Detailed record of SO2 emissions from Pu'u `O`o between episodes 33 and 34 of the 1983-86 ERZ eruption, Kilauea, Hawaii

USGS Publications Warehouse

Chartier, T.A.; Rose, William I.; Stokes, J.B.

1988-01-01

A tripod-mounted correlation spectrometer was used to measure SO2 emissions from Pu`u `O`o vent, mid-ERZ, Kilauea, Hawaii between Episodes 33 and 34 (June 13 to July 6, 1985). In 24 repose days, 906 measurements were collected, averaging 38 determinations/day. Measurements reflect 13% of the total 576 hours of the repose and 42% of the bright daylight hours. The average SO2 emission for the 24-day repose interval is 167??83 t/d, a total of 4000 tonnes emitted for the entire repose. The large standard deviation reflects the "puffing" character of the plume. The overall rate of SO2 degassing gently decreased with a zero-intercept of 44-58 days and was interrupted by two positive peaks. The data are consistent with the gas emanating from a cylindrical conduit of 50 meter diameter and a length of 1700 meters which degasses about 50% of its SO2 during 24 days. This is in support of the Pu'u `O`o model of Greenland et al. (1987). 36 hours before the onset of Episode 34 (July 5-6, 1985), elevated SO2 emissions were detected while the magma column was extremely active ultimately spilling over during dome fountaining. A "mid-repose" anomaly of SO2 emission (June 21-22, 1985) occurs two days before a sudden increase in the rate of summit inflation (on June 24, 1985), suggesting magma was simultaneously being injected in both the ERZ and summit reservoir until July 24 when it was channelled only to the summit reservoir. This implies degassing magma is sensitive to perturbations within the rift zone conduit system and may at times reflect these disturbances. Periods of 7-45 min are detected in the daily SO2 emissions, which possibly reflect timing of convective overturn in the cylindrical magma body. If the 33-34 repose interval is considered representative of other repose periods, the ERZ reposes of Jan 1983-Jan 1986 ERZ activity, contributed 1.6 ?? 105 tonnes of SO2 to the atmosphere. Including summit fuming from non-eruptive fumaroles (2.7 ?? 105 tonnes SO2); 28% of the total SO2 budget from Kilauea between Jan 1983 to Jan 1986 was contributed by quiescent degassing, and the remainder was released during explosive fountaining episodes. ?? 1988 Springer-Verlag.

Multimodel Surface Temperature Responses to Removal of U.S. Sulfur Dioxide Emissions

NASA Astrophysics Data System (ADS)

Conley, A. J.; Westervelt, D. M.; Lamarque, J.-F.; Fiore, A. M.; Shindell, D.; Correa, G.; Faluvegi, G.; Horowitz, L. W.

2018-03-01

Three Earth System models are used to derive surface temperature responses to removal of U.S. anthropogenic SO2 emissions. Using multicentury perturbation runs with and without U.S. anthropogenic SO2 emissions, the local and remote surface temperature changes are estimated. In spite of a temperature drift in the control and large internal variability, 200 year simulations yield statistically significant regional surface temperature responses to the removal of U.S. SO2 emissions. Both local and remote surface temperature changes occur in all models, and the patterns of changes are similar between models for northern hemisphere land regions. We find a global average temperature sensitivity to U.S. SO2 emissions of 0.0055 K per Tg(SO2) per year with a range of (0.0036, 0.0078). We examine global and regional responses in SO4 burdens, aerosol optical depths (AODs), and effective radiative forcing (ERF). While changes in AOD and ERF are concentrated near the source region (United States), the temperature response is spread over the northern hemisphere with amplification of the temperature increase toward the Arctic. In all models, we find a significant response of dust concentrations, which affects the AOD but has no obvious effect on surface temperature. Temperature sensitivity to the ERF of U.S. SO2 emissions is found to differ from the models' sensitivity to radiative forcing of doubled CO2.

Current status and future trends of SO2 and NOx pollution during the 12th FYP period in Guiyang city of China

NASA Astrophysics Data System (ADS)

Tian, Hezhong; Qiu, Peipei; Cheng, Ke; Gao, Jiajia; Lu, Long; Liu, Kaiyun; Liu, Xingang

2013-04-01

In order to investigate the future trends of SO2 and NOx pollution in Guiyang city of China, the MM5/CALMET/CALPUFF modeling system is applied to assess the effects of air pollution improvement that would result from reduction targets for SO2 and NOx emissions during the 12th Five-Year Plan (2011-2015). Three scenarios are established for the objective year 2015 based on the reference emissions in base year 2010. Scenario analysis and modeling results show that emissions are projected to increase by 26.5% for SO2 and 138.0% for NOx in 2015 Business-As-Usual (BAU) relative to base year 2010, respectively, which will lead to a substantial worsening tendency of SO2 and NOx pollution. In comparison, both the 2015 Policy Reduction (PR) and 2015 Intensive Policy Reduction (IPR) scenarios would contribute to improve the urban air quality. Under 2015 PR scenario, the maximum annual average concentration of SO2 and NOx will reduce by 54.9% and 31.7%, respectively, relative to the year 2010, with only 2.1% of all individual gridded receptors exceed the national air quality standard limits; while the maximum annual average concentrations of SO2 and NOx can reduce further under 2015 IPR scenario and comply well with standards limits. In view of the technical feasibility and cost-effectiveness, the emission reduction targets set in the 2015 PR scenario are regarded as more reasonable in order to further improve the air quality in Guiyang during the 12th FYP period and a series of comprehensive countermeasures should be effectively implemented.

Gas and ash emissions associated with the 2010–present activity of Sinabung Volcano, Indonesia

USGS Publications Warehouse

Primulyana, Sofyan; Kern, Christoph; Lerner, Allan; Saing, Ugan; Kunrat, Syegi; Alfianti, Hilma; Marlia, Mitha

2017-01-01

Sinabung Volcano (Sumatra, Indonesia) awoke from over 1200 years of dormancy with multiple phreatic explosions in 2010. After a period of quiescence, Sinabung activity resumed in 2013, producing frequent explosions, lava dome extrusion, and pyroclastic flows from dome collapses, becoming one of the world's most active volcanoes and displacing over 20,000 citizens. This study presents a compilation of the geochemical datasets collected by the Indonesian Center for Volcanology and Geological Hazard Mitigation (CVGHM) from 2010 - current (2016), which provides insights into the evolution of the eruption. Based on observations of SO2 emissions, ash componentry, leachate chemistry, and bulk ash geochemistry, the eruption can be split into five distinct phases. The initial stage of phreatic summit explosions occurred from August - October 2010, during which background SO2 emissions averaged ~550 ± 180 t/d (1 s.d.). An eruptive pause (phase two) starting in October 2010 abruptly ended in September 2013 with a resumption of conduit-clearing eruptions. This third phase had a relatively modest background SO2 emission rate (avg. ~410 ± 275 t/d) and produced ash consisting entirely of accidental ejecta with high S/Cl leachate ratios (up to 30), suggestive of deep-sourced magma and the incorporation of hydrothermal sulfur-bearing phases. The most intense phase of the eruption (phase four) occurred from December 2013 to February 2014, when juvenile magma first reached the surface. This period included dozens of large eruptions per day, high SO2 emission rates (average: 1,120 ± 1,030 t/d, peak: ~3,800 t/d), the onset of lava dome extrusion, and a dramatic drop in S/Cl ash leachates to ratios < 5, all reflecting increased degassing from shallow magma and the clearing out of sulfurous phases from the old hydrothermal system. From late February 2014 through the time of writing (September 2016), Sinabung settled into a relatively steady state of lower activity (phase five). Ash emissions now consist of dominantly juvenile material, and background SO2 emission rates have been progressively decreasing to an average of ~250 - 300 t/d. Starting August 2016, SO2 emissions started being measured in a continuous manner using a network of permanent scanning DOAS instruments. We find that long-term SO2 emission rates have been gradually declining at Sinabung since early 2014, consistent with an apparent decrease in magma supply. Our degassing model suggests that large explosions and pyroclastic flows could continue in the near-term owing to conduit plugging and dome collapses, remaining a major threat until the magma supply rate decreases further and the eruption ends.

Marginal Emissions Factors for Electricity Generation in the Midcontinent ISO.

PubMed

Thind, Maninder P S; Wilson, Elizabeth J; Azevedo, Inês L; Marshall, Julian D

2017-12-19

Environmental consequences of electricity generation are often determined using average emission factors. However, as different interventions are incrementally pursued in electricity systems, the resulting marginal change in emissions may differ from what one would predict based on system-average conditions. Here, we estimate average emission factors and marginal emission factors for CO 2 , SO 2 , and NO x from fossil and nonfossil generators in the Midcontinent Independent System Operator (MISO) region during years 2007-2016. We analyze multiple spatial scales (all MISO; each of the 11 MISO states; each utility; each generator) and use MISO data to characterize differences between the two emission factors (average; marginal). We also explore temporal trends in emissions factors by hour, day, month, and year, as well as the differences that arise from including only fossil generators versus total generation. We find, for example, that marginal emission factors are generally higher during late-night and early morning compared to afternoons. Overall, in MISO, average emission factors are generally higher than marginal estimates (typical difference: ∼20%). This means that the true environmental benefit of an energy efficiency program may be ∼20% smaller than anticipated if one were to use average emissions factors. Our analysis can usefully be extended to other regions to support effective near-term technical, policy and investment decisions based on marginal rather than only average emission factors.

Implications for eruptive processes as indicated by sulfur dioxide emissions from Kilauea Volcano, Hawai'i, 1979-1997

USGS Publications Warehouse

Sutton, A.J.; Elias, T.; Gerlach, T.M.; Stokes, J.B.

2001-01-01

Kı̄lauea Volcano, Hawai‘i, currently hosts the longest running SO2 emission-rate data set on the planet, starting with initial surveys done in 1975 by Stoiber and his colleagues. The 17.5-year record of summit emissions, starting in 1979, shows the effects of summit and east rift eruptive processes, which define seven distinctly different periods of SO2 release. Summit emissions jumped nearly 40% with the onset (3 January 1983) of the Pu`u `Ō`ō-Kūpaianaha eruption on the east rift zone (ERZ). Summit SO2 emissions from Kı̄lauea showed a strong positive correlation with short-period, shallow, caldera events, rather than with long-period seismicity as in more silicious systems. This correlation suggests a maturation process in the summit magma-transport system from 1986 through 1993. During a steady-state throughput-equilibrium interval of the summit magma reservoir, integration of summit-caldera and ERZ SO2 emissions reveals an undegassed volume rate of effusion of 2.1×105 m3/d. This value corroborates the volume-rate determined by geophysical methods, demonstrating that, for Kı̄lauea, SO2 emission rates can be used to monitor effusion rate, supporting and supplementing other, more established geophysical methods. For the 17.5 years of continuous emission rate records at Kı̄lauea, the volcano has released 9.7×106 t (metric tonnes) of SO2, 1.7×106 t from the summit and 8.0×106 t from the east rift zone. On an annual basis, the average SO2 release from Kı̄lauea is 4.6×105 t/y, compared to the global annual volcanic emission rate of 1.2×107 t/y.

Real-world energy use and emission rates for idling long-haul trucks and selected idle reduction technologies.

PubMed

Frey, H Christopher; Kuo, Po-Yao

2009-07-01

Long-haul freight trucks typically idle for 2000 or more hours per year, motivating interest in reducing idle fuel use and emissions using auxiliary power units (APUs) and shore-power (SP). Fuel-use rates are estimated based on electronic control unit (ECU) data for truck engines and measurements for APU engines. Engine emission factors were measured using a portable emission measurement system. Indirect emissions from SP were based on average utility grid emission factors. Base engine fuel use and APU and SP electrical load were analyzed for 20 trucks monitored for more than 1 yr during 2.76 million mi of activity within 42 U.S. states. The average base engine fuel use varied from 0.46 to 0.65 gal/hr. The average APU fuel use varied from 0.24 to 0.41 gal/hr. Fuel-use rates are typically lowest in mild weather, highest in hot or cold weather, and depend on engine speed (revolutions per minute [RPM]). Compared with the base engine, APU fuel use and emissions of carbon dioxide (CO2) and sulfur dioxide (SO2) are lower by 36-47%. Oxides of nitrogen (NO(x)) emissions are lower by 80-90%. Reductions in particulate matter (PM), carbon monoxide (CO), and hydrocarbon emissions vary from approximately 10 to over 50%. SP leads to more substantial reductions, except for SO2. The actual achievable reductions will be lower because only a fraction of base engine usage will be replaced by APUs, SP, or both. Recommendations are made for reducing base engine fuel use and emissions, accounting for variability in fuel use and emissions reductions, and further work to quantify real-world avoided fuel use and emissions.

Sensitivity of air pollution simulations with LOTOS-EUROS to the temporal distribution of anthropogenic emissions

NASA Astrophysics Data System (ADS)

Mues, A.; Kuenen, J.; Hendriks, C.; Manders, A.; Segers, A.; Scholz, Y.; Hueglin, C.; Builtjes, P.; Schaap, M.

2014-01-01

In this study the sensitivity of the model performance of the chemistry transport model (CTM) LOTOS-EUROS to the description of the temporal variability of emissions was investigated. Currently the temporal release of anthropogenic emissions is described by European average diurnal, weekly and seasonal time profiles per sector. These default time profiles largely neglect the variation of emission strength with activity patterns, region, species, emission process and meteorology. The three sources dealt with in this study are combustion in energy and transformation industries (SNAP1), nonindustrial combustion (SNAP2) and road transport (SNAP7). First of all, the impact of neglecting the temporal emission profiles for these SNAP categories on simulated concentrations was explored. In a second step, we constructed more detailed emission time profiles for the three categories and quantified their impact on the model performance both separately as well as combined. The performance in comparison to observations for Germany was quantified for the pollutants NO2, SO2 and PM10 and compared to a simulation using the default LOTOS-EUROS emission time profiles. The LOTOS-EUROS simulations were performed for the year 2006 with a temporal resolution of 1 h and a horizontal resolution of approximately 25 × 25km2. In general the largest impact on the model performance was found when neglecting the default time profiles for the three categories. The daily average correlation coefficient for instance decreased by 0.04 (NO2), 0.11 (SO2) and 0.01 (PM10) at German urban background stations compared to the default simulation. A systematic increase in the correlation coefficient is found when using the new time profiles. The size of the increase depends on the source category, component and station. Using national profiles for road transport showed important improvements in the explained variability over the weekdays as well as the diurnal cycle for NO2. The largest impact of the SNAP1 and 2 profiles were found for SO2. When using all new time profiles simultaneously in one simulation, the daily average correlation coefficient increased by 0.05 (NO2), 0.07 (SO2) and 0.03 (PM10) at urban background stations in Germany. This exercise showed that to improve the performance of a CTM, a better representation of the distribution of anthropogenic emission in time is recommendable. This can be done by developing a dynamical emission model that takes into account regional specific factors and meteorology.

Removal of sulfur dioxide and formation of sulfate aerosol in Tokyo

NASA Astrophysics Data System (ADS)

Miyakawa, T.; Takegawa, N.; Kondo, Y.

2007-07-01

Ground-based in situ measurements of sulfur dioxide (SO2) and submicron sulfate aerosol (SO42-) together with carbon monoxide (CO) were conducted at an urban site in Tokyo, Japan from spring 2003 to winter 2004. The observed concentrations of SO2 were affected dominantly by anthropogenic emissions (for example, manufacturing industries) in source areas, while small fraction of the data (<30%) was affected by large point sources of SO2 (power plant and volcano). Although emission sources of CO in Tokyo are different from those of SO2, the major emission sources of CO and SO2 are colocated, indicating that CO can be used as a tracer of anthropogenic SO2 emissions in Tokyo. The ratio of SO42- to total sulfur compounds (SOx = SO2 + SO42-) and the remaining fraction of SOx, which is derived as the ratio of the linear regression slope of the SOx-CO correlation, is used as measures for the formation of SO42- and removal of SOx, respectively. Using these parameters, the average formation efficiency of SO42- (i.e., amount of SO42- produced per SO2 emitted from emission sources) are estimated to be 0.18 and 0.03 in the summer and winter periods, respectively. A simple box model was developed to estimate the lifetime of SOx. The lifetime of SOx for the summer period (26 h) is estimated to be about two times longer than that for the winter period (14 h). The seasonal variations of the remaining fraction of SOx, estimated formation efficiency of SO42-, and lifetime of SOx are likely due to those of the boundary layer height and photochemical activity (i.e., hydroxyl radical). These results provide useful insights into the formation and removal processes of sulfur compounds exported from an urban area.

Summit CO2 emission rates by the CO2/SO2 ratio method at Kīlauea Volcano, Hawaiʻi, during a period of sustained inflation

USGS Publications Warehouse

Hager, S.A.; Gerlach, T.M.; Wallace, P.J.

2008-01-01

The emission rate of carbon dioxide escaping from the summit of Kīlauea Volcano, Hawaiʻi, proved highly variable, averaging 4900 ± 2000 metric tons per day (t/d) in June–July 2003 during a period of summit inflation. These results were obtained by combining over 90 measurements of COSPEC-derived SO2emission rates with synchronous CO2/SO2 ratios of the volcanic gas plume along the summit COSPEC traverse. The results are lower than the CO2 emission rate of 8500 ± 300 t/d measured by the same method in 1995–1999 during a period of long-term summit deflation [Gerlach, T.M., McGee, K.A., Elias, T., Sutton, A.J. and Doukas, M.P., 2002. Carbon dioxide emission rate of Kīlauea Volcano: Implications for primary magma and the summit reservoir. Journal of Geophysical Research-Solid Earth, 107(B9): art. no.-2189.]. Analysis of the data indicates that the emission rates of the present study likely reflect changes in the magma supply rate and residence time in the summit reservoir. It is also likely that emission rates during the inflation period were heavily influenced by SO2 pulses emitted adjacent to the COSPEC traverse, which biased CO2/SO2 ratios towards low values that may be unrepresentative of the global summit gas plume. We conclude that the SO2 pulses are consequences of summit re-inflation under way since 2003 and that CO2 emission rates remain comparable to, but more variable than, those measured prior to re-inflation.

Meteorological detrending of primary and secondary pollutant concentrations: Method application and evaluation using long-term (2000-2012) data in Atlanta

NASA Astrophysics Data System (ADS)

Henneman, Lucas R. F.; Holmes, Heather A.; Mulholland, James A.; Russell, Armistead G.

2015-10-01

The effectiveness of air pollution regulations and controls are evaluated based on measured air pollutant concentrations. Air pollution levels, however, are highly sensitive to both emissions and meteorological fluctuations. Therefore, an assessment of the change in air pollutant levels due to emissions controls must account for these meteorological fluctuations. Two empirical methods to quantify the impact of meteorology on pollutant levels are discussed and applied to the 13-year time period between 2000 and 2012 in Atlanta, GA. The methods employ Kolmogorov-Zurbenko filters and linear regressions to detrended pollutant signals into long-term, seasonal, weekly, short-term, and white-noise components. The methods differ in how changes in weekly and holiday emissions are accounted for. Both can provide meteorological adjustments on a daily basis for future use in acute health analyses. The meteorological impact on daily signals of ozone, NOx, CO, SO2, PM2.5, and PM species are quantified. Analyses show that the substantial decreases in seasonal averages of NOx and SO2 correspond with controls implemented in the metropolitan Atlanta area. Detrending allows for the impacts of some controls to be observed with averaging times of as little as 3 months. Annual average concentrations of NOx, SO2, and CO have all fallen by at least 50% since 2000. Reductions in NOx levels, however, do not lead to uniform reductions in ozone. While average detrended summer average maximum daily average 8 h ozone (MDA8h O3) levels fell by 4% (2.2 ± 2 ppb) between 2000 and 2012, winter averages have increased by 12% (3.8 ± 1.4 ppb), providing further evidence that high ozone levels are NOx-limited and lower ozone concentrations are NOx-inhibited. High ozone days (with MDA8h O3 greater than 60 ppb) decreased both in number and in magnitude over the study period.

Field test of available methods to measure remotely SO2 and NOx emissions from ships

NASA Astrophysics Data System (ADS)

Balzani Lööv, J. M.; Alfoldy, B.; Beecken, J.; Berg, N.; Berkhout, A. J. C.; Duyzer, J.; Gast, L. F. L.; Hjorth, J.; Jalkanen, J.-P.; Lagler, F.; Mellqvist, J.; Prata, F.; van der Hoff, G. R.; Westrate, H.; Swart, D. P. J.; Borowiak, A.

2013-11-01

Methods for the determination of ship fuel sulphur content and NOx emission factors from remote measurements have been compared in the harbour of Rotterdam and compared to direct stack emission measurements on the ferry Stena Hollandica. The methods were selected based on a review of the available literature on ship emission measurements. They were either optical (LIDAR, DOAS, UV camera), combined with model based estimates of fuel consumption, or based on the so called "sniffer" principle, where SO2 or NOx emission factors are determined from simultaneous measurement of the increase of CO2 and SO2 or NOx concentrations in the plume of the ship compared to the background. The measurements were performed from stations at land, from a boat, and from a helicopter. Mobile measurement platforms were found to have important advantages compared to the landbased ones because they allow to optimize the sampling conditions and to sample from ships on the open sea. Although optical methods can provide reliable results, it was found that at the state of the art, the "sniffer" approach is the most convenient technique for determining both SO2 and NOx emission factors remotely. The average random error on the determination of SO2 emission factors comparing two identical instrumental set-ups was 6%. However, it was found that apparently minor differences in the instrumental characteristics, such as response time, could cause significant differences between the emission factors determined. Direct stack measurements showed that about 14% of the fuel sulphur content was not emitted as SO2. This was supported by the remote measurements and is in agreement with the results of other field studies.

Current and future emissions of primary pollutants from coal-fired power plants in Shaanxi, China.

PubMed

Xu, Yong; Hu, Jianlin; Ying, Qi; Hao, Hongke; Wang, Dexiang; Zhang, Hongliang

2017-10-01

A high-resolution inventory of primary atmospheric pollutants from coal-fired power plants in Shaanxi in 2012 was built based on a detailed database compiled at unit level involving unit capacity, boiler size and type, commission time, corresponding control technologies, and average coal quality of 72 power plants. The pollutants included SO 2 , NO x , fine particulate matter (PM 2.5 ), inhalable particulate matter (PM 10 ), organic carbon (OC), elemental carbon (EC), carbon monoxide (CO) and non-methane volatile organic compounds (NMVOC). Emission factors for SO 2 , NO x , PM 2.5 and PM 10 were adopted from standardized official promulgation, supplemented by those from local studies. The estimated annual emissions of SO 2 , NO x , PM 2.5 , PM 10 , EC, OC, CO and NMVOC were 152.4, 314.8, 16.6, 26.4, 0.07, 0.27, 64.9 and 2.5kt, respectively. Small units (<100MW), which accounted for ~60% of total unit numbers, had less coal consumption but higher emission rates compared to medium (≥100MW and <300MW) and large units (≥300MW). Main factors affecting SO 2 , NO x , PM 2.5 and PM 10 emissions were decontamination efficiency, sulfur content and ash content of coal. Weinan and Xianyang were the two cities with the highest emissions, and Guanzhong Plain had the largest emission density. Despite the projected growth of coal consumption, emissions would decrease in 2030 due to improvement in emission control technologies and combustion efficiencies. SO 2 and NO x emissions would experience significant reduction by ~81% and ~84%, respectively. PM 2.5 , PM 10 , EC and OC would be decreased by ~43% and CO and NMVOC would be reduced by ~16%. Copyright © 2017 Elsevier B.V. All rights reserved.

A decade of global volcanic SO2 emissions measured from space

NASA Astrophysics Data System (ADS)

Carn, S. A.; Fioletov, V. E.; McLinden, C. A.; Li, C.; Krotkov, N. A.

2017-03-01

The global flux of sulfur dioxide (SO2) emitted by passive volcanic degassing is a key parameter that constrains the fluxes of other volcanic gases (including carbon dioxide, CO2) and toxic trace metals (e.g., mercury). It is also a required input for atmospheric chemistry and climate models, since it impacts the tropospheric burden of sulfate aerosol, a major climate-forcing species. Despite its significance, an inventory of passive volcanic degassing is very difficult to produce, due largely to the patchy spatial and temporal coverage of ground-based SO2 measurements. We report here the first volcanic SO2 emissions inventory derived from global, coincident satellite measurements, made by the Ozone Monitoring Instrument (OMI) on NASA’s Aura satellite in 2005-2015. The OMI measurements permit estimation of SO2 emissions from over 90 volcanoes, including new constraints on fluxes from Indonesia, Papua New Guinea, the Aleutian Islands, the Kuril Islands and Kamchatka. On average over the past decade, the volcanic SO2 sources consistently detected from space have discharged a total of ~63 kt/day SO2 during passive degassing, or ~23 ± 2 Tg/yr. We find that ~30% of the sources show significant decadal trends in SO2 emissions, with positive trends observed at multiple volcanoes in some regions including Vanuatu, southern Japan, Peru and Chile.

A decade of global volcanic SO2 emissions measured from space

PubMed Central

Carn, S. A.; Fioletov, V. E.; McLinden, C. A.; Li, C.; Krotkov, N. A.

2017-01-01

The global flux of sulfur dioxide (SO2) emitted by passive volcanic degassing is a key parameter that constrains the fluxes of other volcanic gases (including carbon dioxide, CO2) and toxic trace metals (e.g., mercury). It is also a required input for atmospheric chemistry and climate models, since it impacts the tropospheric burden of sulfate aerosol, a major climate-forcing species. Despite its significance, an inventory of passive volcanic degassing is very difficult to produce, due largely to the patchy spatial and temporal coverage of ground-based SO2 measurements. We report here the first volcanic SO2 emissions inventory derived from global, coincident satellite measurements, made by the Ozone Monitoring Instrument (OMI) on NASA’s Aura satellite in 2005–2015. The OMI measurements permit estimation of SO2 emissions from over 90 volcanoes, including new constraints on fluxes from Indonesia, Papua New Guinea, the Aleutian Islands, the Kuril Islands and Kamchatka. On average over the past decade, the volcanic SO2 sources consistently detected from space have discharged a total of ~63 kt/day SO2 during passive degassing, or ~23 ± 2 Tg/yr. We find that ~30% of the sources show significant decadal trends in SO2 emissions, with positive trends observed at multiple volcanoes in some regions including Vanuatu, southern Japan, Peru and Chile. PMID:28275238

A Decade of Global Volcanic SO2 Emissions Measured from Space

NASA Technical Reports Server (NTRS)

Carn, S. A.; Fioletov, V. E.; McLinden, C. A.; Li, C.; Krotkov, N. A.

2017-01-01

The global flux of sulfur dioxide (SO2) emitted by passive volcanic degassing is a key parameter that constrains the fluxes of other volcanic gases (including carbon dioxide, CO2) and toxic trace metals (e.g., mercury). It is also a required input for atmospheric chemistry and climate models, since it impacts the tropospheric burden of sulfate aerosol, a major climate-forcing species. Despite its significance, an inventory of passive volcanic degassing is very difficult to produce, due largely to the patchy spatial and temporal coverage of ground-based SO2 measurements. We report here the first volcanic SO2 emissions inventory derived from global, coincident satellite measurements, made by the Ozone Monitoring Instrument (OMI) on NASA's Aura satellite in 2005-2015. The OMI measurements permit estimation of SO2 emissions from over 90 volcanoes, including new constraints on fluxes from Indonesia, Papua New Guinea, the Aleutian Islands, the Kuril Islands and Kamchatka. On average over the past decade, the volcanic SO2 sources consistently detected from space have discharged a total of approximately 63 kt/day SO2 during passive degassing, or approximately 23 +/- 2 Tg/yr. We find that approximately 30% of the sources show significant decadal trends in SO2 emissions, with positive trends observed at multiple volcanoes in some regions including Vanuatu, southern Japan, Peru and Chile.

A decade of global volcanic SO2 emissions measured from space.

PubMed

Carn, S A; Fioletov, V E; McLinden, C A; Li, C; Krotkov, N A

2017-03-09

The global flux of sulfur dioxide (SO 2 ) emitted by passive volcanic degassing is a key parameter that constrains the fluxes of other volcanic gases (including carbon dioxide, CO 2 ) and toxic trace metals (e.g., mercury). It is also a required input for atmospheric chemistry and climate models, since it impacts the tropospheric burden of sulfate aerosol, a major climate-forcing species. Despite its significance, an inventory of passive volcanic degassing is very difficult to produce, due largely to the patchy spatial and temporal coverage of ground-based SO 2 measurements. We report here the first volcanic SO 2 emissions inventory derived from global, coincident satellite measurements, made by the Ozone Monitoring Instrument (OMI) on NASA's Aura satellite in 2005-2015. The OMI measurements permit estimation of SO 2 emissions from over 90 volcanoes, including new constraints on fluxes from Indonesia, Papua New Guinea, the Aleutian Islands, the Kuril Islands and Kamchatka. On average over the past decade, the volcanic SO 2 sources consistently detected from space have discharged a total of ~63 kt/day SO 2 during passive degassing, or ~23 ± 2 Tg/yr. We find that ~30% of the sources show significant decadal trends in SO 2 emissions, with positive trends observed at multiple volcanoes in some regions including Vanuatu, southern Japan, Peru and Chile.

Evaluation of Redoubt Volcano's sulfur dioxide emissions by the Ozone Monitoring Instrument

USGS Publications Warehouse

Lopez, Taryn; Carn, Simon A.; Werner, Cynthia A.; Fee, David; Kelly, Peter; Doukas, Michael P.; Pfeffer, Melissa; Webley, Peter; Cahill, Catherine F.; Schneider, David

2013-01-01

The 2009 eruption of Redoubt Volcano, Alaska, provided a rare opportunity to compare satellite measurements of sulfur dioxide (SO2) by the Ozone Monitoring Instrument (OMI) with airborne SO2 measurements by the Alaska Volcano Observatory (AVO). Herein we: (1) compare OMI and airborne SO2 column density values for Redoubt's tropospheric plume, (2) calculate daily SO2 masses from Mount Redoubt for the first three months of the eruption, (3) develop simple methods to convert daily measured SO2 masses into emission rates to allow satellite data to be directly integrated with the airborne SO2 emissions dataset, (4) calculate cumulative SO2 emissions from the eruption, and (5) evaluate OMI as a monitoring tool for high-latitude degassing volcanoes. A linear correlation (R2 ~ 0.75) is observed between OMI and airborne SO2 column densities. OMI daily SO2 masses for the sample period ranged from ~ 60.1 kt on 24 March to below detection limit, with an average daily SO2 mass of ~ 6.7 kt. The highest SO2 emissions were observed during the initial part of the explosive phase and the emissions exhibited an overall decreasing trend with time. OMI SO2 emission rates were derived using three methods and compared to airborne measurements. This comparison yields a linear correlation (R2 ~ 0.82) with OMI-derived emission rates consistently lower than airborne measurements. The comparison results suggest that OMI's detection limit for high latitude, springtime conditions varies from ~ 2000 to 4000 t/d. Cumulative SO2 masses calculated from daily OMI data for the sample period are estimated to range from 542 to 615 kt, with approximately half of this SO2 produced during the explosive phase of the eruption. These cumulative masses are similar in magnitude to those estimated for the 1989–90 Redoubt eruption. Strong correlations between daily OMI SO2 mass and both tephra mass and acoustic energy during the explosive phase of the eruption suggest that OMI data may be used to infer relative eruption size and explosivity. Further, when used in conjunction with complementary datasets, OMI daily SO2 masses may be used to help distinguish explosive from effusive activity and identify changes in lava extrusion rates. The results of this study suggest that OMI is a useful volcano monitoring tool to complement airborne measurements, capture explosive SO2 emissions, and provide high temporal resolution SO2 emissions data that can be used with interdisciplinary datasets to illuminate volcanic processes.

The growing contribution of sulfur emissions from ships in Asian waters, 1988-1995

NASA Astrophysics Data System (ADS)

Streets, David G.; Guttikunda, Sarath K.; Carmichael, Gregory R.

International shipping is a major source of sulfur emissions in Asia. Because the fuel oil used by ships is high in sulfur, the resulting emissions of SO 2 are large and contribute as much as 20% to the atmospheric loading in the vicinity of ports and heavily traveled waterways. Because of the rapid growth of Asian economies in the 1980s and early 1990s, it is estimated that shipping trade grew by an average of 5.4% per year between 1988 and 1995; in particular, crude oil shipments to Asian countries other than Japan grew by an average of 11.4% per year. The emissions of SO 2 from shipping are estimated to have grown by 5.9% per year between 1988 and 1995, rising from 545 Gg in 1988 to 817 Gg in 1995. This study uses the ATMOS atmospheric transport and deposition model to study the effects of these emissions, both in absolute terms and relative to land-based emissions , on wet and dry deposition of sulfur. Southeast Asia is most heavily affected by emissions from ships, particularly Sumatra, peninsular Malaysia, and Singapore, which routinely receive in excess of 10% of their deposition from ships. A strong seasonal component is also observed, with large areas of Southeast Asia and coastal Japan receiving sulfur deposition that exceeds 10 mg S m -2 season -1. Deposition is at least 25% higher in summer and fall than in winter and spring. Peak values of 25-50 mg S m -2 season -1 are calculated for winter in the Strait of Malacca. This work suggests a need to introduce policies to reduce the sulfur content of marine fuels or otherwise reduce emissions of SO 2 from ships in Asian waters.

Measurements of HONO, NO, NOy and SO2 in aircraft exhaust plumes at cruise

NASA Astrophysics Data System (ADS)

Jurkat, T.; Voigt, C.; Arnold, F.; Schlager, H.; Kleffmann, J.; Aufmhoff, H.; Schäuble, D.; Schaefer, M.; Schumann, U.

2011-05-01

Measurements of gaseous nitrogen and sulfur oxide emissions in young aircraft exhaust plumes give insight into chemical oxidation processes inside aircraft engines. Particularly, the OH-induced formation of nitrous acid (HONO) from nitrogen oxide (NO) and sulfuric acid (H2SO4) from sulfur dioxide (SO2) inside the turbine which is highly uncertain, need detailed analysis to address the climate impact of aviation. We report on airborne in situ measurements at cruise altitudes of HONO, NO, NOy, and SO2 in 9 wakes of 8 different types of modern jet airliners, including for the first time also an A380. Measurements of HONO and SO2 were made with an ITCIMS (Ion Trap Chemical Ionization Mass Spectrometer) using a new ion-reaction scheme involving SF5- reagent ions. The measured molar ratios HONO/NO and HONO/NOy with averages of 0.038 ± 0.010 and 0.027 ± 0.005 were found to decrease systematically with increasing NOx emission-index (EI NOx). We calculate an average EI HONO of 0.31 ± 0.12 g NO2 kg-1. Using reliable measurements of HONO and NOy, which are less adhesive than H2SO4 to the inlet walls, we derive the OH-induced conversion fraction of fuel sulfur to sulfuric acid $\\varepsilon$ with an average of 2.2 ± 0.5 %. $\\varepsilon$ also tends to decrease with increasing EI NOx, consistent with earlier model simulations. The lowest HONO/NO, HONO/NOy and $\\varepsilon$ was observed for the largest passenger aircraft A380.

Is Kīlauea's East Rift Zone eruption running out of gas?

NASA Astrophysics Data System (ADS)

Sutton, A. J.; Elias, T.; Orr, T. R.; Patrick, M. R.; Poland, M. P.; Thornber, C. R.

2015-12-01

Gases exsolving from magma are a key force that drives eruptive activity, and emissions from Kīlauea's East Rift Zone (ERZ) dominated the volcano's gas release from the beginning of the long-running and voluminous Pu'u 'Ō'ō eruption in 1983, through February 2008. In the months prior to the March 2008 onset of eruptive activity within Halema'uma'u Crater, however, SO2 degassing at the summit climbed substantially, and summit gas release has remained elevated since. These unprecedented emissions associated with the new summit eruption effectively began robbing gas from magma destined for Kīlauea's ERZ. As a result, ERZ SO2discharge, which had averaged 1,700 +-380 t/d for the previous 15 years, declined sharply and steadily beginning in September, 2008, and reached a new steady low of 380 +- 100 t/d by early 2011. This level persisted through mid-2015. In the years since the late 2008 downturn in ERZ SO2 emissions, there has been an overall slowdown in ERZ eruptive activity. Elevated emissions and effusive activity occurred briefly during the 2011 Kamoamoa fissure eruption and two other outbreaks at Pu'u 'Ō'ō , but otherwise ERZ eruptive activity had waned by 2010, when effusion rates were measured at about half of the long-term rate. Also, the sulfur preserved in ERZ olivine melt-inclusions, which provides a record of pre-eruptive SO2degassing, has steadily declined along with equilibration temperatures of host olivine phenocrysts, since 2008. We suggest that the drop in gas content of magma reaching the ERZ, owing to summit pre-eruptive degassing, has contributed significantly to the downturn in ERZ activity. While SO2 emissions from the ERZ have dropped to sustained levels lower than anything seen in the past 20 years, summit emissions have remained some of the highest recorded since regular measurements began at Kīlauea in 1979. Overall, average total SO2 discharge from Kīlauea in 2014, summit and ERZ, is still about 50% higher than for the 15 years prior to 2008. The effects of summit pre-eruptive degassing observed at Kilauea may have application at other summit-rift shield volcanoes.

Field test of available methods to measure remotely SOx and NOx emissions from ships

NASA Astrophysics Data System (ADS)

Balzani Lööv, J. M.; Alfoldy, B.; Gast, L. F. L.; Hjorth, J.; Lagler, F.; Mellqvist, J.; Beecken, J.; Berg, N.; Duyzer, J.; Westrate, H.; Swart, D. P. J.; Berkhout, A. J. C.; Jalkanen, J.-P.; Prata, A. J.; van der Hoff, G. R.; Borowiak, A.

2014-08-01

Methods for the determination of ship fuel sulphur content and NOx emission factors based on remote measurements have been compared in the harbour of Rotterdam and compared to direct stack emission measurements on the ferry Stena Hollandica. The methods were selected based on a review of the available literature on ship emission measurements. They were either optical (LIDAR, Differential Optical Absorption Spectroscopy (DOAS), UV camera), combined with model-based estimates of fuel consumption, or based on the so called "sniffer" principle, where SO2 or NOx emission factors are determined from simultaneous measurement of the increase of CO2 and SO2 or NOx concentrations in the plume of the ship compared to the background. The measurements were performed from stations at land, from a boat and from a helicopter. Mobile measurement platforms were found to have important advantages compared to the land-based ones because they allow optimizing the sampling conditions and sampling from ships on the open sea. Although optical methods can provide reliable results it was found that at the state of the art level, the "sniffer" approach is the most convenient technique for determining both SO2 and NOx emission factors remotely. The average random error on the determination of SO2 emission factors comparing two identical instrumental set-ups was 6%. However, it was found that apparently minor differences in the instrumental characteristics, such as response time, could cause significant differences between the emission factors determined. Direct stack measurements showed that about 14% of the fuel sulphur content was not emitted as SO2. This was supported by the remote measurements and is in agreement with the results of other field studies.

Constraining the Sulfur Dioxide Degassing Flux from Turrialba Volcano, Costa Rica Using Unmanned Aerial System Measurements

NASA Technical Reports Server (NTRS)

Xi, Xin; Johnson, Matthew S.; Jeong, Seongeun; Fladeland, Matthew; Pieri, David; Diaz, Jorge Andres; Bland, Geoffrey L.

2016-01-01

Observed sulfur dioxide (SO2)mixing ratios onboard unmanned aerial systems (UAS) duringMarch 11-13, 2013 are used to constrain the three-day averaged SO2 degassing flux fromTurrialba volcanowithin a Bayesian inverse modeling framework. A mesoscale model coupled with Lagrangian stochastic particle backward trajectories is used to quantify the source-receptor relationships at very high spatial resolutions (i.e., b1 km). The model shows better performance in reproducing the near-surface meteorological properties and observed SO2 variations when using a first-order closure non-local planetary boundary layer (PBL) scheme. The optimized SO2 degassing fluxes vary from 0.59 +/- 0.37 to 0.83 +/- 0.33 kt d-1 depending on the PBL scheme used. These fluxes are in good agreement with ground-based gas flux measurements, and correspond to corrective scale factors of 8-12 to the posteruptive SO2 degassing rate in the AeroCom emission inventory. The maximum a posteriori solution for the SO2 flux is highly sensitive to the specification of prior and observational errors, and relatively insensitive to the SO2 loss term and temporal averaging of observations. Our results indicate relatively low degassing activity but sustained sulfur emissions from Turrialba volcano to the troposphere during March 2013. This study demonstrates the utility of low-cost small UAS platforms for volcanic gas composition and flux analysis.

Potential air quality benefits from increased solar photovoltaic electricity generation in the Eastern United States

NASA Astrophysics Data System (ADS)

Abel, David; Holloway, Tracey; Harkey, Monica; Rrushaj, Arber; Brinkman, Greg; Duran, Phillip; Janssen, Mark; Denholm, Paul

2018-02-01

We evaluate how fine particulate matter (PM2.5) and precursor emissions could be reduced if 17% of electricity generation was replaced with solar photovoltaics (PV) in the Eastern United States. Electricity generation is simulated using GridView, then used to scale electricity-sector emissions of sulfur dioxide (SO2) and nitrogen oxides (NOX) from an existing gridded inventory of air emissions. This approach offers a novel method to leverage advanced electricity simulations with state-of-the-art emissions inventories, without necessitating recalculation of emissions for each facility. The baseline and perturbed emissions are input to the Community Multiscale Air Quality Model (CMAQ version 4.7.1) for a full accounting of time- and space-varying air quality changes associated with the 17% PV scenario. These results offer a high-value opportunity to evaluate the reduced-form AVoided Emissions and geneRation Tool (AVERT), while using AVERT to test the sensitivity of results to changing base-years and levels of solar integration. We find that average NOX and SO2 emissions across the region decrease 20% and 15%, respectively. PM2.5 concentrations decreased on average 4.7% across the Eastern U.S., with nitrate (NO3-) PM2.5 decreasing 3.7% and sulfate (SO42-) PM2.5 decreasing 9.1%. In the five largest cities in the region, we find that the most polluted days show the most significant PM2.5 decrease under the 17% PV generation scenario, and that the greatest benefits are accrued to cities in or near the Ohio River Valley. We find summer health benefits from reduced PM2.5 exposure estimated as 1424 avoided premature deaths (95% Confidence Interval (CI): 284 deaths, 2 732 deaths) or a health savings of 13.1 billion (95% CI: 0.6 billion, 43.9 billion) These results highlight the potential for renewable energy as a tool for air quality managers to support current and future health-based air quality regulations.

Bulk energy storage increases United States electricity system emissions.

PubMed

Hittinger, Eric S; Azevedo, Inês M L

2015-03-03

Bulk energy storage is generally considered an important contributor for the transition toward a more flexible and sustainable electricity system. Although economically valuable, storage is not fundamentally a "green" technology, leading to reductions in emissions. We model the economic and emissions effects of bulk energy storage providing an energy arbitrage service. We calculate the profits under two scenarios (perfect and imperfect information about future electricity prices), and estimate the effect of bulk storage on net emissions of CO2, SO2, and NOx for 20 eGRID subregions in the United States. We find that net system CO2 emissions resulting from storage operation are nontrivial when compared to the emissions from electricity generation, ranging from 104 to 407 kg/MWh of delivered energy depending on location, storage operation mode, and assumptions regarding carbon intensity. Net NOx emissions range from -0.16 (i.e., producing net savings) to 0.49 kg/MWh, and are generally small when compared to average generation-related emissions. Net SO2 emissions from storage operation range from -0.01 to 1.7 kg/MWh, depending on location and storage operation mode.

Environmental assessment of NH3 injection for an industrial package boiler. Volume 2. Data supplement. Final report, January 1983-January 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castaldini, C.; DeRosier, R.; Waterland, L.R.

1986-02-01

The report discusses emission results from comprehensive flue-gas sampling of a gas- and oil-fired industrial boiler equipped with Exxon's Thermal DeNOx Ammonia Injection Process for NOx reduction. Comprehensive emission measurements included continuous monitoring of flue gas emissions; source assessment sampling system (SASS) tests; EPA Method 5/17 for solid and condensible particulate emissions and ammonia emissions; controlled condensation system for SO2 and SO3; and N2O emission sampling. Ammonia injection at a NH3/NO molar ratio of 2.52 gave a NOx reduction of 41% from an uncontrolled level of 234 ppm to a controlled level of 137 ppm. NH3 emissions increased from 11more » ppm for the baseline to an average of 430 ppm for ammonia injection. Nitrous oxide, N2O, was reduced 68% from a 50 ppm baseline level to a 17 ppm controlled level. Total particulate emissions increased by an order of magnitude from a baseline of 17.7 ng/J to a controlled level of 182 ng/J.« less

Environmental assessment of a firetube boiler firing coal/oil/water mixtures. Volume 1. Technical results. Final report, February 1981-November 1983

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeRosier, R.

1984-09-01

This volume describes emission results from sampling of flue-gas from a firetube boiler burning a coal/oil/water (COW) mixture and COW with soda ash added (COW+SA) to control SO/sub 2/ emissions. Measurements included: continuous monitoring of flue-gas emissions; source assessment sampling system (SASS) sampling of the flue gas with subsequent laboratory analysis of the samples to give total flue gas organics in two boiling point ranges, specific quantitation of the semivolatile organic priority pollutant species, and flue gas concentrations of 73 trace elements; Method 5 sampling for total particulate; and controlled condensation system sampling for SO/sub 2/ and SO/sub 3/ emissions.more » Flue-gas SO/sub 2/ emissions decreased almost 99% with soda ash addition from 1,089 to 13.6 ppm (3% O2). NOx emissions decreased slightly from 477 to 427 ppm, while CO emissions increased significantly from an average of 25 to 426 ppm (all at 3% O2). Particulate loading at the boiler outlet almost doubled (from 1,970 to 3,715 pg/dscm) with the additive. The size distribution of particulate also shifted to a much smaller mean diameter. Total organic emissions increased from 6.7 to 13.1 mg/dscm; most of the increase were nonvolatile (C16+) organics. Of the semivolatile organic priority pollutant species, only fluoranthene and phenanthrene were detected with the COW fuel, and phenanthrene with the COW+SA fuel.« less

Continuation of long-term global SO2 pollution monitoring from OMI to OMPS

NASA Astrophysics Data System (ADS)

Zhang, Yan; Li, Can; Krotkov, Nickolay A.; Joiner, Joanna; Fioletov, Vitali; McLinden, Chris

2017-04-01

Over the past 20 years, advances in satellite remote sensing of pollution-relevant species have made space-borne observations an increasingly important part of atmospheric chemistry research and air quality management. This progress has been facilitated by advanced UV-vis spectrometers, such as the Ozone Monitoring Instrument (OMI) on board the NASA Earth Observing System (EOS) Aura satellite, and continues with new instruments, such as the Ozone Mapping and Profiler Suite (OMPS) on board the NASA-NOAA Suomi National Polar-orbiting Partnership (SNPP) satellite. In this study, we demonstrate that it is possible, using our state-of-the-art principal component analysis (PCA) retrieval technique, to continue the long-term global SO2 pollution monitoring started by OMI with the current and future OMPS instruments that will fly on the NOAA Joint Polar Satellite System (JPSS) 1, 2, 3, and 4 satellites in addition to SNPP, with a very good consistency of retrievals from these instruments. Since OMI SO2 data have been primarily used for (1) providing regional context on air pollution and long-range transport on a daily basis and (2) providing information on point emission sources on an annual basis after data averaging, we focused on these two aspects in our OMI-OMPS comparisons. Four years of retrievals (2012-2015) have been compared for three regions: eastern China, Mexico, and South Africa. In general, the comparisons show relatively high correlations (r = 0. 79-0.96) of daily regional averaged SO2 mass between the two instruments and near-unity regression slopes (0.76-0.97). The annual averaged SO2 loading differences between OMI and OMPS are small (< 0.03 Dobson unit (DU) over South Africa and up to 0.1 DU over eastern China). We also found a very good correlation (r = 0. 92-0.97) in the spatial distribution of annual averaged SO2 between OMI and OMPS over the three regions during 2012-2015. The emissions from ˜ 400 SO2 sources calculated with the two instruments also show a very good correlation (r = ˜ 0.9) in each year during 2012-2015. OMPS-detected SO2 point source emissions are slightly lower than those from OMI, but OMI-OMPS differences decrease with increasing strength of source. The OMI-OMPS SO2 mass differences on a pixel by pixel (daily) basis in each region can show substantial differences. The two instruments have a spatial correlation coefficient of 0.7 or better on < ˜ 50 % of the days. It is worth noting that consistent SO2 retrievals were achieved without any explicit adjustments to OMI or OMPS radiance data and that the retrieval agreement may be further improved by introducing a more comprehensive Jacobian lookup table than is currently used.

Intercomparison of SO2 camera systems for imaging volcanic gas plumes

USGS Publications Warehouse

Kern, Christoph; Lübcke, Peter; Bobrowski, Nicole; Campion, Robin; Mori, Toshiya; Smekens, Jean-Francois; Stebel, Kerstin; Tamburello, Giancarlo; Burton, Mike; Platt, Ulrich; Prata, Fred

2015-01-01

SO2 camera systems are increasingly being used to image volcanic gas plumes. The ability to derive SO2 emission rates directly from the acquired imagery at high time resolution allows volcanic process studies that incorporate other high time-resolution datasets. Though the general principles behind the SO2 camera have remained the same for a number of years, recent advances in CCD technology and an improved understanding of the physics behind the measurements have driven a continuous evolution of the camera systems. Here we present an intercomparison of seven different SO2 cameras. In the first part of the experiment, the various technical designs are compared and the advantages and drawbacks of individual design options are considered. Though the ideal design was found to be dependent on the specific application, a number of general recommendations are made. Next, a time series of images recorded by all instruments at Stromboli Volcano (Italy) is compared. All instruments were easily able to capture SO2 clouds emitted from the summit vents. Quantitative comparison of the SO2 load in an individual cloud yielded an intra-instrument precision of about 12%. From the imagery, emission rates were then derived according to each group's standard retrieval process. A daily average SO2 emission rate of 61 ± 10 t/d was calculated. Due to differences in spatial integration methods and plume velocity determination, the time-dependent progression of SO2 emissions varied significantly among the individual systems. However, integration over distinct degassing events yielded comparable SO2 masses. Based on the intercomparison data, we find an approximate 1-sigma precision of 20% for the emission rates derived from the various SO2 cameras. Though it may still be improved in the future, this is currently within the typical accuracy of the measurement and is considered sufficient for most applications.

Intercomparison of SO2 camera systems for imaging volcanic gas plumes

NASA Astrophysics Data System (ADS)

Kern, Christoph; Lübcke, Peter; Bobrowski, Nicole; Campion, Robin; Mori, Toshiya; Smekens, Jean-François; Stebel, Kerstin; Tamburello, Giancarlo; Burton, Mike; Platt, Ulrich; Prata, Fred

2015-07-01

SO2 camera systems are increasingly being used to image volcanic gas plumes. The ability to derive SO2 emission rates directly from the acquired imagery at high time resolution allows volcanic process studies that incorporate other high time-resolution datasets. Though the general principles behind the SO2 camera have remained the same for a number of years, recent advances in CCD technology and an improved understanding of the physics behind the measurements have driven a continuous evolution of the camera systems. Here we present an intercomparison of seven different SO2 cameras. In the first part of the experiment, the various technical designs are compared and the advantages and drawbacks of individual design options are considered. Though the ideal design was found to be dependent on the specific application, a number of general recommendations are made. Next, a time series of images recorded by all instruments at Stromboli Volcano (Italy) is compared. All instruments were easily able to capture SO2 clouds emitted from the summit vents. Quantitative comparison of the SO2 load in an individual cloud yielded an intra-instrument precision of about 12%. From the imagery, emission rates were then derived according to each group's standard retrieval process. A daily average SO2 emission rate of 61 ± 10 t/d was calculated. Due to differences in spatial integration methods and plume velocity determination, the time-dependent progression of SO2 emissions varied significantly among the individual systems. However, integration over distinct degassing events yielded comparable SO2 masses. Based on the intercomparison data, we find an approximate 1-sigma precision of 20% for the emission rates derived from the various SO2 cameras. Though it may still be improved in the future, this is currently within the typical accuracy of the measurement and is considered sufficient for most applications.

The growing contribution of sulfur emissions from ships in Asian waters, 1988-1995.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Streets, D. G.; Guttikunda, S. K.; Carmichael, G. R.

2000-01-01

International shipping is a major source of sulfur emissions in Asia. Because the fuel oil used by ships is high in sulfur, the resulting emissions of SO{sub 2}2 are large and contribute as much as 20% to the atmospheric loading in the vicinity of ports and heavily traveled waterways. Because of the rapid growth of Asian economies in the 1980s and early 1990s, it is estimated that shipping trade grew by an average of 5.4% per year between 1988 and 1995; in particular, crude oil shipments to Asian countries other than Japan grew by an average of 11.4% per year.more » The emissions of SO{sub 2} from shipping are estimated to have grown by 5.9% per year between 1988 and 1995, rising from 545 Gg in 1988 to 817 Gg in 1995. This study uses the ATMOS atmospheric transport and deposition model to study the effects of these emissions, both in absolute terms and relative to land-based emissions, on wet and dry deposition of sulfur. Southeast Asia is most heavily affected by emissions from ships, particularly Sumatra, peninsular Malaysia, and Singapore, which routinely receive in excess of 10% of their deposition from ships. A strong seasonal component is also observed, with large areas of Southeast Asia and coastal Japan receiving sulfur deposition that exceeds 10 mg S m{sup -2} season{sup -1}. Deposition is at least 25% higher in summer and fall than in winter and spring. Peak values of 25-50 mg S m{sup -2} season{sup -1} are calculated for winter in the Strait of Malacca. This work suggests a need to introduce policies to reduce the sulfur content of marine fuels or otherwise reduce emissions of SO{sub 2} from ships in Asian waters.« less

[Spatial distribution of sulfur dioxide around a tobacco bulk-curing workshop cluster].

PubMed

He, Fan; Wang, Mei; Wang, Tao; Sun, Jian-Feng; Huang, Wu-Xing; Tian, Bin-Qiang; Gong, Chang-Rong

2014-03-01

In order to manifest lower energy consumption and less labor employment, and provide the theoretical basis for constructing environmentally friendly modem tobacco agriculture, this paper analyzed gas composition of the chimney from a bulk-curing barn and the dispersion of sulfur dioxide (SO2) around the workshop cluster using ecom-J2KN flue gas analyzer and air sampler. During curing, the concentrations of carbon dioxide (CO2) and SO2 in the chimney were both highest at 38 degrees C, while the concentration of nitrogen oxides (NOx) was highest at 42 degrees C. The emission concentration of SO2 from the chimney was 1327.60-2218.40 mg x m(-3). Average SO2 emission would decrease by 49.7% through adding 4.0% of a sulfur-fixed agent. The highest concentrations of SO2 in the surface soil appeared at the yellowing stage. SO2 concentration in horizontal direction localized at 43-80 m exceeded 0.5 mg x m(-3). The highest concentration of SO2 (0.57 mg x m(-3)) was observed at 50 m. At 50 m in the downstream wind direction of the workshop cluster, SO2 concentration in vertical direction localized at 0.9-1.8 m exceeded 0.5 mg x m(-3), and the highest concentration of SO2 in vertical direction was 0.65 mg x m(-3) at 1.6 m. During curing, the average concentration of SO2 was decreased by 0.43 mg x m(-3) by using the sulfur-fixed agent. The polluted boundary was localized at 120 m in the downstream wind direction of the workshop cluster.

A simplified approach to analyze the effectiveness of NO2 and SO2 emission reduction of coal-fired power plant from OMI retrievals

NASA Astrophysics Data System (ADS)

Bai, Yang; Wu, Lixin; Zhou, Yuan; Li, Ding

2017-04-01

Nitrogen oxides (NOX) and sulfur dioxide (SO2) emissions from coal combustion, which is oxidized quickly in the atmosphere resulting in secondary aerosol formation and acid deposition, are the main resource causing China's regional fog-haze pollution. Extensive literature has estimated quantitatively the lifetimes and emissions of NO2 and SO2 for large point sources such as coal-fired power plants and cities using satellite measurements. However, rare of these methods is suitable for sources located in a heterogeneously polluted background. In this work, we present a simplified emission effective radius extraction model for point source to study the NO2 and SO2 reduction trend in China with complex polluted sources. First, to find out the time range during which actual emissions could be derived from satellite observations, the spatial distribution characteristics of mean daily, monthly, seasonal and annual concentration of OMI NO2 and SO2 around a single power plant were analyzed and compared. Then, a 100 km × 100 km geographical grid with a 1 km step was established around the source and the mean concentration of all satellite pixels covered in each grid point is calculated by the area weight pixel-averaging approach. The emission effective radius is defined by the concentration gradient values near the power plant. Finally, the developed model is employed to investigate the characteristic and evolution of NO2 and SO2 emissions and verify the effectiveness of flue gas desulfurization (FGD) and selective catalytic reduction (SCR) devices applied in coal-fired power plants during the period of 10 years from 2006 to 2015. It can be observed that the the spatial distribution pattern of NO2 and SO2 concentration in the vicinity of large coal-burning source was not only affected by the emission of coal-burning itself, but also closely related to the process of pollutant transmission and diffusion caused by meteorological factors in different seasons. Our proposed model can be used to identify the effective operation time of FGD and SCR equipped in coal-fired power plant.

New discoveries enabled by OMI SO2 measurements and future missions

NASA Astrophysics Data System (ADS)

Krotkov, Nickolay

2010-05-01

The Ozone Monitoring Instrument (OMI) on NASA Aura satellite makes global daily measurements of the total column of sulfur dioxide (SO2), a short-lived trace gas produced by fossil fuel combustion, smelting, and volcanoes. This talk highlights most recent science results enabled by using OMI SO2 data. OMI daily contiguous volcanic SO2 data continue 25+ climatic record by its predecessors (Total Ozone mapping Spectrometers 1978-2005), but higher SO2 sensitivity allows measuring volcanic plumes for a longer time as well as measuring passive volcanic degassing from space. New algorithm development allows direct estimating of SO2 plume heights to refine SO2 tonnages in largest volcanic plumes important for climate applications. Quantitatively, anthropogenic SO2 is more difficult to measure from space, since ozone absorption and Rayleigh scattering reduce sensitivity to pollutants in the lower troposphere. OMI data first enabled daily detection of SO2 burdens from individual smelters as well as observed SO2 pollution lofting from boundary layer and long-range transport in free troposphere. Interplay between volcanic and anthropogenic SO2 emissions resulted in highly variable SO2 pollution levels in Peru and Mexico City. We have updated our copper smelter analysis, which showed interesting new trends. Combining OMI data with trajectory models and aerosol/cloud measurements by A-train sensors (MODIS, CALIPSO) allowed tracking long-range transport of volcanic and anthropogenic aerosol/SO2 plumes. These studies placed new constraints on conversion rates of SO2 to sulfate at different heights from free troposphere to the lower stratosphere. We describe new techniques for spatial and time averaging that have been used to determine the global distribution of anthropogenic SO2 burdens, and the efficacy of abatement strategies. OMI seasonal to multi-year average images clearly show the world-highest consistent SO2 pollution in eastern China, mostly due to the burning of high-sulfur coal in its many coal-fired power plants. Recently, China's government has instituted nationwide measures to control SO2 emissions through the adoption of flue-gas desulfurization technology (FGD) on new power plants; and even greater measures were adopted in the Beijing area in anticipation of the Olympic Games. We demonstrate that the OMI can pick up both SO2 and NO2 emissions from large point sources in northern China, where large increases in both gases were observed from 2005 to 2007, over areas with newly established power plants. The OMI SO2/NO2 ratio generally agrees with the estimated emission factors for coal-fired power plants based on a bottom-up approach. Between 2007 and 2008, OMI detected little change in NO2 but dramatic decline in SO2 over the same areas. While the almost constant NO2 levels between the two years imply steady electricity generation from the power plants, the large reduction in SO2 confirms the effectiveness of the FGD units, which likely became operational between 2007 and 2008. Further development of satellite detection and monitoring of point pollution sources requires better than 10km ground resolution. We show how planned Dutch /ESA TROPOMI and NASA GEOCape missions will advance the art of measuring point source emissions in coming decade.

76 FR 18407 - Standards of Performance for New Stationary Sources and Emissions Guidelines for Existing Sources...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-04

... removing extraneous text from the hydrogen chloride emissions limit for large hospital/medical/infectious.../dibenzofurans, carbon monoxide, nitrogen oxides (NO X ), hydrogen chloride (HCl), and sulfur dioxide (SO 2...\\ dscf). Hydrogen chloride ppmv or percent 100 or 93% 100 or 93% 100 or 93% 3-run average (1- EPA...

Ghg and Aerosol Emission from Fire Pixel during Crop Residue Burning Under Rice and Wheat Cropping Systems in North-West India

NASA Astrophysics Data System (ADS)

Acharya, Prasenjit; Sreekesh, S.; Kulshrestha, Umesh

2016-10-01

Emission of smoke and aerosol from open field burning of crop residue is a long-standing subject matter of atmospheric pollution. In this study, we proposed a new approach of estimating fuel load in the fire pixels and corresponding emissions of selected GHGs and aerosols i.e. CO2, CO, NO2, SO2, and total particulate matter (TPM) due to burning of crop residue under rice and wheat cropping systems in Punjab in north-west India from 2002 to 2012. In contrasts to the conventional method that uses RPR ratio to estimate the biomass, fuel load in the fire pixels was estimated as a function of enhanced vegetation index (EVI). MODIS fire products were used to detect the fire pixels during harvesting seasons of rice and wheat. Based on the field measurements, fuel load in the fire pixels were modelled as a function of average EVI using second order polynomial regression. Average EVI for rice and wheat crops that were extracted through Fourier transformation were computed from MODIS time series 16 day EVI composites. About 23 % of net shown area (NSA) during rice and 11 % during wheat harvesting seasons are affected by field burning. The computed average fuel loads are 11.32 t/ha (±17.4) during rice and 10.89 t/ha (±8.7) during wheat harvesting seasons. Calculated average total emissions of CO2, CO, NO2, SO2 and TPM were 8108.41, 657.85, 8.10, 4.10, and 133.21 Gg during rice straw burning and 6896.85, 625.09, 1.42, 1.77, and 57.55 Gg during wheat burning. Comparison of estimated values shows better agreement with the previous concurrent estimations. The method, however, shows its efficiency parallel to the conventional method of estimation of fuel load and related pollutant emissions.

Major study reveals EEC gas oil desulfurization costs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Waller, G.J.; Conrad, M.C.; Cremer, G.

1985-01-21

The interest of the European Economic Community (EEC) Commission in the issue of acid rain has prompted a Concawe working group to make an independent study of the cost of achieving a reduction of average sulfur levels for gas oils consumed in the EEC. The need for desulfurization of gas oils should be seen in the context of their overall contribution to SO/sub 2/ emissions. The removal of sulfur from gas oil is apparently one of the most costly ways to reduce SO/sub 2/ emissions. The overall effect is apparently the smallest. A reduction of 0.1% sulfur for all gasmore » oil produced in the EEC would result in a reduction of only about 140,000 tons/year of sulfur, corresponding to less than 2% of the present total SO/sub 2/ emissions. The cost of the incremental ton of sulfur removed from the gas oil pool increases significantly for lower sulfur specifications. The overall conclusion is that sulfur reduction between 0.43% and 0.2% is comparable in cost to other methods of reducing SO/sub 2/ emissions. For a reduction below 0.2%, excessive costs can be expected and it would be more economical in most cases to consider another means.« less

Assessment of air quality benefits from the national pollution control policy of thermal power plants in China: A numerical simulation

NASA Astrophysics Data System (ADS)

Wang, Zhanshan; Pan, Libo; Li, Yunting; Zhang, Dawei; Ma, Jin; Sun, Feng; Xu, Wenshuai; Wang, Xingrun

2015-04-01

In 2010, an emission inventory of air pollutants in China was created using the Chinese Bulletin of the Environment, the INTEX-B program, the First National Pollution Source Census, the National Generator Set Manual, and domestic and international research studies. Two emission scenarios, the standard failed emission scenario (S1) and the standard successful emission scenario (S2), were constructed based upon the Instructions for the Preparation of Emission Standards for Air Pollutants from Thermal Power Plants (second draft). The Fifth-Generation NCAR/Penn State Mesoscale Model (MM5) and the U.S. EPA Models-3 Community Multiscale Air Quality (CMAQ) model were applied to China to study the air quality benefits from Emission Standards for Air Pollutants from Thermal Power Plants GB13223-2011. The performance of MM5 and CMAQ was evaluated with meteorological data from Global Surface Data from the National Climatic Data Center (NCDC) and the daily Air Pollution Index (API) reported by Chinese local governments. The results showed that the implementation of the new standards could reduce the concentration of air pollutants and acid deposition in China by varying degrees. The new standards could reduce NO2 pollution in China. By 2020, for the scenario S2, the area with an NO2 concentration higher than the second-level emission standard, and the average NO2 concentration in 31 selected provinces would be reduced by 55.2% and 24.3%, respectively. The new standards could further reduce the concentration of declining SO2 in China. By 2020, for S2, the area with an SO2 concentration higher than the second-level emission standard and the average SO2 concentration in the 31 selected provinces would be reduced by 40.0% and 31.6%, respectively. The new standards could also reduce PM2.5 pollution in China. By 2020, for S2, the area with a PM2.5 concentration higher than the second-level emission standard and the average concentration of PM2.5 in the 31 selected provinces would be reduced by 17.2% and 14.7%, respectively. The new standard could reduce nitrogen deposition pollution in China. By 2020, for S2, the area with a nitrogen deposition concentration >2.0 tons·km-2 and the total nitrogen deposition in China would be reduced by 28.6% and 16.8%, respectively. The new standards could reduce sulfur deposition pollution in China. By 2020, for S2, the area with a sulfur deposition >1.5 tons·km-2 and the total sulfur deposition in China would be reduced by 55.3% and 21.0%, respectively.

