Impacts of changing cropping pattern on virtual water flows related to crops transfer: a case study for the Hetao irrigation district, China.

PubMed

Liu, Jing; Wu, Pute; Wang, Yubao; Zhao, Xining; Sun, Shikun; Cao, Xinchun

2014-11-01

Analysis of cropping patterns is a prerequisite for their optimisation, and evaluation of virtual water flows could shed new light on water resources management. This study is intended to explore the effects of cropping pattern changes between 1960 and 2008 on virtual water flows related to crops transfer in the Hetao irrigation district, China. (1) The sown area of crops increased at an average rate of 3.57 × 10(3) ha year(-1) while the proportion of sown grain crops decreased from 92.83% in the 1960s to 50.22% in the 2000s. (2) Virtual water content decreased during the study period while net virtual water exports increased since the 1980s. (3) Assuming that the cropping pattern was constant and was equal to the average 1960s value, accumulated net virtual water export in 1980-2008 would have been 4.76 × 10(9) m(3) greater than that in the actual cropping pattern scenario. Cropping pattern changes in the Hetao irrigation district could not only be seen as resulting from the pursuit for higher economic returns, but also as a feedback response to limited water resources. A systematic framework is still needed for future cropping pattern planning by taking food security, continued agricultural expansion and other constraints into consideration. © 2014 Society of Chemical Industry.

Vapor-phase transport of trichloroethene in an intermediate-scale vadose-zone system: retention processes and tracer-based prediction.

PubMed

Costanza-Robinson, Molly S; Carlson, Tyson D; Brusseau, Mark L

2013-02-01

Gas-phase transport experiments were conducted using a large weighing lysimeter to evaluate retention processes for volatile organic compounds (VOCs) in water-unsaturated (vadose-zone) systems, and to test the utility of gas-phase tracers for predicting VOC retardation. Trichloroethene (TCE) served as a model VOC, while trichlorofluoromethane (CFM) and heptane were used as partitioning tracers to independently characterize retention by water and the air-water interface, respectively. Retardation factors for TCE ranged between 1.9 and 3.5, depending on water content. The results indicate that dissolution into the bulk water was the primary retention mechanism for TCE under all conditions studied, contributing approximately two-thirds of the total measured retention. Accumulation at the air-water interface comprised a significant fraction of the observed retention for all experiments, with an average contribution of approximately 24%. Sorption to the solid phase contributed approximately 10% to retention. Water contents and air-water interfacial areas estimated based on the CFM and heptane tracer data, respectively, were similar to independently measured values. Retardation factors for TCE predicted using the partitioning-tracer data were in reasonable agreement with the measured values. These results suggest that gas-phase tracer tests hold promise for characterizing the retention and transport of VOCs in the vadose-zone. Copyright © 2012 Elsevier B.V. All rights reserved.

Estimating the recharge properties of the deep ocean using noble gases and helium isotopes

NASA Astrophysics Data System (ADS)

Loose, Brice; Jenkins, William J.; Moriarty, Roisin; Brown, Peter; Jullion, Loic; Naveira Garabato, Alberto C.; Torres Valdes, Sinhue; Hoppema, Mario; Ballentine, Chris; Meredith, Michael P.

2016-08-01

The distribution of noble gases and helium isotopes in the dense shelf waters of Antarctica reflects the boundary conditions near the ocean surface: air-sea exchange, sea ice formation, and subsurface ice melt. We use a nonlinear least squares solution to determine the value of the recharge temperature and salinity, as well as the excess air injection and glacial meltwater content throughout the water column and in the precursor to Antarctic Bottom Water. The noble gas-derived recharge temperature and salinity in the Weddell Gyre are -1.95°C and 34.95 psu near 5500 m; these cold, salty recharge values are a result of surface cooling as well as brine rejection during sea ice formation in Antarctic polynyas. In comparison, the global value for deep water recharge temperature is -0.44°C at 5500 m, which is 1.5°C warmer than the southern hemisphere deep water recharge temperature, reflecting a distinct contribution from the north Atlantic. The contrast between northern and southern hemisphere recharge properties highlights the impact of sea ice formation on setting the gas properties in southern sourced deep water. Below 1000 m, glacial meltwater averages 3.5‰ by volume and represents greater than 50% of the excess neon and argon found in the water column. These results indicate glacial melt has a nonnegligible impact on the atmospheric gas content of Antarctic Bottom Water.

Climatic variability of soil water in the American Midwest: Part 2. Spatio-temporal analysis

NASA Astrophysics Data System (ADS)

Georgakakos, Konstantine P.; Bae, Deg-Hyo

1994-11-01

A study of the model-estimated soil water, aggregated over three large drainage basins of the Midwestern USA, is reported. The basin areas are in the range from 2000 km 2 to 3500 km 2, and allow the study of mesoscale (1000-10000 km 2) soil water features. In each case, a conceptual hydrologic model was used to produce upper and lower soil water estimates that are consistent with the atmospheric forcing of daily precipitation, potential evapotranspiration and air temperature, and with the observed daily streamflow divergence over a 40 year period. It is shown that the water contents of the upper and lower soil reach peaks in different months, with the soil column being most saturated in June, when the area is prone to serious flooding. Temporal and spatial features of the variability of model-estimated soil water content are identified. The autocorrelation function of monthly averaged soil water shows that the upper soil water remains persistent for about a season, whereas the persistence of the lower soil water extends to several seasons. The soil water estimates of the three study basins exhibit strong similarities in annual cycles and interannual variability. It is shown that the frequency of significant positive (wet) soil water anomalies that extend over a 2° × 2° region is lower than that of significant negative (dry) ones of the same extent in this region of the USA.

[Correlation Among Soil Organic Carbon, Soil Inorganic Carbon and the Environmental Factors in a Typical Oasis in the Southern Edge of the Tarim Basin].

PubMed

Gong, Lu; Zhu, Mei-ling; Liu, Zeng-yuan; Zhang, Xue-ni; Xie, Li-na

2016-04-15

We analyzed the differentiation among the environmental factors and soil organic/inorganic carbon contents of irrigated desert soil, brown desert soil, saline soil and aeolian sandy soil by classical statistics methods, and studied the correlation between soil carbon contents and the environmental factor by redundancy analysis (RDA) in a typical oasis of Yutian in the southern edge of the Tarim Basin. The results showed that the average contents of soil organic carbon and soil inorganic carbon were 2.51 g · kg⁻¹ and 25.63 g · kg⁻¹ respectively. The soil organic carbon content of the irrigated desert soil was significantly higher than those of brown desert soil, saline soil and aeolian sandy soil, while the inorganic carbon content of aeolian sandy soil was significantly higher than those of other soil types. The soil moisture and nutrient content were the highest in the irrigated desert soil and the lowest in the aeolian sandy sail. All soil types had high degree of salinization except the irrigated desert soil. The RDA results showed that the impacts of environmental factors on soil carbon contents ranked in order of importance were total nitrogen > available phosphorus > soil moisture > ground water depth > available potassium > pH > total salt. The soil carbon contents correlated extremely significantly with total nitrogen, available phosphorus, soil moisture and ground water depth (P < 0.01), and it correlated significantly with available potassium and pH (P < 0.05). There was no significant correlation between soil carbon contents and other environmental factors (P > 0.05).

Soil-water movement under natural-site and waste-site conditions: A multiple-year field study in the Mojave Desert, Nevada

USGS Publications Warehouse

Andraski, Brian J.

1997-01-01

Soil-water movement under natural-site and simulated waste-site conditions were compared by monitoring four experimental sites in the Mojave Desert, Nevada, during a 5-year period: one vegetated soil profile, one soil profile where vegetation was removed, and two nonvegetated test trenches. Precipitation ranged from 14 to 162 mm/yr. Temporal changes in water content measured by neutron probe were limited to the upper 0.5–1 m; values ranged from 0.01 to 0.19 m3/m3. Water potential and temperature were measured by thermocouple psychrometers; 77% remained operable for ≥4.5 years. For vegetated soil, precipitation that accumulated in the upper 0.75 m of soil was removed by evapotranspiration: water potentials decreased seasonally by 4 to >8 MPa. During 2 years with below-average precipitation, water potentials below the app arent root zone decreased by 2.3 (1.2-m depth) to 0.4 MPa (5-m depth), and the gradients became predominantly upward. Water potentials then rebounded during 2 years with near- and above-average precipitation, and seasonally variant water potential gradients were reestablished above the 4.2-m depth. Under nonvegetated waste-site conditions, data indicated the long-term accumulation and shallow, but continued, penetration of precipitation: water potentials showed moisture penetration to depths of 0.75−1.85 m. The method of simulated-waste drum placement (stacked versus random) and the associated differences in subsidence showed no measurable influence on the water balance of the trenches: subsidence totaled ≤13 mm during the study. Water potentials below the trenches and below the 2-m depth for the nonvegetated soil remained low (≈−5.5 to −7.5 MPa) and indicated the persistence of typically upward driving forces for isothermal water flow. Water fluxes estimated from water potential and temperature data suggested that isothermal liquid, isothermal vapor, and nonisothermal vapor flow need to be considered in the conceptualization of unsaturated flow at the field sites. Below the depth of temporal water content change, the estimated liquid fluxes ranged from 10−10 to 10−15 cm/s, isothermal vapor fluxes ranged from 10−10 to 10−13 cm/s, and the nonisothermal vapor fluxes ranged from 10−8 to 10−10cm/s.

Comparison of Nimbus-7 SMMR and GOES-1 VISSR Atmospheric Liquid Water Content.

NASA Astrophysics Data System (ADS)

Lojou, Jean-Yves; Frouin, Robert; Bernard, René

1991-02-01

Vertically integrated atmospheric liquid water content derived from Nimbus-7 Scanning Multichannel Microwave Radiometer (SMMR) brightness temperatures and from GOES-1 Visible and Infrared Spin-Scan Radiometer (VISSR) radiances in the visible are compared over the Indian Ocean during MONEX (monsoon experiment). In the retrieval procedure, Wilheit and Chang' algorithm and Stephens' parameterization schemes are applied to the SMMR and VISSR data, respectively. The results indicate that in the 0-100 mg cm2 range of liquid water content considered, the correlation coefficient between the two types of estimates is 0.83 (0.81- 0.85 at the 99 percent confidence level). The Wilheit and Chang algorithm, however, yields values lower than those obtained with Stephens's schemes by 24.5 mg cm2 on the average, and occasionally the SMMR-based values are negative. Alternative algorithms are proposed for use with SMMR data, which eliminate the bias, augment the correlation coefficient, and reduce the rms difference. These algorithms include using the Witheit and Chang formula with modified coefficients (multilinear regression), the Wilheit and Chang formula with the same coefficients but different equivalent atmospheric temperatures for each channel (temperature bias adjustment), and a second-order polynomial in brightness temperatures at 18, 21, and 37 GHz (polynomial development). When applied to a dataset excluded from the regressionn dataset, the multilinear regression algorithm provides the best results, namely a 0.91 correlation coefficient, a 5.2 mg cm2 (residual) difference, and a 2.9 mg cm2 bias. Simply shifting the liquid water content predicted by the Wilheit and Chang algorithm does not yield as good comparison statistics, indicating that the occasional negative values are not due only to a bias. The more accurate SMMR-derived liquid water content allows one to better evaluate cloud transmittance in the solar spectrum, at least in the area and during the period analyzed. Combining this cloud transmittance with a clear sky model would provide ocean surface insulation estimates from SMMR data alone.

7 CFR 51.2548 - Average moisture content determination.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 7 Agriculture 2 2010-01-01 2010-01-01 false Average moisture content determination. 51.2548... moisture content determination. (a) Determining average moisture content of the lot is not a requirement of... connection with grade analysis or as a separate determination. (b) Nuts shall be obtained from a randomly...

Estimating the path-average rainwater content and updraft speed along a microwave link

NASA Technical Reports Server (NTRS)

Jameson, Arthur R.

1993-01-01

There is a scarcity of methods for accurately estimating the mass of rainwater rather than its flux. A recently proposed technique uses the difference between the observed rates of attenuation A with increasing distance at 38 and 25 GHz, A(38-25), to estimate the rainwater content W. Unfortunately, this approach is still somewhat sensitive to the form of the drop-size distribution. An alternative proposed here uses the ratio A38/A25 to estimate the mass-weighted average raindrop size Dm. Rainwater content is then estimated from measurements of polarization propagation differential phase shift (Phi-DP) divided by (1-R), where R is the mass-weighted mean axis ratio of the raindrops computed from Dm. This paper investigates these two water-content estimators using results from a numerical simulation of observations along a microwave link. From these calculations, it appears that the combination (R, Phi-DP) produces more accurate estimates of W than does A38-25. In addition, by combining microwave estimates of W and the rate of rainfall in still air with the mass-weighted mean terminal fall speed derived using A38/A25, it is possible to detect the potential influence of vertical air motion on the raingage-microwave rainfall comparisons.

A cost-effective and customizable automated irrigation system for precise high-throughput phenotyping in drought stress studies

PubMed Central

2018-01-01

The development of high-yielding crops with drought tolerance is necessary to increase food, feed, fiber and fuel production. Methods that create similar environmental conditions for a large number of genotypes are essential to investigate plant responses to drought in gene discovery studies. Modern facilities that control water availability for each plant remain cost-prohibited to some sections of the research community. We present an alternative cost-effective automated irrigation system scalable for a high-throughput and controlled dry-down treatment of plants. This system was tested in sorghum using two experiments. First, four genotypes were subjected to ten days of dry-down to achieve three final Volumetric Water Content (VWC) levels: drought (0.10 and 0.20 m3 m-3) and control (0.30 m3 m-3). The final average VWC was 0.11, 0.22, and 0.31 m3 m-3, respectively, and significant differences in biomass accumulation were observed between control and drought treatments. Second, 42 diverse sorghum genotypes were subjected to a seven-day dry-down treatment for a final drought stress of 0.15 m3 m-3 VWC. The final average VWC was 0.17 m3 m-3, and plants presented significant differences in photosynthetic rate during the drought period. These results demonstrate that cost-effective automation systems can successfully control substrate water content for each plant, to accurately compare their phenotypic responses to drought, and be scaled up for high-throughput phenotyping studies. PMID:29870560

Analysis of heavy metals (Pb and Zn) concentration in sediment of Blanakan fish ponds, Subang, West Java

NASA Astrophysics Data System (ADS)

Wiriawan, A.; Takarina, N. D.; Pin, T. G.

2017-07-01

Blanakan fish ponds receive water resource from Kali Malang and Blanakan rivers. Industrial and domestic activities along the river can cause pollution, especially heavy metals. Zinc (Zn) is an essential element that needed by an organism, while Lead (Pb) is a nonessential element that is not needed. Discharge of waste water from industries and anthropogenic activities continuously not only pollute the water but also the sediment and biota live on it. This research was aimed to know the heavy metals content in the sediment of Blanakan fish ponds. Sediment samples were taken on July and August 2016 at three locations. Heavy metals were analyzed using Atomic Absorption Spectrophotometry (AAS) Shimadzu 6300. The result of Lead (Pb) measurement showed that Fish Pond 1 had higher average concentration compared Fish Pond 2 and Fish Pond 3 which was 0.55 ppm. Standard for Lead (Pb) in sediment according to Ontario Sediment Standards (2008) is 31 ppm. Based on Zinc (Zn) measurement, it was known that average of Zinc (Zn) concentration also higher on Fish Pond 1 compared to Fish Pond 2 and 3 which was 1.93 ppm. According to Ontario Sediment Standards (2008), a standard for Zinc (Zn) in sediment is 120 ppm. This indicated that heavy metals in the sediment of fish ponds were below standards. Statistical analysis using t-test showed that there was no significant difference of heavy metals content among fish ponds.

A cost-effective and customizable automated irrigation system for precise high-throughput phenotyping in drought stress studies.

PubMed

Ortiz, Diego; Litvin, Alexander G; Salas Fernandez, Maria G

2018-01-01

The development of high-yielding crops with drought tolerance is necessary to increase food, feed, fiber and fuel production. Methods that create similar environmental conditions for a large number of genotypes are essential to investigate plant responses to drought in gene discovery studies. Modern facilities that control water availability for each plant remain cost-prohibited to some sections of the research community. We present an alternative cost-effective automated irrigation system scalable for a high-throughput and controlled dry-down treatment of plants. This system was tested in sorghum using two experiments. First, four genotypes were subjected to ten days of dry-down to achieve three final Volumetric Water Content (VWC) levels: drought (0.10 and 0.20 m3 m-3) and control (0.30 m3 m-3). The final average VWC was 0.11, 0.22, and 0.31 m3 m-3, respectively, and significant differences in biomass accumulation were observed between control and drought treatments. Second, 42 diverse sorghum genotypes were subjected to a seven-day dry-down treatment for a final drought stress of 0.15 m3 m-3 VWC. The final average VWC was 0.17 m3 m-3, and plants presented significant differences in photosynthetic rate during the drought period. These results demonstrate that cost-effective automation systems can successfully control substrate water content for each plant, to accurately compare their phenotypic responses to drought, and be scaled up for high-throughput phenotyping studies.

An Attempt of Nondestructive Imaging of Sugar Distribution inside a Fruit Using Microwaves

NASA Astrophysics Data System (ADS)

Watanabe, Masakazu; Miyakawa, Michio

Chirp Pulse Microwave Computed Tomography (CP-MCT) that was originally developed for noninvasive imaging of a human body was applied to visualize sugar distribution inside a fruit. It can visualize not only permittivity distribution itself of a fruit but also various physical- or chemical-quantities relating to the permittivity value. Almost all fruits are dielectric materials containing much water, sugar, acids and so on. But for water, the principal ingredient of a fruit is sugar. Most of the fruits contain sugar from 8% to 22% by weight at the harvest time. Therefore sugar content distribution should be measured by CP-MCT nondestructively. By using apples and Japanese pears, feasibility of sugar distribution imaging has been evaluated by comparing the gray level of CP-MCT and sugar content of the cross section. The averaged correlation coefficients of the apple and pear are 0.793 and 0.681.

House dust in seven Danish offices

NASA Astrophysics Data System (ADS)

Mølhave, L.; Schneider, T.; Kjærgaard, S. K.; Larsen, L.; Norn, S.; Jørgensen, O.

Floor dust from Danish offices was collected and analyzed. The dust was to be used in an exposure experiment. The dust was analyzed to show the composition of the dust which can be a source of airborne dust indoors. About 11 kg of dust from vacuum cleaner bags from seven Danish office buildings with about 1047 occupants (12 751 m 2) was processed according to a standardized procedure yielding 5.5 kg of processed bulk dust. The bulk dust contained 130.000-160.000 CFU g -1 microorganisms and 71.000-90.000 CFU g -1 microfungi. The content of culturable microfungi was 65-123 CFU 30 g -1 dust. The content of endotoxins ranged from 5.06-7.24 EU g -1 (1.45 ng g -1 to 1.01 ng g -1). Allergens (ng g -1) were from 147-159 (Mite), 395-746 (dog) and 103-330 (cat). The macro molecular organic compounds (the MOD-content) varied from 7.8-9.8 mg g -1. The threshold of release of histamine from basophil leukocytes provoked by the bulk dust was between 0.3 and 1.0 mg ml -1. The water content was 2% (WGT) and the organic fraction 33%. 6.5-5.9% (dry) was water soluble. The fiber content was less than 0.2-1.5% (WGT) and the desorbable VOCs was 176-319 μg g -1. Most of the VOC were aldehydes. However, softeners for plastic (DBP and DEHP) were present. The chemical composition includes human and animal skin fragments, paper fibers, glass wool, wood and textilefibers and inorganic and metal particles. The sizes ranged from 0.001-1 mm and the average specific density was 1.0 g m -3. The bulk dust was resuspended and injected into an exposure chamber. The airborne dust was sampled and analyzed to illustrate the exposures that can result from sedimented dirt and dust. The airborne dust resulting from the bulk dust reached concentrations ranging from 0.26-0.75 mg m -3 in average contained 300-170 CFU m -3. The organic fraction was from 55-70% and the water content about 2.5% (WGT). The content of the dust was compared to the similar results reported in the literature and its toxic potency is estimated to be relatively low. The storage of the bulk dust during the experiment had little effect on the specific biological and chemical composition.

Pore-scale investigation on the response of heterotrophic respiration to moisture conditions in heterogeneous soils

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yan, Zhifeng; Liu, Chongxuan; Todd-Brown, Katherine E.

The relationship between microbial respiration rate and soil moisture content is an important property for understanding and predicting soil organic carbon degradation, CO 2 production and emission, and their subsequent effects on climate change. This paper reports a pore-scale modeling study to investigate the response of heterotrophic respiration to moisture conditions in soils and to evaluate various factors that affect this response. X-ray computed tomography was used to derive soil pore structures, which were then used for pore-scale model investigation. The pore-scale results were then averaged to calculate the effective respiration rates as a function of water content in soils.more » The calculated effective respiration rate first increases and then decreases with increasing soil water content, showing a maximum respiration rate at water saturation degree of 0.75 that is consistent with field and laboratory observations. The relationship between the respiration rate and moisture content is affected by various factors, including pore-scale organic carbon bioavailability, the rate of oxygen delivery, soil pore structure and physical heterogeneity, soil clay content, and microbial drought resistivity. Simulations also illustrates that a larger fraction of CO 2 produced from microbial respiration can be accumulated inside soil cores under higher saturation conditions, implying that CO 2 flux measured on the top of soil cores may underestimate or overestimate true soil respiration rates under dynamic moisture conditions. Overall, this study provides mechanistic insights into the soil respiration response to the change in moisture conditions, and reveals a complex relationship between heterotrophic microbial respiration rate and moisture content in soils that is affected by various hydrological, geochemical, and biophysical factors.« less

Reduction of heat insulation upon soaking of the insulation layer

NASA Astrophysics Data System (ADS)

Achtliger, J.

1983-09-01

Improved thermal protection of hollow masonry by introduction of a core insulation between the inner and outer shell is discussed. The thermal conductivity of insulation materials was determined in dry state and after soaking by water with different volume-related moisture contents. The interpolated thermal conductivity values from three measured values at 10 C average temperature are presented as a function of the pertinent moisture content. Fills of expanded polystyrene, perlite and granulated mineral fibers, insulating boards made of mineral fibers and in situ cellular plastics produced from urea-formaldehyde resin were investigated. Test results show a confirmation of thermal conductivity values for insulating materials in hollow masonry.

Characterizing roots and water uptake in a ground cover rice production system.

PubMed

Li, Sen; Zuo, Qiang; Wang, Xiaoyu; Ma, Wenwen; Jin, Xinxin; Shi, Jianchu; Ben-Gal, Alon

2017-01-01

Water-saving ground cover rice production systems (GCRPS) are gaining popularity in many parts of the world. We aimed to describe the characteristics of root growth, morphology, distribution, and water uptake for a GCRPS. A traditional paddy rice production system (TPRPS) was compared with GCRPS in greenhouse and field experiments. In the greenhouse, GCRPS where root zone average soil water content was kept near saturation (GCRPSsat), field capacity (GCRPSfwc) and 80% field capacity (GCRPS80%), were evaluated. In a two-year field experiment, GCRPSsat and GCRPS80% were applied. Similar results were found in greenhouse and field experiments. Before mid-tillering the upper soil temperature was higher for GCRPS, leading to enhanced root dry weight, length, surface area, specific root length, and smaller diameter of roots but lower water uptake rate per root length compared to TPRPS. In subsequent growth stages, the reduced soil water content under GCRPS caused that the preponderance of root growth under GCRPSsat disappeared in comparison to TPRPS. Under other GCRPS treatments (GCRPSfwc and GCRPS80%), significant limitation on root growth, bigger root diameter and higher water uptake rate per root length were found. Discrepancies in soil water and temperature between TPRPS and GCRPS caused adjustments to root growth, morphology, distribution and function. Even though drought stress was inevitable after mid-tillering under GCRPS, especially GCRPS80%, similar or even enhanced root water uptake capacity in comparison to TPRPS might promote allocation of photosynthetic products to shoots and increase water productivity.

Evidence for direct water absorption by shallow-rooted desert plants in desert-oasis ecotone, Northwest China

NASA Astrophysics Data System (ADS)

Fang, Jing

2014-05-01

Besides the absorption by roots from the soil substrate, it has long been known that plants exhibit alternative water-absorption strategies, particularly in drought-prone environments. For many tropical epiphytic orchids, air moisture can be absorbed directly by aerial roots. Some conifers are also found to utilize air moisture by foliar absorption during the summer fog season. However, few studies have been carried out on the atmospheric water vapor absorption by shallow-rooted desert plants. We conducted experiments in desert-oasis ecotone and investigated the effects of dew absorbed by three kinds of shallow-rooted seedlings on net photosynthesis rate, as well as on other water relations variables. Three kinds of typical shallow-rooted desert species (Bassia dasyphylla, Salsola collina and Corispermum declinatum) have been chosen and potted. Each species were subjected to contrasting watering regimes (normal and deficient) and different air moisture conditions (having dew and having no dew) for 10 weeks. Net photosynthesis rate was measured on six occasions during the study. Other water relations variables (midday shoot water potential, relative water content, stomatal conductance) were also measured. Under the dew conditions, average net photosynthesis rate, shoot water potential, leaf relative water content and stomatal conductance increased, with greater responses observed for plants subjected to a deficient watering regime than for well-watered plants. These results indicated dew occurred in arid region could be utilized through foliar absorption by some shallow-rooted plants, and for the shallow-rooted plants, the presence of dew could significantly relieve the deficit of water in water-stressed regime.

Investigation of radon level in air and tap water of workplaces at Thailand Institute of Nuclear Technology, Thailand

NASA Astrophysics Data System (ADS)

Sola, P.; Youngchuay, U.; Kongsri, S.; Kongtana, A.

2017-06-01

Thailand Institute of Nuclear Technology (TINT) has continuously monitored radiation exposure and radionuclide in workplaces specifically radon gas to estimate effective dose for workers. Radon exposure is the second leading cause of lung cancer in the world. In this study, radon in air and tap water at building no. 3, 7, 8, 9 and 18 on Ongkharak site of TINT have been measured for 5 years from 2012 to 2016. Radon level in air and tap water were investigated on 83 stations (workplaces) and 54 samples, respectively. Radon concentrations in air and tap water were measured by using the pulsed ionization chamber (ATMOS 12 DPX). Indoor radon concentrations in air were in the range of 12-138 Bq.m-3 with an average value of 30.13±17.05 Bq.m-3. Radon concentrations in tap water were in the range of 0.10 to 2.89 Bq.l-1 with an average value of 0.51±0.55 Bq.l-1. The results of radon concentrations at TINT were below the US Environmental Protection Agency (US EPA) safety limit of 148 Bq.m-3 and 150 Bq.l-1, for, air and tap water, respectively. The average effective dose for TINT’s workers due to indoor radon exposure was approximately 0.20±0.11 mSv.y-1. The value is 100 times less than the annual dose limit for limit occupational radiation worker defined by the International Commission on Radiological Protection (ICRP). As a result, the TINT’s workplaces are radiologically safe from radon content in air and tap water.

Applying multi-criteria analysis for preliminary assessment of the properties of alginate immobilized Myriophyllum spicatum in lake water samples.

PubMed

Milojković, Jelena V; Popović-Djordjević, Jelena B; Pezo, Lato L; Brčeski, Ilija D; Kostić, Aleksandar Ž; Milošević, Vladan D; Stojanović, Mirjana D

2018-05-11

The preliminary assessment of the properties of alginate immobilized aquatic weed Myriophyllum spicatum beads-MsAlg in a multi-element system of nine Serbian lakes water samples was done. Herein, the results obtained in the biosorption experiment with MsAlg contents of twenty-two elements analysed by inductively coupled plasma-optical emission spectrometry, biosorption capacity, element removal efficiency, total hardness (TH) and quality index of water (WQI) are presented. Scanning electron microscopy with energy dispersive X-ray spectroscopy was used for the characterization of M. spicatum and its beads. The study showed that aluminium, magnesium and strontium were adsorbed by MsAlg in the water samples from all examined lakes; barium and iron in the water samples from six lakes. The overall average efficiency of MsAlg in biosorption of elements was in the following order: Al > Ba > Sr > Fe > Mg (58.6, 51.7, 48.2, 23.9 and 17.7%, respectively). The increase of TH and WQI values after the biosorption was noticed in all studied lake water samples. The most significant correlations for pH were regarding the contents of B, Mg and Ca, whereas WQI was highly correlated to the contents of B and Mg, and pH. The complexity of the obtained data was explained by Cluster Analysis and Principal Component Analysis, which showed good discrimination capabilities between the water samples taken from different locations. Considering that the invasive M. spicatum is natural, widespread and that its immobilization is cheap and eco-friendly, presented findings could be helpful in further assessment of MsAlg beads for its potential use as biofilter. Copyright © 2018 Elsevier Ltd. All rights reserved.

Simulation study of sulfonate cluster swelling in ionomers

NASA Astrophysics Data System (ADS)

Allahyarov, Elshad; Taylor, Philip L.; Löwen, Hartmut

2009-12-01

We have performed simulations to study how increasing humidity affects the structure of Nafion-like ionomers under conditions of low sulfonate concentration and low humidity. At the onset of membrane hydration, the clusters split into smaller parts. These subsequently swell, but then maintain constant the number of sulfonates per cluster. We find that the distribution of water in low-sulfonate membranes depends strongly on the sulfonate concentration. For a relatively low sulfonate concentration, nearly all the side-chain terminal groups are within cluster formations, and the average water loading per cluster matches the water content of membrane. However, for a relatively higher sulfonate concentration the water-to-sulfonate ratio becomes nonuniform. The clusters become wetter, while the intercluster bridges become drier. We note the formation of unusual shells of water-rich material that surround the sulfonate clusters.

Spatially simulating changes of soil water content and their effects on carbon sequestration in Canada's forests and wetlands

NASA Astrophysics Data System (ADS)

Ju, Weimin; Chen, Jing M.; Black, T. Andrew; Barr, Alan G.; McCaughey, Harry

2010-07-01

The variations of soil water content (SWC) and its influences on the carbon (C) cycle in Canada's forests and wetlands were studied through model simulations using the Integrated Terrestrial Ecosystem Carbon (InTEC) model. It shows that Canada's forests and wetlands experienced spatially and temporally heterogeneous changes in SWC from 1901 to 2000. SWC changes caused average NPP to decrease 40.8 Tg C yr-1 from 1901 to 2000, whereas the integrated effect of non-disturbance factors (climate change, CO2 fertilization and N deposition) enhanced NPP by 9.9%. During 1981-2000, the reduction of NPP caused by changes in SWC was 58.1 Tg C yr-1 whereas non-disturbance factors together caused NPP to increase by 16.6%. SWC changes resulted in an average increase of 4.1 Tg C yr-1 in the net C uptake during 1901-2000, relatively small compared with the enhancement in C uptake of 50.2 Tg C yr-1 by the integrated effect of non-disturbance factors. During 1981-2000, changes in SWC caused a reduction of 3.8 Tg C yr-1 in net C sequestration whereas the integrated factors increased net C sequestration by 54.1 Tg C yr-1. Increase in SWC enhanced C sequestration in all ecozones.

Magnetic susceptibility and dielectric properties of peat in Central Kalimantan, Indonesia

NASA Astrophysics Data System (ADS)

Budi, Pranitha Septiana; Zulaikah, Siti; Hidayat, Arif; Azzahro, Rosyida

2017-07-01

Peatlands dominate almost all regions of Borneo, yet its utilization has not been developed optimally. Any information in this field could be obtained using soil magnetization methods by determining the magnetic succeptibility in terms of magnetic susceptibility value that could describe the source and type of magnetic minerals which could describe the source and type of magnetic minerals. Moreover, the dielectric properties of peat soil were also investigated to determine the level of water content by using the dielectric constant value. Samples was taken at six different locations along Pulang pisau to Berengbengkel. Magnetic susceptibility mass value at these locations ranged between -0.0009 - 0.712 (×10-6 m3/kg). Based on the average magnetic susceptibility value, samples that were taken from T1, T3 and T5 belonged to the type of paramagnetic mineral, while samples which were taken from T2, T4 and T6 belonged to the group of diamagnetic mineral. The low value of magnetic susceptibility of peat was probably derived from the pedogenic process. The average value of peat soil in six locations has a large dielectric constant value that is 28.2 which indicated that there was considerable moisture content due to the hydrophilic nature of peatland which means that the ability of peat in water binding is considerably high.

Profiling the quality characteristics of the butter of Pentadesma butyracea with reference to shea butter.

PubMed

Ayegnon, Bernolde P; Kayodé, Adéchola Pp; Tchobo, Fidèle P; Azokpota, Paulin; Soumanou, Mohamed M; Hounhouigan, D Joseph

2015-12-01

Pentadesma butyracea is a tropical plant species. Its kernels are rich in edible butter similar to shea butter. This study evaluated the quality characteristics of the Pentadesma butter produced by cottage enterprises in Benin, using a quantitative survey approach and physicochemical and sensorial analysis methods. The butter of Pentadesma is mostly used for food preparation, cosmetic and therapeutic applications. It is characterized by a yellow colour, a hard texture, a relatively sweet taste and a bright appearance. Consumers preferred Pentadesma butter to shea butter for colour, taste, texture and appearance. Instrumental analysis showed that the average water content (6.5 g kg(-1) ) and peroxide value (0.74 mEq O2 kg(-1) ) of Pentadesma butter were lower than those of shea butter, for which average water content and peroxide values were 20.7g kg(-1) and 2.09 mEq O2 kg(-1) respectively. The fatty acid profile of Pentadesma butter is similar to that of shea butter. This study showed that the Pentadesma butyracea butter produced by cottage enterprises in Benin exhibited quality characteristics which are better than that of shea butter. The data generated can be used for a better exploitation of the butter in food and cosmetic industries. © 2014 Society of Chemical Industry.

An Arctic source for the Great Salinity Anomaly - A simulation of the Arctic ice-ocean system for 1955-1975

NASA Technical Reports Server (NTRS)

Hakkinen, Sirpa

1993-01-01

The paper employs a fully prognostic Arctic ice-ocean model to study the interannual variability of sea ice during the period 1955-1975 and to explain the large variability of the ice extent in the Greenland and Iceland seas during the late 1960s. The model is used to test the contention of Aagaard and Carmack (1989) that the Great Salinity Anomaly (GSA) was a consequence of the anomalously large ice export in 1968. The high-latitude ice-ocean circulation changes due to wind field changes are explored. The ice export event of 1968 was the largest in the simulation, being about twice as large as the average and corresponding to 1600 cu km of excess fresh water. The simulations suggest that, besides the above average ice export to the Greenland Sea, there was also fresh water export to support the larger than average ice cover. The model results show the origin of the GSA to be in the Arctic, and support the view that the Arctic may play an active role in climate change.

Green synthesis of Au nanoparticles using potato extract: stability and growth mechanism

NASA Astrophysics Data System (ADS)

Castillo-López, D. N.; Pal, U.

2014-08-01

We report on the synthesis of spherical, well-dispersed colloidal gold nanoparticles of 17.5-23.5 nm average sizes in water using potato extract (PE) both as reducing and stabilizing agent. The effects of PE content and the pH value of the reaction mixture have been studied. Formation and growth dynamics of the Au nanoparticles in the colloids were studied using transmission electron microscopy and UV-Vis optical absorption spectroscopy techniques. While the reductor content and, hence, the nucleation and growth rates of the nanoparticles could be controlled by controlling the PE content in the reaction solution, the stability of the nanoparticles depended strongly on the pH of the reaction mixture. The mechanisms of Au ion reduction and stabilization of Au nanoparticles by potato starch have been discussed. The use of common natural solvent like water and biological reductor like PE in our synthesis process opens up the possibility of synthesizing Au nanoparticles in fully green (environmental friendly) way, and the Au nanoparticles produced in such way should have good biocompatibility.

Effect of Dietary Processed Sulfur Supplementation on Water-holding Capacity, Color, and Lipid Profiles of Pork

PubMed Central

Yang, FengQi; Kim, Ji-Han; Yeon, Su Jung; Hong, Go-Eun; Park, Woojoon; Lee, Chi-Ho

2015-01-01

This study was performed to investigate the effect of dietary processed sulfur supplementation on water-holding capacity, color, and lipid profiles of pork according to the level of dietary processed sulfur (0%, CON; 0.3%, S). The pigs were slaughtered at an average final weight of 120 kg, and the longissimus dorsi muscles were collected from the carcasses. As results, pork processed with sulfur had significantly higher moisture and ash contents compared to those of CON but lower crude fat, pH, expressible drip, lower redness and yellowness, and greater lightness. Pork processed with sulfur showed significantly lower total lipid content, triglycerides, and atherosclerosis index but significantly higher high-density lipoprotein cholesterol. Feeding processed sulfur significantly lowered myristic acid, heptadecanoic acid, and stearic acid contents, whereas monounsaturated fatty acids and oleic acids were significantly higher compared to those in the CON. Higher amounts of polyunsaturated fatty acids and n-6 fatty acids were observed in the pork processed with sulfur than that of the CON. Therefore, supplementing pigs with dietary sulfur improved nutrient and meat quality. PMID:26877643

[Spatiotemporal variation characteristics of heavy metals pollution in the water, soil and sediments environment of the Lean River-Poyang Lake Wetland].

PubMed

Jian, Min-Fei; Li, Ling-Yu; Xu, Peng-Fei; Chen, Pu-Qing; Xiong, Jian-Qiu; Zhou, Xue-Ling

2014-05-01

Overlying water, sediments, surface soils in the typical wetland areas of Lean River and Poyang Lake which were rich in non-ferrous metal mineral resources on both sides of the river, were chosen for monitoring heavy metals including copper, lead and cadmium of base flow in average season, flood season, and dry season in 2012. Statistical analysis methods were coupled to characterize the spatiotemporal variation of heavy metals pollution and identify the main sources. The results indicated that the concentrations of copper were the highest in all samples of each sampling sites in the Lean River-Poyang Lake wetland. And the content values of copper, lead and cadmium in different samples of different sampling sites also showed that the content values of copper were higher than those of lead, and the content values of lead were also higher than those of cadmium. The results also showed that the heavy metals pollution of copper, lead and cadmium in flood season was the heaviest whereas the heavy metals pollution in dry season was comparatively light. The results of the contents of the three kinds of heavy metals elements in different sampling sites of the watersheds of lean River showed that the contents of copper in the samples from the upstream sampling sites of Lean River were higher than those of other samples from other sites. And the contents of lead in the samples from the downstream sampling sites of Lean River were higher than those of other samples from other sampling sites. The contents of cadmium in the samples from the midstream sampling sites of Lean River were higher than those of other samples from other sites. The first principal component representing copper pollution explained 36. 99% of the total variance of water quality. The second principal component concerning representing lead pollution explained 30. 12% of the total variance. The correlation analysis results showed that there were significant positive correlations among the contents of copper in sediments and the contents of copper in overlying water. And there was also significant positive correlation between the contents of copper in sediments and the contents of copper in the surface soils. And the correlation analysis showed that there were significant positive correlations among the contents of cadmium in sediments and the contents of cadmium in surface soils. The above results reflected that the copper pollution or cadmium sources of water, soil and sediments were consistent, which were mainly from heavy metal acidic waste of mining emissions. The correlations between other components were not very obvious, which reflected the sources of pollutants were different.

Particle water and pH in the eastern Mediterranean: source variability and implications for nutrient availability

NASA Astrophysics Data System (ADS)

Bougiatioti, Aikaterini; Nikolaou, Panayiota; Stavroulas, Iasonas; Kouvarakis, Giorgos; Weber, Rodney; Nenes, Athanasios; Kanakidou, Maria; Mihalopoulos, Nikolaos

2016-04-01

Particle water (liquid water content, LWC) and aerosol pH are important parameters of the aerosol phase, affecting heterogeneous chemistry and bioavailability of nutrients that profoundly impact cloud formation, atmospheric composition, and atmospheric fluxes of nutrients to ecosystems. Few measurements of in situ LWC and pH, however, exist in the published literature. Using concurrent measurements of aerosol chemical composition, cloud condensation nuclei activity, and tandem light scattering coefficients, the particle water mass concentrations associated with the aerosol inorganic (Winorg) and organic (Worg) components are determined for measurements conducted at the Finokalia atmospheric observation station in the eastern Mediterranean between June and November 2012. These data are interpreted using the ISORROPIA-II thermodynamic model to predict the pH of aerosols originating from the various sources that influence air quality in the region. On average, closure between predicted aerosol water and that determined by comparison of ambient with dry light scattering coefficients was achieved to within 8 % (slope = 0.92, R2 = 0.8, n = 5201 points). Based on the scattering measurements, a parameterization is also derived, capable of reproducing the hygroscopic growth factor (f(RH)) within 15 % of the measured values. The highest aerosol water concentrations are observed during nighttime, when relative humidity is highest and the collapse of the boundary layer increases the aerosol concentration. A significant diurnal variability is found for Worg with morning and afternoon average mass concentrations being 10-15 times lower than nighttime concentrations, thus rendering Winorg the main form of particle water during daytime. The average value of total aerosol water was 2.19 ± 1.75 µg m-3, contributing on average up to 33 % of the total submicron mass concentration. Average aerosol water associated with organics, Worg, was equal to 0.56 ± 0.37 µg m-3; thus, organics contributed about 27.5 % to the total aerosol water, mostly during early morning, late evening, and nighttime hours.

The aerosol was found to be highly acidic with calculated aerosol pH varying from 0.5 to 2.8 throughout the study period. Biomass burning aerosol presented the highest values of pH in the submicron fraction and the lowest values in total water mass concentration. The low pH values observed in the submicron mode and independently of air mass origin could increase nutrient availability and especially P solubility, which is the nutrient limiting sea water productivity of the eastern Mediterranean.

Effects of relaxation of gluten network on rehydration kinetics of pasta.

PubMed

Ogawa, Takenobu; Hasegawa, Ayako; Adachi, Shuji

2014-01-01

The aim of this study was to investigate the effects of the relaxation of the gluten network on pasta rehydration kinetics. The moisture content of pasta, under conditions where the effects of the diffusion of water on the moisture content were negligible, was estimated by extrapolating the average moisture content of pasta of various diameters to 0 mm. The moisture content of imaginary, infinitely thin pasta did not reach equilibrium even after 1 h of rehydration. The rehydration of pasta made of only gluten was also measured. The rate constants estimated by the Long and Richman equation for both the pasta indicated that the rehydration kinetics of infinitely thin pasta were similar to those of gluten pasta. These results suggest that the swelling of starch by fast gelatinization was restricted by the honeycomb structural network of gluten and the relaxation of the gluten network controlled pasta rehydration kinetics.

Water distribution at the root-soil interface: is there more water next to roots?

NASA Astrophysics Data System (ADS)

Carminati, A.; Moradi, A.; Oswald, S.; Vetterlein, D.; Weller, U.; Vogel, H.-J.

2009-04-01

Plants are big water movers and have a significant impact on soil water dynamics as well as on the global water cycle. Despite the relevance of root water uptake in terrestrial ecology, the movement of water from soil to roots still presents important open questions, e.g the following two. Which are the properties of the soil near the roots? And what effect do these properties have on soil plant water relations? Most models are based on brute-force spatial averaging of soil properties and assume that the bulk soil has the same properties as the rhizosphere. However, there is evidence in the literature that the rhizosphere has specific properties that may affect water and nutrient uptake (Young 1995, Gregory 2007). In order to investigate the rhizosphere hydraulic properties and their effect on soil plant water relations, we used neutron radiography and neutron tomography to image the water content distribution in soils during plant transpiration. Rectangular (quasi-2D) and cylindrical containers were filled with sandy soil and planted with lupins (Lupinus albus). Three weeks after planting, the samples were equilibrated at water potentials of -10 and 30 hPa and have been imaged for 5 days at intervals of 6 hours. At day 5 the samples were irrigated again via capillary rise and the water distribution was monitored for 4 more days. During the first day of the drying period, regions of water depletion formed around the central part of the tap root where first order laterals were present. As the soil dried up, the picture changed: instead of less water around the roots, as commonly supposed by models, we observed that more water was present around the lateral roots. Interestingly, these regions during drying were retaining high water content, but after irrigation remained markedly drier than the bulk soil. Our hypothesis is that high water content near roots during drying and lower water content during rewetting are explained by the presence of bio-polymers exuded by roots forming a hydrogel that consists of up to 99% water at very negative water potentials (Read et al. 1999). Thanks to its high water holding capacity, this hydrogel maintains a continuous hydraulic pathway across soil and roots for an extended period of time during drying. During rewetting it adversely affects water redistribution, like a storage that needs time to fill up again. These data show for the first time in situ the potential role of mucilage in controlling water dynamics in the rhizosphere and consequences for plant water extraction. Gregory P J, Roots, rhizosphere and soil: the route to a better understanding of soil science? European Journal of Soil Science, 57: 2-12, 2006. Read D P, Gregory P J, and Bell A E. Physical properties of axenic maize root mucilage. Plant and Soil, 211: 87-91, 1999. Young I M. Variation in moisture contents between bulk soil and the rhizosheath of wheat. New Phytologist, 130: 135-139, 1995.

Soil quality evolution after land use change from paddy soil to vegetable land.

PubMed

Cao, Z H; Huang, J F; Zhang, C S; Li, A F

2004-01-01

A survey was done in 15 typical villages, 150 soil and 86 vegetable plant samples were taken in Jiaxin prefecture of the Taihu Lake region, northern Zhejian province. Results indicate that after 15-20 years land use changed from the paddy rice-wheat (or oilseed rape) double cropping system, to a continuous vegetable land has caused soil quality dramatic change. (1) Acidification: average soil pH was 5.4; about 61% of total samples were pH < 5.5. It was 0.9 units lower than 10 years ago with same upland vegetable cultivation and was 1.2 units lower than soil pH of paddy rice-wheat (or oilseed rape) rotation. (2) Fertilizer salt accumulation: the average salt content was 0.28%, among these about 36.2% of the total samples contained more than 0.3%. (3) Nitrate N and available phosphorus (P) over accumulation: on average it was 279 mg NO3-N/kg, and 45-115 mg P/kg. Nitrate N four times higher and available P 4-10 times more than it is in present paddy rice-wheat rotation soils respectively. This has caused wide concern because of possible groundwater and well drinking water pollution by leached nitrate N and the P losses to water by runoff from vegetable lands induce surface water eutrophication.

Technological advances in cosmogenic neutron detectors for measuring soil water content

NASA Astrophysics Data System (ADS)

Zreda, M. G.; Schrön, M.; Köhli, M.

2017-12-01

The cosmic-ray neutron probe is used for measuring area-average soil water content at the hectometer scale. Early work showed a simple exponential decrease with distance of the instrument's sensitivity and a footprint 300 m in radius. Recent research suggested a much higher sensitivity to local neutrons and reduced footprint. We show results confirming the high sensitivity to local neutrons, describe two ways to reduce local and increase far-field effects, and propose ways of measuring neutrons at different spatial scales. Measurements with moderated detectors across a 10-m-wide creek and a 2-m-wide water tank show a decrease by 30% and 20%, respectively, of neutron intensity over water compared to that over land nearby. These results mean that the detector is sensitive to meter-scale heterogeneities of water content. This sensitivity can be reduced by rising the detector or by shielding it from local neutrons. The effect of local water distributions on the measured neutron intensity decreases with height. In the water tank experiment it disappeared almost completely at the height of 2 m, leading to the conjecture that the height roughly equal to the horizontal scale of heterogeneity would eliminate the sensitivity. This may or may not be practical. Shielding the detector below by a hydrogenous material removes a substantial fraction of the local neutrons. The shielded detector has a reduced count rate, reduced sensitivity to local neutrons and increased sensitivity to neutrons farther afield, and a larger footprint. Such a detector could be preferable to the current cosmogenic-neutron probe under heterogeneous soil water conditions. The shielding experiments also inspired the development of a local-area neutron detector. It has hydrogenous neutron shields on all sides except the bottom, substantially blocking the neutrons coming from afar, while allowing the neutrons coming directly from below. Its footprint is equal to its physical dimension when the detector is placed on the surface. Once this detector is calibrated, it can be useful in calibrating the wide-area detector, for example over stony soils that are difficult to sample physically for water content determination, and in high-resolution mapping of neutron intensity and soil moisture.

Chemical composition of polluted mist droplets

NASA Astrophysics Data System (ADS)

Igawa, Manabu; Kamijo, Kosuke; Nanzai, Ben; Matsumoto, Kiyoshi

2017-12-01

Mist events occur frequently worldwide, but the chemical characteristics of the mist droplets has never been investigated because of very low liquid water contents of them. We estimated the concentrations of the mist water, the average concentration of the mist droplets, via the determination of water-soluble components of the coarse aerosol and the observation of the imprints of the droplets on a MgO-coated glass slide. The pH of the mist water was estimated from the equilibrium calculation with the data of the Gran plot of the solution of the dissolved coarse particles, the inorganic ion concentrations of aerosol larger than 10 μm, and the estimated volume of mist water. The mist water was measured as about 1 eq/L total concentration for typical inorganic ions and about pH 4.5 in Yokohama. Such highly concentrated mist droplets may have intense environmental effects.

Palynology, petrography and geochemistry of the Sewickley coal bed (Monongahela Group, Late Pennsylvanian), Northern Appalachian Basin, USA

USGS Publications Warehouse

Eble, C.F.; Pierce, B.S.; Grady, W.C.

2003-01-01

Forty-two bench samples of the Sewickley coal bed were collected from seven localities in the northern Appalachian Basin and analyzed palynologically, petrographically, and geochemically. The Sewickley coal bed occurs in the middle of the Pittsburgh Formation (Monongahela Group) and is of Late Pennsylvanian age. Palynologically, it is dominated by spores of tree ferns. Tree fern spore taxa in the Sewickley include Punctatisporites minutus, Punctatosporites minutus, Laevigatosporites minimus, Spinosporites exiguus, Apiculatasporites saetiger, and Thymospora spp. In fact, Punctatisporites minutus was so abundant that it had to be removed from the standard counts and recorded separately (average 73.2%). Even when Punctatisporites minutus is removed from the counts, tree fern spores still dominate a majority of the assemblages, averaging 64.4%. Among the tree fern spores identified in the Sewickley coal, Thymospora exhibits temporal and spatial abundance variation. Thymospora usually increases in abundance from the base to the top of the bed. Thymospora is also more abundant in columns that are thick (>100 cm) and low in ash yield (< 12.0%, dry basis). Calamite spores (e.g. Calamospora spp., Laevigatosporites minor, and L. vulgaris) are the next most abundant plant group represented in the Sewickley coal, averaging 20%. Contributions from all other plant groups are minor in comparison. Petrographically, the Sewickley coal contains high percentages of vitrinite (average 82.3%, mineral matter-free (mmf)), with structured forms being more common than unstructured forms. In contrast, liptinite and inertinite macerals both occur in low percentages (average 7.7% and 10.0%, respectively). Geochemically, the Sewickley coal has a moderate ash yield (average 12.4%) and high total sulfur content (average 3.4%). Four localities contained a high ash or carbonaceous shale bench. These benches, which may be coeval, are strongly dominated by tree fern spores. Unlike the lower ash benches, they contain low percentages of vitrinite, which mainly occurs as unstructured vitrinite, and higher liptinite and inertinite contents. The accumulated data suggest that the Sewickley paleomire was probably a rheotrophic, planar mire that had a consistent water cover. This is supported by the high vitrinite contents, moderate ash yields, and high total sulfur contents. The high ash and carbonaceous shale benches probably represent either periods of dryness and substrate exposure, or flooding of the mire surface, the duration of which is unknown. ?? 2003 Elsevier B.V. All rights reserved.

Selenium speciation and extractability in Dutch agricultural soils.

