Azimuthal correlations for large transverse momentum charged hadrons have been measured over a wide pseudo-rapidity range and full azimuth in Au+Au and p+p collisions at = {radical}s{sub NN} = 200 GeV. The small-angle correlations observed in p+p collisions and at all centralities of Au+Au collisions are characteristic of hard-scattering processes already observed in elementary collisions. A strong back-to-back correlation exists for p+p and peripheral Au + Au. In contrast, the back-to-back correlations are reduced considerably in the most central Au+Au collisions, indicating substantial interaction as the hard-scattered partons or their fragmentation products traverse the medium.

  19. Disappearance of back-to-back high-pT hadron correlations in central Au+Au collisions at sqrt[s NN ] =200 GeV.

    PubMed

    Adler, C; Ahammed, Z; Allgower, C; Amonett, J; Anderson, B D; Anderson, M; Averichev, G S; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bichsel, H; Billmeier, A; Bland, L C; Blyth, C O; Bonner, B E; Boucham, A; Brandin, A; Bravar, A; Cadman, R V; Caines, H; Calderón de la Barca Sánchez, M; Cardenas, A; Carroll, J; Castillo, J; Castro, M; Cebra, D; Chaloupka, P; Chattopadhyay, S; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Christie, W; Coffin, J P; Cormier, T M; Corral, M M; Cramer, J G; Crawford, H J; Derevschikov, A A; Didenko, L; Dietel, T; Draper, J E; Dunin, V B; Dunlop, J C; Eckardt, V; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Fachini, P; Faine, V; Faivre, J; Fatemi, R; Filimonov, K; Finch, E; Fisyak, Y; Flierl, D; Foley, K J; Fu, J; Gagliardi, C A; Gagunashvili, N; Gans, J; Gaudichet, L; Germain, M; Geurts, F; Ghazikhanian, V; Grachov, O; Grigoriev, V; Guedon, M; Gushin, E; Hallman, T J; Hardtke, D; Harris, J W; Henry, T W; Heppelmann, S; Herston, T; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Huang, H Z; Humanic, T J; Igo, G; Ishihara, A; Ivanshin, Yu I; Jacobs, P; Jacobs, W W; Janik, M; Johnson, I; Jones, P G; Judd, E G; Kaneta, M; Kaplan, M; Keane, D; Kiryluk, J; Kisiel, A; Klay, J; Klein, S R; Klyachko, A; Kollegger, T; Konstantinov, A S; Kopytine, M; Kotchenda, L; Kovalenko, A D; Kramer, M; Kravtsov, P; Krueger, K; Kuhn, C; Kulikov, A I; Kunde, G J; Kunz, C L; Kutuev, R Kh; Kuznetsov, A A; Lakehal-Ayat, L; Lamont, M A C; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lauret, J; Lebedev, A; Lednický, R; Leontiev, V M; LeVine, M J; Li, Q; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, L; Liu, Z; Liu, Q J; Ljubicic, T; Llope, W J; LoCurto, G; Long, H; Longacre, R S; Lopez-Noriega, M; Love, W A; Ludlam, T; Lynn, D; Ma, J; Magestro, D; Majka, R; Margetis, S; Markert, C; Martin, L; Marx, J; Matis, H S; Matulenko, Yu A; McShane, T S; Meissner, F; Melnick, Yu; Meschanin, A; Messer, M; Miller, M L; Milosevich, Z; Minaev, N G; Mitchell, J; Moore, C F; Morozov, V; de Moura, M M; Munhoz, M G; Nelson, J M; Nevski, P; Nikitin, V A; Nogach, L V; Norman, B; Nurushev, S B; Odyniec, G; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Paic, G; Pandey, S U; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Perevoztchikov, V; Peryt, W; Petrov, V A; Planinic, M; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potrebenikova, E; Prindle, D; Pruneau, C; Putschke, J; Rai, G; Rakness, G; Ravel, O; Ray, R L; Razin, S V; Reichhold, D; Reid, J G; Renault, G; Retiere, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Rykov, V; Sakrejda, I; Salur, S; Sandweiss, J; Savin, I; Schambach, J; Scharenberg, R P; Schmitz, N; Schroeder, L S; Schüttauf, A; Schweda, K; Seger, J; Seliverstov, D; Seyboth, P; Shahaliev, E; Shestermanov, K E; Shimanskii, S S; Simon, F; Skoro, G; Smirnov, N; Snellings, R; Sorensen, P; Sowinski, J; Spinka, H M; Srivastava, B; Stephenson, E J; Stock, R; Stolpovsky, A; Strikhanov, M; Stringfellow, B; Struck, C; Suaide, A A P; Sugarbaker, E; Suire, C; Sumbera, M; Surrow, B; Symons, T J M; Szanto de Toledo, A; Szarwas, P; Tai, A; Takahashi, J; Tang, A H; Thein, D; Thomas, J H; Thompson, M; Tikhomirov, V; Tokarev, M; Tonjes, M B; Trainor, T A; Trentalange, S; Tribble, R E; Trofimov, V; Tsai, O; Ullrich, T; Underwood, D G; Van Buren, G; VanderMolen, A M; Vasilevski, I M; Vasiliev, A N; Vigdor, S E; Voloshin, S A; Wang, F; Ward, H; Watson, J W; Wells, R; Westfall, G D; Whitten, C; Wieman, H; Willson, R; Wissink, S W; Witt, R; Wood, J; Xu, N; Xu, Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yurevich, V I; Zanevski, Y V; Zborovský, I; Zhang, H; Zhang, W M; Zoulkarneev, R; Zubarev, A N

    2003-02-28

    Azimuthal correlations for large transverse momentum charged hadrons have been measured over a wide pseudorapidity range and full azimuth in Au+Au and p+p collisions at sqrt[s(NN)]=200 GeV. The small-angle correlations observed in p+p collisions and at all centralities of Au+Au collisions are characteristic of hard-scattering processes previously observed in high-energy collisions. A strong back-to-back correlation exists for p+p and peripheral Au+Au. In contrast, the back-to-back correlations are reduced considerably in the most central Au+Au collisions, indicating substantial interaction as the hard-scattered partons or their fragmentation products traverse the medium. PMID:12633419

  20. How Can We Understand Au8 Cores and Entangled Ligands of Selenolate- and Thiolate-Protected Gold Nanoclusters Au24(ER)20 and Au20(ER)16 (E = Se, S; R = Ph, Me)? A Theoretical Study.

    PubMed

    Takagi, Nozomi; Ishimura, Kazuya; Matsui, Masafuyu; Fukuda, Ryoichi; Matsui, Toru; Nakajima, Takahito; Ehara, Masahiro; Sakaki, Shigeyoshi

    2015-07-01

    The geometries and electronic structures of selenolate-protected Au nanoclusters, Au24(SeR)20 and Au20(SeR)16, and their thiolate analogues are theoretically investigated with DFT and SCS-MP2 methods, to elucidate the electronic structure of their unusual Au8 core and the reason why they have the unusual entangled "staple-like" chain ligands. The Au8 core is understood to be an [Au4](2+) dimer in which the [Au4](2+) species has a tetrahedral geometry with a closed-shell singlet ground state. The SCS-MP2 method successfully reproduced the distance between two [Au4](2+) moieties, but the DFT with various functionals failed it, suggesting that the dispersion interaction is crucial between these two [Au4](2+) moieties. The SCS-MP2-calculated formation energies of these nanocluster compounds indicate that the thiolate staple-like chain ligands are more stable than the selenolate ones, but the Au8 core more strongly coordinates with the selenolate staple-like chain ligands than with the thiolate ones. Though Au20(SeR)16 has not been reported yet, its formation energy is calculated to be large, suggesting that this compound can be synthesized as a stable species if the concentration of Au(SeR) is well adjusted. The aurophilic interactions between the staple-like chain ligands and between the Au8 core and the staple-like chain ligand play an important role for the stability of these compounds. Because of the presence of this autophilic interaction, Au24(SeR)20 is more stable than Au20(SeR)16 and the unusual entangled ligands are involved in these compounds. PMID:26076323

  1. Formation, Migration, and Reactivity of Au CO Complexes on Gold Surfaces

    DOE PAGESBeta

    Wang, Jun; McEntee, Monica; Tang, Wenjie; Neurock, Matthew; Baddorf, Arthur P.; Maksymovych, Petro; Yates, Jr, John T.

    2016-01-12

    Here, we report experimental as well as theoretical evidence that suggests Au CO complex formation upon the exposure of CO to active sites (step edges and threading dislocations) on a Au(111) surface. Room-temperature scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy, transmission infrared spectroscopy, and density functional theory calculations point to Au CO complex formation and migration. Room-temperature STM of the Au(111) surface at CO pressures in the range from 10^ 8 to 10^ 4 Torr (dosage up to 10^6 langmuir) indicates Au atom extraction from dislocation sites of the herringbone reconstruction, mobile Au CO complex formation and diffusion, and Aumore » adatom cluster formation on both elbows and step edges on the Au surface. The formation and mobility of the Au CO complex result from the reduced Au Au bonding at elbows and step edges leading to stronger Au CO bonding and to the formation of a more positively charged CO (CO +) on Au. These studies indicate that the mobile Au CO complex is involved in the Au nanoparticle formation and reactivity, and that the positive charge on CO increases due to the stronger adsorption of CO at Au sites with lower coordination numbers.« less

  2. Enantiospecific adsorption of cysteine on a chiral Au34 cluster

    NASA Astrophysics Data System (ADS)

    de Jesús Pelayo, José; Valencia, Israel; Díaz, Gabriela; López-Lozano, Xóchitl; Garzón, Ignacio L.

    2015-12-01

    The interaction of biological molecules like chiral amino acids with chiral metal clusters is becoming an interesting and active field of research because of its potential impact in, for example, chiral molecular recognition phenomena. In particular, the enantiospecific adsorption (EA) of cysteine (Cys) on a chiral Au55 cluster was theoretically predicted a few years ago. In this work, we present theoretical results, based on density functional theory, of the EA of non-zwitterionic cysteine interacting with the C3-Au34 chiral cluster, which has been experimentally detected in gas phase, using trapped ion electron diffraction. Our results show that, indeed, the adsorption energy of the amino acid depends on which enantiomers participate in the formation Cys-Au34 chiral complex. EA was obtained in the adsorption modes where both the thiol, and the thiol-amino functional groups of Cys are adsorbed on low-coordinated sites of the metal cluster surface. Similarly to what was obtained for the Cys-Au55 chiral complex, in the present work, it is found that the EA is originated from the different strength and location of the bond between the COOH functional group and surface Au atoms of the Au34 chiral cluster. Calculations of the vibrational spectrum for the different Cys-Au34 diastereomeric complexes predict the existence of a vibro-enantiospecific effect, indicating that the vibrational frequencies of the adsorbed amino acid depend on its handedness. Contribution to the Topical Issue "Atomic Cluster Collisions (7th International Symposium)", edited by G. Delgado Barrio, A. Solov'Yov, P. Villarreal, R. Prosmiti.

  3. Public opinion.

    PubMed

    Holden, A

    2013-04-01

    This opinion-based article aims to highlight the worrying decline in support for dental public health as a specialty. Not only is this specialty important for its role in commissioning services, it is crucial for the identification of vulnerable groups in society and ensuring dental services are acceptable and assessable for these populations. Dental public health also addresses the social determinants of health in its approach, acknowledging the impact of these in perpetuating inequalities and looking for multisectoral approaches to their management. This article also looks at the lack of appreciation for these determinants in dental foundation training and how a change in the structure of the programme could both address this and the current shortage of places.

  4. Public Lecture

    ScienceCinema

    None

    2016-07-12

    An outreach activity is being organized by the Turkish community at CERN, on 5 June 2010 at CERN Main Auditorium. The activity consists of several talks that will take 1.5h in total. The main goal of the activity will be describing the CERN based activities and experiments as well as stimulating the public's attention to the science related topics. We believe the wide communication of the event has certain advantages especially for the proceeding membership process of Turkey.

  5. Public Lecture

    SciTech Connect

    2010-06-11

    An outreach activity is being organized by the Turkish community at CERN, on 5 June 2010 at CERN Main Auditorium. The activity consists of several talks that will take 1.5h in total. The main goal of the activity will be describing the CERN based activities and experiments as well as stimulating the public's attention to the science related topics. We believe the wide communication of the event has certain advantages especially for the proceeding membership process of Turkey.

  6. Thiol ligand-induced transformation of Au38(SC2H4Ph)24 to Au36(SPh-t-Bu)24.

    PubMed

    Zeng, Chenjie; Liu, Chunyan; Pei, Yong; Jin, Rongchao

    2013-07-23

    We report a disproportionation mechanism identified in the transformation of rod-like biicosahedral Au38(SCH2CH2Ph)24 to tetrahedral Au36(TBBT)24 nanoclusters. Time-dependent mass spectrometry and optical spectroscopy analyses unambiguously map out the detailed size-conversion pathway. The ligand exchange of Au38(SCH2CH2Ph)24 with bulkier 4-tert-butylbenzenethiol (TBBT) until a certain extent starts to trigger structural distortion of the initial biicosahedral Au38(SCH2CH2Ph)24 structure, leading to the release of two Au atoms and eventually the Au36(TBBT)24 nanocluster with a tetrahedral structure, in which process the number of ligands is interestingly preserved. The other product of the disproportionation process, i.e., Au40(TBBT)m+2(SCH2CH2Ph)24-m, was concurrently observed as an intermediate, which was the result of addition of two Au atoms and two TBBT ligands to Au38(TBBT)m(SCH2CH2Ph)24-m. The reaction kinetics on the Au38(SCH2CH2Ph)24 to Au36(TBBT)24 conversion process was also performed, and the activation energies of the structural distortion and disproportionation steps were estimated to be 76 and 94 kJ/mol, respectively. The optical absorption features of Au36(TBBT)24 are interpreted on the basis of density functional theory simulations.

  7. A simple electrochemical biosensor based on AuNPs/MPS/Au electrode sensing layer for monitoring carbamate pesticides in real samples.

    PubMed

    Song, Yonghai; Chen, Jingyi; Sun, Min; Gong, Coucong; Shen, Yuan; Song, Yonggui; Wang, Li

    2016-03-01

    A simple electrochemical biosensor for quantitative determination of carbamate pesticide was developed based on a sensing interface of citrate-capped gold nanoparticles (AuNPs)/(3-mercaptopropyl)-trimethoxysilane (MPS)/gold electrode (Au). The biosensor was fabricated by firstly assembling three-dimensional (3D) MPS networks on Au electrode and subsequently assembling citrate-capped AuNPs on 3D MPS network via AuS bond. The interface of AuNPs/MPS/Au was negatively charged originating from the citrate coated on AuNPs that would repulse the negatively charged ferricyanide ([Fe(CN)6](3-/4-)) to produce a negative response. In the presence of acetylcholinesterase (AChE) and acetylthiocholine (ATCl), the AChE catalyzes the hydrolysis of ATCl into positively charged thiocholine which would replace the citrate on AuNPs through the strong AuS bond and convert the negative charged surface to be positively charged. The resulted positively charged AuNPs/MPS/Au then attracted the [Fe(CN)6](3-/4-) to produce a positive response. Based on the inhibition of carbamate pesticides on the activity of AChE, the pesticide could be quantitatively determined at a very low potential. The linear range was from 0.003 to 2.00 μM. The sensing platform was also proved to be suitable for carbamate pesticides detection in practical sample.

  8. The characteristics of solar wind magnetic field during the negative-AU and large-AU (>1200nT) events

    NASA Astrophysics Data System (ADS)

    Lyu, L. H.; Kao, W.

    2014-12-01

    The negative-AU events are relatively unusual, which have caught our attention. To understand the cause of negative AU, we first eliminate the ring-current effect by considering only the events with AUAU has strong negative Bz and By components during these negative-AU events. We also found that one of the negative AU events has been reported by Feldstein et al. (2006). They associated the enhancement of westward electric jet by the negative IMF-By component based on previous models obtained independently by Friis-Christensen et al. (1972) and Sumaruk & Feldstein (1973). Enhancement of electric jet in opposite direction is expected to be found when the IMF-By is positive. To verify their models we also examine the strong AU events with AU > 1200nT. We found that these large-AU events are associated with IMF-Bz<0 and IMF-By >0. Both negative-AU and large-AU events tend to occur during the beginning of the main phase of a strong magnetic storm with Kp= 7~9. The enhancement of Cowling electrojet has been proposed by Kan et al. (2011) for the triggering of substorm onset. We will discuss the possibility that a similar enhancement process might take place in the dayside auroral oval during these extreme AU events.

  9. How Public Is Public Administration? A Constitutional Approach of Publicness

    ERIC Educational Resources Information Center

    Ringeling, Arthur

    2015-01-01

    Both in Public Administration and in practice, there is a loss of the concept of public. A view became dominant in which markets were superior to governments and public to private. Not only did the esteem of the public sphere diminish, but also its significance in our reasoning and teaching. It became less clear what the public sphere stood for.…

  10. Effects of stretching and compression on conducting properties of an Au-alkanedithiol-Au molecular junction

    NASA Astrophysics Data System (ADS)

    Xie, Fang; Zhang, Xiao-Jiao; Yu, Ji-Hai; Xu, Hua; Chu, Yu-Fang; Fan, Zhi-Qiang

    2016-03-01

    We have studied the effects of stretching and compression on the electronic properties of 7-alkanedithiol covalently linked to two Au electrodes. Results show a progressive increase in conductivity upon molecule compression and decrease with molecule stretching. The notable conductance increase at high compression is attributed to a significant modification of HOMO and LUMO orbitals of the junction, which enhances electron delocalization and promotes tunneling across the junction. More important, the current switching ratios between the various stages of compressed/extended geometries almost maintain the constant values on the bias region from 0 V to 2 V. In other word, the mechanically-induced conductance enhancement and weakening are stable within a large bias voltage range.

  11. Drowned reefs and antecedent karst topography, Au'au channel, S.E. Hawaiian Islands

    USGS Publications Warehouse

    Grigg, R.W.; Grossman, E.E.; Earle, S.A.; Gittings, S.R.; Lott, D.; McDonough, J.

    2002-01-01

    During the last glacial maximum (LGM), about 21,000 years ago, the Hawaiian Islands of Maui, Lanai, and Molokai were interconnected by limestone bridges, creating a super-island known as Maui-Nui. Approximately 120 m of sea-level rise during the Holocene Transgression flooded, and then drowned, these bridges separating the islands by inter-island channels. A new multibeam high-resolution bathymetric survey of the channels between the islands, coupled with observations and video-transects utilizing DeepWorker-2000 submersibles, has revealed the existence of numerous drowned reef features including concentric solution basins, solution ridges (rims), sand and sediment plains, and conical-shaped reef pinnacles. The concentric basins contain flat lagoon-like bottoms that are rimmed by steep-sided limestone walls. Undercut notches rim the basins at several depths, marking either sea-level still stands or paleo-lake levels. All of the solution basins shallower than 120 m were subaerial at the LGM, and at one stage or another may have been shallow shoreline lakes. Today, about 70 drowned reef pinnacles are scattered across the Maui-Lanai underwater bridge and all are situated in wave-sheltered positions. Most drowned during the interval between 14,000 and 10,000 years ago when sea-level rise averaged 15 mm/year. Virtually all of the surficial topography in the Au'au Channel today is a product of karst processes accentuated by marginal reef growth during the Holocene. Both the submerged basins and the drowned reefs represent an archive of sea-level and climate history in Hawaii during the late Quaternary.

  12. Dielectron production in Au plus Au collisions at root s(NN)=200 GeV

    SciTech Connect

    Adare, A.; Awes, Terry C; Cianciolo, Vince; Efremenko, Yuri V; Enokizono, A.; Silvermyr, D.; Sorensen, Soren P; Stankus, Paul W; Young, Glenn R; PHENIX, Collaboration [

    2016-01-01

    We present measurements of e(+)e-production at midrapidity in Au + Au collisions at root s(NN) = 200 GeV. The invariant yield is studied within the PHENIX detector acceptance over a wide range of mass (m(ee) < 5 GeV/c(2)) and pair transverse momentum (p(T) < 5 GeV/c) for minimum bias and for five centrality classes. The e(+)e(-) yield is compared to the expectations from known sources. In the low-mass region (m(ee) = 0.30-0.76 GeV/c(2)) there is an enhancement that increases with centrality and is distributed over the entire pair p(T) range measured. It is significantly smaller than previously reported by the PHENIX experiment and amounts to 2.3 +/- 0.4(stat) +/- 0.4(syst) +/- 0.2(model) or to 1.7 +/- 0.3(stat) +/- 0.3(syst) +/- 0.2(model) for minimum bias collisions when the open heavy-flavor contribution is calculated with PYTHIA or MC@NLO, respectively. The inclusive mass and p(T) distributions, as well as the centrality dependence, are well reproduced by model calculations where the enhancement mainly originates from the melting of the rho meson resonance as the system approaches chiral symmetry restoration. In the intermediate-mass region (m(ee) = 1.2-2.8 GeV/c(2)), the data hint at a significant contribution in addition to the yield from the semileptonic decays of heavy-flavor mesons.

  13. Dielectron production in Au plus Au collisions at root s(NN)=200 GeV

    DOE PAGESBeta

    Adare, A.; Awes, Terry C; Cianciolo, Vince; Efremenko, Yuri V; Enokizono, A.; Read, K. F.; Silvermyr, D.; Sorensen, Soren P; Stankus, Paul W; Young, Glenn R; et al

    2016-01-01

    We present measurements of e(+)e-production at midrapidity in Au + Au collisions at root s(NN) = 200 GeV. The invariant yield is studied within the PHENIX detector acceptance over a wide range of mass (m(ee) < 5 GeV/c(2)) and pair transverse momentum (p(T) < 5 GeV/c) for minimum bias and for five centrality classes. The e(+)e(-) yield is compared to the expectations from known sources. In the low-mass region (m(ee) = 0.30-0.76 GeV/c(2)) there is an enhancement that increases with centrality and is distributed over the entire pair p(T) range measured. It is significantly smaller than previously reported by themore » PHENIX experiment and amounts to 2.3 +/- 0.4(stat) +/- 0.4(syst) +/- 0.2(model) or to 1.7 +/- 0.3(stat) +/- 0.3(syst) +/- 0.2(model) for minimum bias collisions when the open heavy-flavor contribution is calculated with PYTHIA or MC@NLO, respectively. The inclusive mass and p(T) distributions, as well as the centrality dependence, are well reproduced by model calculations where the enhancement mainly originates from the melting of the rho meson resonance as the system approaches chiral symmetry restoration. In the intermediate-mass region (m(ee) = 1.2-2.8 GeV/c(2)), the data hint at a significant contribution in addition to the yield from the semileptonic decays of heavy-flavor mesons.« less

  14. Intriguing centrality dependence of the Au-Au source size at the AGS

    SciTech Connect

    Baker, M.D.; The E802 Collaboration

    1996-06-01

    One of the main goals of high energy heavy ion physics is to establish the existence of a deconfined phase of nuclear matter--the quark-gluon plasma--at high temperatures or densities. One possible signature of such a phase transition, especially if it were first order, would be a larger source size or lifetime than a similar hadronic system. At current AGS energies, we attempt to form a quark- gluon plasma by achieving a high baryon density for a period of time in the center of the collision region. For a given density threshold, the size of this high density region should be a strong function of the impact parameter: the more central the event, the larger the high density region. Therefore, one possible signature of a quark-gluon plasma would be a sudden change in system lifetime or size as a function of the centrality of the collision. In this talk we present an intriguing effect which was not predicted for simple hadronic systems: a rapid increase of the HBT-measured source radius parameter for pion pairs with increasing centrality for Au-Au collisions at a beam momentum of 11.45 A GeV/c on a fixed target. Experience has shown, however, that we must be cautious in our interpretation. A complete understanding of the collision dynamics at a given energy must be built up from several measurements and new, but conventional, hadronic explanations must be considered for such unexpected effects. More study is needed, therefore, before any strong conclusions can be reached.

  15. Herringbone and triangular patterns of dislocations in Ag, Au, and AgAu alloy films on Ru(0001).

    SciTech Connect

    Thayer, Gayle Echo; de la Figuera, Juan; Bartelt, Norman Charles; Carter, C. Barrington; Hwang, R. Q.; Thurmer, Konrad; Ling, W. L.; Hamilton, John C.; McCarty, Kevin F.

    2008-10-01

    We have studied the dislocation structures that occur in films of Ag, Au, and Ag{sub 0.5}Au{sub 0.5} alloy on a Ru(0001) substrate. Monolayer (ML) films form herringbone phases while films two or more layers thick contain triangular patterns of dislocations. We use scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED) to determine how the film composition affects the structure and periodicity of these ordered structures. One layer of Ag forms two different herringbone phases depending on the exact Ag coverage and temperature. Low-energy electron microscopy (LEEM) establishes that a reversible, first-order phase transition occurs between these two phases at a certain temperature. We critically compare our 1 ML Ag structures to conflicting results from an X-ray scattering study [H. Zajonz et al., Phys. Rev. B 67 (2003) 155417]. Unlike Ag, the herringbone phases of Au and AgAu alloy are independent of the exact film coverage. For two layer films in all three systems, none of the dislocations in the triangular networks thread into the second film layer. In all three systems, the in-plane atomic spacing of the second film layer is nearly the same as in the bulk. Film composition does, however, affect the details of the two layer structures. Ag and Au films form interconnected networks of dislocations, which we refer to as 'trigons.' In 2 ML AgAu alloy, the dislocations form a different triangular network that shares features of both trigon and moire structures. Yet another well-ordered structure, with square symmetry, forms at the boundaries of translational trigon domains in 2 ML Ag films but not in Au films.

  16. Observations of high spin states in {sup 179}Au

    SciTech Connect

    Carpenter, M.P.; Ahmad, I.; Blumenthal, D.J.

    1995-08-01

    As part of a current study on the properties of the {pi} i{sub 13/2} intruder state in the A = 175-190 region, we conducted an experiment at ATLAS to observe high spin states in {sup 179}Au utilizing the reaction {sup 144}Sm({sup 40}Ar,p4n) at beam energies of 207 MeV and 215 MeV. To aid in the identification of {sup 179}Au, and to filter out the large amount of events from fission by-products, the Fragment Mass Analyzer was utilized in conjunction with ten Compton-suppression germanium detectors. In total, 11 x 10{sup 6} {gamma}-{gamma} and 4 x 10{sup 5} {gamma}-recoil events were collected. By comparing {gamma}-rays in coincidence with an A = 179 recoil mass gate and {gamma}-rays in coincidence with Au K{alpha} and K{beta} X-rays, ten {gamma}-rays were identified as belonging to {sup 179}Au. Based on {gamma}-ray coincidence relationships and on comparisons with neighboring odd-A Au nuclei, we constructed a tentative level scheme and assigned a rotational-like sequence to the {pi} i{sub 13/2} proton configuration.

  17. Au/metal oxides for low temperature CO oxidation

    SciTech Connect

    Srinivas, G.; Wright, J.; Bai, C.S.; Cook, R.

    1996-12-31

    Oxidation of carbon monoxide is important for several operations including fuel cells and carbon dioxide lasers. Room temperature CO oxidation has been investigated on a series of Au/metal oxide catalysts at conditions typical of spacecraft atmospheres; CO = 50 ppm, CO{sub 2} = 7,000 ppm, H{sub 2}O = 40% (RH) at 25{degrees}C, balance = air, and gas hourly space velocities of 7,000-60,000 hr{sup -1}. The addition of Au increases the room temperature CO oxidation activity of the metal oxides dramatically. All the Au/metal oxides deactivate during the CO oxidation reaction, especially in the presence of CO{sub 2} in the feed. The stability of the Au/metal oxide catalysts decreases in the following order: TiO{sub 2} > Fe{sub 2}O{sub 3} > NiO > Co{sub 3}O{sub 4}. The stability appears to decrease with an increase in the basicity of the metal oxides. In situ FTIR of CO adsorption on Au/TiO{sub 2} at 25{degrees}C indicates the formation of adsorbed CO, carboxylate, and carbonate species on the catalyst surface.

  18. Au nanoinjectors for electrotriggered gene delivery into the cell nucleus.

    PubMed

    Kang, Mijeong; Kim, Bongsoo

    2015-01-01

    Intracellular delivery of exogenous materials is an essential technique required for many fundamental biological researches and medical treatments. As our understanding of cell structure and function has been improved and diverse therapeutic agents with a subcellular site of action have been continuously developed, there is a demand to enhance the performance of delivering devices. Ideal intracellular delivery devices should convey various kinds of exogenous materials without deteriorating cell viability regardless of cell type and, furthermore, precisely control the location and the timing of delivery as well as the amount of delivered materials for advanced researches.In this chapter the development of a new intracellular delivery device, a nanoinjector made of a Au (gold) nanowire (a Au nanoinjector) is described in which delivery is triggered by external application of an electric pulse. As a model study, a gene was delivered directly into the nucleus of a neuroblastoma cell, and successful delivery without cell damage was confirmed by the expression of the delivered gene. The insertion of a Au nanoinjector directly into a cell can be generally applied to any kind of cell, and a high degree of surface modification of Au allows attachment of diverse materials such as proteins, small molecules, or nanoparticles as well as genes on Au nanoinjectors. This expands their applicability, and it is expected that they will provide important information on the effects of delivered exogenous materials and consequently contribute to the development of related therapeutic or clinical technologies.

  19. Extraordinary epitaxial alignment of graphene islands on Au(111)

    NASA Astrophysics Data System (ADS)

    Wofford, Joseph M.; Starodub, Elena; Walter, Andrew L.; Nie, Shu; Bostwick, Aaron; Bartelt, Norman C.; Thürmer, Konrad; Rotenberg, Eli; McCarty, Kevin F.; Dubon, Oscar D.

    2012-05-01

    Pristine, single-crystalline graphene displays a unique collection of remarkable electronic properties that arise from its two-dimensional, honeycomb structure. Using in situ low-energy electron microscopy, we show that when deposited on the (111) surface of Au carbon forms such a structure. The resulting monolayer, epitaxial film is formed by the coalescence of dendritic graphene islands that nucleate at a high density. Over 95% of these islands can be identically aligned with respect to each other and to the Au substrate. Remarkably, the dominant island orientation is not the better lattice-matched 30° rotated orientation but instead one in which the graphene [01] and Au [011] in-plane directions are parallel. The epitaxial graphene film is only weakly coupled to the Au surface, which maintains its reconstruction under the slightly p-type doped graphene. The linear electronic dispersion characteristic of free-standing graphene is retained regardless of orientation. That a weakly interacting, non-lattice matched substrate is able to lock graphene into a particular orientation is surprising. This ability, however, makes Au(111) a promising substrate for the growth of single crystalline graphene films.

  20. Polarization properties of fluorescent BSA protected Au25 nanoclusters.

    PubMed

    Raut, Sangram; Chib, Rahul; Rich, Ryan; Shumilov, Dmytro; Gryczynski, Zygmunt; Gryczynski, Ignacy

    2013-04-21

    BSA protected gold nanoclusters (Au25) are attracting a great deal of attention due to their unique spectroscopic properties and possible use in biophysical applications. Although there are reports on synthetic strategies, spectroscopy and applications, little is known about their polarization behavior. In this study, we synthesized the BSA protected Au25 nanoclusters and studied their steady state and time resolved fluorescence properties including polarization behavior in different solvents: glycerol, propylene glycol and water. We demonstrated that the nanocluster absorption spectrum can be separated from the extinction spectrum by subtraction of Rayleigh scattering. The nanocluster absorption spectrum is well approximated by three Gaussian components. By a comparison of the emissions from BSA Au25 clusters and rhodamine B in water, we estimated the quantum yield of nanoclusters to be higher than 0.06. The fluorescence lifetime of BSA Au25 clusters is long and heterogeneous with an average value of 1.84 μs. In glycerol at -20 °C the anisotropy is high, reaching a value of 0.35. However, the excitation anisotropy strongly depends on the excitation wavelengths indicating a significant overlap of the different transition moments. The anisotropy decay in water reveals a correlation time below 0.2 μs. In propylene glycol the measured correlation time is longer and the initial anisotropy depends on the excitation wavelength. BSA Au25 clusters, due to long lifetime and high polarization, can potentially be used in studying large macromolecules such as protein complexes with large molecular weight.

  1. Synthesis and characterization of Ni-Au bimetallic nanoparticles

    NASA Astrophysics Data System (ADS)

    Nik Roselina, N. R.; Azizan, A.; Hyie, Koay Mei; Murad, Mardziah Che; Abdullah, Abdul Hakim

    2015-04-01

    Bimetallic structure of nanoparticles is of great interest due to their extraordinary properties, especially in combining the specialty of the core and its shell. This work reports the effect of pH on the synthesis of Ni-Au (nickel-gold) bimetallic nanoparticles. The synthesis involves a two-step process where Ni nanoparticles were first synthesized using polyol method with hydrazine as the reducing agent. This was followed by the process of reducing AuCl4- to Au in the solution containing pre-prepared Ni to form Ni-Au bimetallic nanoparticles using sodium citrate as the reducing agent. The results obtained from Transmission Electron Microscopy (TEM) show that the process can possibly produce either core-shell structure, or mixture of Ni and Au nanoparticles. Magnetic property of core-shell structure investigated using Vibrating Sample Magnetometer (VSM) demonstrated typical characteristic of ferromagnetic with an increased magnetization as compared to Ni nanoparticles. The saturation magnetization (Ms) and coercivity (Hc) were obtained as 19.1 emu/g and 222.3 Oe, respectively.

  2. The Brown Dwarf Desert at 75-1200 AU

    NASA Astrophysics Data System (ADS)

    McCarthy, C.; Zuckerman, B.

    2004-05-01

    We present results of a comprehensive infrared coronagraphic search for substellar companions to nearby stars. The research consisted of (1) a 178-star survey at Steward and Lick observatories, with optical follow-up from Keck Observatory, capable of detecting companions with masses greater than 30 MJ, and semimajor axes between about 140 to 1200 AU; (2) a 102-star survey using the Keck Telescope, capable of detecting extrasolar brown dwarfs and planets typically more massive than 10 MJ, with semimajor axes between about 75 and 300 AU. Only one brown dwarf companion was detected, and no planets. The frequency of brown dwarf companions to G, K, and M stars orbiting between 75 and 300 AU is measured to be 1%+/-1%, the most precise measurement of this quantity to date. The frequency of massive (greater than 30 MJ) brown dwarf companions at 120-1200 AU is found to be f=0.7%+/-0.7%. The frequency of giant planet companions with masses between 5 and 10 MJ orbiting between 75 and 300 AU is measured here for the first time to be no more than ~3%. Together with other surveys that encompass a wide range of orbital separations, these results imply that substellar objects with masses between 12 and 75 MJ form only rarely as companions to stars. Theories of star formation that could explain these data are only now beginning to emerge.

  3. The Brown Dwarf Desert at 75-1200 AU

    NASA Astrophysics Data System (ADS)

    McCarthy, C.; Zuckerman, B.

    2004-05-01

    We present results of a comprehensive infrared coronagraphic search for substellar companions to nearby stars. The research consisted of: 1.) a 178 star survey at Steward and Lick Observatories, with optical followup from Keck Observatory, capable of detecting companions with masses greater than 30 MJupiter, and semi-major axes between about 140 to 1200 AU. 2.) a 102 star survey using the Keck telescope, capable of detecting extrasolar brown dwarfs and planets typically more massive than 10 MJupiter, with semi-major axes between about 75 and 300 AU. Only one brown dwarf companion was detected, and zero planets. The frequency of brown dwarf companions to G, K & M stars orbiting between 75 and 300 AU is measured to be 1±1%, the most precise measurement of this quantity to date. The frequency of massive (> 30MJupiter) brown dwarf companions at 120-1200 AU is found to be 0.7±0.7%. The frequency of giant planet companions with masses between 5 and 10 MJupiter orbiting between 75 and 300 AU is measured here for the first time to be no more than ˜ 3%. Together with other surveys that encompass a wide range of orbital separations, these results imply that substellar objects with masses between 12 and 75 MJupiter form only rarely as companions to stars. Theories of star formation which could explain these data are only now beginning to emerge. We acknowledge support from NASA Astrobiology Institute.

  4. HELIUM ION ANISOTROPIES IN COROTATING INTERACTION REGIONS AT 1 AU

    SciTech Connect

    Ebert, R. W.; Desai, M. I.; Dayeh, M. A.; Mason, G. M.

    2012-08-01

    We investigated the first-order flow anisotropies in the solar wind frame of {approx}0.06-0.95 MeV nucleon{sup -1} He ions during three corotating interaction region (CIR)-associated particle intensity enhancements observed at 1 AU by Wind, examining CIRs with (1) a reverse shock, (2) a well-formed compression region, and (3) a weak compression region. We identified anti-sunward flows in the compression region downstream of the CIR trailing edge in the events with a reverse shock and well-formed compression that transitioned to sunward flows across and upstream of this boundary. These observations suggest that the trailing edge is organizing the He ion flows and is a local source for the particles in these events, this source being inside 1 AU prior to the trailing edge arrival and beyond 1 AU after its passage. The event with the weak compression region had predominantly sunward flows throughout, indicating that the source of the He ions was beyond 1 AU. These observations provide compelling evidence that He ions at 1 AU can be accelerated to suprathermal energies at the CIR trailing edge in events where the compression region is well formed.

  5. Structure of SiAu16: Can a silicon atom be stabilized in a gold cage?

    NASA Astrophysics Data System (ADS)

    Sun, Qiang; Wang, Qian; Chen, Gang; Jena, Puru

    2007-12-01

    Nanostructures of Au and Si as well as Au-Si hybrid structures are topics of great current interest from both scientific and technological points of view. Recent discovery of Au clusters having fullerenelike geometries and the possibility of endohedral complexes with Si atoms inside the Au cage opens new possibilities for designing Au-Si nanostructures. Using ab initio simulated annealing method we have examined the stability of Si -Au16 endohedral complex. Contrary to what we believed, we find that the endohedral configuration is metastable and the structure where Si atom binds to the exterior surface of the Au16 cage is the lowest energy structure. The bonding of Si to Au cluster mimics its behavior of that in bulk and liquid phase of Au. In addition, doping of Si in high concentration would cause fracture and embrittlement in gold nanostructures just as it does in the bulk phase. Covalent bonding between Au-Au and Au-Si is found to be a dominant feature in the stability of the Au-Si nanostructures. Our study provides insight that may be useful in fabricating hybrid Au-Si nanostructures for applications microelectronics, catalysis, biomedine, and jewelry industry.

  6. Study on antibacterial activity of chemically synthesized PANI-Ag-Au nanocomposite

    NASA Astrophysics Data System (ADS)

    Boomi, Pandi; Prabu, Halliah Gurumallesh; Manisankar, Paramasivam; Ravikumar, Sundaram

    2014-05-01

    Pristine polyaniline (PANI), PANI-Ag, PANI-Au and PANI-Ag-Au nanocomposites have been successfully synthesized by chemical oxidative polymerization method using aniline as monomer, ammonium persulphate as oxidant and metal (Ag, Au and Ag-Au) colloids. UV-Vis analysis exhibited surface Plasmon resonances of Ag, Au, Ag-Au nanoparticles. FT-IR spectra revealed the shift in peak position of N-H stretching. X-ray diffraction (XRD) results confirm the presence of Ag, Au and Au-Ag nanoparticles. HR-TEM images show nanosizes of Ag, Au, Ag-Au and the incorporation of such nanoparticles into the PANI matrix. Pristine PANI, PANI-Ag, PANI-Au and PANI-Ag-Au nanocomposites were tested for antibacterial activity by agar well diffusion method. PANI-Ag-Au nanocomposite exhibited higher antibacterial activity against both gram-positive [Streptococcus sp. (MTCC 890), Staphylococcus sp. (MTCC 96)] and gram-negative bacteria [Escherichia coli (MTCC 1671) and Klebsiella sp. (MTCC 7407)] when compared with PANI-Ag nanocomposite, PANI-Au nanocomposite and pristine PANI. The novelty of this study is the polymer-bimetal synthesis and its antibacterial potential.

  7. 2-Thiopheneacetic acid directed synthesis of Au nanorosette as an SERS-active substrate.

    PubMed

    Shin, Hye-Seon; Hong, Jin-Yeon; Huh, Seong

    2013-02-01

    Rosette-like nanoscale Au materials were simply prepared through one-pot reduction of the AuCl₄⁻ precursor by 2-thiopheneacetic acid (2-TAA) without extra surface capping ligands at room temperature. 2-TAA underwent polymerization into polythiophene derivatives while the AuCl₄⁻ precursor was simultaneously reduced into various Au nanostructures. In situ generated polythiophene derivatives played a significant role of surface passivation in guiding the shape of Au nanostructures. The morphology of Au nanostructures was strongly dependent on the molar ratio of 2-TAA to AuCl₄⁻. At lower [2-TAA]/[AuCl₄⁻] ratios, uniform rosette-like Au microparticles consisting of 30-nm-thick Au nanoplates were observed. The Au nanoplates had either triangular prismatic or hexagonal geometry with many defects. Uniform Au nanorosettes could be easily deposited on the Si substrate by drop-casting and were subsequently used as highly active SERS substrates for the detection of methylene blue and crystal violet by Raman spectroscopy. Upon increasing the ratio of [2-TAA]/[AuCl₄⁻], Au nanoparticles or nanorods heavily surrounded with polythiophene polymers were obtained. PMID:23336301

  8. Atomic and electronic structures of Si(1 1 1)-(√3 x √3)R30°-Au and (6 × 6)-Au surfaces.

    PubMed

    Patterson, C H

    2015-12-01

    Si(1 1 1)-Au surfaces with around one monolayer of Au exhibit many ordered structures and structures containing disordered domain walls. Hybrid density functional theory (DFT) calculations presented here reveal the origin of these complex structures and tendency to form domain walls. The conjugate honeycomb chain trimer (CHCT) structure of the [Formula: see text]-Au phase contains Si atoms with non-bonding surface states which can bind Au atoms in pairs in interstices of the CHCT structure and make this surface metallic. Si adatoms adsorbed on the [Formula: see text]-Au surface induce a gapped surface through interaction with the non-bonding states. Adsorption of extra Au atoms in interstitial sites of the [Formula: see text]-Au surface is stabilized by interaction with the non-bonding orbitals and leads to higher coverage ordered structures including the [Formula: see text]-Au phase. Extra Au atoms bound in interstitial sites of the [Formula: see text]-Au surface result in top layer Si atoms with an SiAu4 butterfly wing configuration. The structure of a [Formula: see text]-Au phase, whose in-plane top atomic layer positions were previously determined by an electron holography technique (Grozea et al 1998 Surf. Sci. 418 32), is calculated using total energy minimization. The Patterson function for this structure is calculated and is in good agreement with data from an in-plane x-ray diffraction study (Dornisch et al 1991 Phys. Rev. B 44 11221). Filled and empty state scanning tunneling microscopy (STM) images are calculated for domain walls and the [Formula: see text]-Au structure. The [Formula: see text]-Au phase is 2D chiral and this is evident in computed and actual STM images. [Formula: see text]-Au and domain wall structures contain the SiAu4 motif with a butterfly wing shape. Chemical bonding within the Si-Au top layers of the [Formula: see text]-Au and [Formula: see text]-Au surfaces is analyzed and an explanation for the SiAu4 motif structure is given.

  9. Level densities and thermodynamical properties of Pt and Au isotopes

    NASA Astrophysics Data System (ADS)

    Giacoppo, F.; Bello Garrote, F. L.; Bernstein, L. A.; Bleuel, D. L.; Eriksen, T. K.; Firestone, R. B.; Görgen, A.; Guttormsen, M.; Hagen, T. W.; Kheswa, B. V.; Klintefjord, M.; Koehler, P. E.; Larsen, A. C.; Nyhus, H. T.; Renstrøm, T.; Sahin, E.; Siem, S.; Tornyi, T.

    2014-11-01

    The nuclear level densities of Pt-196194 and Au,198197 below the neutron separation energy have been measured using transfer and scattering reactions. All the level density distributions follow the constant-temperature description. Each group of isotopes is characterized by the same temperature above the energy threshold corresponding to the breaking of the first Cooper pair. A constant entropy excess Δ S =1.9 kB and 1.1 kB is observed in 195Pt and 198Au with respect to 196Pt and 197Au, respectively, giving information on the available single-particle level space for the last unpaired valence neutron. The breaking of nucleon Cooper pairs is revealed by sequential peaks in the microcanonical caloric curve.