CHClF/sub 2/ (F-22) in the earth's atmosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rasmussen, R.A.; Khalil, M.A.K.; Penkett, S.A.

1980-10-01

Recent global measurements of CHClF/sub 2/ (F-22) are reported. Originally, GC/MS techniques were used to obtain these data. Since then, significant advances using an O/sub 2/-doped electron capture detector have been made in the analytical techniques, so that F-22 can be measured by EC/GC methods at ambient concentrations. The atmospheric burden of F-22 calculated from these measurements (average mixing ratio, mid-1979, approx.45 pptv) is considerably greater than that expected from the estimates of direct industrial emissions (average mixing ratio, mid-1979, approx.30 pptv). This difference is probably due to underestimates of F-22 emissions.

CHClF2 (F-22) in the Earth's atmosphere

NASA Astrophysics Data System (ADS)

Rasmussen, R. A.; Khalil, M. A. K.; Penkett, S. A.; Prosser, N. J. D.

1980-10-01

Recent global measurements of CHClF2 (F-22) are reported. Originally, GC/MS techniques were used to obtain these data. Since then, significant advances using an O2-doped electron capture detector have been made in the analytical techniques, so that F-22 can be measured by EC/GC methods at ambient concentrations. The atmospheric burden of F-22 calculated from these measurements (average mixing ratio, mid-1979, ˜45 pptv) is considerably greater than that expected from the estimates of direct industrial emissions (average mixing ratio, mid-1979, ˜30 pptv). This difference is probably due to underestimates of F-22 emissions.

CHClF2 /F-22/ in the earth's atmosphere

NASA Technical Reports Server (NTRS)

Rasmussen, R. A.; Khalil, M. A. K.; Penkett, S. A.; Prosser, N. J. D.

1980-01-01

Recent global measurements of CHClF2 (F-22) are reported. Originally, GC/MS techniques were used to obtain these data. Since then, significant advances using an O2-doped electron capture detector have been made in the analytical techniques, so that F-22 can be measured by EC/GC methods at ambient concentrations. The atmospheric burden of F-22 calculated from these measurements (average mixing ratio, mid-1979, approximately 45 pptv) is considerably greater than that expected from the estimates of direct industrial emissions (average mixing ratio, mid-1979, approximately 30 pptv). This difference is probably due to underestimates of F-22 emissions.

Appalachian basin bituminous coal: sulfur content and potential sulfur dioxide emissions of coal mined for electrical power generation: Chapter G.5 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Trippi, Michael H.; Ruppert, Leslie F.; Attanasi, E.D.; Milici, Robert C.; Freeman, P.A.

2014-01-01

Data from 157 counties in the Appalachian basin of average sulfur content of coal mined for electrical power generation from 1983 through 2005 show a general decrease in the number of counties where coal mining has occurred and a decrease in the number of counties where higher sulfur coals (>2 percent sulfur) were mined. Calculated potential SO2 emissions (assuming no post-combustion SO2 removal) show a corresponding decrease over the same period of time.

Status and trends in atmospheric deposition and emissions near Atlanta, Georgia, 1986-99

USGS Publications Warehouse

Peters, N.E.; Meyers, T.P.; Aulenbach, Brent T.

2002-01-01

Wet and dry atmospheric deposition were investigated from weekly data, 1986-99 (1986-97 for dry deposition) at the Panola Mountain Research Watershed (PMRW), a forested research site 25 km, southeast of Atlanta, Georgia. Furthermore, the wet deposition was compared to that at three adjacent National Atmospheric Deposition Program's National Trends Network (NTN) sites (GA41, 50 km south of PMRW; AL99, 175 km northwest; NC25, 175 km north-northeast) and dry deposition was compared to that at adjacent Clean Air Status and Trends Network (CASTNET) sites, co-located at the NTN sites. The pH of precipitation is acidic and the dominant acid anion is SO4; the pH (derived from the volume-weighted mean H concentration) averages 4.44 for 1986-99, and varies seasonally with average lowest values in summer (4.19) and highest in winter (4.63). From 1986-99, the annual wet deposition of sulfur (S) and nitrogen (N) averaged 400 and 300 eq ha-1 (6.4 and 4.2 kg ha-1), respectively. Inferential model estimates of annual dry S and N deposition from 1986-97 averaged 130 and 150 eq ha-1 (2.1 and 2.1 kg ha-1), respectively. From 1993-99, net S deposition (dry deposition plus canopy interactions) for coniferous and deciduous throughfall (throughfall minus wet-only deposition) averaged 400 and 150 eq ha-1 (6.4 and 2.1 kg ha-1), respectively. The annual wet deposition of S and N species at PMRW was comparable to that at NTN sites, with the exception of higher N species deposition at AL99 and relatively lower H, SO4 and NO3 deposition at GA41. Dry S deposition at PMRW differed markedly from the CASTNET sites despite similarity in S concentrations for all but NC25; the differences are attributed to differences in model parameters associated with the landscape and vegetation characteristics at the sites. At PMRW, atmospheric deposition trends were not detected for the entire sampling period, but were detected for shorter periods (4-5yr). Annual S and N deposition increased from 1986 to 1991, decreased to 1995 and then increased to 1999. SO2 emissions from seven major point sources within 120 km of PMRW decreased markedly from the late 1980s to 1995 and have remained relatively constant or increased slightly from 1995 to 1998 Annual wet and dry S deposition at PMRW significantly correlates (p < 0.01) with SO2 emissions, and the correlation is dominated by the large SO2 emissions decreases in the early 1990s, consistent with the implementation of Phase I of Title IV of the 1990 Clean Air Act Amendments.

Emission inventories for ships in the Arctic based on satellite sampled AIS data

NASA Astrophysics Data System (ADS)

Christensen, J. H.; Winther, M.; Plejdrup, M. S.; Ravn, E. S.; Eriksson, O. M.; Kristensen, H. O.

2013-12-01

Emissions from ships inside Arctic are an important source of the Arctic pollution as e.g. SO2, NOx and Black Carbon (BC). This paper presents a detailed BC, NOx and SO2 emission inventory for ships in the Arctic for the year 2012 based on satellite AIS data, ship engine power functions and technology stratified emission factors. Emission projections are presented for the years 2020, 2030 and 2050 combined with emission from polar diversion routes as given by Corbett et al. (2010). Furthermore the Danish Eulerian Hemispheric Model (Christensen, 1997; Brandt et al., 2012), which is 3-d Chemical Transport Model covering the Northern hemisphere was use to study the transport of BC, SO2 and O3 and estimate BC deposition results in order to study then current and future contribution from Arctic ship traffics to atmospheric concentrations and deposition of pollutants in the Arctic. In 2012, the largest emission contributions of Artic ships emissions are from fishing ships (45% for BC, 38% for NOx and 23% for SO2) followed by passenger ships (20%, 17%, 25%), tankers (9%, 13%, 15%), general cargo (8%, 11%, 12%) and container ships (5%, 7%, 8%). Without diverted traffic from 2012 to 2050 the total BC, NOx and SO2 emissions are expected to change by 16 %, -32 % and -63 %, respectively. For the year 2012 the average calculated contributions for ships of BC, SO, and O3 concentrations and BC deposition become low and similar for the emissions projections without diverted traffic of the years 2020, 2030 and 2050, but with diverted traffic the contributions for ships to the BC, SO, and O3 concentrations and BC deposition becomes significantly higher especially for the year 2050 and especially during the summer season over the areas, where the diverted traffic are assumed to occur. These high forecasted values for BC sea-ice deposition close to the Polar routes are of main concern due to decreases in the albedo which in turn enhances the melting of sea-ice.

Unregulated pollutant emissions from on-road vehicles in China, 1999-2014.

PubMed

Lang, Jianlei; Zhou, Ying; Cheng, Shuiyuan; Zhang, Yanyun; Dong, Meng; Li, Shengyue; Wang, Gang; Zhang, Yonglin

2016-12-15

Multi-year (1999-2014) vehicular unregulated pollutants emissions in China, including SO 2 , CH 4 , N 2 O, NH 3 , Indeno(1,2,3-cd)pyrene (IPY), Benzo(k)fluoranthene (BkF), Benzo(b)fluoranthene (BbF), Benzo(a)pyrene (BaP), dioxins and furans, were estimated based on emission factors calculated by COPERT. The inter-annual trends, correlation with GDP and population, spatial distribution characteristics, contributions from various vehicle types for the ten pollutants emissions were analyzed. Results showed that the emissions of the above ten pollutants changed from approximately 576.9Gg, 130.0Gg, 8.1Gg, 2.1Gg, 1.0Mg, 1.1Mg, 1.4Mg, 0.5Mg, 7.4g and 15.6g in 1999 to 193.8Gg, 171.1Gg, 79.1Gg, 117.8Gg, 3.5Mg, 6.7Mg, 6.8Mg, 2.9Mg, 37.6g and 79.1g in 2014, respectively. Implementation of stringent sulfur content limit during the past decade reduced approximately 94.4% of the SO 2 emission in 2014. CH 4 and N 2 O increased from 1999 to 2011, but began to decrease since 2012; NH 3 emission had the highest annual average change rate (35.5%) from 1999 to 2014; PAHs, dioxins and furans increased continuously during the past decade. The vehicular emissions were higher in Guangdong, Shandong, Henan, Jiangsu, Zhejiang and Hebei. Good linear correlation between vehicular emissions and GDP was found (except SO 2 ); in the provinces/municipalities with higher population density, the emission density was also larger, indicating more significant vehicular emissions' potential damage on human health. HDT and PC, PC and MC, PC and BUS were the major contributors to SO 2 , CH 4 , N 2 O emissions, respectively. In 2014, PC was the dominant contributor to NH 3 emission; PC, BUS and HDT had higher fraction in the total IPY and BaP emissions; HDT was the major contributor to BkF and BbF emissions. In addition, the uncertainties of estimated emissions were also analyzed based on Monte Carlo simulation. Copyright © 2016 Elsevier B.V. All rights reserved.

Potential air quality benefits from increased solar photovoltaic electricity generation in the Eastern United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abel, David; Holloway, Tracey; Harkey, Monica

We evaluate how fine particulate matter (PM2.5) and precursor emissions could be reduced if 17% of electricity generation was replaced with solar photovoltaics (PV) in the Eastern United States. Electricity generation is simulated using GridView, then used to scale electricity-sector emissions of sulfur dioxide (SO2) and nitrogen oxides (NOX) from an existing gridded inventory of air emissions. This approach offers a novel method to leverage advanced electricity simulations with state-of-the-art emissions inventories, without necessitating recalculation of emissions for each facility. The baseline and perturbed emissions are input to the Community Multiscale Air Quality Model (CMAQ version 4.7.1) for a fullmore » accounting of time- and space-varying air quality changes associated with the 17% PV scenario. These results offer a high-value opportunity to evaluate the reduced-form AVoided Emissions and geneRation Tool (AVERT), while using AVERT to test the sensitivity of results to changing base-years and levels of solar integration. We find that average NOX and SO2 emissions across the region decrease 20% and 15%, respectively. PM2.5 concentrations decreased on average 4.7% across the Eastern U.S., with nitrate (NO3-) PM2.5 decreasing 3.7% and sulfate (SO42-) PM2.5 decreasing 9.1%. In the five largest cities in the region, we find that the most polluted days show the most significant PM2.5 decrease under the 17% PV generation scenario, and that the greatest benefits are accrued to cities in or near the Ohio River Valley. We find summer health benefits from reduced PM2.5 exposure estimated as 1424 avoided premature deaths (95% Confidence Interval (CI): 284 deaths, 2 732 deaths) or a health savings of $13.1 billion (95% CI: $0.6 billion, $43.9 billion) These results highlight the potential for renewable energy as a tool for air quality managers to support current and future health-based air quality regulations.« less

OMI measurements of SO2 pollution over Eastern China in 2005-2008

NASA Astrophysics Data System (ADS)

Krotkov, N.; Pickering, K.; Witte, J.; Carn, S.; Yang, K.; Carmichael, G.; Streets, D.; Zhang, Q.; Wei, C.

2009-05-01

The Ozone Monitoring Instrument (OMI) on NASA Aura satellite makes global daily measurements of the total column of sulfur dioxide (SO2), a short-lived trace gas produced by fossil fuel combustion, smelting, and volcanoes. OMI seasonal to multi-year average images clearly show the world-highest consistent SO2 pollution in northeast China. China is the world's largest SO2 emitter, mostly due to the burning of high-sulfur coal in its many coal-fired power plants, which lack the technology used in many other countries to remove sulfur from smoke stack emissions. China's government has instituted nationwide measures to control SO2 emissions through the adoption of flue-gas desulfurization technology on new power plants; and even greater measures were adopted in the Beijing area in anticipation of the Olympic Games. To study the environmental effects of the emission controls we compared OMI SO2 time series over eastern China for 2005 through 2008. The time series have been done as 7-day running means of the cloud-free daily observations. By mid-March we started to see substantial periods of lower SO2 values in 2008 compared to 2007, and by mid June the 2008 values were consistently lower than 2007 and prior years. The decline is widespread with highest SO2 typically located to the south and southwest of Beijing in regions with large clusters of power plants and also around Shanghai. The decline also lasted beyond the Olympic season. We do not yet know to what extent the economic downturn in China (and reduced industrial production) contributed to lower SO2 levels in the fall of 2008. We have also compared the observed and modeled fields using University of Iowa STEM model for the period June - September 2008. The model provided SO2 vertical distributions as well as aerosol vertical profiles that were used to correct OMI operational SO2 retrievals and improve the comparisons. The OMI SO2 changes in 2008 have also been compared with the estimated changes in SO2 emissions derived from a bottom-up analysis of the SO2 reduction measures put into place for the Olympics. Finally we present our plans to use the OMI SO2 columns to provide a top-down constraint on SO2 regional emissions.

Air quality impact of the coal-fired power plants in the northern passageway of the China West-East Power Transmission Project.

PubMed

Xue, Zhigang; Hao, Jiming; Chai, Fahe; Duan, Ning; Chen, Yizhen; Li, Jindan; Chen, Fu; Liu, Simei; Pu, Wenqing

2005-12-01

This paper analyzes the air quality impacts of coal-fired power plants in the northern passageway of the West-East Power Transmission Project in China. A three-layer Lagrangian model called ATMOS, was used to simulate the spatial distribution of incremental sulfur dioxide (SO2) and coarse particulate matter (PM10) concentrations under different emission control scenarios. In the year 2005, the emissions from planned power plants mainly affected the air quality of Shanxi, Shaanxi, the common boundary of Inner Mongolia and Shanxi, and the area around the boundary between Inner Mongolia and Ningxia. In these areas, the annually averaged incremental SO2 and PM10 concentrations exceed 2 and 2.5 microg/m3, respectively. The maximum increases of the annually averaged SO2 and PM10 concentrations are 8.3 and 7.2 microg/m3, respectively, which occur around Hancheng city, near the boundary of the Shaanxi and Shanxi provinces. After integrated control measures are considered, the maximum increases of annually averaged SO2 and PM10 concentrations fall to 4.9 and 4 microg/m3, respectively. In the year 2010, the areas affected by planned power plants are mainly North Shaanxi, North Ningxia, and Northwest Shanxi. The maximum increases of the annually averaged SO2 and PM10, concentrations are, respectively, 6.3 and 5.6 microg/m3, occurring in Northwest Shanxi, which decline to 4.4 and 4.1 microg/m3 after the control measures are implemented. The results showed that the proposed power plants mainly affect the air quality of the region where the power plants are built, with little impact on East China where the electricity will be used. The influences of planned power plants on air quality will be decreased greatly by implementing integrated control measures.

Environmental assessment of NH/sub 3/ injection for an industrial package boiler. Volume 1. Technical results. Final report, January 1983-January 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castaldini, C.; DeRosier, R.; Waterland, L.R.

1986-02-01

The report discusses emission results from comprehensive flue gas sampling of a gas- and oil-fired industrial boiler equipped with Exxon's Thermal DeNO/sub x/ Ammonia Injection Process for NO/sub x/ reduction. Comprehensive emission measurements included continuous monitoring of flue gas emissions; source assessment sampling system (SASS) tests; EPA Method 5/17 for solid and condensible particulate emissions and ammonia emissions; controlled condensation system for SO/sub 2/ and SO/sub 3/; and N/sub 2/O emission sampling. Ammonia injection at a NH/sub 3//NO molar ratio of 2.52 gave a NO/sub x/ reduction of 41% from an uncontrolled level of 234 ppm to a controlled levelmore » of 137 ppm. NH/sub 3/ emissions increased from 11 ppm for the baseline to an average of 430 ppm for ammonia injection. Nitrous oxide, N/sub 2/O was reduced 68% from a 50 ppm baseline level to a 17 ppm controlled level. Total particulate emissions increased by an order of magnitude from a baseline of 17.7 ng/J to a controlled level of 182 ng/J. The increase is in part attributed to formation of ammonia sulfate and bisulfate from residual ammonia and SO/sub x/. Total organic emissions were at a moderate level and showed a relative concentration in the nonvolatile category. Organic emissions of CO and trace inorganic elements were not significantly affected by ammonia injection.« less

Effectiveness of Emission Controls to Reduce the Atmospheric Concentrations of Mercury.

PubMed

Castro, Mark S; Sherwell, John

2015-12-15

Coal-fired power plants in the United States are required to reduce their emissions of mercury (Hg) into the atmosphere to lower the exposure of Hg to humans. The effectiveness of power-plant emission controls on the atmospheric concentrations of Hg in the United States is largely unknown because there are few long-term high-quality atmospheric Hg data sets. Here, we present the atmospheric concentrations of Hg and sulfur dioxide (SO2) measured from 2006 to 2015 at a relatively pristine location in western Maryland that is several (>50 km) kilometers downwind of power plants in Ohio, Pennsylvania, and West Virginia. Annual average atmospheric concentrations of gaseous oxidized mercury (GOM), SO2, fine particulate mercury (PBM2.5), and gaseous elemental mercury (GEM) declined by 75%, 75%, 43%, and 13%, respectively, and were strongly correlated with power-plant Hg emissions from the upwind states. These results provide compelling evidence that reductions in Hg emissions from power plants in the United States had their intended impact to reduce regional Hg pollution.

Anthropogenic, biomass burning, and volcanic emissions of black carbon, organic carbon, and SO2 from 1980 to 2010 for hindcast model experiments

NASA Astrophysics Data System (ADS)

Diehl, T.; Heil, A.; Chin, M.; Pan, X.; Streets, D.; Schultz, M.; Kinne, S.

2012-09-01

Two historical emission inventories of black carbon (BC), primary organic carbon (OC), and SO2 emissions from land-based anthropogenic sources, ocean-going vessels, air traffic, biomass burning, and volcanoes are presented and discussed for the period 1980-2010. These gridded inventories are provided to the internationally coordinated AeroCom Phase II multi-model hindcast experiments. The horizontal resolution is 0.5°×0.5° and 1.0°×1.0°, while the temporal resolution varies from daily for volcanoes to monthly for biomass burning and aircraft emissions, and annual averages for land-based and ship emissions. One inventory is based on inter-annually varying activity rates of land-based anthropogenic emissions and shows strong variability within a decade, while the other one is derived from interpolation between decadal endpoints and thus exhibits linear trends within a decade. Both datasets capture the major trends of decreasing anthropogenic emissions over the USA and Western Europe since 1980, a sharp decrease around 1990 over Eastern Europe and the former USSR, and a steep increase after 2000 over East and South Asia. The inventory differences for the combined anthropogenic and biomass burning emissions in the year 2005 are 34% for BC, 46% for OC, and 13% for SO2. They vary strongly depending on species, year and region, from about 10% to 40% in most cases, but in some cases the inventories differ by 100% or more. Differences in emissions from wild-land fires are caused only by different choices of the emission factors for years after 1996 which vary by a factor of about 1 to 2 for OC depending on region, and by a combination of emission factors and the amount of dry mass burned for years up to 1996. Volcanic SO2 emissions, which are only provided in one inventory, include emissions from explosive, effusive, and quiescent degassing events for 1167 volcanoes.

Real-world volatile organic compound emission rates from seated adults and children for use in indoor air studies.

PubMed

Stönner, C; Edtbauer, A; Williams, J

2018-01-01

Human beings emit many volatile organic compounds (VOCs) of both endogenous (internally produced) and exogenous (external source) origin. Here we present real-world emission rates of volatile organic compounds from cinema audiences (50-230 people) as a function of time in multiple screenings of three films. The cinema location and film selection allowed high-frequency measurement of human-emitted VOCs within a room flushed at a known rate so that emissions rates could be calculated for both adults and children. Gas-phase emission rates are analyzed as a function of time of day, variability during the film, and age of viewer. The average emission rates of CO 2 , acetone, and isoprene were lower (by a factor of ~1.2-1.4) for children under twelve compared to adults while for acetaldehyde emission rates were equivalent. Molecules influenced by exogenous sources such as decamethylcyclopentasiloxanes and methanol tended to decrease over the course of day and then rise for late evening screenings. These results represent average emission rates of people under real-world conditions and can be used in indoor air quality assessments and building design. Averaging over a large number of people generates emission rates that are less susceptible to individual behaviors. © 2017 The Authors. Indoor Air published by John Wiley & Sons Ltd.

Measurement of Fine Particles From Mobile and Stationary Sources, and Reducing the Air Conditioner Power Consumption in Hybrid Electric Vehicles

NASA Astrophysics Data System (ADS)

Brewer, Eli Henry

We study the PM2.5and ultrafine exhaust emissions from a new natural gas-fired turbine power facility to better understand air pollution in California. To characterize the emissions from new natural gas turbines, a series of tests were performed on a GE LMS100 gas turbine. These tests included PM2.5 and wet chemical tests for SO2/SO 3 and NH3, as well as ultrafine (less than 100 nm in diameter) particulate matter measurements. The turbine exhaust had an average particle number concentration that was 2.3x103 times higher than ambient air. The majority of these particles were nanoparticles; at the 100 nm size, stack particle concentrations were about 20 times higher than ambient, and increased to 3.9x104 times higher on average in the 2.5 - 3 nm particle size range. This study also found that ammonia emissions were higher than expected, but in compliance with permit conditions. This was possibly due to an ammonia imbalance entering the catalyst, some flue gas bypassing the catalyst, or not enough catalyst volume. SO3 accounted for an average of 23% of the total sulfur oxides emissions measured. Some of the SO3 is formed in the combustion process, it is likely that the majority formed as the SO2 in the combustion products passed across the oxidizing CO catalyst and SCR catalyst. The 100 MW turbine sampled in this study emitted particle loadings similar to those previously measured from turbines in the SCAQMD area, however, the turbine exhaust contained far more particles than ambient air. The power consumed by an air conditioner accounts for a significant fraction of the total power used by hybrid and electric vehicles especially during summer. This study examined the effect of recirculation of cabin air on power consumption of mobile air conditioners both in-lab and on-road. Real time power consumption and vehicle mileage were recorded by an On Board Diagnostic monitor and carbon balance method. Vehicle mileage improved with increased cabin air recirculation. The recirculation of cabin air also significantly reduced in-cabin particle concentrations. Recirculation of cabin air is an excellent and immediate solution to increase vehicle mileage and improve cabin air quality.

Regionalized life cycle impact assessment of air pollution on the global scale: Damage to human health and vegetation

NASA Astrophysics Data System (ADS)

van Zelm, Rosalie; Preiss, Philipp; van Goethem, Thomas; Van Dingenen, Rita; Huijbregts, Mark

2016-06-01

We developed regionalized characterization factors (CFs) for human health damage from particulate matter (PM2.5) and ozone, and for damage to vegetation from ozone, at the global scale. These factors can be used in the impact assessment phase of an environmental life cycle assessment. CFs express the overall damage of a certain pollutant per unit of emission of a precursor, i.e. primary PM2.5, nitrogen oxides (NOx), ammonia (NH3), sulfur dioxide (SO2) and non-methane volatile organic compounds (NMVOCs). The global chemical transport model TM5 was used to calculate intake fractions of PM2.5 and ozone for 56 world regions covering the whole globe. Furthermore, region-specific effect and damage factors were derived, using mortality rates, background concentrations and years of life lost. The emission-weighted world average CF for primary PM2.5 emissions is 629 yr kton-1, varying up to 3 orders of magnitude over the regions. Larger CFs were obtained for emissions in central Asia and Europe, and smaller factors in Australia and South America. The world average CFs for PM2.5 from secondary aerosols, i.e. NOx, NH3, and SO2, is 67.2 to 183.4 yr kton-1. We found that the CFs for ozone human health damage are 2-4 orders of magnitude lower compared to the CFs for damage due to primary PM2.5 and PM2.5 precursor emissions. Human health damage due to the priority air pollutants considered in this study was 1.7·10-2 yr capita-1 worldwide in year 2010, with primary PM2.5 emissions as the main contributor (62%). The emission-weighted world average CF for ecosystem damage due to ozone was 2.5 km2 yr kton-1 for NMVOCs and 8.7 m2 yr kg-1 for NOx emissions, varying 2-3 orders of magnitude over the regions. Ecosystem damage due to the priority air pollutants considered in this study was 1.6·10-4 km2 capita-1 worldwide in 2010, with NOx as the main contributor (72%). The spatial range in CFs stresses the importance of including spatial variation in life cycle impact assessment of priority air pollutants.

Hidden cost of U.S. agricultural exports: particulate matter from ammonia emissions.

PubMed

Paulot, Fabien; Jacob, Daniel J

2014-01-21

We use a model of agricultural sources of ammonia (NH3) coupled to a chemical transport model to estimate the impact of U.S. food export on particulate matter concentrations (PM2.5). We find that food export accounts for 11% of total U.S. NH3 emissions (13% of agricultural emissions) and that it increases the population-weighted exposure of the U.S. population to PM2.5 by 0.36 μg m(-3) on average. Our estimate is sensitive to the proper representation of the impact of NH3 on ammonium nitrate, which reflects the interplay between agricultural (NH3) and combustion emissions (NO, SO2). Eliminating NH3 emissions from food export would achieve greater health benefits than the reduction of the National Ambient Air Quality Standards for PM2.5 from 15 to 12 μg m(-3). Valuation of the increased premature mortality associated with PM2.5 from food export (36 billion US$ (2006) per year) amounts to 50% of the gross food export value. Livestock operations in densely populated areas have particularly large health costs. Decreasing SO2 and NOx emissions will indirectly reduce health impact of food export as an ancillary benefit.

NO2 and SO2 dispersion modeling and relative roles of emission sources over Map Ta Phut industrial area, Thailand.

PubMed

Chusai, Chatinai; Manomaiphiboon, Kasemsan; Saiyasitpanich, Phirun; Thepanondh, Sarawut

2012-08-01

Map Ta Phut industrial area (MA) is the largest industrial complex in Thailand. There has been concern about many air pollutants over this area. Air quality management for the area is known to be difficult, due to lack of understanding of how emissions from different sources or sectors (e.g., industrial, power plant, transportation, and residential) contribute to air quality degradation in the area. In this study, a dispersion study of NO2 and SO2 was conducted using the AERMOD model. The area-specific emission inventories of NOx and SO2 were prepared, including both stack and nonstack sources, and divided into 11 emission groups. Annual simulations were performed for the year 2006. Modeled concentrations were evaluated with observations. Underestimation of both pollutants was Jbund, and stack emission estimates were scaled to improve the modeled results before quantifying relative roles of individual emission groups to ambient concentration overfour selected impacted areas (two are residential and the others are highly industrialized). Two concentration measures (i.e., annual average area-wide concentration or AC, and area-wide robust highest concentration or AR) were used to aggregately represent mean and high-end concentrations Jbfor each individual area, respectively. For AC-NO2, on-road mobile emissions were found to be the largest contributor in the two residential areas (36-38% of total AC-NO2), while petrochemical-industry emissions play the most important role in the two industrialized areas (34-51%). For AR-NO2, biomass burning has the most influence in all impacted areas (>90%) exceptJor one residential area where on-road mobile is the largest (75%). For AC-SO2, the petrochemical industry contributes most in all impacted areas (38-56%). For AR-SO2, the results vary. Since the petrochemical industry was often identified as the major contributor despite not being the largest emitter, air quality workers should pay special attention to this emission group when managing air quality for the MA.

NO2 and SO2dispersion modeling and relative roles of emission sources over Map Ta Phut industrial area, Thailand.

PubMed

Chusai, Chatinai; Manomaiphiboon, Kasemsan; Saiyasitpanich, Phirun; Thepanondh, Sarawut

2012-08-01

Map Ta Phut industrial area (MA) is the largest industrial complex in Thailand. There has been concern about many air pollutants over this area. Air quality management for the area is known to be difficult, due to lack of understanding of how emissions from different sources or sectors (e.g., industrial, power plant, transportation, and residential) contribute to air quality degradation in the area. In this study, a dispersion study of NO 2 and SO 2 was conducted using the AERMOD model. The area-specific emission inventories of NO x and SO 2 were prepared, including both stack and nonstack sources, and divided into 11 emission groups. Annual simulations were performed for the year 2006. Modeled concentrations were evaluated with observations. Underestimation of both pollutants was found, and stack emission estimates were scaled to improve the modeled results before quantifying relative roles of individual emission groups to ambient concentration over four selected impacted areas (two are residential and the others are highly industrialized). Two concentration measures (i.e., annual average area-wide concentration or AC, and area-wide robust highest concentration or AR) were used to aggregately represent mean and high-end concentrations for each individual area, respectively. For AC-NO 2 , on-road mobile emissions were found to be the largest contributor in the two residential areas (36-38% of total AC-NO 2 ), while petrochemical-industry emissions play the most important role in the two industrialized areas (34-51%). For AR-NO 2 , biomass burning has the most influence in all impacted areas (>90%) except for one residential area where on-road mobile is the largest (75%). For AC-SO 2 , the petrochemical industry contributes most in all impacted areas (38-56%). For AR-SO 2 , the results vary. Since the petrochemical industry was often identified as the major contributor despite not being the largest emitter, air quality workers should pay special attention to this emission group when managing air quality for the MA. [Box: see text] [Box: see text].

Effects of emission reductions on organic aerosol in the southeastern United States

NASA Astrophysics Data System (ADS)

Blanchard, C. L.; Hidy, G. M.; Shaw, S.; Baumann, K.; Edgerton, E. S.

2015-06-01

Long-term (1999 to 2013) data from the Southeastern Aerosol Research and Characterization (SEARCH) network are used to characterize the effects of anthropogenic emission reductions on fine particle organic aerosol (OA) concentrations in the southeastern US. On average, 45 % (range 25 to 63 %) of the 1999 to 2013 mean organic carbon (OC) concentrations are attributed to combustion processes, including fossil-fuel use and biomass burning, through associations of measured OC with combustion products such as elemental carbon (EC), carbon monoxide (CO), and nitrogen oxides (NOx). The 2013 mean combustion-derived OC concentrations were 0.5 to 1.4 μg m-3 at the five sites operating in that year. Mean annual combustion-derived OC concentrations declined from 3.8 ± 0.2 μg m-3 (68 % of total OC) to 1.4 ± 0.1 μg m-3 (60 % of total OC) between 1999 and 2013 at the urban Atlanta, Georgia, site (JST) and from 2.9 ± 0.4 μg m-3 (39 % of total OC) to 0.7 ± 0.1 μg m-3 (30 % of total OC) between 2001 and 2013 at the urban Birmingham, Alabama, site (BHM). The urban OC declines coincide with reductions of motor-vehicle emissions between 2006 and 2010, which may have decreased mean OC concentrations at the urban SEARCH sites by > 2 μg m-3. BHM additionally exhibits a decline in OC associated with SO2 from 0.4 ± 0.04 μg m-3 in 2001 to 0.2 ± 0.03 μg m-3 in 2013, interpreted as the result of reduced emissions from industrial sources within the city. Analyses using non-soil potassium as a biomass-burning tracer indicate that biomass-burning OC occurs throughout the year at all sites. All eight SEARCH sites show an association of OC with sulfate (SO4) ranging from 0.3 to 1.0 μg m-3 on average, representing ~ 25 % of the 1999 to 2013 mean OC concentrations. Because the mass of OC associated with SO4 averages 20 to 30 % of the SO4 concentrations, the mean SO4-associated OC declined by ~ 0.5 to 1 μg m-3 as SO4 decreased throughout the SEARCH region. The 2013 mean SO4 concentrations of 1.7 to 2.0 μg m-3 imply that future decreases in mean SO4-associated OC concentrations would not exceed ~ 0.3 to 0.5 μg m-3. Seasonal OC concentrations, largely associated with ozone (O3), vary from 0.3 to 1.4 μg m-3 (~ 20 % of the total OC concentrations).

Effects of emission reductions on organic aerosol in the southeastern United States

NASA Astrophysics Data System (ADS)

Blanchard, C. L.; Hidy, G. M.; Shaw, S.; Baumann, K.; Edgerton, E. S.

2016-01-01

Long-term (1999 to 2013) data from the Southeastern Aerosol Research and Characterization (SEARCH) network are used to show that anthropogenic emission reductions led to important decreases in fine-particle organic aerosol (OA) concentrations in the southeastern US On average, 45 % (range 25 to 63 %) of the 1999 to 2013 mean organic carbon (OC) concentrations are attributed to combustion processes, including fossil fuel use and biomass burning, through associations of measured OC with combustion products such as elemental carbon (EC), carbon monoxide (CO), and nitrogen oxides (NOx). The 2013 mean combustion-derived OC concentrations were 0.5 to 1.4 µg m-3 at the five sites operating in that year. Mean annual combustion-derived OC concentrations declined from 3.8 ± 0.2 µg m-3 (68 % of total OC) to 1.4 ± 0.1 µg m-3 (60 % of total OC) between 1999 and 2013 at the urban Atlanta, Georgia, site (JST) and from 2.9 ± 0.4 µg m-3 (39 % of total OC) to 0.7 ± 0.1 µg m-3 (30 % of total OC) between 2001 and 2013 at the urban Birmingham, Alabama (BHM), site. The urban OC declines coincide with reductions of motor vehicle emissions between 2006 and 2010, which may have decreased mean OC concentrations at the urban SEARCH sites by > 2 µg m-3. BHM additionally exhibits a decline in OC associated with SO2 from 0.4 ± 0.04 µg m-3 in 2001 to 0.2 ± 0.03 µg m-3 in 2013, interpreted as the result of reduced emissions from industrial sources within the city. Analyses using non-soil potassium as a biomass burning tracer indicate that biomass burning OC occurs throughout the year at all sites. All eight SEARCH sites show an association of OC with sulfate (SO4) ranging from 0.3 to 1.0 µg m-3 on average, representing ˜ 25 % of the 1999 to 2013 mean OC concentrations. Because the mass of OC identified with SO4 averages 20 to 30 % of the SO4 concentrations, the mean SO4-associated OC declined by ˜ 0.5 to 1 µg m-3 as SO4 concentrations decreased throughout the SEARCH region. The 2013 mean SO4 concentrations of 1.7 to 2.0 µg m-3 imply that future decreases in mean SO4-associated OC concentrations would not exceed ˜ 0.3 to 0.5 µg m-3. Seasonal OC concentrations, largely identified with ozone (O3), vary from 0.3 to 1.4 µg m-3 ( ˜ 20 % of the total OC concentrations).

Greenhouse gas and air pollutant emissions from land and forest fire in Indonesia during 2015 based on satellite data

NASA Astrophysics Data System (ADS)

Pribadi, A.; Kurata, G.

2017-01-01

Land and forest fire still become a major problem in environmental management in Indonesia. In this study, we conducted quantitatively assessment of land and forest fire emissions in Indonesia during 2015. We applied methodology of emission inventory based on burned area, biomass density, combustion factor and emission factor for each land cover type using several satellite data such as MODIS burned area, Pantropical National Level Carbon Stock Dataset, as well as Vegetation Condition Index. The greenhouse gases emissions from land and forest fire in Indonesia during 2015 were (in Gg) 806,406 CO2, 8,002 CH4, 96 N2O, while pollutants emissions were (in Gg) 85,268 CO, 1,168 NOx, 340 SO2, 3,093 NMVOC, 1,041 NH3, 259 BC, 1,957 OC, 4,118 PM2.5 and 5,468 PM10. September was the peak of fire season that generate 58% (species average) of total emissions for this year. The largest contribution was from shrubland/savanna burning which account for 66% (species average) of the total emissions, while about 81% of the total emissions were generated from peatland fire. The results of this study emphasizethe importance of proper peatland management in Indonesia as land and forest fire countermeasures strategy.

Investigation of gaseous and particulate emissions from various marine vessel types measured on the banks of the Elbe in Northern Germany

NASA Astrophysics Data System (ADS)

Diesch, J.-M.; Drewnick, F.; Klimach, T.; Borrmann, S.

2013-04-01

Measurements of the ambient aerosol, various trace gases and meteorological quantities using a mobile laboratory (MoLa) were performed on the banks of the Lower Elbe in an emission control area (ECA) which is passed by numerous private and commercial marine vessels reaching and leaving the port of Hamburg, Germany. From 25-29 April 2011 a total of 178 vessels were probed at a distance of about 0.8-1.2 km with high temporal resolution. 139 ship emission plumes were of sufficient quality to be analyzed further and to determine emission factors (EFs). Concentrations of aerosol number and mass as well as polycyclic aromatic hydrocarbons (PAH) and black carbon were measured in PM1 and size distribution instruments covered the diameter range from 6 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase species analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) in the air and a weather station provided wind, precipitation, solar radiation data and other quantities. Together with ship information for each vessel obtained from Automatic Identification System (AIS) broadcasts a detailed characterization of the individual ship types and of features affecting gas and particulate emissions is provided. Particle number EFs (average 2.6e+16 # kg-1) and PM1 mass EFs (average 2.4 g kg-1) tend to increase with the fuel sulfur content. Observed PM1 composition of the vessel emissions was dominated by organic matter (72%), sulfate (22%) and black carbon (6%) while PAHs only account for 0.2% of the submicron aerosol mass. Measurements of gaseous components showed an increase of SO2 (average EF: 7.7 g kg-1) and NOx (average EF: 53 g kg-1) while O3 decreased when a ship plume reached the sampling site. The particle number size distributions of the vessels are generally characterized by a bimodal size distribution, with the nucleation mode in the 10-20 nm diameter range and a combustion aerosol mode centered at about 35 nm while particles > 1 μm were not found. "High particle number emitters" are characterized by a dominant nucleation mode. By contrast, increased particle concentrations around 150 nm primarily occurred for "high black carbon emitters". Classifying the vessels according to their gross tonnage shows a decrease of the number, black carbon and PAH EFs while EFs of SO2, NO, NO2, NOx, AMS species (particulate organics, sulfate) and PM1 mass concentration increase with increasing gross tonnages.

Investigation of gaseous and particulate emissions from various marine vessel types measured on the banks of the Elbe in Northern Germany

NASA Astrophysics Data System (ADS)

Diesch, J.-M.; Drewnick, F.; Klimach, T.; Borrmann, S.

2012-08-01

Measurements of the ambient aerosol, various trace gases and meteorological parameters using a mobile laboratory (MoLa) were performed on the banks of the Lower Elbe in an emission control area (ECA) which is passed by numerous private and commercial marine vessels reaching and leaving the port of Hamburg, Germany. From 25-30 April 2011 a total of 178 vessels were probed at a distance of about 0.8-2 km with high temporal resolution. 139 ship emission plumes were of sufficient quality to be analyzed further and to determine emission factors (EFs). Concentrations of aerosol number and mass as well as polycyclic aromatic hydrocarbons (PAH) and black carbon were measured in PM1 and size distribution instruments covered the size diameter range from 6 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase species analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) in the air and a weather station provided wind, precipitation, solar radiation and other parameters. Together with ship information for each vessel obtained from Automatic Identification System (AIS) broadcasts a detailed characterization of the individual ship types and of features affecting gas and particulate emissions is provided. Particle number EFs (average 2.6×1016 # kg -1) and PM1 mass EFs (average 2.4 g kg -1) positively correlate with the fuel sulfur content and depend on the engine type and performance. Observed PM1 composition of the vessel emissions was dominated by organic matter (72%), sulfate (22%) and black carbon (6%) while PAHs only account for 0.2% of the submicron aerosol mass. Measurements of gaseous components showed an increase of SO2 (average EF: 7.7 g kg-1) and NOx (average EF: 53 g kg-1) while O3 decreased when a ship plume reached the sampling site. The particle number size distributions of the vessels are generally characterized by a bimodal size distribution, with the nucleation mode in the 10-20 nm diameter range and a combustion aerosol mode centered at about 35 nm while particles >1 μm were not found. "High particle number emitters" are characterized by a dominant nucleation mode. By contrast, a third weaker mode at 150 nm primarily occurred for "high black carbon emitters". Classifying the vessels according to their gross tonnage shows a decrease of the number, black carbon and PAH EFs while EFs of SO2, NO, NO2, NOx, AMS species (particulate organics, sulfate) and PM1 mass concentration increase with increasing gross tonnages.

Sulfur dioxide and primary carbonaceous aerosol emissions in China and India, 1996-2010

NASA Astrophysics Data System (ADS)

Lu, Z.; Zhang, Q.; Streets, D. G.

2011-09-01

China and India are the two largest anthropogenic aerosol generating countries in the world. In this study, we develop a new inventory of sulfur dioxide (SO2) and primary carbonaceous aerosol (i.e., black and organic carbon, BC and OC) emissions from these two countries for the period 1996-2010, using a technology-based methodology. Emissions from major anthropogenic sources and open biomass burning are included, and time-dependent trends in activity rates and emission factors are incorporated in the calculation. Year-specific monthly temporal distributions for major sectors and gridded emissions at a resolution of 0.1°×0.1° distributed by multiple year-by-year spatial proxies are also developed. In China, the interaction between economic development and environmental protection causes large temporal variations in the emission trends. From 1996 to 2000, emissions of all three species showed a decreasing trend (by 9 %-17 %) due to a slowdown in economic growth, a decline in coal use in non-power sectors, and the implementation of air pollution control measures. With the economic boom after 2000, emissions from China changed dramatically. BC and OC emissions increased by 46 % and 33 % to 1.85 Tg and 4.03 Tg in 2010. SO2 emissions first increased by 61 % to 34.0 Tg in 2006, and then decreased by 9.2 % to 30.8 Tg in 2010 due to the wide application of flue-gas desulfurization (FGD) equipment in power plants. Driven by the remarkable energy consumption growth and relatively lax emission controls, emissions from India increased by 70 %, 41 %, and 35 % to 8.81 Tg, 1.02 Tg, and 2.74 Tg in 2010 for SO2, BC, and OC, respectively. Monte Carlo simulations are used to quantify the emission uncertainties. The average 95 % confidence intervals (CIs) of SO2, BC, and OC emissions are estimated to be -16 %-17 %, -43 %-93 %, and -43 %-80 % for China, and -15 %-16 %, -41 %-87 %, and -44 %-92 % for India, respectively. Sulfur content, fuel use, and sulfur retention of hard coal and the actual FGD removal efficiency are the main contributors to the uncertainties of SO2 emissions. Biofuel combustion related parameters (i.e., technology divisions, fuel use, and emission factor determinants) are the largest source of OC uncertainties, whereas BC emissions are also sensitive to the parameters of coal combustion in the residential and industrial sectors and the coke-making process. Comparing our results with satellite observations, we find that the trends of estimated emissions in both China and India are in good agreement with the trends of aerosol optical depth (AOD) and SO2 retrievals obtained from different satellites.

Sulfur dioxide and primary carbonaceous aerosol emissions in China and India, 1996-2010

NASA Astrophysics Data System (ADS)

Lu, Z.; Streets, D. G.

2011-07-01

China and India are the two largest anthropogenic aerosol generating countries in the world. In this study, we develop a new inventory of sulfur dioxide (SO2) and primary carbonaceous aerosol (i.e., black and organic carbon, BC and OC) emissions from these two countries for the period 1996-2010, using a technology-based methodology. Emissions from major anthropogenic sources and open biomass burning are included, and time-dependent trends in activity rates and emission factors are incorporated in the calculation. Year-specific monthly fractions for major sectors and gridded emissions at a resolution of 0.1° × 0.1° distributed by multiple year-by-year spatial proxies are also developed. In China, the interaction between economic development and environmental protection causes large temporal variations in the emission trends. From 1996 to 2000, emissions of all three species showed a decreasing trend (by 9 %-17 %) due to a slowdown in economic growth, a decline in coal use in non-power sectors, and the implementation of air pollution control measures. With the economic boom after 2000, emissions from China changed dramatically. BC and OC emissions increased by 46 % and 33 % to 1.85 Tg and 4.03 Tg in 2010. SO2 emissions first increased by 61 % to 34.0 Tg in 2006, and then decreased by 9.2 % to 30.8 Tg in 2010 due to the wide application of flue-gas desulfurization (FGD) equipment in power plants. Driven by the remarkable energy consumption growth and relatively lax emission controls, emissions from India increased by 70 %, 41 %, and 35 % to 8.81 Tg, 1.02 Tg, and 2.74 Tg in 2010 for SO2, BC, and OC, respectively. Monte Carlo simulations are used to quantify the emission uncertainties. The average 95 % confidence intervals (CIs) of SO2, BC, and OC emissions are estimated to be -16 %-17 %, -43 %-93 %, and -43 %-80 % for China, and -15 %-16 %, -41 %-87 %, and -44 %-92 % for India, respectively. Sulfur content, fuel use, and sulfur retention of hard coal and the actual FGD removal efficiency are the main contributors to the uncertainties of SO2 emissions. Biofuel combustion related parameters (i.e., technology divisions, fuel use, and emission factor determinants) are the largest source of OC uncertainties, whereas BC emissions are also sensitive to the parameters of coal combustion in the residential and industrial sectors and the coke-making process. Comparing our results with satellite observations, we find that the trends of estimated emissions in both China and India are in good agreement with the trends of aerosol optical depth (AOD) and SO2 retrievals obtained from different satellites.

Spatially Refined Aerosol Direct Radiative Forcing Efficiencies

NASA Technical Reports Server (NTRS)

Henze, Daven K.; Shindell, Drew Todd; Akhtar, Farhan; Spurr, Robert J. D.; Pinder, Robert W.; Loughlin, Dan; Kopacz, Monika; Singh, Kumaresh; Shim, Changsub

2012-01-01

Global aerosol direct radiative forcing (DRF) is an important metric for assessing potential climate impacts of future emissions changes. However, the radiative consequences of emissions perturbations are not readily quantified nor well understood at the level of detail necessary to assess realistic policy options. To address this challenge, here we show how adjoint model sensitivities can be used to provide highly spatially resolved estimates of the DRF from emissions of black carbon (BC), primary organic carbon (OC), sulfur dioxide (SO2), and ammonia (NH3), using the example of emissions from each sector and country following multiple Representative Concentration Pathway (RCPs). The radiative forcing efficiencies of many individual emissions are found to differ considerably from regional or sectoral averages for NH3, SO2 from the power sector, and BC from domestic, industrial, transportation and biomass burning sources. Consequently, the amount of emissions controls required to attain a specific DRF varies at intracontinental scales by up to a factor of 4. These results thus demonstrate both a need and means for incorporating spatially refined aerosol DRF into analysis of future emissions scenario and design of air quality and climate change mitigation policies.

Long-term (2005-2015) trend analysis of PM2.5 precursor gas NO2 and SO2 concentrations in Taiwan.

PubMed

Lee, Chih-Sheng; Chang, Ken-Hui; Kim, Hyunook

2018-05-26

Ground air monitoring stations have been installed in Taiwan since 1993 to ensure whether the criteria air pollutants meet the ambient air quality standards. In the present study, the data from the monitoring stations were used to evaluate long-term (2005-2015) trend of NO 2 and SO 2 in three metropolitan cities (northern Taipei, central Taichung, and southern Kaohsiung), two eastern coastal cities (Hualien and Taitung), and one agricultural city in west-central plain (Douliu); those cities essentially covered the entire region of Taiwan. The results indicate that SO 2 and NO 2 concentrations of all studied six cities meet the annual average standards of 30 and 50 ppb, respectively. After deseasonalizing the original data and using 7-month moving average, the trend analysis reveals a decreasing trend ranging from 0.15 to 0.57 ppb/year (R 2 from 0.33 to 0.85) for NO 2 and 0.06 to 0.45 ppb/year (R 2 from 0.32 to 0.92) for SO 2 ; the corresponding reductions over the 10-year span are 4 to 42% for NO 2 and 22 to 52% for SO 2 . The reduction trend, despite the growth in GDP, vehicle numbers and energy consumption, industrial output, etc., is similar to those of developed countries. Clearly, there are seasonal/monthly variation patterns for these two precursor gases with minimum levels in summer (July) and maximum in winter (December). The concentration reductions, however, were lagging behind the respective emission reductions. There are significant correlations among six cites for NO 2 (r = 0.58-0.93) and, to some extent, SO 2 (0.32-0.66). The correlation between SO 2 and NO 2 (r = 0.46-0.74) indicates same or similar emission sources. Furthermore, the correlation between observed pollutant concentrations and their emission is excellent for SO 2 in two cities (0.79-0.96). The SO 2 /NO 2 ratios vary with city and time and the value is site specific. For example, in 2005, the SO 2 /NO 2 ratio was 0.38 in Kaohsiung and 0.18 in both Taipei and Taichung, the latter reflecting significant contribution from mobile sources. However, they all converged to 0.18-0.28 in 2015 in the six cities evaluated. All in all, the policies/measures made by the central and local government are effective in reducing ambient SO 2 and NO 2 levels.

A predictive analysis of CO2 emissions, environmental policy stringency, and economic growth in China.

PubMed

Ahmed, Khalid; Ahmed, Sidrah

2018-03-28

This study takes environmental policy stringency and economic activity as the controlling variables and forecasts the CO 2 emissions in China up to 2022. In doing so, an application of corrected grey model with convolution is used over the annual time series data between 1990 and 2012. The simulation results show that (1) between 2012 and 2022, CO 2 emissions in China is expected to increase at an average rate of 17.46% annually, raising the emissions intensity from 7.04 in 2012 to 25.461 metric tons per capita by 2022; (2) stringent environmental policies reduce CO 2 emissions-whereas, GDP tends to increase the emissions intensity in China; (3) stringent environmental policies are found to have a negative impact on GDP in China. Based on the empirical findings, the study also provides some policy suggestions to reduce emissions intensity in China.

Scanning and mobile multi-axis DOAS measurements of SO2 and NO2 emissions from an electric power plant in Montevideo, Uruguay

NASA Astrophysics Data System (ADS)

Frins, E.; Bobrowski, N.; Osorio, M.; Casaballe, N.; Belsterli, G.; Wagner, T.; Platt, U.

2014-12-01

In March 2012 the emissions of NO2 and SO2 from a power station located on the east side of Montevideo Bay (34° 53‧ 10″ S, 56° 11‧ 49″ W) were quantified by simultaneously using mobile and scanning multi-axis differential optical absorption spectroscopy (in the following mobile DOAS and scanning DOAS, respectively). The facility produces electricity by means of two technologies: internal combustion motors and steam generators. The motors are powered with centrifuged heavy oil and produce a maximum power of 80 MW approximately. The steam generators produce approximately 305 MW and are powered with heavy fuel oil. We compare the emissions obtained from the measured slant column densities (mobile DOAS and scanning DOAS) with the emissions estimated from fuel mass balance. On one occasion it was possible to distinguish between the two types of sources, observing two plumes with different SO2 and NO2 emission rates. During the period of the campaign the mean SO2 emission flux was determined to be 0.36 (±0.12) kg s-1 and 0.26 (±0.09) kg s-1 retrieved from mobile and scanning DOAS respectively, while the calculated SO2 flux from the sulphur content of the fuel was 0.34 (±0.03) kg s-1. The average NO2 flux calculated from mobile DOAS was determined to be 11 (±3) × 10-3 kg s-1. Using the scanning DOAS approach a mean NO2 flux of 5.4 (±1.7) × 10-3 kg s-1 was obtained, which is significantly lower than by the mobile measurements. The differences between the results of mobile MAX-DOAS measurements and scanning DOAS measurements are most probably caused by the variability and the limited knowledge of the wind speed and direction.

Long-term variation of the source of sulfate deposition in a leeward area of Asian continent in view of sulfur isotopic composition

NASA Astrophysics Data System (ADS)

Ohizumi, Tsuyoshi; Take, Naoko; Inomata, Yayoi; Yagoh, Hiroaki; Endo, Tomomi; Takahashi, Masaaki; Yanahara, Kazuki; Kusakabe, Minoru

2016-09-01

A large emission of air pollutants from the Asian continent has caused transboundary air pollution, especially in northeastern Asia. This paper evaluates sulfate deposition at a leeward area of Asian continent, i.e., the Nagaoka observation station located along the Sea of Japan. We have monitored atmospheric sulfate deposition and its sulfur isotopic ratio for 28 years at the station. The sulfur isotopic ratios of non-sea-salt sulfate (δ34Snss) ranged from 0.0 to +6.2‰. The isotopic ratios of local emission and Chinese coal sulfur showed negative and positive values, respectively. Several statistically significant trends were detected on the deposition of non-sea-salt sulfate (nss-SO42-) during the study period. The decrease of nss-SO42- deposition since the middle of 1980s was considered to have been caused by local anthropogenic SO2 emission that showed relatively low δ34Snss values during the period. The increase of nss-SO42- deposition from the end of 1990s to the second half of 2000s was interpreted to have been caused by the change in SO2 emission in China because the δ34Snss values increased during the period with the winter values getting closer to the averaged value of Chinese coal sulfur. The decreasing trend of nss-SO42- deposition from the middle of 2000s was likely affected by reduction of Chinese SO2 emission judging from the decrease in δ34Snss values in the period. Mass balance calculations suggested that sulfur released by coal combustion in China during 1990s contributed by about 40% of annual total sulfur deposition in Nagaoka, and its contribution increased up to 60% in the middle of 2000s. The contribution turned to decrease after that peak, which was in harmony with the temporal change of emission from China.

Application of OMI, SCIAMACHY and GOME-2 Satellite SO2 Retrievals for Detection of Large Emission Sources

NASA Technical Reports Server (NTRS)

Fioletov, V.E.; McLinden, C. A.; Krotkov, N.; Yang, K.; Loyola, D. G.; Valks, P.; Theys, N.; Van Roozendael, M.; Nowlan, C. R.; Chance, K.;

SO2 Emissions in China - Their Network and Hierarchical Structures.

PubMed

Yan, Shaomin; Wu, Guang

2017-04-07

SO 2 emissions lead to various harmful effects on environment and human health. The SO 2 emission in China has significant contribution to the global SO 2 emission, so it is necessary to employ various methods to study SO 2 emissions in China with great details in order to lay the foundation for policymaking to improve environmental conditions in China. Network analysis is used to analyze the SO 2 emissions from power generation, industrial, residential and transportation sectors in China for 2008 and 2010, which are recently available from 1744 ground surface monitoring stations. The results show that the SO 2 emissions from power generation sector were highly individualized as small-sized clusters, the SO 2 emissions from industrial sector underwent an integration process with a large cluster contained 1674 places covering all industrial areas in China, the SO 2 emissions from residential sector was not impacted by time, and the SO 2 emissions from transportation sector underwent significant integration. Hierarchical structure is obtained by further combining SO 2 emissions from all four sectors and is potentially useful to find out similar patterns of SO 2 emissions, which can provide information on understanding the mechanisms of SO 2 pollution and on designing different environmental measure to combat SO 2 emissions.

SO2 Emissions in China – Their Network and Hierarchical Structures

PubMed Central

Yan, Shaomin; Wu, Guang

2017-01-01

SO2 emissions lead to various harmful effects on environment and human health. The SO2 emission in China has significant contribution to the global SO2 emission, so it is necessary to employ various methods to study SO2 emissions in China with great details in order to lay the foundation for policymaking to improve environmental conditions in China. Network analysis is used to analyze the SO2 emissions from power generation, industrial, residential and transportation sectors in China for 2008 and 2010, which are recently available from 1744 ground surface monitoring stations. The results show that the SO2 emissions from power generation sector were highly individualized as small-sized clusters, the SO2 emissions from industrial sector underwent an integration process with a large cluster contained 1674 places covering all industrial areas in China, the SO2 emissions from residential sector was not impacted by time, and the SO2 emissions from transportation sector underwent significant integration. Hierarchical structure is obtained by further combining SO2 emissions from all four sectors and is potentially useful to find out similar patterns of SO2 emissions, which can provide information on understanding the mechanisms of SO2 pollution and on designing different environmental measure to combat SO2 emissions. PMID:28387301

Long-term effects of contrasting tillage on soil organic carbon, nitrous oxide and ammonia emissions in a Mediterranean Vertisol under different crop sequences.

PubMed

Badagliacca, Giuseppe; Benítez, Emilio; Amato, Gaetano; Badalucco, Luigi; Giambalvo, Dario; Laudicina, Vito Armando; Ruisi, Paolo

2018-04-01

This 2-year study aimed to verify whether the continuous application of no tillage (NT) for over 20years, in comparison with conventional tillage (CT), affects nitrous oxide (N 2 O) and ammonia (NH 3 ) emissions from a Vertisol and, if so, whether such an effect varies with crop sequence (continuous wheat, WW and wheat after faba bean, FW). To shed light on the mechanisms involved in determining N-gas emissions, soil bulk density, water filled pore space (WFPS), some carbon (C) and nitrogen (N) pools, denitrifying enzyme activity (DEA), and nitrous oxide reductase gene abundance (nosZ gene) were also assessed at 0-15 and 15-30cm soil depth. Tillage system had no significant effect on total NH 3 emissions. On average, total N 2 O emissions were higher under NT (2.45kgN 2 O-Nha -1 ) than CT (1.72kgN 2 O-Nha -1 ), being the differences between the two tillage systems greater in FW than WW. The higher N 2 O emissions in NT treatments were ascribed to the increased bulk density, WFPS, and extractable organic C under NT compared to CT, all factors that generally promote the production of N 2 O. Moreover, compared to CT, NT enhanced the potential DEA (114 vs 16μgNkg -1 h -1 ) and nosZ gene abundance (116 vs 69 copy number mg -1 dry soil) in the topsoil. Finally, NT compared to CT led to an average annual increase in C stock of 0.70MgCha -1 year -1 . Though NT can increase the amount os soil organic matter so storing CO 2 into soil, some criticisms related to the increase of N 2 O emission arise, thereby suggesting the need for defining management strategies to mitigate such a negative effect. Copyright © 2017 Elsevier B.V. All rights reserved.

[Simulation of air pollution characteristics and estimates of environmental capacity in Zibo City].

PubMed

Xue, Wen-Bo; Wang, Jin-Nan; Yang, Jin-Tian; Lei, Yu; Yan, Li; He, Jin-Yu; Han, Bao-Ping

2013-04-01

To develop a new pattern of air pollution control that is based on the integration of "concentration control, total amount control, and quality control", and in the context of developing national (2011-2015 air pollution control plan for key areas) and (Environmental protection plan of Zibo municipality for the "12th Five-Year Plan" period), a simulation of atmospheric dispersion of air pollutants in Zibo City and its peripheral areas is carried out by employing CALPUFF model, and the atmospheric environmental capacity of SO2, NO(x) and PM10 is estimated based on the results of model simulation and using multi-objective linear programming optimization. The results indicates that the air pollution in Zibo City is significantly related to the pollution sources outside of Zibo City, which contributes to the annual average concentration of SO2, NO2 and PM10 in Zibo City by 26.34%, 21.23%, and 14.58% respectively. There is a notable interaction between districts and counties of Zibo municipality, in which the contribution of SO2, NO(x) and PM10 emissions in surrounding counties and districts to the annual average concentrations of SO2, NO2 and PM10 in downtown area are 35.96%, 43.17%, and 17.69% respectively. There is a great variation in spatial sensitivity of air pollutant emission, and the environmental impact of unit pollutant emissions from Zhoucun, Huantai, Zhangdian and Zichuan is greater than that released from other districts/counties. To meet the requirement of (Ambient air quality standard) (GB 3095-2012), the environmental capacities of SO2, NO(x) and PM10 of Zibo City are only 8.03 x 10(4) t, 19.16 x 10(4) t and 3.21 x 10(4) t, respectively. Therefore, it is imperative to implement regional air pollution joint control in Shandong peninsula in order to ensure the achievement of air quality standard in Zibo City.

PM2.5 and gaseous pollutants in New York State during 2005-2016: Spatial variability, temporal trends, and economic influences

NASA Astrophysics Data System (ADS)

Squizzato, Stefania; Masiol, Mauro; Rich, David Q.; Hopke, Philip K.

2018-06-01

Over the past decades, mitigation strategies have been adopted both by federal and state agencies in the United States (US) to improve air quality. Between 2007 and 2009, the US faced a financial/economic crisis that lowered activity and reduced emissions. At the same time, changes in the prices of coal and natural gas drove a shift in fuels used for electricity generation. Seasonal patterns, diel cycles, spatial gradients, and trends in PM2.5 and gaseous pollutants concentrations (NOx, SO2, CO and O3) monitored in New York State (NYS) from 2005 to 2016 were examined. Relationships between ambient concentrations, changes in NYS emissions retrieved from the US EPA trends inventory, and economic indicators were studied. PM2.5 and primary gaseous pollutants concentrations decreased across NYS. By 2016, PM2.5 and SO2 attained relatively homogeneous concentrations across the state. PM2.5 concentrations decreased significantly at all sites. Similarly, SO2 concentrations declined at all sites within this period, with the highest slopes observed at the urban sites. Reductions in NOx emissions likely contributed to summertime average ozone reductions. NOx and VOCs controls reduced O3 peak concentrations as seen in significant relationships between the annual O3 4th-highest daily maximum 8-h concentrations and estimated NOx emissions at rural and suburban sites (r2 ∼ 0.7). Spring maxima were not reduced with most sites showing insignificant slopes or significant positive slopes (e.g., +2.6% y-1 and +2% y-1, at CCNY and PFI, respectively). Increases in autumn and winter ozone concentrations were found (e,g., 6.6 ± 0.4% y-1 on average in New York City). Significant relationships were observed between PM2.5, primary pollutants, and economic indicators. Overall, a decrease in electricity generation with coal, and the simultaneous increase in natural gas consumption for power generation, led to a decrease in PM2.5 and gaseous pollutants concentrations.

Kilauea's double eruption, 2008-2016: volatile budget and associated hazards

NASA Astrophysics Data System (ADS)

Sutton, A. J.; Elias, T.

2016-12-01

After 20 years of effusive behavior on Kilauea's East Rift Zone, a surge in magma supply brought about eruptive changes that significantly improved our understanding of volcanic processes and associated hazards. The volcano's summit deformation changes and increase in CO2 emissions signaled the supply surge beginning in 2003, and heralded the opening of the Overlook Vent in 2008. Along with the supply surge and vent opening came a dramatic spike in gas release. Summit SO2 emissions climbed from 0.2 kt/d to over 10 kt/d while East Rift discharge rose from 2 kt/d to about 6 kt/d before both summit and rift emissions began an overall decline in late 2008. In spite of the emissions decline, however, overall gas release from Kilauea remained well above the previous 20-year average through early 2014. Beginning in 2008, the annual gas budget released from the summit and rift combined, was more than 830 kt, 6.7 kt, and 3.7 kt of SO2, HCl, and HF, respectively. Effects of these elevated emissions sustained ongoing human health concerns and caused a multi-year agricultural disaster designation for the Island. The current activity of Kīlauea consists of a predominant summit gas eruption (where lava and ash discharge are trivial compared to gas release) and a more typical rift lava eruption with sufficient lava effusion to reach a community 20 km from the eruptive vent. An updated gas-based lava effusion estimate shows that Kilauea continued to erupt an average of 0.11 km^3 yr^-1 of dense rock equivalent lava between early 2012 and mid-2016. This value shows that despite the new regime of erupting most of its gas budget at the volcano's summit, the Kilauea system is still capable of pushing magma out of its rift at a rate consistent with the long term average.

[A study on city motor vehicle emission factors by tunnel test].

PubMed

Wang, B; Zhang, Y; Zhu, C; Yu, K; Chan, L; Chan, Z

2001-03-01

Applying the principle of tunnel test to run a typical across-river tunnel test in Guangzhou city, 48 h-online-monitor data include pollutant concentration, traffic activity and meteorological data were gained. The average motor vehicle emission factors of NOx, CO, SO2, PM10 and HC were calculated using mass balance which are 1.379, 15.404, 0.142, 0.637, 1.857 g/km. vehicle respectively. Based on that, combined emission factors of 8 types of city vehicles were calculated using linear regression. The result basically showed the character and level of motor vehicle emission in Chinese city.

