UV lidar measurements of the stratospheric aerosol layer and comparison with other optical data

NASA Technical Reports Server (NTRS)

Uchino, O.

1985-01-01

After the violent volcanic eruptions of El Chichon in Mexico (17.33 deg. N, 93.20 deg. W) in late March and early April 1982, enhanced stratospheric aerosols have been monitored by ruby (lasing wavelength lambda=694.3 nm) or Nd:YAG lidars (lambda=1064 or 532 nm). By these lidars, visible or near-infrared optical informations of stratospheric aerosols and their space-time variations can be obtained. It is usually difficult to measure the background level of stratospheric aerosols by an ultraviolet (UV) lidar, since Rayleigh scattering prevails over Mie scattering in the stratosphere. However, after the large volcanic eruptions, UV lidar measurements of stratospheric aerosols are possible. In order to obtain UV optical properties of stratospheric aerosols, measurements have been made at Fukuoka (33.65 deg. N, 130.35 deg. E) by a p-terphenyl dye laser at a wavelength of 340.5 nm. Observational results during October 1982, through May 1983, are shown and are compared with the results obtained by a ruby lidar at Tsukuba (36.05 deg. N, 140.13 deg. E).

CALIPSO Observations of Volcanic Aerosol in the Stratosphere

NASA Technical Reports Server (NTRS)

Thomason, Larry W.; Pitts, Michael C.

2008-01-01

In the stratosphere, the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) has observed the presence of aerosol plumes associated with the eruptions several volcanoes including Montserrat (May 2006), Chaiten (May 2008), and Kasatochi (August 2008). While the dense ash plumes from these eruptions dissipate relatively quickly, CALIPSO continued to detect an enhanced aerosol layer from the Montserrat eruption from the initial observations in June 2006 well into 2008. Solar occultation missions were uniquely capable of monitoring stratospheric aerosol. However, since the end of long-lived instruments like the Stratospheric Aerosol and Gas Experiment (SAGE II), there has been no clear space-based successor instrument. A number of active instruments, some employing new techniques, are being evaluated as candidate sources of stratospheric aerosol data. Herein, we examine suitability of the CALIPSO 532-nm aerosol backscatter coefficient measurements.

SAM 2 measurements of the polar stratospheric aerosol. Volume 9: October 1982 - April 1983

NASA Technical Reports Server (NTRS)

Mcmaster, L. R.; Powell, K. A.

1991-01-01

The Stratospheric Aerosol Measurement (SAM) II sensor aboard Nimbus 7 is providing 1.0 micron extinction measurements of Antarctic and Arctic stratospheric aerosols with a vertical resolution of 1 km. Representative examples and weekly averages including corresponding temperature profiles provided by NOAA for the time and place of each SAM II measurement are presented. Contours of aerosol extinction as a function of altitude and longitude or time are plotted, and aerosol optical depths are calculated for each week. Typical values of aerosol extinction and stratospheric optical depth in the Arctic are unusually large due to the presence of material from the El Chichon volcano eruption in the Spring of 1982. For example, the optical depth peaked at 0.068, more than 50 times background values. Typical values of aerosol extinction and stratospheric optical depth in the Antarctic varied considerably during this period due to the transport and arrival of the material from the El Chichon eruption. For example, the stratospheric optical depth varied from 0.002 in October 1982, to 0.021 in January 1983. Polar stratospheric clouds were observed during the Arctic winter, as expected. A representative sample is provided of the ninth 6-month period of data to be used in atmospheric and climatic studies.

Stratospheric aerosols from the Sarychev volcano eruption in the 2009 Arctic summer

NASA Astrophysics Data System (ADS)

Jégou, F.; Berthet, G.; Brogniez, C.; Renard, J.-B.; François, P.; Haywood, J. M.; Jones, A.; Bourgeois, Q.; Lurton, T.; Auriol, F.; Godin-Beekmann, S.; Guimbaud, C.; Krysztofiak, G.; Gaubicher, B.; Chartier, M.; Clarisse, L.; Clerbaux, C.; Balois, J. Y.; Verwaerde, C.

2013-02-01

Aerosols from the Sarychev volcano eruption (Kuril Islands, northeast of Japan) were observed in the Arctic lower stratosphere a few days after the strongest SO2 injection which occurred on 15 and 16 June 2009. From the observations provided by the Infrared Atmospheric Sounding Interferometer (IASI) an estimated 0.9 Tg of sulphur dioxide was injected into the Upper Troposphere and Lower Stratosphere (UTLS). The resultant stratospheric sulphate aerosols were detected by the Optical Spectrograph and Infrared Imaging System (OSIRIS) limb sounder and by the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) satellite instruments. By the first week of July the aerosol plume had spread out over the entire Arctic region. The Sarychev-induced stratospheric aerosol over the Kiruna region (north of Sweden) was measured by the Stratospheric and Tropospheric Aerosol Counter (STAC) during eight balloon flights planned in August and September 2009. During this balloon campaign the Micro RADIomètre BALlon (MicroRADIBAL) and the Spectroscopie d'Absorption Lunaire pour l'Observation des Minoritaires Ozone et NOx (SALOMON) remote-sensing instruments also observed these aerosols. Aerosol concentrations returned to near-background levels by spring 2010. The effective radius, the Surface Area Density (SAD), the aerosol extinction, and the total sulphur mass from STAC in situ measurements are enhanced with mean values in the range 0.15-0.21 μm, 5.5-14.7 μm2 cm-3, 5.5-29.5×10-4 km-1, and 4.9-12.6×10-10 kg [S] kg-1 [air], respectively, between 14 km and 18 km. The observed and modelled e-folding time of sulphate aerosols from the Sarychev eruption is around 70-80 days, a value much shorter than the 12-14 months calculated for aerosols from the 1991 eruption of Mt. Pinatubo. The OSIRIS stratospheric Aerosol Optical Depth (AOD) at 750 nm is enhanced by a factor of 6 with a value of 0.02 in late July compared to 0.0035 before the eruption. The HadGEM2 and MIMOSA model outputs

Laboratory studies of stratospheric aerosol chemistry

NASA Technical Reports Server (NTRS)

Molina, Mario J.

1996-01-01

In this report we summarize the results of the two sets of projects funded by the NASA grant NAG2-632, namely investigations of various thermodynamic and nucleation properties of the aqueous acid system which makes up stratospheric aerosols, and measurements of reaction probabilities directly on ice aerosols with sizes corresponding to those of polar stratospheric cloud particles. The results of these investigations are of importance for the assessment of the potential stratospheric effects of future fleets of supersonic aircraft. In particular, the results permit to better estimate the effects of increased amounts of water vapor and nitric acid (which forms from nitrogen oxides) on polar stratospheric clouds and on the chemistry induced by these clouds.

Stratospheric aerosol particle size distribution based on multi-color polarization measurements of the twilight sky

NASA Astrophysics Data System (ADS)

Ugolnikov, Oleg S.; Maslov, Igor A.

2018-03-01

Polarization measurements of the twilight background with Wide-Angle Polarization Camera (WAPC) are used to detect the depolarization effect caused by stratospheric aerosol near the altitude of 20 km. Based on a number of observations in central Russia in spring and summer 2016, we found the parameters of lognormal size distribution of aerosol particles. This confirmed the previously published results of the colorimetric method as applied to the same twilights. The mean particle radius (about 0.1 micrometers) and size distribution are also in agreement with the recent data of in situ and space-based remote sensing of stratospheric aerosol. Methods considered here provide two independent techniques of the stratospheric aerosol study based on the twilight sky analysis.

a Study on the Physical and Chemical Properties of Stratospheric Aerosols.

NASA Astrophysics Data System (ADS)

Tabazadeh, Azadeh

The physical and chemical properties of stratospheric aerosols under background and perturbed conditions are discussed. First, a multi-component aerosol physical chemistry model was developed to study the composition and reactivity of stratospheric aerosols. The compositions are predicted from an equilibrium assumption between the condensed-and gas-phases, and they are calculated as a function of ambient temperature, relative humidity, and the total mass of nitric acid and sulfuric acid present per unit volume of air. The water and solute activity parameters in the aerosol model are derived from various laboratory sources, and the set of equilibrium equations are solved using a unique numerical scheme. The aerosol model is applied to study the formation of nitric acid-containing aerosols in the stratosphere. Also, the equilibrium compositions are used to estimate the extent of aqueous phase processing of chlorine species in the aerosol solutions. This processing can contribute to the depletion of the stratospheric ozone layer, especially after major volcanic eruptions where sulfate aerosols are more abundant. Second, a surface chemistry model was constructed that includes Langmuir trace-gas adsorption and desorption, Brunauer, Emmett and Teller adsorption of water vapor, surface poisoning, solvation and diffusion of molecules on the surface, chemical activation and reaction of adsorbates, and product desorption or reaction. This model is used to study the effects of relative humidity and other physical parameters on the efficiency of heterogeneous chemical processes which occur on the surfaces of solid polar stratospheric clouds. These heterogeneous chemical processes are responsible for the formation of the "ozone hole", can contribute to global ozone depletion, and may have tropospheric significance. Finally, a fluid dynamics and thermodynamics model of volcanic eruption columns was used to develop a scheme for predicting the extent of HCl removal from volcanic

Stratospheric aerosols from the Sarychev volcano eruption in the 2009 Arctic summer

NASA Astrophysics Data System (ADS)

Jégou, F.; Berthet, G.; Brogniez, C.; Renard, J.-B.; François, P.; Haywood, J. M.; Jones, A.; Bourgeois, Q.; Lurton, T.; Auriol, F.; Godin-Beekmann, S.; Guimbaud, C.; Krysztofiak, G.; Gaubicher, B.; Chartier, M.; Clarisse, L.; Clerbaux, C.; Balois, J. Y.; Verwaerde, C.; Daugeron, D.

2013-07-01

Aerosols from the Sarychev volcano eruption (Kuril Islands, northeast of Japan) were observed in the Arctic lower stratosphere a few days after the strongest SO2 injection which occurred on 15 and 16 June 2009. From the observations provided by the Infrared Atmospheric Sounding Interferometer (IASI) an estimated 0.9 Tg of sulphur dioxide was injected into the upper troposphere and lower stratosphere (UTLS). The resultant stratospheric sulphate aerosols were detected from satellites by the Optical Spectrograph and Infrared Imaging System (OSIRIS) limb sounder and by the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and from the surface by the Network for the Detection of Atmospheric Composition Changes (NDACC) lidar deployed at OHP (Observatoire de Haute-Provence, France). By the first week of July the aerosol plume had spread out over the entire Arctic region. The Sarychev-induced stratospheric aerosol over the Kiruna region (north of Sweden) was measured by the Stratospheric and Tropospheric Aerosol Counter (STAC) during eight balloon flights planned in August and September 2009. During this balloon campaign the Micro Radiomètre Ballon (MicroRADIBAL) and the Spectroscopie d'Absorption Lunaire pour l'Observation des Minoritaires Ozone et NOx (SALOMON) remote-sensing instruments also observed these aerosols. Aerosol concentrations returned to near-background levels by spring 2010. The effective radius, the surface area density (SAD), the aerosol extinction, and the total sulphur mass from STAC in situ measurements are enhanced with mean values in the range 0.15-0.21 μm, 5.5-14.7 μm2 cm-3, 5.5-29.5 × 10-4 km-1, and 4.9-12.6 × 10-10 kg[S] kg-1[air], respectively, between 14 km and 18 km. The observed and modelled e-folding time of sulphate aerosols from the Sarychev eruption is around 70-80 days, a value much shorter than the 12-14 months calculated for aerosols from the 1991 eruption of Mt Pinatubo. The OSIRIS stratospheric aerosol optical depth (AOD

Influence of Aerosol Heating on the Stratospheric Transport of the Mt. Pinatubo Eruption

NASA Technical Reports Server (NTRS)

Aquila, Valentina; Oman, Luke D.; Stolarski, Richard S.

2011-01-01

On June 15th, 1991 the eruption of Mt. Pinatubo (15.1 deg. N, 120.3 Deg. E) in the Philippines injected about 20 Tg of sulfur dioxide in the stratosphere, which was transformed into sulfuric acid aerosol. The large perturbation of the background aerosol caused an increase in temperature in the lower stratosphere of 2-3 K. Even though stratospheric winds climatological]y tend to hinder the air mixing between the two hemispheres, observations have shown that a large part of the SO2 emitted by Mt. Pinatubo have been transported from the Northern to the Southern Hemisphere. We simulate the eruption of Mt. Pinatubo with the Goddard Earth Observing System (GEOS) version 5 global climate model, coupled to the aerosol module GOCART and the stratospheric chemistry module StratChem, to investigate the influence of the eruption of Mt. Pinatubo on the stratospheric transport pattern. We perform two ensembles of simulations: the first ensemble consists of runs without coupling between aerosol and radiation. In these simulations the plume of aerosols is treated as a passive tracer and the atmosphere is unperturbed. In the second ensemble of simulations aerosols and radiation are coupled. We show that the set of runs with interactive aerosol produces a larger cross-equatorial transport of the Pinatubo cloud. In our simulations the local heating perturbation caused by the sudden injection of volcanic aerosol changes the pattern of the stratospheric winds causing more intrusion of air from the Northern into the Southern Hemisphere. Furthermore, we perform simulations changing the injection height of the cloud, and study the transport of the plume resulting from the different scenarios. Comparisons of model results with SAGE II and AVHRR satellite observations will be shown.

Lidar measurements of ozone and aerosol distributions during the 1992 airborne Arctic stratospheric expedition

NASA Technical Reports Server (NTRS)

Browell, Edward V.; Butler, Carolyn F.; Fenn, Marta A.; Grant, William B.; Ismail, Syed; Carter, Arlen F.

1994-01-01

The NASA Langley airborne differential absorption lidar system was operated from the NASA Ames DC-8 aircraft during the 1992 Airborne Arctic Stratospheric Expedition to investigate the distribution of stratospheric aerosols and ozone (O3) across the Arctic vortex from January to March 1992. Aerosols from the Mt. Pinatubo eruption were found outside and inside the Arctic vortex with distinctly different scattering characteristics and spatial distributions in the two regions. The aerosol and O3 distributions clearly identified the edge of the vortex and provided additional information on vortex dynamics and transport processes. Few polar stratospheric clouds were observed during the AASE-2; however, those that were found had enhanced scattering and depolarization over the background Pinatubo aerosols. The distribution of aerosols inside the vortex exhibited relatively minor changes during the AASE-2. Ozone depletion inside the vortex as limited to less than or equal to 20 percent in the altitude region from 15-20 km.