  10. Controlled electrodeposition of Au monolayer film on ionic liquid

    NASA Astrophysics Data System (ADS)

    Ma, Qiang; Pang, Liuqing; Li, Man; Zhang, Yunxia; Ren, Xianpei; Liu, Shengzhong Frank

    2016-05-01

    Gold (Au) nanoparticles have been attractive for centuries for their vibrant appearance enhanced by their interaction with sunlight. Nowadays, there have been tremendous research efforts to develop them for high-tech applications including therapeutic agents, sensors, organic photovoltaics, medical applications, electronics and catalysis. However, there remains to be a challenge to fabricate a monolayer Au coating with complete coverage in controlled fashion. Here we present a facile method to deposit a uniform Au monolayer (ML) film on the [BMIM][PF6] ionic liquid substrate using an electrochemical deposition process. It demonstrates that it is feasible to prepare a solid phase coating on the liquid-based substrate. Moreover, the thickness of the monolayer coating can be controlled to a layer-by-layer accuracy.

  11. Single-crystalline octahedral Au-Ag nanoframes.

    PubMed

    Hong, Xun; Wang, Dingsheng; Cai, Shuangfei; Rong, Hongpan; Li, Yadong

    2012-11-01

    We report the formation of single-crystalline octahedral Au-Ag nanoframes by a modified galvanic replacement reaction. Upon sequential addition of AgNO(3), CuCl, and HAuCl(4) to octadecylamine solution, truncated polyhedral silver nanoparticles formed first and then changed into octahedral Au-Ag nanoframes, without requiring a conventional Ag removal step with additional oxidation etchant. The nanoframes have 12 sides, and all of the eight {111} faces are empty. The side grows along the [110] direction, and the diameter is less than 10 nm. The selective gold deposition on the high-energy (110) surface, the diffusion, and the selective redeposition of Au and Ag atoms are the key reasons for the formation of octahedral nanoframes.

  12. Enhancing the reactivity of gold: Nanostructured Au(111) adsorbs CO

    NASA Astrophysics Data System (ADS)

    Hoffmann, F. M.; Hrbek, J.; Ma, S.; Park, J. B.; Rodriguez, J. A.; Stacchiola, D. J.; Senanayake, S. D.

    2016-08-01

    Low-coordinated sites are surface defects whose presence can transform a surface of inert or noble metal such as Au into an active catalyst. Starting with a well-ordered Au(111) surface we prepared by ion sputtering gold surfaces modified by pits, used microscopy (STM) for their structural characterization and CO spectroscopy (IRAS and NEXAFS) for probing reactivity of surface defects. In contrast to the Au(111) surface CO adsorbs readily on the pitted surfaces bonding to low-coordinated sites identified as step atoms forming {111} and {100} microfacets. Pitted nanostructured surfaces can serve as interesting and easily prepared models of catalytic surfaces with defined defects that offer an attractive alternative to vicinal surfaces or nanoparticles commonly employed in catalysis science.

  13. Enhancing the reactivity of gold: Nanostructured Au(111) adsorbs CO

    DOE PAGESBeta

    Hoffmann, F. M.; Hrbek, J.; Ma, S.; Park, J. B.; Rodriguez, J. A.; Stacchiola, D. J.; Senanayake, S. D.

    2015-12-02

    Low-coordinated sites are surface defects whose presence can transform a surface of inert or noble metal such as Au into an active catalyst. We prepared gold surfaces modified by pits, starting with a well-ordered Au(111) surface; we then used microscopy (STM) for their structural characterization and CO spectroscopy (IRAS and NEXAFS) for probing reactivity of surface defects. In contrast to the Au(111) surface CO adsorbs readily on the pitted surfaces bonding to low-coordinated sites identified as step atoms forming {111} and {100} microfacets. Finally, pitted nanostructured surfaces can serve as interesting and easily prepared models of catalytic surfaces with definedmore » defects that offer an attractive alternative to vicinal surfaces or nanoparticles commonly employed in catalysis science.« less

  14. Enhancing the reactivity of gold: Nanostructured Au(111) adsorbs CO

    SciTech Connect

    Hoffmann, F. M.; Hrbek, J.; Ma, S.; Park, J. B.; Rodriguez, J. A.; Stacchiola, D. J.; Senanayake, S. D.

    2015-12-02

    Low-coordinated sites are surface defects whose presence can transform a surface of inert or noble metal such as Au into an active catalyst. We prepared gold surfaces modified by pits, starting with a well-ordered Au(111) surface; we then used microscopy (STM) for their structural characterization and CO spectroscopy (IRAS and NEXAFS) for probing reactivity of surface defects. In contrast to the Au(111) surface CO adsorbs readily on the pitted surfaces bonding to low-coordinated sites identified as step atoms forming {111} and {100} microfacets. Finally, pitted nanostructured surfaces can serve as interesting and easily prepared models of catalytic surfaces with defined defects that offer an attractive alternative to vicinal surfaces or nanoparticles commonly employed in catalysis science.

  15. Nucleation-Suppressed Phase Stabilization in Fe–Au Nanoparticles

    SciTech Connect

    Mukherjee, P.; Jiang, Xiujuan; Wu, Yaqiao; Kramer, Matthew J.; Shield, J. E.

    2013-10-18

    Four nanoparticle compositions, Fe–21, 35, 47, and 67 at. % Au, have been prepared to study the phase stability and solid-state transformation in confined Fe–Au nanoalloys. The formation of two phases, predicted from bulk thermodynamics, has been suppressed in all compositions. Instead, a single phase solid solution forms after heat treatment at 600 °C and slow cooling. However, bulk phase relationships, signified by the precipitation of α-Fe upon cooling, was observed in larger particles (>20 nm) with composition Fe–35 at. % Au. The suppression of the phase transformation/precipitation in small particles is explained thermodynamically, as the free energy decrease associated with the phase transformation does not exceed the increase in energy due to the introduction of an interphase interface (grain boundary) within the cluster. A general equation has been derived to predict the critical cluster size below which transformations are inhibited, which agrees well with the observed experimental results.

  16. Fabrication of Au/Ni Multilayered Nanowires by Electrochemical Deposition

    NASA Astrophysics Data System (ADS)

    Saidin, N. U.; Kok, K. Y.; Ng, I. K.; Ilias, S. H.

    2013-04-01

    Electrochemical deposition of Au/Ni multilayered nanowires using template-assisted growth technique from electrolyte containing nickel chloride and gold solution was studied in details. 60 μm-thick anodized aluminum oxide (AAO) with pore diameter of 200 nm was used as the template. Chronopotentiometry experiments were first carried out to determine the deposition conditions and the growth rate of individual Au and Ni layers. Scanning electron microscopy results revealed that the pore channels of AAO were completely filled with Au/Ni multisegmented nanowires. By selectively removing the Ni segments in the multilayered nanowires, high-yield of pure gold nanorods were obtained. Detailed studies on the nanostructures obtained were carried out using various microscopy and probe-based techniques for structural, morphological and chemical characterizations.

  17. Influence of the S-Au Bond Strength on the Magnetic Behavior of S-Capped Au Nanoparticles

    NASA Astrophysics Data System (ADS)

    Vázquez, María J. Rodríguez; Rivas, José; López-Quintela, M. Arturo; Mosquera, Antonio Mouriño; Torneiro, Mercedes

    Recently, large permanent atomic magnetic moments have been found in Au nanoparticles capped with thiols. It is assumed that the formation of localized Au-S bonds at the particle surface induces the damping of the surface plasmon resonance and the appearance of a ferromagnetic-like behavior. In this work we will show for the first time that thioethers can also induce both phenomena, i.e., the damping of the plasmon band and the appearance of permanent magnetic moments. Furthermore, we have studied the influence of the Au-S bond strength on both phenomena using two different synthesized thioether ligands. It will be shown that, although both ligands can induce a complete damping of the plasmon band, only with one of the ligands (the one corresponding to the stronger S-Au bond) the appearance of a ferromagnetic-like order is observed. This is an indication of the extreme sensitivity of the magnetism on the strength of the charge transfer at the S-Au bond.

  18. Measurement of direct photons in Au+Au collisions at √(s(NN))=200 GeV.

    PubMed

    Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Al-Jamel, A; Alexander, J; Aoki, K; Aphecetche, L; Armendariz, R; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bauer, F; Bazilevsky, A; Belikov, S; Bennett, R; Berdnikov, Y; Bjorndal, M T; Boissevain, J G; Borel, H; Boyle, K; Brooks, M L; Brown, D S; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Campbell, S; Chai, J-S; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Chujo, T; Cianciolo, V; Cleven, C R; Cobigo, Y; Cole, B A; Comets, M P; Connors, M; Constantin, P; Csanád, M; Csörgő, T; Dahms, T; Das, K; David, G; Delagrange, H; Denisov, A; d'Enterria, D; Deshpande, A; Desmond, E J; Dietzsch, O; Dion, A; Drachenberg, J L; Drapier, O; Drees, A; Dubey, A K; Durum, A; Dzhordzhadze, V; Efremenko, Y V; Egdemir, J; Enokizono, A; En'yo, H; Espagnon, B; Esumi, S; Fields, D E; Fleuret, F; Fokin, S L; Forestier, B; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fukao, Y; Fung, S-Y; Gadrat, S; Gastineau, F; Germain, M; Glenn, A; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Grosse Perdekamp, M; Gunji, T; Gustafsson, H-Å; Hachiya, T; Hadj Henni, A; Haggerty, J S; Hagiwara, M N; Hamagaki, H; Harada, H; Hartouni, E P; Haruna, K; Harvey, M; Haslum, E; Hasuko, K; Hayano, R; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hiejima, H; Hill, J C; Hobbs, R; Holmes, M; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hur, M G; Ichihara, T; Iinuma, H; Imai, K; Imrek, J; Inaba, M; Isenhower, D; Isenhower, L; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Jacak, B V; Jia, J; Jin, J; Jinnouchi, O; Johnson, B M; Joo, K S; Jouan, D; Kajihara, F; Kametani, S; Kamihara, N; Kaneta, M; Kang, J H; Kawagishi, T; Kazantsev, A V; Kelly, S; Khanzadeev, A; Kim, D J; Kim, E; Kim, Y-S; Kinney, E; Kiss, A; Kistenev, E; Kiyomichi, A; Klein-Boesing, C; Kochenda, L; Kochetkov, V; Komkov, B; Konno, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kunde, G J; Kurihara, N; Kurita, K; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Lajoie, J G; Lebedev, A; Le Bornec, Y; Leckey, S; Lee, D M; Lee, M K; Leitch, M J; Leite, M A L; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Maguire, C F; Makdisi, Y I; Malakhov, A; Malik, M D; Manko, V I; Masui, H; Matathias, F; McCain, M C; McGaughey, P L; Miake, Y; Miller, T E; Milov, A; Mioduszewski, S; Mishra, G C; Mitchell, J T; Morrison, D P; Moss, J M; Moukhanova, T V; Mukhopadhyay, D; Murata, J; Nagamiya, S; Nagata, Y; Nagle, J L; Naglis, M; Nakamura, T; Newby, J; Nguyen, M; Norman, B E; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Omiwade, O O; Oskarsson, A; Otterlund, I; Ozawa, K; Pak, R; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, J; Park, W J; Pate, S F; Pei, H; Peng, J-C; Pereira, H; Peresedov, V; Peressounko, D Yu; Pinkenburg, C; Pisani, R P; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosendahl, S S E; Rosnet, P; Rukoyatkin, P; Rykov, V L; Ryu, S S; Sahlmueller, B; Saito, N; Sakaguchi, T; Sakai, S; Samsonov, V; Sato, H D; Sato, S; Sawada, S; Semenov, V; Seto, R; Sharma, D; Shea, T K; Shein, I; Shibata, T-A; Shigaki, K; Shimomura, M; Shohjoh, T; Shoji, K; Sickles, A; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Skutnik, S; Smith, W C; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Suire, C; Sullivan, J P; Sziklai, J; Tabaru, T; Takagi, S; Takagui, E M; Taketani, A; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Taranenko, A; Tarján, P; Thomas, T L; Togawa, M; Tojo, J; Torii, H; Towell, R S; Tram, V-N; Tserruya, I; Tsuchimoto, Y; Tuli, S K; Tydesjö, H; Tyurin, N; Vale, C; Valle, H; van Hecke, H W; Velkovska, J; Vértesi, R; Vinogradov, A A; Vznuzdaev, E; Wagner, M; Wang, X R; Watanabe, Y; Wessels, J; White, S N; Willis, N; Winter, D; Woody, C L; Wysocki, M; Xie, W; Yanovich, A; Yokkaichi, S; Young, G R; Younus, I; Yushmanov, I E; Zajc, W A; Zaudtke, O; Zhang, C; Zimányi, J; Zolin, L

    2012-10-12

    We report the measurement of direct photons at midrapidity in Au+Au collisions at √(s(NN))=200 GeV. The direct photon signal was extracted for the transverse momentum range of 4 GeV/cAu+Au collision centralities using the measured p+p direct photon spectrum and compared to theoretical predictions. R(AA) was found to be consistent with unity for all centralities over the entire measured p(T) range. Theoretical models that account for modifications of initial direct photon production due to modified parton distribution functions in Au and the different isospin composition of the nuclei predict a modest change of R(AA) from unity. They are consistent with the data. Models with compensating effects of the quark-gluon plasma on high-energy photons, such as suppression of jet-fragmentation photons and induced-photon bremsstrahlung from partons traversing the medium, are also consistent with this measurement. PMID:23102300

  19. Nonideality of Au/Si and Au/GaAs Schottky barriers due to process-induced defects

    NASA Astrophysics Data System (ADS)

    Maeda, Keiji

    2006-06-01

    A mechanism of local lowering of the Schottky barrier height (SBH) is proposed, which causes nonideality in nearly ideal Au/ n-Si and Au/ n-GaAs Schottky barriers. Positively ionized defects generated by the process very close to the interface induce electrons in the metal-induced gap states (MIGS) and lower the SBH locally. The spatial density distribution of the ionized defects obtained from the SBH distribution is determined by the unique interaction with the MIGS. The defects are considered to have the negative-U property and are neutralized at very close positions to the MIGS. The potential distributions close to the interface have a considerable potential drop due to the large defect density. These inhomogeneous potentials are coincident with the energy level scheme of the defect identified as the defect causing the nonideality. This defect is Si self-interstitial in Au/Si SB, and As antisite in Au/ n-GaAs SB. This MIGS with process-induced defect model supersedes the previously proposed two major Fermi level pinning models. The mystery of the T0 effect is solved. The thermionic-field emission current taking place in the strong electric field has influence on the I- V characteristics at low temperatures. Regarding the C- V characteristics of Au/Si SB, the observed extra capacitance under the forward bias is an experimental evidence in accordance with the proposed model.

  20. Measurement of direct photons in Au+Au collisions at √(s(NN))=200 GeV.

    PubMed

    Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Al-Jamel, A; Alexander, J; Aoki, K; Aphecetche, L; Armendariz, R; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bauer, F; Bazilevsky, A; Belikov, S; Bennett, R; Berdnikov, Y; Bjorndal, M T; Boissevain, J G; Borel, H; Boyle, K; Brooks, M L; Brown, D S; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Campbell, S; Chai, J-S; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Chujo, T; Cianciolo, V; Cleven, C R; Cobigo, Y; Cole, B A; Comets, M P; Connors, M; Constantin, P; Csanád, M; Csörgő, T; Dahms, T; Das, K; David, G; Delagrange, H; Denisov, A; d'Enterria, D; Deshpande, A; Desmond, E J; Dietzsch, O; Dion, A; Drachenberg, J L; Drapier, O; Drees, A; Dubey, A K; Durum, A; Dzhordzhadze, V; Efremenko, Y V; Egdemir, J; Enokizono, A; En'yo, H; Espagnon, B; Esumi, S; Fields, D E; Fleuret, F; Fokin, S L; Forestier, B; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fukao, Y; Fung, S-Y; Gadrat, S; Gastineau, F; Germain, M; Glenn, A; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Grosse Perdekamp, M; Gunji, T; Gustafsson, H-Å; Hachiya, T; Hadj Henni, A; Haggerty, J S; Hagiwara, M N; Hamagaki, H; Harada, H; Hartouni, E P; Haruna, K; Harvey, M; Haslum, E; Hasuko, K; Hayano, R; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hiejima, H; Hill, J C; Hobbs, R; Holmes, M; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hur, M G; Ichihara, T; Iinuma, H; Imai, K; Imrek, J; Inaba, M; Isenhower, D; Isenhower, L; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Jacak, B V; Jia, J; Jin, J; Jinnouchi, O; Johnson, B M; Joo, K S; Jouan, D; Kajihara, F; Kametani, S; Kamihara, N; Kaneta, M; Kang, J H; Kawagishi, T; Kazantsev, A V; Kelly, S; Khanzadeev, A; Kim, D J; Kim, E; Kim, Y-S; Kinney, E; Kiss, A; Kistenev, E; Kiyomichi, A; Klein-Boesing, C; Kochenda, L; Kochetkov, V; Komkov, B; Konno, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kunde, G J; Kurihara, N; Kurita, K; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Lajoie, J G; Lebedev, A; Le Bornec, Y; Leckey, S; Lee, D M; Lee, M K; Leitch, M J; Leite, M A L; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Maguire, C F; Makdisi, Y I; Malakhov, A; Malik, M D; Manko, V I; Masui, H; Matathias, F; McCain, M C; McGaughey, P L; Miake, Y; Miller, T E; Milov, A; Mioduszewski, S; Mishra, G C; Mitchell, J T; Morrison, D P; Moss, J M; Moukhanova, T V; Mukhopadhyay, D; Murata, J; Nagamiya, S; Nagata, Y; Nagle, J L; Naglis, M; Nakamura, T; Newby, J; Nguyen, M; Norman, B E; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Omiwade, O O; Oskarsson, A; Otterlund, I; Ozawa, K; Pak, R; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, J; Park, W J; Pate, S F; Pei, H; Peng, J-C; Pereira, H; Peresedov, V; Peressounko, D Yu; Pinkenburg, C; Pisani, R P; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosendahl, S S E; Rosnet, P; Rukoyatkin, P; Rykov, V L; Ryu, S S; Sahlmueller, B; Saito, N; Sakaguchi, T; Sakai, S; Samsonov, V; Sato, H D; Sato, S; Sawada, S; Semenov, V; Seto, R; Sharma, D; Shea, T K; Shein, I; Shibata, T-A; Shigaki, K; Shimomura, M; Shohjoh, T; Shoji, K; Sickles, A; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Skutnik, S; Smith, W C; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Suire, C; Sullivan, J P; Sziklai, J; Tabaru, T; Takagi, S; Takagui, E M; Taketani, A; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Taranenko, A; Tarján, P; Thomas, T L; Togawa, M; Tojo, J; Torii, H; Towell, R S; Tram, V-N; Tserruya, I; Tsuchimoto, Y; Tuli, S K; Tydesjö, H; Tyurin, N; Vale, C; Valle, H; van Hecke, H W; Velkovska, J; Vértesi, R; Vinogradov, A A; Vznuzdaev, E; Wagner, M; Wang, X R; Watanabe, Y; Wessels, J; White, S N; Willis, N; Winter, D; Woody, C L; Wysocki, M; Xie, W; Yanovich, A; Yokkaichi, S; Young, G R; Younus, I; Yushmanov, I E; Zajc, W A; Zaudtke, O; Zhang, C; Zimányi, J; Zolin, L

    2012-10-12

    We report the measurement of direct photons at midrapidity in Au+Au collisions at √(s(NN))=200 GeV. The direct photon signal was extracted for the transverse momentum range of 4 GeV/cAu+Au collision centralities using the measured p+p direct photon spectrum and compared to theoretical predictions. R(AA) was found to be consistent with unity for all centralities over the entire measured p(T) range. Theoretical models that account for modifications of initial direct photon production due to modified parton distribution functions in Au and the different isospin composition of the nuclei predict a modest change of R(AA) from unity. They are consistent with the data. Models with compensating effects of the quark-gluon plasma on high-energy photons, such as suppression of jet-fragmentation photons and induced-photon bremsstrahlung from partons traversing the medium, are also consistent with this measurement.

  1. Final Technical Report: First Principles Investigations for the Ensemble Effects of PdAu and PtAu Bimetallic Nanocatalysts

    SciTech Connect

    Ruqian Wu

    2012-05-18

    Bimetallic surfaces with tunable chemical properties have attracted broad attention in recent years due to their ample potential for heterogeneous catalysis applications. The local chemical properties of constituents are strongly altered from their parent metals by 'ligand effect', a term encompassing the influences of charge transfer, orbital rehybridization and lattice strain. In comparison to the aforementioned, the 'ensemble effect' associated with particular arrangements of the active constituents have received much less attention, despite their notable importance towards the determination of reactivity and selectivity of bimetallic catalysts. We performed theoretical studies for understanding the ensemble effects on bimetallic catalysis: (i) simulations for the formation of different ensembles on PdAu and PtAu nanoclusters; (ii) studies of the size, shape, and substrate dependence of their electronic properties; and (iii) simulations for model reactions such as CO oxidation, methanol, ethylene and water dehydrogenation on PdAu and PtAu nanoclusters. In close collaboration with leading experimental groups, our theoretical research elucidated the fundamentals of Au based bimetallic nanocatalysts.

  2. Formation of one-dimensional Ag-Au solid solution colloids with Au nanorods as seeds, their alloying mechanisms, and surface plasmon resonances.

    PubMed

    Guo, Tao; Tan, Yiwei

    2013-01-21

    In this work, one dimensional (1D) Ag-Au solid solution nanoalloys were synthesized by rapidly diffusing Ag into the preformed Au nanorod (AuNR) seeds at ambient temperature in aqueous solution. By varying the molar ratio of AgCl/AuNR (in gold atoms), two kinds of 1D Ag-Au alloy nanostructures with a narrow size distribution--AgAu nanowires and Ag(33)Au(67) nanorods--could be obtained in high yields when NaCl and polyvinylpyrrolidone (PVP) were used as an additive and capping reagent, respectively. Based on HRTEM imaging combined with a series of control experiments, it is conceivable that vacancy/defect-motivated interdiffusion of Ag and Au atoms coupled with oxidative etching is a crucial stage in the mechanism responsible for this room-temperature alloying process, and the subsequent conjugation of the fused Ag-Au alloyed nanostructures is associated with the formation of the AgAu nanowires. The resulting 1D Ag-Au nanoalloys form stable colloidal dispersions and show unique localized surface plasmon resonance (LSPR) peaks in the ensemble extinction spectra.

  3. Common suppression pattern of eta and pi0 mesons at high transverse momentum in Au + Au collisions at square root S(NN) = 200 GeV.

    PubMed

    Adler, S S; Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Alexander, J; Amirikas, R; Aphecetche, L; Aronson, S H; Averbeck, R; Awes, T C; Azmoun, R; Babintsev, V; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bazilevsky, A; Belikov, S; Berdnikov, Y; Bhagavatula, S; Boissevain, J G; Borel, H; Borenstein, S; Brooks, M L; Brown, D S; Bruner, N; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Camard, X; Chai, J-S; Chand, P; Chang, W C; Chernichenko, S; Chi, C Y; Chiba, J; Chiu, M; Choi, I J; Choi, J; Choudhury, R K; Chujo, T; Cianciolo, V; Cobigo, Y; Cole, B A; Constantin, P; d'Enterria, D; David, G; Delagrange, H; Denisov, A; Deshpande, A; Desmond, E J; Devismes, A; Dietzsch, O; Drapier, O; Drees, A; du Rietz, R; Durum, A; Dutta, D; Efremenko, Y V; Chenawi, K El; Enokizono, A; En'yo, H; Esumi, S; Ewell, L; Fields, D E; Fleuret, F; Fokin, S L; Fox, B D; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fung, S-Y; Garpman, S; Ghosh, T K; Glenn, A; Gogiberidze, G; Gonin, M; Gosset, J; Goto, Y; de Cassagnac, R Granier; Grau, N; Greene, S V; Perdekamp, M Grosse; Guryn, W; Gustafsson, H-A; Hachiya, T; Haggerty, J S; Hamagaki, H; Hansen, A G; Hartouni, E P; Harvey, M; Hayano, R; Hayashi, N; He, X; Heffner, M; Hemmick, T K; Heuser, J M; Hibino, M; Hiejima, H; Hill, J C; Holzmann, W; Homma, K; Hong, B; Hoover, A; Ichihara, T; Ikonnikov, V V; Imai, K; Isenhower, D; Ishihara, M; Issah, M; Isupov, A; Jacak, B V; Jang, W Y; Jeong, Y; Jia, J; Jinnouchi, O; Johnson, B M; Johnson, S C; Joo, K S; Jouan, D; Kametani, S; Kamihara, N; Kang, J H; Kapoor, S S; Katou, K; Kelly, S; Khachaturov, B; Khanzadeev, A; Kikuchi, J; Kim, D H; Kim, D J; Kim, D W; Kim, E; Kim, G-B; Kim, H J; Kistenev, E; Kiyomichi, A; Kiyoyama, K; Klein-Boesing, C; Kobayashi, H; Kochenda, L; Kochetkov, V; Koehler, D; Kohama, T; Kopytine, M; Kotchetkov, D; Kozlov, A; Kroon, P J; Kuberg, C H; Kurita, K; Kuroki, Y; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Ladygin, V; Lajoie, J G; Lebedev, A; Leckey, S; Lee, D M; Lee, S; Leitch, M J; Li, X H; Lim, H; Litvinenko, A; Liu, M X; Liu, Y; Maguire, C F; Makdisi, Y I; Malakhov, A; Manko, V I; Mao, Y; Martinez, G; Marx, M D; Masui, H; Matathias, F; Matsumoto, T; McGaughey, P L; Melnikov, E; Messer, F; Miake, Y; Milan, J; Miller, T E; Milov, A; Mioduszewski, S; Mischke, R E; Mishra, G C; Mitchell, J T; Mohanty, A K; Morrison, D P; Moss, J M; Mühlbacher, F; Mukhopadhyay, D; Muniruzzaman, M; Murata, J; Nagamiya, S; Nagle, J L; Nakamura, T; Nandi, B K; Nara, M; Newby, J; Nilsson, P; Nyanin, A S; Nystrand, J; O'Brien, E; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, K; Ono, M; Onuchin, V; Oskarsson, A; Otterlund, I; Oyama, K; Ozawa, K; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, J; Parmar, A; Pate, S F; Peitzmann, T; Peng, J-C; Peresedov, V; Pinkenburg, C; Pisani, R P; Plasil, F; Purschke, M L; Purwar, A K; Rak, J; Ravinovich, I; Read, K F; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosnet, P; Ryu, S S; Sadler, M E; Sahlmueller, B; Saito, N; Sakaguchi, T; Sakai, M; Sakai, S; Samsonov, V; Sanfratello, L; Santo, R; Sato, H D; Sato, S; Sawada, S; Schutz, Y; Semenov, V; Seto, R; Shaw, M R; Shea, T K; Shibata, T-A; Shigaki, K; Shiina, T; Silva, C L; Silvermyr, D; Sim, K S; Singh, C P; Singh, V; Sivertz, M; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Sullivan, J P; Takagui, E M; Taketani, A; Tamai, M; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Tarján, P; Tepe, J D; Thomas, T L; Tojo, J; Torii, H; Towell, R S; Tserruya, I; Tsuruoka, H; Tuli, S K; Tydesjö, H; Tyurin, N; van Hecke, H W; Velkovska, J; Velkovsky, M; Veszprémi, V; Villatte, L; Vinogradov, A A; Volkov, M A; Vznuzdaev, E; Wang, X R; Watanabe, Y; White, S N; Wohn, F K; Woody, C L; Xie, W; Yang, Y; Yanovich, A; Yokkaichi, S; Young, G R; Yushmanov, I E; Zajc, W A; Zhang, C; Zhou, S; Zhou, S J; Zolin, L

    2006-05-26

    Inclusive transverse momentum spectra of eta mesons have been measured within p(T) = 2-10 GeV/c at midrapidity by the PHENIX experiment in Au + Au collisions at square root S(NN) = 200 GeV. In central Au+Au the eta yields are significantly suppressed compared to peripheral Au + Au, d + Au, and p + p yields scaled by the corresponding number of nucleon-nucleon collisions. The magnitude, centrality, and p(T) dependence of the suppression is common, within errors, for eta and pi0. The ratio of eta to pi0 spectra at high p(T) amounts to 0.40 < R(eta/pi)0 < 0.48 for the three systems, in agreement with the world average measured in hadronic and nuclear reactions and, at large scaled momentum, in e+e- collisions.

  4. Using bond-length-dependent transferable force constants to predict vibrational entropies in Au-Cu, Au-Pd, and Cu-Pd alloys

    NASA Astrophysics Data System (ADS)

    Wu, Eric J.; Ceder, Gerbrand; van de Walle, Axel

    2003-04-01

    A model is tested to rapidly evaluate the vibrational properties of alloys with site disorder. It is shown that length-dependent transferable force constants exist and can be used to accurately predict the vibrational entropy of substitutionally ordered and disordered structures in Au-Cu, Au-Pd, and Cu-Pd. For each relevant force constant, a length-dependent function is determined and fitted to force constants obtained from first-principles pseudopotential calculations. We show that these transferable force constants can accurately predict vibrational entropies of L12-ordered and disordered phases in Cu3Au, Au3Pd, Pd3Au, Cu3Pd, and Pd3Au. In addition, we calculate the vibrational entropy difference between L12-ordered and disordered phases of Au3Cu and Cu3Pt.

  5. The coupled geochemistry of Au and As in pyrite from hydrothermal ore deposits

    NASA Astrophysics Data System (ADS)

    Deditius, Artur P.; Reich, Martin; Kesler, Stephen E.; Utsunomiya, Satoshi; Chryssoulis, Stephen L.; Walshe, John; Ewing, Rodney C.

    2014-09-01

    The ubiquity of Au-bearing arsenian pyrite in hydrothermal ore deposits suggests that the coupled geochemical behaviour of Au and As in this sulfide occurs under a wide range of physico-chemical conditions. Despite significant advances in the last 20 years, fundamental factors controlling Au and As ratios in pyrite from ore deposits remain poorly known. Here we explore these constraints using new and previously published EMPA, LA-ICP-MS, SIMS, and μ-PIXE analyses of As and Au in pyrite from Carlin-type Au, epithermal Au, porphyry Cu, Cu-Au, and orogenic Au deposits, volcanogenic massive sulfide (VHMS), Witwatersrand Au, iron oxide copper gold (IOCG), and coal deposits. Pyrite included in the data compilation formed under temperatures from ∼30 to ∼600 °C and in a wide variety of geological environments. The pyrite Au-As data form a wedge-shaped zone in compositional space, and the fact that most data points plot below the solid solubility limit defined by Reich et al. (2005) indicate that Au1+ is the dominant form of Au in arsenian pyrite and that Au-bearing ore fluids that deposit this sulfide are mostly undersaturated with respect to native Au. The analytical data also show that the solid solubility limit of Au in arsenian pyrite defined by an Au/As ratio of 0.02 is independent of the geochemical environment of pyrite formation and rather depends on the crystal-chemical properties of pyrite and post-depositional alteration. Compilation of Au-As concentrations and formation temperatures for pyrite indicates that Au and As solubility in pyrite is retrograde; Au and As contents decrease as a function of increasing temperature from ∼200 to ∼500 °C. Based on these results, two major Au-As trends for Au-bearing arsenian pyrite from ore deposits are defined. One trend is formed by pyrites from Carlin-type and orogenic Au deposits where compositions are largely controlled by fluid-rock interactions and/or can be highly perturbed by changes in temperature and

  6. Reduced graphene oxide supported Au nanoparticles as an efficient catalyst for aerobic oxidation of benzyl alcohol

    NASA Astrophysics Data System (ADS)

    Yu, Xianqin; Huo, Yujia; Yang, Jing; Chang, Sujie; Ma, Yunsheng; Huang, Weixin

    2013-09-01

    Various Au/C catalysts were prepared by Au nanoparticels supported on different carbonaceous supports including reduced graphene oxide (RGO), activated carbon (AC) and graphite (GC) using sol-immobilization method. Au/RGO shows a much higher activity than Au/AC and Au/GC in the liquid phase aerobic oxidation of benzyl alcohol. The superior catalytic performance of Au/RGO may be related to the presence of surface O-containing functional groups and moderate graphite character of RGO supports.

  7. Hexagonal-diamond-like gold lattices, Ba and (Au,T)3 interstitials, and delocalized bonding in a family of intermetallic phases Ba2Au6(Au,T)3 (T = Zn, Cd, Ga, In, or Sn).

    PubMed

    Lin, Qisheng; Mishra, Trinath; Corbett, John D

    2013-07-31

    Au-rich polar intermetallics exhibit a wide variety of structural motifs, and this hexagonal-diamond-like gold host is unprecedented. The series Ba2Au6(Au,T)3 (T = Zn, Cd, Ga, In, or Sn), synthesized through fusion of the elements at 700-800 °C followed by annealing at 400-500 °C, occur in space group R3[overline]c (a ≈ 8.6-8.9 Å, c ≈ 21.9-22.6 Å, and Z = 6). Their remarkable structure, generated by just three independent atoms, features a hexagonal-diamond-like gold superstructure in which tunnels along the 3-fold axes are systematically filled by interstitial Ba atoms (blue) and triangles of disordered (Au,T)3 atoms (green) in 2:1 proportions. The Au/Zn mixing in the latter spans ~34 to 87% Zn, whereas the Au/Sn result is virtually invariant compositionally. Complementary bonding between the gold lattice and the disordered (Au,T)3 units is substantial and very regular. Bonding and charge density analyses indicate delocalized bonding within the gold host and the (Au,T)3 triangular units, and moderately polarized bonding between Ba and the electronegative framework. The new structure can also be viewed empirically as the result of an atom-by-triad [i.e., Ba by (Au,T)3 triangle] topological substitution in a BaAu2 (AlB2-type) superstructure.

  8. Collisional modelling of the AU Microscopii debris disc

    NASA Astrophysics Data System (ADS)

    Schüppler, Ch.; Löhne, T.; Krivov, A. V.; Ertel, S.; Marshall, J. P.; Wolf, S.; Wyatt, M. C.; Augereau, J.-C.; Metchev, S. A.

    2015-09-01

    AU Microscopii's debris disc is one of the most famous and best-studied debris discs and one of only two resolved debris discs around M stars. We perform in-depth collisional modelling of the AU Mic disc including stellar radiative and corpuscular forces (stellar winds), aiming at a comprehensive understanding of the dust production and the dust and planetesimal dynamics in the system. Our models are compared to a suite of observational data for thermal and scattered light emission, ranging from the ALMA radial surface brightness profile at 1.3 mm to spatially resolved polarisation measurements in the visible. Most of the data are shown to be reproduced with dust production in a belt of planetesimals with an outer edge at around 40 au and subsequent inward transport of dust by stellar winds. A low dynamical excitation of the planetesimals with eccentricities up to 0.03 is preferred. The radial width of the planetesimal belt cannot be constrained tightly. Belts that are 5 au and 17 au wide, as well as a broad 44 au-wide belt, are consistent with observations. All models show surface density profiles that increase with distance from the star up to ≈40 au, as inferred from observations. The best model is achieved by assuming a stellar mass loss rate that exceeds the solar one by a factor of 50. The models reproduce the spectral energy distribution and the shape of the ALMA radial profile well, but deviate from the scattered light observations more strongly. The observations show a bluer disc colour and a lower degree of polarisation for projected distances <40 au than predicted by the models. These deviations may be reduced by taking irregularly shaped dust grains which have scattering properties different from the Mie spheres used in this work. From tests with a handful of selected dust materials, we favour mixtures of silicate, carbon, and ice of moderate porosity. We also address the origin of the unresolved central excess emission detected by ALMA and show that

  9. Photocatalytic Au-Bi2S3 heteronanostructures.

    PubMed

    Manna, Goutam; Bose, Riya; Pradhan, Narayan

    2014-06-23

    Au-Bi2S3 heteronanostructure photocatalysts were designed in which the coupling of a metal plasmon and a semiconductor exciton aids the absorption of solar light, enhances charge separation, and results in improved catalytic activity. Furthermore, these nanostructures show a unique pattern of structural combination, with Au nanoparticles positioned at the center of Bi2S3 nanorods. The chemistry of formation of these nanostructures, their epitaxy at the junction, and their photoconductance were studied, as well as their photoresponse properties. PMID:24844409

  10. Light nuclei production in relativistic Au+nucleus collisions

    SciTech Connect

    Bennett, M. J.; Pope, J. K.; Beavis, D.; Carroll, J. B.; Chiba, J.; Chikanian, A.; Crawford, H. J.; Cronqvist, M.; Dardenne, Y.; Kumar, B. S.; Nagle, J. L.; Debbe, R.; Doke, T.; Engelage, J.; Greiner, L.; Hayano, R S; Hallman, Timothy J.; Heckman, H. H.; Kashiwagi, T.; Kikuchi, J.; Tanaka, K. H.; Kumar, B. S.; Kuo, C.; Lindstrom, P. J.; Mitchell, J. W.; Nagle, J. L.; Stankus, P.; Tanaka, K. H.; Welsh, R. C.; Zhan, W.

    1998-08-01

    We have measured the yields of protons and A=2-4 nuclei in collisions between 10.8 A GeV/ c Au beams and targets of Al, Cu, and Au. The data, which cover a broad rapidity range at low transverse momenta, were measured as a function of collision centrality using a focusing beam line spectrometer and a high-rate centrality detector. We investigate the dependence of coalescence parameters on event geometry. The data are compared with the predictions of an RQMD+coalescence model. {copyright} {ital 1998} {ital The American Physical Society}

  11. Nanoshells made easy: improving Au layer growth on nanoparticle surfaces.

    PubMed

    Brinson, Bruce E; Lassiter, J Britt; Levin, Carly S; Bardhan, Rizia; Mirin, Nikolay; Halas, Naomi J

    2008-12-16

    The growth of a continuous, uniform Au layer on a dielectric nanoparticle is the critical step in the synthesis of nanoparticles such as nanoshells or nanorice, giving rise to their unique geometry-dependent plasmon resonant properties. Here, we report a novel, streamlined method for Au layer metallization on prepared nanoparticle surfaces using carbon monoxide as the reducing agent. This approach consistently yields plasmonic nanoparticles with highly regular shell layers and is immune to variations in precursor or reagent preparation. Single particle spectroscopy combined with scanning electron microscopy reveal that thinner, more uniform shell layers with correspondingly red-shifted optical resonances are achievable with this approach. PMID:19360963

  12. Effect of tautomerism on Au-6-mercaptopurine nanocluster stability

    NASA Astrophysics Data System (ADS)

    Rashidpour, Neda; Kashid, Vikas; Shah, Vaishali

    2013-02-01

    We have investigated the stability of conjugated nanoparticles of Au-6-Mercaptopurine (6-MP) using ab initio density functional theory. We have studied the conjugation of the 6 tautomers of 6-MP via the different atomic sites with the gold nanoparticles. Our results show that the least stable tautomer has the strongest adsorption with the Au nanoparticles whereas the most stable tautomer has the weakest adsorption. We will discuss our results to explain the experimentally observed increased plasma half life time of the conjugated drug in vitro.

  13. Beyond 3 AU from the Sun: "Hypervolatiles" in Distant Comets

    NASA Astrophysics Data System (ADS)

    Bonev, Boncho P.; Villanueva, Geronimo Luis; Mumma, Michael J.; DiSanti, Michael A.; Paganini, Lucas; Boehnhardt, Hermann; Lippi, Manuela; Gibb, Erika L.; Bockelee-Morvan, Dominique; de Val-Borro, Miguel; Kawakita, Hideyo; Altwegg, Kathrin

    2016-10-01

    Our understanding of inner coma composition in comets has long been biased towards heliocentric distances (Rh) smaller than 2-3 AU. However, observations far from the Sun are also of high value for better understanding the nucleus structure and outgassing of volatiles. Substantial and very important evidence for the activity of distant comets has been accumulated from photometry and analyses of light curves, but direct detections of primary (parent) volatiles are still rare. For example, comet C/2006 W3 (Christensen) remained outside 3.1 AU throughout its apparition, yet it presented the best opportunity since Hale-Bopp (1997) for detailed spectroscopic studies in a distant comet. C/2006 W3 was observed from several space- and ground-based facilities using both infrared and radio techniques. CO, CH4, and C2H6 were measured via infrared spectroscopy at ESO-VLT at Rh = 3.25 AU. Production rates were found to exceed those measured for each of these species in most other comets, despite those comets being observed much closer to the Sun. With its relatively high CO/CO2 ratio, C/2006 W3 also appears as an outlier in the AKARI comet survey of 18 comets. The detections of H2O (Herschel Space Observatory) and CO (ESO-VLT) allow for constraining the coma abundance ratio H2O/CO at Rh = 5 AU.We will compare the C2H6/CH4/CO ratios in C/2006 W3 with those in other comets spanning a large range in Rh: from D/2012 S1 ISON (~0.7 AU) to 29P/Schwassmann-Wachmann 1 (~ 6.3 AU). Notably in situ measurements by the Rosetta mission were performed in the coma of 67P/Churyumov-Gerasimenko, at a very similar heliocentric distance to C/2006 W3 (3.15 AU). While comparisons of column-integrated remote sensing measurements and abundances from in-situ mass spectrometry (as performed by the ROSINA instrument) are not straightforward, both types of measurement are of high value for constraining models of nucleus outgassing beyond 3 AU from the Sun, where the inferred nucleus structure and

  14. Rational design and synthesis of excavated trioctahedral Au nanocrystals

    NASA Astrophysics Data System (ADS)

    Chen, Qiaoli; Jia, Yanyan; Shen, Wei; Xie, Shuifen; Yang, Yanan; Cao, Zhenming; Xie, Zhaoxiong; Zheng, Lansun

    2015-06-01

    Excavated polyhedral nanostructures, possessing the features of high surface area and well-defined surface structure with a specific crystal facet and avoidance of aggregation, could be one of the best choices for the purpose of reducing consumption and improving performance of noble metals in many application fields. However, the formation of the excavated structures is thermodynamically unfavourable and its rational synthesis is far beyond our knowledge. In this work, taking overgrowth of Pd onto trioctahedral Au nanocrystals as a model, we present a deep insight study for synthesizing an excavated structure relying on the protection role of surfactants under suitable crystal growth kinetics. Based on the abovementioned understanding, we designed a simple and effective strategy to synthesize Au nanocrystals with excavated trioctahedral structure in one step. Due to the novel feature of the excavated structure and exposed high energy {110} facets, excavated trioctahedral Au NCs exhibited optical extinction at the near-infrared region and showed high catalytic activity towards the reduction of p-nitrophenol. Moreover, the synthetic strategy can be extended to the synthesis of excavated Au-Pd alloys.Excavated polyhedral nanostructures, possessing the features of high surface area and well-defined surface structure with a specific crystal facet and avoidance of aggregation, could be one of the best choices for the purpose of reducing consumption and improving performance of noble metals in many application fields. However, the formation of the excavated structures is thermodynamically unfavourable and its rational synthesis is far beyond our knowledge. In this work, taking overgrowth of Pd onto trioctahedral Au nanocrystals as a model, we present a deep insight study for synthesizing an excavated structure relying on the protection role of surfactants under suitable crystal growth kinetics. Based on the abovementioned understanding, we designed a simple and effective

  15. Atomic Structure of Au 329 (SR) 84 Faradaurate Plasmonic Nanomolecules

    SciTech Connect

    Kumara, Chanaka; Zuo, Xiaobing; Ilavsky, Jan; Cullen, David A.; Dass, Amala

    2015-05-21

    To design novel nanomaterials, it is important to precisely control the composition, determine the atomic structure, and manipulate the structure to tune the materials property. Here we present a comprehensive characterization of the material whose composition is Au329(SR)84 precisely, therefore referred to as a nanomolecule. The size homogeneity was shown by electron microscopy, solution X-ray scattering, and mass spectrometry. We proposed its atomic structure to contain the Au260 core using experiments and modeling of a total-scattering-based atomic-pair distribution functional analysis. HAADF- STEM images shows fcc-like 2.0 ± 0.1 nm diameter nanomolecules.

  16. Atomic Structure of Au329(SR)84 Faradaurate Plasmonic Nanomolecules

    DOE PAGESBeta

    Kumara, Chanaka; Zuo, Xiaobing; Ilavsky, Jan; Cullen, David; Dass, Amala

    2015-04-03

    To design novel nanomaterials, it is important to precisely control the composition, determine the atomic structure, and manipulate the structure to tune the materials property. Here we present a comprehensive characterization of the material whose composition is Au329(SR)84 precisely, therefore referred to as a nanomolecule. The size homogeneity was shown by electron microscopy, solution X-ray scattering, and mass spectrometry. We proposed its atomic structure to contain the Au260 core using experiments and modeling of a total-scattering-based atomic-pair distribution functional analysis. HAADF-STEM images shows fcc-like 2.0 ± 0.1 nm diameter nanomolecules.