The impact of anthropogenic emissions and meteorological conditions on the spatial variation of ambient SO2 concentrations: A panel study of 113 Chinese cities.

PubMed

Yang, Xue; Wang, Shaojian; Zhang, Wenzhong; Zhan, Dongsheng; Li, Jiaming

2017-04-15

China has received increased international criticism in recent years in relation to its air pollution levels, both in terms of the transmission of pollutants across international borders and the attendant adverse health effects being witnessed. Whilst existing research has examined the factors influencing ambient air pollutant concentrations, previous studies have failed to adequately explore the determinants of such concentrations from either a source or diffusion perspective. This study addressed both source (specifically, anthropogenic emissions) and diffusion (namely, meteorological conditions) indicators, in order to detect their respective impacts on the spatial variations seen in the distribution of air pollution. Spatial panel data for 113 major cities in China was processed using a range of global regression models-the ordinary least square model, the spatial lag model, and the spatial error model-as well as a local, geographic weighted regression (GWR) model. Results from the study suggest that in 2014, average SO 2 concentrations exceeded China's first-level target. The most polluted cities were found to be predominantly located in northern China, while less polluted cities were located in southern China. Global regression results indicated that precipitation exerts a significant effect on SO 2 reduction (p<0.001) and that a regional increase of 1mm in precipitation can reduce SO 2 concentrations by 0.026μg/m 3 . Both emission and temperature factors were found to aggravate SO 2 concentrations, although no such significant correlation was found in relation to wind speed. GWR results suggest that the association between SO 2 and its factors varied over space. Increased emissions were found to be able to produce more pollution in the northwest than in other parts of the country. Higher wind speeds and temperatures in northwestern areas were shown to reinforce SO 2 pollution, while in southern regions, they had the opposite effect. Further, increased precipitation was found to exert a greater inhibitory effect on SO 2 pollution in the country's northeast than that in other areas. Our findings could provide a detailed reference for formulating regionally specific emission reduction policies in China. Copyright © 2016 Elsevier B.V. All rights reserved.

Volcanoes as emission sources of atmospheric mercury in the Mediterranean basin

PubMed

Ferrara; Mazzolai; Lanzillotta; Nucaro; Pirrone

2000-10-02

Emissions from volcanoes, fumaroles and solfataras as well as contributions from widespread geological anomalies could represent an important source of mercury released to the atmosphere in the Mediterranean basin. Volcanoes located in this area (Etna, Stromboli and Vulcano) are the most active in Europe; therefore, it is extremely important to know their mercury contributions to the regional atmospheric budget. Two main methods are used for the evaluation of volcanic mercury flux: a direct determination of the flux (by measuring in the plume) and an indirect one derived from the determination of the Hg/SO2 (or Hg/S) ratio value, as SO2 emissions are constantly monitored by volcanologists. An attempt to estimate mercury flux from the Vulcano volcano and to establish the Hg/S ratio value has been made along three field campaigns carried out in October 1998, in February and May 1999 sampling several fumaroles. Traditional sampling methods were used to collect both total Hg and S. The average Hg/S ratio value resulted to be 1.2 x 10(-7). From the Hg/S value we derived the Hg/SO2 value, and by assuming that all the volcanoes located in this area have the same Hg/SO2 ratio, mercury emissions from Vulcano and Stromboli were estimated to be in the range 1.3-5.5 kg/year and 7.3-76.6 kg/year respectively, while for Etna mercury flux ranged from 61.8 to 536.5 kg/year. Data reported in literature appear to be overestimated (Fitzgerald WF. Mercury emission from volcanos. In: 4th International conference on mercury as a global pollutant, August 4-8 1996, Hamburg, Germany), volcanic mercury emission does not constitute the main natural source of the metal.

Monitoring SO2emission trends and residents' perceived health risks from PGM smelting at Selous Metallurgical Complex in Zimbabwe.

PubMed

Gwimbi, Patrick

2017-11-16

Persistently high sulphur dioxide (SO 2 ) emissions from platinum group metal (PGM) smelting pose a major threat to communities located around smelters. This paper examined SO 2 emission trends, emission regulations and residents' perceived health risks from exposures to such emissions at Selous Metallurgical Complex (SMC) PGM smelting facility in Zimbabwe. SO 2 data from roof monitoring sites at the smelter furnace were aggregated into annual, quarterly and monthly emission trends from 2008 to 2015. The regulatory regime's ability to protect human health from SO 2 pollution in communities located around the smelter was examined. Questionnaire responses to perceived health risks from SO 2 exposure from 40 purposively sampled residents were assessed. The relationships between SO 2 emission trends and residents' self-reported health risks from exposure to SO 2 emissions were explored using STATA version 11. Descriptive statistics were used to illustrate SO 2 emission trends and residents' self-reported health risks from exposure to SO 2 . Between 2008 and 2015, annual SO 2 emissions increased from 7951 to 2500 tonnes. Emissions exceeded the recommended standard limit of 50 mg/Nm 3 , presenting considerable adverse health risks to local residents. Concerns relating to inefficient environmental impact assessment (EIA) licensing system, poor monitoring and auditing by the environmental management agency, as well as non-deterring SO 2 emission exceedance penalties were identified as major drivers of emission increase. Thirty-two (80%) of the forty respondents perceived exposure to SO 2 emissions as adverse and the cause of their illnesses, with coughing, nasal congestion and shortness of breath the most frequently self-reported symptoms. A set of legally-binding SO 2 emission standards supported by stringent EIA licensing arrangements for smelting industries are suggested for development and enforcement to reduce the SO 2 emission problem. Community participation in SO 2 emissions monitoring is also proposed as a core part of sustainable environmental management in communities located around smelters.

40 CFR 74.23 - 1985 Allowable SO 2 emissions rate.

Code of Federal Regulations, 2013 CFR

2013-07-01

....00 1.00 Coal Unit with Federal Limit, but Averaging Time Not Specified 0.93 0.89 (2) Calendar year... Bituminous coal Subbituminous coal Lignite coal Oil lbs Sulfur/mmBtu 2.0 2.0 2.0 2.0 % Sulfur in fuel 1.66 2... year as defined under § 74.23(a)(2). (ii) Citation of statute, regulations, and any other authority...

40 CFR 74.23 - 1985 Allowable SO 2 emissions rate.

Code of Federal Regulations, 2014 CFR

2014-07-01

....00 1.00 Coal Unit with Federal Limit, but Averaging Time Not Specified 0.93 0.89 (2) Calendar year... Bituminous coal Subbituminous coal Lignite coal Oil lbs Sulfur/mmBtu 2.0 2.0 2.0 2.0 % Sulfur in fuel 1.66 2... year as defined under § 74.23(a)(2). (ii) Citation of statute, regulations, and any other authority...

Public health, climate, and economic impacts of desulfurizing jet fuel.

PubMed

Barrett, Steven R H; Yim, Steve H L; Gilmore, Christopher K; Murray, Lee T; Kuhn, Stephen R; Tai, Amos P K; Yantosca, Robert M; Byun, Daewon W; Ngan, Fong; Li, Xiangshang; Levy, Jonathan I; Ashok, Akshay; Koo, Jamin; Wong, Hsin Min; Dessens, Olivier; Balasubramanian, Sathya; Fleming, Gregg G; Pearlson, Matthew N; Wollersheim, Christoph; Malina, Robert; Arunachalam, Saravanan; Binkowski, Francis S; Leibensperger, Eric M; Jacob, Daniel J; Hileman, James I; Waitz, Ian A

2012-04-17

In jurisdictions including the US and the EU ground transportation and marine fuels have recently been required to contain lower concentrations of sulfur, which has resulted in reduced atmospheric SO(x) emissions. In contrast, the maximum sulfur content of aviation fuel has remained unchanged at 3000 ppm (although sulfur levels average 600 ppm in practice). We assess the costs and benefits of a potential ultra-low sulfur (15 ppm) jet fuel standard ("ULSJ"). We estimate that global implementation of ULSJ will cost US$1-4bn per year and prevent 900-4000 air quality-related premature mortalities per year. Radiative forcing associated with reduction in atmospheric sulfate, nitrate, and ammonium loading is estimated at +3.4 mW/m(2) (equivalent to about 1/10th of the warming due to CO(2) emissions from aviation) and ULSJ increases life cycle CO(2) emissions by approximately 2%. The public health benefits are dominated by the reduction in cruise SO(x) emissions, so a key uncertainty is the atmospheric modeling of vertical transport of pollution from cruise altitudes to the ground. Comparisons of modeled and measured vertical profiles of CO, PAN, O(3), and (7)Be indicate that this uncertainty is low relative to uncertainties regarding the value of statistical life and the toxicity of fine particulate matter.

The effect of providing climate and health information on support for alternative electricity portfolios

NASA Astrophysics Data System (ADS)

Sergi, Brian; Davis, Alex; Azevedo, Inês

2018-02-01

Support for addressing climate change and air pollution may depend on the type of information provided to the public. We conduct a discrete choice survey assessing preferences for combinations of electricity generation portfolios, electricity bills, and emissions reductions. We test how participants’ preferences change when emissions information is explicitly provided to them. We find that support for climate mitigation increases when mitigation is accompanied by improvements to air quality and human health. We estimate that an average respondent would accept an increase of 19%-27% in their electricity bill if shown information stating that either CO2 or SO2 emissions are reduced by 30%. Furthermore, an average respondent is willing to pay an increase of 30%-40% in electricity bills when shown information stating that both pollutants are reduced by 30% simultaneously. Our findings suggest that the type of emissions information provided to the public will affect their support for different electricity portfolios.

[Improvement of Air Quality During APEC in Beijing in 2014].

PubMed

Cheng, Nian-liang; Li, Yun-ting; Zhang, Da-wei; Chen, Tian; Li, Ling-jun; Li, Jin; Jiang, Lei

2016-01-15

Variations of air quality, meteorological conditions and the effect of pollution control measures on particle matter concentrations in Beijing were all analyzed during APEC (from 1st to 12th in November) in 2014 based on the atmospheric pollutant monitoring data, monitoring components of PM2.5, meteorological and remote sensing data and CMB model. The results showed that the average concentrations of PM2.5, PM10, SO2, NO2 were 43,62,8,46 [g.m respectively during APEC and the average concentrations of PM2.5, PM10, SO2, NO2 were decreased by 45%, 43%, 64% and 31% compared to those in the same period of the last 5 years (PM2. was the average of the last 2 years); the concentrations of PM25 at different sites were decreased by 27.4%-35.5%; the concentrations of PM2.5 in the center of city and northern mountainous areas were the lowest, which dropped by 30%-45% compared to those in the same period of the last 5 years while in the southern area the decrement was below 25%; the main component SO4(2-), the substance of the crust, and NO3- were decreased by 50%, 76%, 35% respectively compared to those in the same period in 2013 and the chemical mass balance (CMB) model analysis results indicated that contributions of coal boiler, dust, motor vehicle were 2%, 7%, 30% respectively during APEC; air pollution control measures (coal, dust and traffic management) had a significant effect on reducing pollutant emissions and the pollutant emissions control reduced the concentration peak and delayed the accumulation speed.

Volcanic gas emissions and degassing dynamics at Ubinas and Sabancaya volcanoes; implications for the volatile budget of the central volcanic zone

NASA Astrophysics Data System (ADS)

Moussallam, Yves; Tamburello, Giancarlo; Peters, Nial; Apaza, Fredy; Schipper, C. Ian; Curtis, Aaron; Aiuppa, Alessandro; Masias, Pablo; Boichu, Marie; Bauduin, Sophie; Barnie, Talfan; Bani, Philipson; Giudice, Gaetano; Moussallam, Manuel

2017-09-01

Emission of volcanic gas is thought to be the dominant process by which volatiles transit from the deep earth to the atmosphere. Volcanic gas emissions, remain poorly constrained, and volcanoes of Peru are entirely absent from the current global dataset. In Peru, Sabancaya and Ubinas volcanoes are by far the largest sources of volcanic gas. Here, we report the first measurements of the compositions and fluxes of volcanic gases emitted from these volcanoes. The measurements were acquired in November 2015. We determined an average SO2 flux of 15.3 ± 2.3 kg s- 1 (1325-ton day- 1) at Sabancaya and of 11.4 ± 3.9 kg s- 1 (988-ton day- 1) at Ubinas using scanning ultraviolet spectroscopy and dual UV camera systems. In-situ Multi-GAS analyses yield molar proportions of H2O, CO2, SO2, H2S and H2 gases of 73, 15, 10 1.15 and 0.15 mol% at Sabancaya and of 96, 2.2, 1.2 and 0.05 mol% for H2O, CO2, SO2 and H2S at Ubinas. Together, these data imply cumulative fluxes for both volcanoes of 282, 30, 27, 1.2 and 0.01 kg s- 1 of H2O, CO2, SO2, H2S and H2 respectively. Sabancaya and Ubinas volcanoes together contribute about 60% of the total CO2 emissions from the Central Volcanic zone, and dominate by far the total revised volatile budget of the entire Central Volcanic Zone of the Andes.

[Analysis About Spatial and Temporal Distribution of SO2 and An Ambient SO2 Pollution Process in Beijing During 2000-2014].

PubMed

Cheng, Nian-liang; Zhang, Da-wei; Li, Yun-ting; Chen, Tian; Li, Jin-xiang; Dong, Xin; Sun, Rui-wen; Meng, Fan

2015-11-01

Spatial and temporal distribution of SO2 during 2000-2014 was all analyzed based on the SO2 monitoring data that Beijing Municipal Environmental Monitoring Center released and the formation mechanism of a typical air pollution episode in January 2014 was also investigated by combining numerical model CAM(x). Analysis results showed that mass concentration of ρ(SO2) in Beijing in 2014 decreased 69% compared to that in 2000 with an annual gradient from 2000 to 2014 of - 3.5 μg x (m3 x a)(-1). Monthly average concentration of SO2 changed in a U shape curve and from the lowest to the highest, and seasonal variations of SO2 concentrations were as follows: winter > spring > autumn > summer; concentration of SO2 in heating season was significantly higher than that in non heating season. Annual average concentration of SO2 was lower in northern and western regions while higher in six city area and southern area. Concentrations of SO2 at Shijingshan, Dongsi, Tongzhou monitoring sites were significantly decreased related to SO2 emission reduction measures. During a heavy air pollution process in January 14 - 18th 2014 there was obviously SO2 regional transportation and model simulation analysis based on PAST showed that the contribution of SO2 regional transport to Beijing was 83% with elevated power plants surrounding Beijing accounting for 21% and the four major Beijing power plants contributing about 3.5% to the SO2 concentration during this heavy air pollution process.

Spatial Distribution of the Forbidden 1.707 mm Rovibronic Emission on Io

NASA Astrophysics Data System (ADS)

de Pater, Imke; de Kleer, Katherine; Adamkovics, Mate

2017-10-01

Io’s forbidden SO 1.707 mm rovibronic transition was discovered in 1999 when the satellite was observed with the NIRSPEC spectrometer on the Keck telescope while in eclipse [1]. The emission, at the time indicative of a rotational temperature of 1000 K, was attributed to SO molecules in the excited a1D state, ejected as such from the vent at a thermodynamic quenching temperature of ~1500 K. We suggested Loki as its source, a volcano that was exceptionally active during this period. In subsequent years we found that the disk-averaged SO emission varies substantially over time [2]. In November 2002 we observed Io in eclipse with Keck’s NIRSPEC coupled to the Adaptive Optics (AO) system, and identified a latitudinal variation in SO: most emission came from the equator and the south, and practically no emission was detected in the north [3]. To further investigate the nature of the SO emission, we observed Io in eclipse with the near-infrared integral field spectrograph OSIRIS, coupled to the AO system, on the Keck II telescope on UT 27 July 2010 and 25 December 2015. On the latter date we observed simultaneously with the NIRSPEC spectrometer at a high spectral resolution (R ~ 25,000). On these dates Callisto and Ganymede, resp., were close enough to be used for wavefront sensing. The angular resolution of our images is ~0.1”, or ~10 resolution elements across Io’s disk. The emission is extended; preliminary results show that in 2010 most of the emission originated in the north, and in 2015 it appeared to be more confined to the equatorial region. Potential connections to active volcanoes, or absence thereof, and model fits to the emission bands including LTE vs non-LTE contributions will be discussed. [1]: de Pater, I., et al., 2002. Icarus, 156, 296-301.[2]: Laver, C., et al. 2007. Icarus, 189, 401-408.[3]: de Pater, I. et al., 2007. Icarus, 191, 172-182.

40 CFR 57.402 - Elements of the supplementary control system.

Code of Federal Regulations, 2013 CFR

2013-07-01

... capable of routine real time measurement of maximum expected SO2 concentrations for the averaging times of... emission curtailment decisions based on the use of real time information from the air quality monitoring... meteorological information necessary to operate the system; (iv) The ambient concentrations and meteorological...

40 CFR 57.402 - Elements of the supplementary control system.

Code of Federal Regulations, 2011 CFR

2011-07-01

... capable of routine real time measurement of maximum expected SO2 concentrations for the averaging times of... emission curtailment decisions based on the use of real time information from the air quality monitoring... meteorological information necessary to operate the system; (iv) The ambient concentrations and meteorological...

40 CFR 57.402 - Elements of the supplementary control system.

Code of Federal Regulations, 2012 CFR

2012-07-01

... capable of routine real time measurement of maximum expected SO2 concentrations for the averaging times of... emission curtailment decisions based on the use of real time information from the air quality monitoring... meteorological information necessary to operate the system; (iv) The ambient concentrations and meteorological...

40 CFR 57.402 - Elements of the supplementary control system.

Code of Federal Regulations, 2014 CFR

2014-07-01

... capable of routine real time measurement of maximum expected SO2 concentrations for the averaging times of... emission curtailment decisions based on the use of real time information from the air quality monitoring... meteorological information necessary to operate the system; (iv) The ambient concentrations and meteorological...

40 CFR 57.402 - Elements of the supplementary control system.

Code of Federal Regulations, 2010 CFR

2010-07-01

... capable of routine real time measurement of maximum expected SO2 concentrations for the averaging times of... emission curtailment decisions based on the use of real time information from the air quality monitoring... meteorological information necessary to operate the system; (iv) The ambient concentrations and meteorological...

Ambient air quality effects of the 2008-2009 Halema`uma`u eruption on the Island of Hawai`i

NASA Astrophysics Data System (ADS)

Elias, T.; Sutton, A. J.; Kauahikaua, J. P.; Ray, J. D.; Babb, J. L.

2009-12-01

While the Halema`uma`u eruption has enlivened volcanologists with the rare opportunity to observe eruptive processes at Kilauea’s summit, it has also caused significant environmental impact on the Island of Hawai`i. Since the beginning of 2008, the combined SO2 emissions from the east rift zone (ERZ) and summit of Kilauea have increased by ~40% as compared to the 2003-2007 long-term average. However, emissions from Kilauea’s summit have increased ~6-fold, averaging 850 t/d during January 2008-August 2009. Although average emissions from the ERZ during this period have been 1-2 times that of the summit, the relative impact of summit emissions is disproportionately large due to the location of the vent and the plume dispersal pattern to downwind communities. Ambient air quality data show that federal standards have been exceeded frequently in various communities on the south half of the island. Between April 2008 and August 2009, primary health standards for SO2 and PM2.5 were exceeded on 41 and 19 occasions respectively in Pahala, located ~30 km downwind of the Kilauea summit under prevailing trade wind conditions. Pahala, which exceeded the SO2 annual standard for 2008, had not exceeded standards prior to the opening of the Halema`uma`u vent in March 2008. In July 2008, the U.S. Secretary of Agriculture designated Hawai`i County a primary natural disaster area due to agricultural losses from volcanic emissions. Many growers of exotic flower crops in the Ka`u district suffered irrecoverable losses. Coffee and macadamia nut farmers also reported damage to their fields. While some livestock farmers reported eye irritation in cattle, more significant damage was observed in the accelerated deterioration of galvanized fencing, gates, pipelines and other infrastructure. The increase in volcanic pollution has spurred health concerns. A rise in respiratory emergencies for visitors to Kilauea caldera in early 2008 led Hawai`i Volcanoes National Park to close areas downwind of the vent. Two recent health studies on the Island of Hawaii conducted prior to the 2008-2009 activity noted increased upper respiratory symptom prevalence in areas of persistent volcanic pollution. The current activity and exposure provides further opportunity to examine thresholds of human response. Local emergency response agencies were pressured to act quickly to address the air quality hazards. A variety of initial approaches led to an official policy of “shelter-in-place” during extreme air quality events. To date, interagency mitigation efforts have included providing Web-available near-real-time SO2 and PM data, developing an SO2 alert index, public education, supplying community fire stations and schools with SO2 monitoring equipment, surveying water quality in home-based drinking water catchment tanks, exploring forecast models, and working to install air handling systems for affected hospitals. While volcanic pollution has been an ongoing issue on the Island since the ERZ eruption became continuous in 1986, the current summit eruption has posed new challenges to Hawai`i residents, who must adapt to living with an active volcano.

Characterizing reduced sulfur compounds and non-methane volatile organic compounds emissions from a swine concentrated animal feeding operation

NASA Astrophysics Data System (ADS)

Rumsey, Ian Cooper

Reduced sulfur compounds (RSCs) and non-methane volatile organic compounds (NMVOCs) emissions from concentrated animal feeding operations (CAFOs) have become a potential environmental and human health concern. Both RSCs and NMVOCs contribute to odor. In addition, RSCs also have the potential to form fine particulate matter (PMfine) and NMVOCs the potential to form ozone. Measurements of RSCs and NMVOCs emissions were made from both an anaerobic lagoon and barn at a swine CAFO in North Carolina. Emission measurements were made over all four seasonal periods. In each seasonal period, measurements were made from both the anaerobic lagoon and barn for ˜1 week. RSC and NMVOCs samples were collected using passivated canisters. Nine to eleven canister samples were taken from both the lagoon and barn over each sampling period. The canisters were analyzed ex-situ using gas chromatography flame ionization detection (GC-FID). Hydrogen sulfide (H2S) measurements were made in-situ using a pulsed fluorescence H2S/SO2 analyzer. During sampling, measurements of meteorological and physiochemical parameters were made. H2S had the largest RSC flux, with an overall average lagoon flux of 1.33 mug m-2 min-1. The two main RSCs identified by the GC-FID, dimethyl sulfide (DMS) and dimethyl disulfide (DMDS), had overall average lagoon fluxes an order of magnitude lower, 0.12 and 0.09 mug m-2 min-1, respectively. Twelve significant NMVOCs were identified in lagoon samples (ethanol, 2-ethyl-1-hexanol, methanol, acetaldehyde, decanal, heptanal, hexanal, nonanal, octanal, acetone, methyl ethyl ketone, and 4-methylphenol). The overall average fluxes for these NMVOCs, ranged from 0.08 mug m-2 min-1 (4-methylphenol) to 2.11 mug m-2 min-1 (acetone). Seasonal H2S barn concentrations ranged from 72-631 ppb. DMS and DMDS seasonal concentrations were 2-3 orders of magnitude lower. There were six significant NMVOCs identified in barn samples (methanol, ethanol, acetone 2-3 butanedione, acetaldehyde and 4-methylphenol). Their overall average NMVOCs concentrations ranged from 2.87 ppb (4-methylphenol) to 16.21 ppb (ethanol). The overall average barn normalized emissions were 3.3 g day-1 AU-1 (AU (animal unit) = 500 kg) for H2S, 0.018 g day-1 AU-1 for DMS and 0.037 g day -1 AU-1 for DMDS. Normalized overall average NMVOC emissions ranged from 0.45 g day-1 AU-1 for ethanol to 0.16 g day-1 AU-1 for acetaldehyde. Barn H2S concentrations were generally one to two orders of magnitude above their odor thresholds. DMDS concentrations also regularly exceeded the lower limit of an odor threshold. Four NMVOCs (2-3 butanedione, decanal, 4-methylphenol and nonanal) had barn concentrations exceeding an odor threshold. Using overall average lagoon and barn emissions, the emissions from swine CAFOs in North Carolina were estimated. H2S had the largest RSC emission with an estimated North Carolina emission of 1.46 million kg yr -1, which was ˜21% of total North Carolina H2S emissions. Ethanol was the NMVOC with the largest North Carolina emission with an emission of 206,367 kg yr-1.

Mobile measurements of ship emissions in two harbour areas in Finland

NASA Astrophysics Data System (ADS)

Pirjola, L.; Pajunoja, A.; Walden, J.; Jalkanen, J.-P.; Rönkkö, T.; Kousa, A.; Koskentalo, T.

2014-01-01

Four measurement campaigns were performed in two different environments - inside the harbour areas in the city centre of Helsinki, and along the narrow shipping channel near the city of Turku, Finland - using a mobile laboratory van during winter and summer conditions in 2010-2011. The characteristics of gaseous (CO, CO2, SO2, NO, NO2, NOx) and particulate (number and volume size distributions as well as PM2.5) emissions for 11 ships regularly operating on the Baltic Sea were studied to determine the emission parameters. The highest particle concentrations were 1.5 × 106 and 1.6 × 105 cm-3 in Helsinki and Turku, respectively, and the particle number size distributions had two modes. The dominating mode peaked at 20-30 nm, and the accumulation mode at 80-100 nm. The majority of the particle mass was volatile, since after heating the sample to 265 °C, the particle volume of the studied ship decreased by around 70%. The emission factors for NOx varied in the range of 25-100 g (kg fuel)-1, for SO2 in the range of 2.5-17.0 g (kg fuel)-1, for particle number in the range of (0.32-2.26) × 1016 # (kg fuel)-1, and for PM2.5 between 1.0-4.9 g (kg fuel)-1. The ships equipped with SCR (selective catalytic reduction) had the lowest NOx emissions, whereas the ships with DWI (direct water injection) and HAMs (humid air motors) had the lowest SO2 emissions but the highest particulate emissions. For all ships, the averaged fuel sulphur contents (FSCs) were less than 1% (by mass) but none of them was below 0.1% which will be the new EU directive starting 1 January 2015 in the SOx emission control areas; this indicates that ships operating on the Baltic Sea will face large challenges.

Degassing of CO2, SO2, and H2S associated with the 2009 eruption of Redoubt Volcano, Alaska

USGS Publications Warehouse

Werner, Cynthia A.; Kelly, Peter; Doukas, Michael P.; Lopez, Taryn; Pfeffer, Melissa; McGimsey, Robert G.; Neal, Christina

2013-01-01

The 2009 eruption of Redoubt Volcano, Alaska was particularly well monitored for volcanic gas emissions. We report 35 airborne measurements of CO2, SO2, and H2S emission rates that span from October 2008 to August 2010. The magmatic system degassed primarily as a closed system although minor amounts of open system degassing were observed in the 6 months prior to eruption on March 15, 2009 and over 1 year following cessation of dome extrusion. Only 14% of the total CO2 was emitted prior to eruption even though high emissions rates (between 3630 and 9020 t/d) were observed in the final 6 weeks preceding the eruption. A minor amount of the total SO2 was observed prior to eruption (4%), which was consistent with the low emission rates at that time (up to 180 t/d). The amount of the gas emitted during the explosive and dome growth period (March 15–July 1, 2009) was 59 and 66% of the total CO2and SO2, respectively. Maximum emission rates were 33,110 t/d CO2, 16,650 t/d SO2, and 1230 t/d H2S. Post-eruptive passive degassing was responsible for 27 and 30% of the total CO2 and SO2, respectively. SO2 made up on average 92% of the total sulfur degassing throughout the eruption. Magmas were vapor saturated with a C- and S-rich volatile phase, and regardless of composition, the magmas appear to be buffered by a volatile composition with a molar CO2/SO2 ratio of ~ 2.4. Primary volatile contents calculated from degassing and erupted magma volumes range from 0.9 to 2.1 wt.% CO2 and 0.27–0.56 wt.% S; whole-rock normalized values are slightly lower (0.8–1.7 wt.% CO2 and 0.22–0.47 wt.% S) and are similar to what was calculated for the 1989–90 eruption of Redoubt. Such contents argue that primary arc magmas are rich in CO2 and S. Similar trends between volumes of estimated degassed magma and observed erupted magma during the eruptive period point to primary volatile contents of 1.25 wt.% CO2 and 0.35 wt.% S. Assuming these values, up to 30% additional unerupted magma degassed in the year following final dome emplacement.

Degassing of CO2, SO2, and H2S associated with the 2009 eruption of Redoubt Volcano, Alaska

NASA Astrophysics Data System (ADS)

Werner, Cynthia; Kelly, Peter J.; Doukas, Michael; Lopez, Taryn; Pfeffer, Melissa; McGimsey, Robert; Neal, Christina

2013-06-01

The 2009 eruption of Redoubt Volcano, Alaska was particularly well monitored for volcanic gas emissions. We report 35 airborne measurements of CO2, SO2, and H2S emission rates that span from October 2008 to August 2010. The magmatic system degassed primarily as a closed system although minor amounts of open system degassing were observed in the 6 months prior to eruption on March 15, 2009 and over 1 year following cessation of dome extrusion. Only 14% of the total CO2 was emitted prior to eruption even though high emissions rates (between 3630 and 9020 t/d) were observed in the final 6 weeks preceding the eruption. A minor amount of the total SO2 was observed prior to eruption (4%), which was consistent with the low emission rates at that time (up to 180 t/d). The amount of the gas emitted during the explosive and dome growth period (March 15-July 1, 2009) was 59 and 66% of the total CO2 and SO2, respectively. Maximum emission rates were 33,110 t/d CO2, 16,650 t/d SO2, and 1230 t/d H2S. Post-eruptive passive degassing was responsible for 27 and 30% of the total CO2 and SO2, respectively. SO2 made up on average 92% of the total sulfur degassing throughout the eruption. Magmas were vapor saturated with a C- and S-rich volatile phase, and regardless of composition, the magmas appear to be buffered by a volatile composition with a molar CO2/SO2 ratio of ~ 2.4. Primary volatile contents calculated from degassing and erupted magma volumes range from 0.9 to 2.1 wt.% CO2 and 0.27-0.56 wt.% S; whole-rock normalized values are slightly lower (0.8-1.7 wt.% CO2 and 0.22-0.47 wt.% S) and are similar to what was calculated for the 1989-90 eruption of Redoubt. Such contents argue that primary arc magmas are rich in CO2 and S. Similar trends between volumes of estimated degassed magma and observed erupted magma during the eruptive period point to primary volatile contents of 1.25 wt.% CO2 and 0.35 wt.% S. Assuming these values, up to 30% additional unerupted magma degassed in the year following final dome emplacement.

Quantification of Shipping Emissions in the Eastern Mediterranean and Comparison with Satellite Observations

NASA Astrophysics Data System (ADS)

Kilic, A.; Unal, A.; Kindap, T.; Karaca, M.; Khan, M. N.

2010-12-01

Shipping is considered as one of the main emission sources worldwide. Recent studies suggest that, in the Mediterrenean, ship emissions are responsible for 10-50% of black carbon, 2-12% ozone in the surface layer and 5-20% for nitrogen dioxide atmospheric column burden (Marmer et al., 2009). It is, therefore, essential to have an accurate emissions estimation for ships. Marmara Sea, an inland sea connecting the Mediterrenean to the Black Sea, has significant marine activity. Marmara region, surrounding the Marmara Sea, has over 30 million population (including Istanbul megacity) with significant emission sources (e.g., on-road traffic, industry). Emission amounts from ships can be calculated based on two different methodologies, one is according to the total amount of bunker fuels for maritime transport sold which is called top down approach and the other is shipping activity-based bottom-up approach. The top-down estimation method is not suitable for calculations of shipping emissions in Turkey since fuel sales cannot be accurately obtained. Also, top-down approaches possibly have some errors, since data assumptions for the average engine power, engine operating hours and emission factors are the most important uncertain inputs. Previously, a few studies based on bottom-up aproach have been carried on about shipping emissions in Marmara Sea according to the shipping statistics belong to Istanbul and Canakkale Straits and port regions. These studies were mainly depending on very rough assumptions such as avearage ship speed, fixed ships routes, generalized engine types and average fuel consumptions. Deniz C. (2008) estimated shipping emissions in 2003, for Marmara Sea and Turkish Straits as 111,000 tons for NOx, 87,000 tons for SO2, 5,451,000 tons for CO2, 4762 tons for PM. Although- between 2003 and 2008- there is approximately 15% increase in number of ships passsing through Turkish Straits, this study shows that, shippings emissions for the same region are estimated to be more than 3 times of previous studies. In this study, Automatic Information System (AIS) records of marine vessels (having 1 minute temporal resolution) for over 10,000 ships operating at the study area (including Marmara Sea, Istanbul and Canakkale Straits and some parts of Black Sea and Aegian Sea) were obtained from Turkish Undersecretariat for Maritime Affairs for the period between August 2008 and August 2009. These records include the position of the ships, gross tonnage and ship types. Using energy based emission factors for each operation mode, minute-by-minute emissions were estimated. Annual emission totals for merchant ships were estimated as 605,000 tons for NOX; 495,000 tons for SO2; 25,600 tons for HC; 53,300 tons for PM and 29,630,000 tons for CO2. This paper presents the methodology and the findings of the emissions estimates for ships. The results will also be compared to satellite observations. For this purpose, CO measurements from MOPITT and SO2 measurements from OMI will be utilized.

Characterization of NOx, SO2, ethene, and propene from industrial emission sources in Houston, Texas

NASA Astrophysics Data System (ADS)

Washenfelder, R. A.; Trainer, M.; Frost, G. J.; Ryerson, T. B.; Atlas, E. L.; de Gouw, J. A.; Flocke, F. M.; Fried, A.; Holloway, J. S.; Parrish, D. D.; Peischl, J.; Richter, D.; Schauffler, S. M.; Walega, J. G.; Warneke, C.; Weibring, P.; Zheng, W.

2010-08-01

The Houston-Galveston-Brazoria urban area contains industrial petrochemical sources that emit volatile organic compounds and nitrogen oxides, resulting in rapid and efficient ozone production downwind. During September to October 2006, the NOAA WP-3D aircraft conducted research flights as part of the second Texas Air Quality Study (TexAQS II). We use measurements of NOx, SO2, and speciated hydrocarbons from industrial sources in Houston to derive source emission ratios and compare these to emission inventories and the first Texas Air Quality Study (TexAQS) in 2000. Between 2000 and 2006, NOx/CO2 emission ratios changed by an average of -29% ± 20%, while a significant trend in SO2/CO2 emission ratios was not observed. We find that high hydrocarbon emissions are routine for the isolated petrochemical facilities. Ethene (C2H4) and propene (C3H6) are the major contributors to ozone formation based on calculations of OH reactivity for organic species including C2-C10 alkanes, C2-C5 alkenes, ethyne, and C2-C5 aldehydes and ketones. Measured ratios of C2H4/NOx and C3H6/NOx exceed emission inventory values by factors of 1.4-20 and 1-24, respectively. We examine trends in C2H4/NOx and C3H6/NOx ratios between 2000 and 2006 for the isolated petrochemical sources and estimate a change of -30% ± 30%, with significant day-to-day and within-plume variability. Median ambient mixing ratios of ethene and propene in Houston show decreases of -52% and -48%, respectively, between 2000 and 2006. The formaldehyde, acetaldehyde, and peroxyacetyl nitrate products produced by alkene oxidation are observed downwind, and their time evolution is consistent with the rapid photochemistry that also produces ozone.

[Variation of atmospheric pollutants in Qinhuangdao City].

PubMed

Liu, Lu-Ning; Shen, Yu-Xuan; Xin, Jin-Yuan; Ji, Dong-Sheng; Wang, Yue-Si

2013-06-01

To illuminate the air pollution situation of the tourist city of Qinhuangdao, the atmospheric pollutants were measured from autumn 2009 to summer 2010. The results showed that the mean average concentration of NO, NO2, SO2, O3 and PM10 during the observation period reached (18 +/- 18), (45 +/- 18), (42 +/- 46), (44 +/- 25) and (128 +/- 77) microg x m(-3), respectively. The particulate matter pollution was serious, and the rate of the annual mean value exceeded the National Ambient Air Quality Standard II by 28%. The average daily concentration and average max hourly O3 concentration were (64 +/- 21)microg x m(-3) and (126 +/- 42) microg x m(-3) in summer, and the air masses from the southern ocean aggravated the O3 pollution. The concentrations of NO(x) SO2 and PM10 in the heating period were 1.5, 4.9 and 1.5 times more than those in the period without heating and the daily average concentration of SO2 and PM10 exceeded the National Ambient Air Quality Standard II by 53% and 11% in the heating period, respectively. The superimposition effect of regional transport in the Beijing-Tianjin-Hebei region and industrial area surrounding the Bohai Bay and local harbor emission led to an increase of 17% (NO(x)), 27% (SO2) and 12% (PM10), resulting in average concentrations of up to (100 +/- 49), (110 +/- 84) and (215 +/- 108) microg x m(-3) in winter. The winds from northern inland and southern ocean can effectively remove the air pollutants.

PET and MRI image fusion based on combination of 2-D Hilbert transform and IHS method.

PubMed

Haddadpour, Mozhdeh; Daneshvar, Sabalan; Seyedarabi, Hadi

2017-08-01

The process of medical image fusion is combining two or more medical images such as Magnetic Resonance Image (MRI) and Positron Emission Tomography (PET) and mapping them to a single image as fused image. So purpose of our study is assisting physicians to diagnose and treat the diseases in the least of the time. We used Magnetic Resonance Image (MRI) and Positron Emission Tomography (PET) as input images, so fused them based on combination of two dimensional Hilbert transform (2-D HT) and Intensity Hue Saturation (IHS) method. Evaluation metrics that we apply are Discrepancy (D k ) as an assessing spectral features and Average Gradient (AG k ) as an evaluating spatial features and also Overall Performance (O.P) to verify properly of the proposed method. In this paper we used three common evaluation metrics like Average Gradient (AG k ) and the lowest Discrepancy (D k ) and Overall Performance (O.P) to evaluate the performance of our method. Simulated and numerical results represent the desired performance of proposed method. Since that the main purpose of medical image fusion is preserving both spatial and spectral features of input images, so based on numerical results of evaluation metrics such as Average Gradient (AG k ), Discrepancy (D k ) and Overall Performance (O.P) and also desired simulated results, it can be concluded that our proposed method can preserve both spatial and spectral features of input images. Copyright © 2017 Chang Gung University. Published by Elsevier B.V. All rights reserved.

40 CFR 60.46c - Emission monitoring for sulfur dioxide.

Code of Federal Regulations, 2011 CFR

2011-07-01

... potential SO2 emission rate of the fuel combusted, and the span value of the SO2 CEMS at the outlet from the SO2 control device shall be 50 percent of the maximum estimated hourly potential SO2 emission rate of... estimated hourly potential SO2 emission rate of the fuel combusted. (d) As an alternative to operating a...

Modelling the spatial distribution of SO2 and NOx emissions in Ireland.

PubMed

de Kluizenaar, Y; Aherne, J; Farrell, E P

2001-01-01

The spatial distributions of sulphur dioxide (SO2) and nitrogen oxides (NOx) emissions are essential inputs to models of atmospheric transport and deposition. Information of this type is required for international negotiations on emission reduction through the critical load approach. High-resolution emission maps for the Republic of Ireland have been created using emission totals and a geographical information system, supported by surrogate statistics and landcover information. Data have been subsequently allocated to the EMEP 50 x 50-km grid, used in long-range transport models for the investigation of transboundary air pollution. Approximately two-thirds of SO2 emissions in Ireland emanate from two grid-squares. Over 50% of total SO2 emissions originate from one grid-square in the west of Ireland, where the largest point sources of SO2 are located. Approximately 15% of the total SO2 emissions originate from the grid-square containing Dublin. SO2 emission densities for the remaining areas are very low, < 1 t km-2 year-1 for most grid-squares. NOx emissions show a very similar distribution pattern. However, NOx emissions are more evenly spread over the country, as about 40% of total NOx emissions originate from road transport.

Organic aerosols and inorganic species from post-harvest agricultural-waste burning emissions over northern India: impact on mass absorption efficiency of elemental carbon.

PubMed

Rajput, Prashant; Sarin, M M; Sharma, Deepti; Singh, Darshan

2014-01-01

Atmospheric PM2.5 (particulate matter with aerodynamic diameter of ≤ 2.5 μm), collected from a source region [Patiala: 30.2 °N; 76.3 °E; 250 m above mean sea level] of emissions from post-harvest agricultural-waste (paddy-residue) burning in the Indo-Gangetic Plain (IGP), North India, has been studied for its chemical composition and impact on regional atmospheric radiative forcing. On average, organic aerosol mass accounts for 63% of PM2.5, whereas the contribution of elemental carbon (EC) is ∼3.5%. Sulphate, nitrate and ammonium contribute up to ∼85% of the total water-soluble inorganic species (WSIS), which constitutes ∼23% of PM2.5. The potassium-to-organic carbon ratio from paddy-residue burning emissions (KBB(+)/OC: 0.05 ± 0.01) is quite similar to that reported from Amazonian and Savanna forest-fires; whereas non-sea-salt-sulphate-to-OC ratio (nss-SO4(2-)/OC: 0.21) and nss-SO4(2-)/EC ratio of 2.6 are significantly higher (by factor of 5 to 8). The mass absorption efficiency of EC (3.8 ± 1.3 m(2) g(-1)) shows significant decrease with a parallel increase in the concentrations of organic aerosols and scattering species (sulphate and nitrate). A cross plot of OC/EC and nss-SO4(2-)/EC ratios show distinct differences for post-harvest burning emissions from paddy-residue as compared to those from fossil-fuel combustion sources in south-east Asia.

40 CFR 74.22 - Actual SO2 emissions rate.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Actual SO2 emissions rate. 74.22... (CONTINUED) SULFUR DIOXIDE OPT-INS Allowance Calculations for Combustion Sources § 74.22 Actual SO2 emissions... actual SO2 emissions rate shall be 1985. (2) For combustion sources that commenced operation after...

Monitoring shipping emissions in the German Bight using MAX-DOAS measurements

NASA Astrophysics Data System (ADS)

Seyler, André; Wittrock, Folkard; Kattner, Lisa; Mathieu-Üffing, Barbara; Peters, Enno; Richter, Andreas; Schmolke, Stefan; Burrows, John P.

2017-04-01

Shipping is generally the most energy efficient transportation mode, but, at the same time, it accounts for four fifths of the worldwide total merchandise trade volume. As a result, shipping contributes a significant part to the emissions from the transportation sector. The majority of shipping emissions occurs within 400 km of land, impacting on air pollution in coastal areas and harbor towns. The North Sea has one of the highest ship densities in the world and the vast majority of ships heading for the port of Hamburg sail through the German Bight and into the river Elbe. A three-year time series of ground-based MAX-DOAS measurements of NO2 and SO2 on the island Neuwerk in the German Bight has been analyzed for contributions from shipping emissions. Measurements of individual ship plumes as well as of background pollution are possible from this location, which is 6-7 kilometers away from the main shipping lane towards the harbor of Hamburg. More than 2000 individual ship plumes have been identified in the data and analyzed for the emission ratio of SO2 to NO2, yielding an average ratio of 0.3 for the years 2013/2014. Contributions of ships and land-based sources to air pollution levels in the German Bight have been estimated, showing that despite the vicinity to the shipping lane, the contribution of shipping sources to air pollution is only about 40%. Since January 2015, much lower fuel sulfur content limits of 0.1% (before: 1.0%) apply in the North and Baltic Sea Emission Control Area (ECA). Comparing MAX-DOAS measurements from 2015/2016 (new regulation) to 2013/2014 (old regulation), a large reduction in SO2/NO2 ratios in shipping emissions and a significant reduction (by a factor of eight) in ambient coastal SO2 levels have been observed. In addition to that, selected shipping emission measurements from other measurement sites and campaigns are presented. This study is part of the project MeSMarT (Measurements of Shipping emissions in the Marine Troposphere), a cooperation between the University of Bremen and the Federal Maritime and Hydrographic Agency (Bundesamt für Seeschifffahrt und Hydrographie, BSH), supported by the Helmholtz Zentrum Geesthacht (HZG).

Multispectral thermal infrared mapping of sulfur dioxide plumes: A case study from the East Rift Zone of Kilauea Volcano, Hawaii

NASA Astrophysics Data System (ADS)

Realmuto, V. J.; Sutton, A. J.; Elias, T.

1997-07-01

The synoptic perspective and rapid mode of data acquisition provided by remote sensing are well suited for the study of volcanic SO2 plumes. In this paper we describe a plume-mapping procedure that is based on image data acquired with NASA's airborne thermal infrared multispectral scanner (TIMS) and apply the procedure to TIMS data collected over the East Rift Zone of Kilauea Volcano, Hawaii, on September 30, 1988. These image data covered the Pu`u `O `o and Kupaianaha vents and a skylight in the lava tube that was draining the Kupaianaha lava pond. Our estimate of the SO2 emission rate from Pu`u `O `o (17-20 kg s-1) is roughly twice the average of estimates derived from correlation spectrometer (COSPEC) measurements collected 10 days prior to the TIMS overflight (10 kg s-1). The agreement between the TIMS and COSPEC results improves when we compare SO2 burden estimates, which are relatively independent of wind speed. We demonstrate the feasibility of mapping Pu`u `O `o - scale SO2 plumes from space in anticipation of the 1998 launch of the advanced spaceborne thermal emission and reflectance radiometer (ASTER).

Emissions of mercury in Southern Africa derived from long-term observations at Cape Point, South Africa

NASA Astrophysics Data System (ADS)

Brunke, E.-G.; Ebinghaus, R.; Kock, H. H.; Labuschagne, C.; Slemr, F.

2012-05-01

Mercury emissions in South Africa have so far been estimated only by a bottom-up approach from activities and emission factors for different processes. In this paper we derive GEM/CO (GEM being gaseous elemental mercury, Hg0), GEM/CO2, GEM/CH4, CO/CO2, CH4/CO2, and CH4/CO emission ratios from plumes observed during long-term monitoring of these species at Cape Point between March 2007 and December 2009. The average observed GEM/CO, GEM/CO2, GEM/CH4, CO/CO2, CH4/CO2, and CH4/CO emission ratios were 2.40 ± 2.65 pg m-3 ppb-1 (n = 47), 62.7 ± 80.2 pg m-3 ppb-1 (n = 44), 3.61 ± 4.66 pg m-3 ppb-1 (n = 46), 35.6 ± 25.4 ppb ppm-1 (n = 52), 20.2 ± 15.5 ppb ppm-1 (n=48), and 0.876 ± 1.106 ppb ppm-1 (n=42), respectively. The observed CO/CO2, CH4/CO2, and CH4/CO emission ratios agree within the combined uncertainties of the observations and emissions with the ratios calculated from EDGAR (version 4.2) CO2, CO, and CH4 inventories for South Africa and Southern Africa (South Africa, Lesotho, Swaziland, Namibia, Botswana, Zimbabwe, and Mozambique) in 2007 and 2008 (inventories for 2009 are not available yet). Total elemental mercury emission of 13.1, 15.2, and 16.1 t Hg yr-1 are estimated independently using the GEM/CO, GEM/CO2, and GEM/CH4 emission ratios and the annual mean CO, CO2, and CH4 emissions, respectively, of South Africa in 2007 and 2008. The average of these independent estimates of 14.8 ± 1.5 t GEM yr-1 is much less than the total emission of 257 t Hg yr-1 from older inventories. Considering that emission of GEM represents only 50-78% of all mercury emissions, our estimates come close to the total mercury emission estimates ranging between 40-50 t Hg yr-1 from more recent inventories.

40 CFR 75.19 - Optional SO 2, NO X, and CO 2 emissions calculation for low mass emissions (LME) units.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Optional SO 2, NO X, and CO 2... Provisions § 75.19 Optional SO 2, NO X, and CO 2 emissions calculation for low mass emissions (LME) units. (a...) Determination of SO 2, NO X, and CO 2 emission rates. (i) If the unit combusts only natural gas and/or fuel oil...

40 CFR 75.19 - Optional SO 2, NO X, and CO 2 emissions calculation for low mass emissions (LME) units.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Optional SO 2, NO X, and CO 2... Provisions § 75.19 Optional SO 2, NO X, and CO 2 emissions calculation for low mass emissions (LME) units. (a...) Determination of SO 2, NO X, and CO 2 emission rates. (i) If the unit combusts only natural gas and/or fuel oil...

Impact of warmer weather on electricity sector emissions due to building energy use

NASA Astrophysics Data System (ADS)

Meier, Paul; Holloway, Tracey; Patz, Jonathan; Harkey, Monica; Ahl, Doug; Abel, David; Schuetter, Scott; Hackel, Scott

2017-06-01

Most US energy consumption occurs in buildings, with cooling demands anticipated to increase net building electricity use under warmer conditions. The electricity generation units that respond to this demand are major contributors to sulfur dioxide (SO2) and nitrogen oxides (NOx), both of which have direct impacts on public health, and contribute to the formation of secondary pollutants including ozone and fine particulate matter. This study quantifies temperature-driven changes in power plant emissions due to increased use of building air conditioning. We compare an ambient temperature baseline for the Eastern US to a model-calculated mid-century scenario with summer-average temperature increases ranging from 1 C to 5 C across the domain. We find a 7% increase in summer electricity demand and a 32% increase in non-coincident peak demand. Power sector modeling, assuming only limited changes to current generation resources, calculated a 16% increase in emissions of NOx and an 18% increase in emissions of SO2. There is a high level of regional variance in the response of building energy use to climate, and the response of emissions to associated demand. The East North Central census region exhibited the greatest sensitivity of energy demand and associated emissions to climate.

40 CFR 74.25 - Current promulgated SO2 emissions limit.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Current promulgated SO2 emissions... promulgated SO2 emissions limit. The designated representative shall submit the following data: (a) Current promulgated SO2 emissions limit of the combustion source, expressed in lbs/mmBtu, which shall be the most...

40 CFR 74.24 - Current allowable SO2 emissions rate.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Current allowable SO2 emissions rate... allowable SO2 emissions rate. The designated representative shall submit the following data: (a) Current allowable SO2 emissions rate of the combustion source, expressed in lbs/mmBtu, which shall be the most...

The influence of perforation of foil reactors on greenhouse gas emission rates during aerobic biostabilization of the undersize fraction of municipal wastes.

PubMed

Stegenta, Sylwia; Dębowski, Marcin; Bukowski, Przemysław; Randerson, Peter F; Białowiec, Andrzej

2018-02-01

The opinion, that the use of foil reactors for the aerobic biostabilization of municipal wastes is not a valid method, due to vulnerability to perforation, and risk of uncontrolled release of exhaust gasses, was verified. This study aimed to determine the intensity of greenhouse gas (GHG) emissions to the atmosphere from the surface of foil reactors in relation to the extent of foil surface perforation. Three scenarios were tested: intact (airtight) foil reactor, perforated foil reactor, and torn foil reactor. Each experimental variant was triplicated, and the duration of each experiment cycle was 5 weeks. Temperature measurements demonstrated a significant decrease in temperature of the biostabilization in the torn reactor. The highest emissions of CO 2 , CO and SO 2 were observed at the beginning of the process, and mostly in the torn reactor. During the whole experiment, observed emissions of CO, H 2 S, NO, NO 2 , and SO 2 were at a very low level which in extreme cases did not exceed 0.25 mg t -1 .h -1 (emission of gasses mass unit per waste mass unit per unit time). The lowest average emissions of greenhouse gases were determined in the case of the intact reactor, which shows that maintaining the foil reactors in an airtight condition during the process is extremely important. Copyright © 2017 Elsevier Ltd. All rights reserved.

The ion chemistry, seasonal cycle, and sources of PM 2.5 and TSP aerosol in Shanghai

NASA Astrophysics Data System (ADS)

Wang, Ying; Zhuang, Guoshun; Zhang, Xingying; Huang, Kan; Xu, Chang; Tang, Aohan; Chen, Jianmin; An, Zhisheng

Daily total suspended particulate (TSP), particle size smaller than 100 μm and particle size smaller than 2.5 μm (PM 2.5) aerosol samples were collected at two sites in Shanghai in four seasons from September 2003 to January 2005. Concentrations of the water-soluble ions (SO 42-, NO 3-, Cl -, F -, PO 43-, HCOO -, CH 3COO -, NO 2-, MSA, C 2O 42-, NH 4+, Ca 2+, Na +, K +, Mg 2+) were measured for a total of 202 samples. Daily TSP and PM 2.5 mass concentrations ranged from 66.1 to 666.8 μg m -3 and 17.8 to 217.9 μg m -3, with annual average concentrations of 230.5 and 94.6 μg m -3, respectively. The sum of ions contributed an average of 26% and 32% of TSP and PM 2.5 mass concentrations, respectively. In PM 2.5, the concentration of the major ions followed the order of SO 42->NO 3->NH 4+>Cl ->Ca 2+>K +, while in TSP was SO 42->NO 3->Cl ->Ca 2+>NH 4+>Na +. These major ions were mainly in the form of (NH 4) 2SO 4, Ca(NO 3) 2, CaCl 2, and CaSO 4 in aerosol particles. The aerosol was slightly acidic in the fine particle size range, and alkaline in the coarse mode. Seasonal variation of ion concentrations was significant, with the highest concentrations observed in winter and spring and the lowest in summer and autumn. Three types of air masses, i.e. marine, mixing, and continental, were frequently observed, and their distribution in four seasons might result in the clear seasonal variation. It is Shanghai that has the highest NO 3-/SO 42- value among all of those cities in China, indicating that as the biggest city in China the mobile source of the air pollution becomes more and more predominant. However, stationary emissions were still the dominant source in Shanghai indicated by the NO 3-/SO 42- ratio of lower than 1. The formation of NO 3- was largely from the gas-phase photochemical reaction in the cold season, and from the heterogeneous reaction in the warm season, while the formation of SO 42- might be from the heterogeneous reaction in the entire year round. NH 4+, K +, Cl -, NO 3-, and SO 42- were mainly influenced by the anthropogenic emissions in land, meanwhile Cl - and SO 42- might be partly influenced by the sea. Na +, Mg 2+, and Ca 2+ were derived from both inland crustal and marine sources. Chloride depletion was found especially in summer. The air pollution in Shanghai has proved to be under the influence of both the local emissions and the long-range transport from outside areas.

Sensitivity of OMI SO2 measurements to variable eruptive behaviour at Soufrière Hills Volcano, Montserrat

NASA Astrophysics Data System (ADS)

Hayer, C. S.; Wadge, G.; Edmonds, M.; Christopher, T.

2016-02-01

Since 2004, the satellite-borne Ozone Mapping Instrument (OMI) has observed sulphur dioxide (SO2) plumes during both quiescence and effusive eruptive activity at Soufrière Hills Volcano, Montserrat. On average, OMI detected a SO2 plume 4-6 times more frequently during effusive periods than during quiescence in the 2008-2010 period. The increased ability of OMI to detect SO2 during eruptive periods is mainly due to an increase in plume altitude rather than a higher SO2 emission rate. Three styles of eruptive activity cause thermal lofting of gases (Vulcanian explosions; pyroclastic flows; a hot lava dome) and the resultant plume altitudes are estimated from observations and models. Most lofting plumes from Soufrière Hills are derived from hot domes and pyroclastic flows. Although Vulcanian explosions produced the largest plumes, some produced only negligible SO2 signals detected by OMI. OMI is most valuable for monitoring purposes at this volcano during periods of lava dome growth and during explosive activity.

Emissions from miombo woodland and dambo grassland savanna fires

NASA Astrophysics Data System (ADS)

Sinha, Parikhit; Hobbs, Peter V.; Yokelson, Robert J.; Blake, Donald R.; Gao, Song; Kirchstetter, Thomas W.

2004-06-01

Airborne measurements of trace gases and particles over and downwind of two prescribed savanna fires in Zambia are described. The measurements include profiles through the smoke plumes of condensation nucleus concentrations and normalized excess mixing ratios of particles and gases, emission factors for 42 trace gases and seven particulate species, and vertical profiles of ambient conditions. The fires were ignited in plots of miombo woodland savanna, the most prevalent savanna type in southern Africa, and dambo grassland savanna, an important enclave of miombo woodland ecosystems. Emission factors for the two fires are combined with measurements of fuel loading, combustion factors, and burned area (derived from satellite burn scar retrievals) to estimate the emissions of trace gases and particles from woodland and grassland savanna fires in Zambia and southern Africa during the dry season (May-October) of 2000. It is estimated that the emissions of CO2, CO, total hydrocarbons, nitrogen oxides (NOx as NO), sulfur dioxide (SO2), formaldehyde, methyl bromide, total particulate matter, and black carbon from woodland and grassland savanna fires during the dry season of 2000 in southern Africa contributed 12.3%, 12.6%, 5.9%, 10.3%, 7.5%, 24.2%, 2.8%, 17.5%, and 11.1%, respectively, of the average annual emissions from all types of savanna fires worldwide. In 2000 the average annual emissions of methane, ethane, ethene, acetylene, propene, formaldehyde, methanol, and acetic acid from the use of biofuels in Zambia were comparable to or exceeded dry season emissions of these species from woodland and grassland savanna fires in Zambia.

Emissions from Miombo Woodland and Dambo Grassland Savanna Fires

NASA Technical Reports Server (NTRS)

Sinha, Parikhit; Hobbs, Peter V.; Yokelson, Robert J.; Blake, Donald R.; Gao, Song; Kirchstetter, Thomas W.

2004-01-01

Airborne measurements of trace gases and particles over and downwind of two prescribed savanna fires in Zambia are described. The measurements include profiles through the smoke plumes of condensation nucleus concentrations and normalized excess mixing ratios of particles and gases, emission factors for 42 trace gases and seven particulate species, and vertical profiles of ambient conditions. The fires were ignited in plots of miombo woodland savanna, the most prevalent savanna type in southern Africa, and dambo grassland savanna, an important enclave of miombo woodland ecosystems. Emission factors for the two fires are combined with measurements of fuel loading, combustion factors, and burned area (derived from satellite burn scar retrievals) to estimate the emissions of trace gases and particles from woodland and grassland savanna fires in Zambia and southern Africa during the dry season (May-October) of 2000. It is estimated that the emissions of CO2, CO, total hydrocarbons, nitrogen oxides (NOx as NO), sulfur dioxide (SO2), formaldehyde, methyl bromide, total particulate matter, and black carbon from woodland and grassland savanna fires during the dry season of 2000 in southern Africa contributed 12.3%, 12.6%, 5.9%, 10.3%, 7.5%, 24.2%, 2.8%, 17.5%, and 11.1%, respectively, of the average annual emissions from all types of savanna fires worldwide. In 2000 the average annual emissions of methane, ethane, ethene, acetylene, propene, formaldehyde, methanol, and acetic acid from the use of biofuels in Zambia were comparable to or exceeded dry season emissions of these species from woodland and grassland savanna fires in Zambia.

Effect of an acidifying diet combined with zeolite and slight protein reduction on air emissions from laying hens of different ages.

PubMed

Wu-Haan, W; Powers, W J; Angel, C R; Hale, C E; Applegate, T J

2007-01-01

The objectives of the study were to evaluate the effectiveness of a reduced-emission (RE) diet containing 6.9% of a CaSO(4)-zeolite mixture and slightly reduced CP to 21-, 38-, and 59-wk-old Hy-Line W-36 hens (trials 1, 2, and 3, respectively) on egg production and emissions of NH(3), H(2)S, NO, NO(2), CO(2), CH(4), and non-CH(4) total hydrocarbons as compared with feeding a commercial (CM) diet. At each age, 640 hens were allocated, randomly to 8 environmental chambers for a 3-wk period. On an analyzed basis, the CM diet contained 18.0, 17.0, and 16.2% CP and 0.25, 0.18, and 0.20% S in trials 1, 2, and 3, and the RE diet contained 17.0, 15.5, and 15.6% CP and 0.99, 1.20, and 1.10% S in trials 1, 2, and 3. Diets were formulated to contain similar Ca and P contents. Average daily egg weight (56.3 g), average daily egg production (81%), average daily feed intake (92.4 g), and BW change (23.5 g), across ages, were unaffected by diet (P > 0.05) over the study period. Age effects were observed for all performance variables and NH(3) emissions (P < 0.05). In trials 1, 2, and 3, daily NH(3) emissions from hens fed the RE diets (185.5, 312.2, and 333.5 mg/bird) were less than emissions from hens fed the CM diet (255.1, 560.6, and 616.3 mg/bird; P < 0.01). Daily emissions of H(2)S across trials from hens fed the RE diet were 4.08 mg/bird compared with 1.32 mg/bird from hens fed the CM diet (P < 0.01). Diet (P < 0.05) and age (P < 0.05) affected emissions of CO(2) and CH(4). A diet effect (P < 0.01) on NO emissions was observed. No diet or age effects (P > 0.05) were observed for NO(2) or non-CH(4) total hydrocarbons. Results demonstrated that diet and layer age influence air emissions from poultry operations.

40 CFR 51.125 - Emissions reporting requirements for SIP revisions relating to budgets for SO2 and NOX emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... SIP revisions relating to budgets for SO2 and NOX emissions. 51.125 Section 51.125 Protection of... SIP revisions relating to budgets for SO2 and NOX emissions. (a) For its transport SIP revision under § 51.123 and/or 51.124, each State must submit to EPA SO2 and/or NOX emissions data as described in...

Study of meteorological aspects and urban concentration of SO2 in atmospheric environment of La Plata, Argentina.

PubMed

Ratto, Gustavo; Videla, Fabián; Almandos, J Reyna; Maronna, Ricardo; Schinca, Daniel

2006-10-01

This article presents and discusses SO(2) (ppbv) concentration measurements combined with meteorological data (mainly wind speed and direction) for a five-year campaign (1996 to 2000), in a site near an oil refinery plant close to the city of La Plata and surroundings (aprox. 740.000 inh.), considered one of the six most affected cities by air pollution in the country. Since there is no monitoring network in the area, the obtained results should be considered as medium term accumulated data that enables to determine trends by analyzing together gas concentrations and meteorological parameters. Preliminary characterization of the behaviour of the predominant winds of the region in relation with potential atmospheric gas pollutants from seasonal wind roses is possible to carry out from the data. These results are complemented with monthly averaged SO(2) measurements. In particular, for year 2000, pollutant roses were determined which enable predictions about contamination emission sources. As a general result we can state that there is a clear increase in annual SO(2) concentration and that the selected site should be considered as a key site for future survey monitoring network deployment. Annual SO(2) average concentration and prevailing seasonal winds determined in this work, together with the potential health impact of SO(2) reveals the need for a comprehensive and systematic study involving particulate matter an other basic pollutant gases.

40 CFR 97.254 - Compliance with CAIR SO2 emissions limitation.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Compliance with CAIR SO2 emissions... PROGRAMS (CONTINUED) FEDERAL NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS CAIR SO2 Allowance Tracking System § 97.254 Compliance with CAIR SO2 emissions limitation. (a) Allowance transfer...

40 CFR 96.254 - Compliance with CAIR SO2 emissions limitation.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Compliance with CAIR SO2 emissions... PROGRAMS (CONTINUED) NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR SO2 Allowance Tracking System § 96.254 Compliance with CAIR SO2 emissions limitation...

Global and regional emissions estimates of 1,1-difluoroethane (HFC-152a, CH3CHF2) from in situ and air archive observations

NASA Astrophysics Data System (ADS)

Simmonds, P. G.; Rigby, M.; Manning, A. J.; Lunt, M. F.; O'Doherty, S.; McCulloch, A.; Fraser, P. J.; Henne, S.; Vollmer, M. K.; Mühle, J.; Weiss, R. F.; Salameh, P. K.; Young, D.; Reimann, S.; Wenger, A.; Arnold, T.; Harth, C. M.; Krummel, P. B.; Steele, L. P.; Dunse, B. L.; Miller, B. R.; Lunder, C. R.; Hermansen, O.; Schmidbauer, N.; Saito, T.; Yokouchi, Y.; Park, S.; Li, S.; Yao, B.; Zhou, L. X.; Arduini, J.; Maione, M.; Wang, R. H. J.; Ivy, D.; Prinn, R. G.

2016-01-01

High frequency, in situ observations from 11 globally distributed sites for the period 1994-2014 and archived air measurements dating from 1978 onward have been used to determine the global growth rate of 1,1-difluoroethane (HFC-152a, CH3CHF2). These observations have been combined with a range of atmospheric transport models to derive global emission estimates in a top-down approach. HFC-152a is a greenhouse gas with a short atmospheric lifetime of about 1.5 years. Since it does not contain chlorine or bromine, HFC-152a makes no direct contribution to the destruction of stratospheric ozone and is therefore used as a substitute for the ozone depleting chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs). The concentration of HFC-152a has grown substantially since the first direct measurements in 1994, reaching a maximum annual global growth rate of 0.84 ± 0.05 ppt yr-1 in 2006, implying a substantial increase in emissions up to 2006. However, since 2007, the annual rate of growth has slowed to 0.38 ± 0.04 ppt yr-1 in 2010 with a further decline to an annual average rate of growth in 2013-2014 of -0.06 ± 0.05 ppt yr-1. The annual average Northern Hemisphere (NH) mole fraction in 1994 was 1.2 ppt rising to an annual average mole fraction of 10.1 ppt in 2014. Average annual mole fractions in the Southern Hemisphere (SH) in 1998 and 2014 were 0.84 and 4.5 ppt, respectively. We estimate global emissions of HFC-152a have risen from 7.3 ± 5.6 Gg yr-1 in 1994 to a maximum of 54.4 ± 17.1 Gg yr-1 in 2011, declining to 52.5 ± 20.1 Gg yr-1 in 2014 or 7.2 ± 2.8 Tg-CO2 eq yr-1. Analysis of mole fraction enhancements above regional background atmospheric levels suggests substantial emissions from North America, Asia, and Europe. Global HFC emissions (so called "bottom up" emissions) reported by the United Nations Framework Convention on Climate Change (UNFCCC) are based on cumulative national emission data reported to the UNFCCC, which in turn are based on national consumption data. There appears to be a significant underestimate ( > 20 Gg) of "bottom-up" reported emissions of HFC-152a, possibly arising from largely underestimated USA emissions and undeclared Asian emissions.