PubMed

Supriatin, Supriatin; Weng, Liping; Comans, Rob N J

2015-11-01

The study aimed to understand selenium (Se) speciation and extractability in Dutch agricultural soils. Top soil samples were taken from 42 grassland fields and 41 arable land fields in the Netherlands. Total Se contents measured in aqua regia were between 0.12 and 1.97 mg kg(-1) (on average 0.58 mg kg(-1)). Organic Se after NaOCl oxidation-extraction accounted for on average 82% of total Se, whereas inorganic selenite (selenate was not measurable) measured in ammonium oxalate extraction using HPLC-ICP-MS accounted for on average 5% of total Se. The predominance of organic Se in the soils is supported by the positive correlations between total Se (aqua regia) and total soil organic matter content, and Se and organic C content in all the other extractions performed in this study. The amount of Se extracted followed the order of aqua regia > 1 M NaOCl (pH8) > 0.1 M NaOH>ammonium oxalate (pH3) > hot water>0.43 M HNO3 > 0.01 M CaCl2. None of these extractions selectively extracts only inorganic Se, and relative to other extractions 0.43 M HNO3 extraction contains the lowest fraction of organic Se, followed by ammonium oxalate extraction. In the 0.1M NaOH extraction, the hydrophobic neutral (HON) fraction of soil organic matter is richer in Se than in the hydrophilic (Hy) and humic acid (HA) fractions. The organic matter extracted in 0.01 M CaCl2 and hot water is in general richer in Se compared to the organic matter extracted in 0.1M NaOH, and other extractions (HNO3, ammonium oxalate, NaOCl, and aqua regia). Although the extractability of Se follows to a large extent the extractability of soil organic carbon, there is several time variations in the Se to organic C ratios, reflecting the changes in composition of organic matter extracted. Copyright © 2015 Elsevier B.V. All rights reserved.

Mesophilic biomethanation and treatment of poultry waste-water using pilot scale UASB reactor.

PubMed

Atuanya, Ernest I; Aigbirior, Moses

2002-07-01

The feasibility of applying the up-flow anaerobic sludge blanket (UASB) treatment for poultry waste (faeces) water was examined. A continuous-flow UASB pilot scale reactor of 3.50 L capacity using mixed culture was operated for 95 days to assess the treatability of poultry waste-water and its methane production. The maximum chemical oxygen demand (COD) removed was found to be 78% when organic loading rate (OLR) was 2.9 kg COD m(-3) day(-1) at hydraulic retention times (HRT) of 13.2 hr. The average biogas recovery was 0.26 m3 CH4 kg COD with an average methane content of 57% at mean temperature of 30 degrees C. Data indicate more rapid methanogenesis with higher loading rates and shorter hydraulic retention times. At feed concentration of 4.8 kg COD m(-3) day(-1), anaerobic digestion was severely retarded at all hydraulic retention time tested. This complication in the reactor operations may be linked to build-up of colloidal solids often associated with poultry waste water and ammonia toxicity. Isolates from granular sludge and effluent were found to be facultative anaerobes most of which were Pseudomonas genera.

[Geographical distribution of fluoride in the public water supply in the province of Tucumán, Argentina].

PubMed

Durán, Raúl Alberto; Durán, Estela Liliana; Ojeda, Graciela de Jesús; Castellanos, Walter Alfredo

2017-01-01

This work studied the geographical distribution of fluoride content in the public water supply in the province of Tucumán, Argentina. A total of 1,210 samples were collected in 190 localities of the 17 departments of the province during the 2008-2012 period. The analytical determination was performed using the SPADNS method and QGis 2.16 was used for processing the information. The fluoride content requirements in the studied localities were determined according to the Argentine Food Code. The results showed that 94% of population studied consumed water with fluoride concentrations below the recommended limits, 5% were exposed to fluoride concentrations above the required maximum limit and 1% consumed water at optimal fluoride concentrations. The maps showed a heterogeneous geographical distribution of fluorides, in which areas with deficit, excess and recommended values of fluorides can be differentiated; in some departments an inverse relationship between the density of the hydrological network and fluoride concentration can be observed. In the capital of the province, the average value found was 0.32 mg/l, presenting a homogeneous geographical distribution. The information obtained is indispensable for the proper management of fluoride, so as to improve public health through policy.

Synthesis of Nanometric-Sized Barium Titanate Powders Using Acetylacetone as the Chelating Agent in a Sol-Precipitation Process

NASA Astrophysics Data System (ADS)

Hung, Kun Ming; Hsieh, Ching Shieh; Yang, Wein Duo; Tsai, Hui Ju

2007-03-01

Nanometric-sized barium titanate powders were prepared by using titanium isopropoxid as the raw material and acetylacetone as a chelating agent, in a strong alkaline solution (pH > 13) through the sol-precipitation method. The preparatory variables affect the extent of cross-linking in the structure, change the mode of condensation of the gels, and even control the particle size of the powder. The reaction rate of forming powder, at a higher temperature such as 100°C and more water content (the molar ratio of water to titanium isopropoxide is 25) or fewer acetylacetone (the molar ratio of acetylacetone to titanium isopropoxide is 1), is rapid and the particle size formed is finer at 60 80 nm. On the contrary, that of forming powder, at lower temperature (40°C) and less water content (molar ratio of water/titanium isopropoxide = 5) or higher acetylacetone (acetylacetone/titanium isopropoxide = 7), is slow and the particle size of the powder is larger. The optimal preparatory conditions were obtained by using the experimental statistical method; as a result, nanometric-sized BaTiO3 powder with an average particle size of about 50 nm was prepared.

Utilization of an ionic liquid in situ preconcentration method for the determination of the 15 + 1 European Union polycyclic aromatic hydrocarbons in drinking water and fruit-tea infusions.

PubMed

Germán-Hernández, Mónica; Crespo-Llabrés, Pilar; Pino, Verónica; Ayala, Juan H; Afonso, Ana M

2013-08-01

An ionic liquid (IL) in situ preconcentration method was optimized and applied to the monitoring of the 15 + 1 European Union polycyclic aromatic hydrocarbons in water and fruit-tea infusions. The optimized method utilizes 10 mL of water (or infusion) containing 38 μL of the IL 1-butyl-3-methylimidazolium chloride and a content of 36.1 g/L NaCl, which are mixed with Li-NTf2 (340 μL, 0.2 g/mL), followed by vortex (4 min) and centrifugation (5 min). The obtained microdroplet containing hydrocarbons is diluted with acetonitrile and injected into an HPLC with UV/Vis and fluorescence detection. The method presented average enrichment factors of 127 for water (tap water and bottled water) and 27 for two fruit-tea infusions; with average relative recoveries of 86.7 and 106% for water and fruit-tea infusions, respectively. The method was sensitive, with detection limits ranging from 0.001 to 0.050 ng/mL in water, and from 0.010 to 0.600 ng/mL in fruit-tea infusions, for the fluorescent hydrocarbons. Real extraction efficiencies ranged from 12.7 to 58.7% for water, and from 20.2 to 117% for the infusions. The method was also fast (~12 min) and free of organic solvents in the extraction step. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Incorporation of New Convective Ice Microphysics into the NASA GISS GCM and Impacts on Cloud Ice Water Path (IWP) Simulation

NASA Technical Reports Server (NTRS)

Elsaesser, Greg; Del Genio, Anthony

2015-01-01

The CMIP5 configurations of the GISS Model-E2 GCM simulated a mid- and high latitude ice IWP that decreased by 50 relative to that simulated for CMIP3 (Jiang et al. 2012; JGR). Tropical IWP increased by 15 in CMIP5. While the tropical IWP was still within the published upper-bounds of IWP uncertainty derived using NASA A-Train satellite observations, it was found that the upper troposphere (200 mb) ice water content (IWC) exceeded the published upper-bound by a factor of 2. This was largely driven by IWC in deep-convecting regions of the tropics.Recent advances in the model-E2 convective parameterization have been found to have a substantial impact on tropical IWC. These advances include the development of both a cold pool parameterization (Del Genio et al. 2015) and new convective ice parameterization. In this presentation, we focus on the new parameterization of convective cloud ice that was developed using data from the NASA TC4 Mission. Ice particle terminal velocity formulations now include information from a number of NASA field campaigns. The new parameterization predicts both an ice water mass weighted-average particle diameter and a particle cross sectional area weighted-average size diameter as a function of temperature and ice water content. By assuming a gamma-distribution functional form for the particle size distribution, these two diameter estimates are all that are needed to explicitly predict the distribution of ice particles as a function of particle diameter.GCM simulations with the improved convective parameterization yield a 50 decrease in upper tropospheric IWC, bringing the tropical and global mean IWP climatologies into even closer agreement with the A-Train satellite observation best estimates.

Incorporation of New Convective Ice Microphysics into the NASA GISS GCM and Impacts on Cloud Ice Water Path (IWP) Simulation

NASA Astrophysics Data System (ADS)

Elsaesser, G.; Del Genio, A. D.

2015-12-01

The CMIP5 configurations of the GISS Model-E2 GCM simulated a mid- and high-latitude ice IWP that decreased by ~50% relative to that simulated for CMIP3 (Jiang et al. 2012; JGR). Tropical IWP increased by ~15% in CMIP5. While the tropical IWP was still within the published upper-bounds of IWP uncertainty derived using NASA A-Train satellite observations, it was found that the upper troposphere (~200 mb) ice water content (IWC) exceeded the published upper-bound by a factor of ~2. This was largely driven by IWC in deep-convecting regions of the tropics. Recent advances in the model-E2 convective parameterization have been found to have a substantial impact on tropical IWC. These advances include the development of both a cold pool parameterization (Del Genio et al. 2015) and new convective ice parameterization. In this presentation, we focus on the new parameterization of convective cloud ice that was developed using data from the NASA TC4 Mission. Ice particle terminal velocity formulations now include information from a number of NASA field campaigns. The new parameterization predicts both an ice water mass weighted-average particle diameter and a particle cross sectional area weighted-average size diameter as a function of temperature and ice water content. By assuming a gamma-distribution functional form for the particle size distribution, these two diameter estimates are all that are needed to explicitly predict the distribution of ice particles as a function of particle diameter. GCM simulations with the improved convective parameterization yield a ~50% decrease in upper tropospheric IWC, bringing the tropical and global mean IWP climatologies into even closer agreement with the A-Train satellite observation best estimates.

Filler characteristics of modern dental resin composites and their influence on physico-mechanical properties.

PubMed

Randolph, Luc D; Palin, William M; Leloup, Gaëtane; Leprince, Julian G

2016-12-01

The mechanical properties of dental resin-based composites (RBCs) are highly dependent on filler characteristics (size, content, geometry, composition). Most current commercial materials are marketed as "nanohybrids" (i.e. filler size <1μm). In the present study, filler characteristics of a selection of RBCs were described, aiming at identifying correlations with physico-mechanical properties and testing the relevance of the current classification. Micron/sub-micron particles (> or <500nm) were isolated from 17 commercial RBCs and analyzed by laser diffractrometry and/or electron microscopy. Filler and silane content were evaluated by thermogravimetric analysis and a sedimentation technique. The flexural modulus (E flex ) and strength (σ flex ) and micro-hardness were determined by three-point bending or with a Vickers indenter, respectively. Sorption was also determined. All experiments were carried out after one week of incubation in water or 75/25 ethanol/water. Average size for micron-sized fillers was almost always higher than 1μm. Ranges for mechanical properties were: 3.775wt%) were associated with the highest mechanical properties (E flex and σ flex >12GPa and 130MPa, respectively) and lowest solvent sorption (∼0.3%). Mechanical properties and filler characteristics significantly vary among modern RBCs and the current classification does not accurately illustrate either. Further, the chemical stability of RBCs differed, highlighting differences in resin and silane composition. Since E flex and sorption were well correlated to the filler content, a simple and unambiguous classification based on such characteristic is suggested, with three levels (ultra-low fill, low-fill and compact resin composites). Copyright © 2016 The Academy of Dental Materials. All rights reserved.

Water in volcanic glass: From volcanic degassing to secondary hydration

NASA Astrophysics Data System (ADS)

Seligman, Angela N.; Bindeman, Ilya N.; Watkins, James M.; Ross, Abigail M.

2016-10-01

Volcanic glass is deposited with trace amounts (0.1-0.6 wt.%) of undegassed magmatic water dissolved in the glass. After deposition, meteoric water penetrates into the glass structure mostly as molecular H2O. Due to the lower δD (‰) values of non-tropical meteoric waters and the ∼30‰ offset between volcanic glass and environmental water during hydration, secondary water imparts lighter hydrogen isotopic values during secondary hydration up to a saturation concentration of 3-4 wt.% H2O. We analyzed compositionally and globally diverse volcanic glass from 0 to 10 ka for their δD and H2Ot across different climatic zones, and thus different δD of precipitation, on a thermal conversion elemental analyzer (TCEA) furnace attached to a mass spectrometer. We find that tephrachronologically coeval rhyolite glass is hydrated faster than basaltic glass, and in the majority of glasses an increase in age and total water content leads to a decrease in δD (‰), while a few equatorial glasses have little change in δD (‰). We compute a magmatic water correction based on our non-hydrated glasses, and calculate an average 103lnαglass-water for our hydrated felsic glasses of -33‰, which is similar to the 103lnαglass-water determined by Friedman et al. (1993a) of -34‰. We also determine a smaller average 103lnαglass-water for all our mafic glasses of -23‰. We compare the δD values of water extracted from our glasses to local meteoric waters following the inclusion of a -33‰ 103lnαglass-water. We find that, following a correction for residual magmatic water based on an average δD and wt.% H2Ot of recently erupted ashes from our study, the δD value of water extracted from hydrated volcanic glass is, on average, within 4‰ of local meteoric water. To better understand the difference in hydration rates of mafic and felsic glasses, we imaged 6 tephra clasts ranging in age and chemical composition with BSE (by FEI SEM) down to a submicron resolution. Mafic tephra have more bubbles per unit area (25-77 mm-2) than felsic tephra (736 mm-2) and thicker average bubble walls (0.07 mm) than felsic tephra (0.02 mm). We use a simplified diffusion model to quantify the hydration rate of vesicular glass as a function of the diffusivity of water and the average bubble wall thickness. Based on fits to our hydration rate data, we estimate the initial low-temperature diffusivity at 0.1 wt.% H2Ot in volcanic glass (mafic and felsic) to be on the order of 10-3 to 10-4 μm2/year and find that differences in hydration rates between mafic and felsic tephra can be attributed primarily to differences in vesicularity, although slightly slower hydration of basalt cannot be precluded. We also observe no consistent temporal difference in secondary meteoric water uptake in wet versus dry and hot versus cold climates.

Stress relaxation of swine growth plate in semi-confined compression: depth dependent tissue deformational behavior versus extracellular matrix composition and collagen fiber organization.

PubMed

Amini, Samira; Mortazavi, Farhad; Sun, Jun; Levesque, Martin; Hoemann, Caroline D; Villemure, Isabelle

2013-01-01

Mechanical environment is one of the regulating factors involved in the process of longitudinal bone growth. Non-physiological compressive loading can lead to infantile and juvenile musculoskeletal deformities particularly during growth spurt. We hypothesized that tissue mechanical behavior in sub-regions (reserve, proliferative and hypertrophic zones) of the growth plate is related to its collagen and proteoglycan content as well as its collagen fiber orientation. To characterize the strain distribution through growth plate thickness and to evaluate biochemical content and collagen fiber organization of the three histological zones of growth plate tissue. Distal ulnar growth plate samples (N = 29) from 4-week old pigs were analyzed histologically for collagen fiber organization (N = 7) or average zonal thickness (N = 8), or trimmed into the three average zones, based on the estimated thickness of each histological zone, for biochemical analysis of water, collagen and glycosaminoglycan content (N = 7). Other samples (N = 7) were tested in semi-confined compression under 10% compressive strain. Digital images of the fluorescently labeled nuclei were concomitantly acquired by confocal microscopy before loading and after tissue relaxation. Strain fields were subsequently calculated using a custom-designed 2D digital image correlation algorithm. Depth-dependent compressive strain patterns and collagen content were observed. The proliferative and hypertrophic zone developed the highest axial and transverse strains, respectively, under compression compared to the reserve zone, in which the lowest axial and transverse strains arose. The collagen content per wet mass was significantly lower in the proliferative and hypertrophic zones compared to the reserve zone, and all three zones had similar glycosaminoglycan and water content.Polarized light microscopy showed that collagen fibers were mainly organized horizontally in the reserve zone and vertically aligned with the growth direction in the proliferative and hypertrophic zones. Higher strains were developed in growth plate areas (proliferative and hypertrophic) composed of lower collagen content and of vertical collagen fiber organization. The stiffer reserve zone, with its higher collagen content and collagen fibers oriented to restrain lateral expansion under compression, could play a greater role of mechanical support compared to the proliferative and hypertrophic zones, which could be more susceptible to be involved in an abnormal growth process.

Estimating Recharge From Soil Water Tension Data

NASA Astrophysics Data System (ADS)

Sisson, J. B.; Gee, G. W.

2001-12-01

Effectively managing an aquifer requires accurate estimates of the ambient flux as well as the travel time of annual pulses to pass through the vadose zone. When soil water potential and/or water content data are available together with unsaturated hydraulic properties the ambient flux can be estimated using Darcy's Law. A field site, the Buried Waste Test Facility, located at Hanford WA was instrumented with advanced tensiometers to a depth of 20 ft bls and data obtained over a 2 year period. The unsaturated hydraulic properties were available at the closed bottom lysimeter from previous studies. The ambient flux was estimated from the rate of pumpage from the lysimeter to be 55 mm/y. Data from the tensiometers indicated a unit gradient in total water potential at depths greater than 4 m. Thus, the ambient flux was numerically equal to the unsaturated hydraulic conductivity. The data also clearly show the passage of wetting fronts beyond 2.3 m and with some imagination to depths beyond 4.3 m. Using the tensiometer data together with previously estimated hydraulic properties resulted in estimates of ambient flux that ranged from about 10 to 120 mm/y. These estimates were found to depend on the length of the period, for which soil water potentials were averaged, and on how the hydraulic conductivity was averaged.

[Hygienic aspects of the microclimate in intensive management of rabbits].

PubMed

Fiser, A

1994-01-01

In a four-row cowshed adapted for rabbit housing, air temperatures and humidity were recorded ambulantly and instrumentally, air flow rate, cooling variable, gas content in the air, microbial contamination of air and dust deposition were determined ambulantly in the years 1991-1992 and in January to April 1993. The values of ambulant measurings show that at the outside temperature -0.5 degrees C to -5.0 degrees C the microclimate quality decreases particularly with respect to the drop of air temperature in the cowshed below 10.0 degrees C, to the increase in cooling variable up to the value 53.17 mW/cm2 and to the increase in NH3 and CO2 content to 50 ppm and/or 0.45 vol.% in absolute maximum values. In these circumstances, the average determined values of both gases are higher than the standard prescription. At outside temperatures above 27.0 degrees C the average relative air humidity in the cowshed made 69.20% for the average temperature of 25.0 degrees C. To avoid the water vapor tension exceeding the limit in the cowshed air above the value 14.1 mm Hg, when sultry atmosphere sets in, the average relative air humidity should be maximally 59.0%. Hence the cowshed was found to be insufficiently ventilated at high outside temperatures above 27.0 degrees C, and it is recommended to increase the ventilator performance and at the same time to reduce water evaporation from catchpit surfaces when urine output of rabbits is excessive as a result of the increased water intake. Temperature and air humidity readings confirmed the need of heating source installation when the outside temperatures drop below 0.0 degrees C. Evaluation of air microbial contamination showed high counts of molds and particularly of micrococci in comparison with the ambience of a cage facility for piglet raising at a repopulation station with strict hygienic regime. Microbial picture of dust deposition was positively influenced by longitudinal aerosol disinfection of the air in the cowshed.

Plasticity of Sorghum Stem Biomass Accumulation in Response to Water Deficit: A Multiscale Analysis from Internode Tissue to Plant Level

PubMed Central

Perrier, Lisa; Rouan, Lauriane; Jaffuel, Sylvie; Clément-Vidal, Anne; Roques, Sandrine; Soutiras, Armelle; Baptiste, Christelle; Bastianelli, Denis; Fabre, Denis; Dubois, Cécile; Pot, David; Luquet, Delphine

2017-01-01

Sorghum is increasingly used as a biomass crop worldwide. Its genetic diversity provides a large range of stem biochemical composition suitable for various end-uses as bioenergy or forage. Its drought tolerance enables it to reasonably sustain biomass production under water limited conditions. However, drought effect on the accumulation of sorghum stem biomass remains poorly understood which limits progress in crop improvement and management. This study aimed at identifying the morphological, biochemical and histological traits underlying biomass accumulation in the sorghum stem and its plasticity in response to water deficit. Two hybrids (G1, G4) different in stem biochemical composition (G4, more lignified, less sweet) were evaluated during 2 years in the field in Southern France, under two water treatments differentiated during stem elongation (irrigated; 1 month dry-down until an average soil water deficit of -8.85 bars). Plant phenology was observed weekly. At the end of the water treatment and at final harvest, plant height, stem and leaf dry-weight and the size, biochemical composition and tissue histology of internodes at 2–4 positions along the stem were measured. Stem biomass accumulation was significantly reduced by drought (in average 42% at the end of the dry-down). This was due to the reduction of the length, but not diameter, of the internodes expanded during water deficit. These internodes had more soluble sugar but lower lignin and cellulose contents. This was associated with a decrease of the areal proportion of lignified cell wall in internode outer zone whereas the areal proportion of this zone was not affected. All internodes for a given genotype and environment followed a common histochemical dynamics. Hemicellulose content and the areal proportion of inner vs. outer internode tissues were set up early during internode growth and were not drought responsive. G4 exhibited a higher drought sensitivity than G1 for plant height only. At final harvest, the stem dry weight was only 18% lower in water deficit (re-watered) compared to well-watered treatment and internodes growing during re-watering were similar to those on the well-watered plants. These results are being valorized to refine the phenotyping of sorghum diversity panels and breeding populations. PMID:28919904

Vesicles, water, and sulfur in Reykjanes Ridge basalts

USGS Publications Warehouse

Moore, J.G.; Schilling, J.-G.

1973-01-01

Dredge hauls of fresh submarine basalt collected from the axis of the Reykjanes Ridge (Mid-Atlantic Ridge) south of Iceland were taken aboard R/ V TRIDENT in 1967 and 1971. The samples show systematic changes as the water depth of collection (and eruption) decreases: radially elongate vesicles and concentric zones of vesicles appear at about 700 m depth and are conspicuous to shallow water; the smoothed volume percent of vesicles increases from 5% at 1000 m, 10% at 700 m, to 16% at 500 m, and the scatter in degree of vesicularity increases in shallower water; specific gravity decreases from 2.7??0.1 at 1000 m to 2.3??0.3 at 100 m. Bulk sulfur content for the outer 2 cm averages 843 ppm up to a depth of 200 m, then drops off rapidly in shallower water owing to degassing. Sulfur content below 200 m is independent of depth (or geographic position), and the melt is apparently saturated with sulfur, but the excess cannot escape the lava unless another vehicle carries it out. Only shallower than 200 m, where intense vesiculation of other gases occurs can excess sulfur be lost from the lava erupting on the sea floor. H2O+110?? averages about 0.35 percent and H2O+150?? about 0.25 percent, and both apparently decrease in water shallower than 200 m as a result of degassing. H2O+ (below 200 m) decreases with distance from Iceland or increasing depth, presumably as a result of either adsorption of water on the surface of shallower, more vesicular rocks; or more likely due to the presence of the Iceland hot mantle plume supplying undifferentiated primordial material, relative to lavas of the Reykjanes Ridge supplied from the low velocity layer already depleted in volatiles and large lithophile elements. The H2O+110??/S ratio of lava erupting below 200 m water depth ranges from 3 to 5 which is comparable to reliable gas analyses from oceanic basaltic volcanoes. ?? 1973 Springer-Verlag.

[Similarities and differences in absorption characteristics and composition of CDOM between Taihu Lake and Chaohu Lake].

PubMed

Shi, Kun; Li, Yun-mei; Wang, Qiao; Yang, Yu; Jin, Xin; Wang, Yan-fei; Zhang, Hong; Yin, Bin

2010-05-01

Field experiments are conducted separately in Taihu Lake and Chaohu Lake on Apr. and Jun. 2009. The changes in absorption spectra of chromophoric dissolved organic matter (CDOM) characteristics are analyzed using spectral differential analysis technology. According the spectral differential characteristic of absorption coefficient; absorption coefficient from 240 to 450 nm is divided into different stages, and the value of spectral slope S is calculated in each stage. In Stage A, S value of CDOM in Taihu Lake and Chaohu Lake are 0.0166-0.0102 nm(-1) [average (0.0132 +/- 0.0017) nm(-1)], 0.029-0.017 nm(-1) [average (0.0214 +/- 0.0024) nm(-1)]. In Stage B, S values are 0.0187-0.0148 nm(-1) [average (0.0169 +/- 0.001) nm(-1)], 0.0179-0.0055 nm(-1) [average (0.0148 +/- 0.002) nm(-1)]. In Stage C, S values are 0.0208-0.0164 nm(-1) [average (0.0186 +/- 0.0009) nm(-1)], 0.0253-0.0161 nm(-1) [average (0.0197 +/- 0.002) nm(-1)]. The results can be concluded as: (1) Absorption coefficient of water in Taihu Lake, and its contribution to absorption of each component is less than that of water in Chaohu Lake, however the standardized absorption coefficient is larger than that in Chaohu Lake. (2) Both in Taihu Lake and Chaohu Lake, derivative spectra of CDOM absorption coefficient reached valley at 260nm, then rise to top at 290 nm, CDOM absorption coefficient can be delivered into three stages. (3) Generally speaking, content of CDOM in Taihu Lake is less than in Chaohu Lake. (4) pectrum slope (S value) of CDOM is related to composition of CDOM, when content of humic acid in CDOM gets higher, S value of Stage B is the most sensitive value, then is the S value of Stage C. Oppositely, S value of Stage B gets the most sensitive value, then is the S value of Stage A; the least sensitive value is in Stage B.

Variations in the chemical properties of landfill leachate

NASA Astrophysics Data System (ADS)

Chu, L. M.; Cheung, K. C.; Wong, M. H.

1994-01-01

Landfill leachates were collected and their chemical properties analyzed once every two months over a ten-month period from the Gin Drinkers' Bay (GDB) and Junk Bay (JB) landfills. The contents of solids, and inorganic and organic components fluctuated considerably with time. In general, the chemical properties of the two leachates correlated negatively ( P<0.05) with the amounts of rainfall prior to the sampling periods. However, magnesium and pH of the leachates remained relatively constant with respect to sampling time. The JB leachate contained higher average contents of solids and inorganic and organic matter than those of GDB with the exception of trace metals. Trace metals were present in the two leachates in trace quantities (<1.0 mg/liter). The concentrations of average ammoniacal nitrogen were 1040 and 549 mg/liter, while chemical oxygen demand (COD) values were 767 and 695 mg/liter for JB and GDB leachates, respectively. These results suggest that the leachates need further treatment before they can be discharged to the coastal waters.

The effect of leaf size on the microwave backscattering by corn

NASA Technical Reports Server (NTRS)

Paris, J. F.

1986-01-01

Attema and Ulaby (1978) proposed the cloud model to predict the microwave backscattering properties of vegetation. This paper describes a modification in which the biophysical properties and microwave properties of vegetation are related at the level of the individual scatterer (e.g., the leaf or the stalk) rather than at the level of the aggregated canopy (e.g., the green leaf area index). Assuming that the extinction cross section of an average leaf was proportional to its water content, that a power law relationship existed between the backscattering cross section of an average green corn leaf and its area, and that the backscattering coefficient of the surface was a linear function of its volumetric soil moisture content, it is found that the explicit inclusion of the effects of corn leaf size in the model led to an excellent fit between the observed and predicted backscattering coefficients. Also, an excellent power law relationship existed between the backscattering cross section of a corn leaf and its area.

Enzyme-resistant dextrins from potato starch for potential application in the beverage industry.

PubMed

Jochym, Kamila Kapusniak; Nebesny, Ewa

2017-09-15

The objective of this study was to produce soluble enzyme-resistant dextrins by microwave heating of potato starch acidified with small amounts of hydrochloric and citric acids and to characterize their properties. Twenty five samples were initially made and their solubility was determined. Three samples with the highest water solubility were selected for physico-chemical (dextrose equivalent, molecular weight distribution, pasting characteristics, retrogradation tendency), total dietary fiber (TDF) analysis, and stability tests. TDF content averaged 25%. Enzyme-resistant dextrins practically did not paste, even at 20% samples concentration, and were characterized by low retrogradation tendency. The stability of the samples, expressed as a percentage increase of initial and final reducing sugar content, at low pH and during heating at low pH averaged 10% and 15% of the initial value, respectively. The results indicate that microwave heating could be an effective and efficient method of producing highly-soluble, low-viscous, and enzyme-resistant potato starch dextrins. Copyright © 2017 Elsevier Ltd. All rights reserved.

Heating the Ice-Covered Lakes of the McMurdo Dry Valleys, Antarctica - Decadal Trends in Heat Content, Ice Thickness, and Heat Exchange

NASA Astrophysics Data System (ADS)

Gooseff, M. N.; Priscu, J. C.; Doran, P. T.; Chiuchiolo, A.; Obryk, M.

2014-12-01

Lakes integrate landscape processes and climate conditions. Most of the permanently ice-covered lakes in the McMurdo Dry Valleys, Antarctica are closed basin, receiving glacial melt water from streams for 10-12 weeks per year. Lake levels rise during the austral summer are balanced by sublimation of ice covers (year-round) and evaporation of open water moats (summer only). Vertical profiles of water temperature have been measured in three lakes in Taylor Valley since 1988. Up to 2002, lake levels were dropping, ice covers were thickening, and total heat contents were decreasing. These lakes have been gaining heat since the mid-2000s, at rates as high as 19.5x1014 cal/decade). Since 2002, lake levels have risen substantially (as much as 2.5 m), and ice covers have thinned (1.5 m on average). Analyses of lake ice thickness, meteorological conditions, and stream water heat loads indicate that the main source of heat to these lakes is from latent heat released when ice-covers form during the winter. An aditional source of heat to the lakes is water inflows from streams and direct glacieal melt. Mean lake temperatures in the past few years have stabilized or cooled, despite increases in lake level and total heat content, suggesting increased direct inflow of meltwater from glaciers. These results indicate that McMurdo Dry Valley lakes are sensitive indicators of climate processes in this polar desert landscape and demonstrate the importance of long-term data sets when addressing the effects of climate on ecosystem processes.

Health risk assessment of drinking arsenic-containing groundwater in Hasilpur, Pakistan: effect of sampling area, depth, and source.

PubMed

Tabassum, Riaz Ahmad; Shahid, Muhammad; Dumat, Camille; Niazi, Nabeel Khan; Khalid, Sana; Shah, Noor Samad; Imran, Muhammad; Khalid, Samina

2018-02-10

Currently, several news channels and research publications have highlighted the dilemma of arsenic (As)-contaminated groundwater in Pakistan. However, there is lack of data regarding groundwater As content of various areas in Pakistan. The present study evaluated As contamination and associated health risks in previously unexplored groundwater of Hasilpur-Pakistan. Total of 61 groundwater samples were collected from different areas (rural and urban), sources (electric pump, hand pump, and tubewell) and depths (35-430 ft or 11-131 m). The water samples were analyzed for As level and other parameters such as pH, electrical conductivity, total dissolved solids, cations, and anions. It was found that 41% (25 out of 61) water samples contained As (≥ 5 μg/L). Out of 25 As-contaminated water samples, 13 water samples exceeded the permissible level of WHO (10 μg/L). High As contents have been found in tubewell samples and at high sampling depths (> 300 ft). The major As-contaminated groundwater in Hasilpur is found in urban areas. Furthermore, health risk and cancer risk due to As contamination were also assessed with respect to average daily dose (ADD), hazard quotient (HQ), and carcinogenic risk (CR). The values of HQ and CR of As in Hasilpur were up to 58 and 0.00231, respectively. Multivariate analysis revealed a positive correlation between groundwater As contents, pH, and depth in Hasilpur. The current study proposed the proper monitoring and management of well water in Hasilpur to minimize the As-associated health hazards.

Effects of a Circulating-water Garment and Forced-air Warming on Body Heat Content and Core Temperature

PubMed Central

Taguchi, Akiko; Ratnaraj, Jebadurai; Kabon, Barbara; Sharma, Neeru; Lenhardt, Rainer; Sessler, Daniel I.

2005-01-01

Background: Forced-air warming is sometimes unable to maintain perioperative normothermia. We therefore compared heat transfer, regional heat distribution, and core rewarming of forced-air warming with a novel circulating-water garment. Methods: Nine volunteers were each evaluated on two randomly ordered study days. They were anesthetized and cooled to a core temperature near 34°C. The volunteers were subsequently warmed for 2.5 hours with either a circulating-water garment or forced-air cover. Overall, heat balance was determined from the difference between cutaneous heat loss (thermal flux transducers) and metabolic heat production (oxygen consumption). Average arm and leg (peripheral) tissue temperatures were determined from 18 intramuscular needle thermocouples, 15 skin thermal flux transducers, and “deep” arm and foot thermometers. Results: Heat production (≈ 60 kcal/h) and loss (≈45 kcal/h) were similar with each treatment before warming. The increase in heat transfer across anterior portions of the skin surface was similar with each warming system (≈65 kcal/h). Forced-air warming had no effect on posterior heat transfer whereas circulating-water transferred 21 ± 9 kcal/h through the posterior skin surface after a half hour of warming. Over 2.5 h, circulating-water thus increased body heat content 56% more than forced air. Core temperatures thus increased faster than with circulating water than forced air, especially during the first hour, with the result that core temperature was 1.1 ± 0.7°C greater after 2.5 h (P < 0.001). Peripheral tissue heat content increased twice as much as core heat content with each device, but the core-to-peripheral tissue temperature gradient remained positive throughout the study. Conclusions: The circulating-water system transferred more heat than forced air, with the difference resulting largely from posterior heating. Circulating water rewarmed patients 0.4°C/h faster than forced air. A substantial peripheral-to-core tissue-temperature gradient with each device indicated that peripheral tissues insulated the core, thus slowing heat transfer. PMID:15114200

[Characteristics of soil moisture variation in different land use types in the hilly region of the Loess Plateau, China].

PubMed

Tang, Min; Zhao, Xi Ning; Gao, Xiao Dong; Zhang, Chao; Wu, Pu Te

2018-03-01

Soil water availability is a key factor restricting the ecological construction and sustainable land use in the loess hilly region. It is of great theoretical and practical significance to understand the soil moisture status of different land use types for the vegetation restoration and the effective utilization of land resources in this area. In this study, EC-5 soil moisture sensors were used to continuously monitor the soil moisture content in the 0-160 cm soil profile in the slope cropland, terraced fields, jujube orchard, and grassland during the growing season (from May to October) in the Yuanzegou catchment on the Loess Plateau, to investigate soil moisture dynamics in these four typical land use types. The results showed that there were differences in seasonal variation, water storage characteristics, and vertical distribution of soil moisture under different land use types in both the normal precipitation (2014) and dry (2015) years. The terraced fields showed good water retention capacity in the dry year, with the average soil moisture content of 0-60 cm soil layer in the growing season being 2.6%, 4.2%, and 1.8% higher than that of the slope cropland, jujube orchard, and grassland (all P<0.05). The water storage of 0-160 cm soil profile was 43.90, 32.08, and 18.69 mm higher than that of slope cropland, jujube orchard, and grassland, respectively. In the normal precipitation year, the average soil moisture content of 0-60 cm soil layer in jujube orchard in the growing season was 2.9%, 3.8%, and 4.5% lower than that of slope cropland, terraced fields, and grassland, respectively (all P<0.05). In the dry year, the effective soil water storage of 0-160 cm soil profile in the jujube orchard accounted for 35.0% of the total soil water storage. The grey relational grade between the soil moisture in the surface layer (0-20 cm) and soil moisture in the middle layer (20-100 cm) under different land use types was large, and the trend for the similarity degree of soil moisture variation followed terraced fields > grassland > slope cropland > jujube orchard. The slope cropland in this area could be transformed into terraced fields to improve the utilization of precipitation and promote the construction of ecological agriculture. Aiming at resolving the severe water shortage in the rain-fed jujube orchard for the sustainable development of jujube orchard in the loess hilly region, appropriate water management measures should be taken to reduce the water consumption of jujube trees and other inefficient water consumption.

Validation Tests of a Non-Nuclear Combined Asphalt and Soil Density Gauge

DTIC Science & Technology

2014-04-01

limit if applicable. This approach was considered as if this device was to be used on a construction project for quality control where the material...military contingency construction activities, because they are not sufficiently accurate compared to the NDG for quality control use in permanent...binder. Nominal asphalt content with water included was 5.2. m Average results from producer’s Quality Control (QC) testing. The list of instruments

Estimating Temporal Redistribution of Surface Melt Water into Upper Stratigraphy of the Juneau Icefield, Alaska

NASA Astrophysics Data System (ADS)

Wilner, J.; Smith, B.; Moore, T.; Campbell, S. W.; Slavin, B. V.; Hollander, J.; Wolf, J.

2015-12-01

The redistribution of winter accumulation from surface melt into firn or deeper layers (i.e. internal accumulation) remains a poorly understood component of glacier mass balance. Winter accumulation is usually quantified prior to summer melt, however the time window between accumulation and the onset of melt is minimal so this is not always possible. Studies which are initiated following the onset of summer melt either neglect sources of internal accumulation or attempt to estimate melt (and therefore winter accumulation uncertainty) through a variety of modeling methods. Here, we used ground-penetrating radar (GPR) repeat common midpoint (CMP) surveys with supporting common offset surveys, mass balance snow pits, and probing to estimate temporal changes in water content within the winter accumulation and firn layers of the southern Juneau Icefield, Alaska. In temperate glaciers, radio-wave velocity is primarily dependent on water content and snow or firn density. We assume density changes are temporally slow relative to water flow through the snow and firn pack, and therefore infer that changing radio-wave velocities measured by successive CMP surveys result from flux in surface melt through deeper layers. Preliminary CMP data yield radio-wave velocities of 0.15 to 0.2 m/ns in snowpack densities averaging 0.56 g cm-3, indicating partially to fully saturated snowpack (4-9% water content). Further spatial-temporal analysis of CMP surveys is being conducted. We recommend that repeat CMP surveys be conducted over a longer time frame to estimate stratigraphic water redistribution between the end of winter accumulation and maximum melt season. This information could be incorporated into surface energy balance models to further understanding of the influence of internal accumulation on glacier mass balance.

MODIS-derived atmospheric water vapor (AWV) content and its correlation to land use and land cover in Northeast China

NASA Astrophysics Data System (ADS)

Song, Kaishan; Wu, Junjie; Li, Lin; Wang, Zongming; Lu, Dongmei; Du, Jia; Zhang, Bai

2010-08-01

Atmospheric water vapor (AWV) content is closely related to precipitation that in turn has effects on the productivity of agricultural, forestry and range land. MODIS images have been used for AWV retrieval, and the method uses either two (0.841-0.876 μm and 0.915-0.965 μm) or three (0.841-0.876, 0.915-0.965 and 1.230-0-1.250 μm) MODIS channel ratios. We applied both methods to the MODIS data over Northeast China acquired from June to August, 2008 to retrieve AWV content, and the results were validated on ground observed data from 10 radio sonde stations characterized by various land cover. The bulk results indicate that the two-channel ratio outperformed the three-channel ratio based on the coefficient of determination R2 = 0.81 vs. 0.78. The validation results for individual land cover types also support this observation with R2 = 0.92 vs. 0.84 for woodland, 0.82 vs. 0.79 for cropland, 0.90 vs. 0.86 for grassland and 0.673 vs. 0.669 for urban areas. The spatial distribution of AWV derived using the two-channel ratio method was correlated to land-use classification data, and a high correlation was evident when other conditions were similar. With the exception of dry cropland, the amount of average water vapor content over different land use types demonstrates a consistent order: water-body > paddy-field > woodland > grassland > barren for the analyzed multi-temporal MODIS data. This order partially matches the evapotranspiration pattern of underlying surface, and future work is required for analyzing the association of the landscape pattern with AWV in the region.

Ground Field-Based Hyperspectral Imaging: A Preliminary Study to Assess the Potential of Established Vegetation Indices to Infer Variation in Water-Use Efficiency.

NASA Astrophysics Data System (ADS)

Pelech, E. A.; McGrath, J.; Pederson, T.; Bernacchi, C.

2017-12-01

Increases in the global average temperature will consequently induce a higher occurrence of severe environmental conditions such as drought on arable land. To mitigate these threats, crops for fuel and food must be bred for higher water-use efficiencies (WUE). Defining genomic variation through high-throughput phenotypic analysis in field conditions has the potential to relieve the major bottleneck in linking desirable genetic traits to the associated phenotypic response. This can subsequently enable breeders to create new agricultural germplasm that supports the need for higher water-use efficient crops. From satellites to field-based aerial and ground sensors, the reflectance properties of vegetation measured by hyperspectral imaging is becoming a rapid high-throughput phenotyping technique. A variety of physiological traits can be inferred by regression analysis with leaf reflectance which is controlled by the properties and abundance of water, carbon, nitrogen and pigments. Although, given that the current established vegetation indices are designed to accentuate these properties from spectral reflectance, it becomes a challenge to infer relative measurements of WUE at a crop canopy scale without ground-truth data collection. This study aims to correlate established biomass and canopy-water-content indices with ground-truth data. Five bioenergy sorghum genotypes (Sorghum bicolor L. Moench) that have differences in WUE and wild-type Tobacco (Nicotiana tabacum var. Samsun) under irrigated and rainfed field conditions were examined. A linear regression analysis was conducted to determine if variation in canopy water content and biomass, driven by natural genotypic and artificial treatment influences, can be inferred using established vegetation indices. The results from this study will elucidate the ability of ground field-based hyperspectral imaging to assess variation in water content, biomass and water-use efficiency. This can lead to improved opportunities to select ideal genotypes for an increasing water-limited environment and to help parameterize and validate terrestrial vegetation models that require a better representation of genetic variation within crop species.

Genetic Diversity of Daphnia pulex in the Middle and Lower Reaches of the Yangtze River

PubMed Central

Wang, Wenping; Zhang, Kun; Deng, Daogui; Zhang, Ya-Nan; Peng, Shuixiu; Xu, Xiaoxue

2016-01-01

Increased human activities and environmental changes may lead to genetic diversity variations of Cladocerans in water. Daphnia pulex are distributed throughout the world and often regarded as a model organism. The 16S rDNA, cytochrome c oxidase subunit I (COI), and 18S genes were used as molecular marks. The genetic diversity and phylogeny of D. pulex obtained from 10 water bodies in the middle and lower reaches of the Yangtze River were studied. For 16S rDNA, COI gene, and 18S gene, the A+T content (65.4%, 58.4%, and 54.6%) was significantly higher than the G+C content (34.6%, 41.6% and 45.4%). This result was consistent with higher A and T contents among invertebrates. Based on the genetic distances of 16S rDNA and COI genes, the genetic differences of D. pulex from 10 water bodies located in the middle and lower reaches of the Yangtze River in China was minimal (0%–0.8% for 16S rDNA and 0%–1.5% for COI gene). However, D. pulex evolved into two branches in the phylogenetic trees, which coincided with its geographical distribution. Compared with D. pulex from other countries, the average genetic distance of D. pulex obtained from 10 water bodies in the middle and lower reaches of the Yangtze River reached 9.1%–10.5%, thereby indicating that D. pulex may have evolved into different subspecies. PMID:27015539

Cooking rice in excess water reduces both arsenic and enriched vitamins in the cooked grain.

PubMed

Gray, Patrick J; Conklin, Sean D; Todorov, Todor I; Kasko, Sasha M

2016-01-01

This paper reports the effects of rinsing rice and cooking it in variable amounts of water on total arsenic, inorganic arsenic, iron, cadmium, manganese, folate, thiamin and niacin in the cooked grain. We prepared multiple rice varietals both rinsed and unrinsed and with varying amounts of cooking water. Rinsing rice before cooking has a minimal effect on the arsenic (As) content of the cooked grain, but washes enriched iron, folate, thiamin and niacin from polished and parboiled rice. Cooking rice in excess water efficiently reduces the amount of As in the cooked grain. Excess water cooking reduces average inorganic As by 40% from long grain polished, 60% from parboiled and 50% from brown rice. Iron, folate, niacin and thiamin are reduced by 50-70% for enriched polished and parboiled rice, but significantly less so for brown rice, which is not enriched.

The Mars water cycle at other epochs - Recent history of the polar caps and layered terrain

NASA Technical Reports Server (NTRS)

Jakosky, Bruce M.; Henderson, Bradley G.; Mellon, Michael T.

1993-01-01

A numerical model is presented of the integrated role of seasonal water cycle on the evolution of polar deposits on Mars over the last 10 million years. From the model, it is concluded that the only major difference between the polar caps which affects their long-term behavior is ultimately the difference in their elevations. Because of that difference, there is a preference for CO2 frost to stay longer on the northern polar cap. The average difference in sublimation at the caps results in a net south-to-north transport of water ice over long time scales. Superimposed on any long-term behavior is a transfer of water ice between the caps on the 10 exp 5 - 10 exp 6 yr time scales. The amount of water exchanged is small compared to the total ice content of the polar deposits.

The Mars water cycle at other epochs - Recent history of the polar caps and layered terrain

NASA Astrophysics Data System (ADS)

Jakosky, B. M.; Henderson, B. G.; Mellon, M. T.

1993-04-01

A numerical model is presented of the integrated role of seasonal water cycle on the evolution of polar deposits on Mars over the last 10 million years. From the model, it is concluded that the only major difference between the polar caps which affects their long-term behavior is ultimately the difference in their elevations. Because of that difference, there is a preference for CO2 frost to stay longer on the northern polar cap. The average difference in sublimation at the caps results in a net south-to-north transport of water ice over long time scales. Superimposed on any long-term behavior is a transfer of water ice between the caps on the 10 exp 5 - 10 exp 6 yr time scales. The amount of water exchanged is small compared to the total ice content of the polar deposits.

Forecasting the quality of water-suppressed 1 H MR spectra based on a single-shot water scan.

PubMed

Kyathanahally, Sreenath P; Kreis, Roland

2017-08-01

To investigate whether an initial non-water-suppressed acquisition that provides information about the signal-to-noise ratio (SNR) and linewidth is enough to forecast the maximally achievable final spectral quality and thus inform the operator whether the foreseen number of averages and achieved field homogeneity is adequate. A large range of spectra with varying SNR and linewidth was simulated and fitted with popular fitting programs to determine the dependence of fitting errors on linewidth and SNR. A tool to forecast variance based on a single acquisition was developed and its performance evaluated on simulated and in vivo data obtained at 3 Tesla from various brain regions and acquisition settings. A strong correlation to real uncertainties in estimated metabolite contents was found for the forecast values and the Cramer-Rao lower bounds obtained from the water-suppressed spectra. It appears to be possible to forecast the best-case errors associated with specific metabolites to be found in model fits of water-suppressed spectra based on a single water scan. Thus, nonspecialist operators will be able to judge ahead of time whether the planned acquisition can possibly be of sufficient quality to answer the targeted clinical question or whether it needs more averages or improved shimming. Magn Reson Med 78:441-451, 2017. © 2016 International Society for Magnetic Resonance in Medicine. © 2016 International Society for Magnetic Resonance in Medicine.

[Photosynthetic rate, transpiration rate, and water use efficiency of cotton canopy in oasis edge of Linze].

PubMed

Xie, Ting-Ting; Su, Pei-Xi; Gao, Song

2010-06-01

The measurement system of Li-8100 carbon flux and the modified assimilation chamber were used to study the photosynthetic characteristics of cotton (Gossypium hirsutum L.) canopy in the oasis edge region in middle reach of Heihe River Basin, mid Hexi Corridor of Gansu. At the experimental site, soil respiration and evaporation rates were significantly higher in late June than in early August, and the diurnal variation of canopy photosynthetic rate showed single-peak type. The photosynthetic rate was significantly higher (P < 0.01) in late June than in early August, with the daily average value being (43.11 +/- 1.26) micromol CO2 x m(-2) x s(-1) and (24.53 +/- 0.60) micromol CO2 x m(-2) x s(-1), respectively. The diurnal variation of canopy transpiration rate also presented single-peak type, with the daily average value in late June and early August being (3.10 +/- 0.34) mmol H2O x m(-2) x s(-1) and (1.60 +/- 0.26) mmol H2O x m(-2) x s(-1), respectively, and differed significantly (P < 0.01). The daily average value of canopy water use efficiency in late June and early August was (15.67 +/- 1.77) mmol CO2 x mol(-1) H2O and (23.08 +/- 5.54) mmol CO2 x mol(-1) H2O, respectively, but the difference was not significant (P > 0.05). Both in late June and in early August, the canopy photosynthetic rate was positively correlated with air temperature, PAR, and soil moisture content, suggesting that there was no midday depression of photosynthesis in the two periods. In August, the canopy photosynthetic rate and transpiration rate decreased significantly, because of the lower soil moisture content and leaf senescence, but the canopy water use efficiency had no significant decrease.

Ground-based measurements with the ADRON active gamma-ray and neutron spectrometer designed for lunar and Martian landing missions

NASA Astrophysics Data System (ADS)

Litvak, M. L.; Golovin, D. V.; Kolesnikov, A. B.; Vostrukhin, A. A.; Djachkova, M. V.; Kozyrev, A. S.; Mitrofanov, I. G.; Mokrousov, M. I.; Sanin, A. B.

2017-05-01

This paper outlines the main research objectives and gives a description of the ADRON active gamma-ray and neutron spectrometer, which is designed specifically for the Russian lunar landing missions Luna-Glob and Luna-Resurs and for the ExoMars Martian landing platform. The measurement technique is described. The first ground-based calibration results are presented, making it possible to assess the sensitivity of the ADRON instruments in determining the average water content of the underlying surface in the range from 1% (dry ground) to 100% (water ice) to a depth of 0.5 m.

Water and tritium movement through the unsaturated zone at a low-level radioactive-waste disposal site near Sheffield, Illinois, 1981-85

USGS Publications Warehouse

Mills, Patrick C.; Healy, Richard W.

1993-01-01

The movement of water and tritium through the unsaturated zone was studied at a low-level radioactive-waste disposal site near Sheffield, Bureau County, Illinois, from 1981 to 1985. Water and tritium movement occurred in an annual, seasonally timed cycle; recharge to the saturated zone generally occurred in the spring and early summer. Mean annual precipitation (1982-85) was 871 mm (millimeters); mean annual recharge to the disposal trenches (July 1982 through June 1984) was estimated to be 107 mm. Average annual tritium flux below the study trenches was estimated to be 3.4 mCi/yr (millicuries per year). Site geology, climate, and waste-disposal practices influenced the spatial and temporal variability of water and tritium movement. Of the components of the water budget, evapotranspiration contributed most to the temporal variability of water and tritium movement. Disposal trenches are constructed in complexly layered glacial and postglacial deposits that average 17 m (meters) in thickness and overlie a thick sequence of Pennsylvanian shale. The horizontal saturated hydraulic conductivity of the clayey-silt to sand-sized glacial and postglacial deposits ranges from 4.8x10 -1 to 3.4x10 4 mm/d (millimeters per day). A 120-m-long horizontal tunnel provided access for hydrologic measurements and collection of sediment and water samples from the unsaturated and saturated geologic deposits below four disposal trenches. Trench-cover and subtrench deposits were monitored with soil-moisture tensiometers, vacuum and gravity lysimeters, piezometers, and a nuclear soil-moisture gage. A cross-sectional, numerical ground-water-flow model was used to simulate water movement in the variably saturated geologic deposits in the tunnel area. Concurrent studies at the site provided water-budget data for estimating recharge to the disposal trenches. Vertical water movement directly above the trenches was impeded by a zone of compaction within the clayey-silt trench covers. Water entered the trenches primarily at the trench edges where the compacted zone was absent and the cover was relatively thin. Collapse holes in the trench covers that resulted from inadequate compaction of wastes within the trenches provided additional preferential pathways for surface-water drainage into the trenches; drainage into one collapse hole during a rainstorm was estimated to be 1,700 L (liters). Till deposits near trench bases induced lateral water and tritium movement. Limited temporal variation in water movement and small flow gradients (relative to the till deposits) were detected in the unsaturated subtrench sand deposit; maximum gradients during the spring recharge period averaged 1.62 mm/mm (millimeter per millimeter). Time-of-travel of water moving from the trench covers to below the trenches was estimated to be as rapid as 41 days (assuming individual water molecules move this distance in one recharge cycle). Tritium concentrations in water from the unsaturated zone ranged from 200 (background) to 10,000,000 pCi/L (picocuries per liter). Tritium concentrations generally were higher below trench bases (averaging 91,000 pCi/L) than below intertrench sediments (averaging 3,300 pCi/L), and in the subtrench Toulon Member of the Glasford Formation (sand) (averaging 110,000 pCi/L) than in the Hulick Till Member of the Glasford Formation (clayey silt) (averaging 59,000 pCi/L). Average subtrench tritium concentration increased from 28,000 to 100,000 pCi/L during the study period. Within the trench covers, there was a strong seasonal trend in tritium concentrations; the highest concentrations occurred in late summer when soil-moisture contents were at a minimum. Subtrench tritium movement occurred in association with the annual cycle of water movement, as well as independently of the cycle, in apparent response to continuous water movement through the subtrench sand deposits and to the deterioration of trench-waste containers. The increase in concen

Water and tritium movement through the unsaturated zone at a low-level radioactive-waste disposal site near Sheffield, Illinois, 1981-85

USGS Publications Warehouse

Mills, Patrick C.; Healy, R.W.