  17. Self-assembly of flagellin on Au(111) surfaces.

    PubMed

    González Orive, Alejandro; Pissinis, Diego E; Diaz, Carolina; Miñán, Alejandro; Benítez, Guillermo A; Rubert, Aldo; Daza Millone, Antonieta; Rumbo, Martin; Hernández Creus, Alberto; Salvarezza, Roberto C; Schilardi, Patricia L

    2014-11-01

    The adsorption of flagellin monomers from Pseudomonas fluorescens on Au(111) has been studied by Atomic Force Microscopy (AFM), Scanning Tunneling Microscopy (STM), X-ray Photoelectron Spectroscopy (XPS), Surface Plasmon Resonance (SPR), and electrochemical techniques. Results show that flagellin monomers spontaneously self-assemble forming a monolayer thick protein film bounded to the Au surface by the more hydrophobic subunit and exposed to the environment the hydrophilic subunit. The films are conductive and allow allocation of electrochemically active cytochrome C. The self-assembled films could be used as biological platforms to build 3D complex molecular structures on planar metal surfaces and to functionalize metal nanoparticles.

  18. Graphene nanoribbons synthesized from molecular precursor polymerization on Au(110)

    SciTech Connect

    Massimi, Lorenzo; Ourdjini, Oualid; Della Pia, Ada; Mariani, Carlo; Betti, Maria Grazia; Cavaliere, Emanuele; Gavioli, Luca

    2015-06-23

    A spectroscopic study of 10,10-dibromo-9,9 bianthracene (DBBA) molecules deposited on the Au(110) surface is presented, by means of ultraviolet and X-ray photoemission, and X-ray absorption spectroscopy. Through a thermally activated procedure, these molecular precursors polymerize and eventually form graphene nanoribbons (GNRs) with atomically controlled shape and width, very important building blocks for several technological applications. The GNRs observed by scanning tunneling microscopy (STM) appear as short segments on top of the gold surface reconstruction, pointing out the delicate balance among surface diffusion and surface corrugation in their synthesis on the Au(110) surface.

  19. Self-assembly of flagellin on Au(111) surfaces.

    PubMed

    González Orive, Alejandro; Pissinis, Diego E; Diaz, Carolina; Miñán, Alejandro; Benítez, Guillermo A; Rubert, Aldo; Daza Millone, Antonieta; Rumbo, Martin; Hernández Creus, Alberto; Salvarezza, Roberto C; Schilardi, Patricia L

    2014-11-01

    The adsorption of flagellin monomers from Pseudomonas fluorescens on Au(111) has been studied by Atomic Force Microscopy (AFM), Scanning Tunneling Microscopy (STM), X-ray Photoelectron Spectroscopy (XPS), Surface Plasmon Resonance (SPR), and electrochemical techniques. Results show that flagellin monomers spontaneously self-assemble forming a monolayer thick protein film bounded to the Au surface by the more hydrophobic subunit and exposed to the environment the hydrophilic subunit. The films are conductive and allow allocation of electrochemically active cytochrome C. The self-assembled films could be used as biological platforms to build 3D complex molecular structures on planar metal surfaces and to functionalize metal nanoparticles. PMID:25112916

  20. Nuclear Shadowing and Select d+Au Observables

    NASA Astrophysics Data System (ADS)

    Adeluyi, Adeola; Fai, George

    2007-04-01

    Much of the complexity of the description of d+Au collisions in the framework of perturbative Quantum Chromodynamics (pQCD) derives from effects of the nuclear environment. Here we investigate the effects of the most recent available nuclear shadowing parametrization, the Hirai-Kumano-Nagai (HKN) nuclear parton distribution functions (nPDFs) and the updated Albino-Kniehl-Kramer (AKK) fragmentation functions on three select d+Au collision observables. We compare our results to available experimental data from the STAR and BRAHMS collaborations.

  1. Museums, the Public, and Public Value

    ERIC Educational Resources Information Center

    Scott, Carol

    2010-01-01

    Though adopting a Public Value orientation to guide museum planning and positioning has advantages, its implementation, particularly with regard to the role of the public, is complex. Here, the terrain of Public Value is emergent, fluid and contested. This paper examines various views of the role of the public in Public Value including that of…

  2. Gold chloride clusters with Au(III) and Au(I) probed by FT-ICR mass spectrometry and MP2 theory.

    PubMed

    Lemke, Kono H

    2014-05-01

    Microsolvated clusters of gold chloride are probed by electrospray ionization mass spectrometry (ESI-MS) and scalar relativistic electronic structure calculations. Electrospray ionization of aqueous AuCl3 leads to mononuclear clusters of types [AuCl2](+)(H2O)n (n = 0-4), [AuOHCl](+)(H2O)n (n = 0-1) and [AuCl2](+)(HCl)2(H2O)n (n = 0-4). In addition, strong ion signals due to dinuclear [Au2Cl5-xOHx](+)(H2O)n (x = 0-1) are present in ESI mass spectra of aqueous AuCl3, with the abundance of individual dinuclear species controlled by the concentration-dependent variation of the precursor complexes [AuCl2-xOHx](+)(H2O)n and AuCl3. Equilibrium structures, energies and thermodynamic properties of mono- and dinuclear gold clusters have been predicted using MP2 and CCSD(T) theory, and these data have been applied to examine the influence of microsolvation on cluster stability. Specifically, results from CCSD(T) calculations indicate that non-covalently bound ion-neutral complexes Au(+)(Cl2)(H2O)n, with formal Au(I), are the dominant forms of mononuclear gold with n = 0-2, while higher hydrates (n > 2) are covalently bound [AuCl2](+)(H2O)n complexes in which gold exists as Au(III). MP2 calculations show that the lowest energy structure of dinuclear gold is an ion-molecule cluster [Au2Cl(Cl2)2](+) consisting of a single-bridged digold-chloronium ion bound end-on to two dichlorine ligands, with two higher energy isomers, single-bridged [Au2Cl3(Cl2)](+) and double-bridged [Au2Cl5](+) clusters. Finally, AuAu interactions in the singly-bridged clusters [Au2Cl(Cl2)2](+)(H2O)n and [Au2Cl3(Cl2)](+)(H2O)n are examined employing a wide range of computational tools, including natural bond order (NBO) analysis and localized orbital locator (LOL) profiles. PMID:24643288

  3. Interfacial electronic properties of the heterojunctions C{sub 60}/rubrene/Au and rubrene/C{sub 60}/Au

    SciTech Connect

    Cheng, Chiu-Ping; Chan, Yi-Wei; Hsueh, Chih-Feng; Pi, Tun-Wen

    2012-07-15

    Using synchrotron-radiation photoemission, we have studied the electronic structures of rubrene:C{sub 60} heterojunctions on Au substrates. The photoelectron spectra show that the interfacial properties at the C{sub 60}/rubrene/Au and rubrene/C{sub 60}/Au interfaces are asymmetric and do not follow the commutation rule. In the C{sub 60}/rubrene case, a gap state appearing in the initial deposition stage results from negative charges transferred from rubrene to C{sub 60}, while in the inverse deposition process, no strong chemical reaction could be found. A significant shift of the vacuum level induced by alignment of the charge neutrality levels of the two materials was observed in both cases. Furthermore, the charge transfer strongly enhances the dipole potential of the C{sub 60}/rubrene interface. The energy level diagrams show that the C{sub 60}-on-rubrene process has a superior number of advantages in the photovoltaic applications.

  4. Dihadron Azimuthal Correlations in Au+Au Collisions at s_NN = 200 GeV

    SciTech Connect

    Adare, A.; Awes, Terry C; Cianciolo, Vince; Efremenko, Yuri; Read Jr, Kenneth F; Silvermyr, David O; Sorensen, Soren P; Stankus, Paul W; Young, Glenn R; PHENIX, Collaboration

    2008-01-01

    Azimuthal angle ({Delta}{sup {phi}}) correlations are presented for a broad range of transverse momentum (0.4 < p{sub T} < 10 GeV/c) and centrality (0-92%) selections for charged hadrons from dijets in Au+Au collisions at {radical} s{sub NN} = 200 GeV. With increasing p{sub T}, the away-side {Delta}{sup {phi}} distribution evolves from a broad and relatively flat shape to a concave shape, then to a convex shape. Comparisons with p+p data suggest that the away-side distribution can be divided into a partially suppressed 'head' region centered at {Delta}{sup {phi}} {approx} {pi}, and an enhanced 'shoulder' region centered at {Delta}{sup {phi}} {approx} {pi} {+-} 1.1. The p{sub T} spectrum for the associated hadrons in the head region softens toward central collisions. The spectral slope for the shoulder region is independent of centrality and trigger p{sub T}. The properties of the near-side distributions are also modified relative to those in p+p collisions, reflected by the broadening of the jet shape in {Delta}{sup {phi}} and {Delta}{sup {eta}}, and an enhancement of the per-trigger yield. However, these modifications seem to be limited to p{sub T} {approx}< 4 GeV/c, above which both the hadron pair shape and per-trigger yield become similar to p+p collisions. These observations suggest that both the away- and near-side distributions contain a jet fragmentation component which dominates for p{sub T} {approx}> 5 GeV/c and a medium-induced component which is important for p{sub T} {approx}< 4 GeV/c. We also quantify the role of jets at intermediate and low p{sub T} through the yield of jet-induced pairs in comparison with binary scaled p+p pair yield. The yield of jet-induced pairs is suppressed at high pair proxy energy (sum of the p{sub T} magnitudes of the two hadrons) and is enhanced at low pair proxy energy. The former is consistent with jet quenching; the latter is consistent with the enhancement of soft hadron pairs due to transport of lost energy to lower p

  5. Synthesis and electrocatalytic activity of Au/Pt bimetallic nanodendrites for ethanol oxidation in alkaline medium.

    PubMed

    Han, Xinyi; Wang, Dawei; Liu, Dong; Huang, Jianshe; You, Tianyan

    2012-02-01

    Gold/Platinum (Au/Pt) bimetallic nanodendrites were successfully synthesized through seeded growth method using preformed Au nanodendrites as seeds and ascorbic acid as reductant. Cyclic voltammograms (CVs) of a series of Au/Pt nanodendrites modified electrodes in 1M KOH solution containing 1M ethanol showed that the electrocatalyst with a molar ratio (Au:Pt) of 3 exhibited the highest peak current density and the lowest onset potential. The peak current density of ethanol electro-oxidation on the Au(3)Pt(1) nanodendrites modified glassy carbon electrode (Au(3)Pt(1) electrode) is about 16, 12.5, and 4.5 times higher than those on the polycrystalline Pt electrode, polycrystalline Au electrode, and Au nanodendrites modified glassy carbon electrode (Au dendrites electrode), respectively. The oxidation peak potential of ethanol electro-oxidation on the Au(3)Pt(1) electrode is about 299 and 276 mV lower than those on the polycrystalline Au electrode and Au dendrites electrode, respectively. These results demonstrated that the Au/Pt bimetallic nanodendrites may find potential application in alkaline direct ethanol fuel cells (ADEFCs).

  6. Substrate-Structure Dependence of Ag Electromigration on Au-Precovered Si(111) Surfaces

    NASA Astrophysics Data System (ADS)

    Shi, Fangxiao; Shiraki, Ichiro; Nagao, Tadaaki; Hasegawa, Shuji

    2000-07-01

    Electromigration of Ag on Au-precovered Si(111) surfaces was investigated by in-situ ultrahigh vacuum scanning electron microscopy and μ-probe reflection-high-energy electron diffraction (RHEED). Migration behaviors of a Ag-film patch strongly depended on Au coverage θAu and corresponding surface structures. When θAu<0.7 monolayer (ML), the patch expanded preferentially towards the cathode to attain a maximum area in which the sum of Ag and Au coverages were always about 1 ML irrespective of θAu, resulting in two-dimensional (2D) alloy phases (showing \\sqrt{3}×\\sqrt{3} RHEED patterns) with different Au/Ag concentration ratios. The largest expansion of the patch area was achieved on a (5× 2+α-\\sqrt{3}×\\sqrt{3})-Au mixed phase structure (θAu˜ 0.7 ML). However, when θAu>0.7 ML, the patch expansion was greatly reduced. Especially on the β-\\sqrt{3}×\\sqrt{3}-Au surface (θAu˜ 1.0 ML), the patch showed no directional expansion towards the cathode. But Ag atoms were observed to migrate inside the patches on all substrates (including the β-\\sqrt{3}×\\sqrt{3}-Au surface) to form 3D islands near terrace edges.

  7. Electronic structure of Au-Ta alloys:. An X-ray spectroscopy study

    NASA Astrophysics Data System (ADS)

    Kuhn, M.; Sammynaiken, R.; Sham, T. K.

    1998-07-01

    Au-Ta alloys with the compositions of AuTa, AuTa 2 and AuTa 3, prepared by quenching from the melt, has been studied with X-ray diffraction, photoelectron spectroscopy (XPS) and X-ray absorption near-edge structure (XANES) measurements. It was found that while AuTa 3 is a single-phase solid solution, AuTa 2 and AuTa have mixed phases and that the Au and Ta 4f levels of the alloys shift to higher binding energy, relative to the pure metal; this is accompanied by a narrowing of the Au 5d component of the alloy d-band, which moves away from the Fermi level. This observation is interpreted in terms of a charge compensation model in which Au loses d charge but is overcompensated by s-p charge gain, resulting in a small net charge flow from Ta to Au. The observed Ta 4f binding energy shift is as predicted by electronegativity and indicates charge depletion at the Ta site. The notion of d charge depletion at both Au and Ta sites upon alloying is confirmed independently by XANES measurements which showed that the L 2,3 edge whiteline intensity for both Au and Ta increases as they become more dilute in the host, indicating an increase in d hole count. The experimental results compare favorably with a recent linear-augmented Slater-type-orbital (LASTO) calculations. The implications of these results are discussed.

  8. Elliptic flow in Au+Au collisions at square root(S)NN = 130 GeV.

    PubMed

    Ackermann, K H; Adams, N; Adler, C; Ahammed, Z; Ahmad, S; Allgower, C; Amsbaugh, J; Anderson, M; Anderssen, E; Arnesen, H; Arnold, L; Averichev, G S; Baldwin, A; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Beddo, M; Bekele, S; Belaga, V V; Bellwied, R; Bennett, S; Bercovitz, J; Berger, J; Betts, W; Bichsel, H; Bieser, F; Bland, L C; Bloomer, M; Blyth, C O; Boehm, J; Bonner, B E; Bonnet, D; Bossingham, R; Botlo, M; Boucham, A; Bouillo, N; Bouvier, S; Bradley, K; Brady, F P; Braithwaite, E S; Braithwaite, W; Brandin, A; Brown, R L; Brugalette, G; Byrd, C; Caines, H; Calderón de la Barca Sánchez, M; Cardenas, A; Carr, L; Carroll, J; Castillo, J; Caylor, B; Cebra, D; Chatopadhyay, S; Chen, M L; Chen, W; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Chrin, J; Christie, W; Coffin, J P; Conin, L; Consiglio, C; Cormier, T M; Cramer, J G; Crawford, H J; Danilov, V I; Dayton, D; DeMello, M; Deng, W S; Derevschikov, A A; Dialinas, M; Diaz, H; DeYoung, P A; Didenko, L; Dimassimo, D; Dioguardi, J; Dominik, W; Drancourt, C; Draper, J E; Dunin, V B; Dunlop, J C; Eckardt, V; Edwards, W R; Efimov, L G; Eggert, T; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Etkin, A; Fachini, P; Feliciano, C; Ferenc, D; Ferguson, M I; Fessler, H; Finch, E; Fine, V; Fisyak, Y; Flierl, D; Flores, I; Foley, K J; Fritz, D; Gagunashvili, N; Gans, J; Gazdzicki, M; Germain, M; Geurts, F; Ghazikhanian, V; Gojak, C; Grabski, J; Grachov, O; Grau, M; Greiner, D; Greiner, L; Grigoriev, V; Grosnick, D; Gross, J; Guilloux, G; Gushin, E; Hall, J; Hallman, T J; Hardtke, D; Harper, G; Harris, J W; He, P; Heffner, M; Heppelmann, S; Herston, T; Hill, D; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Howe, M; Huang, H Z; Humanic, T J; Hümmler, H; Hunt, W; Hunter, J; Igo, G J; Ishihara, A; Ivanshin, Y I; Jacobs, P; Jacobs, W W; Jacobson, S; Jared, R; Jensen, P; Johnson, I; Jones, P G; Judd, E; Kaneta, M; Kaplan, M; Keane, D; Kenney, V P; Khodinov, A; Klay, J; Klein, S R; Klyachko, A; Koehler, G; Konstantinov, A S; Kormilitsyne, V; Kotchenda, L; Kotov, I; Kovalenko, A D; Kramer, M; Kravtsov, P; Krueger, K; Krupien, T; Kuczewski, P; Kuhn, C; Kunde, G J; Kunz, C L; Kutuev, R K; Kuznetsov, A A; Lakehal-Ayat, L; Lamas-Valverde, J; Lamont, M A; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lebedev, A; LeCompte, T; Leonhardt, W J; Leontiev, V M; Leszczynski, P; LeVine, M J; Li, Q; Li, Q; Li, Z; Liaw, C J; Lin, J; Lindenbaum, S J; Lindenstruth, V; Lindstrom, P J; Lisa, M A; Liu, H; Ljubicic, T; Llope, W J; LoCurto, G; Long, H; Longacre, R S; Lopez-Noriega, M; Lopiano, D; Love, W A; Lutz, J R; Lynn, D; Madansky, L; Maier, R; Majka, R; Maliszewski, A; Margetis, S; Marks, K; Marstaller, R; Martin, L; Marx, J; Matis, H S; Matulenko, Y A; Matyushevski, E A; McParland, C; McShane, T S; Meier, J; Melnick, Y; Meschanin, A; Middlekamp, P; Mikhalin, N; Miller, B; Milosevich, Z; Minaev, N G; Minor, B; Mitchell, J; Mogavero, E; Moiseenko, V A; Moltz, D; Moore, C F; Morozov, V; Morse, R; de Moura, M M; Munhoz, M G; Mutchler, G S; Nelson, J M; Nevski, P; Ngo, T; Nguyen, M; Nguyen, T; Nikitin, V A; Nogach, L V; Noggle, T; Norman, B; Nurushev, S B; Nussbaum, T; Nystrand, J; Odyniec, G; Ogawa, A; Ogilvie, C A; Olchanski, K; Oldenburg, M; Olson, D; Ososkov, G A; Ott, G; Padrazo, D; Paic, G; Pandey, S U; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Pentia, M; Perevotchikov, V; Peryt, W; Petrov, V A; Pinganaud, W; Pirogov, S; Platner, E; Pluta, J; Polk, I; Porile, N; Porter, J; Poskanzer, A M; Potrebenikova, E; Prindle, D; Pruneau, C; Puskar-Pasewicz, J; Rai, G; Rasson, J; Ravel, O; Ray, R L; Razin, S V; Reichhold, D; Reid, J; Renfordt, R E; Retiere, F; Ridiger, A; Riso, J; Ritter, H G; Roberts, J B; Roehrich, D; Rogachevski, O V; Romero, J L; Roy, C; Russ, D; Rykov, V; Sakrejda, I; Sanchez, R; Sandler, Z; Sandweiss, J; Sappenfield, P; Saulys, A C; Savin, I; Schambach, J; Scharenberg, R P; Scheblien, J; Scheetz, R; Schlueter, R; Schmitz, N; Schroeder, L S; Schulz, M; Schüttauf, A; Sedlmeir, J; Seger, J; Seliverstov, D; Seyboth, J; Seyboth, P; Seymour, R; Shakaliev, E I; Shestermanov, K E; Shi, Y; Shimanskii, S S; Shuman, D; Shvetcov, V S; Skoro, G; Smirnov, N; Smykov, L P; Snellings, R; Solberg, K; Sowinski, J; Spinka, H M; Srivastava, B; Stephenson, E J; Stock, R; Stolpovsky, A; Stone, N; Stone, R; Strikhanov, M; Stringfellow, B; Stroebele, H; Struck, C; Suaide, A A; Sugarbaker, E; Suire, C; Symons, T J; Takahashi, J; Tang, A H; Tarchini, A; Tarzian, J; Thomas, J H; Tikhomirov, V; Szanto De Toledo, A; Tonse, S; Trainor, T; Trentalange, S; Tokarev, M; Tonjes, M B; Trofimov, V; Tsai, O; Turner, K; Ullrich, T; Underwood, D G; Vakula, I; Van Buren, G; VanderMolen, A M; Vanyashin, A; Vasilevski, I M; Vasiliev, A N; Vigdor, S E; Visser, G; Voloshin, S A; Vu, C; Wang, F; Ward, H; Weerasundara, D; Weidenbach, R; Wells, R; Wells, R; Wenaus, T; Westfall, G D; Whitfield, J P; Whitten, C; Wieman, H; Willson, R; Wilson, K; Wirth, J; Wisdom, J; Wissink, S W; Witt, R; Wolf, J; Wood, L; Xu, N; Xu, Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yokosawa, A; Yurevich, V I; Zanevski, Y V; Zhang, J; Zhang, W M; Zhu, J; Zimmerman, D; Zoulkarneev, R; Zubarev, A N

    2001-01-15

    Elliptic flow from nuclear collisions is a hadronic observable sensitive to the early stages of system evolution. We report first results on elliptic flow of charged particles at midrapidity in Au+Au collisions at square root(S)NN = 130 GeV using the STAR Time Projection Chamber at the Relativistic Heavy Ion Collider. The elliptic flow signal, v2, averaged over transverse momentum, reaches values of about 6% for relatively peripheral collisions and decreases for the more central collisions. This can be interpreted as the observation of a higher degree of thermalization than at lower collision energies. Pseudorapidity and transverse momentum dependence of elliptic flow are also presented.

  9. Strong non-linear effects in the chiroptical properties of the ligand-exchanged Au38 and Au40 clusters

    NASA Astrophysics Data System (ADS)

    Knoppe, Stefan; Dass, Amala; Bürgi, Thomas

    2012-06-01

    Ligand exchange reactions on size-selected Au38(2-PET)24 and Au40(2-PET)24 clusters (2-PET: 2-phenylethylthiol) with mono- and bi-dentate chiral thiols were performed. The reactions were monitored with MALDI mass spectrometry and the arising chiroptical properties were compared to the number of incorporated chiral ligands. Only a small fraction of chiral ligands is needed to induce significant optical activity to the clusters. The use of bidentate 1,1'-binaphthyl-2,2'-dithiol (BINAS) leads to slow exchange, but the optical activity measured is strong. Moreover, a non-linear behaviour between optical activity and the number of chiral ligands is found in the BINAS case for both Au38 and Au40, which may indicate different exchange rates of enantiopure BINAS with the enantiomers of inherently chiral (but racemic) clusters. This is ascribed to effects arising from the bidentate nature of BINAS. In contrast, the use of monodentate camphor-10-thiol (CamSH) leads to comparably fast exchange on both clusters. The arising optical activity is weak. This is the first study where chiroptical effects are directly correlated with the composition of the ligand shell.Ligand exchange reactions on size-selected Au38(2-PET)24 and Au40(2-PET)24 clusters (2-PET: 2-phenylethylthiol) with mono- and bi-dentate chiral thiols were performed. The reactions were monitored with MALDI mass spectrometry and the arising chiroptical properties were compared to the number of incorporated chiral ligands. Only a small fraction of chiral ligands is needed to induce significant optical activity to the clusters. The use of bidentate 1,1'-binaphthyl-2,2'-dithiol (BINAS) leads to slow exchange, but the optical activity measured is strong. Moreover, a non-linear behaviour between optical activity and the number of chiral ligands is found in the BINAS case for both Au38 and Au40, which may indicate different exchange rates of enantiopure BINAS with the enantiomers of inherently chiral (but racemic) clusters

  10. Low frequency noise in the unstable contact region of Au-to-Au microcontact for microelectromechanical system switches

    NASA Astrophysics Data System (ADS)

    Qiu, Haodong; Wang, Hong; Ke, Feixiang

    2014-06-01

    The noise behavior of Au-to-Au microcontact for microelectromechanical system switches has been experimentally studied in the unstable contact region. The results suggest that the electrical conduction remains nonmetallic at the initial stage during contact formation due to the existence of alien films, and traps in the alien layer located at the contact interface could play an important role in determining the conduction noise. The conduction fluctuation induced by electron trapping-detrapping associated with the hydrocarbon layer is found to be an intrinsic noise source contributing to the low frequency noise in the unstable contact region.

  11. Selective-Area Growth of Thick Diamond Films Using Chemically Stable Masks of Ru/Au and Mo/Au

    NASA Astrophysics Data System (ADS)

    Nagase, Masanori; Watanabe, Katsumi; Umezawa, Hitoshi; Shikata, Shinichi

    2012-07-01

    Selective-area growth of diamond films in microwave-plasma chemical vapor deposition was performed using newly developed masks. By forming chemically stable masks made of Ru/Au or Mo/Au, which have high melting points, good adhesion to diamond, and difficulty in forming carbide compounds, patterned diamond films with a large thickness of 50 µm, a large area of 5 mm2, and a high orientation in the [001] direction were successfully grown on (001) diamond substrates without degradation of the crystal quality of masked areas.

  12. ΛΛ correlation function in Au + Au collisions at √sNN = 200 GeV

    DOE PAGESBeta

    Adamczyk, L.

    2015-01-12

    In this study, we present ΛΛ correlation measurements in heavy-ion collisions for Au+Au collisions at √sNN = 200 GeV using the STAR experiment at the Relativistic Heavy-Ion Collider (RHIC). The Lednický-Lyuboshitz analytical model has been used to fit the data to obtain a source size, a scattering length and an effective range. Implications of the measurement of the ΛΛ correlation function and interaction parameters for di-hyperon searches are discussed.

  13. ΛΛ correlation function in Au + Au collisions at √sNN = 200 GeV

    SciTech Connect

    Adamczyk, L.

    2015-01-12

    In this study, we present ΛΛ correlation measurements in heavy-ion collisions for Au+Au collisions at √sNN = 200 GeV using the STAR experiment at the Relativistic Heavy-Ion Collider (RHIC). The Lednický-Lyuboshitz analytical model has been used to fit the data to obtain a source size, a scattering length and an effective range. Implications of the measurement of the ΛΛ correlation function and interaction parameters for di-hyperon searches are discussed.

  14. Pion-Kaon correlations in central Au+Au collisions at square root [sNN] = 130 GeV.

    PubMed

    Adams, J; Adler, C; Aggarwal, M M; Ahammed, Z; Amonett, J; Anderson, B D; Anderson, M; Arkhipkin, D; Averichev, G S; Badyal, S K; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bezverkhny, B I; Bhardwaj, S; Bhaskar, P; Bhati, A K; Bichsel, H; Billmeier, A; Bland, L C; Blyth, C O; Bonner, B E; Botje, M; Boucham, A; Brandin, A; Bravar, A; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca Sánchez, M; Carroll, J; Castillo, J; Castro, M; Cebra, D; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Christie, W; Coffin, J P; Cormier, T M; Cramer, J G; Crawford, H J; Das, D; Das, S; Derevschikov, A A; Didenko, L; Dietel, T; Dong, X; Draper, J E; Du, F; Dubey, A K; Dunin, V B; Dunlop, J C; Dutta Majumdar, M R; Eckardt, V; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Fachini, P; Faine, V; Faivre, J; Fatemi, R; Filimonov, K; Filip, P; Finch, E; Fisyak, Y; Flierl, D; Foley, K J; Fu, J; Gagliardi, C A; Ganti, M S; Gutierrez, T D; Gagunashvili, N; Gans, J; Gaudichet, L; Germain, M; Geurts, F; Ghazikhanian, V; Ghosh, P; Gonzalez, J E; Grachov, O; Grigoriev, V; Gronstal, S; Grosnick, D; Guedon, M; Guertin, S M; Gupta, A; Gushin, E; Hallman, T J; Hardtke, D; Harris, J W; Heinz, M; Henry, T W; Heppelmann, S; Herston, T; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Huang, H Z; Huang, S L; Humanic, T J; Igo, G; Ishihara, A; Jacobs, P; Jacobs, W W; Janik, M; Johnson, I; Jones, P G; Judd, E G; Kabana, S; Kaneta, M; Kaplan, M; Keane, D; Kiryluk, J; Kisiel, A; Klay, J; Klein, S R; Klyachko, A; Koetke, D D; Kollegger, T; Konstantinov, A S; Kopytine, M; Kotchenda, L; Kovalenko, A D; Kramer, M; Kravtsov, P; Krueger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kunde, G J; Kunz, C L; Kutuev, R Kh; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lauret, J; Lebedev, A; Lednický, R; Leontiev, V M; LeVine, M J; Li, C; Li, Q; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, L; Liu, Z; Liu, Q J; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; Lopez-Noriega, M; Love, W A; Ludlam, T; Lynn, D; Ma, J; Ma, Y G; Magestro, D; Mahajan, S; Mangotra, L K; Mahapatra, D P; Majka, R; Manweiler, R; Margetis, S; Markert, C; Martin, L; Marx, J; Matis, H S; Matulenko, Yu A; McShane, T S; Meissner, F; Melnick, Yu; Meschanin, A; Messer, M; Miller, M L; Milosevich, Z; Minaev, N G; Mironov, C; Mishra, D; Mitchell, J; Mohanty, B; Molnar, L; Moore, C F; Mora-Corral, M J; Morozov, V; de Moura, M M; Munhoz, M G; Nandi, B K; Nayak, S K; Nayak, T K; Nelson, J M; Nevski, P; Nikitin, V A; Nogach, L V; Norman, B; Nurushev, S B; Odyniec, G; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Paic, G; Pandey, S U; Pal, S K; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Perevoztchikov, V; Peryt, W; Petrov, V A; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M; Potrebenikova, E; Potukuchi, B V K S; Prindle, D; Pruneau, C; Putschke, J; Rai, G; Rakness, G; Raniwala, R; Raniwala, S; Ravel, O; Ray, R L; Razin, S V; Reichhold, D; Reid, J G; Renault, G; Retiere, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L J; Rykov, V; Sahoo, R; Sakrejda, I; Salur, S; Sandweiss, J; Savin, I; Schambach, J; Scharenberg, R P; Schmitz, N; Schroeder, L S; Schweda, K; Seger, J; Seliverstov, D; Seyboth, P; Shahaliev, E; Shao, M; Sharma, M; Shestermanov, K E; Shimanskii, S S; Singaraju, R N; Simon, F; Skoro, G; Smirnov, N; Snellings, R; Sood, G; Sorensen, P; Sowinski, J; Spinka, H M; Srivastava, B; Stanislaus, S; Stock, R; Stolpovsky, A; Strikhanov, M; Stringfellow, B; Struck, C; Suaide, A A P; Sugarbaker, E; Suire, C; Sumbera, M; Surrow, B; Symons, T J M; Szanto de Toledo, A; Szarwas, P; Tai, A; Takahashi, J; Tang, A H; Thein, D; Thomas, J H; Tikhomirov, V; Tokarev, M; Tonjes, M B; Trainor, T A; Trentalange, S; Tribble, R E; Trivedi, M D; Trofimov, V; Tsai, O; Ullrich, T; Underwood, D G; Van Buren, G; VanderMolen, A M; Vasiliev, A N; Vasiliev, M; Vigdor, S E; Viyogi, Y P; Voloshin, S A; Waggoner, W; Wang, F; Wang, G; Wang, X L; Wang, Z M; Ward, H; Watson, J W; Wells, R; Westfall, G D; Whitten, C; Wieman, H; Willson, R; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Z; Xu, Z Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yurevich, V I; Zanevski, Y V; Zborovský, I; Zhang, H; Zhang, H Y; Zhang, W M; Zhang, Z P; Zołnierczuk, P A; Zoulkarneev, R; Zoulkarneeva, J; Zubarev, A N

    2003-12-31

    Pion-kaon correlation functions are constructed from central Au+Au STAR data taken at sqrt[s(NN)]=130 GeV by the STAR detector at the Relativistic Heavy Ion Collider (RHIC). The results suggest that pions and kaons are not emitted at the same average space-time point. Space-momentum correlations, i.e., transverse flow, lead to a space-time emission asymmetry of pions and kaons that is consistent with the data. This result provides new independent evidence that the system created at RHIC undergoes a collective transverse expansion. PMID:14754044

  15. Direct observation of dijets in central Au+Au collisions at sqrt[sNN]=200 GeV.

    PubMed

    Adams, J; Aggarwal, M M; Ahammed, Z; Amonett, J; Anderson, B D; Anderson, M; Arkhipkin, D; Averichev, G S; Bai, Y; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellingeri-Laurikainen, A; Bellwied, R; Bezverkhny, B I; Bhardwaj, S; Bhasin, A; Bhati, A K; Bichsel, H; Bielcik, J; Bielcikova, J; Bland, L C; Blyth, C O; Blyth, S-L; Bonner, B E; Botje, M; Bouchet, J; Brandin, A V; Bravar, A; Bystersky, M; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca Sánchez, M; Castillo, J; Catu, O; Cebra, D; Chajecki, Z; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, J H; Chen, Y; Cheng, J; Cherney, M; Chikanian, A; Choi, H A; Christie, W; Coffin, J P; Cormier, T M; Cosentino, M R; Cramer, J G; Crawford, H J; Das, D; Das, S; Daugherity, M; de Moura, M M; Dedovich, T G; Dephillips, M; Derevschikov, A A; Didenko, L; Dietel, T; Djawotho, P; Dogra, S M; Dong, W J; Dong, X; Draper, J E; Du, F; Dunin, V B; Dunlop, J C; Dutta Mazumdar, M R; Eckardt, V; Edwards, W R; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Fatemi, R; Fedorisin, J; Filimonov, K; Filip, P; Finch, E; Fine, V; Fisyak, Y; Fu, J; Gagliardi, C A; Gaillard, L; Gans, J; Ganti, M S; Ghazikhanian, V; Ghosh, P; Gonzalez, J E; Gorbunov, Y G; Gos, H; Grebenyuk, O; Grosnick, D; Guertin, S M; Guimaraes, K S F F; Guo, Y; Gupta, N; Gutierrez, T D; Haag, B; Hallman, T J; Hamed, A; Harris, J W; He, W; Heinz, M; Henry, T W; Hepplemann, S; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horner, M J; Huang, H Z; Huang, S L; Hughes, E W; Humanic, T J; Igo, G; Jacobs, P; Jacobs, W W; Jakl, P; Jia, F; Jiang, H; Jones, P G; Judd, E G; Kabana, S; Kang, K; Kapitan, J; Kaplan, M; Keane, D; Kechechyan, A; Khodyrev, V Yu; Kim, B C; Kiryluk, J; Kisiel, A; Kislov, E M; Klein, S R; Koetke, D D; Kollegger, T; Kopytine, M; Kotchenda, L; Kouchpil, V; Kowalik, K L; Kramer, M; Kravtsov, P; Kravtsov, V I; Krueger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; Lapointe, S; Laue, F; Lauret, J; Lebedev, A; Lednicky, R; Lee, C-H; Lehocka, S; Levine, M J; Li, C; Li, Q; Li, Y; Lin, G; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, H; Liu, J; Liu, L; Liu, Z; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; Lopez-Noriega, M; Love, W A; Lu, Y; Ludlam, T; Lynn, D; Ma, G L; Ma, J G; Ma, Y G; Magestro, D; Mahapatra, D P; Majka, R; Mangotra, L K; Manweiler, R; Margetis, S; Markert, C; Martin, L; Matis, H S; Matulenko, Yu A; McClain, C J; McShane, T S; Melnick, Yu; Meschanin, A; Miller, M L; Minaev, N G; Mioduszewski, S; Mironov, C; Mischke, A; Mishra, D K; Mitchell, J; Mohanty, B; Molnar, L; Moore, C F; Morozov, D A; Munhoz, M G; Nandi, B K; Nattrass, C; Nayak, T K; Nelson, J M; Netrakanti, P K; Nikitin, V A; Nogach, L V; Nurushev, S B; Odyniec, G; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Pachr, M; Pal, S K; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Peitzmann, T; Perevoztchikov, V; Perkins, C; Peryt, W; Petrov, V A; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Poljak, N; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M; Potrebenikova, E; Potukuchi, B V K S; Prindle, D; Pruneau, C; Putschke, J; Rakness, G; Raniwala, R; Raniwala, S; Ray, R L; Razin, S V; Reinnarth, J; Relyea, D; Retiere, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevskiy, O V; Romero, J L; Rose, A; Roy, C; Ruan, L; Russcher, M J; Sahoo, R; Sakrejda, I; Salur, S; Sandweiss, J; Sarsour, M; Sazhin, P S; Schambach, J; Scharenberg, R P; Schmitz, N; Schweda, K; Seger, J; Selyuzhenkov, I; Seyboth, P; Shabetai, A; Shahaliev, E; Shao, M; Sharma, M; Shen, W Q; Shimanskiy, S S; Sichtermann, E; Simon, F; Singaraju, R N; Smirnov, N; Snellings, R; Sood, G; Sorensen, P; Sowinski, J; Speltz, J; Spinka, H M; Srivastava, B; Stadnik, A; Stanislaus, T D S; Stock, R; Stolpovsky, A; Strikhanov, M; Stringfellow, B; Suaide, A A P; Sugarbaker, E; Sumbera, M; Sun, Z; Surrow, B; Swanger, M; Symons, T J M; Szanto de Toledo, A; Tai, A; Takahashi, J; Tang, A H; Tarnowsky, T; Thein, D; Thomas, J H; Timmins, A R; Timoshenko, S; Tokarev, M; Trentalange, S; Tribble, R E; Tsai, O D; Ulery, J; Ullrich, T; Underwood, D G; Van Buren, G; van der Kolk, N; van Leeuwen, M; Vander Molen, A M; Varma, R; Vasilevski, I M; Vasiliev, A N; Vernet, R; Vigdor, S E; Viyogi, Y P; Vokal, S; Voloshin, S A; Waggoner, W T; Wang, F; Wang, G; Wang, J S; Wang, X L; Wang, Y; Watson, J W; Webb, J C; Westfall, G D; Wetzler, A; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Q H; Xu, Z; Yepes, P; Yoo, I-K; Yurevich, V I; Zhan, W; Zhang, H; Zhang, W M; Zhang, Y; Zhang, Z P; Zhao, Y; Zhong, C; Zoulkarneev, R; Zoulkarneeva, Y; Zubarev, A N; Zuo, J X

    2006-10-20

    The STAR Collaboration at the Relativistic Heavy Ion Collider reports measurements of azimuthal correlations of high transverse momentum (pT) charged hadrons in Au+Au collisions at higher pT than reported previously. As (pT) is increased, a narrow, back-to-back peak emerges above the decreasing background, providing a clear dijet signal for all collision centralities studied. Using these correlations, we perform a systematic study of dijet production and suppression in nuclear collisions, providing new constraints on the mechanisms underlying partonic energy loss in dense matter. PMID:17155388

  16. Measurement of J/ψ Azimuthal Anisotropy in Au+Au Collisions at sNN=200GeV

    NASA Astrophysics Data System (ADS)

    Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Alford, J.; Anson, C. D.; Aparin, A.; Arkhipkin, D.; Aschenauer, E.; Averichev, G. S.; Balewski, J.; Banerjee, A.; Barnovska, Z.; Beavis, D. R.; Bellwied, R.; Betancourt, M. J.; Betts, R. R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bichsel, H.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Borowski, W.; Bouchet, J.; Brandin, A. V.; Brovko, S. G.; Bruna, E.; Bültmann, S.; Bunzarov, I.; Burton, T. P.; Butterworth, J.; Cai, X. Z.; Caines, H.; Calderón de la Barca Sánchez, M.; Cebra, D.; Cendejas, R.; Cervantes, M. C.; Chaloupka, P.; Chang, Z.; Chattopadhyay, S.; Chen, H. F.; Chen, J. H.; Chen, J. Y.; Chen, L.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Chung, P.; Chwastowski, J.; Codrington, M. J. M.; Corliss, R.; Cramer, J. G.; Crawford, H. J.; Cui, X.; Das, S.; Davila Leyva, A.; De Silva, L. C.; Debbe, R. R.; Dedovich, T. G.; Deng, J.; Derradi de Souza, R.; Dhamija, S.; di Ruzza, B.; Didenko, L.; Ding, F.; Dion, A.; Djawotho, P.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Du, C. M.; Dunkelberger, L. E.; Dunlop, J. C.; Efimov, L. G.; Elnimr, M.; Engelage, J.; Eppley, G.; Eun, L.; Evdokimov, O.; Fatemi, R.; Fazio, S.; Fedorisin, J.; Fersch, R. G.; Filip, P.; Finch, E.; Fisyak, Y.; Flores, E.; Gagliardi, C. A.; Gangadharan, D. R.; Garand, D.; Geurts, F.; Gibson, A.; Gliske, S.; Grebenyuk, O. G.; Grosnick, D.; Gupta, A.; Gupta, S.; Guryn, W.; Haag, B.; Hajkova, O.; Hamed, A.; Han, L.-X.; Harris, J. W.; Hays-Wehle, J. P.; Heppelmann, S.; Hirsch, A.; Hoffmann, G. W.; Hofman, D. J.; Horvat, S.; Huang, B.; Huang, H. Z.; Huck, P.; Humanic, T. J.; Igo, G.; Jacobs, W. W.; Jena, C.; Judd, E. G.; Kabana, S.; Kang, K.; Kapitan, J.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Kesich, A.; Kikola, D. P.; Kiryluk, J.; Kisel, I.; Kisiel, A.; Klein, S. R.; Koetke, D. D.; Kollegger, T.; Konzer, J.; Koralt, I.; Korsch, W.; Kotchenda, L.; Kravtsov, P.; Krueger, K.; Kulakov, I.; Kumar, L.; Lamont, M. A. C.; Landgraf, J. M.; Landry, K. D.; LaPointe, S.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; Leight, W.; LeVine, M. J.; Li, C.; Li, W.; Li, X.; Li, X.; Li, Y.; Li, Z. M.; Lima, L. M.; Lisa, M. A.; Liu, F.; Ljubicic, T.; Llope, W. J.; Longacre, R. S.; Lu, Y.; Luo, X.; Luszczak, A.; Ma, G. L.; Ma, Y. G.; Madagodagettige Don, D. M. M. D.; Mahapatra, D. P.; Majka, R.; Margetis, S.; Markert, C.; Masui, H.; Matis, H. S.; McDonald, D.; McShane, T. S.; Mioduszewski, S.; Mitrovski, M. K.; Mohammed, Y.; Mohanty, B.; Mondal, M. M.; Munhoz, M. G.; Mustafa, M. K.; Naglis, M.; Nandi, B. K.; Nasim, Md.; Nayak, T. K.; Nelson, J. M.; Nogach, L. V.; Novak, J.; Odyniec, G.; Ogawa, A.; Oh, K.; Ohlson, A.; Okorokov, V.; Oldag, E. W.; Oliveira, R. A. N.; Olson, D.; Pachr, M.; Page, B. S.; Pal, S. K.; Pan, Y. X.; Pandit, Y.; Panebratsev, Y.; Pawlak, T.; Pawlik, B.; Pei, H.; Perkins, C.; Peryt, W.; Pile, P.; Planinic, M.; Pluta, J.; Poljak, N.; Porter, J.; Poskanzer, A. M.; Powell, C. B.; Pruneau, C.; Pruthi, N. K.; Przybycien, M.; Pujahari, P. R.; Putschke, J.; Qiu, H.; Ramachandran, S.; Raniwala, R.; Raniwala, S.; Ray, R. L.; Riley, C. K.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Ross, J. F.; Ruan, L.; Rusnak, J.; Sahoo, N. R.; Sahu, P. K.; Sakrejda, I.; Salur, S.; Sandacz, A.; Sandweiss, J.; Sangaline, E.; Sarkar, A.; Schambach, J.; Scharenberg, R. P.; Schmah, A. M.; Schmidke, B.; Schmitz, N.; Schuster, T. R.; Seger, J.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shao, M.; Sharma, B.; Sharma, M.; Shi, S. S.; Shou, Q. Y.; Sichtermann, E. P.; Singaraju, R. N.; Skoby, M. J.; Smirnov, D.; Smirnov, N.; Solanki, D.; Sorensen, P.; deSouza, U. G.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Stevens, J. R.; Stock, R.; Strikhanov, M.; Stringfellow, B.; Suaide, A. A. P.; Suarez, M. C.; Sumbera, M.; Sun, X. M.; Sun, Y.; Sun, Z.; Surrow, B.; Svirida, D. N.; Symons, T. J. M.; Szanto de Toledo, A.; Takahashi, J.; Tang, A. H.; Tang, Z.; Tarini, L. H.; Tarnowsky, T.; Thomas, J. H.; Tian, J.; Timmins, A. R.; Tlusty, D.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Trzeciak, B. A.; Tsai, O. D.; Turnau, J.; Ullrich, T.; Underwood, D. G.; Van Buren, G.; van Nieuwenhuizen, G.; Vanfossen, J. A., Jr.; Varma, R.; Vasconcelos, G. M. S.; Videbæk, F.; Viyogi, Y. P.; Vokal, S.; Voloshin, S. A.; Vossen, A.; Wada, M.; Wang, F.; Wang, G.; Wang, H.; Wang, J. S.; Wang, Q.; Wang, X. L.; Wang, Y.; Webb, G.; Webb, J. C.; Westfall, G. D.; Whitten, C., Jr.; Wieman, H.; Wissink, S. W.; Witt, R.; Wu, Y. F.; Xiao, Z.; Xie, W.; Xin, K.; Xu, H.; Xu, N.; Xu, Q. H.; Xu, W.; Xu, Y.; Xu, Z.; Xue, L.; Yang, Y.; Yang, Y.; Yepes, P.; Yi, L.; Yip, K.; Yoo, I.-K.; Zawisza, M.; Zbroszczyk, H.; Zhang, J. B.; Zhang, S.; Zhang, X. P.; Zhang, Y.; Zhang, Z. P.; Zhao, F.; Zhao, J.; Zhong, C.; Zhu, X.; Zhu, Y. H.; Zoulkarneeva, Y.; Zyzak, M.