PM2.5 and ultrafine particulate matter emissions from natural gas-fired turbine for power generation

NASA Astrophysics Data System (ADS)

Brewer, Eli; Li, Yang; Finken, Bob; Quartucy, Greg; Muzio, Lawrence; Baez, Al; Garibay, Mike; Jung, Heejung S.

2016-04-01

The generation of electricity from natural gas-fired turbines has increased more than 200% since 2003. In 2007 the South Coast Air Quality Management District (SCAQMD) funded a project to identify control strategies and technologies for PM2.5 and ultrafine emissions from natural gas-fired turbine power plants and test at pilot scale advanced PM2.5 technologies to reduce emissions from these gas turbine-based power plants. This prompted a study of the exhaust from new facilities to better understand air pollution in California. To characterize the emissions from new natural gas turbines, a series of tests were performed on a GE LMS100 gas turbine located at the Walnut Creek Energy Park in August 2013. These tests included particulate matter less than 2.5 μm in diameter (PM2.5) and wet chemical tests for SO2/SO3 and NH3, as well as ultrafine (less than 100 nm in diameter) particulate matter measurements. After turbine exhaust was diluted sevenfold with filtered air, particle concentrations in the 10-300 nm size range were approximately two orders of magnitude higher than those in the ambient air and those in the 2-3 nm size range were up to four orders of magnitude higher. This study also found that ammonia emissions were higher than expected, but in compliance with permit conditions. This was possibly due to an ammonia imbalance entering the catalyst, some flue gas bypassing the catalyst, or not enough catalyst volume. SO3 accounted for an average of 23% of the total sulfur oxides emissions measured. While some of the SO3 is formed in the combustion process, it is likely that the majority formed as the SO2 in the combustion products passed across the oxidizing CO catalyst and SCR catalyst. The 100 MW turbine sampled in this study emitted particle loadings of 3.63E-04 lb/MMBtu based on Methods 5.1/201A and 1.07E-04 lb/MMBtu based on SMPS method, which are similar to those previously measured from turbines in the SCAQMD area (FERCo et al., 2014), however, the turbine exhaust contained orders of magnitude higher particles than ambient air.

SMED - Sulphur MEditerranean Dispersion

NASA Astrophysics Data System (ADS)

Salerno, Giuseppe G.; Sellitto, Pasquale; Corradini, Stefano; Di Sarra, Alcide Giorgio; Merucci, Luca; Caltabiano, Tommaso; La Spina, Alessandro

2016-04-01

Emissions of volcanic gases and particles can have profound impacts on terrestrial environment, atmospheric composition, climate forcing, and then on human health at various temporal and spatial scales. Volcanic emissions have been identified as one of the largest sources of uncertainty in our understanding of recent climate change trends. In particular, a primary role is acted by sulphur dioxide emission due to its conversion to volcanic sulphate aerosol via atmospheric oxidation. Aerosols may play a key role in the radiative budget and then in photochemistry and tropospheric composition. Mt. Etna is one of the most prodigious and persistent emitters of gasses and particles on Earth, accounting for about 10% of global average volcanic emission of CO2 and SO2. Its sulphur emissions stand for 0.7 × 106 t S/yr9 and then about 10 times bigger than anthropogenic sulphur emissions in the Mediterranean area. Centrepiece of the SMED project is to advance the understanding of volcanogenic sulphur dioxide and sulphate aerosol particles dispersion and radiative impact on the downwind Mediterranean region by an integrated approach between ground- and space-based observations and modelling. Research is addressed by exploring the potential relationship between proximal SO2 flux and aerosol measured remotely in the volcanic plume of Mt. Etna between 2000 and 2014 and distal aerosol ground-based measurements in Lampedusa, Greece, and Malta from AERONET network. Ground data are combined with satellite multispectral polar and geostationary imagers able to detect and retrieve volcanic ash and SO2. The high repetition time of SEVIRI (15 minutes) will ensure the potential opportunity to follow the entire evolution of the volcanic cloud, while, the higher spatial resolution of MODIS (1x1 km2), are exploited for investigating the probability to retrieve volcanic SO2 abundances from passive degassing. Ground and space observations are complemented with atmospheric Lagrangian model (FLEXPART) for inspecting the transport and dispersion of volcanic plume over the Mediterranean region and the radiative transfer model UVSPEC for inspecting radiative forcing of volcanic sulphates over the Mediterranean region. Preliminary results exploring the Central-Southern Mediterranean, reveal that thought only 2 -7% of Mt. Etna's volcanic clouds disperses over this region, volcanic impact might be relevant in both SO2 abundances and sulphate-volcanogenic derived aerosol.

40 CFR 75.16 - Special provisions for monitoring emissions from common, bypass, and multiple stacks for SO2...

Code of Federal Regulations, 2011 CFR

2011-07-01

... emissions from common, bypass, and multiple stacks for SO2 emissions and heat input determinations. 75.16... emissions from common, bypass, and multiple stacks for SO2 emissions and heat input determinations. (a... by the Administrator, such that these emissions are not underestimated. (e) Heat input rate. The...

40 CFR 75.16 - Special provisions for monitoring emissions from common, bypass, and multiple stacks for SO 2...

Code of Federal Regulations, 2013 CFR

2013-07-01

... emissions from common, bypass, and multiple stacks for SO 2 emissions and heat input determinations. 75.16... emissions from common, bypass, and multiple stacks for SO 2 emissions and heat input determinations. (a... by the Administrator, such that these emissions are not underestimated. (e) Heat input rate. The...

40 CFR 75.16 - Special provisions for monitoring emissions from common, bypass, and multiple stacks for SO2...

Code of Federal Regulations, 2012 CFR

2012-07-01

... emissions from common, bypass, and multiple stacks for SO2 emissions and heat input determinations. 75.16... emissions from common, bypass, and multiple stacks for SO2 emissions and heat input determinations. (a... by the Administrator, such that these emissions are not underestimated. (e) Heat input rate. The...

40 CFR 75.16 - Special provisions for monitoring emissions from common, bypass, and multiple stacks for SO 2...

Code of Federal Regulations, 2014 CFR

2014-07-01

... emissions from common, bypass, and multiple stacks for SO 2 emissions and heat input determinations. 75.16... emissions from common, bypass, and multiple stacks for SO 2 emissions and heat input determinations. (a... by the Administrator, such that these emissions are not underestimated. (e) Heat input rate. The...

Multi-source SO2 emission retrievals and consistency of satellite and surface measurements with reported emissions

NASA Astrophysics Data System (ADS)

Fioletov, Vitali; McLinden, Chris A.; Kharol, Shailesh K.; Krotkov, Nickolay A.; Li, Can; Joiner, Joanna; Moran, Michael D.; Vet, Robert; Visschedijk, Antoon J. H.; Denier van der Gon, Hugo A. C.

2017-10-01

Reported sulfur dioxide (SO2) emissions from US and Canadian sources have declined dramatically since the 1990s as a result of emission control measures. Observations from the Ozone Monitoring Instrument (OMI) on NASA's Aura satellite and ground-based in situ measurements are examined to verify whether the observed changes from SO2 abundance measurements are quantitatively consistent with the reported changes in emissions. To make this connection, a new method to link SO2 emissions and satellite SO2 measurements was developed. The method is based on fitting satellite SO2 vertical column densities (VCDs) to a set of functions of OMI pixel coordinates and wind speeds, where each function represents a statistical model of a plume from a single point source. The concept is first demonstrated using sources in North America and then applied to Europe. The correlation coefficient between OMI-measured VCDs (with a local bias removed) and SO2 VCDs derived here using reported emissions for 1° by 1° gridded data is 0.91 and the best-fit line has a slope near unity, confirming a very good agreement between observed SO2 VCDs and reported emissions. Having demonstrated their consistency, seasonal and annual mean SO2 VCD distributions are calculated, based on reported point-source emissions for the period 1980-2015, as would have been seen by OMI. This consistency is further substantiated as the emission-derived VCDs also show a high correlation with annual mean SO2 surface concentrations at 50 regional monitoring stations.

A new approach for monthly updates of anthropogenic sulfur dioxide emissions from space: Application to China and implications for air quality forecasts

NASA Astrophysics Data System (ADS)

Wang, Yi; Wang, Jun; Xu, Xiaoguang; Henze, Daven K.; Wang, Yuxuan; Qu, Zhen

2016-09-01

SO2 emissions, the largest source of anthropogenic aerosols, can respond rapidly to economic and policy driven changes. However, bottom-up SO2 inventories have inherent limitations owing to 24-48 months latency and lack of month-to-month variation in emissions (especially in developing countries). This study develops a new approach that integrates Ozone Monitoring Instrument (OMI) SO2 satellite measurements and GEOS-Chem adjoint model simulations to constrain monthly anthropogenic SO2 emissions. The approach's effectiveness is demonstrated for 14 months in East Asia; resultant posterior emissions not only capture a 20% SO2 emission reduction in Beijing during the 2008 Olympic Games but also improve agreement between modeled and in situ surface measurements. Further analysis reveals that posterior emissions estimates, compared to the prior, lead to significant improvements in forecasting monthly surface and columnar SO2. With the pending availability of geostationary measurements of tropospheric composition, we show that it may soon be possible to rapidly constrain SO2 emissions and associated air quality predictions at fine spatiotemporal scales.

78 FR 15376 - Notice of Lodging of Proposed Consent Decree Amendment Under the Clean Air Act; the Clean Water...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-11

... Act; the Clean Water Act; the Resource Conservation and Recovery Act; the Emergency Planning and...'') for violations of the Clean Air Act, the Resource Conservation and Recovery Act, the Clean Water Act... Herculaneum Lead Smelter Facility 12-month rolling average limit for SO 2 emissions and the 12-month rolling...

Global and regional emissions estimates of 1,1-difluoroethane (HFC-152a, CH3CHF2) from in situ and air archive observations

NASA Astrophysics Data System (ADS)

Simmonds, P. G.; Rigby, M.; Manning, A. J.; Lunt, M. F.; O'Doherty, S.; Young, D.; McCulloch, A.; Fraser, P. J.; Henne, S.; Vollmer, M. K.; Reimann, S.; Wenger, A.; Mühle, J.; Harth, C. M.; Salameh, P. K.; Arnold, T.; Weiss, R. F.; Krummel, P. B.; Steele, L. P.; Dunse, B. L.; Miller, B. R.; Lunder, C. R.; Hermansen, O.; Schmidbauer, N.; Saito, T.; Yokouchi, Y.; Park, S.; Li, S.; Yao, B.; Zhou, L. X.; Arduini, J.; Maione, M.; Wang, R. H. J.; Prinn, R. G.

2015-08-01

High frequency, ground-based, in situ measurements from eleven globally-distributed sites covering 1994-2014, combined with measurements of archived air samples dating from 1978 onward and atmospheric transport models, have been used to estimate the growth of 1,1-difluoroethane (HFC-152a, CH3CHF2) mole fractions in the atmosphere and the global emissions required to derive the observed growth. HFC-152a is a significant greenhouse gas but since it does not contain chlorine or bromine, HFC-152a makes no direct contribution to the destruction of stratospheric ozone and is therefore used as a substitute for the ozone depleting chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs). HFC-152a has exhibited substantial atmospheric growth since the first measurements reaching a maximum annualised global growth rate of 0.81 ± 0.05 ppt yr-1 in 2006, implying a substantial increase in emissions up to 2006. However, since 2007, the annualised rate of growth has slowed to 0.38 ± 0.04 ppt yr-1 in 2010 with a further decline to an average rate of change in 2013-2014 of -0.06 ± 0.05 ppt yr-1. The average Northern Hemisphere (NH) mixing ratio in 1994 was 1.2 ppt rising to a mixing ratio of 10.2 ppt in December 2014. Average annual mixing ratios in the Southern Hemisphere (SH) in 1994 and 2014 were 0.34 and 4.4 ppt, respectively. We estimate global emissions of HFC-152a have risen from 7.3 ± 5.6 Gg yr-1 in 1994 to a maximum of 54.4 ± 17.1 Gg yr-1 in 2011, declining to 52.5 ± 20.1 Gg yr-1 in 2014 or 7.2 ± 2.8 Tg-CO2 eq yr-1. Analysis of mixing ratio enhancements above regional background atmospheric levels suggests substantial emissions from North America, Asia and Europe. Global HFC emissions (so called "bottom up" emissions) reported by the United Nations Framework Convention on Climate Change (UNFCCC) are based on cumulative national emission data reported to the UNFCCC, which in turn are based on national consumption data. There appears to be a significant underestimate of "bottom-up" global emissions of HFC-152a, possibly arising from largely underestimated USA emissions and undeclared Asian emissions.

Top-down NOx and SO2 emissions simultaneously estimated from different OMI retrievals and inversion frameworks

NASA Astrophysics Data System (ADS)

Qu, Z.; Henze, D. K.; Wang, J.; Xu, X.; Wang, Y.

2017-12-01

Quantifying emissions trends of nitrogen oxides (NOx) and sulfur dioxide (SO2) is important for improving understanding of air pollution and the effectiveness of emission control strategies. We estimate long-term (2005-2016) global (2° x 2.5° resolution) and regional (North America and East Asia at 0.5° x 0.667° resolution) NOx emissions using a recently developed hybrid (mass-balance / 4D-Var) method with GEOS-Chem. NASA standard product and DOMINO retrievals of NO2 column are both used to constrain emissions; comparison of these results provides insight into regions where trends are most robust with respect to retrieval uncertainties, and highlights regions where seemingly significant trends are retrieval-specific. To incorporate chemical interactions among species, we extend our hybrid method to assimilate NO2 and SO2 observations and optimize NOx and SO2 emissions simultaneously. Due to chemical interactions, inclusion of SO2 observations leads to 30% grid-scale differences in posterior NOx emissions compared to those constrained only by NO2 observations. When assimilating and optimizing both species in pseudo observation tests, the sum of the normalized mean squared error (compared to the true emissions) of NOx and SO2 posterior emissions are 54-63% smaller than when observing/constraining a single species. NOx and SO2 emissions are also correlated through the amount of fuel combustion. To incorporate this correlation into the inversion, we optimize seven sector-specific emission scaling factors, including industry, energy, residential, aviation, transportation, shipping and agriculture. We compare posterior emissions from inversions optimizing only species' emissions, only sector-based emissions, and both species' and sector-based emissions. In situ measurements of NOx and SO2 are applied to evaluate the performance of these inversions. The impacts of the inversion on PM2.5 and O3 concentrations and premature deaths are also evaluated.

PM2.5 emissions and source profiles from open burning of crop residues

NASA Astrophysics Data System (ADS)

Ni, Haiyan; Tian, Jie; Wang, Xiaoliang; Wang, Qiyuan; Han, Yongming; Cao, Junji; Long, Xin; Chen, L.-W. Antony; Chow, Judith C.; Watson, John G.; Huang, Ru-Jin; Dusek, Ulrike

2017-11-01

Wheat straw, rice straw, and corn stalks, the major agricultural crop residues in China, were collected from six major crop producing regions, and burned in a laboratory combustion chamber to determine PM2.5 source profiles and speciated emission factors (EFs). Organic carbon (OC) and water-soluble ions (the sum of NH4+, Na+, K+, Mg2+, Ca2+, Cl-, NO3- and SO42-) are major constituents, accounting for 43.1 ± 8.3% and 27.4 ± 14.6% of PM2.5, respectively. Chloride (Cl-) and water-soluble potassium (K+) are the dominant ionic species, with an average abundance of 14.5 ± 8.2% and 6.4 ± 4.4% in PM2.5, respectively. The average K+/Cl- ratio is ∼0.4, lower than 2.8-5.4 for wood combustion. Similarity measures (i.e., Student's t-test, coefficient of divergence, correlations, and residual to uncertainty ratios) show the crop profiles are too similar for the species measured to be resolved from one another by receptor modeling. The largest difference was found between rice straw and corn stalk emissions, with higher OC and lower Cl- and K+ abundances (50%, 8%, and 3% of PM2.5, respectively) for corn stalks; lower OC, and higher Cl- and K+ abundances (38%, 21%, and 10% of PM2.5, respectively) for rice straw. Average EFs were 4.8 ± 3.1 g kg-1 for OC, 1.3 ± 0.8 g kg-1 for Cl- and 0.59 ± 0.56 g kg-1 for K+. Flaming and smoldering combustions resulted in an average modified combustion efficiency (MCE) of 0.92 ± 0.03, and low elemental carbon (EC) EFs (0.24 ± 0.12 g kg-1). OC/EC ratios from individual source profiles ranged from 12.9 ± 4.3 for rice straw to 24.1 ± 13.5 for wheat straw. The average K+/EC ratio was 2.4 ± 1.5, an order of magnitude higher than those from residential wood combustion (0.2-0.76). Elevated emission rates were found for OC (387 Gg yr-1) and Cl- (122 Gg yr-1), accounting for 44% and 14% of 2008 PM2.5 emissions in China.

Effectiveness of SO2 emission control policy on power plants in the Yangtze River Delta, China-post-assessment of the 11th Five-Year Plan.

PubMed

Tan, Jiani; Fu, Joshua S; Huang, Kan; Yang, Cheng-En; Zhuang, Guoshun; Sun, Jian

2017-03-01

Facing the air pollution problems in China, emission control strategies have been implemented within the framework of national Five-Year Plan (FYP). According to the lack of post-assessment studies in the literature, this study assessed the effectiveness of the SO 2 emission control policies on power plants after the 11th FYP (2006-2010) by modeling emission control scenarios. The idealized emission control policy (the PS90 scenario with assumption of 90% SO 2 emission reduction from power plants) could reduce the SO 2 and SO 4 2- concentrations by about 51 and 14%, respectively, over the Yangtze River Delta region. While the actual emission control condition (the P2010 scenario based on the actual emissions from power plants in 2010) demonstrated that the actual reduction benefits were 30% of SO 2 and 9% of SO 4 2- . On the city scale, the P2010 scenario imposed positive benefits on Shanghai, Nanjing, Nantong, and Hangzhou with SO 2 reductions of about 55, 12, 30, and 21%, respectively, while an 11% increase of SO 2 concentration was found in Ningbo. The number of days exceeding China's National Ambient Air Quality Standard of Class I daily SO 2 concentration was estimated to be 75, 52, 7, 77, and 40 days for Shanghai, Nanjing, Nantong, Ningbo, and Hangzhou under the real SO 2 control condition (P2010). The numbers could be decreased by 16, 11, 2, 21, and 11% if the control effect reaches the level of the PS90 scenario. This study serves as a scientific basis to design capable enforcement of emission control strategies in China in the future national plans.

Changes in SO2 and NO2 Pollution over the Past Decade Observed by Aura OMI

NASA Astrophysics Data System (ADS)

Krotkov, N. A.; Li, C.; Lamsal, L. N.; Celarier, E. A.; Marchenko, S. V.; Swartz, W.; Bucsela, E. J.; Fioletov, V.; McLinden, C. A.; Joiner, J.; Bhartia, P. K.; Duncan, B. N.; Dickerson, R. R.

2014-12-01

The Ozone Monitoring Instrument (OMI), a NASA partnership with the Netherlands and Finland, flies on the EOS Aura satellite and uses reflected sunlight to measure two critical atmospheric trace gases, nitrogen dioxide (NO2) and sulfur dioxide (SO2), characterizing daily air quality. Both gases and the secondary pollutants they produce (particulate matter, PM2.5, and tropospheric ozone) are among USEPA designated criteria pollutants, posing serious threats to human health and the environment (e.g., acid rain, plant damage, and reduced visibility). A new generation of the OMI standard SO2 and NO2 products (based on critically improved DOAS spectral fitting for NO2 and innovative Principal Component Analysis method for SO2) provides a valuable dataset for studying anthropogenic pollution on local to global scales. Here we highlight some of the OMI observed long-term changes in air quality over several regions. Over the US, average NO2 and SO2 pollution levels have decreased dramatically as a result of both technological improvements (e.g., catalytic converters on cars) and stricter regulations of emissions. We see continued decline in NO2 and SO2 pollution over Europe. Over China OMI observed a ~ 60% increase in NO2 pollution between 2005 and 2013, despite a temporary reversal of the growing trend due to both 2008 Olympic Games and the economic recession in 2009. Chinese SO2 pollution seems to have stabilized since peaking in 2007, probably due to government efforts to curb SO2 emissions from the power sector. We have also observed large increases in both SO2 and NO2 pollution particularly in Eastern India where a number of new large coal power plants have been built in recent years. We expect that further improvements in the OMI NO2 and SO2 products will allow more robust quantification of long-term trends in local to global air quality.

Sulfur dioxide emissions in China and sulfur trends in East Asia since 2000.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, Z.; Streets, D. G.; Zhang, Q.

2010-01-01

With the rapid development of the economy, the sulfur dioxide (SO{sub 2}) emission from China since 2000 is of increasing concern. In this study, we estimate the annual SO{sub 2} emission in China after 2000 using a technology-based methodology specifically for China. From 2000 to 2006, total SO{sub 2} emission in China increased by 53%, from 21.7 Tg to 33.2 Tg, at an annual growth rate of 7.3%. Emissions from power plants are the main sources of SO{sub 2} in China and they increased from 10.6 Tg to 18.6 Tg in the same period. Geographically, emission from north China increasedmore » by 85%, whereas that from the south increased by only 28%. The emission growth rate slowed around 2005, and emissions began to decrease after 2006 mainly due to the wide application of flue-gas desulfurization (FGD) devices in power plants in response to a new policy of China's government. This paper shows that the trend of estimated SO{sub 2} emission in China is consistent with the trends of SO{sub 2} concentration and acid rain pH and frequency in China, as well as with the increasing trends of background SO{sub 2} and sulfate concentration in East Asia. A longitudinal gradient in the percentage change of urban SO{sub 2} concentration in Japan is found during 2000-2007, indicating that the decrease of urban SO{sub 2} is lower in areas close to the Asian continent. This implies that the transport of increasing SO{sub 2} from the Asian continent partially counteracts the local reduction of SO{sub 2} emission downwind. The aerosol optical depth (AOD) products of Moderate Resolution Imaging Spectroradiometer (MODIS) are found to be highly correlated with the surface solar radiation (SSR) measurements in East Asia. Using MODIS AOD data as a surrogate of SSR, we found that China and East Asia excluding Japan underwent a continuous dimming after 2000, which is in line with the dramatic increase in SO{sub 2} emission in East Asia. The trends of AOD from both satellite retrievals and model over East Asia are also consistent with the trend of SO2 emission in China, especially during the second half of the year, when sulfur contributes the largest fraction of AOD. The arrested growth in SO{sub 2} emissions since 2006 is also reflected in the decreasing trends of SO{sub 2} and SO{sub 4}{sup 2-} concentrations, acid rain pH values and frequencies, and AOD over East Asia.« less

Fine and ultrafine particles in small cities. A case study in the south of Europe.

PubMed

Aranda, A; Díaz-de-Mera, Y; Notario, A; Rodríguez, D; Rodríguez, A

2015-12-01

Ultrafine particles, PM2.5 and PM10 mass concentration, NO(x), Ozone, SO2, back-trajectories of air masses and meteorological parameters were studied in a small city over the period February, 2013 to June, 2014. The profiles of PM2.5 and PM10 particles are provided, showing averaged values of 16.6 and 21.6 μg m(-3), respectively. The average number concentration of particles in the range of diameters 5.6-560 nm was 1.2 × 10(4)#/ cm(3) with contributions of 42, 51 and 7% from the nucleation, Aitken, and accumulation modes, respectively. The average number concentration of ultrafine particles was 1.1 × 10(4)#/ cm(3). The results obtained are evidence for some differences in the pollution of ambient air by particles in the studied town in comparison to bigger cities. Nucleation events due to emissions from the city were not observed, and traffic emissions amount to a small contribution to PM2.5 and PM10 particles which are mainly due to crustal origin from the arid surroundings and long-range transport from the Sahara Desert.

SO2 Emissions and Lifetimes: Estimates from Inverse Modeling Using In Situ and Global, Space-Based (SCIAMACHY and OMI) Observations

NASA Technical Reports Server (NTRS)

Lee, Chulkyu; Martin Randall V.; vanDonkelaar, Aaron; Lee, Hanlim; Dickerson, RUssell R.; Hains, Jennifer C.; Krotkov, Nickolay; Richter, Andreas; Vinnikov, Konstantine; Schwab, James J.

2011-01-01

Top-down constraints on global sulfur dioxide (SO2) emissions are inferred through inverse modeling using SO2 column observations from two satellite instruments (SCIAMACHY and OMI). We first evaluated the S02 column observations with surface SO2 measurements by applying local scaling factors from a global chemical transport model (GEOS-Chem) to SO2 columns retrieved from the satellite instruments. The resulting annual mean surface SO2 mixing ratios for 2006 exhibit a significant spatial correlation (r=0.86, slope=0.91 for SCIAMACHY and r=0.80, slope = 0.79 for OMI) with coincident in situ measurements from monitoring networks throughout the United States and Canada. We evaluate the GEOS-Chem simulation of the SO2 lifetime with that inferred from in situ measurements to verity the applicability of GEOS-Chem for inversion of SO2 columns to emissions. The seasonal mean SO2 lifetime calculated with the GEOS-Chem model over the eastern United States is 13 h in summer and 48 h in winter, compared to lifetimes inferred from in situ measurements of 19 +/- 7 h in summer and 58 +/- 20 h in winter. We apply SO2 columns from SCIAMACHY and OMI to derive a top-down anthropogenic SO2 emission inventory over land by using the local GEOS-Chem relationship between SO2 columns and emissions. There is little seasonal variation in the top-down emissions (<15%) over most major industrial regions providing some confidence in the method. Our global estimate for annual land surface anthropogenic SO2 emissions (52.4 Tg S/yr from SCIAMACHY and 49.9 Tg S / yr from OMI) closely agrees with the bottom-up emissions (54.6 Tg S/yr) in the GEOS-Chem model and exhibits consistency in global distributions with the bottom-up emissions (r = 0.78 for SCIAMACHY, and r = 0.77 for OMI). However, there are significant regional differences.

Emissions of particulate and gaseous pollutants within the Keelung Harbor region of Taiwan.

PubMed

Yu-Peng, Chiung; Lin, Chern-Gyuan; Jong, Tain-Chyuan

2005-10-01

The Keelung port, which is located on the northern tip of Taiwan, right next to the Taipei metropolitan area, is an important international harbor. However, any air pollutants generated from the Keelung port region, immediately travel to the neighboring Keelung city, and greatly impact the residents' daily life and the quality of their environment. This study has investigated and quantified pollution emissions, from the Keelung port region, between 1997 and 2002. Emissions from major air pollution sources were estimated. The estimated results indicated that total TSP (total suspended particles) emissions had significantly increased, from 5221 ton/yr in 1997 to 262 687 ton/yr in 2002, due to the greatly increased volume of sand imported into Keelung Harbor. Quantities of other emissions, such as SO(2), NO(2), CO and HC remained stable and were 440, 207, 78 and 25 ton/yr, respectively, on average, with variations within 7% over the previous six-year period. By examining the emissions from pollution sources, it was found that TSP emissions mainly originated from re-suspension of dust, due to both vehicle movement and the sand unloading process; this accounted for over 99% of the total TSP emissions produced in the port region. About 80% of the total SO(2) emissions originated from the main ships' engines within the Keelung port region, due to the use of fuel with a high sulfur content. In addition, loading/unloading machines within the port region were the major sources of NO(2), CO and HC pollution emissions, which comprised 54, 58 and 66% of the total emissions of these pollutants, respectively. TSP emissions from Keelung port were much higher than from the neighboring Keelung city; hence, alleviating TSP emissions should be the first priority for air pollution reduction within both the port of Keelung and Keelung city.

Observations of Gas Emissions from Cascade Range Volcanoes (USA) using a Portable Real-Time Sensor Package and Evacuated Flasks

NASA Astrophysics Data System (ADS)

Kelly, P. J.; Werner, C. A.; Evans, W.; Ingebritsen, S.; Tucker, D.

2012-12-01

Degassing from most Cascade Range Volcanoes, USA, is characterized by low-temperature hydrothermal emissions. It is important to monitor these emissions as part of a comprehensive monitoring strategy yet access is often difficult and most features are sampled by the USGS only once per year at best. In an effort to increase the sampling frequency of major gas species and in preparation for building permanent, autonomous units, we built a portable sensor package capable of measuring H2O, CO2, SO2, and H2S in volcanic gas plumes. Here we compare results from the portable sensor package with gas analyses from direct samples obtained using a titanium tube and evacuated glass flasks collected at the same time. The sensor package is housed in a small, rugged case, weighs 5 kg, and includes sensors for measuring H2O (0-16 parts per thousand), CO2 (0-5000 ppmv), SO2 (0-100 ppm), and H2S (0-20 ppm) gases. Additional temperature and pressure sensors, a micro air pump, datalogger, and an internal battery are also incorporated. H2O and CO2 are measured using an infrared spectrometer (Licor 840) and sulfur-containing gases are measured using electrochemical sensors equipped with filters to mitigate cross-sensitivities. Data are collected at a 1 Hz sampling rate and can be recorded and displayed in real-time using a netbook computer or can be saved to the onboard datalogger. The data display includes timeseries of H2O, CO2, SO2, and H2S mixing ratios, the four-component bulk composition of the plume, and automated calculation of gas ratios commonly used in volcanic gas monitoring, such as H2O/CO2, CO2/SO2, and CO2/H2S . In the Cascade Range, the sensor package has been tested at Mt. Baker, Mt. St. Helens, Mt. Hood, and in Lassen Volcanic National Park. In each case, the instrument was placed 5 to 30 meters from the fumarole or fumarole field and emissions were sampled for 5 to 30 minutes. No SO2 was detected at any location. At Mt. Hood the sensor package yielded average CO2/H2S ratios from 10 to 16 in fumarole plumes versus flask CO2/H2S ratios (n = 2) of 13 and 16 on 9 July 2011, and on 28 July 2012 the sensor package yielded an average CO2/H2S ratio of 12 versus flask ratios (n = 2) of 13 (both sets of flask samples obtained in the Crater Rock area). At Mt. Baker, the sensor package yielded average CO2/H2S ratios from 19 to 22 whereas flask ratios (n = 3) were higher, from 25 to 32 (both fumarole-plume and flask samples obtained in the Sherman Crater area) on 22 July 2011. The mismatch falls slightly outside expected analytical uncertainty for the sensor package (about 20% relative for CO2/H2S ratios). However, flask samples collected in Sherman Crater in 2006 and 2007 (n = 5) yielded CO2/H2S ratios from 18 to 29, which nearly spans the range of observations in 2011. Therefore, one explanation for the small mismatch between the results of the sensor package and direct samples is that the sensor package measures bulk plume compositions that may integrate emissions from several chemically distinct fumaroles and the direct samples better represent the composition of discrete vents. Overall, the sensor package and evacuated flask data show good agreement and demonstrate that the real-time technique is a viable means for monitoring major volcanic gas species.

Multispectral thermal infrared mapping of sulfur dioxide plumes: A case study from the East Rift Zone of Kilauea Volcano, Hawaii

USGS Publications Warehouse

Realmuto, V.J.; Sutton, A.J.; Elias, T.

1997-01-01

The synoptic perspective and rapid mode of data acquisition provided by remote sensing are well suited for the study of volcanic SO2 plumes. In this paper we describe a plume-mapping procedure that is based on image data acquired with NASA's airborne thermal infrared multispectral scanner (TIMS) and apply the procedure to TIMS data collected over the East Rift Zone of Kilauea Volcano, Hawaii, on September 30, 1988. These image data covered the Pu'u 'O'o and Kupaianaha vents and a skylight in the lava tube that was draining the Kupaianaha lava pond. Our estimate of the SO2 emission rate from Pu'u 'O'o (17 - 20 kg s-1) is roughly twice the average of estimates derived from correlation spectrometer (COSPEC) measurements collected 10 days prior to the TIMS overflight (10 kg s-1). The agreement between the TIMS and COSPEC results improves when we compare SO2 burden estimates, which are relatively independent of wind speed. We demonstrate the feasibility of mapping Pu'u 'O'o - scale SO2 plumes from space in anticipation of the 1998 launch of the advanced spaceborne thermal emission and reflectance radiometer (ASTER). Copyright 1997 by the American Geophysical Union.

Impacts of transportation sector emissions on future U.S. air quality in a changing climate. Part I: Projected emissions, simulation design, and model evaluation.

PubMed

Campbell, Patrick; Zhang, Yang; Yan, Fang; Lu, Zifeng; Streets, David

2018-07-01

Emissions from the transportation sector are rapidly changing worldwide; however, the interplay of such emission changes in the face of climate change are not as well understood. This two-part study examines the impact of projected emissions from the U.S. transportation sector (Part I) on ambient air quality in the face of climate change (Part II). In Part I of this study, we describe the methodology and results of a novel Technology Driver Model (see graphical abstract) that includes 1) transportation emission projections (including on-road vehicles, non-road engines, aircraft, rail, and ship) derived from a dynamic technology model that accounts for various technology and policy options under an IPCC emission scenario, and 2) the configuration/evaluation of a dynamically downscaled Weather Research and Forecasting/Community Multiscale Air Quality modeling system. By 2046-2050, the annual domain-average transportation emissions of carbon monoxide (CO), nitrogen oxides (NO x ), volatile organic compounds (VOCs), ammonia (NH 3 ), and sulfur dioxide (SO 2 ) are projected to decrease over the continental U.S. The decreases in gaseous emissions are mainly due to reduced emissions from on-road vehicles and non-road engines, which exhibit spatial and seasonal variations across the U.S. Although particulate matter (PM) emissions widely decrease, some areas in the U.S. experience relatively large increases due to increases in ship emissions. The on-road vehicle emissions dominate the emission changes for CO, NO x , VOC, and NH 3 , while emissions from both the on-road and non-road modes have strong contributions to PM and SO 2 emission changes. The evaluation of the baseline 2005 WRF simulation indicates that annual biases are close to or within the acceptable criteria for meteorological performance in the literature, and there is an overall good agreement in the 2005 CMAQ simulations of chemical variables against both surface and satellite observations. Copyright © 2018 Elsevier Ltd. All rights reserved.

76 FR 79541 - Revisions to Final Response to Petition From New Jersey Regarding SO2

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-22

... Revisions to Final Response to Petition From New Jersey Regarding SO2 Emissions From the Portland Generating... Jersey Regarding SO2 Emissions From the Portland Generating Station (Portland) published November 7, 2011... Final Response to Petition From New Jersey Regarding SO2 Emissions From the Portland Generating Station...

Development of atmospheric acid deposition in China from the 1990s to the 2010s.

PubMed

Yu, Haili; He, Nianpeng; Wang, Qiufeng; Zhu, Jianxing; Gao, Yang; Zhang, Yunhai; Jia, Yanlong; Yu, Guirui

2017-12-01

Atmospheric acid deposition is a global environmental issue. China has been experiencing serious acid deposition, which is anticipated to become more severe with the country's economic development and increasing consumption of fossil fuels in recent decades. We explored the spatiotemporal variations of acid deposition (wet acid deposition) and its influencing factors by collecting nationwide data on pH and concentrations of sulfate (SO 4 2- ) and nitrate (NO 3 - ) in precipitation between 1980 and 2014 in China. Our results showed that average precipitation pH values were 4.59 and 4.70 in the 1990s and 2010s, respectively, suggesting that precipitation acid deposition in China has not seriously worsened. Average SO 4 2- deposition declined from 40.54 to 34.87 kg S ha -1 yr -1 but average NO 3 - deposition increased from 4.44 to 7.73 kg N ha -1 yr -1 . Specifically, the area of severe precipitation acid deposition in southern China has shrunk to some extent as a result of controlling the pollutant emissions; but the area of moderate precipitation acid deposition has expanded in northern China, associated with rapid industrial and transportation development. Furthermore, we found significant positive correlations between precipitation acid deposition, energy consumption, and rainfall. Our findings provide a relatively comprehensive evaluation of the spatiotemporal dynamics of precipitation acid deposition in China over past three decades, and confirm the idea that strategies implemented to save energy and control pollutant emissions in China have been effective in alleviating precipitation acid deposition. These findings might be used to demonstrate how developing countries could achieve economic development and environmental protection through the implementation of advanced technologies to reduce pollutant emissions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Vapor saturation and accumulation in magmas of the 1989-1990 eruption of Redoubt Volcano, Alaska

USGS Publications Warehouse

Gerlach, Terrance M.; Westrich, Henry R.; Casadevall, Thomas J.; Finnegan, David L.

1994-01-01

The 1989–1990 eruption of Redoubt Volcano, Alaska, provided an opportunity to compare petrologic estimates of SO2 and Cl emissions with estimates of SO2 emissions based on remote sensing data and estimates of Cl emissions based on plume sampling. In this study, we measure the sulfur and chlorine contents of melt inclusions and matrix glasses in the eruption products to determine petrologic estimates of SO2 and Cl emissions. We compare the results with emission estimates based on COSPEC and TOMS data for SO2 and data for Cl/SO2 in plume samples. For the explosive vent clearing period (December 14–22, 1989), the petrologic estimate for SO2 emission is 21,000 tons, or ~12% of a TOMS estimate of 175,000 tons. For the dome growth period (December 22, 1989 to mid-June 1990), the petrologic estimate for SO2 emission is 18,000 tons, or ~3% of COSPEC-based estimates of 572,000–680,000 tons. The petrologic estimates give a total SO2 emission of only 39,000 tons compared to an integrated TOMS/COSPEC emission estimate of ~1,000,000 tons for the whole eruption, including quiescent degassing after mid-June 1990. Petrologic estimates also appear to underestimate Cl emissions, but apparent HCl scavenging in the plume complicates Cl emission comparisons. Several potential sources of ‘excess sulfur’ often invoked to explain petrologic SO2 deficits are concluded to be unlikely for the 1989–1990 Redoubt eruption — e.g., breakdown of sulfides, breakdown of anhydrite, release of SO2 from a hydrothermal system, degassing of commingled infusions of basalt in the magma chamber, and syn-eruptive degassing of sulfur from melt present in non-erupted magma. Leakage and/or diffusion of sulfur from melt inclusions do not provide convincing explanations for the petrologic SO2 deficits either. The main cause of low petrologic estimates for SO2 is that melt inclusions do not represent the total sulfur content of the Redoubt magmas, which were vapor-saturated magmas carrying most of their sulfur in an accumulated vapor phase. Almost all the sulfur of the SO2 emissions was present prior to emission as accumulated magmatic vapor at 6–10 km depth in the magma that supplied the eruption; whole-rock normalized concentrations of gaseous excess S in these magmas remained at ~0.2 wt.% throughout the eruption, equivalent to ~0.7 vol.% at depth. Data for CO2 emissions during the eruption indicate that CO2 at whole-rock concentrations of ~0.6 wt.% in the erupted magma was a key factor in creating the vapor saturation and accumulation condition making a vapor phase source of excess sulfur possible at depth. When explosive volcanism involves magma with accumulated vapor, melt inclusions do not provide a sufficient basis for predicting SO2 emissions. Thus, petrologic estimates made for SO2 emissions during explosive eruptions of the past may be too low and may significantly underestimate impacts on climate and the chemistry of the atmosphere.

Carbon dioxide emission rate of Kīlauea Volcano: Implications for primary magma and the summit reservoir

USGS Publications Warehouse

Gerlach, T.M.; McGee, K.A.; Elias, T.; Sutton, A.J.; Doukas, M.P.

2002-01-01

 We report a CO2 emission rate of 8500 metric tons per day (t d−1) for the summit of Kīlauea Volcano, several times larger than previous estimates. It is based on three sets of measurements over 4 years of synchronous SO2 emission rates and volcanic CO2/SO2concentration ratios for the summit correlation spectrometer (COSPEC) traverse. Volcanic CO2/SO2 for the traverse is representative of the global ratio for summit emissions. The summit CO2 emission rate is nearly constant, despite large temporal variations in summit CO2/SO2 and SO2 emission rates. Summit CO2 emissions comprise most of Kīlauea's total CO2 output (∼9000 t d−1). The bulk CO2 content of primary magma determined from CO2emission and magma supply rate data is ∼0.70 wt %. Most of the CO2 is present as exsolved vapor at summit reservoir depths, making the primary magma strongly buoyant. Turbulent mixing with resident reservoir magma, however, prevents frequent eruptions of buoyant primary magma in the summit region. CO2 emissions confirm that the magma supply enters the edifice through the summit reservoir. A persistent several hundred parts per million CO2 anomaly arises from the entry of magma into the summit reservoir beneath a square kilometer area east of Halemaumau pit crater. Since most of the CO2 in primary magma is degassed in the summit, the summit CO2 emission rate is an effective proxy for the magma supply rate. Both scrubbing of SO2 and solubility controls on CO2and S in basaltic melt cause high CO2/SO2 in summit emissions and spatially uncorrelated distributions of CO2 and SO2 in the summit plume.

Changing trends in sulfur emissions in Asia: implications for acid deposition, air pollution, and climate.

PubMed

Carmichael, Gregory R; Streets, David G; Calori, Giuseppe; Amann, Markus; Jacobson, Mark Z; Hansen, James; Ueda, Hiromasa

2002-11-15

In the early 1990s, it was projected that annual SO2 emissions in Asia might grow to 80-110 Tg yr(-1) by 2020. Based on new high-resolution estimates from 1975 to 2000, we calculate that SO2 emissions in Asia might grow only to 40-45 Tg yr(-1) by 2020. The main reason for this lower estimate is a decline of SO2 emissions from 1995 to 2000 in China, which emits about two-thirds of Asian SO2. The decline was due to a reduction in industrial coal use, a slowdown of the Chinese economy, and the closure of small and inefficient plants, among other reasons. One effect of the reduction in SO2 emissions in China has been a reduction in acid deposition not only in China but also in Japan. Reductions should also improve visibility and reduce health problems. SO2 emission reductions may increase global warming, but this warming effect could be partially offset by reductions in the emissions of black carbon. How SO2 emissions in the region change in the coming decades will depend on many competing factors (economic growth, pollution control laws, etc.). However a continuation of current trends would result in sulfur emissions lower than any IPCC forecasts.

Methane and nitrous oxide emissions from livestock agriculture in 16 local administrative districts of Korea.

PubMed

Ji, Eun Sook; Park, Kyu-Hyun

2012-12-01

This study was conducted to evaluate methane (CH4) and nitrous oxide (N2O) emissions from livestock agriculture in 16 local administrative districts of Korea from 1990 to 2030. National Inventory Report used 3 yr averaged livestock population but this study used 1 yr livestock population to find yearly emission fluctuations. Extrapolation of the livestock population from 1990 to 2009 was used to forecast future livestock population from 2010 to 2030. Past (yr 1990 to 2009) and forecasted (yr 2010 to 2030) averaged enteric CH4 emissions and CH4 and N2O emissions from manure treatment were estimated. In the section of enteric fermentation, forecasted average CH4 emissions from 16 local administrative districts were estimated to increase by 4%-114% compared to that of the past except for Daejeon (-63%), Seoul (-36%) and Gyeonggi (-7%). As for manure treatment, forecasted average CH4 emissions from the 16 local administrative districts were estimated to increase by 3%-124% compared to past average except for Daejeon (-77%), Busan (-60%), Gwangju (-48%) and Seoul (-8%). For manure treatment, forecasted average N2O emissions from the 16 local administrative districts were estimated to increase by 10%-153% compared to past average CH4 emissions except for Daejeon (-60%), Seoul (-4.0%), and Gwangju (-0.2%). With the carbon dioxide equivalent emissions (CO2-Eq), forecasted average CO2-Eq from the 16 local administrative districts were estimated to increase by 31%-120% compared to past average CH4 emissions except Daejeon (-65%), Seoul (-24%), Busan (-18%), Gwangju (-8%) and Gyeonggi (-1%). The decreased CO2-Eq from 5 local administrative districts was only 34 kt, which was insignificantly small compared to increase of 2,809 kt from other 11 local administrative districts. Annual growth rates of enteric CH4 emissions, CH4 and N2O emissions from manure management in Korea from 1990 to 2009 were 1.7%, 2.6%, and 3.2%, respectively. The annual growth rate of total CO2-Eq was 2.2%. Efforts by the local administrative offices to improve the accuracy of activity data are essential to improve GHG inventories. Direct measurements of GHG emissions from enteric fermentation and manure treatment systems will further enhance the accuracy of the GHG data. (Key Words: Greenhouse Gas, Methane, Nitrous Oxide, Carbon Dioxide Equivalent Emission, Climate Change).

Monitoring so2 emission at the Soufriere Hills volcano: Implications for changes in eruptive conditions

USGS Publications Warehouse

Young, S.R.; Francis, P.W.; Barclay, J.; Casadevall, T.J.; Gardner, C.A.; Darroux, B.; Davies, M.A.; Delmelle, P.; Norton, G.E.; Maciejewski, A.J.H.; Oppenheimer, C.M.M.; Stix, J.; Watson, I.M.

1998-01-01

Correlation spectrometer measurements of sulfur dioxide (SO2) emission rates during the current eruption of the Soufriere Hills volcano, Montserrat, have contributed towards identifying different phases of volcanic activity. SO2 emission rate has increased from 550 td-1 (>6.4 kgs-1) after July 1996, with the uncertainty associated with any individual measurement ca. 30%. Significantly enhanced SO2 emission rates have been identified in association with early phreatic eruptions (800 td-1 (9.3 kgs-1)) and episodes of vigorous dome collapse and pyroclastic flow generation (900 to 1500 td-1 (10.4 to 17.4 kgs-1)). SO2 emission rate has proved a useful proxy measurement for magma production rate. Observed SO2 emission rates are significantly higher than those inferred from analyses of glass inclusions in phenocrysts, implying the existence of a S-rich magmatic vapour phase.

Emissions and Economics of Behind-the-Meter Electricity Storage.

PubMed

Fisher, Michael J; Apt, Jay

2017-02-07

Annual installations of behind-the-meter (BTM) electric storage capacity are forecast to eclipse grid-side electrochemical storage by the end of the decade. Here, we characterize the economic payoff and regional emission consequences of BTM storage without colocated generation under different tariff conditions, battery characteristics, and ownership scenarios using metered loads for several hundred commercial and industrial customers. Net emissions are calculated as increased system emissions from charging minus avoided emissions from discharging. Net CO 2 emissions range from 75 to 270 kg/MWh of delivered energy depending on location and ownership perspective, though in New York, these emissions can be reduced with careful tariff design. Net NO x emissions range from -0.13 to 0.24 kg/MWh, and net SO 2 emissions range from -0.01 to 0.58 kg/MWh. Emission rates are driven primarily by energy losses, not by the difference between marginal emission rates during battery charging and discharging. Economics are favorable for many buildings in regions with high demand charges like California and New York, even without subsidies. Future penetration into regions with average charges like Pennsylvania will depend greatly on installation cost reductions and wholesale prices for ancillary services.

Measuring the impact of global tropospheric ozone, carbon dioxide and sulfur dioxide concentrations on biodiversity loss.

PubMed

Ahmed Bhuiyan, Miraj; Rashid Khan, Haroon Ur; Zaman, Khalid; Hishan, Sanil S

2018-01-01

The aim of this study is to examine the impact of air pollutants, including mono-nitrogen oxides (NOx), nitrous oxide (N 2 O), sulfur dioxide (SO 2 ), carbon dioxide emissions (CO 2 ), and greenhouse gas (GHG) emissions on ecological footprint, habitat area, food supply, and biodiversity in a panel of thirty-four developed and developing countries, over the period of 1995-2014. The results reveal that NOx and SO 2 emissions both have a negative relationship with ecological footprints, while N 2 O emission and real GDP per capita have a direct relationship with ecological footprints. NOx has a positive relationship with forest area, per capita food supply and biological diversity while CO 2 emission and GHG emission have a negative impact on food production. N 2 O has a positive impact on forest area and biodiversity, while SO 2 emissions have a negative relationship with them. SO 2 emission has a direct relationship with per capita food production, while GDP per capita significantly affected per capita food production and food supply variability across countries. The overall results reveal that SO 2 , CO 2 , and GHG emissions affected potential habitat area, while SO 2 and GHG emissions affected the biodiversity index. Trade liberalization policies considerably affected the potential habitat area and biological diversity in a panel of countries. Copyright © 2017 Elsevier Inc. All rights reserved.

Dimethyl sulfide: Less important than long-range transport as a source of sulfate to the remote tropical Pacific marine boundary layer

NASA Astrophysics Data System (ADS)

Simpson, Rebecca M. C.; Howell, Steven G.; Blomquist, Byron W.; Clarke, Antony D.; Huebert, Barry J.

2014-07-01

During the Pacific Atmospheric Sulfur Experiment (PASE), dimethyl sulfide (DMS) was not the principal source of non-sea salt sulfate (NSS) mass in the remote marine boundary layer (MBL), according to an Eulerian sulfur budget based on observations of chemical concentrations from the NCAR C-130 in relatively dry, subsiding regions of the tropical Pacific. Our three (DMS, SO2, and NSS) monthly-average budgets are mutually consistent. The PASE-average DMS emission was 3.0 ± 0.5μmol m-2 d-1 (our budget "units"). SO2 sources include DMS + OH (1.4 ± 0.4 units, assuming 75% of reacted DMS forms SO2) and entrainment from the free troposphere (FT) (0.8 ± 0.2 units). Clouds were the most important chemical reactors for SO2 (-1.0 ± 0.5 units). SO2 loss terms also include divergence (-0.9 ± 0.3 units), dry deposition (-0.5 ± 0.2 units), and OH + SO2 (-0.22 ± 0.05 units). The total SO2 loss balanced the SO2 source. We assume that no SO2 was lost to ozone oxidation on sea salt particles; we found negligible NSS on particles from 2.6 μm (the sea salt mass peak) to 10 μm diameter. Fine-particle NSS sources include in-cloud oxidation of SO2 by H2O2 (1.0 ± 0.5 units), OH + SO2 (0.19 ± 0.05 units), and entrainment (1.1 ± 0.3 units in clean conditions; twice that when continental pollution is present). NSS sources balance NSS loss to divergence. Only about one fourth of emitted DMS becomes NSS. FT entrainment supplied two thirds and DMS oxidation produced one third of MBL NSS, rather similar source terms.

Emissions of mercury in southern Africa derived from long-term observations at Cape Point, South Africa

NASA Astrophysics Data System (ADS)

Brunke, E.-G.; Ebinghaus, R.; Kock, H. H.; Labuschagne, C.; Slemr, F.

2012-08-01

Mercury emissions in South Africa have so far been estimated only by a bottom-up approach from activities and emission factors for different processes. In this paper we derive GEM/CO (GEM being gaseous elemental mercury, Hg0), GEM/CO2, GEM/CH4, CO/CO2, CH4/CO2, and CH4/CO emission ratios from plumes observed during long-term monitoring of these species at Cape Point between March 2007 and December 2009. The average observed GEM/CO, GEM/CO2, GEM/CH4, CO/CO2, CH4/CO2, and CH4/CO emission ratios were 2.40 ± 2.65 pg m-3 ppb-1 (n = 47), 62.7 ± 80.2 pg m-3 ppm-1 (n = 44), 3.61 ± 4.66 pg m-3 ppb-1 (n = 46), 35.6 ± 25.4 ppb ppm-1 (n = 52), 20.2 ± 15.5 ppb ppm-1 (n = 48), and 0.876 ± 1.106 ppb ppb-1 (n = 42), respectively. The observed CO/CO2, CH4/CO2, and CH4/CO emission ratios agree within the combined uncertainties of the observations and emissions with the ratios calculated from EDGAR (version 4.2) CO2, CO, and CH4 inventories for South Africa and southern Africa (South Africa, Lesotho, Swaziland, Namibia, Botswana, Zimbabwe, and Mozambique) in 2007 and 2008 (inventories for 2009 are not available yet). Total elemental mercury emission of 13.1, 15.2, and 16.1 t Hg yr-1 are estimated independently using the GEM/CO, GEM/CO2, and GEM/CH4 emission ratios and the annual mean CO, CO2, and CH4 emissions, respectively, of South Africa in 2007 and 2008. The average of these independent estimates of 14.8 t GEM yr-1 is much less than the total emission of 257 t Hg yr-1 shown by older inventories which are now considered to be wrong. Considering the uncertainties of our emission estimate, of the emission inventories, and the fact that emission of GEM represents 50-78 % of all mercury emissions, our estimate is comparable to the currently cited GEM emissions in 2004 and somewhat smaller than emissions in 2006. A further increase of mercury emissions due to increasing electricity consumption will lead to a more pronounced difference. A quantitative assessment of the difference and its significance, however, will require emission inventories for the years of observations (2007-2009) as well as better data on the speciation of the total mercury emissions in South Africa.

Emission controls and changes in air quality in Guangzhou during the Asian Games

NASA Astrophysics Data System (ADS)

Liu, Huan; Wang, Xuemei; Zhang, Jinpu; He, Kebin; Wu, Ye; Xu, Jiayu

2013-09-01

With the new air quality standards forthcoming in China, the Pearl River Delta region is facing new challenges to achieve its air quality goal. The success of the emission reduction measures introduced by local authorities in the run-up to the Guangzhou Asian Games demonstrated that the Pearl River Delta air quality can be improved by introducing integrated emission reduction measures. This paper combines observation data, emission reduction measures, and air quality simulations that were applied during the Asian Games (12-27 November 2010) to analyze the relationship between emissions and concentrations of pollutants in Guangzhou. The Asian Games abatement strategy totally reduced emissions of 41.1% SO2, 41.9% NOx, 26.5% PM10, 25.8% PM2.5 and 39.7% VOC. The concentrations of SO2, NO2, PM10 and PM2.5 were reduced by 66.8%, 51.3%, 21.5% and 17.1%, respectively. In Guangzhou, the main challenge to be overcome with the new air quality daily requirements is mostly for NO2, PM2.5, and hourly ozone maxima. If pollutants maintain the same concentrations before and after the Asian Games, there will be 47.4% and 31.6% non-attainment days for NO2 and PM2.5 respectively as a period average. Although PM10 concentration can meet the daily limits (150 μg m-3), it is quite difficult to meet the annual limit value (70 μg m-3). One important implication is that the long-term, step-by-step integrated measures of the past six years work better than the strict, intensive, short-term measures on SO2, NO2 and VOC control. Dust control by limiting construction sites and watering the roads can further reduce 12.8% of the PM10 concentration. However, to reduce ambient PM2.5, the abatement strategy should be more complex and extensive. On the contrary, ozone pollution was not improved during the Asian Games, indicating that alleviation strategies should be improved by scientific studies to determine the appropriate control ratio of NO2 and VOC in the Pearl River Delta region.

PM composition and source reconciliation in Mexico City

NASA Astrophysics Data System (ADS)

Mugica, V.; Ortiz, E.; Molina, L.; De Vizcaya-Ruiz, A.; Nebot, A.; Quintana, R.; Aguilar, J.; Alcántara, E.

PM 2.5 and PM 10 were collected during 24-h sampling intervals from March 1st to 31st, 2006 during the MILAGRO campaign carried out in Mexico City's northern region, in order to determine their chemical composition, oxidative activity and the estimation of the source contributions during the sampling period by means of the chemical mass balance (CMB) receptor model. PM 2.5 concentrations ranged from 32 to 70 μg m -3 while that of PM10 did so from 51 to 132 μg m -3. The most abundant chemical species for both PM fractions were: OC, EC, SO 42-, NO 3-, NH 4+, Si, Fe and Ca. The majority of the PM mass was comprised of carbon, up to about 52% and 30% of the PM2.5 and PM10, respectively. PM2.5 constituted more than 50% of PM10. The redox activity, assessed by the dithiothreitol (DTT) assay, was greater for PM 2.5 than for PM 10, and did not display significant differences during the sampling period. The PM 2.5 source reconciliation showed that in average, vehicle exhaust emissions were its most important source in an urban site with a 42% contribution, followed by re-suspended dust with 26%, secondary inorganic aerosols with 11%, and industrial emissions and food cooking with 10% each. These results had a good agreement with the Emission Inventory. In average, the greater mass concentration occurred during O 3S that corresponds to a wind shift initially with transport to the South but moving back to the North. Taken together these results show that PM chemical composition, oxidative potential, and source contribution is influenced by the meteorological conditions.

Maximizing sinter plant operating flexibility through emissions trading and air modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schewe, G.J.; Wagner, J.A.; Heron, T.

1998-12-31

This paper provides details on the dispersion modeling analysis performed to demonstrate air quality impacts associated with an emission trading scheme for a sintering operation in Youngstown, Ohio. The emission trade was proposed to allow the sinter plant to expand its current allowable sulfur dioxide (SO2) emissions while being offset with SO{sub 2} emissions from boilers at a nearby shutdown steel mill. While the emission trade itself was feasible and the emissions required for the offset were available (the boiler shutdown and their subsequent SO{sub 2} emission credits were never claimed, banked, or used elsewhere), the second criteria for determiningmore » compliance was a demonstration of minimal air quality impact. The air analysis combined the increased ambient SO{sub 2} concentrations of the relaxed sinter plant emissions with the offsetting air quality of the shutdown boilers to yield the net air quality impacts. To test this net air impact, dispersion modeling was performed treating the sinter plant SO{sub 2} emissions as positive and the shutdown boiler SO{sub 2} emissions as negative. The results of the modeling indicated that the ambient air concentrations due to the proposed emissions increase will be offset by the nearby boiler emissions to levels acceptable under EPA`s offset policy Level 2 significant impact concentrations. Therefore, the dispersion modeling demonstrated that the emission trading scheme would not result in significant air quality impacts and maximum operating flexibility was provided to the sintering facility.« less

40 CFR 74.23 - 1985 Allowable SO2 emissions rate.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false 1985 Allowable SO2 emissions rate. 74... (CONTINUED) SULFUR DIOXIDE OPT-INS Allowance Calculations for Combustion Sources § 74.23 1985 Allowable SO2... data: (i) Allowable SO2 emissions rate of the combustion source expressed in lbs/mmBtu as defined under...

Sunlit Io Atmospheric [O I] 6300 A and the Plasma Torus

NASA Technical Reports Server (NTRS)

Oliversen, Ronald J.; Scherb, Frank; Smyth, William H.; Freed, Melanie E.; Woodward, R. Carey, Jr.; Marcone, Maximus L.; Retherford, Kurt D.; Lupie, Olivia L.; Morgenthaler, Jeffrey P.; Fisher, Richard R. (Technical Monitor)

2001-01-01

A large database of sunlit Io [O I] 6300A emission, acquired over the period 1990-1999, with extensive coverage of Io orbital phase angle phi and System III longitude lambda(sub III), exhibits significant long-term and short-term variations in [O I] 6300A emission intensities. The long-term average intensity shows a clear dependence on lambda(sub III), which establishes conclusively that the emission is produced by the interaction between Io's atmosphere and the plasma torus. Two prominent average intensity maxima, 70 deg to 90 deg wide, are centered at lambda(sub III) about 130deg. and about 295 deg. A comparison of data from October 1998 with a three-dimensional plasma torus model, based upon electron impact excitation of atomic oxygen, suggests a basis for study of the torus interaction with Io's atmosphere. The observed short-term, erratic [O I] 6300A intensity variations fluctuate approximately 20% to 50% on time scale of tens of minutes with less frequent fluctuations of a factor of about 2. The most likely candidate to produce these fluctuations is a time-variable energy flux of field-aligned nonthermal electrons identified recently in Galileo PLS data. If true, the short-term [O I] intensity fluctuations may be related to variable field-aligned currents driven by inward and outward torus plasma transport and/or transient high-latitude, field-aligned potential drops. A correlation between the intensity and emission line width indicates molecular dissociation may contribute significantly to the [O I] 6300A emission. The nonthermal electron energy flux may produce O(1-D) by electron impact dissociation of SO2 and SO, with the excess energy going into excitation of O and its kinetic energy. The [O I] 6300A emission database establishes Io as a valuable probe of the torus, responding to local conditions at Io's position.

Real-time measurement of volcanic SO2 emissions: Validation of a new UV correlation spectrometer (FLYSPEC)

USGS Publications Warehouse

Horton, Keith A.; Williams-Jones, Glyn; Garbeil, Harold; Elias, Tamar; Sutton, A. Jeff; Mouginis-Mark, Peter J; Porter, John T.; Clegg, Steven

2006-01-01

A miniaturized, lightweight and low-cost UV correlation spectrometer, the FLYSPEC, has been developed as an alternative for the COSPEC, which has long been the mainstay for monitoring volcanic sulfur dioxide fluxes. Field experiments have been conducted with the FLYSPEC at diverse volcanic systems, including Masaya (Nicaragua), Poás (Costa Rica), Stromboli, Etna and Vulcano (Italy), Villarica (Chile) and Kilauea (USA). We present here those validation measurements that were made simultaneously with COSPEC at Kilauea between March 2002 and February 2003. These experiments, with source emission rates that ranged from 95 to 1,560 t d−1, showed statistically identical results from both instruments. SO2 path-concentrations ranged from 0 to >1,000 ppm-m with average correlation coefficients greater than r2=0.946. The small size and low cost create the opportunity for FLYSPEC to be used in novel deployment modes that have the potential to revolutionize the manner in which volcanic and industrial monitoring is performed.

Carbon and nitrogen isotopes unravels sources of aerosol contamination at Caribbean rural and urban coastal sites.

PubMed

Morera-Gómez, Yasser; Santamaría, Jesús Miguel; Elustondo, David; Alonso-Hernández, Carlos Manuel; Widory, David

2018-06-15

The constant increase of anthropogenic emissions of aerosols, usually resulting from a complex mixture from various sources, leads to a deterioration of the ambient air quality. The stable isotope compositions (δ 13 C and δ 15 N) of total carbon (TC) and nitrogen (TN) in both PM 10 and emissions from potential sources were investigated for first time in a rural and an urban Caribbean costal sites in Cuba to better constrain the origin of the contamination. Emissions from road traffic, power plant and shipping emissions were discriminated by coupling their C and N contents and corresponding isotope signatures. Other sources (soil, road dust and cement plant), in contrast, presented large overlapping ranges for both C and N isotope compositions. δ 13 C PM10 isotope compositions in the rural (average of -25.4 ± 1.2‰) and urban (average of -24.8 ± 1.2‰) sites were interpreted as a mixture of contributions from two main contributors: i) fossil fuel combustion and ii) cement plant and quarries. Results also showed that this last source is impacting more air quality at the urban site. A strong influence from local wood burning was also identified at the rural site. These conclusions were comforted by a statistical analysis using a conditional bivariate probability function. TN and δ 15 N values from the urban site demonstrated that nitrogen in PM 10 was generated by secondary processes through the formation of (NH 4 ) 2 SO 4 . The exchange in the (NH 4 ) 2 SO 4 molecule between gaseous NH 3 and particle NH 4 + under stoichiometric equilibrium may control the observed 15 N enrichment. At low nitrogen concentrations in the aerosols, representing PM 10 with both the highest primary N and lowest secondary N proportions, comparison with the δ 15 N of potential sources indicate that emissions from diesel car and power plant emissions may represent the major vectors of primary nitrogen. Copyright © 2018 Elsevier B.V. All rights reserved.

Changes in inorganic fine particulate matter sensitivities to precursors due to large-scale US emissions reductions.

PubMed

Holt, Jareth; Selin, Noelle E; Solomon, Susan

2015-04-21

We examined the impact of large US emissions changes, similar to those estimated to have occurred between 2005 and 2012 (high and low emissions cases, respectively), on inorganic PM2.5 sensitivities to further NOx, SO2, and NH3 emissions reductions using the chemical transport model GEOS-Chem. Sensitivities to SO2 emissions are larger year-round and across the US in the low emissions case than the high emissions case due to more aqueous-phase SO2 oxidation. Sensitivities to winter NOx emissions are larger in the low emissions case, more than 2× those of the high emissions case in parts of the northern Midwest. Sensitivities to NH3 emissions are smaller (∼40%) in the low emissions case, year-round, and across the US. Differences in NOx and NH3 sensitivities indicate an altered atmospheric acidity. Larger sensitivities to SO2 and NOx in the low emissions case imply that reducing these emissions may improve air quality more now than they would have in 2005; conversely, NH3 reductions may not improve air quality as much as previously assumed.