Comparison of the impact of volcanic eruptions and aircraft emissions on the aerosol mass loading and sulfur budget in the stratosphere

NASA Technical Reports Server (NTRS)

Yue, Glenn K.; Poole, Lamont R.

1992-01-01

Data obtained by the Stratospheric Aerosol and Gas Experiment (SAGE) 1 and 2 were used to study the temporal variation of aerosol optical properties and to assess the mass loading of stratospheric aerosols from the eruption of volcanos Ruiz and Kelut. It was found that the yearly global average of optical depth at 1.0 micron for stratospheric background aerosols in 1979 was 1.16 x 10(exp -3) and in 1989 was 1.66 x 10(exp -3). The eruptions of volcanos Ruiz and Kelut ejected at least 5.6 x 10(exp 5) and 1.8 x 10(exp 5) tons of materials into the stratosphere, respectively. The amount of sulfur emitted per year from the projected subsonic and supersonic fleet is comparable to that contained in the background aerosol particles in midlatitudes from 35 deg N to 55 deg N.

ISAMS observations of stratospheric aerosol

NASA Technical Reports Server (NTRS)

Lambert, Alyn; Remedios, John J.; Dudhia, Anu; Corney, Marie; Kerridge, Brian J.; Rodgers, Clive D.; Taylor, Fredric W.

1994-01-01

The Improved Stratospheric and Mesospheric (ISAMS) on board the Upper Atmosphere Research Satellite (UARS) incorporates a 12.1 micron window channel for the measurement of aerosol opacity. The retrieval scheme is discussed briefly and preliminary observations of the Mt. Pinatubo aerosol cloud are presented and compared with SAGE 2 observations at 1.02 microns. The effect of aerosol on other ISAMS channels and its spectral dependence is discussed.

Radiative and Chemical Response to Interactive Stratospheric Sulfate Aerosols in Fully Coupled CESM1(WACCM): Stratospheric Aerosols in CESM1(WACCM)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mills, Michael J.; Richter, Jadwiga H.; Tilmes, Simone

We present a new version of the Community Earth System Model, version 1 (CESM1) with the Whole Atmosphere Community Climate Model (WACCM) featuring numerous improvements that are unique among earth system models. Improved horizontal resolution, dynamics, and chemistry now provide the development of an internally generated quasi-biennial oscillation, and significant improvements to temperatures and ozone throughout the stratosphere. The prognostic treatment of stratospheric sulfate aerosols is shown to represent well the evolution of stratospheric aerosol optical depth and perturbations to solar and longwave radiation following volcanic eruptions. We identify the inclusion of interactive OH chemistry as crucial to the studymore » of aerosol formation following large inputs of SO2 to the stratosphere. We show that depletion of OH levels within the dense SO2 cloud in the first weeks following the June 1991 eruption of Mt. Pinatubo significantly prolonged the e-folding decay time for SO2 oxidation to 47 days. Previous observational and model studies showing a 30-day decay time have not accounted for the large initial losses of SO2 on ash and ice in the first 7-9 days following the eruption, and have not correctly accounted for OH depletion. The completeness of the chemistry, dynamics, and aerosol microphysics in WACCM uniquely qualify it for studies of stratospheric sulfate aerosol geoengineering.« less

Variability and evolution of the midlatitude stratospheric aerosol budget from 22 years of ground-based lidar and satellite observations

NASA Astrophysics Data System (ADS)

Khaykin, Sergey M.; Godin-Beekmann, Sophie; Keckhut, Philippe; Hauchecorne, Alain; Jumelet, Julien; Vernier, Jean-Paul; Bourassa, Adam; Degenstein, Doug A.; Rieger, Landon A.; Bingen, Christine; Vanhellemont, Filip; Robert, Charles; DeLand, Matthew; Bhartia, Pawan K.

2017-02-01

The article presents new high-quality continuous stratospheric aerosol observations spanning 1994-2015 at the French Observatoire de Haute-Provence (OHP, 44° N, 6° E) obtained by two independent, regularly maintained lidar systems operating within the Network for Detection of Atmospheric Composition Change (NDACC). Lidar series are compared with global-coverage observations by Stratospheric Aerosol and Gas Experiment (SAGE II), Global Ozone Monitoring by Occultation of Stars (GOMOS), Optical Spectrograph and InfraRed Imaging System (OSIRIS), Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP), and Ozone Mapping Profiling Suite (OMPS) satellite instruments, altogether covering the time span of OHP lidar measurements. Local OHP and zonal-mean satellite series of stratospheric aerosol optical depth are in excellent agreement, allowing for accurate characterization of stratospheric aerosol evolution and variability at northern midlatitudes during the last 2 decades. The combination of local and global observations is used for a careful separation between volcanically perturbed and quiescent periods. While the volcanic signatures dominate the stratospheric aerosol record, the background aerosol abundance is found to be modulated remotely by the poleward transport of convectively cleansed air from the deep tropics and aerosol-laden air from the Asian monsoon region. The annual cycle of background aerosol at midlatitudes, featuring a minimum during late spring and a maximum during late summer, correlates with that of water vapor from the Aura Microwave Limb Sounder (MLS). Observations covering two volcanically quiescent periods over the last 2 decades provide an indication of a growth in the nonvolcanic component of stratospheric aerosol. A statistically significant factor of 2 increase in nonvolcanic aerosol since 1998, seasonally restricted to late summer and fall, is associated with the influence of the Asian monsoon and growing pollution therein.

MIPAS observations of volcanic sulfate aerosol and sulfur dioxide in the stratosphere

NASA Astrophysics Data System (ADS)

Günther, Annika; Höpfner, Michael; Sinnhuber, Björn-Martin; Griessbach, Sabine; Deshler, Terry; von Clarmann, Thomas; Stiller, Gabriele

2018-01-01

Volcanic eruptions can increase the stratospheric sulfur loading by orders of magnitude above the background level and are the most important source of variability in stratospheric sulfur. We present a set of vertical profiles of sulfate aerosol volume densities and derived liquid-phase H2SO4 (sulfuric acid) mole fractions for 2005-2012, retrieved from infrared limb emission measurements performed with the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on board of the Environmental Satellite (Envisat). Relative to balloon-borne in situ measurements of aerosol at Laramie, Wyoming, the MIPAS aerosol data have a positive bias that has been corrected, based on the observed differences to the in situ data. We investigate the production of stratospheric sulfate aerosol from volcanically emitted SO2 for two case studies: the eruptions of Kasatochi in 2008 and Sarychev in 2009, which both occurred in the Northern Hemisphere midlatitudes during boreal summer. With the help of chemical transport model (CTM) simulations for the two volcanic eruptions we show that the MIPAS sulfate aerosol and SO2 data are qualitatively and quantitatively consistent with each other. Further, we demonstrate that the lifetime of SO2 is explained well by its oxidation by hydroxyl radicals (OH). While the sedimentation of sulfate aerosol plays a role, we find that the long-term decay of stratospheric sulfur after these volcanic eruptions in midlatitudes is mainly controlled by transport via the Brewer-Dobson circulation. Sulfur emitted by the two midlatitude volcanoes resides mostly north of 30° N at altitudes of ˜ 10-16 km, while at higher altitudes ( ˜ 18-22 km) part of the volcanic sulfur is transported towards the Equator where it is lifted into the stratospheric overworld and can further be transported into both hemispheres.

Sampling stratospheric aerosols with impactors

NASA Technical Reports Server (NTRS)

Oberbeck, Verne R.

1989-01-01

Derivation of statistically significant size distributions from impactor samples of rarefield stratospheric aerosols imposes difficult sampling constraints on collector design. It is shown that it is necessary to design impactors of different size for each range of aerosol size collected so as to obtain acceptable levels of uncertainty with a reasonable amount of data reduction.

A model for studying the composition and chemical effects of stratospheric aerosols

NASA Technical Reports Server (NTRS)

Tabazadeh, Azadeh; Turco, Richard P.; Jacobson, Mark Z.

1994-01-01

We developed polynomial expressions for the temperature dependence of the mean binary and water activity coefficients for H2SO4 and HNO3 solutions. These activities were used in an equilibrium model to predict the composition of stratospheric aerosols under a wide range of environmental conditions. For typical concentrations of H2O, H2SO4, HNO3, HCl, HBr, HF, and HOCl in the lower stratosphere, the aerosol composition is estimated as a function of the local temperature and the ambient relative humidity. For temperatures below 200 K, our results indicate that (1) HNO3 contributes a significant mass fraction to stratospheric aerosols, and (2) HCl solubility is considerably affected by HNO3 dissolution into sulfate aerosols. We also show that, in volcanically disturbed periods, changes in stratospheric aerosol composition can significantly alter the microphysics that leads to the formation of polar stratospheric clouds. The effects caused by HNO3 dissolution on the physical and chemical properties of stratospheric aerosols are discussed.

Major Influence of Tropical Volcanic Eruptions on the Stratospheric Aerosol Layer During the Last Decade

NASA Technical Reports Server (NTRS)

Vernier, Jean-Paul; Thomason, Larry W.; Pommereau, J.-P.; Bourassa, Adam; Pelon, Jacques; Garnier, Anne; Hauchecorne, A.; Blanot, L.; Trepte, Charles R.; Degenstein, Doug;

Stratospheric aerosol optical depths, 1850-1990

NASA Technical Reports Server (NTRS)

Sato, Makiko; Hansen, James E.; Mccormick, M. Patrick; Pollack, James B.

1993-01-01

A global stratospheric aerosol database employed for climate simulations is described. For the period 1883-1990, aerosol optical depths are estimated from optical extinction data, whose quality increases with time over that period. For the period 1850-1882, aerosol optical depths are more crudely estimated from volcanological evidence for the volume of ejecta from major known volcanoes. The data set is available over Internet.

Light Absorption of Stratospheric Aerosols: Long-Term Trend and Contribution by Aircraft

NASA Technical Reports Server (NTRS)

Pueschel , R. F.; Gore, Waren J. Y. (Technical Monitor)

1997-01-01

Measurements of aerosol light-absorption coefficients are useful for studies of radiative transfer and heating rates. Ogren appears to have published the first light- absorption coefficients in the stratosphere in 1981, followed by Clarke in 1983 and Pueschel in 1992. Because most stratospheric soot appears to be due to aircraft operations, application of an aircraft soot aerosol emission index to projected fuel consumption suggests a threefold increase of soot loading and light absorption by 2025. Together, those four data sets indicate an increase in mid-visible light extinction at a rate of 6 % per year. This trend is similar to the increase per year of sulfuric acid aerosol and of commercial fleet size. The proportionality between stepped-up aircraft operations above the tropopause and increases in stratospheric soot and sulfuric acid aerosol implicate aircraft as a source of stratospheric pollution. Because the strongly light-absorbing soot and the predominantly light-scattering sulfuric acid aerosol increase at similar rates, however, the mid-visible stratospheric aerosol single scatter albedo is expected to remain constant and not approach a critical value of 0.98 at which stratospheric cooling could change to warming.

A stratospheric aerosol increase

NASA Technical Reports Server (NTRS)

Rosen, J. M.; Hofmann, D. J.

1980-01-01

Large disturbances were noted in the stratospheric aerosol content in the midlatitude Northern Hemisphere commencing about 7 months after the eruption of La Soufriere and less than 1 month after the eruption of Sierra Negra. The aerosol was characterized by a very steep size distribution in the 0.15 to 0.25 micron radius range and contained a volatile component. Measurements near the equator and at the South Pole indicate that the disturbance was widespread. These observations were made before the May 18 eruption of Mt. St. Helens.

Impacts of Mt Pinatubo volcanic aerosol on the tropical stratosphere in chemistry-climate model simulations using CCMI and CMIP6 stratospheric aerosol data

NASA Astrophysics Data System (ADS)

Revell, Laura E.; Stenke, Andrea; Luo, Beiping; Kremser, Stefanie; Rozanov, Eugene; Sukhodolov, Timofei; Peter, Thomas

2017-11-01

To simulate the impacts of volcanic eruptions on the stratosphere, chemistry-climate models that do not include an online aerosol module require temporally and spatially resolved aerosol size parameters for heterogeneous chemistry and aerosol radiative properties as a function of wavelength. For phase 1 of the Chemistry-Climate Model Initiative (CCMI-1) and, later, for phase 6 of the Coupled Model Intercomparison Project (CMIP6) two such stratospheric aerosol data sets were compiled, whose functional capability and representativeness are compared here. For CCMI-1, the SAGE-4λ data set was compiled, which hinges on the measurements at four wavelengths of the SAGE (Stratospheric Aerosol and Gas Experiment) II satellite instrument and uses ground-based lidar measurements for gap-filling immediately after the 1991 Mt Pinatubo eruption, when the stratosphere was too optically opaque for SAGE II. For CMIP6, the new SAGE-3λ data set was compiled, which excludes the least reliable SAGE II wavelength and uses measurements from CLAES (Cryogenic Limb Array Etalon Spectrometer) on UARS, the Upper Atmosphere Research Satellite, for gap-filling following the Mt Pinatubo eruption instead of ground-based lidars. Here, we performed SOCOLv3 (Solar Climate Ozone Links version 3) chemistry-climate model simulations of the recent past (1986-2005) to investigate the impact of the Mt Pinatubo eruption in 1991 on stratospheric temperature and ozone and how this response differs depending on which aerosol data set is applied. The use of SAGE-4λ results in heating and ozone loss being overestimated in the tropical lower stratosphere compared to observations in the post-eruption period by approximately 3 K and 0.2 ppmv, respectively. However, less heating occurs in the model simulations based on SAGE-3λ, because the improved gap-filling procedures after the eruption lead to less aerosol loading in the tropical lower stratosphere. As a result, simulated tropical temperature anomalies in

OMPS Limb Profiler: Extending SAGE and CALIPSO Stratospheric Aerosol Records

NASA Astrophysics Data System (ADS)

Taha, G.; Bhartia, P. K.; Chen, Z.; Xu, P.; Loughman, R. P.; Jaross, G.

