Sample records for average surface water

  1. Estimation of open water evaporation using land-based meteorological data

    NASA Astrophysics Data System (ADS)

    Li, Fawen; Zhao, Yong

    2017-10-01

    Water surface evaporation is an important process in the hydrologic and energy cycles. Accurate simulation of water evaporation is important for the evaluation of water resources. In this paper, using meteorological data from the Aixinzhuang reservoir, the main factors affecting water surface evaporation were determined by the principal component analysis method. To illustrate the influence of these factors on water surface evaporation, the paper first adopted the Dalton model to simulate water surface evaporation. The results showed that the simulation precision was poor for the peak value zone. To improve the model simulation's precision, a modified Dalton model considering relative humidity was proposed. The results show that the 10-day average relative error is 17.2%, assessed as qualified; the monthly average relative error is 12.5%, assessed as qualified; and the yearly average relative error is 3.4%, assessed as excellent. To validate its applicability, the meteorological data of Kuancheng station in the Luan River basin were selected to test the modified model. The results show that the 10-day average relative error is 15.4%, assessed as qualified; the monthly average relative error is 13.3%, assessed as qualified; and the yearly average relative error is 6.0%, assessed as good. These results showed that the modified model had good applicability and versatility. The research results can provide technical support for the calculation of water surface evaporation in northern China or similar regions.

  2. Potentiometric Surface of the Upper Floridan Aquifer in the St. Johns River Water Management District and Vicinity, May 2008

    USGS Publications Warehouse

    Kinnaman, Sandra L.; Dixon, Joann F.

    2008-01-01

    This map depicts the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity for May 2008. Potentiometric contours are based on water-level measurements collected at 567 wells during the period May 6-May 27, near the end of the dry season. Some contours are inferred from previous potentiometric-surface maps with larger well networks. The potentiometric surface of the carbonate Upper Floridan aquifer responds mainly to rainfall, and more locally, to ground-water withdrawals and spring flow. Potentiometric-surface highs generally correspond to topographic highs where the aquifer is recharged. Springs and areas of diffuse upward leakage naturally discharge water from the aquifer and are most prevalent along the St. Johns River. Areas of discharge are reflected by depressions in the potentiometric surface. Ground-water withdrawals locally have lowered the potentiometric surface. Ground water in the Upper Floridan aquifer generally flows from potentiometric highs to potentiometric lows in a direction perpendicular to the contours. Measured values of the potentiometric surface ranged from 7 feet below NGVD29 near Fernandina Beach, Florida, to 124 feet above NGVD29 in Polk County, Florida. The average water level of the network in May 2008 was about 1 foot lower than the average in September 2007 following below-average rainfall during the dry season of 2007-08. Seasonal differences in network average water levels generally range from 4 to 6 feet. For 457 wells with previous measurements, May 2008 levels ranged from about 19 feet below to about 11 feet above September 2007 water levels. The average water level of the network in May 2008 was about 1 foot higher than the average in May 2007. For 544 wells with previous measurements, May 2008 levels ranged from about 8 feet below to about 13 feet above May 2007 water levels. Long-term hydrographs of ground-water levels for continuous and periodic wells are available at internet site: http://waterdata.usgs.gov/fl/nwis/gw

  3. Multi-temporal AirSWOT elevations on the Willamette river: error characterization and algorithm testing

    NASA Astrophysics Data System (ADS)

    Tuozzolo, S.; Frasson, R. P. M.; Durand, M. T.

    2017-12-01

    We analyze a multi-temporal dataset of in-situ and airborne water surface measurements from the March 2015 AirSWOT field campaign on the Willamette River in Western Oregon, which included six days of AirSWOT flights over a 75km stretch of the river. We examine systematic errors associated with dark water and layover effects in the AirSWOT dataset, and test the efficacies of different filtering and spatial averaging techniques at reconstructing the water surface profile. Finally, we generate a spatially-averaged time-series of water surface elevation and water surface slope. These AirSWOT-derived reach-averaged values are ingested in a prospective SWOT discharge algorithm to assess its performance on SWOT-like data collected from a borderline SWOT-measurable river (mean width = 90m).

  4. Perfluoroalkyl acids in surface waters and tapwater in the Qiantang River watershed-Influences from paper, textile, and leather industries.

    PubMed

    Lu, Guo-Hui; Gai, Nan; Zhang, Peng; Piao, Hai-Tao; Chen, Shu; Wang, Xiao-Chun; Jiao, Xing-Chun; Yin, Xiao-Cai; Tan, Ke-Yan; Yang, Yong-Liang

    2017-10-01

    Perfluoroalkyl acids (PFAAs) are widely used as multi-purpose surfactants or water/oil repellents. In order to understand the contamination level and compositional profiles of PFAAs in aqueous environment in textile, leather, and paper making industrial areas, surface waters and tap waters were collected along the watershed of the Qiantang River where China's largest textile, leather, and paper making industrial bases are located. For comparison, surface water and tapwater samples were also collected in Hangzhou and its adjacent areas. 17 PFAAs were analyzed by solid phase extraction-high performance liquid chromatography-tandem mass spectrometry. The results show that the total concentrations of PFAAs (ΣPFAAs) in the Qiantang River waters ranged from 106.1 to 322.9 ng/L, averaging 164.2 ng/L. The contamination levels have been found to be extremely high, comparable to the levels of the most serious PFAA contamination in surface waters of China. The PFAA composition profiles were characterized by the dominant PFOA (average 58.1% of the total PFAAs), and PFHxA (average 18.8%). The ΣPFAAs in tap water ranged from 9.5 to 174.8 ng/L, showing PFAA compositional pattern similar to the surface waters. Good correlations between PFAA composition profiles in tap waters and the surface waters were observed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Using thermal-infrared imagery to delineate ground-water discharge

    USGS Publications Warehouse

    Banks, W.S.L.; Paylor, R.L.; Hughes, W.B.

    1996-01-01

    On March 8 and 9, 1992, a thermal-infrared-multispectral scanner (TIMS) was flown over two military ordnance disposal facilities at the Edgewood Area of Aberdeen Proving Ground, Maryland. The data, collected bythe National Aeronautics and Space Administration, in cooperation with the U.S. Army and the U.S. Geological Survey, were used to locate ground-water discharge zones in surface water. The images from the flight show areas where ground-water discharge is concentrated, as well as areas of diffuse discharge. Concentrated discharge is predominant in isolated or nearly isolated ponds and creeks in the study area. Diffuse dicharge is found near parts of the shoreline where the study area meets the surrounding estuaries of the Chesapeake Bay and the Gunpowder River. The average temperature for surface water, measured directly in the field, and the average temperature, calculated from atmospherically corrected TIMS images, was 10.6??C (Celsius) at the first of two sites. Potentiometric surface maps of both field sites show discharge toward the nontidal marshes, the estuaries which surround the field sites, and creeks which drain into the estuaries. The average measured temperature of ground water at both sites was 10.7??C. The calculated temperature from the TIMS imagery at both sites where ground-water discharge is concentrated within a surface-water body is 10.4??C. In the estuaries which surround the field sites, field measurements of temperature were made resulting in an average temperature of 9.0??C. The average calculated TIMS temperature from the estuaries was 9.3??C. Along the shoreline at the first site and within 40 to 80 meters of the western and southern shores of the second site, water was 1?? to 2??C warmer than water more than 80 meters away. The pattern of warmer water grading to cooler water in an offshore direction could result from diffuse ground-water discharge. Tonal differences in the TIMS imagery could indicate changes in surface-water temperatures. These tonal differences can be interpreted to delineate the location and extent of ground-water discharge to bodies of surface water.

  6. Water resources of Lincoln and Union counties, South Dakota

    USGS Publications Warehouse

    Niehus, C.A.

    1994-01-01

    Water resources of Lincoln and Union Counties occur as surface water in streams and lakes and ground water in ten major glacial and one major bedrock aquifers. The major surface-water sources are the Missouri and Big Sioux Rivers. Glacial aquifers contain about 4 million acre-feet of water in storage; 1.5 million acre-feet are contained in the Missouri aquifer. The Wall Lake, Shindler, and Upper Vemillion-Missouri aquifers are deeply buried, confined aquifers with average thicknesses ranging from 31 to 41 feet. The Harrisburg and Big Sioux aquifers are shallow, water-table aquifers with average thicknesses of 26 and 28 feet, respectively. The Parker-Centerville, Newton Hills, and Brule Creek aquifers are buried, confined aquifers with average thicknesses ranging from 33 to 36 feet. The Lower Vermillion-Missouri aquifer is a buried, confined aquifer with an average thickness of 99 feet. The Missouri aquifer is confined in the northeastern portion of the aquifer and is a shallow, water-table aquifer elsewhere with average cumulative thickness of 84 feet.

  7. Indonesia sea surface temperature from TRMM Microwave Imaging (TMI) sensor

    NASA Astrophysics Data System (ADS)

    Marini, Y.; Setiawan, K. T.

    2018-05-01

    We analysis the Tropical Rainfall Measuring Mission's (TRMM) Microwave Imager (TMI) data to monitor the sea surface temperature (SST) of Indonesia waters for a decade of 2005-2014. The TMI SST data shows the seasonal and interannual SST in Indonesian waters. In general, the SST average was highest in March-May period with SST average was 29.4°C, and the lowest was in June – August period with the SST average was 28.5°C. The monthly SST average fluctuation of Indonesian waters for 10 years tends to increase. The lowest SST average of Indonesia occurred in August 2006 with the SST average was 27.6° C, while the maximum occurred in May 2014 with the monthly SST average temperature was 29.9 ° C.

  8. Environmental monitoring at Mound: 1986 report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Carfagno, D.G.; Farmer, B.M.

    1987-05-11

    The local environment around Mound was monitored for tritium and plutonium-238. The results are reported for 1986. Environmental media analyzed included air, water, vegetation, foodstuffs, and sediment. The average concentrations of plutonium-238 and tritium were within the DOE interim air and water Derived Concentration Guides (DCG) for these radionuclides. The average incremental concentrations of plutonium-238 and tritium oxide in air measured at all offsite locations during 1986 were 0.03% and 0.01%, respectively, of the DOE DCGs for uncontrolled areas. The average incremental concentration of plutonium-238 measured at all locations in the Great Miami River during 1986 was 0.0005% of themore » DOE DCG. The average incremental concentration of tritium measured at all locations in the Great Miami River during 1986 was 0.005% of the DOE DCG. The average incremental concentrations of plutonium-238 found during 1986 in surface and area drinking water were less than 0.00006% of the DOE DCG. The average incremental concentration of tritium in surface water was less than 0.005% of the DOE DCG. All tritium in drinking water data is compared to the US EPA Drinking Water Standard. The average concentrations in local private and municipal drinking water systems were less than 25% and 1.5%, respectively. Although no DOE DCG is available for foodstuffs, the average concentrations are a small fraction of the water DCG (0.04%). The concentrations of sediment samples obtained at offsite surface water sampling locations were extremely low and therefore represent no adverse impact to the environment. The dose equivalent estimates for the average air, water, and foodstuff concentrations indicate that the levels are within 1% of the DOE standard of 100 mrem. None of these exceptions, however, had an adverse impact on the water quality of the Great Miami River or caused the river to exceed Ohio Stream Standards. 20 refs., 5 figs., 31 tabs.« less

  9. The spatial-temporal dynamics of open surface water bodies in CONUS during 1984-2016

    NASA Astrophysics Data System (ADS)

    Zou, Z.; Xiao, X.; Dong, J.; Qin, Y.; Doughty, R.; Menarguez, M.; Wang, J.

    2017-12-01

    Open surface water bodies provided 80% of the total water withdrawals in the Contiguous United States (CONUS) in 1985-2010. The inter-annual variability and changing trends of surface water body areas have various impacts on the human society and ecosystems. This study made use of all Landsat 5, 7, and 8 surface reflectance archives ( 370,000 images) during 1984-2016 and a water index- and pixel-based approach to detect and map open surface water bodies in the cloud-based platform of Google Earth Engine. The year-long water body area and annual average water body area were calculated for each of the last 33 years and their inter-annual variations during 1984-2016 were analyzed through anomaly analysis while their changing trends were analyzed through linear regressions. The national annual average water body areas varied from 265,000 to 281,000 km2 during 1984-2016, which is 3% below to 3% above the mean value 274,000 km2. In state level, significant decreasing trends were found in both year-long and annual average water body areas in some states of dry climates in west and southwest U.S., including Oregon, Nevada, Utah, Arizona, New Mexico, and Oklahoma. In comparison, significant increasing trends were found in some states of wet climates in the southeast and north U.S., including Indiana, Ohio, New Jersey, Delaware, Virginia, Tennessee, North Carolina, South Carolina, Louisiana, Alabama, Georgia, North Dakota and South Dakota. Open surface water body areas in CONUS decreased in relatively dry areas but increased in relatively wet areas. The relationships between open surface water body area variability and climate factors (precipitation, temperature) and human impacts (water exploitation) were also analyzed.

  10. Potentiometric surface of the Upper Floridan aquifer, west-central Florida, September 2010

    USGS Publications Warehouse

    Ortiz, A.G.

    2011-01-01

    This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. This map report shows the potentiometric surface of the Upper Floridan aquifer measured in September 2010. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the wet season, when groundwater levels usually are at an annual high and withdrawals for agricultural use typically are low. The cumulative average rainfall of 53.17 inches for west-central Florida (from October 2009 through September 2010) was 0.41 inches above the historical cumulative average of 52.76 inches (Southwest Florida Water Management District, 2010). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District.

  11. Modeling decadal timescale interactions between surface water and ground water in the central Everglades, Florida, USA

    USGS Publications Warehouse

    Harvey, J.W.; Newlin, J.T.; Krupa, S.L.

    2006-01-01

    Surface-water and ground-water flow are coupled in the central Everglades, although the remoteness of this system has hindered many previous attempts to quantify interactions between surface water and ground water. We modeled flow through a 43,000 ha basin in the central Everglades called Water Conservation Area 2A. The purpose of the model was to quantify recharge and discharge in the basin's vast interior areas. The presence and distribution of tritium in ground water was the principal constraint on the modeling, based on measurements in 25 research wells ranging in depth from 2 to 37 m. In addition to average characteristics of surface-water flow, the model parameters included depth of the layer of 'interactive' ground water that is actively exchanged with surface water, average residence time of interactive ground water, and the associated recharge and discharge fluxes across the wetland ground surface. Results indicated that only a relatively thin (8 m) layer of the 60 m deep surfical aquifer actively exchanges surface water and ground water on a decadal timescale. The calculated storage depth of interactive ground water was 3.1 m after adjustment for the porosity of peat and sandy limestone. Modeling of the tritium data yielded an average residence time of 90 years in interactive ground water, with associated recharge and discharge fluxes equal to 0.01 cm d -1. 3H/3He isotopic ratio measurements (which correct for effects of vertical mixing in the aquifer with deeper, tritium-dead water) were available from several wells, and these indicated an average residence time of 25 years, suggesting that residence time was overestimated using tritium measurements alone. Indeed, both residence time and storage depth would be expected to be overestimated due to vertical mixing. The estimate of recharge and discharge (0.01 cm d-1) that resulted from tritium modeling therefore is still considered reliable, because the ratio of residence time and storage depth (used to calculated recharge and discharge) is much less sensitive to vertical mixing compared with residence time alone. We conclude that a small but potentially significant component of flow through the Everglades is recharged to the aquifer and stored there for years to decades before discharged back to surface water. Long-term storage of water and solutes in the ground-water system beneath the wetlands has implications for restoration of Everglades water quality.

  12. Modeling decadal timescale interactions between surface water and ground water in the central Everglades, Florida, USA

    NASA Astrophysics Data System (ADS)

    Harvey, Judson W.; Newlin, Jessica T.; Krupa, Steven L.

    2006-04-01

    Surface-water and ground-water flow are coupled in the central Everglades, although the remoteness of this system has hindered many previous attempts to quantify interactions between surface water and ground water. We modeled flow through a 43,000 ha basin in the central Everglades called Water Conservation Area 2A. The purpose of the model was to quantify recharge and discharge in the basin's vast interior areas. The presence and distribution of tritium in ground water was the principal constraint on the modeling, based on measurements in 25 research wells ranging in depth from 2 to 37 m. In addition to average characteristics of surface-water flow, the model parameters included depth of the layer of 'interactive' ground water that is actively exchanged with surface water, average residence time of interactive ground water, and the associated recharge and discharge fluxes across the wetland ground surface. Results indicated that only a relatively thin (8 m) layer of the 60 m deep surfical aquifer actively exchanges surface water and ground water on a decadal timescale. The calculated storage depth of interactive ground water was 3.1 m after adjustment for the porosity of peat and sandy limestone. Modeling of the tritium data yielded an average residence time of 90 years in interactive ground water, with associated recharge and discharge fluxes equal to 0.01 cm d -1. 3H/ 3He isotopic ratio measurements (which correct for effects of vertical mixing in the aquifer with deeper, tritium-dead water) were available from several wells, and these indicated an average residence time of 25 years, suggesting that residence time was overestimated using tritium measurements alone. Indeed, both residence time and storage depth would be expected to be overestimated due to vertical mixing. The estimate of recharge and discharge (0.01 cm d -1) that resulted from tritium modeling therefore is still considered reliable, because the ratio of residence time and storage depth (used to calculated recharge and discharge) is much less sensitive to vertical mixing compared with residence time alone. We conclude that a small but potentially significant component of flow through the Everglades is recharged to the aquifer and stored there for years to decades before discharged back to surface water. Long-term storage of water and solutes in the ground-water system beneath the wetlands has implications for restoration of Everglades water quality.

  13. Field and laboratory determination of water-surface elevation and velocity using noncontact measurements

    USGS Publications Warehouse

    Nelson, Jonathan M.; Kinzel, Paul J.; Schmeeckle, Mark Walter; McDonald, Richard R.; Minear, Justin T.

    2016-01-01

    Noncontact methods for measuring water-surface elevation and velocity in laboratory flumes and rivers are presented with examples. Water-surface elevations are measured using an array of acoustic transducers in the laboratory and using laser scanning in field situations. Water-surface velocities are based on using particle image velocimetry or other machine vision techniques on infrared video of the water surface. Using spatial and temporal averaging, results from these methods provide information that can be used to develop estimates of discharge for flows over known bathymetry. Making such estimates requires relating water-surface velocities to vertically averaged velocities; the methods here use standard relations. To examine where these relations break down, laboratory data for flows over simple bumps of three amplitudes are evaluated. As anticipated, discharges determined from surface information can have large errors where nonhydrostatic effects are large. In addition to investigating and characterizing this potential error in estimating discharge, a simple method for correction of the issue is presented. With a simple correction based on bed gradient along the flow direction, remotely sensed estimates of discharge appear to be viable.

  14. Swath-altimetry measurements of the main stem Amazon River: measurement errors and hydraulic implications

    NASA Astrophysics Data System (ADS)

    Wilson, M. D.; Durand, M.; Jung, H. C.; Alsdorf, D.

    2015-04-01

    The Surface Water and Ocean Topography (SWOT) mission, scheduled for launch in 2020, will provide a step-change improvement in the measurement of terrestrial surface-water storage and dynamics. In particular, it will provide the first, routine two-dimensional measurements of water-surface elevations. In this paper, we aimed to (i) characterise and illustrate in two dimensions the errors which may be found in SWOT swath measurements of terrestrial surface water, (ii) simulate the spatio-temporal sampling scheme of SWOT for the Amazon, and (iii) assess the impact of each of these on estimates of water-surface slope and river discharge which may be obtained from SWOT imagery. We based our analysis on a virtual mission for a ~260 km reach of the central Amazon (Solimões) River, using a hydraulic model to provide water-surface elevations according to SWOT spatio-temporal sampling to which errors were added based on a two-dimensional height error spectrum derived from the SWOT design requirements. We thereby obtained water-surface elevation measurements for the Amazon main stem as may be observed by SWOT. Using these measurements, we derived estimates of river slope and discharge and compared them to those obtained directly from the hydraulic model. We found that cross-channel and along-reach averaging of SWOT measurements using reach lengths greater than 4 km for the Solimões and 7.5 km for Purus reduced the effect of systematic height errors, enabling discharge to be reproduced accurately from the water height, assuming known bathymetry and friction. Using cross-sectional averaging and 20 km reach lengths, results show Nash-Sutcliffe model efficiency values of 0.99 for the Solimões and 0.88 for the Purus, with 2.6 and 19.1 % average overall error in discharge, respectively. We extend the results to other rivers worldwide and infer that SWOT-derived discharge estimates may be more accurate for rivers with larger channel widths (permitting a greater level of cross-sectional averaging and the use of shorter reach lengths) and higher water-surface slopes (reducing the proportional impact of slope errors on discharge calculation).

  15. 18 CFR 806.4 - Projects requiring review and approval.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... groundwater or surface water, shall also be subject to the standards set forth in § 806.23. Except to the... average of 100,000 gpd or more from a groundwater or surface water source, or a combination of such... which involves a withdrawal from a groundwater or surface water source and which is subject to the...

  16. 18 CFR 806.4 - Projects requiring review and approval.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... groundwater or surface water, shall also be subject to the standards set forth in § 806.23. Except to the... average of 100,000 gpd or more from a groundwater or surface water source, or a combination of such... which involves a withdrawal from a groundwater or surface water source and which is subject to the...

  17. 18 CFR 806.4 - Projects requiring review and approval.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... groundwater or surface water, shall also be subject to the standards set forth in § 806.23. Except to the... average of 100,000 gpd or more from a groundwater or surface water source, or a combination of such... which involves a withdrawal from a groundwater or surface water source and which is subject to the...

  18. Potentiometric surfaces of the upper glacial and Magothy aquifers and selected streamflow statistics, 1943-72, on Long Island, New York

    USGS Publications Warehouse

    Vaupel, Donald E.; Prince, K.R.; Koehler, A.J.; Runco, Mario

    1977-01-01

    A brief text describes the two major aquifers and the discharge pattern of major streams on Long Island. Four water-table maps for the years 1943, 1959, 1966, and 1972, an average water-table map for the period 1943-72 supplemented by five well hydrographs representing Kings, Queens, western Nassau, eastern Nassau, and Suffolk Counties, and three potentiometric- surface maps of the Magothy aquifer for the years 1959, 1966, and 1972 are included. A statistical summary of stream discharge presents average annual discharges, annual average discharges, and average 7-day, 10-year low-flow discharges for major streams.

  19. Soil Moisture Content Estimation using GPR Reflection Travel Time

    NASA Astrophysics Data System (ADS)

    Lunt, I. A.; Hubbard, S. S.; Rubin, Y.

    2003-12-01

    Ground-penetrating radar (GPR) reflection travel time data were used to estimate changes in soil water content under a range of soil saturation conditions throughout the growing season at a California winery. Data were collected during four data acquisition campaigns over an 80 by 180 m area using 100 MHz surface GPR antennae. GPR reflections were associated with a thin, low permeability clay layer located between 0.8 to 1.3 m below the ground surface that was calibrated with borehole information and mapped across the study area. Field infiltration tests and neutron probe logs suggest that the thin clay layer inhibited vertical water flow, and was coincident with high volumetric water content (VWC) values. The GPR reflection two-way travel time and the depth of the reflector at borehole locations were used to calculate an average dielectric constant for soils above the reflector. A site-specific relationship between the dielectric constant and VWC was then used to estimate the depth-averaged VWC of the soils above the reflector. Compared to average VWC measurements from calibrated neutron probe logs over the same depth interval, the average VWC estimates obtained from GPR reflections had an RMS error of 2 percent. We also investigated the estimation of VWC using reflections associated with an advancing water front, and found that estimates of average VWC to the water front could be obtained with similar accuracy. These results suggested that the two-way travel time to a GPR reflection associated with a geological surface or wetting front can be used under natural conditions to obtain estimates of average water content when borehole control is available. The GPR reflection method therefore has potential for monitoring soil water content over large areas and under variable hydrological conditions.

  20. Simulation of rainfall-runoff response in mined and unmined watersheds in coal areas of West Virginia

    USGS Publications Warehouse

    Puente, Celso; Atkins, John T.

    1989-01-01

    Meteorologic and hydrologic data from five small watersheds in the coal areas of West Virginia were used to calibrate and test the U.S. Geological Survey Precipitation-Runoff Modeling System for simulating streamflow under various climatic and land-use conditions. Three of the basins--Horsecamp Run, Gilmer Run, and Collison Creek--are primarily forested and relatively undisturbed. The remaining basins--Drawdy Creek and Brier Creek-are extensively mined, both surface and underground above stream drainage level. Low-flow measurements at numerous synoptic sites in the mined basins indicate that coal mining has substantially altered the hydrologic system of each basin. The effects of mining on streamflow that were identified are (1) reduced base flow in stream segments underlain by underground mines, (2) increased base flow in streams that are downdip and stratigraphically below the elevation of the mined coal beds, and (3) interbasin transfer of ground water through underground mines. These changes probably reflect increased permeability of surface rocks caused by subsidence fractures associated with collapsed underground mines in the basin. Such fractures would increase downward percolation of precipitation, surface and subsurface flow, and ground-water flow to deeper rocks or to underground mine workings. Model simulations of the water budgets for the unmined basins during the 1972-73 water years indicate that total annual runoff averaged 60 percent of average annual precipitation; annual evapotranspiration losses averaged 40 percent of average annual precipitation. Of the total annual runoff, approximately 91 percent was surface and subsurface runoff and 9 percent was groundwater discharge. Changes in storage in the soil zone and in the subsurface and ground-water reservoirs in the basins were negligible. In contrast, water-budget simulations for the mined basins indicate significant differences in annual recharge and in total annual runoff. Model simulations of the water budget for Drawdy Creek basin indicate that total annual runoff during 1972-73 averaged only 43 percent of average annual precipitation--the lowest of all study basins; annual evapotranspiration losses averaged 49 percent, and interbasin transfer of ground-water losses averaged about 8 percent. Of the total annual runoff, approximately 74 percent was surface and subsurface flow and 26 percent was ground-water discharge. The low total annual runoff at Drawdy Creek probably reflects increased recharge of precipitation and surface and subsurface flow losses to ground water. Most of the increase in ground-water storage is, in turn, lost to a ground-water sink--namely, interbasin transfer of ground water by gravity drainage and (or) mine pumpage from underground mines that extend to adjacent basins. Hypothetical mining situations were posed for model analysis to determine the effects of increased mining on streamflow in the mined basins. Results of model simulations indicate that streamflow characteristics, the water budget, and the seasonal distribution of streamflow would be significantly modified in response to an increase in mining in the basins. Simulations indicate that (1) total annual runoff in the basins would decrease because of increased surface- and subsurface-flow losses and increased recharge of precipitation to ground water (these losses would tend to reduce medium to high flows mainly during winter and spring when losses would be greatest), (2) extreme high flows in response to intense rainstorms would be negligibly affected, regardless of the magnitude of mining in the basins, (3) ground-water discharge also would decrease during winter and spring, but the amount and duration of low flows during summer and fall would substantially increase in response to increased ground-water storage in rocks and in underground mines, and (4) the increase in ground-water storage in the basins would be depleted, mostly by increased losses to a grou

  1. Estimating soil water content from ground penetrating radar coarse root reflections

    NASA Astrophysics Data System (ADS)

    Liu, X.; Cui, X.; Chen, J.; Li, W.; Cao, X.

    2016-12-01

    Soil water content (SWC) is an indispensable variable for understanding the organization of natural ecosystems and biodiversity. Especially in semiarid and arid regions, soil moisture is the plants primary source of water and largely determine their strategies for growth and survival, such as root depth, distribution and competition between them. Ground penetrating radar (GPR), a kind of noninvasive geophysical technique, has been regarded as an accurate tool for measuring soil water content at intermediate scale in past decades. For soil water content estimation with surface GPR, fixed antenna offset reflection method has been considered to have potential to obtain average soil water content between land surface and reflectors, and provide high resolution and few measurement time. In this study, 900MHz surface GPR antenna was used to estimate SWC with fixed offset reflection method; plant coarse roots (with diameters greater than 5 mm) were regarded as reflectors; a kind of advanced GPR data interpretation method, HADA (hyperbola automatic detection algorithm), was introduced to automatically obtain average velocity by recognizing coarse root hyperbolic reflection signals on GPR radargrams during estimating SWC. In addition, a formula was deduced to determine interval average SWC between two roots at different depths as well. We examined the performance of proposed method on a dataset simulated under different scenarios. Results showed that HADA could provide a reasonable average velocity to estimate SWC without knowledge of root depth and interval average SWC also be determined. When the proposed method was applied to estimation of SWC on a real-field measurement dataset, a very small soil water content vertical variation gradient about 0.006 with depth was captured as well. Therefore, the proposed method could be used to estimate average soil water content from ground penetrating radar coarse root reflections and obtain interval average SWC between two roots at different depths. It is very promising for measuring root-zone-soil-moisture and mapping soil moisture distribution around a shrub or even in field plot scale.

  2. Public-supply water use in Kansas, 1990-2012

    USGS Publications Warehouse

    Kenny, Joan F.

    2014-01-01

    This fact sheet describes water-use data collection and quantities of surface water and groundwater diverted for public supply in Kansas for the years 1990 through 2012. Data used in this fact sheet are from the Kansas Department of Agriculture’s Division of Water Resources and the Kansas Water Office. Water used for public supply represents about 10 percent of all reported water withdrawals in Kansas. Between 1990 and 2012, annual withdrawals for public supply ranged from a low of 121 billion gallons in 1993 to a high of 159 billion gallons in 2012. Differences in annual withdrawals were associated primarily with climatic fluctuations. Six suppliers distributed about one-half of the total water withdrawn for public supply, and nearly three-quarters of the surface water. Surface water represented between 52 and 61 percent of total annual withdrawals for public supply. The proportion of surface water obtained through contracts from Federal reservoirs increased from less than 5 percent in the 1990s to 8 percent in 2011 and 2012. More than 99 percent of the reported water withdrawn for public supply in Kansas in 2012 was metered, which was an increase from 92 percent in 1990. State population increased steadily from 2.5 million people in 1990 to 2.9 million in 2012. Recent estimates indicate that about 95 percent of the total population was served by public water supply; the remainder obtained water from other sources such as private wells. Average per capita water use as calculated for State conservation planning purposes varied by region of the State. The smallest regional average water use for the years 1990–2012 was 98 gallons per person per day in easternmost Kansas, and the largest regional average water use was 274 gallons per person per day in westernmost Kansas.

  3. Climate change and water table fluctuation: Implications for raised bog surface variability

    NASA Astrophysics Data System (ADS)

    Taminskas, Julius; Linkevičienė, Rita; Šimanauskienė, Rasa; Jukna, Laurynas; Kibirkštis, Gintautas; Tamkevičiūtė, Marija

    2018-03-01

    Cyclic peatland surface variability is influenced by hydrological conditions that highly depend on climate and/or anthropogenic activities. A low water level leads to a decrease of peatland surface and an increase of C emissions into the atmosphere, whereas a high water level leads to an increase of peatland surface and carbon sequestration in peatlands. The main aim of this article is to evaluate the influence of hydrometeorological conditions toward the peatland surface and its feedback toward the water regime. A regional survey of the raised bog water table fluctuation and surface variability was made in one of the largest peatlands in Lithuania. Two appropriate indicators for different peatland surface variability periods (increase and decrease) were detected. The first one is an 200 mm y- 1 average net rainfall over a three-year range. The second one is an average annual water depth of 25-30 cm. The application of these indicators enabled the reconstruction of Čepkeliai peatland surface variability during a 100 year period. Processes of peatland surface variability differ in time and in separate parts of peatland. Therefore, internal subbasins in peatland are formed. Subbasins involve autogenic processes that can later affect their internal hydrology, nutrient status, and vegetation succession. Internal hydrological conditions, surface fluctuation, and vegetation succession in peatland subbasins should be taken into account during evaluation of their state, nature management projects, and other peatland research works.

  4. Calm water resistance prediction of a bulk carrier using Reynolds averaged Navier-Stokes based solver

    NASA Astrophysics Data System (ADS)

    Rahaman, Md. Mashiur; Islam, Hafizul; Islam, Md. Tariqul; Khondoker, Md. Reaz Hasan

    2017-12-01

    Maneuverability and resistance prediction with suitable accuracy is essential for optimum ship design and propulsion power prediction. This paper aims at providing some of the maneuverability characteristics of a Japanese bulk carrier model, JBC in calm water using a computational fluid dynamics solver named SHIP Motion and OpenFOAM. The solvers are based on the Reynolds average Navier-Stokes method (RaNS) and solves structured grid using the Finite Volume Method (FVM). This paper comprises the numerical results of calm water test for the JBC model with available experimental results. The calm water test results include the total drag co-efficient, average sinkage, and trim data. Visualization data for pressure distribution on the hull surface and free water surface have also been included. The paper concludes that the presented solvers predict the resistance and maneuverability characteristics of the bulk carrier with reasonable accuracy utilizing minimum computational resources.

  5. Ground-water and surface-water flow and estimated water budget for Lake Seminole, southwestern Georgia and northwestern Florida

    USGS Publications Warehouse

    Dalton, Melinda S.; Aulenbach, Brent T.; Torak, Lynn J.

    2004-01-01

    Lake Seminole is a 37,600-acre impoundment formed at the confluence of the Flint and Chattahoochee Rivers along the Georgia?Florida State line. Outflow from Lake Seminole through Jim Woodruff Lock and Dam provides headwater to the Apalachicola River, which is a major supply of freshwater, nutrients, and detritus to ecosystems downstream. These rivers,together with their tributaries, are hydraulically connected to karst limestone units that constitute most of the Upper Floridan aquifer and to a chemically weathered residuum of undifferentiated overburden. The ground-water flow system near Lake Seminole consists of the Upper Floridan aquifer and undifferentiated overburden. The aquifer is confined below by low-permeability sediments of the Lisbon Formation and, generally, is semiconfined above by undifferentiated overburden. Ground-water flow within the Upper Floridan aquifer is unconfined or semiconfined and discharges at discrete points by springflow or diffuse leakage into streams and other surface-water bodies. The high degree of connectivity between the Upper Floridan aquifer and surface-water bodies is limited to the upper Eocene Ocala Limestone and younger units that are in contact with streams in the Lake Seminole area. The impoundment of Lake Seminole inundated natural stream channels and other low-lying areas near streams and raised the water-level altitude of the Upper Floridan aquifer near the lake to nearly that of the lake, about 77 feet. Surface-water inflow from the Chattahoochee and Flint Rivers and Spring Creek and outflow to the Apalachicola River through Jim Woodruff Lock and Dam dominate the water budget for Lake Seminole. About 81 percent of the total water-budget inflow consists of surface water; about 18 percent is ground water, and the remaining 1 percent is lake precipitation. Similarly, lake outflow consists of about 89 percent surface water, as flow to the Apalachicola River through Jim Woodruff Lock and Dam, about 4 percent ground water, and about 2 percent lake evaporation. Measurement error and uncertainty in flux calculations cause a flow imbalance of about 4 percent between inflow and outflow water-budget components. Most of this error can be attributed to errors in estimating ground-water discharge from the lake, which was calculated using a ground-water model calibrated to October 1986 conditions for the entire Apalachicola?Chattahoochee?Flint River Basin and not just the area around Lake Seminole. Evaporation rates were determined using the preferred, but mathematically complex, energy budget and five empirical equations: Priestley-Taylor, Penman, DeBruin-Keijman, Papadakis, and the Priestley-Taylor used by the Georgia Automated Environmental Monitoring Network. Empirical equations require a significant amount of data but are relatively easy to calculate and compare well to long-term average annual (April 2000?March 2001) pan evaporation, which is 65 inches. Calculated annual lake evaporation, for the study period, using the energy-budget method was 67.2 inches, which overestimated long-term average annual pan evaporation by 2.2 inches. The empirical equations did not compare well with the energy-budget method during the 18-month study period, with average differences in computed evaporation using each equation ranging from 8 to 26 percent. The empirical equations also compared poorly with long-term average annual pan evaporation, with average differences in evaporation ranging from 3 to 23 percent. Energy budget and long-term average annual pan evaporation estimates did compare well, with only a 3-percent difference between estimates. Monthly evaporation estimates using all methods ranged from 0.7 to 9.5 inches and were lowest during December 2000 and highest during May 2000. Although the energy budget is generally the preferred method, the dominance of surface water in the Lake Seminole water budget makes the method inaccurate and difficult to use, because surface water makes up m

  6. Thermal Energy Exchange Model and Water Loss of a Barrel Cactus, Ferocactus acanthodes1

    PubMed Central

    Lewis, Donald A.; Nobel, Park S.

    1977-01-01

    The influences of various diurnal stomatal opening patterns, spines, and ribs on the stem surface temperature and water economy of a CAM succulent, the barrel cactus Ferocactus acanthodes, were examined using an energy budget model. To incorporate energy exchanges by shortwave and longwave irradiation, latent heat, conduction, and convection as well as the heat storage in the massive stem, the plant was subdivided into over 100 internal and external regions in the model. This enabled the average surface temperature to be predicted within 1 C of the measured temperature for both winter and summer days. Reducing the stem water vapor conductance from the values observed in the field to zero caused the average daily stem surface temperature to increase only 0.7 C for a winter day and 0.3 C for a summer day. Thus, latent heat loss does not substantially reduce stem temperature. Although the surface temperatures averaged 18 C warmer for the summer day than for the winter day for a plant 41 cm tall, the temperature dependence of stomatal opening caused the simulated nighttime water loss rates to be about the same for the 2 days. Spines moderated the amplitude of the diurnal temperature changes of the stem surface, since the daily variation was 17 C for the winter day and 25 C for the summer day with spines compared with 23 C and 41 C, respectively, in their simulated absence. Ribs reduced the daytime temperature rise by providing 54% more area for convective heat loss than for a smooth circumscribing surface. In a simulation where both spines and ribs were eliminated, the daytime average surface temperature rose by 5 C. PMID:16660148

  7. Area-averaged evapotranspiration over a heterogeneous land surface: aggregation of multi-point EC flux measurements with a high-resolution land-cover map and footprint analysis

    NASA Astrophysics Data System (ADS)

    Xu, Feinan; Wang, Weizhen; Wang, Jiemin; Xu, Ziwei; Qi, Yuan; Wu, Yueru

    2017-08-01

    The determination of area-averaged evapotranspiration (ET) at the satellite pixel scale/model grid scale over a heterogeneous land surface plays a significant role in developing and improving the parameterization schemes of the remote sensing based ET estimation models and general hydro-meteorological models. The Heihe Watershed Allied Telemetry Experimental Research (HiWATER) flux matrix provided a unique opportunity to build an aggregation scheme for area-averaged fluxes. On the basis of the HiWATER flux matrix dataset and high-resolution land-cover map, this study focused on estimating the area-averaged ET over a heterogeneous landscape with footprint analysis and multivariate regression. The procedure is as follows. Firstly, quality control and uncertainty estimation for the data of the flux matrix, including 17 eddy-covariance (EC) sites and four groups of large-aperture scintillometers (LASs), were carefully done. Secondly, the representativeness of each EC site was quantitatively evaluated; footprint analysis was also performed for each LAS path. Thirdly, based on the high-resolution land-cover map derived from aircraft remote sensing, a flux aggregation method was established combining footprint analysis and multiple-linear regression. Then, the area-averaged sensible heat fluxes obtained from the EC flux matrix were validated by the LAS measurements. Finally, the area-averaged ET of the kernel experimental area of HiWATER was estimated. Compared with the formerly used and rather simple approaches, such as the arithmetic average and area-weighted methods, the present scheme is not only with a much better database, but also has a solid grounding in physics and mathematics in the integration of area-averaged fluxes over a heterogeneous surface. Results from this study, both instantaneous and daily ET at the satellite pixel scale, can be used for the validation of relevant remote sensing models and land surface process models. Furthermore, this work will be extended to the water balance study of the whole Heihe River basin.

  8. Ground-water temperature of the Wyoming quadrangle in central Delaware : with application to ground-water-source heat pumps

    USGS Publications Warehouse

    Hodges, Arthur L.

    1982-01-01

    Ground-water temperature was measured during a one-year period (1980-81) in 20 wells in the Wyoming Quadrangle in central Delaware. Data from thermistors set at fixed depths in two wells were collected twice each week, and vertical temperature profiles of the remaining 18 wells were made monthly. Ground-water temperature at 8 feet below land surface in well Jc55-1 ranged from 45.0 degrees F in February to 70.1 degrees F in September. Temperature at 35 feet below land surface in the same well reached a minimum of 56.0 degrees F in August, and a maximum of 57.8 degrees F in February. Average annual temperature of ground water at 25 feet below land surface in all wells ranged from 54.6 degrees F to 57.8 degrees F. Variations of average temperature probably reflect the presence or absence of forestation in the recharge areas of the wells. Ground-water-source heat pumps supplied with water from wells 30 or more feet below land surface will operate more efficiently in both heating and cooling modes than those supplied with water from shallower depths. (USGS)

  9. Hydrologic reconnaissance of Tsala Apopka Lake, Citrus County, Florida

    USGS Publications Warehouse

    Rutledge, A.T.

    1977-01-01

    The swamps, marshes, and open waters of Tsala Apopka Lake, Florida, were mapped and the hydrologic connection between the lake and the Floridan limestone aquifer was studied from October 1975 to September 1976. Tsala Apopka Lake is a series of shallow , interconnected lakes, ponds, and marshes whose water surface slopes northward at 0.5 foot per mile. According to aerial photographs of December 1972, only 6 percent of the 103 square miles of study area is covered by open water. Open water is abundant along the western side of the lake, dense and sparse marshes occupy most of the lake area, and swamps occupy a thick zone around the Withlacoochee River which borders the lake to the east. Only a small fraction of the total surface flow occurs through the lake. The average lake outflow through S-351 canal is 23.6 cfs; while the average river flow at Holder is 714 cfs. Tsala Apopka Lake is hydraulically connected to the Floridan aquifer. At low flow, the major source of water in the river is ground water from the Floridan aquifer. The specific conductance of water in the Floridan aquifer averages 250-350 umho/cm (micromhos per centimeter) at 25C in this area. The specific conductance of water in the Withlacoochee River near Holder averages 268 umho/cm at 25C, while water in Tsala Apopka Lake at Hernando averages 139 umho/cm at 25C. (Woodard-USGS)

  10. [Further study on possibility of diffusion of Oncomelania hupensis with water in river channels of the east route of South-to-North Water Diversion Project].

    PubMed

    Huang, Yi-Xin; Hang, De-Rong; Tang, Hong-Ping; Sun, Dao-Kuan; Zhou, Can-Hua; Gao, Jin-Bin; Zheng, Bo; Hu, Gui-Quan; Li, Qian; Huang, Yong-Jun; She, Guang-Song; Ren, Zhi-Yuan

    2014-12-01

    To study the drifting law of floats and potential risks of Oncomelania hupensis diffusion in the water diversion rivers of the east route of South-to-North Water Diversion Project. The O. hupensis snails in the river channels were monitored by the salvage method and snail luring method with rice straw curtains, and the diffusion possibility of snails along with water was assessed through the drift test of floats with GPS. In the flood seasons from 2006 to 2013, totally 8 338.0 kg of floats were salvaged, and 2 100 rice straw curtains were put into water in the Li Canal and Jinbao shipping channel, but no Oncomelania snails were found. The drift test of floats with GPS before water diversion showed that the flow velocity on water surface (northbound) was 0.45 m/s, the average drift velocity of the floats was 0.56 - 0.60 m/s, and the average drift distances each time were 999.70 - 1 995.50 m in the Gaoshui River section, while there were no obvious drift in Jinbao shipping channel section. During the water diversion period, the flow velocity on water surface (northbound) was 0.45 m/s, the average drift velocity of the floats was 0.35 - 0.41m/s, and the average drift distances each time were 1 248.06 -1 289.44 m in the Gaoshui River, while in Jinbao shipping channel section, the flow velocity on water surface was 0.28 m/s, the average drift velocity of the floats was 0.25 - 0.27 m/s, and the average drift distances each time were 477.76 - 496.38 m. The drift test showed that the floats gradually closed to the river bank as affected by water flow, wind direction and ship waves, when blocked by the reeds, water plants or other obstacles, and they would stopped and could not continue to drift without outside help. There are no Oncomelania snails found in the river channels of the east route of South-to-North Water Diversion Project. The drifting distance of the floating debris along with the water is restricted by the flow rate and shore environment.

  11. Water budgets for selected watersheds in the Delaware River basin, eastern Pennsylvania and western New Jersey

    USGS Publications Warehouse

    Sloto, Ronald A.; Buxton, Debra E.

    2005-01-01

    This pilot study, done by the U.S. Geological Survey in cooperation with the Delaware River Basin Commission, developed annual water budgets using available data for five watersheds in the Delaware River Basin with different degrees of urbanization and different geological settings. A basin water budget and a water-use budget were developed for each watershed. The basin water budget describes inputs to the watershed (precipitation and imported water), outputs of water from the watershed (streamflow, exported water, leakage, consumed water, and evapotranspiration), and changes in ground-water and surface-water storage. The water-use budget describes water withdrawals in the watershed (ground-water and surface-water withdrawals), discharges of water in the watershed (discharge to surface water and ground water), and movement of water of water into and out of the watershed (imports, exports, and consumed water). The water-budget equations developed for this study can be applied to any watershed in the Delaware River Basin. Data used to develop the water budgets were obtained from available long-term meteorological and hydrological data-collection stations and from water-use data collected by regulatory agencies. In the Coastal Plain watersheds, net ground-water loss from unconfined to confined aquifers was determined by using ground-water-flow-model simulations. Error in the water-budget terms is caused by missing data, poor or incomplete measurements, overestimated or underestimated quantities, measurement or reporting errors, and the use of point measurements, such as precipitation and water levels, to estimate an areal quantity, particularly if the watershed is hydrologically or geologically complex or the data-collection station is outside the watershed. The complexity of the water budgets increases with increasing watershed urbanization and interbasin transfer of water. In the Wissahickon Creek watershed, for example, some ground water is discharged to streams in the watershed, some is exported as wastewater, and some is exported for public supply. In addition, ground water withdrawn outside the watershed is imported for public supply or imported as wastewater for treatment and discharge in the watershed. A GIS analysis was necessary to quantify many of the water-budget components. The 89.9-square mile East Branch Brandywine Creek watershed in Pennsylvania is a rural watershed with reservoir storage that is underlain by fractured rock. Water budgets were developed for 1977-2001. Average annual precipitation, streamflow, and evapotranspiration were 46.89, 21.58, and 25.88 inches, respectively. Some water was imported (average of 0.68 inches) into the watershed for public-water supply and as wastewater for treatment and discharge; these imports resulted in a net gain of water to the watershed. More water was discharged to East Branch Brandywine Creek than was withdrawn from it; the net discharge resulted in an increase in streamflow. Most ground water was withdrawn (average of 0.25 inches) for public-water supply. Surface water was withdrawn (average of 0.58 inches) for public-water and industrial supply. Discharge of water by sewage-treatment plants and industries (average of 1.22 inches) and regulation by Marsh Creek Reservoir caused base flow to appear an average of 7.2 percent higher than it would have been without these additional sources. On average, 67 percent of the difference was caused by sewage-treatment-plant and industrial discharges, and 33 percent was caused by regulation of the Marsh Creek Reservoir. Water imports, withdrawals, and discharges have been increasing as the watershed becomes increasingly urbanized. The 64-square mile Wissahickon Creek watershed in Pennsylvania is an urban watershed underlain by fractured rock. Water budgets were developed for 1987-98. Average annual precipitation, streamflow, and evapotranspiration were 47.23, 22.24, and 23.12 inches, respectively. The watershed is highly u

  12. Ground-water levels in the alluvial aquifer in eastern Arkansas, 1988

    USGS Publications Warehouse

    Westerfield, P.W.; Baxter, C.R.

    1990-01-01

    This report, prepared by the U.S. Geological Survey in cooperation with the Arkansas Soil and Water Conservation Commission, the U.S. Soil Conservation Service, and local Conservation Districts, contains groundwater level measurements of 509 wells that tap the alluvial aquifer in the Quaternary deposits of the Mississippi Alluvial Plain. The measurements were made by district Soil Conservation Service personnel during 1988. The shallowest prepumping season water levels occurred in Ashley, Clay, Greene, Mississippi, Phillips, and Randolph Counties where water levels averaged less than 20 ft below the land surface. The deepest water levels occurred in Arkansas, Lonoke, Poinsett, and Prairie Counties where water levels of more than 100 ft below land surface were measured. Water levels in the postpumping season averaged about 4.1 ft lower than during the prepumping season. (USGS)

  13. Interfacial spreading effects on one-dimensional organic liquid imbibition in water-wetted porous media

    NASA Astrophysics Data System (ADS)

    McBride, J. F.; Simmons, C. S.; Cary, J. W.

    1992-10-01

    The spreading coefficient, Csp, determines whether an organic immiscible liquid, OIL, will form a lens ( Csp < 0) or will spread spontaneously ( Csp > 0) on a water surface. An OIL that forms a lens does not perfectly wet the water surface and therefore has a contact angle greater than 0°. The one-dimensional rate at which an OIL spreads spontaneously on a water surface is proportional to the square root of Csp. Of the OIL's that pose a contaminant threat to the subsurface, the majority has a non-zero Csp. To test the influence of such interfacial spreading phenomena on OIL infiltration in a pristine vadose zone, upward OIL and water imbibition infiltration experiments were performed in glass-bead columns, moistened with water, by using OIL's with different Csp. An analytical model for saturated liquid front rise was used to inversely estimate the effective capillary pressure head at the front and the average liquid conductivity. A nonspreading OIL ( Csp ≪ 0) exhibited a reduced capillary pressure head in the water-wetted glass beads. A spontaneously spreading OIL ( Csp ≫0) manifested an enhanced capillary pressure head. Reduced capillary pressure head was associated with an increase in average conductivity, and enhanced capillary pressure head was associated with a decrease in average conductivity when compared to the average water conductivity during water imbibition. The employed experimental method and mathematical analysis of dynamic flow, subject to interfacial spreading phenomena, are practical for quantifying parameters for use in sharp-front OIL infiltration models, but more research is needed to determine how to incorporate the spreading coefficient in numerical multiphase flow models.

  14. Sectoral contributions to surface water stress in the coterminous United States

    NASA Astrophysics Data System (ADS)

    Averyt, K.; Meldrum, J.; Caldwell, P.; Sun, G.; McNulty, S.; Huber-Lee, A.; Madden, N.

    2013-09-01

    Here, we assess current stress in the freshwater system based on the best available data in order to understand possible risks and vulnerabilities to regional water resources and the sectors dependent on freshwater. We present watershed-scale measures of surface water supply stress for the coterminous United States (US) using the water supply stress index (WaSSI) model which considers regional trends in both water supply and demand. A snapshot of contemporary annual water demand is compared against different water supply regimes, including current average supplies, current extreme-year supplies, and projected future average surface water flows under a changing climate. In addition, we investigate the contributions of different water demand sectors to current water stress. On average, water supplies are stressed, meaning that demands for water outstrip natural supplies in over 9% of the 2103 watersheds examined. These watersheds rely on reservoir storage, conveyance systems, and groundwater to meet current water demands. Overall, agriculture is the major demand-side driver of water stress in the US, whereas municipal stress is isolated to southern California. Water stress introduced by cooling water demands for power plants is punctuated across the US, indicating that a single power plant has the potential to stress water supplies at the watershed scale. On the supply side, watersheds in the western US are particularly sensitive to low flow events and projected long-term shifts in flow driven by climate change. The WaSSI results imply that not only are water resources in the southwest in particular at risk, but that there are also potential vulnerabilities to specific sectors, even in the ‘water-rich’ southeast.

  15. Potentiometric Surface of the Upper Floridan Aquifer, West-central Florida, May 2010

    USGS Publications Warehouse

    Ortiz, A.G.

    2010-01-01

    The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing fresh water are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in May 2010. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the dry season, when groundwater levels usually are at an annual low and withdrawals for agricultural use typically are high. The cumulative average rainfall of 55.21 inches for west-central Florida (from June 2009 through May 2010) was 2.55 inches above the historical cumulative average of 52.66 inches (Southwest Florida Water Management District, 2010). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the U.S. Geological Survey during the period May 17-21, 2010. Supplemental water-level data were collected by other agencies and companies. Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a 'snapshot' of conditions at a specific time, nor do they necessarily coincide with the seasonal low water-level condition.

  16. Using Smoke Injection in Drains to Identify Potential Preferential Pathways in a Drained Arable Field

    NASA Astrophysics Data System (ADS)

    Nielsen, M. H.; Petersen, C. T.; Hansen, S.

    2014-12-01

    Macropores forming a continuous pathway between the soil surface and subsurface drains favour the transport of many contaminants from agricultural fields to surface waters. The smoke injection method presented by Shipitalo and Gibbs (2000) used for demonstrating and quantifying such pathways has been further developed and used on a drained Danish sandy loam. In order to identify the preferential pathways to drains, smoke was injected in three 1.15 m deep tile drains (total drain length 93 m), and smoke emitting macropores (SEMP) at the soil surface were counted and characterized as producing either strong or weak plumes compared to reference plumes from 3 and 6 mm wide tubes. In the two situations investigated in the present study - an early spring and an autumn situation, smoke only penetrated the soil surface layer via earthworm burrows located in a 1.0 m wide belt directly above the drain lines. However, it is known from previous studies that desiccation fractures in a dry summer situation also can contribute to the smoke pattern. The distance between SEMP measured along the drain lines was on average 0.46 m whereas the average spacing between SEMP with strong plumes was 2.3 m. Ponded water was applied in 6 cm wide rings placed above 52 burrows including 17 reference burrows which did not emit smoke. Thirteen pathways in the soil were examined using dye tracer and profile excavation. SEMP with strong plumes marked the entrance of highly efficient transport pathways conducting surface applied water and dye tracer into the drain. However, no single burrow was traced all the way from the surface into the drain, the dye patterns branched off in a network of other macropores. Water infiltration rates were significantly higher (P < 0.05) in SEMP with strong plumes (average rate: 247 mL min-1 n = 19) compared to SEMP with weak plumes (average rate: 87 mL min-1 n = 16) and no plumes (average rate: 56 mL min-1 n = 17). The results suggest that the smoke injection method is useful for identification of potentially efficient pathways for surface applied contaminants to drains and surface waters, pathways being associated primarily with unevenly distributed SEMP producing strong smoke plumes.

  17. Characterization of water quality and biological communities, Fish Creek, Teton County, Wyoming, 2007-08

    USGS Publications Warehouse

    Eddy-Miller, Cheryl A.; Peterson, David A.; Wheeler, Jerrod D.; Leemon, Daniel J.

    2010-01-01

    Fish Creek, a tributary to the Snake River, is about 25 river kilometers long and is located in Teton County in western Wyoming near the town of Wilson. Public concern about nuisance growths of aquatic plants in Fish Creek have been increasing in recent years. To address this concern, the U.S. Geological Survey conducted a study in cooperation with the Teton Conservation District to characterize the water quality and biological communities in Fish Creek. Water-quality samples were collected for analyses of physical properties and water chemistry (nutrients, nitrate isotopes, and wastewater chemicals) between March 2007 and October 2008 from seven surface-water sites and three groundwater wells. During this same period, aquatic plant and macroinvertebrate samples were collected and habitat characteristics were measured at the surface-water sites. The main objectives of this study were to (1) evaluate nutrient concentrations (that influence biological indicators of eutrophication) and potential sources of nutrients by using stable isotope analysis and other indicator chemicals (such as caffeine and disinfectants) that could provide evidence of anthropogenic sources, such as wastewater or septic tank contamination in Fish Creek and adjacent groundwater, and (2) characterize the algal, macrophyte, and macroinvertebrate communities and habitat of Fish Creek. Nitrate was the dominant species of dissolved nitrogen present in all samples and was the only bioavailable species detected at concentrations greater than the laboratory reporting level in all surface-water samples. Average concentrations of dissolved nitrate in surface water were largest in samples collected from the two sites with seasonal flow near Teton Village and decreased downstream; the smallest concentration was at downstream site A-Wck. Concentrations of dissolved nitrate in groundwater were consistently greater than concentrations in corresponding surface-water sites during the same sampling event. Orthophosphate was the primary dissolved species of phosphorus present in all surface-water and groundwater samples. The average concentration of dissolved orthophosphate in surface water was largest in samples collected from near Teton Village; samples from all other sites had similar average concentrations. Concentrations of dissolved orthophosphate in groundwater also were typically greater than concentrations in corresponding surface-water sites during the same sampling event. The aquatic plant communities in Fish Creek typically were composed of a mixture of macrophytes, macroalgae, microalgae, and moss. The composition of the aquatic plant community in Fish Creek appeared to shift in the downstream direction in 2007. On average, the proportion of macrophytes ranged from about 1 percent at site A-R1U, the most upstream site, to 54 percent of the plant community at site A-R6D, the farthest downstream site sampled during 2007. The downstream increase in macrophytes was accompanied by a downstream decrease in microalgae. The average proportion of microalgae ranged from 80 percent at site A-R1U to 24 percent at site A-R6D. The proportion of the macroalgae Cladophora in the aquatic plant community was relatively high at sites A-Wck and A-R3D in both 2007 and 2008.

  18. Influence of multi-industrial activities on trace metal contamination: an approach towards surface water body in the vicinity of Dhaka Export Processing Zone (DEPZ).

    PubMed

    Ahmed, Golam; Miah, M Arzu; Anawar, Hossain M; Chowdhury, Didarul A; Ahmad, Jasim U

    2012-07-01

    Industrial wastewater discharged into aquatic ecosystems either directly or because of inadequate treatment of process water can increase the concentrations of pollutants such as toxic metals and others, and subsequently deteriorate water quality, environmental ecology and human health in the Dhaka Export Processing Zone (DEPZ), the largest industrial belt of 6-EPZ in Bangladesh. Therefore, in order to monitor the contamination levels, this study collected water samples from composite effluent points inside DEPZ and the surrounding surface water body connected to effluent disposal sites and determined the environmental hazards by chemical analysis and statistical approach. The water samples were analysed by inductively coupled plasma mass spectrometry to determine 12 trace metals such as As, Ag, Cr, Co, Cu, Li, Ni, Pb, Se, Sr, V and Zn in order to assess the influence of multi-industrial activities on metal concentrations. The composite effluents and surface waters from lagoons were characterized by a strong colour and high concentrations of biochemical oxygen demand, chemical oxygen demand, electrical conductivity, pH, total alkalinity, total hardness, total organic carbon, Turb., Cl(-), total suspended solids and total dissolved solids, which were above the limit of Bangladesh industrial effluent standards, but dissolved oxygen concentration was lower than the standard value. The measurement of skewness and kurtosis values showed asymmetric and abnormal distribution of the elements in the respective phases. The mean trend of variation was found in a decreasing order: Zn > Cu > Sr > Pb > Ni > Cr > Li > Co > V > Se > As > Ag in composite industrial effluents and Zn > Cu > Sr > Pb > Ni > Cr > Li > V > As > Ag > Co > Se in surface waters near the DEPZ. The strong correlations between effluent and surface water metal contents indicate that industrial wastewaters discharged from DEPZ have a strong influence on the contamination of the surrounding water bodies by toxic metals. The average contamination factors were reported to be 0.70-96.57 and 2.85-1,462 for industrial effluents and surface waters, respectively. The results reveal that the surface water in the area is highly contaminated with very high concentrations of some heavy/toxic metals like Zn, Pb, Cu, Ni and Cr; their average contamination factors are 1,460, 860, 136, 74.71 and 4.9, respectively. The concentrations of the metals in effluent and surface water were much higher than the permissible limits for drinking water and the world average concentrations in surface water. Therefore, the discharged effluent and surface water may create health hazards especially for people working and living inside and in the surrounding area of DEPZ.

  19. Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, September 2007

    USGS Publications Warehouse

    Ortiz, A.G.

    2008-01-01

    The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing fresh water are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in September 2007. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the wet season, when ground-water levels usually are at an annual high and withdrawals for agricultural use typically are low. The cumulative average rainfall of 39.50 inches for west-central Florida (from October 2006 through September 2007) was 13.42 inches below the historical cumulative average of 52.92 inches (Southwest Florida Water Management District, 2007). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the U.S. Geological Survey during the period September 17-21, 2007. Supplemental water-level data were collected by other agencies and companies. A corresponding potentiometric-surface map was prepared for areas east and north of the Southwest Florida Water Management District boundary by the U.S. Geological Survey office in Orlando, Florida (Kinnaman and Dixon, 2008). Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a 'snapshot' of conditions at a specific time, nor do they necessarily coincide with the seasonal high water-level condition.

  20. Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, September 2008

    USGS Publications Warehouse

    Ortiz, Anita G.

    2009-01-01

    The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing fresh water are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in September 2008. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the wet season, when ground-water levels usually are at an annual high and withdrawals for agricultural use typically are low. The cumulative average rainfall of 50.63 inches for west-central Florida (from October 2007 through September 2008) was 2.26 inches below the historical cumulative average of 52.89 inches (Southwest Florida Water Management District, 2008). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the U.S. Geological Survey during the period September 15-19, 2008. Supplemental water-level data were collected by other agencies and companies. A corresponding potentiometric-surface map was prepared for areas east and north of the Southwest Florida Water Management District boundary by the U.S. Geological Survey office in Orlando, Florida (Kinnaman and Dixon, 2009). Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a 'snapshot' of conditions at a specific time, nor do they necessarily coincide with the seasonal high water-level condition.

  1. Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, May 2008

    USGS Publications Warehouse

    Ortiz, A.G.

    2008-01-01

    The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing fresh water are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in May 2008. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the dry season, when ground-water levels usually are at an annual low and withdrawals for agricultural use typically are high. The cumulative average rainfall of 46.95 inches for west-central Florida (from June 2007 through May 2008) was 5.83 inches below the historical cumulative average of 52.78 inches (Southwest Florida Water Management District, 2008). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the U.S. Geological Survey during the period May 19-23, 2008. Supplemental water-level data were collected by other agencies and companies. A corresponding potentiometric-surface map was prepared for areas east and north of the Southwest Florida Water Management District boundary by the U.S. Geological Survey office in Orlando, Florida (Kinnaman and Dixon, 2008). Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a 'snapshot' of conditions at a specific time, nor do they necessarily coincide with the seasonal low water-level condition.

  2. Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, May 2007

    USGS Publications Warehouse

    Ortiz, A.G.

    2008-01-01

    The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing fresh water are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in May 2007. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the dry season, when ground-water levels usually are at an annual low and withdrawals for agricultural use typically are high. The cumulative average rainfall of 41.21 inches for west-central Florida (from June 2006 through May 2007) was 11.63 inches below the historical cumulative average of 52.84 inches (Southwest Florida Water Management District, 2007). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the U.S. Geological Survey during the period May 21-25, 2007. Supplemental water-level data were collected by other agencies and companies. A corresponding potentiometric-surface map was prepared for areas east and north of the Southwest Florida Water Management District boundary by the U.S. Geological Survey office in Orlando, Florida (Kinnaman and Dixon, 2007). Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a 'snapshot' of conditions at a specific time, nor do they necessarily coincide with the seasonal low water-level condition.

  3. Water resources of the Humboldt River Valley near Winnemucca, Nevada

    USGS Publications Warehouse

    Cohen, Philip M.

    1965-01-01

    This report, resulting from studies made by the U.S. Geological Survey as part of the interagency Humboldt River Research Project, describes the qualitative and quantitative relations among the components of the hydrologic system in the Winnemucca Reach of the Humboldt River valley. The area studied includes the segment of the Humboldt River valley between the Comus and Rose Creek gaging stations. It is almost entirely in Humboldt County in north-central Nevada, and is about 200 miles downstream from the headwaters of the Humboldt River. Agriculture is the major economic activity in the area. Inasmuch as the valley lowlands receive an average of about 8 inches of precipitation per year and because the rate of evaporation from free-water surfaces is about six times the average annual precipitation, all crops in the area (largely forage crops) are irrigated. About 85 percent of the cultivated land is irrigated with Humboldt River water; the remainder is irrigated from about 20 irrigation wells. The consolidated rocks of the uplifted fault-block mountains are largely barriers to the movement of ground water and form ground-water and surface-water divides. Unconsolidated deposits of late Tertiary and Quaternary age underlie the valley lowlands to a maximum depth of about 5,000 feet. These deposits are in hydraulic continuity with the Humboldt River and store and transmit most of the economically recoverable ground water. Included in the valley fill is a highly permeable sand and gravel deposit having a maximum thickness of about 90-100 feet; it underlies the flood plain and bordering terraces throughout most of the project area. This deposit is almost completely saturated and contains about 500,000 acre-feet of ground water in storage. The Humboldt River is the source of 90-95 percent of the surface-water inflow to the area. In water years 1949-62 the average annual streamflow at the Comus gaging station at the upstream margin of the area was 172,100 acre-feet; outflow at the Rose Creek gaging station averaged about 155,400 acre-feet. Accordingly, the measured loss of Humboldt River streamflow averaged nearly 17,000 acre-feet per year. Most of this water was transpired by phreatophytes and crops, evaporated from free-water surfaces, and evaporated from bare soil. Inasmuch as practically no tributary streamflow normally discharges into the river in the Winnemucca reach and because pumpage is virtually negligible during the nonirrigation season, gains and losses of streamflow during most of the year reflect the close interrelation of the Humboldt River and the groundwater reservoir. An estimated average of about 14,000 acre-feet per year of ground-water underflow moves toward the Humboldt River from tributary areas. Much of this water discharges into the Humboldt River; hovever, some evaporates or is transpired before reaching the river. More than 65 percent of the average annual flow of the river horn-ally occurs in April, May, and June owing to the spring runoff. The stage of the river generally rises rapidly during these months causing water to move from the river to the ground-water reservoir. Furthermore, the period of high streamflow normally coincides with the irrigation season, and much of the excess irrigation water diverted from the river percolates downward to the zone of saturation. The net measured loss of streamflow in April-June, which averaged about 24,000 acre-feet in water years 1949-62, was about 7,000 acre-feet more than the average annual loss. The estimated net average annual increase of ground water in storage during these months in this period was on the order of 10,000 acre-feet. Following the spring runoff and the irrigation season, normally in July, some of the ground water stored in the flood-plain deposits during the spring runoff begins to discharge into the river. In addition, ground-water inflow from tributary areas again begins to discharge into the river. Experiments utilizin

  4. Potentiometric surface of the upper Floridan aquifer, west-central Florida, May 2011

    USGS Publications Warehouse

    Ortiz, Anita G.

    2011-01-01

    The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing freshwater are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in May 2011. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the dry season, when groundwater levels usually are at an annual low and withdrawals for agricultural use typically are high. The cumulative average rainfall of 45.74 inches for west-central Florida (from June 2010 through May 2011) was 6.85 inches below the historical cumulative average of 52.59 inches (Southwest Florida Water Management District, 2011). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September from 1975 through 2010. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the U.S. Geological Survey during the period May 23-27, 2011. Supplemental water-level data were collected by other agencies and companies. Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a "snapshot" of conditions at a specific time, nor do they necessarily coincide with the seasonal low water-level condition.

  5. Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, September 2006

    USGS Publications Warehouse

    Ortiz, A.G.

    2007-01-01

    The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing freshwater are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in September 2006. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the wet season, when ground-water levels usually are at an annual high and withdrawals for agricultural use typically are low. The cumulative average rainfall of 46.06 inches for west-central Florida (from October 2005 through September 2006) was 6.91 inches below the historical cumulative average of 52.97 inches (Southwest Florida Water Management District, 2006). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the U.S. Geological Survey during September 18-22, 2006. Supplemental water-level data were collected by other agencies and companies. A corresponding potentiometric-surface map was prepared for areas east and north of the Southwest Florida Water Management District boundary by the U.S. Geological Survey office in Orlando, Florida (Kinnaman, 2007). Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a 'snapshot' of conditions at a specific time, nor do they necessarily coincide with the seasonal high water-level condition.

  6. Potentiometric surface of the Upper Floridan aquifer, west-central Florida, September 2005

    USGS Publications Warehouse

    Ortiz, A.G.

    2006-01-01

    The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing freshwater are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public-supply, domestic use, irrigation, and brackish-water desalination in coastal communities (Southwest Florida Water Management District, 2000).This map report shows the potentiometric surface of the Upper Floridan aquifer measured in September 2005. The potentiometric surface is an imaginary surface, connecting points of equal altitude to which water will rise in tightly cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the wet season, when ground-water levels usually are at an annual high and withdrawals for agricultural use typically are low. The cumulative average rainfall of 55.19 inches for west-central Florida (from October 2004 through September 2005) was 2.00 inches above the historical cumulative average of 53.19 inches (Southwest Florida Water Management District, 2005). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District.This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the U.S. Geological Survey during the period September 19-23, 2005. Supplemental water-level data were collected by other agencies and companies. A corresponding potentiometric-surface map was prepared for areas east and north of the Southwest Florida Water Management District boundary by the U.S. Geological Survey office in Altamonte Springs, Florida (Kinnaman, 2006). Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a "snapshot" of conditions at a specific time, nor do they necessarily coincide with the seasonal high water-level condition.

  7. Soil moisture content estimation using ground-penetrating radar reflection data

    NASA Astrophysics Data System (ADS)

    Lunt, I. A.; Hubbard, S. S.; Rubin, Y.

    2005-06-01

    Ground-penetrating radar (GPR) reflection travel time data were used to estimate changes in soil water content under a range of soil saturation conditions throughout the growing season at a California winery. Data were collected during three data acquisition campaigns over an 80 by 180 m area using 100 MHz surface GPR antennas. GPR reflections were associated with a thin, low permeability clay layer located 0.8-1.3 m below the ground surface that was identified from borehole information and mapped across the study area. Field infiltration tests and neutron probe logs suggest that the thin clay layer inhibited vertical water flow, and was coincident with high volumetric water content (VWC) values. The GPR reflection two-way travel time and the depth of the reflector at the borehole locations were used to calculate an average dielectric constant for soils above the reflector. A site-specific relationship between the dielectric constant and VWC was then used to estimate the depth-averaged VWC of the soils above the reflector. Compared to average VWC measurements from calibrated neutron probe logs over the same depth interval, the average VWC estimates obtained from GPR reflections had an RMS error of 0.018 m 3 m -3. These results suggested that the two-way travel time to a GPR reflection associated with a geological surface could be used under natural conditions to obtain estimates of average water content when borehole control is available and the reflection strength is sufficient. The GPR reflection method therefore, has potential for monitoring soil water content over large areas and under variable hydrological conditions.

  8. Air-Water Exchange of Legacy and Emerging Organic Pollutants across the Great Lakes

    NASA Astrophysics Data System (ADS)

    Lohmann, R.; Ruge, Z.; Khairy, M.; Muir, D.; Helm, P.

    2014-12-01

    Organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) are transported to great water bodies via long-range atmospheric transport and released from the surface water as air concentrations continue to diminish. As the largest fresh water bodies in North America, the Great Lakes have both the potential to accumulate and serve as a secondary source of persistent bioaccumulative toxins. OCP and PCB concentrations were sampled at 30+ sites across Lake Superior, Ontario and Erie in the summer of 2011. Polyethylene passive samplers (PEs) were simultaneously deployed in surface water and near surface atmosphere to determine air-water gaseous exchange of OCPs and PCBs. In Lake Superior, surface water and atmospheric concentrations were dominated by α-HCH (average 250 pg/L and 4.2 pg/m3, respectively), followed by HCB (average 17 pg/L and 89 pg/m3, respectively). Air-water exchange varied greatly between sites and individual OCPs, however α-endosulfan was consistently deposited into the surface water (average 19 pg/m2/day). PCBs in the air and water were characterized by penta- and hexachlorobiphenyls with distribution along the coast correlated with proximity to developed areas. Air-water exchange gradients generally yielded net volatilization of PCBs out of Lake Superior. Gaseous concentrations of hexachlorobenzene, dieldrin and chlordanes were significantly higher (p < 0.05) at Lake Erie than Lake Ontario. A multiple linear regression that incorporated meteorological, landuse and population data was used to explain variability in the atmospheric concentrations. Results indicated that landuse (urban and/or cropland) greatly explained the variability in the data. Freely dissolved concentrations of OCPs (

  9. Bio-Optical Properties and Ocean Color Algorithms for Coastal Waters Influenced by the Mississippi River During a Cold Front Passage

    NASA Technical Reports Server (NTRS)

    D'Sa Eurico J.; Miller, Richard L.; DelCastillo, Carlos

    2006-01-01

    During the passage of a cold front in March 2002, bio-optical properties examined in coastal waters impacted by the Mississippi River indicated westward advective flows and increasing river discharge containing a larger nonalgal particle content contributed significantly to surface optical variability. A comparison of seasonal data from three cruises indicated spectral models of absorption and scattering to be generally consistent with other coastal environments, while their parameterization in terms of chlorophyll a concentration (Chl) showed seasonal variability. The exponential slope of the colored dissolved organic matter (CDOM) averaged 0.0161 plus or minus 0.00054 per nanometer, and for nonalgal absorption it averaged 0.011 per nanometer with deviations from general trends observed due to anomalous water properties. Although the phytoplankton specific absorption coefficients varied over a wide range (0.02 to 0.1 square meters (mg Chl) sup -1)) being higher in offshore surface waters, values of phytoplankton absorption spectra at the SeaWiFS wavebands were highly correlated to modeled values. The normalized scattering spectral shapes and the mean spectrum were in agreement to observations in other coastal waters, while the backscattering ratios were on average lower in phytoplankton dominated surface waters (0.0101 plus or minus 0.002) and higher in near-bottom waters (0.0191 plus or minus 0.0045) with low Chl. Average percent differences in remote sensing reflectance R (sub rs) derived form modeled and in-eater radiometric measurements were highest in the blue wavebands (52%) and at sampling stations with a ore stratified water column. Estimates of Chl and CDOM absorption derived from SeaWiFS images generated using regional empirical algorithms were highly correlated to in situ data.

  10. The geochemical characteristics of soil water and epikarst springs and their response to vegetation-soil degradation in a karst area

    NASA Astrophysics Data System (ADS)

    Xiao, D. A.; Xu, H.

    2012-04-01

    Samples of soil waters and epi-karst springs in four vegetation types were collected at Maolan nature reserve in Libo county, which including protogenetic arbors, secondary arbor-shrub, shrubs and shrub-grass, to analyze their hydro-geochemical properties and the variations of nutrient elements, and further to illustrate the intrinsic correlations of vegetation, soil, environment changes and their geochemical information. The conclusions have been concluded as follows: (1) The pH of soil waters in the study area varies between 5.32 and 7.93, with a mean value of 6.78, and the conductivity changes between 31.82 and 353.65 μS/cm, with a mean value of 126.19 μS/cm. Both descend as the vegetation degrades. The hydro-chemistry of soil waters are Ca- HCO3-, and their ions mainly consist of Ca2+, Mg2+, HCO3-, SO42-. Ca2+, Mg2+, HCO3-are very sensitive to vegetations degradation. Ion contents are high in rain seasons and low in dry ones. (2) The pH of surface karst springs in the study area vary between 6.7 and 8.42, with a mean value of 7.65, and the conductivity between 125.6 and 452 μS/cm, with a mean value of 288.09 μS/cm. The hydro-chemistry of surface karst springs are Ca- HCO3-. HCO3-and SO42-are the main anions while Ca2+and Mg2+as main cations. The chemical properties and geochemical process of surface springs are mainly controlled by the solubility equilibrium of carbonate rocks, thus not sensitive to vegetation degradations. (3) All the calcite saturation indices of soil waters in four vegetation types are below 0, while most indices of surface karst springs are above 0, demonstrating greater denudation of soil waters than surface karst springs. As soil waters flow to surface springs, the partial pressure of CO2decreases, the denudation of water lessens, and saturation index, Ca2+, HCO3-, consequently, pH and conductivity increase. (4) Inorganic nitrogen in soil waters exist mainly as N-NO3- and N-NH4+, accounting ~ 95% of the 3 Ns. As vegetation degrades, nitrate nitrogen, organic nitrogen and total nitrogen change in follow way, protogenetic arbors > secondary arbor-shrub, shrubs > shrub-grass, but the differences among all vegetation types are not prominent. Ammonia nitrogen, however, changes otherwise as follows: shrubs, shrub-grass > protogenetic arbors, secondary arbor-shrub. In surface springs, few inorganic nitrogen exists as NO2--N ( 2 μg/L on average ), and most exists as NO3-N ( 215 μg/L on average ), and NH4+-N is 185μg/L on average. In general, NH4+-N, NO3--N and TN formations in the four vegetation types are: protogenetic arbors > secondary arbor-shrub > shrubs > shrub-grass. (5) DOC content in soil waters vary between 1.88 and 10.37 mg/L, with an average 4.8 mg/L. DOC content in surface karst springs changes between 0.39 and 9.98 mg/L, with an average 2.25 mg/L. DOCs in soil waters are greater than those in surface karst springs in all four vegetation types, and have sharp differences ( P≤0.01 ). DOCs in soil waters and surface karst springs share a great relationship and a similar change tendency, which well illustrates a main source of surface springs from soil waters. In both of them, DOCs are larger in original vegetations than in degraded vegetations. This is because the soil-vegetation system is stable in an original ecology environment which free from outside disturbs. By contrast, a degraded system is unstable, weak at beating disturbs, and conserves less but loses more. Key words: soil waters, epi-karst springs, hydro-geochemical, vegetation, karst area, Maolan in Guizhou

  11. Persistence and distribution of 4-nonylphenol in water, sediment, macrophytes, and wall material of littoral enclosures

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Heinis, L.J.; Tunell, R.; Liber, K.

    1994-12-31

    Eighteen enclosures (5 m x 10 m) were constructed in the littoral zone of a 2-ha pond near Duluth, MN. Each enclosure consisted of 5 m of natural shoreline and three walls of an inert plastic. The enclosures had an average surface area of 31.9 m{sup 2} , an average depth of 0.6 m and an average water volume of 33.1 m{sup 3}. The enclosure waters were treated with the alkyl phenol ethoxylate precursor and degradation product 4-nonylphenol. Application was accomplished by sub-surface injection over a 20-day period with a 2 day frequency. Nominal aqueous concentrations were 0, 3, 30,more » 100 and 300 {mu}g/L. Concentrations of 4-nonylphenol were monitored during and after application in the water, sediment, macrophytes, and enclosure wall material. Average maximum water concentrations ranged from 96.5% of nominal to 62.0% of nominal and average minimum water concentrations ranged from 33.3% of nominal to 29.5% of nominal during the application period. Water concentrations decreased exponentially after application ended. Sediment concentrations during the application period were constant from 8 to 20 d and peak concentrations occurred 48 d after application began. Macrophyte concentrations peaked 21 d after initial application with a steady decline through 76 d. Enclosure wall material concentrations reached a peak 3 h before the final application. A gradual decline occurred until 34 d after initial application followed by a more rapid dissipation.« less

  12. Hydrology, description of computer models, and evaluation of selected water-management alternatives in the San Bernardino area, California

    USGS Publications Warehouse

    Danskin, Wesley R.; McPherson, Kelly R.; Woolfenden, Linda R.

    2006-01-01

    The San Bernardino area of southern California has complex water-management issues. As an aid to local water managers, this report provides an integrated analysis of the surface-water and ground-water systems, documents ground-water flow and constrained optimization models, and provides seven examples using the models to better understand and manage water resources of the area. As an aid to investigators and water managers in other areas, this report provides an expanded description of constrained optimization techniques and how to use them to better understand the local hydrogeology and to evaluate inter-related water-management problems. In this report, the hydrology of the San Bernardino area, defined as the Bunker Hill and Lytle Creek basins, is described and quantified for calendar years 1945-98. The major components of the surface-water system are identified, and a routing diagram of flow through these components is provided. Annual surface-water inflow and outflow for the area are tabulated using gaged measurements and estimated values derived from linear-regression equations. Average inflow for the 54-year period (1945-98) was 146,452 acre-feet per year; average outflow was 67,931 acre-feet per year. The probability of exceedance for annual surface-water inflow is calculated using a Log Pearson Type III analysis. Cumulative surface-water inflow and outflow and ground-water-level measurements indicate that the relation between the surface-water system and the ground-water system changed in about 1951, in about 1979, and again in about 1992. Higher ground-water levels prior to 1951 and between 1979 and 1992 induced ground-water discharge to Warm Creek. This discharge was quantified using streamflow measurements and can be estimated for other time periods using ground-water levels from a monitoring well (1S/4W-3Q1) and a logarithmic-regression equation. Annual wastewater discharge from the area is tabulated for the major sewage and power-plant facilities. More...

  13. Seasonality of change: Summer warming rates do not fully represent effects of climate change on lake temperatures

    USGS Publications Warehouse

    Winslow, Luke; Read, Jordan S.; Hansen, Gretchen J. A.; Rose, Kevin C.; Robertson, Dale M.

    2017-01-01

    Responses in lake temperatures to climate warming have primarily been characterized using seasonal metrics of surface-water temperatures such as summertime or stratified period average temperatures. However, climate warming may not affect water temperatures equally across seasons or depths. We analyzed a long-term dataset (1981–2015) of biweekly water temperature data in six temperate lakes in Wisconsin, U.S.A. to understand (1) variability in monthly rates of surface- and deep-water warming, (2) how those rates compared to summertime average trends, and (3) if monthly heterogeneity in water temperature trends can be predicted by heterogeneity in air temperature trends. Monthly surface-water temperature warming rates varied across the open-water season, ranging from 0.013 in August to 0.073°C yr−1 in September (standard deviation [SD]: 0.025°C yr−1). Deep-water trends during summer varied less among months (SD: 0.006°C yr−1), but varied broadly among lakes (–0.056°C yr−1 to 0.035°C yr−1, SD: 0.034°C yr−1). Trends in monthly surface-water temperatures were well correlated with air temperature trends, suggesting monthly air temperature trends, for which data exist at broad scales, may be a proxy for seasonal patterns in surface-water temperature trends during the open water season in lakes similar to those studied here. Seasonally variable warming has broad implications for how ecological processes respond to climate change, because phenological events such as fish spawning and phytoplankton succession respond to specific, seasonal temperature cues.

  14. Insights Into the Biogeochemical Cycling of Iron, Nitrate, and Phosphate Across a 5,300 km South Pacific Zonal Section (153°E-150°W)

    NASA Astrophysics Data System (ADS)

    Ellwood, Michael J.; Bowie, Andrew R.; Baker, Alex; Gault-Ringold, Melanie; Hassler, Christel; Law, Cliff S.; Maher, William A.; Marriner, Andrew; Nodder, Scott; Sander, Sylvia; Stevens, Craig; Townsend, Ashley; van der Merwe, Pier; Woodward, E. Malcolm S.; Wuttig, Kathrin; Boyd, Philip W.

    2018-02-01

    Iron, phosphate, and nitrate are essential nutrients for phytoplankton growth, and hence, their supply into the surface ocean controls oceanic primary production. Here we present a GEOTRACES zonal section (GP13; 30-33°S, 153°E-150°W) extending eastward from Australia to the oligotrophic South Pacific Ocean gyre outlining the concentrations of these key nutrients. Surface dissolved iron concentrations are elevated at >0.4 nmol L-1 near continental Australia (west of 165°E) and decreased eastward to ≤0.2 nmol L-1 (170°W-150°W). The supply of dissolved iron into the upper ocean (<100 m) from the atmosphere and vertical diffusivity averaged 11 ± 10 nmol m-2 d-1. In the remote South Pacific Ocean (170°W-150°W), atmospherically sourced iron is a significant contributor to the surface dissolved iron pool with average supply contribution of 23 ± 17% (range 3% to 55%). Surface water nitrate concentrations averaged 5 ± 4 nmol L-1 between 170°W and 150°W, while surface water phosphate concentrations averaged 58 ± 30 nmol L-1. The supply of nitrogen into the upper ocean is primarily from deeper waters (24-1647 μmol m-2 d-1) with atmospheric deposition and nitrogen fixation contributing <1% to the overall flux along the eastern part of the transect. The deep water N:P ratio averaged 14.5 ± 0.5 but declined to <1 above the deep chlorophyll maximum (DCM) indicating a high N:P assimilation ratio by phytoplankton leading to almost quantitative removal of nitrate. The supply stoichiometry for iron and nitrogen relative to phosphate at and above the DCM declines eastward leading to two biogeographical provinces: one with diazotroph production and the other without diazotroph production.

  15. Assessment of the Unintentional Reuse of Municipal Wastewater

    NASA Astrophysics Data System (ADS)

    Okasaki, S.; Fono, L.; Sedlak, D. L.; Dracup, J. A.

    2002-12-01

    Many surface waters that receive wastewater effluent also serve as source waters for drinking water treatment plants. Recent research has shown that a number of previously undiscovered wastewater-derived contaminants are present in these surface waters, including pharmaceuticals and human hormones, several of which are suspected carcinogens or endocrine disrupters and are, as of yet, unregulated through drinking water standards. This research has been designed to determine the extent of contamination of specific wastewater-derived contaminants in surface water bodies that both receive wastewater effluent and serve as a source of drinking water to a sizeable population. We are testing the hypothesis that surface water supplies during low flow are potentially of worse quality than carefully monitored reclaimed water. The first phase of our research involves: (1) the selection of sites for study; (2) a hydrologic analysis of the selected sites to determine average flow of the source water during median- and low-flow conditions; and (3) the development and testing of chemical analyses, including both conservative and reactive tracers that have been studied in microcosms and wetlands for attenuation rates. The second phase involves the development and use of the hydrologic model QUAL2E to simulate each of the selected watersheds in order to estimate potential stream water quality impairments at the drinking water intake at each site. The results of the model are verified with field sampling at designated locations at each site. We expect to identify several critical river basins where surface water at the drinking water intake contains sufficient wastewater-derived contaminants to warrant concern. If wastewater-derived contaminants are detected, we will estimate the average annual exposure of consumers of this water. We will compare these expected and actual concentrations with typical constituent concentrations found in wastewater that has undergone advanced treatment for reclamation. We may demonstrate that the surface water supplies during low flow are actually of worse quality than carefully monitored reclaimed water.

  16. Potentiometric surface of the Upper Floridan aquifer, west-central Florida, May 2005

    USGS Publications Warehouse

    Ortiz, A.G.; Blanchard, R.A.

    2006-01-01

    The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing freshwater are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is a highly productive aquifer and supplies more than 10 times the amount of water pumped from either the surficial aquifer system or the intermediate aquifer system in most of the study area (Duerr and others, 1988). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in May 2005. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in a tightly cased well that taps a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the dry season, when ground-water levels usually are at an annual low and withdrawals for agricultural use typically are high. The cumulative average rainfall of 67.27 inches for west-central Florida (from June 2004 through May 2005) was 14.20 inches above the historical cumulative average of 53.07 inches (Southwest Florida Water Management District (SWFWMD), 2005). The above average precipitation is attributed to the active hurrican season for Florida in 2004. Historical cumulative averages are calculated from regional rainfall summary reports (1915 to the most recent completed calendar year) and are updated monthly by the SWFWMD. This report, prepared by the U.S. Geological Survey (USGS) in cooperation with the SWFWMD, is part of a semiannual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the USGS during May 23-27, 2005. Supplemental water-level data were collected by other agencies and companies. A corresponding potentiometric-surface map was prepared for areas east and north of the SWFWMD boundary by the USGS office in Altamonte Springs, Florida (Kinnaman, 2006). Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a 'snapshot' of conditions at a specific time, nor do they necessarily coincide with the seasonal low water-level condition. Water levels in about 19 percent of the wells measured in May 2005 were lower than the May 2004 water levels (Blanchard and others, 2004). Data from 409 wells indicate that the May 2005 water levels ranged from about 5 feet below to about 18 feet above the May 2004 water levels (fig. 1). The largest water-level declines occurred in southwestern Hernando County, northeastern Hillsborough County, and parts of Hillsborough, Sumter, and Sarasota Counties. The largest water-level rises occurred in southeastern Hillsborough County, eastern Manatee County, and western Hardee County (fig. 1). Water levels in about 95 percent of the wells measured in May 2005 were lower than the September 2004 water levels (Blanchard and Seidenfeld, 2005). Data from 405 wells indicate that the May 2005 water levels ranged from about 22 feet below to 14 feet above the September 2004 water levels. The largest water-level decline was in east-central Manatee County and the largest water-level rise was in central Sarasota County.

  17. Bioinspired Surface Treatments for Improved Decontamination: Icephobic Surfaces

    DTIC Science & Technology

    2017-06-26

    standing droplets of water (left) and methyl salicylate (right) immediately following liquid application (top) and 5 min after liquid application...average of nine measurements for each liquid ). Geometric surface energy was calculated based on the water and ethylene glycol interactions using software...supporting platform angle was gradually increased up to 60°. Sliding angles for each of the liquids were identified as the angle for which movement

  18. Using computational modeling of river flow with remotely sensed data to infer channel bathymetry

    USGS Publications Warehouse

    Nelson, Jonathan M.; McDonald, Richard R.; Kinzel, Paul J.; Shimizu, Y.

    2012-01-01

    As part of an ongoing investigation into the use of computational river flow and morphodynamic models for the purpose of correcting and extending remotely sensed river datasets, a simple method for inferring channel bathymetry is developed and discussed. The method is based on an inversion of the equations expressing conservation of mass and momentum to develop equations that can be solved for depth given known values of vertically-averaged velocity and water-surface elevation. The ultimate goal of this work is to combine imperfect remotely sensed data on river planform, water-surface elevation and water-surface velocity in order to estimate depth and other physical parameters of river channels. In this paper, the technique is examined using synthetic data sets that are developed directly from the application of forward two-and three-dimensional flow models. These data sets are constrained to satisfy conservation of mass and momentum, unlike typical remotely sensed field data sets. This provides a better understanding of the process and also allows assessment of how simple inaccuracies in remotely sensed estimates might propagate into depth estimates. The technique is applied to three simple cases: First, depth is extracted from a synthetic dataset of vertically averaged velocity and water-surface elevation; second, depth is extracted from the same data set but with a normally-distributed random error added to the water-surface elevation; third, depth is extracted from a synthetic data set for the same river reach using computed water-surface velocities (in place of depth-integrated values) and water-surface elevations. In each case, the extracted depths are compared to the actual measured depths used to construct the synthetic data sets (with two- and three-dimensional flow models). Errors in water-surface elevation and velocity that are very small degrade depth estimates and cannot be recovered. Errors in depth estimates associated with assuming water-surface velocities equal to depth-integrated velocities are substantial, but can be reduced with simple corrections.

  19. Atmospheric organochlorine pollutants and air-sea exchange of hexachlorocyclohexane in the Bering and Chukchi Seas

    USGS Publications Warehouse

    Hinckley, D.A.; Bidleman, T.F.; Rice, C.P.

    1991-01-01

    Organochlorine pesticides have been found in Arctic fish, marine mammals, birds, and plankton for some time. The lack of local sources and remoteness of the region imply long-range transport and deposition of contaminants into the Arctic from sources to the south. While on the third Soviet-American Joint Ecological Expedition to the Bering and Chukchi Seas (August 1988), high-volume air samples were taken and analyzed for organochlorine pesticides. Hexachlorocyclohexane (HCH), hexachlorobenzene, polychlorinated camphenes, and chlordane (listed in order of abundance, highest to lowest) were quantified. The air-sea gas exchange of HCH was estimated at 18 stations during the cruise. Average alpha-HCH concentrations in concurrent atmosphere and surface water samples were 250 pg m-3 and 2.4 ng L-1, respectively, and average gamma-HCH concentrations were 68 pg m-3 in the atmosphere and 0.6 ng L-1 in surface water. Calculations based on experimentally derived Henry's law constants showed that the surface water was undersaturated with respect to the atmosphere at most stations (alpha-HCH, average 79% saturation; gamma-HCH, average 28% saturation). The flux for alpha-HCH ranged from -47 ng m-2 day-1 (sea to air) to 122 ng m-2 d-1 (air to sea) and averaged 25 ng m-2 d-1 air to sea. All fluxes of gamma-HCH were from air to sea, ranged from 17 to 54 ng m-2 d-1, and averaged 31 ng m-2 d-1.

  20. Modern Era Retrospective-analysis for Research and Applications (MERRA) Global Water and Energy Budgets

    NASA Technical Reports Server (NTRS)

    Bosilovich, Michael G.; Chen, Junye

    2009-01-01

    In the Summer of 2009, NASA's Modern Era Retrospective-analysis for Research and Applications (MERRA) will have completed 28 years of global satellite data analyses. Here, we characterize the global water and energy budgets of MERRA, compared with available observations and the latest reanalyses. In this analysis, the climatology of the global average components are studied as well as the separate land and ocean averages. In addition, the time series of the global averages are evaluated. For example, the global difference of precipitation and evaporation generally shows the influence of water vapor observations on the system. Since the observing systems change in time, especially remotely sensed observations of water, significant temporal variations can occur across the 28 year record. These then are also closely connected to changes in the atmospheric energy and water budgets. The net imbalance of the energy budget at the surface can be large and different signs for different reanalyses. In MERRA, the imbalance of energy at the surface tends to improve with time being the smallest during the most recent and abundant satellite observations.

  1. Hydrology of the alluvial, buried channel, basal Pleistocene and Dakota aquifers in west-central Iowa

    USGS Publications Warehouse

    Runkle, D.L.

    1985-01-01

    The Dakota aquifer consists of the saturated sandstone and gravel units in the Dakota Formation. Isolated erosional remnants of the Dakota Formation form the caps of many bedrock ridges. The Dakota Formation is thickest where the bedrock surface is relatively high and flat, forming an ancient, buried, surface-water divide between southwest and southeast trending buried drainages in Audubon, Carroll, and Guthrie Counties. Sandstone thickness of as much as 150 feet exists in Guthrie County, but an average thickness of 30 feet is more common. Water from wells less than 200 feet deep generally is a calcium bicarbonate type and has an average dissolved-solids concentration of 650 milligrams per liter. Water from wells more than 200 feet deep generally is a calcium sulfate or sodium bicarbonate type and has an average dissolved-solids concentrations of 2,200 milligrams per liter.

  2. Methane evasion and oxidation in the Big Cypress National Preserve—a low relief carbonate wetland

    NASA Astrophysics Data System (ADS)

    Ward, N. D.; Bianchi, T. S.; Cohen, M. J.; Martin, J. B.; Quintero, C.; Brown, A.; Osborne, T.; Sawakuchi, H. O.

    2016-12-01

    The Big Cypress National Preserve is a low relief carbonate wetland characterized by unique basin patterning known as "cypress domes." Here we examine the concentration and stable isotopic composition of methane in pore waters, surface waters, and bubbles from the sediment across horizontal gradients in four domes during three sampling campaigns. The proportion of methane oxidized in surface waters was estimated based on isotopic differences between surface water and pore waters/bubbles. Rates of methane evasion from surface waters, soils, and cypress knees to the atmosphere were also measured. Surface water CH4 concentrations ranged from 170 to 4,533 ppm with the highest levels generally being observed during wet periods. Pore water CH4 concentrations ranged from 748 to 75,213 ppm. The concentration of methane in bubbles ranged from 6.5 to 71%. The stable isotopic composition of CH4 ranged from -69.2 to -43.8‰ for all samples and was generally more enriched in surface waters compared to bubbles and porewaters, particularly in the two domes that were persistently inundated throughout the year. Based on these isotopic values, the average percentage of surface water CH4 that was oxidized was 37 ± 16% (maximum of 67%) and 19 ± 4% (maximum of 47%) in the two domes that are persistently inundated versus the two domes that are not inundated during the dry season, respectively. The average rate of CH4 evasion was 3.6 ± 1.6 mmol m-2 d-1 via diffusion, 7.6 ± 4.7 mmol m-2 d-1 via ebullition, 10.9 ± 11.4 mmol m-2 d-1­ from soil surfaces, and 34.3 ± 27.4 mmol m-2 d-1 from cypress knees. These results indicate that CH4 is produced in great quantities in inundated sediments, particularly in the center of the cypress domes. Diffusive fluxes from surface waters are suppressed by microbial oxidation in the water column, whereas ebullition from sediments and evasion through cypress knees, and likely other vascular vegetation, are the primary pathways for CH4 outgassing.

  3. Spatial distributions and seasonal variations of organochlorine pesticides in water and soil samples in Bolu, Turkey.

    PubMed

    Karadeniz, Hatice; Yenisoy-Karakaş, Serpil

    2015-03-01

    In this study, a total of 75 water samples (38 groundwater and 37 surface water samples) and 54 surface soil samples were collected from the five districts of Bolu, which is located in the Western Black Sea Region of Turkey in the summer season of 2009. In the autumn season, 17 water samples (surface water and groundwater samples) and 17 soil samples were collected within the city center to observe the seasonal changes of organochlorine pesticides (OCPs). Groundwater and surface water samples were extracted using solid phase extraction. Soil samples were extracted ultrasonically. Sixteen OCP compounds in the standard solution were detected by a gas chromatography-electron capture detector (GC-ECD). Therefore, the method validation was performed for those 16 OCP compounds. However, 13 OCP compounds could be observed in the samples. The concentrations of most OCPs were higher in samples collected in the summer than those in the autumn. The most frequently observed pesticides were endosulfan sulfate and 4,4'-dichlorodiphenyltrichloroethane (DDT) in groundwater samples, α-HCH in surface water samples, and endosulfan sulfate in soil samples. The average concentration of endosulfan sulfate was the highest in water and soil samples. Compared to the literature values, the average concentrations in this study were lower values. Spatial distribution of OCPs was evaluated with the aid of contour maps for the five districts of Bolu. Generally, agricultural processes affected the water and soil quality in the region. However, non-agricultural areas were also affected by pesticides. The concentrations of pesticides were below the legal limits of European directives for each pesticide.

  4. Use of upscaled elevation and surface roughness data in two-dimensional surface water models

    USGS Publications Warehouse

    Hughes, J.D.; Decker, J.D.; Langevin, C.D.

    2011-01-01

    In this paper, we present an approach that uses a combination of cell-block- and cell-face-averaging of high-resolution cell elevation and roughness data to upscale hydraulic parameters and accurately simulate surface water flow in relatively low-resolution numerical models. The method developed allows channelized features that preferentially connect large-scale grid cells at cell interfaces to be represented in models where these features are significantly smaller than the selected grid size. The developed upscaling approach has been implemented in a two-dimensional finite difference model that solves a diffusive wave approximation of the depth-integrated shallow surface water equations using preconditioned Newton–Krylov methods. Computational results are presented to show the effectiveness of the mixed cell-block and cell-face averaging upscaling approach in maintaining model accuracy, reducing model run-times, and how decreased grid resolution affects errors. Application examples demonstrate that sub-grid roughness coefficient variations have a larger effect on simulated error than sub-grid elevation variations.

  5. Spatiotemporal variations of the ⁹⁰Sr in the southern part of the Baltic Sea over the period of 2005-2010.

    PubMed

    Saniewski, Michał

    2013-01-01

    The Baltic Sea is one of the most contaminated seas by the radioactive isotope of strontium in the world; therefore the activity of ⁹⁰Sr is regularly controlled. Due to that fact, seawater samples for ⁹⁰Sr determination were collected at 16 stations located in the southern Baltic Sea between 2005 and 2010. In this period average activity of ⁹⁰Sr was 7.8 Bq m⁻³ and varied within the range from 3.0 Bq m⁻³ to 11.9 Bq m⁻³. Because the higher activity of ⁹⁰Sr was measured in the Baltic Sea than in the North Sea and rivers, inflows from the North Sea and the riverine runoff decreased ⁹⁰Sr activity in the Baltic Sea. The average ⁹⁰Sr activity in the bottom water along the offshore profile was 18% lower than that in the surface water and it was caused by an inflow of salt water from the North Sea. In the Vistula River mouth the average activity of ⁹⁰Sr in the surface water was about 15% lower than the average activity in the bottom waters. Coastal areas, relatively shallow with good mixing condition in the water column, were characterized by low variability in ⁹⁰Sr activity.

  6. Validation of a spatial model used to locate fish spawning reef construction sites in the St. Clair–Detroit River system

    USGS Publications Warehouse

    Fischer, Jason L.; Bennion, David; Roseman, Edward F.; Manny, Bruce A.

    2015-01-01

    Lake sturgeon (Acipenser fulvescens) populations have suffered precipitous declines in the St. Clair–Detroit River system, following the removal of gravel spawning substrates and overfishing in the late 1800s to mid-1900s. To assist the remediation of lake sturgeon spawning habitat, three hydrodynamic models were integrated into a spatial model to identify areas in two large rivers, where water velocities were appropriate for the restoration of lake sturgeon spawning habitat. Here we use water velocity data collected with an acoustic Doppler current profiler (ADCP) to assess the ability of the spatial model and its sub-models to correctly identify areas where water velocities were deemed suitable for restoration of fish spawning habitat. ArcMap 10.1 was used to create raster grids of water velocity data from model estimates and ADCP measurements which were compared to determine the percentage of cells similarly classified as unsuitable, suitable, or ideal for fish spawning habitat remediation. The spatial model categorized 65% of the raster cells the same as depth-averaged water velocity measurements from the ADCP and 72% of the raster cells the same as surface water velocity measurements from the ADCP. Sub-models focused on depth-averaged velocities categorized the greatest percentage of cells similar to ADCP measurements where 74% and 76% of cells were the same as depth-averaged water velocity measurements. Our results indicate that integrating depth-averaged and surface water velocity hydrodynamic models may have biased the spatial model and overestimated suitable spawning habitat. A model solely integrating depth-averaged velocity models could improve identification of areas suitable for restoration of fish spawning habitat.

  7. Evaluation of flood inundation in Crystal Springs Creek, Portland, Oregon

    USGS Publications Warehouse

    Stonewall, Adam; Hess, Glen

    2016-05-25

    Efforts to improve fish passage have resulted in the replacement of six culverts in Crystal Springs Creek in Portland, Oregon. Two more culverts are scheduled to be replaced at Glenwood Street and Bybee Boulevard (Glenwood/Bybee project) in 2016. Recently acquired data have allowed for a more comprehensive understanding of the hydrology of the creek and the topography of the watershed. To evaluate the impact of the culvert replacements and recent hydrologic data, a Hydrologic Engineering Center-River Analysis System hydraulic model was developed to estimate water-surface elevations during high-flow events. Longitudinal surface-water profiles were modeled to evaluate current conditions and future conditions using the design plans for the culverts to be installed in 2016. Additional profiles were created to compare with the results from the most recent flood model approved by the Federal Emergency Management Agency for Crystal Springs Creek and to evaluate model sensitivity.Model simulation results show that water-surface elevations during high-flow events will be lower than estimates from previous models, primarily due to lower estimates of streamflow associated with the 0.01 and 0.002 annual exceedance probability (AEP) events. Additionally, recent culvert replacements have resulted in less ponding behind crossings. Similarly, model simulation results show that the proposed replacement culverts at Glenwood Street and Bybee Boulevard will result in lower water-surface elevations during high-flow events upstream of the proposed project. Wider culverts will allow more water to pass through crossings, resulting in slightly higher water-surface elevations downstream of the project during high-flows than water-surface elevations that would occur under current conditions. For the 0.01 AEP event, the water-surface elevations downstream of the Glenwood/Bybee project will be an average of 0.05 ft and a maximum of 0.07 ft higher than current conditions. Similarly, for the 0.002 AEP event, the water-surface elevations will be an average of 0.04 ft and a maximum of 0.19 ft higher than current conditions.

  8. Estimated depth to the water table and estimated rate of recharge in outcrops of the Chicot and Evangeline aquifers near Houston, Texas

    USGS Publications Warehouse

    Noble, J.E.; Bush, P.W.; Kasmarek, M.C.; Barbie, D.L.

    1996-01-01

    In 1989, the U.S. Geological Survey, in cooperation with the Harris-Galveston Coastal Subsidence District, began a field study to determine the depth to the water table and to estimate the rate of recharge in outcrops of the Chicot and Evangeline aquifers near Houston, Texas. The study area comprises about 2,000 square miles of outcrops of the Chicot and Evangeline aquifers in northwest Harris County, Montgomery County, and southern Walker County. Because of the scarcity of measurable water-table wells, depth to the water table below land surface was estimated using a surface geophysical technique, seismic refraction. The water table in the study area generally ranges from about 10 to 30 foot below land surface and typically is deeper in areas of relatively high land-surface altitude than in areas of relatively low land- surface altitude. The water table has demonstrated no long-term trends since ground-water development began, with the probable exception of the water table in the Katy area: There the water table is more than 75 feet deep, probably due to ground-water pumpage from deeper zones. An estimated rate of recharge in the aquifer outcrops was computed using the interface method in which environmental tritium is a ground-water tracer. The estimated average total recharge rate in the study area is 6 inches per year. This rate is an upper bound on the average recharge rate during the 37 years 1953-90 because it is based on the deepest penetration (about 80 feet) of postnuclear-testing tritium concentrations. The rate, which represents one of several components of a complex regional hydrologic budget, is considered reasonable but is not definitive because of uncertainty regarding the assumptions and parameters used in its computation.