1991-01-01

The movement of water and tritium through the unsaturated zone was studied at a low-level radioactive-waste disposal site near Sheffield, Bureau County, Illinois, from 1981 to 1985. Water and tritium movement occurred in an annual, seasonally timed cycle; recharge to the saturated zone generally occurred in the spring and early summer. Mean annual precipitation (1982-85) was 871 millimeters; mean annual recharge to the disposal trenches (July 1982 through June 1984) was estimated to be 107 millimeters. Average annual tritium flux below the study trenches was estimated to be 3.4 millicuries per year. Site geology, climate, and waste-disposal practices influenced the spatial and temporal variability of water and tritium movement. Of the components of the water budget, evapotranspiration contributed most to the temporal variability of water and tritium movement. Disposal trenches are constructed in complexly layered glacial and postglacial deposits that average 17 meters in thickness and overlie a thick sequence of Pennsylvanian shale. The horizontal saturated hydraulic conductivity of the clayey-silt to sand-sized glacial and postglacial deposits ranges from 4.8x10^-1 to 3.4x10^4 millimeters per day. A 120-meter-long horizontal tunnel provided access for hydrologic measurements and collection of sediment and water samples from the unsaturated and saturated geologic deposits below four disposal trenches. Trench-cover and subtrench deposits were monitored with soil-moisture tensiometers, vacuum and gravity lysimeters, piezometers, and a nuclear soil-moisture gage. A cross-sectional, numerical ground-water-flow model was used to simulate water movement in the variably saturated geologic deposits in the tunnel area. Concurrent studies at the site provided water-budget data for estimating recharge to the disposal trenches. Vertical water movement directly above the trenches was impeded by a zone of compaction within the clayey-silt trench covers. Water entered the trenches primarily at the trench edges where the compacted zone was absent and the cover was relatively thin. Collapse holes in the trench covers that resulted from inadequate compaction of wastes within the trenches provided additional preferential pathways for surface-water drainage into the trenches; drainage into one collapse hole during a rainstorm was estimated to be 1,700 liters. Till deposits near trench bases induced lateral water and tritium movement. Limited temporal variation in water movement and small flow gradients (relative to the till deposits) were detected in the unsaturated subtrench sand deposit; maximum gradients during the spring recharge period averaged 1.62 millimeters per millimeter. Time-of-travel of water moving from the trench covers to below the trenches was estimated to be as rapid as 41 days (assuming individual water molecules move this distance in one recharge cycle). Tritium concentrations in water from the unsaturated zone ranged from 200 (background) to 10,000,000 pCi/L (picocuries per liter). Tritium concentrations generally were higher below trench bases (averaging 91,000 pCi/L) than below intertrench sediments (averaging 3,300 pCi/L), and in the subtrench Toulon Member of the Glasford Formation (sand) (averaging 110,000 pCi/L) than in the Hulick Till Member of the Glasford Formation (clayey silt) (averaging 59,000 pCi/L). Average subtrench tritium concentration increased from 28,000 to 100,000 pCi/L during the study period. Within the trench covers, there was a strong seasonal trend in tritium concentrations; the highest concentrations occurred in late summer when soil-moisture contents were at a minimum. Subtrench tritium movement occurred in association with the annual cycle of water movement, as well as independently of the cycle, in apparent response to continuous water movement through the subtrench sand deposits and to the deterioration of trench-waste containers. The increase in concentrations of tritium with incre

Summer spatial patterning of chukars in relation to free water in Western Utah

USGS Publications Warehouse

Larsen, R.T.; Bissonette, J.A.; Flinders, J.T.; Hooten, M.B.; Wilson, T.L.

2010-01-01

Free water is considered important to wildlife in arid regions. In the western United States, thousands of water developments have been built to benefit wildlife in arid landscapes. Agencies and researchers have yet to clearly demonstrate their effectiveness. We combined a spatial analysis of summer chukar (Alectoris chukar) covey locations with dietary composition analysis in western Utah. Our specific objectives were to determine if chukars showed a spatial pattern that suggested association with free water in four study areas and to document summer dietary moisture content in relation to average distance from water. The observed data for the Cedar Mountains study area fell within the middle of the random mean distance to water distribution suggesting no association with free water. The observed mean distance to water for the other three areas was much closer than expected compared to a random spatial process, suggesting the importance of free water to these populations. Dietary moisture content of chukar food items from the Cedar Mountains (59%) was significantly greater (P < 0.05) than that of birds from Box Elder (44%) and Keg-Dugway (44%). Water developments on the Cedar Mountains are likely ineffective for chukars. Spatial patterns on the other areas, however, suggest association with free water and our results demonstrate the need for site-specific considerations. Researchers should be aware of the potential to satisfy water demand with pre-formed and metabolic water for a variety of species in studies that address the effects of wildlife water developments. We encourage incorporation of spatial structure in model error components in future ecological research. ?? Springer Science+Business Media B.V. 2009.

The role of water in generating Fe-depletion and the calc-alkaline trend

NASA Astrophysics Data System (ADS)

Zimmer, M. M.; Plank, T.

2006-12-01

Describing a magmatic suite as calc-alkaline (CA) or tholeiitic (TH) is a first order characterization, but existing classification schemes (AFM ternary plots and FeO*/MgO vs. SiO2) may convolute magmatic processes and can result in contradictory classification. The salient feature of TH vs. CA evolution is the extent of Fe enrichment or depletion in the magma. A plot of FeO* vs. MgO provides the most straightforward way to quantify Fe enrichment and to develop models for its origin. We present a new quantitative classification utilizing the FeO*-MgO plot, the tholeiitic index (THI) = Fe3-5/Fe8 (Fe3-5=average FeO* at 3-5 wt% MgO; Fe8=FeO* at 8 wt% MgO). THI of 1.2 indicates 20% FeO* enrichment from a magma's starting composition at Fe8, while THI of 0.8 indicates 20% depletion in FeO*. A magmatic suite is CA if THI is <1, and TH if THI is >1. Arcs range from 0.6 to 1.1, back arc basins from 1.1-1.3, and MORBs are \\ge1.6. This classification allows comparison of magmatic evolution on a global basis, regardless of starting composition, and is useful for quantitative comparison to liquid line of descent models. Hypotheses for generating CA magmas include high water contents, high pressure of crystallization, high oxygen fugacity, and high Mg# andesitic starting compositions. In order to test the control of H2O, we compare the THI to average magmatic water contents from undegassed melt inclusions and glasses (S>1000 ppm or CO2>50 ppm) from twenty-eight arc volcanoes and back arc basins, including new water contents from seven Aleutian volcanoes. The resulting negative correlation (R2=0.8) between water concentration and THI (with end-members at 0.8 wt% H2O, THI =1.3 and 6.1 wt% H2O, THI = 0.6) suggests water plays a fundamental role in generating the CA fractionation trend. MORB data plot off the trend at a higher THI, possibly related to lower oxygen fugacity during melting and/or crystallization. Models using the pMelts program are consistent with experimentally- and observationally-demonstrated effects of water on suppression of plagioclase and early formation of oxides relative to silicates during magma fractionation, and the resulting FeO* depletion with respect to decreasing MgO.

Characterizing roots and water uptake in a ground cover rice production system

PubMed Central

Li, Sen; Zuo, Qiang; Wang, Xiaoyu; Ma, Wenwen; Jin, Xinxin; Shi, Jianchu; Ben-Gal, Alon

2017-01-01

Background and aims Water-saving ground cover rice production systems (GCRPS) are gaining popularity in many parts of the world. We aimed to describe the characteristics of root growth, morphology, distribution, and water uptake for a GCRPS. Methods A traditional paddy rice production system (TPRPS) was compared with GCRPS in greenhouse and field experiments. In the greenhouse, GCRPS where root zone average soil water content was kept near saturation (GCRPSsat), field capacity (GCRPSfwc) and 80% field capacity (GCRPS80%), were evaluated. In a two-year field experiment, GCRPSsat and GCRPS80% were applied. Results Similar results were found in greenhouse and field experiments. Before mid-tillering the upper soil temperature was higher for GCRPS, leading to enhanced root dry weight, length, surface area, specific root length, and smaller diameter of roots but lower water uptake rate per root length compared to TPRPS. In subsequent growth stages, the reduced soil water content under GCRPS caused that the preponderance of root growth under GCRPSsat disappeared in comparison to TPRPS. Under other GCRPS treatments (GCRPSfwc and GCRPS80%), significant limitation on root growth, bigger root diameter and higher water uptake rate per root length were found. Conclusions Discrepancies in soil water and temperature between TPRPS and GCRPS caused adjustments to root growth, morphology, distribution and function. Even though drought stress was inevitable after mid-tillering under GCRPS, especially GCRPS80%, similar or even enhanced root water uptake capacity in comparison to TPRPS might promote allocation of photosynthetic products to shoots and increase water productivity. PMID:28686687

Laboratory test investigations on soil water characteristic curve and air permeability of municipal solid waste.

PubMed

Shi, Jianyong; Wu, Xun; Ai, Yingbo; Zhang, Zhen

2018-05-01

The air permeability coefficient has a high correlation with the water content of municipal solid waste. In this study, continuous drying methodology using a tension meter was employed to construct the soil water characteristic curve of municipal solid waste (M-SWCC). The municipal solid waste air permeability test was conducted by a newly designed apparatus. The measured M-SWCC was well reproduced by the van Genuchten (V-G) model and was used to predict the parameters of typical points in M-SWCC, including saturated water content, field capacity, residual water content and water content at the inflection point. It was found that the M-SWCC was significantly influenced by void ratio. The final evaporation and test period of M-SWCC increase with the increase in void ratio of municipal solid waste. The evolution of air permeability coefficient with water content of municipal solid waste depicted three distinct characteristic stages. It was observed that the water contents that corresponded to the two cut-off points of the three stages were residual water content and water content at the inflection point, respectively. The air permeability coefficient of municipal solid waste decreased with the increase of the water content from zero to the residual water content. The air permeability coefficient was almost invariable when the water content increased from residual water content to the water content at the inflection point. When the water content of municipal solid waste exceeded the water content at the inflection point, the air permeability coefficient sharply decreased with the increase of water content.

Effect of cotton bollworm (Helicoverpa armigera Hübner) caused injury on maize grain content, especially regarding to the protein alteration.

PubMed

Keszthelyi, S; Pál-Fám, F; Kerepesi, I

2011-03-01

The cotton bollworm (Helicoverpa armigera Hübner), which migrated in the Carpathian-basin from Mediterraneum in the last decades, is becoming an increasingly serious problem for maize producers in Hungary. In several regions the damage it causes has reached the threshold of economic loss, especially in the case of the sweet maize cultivation. The aim of the research was to determine the changing of ears weights and in-kernel accumulation and alteration in grain as a function of cotton bollworm mastication.Our investigation confirmed that there is an in-kernel and protein pattern change of maize grain by cotton bollworm. Our results proved the significant damaging of each part of ears by cotton bollworm masticating (the average weight loss of ears: 13.99%; the average weight loss of grains: 14.03%; the average weight loss of cobs: 13.74%), with the exception of the increasing of the grain-cob ratio. Our examinations did not prove the water loss - that is the "forced maturing" - caused by the damage. Decreasing of raw fat (control: 2.8%; part-damaged: 2.6%; damaged: 2.4%) and starch content (control: 53.1%; part-damaged: 46.6%; damaged: 44.7%) were registered as a function of injury. In contrast, the raw protein content was increased (control: 4.7%; part-damaged: 5.3%; damaged: 7.4%) by maize ear masticating. The most conspicuous effect on protein composition changing was proved by comparison of damaged grain samples by SDS PAGE. Increased amounts of 114, 50, 46 and 35 kDa molecular mass proteins were detected which explained the more than 50% elevation of raw protein content. The statistical analysis of molecular weights proved the protein realignment as a function of the pest injuries, too.

Drinking water intake of grazing steers: the role of environmental factors controlling canopy wetness.

PubMed

Sun, L Z; Auerswald, K; Wenzel, R; Schnyder, H

2014-01-01

Cattle obtain water primarily from the moisture in their feed and from drinking water. On pasture, the moisture content of the diet is influenced by plant tissue water (internal water) and surface moisture (external water), which may include dew, guttation, and intercepted rain, that influence the drinking water requirement. This study investigated the relationship between daily drinking water intake (DWI, L/d) of steers on pasture (19 steers with mean initial BW of approximately 400 kg) and soil and weather factors that are known to affect plant water status (dry matter content) and surface moisture formation and persistence. Daily records of weather conditions and DWI were obtained during 2 grazing seasons with contrasting spring, summer, and autumn rainfall patterns. Plant available water in the soil (PAW, mm) was modeled from actual and potential evapotranspiration and the water-holding capacity of the soil. The DWI averaged over the herd varied among days from 0 to 29 L/d (grazing season mean 9.8 L/d). The DWI on both dry (<0.2 mm rainfall on the corresponding and previous days) and wet (>2 mm) days increased with increasing temperature (mean, maximum, and minimum), sunshine hours, and global radiation and decreasing relative humidity, and the slopes and coefficients of determination were generally greater for wet days. Wind reduced DWI on wet days but had no effect on dry days. The DWI was reduced by up to 4.4 L/d on wet days compared to dry days, but DWI did not correlate with rainfall amount. Increasing PAW decreased DWI by up to >10 L/d on both dry and wet days. These results are all consistent with environmental effects on the water status (dry matter content) of pasture vegetation and canopy surface moisture, the associated effects on grazing-related water intake, and the corresponding balancing changes of DWI. Using the observed relationships with environmental factors, we derived a new model predicting DWI for any soil moisture condition, for both wet and dry days, which included mean ambient temperature and relative humidity and explained virtually all variation of DWI that was not caused by the random scatter among individual animals.

Co-composting of Beef Cattle Feedlot Manure with Construction and Demolition Waste.

PubMed

Hao, Xiying; Hill, Brett; Caffyn, Pam; Travis, Greg; Olson, Andrew F; Larney, Francis J; McAllister, Tim; Alexander, Trevor

2014-09-01

With increased availability of dried distillers' grains with solubles (DDGS) as cattle feed and the need to recycle organic wastes, this research investigated the feasibility of co-composting DDGS cattle feedlot manure with construction and demolition (C&D) waste. Manure was collected from cattle fed a typical western Canadian finishing diet (CK) of 860 g rolled barley ( L.) grain, 100 g barley silage, and 40 g vitamin and mineral supplement kg dry matter (DM) and from cattle fed the same diet but (DG manure) with 300 g kg DM barley grain being replaced by DDGS. The CK and DG manures were co-composted with and without C&D waste in 13 m bins. Compost materials were turned on Days 14, 37, and 64, and terminated on Day 99. Adding C&D waste led to higher compost temperatures (0.4 to 16.3°C, average 7.2°C) than manure alone. Final composts had similar total C, total N, C/N ratios, and water-extractable K, Mg, and NO content across all treatments. However, adding C&D waste increased δC, δN, water-extractable SO, and Ca contents and decreased pH, total P (TP), water-extractable C, N, and P and most volatile fatty acids (VFA). The higher C&D compost temperatures should reduce pathogens while reduced VFA content should reduce odors. When using the final compost product, the increased SO and reduced TP and available N and P content in C&D waste compost should be taken into consideration. Increased S content in C&D compost may be beneficial for some crops grown on S-deficient soils. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Perceptions of water use.

PubMed

Attari, Shahzeen Z

2014-04-08

In a national online survey, 1,020 participants reported their perceptions of water use for household activities. When asked for the most effective strategy they could implement to conserve water in their lives, or what other Americans could do, most participants mentioned curtailment (e.g., taking shorter showers, turning off the water while brushing teeth) rather than efficiency improvements (e.g., replacing toilets, retrofitting washers). This contrasts with expert recommendations. Additionally, some participants are more likely to list curtailment actions for themselves, but list efficiency actions for other Americans. For a sample of 17 activities, participants underestimated water use by a factor of 2 on average, with large underestimates for high water-use activities. An additional ranking task showed poor discrimination of low vs. high embodied water content in food products. High numeracy scores, older age, and male sex were associated with more accurate perceptions of water use. Overall, perception of water use is more accurate than the perception of energy consumption and savings previously reported. Well-designed efforts to improve public understanding of household water use could pay large dividends for behavioral adaptation to temporary or long-term decreases in availability of fresh water.

Progress report on the ground-water resources of the Louisville area, Kentucky, 1949-55

USGS Publications Warehouse

Bell, Edwin A.; Kellogg, Robert W.; Kulp, Willis K.

1963-01-01

In the Louisville area, the principal water-bearing formations are the glacial-outwash sand and gravel and, in places, the underlying limestone. During the period 1949 through 1955 pumpage from the two aquifers averaged about 30 mgd (million gallons per day). The pumpage was approximately in balance with the normal net recharge to the area but was only about 8 percent of the estimated potential supply of ground water, including induced infiltration from the river. In the Louisville area, ground water is used chiefly for air conditioning and for industrial cooling. In the part of the area southwest of the city, ground water is used also for public supply. High ground-water levels in 1937 resulted from the greatest flood of record. Subsequently, water levels generally declined in the entire Louisville area. In downtown Louisville, where ground water is used for air conditioning, the water level fluctuates seasonally in response to variations in the rate of pumping. In the heavily pumped industrial areas, where ground water is used for cooling, water-level fluctuations correlate with changes in rates of pumping caused by variations in production schedules. Levels were lowest during the years of World War II. During the period 1952-55, relatively low levels throughout the area reflected the effects of less than normal rainfall, summer drought, and sustained pumping. Ground water in the Louisville area is very hard and generally of the calcium bicarbonate or calcium sulfate type. It is high in iron and sulfate content but is moderately low in chloride content. In water of the sand and gravel aquifer, the concentration of sulfate has increased gradually during the period 1949-54.

[Nitrogen and phosphate pollution characteristics and eutrophication evaluation for typical urban landscape waters in Hefei City].

PubMed

Li, Ru-Zhong; Liu, Ke-Feng; Qian, Jing; Yang, Ji-Wei; Zhang, Pian-Pian

2014-05-01

To understand the water environment regimes of the city-circling water system in Hefei City, six typical landscape waters were chosen to investigate pollution characteristics of nitrogen and phosphate and evaluate water eutrophication level according to the monitoring data of water physicochemical characteristics and chlorophyll content from September 2012 to July 2013. Study results showed that (1) the six waters mentioned above have been seriously polluted by nitrogen and phosphorus loadings, with the monthly mean values of total nitrogen (TN) and total phosphorus (TP) concentrations far exceeding the universally accepted threshold values of water eutrophication; (2) the nitrogen contents in the waters of Nanfeihe River, Heichiba and Yuhuatang scenic spots exhibited a markedly monthly variation, and both TP and PO(3-)(4)-P in Nanfeihe River showed a fluctuated characteristic with high concentrations while presenting a significant upward trend in Yuhuatang scenic spot; (3) the average values of TN/TP ratios for Yuhuatang and Heichiba scenic spots were 104.7 and 158.3, respectively, and the ratios for Baohe Park, Yinhe Park, Xiaoyaojin Park, and city segment of Nanfeihe River were 16.8, 18.7, 6.4 and 16.8, respectively, indicating that the scenic waters of Yuhuatang and Heichiba were phosphate-limited whereas Xiaoyaojin Park was nitrogen-limited; (4) all the six scenic waters were, in general, subsumed under just two broad categories, namely Hechiba scenic spot and Nanfeihe River, which were seriously polluted, and clustered together, and the others fall into the second class; and (5) water eutrophication appraisal result indicated that the six waters were all in the state of eutrophication, and could be arranged in the order of eutrophication level, Yinhe Park > Heichiba scenic spot > city segment of Nanfeihe River > Xiaoyaojin Park > Yuhuatang scenic spot > Baohe Park.

Assessing the Climate Sensitivity of Cold Content and Snowmelt in Seasonal Alpine and Subalpine Snowpacks

NASA Astrophysics Data System (ADS)

Jennings, K. S.; Molotch, N. P.

2016-12-01

In cold, high-elevation sites, snowpack cold content acts as a buffer against climate warming by resisting snowmelt during periods of positive energy fluxes. To test the climate sensitivity of cold content and snowmelt, we employed the physical SNOWPACK snow model, forced with a 23-year, hourly, quality-controlled, gap-filled meteorological dataset from the Niwot Ridge Long Term Ecological Research (LTER) site in the Front Range mountains of Colorado. SNOWPACK was run at two points with seasonal snowpacks within the LTER, one in the alpine (3528 m) and one in the subalpine (3022 m). Model output was validated using snow water equivalent (SWE), snowpack temperature, and cold content data from snow pits dug near the met stations and automated SWE data from nearby SNOTEL snow pillows. Cold content accumulates primarily through additions of new snow, while negative energy fluxes—cooling through longwave emission and sublimation—play a lesser role, particularly in the deeper snowpack of the alpine. On average, the snowpack energy balance becomes positive on April 1 in the alpine and March 8 in the subalpine. Peak SWE occurs after these dates and its timing is primarily determined by the amount of precipitation received after peak cold content, with persistent snowfall delaying the main snowmelt pulse. Years with lower cold content, due to reduced precipitation and/or increased air temperature, experience an earlier positive energy balance with more melt events occurring before the date of peak SWE, which has implications for soil moisture, streamflow volume and timing, water uptake by vegetation, and microbial respiration. Synthetic warming experiments show significant cold content reductions and increased late-winter/early-spring melt as positive energy balances occur earlier in the snow season (a forward shift between 5.1 and 21.0 days per °C of warming). These results indicate cold, high-elevation sites, which are critical for water resources in the western United States, may lose their cold content buffering capacity and begin to experience stronger negative trends in SWE with increased climate warming, even as the majority of winter precipitation continues to fall as snow.

Ascorbate in the guinea pig lens: dependence on drinking water supplementation.

PubMed

Mody, Vino C; Kakar, Manoj; Elfving, Ase; Söderberg, Per G; Löfgren, Stefan

2005-04-01

To investigate whether lens ascorbate concentration can be elevated with drinking water supplementation. Pigmented guinea pigs received drinking water supplemented with L-ascorbate, concentration 0.00, 2.84, 5.68 or 8.52 mm for a duration of 4 weeks. In addition, the chow fed to all animals contained 125 mmol L-ascorbate per kg of chow. At the end of the supplementation period, the guinea pigs were killed. Each lens was extracted. The lens was processed and ascorbate concentration was measured using high performance liquid chromatography (HPLC) with 254 nm ultraviolet radiation detection. The data were analysed with regression. At the end of the test period, all lenses were devoid of cataract as observed by slit-lamp examination. All lenses contained a detectable concentration of ascorbate. Estimated 95% confidence intervals for mean animal-averaged lens ascorbate concentrations (micromol/g wet weight of whole lens) per group were 0.51 +/- 0.04 (0.00 mm; n = 6), 0.70 +/- 0.18 (2.84 mm; n = 6), 0.71 +/- 0.11 (5.68 mm; n = 5), and 0.71 +/- 0.06 (8.52 mm; n = 6). Animal-averaged lens ascorbate concentration [Asc(lens)] (micromol/g wet weight lens) increased with ascorbate supplementation in drinking water [Asc(water)] (M), in agreement with the model: [Asc(lens)] = A - Be(-kAsc(water)]. Lens ascorbate concentration increases with drinking water supplementation in the guinea pig without cataract development. The currently presented method for measurement of whole lens ascorbate content is suitable.

Evaluation of the effect of sulfate, alkalinity and disinfector on iron release of iron pipe and iron corrosion scale characteristics under water quality changing condition using response surface methodology

NASA Astrophysics Data System (ADS)

Yang, Fan; Shi, Baoyou; Zhang, Weiyu; Guo, Jianbo; Wu, Nana; Liu, Xinyuan

2018-02-01

The response surface methodology (RSM), particularly Box-Behnken design model, was used in this study to evaluate the sulfate, alkalinity and free chlorine on iron release of pipe with groundwater supply history and its iron corrosion scale characteristics under water quality changing experiment. The RSM results together with response surface contour plots indicated that the iron release of pipe section reactors was positively related with Larson Ratio and free chlorine. The thin Corrosion scales with groundwater supply history upon collection site contained Fe3O4 (18%), α-FeOOH (64%), FeCO3 (9%), β-FeOOH (8%) and γ-FeOOH (5%), besides their averaged amorphous iron oxide content was 13.6%. After the RSM water quality changing experiment, Fe3O4, amorphous iron oxide and intermediate iron products (FeCO3, Green Rust (GR)) content on scale of Cl2Rs increased, while their α-FeOOH contents decreased and β-FeOOH disappeared. The high iron released Cl2Rs receiving higher LR water (1.40-2.04) contained highest FeCO3 (20%) and amorphous iron oxide (42%), while the low iron release Cl2Rs receiving lower LR water (0.52-0.73) had higher GR(6.5%) and the amorphous iron oxide (23.7%). In high LR water (>0.73), the thin and non-protective corrosion scale containing higher amorphous iron oxide, Fe(II) derived from new produced Fe3O4 or FeCO3 or GR was easy for oxidants and sulfate ions penetration, and had higher iron release. However the same unstable corrosion scale didn’t have much iron release in low LR water (≤0.73). RSM experiment indicated that iron release of these unstable corrosion scales had close relationship with water quality (Larson Ratio and disinfectant). Optimizing the water quality of new source water and using reasonable water purification measures can help to eliminate the red water case.

Monitoring toxic cyanobacteria and cyanotoxins (microcystins and cylindrospermopsins) in four recreational reservoirs (Khon Kaen, Thailand).

PubMed

Somdee, Theerasak; Kaewsan, Tunyaluk; Somdee, Anchana

2013-11-01

The toxic cyanobacterial communities of four recreational reservoirs (Bueng Kaen Nakhon, Bueng Thung Sang, Bueng Nong Khot, and Bueng See Than) in Amphur Muang, Khon Kaen Province, Thailand, were investigated. Water samples were collected via monthly sampling from June to October 2011 for the study on the diversity and density of toxic cyanobacteria and toxin quantification. The main toxic cyanobacteria present in these reservoirs were Aphanocapsa sp., Cylindrospermopsis sp., Leptolyngbya sp., Limnothrix sp., Microcystis sp., Oscillatoria sp., Planktolyngbya sp., Planktotrix sp., and Pseudanabaena sp. The dominant bloom-forming genera in the water samples from Bueng Nong Khot and Bueng See Than were Microcystis sp. and Cylindrospermopsis sp., respectively. Enzyme-linked immunosorbent assays specific for cyanotoxins were performed to detect and quantify microcystins and cylindrospermopsins, with the highest average microcystins content (0.913 μgL(-1)) being found in the sample collected from Bueng Nong Khot and the highest average cylindrospermopsins content (0.463 μgL(-1)) being found in the sample collected from Bueng See Than. The application of 16S rRNA analyses to cyanobacterial isolates BKN2, BNK1, BNK2, and BST1 indicated that these isolates are most closely related to Limnothrix planctonica (JQ004026) (98% similarity), Leptolyngbya sp. (FM177494) (99% similarity), Microcystis aeruginosa (DQ887510) (99% similarity), and Limnothrix redekei (FM177493) (99% similarity), respectively.

Arsenic in soil and irrigation water affects arsenic uptake by rice: complementary insights from field and pot studies.

PubMed

Dittmar, Jessica; Voegelin, Andreas; Maurer, Felix; Roberts, Linda C; Hug, Stephan J; Saha, Ganesh C; Ali, M Ashraf; Badruzzaman, A Borhan M; Kretzschmar, Ruben

2010-12-01

Groundwater rich in arsenic (As) is extensively used for dry season boro rice cultivation in Bangladesh, leading to long-term As accumulation in soils. This may result in increasing levels of As in rice straw and grain, and eventually, in decreasing rice yields due to As phytotoxicity. In this study, we investigated the As contents of rice straw and grain over three consecutive harvest seasons (2005-2007) in a paddy field in Munshiganj, Bangladesh, which exhibits a documented gradient in soil As caused by annual irrigation with As-rich groundwater since the early 1990s. The field data revealed that straw and grain As concentrations were elevated in the field and highest near the irrigation water inlet, where As concentrations in both soil and irrigation water were highest. Additionally, a pot experiment with soils and rice seeds from the field site was carried out in which soil and irrigation water As were varied in a full factorial design. The results suggested that both soil As accumulated in previous years and As freshly introduced with irrigation water influence As uptake during rice growth. At similar soil As contents, plants grown in pots exhibited similar grain and straw As contents as plants grown in the field. This suggested that the results from pot experiments performed at higher soil As levels can be used to assess the effect of continuing soil As accumulation on As content and yield of rice. On the basis of a recently published scenario of long-term As accumulation at the study site, we estimate that, under unchanged irrigation practice, average grain As concentrations will increase from currently ∼0.15 mg As kg(-1) to 0.25-0.58 mg As kg(-1) by the year 2050. This translates to a 1.5-3.8 times higher As intake by the local population via rice, possibly exceeding the provisional tolerable As intake value defined by FAO/WHO.

Warming of the Global Ocean: Spatial Structure and Water-Mass Trends

NASA Technical Reports Server (NTRS)

Hakkinen, Sirpa; Rhines, Peter B.; Worthen, Denise L.

2016-01-01

This study investigates the multidecadal warming and interannual-to-decadal heat content changes in the upper ocean (0-700 m), focusing on vertical and horizontal patterns of variability. These results support a nearly monotonic warming over much of the World Ocean, with a shift toward Southern Hemisphere warming during the well-observed past decade. This is based on objectively analyzed gridded observational datasets and on a modeled state estimate. Besides the surface warming, a warming climate also has a subsurface effect manifesting as a strong deepening of the midthermocline isopycnals, which can be diagnosed directly from hydrographic data. This deepening appears to be a result of heat entering via subduction and spreading laterally from the high-latitude ventilation regions of subtropical mode waters. The basin-average multidecadal warming mainly expands the subtropical mode water volume, with weak changes in the temperature-salinity (u-S) relationship (known as ''spice'' variability). However, the spice contribution to the heat content can be locally large, for example in Southern Hemisphere. Multidecadal isopycnal sinking has been strongest over the southern basins and weaker elsewhere with the exception of the Gulf Stream/North Atlantic Current/subtropical recirculation gyre. At interannual to decadal time scales, wind-driven sinking and shoaling of density surfaces still dominate ocean heat content changes, while the contribution from temperature changes along density surfaces tends to decrease as time scales shorten.

Pathways of Methylmercury Transfer to the Water Column Across Multiple Estuaries

NASA Astrophysics Data System (ADS)

Schartup, A. T.; Balcom, P. H.; Mason, R. P.; Chen, C.

2014-12-01

Estuarine water column methylmercury (MeHg) is an important driver of bioaccumulation in pelagic organisms so it is important to understand the sources and cycling of MeHg. As MeHg biomagnifies in food webs, increased water column concentrations can be transferred to fish consumed by humans. Few studies have taken a multi-estuary approach to look at MeHg cycling in the water column of these important MeHg producing areas. We examined the distributions and partitioning of sediment and water column MeHg across a geographic range of estuaries. In 2008 we sampled 10 shallow-water estuarine sites from Maine to New Jersey, sampled 11 sites in 4 estuaries in 2009, and sampled at 3 estuarine turbidity maximum (ETM) sites in 1 estuary in 2012. Sediment measurements included both solid phase and pore water MeHg and total mercury (HgT). Water column parameters included dissolved and particulate MeHg and HgT, total suspended solids, nutrients, and dissolved organic carbon. Average suspended particle MeHg was highest at Wells (ME; 6 to 11.5 pmol/g; 4.5 to 7% of HgT) and lowest at Portsmouth (NH) and in Long Island Sound (CT-NY; 0.2 to 5.5 pmol/g; 0.25 to 3.75% of HgT). Average water column dissolved MeHg was highest in the Delaware River ETM (0.5 to 0.7 pM; 16 to 24% of HgT) and lowest at Portsmouth (0.06 to 0.12 pM; 1 to 2% of HgT). Significant positive correlations were found between MeHg and HgT across multiple estuaries in both sediment and the water column in 2008 and 2009. In contrast, water column dissolved and suspended particle MeHg do not correlate well with sediment MeHg or HgT, pore water MeHg or methylation rates in sediment across estuaries, indicating that sediment is often not a good predictor of water MeHg levels. However, ratios of average dissolved:pore water MeHg and suspended particle:sediment MeHg are close to 1 in the Delaware River ETM, suggesting that sediment supplies MeHg to the water column in this turbulent region, but average pore water MeHg was uniformly elevated above water dissolved MeHg in the other estuaries studied. Several estuaries had higher MeHg at low tide suggesting input as water was delivered from the watersheds. We conclude that the relative importance of sources is dependent on the physical (water residence time, water depth) and chemical characteristics (sediment organic carbon content) of the estuary.

Defining restoration targets for water depth and salinity in wind-dominated Spartina patens (Ait.) Muhl. coastal marshes

USGS Publications Warehouse

Nyman, J.A.; LaPeyre, Megan K.; Caldwell, Andral W.; Piazza, Sarai C.; Thom, C.; Winslow, C.

2009-01-01

Coastal wetlands provide valued ecosystem functions but the sustainability of those functions often is threatened by artificial hydrologic conditions. It is widely recognized that increased flooding and salinity can stress emergent plants, but there are few measurements to guide restoration, management, and mitigation. Marsh flooding can be estimated over large areas with few data where winds have little effect on water levels, but quantifying flooding requires hourly measurements over long time periods where tides are wind-dominated such as the northern Gulf of Mexico. Estimating salinity of flood water requires direct daily measurements because coastal marshes are characterized by dynamic salinity gradients. We analyzed 399,772 hourly observations of water depth and 521,561 hourly observations of water salinity from 14 sites in Louisiana coastal marshes dominated by Spartina patens (Ait.) Muhl. Unlike predicted water levels, observed water levels varied monthly and annually. We attributed those observed variations to variations in river runoff and winds. In stable marshes with slow wetland loss rates, we found that marsh elevation averaged 1 cm above mean high water, 15 cm above mean water, and 32 cm above mean low water levels. Water salinity averaged 3.7 ppt during April, May, and June, and 5.4 ppt during July, August, and September. The daily, seasonal, and annual variation in water levels and salinity that were evident would support the contention that such variation be retained when designing and operating coastal wetland management and restoration projects. Our findings might be of interest to scientists, engineers, and managers involved in restoration, management, and restoration in other regions where S. patens or similar species are common but local data are unavailable.

Defining restoration targets for water depth and salinity in wind-dominated Spartina patens (Ait.) Muhl. coastal marshes

USGS Publications Warehouse

Nyman, J.A.; La Peyre, M.K.; Caldwell, A.; Piazza, S.; Thom, C.; Winslow, C.

2009-01-01

Coastal wetlands provide valued ecosystem functions but the sustainability of those functions often is threatened by artificial hydrologic conditions. It is widely recognized that increased flooding and salinity can stress emergent plants, but there are few measurements to guide restoration, management, and mitigation. Marsh flooding can be estimated over large areas with few data where winds have little effect on water levels, but quantifying flooding requires hourly measurements over long time periods where tides are wind-dominated such as the northern Gulf of Mexico. Estimating salinity of flood water requires direct daily measurements because coastal marshes are characterized by dynamic salinity gradients. We analyzed 399,772 hourly observations of water depth and 521,561 hourly observations of water salinity from 14 sites in Louisiana coastal marshes dominated by Spartina patens (Ait.) Muhl. Unlike predicted water levels, observed water levels varied monthly and annually. We attributed those observed variations to variations in river runoff and winds. In stable marshes with slow wetland loss rates, we found that marsh elevation averaged 1 cm above mean high water, 15 cm above mean water, and 32 cm above mean low water levels. Water salinity averaged 3.7 ppt during April, May, and June, and 5.4 ppt during July, August, and September. The daily, seasonal, and annual variation in water levels and salinity that were evident would support the contention that such variation be retained when designing and operating coastal wetland management and restoration projects. Our findings might be of interest to scientists, engineers, and managers involved in restoration, management, and restoration in other regions where S. patens or similar species are common but local data are unavailable. ?? 2009 Elsevier B.V.

Lipid and PCB compositions in water-striders from contaminated streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Napolitano, G.E.; Richmond, J.E.; Klasson, K.T.

1995-12-31

In a study of hydrophobic substances in stream surface-waters, the authors investigated lipids and polychlorinated biphenyls (PCBs) of water-striders (Gerris remiges). Lipid class, fatty acid, and PCB congener compositions were analyzed in insects from four streams located downstream of the Department of Energy`s facilities near the city of Oak Ridge, Tennessee. Total lipid contents of water-striders varied seasonally, showing maximum concentrations in summer and fall ({approximately} 9.0% of wet weight), and minimum concentrations in winter and spring. Total PCB concentrations of water-striders varied between streams and appeared to parallel PCB concentrations reported for the aquatic fauna of each site. Fattymore » acids were used as chemical markers to detect differences in the food resources of water-striders. The triacylglycerol fatty acid composition was remarkably similar in all the streams and reflected to a large extent, that of a terrestrial insect. The PCB congener composition of water-striders varied significantly between streams, showing a relative enrichment of the less chlorinated congeners in the less contaminated samples. There was also a positive correlation between PCB burden and average molecular weights. Differences between the chlorine content of the dominant congeners suggest distinct sources of PCBs for the different streams. The apparent similarities in the food resources of the water-striders, as inferred from fatty acid markers, and their distinct PCB congener composition, suggest absorption or ingestion from the surface micro-layer, rather than diet, as a more likely route of uptake of lipophilic contaminants by water-striders.« less

Aquifer geochemistry and effects of pumping on ground-water quality at the Green Belt Parkway Well Field, Holbrook, Long Island, New York

USGS Publications Warehouse

Brown, Craig J.; Colabufo, Steven; Coates, John D.

2002-01-01

Geochemistry, microbiology, and water quality of the Magothy aquifer at a new supply well in Holbrook were studied to help identify factors that contribute to iron-related biofouling of public-supply wells. The organic carbon content of borehole sediments from the screen zone, and the dominant terminal electron-accepting processes (TEAPs), varied by depth. TEAP assays of core sediments indicated that iron reduction, sulfate reduction, and undetermined (possibly oxic) reactions and microbial activity are correlated with organic carbon (lignite) content. The quality of water from this well, therefore, reflects the wide range of aquifer microenvironments at this site.High concentrations of dissolved iron (3.6 to 6.4 micromoles per liter) in water samples from this well indicate that some water is derived from Fe(III)-reducing sediments within the aquifer, but traces of dissolved oxygen indicate inflow of shallow, oxygenated water from shallow units that overlie the local confining units. Water-quality monitoring before and during a 2-day pumping test indicates that continuous pumping from the Magothy aquifer at this site can induce downward flow of shallow, oxygenated water despite the locally confined conditions. Average concentrations of dissolved oxygen are high (5.2 milligrams per liter, or mg/L) in the overlying upper glacial aquifer and at the top of the Magothy aquifer (4.3 mg/L), and low ( < 0.1 mg/L) in the deeper, anaerobic part of the Magothy; average concentrations of phosphate are high (0.4 mg/L) in the upper glacial aquifer and lower (0.008 mg/L) at the top of the Magothy aquifer and in the deeper part of the Magothy (0.013 mg/L). Concentrations of both constituents increased during the 2 days of pumping. The δ34S of sulfate in shallow ground water from observation wells (3.8 to 6.4 per mil) was much heavier than that in the supplywell water (-0.1 per mil) and was used to help identify sources of water entering the supply well. The δ34S of sulfate in a deep observation well adjacent to the supply well increased from 2.4 per mil before pumping to 3.3 per mil after pumping; this confirms that the pumping induced downward migration of water. The lighter δ34S value in the pumped water than in the adjacent observation well probably indicates FeS2 oxidation (which releases light δ34S in adjacent sediments) by the downward flow of oxygenated water.

[Content of indole alkaloids and bufadienolides contained in toad medicines].

PubMed

Qu, Ting; Gao, Hui-Min; Chen, Liang-Mian; Wang, Zhi-Min; Zhang, Qi-Wei; Cheng, Yi-Yu

2012-10-01

To kinds of establish a HPLC method for determining contents of indole alkaloids and bufadienolides contained in toad medicines, and analyze two kinds of components contained in toad venom, toad skin and toad periostracum. As for alkaloids, Nucleosil C18 column was adopted with acetonitrile and water containing 0.5% potassium dihydrogen phosphate (6: 94, adjust pH to 3.2 with phosphate acid) as the mobile phase. The flow rate was 0.8 mL x min(-1), the detection wavelength was 275 nm, and the column temperature was 30 degrees C. As for bufadienolides, Alltima C18 column was adopted with acetonitrile and water containing 0.3% acetic acid (B) as the mobile phase. The gradient process was as follows: a linear gradient from 28% to 54% acetonitrile in the first 15 min, then kept at 54% for additional 20 min. The flow rate was 0.6 mL x min(-1), the detection wavelength was 296 nm, and the column temperature was 30 degrees C. The linear ranges were 0.079 6-0.796 microg for serotonin, 0.097 2-1.945 microg for N-methylserotonin, 0.074 4-0.744 microg for N,N-dimethylserotonin, 0.103-2.05 microg for N,N,N-trimethylserotonin, and 0.067 2-0.672 microg for bufothionine, respectively. The average recoveries of serotonin and N-methylserotonin were 98.6% and 91.3%, respectively. The linear ranges of gamabufotalin, bufotalin, bufalin, cinobufagin and resibufogenin were 0.004 83-0.614, 0.007 9-1.006, 0.007 95-1.016, 0.009 7-1.24 and 0.009 6-1.22 microg, respectively, and their average recoveries were 101.6%, 102.5%, 101.0%, 99.1% and 98.9%, respectively. Toad venom has the highest contents of indole alkaloids and bufadienolides, followed by toad skin, and toad periostracum showed the lowest contents and even no detection result.

The quality of surface waters in Texas

USGS Publications Warehouse

Rawson, Jack

1974-01-01

The discharge-weighted average concentrations of dissolved solids, chloride, and ,sulfate for many of the principal streams in Texas are less than 500 mg/l (millijgraljls per liter), 250 mg/l, and 250 mg/l, respectively. At 65 of 131 sites on streams that were sampled at least 10 times, the biochemical oxygen demand of at least half the samples exceeded 3.0 mg/l. At 20 of the sites, the dissolved-oxygen content of at least half the samples was less than 5.0 mg/l. The higher concentrations of minor elements usually were detected in waters from urban areas, indicating a relation to man's activities. Small amounts of some pesticides are widely distributed in low concentrations. The higher concentrations usually were detected in waters from urban areas.

Influence of atmospheric energy transport on amplification of winter warming in the Arctic

NASA Astrophysics Data System (ADS)

Alekseev, Genrikh; Kuzmina, Svetlana; Urazgildeeva, Aleksandra; Bobylev, Leonid

2016-04-01

The study was performed on base reanalysis ERA/Interim to discover the link between amplified warming in the high Arctic and the atmospheric transport of heat and water vapor through the 70 ° N. The partitioning transports across the Atlantic and Pacific "gates" is established the link between variations of atmospheric flux through the "gates" and a larger part of the variability of the average surface air temperature, water vapor content and its trends in the winter 1980-2014. Influence of winter (December-February) atmospheric transport across the Atlantic "gate" at the 1000 hPa on variability of average for January-February surface air temperature to north 70° N is estimated correlation coefficient 0.75 and contribution to the temperature trend 40%. These results for the first time denote the leading role of increasing atmospheric transport on the amplification of winter warming in the high Arctic. The investigation is supported with RFBR project 15-05-03512.

Effect of Growth Conditions and Trehalose Content on Cryotolerance of Bakers' Yeast in Frozen Doughs

PubMed Central

Gélinas, Pierre; Fiset, Gisèle; LeDuy, Anh; Goulet, Jacques

1989-01-01

The cryotolerance in frozen doughs and in water suspensions of bakers' yeast (Saccharomyces cerevisiae) previously grown under various industrial conditions was evaluated on a laboratory scale. Fed-batch cultures were very superior to batch cultures, and strong aeration enhanced cryoresistance in both cases for freezing rates of 1 to 56°C min−1. Loss of cell viability in frozen dough or water was related to the duration of the dissolved-oxygen deficit during fed-batch growth. Strongly aerobic fed-batch cultures grown at a reduced average specific rate (μ = 0.088 h−1 compared with 0.117 h−1) also showed greater trehalose synthesis and improved frozen-dough stability. Insufficient aeration (dissolved-oxygen deficit) and lower growth temperature (20°C instead of 30°C) decreased both fed-batch-grown yeast cryoresistance and trehalose content. Although trehalose had a cryoprotective effect in S. cerevisiae, its effect was neutralized by even a momentary lack of excess dissolved oxygen in the fed-batch growth medium. PMID:16348024

Optimization extraction of polysaccharide from Tunisian Zizyphus lotus fruit by response surface methodology: Composition and antioxidant activity.

PubMed

Mkadmini Hammi, Khaoula; Hammami, Majdi; Rihouey, Christophe; Le Cerf, Didier; Ksouri, Riadh; Majdoub, Hatem

2016-12-01

Response surface methodology using a Box-Behnken design was employed to optimize extraction temperature, extraction time and ratio of water to material to obtain a maximum polysaccharide yield with high uronic acid content and antioxidant property from edible Zizyphus lotus fruit. The optimal conditions were: extraction time of 3h 15min, extraction temperature of 91.2°C and water to solid ratio of 39mL/g. Under these conditions, the experimental extraction yield, uronic acid content and 2,2-diphenyl-1-picrylhydrazyl scavenging ability (IC50) were 18.88%, 41.89 and 0.518mg/mL, respectively. Chemical analysis revealed that the extract was composed of 97.92% carbohydrate of which 41.89% is uronic acid. The extracted polysaccharides, with an average molecular weight of 2720kDa, are composed of arabinose, rhamnose, glucose, fructose, galactose and xylose. Moreover, the polysaccharides exhibited a significant reducing power and anti-lipid peroxidation activities. Copyright © 2016 Elsevier Ltd. All rights reserved.

A Tracer Test at the Los Alamos Canyon Weir

NASA Astrophysics Data System (ADS)

Levitt, D. G.; Stone, W. J.; Newell, D. L.; Wykoff, D. S.

2002-12-01

A low-head weir was constructed in the Los Alamos Canyon to reduce the transport of contaminant-bearing sediment caused by fire-enhanced runoff off Los Alamos National Laboratory (LANL) property towards the Rio Grande following the May 2000 Cerro Grande fire at Los Alamos, New Mexico. Fractured basalt was exposed in the channel by grading during construction of the weir, and water temporarily ponds behind the weir following periods of runoff. In order to monitor any downward transport of contaminants into fractured basalt, and potentially downward to the regional ground water, three boreholes (one vertical, one at 43 degrees, and one at 34 degrees from horizontal) were installed for environmental monitoring. The boreholes penetrate to depths ranging from approximately 9 to 82 m below the weir floor. The two angled boreholes are fitted with flexible FLUTe liners with resistance sensors to measure relative moisture content and absorbent sampling pads for contaminant and environmental tracer sampling within the vadose zone. The two angled boreholes are also monitored for relative changes in moisture content by neutron logging. The vertical borehole penetrates three perched water zones and is equipped with four screens and sampling ports. In April 2002, a tracer test was initiated with the application of a 0.2 M (16,000 ppm) solution of potassium bromide (KBr) onto the weir floor. The tracer experiment was intended to provide data on travel times through the complex hydrogeologic media of fractured basalt. A precipitation and runoff event in June 2002 resulted in approximately 0.61 m of standing water behind the weir. If the KBr and flood waters were well mixed, the concentration of KBr in the flood waters was approximately 24 ppm. Bromide was detected in the absorbent membrane in the 43 degree hole at concentrations up to 2 ppm. Resistance sensors in the 43 degree borehole detected moisture increases within 3 days at a depth of 27 m, indicating an average wetting front velocity of 8.9 m per day in the vadose zone. Increases in bromide concentrations were detected in water samples from two of the four sampling ports in the vertical well within 10 days of the precipitation event, indicating an average wetting front velocity of 5.5 m per day to the sample port at a depth of 55 m below the weir floor. Increases in bromide concentrations were detected at the bottom port of the vertical well at a depth of 78 m below the weir floor within 21 days, indicating an average wetting front velocity of 3.7 m per day. Modeling of this tracer test data will improve our understanding of: the impact of the fire on ground-water quality; the impact of the weir on ground-water quality; surface water/ground water interactions; and the hydraulic properties of the Cerros del Rio basalts underlying the eastern Pajarito Plateau.

Inorganic geochemistry of domed peat in Indonesia and its implication for the origin of mineral matter in coal

USGS Publications Warehouse

Neuzil, Sandra G.; Supardi,; Cecil, C. Blaine; Kane, Jean S.; Soedjono, Kadar

1993-01-01

The inorganic geochemistry of three domed ombrogenous peat deposits in Riau and West Kalimantan provinces, Indonesia, was investigated as a possible modern analogue for certain types of low-ash, low-sulfur coal. Mineral matter entering the deposits is apparently limited to small amounts from the allogenic sources of dryfall, rainfall, and diffusion from substrate pore water. In the low-ash peat in the interior of the deposits, a large portion of the mineral matter is authigenic and has been mobilized and stabilized by hydrological, chemical, and biological processes and conditions.Ash yield and sulfur content are low through most of the peat deposits and average 1.1% and 0.14%, respectively, on a moisture-free basis. Ash and sulfur contents only exceed 5% and 0.3%, respectively, near the base of the deposits, with maximum concentrations of 19.9% ash and 0.56% sulfur. Peat water in all three deposits has a low pH, about 4 units, and low dissolved cation concentration, averaging 14 ppm. Near the base, in the geographic interior of each peat deposit, pH is about two units higher and dissolved cation concentration averages 110 ppm. Relative concentrations of the inorganic constituents vary, resulting in chemical facies in the peat. In general, Si, Al, and Fe are the abundant inorganic constituents, although Mg, Ca, and Na dominate in the middle horizon in the geographic interior of coastal peat deposits.The composition of the three deposits reported in this paper indicates that domed ombrogenous peat deposits will result in low ash and sulfur coal, probably less than 10% ash and 1% sulfur, even if marine rocks are laterally and vertically adjacent to the coal.

Potential Of Microalgae Chlorella vulgaris As Bioremediation Agents of Heavy Metal Pb (Lead) On Culture Media

NASA Astrophysics Data System (ADS)

Dewi, Endah Rita Sulistya; Nuravivah, Riza

2018-02-01

The purpose of this study to determine the ability of Chlorella vulgaris in absorbing Pb (lead) and the effect of the variation of Pb metal concentration on the growth of Chlorella vulgaris.This study using an experimental study with complete random design with 4 treatments, namely control (without the addition of metal), Pb1 (addition of metal 1 mg / l), Pb3 (3 mg / l) and Pb5 (5 mg / l), respectively 3 replications. Exposure Pb ion in Chlorella vulgaris for 7 days. Analysis of the metal content of Pb concentration performed on culture media after exposure it at 3 hours after dispersion Chlorella vulgaris and on day 7 of culture using the AAS method. Do also counting the growth of cells each day. The results of the analysis of the average metal content of Pb in the culture medium at the end of the study was the control (0.1980), Pb1 (0.1453), Pb3 (0.4144) and Pb5 (0.5305). While the average growth of Chlorella vulgaris at the end of the study were control (630.1116 x 104), Pb1 (829.0012 x 104), Pb3 (1069.9446 x 104) and Pb 5 (808.94450 x 104). The results of the analysis of the content of Pb in the F test shown that the difference in concentration of water Pb given real influence on the ability of Chlorella vulgaris in absorbing Pb and growth. The conclusion of this study was Chlorella vulgaris has the ability to absorb metals in the waters, and the provision of various concentrations of Pb can affect the growth of Chlorella vulgaris.