2017-12-01

The OMPS LP instrument is designed to provide high vertical resolution ozone and aerosol profiles from measurements of the scattered solar radiation in the 290-1000 nm spectral range. It collected its first Earth limb measurement in January 10, 2012, and continues to provide daily global measurements of ozone and aerosol profiles from the cloud top up to 60 km and 40 km respectively. The relatively high vertical and spatial sampling allow detection and tracking periodic events when aerosol particles are injected into the stratosphere, such as volcanic eruptions or meteor explosions. OMPS LP can extend the long-term records of stratospheric aerosol at high vertical resolution produced by variety of sensors, such as SAGEII, GOMOS, OSIRIS and CALIPSO. Most of these instruments ceased to operate or well beyond their designed lifetime. After an absence of over a decade, SAGE III/ISS was launched earlier this year and expected to resume the high quality aerosol data record. OMPS LP is also schedule to fly on JPSS-2 and 3. In this study we will examine the suitability of using LP profiles to continue the stratospheric aerosol records beyond SAGE, OSIRIS, and CALIPSO. We will compare OMPS LP released V1.0 aerosol extinction measurements to OSIRIS and CALIPSO. Initial results shows good agreement with OSIRIS measurements to within 20%, with larger bias in the southern hemisphere. To test the effect of the assumed aerosol size model (ASD) and phase function, we compare measurements taken at similar location and time with different viewing geometry. Comparison of ascending and descending aerosol extinction daily zonal means at high latitudes shows systematic bias that is well correlated with the solar scattering angle, indicating ASD uncertainties up to 30%. In addition, results showing latitudinal, and temporal variability of stratospheric aerosol extinction and optical depth for the three instruments will also be presented and compared. We will also present OMPS LP aerosol

Spatial variation of stratospheric aerosol acidity and model refractive index - Implications of recent results

NASA Technical Reports Server (NTRS)

Russell, P. B.; Hamill, P.

1984-01-01

Recent experimental results indicate that little or no solid ammonium sulfate is present in background stratospheric aerosols. Other results allow straightforward calculation of sulfuric acid/water droplet properties (acidity, specific gravity, refractive index) as functions of stratospheric temperature and humidity. These results are combined with a variety of latitudinal and seasonal temperature and humidity profiles to obtain corresponding profiles of droplet properties. These profiles are used to update a previous model of stratospheric aerosol refractive index. The new model retains the simplifying approximation of vertically constant refractive index in the inner stratosphere, but has sulfuric acid/water refractive index values that significantly exceed the previously used room temperature values. Mean conversion ratios (e.g., extinction-to-number, backscatter-to-volume) obtained using Mie scattering calculations with the new refractive indices are very similar to those obtained for the old indices, because the effects of deleting ammonium sulfate and increasing acid indices tend to cancel each other.

Evolution of the stratospheric aerosol in the northern hemisphere following the June 1991 volcanic eruption of Mount Pinatubo: Role of tropospheric-stratospheric exchange and transport

NASA Astrophysics Data System (ADS)

Jónsson, Hafliòi H.; Wilson, James C.; Brock, Charles A.; Dye, J. E.; Ferry, G. V.; Chan, K. R.

1996-01-01

Since the eruption of Mount Pinatubo in June, 1991, measurements of particle size and concentration have intermittently been carried out from an ER-2 aircraft at altitudes of up to 21 km at midlatitudes and high latitudes in the northern hemisphere. They show the evolution and purge of the volcanic aerosol to be due to an interaction of aerosol mechanics with tropospheric-stratospheric exchange processes, transport, and mixing. During the first 5 months after the eruption the volcanic plume spread to higher latitudes in laminae and filaments, producing steep spatial gradients in the properties of the stratospheric aerosol. At the same time the concentration of newly formed particles in the plume rapidly decreased toward background values as a result of coagulation while particle size and aerosol surface area continued to increase. By December 1991, the particle number mixing ratios and aerosol surface area mixing ratios had become spatially uniform over a wide range of latitudes above 18 km. The surface area mixing ratios peaked in this region of the stratosphere at ˜35 times their background values in the winter of 1992. The corresponding condensed mass mixing ratio enhancement was by a factor of ˜200. After the winter of 1992, a gradual removal of the volcanic mass began and initially was dominated by sedimentation above 18 km. The aerosol surface area mixing ratio thus decreased by an order of magnitude over 2.5 years, and the aerosol volume, or condensed mass, mixing ratio decayed by an order of magnitude over approximately 1.7 years. Below 18 km, the purging of the Pinatubo aerosol at mid-latitudes appeared sporadic and disorderly and was strongly influenced by episodal rapid quasi-isentropic transport and dilution by tropical air of tropospheric origin having high condensation nuclei mixing ratios but low mixing ratios of aerosol surface area or condensed mass compared to the volcanic aerosol.

The boiling point of stratospheric aerosols.

NASA Technical Reports Server (NTRS)

Rosen, J. M.

1971-01-01

A photoelectric particle counter was used for the measurement of aerosol boiling points. The operational principle involves raising the temperature of the aerosol by vigorously heating a portion of the intake tube. At or above the boiling point, the particles disintegrate rather quickly, and a noticeable effect on the size distribution and concentration is observed. Stratospheric aerosols appear to have the same volatility as a solution of 75% sulfuric acid. Chemical analysis of the aerosols indicates that there are other substances present, but that the sulfate radical is apparently the major constituent.

Spectral signatures of polar stratospheric clouds and sulfate aerosol

NASA Technical Reports Server (NTRS)

Massie, S. T.; Bailey, P. L.; Gille, J. C.; Lee, E. C.; Mergenthaler, J. L.; Roche, A. E.; Kumer, J. B.; Fishbein, E. F.; Waters, J. W.; Lahoz, W. A.

1994-01-01

Multiwavelength observations of Antarctic and midlatitude aerosol by the Cryogenic Limb Array Etalon Spectrometer (CLAES) experiment on the Upper Atmosphere Research Satellite (UARS) are used to demonstrate a technique that identifies the location of polar stratospheric clouds. The technique discussed uses the normalized area of the triangle formed by the aerosol extinctions at 925, 1257, and 1605/cm (10.8, 8.0, and 6.2 micrometers) to derive a spectral aerosol measure M of the aerosol spectrum. Mie calculations for spherical particles and T-matrix calculations for spheriodal particles are used to generate theoretical spectral extinction curves for sulfate and polar stratospheric cloud particles. The values of the spectral aerosol measure M for the sulfate and polar stratospheric cloud particles are shown to be different. Aerosol extinction data, corresponding to temperatures between 180 and 220 K at a pressure of 46 hPa (near 21-km altitude) for 18 August 1992, are used to demonstrate the technique. Thermodynamic calculations, based upon frost-point calculations and laboratory phase-equilibrium studies of nitric acid trihydrate, are used to predict the location of nitric acid trihydrate cloud particles.

Stratospheric Aerosol and Gas Experiment (SAGE 3)

NASA Technical Reports Server (NTRS)

Mccormick, M. P.

1993-01-01

The proposed SAGE III instrument would be the principal source of data for global changes of stratospheric aerosols, stratospheric water vapor, and ozone profiles, and a contributing source of data for upper tropospheric water vapor, aerosols, and clouds. The ability to obtain such data has been demonstrated by the predecessor instrument, SAGE II, but SAGE III will be substantially more capable, as discussed below. The capabilities for monitoring the profiles of atmospheric constituents have been verified in detail, including ground-based validations, for aerosol, ozone, and water vapor. Indeed, because of its self-calibrating characteristics, SAGE II was an essential component of the international ozone trend assessments, and SAGE II is now proving to be invaluable in tracking the aerosols from Mt. Pinatubo. Although SAGE profiles generally terminate at the height of the first tropospheric cloud layer, it has been found that the measurements extend down to 3 km altitude more than 40 percent of the time at most latitudes. Thus, useful information can also be obtained on upper tropospheric aerosols, water vapor, and ozone.

SAGE measurements of the stratospheric aerosol dispersion and loading from the Soufriere Volcano

NASA Technical Reports Server (NTRS)

Mccormick, M. P.; Kent, G. S.; Yue, G. K.; Cunnold, D. M.

1981-01-01

Explosions of the Soufriere volcano on the Caribbean Island of St. Vincent reduced two major stratospheric plumes which the stratospheric aerosol and gas experiment (SAGE) satellite tracked to West Africa and the North Atlantic Ocean. The total mass of the stratospheric ejecta measured is less than 0.5% of the global stratospheric aerosol burden. No significant temperature or climate perturbation is expected. It is found that the movement and dispersion of the plumes agree with those deduced from high altitude meteorological data and dispersion theory. The stratospheric aerosol dispersion and loading from the Soufrier volcano was measured.

SAGE measurements of the stratospheric aerosol dispersion and loading from the Soufriere Volcano

NASA Astrophysics Data System (ADS)

McCormick, M. P.; Kent, G. S.; Yue, G. K.; Cunnold, D. M.

1981-11-01

Explosions of the Soufriere volcano on the Caribbean Island of St. Vincent reduced two major stratospheric plumes which the stratospheric aerosol and gas experiment (SAGE) satellite tracked to West Africa and the North Atlantic Ocean. The total mass of the stratospheric ejecta measured is less than 0.5% of the global stratospheric aerosol burden. No significant temperature or climate perturbation is expected. It is found that the movement and dispersion of the plumes agree with those deduced from high altitude meteorological data and dispersion theory. The stratospheric aerosol dispersion and loading from the Soufrier volcano was measured.

Tibetan Plateau glacier and hydrological change under stratospheric aerosol injection

NASA Astrophysics Data System (ADS)

Ji, D.

2017-12-01

As an important inland freshwater resource, mountain glaciers are highly related to human life, they provide water for many large rivers and play a very important role in regional water cycles. The response of mountain glaciers to future climate change is a topic of concern especially to the many people who rely on glacier-fed rivers for purposes such as irrigation. Geoengineering by stratospheric aerosol injection is a method of offsetting the global temperature rise from greenhouse gases. How the geoengineering by stratospheric aerosol injection affects the mass balance of mountain glaciers and adjacent river discharge is little understood. In this study, we use regional climate model WRF and catchment-based river model CaMa-Flood to study the impacts of stratospheric aerosol injection to Tibetan Plateau glacier mass balance and adjacent river discharge. To facilitate mountain glacier mass balance study, we improve the description of mountain glacier in the land surface scheme of WRF. The improvements include: (1) a fine mesh nested in WRF horizontal grid to match the highly non-uniform spatial distribution of the mountain glaciers, (2) revising the radiation flux at the glacier surface considering the surrounding terrain. We use the projections of five Earth system models for CMIP5 rcp45 and GeoMIP G4 scenarios to drive the WRF and CaMa-Flood models. The G4 scenario, which uses stratospheric aerosols to reduce the incoming shortwave while applying the rcp4.5 greenhouse gas forcing, starts stratospheric sulfate aerosol injection at a rate of 5 Tg per year over the period 2020-2069. The ensemble projections suggest relatively slower glacier mass loss rates and reduced river discharge at Tibetan Plateau and adjacent regions under geoengineering scenario by stratospheric aerosol injection.

Particle size distribution of the stratospheric aerosol from SCIAMACHY limb measurements

NASA Astrophysics Data System (ADS)

Rozanov, Alexei; Malinina, Elizaveta; Bovensmann, Heinrich; Burrows, John

2017-04-01

A crucial role of the stratospheric aerosols for the radiative budget of the Earth's atmosphere and the consequences for the climate change are widely recognized. A reliable knowledge on physical and optical properties of the stratospheric aerosols as well as on their vertical and spatial distributing is a key issue to assure a proper initialization and running conditions for climate models. On a global scale this information can only be gained from space borne measurements. While a series of past, present and future instruments provide extensive date sets of such aerosol characteristics as extinction coefficient or backscattering ratio, information on a size distribution of the stratospheric aerosols is sparse. One of the important sources on vertically and spatially resolved information on the particle size distribution of stratospheric aerosols is provided by space borne measurements of the scattered solar light in limb viewing geometry performed in visible, near-infrared and short-wave infrared spectral ranges. SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY) instrument operated on the European satellite Envisat from 2002 to 2102 was capable of providing spectral information needed to retrieve parameters of aerosol particle size distributions. In this presentation we discuss the retrieval method, present first validation results with SAGE II data and analyze first data sets of stratospheric aerosol particle size distribution parameters obtained from SCIAMACHY limb measurements. The research work was performed in the framework of ROMIC (Role of the middle atmosphere in climate) project.

SAGE II Measurements of Stratospheric Aerosol Properties at Non-Volcanic Levels

NASA Technical Reports Server (NTRS)

Thomason, Larry W.; Burton, Sharon P.; Luo, Bei-Ping; Peter, Thomas

2008-01-01

Since 2000, stratospheric aerosol levels have been relatively stable and at the lowest levels observed in the historical record. Given the challenges of making satellite measurements of aerosol properties at these levels, we have performed a study of the sensitivity of the product to the major components of the processing algorithm used in the production of SAGE II aerosol extinction measurements and the retrieval process that produces the operational surface area density (SAD) product. We find that the aerosol extinction measurements, particularly at 1020 nm, remain robust and reliable at the observed aerosol levels. On the other hand, during background periods, the SAD operational product has an uncertainty of at least a factor of 2 during due to the lack of sensitivity to particles with radii less than 100 nm.

The Impact of Geoengineering Aerosols on Stratospheric Temperature and Ozone

NASA Technical Reports Server (NTRS)

Heckendorn, P.; Weisenstein, D.; Fueglistaler, S.; Luo, B. P.; Rozanov, E.; Schraner, M.; Peter, T.; Thomason, L. W.

2009-01-01

Anthropogenic greenhouse gas emissions are warming the global climate at an unprecedented rate. Significant emission reductions will be required soon to avoid a rapid temperature rise. As a potential interim measure to avoid extreme temperature increase, it has been suggested that Earth's albedo be increased by artificially enhancing stratospheric sulfate aerosols. We use a 3D chemistry climate model, fed by aerosol size distributions from a zonal mean aerosol model, to simulate continuous injection of 1-10 Mt/a into the lower tropical stratosphere. In contrast to the case for all previous work, the particles are predicted to grow to larger sizes than are observed after volcanic eruptions. The reason is the continuous supply of sulfuric acid and hence freshly formed small aerosol particles, which enhance the formation of large aerosol particles by coagulation and, to a lesser extent, by condensation. Owing to their large size, these particles have a reduced albedo. Furthermore, their sedimentation results in a non-linear relationship between stratospheric aerosol burden and annual injection, leading to a reduction of the targeted cooling. More importantly, the sedimenting particles heat the tropical cold point tropopause and, hence, the stratospheric entry mixing ratio of H2O increases. Therefore, geoengineering by means of sulfate aerosols is predicted to accelerate the hydroxyl catalyzed ozone destruction cycles and cause a significant depletion of the ozone layer even though future halogen concentrations will be significantly reduced.