  9. Potentiometric-surface map of water in the Judith River Formation in the Northern Great Plains area of Montana

    USGS Publications Warehouse

    Levings, Gary W.

    1982-01-01

    The potentiometric surface of the Judith River Formation is mapped at a scale of 1:1,000,000. The map is one of a series produced as part of a regional study of aquifers of Cenozoic and Mesozoic age in the northern Great Plains of Montana. The contour interval is 200 feet. Water in the Judith River Formation occurs under water-table and artesian conditions. The direction of regional ground-water movement is from west to east. Water is discharged from the Judith River Formation to the Milk River from near Havre, Montana, to Malta and to the Missouri River south of the Bearpaw and Little Rocky Mountains. The average discharge from 236 wells is about 10 gallons per minute, and the specific capacity of 186 wells averages 0.66 gallon per minute per foot of drawdown. (USGS)

  10. Storm water runoff concentration matrix for urban areas.

    PubMed

    Göbel, P; Dierkes, C; Coldewey, W G

    2007-04-01

    The infrastructure (roads, sidewalk, commercial and residential structures) added during the land development and urbanisation process is designed to collect precipitation and convey it out of the watershed, typically in existing surface water channels, such as streams and rivers. The quality of surface water, seepage water and ground water is influenced by pollutants that collect on impervious surfaces and that are carried by urban storm water runoff. Heavy metals, e.g. lead (Pb), zinc (Zn), copper (Cu), cadmium (Cd), polycyclic aromatic hydrocarbons (PAH), mineral oil hydrocarbons (MOH) and readily soluble salts in runoff, contribute to the degradation of water. An intensive literature search on the distribution and concentration of the surface-dependent runoff water has been compiled. Concentration variations of several pollutants derived from different surfaces have been averaged. More than 300 references providing about 1300 data for different pollutants culminate in a representative concentration matrix consisting of medians and extreme values. This matrix can be applied to long-term valuations and numerical modelling of storm water treatment facilities.

  11. Water-escape velocities in jumping blacktip sharks

    PubMed Central

    Brunnschweiler, Juerg M

    2005-01-01

    This paper describes the first determination of water-escape velocities in free-ranging sharks. Two approximations are used to estimate the final swimming speed at the moment of penetrating the water surface. Blacktip sharks were videotaped from below the surface and parameters were estimated by analysing the sequences frame by frame. Water-escape velocities averaged 6.3 m s−1. These velocities for blacktip sharks seem accurate and are similar to estimates obtained for other shark species of similar size. PMID:16849197

  12. Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, May 2009

    USGS Publications Warehouse

    Ortiz, Anita G.

    2009-01-01

    The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing fresh water are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in May 2009. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the dry season, when ground-water levels usually are at an annual low and withdrawals for agricultural use typically are high. The cumulative average rainfall of 48.53 inches for west-central Florida (from June 2008 through May 2009) was 4.12 inches below the historical cumulative average of 52.65 inches (Southwest Florida Water Management District, 2009). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the U.S. Geological Survey during the period May 18-22, 2009. Supplemental water-level data were collected by other agencies and companies. A corresponding potentiometric-surface map was prepared for areas east and north of the Southwest Florida Water Management District boundary by the U.S. Geological Survey office in Orlando, Florida (Kinnaman and Dixon, 2009). Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a 'snapshot' of conditions at a specific time, nor do they necessarily coincide with the seasonal low water-level condition. The potentiometric contours are generalized to synoptically portray the head in a dynamic hydrologic system, taking due account of the variations in hydrogeologic conditions, such as differing depths of wells, nonsimultaneous measurements of water levels, variable effects of pumping, and changing climatic influence. The potentiometric contours may not conform exactly with the individual measurements of water levels.

  13. Developing monitoring plans to detect spills related to natural gas production.

    PubMed

    Harris, Aubrey E; Hopkinson, Leslie; Soeder, Daniel J

    2016-11-01

    Surface water is at risk from Marcellus Shale operations because of chemical storage on drill pads during hydraulic fracturing operations, and the return of water high in total dissolved solids (up to 345 g/L) from shale gas production. This research evaluated how two commercial, off-the-shelf water quality sensors responded to simulated surface water pollution events associated with Marcellus Shale development. First, peak concentrations of contaminants from typical spill events in monitored watersheds were estimated using regression techniques. Laboratory measurements were then conducted to determine how standard in-stream instrumentation that monitor conductivity, pH, temperature, and dissolved oxygen responded to three potential spill materials: ethylene glycol (corrosion inhibitor), drilling mud, and produced water. Solutions ranging from 0 to 50 ppm of each spill material were assessed. Over this range, the specific conductivity increased on average by 19.9, 27.9, and 70 μS/cm for drilling mud, ethylene glycol, and produced water, respectively. On average, minor changes in pH (0.5-0.8) and dissolved oxygen (0.13-0.23 ppm) were observed. While continuous monitoring may be part of the strategy for detecting spills to surface water, these minor impacts to water quality highlight the difficulty in detecting spill events. When practical, sensors should be placed at the mouths of small watersheds where drilling activities or spill risks are present, as contaminant travel distance strongly affects concentrations in surface water systems.

  14. Quality of surface-water runoff in selected streams in the San Antonio segment of the Edwards aquifer recharge zone, Bexar County, Texas, 1997-2012

    USGS Publications Warehouse

    Opsahl, Stephen P.

    2012-01-01

    During 1997–2012, the U.S. Geological Survey, in cooperation with the San Antonio Water System, collected and analyzed water-quality constituents in surface-water runoff from five ephemeral stream sites near San Antonio in northern Bexar County, Texas. The data were collected to assess the quality of surface water that recharges the Edwards aquifer. Samples were collected from four stream basins that had small amounts of developed land at the onset of the study but were predicted to undergo substantial development over a period of several decades. Water-quality samples also were collected from a fifth stream basin located on land protected from development to provide reference data by representing undeveloped land cover. Water-quality data included pH, specific conductance, chemical oxygen demand, dissolved solids (filtered residue on evaporation in milligrams per liter, dried at 180 degrees Celsius), suspended solids, major ions, nutrients, trace metals, and pesticides. Trace metal concentration data were compared to the Texas Commission on Environmental Quality established surface water quality standards for human health protection (water and fish). Among all constituents in all samples for which criteria were available for comparison, only one sample had one constituent which exceeded the surface water criteria on one occasion. A single lead concentration (2.76 micrograms per liter) measured in a filtered water sample exceeded the surface water criteria of 1.15 micrograms per liter. The average number of pesticide detections per sample in stream basins undergoing development ranged from 1.8 to 6.0. In contrast, the average number of pesticide detections per sample in the reference stream basin was 0.6. Among all constituents examined in this study, pesticides, dissolved orthophosphate phosphorus, and dissolved total phosphorus demonstrated the largest differences between the four stream basins undergoing development and the reference stream basin with undeveloped land cover.

  15. Long-Wave Radiation Divergence over Water and Land from Measurement and Calculation (Die Langwellige Strahlungsdivergenz ueber Wasser und ueber dem Festen Boden nach Messung und Rechnung),

    DTIC Science & Technology

    surface temperature field. If these are eliminated, which is relatively simple over a water surface, the differences between calculated and measured...divergences at these levels is less than 20%, on the average. The relative variation of the divergence with height is somewhat greater over water than over land, due to the different temperature profiles. (Author)

  16. Satellite observations of rainfall effect on sea surface salinity in the waters adjacent to Taiwan

    NASA Astrophysics Data System (ADS)

    Ho, Chung-Ru; Hsu, Po-Chun; Lin, Chen-Chih; Huang, Shih-Jen

    2017-10-01

    Changes of oceanic salinity are highly related to the variations of evaporation and precipitation. To understand the influence of rainfall on the sea surface salinity (SSS) in the waters adjacent to Taiwan, satellite remote sensing data from the year of 2012 to 2014 are employed in this study. The daily rain rate data obtained from Special Sensor Microwave Imager (SSM/I), Tropical Rainfall Measuring Mission's Microwave Imager (TRMM/TMI), Advanced Microwave Scanning Radiometer (AMSR), and WindSat Polarimetric Radiometer. The SSS data was derived from the measurements of radiometer instruments onboard the Aquarius satellite. The results show the average values of SSS in east of Taiwan, east of Luzon and South China Sea are 33.83 psu, 34.05 psu, and 32.84 psu, respectively, in the condition of daily rain rate higher than 1 mm/hr. In contrast to the rainfall condition, the average values of SSS are 34.07 psu, 34.26 psu, and 33.09 psu in the three areas, respectively at no rain condition (rain rate less than 1 mm/hr). During the cases of heavy rainfall caused by spiral rain bands of typhoon, the SSS is diluted with an average value of -0.78 psu when the average rain rate is higher than 4 mm/hr. However, the SSS was increased after temporarily decreased during the typhoon cases. A possible reason to explain this phenomenon is that the heavy rainfall caused by the spiral rain bands of typhoon may dilute the sea surface water, but the strong winds can uplift the higher salinity of subsurface water to the sea surface.

  17. 'De-watering' capabilities of surfactants in human amniotic fluid.

    PubMed Central

    Hills, B A

    1984-01-01

    The phospholipid extracts from each of eleven samples of human amniotic fluid obtained from eleven full-term births were deposited as orientated monolayers adsorbed to glass. The surfaces were found to be rendered hydrophobic with maximum contact angles averaging 54.5 degrees while, upon withdrawing fluid, the edge of the saline pool receded to expose dry surface with minimum contact angles averaging 15.4 degrees. The extracts were found to be surface-active at the liquid-air interface and there was some indication that direct adsorption to solid surfaces was facilitated by calcium ions. It was found that, in all extracts, a continuous layer of saline adjacent to the adsorbed surface would break up spontaneously to expose dry surface when the thickness was reduced to an average of 764 micron, corresponding to several alveolar diameters. This phenomenon is discussed as a possible means of establishing dry patches on the alveolar membrane, especially in the new-born after the fetal alveolar wall has been exposed to the same surfactants in much the same physical form as found in amniotic fluid. Surfactant adsorbed directly to the tissue subphase is suggested as a physical basis for the discontinuity of the aqueous hypophase seen in many electron micrographs of the adult alveolus. This 'de-watering' of the alveolar surface could facilitate gas transfer. PMID:6546947

  18. Moulding technique demonstrates the contribution of surface geometry to the super-hydrophobic properties of the surface of a water strider.

    PubMed

    Goodwyn, Pablo Perez; De Souza, Emerson; Fujisaki, Kenji; Gorb, Stanislav

    2008-05-01

    Water striders (Insecta, Heteroptera, Gerridae) have a complex three-dimensional waterproof hairy cover which renders them super-hydrophobic. This paper experimentally demonstrates for the first time the mechanism of the super-hydrophobicity of the cuticle of water striders. The complex two-level microstructure of the surface, including the smallest microtrichia (200-300 nm wide, 7-9 microm long), was successfully replicated using a two-step moulding technique. The mould surface exhibited super-hydrophobic properties similar to the original insect surface. The average water contact angle (CA) of the mould was 164.7 degrees , whereas the CA of the flat polymer was about 92 degrees . These results show that (i) in water striders, the topography of the surface plays a dominant role in super-hydrophobicity, (ii) very low surface energy bulk material (typically smaller than 0.020 N m(-1)) is not necessary to achieve super-hydrophobicity; and (3) the two-step moulding technique may be used to mimic quite complex biological functional surfaces.

  19. Spatial variability of induced ground-water recharge beneath the Russian River, California

    NASA Astrophysics Data System (ADS)

    Rosenberry, D. O.; Hatch, C. E.; Cox, M. H.; Zamora, C.; Cloud, A.; Constantz, J. E.; Seymour, D.

    2004-12-01

    The Sonoma County Water Agency extracts water from the alluvial aquifer adjacent to and beneath the Russian River via large-volume Ranney-type collector wells. To aid in this extraction, the stage of the river is increased approximately 3 meters by an inflatable dam. In addition, raising the dam allows water to be diverted into infiltration basins that are located adjacent to the river. Removal of aquifer water induces large fluxes from surface water to ground water through the beds of the infiltration basins and the river. Total extraction during maximum summer withdrawals via five collector wells indicates an average flux from surface water to ground water through the riverbed and infiltration basins of 153 cm/d. Measurements of flux using in-river and in-pond piezometers, diurnal sediment-temperature data, and seepage meters, indicate that actual seepage fluxes are spatially variable and large seepage fluxes are concentrated in specific locations, some of which may not be intuitive. For example, we expected greatest induced seepage fluxes to occur above laterals that extend beneath the river and deliver water to a collector well. Seepage flux along a transverse transect of the riverbed that was located above laterals from one of the collector wells averaged 10 cm/d. At the same time, seepage flux along a transect that was 500 m upstream, and farther from the influence of the collector-well system, averaged 40 cm/d. Seepage fluxes from the central portion of one of the recharge basins averaged 3 cm/d whereas seepage fluxes near the margin of that infiltration basin averaged 250 cm/d. Seepage fluxes derived from in-stream-piezometer Darcy calculations were surprisingly consistent with seepage fluxes derived from seepage-meter measurements. Seepage fluxes derived from temperature measurements were slightly less comparable to the piezometer and seepage-meter measurements. The 121 cm/d average of all seepage-flux measurements was similar to the spatially-integrated rate (153 cm/d) based on the volume of water extracted from the river by the pumping wells divided by the affected area of the riverbed and the flooded infiltration ponds.

  20. Peat characteristics and groundwater geochemistry of calcareous fens in the Minnesota River Basin, U.S.A

    USGS Publications Warehouse

    Almendinger, J.E.; Leete, J.H.

    1998-01-01

    . Calcareous fens in Minnesota are spring-seepage peatlands with a distinctive flora of rare calciphilic species. Peat characteristics and groundwater geochemistry were determined for six calcareous fens in the Minnesota River Basin to better understand the physical structure and chemical processes associated with stands of rare vegetation. Onset of peat accumulation in three of the fens ranged from about 4,700 to 11,000 14C yrs BP and probably resulted from a combination of climate change and local hydrogeologic conditions. Most peat cores had a carbonate-bearing surface zone with greater than 10% carbonates (average 27%, dry wt basis), an underlying carbonate-depleted zone with 10% or less carbonates (average 4%), and a carbonate-bearing lower zone again with greater than 10% carbonates (average 42%). This carbonate zonation was hypothesized to result from the effect of water-table level on carbonate equilibria: carbonate precipitation occurs when the water table is above a critical level, and carbonate dissolution occurs when the water table is lower. Other processes that changed the major ion concentrations in upwelling groundwater include dilution by rain water, sulfate reduction or sulfide oxidation, and ion adsorption or exchange. Geochemical modeling indicated that average shallow water in the calcareous fens during the study period was groundwater mixed with about 6 to 13% rain water. Carbonate precipitation in the surface zone of calcareous fens could be decreased by a number of human activities, especially those that lower the water table. Such changes in shallow water geochemistry could alter the growing conditions that apparently sustain rare fen vegetation.

  1. Selected approaches to estimate water-budget components of the High Plains, 1940 through 1949 and 2000 through 2009

    USGS Publications Warehouse

    Stanton, Jennifer S.; Qi, Sharon L.; Ryter, Derek W.; Falk, Sarah E.; Houston, Natalie A.; Peterson, Steven M.; Westenbroek, Stephen M.; Christenson, Scott C.

    2011-01-01

    The High Plains aquifer, underlying almost 112 million acres in the central United States, is one of the largest aquifers in the Nation. It is the primary water supply for drinking water, irrigation, animal production, and industry in the region. Expansion of irrigated agriculture throughout the past 60 years has helped make the High Plains one of the most productive agricultural regions in the Nation. Extensive withdrawals of groundwater for irrigation have caused water-level declines in many parts of the aquifer and increased concerns about the long-term sustainability of the aquifer. Quantification of water-budget components is a prerequisite for effective water-resources management. Components analyzed as part of this study were precipitation, evapotranspiration, recharge, surface runoff, groundwater discharge to streams, groundwater fluxes to and from adjacent geologic units, irrigation, and groundwater in storage. These components were assessed for 1940 through 1949 (representing conditions prior to substantial groundwater development and referred to as "pregroundwater development" throughout this report) and 2000 through 2009. Because no single method can perfectly quantify the magnitude of any part of a water budget at a regional scale, results from several methods and previously published work were compiled and compared for this study when feasible. Results varied among the several methods applied, as indicated by the range of average annual volumes given for each component listed in the following paragraphs. Precipitation was derived from three sources: the Parameter-Elevation Regressions on Independent Slopes Model, data developed using Next Generation Weather Radar and measured precipitation from weather stations by the Office of Hydrologic Development at the National Weather Service for the Sacramento-Soil Moisture Accounting model, and precipitation measured at weather stations and spatially distributed using an inverse-distance-weighted interpolation method. Precipitation estimates using these sources, as a 10-year average annual total volume for the High Plains, ranged from 192 to 199 million acre-feet (acre-ft) for 1940 through 1949 and from 185 to 199 million acre-ft for 2000 through 2009. Evapotranspiration was obtained from three sources: the National Weather Service Sacramento-Soil Moisture Accounting model, the Simplified-Surface-Energy-Balance model using remotely sensed data, and the Soil-Water-Balance model. Average annual total evapotranspiration estimated using these sources was 148 million acre-ft for 1940 through 1949 and ranged from 154 to 193 million acre-ft for 2000 through 2009. The maximum amount of shallow groundwater lost to evapotranspiration was approximated for areas where the water table was within 5 feet of land surface. The average annual total volume of evapotranspiration from shallow groundwater was 9.0 million acre-ft for 1940 through 1949 and ranged from 9.6 to 12.6 million acre-ft for 2000 through 2009. Recharge was estimated using two soil-water-balance models as well as previously published studies for various locations across the High Plains region. Average annual total recharge ranged from 8.3 to 13.2 million acre-ft for 1940 through 1949 and from 15.9 to 35.0 million acre-ft for 2000 through 2009. Surface runoff and groundwater discharge to streams were determined using discharge records from streamflow-gaging stations near the edges of the High Plains and the Base-Flow Index program. For 1940 through 1949, the average annual net surface runoff leaving the High Plains was 1.9 million acre-ft, and the net loss from the High Plains aquifer by groundwater discharge to streams was 3.1 million acre-ft. For 2000 through 2009, the average annual net surface runoff leaving the High Plains region was 1.3 million acre-ft and the net loss by groundwater discharge to streams was 3.9 million acre-ft. For 2000 through 2009, the average annual total estimated groundwater pumpage volume from two soil-water-balance models ranged from 8.7 to 16.2 million acre-ft. Average annual irrigation application rates for the High Plains ranged from 8.4 to 16.2 inches per year. The USGS Water-Use Program published estimated total annual pumpage from the High Plains aquifer for 2000 and 2005. Those volumes were greater than those estimated from the two soil-water-balance models. Total groundwater in storage in the High Plains aquifer was estimated as 3,173 million acre-ft prior to groundwater development and 2,907 million acre-ft in 2007. The average annual decrease of groundwater in storage between 2000 and 2007 was 10 million acre-ft per year.

  2. Deep artesian aquifers of Sanibel and Captiva Islands, Lee County, Florida

    USGS Publications Warehouse

    Boggess, D.H.; O'Donnell, T. H.

    1982-01-01

    The principal sources of water on Sanibel and Captiva Islands, Lee County, Florida, are two deep artesian aquifers within the upper and lower parts of the Hawthorn Formation. Both aquifers are under artesian pressure and wells flow at the land surface. Water from the upper aquifer is of better quality than that from the lower aquifer and can be used in some areas without desalination. Dissolved solids concentrations in the upper aquifer average 1,540 milligrams per liter. Water levels in wells in the upper aquifer range from 8 to 15 feet above sea level; most wells flow as much as 15 gallons per minute at land surface. The lower aquifer is the source of the public supply for the islands. Dissolved solids concentrations in the lower aquifer range from 1,700 to 4,130 milligrams per liter and average 2,571 milligrams per liter. From July to November 1977, water levels in the aquifer ranged from 7 to 32 feet above sea level throughout Sanibel-Captiva Islands. In 1977 the average pumpage from public supply wells was 1.4 million gallons per day. Pumpage from the artesian aquifers during 1977 was about 690 million gallons. The water is desalinated before distribution. (USGS)

  3. Strontium-90: concentrations in surface waters of the Atlantic Ocean.

    PubMed

    Bowen, V T; Noshkin, V E; Volchok, H L; Sugihara, T T

    1969-05-16

    From the large body of analyses of strontium-90 in surface waters of the Atlantic Ocean, annual average concentrations (from 10 degrees N to 70 degrees N) have been compared to those predicted. The data indicate higher fall-out over ocean than over land and confirm the rapid rates of down-mixing shown by most studies of subsurface strontium-90.

  4. ANNUAL WATER BUDGETS FOR A FORESTED SINKHOLE WETLAND

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hill, Dr. Andrew Jason; Neary, Vincent S

    2012-01-01

    Annual water budgets spanning two years, 2004 and 2005, are constructed for a sinkhole wetland in the Tennessee Highland Rim following conversion of 13 % of its watershed to impervious surfaces. The effect of watershed development on the hydrology of the study wetland was significant. Surface runoff was the dominant input, with a contribution of 61.4 % of the total. An average of 18.9 % of gross precipitation was intercepted by the canopy and evaporated. Seepage from the surface water body to the local groundwater system accounted for 83.1 % of the total outflow. Deep recharge varied from 43.2 %more » (2004) to 12.1 % (2005) of total outflow. Overall, evapotranspiration accounted for 72.4 % of the total losses, with an average of 65.7 % lost from soil profile storage. The annual water budgets indicate that deep recharge is a significant hydrologic function performed by isolated sinkhole wetlands, or karst pans, on the Tennessee Highland Rim. Continued hydrologic monitoring of sinkhole wetlands are needed to evaluate hydrologic function and response to anthropogenic impacts. The regression technique developed to estimate surface runoff entering the wetland is shown to provide reasonable annual runoff estimates, but further testing is needed.« less

  5. Impacts of river segmentation strategies on reach-averaged product uncertainties for the upcoming Surface Water and Ocean Topography (SWOT) mission

    NASA Astrophysics Data System (ADS)

    Frasson, R. P. M.; Wei, R.; Minear, J. T.; Tuozzolo, S.; Domeneghetti, A.; Durand, M. T.

    2016-12-01

    Averaging is a powerful method to reduce measurement noise associated with remote sensing observation of water surfaces. However, when dealing with river measurements, the choice of which points are averaged may affect the quality of the products. We examine the effectiveness of three fully automated reach definition strategies: In the first, we break up reaches at regular intervals measured along the rivers' centerlines. The second strategy consists of identifying hydraulic controls by searching for inflection points on water surface profiles. The third strategy takes into consideration river planform features, breaking up reaches according to channel sinuosity. We employed the Jet Propulsion Laboratory's (JPL) SWOT hydrology simulator to generate 9 synthetic SWOT observations of the Sacramento River in California, USA and 14 overpasses of the Po River in northern Italy. In order to create the synthetic SWOT data, the simulator requires the true water digital elevation model (DEM), which we constructed from hydraulic models of both rivers, and the terrain DEM, which we built from LiDAR data of both basins. We processed the simulated pixel clouds using the JPL's RiverObs package, which traces the river centerline and estimates water surface height and river width on equally spaced nodes located along the centerline. Subsequently, we applied the three reach definition methodologies to the nodes and to the hydraulic models' outputs to generate simulated reach-averaged observations and the reach-averaged truth respectively. Our results generally indicate that height, width, slope, and discharge errors decrease with increasing reach length, with most of the accuracy gains occurring when reach length increases to up to 15 km for both the narrow (Sacramento) and the wide (Po) rivers. The "smart" methods led to smaller slope, width, and discharge errors for the Sacramento River when compared to arbitrary reaches of similar length whereas, for the for the Po River all methods had comparable performance. Our results suggest that river segmentation strategies that take into consideration the hydraulic characteristics of rivers may lead to more meaningful reach boundaries and to better products especially for narrower and more complex rivers.

  6. River Discharge and Bathymetry Estimation from Hydraulic Inversion of Surface Currents and Water Surface Elevation Observations

    NASA Astrophysics Data System (ADS)

    Simeonov, J.; Holland, K. T.

    2015-12-01

    We developed an inversion model for river bathymetry and discharge estimation based on measurements of surface currents, water surface elevation and shoreline coordinates. The model uses a simplification of the 2D depth-averaged steady shallow water equations based on a streamline following system of coordinates and assumes spatially uniform bed friction coefficient and eddy viscosity. The spatial resolution of the predicted bathymetry is related to the resolution of the surface currents measurements. The discharge is determined by minimizing the difference between the predicted and the measured streamwise variation of the total head. The inversion model was tested using in situ and remote sensing measurements of the Kootenai River east of Bonners Ferry, ID. The measurements were obtained in August 2010 when the discharge was about 223 m3/s and the maximum river depth was about 6.5 m. Surface currents covering a 10 km reach with 8 m spatial resolution were estimated from airborne infrared video and were converted to depth-averaged currents using acoustic Doppler current profiler (ADCP) measurements along eight cross-stream transects. The streamwise profile of the water surface elevation was measured using real-time kinematic GPS from a drifting platform. The value of the friction coefficient was obtained from forward calibration simulations that minimized the difference between the predicted and measured velocity and water level along the river thalweg. The predicted along/cross-channel water depth variation was compared to the depth measured with a multibeam echo sounder. The rms error between the measured and predicted depth along the thalweg was found to be about 60cm and the estimated discharge was 5% smaller than the discharge measured by the ADCP.

  7. Aquatic burst locomotion by hydroplaning and paddling in common eiders (Somateria mollissima).

    PubMed

    Gough, William T; Farina, Stacy C; Fish, Frank E

    2015-06-01

    Common eiders (Somateria mollissima) are heavy sea-ducks that spend a large portion of their time swimming at the water surface. Surface swimming generates a bow and hull wave that can constructively interfere and produce wave drag. The speed at which the wavelengths of these waves equal the waterline length of the swimming animal is the hull speed. To increase surface swimming speed beyond the hull speed, an animal must overtake the bow wave. This study found two distinct behaviors that eider ducks used to exceed the hull speed: (1) 'steaming', which involved rapid oaring with the wings to propel the duck along the surface of the water, and (2) 'paddle-assisted flying', during which the ducks lifted their bodies out of the water and used their feet to paddle against the surface while flapping their wings in the air. An average hull speed (0.732±0.046 m s(-1)) was calculated for S. mollissima by measuring maximum waterline length from museum specimens. On average, steaming ducks swam 5.5 times faster and paddle-assisted flying ducks moved 6.8 times faster than the hull speed. During steaming, ducks exceeded the hull speed by increasing their body angle and generating dynamic lift to overcome wave drag and hydroplane along the water surface. During paddle-assisted flying, ducks kept their bodies out of the water, thereby avoiding the limitations of wave drag altogether. Both behaviors provided alternatives to flight for these ducks by allowing them to exceed the hull speed while staying at or near the water surface. © 2015. Published by The Company of Biologists Ltd.

  8. [Distribution, flux and biological consumption of carbon monoxide in the East China Sea and the South Yellow Sea in summer].

    PubMed

    Wang, Jing; Lu, Xiao-Lan; Yang, Gui-Peng; Xu, Guan-Qiu

    2014-11-01

    Carbon monoxide (CO) concentration distribution, sea-to-air flux and microbial consumption rate constant, along with atmospheric CO mixing ratio, were measured in the East China Sea and the South Yellow Sea in summer. Atmospheric CO mixing ratios varied from 68 x 10(-9) -448 x 10(-9), with an average of 117 x 10(-9) (SD = 68 x 10(-9), n = 36). Overall, the concentrations of atmospheric CO displayed a decreasing trend from the coastal stations to the offshore stations. The surface water CO concentrations in the investigated area ranged from 0.23-7.10 nmol x L(-1), with an average of 2.49 nmol x L(-1) (SD = 2.11, n = 36). The surface water CO concentrations were significantly affected by sunlight. Vertical profiles showed that CO concentrations rapidly declined with depth, with the maximum values appearing in the surface water. CO concentrations exhibited obvious diurnal variations in the study area, with the maximum values being 6-40 folds higher than the minimum values. Minimal concentrations of CO all occurred before dawn. However, the maximal concentrations of CO occurred at noon. Marked diurnal variation in the concentrations of CO in the water column indicated that CO was produced primarily by photochemistry. The surface CO concentrations were oversaturated relative to the atmospheric concentrations and the saturation factors ranged from 1.99-99.18, with an average of 29.36 (SD = 24.42, n = 29). The East China Sea and the South Yellow Sea was a net source of atmospheric CO. The sea-to-air fluxes of CO in the East China Sea and the South Yellow Sea ranged 0.37-44.84 μmol x (m2 x d)(-1), with an average of 12.73 μmol x (m2 x d)(-1) (SD = 11.40, n = 29). In the incubation experiments, CO concentrations decreased exponentially with incubation time and the processes conformed to the first order reaction characteristics. The microbial CO consumption rate constants (K(co)) in the surface water ranged from 0.12 to 1.45 h(-1), with an average of 0.47 h(-1) (SD = 0.55, n = 5). A negative correlation between K(co) and salinity was observed in the present study.

  9. Using oxygen isotopes to establish freshwater sources in Bedford Basin, Nova Scotia, a Northwestern Atlantic fjord

    NASA Astrophysics Data System (ADS)

    Kerrigan, Elizabeth A.; Kienast, Markus; Thomas, Helmuth; Wallace, Douglas W. R.

    2017-12-01

    A weekly time-series of oxygen isotope (δ18O) measurements was collected over a 16-month period from near-surface (1 m) and near-bottom (60 m) waters of Bedford Basin, a coastal fjord adjacent to the Scotian Shelf, off eastern Canada. The time-series was complemented with δ18O measurements of local precipitation (rain and snow), river, and wastewater runoff. The isotopic composition of precipitation displayed strong seasonality with an average (volume-weighted) δ18O value of -5.39‰ (±0.96) for summer and a depleted value of -10.37‰ (±2.96) over winter. Winter precipitation exhibited more depleted and variable δ18O of solid precipitation relative to rainfall. The annual, amount-weighted average δ18O of Sackville River discharge (-6.49‰ ± 0.82) was not statistically different from precipitation (-7.24‰ ± 0.92), but exhibited less seasonal variation. Freshwater end-members (zero-salinity intercepts) estimated from annual and seasonal regressions of δ18O versus salinity (S) for Bedford Basin near-surface samples were consistent with the δ18O of summer precipitation and the annual, amount-weighted average for the Sackville River. However, the isotopically depleted signature of winter precipitation was not observed clearly in near-surface waters of Bedford Basin, which might reflect isotope enrichment during sublimation from accumulated snowfall prior to melting and discharge, or retention and mixing within the drainage basin. In near bottom waters, most of the δ18O-S variation (average freshwater end-member: 7.47‰ ± 2.17) could be explained by vertical mixing with near-surface waters (average freshwater end-member: -6.23‰ ± 0.34) and hence with locally-derived freshwater. However the near-bottom δ18O-S variation suggested an additional contribution of a freshwater end-member with a δ18O of -15.55‰ ± 2.3, consistent with a remotely-derived freshwater end-member identified previously for the Scotian Shelf. Residuals from a long-term regression of δ18O-S were generally within the range expected due to analytical uncertainty (±0.05); however near-surface waters exhibited seasonal variability of small amplitude, which was consistent with the timing and δ18O variability of local freshwater inputs.

  10. Geohydrologic evaluation of a landfill in a coastal area, St Petersburg, Florida

    USGS Publications Warehouse

    Hutchinson, C.B.; Stewart, Joseph W.

    1978-01-01

    The 250-acre Toytown landfill site is in a poorly-drained area in coastal Pinellas County, Florida. Average altitude of land surface at the landfill is less than 10 feet. About 1000 tons of solid waste and about 200,000 gallons of digested sewage sludge are disposed of daily at the landfill. The velocity of ground-water flow through the 23-foot thick surficial aquifer northeast from the landfill toward Old Tampa Bay probably ranges from 1 to 10 feet per year, and downward velocity through the confining bed is about 0.00074 foot per day. The horizontal and vertical flow velocities indicate that leachate moves slowly downgradient, and that leachate has not yet seeped through the confining bed after 12 years of landfill operation. Untreated surface run-off from the site averages about 15 inches per year, and ground-water outflow averages about 3.3 inches per year. The Floridan aquifer is used as a limited source of water for domestic supply in this area. (Woodard-USGS)

  11. Evapotranspiration and the water budget of prairie potholes in North Dakota

    USGS Publications Warehouse

    Shjeflo, J.B.

    1968-01-01

    The mass-transfer method was used to study the hydrologic behavior of 10 prairie potholes in central North Dakota during the 5-year period 1960-64. Many of the potholes went dry when precipitation was low. The average evapotranspiration during the May to October period each year was 2.11 feet, and the average seepage was 0.60 foot. These averages remained nearly constant for both wet and dry years. The greatest source of water for the potholes was the direct rainfall on the pond surface; this supplied 1.21 feet per year. Spring snowmelt supplied 0.79 foot of water and runoff from the land surface during the summer supplied 0.53 foot. Even though the water received from snowmelt was only 31 percent of the total, it was probably the most vital part of the annual water supply. This water was available in the spring, when waterfowl were nesting, and generally lasted until about July 1, even with no additional direct rainfall on the pond or runoff from the drainage basin. The average runoff from the land surface into pothole 3 was found to be 1.2 inches per year- 1 inch from snowmelt and 0.2 inch from rainfall.'The presence of growing aquatic plants, such as bulrushes and cattails, was a complicating factor in making measurements. New computation procedures had to be devised to define the variable mass-transfer coefficient. Rating periods were divided into 6-hour units for the vegetated potholes. The instruments had to be carefully maintained, as water levels had to be recorded with such accuracy that changes of 0.001 foot could be detected. In any research project involving the measurements of physical quantities, the results are dependent upon the accuracy and dependability of the instruments used; this was especially true during this project.

  12. Distribution and Emission of Methane in Nakdong Estuary

    NASA Astrophysics Data System (ADS)

    Ryu, J.; An, S.

    2014-12-01

    Despite a small area, coastal areas contribute most to the oceanic methane flux. A wide range of methane fluxes have been reported in the coastal areas, but limited data were presented for Korean coastal areas. The air and surface water was sampled in Nakdong Estuary where the barrage had been constructed, and methane concentrations were measured using Gas Chromatography. To see the influence of the barrage, surface water was sampled outside and inside the barrage respectively. In the expectation that methane distribution would be different depending on the tides, surface water outside the barrage was collected at high and low tide respectively. Headspace technique and Membrane Inlet Mass Spectrometry were also used. The average atmospheric concentration (1.82ppm) was lower than the global average concentration expected from the IPCC scenario. The concentrations of water inside the barrage (average 173nM) were similar to those measured in other rivers but in the lower side. The average concentrations outside the barrage (52nM at high tide, 85nM at low tide) were lower than those measured in other coastal areas, but of the same order of magnitude as the European tidal estuaries. Methane concentrations in Nakdong estuary were higher than the methane concentration equilibrated with the atmosphere. The spatial variability of methane concentration in Nakdong estuary seems to be the result of the fresh (high methane) and sea (low methane) water mixing. Meanwhile large tidal flat area in Nakdong estuary should play a major role in methane dynamics and methane flux measurements during sediment incubation were conducted to evaluate the immersion/emersion cycle and photosynthesis by MPB (micro phyto benthos) effect.

  13. Water-level conditions in the Black Creek and upper Cape Fear aquifers, 1992, in parts of Bladen and Robeson counties, North Carolina

    USGS Publications Warehouse

    Strickland, Alfred Gerald

    1994-01-01

    Water-level measurements were made in 68 wells throughout an area of about 860 square miles in Bladen and Robeson Counties, North Carolina, during September and October 1992. Water levels from 58 wells were used to determine the configuration of the potentiometric surface of the Black Creek aquifer. A map of the potentiometric surface shows the potential for ground water to flow from recharge areas in the local uplands to discharge areas, such as local streams and wells. Pumping from wells at major pumping centers, such as Elizabethtown in Bladen County and Lumberton in Robeson County, where water-level declines of more than 12 feet were recorded from 1988 to 1992, has resulted in cones of depression in the potentiometric surface. The cones were about 4 and 6 miles long across the major axes beneath the Elizabethtown and Lumberton areas, respectively, in 1992. Water levels measured in eight wells in 1988 and 1992, supplemented with water levels in two additional wells from driller's well- construction records, were used to estimate average yearly rates of ground-water change for the upper Cape Fear aquifer for part of the study area. During 1988-92, water-level declines occurred in the aquifer throughout much of the area as a result of pumping. The greatest decline, an average of 4.1 feet per year, was in Bladen County.

  14. Relationship between gas exchange, wind speed, and radar backscatter in a large wind-wave tank

    NASA Technical Reports Server (NTRS)

    Wanninkhof, Richard H.; Bliven, L. F.

    1991-01-01

    The relationships between the gas exchange, wind speed, friction velocity, and radar backscatter from the water surface was investigated using data obtained in a large water tank in the Delft (Netherlands) wind-wave tunnel, filled with water supersaturated with SF6, N2O, and CH4. Results indicate that the gas-transfer velocities of these substances were related to the wind speed with a power law dependence. Microwave backscatter from water surface was found to be related to gas transfer velocities by a relationship in the form k(gas) = a 10 exp (b A0), where k is the gas transfer velocity for the particular gas, the values of a and b are obtained from a least squares fit of the average backscatter cross section and gas transfer at 80 m, and A0 is the directional (azimuthal) averaged return.

  15. Quantifying time-varying ground-water discharge and recharge in wetlands of the northern Florida Everglades

    USGS Publications Warehouse

    Choi, J.; Harvey, J.W.

    2000-01-01

    Developing a more thorough understanding of water and chemical budgets in wetlands depends in part on our ability to quantify time-varying interactions between ground water and surface water. We used a combined water and solute mass balance approach to estimate time-varying ground-water discharge and recharge in the Everglades Nutrient Removal project (ENR), a relatively large constructed wetland (1544 hectare) built for removing nutrients from agricultural drainage in the norther Everglades in South Florida, USA. Over a 4-year period (1994 through 1998), ground-water recharge averaged 13.4 hectare-meter per day (ha-m/day) or 0.9 cm/day, which is approximately 31% of surface water pumped into the ENR for treatment. In contrast, ground-water discharge was much smaller (1.4 ha-m/day, or 0.09 cm/day, or 2.8% of water input to ENR for treatment). Using a water-balance approach alone only allowed net ground-water exchange (discharge - recharge) to be estimated (-12 ?? 2.4 ha-ma/day). Disharge and recharge were individually determined by combining a chloride mass balance with the water balance. For a variety of reasons, the ground-water discharge estimated by the combined mass balance approach was not reliable (1.4 ?? 37 ha-m/day). As a result, ground-water interactions could only be reliably estimated by comparing the mass-balance results with other independent approaches, including direct seepage-meter measurements and previous estimates using ground-water modeling. All three independent approaches provided similar estimates of average ground-water recharge, ranging from 13 to 14 ha-m/day. There was also relatively good agreement between ground-water discharge estimates for the mass balance and seepage meter methods, 1.4 and 0.9 ha-m/day, respectively. However, ground-water-flow modeling provided an average discharge estimate that was approximately a factor of four higher (5.4 ha-m/day) than the other two methods. Our study developed an initial understanding of how the design and operation of the ENR increases interactions between ground water and surface water. A considerable portion of recharged ground water (73%) was collected and returned to the ENR by a seepage canal. Additional recharge that was not captured by the seepage canal only occurred when pumped inflow rates to ENR (and ENR water levels) were relatively high. Management of surface water in the northern Everglades therefore clearly has the potential to increase interactions with ground water.

  16. 2H and 18O depletion of water close to organic surfaces

    NASA Astrophysics Data System (ADS)

    Chen, Guo; Auerswald, Karl; Schnyder, Hans

    2016-06-01

    Hydrophilic surfaces influence the structure of water close to them and may thus affect the isotope composition of water. Such an effect should be relevant and detectable for materials with large surface areas and low water contents. The relationship between the volumetric solid : water ratio and the isotopic fractionation between adsorbed water and unconfined water was investigated for the materials silage, hay, organic soil (litter), filter paper, cotton, casein and flour. Each of these materials was equilibrated via the gas phase with unconfined water of known isotopic composition to quantify the isotopic difference between adsorbed water and unconfined water. Across all materials, isotopic fractionation was significant (p<0.05) and negative (on average -0.91 ± 0.22 ‰ for 18/16O and -20.6 ± 2.4 ‰ for 2/1H at an average solid : water ratio of 0.9). The observed isotopic fractionation was not caused by solutes, volatiles or old water because the fractionation did not disappear for washed or oven-dried silage, the isotopic fractionation was also found in filter paper and cotton, and the fractionation was independent of the isotopic composition of the unconfined water. Isotopic fractionation became linearly more negative with increasing volumetric solid : water ratio and even exceeded -4 ‰ for 18/16O and -44 ‰ for 2/1H. This fractionation behaviour could be modelled by assuming two water layers: a thin layer that is in direct contact and influenced by the surface of the solid and a second layer of varying thickness depending on the total moisture content that is in equilibrium with the surrounding vapour. When we applied the model to soil water under grassland, the soil water extracted from 7 and 20 cm depth was significantly closer to local meteoric water than without correction for the surface effect. This study has major implications for the interpretation of the isotopic composition of water extracted from organic matter, especially when the volumetric solid : water ratio is larger than 0.5 or for processes occurring at the solid-water interface.

  17. Estimated use of water in the United States - 1950

    USGS Publications Warehouse

    MacKichan, Kenneth Allen

    1951-01-01

    An estimated 170,000 million gallons of water was withdrawn from the ground, lakes, or streams each day on the average during 1950 and used on the farms and in the homes, factories, and business establishments of the United States. An additional 1,100,000 million gallons per day was used to generate hydro-power. Water power is the largest user of water; however, irrigation and industry also are large users of both ground and surface water. More surface water was used for industrial purposes than for irrigation, whereas more ground water was used for irrigation than for industrial purposes (fig. 1). The total withdrawal of surface water was considerably in excess of ground-water withdrawal, as shown by figure 1. Large quantities of water were used also for purposes requiring no diversion, such as navigation, waste disposal, recreation, and support of wildlife.

  18. Detailed validation of the bidirectional effect in various Case I and Case II waters.

    PubMed

    Gleason, Arthur C R; Voss, Kenneth J; Gordon, Howard R; Twardowski, Michael; Sullivan, James; Trees, Charles; Weidemann, Alan; Berthon, Jean-François; Clark, Dennis; Lee, Zhong-Ping

    2012-03-26

    Simulated bidirectional reflectance distribution functions (BRDF) were compared with measurements made just beneath the water's surface. In Case I water, the set of simulations that varied the particle scattering phase function depending on chlorophyll concentration agreed more closely with the data than other models. In Case II water, however, the simulations using fixed phase functions agreed well with the data and were nearly indistinguishable from each other, on average. The results suggest that BRDF corrections in Case II water are feasible using single, average, particle scattering phase functions, but that the existing approach using variable particle scattering phase functions is still warranted in Case I water.

  19. Surface-water availability, Tuscaloosa County, Alabama

    USGS Publications Warehouse

    Knight, Alfred L.; Davis, Marvin E.

    1975-01-01

    The average annual runoff, about 1,270 mgd (million gallons per day), originating in Tuscaloosa County is equivalent to 20 inches or 0.95 mgd per square mile. The Black Warrior and Sipsey Rivers, the largest streams in the county, have average flows of 5,230 mgd and 580 mgd, respectively, where they leave the county, and median annual 7-day low flows in excess of 150 mgd and 35 mgd, respectively. North River, Big Sandy Creek, and Hurricane Creek have average flows in excess of 100 mgd and median annual 7-day low flows in excess of 2 mgd. Surface water generally contains less than 100 mg/l (milligrams per liter) dissolved solids, less than 10 mg/l chloride, and is soft to moderately hard. Streams having the higher hardness and the higher dissolved-solids content are in eastern Tuscaloosa County.

  20. Relation between ground water and surface water in Brandywine Creek basin, Pennsylvania

    USGS Publications Warehouse

    Olmsted, F.H.; Hely, A.G.

    1962-01-01

    The relation between ground water and surface water was studied in Brandywine Creek basin, an area of 287 square miles in the Piedmont physiographic province in southeastern Pennsylvania. Most of the basin is underlain by crystalline rocks that yield only small to moderate supplies of water to wells, but the creek has an unusually well-sustained base flow. Streamflow records for the Chadds Ford, Pa., gaging station were analyzed; base flow recession curves and hydrographs of base flow were defined for the calendar years 1928-31 and 1952-53. Water budgets calculated for these two periods indicate that about two-thirds of the runoff of Brandywine Creek is base flow--a significantly higher proportion of base flow than in streams draining most other types of consolidated rocks in the region and almost as high as in streams in sandy parts of the Coastal Plain province in New Jersey and Delaware. Ground-water levels in 16 observation wells were compared with the base flow of the creek for 1952-53. The wells are assumed to provide a reasonably good sample of average fluctuations of the water table and its depth below the land surface. Three of the wells having the most suitable records were selected as index wells to use in a more detailed analysis. A direct, linear relation between the monthly average ground-water stage in the index wells and the base flow of the creek in winter months was found. The average ground-water discharge in the basin for 1952-53 was 489 cfs (316 mgd), of which slightly less than one-fourth was estimated to be loss by evapotranspiration. However, the estimated evapotranspiration from ground water, and consequently the estimated total ground-water discharge, may be somewhat high. The average gravity yield (short-term coefficient of storage) of the zone of water-table fluctuation was calculated by two methods. The first method, based on the ratio of change in ground-water storage as calculated from a witner base-flow recession curve is seasonal change in ground-water stage in the observation wells, gave values of about 7 percent using 16 wells) and 7 1/2 percent (using 3 index wells). The second method, in which the change in ground water storage is based on a hypothetical base-flow recession curve (derived from the observed linear relation between ground-water stage in the index wells and base flow), gave a value of about 10 1/2 percent. The most probable value of gravity yield is between 7 1/2 and 10 percent, but this estimate may require modification when more information on the average magnitude of water-table fluctuation and the sources of base flow of the creek become available. Rough estimates were made of the average coefficient of transmissibility of the rocks in the basin by use of the estimated total ground-water discharge for the period 1952-53, approximate values of length of discharge areas, and average water-table gradients adjacent to the discharge areas. The estimated average coefficient of transmissibility for 1952-53 is roughly 1,000 gpd per foot. The transmissibility is variable, decreasing with decreasing ground-water stage. The seeming inconsistency between the small to moderate ground-water yield to wells and the high yield to streams is explained in terms of the deep permeable soils, the relatively high gravity yield of the zone of water-table fluctuation, the steep water-table gradients toward the streams, the relatively low transmissibility of the rocks, and the rapid decreases in gravity yield below the lower limit of water-table fluctuation. It is concluded that no simple relation exists between the amount of natural ground-water discharge in an area and all the proportion of this discharge that can be diverted to wells.

  1. Surface nanotexturing of tantalum by laser ablation in water

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Barmina, E V; Simakin, Aleksandr V; Shafeev, Georgii A

    2009-01-31

    Surface nanotexturing of tantalum by ablation with short laser pulses in water has been studied experimentally using three ablation sources: a neodymium laser with a pulse duration of 350 ps, an excimer laser (248 nm) with a pulse duration of 5 ps and a Ti:sapphire laser with a pulse duration of 180 fs. The morphology of the nanotextured surfaces has been examined using a nanoprofilometer and field emission scanning electron microscope. The results demonstrate that the average size of the hillocks produced on the target surface depends on the laser energy density and is {approx}200 nm at an energy densitymore » approaching the laser-melting threshold of tantalum and a pulse duration of 350 ps. Their surface density reaches 10{sup 6} cm{sup -2}. At a pulse duration of 5 ps, the average hillock size is 60-70 nm. Nanotexturing is accompanied by changes in the absorption spectrum of the tantalum surface in the UV and visible spectral regions. The possible mechanisms of surface nanotexturing and potential applications of this effect are discussed. (nanostructures)« less

  2. Estimated use of water in the United States, 1965

    USGS Publications Warehouse

    Murray, Charles Richard

    1968-01-01

    Estimates of water use in the United States for 1965 indicate that an average of about 310 bgd (billion gallons per day) were withdrawn for public-supply, rural domestic and livestock, irrigation, and industrial (including thermoelectric power)uses--that is, about 1,600 gallons per capita per day. This represents an increase of 15 percent over the withdrawal of 270 bgd reported for 1960. Fresh water withdrawals for thermoelectric power generation increased nearly 25 percent during the 5 years, and saline water withdrawals increased 33 percent. An additional 2,300 bgd was used for hydroelectric power generation (waterpower), which also represented a 15-percent increase in 5 years. The quantity of water consumed-that is, water made unavailable for further possible withdrawal because of evaporation, incorporation in manufactured products, and other causes - was estimated to average 78 bgd for 1965, an increase of about 28 percent since 1960.Estimates made of the quantities of water withdrawn from surface and ground-water sources indicate withdrawals of 61 bgd of ground water, of which nearly 0.5 bgd was saline, and 250 bgd of surface water, of which 44 bgd was saline. The estimated amount of saline water used by industry increased 36 percent from 1960 to 1965. In addition to surface and ground water sources, reclaimed sewage supplied two-thirds of a billion gallons per day, mainly to irrigation and industry.The average annual streamflow in the United States is approximately 1,200 bgd, about four times the amount withdrawn for all purposes (except hydroelectric power) in 1965, and more than 15 times the estimated quantity of water consumed. However, comparisons of supply and demand in many river basins show that repeated use of the water is made, and at times in some basins all the available supply is consumed.In addition to tabulations of water-use data by States and by the water-use regions previously used, water-use tables are also given for the regions recently defined by the Water Resources Council for its national assessment.

  3. A 30-year record of surface mass balance (1966-95) and motion and surface altitude (1975-95) at Wolverine Glacier, Alaska

    USGS Publications Warehouse

    Mayo, Lawrence R.; Trabant, Dennis C.; March, Rod S.

    2004-01-01

    Scientific measurements at Wolverine Glacier, on the Kenai Peninsula in south-central Alaska, began in April 1966. At three long-term sites in the research basin, the measurements included snow depth, snow density, heights of the glacier surface and stratigraphic summer surfaces on stakes, and identification of the surface materials. Calculations of the mass balance of the surface strata-snow, new firn, superimposed ice, and old firn and ice mass at each site were based on these measurements. Calculations of fixed-date annual mass balances for each hydrologic year (October 1 to September 30), as well as net balances and the dates of minimum net balance measured between time-transgressive summer surfaces on the glacier, were made on the basis of the strata balances augmented by air temperature and precipitation recorded in the basin. From 1966 through 1995, the average annual balance at site A (590 meters altitude) was -4.06 meters water equivalent; at site B (1,070 meters altitude), was -0.90 meters water equivalent; and at site C (1,290 meters altitude), was +1.45 meters water equivalent. Geodetic determination of displacements of the mass balance stake, and glacier surface altitudes was added to the data set in 1975 to detect the glacier motion responses to variable climate and mass balance conditions. The average surface speed from 1975 to 1996 was 50.0 meters per year at site A, 83.7 meters per year at site B, and 37.2 meters per year at site C. The average surface altitudes were 594 meters at site A, 1,069 meters at site B, and 1,293 meters at site C; the glacier surface altitudes rose and fell over a range of 19.4 meters at site A, 14.1 meters at site B, and 13.2 meters at site C.

  4. An index for plant water deficit based on root-weighted soil water content

    NASA Astrophysics Data System (ADS)

    Shi, Jianchu; Li, Sen; Zuo, Qiang; Ben-Gal, Alon

    2015-03-01

    Governed by atmospheric demand, soil water conditions and plant characteristics, plant water status is dynamic, complex, and fundamental to efficient agricultural water management. To explore a centralized signal for the evaluation of plant water status based on soil water status, two greenhouse experiments investigating the effect of the relative distribution between soil water and roots on wheat and rice were conducted. Due to the significant offset between the distributions of soil water and roots, wheat receiving subsurface irrigation suffered more from drought than wheat under surface irrigation, even when the arithmetic averaged soil water content (SWC) in the root zone was higher. A significant relationship was found between the plant water deficit index (PWDI) and the root-weighted (rather than the arithmetic) average SWC over root zone. The traditional soil-based approach for the estimation of PWDI was improved by replacing the arithmetic averaged SWC with the root-weighted SWC to take the effect of the relative distribution between soil water and roots into consideration. These results should be beneficial for scheduling irrigation, as well as for evaluating plant water consumption and root density profile.

  5. Reducing dissolved inorganic nitrogen in surface runoff water from sugarcane production systems.

    PubMed

    Webster, A J; Bartley, R; Armour, J D; Brodie, J E; Thorburn, P J

    2012-01-01

    Nitrogen (N) lost from farms, especially as the highly bioavailable dissolved inorganic form, may be damaging Australia's Great Barrier Reef (GBR). As sugarcane is the dominant cropping system in GBR catchments, its N management practises are coming under increasing scrutiny. This study measured dissolved inorganic N lost in surface runoff water and sugarcane productivity over 3 years. The experiment compared the conventional fertiliser N application rate to sugarcane (average 180kg N/ha/year) and a rate based on replacing N exported in the previous crop (average 94kg N/ha/year). Dissolved inorganic N losses in surface water were 72%, 48% and 66% lower in the three monitored years in the reduced N fertiliser treatment. There was no significant difference in sugarcane yield between the two fertiliser N treatments, nor any treatment difference in soil mineral N - both of these results are indicators of the sustainability of the lower fertiliser N applications. Copyright © 2012 Elsevier Ltd. All rights reserved.

  6. Water resources of the New Orleans area, Louisiana

    USGS Publications Warehouse

    Eddards, Miles LeRoy; Kister, L.R.; Scarcia, Glenn

    1956-01-01

    Industry, commerce, and public utilities in 1954 withdrew about 1,500 mgd from surface- and groundwater sources in the New Orleans area. Most of the withdrawal was made from the Mississippi River. However, some withdrawal of surface water was made from Lake Pontchartrain. A large part of the withdrawal from both ground- and surface-water sources is available for reuse. Ground-water withdrawal amounts to about 100 mgd and is primarily for industrial and commercial uses. The average flow of the Mississippi River for the 23-year period, 1931--54, amounted to 309,000 mgd, and the approximate average flow of all the tributaries to Lake Pontchartrain is about 4,000 mgd. The flow of the Pearl River, which adjoins the tributary drainage area of Lake Pontchartrain, averages about 8,000 mgd. Total withdrawal of ground and surface waters amounts to less than 3 percent of the recorded minimum flow of the Mississippi River or less than 1 percent of the average flow. Although large quantities of water are always available in the Mississippi River the quality of the Water is not suitable for all uses. Streams from the north that drain into Lakes Maurepas and Pontchartrain, and the aquifers in that area, offer one of the best sources of fresh water in the State. Industry, if located on the northern shores of Lake Maurepas or Lake Pontchartrain near the mouths of these tributaries, would be assured of an ample supply of either ground or surface water of excellent quality. All the tributaries north of Lake Pontchartrain have dry-weather flows which are dependable. The Pearl River above Bogalusa also is a good source of fresh water of excellent quality. At present it serves to dilute the tidal flow of salt water into Lake Pontchartrain through the Rigolets, the principal outlet of the lake. In the area north of Lake Pontchartrain, wells 60 to 2,000 feet deep yield fresh water. There are no known wells tapping sands below 2,000 feet. However, electrical logs of. oil-test wells show that fresh water is available to a maximum depth of 3,000 feet. In the area south of Lake Pontchartrain, there is no withdrawal of ground water for public water supplies because of the saline content of the water. Three principal water-bearing sands, the '200-foot, ' '400-foot, ' and '700-foot'sands, are tapped in the New Orleans area south of Lake Pontchartrain for industrial and commercial use. In this area all deeper sands yield salt water. In some areas the '200-foot' sand contains saline water of the sodium chloride type. Consequently, this sand is not developed extensively. Water from the 200-foot' sand is relatively fresh north of the Mississippi River and becomes increasingly saline to the south and west. The 400-foot' sand is the second most highly developed aquifer in the New Orleans industrial district. The aquifer appears to be very prolific, but its full capabilities have not yet been determined. This aquifer yields a highly mineralized sodium chloride water in some areas; however, elsewhere it is a source of large quantities of fresh water. The '700-foot' sand is the most continuous freshwater bearing sand in the area and is the principal source of fresh ground water in the New Orleans industrial district. Most of the wells tapping this aquifer yield soft water of the bicarbonate type. In the southern and western parts of the industrial district the water in the '700-foot' sand is too mineralized to be suitable for human consumption.

  7. Analysis of dissolved gas and fluid chemistry in mountainous region of Goaping river watershed in southern Taiwan

    NASA Astrophysics Data System (ADS)

    Tang, Kai-Wen; Chen, Cheng-Hong; Liu, Tsung-Kwei

    2016-04-01

    Annual rainfall in Taiwan is up to 2500 mm, about 2.5 times the average value of the world. However due to high topographic relief of the Central Mountain Range in Taiwan, groundwater storage is critical for water supply. Mountain region of the Goaping river watershed in southern Taiwan is one of the potential areas to develop groundwater recharge model. Therefore the target of this study is to understand sources of groundwater and surface water using dissolved gas and fluid chemistry. Four groundwater and 6 surface water samples were collected from watershed, 5 groundwater and 13 surface water samples were collected from downstream. All samples were analyzed for stable isotopes (hydrogen and oxygen), dissolved gases (including nitrogen, oxygen, argon, methane and carbon dioxide), noble gases (helium and radon) and major ions. Hydrogen and oxygen isotopic ratios of surface water and groundwater samples aligned along meteoric water line. For surface water, dissolved gases are abundant in N2 (>80%) and O2 (>10%); helium isotopic ratio is approximately equal to 1 RA (RA is 3He/4He ratio of air); radon-222 concentration is below the detection limit (<200 Bq/m3); and concentrations of major anions and cations are low (Na+ <20 ppm, Ca2+ < 60 ppm, Cl- <2 ppm). All these features indicate that surface waters are predominately recharged by precipitation. For groundwater, helium isotopic ratios (0.9˜0.23 RA) are lower and radon-222 concentrations (300˜6000 Bq/m3) are much higher than the surface water. Some samples have high amounts of dissolved gases, such as CH4 (>20%) or CO2 (>10%), most likely contributed by biogenic or geogenic sources. On the other hand, few samples that have temperature 5° higher than the average of other samples, show significantly high Na+ (>1000 ppm), Ca2+ (>150 ppm) and Cl- (>80 ppm) concentrations. An interaction between such groundwater and local hot springs is inferred. Watershed and downstream samples differ in dissolved gas species and fluid chemistry for groundwater and surface water. The higher hydrogen and oxygen isotopic ratios for surface water from downstream are most probably caused by evaporation. Low radon-222 concentrations of some groundwater from downstream may represent sources from different aquifers. Therefore, we conclude that surface water from downstream are recharged directly from its watershed, but groundwater are influenced by the local geological environment. Keywords: groundwater, dissolved gas, noble gas, radon in water, 3He/4He

  8. Estimates of water use and trends in the Colorado River Basin, Southwestern United States, 1985–2010

    USGS Publications Warehouse

    Maupin, Molly A.; Ivahnenko, Tamara I.; Bruce, Breton

    2018-06-26

    The Colorado River Basin (CRB) drains 246,000 square miles and includes parts of California, Colorado, Nevada, New Mexico, Utah, and Wyoming, and all of Arizona (Basin States). This report contains water-use estimates by category of use for drainage basins (Hydrologic Unit Code 8; HUC‑8) within the CRB from 1985 to 2010, at 5-year intervals. Estimates for public supply, domestic, commercial, industrial, irrigation, livestock, mining, aquaculture, hydroelectric and thermoelectric power, and wastewater returns are tabulated as (1) water withdrawals from groundwater or surface‑water sources of fresh or saline quality, (2) water delivered for domestic use, (3) wastewater returns and instream use (hydroelectric), and (4) consumptive use, or water that is consumed (USGS definition) and not available for immediate reuse. Water transported outside of the CRB (interbasin transfers) is not included as part of withdrawals and are not accounted for in any category of use within the CRB.Total withdrawals in the CRB (excluding interbasin transfers) averaged about 17 million acre-feet (maf) from 1985 to 2010, peaked at about 17.76 maf in 2000, and reached their lowest levels of 16.43 maf in 1990. Interbasin transfers to serve mostly public-supply and irrigation needs outside of the CRB are reported for 2000, 2005, and 2010 only, and averaged 5.40 maf. More surface water was used in the CRB than groundwater, averaging about 78 percent of total withdrawals, and its use increased less than 2 percent from 1985 to 2010, while groundwater withdrawals decreased about 12 percent. From 1985 to 2010, surface water averaged 98 percent of withdrawals in the upper CRB, and about 59 percent in the lower CRB. Nearly all withdrawals were freshwater, but some saline groundwater was used for mining and self-supplied industrial.Interbasin transfers have a large effect on flows in the Colorado River and are listed in this report separately with no explanation of how the water is used outside of the CRB. There are 34 interbasin transfers that conveyed an estimated 5.83, 5.20, and 5.18 maf out of the CRB in 2000, 2005, and 2010, respectively. The largest interbasin transfers are in the lower CRB and convey surface water (Colorado River water) to southern California; these accounted for 80 to 84 percent of total interbasin transfers in the CRB from 2000 to 2010. Intrabasin transfers are conveyances of surface water that cross drainage basin or State boundaries in the CRB, but the water does not leave the CRB. There are many intrabasin transfers in the CRB, but this report lists 11 that are mostly in the State of Colorado. The largest is the Central Arizona Project (CAP), through which more than 1.00 maf of water was provided to irrigate nearly 1 million acres in Maricopa, Pinal, and Pima Counties, as well as provide municipal water for Phoenix and Tucson, Arizona, during 2000, 2005, and 2010. In 2010, interbasin and intrabasin transfers accounted for 24 and 11 percent of the total water withdrawals in CRB, respectively, with the larger volumes being conveyed out of the lower CRB.Total population in the CRB increased from 4.56 to 9.44 million people from 1985 to 2010. Most of those people were in the lower CRB, with 86 percent of the total in 1985, and 90 percent of the total in 2010. Total public-supply withdrawals in the CRB provided most people with their potable water, and averaged about 1.63 maf from 1985 to 2010, ranging from about 1.07 maf in 1985 to about 2.10 maf in 2010, when it peaked. Most of public-supply withdrawals occurred in the lower CRB, ranging from 87 to 91 percent of total public-supply withdrawals in the CRB over the 25 years. Total domestic use, comprised of public-supply deliveries and self-supply domestic withdrawals, increased more than 90 percent from 1985 to 2010, from about 0.80 maf to about 1.54 maf. Domestic daily per-capita use rates in the CRB ranged from about 144 (1985) to about 121 (2000) gallons (gal) per‑capita between 1985 and 2010. When comparing domestic daily per-capita rates for the upper and lower CRB, people in the lower CRB, on average, used less water for domestic purposes at 128 gal per-capita daily (1985–2010), while those in the upper CRB for the same time period averaged 133 gal per-capita daily. The trend in daily per-capita use rates for the entire CRB fluctuated between the reporting years, but decreased overall, indicating that more people used less water in 2010 than in 1985, likely due to improved infrastructure, conservation, and improvements to water using appliances in homes and businesses.Irrigation accounted for most total withdrawals in the CRB, excluding instream use for hydroelectric power and interbasin transfers, averaging 85 percent from 1985 to 2010. Far more surface water than groundwater was used for irrigation in both the upper and lower CRB, but in the upper CRB, it accounted for an average of more than 98 percent of the total withdrawals (1985–2010), whereas in the lower CRB, surface-water withdrawals for irrigation averaged 61 percent of total withdrawals. On average, the upper CRB accounted for 56 percent of total irrigated acres, and the irrigation systems in the upper CRB trended towards more efficient sprinkler systems from 1985 to 2010. Long-term drought in the CRB substantially decreased the amount of streamflow available for irrigation. Increases in micro-irrigation acres, which can have efficiencies that exceed 90 percent and require 20–50 percent less water than sprinkler systems, likely contributed to reduced withdrawals in the lower CRB.For thermoelectric power, total withdrawals, including the use of reclaimed wastewater, were greater in the upper CRB from 1985 through 2005. In 2010, the lower CRB exceeded the upper by only 11,000 acre-feet. On average, thermoelectric consumptive use accounted for about 80 percent of the total withdrawals; however, consumptive-use data in the upper CRB was incomplete. Surface water was the primary source in the upper CRB and groundwater was the primary source in the lower CRB. In the CRB overall, water withdrawals for thermoelectric generation has decreased since 2000, except for groundwater withdrawals in the lower CRB. Power generation at thermoelectric plants was greater in the upper CRB from 1985 to 2000, and after 2005 the difference in power generation was small; however, the upper CRB continued to have more power generation. In both the upper and lower CRB, power generation increased from 1985 to 2005.

  9. Orientation-dependent hydration structures at yttria-stabilized cubic zirconia surfaces

    DOE PAGES

    Hou, Binyang; Kim, Seunghyun; Kim, Taeho; ...

    2016-11-30

    Water interaction with surfaces is very important and plays key roles in many natural and technological processes. Because the experimental challenges that arise when studying the interaction water with specific crystalline surfaces, most studies on metal oxides have focused on powder samples, which averaged the interaction over different crystalline surfaces. As a result, studies on the crystal orientation-dependent interaction of water with metal oxides are rarely available in the literature. In this work, water adsorption at 8 mol % yttria-stabilized cubic single crystal zirconia (100) and (111) surfaces was studied in terms of interfacial hydration structures using high resolution X-raymore » reflectivity measurements. The interfacial electron density profiles derived from the structure factor analysis of the measured data show the existence of multiple layers of adsorbed water with additional peculiar metal adsorption near the oxide surfaces.Surface relaxation, depletion, and interaction between the adsorbed layers and bulk water are found to vary greatly between the two surfaces and are also different when compared to the previously studied (110) surface. The fractional ratio between chemisorbed and physisorbed water species were also quantitatively estimated, which turned out to vary dramatically from surface to surface. Finally, the result gives us a unique opportunity to reconsider the simplified 2:1 relation between chemisorption and physisorption, originally proposed by Morimoto et al. based on the adsorption isotherms of water on powder metal oxide samples.« less

  10. Tribological properties of fish scale inspired underwater superoleophobic hierarchical structure in aqueous environment

    NASA Astrophysics Data System (ADS)

    Lian, Zhongxu; Xu, Jinkai; Wan, Yanling; Li, Yiquan; Yu, Zhanjiang; Liu, Qimeng; Yu, Huadong

    2017-10-01

    Underwater superoleophobic surfaces are becoming increasingly important in regard to self-cleaning, anti-fouling, oil droplet transportation and water/oil separation. Although a great number of underwater superoleophobic surfaces have been demonstrated, their tribological properties remain impractical for the purposes of real-life applications. Herein, a two-step method of high speed wire electrical discharge machining and boiling water treatment was adopted to fabricate fish scale inspired underwater oil repellent hierarchical structure on an aluminum (Al) alloy 5083 surface. The hierarchical roughness and hydroxyl groups were obtained on the surface, and the surface exhibited the ability to prevent contact with organic fluids when submerged in water. Moreover, the tribological properties of underwater superoleophobic Al surfaces in aqueous environments were analyzed. The average friction coefficient of underwater superoleophobic surfaces was decreased compared with the polished Al surface. We believe that this research will contribute to the engineering application of underwater superoleophobic surfaces in the future.

  11. Distributions of dissolved monosaccharides and polysaccharides in the surface microlayer and surface water of the Jiaozhou Bay and its adjacent area

    NASA Astrophysics Data System (ADS)

    Zhang, Yan-Ping; Yang, Gui-Peng; Lu, Xiao-Lan; Ding, Hai-Bing; Zhang, Hong-Hai

    2013-07-01

    Sea surface microlayer (SML) samples and corresponding bulk surface water (SW) samples were collected in the Jiaozhou Bay and its adjacent area in July and November 2008. The average concentrations of dissolved monosaccharides (MCHO) and polysaccharides (PCHO) revealed similar temporal variability, with higher concentrations during the green-tide period (in July) than during the non-green-tide period (in November). Average enrichment factors (EF) of MCHO and PCHO, defined as the ratio of the concentration in the SML to that in the SW, were 1.3 and 1.4 in July, respectively, while those values in November were 1.9 and 1.6. Our data also showed that the concentrations of MCHO and PCHO in the SML were strongly correlated with those in the SW, indicating that most of the organic materials in the SML came from the SW. The total dissolved carbohydrate concentrations (TDCHO) in the bulk surface water were closely correlated with salinity during the cruises (July: r=-0.580, n=18, P=0.01; November: r=-0.679, n=26, P<0.001), suggesting that riverine input had an important effect on the distribution of TDCHO in surface seawater of the study area.

  12. APEX (Aqueous Photochemistry of Environmentally occurring Xenobiotics): a free software tool to predict the kinetics of photochemical processes in surface waters.

    PubMed

    Bodrato, Marco; Vione, Davide

    2014-04-01

    The APEX software predicts the photochemical transformation kinetics of xenobiotics in surface waters as a function of: photoreactivity parameters (direct photolysis quantum yield and second-order reaction rate constants with transient species, namely ˙OH, CO₃(-)˙, (1)O₂ and the triplet states of chromophoric dissolved organic matter, (3)CDOM*), water chemistry (nitrate, nitrite, bicarbonate, carbonate, bromide and dissolved organic carbon, DOC), and water depth (more specifically, the optical path length of sunlight in water). It applies to well-mixed surface water layers, including the epilimnion of stratified lakes, and the output data are average values over the considered water column. Based on intermediate formation yields from the parent compound via the different photochemical pathways, the software can also predict intermediate formation kinetics and overall yield. APEX is based on a photochemical model that has been validated against available field data of pollutant phototransformation, with good agreement between model predictions and field results. The APEX software makes allowance for different levels of knowledge of a photochemical system. For instance, the absorption spectrum of surface water can be used if known, or otherwise it can be modelled from the values of DOC. Also the direct photolysis quantum yield can be entered as a detailed wavelength trend, as a single value (constant or average), or it can be defined as a variable if unknown. APEX is based on the free software Octave. Additional applications are provided within APEX to assess the σ-level uncertainty of the results and the seasonal trend of photochemical processes.

  13. A Laboratory Study of a Water Surface in Response to Rainfall

    NASA Astrophysics Data System (ADS)

    Liu, Ren; Liu, Xinan; Duncan, James

    2016-11-01

    The shape of a water surface in response to the impact of raindrops is studied experimentally in a 1.22-m-by-1.22-m water pool with a water depth of 0.3 m. Simulated raindrops are generated by an array of 22-gauge hypodermic needles that are attached to the bottom of an open-surface water tank. The tank is connected to a 2D translation stage to provide a small-radius horizontal circular or oval motion to the needles, thus avoiding repeated drop impacts at the same location under each needle. The drop diameter is about 2.6 mm and the height of the water tank above the water surface of the pool is varied from 1 m to 4.8 m to provide different impact velocities. The water surface features including stalks, crowns and ring waves are measured with a cinematic laser-induced- fluorescence (LIF) technique. It is found that the average stalk height is strongly correlated to the impact velocities of raindrops and the phase speeds of ring waves inside the rain field are different from that measured outside the rain field.

  14. Distribution, diffusive fluxes, and toxicity of heavy metals and PAHs in pore water profiles from the northern bays of Taihu Lake.

    PubMed

    Lei, Pei; Zhang, Hong; Shan, Baoqing; Zhang, Bozheng

    2016-11-01

    Pore water plays a more significant role than do sediments in pollutant cycling dynamics. Also, concentrations of pollutants in pore water provide important information about their bioavailability or eco-toxicity; however, very few studies have focused on this topic. In this study, four duplicate sediment cores from three typical northern bays as well as the central part of Taihu Lake were collected to investigate the distribution, diffusive fluxes, and toxicity of heavy metals and polycyclic aromatic hydrocarbons (PAHs) in pore water profiles, which will be good in understanding the mobility and toxicity of these toxic pollutants and achieving better environmental management. The diffusive fluxes of heavy metals across the sediment-water interface was estimated through Fick's First Law, and the toxicity of heavy metals and PAHs in pore water was assessed by applying a water quality index (interstitial water toxicity criteria unit, IWCTU) and a hazard index (HI), respectively. The average concentrations of Cr, Cu, Ni, Pb, and Zn in surface pore water were 18.8, 23.4, 12.0, 13.5, and 42.5 μg L -1 , respectively. Also, concentrations of the selected heavy metals in both overlying water and pore water from Taihu Lake were all lower than the standard values of the environmental quality standards for surface water. The concentrations as the pore water depth increased, and the highest detected concentrations of heavy metals were recorded between 3 and 5 cm below the sediment surface. The average diffusive fluxes of these metals were 27.3, 24.8, 7.03, 7.81, and -3.32 μg (m 2 day) -1 , respectively, indicating export from sediment into overlying water, with the exception of Zn. There was a potential risk of toxicity, mainly from Pb and Cu, indicating that heavy metals in pore water had slight to moderate impact on sediment-dwelling organisms by values of the IWCTU and the Nemeraw index. The total PAH concentrations in pore water were higher than those in overlying water, and such gradient implies a potential flux of PAHs from pore water to overlying water. The average HI value of PAHs in surface pore water showed no or low ecological risk. While there may be occasional risk due to the HI values in some sites being greater than 1, the dominant contributors were carcinogenic PAHs. Because of their potential biological impact, heavy metals and PAHs and their comprehensive toxic effects in pore water should be given priority attention to keep the safety of Taihu Lake.

  15. Validation of a new device to quantify groundwater-surface water exchange

    NASA Astrophysics Data System (ADS)

    Cremeans, Mackenzie M.; Devlin, J. F.

    2017-11-01

    Distributions of flow across the groundwater-surface water interface should be expected to be as complex as the geologic deposits associated with stream or lake beds and their underlying aquifers. In these environments, the conventional Darcy-based method of characterizing flow systems (near streams) has significant limitations, including reliance on parameters with high uncertainties (e.g., hydraulic conductivity), the common use of drilled wells in the case of streambank investigations, and potentially lengthy measurement times for aquifer characterization and water level measurements. Less logistically demanding tools for quantifying exchanges across streambeds have been developed and include drive-point mini-piezometers, seepage meters, and temperature profiling tools. This project adds to that toolbox by introducing the Streambed Point Velocity Probe (SBPVP), a reusable tool designed to quantify groundwater-surface water interactions (GWSWI) at the interface with high density sampling, which can effectively, rapidly, and accurately complement conventional methods. The SBPVP is a direct push device that measures in situ water velocities at the GWSWI with a small-scale tracer test on the probe surface. Tracer tests do not rely on hydraulic conductivity or gradient information, nor do they require long equilibration times. Laboratory testing indicated that the SBPVP has an average accuracy of ± 3% and an average precision of ± 2%. Preliminary field testing, conducted in the Grindsted Å in Jutland, Denmark, yielded promising agreement between groundwater fluxes determined by conventional methods and those estimated from the SBPVP tests executed at similar scales. These results suggest the SBPVP is a viable tool to quantify groundwater-surface water interactions in high definition in sandy streambeds.

  16. Noncontact methods for measuring water-surface elevations and velocities in rivers: Implications for depth and discharge extraction

    USGS Publications Warehouse

    Nelson, Jonathan M.; Kinzel, Paul J.; McDonald, Richard R.; Schmeeckle, Mark

    2016-01-01

    Recently developed optical and videographic methods for measuring water-surface properties in a noninvasive manner hold great promise for extracting river hydraulic and bathymetric information. This paper describes such a technique, concentrating on the method of infrared videog- raphy for measuring surface velocities and both acoustic (laboratory-based) and laser-scanning (field-based) techniques for measuring water-surface elevations. In ideal laboratory situations with simple flows, appropriate spatial and temporal averaging results in accurate water-surface elevations and water-surface velocities. In test cases, this accuracy is sufficient to allow direct inversion of the governing equations of motion to produce estimates of depth and discharge. Unlike other optical techniques for determining local depth that rely on transmissivity of the water column (bathymetric lidar, multi/hyperspectral correlation), this method uses only water-surface information, so even deep and/or turbid flows can be investigated. However, significant errors arise in areas of nonhydrostatic spatial accelerations, such as those associated with flow over bedforms or other relatively steep obstacles. Using laboratory measurements for test cases, the cause of these errors is examined and both a simple semi-empirical method and computational results are presented that can potentially reduce bathymetric inversion errors.

  17. Solute transport and storage mechanisms in wetlands of the Everglades, south Florida

    USGS Publications Warehouse

    Harvey, Judson W.; Saiers, James E.; Newlin, Jessica T.

    2005-01-01

    Solute transport and storage processes in wetlands play an important role in biogeochemical cycling and in wetland water quality functions. In the wetlands of the Everglades, there are few data or guidelines to characterize transport through the heterogeneous flow environment. Our goal was to conduct a tracer study to help quantify solute exchange between the relatively fast flowing water in the open part of the water column and much more slowly moving water in thick floating vegetation and in the pore water of the underlying peat. We performed a tracer experiment that consisted of a constant‐rate injection of a sodium bromide (NaBr) solution for 22 hours into a 3 m wide, open‐ended flume channel in Everglades National Park. Arrival of the bromide tracer was monitored at an array of surface water and subsurface samplers for 48 hours at a distance of 6.8 m downstream of the injection. A one‐dimensional transport model was used in combination with an optimization code to identify the values of transport parameters that best explained the tracer observations. Parameters included dimensions and mass transfer coefficients describing exchange with both short (hours) and longer (tens of hours) storage zones as well as the average rates of advection and longitudinal dispersion in the open part of the water column (referred to as the “main flow zone”). Comparison with a more detailed set of tracer measurements tested how well the model's storage zones approximated the average characteristics of tracer movement into and out of the layer of thick floating vegetation and the pore water in the underlying peat. The rate at which the relatively fast moving water in the open water column was exchanged with slowly moving water in the layer of floating vegetation and in sediment pore water amounted to 50 and 3% h−1, respectively. Storage processes decreased the depth‐averaged velocity of surface water by 50% relative to the water velocity in the open part of the water column. As a result, flow measurements made with other methods that only work in the open part of the water column (e.g., acoustic Doppler) would have overestimated the true depth‐averaged velocity by a factor of 2. We hypothesize that solute exchange and storage in zones of floating vegetation and peat pore water increase contact time of solutes with biogeochemically active surfaces in this heterogeneous wetland environment.

  18. Developing the greatest Blue Economy: Water productivity, fresh water depletion, and virtual water trade in the Great Lakes basin

    NASA Astrophysics Data System (ADS)

    Mayer, A. S.; Ruddell, B. L.; Mubako, S. T.

    2016-12-01

    The Great Lakes basin hosts the world's most abundant surface fresh water reserve. Historically an industrial and natural resource powerhouse, the region has suffered economic stagnation in recent decades. Meanwhile, growing water resource scarcity around the world is creating pressure on water-intensive human activities. This situation creates the potential for the Great Lakes region to sustainably utilize its relative water wealth for economic benefit. We combine economic production and trade datasets with water consumption data and models of surface water depletion in the region. We find that, on average, the current economy does not create significant impacts on surface waters, but there is some risk that unregulated large water uses can create environmental flow impacts if they are developed in the wrong locations. Water uses drawing on deep groundwater or the Great Lakes themselves are unlikely to create a significant depletion, and discharge of groundwater withdrawals to surface waters offsets most surface water depletion. This relative abundance of surface water means that science-based management of large water uses to avoid accidentally creating "hotspots" is likely to be successful in avoiding future impacts, even if water use is significantly increased. Commercial water uses are the most productive, with thermoelectric, mining, and agricultural water uses in the lowest tier of water productivity. Surprisingly for such a water-abundant economy, the region is a net importer of water-derived goods and services. This, combined with the abundance of surface water, suggests that the region's water-based economy has room to grow in the 21st century.

  19. Drinking water insecurity: water quality and access in coastal south-western Bangladesh.

    PubMed

    Benneyworth, Laura; Gilligan, Jonathan; Ayers, John C; Goodbred, Steven; George, Gregory; Carrico, Amanda; Karim, Md Rezaul; Akter, Farjana; Fry, David; Donato, Katherine; Piya, Bhumika

    2016-01-01

    National drinking water assessments for Bangladesh do not reflect local variability, or temporal differences. This paper reports on the findings of an interdisciplinary investigation of drinking water insecurity in a rural coastal south-western Bangladesh. Drinking water quality is assessed by comparison of locally measured concentrations to national levels and water quality criteria; resident's access to potable water and their perceptions are based on local social surveys. Residents in the study area use groundwater far less than the national average; salinity and local rainwater scarcity necessitates the use of multiple water sources throughout the year. Groundwater concentrations of arsenic and specific conductivity (SpC) were greater than surface water (pond) concentrations; there was no statistically significant seasonal difference in mean concentrations in groundwater, but there was for ponds, with arsenic higher in the dry season. Average arsenic concentrations in local water drinking were 2-4 times times the national average. All of the local groundwater samples exceeded the Bangladesh guidance for SpC, although the majority of residents surveyed did not perceive their water as having a 'bad' or 'salty' taste.

  20. Contamination levels of human pharmaceutical compounds in French surface and drinking water.

    PubMed

    Mompelat, S; Thomas, O; Le Bot, B

    2011-10-01

    The occurrence of 20 human pharmaceutical compounds and metabolites from 10 representative therapeutic classes was analysed from resource and drinking water in two catchment basins located in north-west France. 98 samples were analysed from 63 stations (surface water and drinking water produced from surface water). Of the 20 human pharmaceutical compounds selected, 16 were quantified in both the surface water and drinking water, with 22% of the values above the limit of quantification for surface water and 14% for drinking water). Psychostimulants, non-steroidal anti-inflammatory drugs, iodinated contrast media and anxiolytic drugs were the main therapeutic classes of human pharmaceutical compounds detected in the surface water and drinking water. The results for surface water were close to results from previous studies in spite of differences in prescription rates of human pharmaceutical compounds in different countries. The removal rate of human pharmaceutical compounds at 11 water treatment units was also determined. Only caffeine proved to be resistant to drinking water treatment processes (with a minimum rate of 5%). Other human pharmaceutical compounds seemed to be removed more efficiently (average elimination rate of over 50%) by adsorption onto activated carbon and oxidation/disinfection with ozone or chlorine (not taking account of the disinfection by-products). These results add to the increasing evidence of the occurrence of human pharmaceutical compounds in drinking water that may represent a threat to human beings exposed to a cocktail of human pharmaceutical compounds and related metabolites and by-products in drinking water.

  1. Climate-Induced Changes in the Chemical Characteristics of Natural Organic Matter at a Small Freshwater Wetland

    NASA Astrophysics Data System (ADS)

    Maurice, P. A.; Cabaniss, S. E.; Drummond, J.

    2001-12-01

    This study investigated the spatiotemporal variability in dissolved organic carbon concentration (DOC), natural organic matter (NOM) weight average molecular weight (Mw), and absorptivity at 280 nm (e280, an estimator of aromaticity) at McDonalds Branch, a first-order stream that is a fen wetland. When ground-water discharge to the stream was predominant, the DOC, the Mw, and the e280 were all relatively low. When soil porewater was more important, not only was the DOC higher, but also the Mw and e280. Hence, the contribution of soil pore water relative to ground water controlled not only the concentration but also the average physicochemical characteristics of the NOM. Results from this small watershed study provide insight into climatic effects on surface-water NOM characteristics in a small freshwater fen. Low-flow periods resulted in lower Mw, more aliphatic NOM derived primarily from ground-water discharge to the stream whereas higher flow periods resulted in a higher Mw(by 150-500 Da), more aromatic downstream surface-water NOM pool. Hence, during future summer drought periods, as suggested by climate-change models for much of North America, surface-water NOM likely will be lower molecular weight, more aliphatic, and more hydrophilic with lesser metal binding and HOC uptake abilities, along with decreased ability to attenuate UV radiation.

  2. Preparation of enhanced hydrophobic poly(L-lactide-co-ɛ-caprolactone) films surface and its blood compatibility

    NASA Astrophysics Data System (ADS)

    Kim, Seung Il; Lim, Jin Ik; Jung, Youngmee; Mun, Cho Hay; Kim, Ji Heung; Kim, Soo Hyun

    2013-07-01

    Hydrophobicity-enhanced poly(L-lactide-co-ɛ-caprolactone) (PLCL) (50:50) films were cast by using the solvent-nonsolvent casting method. PLCL (50:50) was synthesized by the well-known random copolymerization process and confirmed by 1H NMR analysis. The molecular weight of the synthesized PLCL was measured by gel permeation chromatography (GPC). Number-average (Mn), weight-average (Mw) molecular weights and polydispersity (Mw/Mn) were 7 × 104, 1.2 × 105, and 1.7, respectively. PLCL films were cast in vacuum condition with various nonsolvents and nonsolvent ratios. Tetrahydrofuran (THF) was used as the solvent and three different alcohols were used as the nonsolvent: methanol, ethanol, and isopropyl alcohol (IPA). Surface hydrophobicity was confirmed by water contact angle. The water contact angle was increased from 81° ± 2° to 107° ± 2°. Water contact angle was influenced by surface porosity and topography. The prepared film surfaces were characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The change of crystalline property was characterized by X-ray diffraction (XRD). Platelet adhesion tests on the modified PLCL film surfaces were evaluated by platelet-rich plasma (PRP). The modified film surface exhibited enhanced hydrophobicity and reduced platelet adhesion ratio depending on the surface topography. One of the candidate products proposed as a potential blood compatible material showed a markedly reduced platelet adhesion property.

  3. PHYSICAL MODELING OF CONTRACTED FLOW.

    USGS Publications Warehouse

    Lee, Jonathan K.

    1987-01-01

    Experiments on steady flow over uniform grass roughness through centered single-opening contractions were conducted in the Flood Plain Simulation Facility at the U. S. Geological Survey's Gulf Coast Hydroscience Center near Bay St. Louis, Miss. The experimental series was designed to provide data for calibrating and verifying two-dimensional, vertically averaged surface-water flow models used to simulate flow through openings in highway embankments across inundated flood plains. Water-surface elevations, point velocities, and vertical velocity profiles were obtained at selected locations for design discharges ranging from 50 to 210 cfs. Examples of observed water-surface elevations and velocity magnitudes at basin cross-sections are presented.

  4. Potentiometric surface of the upper Floridan Aquifer in the St. Johns Water Management District and vicinity, Florida, May 1984

    USGS Publications Warehouse

    Schiner, George R.; Hayes, Eugene C.

    1984-01-01

    This map shows the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity for May 1984. The Upper Floridan aquifer is the principal source of potable water in the area. Water-level measurements were made on approximately 1,000 wells and on several springs. The potentiometric surface is shown mostly by 5-foot contour intervals. In the Fernandina Beach area a 40-foot interval is used to show a deep cone of depression. The potentiometric surface ranged from 126 feet above sea level in Polk County to 84 feet below sea level in Nassau County. Water levels in key wells were mostly above, or less frequently, slightly below averages for May in response to diverse area rainfall patterns. Most levels in the district were about the same, or more commonly, 1 to 2 feet lower than May 1983 levels. (USGS)

  5. Water on the surface of the Moon as seen by the Moon Mineralogy Mapper: Distribution, abundance, and origins

    PubMed Central

    Li, Shuai; Milliken, Ralph E.

    2017-01-01

    A new thermal correction model and experimentally validated relationships between absorption strength and water content have been used to construct the first global quantitative maps of lunar surface water derived from the Moon Mineralogy Mapper near-infrared reflectance data. We find that OH abundance increases as a function of latitude, approaching values of ~500 to 750 parts per million (ppm). Water content also increases with the degree of space weathering, consistent with the preferential retention of water originating from solar wind implantation during agglutinate formation. Anomalously high water contents indicative of interior magmatic sources are observed in several locations, but there is no global correlation between surface composition and water content. Surface water abundance can vary by ~200 ppm over a lunar day, and the upper meter of regolith may contain a total of ~1.2 × 1014 g of water averaged over the globe. Formation and migration of water toward cold traps may thus be a continuous process on the Moon and other airless bodies. PMID:28924612

  6. Hydrology of the Little Androscoggin River Valley aquifer, Oxford County, Maine

    USGS Publications Warehouse

    Morrissey, D.J.

    1983-01-01

    The Little Androscoggin River valley aquifer, a 15-square-mile sand and gravel valley-fill aquifer in southwestern Maine, is the source of water for the towns of Norway, Oxford, and South Paris. Estimated inflows to the aquifer during the 1981 water year were 16.4 cubic feet per second from precipitation directly on the aquifer, 11.2 cubic feet per second from till covered uplands adjacent to the aquifer, and 1.4 cubic feet per second from surface-water leakage. Outflows from the aquifer were 26.7 cubic feet per second to surface water and 2.3 cubic feet per second to wells. A finite-difference ground-water flow model was used to simulate conditions observed in the aquifer during 1981. Model conditions observed in the aquifer during 1981. Model simulations indicate that a 50 percent reduction of average 1981 recharge to the aquifer would cause water level declines of up to 20 feet in some areas. Model simulations of increased pumping at a high yield well in the northern part of the aquifer indicate that resulting changes in the water table will not be sufficient to intercept groundwater contaminated by a sludge disposal site. Water in the aquifer is low in dissolved solids (average for 38 samples was 67 mg/L), slightly acidic and soft. Ground-water contamination has occurred near a sludge-disposal site and in the vicinity of a sanitary landfill. Dissolved solids in ground water near the sludge disposal site were as much as ten times greater than average background values for the aquifer. (USGS)

  7. Feasibility of ground-water features of the alternate plan for the Mountain Home project, Idaho

    USGS Publications Warehouse

    Nace, Raymond L.; West, S.W.; Mowder, R.W.

    1957-01-01

    An early plan of the U. S. Bureau of Reclamation proposed to irrigate 183,000 acres on the arid Snake River Plain south of Boise, Idaho (Mountain Home project) with Boise River water. That water would have been replaced to the Boise Valley with water imported from the Payette River. An alternate plan, proposed in 1953, would divert water from the Boise River to the plain; part of the water would be replaced by pumping ground water in the Boise valley and by importing water from the Snake River. Pumping of ground water in the Boise Valley also would help to drain waterlogged land. The present report evaluates the feasibility of the alternate plan in relation to geology and the occurrence and quality of ground water. The mean annual temperature at Boise is 50.8 ? F and there is an average of 172 days between killing frosts. The annual evaporation rate from open-water surfaces in the area is about 33 inches. Runoff in the Boise River is chiefly from precipitation on mountain slopes at altitudes above 3,000 feet, east of Boise Diversion Dam. The surface-water supply of the Boise Valley is more Than ample for the valley, owing to large upstream storage and regulatory dams and reservoirs. The valley also contains a large volume of ground water in storage, and the perennial rate of recharge is large. The computed consumptive depletion of surface water in the valley is nearly 600,000 acre-feet a year. Apparent depletion, computed from adjusted runoff at Notus, is 1,070,000 acre-feet. The difference of 470,000 acre-feet represents ground-water underflow and ungaged surface outflow from the area east of Notus. After the beginning of irrigation, around the turn of the century, the water table in the Boise Valley rose steadily; the amount of rise at some places was as much as 140 feet. Shallow perched zones of saturation were created locally. More than 100,000 acres of Boise Valley land now is waterlogged or threatened with waterlogging, despite the presence of more than 325 miles of surface drains. Successful operation of the alternate plan would depend, not only on providing adequate water to replace that exported from the Boise Valley, but also on satisfactory drainage of waterlogged land. That is, water management in the valley would have to couple economical pumping of irrigation water with effective drainage by pumping. The average of recorded yearly diversions from the Boise River is 1,280,000 acre-feet of live water (natural flow in a stream) and 201,000 acre-feet cf recycled water. Gross diversions of record in some recent single years of ample water supply reportedly exceeded 1,800,000 acre-feet. Ground water, on the other hand is used on a relatively small scale, yearly pumpage being only about 150,000 acre-feet. The feasibility of exporting 600,000 acre-feet of Boise River water would depend on the availability of replacement water in the Boise Valley and on the availability of the required surface water in the South Fork of the Boise River at the proposed point of diversion to the Mountain Home project. In 6 of the 20 years, 1931-50, recorded diversions of live and return water from th2 Boise River exceeded the live flow at the Boise Diversion Dam by 3,865 to 107,640 acre-feet. Moreover, although the average residual discharge in the river post Notus was 701,000 acre-feet, in most years some river reaches above Notus were dry at times, owing to diversion of all water from the river. Much of the flow past Notus is surface waste and effluent ground water, which averages about 422,000 acre-feet a year. The total of potential yearly ground water recharge in the Boise Valley, derived from precipitation, incoming underflow, and infiltration of irrigation water, is about 554,000 acre-feet in the feasible exchange-pumping area and areas tributary thereto. Identified and estimated consumptive depletion of ground water in the valley is about 230,000 acre-feet a year, but not all that depletion is within the exchange are

  8. Seasonal water chemistry variability in the Pangani River basin, Tanzania.

    PubMed

    Selemani, Juma R; Zhang, Jing; Muzuka, Alfred N N; Njau, Karoli N; Zhang, Guosen; Maggid, Arafa; Mzuza, Maureen K; Jin, Jie; Pradhan, Sonali

    2017-11-01

    The stable isotopes of δ 18 O, δ 2 H, and 87 Sr/ 86 Sr and dissolved major ions were used to assess spatial and seasonal water chemistry variability, chemical weathering, and hydrological cycle in the Pangani River Basin (PRB), Tanzania. Water in PRB was NaHCO 3 type dominated by carbonate weathering with moderate total dissolved solids. Major ions varied greatly, increasing from upstream to downstream. In some stations, content of fluoride and sodium was higher than the recommended drinking water standards. Natural and anthropogenic factors contributed to the lowering rate of chemical weathering; the rate was lower than most of tropical rivers. The rate of weathering was higher in Precambrian than volcanic rocks. 87 Sr/ 86 Sr was lower than global average whereas concentration of strontium was higher than global average with mean annual flux of 0.13 × 10 6  mol year -1 . Evaporation and altitude effects have caused enrichment of δ 18 O and δ 2 H in dry season and downstream of the river. Higher d-excess value than global average suggests that most of the stations were supplied by recycled moisture. Rainfall and groundwater were the major sources of surface flowing water in PRB; nevertheless, glacier from Mt. Kilimanjaro has insignificant contribution to the surface water. We recommend measures to be taken to reduce the level of fluoride and sodium before domestic use.

  9. Surface Net Solar Radiation Estimated from Satellite Measurements: Comparisons with Tower Observations

    NASA Technical Reports Server (NTRS)

    Li, Zhanqing; Leighton, H. G.; Cess, Robert D.

    1993-01-01

    A parameterization that relates the reflected solar flux at the top of the atmosphere to the net solar flux at the surface in terms of only the column water vapor amount and the solar zenith angle was tested against surface observations. Net surface fluxes deduced from coincidental collocated satellite-measured radiances and from measurements from towers in Boulder during summer and near Saskatoon in winter have mean differences of about 2 W/sq m, regardless of whether the sky is clear or cloudy. Furthermore, comparisons between the net fluxes deduced from the parameterization and from surface measurements showed equally good agreement when the data were partitioned into morning and afternoon observations. This is in contrast to results from an empirical clear-sky algorithm that is unable to account adequately for the effects of clouds and that shows, at Boulder, a distinct morning to afternoon variation, which is presumably due to the predominance of different cloud types throughout the day. It is also demonstrated that the parameterization may be applied to irradiances at the top of the atmosphere that have been temporally averaged by using the temporally averaged column water vapor amount and the temporally averaged cosine of the solar zenith angle. The good agreement between the results of the parameterization and surface measurements suggests that the algorithm is a useful tool for a variety of climate studies.

  10. Surface restructuring behavior of various types of poly(dimethylsiloxane) in water detected by SFG.

    PubMed

    Chen, Chunyan; Wang, Jie; Chen, Zhan

    2004-11-09

    Surface structures of several different poly(dimethylsiloxane) (PDMS) materials, tetraethoxysilane-cured hydroxy-terminated PDMS (TEOS-PDMS), platinum-cured vinyl-terminated PDMS (Pt-PDMS), platinum-cured vinyl-terminated poly(diphenylsiloxane)-co-poly(dimethylsiloxane) (PDPS-co-PDMS), and PDMS-co-polystyrene (PDMS-co-PS) copolymer in air and water have been investigated by sum frequency generation (SFG) vibrational spectroscopy. The SFG spectra collected from all PDMS surfaces in both air and water are dominated by methyl group stretches, indicating that all the surfaces are mainly covered by methyl groups. Other than surface-dominating methyl groups, some -Si-CH2-CH2- moieties on the Pt-PDMS surface have also been detected in air, which are present at cross-linking points. Information about the average orientation angle and angle distribution of the methyl groups on the PDMS surface has been evaluated. Surface restructuring of the methyl groups has been observed for all PDMS surfaces in water. Upon contacting water, the methyl groups on all PDMS surfaces tilt more toward the surface. The detailed restructuring behaviors of several PDMS surfaces in water and the effects of molecular weight on restructuring behaviors have been investigated. For comparison, in addition to air and water, surface structures of PDMS materials mentioned above in a nonpolar solvent, FC-75, have also been studied. By comparing the different response of phenyl groups to water on both PDPS-co-PDMS and PS-co-PDMS surfaces, we have demonstrated how the restructuring behaviors of surface phenyl groups are affected by the structural flexibility of the molecular chains where they are attached.

  11. The effects of the variations in sea surface temperature and atmospheric stability in the estimation of average wind speed by SEASAT-SASS

    NASA Technical Reports Server (NTRS)

    Liu, W. T.

    1984-01-01

    The average wind speeds from the scatterometer (SASS) on the ocean observing satellite SEASAT are found to be generally higher than the average wind speeds from ship reports. In this study, two factors, sea surface temperature and atmospheric stability, are identified which affect microwave scatter and, therefore, wave development. The problem of relating satellite observations to a fictitious quantity, such as the neutral wind, that has to be derived from in situ observations with models is examined. The study also demonstrates the dependence of SASS winds on sea surface temperature at low wind speeds, possibly due to temperature-dependent factors, such as water viscosity, which affect wave development.

  12. Water resources of the Port Madison Indian Reservation, Washington

    USGS Publications Warehouse

    Lum, W.E.

    1979-01-01

    The study summarized in this report was made to provide Suquamish Tribal leaders with information on the reservation 's surface- and ground-water resources. The Tribal leaders need this information to help manage and protect their water resources against over-development. The quantity of ground water estimated to be available for withdrawal on a long-term basis is about 600 million gallons per year in the western part of the reservation and 400 million gallons per year in the eastern part of the reservation. It should be possible, economically and practically, to capture at least 40 percent of this ground water with properly constructed and located wells before it is discharged into the sea. This is enough water to supply at least 5,000 and 3,500 people with domestic water in these respective areas--about four times the present population. Of nine stream sites that were studied, the lowest average streamflows for a 7-day period estimated to occur an average of once in 2 years were 1.3 cubic feet per second or less. Streams at three of the sites have been observed dry at least once. The short period of data collection during this study limits the accuracy of statistical estimates of low flows. Both surface and ground water are of good quality with no unusual or harmful constituents; there was no evidence of major pollution in 1977. In the future, seawater intrusion into the ground-water system and pollution of the surface water by improperly treated sewage waste water could become problems. (Woodard-USGS).

  13. How accurately are climatological characteristics and surface water and energy balances represented for the Colombian Caribbean Catchment Basin?

    NASA Astrophysics Data System (ADS)

    Hoyos, Isabel; Baquero-Bernal, Astrid; Hagemann, Stefan

    2013-09-01

    In Colombia, the access to climate related observational data is restricted and their quantity is limited. But information about the current climate is fundamental for studies on present and future climate changes and their impacts. In this respect, this information is especially important over the Colombian Caribbean Catchment Basin (CCCB) that comprises over 80 % of the population of Colombia and produces about 85 % of its GDP. Consequently, an ensemble of several datasets has been evaluated and compared with respect to their capability to represent the climate over the CCCB. The comparison includes observations, reconstructed data (CPC, Delaware), reanalyses (ERA-40, NCEP/NCAR), and simulated data produced with the regional climate model REMO. The capabilities to represent the average annual state, the seasonal cycle, and the interannual variability are investigated. The analyses focus on surface air temperature and precipitation as well as on surface water and energy balances. On one hand the CCCB characteristics poses some difficulties to the datasets as the CCCB includes a mountainous region with three mountain ranges, where the dynamical core of models and model parameterizations can fail. On the other hand, it has the most dense network of stations, with the longest records, in the country. The results can be summarised as follows: all of the datasets demonstrate a cold bias in the average temperature of CCCB. However, the variability of the average temperature of CCCB is most poorly represented by the NCEP/NCAR dataset. The average precipitation in CCCB is overestimated by all datasets. For the ERA-40, NCEP/NCAR, and REMO datasets, the amplitude of the annual cycle is extremely high. The variability of the average precipitation in CCCB is better represented by the reconstructed data of CPC and Delaware, as well as by NCEP/NCAR. Regarding the capability to represent the spatial behaviour of CCCB, temperature is better represented by Delaware and REMO, while precipitation is better represented by Delaware. Among the three datasets that permit an analysis of surface water and energy balances (REMO, ERA-40, and NCEP/NCAR), REMO best demonstrates the closure property of the surface water balance within the basin, while NCEP/NCAR does not demonstrate this property well. The three datasets represent the energy balance fairly well, although some inconsistencies were found in the individual balance components for NCEP/NCAR.

  14. Ground-water levels in the alluvial aquifer in Eastern Arkansas, 1989

    USGS Publications Warehouse

    Westerfield, P.W.; Baxter, C.R.

    1990-01-01

    This report, prepared by the U.S. Geological Survey in cooperation with the Arkansas Soil and Water Conservation Commission, the U.S. Soil Conservation Service and local Conservation Districts, contains groundwater level measurements of 504 wells that tap the alluvial aquifer in the Quaternary deposits of the Mississippi Alluvial Plain. The measurements were made by district Soil Conservation Service personnel during 1989. The shallowest prepumping season water levels occurred in Clay, Greene, Independence, Mississippi, Phillips, and Randolph Counties where water levels averaged less than 20 ft below the land surface. The deepest water levels occurred in Arkansas, Lonoke, Poinsett, and Prairie Counties where water levels of more than 100 ft were measured. Water levels in the postpumping season averaged about 2.5 ft lower than during the prepumping season. (USGS)

  15. Seasonal Variation of Phytoplankton and Primary Production in the Thames River, Southeastern Connecticut

    NASA Astrophysics Data System (ADS)

    Wainright, S. C.

    2016-02-01

    A year-long study was performed to investigate seasonal changes in the phytoplankton biomass and primary production in the Thames River, a salt wedge estuary that empties into Long Island Sound in southeastern CT. Chlorophyll measurements were made on discrete filtered samples collected above and below the 1-3 m deep pycnocline at a 5-meter deep station. Surface chlorophyll concentrations, primarily from diatoms, averaged approx. 2 mg m-3, with maxima (up to 10 mg m-3) during summer months (Jun to Aug) and minima during October through March (as low as 0.3 mg m-3). The lower water layer had nearly the same annual average but a smaller range (0.7-3.3 mg m-3) and a winter/spring bloom (Jan-Apr) that was not seen in surface water. During most of the winter, chlorophyll concentrations were higher in the lower layer. Primary production, as measured by 13C uptake in bottle incubations, averaged 67 mgC m-3 h-1 in surface water [range 0.1 (Jan 2012) to 800 mgC m-3 h-1 (Aug 2011)], and 3 mgC m-3 h-1 [range 0.04 (Jan 2012) to 17 mgC m-3 h-1 (Aug 2011)] in the lower layer. On most occasions, deep water incubated near the surface had a higher primary production rate than surface water incubated at the surface; apparently the light-limited phytoplankton in the lower layer were released from light-limitation during these incubations. During the study period there were over a dozen heavy wind or heavy rain events, including Hurricane Irene in August and a freak Nor'easter snow storm in October 2011. Hurricane Irene was associated with a large decline in phytoplankton biomass and primary production. With significant storms as frequent as the rate of sampling, it is difficult to separate a "storm effect" from a background seasonal pattern. The study reveals that phytoplankton, especially those in the lower layer, are light-limited in the Thames River estuary, and that the effects of significant storm events are superimposed on significant seasonal variation.