Availability of streamflow for recharge of the basal aquifer in the Pearl Harbor area, Hawaii

USGS Publications Warehouse

Hirashima, George Tokusuke

1971-01-01

The Pearl Harbor area is underlain by an extensive basal aquifer that contains large supplies of fresh water. Because of the presence of a cap rock composed of sedimentary material that is less permeable than the basaltic lava of the basal aquifer, seaward movement of ground water is retarded. The cap rock causes the basal water to stand at a high level; thus, the lens of fresh water that floats on sea water is thick. Discharge from the basal ground-water body, which includes pumpage from wells and shafts, averaged 250 million gallons per day during 1931-65. Because the water level in the basal aquifer did not decline progressively, recharge to the ground-water body must have been approximately equal to discharge. Although pumping for agricultural use has decreased since 1931, net ground-water discharge has increased because of a large increase in pumping for urban use. Substitution of ground water for surface water in the irrigation of sugarcane has also contributed to a net increase in ground-water discharge. The development of Mililani Town will further increase discharge. The increase in ground-water discharge may cause an increase in chloride content of the water pumped from wells near the shore of Pearl Harbor unless the increased discharge is balanced by increased recharge to the local aquifer. The aquifer is recharged by direct infiltration and deep percolation of rain, principally in the high forested area, by infiltration and percolation of irrigation water applied in excess of plant requirements, by seepage of water through streambeds, and possibly by ground-water inflow from outside the area. Recharge is greatest in the uplands, where rainfall is heavy and where much infiltration takes place before rainwater collects in the middle and lower reaches of stream channels. Once water collects in and saturates the alluvium of stream channels, additional inflow to the streams will flow out to sea, only slightly decreased by seepage. Average annual direct runoff from the 90-square-mile Pearl Harbor area is 47.27 million gallons per day, or 11.1 inches; this is 13.3 percent of the average annual rainfall (83.3 in.) over the area. Average annual direct runoff in streams at the 800- and 400-foot altitudes is 29 and 38 million gallons per day, respectively. Kipapa Stream has the largest average annual direct runoff at those altitudes--6 and 9 million gallons per day, respectively. Because streams are flashy and have a wide range in discharge, only 60 percent of the average annual runoff can be economically diverted through ditches to recharge areas. The diversion may be increased slightly if reservoirs are used in conjunction with ditches to temporarily detain flows in excess of ditch capacity. The planned irrigation use of some of the perennial flow available in Waikele Stream near sea level will decrease pumping from and increase recharge to the basal aquifer. Suspended-sediment load is mainly silt and clay, and it increases rapidly with increased discharge. Thus, the use of streamflow for artificial recharge poses problems. High flows must be used if recharge is to be effective, but flows must not be so high as to cause clogging of recharge facilities with sediment or woodland debris. Practical tests are needed to determine the advantages and disadvantages of different types of recharge structures, such as a reservoir or basin, large-diameter deep shafts, deep wells, or combinations of all these structures.

Low-level water vapor fields from the VISSR atmospheric sounder (VAS) split window channels at 11 and 12 microns. [visible infrared spin scan radiometer

NASA Technical Reports Server (NTRS)

Chesters, D.; Uccellini, L.; Robinson, W.

1982-01-01

A series of high-resolution water vapor fields were derived from the 11 and 12 micron channels of the VISSR Atmospheric Sounder (VAS) on GOES-5. The low-level tropospheric moisture content was separated from the surface and atmospheric radiances by using the differential adsorption across the 'split window' along with the average air temperature from imbedded radiosondes. Fields of precipitable water are presented in a time sequence of five false color images taken over the United States at 3-hour intervals. Vivid subsynoptic and mesoscale patterns evolve at 15 km horizontal resolution over the 12-hour observing period. Convective cloud formations develop from several areas of enhanced low-level water vapor, especially where the vertical water vapor gradient relatively strong. Independent verification at radiosonde sites indicates fairly good absolute accuracy, and the spatial and temporal continuity of the water vapor features indicates very good relative accuracy. Residual errors are dominated by radiometer noise and unresolved clouds.

Precipitable water: Its linear retrieval using leaps and bounds procedure and its global distribution from SEASAT SMMR data

NASA Technical Reports Server (NTRS)

Pandey, P. C.

1982-01-01

Eight subsets using two to five frequencies of the SEASAT scanning multichannel microwave radiometer are examined to determine their potential in the retrieval of atmospheric water vapor content. Analysis indicates that the information concerning the 18 and 21 GHz channels are optimum for water vapor retrieval. A comparison with radiosonde observations gave an rms accuracy of approximately 0.40 g sq cm. The rms accuracy of precipitable water using different subsets was within 10 percent. Global maps of precipitable water over oceans using two and five channel retrieval (average of two and five channel retrieval) are given. Study of these maps reveals the possibility of global moisture distribution associated with oceanic currents and large scale general circulation in the atmosphere. A stable feature of the large scale circulation is noticed. The precipitable water is maximum over the Bay of Bengal and in the North Pacific over the Kuroshio current and shows a general latitudinal pattern.

Comparative statistical analysis of carcinogenic and non-carcinogenic effects of uranium in groundwater samples from different regions of Punjab, India.

PubMed

Saini, Komal; Singh, Parminder; Bajwa, Bikramjit Singh

2016-12-01

LED flourimeter has been used for microanalysis of uranium concentration in groundwater samples collected from six districts of South West (SW), West (W) and North East (NE) Punjab, India. Average value of uranium content in water samples of SW Punjab is observed to be higher than WHO, USEPA recommended safe limit of 30µgl -1 as well as AERB proposed limit of 60µgl -1 . Whereas, for W and NE region of Punjab, average level of uranium concentration was within AERB recommended limit of 60µgl -1 . Average value observed in SW Punjab is around 3-4 times the value observed in W Punjab, whereas its value is more than 17 times the average value observed in NE region of Punjab. Statistical analysis of carcinogenic as well as non carcinogenic risks due to uranium have been evaluated for each studied district. Copyright © 2016 Elsevier Ltd. All rights reserved.

Mercury pollution in Doha (Qatar) coastal environment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Al-Madfa, H.; Dahab, O.A.; Holail, H.

Surface water and sediment samples were collected from the Doha coastal area and analyzed for content of physico-chemical forms of mercury. Dissolved reactive Hg represented 81.0% of the total dissolved Hg. Organic Hg contributed only 5.0% of total Hg. Mercury showed a strong tendency to be associated with suspended matter in Doha coastal waters, as it represented about 73.0% of the total. Total Hg in bulk Doha surface sediments fluctuated between 0.14 and 1.75 [mu]g g[sup [minus]1] dry weight, with an average of 0.54 [+-] 0.46 [mu]g g[sup [minus]1] dry weight. The sediment fraction past 63 [mu]m contained 0.73 [+-]more » 0.60 [mu]g g[sup [minus]1] dry weight total Hg. Leachable and methyl Hg averaged 0.10 [+-] 0.11 and 0.02 [+-] 0.03 [mu]g g[sup [minus]1] dry weight, respectively, in the < 63-[mu]m sediment fraction. There is a general trend for all Hg species determined in water and sediments to decrease seaward. The significantly elevated Hg levels at certain locations indicated that the main Hg sources to Doha coastal environment are leachate from the solid waste disposal site, the two harbors, and surface-water discharge.« less

Does balneotherapy with low radon concentration in water influence the endocrine system? A controlled non-randomized pilot study.

PubMed

Nagy, Katalin; Berhés, István; Kovács, Tibor; Kávási, Norbert; Somlai, János; Bender, Tamás

2009-08-01

Radon bath is a well-established modality of balneotherapy for the management of degenerative musculoskeletal disorders. The present study was conducted to ascertain whether baths of relatively low (80 Bq/l) radon concentration have any influence on the functioning of the endocrine system. In the study, a non-randomized pilot study, 27 patients with degenerative musculoskeletal disorders received 30-min radon baths (of 31-32 degrees C temperature and 80 Bq/l average radon concentration) daily, for 15 days. Twenty-five patients with matching pathologies were subjected to balneotherapy according to the same protocol, using thermal water with negligible radon content (6 Bq/l). Serum thyroid stimulating hormone, prolactin, cortisol, adrenocorticotropic hormone, and dehydroepiandrosterone levels were measured before and after a balneotherapy course of 15 sessions. Comparison of the accumulated data using the Wilcoxon test did not reveal any significant difference between pre- and post-treatment values or between the two patient groups. It is noted that while the beneficial effects of balneotherapy with radon-containing water on degenerative disorders is widely known, only few data have been published in the literature on its effect on endocrine functions. The present study failed to demonstrate any substantial effect of thermal water with relatively low radon content on the functioning of the endocrine system.

Water relations and gas exchange of fan bryophytes and their adaptations to microhabitats in an Asian subtropical montane cloud forest.

PubMed

Song, Liang; Zhang, Yong-Jiang; Chen, Xi; Li, Su; Lu, Hua-Zheng; Wu, Chuan-Sheng; Tan, Zheng-Hong; Liu, Wen-Yao; Shi, Xian-Meng

2015-07-01

Fan life forms are bryophytes with shoots rising from vertical substratum that branch repeatedly in the horizontal plane to form flattened photosynthetic surfaces, which are well suited for intercepting water from moving air. However, detailed water relations, gas exchange characteristics of fan bryophytes and their adaptations to particular microhabitats remain poorly understood. In this study, we measured and analyzed microclimatic data, as well as water release curves, pressure-volume relationships and photosynthetic water and light response curves for three common fan bryophytes in an Asian subtropical montane cloud forest (SMCF). Results demonstrate high relative humidity but low light levels and temperatures in the understory, and a strong effect of fog on water availability for bryophytes in the SMCF. The facts that fan bryophytes in dry air lose most of their free water within 1 h, and a strong dependence of net photosynthesis rates on water content, imply that the transition from a hydrated, photosynthetically active state to a dry, inactive state is rapid. In addition, fan bryophytes developed relatively high cell wall elasticity and the osmoregulatory capacity to tolerate desiccation. These fan bryophytes had low light saturation and compensation point of photosynthesis, indicating shade tolerance. It is likely that fan bryophytes can flourish on tree trunks in the SMCF because of substantial annual precipitation, average relative humidity, and frequent and persistent fog, which can provide continual water sources for them to intercept. Nevertheless, the low water retention capacity and strong dependence of net photosynthesis on water content of fan bryophytes indicate a high risk of unbalanced carbon budget if the frequency and severity of drought increase in the future as predicted.

Radon Concentrations in Drinking Water in Beijing City, China and Contribution to Radiation Dose

PubMed Central

Wu, Yun-Yun; Ma, Yong-Zhong; Cui, Hong-Xing; Liu, Jian-Xiang; Sun, Ya-Ru; Shang, Bing; Su, Xu

2014-01-01

222Rn concentrations in drinking water samples from Beijing City, China, were determined based on a simple method for the continuous monitoring of radon using a radon-in-air monitor coupled to an air-water exchanger. A total of 89 water samples were sampled and analyzed for their 222Rn content. The observed radon levels ranged from detection limit up to 49 Bq/L. The calculated arithmetic and geometric means of radon concentrations in all measured samples were equal to 5.87 and 4.63 Bq/L, respectively. The average annual effective dose from ingestion of radon in drinking water was 2.78 μSv, and that of inhalation of water-borne radon was 28.5 μSv. It is concluded that it is not the ingestion of waterborne radon, but inhalation of the radon escaping from water that is a substantial part of the radiological hazard. Radon in water is a big concern for public health, especially for consumers who directly use well water with very high radon concentration. PMID:25350007

Nebulized water cooling of the canopy affects leaf temperature, berry composition and wine quality of Sauvignon blanc.

PubMed

Paciello, Pericle; Mencarelli, Fabio; Palliotti, Alberto; Ceccantoni, Brunella; Thibon, Cécile; Darriet, Philippe; Pasquini, Massimiliano; Bellincontro, Andrea

2017-03-01

The present paper details a new technique based on spraying nebulized water on vine canopy to counteract the negative impact of the current wave of hot summers with temperatures above 30 °C, which usually determine negative effects on vine yield, grape composition and wine quality. The automatized spraying system was able to maintain air temperature at below 30 °C (the threshold temperature to start spraying) for all of August 2013, when in the canopy of uncooled vines the temperature was as high as 36 °C. The maintenance of temperature below 30 °C reduced leaf stress linked to high temperature and irradiance regimes as highlighted by the decrease of H 2 O 2 content and catalase activity in the leaves. A higher amount of total polyphenols and organic acids and lower sugars characterized the grapes of cooled vines. Wine from these grapes had a higher content of some volatile thiols like 3-sulfanylhexanol (3SH) and 3-sulfanylhexylacetate (3SHA), and lower content of 4-methyl-4-sulfanylpentan-2-one (4MSP). Under conditions of high temperature and irradiance regimes, water nebulization on the vine canopy can represent a valid solution to reduce and/or avoid oxidative stress and associated effects in the leaves, ensure a regular berry ripening and maintain high wine quality. The consumption of water during nebulization was acceptable, being 180 L ha -1 min -1 , which lasted an average of about 1 min to reduce the temperature below the threshold value of 30 °C. A total of 85-90 hL (from 0.8 to 0.9 mm) of water per hectare per day was required. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

A coupled melt-freeze temperature index approach in a one-layer model to predict bulk volumetric liquid water content dynamics in snow

NASA Astrophysics Data System (ADS)

Avanzi, Francesco; Yamaguchi, Satoru; Hirashima, Hiroyuki; De Michele, Carlo

2016-04-01

Liquid water in snow rules runoff dynamics and wet snow avalanches release. Moreover, it affects snow viscosity and snow albedo. As a result, measuring and modeling liquid water dynamics in snow have important implications for many scientific applications. However, measurements are usually challenging, while modeling is difficult due to an overlap of mechanical, thermal and hydraulic processes. Here, we evaluate the use of a simple one-layer one-dimensional model to predict hourly time-series of bulk volumetric liquid water content in seasonal snow. The model considers both a simple temperature-index approach (melt only) and a coupled melt-freeze temperature-index approach that is able to reconstruct melt-freeze dynamics. Performance of this approach is evaluated at three sites in Japan. These sites (Nagaoka, Shinjo and Sapporo) present multi-year time-series of snow and meteorological data, vertical profiles of snow physical properties and snow melt lysimeters data. These data-sets are an interesting opportunity to test this application in different climatic conditions, as sites span a wide latitudinal range and are subjected to different snow conditions during the season. When melt-freeze dynamics are included in the model, results show that median absolute differences between observations and predictions of bulk volumetric liquid water content are consistently lower than 1 vol%. Moreover, the model is able to predict an observed dry condition of the snowpack in 80% of observed cases at a non-calibration site, where parameters from calibration sites are transferred. Overall, the analysis show that a coupled melt-freeze temperature-index approach may be a valid solution to predict average wetness conditions of a snow cover at local scale.

An Algorithm for Retrieving Land Surface Temperatures Using VIIRS Data in Combination with Multi-Sensors

PubMed Central

Xia, Lang; Mao, Kebiao; Ma, Ying; Zhao, Fen; Jiang, Lipeng; Shen, Xinyi; Qin, Zhihao

2014-01-01

A practical algorithm was proposed to retrieve land surface temperature (LST) from Visible Infrared Imager Radiometer Suite (VIIRS) data in mid-latitude regions. The key parameter transmittance is generally computed from water vapor content, while water vapor channel is absent in VIIRS data. In order to overcome this shortcoming, the water vapor content was obtained from Moderate Resolution Imaging Spectroradiometer (MODIS) data in this study. The analyses on the estimation errors of vapor content and emissivity indicate that when the water vapor errors are within the range of ±0.5 g/cm2, the mean retrieval error of the present algorithm is 0.634 K; while the land surface emissivity errors range from −0.005 to +0.005, the mean retrieval error is less than 1.0 K. Validation with the standard atmospheric simulation shows the average LST retrieval error for the twenty-three land types is 0.734 K, with a standard deviation value of 0.575 K. The comparison between the ground station LST data indicates the retrieval mean accuracy is −0.395 K, and the standard deviation value is 1.490 K in the regions with vegetation and water cover. Besides, the retrieval results of the test data have also been compared with the results measured by the National Oceanic and Atmospheric Administration (NOAA) VIIRS LST products, and the results indicate that 82.63% of the difference values are within the range of −1 to 1 K, and 17.37% of the difference values are within the range of ±2 to ±1 K. In a conclusion, with the advantages of multi-sensors taken fully exploited, more accurate results can be achieved in the retrieval of land surface temperature. PMID:25397919

Agronomic benefits of biochar as a soil amendment after its use as waste water filtration medium.

PubMed

Werner, Steffen; Kätzl, Korbinian; Wichern, Marc; Buerkert, Andreas; Steiner, Christoph; Marschner, Bernd

2018-02-01

In many water-scarce countries, waste water is used for irrigation which poses a health risk to farmers and consumers. At the same time, it delivers nutrients to the farming systems. In this study, we tested the hypotheses that biochar can be used as a filter medium for waste water treatment to reduce pathogen loads. At the same time, the biochar is becoming enriched with nutrients and therefore can act as a fertilizer for soil amendment. We used biochar as a filter medium for the filtration of raw waste water and compared the agronomic effects of this "filterchar" (FC) and the untreated biochar (BC) in a greenhouse pot trial on spring wheat biomass production on an acidic sandy soil from Niger. The biochar filter showed the same removal of pathogens as a common sand filter (1.4 log units on average). We did not observe a nutrient accumulation in FC compared to untreated BC. Instead, P, Mg and K were reduced during filtration while N content remained unchanged. Nevertheless, higher biomass (Triticum L. Spp.) production in BC (+72%) and FC (+37%) treatments (20 t ha -1 ), compared with the unamended control, were found. There were no significant differences in aboveground biomass production between BC and FC. Soil available P content was increased by BC (+106%) and FC (+52%) application. Besides, mineral nitrogen content was reduced in BC treated soil and to a lesser extent when FC was used. This may be explained by reduced sorption affinity for mineral nitrogen compounds on FC surfaces. Although the nutrients provided by FC decreased, due to leaching in the filter, it still yielded higher biomass than the unamended control. Copyright © 2017 Elsevier Ltd. All rights reserved.

Coccolithophore responses to environmental variability in the South China Sea: species composition and calcite content

NASA Astrophysics Data System (ADS)

Jin, Xiaobo; Liu, Chuanlian; Poulton, Alex J.; Dai, Minhan; Guo, Xianghui

2016-08-01

Coccolithophore contributions to the global marine carbon cycle are regulated by the calcite content of their scales (coccoliths) and the relative cellular levels of photosynthesis and calcification rates. All three of these factors vary between coccolithophore species and with response to the growth environment. Here, water samples were collected in the northern basin of the South China Sea (SCS) during summer 2014 in order to examine how environmental variability influenced species composition and cellular levels of calcite content. Average coccolithophore abundance and their calcite concentration in the water column were 11.82 cells mL-1 and 1508.3 pg C mL-1, respectively, during the cruise. Water samples can be divided into three floral groups according to their distinct coccolithophore communities. The vertical structure of the coccolithophore community in the water column was controlled by the trophic conditions, which were regulated by mesoscale eddies across the SCS basin. The evaluation of coccolithophore-based calcite in the surface ocean also showed that three key species in the SCS (Emiliania huxleyi, Gephyrocapsa oceanica, Florisphaera profunda) and other larger, numerically rare species made almost equal contributions to total coccolith-based calcite in the water column. For Emiliania huxleyi biometry measurements, coccolith size positively correlated with nutrients (nitrate, phosphate), and it is suggested that coccolith length is influenced by light and nutrients through the regulation of growth rates. Larger-sized coccoliths were also linked statistically to low pH and calcite saturation states; however, it is not a simple cause and effect relationship, as carbonate chemistry was strongly co-correlated with the other key environmental factors (nutrients, light).

Simultaneous measurement of unfrozen water content and ice content in frozen soil using gamma ray attenuation and TDR

NASA Astrophysics Data System (ADS)

Zhou, Xiaohai; Zhou, Jian; Kinzelbach, Wolfgang; Stauffer, Fritz

2014-12-01

The freezing temperature of water in soil is not constant but varies over a range determined by soil texture. Consequently, the amounts of unfrozen water and ice change with temperature in frozen soil, which in turn affects hydraulic, thermal, and mechanical properties of frozen soil. In this paper, an Am-241 gamma ray source and time-domain reflectometry (TDR) were combined to measure unfrozen water content and ice content in frozen soil simultaneously. The gamma ray attenuation was used to determine total water content. The TDR was used to determine the dielectric constant of the frozen soil. Based on a four-phase mixing model, the amount of unfrozen water content in the frozen soil could be determined. The ice content was inferred by the difference between total water content and unfrozen water content. The gamma ray attenuation and the TDR were both calibrated by a gravimetric method. Water contents measured by gamma ray attenuation and TDR in an unfrozen silt column under infiltration were compared and showed that the two methods have the same accuracy and response to changes of water content. Unidirectional column freezing experiments were performed to apply the combined method of gamma ray attenuation and TDR for measuring unfrozen water content and ice content. The measurement error of the gamma ray attenuation and TDR was around 0.02 and 0.01 m3/m3, respectively. The overestimation of unfrozen water in frozen soil by TDR alone was quantified and found to depend on the amount of ice content. The higher the ice content, the larger the overestimation. The study confirmed that the combined method could accurately determine unfrozen water content and ice content in frozen soil. The results of soil column freezing experiments indicate that total water content distribution is affected by available pore space and the freezing front advance rate. It was found that there is similarity between the soil water characteristic and the soil freezing characteristic of variably saturated soil. Unfrozen water content is independent of total water content and affected only by temperature when the freezing point is reached.

Precipitation patterns and moisture fluxes in a sandy, tropical environment with a shallow water table

NASA Astrophysics Data System (ADS)

Minihane, M. R.; Freyberg, D. L.

2011-08-01

Identifying the dominant mechanisms controlling recharge in shallow sandy soils in tropical climates has received relatively little attention. Given the expansion of coastal fill using marine sands and the growth of coastal populations throughout the tropics, there is a need to better understand the nature of water balances in these settings. We use time series of field observations at a coastal landfill in Singapore coupled with numerical modeling using the Richards' equation to examine the impact of precipitation patterns on soil moisture dynamics, including percolation past the root zone and recharge, in such an environment. A threshold in total precipitation event depth, much more so than peak precipitation intensity, is the strongest event control on recharge. However, shallow antecedent moisture, and therefore the timing between events along with the seasonal depth to water table, also play significant roles in determining recharge amounts. For example, at our field site, precipitation events of less than 3 mm per event yield little to no direct recharge, but for larger events, moisture content changes below the root zone are linearly correlated to the product of the average antecedent moisture content and the total event precipitation. Therefore, water resources planners need to consider identifying threshold precipitation volumes, along with the multiple time scales that capture variability in event antecedent conditions and storm frequency in assessing the role of recharge in coastal water balances in tropical settings.

Investigation of biomass production, crude protein and starch content in laboratory wastewater treatment systems planted with Lemna minor and Lemna gibba.

PubMed

Iatrou, Evangelia I; Kora, Elianta; Stasinakis, Athanasios S

2018-03-09

The use of duckweed-based wastewater treatment systems for producing biomass with high crude protein and starch content was investigated in the current study. For this reason, three lab-scale systems were used; System 1 was planted with Lemna minor, System 2 with Lemna gibba and System 3 with the combination of the two duckweeds. The studied duckweeds were cultivated using secondary treated wastewater as substrate (Phase A), in the presence of excess NH 4 -N (Phase B) and using water with no nutrients (Phase C). All systems achieved average NH 4 -N removal higher that 90%. The specific duckweeds growth rates and the specific duckweeds growth rates normalized to the area ranged between 0.14 d -1 and 8.9 g m -2  d -1 (System 1) to 0.19 d -1 and 14.9 g m -2  d -1 (System 3). The addition of NH 4 -N resulted in a significant increase of biomass protein content, reaching 44.4% in System 3, 41.9% in System 2 and 39.4% in System 1. The transfer of biomass in water containing no nutrients resulted in the gradual increment of the starch content up to the end of the experiment. The highest starch content was achieved for the combination of the two duckweeds (46.1%), followed by L. gibba (44.9%) and L. minor (43.9%).

WWW mesothelioma information: Surfing on unreliable waters. A cross-sectional study into the content and quality of online informational resources for mesothelioma patients.

PubMed

Soloukey Tbalvandany, S Sadaf; Maat, A Alexander P W M; Cornelissen, R Robin; Nuyttens, J Joost J M E; Takkenberg, J Johanna J M

2018-06-01

Malignant Mesothelioma (MM) is a rare asbestos related disease mostly diagnosed in low-skilled patients. The decision-making process for MM treatment is complicated, making an adequate provision of information necessary. The objective of this study is to assess the content and quality of online informational resources available for Dutch MM patients. The first 100 hits of a Google search were studied using the JAMA benchmarks, the Modified Information Score (MIS) and the International Patient Decision Aid Standard Scoring (IPDAS). A total of 37 sources were included. Six of the 37 resources were published by hospitals. On average, the informational resources scored 37 points on the MIS (scale 0-100). The resources from a (bio)medical sources scored the best on this scale. However, on the domain of use of language, these resources scored the worst. The current level of medical content and quality of online informational resources for patient with MM is below average and cannot be used as decision-aids for patients. The criteria used in this article could be used for future improvements of online informational resources for patients, both online, offline and through health education in the care path. Copyright © 2018 Elsevier B.V. All rights reserved.

Characterisation and treatment of VOCs in process water from upgrading facilities for compressed biogas (CBG).

PubMed

Nilsson Påledal, S; Arrhenius, K; Moestedt, J; Engelbrektsson, J; Stensen, K

2016-02-01

Compression and upgrading of biogas to vehicle fuel generates process water, which to varying degrees contains volatile organic compounds (VOCs) originating from the biogas. The compostion of this process water has not yet been studied and scientifically published and there is currently an uncertainty regarding content of VOCs and how the process water should be managed to minimise the impact on health and the environment. The aim of the study was to give an overview about general levels of VOCs in the process water. Characterisation of process water from amine and water scrubbers at plants digesting waste, sewage sludge or agricultural residues showed that both the average concentration and composition of particular VOCs varied depending on the substrate used at the biogas plant, but the divergence was high and the differences for total concentrations from the different substrate groups were only significant for samples from plants using waste compared to residues from agriculture. The characterisation also showed that the content of VOCs varied greatly between different sampling points for same main substrate and between sampling occasions at the same sampling point, indicating that site-specific conditions are important for the results which also indicates that a number of analyses at different times are required in order to make an more exact characterisation with low uncertainty. Inhibition of VOCs in the anaerobic digestion (AD) process was studied in biomethane potential tests, but no inhibition was observed during addition of synthetic process water at concentrations of 11.6 mg and 238 mg VOC/L. Copyright © 2015 Elsevier Ltd. All rights reserved.

Physical and chemical characteristics of fibrous peat

NASA Astrophysics Data System (ADS)

Sutejo, Yulindasari; Saggaff, Anis; Rahayu, Wiwik; Hanafiah

2017-11-01

Banyuasin is one of the regency in South Sumatera which has an area of 200.000 Ha of peat land. Peat soil are characterized by high compressibility parameters and low initial shear strength. Block sampling method was used to obtain undisturbed sample. The results of this paper describe the characteristics of peat soil from physical and chemical testing. The physical and chemical characteristics of peat include water content (ω), specific gravity (Gs), Acidity (pH), unit weight (γ), and ignition loss tests. SEM and EDS test was done to determine the differences in fiber content and to analyze chemical elements of the specimen. The average results ω, Gs, and pH are 263.538 %, 1.847, and 3.353. Peat is classified in H4 (by Von Post). The results of organic content (OC), ash content (AC), and fiber content (FC) are found 78.693 %, 21.310 %, and 73.703 %. From the results of physical and chemical tests, the peat in Banyuasin is classified as fibrous peat. All the results of the characteristics and classification of fibrous peat compared with published data were close.

Water in the Humboldt River Valley near Winnemucca, Nevada

USGS Publications Warehouse

Cohen, Philip M.

1966-01-01

Most of the work of the interagency Humboldt River Research Project in the Winnemucca reach of the Humboldt River valley has been completed. More than a dozen State and Federal agencies and several private organizations and individuals participated in the study. The major objective of the project, which began in 1959, is to evaluate the water resources of the entire Humboldt River basin. However, because of the large size of the basin, most of the work during the first 5 years of the project was done in the Winnemucca area. The purpose of this report is to summarize briefly and simply the information regarding the water resources of the Winnemucca area-especially the quantitative aspects of the flow system-given in previous reports of the project. The Winnemucca reach of the Humboldt River valley, which is in north-central Nevada, is about 200 miles downstream from the headwaters of the Humboldt River and includes that part of the valley between the Comus and Rose Creek gaging stations. Average annual inflow to the storage area (the valley lowlands) in the Winnemucca reach in water years 1949-62 was about 250,000 acre-feet. Of this amount, about 68 percent was Humboldt River streamflow, as measured at the Comus gaging station, 23 percent was precipitation directly on the storage area, 6 percent was ground-water inflow, and about 3 percent was tributary streamflow. Average annual streamflow at the Rose Creek gaging station during the same period was about 155,000 acre-feet, or about 17,000 acre-feet less than that at the Comus gaging station. Nearly all the streamflow lost was consumed by evapotranspiration in the project area. Total average annual evapotranspiration loss during the period was about 115,000 acre-feet, or about 42 percent of the total average annual outflow. The most abundant ions in the ground and surface water in the area are commonly sodium and bicarbonate. Much of the water has a dissolved-solids content that ranges from 500 to 750 parts per million; however, locally, the dissolved-solids content of the ground water is more than 5,000 parts per million. The chemical quality of the Humboldt River, especially during periods of low flow, reflects the chemical quality of ground-water inflow from tributary areas that discharges into the river. Almost all water in the project area is moderately hard to very hard; otherwise, it is generally suitable for most uses. Increased ground-water development, the conjunctive use of ground and surface water, and increased irrigation efficiency would probably conserve much of the water presently consumed by nonbeneficial evapotranspiration. Intensive ground-water development, especially from the highly permeable medial gravel subunit, will, however, decrease the flow of the Humboldt River to the extent that some pumpage may not be offset by a corresponding decrease in natural evapotranspiration losses. Such streamflow depletions will therefore infringe upon downstream surface-water rights. The results of this study indicate that the Humboldt River and ground water in the unconsolidated deposits beneath and adjacent to the river in the Winnemucca area are closely related. Somewhat similar conditions probably exist elsewhere in the Humboldt River valley. Additional detailed studies are needed-both upstream and downstream from the Winnemucca area-to adequately define the flow system and the interrelations among the components of the system in the remainder of the valley. Before proceeding with additional detailed studies, however, a 1-year overall appraisal of the water resources of the basin should be considered. A major objective of this study would be to provide information that would help select the next subarea of the valley to be studied in detail and to decide which of the methods of study used in the Winnemucca area could be most effectively used in the future studies.

Mud volcanoes of trinidad as astrobiological analogs for martian environments.

PubMed

Hosein, Riad; Haque, Shirin; Beckles, Denise M

2014-10-13

Eleven onshore mud volcanoes in the southern region of Trinidad have been studied as analog habitats for possible microbial life on Mars. The profiles of the 11 mud volcanoes are presented in terms of their physical, chemical, mineralogical, and soil properties. The mud volcanoes sampled all emitted methane gas consistently at 3% volume. The average pH for the mud volcanic soil was 7.98. The average Cation Exchange Capacity (CEC) was found to be 2.16 kg/mol, and the average Percentage Water Content was 34.5%. Samples from three of the volcanoes, (i) Digity; (ii) Piparo and (iii) Devil's Woodyard were used to culture bacterial colonies under anaerobic conditions indicating possible presence of methanogenic microorganisms. The Trinidad mud volcanoes can serve as analogs for the Martian environment due to similar geological features found extensively on Mars in Acidalia Planitia and the Arabia Terra region.

Mud Volcanoes of Trinidad as Astrobiological Analogs for Martian Environments

PubMed Central

Hosein, Riad; Haque, Shirin; Beckles, Denise M.

2014-01-01

Eleven onshore mud volcanoes in the southern region of Trinidad have been studied as analog habitats for possible microbial life on Mars. The profiles of the 11 mud volcanoes are presented in terms of their physical, chemical, mineralogical, and soil properties. The mud volcanoes sampled all emitted methane gas consistently at 3% volume. The average pH for the mud volcanic soil was 7.98. The average Cation Exchange Capacity (CEC) was found to be 2.16 kg/mol, and the average Percentage Water Content was 34.5%. Samples from three of the volcanoes, (i) Digity; (ii) Piparo and (iii) Devil’s Woodyard were used to culture bacterial colonies under anaerobic conditions indicating possible presence of methanogenic microorganisms. The Trinidad mud volcanoes can serve as analogs for the Martian environment due to similar geological features found extensively on Mars in Acidalia Planitia and the Arabia Terra region. PMID:25370529

Fractionation and Mobility of Thallium in Volcanic Ashes after Eruption of Eyjafjallajökull (2010) in Iceland.

PubMed

Karbowska, Bozena; Zembrzuski, Wlodzimierz

2016-07-01

Volcanic ash contains thallium (Tl), which is highly toxic to the biosphere. The aim of this study was to determine the Tl concentration in fractions of volcanic ash samples originating from the Eyjafjallajökull volcano. A sequential extraction scheme allowed for a study of element migration in the environment. Differential pulse anodic stripping voltammetry using a flow measuring system was selected as the analytical method to determine Tl content. The highest average content of Tl in volcanic ash was determined in the fraction entrapped in the aluminosilicate matrix (0.329 µg g(-1)), followed by the oxidizable fraction (0.173 µg g(-1)). The lowest content of Tl was found in the water soluble fraction (0.001 µg g(-1)); however, this fraction is important due to the fact that Tl redistribution among all the fractions occurs through the aqueous phase.

[Determination of content and entrapment efficiency of 20 (S)-protopanaxadiol in pharmacosomes by RP-HPLC method].

PubMed

Han, Meihua; Chen, Jing; Chen, Shilin; Wang, Xiangtao

2009-05-01

To establish a RP-HPLC method for content and entrapment efficiency of 20 (S)-protopanaxadiol in pharmacosomes. The separation was performed with a COSMOSIL 5 C18-MS-II column (4.6 mm x 250 mm, 5 mmicrom) using methanol-water (95:5) as the mobile phase and detected at 203 nm. The flow rate was 1.0 mL x min(-1) and 50 microL sample solution was injected for each time. The calibration curve was linear within the range 0.1-0.5 mg x mL(-1) (r = 0. 9999) , the intra-day RSD and inter-day RSD were less than 2% and the average recovery was between 101.44%-103.11% (n = 3). The method is simple, accurate, sensitive and applicable for determination of content and entrapment efficiency of 20 (S)-protopanaxadiol pharmacosomes.

Effects of hydrology on short term plant decomposition and nutrient content in a re-created Everglades wetland

NASA Astrophysics Data System (ADS)

Serna, A.; Richards, J.; Scinto, L.

2012-12-01

The effect of water depth and flow on tissue nutrients and decomposition rates of marsh plant species, and soil chemistry in vegetated plots was measured in the Loxahatchee Impoundment Landscape Assessment (LILA) facility in Boynton Beach, Florida, USA. The LILA facility consists of replicated wetland macrocosms that mimic Everglades ridge-and-slough landscape features. The experiments were conducted in two macrocosms that each had three habitats at different water depths (ridge, shallow slough and deep slough) but differed in flow. Decomposition rates of three common Everglades species, Cladium jamaicense (sawgrass), Eleocharis cellulosa (spikerush), and Nymphaea odorata (white water lily), were measured using litter bags incubated during both a wet and dry condition. Litter bag losses were more pronounced under wet conditions, and decomposition rates were not affected by the hydrologic conditions in this experiment, but rather by litter nutrient content and species. Litter nutrient (TC, TN, TP) concentrations varied over time. Species rich in the limiting nutrient (P) in the ecosystem decomposed faster. Therefore, N. odorata decomposed faster than C. jamaicense and E. cellulosa, confirming the importance of P availability in controlling microbial processes in the Everglades. Planted species had no effect on soil nutrient content over the 3 yrs period of plant growth in these plots. Our results have contributed to defining potential flow targets for restoration in Florida's Everglades by showing that average water velocities of 0.5 cm s-1 may not be sufficient to drive ecosystem changes in decomposition rates for the native species and soil chemistry.

Radiological impact of airborne effluents of coal and nuclear plants.

PubMed

McBride, J P; Moore, R E; Witherspoon, J P; Blanco, R E

1978-12-08

Radiation doses from airborne effluents of model coal-fired and nuclear power plants (1000 megawatts electric) are compared. Assuming a 1 percent ash release to the atmosphere (Environmental Protection Agency regulation) and 1 part per million of uranium and 2 parts per million of thorium in the coal (approximately the U.S. average), population doses from the coal plant are typically higher than those from pressurized-water or boiling-water reactors that meet government regulations. Higher radionuclide contents and ash releases are common and would result in increased doses from the coal plant. The study does not assess the impact of non-radiological pollutants or the total radiological impacts of a coal versus a nuclear economy.

Agricultural chemicals at the outlet of a shallow carbonate aquifer

USGS Publications Warehouse

Felton, G.K.

1996-01-01

A groundwater catchment, located in Woodford and Jessamine Counties in the Inner Bluegrass of Kentucky, was instrumented to develop long- term flow and water quality data. The land uses on this 1 620-ha catchment consist of approximately 59% in grasses consisting of beef farms, horse farms, and a golf course; 16% row crops; 6% orchard: 13% forest; and 6% residential. Water samples were analyzed twice a week for, Ca++, Mg++, Na+, Cl-, HCO3-, O4=, NO3-, total solids, suspended solids, fecal coliforms, fecal streptococci, and triazines. Flow rate and average ambient temperature were also recorded. No strong linear relationship was developed between chemical concentrations and other parameters. The transient nature of the system was emphasized by one event that drastically deviated from others. Pesticide data were summarized and the 'flushing' phenomena accredited to karst systems was discussed. The total solids content in the spring was consistent at approximately 2.06 mg/L. Fecal bacteria contamination was well above drinking water limits (fecal coliform and fetal streptococci averages were I 700 and 4 300 colony-forming-units/100 mL, respectively) and the temporal variation in bacterial contamination was not linked to any other variable.

[Effect of investment composition ratio for pure titanium crown and bridge on some mechanical properties of mould].

PubMed

Yang, Se-fei; Wang, You-xu; Guo, Tian-wen; Liu, Hong-chen

2011-11-01

To determine the optimal composition of a self-developing investment material by measuring physical and mechanical properties of mould. L(9) (3(4)) orthogonal design was adopted. One hundred and fifty specimens with the size of 80 mm × 20 mm × 20 mm were prepared to measure the atmospheric temperature bending strength, high temperature bending strength and residual bending strength. Nine specimens with the size of 5 mm diameter 25 mm heigh were prepared to survey the thermal expansion curve from ambient temperature to 1150°C. Strengths were greatly affected by fine powder proportion in refractory and water/powder ratio. When the content of fine powder was 35% and water/powder ratio was 1:7.5, adequate atmospheric temperature strength and high temperature strength could be achieved. Moreover, the residual strength was moderate. The thermal extension curves of specimens in experiment group were almost similar. And the average linear expansion coefficient was (4 ∼ 5) × 10(-6)/°C. The three kinds of bending strength of self-developing investment material are compared with commercialized investment material for titanium casting when water/powder ratio and the content of fine powder are carefully controlled.

Tannins of tamarind seed husk: preparation, structural characterization, and antioxidant activities.

PubMed

Sinchaiyakit, Puksiri; Ezure, Yohji; Sriprang, Sarin; Pongbangpho, Supakorn; Povichit, Nasapon; Suttajit, Maitree

2011-06-01

The high content (about 39%) of polymeric tannins in tamarind (Tamarindus indica L.) seed husk (TSH) was demonstrated, and an extract (crude TSE) with a high content (about 94%) of polymeric tannins was prepared from TSH with a one pot extraction using ethanol/water (3:2, v/v). The crude TSE was further purified with Sephadex LH20 to give one fraction (metTSE) eluted with methanol/water (3:2, v/v) and another (acTSE) eluted with acetone/water (3:2, v/v). The tannins of acTSE were established as polymeric proanthocyanidins (PA) by 13C NMR spectroscopy; this was further confirmed by IR and UV spectroscopy, n-BuOH/HCl and vanillin assays, and from HPLC pattern. The ratio of procyanidins to prodelphinidins was 2:3, and the average degree of polymerization of acTSE was 7. Galloylated flavan-3-ols were not detected in acTSE. The main ingredients of metTSE were confirmed to be polymeric PA by 13C NMR spectroscopy. The antioxidant activities using DPPH and ABTS assays were investigated. The IC50 values of acTSE were 4.2 +/- 0.2 (DPPH assay) and 6.2 +/- 0.3 microg/mL (ABTS assay).

Full-Scale Test Program for a Shower Wastewater Recycling System: Technical Evaluation

DTIC Science & Technology

1987-01-01

taken, each using sn average 10.6 gal of water. Hathers were permitted to use their own choice of soap and shampoo , a condition expected to exist in a...Laboratories in Richmond, VA, using a Beckman Total Organic Carbon Analyzer, Model 915. Sulfate The Hach SulfaVer 4 Sulfate Reagent was used to measure... sulfate content by the turbidimetric metal.. Turbidity A Hach Laboratory Turbidimeter, Model 2100A, was used to measure turbidity. pH A Photovolt pH meter

Asthenospheric/Lithospheric interaction beneath Lianshan (Subei Basin, Eastern China)

NASA Astrophysics Data System (ADS)

Hao, Yantao; Bonadiman, Costanza; Coltorti, Massimo; Xia, Qunke

2014-05-01

This contribution presents the geochemical characterization of peridotite xenoliths entrained in Cenozoic alkali basalts from Lianshan (Subei Basin, Eastern China). The majority of the samples are lherzolites (lh) subdivided in three groups depending on the modal contents of clinopyroxene (cpx): cpx-poor lh (6

Mesoscale simulations of confined Nafion thin films.

PubMed

Vanya, P; Sharman, J; Elliott, J A

2017-12-07

The morphology and transport properties of thin films of the ionomer Nafion, with thicknesses on the order of the bulk cluster size, have been investigated as a model system to explain the anomalous behaviour of catalyst/electrode-polymer interfaces in membrane electrode assemblies. We have employed dissipative particle dynamics (DPD) to investigate the interaction of water and fluorocarbon chains, with carbon and quartz as confining materials, for a wide range of operational water contents and film thicknesses. We found confinement-induced clustering of water perpendicular to the thin film. Hydrophobic carbon forms a water depletion zone near the film interface, whereas hydrophilic quartz results in a zone with excess water. There are, on average, oscillating water-rich and fluorocarbon-rich regions, in agreement with experimental results from neutron reflectometry. Water diffusivity shows increasing directional anisotropy of up to 30% with decreasing film thickness, depending on the hydrophilicity of the confining material. A percolation analysis revealed significant differences in water clustering and connectivity with the confining material. These findings indicate the fundamentally different nature of ionomer thin films, compared to membranes, and suggest explanations for increased ionic resistances observed in the catalyst layer.

Mesoscale simulations of confined Nafion thin films

NASA Astrophysics Data System (ADS)

Vanya, P.; Sharman, J.; Elliott, J. A.

2017-12-01

The morphology and transport properties of thin films of the ionomer Nafion, with thicknesses on the order of the bulk cluster size, have been investigated as a model system to explain the anomalous behaviour of catalyst/electrode-polymer interfaces in membrane electrode assemblies. We have employed dissipative particle dynamics (DPD) to investigate the interaction of water and fluorocarbon chains, with carbon and quartz as confining materials, for a wide range of operational water contents and film thicknesses. We found confinement-induced clustering of water perpendicular to the thin film. Hydrophobic carbon forms a water depletion zone near the film interface, whereas hydrophilic quartz results in a zone with excess water. There are, on average, oscillating water-rich and fluorocarbon-rich regions, in agreement with experimental results from neutron reflectometry. Water diffusivity shows increasing directional anisotropy of up to 30% with decreasing film thickness, depending on the hydrophilicity of the confining material. A percolation analysis revealed significant differences in water clustering and connectivity with the confining material. These findings indicate the fundamentally different nature of ionomer thin films, compared to membranes, and suggest explanations for increased ionic resistances observed in the catalyst layer.

[Effects of combined use of total alkaloids of Uncaria rhynchophylla and Coryadlis ambailis migo on cerebral ischemia-reperfusion injury in rats].

PubMed

Hu, Xue-yong; Sun, An-sheng; Sui, Yu-xia

2007-11-01

To study the effects of combined use of total alkaloids (TA) of Uncaria rhynchophylla (UR) and Coryadlis ambailis migo (CAM) on cerebral ischemia/reperfusion injury in rats. Rat model of middle cerebral artery ischemia/reperfusion was established, the changes of neurological state was scored before and after treatment with the two kinds of TA, single or combined, and the changes of cerebral infarcted volume, cerebral water content, activities of NOS and SOD and content of MDA in rats' brain were estimated as well. After being treated with the combination of both TA, the average neurological score, cerebral infracted volume, cerebral water content, activity of NOS and content of MDA in the model rats significantly decreased, and the activity of SOD was significantly increased (all P < 0.05). The effect of combined use of the two TA was higher than that of use TA of UR or CAM alone (P <0.05). Moreover, the central nervous system inhibitory effect induced by combined TA was significantly weaker than that of UR. Combined use of TA of UR and CAM may facilitate the protection against cerebral ischemia/reperfusion damage, the action mechanism might be relevant to reducing the lipid peroxidation injury of brain cells through inhibiting the NOS activity and increasing the SOD activity.

Calibrating a Soil-Vegetation-Atmosphere system with a genetical algorithm

NASA Astrophysics Data System (ADS)

Schneider, S.; Jacques, D.; Mallants, D.

2009-04-01

Accuracy of model prediction is well known for being very sensitive to the quality of the calibration of the model. It is also known that quantifying soil hydraulic parameters in a Soil-Vegetation-Atmosphere (SVA) system is a highly non-linear parameter estimation problem, and that robust methods are needed to avoid the optimization process to lead to non-optimal parameters. Evolutionary algorithms and specifically genetic algorithms (GAs) are very well suited for those complex parameter optimization problems. The SVA system in this study concerns a pine stand on a heterogeneous sandy soil (podzol) in the north of Belgium (Campine region). Throughfall and other meteorological data and water contents at different soil depths have been recorded during one year at a daily time step. The water table level, which is varying between 95 and 170 cm, has been recorded with a frequency of 0.5 hours. Based on the profile description, four soil layers have been distinguished in the podzol and used for the numerical simulation with the hydrus1D model (Simunek and al., 2005). For the inversion procedure the MYGA program (Yedder, 2002), which is an elitism GA, was used. Optimization was based on the water content measurements realized at the depths of 10, 20, 40, 50, 60, 70, 90, 110, and 120 cm to estimate parameters describing the unsaturated hydraulic soil properties of the different soil layers. Comparison between the modeled and measured water contents shows a good similarity during the simulated year. Impacts of short and intensive events (rainfall) on the water content of the soil are also well reproduced. Errors on predictions are on average equal to 5%, which is considered as a good result. A. Ben Haj Yedder. Numerical optimization and optimal control : (molecular chemistry applications). PhD thesis, Ecole Nationale des Ponts et Chaussées, 2002. Šimůnek, J., M. Th. van Genuchten, and M. Šejna, The HYDRUS-1D software package for simulating the one-dimensional movement of water, heat, and multiple solutes in variably saturated media. Version 3.0, HYDRUS Software Series 1, Department of Environmental Sciences, University of California Riverside, Riverside, CA, 270 pp., 2005.

Hydrogeochemical characterization of fluoride rich groundwater of Wailpalli watershed, Nalgonda District, Andhra Pradesh, India.

PubMed

Reddy, A G S; Reddy, D V; Rao, P N; Prasad, K Maruthy

2010-12-01

The groundwater of Nalgonda district is well known for its very high fluoride content for the past five decades. Many researchers have contributed their scientific knowledge to unravel causes for fluoride enrichment of groundwater. In the present paper, an attempt has been made to relate the high fluoride content in the groundwater to hydrogeochemical characterization of the water in a fracture hard rock terrain--the Wailpally watershed. Groundwater samples collected from all the major geomorphic units in pre- and post-monsoon seasons were analyzed for its major ion constituents such as Ca(2+), Mg(2+), Na(+), K(+), CO3-, HCO3-, Cl(-), SO4(-2), NO3-, and F(-). The groundwaters in the watershed have the average fluoride content of 2.79 mg/l in pre-monsoon and 2.83 mg/l in post-monsoon. Fluoride concentration in groundwater does not show perceptible change neither with time nor in space. The ionic dominance pattern is in the order of Na(+) > Ca(2+) > Mg(2+) > K(-) among cations and HCO3- Cl(-) > SO4(-2) NO3- F(-) among anions in pre-monsoon. In post-monsoon, Mg replaces Ca(2+) and NO3- takes the place of SO4(-2). The Modified Piper diagram reflect that the water belong to Ca(+2)-Mg(+2)-HCO3- to Na(+)-HCO3- facies. Negative chloralkali indices in both the seasons prove that ion exchange between Na(+) and K(+) in aquatic solution took place with Ca(+2) and Mg(+2) of host rock. The interpretation of plots for different major ions and molar ratios suggest that weathering of silicate rocks and water-rock interaction is responsible for major ion chemistry of groundwater in Wailpally watershed. Chemical characteristics and evolution of this fluoride-contaminated groundwater is akin to normal waters of other hard rock terrain; hence, it can be concluded that aquifer material play an important role in the contribution of fluoride in to the accompanying water. High fluoride content in groundwater can be attributed to the continuous water-rock interaction during the process of percolation with fluoride-bearing country rocks under arid, low precipitation, and high evapotranspiration conditions.

[Distribution characteristics of polycyclic aromatic hydrocarbons in runoff from the middle line source area of south-to-north water diversion project].

PubMed

Tai, Chao; Zhang, Kun-Feng; Zhou, Tian-Jian; Zhao, Tong-Qian; Wang, Qing-Qing; He, Xiao-Qi

2011-07-01

The distribution characteristics of polycyclic aromatic hydrocarbons in runoff from the middle line source area of south-to-north water diversion project were studied. Five groups of artificial runoff fields were established to collect runoff based on the different types of land-use, the contents of 16 USEPA priority PAHs in the runoff were determined using GC/MS method. The results showed that the average concentrations of PAHs of the aqueous phase in the collected runoff samples of different land-use types decreased in the order:cultivated land (26.53 ng x L(-1)) > oak forest (20.91 ng x L(-1)) > orchard (17.59 ng x L(-1)), and the average concentrations of PAHs of the particle phase were cultivated land (1 073.72 ng x g(-1)) > orchard (652.29 ng x g(-1)) > oak forest (385.46 ng x g(-1)). The high carcinogenic components Bap were detected in both run off of cultivated land and orchard with a detected rate of 30%. According to National Recommended Water Quality Standards of priority toxic pollutants (2006 USEPA), it was found that Chr exceed standard 40%, with a detected rate of 100%. It was also found that the runoff volume and the total PAHs content in runoff increase with the slope, and PAHs loss and slope were closely related in same land-use types. Based on the Molecular Markers Indicative Law, it can be concluded that the dominant source of PAHs in runoff of study area was combustion of coal, and a small amount came from vehicle exhaust emissions. There is a certain degree of ecological risk about runoff PAHs pollution in the study area, which is worth further attention.

Bacterial colonization of the phyllosphere of mediterranean perennial species as influenced by leaf structural and chemical features.