Investigations of temporal and spatial distribution of precursors SO2 and NO2 vertical columns in the North China Plain using mobile DOAS

NASA Astrophysics Data System (ADS)

Wu, Fengcheng; Xie, Pinhua; Li, Ang; Mou, Fusheng; Chen, Hao; Zhu, Yi; Zhu, Tong; Liu, Jianguo; Liu, Wenqing

2018-02-01

Recently, Chinese cities have suffered severe events of haze air pollution, particularly in the North China Plain (NCP). Investigating the temporal and spatial distribution of pollutants, emissions, and pollution transport is necessary to better understand the effect of various sources on air quality. We report on mobile differential optical absorption spectroscopy (mobile DOAS) observations of precursors SO2 and NO2 vertical columns in the NCP in the summer of 2013 (from 11 June to 7 July) in this study. The different temporal and spatial distributions of SO2 and NO2 vertical column density (VCD) over this area are characterized under various wind fields. The results show that transport from the southern NCP strongly affects air quality in Beijing, and the transport route, particularly SO2 transport on the route of Shijiazhuang-Baoding-Beijing, is identified. In addition, the major contributors to SO2 along the route of Shijiazhuang-Baoding-Beijing are elevated sources compared to low area sources for the route of Dezhou-Cangzhou-Tianjin-Beijing; this is found using the interrelated analysis between in situ and mobile DOAS observations during the measurement periods. Furthermore, the discussions on hot spots near the city of JiNan show that average observed width of polluted air mass is 11.83 and 17.23 km associated with air mass diffusion, which is approximately 60 km away from emission sources based on geometrical estimation. Finally, a reasonable agreement exists between the Ozone Monitoring Instrument (OMI) and mobile DOAS observations, with a correlation coefficient (R2) of 0.65 for NO2 VCDs. Both datasets also have a similar spatial pattern. The fitted slope of 0.55 is significantly less than unity, which can reflect the contamination of local sources, and OMI observations are needed to improve the sensitivities to the near-surface emission sources through improvements of the retrieval algorithm or the resolution of satellites.

40 CFR 74.24 - Current allowable SO2 emissions rate.

Code of Federal Regulations, 2011 CFR

2011-07-01

... allowable SO2 emissions rate of the combustion source, expressed in lbs/mmBtu, which shall be the most... application. If the allowable SO2 emissions rate is not expressed in lbs/mmBtu, the allowable emissions rate shall be converted to lbs/mmBtu by multiplying the allowable rate by the appropriate factor as specified...

Compilation of a Global Emission Inventory from 1980 to 2000 for Global Model Simulations of the Long-term Trend of Tropospheric Aerosols

NASA Technical Reports Server (NTRS)

Diehl, T. L.; Mian, Chin; Bond, T. C.; Carn, S. A.; Duncan, B. N.; Krotkov, N. A.; Streets, D. G.

2007-01-01

The approach to create a comprehensive emission inventory for the time period 1980 to 2000 is described in this paper. We have recently compiled an emission database, which we will use for a 21 year simulation of tropospheric aerosols with the GOCART model. Particular attention was paid to the time-dependent SO2, black carbon and organic carbon aerosol emissions. For the emission of SO2 from sporadically erupting volcanoes, we assembled emission data from the Global Volcanism Program of the Smithsonian Institution, using the VEI to derive the volcanic cloud height and the SO2 amount, and amended this dataset by the SO2 emission data from the TOMS instrument when available. 3-dimensional aircraft emission data was obtained for a number of years from the AEAP project, converted from burned fuel to SO2 and interpolated to each year, taking the sparsity of the flight patterns into account. Other anthopogenic SO2 emissions are based on gridded emissions from the EDGAR 2000 database (excluding sources from aircraft, biomass burning and international ship traffic), which were scaled to individual years with country/regional based emission inventories. Gridded SO2 emissions from international ship traffic for 2000 and the scaling factors for other years are from [Eyring et al., 2005]. We used gridded anthropogenic black and organic carbon emissions for 1996 [Bond et al., 2005], again excluding aircraft, biomass burning and ship sources. These emissions were scaled with regional based emission inventories from 1980 to 2000 to derive gridded emissions for each year. The biomass burning emissions are based on a climatology, which is scaled with regional scaling factors derived from the TOMS aerosol index and the AVHRR/ATSR fire counts to each year [Duncan et al., 2003]. Details on the integration of the information from the various sources will be provided and the distribution patterns and total emissions in the final product will be discussed.

Compilation of a Global Emission Inventory from 1980 to 2000 for Global Model Simulations of the Long-term Trend of Tropospheric Aerosols

NASA Technical Reports Server (NTRS)

Diehl, Thomas L.; Chin, Mian; Bond, Tami C.; Carn, SImon A.; Duncan, Bryan N.; Krotkov, Nickolay A.; Streets, David G.

2006-01-01

The approach to create a comprehensive emission inventory for the time period 1980 to 2000 is described in this paper. We have recently compiled an emission database, which we will use for a 21 year simulation of tropospheric aerosols with the GOCART model. Particular attention was paid to the time-dependent SO2, black carbon and organic carbon aerosol emissions. For the emission of SO2 from sporadically erupting volcanoes, we assembled emission data from the Global Volcanism Program of the Smithsonian Institution, using the VEI to derive the volcanic cloud height and the SO2 amount, and amended this dataset by the SO2 emission data from the TOMS instrument when available. 3-dimensional aircraft emission data was obtained for a number of years from the AEAP project, converted from burned fuel to SO2 and interpolated to each year, taking the sparsity of the flight patterns into account. Other anthropogenic SO2 emissions are based on gridded emissions from the EDGAR 2000 database (excluding sources from aircraft, biomass burning and international ship traffic), which were scaled to individual years with country/regional based emission inventories. Gridded SO2 emissions from international ship traffic for 2000 and the scaling factors for other years are from [Eyring et al., 2005]. We used gridded anthropogenic black and organic carbon emissions for 1996 [Bond et al., 2005], again excluding aircraft, biomass burning and ship sources. These emissions were scaled with regional based emission inventories from 1980 to 2000 to derive gridded emissions for each year. The biomass burning emissions are based on a climatology, which is scaled with regional scaling factors derived from the TOMS aerosol index and the AVHRR/ASTR fire counts to each year [Duncan et al., 2003]. Details on the integration of the information from the various sources will be provided and the distribution patterns and total emissions in the final product will be discussed.

The Story of Ever Diminishing Vehicle Tailpipe Emissions as Observed in the Chicago, Illinois Area.

PubMed

Bishop, Gary A; Haugen, Molly J

2018-05-15

The University of Denver has collected on-road fuel specific vehicle emissions measurements in the Chicago area since 1989. This nearly 30 year record illustrates the large reductions in light-duty vehicle tailpipe emissions and the remarkable improvements in emissions control durability to maintain low emissions over increasing periods of time. Since 1989 fuel specific carbon monoxide (CO) emissions have been reduced by an order of magnitude and hydrocarbon (HC) emissions by more than a factor of 20. Nitric oxide (NO) emissions have only been collected since 1997 but have seen reductions of 79%. This has increased the skewness of the emissions distribution where the 2016 fleet's 99th percentile contributes ∼3 times more of the 1990 total for CO and HC emissions. There are signs that these reductions may be leveling out as the emissions durability of Tier 2 vehicles in use today has almost eliminated the emissions reduction benefit of fleet turnover. Since 1997, the average age of the Chicago on-road fleet has increased 2 model years and the percentage of passenger vehicles has dropped from 71 to 52% of the fleet. Emissions are now so well controlled that the influence of driving mode has been completely eliminated as a factor for fuel specific CO and NO emissions.

Measuring SO2 ship emissions with an ultraviolet imaging camera

NASA Astrophysics Data System (ADS)

Prata, A. J.

2014-05-01

Over the last few years fast-sampling ultraviolet (UV) imaging cameras have been developed for use in measuring SO2 emissions from industrial sources (e.g. power plants; typical emission rates ~ 1-10 kg s-1) and natural sources (e.g. volcanoes; typical emission rates ~ 10-100 kg s-1). Generally, measurements have been made from sources rich in SO2 with high concentrations and emission rates. In this work, for the first time, a UV camera has been used to measure the much lower concentrations and emission rates of SO2 (typical emission rates ~ 0.01-0.1 kg s-1) in the plumes from moving and stationary ships. Some innovations and trade-offs have been made so that estimates of the emission rates and path concentrations can be retrieved in real time. Field experiments were conducted at Kongsfjord in Ny Ålesund, Svalbard, where SO2 emissions from cruise ships were made, and at the port of Rotterdam, Netherlands, measuring emissions from more than 10 different container and cargo ships. In all cases SO2 path concentrations could be estimated and emission rates determined by measuring ship plume speeds simultaneously using the camera, or by using surface wind speed data from an independent source. Accuracies were compromised in some cases because of the presence of particulates in some ship emissions and the restriction of single-filter UV imagery, a requirement for fast-sampling (> 10 Hz) from a single camera. Despite the ease of use and ability to determine SO2 emission rates from the UV camera system, the limitation in accuracy and precision suggest that the system may only be used under rather ideal circumstances and that currently the technology needs further development to serve as a method to monitor ship emissions for regulatory purposes. A dual-camera system or a single, dual-filter camera is required in order to properly correct for the effects of particulates in ship plumes.

Measurement of CO 2, CO, SO 2, and NO emissions from coal-based thermal power plants in India

NASA Astrophysics Data System (ADS)

Chakraborty, N.; Mukherjee, I.; Santra, A. K.; Chowdhury, S.; Chakraborty, S.; Bhattacharya, S.; Mitra, A. P.; Sharma, C.

Measurements of CO 2 (direct GHG) and CO, SO 2, NO (indirect GHGs) were conducted on-line at some of the coal-based thermal power plants in India. The objective of the study was three-fold: to quantify the measured emissions in terms of emission coefficient per kg of coal and per kWh of electricity, to calculate the total possible emission from Indian thermal power plants, and subsequently to compare them with some previous studies. Instrument IMR 2800P Flue Gas Analyzer was used on-line to measure the emission rates of CO 2, CO, SO 2, and NO at 11 numbers of generating units of different ratings. Certain quality assurance (QA) and quality control (QC) techniques were also adopted to gather the data so as to avoid any ambiguity in subsequent data interpretation. For the betterment of data interpretation, the requisite statistical parameters (standard deviation and arithmetic mean) for the measured emissions have been also calculated. The emission coefficients determined for CO 2, CO, SO 2, and NO have been compared with their corresponding values as obtained in the studies conducted by other groups. The total emissions of CO 2, CO, SO 2, and NO calculated on the basis of the emission coefficients for the year 2003-2004 have been found to be 465.667, 1.583, 4.058, and 1.129 Tg, respectively.

40 CFR 57.205 - Submission of supplementary information upon relaxation of an SO2 SIP emission limitation.

Code of Federal Regulations, 2010 CFR

2010-07-01

... upon relaxation of an SO2 SIP emission limitation. 57.205 Section 57.205 Protection of Environment... Application and the NSO Process § 57.205 Submission of supplementary information upon relaxation of an SO2 SIP emission limitation. (a) In the event an SO2 SIP limit is relaxed subsequent to EPA approval or issuance of...

The temporal variation of SO2 emissions embodied in Chinese supply chains, 2002-2012.

PubMed

Yang, Xue; Zhang, Wenzhong; Fan, Jie; Li, Jiaming; Meng, Jing

2018-05-24

Whilst attention is increasingly being focused on embodied pollutant emissions along supply chains in China, relatively little attention has been paid to dynamic changes in this process. This study utilized environmental extended input-output analysis (EEIOA) and structural path analysis (SPA) to investigate the dynamic variation of the SO 2 emissions embodied in 28 economic sectors in Chinese supply chains during 2002-2012. The main conclusions are summarized as follows: (1) The dominant SO 2 emission sectors differed under production and consumption perspectives. Electricity and heat production dominated SO 2 emissions from the point of view of production, while construction contributed most from the consumption perspective. (2) The embodied SO 2 emissions tended to change from the path (staring from consumption side to production side): "Services→Services→Power" in 2002 to the path: "Construction and Manufacturing→Metal and Nonmetal→Power" in 2012. (3) Metal-driven emissions raised dramatically from 15% in 2002 to 22% in 2012, due to increasing demand for metal products in construction and manufacturing activities. (4) Power generation was found to result in the greatest volume of production-based emissions, a burden it tended to transfer to upstream sectors in 2012. Controlling construction activities and cutting down end-of-pipe discharges in the process of power generation represent the most radical interventions in reducing Chinese SO 2 emissions. This study shed light on changes in SO 2 emissions in the supply chain, providing a range of policy implications from both production and consumption perspectives. Copyright © 2018 Elsevier Ltd. All rights reserved.

Open-path Emission Factors Derived from DOAS and FTIR Measurements in the Mexico City Metropolitan Area

NASA Astrophysics Data System (ADS)

Flores, E.; Grutter, M.; Galle, B.; Mellqvist, J.; Samuelsson, J.; Knighton, B.; Jobson, B. T.; Volkamer, R.; Molina, L. T.; Molina, M. J.

2004-12-01

Mobile sources are responsible for about 50% of VOC (volatile organic compounds) and about 70% of NOx emissions in the Mexico City Metropolitan Area (MCMA). A novel approach has been developed to derive emission factors for mobile sources that are representative of the overall vehicle fleet, using collocated open-path Differential Optical Absorption Spectroscopy (DOAS) and Fourier Transform Infrared (FTIR) spectroscopic measurements. Measurements were recorded at two sites within the MCMA: (1) research-grade DOAS and FTIR systems were operated at the Mexican National Research and Training Center (CENICA) in Iztapalapa, (2) a research grade FTIR was operated at La Merced. In addition, point-sampling with a proton transfer reaction mass spectrometer (PTR-MS) was performed on the same location and the calibration standards for the PTR-MS and the DOAS instruments were cross-calibrated. The DOAS measured speciated aromatic hydrocarbons, including benzene, toluene, m-xylene, p-xylene, ethylbenzene (and mono-substituted alkylbenzenes), benzaldehyde, phenol, and p-cresol. The DOAS detection of aromatic hydrocarbons in the UV/vis spectral range between 250 to 310 nm suffers from the interference of molecular oxygen, and a novel approach is being presented that enables measurement of absolute concentrations of the above species. Further, HONO, NO2, SO2 and HCHO were measured at longer wavelengths. In combination with FTIR measurements of CO, CO2, NO, HCHO, ethylene, ethene, and total alkane, average emission factors for NOx, SO2 and numerous hydrocarbons were derived and scaled with fuel sales data to estimate total emissions of the vehicle fleet in the MCMA. The advantages and limitations of this low-cost emission inventory for mobile sources are decsribed.

Remote measurement of high preeruptive water vapor emissions at Sabancaya volcano by passive differential optical absorption spectroscopy

NASA Astrophysics Data System (ADS)

Kern, Christoph; Masias, Pablo; Apaza, Fredy; Reath, Kevin A.; Platt, Ulrich

2017-05-01

Water (H2O) is by far the most abundant volcanic volatile species and plays a predominant role in driving volcanic eruptions. However, numerous difficulties associated with making accurate measurements of water vapor in volcanic plumes have limited their use as a diagnostic tool. Here we present the first detection of water vapor in a volcanic plume using passive visible-light differential optical absorption spectroscopy (DOAS). Ultraviolet and visible-light DOAS measurements were made on 21 May 2016 at Sabancaya Volcano, Peru. We find that Sabancaya's plume contained an exceptionally high relative water vapor abundance 6 months prior to its November 2016 eruption. Our measurements yielded average sulfur dioxide (SO2) emission rates of 800-900 t/d, H2O emission rates of around 250,000 t/d, and an H2O/SO2 molecular ratio of 1000 which is about an order of magnitude larger than typically found in high-temperature volcanic gases. We attribute the high water vapor emissions to a boiling-off of Sabancaya's hydrothermal system caused by intrusion of magma to shallow depths. This hypothesis is supported by a significant increase in the thermal output of the volcanic edifice detected in infrared satellite imagery leading up to and after our measurements. Though the measurement conditions encountered at Sabancaya were very favorable for our experiment, we show that visible-light DOAS systems could be used to measure water vapor emissions at numerous other high-elevation volcanoes. Such measurements would provide observatories with additional information particularly useful for forecasting eruptions at volcanoes harboring significant hydrothermal systems.

40 CFR 75.11 - Specific provisions for monitoring SO2 emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Specific provisions for monitoring SO2... PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.11 Specific provisions for monitoring SO2 emissions. (a) Coal-fired units. The owner or operator shall meet the general operating...

40 CFR 75.11 - Specific provisions for monitoring SO2 emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Specific provisions for monitoring SO2... PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.11 Specific provisions for monitoring SO2 emissions. (a) Coal-fired units. The owner or operator shall meet the general operating...

40 CFR 75.11 - Specific provisions for monitoring SO2 emissions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Specific provisions for monitoring SO2... PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.11 Specific provisions for monitoring SO2 emissions. (a) Coal-fired units. The owner or operator shall meet the general operating...

Dioxins from medical waste incineration: Normal operation and transient conditions.

PubMed

Chen, Tong; Zhan, Ming-xiu; Yan, Mi; Fu, Jian-ying; Lu, Sheng-yong; Li, Xiao-dong; Yan, Jian-hua; Buekens, Alfons

2015-07-01

Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) are key pollutants in waste incineration. At present, incinerator managers and official supervisors focus only on emissions evolving during steady-state operation. Yet, these emissions may considerably be raised during periods of poor combustion, plant shutdown, and especially when starting-up from cold. Until now there were no data on transient emissions from medical (or hospital) waste incineration (MWI). However, MWI is reputed to engender higher emissions than those from municipal solid waste incineration (MSWI). The emission levels in this study recorded for shutdown and start-up, however, were significantly higher: 483 ± 184 ng Nm(-3) (1.47 ± 0.17 ng I-TEQ Nm(-3)) for shutdown and 735 ng Nm(-3) (7.73 ng I-TEQ Nm(-3)) for start-up conditions, respectively. Thus, the average (I-TEQ) concentration during shutdown is 2.6 (3.8) times higher than the average concentration during normal operation, and the average (I-TEQ) concentration during start-up is 4.0 (almost 20) times higher. So monitoring should cover the entire incineration cycle, including start-up, operation and shutdown, rather than optimised operation only. This suggestion is important for medical waste incinerators, as these facilities frequently start up and shut down, because of their small size, or of lacking waste supply. Forthcoming operation should shift towards much longer operating cycles, i.e., a single weekly start-up and shutdown. © The Author(s) 2015.

Multi-component gas emission measurements of the active lava lake of Nyiragongo, DR Congo

NASA Astrophysics Data System (ADS)

Bobrowski, N.; Giuffrida, G. B.; Yalire, M.; Lübcke, P.; Arellano, S.; Balagizi, C.; Calabrese, S.; Galle, B.; Tedesco, D.

2017-10-01

Between 2007 and 2011 four measurement campaigns (June 2007, July 2010, June 2011, and December 2011) were carried out at the crater rim of Nyiragongo volcano, DR Congo. Nyiragongo is one of the most active volcanoes in Africa. The ground-based remote sensing technique Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS), which uses scattered sunlight, the in-situ Multi-Component Gas Analyzer System (Multi-GAS) and alkaline impregnated filter were simultaneously applied during all field trips. The bromine monoxide to sulfur dioxide (BrO/SO2) and carbon dioxide to sulfur dioxide (CO2/SO2) molar ratios were determined, among other ratios. During the different field trips variations of the level of the lava lake up to several tens of meters were observed during intervals of the order of minutes up to days and also between the years. The measured gas ratios presented covariations with the lava lake level changes. BrO/SO2 ratios and CO2/SO2 ratios showed similar behavior. Annual CO2/SO2 and BrO/SO2 average values are generally positively correlated. In June 2011 increased BrO/SO2 as well as increased CO2/SO2 ratios have been observed before a sudden decrease of the lava lake. Overall the Cl/S ratio, determined by filter-pack sampling, shows an increasing trend with time, which is accompanied by a decreasing sulfur dioxide flux, the later measured nearly continuously by automated MAX-DOAS instruments since 2004. Mean gas emission fluxes of CO2, Cl and 'minimum-BrO' fluxes are calculated using their ratio to SO2. The first two show an increase with time, in contrast to the SO2 fluxes. A simple conceptual model is proposed which can explain in particular the June 2011 data, but as well our entire data set. The proposed model takes up the idea of convective magma cells inside the conduit and the possible temporary interruption of part of the cycling. We propose than two alternatives to explain the observed gas emission variation: 1. It is assumed that the diffuse and fumarolic degassing could have significant influence on measured gas composition. The measured gas composition might rather represent a gas mixture of plume, diffuse and fumarolic degassing than only representing the volcanic plume. 2. It is proposed that the interruption of the convection has taken place in the upper part of the conduit and deep degassing of CO2 and bromine initially continues while mixing already with gas emissions from an ageing source, which is characterized by an already diminishing sulfur content. These complex process but as well as the gas mixing of different sources, could explain general features of our dataset, but can unfortunately neither be confirmed nor disproven by the data available today.

Emission of gas and atmospheric dispersion of SO2 during the December 2013 eruption at San Miguel volcano (El Salvador)

NASA Astrophysics Data System (ADS)

Salerno, Giuseppe G.; Granieri, Domenico; Liuzzo, Marco; La Spina, Alessandro; Giuffrida, Giovanni B.; Caltabiano, Tommaso; Giudice, Gaetano; Gutierrez, Eduardo; Montalvo, Francisco; Burton, Michael; Papale, Paolo

2016-04-01

San Miguel volcano, also known as Chaparrastique, is a basaltic volcano along the Central American Volcanic Arc (CAVA). Volcanism is induced by the convergence of the Cocos Plate underneath the Caribbean Plate, along a 1200-km arc, extending from Guatemala to Costa Rica and parallel to the Central American Trench. The volcano is located in the eastern part of El Salvador, in proximity to the large communities of San Miguel, San Rafael Oriente, and San Jorge. Approximately 70,000 residents, mostly farmers, live around the crater and the city of San Miguel, the second largest city of El Salvador, ten km from the summit, has a population of ~180,000 inhabitants. The Pan-American and Coastal highways cross the north and south flanks of the volcano.San Miguel volcano has produced modest eruptions, with at least 28 VEI 1-2 events between 1699 and 1967 (datafrom Smithsonian Institution http://www.volcano.si.edu/volcano.cfm?vn=343100). It is characterized by visible milddegassing from a summit vent and fumarole field, and by intermittent lava flows and Strombolian activity. Since the last vigorous fire fountaining of 1976, San Miguel has only experienced small steam explosions and gas emissions, minor ash fall and rock avalanches. On 29 December 2013 the volcano erupted producing an eruption that has been classified as VEI 2. While eruptions tend to be low-VEI, the presence of major routes and the dense population in the surrounding of the volcano increases the risk that weak explosions with gas and/or ash emission may pose. In this study, we present the first inventory of SO2, CO2, HCl, and HF emission rates on San Miguel volcano, and an analysis of the hazard from volcanogenic SO2 discharged before, during, and after the December 2013 eruption. SO2 was chosen as it is amongst the most critical volcanogenic pollutants, which may cause acute and chronicle disease to humans. Data were gathered by the geochemical monitoring network managed by the Ministerio de Medio Ambiente y Recursos Naturales (MARN) of El Salvador and by a network of geophysical and geochemical stations established on the volcano by the Italian Istituto Nazionale di Geofisica e Vulcanologia (INGV), immediately after the December 2013 eruption, on the request of MARN. During the eruption, SO2 emissions increased from a background level of ~330 t d-1 to 2200 t d-1, dropping after the eruption to an average level of 680 t d-1. Wind measurements and SO2 fluxes during the pre-, syn- and post-eruptive stages were used to model SO2 dispersion around the volcano. Air SO2 concentration exceeds the dangerous threshold of 5 ppm in the crater region, and in some middle sectors of the highly visited volcanic cone.

Are Emissions of Restricted Halocarbons in the USA and Canada Still Globally Significant?

NASA Astrophysics Data System (ADS)

Hurst, D. F.; Romashkin, P. A.; Hall, B. D.; Elkins, J. W.; Lin, J. C.; Gerbig, C.; Daube, B. C.; Wofsy, S. C.

2004-12-01

The global manufacture of halocarbons regulated by the Montreal Protocol has dropped substantially in response to the January 1, 1996, production phase-out deadline (1994 for halons) for developed (Article 5) countries like the United States and Canada. Contemporary emissions of these ozone-depleting substances (ODS) emanate from ongoing production in developing countries and releases of banked halocarbons world-wide. ODS emissions in developing nations can be appraised from reported production figures, but not so for developed nations where recent manufacture is negligible. Emissions in the United States and Canada are increasingly difficult to estimate because of limited information about bank sizes and release rates in the post-production era. In addition, regional- or national-scale emission estimates should no longer be derived wholly from localized measurements because of the potentially patchy spatial distributions of modern emissions. We estimate ODS emissions in the USA and Canada from >1000 simultaneous, in situ measurements each of CO and six restricted halocarbons (CFC-11, CFC-12, CFC-113, methyl chloroform, carbon tetrachloride, and halon-1211) in and above the planetary boundary layer during the 2003 CO2 Budget and Regional Airborne - North America (COBRA-NA 2003) study. The data obtained during 87 flight hours are geographically extensive (>30,000 km) including two 11,000 km flight circuits across both countries. More than 50 pollution "events" with statistically significant ODS:CO emission ratios were sampled, and for each event we have determined a flux footprint using the Stochastic Time-Inverted Lagrangian Transport (STILT) model. The model also calculates footprint-weighted average population densities and CO fluxes which we convert to footprint-weighted average ODS fluxes using the measured ODS:CO emission ratios. Statistically robust relationships between footprint-averaged ODS fluxes and population densities for several ODS indicate that population-based extrapolations of these relationships to national levels are warranted. Emission estimates for the USA and Canada in 2003 will be presented and compared to the magnitudes of global emissions.

Never Trust Anyone Over 30: Mitigation Strategies for Adapting to Three Decades of Persistent Degassing at Kīlauea Volcano, Hawai'i

NASA Astrophysics Data System (ADS)

Elias, T.; Sutton, A. J.; Tam, E.; Businger, S.; Horton, K. A.; Ley, D.; Petrie, L.

2014-12-01

As Kīlauea Volcano approaches its 33rd year of nearly continuous activity, simultaneous summit and rift eruptions continue to challenge island populations, agriculture, and infrastructure with elevated levels of acidic gases and particles. In 2008, the opening of a new summit vent attended a ten- to one hundred- fold increase in SO2 summit emissions which, combined with the ongoing east rift emissions, resulted in the highest combined annual SO2 release since regular measurements began in 1979. While the overall emissions have decreased in a step-wise manner since 2008, this large local source still contributes 20-60% of the SO2 emitted by all stationary fuel combustion sources in the U.S., and ~ 7-20% of the estimated time-averaged annual global volcanogenic SO2 contribution. Research on the long-term health and environmental effects of chronic exposure to volcanic pollution is ongoing in Hawai'i. Public health statistics suggest that incidences of respiratory emergency increased coincident with the onset of the summit eruption. From 2008-2011, Hawaii County received a Disaster Designation by the U.S. Secretary of Agriculture due to agricultural losses from the effects of volcanic emissions. A multifaceted approach is being used to address the current gas and particle hazards and to mitigate the impacts to affected areas. Multi-agency websites are providing forecast and real-time data regarding acid particle and SO2 gas concentrations to help people minimize their exposures. The short-term concentration data is linked to color-coded health-advisory levels developed by the U.S. Environmental Protection Agency and the Hawaii State Department of Health, with input from the National Park Service and the U.S. Geological Survey. Questions remain, however, on the appropriateness of the designated advisory levels for protecting chronically exposed populations, and if these tools are sufficiently useful to Hawai'i residents and visitors. Other mitigation efforts include community-based health interventions, indoor engineering controls, and innovations and relief programs within the agricultural sector.

Alternative Fuel Vehicle Adoption Increases Fleet Gasoline Consumption and Greenhouse Gas Emissions under United States Corporate Average Fuel Economy Policy and Greenhouse Gas Emissions Standards.

PubMed

Jenn, Alan; Azevedo, Inês M L; Michalek, Jeremy J

2016-03-01

The United States Corporate Average Fuel Economy (CAFE) standards and Greenhouse Gas (GHG) Emission standards are designed to reduce petroleum consumption and GHG emissions from light-duty passenger vehicles. They do so by requiring automakers to meet aggregate criteria for fleet fuel efficiency and carbon dioxide (CO2) emission rates. Several incentives for manufacturers to sell alternative fuel vehicles (AFVs) have been introduced in recent updates of CAFE/GHG policy for vehicles sold from 2012 through 2025 to help encourage a fleet technology transition. These incentives allow automakers that sell AFVs to meet less-stringent fleet efficiency targets, resulting in increased fleet-wide gasoline consumption and emissions. We derive a closed-form expression to quantify these effects. We find that each time an AFV is sold in place of a conventional vehicle, fleet emissions increase by 0 to 60 t of CO2 and gasoline consumption increases by 0 to 7000 gallons (26,000 L), depending on the AFV and year of sale. Using projections for vehicles sold from 2012 to 2025 from the Energy Information Administration, we estimate that the CAFE/GHG AFV incentives lead to a cumulative increase of 30 to 70 million metric tons of CO2 and 3 to 8 billion gallons (11 to 30 billion liters) of gasoline consumed over the vehicles' lifetimes - the largest share of which is due to legacy GHG flex-fuel vehicle credits that expire in 2016. These effects may be 30-40% larger in practice than we estimate here due to optimistic laboratory vehicle efficiency tests used in policy compliance calculations.

On the absolute calibration of SO2 cameras

USGS Publications Warehouse

Lübcke, Peter; Bobrowski, Nicole; Illing, Sebastian; Kern, Christoph; Alvarez Nieves, Jose Manuel; Vogel, Leif; Zielcke, Johannes; Delgados Granados, Hugo; Platt, Ulrich

2013-01-01

This work investigates the uncertainty of results gained through the two commonly used, but quite different, calibration methods (DOAS and calibration cells). Measurements with three different instruments, an SO2 camera, a NFOVDOAS system and an Imaging DOAS (I-DOAS), are presented. We compare the calibration-cell approach with the calibration from the NFOV-DOAS system. The respective results are compared with measurements from an I-DOAS to verify the calibration curve over the spatial extent of the image. The results show that calibration cells, while working fine in some cases, can lead to an overestimation of the SO2 CD by up to 60% compared with CDs from the DOAS measurements. Besides these errors of calibration, radiative transfer effects (e.g. light dilution, multiple scattering) can significantly influence the results of both instrument types. The measurements presented in this work were taken at Popocatepetl, Mexico, between 1 March 2011 and 4 March 2011. Average SO2 emission rates between 4.00 and 14.34 kg s−1 were observed.

Arcsecond Resolution Mapping of Sulfur Dioxide Emission in the Circumstellar Envelope of VY Canis Majoris

NASA Astrophysics Data System (ADS)

Fu, Roger R.; Moullet, Arielle; Patel, Nimesh A.; Biersteker, John; Derose, Kimberly L.; Young, Kenneth H.

2012-02-01

We report Submillimeter Array observations of SO2 emission in the circumstellar envelope (CSE) of the red supergiant VY Canis Majoris, with an angular resolution of ≈1''. SO2 emission appears in three distinct outflow regions surrounding the central continuum peak emission that is spatially unresolved. No bipolar structure is noted in the sources. A fourth source of SO2 is identified as a spherical wind centered at the systemic velocity. We estimate the SO2 column density and rotational temperature assuming local thermal equilibrium (LTE) as well as perform non-LTE radiative transfer analysis using RADEX. Column densities of SO2 are found to be ~1016 cm-2 in the outflows and in the spherical wind. Comparison with existing maps of the two parent species OH and SO shows the SO2 distribution to be consistent with that of OH. The abundance ratio f_{SO_{2}}/f_{SO} is greater than unity for all radii larger than 3 × 1016 cm. SO2 is distributed in fragmented clumps compared to SO, PN, and SiS molecules. These observations lend support to specific models of circumstellar chemistry that predict f_{SO_{2}}/f_{SO}>1 and may suggest the role of localized effects such as shocks in the production of SO2 in the CSE.

Trace gas emissions from combustion of peat, crop residue, domestic biofuels, grasses, and other fuels: configuration and Fourier transform infrared (FTIR) component of the fourth Fire Lab at Missoula Experiment (FLAME-4)

NASA Astrophysics Data System (ADS)

Stockwell, C. E.; Yokelson, R. J.; Kreidenweis, S. M.; Robinson, A. L.; DeMott, P. J.; Sullivan, R. C.; Reardon, J.; Ryan, K. C.; Griffith, D. W. T.; Stevens, L.

2014-09-01

During the fourth Fire Lab at Missoula Experiment (FLAME-4, October-November 2012) a large variety of regionally and globally significant biomass fuels was burned at the US Forest Service Fire Sciences Laboratory in Missoula, Montana. The particle emissions were characterized by an extensive suite of instrumentation that measured aerosol chemistry, size distribution, optical properties, and cloud-nucleating properties. The trace gas measurements included high-resolution mass spectrometry, one- and two-dimensional gas chromatography, and open-path Fourier transform infrared (OP-FTIR) spectroscopy. This paper summarizes the overall experimental design for FLAME-4 - including the fuel properties, the nature of the burn simulations, and the instrumentation employed - and then focuses on the OP-FTIR results. The OP-FTIR was used to measure the initial emissions of 20 trace gases: CO2, CO, CH4, C2H2, C2H4, C3H6, HCHO, HCOOH, CH3OH, CH3COOH, glycolaldehyde, furan, H2O, NO, NO2, HONO, NH3, HCN, HCl, and SO2. These species include most of the major trace gases emitted by biomass burning, and for several of these compounds, this is the first time their emissions are reported for important fuel types. The main fire types included African grasses, Asian rice straw, cooking fires (open (three-stone), rocket, and gasifier stoves), Indonesian and extratropical peat, temperate and boreal coniferous canopy fuels, US crop residue, shredded tires, and trash. Comparisons of the OP-FTIR emission factors (EFs) and emission ratios (ERs) to field measurements of biomass burning verify that the large body of FLAME-4 results can be used to enhance the understanding of global biomass burning and its representation in atmospheric chemistry models. Crop residue fires are widespread globally and account for the most burned area in the US, but their emissions were previously poorly characterized. Extensive results are presented for burning rice and wheat straw: two major global crop residues. Burning alfalfa produced the highest average NH3 EF observed in the study (6.63 ± 2.47 g kg-1), while sugar cane fires produced the highest EF for glycolaldehyde (6.92 g kg-1) and other reactive oxygenated organic gases such as HCHO, HCOOH, and CH3COOH. Due to the high sulfur and nitrogen content of tires, they produced the highest average SO2 emissions (26.2 ± 2.2 g kg-1) and high NOx and HONO emissions. High variability was observed for peat fire emissions, but they were consistently characterized by large EFs for NH3 (1.82 ± 0.60 g kg-1) and CH4 (10.8 ± 5.6 g kg-1). The variability observed in peat fire emissions, the fact that only one peat fire had previously been subject to detailed emissions characterization, and the abundant emissions from tropical peatlands all impart high value to our detailed measurements of the emissions from burning three Indonesian peat samples. This study also provides the first EFs for HONO and NO2 for Indonesian peat fires. Open cooking fire emissions of HONO and HCN are reported for the first time, and the first emissions data for HCN, NO, NO2, HONO, glycolaldehyde, furan, and SO2 are reported for "rocket" stoves: a common type of improved cookstove. The HCN / CO emission ratios for cooking fires (1.72 × 10-3 ± 4.08 × 10-4) and peat fires (1.45 × 10-2 ± 5.47 × 10-3) are well below and above the typical values for other types of biomass burning, respectively. This would affect the use of HCN / CO observations for source apportionment in some regions. Biomass burning EFs for HCl are rare and are reported for the first time for burning African savanna grasses. High emissions of HCl were also produced by burning many crop residues and two grasses from coastal ecosystems. HCl could be the main chlorine-containing gas in very fresh smoke, but rapid partitioning to aerosol followed by slower outgassing probably occurs.

Understanding the variation in the millimeter-wave emission of Venus

NASA Technical Reports Server (NTRS)

Fahd, Antoine K.; Steffes, Paul G.

1992-01-01

Recent observations of the millimeter-wave emission from Venus at 112 GHz (2.6 mm) have shown significant variations in the continuum flux emission that may be attributed to the variability in the abundances of absorbing constituents in the Venus atmosphere. Such constituents include gaseous H2SO4, SO2, and liquid sulfuric acid (cloud condensates). Recently, Fahd and Steffes have shown that the effects of liquid H, SO4, and gaseous SO2 cannot completely account for this measured variability in the millimeter-wave emission of Venus. Thus, it is necessary to study the effect of gaseous H2SO4 on the millimeter-wave emission of Venus. This requires knowledge of the millimeter-wavelength (MMW) opacity of gaseous H2SO4, which unfortunately has never been determined for Venus-like conditions. We have measured the opacity of gaseous H2SO4 in a CO2 atmosphere at 550, 570, and 590 K, at 1 and 2 atm total pressure, and at a frequency of 94.1 GHz. Our results, in addition to previous centimeter-wavelength results are used to verify a modeling formalism for calculating the expected opacity of this gaseous mixture at other frequencies. This formalism is incorporated into a radiative transfer model to study the effect of gaseous H2SO4 on the MMW emission of Venus.

Climate and environmental effects of electric vehicles versus compressed natural gas vehicles in China: a life-cycle analysis at provincial level.

PubMed

Huo, Hong; Zhang, Qiang; Liu, Fei; He, Kebin

2013-02-05

Electric vehicles (EVs) and compressed natural gas vehicles (CNGVs), which are mainly coal-based and natural gas-based, are the two most widely proposed replacements of gasoline internal combustion engine vehicles (ICEVs) in P.R. China. We examine fuel-cycle emissions of greenhouse gases (GHGs), PM(2.5), PM(10), NO(x), and SO(2) of CNGVs and EVs relative to gasoline ICEVs and hybrids, by Chinese province. CNGVs can currently reduce emissions of GHGs, PM(10), PM(2,5), NO(x), and SO(2) by approximately 6%, 7%, 20%, 18% and 22%, respectively. EVs can reduce GHG emissions by 20%, but increase PM(10), PM(2.5), NO(x), and SO(2) emissions by approximately 360%, 250%, 120%, and 370%, respectively. Nevertheless, results vary significantly by province. Regarding their contribution to national emissions, PM increases from EVs are unimportant, because light-duty passenger vehicles contribute very little to overall PM emissions nationwide (≤0.05%); however, their NO(x) and SO(2) increases are important. Since China is striving to reduce power plant emissions, EVs are expected to have equivalent or even lower SO(2) and NO(x) emissions relative to ICEVs in the future (2030). Before then, however, EVs should be developed according to the cleanness of regional power mixes. This would lower their SO(2) and NO(x) emissions and earn more GHG reduction credits.

40 CFR Appendix D to Part 75 - Optional SO2 Emissions Data Protocol for Gas-Fired and Oil-Fired Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Optional SO2 Emissions Data Protocol for Gas-Fired and Oil-Fired Units D Appendix D to Part 75 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Pt. 75, App. D Appendix D to Part 75—Optional SO2 Emissions Data...

Wintertime Emissions from Produced Water Ponds

NASA Astrophysics Data System (ADS)

Evans, J.; Lyman, S.; Mansfield, M. L.

2013-12-01

Every year oil and gas drilling in the U.S. generates billions of barrels of produced water (water brought to the surface during oil or gas production). Efficiently disposing of produced water presents a constant financial challenge for producers. The most noticeable disposal method in eastern Utah's Uintah Basin is the use of evaporation ponds. There are 427 acres of produced water ponds in the Uintah Basin, and these were used to evaporate more than 5 million barrels of produced water in 2012, 6% of all produced water in the Basin. Ozone concentrations exceeding EPA standards have been observed in the Uintah Basin during winter inversion conditions, with daily maximum 8 hour average concentrations at some research sites exceeding 150 parts per billion. Produced water contains ozone-forming volatile organic compounds (VOC) which escape into the atmosphere as the water is evaporated, potentially contributing to air quality problems. No peer-reviewed study of VOC emissions from produced water ponds has been reported, and filling this gap is essential for the development of accurate emissions inventories for the Uintah Basin and other air sheds with oil and gas production. Methane, carbon dioxide, and VOC emissions were measured at three separate pond facilities in the Uintah Basin in February and March of 2013 using a dynamic flux chamber. Pond emissions vary with meteorological conditions, so measurements of VOC emissions were collected during winter to obtain data relevant to periods of high ozone production. Much of the pond area at evaporation facilities was frozen during the study period, but areas that actively received water from trucks remained unfrozen. These areas accounted for 99.2% of total emissions but only 9.5% of the total pond area on average. Ice and snow on frozen ponds served as a cap, prohibiting VOC from being emitted into the atmosphere. Emissions of benzene, toluene, and other aromatic VOCs averaged over 150 mg m-2 h-1 from unfrozen pond surfaces. These compounds are highly reactive and, because of their relatively high water solubility, tend to concentrate in produced water. The average methanol emission rate from unfrozen pond surfaces was more than 100 mg m-2 h-1. Methanol, used as an antifreeze and anti-scaler in the oil and gas industry, is abundant during winter inversions in the Uintah Basin and may also be a significant precursor to ozone production. Total VOC and methanol emissions from produced water ponds during winter were estimated to be 178 and 83 tons month-1, respectively, for the entire Uintah Basin.

A Global Catalogue of Large SO2 Sources and Emissions Derived from the Ozone Monitoring Instrument

NASA Technical Reports Server (NTRS)

Fioletov, Vitali E.; McLinden, Chris A.; Krotkov, Nickolay; Li, Can; Joiner, Joanna; Theys, Nicolas; Carn, Simon; Moran, Mike D.

2016-01-01

Sulfur dioxide (SO2) measurements from the Ozone Monitoring Instrument (OMI) satellite sensor processed with the new principal component analysis (PCA) algorithm were used to detect large point emission sources or clusters of sources. The total of 491 continuously emitting point sources releasing from about 30 kt yr(exp -1) to more than 4000 kt yr(exp -1) of SO2 per year have been identified and grouped by country and by primary source origin: volcanoes (76 sources); power plants (297); smelters (53); and sources related to the oil and gas industry (65). The sources were identified using different methods, including through OMI measurements themselves applied to a new emission detection algorithm, and their evolution during the 2005- 2014 period was traced by estimating annual emissions from each source. For volcanic sources, the study focused on continuous degassing, and emissions from explosive eruptions were excluded. Emissions from degassing volcanic sources were measured, many for the first time, and collectively they account for about 30% of total SO2 emissions estimated from OMI measurements, but that fraction has increased in recent years given that cumulative global emissions from power plants and smelters are declining while emissions from oil and gas industry remained nearly constant. Anthropogenic emissions from the USA declined by 80% over the 2005-2014 period as did emissions from western and central Europe, whereas emissions from India nearly doubled, and emissions from other large SO2-emitting regions (South Africa, Russia, Mexico, and the Middle East) remained fairly constant. In total, OMI-based estimates account for about a half of total reported anthropogenic SO2 emissions; the remaining half is likely related to sources emitting less than 30 kt yr(exp -1) and not detected by OMI.

Impact of external industrial sources on the regional and local SO2 and O3 levels of the Mexico megacity

NASA Astrophysics Data System (ADS)

Almanza, V. H.; Molina, L. T.; Li, G.; Fast, J.; Sosa, G.

2014-08-01

The air quality of megacities can be influenced by external emission sources on both global and regional scales. At the same time their outflow emissions can exert an impact to the surrounding environment. The present study evaluates an SO2 peak observed on 24 March 2006 at the suburban supersite T1 and at ambient air quality monitoring stations located in the northern region of the Mexico City Metropolitan Area (MCMA) during the Megacity Initiative: Local and Global Research Observations (MILAGRO) field campaign. We found that this peak could be related to an important episodic emission event coming from Tizayuca region, northeast of the MCMA. Back-trajectory analyses suggest that the emission event started in the early morning at 04:00 LST and lasted for about 9 h. The estimated emission rate is about 2 kg s-1. To the best of our knowledge, sulfur dioxide emissions from the Tizayuca region have not been considered in previous studies. This finding suggests the possibility of "overlooked" emission sources in this region that could influence the air quality of the MCMA. This further motivated us to study the cement plants, including those in the state of Hidalgo and in the State of Mexico. It was found that they can contribute to the SO2 levels in the northeast (NE) region of the basin (about 42%), at the suburban supersite T1 (41%) and that at some monitoring stations their contribution can be even higher than the contribution from the Tula Industrial Complex (TIC). The contribution of the Tula Industrial Complex to regional ozone levels is estimated. The model suggests low contribution to the MCMA (1 to 4 ppb) and slightly higher contribution at the suburban T1 (6 ppb) and rural T2 (5 ppb) supersites. However, the contribution could be as high as 10 ppb in the upper northwest region of the basin and in the southwest and south-southeast regions of the state of Hidalgo. In addition, the results indicated that the ozone plume could also be transported to northwest Tlaxcala, eastern Hidalgo, and farther northeast of the State of Mexico, but with rather low values. A first estimate of the potential contribution from flaring activities to regional ozone levels is presented. Results suggest that up to 30% of the total regional ozone from TIC could be related to flaring activities. Finally, the influence on SO2 levels from technological changes in the existing refinery is briefly discussed. These changes are due to the upcoming construction of a new refinery in Tula. The combination of emission reductions in the power plant, the refinery and in local sources in the MCMA could result in higher reductions on the average SO2 concentration. Reductions in external sources tend to affect more the northern part of the basin (-16 to -46%), while reductions of urban sources in the megacity tend to diminish SO2 levels substantially in the central, southwest, and southeast regions (-31 to -50%).

Characterizing reduced sulfur compounds emissions from a swine concentrated animal feeding operation

NASA Astrophysics Data System (ADS)

Rumsey, Ian C.; Aneja, Viney P.; Lonneman, William A.

2014-09-01

Reduced sulfur compounds (RSCs) emissions from concentrated animal feeding operations (CAFOs) have become a potential environmental and human health concern, as a result of changes in livestock production methods. RSC emissions were determined from a swine CAFO in North Carolina. RSC measurements were made over a period of ≈1 week from both the barn and lagoon during each of the four seasonal periods from June 2007 to April 2008. During sampling, meteorological and other environmental parameters were measured continuously. Seasonal hydrogen sulfide (H2S) barn concentrations ranged from 72 to 631 ppb. Seasonal dimethyl sulfide (DMS; CH3SCH3) and dimethyl disulfide (DMDS; CH3S2CH3) concentrations were 2-3 orders of magnitude lower, ranging from 0.18 to 0.89 ppb and 0.47 to 1.02 ppb, respectively. The overall average barn emission rate was 3.3 g day-1 AU-1 (AU (animal unit) = 500 kg of live animal weight) for H2S, which was approximately two orders of magnitude higher than the DMS and DMDS overall average emissions rates, determined as 0.017 g day-1 AU-1 and 0.036 g day-1 AU-1, respectively. The overall average lagoon flux was 1.33 μg m-2 min-1 for H2S, which was approximately an order of magnitude higher than the overall average DMS (0.12 μg m-2 min-1) and DMDS (0.09 μg m-2 min-1) lagoon fluxes. The overall average lagoon emission for H2S (0.038 g day-1 AU-1) was also approximately an order of magnitude higher than the overall average DMS (0.0034 g day-1 AU-1) and DMDS (0.0028 g day-1 AU-1) emissions. H2S, DMS and DMDS have offensive odors and low odor thresholds. Over all four sampling seasons, 77% of 15 min averaged H2S barn concentrations were an order of magnitude above the average odor threshold. During these sampling periods, however, DMS and DMDS concentrations did not exceed their odor thresholds. The overall average barn and lagoon emissions from this study were used to help estimate barn, lagoon and total (barn + lagoon) RSC emissions from swine CAFOs in North Carolina. Total (barn + lagoon) H2S emissions from swine CAFOs in North Carolina were estimated to be 1.22*106 kg yr-1. The barns had significantly higher H2S emissions than the lagoons, contributing ≈98% of total North Carolina H2S swine CAFO emissions. Total (barn + lagoon) emissions for DMS and DMDS were 1-2 orders of magnitude lower, with barns contributing ≈86% and ≈93% of total emissions, respectively. H2S swine CAFO emissions were estimated to contribute ≈18% of North Carolina H2S emissions.

Updated SO2 emission estimates over China using OMI/Aura observations

NASA Astrophysics Data System (ADS)

Elissavet Koukouli, Maria; Theys, Nicolas; Ding, Jieying; Zyrichidou, Irene; Mijling, Bas; Balis, Dimitrios; van der A, Ronald Johannes

2018-03-01

The main aim of this paper is to update existing sulfur dioxide (SO2) emission inventories over China using modern inversion techniques, state-of-the-art chemistry transport modelling (CTM) and satellite observations of SO2. Within the framework of the EU Seventh Framework Programme (FP7) MarcoPolo (Monitoring and Assessment of Regional air quality in China using space Observations) project, a new SO2 emission inventory over China was calculated using the CHIMERE v2013b CTM simulations, 10 years of Ozone Monitoring Instrument (OMI)/Aura total SO2 columns and the pre-existing Multi-resolution Emission Inventory for China (MEIC v1.2). It is shown that including satellite observations in the calculations increases the current bottom-up MEIC inventory emissions for the entire domain studied (15-55° N, 102-132° E) from 26.30 to 32.60 Tg annum-1, with positive updates which are stronger in winter ( ˜ 36 % increase). New source areas were identified in the southwest (25-35° N, 100-110° E) as well as in the northeast (40-50° N, 120-130° E) of the domain studied as high SO2 levels were observed by OMI, resulting in increased emissions in the a posteriori inventory that do not appear in the original MEIC v1.2 dataset. Comparisons with the independent Emissions Database for Global Atmospheric Research, EDGAR v4.3.1, show a satisfying agreement since the EDGAR 2010 bottom-up database provides 33.30 Tg annum-1 of SO2 emissions. When studying the entire OMI/Aura time period (2005 to 2015), it was shown that the SO2 emissions remain nearly constant before the year 2010, with a drift of -0.51 ± 0.38 Tg annum-1, and show a statistically significant decline after the year 2010 of -1.64 ± 0.37 Tg annum-1 for the entire domain. Similar findings were obtained when focusing on the greater Beijing area (30-40° N, 110-120° E) with pre-2010 drifts of -0.17 ± 0.14 and post-2010 drifts of -0.47 ± 0.12 Tg annum-1. The new SO2 emission inventory is publicly available and forms part of the official EU MarcoPolo emission inventory over China, which also includes updated NOx, volatile organic compounds and particulate matter emissions.

Air pollution over the North China Plain and its implication of regional transport: A new sight from the observed evidences.

PubMed

Ge, Baozhu; Wang, Zifa; Lin, Weili; Xu, Xiaobin; Li, Jie; Ji, Dongshen; Ma, Zhiqiang

2018-03-01

High concentrations of the fine particles (PM 2.5 ) are frequently observed during all seasons over the North China Plain (NCP) region in recent years. In NCP, the contributions of regional transports to certain area, e.g. Beijing city, are often discussed and estimated by models when considering an effective air pollution controlling strategy. In this study, we selected three sites from southwest to northeast in NCP, in which the concentrations of air pollutants displayed a multi-step decreasing trend in space. An approach based on the measurement results at these sites has been developed to calculate the relative contributions of the minimal local emission (MinLEC) and the maximum regional transport (MaxRTC) to the air pollutants (e.g., SO 2 , NO 2 , CO, PM 2.5 ) in Beijing. The minimal influence of local emission is estimated by the difference of the air pollutants' concentrations between urban and rural areas under the assumption of a similar influence of regional transport. Therefore, it's convenient to estimate the contributions of local emission from regional transport based on the selective measurement results instead of the complex numerical model simulation. For the whole year of 2013, the averaged contributions of MinLEC (MaxRTC) for NO 2 , SO 2 , PM 2.5 and CO are 61.7% (30.7%), 46.6% (48%), 52.1% (40.2%) and 35.8% (45.5%), respectively. The diurnal variation of MaxRTC for SO 2 , PM 2.5 and CO shows an increased pattern during the afternoon and reached a peak (more than 50%) around 18:00, which indicates that the regional transport is the important role for the daytime air pollution in Beijing. Copyright © 2017 Elsevier Ltd. All rights reserved.

Quantifying population exposure to airborne particulate matter during extreme events in California due to climate change

NASA Astrophysics Data System (ADS)

Mahmud, A.; Hixson, M.; Kleeman, M. J.

2012-02-01

The effect of climate change on population-weighted concentrations of particulate matter (PM) during extreme events was studied using the Parallel Climate Model (PCM), the Weather Research and Forecasting (WRF) model and the UCD/CIT 3-D photochemical air quality model. A "business as usual" (B06.44) global emissions scenario was dynamically downscaled for the entire state of California between the years 2000-2006 and 2047-2053. Air quality simulations were carried out for 1008 days in each of the present-day and future climate conditions using year-2000 emissions. Population-weighted concentrations of PM0.1, PM2.5, and PM10 total mass, components species, and primary source contributions were calculated for California and three air basins: the Sacramento Valley air basin (SV), the San Joaquin Valley air basin (SJV) and the South Coast Air Basin (SoCAB). Results over annual-average periods were contrasted with extreme events. Climate change between 2000 vs. 2050 did not cause a statistically significant change in annual-average population-weighted PM2.5 mass concentrations within any major sub-region of California in the current study. Climate change did alter the annual-average composition of the airborne particles in the SoCAB, with notable reductions of elemental carbon (EC; -3%) and organic carbon (OC; -3%) due to increased annual-average wind speeds that diluted primary concentrations from gasoline combustion (-3%) and food cooking (-4%). In contrast, climate change caused significant increases in population-weighted PM2.5 mass concentrations in central California during extreme events. The maximum 24-h average PM2.5 concentration experienced by an average person during a ten-year period in the SJV increased by 21% due to enhanced production of secondary particulate matter (manifested as NH4NO3). In general, climate change caused increased stagnation during future extreme pollution events, leading to higher exposure to diesel engines particles (+32%) and wood combustion particles (+14%) when averaging across the population of the entire state. Enhanced stagnation also isolated populations from distant sources such as shipping (-61%) during extreme events. The combination of these factors altered the statewide population-averaged composition of particles during extreme events, with EC increasing by 23%, nitrate increasing by 58%, and sulfate decreasing by 46%.

Quantifying population exposure to airborne particulate matter during extreme events in California due to climate change

NASA Astrophysics Data System (ADS)

Mahmud, A.; Hixson, M.; Kleeman, M. J.

2012-08-01

The effect of climate change on population-weighted concentrations of particulate matter (PM) during extreme pollution events was studied using the Parallel Climate Model (PCM), the Weather Research and Forecasting (WRF) model and the UCD/CIT 3-D photochemical air quality model. A "business as usual" (B06.44) global emissions scenario was dynamically downscaled for the entire state of California between the years 2000-2006 and 2047-2053. Air quality simulations were carried out for 1008 days in each of the present-day and future climate conditions using year-2000 emissions. Population-weighted concentrations of PM0.1, PM2.5, and PM10 total mass, components species, and primary source contributions were calculated for California and three air basins: the Sacramento Valley air basin (SV), the San Joaquin Valley air basin (SJV) and the South Coast Air Basin (SoCAB). Results over annual-average periods were contrasted with extreme events. The current study found that the change in annual-average population-weighted PM2.5 mass concentrations due to climate change between 2000 vs. 2050 within any major sub-region in California was not statistically significant. However, climate change did alter the annual-average composition of the airborne particles in the SoCAB, with notable reductions of elemental carbon (EC; -3%) and organic carbon (OC; -3%) due to increased annual-average wind speeds that diluted primary concentrations from gasoline combustion (-3%) and food cooking (-4%). In contrast, climate change caused significant increases in population-weighted PM2.5 mass concentrations in central California during extreme events. The maximum 24-h average PM2.5 concentration experienced by an average person during a ten-yr period in the SJV increased by 21% due to enhanced production of secondary particulate matter (manifested as NH4NO3). In general, climate change caused increased stagnation during future extreme pollution events, leading to higher exposure to diesel engines particles (+32%) and wood combustion particles (+14%) when averaging across the population of the entire state. Enhanced stagnation also isolated populations from distant sources such as shipping (-61%) during extreme events. The combination of these factors altered the statewide population-averaged composition of particles during extreme events, with EC increasing by 23 %, nitrate increasing by 58%, and sulfate decreasing by 46%.

Weekday/weekend differences in ambient aerosol level and chemical characteristics of water-soluble components in the city centre

NASA Astrophysics Data System (ADS)

Khoder, M. I.; Hassan, S. K.

Weekday and weekend ambient aerosol samples were collected from the city centre of Cairo, namely "Ramsis" during the summer season of the year 2006, and have been analyzed for water-soluble ionic species. The average concentrations of the total suspended particulate matter (TSP) and their water-soluble components were higher during weekdays than on weekends, indicating that the decreased traffic density on weekends leads to a decrease in the levels of the TSP and their water-soluble ionic species. The average concentrations of the TSP were 454 μg m -3 on weekdays and 298 μg m -3 on weekends. The weekday/weekend concentration ratios were 1.52 for TSP, 1.27 for SO 42-, 1.64 for Cl -, 1.54 for NO 3-, 1.17 for NH 4+, 1.67 for Ca 2+, 1.83 for Na +, 1.75 for K + and 1.73 for Mg 2+. City centre of Cairo has high levels of the TSP and their water-soluble ionic species compared with many polluted cities in the world. Among all of the measured water-soluble components, SO 42- was the most abundant species followed by Ca 2+ on weekdays and weekends. The average mass ratios of NO 3-/SO 42- in the TSP were 0.41 on weekdays and 0.34 on weekends, suggesting that the stationary source emissions were more predominant. The NH 4+/SO 42- molar ratios and its relation with the concentrations of TSP and Ca 2+ during the weekdays and weekends indicate that the chemical form of sulfate and ammonium in aerosol particles varies with TSP and Ca 2+ levels. At high TSP and Ca 2+ levels, and NH 4+/SO 42- molar ratios less than one, SO 42- in aerosol particles may be present as CaSO 4 and (NH 4) 2SO 4·CaSO 4·2H 2O, whereas it is expected to be present as (NH 4) 2SO 4, (NH 4) 2SO 4·CaSO 4·2H 2O and CaSO 4 at low levels of TSP and Ca 2+, and NH 4+/SO 42- molar ratios between 1 and 2. The mean pH values of the TSP were 7.65 on weekdays and 6.97 on weekends, indicating that aerosol particles brought a large amount of crustal species, and might alleviate the tendency of acidification. The relationships between the concentrations of acidic components (NO 3- and SO 42-) and basic components (NH 4+, Ca 2+ and Mg 2+) on weekdays and weekends indicate that the acidity of aerosol particles is neutralized. Ca 2+ and NH 4+ are the most dominant neutralization substances in Cairo atmosphere.

The future of airborne sulfur-containing particles in the absence of fossil fuel sulfur dioxide emissions

DOE PAGES

Perraud, Véronique; Horne, Jeremy R.; Martinez, Andrew S.; ...

2015-10-19

Sulfuric acid (H2SO4), formed from oxidation of sulfur dioxide (SO2) emitted during fossil fuel combustion, is a major precursor of new airborne particles, which have well-documented detrimental effects on health, air quality, and climate. Another precursor is methanesulfonic acid (MSA), produced simultaneously with SO2 during the atmospheric oxidation of organosulfur compounds (OSCs), such as dimethyl sulfide. In the present paper, a multidisciplinary approach is used to examine how contributions of H2SO4 and MSA to particle formation will change in a large coastal urban area as anthropogenic fossil fuel emissions of SO2 decline. The 3-dimensional University of California Irvine–California Institute ofmore » Technology airshed model is used to compare atmospheric concentrations of gas phase MSA, H2SO4, and SO2 under current emissions of fossil fuel-associated SO2 and a best-case futuristic scenario with zero fossil fuel sulfur emissions. Model additions include results from (i) quantum chemical calculations that clarify the previously uncertain gas phase mechanism of formation of MSA and (ii) a combination of published and experimental estimates of OSC emissions, such as those from marine, agricultural, and urban processes, which include pet waste and human breath. Results show that in the zero anthropogenic SO2 emissions case, particle formation potential from H2SO4 will drop by about two orders of magnitude compared with the current situation. However, particles will continue to be generated from the oxidation of natural and anthropogenic sources of OSCs, with contributions from MSA and H2SO4 of a similar order of magnitude. Finally, this could be particularly important in agricultural areas where there are significant sources of OSCs.« less

The future of airborne sulfur-containing particles in the absence of fossil fuel sulfur dioxide emissions.

PubMed

Perraud, Véronique; Horne, Jeremy R; Martinez, Andrew S; Kalinowski, Jaroslaw; Meinardi, Simone; Dawson, Matthew L; Wingen, Lisa M; Dabdub, Donald; Blake, Donald R; Gerber, R Benny; Finlayson-Pitts, Barbara J

2015-11-03

Sulfuric acid (H2SO4), formed from oxidation of sulfur dioxide (SO2) emitted during fossil fuel combustion, is a major precursor of new airborne particles, which have well-documented detrimental effects on health, air quality, and climate. Another precursor is methanesulfonic acid (MSA), produced simultaneously with SO2 during the atmospheric oxidation of organosulfur compounds (OSCs), such as dimethyl sulfide. In the present work, a multidisciplinary approach is used to examine how contributions of H2SO4 and MSA to particle formation will change in a large coastal urban area as anthropogenic fossil fuel emissions of SO2 decline. The 3-dimensional University of California Irvine-California Institute of Technology airshed model is used to compare atmospheric concentrations of gas phase MSA, H2SO4, and SO2 under current emissions of fossil fuel-associated SO2 and a best-case futuristic scenario with zero fossil fuel sulfur emissions. Model additions include results from (i) quantum chemical calculations that clarify the previously uncertain gas phase mechanism of formation of MSA and (ii) a combination of published and experimental estimates of OSC emissions, such as those from marine, agricultural, and urban processes, which include pet waste and human breath. Results show that in the zero anthropogenic SO2 emissions case, particle formation potential from H2SO4 will drop by about two orders of magnitude compared with the current situation. However, particles will continue to be generated from the oxidation of natural and anthropogenic sources of OSCs, with contributions from MSA and H2SO4 of a similar order of magnitude. This could be particularly important in agricultural areas where there are significant sources of OSCs.

The future of airborne sulfur-containing particles in the absence of fossil fuel sulfur dioxide emissions

PubMed Central

Perraud, Véronique; Horne, Jeremy R.; Martinez, Andrew S.; Kalinowski, Jaroslaw; Meinardi, Simone; Dawson, Matthew L.; Wingen, Lisa M.; Dabdub, Donald; Blake, Donald R.; Gerber, R. Benny; Finlayson-Pitts, Barbara J.

2015-01-01

Sulfuric acid (H2SO4), formed from oxidation of sulfur dioxide (SO2) emitted during fossil fuel combustion, is a major precursor of new airborne particles, which have well-documented detrimental effects on health, air quality, and climate. Another precursor is methanesulfonic acid (MSA), produced simultaneously with SO2 during the atmospheric oxidation of organosulfur compounds (OSCs), such as dimethyl sulfide. In the present work, a multidisciplinary approach is used to examine how contributions of H2SO4 and MSA to particle formation will change in a large coastal urban area as anthropogenic fossil fuel emissions of SO2 decline. The 3-dimensional University of California Irvine–California Institute of Technology airshed model is used to compare atmospheric concentrations of gas phase MSA, H2SO4, and SO2 under current emissions of fossil fuel-associated SO2 and a best-case futuristic scenario with zero fossil fuel sulfur emissions. Model additions include results from (i) quantum chemical calculations that clarify the previously uncertain gas phase mechanism of formation of MSA and (ii) a combination of published and experimental estimates of OSC emissions, such as those from marine, agricultural, and urban processes, which include pet waste and human breath. Results show that in the zero anthropogenic SO2 emissions case, particle formation potential from H2SO4 will drop by about two orders of magnitude compared with the current situation. However, particles will continue to be generated from the oxidation of natural and anthropogenic sources of OSCs, with contributions from MSA and H2SO4 of a similar order of magnitude. This could be particularly important in agricultural areas where there are significant sources of OSCs. PMID:26483454

The future of airborne sulfur-containing particles in the absence of fossil fuel sulfur dioxide emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Perraud, Véronique; Horne, Jeremy R.; Martinez, Andrew S.