  16. Mass fluxes of organic pollutants between groundwater, streambed sediments and surface water

    NASA Astrophysics Data System (ADS)

    Schirmer, Mario; Kalbus, Edda; Schmidt, Christian

    2010-05-01

    Rivers and groundwater are commonly hydraulically connected and thus also pollutants migrate between one and the other. Particularly in small lowland streams, pollutant transport by discharging groundwater can deteriorate the surface water quality. Moreover, in urban and industrial areas streambed sediments are often polluted with a variety of organic and inorganic substances. For planning measures to improve surface water quality or to mitigate pollutant migration, it is an essential prerequisite to understand pollutant pathways and mass fluxes between the stream, the streambed sediment and the connected aquifer. We present methodological approaches and results of a study conducted at a small man-made stream located in the industrial area of Bitterfeld-Wolfen, Germany. This site is characterized by a diffuse groundwater contamination with a variety of aliphatic and aromatic organic substances. The underlying approach of this study was to quantify the mass fluxes between the aquifer, the streambed and the stream by combining high-resolution with integral monitoring approaches. Magnitudes and pattern of water fluxes were obtained by mapping streambed temperatures. The method was applied to a reach of 280 m in length. The mass fluxes from the aquifer towards the stream were estimated by combining the water fluxes with representative, average pollutant concentrations. The concentrations were obtained from an integral pumping test with four simultaneously pumped wells operated for the period of five days. For monochlorobenzene (MCB), the main groundwater pollutant at the site, the resulting average mass flux from the aquifer towards the stream was estimated to 724 µg/m²/d. Mass flux calculations with average aqueous concentrations of MCB in the streambed were found to be higher than those originating from the aquifer. Consequently, the streambed sediments represent a secondary pollutant source for the surface water. Pollutant concentrations in the streambed were lower at locations with high groundwater discharge and vice versa. Hence, the spatial heterogeneity of water fluxes must be considered when mass fluxes between surface water and streambed sediments are assessed. River restoration could improve the structural state of rivers and may thus result in an enhanced biodegradation of organic pollutants in the streambed. However, before any physical measure is applied a profound knowledge of pollutant concentration and pathways is required in order to avoid mobilization of sediment-bound pollutants.

  17. Simulated effects of irrigation on salinity in the Arkansas River Valley in Colorado

    USGS Publications Warehouse

    Goff, K.; Lewis, M.E.; Person, M.A.; Konikow, Leonard F.

    1998-01-01

    Agricultural irrigation has a substantial impact on water quantity and quality in the lower Arkansas River valley of southeastern Colorado. A two-dimensional flow and solute transport model was used to evaluate the potential effects of changes in irrigation on the quantity and quality of water in the alluvial aquifer and in the Arkansas River along an 17.7 km reach of the fiver. The model was calibrated to aquifer water level and dissolved solids concentration data collected throughout the 24 year study period (197195). Two categories of irrigation management were simulated with the calibrated model: (1) a decrease in ground water withdrawals for irrigation; and (2) cessation of all irrigation from ground water and surface water sources. In the modeled category of decreased irrigation from ground water pumping, there was a resulting 6.9% decrease in the average monthly ground water salinity, a 0.6% decrease in average monthly river salinity, and an 11.1% increase in ground water return flows to the river. In the modeled category of the cessation of all irrigation, average monthly ground water salinity decreased by 25%; average monthly river salinity decreased by 4.4%; and ground water return flows to the river decreased by an average of 64%. In all scenarios, simulated ground water salinity decreased relative to historical conditions for about 12 years before reaching a new dynamic equilibrium condition. Aquifer water levels were not sensitive to any of the modeled scenarios. These potential changes in salinity could result in improved water quality for irrigation purposes downstream from the affected area.

  18. Determination of hydrologic properties needed to calculate average linear velocity and travel time of ground water in the principal aquifer underlying the southeastern part of Salt Lake Valley, Utah

    USGS Publications Warehouse

    Freethey, G.W.; Spangler, L.E.; Monheiser, W.J.

    1994-01-01

    A 48-square-mile area in the southeastern part of the Salt Lake Valley, Utah, was studied to determine if generalized information obtained from geologic maps, water-level maps, and drillers' logs could be used to estimate hydraulic conduc- tivity, porosity, and slope of the potentiometric surface: the three properties needed to calculate average linear velocity of ground water. Estimated values of these properties could be used by water- management and regulatory agencies to compute values of average linear velocity, which could be further used to estimate travel time of ground water along selected flow lines, and thus to determine wellhead protection areas around public- supply wells. The methods used to estimate the three properties are based on assumptions about the drillers' descriptions, the depositional history of the sediments, and the boundary con- ditions of the hydrologic system. These assump- tions were based on geologic and hydrologic infor- mation determined from previous investigations. The reliability of the estimated values for hydro- logic properties and average linear velocity depends on the accuracy of these assumptions. Hydraulic conductivity of the principal aquifer was estimated by calculating the thickness- weighted average of values assigned to different drillers' descriptions of material penetrated during the construction of 98 wells. Using these 98 control points, the study area was divided into zones representing approximate hydraulic- conductivity values of 20, 60, 100, 140, 180, 220, and 250 feet per day. This range of values is about the same range of values used in developing a ground-water flow model of the principal aquifer in the early 1980s. Porosity of the principal aquifer was estimated by compiling the range of porosity values determined or estimated during previous investigations of basin-fill sediments, and then using five different values ranging from 15 to 35 percent to delineate zones in the study area that were assumed to be underlain by similar deposits. Delineation of the zones was based on depositional history of the area and the distri- bution of sediments shown on a surficial geologic map. Water levels in wells were measured twice in 1990: during late winter when ground-water with- drawals were the least and water levels the highest, and again in late summer, when ground- water withdrawals were the greatest and water levels the lowest. These water levels were used to construct potentiometric-contour maps and subsequently to determine the variability of the slope in the potentiometric surface in the area. Values for the three properties, derived from the described sources of information, were used to produce a map showing the general distribution of average linear velocity of ground water moving through the principal aquifer of the study area. Velocity derived ranged from 0.06 to 144 feet per day with a median of about 3 feet per day. Values were slightly faster for late summer 1990 than for late winter 1990, mainly because increased with- drawal of water during the summer created slightly steeper hydraulic-head gradients between the recharge area near the mountain front and the well fields farther to the west. The fastest average linear-velocity values were located at the mouth of Little Cottonwood Canyon and south of Dry Creek near the mountain front, where the hydraulic con- ductivity was estimated to be the largest because the drillers described the sediments to be pre- dominantly clean and coarse grained. Both of these areas also had steep slopes in the potentiometric surface. Other areas where average linear velocity was fast included small areas near pumping wells where the slope in the potentiometric surface was locally steepened. No apparent relation between average linear velocity and porosity could be seen in the mapped distributions of these two properties. Calculation of travel time along a flow line to a well in the southwestern part of the study area during the sum

  19. Wintertime Emissions from Produced Water Ponds

    NASA Astrophysics Data System (ADS)

    Evans, J.; Lyman, S.; Mansfield, M. L.

    2013-12-01

    Every year oil and gas drilling in the U.S. generates billions of barrels of produced water (water brought to the surface during oil or gas production). Efficiently disposing of produced water presents a constant financial challenge for producers. The most noticeable disposal method in eastern Utah's Uintah Basin is the use of evaporation ponds. There are 427 acres of produced water ponds in the Uintah Basin, and these were used to evaporate more than 5 million barrels of produced water in 2012, 6% of all produced water in the Basin. Ozone concentrations exceeding EPA standards have been observed in the Uintah Basin during winter inversion conditions, with daily maximum 8 hour average concentrations at some research sites exceeding 150 parts per billion. Produced water contains ozone-forming volatile organic compounds (VOC) which escape into the atmosphere as the water is evaporated, potentially contributing to air quality problems. No peer-reviewed study of VOC emissions from produced water ponds has been reported, and filling this gap is essential for the development of accurate emissions inventories for the Uintah Basin and other air sheds with oil and gas production. Methane, carbon dioxide, and VOC emissions were measured at three separate pond facilities in the Uintah Basin in February and March of 2013 using a dynamic flux chamber. Pond emissions vary with meteorological conditions, so measurements of VOC emissions were collected during winter to obtain data relevant to periods of high ozone production. Much of the pond area at evaporation facilities was frozen during the study period, but areas that actively received water from trucks remained unfrozen. These areas accounted for 99.2% of total emissions but only 9.5% of the total pond area on average. Ice and snow on frozen ponds served as a cap, prohibiting VOC from being emitted into the atmosphere. Emissions of benzene, toluene, and other aromatic VOCs averaged over 150 mg m-2 h-1 from unfrozen pond surfaces. These compounds are highly reactive and, because of their relatively high water solubility, tend to concentrate in produced water. The average methanol emission rate from unfrozen pond surfaces was more than 100 mg m-2 h-1. Methanol, used as an antifreeze and anti-scaler in the oil and gas industry, is abundant during winter inversions in the Uintah Basin and may also be a significant precursor to ozone production. Total VOC and methanol emissions from produced water ponds during winter were estimated to be 178 and 83 tons month-1, respectively, for the entire Uintah Basin.

  20. Per- and Polyfluoroalkyl Substances in Swedish Groundwater and Surface Water: Implications for Environmental Quality Standards and Drinking Water Guidelines.

    PubMed

    Gobelius, Laura; Hedlund, Johanna; Dürig, Wiebke; Tröger, Rikard; Lilja, Karl; Wiberg, Karin; Ahrens, Lutz

    2018-04-03

    The aim of this study was to assess per- and polyfluoroalkyl substances (PFASs) in the Swedish aquatic environment, identify emission sources, and compare measured concentrations with environmental quality standards (EQS) and (drinking) water guideline values. In total, 493 samples were analyzed in 2015 for 26 PFASs (∑ 26 PFASs) in surface water, groundwater, landfill leachate, sewage treatment plant effluents and reference lakes, focusing on hot spots and drinking water sources. Highest ∑ 26 PFAS concentrations were detected in surface water (13 000 ng L -1 ) and groundwater (6400 ng L -1 ). The dominating fraction of PFASs in surface water were perfluoroalkyl carboxylates (PFCAs; 64% of ∑ 26 PFASs), with high contributions from C 4 -C 8 PFCAs (94% of ∑PFCAs), indicating high mobility of shorter chain PFCAs. In inland surface water, the annual average (AA)-EQS of the EU Water Framework Directive of 0.65 ng L -1 for ∑PFOS (linear and branched isomers) was exceeded in 46% of the samples. The drinking water guideline value of 90 ng L -1 for ∑ 11 PFASs recommended by the Swedish EPA was exceeded in 3% of the water samples from drinking water sources ( n = 169). The branched isomers had a noticeable fraction in surface- and groundwater for perfluorooctanesulfonamide, perfluorohexanesulfonate, and perfluorooctanesulfonate, highlighting the need to include branched isomers in future guidelines.

  1. Conceptual Analysis of System Average Water Stability

    NASA Astrophysics Data System (ADS)

    Zhang, H.

    2016-12-01

    Averaging over time and area, the precipitation in an ecosystem (SAP - system average precipitation) depends on the average surface temperature and relative humidity (RH) in the system if uniform convection is assumed. RH depends on the evapotranspiration of the system (SAE - system average evapotranspiration). There is a non-linear relationship between SAP and SAE. Studying this relationship can lead mechanistic understanding of the ecosystem health status and trend under different setups. If SAP is higher than SAE, the system will have a water runoff which flows out through rivers. If SAP is lower than SAE, irrigation is needed to maintain the vegetation status. This presentation will give a conceptual analysis of the stability in this relationship under different assumed areas, water or forest coverages, elevations and latitudes. This analysis shows that desert is a stable system. Water circulation in basins is also stabilized at a specific SAP based on the basin profile. It further shows that deforestation will reduce SAP, and can flip the system to an irrigation required status. If no irrigation is provided, the system will automatically reduce to its stable point - desert, which is extremely difficult to turn around.

  2. Simulation of hydraulic characteristics in the white sturgeon spawning habitat of the Kootenai River near Bonners Ferry, Idaho

    USGS Publications Warehouse

    Berenbrock, Charles

    2005-01-01

    Hydraulic characterization of the Kootenai River, especially in the white sturgeon spawning habitat reach, is needed by the Kootenai River White Sturgeon Recovery Team to promote hydraulic conditions that improve spawning conditions for the white sturgeon (Acipenser transmontanus) in the Kootenai River. The decreasing population and spawning failure of white sturgeon has led to much concern. Few wild juvenile sturgeons are found in the river today. Determining the location of the transition between backwater and free-flowing water in the Kootenai River is a primary focus for biologists who believe that hydraulic changes at the transition affect the location where the sturgeon choose to spawn. The Kootenai River begins in British Columbia, Canada, and flows through Montana, Idaho, and back into British Columbia. The 65.6-mile reach of the Kootenai River in Idaho was studied. The study area encompasses the white sturgeon spawning reach that has been designated as a critical habitat. A one-dimensional hydraulic-flow model of the study reach was developed, calibrated, and used to develop relations between hydraulic characteristics and water-surface elevation, discharge, velocity, and backwater extent. The model used 164 cross sections, most of which came from a previous river survey conducted in 2002-03. The model was calibrated to water-surface elevations at specific discharges at five gaging stations. Calibrated water-surface elevations ranged from about 1,743 to about 1,759 feet, and discharges used in calibration ranged from 5,000 to 47,500 cubic feet per second. Model calibration was considered acceptable when the difference between measured and simulated water-surface elevations was ?0.15 foot or less. Measured and simulated average velocities also were compared. These comparisons indicated agreement between measured and simulated values. The location of the transition between backwater and free-flowing water was determined using the calibrated model. The model was used to simulate hydraulic characteristics for a range of water-surface elevations from 1,741 to 1,762 feet and discharges from 4,000 to 75,000 cubic feet per second. These simulated hydraulic characteristics were used to develop a three-parameter relation-discharge in the study reach, water-surface elevation at Kootenai River at Porthill gaging station (12322000), and the location of the transition between backwater and free-flowing water. Simulated hydraulic characteristics produced backwater locations ranging from river mile (RM) 105.6 (Porthill) to RM 158 (near Crossport), a span of about 52 miles. However, backwater locations from measured data ranged primarily from RM 152 to RM 157, a 5-mile span. The average backwater location from measured data was at about RM 154. Three-parameter relations also were developed for determining the amount of discharge in the Shorty Island side channel and average velocity at selected cross sections in the study reach. Simulated discharge for the side channel relative to measured data ranged from 0 to about 5,500 cubic feet per second, and simulated average velocity relative to measured data ranged from 0 to about 3.5 feet per second. Relations using other hydraulic, sediment/incipient motion, ecological, and biological characteristics also could be developed. The relations also can be used in real time by accessing data from the Web. Discharge and stage data for two gaging stations, Tribal Hatchery (12310100) and Porthill (12322500), are available from the Idaho U.S. Geological Survey web page (URL: http://waterdata.usgs.gov/id/nwis/current/?type=flow). Because the coordinate axes of the three-parameter relations use discharge from the Tribal Hatchery gaging station and water-surface elevation from the Porthill gaging station, the location of the transition between backwater and free-flowing water can be determined for current conditions using the real-time data. Similarly, discharge in the Shorty Island side channel and (or) average velocity at selected cross sections also can be determined for current conditions.

  3. Water-quality characteristics of urban runoff and estimates of annual loads in the Tampa Bay area, Florida, 1975-80

    USGS Publications Warehouse

    Lopez, M.A.; Giovannelli, R.F.

    1984-01-01

    Rainfall, runoff, and water quality data were collected at nine urban watersheds in the Tampa Bay area from 1975 to 1980. Watershed drainage area ranged from 0.34 to 0.45 sq mi. Land use was mixed. Development ranged from a mostly residential watershed with a 19% impervious surface, to a commercial-residential watershed with a 61% impervious surface. Average biochemical oxygen demand concentrations of base flow at two sites and of stormwater runoff at five sites exceeded treated sewage effluent standards. Average coliform concentrations of stormwater runoff at all sites were several orders of magnitude greater than standards for Florida Class III receiving water (for recreation or propagation and management of fish and wildlife). Average concentrations of lead and zinc in stormwater runoff were consistently higher than Class III standards. Stormwater-runoff loads and base-flow concentrations of biochemical oxygen demand, chemical oxygen demand, total nitrogen, total organic nitrogen, total phosphorus, and lead were related to runoff volume, land use, urban development, and antecedent daily rainfall by multiple linear regression. Stormwater-runoff volume was related to pervious area, hydraulically connected impervious surfaces, storm rainfall, and soil-infiltration index. Base-flow daily discharge was related to drainage area and antecedent daily rainfall. The flow regression equations of this report were used to compute 1979 water-year loads of biochemical oxygen demand, chemical oxygen demand, total nitrogen, total organic nitrogen, total phosphorus , and total lead for the nine Tampa Bay area urban watersheds. (Lantz-PTT)

  4. Spatial variability in the response of surface-water extent to climate extremes across the Prairie Pothole Region and adjacent Northern Prairie, United States

    NASA Astrophysics Data System (ADS)

    Vanderhoof, M.; Lane, C.; McManus, M.; Alexander, L. C.; Christensen, J.

    2017-12-01

    Surface-water extent, duration and movement will depend not only on climatic inputs but also the relative importance of different hydrologic pathways (e.g., surface storage, infiltration, evapotranspiration, stream outflows). We mapped surface-water extent from historic drought years to historic wet years spanning 1985 - 2015 across eleven Landsat path/rows representing the Prairie Pothole Region (PPR) and adjacent Northern Prairie of the United States. The PPR not only experienced a greater surface water extent under median conditions (2.6 times more) relative to the adjacent Northern Prairie, but showed a greater difference between drought and deluge conditions as well (range averaged 8.5 ha surface water km-2 relative to 2.5 ha surface water km-2 for the PPR and Northern Prairie, respectively). To explain the spatial variability in the amount of surface water expansion and contraction we used a two-stage modeling approach. First, surface-water extent was regressed on accumulated water availability (precipitation minus potential evapotranspiration). The slope of surface-water extent to climate inputs (per watershed) was our dependent variable in the second stage. That slope was regressed against independent variables representing hydrology-related landscape characteristics (e.g., infiltration capacity, surface storage capacity, stream density). Stream-connected surface water can leave via stream flow, influencing the rate at which surface-water may leave a location, therefore stream-connected and disconnected surface water were analyzed separately. Stream-connected surface water responded more strongly to wetter climatic conditions (i.e., accumulated) in landscapes with more lakes and less artificial drainage (e.g., ditching, tile drainage). Disconnected surface water responded more strongly to wetter climatic conditions when landscapes contained greater wetland density, fewer streams and a lower predicted rate of infiltration. From these findings, we can expect that the relationship between upstream and downstream waters will require consideration of hydrology-related landscape characteristics, and that climate-change related shifts in precipitation and evaporative demand will have an uneven effect on surface water expansion and contraction across the landscape.

  5. Status and trends of dissolved oxygen in Corpus Christi Bay, Texas, U.S.A.

    PubMed

    Applebaum, Sally; Montagna, Paul A; Ritter, Christine

    2005-08-01

    The purpose of this study was to determine status and long-term trends of dissolved oxygen concentrations (DO) in Corpus Christi Bay, Texas, U.S.A. A 20-year record of randomized stations was used to determine the trend of surface water DO, salinity, and temperature over space and time. A 13-year record of two fixed stations was used to determine the temporal nutrient trends. A 10-year record of fixed stations in the southeastern region of Corpus Christi Bay was used to determine the status of disturbance caused by low DO in bottom waters. From 1982 to 2002, there was a significant decrease in surface water DO at a rate of 0.06 mg L(-1) yr(-1) and a significant increase in surface water temperature at a rate of 0.07 degrees C yr(-1). The southeastern region of Corpus Christi Bay had the lowest average DO, and during July and August, DO are steadily declining at a rate of 0.09 mg L(-1) yr(-1). It is not likely that eutrophication is causing hypoxia, because freshwater inflow rates have significantly decreased since 1941 and nutrient levels have not changed from 1987 to 2000. Even though long-term trends indicate that average surface DO is decreasing, disturbance by hypoxia appears to be stable, but this may be due to just eight years of data. In fact, if the current trend continues, surface water DO will not meet exceptional aquatic life standards (< or = 5 mg L(-1)) in 2032.

  6. Methanethiol Concentrations and Sea-Air Fluxes in the Subarctic NE Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Kiene, R. P.; Williams, T. E.; Esson, K.; Tortell, P. D.; Dacey, J. W. H.

    2017-12-01

    Exchange of volatile organic sulfur from the ocean to the atmosphere impacts the global sulfur cycle and the climate system and is thought to occur mainly via the gas dimethylsulfide (DMS). DMS is produced during degradation of the abundant phytoplankton osmolyte dimethylsulfoniopropionate (DMSP) but bacteria can also convert dissolved DMSP into the sulfur gas methanethiol (MeSH). MeSH has been difficult to measure in seawater because of its high chemical and biological reactivity and, thus, information on MeSH concentrations, distribution and sea-air fluxes is limited. We measured MeSH in the northeast subarctic Pacific Ocean in July 2016, along transects with strong phytoplankton abundance gradients. Water samples obtained with Niskin bottles were analyzed for MeSH by purge-and-trap gas chromatography. Depth profiles showed that MeSH concentrations were high near the surface and declined with depth. Surface waters (5 m depth) had an average MeSH concentration of 0.75 nM with concentrations reaching up to 3nM. MeSH concentrations were correlated (r = 0.47) with microbial turnover of dissolved DMSP which ranged up to 236 nM per day. MeSH was also correlated with total DMSP (r = 0.93) and dissolved DMS (r = 0.63), supporting the conclusion that DMSP was a major precursor of MeSH. Surface water MeSH:DMS concentration ratios averaged 0.19 and ranged up to 0.50 indicating that MeSH was a significant fraction of the volatile sulfur pool in surface waters. Sea-air fluxes of MeSH averaged 15% of the combined DMS+MeSH flux, therefore MeSH contributed an important fraction of the sulfur emitted to the atmosphere from the subarctic NE Pacific Ocean.

  7. Relationship between changes in the upper and lower tropospheric water vapor: A revisit

    NASA Astrophysics Data System (ADS)

    Yang, M.; Sun, D. Z.; Zhang, G. J.

    2017-12-01

    Upper tropospheric water vapor response to enhanced greenhouse gas forcing is as important as the lower tropospheric water vapor response in determining climate sensitivity. Early studies using older versions of climate models have suggested that the upper- and lower-troposphere water vapor changes are more strongly coupled in the climate models than in the observations. Here we reexamine this issue using a state-of-the-art climate model—the NCAR community model CAM5. Specifically, we have calculated the correlations between interannual variations of specific humidity in all levels of the troposphere with that at the surface in CAM5 and in the observations (as represented by the updated ERA-Interim and NCEP reanalysis). It is found that the previously noted biases in how strongly upper tropospheric water vapor and lower troposphere water vapor are linked still exist in CAM5—the change in the tropical averaged upper tropospheric water vapor is more strongly correlated with the change in the surface. However, this bias disappears in the averaged correlation obtained by averaging the point-by-point correlations over the tropics. The spatial pattern of the point-by-point correlations reveals that the better agreement between the model and the observations is related to the opposite model biases in different regions: the correlation is weaker in the model in the western Pacific, but stronger in the central and eastern Pacific. Further analysis of precipitation fields suggests that the weaker (stronger) coupling between tropospheric water vapor and surface moisture over western (central-eastern) Pacific in model is related to weaker (stronger) simulated convective activities in these regions. More specifically, during El Nino, the model has excessive deep convection in the central Pacific, but too littler deep convection in western Pacific. Implications of the results are discussed in the context of climate change as well as in the context of how to improve the model in this regard.

  8. Patterns and drivers for wetland connections in the Prairie Pothole Region, United States

    USGS Publications Warehouse

    Vanderhoof, Melanie; Christensen, Jay R.; Alexander, Laurie C.

    2017-01-01

    Ecosystem function in rivers, lakes and coastal waters depends on the functioning of upstream aquatic ecosystems, necessitating an improved understanding of watershed-scale interactions including variable surface-water flows between wetlands and streams. As surface water in the Prairie Pothole Region expands in wet years, surface-water connections occur between many depressional wetlands and streams. Minimal research has explored the spatial patterns and drivers for the abundance of these connections, despite their potential to inform resource management and regulatory programs including the U.S. Clean Water Act. In this study, wetlands were identified that did not intersect the stream network, but were shown with Landsat images (1990–2011) to become merged with the stream network as surface water expanded. Wetlands were found to spill into or consolidate with other wetlands within both small (2–10 wetlands) and large (>100 wetlands) wetland clusters, eventually intersecting a stream channel, most often via a riparian wetland. These surface-water connections occurred over a wide range of wetland distances from streams (averaging 90–1400 m in different ecoregions). Differences in the spatial abundance of wetlands that show a variable surface-water connection to a stream were best explained by smaller wetland-to-wetland distances, greater wetland abundance, and maximum surface-water extent. This analysis demonstrated that wetland arrangement and surface water expansion are important mechanisms for depressional wetlands to connect to streams and provides a first step to understanding the frequency and abundance of these surface-water connections across the Prairie Pothole Region.

  9. Networks of triboelectric nanogenerators for harvesting water wave energy: a potential approach toward blue energy.

    PubMed

    Chen, Jun; Yang, Jin; Li, Zhaoling; Fan, Xing; Zi, Yunlong; Jing, Qingshen; Guo, Hengyu; Wen, Zhen; Pradel, Ken C; Niu, Simiao; Wang, Zhong Lin

    2015-03-24

    With 70% of the earth's surface covered with water, wave energy is abundant and has the potential to be one of the most environmentally benign forms of electric energy. However, owing to lack of effective technology, water wave energy harvesting is almost unexplored as an energy source. Here, we report a network design made of triboelectric nanogenerators (TENGs) for large-scale harvesting of kinetic water energy. Relying on surface charging effect between the conventional polymers and very thin layer of metal as electrodes for each TENG, the TENG networks (TENG-NW) that naturally float on the water surface convert the slow, random, and high-force oscillatory wave energy into electricity. On the basis of the measured output of a single TENG, the TENG-NW is expected to give an average power output of 1.15 MW from 1 km(2) surface area. Given the compelling features, such as being lightweight, extremely cost-effective, environmentally friendly, easily implemented, and capable of floating on the water surface, the TENG-NW renders an innovative and effective approach toward large-scale blue energy harvesting from the ocean.

  10. Water polygons in high-resolution protein crystal structures.

    PubMed

    Lee, Jonas; Kim, Sung-Hou

    2009-07-01

    We have analyzed the interstitial water (ISW) structures in 1500 protein crystal structures deposited in the Protein Data Bank that have greater than 1.5 A resolution with less than 90% sequence similarity with each other. We observed varieties of polygonal water structures composed of three to eight water molecules. These polygons may represent the time- and space-averaged structures of "stable" water oligomers present in liquid water, and their presence as well as relative population may be relevant in understanding physical properties of liquid water at a given temperature. On an average, 13% of ISWs are localized enough to be visible by X-ray diffraction. Of those, averages of 78% are water molecules in the first water layer on the protein surface. Of the localized ISWs beyond the first layer, almost half of them form water polygons such as trigons, tetragons, as well as expected pentagons, hexagons, higher polygons, partial dodecahedrons, and disordered networks. Most of the octagons and nanogons are formed by fusion of smaller polygons. The trigons are most commonly observed. We suggest that our observation provides an experimental basis for including these water polygon structures in correlating and predicting various water properties in liquid state.

  11. Water polygons in high-resolution protein crystal structures

    PubMed Central

    Lee, Jonas; Kim, Sung-Hou

    2009-01-01

    We have analyzed the interstitial water (ISW) structures in 1500 protein crystal structures deposited in the Protein Data Bank that have greater than 1.5 Å resolution with less than 90% sequence similarity with each other. We observed varieties of polygonal water structures composed of three to eight water molecules. These polygons may represent the time- and space-averaged structures of “stable” water oligomers present in liquid water, and their presence as well as relative population may be relevant in understanding physical properties of liquid water at a given temperature. On an average, 13% of ISWs are localized enough to be visible by X-ray diffraction. Of those, averages of 78% are water molecules in the first water layer on the protein surface. Of the localized ISWs beyond the first layer, almost half of them form water polygons such as trigons, tetragons, as well as expected pentagons, hexagons, higher polygons, partial dodecahedrons, and disordered networks. Most of the octagons and nanogons are formed by fusion of smaller polygons. The trigons are most commonly observed. We suggest that our observation provides an experimental basis for including these water polygon structures in correlating and predicting various water properties in liquid state. PMID:19551896

  12. A statistical examination of Nimbus 7 SMMR data and remote sensing of sea surface temperature, liquid water content in the atmosphere and surfaces wind speed

    NASA Technical Reports Server (NTRS)

    Prabhakara, C.; Wang, I.; Chang, A. T. C.; Gloersen, P.

    1982-01-01

    Nimbus 7 Scanning Multichannel Microwave Radiometer (SMMR) brightness temperature measurements over the global oceans have been examined with the help of statistical and empirical techniques. Such analyses show that zonal averages of brightness temperature measured by SMMR, over the oceans, on a large scale are primarily influenced by the water vapor in the atmosphere. Liquid water in the clouds and rain, which has a much smaller spatial and temporal scale, contributes substantially to the variability of the SMMR measurements within the latitudinal zones. The surface wind not only increases the surface emissivity but through its interactions with the atmosphere produces correlations, in the SMMR brightness temperature data, that have significant meteorological implications. It is found that a simple meteorological model can explain the general characteristics of the SMMR data. With the help of this model methods to infer over the global oceans, the surface temperature, liquid water content in the atmosphere, and surface wind speed are developed. Monthly mean estimates of the sea surface temperature and surface winds are compared with the ship measurements. Estimates of liquid water content in the atmosphere are consistent with earlier satellite measurements.

  13. Water resources of Kosrae, Caroline Islands

    USGS Publications Warehouse

    Van der Brug, Otto

    1984-01-01

    Kosrae is a high volcanic island about 42 square miles in area and the easternmost of the Caroline Islands. Mount Finkol (Mt. Crozer), at 2,065 feet, is the highest point on the island. Mountainous ridges descend sharply to narrow coastal strips which support a population of 5,500 people. Many streams, some quite large relative to the size of the island, drain radially from the interior. The average annual discharge of surface water amounts to almost 7 million gallons per square mile per day. Annual rainfall for coastal areas on Kosrae averages about 200 inches, and is similar to the rainfall for coastal areas on the island of Ponape, about 340 statute miles to the northwest. Rainfall in the interior was estimated at 225 inches per year of which about two thirds runs off as streamflow. Surface-water quality is very good as shown by 42 chemical analyses of water from 12 streams. This report summarizes in one volume the hydrologic data collected and provides interpretations that can be used by planning and public works officials as a basis for making decisions on the development and management of their water resources. (USGS)

  14. Stormwater Effects on Heavy Metal Sequestration in a Bioretention System in Culver City, California

    NASA Astrophysics Data System (ADS)

    Yousavich, D. J.; Ellis, A. S.; Dorsey, J.; Johnston, K.

    2017-12-01

    Rain Gardens, also referred to as bioretention or biofilters, are often used to capture or filter urban runoff before it drains into surface or groundwater systems. The Culver City Rain Garden (CCRG) is one such system that is designed to capture and filter runoff from approximately 11 acres of mixed-use commercial and industrial land before it enters Ballona Creek. The EPA has designated Ballona Creek as an impaired waterway and established Total Maximum Daily Loads for heavy metals. Previous research has utilized sequential extractions to establish trends in heavy metal sequestration for Cu, Pb, and Zn in bioretention media. The aim of this project is to evaluate if there is a difference in heavy metal sequestration between dry and wetted bioretention media. To characterize the stormwater at the site, influent and surface water were collected and analyzed for sulfate and heavy metals 3 times during the 2016-2017 storm season. Two soil cores from the CCRG were acquired in the summer of 2017 to analyze soil metal sequestration trends. They will be subjected to different wetting conditions, sectioned into discrete depths, and digested with an established sequential extraction technique. Surface water in the CCRG shows average Dissolved Oxygen during wet conditions of 2.92 mg/L and average pH of 6.1 indicating reducing conditions near the surface and the possible protonation of adsorption sites during wet weather conditions. Influent metal data indicate average dissolved iron levels near 1 ppm and influent Cu, Pb, and Zn levels near 0.05, 0.01, and 0.5 ppm respectively. This coupled with average surface water sulfate levels near 3 ppm indicates the potential for iron oxide and sulfide mineral formation depending on redox conditions. The sequential extraction results will elucidate whether heavy metals are adsorbed or are being sequestered in mineral formation. These results will allow for the inclusion of heavy metal sequestration trends in the design of further bioretention projects and maintenance of current sites.

  15. Estimated use of water in South Dakota, 2005

    USGS Publications Warehouse

    Carter, Janet M.; Neitzert, Kathleen M.

    2008-01-01

    During 2005, withdrawals from ground-water and surface-water sources in South Dakota for the eight categories of offstream use totaled about 500 million gallons per day (Mgal/d). Of total withdrawals, about 271 Mgal/d was withdrawn from ground water and about 230 Mgal/d was withdrawn from surface water. The largest use of water in South Dakota during 2005 was irrigation, which accounted for about 58 percent of the total water withdrawn, followed by public supply, which accounted for about 20 percent of withdrawals. Public-supply systems served about 666,210 people, or about 86 percent of South Dakota's population in 2005. Public-supply systems withdrew about 100 Mgal/d in 2005. Ground-water withdrawals accounted for about 66 percent of the total withdrawals (66 Mgal/d), and surface-water withdrawals accounted for about 34 percent of total withdrawals (35 Mgal/d). Total public-supply withdrawals averaged about 151 gallons per day (gal/d) per capita. About 65 percent of the public-supply water was used for domestic purposes, and the average per capita domestic use was 99 gal/d. Self-supplied domestic withdrawals were about 8 Mgal/d, all of which was from ground water. About 109,750 people obtained household water from private wells in 2005, and per capita use was about 70 gal/d. Industrial self-supplied water use during 2005 was about 4 Mgal/d, of which about 98 percent was from ground water and about 2 percent was from surface water. Total withdrawals for thermoelectric use were about 5 Mgal/d, of which about 1 Mgal/d was from ground water and about 4 Mgal/d was from surface water. Total mining water use was about 10 Mgal/d, of which about 5 Mgal/d came from ground water and about 6 Mgal/d came from surface water. Total livestock water use was about 48 Mgal/d, of which about 19 Mgal/d came from ground water and about 28 Mgal/d came from surface water. Total aquaculture use was about 33 Mgal/d, of which about 19 Mgal/d came from ground water and about 14 Mgal/d came from surface water. Irrigation withdrawals during 2005 totaled about 292 Mgal/d, of which about 149 Mgal/d was from ground-water sources and about 143 Mgal/d was from surface-water sources. An estimated 421,830 acres was irrigated during 2005. Of the total acres irrigated, 298,160 acres was irrigated by sprinkler application and 123,670 acres was irrigated by surface (or flood) application. The only instream use reported for South Dakota was for hydroelectric power generation. During 2005, about 68,400 Mgal/d was used by the hydroelectric powerplants to generate about 3,688 gigawatt-hours of electricity. Total water use in South Dakota decreased by about 25 percent (175 Mgal/d) between 1985 and 2005 despite an increase in the State's population of about 70,000 people. Total ground-water use increased slightly (about 21 Mgal/d) between 1985 and 2005, whereas surface-water use decreased by about 195 Mgal/d. The decreases in both total use and surface-water use are mostly attributable to decreases in irrigation water use. Total irrigation water use decreased by about 168 Mgal/d between 1985 and 2005, and surface-water irrigation use decreased by about 204 Mgal/d. Ground-water irrigation use increased by about 36 Mgal/d between 1985 and 2005. Water use for public supply increased about 20 Mgal/d between 1985 and 2005, and the population served by public suppliers increased by about 118,000 people. In contrast, the number of people relying on private wells for domestic use decreased by about 48,000 between 1985 and 2005. All self-supplied domestic water use in 2005 was supplied by ground water. Total domestic use decreased about 8 Mgal/d between 1985 and 2005.

  16. Chemical composition and reactivity of water on hexagonal Pt-group metal surfaces.

    PubMed

    Shavorskiy, A; Gladys, M J; Held, G

    2008-10-28

    The dissociation behaviour and valence-electronic structure of water adsorbed on clean and oxygen-covered Ru{0001}, Rh{111}, Pd{111}, Ir{111} and Pt{111} surfaces has been studied by high-resolution X-ray photoelectron spectroscopy with the aim of identifying similarities and trends within the Pt-group metals. On average, we find higher reactivity for the 4d metals (Ru, Rh, Pd) as compared to 5d (Ir, Pt), which is correlated with characteristic shifts in the 1b(1) and 3a(1) molecular orbitals of water. Small amounts of oxygen (< 0.2 ML) induce dissociation of water on all five surfaces, for higher coverages (> 0.25 ML) only intact water is observed. Under UHV conditions these higher coverages can only be reached on the 4d metals, the 5d metals are, therefore, not passivated.

  17. Comparison of a vertically-averaged and a vertically-resolved model for hyporheic flow beneath a pool-riffle bedform

    NASA Astrophysics Data System (ADS)

    Ibrahim, Ahmad; Steffler, Peter; She, Yuntong

    2018-02-01

    The interaction between surface water and groundwater through the hyporheic zone is recognized to be important as it impacts the water quantity and quality in both flow systems. Three-dimensional (3D) modeling is the most complete representation of a real-world hyporheic zone. However, 3D modeling requires extreme computational power and efforts; the sophistication is often significantly compromised by not being able to obtain the required input data accurately. Simplifications are therefore often needed. The objective of this study was to assess the accuracy of the vertically-averaged approximation compared to a more complete vertically-resolved model of the hyporheic zone. The groundwater flow was modeled by either a simple one-dimensional (1D) Dupuit approach or a two-dimensional (2D) horizontal/vertical model in boundary fitted coordinates, with the latter considered as a reference model. Both groundwater models were coupled with a 1D surface water model via the surface water depth. Applying the two models to an idealized pool-riffle sequence showed that the 1D Dupuit approximation gave comparable results in determining the characteristics of the hyporheic zone to the reference model when the stratum thickness is not very large compared to the surface water depth. Conditions under which the 1D model can provide reliable estimate of the seepage discharge, upwelling/downwelling discharges and locations, the hyporheic flow, and the residence time were determined.

  18. Availability of high-magnitude streamflow for groundwater banking in the Central Valley, California

    NASA Astrophysics Data System (ADS)

    Kocis, Tiffany N.; Dahlke, Helen E.

    2017-08-01

    California’s climate is characterized by the largest precipitation and streamflow variability observed within the conterminous US This, combined with chronic groundwater overdraft of 0.6-3.5 km3 yr-1, creates the need to identify additional surface water sources available for groundwater recharge using methods such as agricultural groundwater banking, aquifer storage and recovery, and spreading basins. High-magnitude streamflow, i.e. flow above the 90th percentile, that exceeds environmental flow requirements and current surface water allocations under California water rights, could be a viable source of surface water for groundwater banking. Here, we present a comprehensive analysis of the magnitude, frequency, duration and timing of high-magnitude streamflow (HMF) for 93 stream gauges covering the Sacramento, San Joaquin and Tulare basins in California. The results show that in an average year with HMF approximately 3.2 km3 of high-magnitude flow is exported from the entire Central Valley to the Sacramento-San Joaquin Delta often at times when environmental flow requirements of the Delta and major rivers are exceeded. High-magnitude flow occurs, on average, during 7 and 4.7 out of 10 years in the Sacramento River and the San Joaquin-Tulare Basins, respectively, from just a few storm events (5-7 1-day peak events) lasting for 25-30 days between November and April. The results suggest that there is sufficient unmanaged surface water physically available to mitigate long-term groundwater overdraft in the Central Valley.

  19. Tropical storm Irene flood of August 2011 in northwestern Massachusetts

    USGS Publications Warehouse

    Bent, Gardner C.; Olson, Scott A.; Massey, Andrew J.

    2016-09-02

    The simulated 1-percent AEP discharge water-surface elevations (nonregulatory) from recent (2015–16) hydraulic models for river reaches in the study area, which include the Deerfield, Green, and North Rivers in the Deerfield River Basin and the Hoosic River in the Hoosic River Basin, were compared with water-surface profiles in the FISs. The water-surface elevation comparisons were generally done downstream and upstream from bridges, dams, and major tributaries. The simulated 1-percent AEP discharge water-surface elevations of the recent hydraulic studies averaged 2.2, 2.3, 0.3, and 0.7 ft higher than water-surface elevations in the FISs for the Deerfield, Green, North, and Hoosic Rivers, respectively. The differences in water-surface elevations between the recent (2015–16) hydraulic studies and the FISs likely are because of (1) improved land elevation data from light detection and ranging (lidar) data collected in 2012, (2) detailed surveying of hydraulic structures and cross sections throughout the river reaches in 2012–13 (reflecting structure and cross section changes during the last 30–35 years), (3) updated hydrology analyses (30–35 water years of additional peak flow data at streamgages), and (4) high-water marks from the 2011 tropical storm Irene flood being used for model calibration.

  20. A study of Bangladesh's sub-surface water storages using satellite products and data assimilation scheme.

    PubMed

    Khaki, M; Forootan, E; Kuhn, M; Awange, J; Papa, F; Shum, C K

    2018-06-01

    Climate change can significantly influence terrestrial water changes around the world particularly in places that have been proven to be more vulnerable such as Bangladesh. In the past few decades, climate impacts, together with those of excessive human water use have changed the country's water availability structure. In this study, we use multi-mission remotely sensed measurements along with a hydrological model to separately analyze groundwater and soil moisture variations for the period 2003-2013, and their interactions with rainfall in Bangladesh. To improve the model's estimates of water storages, terrestrial water storage (TWS) data obtained from the Gravity Recovery And Climate Experiment (GRACE) satellite mission are assimilated into the World-Wide Water Resources Assessment (W3RA) model using the ensemble-based sequential technique of the Square Root Analysis (SQRA) filter. We investigate the capability of the data assimilation approach to use a non-regional hydrological model for a regional case study. Based on these estimates, we investigate relationships between the model derived sub-surface water storage changes and remotely sensed precipitations, as well as altimetry-derived river level variations in Bangladesh by applying the empirical mode decomposition (EMD) method. A larger correlation is found between river level heights and rainfalls (78% on average) in comparison to groundwater storage variations and rainfalls (57% on average). The results indicate a significant decline in groundwater storage (∼32% reduction) for Bangladesh between 2003 and 2013, which is equivalent to an average rate of 8.73 ± 2.45mm/year. Copyright © 2018 Elsevier B.V. All rights reserved.

  1. Potentiometric Surface of the Upper Floridan Aquifer, West-Central Florida, May 2006

    USGS Publications Warehouse

    Ortiz, A.G.

    2007-01-01

    Introduction Hydrologic Conditions in West-Central Florida The Floridan aquifer system consists of the Upper and Lower Floridan aquifers separated by the middle confining unit. The middle confining unit and the Lower Floridan aquifer in west-central Florida generally contain highly mineralized water. The water-bearing units containing fresh water are herein referred to as the Upper Floridan aquifer. The Upper Floridan aquifer is the principal source of water in the Southwest Florida Water Management District and is used for major public supply, domestic use, irrigation, and brackish water desalination in coastal communities (Southwest Florida Water Management District, 2000). This map report shows the potentiometric surface of the Upper Floridan aquifer measured in May 2006. The potentiometric surface is an imaginary surface connecting points of equal altitude to which water will rise in tightly-cased wells that tap a confined aquifer system (Lohman, 1979). This map represents water-level conditions near the end of the dry season, when ground-water levels usually are at an annual low and withdrawals for agricultural use typically are high. The cumulative average rainfall of 50.23 inches for west-central Florida (from June 2005 through May 2006) was 2.82 inches below the historical cumulative average of 53.05 inches (Southwest Florida Water Management District, 2006). Historical cumulative averages are calculated from regional rainfall summary reports (1915 to most recent complete calendar year) and are updated monthly by the Southwest Florida Water Management District. This report, prepared by the U.S. Geological Survey in cooperation with the Southwest Florida Water Management District, is part of a semi-annual series of Upper Floridan aquifer potentiometric-surface map reports for west-central Florida. Potentiometric-surface maps have been prepared for January 1964, May 1969, May 1971, May 1973, May 1974, and for each May and September since 1975. Water-level data are collected in May and September each year to show the approximate annual low and high water-level conditions, respectively. Most of the water-level data for this map were collected by the U.S. Geological Survey during the period May 15-19, 2006. Supplemental water-level data were collected by other agencies and companies. A corresponding potentiometric-surface map was prepared for areas east and north of the Southwest Florida Water Management District boundary by the U.S. Geological Survey office in Altamonte Springs, Florida (Kinnaman, 2006). Most water-level measurements were made during a 5-day period; therefore, measurements do not represent a 'snapshot' of conditions at a specific time, nor do they necessarily coincide with the seasonal low water-level condition. Water-Level Changes Water levels in about 95 percent of the wells measured in May 2006 were lower than the May 2005 water levels (Ortiz and Blanchard, 2006). May 2006 water levels in 403 wells ranged from about 26 feet below to about 6 feet above May 2005 water levels (fig. 1). Significant water level declines occurred in eastern Manatee County, southwestern Polk County, southeastern Hillsborough County, and in all of Hardee County. The largest water level declines occurred in southwestern Hardee County. The largest water level rises occurred in south-central Pasco County, northeastern Levy County, northwestern Marion County, and along the gulf coast from Pasco County to Citrus County (fig. 1). Water levels in about 96 percent of the wells measured in May 2006 were lower than the September 2005 water levels (Ortiz, 2006). May 2006 water levels in 397 wells ranged from about 31 feet below to 3 feet above the September 2005 water levels. The largest water level decline was in west-central Hardee County and the largest rise in water levels was in south-central Pasco County.

  2. Using Profiles of Water Vapor Flux to Characterize Turbulence in the Convective Boundary Layer

    NASA Astrophysics Data System (ADS)

    Weber, Kristy Jane

    The 2015 Plains Elevated Convection at Night (PECAN) field campaign sought to increase understanding of mechanisms for nocturnal severe weather in the Great Plains of the United States. A collection of instruments from this field campaign, including a water vapor Differential LiDAR (Light Detection Imaging And Ranging) (DIAL) and 449 MHz radar wind profiler were used to measure water vapor flux in regions between 300 m and the convective boundary layer. Methods to properly sample eddies using eddy-covariance were established, where analysis showed that a 90-minute Reynold's averaging period was optimal to sample most eddies. Additionally, a case study was used to demonstrate the additional atmospheric parameters which can be calculated from profiles of water vapor flux, such as the water vapor flux convergence/divergence. Flux footprints calculated at multiple heights within the convective boundary layer also show how a surface based instrument is sampling a completely different source than one taking measurements above 300 m. This result is important, as it shows how measurements above the surface layer will not be expected to match with those taken within a few meters of the surface, especially if average surface features such as land use type and roughness length are significantly different. These calculated water vapor flux profile measurements provide a new tool to analyze boundary layer dynamics during the PECAN field campaign, and their relationships to PECAN's study areas such as mesoscale convective systems (MCSs), nocturnal low-level jets (NLLJs), elevated convective initiation, and the propagation of bores or wavelike features from nocturnal convective systems.

  3. Biogeochemistry of Urban, Suburban and Rural Ponds and Lakes in South Central Texas, USA

    NASA Astrophysics Data System (ADS)

    Young, K. L.; Aitkenhead-Peterson, J. A.; Gentry, T. J.; Schwab, A. P.

    2017-12-01

    Urban lotic surface waters have been extensively studied due to reported increases in their alkalinization and dissolved organic carbon (DOC). The same cannot be said for urban lentic surface waters, which are subject to the same Environmental Protection Agency (EPA) standards for recreation and other classifications, yet have received much less attention. This study analyzed 24 urban, suburban, and rural lakes and ponds throughout the Bryan/College Station, TX area for E. coli (monthly), biogeochemistry, BOD5, and total suspended solids (twice monthly). Some of the lentic surface waterbodies are for recreational activities such as swimming, fishing, and boating, while others serve more simply as storm water retention ponds in neighborhoods that have been `beautified' by adding trails for walking recreation or as ponds on golf courses. According to the EPA, the geometric mean standards for surface water E. coli are: 1) Primary Contact Recreation: 126 MPN per 100 mL of water, 2) Secondary Contact Recreation I: 630 MPN per 100 mL, and 3) Secondary Contact Recreation II: 1030 MPN per 100 mL. E. coli concentrations of the 24 lentic lakes and ponds during the spring season averaged 1-1417 MPN per 100 mL, with 7 of the 24 lentic waterbodies exceeding Secondary Contact Recreation I and 1 exceeding Secondary Contact Recreation II standards. There were also several individual samples exceeding the Noncontact Recreation Standard of 2060 MPN per 100 mL. Spring season DOC and DON concentrations averaged 7.3 - 21.9 mg L-1 and 0.48-15.62 mg L-1, respectively, with average specific ultraviolet absorbance at 254 nm (SUVA254) values ranging from 3.4 - 7.7 L mg-1 m-1. Nutrients NO3-N, NH4-N, and PO4-P ranged from 0.01-16.28, 0.01-0.41, and 0.02-5.05 mg L-1, respectively. pH in these surface waterbodies averaged 8.0-10.2 and electrical conductivity values ranged from 147-1677 µS cm-1 in the spring, indicating a tendency towards sodicity rather than salinity. BOD5 ranged from 1.6 - 22.6 mg L-1 and TSS from 6 - 404 mg L-1 Metals in the waterbodies' sediment that is potentially derived from urban runoff will be later quantified, but this presentation will concentrate primarily on the biogeochemistry of these urban lentic water bodies during the spring, summer and fall seasons.

  4. Time series study of weather, water quality, and acute gastroenteritis at Water Safety Plan implementation sites in France and Spain

    PubMed Central

    Setty, Karen E.; Enault, Jerome; Loret, Jean-Francois; Serra, Claudia Puigdomenech; Martin-Alonso, Jordi; Bartram, Jamie

    2018-01-01

    Water Safety Plans (WSPs), recommended by the World Health Organization since 2004, can help drinking water suppliers to proactively identify potential risks and implement preventive barriers that improve safety. Few studies have investigated long-term impacts of WSPs, such as changes in drinking water quality or public health; however, some evidence from high-income countries associates WSP implementation with a reduction in diarrheal disease. To validate the previously observed linkages between WSPs and health outcomes, this time series study examined site-specific relationships between water-related exposures and acute gastroenteritis rates at three locations in France and Spain, including the role of WSP status. Relationships between control or exposure variables and health outcomes were tested using Poisson regression within generalized additive models. Controls included suspected temporal trends in disease reporting. Exposures included temperature, precipitation, raw water quality, and finished water quality (e.g., turbidity, free chlorine). In France, daily acute gastroenteritis cases were tracked using prescription reimbursements; Spanish data aggregated monthly acute gastroenteritis hospital visits. The models identified several significant relationships between indicators of exposure and acute gastroenteritis. Lag times of 6–9 days (including transit time) were most relevant for hydrological indicators (related to precipitation, runoff, and flow) at the two French sites, indicative of viral pathogens. Flush events (defined as surface runoff after a two-week antecedent dry period) linked to nonpoint source pollution were associated with a 10% increase in acute gastroenteritis rates at one location supplied by surface water. Acute gastroenteritis rates were positively associated with elevated turbidity average or maximum values in finished water at locations supplied by both surface and groundwater, by about 4% per 1-NTU increase in the two-week moving average of daily maxima or about 10% per 0.1 NTU increase in the prior month’s average value. In some cases, risk appeared to be mitigated by WSP-related treatment interventions. Our results suggest drinking water exposure is associated with some potentially preventable gastrointestinal illness risk in high-income regions. PMID:29678324

  5. Ground-Water Occurrence and Contribution to Streamflow, Northeast Maui, Hawaii

    USGS Publications Warehouse

    Gingerich, Stephen B.

    1999-01-01

    The study area lies on the northern flank of the East Maui Volcano (Haleakala) and covers about 129 square miles between the drainage basins of Maliko Gulch to the west and Makapipi Stream to the east. About 989 million gallons per day of rainfall and 176 million gallons per day of fog drip reaches the study area and about 529 million gallons per day enters the ground-water system as recharge. Average annual ground-water withdrawal from wells totals only about 3 million gallons per day; proposed (as of 1998) additional withdrawals total about 18 million gallons per day. Additionally, tunnels and ditches of an extensive irrigation network directly intercept at least 10 million gallons per day of ground water. The total amount of average annual streamflow in gaged stream subbasins upstream of 1,300 feet altitude is about 255 million gallons per day and the total amount of average annual base flow is about 62 million gallons per day. Six major surface-water diversion systems in the study area have diverted an average of 163 million gallons per day of streamflow (including nearly all base flow of diverted streams) for irrigation and domestic supply in central Maui during 1925-97. Fresh ground water is found in two main forms. West of Keanae Valley, ground-water flow appears to be dominated by a variably saturated system. A saturated zone in the uppermost rock unit, the Kula Volcanics, is separated from a freshwater lens near sea level by an unsaturated zone in the underlying Honomanu Basalt. East of Keanae Valley, the ground-water system appears to be fully saturated above sea level to altitudes greater than 2,000 feet. The total average annual streamflow of gaged streams west of Keanae Valley is about 140 million gallons per day at 1,200 feet to 1,300 feet altitude. It is not possible to estimate the total average annual streamflow at the coast. All of the base flow measured in the study area west of Keanae Valley represents ground-water discharge from the high-elevation saturated zone. Total average daily ground-water discharge from the high-elevation saturated zone upstream of 1,200 feet altitude is greater than 38 million gallons per day, all of which is eventually removed from the streams by surface-water diversion systems. Perennial streamflow has been measured at altitudes greater than 3,000 feet in several of the streams. Discharge from the high-elevation saturated zone is persistent even during periods of little rainfall. The total average annual streamflow of the gaged streams east of Keanae Valley is about 109 million gallons per day at about 1,300 feet altitude. It is not possible to estimate the total average annual streamflow at the coast nor at higher altitudes. All of the base flow measured east of Keanae Valley represents ground-water discharge from the vertically extensive freshwater-lens system. Total average daily ground-water discharge to gaged streams upstream of 1,200 feet altitude is about 27 million gallons per day. About 19 million gallons per day of ground water discharges through the Kula and Hana Volcanics between about 500 feet and 1,300 feet altitude in the gaged stream sub-basins. About 13 million gallons per day of this discharge is in Hanawi Stream. The total ground-water discharge above 500 feet altitude in this part of the study area is greater than 56 million gallons per day.

  6. Rapid fluctuations in flow and water-column properties in Asan Bay, Guam: implications for selective resilience of coral reefs in warming seas

    USGS Publications Warehouse

    Storlazzi, Curt D.; Field, Michael E.; Cheriton, Olivia M.; Presto, M.K.; Logan, J.B.

    2013-01-01

    Hydrodynamics and water-column properties were investigated off west-central Guam from July 2007 through January 2008. Rapid fluctuations, on time scales of 10s of min, in currents, temperature, salinity, and acoustic backscatter were observed to occur on sub-diurnal frequencies along more than 2 km of the fore reef but not at the reef crest. During periods characterized by higher sea-surface temperatures (SSTs), weaker wind forcing, smaller ocean surface waves, and greater thermal stratification, rapid decreases in temperature and concurrent rapid increases in salinity and acoustic backscatter coincided with onshore-directed near-bed currents and offshore-directed near-surface currents. During the study, these cool-water events, on average, lasted 2.3 h and decreased the water temperature 0.57 °C, increased the salinity 0.25 PSU, and were two orders of magnitude more prevalent during the summer season than the winter. During the summer season when the average satellite-derived SST anomaly was +0.63 °C, these cooling events, on average, lowered the temperature 1.14 °C along the fore reef but only 0.11 °C along the reef crest. The rapid shifts appear to be the result of internal tidal bores pumping cooler, more saline, higher-backscatter oceanic water from depths >50 m over cross-shore distances of 100 s of m into the warmer, less saline waters at depths of 20 m and shallower. Such internal bores appear to have the potential to buffer shallow coral reefs from predicted increases in SSTs by bringing cool, offshore water to shallow coral environments. These cooling internal bores may also provide additional benefits to offset stress such as supplying food to thermally stressed corals, reducing stress due to ultraviolet radiation and/or low salinity, and delivering coral larvae from deeper reefs not impacted by surface thermal stress. Thus, the presence of internal bores might be an important factor locally in the resilience of select coral reefs facing increased thermal stress.

  7. Rapid fluctuations in flow and water-column properties in Asan Bay, Guam: implications for selective resilience of coral reefs in warming seas

    NASA Astrophysics Data System (ADS)

    Storlazzi, C. D.; Field, M. E.; Cheriton, O. M.; Presto, M. K.; Logan, J. B.

    2013-12-01

    Hydrodynamics and water-column properties were investigated off west-central Guam from July 2007 through January 2008. Rapid fluctuations, on time scales of 10s of min, in currents, temperature, salinity, and acoustic backscatter were observed to occur on sub-diurnal frequencies along more than 2 km of the fore reef but not at the reef crest. During periods characterized by higher sea-surface temperatures (SSTs), weaker wind forcing, smaller ocean surface waves, and greater thermal stratification, rapid decreases in temperature and concurrent rapid increases in salinity and acoustic backscatter coincided with onshore-directed near-bed currents and offshore-directed near-surface currents. During the study, these cool-water events, on average, lasted 2.3 h and decreased the water temperature 0.57 °C, increased the salinity 0.25 PSU, and were two orders of magnitude more prevalent during the summer season than the winter. During the summer season when the average satellite-derived SST anomaly was +0.63 °C, these cooling events, on average, lowered the temperature 1.14 °C along the fore reef but only 0.11 °C along the reef crest. The rapid shifts appear to be the result of internal tidal bores pumping cooler, more saline, higher-backscatter oceanic water from depths >50 m over cross-shore distances of 100 s of m into the warmer, less saline waters at depths of 20 m and shallower. Such internal bores appear to have the potential to buffer shallow coral reefs from predicted increases in SSTs by bringing cool, offshore water to shallow coral environments. These cooling internal bores may also provide additional benefits to offset stress such as supplying food to thermally stressed corals, reducing stress due to ultraviolet radiation and/or low salinity, and delivering coral larvae from deeper reefs not impacted by surface thermal stress. Thus, the presence of internal bores might be an important factor locally in the resilience of select coral reefs facing increased thermal stress.

  8. Occurrence, distribution and risks of antibiotics in urban surface water in Beijing, China.

    PubMed

    Li, Wenhui; Gao, Lihong; Shi, Yali; Liu, Jiemin; Cai, Yaqi

    2015-09-01

    The occurrence and distribution of 22 antibiotics, including eight fluoroquinolones, nine sulfonamides and five macrolides, were investigated in the urban surface waters in Beijing, China. A total of 360 surface water samples were collected from the main rivers and lakes in the urban area of Beijing monthly from July 2013 to June 2014 (except the frozen period). Laboratory analyses revealed that antibiotics were widely used and extensively distributed in the surface water of Beijing, and sulfonamides and fluoroquinolones were the predominant antibiotics with the average concentrations of 136 and 132 ng L(-1), respectively. A significant difference of antibiotic concentrations from different sampling sites was observed, and the southern and eastern regions of Beijing showed higher concentrations of antibiotics. Seasonal variation of the antibiotics in the urban surface water was also studied, and the highest level of antibiotics was found in November, which may be due to the low temperature and flow of the rivers during the period of cold weather. Risk assessment showed that several antibiotics might pose high ecological risks to aquatic organisms (algae and plants) in surface water, and more attention should be paid to the risk of antibiotics to the aquatic environment in Beijing.

  9. Ground water resources of southeastern Oakland County, Michigan

    USGS Publications Warehouse

    Ferris, J.G.; Burt, E.M.; Stramel, G.J.; Crosthwaite, E.G.

    1954-01-01

    The area covered by this report comprises a square which measures three townships on a side and enclose 318 square miles in southeastern Oakland County. The investigation of the ground-water resources of this area was made by the U.S. Geological Survey in cooperation with the Detroit Metropolitan Area Regional Planning Commission, the Michigan Department of Conservation, and the Michigan Water Resources Commission.In 1950 the population of this nine-township area exceeded 341,000, or more than 86 percent of the total population of Oakland County. This county ranks third in the state in number of industrial establishments and workers and is fifteenth in agricultural importance. Its numerous lakes and rolling uplands contribute to its top rank in the state in the number of recreational enterprises in rural or suburban areas.The climate is moderately humid. The average annual precipitation is 30 inches and the mean air temperature is 47.2° F. Snowfall averages 38 inches in the November-April interval. The growing season averages 151 days.The regional land surface slopes from northwest to southeast and has a total relief of 360 feet. Pitted outwash plains and morainal hills that are more than 1,000 feet above sea level in the northwest corner of the area give way southeastward to a sequence of terminal moraines and intervening till plains in the middle part. These give way to the broad lake plains that cover the southeastern third of the area.The area lies on the southeast edge of the Michigan Basin and the bedrock is composed of northwest dipping strata of the Devonian and Mississippian systems. The Antrim shale, of Lake Devonian and early Mississippian age, is the oldest formation cropping out beneath the mantle of glacial Berea sandstone, and Sunbury shale overlie the Antrim and are overlain by the Coldwater shale, their areas of outcrop beneath the drift lying successively farther northwest. These formations are of early Mississippian age.Throughout the area the bedrock is covered by glacial drift which ranges in thickness from 25 to more than 350 feet. The drift increases in thickness from southeast to northwest, but considerable relief on the underlying bedrock surface greatly modifies this trend. Extensive moraines, till plains, lake plains, and gravel outwash plains cover the area. In the northwestern third of the area an extensive upland of gravel plains is dotted with lakes ranging from a few feet to more than 100 feet in depth.Precipitation is the perennial source of all water in this area, whether on the surface of underground. The average annual rainfall on the nine-townships is equivalent to a continuous supply of 450 m.g.d. or  9 times the combined annual withdrawal from all wells in the area.About 53 percent of the area is drained by the Clinton River, 44 percent by the River Rouge, and the remaining 3 percent by the Huron River. Less than one-third of the annual precipitation reappears as surface discharge from the watersheds of this area.About two-thirds of the annual precipitation on the area is lost by evaporation from water and land surfaces and by transpirations from vegetative cover. A substantial part of this large annual water loss is from the many lakes and other exposed water surfaces and from contiguous lands where the depth to the water table is slight. Average annual water losses by evapotranspiration are equivalent to about 280 m.g.d. or nearly 6 times the combined withdrawal from all ground-water supplies in the area.The principal aquifers are the alluvial deposits bordering streams and the buried outwash deposits which represent alluvial fills in preglacial or interglacial stream channels. Intensive well developments in the urban areas have greatly lowered ground-water levels in the buried outwash deposits, have brought localized problems of declining well yield, and have induced migration of mineralized waters from the underlying consolidated formations. During 1952, withdrawals of ground water in the nine township area averages about 50 m.g.d., most of this quantity being pumped from municipal wells. This annual pumpage was distributed as follows: 60 percent in Pontiac and environs; 20 percent in Birmingham, Royal Oak and Troy Township; and the remaining 20 percent throughout the suburban and rural areas.

  10. Remote measurement of surface-water velocity using infrared videography and PIV: a proof-of-concept for Alaskan rivers

    USGS Publications Warehouse

    Kinzel, Paul J.; Legleiter, Carl; Nelson, Jonathan M.; Conaway, Jeffrey S.

    2017-01-01

    Thermal cameras with high sensitivity to medium and long wavelengths can resolve features at the surface of flowing water arising from turbulent mixing. Images acquired by these cameras can be processed with particle image velocimetry (PIV) to compute surface velocities based on the displacement of thermal features as they advect with the flow. We conducted a series of field measurements to test this methodology for remote sensing of surface velocities in rivers. We positioned an infrared video camera at multiple stations across bridges that spanned five rivers in Alaska. Simultaneous non-contact measurements of surface velocity were collected with a radar gun. In situ velocity profiles were collected with Acoustic Doppler Current Profilers (ADCP). Infrared image time series were collected at a frequency of 10Hz for a one-minute duration at a number of stations spaced across each bridge. Commercial PIV software used a cross-correlation algorithm to calculate pixel displacements between successive frames, which were then scaled to produce surface velocities. A blanking distance below the ADCP prevents a direct measurement of the surface velocity. However, we estimated surface velocity from the ADCP measurements using a program that normalizes each ADCP transect and combines those normalized transects to compute a mean measurement profile. The program can fit a power law to the profile and in so doing provides a velocity index, the ratio between the depth-averaged and surface velocity. For the rivers in this study, the velocity index ranged from 0.82 – 0.92. Average radar and extrapolated ADCP surface velocities were in good agreement with average infrared PIV calculations.

  11. Occurrence of acidic pharmaceuticals and personal care products in Turia River Basin: from waste to drinking water.

    PubMed

    Carmona, Eric; Andreu, Vicente; Picó, Yolanda

    2014-06-15

    The occurrence of 21 acidic pharmaceuticals, including illicit drugs, and personal care products (PPCPs) in waste, surface and drinking water and in sediments of the Turia River Basin (Valencia, Spain) was studied. A liquid chromatography tandem mass spectrometry (LC-MS/MS) method was developed for the determination of these PPCPs with electrospray (ESI) in negative ionization (NI) mode. Ammonium fluoride in the mobile phase improved ionization efficiency by an average increase in peak area of 5 compared to ammonium formate or formic acid. All studied compounds were detected and their concentration was waste water>surface water>drinking water. PPCPs were in waste water treatment plants (WWTPs) influents up to 7.26μgL(-1), dominated by ibuprofen, naproxen and 11-nor-9-carboxy-Δ9-tetrahydrocannabinol (THCOOH). WWTPs were highly effective in removing most of them, with an average removal rate of >90%. PPCPs were still detected in effluents in the 6.72-940ngL(-1) range, with the THCOOH, triclocarban, gemfibrozil and diclofenac as most prevalent. Similarly, diclofenac, gemfibrozil, ibuprofen, naproxen and propylparaben were detected quite frequently from the low ngL(-1) range to 7μgL(-1) in the surface waters of Turia River. Ibuprofen, methylparaben, salicylic acid and tetrahydrocannabinol (THC) were at concentrations up to 0.85ngg(-1) d.w. in sediments. The discharge of WWTP as well as of non-treated waters to this river is a likely explanation for the significant amount of PPCPs detected in surface waters and sediments. Mineral and tap waters also presented significant amounts (approx. 100ngL(-1)) of ibuprofen, naproxen, propylparaben and butylparaben. The occurrence at trace levels of several PPCPs in drinking water raises concerns about possible implications for human health. Copyright © 2014 Elsevier B.V. All rights reserved.

  12. Ground water in the carbonate rocks of the Franklin area, Tennessee

    USGS Publications Warehouse

    Zurawski, Ann; Burchett, C.R.

    1980-01-01

    A study of ground water in the Franklin area, Tennessee, was undertaken to fill a growing need for information on ground-water occurrence in the carbonate rocks of central Tennessee. Fifteen drilling sites were selected that had one or more of the following characteristics: medium- to thick-bedded limestones within 200 feet of land surface, structural lows, significant streamflow gains and losses, elongated sinkholes, straight stream reaches, linear features or other surface indications of solution cavities at depth. The 15 test wells produced from less than 1 to about 600 gallons per minute and had an average yield of 68 gallons per minute, measured while pumping the wells with compressed air. The average driller-reported yield for the area is five gallons per minute. Specific capacities for the four highest yielding wells ranged from 0.6 to 357 gallons per minute per foot of drawdown after 8 hours of pumping at rates ranging from 70 to 225 gallons per minute. Additional drilling at two sites revealed extensive solution openings. At one site, drawdown in five observation wells did not exceed 8.5 feet during 48 hours of pumping at an average rate of 502 gallons per minute. Raw water in the test wells meets most drinking-water standards and is of rather uniform quality from well to well and throughout the year. (USGS)

  13. Impact-Induced Climate Change on Titan

    NASA Technical Reports Server (NTRS)

    Zahnle, Kevin; Korycansky, Donald

    2012-01-01

    Titan's thick atmosphere and volatile surface cause it to respond to big impacts like the one that produced the prominent Menrva impact basin in a somewhat Earth-like manner. Menrva was big enough to raise the surface temperature by 100 K. If methane in the regolith is generally as abundant as it was at the Huygens landing site, Menrva would have been big enough to double the amount of methane in the atmosphere. The extra methane would have drizzled out of the atmosphere over hundreds of years. Conditions may have been favorable for clathrating volatiles such as ethane. Impacts can also create local crater lakes set in warm ice but these quickly sink below the warm ice; whether the cryptic waters quickly freeze by mixing with the ice crust or whether they long endure under the ice remains a open question. Bigger impacts can create shallow liquid water oceans at the surface. If Titan's crust is made of water ice, the putative Hotei impact (a possible 800-1200 km diameter basin, Soderblom et al 2009) would have raised the average surface temperature to 350-400 K. Water rain would have fallen and global meltwaters would have averaged 50 m to as much as 500 m deep. The meltwaters may not have lasted more than a few decades or centuries at most, but are interesting to consider given Titan's organic wealth.

  14. Ecological optimality in water-limited natural soil-vegetation systems. II - Tests and applications

    NASA Technical Reports Server (NTRS)

    Eagleson, P. S.; Tellers, T. E.

    1982-01-01

    The long-term optimal climatic climax soil-vegetation system is defined for several climates according to previous hypotheses in terms of two free parameters, effective porosity and plant water use coefficient. The free parameters are chosen by matching the predicted and observed average annual water yield. The resulting climax soil and vegetation properties are tested by comparison with independent observations of canopy density and average annual surface runoff. The climax properties are shown also to satisfy a previous hypothesis for short-term optimization of canopy density and water use coefficient. Using these hypotheses, a relationship between average evapotranspiration and optimum vegetation canopy density is derived and is compared with additional field observations. An algorithm is suggested by which the climax soil and vegetation properties can be calculated given only the climate parameters and the soil effective porosity. Sensitivity of the climax properties to the effective porosity is explored.

  15. Summary of the Georgia Agricultural Water Conservation and Metering Program and evaluation of methods used to collect and analyze irrigation data in the middle and lower Chattahoochee and Flint River basins, 2004-2010

    USGS Publications Warehouse

    Torak, Lynn J.; Painter, Jaime A.

    2011-01-01

    Since receiving jurisdiction from the State Legislature in June 2003 to implement the Georgia Agricultural Water Conservation and Metering Program, the Georgia Soil and Water Conservation Commission (Commission) by year-end 2010 installed more than 10,000 annually read water meters and nearly 200 daily reporting, satellite-transmitted, telemetry sites on irrigation systems located primarily in southern Georgia. More than 3,000 annually reported meters and 50 telemetry sites were installed during 2010 alone. The Commission monitored rates and volumes of agricultural irrigation supplied by groundwater, surface-water, and well-to-pond sources to inform water managers on the patterns and amounts of such water use and to determine effective and efficient resource utilization. Summary analyses of 4 complete years of irrigation data collected from annually read water meters in the middle and lower Chattahoochee and Flint River basins during 2007-2010 indicated that groundwater-supplied fields received slightly more irrigation depth per acre than surface-water-supplied fields. Year 2007 yielded the largest disparity between irrigation depth supplied by groundwater and surface-water sources as farmers responded to severe-to-exceptional drought conditions with increased irrigation. Groundwater sources (wells and well-to-pond systems) outnumbered surface-water sources by a factor of five; each groundwater source applied a third more irrigation volume than surface water; and, total irrigation volume from groundwater exceeded that of surface water by a factor of 6.7. Metered irrigation volume indicated a pattern of low-to-high water use from northwest to southeast that could point to relations between agricultural water use, water-resource potential and availability, soil type, and crop patterns. Normalizing metered irrigation-volume data by factoring out irrigated acres allowed irrigation water use to be expressed as an irrigation depth and nearly eliminated the disparity between volumes of applied irrigation derived from groundwater and surface water. Analysis of per-acre irrigation depths provided a commonality for comparing irrigation practices across the entire range of field sizes in southern Georgia and indicated underreporting of irrigated acres for some systems. Well-to-pond systems supplied irrigation at depths similar to groundwater and can be combined with groundwater irrigation data for subsequent analyses. Average irrigation depths during 2010 indicated an increase from average irrigation depths during 2008 and 2009, most likely the result of relatively dry conditions during 2010 compared to conditions in 2008 and 2009. Geostatistical models facilitated estimation of irrigation water use for unmetered systems and demonstrated usefulness in redesigning the telemetry network. Geospatial analysis evaluated the ability of the telemetry network to represent annually reported water-meter data and presented an objective, unbiased method for revising the network.

  16. Water-level fluctuation in wetlands as a function of landscape condition in the prairie pothole region

    USGS Publications Warehouse

    Euliss, Ned H.; Mushet, David M.

    1996-01-01

    We evaluated water-level fluctuation (maximum water depth - minimum water depth/catchment size) in 12 temporary, 12 seasonal, and 12 semipermanent wetlands equally distributed among landscapes dominated by tilled agricultural lands and landscapes dominated by grassland. Water levels fluctuated an average of 14.14 cm in wetlands within tilled agricultural landscapes, while water levels in wetlands within grassland landscapes fluctuated an average of only 4.27 cm. Tillage reduces the natural capacity of catch meets to mitigate surface flow into wetland basins during precipitation events, resulting in greater water-level fluctuations in wetlands with tilled catchments. In addition, water levels in temporary and seasonal wetlands fluctuated an average of 13.74 cm and 11.82 cm, respectively, while water levels in semipermanent wetlands fluctuated only 2.77 cm. Semipermanent wetlands receive a larger proportion of their water as input from ground water than do either temporary or seasonal wetlands. This input of water from the ground has a stabilizing effect on water-levels of semipermanent wetlands. Increases in water-level fluctuation due to tillage or due to alteration of ground-water hydrology may ultimately affect the composition of a wetland's flora and fauna. In this paper, we also describe an inexpensive device for determining absolute maximum and minimum water levels in wetlands.

  17. Influence of the Aral Sea negative water balance on its seasonal circulation and ventilation patterns: use of a 3d hydrodynamic model.

    NASA Astrophysics Data System (ADS)

    Sirjacobs, D.; Grégoire, M.; Delhez, E.; Nihoul, J.

    2003-04-01

    Within the context of the EU INCO-COPERNICUS program "Desertification in the Aral Sea Region: A study of the Natural and Anthropogenic Impacts" (Contract IAC2-CT-2000-10023), a large-scale 3D hydrodynamic model was adapted to address specifically the macroscale processes affecting the Aral Sea water circulation and ventilation. The particular goal of this research is to simulate the effect of lasting negative water balance on the 3D seasonal circulation, temperature, salinity and water-mixing fields of the Aral Sea. The original Aral Sea seasonal hydrodynamism is simulated with the average seasonal forcings corresponding to the period from 1956 to 1960. This first investigation concerns a period of relative stability of the water balance, before the beginning of the drying process. The consequences of the drying process on the hydrodynamic of the Sea will be studied by comparing this first results with the simulation representing the average situation for the years 1981 to 1985, a very low river flow period. For both simulation periods, the forcing considered are the seasonal fluctuations of wind fields, precipitation, evaporation, river discharge and salinity, cloud cover, air temperature and humidity. The meteorological forcings were adapted to the common optimum one-month temporal resolution of the available data sets. Monthly mean kinetic energy flux and surface tensions were calculated from daily ECMWF wind data. Monthly in situ precipitation, surface air temperature and humidity fields were interpolated from data obtained from the Russian Hydrological and Meteorological Institute. Monthly water discharge and average salinity of the river water were considered for both Amu Darya and Syr Darya river over each simulation periods. The water mass conservation routines allowed the simulation of a changing coastline by taking into account local drying and flooding events of particular grid points. Preliminary barotropic runs were realised (for the 1951-1960 situation, before drying up began) in order to get a first experience of the behaviour of the hydrodynamic model. These first runs provide results about the evolution of the following state variables: elevation of the sea surface, 3D fields of vertical and horizontal flows, 2D fields of average horizontal flows and finally the 3D fields of turbulent kinetic energy. The mean seasonal salinity and temperature fields (in-situ data gathered by the Russian Hydrological and Meteorological Institute) are available for the two simulated periods and will allow a first validation of the hydrodynamic model. Various satellites products were identified, collected and processed in the frame of this research project and will be used for the validation of the model outputs. Seasonal level changes measurements derived from water table change will serve for water balance validation and sea surface temperature for hydrodynamics validation.

  18. An investigation of the heat induced during ultrasonic post removal.

    PubMed

    Ettrich, Christopher A; Labossière, Paul E; Pitts, David L; Johnson, James D

    2007-10-01

    The purpose of this study was to investigate the potential for temperature increase along the external root surface during ultrasonic post removal in a simulated clinical environment. Thirty-seven extracted teeth were decoronated, instrumented, and then obturated with gutta-percha and sealer. Post spaces were prepared, followed by cementation of stainless steel posts. A simulated clinical environment was created by using a polymethylmethacrylate sheet with holes custom fitted for the extracted teeth and then suspended over a heated water bath. Two thermocouples were attached at 6 and 12 mm from the top of the post along the external root surface. Teeth were divided into 3 test groups, no coolant, air-cooled, and water-cooled. Temperature changes were recorded by using a Vishay 5000 Strain Smart system. Results demonstrated that a significant difference existed in the average heat rates between the upper and lower thermocouples for no coolant and water-cooled groups at the medium setting and the air-cooled group at the high setting. The average heat rates were significantly different between the 2 thermocouples for all 3 groups when comparing the 2 ultrasonic power settings. Results indicated that the average heat rate was less for the water-cooled group when using a medium power setting.

  19. Energy balance studies and plasma catecholamine values for patients with healed burns.

    PubMed

    Wallace, B H; Cone, J B; Caldwell, F T

    1991-01-01

    We report heat balance studies and plasma catecholamine values for 49 children and young adults with healed burn wounds (age range 0.6 to 31 years and burn range 1% to 82% body surface area burned; mean 41%). All measurements were made during the week of discharge. Heat production for patients with healed burns was not significantly different from predicted normal values. However, compartmented heat loss demonstrated a persistent increment in evaporative heat loss that was secondary to continued elevation of cutaneous water vapor loss immediately after wound closure. A reciprocal decrement in dry heat loss was demonstrated (as a result of a cooler average surface temperature, 0.84 degree C cooler than the average integrated skin temperature of five normal volunteers who were studied in our unit under similar environmental conditions). Mean values for plasma catecholamines were in the normal range: epinephrine = 56 +/- 37 pg/ml, norepinephrine = 385 +/- 220 pg/ml, and dopamine = 34 +/- 29 pg/ml. In conclusion, patients with freshly healed burn wounds have normal rates of heat production; however, there is a residual increment in transcutaneous water vapor loss, which produces surface cooling and decreased average surface temperature, which in turn lowers dry heat loss by an approximately equivalent amount.

  20. Concentration of arsenic in water, sediments and fish species from naturally contaminated rivers.

    PubMed

    Rosso, Juan José; Schenone, Nahuel F; Pérez Carrera, Alejo; Fernández Cirelli, Alicia

    2013-04-01

    Arsenic (As) may occur in surface freshwater ecosystems as a consequence of both natural contamination and anthropogenic activities. In this paper, As concentrations in muscle samples of 10 fish species, sediments and surface water from three naturally contaminated rivers in a central region of Argentina are reported. The study area is one of the largest regions in the world with high As concentrations in groundwater. However, information of As in freshwater ecosystems and associated biota is scarce. An extensive spatial variability of As concentrations in water and sediments of sampled ecosystems was observed. Geochemical indices indicated that sediments ranged from mostly unpolluted to strongly polluted. The concentration of As in sediments averaged 6.58 μg/g ranging from 0.23 to 59.53 μg/g. Arsenic in sediments barely followed (r = 0.361; p = 0.118) the level of contamination of water. All rivers showed high concentrations of As in surface waters, ranging from 55 to 195 μg/L. The average concentration of As in fish was 1.76 μg/g. The level of contamination with As differed significantly between species. Moreover, the level of bioaccumulation of As in fish species related to the concentration of As in water and sediments also differed between species. Whilst some fish species seemed to be able to regulate the uptake of this metalloid, the concentration of As in the large catfish Rhamdia quelen mostly followed the concentration of As in abiotic compartments. The erratic pattern of As concentrations in fish and sediments regardless of the invariable high levels in surface waters suggests the existence of complex biogeochemical processes behind the distribution patterns of As in these naturally contaminated ecosystems.

  1. Seasonal and temporal CO2 dynamics in three tropical mangrove creeks - A revision of global mangrove CO2 emissions

    NASA Astrophysics Data System (ADS)

    Rosentreter, Judith A.; Maher, D. T.; Erler, D. V.; Murray, R.; Eyre, B. D.

    2018-02-01

    Continuous high-resolution surface water pCO2 and δ13C-CO2 and 222Rn (dry season only) were measured over two tidal cycles in the wet and dry season in three tropical tidal mangrove creeks on the north-eastern coast of Queensland, Australia. Mangrove surface water pCO2 followed a clear tidal pattern (ranging from 387 to 13,031 μatm) with higher pCO2-values in the wet season than in the dry season. The δ13C-CO2 in the mangrove waters ranged from -21.7 to -8.8‰ and was rather indicative of a mixed source than a distinct mangrove signature. Surface water CO2 was likely driven by a combination of mangrove and external carbon sources, e.g. exchange with groundwater/pore water enriched in 13C, or terrestrial carbon inputs with a significant contribution of C4-vegetation (sugar cane) source. The kinetic and equilibrium fractionation during the gas exchange at the water-atmosphere interface may have further caused a 13C-enrichment of the CO2 pool in the mangrove surface waters. Average CO2 evasion rates (58.7-277.6 mmol m-2 d-1) were calculated using different empirical gas transfer velocity models. Using our high-resolution time series data and previously published data, the average CO2 flux rate in mangrove ecosystems was estimated to be 56.5 ± 8.9 mmol m-2 d-1, which corresponds to a revised global mangrove CO2 emission of 34.1 ± 5.4 Tg C per year.

  2. Occurrence and quality of surface water and ground water within the Yavapai-Prescott Indian Reservation, central Arizona, 1994-98

    USGS Publications Warehouse

    Littin, Gregory R.; Truini, Margot; Pierce, Herbert A.; Baum, Brad M.

    2000-01-01

    The Yavapai-Prescott Indian Reservation encompasses about 1,395 acres in central Arizona adjacent to the city of Prescott. From October 1994 to September 1997, the annual average rainfall was 14.9 inches and the total annual streamflow leaving the reservation along Granite Creek was about 430 acre-feet more than the amount of streamflow entering the reservation. The channel-fill and valley-fill sediments within the flood plain of Granite Creek make up the principal aquifer. The only ground-water development is from spring discharge that is being contained for livestock and wildlife use. About 29 acre-feet of ground water leaves the reservation each year after discharging into Granite Creek. Water levels in wells throughout the reservation reflect seasonal variations in rainfall and snowmelt. Surface water and ground water on the reservation are calcium bicarbonate types. Specific-conductance field measurements ranged from 187 to 724 microsiemens per centimeter for surface water and 381 to 990 microsiemens per centimeter for ground water. Fecal streptococcal bacteria and fecal coliform bacteria in the surface water make the water unsuitable for domestic use. Some volatile and semivolatile organic compounds were detected in samples of surface water, ground water, and streambed sediment. The potential for contamination exists from point and nonpoint sources on and off the reservation.

  3. Year-long evaluation on the occurrence and fate of pharmaceuticals, personal care products, and endocrine disrupting chemicals in an urban drinking water treatment plant.

    PubMed

    Padhye, Lokesh P; Yao, Hong; Kung'u, Francis T; Huang, Ching-Hua

    2014-03-15

    The occurrence and removal of thirty representative pharmaceutical and personal care products (PPCPs) and endocrine disrupting chemicals (EDCs) in an urban drinking water treatment plant (DWTP) were investigated for a period of one year to evaluate current system's treatment efficacy and assess occurrence of PPCPs and EDCs in finished drinking water. Results showed that the average total PPCPs and EDCs concentration in the surface water source was around 360 ng/L (median concentration = 340 ng/L) with 57% coefficient of variation (CV). The median concentrations of most of the individual PPCPs and EDCs in the surface water were below 15 ng/L except for N,N-diethyltoluamide (DEET) and nonylphenol, which were at 122 and 83 ng/L, respectively. The compounds DEET, nonylphenol, ibuprofen, triclosan, atrazine, tris(2-chloroethyl)-phosphate (TCEP), bisphenol-A, and caffeine (in the order of decreasing median concentration) were among twenty compounds detected at least once in the surface water, while all of the above detected compounds, except two, were also detected in the finished drinking water. The average total PPCPs and EDCs concentration in the finished drinking water was around 98 ng/L (median concentration = 96 ng/L) with 66% CV. The median concentrations of most detected PPCPs and EDCs in drinking water were below 5 ng/L except for DEET and nonylphenol, which were at 12 and 20 ng/L, respectively. There was a strong correlation (r = 0.97) between PPCPs and EDCs' concentrations in the source water and in the drinking water over the one-year study period when data points from two sampling events with unusual removals were excluded. Individual water treatment unit processes showed greater temporal variations of PPCPs and EDCs removal efficiencies than the overall treatment processes. The removal efficiencies also varied greatly among different PPCPs and EDCs. The average removal for total PPCPs and EDCs was 76 ± 18% at the DWTP, with ozonation showing the highest removal efficiency. Based on the similar occurrence and removal trends observed as that of total PPCPs and EDCs in this study, DEET and nonylphenol can be considered as potential indicator compounds for predicting the occurrence and removal of total PPCPs and EDCs in surface water. No strong correlations could be found between total PPCPs and EDCs removal and the removal of suspended solids, turbidity, or organic carbon. Copyright © 2013 Elsevier Ltd. All rights reserved.

  4. Spatial Structure of a Braided River: Metric Resolution Hydrodynamic Modeling Reveals What SWOT Might See

    NASA Astrophysics Data System (ADS)

    Schubert, J.; Sanders, B. F.; Andreadis, K.

    2013-12-01

    The Surface Water and Ocean Topography (SWOT) mission, currently under study by NASA (National Aeronautics and Space Administration) and CNES (Centre National d'Etudes Spatiales), is designed to provide global spatial measurements of surface water properties at resolutions better than 10 m and with centimetric accuracy. The data produced by SWOT will include irregularly spaced point clouds of the water surface height, with point spacings from roughly 2-50 m depending on a point's location within SWOT's swath. This could offer unprecedented insight into the spatial structure of rivers. Features that may be resolved include backwater profiles behind dams, drawdown profiles, uniform flow sections, critical flow sections, and even riffle-pool flow structures. In the event that SWOT scans a river during a major flood, it becomes possible to delineate the limits of the flood as well as the spatial structure of the water surface elevation, yielding insight into the dynamic interaction of channels and flood plains. The Platte River in Nebraska, USA, is a braided river with a width and slope of approximately 100 m and 100 cm/km, respectively. A 1 m resolution Digital Terrain Model (DTM) of the river basin, based on airborne lidar collected during low-flow conditions, was used to parameterize a two-dimensional, variable resolution, unstructured grid, hydrodynamic model that uses 3 m resolution triangles in low flow channels and 10 m resolution triangles in the floodplain. Use of a fine resolution mesh guarantees that local variability in topography is resolved, and after applying the hydrodynamic model, the effects of topographic variability are expressed as variability in the water surface height, depth-averaged velocity and flow depth. Flow is modeled over a reach length of 10 km for multi-day durations to capture both frequent (diurnal variations associated with regulated flow) and infrequent (extreme flooding) flow phenomena. Model outputs reveal a number of interesting features, including a high degree of variability in the water depth and velocity and lesser variability in the free-surface profile and river discharge. Hydraulic control sections are also revealed, and shown to depend on flow stage. Reach-averaging of model output is applied to study the macro-scale balance of forces in this system, and the scales at which such a force balance is appropriate. We find that the reach-average slope exhibits a declining reach-length dependence with increasing reach length, up to reach lengths of 1 km. Hence, 1 km appears to be the minimum appropriate length for reach-averaging, and at this scale, a diffusive-wave momentum balance is a reasonable approximation suitable for emerging models of discharge estimation that rely only on SWOT-observable river properties (width, height, slope, etc.).

  5. Field application of farmstead runoff to vegetated filter strips: surface and subsurface water quality assessment.

    PubMed

    Larson, Rebecca A; Safferman, Steven I

    2012-01-01

    Farmstead runoff poses significant environmental impacts to ground and surface waters. Three vegetated filter strips were assessed for the treatment of dairy farmstead runoff at the soil surface and subsurface at 0.3- or 0. 46-m and 0. 76-m depths for numerous storm events. A medium-sized Michigan dairy was retrofitted with two filter strips on sandy loam soil and a third filter strip was implemented on a small Michigan dairy with sandy soil to collect and treat runoff from feed storage, manure storage, and other impervious farmstead areas. All filter strips were able to eliminate surface runoff via infiltration for all storm events over the duration of the study, eliminating pollutant contributions to surface water. Subsurface effluent was monitored to determine the contributing groundwater concentrations of numerous pollutants including chemical oxygen demand (COD), metals, and nitrates. Subsurface samples have an average reduction of COD concentrations of 20, 11, and 85% for the medium dairy Filter Strip 1 (FS1), medium dairy Filter Strip 2 (FS2), and the small Michigan dairy respectively, resulting in average subsurface concentrations of 355, 3960, and 718 mg L COD. Similar reductions were noted for ammonia and total Kjeldahl nitrogen (TKN) in the subsurface effluent. The small Michigan dairy was able to reduce the pollutant leachate concentrations of COD, TKN, and ammonia over a range of influent concentrations. Increased influent concentrations in the medium Michigan dairy filter strips resulted in an increase in COD, TKN, and ammonia concentrations in the leachate. Manganese was leached from the native soils at all filter strips as evidenced by the increase in manganese concentrations in the leachate. Nitrate concentrations were above standard drinking water limits (10 mg L), averaging subsurface concentrations of 11, 45, and 25 mg L NO-N for FS1, FS2, and the small Michigan dairy, respectively. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  6. MERCURY DEPOSITION AND WATER QUALITY IN THE UPPER MIDWEST, USA

    EPA Science Inventory

    Total wet mercury deposition was monitored weekly at six Upper-Midwest, USA sites for a period of six years, 1990-195, to assess temporal and spatial patterns, and contributions to surface waters. Annual wet mercury deposition averaged 7.4 g Hg/m2yr., showed significant variation...

  7. MERCURY DEPOSITIOIN AND WATER QUALITY TRENDS IN THE UPPER MIDWEST, USA

    EPA Science Inventory

    Total wet mercur deposition was monitored weekly at six Upper-Midwest USA sites for a period of six years, 1990-95, to assess temporal and spatial pattern, and contributions to surface waters. Annual wet mercury deposition averaged 7.4 g Hg/m2yr., showed significant variations b...

  8. Evaluation of an Infiltration Model with Microchannels

    NASA Astrophysics Data System (ADS)

    Garcia-Serrana, M.; Gulliver, J. S.; Nieber, J. L.

    2015-12-01

    This research goal is to develop and demonstrate the means by which roadside drainage ditches and filter strips can be assigned the appropriate volume reduction credits by infiltration. These vegetated surfaces convey stormwater, infiltrate runoff, and filter and/or settle solids, and are often placed along roads and other impermeable surfaces. Infiltration rates are typically calculated by assuming that water flows as sheet flow over the slope. However, for most intensities water flow occurs in narrow and shallow micro-channels and concentrates in depressions. This channelization reduces the fraction of the soil surface covered with the water coming from the road. The non-uniform distribution of water along a hillslope directly affects infiltration. First, laboratory and field experiments have been conducted to characterize the spatial pattern of flow for stormwater runoff entering onto the surface of a sloped surface in a drainage ditch. In the laboratory experiments different micro-topographies were tested over bare sandy loam soil: a smooth surface, and three and five parallel rills. All the surfaces experienced erosion; the initially smooth surface developed a system of channels over time that increased runoff generation. On average, the initially smooth surfaces infiltrated 10% more volume than the initially rilled surfaces. The field experiments were performed in the side slope of established roadside drainage ditches. Three rates of runoff from a road surface into the swale slope were tested, representing runoff from 1, 2, and 10-year storm events. The average percentage of input runoff water infiltrated in the 32 experiments was 67%, with a 21% standard deviation. Multiple measurements of saturated hydraulic conductivity were conducted to account for its spatial variability. Second, a rate-based coupled infiltration and overland model has been designed that calculates stormwater infiltration efficiency of swales. The Green-Ampt-Mein-Larson assumptions were implemented to calculate infiltration along with a kinematic wave model for overland flow that accounts for short-circuiting of flow. Additionally, a sensitivity analysis on the parameters implemented in the model has been performed. Finally, the field experiments results have been used to quantify the validity of the coupled model.

  9. Arctic sea ice albedo from AVHRR

    NASA Technical Reports Server (NTRS)

    Lindsay, R. W.; Rothrock, D. A.

    1994-01-01

    The seasonal cycle of surface albedo of sea ice in the Arctic is estimated from measurements made with the Advanced Very High Resolution Radiometer (AVHRR) on the polar-orbiting satellites NOAA-10 and NOAA-11. The albedos of 145 200-km-square cells are analyzed. The cells are from March through September 1989 and include only those for which the sun is more than 10 deg above the horizon. Cloud masking is performed manually. Corrections are applied for instrument calibration, nonisotropic reflection, atmospheric interference, narrowband to broadband conversion, and normalization to a common solar zenith angle. The estimated albedos are relative, with the instrument gain set to give an albedo of 0.80 for ice floes in March and April. The mean values for the cloud-free portions of individual cells range from 0.18 to 0.91. Monthly averages of cells in the central Arctic range from 0.76 in April to 0.47 in August. The monthly averages of the within-cell standard deviations in the central Arctic are 0.04 in April and 0.06 in September. The surface albedo and surface temperature are correlated most strongly in March (R = -0.77) with little correlation in the summer. The monthly average lead fraction is determined from the mean potential open water, a scaled representation of the temperature or albedo between 0.0 (for ice) and 1.0 (for water); in the central Arctic it rises from an average 0.025 in the spring to 0.06 in September. Sparse data on aerosols, ozone, and water vapor in the atmospheric column contribute uncertainties to instantaneous, area-average albedos of 0.13, 0.04, and 0.08. Uncertainties in monthly average albedos are not this large. Contemporaneous estimation of these variables could reduce the uncertainty in the estimated albedo considerably. The poor calibration of AVHRR channels 1 and 2 is another large impediment to making accurate albedo estimates.

  10. Hydrogeology and analysis of ground-water withdrawal from the Catahoula aquifer system in the Natchez area, Adams County, Mississippi

    USGS Publications Warehouse

    Strom, E.W.; Burt, D.E.; Oakley, W.T.

    1995-01-01

    The city of Natchez, located in Adams County, Mississippi, relies on ground water for public supply and industrial needs. Most public supply and industrial wells are developed in Catahoula Formation sands of Miocene age. In 1991, an investigation began to describe the hydrogeology, analyze the effects of ground-water withdrawal from currently pumped wells, and project the possible effects of increased ground-water withdrawals on water levels in the Catahoula aquifer system within the Natchez area. The study area covers about 80 square miles in Adams County, southwestern Mississippi. The study area contains several aquifers; however, the most important aquifers in terms of water supply are the Mississippi River alluvial aquifer and the Catahoula aquifer system. In the Natchez area, the Catahoula aquifer system consists of three main sand intervals that form the upper, middle, and lower Catahoula aquifers. Ground-water withdrawal from the Catahoula aquifer system in the study area currently (March 1995) is from 24 wells screened in the three aquifers. The current daily rate of withdrawal is about 9.2 million gallons of water per day. Analysis of the effect of ground-water withdrawal from these wells was made using the Theis nonequilibrium equation and applying the principle of superposition. The calculated drawdown surfaces under current conditions indicate cones of depression surrounding the principal wells. In the upper Catahoula sand, most of the drawdown is concentrated about 1 mile east of the downtown Natchez area, where a maximum drawdown of 95x11 feet was calculated. Most of the drawdown in the middle Catahoula sand occurred in the same general vicinity as in the upper sand, with a maximum calculated drawdown of about 113 feet. Drawdown in the lower Catahoula sand was concentrated about 4x11 miles northeast of downtown Natchez, with a maximum calculated drawdown of about 31 feet. Drawdown-surface maps were made using calculations based on current pumping rates for 10 years and 20 years beyond March 1995. Planned changes in the pumping configuration were incorporated into these analyses. The drawdown surface calculated for 10 years beyond March 1995 indicates an average total increase in drawdown of about 7.3 feet for the upper Catahoula sand, with a maximum increase of about 28 feet. An average total increase in drawdown of only 1.2 feet was calculated for the middle Catahoula sand due to the planned discontinued pumping of many of the wells. An average total increase in drawdown of about 19 feet was calculated for the lower Catahoula sand, with a maximum increase of about 41 feet. The drawdown surface calculated for 20 years beyond March 1995 indicates an average total additional increase in drawdown over the 10 year drawdown surface of about 1.9, 0.6, and 2.7 feet for the upper, middle, and lower Catahoula sands, respectively.

  11. Pharmaceuticals in a temperate forest-water reuse system.

    PubMed

    McEachran, Andrew D; Shea, Damian; Nichols, Elizabeth Guthrie

    2017-03-01

    Forest-water reuse systems infiltrate municipal, industrial, and agricultural wastewaters through forest soils to shallow aquifers that ultimately discharge to surface waters. Their ability to mitigate regulated nutrients, metals, and organic chemicals is well known, but the fate of non-regulated chemicals in these systems is largely unstudied. This study quantified 33 pharmaceuticals and personal care products (PPCPs) in soils, groundwaters, and surface waters in a 2000-hectare forest that receives ~1200mm/year of secondary-treated, municipal wastewater in addition to natural rainfall (~1300mm/year). This forest-water reuse system does contribute PPCPs to soils, groundwater, and surface waters. PPCPs were more abundant in soils versus underlying groundwater by an order of magnitude (5-10ng/g summed PPCPs in soil and 50-100ng/L in groundwater) and the more hydrophobic chemicals were predominant in soil over water. PPCP concentrations in surface waters were greater at the onset of significant storm events and during low-rainfall periods when total summed PPCPs were >80ng/L, higher than the annual average. With few exceptions, the margins of exposure for PPCPs in groundwater and surface waters were several orders of magnitude above values indicative of human health risk. Copyright © 2016 Elsevier B.V. All rights reserved.

  12. 90Sr, 137Cs and (239,240)Pu concentration surface water time series in the Pacific and Indian Oceans--WOMARS results.

    PubMed

    Povinec, Pavel P; Aarkrog, Asker; Buesseler, Ken O; Delfanti, Roberta; Hirose, Katsumi; Hong, Gi Hoon; Ito, Toshimichi; Livingston, Hugh D; Nies, Hartmut; Noshkin, Victor E; Shima, Shigeki; Togawa, Orihiko

    2005-01-01

    Under an IAEA's Co-ordinated Research Project "Worldwide Marine Radioactivity Studies (WOMARS)" 90Sr, 137Cs and (239,240)Pu concentration surface water time series in the Pacific and Indian Oceans have been investigated. The Pacific and Indian Oceans were divided into 17 latitudinal boxes according to ocean circulation, global fallout patterns and the location of nuclear weapons test sites. The present levels and time trends in radionuclide concentrations in surface water for each box were studied and the corresponding effective half-lives were estimated. For the year 2000, the estimated average 90Sr, 137Cs and (239,240)Pu concentrations in surface waters of the Pacific and Indian Oceans varied from 0.1 to 1.5 mBq/L, 0.1 to 2.8 mBq/L, and 0.1 to 5.2 microBq/L, respectively. The mean effective half-lives for 90Sr and 137Cs in surface water were 12+/-1 years for the North, 20+/-1 years for the South and 21+/-2 years for the Equatorial Pacific. For (239,240)Pu the corresponding mean effective half-lives were 7+/-1 years for the North, 12+/-4 years for the South and 10+/-2 years for the Equatorial Pacific. For the Indian Ocean the mean effective half-lives of 137Cs and (239,240)Pu were 21+/-2 years and 9+/-1 years, respectively. There is evidence that fallout removal rates before 1970 were faster than those observed during recent decades. The estimated surface water concentrations of 90Sr, 137Cs and (239,240)Pu in latitudinal belts of the Pacific and Indian Oceans for the year 2000 may be used as the average levels so that any new contribution from nuclear facilities, nuclear weapons test sites, radioactive waste dumping sites and from possible nuclear accidents can be identified.

  13. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tribble, G.W.; Sansone, F.J.; Li, Yuan-Hui

    Hydraulic exchange between overlying sea water and the internal structure of a patch reef in Kaneohe Bay, Oahu, Hawaii, was studied with an array of wells, 1, 2, and 4 m deep. Two natural chemical tracers, radon, and salinity, were used to calculate the exchange rate between surface sea water and reef interstitial waters. Dissolved radon concentrations are substantially higher in interstitial waters than is surface water. The degree of radon enrichment is quantitatively related to the time elapsed since interstitial water had equilibrated with the atmosphere. Residence time estimates are 1-40 days, with deeper wells having slower exchange. Themore » average residence time for 1-m-deep wells was 2.1 days. A rainstorm-induced dilution of the salinity of Kaneohe Bay provides the second tracer. Samples of surface and reef interstitial waters following this salinity perturbation are used to calculate an average residence time of 2.6 days at a depth of 1 m and 42 days at a depth of 2 m. Three types of physical forces thought to cause exchange between surface and interstitial water are considered by measurement of the forcing functions and reef permeability. Hydraulic conductivities are about 50 m/d, with lower values near the seaward side of the reef. Most exchange seems to be caused by high-frequency, wave-driven oscillatory pumping and by unidirectional hydraulic head gradients (of uncertain origin) that are stable for at least 3-4 days. Wave-driven mixing is probably more important shallower in the reef, whereas head-driven flow may dominate deeper in the reef. Tidal pumping does not seem to contribute to exchange. All methods indicate that exchange in the upper part of Checker Reef is primarily through vertical exchange. The best estimate for the residence time of water at a depth of 1 m is 2 days. Water at depths of 204 m probably has a residence time of weeks to months. 49 refs., 8 figs., 6 tabs.« less

  14. Grey water characteristics and treatment options for rural areas in Jordan.

    PubMed

    Halalsheh, M; Dalahmeh, S; Sayed, M; Suleiman, W; Shareef, M; Mansour, M; Safi, M

    2008-09-01

    Low water consumption in rural areas in Jordan had resulted in the production of concentrated grey water. Average COD, BOD and TSS values were 2568mg/l, 1056mg/l and 845mg/l, respectively. The average grey water generation was measured to be 14L/c.d. Three different treatment options were selected based on certain criterions, and discussed in this article. The examined treatment systems are septic tank followed by intermittent sand filter; septic tank followed by wetlands; and UASB-hybrid reactor. Advantages and disadvantages of each system are presented. It was concluded that UASB-hybrid reactor would be the most suitable treatment option in terms of compactness and simplicity in operation. The volume of UASB-hybrid reactor was calculated to be 0.268m(3) with a surface area of 0.138m(2) for each house having 10 inhabitants on average. Produced effluent is expected to meet Jordanian standards set for reclaimed water reuse in irrigating fruit trees.

  15. Using a GIS to link digital spatial data and the precipitation-runoff modeling system, Gunnison River Basin, Colorado

    USGS Publications Warehouse

    Battaglin, William A.; Kuhn, Gerhard; Parker, Randolph S.

    1993-01-01

    The U.S. Geological Survey Precipitation-Runoff Modeling System, a modular, distributed-parameter, watershed-modeling system, is being applied to 20 smaller watersheds within the Gunnison River basin. The model is used to derive a daily water balance for subareas in a watershed, ultimately producing simulated streamflows that can be input into routing and accounting models used to assess downstream water availability under current conditions, and to assess the sensitivity of water resources in the basin to alterations in climate. A geographic information system (GIS) is used to automate a method for extracting physically based hydrologic response unit (HRU) distributed parameter values from digital data sources, and for the placement of those estimates into GIS spatial datalayers. The HRU parameters extracted are: area, mean elevation, average land-surface slope, predominant aspect, predominant land-cover type, predominant soil type, average total soil water-holding capacity, and average water-holding capacity of the root zone.

  16. UV sensitivity of planktonic net community production in ocean surface waters

    NASA Astrophysics Data System (ADS)

    Regaudie-de-Gioux, Aurore; Agustí, Susana; Duarte, Carlos M.