PubMed

Yadav, R K P; Karamanoli, K; Vokou, D

2005-08-01

In this study, we assessed various leaf structural and chemical features as possible predictors of the size of the phyllosphere bacterial population in the Mediterranean environment. We examined eight perennial species, naturally occurring and coexisting in the same area, in Halkidiki (northern Greece). They are Arbutus unedo, Quercus coccifera, Pistacia lentiscus, and Myrtus communis (evergreen sclerophyllous species), Lavandula stoechas and Cistus incanus (drought semi-deciduous species), and Calamintha nepeta and Melissa officinalis (non-woody perennial species). M. communis, L. stoechas, C. nepeta, and M. officinalis produce essential oil in substantial quantities. We sampled summer leaves from these species and (1) estimated the size of the bacterial population of their phyllosphere, (2) estimated the concentration of different leaf constituents, and (3) studied leaf morphological and anatomical features and expressed them in a quantitative way. The aromatic plants are on average more highly colonized than the other species, whereas the non-woody perennials are more highly colonized than the woody species. The population size of epiphytic bacteria is positively correlated with glandular and non-glandular trichome densities, and with water and phosphorus contents; it is negatively correlated with total phenolics content and the thickness of the leaf, of the mesophyll, and of the abaxial epidermis. No correlation was found with the density of stomata, the nitrogen, and the soluble sugar contents. By regression tree analysis, we found that the leaf-microbe system can be effectively described by three leaf attributes with leaf water content being the primary explanatory attribute. Leaves with water content >73% are the most highly colonized. For leaves with water content <73%, the phosphorus content, with a critical value of 1.34 mg g(-1) d.w., is the next explanatory leaf attribute, followed by the thickness of the adaxial epidermis. Leaves higher in phosphorus (>1.34 mg g(-1) d.w.) are more colonized, and leaves with the adaxial epidermis thicker than 20.77 microm are the least colonized. Although these critical attributes and values hold true only within the Mediterranean ecosystem studied and the range of observations taken, they are important because they provide a hypothesis to be tested in other Mediterranean ecosystems and other biomes. Such comparative studies may give insight as to the general properties governing the leaf-microbe system.

Determining the Uncertainty of X-Ray Absorption Measurements

PubMed Central

Wojcik, Gary S.

2004-01-01

X-ray absorption (or more properly, x-ray attenuation) techniques have been applied to study the moisture movement in and moisture content of materials like cement paste, mortar, and wood. An increase in the number of x-ray counts with time at a location in a specimen may indicate a decrease in moisture content. The uncertainty of measurements from an x-ray absorption system, which must be known to properly interpret the data, is often assumed to be the square root of the number of counts, as in a Poisson process. No detailed studies have heretofore been conducted to determine the uncertainty of x-ray absorption measurements or the effect of averaging data on the uncertainty. In this study, the Poisson estimate was found to adequately approximate normalized root mean square errors (a measure of uncertainty) of counts for point measurements and profile measurements of water specimens. The Poisson estimate, however, was not reliable in approximating the magnitude of the uncertainty when averaging data from paste and mortar specimens. Changes in uncertainty from differing averaging procedures were well-approximated by a Poisson process. The normalized root mean square errors decreased when the x-ray source intensity, integration time, collimator size, and number of scanning repetitions increased. Uncertainties in mean paste and mortar count profiles were kept below 2 % by averaging vertical profiles at horizontal spacings of 1 mm or larger with counts per point above 4000. Maximum normalized root mean square errors did not exceed 10 % in any of the tests conducted. PMID:27366627

Trace Element Geochemistry as a Tool for the Reconstruction of Upwelling Patterns at 12oS off Peru since the Last Glacial Maximum (LGM)

NASA Astrophysics Data System (ADS)

Boening, P.; Brumsack, H.; Wolf, A.

2002-05-01

Laminated sediments (core 106KL), recovered during R/V Sonne cruise 147 from the Peruvian upper slope mud lens at 12oS, were analyzed for bulk parameters (TOC, TIC, TS) and opal as well as major and trace element composition by XRF and ICP-MS in 5 cm intervals. The composition of the terrigenous-detrital sediment fraction is comparable to average shale. The sediments exhibit slight increases in biogenic silica (diatoms) and carbonate contents (foraminifera) in varying layers. The experimentally determined opal contents correlate well with Si/Al ratios. High TOC and P contents are due to enhanced primary productivity, high sedimentation rates and corresponding organic matter preservation under a strong OMZ. We distinguish between three different groups of elements: 1.) trace elements involved in bio-cycling (e.g. Cd, Ag, Ni, Cu) are highly enriched in the sediments due to their association with plankton, high sedimentation rates (preventing remobilization from the sediments) and fixation as sulfides. 2.) redox-sensitive elements (e.g. Re, Mo) are significantly enriched probably due to reduction and precipitation under suboxic/anoxic conditions. Diffusion of these elements from the water column into sub/anoxic sediments seems to be the controlling factor, besides sulfide precipitation. An average Re/Mo ratio of 1.3 indicates anoxic sedimentary conditions. Most trace elements correlate well with the TOC content presumably documenting productivity events. 3.) Al, Zr and Y are well correlated, presumably representing sporadic high-energy fluvial input from the continent or enhanced current velocities. The three element groups were used to reconstruct the upwelling patterns off Lima since the LGM: TOC content and Al-normalized trace element patterns from the bio/redox-sensitive fractions represent the signal from the water column, whereas Al, Y and Zr reflect the terrigenous input. During the LGM (about 17 ky BP) the site was hardly affected by upwelling as the upwelling cell was located more basinward. As the sea level rose during the Late Glacial (17-10 ky BP) the upwelling cell shifted towards the coast. The Early Holocene (10-5 ky BP) is not documented likely because strong currents (presumably the Peru counter current) eroded the slope. In the Late Holocene the upwelling cell was established at the site. However, a higher terrrigenous proportion and lower input from the water column suggest a basinward shifting of the upwelling cell during the Second Neoglacial (2000-2700 BP). Stronger Element/Al and TOC variabilities indicate the influence of El Nino during the Late Holocene.

[Distribution and source of particulate organic carbon and particulate nitrogen in the Yangtze River Estuary in summer 2012].

PubMed

Xing, Jian-Wei; Xian, Wei-Wei; Sheng, Xiu-Zhen

2014-07-01

Based on the data from the cruise carried out in August 2012 in the Yangtze River Estuary and its adjacent waters, spatial distributions of particulate organic carbon (POC), particulate nitrogen (PN) and their relationships with environmental factors were studied, and the source of POC and the contribution of phytoplankton to POC were analyzed combined with n (C)/n (N) ratio and chlorophyll a (Chl a) in the Yangtze River Estuary in summer 2012. The results showed that the concentrations of POC in the Yangtze River Estuary ranged from 0.68 mg x L(-1) to 34.80 mg x L(-1) in summer and the average content was 3.74 mg x L(-1), and PN contents varied between 0.03 mg x L(-1) and 9.13 mg x L(-1) with an average value of 0.57 mg x L(-1). Both of them presented that the concentrations in bottom layers were higher than those in the surface. POC and PN as well as total suspended matter (TSM) showed a extremel similar horizontal distribution trend that the highest values appeared in the near of the mouth and southwest of the survey waters, and decreased rapidly as toward the open seas, both of them showed higher contents in coastal zones and lower in outer sea. There was a fairly good positive linear relationship between POC and PN, which indicated that they had the same source. POC and PN expressed significantly positive correlations with TSM and chemical oxygen demand (COD), but showed relatively weak correlations with salinit and chlorophyll a, which demonstrated that terrestrial inputs had a strong influence on the distribution of POC and PN, and phytoplankton production was not the major source of organic matters in the Yangtze River Estuary. Both the n (C)/n (N) ratio and POC/Chl a analysis showed that the main source of POC was terrestrial inputs, and organic debris was the main existence form of POC. Quantitative analysis showed the biomass of phytoplankton only made an average of 2.54% contribution to POC in the Yangtze Rive Estuary in summer and non-living POC occupied the overwhelming advantage.

[Determination of aniline in water and fish by liquid chromatography-tandem mass spectrometry].

PubMed

He, Dechun; Zhao, Bo; Tang, Caiming; Xu, Zhencheng; Zhang, Sukun; Han, Jinglei

2014-09-01

A fast analytical method for the determination of aniline in water and fish meat by liquid chromatography-tandem mass spectrometry (LC-MS/MS) has been developed. The water sample was mixed with acetonitrile by 4:1 (v/v) and the fish sample was extracted by 2.00 mL acetonitrile for each gram of sample, and then the extracts of water and fish samples were centrifuged at 5,000 r/min for 5 min. The separation was performed on a reversed-phase C18 column using mobile phases of acetonitrile-0.5% (v/v) formic acid aqueous solution (85:15, v/v). Aniline was separated within 3 min. The calibration curve was linear in the range of 0.5-500 pg/L with R2 > 0.999. The limits of detection (LODs) were 0.50 μg/L and 1.00 μg/kg and the limits of quantification (LOQs) were 1.00 μg/L and 2.00 μg/kg for aniline in water and fish meat, respectively. The average recoveries of aniline in water were 93.7% at the spiked level of 40 ng and 86.7% at the spiked level of 400 ng (n = 5). The average recoveries of aniline in fish were 96.8%, 92.6% and 81.8% at the spiked levels of 5, 50 and 500 ng respectively (n = 5). The relative standard deviations were 1.5%-9.2%. Thirteen water samples and twelve fish samples were collected from a reservoir polluted by aniline and the maximum contents found were 1,943. 6 μg/L in water and 60.8 μg/kg in fish. The method is suitable for the determination of aniline residues in water and fish with the characteristics of easy operation, high accuracy and precision.

Analysis of Heavy Metal Content (Pb) on Waters and Fish at The Floating Cages BPPP Ambon

NASA Astrophysics Data System (ADS)

Wattimena, Rachel L.; Selanno, Debby A. J.; Tuhumury, Semuel F.; Tuahatu, Juliana W.

2018-02-01

Coastal waters play important roles due to highly in natural resources and developing of environmental services. However, there are highly intensity of natural resources utilization, environment and settlement. Consequently, environment and natural resources would be degraded such as in the Ambon Bay. One of the potency at the Ambon Bay is mariculture area namely the floating cages (KJA) which belongs to Fisheries education and training (BPPP) Ambon. The research aimed to analyze physical-chemical of waters (temperature, pH, salinity and current speed), to analyze heavy metal concentration (Pb) on water and fish from floating cages (KJA) and to analyze waters pollution status at KJA BPPP Ambon. The average salinity of each floating cage ranged from 30.09 - 30.34°C, pH ranged from 8.03 - 8.44, salinity ranged from 31.36 - 33.34 PSU, and current speed at spring tide ranged from 0.5 - 55.8 Cm/sec while neap tide ranged from 0.1 - 9.8 Cm/sec. Heavy metal concentration (Pb) on waters was below the standard for waters quality and the average concentration was 0.002 mg/l. Whilst, the heavy metal concentration (Pb) on fishes was below standard for floating cages (floating cages 2-6) which was 0.05 and 0.17mg/l. Otherwise, floating cage 1 had been above maximum standard for fish food and its processing following SNI 7387:2009 (0.3mg/l) which was 0.31 mg/l. The status of waters pollution at KJA BPPP Ambon belonged to C class and could be categorized as moderate based on standard for waters quality issued by State Ministerial Decree for the Environment No. 51 Year 2004.

Calibration and use of an interactive-accounting model to simulate dissolved solids, streamflow, and water-supply operations in the Arkansas River basin, Colorado

USGS Publications Warehouse

Burns, A.W.

1989-01-01

An interactive-accounting model was used to simulate dissolved solids, streamflow, and water supply operations in the Arkansas River basin, Colorado. Model calibration of specific conductance to streamflow relations at three sites enabled computation of dissolved-solids loads throughout the basin. To simulate streamflow only, all water supply operations were incorporated in the regression relations for streamflow. Calibration for 1940-85 resulted in coefficients of determination that ranged from 0.89 to 0.58, and values in excess of 0.80 were determined for 16 of 20 nodes. The model then incorporated 74 water users and 11 reservoirs to simulate the water supply operations for two periods, 1943-74 and 1975-85. For the 1943-74 calibration, coefficients of determination for streamflow ranged from 0.87 to 0.02. Calibration of the water supply operations resulted in coefficients of determination that ranged from 0.87 to negative for simulated irrigation diversions of 37 selected water users. Calibration for 1975-85 was not evaluated statistically, but average values and plots of reservoir contents indicated reasonableness of the simulation. To demonstrate the utility of the model, six specific alternatives were simulated to consider effects of potential enlargement of Pueblo Reservoir. Three general major alternatives were simulated: the 1975-85 calibrated model data, the calibrated model data with an addition of 30 cu ft/sec in Fountain Creek flows, and the calibrated model data plus additional municipal water in storage. These three major alternatives considered the options of reservoir enlargement or no enlargement. A 40,000-acre-foot reservoir enlargement resulted in average increases of 2,500 acre-ft in transmountain diversions, of 800 acre-ft in storage diversions, and of 100 acre-ft in winter-water storage. (USGS)

Perceptions of water use

PubMed Central

Attari, Shahzeen Z.

2014-01-01

In a national online survey, 1,020 participants reported their perceptions of water use for household activities. When asked for the most effective strategy they could implement to conserve water in their lives, or what other Americans could do, most participants mentioned curtailment (e.g., taking shorter showers, turning off the water while brushing teeth) rather than efficiency improvements (e.g., replacing toilets, retrofitting washers). This contrasts with expert recommendations. Additionally, some participants are more likely to list curtailment actions for themselves, but list efficiency actions for other Americans. For a sample of 17 activities, participants underestimated water use by a factor of 2 on average, with large underestimates for high water-use activities. An additional ranking task showed poor discrimination of low vs. high embodied water content in food products. High numeracy scores, older age, and male sex were associated with more accurate perceptions of water use. Overall, perception of water use is more accurate than the perception of energy consumption and savings previously reported. Well-designed efforts to improve public understanding of household water use could pay large dividends for behavioral adaptation to temporary or long-term decreases in availability of fresh water. PMID:24591608

Analysis of weather changes in the region of Surabaya in 2015 and 2016 using water vapor data from GPS and Terra MODIS satellite image

NASA Astrophysics Data System (ADS)

Cahyadi, M. N.; Audah, S.; Mutia, N.; Aliyan, S. A.

2017-07-01

Sea surface temperature conditions in the territorial waters of Indonesia can be used as one indicator of a lot or least the content of water vapor in the atmosphere. It is closely related to the process of cloud formation in the region of Indonesia. Surabaya is the capital of the Indonesia's second largest potential for the occurrence of global warming due to climate change around the region. Global warming has the consequence of occurrence of climate variability, with marked by changes in temperature, and rainfall, as well as runoff of water. Monitoring the space-based Global Positioning System (GPS) and remote sensing satellite data such as Terra MODIS can be used in the field of meteorology. That is to measured the level of water vapor globally, with the approach of the amount of precipitable water vapor (PWV) in the atmosphere layer. It can be seen humidity conditions and the potential occurrence of rainfall in an area. The PWV value obtained from GPS processing had range 25.13 mm - 32.87 mm; average value is 27.38 mm and standard deviation is 2.018 mm. Based on the diurnal variation of the PWV GPS indicates that the climatic conditions in the area of Surabaya in 2015 showed the dry season, this is because the average values of PWV pretty low that occurred in July-September. But in September 2015 the PWV value occurrence an increase in water vapor and can be estimated that in the next month will be approaching rainy season.

The implementation of reverse Kessler warm rain scheme for radar reflectivity assimilation using a nudging approach in New Zealand

NASA Astrophysics Data System (ADS)

Zhang, Sijin; Austin, Geoff; Sutherland-Stacey, Luke

2014-05-01

Reverse Kessler warm rain processes were implemented within the Weather Research and Forecasting Model (WRF) and coupled with a Newtonian relaxation, or nudging technique designed to improve quantitative precipitation forecasting (QPF) in New Zealand by making use of observed radar reflectivity and modest computing facilities. One of the reasons for developing such a scheme, rather than using 4D-Var for example, is that radar VAR scheme in general, and 4D-Var in particular, requires computational resources beyond the capability of most university groups and indeed some national forecasting centres of small countries like New Zealand. The new scheme adjusts the model water vapor mixing ratio profiles based on observed reflectivity at each time step within an assimilation time window. The whole scheme can be divided into following steps: (i) The radar reflectivity is firstly converted to rain water, and (ii) then the rain water is used to derive cloud water content according to the reverse Kessler scheme; (iii) The cloud water content associated water vapor mixing ratio is then calculated based on the saturation adjustment processes; (iv) Finally the adjusted water vapor is nudged into the model and the model background is updated. 13 rainfall cases which occurred in the summer of 2011/2012 in New Zealand were used to evaluate the new scheme, different forecast scores were calculated and showed that the new scheme was able to improve precipitation forecasts on average up to around 7 hours ahead depending on different verification thresholds.

Impact of hydrotherapy on skin blood flow: How much is due to moisture and how much is due to heat?

PubMed

Petrofsky, Jerrold; Gunda, Shashi; Raju, Chinna; Bains, Gurinder S; Bogseth, Michael C; Focil, Nicholas; Sirichotiratana, Melissa; Hashemi, Vahideh; Vallabhaneni, Pratima; Kim, Yumi; Madani, Piyush; Coords, Heather; McClurg, Maureen; Lohman, Everett

2010-02-01

Hydrotherapy and whirlpool are used to increase skin blood flow and warm tissue. However, recent evidence seems to show that part of the increase in skin blood flow is not due to the warmth itself but due to the moisture content of the heat. Therefore, two series of experiments were accomplished on 10 subjects with an average age of 24.2 +/- 9.7 years and free of diabetes and cardiovascular disease. Subjects sat in a 37 degrees C hydrotherapy pool under two conditions: one in which a thin membrane protecting their skin from moisture while their arm was submerged in water and the second where their arm was allowed to be exposed to the water for 15 minutes. During this period of time, skin and body temperature were measured as well as skin blood flow by a Laser Doppler Imager. The results of the experiments showed that the vapor barrier blocked any change in skin moisture content during submersion in water, and while skin temperature was the same as during exposure to the water, the blood flow with the arm exposed to water increased from 101.1 +/- 10.4 flux to 224.9 +/- 18.2 flux, whereas blood flow increased to only 118.7 +/- 11.4 flux if the moisture of the water was blocked. Thus, a substantial portion of the increase in skin blood flow associated with warm water therapy is probably associated with moisturizing of the skin rather than the heat itself.

Evapotranspiration and microclimate at a low-level radioactive-waste disposal site in northwestern Illinois

USGS Publications Warehouse

Healy, R.W.; DeVries, M.P.; Sturrock, A.M.

1987-01-01

From July 1982 through June 1984, a study was made of the microclimate and evapotranspiration at a low-level radioactive-waste disposal site near Sheffield, Bureau County, Illinois. Vegetation at the site consists of mixed pasture grasses, primarily brome (Bromus inermis) and red clover (Trifoleum pratense). Three methods were used to estimate evapotranspiration: (1) an energy-budget with the Bowen ratio, (2) an aerodynamic-profile, and (3) a soil-based water-budget. For the aerodynamic-profile method, sensible-heat flux was estimated by a profile equation and evapotranspiration was then calculated as the residual in the energy-balance equation. Estimates by the energy-budget and aerodynamic-profile methods were computed from hourly data, then summed by days and months. Yearly estimates for March through November, by these methods, were quite close--648 and 626 millimeters, respectively. Daily estimates range up to a maximum of about 6 millimeters. The water-budget method produced only monthly estimates based on weekly or biweekly soil-moisture content measurements. The yearly evapotranspiration estimated by this method (which actually included only the months of April through October) was 655 millimeters. The March-through-November average for the three methods of 657 millimeters was equivalent to 70 percent of precipitation. Continuous measurements were made of incoming and reflected shortwave radiation, incoming and emitted longwave radiation, net radiation, soil-heat flux, soil temperature, horizontal windspeed, and wet- and dry-bulb air temperature. Windspeed and air temperature were measured at heights of 0.5 and 2.0 meters (and also at 1.0 meter after September 1983). Soil-moisture content of the soil zone was measured with a gamma-attenuation gage. Annual precipitation (938 millimeters) and average temperature (10.8 degrees Celsius) were virtually identical to long-term averages from nearby National Weather Service stations. Solar radiation averaged 65 percent of that normally expected under clear skies. Net radiation averaged 70.1 watts per square meter and was highest in July and negative during some winter months. Wind direction varied but was predominately out of the south-southeast. Wind speed at the 2-meter height averaged 3.5 meters per second and was slightly higher in winter months than the rest of the year. The amount of water stored within the soil zone was greatest in early spring and least in late summer. Seasonal and diurnal trends in evapotranspiration rates mirrored those in net radiation; July was usually the month with the highest rate. The ratio of sensible- to latent-heat fluxes (commonly called the Bowen ratio) for the 2-year period was 0.38, as averaged from the three methods. Monthly Bowen ratios fluctuated somewhat but averaged about 0.35 for late spring through summer. In fall, the ratio declined to zero or to slightly negative values. When the ratio was negative, the latent-heat flux was slightly greater than the net radiation because of additional energy supplied by the cooling soil and air. Evapotranspiration calculated by the three methods averaged 75 percent of potential evapotranspiration, as estimated by the Penman equation. There was no apparent seasonal trend in the relation between actual and potential evapotranspiration rates.

Laboratory calibration and field testing of the Chemcatcher-Metal for trace levels of rare earth elements in estuarine waters.

PubMed

Petersen, Jördis; Pröfrock, Daniel; Paschke, Albrecht; Broekaert, Jose A C; Prange, Andreas

2015-10-01

Little knowledge is available about water concentrations of rare earth elements (REEs) in the marine environment. The direct measurement of REEs in coastal waters is a challenging task due to their ultra-low concentrations as well as the high salt content in the water samples. To quantify these elements at environmental concentrations (pg L(-1) to low ng L(-1)) in coastal waters, current analytical techniques are generally expensive and time consuming, and require complex chemical preconcentration procedures. Therefore, an integrative passive sampler was tested as a more economic alternative sampling approach for REE analysis. We used a Chemcatcher-Metal passive sampler consisting of a 3M Empore Chelating Disk as the receiving phase, as well as a cellulose acetate membrane as the diffusion-limiting layer. The effect of water turbulence and temperature on the uptake rates of REEs was analyzed during 14-day calibration experiments by a flow-through exposure tank system. The sampling rates were in the range of 0.42 mL h(-1) (13 °C; 0.25 m s(-1)) to 4.01 mL h(-1) (13 °C; 1 m s(-1)). Similar results were obtained for the different REEs under investigation. The water turbulence was the most important influence on uptake. The uptake rates were appropriate to ascertain time-weighted average concentrations of REEs during a field experiment in the Elbe Estuary near Cuxhaven Harbor (exposure time 4 weeks). REE concentrations were determined to be in the range 0.2 to 13.8 ng L(-1), where the highest concentrations were found for neodymium and samarium. In comparison, most of the spot samples measured along the Chemcatcher samples had REE concentrations below the limit of detection, in particular due to necessary dilution to minimize the analytical problems that arise with the high salt content in marine water samples. This study was among the first efforts to measure REE levels in the field using a passive sampling approach. Our results suggest that passive samplers could be an effective tool to monitor ultra-trace concentrations of REEs in coastal waters with high salt content.

Forest Management Intensity Affects Aquatic Communities in Artificial Tree Holes.

PubMed

Petermann, Jana S; Rohland, Anja; Sichardt, Nora; Lade, Peggy; Guidetti, Brenda; Weisser, Wolfgang W; Gossner, Martin M

2016-01-01

Forest management could potentially affect organisms in all forest habitats. However, aquatic communities in water-filled tree-holes may be especially sensitive because of small population sizes, the risk of drought and potential dispersal limitation. We set up artificial tree holes in forest stands subject to different management intensities in two regions in Germany and assessed the influence of local environmental properties (tree-hole opening type, tree diameter, water volume and water temperature) as well as regional drivers (forest management intensity, tree-hole density) on tree-hole insect communities (not considering other organisms such as nematodes or rotifers), detritus content, oxygen and nutrient concentrations. In addition, we compared data from artificial tree holes with data from natural tree holes in the same area to evaluate the methodological approach of using tree-hole analogues. We found that forest management had strong effects on communities in artificial tree holes in both regions and across the season. Abundance and species richness declined, community composition shifted and detritus content declined with increasing forest management intensity. Environmental variables, such as tree-hole density and tree diameter partly explained these changes. However, dispersal limitation, indicated by effects of tree-hole density, generally showed rather weak impacts on communities. Artificial tree holes had higher water temperatures (on average 2°C higher) and oxygen concentrations (on average 25% higher) than natural tree holes. The abundance of organisms was higher but species richness was lower in artificial tree holes. Community composition differed between artificial and natural tree holes. Negative management effects were detectable in both tree-hole systems, despite their abiotic and biotic differences. Our results indicate that forest management has substantial and pervasive effects on tree-hole communities and may alter their structure and functioning. We furthermore conclude that artificial tree-hole analogues represent a useful experimental alternative to test effects of changes in forest management on natural communities.

Mixed artificial grasslands with more roots improved mine soil infiltration capacity

NASA Astrophysics Data System (ADS)

Wu, Gao-Lin; Yang, Zheng; Cui, Zeng; Liu, Yu; Fang, Nu-Fang; Shi, Zhi-Hua

2016-04-01

Soil water is one of the critical limiting factors in achieving sustainable revegetation. Soil infiltration capacity plays a vital role in determining the inputs from precipitation and enhancing water storage, which are important for the maintenance and survival of vegetation patches in arid and semi-arid areas. Our study investigated the effects of different artificial grasslands on soil physical properties and soil infiltration capacity. The artificial grasslands were Medicago sativa, Astragalus adsurgens, Agropyron mongolicum, Lespedeza davurica, Bromus inermis, Hedysarum scoparium, A. mongolicum + Artemisia desertorum, A. adsurgens + A. desertorum and M. sativa + B. inermis. The soil infiltration capacity index (SICI), which was based on the average infiltration rate of stage I (AIRSI) and the average infiltration rate of stage III (AIRS III), was higher (indicating that the infiltration capacity was greater) under the artificial grasslands than that of the bare soil. The SICI of the A. adsurgens + A. desertorum grassland had the highest value (1.48) and bare soil (-0.59) had the lowest value. It was evident that artificial grassland could improve soil infiltration capacity. We also used principal component analysis (PCA) to determine that the main factors that affected SICI were the soil water content at a depth of 20 cm (SWC20), the below-ground root biomasses at depths of 10 and 30 cm (BGB10, BGB30), the capillary porosity at a depth of 10 cm (CP10) and the non-capillary porosity at a depth of 20 cm (NCP20). Our study suggests that the use of Legume-poaceae mixtures and Legume-shrub mixtures to create grasslands provided an effective ecological restoration approach to improve soil infiltration properties due to their greater root biomasses. Furthermore, soil water content, below-ground root biomass, soil capillary porosity and soil non-capillary porosity were the main factors that affect the soil infiltration capacity.

Forest Management Intensity Affects Aquatic Communities in Artificial Tree Holes

PubMed Central

Petermann, Jana S.; Rohland, Anja; Sichardt, Nora; Lade, Peggy; Guidetti, Brenda; Weisser, Wolfgang W.; Gossner, Martin M.

2016-01-01

Forest management could potentially affect organisms in all forest habitats. However, aquatic communities in water-filled tree-holes may be especially sensitive because of small population sizes, the risk of drought and potential dispersal limitation. We set up artificial tree holes in forest stands subject to different management intensities in two regions in Germany and assessed the influence of local environmental properties (tree-hole opening type, tree diameter, water volume and water temperature) as well as regional drivers (forest management intensity, tree-hole density) on tree-hole insect communities (not considering other organisms such as nematodes or rotifers), detritus content, oxygen and nutrient concentrations. In addition, we compared data from artificial tree holes with data from natural tree holes in the same area to evaluate the methodological approach of using tree-hole analogues. We found that forest management had strong effects on communities in artificial tree holes in both regions and across the season. Abundance and species richness declined, community composition shifted and detritus content declined with increasing forest management intensity. Environmental variables, such as tree-hole density and tree diameter partly explained these changes. However, dispersal limitation, indicated by effects of tree-hole density, generally showed rather weak impacts on communities. Artificial tree holes had higher water temperatures (on average 2°C higher) and oxygen concentrations (on average 25% higher) than natural tree holes. The abundance of organisms was higher but species richness was lower in artificial tree holes. Community composition differed between artificial and natural tree holes. Negative management effects were detectable in both tree-hole systems, despite their abiotic and biotic differences. Our results indicate that forest management has substantial and pervasive effects on tree-hole communities and may alter their structure and functioning. We furthermore conclude that artificial tree-hole analogues represent a useful experimental alternative to test effects of changes in forest management on natural communities. PMID:27187741

Soil Variable Permeability and Water Phase Change Dynamics in a Wastewater Spray Irrigation Agricultural System Located in a Seasonably Cold Climate

NASA Astrophysics Data System (ADS)

Darnault, C. J. G.; Daniel, T. J.; Billy, G.; Hopkins, I.; Guo, L.; Jin, Z.; Gall, H. E.; Lin, H.

2017-12-01

The permeability of the upper meter of soils in frozen conditions, commonly referred to as the active layer, can vary exponentially given the time of year. Variable moisture contents along with temperature, radiation, and slope angle of the soil surface can result in variable depths of frozen soils, which can cause the formation of low permeability ice lenses well into the spring thaw period. The wastewater irrigation site known as the "Living Filter" located in State College, PA has been in continuous operation since 1962. On average 5500 m3/day of wastewater is applied to the site annually, even in the winter months when average temperatures can dip as low as -7 °C during the month of January. The Living Filter is not permitted to discharge to surface water and is intended to recharge the Spring Creek basin that directly underlies the site, therefore runoff from the site is not permitted. We hypothesize that water infiltrates the upper meter of the subsurface during the winter in several different ways such as preferential pathways in the ice layer created by plant stems and weak patches of ice thawed by the warm wastewater. 2D conceptual models of the phase change between ice and water in the soil were created in order to predict soil permeability and its change in temperature. The 2D conceptual models can be correlated between observed soil moisture content and soil temperature data in order to validate the model given spray irrigation and weather patterns. By determining the permeability of the frozen soils, irrigation practices can be adjusted for the winter months so as to reduce the risk of any accidental wastewater runoff. The impact of this study will result in a better understanding of the multiphase dynamics of the active layer and their implication on soil hydrology at the Living Filter and other seasonally frozen sites.

Ticosonde CFH at Costa Rica: A Seasonal Climatology of Tropical UT-LS Water Vapor and Inter-Comparisons with MLS and CALIPSO

NASA Technical Reports Server (NTRS)

Selkirk, Henry B.; Voemel, Holger; Avery, Melody; Rosenlof, Karen; Davis, Sean; Hurst, Dale; Schoeberl, Mark; Diaz, Jorge Andres; Morris, Gary

2014-01-01

Balloon sonde measurements of tropical water vapor using the Cryogenic Frostpoint Hygrometer were initiated in Costa Rica in July 2005 and have continued to the present day. Over the nine years through July 2014, the Ticosonde program has launched 174 CFH payloads, representing the longest-running and most extensive single-site balloon dataset for tropical water vapor. In this presentation we present a seasonal climatology for water vapor and ozone at Costa Rica and examine the frequency of upper tropospheric supersaturation with comparisons to cloud fraction and cloud ice water content observations from the Cloud Aerosol Lidar with Orthogonal Polarization (CALIOP) on the CALIPSO mission. We then make a critical comparison of these data to water vapor measurements from the MLS instrument on board Aura in light of recently published work for other sites. Finally, we examine time series of 2-km altitude averages in the upper troposphere-lower stratosphere at Costa Rica in light of anomalies and trends seen in various large-scale indices of tropical water vapor.

[Spectrum Variance Analysis of Tree Leaves Under the Condition of Different Leaf water Content].

PubMed

Wu, Jian; Chen, Tai-sheng; Pan, Li-xin

2015-07-01

Leaf water content is an important factor affecting tree spectral characteristics. So Exploring the leaf spectral characteristics change rule of the same tree under the condition of different leaf water content and the spectral differences of different tree leaves under the condition of the same leaf water content are not only the keys of hyperspectral vegetation remote sensing information identification but also the theoretical support of research on vegetation spectrum change as the differences in leaf water content. The spectrometer was used to observe six species of tree leaves, and the reflectivity and first order differential spectrum of different leaf water content were obtained. Then, the spectral characteristics of each tree species leaves under the condition of different leaf water content were analyzed, and the spectral differences of different tree species leaves under the condition of the same leaf water content were compared to explore possible bands of the leaf water content identification by hyperspectral remote sensing. Results show that the spectra of each tree leaf have changed a lot with the change of the leaf water content, but the change laws are different. Leaf spectral of different tree species has lager differences in some wavelength range under the condition of same leaf water content, and it provides some possibility for high precision identification of tree species.

Photometric immersion refractometry of bacterial spores.

PubMed Central

Gerhardt, P; Beaman, T C; Corner, T R; Greenamyre, J T; Tisa, L S

1982-01-01

Photometric immersion refractometry was used to determine the average apparent refractive index (n) of five types of dormant Bacillus spores representing a 600-fold range in moist-heat resistance determined as a D100 value. The n of a spore type increased as the molecular size of various immersion solutes decreased. For comparison of the spore types, the n of the entire spore and of the isolated integument was determined by use of bovine serum albumin, which is excluded from permeating into them. The n of the sporoplast (the structures bounded by the outer pericortex membrane) was determined by use of glucose, which was shown to permeate into the spore only as deeply as the pericortex membrane. Among the various spore types, an exponential increase in the heat resistance correlated with the n of the entire spore and of the sporoplast, but not of the isolated perisporoplast integument. Correlation of the n with the solids content of the entire spore provided a method of experimentally obtaining the refractive index increment (dn/dc), which was constant for the various spore types and enables the calculation of solids and water content from an n. Altogether, the results showed that the total water content is distributed unequally within the dormant spore, with less water in the sporoplast than in the perisporoplast integument, and that the sporoplast becomes more refractile and therefore more dehydrated as the heat resistance becomes greater among the various spore types. PMID:6802796

Soil water content evaluation considering time-invariant spatial pattern and space-variant temporal change

NASA Astrophysics Data System (ADS)

Hu, W.; Si, B. C.

2013-10-01

Soil water content (SWC) varies in space and time. The objective of this study was to evaluate soil water content distribution using a statistical model. The model divides spatial SWC series into time-invariant spatial patterns, space-invariant temporal changes, and space- and time-dependent redistribution terms. The redistribution term is responsible for the temporal changes in spatial patterns of SWC. An empirical orthogonal function was used to separate the total variations of redistribution terms into the sum of the product of spatial structures (EOFs) and temporally-varying coefficients (ECs). Model performance was evaluated using SWC data of near-surface (0-0.2 m) and root-zone (0-1.0 m) from a Canadian Prairie landscape. Three significant EOFs were identified for redistribution term for both soil layers. EOF1 dominated the variations of redistribution terms and it resulted in more changes (recharge or discharge) in SWC at wetter locations. Depth to CaCO3 layer and organic carbon were the two most important controlling factors of EOF1, and together, they explained over 80% of the variations in EOF1. Weak correlation existed between either EOF2 or EOF3 and the observed factors. A reasonable prediction of SWC distribution was obtained with this model using cross validation. The model performed better in the root zone than in the near surface, and it outperformed conventional EOF method in case soil moisture deviated from the average conditions.

Temperature, productivity and sediment characteristics as drivers of seasonal and spatial variations of dissolved methane in the near-shore coastal areas (Belgian coastal zone, North Sea)

NASA Astrophysics Data System (ADS)

Borges, Alberto V.; Speeckaert, Gaëlle; Champenois, Willy; Scranton, Mary I.; Gypens, Nathalie

2017-04-01

The open ocean is a modest source of CH4 to the atmosphere compared to other natural and anthropogenic CH4 emissions. Coastal regions are more intense sources of CH4 to the atmosphere than open oceanic waters, in particular estuarine zones. The CH4 emission to the atmosphere from coastal areas is sustained by riverine inputs and methanogenesis in the sediments due to high organic matter (OM) deposition. Additionally, natural gas seeps are sources of CH4 to bottom waters leading to high dissolved CH4 concentrations in bottom waters (from tenths of nmol L-1 up to several µmol L-1). We report a data set of dissolved CH4 concentrations obtained at nine fixed stations in the Belgian coastal zone (Southern North Sea), during one yearly cycle, with a bi-monthly frequency in spring, and a monthly frequency during the rest of the year. This is a coastal area with multiple possible sources of CH4 such as from rivers and gassy sediments, and where intense phytoplankton blooms are dominated by the high dimethylsulfoniopropionate (DMSP) producing micro-algae Phaeocystis globosa, leading to DMSP and dimethylsulfide (DMS) concentrations. Furthermore, the BCZ is a site of important OM sedimentation and accumulation unlike the rest of the North Sea. Spatial variations of dissolved CH4 concentrations were very marked with a minimum yearly average of 9 nmol L-1 in one of the most off-shore stations and maximum yearly average of 139 nmol L-1 at one of the most near-shore stations. The spatial variations of dissolved CH4 concentrations were related to the organic matter (OM) content of sediments, although the highest concentrations seemed to also be related to inputs of CH4 from gassy sediments associated to submerged peat. In the near-shore stations with fine sand or muddy sediments with a high OM content, the seasonal cycle of dissolved CH4 concentration closely followed the seasonal cycle of water temperature, suggesting the control of methanogenesis by temperature in these OM replete sediments. In the off-shore stations with permeable sediments with a low OM content, the seasonal cycle of dissolved CH4 concentration showed a yearly peak following the chlorophyll-a spring peak. This suggests that in these OM poor sediments, methanogenesis depended on the delivery to the sediments of freshly produced OM. In both types of sediments, the seasonal cycle of dissolved CH4 concentrations was unrelated the seasonal cycles of DMS, and DMSP, despite the fact that these quantities were very high during the spring Phaeocystis globosa bloom. This suggests that in this shallow coastal environment CH4 production is overwhelmingly related to benthic processes and unrelated to DMS(P) transformations in the water column as recently suggested in several open ocean regions. The annual average CH4 emission was 41 mmol m-2 yr-1 in the most near-shore stations ( 4 km from the coast) and 10 mmol m-2 yr-1 in the most off-shore stations ( 23 km from the coast), 410-100 times higher than the average value in the open ocean (0.1 mmol m-2 yr-1). The strong control of CH4 concentrations by sediment OM content and by temperature suggests that marine coastal CH4 emissions, in particular shallow coastal areas, should respond in future to eutrophication and warming of climate. This is confirmed by the comparison of CH4 concentrations at five stations obtained in March in years 1990 and 2016, showing a decreasing trend consistent with alleviation of eutrophication in the area.

Geohydrologic reconnaissance of the upper Potomac River basin

USGS Publications Warehouse

Trainer, Frank W.; Watkins, Frank A.

1975-01-01

The upper Potomac River basin, in the central Appalachian region in Pennsylvania, Maryland, Virginia, and West Virginia, is a humid temperate region of diverse fractured rocks. Three geohydrologic terranes, which underlie large parts of the basin, are described in terms of their aquifer characteristics and of the magnitude and duration of their base runoff: (1) fractured rock having a thin regolith, (2) fractured rock having a thick regolith, and (3) carbonate rock. Crystalline rock in the mountainous part of the Blue Ridge province and shale with tight sandstone in the folded Appalachians are covered with thin regolith. Water is stored in and moves through fairly unmodified fractures. Average transmissivity (T) is estimated to be 150 feet squared per day, and average storage coefficient (S), 0.005. Base runoff declines rapidly from its high levels during spring and is poorly sustained during the summer season of high evapotranspiration. The rocks in this geohydrologic terrane are the least effective in the basin for the development of water supplies and as a source of dry-weather streamflow. Crystalline and sedimentary rocks in the Piedmont province and in the lowland part of the Blue Ridge province are covered with thick regolith. Water is stored in and moves through both the regolith and the underlying fractured rock. Estimated average values for aquifer characteristics are T, 200 feet squared per day, and S, 0.01. Base runoff is better sustained in this terrane than in the thin-regolith terrane and on the average .is about twice as great. Carbonate rock, in which fractures have been widened selectively by solution, especially near streams, has estimated average aquifer characteristics of T, 500 feet squared per day, and S, 0.03-0.04. This rock is the most effective in the basin in terms of water supply and base runoff. Where its fractures have not been widened by solution, the carbonate rock is a fractured-rock aquifer much like the noncarbonate rock. At low values the frequency of specific capacities of wells is much the same in all rocks in the basin, but high values of specific capacity are as much as 10 times more frequent in carbonate rock than in noncarbonate rock. Nearly all the large springs and high-capacity wells in the basin are in carbonate rock. Base runoff from the carbonate rock is better sustained during dry weather and on the average is about three times as great as base runoff from fractured rock having a thin regolith. The potential role of these water-bearing terranes in water management probably lies in the local development of large water supplies from the carbonate rock and in the possible manipulation of underground storage for such purposes as providing space for artificial recharge of ground water and providing ground water to be used for the augmentation of low streamflow. The chief water-quality problems in the basin--acidic mine-drainage water in the western part of the basin, local highly mineralized ground water, and the high nitrate content of ground water in some of the densely populated parts of the basin--would probably have little adverse affect on the use of ground water for low-flow augmentation.

Comparing Kaolin and Pinolene to Improve Sustainable Grapevine Production during Drought

PubMed Central

Belfiore, Nicola; Gaiotti, Federica; Lovat, Lorenzo; Sansone, Luigi; Poni, Stefano; Tomasi, Diego

2016-01-01

Viticulture is widely practiced in dry regions, where the grapevine is greatly exposed to water stress. Optimizing plant water use efficiency (WUE) without affecting crop yield, grape and wine quality is crucial to limiting use of water for irrigation and to significantly improving viticulture sustainability. This study examines the use in vineyards of particle film technology (engineered kaolin) and compares it to a film-forming antitranspirant (pinolene), traditionally used to limit leaf water loss, and to an untreated control. The trial was carried out under field conditions over three growing seasons, during which moderate to very severe plant water stress (down to -1.9 MPa) was measured through stem water potential. Leaf stomatal conductance (gs) and photosynthesis rate (An) were measured during the seasons and used to compute intrinsic WUE (WUEi, defined as An/gs ratio). Leaf temperature was also recorded and compared between treatments. Bunch quantity, bunch and berry weight, sugar accumulation, anthocyanin and flavonoid contents were measured. Finally, microvinifications were performed and resultant wines subjected to sensory evaluation.Results showed that the use of kaolin increased grapevine intrinsic WUE (+18% on average as compared to unsprayed vines) without affecting berry and bunch weight and quantity, or sugar level. Anthocyanin content increased (+35%) in kaolin treatment, and the wine was judged more attractive (p-value <0.05) and slightly more appreciated (p-value < 0.1) than control. Pinolene did not increase WUEi, limiting An more than gs; grapes with this treatment contained lower sugar and anthocyanin content than control, and the obtained wine was the least appreciated. This study demonstrates that particle film technology can improve vine WUEi and wine quality at the same time, while traditional antitranspirants were not as effective for these purposes. This positive effect can be used in interaction with other already-demonstrated uses of particle film technology, such as pest control and sunburn reduction, in order to achieve more sustainable vineyard management. PMID:27294368

Characterization of Heat Melt Compactor (HMC) Product Water

NASA Technical Reports Server (NTRS)

Harris, Linden; Wignarajah, Kanapathipi; Alba, Richard Gilbert; Pace, Gregory S.; Fisher, John W.

2013-01-01

The Heat Melt Compactor (HMC) is designed to sterilize and process wastes produced during space missions. Benefits of the HMC include reduction of biohazards to the crew, reduction in volume of wastes that would otherwise require storage, production of radiation shielding tiles, and recovery of water and other resources. Water reuse is critical onboard spacecrafts; it reduces the need for resupply missions and saves valuable storage space. The main sources of water in HMC batches are food, beverages, shampoo, disinfecting wipes, toothpaste, and diapers. Water reclaimed by the HMC was analyzed for concentrations of Na+, NH4+, K+, Mg2+, Ca2+, Cl-­-, NO2-­-, Br-­-, NO3-­-, PO43-­-, SO42-­-, total organic carbon (TOC), total inorganic carbon (TIC), % total solids, and pH. The data are discussed in relation to the current water input characteristics established for the International Space Station Water Processor Assembly system. Batches with higher than average amounts of food produced HMC product water with higher sulfate content, and batches with higher proportions of disinfectant wipes and food yielded HMC product water with higher ammonium concentration. We also compared theoretical chemical composition of HMC product water based on food labels and literature values to experimental results.

Salt tolerance, salt accumulation, and ionic homeostasis in an epidermal bladder-cell-less mutant of the common ice plant Mesembryanthemum crystallinum.

PubMed

Agarie, Sakae; Shimoda, Toshifumi; Shimizu, Yumi; Baumann, Kathleen; Sunagawa, Haruki; Kondo, Ayumu; Ueno, Osamu; Nakahara, Teruhisa; Nose, Akihiro; Cushman, John C

2007-01-01

The aerial surfaces of the common or crystalline ice plant Mesembryanthemum crystallinum L., a halophytic, facultative crassulacean acid metabolism species, are covered with specialized trichome cells called epidermal bladder cells (EBCs). EBCs are thought to serve as a peripheral salinity and/or water storage organ to improve survival under high salinity or water deficit stress conditions. However, the exact contribution of EBCs to salt tolerance in the ice plant remains poorly understood. An M. crystallinum mutant lacking EBCs was isolated from plant collections mutagenized by fast neutron irradiation. Light and electron microscopy revealed that mutant plants lacked EBCs on all surfaces of leaves and stems. Dry weight gain of aerial parts of the mutant was almost half that of wild-type plants after 3 weeks of growth at 400 mM NaCl. The EBC mutant also showed reduced leaf succulence and leaf and stem water contents compared with wild-type plants. Aerial tissues of wild-type plants had approximately 1.5-fold higher Na(+) and Cl(-) content than the mutant grown under 400 mM NaCl for 2 weeks. Na(+) and Cl(-) partitioning into EBCs of wild-type plants resulted in lower concentrations of these ions in photosynthetically active leaf tissues than in leaves of the EBC-less mutant, particularly under conditions of high salt stress. Potassium, nitrate, and phosphate ion content decreased with incorporation of NaCl into tissues in both the wild type and the mutant, but the ratios of Na(+)/K(+) and Cl(-)/NO(3)(-)content were maintained only in the leaf and stem tissues of wild-type plants. The EBC mutant showed significant impairment in plant productivity under salt stress as evaluated by seed pod and seed number and average seed weight. These results clearly show that EBCs contribute to succulence by serving as a water storage reservoir and to salt tolerance by maintaining ion sequestration and homeostasis within photosynthetically active tissues of M. crystallinum.

Volcanic degassing and secondary hydration of volcanic ash and scoria: Implications for paleoaltimetry and paleoclimate studies

NASA Astrophysics Data System (ADS)

Seligman, A. N.; Bindeman, I. N.

2013-12-01

The use of δD of ash as a reliable recorder of δD (and δ18O) values of paleoprecipitation in paleoclimate and paleoaltimetry research still requires experimental verification and testing. It is currently assumed that ash is deposited with a water content of no significance, and that within a few thousand years it becomes sufficiently (up to 4 wt.% H2O) hydrated, although the rate of hydration and whether or not the initial isotopic signature is held, are not well understood. We report analyses of δD and H2O of distal ash from recent eruptions (1980 Mount St. Helens, 1992 Mt. Spurr, and 1974 Volcán de Fuego) that were collected syneruption, in addition to scoria ranging in age from ~50 to 7300 years old from Klyuchevskoy volcano (Kamchatka, Russia), using the TC/EA - MAT 253 continuous flow system. Natural variability of studied samples in wt.% H2O (δD in ‰), with errors represented as 1 s.d. for the average, for recent ash eruptions, range from 0.1 × 0.07 (-102 × 4.7) for Volcán de Fuego up to 0.7 × 0.10 (-104 × 3.5) for Mount St. Helens. Ash from the Mt. Spurr eruption averaged 0.4 × 0.04 (-109 × 4.0), and we plan to also analyze ash from Mt. Pinatubo. The δD values are consistent with a magmatic degassing trend, where the last remaining water is depleted in deuterium, suggesting ash may be deposited with up to 0.7 wt.% H2O as primary magmatic water. Klyuchevskoy scoria (basaltic andesite) shows a general trend of increasing wt.% H2O with increasing age: the youngest samples (<2.0 ka) have ~0.2 wt.% water (-99 to -109 ‰), which is likely primary magmatic, while the older samples (4.7-7.3 ka) generally have a higher water concentration (~0.3-0.5 wt.%); likely local meteoric water based on δD values that are lower than degassed magmatic δD values and higher water content. The samples between ~2.3 and 3.6 ka (0.1 to 0.4 wt.% water) have variable water concentrations due to variations in porosity and therefore surface area between the different scoria. We do not observe a trend between the SiO2 wt.% (51-56 wt.%) and the water content of the samples. The δD values (between -99 × 5.6 and -121 × 1.2 per mil are near equilibrium with local postglacial meteoric waters, when incorporating a -30‰ fractionation, and provide a trend between δD and wt.% H2O, where higher water concentrations are associated with lower δD values. We also report preliminary results of δ18O in extracted water, using experimentally hydrated dacite and rhyolite glass, and a large set of natural ash (ash described above and ash from the Lava Creek Tuff of Yellowstone). These results show water-glass fractionations between -11.5 and -12.7 for experimental glasses and -2.2 to -11.4 for natural ash. We are looking into using δ18Owater in glass as a more robust and retentive proxy of past environmental waters for paleoclimate and paleoaltimetry research.

Geochemistry of placer gold, Koyukuk-Chandalar mining district, Alaska

USGS Publications Warehouse

Mosier, E.L.; Cathrall, J.B.; Antweiler, J.C.; Tripp, R.B.

1989-01-01

The Koyukuk-Chandalar mining district of the Brooks Range mineral belt in north-central Alaska contains numerous placer gold deposits but few known lode gold sources. Gold grains, collected from 46 placer localities and 6 lode gold sites in the district, were analyzed for Ag and 37 trace elements utilizing direct current-arc optical emission spectroscopy. When possible, several measurements were made on each sample and averaged. Gold content was calculated by the summation of the 38 elements determined and subtracting from 100. The objectives of our study were to characterize the deposits by defining the type and number of distinct geochemical characteristics for the Au, to determine relationships of Au in placer deposits to possible lode sources (placer and lode), to identify possible primary sources of placer gold, and to study processes of placer formation. Interpretation of results emphasize that the Au grains are almost invariably ternary (Au-Ag-Cu) alloys. The average Cu content is 0.040% and the average Ag content and fineness [(Au/Au+Ag)??1,000] are 10.5% and 893 parts per thousand, respectively, for the 46 placer localities. Six geochemically distinct types of placer gold can be identified in the Koyukuk-Chandalar mining district based on Ag and Cu values. One type with an average Ag content of 21.2%, an average Cu content of 0.007%, and 786 average fineness is found only in the eastern part of the district. Placer gold grains that have an average Ag content of 6.0%, an average Cu content of 0.276%, and 940 average fineness were found in the western part of the district. Four intermediate types generally occur in order across the district. Variations in the chemistry of the placer gold can be related to variable depositional environments at the primary gold sources. Placer gold geochemistry is important in determining the origin and depositional environment of the primary Au sources and could add to the knowledge of the thermal history of the southcentral Brooks Range. ?? 1989.

Comparison of Cocoa Beans from China, Indonesia and Papua New Guinea

PubMed Central

Gu, Fenglin; Tan, Lehe; Wu, Huasong; Fang, Yiming; Xu, Fei; Chu, Zhong; Wang, Qinghuang

2013-01-01

A survey on five kinds of cocoa beans from new cocoa planting countries was conducted to analyze each kind’s basic quality. The average bean weight and butter content of Hainan cocoa beans were the lowest, at less than 1.1 g, and 39.24% to 43.44%, respectively. Cocoa beans from Indonesia where shown to be about 8.0% and 9.0% higher in average bean weight and butter content, respectively, than that of Papua New Guinea and about 20.0% and 25.0% higher in average bean weight and butter content than Chinese dried beans, respectively. The average total polyphenolic content ranged from 81.22 mg/10 g to 301.01 mg/10 g. The Hainan 2011 sample had the highest total polyphenolic content, followed by the unfermented sample from Indonesia and the Papua New Guinea sample. The polyphenolic levels found in the Hainan 2010 sample were 123.61 mg/10 g and lower than the other three samples, but the Indonesian fermented sample had the lowest total polyphenolic content of 81.22 mg/10 g. The average total amino acid content ranged from 11.58 g/100 g to 18.17 g/100 g. The total amino acid content was the highest in the Indonesian unfermented sample, followed by the Hainan 2011 sample and the Papua New Guinea sample. The levels found in the Hainan 2010 sample were lower; the Indonesian fermented sample had the lowest total amino acid content. PMID:28239108

Chemistry of modern sediments in a hypersaline lagoon, north of Jeddah, Red Sea

NASA Astrophysics Data System (ADS)

El-Sayed, Mahmoud Kh.