Sulfuric acid (H2SO4), formed from oxidation of sulfur dioxide (SO2) emitted during fossil fuel combustion, is a major precursor of new airborne particles, which have well-documented detrimental effects on health, air quality, and climate. Another precursor is methanesulfonic acid (MSA), produced simultaneously with SO2 during the atmospheric oxidation of organosulfur compounds (OSCs), such as dimethyl sulfide. In the present paper, a multidisciplinary approach is used to examine how contributions of H2SO4 and MSA to particle formation will change in a large coastal urban area as anthropogenic fossil fuel emissions of SO2 decline. The 3-dimensional University of California Irvine–California Institute ofmore » Technology airshed model is used to compare atmospheric concentrations of gas phase MSA, H2SO4, and SO2 under current emissions of fossil fuel-associated SO2 and a best-case futuristic scenario with zero fossil fuel sulfur emissions. Model additions include results from (i) quantum chemical calculations that clarify the previously uncertain gas phase mechanism of formation of MSA and (ii) a combination of published and experimental estimates of OSC emissions, such as those from marine, agricultural, and urban processes, which include pet waste and human breath. Results show that in the zero anthropogenic SO2 emissions case, particle formation potential from H2SO4 will drop by about two orders of magnitude compared with the current situation. However, particles will continue to be generated from the oxidation of natural and anthropogenic sources of OSCs, with contributions from MSA and H2SO4 of a similar order of magnitude. Finally, this could be particularly important in agricultural areas where there are significant sources of OSCs.« less

The advantage of calculating emission reduction with local emission factor in South Sumatera region

NASA Astrophysics Data System (ADS)

Buchari, Erika

2017-11-01

Green House Gases (GHG) which have different Global Warming Potential, usually expressed in CO2 equivalent. German has succeeded in emission reduction of CO2 in year 1990s, while Japan since 2001 increased load factor of public transports. Indonesia National Medium Term Development Plan, 2015-2019, has set up the target of minimum 26% and maximum 41% National Emission Reduction in 2019. Intergovernmental Panel on Climate Change (IPCC), defined three types of accuracy in counting emission of GHG, as tier 1, tier 2, and tier 3. In tier 1, calculation is based on fuel used and average emission (default), which is obtained from statistical data. While in tier 2, calculation is based fuel used and local emission factors. Tier 3 is more accurate from those in tier 1 and 2, and the calculation is based on fuel used from modelling method or from direct measurement. This paper is aimed to evaluate the calculation with tier 2 and tier 3 in South Sumatera region. In 2012, Regional Action Plan for Greenhouse Gases of South Sumatera for 2020 is about 6,569,000 ton per year and with tier 3 is about without mitigation and 6,229,858.468 ton per year. It was found that the calculation in tier 3 is more accurate in terms of fuel used of variation vehicles so that the actions of mitigation can be planned more realistically.

A New Global Anthropogenic SO2 Emission Inventory for the Last Decade: A Mosaic of Satellite-derived and Bottom-up Emissions

NASA Astrophysics Data System (ADS)

Liu, F.; Joiner, J.; Choi, S.; Krotkov, N. A.; Li, C.; Fioletov, V. E.; McLinden, C. A.

2017-12-01

Sulfur dioxide (SO2) measurements from the Ozone Monitoring Instrument (OMI) satellite sensor have been used to detect emissions from large point sources using an innovative estimation technique. Emissions from about 500 sources have been quantified individually based on OMI observations, accounting for about a half of total reported anthropogenic SO2 emissions. We developed a new emission inventory, OMI-HTAP, by combining these OMI-based emission estimates and the conventional bottom-up inventory. OMI-HTAP includes OMI-based estimates for over 400 point sources and is gap-filled with the emission grid map of the latest available global bottom-up emission inventory (HTAP v2.2) for the rest of sources. We have evaluated the OMI-HTAP inventory by performing simulations with the Goddard Earth Observing System version 5 (GEOS-5) model. The GEOS-5 simulated SO2 concentrations driven by both the HTAP and the OMI-HTAP inventory were compared against in-situ and satellite measurements. Results show that the OMI-HTAP inventory improves the model agreement with observations, in particular over the US, India and the Middle East. Additionally, simulations with the OMI-HTAP inventory capture the major trends of anthropogenic SO2 emissions over the world and highlight the influence of missing sources in the bottom-up inventory.

Aura OMI Observations of Global SO2 and NO2 Pollution from 2005 to 2013

NASA Technical Reports Server (NTRS)

Krotkov, Nickolay; Li, Can; Lamsal, Lok; Celarier, Edward; Marchenko, Sergey; Swartz, William H.; Bucsela, Eric; Fioletov, Vitali; McLinden, Chris; Joiner, Joanna;

Carbon dioxide emission tallies for 210 U.S. coal-fired power plants: a comparison of two accounting methods.

PubMed

Quick, Jeffrey C

2014-01-01

Annual CO2 emission tallies for 210 coal-fired power plants during 2009 were more accurately calculated from fuel consumption records reported by the US. Energy Information Administration (EIA) than measurements from Continuous Emissions Monitoring Systems (CEMS) reported by the US. Environmental Protection Agency. Results from these accounting methods for individual plants vary by +/- 10.8%. Although the differences systematically vary with the method used to certify flue-gas flow instruments in CEMS, additional sources of CEMS measurement error remain to be identified. Limitations of the EIA fuel consumption data are also discussed. Consideration of weighing, sample collection, laboratory analysis, emission factor, and stock adjustment errors showed that the minimum error for CO2 emissions calculated from the fuel consumption data ranged from +/- 1.3% to +/- 7.2% with a plant average of +/- 1.6%. This error might be reduced by 50% if the carbon content of coal delivered to U.S. power plants were reported. Potentially, this study might inform efforts to regulate CO2 emissions (such as CO2 performance standards or taxes) and more immediately, the U.S. Greenhouse Gas Reporting Rule where large coal-fired power plants currently use CEMS to measure CO2 emissions. Moreover, if, as suggested here, the flue-gas flow measurement limits the accuracy of CO2 emission tallies from CEMS, then the accuracy of other emission tallies from CEMS (such as SO2, NOx, and Hg) would be similarly affected. Consequently, improved flue gas flow measurements are needed to increase the reliability of emission measurements from CEMS.

Simulated impacts of SO 2 emissions from the Miyake volcano on concentration and deposition of sulfur oxides in September and October of 2000

NASA Astrophysics Data System (ADS)

An, Junling; Ueda, Hiromasa; Matsuda, Kazuhide; Hasome, Hisashi; Iwata, Motokazu

A regional air quality Eulerian model was run for 2 months (September and October of 2000) with and without SO 2 emissions from the Miyake volcano to investigate effects of the changes in the volcanic emissions on SO 2 and sulfate concentrations and total sulfur deposition around the surrounding areas. Volcanic emissions were injected into different model layers in different proportions within the planetary boundary layer whereas the other emissions were released in the first model layer above the ground. Meteorological fields four times per day were taken from National Centers for Environmental Prediction (NCEP). Eight Japanese monitoring sites of EANET (Acid Deposition Monitoring Network in East Asia) were used for the model evaluation. Simulations indicate that emissions from the Miyake volcano lead to increases in SO 2 and sulfate concentrations in the surrounding areas downwind in the PBL by up to 300% and 150%, respectively, and those in SO 2 levels in the area found ˜390 km north away from the Miyake site in the free troposphere (FTR) by up to 120%. Total sulfur deposition amounts per month are also increased by up to 300%. Daily SO 2 concentrations in different model layers display strong variability (10-450%) at sites significantly influenced by the volcano. Comparison shows that the RAQM model predicts daily SO 2 variations at relatively clean sites better than those at inland sites closer to volcanoes and the model well captures the timing of SO 2 peaks caused by great changes in SO 2 emissions from the Miyake volcano at most chosen sites and that monthly simulated sulfate concentrations in rainwater agree quite well with observations with the difference within a factor of 2. Improvement in spatial and temporal resolutions of meteorological data and removal of the uncertainty of other volcanic emissions may better simulations.

Broadband UV spectroscopy system used for monitoring of SO 2 and NO emissions from thermal power plants

NASA Astrophysics Data System (ADS)

Zhang, Y. G.; Wang, H. S.; Somesfalean, G.; Wang, Z. Y.; Lou, X. T.; Wu, S. H.; Zhang, Z. G.; Qin, Y. K.

2010-11-01

A gas monitoring system based on broadband absorption spectroscopic techniques in the ultraviolet region is described and tested. The system was employed in real-time continuous concentration measurements of sulfur dioxide (SO 2) and nitric oxide (NO) from a 220-ton h -1 circulating fluidized bed (CFB) boiler in Shandong province, China. The emission coefficients (per kg of coal and per kWh of electricity) and the total emission of the two pollutant gases were evaluated. The measurement results showed that the emission concentrations of SO 2 and NO from the CFB boiler fluctuated in the range of 750-1300 mg m -3 and 100-220 mg m -3, respectively. Compared with the specified emission standards of air pollutants from thermal power plants in China, the values were generally higher for SO 2 and lower for NO. The relatively high emission concentrations of SO 2 were found to mainly depend on the sulfur content of the fuel and the poor desulfurization efficiency. This study indicates that the broadband UV spectroscopy system is suitable for industrial emission monitoring and pollution control.

Rates of volcanic CO2 degassing from airborne determinations of SO2 Emission rates and plume CO2SO2: test study at Pu′u ′O′o Cone, Kilauea Volcano, Hawaii

USGS Publications Warehouse

Gerlach, Terrence M.; McGee, Kenneth A.; Sutton, A. Jefferson; Elias, Tamar

1998-01-01

We present an airborne method that eliminates or minimizes several disadvantages of the customary plume cross-section sampling method for determining volcanic CO2 emission rates. A LI-COR CO2analyzer system (LICOR), a Fourier transform infrared spectrometer system (FTIR), and a correlation spectrometer (COSPEC) were used to constrain the plume CO2/SO2 and the SO2 emission rate. The method yielded a CO2 emission rate of 300 td−1 (metric tons per day) for Pu′u ′O′o cone, Kilauea volcano, on 19 September 1995. The CO2/SO2 of 0.20 determined from airborne LICOR and FTIR plume measurements agreed with the CO2/SO2 of 204 ground-based samples collected from vents over a 14-year period since the Pu′u ′O′o eruption began in January 1983.

Implications of near-term coal power plant retirement for SO2 and NOX and life cycle GHG emissions.

PubMed

Venkatesh, Aranya; Jaramillo, Paulina; Griffin, W Michael; Matthews, H Scott

2012-09-18

Regulations monitoring SO(2), NO(X), mercury, and other metal emissions in the U.S. will likely result in coal plant retirement in the near-term. Life cycle assessment studies have previously estimated the environmental benefits of displacing coal with natural gas for electricity generation, by comparing systems that consist of individual natural gas and coal power plants. However, such system comparisons may not be appropriate to analyze impacts of coal plant retirement in existing power fleets. To meet this limitation, simplified economic dispatch models for PJM, MISO, and ERCOT regions are developed in this study to examine changes in regional power plant dispatch that occur when coal power plants are retired. These models estimate the order in which existing power plants are dispatched to meet electricity demand based on short-run marginal costs, with cheaper plants being dispatched first. Five scenarios of coal plant retirement are considered: retiring top CO(2) emitters, top NO(X) emitters, top SO(2) emitters, small and inefficient plants, and old and inefficient plants. Changes in fuel use, life cycle greenhouse gas emissions (including uncertainty), and SO(2) and NO(X) emissions are estimated. Life cycle GHG emissions were found to decrease by less than 4% in almost all scenarios modeled. In addition, changes in marginal damage costs due to SO(2), and NO(X) emissions are estimated using the county level marginal damage costs reported in the Air Pollution Emissions Experiments and Policy (APEEP) model, which are a proxy for measuring regional impacts of SO(2) and NO(X) emissions. Results suggest that location specific parameters should be considered within environmental policy frameworks targeting coal plant retirement, to account for regional variability in the benefits of reducing the impact of SO(2) and NO(X) emissions.

The possible influences of the increasing anthropogenic emissions in India on tropospheric ozone and OH

NASA Astrophysics Data System (ADS)

Liu, Yu; Li, Weiliang; Zhou, Xiuji; Isaksen, I. S. A.; Sundet, J. K.; He, Jinhai

2003-11-01

A 3-D chemical transport model (OSLO CTM2) is used to investigate the influences of the increasing anthropogenic emission in India. The model is capable of reproducing the observational results of the INDOEX experiment and the measurements in summer over India well. The model results show that when NO x and CO emissions in India are doubled, ozone concentration increases, and global average OH decreases a little. Under the effects of the Indian summer monsoon, NO x and CO in India are efficiently transported into the middle and upper troposphere by the upward current and the convective activities so that the NO x , CO, and ozone in the middle and upper troposphere significantly increase with the increasing NO x and CO emissions. These increases extensively influence a part of Asia, Africa, and Europe, and persist from June to September.

Influence of sulfur dioxide-related interactions on PM2.5 formation in iron ore sintering.

PubMed

Ji, Zhiyun; Fan, Xiaohui; Gan, Min; Chen, Xuling; Lv, Wei; Li, Qiang; Zhou, Yang; Tian, Ye; Jiang, Tao

2017-04-01

The formation of PM 2.5 (aerosol particulate matter less than 2.5 µm in aerodynamic diameter) in association with SO 2 emission during sintering process has been studied by dividing the whole sintering process into six typical sampling stages. A low-pressure cascade impactor was used to collect PM 2.5 by automatically segregating particulates into six sizes. It was found that strong correlation existed between the emission properties of PM 2.5 and SO 2 . Wet mixture layer (overwetted layer and raw mixture layer) had the function to simultaneously capture SO 2 and PM 2.5 during the early sintering stages, and released them back into flue gas mainly in the flue gas temperature-rising period. CaSO 4 crystals constituted the main SO 2 -related PM 2.5 during the disappearing process of overwetted layer, which was able to form perfect individual crystals or to form particles with complex chemical compositions. Besides the existence of individual CaSO 4 crystals, mixed crystals of K 2 SO 4 -CaSO 4 in PM 2.5 were also found during the first half of the temperature-rising period of flue gas. The interaction between fine-grained Ca-based fluxes, potassium vapors, and SO 2 was the potential source of SO 2 -related PM 2.5 . The emission property of PM 2.5 and SO 2 throughout the sintering process exhibited well similarity. This phenomenon tightened the relationship between the formation of PM 2.5 and the emission of SO 2 . Through revealing the properties of SO 2 -related PM 2.5 during sintering process, the potential interaction between fine-grained Ca-based fluxes, potassium vapors, and SO 2 was found to be the source of SO 2 -related PM 2.5 . This information can serve as the guidance to develop efficient techniques to control the formation and emission of PM 2.5 in practical sintering plants.

The geographical distribution of fossil fuels unused when limiting global warming to 2 °C.

PubMed

McGlade, Christophe; Ekins, Paul

2015-01-08

Policy makers have generally agreed that the average global temperature rise caused by greenhouse gas emissions should not exceed 2 °C above the average global temperature of pre-industrial times. It has been estimated that to have at least a 50 per cent chance of keeping warming below 2 °C throughout the twenty-first century, the cumulative carbon emissions between 2011 and 2050 need to be limited to around 1,100 gigatonnes of carbon dioxide (Gt CO2). However, the greenhouse gas emissions contained in present estimates of global fossil fuel reserves are around three times higher than this, and so the unabated use of all current fossil fuel reserves is incompatible with a warming limit of 2 °C. Here we use a single integrated assessment model that contains estimates of the quantities, locations and nature of the world's oil, gas and coal reserves and resources, and which is shown to be consistent with a wide variety of modelling approaches with different assumptions, to explore the implications of this emissions limit for fossil fuel production in different regions. Our results suggest that, globally, a third of oil reserves, half of gas reserves and over 80 per cent of current coal reserves should remain unused from 2010 to 2050 in order to meet the target of 2 °C. We show that development of resources in the Arctic and any increase in unconventional oil production are incommensurate with efforts to limit average global warming to 2 °C. Our results show that policy makers' instincts to exploit rapidly and completely their territorial fossil fuels are, in aggregate, inconsistent with their commitments to this temperature limit. Implementation of this policy commitment would also render unnecessary continued substantial expenditure on fossil fuel exploration, because any new discoveries could not lead to increased aggregate production.

Impacts of traffic emissions on atmospheric particulate nitrate and organics at a downwind site on the periphery of Guangzhou, China

NASA Astrophysics Data System (ADS)

Qin, Yi Ming; Tan, Hao Bo; Jie Li, Yong; Schurman, Misha I.; Li, Fei; Canonaco, Francesco; Prévôt, André S. H.; Chan, Chak K.

2017-09-01

Particulate matter (PM) pollution on the peripheries of Chinese megacities can be as serious as in cities themselves. Given the substantial vehicular emissions in inner-city areas, the direct transport of primary PM (e.g., black carbon and primary organics) and effective formation of secondary PM from precursors (e.g., NOx and volatile organic compounds) can contribute to PM pollution in buffer zones between cities. To investigate how traffic emissions in inner-city areas impact these adjacent buffer zones, a suite of real-time instruments were deployed in Panyu, downwind from central Guangzhou, from November to December 2014. Nitrate mass fraction was higher on high-PM days, with the average nitrate-to-sulfate ratio increasing from around 0.35 to 1.5 as the PM mass concentration increased from 10 to 160 µg m-3. Particulate nitrate was strongly correlated with excess ammonium (([NH4+] / [SO42-] - 1.5) × [SO42-]), with higher concentrations in December than in November due to lower temperatures. The organic mass fraction was the highest across all PM1 levels throughout the campaign. While organic aerosols (OA) were dominated by secondary organic aerosols (SOA = semi-volatile oxygenated organic aerosols + low-volatility oxygenated organic aerosols) as a campaign average, freshly emitted hydrocarbon-like organic aerosols (HOA) contributed up to 40 % of OA during high-OA periods, which typically occurred at nighttime and contributed 23.8 to 28.4 % on average. This was due to daytime traffic restrictions on heavy-duty vehicles in Guangzhou, and HOA almost increased linearly with total OA concentration. SOA increased as odd oxygen (Ox = O3 + NO2) increased during the day due to photochemistry. A combination of nighttime traffic emissions and daytime photochemistry contributed to the buildup of PM in Panyu. The mitigation of PM pollution in inner-city areas by reducing vehicular traffic can potentially improve air quality in peripheral areas.

Fumarole/plume and diffuse CO2 emission from Sierra Negra caldera, Galapagos archipelago

NASA Astrophysics Data System (ADS)

Padrón, Eleazar; Hernández, Pedro A.; Pérez, Nemesio M.; Toulkeridis, Theofilos; Melián, Gladys; Barrancos, José; Virgili, Giorgio; Sumino, Hirochika; Notsu, Kenji

2012-08-01

Measurements of visible and diffuse gas emission were conducted in 2006 at the summit of Sierra Negra volcano, Galapagos, with the aim to better characterize degassing after the 2005 eruption. A total SO2 emission of 11 ± 2 t day-1 was derived from miniature differential optical absorption spectrometer (mini-DOAS) ground-based measurements of the plume emanating from the Mini Azufral fumarolic area, the most important site of visible degassing at Sierra Negra volcano. Using a portable multigas system, the H2S/SO2, CO2/SO2, and H2O/SO2 molar ratios in the Mina Azufral plume emissions were found to be 0.41, 52.2, and 867.9, respectively. The corresponding H2O, CO2, and H2S emission rates were 562, 394, and 3 t day-1, respectively. The total output of diffuse CO2 emissions from the summit of Sierra Negra volcano was 990 ± 85 t day-1, with 605 t day-1 being released by a deep source. The diffuse-to-plume CO2 emission ratio was about 1.5. Mina Azufral fumaroles released gasses containing 73.6 mol% of H2O; the main noncondensable components amounted to 97.4 mol% CO2, 1.5 mol% SO2, 0.6 mol% H2S, and 0.35 mol% N2. The higher H2S/SO2 ratio values found in 2006 as compared to those reported before the 2005 eruption reveal a significant hydrothermal contribution to the fumarolic emissions. 3He/4He ratios measured at Mina Azufral fumarolic discharges showed values of 17.88 ± 0.25 R A , indicating a mid-ocean ridge basalts (MORB) and a Galapagos plume contribution of 53 and 47 %, respectively.

A 15-year record (2001-2015) of the ratio of nitrate to non-sea-salt sulfate in precipitation over East Asia

NASA Astrophysics Data System (ADS)

Itahashi, Syuichi; Yumimoto, Keiya; Uno, Itsushi; Hayami, Hiroshi; Fujita, Shin-ichi; Pan, Yuepeng; Wang, Yuesi

2018-02-01

Acidifying species in precipitation can have severe impacts on ecosystems. The chemical composition of precipitation is directly related to the amount of precipitation; accordingly, it is difficult to identify long-term variation in chemical concentrations. The ratio of the nitrate (NO3-) to non-sea-salt sulfate (nss-SO42-) concentration in precipitation on an equivalent basis (hereinafter, Ratio) is a useful index to investigate the relative contributions of these acidifying species. To identify the long-term record of acidifying species in precipitation over East Asia, the region with the highest emissions worldwide, we compiled ground-based observations of the chemical composition of precipitation over China, Korea, and Japan from 2001 to 2015 based on the Acid Deposition Monitoring Network in East Asia (EANET). The spatial coverage was limited, but additional monitoring data for Japan, southern China, and northern China around Beijing were utilized. The period of analysis was divided into three phases: Phase I (2001-2005), Phase II (2006-2010), and Phase III (2011-2015). The behaviors of NO3- and nss-SO42- concentrations and hence the Ratio in precipitation were related to these precursors. The anthropogenic NOx and SO2 emissions and the NOx / SO2 emission ratio were analyzed. Further, satellite observations of the NO2 and SO2 column density to capture the variation in emissions were applied. We found that the long-term trend in the NO3- concentration in precipitation was not related to the variation in NOx emission and the NO2 column. In comparison, the nss-SO42- concentration in precipitation over China, Korea, and Japan was partially connected to the changes in SO2 emissions from China, but the trends were not significant. The long-term trends of Ratio over China, Korea, and Japan were nearly flat during Phase I, increased significantly during Phase II, and were essentially flat again during Phase III. This variation in Ratio in East Asia clearly corresponded to the NOx / SO2 emission ratio and the NO2 / SO2 column ratio in China. The initial flat trend during Phase I was due to increases in both NOx and SO2 emissions in China, the significantly increasing trend during Phase II was triggered by the increase in NOx emissions and decrease in SO2 emissions in China, and the return to a flat trend during Phase III was caused by declines in both NOx and SO2 emissions in China. These results suggest that emissions in China had a significant impact not only on China but also on downwind precipitation chemistry during the 15-year period of 2001-2015. In terms of wet deposition, the NO3- wet deposition over China, Korea, and Japan did not change dramatically, but the nss-SO42- wet deposition declined over China, Korea, and Japan from Phase II to III. These declines were caused by a strong decrease in the nss-SO42- concentration in precipitation accompanied by a reduction in SO2 emission from China, which counteracted the increase in precipitation. These findings indicated that the acidity of precipitation shifted from sulfur to nitrogen.

Impact of Ship Emissions on Marine Boundary Layer NO(x) and SO2 Distributions over the Pacific Basin

NASA Technical Reports Server (NTRS)

Davis, D. D.; Grodzinsky, G.; Kasibhatla, P.; Crawford, J.; Chen, G.; Liu, S.; Bandy, A.; Thornton, D.; Guan, H.; Sandholm, S.

2001-01-01

The impact of ship emissions on marine boundary layer (MBL) NO(x) and SO2 levels over the Pacific Ocean has been explored by comparing predictions (with and without ships) from a global chemical transport model (GCTM) against compiled airborne observations of MBL NO(x) and SO2. For latitudes above 15 N, which define that part of the Pacific having the heaviest shipping, this analysis revealed significant model over prediction for NOx and a modest under prediction for SO2 when ship emissions were considered. Possible reasons for the difference in NO(x) and SO2 were explored using a full-chemistry box model. These results revealed that for an actual plume setting the NO(x) lifetime could be greatly shortened by chemical processes promoted by ship plume emissions themselves. Similar chemical behavior was not found for SO2.

Contrasted spatial and long-term trends in precipitation chemistry and deposition fluxes at rural stations in France

NASA Astrophysics Data System (ADS)

Pascaud, A.; Sauvage, S.; Coddeville, P.; Nicolas, M.; Croisé, L.; Mezdour, A.; Probst, A.

2016-12-01

The long-distance effect of atmospheric pollution on ecosystems has led to the conclusion of international agreements to regulate atmospheric emissions and monitor their impact. This study investigated variations in atmospheric deposition chemistry in France using data gathered from three different monitoring networks (37 stations) over the period from 1995 to 2007. Despite some methodological differences (e.g. type of collector, frequency of sampling and analysis), converging results were found in spatial variations, seasonal patterns and temporal trends. With regard to spatial variations, the mean annual pH in particular ranged from 4.9 in the north-east to 5.8 in the south-east. This gradient was related to the concentration of NO3- and non-sea-salt SO42- (maximum volume-weighted mean of 38 and 31 μeq l-1 respectively) and of acid-neutralising compounds such as non-sea-salt Ca2+ and NH4+. In terms of seasonal variations, winter and autumn pH were linked to lower acidity neutralisation than during the warm season. The temporal trends in atmospheric deposition varied depending on the chemical species and site location. The most significant and widespread trend was the decrease in non-sea-salt SO42- concentrations (significant at 65% of the stations). At the same time, many stations showed an increasing trend in annual pH (+0.3 on average for 16 stations). These two trends are probably due to the reduction in SO2 emissions that has been imposed in Europe since the 1980s. Temporal trends in inorganic N concentrations were rather moderate and not consistent with the trends reported in emission estimates. Despite the reduction in NOx emissions, NO3- concentrations in atmospheric deposition remained mostly unchanged or even increased at three stations (+0.43 μeq l-1 yr-1 on average). In contrast NH4+ concentrations in atmospheric deposition decreased at several stations located in western and northern areas, while the estimates of NH3 emissions remained fairly stable. The decrease in non-sea-salt SO42- and NH4+ concentrations was mainly due to a decrease in summer values and can in part be related to a dilution process since the precipitation amount showed an increasing trend during the summer. Furthermore, increasing trends in NO3- concentrations in the spring and, to a lesser extent, in NH4+ concentrations suggested that other atmospheric physicochemical processes should also be taken into account.

40 CFR 74.25 - Current promulgated SO2 emissions limit.

Code of Federal Regulations, 2011 CFR

2011-07-01

... promulgated SO2 emissions limit of the combustion source, expressed in lbs/mmBtu, which shall be the most... date. If the promulgated SO2 emissions limit is not expressed in lbs/mmBtu, the limit shall be converted to lbs/mmBtu by multiplying the limit by the appropriate factor as specified in Table 1 of § 74.23...

40 CFR 60.4330 - What emission limits must I meet for sulfur dioxide (SO2)?

Code of Federal Regulations, 2012 CFR

2012-07-01

... sulfur dioxide (SO2)? 60.4330 Section 60.4330 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... sulfur dioxide (SO2)? (a) If your turbine is located in a continental area, you must comply with either... contains total potential sulfur emissions in excess of 26 ng SO2/J (0.060 lb SO2/MMBtu) heat input. If your...

40 CFR 60.4330 - What emission limits must I meet for sulfur dioxide (SO2)?

Code of Federal Regulations, 2010 CFR

2010-07-01

... sulfur dioxide (SO2)? 60.4330 Section 60.4330 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... sulfur dioxide (SO2)? (a) If your turbine is located in a continental area, you must comply with either... contains total potential sulfur emissions in excess of 26 ng SO2/J (0.060 lb SO2/MMBtu) heat input. If your...

40 CFR 60.4330 - What emission limits must I meet for sulfur dioxide (SO2)?

Code of Federal Regulations, 2011 CFR

2011-07-01

... sulfur dioxide (SO2)? 60.4330 Section 60.4330 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... sulfur dioxide (SO2)? (a) If your turbine is located in a continental area, you must comply with either... contains total potential sulfur emissions in excess of 26 ng SO2/J (0.060 lb SO2/MMBtu) heat input. If your...

40 CFR 60.4330 - What emission limits must I meet for sulfur dioxide (SO2)?

Code of Federal Regulations, 2013 CFR

2013-07-01

... sulfur dioxide (SO2)? 60.4330 Section 60.4330 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... sulfur dioxide (SO2)? (a) If your turbine is located in a continental area, you must comply with either... contains total potential sulfur emissions in excess of 26 ng SO2/J (0.060 lb SO2/MMBtu) heat input. If your...

40 CFR 60.4330 - What emission limits must I meet for sulfur dioxide (SO2)?

Code of Federal Regulations, 2014 CFR

2014-07-01

... sulfur dioxide (SO2)? 60.4330 Section 60.4330 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... sulfur dioxide (SO2)? (a) If your turbine is located in a continental area, you must comply with either... contains total potential sulfur emissions in excess of 26 ng SO2/J (0.060 lb SO2/MMBtu) heat input. If your...

A new SO2 emissions budget for Anatahan volcano (Mariana Islands) based on ten years of satellite observations

NASA Astrophysics Data System (ADS)

McCormick, Brendan; Popp, Christoph; Andrews, Benjamin; Cottrell, Elizabeth

2015-04-01

Satellite remote sensing offers great potential for the study of sulphur dioxide (SO2) gas emissions from volcanoes worldwide. Anatahan is a remote volcano in the Mariana Islands, SW Pacific. Existing SO2 emissions data from Anatahan, from ground-based UV spectrometer measurements, place the volcano among the largest natural SO2 sources worldwide. However, these measurements are limited in number and only available from intervals of eruptive activity. Activity varies widely at Anatahan: over the past decade, records held in the Smithsonian Institution Global Volcanism Program Volcanoes of the World database describe the alternation of intense eruptions with long intervals of quiescence, where much lower intensity activity took place. We present ten years of satellite-based measurements of SO2 in the atmosphere over Anatahan, using data from the UV spectrometers OMI, GOME-2, and SCIAMACHY, and the IR spectrometer AIRS. We find Anatahan's emissions to be highly variable both within and between intervals of eruption and quiescence. We demonstrate a close agreement between trends in SO2 emission evident from our remote sensing data and records of activity compiled from a range of other sources and instruments, across daily to annual temporal scales. Mean eruptive SO2 emissions at Anatahan are ~6400 t/d, and range from <1000 to >18000 t/d. Quiescent emissions are below our instrument detection limits and are therefore unlikely to exceed 150-300 t/d. Overall, accounting for both eruptive and quiescent emissions, we calculate a revised decadal mean SO2 emission rate of 1060-1200 t/d. We further calculate a total decadal SO2 yield from Anatahan of 4-5 Mt, significantly lower than the 17-34 Mt calculated if ground-based campaign data are used in isolation. The use of isolated measurements to extrapolate longer term emissions budgets is subject to clear uncertainty, and we argue that our satellite observations, covering a longer interval of Anatahan's history, are better suited to such calculations, and do not require widespread extrapolation. We propose that the use of multi-year satellite datasets, ideally in conjunction with key ground-based data and longterm records of activity, can make major improvements to existing emissions budgets at Anatahan and other volcanoes worldwide.

40 CFR 96.284 - Opt-in process.

Code of Federal Regulations, 2010 CFR

2010-07-01

... TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR SO2 Opt-in Units... of interim review, if the plan appears to contain information demonstrating that the SO2 emissions... section, the owner or operator shall monitor and report the SO2 emissions rate and the heat input of the...

Emission current control system for multiple hollow cathode devices

NASA Technical Reports Server (NTRS)

Beattie, John R. (Inventor); Hancock, Donald J. (Inventor)

1988-01-01

An emission current control system for balancing the individual emission currents from an array of hollow cathodes has current sensors for determining the current drawn by each cathode from a power supply. Each current sensor has an output signal which has a magnitude proportional to the current. The current sensor output signals are averaged, the average value so obtained being applied to a respective controller for controlling the flow of an ion source material through each cathode. Also applied to each controller are the respective sensor output signals for each cathode and a common reference signal. The flow of source material through each hollow cathode is thereby made proportional to the current drawn by that cathode, the average current drawn by all of the cathodes, and the reference signal. Thus, the emission current of each cathode is controlled such that each is made substantially equal to the emission current of each of the other cathodes. When utilized as a component of a multiple hollow cathode ion propulsion motor, the emission current control system of the invention provides for balancing the thrust of the motor about the thrust axis and also for preventing premature failure of a hollow cathode source due to operation above a maximum rated emission current.

Remote measurement of high preeruptive water vapor emissions at Sabancaya volcano by passive differential optical absorption spectroscopy

USGS Publications Warehouse

Kern, Christoph; Masias, Pablo; Apaza, Fredy; Reath, Kevin; Platt, Ulrich

2017-01-01

Water (H2O) is by far the most abundant volcanic volatile species and plays a predominant role in driving volcanic eruptions. However, numerous difficulties associated with making accurate measurements of water vapor in volcanic plumes have limited their use as a diagnostic tool. Here we present the first detection of water vapor in a volcanic plume using passive visible-light differential optical absorption spectroscopy (DOAS). Ultraviolet and visible-light DOAS measurements were made on 21 May 2016 at Sabancaya Volcano, Peru. We find that Sabancaya's plume contained an exceptionally high relative water vapor abundance 6 months prior to its November 2016 eruption. Our measurements yielded average sulfur dioxide (SO2) emission rates of 800–900 t/d, H2O emission rates of around 250,000 t/d, and an H2O/SO2 molecular ratio of 1000 which is about an order of magnitude larger than typically found in high-temperature volcanic gases. We attribute the high water vapor emissions to a boiling-off of Sabancaya's hydrothermal system caused by intrusion of magma to shallow depths. This hypothesis is supported by a significant increase in the thermal output of the volcanic edifice detected in infrared satellite imagery leading up to and after our measurements. Though the measurement conditions encountered at Sabancaya were very favorable for our experiment, we show that visible-light DOAS systems could be used to measure water vapor emissions at numerous other high-elevation volcanoes. Such measurements would provide observatories with additional information particularly useful for forecasting eruptions at volcanoes harboring significant hydrothermal systems.

Source identification of particulate matter in a semi-urban area of Malaysia using multivariate techniques.

PubMed

Wahid, N B A; Latif, M T; Suan, L S; Dominick, D; Sahani, M; Jaafar, S A; Mohd Tahir, N

2014-03-01

This study aims to determine the composition and sources of particulate matter with an aerodynamic diameter of 10 μm or less (PM10) in a semi-urban area. PM10 samples were collected using a high volume sampler. Heavy metals (Fe, Zn, Pb, Mn, Cu, Cd and Ni) and cations (Na(+), K(+), Ca(2+) and Mg(2+)) were detected using inductively coupled plasma mass spectrometry, while anions (SO4 (2-), NO3 (-), Cl(-) and F(-)) were analysed using Ion Chromatography. Principle component analysis and multiple linear regressions were used to identify the source apportionment of PM10. Results showed the average concentration of PM10 was 29.5 ± 5.1 μg/m(3). The heavy metals found were dominated by Fe, followed by Zn, Pb, Cu, Mn, Cd and Ni. Na(+) was the dominant cation, followed by Ca(2+), K(+) and Mg(2+), whereas SO4 (2-) was the dominant anion, followed by NO3 (-), Cl(-) and F(-). The main sources of PM10 were the Earth's crust/road dust, followed by vehicle emissions, industrial emissions/road activity, and construction/biomass burning.

A 10-year spatial and temporal trend of sulfate across the United States

NASA Astrophysics Data System (ADS)

Malm, William C.; Schichtel, Bret A.; Ames, Rodger B.; Gebhart, Kristi A.

2002-11-01

Legislative and regulatory mandates have resulted in reduced sulfur dioxide (SO2) emissions in both the eastern and western United States with anticipation that concurrent levels of ambient SO2, SO42-, and rainwater acidity would decrease. This paper examines spatial and temporal trends in ambient SO42- concentration from 1988 to 1999, SO2 emissions from 1990 to 1999, and the relationship between these two variables. The SO42- concentration data came from combining data from the Interagency Monitoring of Protected Visual Environments (IMPROVE) and the Clean Air Status and Trends Network (CASTNet). Over 70 sites spread across the continental United States are considered in this analysis. From a spatial perspective, the 90th percentile summer sulfate concentrations are highest along the Ohio River Valley and in central Tennessee where the emission density of SO2 is greatest. These concentrations are a factor of 2 greater than the Northeast, northern Michigan, and coastal areas of the Southeast and about a factor of 15 greater than the central western United States. In the East, the largest SO42- decreases in the 80th percentile concentrations occurred north of the Ohio River Valley, while most monitoring sites south of Kentucky and Virginia showed increasing and decreasing trends that were not statistically significant. Big Bend National Park, Texas, Cranberry, North Carolina, and Lassen Volcanic National Park, California, are the only areas that show a statistically significant increase in SO42- mass concentrations. The 1990-1999 annual 80th percentile SO42- time series were compared to the annual SO2 emissions over four broad United States regions. Each region had a unique time series pattern with the SO42- concentrations and SO2 emissions closely tracking each other over the 10-year period. Both the SO42- and SO2 emissions decreased in the Northeast (28%) and the West (15%), while there was little change in the Southeast and a 15% increase over Texas, New Mexico, and Colorado.

High resolution inventory of re-estimating ammonia emissions from agricultural fertilizer in China from 1978 to 2008

NASA Astrophysics Data System (ADS)

Xu, P.; Lin, Y. H.; Liao, Y. J.; Zhao, C. X.; Wang, G. S.; Luan, S. J.

2015-09-01

The quantification of ammonia (NH3) emissions is essential to the more accurate quantification of atmospheric nitrogen deposition, improved air quality and the assessment of ammonia-related agricultural policy and climate mitigation strategies. The quantity, geographic distribution and historical trends of these emissions remain largely uncertain. In this paper, a new Chinese agricultural fertilizer NH3 (CAF_NH3) emissions inventory has been compiled that exhibits the following improvements: (1) a 1 km × 1 km gridded map on the county level was developed for 2008, (2) a combined bottom-up and top-down method was used for the local correction of emission factors (EFs) and parameters, (3) the spatial and temporal patterns of historical time trends for 1978-2008 were estimated and the uncertainties were quantified for the inventories, and (4) a sensitivity test was performed in which a province-level disaggregated map was compared with CAF_NH3 emissions for 2008. The total CAF_NH3 emissions for 2008 were 8.4 Tg NH3 yr-1 (a 6.6-9.8 Tg interquartile range). From 1978 to 2008, annual NH3 emissions fluctuated with three peaks (1987, 1996 and 2005), and total emissions increased from 3.2 to 8.4 Tg at an annual rate of 3.0 %. During the study period, the contribution of livestock manure spreading increased from 37.0 to 45.5 % because of changing fertilization practices and the rapid increase in egg, milk and meat consumption. The average contribution of synthetic fertilizer, which has a positive effect on crop yields, was approximately 38.3 % (minimum: 33.4 %; maximum: 42.7 %). With rapid urbanization causing a decline in the rural population, the contribution of the rural excrement sector varied widely between 20.3 and 8.5 %. The average contributions of cake fertilizer and straw returning were approximately 3.8 and 4.5 %, respectively, thus small and stable. Collectively, the CAF_NH3 emissions reflect the nation's agricultural policy to a certain extent. An effective approach to decreasing PM2.5 concentrations in China would be to simultaneously decrease NOx, SO2 and NH3 emissions.

High-resolution inventory of ammonia emissions from agricultural fertilizer in China from 1978 to 2008

NASA Astrophysics Data System (ADS)

Xu, P.; Liao, Y. J.; Lin, Y. H.; Zhao, C. X.; Yan, C. H.; Cao, M. N.; Wang, G. S.; Luan, S. J.

2016-02-01

The quantification of ammonia (NH3) emissions is essential to the more accurate quantification of atmospheric nitrogen deposition, improved air quality and the assessment of ammonia-related agricultural policy and climate mitigation strategies. The quantity, geographic distribution and historical trends of these emissions remain largely uncertain. In this paper, a new Chinese agricultural fertilizer NH3 (CAF_NH3) emissions inventory has been compiled that exhibits the following improvements: (1) a 1 × 1 km gridded map on the county level was developed for 2008; (2) a combined bottom-up and top-down method was used for the local correction of emission factors (EFs) and parameters; (3) the temporal patterns of historical time trends for 1978-2008 were estimated and the uncertainties were quantified for the inventories; and (4) a sensitivity test was performed in which a province-level disaggregated map was compared with CAF_NH3 emissions for 2008. The total CAF_NH3 emissions for 2008 were 8.4 TgNH3 yr-1 (a 6.6-9.8 Tg interquartile range). From 1978 to 2008, annual NH3 emissions fluctuated with three peaks (1987, 1996 and 2005), and total emissions increased from 3.2 to 8.4 Tg at an annual rate of 3.0 %. During the study period, the contribution of livestock manure spreading increased from 37.0 to 45.5 % because of changing fertilization practices and the rapid increase in egg, milk, and meat consumption. The average contribution of synthetic fertilizer, which has a positive effect on crop yields, was approximately 38.3 % (minimum: 33.4 %; maximum: 42.7 %). With rapid urbanization causing a decline in the rural population, the contribution of the rural excrement sector varied widely between 20.3 % and 8.5 %. The average contributions of cake fertilizer and straw returning were approximately 3.8 and 4.5 %, respectively, thus small and stable. Collectively, the CAF_NH3 emissions reflect the nation's agricultural policy to a certain extent. An effective approach to decreasing PM2.5 concentrations in China would be to simultaneously decrease NOx, SO2, and NH3 emissions.

Houston’s rapid ozone increases: preconditions and geographic origins

PubMed Central

Couzo, Evan; Jeffries, Harvey E.; Vizuete, William

2013-01-01

Many of Houston’s highest 8-h ozone (O3) peaks are characterised by increases in concentrations of at least 40 ppb in 1 h, or 60 ppb in 2 h. These rapid increases are called non-typical O3 changes (NTOCs). In 2004, the Texas Commission on Environmental Quality (TCEQ) developed a novel emissions control strategy aimed at eliminating NTOCs. The strategy limited routine and short-term emissions of ethene, propene, 1,3-butadiene and butene isomers, collectively called highly reactive volatile organic compounds (HRVOCs), which are released from petrochemical facilities. HRVOCs have been associated with NTOCs through field campaigns and modelling studies. This study analysed wind measurements and O3, formaldehyde (HCHO) and sulfur dioxide (SO2) concentrations from 2000 to 2011 at 25 ground monitors in Houston. NTOCs almost always occurred when monitors were downwind of petrochemical facilities. Rapid O3 increases were associated with low wind speeds; 75 % of NTOCs occurred when the 3-h average wind speed preceding the event was less than 6.5 km h−1. Statistically significant differences in HCHO concentrations were seen between days with and without NTOCs. Early afternoon HCHO concentrations were greater on NTOC days. In the morning before an observed NTOC event, however, there were no significant differences in HCHO concentrations between days with and without NTOCs. Hourly SO2 concentrations also increased rapidly, exhibiting behaviour similar to NTOCs. Oftentimes, the SO2 increases preceded a NTOC. These findings show that, despite the apparent success of targeted HRVOC emission controls, further restrictions may be needed to eliminate the remaining O3 events. PMID:24014080

A pilot study of gaseous pollutants' measurement (NO2, SO2, NH3, HNO3 and O3) in Abidjan, Côte d'Ivoire: contribution to an overview of gaseous pollution in African cities

NASA Astrophysics Data System (ADS)

Bahino, Julien; Yoboué, Véronique; Galy-Lacaux, Corinne; Adon, Marcellin; Akpo, Aristide; Keita, Sékou; Liousse, Cathy; Gardrat, Eric; Chiron, Christelle; Ossohou, Money; Gnamien, Sylvain; Djossou, Julien

2018-04-01

This work is part of the DACCIWA FP7 project (Dynamics-Aerosol-Chemistry-Cloud Interactions in West Africa) in the framework of the Work Package 2 Air Pollution and Health. This study aims to characterize urban air pollution levels through the measurement of NO2, SO2, NH3, HNO3 and O3 in Abidjan, the economic capital of Côte d'Ivoire. Measurements of inorganic gaseous pollutants, i.e. NO2, SO2, NH3, HNO3 and O3 were performed in Abidjan during an intensive campaign within the dry season (15 December 2015 to 16 February 2016), using INDAAF (International Network to study Deposition and Atmospheric chemistry in AFrica) passive samplers exposed in duplicate for 2-week periods. Twenty-one sites were selected in the district of Abidjan to be representative of various anthropogenic and natural sources of air pollution in the city. Results from this intensive campaign show that gas concentrations are strongly linked to surrounding pollution sources and show a high spatial variability. Also, NH3, NO2 and O3 gases were present at relatively higher concentrations at all the sites. NH3 average concentrations varied between 9.1 ± 1.7 ppb at a suburban site and 102.1 ± 9.1 ppb at a domestic fires site. NO2 mean concentration varied from 2.7 ± 0.1 ppb at a suburban site to 25.0 ± 1.7 ppb at an industrial site. Moreover, we measured the highest O3 concentration at the two coastal sites of Gonzagueville and Félix-Houphouët-Boigny International Airport located in the southeast of the city, with average concentrations of 19.1 ± 1.7 and 18.8 ± 3.0 ppb, respectively. The SO2 average concentration never exceeded 7.2 ± 1.2 ppb over all the sites, with 71.5 % of the sampling sites showing concentrations ranging between 0.4 and 1.9 ppb. The HNO3 average concentration ranged between 0.2 and 1.4 ppb. All these results were combined with meteorological parameters to provide the first mapping of gaseous pollutants on the scale of the district of Abidjan using geostatistical analysis (ArcGIS software). Spatial distribution results emphasize the importance of the domestic fires source and the significant impact of the traffic emissions on the scale of the city. In addition, in this work we propose a first overview of gaseous SO2 and NO2 concentrations on the scale of several African cities by comparing literature to our values. The daily SO2 standard of World Health Organization (WHO) is exceeded in most of the cities reported in the overview, with concentrations ranging from 0.2 to 3662 µg m-3. Annual NO2 concentrations ranged from 2 to 175 µg m-3, which are lower than the WHO threshold. As a conclusion, this study constitutes an original database to characterize urban air pollution and a first attempt towards presenting a spatial distribution of the pollution levels at the scale of the metropolis of Abidjan. This work should draw the attention of the African public authorities to the necessity of building an air quality monitoring network in order to (1) to define national standards and to better control the pollutants emissions and (2) to investigate the impact on the health of the growing population in developing African countries.

Current state of traffic pollution in Bangladesh and metropolitan Dhaka

DOE Office of Scientific and Technical Information (OSTI.GOV)

Karim, Masud; Matsui, Hiroshi; Ohno, Takashi

1997-12-31

Limited resources, invested for the development of transport facilities, such as infrastructure and vehicles, coupled with the rapid rise in transport demand, existence of a huge number of non-motorized vehicles on roads, lack of application of adequate and proper traffic management schemes are producing severe transport problems in almost all the urban areas of Bangladesh. Worsening situation of traffic congestion in the streets and sufferings of the inhabitants from vehicle emissions demand extensive research in this field. However, no detailed study concerning traffic congestion and pollution problems for urban areas of Bangladesh has yet been done. Therefore, it has becomemore » increasingly important to examine the present state of the problem. This research is a preliminary evaluation of the current situation of traffic pollution problem in Bangladesh. The daily total emissions of NO{sub x}, HC, CO, PM, and SO{sub x} are estimated using the daily fuel consumption and total traffic flows in Dhaka city. Estimated daily emissions are 42, 39, 314, 14, and 42 t/d for NO{sub x}, HC, CO, PM, and SO{sub x}, respectively. The emissions estimated using two different methods revealed good correlation. Daily average concentration of NO{sub x} (NO{sub 2}, NO) were measured at 30 street locations in Dhaka city during September and November, 1996. The results showed extremely high concentrations of NO{sub 2} and NO in these locations.« less

Chemical characterization of extractable water soluble matter associated with PM10 from Mexico City during 2000.

PubMed

Gutiérrez-Castillo, M E; Olivos-Ortiz, M; De Vizcaya-Ruiz, A; Cebrián, M E

2005-11-01

We report the chemical composition of PM10-associated water-soluble species in Mexico City during the second semester of 2000. PM10 samples were collected at four ambient air quality monitoring sites in Mexico City. We determined soluble ions (chloride, nitrate, sulfate, ammonium, sodium, potassium), ionizable transition metals (Zn, Fe, Ti, Pb, Mn, V, Ni, Cr, Cu) and soluble protein. The higher PM(10) levels were observed in Xalostoc (45-174 microg m(-3)) and the lowest in Pedregal (19-54 microg m(-3)). The highest SO2 average concentrations were observed in Tlalnepantla, NO2 in Merced and O3 and NO(x) in Pedregal. The concentration range of soluble sulfate was 6.7-7.9 and 19-25.5 microg m(-3) for ammonium, and 14.8-29.19 for soluble V and 3.2-7.7 ng m(-3) for Ni, suggesting a higher contribution of combustion sources. PM-associated soluble protein levels varied between 0.038 and 0.169 mg m(-3), representing a readily inhalable constituent that could contribute to adverse outcomes. The higher levels for most parameters studied were observed during the cold dry season, particularly in December. A richer content of soluble metals was observed when they were expressed by mass/mass units rather than by air volume units. Significant correlations between Ni-V, Ni-SO4(-2), V-SO4(-2), V-SO2, Ni-SO2 suggest the same type of emission source. The variable soluble metal and ion concentrations were strongly influenced by the seasonal meteoclimatic conditions and the differential contribution of emission sources. Our data support the idea that PM10 mass concentration by itself does not provide a clear understanding of a local PM air pollution problem.

Effect of farming strategies on environmental impact of intensive dairy farms in Italy.

PubMed

Guerci, Matteo; Bava, Luciana; Zucali, Maddalena; Sandrucci, Anna; Penati, Chiara; Tamburini, Alberto

2013-08-01

Agriculture and animal husbandry are important contributors to global emissions of greenhouse (GHG) and acidifying gases. Moreover, they contribute to water pollution and to consumption of non-renewable natural resources such as land and energy. The Life Cycle Assessment (LCA) methodology allows evaluation of the environmental impact of a process from the production of inputs to the final product and to assess simultaneously several environmental impact categories among which GHG emissions, acidification, eutrophication, land use and energy use. The main purpose of this study was to evaluate, using the LCA methodology, the environmental impact of milk production in a sample of 41 intensive Italian dairy farms and to identify, among different farming strategies, those associated with the best environmental performances. The functional unit was 1 kg Fat and Protein Corrected Milk (FPCM). Farms showed characteristics of high production intensity: FPCM, expressed as tonnes per hectare, was 30·8±15·1. Total GHG emission per kg FPCM at farm gate was 1·30±0·19 kg CO2 eq. The main contributors to climate change potential were emissions from barns and manure storage (50·1%) and emissions for production and transportation of purchased feeds (21·2%). Average emission of gases causing acidification to produce 1 kg FPCM was 19·7±3·6 g of SO2 eq. Eutrophication potential was 9·01±1·78 ${\\rm PO}_{\\rm 4}^{{\\rm 3} -} {\\rm eq}.$ per kg FPCM on average. Farms from this study needed on average 5·97±1·32 MJ per kg FPCM from non-renewable energy sources. Energy consumption was mainly due to off-farm activities (58%) associated with purchased factors. Land use was 1·51±0·25 m2 per kg FPCM. The farming strategy based on high conversion efficiency at animal level was identified as the most effective to mitigate the environmental impact per kg milk at farm gate, especially in terms of GHG production and non-renewable energy use per kg FPCM.

Measurements of nitrous oxide emissions from P.F. fired power stations

NASA Astrophysics Data System (ADS)

Sloan, S. A.; Laird, C. K.

Nitrous oxide (N 2O) was measured in the flue gas from four wall-fired and three corner-fired 500 MW boilers, fitted with either conventional or low-NO x burners, at four C.E.G.B. power stations. Measurements were made both by on-line non-dispersive infra red (NDIR) monitors and by extractive sampling for later laboratory analysis by electron capture gas chromatography (ECD GC). It was found that the on-line and laboratory methods were in good agreement for samples analyzed within 1-3 h of sampling, but that the nitrous oxide concentration in the stored samples had a tendency to increase with time, which was dependent on the concentration of water in the sample. Experiments with synthetic mixtures showed that the increase in nitrous oxide concentration was consistent with the overall reaction2NO+SO 2→N 2O+SO 3 in which nitric oxide is reduced by sulphur dioxide. The highest average N 2O concentration measured by the on-line analyzer was 16 vpm, and for most of the boilers monitored the concentration was less than 10 vpm. There was no statistically significant difference between the measured N 2O emissions from normal boilers and those fitted with low-NO x burners. It is suggested that these values are close to the true levels of N 2O emissions from p.f. fired boilers and that recent reports of high levels (up to 200 vpm) are likely to be an artefact resulting from the observed generation of N 2O in stored samples. A consequence of these measurements of N 2O is that current estimates of the contribution of emissions from p.f. fired boilers to the global N 2O budget are likely to be too high.

Evaluation of gas well setback policy in the Marcellus Shale region of Pennsylvania in relation to emissions of fine particulate matter.

PubMed

Banan, Zoya; Gernand, Jeremy M

2018-04-18

Shale gas has become an important strategic energy source with considerable potential economic benefits and the potential to reduce greenhouse gas emissions in so far as it displaces coal use. However, there still exist environmental health risks caused by emissions from exploration and production activities. In the United States, states and localities have set different minimum setback policies to reduce the health risks corresponding to the emissions from these locations, but it is unclear whether these policies are sufficient. This study uses a Gaussian plume model to evaluate the probability of exposure exceedance from EPA concentration limits for PM2.5 at various locations around a generic wellsite in the Marcellus shale region. A set of meteorological data monitored at ten different stations across Marcellus shale gas region in Pennsylvania during 2015 serves as an input to this model. Results indicate that even though the current setback distance policy in Pennsylvania (500 ft. or 152.4 m) might be effective in some cases, exposure limit exceedance occurs frequently at this distance with higher than average emission rates and/or greater number of wells per wellpad. Setback distances should be 736 m to ensure compliance with the daily average concentration of PM2.5, and a function of the number of wells to comply with the annual average PM2.5 exposure standard. The Marcellus Shale gas is known as a significant source of criteria pollutants and studies show that the current setback distance in Pennsylvania is not adequate to protect the residents from exceeding the established limits. Even an effective setback distance to meet the annual exposure limit may not be adequate to meet the daily limit. The probability of exceeding the annual limit increases with number of wells per site. We use a probabilistic dispersion model to introduce a technical basis to select appropriate setback distances.

40 CFR 97.284 - Opt-in process.

Code of Federal Regulations, 2010 CFR

2010-07-01

... BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS CAIR SO2 Opt-in Units § 97.284 Opt-in... demonstrating that the SO2 emissions rate and heat input of the unit and all other applicable parameters are... under paragraph (a) of this section, the owner or operator shall monitor and report the SO2 emissions...

Impacts of the Minamata Convention for Mercury Emissions from Coal-fired Power Generation in Asia

NASA Astrophysics Data System (ADS)

Giang, A.; Stokes, L. C.; Streets, D. G.; Corbitt, E. S.; Selin, N. E.

2014-12-01

We explore the potential implications of the recently signed United Nations Minamata Convention on Mercury for emissions from coal-fired power generation in Asia, and the impacts of these emissions changes on deposition of mercury worldwide by 2050. We use qualitative interviews, document analysis, and engineering analysis to create plausible technology scenarios consistent with the Convention, taking into account both technological and political factors. We translate these scenarios into possible emissions inventories for 2050, based on IPCC development scenarios, and then use the GEOS-Chem global transport model to evaluate the effect of these different technology choices on mercury deposition over geographic regions and oceans. We find that China is most likely to address mercury control through co-benefits from technologies for SO2, NOx, and particulate matter (PM) capture that will be required to attain its existing air quality goals. In contrast, India is likely to focus on improvements to plant efficiency such as upgrading boilers, and coal washing. Compared to current technologies, we project that these changes will result in emissions decreases of approximately 140 and 190 Mg/yr for China and India respectively in 2050, under an A1B development scenario. With these emissions reductions, simulated average gross deposition over India and China are reduced by approximately 10 and 3 μg/m2/yr respectively, and the global average concentration of total gaseous mercury (TGM) is reduced by approximately 10% in the Northern hemisphere. Stricter, but technologically feasible, requirements for mercury control in both countries could lead to an additional 200 Mg/yr of emissions reductions. Modeled differences in concentration and deposition patterns between technology suites are due to differences in both the mercury removal efficiency of technologies and their resulting stack speciation.

COMPARISON OF HISTORIC SO2 AND NOX EMISSION DATA SETS

EPA Science Inventory

The report gives results of a comparison of historic SO2 and NOx emission data sets. During the past few years, several research projects have been conducted to reconstruct historic air pollution emission trends in the U.S. The report compares in detail the emission estimates and...

An evaluation of ambient sulphur dioxide concentrations from passive degassing of the Sulphur Springs, Saint Lucia geothermal system: Implications for human health

NASA Astrophysics Data System (ADS)

Joseph, Erouscilla P.; Beckles, Denise M.; Cox, Leonette; Jackson, Viveka B.; Alexander, Dominic

2015-10-01

Sulphur Springs Park in Saint Lucia is a site of energetic geothermal activity associated with the potentially active Soufrière Volcanic Centre. The Park is one of Saint Lucia's most important tourist attractions, and is marketed as the 'world's only drive-in volcano'. It has an on-site staff of tour guides and vendors, as well as over 200,000 visitors annually. There are also a number of residents living in the areas bordering the Park. Recreational use is made of the geothermal waters for bathing, application of mud masques, and in some cases drinking. As part of the University of the West Indies, Seismic Research Centre's (UWI-SRC's) overall volcano monitoring programme for Saint Lucia, the volcanic emissions at Sulphur Springs (hot springs, mud pools and fumaroles) have been regularly monitored since 2001. In recent years, visitors, staff, and management at the Park have expressed concern about the health effects of exposure to volcanic emissions from the hydrothermal system. In response to this, SRC has expanded its regular geothermal monitoring programme to include a preliminary evaluation of ambient sulphur dioxide (SO2) concentrations in and around the Park, to assess the possible implications for human health. Passive diffusion tubes were used to measure the atmospheric SO2 concentrations at various sites in Sulphur Springs Park (SSP), in the town of Soufrière and in the capital of Castries. Measurements of average monthly ambient SO2 with the passive samplers indicated that during the dry season period of April to July 2014 concentration at sites closest to the main vents at SSP (Group 1), which are routinely used by staff and visitors, frequently exceeded the WHO 10-minute AQG for SO2 of 500 μg/m3. However, for sites that were more distal to the main venting area (Groups 2 and 3), the average monthly ambient SO2 did not exceed the WHO 10-minute AQG for SO2 of 500 μg/m3 during the entire monitoring period. The measured concentrations and dispersion patterns of ambient SO2 at SSP appear to be influenced by rainfall, proximity to the fumarolic vents, altitude (local topography), local atmospheric circulation and plume dispersion, and anthropogenic sources. Brochures and posters were prepared, for public distribution and display, on possible gas hazards that may be encountered at SSP and precautionary measures that may be taken by visitors to help minimise potential risk from elevated exposure to volcanic gases.

40 CFR 75.5 - Prohibitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

.... (c) No owner or operator of an affected unit shall use any alternative monitoring system, alternative... be discharged, emissions of SO2, NOX or CO2 to the atmosphere without accounting for all such... approved emission monitoring method, and thereby avoid monitoring and recording SO2, NOX, or CO2 emissions...

Global Scenarios of Air Pollutant Emissions from Road Transport through to 2050

PubMed Central

Takeshita, Takayuki

2011-01-01

This paper presents global scenarios of sulphur dioxide (SO2), nitrogen oxides (NOx), and particulate matter (PM) emissions from road transport through to 2050, taking into account the potential impacts of: (1) the timing of air pollutant emission regulation implementation in developing countries; (2) global CO2 mitigation policy implementation; and (3) vehicle cost assumptions, on study results. This is done by using a global energy system model treating the transport sector in detail. The major conclusions are the following. First, as long as non-developed countries adopt the same vehicle emission standards as in developed countries within a 30-year lag, global emissions of SO2, NOx, and PM from road vehicles decrease substantially over time. Second, light-duty vehicles and heavy-duty trucks make a large and increasing contribution to future global emissions of SO2, NOx, and PM from road vehicles. Third, the timing of air pollutant emission regulation implementation in developing countries has a large impact on future global emissions of SO2, NOx, and PM from road vehicles, whereas there is a possibility that global CO2 mitigation policy implementation has a comparatively small impact on them. PMID:21845172

CO2, SO2, and H2S Degassing Related to the 2009 Redoubt Eruption, Alaska

NASA Astrophysics Data System (ADS)

Werner, C. A.; Kelly, P. J.; Evans, W.; Doukas, M. P.; McGimsey, R. G.; Neal, C. A.

2012-12-01

The 2009 eruption of Redoubt Volcano, Alaska was particularly well monitored for volcanic gas emissions with 35 airborne measurements of CO2, SO2, and H2S that span from October 2008 to August 2010. Increases in CO2 degassing were detected up to 5 months prior to the eruption and varied between 3630 and 9020 tonnes per day (t/d) in the 6 weeks prior to the eruption. Increased pre-eruptive CO2 degassing was accompanied by comparatively low S emission, resulting in molar C/S ratios that ranged between 30-60. However, the C/S ratio dropped to 2.4 coincident with the first phreatic explosion on March 15, 2009, and remained steady during the explosive (March 22 - April 4, 2009), effusive dome-building (April 5 - July 1, 2009), and waning phases (August 2009 onward) of the eruption. Observations of ice-melt rates, melt water discharge, and water chemistry in the months leading up to the eruption suggested that surface waters represented drainage from surficial, perched reservoirs of condensed magmatic steam and glacial meltwater. While the surface waters were capable of scrubbing many thousands of t/d of SO2, sampling of these fluids revealed that only a few hundred tonnes of SO2 was reacting to a dissolved component each day. This is also much less than the ~ 2100 t/d SO2 expected from degassing of magma in the upper crust (3-6.5 km), where petrologic analysis shows the final magma equilibration occurred. Thus, the high pre-eruptive C/S ratios observed could reflect bulk degassing of upper-crustal magma followed by nearly complete loss of SO2 in a magmatic-hydrothermal system. Alternatively, high C/S ratios could be attributed to degassing of low silica andesitic magma that intruded into the mid-crust in the 5 months prior to eruption; modeling suggests that mixing of this magma with pre-existing high silica andesite magma or mush would have caused a reduction of the C/S ratio to a value consistent with that measured during the eruption. Monitoring emissions regularly throughout the eruptive phases showed that the magmatic system degassed primarily as a closed system with approximately 59 and 66 % of the total CO2 and SO2, respectively, emitted during the explosive and dome growth periods. Maximum emission rates measured with airborne techniques were 33,110 t/d CO2, 16,650 t/d SO2, and 1230 t/d H2S. Pre-eruptive open system degassing accounted for only 14% of the total CO2 and 4% of total SO2, whereas post-eruptive passive degassing was responsible for 27 and 30 % of the total CO2 and SO2 with measurements extending over one year following the cessation of dome extrusion. SO2 made up on average 92% of the total sulfur degassing throughout the eruption. Primary volatile contents calculated from degassing and erupted magma volumes range from 0.9-2.1 wt. % CO2 and 0.27 - 0.56 wt. % S. Similar trends between volumes of estimated degassed magma and observed erupted magma during the eruptive period point to primary volatile contents of 1.25 wt. % CO2 and 0.35 wt. % S. Assuming these values, up to 30% additional unerupted magma degassed in the year following final dome emplacement.

Reaction behavior of SO2 in the sintering process with flue gas recirculation.

PubMed

Yu, Zhi-Yuan; Fan, Xiao-Hui; Gan, Min; Chen, Xu-Ling; Chen, Qiang; Huang, Yun-Song

2016-07-01

The primary goal of this paper is to reveal the reaction behavior of SO2 in the sinter zone, combustion zone, drying-preheating zone, and over-wet zone during flue gas recirculation (FGR) technique. The results showed that SO2 retention in the sinter zone was associated with free-CaO in the form of CaSO3/CaSO4, and the SO2 adsorption reached a maximum under 900ºC. SO2 in the flue gas came almost from the combustion zone. One reaction behavior was the oxidation of sulfur in the sintering mix when the temperature was between 800 and 1000ºC; the other behavior was the decomposition of sulfite/sulfate when the temperature was over 1000ºC. However, the SO2 adsorption in the sintering bed mainly occurred in the drying-preheating zone, adsorbed by CaCO3, Ca(OH)2, and CaO. When the SO2 adsorption reaction in the drying-preheating zone reached equilibrium, the excess SO2 gas continued to migrate to the over-wet zone and was then absorbed by Ca(OH)2 and H2O. The emission rising point of SO2 moved forward in combustion zone, and the concentration of SO2 emissions significantly increased in the case of flue gas recirculation (FGR) technique. Aiming for the reuse of the sensible heat and a reduction in exhaust gas emission, the FGR technique is proposed in the iron ore sintering process. When using the FGR technique, SO2 emission in exhaust gas gets changed. In practice, the application of the FGR technique in a sinter plant should be cooperative with the flue gas desulfurization (FGD) technique. Thus, it is necessary to study the influence of the FGR technique on SO2 emissions because it will directly influence the demand and design of the FGD system.

Methane emissions partially offset “blue carbon” burial in mangroves

PubMed Central

Maher, Damien T.

2018-01-01

Organic matter burial in mangrove forests results in the removal and long-term storage of atmospheric CO2, so-called “blue carbon.” However, some of this organic matter is metabolized and returned to the atmosphere as CH4. Because CH4 has a higher global warming potential than the CO2 fixed in the organic matter, it can offset the CO2 removed via carbon burial. We provide the first estimate of the global magnitude of this offset. Our results show that high CH4 evasion rates have the potential to partially offset blue carbon burial rates in mangrove sediments on average by 20% (sensitivity analysis offset range, 18 to 22%) using the 20-year global warming potential. Hence, mangrove sediment and water CH4 emissions should be accounted for in future blue carbon assessments.