    2014-05-01

    The net plankton community metabolism of oceanic surface waters is particularly important as it more directly affects the partial pressure of CO2 in surface waters and thus the air-sea fluxes of CO2. Plankton communities in surface waters are exposed to high irradiance that includes significant ultraviolet blue (UVB, 280-315 nm) radiation. UVB radiation affects both photosynthetic and respiration rates, increase plankton mortality rates, and other metabolic and chemical processes. Here we test the sensitivity of net community production (NCP) to UVB of planktonic communities in surface waters across contrasting regions of the ocean. We observed here that UVB radiation affects net plankton community production at the ocean surface, imposing a shift in NCP by, on average, 50% relative to the values measured when excluding partly UVB. Our results show that under full solar radiation, the metabolic balance shows the prevalence of net heterotrophic community production. The demonstration of an important effect of UVB radiation on NCP in surface waters presented here is of particular relevance in relation to the increased UVB radiation derived from the erosion of the stratospheric ozone layer. Our results encourage design future research to further our understanding of UVB effects on the metabolic balance of plankton communities.

  17. Surface- and ground-water relations on the Portneuf river, and temporal changes in ground-water levels in the Portneuf Valley, Caribou and Bannock Counties, Idaho, 2001-02

    USGS Publications Warehouse

    Barton, Gary J.

    2004-01-01

    The State of Idaho and local water users are concerned that streamflow depletion in the Portneuf River in Caribou and Bannock Counties is linked to ground-water withdrawals for irrigated agriculture. A year-long field study during 2001 02 that focused on monitoring surface- and ground-water relations was conducted, in cooperation with the Idaho Department of Water Resources, to address some of the water-user concerns. The study area comprised a 10.2-mile reach of the Portneuf River downstream from the Chesterfield Reservoir in the broad Portneuf Valley (Portneuf River Valley reach) and a 20-mile reach of the Portneuf River in a narrow valley downstream from the Portneuf Valley (Pebble-Topaz reach). During the field study, the surface- and ground-water relations were dynamic. A losing river reach was delineated in the middle of the Portneuf River Valley reach, centered approximately 7.2 miles downstream from Chesterfield Reservoir. Two seepage studies conducted in the Portneuf Valley during regulated high flows showed that the length of the losing river reach increased from 2.6 to nearly 6 miles as the irrigation season progressed.Surface- and ground-water relations in the Portneuf Valley also were characterized from an analysis of specific conductance and temperature measurements. In a gaining reach, stratification of specific conductance and temperature across the channel of the Portneuf River was an indicator of ground water seeping into the river.An evolving method of using heat as a tracer to monitor surface- and ground-water relations was successfully conducted with thermistor arrays at four locations. Heat tracing monitored a gaining reach, where ground water was seeping into the river, and monitored a losing reach, where surface water was seeping down through the riverbed (also referred to as a conveyance loss), at two locations.Conveyance losses in the Portneuf River Valley reach were greatest, about 20 cubic feet per second, during the mid-summer regulated high flows. Conveyance losses in the Pebble-Topaz reach were greatest, about 283 cubic feet per second, during the spring regulated high flows and were attributed to a hydroelectric project.Comparison of water levels in 30 wells in the Portneuf Valley during September and October 1968 and 2001 indicated long-term declines since 1968; the median decline was 3.4 feet. September and October were selected for characterizing long-term ground-water-level fluctuations because declines associated with irrigation reach a maximum at the end of the irrigation season. The average annual snowpack in the study area has declined significantly; 1945 85 average annual snowpack was 16.1 inches, whereas 1986 through 2002 average annual snowpack was 11.6 inches. Water-level declines during 1998 2002 may be partially attributable to the extended dry climatic conditions. It is unclear whether the declines could be partially attributed to increases in ground-water withdrawals. Between 1968 and 1980, water rights for ground-water withdrawals nearly doubled from 23,500 to 46,000 acre-feet per year. During this period, ground-water levels were relatively constant and did not exhibit a declining trend that could be related to increased ground-water withdrawal rights. However, ground-water withdrawals are not measured in the valley; thus, the amount of water pumped is not known. Since the 1990s, there have been several years when the Chesterfield Reservoir has not completely refilled, and the water in storage behind the reservoir has been depleted by the middle of the irrigation season. In this situation, surface-water diversions for irrigation were terminated before the end of the irrigation season, and irrigators, who were relying in part on diversions from the Portneuf River, had to rely solely on ground water as an alternate supply. Smaller volumes of water in the Chesterfield Reservoir since the 1990s indicate a growing demand for ground-water supplies.

  18. Estimates of average annual tributary inflow to the lower Colorado River, Hoover Dam to Mexico

    USGS Publications Warehouse

    Owen-Joyce, Sandra J.

    1987-01-01

    Estimates of tributary inflow by basin or area and by surface water or groundwater are presented in this report and itemized by subreaches in tabular form. Total estimated average annual tributary inflow to the Colorado River between Hoover Dam and Mexico, excluding the measured tributaries, is 96,000 acre-ft or about 1% of the 7.5 million acre-ft/yr of Colorado River water apportioned to the States in the lower Colorado River basin. About 62% of the tributary inflow originates in Arizona, 30% in California, and 8% in Nevada. Tributary inflow is a small component in the water budget for the river. Most of the quantities of unmeasured tributary inflow were estimated in previous studies and were based on mean annual precipitation for 1931-60. Because mean annual precipitation for 1951-80 did not differ significantly from that of 1931-60, these tributary inflow estimates are assumed to be valid for use in 1984. Measured average annual runoff per unit drainage area on the Bill Williams River has remained the same. Surface water inflow from unmeasured tributaries is infrequent and is not captured in surface reservoirs in any of the States; it flows to the Colorado River gaging stations. Estimates of groundwater inflow to the Colorad River valley. Average annual runoff can be used in a water budget; although in wet years, runoff may be large enough to affect the calculation of consumptive use and to be estimated from hydrographs for the Colorado River valley are based on groundwater recharge estimates in the bordering areas, which have not significantly changed through time. In most areas adjacent to the Colorado River valley, groundwater pumpage is small and pumping has not significantly affected the quantity of groundwater discharged to the Colorado River valley. In some areas where groundwater pumpage exceeds the quantity of groundwater discharge and water levels have declined, the quantity of discharge probably has decreased and groundwater inflow to the Colorado River valley will eventually be reduced if not stopped completely. Groundwater discharged at springs below Hoover Dam is unused and flows directly to the Colorado River. (Lantz-PTT)

  19. The water footprint of humanity.

    PubMed

    Hoekstra, Arjen Y; Mekonnen, Mesfin M

    2012-02-28

    This study quantifies and maps the water footprint (WF) of humanity at a high spatial resolution. It reports on consumptive use of rainwater (green WF) and ground and surface water (blue WF) and volumes of water polluted (gray WF). Water footprints are estimated per nation from both a production and consumption perspective. International virtual water flows are estimated based on trade in agricultural and industrial commodities. The global annual average WF in the period 1996-2005 was 9,087 Gm(3)/y (74% green, 11% blue, 15% gray). Agricultural production contributes 92%. About one-fifth of the global WF relates to production for export. The total volume of international virtual water flows related to trade in agricultural and industrial products was 2,320 Gm(3)/y (68% green, 13% blue, 19% gray). The WF of the global average consumer was 1,385 m(3)/y. The average consumer in the United States has a WF of 2,842 m(3)/y, whereas the average citizens in China and India have WFs of 1,071 and 1,089 m(3)/y, respectively. Consumption of cereal products gives the largest contribution to the WF of the average consumer (27%), followed by meat (22%) and milk products (7%). The volume and pattern of consumption and the WF per ton of product of the products consumed are the main factors determining the WF of a consumer. The study illustrates the global dimension of water consumption and pollution by showing that several countries heavily rely on foreign water resources and that many countries have significant impacts on water consumption and pollution elsewhere.

  20. Near-Surface Geophysical Character of a Holocene Fault Carrying Geothermal Flow Near Pyramid Lake, Nevada

    NASA Astrophysics Data System (ADS)

    Dudley, C.; Dorsey, A.; Louie, J. N.; Schwering, P. C.; Pullammanappallil, S.

    2012-12-01

    Lines of calcium carbonate tufa columns mark recent faults that cut 11 ka Lake Lahontan sediments at Astor Pass, north of Pyramid Lake, Nevada. Throughout the Great Basin, faults appear to control the location of geothermal resources, providing pathways for fluid migration. Reservoir-depth (greater than 1 km) seismic imaging at Astor Pass shows a fault that projects to one of the lines of tufa columns at the surface. The presence of the tufa deposits suggests this fault carried warm geothermal waters through the lakebed clay sediments in recent time. The warm fluids deposited the tufa when they hit cold Lake Lahontan water at the lakebed. Lake Lahontan covered this location to a depth of at least 60 m at 11 ka. In collaboration with the Pyramid Lake Paiute Tribe, an Applied Geophysics class at UNR investigated the near-surface geophysical characteristics of this fault. The survey comprises near-surface seismic reflection and refraction, nine near-surface refraction microtremor (SeisOpt® ReMi™) arrays, nine near-surface direct-current resistivity soundings, magnetic surveys, and gravity surveys at and near the tufa columns. The refraction microtremor results show shear velocities near tufa and faults to be marginally lower, compared to Vs away from the faults. Overall, the 30-m depth-averaged shear velocities are low, less than 300 m/s, consistent with the lakebed clay deposits. These results show no indication of any fast (> 500 m/s) tufa below the surface at or near the tufa columns. Vs30 averages were 274 ± 13 m/s on the fault, 287 ± 2 m/s at 150 m east of the fault, and 290 ± 15 m/s at 150 m west of the fault. The P-velocity refraction optimization results also show no indication of high-velocity tufa buried below the surface in the Lahontan sediments, reinforcing the idea that all tufa was deposited above the lakebed surface. The seismic results provide a negative test of the hypothesis that deposition of the lakebeds in the Quaternary buried and preserved older tufa columns within the section. Near-surface Wenner arrays with a-spacings up to 30 m show a higher resistivity near the faults, and tufa, than away from the faults. Resistivity averages were 33 ± 17 ohm-m on the fault, 13 ± 3 ohm-m east of the fault, and 9 ± 3 ohm-m west of the fault. It is possible the geothermal waters are fresher than waters held in the lakebed clays. Water samples from more than 1 km depth in exploration wells had almost drinking-water quality. This higher resistivity of the waters carried by the fault zone, with perhaps a higher porosity and permeability along the fault, could explain the higher resistivity near the fault. Our work shows that there is no high-velocity, high-resistivity tufa along the faults below the surface, so we are unable to use buried tufa to locate faults with geothermal upwellings in this area. We can further hypothesize that as sedimentation buried the tufa during the Quaternary, warm geothermal waters re-dissolved it, and re-precipitated it only in the cold lake-bottom water.

  1. Vegetation of prairie potholes, North Dakota, in relation to quality of water and other environmental factors

    USGS Publications Warehouse

    Stewart, R.E.; Kantrud, H.A.

    1972-01-01

    Measurements of specific conductance provide an adequate indication of the average salinity of surface waters in natural ponds and lakes of the northern .prairie region. Yearly and seasonal variations in specific conductance were much greater in brackish and subsaline wetlands than in fresh-water areas. The principal vegetational types. Land-use practices of varying brackish to saline wetlands were sulfates and chlorides of sodium and magnesium. In less saline waters, carbonate and bicarbonate salts of calcium and potassium were of greater importance, but as salinity increased, the proportion of these compounds decreased rapidly.A major environmental factor controlling the establishment of marsh and aquatic vegetation is the permanence of surface water. Permanence is a measure of the extent to which surface water persists at a given site. Varying degrees of water permanence during the growing season led to the establishment of distinct vegetational types, which were differentiated primarily on the 'basis of community structure or life form of the dominant vegetation.Salinity of surface waters was closely correlated with differences in species composition of plant communities found in the principal vegetational types. Land-use practices of varying degrees of intensity also had a secondary influence on species composition. Since an unstable water chemistry is characteristic of most prairie ponds and lakes, it is more reliable to use the plant communities as indicators of average salinity than to use single measurements of specific conductance.Characteristic species of wetland vegetational types occupied the central deeper parts of pond and lake basins or occurred as concentric peripheral bands. The wetland vegetational types are wetland low-prairie, wet-meadow, shallow-marsh emergent, deep-marsh emergent, fen emergent, submerged and floating, natural drawdown, cropland drawdown, and cropland tillage vegetation. Combinations of species (plant associations) within these vegetational types were placed in one of six salinity categories designated as fresh, slightly brackish, moderately brackish, brackish, subsaline, and saline. Salt tolerance apparently varied greatly among the various marsh and aquatic plants since the num'ber of species represented in moderately brackish to saline communities decreased markedly with increased salinity of the surface water environment.

  2. Concentrations, Trends, and Air-Water Exchange of PAHs and PBDEs Derived from Passive Samplers in Lake Superior in 2011.

    PubMed

    Ruge, Zoe; Muir, Derek; Helm, Paul; Lohmann, Rainer

    2015-12-01

    Polycyclic aromatic hydrocarbons (PAHs) and polybrominated diphenylethers (PBDEs) are both currently released into the environment from anthropogenic activity. Both are hence primarily associated with populated or industrial areas, although wildfires can be an important source of PAHs, as well. Polyethylene passive samplers (PEs) were simultaneously deployed in surface water and near surface atmosphere to determine spatial trends and air-water gaseous exchange of 21 PAHs and 11 PBDEs at 19 sites across Lake Superior in 2011. Surface water and atmospheric PAH concentrations were greatest at urban sites (up to 65 ng L(-1) and 140 ng m(-3), respectively, averaged from June to October). Near populated regions, PAHs displayed net air-to-water deposition, but were near equilibrium off-shore. Retene, probably depositing following major wildfires in the region, dominated dissolved PAH concentrations at most Lake Superior sites. Atmospheric and dissolved PBDEs were greatest near urban and populated sites (up to 6.8 pg L(-1) and 15 pg m(-3), respectively, averaged from June to October), dominated by BDE-47. At most coastal sites, there was net gaseous deposition of BDE-47, with less brominated congeners contributing to Sault Ste. Marie and eastern open lake fluxes. Conversely, the central open lake and Eagle Harbor sites generally displayed volatilization of PBDEs into the atmosphere, mainly BDE-47.

  3. Physical and hydrologic characteristics of Matlacha Pass, southwestern Florida

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kane, R.L.; Russell, G.M.

    1994-03-01

    Matlacha Pass is part of the connected inshore waters of the Charlotte Harbor estuary in southwestern Florida. Bathymetry indicates that depths in the main channel of the pass range from 4 to 14 feet below sea level. The channel averages about 8 feet deep in the northern part of the pass and about 5 feet deep in the southern part. Additionally, depths average about 4 feet in a wide section of the middle of the pass and about 2 feet along the mangrove swamps near the shoreline. Tidal flow within Matlacha Pass varies depending on aquatic vegetation densities, oyster beds,more » and tidal flats. Surface-water runoff occurs primarily during the wet season (May to September), with most of the flow entering the Matlacha Pass through two openings in the spreader canal system near the city of Matlacha. Freshwater flow into the pass from the north Cape Coral spreader canal system averaged 113 cubic feet per second from October 1987 to September 1992. Freshwater inflow from the Aries Canal of the south Cape Coral spreader canal system averaged 14.1 cubic feet per second from October 1989 to September 1992. Specific conductance throughout Matlacha Pass ranged from less than 1,000 to 57,000 microsiemens per centimeter. Specific conductance, collected from a continuous monitoring data logger in the middle of the pass from February to September 1992, averaged 36,000 microsiemens per centimeter at 2 feet below the water surface and 40,000 microsiemens per centimeter at 2 feet above the bottom. During both the wet and dry seasons, specific conductance indicated that the primary mixing of tidal waters and freshwater inflow occurs in the mangrove swamps along the shoreline.« less

  4. How Well Can We Estimate Areal-Averaged Spectral Surface Albedo from Ground-Based Transmission in an Atlantic Coastal Area?

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kassianov, Evgueni I.; Barnard, James C.; Flynn, Connor J.

    Areal-averaged albedos are particularly difficult to measure in coastal regions, because the surface is not homogenous, consisting of a sharp demarcation between land and water. With this difficulty in mind, we evaluate a simple retrieval of areal-averaged surface albedo using ground-based measurements of atmospheric transmission alone under fully overcast conditions. To illustrate the performance of our retrieval, we find the areal-averaged albedo using measurements from the Multi-Filter Rotating Shadowband Radiometer (MFRSR) at five wavelengths (415, 500, 615, 673, and 870 nm). These MFRSR data are collected at a coastal site in Graciosa Island, Azores supported by the U.S. Department ofmore » Energy’s (DOE’s) Atmospheric Radiation Measurement (ARM) Program. The areal-averaged albedos obtained from the MFRSR are compared with collocated and coincident Moderate Resolution Imaging Spectroradiometer (MODIS) white-sky albedo at four nominal wavelengths (470, 560, 670 and 860 nm). These comparisons are made during a 19-month period (June 2009 - December 2010). We also calculate composite-based spectral values of surface albedo by a weighted-average approach using estimated fractions of major surface types observed in an area surrounding this coastal site. Taken as a whole, these three methods of finding albedo show spectral and temporal similarities, and suggest that our simple, transmission-based technique holds promise, but with estimated errors of about ±0.03. Additional work is needed to reduce this uncertainty in areas with inhomogeneous surfaces.« less

  5. Field application of passive SBSE for the monitoring of pesticides in surface waters.

    PubMed

    Assoumani, A; Coquery, M; Liger, L; Mazzella, N; Margoum, C

    2015-03-01

    Spot sampling lacks representativeness for monitoring organic contaminants in most surface waters. Passive sampling has emerged as a cost-effective complementary sampling technique. We recently developed passive stir bar sorptive extraction (passive SBSE), with Twister from Gerstel, for monitoring moderately hydrophilic to hydrophobic pesticides (2.18 < log K ow < 5.11) in surface water. The aims of the present study were to assess this new passive sampler for the determination of representative average concentrations and to evaluate the contamination levels of two French rivers. Passive SBSE was evaluated for the monitoring of 16 pesticides in two rivers located in a small vineyard watershed during two 1-month field campaigns in spring 2010 and spring 2011. Passive SBSE was applied for periods of 1 or 2 weeks during the field campaigns and compared with spot sampling and weekly average automated sampling. The results showed that passive SBSE could achieve better time-representativeness than spot sampling and lower limits of quantification than automated sampling coupled with analytical SBSE for the pesticides studied. Finally, passive SBSE proved useful for revealing spatial and temporal variations in pesticide contamination of both rivers and the impact of rainfall and runoff on the river water quality.

  6. Mercury pollution in Doha (Qatar) coastal environment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Al-Madfa, H.; Dahab, O.A.; Holail, H.

    Surface water and sediment samples were collected from the Doha coastal area and analyzed for content of physico-chemical forms of mercury. Dissolved reactive Hg represented 81.0% of the total dissolved Hg. Organic Hg contributed only 5.0% of total Hg. Mercury showed a strong tendency to be associated with suspended matter in Doha coastal waters, as it represented about 73.0% of the total. Total Hg in bulk Doha surface sediments fluctuated between 0.14 and 1.75 [mu]g g[sup [minus]1] dry weight, with an average of 0.54 [+-] 0.46 [mu]g g[sup [minus]1] dry weight. The sediment fraction past 63 [mu]m contained 0.73 [+-]more » 0.60 [mu]g g[sup [minus]1] dry weight total Hg. Leachable and methyl Hg averaged 0.10 [+-] 0.11 and 0.02 [+-] 0.03 [mu]g g[sup [minus]1] dry weight, respectively, in the < 63-[mu]m sediment fraction. There is a general trend for all Hg species determined in water and sediments to decrease seaward. The significantly elevated Hg levels at certain locations indicated that the main Hg sources to Doha coastal environment are leachate from the solid waste disposal site, the two harbors, and surface-water discharge.« less

  7. Preliminary evaluation of the feasibility of artificial recharge in northern Qater

    USGS Publications Warehouse

    Vecchioli, John

    1976-01-01

    Fresh ground water in northern Qatar occurs as a lens in limestone and dolomite of Eocene age. Natural recharge from precipitation averages 17x106 cubic metres per year whereas current discharge averages 26.6x106 cubic metres per year. Depletion of storage is accompanied by a deterioration in quality due to encroachment of salty water from the Gulf and from underlying formations. Artificial recharge with desalted sea water to permit additional agricultural development appears technically feasible but its practicability needs to be examined further. A hydrogeological appraisal including test drilling, geophysical logging, pumping tests, and a recharge test, coupled with engineering analysis of direct surface storage/distribution of desalted sea water versus aquifer storage/distribution, is recommended.

  8. Altitude of potentiometric surface, fall 1985, and historic water-level changes in the Fort Pillow aquifer in western Tennessee

    USGS Publications Warehouse

    Parks, W.S.; Carmichael, J.K.

    1990-01-01

    Recharge to the Fort Pillow aquifer of Tertiary age in Tennessee is from precipitation on the outcrop, which forms a narrow belt across western Tennessee, and by downward infiltration of water from the overlying fluvial deposits of Tertiary and Quaternary age and alluvium of Quaternary age or, where the upper confining unit is absent, from the overlying Memphis aquifer of Tertiary age. The potentiometric surface in the Fort Pillow aquifer slopes gently westward from the outcrop-recharge area, and the water moves slowly in that direction. A depression in the potentiometric surface in the Memphis area is the result of past pumping at Memphis Light, Gas and Water Division (MLGW) well fields (1924-74), and past and present pumping at an industrial well field at Memphis, and the municipal well field at West Memphis, Ark. Water levels in areas affected by pumping have declined at average rates ranging from 0.4 to 0. 9 ft/year during the period 1945-85. The greatest rate of decline was as much as 4.0 ft/year between 1945 and 1954 in an observation well in a well field of MLGW at Memphis. In 1971, MLGW ceased pumping from the Fort Pillow aquifer at this well field, and between 1972 and 1976, water levels rose about 28 ft in this well. Withdrawals from the Fort Pillow aquifer in western Tennessee in 1985 averaged about 12 million gal/day. (USGS)

  9. Using an implicitly-coupled hydrologic and river-operations models to investigate the trade-offs of artificial recharge in agricultural areas

    NASA Astrophysics Data System (ADS)

    Morway, E. D.; Niswonger, R. G.; Triana, E.

    2016-12-01

    In irrigated agricultural regions supplied by both surface-water and groundwater, increased reliance on groundwater during sustained drought leads to long-term water table drawdown and subsequent surface-water losses. This, in turn, may threaten the sustainability of the irrigation project. To help offset groundwater resource losses and restore water supply reliability, an alternative management strategy commonly referred to as managed aquifer recharge (MAR) in agricultural regions helps mitigate long-term aquifer drawdown and provides additional water for subsequent withdraw. Sources of MAR in this investigation are limited to late winter runoff in years with above average precipitation (i.e., above average snowpack). However, where winter MAR results in an elevated water table, non-beneficial consumptive use may increase from evapotranspiration in adjacent and down-gradient fallow and naturally vegetated lands. To rigorously explore this trade-off, the recently published MODSIM-MODFLOW model was applied to quantify both the benefits and unintended consequences of MAR. MODSIM-MODFLOW is a generalized modeling tool capable of exploring the effects of altered river operations within an integrated groundwater and surface-water (GW-SW) model. Thus, the MODSIM-MODFLOW model provides a modeling platform capable of simulating MAR in amounts and duration consistent with other senior water rights in the river system (e.g., minimum in-stream flow requirements). Increases in non-beneficial consumptive use resulting from winter MAR are evaluated for a hypothetical model patterned after alluvial aquifers common in arid and semi-arid areas of the western United States. Study results highlight (1) the benefit of an implicitly-coupled river operations and hydrologic modeling tool, (2) the balance between winter MAR and the potential increase in non-beneficial consumptive use, and (3) conditions where MAR may or may not be an appropriate management option, such as the availability of surface-water storage.

  10. Chemical and biological impacts of ocean acidification along the west coast of North America

    NASA Astrophysics Data System (ADS)

    Feely, Richard A.; Alin, Simone R.; Carter, Brendan; Bednaršek, Nina; Hales, Burke; Chan, Francis; Hill, Tessa M.; Gaylord, Brian; Sanford, Eric; Byrne, Robert H.; Sabine, Christopher L.; Greeley, Dana; Juranek, Lauren

    2016-12-01

    The continental shelf region off the west coast of North America is seasonally exposed to water with a low aragonite saturation state by coastal upwelling of CO2-rich waters. To date, the spatial and temporal distribution of anthropogenic CO2 (Canth) within the CO2-rich waters is largely unknown. Here we adapt the multiple linear regression approach to utilize the GO-SHIP Repeat Hydrography data from the northeast Pacific to establish an annually updated relationship between Canth and potential density. This relationship was then used with the NOAA Ocean Acidification Program West Coast Ocean Acidification (WCOA) cruise data sets from 2007, 2011, 2012, and 2013 to determine the spatial variations of Canth in the upwelled water. Our results show large spatial differences in Canth in surface waters along the coast, with the lowest values (37-55 μmol kg-1) in strong upwelling regions off southern Oregon and northern California and higher values (51-63 μmol kg-1) to the north and south of this region. Coastal dissolved inorganic carbon concentrations are also elevated due to a natural remineralized component (Cbio), which represents carbon accumulated through net respiration in the seawater that has not yet degassed to the atmosphere. Average surface Canth is almost twice the surface remineralized component. In contrast, Canth is only about one third and one fifth of the remineralized component at 50 m and 100 m depth, respectively. Uptake of Canth has caused the aragonite saturation horizon to shoal by approximately 30-50 m since the preindustrial period so that undersaturated waters are well within the regions of the continental shelf that affect the shell dissolution of living pteropods. Our data show that the most severe biological impacts occur in the nearshore waters, where corrosive waters are closest to the surface. Since the pre-industrial times, pteropod shell dissolution has, on average, increased approximately 19-26% in both nearshore and offshore waters.

  11. Surface Water pCO2 Variations and Sea-Air CO2 Fluxes During Summer in the Eastern Canadian Arctic

    NASA Astrophysics Data System (ADS)

    Burgers, T. M.; Miller, L. A.; Thomas, H.; Else, B. G. T.; Gosselin, M.; Papakyriakou, T.

    2017-12-01

    Based on a 2 year data set, the eastern Canadian Arctic Archipelago and Baffin Bay appear to be a modest summertime sink of atmospheric CO2. We measured surface water CO2 partial pressure (pCO2), salinity, and temperature throughout northern Baffin Bay, Nares Strait, and Lancaster Sound from the CCGS Amundsen during its 2013 and 2014 summer cruises. Surface water pCO2 displayed considerable variability (144-364 μatm) but never exceeded atmospheric concentrations, and average calculated CO2 fluxes in 2013 and 2014 were -12 and -3 mmol C m-2 d-1 (into the ocean), respectively. Ancillary measurements of chlorophyll a reveal low summertime productivity in surface waters. Based on total alkalinity and stable oxygen isotopes (δ18O) data, a strong riverine signal in northern Nares Strait coincided with relatively high surface pCO2, whereas areas of sea-ice melt occur with low surface pCO2. Further assessments, extending the seasonal observation period, are needed to properly constrain both seasonal and annual CO2 fluxes in this region.

  12. On the equilibrium contact angle of sessile liquid drops from molecular dynamics simulations.

    PubMed

    Ravipati, Srikanth; Aymard, Benjamin; Kalliadasis, Serafim; Galindo, Amparo

    2018-04-28

    We present a new methodology to estimate the contact angles of sessile drops from molecular simulations by using the Gaussian convolution method of Willard and Chandler [J. Phys. Chem. B 114, 1954-1958 (2010)] to calculate the coarse-grained density from atomic coordinates. The iso-density contour with average coarse-grained density value equal to half of the bulk liquid density is identified as the average liquid-vapor (LV) interface. Angles between the unit normal vectors to the average LV interface and unit normal vector to the solid surface, as a function of the distance normal to the solid surface, are calculated. The cosines of these angles are extrapolated to the three-phase contact line to estimate the sessile drop contact angle. The proposed methodology, which is relatively easy to implement, is systematically applied to three systems: (i) a Lennard-Jones (LJ) drop on a featureless LJ 9-3 surface; (ii) an SPC/E water drop on a featureless LJ 9-3 surface; and (iii) an SPC/E water drop on a graphite surface. The sessile drop contact angles estimated with our methodology for the first two systems are shown to be in good agreement with the angles predicted from Young's equation. The interfacial tensions required for this equation are computed by employing the test-area perturbation method for the corresponding planar interfaces. Our findings suggest that the widely adopted spherical-cap approximation should be used with caution, as it could take a long time for a sessile drop to relax to a spherical shape, of the order of 100 ns, especially for water molecules initiated in a lattice configuration on a solid surface. But even though a water drop can take a long time to reach the spherical shape, we find that the contact angle is well established much faster and the drop evolves toward the spherical shape following a constant-contact-angle relaxation dynamics. Making use of this observation, our methodology allows a good estimation of the sessile drop contact angle values even for moderate system sizes (with, e.g., 4000 molecules), without the need for long simulation times to reach the spherical shape.

  13. On the equilibrium contact angle of sessile liquid drops from molecular dynamics simulations

    NASA Astrophysics Data System (ADS)

    Ravipati, Srikanth; Aymard, Benjamin; Kalliadasis, Serafim; Galindo, Amparo

    2018-04-01

    We present a new methodology to estimate the contact angles of sessile drops from molecular simulations by using the Gaussian convolution method of Willard and Chandler [J. Phys. Chem. B 114, 1954-1958 (2010)] to calculate the coarse-grained density from atomic coordinates. The iso-density contour with average coarse-grained density value equal to half of the bulk liquid density is identified as the average liquid-vapor (LV) interface. Angles between the unit normal vectors to the average LV interface and unit normal vector to the solid surface, as a function of the distance normal to the solid surface, are calculated. The cosines of these angles are extrapolated to the three-phase contact line to estimate the sessile drop contact angle. The proposed methodology, which is relatively easy to implement, is systematically applied to three systems: (i) a Lennard-Jones (LJ) drop on a featureless LJ 9-3 surface; (ii) an SPC/E water drop on a featureless LJ 9-3 surface; and (iii) an SPC/E water drop on a graphite surface. The sessile drop contact angles estimated with our methodology for the first two systems are shown to be in good agreement with the angles predicted from Young's equation. The interfacial tensions required for this equation are computed by employing the test-area perturbation method for the corresponding planar interfaces. Our findings suggest that the widely adopted spherical-cap approximation should be used with caution, as it could take a long time for a sessile drop to relax to a spherical shape, of the order of 100 ns, especially for water molecules initiated in a lattice configuration on a solid surface. But even though a water drop can take a long time to reach the spherical shape, we find that the contact angle is well established much faster and the drop evolves toward the spherical shape following a constant-contact-angle relaxation dynamics. Making use of this observation, our methodology allows a good estimation of the sessile drop contact angle values even for moderate system sizes (with, e.g., 4000 molecules), without the need for long simulation times to reach the spherical shape.

  14. Thermophilic campylobacters in surface waters around Lancaster, UK: negative correlation with Campylobacter infections in the community.

    PubMed

    Jones, K; Betaieb, M; Telford, D R

    1990-11-01

    The incidence of campylobacter enteritis in Lancaster City Health Authority is three times the UK average for similar sizes of population and has marked seasonal peaks in May and June. Environmental monitoring of surface waters around Lancaster showed that thermophilic campylobacters were absent from drinking water from the fells and from the clean upper reaches of the River Conder but were present in the main rivers entering Morecambe Bay, the lower reaches of the River Conder, the Lancaster canal, and seawater from the Lune estuary and Morecambe Bay. All the surface waters tested showed the same seasonality, namely, higher numbers in the winter months and low numbers or none in May, June and July. The absence of thermophilic campylobacters in the summer months may be due to high sunshine levels because experiments on the effects of light showed that campylobacters in sewage effluent and seawater were eliminated within 60 and 30 min of daylight respectively but survived for 24 h in darkness. As the concentrations of campylobacters in surface waters were at their lowest precisely at the time of peak infections in the community it is unlikely that surface waters form Lancaster's reservoir of campylobacter infection for the community.

  15. A continuum model for meltwater flow through compacting snow

    NASA Astrophysics Data System (ADS)

    Meyer, Colin R.; Hewitt, Ian J.

    2017-12-01

    Meltwater is produced on the surface of glaciers and ice sheets when the seasonal energy forcing warms the snow to its melting temperature. This meltwater percolates into the snow and subsequently runs off laterally in streams, is stored as liquid water, or refreezes, thus warming the subsurface through the release of latent heat. We present a continuum model for the percolation process that includes heat conduction, meltwater percolation and refreezing, as well as mechanical compaction. The model is forced by surface mass and energy balances, and the percolation process is described using Darcy's law, allowing for both partially and fully saturated pore space. Water is allowed to run off from the surface if the snow is fully saturated. The model outputs include the temperature, density, and water-content profiles and the surface runoff and water storage. We compare the propagation of freezing fronts that occur in the model to observations from the Greenland Ice Sheet. We show that the model applies to both accumulation and ablation areas and allows for a transition between the two as the surface energy forcing varies. The largest average firn temperatures occur at intermediate values of the surface forcing when perennial water storage is predicted.

  16. Simulations of the effects of U.S. Highway 231 and the proposed Montgomery outer loop on flooding in the Catoma Creek and Little Catoma Creek Basins near Montgomery, Alabama

    USGS Publications Warehouse

    Hedgecock, T. Scott

    1999-01-01

    A two-dimensional finite-element surface-water model was used to study the effects of U.S. Highway 231 and the proposed Montgomery Outer Loop on the water-surface elevations and flow distributions during flooding in the Catoma Creek and Little Catoma Creek Basins southeast of Montgomery, Montgomery County, Alabama. The effects of flooding were simulated for two scenarios--existing and proposed conditions--for the 100- and 500-year recurrence intervals. The first scenario was to model the existing bridge and highway configuration for U.S. Highway 231 and the existing ponds that lie just upstream from this crossing. The second scenario was to model the proposed bridge and highway configuration for the Montgomery Outer Loop and the Montgomery Loop Interchange at U.S. Highway 231 as well as the proposed modifications to the ponds upstream. Simulation of floodflow for Little Catoma Creek for the existing conditions at U.S. Highway 231 indicates that, for the 100-year flood, 54 percent of the flow (8,140 cubic feet per second) was conveyed by the northernmost bridge, 21 percent (3,130 cubic feet per second) by the middle bridge, and 25 percent (3,780 cubic feet per second) by the southernmost bridge. No overtopping of U.S. Highway 231 occurred. However, the levees of the catfish ponds immediately upstream from the crossing were completely overtopped. The average water- surface elevations for the 100-year flood at the upstream limits of the study reach for Catoma Creek and Little Catoma Creek were 216.9 and 218.3 feet, respectively. For the 500-year flood, the simulatin indicates that 51 percent of the flow (11,200 cubic feet per second) was conveyed by the northernmost bridge, 25 percent (5,480 cubic feet per second) by the middle bridge, and 24 percent (5,120 cubic feet per second) by the southernmost bridge. The average water0surface elevations for the 500-year flood at the upstream limits of the study reach for Catoma Creek and Little Catoma Creek were 218.2 and 219.5 feet, respectively. For the 500-year flood, no overtopping of U.S. Highway 231 occurred. Simulation of the 100-year floodflow for Little Catoma Creek for the proposed conditions indicates that, for the existing bridges on U.S. Highway 231, 54 percent of the flow (8,190 cubic feet per second) was conveyed by the northernmost bridge, 22 percent (3,350 cubic feet per second) by the middle bridge, and 24 percent (3,490 cubic feet per second) by the southernmost bridge. The two proposed relief bridges on the Montgomery Outer Loop upstream from the proposed remaining catfish ponds conveyed about 7,750 cubic feet per second (3,400 cubic feet per second for the west relief bridge and 4,350 cubic feet per second for the east relief bridge) with an average depth of flow of about 7 feet. The average water-surface elevation at the upstream limit of the study reach for Little Catoma Creek was 218.8 feet, which is about 0.5 foot higher than the average water-surface elevation for the existing conditions. For the 100-year flood, there was no overtopping of either U.S. Highway 231 or the Montgomery Outer Loop. However, the levees of the proposed remaining catfish ponds were completely overtopped. For the Montgomery Outer Loop crossing of Catoma Creek, simulation of the 100-year floodflow indicates that about 58 percent of the flow (14,100 cubic feet per second) was conveyed by the proposed main channel bridge and 42 percent (10,200 cubic feet per second) by the proposed relief bridge. The average water-surface elevation at the upstream limit of the study reach for Catoma Creek was 216.9 feet, which is the same as the water-surface elevation for the existing conditions. Results of model simulations for the 500-year flood for the proposed conditions indicate that there was no overtopping on either U.S. Highway 231 or the Montgomery Outer Loop. For the existing bridges on U.S. Highway 231, 42 percent of the flow (11,300 cubic feet per second) was conveyed by the northernmost bridge

  17. Groundwater-surface water interactions across scales in a boreal landscape investigated using a numerical modelling approach

    NASA Astrophysics Data System (ADS)

    Jutebring Sterte, Elin; Johansson, Emma; Sjöberg, Ylva; Huseby Karlsen, Reinert; Laudon, Hjalmar

    2018-05-01

    Groundwater and surface-water interactions are regulated by catchment characteristics and complex inter- and intra-annual variations in climatic conditions that are not yet fully understood. Our objective was to investigate the influence of catchment characteristics and freeze-thaw processes on surface and groundwater interactions in a boreal landscape, the Krycklan catchment in Sweden. We used a numerical modelling approach and sub-catchment evaluation method to identify and evaluate fundamental catchment characteristics and processes. The model reproduced observed stream discharge patterns of the 14 sub-catchments and the dynamics of the 15 groundwater wells with an average accumulated discharge error of 1% (15% standard deviation) and an average groundwater-level mean error of 0.1 m (0.23 m standard deviation). We show how peatland characteristics dampen the effect of intense rain, and how soil freeze-thaw processes regulate surface and groundwater partitioning during snowmelt. With these results, we demonstrate the importance of defining, understanding and quantifying the role of landscape heterogeneity and sub-catchment characteristics for accurately representing catchment hydrological functioning.

  18. Water resources of Parowan Valley, Iron County, Utah

    USGS Publications Warehouse

    Marston, Thomas M.

    2017-08-29

    Parowan Valley, in Iron County, Utah, covers about 160 square miles west of the Red Cliffs and includes the towns of Parowan, Paragonah, and Summit. The valley is a structural depression formed by northwest-trending faults and is, essentially, a closed surface-water basin although a small part of the valley at the southwestern end drains into the adjacent Cedar Valley. Groundwater occurs in and has been developed mainly from the unconsolidated basin-fill aquifer. Long-term downward trends in groundwater levels have been documented by the U.S. Geological Survey (USGS) since the mid-1950s. The water resources of Parowan Valley were assessed during 2012 to 2014 with an emphasis on refining the understanding of the groundwater and surface-water systems and updating the groundwater budget.Surface-water discharge of five perennial mountain streams that enter Parowan Valley was measured from 2013 to 2014. The total annual surface-water discharge of the five streams during 2013 to 2014 was about 18,000 acre-feet (acre-ft) compared to the average annual streamflow of about 22,000 acre-ft from USGS streamgages operated on the three largest of these streams from the 1940s to the 1980s. The largest stream, Parowan Creek, contributes more than 50 percent of the annual surface-water discharge to the valley, with smaller amounts contributed by Red, Summit, Little, and Cottonwood Creeks.Average annual recharge to the Parowan Valley groundwater system was estimated to be about 25,000 acre-ft from 1994 to 2013. Nearly all recharge occurs as direct infiltration of snowmelt and rainfall on the Markagunt Plateau east of the valley. Smaller amounts of recharge occur as infiltration of streamflow and unconsumed irrigation water near the east side of the valley on alluvial fans associated with mountain streams at the foot of the Red Cliffs. Subsurface flow from the mountain block to the east of the valley is a significant source of groundwater recharge to the basin-fill aquifer. Groundwater flows from the high-altitude recharge areas downward toward the basin-fill aquifer in Parowan Valley. Almost all groundwater discharge occurs as withdrawals from irrigation wells in the valley with a small amount of discharge from phreatophytic evapotranspiration. Subsurface groundwater discharge to Cedar Valley is likely minimal. Withdrawals from wells during 2013 were about 32,000 acre-ft. The estimated withdrawals from wells from 1994 to 2013 have ranged from 22,000 to 39,000 acre-ft per year. Declining water levels are an indication of the estimated average annual decrease in groundwater storage of 15,000 acre-ft from 1994 to 2013.Groundwater and surface-water samples were collected from 46 sites in Parowan Valley and Cedar Valley near the town of Enoch during June 2013. Groundwater samples from 34 wells were submitted for geochemical analysis. The total dissolved-solids concentration in water from these wells ranged from 142 to 886 milligrams per liter. Results of stable isotope analysis of oxygen and deuterium from groundwater and surface-water samples indicate that most of the groundwater in Parowan Valley and in Cedar Valley near Enoch is similar in isotopic composition to water from mountain streams, which reflects meteoric water recharged in high-altitude areas east of the valley. In addition, results of stable isotope analysis of a subset of samples from wells located near Little Salt Lake may indicate recharge of precipitation that occurred during cooler climatic conditions of the Pleistocene Epoch.

  19. [Surface water quality assessment in Miyun reservoir watershed, Beijing in the period 1980-2003].

    PubMed

    Zhang, Wei-wei; Sun, Dan-feng; Li, Hong; Zhou, Lian-di

    2010-07-01

    Single factor water quality identification index was adopted to assess the surface water quality of Miyun reservoir watershed in Beijing using nearly 20 years monitoring data of 4 sites, also the surface water quality pollution sources were analyzed. The results indicated TP had the largest temporal variation at every monitoring site, coefficients of variation were 93.86%, 86.08%, 50.56% and 139.47%, respectively. The following element was Hg, the coefficients of its variation were 86.08%, 25.75%, 56.52% and 47.01%, respectively. While TN, permanganate index, BOD5, Pb and Cr were relatively stable with small coefficient of temporal variation. The permanganate index, BOD5, Pb and Cr did not exceed to the Chinese surface drinking water standard limit in the study period, while Hg had high pollution risk in several years, such as monitoring sites S1 and S3 in 1992, monitoring sites S4 in 1996. The major pollutants of Miyun reservoir watershed in Beijing were TN and TP, and TN had larger pollution risk compared with TP in most years. Comparing to that before the 1990s, the decade average fertilizer, pesticide and agricultural plastic mulch inputs after the 1990s had increased by 46%, 173% and 359%, respectively. The husbandry proportion in agriculture rose from 24.4% to 39.8%, and the average gross industrial production by 424%. The upstream of Miyun reservoir had larger pollution risk than its downstream. In addition, Chaohe watershed contributed more TN and TP to the reservoir than Baihe watershed.

  20. Thermal effects on electronic properties of CO/Pt(111) in water.

    PubMed

    Duan, Sai; Xu, Xin; Luo, Yi; Hermansson, Kersti; Tian, Zhong-Qun

    2013-08-28

    Structure and adsorption energy of carbon monoxide molecules adsorbed on the Pt(111) surfaces with various CO coverages in water as well as work function of the whole systems at room temperature of 298 K were studied by means of a hybrid method that combines classical molecular dynamics and density functional theory. We found that when the coverage of CO is around half monolayer, i.e. 50%, there is no obvious peak of the oxygen density profile appearing in the first water layer. This result reveals that, in this case, the external force applied to water molecules from the CO/Pt(111) surface almost vanishes as a result of the competitive adsorption between CO and water molecules on the Pt(111) surface. This coverage is also the critical point of the wetting/non-wetting conditions for the CO/Pt(111) surface. Averaged work function and adsorption energy from current simulations are consistent with those of previous studies, which show that thermal average is required for direct comparisons between theoretical predictions and experimental measurements. Meanwhile, the statistical behaviors of work function and adsorption energy at room temperature have also been calculated. The standard errors of the calculated work function for the water-CO/Pt(111) interfaces are around 0.6 eV at all CO coverages, while the standard error decreases from 1.29 to 0.05 eV as the CO coverage increases from 4% to 100% for the calculated adsorption energy. Moreover, the critical points for these electronic properties are the same as those for the wetting/non-wetting conditions. These findings provide a better understanding about the interfacial structure under specific adsorption conditions, which can have important applications on the structure of electric double layers and therefore offer a useful perspective for the design of the electrochemical catalysts.

  1. A comparative study on carbon, boron-nitride, boron-phosphide and silicon-carbide nanotubes based on surface electrostatic potentials and average local ionization energies.

    PubMed

    Esrafili, Mehdi D; Behzadi, Hadi

    2013-06-01

    A density functional theory study was carried out to predict the electrostatic potentials as well as average local ionization energies on both the outer and the inner surfaces of carbon, boron-nitride (BN), boron-phosphide (BP) and silicon-carbide (SiC) single-walled nanotubes. For each nanotube, the effect of tube radius on the surface potentials and calculated average local ionization energies was investigated. It is found that SiC and BN nanotubes have much stronger and more variable surface potentials than do carbon and BP nanotubes. For the SiC, BN and BP nanotubes, there are characteristic patterns of positive and negative sites on the outer lateral surfaces. On the other hand, a general feature of all of the systems studied is that stronger potentials are associated with regions of higher curvature. According to the evaluated surface electrostatic potentials, it is concluded that, for the narrowest tubes, the water solubility of BN tubes is slightly greater than that of SiC followed by carbon and BP nanotubes.

  2. Water balance-based estimation of groundwater recharge in the Lake Chad Basin

    NASA Astrophysics Data System (ADS)

    Babamaaji, R. A.; Lee, J.

    2012-12-01

    Lake Chad Basin (LCB) has experienced drastic changes of land cover and poor water management practices during the last 50 years. The successive droughts in the 1970s and 1980s resulted in the shortage of surface water and groundwater resources. This problem of drought and shortage of water has a devastating implication on the natural resources of the Basin with great consequence on food security, poverty reduction and quality of life of the inhabitants in the LCB. Therefore, understanding the change of land use and its characteristics must be a first step to find how such changes disturb the water cycle especially the groundwater in the LCB. The abundance of groundwater is affected by the climate change through the interaction with surface water, such as lakes and rivers, and vertical recharge through an infiltration process. Quantifying the impact of climate change on the groundwater resource requires not only reliable forecasting of changes in the major climatic variables, but also accurate estimation of groundwater recharge. Spatial variations in the land use/land cover, soil texture, topographic slope, and meteorological conditions should be accounted for in the recharge estimation. In this study, we employed a spatially distributed water balance model WetSpass to simulate a long-term average change of groundwater recharge in the LCB of Africa. WetSpass is a water balance-based model to estimate seasonal average spatial distribution of surface runoff, evapotranspiration, and groundwater recharge. The model is especially suitable for studying the effect of land use/land cover change on the water regime in the LCB. The present study describes the concept of the model and its application to the development of recharge map of the LCB.

  3. Monsoon-induced changes in the size-fractionated phytoplankton biomass and production rate in the estuarine and coastal waters of southwest coast of India.

    PubMed

    Madhu, N V; Jyothibabu, R; Balachandran, K K

    2010-07-01

    Changes in the autotrophic pico- (0.2-2 microm), nano- (2-20 microm), and microplankton (>20 microm) biomass (chlorophyll a) and primary production were measured in the estuarine and coastal waters off Cochin, southwest coast of India during the onset and establishment of a monsoon. During this period, the estuary was dominated by nutrient-rich freshwater, whereas the coastal waters were characterized with higher salinity values (>30 psu) and less nutrients. The average surface chlorophyll a concentrations and primary production rates were higher in the estuary (average 13.7 mg m(-3) and 432 mgC m(-3) day(-1)) as compared to the coastal waters (5.3 mg m(-3) and 224 mgC m(-3) day(-1)). The nanoplankton community formed the major fraction of chlorophyll a and primary production, both in the estuary (average 85 +/- SD 8.3% and 81.2 +/- SD 3.2%) and the coastal waters (average 73.2 +/- SD 17.2% and 81.9 +/- 15.7%). Nanoplankton had the maximum photosynthetic efficiency in the coastal waters (average 4.8 +/- SD 3.9 mgC mgChl a m(-3) h(-1)), whereas in the estuary, the microplankton had higher photosynthetic efficiency (average 7.4 +/- 7 mgC mgChl a m(-3) h(-1)). The heavy cloud cover and increased water column turbidity not only limit the growth of large-sized phytoplankton in the Cochin estuary and coastal waters but also support the proliferation of nanoplankton community during the monsoon season, even though large variation in nanoplankton chlorophyll a and production exists between these two areas.

  4. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dorsey, Alison; Dudley, Colton; Louie, John

    Linear deposits of calcium carbonate tufa columns mark recent faults that cut 11 ka Lake Lahontan sediments at Astor Pass, north of Pyramid Lake, Nevada. Throughout the Great Basin, faults appear to control the location of geothermal resources by providing pathways for fluid migration. Reservoir-depth (greater than 1 km) seismic imaging at Astor Pass reveals a fault that projects to one of the lines of tufa columns at the surface. The presence of the tufa deposits suggests this fault carried warm geothermal waters through the lakebed clay sediments in recent time. The warm fluids deposited the tufa when they hitmore » cold Lake Lahontan water at the lakebed. Lake Lahontan covered this location 11 ka to a depth of at least 60 m. In collaboration with the Pyramid Lake Paiute Tribe, an Applied Geophysics class at UNR investigated the near-surface geophysical characteristics of this fault. The survey at and near the tufa columns comprises near-surface Pwave seismic reflection and refraction, electrical resistivity tomography, nearsurface refraction microtremor arrays, nine near-surface direct-current resistivity soundings, magnetic surveys, and gravity surveys. The refraction microtremor results show shear velocities near tufa and faults to be marginally lower, compared to Vs away from the faults. Overall, the 30-m depth-averaged shear velocities are low, less than 300 m/s, consistent with the lakebed clay deposits. These results indicate that no seismically fast (> 500 m/s) tufa deposits are present below the surface at or near the tufa columns. Vs30 averages were for example 274 ± 13 m/s on the fault, 287 ± 2 m/s at 150 m east of the fault, and 290 ± 15 m/s at 150 m west of the fault. The P-velocity refraction optimization results similarly indicate a lack of high-velocity tufa buried below the surface in the Lahontan sediments, reinforcing the idea that all tufa was deposited above the lakebed surface. The seismic results provide a negative test of the hypothesis that deposition of the lakebeds in the Quaternary buried and preserved older tufa columns within the section. Near-surface Wenner arrays with a-spacings up to 30 m show a higher resistivity near the faults, and tufa, than away from the faults. Resistivity averages within a few meters of the surface were 33 ± 17 ohm-m on the fault, 13 ± 3 ohm-m east of the fault, and 9 ± 3 ohm-m west of the fault. It is possible that the geothermal waters are fresher, and more resistive, than waters held in the lakebed clays. Water samples from more than 1 km depth in exploration wells have a TDS of 2500 p.p.m., nearly drinking-water quality. The relatively resistive water, perhaps localized by greater permeability along the fault, could explain the higher resistivity measured near the fault. The results show that there is no high-velocity, high-resistivity tufa along the faults below the surface, so we are unable to use buried tufa to locate the faults that may promote geothermal upwelling in this area. We further hypothesize that as sedimentation buried the tufa during the Quaternary, warm geothermal waters re-dissolved it, and re-precipitated it in the cold lake-bottom water.« less

  5. Experimental investigation of time and repeated cycles in nucleate pool boiling of alumina/water nanofluid on polished and machined surfaces

    NASA Astrophysics Data System (ADS)

    Rajabzadeh Dareh, F.; Haghshenasfard, M.; Nasr Esfahany, M.; Salimi Jazi, H.

    2018-06-01

    Pool boiling heat transfer of pure water and nanofluids on a copper block has been studied experimentally. Nanofluids with various concentrations of 0.0025, 0.005 and 0.01 vol.% are employed and two simple surfaces (polished and machined copper surface) are used as the heating surfaces. The results indicated that the critical heat flux (CHF) in boiling of fluids on the polished surface is 7% higher than CHF on the machined surface. In the case of machined surface, the heat transfer coefficient (HTC) of 0.01 vol.% nanofluid is about 37% higher than HTC of base fluid, while in the polished surface the average HTC of 0.01% nanofluid is about 19% lower than HTC of the pure water. The results also showed that the boiling time and boiling cycles on the polished surface changes the heat transfer performance. By increasing the boiling time from 5 to 10 min, the roughness enhances about 150%, but by increasing the boiling time to 15 min, the roughness enhancement is only 8%.

  6. Geographic, geologic, and hydrologic summaries of intermontane basins of the northern Rocky Mountains, Montana

    USGS Publications Warehouse

    Kendy, Eloise; Tresch, R.E.

    1996-01-01

    This report combines a literature review with new information to provide summaries of the geography, geology, and hydrology of each of 32 intermontane basins in western Montana. The summary of each intermontane basin includes concise descriptions of topography, areal extent, altitude, climate, 1990 population, land and water use, geology, surface water, aquifer hydraulic characteristics, ground-water flow, and ground-water quality. If present, geothermal features are described. Average annual and monthly temperature and precipitation are reported from one National Weather Service station in each basin. Streamflow data, including the drainage area, period of record, and average, minimum, and maximum historical streamflow, are reported for all active and discontinued USGS streamflow-gaging stations in each basin. Monitoring-well data, including the well depth, aquifer, period of record, and minimum and maximum historical water levels, are reported for all long-term USGS monitoring wells in each basin. Brief descriptions of geologic, geophysical, and potentiometric- surface maps available for each basin also are included. The summary for each basin also includes a bibliography of hydrogeologic literature. When used alone or in conjunction with regional RASA reports, this report provides a practical starting point for site-specific hydrogeologic investigations.

  7. Modeling the Thickness of Perennial Ice Covers on Stratified Lakes of the Taylor Valley, Antarctica

    NASA Technical Reports Server (NTRS)

    Obryk, M. K.; Doran, P. T.; Hicks, J. A.; McKay, C. P.; Priscu, J. C.

    2016-01-01

    A one-dimensional ice cover model was developed to predict and constrain drivers of long term ice thickness trends in chemically stratified lakes of Taylor Valley, Antarctica. The model is driven by surface radiative heat fluxes and heat fluxes from the underlying water column. The model successfully reproduced 16 years (between 1996 and 2012) of ice thickness changes for west lobe of Lake Bonney (average ice thickness = 3.53 m; RMSE = 0.09 m, n = 118) and Lake Fryxell (average ice thickness = 4.22 m; RMSE = 0.21 m, n = 128). Long-term ice thickness trends require coupling with the thermal structure of the water column. The heat stored within the temperature maximum of lakes exceeding a liquid water column depth of 20 m can either impede or facilitate ice thickness change depending on the predominant climatic trend (temperature cooling or warming). As such, shallow (< 20 m deep water columns) perennially ice-covered lakes without deep temperature maxima are more sensitive indicators of climate change. The long-term ice thickness trends are a result of surface energy flux and heat flux from the deep temperature maximum in the water column, the latter of which results from absorbed solar radiation.

  8. Prevalence and characteristics of ESBL-producing E. coli in Dutch recreational waters influenced by wastewater treatment plants.

    PubMed

    Blaak, Hetty; de Kruijf, Patrick; Hamidjaja, Raditijo A; van Hoek, Angela H A M; de Roda Husman, Ana Maria; Schets, Franciska M

    2014-07-16

    Outside health care settings, people may acquire ESBL-producing bacteria through different exposure routes, including contact with human or animal carriers or consumption of contaminated food. However, contact with faecally contaminated surface water may also represent a possible exposure route. The current study investigated the prevalence and characteristics of ESBL-producing Escherichia coli in four Dutch recreational waters and the possible role of nearby waste water treatment plants (WWTP) as contamination source. Isolates from recreational waters were compared with isolates from WWTP effluents, from surface water upstream of the WWTPs, at WWTP discharge points, and in connecting water bodies not influenced by the studied WWTPs. ESBL-producing E. coli were detected in all four recreational waters, with an average concentration of 1.3 colony forming units/100ml, and in 62% of all samples. In surface waters not influenced by the studied WWTPs, ESBL-producing E. coli were detected in similar concentrations, indicating the existence of additional ESBL-E. coli contamination sources. Isolates with identical ESBL-genes, phylogenetic background, antibiotic resistance profiles, and sequence type, were obtained from effluent and different surface water sites in the same watershed, on the same day; occasionally this included isolates from recreational waters. Recreational waters were identified as a potential exposure source of ESBL-producing E. coli. WWTPs were shown to contribute to the presence of these bacteria in surface waters, but other (yet unidentified) sources likely co-contribute. Copyright © 2014 Elsevier B.V. All rights reserved.

  9. The integration of constructed wetlands into a treatment system for airport runoff.

    PubMed

    Revitt, D M; Worral, P; Brewer, D

    2001-01-01

    A new surface runoff treatment system has been designed for London Heathrow Airport, which incorporates separate floating constructed wetlands or reedbeds and sub-surface flow constructed wetlands as major pollutant removal systems. The primary requirement of the newly developed treatment system is to control the concentrations of glycols following their use as de-icers and anti-icers within the airport. The ability of reedbeds to contribute to this treatment role was fully tested through pilot scale, on-site experiments over a 2 year period. The average reductions in runoff BOD concentrations achieved by pilot scale surface flow and sub-surface flow reedbeds were 30.9% and 32.9%, respectively. The corresponding average glycol removal efficiencies were 54.2% and 78.3%, following shock dosing inputs. These treatment performances are used to predict the required full scale constructed wetland surface areas needed to attain the desired effluent water quality. The treatment system also incorporates aeration, storage and, combined with reedbed technology, has been designed to reduce a mixed inlet BOD concentration of 240 mg/l to less than 40 mg/l for water temperatures varying between 6 degrees C and 20 degrees C.

  10. Surface Freshwater Storage and Variability in the Amazon Basin from Multi-Satellite Observations, 1993-2007

    NASA Technical Reports Server (NTRS)

    Papa, Fabrice; Frappart, Frederic; Guntner, Andreas; Prigent, Catherine; Aires, Filipe; Getirana, Augusto; Maurer, Raffael

    2013-01-01

    The amount of water stored and moving through the surface water bodies of large river basins (river, floodplains, wetlands) plays a major role in the global water and biochemical cycles and is a critical parameter for water resources management. However, the spatio-temporal variations of these freshwater reservoirs are still widely unknown at the global scale. Here, we propose a hypsographic curve approach to estimate surface freshwater storage variations over the Amazon basin combining surface water extent from a multi-satellite-technique with topographic data from the Global Digital Elevation Model (GDEM) from Advance Spaceborne Thermal Emission and Reflection Radiometer (ASTER). Monthly surface water storage variations for 1993-2007 are presented, showing a strong seasonal and interannual variability, and are evaluated against in situ river discharge and precipitation. The basin-scale mean annual amplitude of approx. 1200 cu km is in the range of previous estimates and contributes to about half of the Gravity Recovery And Climate Experiment (GRACE) total water storage variations. For the first time, we map the surface water volume anomaly during the extreme droughts of 1997 (October-November) and 2005 (September-October) and found that during these dry events the water stored in the river and flood-plains of the Amazon basin was, respectively, approx. 230 (approx. 40%) and 210 (approx. 50%) cu km below the 1993-2007 average. This new 15year data set of surface water volume represents an unprecedented source of information for future hydrological or climate modeling of the Amazon. It is also a first step toward the development of such database at the global scale.

  11. [Spatial Distribution Characteristics of Different Species Mercury in Water Body of Changshou Lake in Three Gorges Reservoir Region].

    PubMed

    Bai, Wei-yang; Zhang, Cheng; Zhao, Zheng; Tang, Zhen-ya; Wang, Ding-yong

    2015-08-01

    An investigation on the concentrations and the spatial distribution characteristics of different species of mercury in the water body of Changshou Lake in Three Gorges Reservoir region was carried out based on the AreGIS statistics module. The results showed that the concentration of the total mercury in Changshou Lake surface water ranged from 0.50 to 3.78 ng x L(-1), with an average of 1.51 ng x L(-1); the concentration of the total MeHg (methylmercury) ranged from 0.10 to 0.75 ng x L(-1), with an average of 0.23 ng x L(-1). The nugget effect value of total mercury in surface water (50.65%), dissolved mercury (49.80%), particulate mercury (29.94%) and the activity mercury (26.95%) were moderate spatial autocorrelation. It indicated that the autocorrelation was impacted by the intrinsic properties of sediments (such as parent materials and rocks, geological mineral and terrain), and on the other hand it was also disturbed by the exogenous input factors (such as aquaculture, industrial activities, farming etc). The nugget effect value of dissolved methylmercury (DMeHg) in Changshou lake surface water (3.49%) was less than 25%, showing significant strong spatial autocorrelation. The distribution was mainly controlled by environmental factors in water. The proportion of total MeHg in total Hg in Changshou Lake water reached 30% which was the maximum ratio of the total MeHg to total Hg in freshwater lakes and rivers. It implied that mercury was easily methylated in the environment of Chanashou Lake.

  12. The importance of base flow in sustaining surface water flow in the Upper Colorado River Basin

    USGS Publications Warehouse

    Miller, Matthew P.; Buto, Susan G.; Susong, David D.; Rumsey, Christine

    2016-01-01

    The Colorado River has been identified as the most overallocated river in the world. Considering predicted future imbalances between water supply and demand and the growing recognition that base flow (a proxy for groundwater discharge to streams) is critical for sustaining flow in streams and rivers, there is a need to develop methods to better quantify present-day base flow across large regions. We adapted and applied the spatially referenced regression on watershed attributes (SPARROW) water quality model to assess the spatial distribution of base flow, the fraction of streamflow supported by base flow, and estimates of and potential processes contributing to the amount of base flow that is lost during in-stream transport in the Upper Colorado River Basin (UCRB). On average, 56% of the streamflow in the UCRB originated as base flow, and precipitation was identified as the dominant driver of spatial variability in base flow at the scale of the UCRB, with the majority of base flow discharge to streams occurring in upper elevation watersheds. The model estimates an average of 1.8 × 1010 m3/yr of base flow in the UCRB; greater than 80% of which is lost during in-stream transport to the Lower Colorado River Basin via processes including evapotranspiration and water diversion for irrigation. Our results indicate that surface waters in the Colorado River Basin are dependent on base flow, and that management approaches that consider groundwater and surface water as a joint resource will be needed to effectively manage current and future water resources in the Basin.

  13. The importance of base flow in sustaining surface water flow in the Upper Colorado River Basin

    NASA Astrophysics Data System (ADS)

    Miller, Matthew P.; Buto, Susan G.; Susong, David D.; Rumsey, Christine A.

    2016-05-01

    The Colorado River has been identified as the most overallocated river in the world. Considering predicted future imbalances between water supply and demand and the growing recognition that base flow (a proxy for groundwater discharge to streams) is critical for sustaining flow in streams and rivers, there is a need to develop methods to better quantify present-day base flow across large regions. We adapted and applied the spatially referenced regression on watershed attributes (SPARROW) water quality model to assess the spatial distribution of base flow, the fraction of streamflow supported by base flow, and estimates of and potential processes contributing to the amount of base flow that is lost during in-stream transport in the Upper Colorado River Basin (UCRB). On average, 56% of the streamflow in the UCRB originated as base flow, and precipitation was identified as the dominant driver of spatial variability in base flow at the scale of the UCRB, with the majority of base flow discharge to streams occurring in upper elevation watersheds. The model estimates an average of 1.8 × 1010 m3/yr of base flow in the UCRB; greater than 80% of which is lost during in-stream transport to the Lower Colorado River Basin via processes including evapotranspiration and water diversion for irrigation. Our results indicate that surface waters in the Colorado River Basin are dependent on base flow, and that management approaches that consider groundwater and surface water as a joint resource will be needed to effectively manage current and future water resources in the Basin.

  14. The distribution of water frost on Charon

    NASA Technical Reports Server (NTRS)

    Buie, Marc W.; Shriver, Scott K.

    1994-01-01

    We present high-spatial-resolution imaging observations of the Pluto-Charon system taken with ProtoCAM on the Infrared Telescope Facility (IRTF). Our dataset consists of measurements from eight nights at widely separated rotational longitudes and covering five wavelengths -- standard J, H, and K, plus two special narrow band filters at 1.5 and 1.75 microns. The relative flux contributions of Pluto and Charon were extracted, when possible, by fitting a two-source Gaussian image model to the observed images. At K, we find the Charon-Pluto magnitude difference to be on average 1.8 mag, somewhat less than the value of 2.2 mag found by Bosh et al. (1992). The average differential magnitude at 1.5 and 1.75 microns is 2.0 and 1.6, respectively. The larger magnitude difference at 1.5 microns is due to a water-frost absorption band on the surface of Charon. Our observations are consistent with a surface of Charon dominated by water frost at all longitudes.

  15. The mean and turbulent flow structure of a weak hydraulic jump

    NASA Astrophysics Data System (ADS)

    Misra, S. K.; Kirby, J. T.; Brocchini, M.; Veron, F.; Thomas, M.; Kambhamettu, C.

    2008-03-01

    The turbulent air-water interface and flow structure of a weak, turbulent hydraulic jump are analyzed in detail using particle image velocimetry measurements. The study is motivated by the need to understand the detailed dynamics of turbulence generated in steady spilling breakers and the relative importance of the reverse-flow and breaker shear layer regions with attention to their topology, mean flow, and turbulence structure. The intermittency factor derived from turbulent fluctuations of the air-water interface in the breaker region is found to fit theoretical distributions of turbulent interfaces well. A conditional averaging technique is used to calculate ensemble-averaged properties of the flow. The computed mean velocity field accurately satisfies mass conservation. A thin, curved shear layer oriented parallel to the surface is responsible for most of the turbulence production with the turbulence intensity decaying rapidly away from the toe of the breaker (location of largest surface curvature) with both increasing depth and downstream distance. The reverse-flow region, localized about the ensemble-averaged free surface, is characterized by a weak downslope mean flow and entrainment of water from below. The Reynolds shear stress is negative in the breaker shear layer, which shows that momentum diffuses upward into the shear layer from the flow underneath, and it is positive just below the mean surface indicating a downward flux of momentum from the reverse-flow region into the shear layer. The turbulence structure of the breaker shear layer resembles that of a mixing layer originating from the toe of the breaker, and the streamwise variations of the length scale and growth rate are found to be in good agreement with observed values in typical mixing layers. All evidence suggests that breaking is driven by a surface-parallel adverse pressure gradient and a streamwise flow deceleration at the toe of the breaker. Both effects force the shear layer to thicken rapidly, thereby inducing a sharp free surface curvature change at the toe.

  16. Methodology for Outdoor Water Savings Model and Spreadsheet Tool for U.S. and Selected States

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Williams, Alison A.; Chen, Yuting; Dunham, Camilla

    Green lawns and landscaping are archetypical of the populated American landscape, and typically require irrigation, which corresponds to a significant fraction of residential, commercial, and institutional water use. In North American cities, the estimated portion of residential water used for outdoor purposes ranges from 22-38% in cooler climates up to 59-67% in dry and hot environments, while turfgrass coverage within the United States spans 11.1-20.2 million hectares (Milesi et al. 2009). One national estimate uses satellite and aerial photography data to develop a relationship between impervious surface and lawn surface area, yielding a conservative estimate of 16.4 (± 3.6) millionmore » hectares of lawn surface area in the United States—an area three times larger than that devoted to any irrigated crop (Milesi et al. 2005). One approach that holds promise for cutting unnecessary outdoor water use is the increased deployment of “smart” irrigation controllers to increase the water efficiency of irrigation systems. This report describes the methodology and inputs employed in a mathematical model that quantifies the effects of the U.S. Environmental Protection Agency’s WaterSense labeling program for one such type of controller, weather-based irrigation controllers (WBIC). This model builds off that described in “Methodology for National Water Savings Model and Spreadsheet Tool–Outdoor Water Use” and uses a two-tiered approach to quantify outdoor water savings attributable to the WaterSense program for WBIC, as well as net present value (NPV) of that savings. While the first iteration of the model assessed national impacts using averaged national values, this version begins by evaluating impacts in three key large states that make up a sizable portion of the irrigation market: California, Florida, and Texas. These states are considered to be the principal market of “smart” irrigation controllers that may result in the bulk of national savings. Modeled water savings and net present value for these three states should be more accurate and representative than the averaged national values given state-specific inputs such as lot size, water price, and housing stock. To complete the picture of national impacts, the remaining WBIC shipments not assigned to these three states are assessed using the original methodology based on the averaged national values.« less

  17. Remote sensing monitoring study of ecological environment change in Qingtu Lake

    NASA Astrophysics Data System (ADS)

    Han, Tao; Wang, Dawei; Jiang, Youyan; Qian, Li; Chen, Lei; Hao, Xiaocui

    2018-03-01

    Based on the Environmental Mitigation Satellite (HJ-1) data, this paper has carried on the remote sensing monitoring to change of the surrounding vegetation and water area of the Qingtu Lake since 2009. The result shows that the average area of water has increased by 3.59 square kilometres annually since the reappearance of the waters with the Qingtu Lake in 2010. The area of Qingtu Lake and surrounding vegetation cover has presented an average increase of 1.09 square kilometres per year. Since 2010, the precipitation of the Qingtu Lake and its surrounding area in Minqin county have a significant increase in the trend, the average increase rate of 6.0 mm/year. Compared to 2010 years ago, the average precipitation increased 36.4 mm. And it shows that the change of the Qingtu Lake underlying surface has a positive feedback effect to local heavy rainfall according to the comparative analysis of the precipitation observation in the surrounding weather station.

  18. Reconnaissance of Surface-Water Quality and Possible Sources of Nutrients and Bacteria in the Turkey Creek Watershed, Northwest Oklahoma, 2002-2003

    USGS Publications Warehouse

    Becker, Carol J.

    2004-01-01

    The U.S. Geological Survey in cooperation with the Oklahoma Department of Environmental Quality and the U.S. Environmental Protection Agency investigated the distribution of surface-water quality and possible sources of nutrients and Escherichia coli bacteria to surface water in Turkey Creek, which flows about 70 miles through mostly rural agricultural areas in northwest Oklahoma. Results show that discharge on the main stem of Turkey Creek increased during low-flow conditions from an average of 5.4 cubic feet per second at the upper most site to 39 cubic feet per second at the lower most site in the watershed, indicating that Turkey Creek gains water from ground-water discharge. A portion of the increase in stream discharge may be from discharges of treated effluent from city sewage lagoons. However, the volume and frequency of discharges are unknown. Surface-water-quality samples show that specific conductance ranged from 1,180 to 1,740 microsiemens per centimeter at 25 degrees Celsius during low-flow conditions and in general, decreased downstream with site 1 or site 2 having the largest measurement and site 5 having the lowest. The pH values were slightly alkaline and ranged from 6.8 to 8.5 with a median of 8.2. Dissolved oxygen ranged from 9.3 to 15.9 milligrams per liter in samples collected in the months of November, February, and March and ranged from 5.3 to 13.9 milligrams per liter in samples collected in the months of June, July, and August. Surface-water-quality samples show that the median concentrations of nitrite plus nitrate as nitrogen (1.16 milligrams per liter) and total phosphorus (0.275 milligram per liter) are larger than the average median concentrations of 0.35 and 0.083 milligram per liter, respectively, calculated from water-quality sites in Oklahoma and part of Arkansas (excluding sites in the Ozark Highland and the Ouachita Mountains ecoregions) having similar stream orders and stream slopes. Concentrations of nitrite plus nitrate as nitrogen increased slightly in the winter months and decreased in the summer months, whereas, concentrations of total phosphorus and orthophosphate as phosphorus tended to increase during the summer months and decrease in the winter months. During high-flow conditions total phosphorus increased 7.7 times above the average concentration of 0.261 milligram per liter in low-flow samples. Orthophosphate concentrations increased 3.5 to 4 times during high-flow conditions. Almost all low-flow samples showed 15N values between 4 and 10 parts per thousand, above the range for atmospheric nitrogen and synthetic fertilizer and below the range for animal waste. These samples may represent a mixture of nitrate from these two sources and other sources enriched with 15N, such as soils and plants. Results of the bacterial source tracking indicated that the two source groups having the greatest number of ribopattern matches with surface-water isolates were the cattle group, 53 isolates or 23.5 percent, and the human group, 41 isolates or 18.2 percent. Fewer surface-water isolates matched the deer and horse groups, 8.0 percent and 3.5 percent, respectively. About 43 percent or 96 surface-water isolates were not matched to any source group.

  19. Investigation of Seepage Meter Measurements in Steady Flow and Wave Conditions.

    PubMed

    Russoniello, Christopher J; Michael, Holly A

    2015-01-01

    Water exchange between surface water and groundwater can modulate or generate ecologically important fluxes of solutes across the sediment-water interface. Seepage meters can directly measure fluid flux, but mechanical resistance and surface water dynamics may lead to inaccurate measurements. Tank experiments were conducted to determine effects of mechanical resistance on measurement efficiency and occurrence of directional asymmetry that could lead to erroneous net flux measurements. Seepage meter efficiency was high (average of 93%) and consistent for inflow and outflow under steady flow conditions. Wave effects on seepage meter measurements were investigated in a wave flume. Seepage meter net flux measurements averaged 0.08 cm/h-greater than the expected net-zero flux, but significantly less than theoretical wave-driven unidirectional discharge or recharge. Calculations of unidirectional flux from pressure measurements (Darcy flux) and theory matched well for a ratio of wave length to water depth less than 5, but not when this ratio was greater. Both were higher than seepage meter measurements of unidirectional flux made with one-way valves. Discharge averaged 23% greater than recharge in both seepage meter measurements and Darcy calculations of unidirectional flux. Removal of the collection bag reduced this net discharge. The presence of a seepage meter reduced the amplitude of pressure signals at the bed and resulted in a nearly uniform pressure distribution beneath the seepage meter. These results show that seepage meters may provide accurate measurements of both discharge and recharge under steady flow conditions and illustrate the potential measurement errors associated with dynamic wave environments. © 2014, National Ground Water Association.

  20. Hydrogeochemical analysis and evaluation of surface water quality of Pratapgarh district, Uttar Pradesh, India

    NASA Astrophysics Data System (ADS)

    Tiwari, Ashwani Kumar; Singh, Abhay Kumar; Singh, Amit Kumar; Singh, M. P.

    2017-07-01

    The hydrogeochemical study of surface water in Pratapgarh district has been carried out to assess the major ion chemistry and water quality for drinking and domestic purposes. For this purpose, twenty-five surface water samples were collected from river, ponds and canals and analysed for pH, electrical conductivity, total dissolved solids (TDS), turbidity, hardness, major cations (Ca2+, Mg2+, Na+ and K+), major anions (HCO3 -, F-, Cl-, NO3 -, SO4 2-) and dissolved silica concentration. The analytical results show mildly acidic to alkaline nature of surface water resources of Pratapgarh district. HCO3 - and Cl- are the dominant anions, while cation chemistry is dominated by Na+ and Ca2+. The statistical analysis and data plotted on the Piper diagram reveals that the surface water chemistry is mainly controlled by rock weathering with secondary contributions from agriculture and anthropogenic sources. Ca2+-Mg2+-HCO3 -, Ca2+-Mg2+-Cl- and Na+-HCO3 --Cl- are the dominant hydrogeochemical facies in the surface water of the area. For quality assessment, values of analysed parameters were compared with Indian and WHO water quality standards, which shows that the concentrations of TDS, F-, NO3 -, Na+, Mg2+ and total hardness are exceeding the desirable limits in some water samples. Water Quality Index (WQI) is one of the most effective tools to communicate information on the quality of any water body. The computed WQI values of Pratapgarh district surface water range from 28 to 198 with an average value of 82, and more than half of the study area is under excellent to good category.

  1. Catchment-scale groundwater recharge and vegetation water use efficiency

    NASA Astrophysics Data System (ADS)

    Troch, P. A. A.; Dwivedi, R.; Liu, T.; Meira, A.; Roy, T.; Valdés-Pineda, R.; Durcik, M.; Arciniega, S.; Brena-Naranjo, J. A.

    2017-12-01

    Precipitation undergoes a two-step partitioning when it falls on the land surface. At the land surface and in the shallow subsurface, rainfall or snowmelt can either runoff as infiltration/saturation excess or quick subsurface flow. The rest will be stored temporarily in the root zone. From the root zone, water can leave the catchment as evapotranspiration or percolate further and recharge deep storage (e.g. fractured bedrock aquifer). Quantifying the average amount of water that recharges deep storage and sustains low flows is extremely challenging, as we lack reliable methods to quantify this flux at the catchment scale. It was recently shown, however, that for semi-arid catchments in Mexico, an index of vegetation water use efficiency, i.e. the Horton index (HI), could predict deep storage dynamics. Here we test this finding using 247 MOPEX catchments across the conterminous US, including energy-limited catchments. Our results show that the observed HI is indeed a reliable predictor of deep storage dynamics in space and time. We further investigate whether the HI can also predict average recharge rates across the conterminous US. We find that the HI can reliably predict the average recharge rate, estimated from the 50th percentile flow of the flow duration curve. Our results compare favorably with estimates of average recharge rates from the US Geological Survey. Previous research has shown that HI can be reliably estimated based on aridity index, mean slope and mean elevation of a catchment (Voepel et al., 2011). We recalibrated Voepel's model and used it to predict the HI for our 247 catchments. We then used these predicted values of the HI to estimate average recharge rates for our catchments, and compared them with those estimated from observed HI. We find that the accuracies of our predictions based on observed and predicted HI are similar. This provides an estimation method of catchment-scale average recharge rates based on easily derived catchment characteristics, such as climate and topography, and free of discharge measurements.

  2. The chemical composition of rivers and snow affected by the 2014/2015 Bárðarbunga eruption, Iceland

    NASA Astrophysics Data System (ADS)

    Galeczka, Iwona; Sigurdsson, Gunnar; Eiriksdottir, Eydis Salome; Oelkers, Eric H.; Gislason, Sigurdur R.

    2016-04-01

    The 2014/15 Bárðarbunga volcanic eruption was the largest in Iceland for more than 200 years. This eruption released into the atmosphere on average 60,000 tonnes/day of SO2, 30,000 tonnes/day of CO2, and 500 tonnes/day of HCl affecting the chemical composition of rain, snow, and surface water. The interaction of these volcanic gases with natural waters, decreases fluid pH and accelerates rock dissolution. This leads to the enhanced release of elements, including toxic metals such as aluminium, to these waters. River monitoring, including spot and continuous osmotic sampling, shows that although the water conductivity was relatively stable during the volcanic unrest, the dissolution of volcanic gases increased the SO4, F, and Cl concentrations of local surface waters by up to two orders of magnitude decreasing the carbon alkalinity. In addition the concentration of SiO2, Ca, Mg, Na and trace metals rose considerably due to the water-molten lava and hot solid lava interaction. The presence of pristine lava and acidic gases increased the average chemical denudation rate, calculated based on Na flux, within Jökulsá á Fjöllum catchment by a factor of two compared to the background flux. Melted snow samples collected at the eruption site were characterised by a strong dependence of the pH on SO4, F and Cl and metal concentrations, indicating that volcanic gases and aerosols acidified the snow. Protons balanced about half of the negatively charged anions; the rest was balanced by water-soluble salts and aerosols containing a variety of metals including Al, Fe, Na, Ca, and Mg. The concentrations of F, Al, Fe, Mn, Cd, Cu, and Pb in the snowmelt water surpassed drinking- and surface water standards. Snowmelt-river water mixing calculations indicate that low alkalinity surface waters, such as numerous salmon rivers in East Iceland, will be more affected by polluted snowmelt waters than high alkalinity spring and glacier fed rivers.

  3. On the relationship between water vapor over the oceans and sea surface temperature

    NASA Technical Reports Server (NTRS)

    Stephens, Graeme L.

    1990-01-01

    Monthly mean precipitable water data obtained from passive microwave radiometry were correlated with the National Meteorological Center (NMC) blended sea surface temperature data. It is shown that the monthly mean water vapor content of the atmosphere above the oceans can generally be prescribed from the sea surface temperature with a standard deviation of 0.36 g/sq cm. The form of the relationship between precipitable water and sea surface temperature in the range T (sub s) greater than 18 C also resembles that predicted from simple arguments based on the Clausius-Clapeyron relationship. The annual cycle of the globally integrated mass of Scanning Multichannel Microwave Radiometer (SMMR) water vapor is shown to differ from analyses of other water vapor data in both phase and amplitude and these differences point to a significant influence of the continents on water vapor. Regional scale analyses of water vapor demonstrate that monthly averaged water vapor data, when contrasted with the bulk sea surface temperature relationship developed in this study, reflect various known characteristics of the time mean large-scale circulation over the oceans. A water vapor parameter is introduced to highlight the effects of large-scale motion on atmospheric water vapor. Based on the magnitude of this parameter, it is shown that the effects of large-scale flow on precipitable water vapor are regionally dependent, but for the most part, the influence of circulation is generally less than about + or - 20 percent of the seasonal mean.

  4. On the relationship between water vapor over the oceans and sea surface temperature

    NASA Technical Reports Server (NTRS)

    Stephens, Graeme L.

    1989-01-01

    Monthly mean precipitable water data obtained from passive microwave radiometry were correlated with the National Meteorological Center (NMC) blended sea surface temperature data. It is shown that the monthly mean water vapor content of the atmosphere above the oceans can generally be prescribed from the sea surface temperature with a standard deviation of 0.36 g/sq cm. The form of the relationship between precipitable water and sea surface temperature in the range T(sub s) greater than 18 C also resembles that predicted from simple arguments based on the Clausius-Clapeyron relationship. The annual cycle of the globally integrated mass of Scanning Multichannel Microwave Radiometer (SMMR) water vapor is shown to differ from analyses of other water vapor data in both phase and amplitude and these differences point to a significant influence of the continents on water vapor. Regional scale analyses of water vapor demonstrate that monthly averaged water vapor data, when contrasted with the bulk sea surface temperature relationship developed in this study, reflect various known characteristics of the time mean large-scale circulation over the oceans. A water vapor parameter is introduced to highlight the effects of large-scale motion on atmospheric water vapor. Based on the magnitude of this parameter, it is shown that the effects of large-scale flow on precipitable water vapor are regionally dependent, but for the most part, the influence of circulation is generally less than about + or - 20 percent of the seasonal mean.

  5. Water balance model for mean annual hydrogen and oxygen isotope distributions in surface waters of the contiguous United States

    NASA Astrophysics Data System (ADS)

    Bowen, Gabriel J.; Kennedy, Casey D.; Liu, Zhongfang; Stalker, Jeremy

    2011-12-01

    The stable H and O isotope composition of river and stream water records information on runoff sources and land-atmosphere water fluxes within the catchment and is a potentially powerful tool for network-based monitoring of ecohydrological systems. Process-based hydrological models, however, have thus far shown limited power to replicate observed large-scale variation in U.S. surface water isotope ratios. Here we develop a geographic information system-based model to predict long-term annual average surface water isotope ratios across the contiguous United States. We use elevation-explicit, gridded precipitation isotope maps as model input and data from a U.S. Geological Survey monitoring program for validation. We find that models incorporating monthly variation in precipitation-evapotranspiration (P-E) amounts account for the majority (>89%) of isotopic variation and have reduced regional bias relative to models that do not consider intra-annual P-E effects on catchment water balance. Residuals from the water balance model exhibit strong spatial patterning and correlations that suggest model residuals isolate additional hydrological signal. We use interpolated model residuals to generate optimized prediction maps for U.S. surface water δ2H and δ18O values. We show that the modeled surface water values represent a relatively accurate and unbiased proxy for drinking water isotope ratios across the United States, making these data products useful in ecological and criminal forensics applications that require estimates of the local environmental water isotope variation across large geographic regions.

  6. The water footprint of humanity

    PubMed Central

    Hoekstra, Arjen Y.; Mekonnen, Mesfin M.

    2012-01-01

    This study quantifies and maps the water footprint (WF) of humanity at a high spatial resolution. It reports on consumptive use of rainwater (green WF) and ground and surface water (blue WF) and volumes of water polluted (gray WF). Water footprints are estimated per nation from both a production and consumption perspective. International virtual water flows are estimated based on trade in agricultural and industrial commodities. The global annual average WF in the period 1996–2005 was 9,087 Gm3/y (74% green, 11% blue, 15% gray). Agricultural production contributes 92%. About one-fifth of the global WF relates to production for export. The total volume of international virtual water flows related to trade in agricultural and industrial products was 2,320 Gm3/y (68% green, 13% blue, 19% gray). The WF of the global average consumer was 1,385 m3/y. The average consumer in the United States has a WF of 2,842 m3/y, whereas the average citizens in China and India have WFs of 1,071 and 1,089 m3/y, respectively. Consumption of cereal products gives the largest contribution to the WF of the average consumer (27%), followed by meat (22%) and milk products (7%). The volume and pattern of consumption and the WF per ton of product of the products consumed are the main factors determining the WF of a consumer. The study illustrates the global dimension of water consumption and pollution by showing that several countries heavily rely on foreign water resources and that many countries have significant impacts on water consumption and pollution elsewhere. PMID:22331890

  7. ESTCP Cost and Performance Report (ER-200742) Open Burn/Open Detonation (OBOD) Area Management Using Lime for Explosives Transformation and Metals Immobilization

    DTIC Science & Technology

    2011-10-01

    vertical transport of water on the APG OD area. ............................................................... 33  Table 5. Runoff water and leachate ...untreated control soil (study average). There was an insignificant change in leachate pH from Day 1 to Day 9 showing that, while the increase was...explosives from OB/OD area soils have occurred through horizontal transport in surface water and vertical leachate water transport. These pathways

  8. Bridge-scour analysis using the water surface profile (WSPRO) model

    USGS Publications Warehouse

    Mueller, David S.; ,

    1993-01-01

    A program was developed to extract hydraulic information required for bridge-scour computations, from the Water-Surface Profile computation model (WSPRO). The program is written in compiled BASIC and is menu driven. Using only ground points, the program can compute average ground elevation, cross-sectional area below a specified datum, or create a Drawing Exchange Format (DXF) fie of cross section. Using both ground points ad hydraulic information form the equal-conveyance tubes computed by WSPRO, the program can compute hydraulic parameters at a user-specified station or in a user-specified subsection of the cross section. The program can identify the maximum velocity in a cross section and the velocity and depth at a user-specified station. The program also can identify the maximum velocity in the cross section and the average velocity, average depth, average ground elevation, width perpendicular to the flow, cross-sectional area of flow, and discharge in a subsection of the cross section. This program does not include any help or suggestions as to what data should be extracted; therefore, the used must understand the scour equations and associated variables to the able to extract the proper information from the WSPRO output.

  9. Nitrogen-isotope analysis of groundwater nitrate in carbonate aquifers: Natural sources versus human pollution

    NASA Astrophysics Data System (ADS)

    Kreitler, Charles W.; Browning, Lawrence A.

    1983-02-01

    Results of nitrogen-isotope analyses of nitrate in the waters of the Cretaceous Edwards aquifer in Texas, U.S.A., indicate that the source of the nitrate is naturally-occurring nitrogen compounds in the recharge streams. In contrast, nitrogen isotopes of nitrate in the fresh waters of the Pleistocene Ironshore Formation on Grand Cayman Island, West Indies, indicate that human wastes are the source of the nitrate. The Cretaceous Edwards Limestone is a prolific aquifer that produces principally from fracture porosity along the Balcones Fault Zone. Recharge is primarily by streams crossing the fault zone. Rainfall is ˜ 70 cm yr. -1, and the water table is generally deeper than 30 m below land surface. The δ15 N of 73 samples of nitrate from Edwards waters ranged from + 1.9 to + 10‰ with an average of + 6.2‰. This δ15 N range is within the range of nitrate in surface water in the recharge streams ( δ 15N range = + 1 to + 8.3‰ ) and within the range of nitrate in surface water from the Colorado River, Texas, ( δ 15N range = + 1 to + 11‰ ). No sample was found to be enriched in 15N, which would suggest the presence of nitrate from animal waste ( δ 15N range = + 10 to + 22‰ ). The Ironshore Formation contains a small freshwater lens that is recharged entirely by percolation through the soil. Average rainfall is 165 cm yr. -1, and the water table is within 3 m of land surface. The δ15 N of four nitrate samples from water samples of the Ironshore Formation ranged from + 18 to + 23.9‰, which indicates a cesspool/septictank source of the nitrate. Limestone aquifers in humid environments that are recharged by percolation through the soil appear to be more susceptible to contamination by septic tanks than are aquifers in subhumid environments that feature thick unsaturated sections and are recharged by streams.

  10. Combustion characteristics of paper and sewage sludge in a pilot-scale fluidized bed.

    PubMed

    Yu, Yong-Ho; Chung, Jinwook

    2015-01-01

    This study characterizes the combustion of paper and sewage sludge in a pilot-scale fluidized bed. The highest temperature during combustion within the system was found at the surface of the fluidized bed. Paper sludge containing roughly 59.8% water was burned without auxiliary fuel, but auxiliary fuel was required to incinerate the sewage sludge, which contained about 79.3% water. The stability of operation was monitored based on the average pressure and the standard deviation of pressure fluctuations. The average pressure at the surface of the fluidized bed decreased as the sludge feed rate increased. However, the standard deviation of pressure fluctuations increased as the sludge feed rate increased. Finally, carbon monoxide (CO) emissions decreased as oxygen content increased in the flue gas, and nitrogen oxide (NOx) emissions were also tied with oxygen content.

  11. Determination of the relative uptake of ground vs. surface water by Populus deltoides during phytoremediation

    USGS Publications Warehouse

    Clinton, B.D.; Vose, J.M.; Vroblesky, D.A.; Harvey, G.J.

    2004-01-01

    The use of plants to remediate polluted groundwater is becoming an attractive alternative to more expensive traditional techniques. In order to adequately assess the effectiveness of the phytoremediation treatment, a clear understanding of water-use habits by the selected plant species is essential. We examined the relative uptake of surface water (i.e., precipitation) vs. groundwater by mature Populus deltoides by applying irrigation water at a rate equivalent to a 5-cm rain event. We used stable isotopes of hydrogen (D) and oxygen (18O) to identify groundwater and surface water (irrigation water) in the xylem sap water. Pretreatment isotopic ratios of both deuterium and 18O, ranked from heaviest to lightest, were irrigation water > groundwater > xylem sap. The discrepancy in preirrigation isotopic signatures between groundwater and xylem sap suggests that in the absence of a surface source of water (i.e., between rain events) there is an unknown amount of water being extracted from sources other than groundwater (i.e., soil surface water). We examined changes in volumetric soil water content (%), total hourly sapflux rates, and trichloroethene (TCE) concentrations. Following the irrigation treatment, volumetric soil water increased by 86% and sapflux increased by as much as 61%. Isotopic signatures of the xylem sap became substantially heavier following irrigation, suggesting that the applied irrigation water was quickly taken up by the plants. TCE concentrations in the xylem sap were diluted by an average of 21% following irrigation; however, dilution was low relative to the increase in sapflux. Our results show that water use by Populus deltoides is variable. Hence, studies addressing phytoremediation effectiveness must account for the relative proportion of surface vs. groundwater uptake.

  12. Water quality parameters controlling the photodegradation of two herbicides in surface waters of the Columbia Basin, Washington.

    PubMed

    Furman, Olha S; Yu, Miao; Teel, Amy L; Watts, Richard J

    2013-11-01

    The water quality parameters nitrate-nitrogen, dissolved organic carbon, and suspended solids were correlated with photodegradation rates of the herbicides atrazine and 2,4-D in samples collected from four sites in the Columbia River Basin, Washington, USA. Surface water samples were collected in May, July, and October 2010 and analyzed for the water quality parameters. Photolysis rates for the two herbicides in the surface water samples were then evaluated under a xenon arc lamp. Photolysis rates of atrazine and 2,4-D were similar with rate constants averaging 0.025 h(-1) for atrazine and 0.039 h(-1) for 2,4-D. Based on multiple regression analysis, nitrate-nitrogen was the primary predictor of photolysis for both atrazine and 2,4-D, with dissolved organic carbon also a predictor for some sites. However, at sites where suspended solids concentrations were elevated, photolysis rates of the two herbicides were controlled by the suspended solids concentration. The results of this research provide a basis for evaluating and predicting herbicide photolysis rates in shallow surface waters. Copyright © 2013 Elsevier Ltd. All rights reserved.

  13. Water World Artist Concept

    NASA Image and Video Library

    2017-04-12

    This artist's concept shows a hypothetical planet covered in water around the binary star system of Kepler-35A and B. In a 2017 study in the journal Nature Communications, researchers investigating the climates of exoplanets determined that this hypothetical planet could be habitable, depending on its distance from the two stars. On the far edge of the habitable zone, the hypothetical water-covered planet would have a lot of variation in its surface temperatures. But closer to the stars, near the inner edge of the habitable zone, the global average surface temperatures on the same planet would stay almost constant. https://photojournal.jpl.nasa.gov/catalog/PIA21470

  14. Impacts of Aerosols on Seasonal Precipitation and Snowpack in California Based on Convection-Permitting WRF-Chem Simulations

    NASA Astrophysics Data System (ADS)

    Gu, Y.; Wu, L.; Jiang, J. H.; Su, H.; Yu, N.; Zhao, C.; Qian, Y.; Zhao, B.; Liou, K. N.; Choi, Y. S.

    2017-12-01

    A version of the WRF-Chem model with fully coupled aerosol-meteorology-snowpack is employed to investigate the impacts of various aerosol sources on precipitation and snowpack in California. In particular, the impacts of locally emitted anthropogenic and dust aerosols, and aerosols transported from outside of California are studied. We differentiate three pathways of aerosol effects including aerosol-radiation interaction (ARI), aerosol-snow interaction (ASI), and aerosol-cloud interaction (ACI). The convection-permitting model simulations show that precipitation, snow water equivalent (SWE), and surface air temperature averaged over the whole domain (34-42°N, 117-124°W, not including ocean points) are reduced when aerosols are included, therefore reducing the high model biases of these variables when aerosol effects are not considered. Aerosols affect California water resources through the warming of mountain tops and anomalously low precipitation, however, different aerosol sources play different roles in changing surface temperature, precipitation and snowpack in California by means of various weights of the three pathways. ARI by all aerosols mainly cools the surface, leading to slightly increased SWE over the mountains. Locally emitted dust aerosols warm the surface of mountain tops through ASI, in which the reduced snow albedo associated with dirty snow leads to more surface absorption of solar radiation and reduced SWE. Transported and local anthropogenic aerosols play a dominant role in increasing cloud water amount but reducing precipitation through ACI, leading to reduced SWE and runoff over the Sierra Nevada, as well as the warming of mountain tops associated with decreased SWE and hence lower surface albedo. The average changes in surface temperature from October to June are about -0.19 K and 0.22 K for the whole domain and over mountain tops, respectively. Overall, the averaged reduction during October to June is about 7% for precipitation, 3% for SWE, and 7% for surface runoff for the whole domain, while the corresponding numbers are 12%, 10%, and 10% for mountain tops. The reduction in SWE is more significant in a dry year, with 9% for the whole domain and 16% for mountain tops.

  15. Fabrication of Water Jet Resistant and Thermally Stable Superhydrophobic Surfaces by Spray Coating of Candle Soot Dispersion.

    PubMed

    Qahtan, Talal F; Gondal, Mohammed A; Alade, Ibrahim O; Dastageer, Mohammed A

    2017-08-08

    A facile synthesis method for highly stable carbon nanoparticle (CNP) dispersion in acetone by incomplete combustion of paraffin candle flame is presented. The synthesized CNP dispersion is the mixture of graphitic and amorphous carbon nanoparticles of the size range of 20-50 nm and manifested the mesoporosity with an average pore size of 7 nm and a BET surface area of 366 m 2 g -1 . As an application of this material, the carbon nanoparticle dispersion was spray coated (spray-based coating) on a glass surface to fabricate superhydrophobic (water contact angle > 150° and sliding angle < 10 °) surfaces. The spray coated surfaces were found to exhibit much improved water jet resistance and thermal stability up to 400 °C compared to the surfaces fabricated from direct candle flame soot deposition (candle-based coating). This study proved that water jet resistant and thermally stable superhydrophobic surfaces can be easily fabricated by simple spray coating of CNP dispersion gathered from incomplete combustion of paraffin candle flame and this technique can be used for different applications with the potential for the large scale fabrication.

  16. Water Use in Arkansas, 2005

    USGS Publications Warehouse

    Holland, Terrance W.

    2007-01-01

    The water-use program in Arkansas is a cooperative effort between the Arkansas Natural Resources Commission and the U.S. Geological Survey to inventory water use. During 2005, the amount of water withdrawn from ground- and surface-water sources in Arkansas was estimated to be 11,455 million gallons per day (Mgal/d). Of this amount, about 7,510 Mgal/d (66 percent) was from ground-water and about 3,946 Mgal/d (34 percent) was from surface-water sources. Approximately 93 percent of the population (2.6 million people) in Arkansas was served by public supply systems during 2005. These systems withdrew approximately 404 Mgal/d. Most of the water, 66 percent, was from surface-water sources. The statewide average for per-capita residential use from public supply systems was 157 gallons per day and increased about 35 percent between 1965 and 2005. The largest use of water was for irrigation (8,265 Mgal/d), which accounted for 92 percent (6,942 Mgal/d) of the ground water withdrawn in Arkansas and 72 percent of the total withdrawals (both ground water and surface water). The next largest use category is thermoelectric generation (1,997 Mgal/d), followed by public supply (404 Mgal/d) and duck (hunting) clubs (269 Mgal/d). The withdrawal categories of domestic, commercial, industrial, mining, livestock, and aquaculture each withdrew less than 260 Mgal/d.

  17. Potentiometric surfaces of aquifers in the Cockfield Formation in southeastern Arkansas and the Wilcox Group in southern and northeastern Arkansas, 2000

    USGS Publications Warehouse

    Schrader, Tony P.; Joseph, Robert L.

    2000-01-01

    The Cockfield and lower Wilcox aquifers are sources of water for local use in southern and northeastern Arkansas, where in 1995 more than 51 million gallons per day of water was withdrawn. During January through April 2000, 54 water-level measurements were made in wells completed in the Cockfield aquifer, 13 water-level measurements were made in wells completed in the lower Wilcox aquifer in southern Arkansas, and 43 water-level measurements were made in wells completed in the lower Wilcox aquifer in northeastern Arkansas. The potentiometric surface data reveal spatial trends in both aquifers across the study areas. The regional direction of ground-water flow of the Cockfield aquifer is generally toward the east and south, away from the outcrop area, except in areas of intense ground-water withdrawals. The configuration of the potentiometric surface indicates that heavy pumpage has probably altered or reversed the natural direction of flow in these areas. A potentiometric low caused by the pumpage near Greenville, Mississippi, extends into Chicot, Desha, and Drew Counties. Water levels in five wells showed average declines between 0.5 and 0.8 foot per year. The regional direction of ground-water flow in the lower Wilcox aquifers is generally east and south, away from the outcrop, except in areas of intense ground-water withdrawals. Potentiometric depressions, where flow is toward centers of pumping, indicate that heavy pumpage has probably altered or reversed the natural direction of flow. Two potentiometric depressions are centered in the vicinity of Paragould and West Memphis, Arkansas, where ground-water withdrawals probably have altered the natural direction of flow. Long-term hydrographs of seven wells show water-level declines in the lower Wilcox aquifer in northeastern Arkansas. The average water-level decline in two wells was between 0.8 and 1.0 foot per year and in five wells was between 1.2 and 1.8 foot per year.

  18. Numerical investigation of roughness effects in aircraft icing calculations

    NASA Astrophysics Data System (ADS)

    Matheis, Brian Daniel

    2008-10-01

    Icing codes are playing a role of increasing significance in the design and certification of ice protected aircraft surfaces. However, in the interest of computational efficiency certain small scale physics of the icing problem are grossly approximated by the codes. One such small scale phenomena is the effect of ice roughness on the development of the surface water film and on the convective heat transfer. This study uses computational methods to study the potential effect of ice roughness on both of these small scale phenomena. First, a two-dimensional condensed layer code is used to examine the effect of roughness on surface water development. It is found that the Couette approximation within the film breaks down as the wall shear goes to zero, depending on the film thickness. Roughness elements with initial flow separation in the air induce flow separation in the water layer at steady state, causing a trapping of the film. The amount of trapping for different roughness configurations is examined. Second, a three-dimensional incompressible Navier-Stokes code is developed to examine large scale ice roughness on the leading edge. The effect on the convective heat transfer and potential effect on the surface water dynamics is examined for a number of distributed roughness parameters including Reynolds number, roughness height, streamwise extent, roughness spacing and roughness shape. In most cases the roughness field increases the net average convective heat transfer on the leading edge while narrowing surface shear lines, indicating a choking of the surface water flow. Both effects show significant variation on the scale of the ice roughness. Both the change in heat transfer as well as the potential change in surface water dynamics are presented in terms of the development of singularities in the surface shear pattern. Of particular interest is the effect of the smooth zone upstream of the roughness which shows both a relatively large increase in convective heat transfer as well as excessive choking of the surface shear lines at the upstream end of the roughness field. A summary of the heat transfer results is presented for both the averaged heat transfer as well as the maximum heat transfer over each roughness element, indicating that the roughness Reynolds number is the primary parameter which characterizes the behavior of the roughness for the problem of interest.

  19. Generation of Accurate Lateral Boundary Conditions for a Surface-Water Groundwater Interaction Model

    NASA Astrophysics Data System (ADS)

    Khambhammettu, P.; Tsou, M.; Panday, S. M.; Kool, J.; Wei, X.

    2010-12-01

    The 106 mile long Peace River in Florida flows south from Lakeland to Charlotte Harbor and has a drainage basin of approximately 2,350 square miles. A long-term decline in stream flows and groundwater potentiometric levels has been observed in the region. Long-term trends in rainfall, along with effects of land use changes on runoff, surface-water storage, recharge and evapotranspiration patterns, and increased groundwater and surface-water withdrawals have contributed to this decline. The South West Florida Water Management District (SWFWMD) has funded the development of the Peace River Integrated Model (PRIM) to assess the effects of land use, water use, and climatic changes on stream flows and to evaluate the effectiveness of various management alternatives for restoring stream flows. The PRIM was developed using MODHMS, a fully integrated surface-water groundwater flow and transport simulator developed by HydroGeoLogic, Inc. The development of the lateral boundary conditions (groundwater inflow and outflow) for the PRIM in both historical and predictive contexts is discussed in this presentation. Monthly-varying specified heads were used to define the lateral boundary conditions for the PRIM. These head values were derived from the coarser Southern District Groundwater Model (SDM). However, there were discrepancies between the simulated SDM heads and measured heads: the likely causes being spatial (use of a coarser grid) and temporal (monthly average pumping rates and recharge rates) approximations in the regional SDM. Finer re-calibration of the SDM was not feasible, therefore, an innovative approach was adopted to remove the discrepancies. In this approach, point discrepancies/residuals between the observed and simulated heads were kriged with an appropriate variogram to generate a residual surface. This surface was then added to the simulated head surface of the SDM to generate a corrected head surface. This approach preserves the trends associated with groundwater pumping / recharge in the SDM and adds the kriged residual surface as variations back to the trend. The variations could be from the scale effects of grid resolution and from the temporal averaging of stresses (pumping, recharge, etc.,). The validity of the approach is demonstrated by visual and statistical comparison of the observed and simulated heads before and after correction. For predictive simulations, an Artificial Neural Network was trained to predict heads at monitoring wells based on precipitation and pumping. These predicted head values could then be used as surrogate observations for correcting the results of the regional SDM. In summary, an appropriate approach to link a regional groundwater model to a detailed surface-water groundwater interaction model is demonstrated with an example.

  20. Enhancing surface methane fluxes from an oligotrophic lake: exploring the microbubble hypothesis.

    PubMed

    McGinnis, Daniel F; Kirillin, Georgiy; Tang, Kam W; Flury, Sabine; Bodmer, Pascal; Engelhardt, Christof; Casper, Peter; Grossart, Hans-Peter

    2015-01-20

    Exchange of the greenhouse gases carbon dioxide (CO2) and methane (CH4) across inland water surfaces is an important component of the terrestrial carbon (C) balance. We investigated the fluxes of these two gases across the surface of oligotrophic Lake Stechlin using a floating chamber approach. The normalized gas transfer rate for CH4 (k600,CH4) was on average 2.5 times higher than that for CO2 (k600,CO2) and consequently higher than Fickian transport. Because of its low solubility relative to CO2, the enhanced CH4 flux is possibly explained by the presence of microbubbles in the lake’s surface layer. These microbubbles may originate from atmospheric bubble entrainment or gas supersaturation (i.e., O2) or both. Irrespective of the source, we determined that an average of 145 L m(–2) d(–1) of gas is required to exit the surface layer via microbubbles to produce the observed elevated k600,CH4. As k600 values are used to estimate CH4 pathways in aquatic systems, the presence of microbubbles could alter the resulting CH4 and perhaps C balances. These microbubbles will also affect the surface fluxes of other sparingly soluble gases in inland waters, including O2 and N2.