    2013-08-01

    The measurement of J/ψ azimuthal anisotropy is presented as a function of transverse momentum for different centralities in Au+Au collisions at sNN=200GeV. The measured J/ψ elliptic flow is consistent with zero within errors for transverse momentum between 2 and 10GeV/c. Our measurement suggests that J/ψ particles with relatively large transverse momenta are not dominantly produced by coalescence from thermalized charm quarks, when comparing to model calculations.

  17. Measurement of inclusive antiprotons from Au+Au collisions at square root of s(NN) = 130 GeV.

    PubMed

    Adler, C; Ahammed, Z; Allgower, C; Amonett, J; Anderson, B D; Anderson, M; Averichev, G S; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bichsel, H; Bland, L C; Blyth, C O; Bonner, B E; Boucham, A; Brandin, A; Cadman, R V; Caines, H; Calderón de la Barca Sánchez, M; Cardenas, A; Carroll, J; Castillo, J; Castro, M; Cebra, D; Chattopadhyay, S; Chen, M L; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Christie, W; Coffin, J P; Cormier, T M; Cramer, J G; Crawford, H J; DeMello, M; Deng, W S; Derevschikov, A A; Didenko, L; Draper, J E; Dunin, V B; Dunlop, J C; Eckardt, V; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Fachini, P; Faine, V; Filimonov, K; Finch, E; Fisyak, Y; Flierl, D; Foley, K J; Fu, J; Gagliardi, C A; Gagunashvili, N; Gans, J; Gaudichet, L; Germain, M; Geurts, F; Ghazikhanian, V; Grabski, J; Grachov, O; Grigoriev, V; Guedon, M; Gushin, E; Hallman, T J; Hardtke, D; Harris, J W; Heffner, M; Heppelmann, S; Herston, T; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Huang, H Z; Humanic, T J; Hümmler, H; Igo, G; Ishihara, A; Ivanshin, Y I; Jacobs, P; Jacobs, W W; Janik, M; Johnson, I; Jones, P G; Judd, E; Kaneta, M; Kaplan, M; Keane, D; Kisiel, A; Klay, J; Klein, S R; Klyachko, A; Konstantinov, A S; Kotchenda, L; Kovalenko, A D; Kramer, M; Kravtsov, P; Krueger, K; Kuhn, C; Kulikov, A I; Kunde, G J; Kunz, C L; Kutuev, R K; Kuznetsov, A A; Lakehal-Ayat, L; Lamas-Valverde, J; Lamont, M A; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lebedev, A; Lednický, R; Leontiev, V M; LeVine, M J; Li, Q; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, L; Liu, Z; Liu, Q J; Ljubicic, T; Llope, W J; LoCurto, G; Long, H; Longacre, R S; Lopez-Noriega, M; Love, W A; Lynn, D; Majka, R; Margetis, S; Martin, L; Marx, J; Matis, H S; Matulenko, Y A; McShane, T S; Meissner, F; Melnick, Y; Meschanin, A; Messer, M; Miller, M L; Milosevich, Z; Minaev, N G; Mitchell, J; Moiseenko, V A; Moore, C F; Morozov, V; de Moura, M M; Munhoz, M G; Mutchler, G S; Nelson, J M; Nevski, P; Nikitin, V A; Nogach, L V; Norman, B; Nurushev, S B; Odyniec, G; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Paic, G; Pandey, S U; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Perevoztchikov, V; Peryt, W; Petrov, V A; Platner, E; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potrebenikova, E; Prindle, D; Pruneau, C; Radomski, S; Rai, G; Ravel, O; Ray, R L; Razin, S V; Reichhold, D; Reid, J G; Retiere, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Roy, C; Rykov, V; Sakrejda, I; Sandweiss, J; Saulys, A C; Savin, I; Schambach, J; Scharenberg, R P; Schmitz, N; Schroeder, L S; Schüttauf, A; Schweda, K; Seger, J; Seliverstov, D; Seyboth, P; Shahaliev, E; Shestermanov, K E; Shimanskii, S S; Shvetcov, V S; Skoro, G; Smirnov, N; Snellings, R; Sowinski, J; Spinka, H M; Srivastava, B; Stephenson, E J; Stock, R; Stolpovsky, A; Strikhanov, M; Stringfellow, B; Struck, C; Suaide, A A; Sugarbaker, E; Suire, C; Sumbera, M; Symons, T J; de Toledo, A S; Szarwas, P; Takahashi, J; Tang, A H; Thomas, J H; Thompson, M; Tikhomirov, V; Trainor, T A; Trentalange, S; Tribble, R E; Tokarev, M; Tonjes, M B; Trofimov, V; Tsai, O; Turner, K; Ullrich, T; Underwood, D G; Van Buren, G; VanderMolen, A M; Vanyashin, A; Vasilevski, I M; Vasiliev, A N; Vigdor, S E; Voloshin, S A; Wang, F; Ward, H; Watson, J W; Wells, R; Wenaus, T; Westfall, G D; Whitten, C; Wieman, H; Willson, R; Wissink, S W; Witt, R; Xu, N; Xu, Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yurevich, V I; Zanevski, Y V; Zborovský, I; Zhang, H; Zhang, W M; Zoulkarneev, R; Zubarev, A N

    2001-12-24

    We report the first measurement of inclusive antiproton production at midrapidity in Au+Au collisions at square root of s(NN) = 130 GeV by the STAR experiment at RHIC. The antiproton transverse mass distributions in the measured transverse momentum range of 0.25

  18. Pion Interferometry of square root of (s(NN)) =130 GeV Au + Au collisions at RHIC.

    PubMed

    Adler, C; Ahammed, Z; Allgower, C; Amonett, J; Anderson, B D; Anderson, M; Averichev, G S; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bichsel, H; Bland, L C; Blyth, C O; Bonner, B E; Bossingham, R; Boucham, A; Brandin, A; Cadman, R V; Caines, H; Calderón De La Barca Sánchez, M; Cardenas, A; Carroll, J; Castillo, J; Castro, M; Cebra, D; Chattopadhyay, S; Chen, M L; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Christie, W; Coffin, J P; Conin, L; Cormier, T M; Cramer, J G; Crawford, H J; DeMello, M; Deng, W S; Derevschikov, A A; Didenko, L; Draper, J E; Dunin, V B; Dunlop, J C; Eckardt, V; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Fachini, P; Faine, V; Finch, E; Fisyak, Y; Flierl, D; Foley, K J; Fu, J; Gagunashvili, N; Gans, J; Gaudichet, L; Germain, M; Geurts, F; Ghazikhanian, V; Grabski, J; Grachov, O; Greiner, D; Grigoriev, V; Guedon, M; Gushin, E; Hallman, T J; Hardtke, D; Harris, J W; Heffner, M; Heppelmann, S; Herston, T; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Huang, H Z; Humanic, T J; Hümmler, H; Igo, G; Ishihara, A; Ivanshin, Y I; Jacobs, P; Jacobs, W W; Janik, M; Johnson, I; Jones, P G; Judd, E; Kaneta, M; Kaplan, M; Keane, D; Kisiel, A; Klay, J; Klein, S R; Klyachko, A; Konstantinov, A S; Kotchenda, L; Kovalenko, A D; Kramer, M; Kravtsov, P; Krueger, K; Kuhn, C; Kulikov, A I; Kunde, G J; Kunz, C L; Kutuev, R K; Kuznetsov, A A; Lakehal-Ayat, L; Lamas-Valverde, J; Lamont, M A; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lebedev, A; LeCompte, T; Lednický, R; Leontiev, V M; LeVine, M J; Li, Q; Li, Q; Lindenbaum, S J; Lisa, M A; Ljubicic, T; Llope, W J; LoCurto, G; Long, H; Longacre, R S; Lopez-Noriega, M; Love, W A; Lynn, D; Majka, R; Margetis, S; Martin, L; Marx, J; Matis, H S; Matulenko, Y A; McShane, T S; Meissner, F; Melnick, Y; Meschanin, A; Messer, M; Miller, M L; Milosevich, Z; Minaev, N G; Mitchell, J; Moiseenko, V A; Moltz, D; Moore, C F; Morozov, V; de Moura, M M; Munhoz, M G; Mutchler, G S; Nelson, J M; Nevski, P; Nikitin, V A; Nogach, L V; Norman, B; Nurushev, S B; Odyniec, G; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Paic, G; Pandey, S U; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Perevoztchikov, V; Peryt, W; Petrov, V A; Pinganaud, W; Platner, E; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potrebenikova, E; Prindle, D; Pruneau, C; Radomski, S; Rai, G; Ravel, O; Ray, R L; Razin, S V; Reichhold, D; Reid, J G; Retiere, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Roy, C; Russ, D; Rykov, V; Sakrejda, I; Sandweiss, J; Saulys, A C; Savin, I; Schambach, J; Scharenberg, R P; Schweda, K; Schmitz, N; Schroeder, L S; Schüttauf, A; Seger, J; Seliverstov, D; Seyboth, P; Shahaliev, E; Shestermanov, K E; Shimanskii, S S; Shvetcov, V S; Skoro, G; Smirnov, N; Snellings, R; Sowinski, J; Spinka, H M; Srivastava, B; Stephenson, E J; Stock, R; Stolpovsky, A; Strikhanov, M; Stringfellow, B; Stroebele, H; Struck, C; Suaide, A A; Sugarbaker, E; Suire, C; Sumbera, M; Symons, T J; Szanto De Toledo, A; Szarwas, P; Takahashi, J; Tang, A H; Thomas, J H; Tikhomirov, V; Trainor, T A; Trentalange, S; Tokarev, M; Tonjes, M B; Trofimov, V; Tsai, O; Turner, K; Ullrich, T; Underwood, D G; Van Buren, G; VanderMolen, A M; Vanyashin, A; Vasilevski, I M; Vasiliev, A N; Vigdor, S E; Voloshin, S A; Wang, F; Ward, H; Watson, J W; Wells, R; Wenaus, T; Westfall, G D; Whitten, C; Wieman, H; Willson, R; Wissink, S W; Witt, R; Xu, N; Xu, Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yokosawa, A; Yurevich, V I; Zanevski, Y V; Zborovský, I; Zhang, W M; Zoulkarneev, R; Zubarev, A N

    2001-08-20

    Two-pion correlation functions in Au+Au collisions at square root of [s(NN)] = 130 GeV have been measured by the STAR (solenoidal tracker at RHIC) detector. The source size extracted by fitting the correlations grows with event multiplicity and decreases with transverse momentum. Anomalously large sizes or emission durations, which have been suggested as signals of quark-gluon plasma formation and rehadronization, are not observed. The Hanbury Brown-Twiss parameters display a weak energy dependence over a broad range in square root of [s(NN)]. PMID:11497937

  19. Elliptic flow in Au+Au collisions at square root(S)NN = 130 GeV.

    PubMed

    Ackermann, K H; Adams, N; Adler, C; Ahammed, Z; Ahmad, S; Allgower, C; Amsbaugh, J; Anderson, M; Anderssen, E; Arnesen, H; Arnold, L; Averichev, G S; Baldwin, A; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Beddo, M; Bekele, S; Belaga, V V; Bellwied, R; Bennett, S; Bercovitz, J; Berger, J; Betts, W; Bichsel, H; Bieser, F; Bland, L C; Bloomer, M; Blyth, C O; Boehm, J; Bonner, B E; Bonnet, D; Bossingham, R; Botlo, M; Boucham, A; Bouillo, N; Bouvier, S; Bradley, K; Brady, F P; Braithwaite, E S; Braithwaite, W; Brandin, A; Brown, R L; Brugalette, G; Byrd, C; Caines, H; Calderón de la Barca Sánchez, M; Cardenas, A; Carr, L; Carroll, J; Castillo, J; Caylor, B; Cebra, D; Chatopadhyay, S; Chen, M L; Chen, W; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Chrin, J; Christie, W; Coffin, J P; Conin, L; Consiglio, C; Cormier, T M; Cramer, J G; Crawford, H J; Danilov, V I; Dayton, D; DeMello, M; Deng, W S; Derevschikov, A A; Dialinas, M; Diaz, H; DeYoung, P A; Didenko, L; Dimassimo, D; Dioguardi, J; Dominik, W; Drancourt, C; Draper, J E; Dunin, V B; Dunlop, J C; Eckardt, V; Edwards, W R; Efimov, L G; Eggert, T; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Etkin, A; Fachini, P; Feliciano, C; Ferenc, D; Ferguson, M I; Fessler, H; Finch, E; Fine, V; Fisyak, Y; Flierl, D; Flores, I; Foley, K J; Fritz, D; Gagunashvili, N; Gans, J; Gazdzicki, M; Germain, M; Geurts, F; Ghazikhanian, V; Gojak, C; Grabski, J; Grachov, O; Grau, M; Greiner, D; Greiner, L; Grigoriev, V; Grosnick, D; Gross, J; Guilloux, G; Gushin, E; Hall, J; Hallman, T J; Hardtke, D; Harper, G; Harris, J W; He, P; Heffner, M; Heppelmann, S; Herston, T; Hill, D; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Howe, M; Huang, H Z; Humanic, T J; Hümmler, H; Hunt, W; Hunter, J; Igo, G J; Ishihara, A; Ivanshin, Y I; Jacobs, P; Jacobs, W W; Jacobson, S; Jared, R; Jensen, P; Johnson, I; Jones, P G; Judd, E; Kaneta, M; Kaplan, M; Keane, D; Kenney, V P; Khodinov, A; Klay, J; Klein, S R; Klyachko, A; Koehler, G; Konstantinov, A S; Kormilitsyne, V; Kotchenda, L; Kotov, I; Kovalenko, A D; Kramer, M; Kravtsov, P; Krueger, K; Krupien, T; Kuczewski, P; Kuhn, C; Kunde, G J; Kunz, C L; Kutuev, R K; Kuznetsov, A A; Lakehal-Ayat, L; Lamas-Valverde, J; Lamont, M A; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lebedev, A; LeCompte, T; Leonhardt, W J; Leontiev, V M; Leszczynski, P; LeVine, M J; Li, Q; Li, Q; Li, Z; Liaw, C J; Lin, J; Lindenbaum, S J; Lindenstruth, V; Lindstrom, P J; Lisa, M A; Liu, H; Ljubicic, T; Llope, W J; LoCurto, G; Long, H; Longacre, R S; Lopez-Noriega, M; Lopiano, D; Love, W A; Lutz, J R; Lynn, D; Madansky, L; Maier, R; Majka, R; Maliszewski, A; Margetis, S; Marks, K; Marstaller, R; Martin, L; Marx, J; Matis, H S; Matulenko, Y A; Matyushevski, E A; McParland, C; McShane, T S; Meier, J; Melnick, Y; Meschanin, A; Middlekamp, P; Mikhalin, N; Miller, B; Milosevich, Z; Minaev, N G; Minor, B; Mitchell, J; Mogavero, E; Moiseenko, V A; Moltz, D; Moore, C F; Morozov, V; Morse, R; de Moura, M M; Munhoz, M G; Mutchler, G S; Nelson, J M; Nevski, P; Ngo, T; Nguyen, M; Nguyen, T; Nikitin, V A; Nogach, L V; Noggle, T; Norman, B; Nurushev, S B; Nussbaum, T; Nystrand, J; Odyniec, G; Ogawa, A; Ogilvie, C A; Olchanski, K; Oldenburg, M; Olson, D; Ososkov, G A; Ott, G; Padrazo, D; Paic, G; Pandey, S U; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Pentia, M; Perevotchikov, V; Peryt, W; Petrov, V A; Pinganaud, W; Pirogov, S; Platner, E; Pluta, J; Polk, I; Porile, N; Porter, J; Poskanzer, A M; Potrebenikova, E; Prindle, D; Pruneau, C; Puskar-Pasewicz, J; Rai, G; Rasson, J; Ravel, O; Ray, R L; Razin, S V; Reichhold, D; Reid, J; Renfordt, R E; Retiere, F; Ridiger, A; Riso, J; Ritter, H G; Roberts, J B; Roehrich, D; Rogachevski, O V; Romero, J L; Roy, C; Russ, D; Rykov, V; Sakrejda, I; Sanchez, R; Sandler, Z; Sandweiss, J; Sappenfield, P; Saulys, A C; Savin, I; Schambach, J; Scharenberg, R P; Scheblien, J; Scheetz, R; Schlueter, R; Schmitz, N; Schroeder, L S; Schulz, M; Schüttauf, A; Sedlmeir, J; Seger, J; Seliverstov, D; Seyboth, J; Seyboth, P; Seymour, R; Shakaliev, E I; Shestermanov, K E; Shi, Y; Shimanskii, S S; Shuman, D; Shvetcov, V S; Skoro, G; Smirnov, N; Smykov, L P; Snellings, R; Solberg, K; Sowinski, J; Spinka, H M; Srivastava, B; Stephenson, E J; Stock, R; Stolpovsky, A; Stone, N; Stone, R; Strikhanov, M; Stringfellow, B; Stroebele, H; Struck, C; Suaide, A A; Sugarbaker, E; Suire, C; Symons, T J; Takahashi, J; Tang, A H; Tarchini, A; Tarzian, J; Thomas, J H; Tikhomirov, V; Szanto De Toledo, A; Tonse, S; Trainor, T; Trentalange, S; Tokarev, M; Tonjes, M B; Trofimov, V; Tsai, O; Turner, K; Ullrich, T; Underwood, D G; Vakula, I; Van Buren, G; VanderMolen, A M; Vanyashin, A; Vasilevski, I M; Vasiliev, A N; Vigdor, S E; Visser, G; Voloshin, S A; Vu, C; Wang, F; Ward, H; Weerasundara, D; Weidenbach, R; Wells, R; Wells, R; Wenaus, T; Westfall, G D; Whitfield, J P; Whitten, C; Wieman, H; Willson, R; Wilson, K; Wirth, J; Wisdom, J; Wissink, S W; Witt, R; Wolf, J; Wood, L; Xu, N; Xu, Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yokosawa, A; Yurevich, V I; Zanevski, Y V; Zhang, J; Zhang, W M; Zhu, J; Zimmerman, D; Zoulkarneev, R; Zubarev, A N

    2001-01-15

    Elliptic flow from nuclear collisions is a hadronic observable sensitive to the early stages of system evolution. We report first results on elliptic flow of charged particles at midrapidity in Au+Au collisions at square root(S)NN = 130 GeV using the STAR Time Projection Chamber at the Relativistic Heavy Ion Collider. The elliptic flow signal, v2, averaged over transverse momentum, reaches values of about 6% for relatively peripheral collisions and decreases for the more central collisions. This can be interpreted as the observation of a higher degree of thermalization than at lower collision energies. Pseudorapidity and transverse momentum dependence of elliptic flow are also presented. PMID:11177841

  20. Low frequency noise in the unstable contact region of Au-to-Au microcontact for microelectromechanical system switches

    SciTech Connect

    Qiu, Haodong; Wang, Hong; Ke, Feixiang

    2014-06-23

    The noise behavior of Au-to-Au microcontact for microelectromechanical system switches has been experimentally studied in the unstable contact region. The results suggest that the electrical conduction remains nonmetallic at the initial stage during contact formation due to the existence of alien films, and traps in the alien layer located at the contact interface could play an important role in determining the conduction noise. The conduction fluctuation induced by electron trapping-detrapping associated with the hydrocarbon layer is found to be an intrinsic noise source contributing to the low frequency noise in the unstable contact region.

  1. Pseudorapidity distribution of multiplicity in Au+Au collisions at √sNN = 200 GeV

    NASA Astrophysics Data System (ADS)

    Dong, Ya-Fei; Jiang, Zhi-Jin; Wang, Zeng-Wei

    2008-04-01

    Using the Glauber model, we discuss the number of binary nucleon-nucleon collisions in heavy-ion collisions. Based on the latter, after considering the effect of energy loss of the nucleons in multiple collisions, we derive the pseudorapidity distribution of the multiplicity as a function of the impact parameter in nucleus-nucleus collisions. Using this, we analyze the experimental measurements carried out by the BRAHMS Collaboration in Au + Au collisions at √sNN = 200 GeV. The results are in good agreement with the experimental observations. Supported by Key Foundation of Shanghai (06JC14075)

  2. Depth limit for reef building corals in the Au'au Channel, S.E. Hawaii

    NASA Astrophysics Data System (ADS)

    Grigg, Richard W.

    2006-03-01

    In this paper, the relationship between reef building (accretion) and depth in an optimal inter-island channel environment in Hawaii is analyzed. For accretion, the growth rate of Porites lobata is used as a proxy for the reef community, because it is the most abundant and dominant species of reef building coral in Hawaii. Optimal growth of P. lobata occurs at a depth of 6 m, below which both growth rate and abundance decrease with increasing depth. A lower depth limit for this species is found at about 80-100 m, yet reef accretion ceases at ~50 m depth. Below 50 m, rates of bio-erosion of colony holdfasts equal or exceed the growth of basal attachments, causing colonies to detach from the bottom. Continued bio-erosion further erodes and dislodges colonies leading to their breakdown and ultimately to the formation of coralline rubble and sand. Thus, within this channel environment in Hawaii, a threshold for reef building exists at ~ 50 m depth, where coral accretion is interrupted by bio-erosion. Conceptually viewed, this depth horizon is analogous to a vertical Darwin Point, although quite narrow in space and time. More importantly, it explains the history of reef morphology in the Au’au Channel where a chronological hiatus exists at a depth near 50 m. This hiatus separates shallower modern growth (about 100 years or less) from the deeper reef which is all due to accretion during the early Holocene or Pleistocene epochs.

  3. Understanding the effect of ultrathin AuPd alloy shells of irregularly shaped Au@AuPd nanoparticles with high-index facets on enhanced performance of ethanol oxidation

    NASA Astrophysics Data System (ADS)

    Bi, Cuixia; Feng, Cong; Miao, Tingting; Song, Yahui; Wang, Dayang; Xia, Haibing

    2015-11-01

    In this study, irregularly shaped, concave cuboidal Au@AuPd nanoparticles (ISCC-Au@AuPd NPs) with high-index facets were synthesized via Pd overgrowth on pre-formed ISCC-Au NPs with a concentration of Pd precursors as low as 2%. The AuPd alloy nature of the resulting shells was confirmed by X-ray photoelectron spectroscopy, cyclic voltammogram analysis, and energy dispersive X-ray spectroscopy. Among the irregularly shaped NPs obtained, the ISCC-Au97.5@Au0.5Pd2.0 NPs display the largest electrochemically active surface area (up to 92.11 m2 g-1), as their closed-packed agglomeration was prevented, and the best long-term stability with respect to ethanol oxidation (0.50 M) in alkaline media (0.30 KOH) by efficiently removing intermediates. Their mass- and ECSA-normalized current densities (4.15 A mgPd-1 and 4.51 mA cm-2) are about 20.7 times and 6.9 times higher than those of commercial Pd/C catalysts (0.20 A mgPd-1 and 0.65 mA cm-2), respectively.In this study, irregularly shaped, concave cuboidal Au@AuPd nanoparticles (ISCC-Au@AuPd NPs) with high-index facets were synthesized via Pd overgrowth on pre-formed ISCC-Au NPs with a concentration of Pd precursors as low as 2%. The AuPd alloy nature of the resulting shells was confirmed by X-ray photoelectron spectroscopy, cyclic voltammogram analysis, and energy dispersive X-ray spectroscopy. Among the irregularly shaped NPs obtained, the ISCC-Au97.5@Au0.5Pd2.0 NPs display the largest electrochemically active surface area (up to 92.11 m2 g-1), as their closed-packed agglomeration was prevented, and the best long-term stability with respect to ethanol oxidation (0.50 M) in alkaline media (0.30 KOH) by efficiently removing intermediates. Their mass- and ECSA-normalized current densities (4.15 A mgPd-1 and 4.51 mA cm-2) are about 20.7 times and 6.9 times higher than those of commercial Pd/C catalysts (0.20 A mgPd-1 and 0.65 mA cm-2), respectively. Electronic supplementary information (ESI) available: High magnification TEM

  4. Templated Control of Au nanospheres in Silica Nanowires

    SciTech Connect

    Tringe, J W; Vanamu, G; Zaidi, S H

    2007-03-15

    The formation of regularly-spaced metal nanostructures in selectively-placed insulating nanowires is an important step toward realization of a wide range of nano-scale electronic and opto-electronic devices. Here we report templated synthesis of Au nanospheres embedded in silica nanowires, with nanospheres consistently spaced with a period equal to three times their diameter. Under appropriate conditions, nanowires form exclusively on Si nanostructures because of enhanced local oxidation and reduced melting temperatures relative to templates with larger dimensions. We explain the spacing of the nanospheres with a general model based on a vapor-liquid-solid mechanism, in which an Au/Si alloy dendrite remains liquid in the nanotube until a critical Si concentration is achieved locally by silicon oxide-generated nanowire growth. Additional Si oxidation then locally reduces the surface energy of the Au-rich alloy by creating a new surface with minimum area inside of the nanotube. The isolated liquid domain subsequently evolves to become an Au nanosphere, and the process is repeated.

  5. Formation of Au and tetrapyridyl porphyrin complexes in superfluid helium.

    PubMed

    Feng, Cheng; Latimer, Elspeth; Spence, Daniel; Al Hindawi, Aula M A A; Bullen, Shem; Boatwright, Adrian; Ellis, Andrew M; Yang, Shengfu

    2015-07-14

    Binary clusters containing a large organic molecule and metal atoms have been formed by the co-addition of 5,10,15,20-tetra(4-pyridyl)porphyrin (H2TPyP) molecules and gold atoms to superfluid helium nanodroplets, and the resulting complexes were then investigated by electron impact mass spectrometry. In addition to the parent ion H2TPyP yields fragments mainly from pyrrole, pyridine and methylpyridine ions because of the stability of their ring structures. When Au is co-added to the droplets the mass spectra are dominated by H2TPyP fragment ions with one or more Au atoms attached. We also show that by switching the order in which Au and H2TPyP are added to the helium droplets, different types of H2TPyP-Au complexes are clearly evident from the mass spectra. This study suggests a new route for the control over the growth of metal-organic compounds inside superfluid helium nanodroplets.

  6. Templated control of Au nanospheres in silica nanowires

    SciTech Connect

    Tringe, Joseph W.; Vanamu, Ganesh; Zaidi, Saleem H.

    2008-11-01

    The formation of regularly spaced metal nanostructures in selectively placed insulating nanowires is an important step toward realization of a wide range of nanoscale electronic and optoelectronic devices. Here we report templated synthesis of Au nanospheres embedded in silica nanowires, with nanospheres consistently spaced with a period equal to three times their diameter. Under appropriate conditions, nanowires form exclusively on Si nanostructures because of enhanced local oxidation and reduced melting temperatures relative to templates with larger dimensions. We explain the spacing of the nanospheres with a general model based on a vapor-liquid-solid mechanism, in which an Au/Si alloy dendrite remains liquid in the nanotube until a critical Si concentration is achieved locally by silicon oxide-generated nanowire growth. Additional Si oxidation then locally reduces the surface energy of the Au-rich alloy by creating a new surface with smaller area inside of the nanotube. The isolated liquid domain subsequently evolves to become an Au nanosphere, and the process is repeated.

  7. Vacuum synthesis of magnetic aluminum phthalocyanine on Au(111).

    PubMed

    Hong, I-Po; Li, Na; Zhang, Ya-Jie; Wang, Hao; Song, Huan-Jun; Bai, Mei-Lin; Zhou, Xiong; Li, Jian-Long; Gu, Gao-Chen; Zhang, Xue; Chen, Min; Gottfried, J Michael; Wang, Dong; Lü, Jing-Tao; Peng, Lian-Mao; Hou, Shi-Min; Berndt, Richard; Wu, Kai; Wang, Yong-Feng

    2016-08-16

    Air-unstable magnetic aluminum phthalocyanine (AlPc) molecules are prepared by an on-surface metalation reaction of phthalocyanine with aluminum (Al) atoms on Au(111) in ultrahigh vacuum. Experiments and density functional theory calculations show that an unpaired spin is located on the conjugated isoindole lobes of the molecule rather than at the Al position. PMID:27406881

  8. Rational design and synthesis of excavated trioctahedral Au nanocrystals.

    PubMed

    Chen, Qiaoli; Jia, Yanyan; Shen, Wei; Xie, Shuifen; Yang, Yanan; Cao, Zhenming; Xie, Zhaoxiong; Zheng, Lansun

    2015-06-28

    Excavated polyhedral nanostructures, possessing the features of high surface area and well-defined surface structure with a specific crystal facet and avoidance of aggregation, could be one of the best choices for the purpose of reducing consumption and improving performance of noble metals in many application fields. However, the formation of the excavated structures is thermodynamically unfavourable and its rational synthesis is far beyond our knowledge. In this work, taking overgrowth of Pd onto trioctahedral Au nanocrystals as a model, we present a deep insight study for synthesizing an excavated structure relying on the protection role of surfactants under suitable crystal growth kinetics. Based on the abovementioned understanding, we designed a simple and effective strategy to synthesize Au nanocrystals with excavated trioctahedral structure in one step. Due to the novel feature of the excavated structure and exposed high energy {110} facets, excavated trioctahedral Au NCs exhibited optical extinction at the near-infrared region and showed high catalytic activity towards the reduction of p-nitrophenol. Moreover, the synthetic strategy can be extended to the synthesis of excavated Au-Pd alloys.

  9. Electrochemical functionalization of Au by aminobenzene and 2-aminotoluene

    NASA Astrophysics Data System (ADS)

    Rösicke, F.; Sun, G.; Neubert, T.; Janietz, S.; Hinrichs, K.; Rappich, J.

    2016-03-01

    Au surfaces are functionalized by aminobenzene (AB) and 2-aminotoluene (AT) using the electrochemical reduction of diazotized 1,4-diaminobenzene and 2,5-diaminotoluene. The IR spectroscopic measurements reveal the successful modification of Au surfaces by AB and AT. Both types of layers show similar thicknesses as obtained by microgravimetric measurements via electrochemical quartz crystal microbalance (EQCM). However, the faradaic efficiency for the grafting of AT onto an EQCM-Au sensor was 6% compared to 41% for the grafting of AB. This behavior points to a steric hindrance during the binding of AT to the EQCM surface induced by the additional methyl group present in the toluene derivative. The AB and AT functionalized surfaces have been further modified by the amidation reaction of EDC/NHS activated 4-nitrobenzoic acid. This model system reveals that the amidation reaction is slightly hindered in case of the AT layer due to the presence of the methyl group close to the amino group. This behavior leads to a four times less amount of amide bonds at the AT compared to AB modified Au surfaces as obtained from IR spectroscopic measurements.

  10. Nitrogen mineralization from 'AU Golden' sunn hemp residue

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The tropical legume sunn hemp (Crotalaria juncea) cultivar ‘AU Golden’ has the potential to provide substantial amounts of nitrogen (N) to subsequent crops that could reduce recommended application rates of synthetic N fertilizers. Nitrogen fertilization problems via legumes are often due to asynch...

  11. Physical parameters of Au-n-InP structures

    NASA Astrophysics Data System (ADS)

    Touhami, R.; Ravelet, S.

    1999-05-01

    An approach suitable for determining the physical parameters of Au-oxide-n-InP structures is presented in this article. This approach consists in describing the Au-oxide-n-InP structures by a modified current-voltage model in which both least squares and Newton-Raphson methods are used in the parameter determination. The Au-oxide-n-InP samples under study are either oxidized by air or treated with oxygen plasma. The ideality factor, the series resistance, the effective Richardson constant, and the effective barrier height of these structures are computed by means of the current voltage model. A better estimation of these parameters is obtained when we consider another definition of the Richardson constant, namely, the correct value of the Richardson constant. Physical parameters such as the barrier lowering at zero bias due to the image force, the barrier height at 0 K, the correct value of the Richardson constant, and the tunnel coefficient are then simulated. The values of these parameters obtained for Au-oxide-n-InP structures are in good agreement with those published in the literature.

  12. Electrochemical functionalization of Au by aminobenzene and 2-aminotoluene.

    PubMed

    Rösicke, F; Sun, G; Neubert, T; Janietz, S; Hinrichs, K; Rappich, J

    2016-03-01

    Au surfaces are functionalized by aminobenzene (AB) and 2-aminotoluene (AT) using the electrochemical reduction of diazotized 1,4-diaminobenzene and 2,5-diaminotoluene. The IR spectroscopic measurements reveal the successful modification of Au surfaces by AB and AT. Both types of layers show similar thicknesses as obtained by microgravimetric measurements via electrochemical quartz crystal microbalance (EQCM). However, the faradaic efficiency for the grafting of AT onto an EQCM-Au sensor was 6% compared to 41% for the grafting of AB. This behavior points to a steric hindrance during the binding of AT to the EQCM surface induced by the additional methyl group present in the toluene derivative. The AB and AT functionalized surfaces have been further modified by the amidation reaction of EDC/NHS activated 4-nitrobenzoic acid. This model system reveals that the amidation reaction is slightly hindered in case of the AT layer due to the presence of the methyl group close to the amino group. This behavior leads to a four times less amount of amide bonds at the AT compared to AB modified Au surfaces as obtained from IR spectroscopic measurements.

  13. Determination of 198Au X-rays emission probabilities.

    PubMed

    Moreira, D S; Koskinas, M F; Dias, M S; Yamazaki, I M

    2010-01-01

    This work describes the measurements of the K X-ray and gamma-ray emission probabilities per decay of (198)Au performed at the Nuclear Metrology Laboratory (LMN) at the IPEN, São Paulo. The radioactive sample was obtained by means of (197)Au(n, gamma)(198)Au reaction irradiating an Au foil in a thermal neutron flux near the core of the IPEN 3.5 MW research reactor. The activity of samples was determined in a 4pibeta-gamma coincidence system, setting the gamma window at the 411.80 keV total energy absorption peak. The same samples were measured in two different spectrometers: a HPGe planar spectrometer with Be window, suitable for measurements in the low energy range and a coaxial REGe spectrometer. Both spectrometers were previously calibrated in a well defined geometry by means of standard sources calibrated in a 4pibeta-gamma coincidence system. MCNP4C Monte Carlo code was used for simulating the REGe spectrometer calibration curve, and a new version of code ESQUEMA was adopted for simulating the detection processes in the coincidence system, in order to predict the efficiency extrapolation curve.

  14. Syn-deformational features of Carlin-type Au deposits

    USGS Publications Warehouse

    Peters, S.G.

    2004-01-01

    Syn-deformational ore deposition played an important role in some Carlin-type Au deposits according to field and laboratory evidence, which indicates that flow of Au-bearing fluids was synchronous with regional-scale deformation events. Gold-related deformation events linked to ore genesis were distinct from high-level, brittle deformation that is typical of many epithermal deposits. Carlin-type Au deposits, with brittle-ductile features, most likely formed during tectonic events that were accompanied by significant fluid flow. Interactive deformation-fluid processes involved brittle-ductile folding, faulting, shearing, and gouge development that were focused along illite-clay and dissolution zones caused by hydrothermal alteration. Alteration along these deformation zones resulted in increased porosity and enhancement of fluid flow, which resulted in decarbonated, significant dissolution, collapse, and volume and mass reduction. Carlin-type Au deposits commonly are hosted in Paleozoic and Mesozoic sedimentary rocks (limestone, siltstone, argillite, shale, and quartzite) on the margins of cratons. The sedimentary basins containing the host rocks underwent tectonic events that influenced the development of stratabound, structurally controlled orebodies. Published by Elsevier Ltd.

  15. Au42: a possible ground-state noble metallic nanotube.

    PubMed

    Wang, Jing; Ning, Hua; Ma, Qing-Min; Liu, Ying; Li, You-Cheng

    2008-10-01

    A large hollow tubelike Au(42) is predicted as a new ground-state configuration based on the scalar relativistic density functional theory. The shape of this new Au(42) cluster is similar to a (5,5) single-wall gold nanotube, the two ends of which are capped by half of a fullerenelike Au(32). In the same way, a series of Au(n) (n = 37, 42, 47, 52, 57, 62, 67, 72, ..., Delta n = 5) tubelike structures has been constructed. The highest occupied molecular orbital-lowest unoccupied molecular orbital gaps suggested a significant semiconductor-conductor alternation in n is an element of [32,47]. Similar to the predictions and speculation of Daedalus [D. E. H. Jones, New Sci. 32, 245 (1966); E. Osawa, Superaromaticity (Kagaku, Kyoto, 1970), Vol. 25, pp. 854-863; Z. Yoshida and E. Osawa, Aromaticity Chemical Monograph (Kagaku Dojin, Kyoto, Japan, 1971), Vol. 22, pp. 174-176; D. A. Bochvar and E. G. Gal'pern, Dokl. Akad. Nauk SSSR 209, 610 (1973)], here a large hollow ground-state gold nanotube was predicted theoretically. PMID:19045114

  16. Synthesis of Au@Pt bimetallic nanoparticles with concave Au nanocuboids as seeds and their enhanced electrocatalytic properties in the ethanol oxidation reaction

    NASA Astrophysics Data System (ADS)

    Tan, Lingyu; Li, Lidong; Peng, Yi; Guo, Lin

    2015-12-01

    Herein, a new type of uniform and well-structured Au@Pt bimetallic nanoparticles (BNPs) with highly active concave Au nanocuboids (NCs) as seeds was successfully synthesized by using the classic seed-mediated method. Electrochemical measurements were conducted to demonstrate their greatly enhanced catalytic performance in the ethanol oxidation reaction (EOR). It was found that the electrochemical performance for Au@Pt BNPs with the concave Au NCs as seeds, which were enclosed by {611} high-index facets, could be seven times higher than that of the Au@Pt bimetallic nanoparticles with regular spherical Au NPs as seeds. Furthermore, our findings show that the morphology and electrocatalytic activity of the Au@Pt BNPs can be tuned simply by changing the compositional ratios of the growth solution. The lower the amount of H2PtCl6 used in the growth solution, the thinner the Pt shell grew, and the more high-index facets of concave Au NCs seeds were exposed in Au@Pt BNPs, leading to higher electrochemical activity. These as-prepared concave Au@Pt BNPs will open up new strategies for improving catalytic efficiency and reducing the use of the expensive and scarce resource of platinum in the ethanol oxidation reaction, and are potentially applicable as electrochemical catalysts for direct ethanol fuel cells.

  17. Synthesis of Au@Pt bimetallic nanoparticles with concave Au nanocuboids as seeds and their enhanced electrocatalytic properties in the ethanol oxidation reaction.

    PubMed

    Tan, Lingyu; Li, Lidong; Peng, Yi; Guo, Lin

    2015-12-18

    Herein, a new type of uniform and well-structured Au@Pt bimetallic nanoparticles (BNPs) with highly active concave Au nanocuboids (NCs) as seeds was successfully synthesized by using the classic seed-mediated method. Electrochemical measurements were conducted to demonstrate their greatly enhanced catalytic performance in the ethanol oxidation reaction (EOR). It was found that the electrochemical performance for Au@Pt BNPs with the concave Au NCs as seeds, which were enclosed by {611} high-index facets, could be seven times higher than that of the Au@Pt bimetallic nanoparticles with regular spherical Au NPs as seeds. Furthermore, our findings show that the morphology and electrocatalytic activity of the Au@Pt BNPs can be tuned simply by changing the compositional ratios of the growth solution. The lower the amount of H2PtCl6 used in the growth solution, the thinner the Pt shell grew, and the more high-index facets of concave Au NCs seeds were exposed in Au@Pt BNPs, leading to higher electrochemical activity. These as-prepared concave Au@Pt BNPs will open up new strategies for improving catalytic efficiency and reducing the use of the expensive and scarce resource of platinum in the ethanol oxidation reaction, and are potentially applicable as electrochemical catalysts for direct ethanol fuel cells.

  18. Core-shell Au@Pd nanoparticles with enhanced catalytic activity for oxygen reduction reaction via core-shell Au@Ag/Pd constructions

    PubMed Central

    Chen, Dong; Li, Chengyin; Liu, Hui; Ye, Feng; Yang, Jun

    2015-01-01

    Core-shell nanoparticles often exhibit improved catalytic properties due to the lattice strain created in these core-shell particles. Herein, we demonstrate the synthesis of core-shell Au@Pd nanoparticles from their core-shell Au@Ag/Pd parents. This strategy begins with the preparation of core-shell Au@Ag nanoparticles in an organic solvent. Then, the pure Ag shells are converted into the shells made of Ag/Pd alloy by galvanic replacement reaction between the Ag shells and Pd2+ precursors. Subsequently, the Ag component is removed from the alloy shell using saturated NaCl solution to form core-shell Au@Pd nanoparticles with an Au core and a Pd shell. In comparison with the core-shell Au@Pd nanoparticles upon directly depositing Pd shell on the Au seeds and commercial Pd/C catalysts, the core-shell Au@Pd nanoparticles via their core-shell Au@Ag/Pd templates display superior activity and durability in catalyzing oxygen reduction reaction, mainly due to the larger lattice tensile effect in Pd shell induced by the Au core and Ag removal. PMID:26144550

  19. Electrochemical Deposition and Re-oxidation of Au at Highly Oriented Pyrolytic Graphite. Stabilization of Au Nanoparticles on the Upper Plane of Step Edges

    SciTech Connect

    Pinhero, Patrick Joseph; Lister, Tedd Edward; Boxley, Chett J.; White, Henry S.

    2003-10-01

    The electrochemical deposition and reoxidation of Au on the basal plane of highly oriented pyrolytic graphite (HOPG) immersed in a 5 mM AuCl4-/6 M LiCl solution is reported. Scanning electron microscopy (SEM) and ex-situ atomic force microscopy (AFM) demonstrate that Au nanoparticles, ~3.3 nm in height and ~10 nm in diameter, are deposited at times less than ~1 s. The density of nanoparticles, 6 × 109 cm-2, is of the same order of magnitude as the surface point defect density, suggesting that point defects act as nucleation sites for Au electrodeposition. A small subset of the Au nanoparticles (~7%) continues to grow between 1 and 50 s, reaching a height of ~150 nm and a diameter of ~300 nm. At times greater than 50 s, the larger particles coalesce to yield a surface comprised of a low density (~2 × 106 cm-2) of micrometer-size Au crystallites surrounded by Au nanoparticles. Double potential step chronocoulometric experiments demonstrate that the electrodeposition of Au is chemically irreversible, a finding supported by SEM and AFM observations of Au nanoparticles and larger crystallites on the surface after long periods of reoxidation (>3600 s). Au nanoparticles are observed to be preferentially deposited on the upper plane of step edges, a consequence of the nonuniform surface electron density that results from relaxation of the graphite lattice near steps.

  20. System size dependence of hadron pT spectra in p + p and Au+Au collisions at \\sqrt{s_{NN}} = 200 GeV

    NASA Astrophysics Data System (ADS)

    Khandai, P. K.; Sett, P.; Shukla, P.; Singh, V.

    2014-02-01

    We make a systematic study of transverse momentum (pT) spectra of hadrons produced in p + p and in different centralities of Au+Au collisions at center of mass energy of 200 GeV using phenomenological fit functions. The Tsallis distribution gives a very good description of hadron spectra in p + p collisions with just two parameters but does not produce the same in Au+Au collisions at intermediate pT. To explain the hadron spectra in heavy ion collisions in a wider pT range we propose a modified Tsallis function by introducing an additional parameter that accounts for collective flow. The new analytical function gives a very good description of both mesons and baryons spectra at all centralities of Au+Au collisions in terms of the parameters having a potential physics interpretation. With this modified Tsallis function we study the spectra of pions, kaons, protons, Λ and Ξ- as a function of system size at \\sqrt{s_{NN}} = 200 GeV. The parameter representing transverse flow increases with system size and is found to be more for baryons than that for mesons in central Au+Au collisions. The freeze-out temperature for baryons increases with centrality in Au+Au collisions more rapidly than for mesons.