The Impact of Geoengineering Aerosols on Stratospheric Temperature and Ozone

NASA Technical Reports Server (NTRS)

Heckendorn, P.; Weisenstein, D.; Fueglistaler, S.; Luo, B. P.; Rozanov, E.; Schraner, M.; Thomason, L. W.; Peter, T.

2011-01-01

Anthropogenic greenhouse gas emissions are warming the global climate at an unprecedented rate. Significant emission reductions will be required soon to avoid a rapid temperature rise. As a potential interim measure to avoid extreme temperature increase, it has been suggested that Earth's albedo be increased by artificially enhancing stratospheric sulfate aerosols. We use a 3D chemistry climate model, fed by aerosol size distributions from a zonal mean aerosol model. to simulate continuous injection of 1-10 Mt/a into the lower tropical stratosphere. In contrast to the case for all previous work, the particles are predicted to grow to larger sizes than are observed after volcanic eruptions. The reason is the continuous supply of sulfuric acid and hence freshly formed small aerosol particles, which enhance the formation of large aerosol particles by coagulation and, to a lesser extent, by condensation. Owing to their large size, these particles have a reduced albedo. Furthermore, their sedimentation results in a non-linear relationship between stratospheric aerosol burden and annual injection, leading to a reduction of the targeted cooling. More importantly, the sedimenting particles heat the tropical cold point tropopause and, hence, the stratospheric entry mixing ratio of H2O increases. Therefore, geoengineering by means of sulfate aerosols is predicted to accelerate the hydroxyl catalyzed ozone destruction cycles and cause a significant depletion of the ozone layer even though future halogen concentrations will he significantly reduced.

The Many Problems with Geoengineering Using Stratospheric Aerosols

NASA Astrophysics Data System (ADS)

Robock, Alan

2009-05-01

In response to the global warming problem, there has been a recent renewed call for geoengineering ``solutions'' involving injecting particles into the stratosphere or blocking sunlight with satellites between the Sun and Earth. While volcanic eruptions have been suggested as innocuous examples of stratospheric aerosols cooling the planet, the volcano analog actually argues against geoengineering because of ozone depletion and regional hydrologic and temperature responses. In this talk, I consider the suggestion to create an artificial stratospheric aerosol layer. No systems to conduct geoengineering now exist, but a comparison of different proposed stratospheric injection schemes, airplanes, balloons, artillery, and a space elevator, shows that using airplanes would not be that expensive. We simulated the climate response to both tropical and Arctic stratospheric injection of sulfate aerosol precursors using a comprehensive atmosphere-ocean general circulation model, the National Aeronautics and Space Administration Goddard Institute for Space Studies ModelE. We simulated the injection of SO2 and the model converts it to sulfate aerosols, transports them and removes them through dry and wet deposition, and calculates the climate response to the radiative forcing from the aerosols. We conducted simulations of future climate with the Intergovernmental Panel on Climate Change A1B business-as-usual scenario both with and without geoengineering, and compare the results. We found that if there were a way to continuously inject SO2 into the lower stratosphere, it would produce global cooling. Acid deposition from the sulfate would not be enough to disturb most ecosystems. Tropical SO2 injection would produce sustained cooling over most of the world, with more cooling over continents. Arctic SO2 injection would not just cool the Arctic. But both tropical and Arctic SO2 injection would disrupt the Asian and African summer monsoons, reducing precipitation to the food supply

Aerosol physical properties in the stratosphere (APPS) radiometer design

NASA Technical Reports Server (NTRS)

Gray, C. R.; Woodin, E. A.; Anderson, T. J.; Magee, R. J.; Karthas, G. W.

1977-01-01

The measurement concepts and radiometer design developed to obtain earth-limb spectral radiance measurements for the Aerosol Physical Properties in the Stratosphere (APPS) measurement program are presented. The measurements made by a radiometer of this design can be inverted to yield vertical profiles of Rayleigh scatterers, ozone, nitrogen dioxide, aerosol extinction, and aerosol physical properties, including a Junge size-distribution parameter, and a real and imaginary index of refraction. The radiometer design provides the capacity for remote sensing of stratospheric constituents from space on platforms such as the space shuttle and satellites, and therefore provides for global measurements on a daily basis.

Stratospheric aerosols and climatic change

NASA Technical Reports Server (NTRS)

Toon, O. B.; Pollack, J. B.

1978-01-01

Stratospht1ic sulfuric acid particles scatter and absorb sunlight and they scatter, absorb and emit terrestrial thermal radiation. These interactions play a role in the earth's radiation balance and therefore affect climate. The stratospheric aerosols are perturbed by volcanic injection of SO2 and ash, by aircraft injection of SO2, by rocket exhaust of Al2O3 and by tropospheric mixing of particles and pollutant SO2 and COS. In order to assess the effects of these perturbations on climate, the effects of the aerosols on the radiation balance must be understood and in order to understand the radiation effects the properties of the aerosols must be known. The discussion covers the aerosols' effect on the radiation balance. It is shown that the aerosol size distribution controls whether the aerosols will tend to warm or cool the earth's surface. Calculations of aerosol properties, including size distribution, for various perturbation sources are carried out on the basis of an aerosol model. Calculations are also presented of the climatic impact of perturbed aerosols due to volcanic eruptions and Space Shuttle flights.

Measurements of the absorption coefficient of stratospheric aerosols

NASA Technical Reports Server (NTRS)

Ogren, J. A.; Ahlquist, N. C.; Clarke, A. D.; Charlson, R. J.

1981-01-01

The absorption coefficients of stratospheric aerosols are measured using a variation on the integrating plate method. The technique is based on the decrease in the transparency of a substrate when an absorbing aerosol is deposited on it. A Lambert scatterer is placed behind the substrate to integrate forward scattered light and minimize the effect of scattering on the measurement. The low pressure in the stratosphere is used for the direct impaction of particles onto a narrow strip of opal glass. The eight samples collected had a median value of 4 x 10 to the -9th m with an uncertainty of + or - 5 x 10 to the -9th m. If this absorption is due to graphitic carbon, then its concentration is estimated at about 0.4 ng/cu m, or about 0.25% of the total aerosol mass concentration. Estimates of the aerosol scattering coefficients based on satellite extinction inversions result in an aerosol single-scattering albedo in the range of 0.96-1.0.

Sensitivity of Stratospheric Geoengineering with Black Carbon to Aerosol Size and Altitude of Injection

NASA Technical Reports Server (NTRS)

Kravitz, Ben; Robock, Alan; Shindell, Drew T.; Miller, Mark A.

2012-01-01

Simulations of stratospheric geoengineering with black carbon (BC) aerosols using a general circulation model with fixed sea surface temperatures show that the climate effects strongly depend on aerosol size and altitude of injection. 1 Tg BC/a injected into the lower stratosphere would cause little surface cooling for large radii but a large amount of surface cooling for small radii and stratospheric warming of over 60 C. With the exception of small particles, increasing the altitude of injection increases surface cooling and stratospheric warming. Stratospheric warming causes global ozone loss by up to 50% in the small radius case. The Antarctic shows less ozone loss due to reduction of polar stratospheric clouds, but strong circumpolar winds would enhance the Arctic ozone hole. Using diesel fuel to produce the aerosols is likely prohibitively expensive and infeasible. Although studying an absorbing aerosol is a useful counterpart to previous studies involving sulfate aerosols, black carbon geoengineering likely carries too many risks to make it a viable option for deployment.

A miniature particle counter LOAC under meteorological balloon for the survey of stratospheric aerosols - comparison with other datasets

NASA Astrophysics Data System (ADS)

Vignelles, Damien; Berthet, Bwenael; Renard, Jean-Baptiste; Rieger, Landon; Bourassa, Adam; Vernier, Jean-Paul; Taha, Ghassan; Khaykin, Sergey; Lurton, Thibaut; Jegou, Fabrice; Couté, Benoît; Duverger, Vincent

2017-04-01

Stratospheric aerosols contribute to the terrestrial radiative budget during large eruptive events but also during volcanic quiescent periods (Kremser et al. 2016). The survey of background stratospheric aerosols, especially in the middle stratosphere, is challenging due to extreme experimental conditions and low particle concentration. Furthermore, during periods of low volcanic activity, origins and optical properties of aerosols in the middle and high stratosphere are not well defined yet (Neely et al. 2011). We propose to study the capabilities of a new miniature particle counter called LOAC (Light Optical Aerosol Counter), light enough to be carried under meteorological balloons, whichensure a very good frequency of flights and designed to be able to measure and discriminate between several main aerosol types. The LOAC miniature particle counter has been initially designed for balloon-borne tropospheric studies (Renard et al. 2016).Metrological performances of the LOAC instrument have been determined in the laboratory and during balloon flights. Principal limitations of the use of LOAC in the stratosphere areinduced by the temperature variations and the influence of cosmic rays. A detection threshold has been determined in the laboratory to be of 0.8 particule.cm-3 in terms of concentration which also limits the use of LOAC in the stratosphere where aerosol concentrations during volcanic quiescent periods may be lower than this limit. Since June 2013, more than 100 hundred LOAC instruments have been launched under meteorological balloons during the ChArMEx and Voltaire-LOAC field campaigns. This dataset has been studied and compared to satellite records such as OSIRIS, OMPS, and CALIOPbut also to ground-based lidar data (NDACC lidar OHP) and outputs from the WACCM/CARMA model. Results show that large variations in stratospheric aerosols are well defined by satellite but less visible in LOAC records. Instrumental LOAC limitations in the stratosphere can explain

The post-pinatubo evolution of stratospheric aerosol surface area density as inferred from SAGE 2

NASA Technical Reports Server (NTRS)

Poole, L. R.; Thomason, L. W.

1994-01-01

Following the eruption of Mount Pinatubo in June of 1991, the aerosol mass loading of the stratosphere increased from -1 Mt to approximately 30 Mt. This change in aerosol loading was responsible for numerous radiative and chemical changes observed within the stratosphere. As a result, the ability to quantify aerosol properties on a global basis during this period is important. Aerosol surface area density is a critical parameter in governing the rates of heterogeneous reactions, such as ClONO2 plus H2O yields HNO3 plus HOCl, which influence the stratospheric abundance of ozone. Following the eruption of Mt. Pinatubo, measurements by the Stratospheric Aerosol and Gas Experiment (SAGE 2) indicated that the stratospheric aerosol surface area density increased by as much as a factor of 100. Using SAGE 2 multi-wavelength aerosol extinction data, aerosol surface area density as well as mass are derived for the period following the eruption of Mt. Pinatubo through the present.

Impact of geoengineered aerosols on the troposphere and stratosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tilmes, S.; Garcia, Rolando R.; Kinnison, Douglas E.

2009-06-27

A coupled chemistry climate model, the Whole Atmosphere Community Climate Model was used to perform a transient climate simulation to quantify the impact of geoengineered aerosols on atmospheric processes. In contrast to previous model studies, the impact on stratospheric chemistry, including heterogeneous chemistry in the polar regions, is considered in this simulation. In the geoengineering simulation, a constant stratospheric distribution of volcanic-sized, liquid sulfate aerosols is imposed in the period 2020–2050, corresponding to an injection of 2 Tg S/a. The aerosol cools the troposphere compared to a baseline simulation. Assuming an Intergovernmental Panel on Climate Change A1B emission scenario, globalmore » warming is delayed by about 40 years in the troposphere with respect to the baseline scenario. Large local changes of precipitation and temperatures may occur as a result of geoengineering. Comparison with simulations carried out with the Community Atmosphere Model indicates the importance of stratospheric processes for estimating the impact of stratospheric aerosols on the Earth’s climate. Changes in stratospheric dynamics and chemistry, especially faster heterogeneous reactions, reduce the recovery of the ozone layer in middle and high latitudes for the Southern Hemisphere. In the geoengineering case, the recovery of the Antarctic ozone hole is delayed by about 30 years on the basis of this model simulation. For the Northern Hemisphere, a onefold to twofold increase of the chemical ozone depletion occurs owing to a simulated stronger polar vortex and colder temperatures compared to the baseline simulation, in agreement with observational estimates.« less

Development of the Multi-Angle Stratospheric Aerosol Radiometer (MASTAR) Instrument

NASA Astrophysics Data System (ADS)

DeLand, M. T.; Colarco, P. R.; Kowalewski, M. G.; Gorkavyi, N.; Ramos-Izquierdo, L.

2017-12-01

Aerosol particles in the stratosphere ( 15-25 km altitude), both produced naturally and perturbed by volcanic eruptions and anthropogenic emissions, continue to be a source of significant uncertainty in the Earth's energy budget. Stratospheric aerosols can offset some of the warming effects caused by greenhouse gases. These aerosols are currently monitored using measurements from the Ozone Mapping and Profiling Suite (OMPS) Limb Profiler (LP) instrument on the Suomi NPP satellite. In order to improve the sensitivity and spatial coverage of these aerosol data, we are developing an aerosol-focused compact version of the OMPS LP sensor called Multi-Angle Stratospheric Aerosol Radiometer (MASTAR) to fly on a 3U Cubesat satellite, using a NASA Instrument Incubator Program (IIP) grant. This instrument will make limb viewing measurements of the atmosphere in multiple directions simultaneously, and uses only a few selected wavelengths to reduce size and cost. An initial prototype version has been constructed using NASA GSFC internal funding and tested in the laboratory. Current design work is targeted towards a preliminary field test in Spring 2018. We will discuss the scientific benefits of MASTAR and the status of the project.

Constraining Upper Troposphere/Lower Stratosphere Aerosol Physical Processes with High-Altitude Aircraft Measurements

NASA Technical Reports Server (NTRS)

Jensen, Eric; Rosenlof, Karen H.; Thornberry, Troy

2018-01-01

Interest in a more complete understanding of the sources, composition and microphysics of stratospheric aerosol particles has intensified during recent years for several reasons: (1) small volcanic eruptions have been recognized as a driver of short-term changes in climate forcing; (2) emissions of sulfur dioxide (SO2) and other aerosol precursors have shifted to south Asia and other low latitude regions with intense vertical transport; (3) organic material has been recognized as a key contributor to lower stratospheric aerosol mass; and (4) interest in possible solar radiation management (geoengineering) through significant enhancements in stratospheric aerosols has intensified. To address stratospheric aerosol science issues, we are proposing a NASA Earth Ventures mission to NASA to provide extensive high-altitude aircraft measurements of critical gas-phase and aerosol properties at multiple locations across the planet. In this presentation, we will discuss the objectives of the proposed campaign, the measurements provided, the sampling strategy, and the modeling and analysis approaches that would be used to address specific science questions.