  1. Influence of geology on arsenic concentrations in ground and surface water in central Lesvos, Greece.

    PubMed

    Aloupi, Maria; Angelidis, Michael O; Gavriil, Apostolos M; Koulousaris, Michael; Varnavas, Soterios P

    2009-04-01

    The occurrence of As was studied in groundwater used for human consumption and irrigation, in stream water and sediments and in water from thermal springs in the drainage basin of Kalloni Gulf, island of Lesvos, Greece, in order to investigate the potential influence of the geothermal field of Polichnitos-Lisvori on the ground and surface water systems of the area. Total dissolved As varied in the range <0.7-88.3 microg L(-1) in groundwater, 41.1-90.7 microg L(-1) in thermal spring water and 0.4-13.2 microg L(-1) in stream water, whereas As concentrations in stream sediments varied between 2.0-21.9 mg kg(-1). Four out of 31 groundwater samples exceeded the EC standard of 10 microg L(-1). The survey revealed an enrichment in both surface and groundwater hydrological systems in the northern part of the area (average concentrations of As in groundwater, stream water and stream sediment: 8.0 microg L(-1), 8.8 microg L(-1) and 15.0 mg kg(-1) respectively), in association with the volcanic bedrocks, while lower As concentrations were found in the eastern part (average concentrations in groundwater, stream water and stream sediment: 2.9 microg L(-1), 1.7 microg L(-1) and 5.9 mg kg(-1) respectively), which is dominated by ophiolitic ultramafic formations. The variation of As levels between the different parts of the study area suggests that local geology exerts a determinant influence on As geochemical behaviour. On the other hand, the geothermal activity manifested in the area of Polichnitos-Lisvori does not affect the presence of As in groundwater and streams.

  2. Wettability of Y2O3: A Relative Analysis of Thermally Oxidized, Reactively Sputtered and Template Assisted Nanostructured Coatings

    PubMed Central

    Barshilia, Harish C.; Chaudhary, Archana; Kumar, Praveen; Manikandanath, Natarajan T.

    2012-01-01

    The wettability of reactively sputtered Y2O3, thermally oxidized Y-Y2O3 and Cd-CdO template assisted Y2O3 coatings has been studied. The wettability of as-deposited Y2O3 coatings was determined by contact angle measurements. The water contact angles for reactively sputtered, thermally oxidized and template assisted Y2O3 nanostructured coatings were 99°, 117° and 155°, respectively. The average surface roughness values of reactively sputtered, thermally oxidized and template assisted Y2O3 coatings were determined by using atomic force microscopy and the corresponding values were 3, 11 and 180 nm, respectively. The low contact angle of the sputter deposited Y2O3 and thermally oxidized Y-Y2O3 coatings is attributed to a densely packed nano-grain like microstructure without any void space, leading to low surface roughness. A water droplet on such surfaces is mostly in contact with a solid surface relative to a void space, leading to a hydrophobic surface (low contact angle). Surface roughness is a crucial factor for the fabrication of a superhydrophobic surface. For Y2O3 coatings, the surface roughness was improved by depositing a thin film of Y2O3 on the Cd-CdO template (average roughness = 178 nm), which resulted in a contact angle greater than 150°. The work of adhesion of water was very high for the reactively sputtered Y2O3 (54 mJ/m2) and thermally oxidized Y-Y2O3 coatings (43 mJ/m2) compared to the Cd-CdO template assisted Y2O3 coating (7 mJ/m2). PMID:28348296

  3. Influence of Sub-Surface Irrigation on Soil Conditions and Water Irrigation Efficiency in a Cherry Orchard in a Hilly Semi-Arid Area of Northern China

    PubMed Central

    Peng, Gao; Bing, Wang; Guangcan, Zhang

    2013-01-01

    Sub-surface irrigation (SUI) is a new water-saving irrigation technology. To explore the influence of SUI on soil conditions in a cherry orchard and its water-saving efficiency, experiments were conducted from 2009 to 2010 using both SUI and flood irrigation (FLI) and different SUI quotas in hilly semi-arid area of northern China. The results demonstrated the following: 1) The bulk density of the soil under SUI was 6.8% lower than that of soil under FLI (P<0.01). The total soil porosity, capillary porosity and non-capillary porosity of soils using SUI were 11.7% (P<0.01), 8.7% (P<0.01) and 43.8% (P<0.01) higher than for soils using FLI. 2) The average soil temperatures at 0, 5, 10, 15 and 20 cm of soil depth using SUI were 1.7, 1.1, 0.7, 0.4 and 0.3°C higher than those for FLI, specifically, the differences between the surface soil layers were more significant. 3) Compared with FLI, the average water-saving efficiency of SUI was 55.6%, and SUI increased the irrigation productivity by 7.9-12.3 kg m-3 ha-1. 4) The soil moisture of different soil layers using SUI increased with increases in the irrigation quotas, and the soil moisture contents under SUI were significantly higher in the 0-20 cm layer and in the 21-50 cm layer than those under FLI (P<0.01). 5) The average yields of cherries under SUI with irrigation quotas of 80-320 m3 ha-1 were 8.7%-34.9% higher than those in soil with no irrigation (CK2). The average yields of cherries from soils using SUI were 4.5%-12.2% higher than using FLI. It is appropriate to irrigate 2-3 times with 230 m3 ha-1 per application using SUI in a year with normal rainfall. Our findings indicated that SUI could maintain the physical properties, greatly improve irrigation water use efficiency, and significantly increase fruit yields in hilly semi-arid areas of northern China. PMID:24039986

  4. Tidally averaged water and salt transport velocities and their distributions in the Pearl River Estuary

    NASA Astrophysics Data System (ADS)

    Zhu, Shouxian; Sheng, Jinyu; Ji, Xiaomei

    2016-09-01

    Tidally averaged transports of water and substance are important physical quantities over estuarine, coastal, and shelf waters, but they have been indistinguishably expressed in terms of the Eulerian residual current (ERC) or Lagrangian residual current (LRC) in many previous studies. In this study, the tidally averaged transport velocities for water (TA-WTV) and substance (TA-STV) are considered based on residual fluxes. The main advantage of these newly defined transport velocities is that they can be used to quantify differences in amplitude and direction between the tidally averaged water and substance transports. The two-dimensional TA-STV is interpreted as the transport due to the residual flow of water, tidal pumping, and vertical shear. The three-dimensional TA-STV includes transports from the residual flow of water and tidal pumping. Numerical results of sea surface elevations, currents, and salinity produced by a triply nested coastal ocean model for the Pearl River Estuary (PRE) are used to calculate the TA-WTV and TA-STV for salt (TA-STVsa). The general features of the TA-WTV and TA-STVsa are similar over the most part of the PRE but differ significantly in amplitude and direction over the salinity frontal zone. The ERC and LRC calculated from model results are also significantly different from the TA-STVsa over the salinity frontal zone.

  5. A Numerical Study of Currents, Water Surface Elevations, and Energy Dissipation in Chandeleur-Breton Sound, Louisiana.

    DTIC Science & Technology

    1978-02-01

    Numerical methods in the form of a digital computer model were used to simulate and study the tide- and wind-induced circulation in Chandeleur -Breton...entrances through the Chandeleur Island chain, where speed reaches 50-60 cm/sec for short periods. Surface elevations were found to have an average tide range

  6. Fate of Airborne Contaminants in Okefenokee National Wildlife Refuge

    USGS Publications Warehouse

    Winger, P.V.; Lasier, P.J.

    1997-01-01

    Designation of Okefenokee National Wildlife Refuge as a Class I Air Quality Area (given the highest level of protection possible from air pollutants under the Clean Air Act Amendments of 1977) affords mandatory protection of the Refuge's airshed through the permit-review process for planned developments. Rainfall is the major source of water to the swamp, and potential impacts from developments to the airshed are high. To meet management needs for baseline information, chemical contributions from atmospheric deposition and partitioning of anions and cations, with emphasis on mercury and lead, in the various matrices of the Swamp were determined between July 1993 and April 1995. Chemistry of rainfall was determined on an event basis from one site located at Refuge Headquarters. Field samples of surface water, pore water, floc and sediment were collected from four locations on the Refuge: Chesser Prairie, Chase Prairie, Durden Prairie, and the Narrows. A sediment core sample was collected from the Refuge interior at Bluff Lake for aging of mercury deposition. Rainfall was acidic (pH 4.8) with sulfate concentrations averaging 1.2 mg/L and nitrate averaging 0.8 mg/L. Lead in rainfall averaged 1 ?g/L and total and methylmercury concentrations were 11.7 ng/L and 0.025 ng/L, respectively. The drought of 1993 followed by heavy rains during the fall and winter caused a temporary alteration in the cycling and availability of trace-elements within the different matrices of the Swamp. Surface water was acidic (pH 3.8 to 4.1), dilute (specific conductance 35-60 ?S/cm), and highly organic (DOC 35-50 mg/L). Sediment and floc were also highly organic (>90%). Total mercury averaged 3.6 ng/L in surface water, 9.0 ng/L in pore water and about 170 ng/g in floc and sediments. Mercury bioaccumulated in the biota of the Refuge: fish fillets (Centrarchus macropterus, Esox niger, Lepomus gulosus and Amia calva) had >2 ?g/g dry weight, alligators (Alligator mississippiensis) >4 ?g/g dry weight in liver and kidney, and raccoons (Procyon lotor) >16 ?g/g dry weight in the liver and kidney. Lead averaged 1 ?g/L in rainfall, 6.6 ?g/L in surface water, 9.8 ?g/L in pore water, 12.3 ?g/g in floc and 12.5 ?g/g in sediments. Lead in fish muscle was ~0.1 ?g/g and >1.2 ?g/g in bone, alligator kidney had 1.5 ?g/g lead and liver had 3.8 ?g/g; raccoon kidney and liver averaged about 1 ?g/g. Historical patterns of mercury deposition based on 210Pb aging of the core sample showed mercury increased from pre-1800 concentrations of 500 ng/g in the 1950s, with a subsequent decline to current levels. Lead concentrations in the core sample followed a similar pattern as that of mercury. Okefenokee Swamp serves as a sump for the cations and anions deposited through rainfall. Although mercury and lead levels in the biota are not currently acutely hazardous, concentrations are high enough to cause adverse chronic effects on behavioral, physiological or reproductive functions of resident biota, especially piscivorous species. To protect trust resources associated with the Refuge, activities and developments in the airshed that have the potential to increase atmospheric contamination, especially for lead and mercury, should be curtailed.

  7. Water use in Kentucky, 1990

    USGS Publications Warehouse

    Sholar, C.J.; Wood, P.A.

    1995-01-01

    Water-use information for 1990 was collected and reported, by county, for eight major categories of use. Seven of the categories were offstream uses, which included public supply, commercial, domestic, industrial, mining, thermoelectric, and agricultural uses. The agricultural category was subdivided into irrigation and livestock water use. Instream water- use data also were collected for hydroelectric-power generation. Estimated average water use in Kentucky exceeded 4,300 million gallons per day during 1990 for all offstream uses. About 94 percent of this amount was from surface-water sources, and about 6 percent was from ground-water sources. Per capita use for all offstream uses was almost 1,200 gallons per day. Estimated average consumptive use was 309 million gallons per day. Estimated average instream water use for hydroelectric-power generation was 83,000 million gallons per day. Ninety-seven percent of the offstream water withdrawals during 1990 were withdrawn for thermoelectric, public supply, and industrial use. Cooling water used in the production of thermoelectric power accounted for about 80 percent of the total offstream water use during 1990. Water withdrawn for public supplies was second largest at almost 10 percent of the total, and industrial water withdrawals were about 7 percent of the total. Thermoelectric, domestic, and livestock uses accounted for almost 90 percent of the consumptive use during 1990. The thermoelectric category accounted for almost two-thirds of the total consumptive use in the State for all uses.

  8. Methane emissions from tundra environments in the Yukon-Kuskokwin Delta, Alaska

    NASA Technical Reports Server (NTRS)

    Bartlett, Karen B.; Crill, Patrick M.; Sass, Ronald L.; Harriss, Robert C.; Dise, Nancy B.

    1992-01-01

    This paper reports CH4 flux to the atmosphere from a variety of tundra environments near Bethel, Alaska during the summer months of 1988. Emissions from wet meadow tundra averaged 144 +/- 31 mg/sq m/d and ranged from 15.6 to 426 mg/sq m/d varying with soil moisture and temperature. Flux from the drier upland tundra was about two orders of magnitude lower and averaged 2.3 +/- 1.1 mg/sq m/d. Tundra lakes emit CH4 from the open water surface as well as from fringing aquatic vegetation; the presence of vegetation significantly enhanced flux over open water rates. Calculated diffusive fluxes from open water varied with lake size, the large lakes emitting 3.8 mg/sq m/d and small lakes emitting an average of 77 mg/sq m/d. An updated estimate of global emissions from tundra indicates an annual fluxes of approximately 11 +/- 3 Tg CH4.

  9. Quantum dynamics of water dissociative chemisorption on rigid Ni(111): An approximate nine-dimensional treatment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jiang, Bin, E-mail: bjiangch@ustc.edu.cn, E-mail: hguo@unm.edu; Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico 87131; Song, Hongwei

    The quantum dynamics of water dissociative chemisorption on the rigid Ni(111) surface is investigated using a recently developed nine-dimensional potential energy surface. The quantum dynamical model includes explicitly seven degrees of freedom of D{sub 2}O at fixed surface sites, and the final results were obtained with a site-averaging model. The mode specificity in the site-specific results is reported and analyzed. Finally, the approximate sticking probabilities for various vibrationally excited states of D{sub 2}O are obtained considering surface lattice effects and formally all nine degrees of freedom. The comparison with experiment reveals the inaccuracy of the density functional theory and suggestsmore » the need to improve the potential energy surface.« less

  10. Relationship between landscape characteristics and surface water quality.

    PubMed

    Chang, C L; Kuan, W H; Lui, P S; Hu, C Y

    2008-12-01

    The effects of landscape characteristics on surface water quality were evaluated in terms of land-use condition, soil type and slope. The case area, the Chichiawan stream in the Wulin catchment in Taiwan, is Formosan landlocked salmon's natural habitat. Due to the agriculture behavior and mankind's activities, the water and environmental quality has gradually worsened. This study applied WinVAST model to predict hydrological responses and non-point source pollution (NPSP) exports in the Wulin catchment. The land-use condition and the slope of land surface in a catchment are major effect factors for watershed responses, including flows and pollutant exports. This work discussed the possible variation of watershed responses induced by the change of land-use condition, soil type and slope, etc. The results show that hydrological responses are highly relative to the value of Curve Number (CN); Pollutant exports have large relation to the average slope of the land surface in the Wulin catchment.

  11. Evapotranspiration and runoff from large land areas: Land surface hydrology for atmospheric general circulation models

    NASA Technical Reports Server (NTRS)

    Famiglietti, J. S.; Wood, Eric F.

    1993-01-01

    A land surface hydrology parameterization for use in atmospheric GCM's is presented. The parameterization incorporates subgrid scale variability in topography, soils, soil moisture and precipitation. The framework of the model is the statistical distribution of a topography-soils index, which controls the local water balance fluxes, and is therefore taken to represent the large land area. Spatially variable water balance fluxes are integrated with respect to the topography-soils index to yield our large topography-soils distribution, and interval responses are weighted by the probability of occurrence of the interval. Grid square averaged land surface fluxes result. The model functions independently as a macroscale water balance model. Runoff ratio and evapotranspiration efficiency parameterizations are derived and are shown to depend on the spatial variability of the above mentioned properties and processes, as well as the dynamics of land surface-atmosphere interactions.

  12. Evolution of anomalies of salinity of surface waters of Arctic Ocean and their possible influence on climate changes

    NASA Astrophysics Data System (ADS)

    Popov, A.; Rubchenia, A.

    2009-04-01

    Numerous of model simulations of ice extent in Arctic Ocean predict almost full disappearance of sea ice in Arctic regions by 2050. However, the nature, as against models, does not suffer the unidirectional processes. By means of various feedback responses system aspires to come in an equilibrium condition. In Arctic regions one of the most powerful generators of a negative feedback is the fresh-water stream to Greenland Sea and Northern Atlantic. Increasing or decreasing of a fresh-water volume from the Arctic basin to Greenland Sea and Northern Atlantic results in significant changes in climatic system. At the Oceanology department of Arctic and Antarctic Research Institute (AARI) (St-Petersburg, Russia) in 2007, on the basis of the incorporated Russian-American database of the oceanographic data, reconstruction of long-term time series of average salinity of ocean surface was executed. The received time series describes the period from 1950 to 1993. For allocation of the processes determining formation of changes of average salinity of surface waters in Arctic basin the correlation analysis of interrelation of the received time series and several physical parameters which could affect formation of changes of salinity was executed. We found counter-intuitive result: formation of long-term changes of average salinity of surface waters of Arctic basin in the winter period does not depend on changes of a Siberian rivers runoff. Factors of correlation do not exceed -0,31. At the same time, clear inverse relationship of salinity of surface waters from volumes of the ice formed in flaw lead polynyas of the Siberian shelf seas is revealed. In this case factors of correlation change from -0,56 to -0,7. The maximum factor of correlation is -0,7. It characterizes interrelation of total volume of the ice formed in flaw lead polynyas of all seas of the Siberian shelf and average salinity of surface waters of Arctic basin. Thus, at increase of volumes of the ice formed in flaw lead polynyas there is a reduction of average salinity of surface waters of Arctic basin. In the winter period obvious influence of waters of a river runoff on a hydrological situation of this or that sea is limited to a zone of distribution of fast ice and a narrow zone of flaw lead polynyas between fast ice and drift ice. That fresh water from the Arctic seas is transferred in the Arctic basin. There should be a certain effective mechanism to carry it. Presence of clear interrelation of salinity of surface waters and volumes of ice formed in polynyas, allows us to offer the following circuit of formation of average salinity of surface waters in the Arctic basin. The ice formed in polynya, is constantly taken out for limits of an area of flaw lead polynyas. This ice accumulates the fresh water acting with a river runoff. New ice hummocking and accumulate snow - the next source of fresh water. In the summer period ice is melting and forms surface fresh layer. In the cold period of year, presence of thick ice not allows accumulating all fresh water, and the zone of fresh water is forming. These fresh water areas could exist for months. In the reports [1] was offered a hypothesis describing formation of distant connections in climatic system. In the hypothesis offered by us about a role of polynyas in formation of distant feedback in climatic system the most important and, unfortunately, the least certain parameter is «reaching time» of climatic signal from a place of origin (in flaw lead polynya area) up to the Greenland sea and Northern Atlantic. For an estimation of reaching time» we tried to trace drift of this anomaly from polynyas to Greenland Sea. For the initial moment of anomaly genesis month of the maximal development of polynya (when ice production of it was maximal) was chosen. Core of freshwater anomaly was determined for several polynyas. Using results of our simulations, data from database with areas of polynyas, wind stress data and current speed data from several sources, we got vector diagrams of drift of anomalies. Within the limits of the seas were taken into account a vector of constant currents. The vector of displacement within the limits of each of the seas represented the sum of constant current and average for one month of a vector of isobaric drift. In the Arctic basin we used only a vector of isobaric drift. Vectors of isobaric drift are constructed by I. Karelin (AARI, St-Petersburg, Russia) on the basis of average for one month of fields of ground pressure. As shown in numerous researches, monthly averaging most adequately allow us to display a field of wind drift of ice. For construction of vector diagrams on sphere we used «MapInfo Professional 7.5». For conviction of a reality of our hypothetical assumptions of carry of anomalies of salinity we have executed comparison of a spatial-temporal arrangement of areas vector diagrams we got with an arrangement of real anomalies of the salinity revealed as a result of instrumental observations. Such results of comparison have surpassed all expectations. We got confirmation of position of fresh water areas from instrumental observations executed in 2005-2007 by several cruises of AARI institute. Thus good concurrence of time and the location of areas of abnormal fleshing, received by theoretical and instrumentally observed conditions is marked. The map of a field of anomalies of the salinity, constructed for 2007 is most indicative. On this map a number of isolated fresh water areas in surface waters clearly allocated. To each of these areas of observed freshening there corresponds predicted passage of core of predicted anomaly. We could conclude that there is concurrence of predicted fresh water anomalies and observed fresh water areas. It allows us to say hypothesis is working. Flaw lead polynyas really forming significant anomalies of salinity which being distributed in Arctic basin. These anomalies keep the properties within several years. Hydrodynamic aspects of distribution of anomalies are not clear yet. But the fact of formation and distribution of anomalies of salinity of surface waters in Arctic basin could be taken for granted. In a case when the climatic signal from the several seas simultaneously reach Greenland Sea climatically significant anomaly of fresh water of ice could appear. It capable to result in sharp change of a climatic situation. Probably, the similar situation was in 1963-1964 years when «Great Salinity Anomaly» was observed in North Atlantic. Changes of atmospheric circulation was so significant, that in Arctic regions has rather sharply increased ice cover areas and the temperature of air has gone down. In our opinion similar conditions could arise in the present period when after several years of extreme development of flaw lead polynyas extreme freshwater anomaly which reaching of Greenland Sea is possible to expect 2008-2009 should be generated. In 2008 several freshwater anomalies generated in various flaw lead polynyas in 2003-2004 years already has left to Greenland sea and in April, July and November has reached Northern Atlantic. Synoptic situations which, in our opinion, can be connected to the given phenomenon, and also reaction of the Arctic seas to the given atmospheric processes are shown. The analysis of a map of drift of anomalies allows us to conclude, that in 2009 it is necessary to expect an exit of the strong salinity anomaly generated from several large polynyas. To the given event there will correspond reduction of repeatability and reduction of areas of polynyas in the seas of the Siberian shelf, easing of carrying out concerning warm air masses to the Central Arctic regions and increase here ground atmospheric pressure in the cold period of year. In the summer period will take place strengthening of ice cover and, hence - downturn of temperature of air in Arctic regions. We could assume we are at the break point of temperature change and next year there will be cooling in Arctic. [1] Popov A., Rubchenia A. Flaw polynyas as a source of long-distance connections in climate system // Geophysical Research Abstracts, Vol. 10, EGU2008-A-02009, 2008 SRef-ID: 1607-7962/gra/EGU2008-A-02009 EGU General Assembly 2008

  13. Changes in Land Surface Water Dynamics since the 1990s and Relation to Population Pressure

    NASA Technical Reports Server (NTRS)

    Prigent, C.; Papa, F.; Aires, F.; Jimenez, C.; Rossow, W. B.; Matthews, E.

    2012-01-01

    We developed a remote sensing approach based on multi-satellite observations, which provides an unprecedented estimate of monthly distribution and area of land-surface open water over the whole globe. Results for 1993 to 2007 exhibit a large seasonal and inter-annual variability of the inundation extent with an overall decline in global average maximum inundated area of 6% during the fifteen-year period, primarily in tropical and subtropical South America and South Asia. The largest declines of open water are found where large increases in population have occurred over the last two decades, suggesting a global scale effect of human activities on continental surface freshwater: denser population can impact local hydrology by reducing freshwater extent, by draining marshes and wetlands, and by increasing water withdrawals. Citation: Prigent, C., F. Papa, F. Aires, C. Jimenez, W. B. Rossow, and E. Matthews (2012), Changes in land surface water dynamics since the 1990s and relation to population pressure, in section 4, insisting on the potential applications of the wetland dataset.

  14. Four-month Moon and Mars crew water utilization study conducted at the Flashline Mars Arctic Research Station, Devon Island, Nunavut

    NASA Astrophysics Data System (ADS)

    Bamsey, M.; Berinstain, A.; Auclair, S.; Battler, M.; Binsted, K.; Bywaters, K.; Harris, J.; Kobrick, R.; McKay, C.

    2009-04-01

    A categorized water usage study was undertaken at the Flashline Mars Arctic Research Station on Devon Island, Nunavut in the High Canadian Arctic. This study was conducted as part of a long duration four-month Mars mission simulation during the summer of 2007. The study determined that the crew of seven averaged 82.07 L/day over the expedition (standard deviation 22.58 L/day). The study also incorporated a Mars Time Study phase which determined that an average of 12.12 L/sol of water was required for each crewmember. Drinking, food preparation, hand/face, oral, dish wash, clothes wash, shower, shaving, cleaning, engineering, science, plant growth and medical water were each individually monitored throughout the detailed study phases. It was determined that implementing the monitoring program itself resulted in an approximate water savings of 1.5 L/day per crewmember. The seven person crew averaged 202 distinct water draws a day (standard deviation 34) with high water use periods focusing around meal times. No statistically significant correlation was established between total water use and EVA or exercise duration. Study results suggest that current crew water utilization estimates for long duration planetary surface stays are more than two times greater than that required.

  15. Hydrated states of MgSO4 at equatorial latiudes on Mars

    USGS Publications Warehouse

    Feldman, W.C.; Mellon, M.T.; Maurice, S.; Prettyman, T.H.; Carey, J.W.; Vaniman, D.T.; Bish, D.L.; Fialips, C.I.; Chipera, S.J.; Kargel, J.S.; Elphic, R.C.; Funsten, H.O.; Lawrence, D.J.; Tokar, R.L.

    2004-01-01

    The stability of water ice, epsomite, and hexahydrite to loss of H 2O molecules to the atmosphere at equatorial latitudes of Mars was studied to determine their potential contributions to the measured abundance of water-equivalent hydrogen (WEH). Calculation of the relative humidity based on estimates of yearly averages of water-vapor pressures and temperatures at the Martian surface was used for this purpose. Water ice was found to be sufficiently unstable everywhere within 45?? of the equator that if the observed WEH is due to water ice, it requires a low-permeability cover layer near the surface to isolate the water ice below from the atmosphere above. In contrast, epsomite or hexahydrite may be stable in many near-equatorial locations where significant amounts of WEH are observed. Copyright 2004 by the American Geophysical Union.

  16. Rates of evapotranspiration, recharge from precipitation beneath selected areas of native vegetation, and streamflow gain and loss in Carson Valley, Douglas County, Nevada, and Alpine County, California

    USGS Publications Warehouse

    Maurer, Douglas K.; Berger, David L.; Tumbusch, Mary L.; Johnson, Michael J.

    2006-01-01

    Rapid growth and development in Carson Valley is causing concern over the continued availability of water resources to sustain such growth into the future. A study to address concerns over water resources and to update estimates of water-budget components in Carson Valley was begun in 2003 by the U.S. Geological Survey, in cooperation with Douglas County, Nevada. This report summarizes micrometeorologic, soil-chloride, and streambed-temperature data collected in Carson Valley from April 2003 through November 2004. Using these data, estimates of rates of discharge by evapotranspiration (ET), rates of recharge from precipitation in areas of native vegetation on the eastern and northern sides of the valley, and rates of recharge and discharge from streamflow infiltration and seepage on the valley floor were calculated. These rates can be used to develop updated water budgets for Carson Valley and to evaluate potential effects of land- and water-use changes on the valley's water budget. Data from eight ET stations provided estimates of annual ET during water year 2004, the sixth consecutive year of a drought with average or below average precipitation since 1999. Estimated annual ET from flood-irrigated alfalfa where the water table was from 3 to 6 feet below land surface was 3.1 feet. A similar amount of ET, 3.0 feet, was estimated from flood-irrigated alfalfa where the water table was about 40 feet below land surface. Estimated annual ET from flood-irrigated pasture ranged from 2.8 to 3.2 feet where the water table ranged from 2 to 5 feet below land surface, and was 4.4 feet where the water table was within 2 feet from land surface. Annual ET estimated from nonirrigated pasture was 1.7 feet. Annual ET estimated from native vegetation was 1.9 feet from stands of rabbitbrush and greasewood near the northern end of the valley, and 1.5 feet from stands of native bitterbrush and sagebrush covering alluvial fans along the western side of the valley. Uncertainty in most ET estimates is about 12 percent, but ranged from +30 and +50 percent to -20 and -40 percent for nonirrigated pasture and native bitterbrush and sagebrush. Estimated rates for water year 2004 likely are less than those during years of average, or above average precipitation when the water table would be closer to land surface. Test holes drilled in areas of native vegetation on the northern and eastern sides of Carson Valley had high concentrations of soil chloride at depths ranging from 4 to 18 feet below land surface at six locations on the eastern side of the valley. The high chloride concentrations indicate that modern-day precipitation at the six locations does not percolate deeper than the root zone of native vegetation. Estimates of the time required to accumulate the measured amount of chloride to depths of about 30 feet below land surface at the six test holes ranged from about 3,000 to 12,000 years. Low concentrations of soil chloride in two test holes on the northern end of Carson Valley and in a test hole on the eastern side of Fish Spring Flat indicate that a small amount of recharge from modern-day precipitation is taking place. Estimated annual recharge from precipitation at the two locations was 0.03 and 0.04 foot on the northern end of the valley and 0.02 foot on the eastern side of Fish Spring Flat. Uncertainty in the estimated recharge rates was about ?0.01 foot. Estimates of the time required to accumulate the measured amount of chloride to depths of about 30 feet below land surface at the three test holes ranged from about 100 to 700 years. The two test holes near the northern end of the valley are in gravel and eolian sand deposits and recharge from precipitation may be taking place at similar rates in other areas with gravel and eolian sand deposits. Based on results from other test holes, recharge at the rate estimated for the test hole on the eastern side of Fish Spring Flat is not likely applicable to a large area. Data from 37 site

  17. Temperature of surface waters in the conterminous United States

    USGS Publications Warehouse

    Blakey, James F.

    1966-01-01

    Temperature is probably the most important, but least discussed, parameter in determining water quality. The purpose of this report is to present the average or most probable temperatures of surface waters in the conterminous United States and to cite factors that affect and are affected by water temperature. Temperature is related, usually directly, to all the chemical, physical, and biological properties of water. The ability of water to dissolve or precipitate materials is temperature dependent, the ability of water to transport or deposit suspended material is temperature dependent, and the aquatic life of a lake or stream may thrive or die because of the water temperature.Everyone is concerned, though often unknowingly, about water temperature. The amount and type of treatment necessary for a municipal supply are temperature dependent; therefore it affects the consumer cost. Temperature determines the volume of cooling water needed for industrial processes and steampower generation. Conservation and recreation practices are affected by water temperature, and the farmers' irrigation practices and livestock production may be affected by the water temperature.

  18. Review of literature on the finite-element solution of the equations of two-dimensional surface-water flow in the horizontal plane

    USGS Publications Warehouse

    Lee, Jonathan K.; Froehlich, David C.

    1987-01-01

    Published literature on the application of the finite-element method to solving the equations of two-dimensional surface-water flow in the horizontal plane is reviewed in this report. The finite-element method is ideally suited to modeling two-dimensional flow over complex topography with spatially variable resistance. A two-dimensional finite-element surface-water flow model with depth and vertically averaged velocity components as dependent variables allows the user great flexibility in defining geometric features such as the boundaries of a water body, channels, islands, dikes, and embankments. The following topics are reviewed in this report: alternative formulations of the equations of two-dimensional surface-water flow in the horizontal plane; basic concepts of the finite-element method; discretization of the flow domain and representation of the dependent flow variables; treatment of boundary conditions; discretization of the time domain; methods for modeling bottom, surface, and lateral stresses; approaches to solving systems of nonlinear equations; techniques for solving systems of linear equations; finite-element alternatives to Galerkin's method of weighted residuals; techniques of model validation; and preparation of model input data. References are listed in the final chapter.

  19. Tidal truncation and barotropic convergence in a channel network tidally driven from opposing entrances

    USGS Publications Warehouse

    Warner, J.C.; Schoellhamer, D.; Schladow, G.

    2003-01-01

    Residual circulation patterns in a channel network that is tidally driven from entrances on opposite sides are controlled by the temporal phasing and spatial asymmetry of the two forcing tides. The Napa/Sonoma Marsh Complex in San Francisco Bay, CA, is such a system. A sill on the west entrance to the system prevents a complete tidal range at spring tides that results in tidal truncation of water levels. Tidal truncation does not occur on the east side but asymmetries develop due to friction and off-channel wetland storage. The east and west asymmetric tides meet in the middle to produce a barotropic convergence zone that controls the transport of water and sediment. During spring tides, tidally averaged water-surface elevations are higher on the truncated west side. This creates tidally averaged fluxes of water and sediment to the east. During neap tides, the water levels are not truncated and the propagation speed of the tides controls residual circulation, creating a tidally averaged flux in the opposite direction. ?? 2003 Elsevier Science B.V. All rights reserved.

  20. Sources and behavior of perchlorate ions (ClO4-) in chalk aquifer of Champagne-Ardenne, France: preliminary results

    NASA Astrophysics Data System (ADS)

    Cao, Feifei; Jaunat, Jessy; Ollivier, Patrick; Cancès, Benjamin; Morvan, Xavier; Hubé, Daniel; Devos, Alain; Devau, Nicolas; Barbin, Vincent; Pannet, Pierre

    2018-06-01

    Perchlorate (ClO4-) is an environmental contaminant of growing concern due to its potential human health effects and widespread occurrence in surface water and groundwater. Analyses carried out in France have highlighted the presence of ClO4- in drinking water of Champagne-Ardenne (NW of France), with two potential sources suspected: a military source related to the First World War and an agricultural source related to the past use of Chilean nitrates. To determine the sources of ClO4- in groundwater, major and trace elements, 2H and 18O, ClO3- and ClO4- ions and a list of 39 explosives were analyzed from 35 surface water and groundwater sampling points in the east of the city of Reims. ClO4- ions were found in almost all sampling points (32 out of 35) with a max value of 33 µg L-1. ClO4- concentrations were highest in groundwater ranging from 0.7 to 33 µg L-1 (average value of about 6.2 µg L-1) against from < 0.5 to 10.2 µg L-1 in surface water (average value of about 2.7 µg L-1). Most of the water samples showing high ClO4- levels (> 4 µg L-1) were collected near a military camp, where huge quantities of ammunitions have been used, stored and destroyed during and after the First World War.

  1. The characteristics and dynamics of wave-driven flow across a platform coral reef in the Red Sea

    NASA Astrophysics Data System (ADS)

    Lentz, S. J.; Churchill, J. H.; Davis, K. A.; Farrar, J. T.; Pineda, J.; Starczak, V.

    2016-02-01

    Current dynamics across a platform reef in the Red Sea near Jeddah, Saudi Arabia, are examined using 18 months of current profile, pressure, surface wave, and wind observations. The platform reef is 700 m long, 200 m across with spatial and temporal variations in water depth over the reef ranging from 0.6 to 1.6 m. Surface waves breaking at the seaward edge of the reef cause a 2-10 cm setup of sea level that drives cross-reef currents of 5-20 cm s-1. Bottom stress is a significant component of the wave setup balance in the surf zone. Over the reef flat, where waves are not breaking, the cross-reef pressure gradient associated with wave setup is balanced by bottom stress. The quadratic drag coefficient for the depth-average flow decreases with increasing water depth from Cda = 0.17 in 0.4 m of water to Cda = 0.03 in 1.2 m of water. The observed dependence of the drag coefficient on water depth is consistent with open-channel flow theory and a hydrodynamic roughness of zo = 0.06 m. A simple one-dimensional model driven by incident surface waves and wind stress accurately reproduces the observed depth-averaged cross-reef currents and a portion of the weaker along-reef currents over the focus reef and two other Red Sea platform reefs. The model indicates the cross-reef current is wave forced and the along-reef current is partially wind forced.

  2. Evaluating regional water scarcity: Irrigated crop water budgets for groundwater management in the Wisconsin Central Sands

    NASA Astrophysics Data System (ADS)

    Nocco, M. A.; Kucharik, C. J.; Kraft, G.

    2013-12-01

    Regional water scarcity dilemmas between agricultural and aquatic land users pervade the humid northern lake states of Wisconsin, Minnesota, and Michigan, where agricultural irrigation relies on groundwater drawn from shallow aquifers. As these aquifers have strong connectivity to surface waters, irrigation lowers water levels in lakes and wetlands and reduces stream discharges. Irrigation expansion has cultivated a 60-year water scarcity dilemma in The Wisconsin Central Sands, the largest irrigated region in the humid northern lake states, dedicated to potato, maize, and processing vegetable production. Irrigation has depleted Wisconsin Central Sands surface waters, lowering levels in some lakes by over 2 m and drying some coldwater trout streams. Aquatic ecosystems, property values, and recreational uses in some surface waters have been devastated. While the causal link between pumping and surface water stress is established, understanding crop-mediated processes, such as the timing and magnitude of groundwater consumption by evapotranspiration (ET) and groundwater recharge, will be useful in management of groundwater, irrigated cropping systems, and surface water health. Previous modeling and field efforts have compared irrigated crop water use to a natural reference condition on a net annual basis. As a result, we presently understand that for irrigated potatoes and maize, the average annual ET is greater and therefore, the average annual recharge is less than rainfed row crops, grasslands, and both coniferous and deciduous forests. However, we have a limited understanding of the magnitude and timing of ET and recharge from irrigated cropping systems on shorter time scales that proceed with the annual cropping cycle (i.e. planting, full canopy, harvest, residue cover). We seek to understand the spatiotemporal variability of crop water budgets and associated water scarcity in the Wisconsin Central Sands through detailed measurements of drainage (potential recharge) and by inferring ET through difference, modeling, and gas exchange. In April 2013 prior to planting, we installed 10 passive capillary wick lysimeters below the effective rooting zone (z=100 cm) in potato (n=6) and maize (n=4) cropping systems to collect drainage at a 10-minute time-step under cultivation on Isherwood Farms, a sixth-generation family farm in the Wisconsin Central Sands region. Lysimeters were also instrumented to measure soil moisture and temperature at depth (z=10, 20, 40, 80 cm). Farm operators initiated center-pivot irrigation when soil moisture dropped to approximately 50% of plant available water content. Results show that drainage for May-July 2013 was 43 × 53 mm and 48 × 41 mm in irrigated potato and maize cropping systems, respectively, despite 320 mm of precipitation received during the experimental period, which was 15% above average for this region. Soil moisture consistently fluctuated in response to precipitation/irrigation events at the 10 and 20 cm soil depths, but rarely fluctuated in response to precipitation/irrigation events at the 40 and 80 cm soil depths, supporting the low drainage observed during the growing season. Future work will couple these drainage data to ongoing phenological, micrometeorological, and gas exchange observations in order to infer ET and calculate crop water budgets on a seasonal basis.

  3. Thermal Pollution Mathematical Model. Volume 6; Verification of Three-Dimensional Free-Surface Model at Anclote Anchorage; [environment impact of thermal discharges from power plants

    NASA Technical Reports Server (NTRS)

    Lee, S. S.; Sengupta, S.; Tuann, S. Y.; Lee, C. R.

    1980-01-01

    The free-surface model presented is for tidal estuaries and coastal regions where ambient tidal forces play an important role in the dispersal of heated water. The model is time dependent, three dimensional, and can handle irregular bottom topography. The vertical stretching coordinate is adopted for better treatment of kinematic condition at the water surface. The results include surface elevation, velocity, and temperature. The model was verified at the Anclote Anchorage site of Florida Power Company. Two data bases at four tidal stages for winter and summer conditions were used to verify the model. Differences between measured and predicted temperatures are on an average of less than 1 C.

  4. Quantifying Water Stress Using Total Water Volumes and GRACE

    NASA Astrophysics Data System (ADS)

    Richey, A. S.; Famiglietti, J. S.; Druffel-Rodriguez, R.

    2011-12-01

    Water will follow oil as the next critical resource leading to unrest and uprisings globally. To better manage this threat, an improved understanding of the distribution of water stress is required today. This study builds upon previous efforts to characterize water stress by improving both the quantification of human water use and the definition of water availability. Current statistics on human water use are often outdated or inaccurately reported nationally, especially for groundwater. This study improves these estimates by defining human water use in two ways. First, we use NASA's Gravity Recovery and Climate Experiment (GRACE) to isolate the anthropogenic signal in water storage anomalies, which we equate to water use. Second, we quantify an ideal water demand by using average water requirements for the domestic, industrial, and agricultural water use sectors. Water availability has traditionally been limited to "renewable" water, which ignores large, stored water sources that humans use. We compare water stress estimates derived using either renewable water or the total volume of water globally. We use the best-available data to quantify total aquifer and surface water volumes, as compared to groundwater recharge and surface water runoff from land-surface models. The work presented here should provide a more realistic image of water stress by explicitly quantifying groundwater, defining water availability as total water supply, and using GRACE to more accurately quantify water use.

  5. Two-dimensional streamflow simulations of the Jordan River, Midvale and West Jordan, Utah

    USGS Publications Warehouse

    Kenney, Terry A.; Freeman, Michael L.

    2011-01-01

    The Jordan River in Midvale and West Jordan, Utah, flows adjacent to two U.S. Environmental Protection Agency Superfund sites: Midvale Slag and Sharon Steel. At both sites, geotechnical caps extend to the east bank of the river. The final remediation tasks for these sites included the replacement of a historic sheet-pile dam and the stabilization of the river banks adjacent to the Superfund sites. To assist with these tasks, two hydraulic modeling codes contained in the U.S. Geological Survey (USGS) Multi-Dimensional Surface-Water Modeling System (MD_SWMS), System for Transport and River Modeling (SToRM) and Flow and Sediment Transport and Morphological Evolution of Channels (FaSTMECH), were used to provide predicted water-surface elevations, velocities, and boundary shear-stress values throughout the study reach of the Jordan River. A SToRM model of a 0.7 mile subreach containing the sheet-pile dam was used to compare water-surface elevations and velocities associated with the sheet-pile dam and a proposed replacement structure. Maps showing water-surface elevation and velocity differences computed from simulations of the historic sheet-pile dam and the proposed replacement structure topographies for streamflows of 500 and 1,000 cubic feet per second (ft3/s) were created. These difference maps indicated that the velocities associated with the proposed replacement structure topographies were less than or equal to those associated with the historic sheet-pile dam. Similarly, water-surface elevations associated with the proposed replacement structure topographies were all either greater than or equal to water-surface elevations associated with the sheet-pile dam. A FaSTMECH model was developed for the 2.5-mile study reach to aid engineers in bank stabilization designs. Predicted water-surface elevations, velocities and shear-stress values were mapped on an aerial photograph of the study reach to place these parameters in a spatial context. Profile plots of predicted cross-stream average water-surface elevations and cross-stream maximum and average velocities showed how these parameters change along the study reach for two simulated discharges of 1,040 ft3/s and 2,790 ft3/s. The profile plots for the simulated streamflow of 1,040 ft3/s show that the highest velocities are associated with the constructed sheet-pile replacement structure. Results for the simulated streamflow of 2,790 ft3/s indicate that the geometry of the 7800 South Bridge causes more backwater and higher velocities than the constructed sheet-pile replacement structure.

  6. Porewater inputs drive Fe redox cycling in the water column of a temperate mangrove wetland

    NASA Astrophysics Data System (ADS)

    Holloway, Ceylena J.; Santos, Isaac R.; Rose, Andrew L.

    2018-07-01

    Iron is a vital micronutrient within coastal marine ecosystems, playing an integral role in the scale and dynamics of primary production and carbon cycling in the world's oceans. We investigated the relative importance of in situ Fe(II) production from photochemical, microbial and thermal Fe reduction in the surface water column as well as advective porewater inputs in a temperate saline wetland in Australia containing mangrove and saltmarsh vegetation. The diel average concentration of Fe(II) (0.63 ± 0.21 μM, accounting for >70% of the total dissolved Fe present in surface water) was much higher than commonly reported in oxygenated marine waters despite high dissolved oxygen concentrations (81-112% saturation), pH (7.7-7.8) and salinity (33-36) that favor Fe oxidation. In situ production of Fe(II) in the surface water column was primarily driven by microbial processes rather than photochemical and thermal reduction, with a maximum production rate of 4.9 × 10-3 nM s-1. Advective porewater Fe(II) inputs to the wetland averaged over a diel cycle (3.0 × 10-1 nM s-1) were an order of magnitude greater than the combined Fe(II) production rate from autochthonous water column processes (1.0 × 10-2 nM s-1). A bottom up model based on the estimated individual fluxes was used to explain the high Fe(II) concentrations measured during a 24 h time series experiment. Combined, different lines of evidence suggest that advective porewater exchange provides significant quantities of Fe(II) to the estuarine wetland.

  7. Description and interpretation of geologic materials from shotholes drilled for the Trans-Alaska Crustal Transect project, Copper River basin, Alaska, May 1985

    USGS Publications Warehouse

    Odum, J.K.; Yehle, L.A.; Schmoll, H.R.; Gilbert, Chuck

    1986-01-01

    This map shows the potentiometric surface of the Upper Floridan aquifer in the St. Johns River Water Management District and vicinity, Florida, for May 1986. The Upper Floridan aquifer is the principal source of potable water in the area. Water level measurements were made on approximately 1,000 wells and on several springs. The potentiometric surface is shown mostly by 5-foot contour intervals. In the Fernandina Beach area of Nassau County, a 30-ft. interval is used to show a deep cone of depression. The potentiometric surface ranged from 125 feet above sea level in Polk County to 75 feet below sea level in Nassau County. Water levels in most key wells ranged from 1 to 9 feet below the May average in response to the lack of recharge from rainfall and an attendant increase in pumpage. Many levels in the district were equal to or lower than the below average levels of May 1985. Declines of about a foot from May 1985 levels were common in the eastern half of the district. However, the largest declines from May 1985 levels, as much as 7 to 9 feet, were mostly in well fields along the coastline. Levels in many wells approached, and in a few wells exceeded, record lows. (USGS)

  8. Withdrawal of ground water and pond water on Long Island from 1904 to 1949

    USGS Publications Warehouse

    Lusczynski, Norbert J.

    1950-01-01

    For more than 50 years the highly productive and readily replenishable water-bearing sands and gravels on Long Island -- capable of yielding an average of at least 1,000 million gallons a day -- and also some surface streams and ponds have been utilized on a large scale of public water supply and industrial, agricultural and domestic uses. During the drought months of 1949, when many surface and groundwater supplied were being depleted at an alarming rate in many localities in the Northeast, the abundant water resources of Long Island provided sufficient water for public water supply for a large number of private companies and municipalities, as well as for large emergency drafts by the City of New York. In addition they kept industrial concerns from curtailing production, saved millions of dollars of potato, cauliflower, and other Long Island crops, and even furnished, during the summer heat, comfort cooling and theatergoers.

  9. [Preliminary observation on survival and reproduction of imported Oncomelania snails in water network regions: a simulated experiment].

    PubMed

    Tian, Jian-Guo; Zhong, Wen-Jiang; Li, Gui-Fu; Peng, Li-Xia; Xiang, Xiao-Ping

    2011-04-01

    To observe the survival and reproduction of exotic imported Oncomelania snails in water network regions. During a period between May 22, 2008 and August 7, 2009, a study pilot was established in a historical snail habitat in Qingpu District of Shanghai City. A total of 12 soil samples were collected from Qingpu, Jinshan and Songjiang districts and placed in the study area. Active marked adults snails without infections (with a female/male ratio of 1) were placed on soil surface, and the activity, survival and reproduction of snails on soil surface were observed. The temperature during the period of the study was recorded. During the experiment period, the highest temperature was 39 degrees C, the lowest was -3 degrees C, and the average was 20 degrees C. The activity of snails reduced significantly on the soil surface at high temperature in summer and low temperature in winter. There were 91 old snails (5.2%) that moved on soil surface in March and 73 (12.2% ) in June, 2009. A total of 26 and 59 offspring snails were found respectively in April and June, 2009, with average density of 2.17 snails/m2 (26/12) and 4.92 snails/m2 (59/12) respectively. The exotic imported snails can survive and reproduce in water network regions. Further monitoring should be strengthened on the imported snails in these regions.

  10. Regional water consumption for hydro and thermal electricity generation in the United States

    DOE PAGES

    Lee, Uisung; Han, Jeongwoo; Elgowainy, Amgad; ...

    2017-05-18

    Water is an essential resource for most electric power generation technologies. Thermal power plants typically require a large amount of cooling water whose evaporation is regarded to be consumed. Hydropower plants result in evaporative water loss from the large surface areas of the storing reservoirs. This paper estimated the regional water consumption factors (WCFs) for thermal and hydro electricity generation in the United States, because the WCFs of these power plants vary by region and water supply and demand balance are of concern in many regions. For hydropower, total WCFs were calculated using a reservoir’s surface area, state-level water evaporation,more » and background evapotranspiration. Then, for a multipurpose reservoir, a fraction of its WCF was allocated to hydropower generation based on the share of the economic valuation of hydroelectricity among benefits from all purposes of the reservoir. For thermal power plants, the variations in WCFs by type of cooling technology, prime mover technology, and by region were addressed. The results show that WCFs for electricity generation vary significantly by region. Finally, the generation-weighted average WCFs of thermoelectricity and hydropower are 1.25 (range of 0.18–2.0) and 16.8 (range of 0.67–1194) L/kWh, respectively, and the generation-weighted average WCF by the U.S. generation mix in 2015 is estimated at 2.18 L/kWh.« less

  11. Air-water exchange and dry deposition of polybrominated diphenyl ethers at a coastal site in Izmir Bay, Turkey.

    PubMed

    Cetin, Banu; Odabasi, Mustafa

    2007-02-01

    The air-water exchange of polybrominated diphenyl ethers (PBDEs), an emerging class of persistent organic pollutants (POPs), was investigated using paired air-water samples (n = 15) collected in July and December, 2005 from Guzelyali Port in Izmir Bay, Turkey. Total dissolved-phase water concentrations of PBDEs (sigma7PBDEs) were 212 +/- 65 and 87 +/- 57 pg L(-1) (average +/- SD) in summer and winter, respectively. BDE-209 was the most abundant congener in all samples, followed by BDE-99 and -47. Average ambient gas-phase sigma7PBDE concentrations were between 189 +/- 61 (summer) and 76 +/- 65 pg m(-3) (winter). Net air-water exchange fluxes ranged from -0.9 +/- 1.0 (BDE-28) (volatilization) to 11.1 +/- 5.4 (BDE-209) ng m(-2) day(-1) (deposition). The BDE-28 fluxes were mainly volatilization while the other congeners were deposited. Gas- and dissolved-phase concentrations were significantly correlated (P = 0.33-0.55, p < 0.05, except for BDE-209, r = 0.05, p > 0.05) indicating thatthe atmosphere controls the surface water PBDE levels in this coastal environment. Estimated particulate dry deposition fluxes ranged between 2.7 +/- 1.9 (BDE-154) and 116 +/- 84 ng m(-2) day(-1) (BDE-209) indicating that dry deposition is also a significant input to surface waters in the study area.

  12. Regional water consumption for hydro and thermal electricity generation in the United States

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, Uisung; Han, Jeongwoo; Elgowainy, Amgad

    Water is an essential resource for most electric power generation technologies. Thermal power plants typically require a large amount of cooling water whose evaporation is regarded to be consumed. Hydropower plants result in evaporative water loss from the large surface areas of the storing reservoirs. This paper estimated the regional water consumption factors (WCFs) for thermal and hydro electricity generation in the United States, because the WCFs of these power plants vary by region and water supply and demand balance are of concern in many regions. For hydropower, total WCFs were calculated using a reservoir’s surface area, state-level water evaporation,more » and background evapotranspiration. Then, for a multipurpose reservoir, a fraction of its WCF was allocated to hydropower generation based on the share of the economic valuation of hydroelectricity among benefits from all purposes of the reservoir. For thermal power plants, the variations in WCFs by type of cooling technology, prime mover technology, and by region were addressed. The results show that WCFs for electricity generation vary significantly by region. Finally, the generation-weighted average WCFs of thermoelectricity and hydropower are 1.25 (range of 0.18–2.0) and 16.8 (range of 0.67–1194) L/kWh, respectively, and the generation-weighted average WCF by the U.S. generation mix in 2015 is estimated at 2.18 L/kWh.« less

  13. Retrieval of Ocean Surface Windspeed and Rainrate from the Hurricane Imaging Radiometer (HIRAD) Brightness Temperature Observations

    NASA Technical Reports Server (NTRS)

    Biswas, Sayak K.; Jones, Linwood; Roberts, Jason; Ruf, Christopher; Ulhorn, Eric; Miller, Timothy

    2012-01-01

    The Hurricane Imaging Radiometer (HIRAD) is a new airborne synthetic aperture passive microwave radiometer capable of wide swath imaging of the ocean surface wind speed under heavy precipitation e.g. in tropical cyclones. It uses interferometric signal processing to produce upwelling brightness temperature (Tb) images at its four operating frequencies 4, 5, 6 and 6.6 GHz [1,2]. HIRAD participated in NASA s Genesis and Rapid Intensification Processes (GRIP) mission during 2010 as its first science field campaign. It produced Tb images with 70 km swath width and 3 km resolution from a 20 km altitude. From this, ocean surface wind speed and column averaged atmospheric liquid water content can be retrieved across the swath. The column averaged liquid water then could be related to an average rain rate. The retrieval algorithm (and the HIRAD instrument itself) is a direct descendant of the nadir-only Stepped Frequency Microwave Radiometer that is used operationally by the NOAA Hurricane Research Division to monitor tropical cyclones [3,4]. However, due to HIRAD s slant viewing geometry (compared to nadir viewing SFMR) a major modification is required in the algorithm. Results based on the modified algorithm from the GRIP campaign will be presented in the paper.

  14. Molecular dynamics of the water liquid-vapor interface

    NASA Technical Reports Server (NTRS)

    Wilson, M. A.; Pohorille, A.; Pratt, L. R.; MacElroy, R. D. (Principal Investigator)

    1987-01-01

    The results of molecular dynamics calculations on the equilibrium interface between liquid water and its vapor at 325 K are presented. For the TIP4P model of water intermolecular pair potentials, the average surface dipole density points from the vapor to the liquid. The most common orientations of water molecules have the C2 nu molecular axis roughly parallel to the interface. The distributions are quite broad and therefore compatible with the intermolecular correlations characteristic of bulk liquid water. All near-neighbor pairs in the outermost interfacial layers are hydrogen bonded according to the common definition adopted here. The orientational preferences of water molecules near a free surface differ from those near rigidly planar walls which can be interpreted in terms of patterns found in hexagonal ice 1. The mean electric field in the interfacial region is parallel to the mean polarization which indicates that attention cannot be limited to dipolar charge distributions in macroscopic descriptions of the electrical properties of this interface. The value of the surface tension obtained is 132 +/- 46 dyn/cm, significantly different from the value for experimental water of 68 dyn/cm at 325 K.

  15. Hydrology of the Lake Deaton and Lake Okahumpka area, Northeast Sumter County, Florida

    USGS Publications Warehouse

    Simonds, Edward P.; German, E.R.

    1980-01-01

    The Floridan aquifer in the Lake Deaton and Lake Okahumpka area is 50 to 130 feet below land surface. During the 16-year period 1963-78 lake evaporation exceeded rainfall by 0.4 inches. Drainage from Lake Deaton and its surrounding area goes into Chitty Chatty Creek and on the Hogeye Sink when the altitude of the potentiometric surface of the Floridan aquifer is low. During a higher altitude of the Floridan potentiometric surface, Hogeye Sink may discharge water; this water, along with the normal runoff, goes into Lake Okahumpka. Average lake fluctuation is 1.5 to 2.0 feet per year. Lake Deaton supports a large population of blue-green algae and Lake Okahumpka is choked with aquatic plants. The water quality of the two lakes differ, with Lake Deaton having a sodium chloride water and Lake Okahumpka having a calcium bicarbonate water. Analysis of water and bottom material samples showed that only cadmium and mercury exceeded the Florida Department of Environmental Regulation 's criteria for Class III waters; however, the amounts detected were at or slightly above the limits of the analytical method. (USGS)

  16. Determining water storage depletion within Iran by assimilating GRACE data into the W3RA hydrological model

    NASA Astrophysics Data System (ADS)

    Khaki, M.; Forootan, E.; Kuhn, M.; Awange, J.; van Dijk, A. I. J. M.; Schumacher, M.; Sharifi, M. A.

    2018-04-01

    Groundwater depletion, due to both unsustainable water use and a decrease in precipitation, has been reported in many parts of Iran. In order to analyze these changes during the recent decade, in this study, we assimilate Terrestrial Water Storage (TWS) data from the Gravity Recovery And Climate Experiment (GRACE) into the World-Wide Water Resources Assessment (W3RA) model. This assimilation improves model derived water storage simulations by introducing missing trends and correcting the amplitude and phase of seasonal water storage variations. The Ensemble Square-Root Filter (EnSRF) technique is applied, which showed stable performance in propagating errors during the assimilation period (2002-2012). Our focus is on sub-surface water storage changes including groundwater and soil moisture variations within six major drainage divisions covering the whole Iran including its eastern part (East), Caspian Sea, Centre, Sarakhs, Persian Gulf and Oman Sea, and Lake Urmia. Results indicate an average of -8.9 mm/year groundwater reduction within Iran during the period 2002 to 2012. A similar decrease is also observed in soil moisture storage especially after 2005. We further apply the canonical correlation analysis (CCA) technique to relate sub-surface water storage changes to climate (e.g., precipitation) and anthropogenic (e.g., farming) impacts. Results indicate an average correlation of 0.81 between rainfall and groundwater variations and also a large impact of anthropogenic activities (mainly for irrigations) on Iran's water storage depletions.

  17. Review: Groundwater management and groundwater/surface-water interaction in the context of South African water policy

    NASA Astrophysics Data System (ADS)

    Levy, Jonathan; Xu, Yongxin

    2012-03-01

    Groundwater/surface-water interaction is receiving increasing focus in Africa due to its importance to ecologic systems and sustainability. In South Africa's 1998 National Water Act (NWA), water-use licenses, including groundwater, are granted only after defining the Reserve, the amount of water needed to supply basic human needs and preserve some ecological integrity. Accurate quantification of groundwater contributions to ecosystems for successful implementation of the NWA proves challenging; many of South Africa's aquifers are in heterogeneous and anisotropic fractured-rock settings. This paper reviews the current conceptualizations and investigative approaches regarding groundwater/surface-water interactions in the context of South African policies. Some selected pitfall experiences are emphasized. The most common approach in South Africa is estimation of average annual fluxes at the scale of fourth-order catchments (˜500 km2) with baseflow separation techniques and then subtracting the groundwater discharge rate from the recharge rate. This approach might be a good start, but it ignores spatial and temporal variability, potentially missing local impacts associated with production-well placement. As South Africa's NWA has already been emulated in many countries including Zambia, Zimbabwe and Kenya, the successes and failures of the South African experience dealing with the groundwater/surface-water interaction will be analyzed to guide future policy directions.

  18. Recovery of diverse microbes in high turbidity surface water samples using dead-end ultrafiltration

    PubMed Central

    Mull, Bonnie; Hill, Vincent R.

    2015-01-01

    Dead-end ultrafiltration (DEUF) has been reported to be a simple, field-deployable technique for recovering bacteria, viruses, and parasites from large-volume water samples for water quality testing and waterborne disease investigations. While DEUF has been reported for application to water samples having relatively low turbidity, little information is available regarding recovery efficiencies for this technique when applied to sampling turbid water samples such as those commonly found in lakes and rivers. This study evaluated the effectiveness of a DEUF technique for recoveringMS2 bacteriophage, enterococci, Escherichia coli, Clostridium perfringens, and Cryptosporidium parvum oocysts in surface water samples having elevated turbidity. Average recovery efficiencies for each study microbe across all turbidity ranges were: MS2 (66%), C. parvum (49%), enterococci (85%), E. coli (81%), and C. perfringens (63%). The recovery efficiencies for MS2 and C. perfringens exhibited an inversely proportional relationship with turbidity, however no significant differences in recovery were observed for C. parvum, enterococci, or E. coli. Although ultrafilter clogging was observed, the DEUF method was able to process 100-L surface water samples at each turbidity level within 60 min. This study supports the use of the DEUF method for recovering a wide array of microbes in large-volume surface water samples having medium to high turbidity. PMID:23064261

  19. Recovery of diverse microbes in high turbidity surface water samples using dead-end ultrafiltration.

    PubMed

    Mull, Bonnie; Hill, Vincent R

    2012-12-01

    Dead-end ultrafiltration (DEUF) has been reported to be a simple, field-deployable technique for recovering bacteria, viruses, and parasites from large-volume water samples for water quality testing and waterborne disease investigations. While DEUF has been reported for application to water samples having relatively low turbidity, little information is available regarding recovery efficiencies for this technique when applied to sampling turbid water samples such as those commonly found in lakes and rivers. This study evaluated the effectiveness of a DEUF technique for recovering MS2 bacteriophage, enterococci, Escherichia coli, Clostridium perfringens, and Cryptosporidium parvum oocysts in surface water samples having elevated turbidity. Average recovery efficiencies for each study microbe across all turbidity ranges were: MS2 (66%), C. parvum (49%), enterococci (85%), E. coli (81%), and C. perfringens (63%). The recovery efficiencies for MS2 and C. perfringens exhibited an inversely proportional relationship with turbidity, however no significant differences in recovery were observed for C. parvum, enterococci, or E. coli. Although ultrafilter clogging was observed, the DEUF method was able to process 100-L surface water samples at each turbidity level within 60 min. This study supports the use of the DEUF method for recovering a wide array of microbes in large-volume surface water samples having medium to high turbidity. Published by Elsevier B.V.

  20. Prospect of life on cold planets with low atmospheric pressures

    NASA Astrophysics Data System (ADS)

    Pavlov, A. A.; Vdovina, M.

    2009-12-01

    Stable liquid water on the surface of a planet has been viewed as the major requirement for a habitable planet. Such approach would exclude planets with low atmospheric pressures and cold mean surface temperatures (like present Mars) as potential candidates for extraterrestrial life search. Here we explore a possibility of the liquid water formation in the extremely shallow (1-3 cm) subsurface layer under low atmospheric pressures (0.1-10 mbar) and low average surface temperatures (~-30 C). During brief periods of simulated daylight warming the shallow subsurface ice sublimates, the water vapor can diffuse through the porous surface layer of soil temporarily producing supersaturated conditions in the soil, which lead to the formation of liquid films. We show that non-extremophile terrestrial microorganisms (Vibrio sp.) can grow and reproduce under such conditions. The necessary conditions for metabolism and reproduction are the sublimation of ground ice through a thin layer of soil and short episodes of warm temperatures at the planetary surface.

  1. Methylmercury production in and export from agricultural wetlands in California, USA: the need to account for physical transport processes into and out of the root zone

    USGS Publications Warehouse

    Bachand, Philip A.M.; Bachand, Sandra M.; Fleck, Jacob A.; Alpers, Charles N.; Stephenson, Mark; Windham-Myers, Lisamarie

    2014-01-01

    Concentration and mass balance analyses were used to quantify methylmercury (MeHg) loads from conventional (white) rice, wild rice, and fallowed fields in northern California's Yolo Bypass. These analyses were standardized against chloride to distinguish transport pathways and net ecosystem production (NEP). During summer, chloride loads were both exported with surface water and moved into the root zone at a 2:1 ratio. MeHg and dissolved organic carbon (DOC) behaved similarly with surface water and root zone exports at ~ 3:1 ratio. These trends reversed in winter with DOC, MeHg, and chloride moving from the root zone to surface waters at rates opposite and exceeding summertime root zone fluxes. These trends suggest that summer transpiration advectively moves constituents from surface water into the root zone, and winter diffusion, driven by concentration gradients, subsequently releases those constituents into surface waters. The results challenge a number of paradigms regarding MeHg. Specifically, biogeochemical conditions favoring microbial MeHg production do not necessarily translate to synchronous surface water exports; MeHg may be preserved in the soils allowing for release at a later time; and plants play a role in both biogeochemistry and transport. Our calculations show that NEP of MeHg occurred during both summer irrigation and winter flooding. Wild rice wet harvesting and winter flooding of white rice fields were specific practices that increased MeHg export, both presumably related to increased labile organic carbon and disturbance. Outflow management during these times could reduce MeHg exports. Standardizing MeHg outflow:inflow concentration ratios against natural tracers (e.g. chloride, EC) provides a simple tool to identify NEP periods. Summer MeHg exports averaged 0.2 to 1 μg m− 2 for the different agricultural wetland fields, depending upon flood duration. Average winter MeHg exports were estimated at 0.3 μg m− 2. These exports are within the range reported for other shallow aquatic systems.

  2. Methylmercury production in and export from agricultural wetlands in California, USA: the need to account for physical transport processes into and out of the root zone.

    PubMed

    Bachand, P A M; Bachand, S M; Fleck, J A; Alpers, C N; Stephenson, M; Windham-Myers, L

    2014-02-15

    Concentration and mass balance analyses were used to quantify methylmercury (MeHg) loads from conventional (white) rice, wild rice, and fallowed fields in northern California's Yolo Bypass. These analyses were standardized against chloride to distinguish transport pathways and net ecosystem production (NEP). During summer, chloride loads were both exported with surface water and moved into the root zone at a 2:1 ratio. MeHg and dissolved organic carbon (DOC) behaved similarly with surface water and root zone exports at ~3:1 ratio. These trends reversed in winter with DOC, MeHg, and chloride moving from the root zone to surface waters at rates opposite and exceeding summertime root zone fluxes. These trends suggest that summer transpiration advectively moves constituents from surface water into the root zone, and winter diffusion, driven by concentration gradients, subsequently releases those constituents into surface waters. The results challenge a number of paradigms regarding MeHg. Specifically, biogeochemical conditions favoring microbial MeHg production do not necessarily translate to synchronous surface water exports; MeHg may be preserved in the soils allowing for release at a later time; and plants play a role in both biogeochemistry and transport. Our calculations show that NEP of MeHg occurred during both summer irrigation and winter flooding. Wild rice wet harvesting and winter flooding of white rice fields were specific practices that increased MeHg export, both presumably related to increased labile organic carbon and disturbance. Outflow management during these times could reduce MeHg exports. Standardizing MeHg outflow:inflow concentration ratios against natural tracers (e.g. chloride, EC) provides a simple tool to identify NEP periods. Summer MeHg exports averaged 0.2 to 1 μg m(-2) for the different agricultural wetland fields, depending upon flood duration. Average winter MeHg exports were estimated at 0.3 μg m(-2). These exports are within the range reported for other shallow aquatic systems. Copyright © 2013 Elsevier B.V. All rights reserved.

  3. Rare earth elements (REE) and yttrium in stream waters, stream sediments, and Fe Mn oxyhydroxides: Fractionation, speciation, and controls over REE + Y patterns in the surface environment

    NASA Astrophysics Data System (ADS)

    Leybourne, Matthew I.; Johannesson, Karen H.

    2008-12-01

    We have collected ˜500 stream waters and associated bed-load sediments over an ˜400 km 2 region of Eastern Canada and analyzed these samples for Fe, Mn, and the rare earth elements (REE + Y). In addition to analyzing the stream sediments by total digestion (multi-acid dissolution with metaborate fusion), we also leached the sediments with 0.25 M hydroxylamine hydrochloride (in 0.05 M HCl), to determine the REE + Y associated with amorphous Fe- and Mn-oxyhydroxide phases. We are thus able to partition the REE into "dissolved" (<0.45 μm), labile (hydroxylamine) and detrital sediment fractions to investigate REE fractionation, and in particular, with respect to the development of Ce and Eu anomalies in oxygenated surface environments. Surface waters are typically LREE depleted ([La/Sm] NASC ranges from 0.16 to 5.84, average = 0.604, n = 410; where the REE are normalized to the North America Shale Composite), have strongly negative Ce anomalies ([Ce/Ce ∗] NASC ranges from 0.02 to 1.25, average = 0.277, n = 354), and commonly have positive Eu anomalies ([Eu/Eu ∗] NASC ranges from 0.295 to 1.77, average = 0.764, n = 84). In contrast, the total sediment have flatter REE + Y patterns relative to NASC ([La/Sm] NASC ranges from 0.352 to 1.12, average = 0.778, n = 451) and are slightly middle REE enriched ([Gd/Yb] NASC ranges from 0.55 to 3.75, average = 1.42). Most total sediments have negative Ce and Eu anomalies ([Ce/Ce ∗] NASC ranges from 0.097 to 2.12, average = 0.799 and [Eu/Eu ∗] NASC ranges from 0.39 to 1.43, average = 0.802). The partial extraction sediments are commonly less LREE depleted than the total sediments ([La/Sm] NASC ranges from 0.24 to 3.31, average = 0.901, n = 4537), more MREE enriched ([Gd/Yb] NASC ranges from 0.765 to 6.28, average = 1.97) and Ce and Eu anomalies (negative and positive) are more pronounced. The partial extraction recovered, on average ˜20% of the Fe in the total sediment, ˜80% of the Mn, and 21-29% of the REEs (Ce = 19% and Y = 32%). Comparison between REEs in water, partial extraction and total sediment analyses indicates that REEs + Y in the stream sediments have two primary sources, the host lithologies (i.e., mechanical dispersion) and hydromorphically transported (the labile fraction). Furthermore, Eu appears to be more mobile than the other REE, whereas Ce is preferentially removed from solution and accumulates in the stream sediments in a less labile form than the other REEs + Y. Despite poor statistical correlations between the REEs + Y and Mn in either the total sediment or partial extractions, based on apparent distribution coefficients and the pH of the stream waters, we suggest that either sediment organic matter and/or possibly δ-MnO 2/FeOOH are likely the predominant sinks for Ce, and to a lesser extent the other REE, in the stream sediments.

  4. Recharging California's Groundwater: Crop Suitability and Surface Water Availability for Agricultural Groundwater Banking

    NASA Astrophysics Data System (ADS)

    Dahlke, H. E.; Kocis, T. N.; Brown, A.

    2016-12-01

    Groundwater banking, the intentional recharge of groundwater from surface water for storage and recovery, is an important conjunctive use strategy for water management in California (CA). A largely unexplored approach to groundwater banking, agricultural groundwater banking (ag-GB), utilizes flood flows and agricultural lands (alfalfa/pasture) for recharging groundwater. Understanding soil suitability for ag-GB, crop health and flooding tolerance, leaching of soil nitrate and salts, the availability of surface water for recharge, and the economic costs and benefits of ag-GB is fundamental to assessing the feasibility of local-scale implementation of ag-GB. The study presented here considers both the availability of excess streamflow (e.g., the magnitude, frequency, timing, and duration of winter flood flow) for ag-GB and the risks and benefits associated with using alfalfa fields as spreading grounds for ag-GB. The availability of surface water for winter (Nov to Apr) ag-GB were estimated based on daily streamflow records for 93 stream gauges within the Central Valley, CA. Analysis focused on high-magnitude (>90thpercentile) flows because most lower flows are likely legally allocated in CA. Results based >50 years of data indicate that an average winter/spring (Nov. - Apr.) in the Sacramento River Basin could provide 7 million acre-feet (AF) (8.6 km3) of water for ag-GB from flows above the 90th percentile. These flows originate from few storm events (5-7 events) and occur on average for 25-30 days between November and April. Wintertime on-farm recharge experiments were conducted on a 9-yr old, 15-acre alfalfa field in the Scott Valley, CA, where 135 AF and 107 AF of water were recharged during the winters of 2015 and 2016, respectively. Biomass data collected indicates that pulsed application of 6-10 ft of water on dormant alfalfa results in minimal yield loss (0.5 ton/acre reduction), short-duration saturated conditions in the root-zone, and high recharge fractions (70-95%) of applied water. Together these results highlight the opportunity and potential benefits for growers and water districts to implement ag-GB as part of the sustainable groundwater management plans.

  5. The water footprint of humanity

    NASA Astrophysics Data System (ADS)

    Mekonnen, M. M.; Hoekstra, A. Y.

    2011-12-01

    This study quantifies and maps the water footprint (WF) of humanity at a high spatial resolution level. It reports on consumptive use of rainwater (green WF) and ground and surface water (blue WF) and volumes of water polluted (grey WF). Water footprints are estimated per nation from both a production and consumption perspective. International virtual water flows are estimated based on trade in agricultural and industrial commodities. The global WF in the period 1996-2005 was 9087 Gm3/yr (74% green, 11% blue, 15% grey). Agricultural production contributes 92%. About one fifth of the global WF relates to production for export. The total volume of international virtual water flows related to trade in agricultural and industrial products was 2320 Gm3/yr (68% green, 13% blue, 19% grey). The WF of the global average consumer was 1385 m3/yr. The average consumer in the US has a WF of 2842 m3/yr, while the average citizens in China and India have WFs of 1071 m3/yr and 1089 m3/yr, respectively. Consumption of cereal products gives the largest contribution to the WF of the average consumer (27%), followed by meat (22%) and milk products (7%). The volume and pattern of consumption and the WF per ton of product of the products consumed are the main factors determining the WF of a consumer. The study illustrates the global dimension of water consumption and pollution by showing that several countries heavily rely on foreign water resources and that many countries have significant impacts on water consumption and pollution elsewhere.

  6. Improved Detection of Norovirus and Hepatitis A Virus in Surface Water by Applying Pre-PCR Processing.

    PubMed

    Borgmästars, Emmy; Jazi, Mehrdad Mousavi; Persson, Sofia; Jansson, Linda; Rådström, Peter; Simonsson, Magnus; Hedman, Johannes; Eriksson, Ronnie

    2017-12-01

    Quantitative reverse transcriptase polymerase chain reaction (RT-qPCR) detection of waterborne RNA viruses generally requires concentration of large water volumes due to low virus levels. A common approach is to use dead-end ultrafiltration followed by precipitation with polyethylene glycol. However, this procedure often leads to the co-concentration of PCR inhibitors that impairs the limit of detection and causes false-negative results. Here, we applied the concept of pre-PCR processing to optimize RT-qPCR detection of norovirus genogroup I (GI), genogroup II (GII), and hepatitis A virus (HAV) in challenging water matrices. The RT-qPCR assay was improved by screening for an inhibitor-tolerant master mix and modifying the primers with twisted intercalating nucleic acid molecules. Additionally, a modified protocol based on chaotropic lysis buffer and magnetic silica bead nucleic acid extraction was developed for complex water matrices. A validation of the modified extraction protocol on surface and drinking waters was performed. At least a 26-fold improvement was seen in the most complex surface water studied. The modified protocol resulted in average recoveries of 33, 13, 8, and 4% for mengovirus, norovirus GI, GII, and HAV, respectively. The modified protocol also improved the limit of detection for norovirus GI and HAV. RT-qPCR inhibition with C q shifts of 1.6, 2.8, and 3.5 for norovirus GI, GII, and HAV, respectively, obtained for the standard nucleic acid extraction were completely eliminated by the modified protocol. The standard nucleic acid extraction method worked well on drinking water with no RT-qPCR inhibition observed and average recoveries of 80, 124, 89, and 32% for mengovirus, norovirus GI, GII, and HAV, respectively.

  7. Global Distribution of Outbreaks of Water-Associated Infectious Diseases

    PubMed Central

    Yang, Kun; LeJeune, Jeffrey; Alsdorf, Doug; Lu, Bo; Shum, C. K.; Liang, Song

    2012-01-01

    Background Water plays an important role in the transmission of many infectious diseases, which pose a great burden on global public health. However, the global distribution of these water-associated infectious diseases and underlying factors remain largely unexplored. Methods and Findings Based on the Global Infectious Disease and Epidemiology Network (GIDEON), a global database including water-associated pathogens and diseases was developed. In this study, reported outbreak events associated with corresponding water-associated infectious diseases from 1991 to 2008 were extracted from the database. The location of each reported outbreak event was identified and geocoded into a GIS database. Also collected in the GIS database included geo-referenced socio-environmental information including population density (2000), annual accumulated temperature, surface water area, and average annual precipitation. Poisson models with Bayesian inference were developed to explore the association between these socio-environmental factors and distribution of the reported outbreak events. Based on model predictions a global relative risk map was generated. A total of 1,428 reported outbreak events were retrieved from the database. The analysis suggested that outbreaks of water-associated diseases are significantly correlated with socio-environmental factors. Population density is a significant risk factor for all categories of reported outbreaks of water-associated diseases; water-related diseases (e.g., vector-borne diseases) are associated with accumulated temperature; water-washed diseases (e.g., conjunctivitis) are inversely related to surface water area; both water-borne and water-related diseases are inversely related to average annual rainfall. Based on the model predictions, “hotspots” of risks for all categories of water-associated diseases were explored. Conclusions At the global scale, water-associated infectious diseases are significantly correlated with socio-environmental factors, impacting all regions which are affected disproportionately by different categories of water-associated infectious diseases. PMID:22348158

  8. Quantification of surface water volume changes in the Mackenzie Delta using satellite multi-mission data

    NASA Astrophysics Data System (ADS)

    Normandin, Cassandra; Frappart, Frédéric; Lubac, Bertrand; Bélanger, Simon; Marieu, Vincent; Blarel, Fabien; Robinet, Arthur; Guiastrennec-Faugas, Léa

    2018-02-01

    Quantification of surface water storage in extensive floodplains and their dynamics are crucial for a better understanding of global hydrological and biogeochemical cycles. In this study, we present estimates of both surface water extent and storage combining multi-mission remotely sensed observations and their temporal evolution over more than 15 years in the Mackenzie Delta. The Mackenzie Delta is located in the northwest of Canada and is the second largest delta in the Arctic Ocean. The delta is frozen from October to May and the recurrent ice break-up provokes an increase in the river's flows. Thus, this phenomenon causes intensive floods along the delta every year, with dramatic environmental impacts. In this study, the dynamics of surface water extent and volume are analysed from 2000 to 2015 by combining multi-satellite information from MODIS multispectral images at 500 m spatial resolution and river stages derived from ERS-2 (1995-2003), ENVISAT (2002-2010) and SARAL (since 2013) altimetry data. The surface water extent (permanent water and flooded area) peaked in June with an area of 9600 km2 (±200 km2) on average, representing approximately 70 % of the delta's total surface. Altimetry-based water levels exhibit annual amplitudes ranging from 4 m in the downstream part to more than 10 m in the upstream part of the Mackenzie Delta. A high overall correlation between the satellite-derived and in situ water heights (R > 0.84) is found for the three altimetry missions. Finally, using altimetry-based water levels and MODIS-derived surface water extents, maps of interpolated water heights over the surface water extents are produced. Results indicate a high variability of the water height magnitude that can reach 10 m compared to the lowest water height in the upstream part of the delta during the flood peak in June. Furthermore, the total surface water volume is estimated and shows an annual variation of approximately 8.5 km3 during the whole study period, with a maximum of 14.4 km3 observed in 2006. The good agreement between the total surface water volume retrievals and in situ river discharges (R = 0.66) allows for validation of this innovative multi-mission approach and highlights the high potential to study the surface water extent dynamics.

  9. Estimating spatially and temporally varying recharge and runoff from precipitation and urban irrigation in the Los Angeles Basin, California

    USGS Publications Warehouse

    Hevesi, Joseph A.; Johnson, Tyler D.

    2016-10-17

    A daily precipitation-runoff model, referred to as the Los Angeles Basin watershed model (LABWM), was used to estimate recharge and runoff for a 5,047 square kilometer study area that included the greater Los Angeles area and all surface-water drainages potentially contributing recharge to a 1,450 square kilometer groundwater-study area underlying the greater Los Angeles area, referred to as the Los Angeles groundwater-study area. The recharge estimates for the Los Angeles groundwater-study area included spatially distributed recharge in response to the infiltration of precipitation, runoff, and urban irrigation, as well as mountain-front recharge from surface-water drainages bordering the groundwater-study area. The recharge and runoff estimates incorporated a new method for estimating urban irrigation, consisting of residential and commercial landscape watering, based on land use and the percentage of pervious land area.The LABWM used a 201.17-meter gridded discretization of the study area to represent spatially distributed climate and watershed characteristics affecting the surface and shallow sub-surface hydrology for the Los Angeles groundwater study area. Climate data from a local network of 201 monitoring sites and published maps of 30-year-average monthly precipitation and maximum and minimum air temperature were used to develop the climate inputs for the LABWM. Published maps of land use, land cover, soils, vegetation, and surficial geology were used to represent the physical characteristics of the LABWM area. The LABWM was calibrated to available streamflow records at six streamflow-gaging stations.Model results for a 100-year target-simulation period, from water years 1915 through 2014, were used to quantify and evaluate the spatial and temporal variability of water-budget components, including evapotranspiration (ET), recharge, and runoff. The largest outflow of water from the LABWM was ET; the 100-year average ET rate of 362 millimeters per year (mm/yr) accounted for 66 percent of the combined water inflow of 551 mm/yr, including 488 mm/yr from precipitation and 63 mm/yr from urban irrigation. The simulated ET rate varied from a minimum of 0 mm/yr for impervious areas to high values of more than 1,000 mm/yr for many areas, including the south-facing slopes of the San Gabriel Mountains, stream channels underlain by permeable soils and thick root zones, and pervious locations receiving inflows both from urban irrigation and surface water. Runoff was the next largest outflow, averaging 145 mm/yr for the 100-year period, or 26 percent of the combined precipitation and urban-irrigation inflow. Recharge averaged 45 mm/yr, or about 8 percent of the combined inflow from precipitation and urban irrigation.Simulation results indicated that recharge in response to urban irrigation was an important component of spatially distributed recharge, contributing an average of 56 percent of the total recharge to the eight LABWM subdomains containing the Los Angeles groundwater study area. The 100‑year average recharge rate for the eight subdomains was 41 mm/yr, or 8,473 hectare-meters per year (ha-m/yr), with urban irrigation included in the simulation compared to a recharge rate of 18 mm/yr, or 3,741 ha-m/yr, with urban irrigation excluded. In contrast to recharge, the effect of urban irrigation on runoff was slight; runoff was 72,667 ha-m/yr with urban irrigation included compared to 72,618 ha-m/yr with urban irrigation excluded, an increase of only 48 ha-m/yr (about 0.1 percent).Simulation results also indicated that potential recharge from hilly drainages outside of, but bordering and tributary to, the lower-lying area of the Los Angeles groundwater study area, in this study referred to as mountain-front recharge, could provide an important contribution to the total recharge for the groundwater basins. The time-averaged recharge rate was similar to the combined direct and mountain-front recharge components estimated in a previous study and used as input for a calibrated groundwater model. The annual (water year) recharge estimates simulated in this study, however, indicated much greater year-to-year variability, which was dependent on year-to-year variability in the magnitude and distribution of daily precipitation, compared to the previous estimates.

  10. Estimation of River Bathymetry from ATI-SAR Data

    NASA Astrophysics Data System (ADS)

    Almeida, T. G.; Walker, D. T.; Farquharson, G.

    2013-12-01

    A framework for estimation of river bathymetry from surface velocity observation data is presented using variational inverse modeling applied to the 2D depth-averaged, shallow-water equations (SWEs) including bottom friction. We start with with a cost function defined by the error between observed and estimated surface velocities, and introduce the SWEs as a constraint on the velocity field. The constrained minimization problem is converted to an unconstrained minimization through the use of Lagrange multipliers, and an adjoint SWE model is developed. The adjoint model solution is used to calculate the gradient of the cost function with respect to river bathymetry. The gradient is used in a descent algorithm to determine the bathymetry that yields a surface velocity field that is a best-fit to the observational data. In applying the algorithm, the 2D depth-averaged flow is computed assuming a known, constant discharge rate and a known, uniform bottom-friction coefficient; a correlation relating surface velocity and depth-averaged velocity is also used. Observation data was collected using a dual beam squinted along-track-interferometric, synthetic-aperture radar (ATI-SAR) system, which provides two independent components of the surface velocity, oriented roughly 30 degrees fore and aft of broadside, offering high-resolution bank-to-bank velocity vector coverage of the river. Data and bathymetry estimation results are presented for two rivers, the Snohomish River near Everett, WA and the upper Sacramento River, north of Colusa, CA. The algorithm results are compared to available measured bathymetry data, with favorable results. General trends show that the water-depth estimates are most accurate in shallow regions, and performance is sensitive to the accuracy of the specified discharge rate and bottom friction coefficient. The results also indicate that, for a given reach, the estimated water depth reaches a maximum that is smaller than the true depth; this apparent maximum depth scales with the true river depth and discharge rate, so that the deepest parts of the river show the largest bathymetry errors.

  11. Estimating lake-water evaporation from data of large-aperture scintillometer in the Badain Jaran Desert, China, with two comparable methods

    NASA Astrophysics Data System (ADS)

    Han, Peng-Fei; Wang, Xu-Sheng; Jin, Xiaomei; Hu, Bill X.

    2018-06-01

    Accurate quantification of evaporation (E0) from open water is vital in arid regions for water resource management and planning, especially for lakes in the desert. The scintillometers are increasingly recognized by researchers for their ability to determine sensible (H) and latent heat fluxes (LE) accurately over distances of hundreds of meters to several kilometers, though scintillometers are mainly used to monitor the land surface processes. In this paper, it is installed on both sides of the shore over a lake. Compared to the data of evaporationpan, the scintillometer was successfully applied to Sumu Barun Jaran in Badain Jaran Desert using the classical method and the proposed linearized β method. Due to the difficulty in measuring water surface temperature and the easiness to monitor the water temperature at different depths, it is worth thinking that if is feasible to utilize the shallow water temperature instead of the water surface temperature and how much errors it will cause. Water temperature at 10 and 20 cm depths were used to replace the lakewater surface temperature in the two methods to analyze the changes of sensible and latent heat fluxes in hot and cold seasons at halfhour time scales. Based on the classical method, the values of H were almost barely affected, and the average value of LE using water temperature at 20 cm depth is 0.8-9.5 % smaller than that at 10 cm depth in cold seasons. In hot seasons, compared to the results at 10 cm depth, the average value of H increased by 20-30 %, and LE decreased by about 20 % at 20 cm depth. In the proposed linearized β method of scintillometer, only the slope of the saturation pressure curve (Δ) is related to the water surface temperature, which was estimated using available equations of saturated vapor pressure versus temperature of the air. Compared to the values of estimated by the air temperature, while the water surface temperature are replaced by water temperature at 10 and 20 cm depths, in different seasons, the errors of 2-25 % in Δ were caused. Thus was calculated by the original equation in the proposed linearized β method of scintillometer. Interestingly, the water temperature at 10 and 20 cm depths had little effect on H, LE (E0) in different seasons. The reason is that the drying power of the air (EA) accounted for about 85 % of the evaporation (i.e. the changes of Δ have only about 3 % impact on evaporation), which indicated that the driving force from unsaturated to saturated vapor pressure at 2 m height (i.e. the aerodynamic portion) has the main role on evaporation. Therefore, the proposed linearized β method of scintillometer is recommended to quantify the H, LE (E0) over open water, especially when the water surface temperature cannot be accurately measured.

  12. Soil-water content characterisation in a modified Jarvis-Stewart model: A case study of a conifer forest on a shallow unconfined aquifer

    NASA Astrophysics Data System (ADS)

    Guyot, Adrien; Fan, Junliang; Oestergaard, Kasper T.; Whitley, Rhys; Gibbes, Badin; Arsac, Margaux; Lockington, David A.

    2017-01-01

    Groundwater-vegetation-atmosphere fluxes were monitored for a subtropical coastal conifer forest in South-East Queensland, Australia. Observations were used to quantify seasonal changes in transpiration rates with respect to temporal fluctuations of the local water table depth. The applicability of a Modified Jarvis-Stewart transpiration model (MJS), which requires soil-water content data, was assessed for this system. The influence of single depth values compared to use of vertically averaged soil-water content data on MJS-modelled transpiration was assessed over both a wet and a dry season, where the water table depth varied from the surface to a depth of 1.4 m below the surface. Data for tree transpiration rates relative to water table depth showed that trees transpire when the water table was above a threshold depth of 0.8 m below the ground surface (water availability is non-limiting). When the water table reached the ground surface (i.e., surface flooding) transpiration was found to be limited. When the water table is below this threshold depth, a linear relationship between water table depth and the transpiration rate was observed. MJS modelling results show that the influence of different choices for soil-water content on transpiration predictions was insignificant in the wet season. However, during the dry season, inclusion of deeper soil-water content data improved the model performance (except for days after isolated rainfall events, here a shallower soil-water representation was better). This study demonstrated that, to improve MJS simulation results, appropriate selection of soil water measurement depths based on the dynamic behaviour of soil water profiles through the root zone was required in a shallow unconfined aquifer system.

  13. Methane emissions to the troposphere from the Amazon floodplain

    NASA Technical Reports Server (NTRS)

    Devol, Allen H.; Richey, Jeffrey E.; Clark, Wayne A.; King, Stagg L.; Martinelli, Luiz A.

    1988-01-01

    The magnitudes of CH4 emissions to the troposphere from the Amazon River floodplain and the mechanism of these emissions were investigated using the data of 94 individual flux measurements made along a 1700-km stretch of the river during July/August 1985. The overall average rate of CH4 emission from wetlands was found to be 390 mg CH4/sq m per day, with the highest emissions (590 mg CH4/sq m per day) attributed to the water surfaces covered by aquatic macrophytes. Ebullition was the dominant mechanism of emission, accounting for 85 percent of the total. Surface-water CH4 concentrations were highly supersaturated, averaging 6.4 micromolar. The annual emission of CH4 from the Amazon Basin to the troposphere, estimated from the area and the known emission rate, is about 10 CH4 Tg/yr, indicating the importance of the area in the global atmospheric CH4 cycle.

  14. Dissolved and particulate trace metals in coastal waters of the Gulf and Western Arabian Sea

    NASA Astrophysics Data System (ADS)

    Fowler, S. W.; Huynh-Ngoc, L.; Fukai, R.

    Concentrations of chemical species of selected heavy metals (Cu, Zn, Cd, Hg and Pb) were determined in surface waters from a series of coastal sites in Bahrain, United Arab Emirates (UAE) and the Sultanate of Oman. Analyses were carried out on bulk sea water samples as well as on suspended particulates by anodic stripping voltammetry. Heavy metal concentrations were relatively low with the exception of some "hot spots" which occurred in the vicinity of industrial and port activities. Average copper levels along the coast of UAE were generally higher than those measured in sea water from either Bahrain of Oman. Waters from the more populated and industrialised northwest coast of Oman were found to contain approximately 3 to 4-fold higher Cd and Zn (pH 4-4.5) concentrations than those from the southern coast, an undeveloped region adjacent to the more open waters of the Arabian Sea. Possible reasons for the observed regional variations in trace metal concentrations in Oman are discussed in terms of natural and anthropogenic input sources. Average concentrations in the Gulf (inside the Strait of Hormuz) were 510 ng 1 -1 (Cu), 340 ng 1 -1 (Zn), 20 ng 1 -1 (Cd), 16 ng 1 -1 (Hg) and 76 ng 1 -1 (Pb); in the western Arabian Sea along the coast of Oman concentrations averaged 290 ng 1 -1 (Cu), 180 ng 1 -1 (Zn), 37 ng 1 -1 (Cd), 11 ng 1 -1 (Hg) and 80 ng 1 -1 (Pb). Ranges of concentrations for these metals in Gulf and western Arabian Sea waters approach those which have been reported for open surface waters of the Atlantic, Pacific, Indian Oceans and the Mediterranean Sea indicating that, in general, the coastal waters of this region are not impacted by metal pollution and that the existing natural levels can be used as a point of reference for future pollutant studies.

  15. The tidally averaged momentum balance in a partially and periodically stratified estuary

    USGS Publications Warehouse

    Stacey, M.T.; Brennan, Matthew L.; Burau, J.R.; Monismith, Stephen G.

    2010-01-01

    Observations of turbulent stresses and mean velocities over an entire spring-neap cycle are used to evaluate the dynamics of tidally averaged flows in a partially stratified estuarine channel. In a depth-averaged sense, the net flow in this channel is up estuary due to interaction of tidal forcing with the geometry of the larger basin. The depth-variable tidally averaged flow has the form of an estuarine exchange flow (downstream at the surface, upstream at depth) and varies in response to the neap-spring transition. The weakening of the tidally averaged exchange during the spring tides appears to be a result of decreased stratification on the tidal time scale rather than changes in bed stress. The dynamics of the estuarine exchange flow are defined by a balance between the vertical divergence of the tidally averaged turbulent stress and the tidally averaged pressure gradient in the lower water column. In the upper water column, tidal stresses are important contributors, particularly during the neap tides. The usefulness of an effective eddy viscosity in the tidally averaged momentum equation is explored, and it is seen that the effective eddy viscosity on the subtidal time scale would need to be negative to close the momentum balance. This is due to the dominant contribution of tidally varying turbulent momentum fluxes, which have no specific relation to the subtidal circulation. Using a water column model, the validity of an effective eddy viscosity is explored; for periodically stratified water columns, a negative effective viscosity is required. ?? 2010 American Meteorological Society.

  16. The Influence of a Sandy Substrate, Seagrass, or Highly Turbid Water on Albedo and Surface Heat Flux

    NASA Astrophysics Data System (ADS)

    Fogarty, M. C.; Fewings, M. R.; Paget, A. C.; Dierssen, H. M.

    2018-01-01

    Sea-surface albedo is a combination of surface-reflected and water-leaving irradiance, but water-leaving irradiance typically contributes less than 15% of the total albedo in open-ocean conditions. In coastal systems, however, the bottom substrate or suspended particulate matter can increase the amount of backscattered light, thereby increasing albedo and decreasing net shortwave surface heat flux. Here a sensitivity analysis using observations and models predicts the effect of light scattering on albedo and the net shortwave heat flux for three test cases: a bright sand bottom, a seagrass canopy, and turbid water. After scaling to the full solar shortwave spectrum, daytime average albedo for the test cases is up to 0.20 and exceeds the value of 0.05 predicted using a commonly applied parameterization. Daytime net shortwave heat flux into the water is significantly reduced, particularly for waters with bright sediments, dense horizontal seagrass canopies < 0.25 m from the sea surface, or highly turbid waters with suspended particulate matter concentration ≥ 50 g m-3. Observations of a more vertical seagrass canopy within 0.2 and 1 m of the surface indicate the increase in albedo compared to the common parameterization is negligible. Therefore, we suggest that the commonly applied albedo lookup table can be used in coastal heat flux estimates in water as shallow as 1 m unless the bottom substrate is highly reflective or the water is highly turbid. Our model results provide guidance to researchers who need to determine albedo in highly reflective or highly turbid conditions but have no direct observations.

  17. Definition of SMOS Level 3 Land Products for the Villafranca del Castillo Data Processing Centre (CP34)

    NASA Astrophysics Data System (ADS)

    Lopez-Baeza, E.; Monsoriu Torres, A.; Font, J.; Alonso, O.

    2009-04-01

    The ESA SMOS (Soil Moisture and Ocean Salinity) Mission is planned to be launched in July 2009. The satellite will measure soil moisture over the continents and surface salinity of the oceans at resolutions that are sufficient for climatological-type studies. This paper describes the procedure to be used at the Spanish SMOS Level 3 and 4 Data Processing Centre (CP34) to generate Soil Moisture and other Land Surface Product maps from SMOS Level 2 data. This procedure can be used to map Soil Moisture, Vegetation Water Content and Soil Dielectric Constant data into different pre-defined spatial grids with fixed temporal frequency. The L3 standard Land Surface Products to be generated at CP34 are: Soil Moisture products: maximum spatial resolution with no spatial averaging, temporal averaging of 3 days, daily generation maximum spatial resolution with no spatial averaging, temporal averaging of 10 days, generation frequency of once every 10 days. b': maximum spatial resolution with no spatial averaging, temporal averaging of monthly decades (1st to 10th of the month, 11th to 20th of the month, 21st to last day of the month), generation frequency of once every decade monthly average, temporal averaging from L3 decade averages, monthly generation Seasonal average, temporal averaging from L3 monthly averages, seasonally generation yearly average, temporal averaging from L3 monthly averages, yearly generation Vegetation Water Content products: maximum spatial resolution with no spatial averaging, temporal averaging of 10 days, generation frequency of once every 10 days. a': maximum spatial resolution with no spatial averaging, temporal averaging of monthly decades (1st to 10th of the month, 11th to 20th of the month, 21st to last day of the month) using simple averaging method over the L2 products in ISEA grid, generation frequency of once every decade monthly average, temporal averaging from L3 decade averages, monthly generation seasonal average, temporal averaging from L3 monthly averages, seasonally generation yearly average, temporal averaging from L3 monthly averages, yearly generation Dielectric Constant products: (the dielectric constant products are delivered together with soil moisture products, with the same averaging periods and generation frequency): maximum spatial resolution with no spatial averaging, temporal averaging of 3 days, daily generation maximum spatial resolution with no spatial averaging, temporal averaging of 10 days, generation frequency of once every 10 days. b': maximum spatial resolution with no spatial averaging, temporal averaging of monthly decades (1st to 10th of the month, 11th to 20th of the month, 21st to last day of the month), generation frequency of once every decade monthly average, temporal averaging from L3 decade averages, monthly generation seasonal average, temporal averaging from L3 monthly averages, seasonally generation yearly average, temporal averaging from L3 monthly averages, yearly generation.

  18. Characterizing groundwater/surface-water interactions in the interior of Jianghan Plain, central China

    NASA Astrophysics Data System (ADS)

    Du, Yao; Ma, Teng; Deng, Yamin; Shen, Shuai; Lu, Zongjie

    2018-06-01

    Quantifying groundwater/surface-water interactions is essential for managing water resources and revealing contaminant fate. There has been little concern on the exchange between streams and aquifers through an extensive aquitard thus far. In this study, hydrogeologic calculation and tritium modeling were jointly applied to characterize such interactions through an extensive aquitard in the interior of Jianghan Plain, an alluvial plain of Yangtze River, China. One groundwater simulation suggested that the lateral distance of influence from the river was about 1,000 m; vertical flow in the aquitard followed by lateral flow in the aquifer contributed significantly more ( 90%) to the aquifer head change near the river than lateral bank storage in the aquitard followed by infiltration. The hydrogeologic calculation produced vertical fluxes of the order 0.01 m/day both near and farther from the river, suggesting that similar shorter-lived (half-monthly) vertical fluxes occur between the river and aquitard near the river, and between the surface end members and aquitard farther from the river. Tritium simulation based on the OTIS model produced an average groundwater residence time of about 15 years near the river and a resulting vertical flux of the order 0.001 m/day. Another tritium simulation based on a dispersion model produced a vertical flux of the order 0.0001 m/day away from the river, coupled with an average residence time of around 90 years. These results suggest an order of magnitude difference for the longer-lived (decadal) vertical fluxes between surface waters and the aquifer near and away from the river.

  19. Characterizing groundwater/surface-water interactions in the interior of Jianghan Plain, central China

    NASA Astrophysics Data System (ADS)

    Du, Yao; Ma, Teng; Deng, Yamin; Shen, Shuai; Lu, Zongjie

    2018-01-01

    Quantifying groundwater/surface-water interactions is essential for managing water resources and revealing contaminant fate. There has been little concern on the exchange between streams and aquifers through an extensive aquitard thus far. In this study, hydrogeologic calculation and tritium modeling were jointly applied to characterize such interactions through an extensive aquitard in the interior of Jianghan Plain, an alluvial plain of Yangtze River, China. One groundwater simulation suggested that the lateral distance of influence from the river was about 1,000 m; vertical flow in the aquitard followed by lateral flow in the aquifer contributed significantly more ( 90%) to the aquifer head change near the river than lateral bank storage in the aquitard followed by infiltration. The hydrogeologic calculation produced vertical fluxes of the order 0.01 m/day both near and farther from the river, suggesting that similar shorter-lived (half-monthly) vertical fluxes occur between the river and aquitard near the river, and between the surface end members and aquitard farther from the river. Tritium simulation based on the OTIS model produced an average groundwater residence time of about 15 years near the river and a resulting vertical flux of the order 0.001 m/day. Another tritium simulation based on a dispersion model produced a vertical flux of the order 0.0001 m/day away from the river, coupled with an average residence time of around 90 years. These results suggest an order of magnitude difference for the longer-lived (decadal) vertical fluxes between surface waters and the aquifer near and away from the river.

  20. Error analysis of 3D-PTV through unsteady interfaces

    NASA Astrophysics Data System (ADS)

    Akutina, Yulia; Mydlarski, Laurent; Gaskin, Susan; Eiff, Olivier

    2018-03-01

    The feasibility of stereoscopic flow measurements through an unsteady optical interface is investigated. Position errors produced by a wavy optical surface are determined analytically, as are the optimal viewing angles of the cameras to minimize such errors. Two methods of measuring the resulting velocity errors are proposed. These methods are applied to 3D particle tracking velocimetry (3D-PTV) data obtained through the free surface of a water flow within a cavity adjacent to a shallow channel. The experiments were performed using two sets of conditions, one having no strong surface perturbations, and the other exhibiting surface gravity waves. In the latter case, the amplitude of the gravity waves was 6% of the water depth, resulting in water surface inclinations of about 0.2°. (The water depth is used herein as a relevant length scale, because the measurements are performed in the entire water column. In a more general case, the relevant scale is the maximum distance from the interface to the measurement plane, H, which here is the same as the water depth.) It was found that the contribution of the waves to the overall measurement error is low. The absolute position errors of the system were moderate (1.2% of H). However, given that the velocity is calculated from the relative displacement of a particle between two frames, the errors in the measured water velocities were reasonably small, because the error in the velocity is the relative position error over the average displacement distance. The relative position error was measured to be 0.04% of H, resulting in small velocity errors of 0.3% of the free-stream velocity (equivalent to 1.1% of the average velocity in the domain). It is concluded that even though the absolute positions to which the velocity vectors are assigned is distorted by the unsteady interface, the magnitude of the velocity vectors themselves remains accurate as long as the waves are slowly varying (have low curvature). The stronger the disturbances on the interface are (high amplitude, short wave length), the smaller is the distance from the interface at which the measurements can be performed.

  1. Exploring the long-term balance between net precipitation and net groundwater exchange in Florida seepage lakes

    USGS Publications Warehouse

    Lee, Terrie M.; Sacks, Laura A.; Swancar, Amy

    2014-01-01

    The long-term balance between net precipitation and net groundwater exchange that maintains thousands of seepage lakes in Florida’s karst terrain is explored at a representative lake basin and then regionally for the State’s peninsular lake district. The 15-year water budget of Lake Starr includes El Niño Southern Oscillation (ENSO)-related extremes in rainfall, and provides the longest record of Bowen ratio energy-budget (BREB) lake evaporation and lake-groundwater exchanges in the southeastern United States. Negative net precipitation averaging -25 cm/yr at Lake Starr overturns the previously-held conclusion that lakes in this region receive surplus net precipitation. Net groundwater exchange with the lake was positive on average but too small to balance the net precipitation deficit. Groundwater pumping effects and surface-water withdrawals from the lake widened the imbalance. Satellite-based regional estimates of potential evapotranspiration at five large lakes in peninsular Florida compared well with basin-scale evaporation measurements from seven open-water sites that used BREB methods. The regional average lake evaporation estimated for Lake Starr during 1996-2011 was within 5 percent of its measured average, and regional net precipitation agreed within 10 percent. Regional net precipitation to lakes was negative throughout central peninsular Florida and the net precipitation deficit increased by about 20 cm from north to south. Results indicate that seepage lakes farther south on the peninsula receive greater net groundwater inflow than northern lakes and imply that northern lakes are in comparatively leakier hydrogeologic settings. Findings reveal the peninsular lake district to be more vulnerable than was previously realized to drier climate, surface-water withdrawals from lakes, and groundwater pumping effects.

  2. δ2H isotopic flux partitioning of evapotranspiration over a grass field following a water pulse and subsequent dry down

    NASA Astrophysics Data System (ADS)

    Good, Stephen P.; Soderberg, Keir; Guan, Kaiyu; King, Elizabeth G.; Scanlon, Todd M.; Caylor, Kelly K.

    2014-02-01

    The partitioning of surface vapor flux (FET) into evaporation (FE) and transpiration (FT) is theoretically possible because of distinct differences in end-member stable isotope composition. In this study, we combine high-frequency laser spectroscopy with eddy covariance techniques to critically evaluate isotope flux partitioning of FET over a grass field during a 15 day experiment. Following the application of a 30 mm water pulse, green grass coverage at the study site increased from 0 to 10% of ground surface area after 6 days and then began to senesce. Using isotope flux partitioning, transpiration increased as a fraction of total vapor flux from 0% to 40% during the green-up phase, after which this ratio decreased while exhibiting hysteresis with respect to green grass coverage. Daily daytime leaf-level gas exchange measurements compare well with daily isotope flux partitioning averages (RMSE = 0.0018 g m-2 s-1). Overall the average ratio of FT to FET was 29%, where uncertainties in Keeling plot intercepts and transpiration composition resulted in an average of uncertainty of ˜5% in our isotopic partitioning of FET. Flux-variance similarity partitioning was partially consistent with the isotope-based approach, with divergence occurring after rainfall and when the grass was stressed. Over the average diurnal cycle, local meteorological conditions, particularly net radiation and relative humidity, are shown to control partitioning. At longer time scales, green leaf area and available soil water control FT/FET. Finally, we demonstrate the feasibility of combining isotope flux partitioning and flux-variance similarity theory to estimate water use efficiency at the landscape scale.