  1. Synthesis of 4H/fcc-Au@Metal Sulfide Core-Shell Nanoribbons.

    PubMed

    Fan, Zhanxi; Zhang, Xiao; Yang, Jian; Wu, Xue-Jun; Liu, Zhengdong; Huang, Wei; Zhang, Hua

    2015-09-01

    Although great advances on the synthesis of Au-semiconductor heteronanostructures have been achieved, the crystal structure of Au components is limited to the common face-centered cubic (fcc) phase. Herein, we report the synthesis of 4H/fcc-Au@Ag2S core-shell nanoribbon (NRB) heterostructures from the 4H/fcc Au@Ag NRBs via the sulfurization of Ag. Remarkably, the obtained 4H/fcc-Au@Ag2S NRBs can be further converted to a novel class of 4H/fcc-Au@metal sulfide core-shell NRB heterostructures, referred to as 4H/fcc-Au@MS (M = Cd, Pb or Zn), through the cation exchange. We believe that these novel 4H/fcc-Au@metal sulfide NRB heteronanostructures may show some promising applications in catalysis, surface enhanced Raman scattering, solar cells, photothermal therapy, etc.

  2. Asymmetric photoelectric property of transparent TiO2 nanotube films loaded with Au nanoparticles

    NASA Astrophysics Data System (ADS)

    Wang, Hui; Liang, Wei; Liu, Yiming; Zhang, Wanggang; Zhou, Diaoyu; Wen, Jing

    2016-11-01

    Semitransparent composite films of Au loaded TiO2 nanotubes (TNT-Au) were prepared by sputtering Au nanoparticles on highly transparent TiO2 nanotubes films, which were fabricated directly on FTO glasses by anodizing the Ti film sputtered on the FTO glasses. Compared with pure TNT films, the prepared TNT-Au films possessed excellent absorption ability and high photocurrent response and improved photocatalytic activity under visible-light irradiation. It could be concluded that Au nanoparticles played important roles in improving the photoelectrochemical performance of TNT-Au films. Moreover, in this work, both sides of TNT-Au films were researched and compared owing to theirs semitransparency. It was firstly found that the photoelectric activity of TNT-Au composite films with back-side illumination was obviously superior to front-side illumination.

  3. AuRu/AC as an effective catalyst for hydrogenation reactions

    DOE PAGESBeta

    Villa, Alberto; Chan-Thaw, Carine E.; Campisi, Sebastiano; Bianchi, Claudia L.; Wang, Di; Kotula, Paul G.; Kübel, Christian; Prati, Laura

    2015-03-23

    AuRu bimetallic catalysts have been prepared by sequential deposition of Au on Ru or vice versa obtaining different nanostructures: when Ru has been deposited on Au, a Aucore–Rushell has been observed, whereas the deposition of Au on Ru leads to a bimetallic phase with Ru enrichment on the surface. In the latter case, the unexpected Ru enrichment could be attributed to the weak adhesion of Ru on the carbon support, thus allowing Ru particles to diffuse on Au particles. Both structures result very active in catalysing the liquid phase hydrogenolysis of glycerol and levulinic acid but the activity, the selectivitymore » and the stability depend on the structure of the bimetallic nanoparticles. Ru@Au/AC core–shell structure mostly behaved as the monometallic Ru, whereas the presence of bimetallic AuRu phase in Au@Ru/AC provides a great beneficial effect on both activity and stability.« less

  4. Effect of experimental conditions on size control of Au nanoparticles synthesized by atmospheric microplasma electrochemistry.

    PubMed

    Huang, Xunzhi; Li, Yongsheng; Zhong, Xiaoxia

    2014-01-01

    Atmospheric microplasma electrochemistry was utilized to synthesize Au nanoparticles (NPs). The synthesized Au NPs were investigated as a function of reduction current, solution temperature, and stirring (or not) by using ultraviolet-visible (UV-Vis) absorbance and transmission electron microscopy (TEM). It was illustrated that high current promoted the growth of Au NPs with small size, and more Au NPs with large size were synthesized as a rise of temperature. The Au NPs often with small size were synthesized as a result of stirring. The production rate, the electrostatic repulsion, and the residence time of the Au NPs at the interfacial region play an important role in the growth of Au NPs. The results shed light upon the roadmap to control the size and particle size distribution (PSD) of Au NPs synthesized by atmospheric microplasma electrochemistry. PMID:25364315

  5. Polarization properties of fluorescent BSA protected Au25 nanoclusters

    NASA Astrophysics Data System (ADS)

    Raut, Sangram; Chib, Rahul; Rich, Ryan; Shumilov, Dmytro; Gryczynski, Zygmunt; Gryczynski, Ignacy

    2013-03-01

    BSA protected gold nanoclusters (Au25) are attracting a great deal of attention due to their unique spectroscopic properties and possible use in biophysical applications. Although there are reports on synthetic strategies, spectroscopy and applications, little is known about their polarization behavior. In this study, we synthesized the BSA protected Au25 nanoclusters and studied their steady state and time resolved fluorescence properties including polarization behavior in different solvents: glycerol, propylene glycol and water. We demonstrated that the nanocluster absorption spectrum can be separated from the extinction spectrum by subtraction of Rayleigh scattering. The nanocluster absorption spectrum is well approximated by three Gaussian components. By a comparison of the emissions from BSA Au25 clusters and rhodamine B in water, we estimated the quantum yield of nanoclusters to be higher than 0.06. The fluorescence lifetime of BSA Au25 clusters is long and heterogeneous with an average value of 1.84 μs. In glycerol at -20 °C the anisotropy is high, reaching a value of 0.35. However, the excitation anisotropy strongly depends on the excitation wavelengths indicating a significant overlap of the different transition moments. The anisotropy decay in water reveals a correlation time below 0.2 μs. In propylene glycol the measured correlation time is longer and the initial anisotropy depends on the excitation wavelength. BSA Au25 clusters, due to long lifetime and high polarization, can potentially be used in studying large macromolecules such as protein complexes with large molecular weight.BSA protected gold nanoclusters (Au25) are attracting a great deal of attention due to their unique spectroscopic properties and possible use in biophysical applications. Although there are reports on synthetic strategies, spectroscopy and applications, little is known about their polarization behavior. In this study, we synthesized the BSA protected Au25 nanoclusters and

  6. Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI 4AgI] Complexes: C−H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines

    PubMed Central

    Smirnova, Ekaterina S.; Muñoz Molina, José M.; Johnson, Alice; Bandeira, Nuno A. G.; Bo, Carles

    2016-01-01

    Abstract The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [AuI 8] core, and pentanuclear [AuI 4MI] (M=Cu, Ag) complexes is presented. The linear [AuI 4] complex undergoes C−H functionalization of carbonyl compounds under mild reaction conditions. In addition, [AuI 4AgI] catalyzes the carbonylation of primary amines to form ureas under homogeneous conditions with efficiencies higher than those achieved by gold nanoparticles. PMID:27167611

  7. Dependence of SERS enhancement on the chemical composition and structure of Ag/Au hybrid nanoparticles.

    PubMed

    Chaffin, Elise; O'Connor, Ryan T; Barr, James; Huang, Xiaohua; Wang, Yongmei

    2016-08-01

    Noble metal nanoparticles (NPs) such as silver (Ag) and gold (Au) have unique plasmonic properties that give rise to surface enhanced Raman scattering (SERS). Generally, Ag NPs have much stronger plasmonic properties and, hence, provide stronger SERS signals than Au NPs. However, Ag NPs lack the chemical stability and biocompatibility of comparable Au NPs and typically exhibit the most intense plasmonic resonance at wavelengths much shorter than the optimal spectral region for many biomedical applications. To overcome these issues, various experimental efforts have been devoted to the synthesis of Ag/Au hybrid NPs for the purpose of SERS detections. However, a complete understanding on how the SERS enhancement depends on the chemical composition and structure of these nanoparticles has not been achieved. In this study, Mie theory and the discrete dipole approximation have been used to calculate the plasmonic spectra and near-field electromagnetic enhancements of Ag/Au hybrid NPs. In particular, we discuss how the electromagnetic enhancement depends on the mole fraction of Au in Ag/Au alloy NPs and how one may use extinction spectra to distinguish between Ag/Au alloyed NPs and Ag-Au core-shell NPs. We also show that for incident laser wavelengths between ∼410 nm and 520 nm, Ag/Au alloyed NPs provide better electromagnetic enhancement than pure Ag, pure Au, or Ag-Au core-shell structured NPs. Finally, we show that silica-core Ag/Au alloy shelled NPs provide even better performance than pure Ag/Au alloy or pure solid Ag and pure solid Au NPs. The theoretical results presented will be beneficial to the experimental efforts in optimizing the design of Ag/Au hybrid NPs for SERS-based detection methods. PMID:27497571

  8. Dependence of SERS enhancement on the chemical composition and structure of Ag/Au hybrid nanoparticles

    NASA Astrophysics Data System (ADS)

    Chaffin, Elise; O'Connor, Ryan T.; Barr, James; Huang, Xiaohua; Wang, Yongmei

    2016-08-01

    Noble metal nanoparticles (NPs) such as silver (Ag) and gold (Au) have unique plasmonic properties that give rise to surface enhanced Raman scattering (SERS). Generally, Ag NPs have much stronger plasmonic properties and, hence, provide stronger SERS signals than Au NPs. However, Ag NPs lack the chemical stability and biocompatibility of comparable Au NPs and typically exhibit the most intense plasmonic resonance at wavelengths much shorter than the optimal spectral region for many biomedical applications. To overcome these issues, various experimental efforts have been devoted to the synthesis of Ag/Au hybrid NPs for the purpose of SERS detections. However, a complete understanding on how the SERS enhancement depends on the chemical composition and structure of these nanoparticles has not been achieved. In this study, Mie theory and the discrete dipole approximation have been used to calculate the plasmonic spectra and near-field electromagnetic enhancements of Ag/Au hybrid NPs. In particular, we discuss how the electromagnetic enhancement depends on the mole fraction of Au in Ag/Au alloy NPs and how one may use extinction spectra to distinguish between Ag/Au alloyed NPs and Ag-Au core-shell NPs. We also show that for incident laser wavelengths between ˜410 nm and 520 nm, Ag/Au alloyed NPs provide better electromagnetic enhancement than pure Ag, pure Au, or Ag-Au core-shell structured NPs. Finally, we show that silica-core Ag/Au alloy shelled NPs provide even better performance than pure Ag/Au alloy or pure solid Ag and pure solid Au NPs. The theoretical results presented will be beneficial to the experimental efforts in optimizing the design of Ag/Au hybrid NPs for SERS-based detection methods.

  9. Dependence of SERS enhancement on the chemical composition and structure of Ag/Au hybrid nanoparticles.

    PubMed

    Chaffin, Elise; O'Connor, Ryan T; Barr, James; Huang, Xiaohua; Wang, Yongmei

    2016-08-01

    Noble metal nanoparticles (NPs) such as silver (Ag) and gold (Au) have unique plasmonic properties that give rise to surface enhanced Raman scattering (SERS). Generally, Ag NPs have much stronger plasmonic properties and, hence, provide stronger SERS signals than Au NPs. However, Ag NPs lack the chemical stability and biocompatibility of comparable Au NPs and typically exhibit the most intense plasmonic resonance at wavelengths much shorter than the optimal spectral region for many biomedical applications. To overcome these issues, various experimental efforts have been devoted to the synthesis of Ag/Au hybrid NPs for the purpose of SERS detections. However, a complete understanding on how the SERS enhancement depends on the chemical composition and structure of these nanoparticles has not been achieved. In this study, Mie theory and the discrete dipole approximation have been used to calculate the plasmonic spectra and near-field electromagnetic enhancements of Ag/Au hybrid NPs. In particular, we discuss how the electromagnetic enhancement depends on the mole fraction of Au in Ag/Au alloy NPs and how one may use extinction spectra to distinguish between Ag/Au alloyed NPs and Ag-Au core-shell NPs. We also show that for incident laser wavelengths between ∼410 nm and 520 nm, Ag/Au alloyed NPs provide better electromagnetic enhancement than pure Ag, pure Au, or Ag-Au core-shell structured NPs. Finally, we show that silica-core Ag/Au alloy shelled NPs provide even better performance than pure Ag/Au alloy or pure solid Ag and pure solid Au NPs. The theoretical results presented will be beneficial to the experimental efforts in optimizing the design of Ag/Au hybrid NPs for SERS-based detection methods.

  10. Core-shell-like Au sub-nanometer clusters in Er-implanted silica

    NASA Astrophysics Data System (ADS)

    Maurizio, Chiara; Cesca, Tiziana; Perotto, Giovanni; Kalinic, Boris; Michieli, Niccolò; Scian, Carlo; Joly, Yves; Battaglin, Giancarlo; Mazzoldi, Paolo; Mattei, Giovanni

    2015-05-01

    The very early steps of Au metal cluster formation in Er-doped silica have been investigated by high-energy resolution fluorescence-detected X-ray absorption spectroscopy (HERFD-XAS). A combined analysis of the near-edge and extended part of the experimental spectra shows that Au cluster nucleation starts from a few Au and O atoms covalently interconnected, likely in the presence of embryonic Au-Au correlation. The first Au clusters, characterized by a well defined Au-Au coordination distance, form upon 400 °C inert annealing. The estimated upper limit of the Gibbs free energy for the associated heterogeneous nucleation is 0.06 eV per atom, suggesting that the Au nucleation is assisted by matrix defects, most likely non-bridging oxygen atoms. The experimental results indicate that the formed subnanometer Au clusters can be applied as effective core-shell systems in which the Au atoms of the `core' develop a metallic character, whereas the Au atoms in the `shell' can retain a partially covalent bond with O atoms of the silica matrix. High structural disorder at the Au site is found upon neutral annealing at a moderate temperature (600 °C), likely driven by the configurational disorder of the defective silica matrix. A suitable choice of the Au concentration and annealing temperature allows tailoring of the Au cluster size in the sub-nanometer range. The interaction of the Au cluster surface with the surrounding silica matrix is likely responsible for the infrared luminescence previously reported on the same systems.

  11. Biosensors based on the plasmonic properties of Au microhole arrays

    NASA Astrophysics Data System (ADS)

    Live, Ludovic S.; Breault-Turcot, Julien; Bolduc, Olivier; Masson, Jean-Francois

    2011-08-01

    The plasmonic properties of metallic nanoparticles and macroscopic Au film have been thoroughly investigated for the development of biosensors based on surface plasmon resonance (SPR). Nanoparticle based localized surface plasmon resonance (LSPR) is a technique extremely sensitive to molecular adsorbate, whilst conventional SPR based on the Kretschmann configuration (macroscopic smooth Au film) is especially sensitive to bulk refractive index. SPR currently provides the best RI resolution, a measure typically used for comparison of the potential of plasmonic sensor. A technique that could combine high bulk refractive index resolution and high sensitivity to molecular adsorbate would increase the scope of SPR-based technique by providing lower detection limits. A potential solution may exploit micro-structured Au films. However, the plasmonic properties of micropatterned metallic films are still relatively unknown. We have undertaken the study of the plasmonic properties from Au film with features on the order of 1 to 3 μm. Microtriangle and microhole arrays were fabricated by modified nanosphere lithography, consisting of a polymer microsphere mask deposited in a close-packed hexagonal monolayer, etched by oxygen plasma. Etch time controls the diameter of the microhole and the initial microsphere diameter sets the periodicity. Investigation of the SPR properties in the Kretschmann configuration was undertaken using a SPR with a dove prism and a multi-wavelength scanning angle SPR. The sensitivity of SPR with microhole arrays exhibits an improvement by a factor of 3 in comparison to SPR using a smooth Au film. This is accomplished by tuning the angle to near 73 degrees (with a BK7 glass prism). Moreover, the sensitivity to the immobilization of an antibody was improved by at least a factor of 4 as demonstrated with the kinetics of immobilization for IgY, without employing secondary amplification techniques. No modification to the instrumentation is required and

  12. Observation of dynamic water microadsorption on Au surface

    SciTech Connect

    Huang, Xiaokang Gupta, Gaurav; Gao, Weixiang; Tran, Van; Nguyen, Bang; McCormick, Eric; Cui, Yongjie; Yang, Yinbao; Hall, Craig; Isom, Harold

    2014-05-15

    Experimental and theoretical research on water wettability, adsorption, and condensation on solid surfaces has been ongoing for many decades because of the availability of new materials, new detection and measurement techniques, novel applications, and different scales of dimensions. Au is a metal of special interest because it is chemically inert, has a high surface energy, is highly conductive, and has a relatively high melting point. It has wide applications in semiconductor integrated circuitry, microelectromechanical systems, microfluidics, biochips, jewelry, coinage, and even dental restoration. Therefore, its surface condition, wettability, wear resistance, lubrication, and friction attract a lot of attention from both scientists and engineers. In this paper, the authors experimentally investigated Au{sub 2}O{sub 3} growth, wettability, roughness, and adsorption utilizing atomic force microscopy, scanning electron microscopy, reflectance spectrometry, and contact angle measurement. Samples were made using a GaAs substrate. Utilizing a super-hydrophilic Au surface and the proper surface conditions of the surrounding GaAs, dynamic microadsorption of water on the Au surface was observed in a clean room environment. The Au surface area can be as small as 12 μm{sup 2}. The adsorbed water was collected by the GaAs groove structure and then redistributed around the structure. A model was developed to qualitatively describe the dynamic microadsorption process. The effective adsorption rate was estimated by modeling and experimental data. Devices for moisture collection and a liquid channel can be made by properly arranging the wettabilities or contact angles of different materials. These novel devices will be very useful in microfluid applications or biochips.

  13. Graphene/AuNPs/chitosan nanocomposites film for glucose biosensing.

    PubMed

    Shan, Changsheng; Yang, Huafeng; Han, Dongxue; Zhang, Qixian; Ivaska, Ari; Niu, Li

    2010-01-15

    A novel glucose biosensor based on immobilization of glucose oxidase in thin films of chitosan containing nanocomposites of graphene and gold nanoparticles (AuNPs) at a gold electrode was developed. The resulting graphene/AuNPs/chitosan composites film exhibited good electrocatalytical activity toward H(2)O(2) and O(2). The wide linear response to H(2)O(2) ranging from 0.2 to 4.2 mM (R=0.998) at -0.2V, high sensitivity of 99.5 microA mM(-1) cm(-2) and good reproducibility were obtained. The good electrocatalytical activity might be attributed to the synergistic effect of graphene and AuNPs. With glucose oxidase (GOD) as a model, the graphene/AuNPs/GOD/chitosan composite-modified electrode was constructed through a simple casting method. The resulting biosensor exhibited good amperometric response to glucose with linear range from 2 to 10 mM (R=0.999) at -0.2V and from 2 to 14 mM (R=0.999) at 0.5 V, good reproducibility and detection limit of 180 microM. Glucose concentration in human blood was studied preliminarily. From 2.5 to 7.5 mM, the cathodic peak currents of the biosensor decrease linearly with increasing the glucose concentrations. The graphene/AuNPs/GOD/chitosan composites film shows prominent electrochemical response to glucose, which makes a promising application for electrochemical detection of glucose. PMID:19883999

  14. Differences in Catalytic Sites for CO Oxidation and Propylene Epoxidation on Au Nanoparticles

    SciTech Connect

    Lee, W.S.; Stach, E.; Zhang, R.; Akatay, M.C.; Baertsch, C.D.; Ribeiro, F.H.; Delgass, W.N.

    2011-08-29

    Sintering and increased Au loading of Au/TS-1 causes the rate of CO oxidation per mole of Au to increase, whereas that for epoxidation of propylene in O{sub 2} and H{sub 2} decreases. This opposite trend in rate behavior shows that the catalytic sites for the two reactions must be different.

  15. Unique Bonding Properties of the Au36(SR)24 Nanocluster with FCC-Like Core.

    PubMed

    Chevrier, Daniel M; Chatt, Amares; Zhang, Peng; Zeng, Chenjie; Jin, Rongchao

    2013-10-01

    The recent discovery on the total structure of Au36(SR)24, which was converted from biicosahedral Au38(SR)24, represents a surprising finding of a face-centered cubic (FCC)-like core structure in small gold-thiolate nanoclusters. Prior to this finding, the FCC feature was only expected for larger (nano)crystalline gold. Herein, we report results on the unique bonding properties of Au36(SR)24 that are associated with its FCC-like core structure. Temperature-dependent X-ray absorption spectroscopy (XAS) measurements at the Au L3-edge, in association with ab initio calculations, show that the local structure and electronic behavior of Au36(SR)24 are of more molecule-like nature, whereas its icosahedral counterparts such as Au38(SR)24 and Au25(SR)18 are more metal-like. Moreover, site-specific S K-edge XAS studies indicate that the bridging motif for Au36(SR)24 has different bonding behavior from the staple motif from Au38(SR)24. Our findings highlight the important role of "pseudo"-Au4 units within the FCC-like Au28 core in interpreting the bonding properties of Au36(SR)24 and suggest that FCC-like structure in gold thiolate nanoclusters should be treated differently from its bulk counterpart.

  16. Tuning plasmonic and chemical enhancement for SERS detection on graphene-based Au hybrids.

    PubMed

    Liang, Xiu; Liang, BenLiang; Pan, Zhenghui; Lang, Xiufeng; Zhang, Yuegang; Wang, Guangsheng; Yin, Penggang; Guo, Lin

    2015-12-21

    Various graphene-based Au nanocomposites have been developed as surface-enhanced Raman scattering (SERS) substrates recently. However, efficient use of SERS has been impeded by the difficulty of tuning SERS enhancement effects induced from chemical and plasmonic enhancement by different preparation methods of graphene. Herein, we developed graphene-based Au hybrids through physical sputtering gold NPs on monolayer graphene prepared by chemical vapor deposition (CVD) as a CVD-G/Au hybrid, as well as graphene oxide-gold (GO/Au) and reduced-graphene oxide (rGO/Au) hybrids prepared using the chemical in situ crystallization growth method. Plasmonic and chemical enhancements were tuned effectively by simple methods in these as-prepared graphene-based Au systems. SERS performances of CVD-G/Au, rGO/Au and GO/Au showed a gradually monotonic increasing tendency of enhancement factors (EFs) for adsorbed Rhodamine 6G (R6G) molecules, which show clear dependence on chemical bonds between graphene and Au, indicating that the chemical enhancement can be steadily controlled by chemical groups in a graphene-based Au hybrid system. Most notably, we demonstrate that the optimized GO/Au was able to detect biomolecules of adenine, which displayed high sensitivity with a detection limit of 10(-7) M as well as good reproducibility and uniformity. PMID:26575834

  17. Nanoporous Au-based chronocoulometric aptasensor for amplified detection of Pb(2+) using DNAzyme modified with Au nanoparticles.

    PubMed

    Zhang, Chen; Lai, Cui; Zeng, Guangming; Huang, Danlian; Tang, Lin; Yang, Chunping; Zhou, Yaoyu; Qin, Lei; Cheng, Min

    2016-07-15

    The authors herein described an amplified detection strategy employing nanoporous Au (NPG) and gold nanoparticles (AuNPs) to detect Pb(2+) ions in aqueous solution. The thiol modified Pb(2+)-specific DNAzyme was self-assembled onto the surface of the NPG modified electrode for hybridizing with the AuNPs labeled oligonucleotide and for forming the DNA double helix structure. Electrochemical signal, redox charge of hexaammineruthenium(III) chloride (RuHex), was measured by chronocoulometry. Taking advantage of amplification effects of the NPG electrode for increasing the reaction sites of capture probe and DNA-AuNPs complexes for bringing about the adsorption of large numbers of RuHex molecules, this electrochemical sensor could detect Pb(2+) quantitatively, in the range of 0.05-100nM, with a limit of detection as low as 0.012nM. Selectivity measurements revealed that the sensor was specific for Pb(2+) even with interference by high concentrations of other metal ions. This sensor was also used to detect Pb(2+) ions from samples of tap water, river water, and landfill leachate samples spiked with Pb(2+) ions, and the results showed good agreement with the found values determined by an atomic fluorescence spectrometer. This simple aptasensor represented a promising potential for on-site detecting Pb(2+) in drinking water. PMID:26921553

  18. Strong non-linear effects in the chiroptical properties of the ligand-exchanged Au38 and Au40 clusters.

    PubMed

    Knoppe, Stefan; Dass, Amala; Bürgi, Thomas

    2012-07-21

    Ligand exchange reactions on size-selected Au(38)(2-PET)(24) and Au(40)(2-PET)(24) clusters (2-PET: 2-phenylethylthiol) with mono- and bi-dentate chiral thiols were performed. The reactions were monitored with MALDI mass spectrometry and the arising chiroptical properties were compared to the number of incorporated chiral ligands. Only a small fraction of chiral ligands is needed to induce significant optical activity to the clusters. The use of bidentate 1,1'-binaphthyl-2,2'-dithiol (BINAS) leads to slow exchange, but the optical activity measured is strong. Moreover, a non-linear behaviour between optical activity and the number of chiral ligands is found in the BINAS case for both Au(38) and Au(40), which may indicate different exchange rates of enantiopure BINAS with the enantiomers of inherently chiral (but racemic) clusters. This is ascribed to effects arising from the bidentate nature of BINAS. In contrast, the use of monodentate camphor-10-thiol (CamSH) leads to comparably fast exchange on both clusters. The arising optical activity is weak. This is the first study where chiroptical effects are directly correlated with the composition of the ligand shell. PMID:22653001

  19. Neutral pion production in Au+Au collisions at {radical}(s{sub NN})=200 GeV

    SciTech Connect

    Abelev, B. I.; Barannikova, O.; Betts, R. R.; Garcia-Solis, E. J.; Hofman, D. J.; Hollis, R. S.; Iordanova, A.; Kauder, K.; Suarez, M. C.; Aggarwal, M. M.; Bhati, A. K.; Kumar, L.; Pruthi, N. K.; Ahammed, Z.; Chattopadhyay, S.; Mazumdar, M. R. Dutta; Ganti, M. S.; Ghosh, P.; Mohanty, B.; Nayak, T. K.

    2009-10-15

    The results of midrapidity (0Au+Au collisions, measured by the STAR experiment, are presented. The neutral pions are reconstructed from photons measured either by the STAR Barrel Electro-Magnetic Calorimeter or by the Time Projection Chamber via tracking of conversion electron-positron pairs. Our measurements are compared to previously published {pi}{sup {+-}} and {pi}{sup 0} results. The nuclear modification factors R{sub CP} and R{sub AA} of {pi}{sup 0} are also presented as a function of p{sub T}. In the most central Au+Au collisions, the binary collision scaled {pi}{sup 0} yield at high p{sub T} is suppressed by a factor of about 5 compared to the expectation from the yield of p+p collisions. Such a large suppression is in agreement with previous observations for light quark mesons and is consistent with the scenario that partons suffer considerable energy loss in the dense medium formed in central nucleus-nucleus collisions at the Relativistic Heavy Ion Collider.

  20. Neutral pion production in Au+Au collisions at {radical}{ovr s}{sub NN} = 200 GeV.

    SciTech Connect

    Abelev, B. I.; Aggarwal, M. M.; Ahammed, Z.; Alakhverdyants, A. V.; Anderson, B. D.; Krueger, K.; Spinka, H. M.; Underwood, D. G.; STAR Collaboration; High Energy Physics; Univ. of Illinois at Chicago; Panjab Univ.; Variable Energy Cyclotron Centre; Joint Inst. for Nuclear Research; Kent State Univ.

    2009-10-01

    The results of midrapidity (0 < y < 0.8) neutral pion spectra over an extended transverse momentum range (1 < p{sub T} < 12 GeV/c) in {radical}{ovr s}{sub NN} = 200 GeV Au+Au collisions, measured by the STAR experiment, are presented. The neutral pions are reconstructed from photons measured either by the STAR Barrel Electro-Magnetic Calorimeter or by the Time Projection Chamber via tracking of conversion electron-positron pairs. Our measurements are compared to previously published {pi}{sup {+-}} and {pi}{sup 0} results. The nuclear modification factors R{sub CP} and R{sub AA} of {pi}{sup 0} are also presented as a function of p{sub T}. In the most central Au+Au collisions, the binary collision scaled {pi}{sup 0} yield at high p{sub T} is suppressed by a factor of about 5 compared to the expectation from the yield of p+p collisions. Such a large suppression is in agreement with previous observations for light quark mesons and is consistent with the scenario that partons suffer considerable energy loss in the dense medium formed in central nucleus-nucleus collisions at the Relativistic Heavy Ion Collider.

  1. Neutral Pion Production in Au+Au Collisions at sqrt sNN = 200 GeV

    SciTech Connect

    STAR Collaboration; Abelev, B. I.

    2009-10-23

    The results of mid-rapidity (0 < y < 0.8) neutral pion spectra over an extended transverse momentum range (1 < p{sub T} < 12 GeV/c) in {radical}s{sub NN} = 200 GeV Au+Au collisions, measured by the STAR experiment, are presented. The neutral pions are reconstructed from photons measured either by the STAR Barrel Electro-Magnetic Calorimeter (BEMC) or by the Time Projection Chamber (TPC) via tracking of conversion electron-positron pairs. Our measurements are compared to previously published {pi}{sup {+-}} and {pi}{sup 0} results. The nuclear modification factors R{sub CP} and R{sub AA} of {pi}{sup 0} are also presented as a function of p{sub T}. In the most central Au+Au collisions, the binary collision scaled {pi}{sup 0} yield at high p{sub T} is suppressed by a factor of about 5 compared to the expectation from the yield of p+p collisions. Such a large suppression is in agreement with previous observations for light quark mesons and is consistent with the scenario that partons suffer considerable energy loss in the dense medium formed in central nucleus-nucleus collisions at RHIC.

  2. Energy Loss and Flow of Heavy Quarks in Au + Au Collisions at sqrt(s_NN) = 200 GeV

    SciTech Connect

    Awes, Terry C; Batsouli, Sotiria; Cianciolo, Vince; Efremenko, Yuri; Plasil, F; Read Jr, Kenneth F; Silvermyr, David O; Sorensen, Soren P; Stankus, Paul W; Young, Glenn R; Zhang, Chun; PHENIX, Collaboration

    2007-04-01

    The PHENIX experiment at the BNL Relativistic Heavy Ion Collider (RHIC) has measured electrons with 0.3Au+Au collisions at {radical}(s{sub NN})=200 GeV. The nuclear modification factor R{sub AA} relative to p+p collisions shows a strong suppression in central Au+Au collisions, indicating substantial energy loss of heavy quarks in the medium produced at RHIC energies. A large azimuthal anisotropy v2 with respect to the reaction plane is observed for 0.5

  3. Energy Lossand Flow of Heavy Quarks in Au+Au Collisions at root-s=200GeV

    SciTech Connect

    Soltz, R; Klay, J; Enokizono, A; Newby, J; Heffner, M; Hartouni, E

    2007-02-26

    The PHENIX experiment at the Relativistic Heavy Ion Collider (RHIC) has measured electrons with 0.3 < p{sub rmT} < 9 GeV/c at midrapidity (|y| < 0.35) from heavy flavor (charm and bottom) decays in Au+Au collisions at {radical}s{sub NN} = 200 GeV. The nuclear modification factor R{sub AA} relative to p+p collisions shows a strong suppression in central Au+Au collisions, indicating substantial energy loss of heavy quarks in the medium produced at RHIC energies. A large azimuthal anisotropy, v{sub 2}, with respect to the reaction plane is observed for 0.5 < p{sub rmT} < 5 GeV/c indicating non-zero heavy flavor elliptic flow. A simultaneous description of R{sub AA}(p{sub rmT}) and v{sub 2}(p{sub rmT}) constrains the existing models of heavy-quark rescattering in strongly interacting matter and provides information on the transport properties of the produced medium. In particular, a viscosity to entropy density ratio close to the conjectured quantum lower bound, i.e. near a perfect fluid, is suggested.

  4. Correlated Production of Protons and Antiprotons in Au + Au Collisions at sqrt(s_NN) = 200 GeV

    SciTech Connect

    Awes, Terry C; Batsouli, Sotiria; Cianciolo, Vince; Efremenko, Yuri; Plasil, F; Read Jr, Kenneth F; Silvermyr, David O; Sorensen, Soren P; Stankus, Paul W; Young, Glenn R; Zhang, Chun; PHENIX, Collaboration

    2007-04-01

    Correlations between p and {anti p} at transverse momenta typical of enhanced baryon production in Au + Au collisions are reported. The PHENIX experiment has measured same and opposite sign baryon pairs in Au + Au collisions at {radical}{ovr S{sub NN}} = 200 GeV. Correlated production of proton and {anti p} with the trigger particle from the range 2.5 < p{sub T} < 4.0 GeV/c and the associated particle with 1.8 < p{sub T} < 2.5 GeV/c is observed to be nearly independent of the centrality of the collisions. Same sign pairs show no correlation at any centrality. The conditional yield of mesons triggered by baryons (and anti-baryons) and mesons in the same p{sub T} range rises with increasing centrality, except for the most central collisions, where baryons show a significantly smaller number of associated mesons. These data are consistent with a picture in which hard scattered partons produce correlated p and {anti p} in the p{sub T} region of the baryon excess.

  5. Binding of Trivalent Arsenic onto the Tetrahedral Au20 and Au19Pt Clusters: Implications in Adsorption and Sensing.

    PubMed

    Cortés-Arriagada, Diego; Oyarzún, María Paz; Sanhueza, Luis; Toro-Labbé, Alejandro

    2015-07-01

    The interaction of arsenic(III) onto the tetrahedral Au20 cluster was studied computationally to get insights into the interaction of arsenic traces (presented in polluted waters) onto embedded electrodes with gold nanostructures. Pollutant interactions onto the vertex, edge, or inner gold atoms of Au20 were observed to have a covalent character by forming metal-arsenic or metal-oxygen bonding, with adsorption energies ranging from 0.5 to 0.8 eV, even with a stable physisorption; however, in aqueous media, the Au-vertex-pollutant interaction was found to be disadvantageous. The substituent effect of a platinum atom onto the Au20 cluster was evaluated to get insights into the changes in the adsorption and electronic properties of the adsorbent-adsorbate systems due to chemical doping. It was found that the dopant atom increases both the metal-pollutant adsorption energy and stability onto the support in a water media for all interaction modes; adsorption energies were found to be in a range of 0.6 to 1.8 eV. All interactions were determined to be accompanied by electron transfer as well as changes in the local reactivity that determine the amount of transferred charge and a decrease in the HOMO-LUMO energy gap with respect to the isolated substrate.

  6. Numerical simulations of high-speed solar wind streams within 1 AU and their signatures at 1 AU

    NASA Technical Reports Server (NTRS)

    Smith, Z.; Dryer, M.

    1991-01-01

    A parametric study of the evolution within, and signatures at, 1 AU of high-speed streams is performed with the use of a MHD two-and-a-half-dimensional time-dependent model. This study is an extension of an earlier one by Smith and Dryer (1990) who examined the ecliptic plane consequences of relatively short-duration, energetic solar disturbances. The present study examines both the erupting and corotating parts of long-duration, high-speed streams characteristic of coronal hole flows. By examining the variation of the simulated plasma velocity, density, temperature, and magnetic field at 1 AU, as well as the location of the solar coronal hole sources relative to the observer at 1 AU, it was possible to provide some insight into the identification of the solar sources of interplanetary disturbances. Two definitions for angle locating the solar source of interplanetary disturbances at 1 AU are presented and discussed. The results are applied to the suggestion by Hewish (1988) that low-latitude coronal holes are suitably positioned to be the sources of major geomagnetic storms when the holes are in the eastern half of the solar hemisphere at the time of the commencement of the storm. The results indicate that, for these cases, the streams emanating from within the hole must be very fast, greater than 1000 km/s, or very wide, greater than 60 deg, at the inner boundary of 18 solar radii.

  7. AuPd alloy formation in Au-Pd/Al 2O 3 catalysts and its role on aromatics hydrogenation

    NASA Astrophysics Data System (ADS)

    Pawelec, B.; Venezia, A. M.; La Parola, V.; Cano-Serrano, E.; Campos-Martin, J. M.; Fierro, J. L. G.

    2005-04-01

    Alumina-supported bimetallic Au-Pd catalysts were prepared by the simultaneous reduction of palladium and gold precursors by ethanol in the presence of the polyvinylpyrrolidone (PVP) and classical incipient wetness co-impregnation method (iwi). The catalysts were characterized by a variety of techniques (AAS, N 2 adsorption-desorption, XRD, TEM, CO chemisorption, TGA, FTIR-CO, DRIFTS-NH 3, and XPS). According to X-ray diffraction measurements and FTIR-CO spectra, an AuPd alloy formed on the sample prepared by the PVP method, whereas distinct phases of gold and palladium metals formed on the iwi samples. The effect of the presence of the AuPd alloy on the catalytic activity was investigated in the simultaneous hydrogenation (HYD) of toluene (T) and naphthalene (NP) in the presence of dibenzothiophene (DBT) at P = 5.0 MPa, T = 523 K, WHSV = 41.2 h -1. Under the selected conditions, all the catalysts were resistant to poisoning with 113 ppm of S (as DBT). The enhancement in activity observed for the sample prepared by PVP method as compared to those prepared by impregnation is related to the geometric effect resulting from the dilution of the Pd ensemble in the AuPd alloy and also to the presence of smaller Pd 0 particles.

  8. Binding of Trivalent Arsenic onto the Tetrahedral Au20 and Au19Pt Clusters: Implications in Adsorption and Sensing.

    PubMed

    Cortés-Arriagada, Diego; Oyarzún, María Paz; Sanhueza, Luis; Toro-Labbé, Alejandro

    2015-07-01

    The interaction of arsenic(III) onto the tetrahedral Au20 cluster was studied computationally to get insights into the interaction of arsenic traces (presented in polluted waters) onto embedded electrodes with gold nanostructures. Pollutant interactions onto the vertex, edge, or inner gold atoms of Au20 were observed to have a covalent character by forming metal-arsenic or metal-oxygen bonding, with adsorption energies ranging from 0.5 to 0.8 eV, even with a stable physisorption; however, in aqueous media, the Au-vertex-pollutant interaction was found to be disadvantageous. The substituent effect of a platinum atom onto the Au20 cluster was evaluated to get insights into the changes in the adsorption and electronic properties of the adsorbent-adsorbate systems due to chemical doping. It was found that the dopant atom increases both the metal-pollutant adsorption energy and stability onto the support in a water media for all interaction modes; adsorption energies were found to be in a range of 0.6 to 1.8 eV. All interactions were determined to be accompanied by electron transfer as well as changes in the local reactivity that determine the amount of transferred charge and a decrease in the HOMO-LUMO energy gap with respect to the isolated substrate. PMID:26061641

  9. Publicizing Public-School Realities for Survival

    ERIC Educational Resources Information Center

    Cook, Glenn

    2004-01-01

    In characterizing urban public schools, the public does not appreciate that the complexities of urban education cannot be reduced to a few short facts. Instead, the public often works from perception based on nostalgia, rumor, and what is on the newspapers and on television. In this paper, the author discusses public school realities in an effort…

  10. Glucose-functionalized Au nanoprisms for optoacoustic imaging and near-infrared photothermal therapy

    NASA Astrophysics Data System (ADS)

    Han, Jishu; Zhang, Jingjing; Yang, Meng; Cui, Daxiang; de La Fuente, Jesus M.

    2015-12-01

    Targeted imaging and tumor therapy using nanomaterials has stimulated research interest recently, but the high cytotoxicity and low cellular uptake of nanomaterials limit their bioapplication. In this paper, glucose (Glc) was chosen to functionalize Au nanoprisms (NPrs) for improving the cytotoxicity and cellular uptake of Au@PEG-Glc NPrs into cancer cells. Glucose is a primary source of energy at the cellular level and at cellular membranes for cell recognition. A coating of glucose facilitates the accumulation of Au@PEG-Glc NPrs in a tumor region much more than Au@PEG NPrs. Due to the high accumulation and excellent photoabsorbing property of Au@PEG-Glc NPrs, enhanced optoacoustic imaging of a tumor in vivo was achieved, and visualization of the tumor further guided cancer treatment. Based on the optical-thermal conversion performance of Au@PEG-Glc NPrs, the tumor in vivo was effectively cured through photothermal therapy. The current work demonstrates the great potential of Au@PEG-Glc NPrs in optoacoustic imaging and photothermal cancer therapy in future.Targeted imaging and tumor therapy using nanomaterials has stimulated research interest recently, but the high cytotoxicity and low cellular uptake of nanomaterials limit their bioapplication. In this paper, glucose (Glc) was chosen to functionalize Au nanoprisms (NPrs) for improving the cytotoxicity and cellular uptake of Au@PEG-Glc NPrs into cancer cells. Glucose is a primary source of energy at the cellular level and at cellular membranes for cell recognition. A coating of glucose facilitates the accumulation of Au@PEG-Glc NPrs in a tumor region much more than Au@PEG NPrs. Due to the high accumulation and excellent photoabsorbing property of Au@PEG-Glc NPrs, enhanced optoacoustic imaging of a tumor in vivo was achieved, and visualization of the tumor further guided cancer treatment. Based on the optical-thermal conversion performance of Au@PEG-Glc NPrs, the tumor in vivo was effectively cured through

  11. Scaling properties of azimuthal anisotropy in Au+Au and Cu+Cu Collisions at sqrt[s NN]=200 GeV.

    PubMed

    Adare, A; Afanasiev, S; Aidala, C; Ajitanand, N N; Akiba, Y; Al-Bataineh, H; Alexander, J; Al-Jamel, A; Aoki, K; Aphecetche, L; Armendariz, R; Aronson, S H; Asai, J; Atomssa, E T; Averbeck, R; Awes, T C; Azmoun, B; Babintsev, V; Baksay, G; Baksay, L; Baldisseri, A; Barish, K N; Barnes, P D; Bassalleck, B; Bathe, S; Batsouli, S; Baublis, V; Bauer, F; Bazilevsky, A; Belikov, S; Bennett, R; Berdnikov, Y; Bickley, A A; Bjorndal, M T; Boissevain, J G; Borel, H; Boyle, K; Brooks, M L; Brown, D S; Bucher, D; Buesching, H; Bumazhnov, V; Bunce, G; Burward-Hoy, J M; Butsyk, S; Campbell, S; Chai, J-S; Chang, B S; Charvet, J-L; Chernichenko, S; Chiba, J; Chi, C Y; Chiu, M; Choi, I J; Chujo, T; Chung, P; Churyn, A; Cianciolo, V; Cleven, C R; Cobigo, Y; Cole, B A; Comets, M P; Constantin, P; Csanád, M; Csörgo, T; Dahms, T; Das, K; David, G; Deaton, M B; Dehmelt, K; Delagrange, H; Denisov, A; d'Enterria, D; Deshpande, A; Desmond, E J; Dietzsch, O; Dion, A; Donadelli, M; Drachenberg, J L; Drapier, O; Drees, A; Dubey, A K; Durum, A; Dzhordzhadze, V; Efremenko, Y V; Egdemir, J; Ellinghaus, F; Emam, W S; Enokizono, A; En'yo, H; Espagnon, B; Esumi, S; Eyser, K O; Fields, D E; Finger, M; Finger, M; Fleuret, F; Fokin, S L; Forestier, B; Fraenkel, Z; Frantz, J E; Franz, A; Frawley, A D; Fujiwara, K; Fukao, Y; Fung, S-Y; Fusayasu, T; Gadrat, S; Garishvili, I; Gastineau, F; Germain, M; Glenn, A; Gong, H; Gonin, M; Gosset, J; Goto, Y; Granier de Cassagnac, R; Grau, N; Greene, S V; Grosse Perdekamp, M; Gunji, T; Gustafsson, H-A; Hachiya, T; Hadj Henni, A; Haegemann, C; Haggerty, J S; Hagiwara, M N; Hamagaki, H; Han, R; Harada, H; Hartouni, E P; Haruna, K; Harvey, M; Haslum, E; Hasuko, K; Hayano, R; Heffner, M; Hemmick, T K; Hester, T; Heuser, J M; He, X; Hiejima, H; Hill, J C; Hobbs, R; Hohlmann, M; Holmes, M; Holzmann, W; Homma, K; Hong, B; Horaguchi, T; Hornback, D; Hur, M G; Ichihara, T; Imai, K; Inaba, M; Inoue, Y; Isenhower, D; Isenhower, L; Ishihara, M; Isobe, T; Issah, M; Isupov, A; Jacak, B V; Jia, J; Jin, J; Jinnouchi, O; Johnson, B M; Joo, K S; Jouan, D; Kajihara, F; Kametani, S; Kamihara, N; Kamin, J; Kaneta, M; Kang, J H; Kano, H; Kanou, H; Kawagishi, T; Kawall, D; Kazantsev, A V; Kelly, S; Khanzadeev, A; Kikuchi, J; Kim, D H; Kim, D J; Kim, E; Kim, Y-S; Kinney, E; Kiss, A; Kistenev, E; Kiyomichi, A; Klay, J; Klein-Boesing, C; Kochenda, L; Kochetkov, V; Komkov, B; Konno, M; Kotchetkov, D; Kozlov, A; Král, A; Kravitz, A; Kroon, P J; Kubart, J; Kunde, G J; Kurihara, N; Kurita, K; Kweon, M J; Kwon, Y; Kyle, G S; Lacey, R; Lai, Y-S; Lajoie, J G; Lebedev, A; Le Bornec, Y; Leckey, S; Lee, D M; Lee, M K; Lee, T; Leitch, M J; Leite, M A L; Lenzi, B; Lim, H; Liska, T; Litvinenko, A; Liu, M X; Li, X; Li, X H; Love, B; Lynch, D; Maguire, C F; Makdisi, Y I; Malakhov, A; Malik, M D; Manko, V I; Mao, Y; Masek, L; Masui, H; Matathias, F; McCain, M C; McCumber, M; McGaughey, P L; Miake, Y; Mikes, P; Miki, K; Miller, T E; Milov, A; Mioduszewski, S; Mishra, G C; Mishra, M; Mitchell, J T; Mitrovski, M; Morreale, A; Morrison, D P; Moss, J M; Moukhanova, T V; Mukhopadhyay, D; Murata, J; Nagamiya, S; Nagata, Y; Nagle, J L; Naglis, M; Nakagawa, I; Nakamiya, Y; Nakamura, T; Nakano, K; Newby, J; Nguyen, M; Norman, B E; Nyanin, A S; Nystrand, J; O'Brien, E; Oda, S X; Ogilvie, C A; Ohnishi, H; Ojha, I D; Okada, H; Okada, K; Oka, M; Omiwade, O O; Oskarsson, A; Otterlund, I; Ouchida, M; Ozawa, K; Pak, R; Pal, D; Palounek, A P T; Pantuev, V; Papavassiliou, V; Park, J; Park, W J; Pate, S F; Pei, H; Peng, J-C; Pereira, H; Peresedov, V; Peressounko, D Yu; Pinkenburg, C; Pisani, R P; Purschke, M L; Purwar, A K; Qu, H; Rak, J; Rakotozafindrabe, A; Ravinovich, I; Read, K F; Rembeczki, S; Reuter, M; Reygers, K; Riabov, V; Riabov, Y; Roche, G; Romana, A; Rosati, M; Rosendahl, S S E; Rosnet, P; Rukoyatkin, P; Rykov, V L; Ryu, S S; Sahlmueller, B; Saito, N; Sakaguchi, T; Sakai, S; Sakata, H; Samsonov, V; Sato, H D; Sato, S; Sawada, S; Seele, J; Seidl, R; Semenov, V; Seto, R; Sharma, D; Shea, T K; Shein, I; Shevel, A; Shibata, T-A; Shigaki, K; Shimomura, M; Shohjoh, T; Shoji, K; Sickles, A; Silva, C L; Silvermyr, D; Silvestre, C; Sim, K S; Singh, C P; Singh, V; Skutnik, S; Slunecka, M; Smith, W C; Soldatov, A; Soltz, R A; Sondheim, W E; Sorensen, S P; Sourikova, I V; Staley, F; Stankus, P W; Stenlund, E; Stepanov, M; Ster, A; Stoll, S P; Sugitate, T; Suire, C; Sullivan, J P; Sziklai, J; Tabaru, T; Takagi, S; Takagui, E M; Taketani, A; Tanaka, K H; Tanaka, Y; Tanida, K; Tannenbaum, M J; Taranenko, A; Tarján, P; Thomas, T L; Togawa, M; Toia, A; Tojo, J; Tomásek, L; Torii, H; Towell, R S; Tram, V-N; Tserruya, I; Tsuchimoto, Y; Tuli, S K; Tydesjö, H; Tyurin, N; Vale, C; Valle, H; van Hecke, H W; Velkovska, J; Vertesi, R; Vinogradov, A A; Virius, M; Vrba, V; Vznuzdaev, E; Wagner, M; Walker, D; Wang, X R; Watanabe, Y; Wessels, J; White, S N; Willis, N; Winter, D; Woody, C L; Wysocki, M; Xie, W; Yamaguchi, Y L; Yanovich, A; Yasin, Z; Ying, J; Yokkaichi, S; Young, G R; Younus, I; Yushmanov, I E; Zajc, W A; Zaudtke, O; Zhang, C; Zhou, S; Zimányi, J; Zolin, L

    2007-04-20

    Differential measurements of elliptic flow (v2) for Au+Au and Cu+Cu collisions at sqrt[sNN]=200 GeV are used to test and validate predictions from perfect fluid hydrodynamics for scaling of v2 with eccentricity, system size, and transverse kinetic energy (KE T). For KE T identical with mT-m up to approximately 1 GeV the scaling is compatible with hydrodynamic expansion of a thermalized fluid. For large values of KE T mesons and baryons scale separately. Quark number scaling reveals a universal scaling of v2 for both mesons and baryons over the full KE T range for Au+Au. For Au+Au and Cu+Cu the scaling is more pronounced in terms of KE T, rather than transverse momentum.