Aerosol composition, chemistry, and source characterization during the 2008 VOCALS Experiment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Y.; Springston, S.; Jayne, J.

2010-03-15

Chemical composition of fine aerosol particles over the northern Chilean coastal waters was determined onboard the U.S. DOE G-1 aircraft during the VOCALS (VAMOS Ocean-Cloud-Atmosphere-Land Study) field campaign between October 16 and November 15, 2008. SO42-, NO3-, NH4+, and total organics (Org) were determined using an Aerodyne Aerosol Mass Spectrometer, and SO42-, NO3-, NH4+, Na+, Cl-, CH3SO3-, Mg2+, Ca2+, and K+ were determined using a particle-into-liquid sampler-ion chromatography technique. The results show the marine boundary layer (MBL) aerosol mass was dominated by non- sea-salt SO42- followed by Na+, Cl-, Org, NO3-, and NH4+, in decreasing importance; CH3SO3-, Ca2+, and K+more » rarely exceeded their respective limits of detection. The SO42- aerosols were strongly acidic as the equivalent NH4+ to SO42- ratio was only {approx}0.25 on average. NaCl particles, presumably of sea-salt origin, showed chloride deficits but retained Cl- typically more than half the equivalency of Na+, and are externally mixed with the acidic sulfate aerosols. Nitrate was observed only on sea-salt particles, consistent with adsorption of HNO3 on sea-salt aerosols, responsible for the Cl- deficit. Dust particles appeared to play a minor role, judging from the small volume differences between that derived from the observed mass concentrations and that calculated based on particle size distributions. Because SO42- concentrations were substantial ({approx}0.5 - {approx}3 {micro}g/m3) with a strong gradient (highest near the shore), and the ocean-emitted dimethylsulfide and its unique oxidation product, CH3SO3-, were very low (i.e., {le} 40 parts per trillion and <0.05 {micro}g/m3, respectively), the observed SO42- aerosols are believed to be primarily of terrestrial origin. Back trajectory calculations indicate sulfur emissions from smelters and power plants along coastal regions of Peru and Chile are the main sources of these SO4- aerosols. However, compared to observations, model calculations appeared to underestimate sulfate concentrations based on an existing emission inventory. The agreement between observations and model predictions of CO as well as total sulfur is reexamined in this work with a new emission inventory made available recently.« less

40 CFR 75.16 - Special provisions for monitoring emissions from common, bypass, and multiple stacks for SO2...

Code of Federal Regulations, 2010 CFR

2010-07-01

... maintain an SO2 continuous emission monitoring system and flow monitoring system in the duct to the common... emission monitoring system and flow monitoring system in the common stack and combine emissions for the... continuous emission monitoring system and flow monitoring system in the duct to the common stack from each...

Source apportionment of PM(2.5) in the harbour-industrial area of Brindisi (Italy): identification and estimation of the contribution of in-port ship emissions.

PubMed

Cesari, D; Genga, A; Ielpo, P; Siciliano, M; Mascolo, G; Grasso, F M; Contini, D

2014-11-01

Harbours are important for economic and social development of coastal areas but they also represent an anthropogenic source of emissions often located near urban centres and industrial areas. This increases the difficulties in distinguishing the harbour contribution with respect to other sources. The aim of this work is the characterisation of main sources of PM2.5 acting on the Brindisi harbour-industrial area, trying to pinpoint the contribution of in-port ship emissions to primary and secondary PM2.5. Brindisi is an important port-city of the Adriatic Sea considered a hot-spot for anthropogenic environmental pressures at National level. Measurements were performed collecting PM2.5 samples and characterising the concentrations of 23 chemical species (water soluble organic and inorganic carbon; major ions: SO4(2-), NO3(-), NH4(+), Cl(-), C2O4(2-), Na(+), K(+), Mg(2+), Ca(2+); and elements: Ni, Cu, V, Mn, As, Pb, Cr, Sb, Fe, Al, Zn, and Ti). These species represent, on average, 51.4% of PM2.5 and were used for source apportionment via PMF. The contributions of eight sources were estimated: crustal (16.4±0.9% of PM2.5), aged marine (2.6±0.5%), crustal carbonates (7.7±0.3%), ammonium sulphate (27.3±0.8%), biomass burning-fires (11.7±0.7%), traffic (16.4±1.7 %), industrial (0.4±0.3%) and a mixed source oil combustion-industrial including ship emissions in harbour (15.3±1.3%). The PMF did not separate the in-port ship emission contribution from industrial releases. The correlation of estimated contribution with meteorology showed directionality with an increase of oil combustion and sulphate contribution in the harbour direction with respect to the direction of the urban area and an increase of the V/Ni ratio. This allowed for the use of V as marker of primary ship contribution to PM2.5 (2.8%+/-1.1%). The secondary contribution of oil combustion to non-sea-salt-sulphate, nssSO4(2-), was estimated to be 1.3 μg/m(3) (about 40% of total nssSO4(2-) or 11% of PM2.5). Copyright © 2014 Elsevier B.V. All rights reserved.

Evaluation of Externality Costs in Life-Cycle Optimization of Municipal Solid Waste Management Systems.

PubMed

Martinez-Sanchez, Veronica; Levis, James W; Damgaard, Anders; DeCarolis, Joseph F; Barlaz, Morton A; Astrup, Thomas F

2017-03-21

The development of sustainable solid waste management (SWM) systems requires consideration of both economic and environmental impacts. Societal life-cycle costing (S-LCC) provides a quantitative framework to estimate both economic and environmental impacts, by including "budget costs" and "externality costs". Budget costs include market goods and services (economic impact), whereas externality costs include effects outside the economic system (e.g., environmental impact). This study demonstrates the applicability of S-LCC to SWM life-cycle optimization through a case study based on an average suburban U.S. county of 500 000 people generating 320 000 Mg of waste annually. Estimated externality costs are based on emissions of CO 2 , CH 4 , N 2 O, PM 2.5 , PM 10 , NO x , SO 2 , VOC, CO, NH 3 , Hg, Pb, Cd, Cr (VI), Ni, As, and dioxins. The results indicate that incorporating S-LCC into optimized SWM strategy development encourages the use of a mixed waste material recovery facility with residues going to incineration, and separated organics to anaerobic digestion. Results are sensitive to waste composition, energy mix and recycling rates. Most of the externality costs stem from SO 2 , NO x , PM 2.5 , CH 4 , fossil CO 2 , and NH 3 emissions. S-LCC proved to be a valuable tool for policy analysis, but additional data on key externality costs such as organic compounds emissions to water would improve future analyses.

Agriculture-driven deforestation in the tropics from 1990-2015: emissions, trends and uncertainties

NASA Astrophysics Data System (ADS)

Carter, Sarah; Herold, Martin; Avitabile, Valerio; de Bruin, Sytze; De Sy, Veronique; Kooistra, Lammert; Rufino, Mariana C.

2018-01-01

Limited data exists on emissions from agriculture-driven deforestation, and available data are typically uncertain. In this paper, we provide comparable estimates of emissions from both all deforestation and agriculture-driven deforestation, with uncertainties for 91 countries across the tropics between 1990 and 2015. Uncertainties associated with input datasets (activity data and emissions factors) were used to combine the datasets, where most certain datasets contribute the most. This method utilizes all the input data, while minimizing the uncertainty of the emissions estimate. The uncertainty of input datasets was influenced by the quality of the data, the sample size (for sample-based datasets), and the extent to which the timeframe of the data matches the period of interest. Area of deforestation, and the agriculture-driver factor (extent to which agriculture drives deforestation), were the most uncertain components of the emissions estimates, thus improvement in the uncertainties related to these estimates will provide the greatest reductions in uncertainties of emissions estimates. Over the period of the study, Latin America had the highest proportion of deforestation driven by agriculture (78%), and Africa had the lowest (62%). Latin America had the highest emissions from agriculture-driven deforestation, and these peaked at 974 ± 148 Mt CO2 yr-1 in 2000-2005. Africa saw a continuous increase in emissions between 1990 and 2015 (from 154 ± 21-412 ± 75 Mt CO2 yr-1), so mitigation initiatives could be prioritized there. Uncertainties for emissions from agriculture-driven deforestation are ± 62.4% (average over 1990-2015), and uncertainties were highest in Asia and lowest in Latin America. Uncertainty information is crucial for transparency when reporting, and gives credibility to related mitigation initiatives. We demonstrate that uncertainty data can also be useful when combining multiple open datasets, so we recommend new data providers to include this information.

Effect of Alum Additions to Poultry Litter on In-House Ammonia and Greenhouse Gas Concentrations and Emissions.

PubMed

Eugene, Branly; Moore, Philip A; Li, Hong; Miles, Dana; Trabue, Steven; Burns, Robert; Buser, Michael

2015-09-01

Alum [Al(SO4) ·14HO] addition to poultry litter has been shown to reduce ammonia (NH) concentrations in poultry houses; however, its effects on greenhouse gas (GHG; NO, CH, and CO) emissions is unknown. The objectives of this study were to determine the effects of alum additions on (i) in-house NH and GHG concentrations, (ii) NH and GHG emissions, and (iii) litter chemical properties. Two identical broiler houses located in northwest Arkansas were used for this study: one house was a control and the other was treated with alum between each flock of birds. Ventilation rates were coupled with in-house NH and GHG measurements to determine emission rates. Overall, alum additions significantly reduced the daily average in-house NH concentration by 42% (8.9 vs. 15.4 μL L), and the overall NH emission rate was reduced by 47% (7.2 vs. 13.4 kg d house). The average cumulative NH emission for the three flocks was 330 kg house flock for the alum-treated house and 617 kg house flock for the control. Concentrations and emissions of nitrous oxide (NO) and methane (CH) from the alum-treated house were not significantly different than the untreated house. However, carbon dioxide (CO) emissions were significantly higher from the untreated house than the alum-treated house. Alum also significantly increased litter N content and reduced the C/N ratio. These results indicate that the addition of alum to poultry litter is not only an effective management practice for reducing in-house NH concentrations and emissions but also significantly reduces CO emissions from poultry facilities. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

[Valuation of forest damage cost from SO2 emission: a case study in Hunan Province].

PubMed

Hao, Jiming; Li, Ji; Duan, Lei; He, Kebin; Dai, Wennan

2002-11-01

Large amount SO2 emission caused serious damage of forest ecosystem in China and calculation of the damage cost is an important issue for policy-making. However, no applicable method was developed to estimate forest damage under different SO2 emission scenarios. Basing on previous field researches on sulfur-related forest impact in China and recent critical load mapping research, this paper presented a model for forest damage calculation by developing a dose-response function that related the damage to cumulative sulfur critical loads. This model was applied to the forests in Hunan, a province in acid rain control zone in China. Results showed that in the business-as-usual case, SO2 emission in Hunan will increase by 120% from 1995 (8.82 mil. ton) to 2020 (19.56 mil. ton), but damage cost will increase by 4.3 times, reaching 6.19 billion RMB in 2020. Results also showed the measures for SO2 control were cost-effective because the marginal damage cost will be about 6000 RMB per ton SO2 in 2020 in BAU case. At current SO2 emission level, marginal benefit will be about 1500 RMB per ton. Uncertainty analysis demonstrated that this model provides reasonable damage estimates and would therefore be applicable in a broad range of policy settings.

Real-World Emission Factors of Gaseous and Particulate Pollutants from Marine Fishing Boats and Their Total Emissions in China.

PubMed

Zhang, Fan; Chen, Yingjun; Chen, Qi; Feng, Yanli; Shang, Yu; Yang, Xin; Gao, Huiwang; Tian, Chongguo; Li, Jun; Zhang, Gan; Matthias, Volker; Xie, Zhiyong

2018-04-17

Pollutants from fishing boats have generally been neglected worldwide, and there is an acute shortage of measured emission data, especially in China. Therefore, on-board measurements of pollutants emitted from 12 different fishing boats in China (including gill net, angling, and trawler boats) were carried out in this study to investigate emission factors (EFs), characteristics and total emissions. The average EFs for CO 2 , CO, NO x , PM, and SO 2 were 3074 ± 55.9, 50.6 ± 31.7, 54.2 ± 30.7, 9.54 ± 2.24, and 5.94 ± 6.38 g (kg fuel) -1 , respectively, which were higher than those from previous studies of fishing boats. When compared to medium-speed and slow-speed engine vessels, high-speed engines on fishing boats had higher CO EFs but lower NO x EFs. Notably, when fishing boats were in low-load conditions, they always had higher EFs of CO, PM, and NO 2 compared to other operating modes. The estimated results showed that emissions from motor-powered fishing boats in China in 2012 (232, 379, and 61.8 kt CO, NO x and PM) accounted for 10.7%, 10.9%, and 19.3% of the total CO, NO x and PM emitted from nonroad mobile sources, which means significant contribution of fishing boats to air pollution, especially in southern China areas.

Regional aerosol emissions and temperature response: Local and remote climate impacts of regional aerosol forcing

NASA Astrophysics Data System (ADS)

Lewinschal, Anna; Ekman, Annica; Hansson, Hans-Christen

2017-04-01

Emissions of anthropogenic aerosols vary substantially over the globe and the short atmospheric residence time of aerosols leads to a highly uneven radiative forcing distribution, both spatially and temporally. Regional aerosol radiative forcing can, nevertheless, exert a large influence on the temperature field away from the forcing region through changes in heat transport or the atmospheric or ocean circulation. Moreover, the global temperature response distribution to aerosol forcing may vary depending on the geographical location of the forcing. In other words, the climate sensitivity in one region can vary depending on the location of the forcing. The surface temperature distribution response to changes in sulphate aerosol forcing caused by sulphur dioxide (SO2) emission perturbations in four different regions is investigated using the Norwegian Earth System Model (NorESM). The four regions, Europe, North America, East and South Asia, are all regions with historically high aerosol emissions and are relevant from both an air-quality and climate policy perspective. All emission perturbations are defined relative to the year 2000 emissions provided for the Coupled Model Intercomparison Project phase 5. The global mean temperature change per unit SO2 emission change is similar for all four regions for similar magnitudes of emissions changes. However, the global temperature change per unit SO2 emission in simulations where regional SO2 emission were removed is substantially higher than that obtained in simulations where regional SO2 emissions were increased. Thus, the climate sensitivity to regional SO2 emissions perturbations depends on the magnitude of the emission perturbation in NorESM. On regional scale, on the other hand, the emission perturbations in different geographical locations lead to different regional temperature responses, both locally and in remote regions. The results from the model simulations are used to construct regional temperature potential (RTP) coefficients, which directly link regional aerosol or aerosol precursor emissions to the temperature response in different regions. These RTP coefficients can provide a simplified way to perform an initial evaluation of climate impacts of e.g. different emission policy pathways and pollution abatement strategies.

Relative impact of short-term emissions controls on gas and particle-phase oxidative potential during the 2015 China Victory Day Parade in Beijing, China

NASA Astrophysics Data System (ADS)

Huang, Wei; Fang, Dongqing; Shang, Jing; Li, Zhengqiang; Zhang, Yang; Huo, Peng; Liu, Zhaoying; Schauer, James J.; Zhang, Yuanxun

2018-06-01

A field observation focusing on reactive oxygen species (ROS) was conducted before, during, and after the 2015 China Victory Day Parade to understand the influence of short-term emissions controls on atmospheric oxidative activity. The hourly average concentrations of PM2.5, SO2, NO, NO2, CO, O3, as well as gas and particle-phase ROS, were measured using a series of online instruments. PM2.5 concentrations during control days were significantly lower than non-control days, which directly lead to the "Parade Blue", yet reductions of most gaseous pollutants except SO2 were not so obvious as PM. Similarly, the control measures also led to a great loss of particle-phase ROS throughout the control period, while the reduction of ROS in gas phase was not obvious until the more stringent measures implemented since September 1. Furthermore, only weak positive correlations were observed among ROS and some other measured species, indicating ROS concentrations were affected by a number of comprehensive factors that single marker could not capture. Meanwhile, meteorological condition and regional transportation were also shown to be the minor factors affecting atmospheric oxidizing capacity. The results of this observation mainly revealed the control measures were conducive to reducing particle-related ROS. However, the reduction of gas-phase ROS activity was less effective given the menu of controls employed for the 2015 China Victory Day Parade. Therefore, short-term emissions controls only aimed to PM reduction and visibility improvement will produce the blue sky but will not equivalently reduce the gas-phase ROS. Supplemental control measures will be needed to further reduce gas-phase ROS concentrations.

Aged particles derived from emissions of coal-fired power plants: The TERESA field results

PubMed Central

Kang, Choong-Min; Gupta, Tarun; Ruiz, Pablo A.; Wolfson, Jack M.; Ferguson, Stephen T.; Lawrence, Joy E.; Rohr, Annette C.; Godleski, John; Koutrakis, Petros

2013-01-01

The Toxicological Evaluation of Realistic Emissions Source Aerosols (TERESA) study was carried out at three US coal-fired power plants to investigate the potential toxicological effects of primary and photochemically aged (secondary) particles using in situ stack emissions. The exposure system designed successfully simulated chemical reactions that power plant emissions undergo in a plume during transport from the stack to receptor areas (e.g., urban areas). Test atmospheres developed for toxicological experiments included scenarios to simulate a sequence of atmospheric reactions that can occur in a plume: (1) primary emissions only; (2) H2SO4 aerosol from oxidation of SO2; (3) H2SO4 aerosol neutralized by gas-phase NH3; (4) neutralized H2SO4 with secondary organic aerosol (SOA) formed by the reaction of α-pinene with O3; and (5) three control scenarios excluding primary particles. The aged particle mass concentrations varied significantly from 43.8 to 257.1 μg/m3 with respect to scenario and power plant. The highest was found when oxidized aerosols were neutralized by gas-phase NH3 with added SOA. The mass concentration depended primarily on the ratio of SO2 to NOx (particularly NO) emissions, which was determined mainly by coal composition and emissions controls. Particulate sulfate (H2SO4 + neutralized sulfate) and organic carbon (OC) were major components of the aged particles with added SOA, whereas trace elements were present at very low concentrations. Physical and chemical properties of aged particles appear to be influenced by coal type, emissions controls and the particular atmospheric scenarios employed. PMID:20462390

Contributions of mobile, stationary and biogenic sources to air pollution in the Amazon rainforest: a numerical study with the WRF-Chem model

NASA Astrophysics Data System (ADS)

Abou Rafee, Sameh A.; Martins, Leila D.; Kawashima, Ana B.; Almeida, Daniela S.; Morais, Marcos V. B.; Souza, Rita V. A.; Oliveira, Maria B. L.; Souza, Rodrigo A. F.; Medeiros, Adan S. S.; Urbina, Viviana; Freitas, Edmilson D.; Martin, Scot T.; Martins, Jorge A.

2017-06-01

This paper evaluates the contributions of the emissions from mobile, stationary and biogenic sources on air pollution in the Amazon rainforest by using the Weather Research and Forecasting with Chemistry (WRF-Chem) model. The analyzed air pollutants were CO, NOx, SO2, O3, PM2. 5, PM10 and volatile organic compounds (VOCs). Five scenarios were defined in order to evaluate the emissions by biogenic, mobile and stationary sources, as well as a future scenario to assess the potential air quality impact of doubled anthropogenic emissions. The stationary sources explain the highest concentrations for all air pollutants evaluated, except for CO, for which the mobile sources are predominant. The anthropogenic sources considered resulted an increasing in the spatial peak-temporal average concentrations of pollutants in 3 to 2780 times in relation to those with only biogenic sources. The future scenario showed an increase in the range of 3 to 62 % in average concentrations and 45 to 109 % in peak concentrations depending on the pollutant. In addition, the spatial distributions of the scenarios has shown that the air pollution plume from the city of Manaus is predominantly transported west and southwest, and it can reach hundreds of kilometers in length.

Horizontal and Vertical Distributions of SO2 Observed During the PEACE Missions

NASA Astrophysics Data System (ADS)

Tanimoto, H.; Hatakeyama, S.; Takami, A.; Kita, K.

2002-12-01

Measurements of sulfur dioxide (SO2) were made by a significantly modified pulsed-fluorescence analyzer during the PEACE (Pacific Exploration of Asian Continental Emission) B aircraft missions, which were conducted over the East Asian Pacific rim/Western Pacific region in spring 2002. The SO2 data are successfully obtained up to approximately 5 km during the whole flights. The mixing ratios of SO2 show a large variability ranging from <100 pptv to 15 ppbv. The SO2 variability is mainly controlled by the switching of continental and maritime air masses. Enhanced SO2 levels due to _gfresh_h continental outflow events are found below 2 km regions over the Sea of Japan. Several plumes, whose mixing ratios elevated as high as >10 ppbv, are attributed to emissions from volcanic islands around Japan. Although the continental emissions and outflow make large contribution to the mixing ratio levels, variations, and distributions of SO2 around the East Asian continental rim and the western Pacific regions, volcanic activities also significantly inject large amount of SO2 into the lower atmosphere of the regions. The SO2 data are compared with those from PEACE-A and previous campaigns (e.g., PEM-West A and B, PEACAMPOT). Relative importance of the contribution from anthropogenic and volcanic emissions on the SO2 distributions in this region is discussed.

A new approach for the construction of gridded emission inventories from satellite data

NASA Astrophysics Data System (ADS)

Kourtidis, Konstantinos; Georgoulias, Aristeidis; Mijling, Bas; van der A, Ronald; Zhang, Qiang; Ding, Jieying

2017-04-01

We present a new method for the derivation of anthropogenic emission estimates for SO2. The method, which we term Enhancement Ratio Method (ERM), uses observed relationships between measured OMI satellite tropospheric columnar levels of SO2 and NOx in each 0.25 deg X 0.25 deg grid box at low wind speeds, and the Daily Emission estimates Constrained by Satellite Observations (DECSO) versions v1 and v3a NOx emission estimates to scale the SO2 emissions. The method is applied over China, and emission estimates for SO2 are derived for different seasons and years (2007-2011), thus allowing an insight into the interannual evolution of the emissions. The inventory shows a large decrease of emissions during 2007-2009 and a modest increase between 2010-2011. The evolution in emission strength over time calculated here is in general agreement with bottom-up inventories, although differences exist, not only between the current inventory and other inventories but also among the bottom up inventories themselves. The gridded emission estimates derived appear to be consistent, both in their spatial distribution and their magnitude, with the Multi-resolution Emission Inventory for China (MEIC). The total emissions correlate very well with most existing inventories. This research has been financed under the FP7 Programme MarcoPolo (Grand Number 606953, Theme SPA.2013.3.2-01).

Organically fertilized tea plantation stimulates N2O emissions and lowers NO fluxes in subtropical China

NASA Astrophysics Data System (ADS)

Yao, Z.; Wei, Y.; Liu, C.; Zheng, X.; Xie, B.

2015-07-01

Tea plantations are rapidly expanding in China and other countries in the tropical and subtropical zones, but so far there are very few studies including direct measurements on nitrogenous gases fluxes from tea plantations. On the basis of 2 year field measurements from 2012 to 2014, we provided an insight into the assessment of annual nitrous oxide (N2O) and nitric oxide (NO) fluxes from Chinese subtropical tea plantations under three practices of conventional urea application, alternative oilcake incorporation and no nitrogen fertilization. Clearly, the N2O and NO fluxes exhibited large intra- and inter-annual variations, and furthermore their temporal variability could be well described by a combination of soil environmental factors including soil mineral N, water-filled pore space and temperature, based on a revised "hole-in-the-pipe" model. Averaged over 2 years, annual background N2O and NO emissions were approximately 4.0 and 1.6 kg N ha-1 yr-1, respectively. Compared to no nitrogen fertilization, both urea and oilcake application significantly stimulated annual N2O and NO emissions, amounting to 14.4-32.7 kg N2O-N ha-1 yr-1 and at least 12.3-19.4 kg NO-N ha-1 yr-1. In comparison with conventional urea treatment, on average, the application of organic fertilizer significantly increased N2O emission by 71 % but decreased NO emission by 22 %. Although the magnitude of N2O and NO fluxes was substantially influenced by N source, the annual direct emission factors of fertilizer N were estimated to be 2.8-5.9, 2.7-4.0 and 6.8-9.1 % for N2O, NO and N2O + NO, respectively, which are significantly higher than those defaults for global upland croplands. This indicated that the rarely determined N2O and NO formation appeared to be a significant pathway in the nitrogen cycle of tea plantations, which are a potential source of national nitrogenous gases inventory.

Organically fertilized tea plantation stimulates N2O emissions and lowers NO fluxes in subtropical China

NASA Astrophysics Data System (ADS)

Yao, Z.; Wei, Y.; Liu, C.; Zheng, X.; Xie, B.

2015-10-01

Tea plantations are rapidly expanding in China and other countries in the tropical and subtropical zones, but so far there are very few studies including direct measurements of nitrogenous gas fluxes from tea plantations. On the basis of 2-year field measurements from 2012 to 2014, we provided an insight into the assessment of annual nitrous oxide (N2O) and nitric oxide (NO) fluxes from Chinese subtropical tea plantations under three practices of conventional urea application, alternative oilcake incorporation and no nitrogen fertilization. Clearly, the N2O and NO fluxes exhibited large intra- and inter-annual variations, and furthermore, their temporal variability could be well described by a combination of soil environmental factors including soil mineral N, water-filled pore space and temperature, based on a revised "hole-in-the-pipe" model. Averaged over a 2-year study, annual background N2O and NO emissions were approximately 4.0 and 1.6 kg N ha-1 yr-1, respectively. Compared to no nitrogen fertilization, both urea and oilcake application significantly stimulated annual N2O and NO emissions, amounting to 14.4-32.7 kg N2O-N ha-1 yr-1 and at least 12.3-19.4 kg NO-N ha-1 yr-1, respectively. In comparison with conventional urea treatment, on average, the application of organic fertilizer significantly increased N2O emission by 71 % but decreased NO emission by 22 %. Although the magnitude of N2O and NO fluxes was substantially influenced by the source of N, the annual direct emission factors of N fertilizer were estimated to be 2.8-5.9, 2.7-4.0 and 6.8-9.1 % for N2O, NO and N2O+NO, respectively, which are significantly higher than those defaults for global upland croplands. This indicated that the rarely determined N2O and NO formation appeared to be a significant pathway in the nitrogen cycle of tea plantations, which are a potential source of national nitrogenous gases inventory.

Emission factors of fine particles, carbonaceous aerosols and traces gases from road vehicles: Recent tests in an urban tunnel in the Pearl River Delta, China

NASA Astrophysics Data System (ADS)

Zhang, Yanli; Wang, Xinming; Li, Guanghui; Yang, Weiqiang; Huang, Zhonghui; Zhang, Zhou; Huang, Xinyu; Deng, Wei; Liu, Tengyu; Huang, Zuzhao; Zhang, Zhanyi

2015-12-01

Motor vehicles contribute primarily and secondarily to air quality problems due to fine particle (PM2.5) and ozone (O3) pollution in China's megacities. Characterizing vehicle emission with the rapid change of vehicle numbers and fleet compositions is vital for both bottom-up emission survey and top-down source apportioning. To obtain emission factors (EFs) of PM2.5, carbonaceous aerosols and trace gases for road vehicles, in urban Guangzhou we conducted a field campaign in 2014 in the Zhujiang Tunnel, a heavily burdened tunnel with about 40,000 motor vehicles passing through each of its two separated bores per day. PM2.5 and volatile organic compounds (VOCs) were sampled for offline analysis while trace gases including SO2, NOx and CO were measured online and in situ. An eddy covariance system with an integrated 3-D sonic anemometer was also adopted to measure CO2 and winds inside the tunnel. We recorded an average fleet composition of 61% light-duty gasoline vehicles (LDVs) + 12% heavy-duty diesel vehicles (HDVs) + 27% liquefied petroleum gas vehicles (LPGVs), and EFs of 82.7 ± 28.3, 19.3 ± 4.7 and 13.3 ± 3.3 mg veh-1 km-1, respectively, for PM2.5, organic carbon (OC) and elemental carbon (EC). These EFs were respectively 23.4%, 18.3% and 72.3% lower when compared to that measured in the same tunnel in 2004. EFs of PM2.5, OC and EC were higher at night time (148 ± 126, 29 ± 24 and 21 ± 18 mg veh-1 km-1, respectively) due to significantly elevated fractions of HDVs in the traffic fleets. An average ratio of OC to EC 1.45 from this tunnel study was much higher than that of ∼0.5 in previous tunnel studies. The EFs of SO2, NOx, CO, CO2 and NMHCs for road traffic were also obtained from our tunnel tests, and they were 20.7 ± 2.9, (1.29 ± 0.2)E+03, (3.10 ± 0.68)E+03, (3.90 ± 0.49)E+05, and 448 ± 39 mg veh-1 km-1, respectively.

Greenidge Multi-Pollutant Control Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Connell, Daniel

2008-10-18

The Greenidge Multi-Pollutant Control Project was conducted as part of the U.S. Department of Energy's Power Plant Improvement Initiative to demonstrate an innovative combination of air pollution control technologies that can cost-effectively reduce emissions of SO{sub 2}, NO{sub x}, Hg, acid gases (SO{sub 3}, HCl, and HF), and particulate matter from smaller coal-fired electric generating units (EGUs). There are about 400 units in the United States with capacities of 50-300 MW that currently are not equipped with selective catalytic reduction (SCR), flue gas desulfurization (FGD), or mercury control systems. Many of these units, which collectively represent more than 55 GWmore » of installed capacity, are difficult to retrofit for deep emission reductions because of space constraints and unfavorable economies of scale, making them increasingly vulnerable to retirement or fuel switching in the face of progressively more stringent environmental regulations. The Greenidge Project sought to confirm the commercial readiness of an emissions control system that is specifically designed to meet the environmental compliance requirements of these smaller coal-fired EGUs by offering a combination of deep emission reductions, low capital costs, small space requirements, applicability to high-sulfur coals, mechanical simplicity, and operational flexibility. The multi-pollutant control system includes a NO{sub x}OUT CASCADE{reg_sign} hybrid selective non-catalytic reduction (SNCR)/in-duct SCR system for NO{sub x} control and a Turbosorp{reg_sign} circulating fluidized bed dry scrubbing system (with a new baghouse) for SO{sub 2}, SO{sub 3}, HCl, HF, and particulate matter control. Mercury removal is provided as a co-benefit of the in-duct SCR, dry scrubber, and baghouse, and by injection of activated carbon upstream of the scrubber, if required. The multi-pollutant control system was installed and tested on the 107-MW{sub e}, 1953-vintage AES Greenidge Unit 4 by a team including CONSOL Energy Inc. as prime contractor, AES Greenidge LLC as host site owner, and Babcock Power Environmental Inc. as engineering, procurement, and construction contractor. About 44% of the funding for the project was provided by the U.S. Department of Energy, through its National Energy Technology Laboratory, and the remaining 56% was provided by AES Greenidge. Project goals included reducing high-load NO{sub x} emissions to {le} 0.10 lb/mmBtu; reducing SO{sub 2}, SO{sub 3}, HCl, and HF emissions by at least 95%; and reducing Hg emissions by at least 90% while the unit fired 2-4% sulfur eastern U.S. bituminous coal and co-fired up to 10% biomass. This report details the final results from the project. The multi-pollutant control system was constructed in 2006, with a total plant cost of $349/kW and a footprint of 0.4 acre - both substantially less than would have been required to retrofit AES Greenidge Unit 4 with a conventional SCR and wet scrubber. Start-up of the multi-pollutant control system was completed in March 2007, and the performance of the system was then evaluated over an approximately 18-month period of commercial operation. Guarantee tests conducted in March-June 2007 demonstrated attainment of all of the emission reduction goals listed above. Additional tests completed throughout the performance evaluation period showed 96% SO{sub 2} removal, 98% mercury removal (with no activated carbon injection), 95% SO{sub 3} removal, and 97% HCl removal during longer-term operation. Greater than 95% SO{sub 2} removal efficiency was observed even when the unit fired high-sulfur coals containing up to 4.8 lb SO{sub 2}/mmBtu. Particulate matter emissions were reduced by more than 98% relative to the emission rate observed prior to installation of the technology. The performance of the hybrid SNCR/SCR system was affected by problems with large particle ash, ammonia slip, and nonideal combustion characteristics, and high-load NO{sub x} emissions averaged 0.14 lb/mmBtu during long-term operation. Nevertheless, the system has reduced the unit's overall NO{sub x} emissions by 52% on a lb/mmBtu basis. The commercial viability of the multi-pollutant control system was demonstrated at AES Greenidge Unit 4. The system, which remains in service after the conclusion of the project, has enabled the unit to satisfy its permit requirements while continuing to operate profitably. As a result of the success at AES Greenidge Unit 4, three additional deployments of the Turbosorp{reg_sign} technology had been announced by the end of the project.« less

Volcanic gas composition changes during the gradual decrease of the gigantic degassing activity of Miyakejima volcano, Japan, 2000-2015

NASA Astrophysics Data System (ADS)

Shinohara, Hiroshi; Geshi, Nobuo; Matsushima, Nobuo; Saito, Genji; Kazahaya, Ryunosuke

2017-02-01

The composition of volcanic gases discharged from Miyakejima volcano has been monitored during the intensive degassing activity that began after the eruption in 2000. During the 15 years from 2000 to 2015, Miyakejima volcano discharged 25.5 Mt of SO2, which required degassing of 3 km3 of basaltic magma. The SO2 emission rate peaked at 50 kt/day at the end of 2000 and quickly decreased to 5 kt/day by 2003. During the early degassing period, the volcanic gas composition was constant with the CO2/SO2 = 0.8 (mol ratio), H2O/SO2 = 35, HCl/SO2 = 0.08, and SO2/H2S = 15. The SO2 emission rate decreased gradually to 0.5 kt/day by 2012, and the gas composition also changed gradually to CO2/SO2 = 1.5, H2O/SO2 = 150, HCl/SO2 = 0.15, and SO2/H2S = 6. The compositional changes are not likely caused by changes in degassing pressure or volatile heterogeneity of a magma chamber but are likely attributed to an increase of hydrothermal scrubbing caused by large decrease of the volcanic gas emission rate, suggesting a supply of gases with constant composition during the 15 years. The intensive degassing was modeled based on degassing of a convecting magma conduit. The gradual SO2 emission rate that decrease without changes in volcanic gas composition is attributed to a reduction of diameter of the convecting magma conduit.

Synthesis and characterization of prospective polyanionic electrode materials for high performance energy storage applications

NASA Astrophysics Data System (ADS)

Jayachandran, M.; Durai, G.; Vijayakumar, T.

2018-04-01

In the present study, Polyanionic compound (SO4)-group based on Li2Ni(SO4)2 (Lithium Nickel Sulphate) composite electrodes materials were prepared by a ball-milling method and solid-state reaction route. X-ray diffraction analysis confirmed the formation of a polycrystalline orthorhombic phase of composite Li2Ni(SO4)2 with an average crystallite size of about 50.16 nm. Field Emission Scanning electron microscopy investigation reveals the spherical shape particles with the particle size of around 200–500 nm. Raman and FTIR analysis confirms the structural and functional groups of the synthesized materials and also the formation of Li2Ni(SO4)2. The electrochemical measurements using cyclic voltammetry (CV) and galvanostatic charging-discharging (GCD) techniques were carried out to study the electrochemical supercapacitive performance of the composite Li2Ni (SO4)2 electrodes. From the CV investigations, an areal capacitance of 508 mF cm‑2 was obtained at 10 mV s‑1. The galvanostatic charge-discharge (GCD) measurements exhibited the areal capacitance of 101 mF cm‑2 at a constant current density of 2 mA cm‑2 in 2 M KOH. These GCD profiles were linear and also symmetric in nature with the maximum columbic efficiency of about 85%. The electrochemical performance of the composite Li2Ni(SO4)2 electrode material shows excellent performance for supercapacitor applications.

Crustal-scale degassing due to magma system destabilization and magma-gas decoupling at Soufrière Hills Volcano, Montserrat

NASA Astrophysics Data System (ADS)

Christopher, T. E.; Blundy, J.; Cashman, K.; Cole, P.; Edmonds, M.; Smith, P. J.; Sparks, R. S. J.; Stinton, A.

2015-09-01

Activity since 1995 at Soufrière Hills Volcano (SHV), Montserrat has alternated between andesite lava extrusion and quiescence, which are well correlated with seismicity and ground deformation cycles. Large variations in SO2 flux do not correlate with these alternations, but high and low HCl/SO2 characterize lava dome extrusion and quiescent periods respectively. Since lava extrusion ceased (February 2010) steady SO2 emissions have continued at an average rate of 374 tonnes/day (± 140 t/d), and incandescent fumaroles (temperatures up to 610oC) on the dome have not changed position or cooled. Occasional short bursts (over several hours) of higher (˜ 10x) SO2 flux have been accompanied by swarms of volcano-tectonic earthquakes. Strain data from these bursts indicate activation of the magma system to depths up to 10 km. SO2 emissions since 1995 greatly exceed the amounts that could be derived from 1.1 km3 of erupted andesite, and indicating extensive partitioning of sulfur into a vapour phase, as well as efficient decoupling and outgassing of sulfur-rich gases from the magma. These observations are consistent with a vertically extensive, crustal magmatic mush beneath SHV. Three states of the magmatic system are postulated to control degassing. During dormant periods (103 to 104 years) magmatic vapour and melts separate as layers from the mush and decouple from each other. In periods of unrest (years) without eruption, melt and fluid layers become unstable, ascend and can amalgamate. Major destabilization of the mush system leads to eruption, characterized by magma mixing and release of volatiles with different ages, compositions and sources.

Fluxes of CH4 and CO2 from soil and termite mounds in south Sudanian savanna of Burkina Faso (West Africa)

NASA Astrophysics Data System (ADS)

Brümmer, Christian; Papen, Hans; Wassmann, Reiner; Brüggemann, Nicolas

2009-03-01

The contribution of West African savanna ecosystems to global greenhouse gas budgets is highly uncertain. In this study we quantified soil-atmosphere CH4 and CO2 fluxes in the southwest of Burkina Faso from June to September 2005 and from April to September 2006 at four different agricultural fields planted with sorghum (n = 2), cotton, and peanut and at a natural savanna site with termite (Cubitermes fungifaber) mounds. During the rainy season both CH4 uptake and CH4 emission were observed in the savanna, which was on average a CH4 source of 2.79 and 2.28 kg CH4-C ha-1 a-1 in 2005 and 2006, respectively. The crop sites were an average CH4 sink of -0.67 and -0.70 kg CH4-C ha-1 a-1 in the 2 years, without significant seasonal variation. Mean annual soil respiration ranged between 3.86 and 5.82 t CO2-C ha-1 a-1 in the savanna and between 2.50 and 4.51 t CO2-C ha-1 a-1 at the crop sites. CH4 emission from termite mounds was 2 orders of magnitude higher than soil CH4 emissions, whereas termite CO2 emissions were of the same order of magnitude as soil CO2 emissions. Termite CH4 and CO2 release in the savanna contributed 8.8% and 0.4% to the total soil CH4 and CO2 emissions, respectively. At the crop sites, where termite mounds had been almost completely removed because of land use change, termite fluxes were insignificant. Mound density-based upscaling of termite CH4 fluxes resulted in a global termite CH4 source of 0.9 Tg a-1, which corresponds to 0.15% of the total global CH4 budget of 582 Tg a-1, hence significantly lower than those obtained previously by biomass-based calculations. This study emphasizes that land use change, which is of high relevance in this region, has particularly affected soil CH4 fluxes in the past and might still do so in the future.

40 CFR 63.652 - Emissions averaging provisions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... emissions average. This must include any Group 1 emission points to which the reference control technology... controls for a Group 1 emission point, the pollution prevention measure alone does not have to reduce... in control after November 15, 1990; (2) Group 1 emission points that are controlled by a reference...

40 CFR 63.652 - Emissions averaging provisions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... emissions average. This must include any Group 1 emission points to which the reference control technology... controls for a Group 1 emission point, the pollution prevention measure alone does not have to reduce... in control after November 15, 1990; (2) Group 1 emission points that are controlled by a reference...

Cotopaxi volcano's unrest and eruptive activity in 2015: mild awakening after 73 years of quiescence

NASA Astrophysics Data System (ADS)

Hidalgo, Silvana; Bernard, Benjamin; Battaglia, Jean; Gaunt, Elizabeth; Barrington, Charlotte; Andrade, Daniel; Ramón, Patricio; Arellano, Santiago; Yepes, Hugo; Proaño, Antonio; Almeida, Stefanie; Sierra, Daniel; Dinger, Florian; Kelly, Peter; Parra, René; Bobrowski, Nicole; Galle, Bo; Almeida, Marco; Mothes, Patricia; Alvarado, Alexandra

2016-04-01

Cotopaxi volcano (5,897 m) is located 50 km south of Quito, the capital of Ecuador. The most dangerous hazards of this volcano are the devastating lahars that can be generated by the melting of its ice cap during pyroclastic flow-forming eruptions. The first seismic station was installed in 1976. Cotopaxi has been monitored by the Instituto Geofísico (Escuela Politécnica Nacional) since 1983. Presently the monitoring network is comprised of 11 broadband and 5 short period seismometers, 4 scanning DOAS, 1 infrared and 5 visible cameras, 7 DGPS, 5 tiltmeters, 11 AFM (lahar detectors) and a network of ashmeters. Due to the recent unrest, the monitoring of the volcano has been complemented by campaign airborne Multi-GAS and thermal IR measurements and ground-based mobile DOAS and stationary solar FTIR. After 73 years of quiescence, the first sign of unrest was a progressive increase in the amplitude of transient seismic events in April 2015. Since May 20, an increase in SO2 emissions from ˜500 t/d to ˜3 kt/day was detected followed by the appearance of seismic tremor on June 4. Both SO2 emissions of up to 5 kt/day and seismic tremor were observed until August 14 when a swarm of volcano-tectonic earthquakes preceded the first phreatic explosions. These explosions produced ash and gas columns reaching up to 9 km above the crater. The ash fall produced by the opening phase covered over 500 km2 with a submillimetric deposit corresponding to a mass of 1.65E+8 kg (VEI 1). During this period of explosions, SO2 emission rates up to 24 kt/day were observed, the highest thus far. The ash was dominantly hydrothermally altered and oxidized lithic fragments, hydrothermal minerals (alunite, gypsum), free crystals of plagioclase and pyroxenes, and little juvenile material. Unrest continued after August 14, with three episodes of ash emission. However, the intensity of ash fallout, average seismic amplitude, and SO2 emissions during each successive episode progressively decreased, while juvenile component increased. Total ash fallout mass since August 14 yield 1.19E+9 kg. During these episodes BrO and HCl were detected in the plume, and airborne Multi-GAS measurements showed that the plume had a CO2/SO2 ratio from 1 to 2.5 and that SO2 was >99% of total sulfur (SO2+ H2S), indicating a shallow magmatic origin for the gas. During ash emissions temperatures of up to 200° C were measured at the column with an IR camera. Thermal anomalies in the upper part of the edifice have also been observed and have resulted in minor melting of the ice cap. This phenomenon has produced small secondary lahars with a maximum discharge on the order of 10 to 30 m3/s. Since late November 2015, surface manifestations and the other monitored parameters have shown a marked decrease. Historical reports of Cotopaxi's activity show that both short and long-lasting eruptive periods usually start with mild eruptive phases prior to culminating in VEI 3 or 4 eruptions. Therefore special care should be taken in monitoring unrest at Cotopaxi in order to identify precursory signs of a larger eruption.

Effect of selective catalytic reduction (SCR) on fine particle emission from two coal-fired power plants in China

NASA Astrophysics Data System (ADS)

Li, Zhen; Jiang, Jingkun; Ma, Zizhen; Wang, Shuxiao; Duan, Lei

2015-11-01

Nitrogen oxides (NOx) emission abatement of coal-fired power plants (CFPPs) requires large-scaled installation of selective catalytic reduction (SCR), which would reduce secondary fine particulate matter (PM2.5) (by reducing nitrate aerosol) in the atmosphere. However, our field measurement of two CFPPs equipped with SCR indicates a significant increase of SO42- and NH4+ emission in primary PM2.5, due to catalytic enhancement of SO2 oxidation to SO3 and introducing of NH3 as reducing agent. The subsequent formation of (NH4)2SO4 or NH4HSO4 aerosol is commonly concentrated in sub-micrometer particulate matter (PM1) with a bimodal pattern. The measurement at the inlet of stack also showed doubled primary PM2.5 emission by SCR operation. This effect should therefore be considered when updating emission inventory of CFPPs. By rough estimation, the enhanced primary PM2.5 emission from CFPPs by SCR operation would offset 12% of the ambient PM2.5 concentration reduction in cities as the benefit of national NOx emission abatement, which should draw attention of policy-makers for air pollution control.

Response of SO2 and Particulate Air Pollution to Local and Regional Emission Controls: A Case Study in Maryland

NASA Technical Reports Server (NTRS)

He, Hao; Vinnikov, Konstantin Y.; Li, Can; Krotkov, Nickolay Anatoly; Jongeward, Andrew R.; Li, Zhanqing; Stehr, Jeffrey W.; Hains, Jennifer; Dickerson, RUssell R.

2016-01-01

This paper addresses the questions of what effect local regulations can have on pollutants with different lifetimes and how surface observations and remotely sensed data can be used to determine the impacts. We investigated the decadal trends of tropospheric sulfur dioxide (SO2) and aerosol pollution over Maryland and its surrounding states, using surface, aircraft, and satellite measurements. Aircraft measurements indicated fewer isolated SO2 plumes observed in summers, a 40 decrease of column SO2, and a 20 decrease of atmospheric optical depth (AOD) over Maryland after the implementation of local regulations on sulfur emissions from power plants (90 reduction from 2010). Surface observations of SO2 and particulate matter (PM) concentrations in Maryland show similar trends. OMI SO2 and MODIS AOD observations were used to investigate the column contents of air pollutants over the eastern U.S.; these indicate decreasing trends in column SO2 (60 decrease) and AOD (20 decrease). The decrease of upwind SO2 emissions also reduced aerosol loadings over the downwind Atlantic Ocean near the coast by 20, while indiscernible changes of the SO2 column were observed. A step change of SO2 emissions in Maryland starting in 20092010 had an immediate and profound benefit in terms of local surface SO2 concentrations but a modest impact on aerosol pollution, indicating that short-lived pollutants are effectively controlled locally, while long-lived pollutants require regional measures.

Characteristics and source apportionment of fine haze aerosol in Beijing during the winter of 2013

NASA Astrophysics Data System (ADS)

Shang, Xiaona; Zhang, Kai; Meng, Fan; Wang, Shihao; Lee, Meehye; Suh, Inseon; Kim, Daigon; Jeon, Kwonho; Park, Hyunju; Wang, Xuezhong; Zhao, Yuxi

2018-02-01

For PM2.5 filter samples collected daily at the Chinese Research Academy of Environmental Sciences (Beijing, China) from December of 2013 to February of 2014 (the winter period), chemical characteristics and sources were investigated with an emphasis on haze events in different alert levels. During the 3 months, the average PM2.5 concentration was 89 µg m-3, exceeding the Chinese national standard of 75 µg m-3 in 24  h. The maximum PM2.5 concentration was 307 µg m-3, which characterizes developed-type pollution (PM2.5 / PM10>0.5) in the World Health Organization criteria. PM2.5 was dominated by SO42-, NO3-, and pseudo-carbonaceous compounds with obvious differences in concentrations and proportions between non-haze and haze episodes. The non-negative matrix factorization (NMF) analysis provided reasonable PM2.5 source profiles, by which five sources were identified: soil dust, traffic emission, biomass combustion, industrial emission, and coal combustion accounting for 13, 22, 12, 28, and 25  % of the total, respectively. The dust impact increased with northwesterlies during non-haze periods and decreased under stagnant conditions during haze periods. A blue alert of heavy air pollution was characterized by the greatest contribution from industrial emissions (61  %). During the Chinese Lantern Festival, an orange alert was issued and biomass combustion was found to be the major source owing to firework explosions. Red-alert haze was almost equally contributed by local traffic and transported coal combustion emissions from the vicinity of Beijing (approximately 40  % each) that was distinguished by the highest levels of NO3- and SO42-, respectively. This study also reveals that the severity and source of haze are largely dependent on meteorological conditions.

40 CFR 60.84 - Emission monitoring.

Code of Federal Regulations, 2011 CFR

2011-07-01

... velocities or production rate. Continuous emission monitoring systems for measuring SO2, O2, and CO2 (if... H2SO4 produced. Cs=concentration of SO2, kg/dscm (lb/dscf). S=acid production rate factor, 368 dscm.... A=auxiliary fuel factor, =0.00 for no fuel. =0.0226 for methane. =0.0217 for natural gas. =0.0196...

40 CFR 60.84 - Emission monitoring.

Code of Federal Regulations, 2013 CFR

2013-07-01

... velocities or production rate. Continuous emission monitoring systems for measuring SO2, O2, and CO2 (if... H2SO4 produced. Cs=concentration of SO2, kg/dscm (lb/dscf). S=acid production rate factor, 368 dscm.... A=auxiliary fuel factor, =0.00 for no fuel. =0.0226 for methane. =0.0217 for natural gas. =0.0196...

40 CFR 60.84 - Emission monitoring.

Code of Federal Regulations, 2010 CFR

2010-07-01

... velocities or production rate. Continuous emission monitoring systems for measuring SO2, O2, and CO2 (if... H2SO4 produced. Cs=concentration of SO2, kg/dscm (lb/dscf). S=acid production rate factor, 368 dscm.... A=auxiliary fuel factor, =0.00 for no fuel. =0.0226 for methane. =0.0217 for natural gas. =0.0196...

40 CFR 60.84 - Emission monitoring.

Code of Federal Regulations, 2012 CFR

2012-07-01

... velocities or production rate. Continuous emission monitoring systems for measuring SO2, O2, and CO2 (if... H2SO4 produced. Cs=concentration of SO2, kg/dscm (lb/dscf). S=acid production rate factor, 368 dscm.... A=auxiliary fuel factor, =0.00 for no fuel. =0.0226 for methane. =0.0217 for natural gas. =0.0196...

40 CFR 60.84 - Emission monitoring.

Code of Federal Regulations, 2014 CFR

2014-07-01

... velocities or production rate. Continuous emission monitoring systems for measuring SO2, O2, and CO2 (if... of H2SO4 produced. Cs = concentration of SO2, kg/dscm (lb/dscf). S = acid production rate factor, 368... dry basis. A = auxiliary fuel factor, = 0.00 for no fuel. = 0.0226 for methane. = 0.0217 for natural...

A Comparison of Inventoried and Measured U.S. Urban/Industrial Hg Emission Factors during the NOMADSS Experiment

NASA Astrophysics Data System (ADS)

Ambrose, J. L., II; Gratz, L.; Jaffe, D. A.; Apel, E. C.; Campos, T. L.; Flocke, F. M.; Guenther, A. B.; Hornbrook, R. S.; Karl, T.; Kaser, L.; Knapp, D. J.; Weinheimer, A. J.; Cantrell, C. A.; Mauldin, L.; Yuan, B.

2014-12-01

We performed an airborne survey of some large anthropogenic mercury (Hg) emission sources in the Southeast U.S. during the 2013 Nitrogen, Oxidants, Mercury and Aerosol Distribution, Sources, and Sinks (NOMADSS) experiment. The observations included speciated atmospheric Hg, and tracers of urban/industrial emissions and associated photochemistry (e.g., carbon monoxide, CO; carbon dioxide, CO2; sulfur dioxide, SO2; nitrogen oxides (NOx); volatile organic compounds, VOCs; ozone, O3; hydroxyl radical, HO·; sulfuric acid, H2SO4) and were made from the National Science Foundation's/National Center for Atmospheric Research's C-130 research aircraft. Mercury was measured using the University of Washington's Detector for Oxidized Hg Species. We derived Hg emission factors (EF) for several U.S. urban areas and large industrial point sources, including coal-fired power plants (CFPPs) in Louisiana, Pennsylvania, Texas, and West Virginia. We compared our measured Hg EFs with inventory-based values from two separate Hg emission inventories provided by the U.S. Environmental Protection Agency - the National Emissions Inventory (NEI) and the Toxics Release Inventory (TRI). We also performed an inter-comparison of the inventory-based Hg EFs. For the CFPPs sampled, we find that actual Hg emissions differed from inventoried values by more than a factor of two in some cases. Measured Hg EFs were weakly correlated with values reported in the NEI: m = 0.71; r2 = 0.47 (p = 0.06; n = 8), whereas EFs derived from the TRI were not meaningfully predictive of the measured values: m = -3.3; r2 = 0.61 (p < 0.05; n = 8). Median absolute differences between measured and inventory-based EFs were ≥50%, relative to the inventory values. The median absolute average difference between the Hg EFs reported in the two inventories was approximately 40%. Our results place quantitative constraints on uncertainties associated with the inventoried Hg emissions. Additionally, our results suggest that the current formulation of the Hg emission inventories critically limits our ability to accurately predict the transport and fate of U.S. urban/industrial emissions of Hg to the atmosphere. These findings are broadly relevant to the design and use of emission inventories for industrial hazardous air pollutants.

First data on the volatile fluxes from passively degassing volcanoes of the Kuril Island arc

NASA Astrophysics Data System (ADS)

Melnikov, Dmitry; Malik, Nataliya; Chaplygin, Ilya; Zelenski, Mikhail

2017-04-01

We report the first data on the volatile fluxes from passively degassing volcanoes of Kuril Island arc in the North-Western Pacific measured in 2015-2016. Four volcanoes: Ebeko on the northern Paramushir Island, Kuntomintar and Pallace on the Central Shiashkotan and Ketoy islands, and Kudryavy on the southern Iturup island are representative for the whole Kuril arc as having the largest and strongest fumarolic fields among 40 of the active volcanoes of the arc. The fluxes were measured using scanning DOAS, remote miniDOAS, plume MultiGas and direct sampling techniques using the SO2 flux from the DOAS data and ratios measured by MultiGas (SO2/CO2, SO2/H2S, SO2/H2O) and direct sampling (SO2/HCl). For Kudryavy volcano the ratios were applied that have been measured by Taran et al. (1995) and Fischer et al. (1998) using direct sampling. Until now, for Kuril arc only the SO2 flux from Kudryavy was measured by the COSPEC technique in 1995 by Fischer et al. (1998) with an average SO2 flux of 75 t/d. Our data give for Kudryavy in October 2016 a value of 340 t/d. The total measured SO2 flux in 2015-2016 from the passively degassing volcanoes of the Kuril arc is near 1000 t/d. This value is an excellent agreement with the estimation made in Taran (2009) using a comparative plume height technique based on visual observations. Averaged fluxes (in ton/day) of mayor (Range of vent temperatures °C, SO2, CO2, H2O, HCl, total flux) components of volcanic emissions from Kurilian volcanoes in 2016: Ebeko - 97-490 °C, 100 (SO2), 81 (CO2), 1120 (H2O), 17 (HCl), 1319; Kuntomintar - 130-260 °C, 54 (SO2), 157 (CO2), 1064 (H2O), 8 (HCl), 1283; Pallas - 140-720 °C, 450 (SO2), 78 (CO2), 3800 (H2O), 120 (HCl), 4448; Kudryavy - 130-920 °C, 340 (SO2), 131 (CO2), 4445 (H2O), 85 (HCl), 5001. Total (± 20%): 930 (SO2), 450 (CO2), 10400 (H2O), 230 (HCl), 12050 (total flux). This work was supported by grant from the Russian Science Foundation # 15-17-20011. References: Taran et al. (1995) GCA, 59, 1741-1761; Fischer et al. (1998) EPSL, 160, 81-96; Taran (2009) GCA, 73, 1067-1091

Aura OMI observations of changes in SO2 and NO2 emissions at local, regional and global scales

NASA Astrophysics Data System (ADS)

Krotkov, N. A.; McLinden, C. A.; Li, C.; Lamsal, L. N.; Celarier, E. A.; Marchenko, S. V.; Swartz, W.; Bucsela, E. J.; Joiner, J.; Duncan, B. N.; Boersma, K. F.; Veefkind, P.; Levelt, P.; Fioletov, V.; Dickerson, R. R.; He, H.; Lu, Z.; Streets, D. G.

2015-12-01

Space-based pollution monitoring from current and planned satellite UV-Vis spectrometers play an increasingly important role in studies of tropospheric chemistry and also air quality applications to help mitigate anthropogenic and natural impacts on sensitive ecosystems, and human health. We present long-term changes in tropospheric SO2 and NO2 over some of the most polluted industrialized regions of the world observed by the Ozone Monitoring Instrument (OMI) onboard NASA's Aura satellite. Using OMI data, we identified about 400 SO2 "hot spots" and estimated emissions from them. In many regions emissions and their ambient pollution levels have decreased significantly, such as over eastern US, Europe and China. OMI observed about 50% reduction in SO2 and NO2 pollution over the North China plain in 2012-2014 that can be attributed to both government efforts to restrain emissions from the power and industrial sectors and the economic slowdown. While much smaller, India's SO2 and NO2 emissions from coal power plants and smelters are growing at a fast pace, increasing by about 200% and 50% from 2005 to 2014. Over Europe and the US OMI-observed trends agree well with those from available in situ measurements of surface concentrations, deposition and emissions data. However, for some regions (e.g., Mexico, Middle East) the emission inventories may be incomplete and OMI can provide emission estimates for missing sources, such as SO2 sources observed over the Persian Gulf. It is essential to continue long-term overlapping satellite data records of air quality with increased spatial and temporal resolution to resolve point pollution sources using oversampling technique. We discuss how Aura OMI pollution measurements and emission estimates will be continued with the US JPSS and European Sentinel series for the next 20 years and further enhanced by the addition of three geostationary UV-VIS instruments.

When will European countries exceed the 2°C temperature increase?

NASA Astrophysics Data System (ADS)

Caminade, C.; Morse, A. P.

2012-04-01

Climatologists all agree that an increase of 2°C at global scale could have serious socio-economic consequences for the future. The Cancun agreement in 2010 officially stated that "With a view to reducing global greenhouse gas emissions so as to hold the increase in global average temperature below 2 °C above pre- industrial levels . . . Parties should take urgent action to meet this long-term goal." Recent studies highlighted that this threshold is likely to be reached by 2060 at global scale if we follow the higher greenhouse gases emission scenarios. However, this threshold might be crossed earlier over lands, by 2040, for Europe, Asia, North Africa and Canada. This study aims to highlight when this threshold might be reached at the country level for members states of the European Union. A large ensemble of regional climate model simulations driven by the SRESA1B emission scenario carried out within the ENSEMBLES project framework for the European continent is employed to achieve such a task. Results corroborate that the European continent is likely to warm faster than the global average temperatures, with the multi-model ensemble mean crossing the 2°C threshold by 2045-2055. Regionally, Eastern Europe, Scandinavia and the Mediterranean basin are likely to cross that threshold earlier than northwestern/central Europe. As an example of these regional differences, Cyprus is likely to experience a 2°C increase during the mid 2040s while this might happen over Ireland during the late 21st century.

Assessment of shipping emissions on four ports of Portugal.

PubMed

Nunes, R A O; Alvim-Ferraz, M C M; Martins, F G; Sousa, S I V

2017-12-01

In the last few years, ship emissions have attracted growing attention in the scientific community. The main reason is the constant increase of marine emissions over the last twenty years due to the intensification of port traffic. Thus, this study aimed to evaluate ship emissions (PM 10 , PM 2.5 , NO x , SO 2 , CO, CO 2 , N 2 O CH 4 , NMVOC, and HC) through the activity-based methodology in four of the main ports of Portugal (Leixões, Setúbal, Sines and Viana do Castelo) during 2013 and 2014. The analysis was performed according to ship types (bulk carrier, container, general cargo, passenger, Ro-Ro cargo, tanker and others) and operational modes (manoeuvring, hotelling and during cruising). Results indicated that tankers were the largest emitters in two of the four analysed ports. Regarding cruising emissions, container ships were the largest emitters. . CO 2 , NO x and SO 2 estimated emissions represented more than 95% of the cruising and in-port emissions. Results were also compared with the total national emissions reported by the Portuguese Environment Agency, and if the in-port emissions estimated in the present study would have been taken into account to these totals, emissions of NO x and SO 2 would increase 15% and 24% in 2013 and 16% and 28% in 2014. Summing up ships seem to be an important source of air pollution, mainly regarding NO x and SO 2 . Copyright © 2017 Elsevier Ltd. All rights reserved.

Estimation of the local and long-range contributions to particulate matter levels using continuous measurements in a single urban background site

NASA Astrophysics Data System (ADS)

Diamantopoulou, Marianna; Skyllakou, Ksakousti; Pandis, Spyros N.

2016-06-01

The Particulate Matter Source Apportionment Technology (PSAT) algorithm is used together with PMCAMx, a regional chemical transport model, to develop a simple observation-based method (OBM) for the estimation of local and regional contributions of sources of primary and secondary pollutants in urban areas. We test the hypothesis that the minimum of the diurnal average concentration profile of the pollutant is a good estimate of the average contribution of long range transport levels. We use PMCAMx to generate "pseudo-observations" for four different European cities (Paris, London, Milan, and Dusseldorf) and PSAT to estimate the corresponding "true" local and regional contributions. The predictions of the proposed OBM are compared to the "true" values for different definitions of the source area. During winter, the estimates by the OBM for the local contributions to the concentrations of total PM2.5, primary pollutants, and sulfate are within 25% of the "true" contributions of the urban area sources. For secondary organic aerosol the OBM overestimates the importance of the local sources and it actually estimates the contributions of sources within 200 km from the receptor. During summer for primary pollutants and cities with low nearby emissions (ratio of emissions in an area extending 100 km from the city over local emissions lower than 10) the OBM estimates correspond to the city emissions within 25% or so. For cities with relatively high nearby emissions the OBM estimates correspond to emissions within 100 km from the receptor. For secondary PM2.5 components like sulfate and secondary organic aerosol the OBM's estimates correspond to sources within 200 km from the receptor. Finally, for total PM2.5 the OBM provides approximately the contribution of city emissions during the winter and the contribution of sources within 100 km from the receptor during the summer.

Characterization and source identification of fine particulate matter in urban Beijing during the 2015 Spring Festival.

PubMed

Ji, Dongsheng; Cui, Yang; Li, Liang; He, Jun; Wang, Lili; Zhang, Hongliang; Wang, Wan; Zhou, Luxi; Maenhaut, Willy; Wen, Tianxue; Wang, Yuesi

2018-07-01

The Spring Festival (SF) is the most important holiday in China for family reunion and tourism. During the 2015 SF an intensive observation campaign of air quality was conducted to study the impact of the anthropogenic activities and the dynamic characteristics of the sources. During the study period, pollution episodes frequently occurred with 12days exceeding the Chinese Ambient Air Quality Standards for 24-h average PM 2.5 (75μg/m 3 ), even 8days with exceeding 150μg/m 3 . The daily maximum PM 2.5 concentration reached 350μg/m 3 while the hourly minimum visibility was <0.8km. Three pollution episodes were selected for detailed analysis including chemical characterization and diurnal variation of the PM 2.5 and its chemical composition, and sources were identified using the Positive Matrix Factorization model. The first episode occurring before the SF was characterized by more formation of SO 4 2- and NO 3 - and high crustal enrichment factors for Ag, As, Cd, Cu, Hg, Pb, Se and Zn and seven categories of pollution sources were identified, whereby vehicle emission contributed 38% to the PM 2.5 . The second episode occurring during the SF was affected heavily by large-scale firework emissions, which led to a significant increase in SO 4 2- , Cl - , OC, K and Ba; these emissions were the largest contributor to the PM 2.5 accounting for 36%. During the third episode occurring after the SF, SO 4 2- , NO 3 - , NH 4 + and OC were the major constituents of the PM 2.5 and the secondary source was the dominant source with a contribution of 46%. The results provide a detailed understanding on the variation in occurrence, chemical composition and sources of the PM 2.5 as well as of the gaseous pollutants affected by the change in anthropogenic activities in Beijing throughout the SF. They highlight the need for limiting the firework emissions during China's most important traditional festival. Copyright © 2018 Elsevier B.V. All rights reserved.

Fractal Analysis of Air Pollutant Concentrations

NASA Astrophysics Data System (ADS)

Cortina-Januchs, M. G.; Barrón-Adame, J. M.; Vega-Corona, A.; Andina, D.

2010-05-01

Air pollution poses significant threats to human health and the environment throughout the developed and developing countries. This work focuses on fractal analysis of pollutant concentration in Salamanca, Mexico. The city of Salamanca has been catalogued as one of the most polluted cities in Mexico. The main causes of pollution in this city are fixed emission sources, such as chemical industry and electricity generation. Sulphur Dioxide (SO2) and Particulate Matter less than 10 micrometer in diameter (PM10) are the most important pollutants in this region. Air pollutant concentrations were investigated by applying the box counting method in time series obtained of the Automatic Environmental Monitoring Network (AEMN). One year of time series of hourly average concentrations were analyzed in order to characterize the temporal structures of SO2 and PM10.

Ammonia Emissions from agricultural fertilizer in China: From 1978 to 2008

NASA Astrophysics Data System (ADS)

Xu, P.