  3. Water resources in the Big Lost River Basin, south-central Idaho

    USGS Publications Warehouse

    Crosthwaite, E.G.; Thomas, C.A.; Dyer, K.L.

    1970-01-01

    The Big Lost River basin occupies about 1,400 square miles in south-central Idaho and drains to the Snake River Plain. The economy in the area is based on irrigation agriculture and stockraising. The basin is underlain by a diverse-assemblage of rocks which range, in age from Precambrian to Holocene. The assemblage is divided into five groups on the basis of their hydrologic characteristics. Carbonate rocks, noncarbonate rocks, cemented alluvial deposits, unconsolidated alluvial deposits, and basalt. The principal aquifer is unconsolidated alluvial fill that is several thousand feet thick in the main valley. The carbonate rocks are the major bedrock aquifer. They absorb a significant amount of precipitation and, in places, are very permeable as evidenced by large springs discharging from or near exposures of carbonate rocks. Only the alluvium, carbonate rock and locally the basalt yield significant amounts of water. A total of about 67,000 acres is irrigated with water diverted from the Big Lost River. The annual flow of the river is highly variable and water-supply deficiencies are common. About 1 out of every 2 years is considered a drought year. In the period 1955-68, about 175 irrigation wells were drilled to provide a supplemental water supply to land irrigated from the canal system and to irrigate an additional 8,500 acres of new land. Average. annual precipitation ranged from 8 inches on the valley floor to about 50 inches at some higher elevations during the base period 1944-68. The estimated water yield of the Big Lost River basin averaged 650 cfs (cubic feet per second) for the base period. Of this amount, 150 cfs was transpired by crops, 75 cfs left the basin as streamflow, and 425 cfs left as ground-water flow. A map of precipitation and estimated values of evapotranspiration were used to construct a water-yield map. A distinctive feature of the Big Lost River basin, is the large interchange of water from surface streams into the ground and from the ground into the surface streams. Large quantities of water disappear in the Chilly, Darlington, and other sinks and reappear above Mackay Narrows, above Moore Canal heading, and in other reaches. A cumulative summary of water yield upstream from selected points in the basin is as follows : Above Howell Ranch: water yield: 345 cfs; surface water: 310 cfs; ground water: 35 cfs Above. Mackay Narrows water yield: 450 cfs; surface water: 325 cfs; ground water: 75 cfs; crop evapotranspiration: 50 cfs Above Arco: water yield: 650 cfs; surface water: 75 cfs; ground water: 425 cfs; crop evapotranspiration: 150 cfs Ground-water pumping affects streamflow in reaches , where the stream and water table are continuous, but the effects of pumping were not measured except locally. Pumping depletes the total water supply by the. amount of the pumped water that is evapotranspired by crops. The part of the pumped water that is not consumed percolates into the ground or runs off over the land surface to the stream. The estimated 425 cfs that leaves the basin as ground-water flow is more than adequate for present and foreseeable needs. However because much of the outflow occurs at considerable depth, the quantity that is salvageable is unknown. Both the surface and ground waters are of good quality and are suitable for most uses. Although these waters are low in total dissolved solids, they tend to be hard or very hard.

  4. Quality assessment of butter cookies applying multispectral imaging

    PubMed Central

    Andresen, Mette S; Dissing, Bjørn S; Løje, Hanne

    2013-01-01

    A method for characterization of butter cookie quality by assessing the surface browning and water content using multispectral images is presented. Based on evaluations of the browning of butter cookies, cookies were manually divided into groups. From this categorization, reference values were calculated for a statistical prediction model correlating multispectral images with a browning score. The browning score is calculated as a function of oven temperature and baking time. It is presented as a quadratic response surface. The investigated process window was the intervals 4–16 min and 160–200°C in a forced convection electrically heated oven. In addition to the browning score, a model for predicting the average water content based on the same images is presented. This shows how multispectral images of butter cookies may be used for the assessment of different quality parameters. Statistical analysis showed that the most significant wavelengths for browning predictions were in the interval 400–700 nm and the wavelengths significant for water prediction were primarily located in the near-infrared spectrum. The water prediction model was found to correctly estimate the average water content with an absolute error of 0.22%. From the images it was also possible to follow the browning and drying propagation from the cookie edge toward the center. PMID:24804036

  5. Air-water CO2 and CH4 fluxes along a river-reservoir continuum: Case study in the Pengxi River, a tributary of the Yangtze River in the Three Gorges Reservoir, China.

    PubMed

    Huang, Yang; Yasarer, Lindsey M W; Li, Zhe; Sturm, Belinda S M; Zhang, Zengyu; Guo, Jinsong; Shen, Yu

    2017-05-01

    Water surface greenhouse gas (GHG) emissions in freshwater reservoirs are closely related to limnological processes in the water column. Affected by both reservoir operation and seasonal changes, variations in the hydro-morphological conditions in the river-reservoir continuum will create distinctive patterns in water surface GHG emissions. A one-year field survey was carried out in the Pengxi River-reservoir continuum, a part of the Three Gorges Reservoir (TGR) immediately after the TGR reached its maximum water level. The annual average water surface CO 2 and CH 4 emissions at the riverine background sampling sites were 6.23 ± 0.93 and 0.025 ± 0.006 mmol h -1  m -2 , respectively. The CO 2 emissions were higher than those in the downstream reservoirs. The development of phytoplankton controlled the downstream decrease in water surface CO 2 emissions. The presence of thermal stratification in the permanent backwater area supported extensive phytoplankton blooms, resulting in a carbon sink during several months of the year. The CH 4 emissions were mainly impacted by water temperature and dissolved organic carbon. The greatest water surface CH 4 emission was detected in the fluctuating backwater area, likely due to a shallower water column and abundant organic matter. The Pengxi River backwater area did not show significant increase in water surface GHG emissions reported in tropical reservoirs. In evaluating the net GHG emissions by the impoundment of TGR, the net change in the carbon budget and the contribution of nitrogen and phosphorus should be taken into consideration in this eutrophic river-reservoir continuum.

  6. Low reservoir ages for the surface ocean from mid-Holocene Florida corals

    USGS Publications Warehouse

    Druffel, E.R.M.; Robinson, L.F.; Griffin, S.; Halley, R.B.; Southon, J.R.; Adkins, J.F.

    2008-01-01

    The 14C reservoir age of the surface ocean was determined for two Holocene periods (4908-4955 and 3008-3066 calendar (cal) B.P.) using U/Th-dated corals from Biscayne National Park, Florida, United States. We found that the average reservoir ages for these two time periods (294 ?? 33 and 291 ?? 27 years, respectively) were lower than the average value between A.D. 1600 and 1900 (390 ?? 60 years) from corals. It appears that the surface ocean was closer to isotopic equilibrium with CO2 in the atmosphere during these two time periods than it was during recent times. Seasonal ??18O measurements from the younger coral are similar to modern values, suggesting that mixing with open ocean waters was indeed occurring during this coral's lifetime. Likely explanations for the lower reservoir age include increased stratification of the surface ocean or increased ??14C values of subsurface waters that mix into the surface. Our results imply that a more correct reservoir age correction for radiocarbon measurements of marine samples in this location from the time periods ???3040 and ???4930 cal years B.P. is ???292 ?? 30 years, less than the canonical value of 404 ?? 20 years. Copyright 2008 by the American Geophysical Union.

  7. A Strontium-Modified Titanium Surface Produced by a New Method and Its Biocompatibility In Vitro

    PubMed Central

    Liu, Chundong; Zhang, Yanli; Wang, Lichao; Zhang, Xinhua; Chen, Qiuyue; Wu, Buling

    2015-01-01

    Objective To present a new and effective method of producing titanium surfaces modified with strontium and to investigate the surface characteristics and in vitro biocompatibility of titanium (Ti) surfaces modified with strontium (Sr) for bone implant applications. Materials and Methods Sr-modified Ti surfaces were produced by sequential treatments with NaOH, strontium acetate, heat and water. The surface characteristics and the concentration of the Sr ions released from the samples were examined. Cell adhesion, morphology and growth were investigated using osteoblasts isolated from the calvaria of neonatal Sprague-Dawley rats. Expression of osteogenesis-related genes and proteins was examined to assess the effect of the Sr-modified Ti surfaces on osteoblasts. Results The modified titanium surface had a mesh structure with significantly greater porosity, and approximately5.37±0.35at.% of Sr was incorporated into the surface. The hydrophilicity was enhanced by the incorporation of Sr ions and water treatment. The average amounts of Sr released from the Sr-modified plates subjected to water treatment were slight higher than the plates without water treatment. Sr promoted cellular adhesion, spreading and growth compared with untreated Ti surfaces. The Sr-modified Ti plates also promoted expression of osteogenesis-related genes,and expression of OPN and COL-І by osteoblasts. Ti plates heat treated at 700°C showed increased bioactivity in comparison with those treated at 600°C. Water treatment upregulated the expression of osteogenesis-related genes. Conclusions These results show that Sr-modification of Ti surfaces may improve bioactivity in vitro. Water treatment has enhanced the response of osteoblasts. The Sr-modified Ti heat-treated at 700°C exhibited better bioactivity compared with that heated at 600°C. PMID:26529234

  8. A Strontium-Modified Titanium Surface Produced by a New Method and Its Biocompatibility In Vitro.

    PubMed

    Liu, Chundong; Zhang, Yanli; Wang, Lichao; Zhang, Xinhua; Chen, Qiuyue; Wu, Buling

    2015-01-01

    To present a new and effective method of producing titanium surfaces modified with strontium and to investigate the surface characteristics and in vitro biocompatibility of titanium (Ti) surfaces modified with strontium (Sr) for bone implant applications. Sr-modified Ti surfaces were produced by sequential treatments with NaOH, strontium acetate, heat and water. The surface characteristics and the concentration of the Sr ions released from the samples were examined. Cell adhesion, morphology and growth were investigated using osteoblasts isolated from the calvaria of neonatal Sprague-Dawley rats. Expression of osteogenesis-related genes and proteins was examined to assess the effect of the Sr-modified Ti surfaces on osteoblasts. The modified titanium surface had a mesh structure with significantly greater porosity, and approximately5.37±0.35at.% of Sr was incorporated into the surface. The hydrophilicity was enhanced by the incorporation of Sr ions and water treatment. The average amounts of Sr released from the Sr-modified plates subjected to water treatment were slight higher than the plates without water treatment. Sr promoted cellular adhesion, spreading and growth compared with untreated Ti surfaces. The Sr-modified Ti plates also promoted expression of osteogenesis-related genes,and expression of OPN and COL-І by osteoblasts. Ti plates heat treated at 700°C showed increased bioactivity in comparison with those treated at 600°C. Water treatment upregulated the expression of osteogenesis-related genes. These results show that Sr-modification of Ti surfaces may improve bioactivity in vitro. Water treatment has enhanced the response of osteoblasts. The Sr-modified Ti heat-treated at 700°C exhibited better bioactivity compared with that heated at 600°C.

  9. A second-order Budkyo-type parameterization of landsurface hydrology

    NASA Technical Reports Server (NTRS)

    Andreou, S. A.; Eagleson, P. S.

    1982-01-01

    A simple, second order parameterization of the water fluxes at a land surface for use as the appropriate boundary condition in general circulation models of the global atmosphere was developed. The derived parameterization incorporates the high nonlinearities in the relationship between the near surface soil moisture and the evaporation, runoff and percolation fluxes. Based on the one dimensional statistical dynamic derivation of the annual water balance, it makes the transition to short term prediction of the moisture fluxes, through a Taylor expansion around the average annual soil moisture. A comparison of the suggested parameterization is made with other existing techniques and available measurements. A thermodynamic coupling is applied in order to obtain estimations of the surface ground temperature.

  10. Effect of seasonal and long-term changes in stress on sources of water to wells

    USGS Publications Warehouse

    Reilly, Thomas E.; Pollock, David W.

    1995-01-01

    The source of water to wells is ultimately the location where the water flowing to a well enters the boundary surface of the ground-water system . In ground-water systems that receive most of their water from areal recharge, the location of the water entering the system is at the water table . The area contributing recharge to a discharging well is the surface area that defines the location of the water entering the groundwater system. Water entering the system at the water table flows to the well and is eventually discharged from the well. Many State agencies are currently (1994) developing wellhead-protection programs. The thrust of some of these programs is to protect water supplies by determining the areas contributing recharge to water-supply wells and by specifying regulations to minimize the opportunity for contamination of the recharge water by activities at the land surface. In the analyses of ground-water flow systems, steady-state average conditions are frequently used to simplify the problem and make a solution tractable. Recharge is usually cyclic in nature, however, having seasonal cycles and longer term climatic cycles. A hypothetical system is quantitatively analyzed to show that, in many cases, these cyclic changes in the recharge rates apparently do not significantly affect the location and size of the areas contributing recharge to wells. The ratio of the mean travel time to the length of the cyclic stress period appears to indicate whether the transient effects of the cyclic stress must be explicitly represented in the analysis of contributing areas to wells. For the cases examined, if the ratio of the mean travel time to the period of the cyclic stress was much greater than one, then the transient area contributing recharge to wells was similar to the area calculated using an average steady-state condition. Noncyclic long-term transient changes in water use, however, and cyclic stresses on systems with ratios less than 1 can and do affect the location and size of the areas contributing recharge to wells.

  11. A case study examining the efficacy of drainage setbacks for limiting effects to wetlands in the Prairie Pothole Region, USA

    USGS Publications Warehouse

    Tangen, Brian; Finocchiaro, Raymond

    2017-01-01

    The enhancement of agricultural lands through the use of artificial drainage systems is a common practice throughout the United States, and recently the use of this practice has expanded in the Prairie Pothole Region. Many wetlands are afforded protection from the direct effects of drainage through regulation or legal agreements, and drainage setback distances typically are used to provide a buffer between wetlands and drainage systems. A field study was initiated to assess the potential for subsurface drainage to affect wetland surface-water characteristics through a reduction in precipitation runoff, and to examine the efficacy of current U.S. Department of Agriculture drainage setback distances for limiting these effects. Surface-water levels, along with primary components of the catchment water balance, were monitored over 3 y at four seasonal wetland catchments situated in a high-relief terrain (7–11% slopes). During the second year of the study, subsurface drainage systems were installed in two of the catchments using drainage setbacks, and the drainage discharge volumes were monitored. A catchment water-balance model was used to assess the potential effect of subsurface drainage on wetland hydrology and to assess the efficacy of drainage setbacks for mitigating these effects. Results suggest that overland precipitation runoff can be an important component of the seasonal water balance of Prairie Pothole Region wetlands, accounting on average for 34% (19–49%) or 45% (39–49%) of the annual (includes snowmelt runoff) or seasonal (does not include snowmelt) input volumes, respectively. Seasonal (2014–2015) discharge volumes from the localized drainage systems averaged 81 m3 (31–199 m3), and were small when compared with average combined inputs of 3,745 m3 (1,214–6,993 m3) from snowmelt runoff, direct precipitation, and precipitation runoff. Model simulations of reduced precipitation runoff volumes as a result of subsurface drainage systems showed that ponded wetland surface areas were reduced by an average of 590 m2 (141–1,787 m2), or 24% (3–46%), when no setbacks were used (drainage systems located directly adjacent to wetland). Likewise, wetland surface areas were reduced by an average of 141 m2 (23–464 m2), or 7% (1–28%), when drainage setbacks (buffer) were used. In totality, the field data and model simulations suggest that the drainage setbacks should reduce, but not eliminate, impacts to the water balance of the four wetlands monitored in this study that were located in a high-relief terrain. However, further study is required to assess the validity of these conclusions outside of the limited parameters (e.g., terrain, weather, soils) of this study and to examine potential ecological effects of altered wetland hydrology.

  12. Documentation of a deep percolation model for estimating ground-water recharge

    USGS Publications Warehouse

    Bauer, H.H.; Vaccaro, J.J.

    1987-01-01

    A deep percolation model, which operates on a daily basis, was developed to estimate long-term average groundwater recharge from precipitation. It has been designed primarily to simulate recharge in large areas with variable weather, soils, and land uses, but it can also be used at any scale. The physical and mathematical concepts of the deep percolation model, its subroutines and data requirements, and input data sequence and formats are documented. The physical processes simulated are soil moisture accumulation, evaporation from bare soil, plant transpiration, surface water runoff, snow accumulation and melt, and accumulation and evaporation of intercepted precipitation. The minimum data sets for the operation of the model are daily values of precipitation and maximum and minimum air temperature, soil thickness and available water capacity, soil texture, and land use. Long-term average annual precipitation, actual daily stream discharge, monthly estimates of base flow, Soil Conservation Service surface runoff curve numbers, land surface altitude-slope-aspect, and temperature lapse rates are optional. The program is written in the FORTRAN 77 language with no enhancements and should run on most computer systems without modifications. Documentation has been prepared so that program modifications may be made for inclusions of additional physical processes or deletion of ones not considered important. (Author 's abstract)

  13. The Contribution of Reservoirs to Global Land Surface Water Storage Variations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhou, Tian; Nijssen, Bart; Gao, Huilin

    Man-made reservoirs play a key role in the terrestrial water system. They alter water fluxes at the land surface and impact surface water storage through water management regulations for diverse purposes such as irrigation, municipal water supply, hydropower generation, and flood control. Although most developed countries have established sophisticated observing systems for many variables in the land surface water cycle, long-term and consistent records of reservoir storage are much more limited and not always shared. Furthermore, most land surface hydrological models do not represent the effects of water management activities. Here, the contribution of reservoirs to seasonal water storage variationsmore » is investigated using a large-scale water management model to simulate the effects of reservoir management at basin and continental scales. The model was run from 1948 to 2010 at a spatial resolution of 0.258 latitude–longitude. A total of 166 of the largest reservoirs in the world with a total capacity of about 3900 km3 (nearly 60%of the globally integrated reservoir capacity) were simulated. The global reservoir storage time series reflects the massive expansion of global reservoir capacity; over 30 000 reservoirs have been constructed during the past half century, with a mean absolute interannual storage variation of 89 km3. The results indicate that the average reservoir-induced seasonal storage variation is nearly 700 km3 or about 10%of the global reservoir storage. For some river basins, such as the Yellow River, seasonal reservoir storage variations can be as large as 72%of combined snow water equivalent and soil moisture storage.« less

  14. Mining influence on underground water resources in arid and semiarid regions

    NASA Astrophysics Data System (ADS)

    Luo, A. K.; Hou, Y.; Hu, X. Y.

    2018-02-01

    Coordinated mining of coal and water resources in arid and semiarid regions has traditionally become a focus issue. The research takes Energy and Chemical Base in Northern Shaanxi as an example, and conducts statistical analysis on coal yield and drainage volume from several large-scale mines in the mining area. Meanwhile, research determines average water volume per ton coal, and calculates four typical years’ drainage volume in different mining intensity. Then during mining drainage, with the combination of precipitation observation data in recent two decades and water level data from observation well, the calculation of groundwater table, precipitation infiltration recharge, and evaporation capacity are performed. Moreover, the research analyzes the transforming relationship between surface water, mine water, and groundwater. The result shows that the main reason for reduction of water resources quantity and transforming relationship between surface water, groundwater, and mine water is massive mine drainage, which is caused by large-scale coal mining in the research area.

  15. Geo-referenced modelling of metal concentrations in river basins at the catchment scale

    NASA Astrophysics Data System (ADS)

    Hüffmeyer, N.; Berlekamp, J.; Klasmeier, J.

    2009-04-01

    1. Introduction The European Water Framework Directive demands the good ecological and chemical state of surface waters [1]. This implies the reduction of unwanted metal concentrations in surface waters. To define reasonable environmental target values and to develop promising mitigation strategies a detailed exposure assessment is required. This includes the identification of emission sources and the evaluation of their effect on local and regional surface water concentrations. Point source emissions via municipal or industrial wastewater that collect metal loads from a wide variety of applications and products are important anthropogenic pathways into receiving waters. Natural background and historical influences from ore-mining activities may be another important factor. Non-point emissions occur via surface runoff and erosion from drained land area. Besides deposition metals can be deposited by fertilizer application or the use of metal products such as wires or metal fences. Surface water concentrations vary according to the emission strength of sources located nearby and upstream of the considered location. A direct link between specific emission sources and pathways on the one hand and observed concentrations can hardly be established by monitoring alone. Geo-referenced models such as GREAT-ER (Geo-referenced Regional Exposure Assessment Tool for European Rivers) deliver spatially resolved concentrations in a whole river basin and allow for evaluating the causal relationship between specific emissions and resulting concentrations. This study summarizes the results of investigations for the metals zinc and copper in three German catchments. 2. The model GREAT-ER The geo-referenced model GREAT-ER has originally been developed to simulate and assess chemical burden of European river systems from multiple emission sources [2]. Emission loads from private households and rainwater runoff are individually estimated based on average consumption figures, runoff rates and the site-specific population and surface area (roof, gutter, street) connected to the local sewer system. For emissions from industry and mine drainage quantitative data on average annual loads are collected. WWTP effluent loads additionally consider average removal during wastewater treatment. Runoff from non-point sources such as agricultural areas and unsealed soils is estimated from average wash-off rates per area multiplied with the total area drained into a specified river reach of the river system. Groundwater infiltration is considered in quantities equal to the base flow in the respective river stretch. The model simulates the steady-state concentration distribution in the whole river basin considering transport and removal processes in the river system. The only major removal process for metals in surface water is sedimentation. Simulations have been carried out exemplary for zinc and copper in the German river basins Main (27,292 km2), Ruhr (4,485 km2) and Sieg (2,832 km2). 3. Results and discussion Model estimations of effluent loads for selected WWTPs agreed well with available surveillance data so that the emission module outcome can be assumed as appropriate starting point for surface water modeling. A detailed comparison of simulated surface water concentrations with monitoring data was performed for zinc in the Ruhr river basin. Good agreement between monitoring data and model simulations was achieved at 20 monitoring sites in the Ruhr River and its major tributaries. GREAT-ER was able to simulate zinc concentrations in surface waters based on estimation of loads from several emission sources and via different emission pathways. A wide applicability of the model was corroborated by successful simulations of zinc concentrations in the Main river basin and simulations for copper in both catchments. The functionality of the model allows for running scenarios with different emission assumptions that can be easily compared. Such case studies can be used to demonstrate the effect of specific mitigation strategies such as improved treatment of rainwater, reduction of metal products exposed to rain or reduced input from mine drainage. The model can thus be a valuable tool for setting up management plans as required in the Water Framework Directive with a special emphasis on promising mitigation strategies in case of exceedance of target values. 4. References [1] Directive 2000/60/EC of the European Parliament and of the Council (EU Water Framework Directive) [2] Feijtel T.C.J., Boeije G., Matthies M., Young A., Morris G., Gandolfi C., Hansen B., Fox K., Holt M., Koch V., Schröder R., Cassani G., Schowanek D., Rosenblom J. and Niessen H.; Chemosphere 34, 2351-2374, 1997. Acknowledgement - We would like to thank the International Zinc Association (IZA) and the European Copper Insitute (ECI) for financial support.

  16. The Effects of Fine-scale Soil Moisture and Canopy Heterogeneities on Energy and Soil Water Fluxes in a Temperate Mixed Deciduous Forest

    NASA Astrophysics Data System (ADS)

    He, L.; Ivanov, V. Y.; Bohrer, G.; Maurer, K.; Vogel, C. S.; Moghaddam, M.

    2011-12-01

    Vegetation is heterogeneous at different scales, influencing spatially variable energy and water exchanges between land-surface and atmosphere. Current land surface parameterizations of large-scale models consider spatial variability at a scale of a few kilometers and treat vegetation cover as aggregated patches with uniform properties. However, the coupling mechanisms between fine-scale soil moisture, vegetation, and energy fluxes such as evapotranspiration are strongly nonlinear; the aggregation of surface variations may produce biased energy fluxes. This study aims to improve the understanding of the scale impact in atmosphere-biosphere-hydrosphere interactions, which affects predictive capabilities of land surface models. The study uses a high-resolution, physically-based ecohydrological model tRIBS + VEGGIE as a data integration tool to upscale the heterogeneity of canopy distribution resolved at a few meters to the watershed scale. The study was carried out for a spatially heterogeneous, temperate mixed forest environment of Northern Michigan located near the University of Michigan Biological Station (UMBS). Energy and soil water dynamics were simulated at the tree-canopy resolution in the horizontal plane for a small domain (~2 sq. km) located within a footprint of the AmeriFlux tower. A variety of observational data were used to constrain and confirm the model, including a 3-m profile continuous soil moisture dataset and energy flux data (measured at the AmeriFlux tower footprint). A scenario with a spatially uniform canopy, corresponding to the commonly used 'big-leaf' scheme in land surface parameterizations was used to infer the effects of coarse-scale averaging. To gain insights on how heterogeneous canopy and soil moisture interact and contribute to the domain-averaged transpiration, several scenarios of tree-scale leaf area and soil moisture spatial variability were designed. Specifically, for the same mean states, the scenarios of variability of canopy biomass account for the spatial distribution of photosynthesis (and thus the stomatal resistance), the aerodynamic and leaf boundary layer resistances as well as the differential radiation forcing due to tall tree exposure and lateral shading of short trees. The numerical experiments show that by transpiring spatially varying amounts of water, heterogeneous canopies adjust the spatial soil water state to the scaled inverse of the canopy biomass regardless of the initial moisture state. Such a spatial distribution can be further wiped out because of the differential water stress. The aggregation of canopy-scale atmosphere-biosphere-hydrosphere interactions demonstrates non-linear relationship between soil moisture and evapotranspiration, influencing domain-averaged energy fluxes.

  17. The spatial and temporal distribution of chemical species in Padaviya Reservoir, Sri Lanka.

    NASA Astrophysics Data System (ADS)

    Koliyabandara, S. M. P. A.; Siriwardhana, C.; Cooray, P. L. A. T.; Liyanage, S. S.

    2017-12-01

    Water is one of the most important assets for human life. Eutrophication and pollution are some of the major threats to many freshwater bodies. There are thousands of reservoirs exist in Sri Lanka; however, only a handful of them has been thoroughly monitored and studied. The main objective of this study is to investigate the temporal and spatial distribution of chemical species in Padaviya reservoir which is shallow man-made irrigation reservoir (8°49'30.6" N and 80°46'2.05"E) located in Sri Lanka constructed around 300 BC. The average depth is 8 m and 4 m in wet and dry seasons respectively. It has a catchment area of 270 km2. Water sampling was done at bi-monthly intervals for a period of one year staring from January 2016. Chemical analyses were conducted according to standard protocols. The maximum temperature difference between the surface and bottom waters of the reservoir was 2 °C throughout the year. The surface and bottom water conductivity varied between 175 ± 2.3 to 250 ± 3.0 μS cm-1 and 475 ± 3.7 to 600 ± 4.5 μScm-1 respectively. The average pH of surface and bottom waters varied between 8.5 ± 0.1 to 7.8 ± 0.2 and 7.2 ± 0.02 to 6.8 ± 0.2 respectively. The dissolved oxygen concentration showed a clinograde type distribution throughout the year where the surface waters were well oxygenated (DO ≈ 7.5 ppm) and the bottom waters were anoxic (DO ≈ 0.15 ppm). Ammonia concentration increased with the depth from surface concentration of 150 ± 50 to 300 ± 25 ppb at the bottom. Nitrite distribution was similar to ammonia and the surface concentration was 100 ± 25ppb throughtout the year and at the bottom it varied between 300 ± 30 to 4500 ± 30 ppb. Water soluble phosphate distribution was also similar to ammonia. The surface concentration was 200 ± 20 ppb throughtout the year and varied from 100 ± 20 to 2000 ±20 ppb at the bottom. Nitrate distribution was inverse of the ammonia. The surface concentration was 500 ± 30 to 900 ± 30 ppb while the it was 100 ± 30ppb at the bottom throughout the year. The fluctionations of the concentrations of chemical species was attributed to the wet and dry seasons of the reservoir. Key words - Chemical species, Water quality, Padaviya,Acknowledgement - Financial support by University of Sri Jayewardenepura, ASP/01/RE/SCI/2015/29.

  18. Effect of Ionic Soil Stabilizers on Soil-Water Characteristic of Special Clay

    NASA Astrophysics Data System (ADS)

    Cui, D.; Xiang, W.

    2011-12-01

    The engineering properties of special clay are conventionally improved through the use of chemical additive such as ionic soil stabilizer (ISS). Such special clays are often referred to as stabilized or treated clays. The soil-water characteristic curves (SWCC) of special clays from Henan province and Hubei province were measured both in natural and stabilized conditions using the pressure plate apparatus in the suction range of 0-500 kPa. The SWCC results are used to interpret the special clays behavior due to stabilizer treatment. In addition, relationships were developed between the basic clay and stabilized properties such as specific surface area and pore size distribution. The analysis showed that specific surface area decreases, cumulative pore volume and average pore size diameter decrease, dehydration rate slows and the thickness of water film thins after treatment with Ionic Soil Stabilizer. The research data and interpretation analysis presented here can be extended to understand the water film change behaviors influencing the mechanical and physical properties of stabilized special clay soils. KEY WORDS: ionic soil stabilizer, special clay, pore size diameter, specific surface area, soil water characteristic curve, water film

  19. Dissolved Concentrations, Sources, and Risk Evaluation of Selected Metals in Surface Water from Mangla Lake, Pakistan

    PubMed Central

    Saleem, Muhammad; Iqbal, Javed; Shah, Munir H.

    2014-01-01

    The present study is carried out for the assessment of water quality parameters and selected metals levels in surface water from Mangla Lake, Pakistan. The metal levels (Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, Pb, Sr, and Zn) were determined by flame atomic absorption spectrophotometry. Average levels of Cd, Co, Cr, Ni, and Pb were higher than the allowable concentrations set by national and international agencies. Principal component analysis indicated significant anthropogenic contributions of Cd, Co, Cr, Ni, and Pb in the water reservoir. Noncarcinogenic risk assessment was then evaluated using Hazard Quotient (HQing/derm) and Hazard Index (HIing/derm) following USEPA methodology. For adults and children, Cd, Co, Cr, and Pb (HQing > 1) emerged as the most important pollutants leading to noncarcinogenic concerns via ingestion route, whereas there was no risk via dermal contact of surface water. This study helps in establishing pollutant loading reduction goal and the total maximum daily loads, and consequently contributes to preserve public health and develop water conservation strategy. PMID:24744690

  20. Hydration water and bulk water in proteins have distinct properties in radial distributions calculated from 105 atomic resolution crystal structures.

    PubMed

    Chen, Xianfeng; Weber, Irene; Harrison, Robert W

    2008-09-25

    Water plays a critical role in the structure and function of proteins, although the experimental properties of water around protein structures are not well understood. The water can be classified by the separation from the protein surface into bulk water and hydration water. Hydration water interacts closely with the protein and contributes to protein folding, stability, and dynamics, as well as interacting with the bulk water. Water potential functions are often parametrized to fit bulk water properties because of the limited experimental data for hydration water. Therefore, the structural and energetic properties of the hydration water were assessed for 105 atomic resolution (

  1. Changes in water and solute fluxes in the vadose zone after switching crops

    NASA Astrophysics Data System (ADS)

    Turkeltaub, Tuvia; Dahan, Ofer; Kurtzman, Daniel

    2015-04-01

    Switching crop type and therefore changing irrigation and fertilization regimes leads to alternation in deep percolation and concentrations of solutes in pore water. Changes of fluxes of water, chloride and nitrate under a commercial greenhouse due to a change from tomato to green spices were observed. The site, located above the a coastal aquifer, was monitored for the last four years. A vadose-zone monitoring system (VMS) was implemented under the greenhouse and provided continuous data on both the temporal variation in water content and the chemical composition of pore water at multiple depths in the deep vadose zone (~20 m). Chloride and nitrate profiles, before and after the crop type switching, indicate on a clear alternation in soil water solutes concentrations. Before the switching of the crop type, the average chloride profile ranged from ~130 to ~210, while after the switching, the average profile ranged from ~34 to ~203 mg L-1, 22% reduction in chloride mass. Counter trend was observed for the nitrate concentrations, the average nitrate profile before switching ranged from ~11 to ~44 mg L-1, and after switching, the average profile ranged from ~500 to ~75 mg L-1, 400% increase in nitrate mass. A one dimensional unsaturated water flow and chloride transport model was calibrated to transient deep vadose zone data. A comparison between the simulation results under each of the surface boundary conditions of the vegetables and spices cultivation regime, clearly show a distinct alternation in the quantity and quality of groundwater recharge.

  2. Effects of Acids, Bases, and Heteroatoms on Proximal Radial Distribution Functions for Proteins.

    PubMed

    Nguyen, Bao Linh; Pettitt, B Montgomery

    2015-04-14

    The proximal distribution of water around proteins is a convenient method of quantifying solvation. We consider the effect of charged and sulfur-containing amino acid side-chain atoms on the proximal radial distribution function (pRDF) of water molecules around proteins using side-chain analogs. The pRDF represents the relative probability of finding any solvent molecule at a distance from the closest or surface perpendicular protein atom. We consider the near-neighbor distribution. Previously, pRDFs were shown to be universal descriptors of the water molecules around C, N, and O atom types across hundreds of globular proteins. Using averaged pRDFs, a solvent density around any globular protein can be reconstructed with controllable relative error. Solvent reconstruction using the additional information from charged amino acid side-chain atom types from both small models and protein averages reveals the effects of surface charge distribution on solvent density and improves the reconstruction errors relative to simulation. Solvent density reconstructions from the small-molecule models are as effective and less computationally demanding than reconstructions from full macromolecular models in reproducing preferred hydration sites and solvent density fluctuations.

  3. Late Holocene Radiocarbon Variability in Northwest Atlantic Slope Waters

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sherwood, O; Edinger, E; Guilderson, T P

    2008-08-15

    Deep-sea gorgonian corals secrete a 2-part skeleton of calcite, derived from dissolved inorganic carbon at depth, and gorgonin, derived from recently fixed and exported particulate organic matter. Radiocarbon contents of the calcite and gorgonin provide direct measures of seawater radiocarbon at depth and in the overlying surface waters, respectively. Using specimens collected from Northwest Atlantic slope waters, we generated radiocarbon records for surface and upper intermediate water layers spanning the pre- and post bomb-{sup 14}C eras. In Labrador Slope Water (LSW), convective mixing homogenizes the pre-bomb {Delta}{sup 14}C signature (-67 {+-} 4{per_thousand}) to at least 1000 m depth. Surface watermore » bomb-{sup 14}C signals were lagged and damped (peaking at {approx} +45{per_thousand} in the early 1980s) relative to other regions of the northwest Atlantic, and intermediate water signals were damped further. Off southwest Nova Scotia, the vertical gradient in {Delta}{sup 14}C is much stronger. In surface water, pre-bomb {Delta}{sup 14}C averaged -75 {+-} 5{per_thousand}. At 250-475 m depth, prebomb {Delta}{sup 14}C oscillated quasi-decadally between -80 and -100{per_thousand}, likely reflecting interannual variability in the presence of Labrador Slope Water vs. Warm Slope Water (WSW). Finally, subfossil corals reveal no systematic changes in vertical {Delta}{sup 14}C gradients over the last 1200 years.« less

  4. Aquifer-test results, direction of ground-water flow, and 1984-90 annual ground-water pumpage for irrigation, lower Big Lost River Valley, Idaho

    USGS Publications Warehouse

    Bassick, M.D.; Jones, M.L.

    1992-01-01

    The study area (see index map of Idaho), part of the Big Lost River drainage basin, is at the northern side of the eastern Snake River Plain. The lower Big Lost River Valley extends from the confluence of Antelope Creek and the Big Lost River to about 4 mi south of Arco and encompasses about 145 mi2 (see map showing water-level contours). The study area is about 18 mi long and, at its narrowest, 4 mi wide. Arco, Butte City, and Moore, with populations of 1,016, 59, and 190, respectively, in 1990, are the only incorporated towns. The entire study area, except the extreme northwestern part, is in Butte City. The study area boundary is where alluvium and colluvium pinch out and abut against the White Knob Mountains (chiefly undifferentiated sedimentary rock with lesser amounts of volcanic rock) on the west and the Lost River Range (chiefly sedimentary rock) on the east. Gravel and sand in the valley fill compose the main aquifer. The southern boundary is approximately where Big Lost River valley fill intercalates with or abuts against basalt of the Snake River Group. Spring ground-water levels and flow in the Big Lost River depend primarily on temperature and the amount and timing of precipitation within the entire drainage basin. Periods of abundant water supply and water shortages are, therefore, related to the amount of annual precipitation. Surface reservoir capacity in the valley (Mackay Reservoir, about 20 mi northwest of Moore) is only 20 percent of the average annual flow of the Big Lost River (Crosthwaite and others, 1970, p. 3). Stored surface water is generally unavailable for carryover from years of abundant water supply to help relieve drought conditions in subsequent years. Many farmers have drilled irrigation wells to supplement surface-water supplies and to increase irrigated acreage. Average annual flow of the Big Lost River below Mackay Reservoir near Mackay (gaging station 13127000, not shown) in water years 1905, 1913-14, and 1920-90 was about 224,600 acre-ft; average annual flow of the Big Lost River near Arco (gaging station 13132500; see map showing water-level contours) in water years 1947-61, 1967-80, and 1983-90 was about 79,000 acre-ft (Harenberg and others, 1991, p. 254-255). Moore Canal and East Side Ditch divert water from the Big Lost River at the Moore Diversion, 3 mi north of Moore (see map showing water-level contours) and supply water for irrigation near the margins of the valley. When water supply is average or greater, water in the Big Lost River flows through the study area and onto the Snake River Plain, where it evaporates or infiltrates into the Snake River Plain aquifer. When water supply is below average, water in the Big Lost River commonly does not reach Arco; rather, it is diverted for irrigation in the interior of the valley, evaporates, or infiltrates to the valley-fill aquifer. This report describes the results of a study by the U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources, to collect hydrologic data needed to help address water-supply problems in the Big Lost River Valley. Work involved (1) field inventory of 81 wells, including 46 irrigation wells; (2) measurement of water levels in 154 wells in March 1991; (3) estimation of annual ground-water pumpage for irrigation from 1984 through 1990; and (4) analysis of results of an aquifer test conducted southwest of Moore. All data obtained during this study may be inspected at the U.S. Geological Survey, Idaho District office, Boise.

  5. Water footprinting of pasture-based farms; beef and sheep.

    PubMed

    Murphy, E; Curran, T P; Holden, N M; O'Brien, D; Upton, J

    2018-05-01

    In the context of water use for agricultural production, water footprints (WFs) have become an important sustainability indicator. To understand better the water demand for beef and sheep meat produced on pasture-based systems, a WF of individual farms is required. The main objective of this study was to determine the primary contributors to freshwater consumption up to the farm gate expressed as a volumetric WF and associated impacts for the production of 1 kg of beef and 1 kg of sheep meat from a selection of pasture-based farms for 2 consecutive years, 2014 and 2015. The WF included green water, from the consumption of soil moisture due to evapotranspiration, and blue water, from the consumption of ground and surface waters. The impact of freshwater consumption on global water stress from the production of beef and sheep meat in Ireland was also computed. The average WF of the beef farms was 8391 l/kg carcass weight (CW) of which 8222 l/kg CW was green water and 169 l/kg CW was blue water; water for the production of pasture (including silage and grass) contributed 88% to the WF, concentrate production - 10% and on-farm water use - 1%. The average stress-weighted WF of beef was 91 l H2O eq/kg CW, implying that each kg of beef produced in Ireland contributed to freshwater scarcity equivalent to the consumption of 91 l of freshwater by an average world citizen. The average WF of the sheep farms was 7672 l/kg CW of which 7635 l/kg CW was green water and 37 l/kg CW was blue water; water for the production of pasture contributed 87% to the WF, concentrate production - 12% and on-farm water use - 1%. The average stress-weighted WF was 2 l H2O eq/kg CW for sheep. This study also evaluated the sustainability of recent intensification initiatives in Ireland and found that increases in productivity were supported through an increase in green water use and higher grass yields per hectare on both beef and sheep farms.

  6. Big and small: menisci in soil pores affect water pressures, dynamics of groundwater levels, and catchment-scale average matric potentials

    NASA Astrophysics Data System (ADS)

    de Rooij, G. H.

    2010-09-01

    Soil water is confined behind the menisci of its water-air interface. Catchment-scale fluxes (groundwater recharge, evaporation, transpiration, precipitation, etc.) affect the matric potential, and thereby the interface curvature and the configuration of the phases. In turn, these affect the fluxes (except precipitation), creating feedbacks between pore-scale and catchment-scale processes. Tracking pore-scale processes beyond the Darcy scale is not feasible. Instead, for a simplified system based on the classical Darcy's Law and Laplace-Young Law we i) clarify how menisci transfer pressure from the atmosphere to the soil water, ii) examine large-scale phenomena arising from pore-scale processes, and iii) analyze the relationship between average meniscus curvature and average matric potential. In stagnant water, changing the gravitational potential or the curvature of the air-water interface changes the pressure throughout the water. Adding small amounts of water can thus profoundly affect water pressures in a much larger volume. The pressure-regulating effect of the interface curvature showcases the meniscus as a pressure port that transfers the atmospheric pressure to the water with an offset directly proportional to its curvature. This property causes an extremely rapid rise of phreatic levels in soils once the capillary fringe extends to the soil surface and the menisci flatten. For large bodies of subsurface water, the curvature and vertical position of any meniscus quantify the uniform hydraulic potential under hydrostatic equilibrium. During unit-gradient flow, the matric potential corresponding to the mean curvature of the menisci should provide a good approximation of the intrinsic phase average of the matric potential.

  7. Chloride cycling in two forested lake watersheds in the west-central Adirondack Mountains, New York, U.S.A.

    USGS Publications Warehouse

    Peters, N.E.

    1991-01-01

    The chemistry of precipitation, throughfall, soil water, ground water, and surface water was evaluated in two forested lake-watersheds over a 4-yr period to assess factors controlling C1- cycling. Results indicate that C1- cycling in these watersheds is more complex than the generally held view of the rapid transport of atmospherically derived C1- through the ecosystem. The annual throughfall Cl- flux for individual species in the northern hardwood forest was 2 to 5 times that of precipitation (56 eq ha-1), whereas the Na+ throughfall flux, in general, was similar to the precipitation flux. Concentrations of soil-water Cl- sampled from ceramic tension lysimeters at 20 cm below land surface generally exceeded the Na+ concentrations and averaged 31 ??eq L-1, the highest of any waters sampled in the watersheds, except throughfall under red spruce which averaged 34 ??eq L-1. Chloride was concentrated prior to storms and mobilized rapidly during storms as suggested by increases in streamwater Cl- concentrations with increasing flow. Major sources of Cl- in both watersheds are the forest floor and hornblende weathering in the soils and till. In the Panther Lake watershed, which contains mainly thick deposits of till( > 3 m), hornblende weathering results in a net Cl- flux 3 times greater than that in the Woods Lake watershed, which contains mainly thin deposits of till. The estimated accumulation rate of Cl- in the biomass of the two watersheds was comparable to the precipitation Cl- flux.The chemistry of precipitation, throughfall, soil water, ground water, and surface water was evaluated in two forested lake-watersheds over a 4-yr period to assess factors controlling Cl- cycling. Results indicate that Cl- cycling in these watersheds is more complex than the generally held view of the rapid transport of atmospherically derived Cl- through the excosystem. The annual throughfall Cl- flux for individual species in the northern hardwood forest was 2 to 5 times that of precipitation (56 eq ha-1), whereas the Na+ throughfall flux, in general, was similar to the precipitation flux. Concentrations of soil-water Cl- sampled from ceramic tension lysimeters at 20 cm below land surface generally exceeded the Na+ concentrations and averaged 31 ??eq L-1, the highest of any waters sampled in the watersheds, except throughfall under red spruce which averaged 34 ??eq L-1. Chloride was concentrated prior to storms and mobilized rapidly during storms as suggested by increases in streamwater Cl- concentrations with increasing flow. Major sources of Cl- in both watersheds are the forest floor and hornblende weathering in the soils and till. In the Panther Lake watershed, which contains mainly thick deposits of till (> 3 m), hornblende weathering results in a net Cl- flux 3 times greater than that in the Woods Lake watershed, which contains mainly thin deposits of till. The estimated accumulation rate of Cl- in the biomass of the two watersheds was comparable to the precipitation Cl- flux.

  8. Are atmospheric surface layer flows ergodic?

    NASA Astrophysics Data System (ADS)

    Higgins, Chad W.; Katul, Gabriel G.; Froidevaux, Martin; Simeonov, Valentin; Parlange, Marc B.

    2013-06-01

    The transposition of atmospheric turbulence statistics from the time domain, as conventionally sampled in field experiments, is explained by the so-called ergodic hypothesis. In micrometeorology, this hypothesis assumes that the time average of a measured flow variable represents an ensemble of independent realizations from similar meteorological states and boundary conditions. That is, the averaging duration must be sufficiently long to include a large number of independent realizations of the sampled flow variable so as to represent the ensemble. While the validity of the ergodic hypothesis for turbulence has been confirmed in laboratory experiments, and numerical simulations for idealized conditions, evidence for its validity in the atmospheric surface layer (ASL), especially for nonideal conditions, continues to defy experimental efforts. There is some urgency to make progress on this problem given the proliferation of tall tower scalar concentration networks aimed at constraining climate models yet are impacted by nonideal conditions at the land surface. Recent advancements in water vapor concentration lidar measurements that simultaneously sample spatial and temporal series in the ASL are used to investigate the validity of the ergodic hypothesis for the first time. It is shown that ergodicity is valid in a strict sense above uniform surfaces away from abrupt surface transitions. Surprisingly, ergodicity may be used to infer the ensemble concentration statistics of a composite grass-lake system using only water vapor concentration measurements collected above the sharp transition delineating the lake from the grass surface.

  9. Thermodynamics of Manganese Oxides at Bulk and Nanoscale: Phase Formation, Transformation, Oxidation-Reduction, and Hydration

    NASA Astrophysics Data System (ADS)

    Birkner, Nancy R.

    Natural manganese oxides are generally formed in surficial environments that are near ambient temperature and water-rich, and may be exposed to wet-dry cycles and a variety of adsorbate species that influence dramatically their level of hydration. Manganese oxide minerals are often poorly crystalline, nanophase, and hydrous. In the near-surface environment they are involved in processes that are important to life, such as water column oxygen cycling, biomineralization, and transport of minerals/nutrients through soils and water. These processes, often involving transformations among manganese oxide polymorphs, are governed by a complex interplay between thermodynamics and kinetics. Manganese oxides are also used in technology as catalysts, and for other applications. The major goal of this dissertation is to examine the energetics of bulk and nanophase manganese oxide phases as a function of particle size, composition, and surface hydration. Careful synthesis and characterization of manganese oxide phases with different surface areas provided samples for the study of enthalpies of formation by high temperature oxide melt solution calorimetry and of the energetics of water adsorption on their surfaces. These data provide a quantitative picture of phase stability and how it changes at the nanoscale. The surface energy of the hydrous surface of Mn3O4 is 0.96 +/- 0.08 J/m2, of Mn2O3 is 1.29 +/- 0.10 J/m2, and of MnO2 is 1.64 +/- 0.10 J/m2. The surface energy of the anhydrous surface of Mn3O4 is 1.62 +/- 0.08 J/m 2, of Mn2O3 is 1.77 +/- 0.10 J/m 2, and of MnO2 is 2.05 +/- 0.10 J/m2. Supporting preliminary findings (Navrotsky et al., 2010), the spinel phase (Mn3O4) has a lower surface energy (more stabilizing) than bixbyite, while the latter has a smaller surface energy than pyrolusite. These differences significantly change the positions in oxygen fugacity---temperature space of the redox couples Mn3O4-Mn2O 3 and Mn2O3-MnO2 favoring the lower surface enthalpy phase (the spinel Mn3O4) for smaller particle size and in the presence of surface hydration. Chemisorption of water onto anhydrous nanophase Mn2O 3 surfaces promotes rapidly reversible redox phase changes at room temperature as confirmed by calorimetry, X-ray diffraction, and titration for manganese average oxidation state. Water adsorption microcalorimetry (in situ) at room temperature measured the strongly exothermic integral enthalpy of water adsorption (-103.5 kJ/mol) and monitored the energetics of the redox phase transformation. Hydration-driven redox transformation of anhydrous nanophase Mn(III) 2O3, (high surface enthalpy of anhydrous surfaces 1.77 +/- 0.10 J/m2) to Mn(II,III)3O4 (lower surface enthalpy 0.96 +/- 0.08 J/m2) occurred during the first few doses of water vapor. Surface reduction of nanoparticle bixbyite (Mn 2O3) to hausmannite (Mn3O4) occurs under conditions where no such reactions are seen or expected on grounds of bulk thermodynamics in coarse-grained materials. Layered structure manganese oxides contain alkali or alkaline earth cations and water, are generally fine-grained, and have considerable thermodynamic stability. The surface enthalpies (SE) of layered and tunnel structure complex manganese oxides are significantly lower than those of the binary manganese oxide phases. The SE for hydrous surfaces and overall manganese average oxidation state (AOS) (value in parentheses) are: cryptomelane 0.77 +/- 0.10 J/m 2 (3.78), sodium birnessite 0.69 +/- 0.13 J/m2 (3.56), potassium birnessite 0.55 +/- 0.11 J/m2 (3.52), and calcium birnessite 0.41 +/- 0.11 J/m2 (3.50). Surface enthalpies of hydrous surfaces of the calcium manganese oxide nanosheets are: deltaCa 0.39MnO2.3nH2O 0.75 +/- 0.10 J/m2 (3.89) and deltaCa0.43MnO2.3nH2O 0.57 +/- 0.12 J/m2 (3.68). The surface enthalpy of the complex manganese oxides appears to decrease with decreasing manganese average oxidation state, that is, with greater mixed valence manganese (Mn 3+/4+). Low surface energy suggests loose binding of H2O on the internal and external surfaces and may be critical to catalysis in both natural and technological settings.

  10. Hydrogeologic controls of surface-water chemistry in the Adirondack region of New York State

    USGS Publications Warehouse

    Peters, N.E.; Driscoll, C.T.

    1987-01-01

    Relationships between surface-water discharge, water chemistry, and watershed geology were investigated to evaluate factors affecting the sensitivity of drainage waters in the Adirondack region of New York to acidification by atmospheric deposition. Instantaneous discharge per unit area was derived from relationships between flow and staff-gage readings at 10 drainage basins throughout the region. The average chemical composition of the waters was assessed from monthly samples collected from July 1982 through July 1984. The ratio of flow at the 50-percent exceedence level to the flow at the 95-percent exceedence level of flow duration was negatively correlated with mean values of alkalinity or acid-neutralizing capacity (ANC), sum of basic cations (SBC), and dissolved silica, for basins containing predominantly aluminosilicate minerals and little or no carbonate-bearing minerals. Low ratios are indicative of systems in which flow is predominately derived from surface- and ground-water storage, whereas high ratios are characteristic of watersheds with variable flow that is largely derived from surface runoff. In an evaluation of two representative surface-water sites, concentrations of ANC, SBC, and dissolved silica, derived primarily from soil mineral weathering reactions. decreased with increasing flow. Furthermore, the ANC was highest at low flow when the percentage of streamflow derived from ground water was maximum. As flow increased, the ANC decreased because the contribution of dilute surface runoff and lateral flow through the shallow acidic soil horizons to total flow increased. Basins having relatively high ground-water contributions to total flow, in general, have large deposits of thick till or stratified drift. A major factor controlling the sensitivity of these streams and lakes to acidification is the relative contribution of ground water to total discharge. ?? 1987 Martinus Nijhoff/Dr W. Junk Publishers.

  11. Surface water of Beaver Creek Basin, in South-Central Oklahoma

    USGS Publications Warehouse

    Laine, L.L.; Murphy, J.J.

    1962-01-01

    Annual discharge from Beaver Creek basin is estimated to have averaged 217,000 acre-feet during a 19-year base period, water years 1938-56, equivalent to an average annual runoff depth of 4.7 inches over the 857 square-mile drainage area. About 55,000 acre-feet per year comes from Little Beaver Creek basin, a tributary drainage of 195 square miles. Yearly streamflow is highly variable. The discharge of Little Beaver Creek near Duncan during 13-year period of record (water years 1949-61) has ranged from 86,530 acre-feet in calendar year 1957 to 4,880 acre-feet in 1956, a ratio of almost 18 to 1. Highest runoff within a year tends to occur in the spring months of May and June, a 2-month period that, on the average, accounts for more than half of the annual discharge of Little Beaver Creek near Duncan. The average monthly runoff during record was lowest in January. Variation in daily streamflow is such that while the average discharge for the 13-year period of record was 50.1 cfs (cubic feet per second), the daily discharge was more than 6 cfs only about half of the time. There was no flow at the site 19 percent of the time during the period. Some base runoff usually exists in the headwaters of Beaver and Little Beaver Creeks, and in the lower reaches of Beaver Creek. Low flow in Cow Creek tends to be sustained by waste water from Duncan, where water use in 1961 averaged 4 million gallons per day. In the remainder of the basin, periods of no flow occur in most years. The surface water of Beaver Creek basin is very hard but in general is usable for municipal, agricultural and industrial purposes. The chemical character of the water is predominantly a calcium, magnesium bicarbonate type of water in the lower three quarters of the basin, except in Cow Creek where oil-field brines induce a distinct sodium, calcium chloride characteristic at low and medium flows. A calcium sulfate type of water occurs in most of the northern part of the basin except in headwater areas underlain by the Rush Springs Sandstone, where quality is similar to that in the lower basin. The report gives an estimate of the average discharge at several sites in Beaver Creek basin for a 19-year base period, October 1937 to September 1956. Duration curves of daily discharge for Little Beaver Creek near Duncan and Beaver Creek near Waurika are shown for the period of record. Monthly and annual discharge records for these gaging stations are presented. The results of 52 discharge measurements at 17 other sites in the basin are tabulated, with 5 groups being plotted as discharge profiles. Storage requirements for regulated discharge at the two gaging stations are shown. (available as photostat copy only)

  12. Investigation of the local structure variance of water molecules in laser-induced thermal desorption process

    NASA Astrophysics Data System (ADS)

    Ju, Shin-Pon; Weng, Cheng-I.

    2004-05-01

    This paper presents the use of molecular dynamics simulation in the study of laser-induced thermal desorption (LITD) of water molecules adjacent to a laser-heated Au substrate. The local structure of the water molecules is investigated by considering the densities of the oxygen and hydrogen atoms, the average number of neighbors, nNN, and the average number of H-bonds, nHB. At an equilibrium temperature of 300 K, the simulation results show that three adsorption water layers are formed in the immediate vicinity of the Au surface, and that each four-fold hollow site on the uppermost Au(0 0 1) surface is occupied by a single water molecule. Following laser-induced heating of the Au substrate with a sub-picosecond laser pulse of 350 fs, the substrate temperature increases to 1000 K. This causes a gradual heating of the adjacent water film, which is accompanied by a decrease in the values of nNN and nHB. Hence, it can be concluded that an increase in the water film temperature destroys the hydrogen-bonding network throughout the water film. Although the maximum local temperature of the water film occurs in the region immediately adjacent to the Au substrate, it is determined that the attractive energy between the Au atoms and the water molecules in this region causes the water molecules to aggregate together to form three-dimensional water clusters. Furthermore, this energy prevents the hydrogen bonds in this region from breaking apart as violently as those within the phase explosion region. Finally, it is observed that the phase explosion phenomenon occurs in the region of the water film where the values of nNN and nHB are at a minimum.

  13. Effects of surface-water and groundwater inflows and outflows on the hydrology of the Tsala Apopka Lake Basin in Citrus County, Florida

    USGS Publications Warehouse

    Sepúlveda, Nicasio; Fulkerson, Mark; Basso, Ron; Ryan, Patrick J.

    2018-05-21

    The U.S. Geological Survey, in cooperation with the Southwest Florida Water Management District, initiated a study to quantify the inflows and outflows in the Floral City, Inverness, and Hernando pools of the Tsala Apopka Lake Basin in Citrus County, Florida. This study assesses hydrologic changes in pool stages, groundwater levels, spring flows, and streamflows caused by the diversion of streamflow from the Withlacoochee River to the Tsala Apopka Lake Basin through water-control structures. A surface-water/groundwater flow model was developed using hydraulic parameters for lakes, streams, the unsaturated zone, and the underlying surficial and Upper Floridan aquifers estimated using an inverse modeling calibration technique. After calibration, the model was used to assess the relation between inflows and outflows in the Tsala Apopka Lake Basin and changes in pool stages.Simulation results using the calibrated surface-water/groundwater flow model showed that leakage rates from the pools to the Upper Floridan aquifer were largest at the deep lake cells and that these leakage rates to the Upper Floridan aquifer were the highest in the model area. Downward leakage to the Upper Floridan aquifer occurred beneath most of the extent of the Floral City, Inverness, and Hernando pools. These leakage rates depended on the lakebed leakance and the difference between lake stages and heads in the Upper Floridan aquifer. Leakage rates were higher for the Floral City pool than for the Inverness pool, and higher for the Inverness pool than for the Hernando pool. Lakebed leakance was higher for the Floral City pool than for the Hernando pool, and higher for the Hernando pool than for the Inverness pool.Simulation results showed that the average recharge rate to the surficial aquifer was 10.3 inches per year for the 2004 to 2012 simulation period. Areas that recharge the surficial aquifer covered about 86 percent of the model area. Simulations identified areas along segments of the Withlacoochee River and within land-surface depressions that receive water from the surficial aquifer. Recharge rates were largest in physiographic regions having a deep water table. Simulated heads in the Upper Floridan aquifer indicated the general flow directions in the active flow model area were from the northeast toward the southwest and then westward toward the coast, and from the southeast toward the northwest and then westward toward the coast, consistent with flow directions inferred from the estimated potentiometric surface map for May 2010. The largest inflow in the water budget of the Upper Floridan aquifer was downward leakage from the overlying hydrogeologic unit. The largest outflow in the water budget of the Upper Floridan aquifer was spring flow.The calibrated surface-water and groundwater flow model was used to simulate hydrologic scenarios that included changes in rainfall rates, projected increases in groundwater pumping rates for 2025 and 2035, no flow for the 2004–12 period through the eight water-control structures in the Tsala Apopka Lake Basin, and the removal of the Inglis Dam and the Inglis Bypass Spillway on Lake Rousseau. Scenario simulation results were compared to annual average calibrated water levels and flows from 2004 to 2012. Simulated declines in the Tsala Apopka Lake pool stages under the 10-percent lower rainfall scenario were about 0.8, 0.3, and 1.3 feet (ft) for the Floral City, Inverness, and Hernando pools, respectively. Simulated groundwater levels under the same scenario declined up to 5.4 ft in the surficial aquifer and up to 2.9 ft in the Upper Floridan aquifer. Under the projected increases in groundwater pumping rates for 2035 that represented an increase of 36 percent from average 2004 to 2012 pumping rates, the simulated declines in the Floral City, Inverness, and Hernando pool stages were, in downstream order, 0.02, 0.06, and 0.04 ft. The largest drawdown under the projected increases in groundwater pumping rates for 2035 was 2.1 ft in the surficial aquifer and about 1.8 ft in the Upper Floridan aquifer. A scenario of decreased rainfall by 10 percent caused greater declines in water levels and pool stages than projected increases in groundwater pumping rates. The simulation with no flow through the eight Tsala Apopka Lake water-control structures resulted in simulated declines in average pool stage of 1.8, 1.9, and 0.5 ft in the Floral City, Inverness, and Hernando pools, respectively. The simulated removal of the two water-control structures in Lake Rousseau caused flow to increase at Rainbow Springs by 28 cubic feet per second, an increase of 4.7 percent from the average calibrated flow for 2004 to 2012.

  14. Occurrence and distribution of dissolved solids, selenium, and uranium in groundwater and surface water in the Arkansas River Basin from the headwaters to Coolidge, Kansas, 1970-2009

    USGS Publications Warehouse

    Miller, Lisa D.; Watts, Kenneth R.; Ortiz, Roderick F.; ,

    2010-01-01

    In 2007, the U.S. Geological Survey (USGS), in cooperation with City of Aurora, Colorado Springs Utilities, Colorado Water Conservation Board, Lower Arkansas Valley Water Conservancy District, Pueblo Board of Water Works, Southeastern Colorado Water Activity Enterprise, Southeastern Colorado Water Conservancy District, and Upper Arkansas Water Conservancy District began a retrospective evaluation to characterize the occurrence and distribution of dissolved-solids (DS), selenium, and uranium concentrations in groundwater and surface water in the Arkansas River Basin based on available water-quality data collected by several agencies. This report summarizes and characterizes available DS, dissolved-selenium, and dissolved-uranium concentrations in groundwater and surface water for 1970-2009 and describes DS, dissolved-selenium, and dissolved-uranium loads in surface water along the main-stem Arkansas River and selected tributary and diversion sites from the headwaters near Leadville, Colorado, to the USGS 07137500 Arkansas River near Coolidge, Kansas (Ark Coolidge), streamgage, a drainage area of 25,410 square miles. Dissolved-solids concentrations varied spatially in groundwater and surface water in the Arkansas River Basin. Dissolved-solids concentrations in groundwater from Quaternary alluvial, glacial drift, and wind-laid deposits (HSU 1) increased downgradient with median values of about 220 mg/L in the Upper Arkansas subbasin (Arkansas River Basin from the headwaters to Pueblo Reservoir) to about 3,400 mg/L in the Lower Arkansas subbasin (Arkansas River Basin from John Martin Reservoir to Ark Coolidge). Dissolved-solids concentrations in the Arkansas River also increased substantially in the downstream direction between the USGS 07086000 Arkansas River at Granite, Colorado (Ark Granite), and Ark Coolidge streamgages. Based on periodic data collected from 1976-2007, median DS concentrations in the Arkansas River ranged from about 64 mg/L at Ark Granite to about 4,060 mg/L at Ark Coolidge representing over a 6,000 percent increase in median DS concentrations. Temporal variations in specific conductance values (which are directly related to DS concentrations) and seasonal variations in DS concentrations and loads were investigated at selected sites in the Arkansas River from Ark Granite to Ark Coolidge. Analyses indicated that, for the most part, specific conductance values (surrogate for DS concentrations) have remained relatively constant or have decreased in the Arkansas River since about 1970. Dissolved-solids concentrations in the Arkansas River were higher during the nonirrigation season (November-February) than during the irrigation season (March-October). Average annual DS loads, however, were higher during the irrigation season than during the nonirrigation season. Average annual DS loads during the irrigation season were at least two times and as much as 23 times higher than average annual DS loads during the nonirrigation season with the largest differences occurring at sites located downstream from the two main-stem reservoirs at USGS 07099400 Arkansas River above Pueblo, Colorado (Ark Pueblo), (which is below Pueblo Reservoir) and USGS 07130500 Arkansas River below John Martin Reservoir, Colorado (Ark below JMR). View report for unabridged abstract.

  15. Modeling the Effect of Summertime Heating on Urban Runoff Temperature

    NASA Astrophysics Data System (ADS)

    Thompson, A. M.; Gemechu, A. L.; Norman, J. M.; Roa-Espinosa, A.

    2007-12-01

    Urban impervious surfaces absorb and store thermal energy, particularly during warm summer months. During a rainfall/runoff event, thermal energy is transferred from the impervious surface to the runoff, causing it to become warmer. As this higher temperature runoff enters receiving waters, it can be harmful to coldwater habitat. A simple model has been developed for the net energy flux at the impervious surfaces of urban areas to account for the heat transferred to runoff. Runoff temperature is determined as a function of the physical characteristics of the impervious areas, the weather, and the heat transfer between the moving film of runoff and the heated impervious surfaces that commonly exist in urban areas. Runoff from pervious surfaces was predicted using the Green- Ampt Mein-Larson infiltration excess method. Theoretical results were compared to experimental results obtained from a plot-scale field study conducted at the University of Wisconsin's West Madison Agricultural Research Station. Surface temperatures and runoff temperatures from asphalt and sod plots were measured throughout 15 rainfall simulations under various climatic conditions during the summers of 2004 and 2005. Average asphalt runoff temperatures ranged from 23.2°C to 37.1°C. Predicted asphalt runoff temperatures were in close agreement with measured values for most of the simulations (average RMSE = 4.0°C). Average pervious runoff temperatures ranged from 19.7° to 29.9°C and were closely approximated by the rainfall temperature (RMSE = 2.8°C). Predicted combined asphalt and sod runoff temperatures using a flow-weighted average were in close agreement with observed values (average RMSE = 3.5°C).

  16. Water use in Kansas, 1990-2000

    USGS Publications Warehouse

    Kenny, Joan F.; Hansen, Cristi V.

    2004-01-01

    This fact sheet compares water use in 1990, 1995, and 2000 for the 12 major river basins in Kansas. Of these 3 years, irrigation water use was largest in 1990 and smallest in 1995, largely because of differing climatic conditions. Irrigation averaged about 85 percent of total water use in Kansas each year, and ground water pumped in the western part of the State provided most of the irrigation water used. Water use for public supply, industry, and livestock increased between 1990 and 2000. Total State population increased 8 percent between 1990 and 2000, and the number of people served by public water suppliers increased 12 percent. Surface water withdrawn for public supply increased 24 percent because of population growth in the northeastern and south-central parts of the State and decreasing reliance on ground water by the city of Wichita. From 1990 to 2000, ground-water withdrawals for livestock and meat processing increased in western Kansas, and surface-water withdrawals for sand dredging increased in eastern Kansas. This fact sheet was produced as part of an ongoing cooperative program supported in part by the Kansas State Water Plan Fund.

  17. Geographic patterns of fishes and jellyfish in Puget Sound surface waters

    USGS Publications Warehouse

    Rice, Casimir A.; Duda, Jeffrey J.; Greene, Correigh M.; Karr, James R.

    2012-01-01

    We explored patterns of small pelagic fish assemblages and biomass of gelatinous zooplankton (jellyfish) in surface waters across four oceanographic subbasins of greater Puget Sound. Our study is the first to collect data documenting biomass of small pelagic fishes and jellyfish throughout Puget Sound; sampling was conducted opportunistically as part of a juvenile salmon survey of daytime monthly surface trawls at 52 sites during May–August 2003. Biomass composition differed spatially and temporally, but spatial differences were more distinct. Fish dominated in the two northern basins of Puget Sound, whereas jellyfish dominated in the two southern basins. Absolute and relative abundance of jellyfish, hatchery Chinook salmon Oncorhynchus tshawytscha, and chum salmon O. keta decreased with increasing latitude, whereas the absolute and relative abundance of most fish species and the average fish species richness increased with latitude. The abiotic factors with the strongest relationship to biomass composition were latitude, water clarity, and sampling date. Further study is needed to understand the spatial and temporal heterogeneity in the taxonomic composition we observed in Puget Sound surface waters, especially as they relate to natural and anthropogenic influences.

  18. Georeferenced model simulations efficiently support targeted monitoring

    NASA Astrophysics Data System (ADS)

    Berlekamp, Jürgen; Klasmeier, Jörg

    2010-05-01

    The European Water Framework Directive (WFD) demands the good ecological and chemical status of surface waters. To meet the definition of good chemical status of the WFD surface water concentrations of priority pollutants must not exceed established environmental quality standards (EQS). Surveillance of the concentrations of numerous chemical pollutants in whole river basins by monitoring is laborious and time-consuming. Moreover, measured data do often not allow for immediate source apportionment which is a prerequisite for defining promising reduction strategies to be implemented within the programme of measures. In this context, spatially explicit model approaches are highly advantageous because they provide a direct link between local point emissions (e.g. treated wastewater) or diffuse non-point emissions (e.g. agricultural runoff) and resulting surface water concentrations. Scenario analyses with such models allow for a priori investigation of potential positive effects of reduction measures such as optimization of wastewater treatment. The geo-referenced model GREAT-ER (Geography-referenced Regional Exposure Assessment Tool for European Rivers) has been designed to calculate spatially resolved averaged concentrations for different flow conditions (e.g. mean or low flow) based on emission estimations for local point source emissions such as treated effluents from wastewater treatment plants. The methodology was applied to selected pharmaceuticals (diclofenac, sotalol, metoprolol, carbamazepin) in the Main river basin in Germany (approx. 27,290 km²). Average concentrations of the compounds were calculated for each river reach in the whole catchment. Simulation results were evaluated by comparison with available data from orienting monitoring and used to develop an optimal monitoring strategy for the assessment of water quality regarding micropollutants at the catchment scale.

  19. Identification of Suitable Water Harvesting Zones Based on Geomorphic Resources for Drought Areas: A Case Study of Una District, Himachal Pradesh, India.

    NASA Astrophysics Data System (ADS)

    Prakasam, D. C., Jr.; Zaman, B.

    2014-12-01

    Water is one of the most vital natural resource and its availability and quality determine ecosystem productivity, both for agricultural and natural systems. Una district is one of the major potential agricultural districts in Himachal Pradesh, India. More than 70% of the population of this district is engaged in agriculture and allied sectors and major crops grown are maize, wheat, rice, sugarcane, pulses and vegetables. The region faces drought every year and about 90 per cent of the area is water stressed. This has resulted in crop loss and shortage of food and fodder. The sources of drinking water, small ponds and bowlies dry-up during summer season resulting in scarcity of drinking water. Una district receives rainfall during monsoons from June to September and also during non-monsoon period (winter). The annual average rainfall in the area is about 1040 mm with 55 average rainy days. But due to heavy surface run-off the farmers not able to cultivate the crops more than once in a year. Past research indicate that the geomorphology of the Una district might be responsible for such droughts as it controls the surface as well as ground water resources. The research proposes to develop a water stress model for Una district using the geomorphic parameters, water resource and land use land cover data of the study area. Using Survey of India topographical maps (1:50000), the geomorphic parameters are extracted. The spatial layers of these parameters i.e. drainage density, slope, relative relief, ruggedness index, surface water body's frequency are created in GIS. A time series of normalized remotely sensed data of the study area is used for land use land cover classification and analyses. Based on the results from the water stress model, the drought/water stress areas and water harvesting zones are identified and documented. The results of this research will help the general population in resolving the drinking water problem to a certain extent and also the cultivators to water the crops more than twice per year which might increase the crop yield in Una district.

  20. Mapping inter-annual dynamics of open surface water bodies in Oklahoma from Landsat images in 1984 to 2015 at 30-m spatial resolution

    NASA Astrophysics Data System (ADS)

    Zou, Z.; Xiao, X.; Menarguez, M.; Dong, J.; Qin, Y.

    2016-12-01

    Open surface water bodies are important water resource for public supply, irrigation, livestock, and wildlife in Oklahoma. The inter-annual variation of Oklahoma water bodies directly affect the water availability for public supply, irrigation and cattle industry. In this study, tens of thousands of Landsat TM/ETM+ images from 1984 to 2015 were used to track the dynamics of open surface water bodies. Both water-related spectral indices and vegetation indices were used to map water bodies for individual images. The resultant maps show that Oklahoma year-long open surface water bodies varied significantly over the last 32 years, with an average annual water body area equals to 2300 km2, accounting for 1.27 % of the Oklahoma state area (181,037 km2). 4.3 million year-long water body pixels were detected in the 32-year accumulated water frequency map, corresponding to 3100 km2. Only 45% ( 1400 km2) of the those pixels had water throughout the 32 years, while the rest 55% pixels had a dry-up period. The smaller water bodies have a higher risk to dry up and a lower probability to have water throughout the years. Drought years could significantly decrease the number of small water bodies and shrink the area of large water bodies, while pluvial years could create large number of small seasonal water bodies. The significant influencing factors of current year water bodies include the precipitation and temperature of current year and the water body condition of the previous year. This water body dynamics study could be used to support water resource management, crop and livestock production, and biodiversity conservation in Oklahoma.

  1. Overview of surface-water resources at the U.S. Coast Guard Support Center Kodiak, Alaska, 1987-89

    USGS Publications Warehouse

    Solin, G.L.

    1996-01-01

    Hydrologic data at a U.S. Coast Guard Support Center on Kodiak Island, Alaska, were collected from 1987 though 1989 to determine hydrologic conditions and if contamination of soils, ground water, or surface water has occurred. This report summarizes the surface-water-discharge data collected during the study and estimates peak, average, and low-flow values for Buskin River near its mouth. Water-discharge measurements were made at least once at 48 sites on streams in or near the Center. Discharges were measured in the Buskin River near its mouth five times during 1987-89 and ranged from 27 to 367 cubic feet per second. Tributaries of Buskin River below Buskin Lake that had discharges greater than 1 cubic foot per second include Bear Creek, Alder Creek, Magazine Creek, Devils Creek and an outlet from Lake Louise. Streams having flows generally greater than 0.1 cubic foot per second but less than 1 cubic foot per second include an unnamed tributary to Buskin River, an unnamed tributary to Lake Catherine and a drainage channel at Kodiak airport. Most other streams flowing into Buskin River, and all streams on Nyman Peninsula, usually had little or no flow except during periods of rainfall or snowmelt. During a low-flow period in February 1989, discharge measurements in Buskin River and its tributaries indicate that three reaches of Buskin River below Buskin Lake lost water to the ground-water system, whereas two reaches gained water; the net gain in streamflow attributed to ground-water inflow at a location near the mouth was estimated to be 2.2 cubic feet per second. The 100-year peak flow for Buskin River near its mouth was estimated to be 4,460 cubic feet per second. Average discharge was estimated to be 125 cubic feet per second and the 7-day 10-year low flow was estimated to be 5.8 cubic feet per second.

  2. Mapping global surface water inundation dynamics using synergistic information from SMAP, AMSR2 and Landsat

    NASA Astrophysics Data System (ADS)

    Du, J.; Kimball, J. S.; Galantowicz, J. F.; Kim, S.; Chan, S.; Reichle, R. H.; Jones, L. A.; Watts, J. D.

    2017-12-01

    A method to monitor global land surface water (fw) inundation dynamics was developed by exploiting the enhanced fw sensitivity of L-band (1.4 GHz) passive microwave observations from the Soil Moisture Active Passive (SMAP) mission. The L-band fw (fwLBand) retrievals were derived using SMAP H-polarization brightness temperature (Tb) observations and predefined L-band reference microwave emissivities for water and land endmembers. Potential soil moisture and vegetation contributions to the microwave signal were represented from overlapping higher frequency Tb observations from AMSR2. The resulting fwLBand global record has high temporal sampling (1-3 days) and 36-km spatial resolution. The fwLBand annual averages corresponded favourably (R=0.84, p<0.001) with a 250-m resolution static global water map (MOD44W) aggregated at the same spatial scale, while capturing significant inundation variations worldwide. The monthly fwLBand averages also showed seasonal inundation changes consistent with river discharge records within six major US river basins. An uncertainty analysis indicated generally reliable fwLBand performance for major land cover areas and under low to moderate vegetation cover, but with lower accuracy for detecting water bodies covered by dense vegetation. Finer resolution (30-m) fwLBand results were obtained for three sub-regions in North America using an empirical downscaling approach and ancillary global Water Occurrence Dataset (WOD) derived from the historical Landsat record. The resulting 30-m fwLBand retrievals showed favourable classification accuracy for water (commission error 31.84%; omission error 28.08%) and land (commission error 0.82%; omission error 0.99%) and seasonal wet and dry periods when compared to independent water maps derived from Landsat-8 imagery. The new fwLBand algorithms and continuing SMAP and AMSR2 operations provide for near real-time, multi-scale monitoring of global surface water inundation dynamics, potentially benefiting hydrological monitoring, flood assessments, and global climate and carbon modeling.

  3. On the transition towards slow manifold in shallow-water and 3D Euler equations in a rotating frame

    NASA Technical Reports Server (NTRS)

    Mahalov, A.

    1994-01-01

    The long-time, asymptotic state of rotating homogeneous shallow-water equations is investigated. Our analysis is based on long-time averaged rotating shallow-water equations describing interactions of large-scale, horizontal, two-dimensional motions with surface inertial-gravity waves field for a shallow, uniformly rotating fluid layer. These equations are obtained in two steps: first by introducing a Poincare/Kelvin linear propagator directly into classical shallow-water equations, then by averaging. The averaged equations describe interaction of wave fields with large-scale motions on time scales long compared to the time scale 1/f(sub o) introduced by rotation (f(sub o)/2-angular velocity of background rotation). The present analysis is similar to the one presented by Waleffe (1991) for 3D Euler equations in a rotating frame. However, since three-wave interactions in rotating shallow-water equations are forbidden, the final equations describing the asymptotic state are simplified considerably. Special emphasis is given to a new conservation law found in the asymptotic state and decoupling of the dynamics of the divergence free part of the velocity field. The possible rising of a decoupled dynamics in the asymptotic state is also investigated for homogeneous turbulence subjected to a background rotation. In our analysis we use long-time expansion, where the velocity field is decomposed into the 'slow manifold' part (the manifold which is unaffected by the linear 'rapid' effects of rotation or the inertial waves) and a formal 3D disturbance. We derive the physical space version of the long-time averaged equations and consider an invariant, basis-free derivation. This formulation can be used to generalize Waleffe's (1991) helical decomposition to viscous inhomogeneous flows (e.g. problems in cylindrical geometry with no-slip boundary conditions on the cylinder surface and homogeneous in the vertical direction).

  4. Assessment of Surface Water Contamination from Coalbed Methane Fracturing-Derived Volatile Contaminants in Sullivan County, Indiana, USA.

    PubMed

    Meszaros, Nicholas; Subedi, Bikram; Stamets, Tristan; Shifa, Naima

    2017-09-01

    There is a growing concern over the contamination of surface water and the associated environmental and public health consequences from the recent proliferation of hydraulic fracturing in the USA. Petroleum hydrocarbon-derived contaminants of concern [benzene, toluene, ethylbenzene, and xylenes (BTEX)] and various dissolved cations and anions were spatially determined in surface waters around 15 coalbed methane fracking wells in Sullivan County, IN, USA. At least one BTEX compound was detected in 69% of sampling sites (n = 13) and 23% of sampling sites were found to be contaminated with all of the BTEX compounds. Toluene was the most common BTEX compound detected across all sampling sites, both upstream and downstream from coalbed methane fracking wells. The average concentration of toluene at a reservoir and its outlet nearby the fracking wells was ~2× higher than other downstream sites. However, one of the upstream sites was found to be contaminated with BTEX at similar concentrations as in a reservoir site nearby the fracking well. Calcium (~60 ppm) and sulfates (~175 ppm) were the dominant cations and anions, respectively, in surface water around the fracking sites. This study represents the first report of BTEX contamination in surface water from coalbed methane hydraulic fracturing wells.

  5. Multinuclear NMR studies of single lipid bilayers supported in cylindrical aluminum oxide nanopores.

    PubMed

    Gaede, Holly C; Luckett, Keith M; Polozov, Ivan V; Gawrisch, Klaus

    2004-08-31

    Lipid bilayers were deposited inside the 0.2 microm pores of anodic aluminum oxide (AAO) filters by extrusion of multilamellar liposomes and their properties studied by 2H, 31P, and 1H solid-state NMR. Only the first bilayer adhered strongly to the inner surface of the pores. Additional layers were washed out easily by a flow of water as demonstrated by 1H magic angle spinning NMR experiments with addition of Pr3+ ions to shift accessible lipid headgroup resonances. A 13 mm diameter Anopore filter of 60 microm thickness oriented approximately 2.5 x 10(-7) mol of lipid as a single bilayer, corresponding to a total membrane area of about 500 cm2. The 2H NMR spectra of chain deuterated POPC are consistent with adsorption of wavy, tubular bilayers to the inner pore surface. By NMR diffusion experiments, we determined the average length of those lipid tubules to be approximately 0.4 microm. There is evidence for a thick water layer between lipid tubules and the pore surface. The ends of tubules are well sealed against the pore such that Pr3+ ions cannot penetrate into the water underneath the bilayers. We successfully trapped poly(ethylene glycol) (PEG) with a molecular weight of 8000 in this water layer. From the quantity of trapped PEG, we calculated an average water layer thickness of 3 nm. Lipid order parameters and motional properties are unperturbed by the solid support, in agreement with existence of a water layer. Such unperturbed, solid supported membranes are ideal for incorporation of membrane-spanning proteins with large intra- and extracellular domains. The experiments suggest the promise of such porous filters as membrane support in biosensors.

  6. On the theory relating changes in area-average and pan evaporation (Invited)

    NASA Astrophysics Data System (ADS)

    Shuttleworth, W.; Serrat-Capdevila, A.; Roderick, M. L.; Scott, R.

    2009-12-01

    Theory relating changes in area-average evaporation with changes in the evaporation from pans or open water is developed. Such changes can arise by Type (a) processes related to large-scale changes in atmospheric concentrations and circulation that modify surface evaporation rates in the same direction, and Type (b) processes related to coupling between the surface and atmospheric boundary layer (ABL) at the landscape scale that usually modify area-average evaporation and pan evaporation in different directions. The interrelationship between evaporation rates in response to Type (a) changes is derived. They have the same sign and broadly similar magnitude but the change in area-average evaporation is modified by surface resistance. As an alternative to assuming the complementary evaporation hypothesis, the results of previous modeling studies that investigated surface-atmosphere coupling are parameterized and used to develop a theoretical description of Type (b) coupling via vapor pressure deficit (VPD) in the ABL. The interrelationship between appropriately normalized pan and area-average evaporation rates is shown to vary with temperature and wind speed but, on average, the Type (b) changes are approximately equal and opposite. Long-term Australian pan evaporation data are analyzed to demonstrate the simultaneous presence of Type (a) and (b) processes, and observations from three field sites in southwestern USA show support for the theory describing Type (b) coupling via VPD. England's victory over Australia in 2009 Ashes cricket test match series will not be mentioned.

  7. Using Iron-Manganese Co-Oxide Filter Film to Remove Ammonium from Surface Water

    PubMed Central

    Zhang, Ruifeng; Huang, Tinglin; Wen, Gang; Chen, Yongpan; Cao, Xin; Zhang, Beibei

    2017-01-01

    An iron-manganese co-oxide filter film (MeOx) has been proven to be a good catalyst for the chemical catalytic oxidation of ammonium in groundwater. Compared with groundwater, surface water is generally used more widely and has characteristics that make ammonium removal more difficult. In this study, MeOx was used to remove ammonium from surface water. It indicated that the average ammonium removal efficiency of MeOx was greater than 90%, even though the water quality changed dramatically and the water temperature was reduced to about 6–8 °C. Then, through inactivating microorganisms, it showed that the removal capability of MeOx included both biological (accounted for about 41.05%) and chemical catalytic oxidation and chemical catalytic oxidation (accounted for about 58.95%). The investigation of the characterizations suggested that MeOx was formed by abiotic ways and the main elements on the surface of MeOx were distributed homogenously. The analysis of the catalytic oxidation process indicated that ammonia nitrogen may interact with MeOx as both ammonia molecules and ammonium ions and the active species of O2 were possibly •O and O2−. PMID:28753939

  8. Using Iron-Manganese Co-Oxide Filter Film to Remove Ammonium from Surface Water.

    PubMed

    Zhang, Ruifeng; Huang, Tinglin; Wen, Gang; Chen, Yongpan; Cao, Xin; Zhang, Beibei

    2017-07-19

    An iron-manganese co-oxide filter film (MeO x ) has been proven to be a good catalyst for the chemical catalytic oxidation of ammonium in groundwater. Compared with groundwater, surface water is generally used more widely and has characteristics that make ammonium removal more difficult. In this study, MeO x was used to remove ammonium from surface water. It indicated that the average ammonium removal efficiency of MeO x was greater than 90%, even though the water quality changed dramatically and the water temperature was reduced to about 6-8 °C. Then, through inactivating microorganisms, it showed that the removal capability of MeO x included both biological (accounted for about 41.05%) and chemical catalytic oxidation and chemical catalytic oxidation (accounted for about 58.95%). The investigation of the characterizations suggested that MeO x was formed by abiotic ways and the main elements on the surface of MeO x were distributed homogenously. The analysis of the catalytic oxidation process indicated that ammonia nitrogen may interact with MeO x as both ammonia molecules and ammonium ions and the active species of O₂ were possibly • O and O₂ - .

  9. Pre-bomb {Delta}{sup 14}C variability and the Suess Effect in Cariaco Basin Surface Waters as Recorded in Hermatypic Corals

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Guilderson, T; Cole, J; Southon, J

    2004-10-28

    The {Delta}{sup 14}C content of surface waters in and around the Cariaco Basin were reconstructed from {sup 14}C measurements on sub-annually sampled coral skeletal material. During the late 1930s - early 1940s surface waters within and outside of the Cariaco Basin are similar. Within the Cariaco Basin at Islas Tortugas coral {Delta}{sup 14}C averages -51.9 {+-}3.3 {per_thousand}. Corals collected outside of the basin at Boca de Medio and Los Testigos have {Delta}{sup 14}C values of -53.4 {+-} 3.3 {per_thousand} and -54.3 {+-} 2.6 respectively. Additional {sup 14}C analyses on the Isla Tortugas coral document an {approx} 11 {per_thousand} decrease betweenmore » {approx}1905 (-40.9 {+-}4.5 {per_thousand}) and {approx}1940. The implied Suess Effect trend (-3 {per_thousand}/decade) is nearly as large as that observed in the atmosphere over the same time period. If we assume that there is little to no fossil fuel {sup 14}CO{sub 2} signature in Cariaco surface waters in {approx}1905, the waters have an equivalent reservoir age of {approx}312 years.« less

  10. Early stages in the evolution of the atmosphere and climate on the Earth-group planets

    NASA Technical Reports Server (NTRS)

    Moroz, V. I.; Mukhin, L. M.

    1977-01-01

    The early evolution of the atmospheres and climate of the Earth, Mars and Venus is discussed, based on a concept of common initial conditions and main processes (besides known differences in chemical composition and outgassing rate). It is concluded that: (1) liquid water appeared on the surface of the earth in the first few hundred million years; the average surface temperature was near the melting point for about the first two eons; CO2 was the main component of the atmosphere in the first 100-500 million years; (2) much more temperate outgassing and low solar heating led to the much later appearance of liquid water on the Martian surface, only one to two billion years ago; the Martian era of rivers, relatively dense atmosphere and warm climate ended as a result of irreversible chemical bonding of CO2 by Urey equilibrium processes; (3) a great lack of water in the primordial material of Venus is proposed; liquid water never was present on the surface of the planet, and there was practically no chemical bonding of CO2; the surface temperature was over 600 K four billion years ago.

  11. Water quality in irrigation and drainage networks of Thessaloniki plain in Greece related to land use, water management, and agroecosystem protection.

    PubMed

    Litskas, Vassilis D; Aschonitis, Vassilis G; Antonopoulos, Vassilis Z

    2010-04-01

    A representative agricultural area of 150 ha located in a protected ecosystem (Axios River Delta, Thermaikos Gulf-N. Aegean, Greece) was selected in order to investigate water quality parameters [pH, electrical conductivity (EC(w)), NO(3)-N, NH(4)-N, total phosphorus (TP)] in irrigation and drainage water. In the study area, the cultivated crops are mainly rice, maize, cotton, and fodder. Surface irrigation methods are applied using open channels network, and irrigation water is supplied by Axios River, which is facing pollution problems. The return flow from surface runoff and the surplus of irrigation water are collected to drainage network and disposed to Thermaikos Gulf. A 2-year study (2006-2007) was conducted in order to evaluate the effects of land use and irrigation water management on the drainage water quality. The average pH and NO(3)-N concentration was higher in the irrigation water (8.0 and 1.3 mg/L, respectively) than that in the drainage water (7.6 and 1.0 mg/L, respectively). The average EC(W), NH(4)-N, and TP concentration was higher in the drainage water (1,754 muS/cm, 90.3 microg/L, and 0.2 mg/L, respectively) than that in the irrigation water (477.1 muS/cm, 46.7 microg/L, and 0.1 mg/L, respectively). Average irrigation efficiency was estimated at 47% and 51% in 2006 and 2007 growing seasons (April-October), respectively. The loads of NO(3)-N in both seasons were higher in the irrigation water (35.1 kg/ha in 2006 and 24.9 kg/ha in 2007) than those in the drainage water (8.1 kg/ha in 2006 and 7.6 kg/ha in 2007). The load of TP was higher in the irrigation water in season 2006 (2.8 kg/ha) than that in the drainage water (1.1 kg/ha). Total phosphorus load in 2007 was equal in irrigation and drainage water (1.2 kg/ha). Wetland conditions, due to rice irrigation regime, drainage network characteristics, and the crop distribution in the study area, affect the drainage water ending in the protected ecosystem of Thermaikos Gulf.

  12. Water requirements of the petroleum refining industry

    USGS Publications Warehouse

    Otts, Louis Ethelbert

    1964-01-01

    About 3,500 million gallons of water was withdrawn daily in 1955 for use by petroleum refineries in the United States. This was about 3 percent of the estimated daily withdrawal of industrial water in the United States in 1955. An average of 468 gallons of water was required to refine a barrel of crude oil, and the median was 95 gallons of water per barrel of crude charge; withdrawals ranged from 6.5 to 3,240 gallons per barrel. Ninety-one percent of the water requirements of the petroleum refineries surveyed was for cooling. One-third of the refineries reused their cooling water from 10 to more than 50 times. Only 17 refineries used once-through cooling systems. Refineries with recirculating cooling systems circulated about twice as much cooling water but needed about 25 times less makeup; however, they consumed about 24 times more water per barrel of charge than refineries using once-through cooling systems. The average noncracking refinery used about 375 gallons of water per barrel of crude, which is less than the 471-gallon average of refineries with cracking facilities. Refineries are composed of various processing units, and the water requirements of such units varied ; median makeup needs ranged from about 125 gallons per barrel for polymerization and alkylation units to 15.5 gallons per barrel for distillation units. Refinery-owned sources of water supplied 95 percent of the makeup-water requirements. Surface-water sources provided 86 percent of the makeup-water demand. Less than 1 percent of the makeup water was obtained from reprocessed municipal sewage.

  13. Underground storage of imported water in the San Gorgonio Pass area, southern California

    USGS Publications Warehouse

    Bloyd, Richard M.

    1971-01-01

    The San Gorgonio Pass ground-water basin is divided into the Beaumont, Banning, Cabazon, San Timoteo, South Beaumont, Banning Bench, and Singleton storage units. The Beaumont storage unit, centrally located in the agency area, is the largest in volume of the storage units. Estimated long-term average annual precipitation in the San Gorgonio Pass Water Agency drainage area is 332,000 acre-feet, and estimated average annual recoverable water is 24,000 acre-feet, less than 10 percent of the total precipitation. Estimated average annual surface outflow is 1,700 acre-feet, and estimated average annual ground-water recharge is 22,000 acre-feet. Projecting tack to probable steady-state conditions, of the 22.000 acre-feet of recharge, 16,003 acre-feet per year became subsurface outflow into Coachella Valley, 6,000 acre-feet into the Redlands area, and 220 acre-feet into Potrero Canyon. After extensive development, estimated subsurface outflow from the area in 1967 was 6,000 acre-feet into the Redlands area, 220 acre-feet into Potrero Canyon, and 800 acre-feet into the fault systems south of the Banning storage unit, unwatered during construction of a tunnel. Subsurface outflow into Coachella Valley in 1967 is probably less than 50 percent of the steady-state flow. An anticipated 17,000 .acre-feet of water per year will be imported by 1980. Information developed in this study indicates it is technically feasible to store imported water in the eastern part of the Beaumont storage unit without causing waterlogging in the storage area and without losing any significant quantity of stored water.

  14. Modeling Climate-Water Impacts on Electricity Sector Capacity Expansion: Preprint

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cohen, S. M.; Macknick, J.; Averyt, K.

    2014-05-01

    Climate change has the potential to exacerbate water availability concerns for thermal power plant cooling, which is responsible for 41% of U.S. water withdrawals. This analysis describes an initial link between climate, water, and electricity systems using the National Renewable Energy Laboratory (NREL) Regional Energy Deployment System (ReEDS) electricity system capacity expansion model. Average surface water projections from Coupled Model Intercomparison Project 3 (CMIP3) data are applied to surface water rights available to new generating capacity in ReEDS, and electric sector growth is compared with and without climate-influenced water rights. The mean climate projection has only a small impact onmore » national or regional capacity growth and water use because most regions have sufficient unappropriated or previously retired water rights to offset climate impacts. Climate impacts are notable in southwestern states that purchase fewer water rights and obtain a greater share from wastewater and other higher-cost water resources. The electric sector climate impacts demonstrated herein establish a methodology to be later exercised with more extreme climate scenarios and a more rigorous representation of legal and physical water availability.« less

  15. The role of storage capacity in coping with intra-annual runoff variability on a global scale

    NASA Astrophysics Data System (ADS)

    Gaupp, Franziska; Hall, Jim; Dadson, Simon

    2015-04-01

    Intra-annual variability poses a risk to water security in many basins as runoff is unevenly distributed over the year. Areas such as Northern Africa, Australia and the South-Western USA are characterized by a high coefficient of variability of monthly runoff. Analyzing the global risk of water scarcity, this study examines 680 basin-country units (BCUs) (403 river basins divided by country borders). By calculating the water balance for each BCU, the interplay of runoff on the one hand and domestic, industrial and environmental water needs on the other hand is shown. In contrast to other studies on average water scarcity, this work focuses on variability of water supply as metrics based on annual average water availability and demand can underestimate the risk of scarcity. The model is based on the assumption that each country-basin with sub-basins and tributaries can be treated as one single reservoir with storage capacity aggregated over that BCU. It includes surface runoff and the possibility to withdraw groundwater as water supply. The storage capacity of each BCU represents the ability to transfer water from wet months to dry months in order to buffer and cope with intra-annual water supply variability and to meet total water demand. Average monthly surface runoff per country-basin for the period 1979 to 2012 is derived from outcomes of the hydrological model Mac-PDM. Mac-PDM is forced with monthly ERAI-Interim reanalysis climate data on a one degree resolution. Groundwater withdrawal capacity, total water demand and storage capacity are taken from the IMPACT model provided by the International Food Research Institute (IFPRI). Storage refers to any kind of surface reservoir whose water can be managed and used for human activities in the industrial, domestic and agricultural sectors. Groundwater withdrawal capacity refers to the technological capacity to pump water rather than the amount of groundwater available. Total water demand includes consumptive water use from the industrial, domestic and agricultural sectors and varies between months. Due to a lack of data, the 2010 figures for groundwater withdrawal capacity are assumed to be equally distributed over 12 months without accounting for possible variation within a year. For runoff and water demand, monthly data are used. Our study shows that storage capacity helps to cope with intra-annual water variability and thereby decreases the risk of water scarcity. Several cases emerge where water security is critically dependent on transboundary flows such as the Nile in Egypt or the Aral Drainage in Uzbekistan. Furthermore, we calculate environmental flow requirements using the Variable Monthly Flow (VMF) method and analyse the effects of abstraction and dam construction on environmental flows. For each BCU, we examine whether environmental water requirements can be met with given human abstractions. Additionally, water scarcity is examined for the case when water is reserved for the environment and cannot be abstracted for human purposes.

  16. Temperature dependence of the evaporation lengthscale for water confined between two hydrophobic plates.

    PubMed

    Djikaev, Yuri S; Ruckenstein, Eli

    2015-07-01

    Liquid water in a hydrophobic confinement is the object of high interest in physicochemical sciences. Confined between two macroscopic hydrophobic surfaces, liquid water transforms into vapor if the distance between surfaces is smaller than a critical separation, referred to as the evaporation lengthscale. To investigate the temperature dependence of the evaporation lengthscale of water confined between two hydrophobic parallel plates, we use the combination of the density functional theory (DFT) with the probabilistic hydrogen bond (PHB) model for water-water hydrogen bonding. The PHB model provides an analytic expression for the average number of hydrogen bonds per water molecule as a function of its distance to a hydrophobic surface and its curvature. Knowing this expression, one can implement the effect of hydrogen bonding between water molecules on their interaction with the hydrophobe into DFT, which is then employed to determine the distribution of water molecules between two macroscopic hydrophobic plates at various interplate distances and various temperatures. For water confined between hydrophobic plates, our results suggest the evaporation lengthscale to be of the order of several nanometers and a linearly increasing function of temperature from T=293 K to T=333 K, qualitatively consistent with previous results. Copyright © 2015 Elsevier Inc. All rights reserved.

  17. Hydrologic modeling in a marsh-mangrove ecotone: Predicting wetland surface water and salinity response to restoration in the Ten Thousand Islands region of Florida, USA

    USGS Publications Warehouse

    Michot, B.D.; Meselhe, E.A.; Krauss, Ken W.; Shrestha, Surendra; From, Andrew S.; Patino, Eduardo

    2017-01-01

    At the fringe of Everglades National Park in southwest Florida, United States, the Ten Thousand Islands National Wildlife Refuge (TTINWR) habitat has been heavily affected by the disruption of natural freshwater flow across the Tamiami Trail (U.S. Highway 41). As the Comprehensive Everglades Restoration Plan (CERP) proposes to restore the natural sheet flow from the Picayune Strand Restoration Project area north of the highway, the impact of planned measures on the hydrology in the refuge needs to be taken into account. The objective of this study was to develop a simple, computationally efficient mass balance model to simulate the spatial and temporal patterns of water level and salinity within the area of interest. This model could be used to assess the effects of the proposed management decisions on the surface water hydrological characteristics of the refuge. Surface water variations are critical to the maintenance of wetland processes. The model domain is divided into 10 compartments on the basis of their shared topography, vegetation, and hydrologic characteristics. A diversion of +10% of the discharge recorded during the modeling period was simulated in the primary canal draining the Picayune Strand forest north of the Tamiami Trail (Faka Union Canal) and this discharge was distributed as overland flow through the refuge area. Water depths were affected only modestly. However, in the northern part of the refuge, the hydroperiod, i.e., the duration of seasonal flooding, was increased by 21 days (from 115 to 136 days) for the simulation during the 2008 wet season, with an average water level rise of 0.06 m. The average salinity over a two-year period in the model area just south of Tamiami Trail was reduced by approximately 8 practical salinity units (psu) (from 18 to 10 psu), whereas the peak dry season average was reduced from 35 to 29 psu (by 17%). These salinity reductions were even larger with greater flow diversions (+20%). Naturally, the reduction in salinity diminished toward the open water areas where the daily flood tides mix in saline bay water. Partially restoring hydrologic flows to TTINWR will affect hydroperiod and salinity regimes within downslope wetlands, and perhaps serve as a management tool to reduce the speed of future encroachment of mangroves into marsh as sea levels rise.

  18. Drinking water as a proportion of total human exposure to volatile N-nitrosamines.

    PubMed

    Hrudey, Steve E; Bull, Richard J; Cotruvo, Joseph A; Paoli, Greg; Wilson, Margaret

    2013-12-01

    Some volatile N-nitrosamines, primarily N-nitrosodimethylamine (NDMA), are recognized as products of drinking water treatment at ng/L levels and as known carcinogens. The U.S. EPA has identified the N-nitrosamines as contaminants being considered for regulation as a group under the Safe Drinking Water Act. Nitrosamines are common dietary components, and a major database (over 18,000 drinking water samples) has recently been created under the Unregulated Contaminant Monitoring Rule. A Monte Carlo modeling analysis in 2007 found that drinking water contributed less than 2.8% of ingested NDMA and less than 0.02% of total NDMA exposure when estimated endogenous formation was considered. Our analysis, based upon human blood concentrations, indicates that endogenous NDMA production is larger than expected. The blood-based estimates are within the range that would be calculated from estimates based on daily urinary NDMA excretion and an estimate based on methylated guanine in DNA of lymphocytes from human volunteers. Our analysis of ingested NDMA from food and water based on Monte Carlo modeling with more complete data input shows that drinking water contributes a mean proportion of the lifetime average daily NDMA dose ranging from between 0.0002% and 0.001% for surface water systems using free chlorine or between 0.001% and 0.01% for surface water systems using chloramines. The proportions of average daily dose are higher for infants (zero to six months) than other age cohorts, with the highest mean up to 0.09% (upper 95th percentile of 0.3%). © 2013 Society for Risk Analysis.

  19. Recalibration and predictive reliability of a solute-transport model of an irrigated stream-aquifer system

    USGS Publications Warehouse

    Person, M.; Konikow, Leonard F.

    1986-01-01

    A solute-transport model of an irrigated stream-aquifer system was recalibrated because of discrepancies between prior predictions of ground-water salinity trends during 1971-1982 and the observed outcome in February 1982. The original model was calibrated with a 1-year record of data collected during 1971-1972 in an 18-km reach of the Arkansas River Valley in southeastern Colorado. The model is improved by incorporating additional hydrologic processes (salt transport through the unsaturated zone) and through reexamination of the reliability of some input data (regression relationship used to estimate salinity from specific conductance data). Extended simulations using the recalibrated model are made to investigate the usefulness of the model for predicting long-term trends of salinity and water levels within the study area. Predicted ground-water levels during 1971-1982 are in good agreement with the observed, indicating that the original 1971-1972 study period was sufficient to calibrate the flow model. However, long-term simulations using the recalibrated model based on recycling the 1971-1972 data alone yield an average ground-water salinity for 1982 that is too low by about 10%. Simulations that incorporate observed surface-water salinity variations yield better results, in that the calculated average ground-water salinity for 1982 is within 3% of the observed value. Statistical analysis of temporal salinity variations of the applied surface water indicates that at least a 4-year sampling period is needed to accurately calibrate the transport model. ?? 1986.

  20. Water's role in the force-induced unfolding of ubiquitin.

    PubMed

    Li, Jingyuan; Fernandez, Julio M; Berne, B J

    2010-11-09

    In atomic force spectroscopic studies of the elastomeric protein ubiquitin, the β-strands 1-5 serve as the force clamp. Simulations show how the rupture force in the force-induced unfolding depends on the kinetics of water molecule insertion into positions where they can eventually form hydrogen bonding bridges with the backbone hydrogen bonds in the force-clamp region. The intrusion of water into this region is slowed down by the hydrophobic shielding effect of carbonaceous groups on the surface residues of β-strands 1-5, which thereby regulates water insertion prior to hydrogen bond breakage. The experiments show that the unfolding of the mechanically stressed protein is nonexponential due to static disorder. Our simulations show that different numbers and/or locations of bridging water molecules give rise to a long-lived distribution of transition states and static disorder. We find that slowing down the translational (not rotational) motions of the water molecules by increasing the mass of their oxygen atoms, which leaves the force field and thereby the equilibrium structure of the solvent unchanged, increases the average rupture force; however, the early stages of the force versus time behavior are very similar for our "normal" and fictitious "heavy" water models. Finally, we construct six mutant systems to regulate the hydrophobic shielding effect of the surface residues in the force-clamp region. The mutations in the two termini of β-sheets 1-5 are found to determine a preference for different unfolding pathways and change mutant's average rupture force.

  1. Relations between precipitation, groundwater withdrawals, and changes in hydrologic conditions at selected monitoring sites in Volusia County, Florida, 1995--2010

    USGS Publications Warehouse

    Murray, Louis C.