  12. Observation of D0 meson nuclear modifications in Au+Au collisions at sqrt[s(NN)] = 200 GeV.

    PubMed

    Adamczyk, L; Adkins, J K; Agakishiev, G; Aggarwal, M M; Ahammed, Z; Alekseev, I; Alford, J; Anson, C D; Aparin, A; Arkhipkin, D; Aschenauer, E C; Averichev, G S; Banerjee, A; Beavis, D R; Bellwied, R; Bhasin, A; Bhati, A K; Bhattarai, P; Bichsel, H; Bielcik, J; Bielcikova, J; Bland, L C; Bordyuzhin, I G; Borowski, W; Bouchet, J; Brandin, A V; Brovko, S G; Bültmann, S; Bunzarov, I; Burton, T P; Butterworth, J; Caines, H; Calderón de la Barca Sánchez, M; Cebra, D; Cendejas, R; Cervantes, M C; Chaloupka, P; Chang, Z; Chattopadhyay, S; Chen, H F; Chen, J H; Chen, L; Cheng, J; Cherney, M; Chikanian, A; Christie, W; Chwastowski, J; Codrington, M J M; Contin, G; Cramer, J G; Crawford, H J; Cui, X; Das, S; Davila Leyva, A; De Silva, L C; Debbe, R R; Dedovich, T G; Deng, J; Derevschikov, A A; Derradi de Souza, R; Dhamija, S; di Ruzza, B; Didenko, L; Dilks, C; Ding, F; Djawotho, P; Dong, X; Drachenberg, J L; Draper, J E; Du, C M; Dunkelberger, L E; Dunlop, J C; Efimov, L G; Engelage, J; Engle, K S; Eppley, G; Eun, L; Evdokimov, O; Eyser, O; Fatemi, R; Fazio, S; Fedorisin, J; Filip, P; Finch, E; Fisyak, Y; Flores, C E; Gagliardi, C A; Gangadharan, D R; Garand, D; Geurts, F; Gibson, A; Girard, M; Gliske, S; Greiner, L; Grosnick, D; Gunarathne, D S; Guo, Y; Gupta, A; Gupta, S; Guryn, W; Haag, B; Hamed, A; Han, L-X; Haque, R; Harris, J W; Heppelmann, S; Hirsch, A; Hoffmann, G W; Hofman, D J; Horvat, S; Huang, B; Huang, H Z; Huang, X; Huck, P; Humanic, T J; Igo, G; Jacobs, W W; Jang, H; Judd, E G; Kabana, S; Kalinkin, D; Kang, K; Kauder, K; Ke, H W; Keane, D; Kechechyan, A; Kesich, A; Khan, Z H; Kikola, D P; Kisel, I; Kisiel, A; Koetke, D D; Kollegger, T; Konzer, J; Koralt, I; Kotchenda, L; Kraishan, A F; Kravtsov, P; Krueger, K; Kulakov, I; Kumar, L; Kycia, R A; Lamont, M A C; Landgraf, J M; Landry, K D; Lauret, J; Lebedev, A; Lednicky, R; Lee, J H; LeVine, M J; Li, C; Li, W; Li, X; Li, X; Li, Y; Li, Z M; Lisa, M A; Liu, F; Ljubicic, T; Llope, W J; Lomnitz, M; Longacre, R S; Luo, X; Ma, G L; Ma, Y G; Madagodagettige Don, D M M D; Mahapatra, D P; Majka, R; Margetis, S; Markert, C; Masui, H; Matis, H S; McDonald, D; McShane, T S; Minaev, N G; Mioduszewski, S; Mohanty, B; Mondal, M M; Morozov, D A; Mustafa, M K; Nandi, B K; Nasim, Md; Nayak, T K; Nelson, J M; Nigmatkulov, G; Nogach, L V; Noh, S Y; Novak, J; Nurushev, S B; Odyniec, G; Ogawa, A; Oh, K; Ohlson, A; Okorokov, V; Oldag, E W; Olvitt, D L; Pachr, M; Page, B S; Pal, S K; Pan, Y X; Pandit, Y; Panebratsev, Y; Pawlak, T; Pawlik, B; Pei, H; Perkins, C; Peryt, W; Pile, P; Planinic, M; Pluta, J; Poljak, N; Porter, J; Poskanzer, A M; Pruthi, N K; Przybycien, M; Pujahari, P R; Putschke, J; Qiu, H; Quintero, A; Ramachandran, S; Raniwala, R; Raniwala, S; Ray, R L; Riley, C K; Ritter, H G; Roberts, J B; Rogachevskiy, O V; Romero, J L; Ross, J F; Roy, A; Ruan, L; Rusnak, J; Rusnakova, O; Sahoo, N R; Sahu, P K; Sakrejda, I; Salur, S; Sandweiss, J; Sangaline, E; Sarkar, A; Schambach, J; Scharenberg, R P; Schmah, A M; Schmidke, W B; Schmitz, N; Seger, J; Seyboth, P; Shah, N; Shahaliev, E; Shanmuganathan, P V; Shao, M; Sharma, B; Shen, W Q; Shi, S S; Shou, Q Y; Sichtermann, E P; Singaraju, R N; Skoby, M J; Smirnov, D; Smirnov, N; Solanki, D; Sorensen, P; Spinka, H M; Srivastava, B; Stanislaus, T D S; Stevens, J R; Stock, R; Strikhanov, M; Stringfellow, B; Sumbera, M; Sun, X; Sun, X M; Sun, Y; Sun, Z; Surrow, B; Svirida, D N; Symons, T J M; Szelezniak, M A; Takahashi, J; Tang, A H; Tang, Z; Tarnowsky, T; Thomas, J H; Timmins, A R; Tlusty, D; Tokarev, M; Trentalange, S; Tribble, R E; Tribedy, P; Trzeciak, B A; Tsai, O D; Turnau, J; Ullrich, T; Underwood, D G; Van Buren, G; van Nieuwenhuizen, G; Vandenbroucke, M; Vanfossen, J A; Varma, R; Vasconcelos, G M S; Vasiliev, A N; Vertesi, R; Videbæk, F; Viyogi, Y P; Vokal, S; Vossen, A; Wada, M; Wang, F; Wang, G; Wang, H; Wang, J S; Wang, X L; Wang, Y; Wang, Y; Webb, G; Webb, J C; Westfall, G D; Wieman, H; Wissink, S W; Witt, R; Wu, Y F; Xiao, Z; Xie, W; Xin, K; Xu, H; Xu, J; Xu, N; Xu, Q H; Xu, Y; Xu, Z; Yan, W; Yang, C; Yang, Y; Yang, Y; Ye, Z; Yepes, P; Yi, L; Yip, K; Yoo, I-K; Yu, N; Zawisza, Y; Zbroszczyk, H; Zha, W; Zhang, J B; Zhang, J L; Zhang, S; Zhang, X P; Zhang, Y; Zhang, Z P; Zhao, F; Zhao, J; Zhong, C; Zhu, X; Zhu, Y H; Zoulkarneeva, Y; Zyzak, M

    2014-10-01

    We report the first measurement of charmed-hadron (D(0)) production via the hadronic decay channel (D(0) → K(-) + π(+)) in Au+Au collisions at sqrt[s(NN)] = 200 GeV with the STAR experiment. The charm production cross section per nucleon-nucleon collision at midrapidity scales with the number of binary collisions, N(bin), from p+p to central Au+Au collisions. The D(0) meson yields in central Au + Au collisions are strongly suppressed compared to those in p+p scaled by N(bin), for transverse momenta p(T) > 3 GeV/c, demonstrating significant energy loss of charm quarks in the hot and dense medium. An enhancement at intermediate p(T) is also observed. Model calculations including strong charm-medium interactions and coalescence hadronization describe our measurements. PMID:25325635

  13. Growth of long range forward-backward multiplicity correlations with centrality in Au + Au collisions at square root of sNN = 200 GeV.

    PubMed

    Abelev, B I; Aggarwal, M M; Ahammed, Z; Anderson, B D; Arkhipkin, D; Averichev, G S; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Baumgart, S; Beavis, D R; Bellwied, R; Benedosso, F; Betancourt, M J; Betts, R R; Bhasin, A; Bhati, A K; Bichsel, H; Bielcik, J; Bielcikova, J; Biritz, B; Bland, L C; Bombara, M; Bonner, B E; Botje, M; Bouchet, J; Braidot, E; Brandin, A V; Bruna, E; Bueltmann, S; Burton, T P; Bystersky, M; Cai, X Z; Caines, H; Calderón de la Barca Sánchez, M; Catu, O; Cebra, D; Cendejas, R; Cervantes, M C; Chajecki, Z; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, J H; Chen, J Y; Cheng, J; Cherney, M; Chikanian, A; Choi, K E; Christie, W; Clarke, R F; Codrington, M J M; Corliss, R; Cormier, T M; Cosentino, M R; Cramer, J G; Crawford, H J; Das, D; Dash, S; Daugherity, M; De Silva, L C; Dedovich, T G; DePhillips, M; Derevschikov, A A; Derradi de Souza, R; Didenko, L; Djawotho, P; Dogra, S M; Dong, X; Drachenberg, J L; Draper, J E; Du, F; Dunlop, J C; Dutta Mazumdar, M R; Edwards, W R; Efimov, L G; Elhalhuli, E; Elnimr, M; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Eun, L; Fachini, P; Fatemi, R; Fedorisin, J; Feng, A; Filip, P; Finch, E; Fine, V; Fisyak, Y; Gagliardi, C A; Gaillard, L; Gangadharan, D R; Ganti, M S; Garcia-Solis, E J; Geromitsos, A; Geurts, F; Ghazikhanian, V; Ghosh, P; Gorbunov, Y N; Gordon, A; Grebenyuk, O; Grosnick, D; Grube, B; Guertin, S M; Guimaraes, K S F F; Gupta, A; Gupta, N; Guryn, W; Haag, B; Hallman, T J; Hamed, A; Harris, J W; He, W; Heinz, M; Heppelmann, S; Hippolyte, B; Hirsch, A; Hjort, E; Hoffman, A M; Hoffmann, G W; Hofman, D J; Hollis, R S; Huang, H Z; Humanic, T J; Huo, L; Igo, G; Iordanova, A; Jacobs, P; Jacobs, W W; Jakl, P; Jena, C; Jin, F; Jones, C L; Jones, P G; Joseph, J; Judd, E G; Kabana, S; Kajimoto, K; Kang, K; Kapitan, J; Keane, D; Kechechyan, A; Kettler, D; Khodyrev, V Yu; Kikola, D P; Kiryluk, J; Kisiel, A; Knospe, A G; Kocoloski, A; Koetke, D D; Kopytine, M; Korsch, W; Kotchenda, L; Kouchpil, V; Kravtsov, P; Kravtsov, V I; Krueger, K; Krus, M; Kuhn, C; Kumar, L; Kurnadi, P; Lamont, M A C; Landgraf, J M; LaPointe, S; Lauret, J; Lebedev, A; Lednicky, R; Lee, C-H; Lee, J H; Leight, W; Levine, M J; Li, N; Li, C; Li, Y; Lin, G; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, J; Liu, L; Ljubicic, T; Llope, W J; Longacre, R S; Love, W A; Lu, Y; Ludlam, T; Ma, G L; Ma, Y G; Mahapatra, D P; Majka, R; Mall, O I; Mangotra, L K; Manweiler, R; Margetis, S; Markert, C; Matis, H S; Matulenko, Yu A; McShane, T S; Meschanin, A; Milner, R; Minaev, N G; Mioduszewski, S; Mischke, A; Mitchell, J; Mohanty, B; Morozov, D A; Munhoz, M G; Nandi, B K; Nattrass, C; Nayak, T K; Nelson, J M; Netrakanti, P K; Ng, M J; Nogach, L V; Nurushev, S B; Odyniec, G; Ogawa, A; Okada, H; Okorokov, V; Olson, D; Pachr, M; Page, B S; Pal, S K; Pandit, Y; Panebratsev, Y; Pawlak, T; Peitzmann, T; Perevoztchikov, V; Perkins, C; Peryt, W; Phatak, S C; Planinic, M; Pluta, J; Poljak, N; Poskanzer, A M; Potukuchi, B V K S; Prindle, D; Pruneau, C; Pruthi, N K; Pujahari, P R; Putschke, J; Raniwala, R; Raniwala, S; Redwine, R; Reed, R; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevskiy, O V; Romero, J L; Rose, A; Roy, C; Ruan, L; Russcher, M J; Sahoo, R; Sakrejda, I; Sakuma, T; Salur, S; Sandweiss, J; Sarsour, M; Schambach, J; Scharenberg, R P; Schmitz, N; Seger, J; Selyuzhenkov, I; Seyboth, P; Shabetai, A; Shahaliev, E; Shao, M; Sharma, M; Shi, S S; Shi, X-H; Sichtermann, E P; Simon, F; Singaraju, R N; Skoby, M J; Smirnov, N; Snellings, R; Sorensen, P; Sowinski, J; Spinka, H M; Srivastava, B; Stadnik, A; Stanislaus, T D S; Staszak, D; Strikhanov, M; Stringfellow, B; Suaide, A A P; Suarez, M C; Subba, N L; Sumbera, M; Sun, X M; Sun, Y; Sun, Z; Surrow, B; Symons, T J M; Szanto de Toledo, A; Takahashi, J; Tang, A H; Tang, Z; Tarnowsky, T; Thein, D; Thomas, J H; Tian, J; Timmins, A R; Timoshenko, S; Tlusty, D; Tokarev, M; Tram, V N; Trattner, A L; Trentalange, S; Tribble, R E; Tsai, O D; Ulery, J; Ullrich, T; Underwood, D G; Van Buren, G; van Leeuwen, M; Vander Molen, A M; Vanfossen, J A; Varma, R; Vasconcelos, G M S; Vasilevski, I M; Vasiliev, A N; Videbaek, F; Vigdor, S E; Viyogi, Y P; Vokal, S; Voloshin, S A; Wada, M; Walker, M; Wang, F; Wang, G; Wang, J S; Wang, Q; Wang, X; Wang, X L; Wang, Y; Webb, G; Webb, J C; Westfall, G D; Whitten, C; Wieman, H; Wissink, S W; Witt, R; Wu, Y; Xie, W; Xu, N; Xu, Q H; Xu, Y; Xu, Z; Yang, Y; Yepes, P; Yoo, I-K; Yue, Q; Zawisza, M; Zbroszczyk, H; Zhan, W; Zhang, S; Zhang, W M; Zhang, X P; Zhang, Y; Zhang, Z P; Zhao, Y; Zhong, C; Zhou, J; Zoulkarneev, R; Zoulkarneeva, Y; Zuo, J X

    2009-10-23

    Forward-backward multiplicity correlation strengths have been measured with the STAR detector for Au + Au and p + p collisions at square root of s(NN) = 200 GeV. Strong short- and long-range correlations (LRC) are seen in central Au + Au collisions. The magnitude of these correlations decrease with decreasing centrality until only short-range correlations are observed in peripheral Au + Au collisions. Both the dual parton model (DPM) and the color glass condensate (CGC) predict the existence of the long-range correlations. In the DPM, the fluctuation in the number of elementary (parton) inelastic collisions produces the LRC. In the CGC, longitudinal color flux tubes generate the LRC. The data are in qualitative agreement with the predictions of the DPM and indicate the presence of multiple parton interactions. PMID:19905749

  14. Formation of Au and AuSix-Pyramids in Separation by Implanted Oxygen Wafers with Si Pillars in SiO2 Layer

    NASA Astrophysics Data System (ADS)

    Ishikawa, Yukari; Saito, Tomohiro; Sakashita, Mitsuo; Shibata, Noriyoshi; Zaima, Shigeaki

    1995-11-01

    Very small pyramid structures of single-crystal Au and AuSi x 100 nm in size were produced in Si(100) wafers by annealing at 310° C after 100 nm-thick Au film was evaporated onto a thin SOI structure with Si pillars in the SiO2 layer. Surface Au atoms diffuse through Si pillars just under the SiO2 layer and form pyramid structures which are surrounded by one Si(100) and four Si{111} planes. There is no amorphous layer between Si and pyramid crystals. Pyramids are Au or AuSi x single crytals, but crystal directions and structures are different for each pyramid.

  15. Growth of Long Range Forward-Backward Multiplicity Correlations with Centrality in Au+Au Collisions at sqrt sNN = 200 GeV

    SciTech Connect

    STAR Collaboration; Abelev, Betty

    2010-07-05

    Forward-backward multiplicity correlation strengths have been measured with the STAR detector for Au+Au and p+p collisions at {radical}s{sub NN} = 200 GeV. Strong short and long range correlations (LRC) are seen in central Au+Au collisions. The magnitude of these correlations decrease with decreasing centrality until only short range correlations are observed in peripheral Au+Au collisions. Both the Dual Parton Model (DPM) and the Color Glass Condensate (CGC) predict the existence of the long range correlations. In the DPM the fluctuation in the number of elementary (parton) inelastic collisions produces the LRC. In the CGC longitudinal color flux tubes generate the LRC. The data is in qualitative agreement with the predictions from the DPM and indicates the presence of multiple parton interactions.

  16. Tuning plasmonic and chemical enhancement for SERS detection on graphene-based Au hybrids

    NASA Astrophysics Data System (ADS)

    Liang, Xiu; Liang, Benliang; Pan, Zhenghui; Lang, Xiufeng; Zhang, Yuegang; Wang, Guangsheng; Yin, Penggang; Guo, Lin

    2015-11-01

    Various graphene-based Au nanocomposites have been developed as surface-enhanced Raman scattering (SERS) substrates recently. However, efficient use of SERS has been impeded by the difficulty of tuning SERS enhancement effects induced from chemical and plasmonic enhancement by different preparation methods of graphene. Herein, we developed graphene-based Au hybrids through physical sputtering gold NPs on monolayer graphene prepared by chemical vapor deposition (CVD) as a CVD-G/Au hybrid, as well as graphene oxide-gold (GO/Au) and reduced-graphene oxide (rGO/Au) hybrids prepared using the chemical in situ crystallization growth method. Plasmonic and chemical enhancements were tuned effectively by simple methods in these as-prepared graphene-based Au systems. SERS performances of CVD-G/Au, rGO/Au and GO/Au showed a gradually monotonic increasing tendency of enhancement factors (EFs) for adsorbed Rhodamine 6G (R6G) molecules, which show clear dependence on chemical bonds between graphene and Au, indicating that the chemical enhancement can be steadily controlled by chemical groups in a graphene-based Au hybrid system. Most notably, we demonstrate that the optimized GO/Au was able to detect biomolecules of adenine, which displayed high sensitivity with a detection limit of 10-7 M as well as good reproducibility and uniformity.Various graphene-based Au nanocomposites have been developed as surface-enhanced Raman scattering (SERS) substrates recently. However, efficient use of SERS has been impeded by the difficulty of tuning SERS enhancement effects induced from chemical and plasmonic enhancement by different preparation methods of graphene. Herein, we developed graphene-based Au hybrids through physical sputtering gold NPs on monolayer graphene prepared by chemical vapor deposition (CVD) as a CVD-G/Au hybrid, as well as graphene oxide-gold (GO/Au) and reduced-graphene oxide (rGO/Au) hybrids prepared using the chemical in situ crystallization growth method. Plasmonic

  17. Au-supported Pt-Au mixed atomic monolayer electrocatalyst with ultrahigh specific activity for oxidation of formic acid in acidic solution.

    PubMed

    Huang, Zhao; Liu, Yan; Xie, Fangyun; Fu, Yingchun; He, Yong; Ma, Ming; Xie, Qingji; Yao, Shouzhuo

    2012-12-25

    Au-supported Pt-Au mixed atomic monolayer electrocatalyst was prepared by underpotential deposition of Cu on Au and then redox replacement with noble metal atoms, which shows an ultrahigh Pt-mass (or Pt-area) normalized specific electrocatalytic activity of 102 mA μg(Pt)(-1) (124 mA cm(Pt)(-2)) for oxidation of formic acid in acidic aqueous solution.

  18. Evidence of chitosan-mediated reduction of Au(III) to Au(0) nanoparticles under electron beam by using OH˙ and e⁻(aq) scavengers.

    PubMed

    Dang Nguyen Vô, Khoa; Kowandy, Christelle; Dupont, Laurent; Coqueret, Xavier

    2015-03-01

    Selective scavengers of e(-)(aq) and OH˙ radicals were used to investigate the radiolytic synthesis of gold nanoparticles from Au(III) solutions in the presence of chitosan. This reaction does not exclusively follow the direct reduction by solvated electrons. Irradiation generates short-lived and long-lived reductive species derived from chitosan that efficiently convert Au(III) into Au(0) which aggregates to form clusters.

  19. The Influence of Interstitial Ga and Interfacial Au (sub 2)P (sub 3) on the Electrical and Metallurgical Behavior of Au-Contacted III-V Semiconductors

    NASA Technical Reports Server (NTRS)

    Weizer, Victor G.; Fatemi, Navid S.

    1991-01-01

    The introduction of a very small amount of Ga into Au contact metallization on InP is shown to have a significant effect on both the metallurgical and electrical behavior of that contact system. Ga atoms in the interstices of the Au lattice are shown to be effective in preventing the solid state reactions that normally take place between Au and InP during contact sintering. In addition to suppressing the metallurgical interaction, the presence of small amounts of Ga is shown to cause an order of magnitude reduction in the specific contact resistivity. Evidence is presented that the reactions of GaP and GaAs with Au contacts are also drastically affected by the presence of Ga. The sintering behavior of the Au-GaP and the Au-GaAs systems (as contrasted with that of the Au-InP system) is explained as due to the presence of interstitial Ga in the contact metallization. Finally the large, two-to-three order of magnitude drop in the contact resistance that occurs in the Au-InP system upon sintering at 400 degrees Centigrade is shown to be a result of the formation of an Au (sub 2) P (sub 3) layer at the metal-semiconductor interface. Contact resistivities in the 10 (sup -6) ohm square centimeter range are obtained for as-deposited Au on InP when a thin (20 Angstrom) layer of Au (sub 2) P (sub 3) is introduced between the InP and the Au contacts.

  20. Probing the electronic structure and Au—C chemical bonding in AuCn- and AuCnH- (n = 2, 4, and 6) using high-resolution photoelectron spectroscopy

    NASA Astrophysics Data System (ADS)

    León, Iker; Ruipérez, Fernando; Ugalde, Jesus M.; Wang, Lai-Sheng

    2016-08-01

    We report a joint photoelectron spectroscopy and theoretical study on AuC4-, AuC6-, and AuCnH- (n = 2, 4, and 6) using high-resolution photoelectron imaging and ab initio calculations. The ground state of AuC2H-, AuC4H-, and AuC6H- is found to be linear, while that of AuC4- and AuC6- is bent. All the species are found to be linear in their neutral ground states. The electron affinities (EAs) are measured to be 3.366(1) and 3.593(1) eV for AuC4 and AuC6, respectively. Both bending and stretching frequencies are resolved in the spectra of AuC4- and AuC6-. High-resolution data of AuCnH- reveal major vibrational progressions in the Au—C stretching and bending modes. AuC2H- has a ground state stretching frequency of 445(10) cm-1 and a bending frequency of 260(10) cm-1; AuC4H- has a ground state stretching frequency of 340(10) cm-1; AuC6H- has a ground state stretching frequency of 260(10) cm-1 and a bending frequency of 55(10) cm-1. The EAs are measured to be 1.475(1), 1.778(1), and 1.962(1) eV for AuC2H, AuC4H, and AuC6H, respectively. The strength of the Au—C bond decreases as the number of carbon atoms increases. The current study provides a wealth of electronic structure information about AuC4-, AuC6-, and AuCnH- (n = 2, 4, and 6) and their corresponding neutrals.

  1. NASA educational publications

    NASA Technical Reports Server (NTRS)

    1987-01-01

    This is a catalog of educational and technical publications, sponsored by NASA, that are available to the general public from the Government Printing Office (GPO). The following types of publications are announced: periodicals, educational publications, NASA Facts, posters and wallsheets, other publications of interest to educators, scientific and technical publications, and educational materials from Regional Service Centers.

  2. The growth of sulfur adlayers on Au(100)

    SciTech Connect

    Jiang, Yue; Ren, Shendong; Chen, Chi-Lu; Liang, Xihui; Fan, Liang-Jen; Yang, Yaw-Wen; Tang, Jian-Ming; Luh, Dah-An

    2015-02-14

    We have studied the growth of S layers adsorbed on Au(100) with low-energy electron diffraction (LEED), X-ray photoemission spectra (XPS), and scanning tunneling microscope (STM). Three phases of S/Au(100)—(2 × 2), trimer, and c(2 × 4)—are identified; the latter two are not previously reported. A dose of S{sub 2} at 300 K transformed Au(100)-(5 × 20) initially into the (2 × 2) phase and formed the c(2 × 4) phase at a saturation coverage. The STM results show that monolayer Au islands formed during the initial S dose and remained throughout the growth, resulting in a rough c(2 × 4) surface. We show that a highly ordered c(2 × 4) phase can be obtained with a flat (2 × 2) phase as an intermediate step during growth. Based on the evolution of XPS and STM images with varied S{sub 2} dose, the components of S 2p are assigned and structural models for the various S/Au(100) phases are proposed. In the (2 × 2) phase, one S atom resides on a four-fold hollow site in each (2 × 2) unit cell, corresponding to a S coverage of 0.25 ML; in the trimer phase, three S atoms form a trimer residing on a four-fold hollow site in each (2 × 2) unit cell, corresponding to a S coverage of 0.75 ML; in the c(2 × 4) phase, there are five S atoms in each primitive unit cell of c(2 × 4); three of them form a trimer residing on a four-fold hollow site, and the other two form a dimer located on the top of the trimer, corresponding to a nominal S coverage of 1.25 ML. With the proposed structural models, the growth of S on Au(100) at 300 K is described in detail.

  3. Au25(SG)18 as a fluorescent iodide sensor

    NASA Astrophysics Data System (ADS)

    Wang, Man; Wu, Zhikun; Yang, Jiao; Wang, Guozhong; Wang, Hongzhi; Cai, Weiping

    2012-06-01

    The recently emerging gold nanoclusters (GNC) are of major importance for both basic science studies and practical applications. Based on its surface-induced fluorescence properties, we investigated the potential use of Au25(SG)18 (GSH: glutathione) as a fluorescent iodide sensor. The current detection limit of 400 nM, which can possibly be further enhanced by optimizing the conditions, and excellent selectivity among 12 types of anion (F-, Cl-, Br-, I-, NO3-, ClO4-, HCO3-, IO3-, SO42-, SO32-, CH3COO- and C6H5O73-) make Au25(SG)18 a good candidate for iodide sensing. Furthermore, our work has revealed the particular sensing mechanism, which was found to be affinity-induced ratiometric and enhanced fluorescence (abbreviated to AIREF), which has rarely been reported previously and may provide an alternative strategy for devising nanoparticle-based sensors.The recently emerging gold nanoclusters (GNC) are of major importance for both basic science studies and practical applications. Based on its surface-induced fluorescence properties, we investigated the potential use of Au25(SG)18 (GSH: glutathione) as a fluorescent iodide sensor. The current detection limit of 400 nM, which can possibly be further enhanced by optimizing the conditions, and excellent selectivity among 12 types of anion (F-, Cl-, Br-, I-, NO3-, ClO4-, HCO3-, IO3-, SO42-, SO32-, CH3COO- and C6H5O73-) make Au25(SG)18 a good candidate for iodide sensing. Furthermore, our work has revealed the particular sensing mechanism, which was found to be affinity-induced ratiometric and enhanced fluorescence (abbreviated to AIREF), which has rarely been reported previously and may provide an alternative strategy for devising nanoparticle-based sensors. Electronic supplementary information (ESI) available: fluorescence spectra of Au25(SG)18 (1.6 μM in H2O) with successive titration of I- and the time-dependent fluorescence of Au25(SG)18. See DOI: 10.1039/c2nr30169e.

  4. Spin resonance transport properties of a single Au atom in S–Au–S junction and Au–Au–Au junction

    NASA Astrophysics Data System (ADS)

    Fangyuan, Wang; Guiqin, Li

    2016-07-01

    The spin transport properties of S–Au–S junction and Au–Au–Au junction between Au nanowires are investigated with density functional theory and the non-equilibrium Green's function. We mainly focus on the spin resonance transport properties of the center Au atom. The breaking of chemical bonds between anchor atoms and center Au atom significantly influences their spin transmission characteristics. We find the 0.8 eV orbital energy shift between anchor S atoms and the center Au atom can well protect the spin state stored in the S–Au–S junction and efficiently extract its spin state to the current by spin resonance mechanism, while the spin interaction of itinerant electrons and the valence electron of the center Au atom in the Au–Au–Au junction can extract the current spin information into the center Au atom. Fermi energy drift and bias-dependent spin filtering properties of the Au–Au–Au junction may transform information between distance, bias, and electron spin. Those unique properties make them potential candidates for a logical nanocircuit. Project supported by the National Basic Research Program of China (Grants No. 2011CB921602) and the National Natural Science Foundation of China (Grants No. 20121318158).

  5. Transverse momentum and centrality dependence of high-ptnon-photonic electron suppression in Au+Au collisions at $\\sqrt{s_{NN}}$= 200 GeV

    SciTech Connect

    Abelev, B.I.; Adams, J.; Aggarwal, M.M.; Ahammed, Z.; Amonett,J.; Anderson, B.D.; Anderson, M.; Arkhipkin, D.; Averichev, G.S.; Bai,Y.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellingeri-Laurikainen, A.; Bellwied, R.; Benedosso, F.; Bhardwaj, S.; Bhasin, A.; Bhati, A.K.; Bichsel, H.; Bielcik, J.; Bielcikova, J.; Bland, L.C.; Blyth, S.-L.; Bonner, B.E.; Botje, M.; Bouchet, J.; Brandin, A.V.; Bravar, A.; Bystersky, M.; Cadman, R.V.; Cai,X.Z.; Caines, H.; Calderon de la Barca Sanchez, M.; Castillo, J.; Catu,O.; Cebra, D.; Chajecki, Z.; Chaloupka, P.; Chattopadhyay, S.; Chen,H.F.; Chen, J.H.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Cosentino, M.R.; Cramer, J.G.; Crawford,H.J.; Das, D.; Das, S.; Daugherity, M.; de Moura, M.M.; Dedovich, T.G.; DePhillips, M.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Djawotho,P.; Dogra, S.M.; Dong, W.J.; Dong, X.; Draper, J.E.; Du, F.; Dunin, V.B.; Dunlop, J.C.; Dutta Mazumdar, M.R.; Eckardt, V.; Edwards, W.R.; Efimov,L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Fatemi, R.; Fedorisin, J.; Filimonov, K.; Filip, P.; Finch,E.; Fine, V.; Fisyak, Y.; Fu, J.; Gagliardi, C.A.; Gaillard, L.; Ganti,M.S.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J.S.; Gorbunov, Y.G.; Gos,H.; Grebenyuk, O.; Grosnick, D.; Guertin, S.M.; Guimaraes, K.S.F.F.; Guo,Y.; Gupta, N.; Gutierrez, T.D.; Haag, B.; Hallman, T.J.; Hamed, A.; Harris, J.W.; He, W.; Heinz, M.; Henry, T.W.; Hepplemann, S.; Hippolyte,B.; Hirsch, A.; Hjort, E.; Hoffman, A.M.; Hoffmann, G.W.; Horner, M.J.; Huang, H.Z.; Huang, S.L.; Hughes, E.W.; Humanic, T.J.; Igo, G.; Jacobs,P.; Jacobs, W.W.; Jakl, P.; Jia, F.; Jiang, H.; Jones, P.G.; Judd, E.G.; Kabana, S.; Kang, K.; Kapitan, J.; Kaplan, M.; Keane, D.; Kechechyan, A.; Khodyrev, V.Yu.; Kim, B.C.; Kiryluk, J.; Kisiel, A.; Kislov, E.M.; Klein,S.R.; Kocoloski, A.; Koetke, D.D.; et al.

    2006-07-11

    The STAR collaboration at RHIC reports measurements of theinclusive yield of non-photonic electrons, which arise dominantly fromsemi-leptonic decays of heavy flavor mesons, over a broad range oftransverse momenta (1.2Au, and AuAucollisions at sqrt sNN = 200 GeV. The non-photonic electron yieldexhibits unexpectedly large suppression in central AuAu collisions athigh pt, suggesting substantial heavy quark energy loss at RHIC. Thecentrality and \\pt dependences of the suppression provide constraints ontheoretical models of suppression.

  6. Effect of Au nanorods on potential barrier modulation in morphologically controlled Au@Cu2O core-shell nanoreactors for gas sensor applications.

    PubMed

    Majhi, Sanjit Manohar; Rai, Prabhakar; Raj, Sudarsan; Chon, Bum-Soo; Park, Kyung-Kuen; Yu, Yeon-Tae

    2014-05-28

    In this work, Au@Cu2O core-shell nanoparticles (NPs) were synthesized by simple solution route and applied for CO sensing applications. Au@Cu2O core-shell NPs were formed by the deposition of 30-60 nm Cu2O shell layer on Au nanorods (NRs) having 10-15 nm width and 40-60 nm length. The morphology of Au@Cu2O core-shell NPs was tuned from brick to spherical shape by tuning the pH of the solution. In the absence of Au NRs, cubelike Cu2O NPs having ∼200 nm diameters were formed. The sensor having Au@Cu2O core-shell layer exhibited higher CO sensitivity compared to bare Cu2O NPs layer. Tuning of morphology of Au@Cu2O core-shell NPs from brick to spherical shape significantly lowered the air resistance. Transition from p- to n-type response was observed for all devices below 150 °C. It was demonstrated that performance of sensor depends not only on the electronic sensitization of Au NRs but also on the morphology of the Au@Cu2O core-shell NPs.

  7. Identified particle distributions in pp and Au+Au collisions at square root of (sNN)=200 GeV.

    PubMed

    Adams, J; Adler, C; Aggarwal, M M; Ahammed, Z; Amonett, J; Anderson, B D; Anderson, M; Arkhipkin, D; Averichev, G S; Badyal, S K; Balewski, J; Barannikova, O; Barnby, L S; Baudot, J; Bekele, S; Belaga, V V; Bellwied, R; Berger, J; Bezverkhny, B I; Bhardwaj, S; Bhaskar, P; Bhati, A K; Bichsel, H; Billmeier, A; Bland, L C; Blyth, C O; Bonner, B E; Botje, M; Boucham, A; Brandin, A; Bravar, A; Cadman, R V; Cai, X Z; Caines, H; Calderón de la Barca Sánchez, M; Carroll, J; Castillo, J; Castro, M; Cebra, D; Chaloupka, P; Chattopadhyay, S; Chen, H F; Chen, Y; Chernenko, S P; Cherney, M; Chikanian, A; Choi, B; Christie, W; Coffin, J P; Cormier, T M; Cramer, J G; Crawford, H J; Das, D; Das, S; Derevschikov, A A; Didenko, L; Dietel, T; Dong, X; Draper, J E; Du, F; Dubey, A K; Dunin, V B; Dunlop, J C; Dutta Majumdar, M R; Eckardt, V; Efimov, L G; Emelianov, V; Engelage, J; Eppley, G; Erazmus, B; Estienne, M; Fachini, P; Faine, V; Faivre, J; Fatemi, R; Filimonov, K; Filip, P; Finch, E; Fisyak, Y; Flierl, D; Foley, K J; Fu, J; Gagliardi, C A; Ganti, M S; Gutierrez, T D; Gagunashvili, N; Gans, J; Gaudichet, L; Germain, M; Geurts, F; Ghazikhanian, V; Ghosh, P; Gonzalez, J E; Grachov, O; Grigoriev, V; Gronstal, S; Grosnick, D; Guedon, M; Guertin, S M; Gupta, A; Gushin, E; Hallman, T J; Hardtke, D; Harris, J W; Heinz, M; Henry, T W; Heppelmann, S; Herston, T; Hippolyte, B; Hirsch, A; Hjort, E; Hoffmann, G W; Horsley, M; Huang, H Z; Huang, S L; Humanic, T J; Igo, G; Ishihara, A; Jacobs, P; Jacobs, W W; Janik, M; Johnson, I; Jones, P G; Judd, E G; Kabana, S; Kaneta, M; Kaplan, M; Keane, D; Kiryluk, J; Kisiel, A; Klay, J; Klein, S R; Klyachko, A; Koetke, D D; Kollegger, T; Konstantinov, A S; Kopytine, M; Kotchenda, L; Kovalenko, A D; Kramer, M; Kravtsov, P; Krueger, K; Kuhn, C; Kulikov, A I; Kumar, A; Kunde, G J; Kunz, C L; Kutuev, R Kh; Kuznetsov, A A; Lamont, M A C; Landgraf, J M; Lange, S; Lansdell, C P; Lasiuk, B; Laue, F; Lauret, J; Lebedev, A; Lednický, R; Leontiev, V M; LeVine, M J; Li, C; Li, Q; Lindenbaum, S J; Lisa, M A; Liu, F; Liu, L; Liu, Z; Liu, Q J; Ljubicic, T; Llope, W J; Long, H; Longacre, R S; Lopez-Noriega, M; Love, W A; Ludlam, T; Lynn, D; Ma, J; Ma, Y G; Magestro, D; Mahajan, S; Mangotra, L K; Mahapatra, D P; Majka, R; Manweiler, R; Margetis, S; Markert, C; Martin, L; Marx, J; Matis, H S; Matulenko, Yu A; McShane, T S; Meissner, F; Melnick, Yu; Meschanin, A; Messer, M; Miller, M L; Milosevich, Z; Minaev, N G; Mironov, C; Mishra, D; Mitchell, J; Mohanty, B; Molnar, L; Moore, C F; Mora-Corral, M J; Morozov, V; de Moura, M M; Munhoz, M G; Nandi, B K; Nayak, S K; Nayak, T K; Nelson, J M; Nevski, P; Nikitin, V A; Nogach, L V; Norman, B; Nurushev, S B; Odyniec, G; Ogawa, A; Okorokov, V; Oldenburg, M; Olson, D; Paic, G; Pandey, S U; Pal, S K; Panebratsev, Y; Panitkin, S Y; Pavlinov, A I; Pawlak, T; Perevoztchikov, V; Peryt, W; Petrov, V A; Phatak, S C; Picha, R; Planinic, M; Pluta, J; Porile, N; Porter, J; Poskanzer, A M; Potekhin, M; Potrebenikova, E; Potukuchi, B V K S; Prindle, D; Pruneau, C; Putschke, J; Rai, G; Rakness, G; Raniwala, R; Raniwala, S; Ravel, O; Ray, R L; Razin, S V; Reichhold, D; Reid, J G; Renault, G; Retiere, F; Ridiger, A; Ritter, H G; Roberts, J B; Rogachevski, O V; Romero, J L; Rose, A; Roy, C; Ruan, L J; Sahoo, R; Sakrejda, I; Salur, S; Sandweiss, J; Savin, I; Schambach, J; Scharenberg, R P; Schmitz, N; Schroeder, L S; Schweda, K; Seger, J; Seliverstov, D; Seyboth, P; Shahaliev, E; Shao, M; Sharma, M; Shestermanov, K E; Shimanskii, S S; Singaraju, R N; Simon, F; Skoro, G; Smirnov, N; Snellings, R; Sood, G; Sorensen, P; Sowinski, J; Spinka, H M; Srivastava, B; Stanislaus, S; Stock, R; Stolpovsky, A; Strikhanov, M; Stringfellow, B; Struck, C; Suaide, A A P; Sugarbaker, E; Suire, C; Sumbera, M; Surrow, B; Symons, T J M; de Toledo, A Szanto; Szarwas, P; Tai, A; Takahashi, J; Tang, A H; Thein, D; Thomas, J H; Tikhomirov, V; Tokarev, M; Tonjes, M B; Trainor, T A; Trentalange, S; Tribble, R E; Trivedi, M D; Trofimov, V; Tsai, O; Ullrich, T; Underwood, D G; Van Buren, G; VanderMolen, A M; Vasiliev, A N; Vasiliev, M; Vigdor, S E; Viyogi, Y P; Voloshin, S A; Waggoner, W; Wang, F; Wang, G; Wang, X L; Wang, Z M; Ward, H; Watson, J W; Wells, R; Westfall, G D; Whitten, C; Wieman, H; Willson, R; Wissink, S W; Witt, R; Wood, J; Wu, J; Xu, N; Xu, Z; Xu, Z Z; Yakutin, A E; Yamamoto, E; Yang, J; Yepes, P; Yurevich, V I; Zanevski, Y V; Zborovský, I; Zhang, H; Zhang, H Y; Zhang, W M; Zhang, Z P; Zołnierczuk, P A; Zoulkarneev, R; Zoulkarneeva, J; Zubarev, A N

    2004-03-19

    Transverse mass and rapidity distributions for charged pions, charged kaons, protons, and antiprotons are reported for square root of [sNN]=200 GeV pp and Au+Au collisions at Relativistic Heary Ion Collider (RHIC). Chemical and kinetic equilibrium model fits to our data reveal strong radial flow and long duration from chemical to kinetic freeze-out in central Au+Au collisions. The chemical freeze-out temperature appears to be independent of initial conditions at RHIC energies. PMID:15089125

  8. Impact of surface roughness of Au core in Au/Pd core-shell nanoparticles toward formic acid oxidation - Experiment and simulation

    NASA Astrophysics Data System (ADS)

    Hsu, Chiajen; Huang, Chienwen; Hao, Yaowu; Liu, Fuqiang

    2013-12-01

    The Au/Pd core-shell nanoparticles (NPs) were synthesized via galvanic replacement of Cu by Pd on hollow Au cores by adding different concentrations of Na2SO3 solution. It was found that the higher concentration of Na2SO3 that was used, the rougher the Au nanospheres became. However, the rougher Au surface may cause more defects in the Pd layers and decrease the catalytic abilities. The Au/Pd NPs synthesized using 0 M Na2SO3 (denoted as 0 M-Au/Pd NPs) have the smoothest Pd surface and demonstrate higher formic acid oxidation (FAO) activity (0.714 mA cm-2, normalized to the surface area of Pd) than other Au/Pd NPs and commercial Pd black (0.47 mA cm-2). Additional electrochemical characterization of the 0 M-Au/Pd NPs also demonstrated lower CO-stripping onset and peak potentials, higher stability (8× improvement in stabilized oxidation current), and superior durability (by 1.6×) than the Pd black. In addition, a simple simulation of FAO was adopted to predict the anodic curve by including reaction intermediates of formate and hydroxyl. The 0 M-Au/Pd NPs were found to show higher formate and lower hydroxyl coverage than the Pd black.