2015-12-01

The quantification of ammonia (NH3) emissions is essential to the more accurate quantification of atmospheric nitrogen deposition, improved air quality and the assessment of ammonia-related agricultural policy and climate mitigation strategies. Chinese agricultural fertilizer (CAF), which is widely used in China, is the nation's largest source of NH3 emissions. The quantity, geographic distribution and historical trends of these emissions remain largely uncertain. In this paper, a new CAF NH3 (CAF_NH3) emissions inventory has been compiled that exhibits the following improvements: (1) a 1 ´1 km gridded map on the county level was developed for 2008; (2) a combined bottom-up and top-down method was used for the local correction of emission factors (EFs) and parameters; (3) time trends were derived for 1978-2008 in which the spatial and temporal patterns and the uncertainties associated with the inventory were quantified; and (4) a sensitivity test was performed in which a province-level disaggregated map was compared with CAF_NH3 emissions for 2008. The total CAF_NH3 emissions for 2008 were 8.4 TgNH3·yr-1 (a 6.6-9.8 Tg interquartile range). From 1978 to 2008, annual NH3 emissions fluctuated with three peaks (1987, 1996 and 2005), and total emissions increased from 3.2 to 8.4 Tg at an annual rate of 3.0%. During the study period, the contribution of livestock manure spreading increased from 37.0% to 45.5% because of changing fertilization practices and the rapid increase in egg, milk and meat consumption. The average contribution of synthetic fertilizer, which has a positive effect on crop yields, was approximately 38.3% (minimum: 33.4%; maximum: 42.7%). With rapid urbanization causing a decline in the rural population, the contribution of the rural excrement sector varied widely between 20.3% and 8.5%. The average contributions of cake fertilizer and straw returning were approximately 3.8% and 4.5%, respectively, thus small and stable. Collectively, the CAF NH3 emissions reflect the nation's agricultural policy to a certain extent. An effective approach to decreasing PM2.5 concentrations in China would be to simultaneously decrease NOx, SO2 and NH3 emissions.

Optical Remote Sensing Measurements of Air Pollution in Mexico City During MCMA- 2006

NASA Astrophysics Data System (ADS)

Galle, B.; Mellqvist, J.; Johansson, M.; Rivera, C.; Samuelsson, J.; Zhang, Y.

2007-05-01

During March 2006 the Optical Remote sensing group at Chalmers University of Technology participated in the MCMA-2006 field campaign in Mexico City, performing measurements of air pollution using a set of different optical remote sensing instruments. This poster gives an overview of the techniques applied and results obtained. The techniques applied were: Solar Occultation FTIR and UV spectroscopy from fixed locations throughout the MCMA area, yielding total columns of CO, CH2O, SO2 and NO2. Long Path FTIR measurements from site T0 located in the north part of central Mexico City. With this instrument line-averaged concentration measurements of CO and CO2 was obtained in parallel with DOAS measurements performed by other partners. MAX-DOAS measurements from site T0, yielding total column and spatial distributions of SO2 and NO2. Mobile DOAS scattered Sunlight measurements of total columns of SO2 and NO2 in and around the MCMA area. Mobile and stationary DOAS measurements in the vicinity of Tula and Popocatépetl in order to quantify emissions from industry and volcano.

The Relationship Between Emissions and Economic Growth for SO2, CO2, and BC

NASA Astrophysics Data System (ADS)

Ru, M.; Shindell, D. T.; Tao, S.; Zhong, Q.; Seltzer, K.

2017-12-01

We characterize the relationship between per person emissions of SO2, CO2, and black carbon (BC) and income using a global country-level emission inventory. Pollutant emissions of SO2 and BC from the power, industry, and transportation sectors largely follow an Environmental Kuznets Curve (EKC) pattern with peak emissions at income levels between 10,000 and 100,000 USD per capita. However, for CO2, any estimated turnover income is extremely high and unlikely to be reached in the near future in power, industry, and transportation. Residential emissions show a negatively sloped linear relationship for BC, a small positive slope for CO2, and a fairly flat trajectory for SO2. For the EKC-like trajectories, "turning point" incomes for each sector and pollutant are related to technological advances and the effectiveness of emission controls. These results suggest that policy targeting technological advances and emission controls could change future pathways by affecting the "turning point" incomes. For the linear trajectories in the residential sector, we show that transitions from biomass fuel to coal in low-income countries and from coal to natural gas in middle and high-income countries, in concert with electrification levels, are the main factors governing slopes. Thus, the three pollutants show different income-emission trajectories based on the sum of the four major sectors, and the residential sector in particular has a unique relationship with income growth. As one of the first studies to analyze historical emission trajectories of BC, we find that BC differs from SO2 and CO2 because of its significantly earlier turnover in the power and industry sectors due to control policies. Total BC emissions trajectories follow a unique shape due to the combination of linearly decreasing residential emissions with EKC-like patterns in industry and transportation. We compare these trajectories to those in three Integrated Assessment Models (IAMs), GCAM, AIM, and MESSAGE, finding large differences for residential sector trajectories and earlier estimations of turnover incomes in the IAMs. Users of IAMs should consider the assumptions underlying projected emissions in light of this historical analysis, especially the apparently optimistic turnover incomes and residential sector emissions.

Estimating the volcanic emission rate and atmospheric lifetime of SO2 from space: a case study for Kīlauea volcano, Hawai'i

USGS Publications Warehouse

Beirle, Steffen; Hörmann, Christoph; Penning de Vries, Malouse; Dörner, Stefan; Kern, Christoph; Wagner, Thomas

2014-01-01

We present an analysis of SO2 column densities derived from GOME-2 satellite measurements for the Kīlauea volcano (Hawai`i) for 2007–2012. During a period of enhanced degassing activity in March–November 2008, monthly mean SO2 emission rates and effective SO2 lifetimes are determined simultaneously from the observed downwind plume evolution and meteorological wind fields, without further model input. Kīlauea is particularly suited for quantitative investigations from satellite observations owing to the absence of interfering sources, the clearly defined downwind plumes caused by steady trade winds, and generally low cloud fractions. For March–November 2008, the effective SO2 lifetime is 1–2 days, and Kīlauea SO2 emission rates are 9–21 kt day−1, which is about 3 times higher than initially reported from ground-based monitoring systems.

Major impact of volcanic gases on the chemical composition of precipitation in Iceland during the 2014-2015 Holuhraun eruption

NASA Astrophysics Data System (ADS)

Stefánsson, Andri; Stefánsson, Gerdur; Keller, Nicole S.; Barsotti, Sara; Sigurdsson, Árni; Thorláksdóttir, Svava Björk; Pfeffer, Melissa Anne; Eiríksdóttir, Eydís. S.; Jónasdóttir, Elín. Björk; von Löwis, Sibylle; Gíslason, Sigurdur R.

2017-02-01

The Holuhraun eruption in 2014-2015 was the largest in Iceland for more than 200 years. It resulted in emissions of large quantities of volcanic gases into the atmosphere (11 megaton (Mt) SO2, 0.1 Mt HCl, and 0.05 Mt HF). During the eruption the volcanic gases had major effects on F, SO4 and to a lesser extent Cl concentrations in precipitaxtion throughout Iceland, effects not observed in recent decades. The concentrations of F, Cl, and SO4 (n = 705) reached values of 444 µm 12,270 µm, and 17,324 µm during the eruption and were on average 20 times higher for F and SO4 and much lower for Cl compared to preeruption times. The concentrations of major cations (Si, Na, K, Ca, Mg, Al, and Fe) (n = 151) in the precipitation were taken as having originated from seawater spray and dissolution of rock dust and aerosol. Based on the mixing model developed here, it is demonstrated that the source of the enrichment of F and SO4 was indeed the volcanic gas emissions with >60-100 mol % of SO4 and F in the precipitation originated from volcanic gas, whereas the Cl originated mostly from seawater spray, making the volcanic gas input of Cl relatively less important than for F and SO4. The results showed that large volcanic eruptions can have major effects on atmospheric chemistry and impact the composition of precipitation.

Dynamic linkages between road transport energy consumption, economic growth, and environmental quality: evidence from Pakistan.

PubMed

Danish; Baloch, Muhammad Awais

2018-03-01

The focus of the present research work is to investigate the dynamic relationship between economic growth, road transport energy consumption, and environmental quality. To this end, we rely on time series data for the period 1971 to 2014 in the context of Pakistan. To use sulfur dioxide (SO 2 ) emission from transport sector as a new proxy for measuring environmental quality, the present work employs time series technique ARDL which allows energy consumption from the transport sector, urbanization, and road infrastructure to be knotted by symmetric relationships with SO 2 emissions and economic growth. From the statistical results, we confirm that road infrastructure boosts economic growth. Simultaneously, road infrastructure and urbanization hampers environmental quality and causes to accelerate emission of SO 2 in the atmosphere. Furthermore, economic growth has a diminishing negative impact on total SO 2 emission. Moreover, we did not find any proof of the expected role of transport energy consumption in SO 2 emission. The acquired results directed that care should be taken in the expansion of road infrastructure and green city policies and planning are required in the country.

Characterizing the Sources and Processing of Submicron Aerosols at a Coastal Site near Houston, TX, with a Specific Focus on the Impact of Regional Shipping Emissions

NASA Astrophysics Data System (ADS)

Schulze, B.; Wallace, H. W., IV; Bui, A.; Flynn, J. H., III; Erickson, M. H.; Griffin, R. J.

2017-12-01

The Texas Gulf Coast region historically has been influenced heavily by regional shipping emissions. However, the effects of the recent establishment of the North American Emissions Control Area (ECA) on aerosol properties in this region are presently unknown. In order to understand better the current sources and processing mechanisms influencing coastal aerosol near Houston, a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) was deployed for three weeks at a coastal location during May-June 2016. Total mass loadings of organic and inorganic non-refractory aerosol components during onshore flow periods were similar to those published before establishment of the regulations. Using estimated methanesulfonic acid (MSA) mass loadings and published biogenic MSA:non-sea-salt-sulfate (nss-SO4) ratios, we determined that over 70% of nss-SO4 over the Gulf was from anthropogenic sources, predominantly shipping emissions. Mass spectral analysis indicated that for periods with similar backward-trajectory-averaged meteorological conditions, air masses influenced by shipping emissions have an increased mass fraction of ions related to carboxylic acids and a significantly larger oxygen-to-carbon (O:C) ratio than air masses that stay within the ECA boundary, suggesting that shipping emissions impact marine organic aerosol (OA) oxidation state. Amine fragment mass loadings were positively correlated with anthropogenic nss-SO4 during onshore flow, implying anthropogenic-biogenic interaction in marine OA production. Five OA factors were resolved by positive matrix factorization, corresponding to a hydrocarbon-like OA, a semi-volatile OA, and three different oxygenated organic aerosols ranked by their O:C ratio (OOA-1, OOA-2, and OOA-3). OOA-1 constituted the majority of OA mass during a period likely influenced by aqueous-phase processing and may be linked to local glyoxal/methylglyoxal-related sources. OOA-2 was produced within the Houston urban region and was dominant during a multi-day period of air mass recirculation due to land-sea breeze effects. OOA-3, which was linked to shipping emissions, represented the majority of OA mass during onshore flow periods.

Well-to-refinery emissions and net-energy analysis of China's crude-oil supply

NASA Astrophysics Data System (ADS)

Masnadi, Mohammad S.; El-Houjeiri, Hassan M.; Schunack, Dominik; Li, Yunpo; Roberts, Samori O.; Przesmitzki, Steven; Brandt, Adam R.; Wang, Michael

2018-03-01

Oil is China's second-largest energy source, so it is essential to understand the country's greenhouse gas emissions from crude-oil production. Chinese crude supply is sourced from numerous major global petroleum producers. Here, we use a per-barrel well-to-refinery life-cycle analysis model with data derived from hundreds of public and commercial sources to model the Chinese crude mix and the upstream carbon intensities and energetic productivity of China's crude supply. We generate a carbon-denominated supply curve representing Chinese crude-oil supply from 146 oilfields in 20 countries. The selected fields are estimated to emit between 1.5 and 46.9 g CO2eq MJ-1 of oil, with volume-weighted average emissions of 8.4 g CO2eq MJ-1. These estimates are higher than some existing databases, illustrating the importance of bottom-up models to support life-cycle analysis databases. This study provides quantitative insight into China's energy policy and the economic and environmental implications of China's oil consumption.

Boiler briquette coal versus raw coal: Part I--Stack gas emissions.

PubMed

Ge, S; Bai, Z; Liu, W; Zhu, T; Wang, T; Qing, S; Zhang, J

2001-04-01

Stack gas emissions were characterized for a steam-generating boiler commonly used in China. The boiler was tested when fired with a newly formulated boiler briquette coal (BB-coal) and when fired with conventional raw coal (R-coal). The stack gas emissions were analyzed to determine emission rates and emission factors and to develop chemical source profiles. A dilution source sampling system was used to collect PM on both Teflon membrane filters and quartz fiber filters. The Teflon filters were analyzed gravimetrically for PM10 and PM2.5 mass concentrations and by X-ray fluorescence (XRF) for trace elements. The quartz fiber filters were analyzed for organic carbon (OC) and elemental carbon (EC) using a thermal/optical reflectance technique. Sulfur dioxide was measured using the standard wet chemistry method. Carbon monoxide was measured using an Orsat combustion analyzer. The emission rates of the R-coal combustion (in kg/hr), determined using the measured stack gas concentrations and the stack gas emission rates, were 0.74 for PM10, 0.38 for PM2.5, 20.7 for SO2, and 6.8 for CO, while those of the BB-coal combustion were 0.95 for PM10, 0.30 for PM2.5, 7.5 for SO2, and 5.3 for CO. The fuel-mass-based emission factors (in g/kg) of the R-coal, determined using the emission rates and the fuel burn rates, were 1.68 for PM10, 0.87 for PM2.5, 46.7 for SO2, and 15 for CO, while those of the BB-coal were 2.51 for PM10, 0.79 for PM2.5, 19.9 for SO2, and 14 for CO. The task-based emission factors (in g/ton steam generated) of the R-coal, determined using the fuel-mass-based emission factors and the coal/steam conversion factors, were 0.23 for PM10, 0.12 for PM2.5, 6.4 for SO2, and 2.0 for CO, while those of the BB-coal were 0.30 for PM10, 0.094 for PM2.5, 2.4 for SO2, and 1.7 for CO. PM10 and PM2.5 elemental compositions are also presented for both types of coal tested in the study.

[Estimation of average traffic emission factor based on synchronized incremental traffic flow and air pollutant concentration].

PubMed

Li, Run-Kui; Zhao, Tong; Li, Zhi-Peng; Ding, Wen-Jun; Cui, Xiao-Yong; Xu, Qun; Song, Xian-Feng

2014-04-01

On-road vehicle emissions have become the main source of urban air pollution and attracted broad attentions. Vehicle emission factor is a basic parameter to reflect the status of vehicle emissions, but the measured emission factor is difficult to obtain, and the simulated emission factor is not localized in China. Based on the synchronized increments of traffic flow and concentration of air pollutants in the morning rush hour period, while meteorological condition and background air pollution concentration retain relatively stable, the relationship between the increase of traffic and the increase of air pollution concentration close to a road is established. Infinite line source Gaussian dispersion model was transformed for the inversion of average vehicle emission factors. A case study was conducted on a main road in Beijing. Traffic flow, meteorological data and carbon monoxide (CO) concentration were collected to estimate average vehicle emission factors of CO. The results were compared with simulated emission factors of COPERT4 model. Results showed that the average emission factors estimated by the proposed approach and COPERT4 in August were 2.0 g x km(-1) and 1.2 g x km(-1), respectively, and in December were 5.5 g x km(-1) and 5.2 g x km(-1), respectively. The emission factors from the proposed approach and COPERT4 showed close values and similar seasonal trends. The proposed method for average emission factor estimation eliminates the disturbance of background concentrations and potentially provides real-time access to vehicle fleet emission factors.

Analyze Experiment For Vigas and Pertamax to Performance and Exhaust Gas Emission for Gasoline Motor 2000cc

NASA Astrophysics Data System (ADS)

As'adi, Muhamad; Chrisna Ayu Dwiharpini Tupan, Diachirta

2018-02-01

The purpose and target for this analyze experiment is we get the performance variabel from gasoline motor which used LGV for fuel and Pertamax, so can give knowledge to community if LGV can be using LGV for fuel to transportation industry and more economic. We used experiment method of engine gasoline motor with 2000 cc which is LGV and Pertamax for fuel. The experiment with static experiment tes above Dyno Test. The result is engine perform to subscribe Torque, power, fuel consumption. Beside the static test we did the Exhaust Steam Emission. The result is the used LGV with the commercial brand Vigas can increase the maximum Engine Power 20.86% and Average Power 14.1%, the maximum torque for Motor which is use LGV as fuel is smaller than Motor with Pertamax, the decrease is 0.94%.Using Vigas in Motor can increase the mileage until 6.9% compare with the Motor with pertamax.Air Fuel Ratio (AFR) for both of the fuels still below the standard, so still happen waste of fuel, specially in low compression.Using Vigas can reduce the Exhaust Steam Emission especially CO2

Engine Test and Measurements

NASA Technical Reports Server (NTRS)

Wey, Chown Chou

1999-01-01

Although the importance of aerosols and their precursors are now well recognized, the characterization of current subsonic engines for these emissions is far from complete. Furthermore, since the relationship of engine operating parameters to aerosol emissions is not known, extrapolation to untested and unbuilt engines necessarily remains highly uncertain. 1997 NASA LaRC engine test, as well as the parallel 1997 NASA LaRC flight measurement, attempts to address both issues by expanding measurements of aerosols and aerosol precursors with fuels containing different levels of fuel sulfur content. The specific objective of the 1997 engine test is to obtain a database of sulfur oxides emissions as well as the non-volatile particulate emission properties as a function of fuel sulfur and engine operating conditions. Four diagnostic systems, extractive and non-intrusive (optical), will be assembled for the gaseous and particulate emissions characterization measurements study. NASA is responsible for the extractive gaseous emissions measurement system which contains an array of analyzers dedicated to examining the concentrations of specific gases (NO, NO(x), CO, CO2, O2, THC, SO2) and the smoke number. University of Missouri-Rolla uses the Mobile Aerosol Sampling System to measure aerosol/particulate total concentration, size distribution, volatility and hydration property. Air Force Research Laboratory uses the Chemical Ionization Mass Spectrometer to measure SO2, SO3/H2SO4, and HN03 Aerodyne Research, Inc. uses Infrared Tunable Diode Laser system to measure SO2, SO3, NO, H2O, and CO2.

Tailoring Meridional and Seasonal Radiative Forcing by Sulfate Aerosol Solar Geoengineering

NASA Astrophysics Data System (ADS)

Dai, Z.; Weisenstein, D. K.; Keith, D. W.

2018-01-01

We study the possibility of designing solar radiation management schemes to achieve a desired meridional radiative forcing (RF) profile using a two-dimensional chemistry-transport-aerosol model. Varying SO2 or H2SO4 injection latitude, altitude, and season, we compute RF response functions for a broad range of possible injection schemes, finding that linear combinations of these injection cases can roughly achieve RF profiles that have been proposed to accomplish various climate objectives. Globally averaged RF normalized by the sulfur injection rate (the radiative efficacy) is largest for injections at high altitudes, near the equator, and using emission of H2SO4 vapor into an aircraft wake to produce accumulation-mode particles. There is a trade-off between radiative efficacy and control as temporal and spatial control is best achieved with injections at lower altitudes and higher latitudes. These results may inform studies using more realistic models that couple aerosol microphysics, chemistry, and stratospheric dynamics.

Global and Regional Radiative Forcing from 20 Reductions in BC, OC and SO4 an HTAP2 Multi-Model Study

NASA Technical Reports Server (NTRS)

Stjern, Camilla Weum; Samset, Bjorn Hallvard; Myhre, Gunnar; Bian, Huisheng; Chin, Mian; Davila, Yanko; Dentener, Frank; Emmons, Louisa; Flemming, Johannes; Haslerud, Amund Sovde;

Boiler Briquette Coal versus Raw Coal: Part I-Stack Gas Emissions.

PubMed

Ge, Su; Bai, Zhipeng; Liu, Weili; Zhu, Tan; Wang, Tongjian; Qing, Sheng; Zhang, Junfeng

2001-04-01

Stack gas emissions were characterized for a steam-generating boiler commonly used in China. The boiler was tested when fired with a newly formulated boiler briquette coal (BB-coal) and when fired with conventional raw coal (R-coal). The stack gas emissions were analyzed to determine emission rates and emission factors and to develop chemical source profiles. A dilution source sampling system was used to collect PM on both Teflon membrane filters and quartz fiber filters. The Teflon filters were analyzed gravimetrically for PM 10 and PM 2.5 mass concentrations and by X-ray fluorescence (XRF) for trace elements. The quartz fiber filters were analyzed for organic carbon (OC) and elemental carbon (EC) using a thermal/optical reflectance technique. Sulfur dioxide was measured using the standard wet chemistry method. Carbon monoxide was measured using an Orsat combustion analyzer. The emission rates of the R-coal combustion (in kg/hr), determined using the measured stack gas concentrations and the stack gas emission rates, were 0.74 for PM 10 , 0.38 for PM 25 , 20.7 for SO 2 , and 6.8 for CO, while those of the BB-coal combustion were 0.95 for PM 10 , 0.30 for PM 2 5 , 7.5 for SO 2 , and 5.3 for CO. The fuel-mass-based emission factors (in g/kg) of the R-coal, determined using the emission rates and the fuel burn rates, were 1.68 for PM 10 , 0.87 for PM 25 , 46.7 for SO 2 , and 15 for CO, while those of the BB-coal were 2.51 for PM 10 , 0.79 for PM 2.5 , 19.9 for SO 2 , and 14 for CO. The task-based emission factors (in g/ton steam generated) of the R-coal, determined using the fuel-mass-based emission factors and the coal/ steam conversion factors, were 0.23 for PM 10 , 0.12 for PM 2.5 , 6.4 for SO 2 , and 2.0 for CO, while those of the BB-coal were 0.30 for PM 10 , 0.094 for PM 2.5 , 2.4 for SO 2 , and 1.7 for CO. PM 10 and PM 2.5 elemental compositions are also presented for both types of coal tested in the study.

Analysis of Strategies for Multiple Emissions from Electric Power SO2, NOX, CO2, Mercury and RPS

EIA Publications

2001-01-01

At the request of the Subcommittee, the Energy Information Administration prepared an initial report that focused on the impacts of reducing power sector NOx, SO2, and CO2 emissions. The current report extends the earlier analysis to add the impacts of reducing power sector mercury emissions and introducing renewable portfolio standard (RPS) requirements.

Volcanogenic SO2, a natural pollutant: Measurements, modeling and hazard assessment at Vulcano Island (Aeolian Archipelago, Italy).

PubMed

Granieri, Domenico; Vita, Fabio; Inguaggiato, Salvatore

2017-12-01

Sulfur dioxide (SO 2 ) is a major component of magmatic gas discharges. Once emitted in the atmosphere it can affect the air and land environment at different spatial and temporal scales, with harmful effects on human health and plant communities. We used a dense dataset of continuous SO 2 flux and meteorological measurements collected at Vulcano over an 8-year period spanning from May 2008 to February 2016 to model air SO 2 concentrations over the island. To this end, we adopted the DISGAS (DISpersion of GAS) numerical code coupled with the Diagnostic Wind Model (DWM). SO 2 concentrations in air were determined for three different SO 2 emission rates: a reference SO 2 flux of ∼18 t/d (the median of more than 800 measurements), an enhanced SO 2 flux of 40 t/d (average of all measurements plus 1 σ), and a maximum SO 2 flux of 106 t/d (maximum value measured in the investigated period). Maximum SO 2 concentrations in air were estimated at the crater, near the high-T fumarole field that is the source of the gas, and ranged from 2000 ppb to ∼24,000 ppb for the reference flux, from 2000 ppb to 51,000 ppb for the enhanced flux and from 5000 ppb to 136,000 ppb for the maximum flux, with peak values in limited areas at the bottom of the crater. These concentrations pose a hazard for people visiting the crater, for sensitive individuals in particular. Based on estimated SO 2 concentrations in air, we also consider the phytotoxic effects of SO 2 on local vegetation. Copyright © 2017 Elsevier Ltd. All rights reserved.

Seasonal variations in elemental carbon aerosol, carbon monoxide and sulfur dioxide: Implications for sources

NASA Astrophysics Data System (ADS)

Antony Chen, L.-W.; Doddridge, Bruce G.; Dickerson, Russell R.; Chow, Judith C.; Mueller, Peter K.; Quinn, John; Butler, William A.

As part of Maryland Aerosol Research and CHaracterization (MARCH-Atlantic) study, measurements of 24-hr average elemental carbon (EC) aerosol concentration were made at Fort Meade, Maryland, USA, a suburban site within the Baltimore-Washington corridor during July 1999, October 1999, January 2000, April 2000 and July 2000. Carbon monoxide (CO) and sulfur dioxide (SO2) were also measured nearly continuously over the period. Tight correlation between EC and CO in every month suggests common or proximate sources, likely traffic emissions. The EC versus CO slope varies in different seasons and generally increases with ambient temperature. The temperature dependence of EC/CO ratios suggests that EC source strength peaks in summer. By using the well established emission inventory for CO, and EC/CO ratio found in this study, EC emission over North America is estimated at 0.31±0.12 Tg yr-1, on the low end but in reasonable agreement with prior inventories based on emission factors and fuel consumption.

Seasonal variations in elemental carbon aerosol, carbon monoxide and sulfur dioxide: Implications for sources

NASA Astrophysics Data System (ADS)

Chen, L.-W. Antony; Doddridge, Bruce G.; Dickerson, Russell R.; Chow, Judith C.; Mueller, Peter K.; Quinn, John; Butler, William A.

2001-05-01

As part of Maryland Aerosol Research and CHaracterization (MARCH-Atlantic) study, measurements of 24-hr average elemental carbon (EC) aerosol concentration were made at Fort Meade, Maryland, USA, a suburban site within the Baltimore-Washington corridor during July 1999, October 1999, January 2000, April 2000 and July 2000. Carbon monoxide (CO) and sulfur dioxide (SO2) were also measured nearly continuously over the period. Tight correlation between EC and CO in every month suggests common or proximate sources, likely traffic emissions. The EC versus CO slope varies in different seasons and generally increases with ambient temperature. The temperature dependence of EC/CO ratios suggests that EC source strength peaks in summer. By using the well established emission inventory for CO, and EC/CO ratio found in this study, EC emission over North America is estimated at 0.31+/-0.12Tgyr-1, on the low end but in reasonable agreement with prior inventories based on emission factors and fuel consumption.

Evaluation of an 18-year CMAQ simulation: Seasonal variations and long-term temporal changes in sulfate and nitrate

NASA Astrophysics Data System (ADS)

Civerolo, Kevin; Hogrefe, Christian; Zalewsky, Eric; Hao, Winston; Sistla, Gopal; Lynn, Barry; Rosenzweig, Cynthia; Kinney, Patrick L.

2010-10-01

This paper compares spatial and seasonal variations and temporal trends in modeled and measured concentrations of sulfur and nitrogen compounds in wet and dry deposition over an 18-year period (1988-2005) over a portion of the northeastern United States. Substantial emissions reduction programs occurred over this time period, including Title IV of the Clean Air Act Amendments of 1990 which primarily resulted in large decreases in sulfur dioxide (SO 2) emissions by 1995, and nitrogen oxide (NO x) trading programs which resulted in large decreases in warm season NO x emissions by 2004. Additionally, NO x emissions from mobile sources declined more gradually over this period. The results presented here illustrate the use of both operational and dynamic model evaluation and suggest that the modeling system largely captures the seasonal and long-term changes in sulfur compounds. The modeling system generally captures the long-term trends in nitrogen compounds, but does not reproduce the average seasonal variation or spatial patterns in nitrate.

Total sulfur dioxide emissions and pre-eruption vapor-saturated magma at Mount St. Helens, 1980-88

NASA Astrophysics Data System (ADS)

Gerlach, T. M.; McGee, K. A.

1994-12-01

SO2 from explosive volcanism can cause significant climatic and atmospheric impacts, but the source of the sulfur is controversial. Total ozone mapping spectrometer (TOMS), correlation spectrometer (COSPEC), and ash leachate data for Mount St. Helens from the time of the climactic eruption on 18 May 1980 to the final stages of non-explosive degassing in 1988 give a total SO2 emission of 2 Mt. COSPEC data show a sharp drop in emission rate that was apparently controlled by a decreasing rate of magma supply. A total SO2 emission of only 0.08 Mt is estimated from melt inclusion data and the conventional assumption that the main sulfur source was pre-eruption melt; commonly invoked sources of 'excess sulfur' (anhydrite decomposition, basaltic magma, and degassing of non-erupted magma) are unlikely in this case. Thus melt inclusions may significantly underestimate SO2 emissions and impacts of explosive volcanism on climate and the atmosphere. Measured CO2 emissions, together with the H2O content of melt inclusions and experimental solubility data, indicate the Mount St. Helens dacite was vapor-saturated at depth prior to ascent and suggest that a vapor phase was the main source of sulfur for the 2-Mt of SO2. A vapor source is consistent with experimental studies on the Mount St. Helens dacite and removes the need for a much debated shallow magma body.

Changes in the chemistry of precipitation in the United States, 1981-1998

USGS Publications Warehouse

Nilles, M.A.; Conley, B.E.

2001-01-01

Regulatory measures in the United States, such as Title IV of the Clean Air Act Amendments of 1990, have primarily restricted sulfur dioxide emissions as a way to control acidic deposition. These restrictions, coupled with increasing concentrations of NH4+ in wet deposition in some regions of the U.S. and continued high emissions of nitrogen oxides have generated a significant shift in the chemistry of precipitation as measured at National Atmospheric Deposition Program/National Trends Network sites. Trends in precipitation chemistry at NADP/NTN sites were evaluated for statistical significance for the period 1981-1998 using a Seasonal Mann-Kendall Test, a robust non-parametric test for detection of monotonic trends. SO42- declines were detected at 100 of the 147 sites examined while no sites exhibited increasing SO42- trends. On average, SO42- declined 35% over the period 1981-1998 with downward SO42- trends being most pronounced in the northeastern United States. In contrast, no consistent trends in NO3- concentrations were observed in precipitation in any major region of the United States. Although the majority of sites did not exhibit significant trends in NH4+ concentration, 30 sites exhibited upward trends. For Ca2+ concentration in precipitation, 64 sites exhibited a significant decreasing trend and no sites exhibited an upward trend.

Cost-effectiveness of reducing sulfur emissions from ships.

PubMed

Wang, Chengfeng; Corbett, James J; Winebrake, James J

2007-12-15

We model cost-effectiveness of control strategies for reducing SO2 emissions from U.S. foreign commerce ships traveling in existing European or hypothetical U.S. West Coast SO(x) Emission Control Areas (SECAs) under international maritime regulations. Variation among marginal costs of control for individual ships choosing between fuel-switching and aftertreatment reveals cost-saving potential of economic incentive instruments. Compared to regulations prescribing low sulfur fuels, a performance-based policy can save up to $260 million for these ships with 80% more emission reductions than required because least-cost options on some individual ships outperform standards. Optimal simulation of a market-based SO2 control policy for approximately 4,700 U.S. foreign commerce ships traveling in the SECAs in 2002 shows that SECA emissions control targets can be achieved by scrubbing exhaust gas of one out of ten ships with annual savings up to $480 million over performance-based policy. A market-based policy could save the fleet approximately $63 million annually under our best-estimate scenario. Spatial evaluation of ship emissions reductions shows that market-based instruments can reduce more SO2 closer to land while being more cost-effective for the fleet. Results suggest that combining performance requirements with market-based instruments can most effectively control SO2 emissions from ships.

Sulfur emission from Victorian brown coal under pyrolysis, oxy-fuel combustion and gasification conditions.

PubMed

Chen, Luguang; Bhattacharya, Sankar

2013-02-05

Sulfur emission from a Victorian brown coal was quantitatively determined through controlled experiments in a continuously fed drop-tube furnace under three different atmospheres: pyrolysis, oxy-fuel combustion, and carbon dioxide gasification conditions. The species measured were H(2)S, SO(2), COS, CS(2), and more importantly SO(3). The temperature (873-1273 K) and gas environment effects on the sulfur species emission were investigated. The effect of residence time on the emission of those species was also assessed under oxy-fuel condition. The emission of the sulfur species depended on the reaction environment. H(2)S, SO(2), and CS(2) are the major species during pyrolysis, oxy-fuel, and gasification. Up to 10% of coal sulfur was found to be converted to SO(3) under oxy-fuel combustion, whereas SO(3) was undetectable during pyrolysis and gasification. The trend of the experimental results was qualitatively matched by thermodynamic predictions. The residence time had little effect on the release of those species. The release of sulfur oxides, in particular both SO(2) and SO(3), is considerably high during oxy-fuel combustion even though the sulfur content in Morwell coal is only 0.80%. Therefore, for Morwell coal utilization during oxy-fuel combustion, additional sulfur removal, or polishing systems will be required in order to avoid corrosion in the boiler and in the CO(2) separation units of the CO(2) capture systems.

Emissions of HC, CO, NOx, CO2, and SO2 from civil aviation in China in 2010

NASA Astrophysics Data System (ADS)

Fan, Weiyi; Sun, Yifei; Zhu, Tianle; Wen, Yi

2012-09-01

Civil aviation in China has developed rapidly in recent years, and the effects of civil aviation emissions on the atmospheric environment should not be neglected. The establishment of emission inventories of atmospheric pollutants from civil aviation contributes to related policy formation and pollution control. According to the 2010's China flight schedules, aircraft/engine combination information and revised emission indices from the International Civil Aviation Organization emission data bank based on meteorological data, the fuel consumption and HC, CO, NOx, CO2, SO2 emissions from domestic flights of civil aviation in China (excluding Taiwan Province) in 2010 are estimated in this paper. The results show that fuel consumption in 2010 on domestic flights in China is 12.12 million tons (metric tons), HC, CO, NOx, CO2 and SO2 emissions are 4600 tons, 39,700 tons, 154,100 tons, 38.21 million tons and 9700 tons, respectively. The fuel consumption and pollutant emissions of China Southern Airline are responsible for the largest national proportion of each, accounting for 27% and 25-28%, respectively.

Recent Large Reduction in Sulfur Dioxide Emissions from Chinese Power Plants Observed by the Ozone Monitoring Instrument

NASA Technical Reports Server (NTRS)

Li, Can; Zhang, Qiang; Krotkov, Nickolay A.; Streets, David G.; He, Kebin; Tsay, Si-Chee; Gleason, James F.

2010-01-01

The Ozone Monitoring Instrument (OMI) aboard NASA's Aura satellite observed substantial increases in total column SO2 and tropospheric column NO2 from 2005 to 2007, over several areas in northern China where large coal-fired power plants were built during this period. The OMI-observed SO2/NO2 ratio is consistent with the SO2/ NO2, emissions estimated from a bottom-up approach. In 2008 over the same areas, OMI detected little change in NO2, suggesting steady electricity output from the power plants. However, dramatic reductions of S0 2 emissions were observed by OMI at the same time. These reductions confirm the effectiveness of the flue-gas desulfurization (FGD) devices in reducing S02 emissions, which likely became operational between 2007 and 2008. This study further demonstrates that the satellite sensors can monitor and characterize anthropogenic emissions from large point sources.

A review of current knowledge concerning PM2. 5 chemical composition, aerosol optical properties and their relationships across China

NASA Astrophysics Data System (ADS)

Tao, Jun; Zhang, Leiming; Cao, Junji; Zhang, Renjian

2017-08-01

To obtain a thorough knowledge of PM2. 5 chemical composition and its impact on aerosol optical properties across China, existing field studies conducted after the year 2000 are reviewed and summarized in terms of geographical, interannual and seasonal distributions. Annual PM2. 5 was up to 6 times the National Ambient Air Quality Standards (NAAQS) in some megacities in northern China. Annual PM2. 5 was higher in northern than southern cities, and higher in inland than coastal cities. In a few cities with data longer than a decade, PM2. 5 showed a slight decrease only in the second half of the past decade, while carbonaceous aerosols decreased, sulfate (SO42-) and ammonium (NH4+) remained at high levels, and nitrate (NO3-) increased. The highest seasonal averages of PM2. 5 and its major chemical components were typically observed in the cold seasons. Annual average contributions of secondary inorganic aerosols to PM2. 5 ranged from 25 to 48 %, and those of carbonaceous aerosols ranged from 23 to 47 %, both with higher contributions in southern regions due to the frequent dust events in northern China. Source apportionment analysis identified secondary inorganic aerosols, coal combustion and traffic emission as the top three source factors contributing to PM2. 5 mass in most Chinese cities, and the sum of these three source factors explained 44 to 82 % of PM2. 5 mass on annual average across China. Biomass emission in most cities, industrial emission in industrial cities, dust emission in northern cities and ship emission in coastal cities are other major source factors, each of which contributed 7-27 % to PM2. 5 mass in applicable cities. The geographical pattern of scattering coefficient (bsp) was similar to that of PM2. 5, and that of aerosol absorption coefficient (bap) was determined by elemental carbon (EC) mass concentration and its coating. bsp in ambient condition of relative humidity (RH) = 80 % can be amplified by about 1.8 times that under dry conditions. Secondary inorganic aerosols accounted for about 60 % of aerosol extinction coefficient (bext) at RH greater than 70 %. The mass scattering efficiency (MSE) of PM2. 5 ranged from 3.0 to 5.0 m2 g-1 for aerosols produced from anthropogenic emissions and from 0.7 to 1.0 m2 g-1 for natural dust aerosols. The mass absorption efficiency (MAE) of EC ranged from 6.5 to 12.4 m2 g-1 in urban environments, but the MAE of water-soluble organic carbon was only 0.05 to 0.11 m2 g-1. Historical emission control policies in China and their effectiveness were discussed based on available chemically resolved PM2. 5 data, which provides the much needed knowledge for guiding future studies and emissions policies.

Detecting volcanic SO2 emissions with the Infrared Atmospheric Sounding Interferometer

NASA Astrophysics Data System (ADS)

Taylor, Isabelle; Carboni, Elisa; Mather, Tamsin; Grainger, Don

2017-04-01

Sulphur dioxide (SO2) emissions are one of the many hazards associated with volcanic activity. Close to the volcano they have negative impacts on human and animal health and affect the environment. Further afield they present a hazard to aviation (as well as being a proxy for volcanic ash) and can cause global changes to climate. These are all good reasons for monitoring gas emissions at volcanoes and this monitoring can also provide insight into volcanic, magmatic and geothermal processes. Advances in satellite technology mean that it is now possible to monitor these emissions from space. The Infrared Atmospheric Sounding Interferometer (IASI) on board the European Space Agency's MetOp satellites is commonly used, alongside other satellite products, for detecting SO2 emissions across the globe. A fast linear retrieval developed in Oxford separates the signal of the target species (SO2) from the spectral background by representing background variability (determined from pixels containing no SO2) in a background covariance matrix. SO2 contaminated pixels can be distinguished from this quickly, facilitating the use of this algorithm for near real time monitoring and for scanning of large datasets for signals to explore further with a full retrieval. In this study, the retrieval has been applied across the globe to identify volcanic emissions. Elevated signals are identified at numerous volcanoes including both explosive and passive emissions, which match reports of activity from other sources. Elevated signals are also evident from anthropogenic activity. These results imply that this tool could be successfully used to identify and monitor activity across the globe.

A Multimodel Assessment of the Influence of Regional Anthropogenic Emission Reductions on Aerosol Direct Radiative Forcing and the Role of Intercontinental Transport

NASA Technical Reports Server (NTRS)

Yu, Hongbin; Chin, Mian; West, Jason; Atherton, Cynthia S.; Bellouin, Nicolas; Bergmann, Dan; Bey, Isabelle; Bian, Huisheng; Diehl, Thomas; Forberth, Gerd;

Air Quality Co-benefits of Energy Policy in China: Evidence from Iron & Steel and Cement Industries

NASA Astrophysics Data System (ADS)

Qiu, M.; Weng, Y.; Selin, N. E.; Karplus, V. J.; Cao, J.

2017-12-01

Previous literature has calculated large air quality co-benefits from policies that reduce CO2 emissions and increase energy efficiency. These (often prospective) studies rely on assumptions about how air pollutant emissions respond to energy use changes. Using a unique firm-level data set from China, we examine how a real-world energy efficiency policy affected SO2 emissions, estimate its actual effects on atmospheric PM2.5, and compare to ex ante theoretical estimates. During the 11th Five-year plan (2006-2010), the Chinese government implemented policies directing large energy-consuming firms to reduce their energy consumption per unit of economic output. The Top 1000 Enterprises Program (T1000P) set binding energy intensity targets for China's 1000 highest energy-consuming firms. This program is widely considered a policy success, as 92% of firms met their energy intensity target. Focusing on the cement and iron and steel industry, we examine how T1000P (and related provincial policies) affected firms' SO2 emissions and coal consumption from 2005 to 2008. By comparing T1000P firms with similar firms not subject to the policy, we find that T1000P had a very limited incremental effect on energy use or on air quality co-benefits. Compared to firms not subject to the policy, T1000P firms had 14.7% (cement) and 24.0% (iron & steel) lower reductions in SO2 emission per unit energy use. We also observe large, heterogeneous changes in emission factors (defined as SO2 emissions per unit of coal consumption) among all firms during this period. In comparison to co-benefits estimates that assume constant emission factors, SO2 emissions from T1000P firms in the post-policy period are 23.2% (iron and steel) and 40.2% (cement) lower, but spatially heterogeneous, with some regions experiencing increases. Using the GEOS-Chem model, we estimate the air quality co-benefits of the T1000P policy with realized SO2 emissions changes and compare them with two theoretical estimations of co-benefits: one assuming that emission factors stay the same, and one in which emissions factors decline exponentially with time. We conclude that heterogeneous technology and behavioral responses of covered firms can significantly affect the real-world air quality co-benefits of energy intensity policies delivered by a fixed policy design.

Speed Profiles for Improvement of Maritime Emission Estimation.

PubMed

Yau, Pui Shan; Lee, Shun-Cheng; Ho, Kin Fai

2012-12-01

Maritime emissions play an important role in anthropogenic emissions, particularly for cities with busy ports such as Hong Kong. Ship emissions are strongly dependent on vessel speed, and thus accurate vessel speed is essential for maritime emission studies. In this study, we determined minute-by-minute high-resolution speed profiles of container ships on four major routes in Hong Kong waters using Automatic Identification System (AIS). The activity-based ship emissions of NO(x), CO, HC, CO(2), SO(2), and PM(10) were estimated using derived vessel speed profiles, and results were compared with those using the speed limits of control zones. Estimation using speed limits resulted in up to twofold overestimation of ship emissions. Compared with emissions estimated using the speed limits of control zones, emissions estimated using vessel speed profiles could provide results with up to 88% higher accuracy. Uncertainty analysis and sensitivity analysis of the model demonstrated the significance of improvement of vessel speed resolution. From spatial analysis, it is revealed that SO(2) and PM(10) emissions during maneuvering within 1 nautical mile from port were the highest. They contributed 7%-22% of SO(2) emissions and 8%-17% of PM(10) emissions of the entire voyage in Hong Kong.

Benefits of China's efforts in gaseous pollutant control indicated by the bottom-up emissions and satellite observations 2000-2014

NASA Astrophysics Data System (ADS)

Xia, Yinmin; Zhao, Yu; Nielsen, Chris P.

2016-07-01

To evaluate the effectiveness of national air pollution control policies, the emissions of SO2, NOX, CO and CO2 in China are estimated using bottom-up methods for the most recent 15-year period (2000-2014). Vertical column densities (VCDs) from satellite observations are used to test the temporal and spatial patterns of emissions and to explore the ambient levels of gaseous pollutants across the country. The inter-annual trends in emissions and VCDs match well except for SO2. Such comparison is improved with an optimistic assumption in emission estimation that the emission standards for given industrial sources issued after 2010 have been fully enforced. Underestimation of emission abatement and enhanced atmospheric oxidization likely contribute to the discrepancy between SO2 emissions and VCDs. As suggested by VCDs and emissions estimated under the assumption of full implementation of emission standards, the control of SO2 in the 12th Five-Year Plan period (12th FYP, 2011-2015) is estimated to be more effective than that in the 11th FYP period (2006-2010), attributed to improved use of flue gas desulfurization in the power sector and implementation of new emission standards in key industrial sources. The opposite was true for CO, as energy efficiency improved more significantly from 2005 to 2010 due to closures of small industrial plants. Iron & steel production is estimated to have had particularly strong influence on temporal and spatial patterns of CO. In contrast to fast growth before 2011 driven by increased coal consumption and limited controls, NOX emissions decreased from 2011 to 2014 due to the penetration of selective catalytic/non-catalytic reduction systems in the power sector. This led to reduced NO2 VCDs, particularly in relatively highly polluted areas such as the eastern China and Pearl River Delta regions. In developed areas, transportation is playing an increasingly important role in air pollution, as suggested by the increased ratio of NO2 to SO2 VCDs. For air quality in mega cities, the inter-annual trends in emissions and VCDs indicate that surrounding areas are more influential in NO2 level for Beijing than those for Shanghai.

Significant geographic gradients in particulate sulfate over Japan determined from multiple-site measurements and a chemical transport model: Impacts of transboundary pollution from the Asian continent

NASA Astrophysics Data System (ADS)

Aikawa, Masahide; Ohara, Toshimasa; Hiraki, Takatoshi; Oishi, Okihiro; Tsuji, Akihiro; Yamagami, Makiko; Murano, Kentaro; Mukai, Hitoshi

2010-01-01

We found a significant geographic gradient (longitudinal and latitudinal) in the sulfate (SO 42-) concentrations measured at multiple sites over the East Asian Pacific Rim region. Furthermore, the observed gradient was well reproduced by a regional chemical transport model. The observed and modeled SO 42- concentrations were higher at the sites closer to the Asian continent. The concentrations of SO 42- from China as calculated by the model also showed the fundamental features of the longitudinal/latitudinal gradient. The proportional contribution of Chinese SO 42- to the total in Japan throughout the year was above 50-70% in the control case, using data for Chinese sulfur dioxide (SO 2) emission from the Regional Emission Inventory in Asia (40-60% in the low Chinese emissions case, using Chinese SO 2 emissions data from the State Environmental Protection Administration of China), with a winter maximum of approximately 65-80%, although the actual concentrations of SO 42- from China were highest in summer. The multiple-site measurements and the model analysis strongly suggest that the SO 42- concentrations in Japan were influenced by the outflow from the Asian continent, and this influence was greatest in the areas closer to the Asian continent. In contrast, we found no longitudinal/latitudinal gradient in SO 2 concentrations; instead SO 2 concentrations were significantly correlated with local SO 2 emissions. Our results show that large amounts of particulate sulfate are transported over long distances from the East Asian Pacific Rim region, and consequently the SO 42- concentrations in Japan are controlled by the transboundary outflow from the Asian continent.

Drivers for spatial, temporal and long-term trends in atmospheric ammonia and ammonium in the UK

NASA Astrophysics Data System (ADS)

Tang, Yuk S.; Braban, Christine F.; Dragosits, Ulrike; Dore, Anthony J.; Simmons, Ivan; van Dijk, Netty; Poskitt, Janet; Dos Santos Pereira, Gloria; Keenan, Patrick O.; Conolly, Christopher; Vincent, Keith; Smith, Rognvald I.; Heal, Mathew R.; Sutton, Mark A.

2018-01-01

A unique long-term dataset from the UK National Ammonia Monitoring Network (NAMN) is used here to assess spatial, seasonal and long-term variability in atmospheric ammonia (NH3: 1998-2014) and particulate ammonium (NH4+: 1999-2014) across the UK. Extensive spatial heterogeneity in NH3 concentrations is observed, with lowest annual mean concentrations at remote sites (< 0.2 µg m-3) and highest in the areas with intensive agriculture (up to 22 µg m-3), while NH4+ concentrations show less spatial variability (e.g. range of 0.14 to 1.8 µg m-3 annual mean in 2005). Temporally, NH3 concentrations are influenced by environmental conditions and local emission sources. In particular, peak NH3 concentrations are observed in summer at background sites (defined by 5 km grid average NH3 emissions < 1 kg N ha-1 yr-1) and in areas dominated by sheep farming, driven by increased volatilization of NH3 in warmer summer temperatures. In areas where cattle, pig and poultry farming is dominant, the largest NH3 concentrations are in spring and autumn, matching periods of manure application to fields. By contrast, peak concentrations of NH4+ aerosol occur in spring, associated with long-range transboundary sources. An estimated decrease in NH3 emissions by 16 % between 1998 and 2014 was reported by the UK National Atmospheric Emissions Inventory. Annually averaged NH3 data from NAMN sites operational over the same period (n = 59) show an indicative downward trend, although the reduction in NH3 concentrations is smaller and non-significant: Mann-Kendall (MK), -6.3 %; linear regression (LR), -3.1 %. In areas dominated by pig and poultry farming, a significant reduction in NH3 concentrations between 1998 and 2014 (MK: -22 %; LR: -21 %, annually averaged NH3) is consistent with, but not as large as the decrease in estimated NH3 emissions from this sector over the same period (-39 %). By contrast, in cattle-dominated areas there is a slight upward trend (non-significant) in NH3 concentrations (MK: +12 %; LR: +3.6 %, annually averaged NH3), despite the estimated decline in NH3 emissions from this sector since 1998 (-11 %). At background and sheep-dominated sites, NH3 concentrations increased over the monitoring period. These increases (non-significant) at background (MK: +17 %; LR: +13 %, annually averaged data) and sheep-dominated sites (MK: +15 %; LR: +19 %, annually averaged data) would be consistent with the concomitant reduction in SO2 emissions over the same period, leading to a longer atmospheric lifetime of NH3, thereby increasing NH3 concentrations in remote areas. The observations for NH3 concentrations not decreasing as fast as estimated emission trends are consistent with a larger downward trend in annual particulate NH4+ concentrations (1999-2014: MK: -47 %; LR: -49 %, p < 0.01, n = 23), associated with a lower formation of particulate NH4+ in the atmosphere from gas phase NH3.

Long-term study of urban ultrafine particles and other pollutants

NASA Astrophysics Data System (ADS)

Wang, Yungang; Hopke, Philip K.; Chalupa, David C.; Utell, Mark J.

2011-12-01

Continuous measurements of number size distributions of ultrafine particles (UFPs) and other pollutants (PM 2.5, SO 2, CO and O 3) have been performed in Rochester, New York since late November 2001. The 2002-2009 average number concentrations of particles in three size ranges (10-50 nm, 50-100 nm and 100-500 nm) were 4730 cm -3, 1838 cm -3, and 1073 cm -3, respectively. The lowest annual average number concentrations of particles in 10-50 nm and 50-100 nm were observed during 2008-2009. The lowest monthly average number concentration of 10-50 nm particles was observed in July and the highest in February. The daily patterns of 10-50 nm particles had two peaks at early morning (7-8 AM) and early afternoon (2 PM). There was a distinct declining trend in the peak number concentrations from 2002-2005 to 2008-2009. Large reductions in SO 2 concentrations associated with northerly winds between 2007 and 2009 were observed. The most significant annual decrease in the frequency of morning particle nucleation was observed from 2005 to 2007. The monthly variation in the morning nucleation events showed a close correlation with number concentrations of 10-50 nm particles ( r = 0.89). The frequency of the local SO 2-related nucleation events was much higher before 2006. All of these results suggest significant impacts of highway traffic and industrial sources. The decrease in particle number concentrations and particle nucleation events likely resulted from a combination of the U.S. EPA 2007 Heavy-Duty Highway Rule implemented on October 1, 2006, the closure of a large coal-fired power plant in May 2008, and the reduction of Eastman Kodak emissions.

Pollution Emissions, Environmental Policy, and Marginal Abatement Costs

PubMed Central

He, Ling-Yun; Ou, Jia-Jia

2017-01-01

Pollution emissions impose serious social negative externalities, especially in terms of public health. To reduce pollution emissions cost-effectively, the marginal abatement costs (MACs) of pollution emissions must be determined. Since the industrial sectors are the essential pillars of China’s economic growth, as well as leading energy consumers and sulfur dioxide (SO2) emitters, estimating MACs of SO2 emissions at the industrial level can provide valuable information for all abatement efforts. This paper tries to address the critical and essential issue in pollution abatement: How do we determine the MACs of pollution emissions in China? This paper first quantifies the SO2 emission contribution of different industrial sectors in the Chinese economy by an Input-Output method and then estimates MACs of SO2 for industrial sectors at the national level, provincial level, and sectoral level by the shadow price theory. Our results show that six sectors (e.g., the Mining and Washing of Coal sector) should be covered in the Chinese pollution emission trading system. We have also found that the lowest SO2 shadow price is 2000 Yuan/ton at the national level, and that shadow prices should be set differently at the provincial level. Our empirical study has several important policy implications, e.g., the estimated MACs may be used as a pricing benchmark through emission allowance allocation. In this paper, the MACs of industrial sectors are calculated from the national, provincial and sectoral levels; therefore, we provide an efficient framework to track the complex relationship between sectors and provinces. PMID:29206170

Emission Characteristics of Gas-Fired Boilers based on Category-Specific Emission Factor from Field Measurements in Beijing, China

NASA Astrophysics Data System (ADS)

Itahashi, S.; Yan, X.; Song, G.; Yan, J.; Xue, Y.

2017-12-01

Gas-fired boilers will become the main stationary sources of NOx in Beijing. However, the knowledge of gas-fired boilers in Beijing is limited. In the present study, the emission characteristics of NOx, SO2, and CO from gas-fired boilers in Beijing were established using category-specific emission factors (EFs) from field measurements. In order to obtain category-specific EFs, boilers were classified through influence analysis. Factors such as combustion mode, boiler type, and installed capacity were considered critical for establishing EFs because they play significant roles in pollutant formation. The EFs for NOx, CO, and SO2 ranged from 1.42-6.86 g m-3, 0.05-0.67 g m-3 and 0.03-0.48 g m-3. The emissions of NOx, SO2, and CO for gas-fired boilers in Beijing were 11121 t, 468 t, and 222 t in 2014, respectively. The emissions were spatially allocated into grid cells with a resolution of 1 km × 1 km, and the results indicated that top emitters were in central Beijing. The uncertainties were quantified using a Monte Carlo simulation. The results indicated high uncertainties in CO (-157% to 154%) and SO2 (-127% to 182%) emissions, and relatively low uncertainties (-34% to 34%) in NOx emission. Furthermore, approximately 61.2% and 96.8% of the monitored chamber combustion boilers (CCBs) met the standard limits for NOx and SO2, respectively. Concerning NOx, low-NOx burners and NOx emission control measures are urgently needed for implementing of stricter standards. Adopting terminal control measures is unnecessary for SO2, although its concentration occasionally exceeds standard limits, because reduction of its concentration can be achieved thorough control of the sulfur content of natural gas at a stable low level. Furthermore, the atmospheric combustion boilers (ACBs) should be substituted with CCBs, because ACBs have a higher emission despite lower gross installed capacity. The results of this study will enable in understanding and controlling emissions from gas-fired boilers in Beijing.

Sulfur dioxide emission rates from Kīlauea Volcano, Hawai‘i, 2007–2010

USGS Publications Warehouse

Elias, T.; Sutton, A.J.

2012-01-01

Kīlauea Volcano has one of the longest running volcanic sulfur dioxide (SO2) emission rate databases on record. Sulfur dioxide emission rates from Kīlauea Volcano were first measured by Stoiber and Malone (1975) and have been measured on a regular basis since 1979 (Elias and Sutton, 2007, and references within). Compilations of SO2 emission-rate and wind-vector data from 1979 through 2006 are available on the USGS Web site (Elias and others, 1998; Elias and Sutton, 2002; Elias and Sutton, 2007). This report updates the database, documents the changes in data collection and processing methods, and highlights how SO2 emissions have varied with eruptive activity at Kīlauea Volcano for the interval 2007–2010.

Why an SO/sub 2/ emission tax is an unpopular policy instrument: Simulation results from a general equilibrium model of the Norwegian economy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hanson, D.A.; Alfsen, K.H.

1986-01-01

Norway, together with some twenty other countries, signed the Helsinki treaty in July 1985 for the purpose of reducing SO/sub 2/ emissions. Hence, it is interesting to analyze the emission reductions that could be achieved using a tax on SO/sub 2/ emissions, as well as the indirect impacts on the economy. Simulations of the economic impact of the tax (which effectively increases the cost of using energy) were made using the Multi-Sectoral Growth (MSG) model. Results of the simulations indicated a larger than expected reduction in economic output.

40 CFR 75.58 - General recordkeeping provisions for specific situations.

Code of Federal Regulations, 2012 CFR

2012-07-01

... C to this part, for each hour of missing SO2 concentration or volumetric flow data: (i) The... owner or operator shall record: (i) Parametric data which demonstrate, for each hour of missing SO2 or... indicating, for each hour of missing SO2 or NOX emission data, either that the add-on emission controls are...

40 CFR 75.58 - General recordkeeping provisions for specific situations.

Code of Federal Regulations, 2013 CFR

2013-07-01

... C to this part, for each hour of missing SO2 concentration or volumetric flow data: (i) The... owner or operator shall record: (i) Parametric data which demonstrate, for each hour of missing SO2 or... indicating, for each hour of missing SO2 or NOX emission data, either that the add-on emission controls are...

40 CFR 75.58 - General recordkeeping provisions for specific situations.

Code of Federal Regulations, 2014 CFR

2014-07-01

... C to this part, for each hour of missing SO2 concentration or volumetric flow data: (i) The... owner or operator shall record: (i) Parametric data which demonstrate, for each hour of missing SO2 or... indicating, for each hour of missing SO2 or NOX emission data, either that the add-on emission controls are...

40 CFR 75.58 - General recordkeeping provisions for specific situations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... C to this part, for each hour of missing SO2 concentration or volumetric flow data: (i) The... owner or operator shall record: (i) Parametric data which demonstrate, for each hour of missing SO2 or... indicating, for each hour of missing SO2 or NOX emission data, either that the add-on emission controls are...

40 CFR Appendix C to Part 72 - Actual 1985 Yearly SO2 Emissions Calculation

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Actual 1985 Yearly SO2 Emissions Calculation C Appendix C to Part 72 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Pt. 72, App. C Appendix C to Part 72—Actual 1985 Yearly SO2...

40 CFR Appendix C to Part 72 - Actual 1985 Yearly SO2 Emissions Calculation

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Actual 1985 Yearly SO2 Emissions Calculation C Appendix C to Part 72 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Pt. 72, App. C Appendix C to Part 72—Actual 1985 Yearly SO2...

40 CFR Appendix C to Part 72 - Actual 1985 Yearly SO2 Emissions Calculation

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Actual 1985 Yearly SO2 Emissions Calculation C Appendix C to Part 72 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) PERMITS REGULATION Pt. 72, App. C Appendix C to Part 72—Actual 1985 Yearly SO2...

Time Series of SO2 Flux from Popocatépetl Volcano by an Ultra-Violet Camera with a Set of Different Band-Pass Filters

NASA Astrophysics Data System (ADS)

Schiavo, B.; Stremme, W.; Grutter, M.; Campion, R.; Rivera, C. I.; Inguaggiato, S.

2017-12-01

The measurement of SO2flux from active volcanoes are of great importance, for monitoring and hazard of volcanic activity, environmental impact and flux emissions related to changes of magmatic activity. Sulfur dioxide total flux from Popocatépetl volcano was determinad using a ultra-violet camera (or SO2 camera) with different band-pass filter. The flux is obteined from the product of the gas concentration over integrated the plume cross-section (slant column in molec/cm2 or ppm*m) and wind velocity data. Model of plume altitude and wind speed measurement are used to calculate a wind velocity, but a new method of sequential images is widely used in several years for this calculation. Volcanic plume measurements, for a total of about 60 days from from January to March 2017, were collected and utilized to generate the SO2 time series. The importance of monitoring and the time series of volcanic gas emissions is described and proven by many scientific studies. A time series of the Popocatépetl volcano will allow us to detect the volcanic gas as well as anomalies in volcanic processes and help to estimate the average SO2 flux of the volcano. We present a detailed description of the posterior correction of the dilution effect, which occurs due to a simplification of the radiative transfer equation. The correction scheme is especial applicable for long term monitoring from a permanent observation site. Images of volcanic SO2 plumes from the active Popocatépetl volcano in Mexico are presented, showing persistent passive degassing. The measurment are taken from the Altzomoni Atmospheric Observatory (19.12N, -98.65W, 3,985 m.a.s.l.), which forms part of the RUOA (www.ruoa.unam.mx) and NDACC (https://www2.acom.ucar.edu/irwg) networks. It is located north of the crater at 11 km distance. The data to calculate SO2 flux (t/d or kg/s) were recorded with the QSI UV camera and processed using Python scripts.

ATMOSPHERIC AEROSOL SOURCE-RECEPTOR RELATIONSHIPS: THE ROLE OF COAL-FIRED POWER PLANTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Allen L. Robinson; Spyros N. Pandis; Cliff I. Davidson

2004-04-01

This report describes the technical progress made on the Pittsburgh Air Quality Study (PAQS) during the period of September 2003 through February 2004. Significant progress was made this project period on the analysis of ambient data, source apportionment, and deterministic modeling activities. Results highlighted in this report include chemical fractionation of the organic fraction to quantify the ratio of organic mass to organic carbon (OM/OC). The average OM/OC ratio for the 31 samples analyzed so far is 1.89, ranging between 1.62 and 2.53, which is consistent with expectations for an atmospherically processed regional aerosol. Analysis of the single particle datamore » reveals that a on a particles in Pittsburgh consist of complex mixture of primary and secondary components. Approximately 79% of all particles measured with the instrument containing some form of carbon, with Carbonaceous Ammonium Nitrate (54.43%) being the dominant particle class. PMCAMx predictions were compared with data from more than 50 sites of the STN network located throughout the Eastern United States for the July 2001 period. OC and sulfate concentrations predicted by PMCAMx are within {+-}30% of the observed concentration at most of these sites. Spherical Aluminum Silicate particle concentrations (SAS) were used to estimate the contribution of primary coal emissions to fine particle levels at the central monitoring site. Primary emissions from coal combustion contribute on average 0.44 {+-} 0.3 {micro}g/m{sup 3} to PM{sub 2.5} at the site or 1.4 {+-} 1.3% of the total PM{sub 2.5} mass. Chemical mass balance analysis was performed to apportion the primary organic aerosol. About 70% of the primary OC emissions are from vehicular sources, with the gasoline contribution being on average three times greater than the diesel emissions in the summer.« less

The sensitivities of emissions reductions for the mitigation of UK PM2.5

NASA Astrophysics Data System (ADS)

Vieno, M.; Heal, M. R.; Williams, M. L.; Carnell, E. J.; Nemitz, E.; Stedman, J. R.; Reis, S.

2016-01-01

The reduction of ambient concentrations of fine particulate matter (PM2.5) is a key objective for air pollution control policies in the UK and elsewhere. Long-term exposure to PM2.5 has been identified as a major contributor to adverse human health effects in epidemiological studies and underpins ambient PM2.5 legislation. As a range of emission sources and atmospheric chemistry transport processes contribute to PM2.5 concentrations, atmospheric chemistry transport models are an essential tool to assess emissions control effectiveness. The EMEP4UK atmospheric chemistry transport model was used to investigate the impact of reductions in UK anthropogenic emissions of primary PM2.5, NH3, NOx, SOx or non-methane VOC on surface concentrations of PM2.5 in the UK for a recent year (2010) and for a future current legislation emission (CLE) scenario (2030). In general, the sensitivity to UK mitigation is rather small. A 30 % reduction in UK emissions of any one of the above components yields (for the 2010 simulation) a maximum reduction in PM2.5 in any given location of ˜ 0.6 µg m-3 (equivalent to ˜ 6 % of the modelled PM2.5). On average across the UK, the sensitivity of PM2.5 concentrations to a 30 % reduction in UK emissions of individual contributing components, for both the 2010 and 2030 CLE baselines, increases in the order NMVOC, NOx, SOx, NH3 and primary PM2.5; however there are strong spatial differences in the PM2.5 sensitivities across the UK. Consequently, the sensitivity of PM2.5 to individual component emissions reductions varies between area and population weighting. Reductions in NH3 have the greatest effect on area-weighted PM2.5. A full UK population weighting places greater emphasis on reductions of primary PM2.5 emissions, which is simulated to be the most effective single-component control on PM2.5 for the 2030 scenario. An important conclusion is that weighting corresponding to the average exposure indicator metric (using data from the 45 model grids containing a monitor whose measurements are used to calculate the UK AEI) further increases the emphasis on the effectiveness of primary PM2.5 emissions reductions (and of NOx emissions reductions) relative to the effectiveness of NH3 emissions reductions. Reductions in primary PM2.5 have the largest impact on the AEI in both 2010 and the 2030 CLE scenario. The summation of the modelled reductions to the UK PM2.5 AEI from 30 % reductions in UK emissions of primary PM2.5, NH3, SOx, NOx and VOC totals 1.17 and 0.82 µg m-3 for the 2010 and 2030 CLE simulations, respectively (not accounting for non-linearity).