    2012-01-01

    A study to examine the influences of climatic and anthropogenic stressors on groundwater levels, lake stages, and surface-water discharge at selected sites in northern Volusia County, Florida, was conducted in 2009 by the U.S. Geological Survey. Water-level data collected at 20 monitoring sites (17 groundwater and 3 lake sites) in the vicinity of a wetland area were analyzed with multiple linear regression to examine the relative influences of precipitation and groundwater withdrawals on changes in groundwater levels and lake stage. Analyses were conducted across varying periods of record between 1995 and 2010 and included the effects of groundwater withdrawals aggregated from municipal water-supply wells located within 12 miles of the project sites. Surface-water discharge data at the U.S. Geological Survey Tiger Bay canal site were analyzed for changes in flow between 1978 and 2001. As expected, water-level changes in monitoring wells located closer to areas of concentrated groundwater withdrawals were more highly correlated with withdrawals than were water-level changes measured in wells further removed from municipal well fields. Similarly, water-level changes in wells tapping the Upper Floridan aquifer, the source of municipal supply, were more highly correlated with groundwater withdrawals than were water-level changes in wells tapping the shallower surficial aquifer system. Water-level changes predicted by the regression models over precipitation-averaged periods of record were underestimated for observations having large positive monthly changes (generally greater than 1.0 foot). Such observations are associated with high precipitation and were identified as points in the regression analyses that produced large standardized residuals and/or observations of high influence. Thus, regression models produced by multiple linear regression analyses may have better predictive capability in wetland environments when applied to periods of average or below average precipitation conditions than during wetter than average conditions. For precipitation-averaged hydrologic conditions, water-level changes in the surficial aquifer system were statistically correlated solely with precipitation or were more highly correlated with precipitation than with groundwater withdrawals. Changes in Upper Floridan aquifer water levels and in water-surface stage (stage) at Indian and Scoggin Lakes tended to be highly correlated with both precipitation and withdrawals. The greater influence of withdrawals on stage changes, relative to changes in nearby surficial aquifer system water levels, indicates that these karstic lakes may be better connected hydraulically with the underlying Upper Floridan aquifer than is the surficial aquifer system at the other monitoring sites. At most sites, and for both aquifers, the 2-month moving average of precipitation or groundwater withdrawals included as an explanatory variable in the regression models indicates that water-level changes are not only influenced by stressor conditions across the current month, but also by those of the previous month. The relations between changes in water levels, precipitation, and groundwater withdrawals varied seasonally and in response to a period of drought. Water-level changes tended to be most highly correlated with withdrawals during the spring, when relatively large increases contributed to water-level declines, and during the fall when reduced withdrawal rates contributed to water-level recovery. Water-level changes tended to be most highly (or solely) correlated with precipitation in the winter, when withdrawals are minimal, and in the summer when precipitation is greatest. Water-level changes measured during the drought of October 2005 to June 2008 tended to be more highly correlated with groundwater withdrawals at Upper Floridan aquifer sites than at surficial aquifer system sites, results that were similar to those for precipitation-averaged conditions. Also, changes in stage at Indian and Scoggin Lakes were highly correlated with precipitation and groundwater withdrawals during the drought. Groundwater-withdrawal rates during the drought were, on average, greater than those for precipitation-averaged conditions. Accounting only for withdrawals aggregated from pumping wells located within varying radial distances of less than 12 miles of each site produced essentially the same relation between water-level changes and groundwater withdrawals as that determined for withdrawals aggregated within 12 miles of the site. Similarly, increases in withdrawals aggregated over distances of 1 to 12 miles of the sites had little effect on adjusted R-squared values. Analyses of streamflow measurements collected between 1978 and 2001 at the U.S. Geological Survey Tiger Bay canal site indicate that significant changes occurred during base-flow conditions during that period. Hypothesis and trend testing, together with analyses of flow duration, the number of zero-flow days, and double-mass curves indicate that, after 1988, when a municipal well field began production, base flow was statistically lower than the period before 1988. This decrease in base flow could not be explained by variations in precipitation between these two periods.

  2. Prediction of concentration levels of metformin and other high consumption pharmaceuticals in wastewater and regional surface water based on sales data.

    PubMed

    Oosterhuis, Mathijs; Sacher, Frank; Ter Laak, Thomas L

    2013-01-01

    Local consumption data of pharmaceuticals were used to study the emission to wastewater and surface waters in two small Dutch water catchments. For nine high consumption pharmaceuticals: metformin, metoprolol, sotalol, losartan, valsartan, irbesartan, hydrochlorothiazide, diclofenac and carbamazepine, predicted emissions were compared to wastewater concentrations, removal in sewage treatment plants and recovery in regional surface water. The study shows that local consumption data can be very useful to select pharmaceuticals for monitoring and to predict wastewater concentrations. Measured influent concentrations were on average 78% with a range of 31-138% of predicted influent concentrations. Metformin is the pharmaceutical with the highest concentration in wastewater (64-98 μg/L) but it is removed with >98% in sewage treatment plants (STP). Guanylurea, a biodegradation product of metformin, was detected in STP effluents and surface waters at concentrations of 39-56 μg/L and 1.8-3.9 μg/L, respectively. The STP removal of the different pharmaceuticals varied strongly. For carbamazepine, hydrochlorothiazide and sotalol a significant better removal was found at higher temperatures and longer hydraulic retention times while for metoprolol significantly better removal was only observed at higher temperatures. Predicting environmental concentrations from regional consumption data might be an alternative to monitoring of pharmaceuticals in wastewater and surface waters. Crown Copyright © 2012. Published by Elsevier B.V. All rights reserved.

  3. Measuring real-time streamflow using emerging technologies: Radar, hydroacoustics, and the probability concept

    NASA Astrophysics Data System (ADS)

    Fulton, John; Ostrowski, Joseph

    2008-07-01

    SummaryForecasting streamflow during extreme hydrologic events such as floods can be problematic. This is particularly true when flow is unsteady, and river forecasts rely on models that require uniform-flow rating curves to route water from one forecast point to another. As a result, alternative methods for measuring streamflow are needed to properly route flood waves and account for inertial and pressure forces in natural channels dominated by nonuniform-flow conditions such as mild water surface slopes, backwater, tributary inflows, and reservoir operations. The objective of the demonstration was to use emerging technologies to measure instantaneous streamflow in open channels at two existing US Geological Survey streamflow-gaging stations in Pennsylvania. Surface-water and instream-point velocities were measured using hand-held radar and hydroacoustics. Streamflow was computed using the probability concept, which requires velocity data from a single vertical containing the maximum instream velocity. The percent difference in streamflow at the Susquehanna River at Bloomsburg, PA ranged from 0% to 8% with an average difference of 4% and standard deviation of 8.81 m 3/s. The percent difference in streamflow at Chartiers Creek at Carnegie, PA ranged from 0% to 11% with an average difference of 5% and standard deviation of 0.28 m 3/s. New generation equipment is being tested and developed to advance the use of radar-derived surface-water velocity and instantaneous streamflow to facilitate the collection and transmission of real-time streamflow that can be used to parameterize hydraulic routing models.

  4. Measuring real-time streamflow using emerging technologies: Radar, hydroacoustics, and the probability concept

    USGS Publications Warehouse

    Fulton, J.; Ostrowski, J.

    2008-01-01

    Forecasting streamflow during extreme hydrologic events such as floods can be problematic. This is particularly true when flow is unsteady, and river forecasts rely on models that require uniform-flow rating curves to route water from one forecast point to another. As a result, alternative methods for measuring streamflow are needed to properly route flood waves and account for inertial and pressure forces in natural channels dominated by nonuniform-flow conditions such as mild water surface slopes, backwater, tributary inflows, and reservoir operations. The objective of the demonstration was to use emerging technologies to measure instantaneous streamflow in open channels at two existing US Geological Survey streamflow-gaging stations in Pennsylvania. Surface-water and instream-point velocities were measured using hand-held radar and hydroacoustics. Streamflow was computed using the probability concept, which requires velocity data from a single vertical containing the maximum instream velocity. The percent difference in streamflow at the Susquehanna River at Bloomsburg, PA ranged from 0% to 8% with an average difference of 4% and standard deviation of 8.81 m3/s. The percent difference in streamflow at Chartiers Creek at Carnegie, PA ranged from 0% to 11% with an average difference of 5% and standard deviation of 0.28 m3/s. New generation equipment is being tested and developed to advance the use of radar-derived surface-water velocity and instantaneous streamflow to facilitate the collection and transmission of real-time streamflow that can be used to parameterize hydraulic routing models.

  5. A summary of measured hydraulic data for the series of steady and unsteady flow experiments over patterned roughness

    USGS Publications Warehouse

    Collins, Dannie L.; Flynn, Kathleen M.

    1979-01-01

    This report summarizes and makes available to other investigators the measured hydraulic data collected during a series of experiments designed to study the effect of patterned bed roughness on steady and unsteady open-channel flow. The patterned effect of the roughness was obtained by clear-cut mowing of designated areas of an otherwise fairly dense coverage of coastal Bermuda grass approximately 250 mm high. All experiments were conducted in the Flood Plain Simulation Facility during the period of October 7 through December 12, 1974. Data from 18 steady flow experiments and 10 unsteady flow experiments are summarized. Measured data included are ground-surface elevations, grass heights and densities, water-surface elevations and point velocities for all experiments. Additional tables of water-surface elevations and measured point velocities are included for the clear-cut areas for most experiments. One complete set of average water-surface elevations and one complete set of measured point velocities are tabulated for each steady flow experiment. Time series data, on a 2-minute time interval, are tabulated for both water-surface elevations and point velocities for each unsteady flow experiment. All data collected, including individual records of water-surface elevations for the steady flow experiments, have been stored on computer disk storage and can be retrieved using the computer programs listed in the attachment to this report. (Kosco-USGS)

  6. Intensity of Cold Water and its effects on marine culturing farms along the southeast coast of Korea

    NASA Astrophysics Data System (ADS)

    Lee, Yong-Hwa; Shim, JeongHee; Choi, Yang-Ho; Kim, Sang-Woo; Shim, Jeong-Min

    2017-04-01

    To understand the characteristics and strength of the cold water that has caused damage to marine-culturing farms around Guryongpo, in the southeast coast of Korea, surface and water column temperatures were collected from temperature loggers deployed at a sea squirt farm during August-November 2007 and from a Real-time Information System for aquaculture environments operated by NIFS during July-August 2015 and 2016. During the study period, surface temperature at Guryongpo decreased sharply when south/southwestern winds prevailed (the 18-26th of August and 20-22nd of September 2007 and the 13-15th of July 2015) as a result of upwelling. However, the deep-water (20-30m) temperature increased during periods of strong north/northeasterly winds (the 5-7th and 16-18th of September 2007) as a result of downwelling. Among the cold water events that occurred at Guryongpo, the mass death of cultured fish followed strong cold water events (surface temperatures below 10℃) that were caused by more than two days of successive south/southeastern winds with maximum speeds higher than 5 m/s. A Cold Water Index (CWI) was defined and calculated using maximum wind speed and direction as measured daily at Pohang Meteorological Observatory. When the average CWI over two days (CWI2d) was higher than 100, mass fish mortality occurred. The four-day average CWI (CWI4d) showed a high negative correlation with surface temperature from July-August in the Guryongpo area (R2 = 0.5), suggesting that CWI is a good index for predicting strong cold water events and massive mortality. In October 2007, the sea temperature at a depth of 30 m showed a high fluctuation that ranged from 7-23℃, with frequency and spectrum coinciding with tidal levels at Ulsan, affected by the North Korean Cold Current. If temperature variations at the depth of fish cages also regularly fluctuate within this range, damage may be caused to the fish industry along the southeast coast of Korea.

  7. Stream structure at low flow: biogeochemical patterns in intermittent streams over space and time

    NASA Astrophysics Data System (ADS)

    MacNeille, R. B.; Lohse, K. A.; Godsey, S.; McCorkle, E. P.; Parsons, S.; Baxter, C.

    2017-12-01

    Climate change in the western United States is projected to lead to earlier snowmelt, increasing fire risk and potentially transitioning perennial streams to intermittent ones. Differences between perennial and intermittent streams, especially the temporal and spatial patterns of carbon and nutrient dynamics during periods of drying, are understudied. We examined spatial and temporal patterns in surface water biogeochemistry during a dry (2016) and a wet (2017) water year in southwest Idaho. We hypothesized that as streams dry, carbon concentrations would increase due to evapoconcentration and/or increased in-stream production, and that the heterogeneity of constituents within each stream would increase. We expected these patterns to differ in a high water year compared to a low water year due to algae scour. Finally, we expected that the spatial heterogeneity of biogeochemistry would decrease with time following fire. To test these hypotheses, in 2016 we collected surface water samples at 50 meter intervals from two intermittent headwater streams over 2,500 meter reaches in April, May, and June. One stream is burned and one remains unburned. In 2017, we collected surface water at the 50, 25 and 10 meter intervals from each stream once during low flow. 2016 results showed average concentrations of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC) increased 3-fold from April to June in the burned site compared to the unburned site. Interestingly, average concentrations of total nitrogen (TN) dropped substantially for the burned site over these three months, but only decreased slightly for the unburned site over the same time period. Between wet and dry water years, we observed a decrease in the spatial heterogeneity as measured by the standard deviation (SD) in conductivity at 50 meter intervals; the burned stream had a SD of 23.08 in 2016 and 11.40 in 2017 whereas the unburned stream had similar SDs. We conclude that the burned stream experienced more inter and intra-annual surface water change in chemistry patterns than did the unburned stream.

  8. Creating a monthly time series of the potentiometric surface in the Upper Floridan aquifer, Northern Tampa Bay area, Florida, January 2000-December 2009

    USGS Publications Warehouse

    Lee, Terrie M.; Fouad, Geoffrey G.

    2014-01-01

    In Florida’s karst terrain, where groundwater and surface waters interact, a mapping time series of the potentiometric surface in the Upper Floridan aquifer offers a versatile metric for assessing the hydrologic condition of both the aquifer and overlying streams and wetlands. Long-term groundwater monitoring data were used to generate a monthly time series of potentiometric surfaces in the Upper Floridan aquifer over a 573-square-mile area of west-central Florida between January 2000 and December 2009. Recorded groundwater elevations were collated for 260 groundwater monitoring wells in the Northern Tampa Bay area, and a continuous time series of daily observations was created for 197 of the wells by estimating missing daily values through regression relations with other monitoring wells. Kriging was used to interpolate the monthly average potentiometric-surface elevation in the Upper Floridan aquifer over a decade. The mapping time series gives spatial and temporal coherence to groundwater monitoring data collected continuously over the decade by three different organizations, but at various frequencies. Further, the mapping time series describes the potentiometric surface beneath parts of six regionally important stream watersheds and 11 municipal well fields that collectively withdraw about 90 million gallons per day from the Upper Floridan aquifer. Monthly semivariogram models were developed using monthly average groundwater levels at wells. Kriging was used to interpolate the monthly average potentiometric-surface elevations and to quantify the uncertainty in the interpolated elevations. Drawdown of the potentiometric surface within well fields was likely the cause of a characteristic decrease and then increase in the observed semivariance with increasing lag distance. This characteristic made use of the hole effect model appropriate for describing the monthly semivariograms and the interpolated surfaces. Spatial variance reflected in the monthly semivariograms decreased markedly between 2002 and 2003, timing that coincided with decreases in well-field pumping. Cross-validation results suggest that the kriging interpolation may smooth over the drawdown of the potentiometric surface near production wells. The groundwater monitoring network of 197 wells yielded an average kriging error in the potentiometric-surface elevations of 2 feet or less over approximately 70 percent of the map area. Additional data collection within the existing monitoring network of 260 wells and near selected well fields could reduce the error in individual months. Reducing the kriging error in other areas would require adding new monitoring wells. Potentiometric-surface elevations fluctuated by as much as 30 feet over the study period, and the spatially averaged elevation for the entire surface rose by about 2 feet over the decade. Monthly potentiometric-surface elevations describe the lateral groundwater flow patterns in the aquifer and are usable at a variety of spatial scales to describe vertical groundwater recharge and discharge conditions for overlying surface-water features.

  9. Sources of groundwater and characteristics of surface-water recharge at Bell, White, and Suwannee Springs, Florida, 2012–13

    USGS Publications Warehouse

    Stamm, John F.; McBride, W. Scott

    2016-12-21

    Discharge from springs in Florida is sourced from aquifers, such as the Upper Floridan aquifer, which is overlain by an upper confining unit that locally can have properties of an aquifer. Water levels in aquifers are affected by several factors, such as precipitation, recharge, and groundwater withdrawals, which in turn can affect discharge from springs. Therefore, identifying groundwater sources and recharge characteristics can be important in assessing how these factors might affect flows and water levels in springs and can be informative in broader applications such as groundwater modeling. Recharge characteristics include the residence time of water at the surface, apparent age of recharge, and recharge water temperature.The groundwater sources and recharge characteristics of three springs that discharge from the banks of the Suwannee River in northern Florida were assessed for this study: Bell Springs, White Springs, and Suwannee Springs. Sources of groundwater were also assessed for a 150-foot-deep well finished within the Upper Floridan aquifer, hereafter referred to as the UFA well. Water samples were collected for geochemical analyses in November 2012 and October 2013 from the three springs and the UFA well. Samples were analyzed for a suite of major ions, dissolved gases, and isotopes of sulfur, strontium, oxygen, and hydrogen. Daily means of water level and specific conductance at White Springs were continuously recorded from October 2012 through December 2013 by the Suwannee River Water Management District. Suwannee River stage at White Springs was computed on the basis of stage at a U.S. Geological Survey streamgage about 2.4 miles upstream. Water levels in two wells, located about 2.5 miles northwest and 13 miles southeast of White Springs, were also used in the analyses.Major ion concentrations were used to differentiate water from the springs and Upper Floridan aquifer into three groups: Bell Springs, UFA well, and White and Suwannee Springs. When considered together, evidence from water-level, specific conductance, major-ion concentration, and isotope data indicated that groundwater at Bell Springs and the UFA well was a mixture of surface water and groundwater from the upper confining unit, and that groundwater at White and Suwannee Springs was a mixture of surface water, groundwater from the upper confining unit, and groundwater from the Upper Floridan aquifer. Higher concentrations of magnesium in groundwater samples at the UFA well than in samples at Bell Springs might indicate less mixing with surface water at the UFA well than at Bell Springs. Characteristics of surface-water recharge, such as residence time at the surface, apparent age, and recharge water temperature, were estimated on the basis of isotopic ratios, and dissolved concentrations of gases such as argon, tritium, and sulfur hexafluoride. Oxygen and deuterium isotopic ratios were consistent with rapid recharge by rainwater for samples collected in 2012, and longer residence time at the surface (ponding) for samples collected in 2013. Apparent ages of groundwater samples, computed on the basis of tritium activity and sulfur hexafluoride concentration, indicated groundwater recharge occurred after the late 1980s; however, the estimated apparent ages likely represent the average of ages of multiple sources. Recharge since the 1980s is consistent with groundwater from shallow sources, such as the upper confining unit and Upper Floridan aquifer. Recharge water temperature computed for the three springs and UFA well averaged 20.1 degrees Celsius, which is similar to the mean annual air temperature of 20.6 degrees Celsius at a nearby weather station for 1960–2014.

  10. [Hydrochemistry and Dissolved Inorganic Carbon Stable Isotope of Shibing Dolomite Karst Area in Guizhou Province].

    PubMed

    Xiao, Shi-zhen; Lan, Jia-cheng; Yuan, Dao-xian; Wang, Yun; Yang, Long; Ao, Xiang-hong

    2015-06-01

    Totally 49 water samples were collected in Shibing Dolomite Karst World Natural Heritage Site in Guizhou Province to analyze the characteristics and controlling factors of both the surface and underground waters, as well as the features and their origins of the dissolved inorganic carbon isotope. It was found that the pH of the study area was neutral to alkaline with low concentrations of total dissolved solids. The cations were dominated by Ca2+, Mg2 and anions by HCO3-, featured by HCO3-Ca x Mg type water. The ratios of Cl-, NO3- and SO4(2-) in the allogenic water from the shale area in the northern catchment were higher than those in autogenic water from the dolomite karst area, so did the concentration of Si. The SIc and SId of the allogenic waters in the shale area were negative. After the waters entered into and flew by the dolomite karst area, both the SIc and SId increased to over 0. It could be told by the water chemistry that the hydrochemistry was little impacted by the rainfall and human activities. The Gibbs plot revealed that the chemical composition of the waters was mainly controlled by rock weathering. The δ(13)C(DIC) of the surface waters ranged from -8.27% to -11.55% per hundred, averaging -9.45% per hundredo, while that of the underground waters ranged from -10.57% per hundred to -15.59% per hundred, averaging -12.04% per hundred, which was lighter than that of surface water. For the distribution features, it was found the δ(13)C(DIC), of the upper reaches of branches of Shangmuhe River was lighter than that of the lower reach, while that of the main river Shangmuhe River was relatively complex. Based on the mass balance of stable isotopes and the δ(13)C(DIC), the ratio of the origin of DIC of the ground water was calculated. It was found that 51.2% was from soil CO2, and 48.8% was from the rock itself.

  11. Characterizing water-metal interfaces and machine learning potential energy surfaces

    NASA Astrophysics Data System (ADS)

    Ryczko, Kevin

    In this thesis, we first discuss the fundamentals of ab initio electronic structure theory and density functional theory (DFT). We also discuss statistics related to computing thermodynamic averages of molecular dynamics (MD). We then use this theory to analyze and compare the structural, dynamical, and electronic properties of liquid water next to prototypical metals including platinum, graphite, and graphene. Our results are built on Born-Oppenheimer molecular dynamics (BOMD) generated using density functional theory (DFT) which explicitly include van der Waals (vdW) interactions within a first principles approach. All calculations reported use large simulation cells, allowing for an accurate treatment of the water-electrode interfaces. We have included vdW interactions through the use of the optB86b-vdW exchange correlation functional. Comparisons with the Perdew-Burke-Ernzerhof (PBE) exchange correlation functional are also shown. We find an initial peak, due to chemisorption, in the density profile of the liquid water-Pt interface not seen in the liquid water-graphite interface, liquid watergraphene interface, nor interfaces studied previously. To further investigate this chemisorption peak, we also report differences in the electronic structure of single water molecules on both Pt and graphite surfaces. We find that a covalent bond forms between the single water molecule and the platinum surface, but not between the single water molecule and the graphite surface. We also discuss the effects that defects and dopants in the graphite and graphene surfaces have on the structure and dynamics of liquid water. Lastly, we introduce artificial neural networks (ANNs), and demonstrate how they can be used to machine learn electronic structure calculations. As a proof of principle, we show the success of an ANN potential energy surfaces for a dimer molecule with a Lennard-Jones potential.

  12. WatER: The proposed Water Elevation Recovery satellite mission

    NASA Astrophysics Data System (ADS)

    Alsdorf, D.; Mognard, N.; Rodriguez, E.; Participants, W.

    2005-12-01

    Surface fresh water is essential for life, yet we have surprisingly poor knowledge of the spatial and temporal dynamics of surface water storage and discharge globally. The core mission objective is to describe and understand the continental water cycle and the hydrological processes (e.g., floodplain hydraulics) at work in a river basin. The key question that will be answered by WatER is: "Where is water stored on Earth's land surfaces, and how does this storage vary in space and time?" WatER will facilitate societal needs by (1) improving our understanding of flood hazards; (2) freely providing water volume information to countries who critically rely on rivers that cross political borders; and (3) mapping the variations in water bodies that contribute to disease vectors (e.g., malaria). Conventional altimeter profiles are, without question, incapable of supplying the measurements needed to address scientific and societal questions. WatER will repeatedly measure the spatially distributed water surface elevations (h) of wetlands, rivers, lakes, reservoirs, etc. Successive h measurements yield dh/dt, (t is time), hence a volumetric change in water stored or lost. Individual images of h yield dh/dx (x is distance), hence surface water slope, which is necessary for estimating streamflow. WatER's main instrument is a Ka-band radar interferometer (KaRIN) which is the only technology capable of supplying the required imaging capability of h. KaRIN has a rich heritage based on (1) the many highly successful ocean observing radar altimeters, (2) the Shuttle Radar Topography Mission (SRTM), and (3) the development effort of the Wide Swath Ocean Altimeter (WSOA). The interferometric altimeter is a near-nadir viewing, 120 km wideswath based instrument that uses interferometric SAR processing of the returned pulses to yield single-look 5m azimuth and 10m to 70m range resolution, with an elevation accuracy of approximately 50 cm. Polynomial based averaging of heights along the water body increases the height accuracy to about 3 cm. The entire globe is covered twice every 16 days and orbit subcycles allow the average visit to be about half this time at low to mid-latitudes, and almost daily at high latitudes. The WatER mission is an international effort with a large, supporting scientific community. It is already proposed as an ESA Earth Explorer Core mission and will also be jointly submitted to NASA's Earth System Science Pathfinder program. WatER is designed to meet high priority targets for all nations and will provide essential data for the EU Water Framework Directive and the European Flood Alert System. WatER will meet the United Nations call for a "greater focus on water related issues", responds to the hydroclimatological needs of the International Working Group on Earth Observations, and answers the U.S. federal government call to focus on our "ability to measure, monitor, and forecast U.S. and global supplies of fresh water".

  13. Estimation of effective hydrologic properties of soils from observations of vegetation density. M.S. Thesis; [water balance of watersheds in Clinton, Maine and Santa Paula, California

    NASA Technical Reports Server (NTRS)

    Tellers, T. E.

    1980-01-01

    An existing one-dimensional model of the annual water balance is reviewed. Slight improvements are made in the method of calculating the bare soil component of evaporation, and in the way surface retention is handled. A natural selection hypothesis, which specifies the equilibrium vegetation density for a given, water limited, climate-soil system, is verified through comparisons with observed data and is employed in the annual water balance of watersheds in Clinton, Ma., and Santa Paula, Ca., to estimate effective areal average soil properties. Comparison of CDF's of annual basin yield derived using these soil properties with observed CDF's provides excellent verification of the soil-selection procedure. This method of parameterization of the land surface should be useful with present global circulation models, enabling them to account for both the non-linearity in the relationship between soil moisture flux and soil moisture concentration, and the variability of soil properties from place to place over the Earth's surface.

  14. Phlogopite Decomposition, Water, and Venus

    NASA Technical Reports Server (NTRS)

    Johnson, N. M.; Fegley, B., Jr.

    2005-01-01

    Venus is a hot and dry planet with a surface temperature of 660 to 740 K and 30 parts per million by volume (ppmv) water vapor in its lower atmosphere. In contrast Earth has an average surface temperature of 288 K and 1-4% water vapor in its troposphere. The hot and dry conditions on Venus led many to speculate that hydrous minerals on the surface of Venus would not be there today even though they might have formed in a potentially wetter past. Thermodynamic calculations predict that many hydrous minerals are unstable under current Venusian conditions. Thermodynamics predicts whether a particular mineral is stable or not, but we need experimental data on the decomposition rate of hydrous minerals to determine if they survive on Venus today. Previously, we determined the decomposition rate of the amphibole tremolite, and found that it could exist for billions of years at current surface conditions. Here, we present our initial results on the decomposition of phlogopite mica, another common hydrous mineral on Earth.

  15. Poly- and perfluoroalkylated substances (PFASs) in water, sediment and fish muscle tissue from Lake Tana, Ethiopia and implications for human exposure.

    PubMed

    Ahrens, Lutz; Gashaw, Habiba; Sjöholm, Margareta; Gebrehiwot, Solomon Gebreyohannis; Getahun, Abebe; Derbe, Ermias; Bishop, Kevin; Åkerblom, Staffan

    2016-12-01

    Lake Tana is Ethiopia's largest lake and there are plans to increase the harvest of fish from the lake. The objective of this study was to assess the levels of poly- and perfluoroalkyl substances (PFASs) in different compartments of the lake (water, sediment, and fish muscle tissue), and its implications for human exposure. The results showed higher PFAS concentrations in piscivorous fish species (Labeobarbus megastoma and Labeobarbus gorguari) than non-piscivorous species (Labeobarbus intermedius, Oreochromis niloticus and Clarias gariepinus) and also spatial distribution similarities. The ∑PFAS concentrations ranged from 0.073 to 5.6 ng L -1 (on average, 2.9 ng L -1 ) in surface water, 0.22-0.55 ng g -1 dry weight (dw) (on average, 0.30 ng g -1 dw) in surface sediment, and non-detected to 5.8 ng g -1 wet weight (ww) (on average, 1.2 ng g -1 ww) in all fish species. The relative risk (RR) indicates that the consumption of fish contaminated with perfluorooctane sulfonate (PFOS) will likely not cause any harmful effects for the Ethiopian fish eating population. However, mixture toxicity of the sum of PFASs, individual fish consumption patterns and increasing fish consumption are important factors to consider in future risk assessments. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. Automated fabrication of back surface field silicon solar cells with screen printed wraparound contacts

    NASA Technical Reports Server (NTRS)

    Thornhill, J. W.

    1977-01-01

    The development of a process for fabricating 2 x 4 cm back surface field silicon solar cells having screen printed wraparound contacts is described. This process was specifically designed to be amenable for incorporation into the automated nonvacuum production line. Techniques were developed to permit the use of screen printing for producing improved back surface field structures, wraparound dielectric layers, and wraparound contacts. The optimized process sequence was then used to produce 1852 finished cells. Tests indicated an average conversion efficiency of 11% at AMO and 28 C, with an average degradation of maximum power output of 1.5% after boiling water immersion or thermal shock cycling. Contact adherence was satisfactory after these tests, as well as long term storage at high temperature and high humidity.

  17. Effects of agricultural nutrient management on nitrogen fate and transport in Lancaster County, Pennsylvania

    USGS Publications Warehouse

    Hall, D.W.; Risser, D.W.

    1993-01-01

    Nitrogen inputs to, and outputs from, a 55-acre site in Lancaster County, Pennsylvania, were estimated to determine the pathways and relative magnitude of loads of nitrogen entering and leaving the site, and to compare the loads of nitrogen before and after the implementation of nutrient management. Inputs of nitrogen to the site were manure fertilizer, commercial fertilizer, nitrogen in precipitation, and nitrogen in ground-water inflow; and these sources averaged 93, 4, 2, and 1 percent of average annual nitrogen additions, respectively. Outputs of nitrogen from the site were nitrogen in harvested crops, loads of nitrogen in surface runoff, volatilization of nitrogen, and loads of nitrogen in ground-water discharge, which averaged 37, less than 1,25, and 38 percent of average annual nitrogen removals from the site, respectively. Virtually all of the nitrogen leaving the site that was not removed in harvested crops or by volatilization was discharged in the ground water. Applications of manure and fertilizer nitrogen to 47.5 acres of cropped fields decreased about 33 percent, from an average of 22,700 pounds per year (480 pounds per acre per year) before nutrient management to 15,175 pounds of nitrogen per year (320 pounds per acre per year) after the implementation of nutrient management practices. Nitrogen loads in ground-water discharged from the site decreased about 30 percent, from an average of 292 pounds of nitrogen per million gallons of ground water before nutrient management to an average of 203 pounds of nitrogen per million gallons as a result of the decreased manure and commercial fertilizer applications. Reductions in manure and commercial fertilizer applications caused a reduction of approximately 11,000 pounds (3,760 pounds per year, 70 pounds per acre per year) in the load of nitrogen discharged in ground water from the 55-acre site during the three-year period 1987-1990.

  18. Water resources of the Yadkin-Pee Dee River Basin, North Carolina

    USGS Publications Warehouse

    Fish, Robert Eugene; LeGrand, H.E.; Billingsley, G.A.

    1957-01-01

    Sufficient water is available in the basin of the Yadkin and Pee Dee Rivers to meet present requirements and those for many years to come if water use increases at about the present rate. Data presented in this report show that the average annual streamflow from approximately 82 percent of the basin area during the 25-year period, 1929-53, was about 6,200 mgd, representing essentially the total available water supply. Comparison of the available water supply to the estimated withdrawal use (excluding water power) of both surface and ground water of 600 mgd indicates the relative utilization of the water resources of the basin at present. If proper pollution controls are observed and practiced so that water in the various streams may be reused several times, the potential water available is even greater than indicated by the above comparison. Preliminary studies indicate that the quantity of water now being withdrawn from ground-water reservoirs in the basin is only a fraction of the total that may be obtained from this source. Twenty-eight of the 64 municipalities having public water-supply systems use surface water; however, as the largest cities in the area use surface supplies, about 85 percent of the water used for public supplies is from surface sources. Of the 20 complete-record stream-gaging stations now in operation in this area 7 have been in operation for 24 years or longer. Periodic measurements of the rate of flow have been made at 31 additional sites on streams scattered widely over the basin. All available streamflow data including those for 1953 are summarized in either graphic or tabular form, or both. Because of the critically low flows occurring during the drought of 1954, several illustrations include data for 1954 and the early months of 1955 for comparison with the minima of previous years. Adequate water for domestic use is available from wells throughout the basin. The consolidated rocks of the Piedmont furnish water for small industries and for municipalities whose population is less than about 1,500. The yields of wells in rock range from less than 1 gpm to as much as 200 gpm with local, rather than regional, geologic factors controlling the yield. The average municipal well in consolidated rocks yields about 30 gpm. In contrast, the sands of the Coastal Plain, in the eastern part of the basin, furnish as much as 500 gpm to individual wells, and ground-water conditions are generally similar throughout that region. A cumulative deficiency in rainfall from 1953 to 1955, has caused ground-water levels to fall below the seasonal averages, but the decline is thought not to indicate a long-term trend. The most serious problem involving future use of ground water is the lack of knowledge of the characteristics of the ground-water provinces in the basin. Generally the chemical quality of the surface waters in the Yadkin-Pee Dee River basin is good. They are low in mineral matter and soft, although some of the surface water contains excessive quantities of iron. In some local areas the streams have been polluted by municipal and industrial wastes. During periods of high runoff many of the streams transport large quantities of suspended sediment. Tributary streams in the lower eastern part of the basin are highly colored because of drainage from swampy areas. Ground water from the consolidated rocks in the Piedmont region is more variable in quality than water from other areas in the basin. The dissolved solids in water from the consolidated rocks ranged from 26 to 1,480 ppm with a median of 109 ppm. Wells in the Cretaceous clay province normally yield slightly acid waters. The pH ranges from 4.7 to 7.7 with a median of 5.3. Generally ground water in this province is extremely soft and low in dissolved solids. Wells in the Cretaceous sand province yield a sodium bicarbonate type of water ranging in hardness from 2 to 130 ppm.

  19. Assessment of the water and energy budget simulation of three land surface models: CLM4.5, CoLM2014, and CoLM2005

    NASA Astrophysics Data System (ADS)

    Li, C.; Lu, H.; Wen, X.

    2015-12-01

    Land surface model (LSM), which simulates energy, water and momentum exchanges between land and atmosphere, is an important component of Earth System Models (ESM). As shown in CMIP5, different ESMs usually use different LSMs and represent various land surface status. In order to select a land surface model which could be embedded into the ESM developed in Tsinghua University, we firstly evaluate the performance of three LSMs: Community Land Model (CLM4.5) and two different versions of Common Land Model (CoLM2005 and CoLM2014). All of three models were driven by CRUNCEP data and simulation results from 1980 to 2010 were used in this study. Diagnostic data provided by NCAR, global latent and sensible heat flux map estimated by Jung, net radiation from SRB, and in situ observation collected from FluxNet were used as reference data. Two variables, surface runoff and snow depth, were used for evaluating the model performance in water budget simulation, while three variables including net radiation, sensible heat, and latent heat were used for assessing energy budget simulation. For 30 years averaged runoff, global average value of Colm2014 is 0.44mm/day and close to the diagnostic value of 0.75 mm/day, while that of Colm2005 is 0.44mm/day and that of CLM is 0.20mm/day. For snow depth simulation, three models all have overestimation in the Northern Hemisphere and underestimation in the Southern Hemisphere compare to diagnostic data. For 30 years energy budget simulation, at global scale, CoLM2005 performs best in latent heat estimation, CoLM2014 performs best in sensible heat simulation, and CoLM2005 and CoLM2014 make similar performance in net radiation estimation but is still better than CLM. At regional and local scale, comparing to the four years average of flux tower observation, RMSE of CoLM2005 is the smallest for latent heat (9.717 W/m2) , and for sensible heat simulation, RMSE of CoLM2005 (13.048 W/m2) is slightly greater than CLM(10.767 W/m2) but still better than CoLM2014(30.085 W/m2). Our analysis shows that both CoLM 2005 and CoLM 2014 are able to reproduce comparable land surface water and energy fluxes. It implies that the ESM developed in Tsinghua University may use CoLM, a LSM developed and maintained in China, as the land surface component. .

  20. Potentiometric surface of the Floridan Aquifer and its use in management of water resources, St. Johns River Water Management District, Florida

    USGS Publications Warehouse

    Rodis, Harry George; Munch, D.A.

    1983-01-01

    The Floridan aquifer supplies most of the fresh groundwater for municipal, industrial, and agricultural uses within the 12,400 sq mi St. Johns River Water Management District. Because of the growing demand for water and the variation in rainfall, resource managers need timely information on short-term and long-term changes in the availability of fresh water. The purpose of this report is to explain potentiometric surface maps and their value in assessing the resource, particularly during drought conditions. The Floridan aquifer is recharged by rainfall falling directly on the outcrop of the aquifer, and, where the aquifer is overlain by the surficial aquifer with the water table above the potentiometric surface of the Floridan, by water infiltrating downward from the overlying surficial aquifer. Water is discharged by pumping and free-flowing wells, springflow, and upward leakage into overlying formations, streams, and lakes or into the ocean. Fluctuations in the potentiometric surface reflect net gains (recharge) or losses (discharge) of water stored in the aquifer. Net gains occur during the wet season (June through September) when recharge exceeds discharge and causes the potentiometric surface to rise in most places. Net losses in storage, and declines in the potentiometric surface, follow during the dry season (October through May) when discharge exceeds recharge. Seasonal changes in the potentiometric surface, based on a 2-yr average of water level measurements during May and September 1977, and May and September 1978, are illustrated. Two of the greater long-term declines in the potentiometric surface have occurred in the growing metropolitan areas of Jacksonville and Orlando-Winter Park, the two largest public suppliers of water in the Water Management District. Municipal pumpage increased in Jacksonville from 37 million gallons per day (mgd) in 1961 to 56 mgd in 1980. The increased pumpage and a deficiency in rainfall of 15.8 inches contributed to a decline in the potentiometric surface of as much as 15 ft. Orlando-Winter Park municipal pumpage increasing from 27 mgd in 1961 to 62 mgd in 1980. The periodic preparation of maps showing changes in the potentiometric surface of the aquifer provide the best base information for both short-term and long-term management of the water resources in the St. Johns River Water Management District. (Lantz-PTT)

  1. Hydrologic reconnaissance of the Wah Wah Valley drainage basin, Millard and Beaver Counties, Utah

    USGS Publications Warehouse

    Stephens, Jerry C.

    1974-01-01

    The Wah Wah Valley drainage basin is an area of about 600 square miles (1,550 km2) in Millard and Beaver Counties in southwestern Utah. Surface-water supplies of the area are negligible--total runoff averages about 7,800 acre-feet (9.62 hm3) annually, all streams are ephemeral or intermittent, and surface storage is negligible. Evaporation and transpiration within the basin consume more than 97 percent of total annual precipitation. There is no surface outflow.

  2. Potentiometric map of the Gordo Aquifer in northeastern Mississippi, September, October, and November 1978

    USGS Publications Warehouse

    Wasson, B.E.

    1979-01-01

    This potentiometric map of the Gordo aquifer in northeastern Mississippi is the second in a series of maps, prepared by the U.S. Geological Survey in cooperation with the Mississippi Department of Natural Resources, Bureau of Land and Water Resources, delineating the potentiometric surfaces of the major aquifers in Mississippi. The potentiometric surface of the Gordo aquifer slopes generally to the west away from the outcrop area and it is depressed generally by large ground-water withdrawals in the Tupelo and Columbus areas. Historically, water levels in or near the outcrop of the Gordo aquifer have shown little or no long-term changes. Heavy withdrawals from the downdip area have caused long-term water-level declines of 1 to 2 feet per year in much of the confined part of the aquifer. Water-level decline in one observation well in Tupelo has averaged about 5 feet per year since 1966. (USGS)

  3. Do initial conditions matter? A comparison of model climatologies generated from different initial states

    NASA Technical Reports Server (NTRS)

    Spar, J.; Cohen, C.; Wu, P.

    1981-01-01

    A coarse mesh (8 by 10) 7 layer global climate model was used to compute 15 months of meteorological history in two perpetual January experiments on a water planet (without continents) with a zonally symmetric climatological January sea surface temperature field. In the first of the two water planet experiments the initial atmospheric state was a set of zonal mean values of specific humidity, temperature, and wind at each latitude. In the second experiment the model was initialized with globally uniform mean values of specific humidity and temperature on each sigma level surface, constant surface pressure (1010 mb), and zero wind everywhere. A comparison was made of the mean January climatic states generated by the two water planet experiments. The first two months of each 15 January run were discarded, and 13 month averages were computed from months 3 through 15.

  4. Diel Surface Temperature Range Scales with Lake Size

    PubMed Central

    Woolway, R. Iestyn; Jones, Ian D.; Maberly, Stephen C.; French, Jon R.; Livingstone, David M.; Monteith, Donald T.; Simpson, Gavin L.; Thackeray, Stephen J.; Andersen, Mikkel R.; Battarbee, Richard W.; DeGasperi, Curtis L.; Evans, Christopher D.; de Eyto, Elvira; Feuchtmayr, Heidrun; Hamilton, David P.; Kernan, Martin; Krokowski, Jan; Rimmer, Alon; Rose, Kevin C.; Rusak, James A.; Ryves, David B.; Scott, Daniel R.; Shilland, Ewan M.; Smyth, Robyn L.; Staehr, Peter A.; Thomas, Rhian; Waldron, Susan; Weyhenmeyer, Gesa A.

    2016-01-01

    Ecological and biogeochemical processes in lakes are strongly dependent upon water temperature. Long-term surface warming of many lakes is unequivocal, but little is known about the comparative magnitude of temperature variation at diel timescales, due to a lack of appropriately resolved data. Here we quantify the pattern and magnitude of diel temperature variability of surface waters using high-frequency data from 100 lakes. We show that the near-surface diel temperature range can be substantial in summer relative to long-term change and, for lakes smaller than 3 km2, increases sharply and predictably with decreasing lake area. Most small lakes included in this study experience average summer diel ranges in their near-surface temperatures of between 4 and 7°C. Large diel temperature fluctuations in the majority of lakes undoubtedly influence their structure, function and role in biogeochemical cycles, but the full implications remain largely unexplored. PMID:27023200

  5. Environmental Setting and Effects on Water Quality in the Great and Little Miami River Basins, Ohio and Indiana

    USGS Publications Warehouse

    Debrewer, Linda M.; Rowe, Gary L.; Reutter, David C.; Moore, Rhett C.; Hambrook, Julie A.; Baker, Nancy T.

    2000-01-01

    The Great and Little Miami River Basins drain approximately 7,354 square miles in southwestern Ohio and southeastern Indiana and are included in the more than 50 major river basins and aquifer systems selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Principal streams include the Great and Little Miami Rivers in Ohio and the Whitewater River in Indiana. The Great and Little Miami River Basins are almost entirely within the Till Plains section of the Central Lowland physiographic province and have a humid continental climate, characterized by well-defined summer and winter seasons. With the exception of a few areas near the Ohio River, Pleistocene glacial deposits, which are predominantly till, overlie lower Paleozoic limestone, dolomite, and shale bedrock. The principal aquifer is a complex buried-valley system of sand and gravel aquifers capable of supporting sustained well yields exceeding 1,000 gallons per min-ute. Designated by the U.S. Environmental Protection Agency as a sole-source aquifer, the Buried-Valley Aquifer System is the principal source of drinking water for 1.6 million people in the basins and is the dominant source of water for southwestern Ohio. Water use in the Great and Little Miami River Basins averaged 745 million gallons per day in 1995. Of this amount, 48 percent was supplied by surface water (including the Ohio River) and 52 percent was supplied by ground water. Land-use and waste-management practices influence the quality of water found in streams and aquifers in the Great and Little Miami River Basins. Land use is approximately 79 percent agriculture, 13 percent urban (residential, industrial, and commercial), and 7 percent forest. An estimated 2.8 million people live in the Great and Little Miami River Basins; major urban areas include Cincinnati and Dayton, Ohio. Fertilizers and pesticides associated with agricultural activity, discharges from municipal and industrial wastewater- treatment and thermoelectric plants, urban runoff, and disposal of solid and hazardous wastes contribute contaminants to surface water and ground water throughout the study area. Surface water and ground water in the Great and Little Miami River Basins are classified as very hard, calcium-magnesium- bicarbonate waters. The major-ion composition and hardness of surface water and ground water reflect extensive contact with the carbonate-rich soils, glacial sediments, and limestone or dolomite bedrock. Dieldrin, endrin, endosulfan II, and lindane are the most commonly reported organochlorine pesticides in streams draining the Great and Little Miami River Basins. Peak concentrations of the her-bicides atrazine and metolachlor in streams commonly are associated with post-application runoff events. Nitrate concentrations in surface water average 3 to 4 mg/L (milligrams per liter) in the larger streams and also show strong seasonal variations related to application periods and runoff events. Ambient iron concentrations in ground water pumped from aquifers in the Great and Little Miami River Basins often exceed the U.S. Environmental Protection Agency Secondary Maximum Contaminant Level (300 micrograms per liter). Chloride concentrations are below aesthetic drinking-water guidelines (250 mg/L), except in ground water pumped from low-yielding Ordovician shale; chloride concentrations in sodium-chloride- rich ground water pumped from the shale bedrock can exceed 1,000 mg/L. Some of the highest average nitrate concentrations in ground water in Ohio and Indiana are found in wells completed in the buried-valley aquifer; these concentrations typically are found in those parts of the sand and gravel aquifer that are not overlain by clay-rich till. Atrazine was the most commonly detected herbicide in private wells. Concentrations of volatile organic compounds in ground water generally were below Federal drinking-water standards, except near areas of known or

  6. Mathematical modelling of surface water-groundwater flow and salinity interactions in the coastal zone

    NASA Astrophysics Data System (ADS)

    Spanoudaki, Katerina; Kampanis, Nikolaos A.

    2014-05-01

    Coastal areas are the most densely-populated areas in the world. Consequently water demand is high, posing great pressure on fresh water resources. Climatic change and its direct impacts on meteorological variables (e.g. precipitation) and indirect impact on sea level rise, as well as anthropogenic pressures (e.g. groundwater abstraction), are strong drivers causing groundwater salinisation and subsequently affecting coastal wetlands salinity with adverse effects on the corresponding ecosystems. Coastal zones are a difficult hydrologic environment to represent with a mathematical model due to the large number of contributing hydrologic processes and variable-density flow conditions. Simulation of sea level rise and tidal effects on aquifer salinisation and accurate prediction of interactions between coastal waters, groundwater and neighbouring wetlands requires the use of integrated surface water-groundwater models. In the past few decades several computer codes have been developed to simulate coupled surface and groundwater flow. In these numerical models surface water flow is usually described by the 1-D Saint Venant equations (e.g. Swain and Wexler, 1996) or the 2D shallow water equations (e.g. Liang et al., 2007). Further simplified equations, such as the diffusion and kinematic wave approximations to the Saint Venant equations, are also employed for the description of 2D overland flow and 1D stream flow (e.g. Gunduz and Aral, 2005). However, for coastal bays, estuaries and wetlands it is often desirable to solve the 3D shallow water equations to simulate surface water flow. This is the case e.g. for wind-driven flows or density-stratified flows. Furthermore, most integrated models are based on the assumption of constant fluid density and therefore their applicability to coastal regions is questionable. Thus, most of the existing codes are not well-suited to represent surface water-groundwater interactions in coastal areas. To this end, the 3D integrated surface water-groundwater model IRENE (Spanoudaki et al., 2009; Spanoudaki, 2010) has been modified in order to simulate surface water-groundwater flow and salinity interactions in the coastal zone. IRENE, in its original form, couples the 3D, non-steady state Navier-Stokes equations, after Reynolds averaging and with the assumption of hydrostatic pressure distribution, to the equations describing 3D saturated groundwater flow of constant density. A semi-implicit finite difference scheme is used to solve the surface water flow equations, while a fully implicit finite difference scheme is used for the groundwater equations. Pollution interactions are simulated by coupling the advection-diffusion equation describing the fate and transport of contaminants introduced in a 3D turbulent flow field to the partial differential equation describing the fate and transport of contaminants in 3D transient groundwater flow systems. The model has been further developed to include the effects of density variations on surface water and groundwater flow, while the already built-in solute transport capabilities are used to simulate salinity interactions. Initial results show that IRENE can accurately predict surface water-groundwater flow and salinity interactions in coastal areas. Important research issues that can be investigated using IRENE include: (a) sea level rise and tidal effects on aquifer salinisation and the configuration of the saltwater wedge, (b) the effects of surface water-groundwater interaction on salinity increase of coastal wetlands and (c) the estimation of the location and magnitude of groundwater discharge to coasts. Acknowledgement The work presented in this paper has been funded by the Greek State Scholarships Foundation (IKY), Fellowships of Excellence for Postdoctoral Studies (Siemens Program), 'A simulation-optimization model for assessing the best practices for the protection of surface water and groundwater in the coastal zone', (2013 - 2015). References Gunduz, O. and Aral, M.M. (2005). River networks and groundwater flow: a simultaneous solution of a coupled system. Journal of Hydrology 301 (1-4), 216-234. Liang, D., Falconer, R.A. and Lin, B. (2007). Coupling surface and subsurface flows in a depth-averaged flood wave model. Journal of Hydrology 337, 147-158. Spanoudaki, K., Stamou, A.I. and Nanou-Giannarou, A. (2009). Development and verification of a 3-D integrated surface water-groundwater model. Journal of Hydrology, 375 (3-4), 410-427. Spanoudaki, K. (2010). Integrated numerical modelling of surface water groundwater systems (in Greek). Ph.D. Thesis, National Technical University of Athens, Greece. Swain, E.D. and Wexler, E.J. (1996). A coupled surface water and groundwater flow model (Modbranch) for simulation of stream-aquifer interaction. United States Geological Survey, Techniques of Water Resources Investigations (Book 6, Chapter A6).

  7. Application of bimodal distribution to the detection of changes in uranium concentration in drinking water collected by random daytime sampling method from a large water supply zone.

    PubMed

    Garboś, Sławomir; Święcicka, Dorota

    2015-11-01

    The random daytime (RDT) sampling method was used for the first time in the assessment of average weekly exposure to uranium through drinking water in a large water supply zone. Data set of uranium concentrations determined in 106 RDT samples collected in three runs from the water supply zone in Wroclaw (Poland), cannot be simply described by normal or log-normal distributions. Therefore, a numerical method designed for the detection and calculation of bimodal distribution was applied. The extracted two distributions containing data from the summer season of 2011 and the winter season of 2012 (nI=72) and from the summer season of 2013 (nII=34) allowed to estimate means of U concentrations in drinking water: 0.947 μg/L and 1.23 μg/L, respectively. As the removal efficiency of uranium during applied treatment process is negligible, the effect of increase in uranium concentration can be explained by higher U concentration in the surface-infiltration water used for the production of drinking water. During the summer season of 2013, heavy rains were observed in Lower Silesia region, causing floods over the territory of the entire region. Fluctuations in uranium concentrations in surface-infiltration water can be attributed to releases of uranium from specific sources - migration from phosphate fertilizers and leaching from mineral deposits. Thus, exposure to uranium through drinking water may increase during extreme rainfall events. The average chronic weekly intakes of uranium through drinking water, estimated on the basis of central values of the extracted normal distributions, accounted for 3.2% and 4.1% of tolerable weekly intake. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Relationship between Secchi disc readings and light penetration in Lake Huron

    USGS Publications Warehouse

    Beeton, Alfred M.

    1958-01-01

    Fifty-seven paired photometer and Secchi disc measurements made at 18 stations in Saginaw Bay and Lake Huron support the view that a counter-clockwise current usually occurs in the Bay with more transparent Lake Huron water flowing in along the northwest shore and less transparent Bay water flowing out along the southeast shore. The average percentage transmission of surface light intensity, at the Secchi disc depth, was 14.7 percent. Discrepancies in the relationship of disc readings to percentage transmission of surface light are related to the condition of the sky and sea. It is suggested that these discrepancies can best be explained on the basis of the spectral sensitivity of the human eye and its response to surface glare.

  9. Revisiting a Hydrological Analysis Framework with International Satellite Land Surface Climatology Project Initiative 2 Rainfall, Net Radiation, and Runoff Fields

    NASA Technical Reports Server (NTRS)

    Koster, Randal D.; Fekete, Balazs M.; Huffman, George J.; Stackhouse, Paul W.

    2006-01-01

    The International Satellite Land Surface Climatology Project Initiative 2 (ISLSCP-2) data set provides the data needed to characterize the surface water budget across much of the globe in terms of energy availability (net radiation) and water availability (precipitation) controls. The data, on average, are shown to be consistent with Budyko s decades-old framework, thereby demonstrating the continuing relevance of Budyko s semiempirical relationships. This consistency, however, appears only when a small subset of the data with hydrologically suspicious behavior is removed from the analysis. In general, the precipitation, net radiation, and runoff data also appear consistent in their interannual variability and in the phasing of their seasonal cycles.

  10. Availability of water in Kalamazoo County, southwestern Michigan

    USGS Publications Warehouse

    Allen, William Burrows; Miller, John B.; Wood, Warren W.

    1972-01-01

    Kalamazoo County comprises an area of 572 square miles in the southwestern part of Michigan. It includes parts of the Kalamazoo, St. Joseph, and Paw Paw River basins, which drain into Lake Michigan. The northern two-thirds of the county is drained by the Kalamazoo River and its tributaries. A small area in the western piart of the county is drained by the Paw Paw River, and the rest, by tributaries of the St. Joseph River. Glacial deposits, containing sand and gravel, form an upper aquifer and a lower aquifer underlying large parts of the county. Areas of high transmissibility and thick saturated deposits are sufficiently localized to be considered as separate ground-water reservoirs having limited areal extent and definite hydrologic boundaries. Ground-water runoff from the basins constitutes a large part of the streamflow. Hydrograph separation shows that ground-water runoff composed 65 and 73 percent of the discharge of Kalamazoo River at Comstock and 75 and 79 percent of the discharge of Portage River near Vicksburg in 1965 and 1966, respectively. Based on the hydrologic budgets for the same years, ground-water recharge was 9.1 and 9.0 inches in the Kalamazoo River basin and 12.2 and 11.6 inches in the St. Joseph River basin. Ground-water recharge in the Kalamazoo River basin extrapolated for the 34-year period 1933-66 ranged from 4 to 13 inches and averaged 9 inches. In the St. Joseph River basin average recharge was about 9 inches for the same period. There is a wide range in runoff in the county. Augusta Creek, Portage Creek near Kalamazoo, and Gourdneck Creek have the highest annual runoff and maintain high yields even during periods of deficient precipitation. Spring Brook also reflects large ground-water contributions to streamflow. Storage in these basins could provide additional water during low flows for municipal and industrial needs. The primary use of lakes in the county is for recreational and esthetic purposes. Maintaining lake levels is therefore of the utmost importance. Levels at Crooked and Eagle Lakes have been maintained by pumping from lower aquifers. Diversion of water from Gourdneck Creek to West and Austin Lakes has helped in maintaining levels. Several relatively undeveloped lakes could be utilized as reservoirs whose storage could be used to augment streamflow or for water supply.Water in streams is generally of good chemical quality; however, several streams, including the Kalamazoo River downstream from Kalamazoo, have been degraded by municipal and industrial waste disposal. Water in the lakes is generally of good chemical quality with the exception of Barton Lake, which has been degraded by waste disposal. There is sufficient surface water available in Kalamazoo County to meet requirements for development of large quantities of water. The total available supply (average discharge of a stream) is about 680 mgd (million gallons per day). The dependable supply (7-day Q2, or average 7-day low flow having a recurrence interval of 2 years) is about 303 mgd. By developing artificial recharge facilities, surface runoff during winter and spring could be utilized to recharge ground-water reservoirs. Surface-water withdrawal in 1966 was about 58 mgd, of which 33 mgd was withdrawn from the Kalamazoo River. The quantity of water now being withdrawn from the ground and surface sources is small compared to the total that may be obtained in the area through full utilization of these resources. Mathematical models were used to simulate hydrologic conditions in the ground-water reservoirs and to evaluate maximum drawdowns for periods of little or no recharge. The practical limits of development as determined for the ground-water reservoirs are estimated to be at the following average withdrawal rates: Kalamazoo, 39 .mgd; Schoolcraft, 17 mgd; Kalamazoo-Portage, 24 mgd; and several small reservoirs, 67 mgd. These total 147 mgd. Further development would require additional artificial recharge facilities. Average ground-water withdrawal in 1966 was about 54 mgd. The Kalamazoo River ground-water reservoir furnished about 28 mgd, the Kalamazoo-Portage ground-water reservoir, about 21 mgd, and the other reservoirs, about 5 mgd. Thus, further development without artificial recharge is estimated to be about 11 mgd in the Kalamazoo River reservoir, 17 mgd in the Schoolcraft reservoir, 62 mgd in the several small reservoirs, and only 3 mgd in the Kalamazoo-Portage reservoir.The ground water is generally of good chemical quality and is suitable for most uses; however, it is Usually very hard and may contain objectionable amounts of iron. Some deterioration of water quality- has .been observed in several areas because of seepage from stockpiles of industrial minerals. The presence of many inland lakes, streams having high ground-water runoff, and, in places, relatively undeveloped ground-water reservoirs provides -flexibility in water management.

  11. Evaporation from Lake Michie, North Carolina 1961-71

    USGS Publications Warehouse

    Yonts, W.L.; Giese, G.L.; Hubbard, E.F.

    1973-01-01

    The Geological Survey, in cooperation with the city of Durham, N. C., collected evaporation data at Lake Michie, Durham's 480-acre water-supply reservoir, for 10 consecutive years from September 1961 to September 1971. Wind speed, air temperature, and water temperature-collected continuously-were used in conjunction with water-budget data to calibrate the semi-empirical mass-transfer equation, E Nu(eo - ea), where E is evaporation; N is the mass-transfer coefficient, which is a constant for a given lake; u is wind speed; eo is the vapor pressure of the saturated air at the water surface; and ea is the vapor pressure of the surrounding air. For evaporation expressed in inches, the mass-transfer coefficient for Lake Michie is 0.0036.During the study period the average annual evaporation from Lake Michie was 37.9 inches. Within-year variation of evaporation from the lake is sinusoidal, with a high during July averaging 4.71 inches and a low during January averaging 1.45 inches.Evaporation from Lake Michie was 0.72 (or about three-quarters) of the evaporation from the National Weather Service evaporation pan at Chapel Hill. This ratio, called a pan coefficient, was not constant throughout the year, ranging from an average of 0.57 for April to 1.09 for December.

  12. Public water supplies of North Carolina : a summary of water sources, use, treatment, and capacity of water-supply systems

    USGS Publications Warehouse

    Mann, L.T.

    1978-01-01

    Data were collected during 1970-76 on 224 public water supply systems in North Carolina with 500 or more customers. This report summarizes these data that were previously published in five separate regional reports. The data are presented in order to Council of Government region, county, and water system name and include population served, average and maximum daily use, industrial use, water source, allowable draft of surface-water supplies, raw water pumping capacity, raw and finished water storage, type of water treatment, treatment plant capacity, and a summary of the chemical quality of finished water. Tables and maps provide cross references for system names, counties, Council of Government regions and water source.

  13. Transport of lincomycin to surface and ground water from manure-amended cropland.

    PubMed

    Kuchta, Sandra L; Cessna, Allan J; Elliott, Jane A; Peru, Kerry M; Headley, John V

    2009-01-01

    Livestock manure containing antimicrobials becomes a possible source of these compounds to surface and ground waters when applied to cropland as a nutrient source. The potential for transport of the veterinary antimicrobial lincomycin to surface waters via surface runoff and to leach to ground water was assessed by monitoring manure-amended soil, simulated rainfall runoff, snowmelt runoff, and ground water over a 2-yr period in Saskatchewan, Canada, after fall application of liquid swine manure to cropland. Liquid chromatography tandem mass spectrometry was used to quantify lincomycin in all matrix extracts. Initial concentrations in soil (46.3-117 mug kg(-1)) were not significantly different (p > 0.05) for manure application rates ranging from 60,000 to 95,000 L ha(-1) and had decreased to nondetectable levels by mid-summer the following year. After fall manure application, lincomycin was present in all simulated rainfall runoff (0.07-2.7 mug L(-1)) and all snowmelt runoff (0.038-3.2 mug L(-1)) samples. Concentrations in snowmelt runoff were not significantly different from those in simulated rainfall runoff the previous fall. On average, lincomycin concentrations in ephemeral wetlands dissipated by 50% after 31 d. Concentrations of lincomycin in ground water were generally <0.005 mug L(-1). This study demonstrates that the management practice of using livestock manure from confined animal feeding operations as a plant nutrient source on cropland may result in antimicrobial transport to surface and ground waters.

  14. Tribological properties of glass fiber filled polytetrafluoroethylene sliding against stainless steel under dry and aqueous environments: enhanced tribological performance in sea water

    NASA Astrophysics Data System (ADS)

    Jebran Khan, Mohammad; Wani, M. F.; Gupta, Rajat

    2018-05-01

    The present study aims at investigating the tribological behavior of glass fiber filled PTFE on sliding against AISI 420 stainless steel in ambient air, distilled water and natural sea water. The friction and wear tests were carried out using a pin-on-disc configuration at room temperature on 25 wt% glass fiber filled PTFE at a normal load of 10 N. The glass fiber filled PTFE showed superior tribological performance in sea water compared to dry sliding and distilled water environment conditions. The lowest average coefficient of friction of 0.028 and lowest specific wear rate of 5.85 × 10‑6 mm3 Nm‑1 was observed under sea water environment. The worn surfaces were examined using Optical microscopy, SEM, EDS and Raman spectroscopy to reveal the wear mechanisms. It was revealed that the superior tribological performance of glass fiber filled PTFE in sea water is due to the formation of a lubricating film on the surface of glass fiber filled PTFE in sea water. The profilometric traces of the counterface after tribological tests were taken using an optical 3D surface profilometer to investigate the effect of indirect corrosive wear on the friction and wear of glass fiber filled PTFE under sea water environment.

  15. Dynamic Stabilization of Metal Oxide–Water Interfaces

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McBriarty, Martin E.; von Rudorff, Guido Falk; Stubbs, Joanne E.

    2017-02-08

    The interaction of water with metal oxide surfaces plays a crucial role in the catalytic and geochemical behavior of metal oxides. In a vast majority of studies, the interfacial structure is assumed to arise from a relatively static lowest energy configuration of atoms, even at room temperature. Using hematite (α-Fe2O3) as a model oxide, we show through a direct comparison of in situ synchrotron X-ray scattering with density functional theory-based molecular dynamics simulations that the structure of the (1102) termination is dynamically stabilized by picosecond water exchange. Simulations show frequent exchanges between terminal aquo groups and adsorbed water in locationsmore » and with partial residence times consistent with experimentally determined atomic sites and fractional occupancies. Frequent water exchange occurs even for an ultrathin adsorbed water film persisting on the surface under a dry atmosphere. The resulting time-averaged interfacial structure consists of a ridged lateral arrangement of adsorbed water molecules hydrogen bonded to terminal aquo groups. Surface pKa prediction based on bond valence analysis suggests that water exchange will influence the proton-transfer reactions underlying the acid/base reactivity at the interface. Our findings provide important new insights for understanding complex interfacial chemical processes at metal oxide–water interfaces.« less

  16. Water resources and hydrology of Mars

    NASA Technical Reports Server (NTRS)

    Baker, V. R.; Gulick, V. C.; Kargel, J. S.; Strom, R. G.

    1991-01-01

    The surface of Mars has been extensively modified by a large variety of water erosional and depositional processes. Although liquid water is presently unstable on the planet's surface, in its cold, hyperarid climate, there is abundant geomorphological evidence of past fluvial valley development multiple episodes of catastrophic flooding, periglacial landforms, ice-related permafrost, lake deposits, eroded impact craters and possible glacial landforms throughout much of Mars' geological history. The amount of water required to form such features is estimated to be equivalent to a planet-wide layer approximately 50 meters deep. Some of this water undoubtedly was removed from the planet by atmospheric escape processes, but much probably remains in the subsurface of Mars. Jakosky summarized the present partitioning of water on Mars, expressed as an average global depth, as follows: in the polar caps, 30 meters; in the megaregolith, 500 to 1000 meters; structurally bound in clays, 10 meters; and in high latitude regolith, a few meters. However, most of this water is probably in the form of ice, except in anomalous areas of possible near surface liquid water, and in regions where hydrothermal systems are still active. The best locations for prospecting are those areas where water or ice is sufficiently concentrated at shallow enough depths to make it feasible to pump out or mine.

  17. Concentration and characterization of dissolved organic matter in the surface microlayer and subsurface water of the Bohai Sea, China

    NASA Astrophysics Data System (ADS)

    Chen, Yan; Yang, Gui-Peng; Wu, Guan-Wei; Gao, Xian-Chi; Xia, Qing-Yan

    2013-01-01

    A total of 19 sea-surface microlayer and corresponding subsurface samples collected from the Bohai Sea, China in April 2010 were analyzed for chlorophyll a, dissolved organic carbon (DOC) and its major compound classes including total dissolved carbohydrates (TDCHO, including monosaccharides, MCHO, and polysaccharides, PCHO) and total hydrolysable amino acids (THAA, including dissolved free, DFAA, and combined fraction, DCAA). The concentrations of DOC in the subsurface water ranged from 130.2 to 407.7 μM C, with an average of 225.9±75.4 μM C, while those in the surface microlayer varied between 140.1 and 330.9 μM C, with an average of 217.8±56.8 μM C. The concentrations of chlorophyll a, DOC, TDCHO and THAA in the microlayer were, respectively correlated with their subsurface water concentrations, implying that there was a strong exchange effect between the microlayer and subsurface water. The concentrations of DOC and TDCHO were negatively correlated with salinity, respectively, indicating that water mixing might play an important role in controlling the distribution of DOC and TDCHO in the water column. Major constituents of DCAA and DFAA present in the study area were glycine, alanine, glutamic acid, serine and histidine. Principal component analysis (PCA) was applied to examine the complex compositional differences that existed among the sampling sites. Our results showed that DFAA had higher mole percentages of glycine, valine and serine in the microlayer than in the subsurface water, while DCAA tended to have higher mole percentages of glutamic acid, aspartic acid, threonine, arginine, alanine, tyrosine, phenylalanine and leucine in the microlayer. The yields of TDCHO and THAA exhibited similar trends between the microlayer and subsurface water. Carbohydrate species displayed significant enrichment in the microlayer, whereas the DFAA and DCAA exhibited non-uniform enrichment in the microlayer.

  18. Hydrogeology and ground-water flow in the carbonate rocks of the Little Lehigh Creek basin, Lehigh County, Pennsylvania

    USGS Publications Warehouse

    Sloto, R.A.; Cecil, L.D.; Senior, L.A.

    1991-01-01

    The Little Lehigh Creek basin is underlain mainly by a complex assemblage of highly-deformed Cambrian and Ordovician carbonate rocks. The Leithsville Formation, Allentown Dolomite, Beekmantown Group, and Jacksonburg Limestone act as a single hydrologic unit. Ground water moves through fractures and other secondary openings and generally is under water-table conditions. Median annual ground-water discharge (base flow) to Little Lehigh Creek near Allentown (station 01451500) during 1946-86 was 12.97 inches or 82 percent of streamflow. Average annual recharge for 1975-83 was 21.75 inches. Groundwater and surface-water divides do not coincide in the basin. Ground-water underflow from the Little Lehigh Creek basin to the Cedar Creek basin in 1987 was 4 inches per year. A double-mass curve analysis of the relation of cumulative precipitation at Allentown to the flow of Schantz Spring for 1956-84 showed that cessation of quarry pumping and development of ground water for public supply in the Schantz Spring basin did not affect the flow of Schantz Spring. Ground-water flow in the Little Lehigh Creek basin was simulated using a finite-difference, two-dimensional computer model. The geologic units in the modeled area were simulated as a single water-table aquifer. The 134-squaremile area of carbonate rocks between the Lehigh River and Sacony Creek was modeled to include the natural hydrologic boundaries of the ground-water-flow system. The ground-water-flow model was calibrated under steady-state conditions using 1975-83 average recharge, evapotranspiration, and pumping rates. Each geologic unit was assigned a different hydraulic conductivity. Initial aquifer hydraulic conductivity was estimated from specific-capacity data. The average (1975-83) water budget for the Little Lehigh Creek basin was simulated. The simulated base flow from the carbonate rocks of the Little Lehigh Creek basin above gaging station 01451500 is 11.85 inches per year. The simulated ground-water underflow from the Little Lehigh Creek basin to the Cedar Creek basin is 4.04 inches per year. For steady-state calibration, the root-mean-squared difference between observed and simulated heads was 21.19 feet. The effects of increased ground-water development on base flow and underflow out of the Little Lehigh Creek basin for average and drought conditions were simulated by locating a hypothetical well field in different parts of the basin. Steady-state simulations were used to represent equilibrium conditions, which would be the maximum expected long-term effect. Increased ground-water development was simulated as hypothetical well fields pumping at the rate of 15, 25, and 45 million gallons per day in addition to existing ground-water withdrawals. Four hypothetical well fields were located near and away from Little Lehigh Creek in upstream and downstream areas. The effects of pumping a well field in different parts of the Little Lehigh Creek basin were compared. Pumping a well field located near the headwaters of Little Lehigh Creek and away from the stream would have greatest effect on inducing underflow from the Sacony Greek basin and the least effect on reducing base flow and underflow to the Ceda^r Creek basin. Pumping a well field located near the headwaters of Little Leh|igh Creek near the stream would have less impact on inducing underflow from|the Sacony Creek basin and a greater impact on reducing the base flow of Little Lehigh Creek because more of the pumpage would come from diverted base flow. Pumping a well field located in the downstream area of the Little Lehigh Creek basin away from the stream would have the greatest effect on the underflow to the Cedar Creek basin. Pumping a well field located in the downstream area of the Little Lehigh Creek basin near the stream would have the greatest effect on reducing the base flow of Little Lehigh Cteek. Model simulations show that groundwater withdrawals do not cause a proportional reduction in base flow. Under average conditions, ground-water withdrawals are equal to 48 to 70 percent of simulated base-flow reductions; under drought conditions, ground-water withdrawals are equal to 35 to 73 percent of simulated base-flow reductions. The hydraulic effects of pumping largely depend on well location. In the Little Lehigh basin, surface-water and ground-water divides do not coincide, and ground-water development, especially near surface-water divides, can cause ground-water divides to shift and induce ground-water underflow from adjacent basins. Large-scale ground-water pumping in a basin may not produce expected reductions of base flow in that basin because of shifts in the ground-water divide; however, such shifts can reduce base flow in adjacent surface-water basins. 

  19. The global distribution and dynamics of surface soil moisture

    NASA Astrophysics Data System (ADS)

    McColl, Kaighin A.; Alemohammad, Seyed Hamed; Akbar, Ruzbeh; Konings, Alexandra G.; Yueh, Simon; Entekhabi, Dara

    2017-01-01

    Surface soil moisture has a direct impact on food security, human health and ecosystem function. It also plays a key role in the climate system, and the development and persistence of extreme weather events such as droughts, floods and heatwaves. However, sparse and uneven observations have made it difficult to quantify the global distribution and dynamics of surface soil moisture. Here we introduce a metric of soil moisture memory and use a full year of global observations from NASA's Soil Moisture Active Passive mission to show that surface soil moisture--a storage believed to make up less than 0.001% of the global freshwater budget by volume, and equivalent to an, on average, 8-mm thin layer of water covering all land surfaces--plays a significant role in the water cycle. Specifically, we find that surface soil moisture retains a median 14% of precipitation falling on land after three days. Furthermore, the retained fraction of the surface soil moisture storage after three days is highest over arid regions, and in regions where drainage to groundwater storage is lowest. We conclude that lower groundwater storage in these regions is due not only to lower precipitation, but also to the complex partitioning of the water cycle by the surface soil moisture storage layer at the land surface.

  20. Characterising urban zinc generation to identify surface pollutant hotspots in a low intensity rainfall climate.

    PubMed

    Charters, F J; Cochrane, T A; O'Sullivan, A D

    2017-09-01

    Characterising stormwater runoff quality provides useful insights into the dynamics of pollutant generation and wash off rates. These can be used to prioritise stormwater management strategies. This study examined the effects of a low intensity rainfall climate on zinc contributions from different impermeable urban surface types. First flush (FF) and steady state samples were collected from seven different surfaces for characterisation, and the data were also used to calibrate an event-based pollutant load model to predict individual 'hotspot' surfaces across the catchment. Unpainted galvanised roofs generated very high concentrations of zinc, primarily in the more biologically available dissolved form. An older, unpainted galvanised roof had FF concentrations averaging 32,338 μg/L, while the new unpainted roof averaged 4,782 μg/L. Roads and carparks also had elevated zinc, but FF concentrations averaged only 822-1,584 μg/L. Modelling and mapping expected zinc loads from individual impermeable surfaces across the catchment identified specific commercial roof surfaces to be targeted for zinc management. The results validate a policy strategy to replace old galvanised roof materials and avoid unpainted galvanised roofing in future urban development for better urban water quality outcomes. In the interim, readily-implemented treatment options are required to help mitigate chronic zinc impacts on receiving waterways.

  1. Ground-water resources of Kansas

    USGS Publications Warehouse

    Moore, R.C.; Lohman, S.W.; Frye, J.C.; Waite, H.A.; McLaughlin, Thad G.; Latta, Bruce

    1940-01-01

    Importance of ground-water resources.—The importance of Kansas' ground-water resources may be emphasized from various viewpoints and in different ways. More than three-fourths of the public water supplies of Kansas are obtained from wells. In 1939, only 60 out of 375 municipal water supplies in Kansas, which is 16 percent, utilized surface waters. If the water wells of the cities and those located on all privately owned land in the state were suddenly destroyed, making it necessary to go to streams, springs, lakes (which are almost all artificial), and ponds for water supply domestic, stock, and industrial use, there would be almost incalculable difficulty and expense. If one could not go to springs, or dig new wells, or use any surface water derived from underground flow, much of Kansas would become uninhabitable.  These suggested conditions seem absurd, but they emphasize our dependence on ground-water resources. Fromm a quantitative standpoint, ground-water supplies existent in Kansas far outweigh surface waters that are present in the state at any one time. No exact figures for such comparison can be given, but, taking 384 square miles as the total surface water area of the state and estimating an average water depth of five feet, the computed volume of surface waters is found to be 1/100th of that of the conservatively estimated ground-water storage in Kansas. The latter takes account only of potable fresh water and is based on an assumed mean thickness of ten feet of reservoir having an effective porosity of twenty percent. It is to be remembered, however, that most of the surface water is run-off, which soon leaves the state, stream valleys being replenished from rainfall and flow from ground-water reservoirs. Most of the ground-water supplies, on the other hand, have existed for many years with almost no appreciable movement--in fact, it is reasonably certain that some well water drawn from beneath the surface of Kansas in 1940 represents rainfall in this region at time before the first white man entered Kansas, even before the visit of Coronado in the 16th century. Most ground water is to be regarded as water in storage rather than water in transit.   

  2. Stick-Jump (SJ) Evaporation of Strongly Pinned Nanoliter Volume Sessile Water Droplets on Quick Drying, Micropatterned Surfaces.

    PubMed

    Debuisson, Damien; Merlen, Alain; Senez, Vincent; Arscott, Steve

    2016-03-22

    We present an experimental study of stick-jump (SJ) evaporation of strongly pinned nanoliter volume sessile water droplets drying on micropatterned surfaces. The evaporation is studied on surfaces composed of photolithographically micropatterned negative photoresist (SU-8). The micropatterning of the SU-8 enables circular, smooth, trough-like features to be formed which causes a very strong pinning of the three phase (liquid-vapor-solid) contact line of an evaporating droplet. This is ideal for studying SJ evaporation as it contains sequential constant contact radius (CCR) evaporation phases during droplet evaporation. The evaporation was studied in nonconfined conditions, and forced convection was not used. Micropatterned concentric circles were defined having an initial radius of 1000 μm decreasing by a spacing ranging from 500 to 50 μm. The droplet evaporates, successively pinning and depinning from circle to circle. For each pinning radius, the droplet contact angle and volume are observed to decrease quasi-linearly with time. The experimental average evaporation rates were found to decrease with decreasing pining radii. In contrast, the experimental average evaporation flux is found to increase with decreasing droplet radii. The data also demonstrate the influence of the initial contact angle on evaporation rate and flux. The data indicate that the total evaporation time of a droplet depends on the specific micropattern spacing and that the total evaporation time on micropatterned surfaces is always less than on flat, homogeneous surfaces. Although the surface patterning is observed to have little effect on the average droplet flux-indicating that the underlying evaporation physics is not significantly changed by the patterning-the total evaporation time is considerably modified by patterning, up to a factor or almost 2 compared to evaporation on a flat, homogeneous surface. The closely spaced concentric circle pinning maintains a large droplet radius and small contact angle from jump to jump; the result is a large evaporation rate leading to faster evaporation.

  3. Hydrogeologic data for the Big River-Mishnock River stream-aquifer system, central Rhode Island

    USGS Publications Warehouse

    Craft, P.A.

    2001-01-01

    Hydrogeology, ground-water development alternatives, and water quality in the BigMishnock stream-aquifer system in central Rhode Island are being investigated as part of a long-term cooperative program between the Rhode Island Water Resources Board and the U.S. Geological Survey to evaluate the ground-water resources throughout Rhode Island. The study area includes the Big River drainage basin and that portion of the Mishnock River drainage basin upstream from the Mishnock River at State Route 3. This report presents geologic data and hydrologic and water-quality data for ground and surface water. Ground-water data were collected from July 1996 through September 1998 from a network of observation wells consisting of existing wells and wells installed for this study, which provided a broad distribution of data-collection sites throughout the study area. Streambed piezometers were used to obtain differences in head data between surface-water levels and ground-water levels to help evaluate stream-aquifer interactions throughout the study area. The types of data presented include monthly ground-water levels, average daily ground-water withdrawals, drawdown data from aquifer tests, and water-quality data. Historical water-level data from other wells within the study area also are presented in this report. Surface-water data were obtained from a network consisting of surface-water impoundments, such as ponds and reservoirs, existing and newly established partial-record stream-discharge sites, and synoptic surface-water-quality sites. Water levels were collected monthly from the surface-water impoundments. Stream-discharge measurements were made at partial-record sites to provide measurements of inflow, outflow, and internal flow throughout the study area. Specific conductance was measured monthly at partial-record sites during the study, and also during the fall and spring of 1997 and 1998 at 41 synoptic sites throughout the study area. General geologic data, such as estimates of depth to bedrock and depth to water table, as well as indications of underlying geologic structure, were obtained from geophysical surveys. Site-specific geologic data were collected during the drilling of observation wells and test holes. These data include depth to bedrock or refusal, depth to water table, and lithologic information.

  4. Influence of long-range forces and capillarity on the function of underwater superoleophobic wrinkled surfaces.

    PubMed

    Owais, Ahmed; Smith-Palmer, Truis; Gentle, Angus; Neto, Chiara

    2018-06-26

    Underwater superoleophobic surfaces can be considered a particular type of lubricant-infused surface, that have anti-fouling properties by virtue of a trapped water layer that repels oils. However, as their function relies on a water layer being trapped in the surface roughness, it is crucial to understand the factors that determine the layer stability. In this work, the forces that are responsible for the stability of thin liquid films within structured surfaces were quantified, and the conclusions were tested against the performance of wrinkled surfaces as underwater superoleophobic coatings. Here, the system studied was a family of wrinkled surfaces made of hydrophilic poly(4-vinylpyridine) (P4VP), whereby the wrinkle width could be controllably tuned in the range 90 nm to 8000 nm. The van der Waals free energy was quantified and the capillary forces trapping water in the surface micro- and nano-wrinkle structure were estimated. P4VP surfaces with micro-scale wrinkles had underwater superoleophobic properties, and low adhesion to different oils with droplet roll-off angle below 6° ± 1°. Despite the van der Waals free energy of the system pointing to the dewetting of a water film under oil on top of a smooth P4VP film, the wrinkled structure is sufficient to induce a Cassie state with a trapped water layer. The micro-scale wrinkles (average width 4-12 μm) were found to be particularly effective in the trapping of the water in a Cassie non-adhesive state. The P4VP wrinkled surfaces are superamphiphobic, as when they were first infused with oil, and then exposed to a droplet of water under oil, they exhibited superhydrophobic behavior. The P4VP wrinkles have the additional useful feature of being transparent underwater, which makes them useful candidates for the protection of underwater cameras and sensors.

  5. Denitrification in the shallow ground water of a tile-drained, agricultural watershed

    USGS Publications Warehouse

    Mehnert, E.; Hwang, H.-H.; Johnson, T.M.; Sanford, R.A.; Beaumont, W.C.; Holm, T.R.

    2007-01-01

    Nonpoint-source pollution of surface water by N is considered a major cause of hypoxia. Because Corn Belt watersheds have been identified as major sources of N in the Mississippi River basin, the fate and transport of N from midwestern agricultural watersheds have received considerable interest. The fate and transport of N in the shallow ground water of these watersheds still needs additional research. Our purpose was to estimate denitrification in the shallow ground water of a tile-drained, Corn Belt watershed with fine-grained soils. Over a 3-yr period, N was monitored in the surface and ground water of an agricultural watershed in central Illinois. A significant amount of N was transported past the tile drains and into shallow ground water. The ground water nitrate was isotopically heavier than tile drain nitrate, which can be explained by denitrification in the subsurface. Denitrifying bacteria were found at depths to 10 m throughout the watershed. Laboratory and push-pull tests showed that a significant fraction of nitrate could be denitrified rapidly. We estimated that the N denitrified in shallow ground water was equivalent to 0.3 to 6.4% of the applied N or 9 to 27% of N exported via surface water. These estimates varied by water year and peaked in a year of normal precipitation after 2 yr of below average precipitation. Three years of monitoring data indicate that shallow ground water in watersheds with fine-grained soils may be a significant N sink compared with N exported via surface water. ?? ASA, CSSA, SSSA.

  6. Geology and ground-water resources of Fillmore County, Nebraska

    USGS Publications Warehouse

    Keech, Charles Franklin; Dreeszen, V.H.

    1968-01-01

    Fillmore County, an area 24 miles square, lies in the eastern part of the Nebraska loess plain. Although tributaries of the Big Blue River have eroded valleys into this plain, much of the original surface is intact. Broad flats and numerous shallow undrained depressions characterize the plain. The county is underlain by unconsolidated deposits of Quaternary age to depths ranging from about 80 to 450 feet. The upper part of this depositional sequence consists largely of wind-deposited clayey silt, and the lower part of stream-deposited sand and gravel. In part of the county, deposits of glacial till also are included. The Quaternary deposits mantle an eroded surface of marine-deposited strata of Cretaceous age. The lower deposits of Quaternary age are saturated and constitute a highly productive aquifer throughout much of the county. The saturated zone ranges from about 20 to 350 feet in thickness. Replenishment to this aquifer, derived principally from precipitation, is believed to average about 1.4 inches per year. Because the quantity of ground water pumped per year exceeds the average annual quantity of recharge, some of the water used for irrigation is from storage. Consequently, water levels in wells .are declining. This trend is likely to continue. The ground water is of the calcium bicarbonate type and is hard, but it is chemically suitable for irrigation use on most soils in the county.

  7. Sequential estimation of surface water mass changes from daily satellite gravimetry data

    NASA Astrophysics Data System (ADS)

    Ramillien, G. L.; Frappart, F.; Gratton, S.; Vasseur, X.

    2015-03-01

    We propose a recursive Kalman filtering approach to map regional spatio-temporal variations of terrestrial water mass over large continental areas, such as South America. Instead of correcting hydrology model outputs by the GRACE observations using a Kalman filter estimation strategy, regional 2-by-2 degree water mass solutions are constructed by integration of daily potential differences deduced from GRACE K-band range rate (KBRR) measurements. Recovery of regional water mass anomaly averages obtained by accumulation of information of daily noise-free simulated GRACE data shows that convergence is relatively fast and yields accurate solutions. In the case of cumulating real GRACE KBRR data contaminated by observational noise, the sequential method of step-by-step integration provides estimates of water mass variation for the period 2004-2011 by considering a set of suitable a priori error uncertainty parameters to stabilize the inversion. Spatial and temporal averages of the Kalman filter solutions over river basin surfaces are consistent with the ones computed using global monthly/10-day GRACE solutions from official providers CSR, GFZ and JPL. They are also highly correlated to in situ records of river discharges (70-95 %), especially for the Obidos station where the total outflow of the Amazon River is measured. The sparse daily coverage of the GRACE satellite tracks limits the time resolution of the regional Kalman filter solutions, and thus the detection of short-term hydrological events.

  8. Potential of green infrastructure to restore predevelopment water budget of a semi-arid urban catchment

    NASA Astrophysics Data System (ADS)

    Feng, Youcan; Burian, Steven; Pomeroy, Christine

    2016-11-01

    This paper presents a study of the potential for green infrastructure (GI) to restore the predevelopment hydrologic cycle in a semi-arid urban catchment. Simulations of stormwater runoff from a 0.11-km2 urban catchment in Salt Lake City, Utah, USA for predeveloped (Natural Hydrology, NH), developed (Baseline, BL), and developed with GI (Green Infrastructure, GI) conditions were executed for a one-year period. The study was repeated for a relatively dry year, wet year, and an average year based on precipitation amounts in the year. Bioretention and green roofs were chosen for the GI plan. Results showed that the water budget of the catchment with the GI plan implemented more closely matches the NH water budget compared to the BL scenario, for all three years (dry, wet, average). The BL and GI scenarios showed more significant modifications to the water budget than what has been found by studies in humid climates. Compared to the BL condition, GI annually reduces surface runoff by 35%, 45%, and 43% and restores evapotranspiration by 18%, 19%, and 25% for the dry, average, wet years, respectively. Based on the introduced water budget restoration coefficient (WBRC), the water budget of the study catchment was restored by the GI plan to 90%, 90%, and 82% of the predevelopment state in the dry, average, and wet years, respectively. By comparing the WBRC estimated for other studies, it is further inferred that the water budget is more significantly affected by development and GI restoration in semi-arid than humid climates, but the differences lessen as the precipitation amount increases.

  9. Ground water recharge and discharge in the central Everglades

    USGS Publications Warehouse

    Harvey, Judson W.; Krupa, Steven L.; Krest, James M.

    2004-01-01

    Rates of ground water recharge and discharge are not well known in the central Everglades. Here we report estimates of ground water recharge and discharge at 15 sites in the Everglades Nutrient Removal Project and in Water Conservation Area 2A (WCA-2A), along with measurements of hydraulic properties of peat at 11 sites. A simple hydrogeologic simulation was used to assess how specific factors have influenced recharge and discharge. Simulations and measurements agreed that the highest values of recharge and discharge occur within 600 m of levees, the result of ground water flow beneath levees. There was disagreement in the interior wetlands of WCA-2A (located > 1000 m from levees) where measurements of recharge and discharge were substantially higher than simulated fluxes. A five-year time series (1997 to 2002) of measured fluxes indicated that recharge and discharge underwent reversals in direction on weekly, monthly, and annual timescales at interior sites in WCA-2A. Ground water discharge tended to occur during average to moderately dry conditions when local surface water levels were decreasing. Recharge tended to occur during moderately wet periods or during very dry periods just as water levels began to increase following precipitation or in response to a pulse of surface water released from water-control structures by water managers. Discharge also tended to occur at sites in the wetland interior for ∼1 week preceding the arrival of the surface water pulse. We conclude that ground water recharge and discharge vary cyclically in the interior wetlands of the central Everglades, driven by the differential responses of surface water and ground water to annual, seasonal, and weekly trends in precipitation and operation of water-control structures.

  10. Characteristics and Future Changes of Great Mississippi Flood Events in a Global Coupled Climate Model

    NASA Astrophysics Data System (ADS)

    van der Wiel, K.; Kapnick, S. B.; Vecchi, G.; Smith, J. A.

    2017-12-01

    The Mississippi-Missouri river catchment houses millions of people and much of the U.S. national agricultural production. Severe flooding events can therefore have large negative societal, natural and economic impacts. GFDL FLOR, a global coupled climate model (atmosphere, ocean, land, sea ice with integrated river routing module) is used to investigate the characteristics of great Mississippi floods with an average return period of 100 years. Model experiments under pre-industrial greenhouse gas forcing were conducted for 3400 years, such that the most extreme flooding events were explicitly modeled and the land and/or atmospheric causes could be investigated. It is shown that melt of snow pack and frozen sub-surface water in the Missouri and Upper Mississippi basins prime the river system, subsequently sensitizing it to above average precipitation in the Ohio and Tennessee basins. The months preceding the greatest flooding events are above average wet, leading to moist sub-surface conditions. Anomalous melt depends on the availability of frozen water in the catchment, therefore anomalous amounts of sub-surface frozen water and anomalous large snow pack in winter (Nov-Feb) make the river system susceptible for these great flooding events in spring (Feb-Apr). An additional experiment of 1200 years under transient greenhouse gas forcing (RCP4.5, 5 members) was done to investigate potential future change in flood risk. Based on a peak-over-threshold method, it is found that the number of great flooding events decreases in a warmer future. This decrease coincides with decreasing occurrence of large melt events, but is despite increasing numbers of large precipitation events. Though the model results indicate a decreasing risk for the greatest flooding events, the predictability of events might decrease in a warmer future given the changing characters of melt and precipitation.

  11. [Contamination and Ecological Risk Assessment of Mercury in Hengshuihu Wetland, Hebei Province].

    PubMed

    Wang, Nai-shan; Zhang, Man-yin; Cui, Li-juan; Ma, Mu-yuan; Yan, Liang; Mu, Yong-lin; Qin, Peng

    2016-05-15

    Investigation on the concentrations and the distribution characteristics of total mercury in atmosphere, water surface and soil/ sediments of Hengshuihu wetland was carried out based on a uniform set point sampling method. The geoaccumulation index and potential ecological risk index methods were simultaneously used to assess the mercury pollution in Hengshuihu wetland ecosystem. The results showed that: the total mercury content in Hengshuihu wetland atmosphere ranged from 1.0 to 5.0 ng · m⁻³, with an average of (2.9 ± 0.85) ng · m⁻³; the total mercury content in water surface ranged from 0.010 to 0.57 µg · L⁻¹, with the average value of (0.081 ± 0.053) µg · L⁻¹; the total mercury content in soil/sediment ranged from 0.001 0 to 0.058 mg · kg⁻¹, with an average of (0.027 ± 0.013) mg · kg⁻¹. The distribution features of total mercury in Hengshuihu wetland were as follows: the total mercury concentration in surface water of the shore was significantly higher than that in the center (P < 0.05), but the total mercury concentration of sediments in the center of the lake was significantly higher than that at the shore (P < 0.05); the total mercury in the soil of shore had a consistent trend with that in the atmosphere; high concentrations of total mercury pollution were accompanied by severe human activities. The geoaccumulation index showed that mercury pollution in Hengshuihu wetland was at clean level; potential ecological risk index showed mercury contamination had a low ecological risk in Hengshuihu wetland.

  12. Studies of drag on the nanocomposite superhydrophobic surfaces

    NASA Astrophysics Data System (ADS)

    Brassard, Jean-Denis; Sarkar, D. K.; Perron, Jean

    2015-01-01

    The nanocomposite thin films of stearic acid (SA)-functionalized ZnO nanoparticles incorporated in epoxy polymer matrix have been achieved. The X-ray diffraction (XRD) studies show the formation of zinc stearate on ZnO nanoparticles as the confirmation of SA-functionalization of ZnO nanoparticles in the thin films. Morphological analyses reveal the presence of micro-holes with the presence of irregular nanoparticles. The measured root mean square (rms) roughness of the thin film is found to be 12 ± 1 μm with the adhesion of 5B on both glass and aluminum substrates. The wetting property shows that the surface of the film is superhydrophobic with the contact angle of water of 156 ± 4° having contact angle hysteresis (CAH) of 4 ± 2°. The average terminal velocity in the water of the as-received glass spheres and superhydrophobic spheres were found to be 0.66 ± 0.01 m/s and 0.72 ± 0.01 m/s respectively. Consequently, the calculated average coefficients of the surface drag of the as-received glass sphere and superhydrophobic glass sphere were 2.30 ± 0.01 and 1.93 ± 0.03, respectively. Hence, the drag reduction on the surface of superhydrophobic glass sphere is found to be approximately 16% lower than as-received glass sphere.

  13. Tile Drainage Management Influences on Surface-Water and Groundwater Quality following Liquid Manure Application.

    PubMed

    Frey, Steven K; Topp, Ed; Ball, Bonnie R; Edwards, Mark; Gottschall, Natalie; Sunohara, Mark; Zoski, Erin; Lapen, David R

    2013-01-01

    This study investigated the potential for controlled tile drainage (CD) to reduce bacteria and nutrient loading to surface water and groundwater from fall-season liquid manure application (LMA) on four macroporous clay loam plots, of which two had CD and two had free-draining (FD) tiles. Rhodamine WT (RWT) was mixed into the manure and monitored in the tile water and groundwater following LMA. Tile water and groundwater quality were influenced by drainage management. Following LMA on the FD plots, RWT, nutrients, and bacteria moved rapidly via tiles to surface water; at the CD plots, tiles did not flow until the first post-LMA rainfall, so the immediate risk of LMA-induced contamination of surface water was abated. During the 36-d monitoring period, flow-weighted average specific conductance, redox potential, and turbidity, as well as total Kjeldahl N (TKN), total P (TP), NH-N, reactive P, and RWT concentrations, were higher in the CD tile effluent; however, because of lower tile discharge from the CD plots, there was no significant ( ≤ 0.05) difference in surface water nutrient and RWT loading between the CD and FD plots when all tiles were flowing. The TKN, TP, and RWT concentrations in groundwater also tended to be higher at the CD plots. Bacteria behaved differently than nutrients and RWT, with no significant difference in total coliform, , fecal coliform, fecal streptococcus, and concentrations between the CD and FD tile effluent; however, for all but , hourly loading was higher from the FD plots. Results indicate that CD has potential for mitigating bacteria movement to surface water. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  14. Observations and model predictions of water skin temperatures at MTI core site lakes and reservoirs

    NASA Astrophysics Data System (ADS)

    Garrett, Alfred J.; Kurzeja, Robert J.; O'Steen, Byron L.; Parker, Matthew J.; Pendergast, Malcolm M.; Villa-Aleman, Eliel; Pagnutti, Mary A.

    2001-08-01

    The Savannah River Technology Center (SRTC) measured water skin temperatures at four of the Multi-spectral Thermal Imager (MTI) core sites. The depression of the skin temperature relative to the bulk water temperature ((Delta) T) a few centimeters below the surface is a complex function of the weather conditions, turbulent mixing in the water and the bulk water temperature. Observed skin temperature depressions range from near zero to more than 1.0 degree(s)C. Skin temperature depressions tend to be larger when the bulk water temperature is high, but large depressions were also observed in cool bodies of water in calm conditions at night. We compared (Delta) T predictions from three models (SRTC, Schlussel and Wick) against measured (Delta) T's from 15 data sets taken at the MTI core sites. The SRTC and Wick models performed somewhat better than the Schlussel model, with RMSE and average absolute errors of about 0.2 degree(s)C, relative to 0.4 degree(s)C for the Schlussel model. The average observed (Delta) T for all 15 databases was -0.7 degree(s)C.

  15. Sources of Water to Wells for Transient Cyclic Systems

    USGS Publications Warehouse

    Reilly, T.E.; Pollock, D.W.

    1996-01-01

    Many state agencies are currently (1995) developing wellhead protection programs. The thrust of some of these programs is to protect water supplies by determining the areas contributing recharge to water-supply wells and by specifying regulations to minimize the opportunity for contamination of the recharge water by activities at the land surface. The area contributing recharge to a discharging well is the surface area at the water table through which the water flowing to the well entered the ground-water system. In the analyses of ground-water flow systems, steady-state average conditions are commonly used to simplify the problem and make a solution tractable. However, recharge is usually cyclic in nature, with seasonal cycles and longer term climatic cycles. The effect of these cyclic stresses on the area contributing recharge to wells is quantitatively analyzed for a hypothetical alluvial valley aquifer system that is representative of a large class of ground-water systems that are extensively developed for water supply. The analysis shows that, in many cases, these cyclic changes in the recharge rates do not significantly affect the location and size of the areas contributing recharge to wells. The ratio of the mean travel time to the length of the cyclic stress period appears to be an indicator of whether the transient effects of the cyclic stress must be explicitly represented in the analysis of contributing areas to wells. For the cases examined, if the ratio of the mean travel time to the period of the cyclic stress was much greater than one, then the transient area contributing recharge to wells was similar to the area calculated using an average steady-state condition. However, cyclic stresses on systems with ratios less than one do have an effect on the location and size of the areas contributing recharge to wells.

  16. Surface-water hydrology of the Little Black River basin, Missouri and Arkansas, before water-land improvement practices

    USGS Publications Warehouse

    Berkas, W.R.; Femmer, Suzanne R.; Mesko, T.O.; Thompson, B.W.

    1987-01-01

    The U. S. Department of Agriculture, Soil Conservation Service, in accordance with Public Law 566, is implementing various types of water-land improvement practices in the Little Black River basin in southeastern Missouri. These practices are designed, in part, to decrease the suspended sediment (SS) transport in the basin, decrease flood damage in the basin, and improve drainage in the agricultural area. The general features of the basin, such as geology, groundwater hydrology, soils, land use, water use, and precipitation are described; surface water quantity, quality, and suspended sediment discharge are also described. The aquifers are the Mississippi River valley alluvial aquifer, which can yield about 3,500 gal/min to properly constructed wells, and the Ozark and St. Francois aquifers, which can yield from about 30 to 500 gal/min to properly constructed wells. Soils in the area have formed in loess and cherty residuum in the uplands or have formed in alluvial sediment in the lowlands. About 93% of the estimated 3 billion gal/year of water used in the basin is for crop irrigation. The average monthly precipitation varies slightly throughout the year, with an average annual precipitation of about 47 inches. Water quality data were collected at seven stations. Specific conductance values ranged from 50 to 400 microsiemens/cm at 25 C. Water temperatures ranged from 0.0 C in the winter to 33.5 C in summer. pH values ranged from 6.4 to 8.5 units. Dissolved oxygen concentrations ranged from 2.2 to 12.8 ml/l. Total nitrogen concentrations ranged from 0.13 to 2.20 ml/l as nitrogen, with organic nitrogen as the most abundant form. Phosphorus concentrations ranged from zero to 0.29 ml/l as phosphorus. Bacterial counts were largest during storm runoff in the basin with livestock waste as the significant contributor. For the period from October 1, 1980, to September 30, 1984, the average annual SS discharge ranged from 2,230 tons/yr in the headwater areas to 27,800 tons/yr at the most downstream station. The average annual SS yield ranged from 59.6 to 85.9 tons/sq mi. (Author 's abstract)

  17. Reservoir compaction of the Belridge Diatomite and surface subsidence, south Belridge field, Kern County, California

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bowersox, J.R.; Shore, R.A.

    1990-05-01

    Surface subsidence due to reservoir compaction during production has been observed in many large oil fields. Subsidence is most obvious in coastal and offshore fields where inundation by the sea occurs. Well-known examples are Wilmington field in California and Ekofisk field in the North Sea. In South Belridge field, the Belridge Diatomite member of the late Miocene Reef Ridge Shale has proven prone to compaction during production. The reservoir, a high-porosity, low-permeability, highly compressive rock composed largely of diatomite and mudstone, is about 1,000 ft thick and lies at an average depth of 1,600 ft. Within the Belridge Diatomite, reservoirmore » compaction due to withdrawal of oil and water in Sec. 12, T28S, R20E, MDB and M, was noticed after casing failures in producing wells began occurring and tension cracks, enlarged by hydrocompaction after a heavy rainstorm were observed. Surface subsidence in Sec. 12 has been monitored since April 1987, through the surveying of benchmark monuments. The average annualized subsidence rate during 1987 was {minus}1.86 ft/yr, {minus}0.92 ft/yr during 1988, and {minus}0.65 ft/yr during 1989; the estimated peak subsidence rate reached {minus}7.50 ft/yr in July 1985, after 1.5 yrs of production from the Belridge Diatomite reservoir. Since production from the Belridge Diatomite reservoir commenced in February 1984, the surface of the 160-ac producing area has subsided about 12.5 ft. This equates to an estimated reservoir compaction of 30 ft in the Belridge Diatomite and an average loss of reservoir porosity of 2.4% from 55.2 to 52.8%. Injection of water for reservoir pressure maintenance in the Belridge diatomite began in June 1987, and has been effective in mitigating subsidence to current rates and repressurizing the reservoir to near-initial pressure. An added benefit of water injection has been improved recovery of oil from the Belridge Diatomite by waterflood.« less

  18. A geographical approach to tracking Escherichia coli and other water quality constituents in a Texas coastal plains watershed.

    PubMed

    Harclerode, C L; Gentry, T J; Aitkenhead-Peterson, J A

    2013-06-01

    Diffuse sources of surface water pathogens and nutrients can be difficult to isolate in larger river basins. This study used a geographical or nested approach to isolate diffuse sources of Escherichia coli and other water quality constituents in a 145.7-km(2) river basin in south central Texas, USA. Average numbers of E. coli ranged from 49 to 64,000 colony forming units (CFU) per 100 mL depending upon season and stream flow over the 1-year sampling period. Nitrate-N concentrations ranged from 48 to 14,041 μg L(-1) and orthophosphate-P from 27 to 2,721 μg L(-1). High concentrations of nitrate-N, dissolved organic nitrogen, and orthophosphate-P were observed downstream of waste water treatment plants but E. coli values were higher in a watershed draining an older part of the city. Total urban land use explained between 56 and 72 % of the variance in mean annual E. coli values (p < 0.05) in nine hydrologically disconnected creeks. Of the types of urban land use, commercial land use explained most of the variance in E. coli values in the fall and winter. Surface water sodium, alkalinity, and potassium concentrations in surface water were best described by the proportion of commercial land use in the watershed. Based on our nested approach in examining surface water, city officials are able to direct funding to specific areas of the basin in order to mitigate high surface water E. coli numbers and nutrient concentrations.

  19. Thermodynamic analysis of water molecules at the surface of proteins and applications to binding site prediction and characterization.

    PubMed

    Beuming, Thijs; Che, Ye; Abel, Robert; Kim, Byungchan; Shanmugasundaram, Veerabahu; Sherman, Woody

    2012-03-01

    Water plays an essential role in determining the structure and function of all biological systems. Recent methodological advances allow for an accurate and efficient estimation of the thermodynamic properties of water molecules at the surface of proteins. In this work, we characterize these thermodynamic properties and relate them to various structural and functional characteristics of the protein. We find that high-energy hydration sites often exist near protein motifs typically characterized as hydrophilic, such as backbone amide groups. We also find that waters around alpha helices and beta sheets tend to be less stable than waters around loops. Furthermore, we find no significant correlation between the hydration site-free energy and the solvent accessible surface area of the site. In addition, we find that the distribution of high-energy hydration sites on the protein surface can be used to identify the location of binding sites and that binding sites of druggable targets tend to have a greater density of thermodynamically unstable hydration sites. Using this information, we characterize the FKBP12 protein and show good agreement between fragment screening hit rates from NMR spectroscopy and hydration site energetics. Finally, we show that water molecules observed in crystal structures are less stable on average than bulk water as a consequence of the high degree of spatial localization, thereby resulting in a significant loss in entropy. These findings should help to better understand the characteristics of waters at the surface of proteins and are expected to lead to insights that can guide structure-based drug design efforts. Copyright © 2011 Wiley Periodicals, Inc.

  20. Preliminary evaluation of magnitude and frequency of floods in selected small drainage basins in Ohio

    USGS Publications Warehouse

    Kolva, J.R.

    1985-01-01

    A previous study of flood magitudes and frequencies in Ohio concluded that existing regionalized flood equations may not be adequate for estimating peak flows in small basins that are heavily forested, surface mined, or located in northwestern Ohio. In order to provide a large data base for improving estimation of flood peaks in these basins, 30 crest-stage gages were installed in 1977, in cooperation with the Ohio Department of Transportation, to provide a 10-year record of flood data The study area consists of two distinct parts: Northwestern Ohio, which contains 8 sites, and southern and eastern Ohio, which contains 22 sites in small forested or surface-mined drainage basins. Basin characteristics were determined for all 30 sites for 1978 conditions. Annual peaks were recorded or estimated for all 30 sites for water years 1978-82; an additional year of peak discharges was available at four sites. The 2-year (Q2) and 5-year (Q5) flood peaks were determined from these annual peaks.Q2 and Q5 values also were calculated using published regionalized regression equations for Ohio. The ratios of the observed to predicted 2-year (R2) and 5-year (R5) values were then calculated. This study found that observed flood peaks aree lower than estimated peaks by a significant amount in surface-mined basins. The average ratios of observed to predicted R2 values are 0.51 for basins with more than 40 percent surface-minded land, and 0.68 for sites with any surface-mined land. The average R5 value is 0.55 for sites with more than 40 percent surface-minded land, and 0.61 for sites with any surface-mined land. Estimated flood peaks from forested basins agree with the observed values fairly well. R2 values average 0.87 for sites with 20 percent or more forested land, but no surface-mined land, and R5 values average 0.96. If all sites with more than 20 percent forested land and some surface-mined land are considered, R2 the values average 0.86, and the R5 values average 0.82.

  1. Water resources of Taos County, New Mexico

    USGS Publications Warehouse

    Garrabrant, Lynn A.