1987-10-01

Previous studies of modern peritidal sedimentary environments of the Red Sea, such as hypersaline lagoons and sea-marginal flats, have concentrated on its northern part, particularly in the Gulf of Aqaba. However, little is known about lagoon sediments in other localities along the Red Sea coastal stretches. This paper deals with the chemical characteristics of the sediments of a hypersaline (Ras Hatiba) lagoon, north of Jeddah, Saudi Arabia. The chemistry of hypersaline lagoon sediments is considerably changed following the modifications to the water chemistry by evaporation and precipitation. Ras Hatiba lagoon is a hypersaline elongated water body connected to the Red Sea by a narrow and shallow opening. The total area of the lagoon is c. 30 km 2. Coarse bioclastic sands are dominant in the lagoon and mostly surround lithified calcareous grounds. However, fine silt and clay sediments are present in separate patches. The sediments are rich in carbonates (average 78·5%) and organic carbon (average 7·3%), although they are negatively correlated. Calcium (average 25·1%) and magnesium (average 10·8‰) show a similar distribution pattern in the lagoon sediments. Strontium (average 5·2‰) is positively correlated with calcium. Sodium and potassium are relatively highly concentrated in the sediments (average 118 ppm and 173 ppm, respectively). Magnesium and strontium are of prime importance in the process of mineralization and diagenesis. The sabkha formation surrounding the lagoon is of low carbonate and organic carbon content, compared with the lagoon sediments, whilst it is characterized by high magnesium, sodium and potassium concentrations. Ras Hatiba lagoon sediments and sabkha resemble those of the northern Red Sea in the Gulfs of Aqaba and Suez and the Arabian Gulf in their major sedimentological and chemical characteristics.

Evaluating a sensor setup with respect to near-surface soil water monitoring and determination of in-situ water retention functions

NASA Astrophysics Data System (ADS)

Nolz, R.; Kammerer, G.

2017-06-01

Monitoring water status near the soil surface is a prerequisite for studying hydrological processes at the soil-atmosphere boundary and an option for calibrating remotely sensed water content data, for instance. As the water status of the uppermost soil layer is highly variable in space and time, adequate sensors are required to enable accurate measurements. Therefore, a sensor setup was tested and evaluated in the laboratory and in the field for such a purpose. The arrangement included Hydra Probe and MPS-2 sensors to measure water content and matric potential, respectively. Performance of the MPS-2 was validated in the laboratory by comparing sensor readings with the water potential of a soil, drained to equilibrium for certain pressure steps inside a pressure plate apparatus. Afterwards, six Hydra Probes and twelve MPS-2 sensors were installed in bare soil at a small field plot of about 9 m2. The measurements represented soil water status to a depth of 6 cm from surface. Core samples were repeatedly excavated around the measurement spots. Their water content was determined and the samples were further utilized to analyze water retention characteristics. The tested setup properly reflected changes of near-surface soil water status due to rainfall and evaporation. However, some shortcomings weakened the potential of the chosen arrangement. Site-specific calibration of the Hydra Probes - implemented by relating sensor readings to the water content values of the core samples - confirmed the applicability of the recommended standard calibration parameters for the respective soil texture. The derived user calibration enabled a measurement accuracy of 0.02 cm3·cm-3. Further improvement was restrained by the spatial variability of soil moisture. In this context, spots that were permanently drier or wetter than the others were discovered by means of a temporal stability approach. Performance of MPS-2 sensors was more critical with respect to the objectives. Sensor-to-sensor variation was small at the applied pressure steps of -20, -50, and -100 kPa, but the respective averaged readings were -18, -37, and -57 kPa. At matric potentials of -200 and -300 kPa, the MPS-2 revealed substantial sensor-to-sensor variation. The large deviation of the sensor readings in the field confirmed that the calibration of the MPS-2 should be improved. However, in spite of this inaccuracy, the wide measuring range of the MPS-2 offers suitability to a wide range of potential applications. As an example, water retention functions were calculated from the in-situ data and compared to retention data from the core samples.

Retrieval of Ocean Surface Windspeed and Rainrate from the Hurricane Imaging Radiometer (HIRAD) Brightness Temperature Observations

NASA Technical Reports Server (NTRS)

Biswas, Sayak K.; Jones, Linwood; Roberts, Jason; Ruf, Christopher; Ulhorn, Eric; Miller, Timothy

2012-01-01

The Hurricane Imaging Radiometer (HIRAD) is a new airborne synthetic aperture passive microwave radiometer capable of wide swath imaging of the ocean surface wind speed under heavy precipitation e.g. in tropical cyclones. It uses interferometric signal processing to produce upwelling brightness temperature (Tb) images at its four operating frequencies 4, 5, 6 and 6.6 GHz [1,2]. HIRAD participated in NASA s Genesis and Rapid Intensification Processes (GRIP) mission during 2010 as its first science field campaign. It produced Tb images with 70 km swath width and 3 km resolution from a 20 km altitude. From this, ocean surface wind speed and column averaged atmospheric liquid water content can be retrieved across the swath. The column averaged liquid water then could be related to an average rain rate. The retrieval algorithm (and the HIRAD instrument itself) is a direct descendant of the nadir-only Stepped Frequency Microwave Radiometer that is used operationally by the NOAA Hurricane Research Division to monitor tropical cyclones [3,4]. However, due to HIRAD s slant viewing geometry (compared to nadir viewing SFMR) a major modification is required in the algorithm. Results based on the modified algorithm from the GRIP campaign will be presented in the paper.

[Applicability of agricultural production systems simulator (APSIM) in simulating the production and water use of wheat-maize continuous cropping system in North China Plain].

PubMed

Wang, Lin; Zheng, You-fei; Yu, Qiang; Wang, En-li

2007-11-01

The Agricultural Production Systems Simulator (APSIM) was applied to simulate the 1999-2001 field experimental data and the 2002-2003 water use data at the Yucheng Experiment Station under Chinese Ecosystem Research Network, aimed to verify the applicability of the model to the wheat-summer maize continuous cropping system in North China Plain. The results showed that the average errors of the simulations of leaf area index (LAI), biomass, and soil moisture content in 1999-2000 and 2000-2001 field experiments were 27.61%, 24.59% and 7.68%, and 32.65%, 35.95% and 10.26%, respectively, and those of LAI and biomass on the soils with high and low moisture content in 2002-2003 were 26.65% and 14.52%, and 23.91% and 27.93%, respectively. The simulations of LAI and biomass accorded well with the measured values, with the coefficients of determination being > 0.85 in 1999-2000 and 2002-2003, and 0.78 in 2000-2001, indicating that APSIM had a good applicability in modeling the crop biomass and soil moisture content in the continuous cropping system, but the simulation error of LAI was a little larger.

[Virtual water content of livestock products in China].

PubMed

Wang, Hong-rui; Wang, Jun-hong

2006-04-01

The paper expatiated the virtual water content concept of livestock products and the study meaning on developing virtual water trade of livestock products in China, then summarized the calculation methods on virtual water and virtual water trade of livestock products. Based on these, the paper analyzed and researched every province virtual water content of livestock products in details, then elicited various situation of every province virtual water content of livestock products in China by year. Moreover, it compared virtual water content of livestock products with local water resources. The study indicated the following results: (1) The virtual water content of livestock products is increasing rapidly in China recently, especially poultry eggs and pork. (2) The distribution of virtual water content of livestock products is not balanced, mainly lies in North China, East China and so on; (3) The increasing production of livestock in Beijing City, Tianjin City, Hebei, Nei Monggol, Liaononing, Jilin, Shandong, Henan and Ningxia province and autonom ous region will bring pressure to local water shortage.

Does water content or flow rate control colloid transport in unsaturated porous media?

PubMed

Knappenberger, Thorsten; Flury, Markus; Mattson, Earl D; Harsh, James B

2014-04-01

Mobile colloids can play an important role in contaminant transport in soils: many contaminants exist in colloidal form, and colloids can facilitate transport of otherwise immobile contaminants. In unsaturated soils, colloid transport is, among other factors, affected by water content and flow rate. Our objective was to determine whether water content or flow rate is more important for colloid transport. We passed negatively charged polystyrene colloids (220 nm diameter) through unsaturated sand-filled columns under steady-state flow at different water contents (effective water saturations Se ranging from 0.1 to 1.0, with Se = (θ - θr)/(θs - θr)) and flow rates (pore water velocities v of 5 and 10 cm/min). Water content was the dominant factor in our experiments. Colloid transport decreased with decreasing water content, and below a critical water content (Se < 0.1), colloid transport was inhibited, and colloids were strained in water films. Pendular ring and water film thickness calculations indicated that colloids can move only when pendular rings are interconnected. The flow rate affected retention of colloids in the secondary energy minimum, with less colloids being trapped when the flow rate increased. These results confirm the importance of both water content and flow rate for colloid transport in unsaturated porous media and highlight the dominant role of water content.

Coordinating management of water, salinity and trace elements for cotton under mulched drip irrigation with brackish water

NASA Astrophysics Data System (ADS)

Jin, M.; Chen, W.; Liang, X.

2016-12-01

Rational irrigation with brackish water can increase crop production, but irrational use may cause soil salinization. In order to understand the relationships among water, salt, and nutrient (including trace elements) and find rational schemes to manage water, salinity and nutrient in cotton fields, field and pot experiments were conducted in an arid area of southern Xinjiang, northwest China. Field experiments were performed from 2008 to 2015, and involved mulched drip irrigation during the growing season and flood irrigation afterwards. The average cotton yield of seven years varied between 3,575 and 5,095 kg/ha, and the irrigation water productivity between 0.91 and 1.16 kg/m3. With the progress of brackish water irrigation, Cu, Fe, Mn, and Na showed strong aggregation in topsoil at the narrow row, whereas the contents of Ca and K decreased in the order of inter-mulch gap, the wide inter row, and the narrow row. The contents of Cu, Fe, Mn, Ca and K in root soil reduced with cotton growth, whereas Na increased. Although mulched drip irrigation during the growing season resulted in an increase in salinity in the root zone, flood irrigation after harvesting leached the accumulated salts below background levels. Based on experiments a scheme for coordinating management of soil water, salt, and nutrient is proposed, that is, under the planting pattern of one mulch, two drip lines and four rows, the alternative irrigation plus a flood irrigation after harvesting or before seeding was the ideal scheme. Numerical simulations using solute transport model coupled with the root solute uptake based on the experiments and extended by another 20 years, suggest that the mulched drip irrigation using alternatively fresh and brackish water during the growing season and flood irrigation with fresh water after harvesting, is a sustainable irrigation practice that should not lead to soil salinization. Pot experiments with trace elements and different saline water showed significantly antagonistic effects on cotton growth and yield between NaCl and Mn or Zn or B. Zn concentration in irrigation water under salinity stress affected the uptake of nutrient elements and caused the different contents of nutrient elements in cotton, and influenced cotton growth and yields.

Implications of Topographically Induced Variations in Solar Radiation for Water Balance, Vegetation and Soil Development.

NASA Astrophysics Data System (ADS)

Seyfried, M. S.; Flerchinger, G. N.; Link, T. E.; McNamara, J. P.

2016-12-01

Vegetation cover and stature in semiarid regions are highly sensitive to variations in evaporative demand and precipitation. Where the terrain is complex, this may result in a spatial mosaic of vegetation cover related to topographically induced variations in solar radiation and hence evaporative demand. The associated energy and water fluxes and carbon stocks probably do not scale linearly, but are potentially predictable. Johnston Draw, a small, semiarid, granitic catchment in the Reynolds Creek Experimental Watershed in Idaho, is dominated by steep north and south-facing slopes. Vegetation on North-facing slopes is more complete. We made spatially extensive, periodic measurements of soil temperature (Ts) soil water content (Ws) to establish the spatial variability of those parameters. In addition, we monitored Ts and Ws in profiles to bedrock, snow depth and meteorological parameters at three paired, north- and south-facing slope locations. These data were compared to simulations of water and energy flux calculated using the Simultaneous Heat and Water (SHAW) model. We found dramatic differences in Ts, with the annual average soil temperature about 5 C warmer on south-facing slopes. Differences varied seasonally, with the biggest differences in the summer, exactly out of phase with the solar radiation differences. Each year soils dried to consistent, low values, but the north-facing soils retained water about one month longer, on average, owing mostly to the greater depth, and hence available water, on those soils. Modeling results indicate that water is retained longer in north-facing soils and the differences in Ts are due to differences in soil cover, primarily from the greater density of vegetative cover. These differences appear to have evolved over time as the result of feedbacks between atmospheric forcings and vegetation response, which promote greater carbon accumulations and deeper soil formation.

Water for the growing needs of Harrison County, Mississippi

USGS Publications Warehouse

Newcome, Roy; Shattles, Donald E.; Humphreys, Carney P.

1968-01-01

The potential for water-supply development in Harrison County is almost unlimited. During an average year, more than 350 billion gallons of water flow into the Gulf of Mexico from the streams of the county. With storage reservoirs these streams have a potential sustained supply of hundreds of millions of. gallons per day. Recreation uses and flood-control benefits could also be considered in reservoir design. Upstream from the zones of salt-water penetration, mineral content is low and fairly constant. Water in the streams generally has high color and low pH ; treatment would be required for most municipal and industrial uses. Impoundment in reservoirs normally would have little effect on the quality of the surface water. However, impoundment would trap most of the suspended-sediment load of the streams. Flooding along the major streams of Harrison County is a minor hazard at present (1966), but with further industrial development and urbanization, flooding in these now rural areas could become serious. Intense rainfall from thunderstorms and hurricanes causes serious local flooding in the populous areas near the coast. Tidal flooding, a result of tropical storms, is an ever-present hazard in areas near the coast. The ground-water reservoir, which at present provides all fresh-water supplies, is capable of supporting many times the 25 million gallons per day withdrawal through existing wells. Fresh water occurs to depths as great as 2,500 feet in sand aquifers of Pliocene and Miocene age. Many of the aquifers have high transmissibility; most of those tested have transmissibility in the range, of 50,000-100,000 gallons per day per foot. Although few wells produce more than 1,000 gallons per minute, several of the aquifers can yield two to three times that amount to wells designed for the higher production. Artesian water levels along the coast are declining at a rate of 1 foot per year on the average; however, water levels are still above or only slightly below the land surface in most places, and considerable additional drawdown is economically available. Newly discovered deep aquifers (1,700-2,500 ft) have water levels 100 feet above the surface and probably will provide flow yields of 2,000 gallons per minute or more. The temperature of this deep water is nearly 100?F. Nearly all the ground water is of good quality and requires little or no treatment for most uses. It is soft, and total mineral content is usually less than 250 parts per million. Color is seldom a problem, although it may have to be considered in the undeveloped deep aquifers. The pH ordinarily is greater than 7.0, but it is slightly less than 7.0 in most places in the shallow aquifers.

Carbon, nitrogen, and phosphorus stoichiometry of plankton and the nutrient regime in Cabo Frio Bay, SE Brazil.

PubMed

Kütter, Vinicius T; Wallner-Kersanach, Monica; Sella, Silvia M; Albuquerque, Ana Luiza S; Knoppers, Bastiaan A; Silva-Filho, Emmanoel V

2014-01-01

This long-term study, performed during the years 2003-2005 and 2008-2009, investigated the carbon (C), nitrogen (N), and phosphorus (P) contents of the phyto- and zooplankton communities and the nutrient regime of Cabo Frio Bay, SE Brazil. The information intends to serve as baseline of the plankton C, N, and P stoichiometry for the calibration of biogeochemical and ecological models in support to future findings related to the local and regional phenomena of climatic change. Cabo Frio Bay is a small semienclosed system set adjacent to a region subject to sporadic coastal upwelling. Zooplankton exhibited average annual C, N, and P contents of 11.6 ± 6.9 %, 2.8 ± 1.8 %, and 0.18 ± 0.08 %, and phytoplankton (>20 μm) 6.8 ± 6.0 %, 1.6 ± 1.5 %, and 0.09 ± 0.08 %, respectively. The C/N/P ratios correspond to the lowest already found to date for a marine environment. The low C contents must have been brought about by a predominance of gelatinous zooplankton, like Doliolids/ Salps and also Pteropods. Average annual nutrient concentrations in the water were 0.21 ± 0.1 μM for phosphate, 0.08 ± 0.1 μM for nitrite, 0.74 ± 1.6 μM for nitrate, and 1.27 ± 1.1 μM for ammonium. N/P ratios were around 8:1 during the first study period and 12:1 during the second. The plankton C/N/P and N/P nutrient ratios and elemental concentrations suggest that the system was oligotrophic and nitrogen limited. The sporadic intrusions of upwelling waters during the first study period had no marked effect upon the systems metabolism, likely due to dilution effects and the short residence times of water of the bay.

Risk assessment of human exposure to Ra-226 in oil produced water from the Bakken Shale.

PubMed

Torres, Luisa; Yadav, Om Prakash; Khan, Eakalak

2018-06-01

Unconventional oil production in North Dakota (ND) and other states in the United States uses large amounts of water for hydraulic fracturing to stimulate oil flow. Most of the water used returns to the surface as produced water (PW) containing different constituents. Some of these contents are total dissolved solids and radionuclides. The most predominant radionuclide in PW is radium-226 (Ra-226) of which level depends on several factors including the content of certain cations. A multivariate regression model was developed to predict Ra-226 in PW from the Bakken Shale based on the levels of barium, strontium, and calcium. The simulated Ra-226 activity concentration in PW was 535 pCi/L supporting extremely limited actual data based on three PW samples from the Bakken (527, 816, and 1210 pCi/L). The simulated activity concentration was further analyzed by studying its impact in the event of a PW spill reaching a surface water body that provides drinking water, irrigation water for crops, and recreational fishing. Using food transfer factors found in the literature, the final annual effective dose rate for an adult in ND was estimated. The global average annual effective dose rate via food and drinking water is 0.30 mSv, while the predicted dose rate in this study was 0.49 mSv indicating that there is potential risk to human health in ND due to Ra-226 in PW spills. This predicted dose rate is considered the best case scenario as it is based on the simulated Ra-226 activity concentration in PW of 535 pCi/L which is close to the low end actual activity concentration of 527 pCi/L. Copyright © 2018 Elsevier B.V. All rights reserved.

Evaluation of the cosmic-ray neutron method for measuring integral soil moisture dynamics of a forested head water catchment

NASA Astrophysics Data System (ADS)

Bogena, H. R.; Metzen, D.; Baatz, R.; Hendricks Franssen, H.; Huisman, J. A.; Montzka, C.; Vereecken, H.

2011-12-01

Measurements of low-energy secondary neutron intensity above the soil surface by cosmic-ray soil moisture probes (CRP) can be used to estimate soil moisture content. CRPs utilise the fact that high-energy neutrons initiated by cosmic rays are moderated (slowed to lower energies) most effectively by collisions with hydrogen atoms contained in water molecules in the soil. The conversion of neutron intensity to soil moisture content can potentially be complicated because neutrons are also moderated by aboveground water storage (e.g. vegetation water content, canopy storage of interception). Recently, it was demonstrated experimentally that soil moisture content derived from CRP measurements agrees well with average moisture content from gravimetric soil samples taken within the footprint of the cosmic ray probe, which is proposed to be up to several hundred meters in size [1]. However, the exact extension and shape of the CRP integration footprint is still an open question and it is also unclear how CRP measurements are affected by the soil moisture distribution within the footprint both in horizontal and vertical directions. In this paper, we will take advantage of an extensive wireless soil moisture sensor network covering most of the estimated footprint of the CRP. The network consists of 150 nodes and 900 soil moisture sensors which were installed in the small forested Wüstebach catchment (~27 ha) in the framework of the Transregio32 and the Helmholtz initiative TERENO (Terrestrial Environmental Observatories) [2]. This unique soil moisture data set provides a consistent picture of the hydrological status of the catchment in a high spatial and temporal resolution and thus the opportunity to evaluate the CRP measurements in a rigorous way. We will present first results of the comparison with a specific focus on the sensitivity of the CRP measurements to soil moisture variation in both the horizontal and vertical direction. Furthermore, the influence of forest biomass and shallow groundwater table fluctuations on the attenuation of cosmic-ray neutrons will be considered.

Reconstructing Heat Fluxes Over Lake Erie During the Lake Effect Snow Event of November 2014

NASA Astrophysics Data System (ADS)

Fitzpatrick, L.; Fujisaki-Manome, A.; Gronewold, A.; Anderson, E. J.; Spence, C.; Chen, J.; Shao, C.; Posselt, D. J.; Wright, D. M.; Lofgren, B. M.; Schwab, D. J.

2017-12-01

The extreme North American winter storm of November 2014 triggered a record lake effect snowfall (LES) event in southwest New York. This study examined the evaporation from Lake Erie during the record lake effect snowfall event, November 17th-20th, 2014, by reconstructing heat fluxes and evaporation rates over Lake Erie using the unstructured grid, Finite-Volume Community Ocean Model (FVCOM). Nine different model runs were conducted using combinations of three different flux algorithms: the Met Flux Algorithm (COARE), a method routinely used at NOAA's Great Lakes Environmental Research Laboratory (SOLAR), and the Los Alamos Sea Ice Model (CICE); and three different meteorological forcings: the Climate Forecast System version 2 Operational Analysis (CFSv2), Interpolated observations (Interp), and the High Resolution Rapid Refresh (HRRR). A few non-FVCOM model outputs were also included in the evaporation analysis from an atmospheric reanalysis (CFSv2) and the large lake thermodynamic model (LLTM). Model-simulated water temperature and meteorological forcing data (wind direction and air temperature) were validated with buoy data at three locations in Lake Erie. The simulated sensible and latent heat fluxes were validated with the eddy covariance measurements at two offshore sites; Long Point Lighthouse in north central Lake Erie and Toledo water crib intake in western Lake Erie. The evaluation showed a significant increase in heat fluxes over three days, with the peak on the 18th of November. Snow water equivalent data from the National Snow Analyses at the National Operational Hydrologic Remote Sensing Center showed a spike in water content on the 20th of November, two days after the peak heat fluxes. The ensemble runs presented a variation in spatial pattern of evaporation, lake-wide average evaporation, and resulting cooling of the lake. Overall, the evaporation tended to be larger in deep water than shallow water near the shore. The lake-wide average evaporations from CFSv2 and LLTM are significantly smaller than those from FVCOM. The variation among the nine FVCOM runs resulted in the 3D mean water temperature cooling in a range from 3 degrees C to 5 degrees C (6-10 EJ loss in heat content), implication for impacts on preconditioning for the upcoming ice season.

Preparation of Pure and Stable Chitosan Nanofibers by Electrospinning in the Presence of Poly(ethylene oxide)

PubMed Central

Mengistu Lemma, Solomon; Bossard, Frédéric; Rinaudo, Marguerite

2016-01-01

Electrospinning was employed to obtain chitosan nanofibers from blends of chitosans (CS) and poly(ethylene oxide) (PEO). Blends of chitosan (MW (weight-average molecular weight) = 102 kg/mol) and PEO (M (molecular weight) = 1000 kg/mol) were selected to optimize the electrospinning process parameters. The PEO powder was solubilized into chitosan solution at different weight ratios in 0.5 M acetic acid. The physicochemical changes of the nanofibers were determined by scanning electron microscopy (SEM), swelling capacity, and nuclear magnetic resonance (NMR) spectroscopy. For stabilization, the produced nanofibers were neutralized with K2CO3 in water or 70% ethanol/30% water as solvent. Subsequently, repeated washings with pure water were performed to extract PEO, potassium acetate and carbonate salts formed in the course of chitosan nanofiber purification. The increase of PEO content in the blend from 20 to 40 w% exhibited bead-free fibers with average diameters 85 ± 19 and 147 ± 28 nm, respectively. Their NMR analysis proved that PEO and the salts were nearly completely removed from the nanostructure of chitosan, demonstrating that the adopted strategy is successful for producing pure chitosan nanofibers. In addition, the nanofibers obtained after neutralization in ethanol-aqueous solution has better structural stability, at least for six months in aqueous solutions (phosphate buffer (PBS) or water). PMID:27792192

Deforestation effects on soil quality and water retention curve parameters in eastern Ardabil, Iran

NASA Astrophysics Data System (ADS)

Asghari, Sh.; Ahmadnejad, S.; Keivan Behjou, F.

2016-03-01

The land use change from natural to managed ecosystems causes serious soil degradation. The main objective of this research was to assess deforestation effects on soil physical quality attributes and soil water retention curve (SWRC) parameters in the Fandoghlou region of Ardabil province, Iran. Totally 36 surface and subsurface soil samples were taken and soil water contents measured at 13 suctions. Alfa (α) and n parameters in van Genuchten (1980) model were estimated by fitting SWRC data by using RETC software. The slope of SWRC at inflection point (SP) was calculated by Dexter (2004) equation. The results indicated that with changing land use from forest (F) to range land (R) and cultivated land (C), and also with increasing soil depth from 0-25 to 75-100 cm in each land use, organic carbon, micropores, saturated and available water contents decreased and macropores and bulk density increased significantly ( P < 0.05). The position of SWRC shape in F was higher than R and C lands at all soil depths. Changing F to R and C lands and also increasing soil depth in each land use significantly ( P < 0.05) increased α and decreased n and SP. The average values of SP were obtained 0.093, 0.051 and 0.031 for F, R and C, respectively. As a result, deforestation reduced soil physical quality by affecting SWRC parameters.

Determination of dew point conditions for CO2 with impurities using microfluidics.

PubMed

Song, Wen; Fadaei, Hossein; Sinton, David

2014-03-18

Impurities can greatly modify the phase behavior of carbon dioxide (CO2), with significant implications on the safety and cost of transport in pipelines. In this paper we demonstrate a microfluidic approach to measure the dew point of such mixtures, specifically the point at which water in supercritical CO2 mixtures condenses to a liquid state. The method enables direct visualization of dew formation (∼ 1-2 μm diameter droplets) at industrially relevant concentrations, pressures, and temperatures. Dew point measurements for the well-studied case of pure CO2-water agreed well with previous theoretical and experimental data over the range of pressure (up to 13.17 MPa), temperature (up to 50 °C), and water content (down to 0.00229 mol fraction) studied. The microfluidic approach showed a nearly 3-fold reduction in error as compared to previous methods. When applied to a mixture with nitrogen (2.5%) and oxygen (5.8%) impurities--typical of flue gas from natural gas oxy-fuel combustion processes--the measured dew point pressure increased on average 17.55 ± 5.4%, indicating a more stringent minimum pressure for pipeline transport. In addition to increased precision, the microfluidic method offers a direct measurement of dew formation, requires very small volumes (∼ 10 μL), and is applicable to ultralow water contents (<0.005 mol fractions), circumventing the limits of previous methods.

[Pollution by heavy metals in the petrochemical sewage waters of the sea area of Daya Bay and assessment on potential ecological risks].

PubMed

Xu, Shan-Nan; Li, Chun-Hou; Xu, Jiao-Jiao; Xiao, Ya-Yuan; Lin, Lin; Huang, Xiao-Ping

2014-06-01

This study aimed to gain a clear understanding on the status of pollution by heavy metals in the petrochemical sewage and the potential ecological risk caused by heavy metal pollution in the sea area of Daya Bay. The contents and spatial distributions of heavy metals including Zn, Pb, Cu, Cd, Cr, As and Hg in seawater, sediment and fishes collected from Daya Bay were analyzed. The comprehensive pollution index (CPI) and ecological risk indexes (ERIs) were used to evaluate the contaminated severity and potential ecological risks of heavy metals in seawater and sediment. The results showed that the contents of these heavy metals, except for those of Zn and Pb, in several stations set in Daya Bay from 2011 to 2012 were relatively low, which were lower than the quality standard of class I according to the China National Standard Criteria for Seawater Quality, suggesting that the seawater in Daya Bay has not been polluted yet by these heavy metals. The average CPI of heavy metals in seawater during flooding season (0.72) was higher than that during dry season (0.38) whereas the average CPI of heavy metals in sediment during dry season (7.77) was higher than that during flooding season (5.70). Hg was found to be the primary contaminating heavy metal in sediment during dry season, which was followed by As and Zn whereas during flooding season, Hg was the primary contaminating metal in sediment, followed by Zn and Cu. The contents of these 7 heavy metals in fishes collected from the surveyed areas were lower than those of the standard requirements. A correlation analysis indicated that there were significant differences in the correlations between the midst of the heavy metals in sea water and the different periods. The ERIs of heavy metals in sediment during dry season (129.20) was higher than that during flooding season (102.86), and 25% of the sampling sites among all stations were under the risk of high-level alarm. The potential ERIs of heavy metals in sediment in offshore waters were higher than those of inshore waters, and were higher in the bay-mouth than in the bay-head. However, the distributions of potential ERIs showed reversed trend during dry season. The comprehensive assessment results showed that Hg was the primary heavy metal with a high ecological risk whereas the potential ERIs for the other six heavy metals in the petrochemical sewage waters in Daya Bay were relatively low.

Determination of bulk properties of tropical cloud clusters from large scale heat and moisture budgets, appendix B

NASA Technical Reports Server (NTRS)

Yanai, M.; Esbensen, S.; Chu, J.

1972-01-01

The bulk properties of tropical cloud clusters, as the vertical mass flux, the excess temperature, and moisture and the liquid water content of the clouds, are determined from a combination of the observed large-scale heat and moisture budgets over an area covering the cloud cluster, and a model of a cumulus ensemble which exchanges mass, heat, vapor and liquid water with the environment through entrainment and detrainment. The method also provides an understanding of how the environmental air is heated and moistened by the cumulus convection. An estimate of the average cloud cluster properties and the heat and moisture balance of the environment, obtained from 1956 Marshall Islands data, is presented.

Partitioning and bioavailability of mercury in an experimentally acidified Wisconsin lake

USGS Publications Warehouse

Wiener, James G.; Fitzgerald, William F.; Watras, Carl J.; Rada, Ronald G.

1990-01-01

We studied the partitioning of mercury (Hg) among air, water, sediments and fish at Little Rock Lake, a clear water seepage lake in north-central Wisconsin. The lake was divided with a sea curtain into two basins, one acidified with sulfuric acid to pH 5.6 for two years and the other an untreated reference site (mean pH 6.1), to document the effects of acidification. Trace-metal-free protocols were used to measure Hg at the picomolar level in air and water. Total gaseous Hg in air samples averaged 2.0 ng/m3. Total Hg in unfiltered water samples collected in 1986 after the fall overturn averaged about 1 ng/L in the acidified and reference basins. Mercury in surficial sediments was strongly correlated with volatile matter content and ranged from 10 to about 170 ng/g (dry weight) in both basins. Total Hg concentrations in whole, calendar age-1 yellow perch (Perca flavescens), sampled after one year of residence in the lake, averaged 114 ng/g (fresh weight) in the reference basin and 135 ng/g in the acidified basin – a highly significant (p < 0.01) difference. The mean whole-body burden (quantity) of Hg in age-1 perch did not differ between basins after the first year, but was significantly greater in the treatment basin than in the reference basin after the second year of acidification. Differences between the two basins in the bioaccumulation of Hg were attributed to internal (within-lake) processes that influence the bioavailability of the metal. An initial Hg budget for the treatment basin of Little Rock Lake showed that atmospheric deposition and sedimentary remobilization of Hg are potentially important processes influencing its biogeochemical cycling and uptake by fish.

Spatial Variability of Soil Water and Soil Organic Carbon Contents Under Different Degradation Degrees of Alpine Meadow Soil over the Qinghai-Tibetan Plateau

NASA Astrophysics Data System (ADS)

Zeng, C.; Zhang, F.

2014-12-01

Alpine meadow is one of widespread vegetation types of the Qinghai-Tibetan Plateau. However, alpine meadow ecosystem is undergoing degradation in recent years. The degradation of alpine meadow can changes soil physical and chemical properties as well as it's spatial variability. However, little research has been done that address the spatial patterns of soil properties under different degradation degrees of alpine meadow of the Qinghai-Tibetan Plateau although these changes were important to water and heat study and modelling of land surface. 296 soil surface (0-10 cm) samples were collected using grid sampling design from three different degraded alpine meadow regions (1 km2). Then soil water content (SWC) and organic carbon content (OCC) were measured. Classical statistical and geostatistical methods were employed to study the spatial heterogeneities of SWC and OCC under different degradation degrees (Non-degraded ND, moderately degraded MD, extremely degraded ED) of alpine meadow. Results show that both SWC and OCC of alpine meadow were normally distributed with the exception of SWC under ED. On average, both SWC and OCC of alpine meadow decreased in the order that ND > MD > ED. For nugget ratios, SWC and OCC of alpine meadow showed increasing spatial dependence tendency from ND to ED. For the range of spatial variation, both SWC and OCC of alpine meadow showed increasing tendency in distance with the increasing degree of degradation. In all, the degradation of alpine meadow has significant impact on spatial heterogeneities of SWC and OCC of alpine meadow. With increasing of alpine meadow degradation, soil water condition and nutrient condition become worse, and their distributions in spatial become unevenly.

Molecular characterization and comparison of shale oils generated by different pyrolysis methods using FT-ICR mass spectrometry

USGS Publications Warehouse

Jin, J.M.; Kim, S.; Birdwell, J.E.

2011-01-01

Fourier transform ion cyclotron resonance mass spectrometry (FT ICR-MS) was applied in the analysis of shale oils generated using two different pyrolysis systems under laboratory conditions meant to simulate surface and in situ oil shale retorting. Significant variations were observed in the shale oils, particularly the degree of conjugation of the constituent molecules. Comparison of FT ICR-MS results to standard oil characterization methods (API gravity, SARA fractionation, gas chromatography-flame ionization detection) indicated correspondence between the average Double Bond Equivalence (DBE) and asphaltene content. The results show that, based on the average DBE values and DBE distributions of the shale oils examined, highly conjugated species are enriched in samples produced under low pressure, high temperature conditions and in the presence of water.

Loss of halogens from crystallized and glassy silicic volcanic rocks

USGS Publications Warehouse

Noble, D.C.; Smith, V.C.; Peck, L.C.

1967-01-01

One hundred and sixty-four F and Cl analyses of silicic welded tuffs and lavas and glass separates are presented. Comparison of the F and Cl contents of crystallized rocks with those of nonhydrated glass and hydrated glassy rocks from the same rock units shows that most of the halogens originally present were lost on crystallization. An average of about half of the F and four-fifths of the Cl originally present was lost. Analyses of hydrated natural glasses and of glassy rocks indicate that in some cases significant amounts of halogens may be removed from or added to hydrated glass through prolonged contact with ground water. The data show that the original halogen contents of the groundmass of a silicic volcanic rock can be reliably determined only from nonhydrated glass. ?? 1967.

Adapting FAO-56 Spreadsheet Program to estimate olive orchard transpiration fluxes under soil water stress condition

NASA Astrophysics Data System (ADS)

Rallo, G.; Provenzano, G.; Manzano-Juárez, J.

2012-04-01

In the Mediterranean environment, where the period of crops growth does not coincide with the rainy season, the crop is subject to water stress periods that may be amplified with improper irrigation management. Agro-hydrological models can be considered an economic and simple tool to optimize irrigation water use, mainly when water represents a limiting factor for crop production. In the last two decades, agro-hydrological physically based models have been developed to simulate mass and energy exchange processes in the soil-plant-atmosphere system (Feddes et al., 1978; Bastiaanssen et al., 2007). Unfortunately these models, although very reliable, as a consequence of the high number of required variables and the complex computational analysis, cannot often be used. Therefore, simplified agro-hydrological models may represent an useful and simple tool for practical irrigation scheduling. The main objective of the work is to assess, for an olive orchard, the suitability of FAO-56 spreadsheet agro-hydrological model to estimate a long time series of field transpiration, soil water content and crop water stress dynamic. A modification of the spreadsheet is suggested in order to adapt the simulations to a crop tolerant to water stress. In particular, by implementing a new crop water stress function, actual transpiration fluxes and an ecophysiological stress indicator, i. e. the relative transpiration, are computed in order to evaluate a plant-based irrigation scheduling parameter. Validation of the proposed amendment is carried out by means of measured sap fluxes, measured on different plants and up-scaled to plot level. Spatial and temporal variability of soil water contents in the plot was measured, at several depths, using the Diviner 2000 capacitance probe (Sentek Environmental Technologies, 2000) and TDR-100 (Campbell scientific, Inc.) system. The detailed measurements of soil water content, allowed to explore the high spatial variability of soil water content due to the combined effect of the punctual irrigation and the non-uniform root density distribution. A further validation of the plant-based irrigation-timing indicator will be carried out by considering another ecophysiological stress variable like the predawn leaf water potential. Accuracy of the model output was assessed using the Mean Absolute Difference, the Root Mean Square Difference and the efficiency index of Nash and Sutcliffe. Experimental data, recorded during three years of field observation, allowed, with a great level of detail, to investigate on the dynamic of water fluxes from the soil to atmosphere as well as to validate the proposed amendment of the FAO-56 spreadsheet. The modified model simulated with a satisfactory approximation the measured values of average soil water content in the root zone, with error of estimation equal to about 2.0%. These differences can be considered acceptable for practical applications taking into account the intrinsic variability of the data especially in the soil moisture point measurements. An error less than 1 mm was calculated in the daily transpiration estimation. A good performance was observed in the estimation of the cumulate transpiration fluxes.

[Chemical forms and ecological effect of soil Mn in liver cancer's high incidence area in Zhu-jiang River Delta, China].

PubMed

Dou, Lei; Zhou, Yong-Zhang; Li, Yong; Ma, Jin; An, Yan-Fei; Du, Hai-Yan; Li, Zhan-Qiang

2008-06-01

The samples of surface soil, deep soil, and vegetables were collected from the liver cancer's high- and low incidence areas in Zhujiang River Delta to study the relationships between soil Mn forms and vegetables' Mn enrichment. The results showed that the soil Mn in study area was mainly derived from parent materials, and rarely come from human activities. The average soil Mn content in liver cancer's high incidence area was 577.65 mg x kg(-1), being significantly lower than that of liver cancer's low incidence area (718.04 mg x kg(-1)) and whole country (710 mg x kg(-1)). The Mn forms in high incidence area were mainly of residual Mn and Fe-Mn oxide, and less of water soluble Mn and exchangeable Mn, with the sum of the latter two's distribution coefficients being not higher than 4%. In low incidence area, the distribution pattern of soil Mn forms was similar to that in high incidence area, but the absolute contents of the Mn forms were significantly higher. Soil total Mn and soil pH had significant effects on soil Mn forms. There existed significant positive correlations between soil total Mn and the Mn forms of Fe-Mn bound, humic acid bound, carbonate bound, and residual, and negative correlations between soil pH and soil water soluble and organic bound Mn forms. Among the test five kinds of vegetables, Youmai lettuce and Chinese cabbage in liver cancer' s high incidence area had a significantly lower Mn content than in low incidence area, while the other three had less difference. The Mn enrichment in test vegetables was positively correlated with to the content of soil available Mn (sum of water soluble Mn and exchangeable Mn), but had no correlations with the contents of soil total Mn and other Mn forms.

Biomaterial compounds and bioactivity of horseshoe crab Carsinoscorpius rotundicauda biomass harvested from the Madura Strait

NASA Astrophysics Data System (ADS)

Asih, Eka Nurrahema Ning; Kawaroe, Mujizat; Bengen, Dietriech G.

2018-03-01

Carsinoscorpius rotundicauda or horseshoe crab biomass has great potential in pharmaceutical aspects, one of them as an antibacterial substance. Information related to the benefits of Carsinoscorpius rotundicauda biomass such as meat and blood is essential because in fact, this species is considered a pest by fishermen, a low market value and has no legal protection in Indonesia. The purpose of this study was to determine the content of biomaterial compounds of meat and bioactivity of Carsinoscorpius rotundicauda plasma on bacterial inhibition from three different stations harvested from the waters in Madura Strait. The observation of the utilization of the potential from horseshoe crab biomass ie meat and plasma was performed by measuring the content of biomaterial compound in horseshoe crab meat by HPLC method and zone of inhibition test for gram-positive and gram-negative bacteria in horseshoe crab plasma. Analysis of the relationship between the two parameters used the Principal Component Analysis. The highest content of biomaterial compounds of monoterpenoid and zoosterol is found in horseshoe crab from Bangkalan waters, namely monoterpenoid (18.33 ppm) and zoosterol (22.67 ppm), while the smallest compound content obtained in horseshoe crab from Probolinggo waters, namely monoterpenoid (13.67) ppm and zoosterol (17.33 ppm). The bioactivity of Dark Blue Plasma (BDP) and Light Blue Plasma (LBP) samples of horseshoe crab obtained around the Madura Strait has the ability to inhibit gram-positive bacteria higher than gram-negative bacteria. The total average of DBP plasma inhibitory power on Staphylococcus aureus was 10.00 mm and 10.07 mm on Bacillus, while that in LBP sample, Staphylococcus aureus was 9.11 mm and Bacillus was 9.67 mm. The high biomaterial compound content of horseshoe crab is in line with the ability of horseshoe crab plasma to inhibit Bacillus and Staphylococcus aureus.

[Effects of fertilizing regime and planting age on soil calcium decline in Luochuan apple orchards].

PubMed

Li, Peng; Li, Chun Yue; Wang, Yi Quan; Jiao, Cai Qiang

2017-05-18

This study was conducted to assess the effects of fertilizing regime and orchard planting age on soil calcium contents and stocks in the apple orchards on the Loess Plateau. The apple orchards in Luochuan County, one of the best regions for apple plantation in the world, were selec-ted in this study. The contents of calcium carbonate,water-soluble calcium and exchangeable cal-cium at 0-100 cm soil layer under different fertilizing regimes and various planting ages were mea-sured, their stocks were calculated and their variation features were analyzed. The results showed that soil in the apple orchards in the study region was characterized by the decline in calcium contents. The decline was more serious in apple orchards with long-term application of chemical fertili-zer than in those with combined application of chemical fertilizer and farmyard manure. The average contents of calcium carbonate, water-soluble calcium and exchangeable calcium at 0-100 cm soil layer in apple orchards with long-term application of chemical fertilizer decreased by 38.8%, 25.4% and 5.6% respectively than those in the apple orchards with long-term application of both chemical fertilizer and farmyard manure. The stocks of calcium carbonate, water-soluble calcium and exchangeable calcium decreased by 36.4%, 26.0% and 4.3%, respectively. The decline of soil cal-cium was aggravated with the increase of orchard planting age. The contents of calcium carbonate, water-soluble calcium and exchangeable calcium at 0-100 cm soil layer in orchards of more than 25 years of planting age decreased by 48.8%, 69.4% and 39.5% respectively, compared with orchards of less than 10 years of planting age, and the stocks decreased by 40.8%, 64.1% and 33.0%, respectively. These results indicated that either long-term application of chemical fertilizer or long-term plantation of apple trees obviously depleted soil calcium carbonate, water-soluble calcium and exchangeable calcium. Therefore, it was recommended that application of chemical fertilizer and farmyard manure should be combined to mitigate soil calcium decline, and calcium management should be strengthened in apple orchards of more than 25 years of planting age. The fertilizing regime was a driving factor of soil calcium decline which had a significant temporal (orchard planting age) and spatial (soil depth) effect.

Impact of Moisture Content and Grain Size on Hydrocarbon Diffusion in Porous Media

NASA Astrophysics Data System (ADS)

McLain, A. A.; Ho, C. K.

2001-12-01

Diffusion of hydrocarbon vapors in porous media can play an important role in our ability to characterize subsurface contaminants such as trichloroethylene (TCE). For example, traditional monitoring methods often rely on direct sampling of contaminated soils or vapor. These samples may be influenced by the diffusion of vapors away from the contaminant source term, such as non-aqueous-phase TCE liquid. In addition, diffusion of hydrocarbon vapors can also impact the migration and dispersion of the contaminant in the subsurface. Therefore, understanding the diffusion rates and vapor transport processes of hydrocarbons in variably-saturated, heterogeneous porous media will assist in the characterization and detection of these subsurface contaminants. The purpose of this study was to investigate the impact of soil heterogeneity and water-moisture content on the diffusion processes for TCE. A one-dimensional column experiment was used to monitor the rates of vapor diffusion through sand. Experiments were performed with different average water-moisture contents and different grain sizes. On one end of the column, a reservoir cap is used to encase the TCE, providing a constant vapor boundary condition while sealing the end. The other end of the column contains a novel microchemical sensor. The sensor employs a polymer-absorption resistor (chemiresistor) that reversibly swells and increases in resistance when exposed to hydrocarbons. Once calibrated, the chemiresistors can be used to passively monitor vapor concentrations. This unique method allows the detection of in-situ vapor concentrations without disturbing the local environment. Results are presented in the form of vapor-concentration breakthrough curves as detected by the sensor. The shape of the breakthrough curve is dependent on several key parameters, including the length of the column and parameters (e.g., water-moisture content and grain-size) that affect the effective diffusion coefficient of TCE in air. Comparisons are made between theoretical and observed breakthrough curves to evaluate the diffusion of TCE and other relevant physical processes (e.g., air-water partitioning of TCE). The relative impact of water-moisture content and grain size on the diffusion of TCE vapor in porous media is also addressed. The authors thank Bob Hughes, who developed the chemiresistor sensors, and Chad Davis, who assisted with the calibrations. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy under Contract DE-AC04-94AL85000.

Assessing the average sodium content of prepacked foods with nutrition declarations: the importance of sales data.

PubMed

Korošec, Živa; Pravst, Igor

2014-09-04

Processed foods are recognized as a major contributor to high dietary sodium intake, associated with increased risk of cardiovascular disease. Different public health actions are being introduced to reduce sodium content in processed foods and sodium intake in general. A gradual reduction of sodium content in processed foods was proposed in Slovenia, but monitoring sodium content in the food supply is essential to evaluate the progress. Our primary objective was to test a new approach for assessing the sales-weighted average sodium content of prepacked foods on the market. We show that a combination of 12-month food sales data provided by food retailers covering the majority of the national market and a comprehensive food composition database compiled using food labelling data represent a robust and cost-effective approach to assessing the sales-weighted average sodium content of prepacked foods. Food categories with the highest sodium content were processed meats (particularly dry cured meat), ready meals (especially frozen pizza) and cheese. The reported results show that in most investigated food categories, market leaders in the Slovenian market have lower sodium contents than the category average. The proposed method represents an excellent tool for monitoring sodium content in the food supply.

Assessing the Average Sodium Content of Prepacked Foods with Nutrition Declarations: The Importance of Sales Data

PubMed Central

Korošec, Živa; Pravst, Igor

2014-01-01

Processed foods are recognized as a major contributor to high dietary sodium intake, associated with increased risk of cardiovascular disease. Different public health actions are being introduced to reduce sodium content in processed foods and sodium intake in general. A gradual reduction of sodium content in processed foods was proposed in Slovenia, but monitoring sodium content in the food supply is essential to evaluate the progress. Our primary objective was to test a new approach for assessing the sales-weighted average sodium content of prepacked foods on the market. We show that a combination of 12-month food sales data provided by food retailers covering the majority of the national market and a comprehensive food composition database compiled using food labelling data represent a robust and cost-effective approach to assessing the sales-weighted average sodium content of prepacked foods. Food categories with the highest sodium content were processed meats (particularly dry cured meat), ready meals (especially frozen pizza) and cheese. The reported results show that in most investigated food categories, market leaders in the Slovenian market have lower sodium contents than the category average. The proposed method represents an excellent tool for monitoring sodium content in the food supply. PMID:25192028

Health risk assessment to fluoride in drinking water of rural residents living in the Poldasht city, Northwest of Iran.

PubMed

Yousefi, Mahmood; Ghoochani, Mahboobeh; Hossein Mahvi, Amir

2018-02-01

This study analyzes the concentrations and health risks of fluoride in 112 drinking water samples collected from 28 villages of the Poldasht city, West Azerbaijan province in Iran. Results indicated that fluoride content in drinking water ranged from0.27 to 10.3mgL -1 (average 1.70mgL -1 ). The 57% of samples analyzed exceeded the limit set for fluoride in drinking water. Based on findings from health risk assessment this study, the highest fluoride exposure for different regions of Poldasht city was observed in young consumers, children and teenager's groups. Also, most of the rural residents suffered from fluoride contaminated drinking water. The calculated HQ value was > 1 for all groups of residents in Agh otlogh and Sari soo areas. Therefore, it is imperative to take measures to reduce fluoride concentration in drinking water and control of fluorosis. Action should be implemented to enhance monitoring of fluoride levels to avoid the potential risk to the population. Copyright © 2017 Elsevier Inc. All rights reserved.

Study of isotopes of carbon, thorium, and uranium in travertine and thermal spring samples: implications for effects of changes in geochemical environment and processes.

PubMed

Malov, Alexander I

2018-03-01

Data on modern radiocarbon activity in the old travertine formations of the Pymvashor hydrothermal system were used, in combination with 230 Th/U dating of the travertine, to estimate the 14 C contents of the total dissolved inorganic carbon in the ancient thermal water at the time of precipitation of the travertine ( 14 C calc ). With the known values of 14 C calc and average age of the thermal water, and under the assumption that the residence time of the water in aquifer was constant over the last 13.9 ± 1.5 ka, the initial 14 C contents ( 14 C 0 ) in the ancient thermal water were estimated. The findings in this study are that (1) both 14 C 0 and δ 13 С have decreased in young waters compared to the ancient waters; (2) although atmospheric 14 C activity ( 14 C atm ) has also decreased in the same time, the decrease in 14 C 0 is faster than the decrease in 14 C atm . Under certain assumptions, one could link changes in 14 C 0 and δ 13 C to climate change. Decrease in δ 13 С of soil CO 2 and decrease in 14 C 0 was caused predominantly by warmer and wetter climate, decomposition of fossil organic matter, and decrease in 14 C atm . There could be also increased dissolution of solid carbonate and increased carbon exchange between DIC and soil CO 2 , caused by thawing permafrost.

Hydration-Dependent Dynamical Modes in Xyloglucan from Molecular Dynamics Simulation of 13C NMR Relaxation Times and Their Distributions.

PubMed

Chen, Pan; Terenzi, Camilla; Furó, István; Berglund, Lars A; Wohlert, Jakob

2018-05-15

Macromolecular dynamics in biological systems, which play a crucial role for biomolecular function and activity at ambient temperature, depend strongly on moisture content. Yet, a generally accepted quantitative model of hydration-dependent phenomena based on local relaxation and diffusive dynamics of both polymer and its adsorbed water is still missing. In this work, atomistic-scale spatial distributions of motional modes are calculated using molecular dynamics simulations of hydrated xyloglucan (XG). These are shown to reproduce experimental hydration-dependent 13 C NMR longitudinal relaxation times ( T 1 ) at room temperature, and relevant features of their broad distributions, which are indicative of locally heterogeneous polymer reorientational dynamics. At low hydration, the self-diffusion behavior of water shows that water molecules are confined to particular locations in the randomly aggregated XG network while the average polymer segmental mobility remains low. Upon increasing water content, the hydration network becomes mobile and fully accessible for individual water molecules, and the motion of hydrated XG segments becomes faster. Yet, the polymer network retains a heterogeneous gel-like structure even at the highest level of hydration. We show that the observed distribution of relaxations times arises from the spatial heterogeneity of chain mobility that in turn is a result of heterogeneous distribution of water-chain and chain-chain interactions. Our findings contribute to the picture of hydration-dependent dynamics in other macromolecules such as proteins, DNA, and synthetic polymers, and hold important implications for the mechanical properties of polysaccharide matrixes in plants and plant-based materials.