  9. Transverse-momentum dependent modification of dynamic texture in central Au+Au collisions at sqrt(sNN) = 200 GeV

    SciTech Connect

    Adams, J.; Aggarwal, M.M.; Ahammed, Z.; Amonett, J.; Anderson, B.D.; Arkhipkin, D.; Averichev, G.S.; Badyal, S.K.; Bai, Y.; Balewski, J.; Barannikova, O.; Barnby, L.S.; Baudot, J.; Bekele, S.; Belaga, V.V.; Bellwied, R.; Berger, J.; Bezverkhny, B.I.; Bharadwaj, S.; Bhasin, A.; Bhati, A.K.; Bhatia, V.S.; Bichsel, H.; Billmeier, A.; Bland, L.C.; Blyth, C.O.; Bonner, B.E.; Botje, M.; Boucham, A.; Brandin, A.V.; Bravar, A.; Bystersky, M.; Cadman, R.V.; Cai, X.Z.; Caines, H.; Calderon de la Barca Sanchez, M.; Castillo, J.; Cebra, D.; Chajecki, Z.; Chaloupka, P.; Chattopadhyay, S.; Chen, H.F.; Chen, Y.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Coffin, J.P.; Cormier, T.M.; Cramer, J.G.; Crawford, H.J.; Das, D.; Das, S.; de Moura, M.M.; Derevschikov, A.A.; Didenko, L.; Dietel, T.; Dogra, S.M.; Dong, W.J.; Dong, X.; Draper, J.E.; Du, F.; Dubey, A.K.; Dunin, V.B.; Dunlop, J.C.; Dutta Mazumdar, M.R.; Eckardt, V.; Edwards, W.R.; Efimov, L.G.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Fachini, P.; Faivre, J.; Fatemi, R.; Fedorisin, J.; Filimonov, K.; Filip, P.; Finch, E.; Fine, V.; Fisyak, Y.; Fomenko, K.; Fu, J.; Gagliardi, C.A.; Gans, J.; Ganti, M.S.; Gaudichet, L.; Geurts, F.; Ghazikhanian, V.; Ghosh, P.; Gonzalez, J.E.; Grachov, O.; Grebenyuk, O.; Grosnick, D.; Guertin, S.M.; Guo, Y.; Gupta, A.; Gutierrez, T.D.; Hallman, T.J.; Hamed, A.; Hardtke, D.; Harris, J.W.; Heinz, M.; Henry, T.W.; Hepplemann, S.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffmann, G.W.; Huang, H.Z.; Huang, S.L.; Hughes, E.W.; Humanic, T.J.; Igo, G.; Ishihara, A.; Jacobs, P.; Jacobs, W.W.; Janik, M.; Jiang, H.; Jones, P.G.; Judd, E.G.; Kabana, S.; Kang, K.; Kaplan, M.; Keane, D.; Khodyrev, V.Yu.; Kiryluk, J.; Kisiel, A.; Kislov, E.M.; Klay, J.; Klein, S.R.; Klyachko, A.; Koetke, D.D.; Kollegger, T.; Kopytine, S.M.; Kotchenda, L.; Kramer, M.; Kravtsov, P.; Kravtsov, V.I.; Krueger, K.; Kuhn, C.; Kulikov, A.I.; Kumar, A.; Kutuev, R.Kh.; et al.

    2005-01-10

    Correlations in the hadron distributions produced in relativistic Au+Au collisions are studied in the discrete wavelet expansion method. The analysis is performed in the space of pseudorapidity (|{eta}| {le} 1) and azimuth (full 2{pi}) in bins of transverse momentum (p{sub t}) from 0.14 {le} p{sub t} {le} 2.1 GeV/c. In peripheral Au+Au collisions a correlation structure ascribed to minijet fragmentation is observed. It evolves with collision centrality and p{sub t} in a way not seen before which suggests strong dissipation of minijet fragmentation in the longitudinally-expanding medium.

  10. Nuclear modification factors at forward rapidity in Au Au and Cu Cu collisions at \\sqrt{s_NN} = 62.4 GeV

    NASA Astrophysics Data System (ADS)

    Larsen, Truls Martin; BRAHMS Collaboration

    2007-08-01

    Data from Au Au, Cu Cu and p p collisions at \\sqrt{s_NN}=62.4 GeV have been collected by the BRAHMS experiment from pseudorapidity η = 0 3.1. Nuclear modification factors, RAA at forward rapidity, with pT up to ~2 GeV/c, which corresponds to more than half of the kinematical limit, are presented together with results from midrapidity for Au Au and Cu Cu collisions. They will also be shown as a function of centrality.

  11. Plasmonic enhancement of visible-light water splitting with Au-TiO2 composite aerogels.

    PubMed

    DeSario, Paul A; Pietron, Jeremy J; DeVantier, Devyn E; Brintlinger, Todd H; Stroud, Rhonda M; Rolison, Debra R

    2013-09-01

    We demonstrate plasmonic enhancement of visible-light-driven splitting of water at three-dimensionally (3D) networked gold-titania (Au-TiO2) aerogels. The sol-gel-derived ultraporous composite nanoarchitecture, which contains 1 to 8.5 wt% Au nanoparticles and titania in the anatase form, retains the high surface area and mesoporosity of unmodified TiO2 aerogels and maintains stable dispersion of the ~5 nm Au guests. A broad surface plasmon resonance (SPR) feature centered at ~550 nm is present for the Au-TiO2 aerogels, but not Au-free TiO2 aerogels, and spans a wide range of the visible spectrum. Gold-derived SPR in Au-TiO2 aerogels cast as films on transparent electrodes drives photoelectrochemical oxidation of aqueous hydroxide and extends the photocatalytic activity of TiO2 from the ultraviolet region to visible wavelengths exceeding 700 nm. Films of Au-TiO2 aerogels in which Au nanoparticles are deposited on pre-formed TiO2 aerogels by a deposition-precipitation method (DP Au/TiO2) also photoelectrochemically oxidize aqueous hydroxide, but less efficiently than 3D Au-TiO2, despite having an essentially identical Au nanoparticle weight fraction and size distribution. For example, 3D Au-TiO2 containing 1 wt% Au is as active as DP Au/TiO2 with 4 wt% Au. The higher photocatalytic activity of 3D Au-TiO2 derives only in part from its ability to retain the surface area and porosity of unmodified TiO2 aerogel. The magnitude of improvement indicates that in the 3D arrangement either a more accessible photoelectrochemical reaction interphase (three-phase boundary) exists or more efficient conversion of excited surface plasmons into charge carriers occurs, thereby amplifying reactivity over DP Au/TiO2. The difference in photocatalytic efficiency between the two forms of Au-TiO2 demonstrates the importance of defining the structure of Au[parallel]TiO2 interfaces within catalytic Au-TiO2 nanoarchitectures. PMID:23877169

  12. Structure analysis of bimetallic Co-Au nanoparticles formed by sequential ion implantation

    NASA Astrophysics Data System (ADS)

    Chen, Hua-jian; Wang, Yu-hua; Zhang, Xiao-jian; Song, Shu-peng; chen, Hong; Zhang, Ke; Xiong, Zu-zhao; Ji, Ling-ling; Dai, Hou-mei; Wang, Deng-jing; Lu, Jian-duo; Wang, Ru-wu; Zheng, Li-rong

    2016-08-01

    Co-Au alloy Metallic nanoparticles (MNPs) are formed by sequential ion implantation of Co and Au into silica glass at room temperature. The ion ranges of Au ions implantation process have been displayed to show the ion distribution. We have used the atomic force microscopy (AFM) and transmission electron microscopy (TEM) to investigate the formation of bimetallic nanoparticles. The extended X-ray absorption fine structure (EXAFS) has been used to study the local structural information of bimetallic nanoparticles. With the increase of Au ion implantation, the local environments of Co ions are changed enormously. Hence, three oscillations, respectively, Co-O, Co-Co and Co-Au coordination are determined.

  13. Centrality, Rapidity And Transverse-Momentum Dependence of Cold Nuclear Matter Effects on J/Psi Production in D Au, Cu Cu And Au Au Collisions at S(NN)**(1/2)

    SciTech Connect

    Ferreiro, E.G.; Fleuret, F.; Lansberg, J.P.; Rakotozafindrabe, A.; /SPhN, DAPNIA, Saclay

    2011-11-11

    We have carried out a wide study of Cold Nuclear Matter (CNM) effects on J/{Psi} = production in dAu, CuCu and AuAu collisions at {radical}s{sub NN} = 200 GeV. We have studied the effects of three different gluon-shadowing parameterizations, using the usual simplified kinematics for which the momentum of the gluon recoiling against the J/{Psi} is neglected as well as an exact kinematics for a 2 {yields} 2 process, namely g + g {yields} J/{psi} + g as expected from LO pQCD. We have shown that the rapidity distribution of the nuclear modification factor R{sub dAu}, and particularly its anti-shadowing peak, is systematically shifted toward larger rapidities in the 2 {yields} 2 kinematics, irrespective of which shadowing parameterization is used. In turn, we have noted differences in the effective final-state nuclear absorption needed to fit the PHENIX dAu data. Taking advantage of our implementation of a 2 {yields} 2 kinematics, we have also computed the transverse momentum dependence of the nuclear modification factor, which cannot be predicted with the usual simplified kinematics. All the corresponding observables have been computed for CuCu and AuAu collisions and compared to the PHENIX and STAR data. Finally, we have extracted the effective nuclear absorption from the recent measurements of RCP in dAu collisions by the PHENIX collaboration.

  14. Comparison of photoluminescence properties of HSA-protected and BSA-protected Au25 nanoclusters

    NASA Astrophysics Data System (ADS)

    Tsukamoto, Masato; Kawasaki, Hideya; Saitoh, Tadashi; Inada, Mitsuru; Kansai Univ. Collaboration

    Gold nanoclusters (NCs) have attracted great interest for a wide range of applications. In particular, red light-emitting Au25 NCs have been prepared with various biological ligands. It has been shown that Au25 NCs have Au13-core/6Au2(SR)3-semiring structure. The red luminescence thought to be originated from both core (670 nm) and semiring (625 nm). It is important to reveal a structure of Au25 NCs to facilitate the progress of applications. However, the precise structure of Au25 NCs has not been clarified. There is a possibility of obtaining structural information about Au25 NCs to compare optical properties of the NCs that protected by slightly different molecules. Bovine and human serum albumin (BSA, HSA) are suitable one for this purpose. It has been suggested that rich tyrosine and cysteine residues in these molecules are important to produce the thiolate-protected Au NCs. If Au25 NCs have core/shell structure, only the luminescence of the semiring will be affected by the difference of the albumin molecules. We carefully compared PL characteristics of BSA- and HSA- protected Au25 NCs. As a result, there was no difference in the PL at 670 nm (core), while differences were observed in the PL at 625 nm (semiring). The results support that Au25 NCs have core/semiring structure.

  15. Bringing Planet Finder Closer: 1AU missions for Terrestrial Planet Finder, precursor and follow-on

    NASA Astrophysics Data System (ADS)

    Woolf, N. J.

    1997-12-01

    A mission to search for Earth-like planets and obtain their spectra was set at 5AU because the zodiacal dust emission at 1AU would make larger mirrors necessary. When the concept was developed in 1995, the Space Telescope with a 2.4m mirror cost \\2 billion. To ask for even larger mirrors on a mission seemed unrealistic. Now, Next Generation Space Telescope with a 6-8m glass membrane primary from the Mirror Lab seems achievable within budget, and a 1 AU Terrestrial Planet Finder mission with only half as much glass could be made at no greater cost. The advantages of a 1 AU mission are (1) further IR detector development would no longer be needed; (2) cryogens in dewars would last long enough; (3) for 1AU/5AU systems matched in performance for 15pc planets, the 1AU system would allow higher spectral resolution for closer planetary systems, possibly permitting detection of methane; (4) the signal /noise for a 1AU system will deteriorate less when a planetary system with strong exo-zodiacal emission is encountered; (5) neither RTGs nor large solar cell arrays are needed; (6) mass is less constrained. A precursor mission to confirm TPF techniques at lower cost, and study giant planets at 5\\mu$ could also operate at 1AU. A follow on mission to obtain high resolution spectra of exo-planetary atmospheres would not benefit appreciably from 5AU operation. A 1AU mission would be fine for it.

  16. Growth of textured thin Au coatings on iron oxide nanoparticles with near infrared absorbance

    PubMed Central

    Ma, L L; Borwankar, A U; Willsey, B W; Yoon, K Y; Tam, J O; Sokolov, K V; Feldman, M D; Milner, T E; Johnston, K P

    2013-01-01

    A homologous series of Au-coated iron oxide nanoparticles, with hydrodynamic diameters smaller than 60 nm was synthesized with very low Auto-iron mass ratios as low as 0.15. The hydrodynamic diameter was determined by dynamic light scattering and the composition by atomic absorption spectroscopy and energy dispersive x-ray spectroscopy (EDS). Unusually low Au precursor supersaturation levels were utilized to nucleate and grow Au coatings on iron oxide relative to formation of pure Au nanoparticles. This approach produced unusually thin coatings, by lowering autocatalytic growth of Au on Au, as shown by transmission electron microscopy (TEM). Nearly all of the nanoparticles were attracted by a magnet indicating a minimal amount of pure Au particles The coatings were sufficiently thin to shift the surface plasmon resonance (SPR) to the near infrared (NIR), with large extinction coefficients., despite the small particle hydrodynamic diameters, observed from dynamic light scattering to be less than 60 nm. PMID:23238021

  17. Understanding the structural properties and thermal stabilities of Au-Pd-Pt trimetallic clusters

    NASA Astrophysics Data System (ADS)

    Zhao, Zheng; Li, Mingjiang; Cheng, Daojian; Zhu, Jiqin

    2014-09-01

    In this work, surface segregation phenomena of Au-Pd-Pt trimetallic clusters are investigated by using semi-grand Monte Carlo simulations based on the Gupta potential. It is found that Au atoms are systematically segregated on the surface of the Au-Pd-Pt clusters (6-24 at.% higher than the overall Au concentration), due to the competition among the surface energies of Au, Pd, and Pt. The melting properties of Au-Pd-Pt trimetallic clusters with different composition and size are investigated by using molecular dynamics simulations, based on the same Gupta potential. It is found that the Au-Pd-Pt trimetallic cluster with the highest melting point corresponds to the one with the most stable structure. In addition, linear decrease in cluster melting point with the inverse cluster diameter is predicted for both pure and trimetallic clusters, which is well-known as the Pawlow's law.

  18. Facile synthesis of PtAu alloy nanoparticles with high activity for formic acid oxidation

    SciTech Connect

    Zhang, Sheng; Shao, Yuyan; Yin, Geping; Lin, Yuehe

    2010-02-15

    We report the facile synthesis of carbon supported PtAu alloy nanoparticles with high electrocatalytic activity as the anode catalyst for direct formic acid fuel cells (DFAFCs). PtAu alloy nanopaticles are synthesized by co-reducing HAuCl4 and H2PtCl6 with NaBH4 in the presence of sodium citrate and then the nanoparticles are deposited on Vulcan XC-72R carbon support (PtAu/C). The obtained catalysts are characterized with X-ray diffraction (XRD) and transmission electron microscope (TEM), which reveal PtAu alloy formation with an average diameter of 4.6 nm. PtAu/C exhibits 8 times higher catalytic activity toward formic acid oxidation than Pt/C. The enhanced activity of PtAu/C catalyst is attributed to noncontinuous Pt sites formed in the presence of the neighbored Au sites, which promotes direct oxidation of formic acid by avoiding poison CO.

  19. The support effect on the size and catalytic activity of thiolated Au25 nanoclusters as precatalysts

    NASA Astrophysics Data System (ADS)

    Fang, Jun; Li, Jingguo; Zhang, Bin; Yuan, Xun; Asakura, Hiroyuki; Tanaka, Tsunehiro; Teramura, Kentaro; Xie, Jianping; Yan, Ning

    2015-03-01

    In this study, 6-mercaptohexanoic (MHA) protected Au25(MHA)18 nanoclusters (or thiolated Au NCs) deposited on various inorganic supports, including hydroxyapatite (HAP), TiO2 (Degussa P25), activated carbon (AC), pyrolyzed graphene oxide (PGO), and fumed SiO2 were prepared via a conventional impregnation method. Following that, calcination under a N2 stream was conducted to produce surface ligand free, highly dispersed Au NCs catalysts. The effects of supports on the size and catalytic activity of Au NCs were systematically investigated. No obvious size growth was observed for Au NCs on HAP and P25 after thermally induced ligand removal, due to the strong interaction between the metal and the supports. However, severe aggregations of Au NCs were seen after thermal treatment on three other supports, including AC, PGO, and SiO2. The removal of surface thiol ligands from the Au NCs is crucial to catalyze nitrobenzene hydrogenation, where only calcined Au/HAP and Au/P25 exhibited good catalytic activity. On the other hand, all the supported Au NCs were active for the styrene oxidation, where Au/HAP exhibited the best catalytic performance. Altogether, both the size effect and metal-support interaction are crucial for the design of supported Au NCs as efficient catalysts for targeted reactions.In this study, 6-mercaptohexanoic (MHA) protected Au25(MHA)18 nanoclusters (or thiolated Au NCs) deposited on various inorganic supports, including hydroxyapatite (HAP), TiO2 (Degussa P25), activated carbon (AC), pyrolyzed graphene oxide (PGO), and fumed SiO2 were prepared via a conventional impregnation method. Following that, calcination under a N2 stream was conducted to produce surface ligand free, highly dispersed Au NCs catalysts. The effects of supports on the size and catalytic activity of Au NCs were systematically investigated. No obvious size growth was observed for Au NCs on HAP and P25 after thermally induced ligand removal, due to the strong interaction between the

  20. Synthesis and enhanced humidity detection response of nanoscale Au-particle-decorated ZnS spheres

    PubMed Central

    2014-01-01

    We successfully prepared Au-nanoparticle-decorated ZnS (ZnS-Au) spheres by sputtering Au ultrathin films on surfaces of hydrothermally synthesized ZnS spheres and subsequently postannealed the samples in a high-vacuum atmosphere. The Au nanoparticles were distributed on ZnS surfaces without substantial aggregation. The Au nanoparticle diameter range was 5 to 10 nm. Structural information showed that the surface of the annealed ZnS-Au spheres became more irregular and rough. A humidity sensor constructed using the Au-nanoparticle-decorated ZnS spheres demonstrated a substantially improved response to the cyclic change in humidity from 11% relative humidity (RH) to 33% to 95% RH at room temperature. The improved response was associated with the enhanced efficiency of water molecule adsorption onto the surfaces of the ZnS because of the surface modification of the ZnS spheres through noble-metal nanoparticle decoration. PMID:25520595

  1. Significant Broadband Photocurrent Enhancement by Au-CZTS Core-Shell Nanostructured Photocathodes

    NASA Astrophysics Data System (ADS)

    Zhang, Xuemei; Wu, Xu; Centeno, Anthony; Ryan, Mary P.; Alford, Neil M.; Riley, D. Jason; Xie, Fang

    2016-03-01

    Copper zinc tin sulfide (CZTS) is a promising material for harvesting solar energy due to its abundance and non-toxicity. However, its poor performance hinders their wide application. In this paper gold (Au) nanoparticles are successfully incorporated into CZTS to form Au@CZTS core-shell nanostructures. The photocathode of Au@CZTS nanostructures exhibits enhanced optical absorption characteristics and improved incident photon-to-current efficiency (IPCE) performance. It is demonstrated that using this photocathode there is a significant increase of the power conversion efficiency (PCE) of a photoelectrochemical solar cell of 100% compared to using a CZTS without Au core. More importantly, the PCE of Au@CZTS photocathode improved by 15.8% compared to standard platinum (Pt) counter electrode. The increased efficiency is attributed to plasmon resonance energy transfer (PRET) between the Au nanoparticle core and the CZTS shell at wavelengths shorter than the localized surface plasmon resonance (LSPR) peak of the Au and the semiconductor bandgap.

  2. Hysteresis-free nanoplasmonic Pd-Au alloy hydrogen sensors.

    PubMed

    Wadell, Carl; Nugroho, Ferry Anggoro Ardy; Lidström, Emil; Iandolo, Beniamino; Wagner, Jakob B; Langhammer, Christoph

    2015-05-13

    The recent market introduction of hydrogen fuel cell cars and the prospect of a hydrogen economy have drastically accelerated the need for safe and accurate detection of hydrogen. In this Letter, we investigate the use of arrays of nanofabricated Pd-Au alloy nanoparticles as plasmonic optical hydrogen sensors. By increasing the amount of Au in the alloy nanoparticles up to 25 atom %, we are able to suppress the hysteresis between hydrogen absorption and desorption, thereby increasing the sensor accuracy to below 5% throughout the investigated 1 mbar to 1 bar hydrogen pressure range. Furthermore, we observe an 8-fold absolute sensitivity enhancement at low hydrogen pressures compared to sensors made of pure Pd, and an improved sensor response time to below one second within the 0-40 mbar pressure range, that is, below the flammability limit, by engineering the nanoparticle size. PMID:25915663

  3. Size dependence of Peltier cooling in ferromagnet/Au nanopillars

    NASA Astrophysics Data System (ADS)

    Bosu, Subrojati; Sakuraba, Yuya; Kubota, Takahide; Juarez-Acosta, Isaac; Sugiyama, Tomoko; Saito, Kesami; Olivares-Robles, Miguel A.; Takahashi, Saburo; Bauer, Gerrit E. W.; Takanashi, Koki

    2015-08-01

    We study Peltier cooling in current-perpendicular-to-plane multilayer nanopillars with diameters D varying from 60 to 430 nm and made from Au and various ferromagnets (FMs): Heusler compounds Co2MnSi and Co2FeSi (CFS) and conventional FM metals Fe and Co. We report an enhanced effective Peltier coefficient ΠCPP in resistance-current curves at small D (<120 nm). The maximum ΠCPP value of about 165 mV, found for the CFS/Au interface with D ˜ 60 nm, is 24 times higher than the bulk Peltier coefficient Πbulk (˜7 mV) and corresponds to a high cooling power of 43.6 MW/cm2.

  4. The AuScope Project and Trans-Tasman VLBI

    NASA Technical Reports Server (NTRS)

    Lovell, Jim; Dickey, John; Gulyaev, Sergei; Natusch, Tim; Titov, Oleg; Tingay, Steven

    2010-01-01

    Three 12-meter radio telescopes are being built in Australia (the AuScope project) and one in New Zealand. These facilities will be fully-equipped for undertaking S and X-band geodetic VLBI observations and correlation will take place on a software correlator (part of the AuScope project). All sites are equipped with permanent GPS receivers to provide co-location of several space geodetic techniques. The following scientific tasks of geodesy and astrometry are considered. 1. Improvement and densification of the International Celestial Reference Frame in the southern hemisphere; 2. Improvement of the International Terrestrial Reference Frame in the region; 3. Measurement of intraplate deformation of the Australian tectonic plate.

  5. Missing-Row Contractive Reconstruction on Au(311)

    NASA Astrophysics Data System (ADS)

    Ercolessi, Furio; Tosatti, Erio

    All the low-index surfaces of gold are known to reconstruct, and their vicinals often exhibit magic orientations. The (311) orientation lies in between (100) and (111), and can be regarded as either a (111) or (100) vicinal with a very high step density, or as a flat open surface. In view of rather puzzling reconstructions observed experimentally [(1 × 4), (1 × 5), (1 × 6)], we have undertaken a structural study of Au(311) using the glue model and molecular-dynamics-based simulated annealing. The optical geometry is a (1 × 5) missing-row structure with (111) and reconstructed (100) microfacets, and an alternation of (1 × 2) and (1 × 3) hills. An extra atomic row is present on (1 × 3) hills to optimize packing. The experimentally observed disappearance of the reconstruction between 700 and 750 K is probably associated with an order-disorder transition similar to that of Au(110).

  6. Mass Transfer and Light Time Effect Studies for AU Serpentis

    NASA Astrophysics Data System (ADS)

    Amin, S. M.

    2015-02-01

    The orbital period changes of theWUMa eclipsing binary AU Ser are studied using the (O-C) method. We conclude that the period variation is due to mass transfer from the primary star to the secondary one at a very low and decreasing rate dP/dt = -8.872 × 10-8, superimposed on the sinusoidal variation due to a third body orbiting the binary with period 42.87 ± 3.16 years, orbital eccentricity e = 0.52±0.12 and a longitude of periastron passage ! = 133.7±15. On studying the magnetic activity, we have concluded that the Applegate mechanism failed to describe the cycling variation of the (O-C) diagram of AU Ser.

  7. Injection and acceleration of Au31+ in the BNL AGS.

    SciTech Connect

    Fischer,W.; Ahrens, L.; Brown, K.; Gardner, C.; Glenn, W.; Huang, H.; Mapes, M.; Smart, L.; Thieberger, P.; Tsoupas, N.; Zhang, S.Y.; Zeno, K.; Omet, C.; Spiller, P.

    2008-06-23

    Injection and acceleration of ions in a lower charge state reduces space charge effects, and, if further elcctron stripping is needed, may allow elimination of a stripping stage and the associated beam losses. The former is of interest to the accelerators in the GSI FAIR complex, the latter for BNL RHIC collider operation at energies lower than the current injection energy. Lower charge state ions, however, have a higher likelihood of electron stripping which can lead to dynamic pressures rises and subsequent beam losses. We report on experiments in the AGS where Au{sup 31+} ions were injected and accelerated instead of the normally used Au{sup 77+} ions. Beam intensities and the average pressure in the AGS ring are recorded, and compared with calculations for dynamic pressures and beam losses. The experimental results will be used to benchmark the StrahlSim dynamic vacuum code and will be incorporated in the GSI FAIR SIS100 design.

  8. Laser generation of Au ions with charge states above 50+

    SciTech Connect

    Laska, L.; Jungwirth, K.; Krasa, J.; Krousky, E.; Rohlena, K.; Skala, J.; Velyhan, A.; Margarone, D.; Torrisi, L.; Ryc, L.; Ullschmied, J.

    2008-02-15

    Results of recent studies on highly charged Au ion generation, using the intense long pulses of the PALS high power iodine laser ({lambda}=1.315 {mu}m, E{sub L}=800 J/400 ps), operating under variable experimental conditions (1{omega}, 3{omega}, varying target thickness and changing focus positions), are presented. Both the ion collectors and the ion electrostatic analyzers were applied for the identification of ions in a large distance from the target. The time-of-flight collector signals were treated by a means of peak deconvolution assuming a shifted Maxwell-Boltzmann form of the constituent ion current peaks. Attention was paid to the influence of pulse precursor, which becomes evident, especially, if using thinner targets and 1{omega}. The results for 3{omega} point to the presence of several groups of ions with the highest recorded charge state Au{sup 53+}.

  9. Plasmon Mapping in Au@Ag Nanocube Assemblies

    PubMed Central

    2014-01-01

    Surface plasmon modes in metallic nanostructures largely determine their optoelectronic properties. Such plasmon modes can be manipulated by changing the morphology of the nanoparticles or by bringing plasmonic nanoparticle building blocks close to each other within organized assemblies. We report the EELS mapping of such plasmon modes in pure Ag nanocubes, Au@Ag core–shell nanocubes, and arrays of Au@Ag nanocubes. We show that these arrays enable the creation of interesting plasmonic structures starting from elementary building blocks. Special attention will be dedicated to the plasmon modes in a triangular array formed by three nanocubes. Because of hybridization, a combination of such nanotriangles is shown to provide an antenna effect, resulting in strong electrical field enhancement at the narrow gap between the nanotriangles. PMID:25067991

  10. Revealing the properties of Mn2Au for antiferromagnetic spintronics.

    PubMed

    Barthem, V M T S; Colin, C V; Mayaffre, H; Julien, M-H; Givord, D

    2013-01-01

    The continuous reduction in size of spintronic devices requires the development of structures, which are insensitive to parasitic external magnetic fields, while preserving the magnetoresistive signals of existing systems based on giant or tunnel magnetoresistance. This could be obtained in tunnel anisotropic magnetoresistance structures incorporating an antiferromagnetic, instead of a ferromagnetic, material. To turn this promising concept into real devices, new magnetic materials with large spin-orbit effects must be identified. Here we demonstrate that Mn2Au is not a Pauli paramagnet as hitherto believed but an antiferromagnet with Mn moments of ~4 μB. The particularly large strength of the exchange interactions leads to an extrapolated Néel temperature well above 1,000 K, so that ground-state magnetic properties are essentially preserved up to room temperature and above. Combined with the existence of a significant in-plane anisotropy, this makes Mn2Au the most promising material for antiferromagnetic spintronics identified so far.

  11. Magnetostatic interaction in electrodeposited Ni/Au multilayer nanowire arrays

    NASA Astrophysics Data System (ADS)

    He, Li-Zhong; Qin, Li-Rong; Zhao, Jian-Wei; Yin, Ying-Ying; Yang, Yu; Li, Guo-Qing

    2016-08-01

    Ordered Ni/Au multilayer nanowire arrays are successfully fabricated inside the nanochannels of anodic aluminum oxide template by pulse electrodeposition method. The thickness of the alternating layers is controlled to examine the magnetostatic interaction in Ni/Au multilayer nanowires. The magnetic easy axis parallel to the nanowires indicates that here the magnetostatic coupling along the wire axis dominates over the interactions perpendicular to the nanowires. However, the magnetostatic interaction between adjacent nanowires with larger magnetic layers is enhanced, leading to the existence of an optimum coercivity value. Project supported by the National Natural Science Foundation of China (Grant No. 11204246) and the Natural Science Foundation of CQCSTC (Grant No. cstc2014jcyjA50027).

  12. Magnetostatic interaction in electrodeposited Ni/Au multilayer nanowire arrays

    NASA Astrophysics Data System (ADS)

    He, Li-Zhong; Qin, Li-Rong; Zhao, Jian-Wei; Yin, Ying-Ying; Yang, Yu; Li, Guo-Qing

    2016-08-01

    Ordered Ni/Au multilayer nanowire arrays are successfully fabricated inside the nanochannels of anodic aluminum oxide template by pulse electrodeposition method. The thickness of the alternating layers is controlled to examine the magnetostatic interaction in Ni/Au multilayer nanowires. The magnetic easy axis parallel to the nanowires indicates that here the magnetostatic coupling along the wire axis dominates over the interactions perpendicular to the nanowires. However, the magnetostatic interaction between adjacent nanowires with larger magnetic layers is enhanced, leading to the existence of an optimum coercivity value. Project supported by the National Natural Science Foundation of China (Grant No. 11204246) and the Natural Science Foundation of CQCSTC (Grant No. cstc2014jcyjA50027).

  13. Au-Ag-Cu nano-alloys: tailoring of permittivity.

    PubMed

    Hashimoto, Yoshikazu; Seniutinas, Gediminas; Balčytis, Armandas; Juodkazis, Saulius; Nishijima, Yoshiaki

    2016-01-01

    Precious metal alloys enables new possibilities to tailor materials for specific optical functions. Here we present a systematic study of the effects of a nanoscale alloying on the permittivity of Au-Ag-Cu metals at 38 different atomic mixing ratios. The permittivity was measured and analyzed numerically by applying the Drude model. X-ray diffraction (XRD) revealed the face centered cubic lattice of the alloys. Both, optical spectra and XRD results point towards an equivalent composition-dependent electron scattering behavior. Correlation between the fundamental structural parameters of alloys and the resulting optical properties is elucidated. Plasmonic properties of the Au-Ag-Cu alloy nanoparticles were investigated by numerical simulations. Guidelines for designing plasmonic response of nano- structures and their patterns are presented from the material science perspective. PMID:27118459

  14. Synthesis of triangular Au core-Ag shell nanoparticles

    SciTech Connect

    Rai, Akhilesh; Chaudhary, Minakshi; Ahmad, Absar; Bhargava, Suresh; Sastry, Murali . E-mail: msastry@tatachemicals.com

    2007-07-03

    In this paper, we demonstrate a simple and reproducible method for the synthesis of triangular Au core-Ag shell nanoparticles. The triangular gold core is obtained by the reduction of gold ions by lemongrass extract. Utilizing the negative charge on the gold nanotriangles, silver ions are bound to their surface and thereafter reduced by ascorbic acid under alkaline conditions. The thickness of the silver shell may be modulated by varying the pH of the reaction medium. The formation of the Au core-Ag shell triangular nanostructures has been followed by UV-vis-NIR Spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy (TEM) and atomic force microscopy (AFM) measurements. The sharp vertices of the triangles coupled with the core-shell structure is expected to have potential for application in surface enhanced Raman spectroscopy and in the sensitive detection of biomolecules.

  15. Au-Ag-Cu nano-alloys: tailoring of permittivity

    PubMed Central

    Hashimoto, Yoshikazu; Seniutinas, Gediminas; Balčytis, Armandas; Juodkazis, Saulius; Nishijima, Yoshiaki

    2016-01-01

    Precious metal alloys enables new possibilities to tailor materials for specific optical functions. Here we present a systematic study of the effects of a nanoscale alloying on the permittivity of Au-Ag-Cu metals at 38 different atomic mixing ratios. The permittivity was measured and analyzed numerically by applying the Drude model. X-ray diffraction (XRD) revealed the face centered cubic lattice of the alloys. Both, optical spectra and XRD results point towards an equivalent composition-dependent electron scattering behavior. Correlation between the fundamental structural parameters of alloys and the resulting optical properties is elucidated. Plasmonic properties of the Au-Ag-Cu alloy nanoparticles were investigated by numerical simulations. Guidelines for designing plasmonic response of nano- structures and their patterns are presented from the material science perspective. PMID:27118459

  16. First enlargement within 1000 AU of a massive YSO

    NASA Astrophysics Data System (ADS)

    Sanna, A.

    2016-05-01

    We presented a comprehensive view, from scales of 0.1 pc down to 100 AU, of the gas dynamics driven by a massive young stellar object (YSO) in the star-forming region G023.01-00.41. Toward this region, we conducted both: 1) sub-arcsecond and high sensitivity Submillimeter Array (SMA) observations of different (e.g., CO, SiO, CH3CN, and CH3OH) molecular lines (Sanna et al. [2]), and 2) multi-epoch Very Long Baseline Interferometry (VLBI) observations of both H2O and CH3OH masers (Sanna et al. [3]). In particular, these VLBI observations allowed us to reconstruct, for the first time, both the 3D gas kinematics and magnetic field morphology in the vicinity (<1000 AU) of a massive YSO (Sanna et al. [1]).

  17. Rhombohedrally Distorted γ-Au5-xZn8+y Phases in the Au-Zn System

    SciTech Connect

    Thimmaiah, Srinivasa; Miller, Gordon J.

    2013-01-16

    The region of the Au–Zn phase diagram encompassing γ-brass-type phases has been studied experimentally from 45 to 85 atom % Zn. The γ phases were obtained directly from the pure elements by heating to 680 °C in evacuated silica tubes, followed by annealing at 300 °C. Powder X-ray and single-crystal diffraction studies show that γ-“Au5Zn8” phases adopt a rhombohedrally distorted Cr5Al8 structure type rather than the cubic Cu5Zn8 type. The refined compositions from two single crystals extracted from the Zn- and Au-rich loadings are Au4.27(3)Zn8.26(3)γ0.47 (I) and Au4.58(3)Zn8.12(3)γ0.3 (II), respectively (γ = vacancy). These (I and II) refinements indicated both nonstatistical mixing of Au and Zn atoms as well as partially ordered vacancy distributions. The structures of these γ phases were solved in the acentric space group R3m (No. 160, Z = 6), and the observed lattice parameters from powder patterns were found to be a = 13.1029(6) and 13.1345(8) Å and c = 8.0410(4) and 8.1103(6) Å for crystals I and II, respectively. According to single-crystal refinements, the vacancies were found on the outer tetrahedron (OT) and octahedron (OH) of the 26-atom cluster. Single-crystal structural refinement clearly showed that the vacancy content per unit cell increases with increasing Zn, or valence-electron concentration. Electronic structure calculations, using the tight-binding linear muffin-tin orbital method with the atomic-sphere approximation (TB-LMTO-ASA) method, indicated the presence of a well-pronounced pseudogap at the Fermi level for “Au5Zn8” as the representative composition, an outcome that is consistent with the Hume–Rothery interpretation of γ brass.

  18. Public benefits of public power. [Booklet

    SciTech Connect

    Not Available

    1980-01-01

    The principal characteristics and benefits of public power are described using a question and answer format. The book begins by defining public power, describing its history, and confirming that people have a right to choose. The answers to questions about the benefits of public power are grouped under three major headings: rates, local control; economic and political benefits; and power supply and consumption. Establishing community public systems is hard work, requiring a progression through local government authorization, legal and financial analyses, public persuasion, voter approval, and a bond issue. Electric utility statistics show that local public systems outnumber all other types of ownership. (DCK)

  19. Self-assembly of alkanols on Au(111) surfaces.

    PubMed

    Zhang, Hai-Ming; Yan, Jia-Wei; Xie, Zhao-Xiong; Mao, Bing-Wei; Xu, Xin

    2006-05-15

    Self-assembled monolayers (SAMs) of alkanols (1-C(N)H(2N+1)OH) with varying carbon-chain lengths (N = 10-30) have been systematically studied by means of scanning tunneling microscopy (STM) at the interfaces between alkanol solutions (or liquids) and Au(111) surfaces. The carbon skeletons were found to lie flat on the surfaces. This orientation is consistent with SAMs of alkanols on highly oriented pyrolytic graphite (HOPG) and MoS2 surfaces, and also with alkanes on reconstructed Au(111) surfaces. This result differs from a prior report, which claimed that 1-decanol molecules (N = 10) stood on their ends with the OH polar groups facing the gold substrate. Compared to alkanes, the replacement of one terminal CH3 group with an OH group introduces new bonding features for alkanols owing to the feasibility of forming hydrogen bonds. While SAMs of long-chain alkanols (N > 18) resemble those of alkanes, in which the aliphatic chains make a greater contribution, hydrogen bonding plays a more important role in the formation of SAMs of short-chain alkanols. Thus, in addition to the titled lamellar structure, a herringbone-like structure, seldom seen in SAMs of alkanes, is dominant in alkanol SAMs for values of N < 18. The odd-even effect present in alkane SAMs is also present in alkanol SAMs. Thus, the odd N alkanols (alkanols with an odd number of carbon atoms) adopt perpendicular lamellar structures owing to the favorable interactions of the CH3 terminal groups, similar to the result observed for odd alkanes. In contrast to alkanes on Au(111) surfaces, for which no SAMs on an unreconstructed gold substrate were observed, alkanols are capable of forming SAMs on either the reconstructed or the unreconstructed gold surfaces. Structural models for the packing of alkanol molecules on Au(111) surfaces have been proposed, which successfully explain these experimental observations.

  20. Au enrichment and vertical relaxation of the Cu3Au (111 ) surface studied by normal-incidence x-ray standing waves

    NASA Astrophysics Data System (ADS)

    Bauer, O.; Schmitz, C. H.; Ikonomov, J.; Willenbockel, M.; Soubatch, S.; Tautz, F. S.; Sokolowski, M.

    2016-06-01

    We have investigated the Cu3Au (111 ) surface, prepared under ultrahigh vacuum conditions by sputtering and annealing, by low energy electron diffraction (LEED), scanning tunneling microscopy (STM), x-ray photoelectron spectroscopy, and normal incidence x-ray standing waves (NIXSW). We find the surface to be depleted with Cu and enriched with Au at the same time, yielding a nominal Cu:Au ratio of 0.61:0.39 in the topmost layer. The STM images reveal that the first layer is nearly closely filled with atoms and contains a small amount of vacancies with an area concentration of about 5 % . Together with the Au enrichment, these cause local short-range disorder of the Au p (2 ×2 ) reconstruction. From this data, the average stoichiometry of the p (2 ×2 ) surface unit cell is estimated at C u2.22A u1.44□0.20 (instead of C u3.00A u1.00□0.00 of the ideal surface; □ denotes an atomic vacancy site). From NIXSW we find a significant outward relaxation of both the Cu and Au atoms of the topmost layer by 0.28 Å and 0.33 Å, which corresponds to 13 % and 15 % of the (111) bulk layer spacing of C u3Au . We suggest that this originates from a widening of the first/second layer spacing, by 6.8 % and 8.8 % for the Cu and Au atoms, respectively, plus an additional rigid increase in the second/third layer spacing by 6.2 % . We explain this by steric repulsions between Au atoms of the topmost layer, replacing smaller Cu atoms, and Au atoms in the second layer in combination with disorder. Finally, a lateral reconstruction, similar to that on the Au(111) surface, but with a much larger periodicity of 290 Å, is identified from LEED.

  1. Long Term Measurement of the Vapor Pressure of Gold in the Au-C System

    NASA Technical Reports Server (NTRS)

    Copland, Evan H.

    2009-01-01

    Incorporating the {Au(s,l) + graphite} reference in component activity measurements made with the multiple effusion-cell vapor source mass spectrometry (multicell KEMS) technique provides a fixed temperature defining ITS-90 (T(sub mp)(Au) = 1337.33K) and a systematic method to check accuracy. Over a 2 year period delta H sub(298)Au was determined by the 2nd and 3rd law methods in 25 separate experiments and were in the ranges 362.2 plus or minus 3.3 kJmol(sup -1) and 367.8 plus or minus 1.1 kJmol(sup -1), respectively. This 5 kJmol-1 discrepancy is transferred directly to the measured activities. This is unacceptable and the source of this discrepancy needs to be understood and corrected. Accepting the 2nd law value increases p(Au) by about 50 percent, brings the 2nd and 3rd law values into agreement and removes the T dependence in the 3rd law values. While compelling, there is no way to independently determine instrument sensitivities, S(sub Au), with T in a single experiment with KEMS. This lack of capability is stopping a deeper understanding of this problem. In addition, the Au-C phase diagram suggests a eutectic invariant reaction: L-Au(4.7at%C) = FCC-Au(0.08at%C) + C(graphite) at T(sub e) approximately 1323K. This high C concentration in Au(l) must reduce p(Au) in equilibrium with {Au(s,l) + graphite} and raises some critical questions about the Gibbs free energy functions of Au(s,l) and the Au fixed point (T(sub mp)(Au) = 1337.33K) which is always measured in graphite.