    1993-01-01

    In Taos County, ground water generally is unconfined and moves toward the Rio Grande or perennial streams. Water quality is good except in some areas where water has high values of specific conductance and hardness and contains high concentrations of dissolved solids and fluoride. Most wells are completed in alluvial sediments of Quaternary and Tertiary age in the Costilla Plains. A few wells are completed in basalt of the Taos Plateau and in alluvium of stream channels in the Sangre de Cristo Mountains. Depths to water in wells range from less than 1 to 1,080 feet below land surface. Well yields range from 1 to 3,000 gallons per minute. Water levels in wells in Sunshine Valley dropped 5 to 50 feet between 1955 and 1970. Ground-water irrigation has since declined and water levels have risen. Surface-water records show the county is a net producer of water. The average discharge gained in the Rio Grande as it flows through the county was 271,700 acre-feet per year for water years 1931-89. The highest mean monthly discharge occurs in May or June due to snowmelt runoff. Water quality ranges from good in upstream reaches to fair in lower reaches. Surface water was the source for 93 percent of water withdrawn in 1990, but ground water was used for all public supply, domestic, and industrial purposes. The largest water use is irrigation. About 28,500 acres were irrigated in 1990; alfalfa, native pasture, and planted pasture accounted for 91 percent of this acreage.

  2. Assessment of impacts of climate change on surface water availability using coupled SWAT and WEAP models: case of upper Pangani River Basin, Tanzania

    NASA Astrophysics Data System (ADS)

    Kishiwa, Peter; Nobert, Joel; Kongo, Victor; Ndomba, Preksedis

    2018-05-01

    This study was designed to investigate the dynamics of current and future surface water availability for different water users in the upper Pangani River Basin under changing climate. A multi-tier modeling technique was used in the study, by coupling the Soil and Water Assessment Tool (SWAT) and Water Evaluation And Planning (WEAP) models, to simulate streamflows under climate change and assess scenarios of future water availability to different socio-economic activities by year 2060. Six common Global Circulation Models (GCMs) from WCRP-CMIP3 with emissions Scenario A2 were selected. These are HadCM3, HadGEM1, ECHAM5, MIROC3.2MED, GFDLCM2.1 and CSIROMK3. They were downscaled by using LARS-WG to station scale. The SWAT model was calibrated with observed data and utilized the LARS-WG outputs to generate future streamflows before being used as input to WEAP model to assess future water availability to different socio-economic activities. GCMs results show future rainfall increase in upper Pangani River Basin between 16-18 % in 2050s relative to 1980-1999 periods. Temperature is projected to increase by an average of 2 °C in 2050s, relative to baseline period. Long-term mean streamflows is expected to increase by approximately 10 %. However, future peak flows are estimated to be lower than the prevailing average peak flows. Nevertheless, the overall annual water demand in Pangani basin will increase from 1879.73 Mm3 at present (2011) to 3249.69 Mm3 in the future (2060s), resulting to unmet demand of 1673.8 Mm3 (51.5 %). The impact of future shortage will be more severe in irrigation where 71.12 % of its future demand will be unmet. Future water demands of Hydropower and Livestock will be unmet by 27.47 and 1.41 % respectively. However, future domestic water use will have no shortage. This calls for planning of current and future surface water use in the upper Pangani River Basin.

  3. Effects of human activities and climate variability on water resources in the Saveh plain, Iran.

    PubMed

    Mohammadi Ghaleni, M; Ebrahimi, K

    2015-02-01

    Quantity and quality distribution of surface water and groundwater are changing under the impacts of both climate variability and human activities. The main goal of this paper is to evaluate the abovementioned impacts on the water resources in the Saveh plain, central Iran. To achieve this aim, spatial and temporal changes of the surface and groundwater quality and quantity have been analyzed, using hydrometric and meteorological data. The nonparametric Mann-Kendall test was used to identify trends and change points in the annual rainfall and runoff for the period of 1946 to 2011. In order to analyze the impacts of the Saveh Dam on runoff, the dam operation year, 1994, was considered as a change point. Mann-Kendall test results show that rainfall time series was divided into two parts, namely, 1966-1989 and 1990-2007, and averages of annual rainfall in five stations increase from 10 to 21 %. Also, runoff time series was divided into two parts, namely, 1946-1995 and 1996-2007 and averages of annual runoff in four stations decrease from 8 to 83 %. Results show that rainfall changes in Shahabasi, Razin, Jalayer, Emamabad, and Ahmadabad stations increased from 9 to 33 % before and after 1994. Nevertheless, runoff decreased from 24 to 81 %. The results indicate that the greatest lack of runoff between stations is at Shahabasi station and one important reason for the severe lack is operation of the Saveh Dam in 1994. Highest groundwater level decline, about 168.67 cm, occurred in 1994 that is the operation year of the Saveh Dam. Trend analysis of surface water quality show that electrical conductivity increased 957.34 μmho/cm before and after 1994. Also, the Wilcox water quality classification method has been reduced from C3-S1 to C4-S2. Average groundwater electrical conductivity (EC) during 1999-2003 and 2004-2009 increased to 89.6 μmho/cm. Also, the groundwater quality indices for agricultural usages are classified in four classes including, C4-S2 16, C4-S1 46, C3-S1 30, and C2-S1 8 % of the total aquifer area. In conclusion, in order to have a sustainable development, the effects of water projects on environment and water resources need to be predicted very carefully.

  4. Prevalence of dental erosion in adolescent competitive swimmers exposed to gas-chlorinated swimming pool water.

    PubMed

    Buczkowska-Radlińska, J; Łagocka, R; Kaczmarek, W; Górski, M; Nowicka, A

    2013-03-01

    The purpose of this study was to analyze the prevalence of dental erosion among competitive swimmers of the local swimming club in Szczecin, Poland, who train in closely monitored gas-chlorinated swimming pool water. The population for this survey consisted of a group of junior competitive swimmers who had been training for an average of 7 years, a group of senior competitive swimmers who had been training for an average of 10 years, and a group of recreational swimmers. All subjects underwent a clinical dental examination and responded to a questionnaire regarding aspects of dental erosion. In pool water samples, the concentration of calcium, magnesium, phosphate, sodium, and potassium ions and pH were determined. The degree of hydroxyapatite saturation was also calculated. Dental erosion was found in more than 26 % of the competitive swimmers and 10 % of the recreational swimmers. The lesions in competitive swimmers were on both the labial and palatal surfaces of the anterior teeth, whereas erosions in recreational swimmers developed exclusively on the palatal surfaces. Although the pH of the pool water was neutral, it was undersaturated with respect to hydroxyapatite. The factors that increase the risk of dental erosion include the duration of swimming and the amount of training. An increased risk of erosion may be related to undersaturation of pool water with hydroxyapatite components. To decrease the risk of erosion in competitive swimmers, the degree of dental hydroxyapatite saturation should be a controlled parameter in pool water.

  5. Groundwater and surface-water interactions near White Bear Lake, Minnesota, through 2011

    USGS Publications Warehouse

    Jones, Perry M.; Trost, Jared J.; Rosenberry, Donald O.; Jackson, P. Ryan; Bode, Jenifer A.; O'Grady, Ryan M.

    2013-01-01

    The U.S. Geological Survey, in cooperation with the White Bear Lake Conservation District, the Minnesota Pollution Control Agency, the Minnesota Department of Natural Resources, and other State, county, municipal, and regional planning agencies, watershed organizations, and private organizations, conducted a study to characterize groundwater and surface-water interactions near White Bear Lake through 2011. During 2010 and 2011, White Bear Lake and other lakes in the northeastern part of the Twin Cities Metropolitan Area were at historically low levels. Previous periods of lower water levels in White Bear Lake correlate with periods of lower precipitation; however, recent urban expansion and increased pumping from the Prairie du Chien-Jordan aquifer have raised the question of whether a decline in precipitation is the primary cause for the recent water-level decline in White Bear Lake. Understanding and quantifying the amount of groundwater inflow to a lake and water discharge from a lake to aquifers is commonly difficult but is important in the management of lake levels. Three methods were used in the study to assess groundwater and surface-water interactions on White Bear Lake: (1) a historical assessment (1978-2011) of levels in White Bear Lake, local groundwater levels, and their relation to historical precipitation and groundwater withdrawals in the White Bear Lake area; (2) recent (2010-11) hydrologic and water-quality data collected from White Bear Lake, other lakes, and wells; and (3) water-balance assessments for White Bear Lake in March and August 2011. An analysis of covariance between average annual lake-level change and annual precipitation indicated the relation between the two variables was significantly different from 2003 through 2011 compared with 1978 through 2002, requiring an average of 4 more inches of precipitation per year to maintain the lake level. This shift in the linear relation between annual lake-level change and annual precipitation indicated the net effect of the non-precipitation terms on the water balance has changed relative to precipitation. The average amount of precipitation required each year to maintain the lake level has increased from 33 inches per year during 1978-2002 to 37 inches per year during 2003-11. The combination of lower precipitation and an increase in groundwater withdrawals can explain the change in the lake-level response to precipitation. Annual and summer groundwater withdrawals from the Prairie du Chien-Jordan aquifer have more than doubled from 1980 through 2010. Results from a regression model constructed with annual lake-level change, annual precipitation minus evaporation, and annual volume of groundwater withdrawn from the Prairie du Chien-Jordan aquifer indicated groundwater withdrawals had a greater effect than precipitation minus evaporation on water levels in the White Bear Lake area for all years since 2003. The recent (2003-11) decline in White Bear Lake reflects the declining water levels in the Prairie du Chien-Jordan aquifer; increases in groundwater withdrawals from this aquifer are a likely cause for declines in groundwater levels and lake levels. Synoptic, static groundwater-level and lake-level measurements in March/April and August 2011 indicated groundwater was potentially flowing into White Bear Lake from glacial aquifers to the northeast and south, and lake water was potentially discharging from White Bear Lake to the underlying glacial and Prairie du Chien-Jordan aquifers and glacial aquifers to the northwest. Groundwater levels in the Prairie du Chien-Jordan aquifer below White Bear Lake are approximately 0 to 19 feet lower than surface-water levels in the lake, indicating groundwater from the aquifer likely does not flow into White Bear Lake, but lake water may discharge into the aquifer. Groundwater levels from March/April to August 2011 declined more than 10 feet in the Prairie du Chien-Jordan aquifer south of White Bear Lake and to the north in Hugo, Minnesota. Water-quality analyses of pore water from nearshore lake-sediment and well-water samples, seepage-meter measurements, and hydraulic-head differences measured in White Bear Lake also indicated groundwater was potentially flowing into White Bear Lake from shallow glacial aquifers to the east and south. Negative temperature anomalies determined in shallow waters in the water-quality survey conducted in White Bear Lake indicated several shallow-water areas where groundwater may be flowing into the lake from glacial aquifers below the lake. Cool lake-sediment temperatures (less than 18 degrees Celsius) were measured in eight areas along the northeast, east, south, and southwest shores of White Bear Lake, indicating potential areas where groundwater may flow into the lake. Stable isotope analyses of well-water, precipitation, and lake-water samples indicated wells downgradient from White Bear Lake screened in the glacial buried aquifer or open to the Prairie du Chien-Jordan aquifer receive a mixture of surface water and groundwater; the largest surface-water contributions are in wells closer to White Bear Lake. A wide range in oxygen-18/oxygen-16 and deuterium/protium ratios was measured in well-water samples, indicating different sources of water are supplying water to the wells. Well water with oxygen-18/oxygen-16 and deuterium/protium ratios that plot close to the meteoric water line consisted mostly of groundwater because deuterium/protium ratios for most groundwater usually are similar to ratios for rainwater and snow, plotting close to meteoric water lines. Well water with oxygen-18/oxygen-16 and deuterium/protium ratios that plot between the meteoric water line and ratios for the surface-water samples from White Bear Lake consists of a mixture of surface water and groundwater; the percentage of each source varies relative to its ratios. White Bear Lake is the likely source of the surface water to the wells that have a mixture of surface water and groundwater because (1) it is the only large, deep lake near these wells; (2) these wells are near and downgradient from White Bear Lake; and (3) these wells obtain their water from relatively deep depths, and White Bear Lake is the deepest lake in that area. The percentages of surface-water contribution to the three wells screened in the glacial buried aquifer receiving surface water were 16, 48, and 83 percent. The percentages of surface-water contribution ranged from 5 to 79 percent for the five wells open to the Prairie du Chien-Jordan aquifer receiving surface water; wells closest to White Bear Lake had the largest percentages of surface-water contribution. Water-balance analysis of White Bear Lake in March and August 2011 indicated a potential discharge of 2.8 and 4.5 inches per month, respectively, over the area of the lake from the lake to local aquifers. Most of the sediments from a 12.4-foot lake core collected at the deepest part of White Bear Lake consisted of silts, sands, and gravels likely slumped from shallower waters, with a very low amount of low-permeability, organic material.

  6. Dissolved-mineral inflow to Great Salt Lake and chemical characteristics of the salt lake brine: Summary for water years 1960, 1961, and 1964

    USGS Publications Warehouse

    Hahl, D.C.

    1968-01-01

    The investigation of dissolved-mineral inflow to Great Salt Lake during the water years 1960, 1961, and 1964 was conducted during conditions of streamflow that were representative of the lowest and the average recorded during the water years 1934-64. The study conducted during the 1960 and 1961 water years was limited to defining surface-water inflow at sites close to the lakeshore, as well as at sites used in the 1960-6 study. From these comparative data, estimates of inflow at the lakeshore were made for the 1960 and 1961 water years. During the 1964 water year, when inflow to the lake was probably representative of the 31-year period, about 800,000 acre-feet of water containing 2,200,000 tons of dissolved solids entered the lake.During the years of average streamflow, about 500,000 acre-feet of water which might be developed for culinary use, passes the lowest sampling sites on the Bear and Weber Rivers. Also, more than 90 percent of the flow near the mouths of the Bear, Weber, and Jordan Rivers would be suitable for irrigation.Sources of inflow could be selected to provide a water supply for a fresh-water lake east of Antelope Island. The supply would range from 300,000 acre-feet of water containing 800 ppm (parts per million) of dissolved solids during periods of low streamflow to 1 million acre-feet containing 500 ppm during periods of average streamflow.

  7. Water resources of Spink County, South Dakota

    USGS Publications Warehouse

    Hamilton, L.J.; Howells, L.W.

    1996-01-01

    Spink County, an agricultural area of about 1,505 square miles, is in the flat to gently rolling James River lowland of east-central South Dakota. The water resources are characterized by the highly variable flows of the James River and its tributaries and by aquifers both in glacial deposits of sand and gravel, and in sandstone in the bedrock. Glacial aquifers underlie about half of the county, and bedrock aquifers underlie most of the county. The James River is an intermittent prairie stream that drains nearly 8,900 square miles north of Spink County and has an average annual discharge of about 124 cubic feet per second where it enters the county. The discharge is augmented by the flow of Snake and Turtle Creeks, each of which has an average annual flow of about 25 to 30 cubic feet per second. Streamflow is unreliable as a water supply because precipitation, which averages 18.5 inches annually, is erratic both in volume and in distribution, and because the average annual potential evapotranspiration rate is 43 inches. The flow of tributaries generally ceases by summer, and zero flows are common in the James River in fall and winter. Aquifers in glacial drift deposits store nearly 3.3 million acre-feet of fresh to slightly saline water at depths of from near land surface to more than 500 feet below land surface beneath an area of about 760 square miles. Yields of properly developed wells in the more productive aquifers exceed 1,000 gallons per minute in some areas. Withdrawals from the aquifers, mostly for irrigation, totaled about 15,000 acre-feet of water in 1990. Water levels in observation wells generally have declined less than 15 feet over several decades of increasing pumpage for irrigation, but locally have declined nearly 30 feet. Water levels generally rose during the wet period of 1983-86. In Spink County, bedrock aquifers store more than 40 million acre-feet of slightly to moderately saline water at depths of from 80 to about 1,300 feet below land surface. Yields of properly developed wells range from 2 to 600 gallons per minute. The artesian head of the heavily used Dakota aquifer has declined about 350 feet in the approximately 100 years since the first artesian wells were drilled in the county, but water levels have stabilized locally as a result of decreases in the discharge of water from the wells. Initial flows of from 4 gallons per minute to as much as 30 gallons per minute of very hard water can be obtained in the southwestern part of the county, where drillers report artesian heads of nearly 100 feet above land surface. The quality of water from aquifers in glacial drift varies greatly, even within an aquifer. Concentrations of dissolved solids in samples ranged from 151 to 9,610 milligrams per liter, and hardness ranged from 84 to 3,700 milligrams per liter. Median concentrations of dissolved solids, sulfate, iron, and manganese in some glacial aquifers are near or exceed Secondary Maximum Contaminant Levels (SMCL's) established by the U.S. Environmental Protection Agency (EPA). Some of the water from aquifers in glacial drift is suitable for irrigation use. Water samples from aquifers in the bedrock contained concentrations of dissolved solids that ranged from 1,410 to 2,670 milligrams per liter (sum of constituents) and hardness that ranged from 10 to 1,400 milligrams per liter; these concentrations generally are largest for aquifers below the Dakota aquifer. Median concentrations of dissolved solids, sulfate, iron, and manganese in Dakota wells either are near or exceed EPA SMCL's. Dissolved solids, sodium, and boron concentrations in water from bedrock aquifers commonly are too large for the water to be suitable for irrigation use.

  8. Compilation of water resources development and hydrologic data of Saipan, Mariana Islands

    USGS Publications Warehouse

    Van der Brug, Otto

    1985-01-01

    Saipan is the largest island of the Northern Mariana Islands, a chain of 14 islands north of Guam. Saipan comprises one third of the land area of the islands. No long-term rainfall record is available at any location, but some rainfall records are for periods up to 16 years, some of which began in 1901. Average annual rainfall for the island is 81 inches, with the southern end receiving about 10 inches less annually than the rest of the island. The amount of rainfall which runs off in northeast Saipan ranges from 23 to 64 percent and averages about 40 percent. Runoff on the rest of the island is from springs or occurs only during heavy rainfall. Surface-water development appears impractical. Ground water is the main source of water for the island and production was almost 4 million gallons per day in 1982. However, chloride concentration in ground water exceeds 1,000 milligrams per liter in many locations. The average chloride concentration of the domestic water stays near the maximum permissible level (600 milligrams per liter). This report summarizes the history of the water-resources development and presents all available hydrologic data, including rainfall records since 1901, streamflow records since 1968, and drilling logs, pumping tests, chemical analyses, and production figures from 180 testholes and wells drilled on Saipan. (USGS)

  9. Hydrology of Park County, Wyoming, exclusive of Yellowstone National Park

    USGS Publications Warehouse

    Lowry, M.E.; Smalley, M.L.; Mora, K.L.; Stockdale, R.G.; Martin, M.W.

    1993-01-01

    The climate of Park County, Wyoming, ranges from desert to alpine tundra. Average annual precipitation ranges from 6 to 40 inches. Ground water is present throughout most of the county, but supplies adequate for stock or domestic use are not readily available in areas of greatest need. The chemical quality of most of the water sampled was of suitable quality for livestock, but most of the water was not suitable for drinking, and the water from bedrock aquifers generally was not suitable for irrigation. Unconsolidated deposits are a principal source of ground water in the county. However, ground water is found in deposits topographically higher than stream level only where surface water has been applied for irrigation; those unconsolidated deposits beneath areas that are not irrigated, such as Polecat Bench, are dry. The conversion of irrigated land to urban development poses problems in some areas because yields of water-supply wells will be adversely affected by reduced recharge. The trend toward urban development also increases the risk of contamination of the ground water by septic tanks, petroleum products, and toxic and hazardous wastes. Perennial streams originate in the mountains and in areas where drainage from irrigated land is adequate to sustain flow. The average annual runoff from streams originating in the mountains is as large as 598 acre-feet per square mile, and the average annual runoff from streams originating in badlands and plains is as low as 14.8 acre-feet per square mile.

  10. Hydraulic analysis of the Schoharie Creek bridge

    USGS Publications Warehouse

    Froehlich, David C.; Trent, Roy E.

    1989-01-01

    Ten people died on April 5, 1987 as a result of the collapse of two spans of a New York State Thruway bridge into the floodwaters of Schoharie Creek. The cause of the bridge failure was determined to be scour of bed material from under the foundations of piers supporting the bridge. To evaluate the hydraulic conditions that produced the scour, a two-dimensional finite element surface-water flow model was constructed. The model was used to obtain a detailed description of water-surface elevations and depth-averaged velocities within a reach that extends from about 4000 ft downstream of the bridge to about 6000 ft upstream of the bridge.

  11. Quantum and classical dynamics of water dissociation on Ni(111): A test of the site-averaging model in dissociative chemisorption of polyatomic molecules

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jiang, Bin; Department of Chemical Physics, University of Science and Technology of China, Hefei 230026; Guo, Hua, E-mail: hguo@unm.edu

    Recently, we reported the first highly accurate nine-dimensional global potential energy surface (PES) for water interacting with a rigid Ni(111) surface, built on a large number of density functional theory points [B. Jiang and H. Guo, Phys. Rev. Lett. 114, 166101 (2015)]. Here, we investigate site-specific reaction probabilities on this PES using a quasi-seven-dimensional quantum dynamical model. It is shown that the site-specific reactivity is largely controlled by the topography of the PES instead of the barrier height alone, underscoring the importance of multidimensional dynamics. In addition, the full-dimensional dissociation probability is estimated by averaging fixed-site reaction probabilities with appropriatemore » weights. To validate this model and gain insights into the dynamics, additional quasi-classical trajectory calculations in both full and reduced dimensions have also been performed and important dynamical factors such as the steering effect are discussed.« less

  12. Influence of atmospheric energy transport on amplification of winter warming in the Arctic

    NASA Astrophysics Data System (ADS)

    Alekseev, Genrikh; Kuzmina, Svetlana; Urazgildeeva, Aleksandra; Bobylev, Leonid

    2016-04-01

    The study was performed on base reanalysis ERA/Interim to discover the link between amplified warming in the high Arctic and the atmospheric transport of heat and water vapor through the 70 ° N. The partitioning transports across the Atlantic and Pacific "gates" is established the link between variations of atmospheric flux through the "gates" and a larger part of the variability of the average surface air temperature, water vapor content and its trends in the winter 1980-2014. Influence of winter (December-February) atmospheric transport across the Atlantic "gate" at the 1000 hPa on variability of average for January-February surface air temperature to north 70° N is estimated correlation coefficient 0.75 and contribution to the temperature trend 40%. These results for the first time denote the leading role of increasing atmospheric transport on the amplification of winter warming in the high Arctic. The investigation is supported with RFBR project 15-05-03512.

  13. [Ammonia volatilization loss of nitrogen fertilizer from rice field and wet deposition of atmospheric nitrogen in rice growing season].

    PubMed

    Su, Chengguo; Yin, Bin; Zhu, Zhaoliang; Shen, Qirong

    2003-11-01

    Plot and field experiments showed that the NH3 volatilization loss from rice field reached its maximum in 1-3 days after N-fertilization, which was affected by the local climate conditions (e.g., sun illumination, temperature, humidity, wind speed, and rainfall), fertilization time, and ammonium concentration in surface water of the rice field. The wet deposition of atmospheric nitrogen was correlated with the application rate of N fertilizer and the rainfall. The amount of nitrogen brought into soil or surface water by the wet deposition in rice growing season reached 7.5 kg.hm-2. The percent of NH4(+)-N in the wet deposition was about 39.8%-73.2%, with an average of 55.5%. There was a significant correlation of total ammonia volatilization loss with the average concentration of NH4(+)-N in wet deposition and total amount of wet deposition in rice growing season.

  14. Geohydrology of the French Creek basin and simulated effects of droughtand ground-water withdrawals, Chester County, Pennsylvania

    USGS Publications Warehouse

    Sloto, Ronald A.

    2004-01-01

    This report describes the results of a study by the U.S. Geological Survey, in cooperation with the Delaware River Basin Commission, to develop a regional ground-water-flow model of the French Creek Basin in Chester County, Pa. The model was used to assist water-resource managers by illustrating the interconnection between ground-water and surface-water systems. The 70.7-mi2 (square mile) French Creek Basin is in the Piedmont Physiographic Province and is underlain by crystalline and sedimentary fractured-rock aquifers. Annual water budgets were calculated for 1969-2001 for the French Creek Basin upstream of streamflow measurement station French Creek near Phoenixville (01472157). Average annual precipitation was 46.28 in. (inches), average annual streamflow was 20.29 in., average annual base flow determined by hydrograph separation was 12.42 in., and estimated average annual ET (evapotranspiration) was 26.10 in. Estimated average annual recharge was 14.32 in. and is equal to 31 percent of the average annual precipitation. Base flow made up an average of 61 percent of streamflow. Ground-water flow in the French Creek Basin was simulated using the finite-difference MODFLOW-96 computer program. The model structure is based on a simplified two-dimensional conceptualization of the ground-water-flow system. The modeled area was extended outside the French Creek Basin to natural hydrologic boundaries; the modeled area includes 40 mi2 of adjacent areas outside the basin. The hydraulic conductivity for each geologic unit was calculated from reported specific-capacity data determined from aquifer tests and was adjusted during model calibration. The model was calibrated for aboveaverage conditions by simulating base-flow and water-level measurements made on May 1, 2001, using a recharge rate of 20 in/yr (inches per year). The model was calibrated for below-average conditions by simulating base-flow and water-level measurements made on September 11 and 17, 2001, using a recharge rate of 6.2 in/yr. Average conditions were simulated by adjusting the recharge rate until simulated streamflow at streamflow-measurement station 01472157 matched the long-term (1968-2001) average base flow of 54.1 cubic feet per second. The recharge rate used for average conditions was 15.7 in/yr. The effect of drought in the French Creek Basin was simulated using a drought year recharge rate of 8 in/yr for 3 months. After 3 months of drought, the simulated streamflow of French Creek at streamflow-measurement station 01472157 decreased 34 percent. The simulations show that after 6 months of average recharge (15.7 in/yr) following drought, streamflow and water levels recovered almost to pre-drought conditions. The effect of increased ground-water withdrawals on stream base flow in the South Branch French Creek Subbasin was simulated under average and drought conditions with pumping rates equal to 50, 75, and 100 percent of the Delaware River Basin Commission Ground Water Protected Area (GWPA) withdrawal limit (1,393 million gallons per year) with all pumped water removed from the basin. For average recharge conditions, the simulated streamflow of South Branch French Creek at the mouth decreased 18, 28, and 37 percent at a withdrawal rate equal to 50, 75, and 100 percent of the GWPA limit, respectively. After 3 months of drought recharge conditions, the simulated streamflow of South Branch French Creek at the mouth decreased 27, 40, and 52 percent at a withdrawal rate equal to 50, 75, and 100 percent of the GWPA limit, respectively. The effect of well location on base flow, water levels, and the sources of water to the well was simulated by locating a hypothetical well pumping 200 gallons per minute in different places in the Beaver Run Subbasin with all pumped water removed from the basin. The smallest reduction in the base flow of Beaver Run was from a well on the drainage divide

  15. A comprehensive analysis of high-magnitude streamflow and trends in the Central Valley, California

    NASA Astrophysics Data System (ADS)

    Kocis, T. N.; Dahlke, H. E.

    2017-12-01

    California's climate is characterized by the largest precipitation and streamflow variability observed within the conterminous US. This, combined with chronic groundwater overdraft of 0.6-3.5 km3 yr-1, creates the need to identify additional surface water sources available for groundwater recharge using methods such as agricultural groundwater banking, aquifer storage and recovery, and spreading basins. High-magnitude streamflow, i.e. flow above the 90th percentile, that exceeds environmental flow requirements and current surface water allocations under California water rights, could be a viable source of surface water for groundwater banking. Here, we present a comprehensive analysis of the magnitude, frequency, duration and timing of high-magnitude streamflow (HMF "metrics") over multiple time periods for 93 stream gauges covering the Sacramento, San Joaquin and Tulare basins in California. In addition, we present trend analyses conducted on the same dataset and all HMF metrics using generalized additive models, the Mann-Kendall trend test, and the Signal to Noise Ratio test. The results of the comprehensive analysis show, in short, that in an average year with HMF approximately 3.2 km3 of high-magnitude flow is exported from the entire Central Valley to the Sacramento-San Joaquin Delta, often at times when environmental flow requirements of the Delta and major rivers are exceeded. High-magnitude flow occurs, on average, during 7 and 4.7 out of 10 years in the Sacramento River and the San Joaquin-Tulare Basins, respectively, from just a few storm events (5-7 1-day peak events) lasting for a total of 25-30 days between November and April. Preliminary trend tests suggest that all HMF metrics show limited change over the last 50 years. As a whole, the results suggest that there is sufficient unmanaged surface water physically available to mitigate long-term groundwater overdraft in the Central Valley.

  16. A novel method for bacterial inactivation using electrosprayed water nanostructures

    NASA Astrophysics Data System (ADS)

    Pyrgiotakis, Georgios; McDevitt, James; Yamauchi, Toshiyuki; Demokritou, Philip

    2012-08-01

    This is a study focusing on the potential to deactivate biological agents (bacteria and endospores) using engineered water nanostructures (EWNS). The EWNS were generated using an electrospray device that collects water by condensing atmospheric water vapor on a Peltier-cooled electrode. A high voltage is applied between the collection electrode and a grounded electrode resulting in aerosolization of the condensed water and a constant generation of EWNS. Gram-negative Serratia marcescens, gram-positive Staphylococcus aureus, and Bacillus atrophaeus endospores were placed on stainless steel coupons and exposed to generated EWNS at multiple time intervals. Upon exposures, the bacteria were recovered and placed on nutrient agar to grow, and the colony forming units were counted. Ozone levels as well as air temperature and relative humidity were monitored during the experiments. Qualitative confirmation of bacterial destruction was also obtained by transmission electron microscopy. In addition, important EWNS aerosol properties such as particle number concentration as a function of size as well as the average surface charge of the generated EWNS were measured using real-time instrumentation. It was shown that the novel electrospray method can generate over time a constant flux of EWNS. EWNS have a peak number concentration of 8,000 particles per cubic centimeter with a modal peak size around 20 nm. The average surface charge of the generated EWNS was found to be 10 ± 2 electrons per particle. In addition, it was shown that the EWNS have the potential to deactivate both bacteria types from surfaces. At the same administrate dose, however, the endospores were not inactivated. This novel method and the unique properties of the generated EWNS could potentially be used to develop an effective, environmentally friendly, and inexpensive method for bacteria inactivation.

  17. Antarctic Mirabilite Mounds as Mars Analogs: The Lewis Cliffs Ice Tongue Revisited

    NASA Technical Reports Server (NTRS)

    Socki, Richard A.; Sun, Tao; Niles, Paul B.; Harvey, Ralph P.; Bish, David L.; Tonui, Eric

    2012-01-01

    It has been proposed, based on geomorphic and geochemical arguments, that subsurface water has played an important role in the history of water on the planet Mars [1]. Subsurface water, if present, could provide a protected and long lived environment for potential life. Discovery of gullies [2] and recurring slopes [3] on Mars suggest the potential for subsurface liquid water or brines. Recent attention has also focused on small (< approx. 1km dia.) mound-like geomorphic features discovered within the mid to high latitudes on the surface of Mars which may be caused by eruptions of subsurface fluids [4, 5]. We have identified massive but highly localized Na-sulfate deposits (mirabilite mounds, Na2SO4 .10H2O) that may be derived from subsurface fluids and may provide insight into the processes associated with subsurface fluids on Mars. The mounds are found on the end moraine of the Lewis Cliffs Ice Tongue (LCIT) [6] in the Transantarctic Mountains, Antarctica, and are potential terrestrial analogs for mounds observed on the martian surface. The following characteristics distinguish LCIT evaporite mounds from other evaporite mounds found in Antarctic coastal environments and/or the McMurdo Dry Valleys: (1) much greater distance from the open ocean (approx.500 km); (2) higher elevation (approx.2200 meters); and (3) colder average annual temperature (average annual temperature = -30 C for LCIT [7] vs. 20 C at sea level in the McMurdo region [8]. Furthermore, the recent detection of subsurface water ice (inferred as debris-covered glacial ice) by the Mars Reconnaissance Orbiter [9] supports the use of an Antarctic glacial environment, particularly with respect to the mirabilite deposits described in this work, as an ideal terrestrial analog for understanding the geochemistry associated with near-surface martian processes. S and O isotopic compositions.

  18. Effects of low-level radioactive-waste disposal on water chemistry in the unsaturated zone at a site near Sheffield, Illinois, 1982-84

    USGS Publications Warehouse

    Peters, C.A.; Striegl, Robert G.; Mills, P.C.; Healy, R.W.

    1992-01-01

    A 1982-84 field study defined the chemistry of water collected from the unsaturated zone at a low-level radioactive-waste disposal site near Sheffield, Bureau County, Illinois. Chemical data were evaluated to determine the principal naturally occurring geochemical reactions in the unsaturated zone and to evaluate waste-induced effects on pore-water chemistry. Samples of precipitation, unsaturated-zone pore water, and saturated-zone water were analyzed for specific conductance, pH, alkalinity, major cations and anions, dissolved organic carbon, gross alpha and beta radiation, and tritium. Little change in concentration of most major constituents in the unsaturated-zone water was observed with respect to depth or distance from disposal trenches. Tritium and dissolved organic carbon concentrations were, however, dependent on proximity to trenches. The primary reactions, both on- site and off-site, were carbonate and clay dissolution, cation exchange, and the oxidation of pyrite. The major difference between on-site and off-site inorganic water chemistry resulted from the removal of the Roxana Silt and the Radnor Till Member of the Glasford Formation from on-site. Off-site, the Roxana Silt contributed substantial quantities of sodium to solution from montmorillonite dissolution and associated cation-exchange reactions. The Radnor Till Member provided exchange surfaces for magnesium. Precipitation at the site had an ionic composition of calcium zinc sulfate and an average pH of 4.6. Within 0.3 meter of the land surface, infiltrating rain water or snowmelt changed to an ionic canposition of calcium sulfate off-site and calcium bicarbonate on-site and had an average pH of 7.9; below that depth, pH averaged 7.5 and the ionic composition generally was calcium magnesium bicarbonate. Alkalinity and specific conductance differed primarily according to composition of geologic materials. Tritium concentrations ranged from 0.2 (detection limit) to 1,380 nanocuries per liter. The methods of constructing, installing, and sampling with lysimeters were evaluated to ensure data reliability. These evaluations indicate that, with respect to most constituents, the samples retrieved from the lysimeters accurately represented pore-water chemistry.

  19. Modeling the dispersal of Levantine Intermediate Water and its role in Mediterranean deep water formation

    NASA Astrophysics Data System (ADS)

    Wu, Peili; Haines, Keith

    1996-03-01

    This paper demonstrates the importance of Levantine Intermediate Water (LIW) in the deep water formation process in the Mediterranean using the modular ocean general circulation model at 0.25° resolution, 19 vertical levels, over the entire Mediterranean with an open Gibraltar strait. LIW formation is strongly prescribed in the Rhodes Gyre region by Haney [1971] relaxation, while in other regions, surface salinity relaxation is much reduced by applying the `mixed' thermohaline surface boundary conditions. Isopycnal diagnostics are used to trace water mass movements, and volume fluxes are monitored at straits. Low viscosity and diffusion are used to permit baroclinic eddies to play a role in water mass dispersal. The overall water budget is measured by an average flux at Gibraltar of 0.8 Sv, of which 0.7 Sv is exchanged with the eastern basin at Sicily. LIW (density around 28.95) spreads rapidly after formation throughout the entire Levantine due to baroclinic eddies. Toward the west, LIW accumulates in the northern and central Ionian, with some entering the Adriatic through Otranto and some mixing southward in eddies and exiting to the western Mediterranean through Sicily. LIW is converted to deep water in the south Adriatic at an average rate of 0.4 Sv. Water exchange through the Otranto strait appears to be buoyancy driven, with a strong bias to the end of winter (March-April), while at Sicily the exchange has a strong symmetric seasonal cycle, with maximum transport of 1.1 Sv in December indicating the effects of wind driving. LIW pathways in the west are complex and variable. In the Tyrrhenian, intermediate water becomes uniform on isopycnal surfaces due to eddy stirring. West of Sardinia, two LIW boundary currents are formed in the Balearic basin; one flows northward up the west coast of Sardinia and Corsica, and one westward along the northern African coast. The northward current is consistent with observations, while the westward current is intermittent for the first 10 years, often breaking up into eddies which enter the basin interior. Some observations of high-salinity waters near the African coast may support this interpretation. LIW retains a subsurface salinity maximum of 38.4-38.5 practical salinity units (psu) when reaching the northwestern Mediterranean, contrasting with surface waters fresher than 38.0 psu. West Mediterranean deep water is formed below 1500 m depth with climatological characteristics, when it is mixed and cooled during winter convection in Lions Gyre.

  20. AirSWOT Measurements of Water Surface Elevations and Hydraulic Gradients over the Yukon Flats, Alaska

    NASA Astrophysics Data System (ADS)

    Pitcher, L. H.; Pavelsky, T.; Smith, L. C.; Moller, D.; Altenau, E. H.; Lion, C.; Bertram, M.; Cooley, S. W.

    2017-12-01

    AirSWOT is an airborne, Ka-band synthetic aperture radar interferometer (InSAR) intended to quantify surface water fluxes by mapping water surface elevations (WSE). AirSWOT will also serve as a calibration/validation tool for the Surface Water and Ocean Topography (SWOT) satellite mission (scheduled for launch in 2021). The hydrology objectives for AirSWOT and SWOT are to measure WSE with accuracies sufficient to estimate hydrologic fluxes in lakes, wetlands and rivers. However, current understanding of the performance of these related though not identical instruments when applied to complex river-lake-wetland fluvial environments remains predominantly theoretical. We present AirSWOT data acquired 15-June-2015 over the Yukon Flats, Alaska, USA, together with in situ field surveys, to assess the accuracy of AirSWOT WSE measurements in lakes and rivers. We use these data to demonstrate that AirSWOT can be used to estimate large-scale hydraulic gradients across wetland complexes. Finally, we present key lessons learned from this AirSWOT analysis for consideration in future campaigns, including: maximizing swath overlap for spatial averaging to minimize uncertainty as well as orienting flight paths parallel to river flow directions to reduce along track aircraft drift for neighboring flight paths. We conclude that spatially dense AirSWOT measurements of river and lake WSEs can improve geospatial understanding of surface water hydrology and fluvial processes.

  1. Monitoring of 45 pesticides in Lebanese surface water using Polar Organic Chemical Integrative Sampler (POCIS)

    NASA Astrophysics Data System (ADS)

    Aisha, Al Ashi; Hneine, Wael; Mokh, Samia; Devier, Marie-Hélène; Budzinski, Hélèn; Jaber, Farouk

    2017-09-01

    The aim of this study is to assess the dissolved concentration of 45 pesticides in the surface waters of the Lebanese Republic using Polar Organic Chemical Integrative Sampler "POCIS". All of the sampling sites are located in the major agricultural land areas in Lebanon. POCIS (n = 3) were deployed at Ibrahim River, Qaraoun Lake and Hasbani River for a duration of 14 days. The total concentration of pesticides ranged from not detected (nd) to 137.66 ng.L-1. Chlorpyrifos, DDE-pp, diazinon and Fenpropathrin were the most abundant compounds. Qaraoun Lake and Hasbani River were found to be more polluted than Ibrahim River, since they receive large amounts of waste water derived from nearby agricultural lands and they had the lowest dilution factor. The aqueous average concentration of the target compounds were estimated using sampling rates obtained from the literature. Comparison between Time Weighed Average concentrations "TWA" using POCIS and spot sampling is presented. Results showed that POCIS TWA concentrations are in agreement with spot sampling concentrations for Ibrahim and Hasbani Rivers. The toxicity of the major detected pesticides on three representative aquatic species ( Daphnia magna, Scenedesmus quadricauda and Oncorhynchus mykiss) is also reported.

  2. Impact on the Columbia River of an outburst of Spirit Lake

    USGS Publications Warehouse

    Sikonia, W.G.

    1985-01-01

    A one-dimensional sediment-transport computer model was used to study the effects of an outburst of Spirit Lake on the Columbia River. According to the model, flood sediment discharge to the Columbia from the Cowlitz would form a blockage to a height of 44 feet above the current streambed of the Columbia River, corresponding to a new streambed elevation of -3 feet, that would impound the waters of the Columbia River. For an average flow of 233,000 cubic feet in that river, water surface elevations would continue to increase for 16 days after the blockage had been formed. The river elevation at the Trojan nuclear power plant, 5 miles upstream of the Cowlitz River, would rise to 32 feet, compared to a critical elevation of 45 feet, above which the plant would be flooded. For comparison, the Columbia River at average flow without the blockage has an elevation at this location of 6 feet. Correspondingly high water surface elevations would occur along the river to Bonneville Dam , with that at Portland, Oregon, for example, rising also to 32 feet, compared to 10 feet without the blockage. (USGS)

  3. Effects of Acids, Bases, and Heteroatoms on Proximal Radial Distribution Functions for Proteins

    PubMed Central

    Nguyen, Bao Linh; Pettitt, B. Montgomery

    2015-01-01

    The proximal distribution of water around proteins is a convenient method of quantifying solvation. We consider the effect of charged and sulfur-containing amino acid side-chain atoms on the proximal radial distribution function (pRDF) of water molecules around proteins using side-chain analogs. The pRDF represents the relative probability of finding any solvent molecule at a distance from the closest or surface perpendicular protein atom. We consider the near-neighbor distribution. Previously, pRDFs were shown to be universal descriptors of the water molecules around C, N, and O atom types across hundreds of globular proteins. Using averaged pRDFs, a solvent density around any globular protein can be reconstructed with controllable relative error. Solvent reconstruction using the additional information from charged amino acid side-chain atom types from both small models and protein averages reveals the effects of surface charge distribution on solvent density and improves the reconstruction errors relative to simulation. Solvent density reconstructions from the small-molecule models are as effective and less computationally demanding than reconstructions from full macromolecular models in reproducing preferred hydration sites and solvent density fluctuations. PMID:26388706

  4. Global lake response to the recent warming hiatus

    NASA Astrophysics Data System (ADS)

    Winslow, Luke A.; Leach, Taylor H.; Rose, Kevin C.

    2018-05-01

    Understanding temporal variability in lake warming rates over decadal scales is important for understanding observed change in aquatic systems. We analyzed a global dataset of lake surface water temperature observations (1985‑2009) to examine how lake temperatures responded to a recent global air temperature warming hiatus (1998‑2012). Prior to the hiatus (1985‑1998), surface water temperatures significantly increased at an average rate of 0.532 °C decade‑1 (±0.214). In contrast, water temperatures did not change significantly during the hiatus (average rate ‑0.087 °C decade‑1 ±0.223). Overall, 83% of lakes in our dataset (129 of 155) had faster warming rates during the pre-hiatus period than during the hiatus period. These results demonstrate that lakes have exhibited decadal-scale variability in warming rates coherent with global air temperatures and represent an independent line of evidence for the recent warming hiatus. Our analyses provide evidence that lakes are sentinels of broader climatological processes and indicate that warming rates based on datasets where a large proportion of observations were collected during the hiatus period may underestimate longer-term trends.

  5. Dipolar response of hydrated proteins

    NASA Astrophysics Data System (ADS)

    Matyushov, Dmitry V.

    2012-02-01

    The paper presents an analytical theory and numerical simulations of the dipolar response of hydrated proteins in solution. We calculate the effective dielectric constant representing the average dipole moment induced at the protein by a uniform external field. The dielectric constant shows a remarkable variation among the proteins, changing from 0.5 for ubiquitin to 640 for cytochrome c. The former value implies a negative dipolar susceptibility, that is a dia-electric dipolar response and negative dielectrophoresis. It means that ubiquitin, carrying an average dipole of ≃240 D, is expected to repel from the region of a stronger electric field. This outcome is the result of a negative cross-correlation between the protein and water dipoles, compensating for the positive variance of the intrinsic protein dipole in the overall dipolar susceptibility. In contrast to the neutral ubiquitin, charged proteins studied here show para-electric dipolar response and positive dielectrophoresis. The study suggests that the dipolar response of proteins in solution is strongly affected by the coupling of the protein surface charge to the hydration water. The protein-water dipolar cross-correlations are long-ranged, extending ˜2 nm from the protein surface into the bulk. A similar correlation length of about 1 nm is seen for the electrostatic potential produced by the hydration water inside the protein. The analysis of numerical simulations suggests that the polarization of the protein-water interface is highly heterogeneous and does not follow the standard dielectric results for cavities carved in dielectrics. The polarization of the water shell gains in importance, relative to the intrinsic protein dipole, at high frequencies, above the protein Debye peak. The induced interfacial dipole can be either parallel or antiparallel to the protein dipole, depending on the distribution of the protein surface charge. As a result, the high-frequency absorption of the protein solution can be either higher or lower than the absorption of water. Both scenarios have been experimentally observed in the THz window of radiation.

  6. Using an Integrated Surface Water - Groundwater Flow Model for Evaluating the Hydrologic Impacts of Historic and Potential Future Dry Periods on Simulated Water Budgets in the Santa Rosa Plain Watershed, Northern California, USA

    NASA Astrophysics Data System (ADS)

    Hevesi, J. A.; Woolfenden, L. R.; Nishikawa, T.

    2014-12-01

    Communities in the Santa Rosa Plain watershed (SRPW), Sonoma County, CA, USA are experiencing increasing demand for limited water resources. Streamflow in the SRPW is runoff dominated; however, groundwater also is an important resource in the basin. The watershed has an area of 262 mi2 that includes natural, agricultural, and urban land uses. To evaluate the hydrologic system, an integrated hydrologic model was developed using the U.S. Geological Survey coupled groundwater and surface-water flow model, GSFLOW. The model uses a daily time step and a grid-based discretization of the SRPW consisting of 16,741 10-acre cells for 8 model layers to simulate all water budget components of the surface and subsurface hydrologic system. Simulation results indicate significant impacts on streamflow and recharge in response to the below average precipitation during the dry periods. The recharge and streamflow distributions simulated for historic dry periods were compared to future dry periods projected from 4 GCM realizations (two different GCMs and two different CO2 forcing scenarios) for the 21st century, with the dry periods defined as 3 consecutive years of below average precipitation. For many of the projected dry periods, the decreases in recharge and streamflow were greater than for the historic dry periods due to a combination of lower precipitation and increases in simulated evapotranspiration for the warmer 21st century projected by the GCM realizations. The greatest impact on streamflow for both historic and projected future dry periods is the diminished baseflow from late spring to early fall, with an increase in the percentage of intermittent and dry stream reaches. The results indicate that the coupled model is a useful tool for water managers to better understand the potential effects of future dry periods on spatially and temporally distributed streamflow and recharge, as well as other components of the water budget.

  7. Dipolar response of hydrated proteins.

    PubMed

    Matyushov, Dmitry V

    2012-02-28

    The paper presents an analytical theory and numerical simulations of the dipolar response of hydrated proteins in solution. We calculate the effective dielectric constant representing the average dipole moment induced at the protein by a uniform external field. The dielectric constant shows a remarkable variation among the proteins, changing from 0.5 for ubiquitin to 640 for cytochrome c. The former value implies a negative dipolar susceptibility, that is a dia-electric dipolar response and negative dielectrophoresis. It means that ubiquitin, carrying an average dipole of ≃240 D, is expected to repel from the region of a stronger electric field. This outcome is the result of a negative cross-correlation between the protein and water dipoles, compensating for the positive variance of the intrinsic protein dipole in the overall dipolar susceptibility. In contrast to the neutral ubiquitin, charged proteins studied here show para-electric dipolar response and positive dielectrophoresis. The study suggests that the dipolar response of proteins in solution is strongly affected by the coupling of the protein surface charge to the hydration water. The protein-water dipolar cross-correlations are long-ranged, extending ~2 nm from the protein surface into the bulk. A similar correlation length of about 1 nm is seen for the electrostatic potential produced by the hydration water inside the protein. The analysis of numerical simulations suggests that the polarization of the protein-water interface is highly heterogeneous and does not follow the standard dielectric results for cavities carved in dielectrics. The polarization of the water shell gains in importance, relative to the intrinsic protein dipole, at high frequencies, above the protein Debye peak. The induced interfacial dipole can be either parallel or antiparallel to the protein dipole, depending on the distribution of the protein surface charge. As a result, the high-frequency absorption of the protein solution can be either higher or lower than the absorption of water. Both scenarios have been experimentally observed in the THz window of radiation.

  8. Simulating the environmental performance of post-harvest management measures to comply with the EU Nitrates Directive.

    PubMed

    De Waele, J; D'Haene, K; Salomez, J; Hofman, G; De Neve, S

    2017-02-01

    Nitrate (NO 3 - ) leaching from farmland remains the predominant source of nitrogen (N) loads to European ground- and surface water. As soil mineral N content at harvest is often high and may increase by mineralisation from crop residues and soil organic matter, it is critical to understand which post-harvest management measures can be taken to restrict the average NO 3 - concentration in ground- and surface waters below the norm of 50 mg l -1 . Nitrate leaching was simulated with the EU-rotate_N model on a silty and a sandy soil following the five main arable crops cultivated in Flanders: cut grassland, silage maize, potatoes, sugar beets and winter wheat, in scenarios of optimum fertilisation with and without post-harvest measures. We compared the average NO 3 - concentration in the leaching water at a depth of 90 cm in these scenarios after dividing it by a factor of 2.1 to include natural attenuation processes occurring during transport towards ground- and surface water. For cut grassland, the average attenuated NO 3 - concentration remained below the norm on both soils. In order to comply with the Nitrates Directive, post-harvest measures seemed to be necessary on sandy soils for the four other crops and on silty soils for silage maize and for potatoes. Successful measures appeared to be the early sowing of winter crops after harvesting winter wheat, the undersowing of grass in silage maize and the removal of sugar beet leaves. Potatoes remained a problematic crop as N uptake by winter crops was insufficient to prevent excessive NO 3 - leaching. For each crop, maximum levels of soil mineral N content at harvest were proposed, both with and without additional measures, which could be used in future nutrient legislation. The approach taken here could be upscaled from the field level to the subcatchment level to see how different crops could be arranged within a subcatchment to permit the cultivation of problem crops without adversely affecting the water quality in such a subcatchment. Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Distribution, Numbers, and Diversity of ESBL-Producing E. coli in the Poultry Farm Environment

    PubMed Central

    Blaak, Hetty; van Hoek, Angela H. A. M.; Hamidjaja, Raditijo A.; van der Plaats, Rozemarijn Q. J.; Kerkhof-de Heer, Lianne; de Roda Husman, Ana Maria; Schets, Franciska M.

    2015-01-01

    This study aimed to discern the contribution of poultry farms to the contamination of the environment with ESBL-producing Escherichia coli and therewith, potentially to the spread of these bacteria to humans and other animals. ESBL-producing E. coli were detected at all investigated laying hen farms (n = 5) and broiler farms (n = 3) in 65% (46/71) and 81% (57/70) of poultry faeces samples, respectively. They were detected in rinse water and run-off water (21/26; 81%), other farm animals (11/14; 79%), dust (21/35; 60%), surface water adjacent to farms (20/35; 57%), soil (48/87; 55%), on flies (11/73; 15%), and in barn air (2/33; 6%). The highest prevalence and concentrations in the outdoor environment were observed in soil of free-range areas at laying hen farms (100% of samples positive, geometric mean concentration 2.4×104 cfu/kg), and surface waters adjacent to broiler farms during, or shortly after, cleaning between production rounds (91% of samples positive, geometric mean concentration 1.9×102 cfu/l). The diversity of ESBL-producing E. coli variants with respect to sequence type, phylogenetic group, ESBL-genotype and antibiotic resistance profile was high, especially on broiler farms where on average 16 different variants were detected, and the average Simpson’s Indices of diversity (SID; 1–D) were 0.93 and 0.94 among flock and environmental isolates respectively. At laying hen farms on average nine variants were detected, with SIDs of 0.63 (flock isolates) and 0.77 (environmental isolates). Sixty percent of environmental isolates were identical to flock isolates at the same farm. The highest proportions of ‘flock variants’ were observed in dust (94%), run-off gullies (82%), and barn air (67%), followed by surface water (57%), soil (56%), flies (50%) and other farm animals (35%).The introduction of ESBL-producing E. coli from poultry farms to the environment may pose a health risk if these bacteria reach places where people may become exposed. PMID:26270644

  10. Availability of ground water in York County, Nebraska; Contributions to the Hydrology of the United States

    USGS Publications Warehouse

    Keech, Charles Franklin; Dreeszen, V.H.; Emery, Philip A.

    1967-01-01

    York County, an area of 575 square miles, is situated on an upland plain in southeast Nebraska. Although tributaries of the Big Blue River have eroded valleys into this plain, much of the original surface is still intact and is characterized by broad shallow undrained depressions. The economy is based almost wholly on agriculture, and corn is the major crop. More than 111,000 acres of cropland was irrigated in 1964 with water pumped from 1,240 wells. The upland plain is underlain to depths of 100-450 feet by unconsolidated deposits of Quaternary age. The upper part of this depositional sequence consists largely of wind-deposited clayey silt, and the lower part consists of stream-deposited sand and gravel. In part of the county, the sequence includes some glacial till also. The unconsolidated Quaternary deposits mantle the eroded surface of marine strata of Cretaceous age. The lower unconsolidated rocks of Quaternary age are saturated and constitute a highly productive aquifer throughout much of the county. Replenishment to this aquifer, derived principally from precipitation, is believed to average about 1.5 inches per year. As the quantity of ground water pumped per year greatly exceeds the average annual quantity of recharge, most of the. water used for irrigation is from storage. Consequently, water levels have been trending downward. A comparison of 1964 water levels in wells with water levels measured in 1953 shows that the water table declined more than 10 feet beneath 42 square miles. The ground water is of the calcium bicarbonate type, and, though hard, is chemically suitable for irrigation use on most soils in the county.

  11. Determination of methyl mercury by aqueous phase Eehylation, followed by gas chromatographic separation with cold vapor atomic fluorescence detection

    USGS Publications Warehouse

    De Wild, John F.; Olsen, Mark L.; Olund, Shane D.

    2002-01-01

    A recent national sampling of streams in the United States revealed low methyl mercury concentrations in surface waters. The resulting median and mean concentrations, calculated from 104 samples, were 0.06 nanograms per liter (ng/L) and 0.15 ng/L, respectively. This level of methyl mercury in surface water in the United States has created a need for analytical techniques capable of detecting sub-nanogram per liter concentrations. In an attempt to create a U.S. Geological Survey approved method, the Wisconsin District Mercury Laboratory has adapted a distillation/ethylation/ gas-phase separation method with cold vapor atomic fluorescence spectroscopy detection for the determination of methyl mercury in filtered and unfiltered waters. This method is described in this report. Based on multiple analyses of surface water and ground-water samples, a method detection limit of 0.04 ng/L was established. Precision and accuracy were evaluated for the method using both spiked and unspiked ground-water and surface-water samples. The percent relative standard deviations ranged from 10.2 to 15.6 for all analyses at all concentrations. Average recoveries obtained for the spiked matrices ranged from 88.8 to 117 percent. The precision and accuracy ranges are within the acceptable method-performance limits. Considering the demonstrated detection limit, precision, and accuracy, the method is an effective means to quantify methyl mercury in waters at or below environmentally relevant concentrations

  12. Towards a better understanding of flood generation and surface water inundation mechanisms using NASA remote sensing data products

    NASA Astrophysics Data System (ADS)

    Lucey, J.; Reager, J. T., II; Lopez, S. R.

    2017-12-01

    Floods annually cause several weather-related fatalities and financial losses. According to NOAA and FEMA, there were 43 deaths and 18 billion dollars paid out in flood insurance policies during 2005. The goal of this work is to improve flood prediction and flood risk assessment by creating a general model of predictability of extreme runoff generation using various NASA products. Using satellite-based flood inundation observations, we can relate surface water formation processes to changes in other hydrological variables, such as precipitation, storage and soil moisture, and understand how runoff generation response to these forcings is modulated by local topography and land cover. Since it is known that a flood event would cause an abnormal increase in surface water, we examine these underlying physical relationships in comparison with the Dartmouth Flood Observatory archive of historic flood events globally. Using ground water storage observations (GRACE), precipitation (TRMM or GPCP), land use (MODIS), elevation (SRTM) and surface inundation levels (SWAMPS), an assessment of geological and climate conditions can be performed for any location around the world. This project utilizes multiple linear regression analysis evaluating the relationship between surface water inundation, total water storage anomalies and precipitation values, grouped by average slope or land use, to determine their statistical relationships and influences on inundation data. This research demonstrates the potential benefits of using global data products for early flood prediction and will improve our understanding of runoff generation processes.

  13. Hydrogeology and analysis of ground-water withdrawal in the Mendenhall-D'Lo area, Simpson County, Mississippi

    USGS Publications Warehouse

    Strom, E.W.; Oakley, W.T.

    1995-01-01

    The cities of Mendenhall and D'Lo, located in Simpson County, rely on ground water for their public supply and industrial needs. Most of the ground water comes from an aquifer of Miocene age. A study began in 1991 to describe the hydrogeology, analyze effects of ground-water withdrawal by making a drawdown map, and estimate the effects increased ground-water withdrawal might have on water levels in the Miocene age aquifer in the Mendenhall-D'Lo area. The most significant withdrawals of ground water in the study area are from 10 wells screened in the lower sand of the Catahoula Formation of Miocene age. Analysis of the effect of withdrawals from the 10 wells was made using the Theis non- equilibrium equation and applying the principle of superposition. Analysis of 1994 conditions was based on the pumpage history and aquifer properties deter- mined for each well. The drawdown surface resulting from the analysis indicates three general cones of depression. One cone is in the northwestern D'Lo area, one in the south-central Mendenhall area, and one about 1-1/2 miles east of Mendenhall. Calculated drawdown ranges from 21 to 47 feet. Potential drawdown-surface maps were made for 10 years and 20 years beyond 1994 using a constant pumpage. The map made for 10 years beyond 1994 indicates an average total increase in drawdown of about 5.3 feet. The map made for 20 years beyond 1994 indicates an average total increase in drawdown of about 7.3 feet.

  14. Nitrification in the euphotic zone as evidenced by nitrate dual isotopic composition: Observations from Monterey Bay, California

    USGS Publications Warehouse

    Wankel, Scott D.; Kendall, C.; Pennington, J.T.; Chavez, F.P.; Paytan, A.

    2007-01-01

    Coupled measurements of nitrate (NO3-), nitrogen (N), and oxygen (O) isotopic composition (??15NNO3 and ??18ONO3) were made in surface waters of Monterey Bay to investigate multiple N cycling processes occurring within surface waters. Profiles collected throughout the year at three sites exhibit a wide range of values, suggesting simultaneous and variable influence of both phytoplankton NO3- assimilation and nitrification within the euphotic zone. Specifically, increases ??18ONO3 were consistently greater than those in ??15NN03. A coupled isotope steady state box model was used to estimate the amount of NO3- supplied by nitrification in surface waters relative to that supplied from deeper water. The model highlights the importance of the branching reaction during ammonium (NH4+) consumption, in which NH4+ either serves as a substrate for regenerated production or for nitrification. Our observations indicate that a previously unrecognized proportion of nitrate-based productivity, on average 15 to 27%, is supported by nitrification in surface waters and should not be considered new production. This work also highlights the need for a better understanding of isotope effects of NH4+ oxidation, NH4+ assimilation, and NO4+ assimilation in marine environments.

  15. Coupling biophysical processes and water rights to simulate spatially distributed water use in an intensively managed hydrologic system

    NASA Astrophysics Data System (ADS)

    Han, Bangshuai; Benner, Shawn G.; Bolte, John P.; Vache, Kellie B.; Flores, Alejandro N.

    2017-07-01

    Humans have significantly altered the redistribution of water in intensively managed hydrologic systems, shifting the spatiotemporal patterns of surface water. Evaluating water availability requires integration of hydrologic processes and associated human influences. In this study, we summarize the development and evaluation of an extensible hydrologic model that explicitly integrates water rights to spatially distribute irrigation waters in a semi-arid agricultural region in the western US, using the Envision integrated modeling platform. The model captures both human and biophysical systems, particularly the diversion of water from the Boise River, which is the main water source that supports irrigated agriculture in this region. In agricultural areas, water demand is estimated as a function of crop type and local environmental conditions. Surface water to meet crop demand is diverted from the stream reaches, constrained by the amount of water available in the stream, the water-rights-appropriated amount, and the priority dates associated with particular places of use. Results, measured by flow rates at gaged stream and canal locations within the study area, suggest that the impacts of irrigation activities on the magnitude and timing of flows through this intensively managed system are well captured. The multi-year averaged diverted water from the Boise River matches observations well, reflecting the appropriation of water according to the water rights database. Because of the spatially explicit implementation of surface water diversion, the model can help diagnose places and times where water resources are likely insufficient to meet agricultural water demands, and inform future water management decisions.

  16. Ground-water, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona, 1996

    USGS Publications Warehouse

    Littin, Gregory R.; Monroe, Stephen A.

    1997-01-01

    The Black Mesa monitoring program is designed to document long-term effects of ground-water pumping from the N aquifer by industrial and municipal users. The N aquifer is the major source of water in the 5,400-square-mile Black Mesa area, and the ground water occurs under confined and unconfined conditions. Monitoring activities include continuous and periodic measurements of (1) ground-water pumpage from the confined and unconfined parts of the aquifer, (2) ground-water levels in the confined and unconfined areas of the aquifer, (3) surface-water discharge, and (4) chemistry of the ground water and surface water. In 1996, ground-water withdrawals for industrial and municipal use totaled about 7,040 acre-feet, which is less than a 1-percent decrease from 1995. Pumpage from the confined part of the aquifer decreased by about 3 percent to 5,390 acre-feet, and pumpage from the unconfined part of the aquifer increased by about 9 percent to 1,650 acre-feet. Water-level declines in the confined area during 1996 were recorded in 11 of 13 wells, and the median change was a decline of about 2.7 feet as opposed to a decline of 1.8 feet for 1995. Water-level declines in the unconfined area were recorded in 11 of 18 wells, and the median change was a decline of 0.5 foot in 1996 as opposed to a decline of 0.1 foot in 1995. The average low-flow discharge at the Moenkopi streamflow-gaging station was 2.3 cubic feet per second in 1996. Streamflow-discharge measurements also were made at Laguna Creek, Dinnebito Wash, and Polacca Wash during 1996. Average low-flow discharge was 2.3 cubic feet per second at Laguna Creek, 0.4 cubic foot per second at Dinnebito Wash, and 0.2 cubic foot per second at Polacca Wash. Discharge was measured at three springs. Discharge from Moenkopi School Spring decreased by about 2 gallons per minute from the measurement in 1995. Discharge from an unnamed spring near Dennehotso decreased by 1.3 gallons per minute from the measurement made in 1995; however, discharge increased slightly at Burro Spring. Regionally, long-term water-chemistry data for wells and springs have remained stable.

  17. Fluvial sediment in the little Arkansas River basin, Kansas

    USGS Publications Warehouse

    Albert, C.D.; Stramel, G.J.

    1966-01-01

    Characteristics and transport of sediment in the Little Arkansas River basin in south-central Kansas were studied to determine if the water from the river could be used as a supplemental source for municipal supply or would provide adequate recharge to aquifers that are sources of municipal and agricultural water supplies. During periods when overland 1low contributed a significant amount to streamflow, the suspended sediment in the Little Arkansas River at Valley Center averaged about 85 percent of clay, about 13 percent of silt, and about 2 percent of sand. The average annual suspended-sediment discharge for the water years 1958, 1959, 1960, and 1961 was about 306,000 tons, and about 80 percent of the load was transported during 133 days of the 1,461-day period. The average daily water discharge of 352 cubic feet per second for the period 1958-61 was more than the long-term (i}9-year) average of 245 cfs; therefore, the average annual sediment load for 1958-61 was probably greater than the average annual load for the same long-term period. Studies of seepage in a part of the channel of Kisiwa Creek indicated that an upstream gravel-pit operation yielded clays which, when deposited in the channel, reduced seepage. A change in plant operation and subsequent runoff that removed the deposited clays restored natural seepage conditions. Experiments by the Wichita Water Department showed that artificial recharge probably cannot be accomplished by using raw turbid water that is injected into wells or by using pits. Recharge by raw turbid water on large permeable areas or by seepage canals may be feasible. Studies of chemical quality of surface water at several sites in the Little Arkansas River basin indicate that Turkey. Creek is a major contributor of chloride and other dissolved solids to the Little Arkansas River and that the dissolved-solids content is probably highest during low-flow periods when suspended-sediment concentration is low. Data collected by the Wichita Water Department indicate that chloride concentrations are diminishing with time at sampled locations. and they receive recharge from rainwater and snowmelt moving through overlying alluvium and from storage in the De Chelly sandstone which encloses the east half of the diatreme. The quality of water from all areas is suitable for domestic use. However, special treatment may be necessary to make the water suitable for pulp processing.

  18. Spatial and Temporal Evolution of Evaporation in a Drying Soil

    NASA Astrophysics Data System (ADS)

    Eichinger, W.; Nichols, J.; Cooper, D.; Prueger, J.

    2005-12-01

    The Los Alamos Scanning Raman Lidar is capable of making spatially resolved estimates of evapotranspiration over an area approaching a square kilometer, with relatively fine (25 meter) spatial resolution, using three dimensional measurements of water vapor concentrations. The method is based upon Monin-Obukhov similarity theory applied to spatially and temporally averaged data. During SMEX02, the instrument was positioned between fields of corn and soybeans. Periodic maps of evapotranspiration rates over the two fields are presented. The maps show the relatively uniform response in the early morning when surface moisture is available and progress through the day as surface water becomes increasingly limited. The change in ET rates between the two crop types is noted as are the spatial patterns as the surface dries non-uniformly.

  19. Assessing recent air-sea freshwater flux changes using a surface temperature-salinity space framework

    NASA Astrophysics Data System (ADS)

    Grist, Jeremy P.; Josey, Simon A.; Zika, Jan D.; Evans, Dafydd Gwyn; Skliris, Nikolaos

    2016-12-01

    A novel assessment of recent changes in air-sea freshwater fluxes has been conducted using a surface temperature-salinity framework applied to four atmospheric reanalyses. Viewed in the T-S space of the ocean surface, the complex pattern of the longitude-latitude space mean global Precipitation minus Evaporation (PME) reduces to three distinct regions. The analysis is conducted for the period 1979-2007 for which there is most evidence for a broadening of the (atmospheric) tropical belt. All four of the reanalyses display an increase in strength of the water cycle. The range of increase is between 2% and 30% over the period analyzed, with an average of 14%. Considering the average across the reanalyses, the water cycle changes are dominated by changes in tropical as opposed to mid-high latitude precipitation. The increases in the water cycle strength, are consistent in sign, but larger than in a 1% greenhouse gas run of the HadGEM3 climate model. In the model a shift of the precipitation/evaporation cells to higher temperatures is more evident, due to the much stronger global warming signal. The observed changes in freshwater fluxes appear to be reflected in changes in the T-S distribution of the Global Ocean. Specifically, across the diverse range of atmospheric reanalyses considered here, there was an acceleration of the hydrological cycle during 1979-2007 which led to a broadening of the ocean's salinity distribution. Finally, although the reanalyses indicate that the warm temperature tropical precipitation dominated water cycle change, ocean observations suggest that ocean processes redistributed the freshening to lower ocean temperatures.

  20. Simulated water sources and effects of pumping on surface and ground water, Sagamore and Monomoy flow lenses, Cape Cod, Massachusetts

    USGS Publications Warehouse

    Walter, Donald A.; Whealan, Ann T.

    2005-01-01

    The sandy sediments underlying Cape Cod, Massachusetts, compose an important aquifer that is the sole source of water for a region undergoing rapid development. Population increases and urbanization on Cape Cod lead to two primary environmental effects that relate directly to water supply: (1) adverse effects of land use on the quality of water in the aquifer and (2) increases in pumping that can adversely affect environmentally sensitive surface waters, such as ponds and streams. These considerations are particularly important on the Sagamore and Monomoy flow lenses, which underlie the largest and most populous areas on Cape Cod. Numerical models of the two flow lenses were developed to simulate ground-water-flow conditions in the aquifer and to (1) delineate areas at the water table contributing water to wells and (2) estimate the effects of pumping and natural changes in recharge on surface waters. About 350 million gallons per day (Mgal/d) of water recharges the aquifer at the water table in this area; most water (about 65 percent) discharges at the coast and most of the remaining water (about 28 percent) discharges into streams. A total of about 24.9 Mgal/d, or about 7 percent, of water in the aquifer is withdrawn for water supply; most pumped water is returned to the hydrologic system as return flow creating a state of near mass balance in the aquifer. Areas at the water table that contribute water directly to production wells total about 17 square miles; some water (about 10 percent) pumped from the wells flows through ponds prior to reaching the wells. Current (2003) steady-state pumping reduces simulated ground-water levels in some areas by more than 4 feet; projected (2020) pumping may reduce water levels by an additional 3 feet or more in these same areas. Current (2003) and future (2020) pumping reduces total streamflow by about 4 and 9 cubic feet per second (ft3/s), corresponding to about 5 percent and 9 percent, respectively, of total streamflow. Natural recharge varies with time, over both monthly and multiyear time scales. Monthly changes in recharge cause pond levels to vary between 1 and 2 feet in an average year; annual changes in recharge, which can be much larger than monthly variations, can cause pond levels to vary by more than 10 feet in some areas over a period of years. Streamflow, which also changes in response to changes in recharge, varies by a factor of two over an average year and can vary more over multiyear periods. On average, monthly pumping ranges from 15.8 Mgal/d in March to 45.3 Mgal/d in August. Pumping and the distribution of return flow can seasonally affect the hydrologic system by lowering ground-water and pond levels and by depleting streamflows, particularly in the summer months. Maximum drawdowns in March and August exceed 3 feet and 6 feet, respectively, for current (2003) pumping. Simulated drawdowns from projected (2020) pumping, relative to water levels representing 2003 pumping conditions, exceed 2 feet in March and 5 feet in August. Current (2003) and future (2020) pumping can decrease pond levels in some areas by more than 3 feet; drawdown generally is largest during the month of August of an average year. Over multiyear periods, seasonal pumping can lower pond levels in some areas by more than 4 feet; the effects of seasonal pumping are largest during periods of reduced recharge. Monthly streamflow depletion varies in individual streams but can exceed 2 ft3/s in some streams. The combined effects of seasonal pumping and drought can reduce pond levels by more than 10 feet below average levels. Water levels in Mary Dunn Pond, which is in an area of large current and projected pumping, are predicted (2020) to decline during drought conditions by about 10.6 feet: about 6.9 feet from lower recharge, about 2.3 feet from current (2003) pumping, and about 1.4 feet from additional future (2020) pumping. The results indicate that pumping generally does not cause substantial

  1. Environmental Assessment: Installation Development at Sheppard Air Force Base, Texas

    DTIC Science & Technology

    2007-05-01

    column, or in topographic depressions. Water is then utilized by plants and is respired, or it moves slowly into groundwater and/or eventually to surface...water bodies where it slowly moves through the hydrologic cycle. Removal of vegetation decreases infiltration into the soil column and thereby...School District JP-4 jet propulsion fuel 4 kts knots Ldn Day- Night Average Sound Level Leq equivalent noise level Lmax maximum sound level lb pound

  2. Geohydrology and simulation of ground-water flow in the Red Clay Creek Basin, Chester County, Pennsylvania, and New Castle County, Delaware

    USGS Publications Warehouse

    Vogel, Karen L.; Reif, Andrew G.

    1993-01-01

    The 54-square-mile Red Clay Creek Basin, located in the lower Delaware River Basin, is underlain primarily by metamorphic rocks that range from Precambrian to Lower Paleozoic in age. Ground water flows through secondary openings in fractured crystalline rock and through primary openings below the water table in the overlying saprolite. Secondary porosity and permeability vary with hydrogeologic unit, topographic setting, and depth. Thirty-nine percent of the water-bearing zones are encountered within 100 feet of the land surface, and 79 percent are within 200 feet. The fractured crystalline rock and overlying saprolite act as a single aquifer under unconfined conditions. The water table is a subdued replica of the land surface. Local ground-water flow systems predominate in the basin, and natural ground-water discharge is to streams, comprising 62 to 71 percent of streamflow. Water budgets for 1988-90 for the 45-square-mile effective drainage area above the Woodale, Del., streamflow-measurement station show that annual precipitation ranged from 43.59 to 59.14 inches and averaged 49.81 inches, annual streamflow ranged from 15.35 to 26.33 inches and averaged 20.24 inches, and annual evapotranspiration ranged from 27.87 to 30.43 inches and averaged 28.98 inches. The crystalline rocks of the Red Clay Creek Basin were simulated two-dimensionally as a single aquifer under unconfined conditions. The model was calibrated for short-term steady-state conditions on November 2, 1990. Recharge was 8.32 inches per year. Values of aquifer hydraulic conductivity in hillside topographic settings ranged from 0.07 to 2.60 feet per day. Values of streambed hydraulic conductivity ranged from 0.08 to 26.0 feet per day. Prior to simulations where ground-water development was increased, the calibrated steady-state model was modified to approximate long-term average conditions in the basin. Base flow of 11.98 inches per year and a ground-water evapotranspiration rate of 2.17 inches per year were simulated by the model. Different combinations of ground-water supply and wastewater-disposal plans were simulated to assess their effects on the stream-aquifer system. Six of the simulations represent an increase in population of 14,283 and water use of 1.07 million gallons per day. One simulation represents an increase in population of 28,566 and water use of 2.14 million gallons per day. Reduction of average base flow is greatest for development plans with wastewater removed from the basin through sewers and is proportional to the amount of water removed from the basin. The development plan that had the least effect on water levels and base flow included on-lot wells and on-lot septic systems. Five organochlorine insecticides--lindane, DDT, dieldrin, heptachlor, and methoxychlor--were detected in ground water. Four organophosphorus insecticides--malathion, parathion, diazinon, and phorate--were detected in ground water. Four volatile organic compounds--benzene, toluene, tetrachloroethylene, and trichloroethylene--were detected in ground water. Phenol was detected at concentrations up to 8 micrograms per liter in water from 50 percent of 14 wells sampled. The concentration of dissolved nitrate in water from 18 percent of wells sampled exceeded 10 milligrams per liter as nitrogen; concentration of nitrate were as high as 19 milligrams per liter. PCB was detected in the bottom material of West Branch Red Clay Creek at Kennet Square at concentrations up to 5,600 micrograms per kilogram.

  3. Warming trend in the western Mediterranean deep water

    NASA Astrophysics Data System (ADS)

    Bethoux, J. P.; Gentili, B.; Raunet, J.; Tailliez, D.

    1990-10-01

    THE western Mediterranean Sea comprises three water masses: a surface layer (from 0 to ~150 m depth), an intermediate layer (~150-400 m) issuing from the eastern basin, and a deep water mass at depths below 400 m. The deep water is homogeneous and has maintained a more or less constant temperature and salinity from the start of the century until recently1. Here we report measurements from the Medatlante cruises of December 1988 and August 1989, which show the deep layer to be 0.12 °C warmer and ~0.03 p.s.u. more saline than in 1959. Taking these data together with those from earlier cruises, we find a trend of continuously increasing temperatures over the past three decades. These deep-water records reflect the averaged evolution of climate conditions at the surface during the winter, when the deep water is formed. Consideration of the heat budget and water flux in the Mediterranean2,3 leads to the possibility that the deep-water temperature trend may be the result of greenhouse-gas-induced local warming.

  4. Residual-Mean Analysis of the Air-Sea Fluxes and Associated Oceanic Meridional Overturning

    DTIC Science & Technology

    2006-12-01

    the adiabatic component of the MOC which is based entirely on the sea surface data . The coordinate system introduced in this study is somewhat...heat capacity of water. The technique utilizes the observational data based on meteorological re- analysis (density flux at the sea surface) and...Figure 8. Annual mean and temporal standard deviation of the zonally-averaged mixed- layer depth. The plotted data are based on Levitus 94 climatology

  5. Water indicators based on SPOT 6 satellite images in irrigated area at the Paracatu River Basin, Brazil

    NASA Astrophysics Data System (ADS)

    Leivas, Janice F.; de C. Teixeira, Antônio Heriberto; Bayma-Silva, Gustavo; Monteiro Garçon, Edlene A.; Ronquim, Carlos Cesar

    2017-10-01

    The Paracatu River is the largest affluent of the São Francisco River, Brazil. The main water use in the Paracatu river basin is irrigation, which occupies an area of 37,150 ha. The objective in this study was to obtain water indicators at irrigated areas using the SAFER (Simple Algorithm For Evapotranspiration Retrieving) and the Penman-Monteith models with images of SPOT 6 satellite (without the thermal band). The parameters obtained are evapotranspiration (ET), albedo (α), biomass (BIO), surface temperature (Tsup) and water productivity (PA) in irrigated areas of Paracatu River Basin. We used 2 satellite images by the sensor SPOT6 (by Astrium Company) with a spatial resolution of 6 m (August 8, 2014 and August 23, 2015) and data from meteorological stations. In irrigated areas, the NDVI reached values higher than 0.76, due the response of vegetation to irrigation. The daily average albedo was 0.18 ± 0.01 and 0.02 ± 0.17 respectively. In the analysis of the surface temperature (Tsup), it can be observed that in the image of 2015, mean values higher than those observed in the image of 2014 (303.03 +/- 1.97 K and 299.34 +/- 3.47 K, respectively). In 2015, due to increased atmospheric evaporative demand, ET reached values higher than those seen in the scene in 2014. The average daily evapotranspiration rate in Paracatu for 2014 scene was of 0.81+/-1.49 mm, with a maximum value of 8.96 mm at the irrigated areas. In image of 2015 the average evapotranspiration (ET) values was 1.87+/-1.27 mm. The results obtained in this study may assist in the monitoring of irrigated agriculture to face a trend of scarcity of water resources and of increasing conflicts over water use as occurs in the Paracatu River Basin.

  6. Salinization and arsenic contamination of surface water in southwest Bangladesh.

    PubMed

    Ayers, John C; George, Gregory; Fry, David; Benneyworth, Laura; Wilson, Carol; Auerbach, Leslie; Roy, Kushal; Karim, Md Rezaul; Akter, Farjana; Goodbred, Steven

    2017-09-11

    To identify the causes of salinization and arsenic contamination of surface water on an embanked island (i.e., polder) in the tidal delta plain of SW Bangladesh we collected and analyzed water samples in the dry (May) and wet (October) seasons in 2012-2013. Samples were collected from rice paddies (wet season), saltwater ponds used for brine shrimp aquaculture (dry season), freshwater ponds and tidal channels (both wet and dry season), and rainwater collectors. Continuous measurements of salinity from March 2012 to February 2013 show that tidal channel water increases from ~0.15 ppt in the wet season up to ~20 ppt in the dry season. On the polder, surface water exceeds the World Health Organization drinking water guideline of 10 μg As/L in 78% of shrimp ponds and 27% of rice paddies, raising concerns that produced shrimp and rice could have unsafe levels of As. Drinking water sources also often have unsafe As levels, with 83% of tubewell and 43% of freshwater pond samples having >10 μg As/L. Water compositions and field observations are consistent with shrimp pond water being sourced from tidal channels during the dry season, rather than the locally saline groundwater from tubewells. Irrigation water for rice paddies is also obtained from the tidal channels, but during the wet season when surface waters are fresh. Salts become concentrated in irrigation water through evaporation, with average salinity increasing from 0.43 ppt in the tidal channel source to 0.91 ppt in the rice paddies. Our observations suggest that the practice of seasonally alternating rice and shrimp farming in a field has a negligible effect on rice paddy water salinity. Also, shrimp ponds do not significantly affect the salinity of adjacent surface water bodies or subjacent groundwater because impermeable shallow surface deposits of silt and clay mostly isolate surface water bodies from each other and from the shallow groundwater aquifer. Bivariate plots of conservative element concentrations show that all surface water types lie on mixing lines between dry season tidal channel water and rainwater, i.e., all are related by varying degrees of salinization. High As concentrations in dry season tidal channel water and shrimp ponds likely result from groundwater exfiltration and upstream irrigation in the dry season. Arsenic is transferred from tidal channels to rice paddies through irrigation. Including groundwater samples from the same area (Ayers et al. in Geochem Trans 17:1-22, 2016), principal components analysis and correlation analysis reveal that salinization explains most variation in surface water compositions, whereas progressive reduction of buried surface water by dissolved organic carbon is responsible for the nonconservative behavior of S, Fe, and As and changes in Eh and alkalinity of groundwater.

  7. On the relation between SMMR 37-GHz polarization difference and the rainfall over Africa and Australia

    NASA Technical Reports Server (NTRS)

    Choudhury, Bhaskar J.; Digirolamo, Nicolo E.

    1994-01-01

    A major difficulty in interpreting coarse resolution satellite data in terms of land surface characteristics is unavailability of spatially and temporally representative ground observations. Under certain conditions rainfall has been found to provide a proxy measure for surface characteristics, and thus a relation between satellite observations and rainfall might provide an indirect approach for relating satellite data to these characteristics. Relationship between rainfall over Africa and Australia and 7-year average (1979-1985) polarization difference (PD) at 37 GHz from scanning multichannel microwave radiometer (SMMR) on board the Nimbus-7 satellite is studied in this paper. Quantitative methods have been used to screen (accept or reject) PD data considering antenna pattern, geolocation uncertainty, water contamination, surface roughness, and adverse effect of drought on the relation between rainfall and surface characteristics. The rainfall data used in the present analysis are climatologic averages and also 1979-1985 averages, and no screening has been applied to this data. The PD data has been screened considering only the location of rainfall stations, without any regard to rainfall amounts. The present analysis confirms a non-linear relation between rainfall and PD published previously.

  8. STUDIES ON THE AMOUNT OF LIGHT EMITTED BY MIXTURES OF CYPRIDINA LUCIFERIN AND LUCIFERASE

    PubMed Central

    Stevens, Kenneth P.

    1927-01-01

    1. A photometric method was devised for measuring the intensities of light emitted per cc. of hiciferin solution and calculating the amount of light emitted per gm. of dried Cypridina powder. A total of 128 runs was made and the data are incorporated in this report. 2. The maximum amount of light emitted from 1 gm. of powder under the experimental conditions was 0.655 lumens. Different samples of powder vary greatly in amount of light production. 3. When the concentration of substrate is doubled, nearly twice as much light is emitted, or an average ratio 2C/C of 1.86. Calculations of total light emissions per gm. of powder at different concentrations indicate that slightly more light is produced from the smaller concentrations. The maximum amount of light was produced by the solutions made with neutral sea water and averaged 0.445 lumens. The least light was obtained from solutions in distilled water saturated with hydrogen. The technique allows too rapid spontaneous oxidation prior to the saturation with hydrogen. The maximum amount of light from such experiments was only 0.077 lumens. Acid sea water solutions subsequently neutralized gave an average maximum of 0.386 lumens per gm. of powder per second. 4. When the concentration of enzyme is doubled, approximately the same amount of light is produced by both concentrations, although the stronger concentrations are slightly less effective than weaker ones. This undoubtedly is due to the colloidal nature of the enzyme and is a function of surface rather than of mass. In dilute solutions greater dispersion probably allows for greater adsorption to the surface of the enzyme. The average maximum amount of light produced in the series of enzyme experiments is of the magnitude 0.56 lumens per gm. of powder. PMID:19872366

  9. A nested observation and model approach to non linear groundwater surface water interactions.

    NASA Astrophysics Data System (ADS)

    van der Velde, Y.; Rozemeijer, J. C.; de Rooij, G. H.

    2009-04-01

    Surface water quality measurements in The Netherlands are scattered in time and space. Therefore, water quality status and its variations and trends are difficult to determine. In order to reach the water quality goals according to the European Water Framework Directive, we need to improve our understanding of the dynamics of surface water quality and the processes that affect it. In heavily drained lowland catchment groundwater influences the discharge towards the surface water network in many complex ways. Especially a strong seasonal contracting and expanding system of discharging ditches and streams affects discharge and solute transport. At a tube drained field site the tube drain flux and the combined flux of all other flow routes toward a stretch of 45 m of surface water have been measured for a year. Also the groundwater levels at various locations in the field and the discharge at two nested catchment scales have been monitored. The unique reaction of individual flow routes on rainfall events at the field site allowed us to separate the discharge at a 4 ha catchment and at a 6 km2 into flow route contributions. The results of this nested experimental setup combined with the results of a distributed hydrological model has lead to the formulation of a process model approach that focuses on the spatial variability of discharge generation driven by temporal and spatial variations in groundwater levels. The main idea of this approach is that discharge is not generated by catchment average storages or groundwater heads, but is mainly generated by points scale extremes i.e. extreme low permeability, extreme high groundwater heads or extreme low surface elevations, all leading to catchment discharge. We focused on describing the spatial extremes in point scale storages and this led to a simple and measurable expression that governs the non-linear groundwater surface water interaction. We will present the analysis of the field site data to demonstrate the potential of nested-scale, high frequency observations. The distributed hydrological model results will be used to show transient catchment scale relations between groundwater levels and discharges. These analyses lead to a simple expression that can describe catchment scale groundwater surface water interactions.

  10. Estimation of sea surface temperature from remote sensing in the 11-13 micron window region

    NASA Technical Reports Server (NTRS)

    Prabhakara, C.; Dalu, G.; Kunde, V. G.

    1974-01-01

    The Nimbus 3 and 4 IRIS spectral data in the 11-13 micron water vapor window region are analyzed to determine the sea surface temperature (SST). The high spectral resolution data of IRIS are averaged over approximately 1 micron wide intervals to simulate channels of a radiometer to measure the SST. Three channels are utilized to measure SST over cloud-free oceans. However, two of these channels are sufficient in routine SST determination. The differential absorption properties of water vapor in the two channels enable one to determine the water vapor absorption correction without detailed knowledge of the vertical profiles of temperature and water vapor. The feasibility of determining the SST is demonstrated globally with Nimbus 3 data where cloud-free areas can be selected with the help of albedo data from the MRIR experiment on board the same satellite.

  11. Hydroecological factors governing surface water flow on a low-gradient floodplain

    USGS Publications Warehouse

    Harvey, J.W.; Schaffranek, R.W.; Noe, G.B.; Larsen, L.G.; Nowacki, D.J.; O'Connor, B.L.

    2009-01-01

    Interrelationships between hydrology and aquatic ecosystems are better understood in streams and rivers compared to their surrounding floodplains. Our goal was to characterize the hydrology of the Everglades ridge and slough floodplain ecosystem, which is valued for the comparatively high biodiversity and connectivity of its parallel-drainage features but which has been degraded over the past century in response to flow reductions associated with flood control. We measured flow velocity, water depth, and wind velocity continuously for 3 years in an area of the Everglades with well-preserved parallel-drainage features (i.e., 200-m wide sloughs interspersed with slightly higher elevation and more densely vegetated ridges). Mean daily flow velocity averaged 0.32 cm s-1 and ranged between 0.02 and 0.79 cm s-1. Highest sustained velocities were associated with flow pulses caused by water releases from upstream hydraulic control structures that increased flow velocity by a factor of 2-3 on the floodplain for weeks at a time. The highest instantaneous measurements of flow velocity were associated with the passage of Hurricane Wilma in 2005 when the inverse barometric pressure effect increased flow velocity up to 5 cm s-1 for several hours. Time-averaged flow velocities were 29% greater in sloughs compared to ridges because of marginally higher vegetative drag in ridges compared to sloughs, which contributed modestly (relative to greater water depth and flow duration in sloughs compared to ridges) to the predominant fraction (86%) of total discharge through the landscape occurring in sloughs. Univariate scaling relationships developed from theory of flow through vegetation, and our field data indicated that flow velocity increases with the square of water surface slope and the fourth power of stem diameter, decreases in direct proportion with increasing frontal area of vegetation, and is unrelated to water depth except for the influence that water depth has in controlling the submergence height of vegetation that varies vertically in its architectural characteristics. In the Everglades the result of interactions among controlling variables was that flow velocity was dominantly controlled by water surface slope variations responding to flow pulses more than spatial variation in vegetation characteristics or fluctuating water depth. Our findings indicate that floodplain managers could, in addition to managing water depth, manipulate the frequency and duration of inflow pulses to manage water surface slope, which would add further control over flow velocities, water residence times, sediment settling, biogeochemical transformations, and other processes that are important to floodplain function. ?? 2009 by American Geophysical Union.

  12. Utilization of surface mine ponds in East Tennessee by breeding amphibians

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Turner, L.J.; Fowler, D.K.

    1981-06-01

    Of 24 ponds examined on Ollis Creek Surface Mine, Campbell County, Tennessee, 21 contained breeding amphibians. Twelve species of amphibians were identified in ponds that ranged from 4.0 to 8.0 in pH. Although ponds with low pH values were used by breeding amphibians, significantly more amphibian species were found in ponds with higher pH values. The average pH of ponds occupied by each amphibian species varied. Spring peepers (Hyla crucifer) occupied ponds with the lowest average pH (5.22) while upland chorus frogs (Pseudacris triseriata feriarum) utilized ponds with the highest average pH (6.33). Findings indicated high biological productivity in surfacemore » mine ponds. Aquatic vegetation was present in 20 of the 24 ponds. Aquatic insects and a diverse wildlife fauna utilized the study ponds. Large mammals (3 species), waterbirds (17 species), and snakes (2 species) were among those species observed. Surface mine ponds were found to supply an important habitat component for a variety of wildlife species and therefore improve the quality of wildlife habitat on the surface mines. In some areas, mine ponds are the only source of surface water available for wildlife use. 23 references, 9 figures, 5 tables.« less

  13. Energy from vascular plant wastewater treatment systems

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wolverton, B.C.; McDonald, R.C.

    1981-04-01

    Water hyacinth (Eichhornia crassipes) duckweed (Spirodela sp. and Lemna sp.), water pennywort (Hydrocotyle ranunculoides), and kudzu (Pueraria lobata) were anaerobically fermented using an anaerobic filter technique that reduced the total digestion time from 90 d to an average of 23 d and produced 0.14 to 0.22 m/sup 3/ CH/sub 4//kg (dry weight) (2.3 to 3.6 ft/sup 3//lb) from mature filters for the 3 aquatic species. Kudzu required an average digestion time of 33 d and produced an average of 0.21 m/sup 3/ CH/sub 4//kg (dry weight) (3.4 ft/sup 3//lb). The anaerobic filter provided a large surface area for the anaerobicmore » bacteria to establish and maintain an optimal balance of facultative, acid-forming, and methane-producing bacteria. Consequently the efficiency of the process was greatly improved over prior batch fermentations.« less

  14. Measurement of the adsorption energy difference between ortho- and para-D2 on an amorphous ice surface.

    PubMed

    Amiaud, L; Momeni, A; Dulieu, F; Fillion, J H; Matar, E; Lemaire, J-L

    2008-02-08

    Molecular hydrogen interaction on water ice surfaces is a major process taking place in interstellar dense clouds. By coupling laser detection and classical thermal desorption spectroscopy, it is possible to study the effect of rotation of D(2) on adsorption on amorphous solid water ice surfaces. The desorption profiles of ortho- and para-D(2) are different. This difference is due to a shift in the adsorption energy distribution of the two lowest rotational states. Molecules in J''=1 rotational state are on average more strongly bound to the ice surface than those in J''=0 rotational state. This energy difference is estimated to be 1.4+/-0.3 meV. This value is in agreement with previous calculation and interpretation. The nonspherical wave function J'' =1 has an interaction with the asymmetric part of the adsorption potential and contributes positively in the binding energy.

  15. Seasonal and Interannual Variation of Currents and Water Properties off the Mid-East Coast of Korea

    NASA Astrophysics Data System (ADS)

    Park, J. H.; Chang, K. I.; Nam, S.

    2016-02-01

    Since 1999, physical parameters such as current, temperature, and salinity off the mid-east coast of Korea have been continuously observed from the long-term buoy station called `East-Sea Real-time Ocean monitoring Buoy (ESROB)'. Applying harmonic analysis to 6-year-long (2007-2012) depth-averaged current data from the ESROB, a mean seasonal cycle of alongshore currents, characterized by poleward current in average and equatorward current in summer, is extracted which accounts for 5.8% of the variance of 40 hours low-pass filtered currents. In spite of the small variance explained, a robust seasonality of summertime equatorward reversal typifies the low-passed alongshore currents along with low-density water. To reveal the dynamics underlying the seasonal variation, each term of linearized, depth-averaged momentum equations is estimated using the data from ESROB, adjacent tide gauge stations, and serial hydrographic stations. The result indicates that the reversal of alongshore pressure gradient is a major driver of the equatorward reversals in summer. The reanalysis wind product (MERRA) and satellite altimeter-derived sea surface height (AVISO) data show correlated features between positive (negative) wind stress curl and sea surface depression (uplift). Quantitative estimates reveal that the wind-stress curl accounts for 42% of alongshore sea level variation. Summertime low-density water originating from the northern coastal region is a footprint of the buoyancy-driven equatorward current. An interannual variation (anomalies from the mean seasonal cycle) of alongshore currents and its possible driving mechanisms will be discussed.

  16. Surface-water characteristics and quality on the Osage Reservation, Osage County, Oklahoma, 1999

    USGS Publications Warehouse

    Abbott, Marvin M.; Tortorelli, Robert L.

    2002-01-01

    Concern about the effects of early oil-industry practices of surface disposal of produced-brine water prompted an investigation of the surface-water quality on the Osage Reservation. About 38,600 oil wells have been drilled on the Osage Reservation since drilling began in 1896. The Osage Reservation comprises three major drainage basins. The Caney River Basin is in the northeast, the Bird Creek Basin is in the southeast, and the Salt Creek Basin in the west. Variations in streamflow on the Osage Reservation during a year primarily result from variations in the quantity and frequency of rainfall, evapotranspiration, and reservoir operations. Most streams do not flow during low rainfall periods in late summer, early fall, and in winter. Percent of mean annual discharge is largest during March through June, averaging 54 to 62 percent and smallest during December, January, July, and August, averaging only 14 to 21 percent. The basin areas of Caney River in the reservation (251 square miles), Salt Creek (273 square miles), and Sand Creek (227 square miles) are about the same and the basin areas of the Bird Creek Basin (418 square miles) and Homily Creek Basin (383 square miles) are similar in area. One hundred forty surface-water sites were sampled once during either February, March or August 1999. The surface-drainage areas, incremental basins, between sample sites along a stream, range in size from 0.26 to 123 square miles with a median of 8.6 square miles. Total number of oil wells upgradient of the samples sites is 31,432 or 80 percent of the total in the reservation. The total number of oil wells in the Caney River Basin in the reservation (2,975 wells), Salt Creek Basin (4,619 wells), and Sand Creek Basin (3,858 wells) are about the same and the total number of oil wells in the Bird Creek Basin (8,858 wells) and Hominy Creek Basin (7,842 wells) are similar. The number of oil wells per square mile in the incremental basins ranges for 0.86 to 154. Surface-water quality monitoring had been conducted previously at two sites included in this study. Dissolved chloride concentrations for the two samples collected during 1999 were equaled or exceeded at both sites by the historical data. There is no statistically significant difference between the distribution of the dissolved chloride concentrations from the surface water and nearby ground-water samples. The surface-water quality samples had significantly lesser concentrations of dissolved solids, sulfate, and nitrite plus nitrate as nitrogen than the ground-water samples. Chloride yield, reported in tons per day per square mile, is the chloride load divided by the basin area upstream of the sample site. The mean of the chloride yields for all the samples was 0.07 ton per day per square mile. Many sample locations where yields were greater than 0.07 ton per day per square mile were areas where dissolved chloride concentrations from surface-water samples were greater than 250 milligrams per liter in an earlier water-quality investigation. An investigation of possible relations between the surface-water quality data and the oil-well construction data for the incremental basins and for 1-mile radial distance upstream in the incremental basins was conducted. The oil-well data also were grouped by the time periods of activity into pre-1930, 1930 to 1970, and post-1970. These groups attempt to account for differences in industry drilling and producing practices associated with various periods. No statistically significant correlations were found between the surface-water quality data and the oil-well construction data.

  17. Uncertainty of water type-specific hazardous copper concentrations derived with biotic ligand models.

    PubMed

    Vijver, Martina G; De Koning, Arjan; Peijnenburg, Willie J G M

    2008-11-01

    One of the aims of the Water Framework Directive is to derive Europe-wide environmental quality standards that are scientifically based and protective of surface waters. Accounting for water type-specific bioavailability corrections presents challenges and opportunities for metals research. In this study, we present generally applicable approaches for tiered risk assessment of chemicals for prospective use. The objective of the present study was to derive water type-specific dissolved copper criteria for Dutch surface waters. The intent was to show the utility of accounting for bioavailability by using biotic ligand models (BLMs) and two different ways of extrapolating these BLMs in order to obtain reliable bioavailability-corrected species sensitivity distributions. Water type-specific criteria estimations were generated for six different water quality conditions. Average hazard concentrations as calculated using the BLMs and the two alternate normalization scenarios varied significantly among the different water types, from 5.6 to 73.6 microg/L. Water types defined as large rivers, sandy springs, and acid ponds were most sensitive for Cu. Streams and brooks had the highest hazard concentrations. The two different options examined for toxicity data normalization did impact the calculated hazard concentrations for each water type.

  18. Biogeochemical Processes Related to Metal Removal and Toxicity Reduction in the H-02 Constructed Wetland, Savannah River Site

    NASA Astrophysics Data System (ADS)

    Burgess, E. A.; Mills, G. L.; Harmon, M.; Samarkin, V.

    2011-12-01

    The H-02 wetland system was designed to treat building process water and storm water runoff from multiple sources associated with the Tritium Facility at the DOE-Savannah River Site, Aiken, SC. The wetland construction included the addition of gypsum (calcium sulfate) to foster a sulfate-reducing bacterial population. Conceptually, the wetland functions as follows: ? Cu and Zn initially bind to both dissolved and particulate organic detritus within the wetland. ? A portion of this organic matter is subsequently deposited into the surface sediments within the wetland. ? The fraction of Cu and Zn that is discharged in the wetland effluent is organically complexed, less bioavailable, and consequently, less toxic. ? The Cu and Zn deposited in the surface sediments are eventually sequestered into insoluble sulfide minerals in the wetland. Development of the H-02 system has been closely monitored; sampling began in August 2007, shortly after its construction. This monitoring has included the measurement of water quality parameters, Cu and Zn concentrations in surface water and sediments, as well as, characterization of the prokaryotic (e.g., bacterial) component of wetland biogeochemical processes. Since the beginning of the study, the mean influent Cu concentration was 31.5±12.1 ppb and the mean effluent concentration was 11.9±7.3 ppb, corresponding to an average Cu removal of 64%. Zn concentrations were more variable, averaging 39.2±13.8 ppb in the influent and 25.7±21.3 ppb in the effluent. Average Zn removal was 52%. The wetland also ameliorated high pH values associated with influent water to values similar to those measured at reference sites. Seasonal variations in DOC concentration corresponded to seasonal variations in Cu and Zn removal efficiency. The concentration of Cu and Zn in the surface layer of the sediments has increased over the lifetime of the wetland and, like removal efficiency, demonstrated seasonal variation. Within its first year, the H-02 wetland showed biomarkers for sulfate-reducing bacteria. Sulfate-reduction and methane-oxidation rates in the sediments were determined using radiotracer techniques. Sulfate-reduction was detected in all depths of sediment cores, even in surface detritus layers. Gas measurements from H-02 sediments demonstrated that methane is available to support a methane oxidizing community, and active methane-oxidation was detected in the sediments and overlying water. Our results demonstrate that the H-02 wetlands are functioning successfully to remove Cu and Zn from influent waters. The continued success and long-term sustainability of the functioning H-02 system is predicated on maintaining in situ biogeochemistry. However, the relative importance of various biogeochemical cycles remains unclear. For example, the Cu and Zn deposited in the sediments are associated with organic detritus at the sediment surface; the extent and rate at which the metals will redistribute to more recalcitrant sulfide mineral phases remain to be determined. Thus, the H-02 wetland system is a valuable resource not only for metal removal at SRS, but also can further enhance the understanding of wetland function within the scientific and regulatory communities.

  19. Delineation of areas contributing recharge to selected public-supply wells in Glacial Valley-Fill and Wetland Settings, Rhode Island

    USGS Publications Warehouse

    Friesz, Paul J.

    2004-01-01

    Areas contributing recharge and sources of water to one proposed and seven present public-supply wells, screened in sand and gravel deposits and clustered in three study areas, were determined on the basis of calibrated, steady-state ground-water-flow models representing average hydrologic conditions. The area contributing recharge to a well is defined as the surface area where water recharges the ground water and then flows toward and discharges to the well. In Cumberland and Lincoln, public-supply well fields on opposite sides of the Blackstone River are in a narrow valley bordered by steep hillslopes. Ground-water-level and river-stage measurements indicated that river water was infiltrating the aquifer and flowing toward the wells during pumping conditions. Simulated areas contributing recharge to the Cumberland well field operating alone for both average (324 gallons per minute) and maximum (1,000 gallons per minute) pumping rates extend on both sides of the river to the lateral model boundaries, which is the contact between the valley and uplands. The area contributing recharge at the average pumping rate is about 0.05 square mile and the well field derives 72 percent of pumped water from upland runoff. At the maximum pumping rate, the area contributing recharge extends farther up and down the valley to 0.12 square mile and the primary source of water to the well field was infiltrated river water (53 percent). Upland areas draining toward the areas contributing recharge encompass 0.58 and 0.66 square mile for the average and maximum rates, respectively. By incorporating the backup Lincoln well-field withdrawals (2,083 gallons per minute) into the model, the area contributing recharge to the Cumberland well field operating at its maximum rate is reduced to 0.08 square mile; part of the simulated area which contributes recharge to the Cumberland well field when it is operating alone contributes instead to the Lincoln well field when both well fields are pumped. The Cumberland well field compensates by increasing the percentage of water it withdraws from the river by 11 percent. The upland area draining toward the Cumberland contributing area is 0.55 square mile. The area contributing recharge to the Lincoln well field is 0.08 square mile and infiltrated river water contributes 88 percent of the total water; the upland area draining toward the contributing area is 0.34 square mile. In North Smithfield, a public-supply well in a valley-fill setting is close to Trout Brook Pond, which is an extension of the Lower Slatersville Reservoir. A comparison of water levels from the pond and underlying sediments indicates that water is not infiltrated from Trout Brook Pond when the supply well is pumped at its maximum rate of 200 gallons per minute. Simulated areas contributing recharge for the maximum pumping rate and for the estimated maximum yield, 500 gallons per minute, of a proposed replacement well extend to the ground-water divides on both sides of Trout Brook Pond. For the 200 gallons-per-minute rate, the area contributing recharge is 0.23 square mile; the well derives almost all of its water from intercepted ground water that normally discharges to surface-water bodies. For the pumping rate of 500 gallons per minute, the area contributing recharge is 0.45 square mile. The increased pumping rate is balanced by additional intercepted ground water and by inducing 25 percent of the total withdrawn water from surface water. In Westerly, one public-supply well is in a watershed where the primarily hydrologic feature is a wetland. Water levels in piezometers surrounding the well site indicated a downward vertical gradient and the potential for water in the wetland to infiltrate the underlying aquifer. The simulated area contributing recharge for the average pumping rate (240 gallons per minute) and for the maximum pumping rate (700 gallons per minute) extends to the surrounding uplands (surficial materials not covered by t

  20. Trends in summer bottom-water temperatures on the northern Gulf of Mexico continental shelf from 1985 to 2015.

    PubMed

    Turner, R Eugene; Rabalais, Nancy N; Justić, Dubravko

    2017-01-01

    We quantified trends in the 1985 to 2015 summer bottom-water temperature on the northern Gulf of Mexico (nGOM) continental shelf for data collected at 88 stations with depths ranging from 3 to 63 m. The analysis was supplemented with monthly data collected from 1963 to 1965 in the same area. The seasonal summer peak in average bottom-water temperature varied concurrently with air temperature, but with a 2- to 5-month lag. The summer bottom-water temperature declined gradually with depth from 30 oC at stations closest to the shore, to 20 oC at the offshore edge of the study area, and increased an average 0.051 oC y-1 between1963 and 2015. The bottom-water warming in summer for all stations was 1.9 times faster compared to the rise in local summer air temperatures, and 6.4 times faster than the concurrent increase in annual global ocean sea surface temperatures. The annual rise in average summer bottom-water temperatures on the subtropical nGOM continental shelf is comparable to the few published temperature trend estimates from colder environments. These recent changes in the heat storage on the nGOM continental shelf will affect oxygen and carbon cycling, spatial distribution of fish and shrimp, and overall species diversity.

Top