Influence of Sub-Surface Irrigation on Soil Conditions and Water Irrigation Efficiency in a Cherry Orchard in a Hilly Semi-Arid Area of Northern China

PubMed Central

Peng, Gao; Bing, Wang; Guangcan, Zhang

2013-01-01

Sub-surface irrigation (SUI) is a new water-saving irrigation technology. To explore the influence of SUI on soil conditions in a cherry orchard and its water-saving efficiency, experiments were conducted from 2009 to 2010 using both SUI and flood irrigation (FLI) and different SUI quotas in hilly semi-arid area of northern China. The results demonstrated the following: 1) The bulk density of the soil under SUI was 6.8% lower than that of soil under FLI (P<0.01). The total soil porosity, capillary porosity and non-capillary porosity of soils using SUI were 11.7% (P<0.01), 8.7% (P<0.01) and 43.8% (P<0.01) higher than for soils using FLI. 2) The average soil temperatures at 0, 5, 10, 15 and 20 cm of soil depth using SUI were 1.7, 1.1, 0.7, 0.4 and 0.3°C higher than those for FLI, specifically, the differences between the surface soil layers were more significant. 3) Compared with FLI, the average water-saving efficiency of SUI was 55.6%, and SUI increased the irrigation productivity by 7.9-12.3 kg m-3 ha-1. 4) The soil moisture of different soil layers using SUI increased with increases in the irrigation quotas, and the soil moisture contents under SUI were significantly higher in the 0-20 cm layer and in the 21-50 cm layer than those under FLI (P<0.01). 5) The average yields of cherries under SUI with irrigation quotas of 80-320 m3 ha-1 were 8.7%-34.9% higher than those in soil with no irrigation (CK2). The average yields of cherries from soils using SUI were 4.5%-12.2% higher than using FLI. It is appropriate to irrigate 2-3 times with 230 m3 ha-1 per application using SUI in a year with normal rainfall. Our findings indicated that SUI could maintain the physical properties, greatly improve irrigation water use efficiency, and significantly increase fruit yields in hilly semi-arid areas of northern China. PMID:24039986

Effects of high dietary sodium chloride content on performance and sodium and potassium balance in growing pigs.

PubMed

Chittavong, Malavanh; Jansson, Anna; Lindberg, Jan Erik

2013-10-01

Thirty castrated male Moo Lath pigs (6-8 weeks of age) were used in a 15-week growth trial to study the effect of high dietary sodium chloride (NaCl) content on feed and water intake, performance, sodium (Na) and potassium (K) balance, and plasma aldosterone concentration. The pigs were randomly allocated (ten per treatment) to diets containing 0.24 % Na (Na0.24), 0.28 % Na (Na0.28), and 0.32 % Na (Na0.32) per kg diet. Feed and water was provided ad libitum, and water consumption, feed offered, and feed residues were recorded daily. Every third week, the pigs were weighed, blood samples were collected, and a 3-day total collection of urine and feces was performed. Water intake was higher (P = 0.001) in pigs fed with diets Na0.28 (3.7 L/day) and Na0.32 (3.9 L/day) than in pigs fed with diet Na0.24 (3.4 L/day), and dry matter (DM) intake was higher on diet Na0.32 (P = 0.041) than on the other diets. The average daily body weight (BW) gain was higher on diet Na0.32 than on the other diets (P = 0.031). The feed conversion ratio (in kilogram feed DM to kilogram BW gain) was 4.6, 4.6, and 4.1 on treatments Na0.24, Na0.28, and Na0.32, respectively (P = 0.14). The highest Na balance was observed on diet Na0.32 followed by diets Na0.28 and Na0.24 (P < 0.001), while there was no treatment-related pattern for the K balance. The Na/K ratio in feces and urine increased (P < 0.001), and the K/Na ratio in feces (P < 0.001) decreased with increasing Na content in the diet. Plasma aldosterone concentration decreased (P < 0.001) with increasing dietary content of Na. These results indicate that high NaCl intake and free access to water will increase Na balance but do not negatively influence feed intake and performance of growing local pigs.

Effect of water management, tillage options and phosphorus status on arsenic uptake in rice.

PubMed

Talukder, A S M H M; Meisner, C A; Sarkar, M A R; Islam, M S

2011-05-01

High arsenic (As) concentrations in soil may lead to elevated concentrations of arsenic in agricultural products. Field experiments were conducted to examine the effects of water management (WM) and Phosphorus (P) rates on As uptake, rice growth, yield and yield attributes of winter (boro) and monsoon (aman) rice in an As contaminated soil-water at Gobindagonj, Gaibandha, Bangladesh in 2004 and 2005. Significantly, the highest average grain yields (6.88±0.07 t ha(-1) in boro 6.38±0.06 t ha(-1) in aman) were recorded in permanent raised bed (PRB; aerobic WM: Eh=+360 mV) plus 100% P amendment. There was a 12% yield increase over conventional till on flat (CTF; anaerobic WM: Eh=-56 mV) at the same P level. In boro, the As content in grain and As content in straw were about 3 and 6 times higher in CTF compared to PRB, respectively. The highest total As content (0.646±0.01 ppm in grain and 10.93±0.19 ppm in straw) was recorded under CTF, and the lowest total As content (0.247±0.01 and 1.554±0.09 ppm in grain and straw, respectively) was recorded under PRB (aerobic WM). The results suggest that grain and straw As are closely associated in boro rice. The furrow irrigation approach of the PRB treatments consistently reduced irrigation input by 29-31% for boro and 27-30% for aman rice relative to CTF treatments in 2004 and 2005, respectively, thus reducing the amount of As added to the soil from the As-contaminated irrigation water. Yearly, 30% less As was deposited to the soil compared to CTF system through irrigation water during boro season. High As concentrations in grain and straw in rice grown using CTF in the farmers' field, and the fact that using PRB reduced grain As concentrations to value less than half of the proposed food hygiene standard. Copyright © 2010 Elsevier Inc. All rights reserved.

Radioactivity in the groundwater of a high background radiation area.

PubMed

Shabana, E I; Kinsara, A A

2014-11-01

Natural radioactivity was measured in groundwater samples collected from 37 wells scattered in an inhabited area of high natural background radiation, in a purpose of radiation protection. The study area is adjacent to Aja heights of granitic composition in Hail province, Saudi Arabia. Initial screening for gross α and gross β activities showed levels exceeded the national regulation limits set out for gross α and gross β activities in drinking water. The gross α activity ranged from 0.17 to 5.41 Bq L(-)(1) with an average value of 2.15 Bq L(-)(1), whereas gross β activity ranged from 0.48 to 5.16 Bq L(-)(1), with an average value of 2.60 Bq L(-)(1). The detail analyses indicated that the groundwater of this province is contaminated with uranium and radium ((226)Ra and (228)Ra). The average activity concentrations of (238)U, (234)U, (226)Ra and (228)Ra were 0.40, 0.77, 0.29 and 0.46 Bq L(-)(1), respectively. The higher uranium content was found in the samples of granitic aquifers, whereas the higher radium content was found in the samples of sandstone aquifers. Based on the obtained results, mechanism of leaching of the predominant radionuclides has been discussed in detail. Copyright © 2014 Elsevier Ltd. All rights reserved.

Running-induced patellofemoral pain fluctuates with changes in patella water content.

PubMed

Ho, Kai-Yu; Hu, Houchun H; Colletti, Patrick M; Powers, Christopher M

2014-01-01

Although increased bone water content resulting from repetitive patellofemoral joint loading has been suggested to be a possible mechanism underlying patellofemoral pain (PFP), there is little data to support this mechanism. The purpose of the current study was to determine whether running results in increases in patella water content and pain and whether 48 hours of rest reduces patella water content and pain to pre-running levels. Ten female runners with a diagnosis of PFP (mean age 25.1 years) participated. Patella water content was quantified using a chemical-shift-encoded water-fat magnetic resonance imaging (MRI) protocol. The visual analog scale (VAS) was used to quantify subjects' pain levels. MRI and pain data were obtained prior to running, immediately following a 40-minute running session, and 48 hours post-running. Pain and patella water content were compared among the 3 time points using one-way ANOVA's with repeated measures. Immediately post-running, persons with PFP reported significant increases in pain and exhibited elevated patella water content. Pain and patella water content decreased to pre-running levels following 48 hours of rest. Our findings suggest that transient changes in patella water content associated with running may, in part, contribute to patellofemoral symptoms.

Heating rates in tropical anvils

NASA Technical Reports Server (NTRS)

Ackerman, Thomas P.; Valero, Francisco P. J.; Pfister, Leonhard; Liou, Kuo-Nan

1988-01-01

The interaction of infrared and solar radiation with tropical cirrus anvils is addressed. Optical properties of the anvils are inferred from satellite observations and from high-altitude aircraft measurements. An infrared multiple-scattering model is used to compute heating rates in tropical anvils. Layer-average heating rates in 2 km thick anvils were found to be on the order of 20 to 30 K/day. The difference between heating rates at cloud bottom and cloud top ranges from 30 to 200 K/day, leading to convective instability in the anvil. The calculations are most sensitive to the assumed ice water content, but also are affected by the vertical distribution of ice water content and by the anvil thickness. Solar heating in anvils is shown to be less important than infrared heating but not negligible. The dynamical implications of the computed heating rates are also explored and it is concluded that the heating may have important consequences for upward mass transport in the tropics. The potential impact of tropical cirrus on the tropical energy balance and cloud forcing are discussed.

Chemical characterization, antioxidant and antitumor activity of sulfated polysaccharide from Sargassum horneri.

PubMed

Shao, Ping; Chen, Xiaoxiao; Sun, Peilong

2014-05-25

Three water-soluble polysaccharide fractions (SHP30, SHP60, and SHP80) extracted from the Sargassum horneri were obtained by water extraction and radial flow chromatography. The high-performance gel-permeation chromatography analysis showed that the average molecular weight (Mw) of three polysaccharides were approximately 1.58×10(3), 1.92×10(3) and 11.2KDa, respectively. Their in vitro antioxidant activities, antitumor activities were investigated and compared. Among these three polysaccharides, SHP30 with the highest sulfate content and intermediate molecular weight exhibited excellent antioxidant and antitumor activities in the superoxide radical assay, hydroxyl radical assay, reducing power assay, and MTT assay. Then, flow cytometry assay and quantitative real-time reverse transcription-PCR analysis suggested that the accumulation of cells in G0/G1 and S phase effecting apoptosis-associated gene expressions such as Bcl-2 and Bax might account for the growth inhibition of DLD cells by SHP30. Based on these results, we have inferred that sulfate content and molecular weight were the factors influencing antioxidant and antitumor activities. Crown Copyright © 2014. Published by Elsevier Ltd. All rights reserved.

Anaerobic methane oxidation in low-organic content methane seep sediments

USGS Publications Warehouse

Pohlman, John W.; Riedel, Michael; Bauer, James E.; Canuel, Elizabeth A.; Paull, Charles K.; Lapham, Laura; Grabowski, Kenneth S.; Coffin, Richard B.; Spence, George D.

2013-01-01

Sulfate-dependent anaerobic oxidation of methane (AOM) is the key sedimentary microbial process limiting methane emissions from marine sediments and methane seeps. In this study, we investigate how the presence of low-organic content sediment influences the capacity and efficiency of AOM at Bullseye vent, a gas hydrate-bearing cold seep offshore of Vancouver Island, Canada. The upper 8 m of sediment contains 14C. A fossil origin for the DIC precludes remineralization of non-fossil OM present within the sulfate zone as a significant contributor to pore water DIC, suggesting that nearly all sulfate is available for anaerobic oxidation of fossil seep methane. Methane flux from the SMT to the sediment water interface in a diffusion-dominated flux region of Bullseye vent was, on average, 96% less than at an OM-rich seep in the Gulf of Mexico with a similar methane flux regime. Evidence for enhanced methane oxidation capacity within OM-poor sediments has implications for assessing how climate-sensitive reservoirs of sedimentary methane (e.g., gas hydrate) will respond to ocean warming, particularly along glacially-influenced mid and high latitude continental margins.

Quantity of protein deposited on hydrogel contact lenses and its relation to visible protein deposits.

PubMed

Myers, R I; Larsen, D W; Tsao, M; Castellano, C; Becherer, L D; Fontana, F; Ghormley, N R; Meier, G

1991-10-01

The purposes of this study were to determine if the quantity of protein deposited (QPD) upon hydrogel lenses was affected by enzymatic cleaning and to test the potential relation between QPD and visible protein deposition (VPD) and change. Seventy-four contact lens patients classified as "heavy depositors" wore new lenses for an average of 80 (SD = 32) days. Cleaning and disinfection solutions varied. One lens was cleaned weekly by a papain enzymatic treatment. The distribution of QPD measurements was bimodal and was related to the FDA material for nonionic, low water content lenses (FDA Materials Group no. 1). The mean deposition was 45 micrograms/cm2 (N = 112) compared with that of ionic, high water content lenses (FDA Materials Group no. 4), which was 1010 micrograms/cm2 (N = 30). VPD distributions were the same for the FDA Group no. 1 and no. 4 lenses. Enzymatic treatment did not significantly reduce QPD; however, enzymatic treatment did reduce VPD. Thus QPD and VPD are independent phenomena and possible reasons for this are given.

Near surface water content estimation using GPR data: investigations within California vineyards

NASA Astrophysics Data System (ADS)

Hubbard, S.; Grote, K.; Lunt, I.; Rubin, Y.

2003-04-01

Detailed estimates of water content are necessary for variety of hydrogeological investigations. In viticulture applications, this information is particularly useful for assisting the design of both vineyard layout and efficient irrigation/agrochemical application. However, it is difficult to obtain sufficient information about the spatial variation of water content within the root zone using conventional point or wellbore measurements. We have investigated the applicability of ground penetrating radar (GPR) methods to estimate near surface water content within two California vineyard study sites: the Robert Mondavi Vineyard in Napa County and the Dehlinger Vineyard within Sonoma County. Our research at the winery study sites involves assessing the feasibility of obtaining accurate, non-invasive and dense estimates of water content and the changes in water content over space and time using both groundwave and reflected GPR events. We will present the spatial and temporal estimates of water content obtained from the GPR data at both sites. We will compare our estimates with conventional measurements of water content (obtained using gravimetric, TDR, and neutron probe techniques) as well as with soil texture and plant vigor measurements. Through these comparisons, we will illustrate the potential of GPR for providing reliable and spatially dense water content estimates and the linkages between water content, soil properties and ecosystem responses at the two study sites.

Soil water content spatial pattern estimated by thermal inertia from air-borne sensors

NASA Astrophysics Data System (ADS)

Coppola, Antonio; Basile, Angelo; Esposito, Marco; Menenti, Massimo; Buonanno, Maurizio

2010-05-01

Remote sensing of soil water content from air- or space-borne platforms offer the possibility to provide large spatial coverage and temporal continuity. The water content can be actually monitored in a thin soil layer, usually up to a depth of 0.05m below the soil surface. To the contrary, difficulties arise in the estimation of the water content storage along the soil profile and its spatial (horizontal) distribution, which are closely connected to soil hydraulic properties and their spatial distribution. A promising approach for estimating soil water contents profiles is the integration of remote sensing of surface water content and hydrological modeling. A major goal of the scientific group is to develop a practical and robust procedure for estimating water contents throughout the soil profile from surface water content. As a first step, in this work, we will show some preliminary results from aircraft images analysis and their validation by field campaigns data. The data extracted from the airborne sensors provided the opportunity of retrieving land surface temperatures with a very high spatial resolution. The surface water content pattern, as deduced by the thermal inertia estimations, was compared to the surface water contents maps measured in situ by time domain reflectometry-based probes.

Increases in soil water content after the mortality of non-native trees in oceanic island forest ecosystems are due to reduced water loss during dry periods.

PubMed

Hata, Kenji; Kawakami, Kazuto; Kachi, Naoki

2016-03-01

The control of dominant, non-native trees can alter the water balance of soils in forest ecosystems via hydrological processes, which results in changes in soil water environments. To test this idea, we evaluated the effects of the mortality of an invasive tree, Casuarina equisetifolia Forst., on the water content of surface soils on the Ogasawara Islands, subtropical islands in the northwestern Pacific Ocean, using a manipulative herbicide experiment. Temporal changes in volumetric water content of surface soils at 6 cm depth at sites where all trees of C. equisetifolia were killed by herbicide were compared with those of adjacent control sites before and after their mortality with consideration of the amount of precipitation. In addition, the rate of decrease in the soil water content during dry periods and the rate of increase in the soil water content during rainfall periods were compared between herbicide and control sites. Soil water content at sites treated with herbicide was significantly higher after treatment than soil water content at control sites during the same period. Differences between initial and minimum values of soil water content at the herbicide sites during the drying events were significantly lower than the corresponding differences in the control quadrats. During rainfall periods, both initial and maximum values of soil water contents in the herbicided quadrats were higher, and differences between the maximum and initial values did not differ between the herbicided and control quadrats. Our results indicated that the mortality of non-native trees from forest ecosystems increased water content of surface soils, due primarily to a slower rate of decrease in soil water content during dry periods. Copyright © 2015 Elsevier B.V. All rights reserved.

Use of electromagnetic induction surveys to delimit zones of contrasting tree development in an irrigated olive orchard in Southern Spain.

NASA Astrophysics Data System (ADS)

Pedrera, Aura; Vanderlinden, Karl; Jesús Espejo-Pérez, Antonio; Gómez, José Alfonso; Giráldez, Juan Vicente

2014-05-01

Olives are historically closely linked to Mediterranean culture and have nowadays important societal and economical implications. Improving yield and preventing infestation by soil-borne pathogens are crucial issues in maintaining olive cropping competitive. In order to assess both issues properly at the farm or field scale, accurate knowledge of the spatial distribution of soil physical properties and associated water dynamics is required. Conventional soil surveying is generally prohibitive at commercial farms, but electromagnetic induction (EMI) sensors, measuring soil apparent electrical conductivity (ECa) provide a suitable alternative. ECa depends strongly on soil texture and water content and has been used exhaustively in precision agriculture to delimit management zones. The aim of this study was to delimit areas with unsatisfactory tree development in an olive orchard using EMI, and to identify the underlying relationships between ECa and the soil properties driving the spatial tree development pattern. An experimental catchment in S. Spain dedicated to irrigated olive cropping was surveyed for ECa under dry and wet soil conditions (0.06 vs. 0.22 g/g, respectively), using a Dualem 21-S EMI sensor. In addition, ECa and gravimetric soil water content (SWC) was measured at 45 locations throughout the catchment during each survey. At each of these locations, soil profile samples were collected to determine textural class including coarse particles content, organic matter (OM), and bulk density. Measurements for dry soil conditions with the perpendicular coil configuration with a separation of 2.1 m (P2.1) were chosen to make a first assessment of the orchard-growth variability. According to the shape of the histogram, the P2.1 ECa values were classified to delimit three areas in the field for which canopy coverage was estimated. Combining the 4 ECa signals for the wet and dry surveys, a principal component (PC) analysis showed that 91% of the total variance could be explained by the first PC, representing a common pattern in the ECa data and showing a correlation of 0.98 with the P2.1 signal. The spatial pattern of canopy coverage corresponded well with the pattern of the ECa P2.1 signal. The area with the lowest ECa (Zone A) showed optimal tree growth and presented significantly lower average clay content than the area with intermediate and highest ECa (Zones B and C, respectively). Zone B, located in the lowest area of the field, with the highest profile-averaged soil-water, stone and OM contents, showed deficient tree development and tree die-off as a result of soil-borne pathogens. EMI surveys reflecting subtle differences in soil properties provided a useful information to delimit areas with tree development problems. This information can be used in conjunction with topographic surveys to identify before planting areas with potential tree development problems, including soil-borne pathogens.

Near-Infrared Spectroscopic Method for Monitoring Water Content in Epoxy Resins and Fiber-Reinforced Composites

PubMed Central

Gagani, Abedin I.; Echtermeyer, Andreas T.

2018-01-01

Monitoring water content and predicting the water-induced drop in strength of fiber-reinforced composites are of great importance for the oil and gas and marine industries. Fourier transform infrared (FTIR) spectroscopic methods are broadly available and often used for process and quality control in industrial applications. A benefit of using such spectroscopic methods over the conventional gravimetric analysis is the possibility to deduce the mass of an absolutely dry material and subsequently the true water content, which is an important indicator of water content-dependent properties. The objective of this study is to develop an efficient and detailed method for estimating the water content in epoxy resins and fiber-reinforced composites. In this study, Fourier transform near-infrared (FT-NIR) spectroscopy was applied to measure the water content of amine-epoxy neat resin. The method was developed and successfully extended to glass fiber-reinforced composite materials. Based on extensive measurements of neat resin and composite samples of varying water content and thickness, regression was performed, and the quantitative absorbance dependence on water content in the material was established. The mass of an absolutely dry resin was identified, and the true water content was obtained. The method was related to the Beer–Lambert law and explained in such terms. A detailed spectroscopic method for measuring water content in resins and fiber-reinforced composites was developed and described. PMID:29641451

Near-Infrared Spectroscopic Method for Monitoring Water Content in Epoxy Resins and Fiber-Reinforced Composites.

PubMed

Krauklis, Andrey E; Gagani, Abedin I; Echtermeyer, Andreas T

2018-04-11

Monitoring water content and predicting the water-induced drop in strength of fiber-reinforced composites are of great importance for the oil and gas and marine industries. Fourier transform infrared (FTIR) spectroscopic methods are broadly available and often used for process and quality control in industrial applications. A benefit of using such spectroscopic methods over the conventional gravimetric analysis is the possibility to deduce the mass of an absolutely dry material and subsequently the true water content, which is an important indicator of water content-dependent properties. The objective of this study is to develop an efficient and detailed method for estimating the water content in epoxy resins and fiber-reinforced composites. In this study, Fourier transform near-infrared (FT-NIR) spectroscopy was applied to measure the water content of amine-epoxy neat resin. The method was developed and successfully extended to glass fiber-reinforced composite materials. Based on extensive measurements of neat resin and composite samples of varying water content and thickness, regression was performed, and the quantitative absorbance dependence on water content in the material was established. The mass of an absolutely dry resin was identified, and the true water content was obtained. The method was related to the Beer-Lambert law and explained in such terms. A detailed spectroscopic method for measuring water content in resins and fiber-reinforced composites was developed and described.

Characterization of cement float buoyancy in the stalked barnacle Dosima fascicularis (Crustacea, Cirripedia).

PubMed

Zheden, Vanessa; Kovalev, Alexander; Gorb, Stanislav N; Klepal, Waltraud

2015-02-06

Dosima fascicularis is the only barnacle which can drift autonomously at the water surface with a foam-like cement float. The cement secreted by the animal contains numerous gas-filled cells of different size. When several individuals share one float, their size and not their number is crucial for the production of both volume and mass of the float. The gas content within the cells of the foam gives positive static buoyancy to the whole float. The volume of the float, the gas volume and the positive static buoyancy are positively correlated. The density of the cement float without gas is greater than that of seawater. This study shows that the secreted cement consists of more than 90% water and the gas volume is on average 18.5%. Our experiments demonstrate that the intact foam-like cement float is sealed to the surrounding water.

Characterization of cement float buoyancy in the stalked barnacle Dosima fascicularis (Crustacea, Cirripedia)

PubMed Central

Zheden, Vanessa; Kovalev, Alexander; Gorb, Stanislav N.; Klepal, Waltraud

2015-01-01

Dosima fascicularis is the only barnacle which can drift autonomously at the water surface with a foam-like cement float. The cement secreted by the animal contains numerous gas-filled cells of different size. When several individuals share one float, their size and not their number is crucial for the production of both volume and mass of the float. The gas content within the cells of the foam gives positive static buoyancy to the whole float. The volume of the float, the gas volume and the positive static buoyancy are positively correlated. The density of the cement float without gas is greater than that of seawater. This study shows that the secreted cement consists of more than 90% water and the gas volume is on average 18.5%. Our experiments demonstrate that the intact foam-like cement float is sealed to the surrounding water. PMID:25657839

Conditioning of inspired air by a hygroscopic condenser humidifier.

PubMed

Primiano, F P; Moranz, M E; Montague, F W; Miller, R B; Sachs, D P

1984-08-01

The heat and water content of inspired air is critical to the pulmonary viability of patients with artificial airways. By continuously measuring gas conditions in the ventilator circuits of 6 adult ICU patients, we studied the heat and water reclaimed from expired air by a hygroscopic condenser humidifier (HCH) in the circuit. Temperature, partial pressure of water vapor (PH2O) and relative humidity (RH) were determined at the tracheal outlet of the endotracheal tube. The HCH was 63% efficient; the end-inspiratory gas delivered to the patients averaged 30.9 degrees C with a PH2O of 32.5 mm Hg and an RH of 97.3% or, equivalently, an RH of 69.2% referenced to 37 degrees C. These values are lower than those reported in the literature for gas in the trachea during nose breathing of ambient air, but greater than the values reported for mouth breathing of ambient air.

Genetic algorithm applied to a Soil-Vegetation-Atmosphere system: Sensitivity and uncertainty analysis

NASA Astrophysics Data System (ADS)

Schneider, Sébastien; Jacques, Diederik; Mallants, Dirk

2010-05-01

Numerical models are of precious help for predicting water fluxes in the vadose zone and more specifically in Soil-Vegetation-Atmosphere (SVA) systems. For such simulations, robust models and representative soil hydraulic parameters are required. Calibration of unsaturated hydraulic properties is known to be a difficult optimization problem due to the high non-linearity of the water flow equations. Therefore, robust methods are needed to avoid the optimization process to lead to non-optimal parameters. Evolutionary algorithms and specifically genetic algorithms (GAs) are very well suited for those complex parameter optimization problems. Additionally, GAs offer the opportunity to assess the confidence in the hydraulic parameter estimations, because of the large number of model realizations. The SVA system in this study concerns a pine stand on a heterogeneous sandy soil (podzol) in the Campine region in the north of Belgium. Throughfall and other meteorological data and water contents at different soil depths have been recorded during one year at a daily time step in two lysimeters. The water table level, which is varying between 95 and 170 cm, has been recorded with intervals of 0.5 hour. The leaf area index was measured as well at some selected time moments during the year in order to evaluate the energy which reaches the soil and to deduce the potential evaporation. Water contents at several depths have been recorded. Based on the profile description, five soil layers have been distinguished in the podzol. Two models have been used for simulating water fluxes: (i) a mechanistic model, the HYDRUS-1D model, which solves the Richards' equation, and (ii) a compartmental model, which treats the soil profile as a bucket into which water flows until its maximum capacity is reached. A global sensitivity analysis (Morris' one-at-a-time sensitivity analysis) was run previously to the calibration, in order to check the sensitivity in the chosen parameter search space. For the inversion procedure a genetical algorithm (GA) was used. Specific features such as elitism, roulette-wheel process for selection operator and island theory were implemented. Optimization was based on the water content measurements recorded at several depths. Ten scenarios have been elaborated and applied on the two lysimeters in order to investigate the impact of the conceptual model in terms of processes description (mechanistic or compartmental) and geometry (number of horizons in the profile description) on the calibration accuracy. Calibration leads to a good agreement with the measured water contents. The most critical parameters for improving the goodness of fit are the number of horizons and the type of process description. Best fit are found for a mechanistic model with 5 horizons resulting in absolute differences between observed and simulated water contents less than 0.02 cm3cm-3 in average. Parameter estimate analysis shows that layers thicknesses are poorly constrained whereas hydraulic parameters are much well defined.

Recreational runners with patellofemoral pain exhibit elevated patella water content.

PubMed

Ho, Kai-Yu; Hu, Houchun H; Colletti, Patrick M; Powers, Christopher M

2014-09-01

Increased bone water content resulting from repetitive patellofemoral joint overloading has been suggested to be a possible mechanism underlying patellofemoral pain (PFP). To date, it remains unknown whether persons with PFP exhibit elevated bone water content. The purpose of this study was to determine whether recreational runners with PFP exhibit elevated patella water content when compared to pain-free controls. Ten female recreational runners with a diagnosis of PFP (22 to 39years of age) and 10 gender, age, weight, height, and activity matched controls underwent chemical-shift-encoded water-fat magnetic resonance imaging (MRI) to quantify patella water content (i.e., water-signal fraction). Differences in bone water content of the total patella, lateral aspect of the patella, and medial aspect of the patella were compared between groups using independent t tests. Compared with the control group, the PFP group demonstrated significantly greater total patella bone water content (15.4±3.5% vs. 10.3±2.1%; P=0.001), lateral patella water content (17.2±4.2% vs. 11.5±2.5%; P=0.002), and medial patella water content (13.2±2.7% vs. 8.4±2.3%; P<0.001). The higher patella water content observed in female runners with PFP is suggestive of venous engorgement and elevated extracellular fluid. In turn, this may lead to an increase in intraosseous pressure and pain. Copyright © 2014 Elsevier Inc. All rights reserved.

Water Absorption Behavior of Hemp Hurds Composites

PubMed Central

Stevulova, Nadezda; Cigasova, Julia; Purcz, Pavol; Schwarzova, Ivana; Kacik, Frantisek; Geffert, Anton

2015-01-01

In this paper, water sorption behavior of 28 days hardened composites based on hemp hurds and inorganic binder was studied. Two kinds of absorption tests on dried cube specimens in deionized water bath at laboratory temperature were performed. Short-term (after one hour water immersion) and long-term (up to 180 days) water absorption tests were carried out to study their durability. Short-term water sorption behavior of original hemp hurds composites depends on mean particle length of hemp and on binder nature. The comparative study of long-term water sorption behavior of composites reinforced with original and chemically modified hemp hurds in three reagents confirmed that surface treatment of filler influences sorption process. Based on evaluation of sorption curves using a model for composites based on natural fibers, diffusion of water molecules in composite reinforced with original and chemically modified hemp hurds is anomalous in terms of the Fickian behavior. The most significant decrease in hydrophility of hemp hurds was found in case of hemp hurds modified by NaOH and it relates to change in the chemical composition of hemp hurds, especially to a decrease in average degree of cellulose polymerization as well as hemicellulose content.

Online monitoring of water-soluble ionic composition of PM10 during early summer over Lanzhou City.

PubMed

Fan, Jin; Yue, Xiaoying; Jing, Yi; Chen, Qiang; Wang, Shigong

2014-02-01

Lanzhou is one of the most aerosol-polluted cities in China. In this study, an online analyzer for Monitoring for AeRosols and GAses was deployed to measure major water-soluble inorganic ions in PM10 at 1-hour time resolution, and 923 samples were obtained from Apr 1 to May 24, 2011. During the field campaign, air pollution days were encountered with Air Quality Index more than 100 and daily average concentration of PM10 exceeding 150 microg/m3. Based on the variation of water-soluble ions and results of Positive Matrix Factorization 3.0 model execution, the air pollution days were classified as crustal species- or secondary aerosol-induced, and the different formation mechanisms of these two air pollution types were studied. During the crustal species pollution days, the content of Ca2+ increased and was about 2.3 times higher than the average on clear days, and the air parcel back trajectory was used to analyze the sources of crustal species. Data on sulfate, trace gases and meteorological factors were used to reveal the formation mechanism of secondary aerosol pollution. The sulfur oxidation ratio (SOR) was derived from the 923 samples, and the SOR had high positive correlation with relative humidity in early summer in Lanzhou.

Time lag estimates for nitrate travel through the vadose zone in Southland, New Zealand

NASA Astrophysics Data System (ADS)

Wilson, Scott; Chanut, Pierre; Ledgard, George; Rissmann, Clint

2014-05-01

A regional-scale study was carried out to calculate the travel time of a nitrate particle from the ground surface into shallow groundwater. The aim of the study was to obtain preliminary answers to two questions. Firstly, if leaching limits are set, how long would it take to see an improvement in shallow groundwater quality? Secondly, have groundwater nitrate concentrations reached equilibrium from recent dairy expansion in the region, or could we expect future increases? We applied a methodology that provides a balance between the detail and generalisation that is required for a regional-scale study. Steady-state advective transport through the vadose zone was modelled with water retention curves. These curves enable an estimate of the average volumetric water content of the vadose zone. The percentage saturation can then be used to calculate the vadose zone transit time if effective porosity, depth to the water table and annual average soil drainage are known. A time for mixing in the uppermost part of the aquifer has also been calculated. Two different vadose zone water retention curve models were used for comparison, the Brooks-Corey (1964), and the Van Genuchten (1980) methods. The water retention curves were parameterised by sediment texture via the Rawls and Brakensiek (1985) pedotransfer functions. Hydraulic properties were derived by positioning sediment textural descriptions on the Folk textural triangle, estimates of effective porosity from literature, and hydraulic conductivity values from aquifer tests. Uncertainty of parameter estimates was included by assigning standard deviations and appropriate probability distributions. Vadose zone saturation was modelled at 6,450 sites across the region with a Monte Carlo simulation involving 10,000 realisations. This generated a probability distribution of saturation for each site. Average volumetric water content of the vadose zone ranged from 8.5 to 40.7 % for the Brooks-Corey model and 12.9 to 36.3% for the Van Genuchten model. The large number of 1-D calculations allows the results to be presented spatially. About 80% of the region is expected to have a transit time of less than five years, and 90% less than two years. Older transit times are associated with mid Pleistocene outwash gravels. These deposits have lower permeability, and are also located at higher elevations above the rivers. The results indicate that shallow groundwater beneath properties in most of Southland will respond rapidly to a reduction in leaching rates. Large future increases in nitrate concentrations are only expected in discrete areas beneath older more elevated outwash gravel deposits. Preliminary validation of the modelled values has been carried out by comparison with tritium ages at the top of the aquifer and the results are encouraging.

[Low caloric value and high salt content in the meals served in school canteens].

PubMed

Paiva, Isabel; Pinto, Carlos; Queirós, Laurinda; Meister, Maria Cristina; Saraiva, Margarida; Bruno, Paula; Antunes, Delfina; Afonso, Manuel

2011-01-01

School lunch can contribute to aggravate food quality, by excess or deficiency, or it can contribute to compensate and alleviate them. This school meal should be an answer to combating the epidemic of obesity, and to feed some grace children. The objective was to study the nutritional composition of catering in canteens of public schools, from Northern municipalities in the District of Porto: Vila do Conde, Póvoa de Varzim, Santo Tirso and Trofa. Meals were subjected to laboratory analysis. Thirty two meals, four per each school were analysed, reference values for the analysis of the nutritional composition of meals were dietary reference intakes (USA) and eating well at school (UK). The average energy meal content was 447 kcal and the median 440 kcal (22% of daily calories). The average values of nutrients, per meal, were: lipids 9, 8 g, carbohydrate 65,7 g and proteins 24,0 g. In average the contribution for the meal energy was: 20% fat, 59% carbohydrate and 21% protein. In more than 75% of meals the contribution of lipid content was below the lower bound of the reference range. The average content of sodium chloride per meal was 3.4 g, and the confidence interval 95% to average 3.0 to 3.8 g, well above the recommended maximum value of 1.5 grams. The average content fiber per meal was 10.8 g higher than the minimum considered appropriate. In conclusion, the value low caloric meals was mainly due to the low fat content, and content salt of any of the components of the meal was very high.

Tectonic setting of Jurassic basins in Central Mongolia: Insights from the geochemistry of Tsagaan-Ovoo oil shale

NASA Astrophysics Data System (ADS)

Erdenetsogt, B. O.; Hong, S. K.; Choi, J.; Odgerel, N.; Lee, I.; Ichinnorov, N.; Tsolmon, G.; Munkhnasan, B.

2017-12-01

Tsagaan-Ovoo syncline hosting Lower-Middle Jurassic oil shale is a part of Saikhan-Ovoo the largest Jurassic sedimentary basin in Central Mongolia. It is generally accepted that early Mesozoic basins are foreland basins. In total, 18 oil shale samples were collected from an open-pit mine. The contents of organic carbon, and total nitrogen and their isotopic compositions as well as major element concentrations were analyzed. The average TOC content is 12.4±1.2 %, indicating excellent source rock potential. C/N ratios show an average of 30.0±1.2, suggesting terrestrial OM. The average value of δ15N is +3.9±0.2‰, while that of δ13Corg is -25.7±0.1‰. The isotopic compositions argue for OM derived dominantly from land plant. Moreover, changes in δ15N values of analyzed samples reflect variations in algal OM concentration of oil shale. The lowest δ15N value (+2.5‰) was obtained from base section, representing the highest amount of terrestrial OM, whereas higher δ15N values (up to +5.2‰) are recorded at top section, reflecting increased amount of algal OM. On the other hand, changes in δ15N value may also represent changes in redox state of water column in paleolake. The oil shale at bottom of section with low δ15N value was accumulated under oxic condition, when the delivery of land plant OM was high. With increase in subsidence rate through time, lake was deepened and water column was depleted in oxygen probably due to extensive phytoplankton growth, which results increase in algae derived OM contents as well as bulk δ15N of oil shale. The average value of CAI for Tsagan-Ovoo oil shale is 81.6±1.3, reflecting intensive weathering in the source area. The plotted data on A-CN-K diagram displays that oil shale was sourced mainly from Early Permian granodiorite and diorite, which are widely distributed around Tsagaan-Ovoo syncline. To infer tectonic setting, two multi-dimensional discrimination diagrams were used. The results suggest that the tectonic setting of Tsagaan-Ovoo syncline, in which the studied oil shale was deposited, was continental rift. This finding contradicts with generally accepted contractile deformation during early Mesozoic in Mongolia and China. Further detailed study is required to decipher the tectonic settings of central Mongolian Jurassic basins.

Seawater as the source of minor elements in black shales, phosphorites and other sedimentary rocks

USGS Publications Warehouse

Piper, D.Z.

1994-01-01

Many of the minor elements in seawater today have a concentration-depth profile similar to that of the biologically essential nutrients, NO-3 and PO3-4. They show a relative depletion in the photic zone and enrichment in the deep ocean. The difference between their surface- and deep-ocean values, normalized to the change in PO3-4, approaches the average of measured minor-element: P ratios in marine plankton, although individual analyses of the latter show extreme scatter for a variety of reasons. Despite this scatter in the minor-element analyses of plankton, agreement between the two sets of data shows unequivocally that an important marine flux of many minor elements through the ocean is in the form of biogenic matter, with a composition approaching that of plankton. This interpretation is further supported by sediment studies, particularly of sediments which accumulate in shelf-slope environments where biological productivity in the photic zone is exceptionally high and organic carbon contents of the underlying sediment elevated. The interelement relations observed for some of these sediments approach the average values of plankton. These same interelement relations are observed in many marine sedimentary rocks such as metalliferous black shales and phosphorites, rocks which have a high content of marine fractions (e.g., organic matter, apatite, biogenic silica and carbonates). Many previous studies of the geochemistry of these rocks have concluded that local hydrothermal activity, and/or seawater with an elemental content different from that of the modern ocean, was required to account for their minor-element contents. However, the similarity in several of the minor-element ratios in many of these formations to minor-element ratios in modern plankton demonstrates that these sedimentary rocks accumulated in environments whose marine chemistry was virtually identical to that seen on continental shelf-slopes, or in marginal seas, of the ocean today. The accumulation of the marine fraction of minor elements on these ancient sea floors was determined largely by the accumulation of organic matter, settling from the photic zone and with a composition of average plankton. A second marine fraction of minor elements in these rocks accumulated through precipitation and adsorption from seawater. The suite of elements in this fraction reflects redox conditions in the bottom water, as determined by bacterial respiration. For example, high Mn, high Cr+V and high Mo concentrations, above those which can be attributed to the accumulation of planktonic matter, characterize accumulation under bottom-water oxidizing, denitrifying and sulfate-reducing conditions, respectively. ?? 1994.

Transport of human adenoviruses in porous media

NASA Astrophysics Data System (ADS)

Kokkinos, Petros; Syngouna, Vasiliki I.; Tselepi, Maria A.; Bellou, Maria; Chrysikopoulos, Constantinos V.; Vantarakis, Apostolos

2015-04-01

Groundwater may be contaminated with infective human enteric viruses from various wastewater discharges, sanitary landfills, septic tanks, agricultural practices, and artificial groundwater recharge. Coliphages have been widely used as surrogates of enteric viruses, because they share many fundamental properties and features. Although a large number of studies focusing on various factors (i.e. pore water solution chemistry, fluid velocity, moisture content, temperature, and grain size) that affect biocolloid (bacteria, viruses) transport have been published over the past two decades, little attention has been given toward human adenoviruses (hAdVs). The main objective of this study was to evaluate the effect of pore water velocity on hAdV transport in water saturated laboratory-scale columns packed with glass beads. The effects of pore water velocity on virus transport and retention in porous media was examined at three pore water velocities (0.39, 0.75, and 1.22 cm/min). The results indicated that all estimated average mass recovery values for hAdV were lower than those of coliphages, which were previously reported in the literature by others for experiments conducted under similar experimental conditions. However, no obvious relationship between hAdV mass recovery and water velocity could be established from the experimental results. The collision efficiencies were quantified using the classical colloid filtration theory. Average collision efficiency, α, values decreased with decreasing flow rate, Q, and pore water velocity, U, but no significant effect of U on α was observed. Furthermore, the surface properties of viruses and glass beads were used to construct classical DLVO potential energy profiles. The results revealed that the experimental conditions of this study were unfavorable to deposition and that no aggregation between virus particles is expected to occur. A thorough understanding of the key processes governing virus transport is pivotal for public health protection.

Seven hundred years of peat formation recorded throughout a deep floating mire profile from Central Italy

NASA Astrophysics Data System (ADS)

Lobianco, Daniela; D'Orazio, Valeria; Miano, Teodoro; Zaccone, Claudio

2016-04-01

Floating mires are defined by the occurrence of emergent vegetation rooted in highly organic buoyant mats that rise and fall with changes in water level. Islands floating and moving on a lake naturally were already described by Pliny the Elder in his Naturalis historia almost two millennia ago. Actually, he devoted a whole chapter of Naturalis historia to "Of Islands Ever Floating and Swimming", reporting how certain isles were always waving and never stood still. The status of "flotant" has been defined transitory; in fact, these small isles often disappear, in most of the cases because of a transition from floating island to firm land during decades is likely to happen. That is why most of the floating islands described by Pliny the Elder (e.g., Lacus Fundanus, Lacus Cutiliensis, Lacus Mutinensis, Lacus Statoniensis, Lacus Tarquiniensis, Lydia Calaminae, Lacus Vadimonis) do not exist anymore. In the present study, peat formation and organic matter evolution were investigated in order to understand how these peculiar environments form, and how stable actually they are. In fact, it is hoped that peat-forming floating mires could provide an exceptional tool for environmental studies, since much of their evolution, as well as the changes of the surrounding areas, is recorded in their peat deposits. A complete, 4-m deep peat core was collected in July 2012 from the floating island of Posta Fibreno, a relic mire in the Central Italy. This floating island has a diameter of ca. 30 m, a submerged thickness of about 3 m, and the vegetation is organized in concentric belts, from the Carex paniculata palisade to the Sphagnum centre. Here, some of the southernmost Italian populations of Sphagnum palustre occur. The 14C age dating of organic sediments isolated from the sample at 385 cm of depth revealed that the island formed ca. 700 yrs ago (620±30 yr BP). The top 100 cm, consisting almost exclusively of Sphagnum mosses, show a very low bulk density (avg., 0.03±0.01 g cm-3), an ash content ranging from 0.8 and 7.4%, an average gravimetric water content of 26.6±7.7 gwater gdrypeat-1, and a pH generally increasing with depth (from 4.1 to 7.2). The C content along the profile ranged between 35 and 47% (avg., 41±4%), whereas the N between 0.3 and 1.1% (avg., 0.5±0.1%). Main atomic ratios (C/N, H/C and O/C) and FT-IR spectra seem to confirm what found during the visual inspection of the core, i.e., Sphagnum material so well preserved that it is hard to classify it as "peat". In fact, the 14C age dating suggests that the first 110 cm of Sphagnum material accumulated in ca. 55 yrs, thus resulting in an average growing rate of 2 cm yr-1. The remaining 300 cm (from 100 to 400 cm of depth), i.e., the submerged part of the island, consist of peat showing completely different botanical composition (reed-fen peat and silty peat rich in reeds) and physical and chemical properties. In particular, both bulk density (avg., 0.09±0.05 g cm-3) and ash content increase, reaching their maximum at 300-325 cm of depth (0.27 g cm-3 and 17%, respectively), whereas the average gravimetric water content significantly decreases (17.4±9.0 gwater gdrypeat-1). The pH ranges from 6.6 and 7.4. Both C and N along this section of the profile show higher average contents (44±3 and 1.3±0.6%, respectively) compared to those recorded in the upper 100 cm layer; furthermore, the decrease with depth of C/N, H/C and O/C atomic ratios, as well as main absorption bands of FT-IR spectra, clearly indicate the occurrence of an organic matter highly humified. The estimated accumulation rate for the bottom 300 cm of the island is 0.5 cm yr-1. At the best of our knowledge, this work represents the first characterization of a (4 m) deep floating mire profile. At Posta Fibreno, the deep water layer below the base of the island (7 m) and the movement on the water surface probably avoided the transition from floating island to firm land, thus allowing this island to float during the last centuries. The Authors thank the Municipality of Posta Fibreno (FR), Managing Authority of the Regional Natural Reserve of Lake Posta Fibreno, for allowing peat cores sampling.

Hydrologic data for the Larimer-Weld regional water-monitoring program, Colorado, 1975-82

USGS Publications Warehouse

Blakely, S.R.; Steinheimer, J.T.

1984-01-01

The Larimer-Weld, Colorado, regional Monitoring Program was begun in 1976 to provide information on the quality and quantity of the surface-water resources in the area. Three stations on the big Thompson River and five stations on the Cache La Poudre River were selected for a data-collection network. Four previously established stations were added to complete the data-collection network: Horsetooth Reservoir, Joe Wright Creek above and below Joe Wright Reservoir, and Michigan River near Cameron Pass. Station description, location, and period of record are given for each station. A statistical summary of the water-quality data for each station is tabulated. Frequency of occurrence is given at the 95th, 75th, 50th, and 25th percentiles. Monthly water-quality data and daily average streamflow data are tabulated for each streamflow station for which this data was collected; Monthly contents data are presented for Horsetooth Reservoir. All data tabulated and summarized are from the period October 1, 1975, through September 30, 1982. (USGS)

Bio-conversion of water hyacinths into methane gas. Part 1. [Effects of cadmium and nickel pollution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wolverton, B.C.; Mcdonald, R.C.; Gordon, J.

1974-07-01

Bio-gas and methane production from the microbial anaerobic decomposition of water hyacinths (Eichhornia crassipes) (Mart) Solms was investigated. These experiments demonstrated the ability of water hyacinths to produce an average of 13.9 ml of methane gas per gram of wet plant weight. This study revealed that sample preparation had no significant effect on bio-gas and/or methane production. Pollution of water hyacinths by two toxic heavy materials, nickel and cadmium, increased the rate of methane production from 51.8 ml/day for non-contaminated plants incubated at 36 C to 81.0 ml/day for Ni-Cd contaminated plants incubated at the same temperature. The methane contentmore » of bio-gas evolved from the anaerobic decomposition of Ni-Cd contaminated plants was 91.1 percent as compared to 69.2 percent methane content of bio-gas collected from the fermentation of non-contaminated plants. (Author) (GRA)« less

Cultivation of marine microalgae using shale gas flowback water and anaerobic digestion effluent as the cultivation medium.

PubMed

Racharaks, Ratanachat; Ge, Xumeng; Li, Yebo

2015-09-01

The potential of shale gas flowback water and anaerobic digestion (AD) effluent to reduce the water and nutrient requirements for marine microalgae cultivation was evaluated with the following strains: Nannochloropsis salina, Dunaliella tertiolecta, and Dunaliella salina. N. salina and D. tertiolecta achieved the highest biomass productivity in the medium composed of flowback water and AD effluent (6% v/v). Growth in the above unsterilized medium was found to be comparable to that in sterilized commercial media with similar initial inorganic nitrogen concentrations, salinity, and pH levels. Specific growth rates of 0.293 and 0.349 day(-1) and average biomass productivities of 225 and 275 mg L(-1)day(-1) were obtained for N. salina and D. tertiolecta, respectively. The lipid content and fatty acid profile of both strains in the medium were also comparable to those obtained with commercial nutrients and salts. Copyright © 2015 Elsevier Ltd. All rights reserved.

Preparation of Starch/Gelatin Blend Microparticles by a Water-in-Oil Emulsion Method for Controlled Release Drug Delivery.

PubMed

Phromsopha, Theeraphol; Baimark, Yodthong

2014-01-01

Information on the preparation and properties of starch/gelatin blend microparticles with and without crosslinking for drug delivery is presented. The blend microparticles were prepared by the water-in-oil emulsion solvent diffusion method. Glutaraldehyde and methylene blue were used as the crosslinker and the water-soluble drug model, respectively. The blend microparticles were characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and UV-Vis spectroscopy. The functional groups of the starch and gelatin blend matrices were determined from the FTIR spectra. Blend microparticles with a nearly spherical shape and internal porous structure were observed from SEM images. The average particle size of the gelatin microparticles depended on the crosslinker ratio but not on the starch/gelatin blend ratio. The in vitro drug release content significantly decreased as the crosslinker ratio increased and the starch blend ratio decreased. The results demonstrated that the starch/gelatin blend microparticles should be a useful controlled release delivery carrier for water-soluble drugs.

Preparation of Starch/Gelatin Blend Microparticles by a Water-in-Oil Emulsion Method for Controlled Release Drug Delivery

PubMed Central

Phromsopha, Theeraphol; Baimark, Yodthong

2014-01-01

Information on the preparation and properties of starch/gelatin blend microparticles with and without crosslinking for drug delivery is presented. The blend microparticles were prepared by the water-in-oil emulsion solvent diffusion method. Glutaraldehyde and methylene blue were used as the crosslinker and the water-soluble drug model, respectively. The blend microparticles were characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and UV-Vis spectroscopy. The functional groups of the starch and gelatin blend matrices were determined from the FTIR spectra. Blend microparticles with a nearly spherical shape and internal porous structure were observed from SEM images. The average particle size of the gelatin microparticles depended on the crosslinker ratio but not on the starch/gelatin blend ratio. The in vitro drug release content significantly decreased as the crosslinker ratio increased and the starch blend ratio decreased. The results demonstrated that the starch/gelatin blend microparticles should be a useful controlled release delivery carrier for water-soluble drugs. PMID:24868207

[Effect of shifting sand burial on evaporation reduction and salt restraint under saline water irrigation in extremely arid region].

PubMed

Zhang, Jian-Guo; Zhao, Ying; Xu, Xin-Wen; Lei, Jia-Qiang; Li, Sheng-Yu; Wang, Yong-Dong

2014-05-01

The Taklimakan Desert Highway Shelterbelt is drip-irrigated with high saline groundwater (2.58-29.70 g x L(-1)), and shifting sand burial and water-salt stress are most common and serious problems in this region. So it is of great importance to study the effect of shifting sand burial on soil moisture evaporation, salt accumulation and their distribution for water saving, salinity restraint, and suitable utilization of local land and water resources. In this study, Micro-Lysimeters (MLS) were used to investigate dynamics of soil moisture and salt under different thicknesses of sand burial (1, 2, 3, 4, and 5 cm), and field control experiments of drip-irrigation were also carried out to investigate soil moisture and salt distribution under different thicknesses of shifting sand burial (5, 10, 15, 20, 25, 30, 35, and 40 cm). The soil daily and cumulative evaporation decreased with the increase of sand burial thickness in MLS, cumulative evaporation decreased by 2.5%-13.7% compared with control. And evaporative inhibiting efficiency increased with sand burial thickness, evaporative inhibiting efficiency of 1-5 cm sand burial was 16.7%-79.0%. Final soil moisture content beneath the interface of sand burial increased with sand burial thickness, and it increased by 2.5%-13.7% than control. The topsoil EC of shifting sand in MLS decreased by 1.19-6.00 mS x cm(-1) with the increasing sand burial thickness, whereas soil salt content beneath the interface in MLS increased and amplitude of the topsoil salt content was higher than that of the subsoil. Under drip-irrigation with saline groundwater, average soil moisture beneath the interface of shifting sand burial increased by 0.4% -2.0% compare with control, and the highest value of EC was 7.77 mS x cm(-1) when the sand burial thickness was 10 cm. The trend of salt accumulation content at shifting sand surface increased firstly, and then decreased with the increasing sand burial thickness. Soil salt contents beneath the interface of shifting sand burial were much lower than that of shifting sand surface. 35 cm was the critical sand burial thickness for water-saving and salt restraint. In summary, sand burial had obvious inhibition effects on soil evaporation and salt accumulation, so maybe it could be used to save water and reduce salt accumulation in arid shifting desert areas.