Stratospheric aerosol modification by supersonic transport operations with climate implications

NASA Technical Reports Server (NTRS)

Toon, O. B.; Turco, R. P.; Pollack, J. B.; Whitten, R. C.; Poppoff, I. G.; Hamill, P.

1980-01-01

The potential effects on stratospheric aerosois of supersonic transport emissions of sulfur dioxide gas and submicron size soot granules are estimated. An interactive particle-gas model of the stratospheric aerosol is used to compute particle changes due to exhaust emissions, and an accurate radiation transport model is used to compute the attendant surface temperature changes. It is shown that a fleet of several hundred supersonic aircraft, operating daily at 20 km, could produce about a 20% increase in the concentration of large particles in the stratosphere. Aerosol increases of this magnitude would reduce the global surface temperature by less than 0.01 K.

Observations of Ozone-aerosol Correlated Behaviour in the Lower Stratosphere During the EASOE Campaign

NASA Technical Reports Server (NTRS)

Digirolamo, P.; Cacciani, M.; Disarra, A.; Fiocco, G.; Fua, D.; Joergensen, T. S.; Knudsen, B.; Larsen, N.

1992-01-01

The question of possible interactions between ozone and stratospheric aerosol has been open for a long time. Measurements carried out after the Mt. Agung and El Chicon eruptions showed evidence of negative correlations between the presence of volcanic stratospheric aerosols and ozone concentration. Evidence for negative correlations in the polar winter has been also found. It is only after the discovery of the Antarctic ozone hole that catalytic effects related to low temperature heterogeneous chemistry have become the object of much investigation, now extended to the role of volcanic aerosol in the ozone reduction. These phenomena can be the object of various interpretations, not mutually exclusive, including the effect of transport, diffuse radiation as well as heterogeneous chemistry. The present paper provides preliminary results of simultaneous measurements of ozone and aerosol, carried out at Thule, Greenland, during the winter 1991-92. The European Stratospheric Ozone Experiment (EASOE) was aimed at monitoring the winter Arctic stratosphere in order to obtain a deeper insight of the ozone destruction processes taking place in the polar regions. A large amount of aerosol was injected into the lower stratosphere by the recent eruption of Volcano Pinatubo. A lidar system, already operational in Thule since November 1990, has provided detailed measurements of the stratospheric aerosol concentration during EASOE. In the same period, a large number of ozonesondes were launched. Although no PSC formation was detected over Thule, the simultaneous measurement of the stratospheric aerosol and ozone profiles give the possibility to study interactions occurring in the stratosphere between these two constituents.

High-latitude stratospheric aerosols measured by the SAM II satellite system in 1978 and 1979

NASA Technical Reports Server (NTRS)

Mccormick, M. P.; Chu, W. P.; Mcmaster, L. R.; Grams, G. W.; Hamill, P.; Steele, H. M.; Swissler, T. J.; Herman, B. M.; Pepin, T. J.; Russell, P. B.

1981-01-01

Results of the first year of data collection by the SAM (Stratospheric Aerosol Measurement) II satellite system are presented. Almost 10,000 profiles of stratospheric aerosol extinction in the Arctic and Antarctic regions are used to construct plots of weekly averaged aerosol extinction versus altitude and time and stratospheric optical depth versus time. Corresponding temperature fields are presented. These data show striking similarities in the aerosol behavior for corresponding seasons. Wintertime polar stratospheric clouds that are strongly correlated with temperature are documented. They are much more prevalent in the Antarctic stratosphere during the cold austral winter and increase the stratospheric optical depths by as much as an order of magnitude for a period of about 2 months. These clouds might represent a sink for stratospheric water vapor and must be considered in the radiative budget for this region and time.

Sulphur-rich volcanic eruptions and stratospheric aerosols

NASA Technical Reports Server (NTRS)

Rampino, M. R.; Self, S.

1984-01-01

Data from direct measurements of stratospheric optical depth, Greenland ice-core acidity, and volcanological studies are compared, and it is shown that relatively small but sulfur-rich volcanic eruptions can have atmospheric effects equal to or even greater than much larger sulfur-poor eruptions. These small eruptions are probably the most frequent cause of increased stratospheric aerosols. The possible sources of the excess sulfur released in these eruptions are discussed.

Evaluation of SAGE II and Balloon-Borne Stratospheric Aerosol Measurements: Evaluation of Aerosol Measurements from SAGE II, HALOE, and Balloonborne Optical Particle Counters

NASA Technical Reports Server (NTRS)

Hervig, Mark; Deshler, Terry; Moddrea, G. (Technical Monitor)

2002-01-01

Stratospheric aerosol measurements from the University of Wyoming balloonborne optical particle counters (OPCs), the Stratospheric Aerosol and Gas Experiment (SAGE) II, and the Halogen Occultation Experiment (HALOE) were compared in the period 1982-2000, when measurements were available. The OPCs measure aerosol size distributions, and HALOE multiwavelength (2.45-5.26 micrometers) extinction measurements can be used to retrieve aerosol size distributions. Aerosol extinctions at the SAGE II wavelengths (0.386-1.02 micrometers) were computed from these size distributions and compared to SAGE II measurements. In addition, surface areas derived from all three experiments were compared. While the overall impression from these results is encouraging, the agreement can change with latitude, altitude, time, and parameter. In the broadest sense, these comparisons fall into two categories: high aerosol loading (volcanic periods) and low aerosol loading (background periods and altitudes above 25 km). When the aerosol amount was low, SAGE II and HALOE extinctions were higher than the OPC estimates, while the SAGE II surface areas were lower than HALOE and the OPCS. Under high loading conditions all three instruments mutually agree to within 50%.

Correlative measurements of the stratospheric aerosols

NASA Astrophysics Data System (ADS)

Santer, R.; Brogniez, C.; Herman, M.; Diallo, S.; Ackerman, M.

1992-12-01

Joint experiments were organized or available during stratospheric flights of a photopolarimeter, referred to as RADIBAL (radiometer balloon). In May 1984, RADIBAL flew simultaneously with another balloonborne experiment conducted by the Institut d'Aeronomie Spatiale de Belgique (IASB), which provides multiwavelength vertical profiles of the aerosol scattering coefficient. At this time, the El Chichon layer was observable quite directly from mountain sites. A ground-based station set up at Pic du Midi allowed an extensive description of the aerosol optical properties. The IASB and the Pic du Midi observations are consistent with the aerosol properties derived from the RADIBAL measurement analysis.

Antarctic polar stratospheric aerosols: The roles of nitrates, chlorides and sulfates

NASA Technical Reports Server (NTRS)

Pueschel, R. F.; Snetsinger, K. G.; Goodman, J. K.; Ferry, G. V.; Oberbeck, V. R.; Verma, S.; Fong, W.

1988-01-01

Nitric and hydrochloric acids have been postulated to condense in the winter polar stratosphere to become an important component of polar stratospheric clouds. One implication is that the removal of NO(y) from the gas phase by this mechanism allows high Cl(x) concentrations to react with O3, because the formation of ClNO3 is inhibited. Contributions of NO3 and Cl to the stratospheric aerosol were determined during the 1987 Airborne Antarctic Ozone Experiment by testing for the presence of nitrates and chlorides in the condensed phase. Aerosol particles were collected on four 500 micron diameter gold wires, each pretreated differently to give results that were specific to certain physical and chemical aerosol properties. One wire was carbon-coated for concentration and size analyses by scanning electron microscopy; X-ray energy dispersive analyses permitted the detection of S and Cl in individual particles. Three more wires were coated with Nitron, barium chloride and silver nitrate, respectively, to detect nitrate, sulfate and chloride in aerosol particles. All three ions, viz., sulfates, nitrates and chlorides were detected in the Antarctic stratospheric aerosol. In terms of number concentrations, the aerosol was dominated by sulfates, followed by chlorides and nitrates. An inverse linear regression can be established between nitrate concentrations and ozone mixing ratio, and between temperature and nitrates.

Efficiency of aerosol collection on wires exposed in the stratosphere

NASA Technical Reports Server (NTRS)

Lem, H. Y.; Farlow, N. H.

1979-01-01

The theory of inertial impaction is briefly presented. Stratospheric aerosol research experiments were performed duplicating Wong et al. experiments. The use of the curve of inertial parameters vs particle collection efficiency, derived from Wong et al., was found to be justified. The results show that stratospheric aerosol particles of all sizes are collectible by wire impaction technique. Curves and tables are presented and used to correct particle counts for collection efficiencies less than 100%.

Stratospheric aerosols and precursor gases

NASA Technical Reports Server (NTRS)

1982-01-01

Measurements were made of the aerosol size, height and geographical distribution, their composition and optical properties, and their temporal variation with season and following large volcanic eruptions. Sulfur-bearing gases were measured in situ in the stratosphere, and studied of the chemical and physical processes which control gas-to-particle conversion were carried out in the laboratory.

An overview of geoengineering of climate using stratospheric sulphate aerosols

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rasch, Philip J.; Tilmes, S.; Turco, Richard P.

2010-01-01

We provide an overview of geoengineering by stratospheric sulphate aerosols. The state of understanding about this topic as of early 2008 is reviewed, summarizing the past 30 years of work in the area, highlighting some very recent studies using climate models, and discussing methods used to deliver sulphur species to the stratosphere. The studies reviewed here suggest that sulphate aerosols can counteract the globally averaged temperature increase associated with increasing greenhouse gases, and reduce changes to some other components of the Earth system. There are likely to be remaining regional climate changes after geoengineering, with some regions experiencing significant changesmore » in temperature or precipitation. The aerosols also serve as surfaces for heterogeneous chemistry resulting in increased ozone depletion. The delivery of sulphur species to the stratosphere in a way that will produce particles of the right size is shown to be a complex and potentially very difficult task. Two simple delivery scenarios are explored, but similar exercises will be needed for other suggested delivery mechanisms. While the introduction of the geoengineering source of sulphate aerosol will perturb the sulphur cycle of the stratosphere signicantly, it is a small perturbation to the total (stratosphere and troposphere) sulphur cycle. The geoengineering source would thus be a small contributor to the total global source of ‘acid rain’ that could be compensated for through improved pollution control of anthropogenic tropospheric sources. Some areas of research remain unexplored. Although ozone may be depleted, with a consequent increase to solar ultraviolet-B (UVB) energy reaching the surface and a potential impact on health and biological populations, the aerosols will also scatter and attenuate this part of the energy spectrum, and this may compensate the UVB enhancement associated with ozone depletion. The aerosol will also change the ratio of diffuse to direct

An overview of geoengineering of climate using stratospheric sulphate aerosols.

PubMed

Rasch, Philip J; Tilmes, Simone; Turco, Richard P; Robock, Alan; Oman, Luke; Chen, Chih-Chieh; Stenchikov, Georgiy L; Garcia, Rolando R

2008-11-13

We provide an overview of geoengineering by stratospheric sulphate aerosols. The state of understanding about this topic as of early 2008 is reviewed, summarizing the past 30 years of work in the area, highlighting some very recent studies using climate models, and discussing methods used to deliver sulphur species to the stratosphere. The studies reviewed here suggest that sulphate aerosols can counteract the globally averaged temperature increase associated with increasing greenhouse gases, and reduce changes to some other components of the Earth system. There are likely to be remaining regional climate changes after geoengineering, with some regions experiencing significant changes in temperature or precipitation. The aerosols also serve as surfaces for heterogeneous chemistry resulting in increased ozone depletion. The delivery of sulphur species to the stratosphere in a way that will produce particles of the right size is shown to be a complex and potentially very difficult task. Two simple delivery scenarios are explored, but similar exercises will be needed for other suggested delivery mechanisms. While the introduction of the geoengineering source of sulphate aerosol will perturb the sulphur cycle of the stratosphere signicantly, it is a small perturbation to the total (stratosphere and troposphere) sulphur cycle. The geoengineering source would thus be a small contributor to the total global source of 'acid rain' that could be compensated for through improved pollution control of anthropogenic tropospheric sources. Some areas of research remain unexplored. Although ozone may be depleted, with a consequent increase to solar ultraviolet-B (UVB) energy reaching the surface and a potential impact on health and biological populations, the aerosols will also scatter and attenuate this part of the energy spectrum, and this may compensate the UVB enhancement associated with ozone depletion. The aerosol will also change the ratio of diffuse to direct energy

Effect of stratospheric aerosol layers on the TOMS/SBUV ozone retrieval

NASA Technical Reports Server (NTRS)

Torres, O.; Ahmad, Zia; Pan, L.; Herman, J. R.; Bhartia, P. K.; Mcpeters, R.

1994-01-01

An evaluation of the optical effects of stratospheric aerosol layers on total ozone retrieval from space by the TOMS/SBUV type instruments is presented here. Using the Dave radiative transfer model we estimate the magnitude of the errors in the retrieved ozone when polar stratospheric clouds (PSC's) or volcanic aerosol layers interfere with the measurements. The largest errors are produced by optically thick water ice PSC's. Results of simulation experiments on the effect of the Pinatubo aerosol cloud on the Nimbus-7 and Meteor-3 TOMS products are presented.

Aerosol particle size distribution in the stratosphere retrieved from SCIAMACHY limb measurements

NASA Astrophysics Data System (ADS)

Malinina, Elizaveta; Rozanov, Alexei; Rozanov, Vladimir; Liebing, Patricia; Bovensmann, Heinrich; Burrows, John P.