  2. First Results on High-spin States in ^179Au

    NASA Astrophysics Data System (ADS)

    Mueller, W. F.; Bingham, C. R.; Reviol, W.; Riedinger, L. L.; Smith, B. H.; Wauters, J.; Ahmad, I.; Amro, H. A.; Blumenthal, D. J.; Carpenter, M. P.; Davids, C. N.; Fischer, S. M.; Hackman, G.; Henderson, D. J.; Janssens, R. V. F.; Khoo, T. L.; Lauritsen, T.; Lister, C. J.; Nisius, D. T.; Seweryniak, D.; Ma, W. C.

    1996-05-01

    High-spin states in ^179Au were studied for the first time in two experiments at the Argonne uc(atlas) facility. The ^144Sm(^40Ar,p4n)^179Au reaction at 207 MeV was used for the first experiment and ^124Te(^58Ni,p2n)^179Au at 255 MeV in the second. The setup in the first experiment consisted of the Fragment Mass Analyzer (uc(fma)) plus Parallel Plate Avalanche Counter (uc(ppac)) system and 10 Compton-suppressed Ge detectors (CSG's). From this run, several transitions from the yrast bands were established. The latter experiment utilized the uc(fma) + uc(ppac) system in conjunction with the uc(aye-ball) array of 19 Ge detectors (eight >70% efficient CSG's, nine 25% efficient CSG's, and two LEPS; one with Compton suppression) and a double sided silicon strip detector (uc(dssd).) The results from these experiments, including a level scheme, will be presented and discussed.

  3. Probing the interstellar medium with pulsars on AU scales

    NASA Technical Reports Server (NTRS)

    Frail, Dale A.; Weisberg, Joel M.; Cordes, James M.; Mathers, Corey

    1994-01-01

    We present a new technique, multiepoch observations of 21 cm absorption against high-velocity pulsars, to probe the properties of the cold neutral hydrogen gas (H I) in the interstellar medium (ISM) at AU scales. In three epochs, over a 1.7 yr interval, we find evidence for significant opacity variations toward all of the pulsars in our sample. Small-scale structure in the ISM is detected on a range of scales from 5 AU to 100 AU, over a wide range of distances (50-2600 pc), opacities (tau(sub max) = 0.1 - 2.5) and directions (anticenter, interarm, high latitude, and local ISM). It appears that small-scale structure is a general property of the ISM and is not confined to special lines of sight. A significant fraction (10%-15%) of the cold H I gas is in this form. These opacity variations do not show any strong correlations with such parameters as transverse distance or integrated opacity, and there is no obvious relation between these structures and those seen in the ionized phase of the ISM.

  4. Synthesis of Au-Pd Nanoflowers Through Nanocluster Assembly

    SciTech Connect

    Xu, Jianguang; Howe, Jane Y; Chi, Miaofang; Wilson, Adria; Rathmall, Aaron; Wiley, Benjamin J

    2011-01-01

    Reduction of Pd ions by hydroquinone in the presence of gold nanoparticles and polyvinylpyrrolidone resulted in the formation of nanoflowers with a Au core and Pd petals. Addition of HCl to the synthesis halted the reduction by hydroquinone and enabled the acquisition of snapshots of the nanoflowers at different stages of growth. TEM images of the reaction after 10 s show that the nanoflower morphology resulted from the homogeneous nucleation of Pd clusters in solution and their subsequent attachment to gold seeds coated with a thin (0.8 {+-} 0.1 nm) shell of Pd. UV-visible spectra also indicate Pd clusters formed in the early stages of the reaction and disappeared as the nanoflowers grew. The speed at which this reaction can be halted is useful not only for producing a variety of bimetallic nanostructures with precisely controlled dimensions and morphologies but also for understanding the growth mechanism of these structures. The ability of the AuPd core-shell structure to catalyze the Suzuki coupling reaction of iodobenzene to phenylboronic acid was probed and compared against the activity of Pd nanocubes and thin-shelled AuPd core-shell nanoparticles. The results of this study suggest that Suzuki coupling was not affected by the surface structure or subsurface composition of the nanoparticles, but instead was primarily catalyzed by molecular Pd species that leached from the nanostructures.

  5. Synthesis and Catalytic Properties of Au Pd Nanoflowers

    SciTech Connect

    Xu, Jianguang; Wilson, Adria; Howe, Jane Y; Chi, Miaofang; Wiley, Benjamin J

    2011-01-01

    Reduction of Pd ions by hydroquinone in the presence of gold nanoparticles and polyvinylpyrrolidone resulted in the formation of nanoflowers with a Au core and Pd petals. Addition of HCl to the synthesis halted the reduction by hydroquinone and enabled the acquisition of snapshots of the nanoflowers at different stages of growth. TEM images of the reaction after 10 s show that the nanoflower morphology resulted from the homogeneous nucleation of Pd clusters in solution and their subsequent attachment to gold seeds coated with a thin (0.8 0.1 nm) shell of Pd. UV visible spectra also indicate Pd clusters formed in the early stages of the reaction and disappeared as the nanoflowers grew. The speed at which this reaction can be halted is useful not only for producing a variety of bimetallic nanostructures with precisely controlled dimensions and morphologies but also for understanding the growth mechanism of these structures. The ability of the AuPd core shell structure to catalyze the Suzuki coupling reaction of iodobenzene to phenylboronic acid was probed and compared against the activity of Pd nanocubes and thin-shelled AuPd core shell nanoparticles. The results of this study suggest that Suzuki coupling was not affected by the surface structure or subsurface composition of the nanoparticles, but instead was primarily catalyzed by molecular Pd species that leached from the nanostructures.

  6. Photochromic reaction of the diarylethene derivative on Au nanoparticles

    NASA Astrophysics Data System (ADS)

    Takahashi, Ryoji; Kaneko, Satoshi; Fujii, Shintaro; Kiguchi, Manabu

    2015-03-01

    We have studied the photochromic reaction of the diarylethene derivative on Au nanoparticles using the incoherent excitation as a function of the wavelength of the irradiation light with the aim to clarify the effect of metal nanoparticles on the reaction yield. The photochemical reaction was suppressed by the Au nanoparticles under the irradiation of light whose wave length was shorter than 700 nm, while photochemical reaction was enhanced by the irradiation of light whose wavelength was longer than 750 nm via two-photon absorption process. The suppression of the photochemical reaction could be explained by the quenching of the excited state via radiative and non-radiative decay through energy or charge transfer to the metal substrate (e.g. electron-hole pair formation, surface plasmon excitation, formation of induced-dipole induced-dipole coupling), and the absorption of light by the Au nanoparticle. Invited talk at the 7th International Workshop on Advanced Materials Science and Nanotechnology IWAMSN2014, 2-6 November, 2014, Ha Long, Vietnam.

  7. Effect of microstructure on Au/sapphire interfacial thermal resistance

    SciTech Connect

    Xu Yibin; Kato, Ryozo; Goto, Masahiro

    2010-11-15

    We deposit Au films on single crystal sapphire substrates by sputtering and evaporation methods. The microstructure characteristics such as crystal textures, grain sizes, and fraction of contacted area of the films are examined by x-ray diffraction and transmission electron microscopy. The sputtered films have an average grain size of about 200 nm and perfectly attach to the substrates; the as-evaporated films partially attach to the substrate; the grain size varies from 10 to 30 nm, and after annealing, increases to 50 nm. Au{sub 2}Al phase is observed in the annealed samples. The interfacial thermal resistance is measured by a frequency domain thermoreflectance method. The thermal resistance of the sputtered Au/sapphire interfaces is 35.5x10{sup -9} m{sup 2} K W{sup -1}, and those of the evaporated samples are up to three times as large as this value. The change in interfacial thermal resistance is explained by the effect of detachment using a parallel arranged thermal resistance model, the effect of grain size, and the influence of chemical bonding at the interfaces.

  8. Photoacoustic emission from Au nanoparticles arrayed on thermal insulation layer.

    PubMed

    Namura, Kyoko; Suzuki, Motofumi; Nakajima, Kaoru; Kimura, Kenji

    2013-04-01

    Efficient photoacoustic emission from Au nanoparticles on a porous SiO(2) layer was investigated experimentally and theoretically. The Au nanoparticle arrays/porous SiO(2)/SiO(2)/Ag mirror sandwiches, namely, local plasmon resonators, were prepared by dynamic oblique deposition (DOD). Photoacoustic measurements were performed on the local plasmon resonators, whose optical absorption was varied from 0.03 (3%) to 0.95 by varying the thickness of the dielectric SiO(2) layer. The sample with high absorption (0.95) emitted a sound that was eight times stronger than that emitted by graphite (0.94) and three times stronger than that emitted by the sample without the porous SiO(2) layer (0.93). The contribution of the porous SiO(2) layer to the efficient photoacoustic emission was analyzed by means of a numerical method based on a one-dimensional heat transfer model. The result suggested that the low thermal conductivity of the underlying porous layer reduces the amount of heat escaping from the substrate and contributes to the efficient photoacoustic emission from Au nanoparticle arrays. Because both the thermal conductivity and the spatial distribution of the heat generation can be controlled by DOD, the local plasmon resonators produced by DOD are suitable for the spatio-temporal modulation of the local temperature. PMID:23571958

  9. Fe/Au Core-Shell Nanoparticles for Biomedical Applications

    NASA Astrophysics Data System (ADS)

    Sra, Amandeep; Leslie-Pelecky, Diandra

    2009-10-01

    The physical properties of nanoparticles, including size, composition and surface chemistry, greatly influence biological and pharmacological properties and, ultimately, their clinical applications. Superparamagnetic iron oxide nanoparticles are widely used for applications such as MRI contrast agents, drug delivery via magnetic targeting and hyperthermia due to their chemical stability and biocompatibility; however, enhancing the saturation magnetization (Ms) of nanoparticles would produce greater sensitivity. Our design strategy involves a bottom-up wet chemistry approach to the synthesis of Fe nanoparticles. Specific advantages of Fe are the high value of Ms (210 emu/g in bulk) coupled with low toxicity; however, Fe nanoparticles must be protected from oxidation, which causes a dramatic reduction in Ms. To circumvent oxidation, Fe nanoparticles are coated with a Au shell that prevents the oxidation of the magnetic core and also provides the nanoparticles with plasmonic properties for optical stimulation. Ligands of various functionalities can be introduced through the well established Au-thiol surface chemistry for different biomedical applications while maintaining the magnetic functionality of the Fe core. In this presentation, we will discuss the physical, chemical and magnetic properties of our Fe/Au nanoparticles and their resistance to oxidation.

  10. Cell adhesion and proliferation on polyethylene grafted with Au nanoparticles

    NASA Astrophysics Data System (ADS)

    Kasálková, N. Slepičková; Slepička, P.; Kolská, Z.; Sajdl, P.; Bačáková, L.; Rimpelová, S.; Švorčík, V.

    2012-02-01

    Plasma treatment and subsequent Au nano-particles grafting of polyethylene (PE) lead to changes in surface morphology, roughness and wettability, significantly increasing the attractiveness of the material for cells. The PE samples were exposed to argon plasma. Plasma modified PE was chemically grafted by immersion to biphenyldithiol and consequently into solution of Au nano-particles. Changes in chemical structure of the modified PE were studied using X-ray Photoelectron Spectroscopy (XPS) and electrokinetic analysis ( ζ-potential). The surface wettability of the modified PE samples was examined by measurement of the contact angle by standard goniometry. The surface morphology of the plasma modified PE and that grafted with Au nano-particles was studied by Atomic Force Microscopy (AFM). The modified PE samples were seeded with rat vascular smooth muscle cells (VSMCs) and their adhesion and proliferation were studied. Chemically bounded biphenyldithiol increases the number of the incorporated gold nano-particles and changes sample surface properties. The presence of the biphenyldithiol and the gold nano-particles on the PE surface influences dramatically adhesion and proliferation of VSMCs.

  11. Evaluation of the clinical chemistry analyser Olympus AU400.

    PubMed

    Lasnier, E; Mario, N; Boque, M C; You, S N; Vaubourdolle, M

    2000-10-01

    The Olympus AU400 analyser (Olympus, Tokyo, Japan) is an automated chemistry instrument for turbidimetric, spectrophotometric and ion selective electrode measurements. Overall analytical performances of the AU400 and the reagents provided by Olympus were evaluated according to the French Society of Clinical Biology guidelines. Twenty parameters including specific proteins, substrates, enzyme activities and electrolytes were tested. The linearity exceeded the specifications given by the manufacturer. Within- and between-run imprecision (CV%), evaluated at two levels, was below 1.5% for ion selective electrode parameters and 3% for other analytes, except for CO2, alkaline phosphatase at low levels and magnesium. Results compared well with those obtained with the analysers routinely used in our laboratory (Behring BNII, Olympus AU800 and Beckman CX3 Delta). The usual positive interferences from lipaemia and haemoglobin on total protein measurement were observed. Creatine kinase and alkaline phosphatase assays were the subject of positive and negative interference by haemoglobin, respectively. There was a negative interference by bilirubin in the uric acid, aspartate-amino transferase, creatine kinase and lactate dehydrogenase assays and a positive interference in the calcium assay. The system was found to be very easy to use and the workstation is user-friendly. PMID:11140621

  12. The Thermal Stability of Nanocrystalline Au-Cu Alloys

    SciTech Connect

    Jankowski, A F; Saw, C K; Hayes, J P

    2006-02-15

    Grain refinement to the nanocrystalline scale is known to enhance physical properties as strength and surface hardness. For the case of Au-Cu alloys, development of the pulsed electroplating has led to the functional control of nanocrystalline grain size in the as-deposited condition. The thermal aging of Au-Cu electrodeposits is now investigated to assess the stability of the nanocrystalline grain structure and the difference between two diffusion mechanisms. The mobility of grain boundaries, dominant at low temperatures, leads to coarsening of grain size whereas at high temperature the process of bulk diffusion dominates. Although the kinetics of bulk diffusion are slow below 500 K at 10{sup -20} cm{sup 2} {center_dot} sec, the kinetics of grain boundary diffusion are faster at 10{sup -16} cm{sup 2} {center_dot} sec. The diffusivity values indicate that the grain boundaries of the as-deposited nanocrystalline Au-Cu are mobile and sensitive to low-temperature anneal treatments affecting the grain size, hence the strength of the material.

  13. Kinetics of low-temperature CO oxidation on Au(111)

    NASA Astrophysics Data System (ADS)

    Thuening, Theodore; Walker, Joshua; Adams, Heather; Furlong, Octavio; Tysoe, Wilfred T.

    2016-06-01

    The oxidation of carbon monoxide on oxygen-modified Au(111) surfaces is studied using a combination of reflection-absorption infrared spectroscopy (RAIRS) and temperature-programmed desorption (TPD). TPD reveals that CO desorbs in two states with the low-temperature state have a peak temperature between ~ 130 and 150 K, and the higher-temperature state having a peak temperature that varies from ~ 175 to ~ 220 K depending on the initial oxygen and CO coverages. Infrared spectroscopy indicates that the low-temperature CO desorption state is predominantly associated with CO adsorbed on Auδ + sites, while the higher-temperature states are due to CO on Au0 sites. No additional vibrational features are detected indicating that CO reacts directly with adsorbed atomic oxygen on gold to form CO2. Estimates of the activation energy for CO2 formation suggest that they are in the same range and found for supported gold catalysts at reaction temperature below ~ 300 K.

  14. Surface dislocation nucleation controlled deformation of Au nanowires

    SciTech Connect

    Roos, B.; Kapelle, B.; Volkert, C. A.; Richter, G.

    2014-11-17

    We investigate deformation in high quality Au nanowires under both tension and bending using in-situ transmission electron microscopy. Defect evolution is investigated during: (1) tensile deformation of 〈110〉 oriented, initially defect-free, single crystal nanowires with cross-sectional widths between 30 and 300 nm, (2) bending deformation of the same wires, and (3) tensile deformation of wires containing coherent twin boundaries along their lengths. We observe the formation of twins and stacking faults in the single crystal wires under tension, and storage of full dislocations after bending of single crystal wires and after tension of twinned wires. The stress state dependence of the deformation morphology and the formation of stacking faults and twins are not features of bulk Au, where deformation is controlled by dislocation interactions. Instead, we attribute the deformation morphologies to the surface nucleation of either leading or trailing partial dislocations, depending on the Schmid factors, which move through and exit the wires producing stacking faults or full dislocation slip. The presence of obstacles such as neutral planes or twin boundaries hinder the egress of the freshly nucleated dislocations and allow trailing and leading partial dislocations to combine and to be stored as full dislocations in the wires. We infer that the twins and stacking faults often observed in nanoscale Au specimens are not a direct size effect but the result of a size and obstacle dependent transition from dislocation interaction controlled to dislocation nucleation controlled deformation.

  15. Photoacoustic emission from Au nanoparticles arrayed on thermal insulation layer.

    PubMed

    Namura, Kyoko; Suzuki, Motofumi; Nakajima, Kaoru; Kimura, Kenji

    2013-04-01

    Efficient photoacoustic emission from Au nanoparticles on a porous SiO(2) layer was investigated experimentally and theoretically. The Au nanoparticle arrays/porous SiO(2)/SiO(2)/Ag mirror sandwiches, namely, local plasmon resonators, were prepared by dynamic oblique deposition (DOD). Photoacoustic measurements were performed on the local plasmon resonators, whose optical absorption was varied from 0.03 (3%) to 0.95 by varying the thickness of the dielectric SiO(2) layer. The sample with high absorption (0.95) emitted a sound that was eight times stronger than that emitted by graphite (0.94) and three times stronger than that emitted by the sample without the porous SiO(2) layer (0.93). The contribution of the porous SiO(2) layer to the efficient photoacoustic emission was analyzed by means of a numerical method based on a one-dimensional heat transfer model. The result suggested that the low thermal conductivity of the underlying porous layer reduces the amount of heat escaping from the substrate and contributes to the efficient photoacoustic emission from Au nanoparticle arrays. Because both the thermal conductivity and the spatial distribution of the heat generation can be controlled by DOD, the local plasmon resonators produced by DOD are suitable for the spatio-temporal modulation of the local temperature.

  16. Au42: A possible ground-state noble metallic nanotube

    NASA Astrophysics Data System (ADS)

    Wang, Jing; Ning, Hua; Ma, Qing-Min; Liu, Ying; Li, You-Cheng

    2008-10-01

    A large hollow tubelike Au42 is predicted as a new ground-state configuration based on the scalar relativistic density functional theory. The shape of this new Au42 cluster is similar to a (5,5) single-wall gold nanotube, the two ends of which are capped by half of a fullerenelike Au32. In the same way, a series of Aun (n =37,42,47,52,57,62,67,72,…, Δn =5) tubelike structures has been constructed. The highest occupied molecular orbital-lowest unoccupied molecular orbital gaps suggested a significant semiconductor-conductor alternation in n ɛ[32,47]. Similar to the predictions and speculation of Daedalus [D. E. H. Jones, New Sci. 32, 245 (1966); E. Osawa, Superaromaticity (Kagaku, Kyoto, 1970), Vol. 25, pp. 854-863; Z. Yoshida and E. Osawa, Aromaticity Chemical Monograph (Kagaku Dojin, Kyoto, Japan, 1971), Vol. 22, pp. 174-176; D. A. Bochvar and E. G. Gal'pern, Dokl. Akad. Nauk SSSR 209, 610 (1973)], here a large hollow ground-state gold nanotube was predicted theoretically.

  17. Public Television as a Public Good

    ERIC Educational Resources Information Center

    Campbell, David C.; Campbell, Joyce B.

    1978-01-01

    Evaluates the Station Program Cooperative (SPC) of the Public Broadcasting System (PBS) instituted in 1974 to reduce network executive's power in public television programming by using local station program managers as consumer representatives. (MH)

  18. Realism in Public Library Public Relations

    ERIC Educational Resources Information Center

    Scilken, Marvin H.

    1972-01-01

    The threat from school libraries coupled with misdirected publicity efforts has created the need for a massive nationwide public relations and advertising campaign whose main appeal should be to nonusers. (Author/NH)

  19. Dielectron Azimuthal Anisotropy at mid-rapidity in Au+Au collisions at root s=200GeV

    DOE PAGESBeta

    Adamczyk, L.

    2014-12-11

    We report on the first measurement of the azimuthal anisotropy (v₂) of dielectrons (e⁺e⁻ pairs) at mid-rapidity from √(sNN)=200 GeV Au + Au collisions with the STAR detector at the Relativistic Heavy Ion Collider (RHIC), presented as a function of transverse momentum (pT) for different invariant-mass regions. In the mass region Mee<1.1 GeV/c² the dielectron v₂ measurements are found to be consistent with expectations from π⁰,η,ω, and Φ decay contributions. In the mass region 1.1ee<2.9GeV/c², the measured dielectron v₂ is consistent, within experimental uncertainties, with that from the cc¯ contributions.

  20. Transverse momentum dependence of η meson suppression in Au+Au collisions at sNN=200 GeV

    NASA Astrophysics Data System (ADS)

    Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Al-Bataineh, H.; Alexander, J.; Aoki, K.; Aphecetche, L.; Aramaki, Y.; Asai, J.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Bai, M.; Baksay, G.; Baksay, L.; Baldisseri, A.; Barish, K. N.; Barnes, P. D.; Bassalleck, B.; Basye, A. T.; Bathe, S.; Batsouli, S.; Baublis, V.; Baumann, C.; Bazilevsky, A.; Belikov, S.; Belmont, R.; Bennett, R.; Berdnikov, A.; Berdnikov, Y.; Bickley, A. A.; Boissevain, J. G.; Bok, J. S.; Borel, H.; Boyle, K.; Brooks, M. L.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Butsyk, S.; Camacho, C. M.; Campbell, S.; Chang, B. S.; Chang, W. C.; Charvet, J.-L.; Chen, C.-H.; Chernichenko, S.; Chi, C. Y.; Chiu, M.; Choi, I. J.; Choudhury, R. K.; Christiansen, P.; Chujo, T.; Chung, P.; Churyn, A.; Chvala, O.; Cianciolo, V.; Citron, Z.; Cole, B. A.; Connors, M.; Constantin, P.; Csanád, M.; Csörgő, T.; Dahms, T.; Dairaku, S.; Danchev, I.; Das, K.; Datta, A.; David, G.; Denisov, A.; D'Enterria, D.; Deshpande, A.; Desmond, E. J.; Dietzsch, O.; Dion, A.; Donadelli, M.; Drapier, O.; Drees, A.; Drees, K. A.; Dubey, A. K.; Durham, J. M.; Durum, A.; Dutta, D.; Dzhordzhadze, V.; Edwards, S.; Efremenko, Y. V.; Ellinghaus, F.; Engelmore, T.; Enokizono, A.; En'yo, H.; Esumi, S.; Eyser, K. O.; Fadem, B.; Fields, D. E.; Finger, M., Jr.; Finger, M.; Fleuret, F.; Fokin, S. L.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fujiwara, K.; Fukao, Y.; Fusayasu, T.; Garishvili, I.; Glenn, A.; Gong, H.; Gonin, M.; Gosset, J.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grosse Perdekamp, M.; Gunji, T.; Gustafsson, H.-Å.; Hadj Henni, A.; Haggerty, J. S.; Hahn, K. I.; Hamagaki, H.; Hamblen, J.; Hanks, J.; Han, R.; Hartouni, E. P.; Haruna, K.; Haslum, E.; Hayano, R.; Heffner, M.; Hegyi, S.; Hemmick, T. K.; Hester, T.; He, X.; Hill, J. C.; Hohlmann, M.; Holzmann, W.; Homma, K.; Hong, B.; Horaguchi, T.; Hornback, D.; Huang, S.; Ichihara, T.; Ichimiya, R.; Ide, J.; Iinuma, H.; Ikeda, Y.; Imai, K.; Imrek, J.; Inaba, M.; Isenhower, D.; Ishihara, M.; Isobe, T.; Issah, M.; Isupov, A.; Ivanischev, D.; Jacak, B. V.; Jia, J.; Jin, J.; Johnson, B. M.; Joo, K. S.; Jouan, D.; Jumper, D. S.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kamin, J.; Kang, J. H.; Kapustinsky, J.; Karatsu, K.; Kawall, D.; Kawashima, M.; Kazantsev, A. V.; Kempel, T.; Khanzadeev, A.; Kijima, K. M.; Kikuchi, J.; Kim, B. I.; Kim, D. H.; Kim, D. J.; Kim, E. J.; Kim, E.; Kim, S. H.; Kim, Y. J.; Kinney, E.; Kiriluk, K.; Kiss, Á.; Kistenev, E.; Klay, J.; Klein-Boesing, C.; Kochenda, L.; Komkov, B.; Konno, M.; Koster, J.; Kotchetkov, D.; Kozlov, A.; Král, A.; Kravitz, A.; Kunde, G. J.; Kurita, K.; Kurosawa, M.; Kweon, M. J.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lai, Y. S.; Lajoie, J. G.; Layton, D.; Lebedev, A.; Lee, D. M.; Lee, J.; Lee, K. B.; Lee, K.; Lee, K. S.; Lee, T.; Leitch, M. J.; Leite, M. A. L.; Leitner, E.; Lenzi, B.; Liebing, P.; Linden Levy, L. A.; Liška, T.; Litvinenko, A.; Liu, H.; Liu, M. X.; Li, X.; Love, B.; Luechtenborg, R.; Lynch, D.; Maguire, C. F.; Makdisi, Y. I.; Malakhov, A.; Malik, M. D.; Manko, V. I.; Mannel, E.; Mao, Y.; Mašek, L.; Masui, H.; Matathias, F.; McCumber, M.; McGaughey, P. L.; Means, N.; Meredith, B.; Miake, Y.; Mignerey, A. C.; Mikeš, P.; Miki, K.; Milov, A.; Mishra, M.; Mitchell, J. T.; Mohanty, A. K.; Morino, Y.; Morreale, A.; Morrison, D. P.; Moukhanova, T. V.; Mukhopadhyay, D.; Murata, J.; Nagamiya, S.; Nagle, J. L.; Naglis, M.; Nagy, M. I.; Nakagawa, I.; Nakamiya, Y.; Nakamura, T.; Nakano, K.; Newby, J.; Nguyen, M.; Niita, T.; Nouicer, R.; Nyanin, A. S.; O'Brien, E.; Oda, S. X.; Ogilvie, C. A.; Okada, K.; Oka, M.; Onuki, Y.; Oskarsson, A.; Ouchida, M.; Ozawa, K.; Pak, R.; Palounek, A. P. T.; Pantuev, V.; Papavassiliou, V.; Park, I. H.; Park, J.; Park, S. K.; Park, W. J.; Pate, S. F.; Pei, H.; Peng, J.-C.; Pereira, H.; Peresedov, V.; Peressounko, D. Yu.; Pinkenburg, C.; Pisani, R. P.; Proissl, M.; Purschke, M. L.; Purwar, A. K.; Qu, H.; Rak, J.; Rakotozafindrabe, A.; Ravinovich, I.; Read, K. F.; Rembeczki, S.; Reygers, K.; Riabov, V.; Riabov, Y.; Richardson, E.; Roach, D.; Roche, G.; Rolnick, S. D.; Rosati, M.; Rosen, C. A.; Rosendahl, S. S. E.; Rosnet, P.; Rukoyatkin, P.; Ružička, P.; Rykov, V. L.; Sahlmueller, B.; Saito, N.; Sakaguchi, T.; Sakai, S.; Sakashita, K.; Samsonov, V.; Sano, S.; Sato, T.; Sawada, S.; Sedgwick, K.; Seele, J.; Seidl, R.; Semenov, A. Yu.; Semenov, V.; Seto, R.; Sharma, D.; Shein, I.; Shibata, T.-A.; Shigaki, K.; Shimomura, M.; Shoji, K.; Shukla, P.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Silvestre, C.; Sim, K. S.; Singh, B. K.; Singh, C. P.; Singh, V.; Slunečka, M.; Soldatov, A.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Sourikova, I. V.; Sparks, N. A.; Staley, F.; Stankus, P. W.; Stenlund, E.; Stepanov, M.; Ster, A.; Stoll, S. P.; Sugitate, T.; Suire, C.; Sukhanov, A.; Sziklai, J.; Takagui, E. M.; Taketani, A.; Tanabe, R.; Tanaka, Y.; Tanida, K.; Tannenbaum, M. J.; Tarafdar, S.; Taranenko, A.; Tarján, P.; Themann, H.; Thomas, T. L.; Togawa, M.; Toia, A.; Tomášek, L.; Tomita, Y.; Torii, H.; Towell, R. S.; Tram, V.-N.; Tserruya, I.; Tsuchimoto, Y.; Vale, C.; Valle, H.; van Hecke, H. W.; Vazquez-Zambrano, E.; Veicht, A.; Velkovska, J.; Vértesi, R.; Vinogradov, A. A.; Virius, M.; Vrba, V.; Vznuzdaev, E.; Wang, X. R.; Watanabe, D.; Watanabe, K.; Watanabe, Y.; Wei, F.; Wei, R.; Wessels, J.; White, S. N.; Winter, D.; Wood, J. P.; Woody, C. L.; Wright, R. M.; Wysocki, M.; Xie, W.; Yamaguchi, Y. L.; Yamaura, K.; Yang, R.; Yanovich, A.; Ying, J.; Yokkaichi, S.; Young, G. R.; Younus, I.; You, Z.; Yushmanov, I. E.; Zajc, W. A.; Zaudtke, O.; Zhang, C.; Zhou, S.; Zolin, L.

    2010-07-01

    New measurements by the PHENIX experiment at the Relativistic Heavy Ion Collider for η production at midrapidity as a function of transverse momentum (pT) and collision centrality in sNN=200 GeV Au+Au and p+p collisions are presented. They indicate nuclear modification factors (RAA) which are similar in both magnitude and trend to those found in earlier π0 measurements. Linear fits to RAA as a function of pT in 5-20 GeV/c show that the slope is consistent with zero within two standard deviations at all centralities, although a slow rise cannot be excluded. Having different statistical and systematic uncertainties, the π0 and η measurements are complementary at high pT; thus, along with the extended pT range of these data they can provide additional constraints for theoretical modeling and the extraction of transport properties.

  1. Elliptic and Hexadecapole Flow of Charged Hadrons in Au+Au Collisions at sNN=200GeV

    NASA Astrophysics Data System (ADS)

    Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Al-Bataineh, H.; Alexander, J.; Aoki, K.; Aramaki, Y.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Bai, M.; Baksay, G.; Baksay, L.; Barish, K. N.; Bassalleck, B.; Basye, A. T.; Bathe, S.; Baublis, V.; Baumann, C.; Bazilevsky, A.; Belikov, S.; Belmont, R.; Bennett, R.; Berdnikov, A.; Berdnikov, Y.; Bickley, A. A.; Bok, J. S.; Boyle, K.; Brooks, M. L.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Butsyk, S.; Camacho, C. M.; Campbell, S.; Chen, C.-H.; Chi, C. Y.; Chiu, M.; Choi, I. J.; Choudhury, R. K.; Christiansen, P.; Chujo, T.; Chung, P.; Chvala, O.; Cianciolo, V.; Citron, Z.; Cole, B. A.; Connors, M.; Constantin, P.; Csanád, M.; Csörgő, T.; Dahms, T.; Dairaku, S.; Danchev, I.; Das, K.; Datta, A.; David, G.; Denisov, A.; Deshpande, A.; Desmond, E. J.; Dietzsch, O.; Dion, A.; Donadelli, M.; Drapier, O.; Drees, A.; Drees, K. A.; Durham, J. M.; Durum, A.; Dutta, D.; Edwards, S.; Efremenko, Y. V.; Ellinghaus, F.; Engelmore, T.; Enokizono, A.; En'Yo, H.; Esumi, S.; Fadem, B.; Fields, D. E.; Finger, M., Jr.; Finger, M.; Fleuret, F.; Fokin, S. L.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fujiwara, K.; Fukao, Y.; Fusayasu, T.; Garishvili, I.; Glenn, A.; Gong, H.; Gonin, M.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grosse Perdekamp, M.; Gunji, T.; Gustafsson, H.-Å.; Haggerty, J. S.; Hahn, K. I.; Hamagaki, H.; Hamblen, J.; Hanks, J.; Han, R.; Hartouni, E. P.; Haslum, E.; Hayano, R.; Heffner, M.; Hegyi, S.; Hemmick, T. K.; Hester, T.; He, X.; Hill, J. C.; Hohlmann, M.; Holzmann, W.; Homma, K.; Hong, B.; Horaguchi, T.; Hornback, D.; Huang, S.; Ichihara, T.; Ichimiya, R.; Ide, J.; Ikeda, Y.; Imai, K.; Inaba, M.; Isenhower, D.; Ishihara, M.; Isobe, T.; Issah, M.; Isupov, A.; Ivanischev, D.; Jacak, B. V.; Jia, J.; Jin, J.; Johnson, B. M.; Joo, K. S.; Jouan, D.; Jumper, D. S.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kamin, J.; Kang, J. H.; Kapustinsky, J.; Karatsu, K.; Kawall, D.; Kawashima, M.; Kazantsev, A. V.; Kempel, T.; Khanzadeev, A.; Kijima, K. M.; Kim, B. I.; Kim, D. H.; Kim, D. J.; Kim, E. J.; Kim, E.; Kim, S. H.; Kim, Y. J.; Kinney, E.; Kiriluk, K.; Kiss, Á.; Kistenev, E.; Kochenda, L.; Komkov, B.; Konno, M.; Koster, J.; Kotchetkov, D.; Kozlov, A.; Král, A.; Kravitz, A.; Kunde, G. J.; Kurita, K.; Kurosawa, M.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lai, Y. S.; Lajoie, J. G.; Lebedev, A.; Lee, D. M.; Lee, J.; Lee, K. B.; Lee, K.; Lee, K. S.; Leitch, M. J.; Leite, M. A. L.; Leitner, E.; Lenzi, B.; Liebing, P.; Linden Levy, L. A.; Liška, T.; Litvinenko, A.; Liu, H.; Liu, M. X.; Li, X.; Love, B.; Luechtenborg, R.; Lynch, D.; Maguire, C. F.; Makdisi, Y. I.; Malakhov, A.; Malik, M. D.; Manko, V. I.; Mannel, E.; Mao, Y.; Masui, H.; Matathias, F.; McCumber, M.; McGaughey, P. L.; Means, N.; Meredith, B.; Miake, Y.; Mignerey, A. C.; Mikeš, P.; Miki, K.; Milov, A.; Mishra, M.; Mitchell, J. T.; Mohanty, A. K.; Morino, Y.; Morreale, A.; Morrison, D. P.; Moukhanova, T. V.; Murata, J.; Nagamiya, S.; Nagle, J. L.; Naglis, M.; Nagy, M. I.; Nakagawa, I.; Nakamiya, Y.; Nakamura, T.; Nakano, K.; Newby, J.; Nguyen, M.; Nouicer, R.; Nyanin, A. S.; O'Brien, E.; Oda, S. X.; Ogilvie, C. A.; Okada, K.; Oka, M.; Onuki, Y.; Oskarsson, A.; Ouchida, M.; Ozawa, K.; Pak, R.; Pantuev, V.; Papavassiliou, V.; Park, I. H.; Park, J.; Park, S. K.; Park, W. J.; Pate, S. F.; Pei, H.; Peng, J.-C.; Pereira, H.; Peresedov, V.; Peressounko, D. Yu.; Pinkenburg, C.; Pisani, R. P.; Proissl, M.; Purschke, M. L.; Purwar, A. K.; Qu, H.; Rak, J.; Rakotozafindrabe, A.; Ravinovich, I.; Read, K. F.; Reygers, K.; Riabov, V.; Riabov, Y.; Richardson, E.; Roach, D.; Roche, G.; Rolnick, S. D.; Rosati, M.; Rosen, C. A.; Rosendahl, S. S. E.; Rosnet, P.; Rukoyatkin, P.; Ružička, P.; Sahlmueller, B.; Saito, N.; Sakaguchi, T.; Sakashita, K.; Samsonov, V.; Sano, S.; Sato, T.; Sawada, S.; Sedgwick, K.; Seele, J.; Seidl, R.; Semenov, A. Yu.; Seto, R.; Sharma, D.; Shein, I.; Shibata, T.-A.; Shigaki, K.; Shimomura, M.; Shoji, K.; Shukla, P.; Sickles, A.; Silva, C. L.; Silvermyr, D.; Silvestre, C.; Sim, K. S.; Singh, B. K.; Singh, C. P.; Singh, V.; Slunečka, M.; Soltz, R. A.; Sondheim, W. E.; Sorensen, S. P.; Sourikova, I. V.; Sparks, N. A.; Stankus, P. W.; Stenlund, E.; Stoll, S. P.; Sugitate, T.; Sukhanov, A.; Sziklai, J.; Takagui, E. M.; Taketani, A.; Tanabe, R.; Tanaka, Y.; Tanida, K.; Tannenbaum, M. J.; Tarafdar, S.; Taranenko, A.; Tarján, P.; Themann, H.; Thomas, T. L.; Togawa, M.; Toia, A.; Tomášek, L.; Torii, H.; Towell, R. S.; Tserruya, I.; Tsuchimoto, Y.; Vale, C.; Valle, H.; van Hecke, H. W.; Vazquez-Zambrano, E.; Veicht, A.; Velkovska, J.; Vértesi, R.; Vinogradov, A. A.; Virius, M.; Vrba, V.; Vznuzdaev, E.; Wang, X. R.; Watanabe, D.; Watanabe, K.; Watanabe, Y.; Wei, F.; Wei, R.; Wessels, J.; White, S. N.; Winter, D.; Wood, J. P.; Woody, C. L.; Wright, R. M.; Wysocki, M.; Xie, W.; Yamaguchi, Y. L.; Yamaura, K.; Yang, R.; Yanovich, A.; Ying, J.; Yokkaichi, S.; Young, G. R.; Younus, I.; You, Z.; Yushmanov, I. E.; Zajc, W. A.; Zhang, C.; Zhou, S.; Zolin, L.

    2010-08-01

    Differential measurements of the elliptic (v2) and hexadecapole (v4) Fourier flow coefficients are reported for charged hadrons as a function of transverse momentum (pT) and collision centrality or number of participant nucleons (Npart) for Au+Au collisions at sNN=200GeV. The v2,4 measurements at pseudorapidity |η|≤0.35, obtained with four separate reaction-plane detectors positioned in the range 1.0<|η|<3.9, show good agreement, indicating the absence of significant Δη-dependent nonflow correlations. Sizable values for v4(pT) are observed with a ratio v4(pT,Npart)/v22(pT,Npart)≈0.8 for 50≲Npart≲200, which is compatible with the combined effects of a finite viscosity and initial eccentricity fluctuations. For Npart≳200 this ratio increases up to 1.7 in the most central collisions.

  2. Measurements of Higher Order Flow Harmonics in Au+Au Collisions at sNN=200GeV

    NASA Astrophysics Data System (ADS)

    Adare, A.; Afanasiev, S.; Aidala, C.; Ajitanand, N. N.; Akiba, Y.; Al-Bataineh, H.; Alexander, J.; Aoki, K.; Aramaki, Y.; Atomssa, E. T.; Averbeck, R.; Awes, T. C.; Azmoun, B.; Babintsev, V.; Bai, M.; Baksay, G.; Baksay, L.; Barish, K. N.; Bassalleck, B.; Basye, A. T.; Bathe, S.; Baublis, V.; Baumann, C.; Bazilevsky, A.; Belikov, S.; Belmont, R.; Bennett, R.; Berdnikov, A.; Berdnikov, Y.; Bickley, A. A.; Bok, J. S.; Boyle, K.; Brooks, M. L.; Buesching, H.; Bumazhnov, V.; Bunce, G.; Butsyk, S.; Camacho, C. M.; Campbell, S.; Chen, C.-H.; Chi, C. Y.; Chiu, M.; Choi, I. J.; Choudhury, R. K.; Christiansen, P.; Chujo, T.; Chung, P.; Chvala, O.; Cianciolo, V.; Citron, Z.; Cole, B. A.; Connors, M.; Constantin, P.; Csanád, M.; Csörgő, T.; Dahms, T.; Dairaku, S.; Danchev, I.; Das, K.; Datta, A.; David, G.; Denisov, A.; Deshpande, A.; Desmond, E. J.; Dietzsch, O.; Dion, A.; Donadelli, M.; Drapier, O.; Drees, A.; Drees, K. A.; Durham, J. M.; Durum, A.; Dutta, D.; Edwards, S.; Efremenko, Y. V.; Ellinghaus, F.; Engelmore, T.; Enokizono, A.; En'Yo, H.; Esumi, S.; Fadem, B.; Fields, D. E.; Finger, M.; Finger, M., Jr.; Fleuret, F.; Fokin, S. L.; Fraenkel, Z.; Frantz, J. E.; Franz, A.; Frawley, A. D.; Fujiwara, K.; Fukao, Y.; Fusayasu, T.; Garishvili, I.; Glenn, A.; Gong, H.; Gonin, M.; Goto, Y.; Granier de Cassagnac, R.; Grau, N.; Greene, S. V.; Grosse Perdekamp, M.; Gunji, T.; Gustafsson, H.-Å.; Haggerty, J. S.; Hahn, K. I.; Hamagaki, H.; Hamblen, J.; Han, R.; Hanks, J.; Hartouni, E. P.; Haslum, E.; Hayano, R.; He, X.; Heffner, M.; Hemmick, T. K.; Hester, T.; Hill, J. C.; Hohlmann, M.; Holzmann, W.; Homma, K.; Hong, B.; Horaguchi, T.; Hornback, D.; Huang, S.; Ichihara, T.; Ichimiya, R.; Ide, J.; Ikeda, Y.; Imai, K.; Inaba, M.; Isenhower, D.; Ishihara, M.; Isobe, T.; Issah, M.; Isupov, A.; Ivanischev, D.; Jacak, B. V.; Jia, J.; Jin, J.; Johnson, B. M.; Joo, K. S.; Jouan, D.; Jumper, D. S.; Kajihara, F.; Kametani, S.; Kamihara, N.; Kamin, J.; Kang, J. H.; Kapustinsky, J.; Karatsu, K.; Kawall, D.; Kawashima, M.; Kazantsev, A. V.; Kempel, T.; Khanzadeev, A.; Kijima, K. M.; Kim, B. I.; Kim, D. H.; Kim, D. J.; Kim, E.; Kim, E. J.; Kim, S. H.; Kim, Y. J.; Kinney, E.; Kiriluk, K.; Kiss, Á.; Kistenev, E.; Kochenda, L.; Komkov, B.; Konno, M.; Koster, J.; Kotchetkov, D.; Kozlov, A.; Král, A.; Kravitz, A.; Kunde, G. J.; Kurita, K.; Kurosawa, M.; Kwon, Y.; Kyle, G. S.; Lacey, R.; Lai, Y. S.; Lajoie, J. G.; Lebedev, A.; Lee, D. M.; Lee, J.; Lee, K.; Lee, K. B.; Lee, K. S.; Leitch, M. J.; Leite, M. A. L.; Leitner, E.; Lenzi, B.; Li, X.; Liebing, P.; Linden Levy, L. A.; Liška, T.; Litvinenko, A.; Liu, H.; Liu, M. X.; Love, B.; Luechtenborg, R.; Lynch, D.; Maguire, C. F.; Makdisi, Y. I.; Malakhov, A.; Malik, M. D.; Manko, V. I.; Mannel, E.; Mao, Y.; Masui, H.; Matathias, F.; McCumber, M.; McGaughey, P. L.; Means, N.; Meredith, B.; Miake, Y.; Mignerey, A. C.; Mikeš, P.; Miki, K.; Milov, A.; Mishra, M.; Mitchell, J. T.; Mohanty, A. K.; Morino, Y.; Morreale, A.; Morrison, D. P.; Moukhanova, T. V.; Murata, J.; Nagamiya, S.; Nagle, J. L.; Naglis, M.; Nagy, M. I.; Nakagawa, I.; Nakamiya, Y.; Nakamura, T.; Nakano, K.; Newby, J.; Nguyen, M.; Nouicer, R.; Nyanin, A. S.; O'Brien, E.; Oda, S. X.; Ogilvie, C. A.; Oka, M.; Okada, K.; Onuki, Y.; Oskarsson, A.; Ouchida, M.; Ozawa, K.; Pak, R.; Pantuev, V.; Papavassiliou, V.; Park, I. H.; Park, J.; Park, S. K.; Park, W. J.; Pate