Depositional environments of the Jurassic Maghara main coal seam in north central Sinai, Egypt

NASA Astrophysics Data System (ADS)

Edress, Nader Ahmed Ahmed; Opluštil, Stanislav; Sýkorová, Ivana

2018-04-01

Twenty-eight channel samples with a cumulative thickness of about 4 m collected from three sections of the Maghara main coal seam in the middle Jurassic Safa Formation have been studied for their lithotype and maceral compositions to reconstruct the character of peat swamp, its hydrological regime and the predominating type of vegetation. Lithotype composition is a combination of dully lithotypes with duroclarain (19% of total cumulative thickness), clarodurain (15%), black durain (15%), and shaly coal (15%) and bright lithotypes represented by clarain (23%), vitrain (12%) and a small proportion of wild fire-generated fusain (1%). Maceral analyses revealed the dominance of vitrinite (70.6% on average), followed by liptinite (25.2%) and inertinite (8.1%). Mineral matter content is ∼9% on average and consists of clay, quartz and pyrite concentrate mostly at the base and the roof of the seam. Dominantly vitrinite composition of coal and extremely low fire- and oxidation-borne inertinite content, together with high Gelification Indices imply predomination of waterlogged anoxic conditions in the precursing mire with water tables mostly above the peat surface throughout most of the time during peat swamp formation. Increases in collotelinite contents and Tissue Preservation Index up the section, followed by a reversal trend in upper third of the coal section, further accompanied by a reversal trend in collodetrinite, liptodetrinite, alginite, sporinite and clay contents records a transition from dominately limnotelmatic and limnic at the lower part to dominately limnotelmatic with increase telmatic condition achieved in the middle part of coal. At the upper part of coal seam an opposite trend marks the return to limnic and limnotelmatic conditions in the final phases of peat swamp history and its subsequent inundation. The proportion of arborescent (mostly coniferous) and herbaceous vegetation varied throughout the section of the coal with tendency of increasing density of arborescent vegetation to the middle part of the coal seam section. The intercalation of coal in shallow marine strata implies that peat swamp precursor formed in a coastal setting, probably on delta plain or lagoon. Its formation was controlled by water table changes driven by sea level fluctuations that created an accommodation space necessary for preservation of peat.

Eutrophic mire, its characteristics and modern conditions of peat genesis

NASA Astrophysics Data System (ADS)

Inisheva, L. I.; Golubina, O. A.; Zaplatnikova, Yu. D.; Dubrovskaya, L. I.

2009-04-01

The study of structure functional organization of Siberian mire ecosystems is the base of after-effects influence of their reclamation on global changes of biosphere. The aim of this investigation is to study the structure functional organization of eutrophic mire ecosystem "Tagan". Peat deposit "Tagan" (West Siberia, 20 kilometers near Tomsk) is situated on the second flood-plain terrace of the river Tom of ancient flow channel. Maximum power of peat deposit is 9.3 meters. Subsoil is made up from sand, more seldom from loamy sand and loam. Eutrophic vegetation covers almost the whole mire. It is presented by woody sedge, sedge, sedge-moss and grass undershrub phytocenoses. The oligotrophic vegetation is presented by Sphagnum pine cotton-grass phytocenosis. There were organized three observation points on the mire in 2007. They watched dynamics of hydrothermic, redox, biological, hydrochemical regimes. There were studied physicochemical properties at given points. Peats with normal ash basically refer to grass, woody grass group of lowland type. They are characterized by high degree of decomposition which is increased down deposit. Group composition of organic matters of investigated peats showed that bitumen content in peat changes from 1.4 to 3.56%, and humid acids content is within the limits of 16.67 - 44.34 %. Water-soluble and hardly-hydrolyzed matters are contained in quantity of 19.04 - 49.76% of the whole dry peat mass. The overall nitrogen content changes within the limits of 1.76 - 3.52%. It is presented mainly by fraction of unhydrolyzed nitrogen (72.07 - 95.67% of the whole nitrogen). Highly-hydrolyzed nitrogen is the most available reserve of mineral compound of nitrogen and its content changes within the limits of 0.18 - 4.79 of the overall nitrogen. 2008 year is characterized as an average year at conditions of moistening and heat providing. Investigations, made during this year, revealed the following results. Bog waters were kept at a surface level of 20 - 69cm in summer. Peat deposit heating up to 10˚ C was observed at a depth of 120cm. Oxidizing conditions are traced up to 40 - 60cm deep. There is gradual change into restoring conditions deep in peat deposit. Very reduction conditions are observed at a depth of 60cm. Weather conditions of 2008 year were favorable for biological processes activation. In the result of their manifestation hydrochemical composition of bog waters was formed. First of all, one should pay attention to weak alkaline reaction of bog waters. Calcium content in bog waters changes from 70.2 to 150.9 mg/l. One may state calcium removal from peat deposit of eutrophic mire into an outfall. The latter is the river which is flowing along the mire. Magnesium concentration in bog waters changed within the limits of 8.5 - 42.5 mg/l. It is important to note high content of iron in individual months - up to 17.8 mg/l. Organic matters content in bog waters, which are presented by humid acids (HA) and fulvic acids (FA), is HA 3.4 - 24.65 mg/l, FA 11.0 - 58.3 mg/l. Let's, first of all, examine dynamics of individual components in bog waters. Thus, content of calcium, water-soluble carbon, and fulvic acids naturally increased in July, when it was marked combination of high temperature and minor precipitation. Active iron in bog waters had the highest concentration in spring which had gradually decreased by September (from 18 and 8 mg/l to 0.1 mg/l). Preliminary obtained results reveal bog drainage occurring at present. It is followed also from the fact that there are favorable redox conditions in a meter layer of peat deposit and high degree of peats decomposition. The examination of dynamics of hydrothermic, biological and hydrochemical regimes also is evidence of biological processes activity in eutrophic mire "Tagan". This fact, in its turn, influences on hydrochemical compound formation of bog waters.

Effect of inter-row cultivation on soil CO2 emission in a peach plantation

NASA Astrophysics Data System (ADS)

Tóth, E.; Farkas, Cs.; Gelybó, Gy.; Lagzi, I.

2012-04-01

We examined the effect of inter-row cultivation on soil CO2 emission in a peach plantation planted in 1991. The soil is Ramann type brown forest soil /Mollic Cambisol/ developed on sandy loam. Every second row in the orchard is covered with undisturbed grass, and every other row is disked (depth: 12-15cm) with a two-three-week frequency. The humus content varies from 1,69% to 2,28% in the upper 20 cm layer, where the sand, loam and clay contents are 58%, 21% and 19 %, respectively. The average annual precipitation total is 570 mm (330 mm for the growing season) at the site. During the vegetation period of 2009 soil CO2 emission measurements were carried out with static chamber method in the differently managed rows. Parallel with CO2 measurements soil volumetric water content and soil temperature were also determined. Soil microbiological properties water-extractable organic carbon (WEOC) and water-extractable nitrogen (WEN) as well as substrate-induced respiration (SIR) were determined from disturbed soil samples collected on the first measurement day. The measured soil physical properties showed that different soil management practices influence soil water content, bulk density and soil temperature as well. Soil water content was higher in the grass covered row on 10 of the 13 measurement days, the difference - which reached 10 v% - was the highest on the warmest days. Soil temperature is also different in case of disked and grass covered rows, found to be lower in the grass covered rows on every measurement days. SIR, WEOC and WEN were all higher in the grass covered row (19.45 μg CO2-C g-1 soil 36.91 μg g-1 soil, 139.36 μg g-1 soil, respectively) than in the disked row (4.88 μg CO2-C g-1 soil 25.43 μg C g-1 soil, 61.25 μg N g-1 soil, respectively) in 2009. Soil CO2 emission also differed between the two rows, grass covered rows produced higher emission in all measurements days without exemption. The difference between CO2 fluxes from the two cultivation methods were found to be statistically significant (p = 0.05) on each measurement day, except for the two driest days according to soil water content data. Nevertheless, soil emission data from the grass covered rows are more scattered due to the greater spatiotemporal variability in the lack of disturbance. Homogenization is a well known consequence of cultivation, which explains the moderate variation of emission in the disked row.

Spatio-temporal variability of soil water content on the local scale in a Mediterranean mountain area (Vallcebre, North Eastern Spain). How different spatio-temporal scales reflect mean soil water content

NASA Astrophysics Data System (ADS)

Molina, Antonio J.; Latron, Jérôme; Rubio, Carles M.; Gallart, Francesc; Llorens, Pilar

2014-08-01

As a result of complex human-land interactions and topographic variability, many Mediterranean mountain catchments are covered by agricultural terraces that have locally modified the soil water content dynamic. Understanding these local-scale dynamics helps us grasp better how hydrology behaves on the catchment scale. Thus, this study examined soil water content variability in the upper 30 cm of the soil on a Mediterranean abandoned terrace in north-east Spain. Using a dataset of high spatial (regular grid of 128 automatic TDR probes at 2.5 m intervals) and temporal (20-min time step) resolution, gathered throughout a 84-day period, the spatio-temporal variability of soil water content at the local scale and the way that different spatio-temporal scales reflect the mean soil water content were investigated. Soil water content spatial variability and its relation to wetness conditions were examined, along with the spatial structuring of the soil water content within the terrace. Then, the ability of single probes and of different combinations of spatial measurements (transects and grids) to provide a good estimate of mean soil water content on the terrace scale was explored by means of temporal stability analyses. Finally, the effect of monitoring frequency on the magnitude of detectable daily soil water content variations was studied. Results showed that soil water content spatial variability followed a bimodal pattern of increasing absolute variability with increasing soil water content. In addition, a linear trend of decreasing soil water content as the distance from the inner part of the terrace increased was identified. Once this trend was subtracted, resulting semi-variograms suggested that the spatial resolution examined was too high to appreciate spatial structuring in the data. Thus, the spatial pattern should be considered as random. Of all the spatial designs tested, the 10 × 10 m mesh grid (9 probes) was considered the most suitable option for a good, time-stable estimate of mean soil water content, as no improvement was obtained with the 5 × 5 m mesh grid (30 probes). Finally, the results of temporal aggregation showed that decreasing the monitoring frequency down to 8 h during wetting-up periods and to 1 day during drying-down ones did not result in a loss of information on daily soil water content variations.

Experimental and numerical study on thermal conductivity of partially saturated unconsolidated sands

NASA Astrophysics Data System (ADS)

Lee, Youngmin; Keehm, Youngseuk; Kim, Seong-Kyun; Shin, Sang Ho

2016-04-01

A class of problems in heat flow applications requires an understanding of how water saturation affects thermal conductivity in the shallow subsurface. We conducted a series of experiments using a sand box to evaluate thermal conductivity (TC) of partially saturated unconsolidated sands under varying water saturation (Sw). We first saturated sands fully with water and varied water saturation by drainage through the bottom of the sand box. Five water-content sensors were integrated vertically into the sand box to monitor water saturation changes and a needle probe was embedded to measure thermal conductivity of partially saturated sands. The experimental result showed that thermal conductivity decreases from 2.5 W/mK for fully saturated sands to 0.7 W/mK when water saturation is 5%. We found that the decreasing trend is quite non-linear: highly sensitive at very high and low water saturations. However, the boundary effects on the top and the bottom of the sand box seemed to be responsible for this high nonlinearity. We also found that the determination of water saturation is quite important: the saturation by averaging values from all five sensors and that from the sensor at the center position, showed quite different trends in the TC-Sw domain. In parallel, we conducted a pore-scale numerical modeling, which consists of the steady-state two-phase Lattice-Boltzmann simulator and FEM thermal conduction simulator on digital pore geometry of sand aggregation. The simulation results showed a monotonous decreasing trend, and are reasonably well matched with experimental data when using average water saturations. We concluded that thermal conductivity would decrease smoothly as water saturation decreases if we can exclude boundary effects. However, in dynamic conditions, i.e. imbibition or drainage, the thermal conductivity might show hysteresis, which can be investigated with pore-scale numerical modeling with unsteady-state two-phase flow simulators in our future work.

Fluoride content and distribution pattern in groundwater of eastern Yunnan and western Guizhou, China.

PubMed

Luo, Kunli; Liu, Yonglin; Li, Huijie

2012-02-01

For study, the fluoride (F) content and distribution pattern in groundwater of eastern Yunnan and western Guizhou fluorosis area in southwestern China, the F content of 93 water samples [groundwater (fissure water, cool spring, and hot springs), rivers water] and 60 rock samples were measured. The result shows the F content of the fissure water and cold spring water is 0.027-0.47 mg/L, and river water is 0.048-0.224 mg/L. The F content of hot spring water is 1.02-6.907 mg/L. The drinking water supplied for local resident is mainly from fissure water, cool spring, and river water. And the F content in all of them is much lower than the Chinese National Standard (1.0 mg/L), which is the safe intake of F in drinking water. The infected people in eastern Yunnan and western Guizhou fluorosis area have very little F intake from the drinking water. The hot spring water in fluorosis area of eastern Yunnan and western Guizhou, southwest China has high F content, which is not suitable for drinking. © Springer Science+Business Media B.V. 2011

Optimization of the omega-3 extraction as a functional food from flaxseed.

PubMed

Hassan-Zadeh, A; Sahari, M A; Barzegar, M

2008-09-01

The fatty acid content, total lipid, refractive index, peroxide, iodine, acid and saponification values of Iranian linseed oil (Linum usitatissimum) were studied. For optimization of extraction conditions, this oil was extracted by solvents (petroleum benzene and methanol-water-petroleum benzene) in 1:2, 1:3 and 1:4 ratios at 2, 5 and 8 h. Then its fatty acid content, omega-3 content and extraction yield were determined. According to the statistical analysis, petroleum benzene in a ratio of 1:3 at 5 h was chosen for the higher fatty acid, extraction yield, and economical feasibility. For preservation of omega-3 ingredients, oil with specified characters containing 46.8% omega-3 was kept under a nitrogen atmosphere at -30 degrees C during 0, 7, 30, 60 and 90 days and its peroxide value was determined. Statistical analysis showed a significant difference in the average amount of peroxide value only on the first 7 days of storage, and its increase (8.30%) conformed to the international standard.

Effect of water content on stability of landslides triggered by earthquakes

NASA Astrophysics Data System (ADS)

Beyabanaki, S.; Bagtzoglou, A. C.; Anagnostou, E. N.

2013-12-01

Earthquake- triggered landslides are one of the most important natural hazards that often result in serious structural damage and loss of life. They are widely studied by several researchers. However, less attention has been focused on soil water content. Although the effect of water content has been widely studied for rainfall- triggered landslides [1], much less attention has been given to it for stability analysis of earthquake- triggered landslides. We developed a combined hydrology and stability model to investigate effect of soil water content on earthquake-triggered landslides. For this purpose, Bishop's method is used to do the slope stability analysis and Richard's equation is employed to model infiltration. Bishop's method is one the most widely methods used for analyzing stability of slopes [2]. Earthquake acceleration coefficient (EAC) is also considered in the model to analyze the effect of earthquake on slope stability. Also, this model is able to automatically determine geometry of the potential landslide. In this study, slopes with different initial water contents are simulated. First, the simulation is performed in the case of earthquake only with different EACs and water contents. As shown in Fig. 1, initial water content has a significant effect on factor of safety (FS). Greater initial water contents lead to less FS. This impact is more significant when EAC is small. Also, when initial water content is high, landslides can happen even with small earthquake accelerations. Moreover, in this study, effect of water content on geometry of landslides is investigated. For this purpose, different cases of landslides triggered by earthquakes only and both rainfall and earthquake for different initial water contents are simulated. The results show that water content has more significant effect on geometry of landslides triggered by rainfall than those triggered by an earthquake. Finally, effect of water content on landslides triggered by earthquakes during rainfall is investigated. In this study, after different durations of rainfall, an earthquake is applied to the model and the elapsed time in which the FS gets less than one obtains by trial and error. The results for different initial water contents and earthquake acceleration coefficients show that landslides can happen after shorter rainfall duration when water content is greater. If water content is high enough, the landslide occurs even without rainfall. References [1] Ray RL, Jacobs JM, de Alba P. Impact of unsaturated zone soil moisture and groundwater table on slope instability. J. Geotech. Geoenviron. Eng., 2010, 136(10):1448-1458. [2] Das B. Principles of Foundation Engineering. Stanford, Cengage Learning, 2011. Fig. 1. Effect of initial water content on FS for different EACs

Cycling of Volatiles and Stable Isotopes During High-P Subduction Dehydration of Serpentinite

NASA Astrophysics Data System (ADS)

Alt, J.; Garrido, C. J.; Shanks, W. C.; Turchyn, A. V.; López-Sánchez-Vizcaíno, V.; Gómez-Pugnaire, M.

2009-12-01

We present volatile contents and stable isotope compositions of high-P antigorite serpentinites and their chlorite-harzburgite dehydration products from the Cerro del Almirez complex, Spain. The serpentinites are former Tethyan seafoor consisting of antigorite with olivine, diopside, chlorite, magnetite, tremolite, and Ti-clinohumite, dehydrated to chlorite-harzburites comprising spinifex-like olivine + orthopyroxene, with chlorite, tremolite, and magnetite, at T> 650°C and P>2 GPa. The serpentinites have elevated H2O, S, and C contents, averaging (n=10) 1000 ppm S and 10 wt% H2O, and with 180-1280 ppm total C. Bulk δ18O values of 7.9-9.1‰ and δD= -49 to -61‰ are consistent with serpentinization by seawater at 50-100°C. The high sulfide contents and preliminary δ34S analyses of ~10‰ likely reflect microbial reduction of seawater sulfate, and δ13C (total C) values of -10.9 to -20.2‰ are consistent with the presence of an organic carbon component. These data and processes are similar to those for modern seafloor serpentinites. High-P dehydration of the serpentinites resulted in loss of about half of their H2O and S: chlorite-harzburgites (n=11) average 5.7 wt% H2O and 610 ppm S. The δ34S (-5.1 to 10.2‰) and δ18O (6.4-9.5‰) of the metamorphic harzburgites are unchanged from serpentinite, but hydrogen isotopes are fractionated during dehydration, from serpentinite δD values around -55‰ to chlorite-harzburgite values of ~ -70 to -90‰. Carbon contents and δ13C values of the two rock types overlap, with a broad trend of decreasing C contents and δ13C, from ~1200 to 200 ppm and -9.6 to -20.3‰, perhaps reflecting loss of CO2. Our results indicate: 1) significant uptake of H2O, S and C during serpentinization on the seafloor; 2) that recycling of serpentinites to high P and T results in loss of isotopically fractionated sulfur, water and possibly carbon to the sub-arc mantle; and 3) that fractionated sulfur, water and carbon in serpentinite dehydration products can be recycled into the mantle where they can contribute to isotope heterogeneities.

[Development and succession of artificial biological soil crusts and water holding characteristics of topsoil].

PubMed

Wu, Li; Chen, Xiao-Guo; Zhang, Gao-Ke; Lan, Shu-Bin; Zhang, De-Lu; Hu, Chun-Xiang

2014-03-01

In order to understand the improving effects of cyanobacterial inoculation on water retention of topsoil in desert regions, this work focused on the development and succession of biological soil crusts and water holding characteristics of topsoil after cyanobacterial inoculation in Qubqi Desert. The results showed that after the artificial inoculation of desert cyanobacteria, algal crusts were quickly formed, and in some microenvironments direct succession of the algal crusts to moss crusts occurred after 2-3 years. With the development and succession of biological soil crusts, the topsoil biomass, polysaccharides content, crust thickness and porosity increased, while the soil bulk density decreased. At the same time, with crust development and succession, the topsoil texture became finer and the percents of fine soil particles including silt and clay contents increased, while the percents of coarse soil particles (sand content) decreased proportionately. In addition, it was found that with crust development and succession, the water holding capacity and water content of topsoil showed an increasing trend, namely: moss crust > algal crusts > shifting sand. The water content (or water holding capacity) in algal and moss crusts were 1.1-1.3 and 1.8-2.2 times of those in shifting sand, respectively. Correlation analysis showed that the water holding capacity and water content of topsoil were positively correlated with the crust biomass, polysaccharides content, thickness, bulk density, silt and clay content; while negatively correlated with the porosity and sand content. Furthermore, stepwise regression analysis showed that the main factor affecting water content was the clay content, while that affecting water holding capacity was the porosity.

[Effects of field border length for irrigation on photosynthetic characteristics, dry matter accumulation and water use efficiency of wheat].

PubMed

Ma, Shang-Yu; Yu, Zhen-Wen; Shi, Yu; Zhao, Jun-Ye; Zhang, Yong-Li

2014-04-01

With the high-yielding winter wheat cultivar Jimai 22 as test material, a three-year field experiment was conducted to examine the effects of border length for irrigation on flag leaf water potential, photosynthetic characteristics, dry matter accumulation and distribution of wheat. In the 2010-2011 growing season, six treatments were installed, i. e., the field border length was designed as 10 m (L10), 20 m (L20), 40 m (L40), 60 m (L60), 80 m (L80) and 100 m (L100). In the 2011-2012 and 2012-2013 growing seasons, the field border length was designed as 40 m (L40), 60 m (L60), 80 m (L80) and 100 m (L100). The results showed that the average relative soil water content of the 0-200 cm soil layer was presented as L80, L60>L100>L40>L20>L10 at anthesis in the 2010-2011 growing season and as L80, L60>L100>L40 in the 2011-2012 and 2012-2013 growing seasons. At 11 d and 21 d after anthesis, the water potential, net photosynthetic rate and transpiration rate of flag leaf were presented as L80, L100>L60>L40>L20, L10, and as L80>L60, L100>L40, L20, L10 at 31 d after anthesis. The coefficients of variability both of the dry matter accumulation at anthesis and maturity and of grain yield in different regions of L80 field were lower than those of L100. The average dry matter accumulation, dry matter accumulation after anthesis and the contribution to grain of L80 were dramatically higher than those of L100, L40, L20 and L10. L80 had the highest average grain yield and water use efficiency, being the best treatment for irrigation in our study.

Fungal Endophyte (Epichloë festucae) Alters the Nutrient Content of Festuca rubra Regardless of Water Availability

PubMed Central

Vázquez-de-Aldana, Beatriz R.; García-Ciudad, Antonia; García-Criado, Balbino; Vicente-Tavera, Santiago; Zabalgogeazcoa, Iñigo

2013-01-01

Festuca rubra plants maintain associations with the vertically transmitted fungal endophyte Epichloë festucae. A high prevalence of infected host plants in semiarid grasslands suggests that this association could be mutualistic. We investigated if the Epichloë-endophyte affects the growth and nutrient content of F. rubra plants subjected to drought. Endophyte-infected (E+) and non-infected (E−) plants of two half-sib lines (PEN and RAB) were subjected to three water availability treatments. Shoot and root biomass, nutrient content, proline, phenolic compounds and fungal alkaloids were measured after the treatments. The effect of the endophyte on shoot and root biomass and dead leaves depended on the plant line. In the PEN line, E+ plants had a greater S:R ratio than E-, but the opposite occurred in RAB. In both plant lines and all water treatments, endophyte-infected plants had greater concentrations of N, P and Zn in shoots and Ca, Mg and Zn in roots than E- plants. On average, E+ plants contained in their shoots more P (62%), Zn (58%) and N (19%) than E- plants. While the proline in shoots increased in response to water stress, the endophyte did not affect this response. A multivariate analysis showed that endophyte status and plant line impose stronger differences in the performance of the plants than the water stress treatments. Furthermore, differences between PEN and RAB lines seemed to be greater in E- than in E+ plants, suggesting that E+ plants of both lines are more similar than those of their non-infected version. This is probably due to the endophyte producing a similar effect in both plant lines, such as the increase in N, P and Zn in shoots. The remarkable effect of the endophyte in the nutrient balance of the plants could help to explain the high prevalence of infected plants in natural grasslands. PMID:24367672

Remote biopsy darting and marking of polar bears

USGS Publications Warehouse

Pagano, Anthony M.; Peacock, Elizabeth; McKinney, Melissa A.

2014-01-01

Remote biopsy darting of polar bears (Ursus maritimus) is less invasive and time intensive than physical capture and is therefore useful when capture is challenging or unsafe. We worked with two manufacturers to develop a combination biopsy and marking dart for use on polar bears. We had an 80% success rate of collecting a tissue sample with a single biopsy dart and collected tissue samples from 143 polar bears on land, in water, and on sea ice. Dye marks ensured that 96% of the bears were not resampled during the same sampling period, and we recovered 96% of the darts fired. Biopsy heads with 5 mm diameters collected an average of 0.12 g of fur, tissue, and subcutaneous adipose tissue, while biopsy heads with 7 mm diameters collected an average of 0.32 g. Tissue samples were 99.3% successful (142 of 143 samples) in providing a genetic and sex identification of individuals. We had a 64% success rate collecting adipose tissue and we successfully examined fatty acid signatures in all adipose samples. Adipose lipid content values were lower compared to values from immobilized or harvested polar bears, indicating that our method was not suitable for quantifying adipose lipid content.

Evapotranspiration and microclimate at a low-level radioactive-waste disposal site in northwestern Illinois

USGS Publications Warehouse

Healy, R.W.; DeVries, M.P.; Sturrock, Alex M.

1989-01-01

From July 1982 through June 1984, a study was made of the evapotranspiration and microclimate at a low-level radioactive-waste disposal site near Sheffield, Bureau County, Illinois. Vegetation at the site consists of mixed pasture grasses, primarily awnless brome (Bromus inermis) and red clover (Trifoleum pratense). Three methods were used to estimate evapotranspiration: (1) an energy budget with the Bowen ratio, (2) an aerodynamic profile, and (3) a soil-based water budget. For the aerodynamic-profile method, sensible-heat flux was estimated by a profile equation and evapotranspiration was then calculated as the residual in the energy-balance equation. Estimates by the energy-budget and aerodynamic-profile methods were computed from hourly data and then summed by days and months. Yearly estimates (for March through November) by these methods were in close agreement: 648 and 626 millimeters, respectively. Daily estimates reach a maximum of about 6 millimeters. The water-budget method produced only monthly estimates based on weekly or biweekly soil-moisture content measurements. The yearly evapotranspiration estimated by this method (which actually included only the months of April through October) was 655 millimeters. The March-through-November average for the three methods of 657 millimeters was equivalent to 70 percent of total precipitation. Continuous measurements were made of incoming and reflected shortwave radiation, incoming and emitted longwave radiation, net radiation, soil-heat flux, soil temperature, horizontal windspeed, and wet- and dry-bulb air temperature. Windspeed and air temperature were measured at heights of 0.5 and 2.0 meters (and also at 1.0 meter after September 1983). Soilmoisture content of the soil zone was measured with a gamma-attenuation gage. Annual precipitation (938 millimeters) and average temperature (10.8 degrees Celsius) at the Sheffield site were virtually identical to long-term averages from nearby National Weather Service stations. Solar radiation averaged 65 percent of that normally expected under clear skies. Net radiation averaged 70.1 watts per square meter and was highest in July and negative during some winter months. Wind direction varied but was predominately south-southeasterly. Wind speed at the 2-meter height averaged 3.5 meters per second and was slightly higher in winter months than the rest of the year. The amount of water stored within the soil zone was greatest in early spring and least in late summer. Seasonal and diurnal trends of evapotranspiration rates mirrored those of net radiation; July was usually the month with the highest evapotranspiration rate. The ratio of sensible- to latentheat fluxes (commonly called the Bowen ratio) for the 2-year study period was 0.38, as averaged from the three methods. Monthly Bowen ratios fluctuated somewhat but averaged about 0.35 for late spring through summer. In fall, the ratio declined to zero or to slightly negative values. When the ratio was negative, the latent-heat flux was slightly greater than the net radiation because of additional energy supplied by' the cooling soil and air. Evapotranspiration calculated by the three methods averaged 75 percent of potential evapotranspiration, as estimated by the Penman equation. There was no apparent seasonal trend in the relation between actual and potential evapotranspiration rates.

Atmospheric partitioning and the air-water exchange of polycyclic aromatic hydrocarbons in a large shallow Chinese lake (Lake Chaohu).

PubMed

Qin, Ning; He, Wei; Kong, Xiang-Zhen; Liu, Wen-Xiu; He, Qi-Shuang; Yang, Bin; Ouyang, Hui-Ling; Wang, Qing-Mei; Xu, Fu-Liu

2013-11-01

The residual levels of polycyclic aromatic hydrocarbons (PAHs) in the atmosphere and in dissolved phase from Lake Chaohu were measured by (GC-MS). The composition and seasonal variation were investigated. The diffusive air-water exchange flux was estimated by a two-film model, and the uncertainty in the flux calculations and the sensitivity of the parameters were evaluated. The following results were obtained: (1) the average residual levels of all PAHs (PAH16) in the atmosphere from Lake Chaohu were 60.85±46.17 ng m(-3) in the gaseous phase and 14.32±23.82 ng m(-3) in the particulate phase. The dissolved PAH16 level was 173.46±132.89 ng L(-1). (2) The seasonal variation of average PAH16 contents ranged from 43.09±33.20 ng m(-3) (summer) to 137.47±41.69 ng m(-3) (winter) in gaseous phase, from 6.62±2.72 ng m(-3) (summer) to 56.13±22.99 ng m(-3) (winter) in particulate phase, and 142.68±74.68 ng L(-1) (winter) to 360.00±176.60 ng L(-1) (summer) in water samples. Obvious seasonal trends of PAH16 concentrations were found in the atmosphere and water. The values of PAH16 for both the atmosphere and the water were significantly correlated with temperature. (3) The monthly diffusive air-water exchange flux of total PAH16 ranged from -1.77×10(4) ng m(-2) d(-1) to 1.11×10(5) ng m(-2) d(-1), with an average value of 3.45×10(4) ng m(-2) d(-1). (4) The results of a Monte Carlo simulation showed that the monthly average PAH fluxes ranged from -3.4×10(3) ng m(-2) d(-1) to 1.6×10(4) ng m(-2) d(-1) throughout the year, and the uncertainties for individual PAHs were compared. (5) According to the sensitivity analysis, the concentrations of dissolved and gaseous phase PAHs were the two most important factors affecting the results of the flux calculations. Copyright © 2013 Elsevier Ltd. All rights reserved.

Spatial and temporal distribution patterns of benthic foraminifera in the Northeast Water Polynya, Greenland

NASA Astrophysics Data System (ADS)

Ahrens, Michael J.; Graf, Gerhard; Altenbach, Alexander V.

1997-01-01

Abundance, biofacies and ATP content of benthic foraminifera (>63 μm) were studied in the Northeast Water (NEW) Polynya (77-81°N, 5-17°W) over the ice-free summer, 1993, to investigate how a polynya system might influence the underlying benthic community. In the living assemblage, distinguished by Rose Bengal staining, over 60 taxa could be identified. The biofacies identified was similar to that of other Arctic shelf habitats. Foraminifera were counted in 3 size fractions (63-125 μm, 125-250 μm and >250 μm), with 65% of the foraminifera occurring in the smallest size fraction (63-125 μm). Total abundances (>63 μm) in the uppermost 1 cm averaged approximately 200 ind/10 cm 3 and declined down-core, as did the number of species. Abundances and species composition correlated positively with sediment chlorophyll and ATP content, with maxima occurring in the shallower northern regions of the polynya, suggesting a general dependence on food. Foraminera biomass was estimated to be 0.1-0.3 g C org/m 2. Abundances, biomass and ATP content were comparable to ice-free, deep-sea regions in the Norwegian Sea. Temporal changes observed over a 2 month period at one location were difficult to distinguish from spatial and analytical variability. Contrary to expectations, growth was unpronounced at the community and at a species level, implying either a delayed response of the benthic foraminiferal community to food inputs from the overlying water column or the presence of biological limitations other than food, such as predation.

A Self-Powered and Autonomous Fringing Field Capacitive Sensor Integrated into a Micro Sprinkler Spinner to Measure Soil Water Content.

PubMed

da Costa, Eduardo Ferreira; de Oliveira, Nestor E; Morais, Flávio J O; Carvalhaes-Dias, Pedro; Duarte, Luis Fernando C; Cabot, Andreu; Siqueira Dias, J A

2017-03-12

We present here the design and fabrication of a self-powered and autonomous fringing field capacitive sensor to measure soil water content. The sensor is manufactured using a conventional printed circuit board and includes a porous ceramic. To read the sensor, we use a circuit that includes a 10 kHz triangle wave generator, an AC amplifier, a precision rectifier and a microcontroller. In terms of performance, the sensor's capacitance (measured in a laboratory prototype) increases up to 5% when the volumetric water content of the porous ceramic changed from 3% to 36%, resulting in a sensitivity of S = 15.5 pF per unity change. Repeatability tests for capacitance measurement showed that the θ v sensor's root mean square error is 0.13%. The average current consumption of the system (sensor and signal conditioning circuit) is less than 1.5 μ A, which demonstrates its suitability for being powered by energy harvesting systems. We developed a complete irrigation control system that integrates the sensor, an energy harvesting module composed of a microgenerator installed on the top of a micro sprinkler spinner, and a DC/DC converter circuit that charges a 1 F supercapacitor. The energy harvesting module operates only when the micro sprinkler spinner is irrigating the soil, and the supercapacitor is fully charged to 5 V in about 3 h during the first irrigation. After the first irrigation, with the supercap fully charged, the system can operate powered only by the supercapacitor for approximately 23 days, without any energy being harvested.

A Self-Powered and Autonomous Fringing Field Capacitive Sensor Integrated into a Micro Sprinkler Spinner to Measure Soil Water Content

PubMed Central

da Costa, Eduardo Ferreira; de Oliveira, Nestor E.; Morais, Flávio J. O.; Carvalhaes-Dias, Pedro; Duarte, Luis Fernando C.; Cabot, Andreu; Siqueira Dias, J. A.

2017-01-01

We present here the design and fabrication of a self-powered and autonomous fringing field capacitive sensor to measure soil water content. The sensor is manufactured using a conventional printed circuit board and includes a porous ceramic. To read the sensor, we use a circuit that includes a 10 kHz triangle wave generator, an AC amplifier, a precision rectifier and a microcontroller. In terms of performance, the sensor’s capacitance (measured in a laboratory prototype) increases up to 5% when the volumetric water content of the porous ceramic changed from 3% to 36%, resulting in a sensitivity of S=15.5 pF per unity change. Repeatability tests for capacitance measurement showed that the θv sensor’s root mean square error is 0.13%. The average current consumption of the system (sensor and signal conditioning circuit) is less than 1.5 μA, which demonstrates its suitability for being powered by energy harvesting systems. We developed a complete irrigation control system that integrates the sensor, an energy harvesting module composed of a microgenerator installed on the top of a micro sprinkler spinner, and a DC/DC converter circuit that charges a 1 F supercapacitor. The energy harvesting module operates only when the micro sprinkler spinner is irrigating the soil, and the supercapacitor is fully charged to 5 V in about 3 h during the first irrigation. After the first irrigation, with the supercap fully charged, the system can operate powered only by the supercapacitor for approximately 23 days, without any energy being harvested. PMID:28287495

Applying petrophysical models to radar travel time and electrical resistivity tomograms: Resolution-dependent limitations

USGS Publications Warehouse

Day-Lewis, F. D.; Singha, K.; Binley, A.M.

2005-01-01

Geophysical imaging has traditionally provided qualitative information about geologic structure; however, there is increasing interest in using petrophysical models to convert tomograms to quantitative estimates of hydrogeologic, mechanical, or geochemical parameters of interest (e.g., permeability, porosity, water content, and salinity). Unfortunately, petrophysical estimation based on tomograms is complicated by limited and variable image resolution, which depends on (1) measurement physics (e.g., electrical conduction or electromagnetic wave propagation), (2) parameterization and regularization, (3) measurement error, and (4) spatial variability. We present a framework to predict how core-scale relations between geophysical properties and hydrologic parameters are altered by the inversion, which produces smoothly varying pixel-scale estimates. We refer to this loss of information as "correlation loss." Our approach upscales the core-scale relation to the pixel scale using the model resolution matrix from the inversion, random field averaging, and spatial statistics of the geophysical property. Synthetic examples evaluate the utility of radar travel time tomography (RTT) and electrical-resistivity tomography (ERT) for estimating water content. This work provides (1) a framework to assess tomograms for geologic parameter estimation and (2) insights into the different patterns of correlation loss for ERT and RTT. Whereas ERT generally performs better near boreholes, RTT performs better in the interwell region. Application of petrophysical models to the tomograms in our examples would yield misleading estimates of water content. Although the examples presented illustrate the problem of correlation loss in the context of near-surface geophysical imaging, our results have clear implications for quantitative analysis of tomograms for diverse geoscience applications. Copyright 2005 by the American Geophysical Union.

Low-field NMR logging sensor for measuring hydraulic parameters of model soils

NASA Astrophysics Data System (ADS)

Sucre, Oscar; Pohlmeier, Andreas; Minière, Adrien; Blümich, Bernhard

2011-08-01

SummaryKnowing the exact hydraulic parameters of soils is very important for improving water management in agriculture and for the refinement of climate models. Up to now, however, the investigation of such parameters has required applying two techniques simultaneously which is time-consuming and invasive. Thus, the objective of this current study is to present only one technique, i.e., a new non-invasive method to measure hydraulic parameters of model soils by using low-field nuclear magnetic resonance (NMR). Hereby, two model clay or sandy soils were respectively filled in a 2 m-long acetate column having an integrated PVC tube. After the soils were completely saturated with water, a low-field NMR sensor was moved up and down in the PVC tube to quantitatively measure along the whole column the initial water content of each soil sample. Thereafter, both columns were allowed to drain. Meanwhile, the NMR sensor was set at a certain depth to measure the water content of that soil slice. Once the hydraulic equilibrium was reached in each of the two columns, a final moisture profile was taken along the whole column. Three curves were subsequently generated accordingly: (1) the initial moisture profile, (2) the evolution curve of the moisture depletion at that particular depth, and (3) the final moisture profile. All three curves were then inverse analyzed using a MATLAB code over numerical data produced with the van Genuchten-Mualem model. Hereby, a set of values ( α, n, θr and θs) was found for the hydraulic parameters for the soils under research. Additionally, the complete decaying NMR signal could be analyzed through Inverse Laplace Transformation and averaged on the 1/ T2 space. Through measurement of the decay in pure water, the effect on the relaxation caused by the sample could be estimated from the obtained spectra. The migration of the sample-related average <1/ T2, Sample> with decreasing saturation speaks for a enhancement of the surface relaxation as the soil dries, in concordance with results found by other authors. In conclusion, this low-field mobile NMR technique has proven itself to be a fast and a non-invasive mean to investigate the hydraulic behavior of soils and to explore microscopical aspect of the water retained in them. In the future, the sensor should allow easy soil moisture measurements on-field.

Solar energy dryer kinetics using flat-plate finned collector and forced convection for potato drying

NASA Astrophysics Data System (ADS)

Batubara, Fatimah; Misran, Erni; Dina, Sari Farah; Heppy

2017-06-01

Research on potato drying using the indirect solar dryer with flat-plate finned collector and forced convection has been done. The research was conducted at the outdoor field of Laboratory of Institute for Research and Standardization of Industry on June 14th-23rd, 2016 from 9:00 am to 4:00 pm. This research aims to obtain the drying kinetics model of potato (Solanumtuberosum L.) using an indirect solar dryer's (ISD) with flat plate-finned collector and forced convection. The result will be compared to the open sun drying (OSD) method. Weather conditions during the drying process took place as follows; surrounding air temperature was in the range 27 to 34.7 °C, relative humidity (RH) 29.5 to 61.0% and the intensity of solar radiation 105.6 to 863.1 Watt/m2. The dried potato thicknesses were 1.0 cm, 1.5 cm and 2.0 cm, with the average initial water content of 76.46%. The average temperature in the collector chamber ranged from 42.2 to 57.4 °C and the drying chamber was at 46.2 °C. The best drying result was obtained from a sample size of 1 cm thickness using the IDS method with an average drying rate of 0.018 kg H2O per kg dry-weight.hour and the water content was constant at 5.02% in 21 hours of drying time. The most suitable kinetics model is Page model, equation MR = exp (-0.049 t1,336) for 1.0 cm thickness, exp (-0.066 t1,222) for 1.5 cm thickness and exp (-0.049 t1,221) for 2.0 cm thickness. The quality of potato drying using ISD method is better than using OSD which can be seen from the color produced.

Effect of mismanagement at the state of organic matter in soil

NASA Astrophysics Data System (ADS)

Hladký, Jan; Elbl, Jakub; Kynický, Jindřich; Dvořáčková, Helena; Juřička, David; Pecina, Václav; Brtnický, Martin

2017-04-01

Organic matter is an essential part of the soil. It affects the physical, chemical, and biological properties of the soil. It is therefore necessary to maintain organic matter in the soil and its quality as the prevention of soil degradation. Loss of organic matter is in the Czech Republic threatened up to 45% of arable soil. The most important reason for the loss of organic matter in the soil is poor management, especially improper crop rotation, cultivation of erosion-prone crops where erosion takes away valuable topsoil with nutrients and organic matter. The aim of our study was to verify the influence of inappropriate management on selected 5 plots in southern Moravia in the Czech Republic. It is the region with the highest incidence of water erosion in the Czech Republic. Were selected plots with significantly sloping, where corn was grown. Samples were taken in the autumn after the harvest, each of topsoil. The sampling sites were placed in positions on the slope where soil was not damaged by erosion, as well as the place greatest damage and the place where washed soil was accumulated. Soil average humus content was for undamaged position on the slope 1.93% and 0.84 quality, the most heavily damaged part of the slope humus content dropped to 1.35% and its quality at only 0.56. In the case of position of accumulated soils was found the average amount of humus 1.70% and 0.90 quality. Humus content and its quality is statistically significantly influenced by water erosion (α = 0.05). The study showed that bad management, when there is not crop rotation adapted to the given conditions and not subjected to any suitable soil-protecting technologies, there is significant damage to soils, which shows mainly organic matter decline and a decline in its quality. Continuation of our study will verify the possibility of stabilization of soil organic matter and draft appropriate technologies.

Nutritional Evaluation of Distillery Sludge and Its Effect as a Substitute of Canola Meal on Performance of Broiler Chickens

PubMed Central

Sharif, M.; Shahzad, M. A.; Rehman, S.; Khan, S.; Ali, R.; Khan, M. L.; Khan, K.

2012-01-01

The study was conducted to investigate the chemical composition of distillery yeast sludge and its inclusion in broiler diets to replace canola meal. Raw distillery yeast sludge was washed with water using water and sludge in the ratio 6:1, respectively. Proximate analysis of raw distillery yeast sludge and washed distillery sludge was carried out for crude protein (CP), true protein (TP), ether extract (EE), ash, acid insoluble ash and nitrogen free extract (NFE) determination. Mineral contents and amino acid profile of raw distillery yeast sludge and washed distillery sludge were also determined. After chemical evaluation, four iso-caloric and iso-nitrogenous broiler starter and finisher diets were prepared in mash form using 0 (control), 4, 8 and 12% levels of washed distillery sludge replacing canola meal. One hundred and twenty day-old broiler chicks were randomly distributed into 12 experimental units in such a way that each diet was offered to three experimental units, each comprising of 10 chicks. It was observed that washing affected the nutrients either by decreasing or increasing their concentration. It decreased the total mineral contents whereas CP, TP, EE and NFE contents increased. Washing also increased amino acid profile. Average feed intake and weight gain were higher in birds fed diet containing 8% washed distillery sludge and lower in birds fed diet containing 0% washed distillery sludge. Feed cost per kg live weight gain decreased significantly as the level of washed distillery sludge was increased in the diet. Average heart, liver and pancreas weights decreased with increased level of washed distillery sludge in the diet. The study revealed that after washing, distillery yeast sludge can be used successfully in broiler diets up to the level of 8% without any adverse effect on broiler’s performance. PMID:25049579

Metasomatic Control of Water in Garnet and Pyroxene from Kaapvaal Craton Mantle Xenoliths

NASA Technical Reports Server (NTRS)

Peslier, Anne H.; Woodland, Alan B.; Bell, David R.; Lazarov, Marina; Lapen, Thomas J.

2012-01-01

Fourier transform infrared spectrometry (FTIR) and laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) were used to determine water, rare earth (REE), lithophile (LILE), and high field strength (HFSE) element contents in garnet and pyroxene from mantle xenoliths, Kaapvaal craton, southern Africa. Water enters these nominally anhydrous minerals as protons bonded to structural oxygen in lattice defects. Pyroxene water contents (150-400 ppm in clinopyroxene; 40-250 ppm in orthopyroxene) correlate with their Al, Fe, Ca and Na and are homogeneous within a mineral grains and a xenolith. Garnets from Jagersfontein are chemically zoned for Cr, Ca, Ti and water contents. Garnets contain 0 to 20 ppm H2 Despite the fast diffusion rate of H in mantle m inerals, the observations above indicate that the water contents of mantle xenolith minerals were not disturbed during kimberlite entrainment and that the measured water data represent mantle values. Trace elements in all minerals show various degrees of light REE and LILE enrichments indicative of minimal to strong metasomatism. Water contents of peridotite minerals from the Kaapvaal lithosphere are not related to the degree of depletion of the peridotites. Instead, metasomatism exerts a clear control on the amount of water of mantle minerals. Xenoliths from each location record specific types of metasomatism with different outcomes for the water contents of mantle minerals. At pressures . 5.5 GPa, highly alkaline melts metasomatized Liqhobong and Kimberley peridotites, and increased the water contents of their olivine, pyroxenes and garnet. At higher pressures, the circulation of ultramafic melts reacting with peridotite resulted in co-variation of Ca, Ti and water at the edge of garnets at Jagersfontein, overall decreasing their water content, and lowered the water content of olivines at Finsch Mine. The calculated water content of these melts varies depending on whether the water content of the peridotite (2 wt% HO. 2O) or individual m inerals (<0.5-13 wt% H2O) are used, and also depend on the mineral-melt water partition coefficients. These metasomatic events are thought to have occurred during the Archean and Proterozoic, meaning that the water contents measured here have been preserved since that time and can be used to investigate viscocity and longevity of cratonic mantle roots.

Water Contents of the Mantle Beneath the Rio Grande Rift: FTIR Analysis of Kilbourne Hole Peridotite Xenoliths

NASA Technical Reports Server (NTRS)

Schaffer, Lillian A.; Peslier, Anne; Brandon, Alan

2013-01-01

Although nominally anhydrous mantle minerals contain only trace amounts of water, they are the main reservoir of water in the mantle. Added up at the scale of the Earth's mantle, these trace amounts of water represent oceans worth in mass]. Mantle xenoliths from Kilbourne Hole in southern New Mexico are ideal to study mantle water distribution in a rift tectonic setting as they come from a recently-erupted maar in the middle of the Rio Grande Rift. Eleven lherzolites, one harzburgite, and one dunite are being analyzed for water contents by FTIR. The xenoliths will also be analyzed for major and trace element composition, Fe3+/Summation (Fe) ratios, and characterized petrologically. Olivines exhibit variable water contents with less water at the rims compared to the cores. This is probably due to H loss during decompression and xenolith transport by the host magma. Mantle water contents appear to have been primarily preserved in the core of the olivines, based on diffusion modeling of the typically plateau-shaped water content profiles across these grains. Water concentrations are in equilibrium between clino- and orthopyroxene, but olivine concentrations are typically not in equilibrium with those of either pyroxene. Lherzolites analyzed so far have water contents of 2-12 ppm H2O in olivines, 125-165 ppm H2O in orthopyroxenes, and 328-447 ppm H2O in clinopyroxenes. These water contents are similar to, but with a narrower range, than those for the respective minerals in other continental peridotite xenoliths. The lherzolites have bulk-rock (BR) Al2O3 contents that range between 3.17 and 3.78 wt%, indicating similar degrees of partial melting, which could explain the narrow range of their pyroxene water contents. Primitive mantle normalized rare earth element (REE) profiles of the bulk lherzolites vary from light REE depleted to flat, with no significant differences between, nor relation to, their mineral water contents. Consequently, the metasomatic agents that enriched LREEs in these lherzolites were most likely water-poor. The harzburgite and the dunite have lower weight percent Al2O3 compared to the lherzolites (2.11% and 0.34% respectively) indicating higher degrees of melting. Their olivine water contents, however, are similar to those of the lherzolites. Moreover, no correlations are observed between pyroxene water contents and indices of melting or metasomatism between the lherzolite group, the harzburgite, and the dunite, although the latter has the lowest pyroxene water contents. More samples will be analyzed to determine if the water contents are controlled by melting, metasomatism, or a combination of the two in the Kilbourne Hole mantle.

Vegetation water content of crops and woodlands for improving soil moisture retrievals from Coriolis WindSat

USDA-ARS?s Scientific Manuscript database

Estimation of vegetation water content (VWC) by shortwave infrared remote sensing improves soil moisture retrievals. The largest unknown for predicting VWC is stem water content; for woodlands, stem water content is expected to be proportional to stem height. Airborne imagery were acquired and photo...

Vegetation water content of crops and woodlands for improving soil moisture retrievals from Coriolis WindSat

USDA-ARS?s Scientific Manuscript database

Estimation of vegetation water content (VWC) by shortwave infrared remote sensing improves soil moisture retrievals. The largest unknown for predicting VWC is stem water content, which is assumed to be allometrically related to canopy water content. From forest science, stem volume is linearly relat...

Experimental and analytical analysis of polarization and water transport behaviors of hydrogen alkaline membrane fuel cell

NASA Astrophysics Data System (ADS)

Huo, Sen; Zhou, Jiaxun; Wang, Tianyou; Chen, Rui; Jiao, Kui

2018-04-01

Experimental test and analytical modeling are conducted to investigate the operating behavior of an alkaline electrolyte membrane (AEM) fuel cell fed by H2/air (or O2) and explore the effect of various operating pressures on the water transfer mechanism. According to the experimental test, the cell performance is greatly improved through increasing the operating pressure gradient from anode to cathode which leads to significant liquid water permeation through the membrane. The high frequency resistance of the A901 alkaline membrane is observed to be relatively stable as the operating pressure varies based on the electrochemical impedance spectroscopy (EIS) method. Correspondingly, based on the modeling prediction, the averaged water content in the membrane electrode assembly (MEA) does not change too much which leads to the weak variation of membrane ohmic resistance. This reveals that the performance enhancement should give the credit to better electro-chemical reaction kinetics for both the anode and cathode, also prone by the EIS results. The reversion of water back diffusion direction across the membrane is also observed through analytical solution.

Environmental factors controlling benthic foraminiferal distribution in Hurghada area, Red Sea coast, Egypt

NASA Astrophysics Data System (ADS)

Mounir El-Kahawy, Ramadan; El-Wahab, Mohamed Abd

2017-04-01

Benthic foraminiferal assemblages were investigated at Hurghada on the Red Sea coast of Egypt, to determine the distribution and their common environmental factors that control on this distribution. 43 sediment samples were collected and environmental factors (T°C, pH, and salinity ‰), water depth, grain size, organic matter and carbonate content were measured. Faunal abundance (14-1755 tests/g) with an average 709 tests/g, and faunal diversity (6-39 specimens) with an average 31 specimen. Cluster analysis was divided the Hurghada site into four distinct biotopes based on the faunal data: Biotope (1) is dominated by a Quinqueloculina seminula& Quinqueloculina laevigata, and Triloculina terquemiana assemblage. Biotope (2) is dominated by a Sorites marginalis & Triloculina trigonula assemblage. Biotope (3) is dominated by an Amphistegina lessonii, Ammonia beccarii and Elphidium spp assemblage. Biotope (4) is dominated by a Peneroplis planatus& Coscinospira hemprichii& Sorites orbiculus and Neorotalia calcar assemblage. Some of the recorded foraminiferal tests showed abnormalities in their apertures, coiling and shape of chambers. The distribution of benthic foraminiferal species is governed by environmental factors such as salinity, temperature, substrates-type, water depth and pH. P. planatus and C. hemprichii positively correlate with extreme salinity and temperature, indicating that these species reflect a warm, arid climate conditions. Aside, the heavy metals (Cu, Cd, Zn, Pb, Ni and Mn) concentrations in the sediment samples were analyzed using ICP-OES. The comparative study between the faunal content and the heavy metals enrichments in each sample displayed positive character indicating the worsening of the environmental conditions. Keywords: benthic foraminifera, Hurghada, Red Sea, Egypt