2018-04-01

aerosols in the Earth's atmosphere is of a great importance in the scientific community. While tropospheric aerosol influences the radiative balance of the troposphere and affects human health, stratospheric aerosol plays an important role in atmospheric chemistry and climate change. In particular, information about the amount and distribution of stratospheric aerosols is required to initialize climate models, as well as validate aerosol microphysics models and investigate geoengineering. In addition, good knowledge of stratospheric aerosol loading is needed to increase the retrieval accuracy of key trace gases (e.g. ozone or water vapour) when interpreting remote sensing measurements of the scattered solar light. The most commonly used characteristics to describe stratospheric aerosols are the aerosol extinction coefficient and Ångström coefficient. However, the use of particle size distribution parameters along with the aerosol number density is a more optimal approach. In this paper we present a new retrieval algorithm to obtain the particle size distribution of stratospheric aerosol from space-borne observations of the scattered solar light in the limb-viewing geometry. While the mode radius and width of the aerosol particle size distribution are retrieved, the aerosol particle number density profile remains unchanged. The latter is justified by a lower sensitivity of the limb-scattering measurements to changes in this parameter. To our knowledge this is the first data set providing two parameters of the particle size distribution of stratospheric aerosol from space-borne measurements of scattered solar light. Typically, the mode radius and w can be retrieved with an uncertainty of less than 20 %. The algorithm was successfully applied to the tropical region (20° N-20° S) for 10 years (2002-2012) of SCIAMACHY observations in limb-viewing geometry, establishing a unique data set. Analysis of this new climatology for the particle size

A global space-based stratospheric aerosol climatology: 1979-2016

NASA Astrophysics Data System (ADS)

Thomason, Larry W.; Ernest, Nicholas; Millán, Luis; Rieger, Landon; Bourassa, Adam; Vernier, Jean-Paul; Manney, Gloria; Luo, Beiping; Arfeuille, Florian; Peter, Thomas

2018-03-01

We describe the construction of a continuous 38-year record of stratospheric aerosol optical properties. The Global Space-based Stratospheric Aerosol Climatology, or GloSSAC, provided the input data to the construction of the Climate Model Intercomparison Project stratospheric aerosol forcing data set (1979-2014) and we have extended it through 2016 following an identical process. GloSSAC focuses on the Stratospheric Aerosol and Gas Experiment (SAGE) series of instruments through mid-2005, and on the Optical Spectrograph and InfraRed Imager System (OSIRIS) and the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) data thereafter. We also use data from other space instruments and from ground-based, air, and balloon borne instruments to fill in key gaps in the data set. The end result is a global and gap-free data set focused on aerosol extinction coefficient at 525 and 1020 nm and other parameters on an "as available" basis. For the primary data sets, we developed a new method for filling the post-Pinatubo eruption data gap for 1991-1993 based on data from the Cryogenic Limb Array Etalon Spectrometer. In addition, we developed a new method for populating wintertime high latitudes during the SAGE period employing a latitude-equivalent latitude conversion process that greatly improves the depiction of aerosol at high latitudes compared to earlier similar efforts. We report data in the troposphere only when and where it is available. This is primarily during the SAGE II period except for the most enhanced part of the Pinatubo period. It is likely that the upper troposphere during Pinatubo was greatly enhanced over non-volcanic periods and that domain remains substantially under-characterized. We note that aerosol levels during the OSIRIS/CALIPSO period in the lower stratosphere at mid- and high latitudes is routinely higher than what we observed during the SAGE II period. While this period had nearly continuous low-level volcanic activity, it

Sulfate aerosols and polar stratospheric cloud formation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tolbert, M.A.

Before the discovery of the Antarctic ozone hole, it was generally assumed that gas-phase chemical reactions controlled the abundance of stratospheric ozone. However, the massive springtime ozone losses over Antarctica first reported by Farman et al in 1985 could not be explained on the basis of gas-phase chemistry alone. In 1986, Solomon et al suggested that chemical reactions occurring on the surfaces of polar stratospheric clouds (PSCs) could be important for the observed ozone losses. Since that time, an explosion of laboratory, field, and theoretical research in heterogeneous atmospheric chemistry has occurred. Recent work has indicated that the most importantmore » heterogeneous reaction on PSCs is ClONO[sub 2] + HCl [yields] Cl[sub 2] + HNO[sub 3]. This reaction converts inert chlorine into photochemically active Cl[sub 2]. Photolysis of Cl[sub 2] then leads to chlorine radicals capable of destroying ozone through very efficient catalytic chain reactions. New observations during the second Airborne Arctic Stratospheric Expedition found stoichiometric loss of ClONO[sub 2] and HCl in air processed by PSCs in accordance with reaction 1. Attention is turning toward understanding what kinds of aerosols form in the stratospheric, their formation mechanism, surface area, and specific chemical reactivity. Some of the latest findings, which underline the importance of aerosols, were presented at a recent National Aeronautics and Space Administration workshop in Boulder, Colorado.« less

SAM 2 Measurements of the Polar Stratospheric Aerosol, volume 2. April 1979 to October 1979

NASA Technical Reports Server (NTRS)

Mccormick, M. P.; Steele, H. M.; Hamill, P.

1982-01-01

The Stratospheric Aerosol Measurement (SAM) II sensor is abroad the Earth orbiting Nimbus 7 spacecraft proving extinction measurements of the Antarctic and Arctic stratospheric aerosol with a vertical resolution of 1 km. Representative examples and weekly averages of aerosol data and corresponding temperature profiles for the time and place of each SAM II measurement (April 29, 1979, to October 27, 1979) is presented. Contours of aerosol extinction as a function of altitude and longitude or time were plotted and weekly aerosol optical depths were calculated. Seasonal variations and variations in space (altitude and longitude) for both polar regions are easily seen. Typical values of aerosol extinction at the SAM II wavelength of 1.0 micron for the time priod were 1 to 3 x 10 to the -4th power km -1 in the main stratospheric aerosol layer. Optical depths for the stratosphere were about 0.002. Polar stratospheric clouds at altitudes between the tropopause and 20 km were observed during the Antarctic winter at various times and locations. A ready-to-use format containing a representative sample of the second 6 months of data to be used in atmospheric and climatic studies is presented.

Stratospheric ion and aerosol chemistry and possible links with cirrus cloud microphysics - A critical assessment

NASA Technical Reports Server (NTRS)

Mohnen, Volker A.

1990-01-01

Aspects of stratospheric ion chemistry and physics are assessed as they relate to aerosol formation and the transport of aerosols to upper tropospheric regions to create conditions favorable for cirrus cloud formation. It is found that ion-induced nucleation and other known phase transitions involving ions and sulfuric acid vapor are probably not efficient processes for stratospheric aerosol formation, and cannot compete with condensation of sulfuric acid on preexisting particles of volcanic or meteoritic origin which are larger than about 0.15 micron in radius. Thus, galactic cosmic rays cannot have a significant impact on stratospheric aerosol population. Changes in the stratospheric aerosol burden due to volcanos are up to two orders of magnitude larger than changes in ion densities. Thus, volcanic activity may modulate the radiative properties of cirrus clouds.

Stratospheric aerosol effects from Soufriere Volcano as measured by the SAGE satellite system

NASA Technical Reports Server (NTRS)

Mccormick, M. P.; Kent, G. S.; Yue, G. K.; Cunnold, D. M.

1982-01-01

During its April 1979 eruption series, Soufriere Volcano produced two major stratospheric plumes that the SAGE (Stratospheric Aerosol and Gas Experiment) satellite system tracked to West Africa and the North Atlantic Ocean. The total mass of these plumes, whose movement and dispersion are in agreement with those deduced from meteorological data and dispersion theory, was less than 0.5 percent of the global stratospheric aerosol burden; no significant temperature or climate perturbation is therefore expected.

Stratospheric Aerosol Effects from Soufriere Volcano as Measured by the SAGE Satellite System.

PubMed

McCormick, M P; Kent, G S; Yue, G K; Cunnold, D M

1982-06-04

During its April 1979 eruption series, Soufriere Volcano produced two major stratospheric plumes that the SAGE (Stratospheric Aerosol and Gas Experiment) satellite system tracked to West Africa and the North Atlantic Ocean. The total mass of these plumes, whose movement and dispersion are in agreement with those deduced from meteorological data and dispersion theory, was less than 0.5 percent of the global stratospheric aerosol burden; no significant temperature or climate perturbation is therefore expected.

Validation of stratospheric aerosol and gas experiments 1 and 2 satellite aerosol optical depth measurements using surface radiometer data

NASA Technical Reports Server (NTRS)

Kent, G. S.; Mccormick, M. P.; Wang, P.-H.

1994-01-01

The stratospheric aerosol measurement 2, stratospheric aerosol and gas experiment (SAGE) 1, and SAGE 2 series of solar occultation satellite instruments were designed for the study of stratospheric aerosols and gases and have been extensively validated in the stratosphere. They are also capable, under cloud-free conditions, of measuring the extinction due to aerosols in the troposphere. Such tropospheric extinction measurements have yet to be validated by appropriate lidar and in situ techniques. In this paper published atmospheric aerosol optical depth measurements, made from high-altitude observatories during volcanically quiet periods, have been compared with optical depths calculated from local SAGE 1 and SAGE 2 extinction profiles. Surface measurements from three such observatories have been used, one located in Hawaii and two within the continental United States. Data have been intercompared on a seasonal basis at wave-lenths between 0.5 and 1.0 micron and found to agree within the range of measurement errors and expected atmospheric variation. The mean rms difference between the optical depths for corresponding satellite and surface measured data sets is 29%, and the mean ratio of the optical depths is 1.09.

Interpretation of DIAL Measurements of Lower Stratospheric Ozone in Regions with Pinatubo Aerosols

NASA Technical Reports Server (NTRS)

Grant, William B.; Browell, Edward V.; Fenn, Marta A.; Butler, Carolyn F.; Brackett, Vincent G.; Veiga, Robert E.; Mayor, Shane D.; Fishman, Jack; Nganga, D.; Minga, A.

1992-01-01

The influence of volcanic aerosols on stratospheric ozone is a topic of current interest, especially with the June 15, 1991 eruption of Mt. Pinatubo in the Philippines. Lidar has been used in the past to provide aerosol profiles which could be compared with ozone profiles measured using ozonesondes to look for coincidences between volcanic aerosols and ozone decreases. The differential absorption lidar (DIAL) technique has the advantages of being able to measure ozone and aerosol profiles simultaneously as well as being able to cover large geographical regions rapidly. While there are problems associated with correcting the ozone profiles for the presence of aerosols, the corrections can be made reliably when the wavelengths are closely spaced and the Bernoulli method is applied. The DIAL measurements considered in this paper are those obtained in the tropical stratosphere in January 1992 during the Airborne Arctic Stratospheric Expedition (AASE-II). The determination of ozone profiles in the presence of Pinatubo aerosols is discussed in a companion paper.

Radiative and Chemical Response to Interactive Stratospheric Sulfate Aerosols in Fully Coupled CESM1(WACCM)

NASA Astrophysics Data System (ADS)

Mills, Michael J.; Richter, Jadwiga H.; Tilmes, Simone; Kravitz, Ben; MacMartin, Douglas G.; Glanville, Anne A.; Tribbia, Joseph J.; Lamarque, Jean-François; Vitt, Francis; Schmidt, Anja; Gettelman, Andrew; Hannay, Cecile; Bacmeister, Julio T.; Kinnison, Douglas E.

2017-12-01

We present new insights into the evolution and interactions of stratospheric aerosol using an updated version of the Whole Atmosphere Community Climate Model (WACCM). Improved horizontal resolution, dynamics, and chemistry now produce an internally generated quasi-biennial oscillation and significant improvements to stratospheric temperatures and ozone compared to observations. We present a validation of WACCM column ozone and climate calculations against observations. The prognostic treatment of stratospheric sulfate aerosols accurately represents the evolution of stratospheric aerosol optical depth and perturbations to solar and longwave radiation following the June 1991 eruption of Mount Pinatubo. We confirm the inclusion of interactive OH chemistry as an important factor in the formation and initial distribution of aerosol following large inputs of sulfur dioxide (SO2) to the stratosphere. We calculate that depletion of OH levels within the dense SO2 cloud in the first weeks following the Pinatubo eruption significantly prolonged the average initial e-folding decay time for SO2 oxidation to 47 days. Previous observational and model studies showing a 30 day decay time have not accounted for the large (30-55%) losses of SO2 on ash and ice within 7-9 days posteruption and have not correctly accounted for OH depletion. We examine the variability of aerosol evolution in free-running climate simulations due to meteorology, with comparison to simulations nudged with specified dynamics. We assess calculated impacts of volcanic aerosols on ozone loss with comparisons to observations. The completeness of the chemistry, dynamics, and aerosol microphysics in WACCM qualify it for studies of stratospheric sulfate aerosol geoengineering.

Lidar Observations of Stratospheric Aerosol Layer After the Mt. Pinatubo Volcanic Eruption

NASA Technical Reports Server (NTRS)

Nagai, Tomohiro; Uchino, Osamu; Fujimoto, Toshifumi

1992-01-01

The volcano Mt. Pinatubo located on the Luzon Island, Philippines, had explosively erupted on June 15, 1991. The volcanic eruptions such as volcanic ash, SO2 and H2O reached into the stratosphere over 30 km altitude by the NOAA-11 satellite observation and this is considered one of the biggest volcanic eruptions in this century. A grandiose volcanic eruption influences the atmosphere seriously and causes many climatic effects globally. There had been many impacts on radiation, atmospheric temperature and stratospheric ozone after some past volcanic eruptions. The main cause of volcanic influence depends on stratospheric aerosol, that stay long enough to change climate and other meteorological conditions. Therefore it is very important to watch stratospheric aerosol layers carefully and continuously. Standing on this respect, we do not only continue stratospheric aerosol observation at Tsukuba but also have urgently developed another lidar observational point at Naha in Okinawa Island. This observational station could be thought valuable since there is no lidar observational station in this latitudinal zone and it is much nearer to Mt. Pinatubo. Especially, there is advantage to link up these two stations on studying the transportation mechanism in the stratosphere. In this paper, we present the results of lidar observations at Tsukuba and Naha by lidar systems with Nd:YAG laser.

A simple method to compute the change in earth-atmosphere radiative balance due to a stratospheric aerosol layer

NASA Technical Reports Server (NTRS)

Lenoble, J.; Tanre, D.; Deschamps, P. Y.; Herman, M.

1982-01-01

A computer code was developed in terms of a three-layer model for the earth-atmosphere system, using a two-stream approximation for the troposphere and stratosphere. The analysis was limited to variable atmosphere loading by solar radiation over an unperturbed section of the atmosphere. The scattering atmosphere above a Lambertian ground layer was considered in order to derive the planar albedo and the spherical albedo. Attention was given to the influence of the aerosol optical thickness in the stratosphere, the single scattering albedo and asymmetry factor, and the sublayer albedo. Calculations were performed of the zonal albedo and the planetary radiation balance, taking into account a stratospheric aerosol layer containing H2SO4 droplets and volcanic ash. The resulting ground temperature disturbance was computed using a Budyko (1969) climate model. Local decreases in the albedo in the summer were observed in high latitudes, implying a heating effect of the aerosol. An accompanying energy loss of 23-27 W/sq m was projected, which translates to surface temperature decreases of either 1.1 and 0.45 C, respectively, for background and volcanic aerosols.

Efficient transport of tropospheric aerosol into the stratosphere via the Asian summer monsoon anticyclone

NASA Astrophysics Data System (ADS)

Yu, Pengfei; Rosenlof, Karen H.; Liu, Shang; Telg, Hagen; Thornberry, Troy D.; Rollins, Andrew W.; Portmann, Robert W.; Bai, Zhixuan; Ray, Eric A.; Duan, Yunjun; Pan, Laura L.; Toon, Owen B.; Bian, Jianchun; Gao, Ru-Shan

2017-07-01

An enhanced aerosol layer near the tropopause over Asia during the June-September period of the Asian summer monsoon (ASM) was recently identified using satellite observations. Its sources and climate impact are presently not well-characterized. To improve understanding of this phenomenon, we made in situ aerosol measurements during summer 2015 from Kunming, China, then followed with a modeling study to assess the global significance. The in situ measurements revealed a robust enhancement in aerosol concentration that extended up to 2 km above the tropopause. A climate model simulation demonstrates that the abundant anthropogenic aerosol precursor emissions from Asia coupled with rapid vertical transport associated with monsoon convection leads to significant particle formation in the upper troposphere within the ASM anticyclone. These particles subsequently spread throughout the entire Northern Hemispheric (NH) lower stratosphere and contribute significantly (˜15%) to the NH stratospheric column aerosol surface area on an annual basis. This contribution is comparable to that from the sum of small volcanic eruptions in the period between 2000 and 2015. Although the ASM contribution is smaller than that from tropical upwelling (˜35%), we find that this region is about three times as efficient per unit area and time in populating the NH stratosphere with aerosol. With a substantial amount of organic and sulfur emissions in Asia, the ASM anticyclone serves as an efficient smokestack venting aerosols to the upper troposphere and lower stratosphere. As economic growth continues in Asia, the relative importance of Asian emissions to stratospheric aerosol is likely to increase.

Effect of the eruption of El Chichon stratospheric aerosol size and composition

NASA Technical Reports Server (NTRS)

Oberbeck, V. R.; Danielsen, E. F.; Snetsinger, K. G.; Ferry, G. V.; Fong, W.; Hayes, D. M.

1983-01-01

Dominant effects of the El Chichon eruption on stratospheric aerosols at 19.8 to 20.7 km are: (1) vapor depositional growth of the small-aerosol (background) mode; (2) development of a large-particle mode by sedimentation from the highest altitudes in the cloud; (3) a change in the large-particle mode from sulfate-coated silicates to sulfate aerosols, some with silicate cores; (4) a 100-fold increase in sulfate mass in the large particle mode. Terminal velocities of large silicate particles, maximum r = 2.3 micron, sampled 1 month after eruption, and calibrated with the aid of lidar data, indicate initial injection to 26 to 27 km. Smaller velocities of sulfate aerosols, median r = 0.5 micron, are compatible with major growth in 2 to 3 months at 27 to 28 km. Aerosol settling accounts for the descent of the main lidar return to 26.5 km in August and to 20 to 21 km in December.

Small volcanic eruptions and the stratospheric sulfate aerosol burden

NASA Astrophysics Data System (ADS)

Pyle, David M.

2012-09-01

least 1.3-1.5 Tg of SO2 (Krotkov et al 2011, Clarisse et al 2012). This was probably the largest sulfur yield from an explosive eruption since Pinatubo and Hudson in 1991 (Deshler et al 2006, Krotkov et al 2010). Within two weeks, volcanic aerosol had been detected at elevations of 15-20 km within the upper troposphere/lower stratosphere above north Africa and southern Eurasia; and within a month, the aerosol had been detected by lidar instruments on every continent in the northern hemisphere, from 20°-45°N. The aerosol, presumed to be dominated by sulfate, persisted for the period of observation (June-September 2011), and led to a small but significant stratospheric aerosol optical depth (AOD) perturbation (average ~0.02). While this is an order of magnitude lower than global AOD perturbations following the most significant eruptions of the 20th century (e.g. Stothers 1996), it is nonetheless substantially larger than estimates of the typical 'nonvolcanic' stratospheric aerosol background ( < 0.01, Deshler 2008). The Nabro eruption was a particularly interesting event, partly because it was unremarkable. Without remote-sensing measurements, this eruption would probably have passed with little notice; and the geological record of this event is likely to be modest. But now we know that events of this scale still have the potential to have a hemispheric impact on the stratosphere. In this case, as both Sawamura et al (2012) and Bourassa et al (2012) show, the strong Asian summer monsoon was probably responsible for the rapid lofting of the SO2 plume into the lower stratosphere, where it was able to react to form a fine sulfate aerosol with the potential to persist for some months. Similar arguments will pertain to other geological small—but sulfur-rich—volcanic events in the past, and this calls for a reassessment of our assumptions about the potential impact of small volcanic eruptions on the stratospheric sulfate aerosol burden. References Bekki S and Pyle J A

Interactions between meteoric smoke particles and the stratospheric aerosol layer

NASA Astrophysics Data System (ADS)

Mann, G. W.; Marshall, L.; Brooke, J. S. A.; Dhomse, S.; Plane, J. M. C.; Feng, W.; Neely, R.; Bardeen, C.; Bellouin, N.; Dalvi, M.; Johnson, C.; Abraham, N. L.; Schmidt, A.; Carslaw, K. S.; Chipperfield, M.; Deshler, T.; Thomason, L. W.

2017-12-01

In-situ measurements in the Arctic, Antarctic and at mid-latitudes suggest a widespread presence of meteoric smoke particles (MSPs), as an inclusion within a distinct class of stratospheric aerosol particles. We apply the UM-UKCA stratosphere-troposphere composition-climate model, with interactive aerosol microphysics, to map the global distribution of these "meteoric-sulphuric particles" and explore the implications of their presence. Comparing to balloon-borne stratospheric aerosol measurements, we indirectly constrain the uncertain MSP flux into the upper mesosphere, and assess whether meteoric inclusion can explain observed refractory/non-volatile particle concentrations. Our experiments suggest meteoric-sulphuric particles are present at all latitudes, the Junge layer transitioning from mostly homogeneously nucleated particles at the bottom, to mostly meteoric-sulphuric particles at the top. We find MSPs exert a major influence on the quiescent Junge layer, with meteoric-sulphuric particles generally bigger than homogeneously nucleated particles, and therefore more rapidly removed into the upper troposphere. Resolving the smoke interactions weakens homogeneous nucleation in polar spring, reduces the quiescent sulphur burden, and improves comparisons to a range of different stratospheric aerosol measurements. The refractory nature of meteoric-sulphuric particles also means they "survive" ascent through the uppermost Junge layer, whereas homogeneously nucleated particles evaporate completely. Simulations through the Pinatubo-perturbed period are more realistic, with greater volcanic enhancement of effective radius, causing faster decay towards quiescent conditions, both effects matching better with observations. Overall, our experiments suggest meteoric-sulphuric particles are an important component of the Junge layer, strongly influential in both quiescent and volcanically perturbed conditions.

Evaluation of SAGE II and Balloon-Borne Stratospheric Aerosol Measurements

NASA Technical Reports Server (NTRS)

2002-01-01

Under funding from this proposal we evaluated measurements of stratospheric sulfate aerosols from three platforms. Two were satellite platforms providing solar extinction measurements, the Stratospheric Aerosol and Gas Experiment (SAGE) II using wavelengths from 0.386 - 1.02 microns, and the Halogen Occultation Experiment (HALOE) using wavelengths from 2.45 to 5.26 microns. The third set of measurements was from in situ sampling by balloonborne optical particle counters (OPCs). The goal was to determine the consistency among these data sets. This was accomplished through analysis of the existing measurement records, and through additional balloonborne OPC flights coinciding with new SAGE II observations over Laramie, Wyoming. All analyses used the SAGE II v 6.0 data. This project supported two balloon flights per year over Laramie dedicated to SAGE II coincidence. Because logistical factors, such as poor surface weather or unfavorable payload impact location, can make it difficult to routinely obtain close coincidences with SAGE II, we attempt to conduct nearly every Laramie flight (roughly one per month) in conjunction with a SAGE II overpass. The Laramie flight frequency has varied over the years depending on field commitments and funding sources. Current support for the Laramie measurements is from the National Science Foundation in addition to support from this NASA grant. We have also completed a variety of comparisons using aerosol measurements from SAGE II, OPCs, and HALOE. The instruments were compared for their various estimates of aerosol extinction at the SAGE II wavelengths and for aerosol surface area. Additional results, such as illustrated here, can be found in a recently accepted manuscript describing comparisons between SAGE II, HALOE, and OPCs for the period 1982 - 2000. While overall, the impression from these results is encouraging, the agreement of the measurements changes with latitude, altitude, time, and parameter. In the broadest sense

Satellite stratospheric aerosol measurement validation

NASA Technical Reports Server (NTRS)

Russell, P. B.; Mccormick, M. P.

1984-01-01

The validity of the stratospheric aerosol measurements made by the satellite sensors SAM II and SAGE was tested by comparing their results with each other and with results obtained by other techniques (lider, dustsonde, filter, and impactor). The latter type of comparison required the development of special techniques that convert the quantity measured by the correlative sensor (e.g. particle backscatter, number, or mass) to that measured by the satellite sensor (extinction) and quantitatively estimate the uncertainty in the conversion process. The results of both types of comparisons show agreement within the measurement and conversion uncertainties. Moreover, the satellite uncertainty is small compared to aerosol natural variability (caused by seasonal changes, volcanoes, sudden warmings, and vortex structure). It was concluded that the satellite measurements are valid.

30-year lidar observations of the stratospheric aerosol layer state over Tomsk (Western Siberia, Russia)

NASA Astrophysics Data System (ADS)

Zuev, Vladimir V.; Burlakov, Vladimir D.; Nevzorov, Aleksei V.; Pravdin, Vladimir L.; Savelieva, Ekaterina S.; Gerasimov, Vladislav V.

2017-02-01

There are only four lidar stations in the world which have almost continuously performed observations of the stratospheric aerosol layer (SAL) state over the last 30 years. The longest time series of the SAL lidar measurements have been accumulated at the Mauna Loa Observatory (Hawaii) since 1973, the NASA Langley Research Center (Hampton, Virginia) since 1974, and Garmisch-Partenkirchen (Germany) since 1976. The fourth lidar station we present started to perform routine observations of the SAL parameters in Tomsk (56.48° N, 85.05° E, Western Siberia, Russia) in 1986. In this paper, we mainly focus on and discuss the stratospheric background period from 2000 to 2005 and the causes of the SAL perturbations over Tomsk in the 2006-2015 period. During the last decade, volcanic aerosol plumes from tropical Mt. Manam, Soufrière Hills, Rabaul, Merapi, Nabro, and Kelut and extratropical (northern) Mt. Okmok, Kasatochi, Redoubt, Sarychev Peak, Eyjafjallajökull, and Grímsvötn were detected in the stratosphere over Tomsk. When it was possible, we used the NOAA HYSPLIT trajectory model to assign aerosol layers observed over Tomsk to the corresponding volcanic eruptions. The trajectory analysis highlighted some surprising results. For example, in the cases of the Okmok, Kasatochi, and Eyjafjallajökull eruptions, the HYSPLIT air mass backward trajectories, started from altitudes of aerosol layers detected over Tomsk with a lidar, passed over these volcanoes on their eruption days at altitudes higher than the maximum plume altitudes given by the Smithsonian Institution Global Volcanism Program. An explanation of these facts is suggested. The role of both tropical and northern volcanic eruptions in volcanogenic aerosol loading of the midlatitude stratosphere is also discussed. In addition to volcanoes, we considered other possible causes of the SAL perturbations over Tomsk, i.e., the polar stratospheric cloud (PSC) events and smoke plumes from strong forest fires. At least

Stratospheric Aerosol and Gas Experiment III on the International Space Station (SAGE III/ISS)

NASA Technical Reports Server (NTRS)

Gasbarre, Joseph; Walker, Richard; Cisewski, Michael; Zawodny, Joseph; Cheek, Dianne; Thornton, Brooke

2015-01-01

The Stratospheric Aerosol and Gas Experiment III on the International Space Station (SAGE III/ISS) mission will extend the SAGE data record from the ideal vantage point of the International Space Station (ISS). The ISS orbital inclination is ideal for SAGE measurements providing coverage between 70 deg north and 70 deg south latitude. The SAGE data record includes an extensively validated data set including aerosol optical depth data dating to the Stratospheric Aerosol Measurement (SAM) experiments in 1975 and 1978 and stratospheric ozone profile data dating to the Stratospheric Aerosol and Gas Experiment (SAGE) in 1979. These and subsequent data records, notably from the SAGE II experiment launched on the Earth Radiation Budget Satellite in 1984 and the SAGE III experiment launched on the Russian Meteor-3M satellite in 2001, have supported a robust, long-term assessment of key atmospheric constituents. These scientific measurements provide the basis for the analysis of five of the nine critical constituents (aerosols, ozone (O3), nitrogen dioxide (NO2), water vapor (H2O), and air density using O2) identified in the U.S. National Plan for Stratospheric Monitoring. SAGE III on ISS was originally scheduled to fly on the ISS in the same timeframe as the Meteor-3M mission, but was postponed due to delays in ISS construction. The project was re-established in 2009.

Mechanism and Kinetics of the Formation and Transport of Aerosol Particles in the Lower Stratosphere

NASA Astrophysics Data System (ADS)

Aloyan, A. E.; Ermakov, A. N.; Arutyunyan, V. O.

2018-03-01

Field and laboratory observation data on aerosol particles in the lower stratosphere are considered. The microphysics of their formation, mechanisms of heterogeneous chemical reactions involving reservoir gases (e.g., HCl, ClONO2, etc.) and their kinetic characteristics are analyzed. A new model of global transport of gaseous and aerosol admixtures in the lower stratosphere is described. The preliminary results from a numerical simulation of the formation of sulfate particles of the Junge layer and particles of polar stratospheric clouds (PSCs, types Ia, Ib, and II) are presented, and their effect on the gas and aerosol composition is analyzed.

Anthropogenic and Volcanic Contributions to the Decadal Variations of Aerosols in the Upper Troposphere and Lower Stratosphere

NASA Technical Reports Server (NTRS)

Chin, Mian; Diehl, Thomas; Bian, Huisheng; Aquila, Valentina; Colarco, Peter R.; Tan, Qian; Burrows, John P.; Krotov, Nickolay A.; Vernier, Jean P.; Lu, Zifeng;

Stratospheric Aerosols for Solar Radiation Management

NASA Astrophysics Data System (ADS)

Kravitz, Ben

SRM in the context of this entry involves placing a large amount of aerosols in the stratosphere to reduce the amount of solar radiation reaching the surface, thereby cooling the surface and counteracting some of the warming from anthropogenic greenhouse gases. The way this is accomplished depends on the specific aerosol used, but the basic mechanism involves backscattering and absorbing certain amounts of solar radiation aloft. Since warming from greenhouse gases is due to longwave (thermal) emission, compensating for this warming by reduction of shortwave (solar) energy is inherently imperfect, meaning SRM will have climate effects that are different from the effects of climate change. This will likely manifest in the form of regional inequalities, in that, similarly to climate change, some regions will benefit from SRM, while some will be adversely affected, viewed both in the context of present climate and a climate with high CO2 concentrations. These effects are highly dependent upon the means of SRM, including the type of aerosol to be used, the particle size and other microphysical concerns, and the methods by which the aerosol is placed in the stratosphere. SRM has never been performed, nor has deployment been tested, so the research up to this point has serious gaps. The amount of aerosols required is large enough that SRM would require a major engineering endeavor, although SRM is potentially cheap enough that it could be conducted unilaterally. Methods of governance must be in place before deployment is attempted, should deployment even be desired. Research in public policy, ethics, and economics, as well as many other disciplines, will be essential to the decision-making process. SRM is only a palliative treatment for climate change, and it is best viewed as part of a portfolio of responses, including mitigation, adaptation, and possibly CDR. At most, SRM is insurance against dangerous consequences that are directly due to increased surface air

Radiative and Chemical Response to Interactive Stratospheric Sulfate Aerosols in Fully Coupled CESM1(WACCM)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mills, Mike; Richter, Jadwiga; Tilmes, S.

2017-11-06

We present a new version of the Community Earth System Model, version 1 (CESM1) with the Whole Atmosphere Community Climate Model (WACCM) featuring numerous improvements that are unique among earth system models. Improved horizontal resolution, dynamics, and chemistry now provide the development of an internally generated quasi-biennial oscillation, and significant improvements to temperatures and ozone throughout the stratosphere. The prognostic treatment of stratospheric sulfate aerosols is shown to represent well the evolution of stratospheric aerosol optical depth and perturbations to solar and longwave radiation following volcanic eruptions. We identify the inclusion of interactive OH chemistry as crucial to the studymore » of aerosol formation following large inputs of SO2 to the stratosphere. We show that depletion of OH levels within the dense SO2 cloud in the first weeks following the June 1991 eruption of Mt. Pinatubo significantly prolonged the e-folding decay time for SO2 oxidation to 47 days. Previous observational and model studies showing a 30-day decay time have not accounted for the large initial losses of SO2 on ash and ice in the first 7-9 days following the eruption, and have not correctly accounted for OH depletion. The completeness of the chemistry, dynamics, and aerosol microphysics in WACCM uniquely qualify it for studies of stratospheric sulfate aerosol geoengineering.« less

A Model Simulation of Pinatubo Volcanic Aerosols in the Stratosphere

NASA Technical Reports Server (NTRS)

Zhao , Jing-xia; Turco, Richard P.; Toon, Owen B.

1995-01-01

A one-dimensional, time-dependent model is used to study the chemical, microphysical, and radiative properties of volcanic aerosols produced by the Mount Pinatubo eruption on June 15, 1991. Our model treats gas-phase sulfur photochemistry, gas-to-particle conversion of sulfur, and the microphysics of sulfate aerosols and ash particles under stratospheric conditions. The dilution and diffusion of the volcanic eruption clouds are also accounted for in these conditions. Heteromolecular homogeneous and heterogeneous binary H2SO4/H2O nucleation, acid and water condensational growth, coagulation, and gravitational sedimentation are treated in detail in the model. Simulations suggested that after several weeks, the volcanic cloud was composed mainly of sulfuric acid/water droplets produced in situ from the SO2 emissions. The large amounts of SO2 (around 20 Mt) injected into the stratosphere by the Pinatubo eruption initiated homogeneous nucleation which generated a high concentration of small H2SO4/H2O droplets. These newly formed particles grew rapidly by condensation and coagulation in the first few months and then reach their stabilized sizes with effective radii in a range between 0.3 and 0.5 micron approximately one-half year after the eruption. The predicted volcanic cloud parameters reasonably agree with measurements in term of the vertical distribution and lifetime of the volcanic aerosols, their basic microphysical structures (e.g., size distribution, concentration, mass ratio, and surface area) and radiative properties. The persistent volcanic aerosols can produce significant anomalies in the radiation field, which have important climatic consequences. The large enhancement in aerosol surface area can result in measurable global stratospheric ozone depletion.

Aerosol-associated changes in tropical stratospheric ozone following the eruption of Mount Pinatubo

NASA Technical Reports Server (NTRS)

Grant, William B.; Browell, Edward V.; Fishman, Jack; Brackett, Vincent G.; Veiga, Robert E.; Nganga, Dominique; Minga, A.; Cros, Bernard; Butler, Carolyn F.; Fenn, Marta A.

1994-01-01

The large amount of sulfuric acid aerosol formed in the stratosphere by conversion of sulfur dioxide emitted by the eruption of Mount Pinatubo (15.14 deg N, 120.35 deg E) in the Philippines around June 15, 1991, has had a pronounced effect on lower stratospheric ozone in the tropics. Measurements of stratospheric ozone in the tropics using electrochemical concentration cell (ECC) sondes before and after the eruption and the airborne UV differential absorption lidar (DIAL) system after the eruption are compared with Stratospheric Aerosol and Gas Experiment II (SAGE II) measurements from several years before the eruption and ECC sonde measurements from the year prior to the eruption to determine the resulting changes. Ozone decreases of up to 33 % compared with SAGE II climatological values were found to be directly correlated with altitude regions of enhanced aerosol loading in the 16- to 28-km range. A maximum partial-column decrease of 29 +/- Dobson units (DU) was found over the 16- to 28-km range in September 1991 along with small increases (to 5.9 +/- 2 DU) from 28 to 31.5 km. A large decrease of ozone was also found at 4 deg to 8 deg S from May to August 1992, with a maximum decrease of 33 +/- 7 DU found above Brazzaville in July. Aerosol data form the visible channel of the advanced very high resolution radiometer (AVHRR) and the visible wavelength of the UV DIAL system were used to examine the relationship between aerosol (surface area) densities and ozone changes. The tropical stratospheric ozone changes we observed in 1991 and 1992 are likely be explained by a combination of dynamical (vertical transport) perturbations, radiative perturbations on ozone photochemistry, and heterogeneous chemistry.

The Stratospheric Aerosol and Gas Experiment (SAGE) IV Pathfinder

NASA Astrophysics Data System (ADS)

Hill, C. A.; Damadeo, R. P.; Gasbarre, J. F.

2017-12-01

Stratospheric ozone has been the subject of observation and research for decades. Measurements from satellites provided data on the initial decline in the late 1970s and early 1980s that supported the adoption of the Montreal Protocol to current observations hinting at potential recovery. Adequate determination of that recovery requires continuous and, in the case of multiple instruments, overlapping data records. However, most current satellite systems are well beyond their expected lifetimes and thus, with only a few "younger" instruments available, we look towards the future of satellite observations of stratospheric ozone to develop the Stratospheric Aerosol and Gas Experiment (SAGE) IV Pathfinder. The SAGE IV Pathfinder project will develop and validate a technology demonstration that will pave the way for a future SAGE IV mission. Utilizing solar occultation imaging, SAGE IV will be capable of measuring ozone, aerosol, and other trace gas species with the same quality as previous SAGE instruments but with greatly improved pointing knowledge. Furthermore, current technological advancements allow SAGE IV to fit within a CubeSat framework and make use of commercial hardware, significantly reducing the size and cost when compared with traditional missions and enabling sustainability of future measurements.

Anthropogenic and Volcanic Contributions to the Tropospheric and Stratospheric Sulfate Aerosols

NASA Technical Reports Server (NTRS)

Chin, Mian

2011-01-01

We investigate anthropogenic and volcanic contributions to sulfate aerosol in the atmosphere through modeling and analysis of Aura data. We use a global model GOCART to simualte 502 and sulfate aerosol from 2000 to 2010 with the new anthropogenic and volcanic emission estimates to assess the origin of sulfate aerosols in the atmosphere. We will compare the model results with 502 data from OMI and MLS instrument on Aura, and aerosol vertical profiles from CALIPSO. Our goal is to understand the dec ada 1 trends of observed tropospheric and stratospheric aerosols.

Lidar investigations of thermal regime and aerosol stratification of the stratosphere over tomsk

NASA Astrophysics Data System (ADS)

Matvienko, Gennady; Marichev, Valeriy; Bochkovsky, Dmitry

2018-04-01

One of the important applications of lidar techniques is the study of thermal regime and aerosol content of the stratosphere. Such investigations in monitoring mode were started at the Institute of atmospheric optics since 1994 and are continued to date. The main attention is paid for the study of the unexpected disturbances caused by winter stratospheric warming. In this paper we present the results of the study of the vertical distribution of temperature and aerosol over Tomsk of last years.

Challenges to producing a long-term stratospheric aerosol climatology for chemistry and climate

NASA Astrophysics Data System (ADS)

Thomason, Larry; Vernier, Jean-Paul; Bourassa, Adam; Rieger, Landon; Luo, Beiping; Peter, Thomas; Arfeuille, Florian

2016-04-01

Stratospheric aerosol data sets are key inputs for climate models (GCMs, CCMs) particularly for understanding the role of volcanoes on climate and as a surrogate for understanding the potential of human-derived stratospheric aerosol as mitigation for global warming. In addition to supporting activities of individual climate models, the data sets also act as a historical input to the activities of SPARC's Chemistry-Climate Model Initiative (CCMI) and the World Climate Research Programme's Coupled Model Intercomparison Project (CMIP). One such data set was produced in 2004 as a part of the SPARC Assessment of Stratospheric Aerosol Properties (ASAP), extending from 1979 and 2004. It was primarily constructed from the Stratospheric Aerosol and Gas Experiment series of instruments but supplemented by data from other space-based sources and a number of ground-based and airborne instruments. Updates to this data set have expanded the timeframe to span from 1850 through 2014 through the inclusion of data from additional sources, such as photometer data and ice core analyses. Fundamentally, there are limitations to the reliability of the optical properties of aerosol inferred from even the most complete single instrument data sets. At the same time, the heterogeneous nature of the underlying data to this historical data set produces considerable challenges to the production of a climate data set which is both homogeneous and reliable throughout its timespan. In this presentation, we will discuss the impact of this heterogeneity showing specific examples such as the SAGE II to OSIRIS/CALIPSO transition in 2005. Potential solutions to these issues will also be discussed.

SAGE II observations of a previously unreported stratospheric volcanic aerosol cloud in the northern polar summer of 1990

NASA Technical Reports Server (NTRS)

Yue, Glenn K.; Veiga, Robert E.; Wang, Pi-Huan

1994-01-01

Analysis of aerosol extinction profiles obtained by the spaceborne SAGE II sensor reveals that there was an anomalous increase of aerosol extinction below 18.5 km at latitudes poleward of 50 deg N from July 28 to September 9, 1990. This widespread increase of aerosol extinction in the lower stratosphere was apparently due to a remote high-latitude volcanic eruption that has not been reported to date. The increase in stratospheric optical depth in the northern polar region was about 50% in August and had diminished by October 1990. This eruption caused an increase in stratospheric aerosol mass of about 0.33 x 10(exp 5) tons, assuming the aerosol was composed of sulfuric acid and water.

Modern Day Re-analysis of Pinatubo SO2 Injection, Cloud dispersion and Stratospheric Aerosols

NASA Astrophysics Data System (ADS)

Bhartia, P. K.; Krotkov, N. A.; Aquila, V.; Hughes, E. J.; Li, C.; Fisher, B. L.

2016-12-01

Cataclysmic June 15 1991 eruption of Mt. Pinatubo injected largest amount of SO2 in the lower stratosphere during the satellite era. The resulting volcanic clouds were tracked by the NASA's Nimbus 7 TOMS sensor that provided first estimates of total emissions of SO2 gas ( 15+/-3 Mt). Over time SO2 converted to long-lasting sulfate aerosols affecting radiation balance and composition of the stratosphere. Large numbers of articles and papers published in the past 25 years make this the most well-studied volcanic eruption. Still, several unresolved scientific issues remain: SO2 injection height, subsequent lofting of SO2 and aerosols in the stratosphere, how much sulfate aerosols were produced in the eruption (i.e., initial sulfate to SO2 ratio), and impact on stratospheric ozone. To answer these questions we have re-analyzed past satellite measurements using modern day tools, such as re-analyzed wind data from Goddard Modeling and Assimilation Office (GMAO), improved trajectory analysis tools, better radiative transfer model to process backscatter UV data from N7/TOMS and two NOAA SBUV/2s sensors, which provided measurements at shorter UV wavelengths that are sensitive to aerosols and SO2 in the mid stratosphere ( 25 km). We have also re-analyzed aerosol data from SAGE, AVHRR, and several instruments on the UARS satellite. These data provide strong support for recent assessment by modelers that the bulk of SO2 mass injected by the volcano was well below the 25 km altitude, contrary to earlier estimates. We also find convincing evidence that there was significant amount of sulfate aerosols embedded even in the day-old SO2 cloud. These results strongly support the hypothesis that SO2 gas self-lofted to 25 km as seeen by UARS MLS several weeks after the eruption and aerosols to 35 km, as seen by the SAGE sensor several months later.

Global microphysical simulation of stratospheric sulfate aerosol after the Mt. Pinatubo eruption

NASA Astrophysics Data System (ADS)

Sekiya, T.; Sudo, K.

2014-12-01

An explosive volcanic eruption can inject a large amount of SO2 into the stratosphere, which is oxidized to form sulfate aerosol. Such aerosol has an impact on the Earth's radiative budget by enhancing back-scattering of the solar radiation. Changes in the size distribution of the aerosol were observed after large volcanic eruptions. Representing the changes in size distribution is important for climate simulation, because the changes affect climate responses to large volcanic eruptions. This study newly developed an aerosol microphysics module and investigated changes in stratospheric sulfate aerosol after the Mt. Pinatubo eruption in the framework of a chemistry-aerosol coupled climate model MIROC-CHASER/SPRINTARS. The module represents aerosol size distribution with three lognormal modes (nucleation, Aitken, and accumulation modes) and includes nucleation, condensation growth/evaporation, and coagulation processes. As a model evaluation, we tested reproducibility of the impacts of the Mt. Pinatubo eruption. We carried out a simulation, in which 20 Mt of SO2 and 100 Mt of volcanic ash were injected respectively into 25 km and 16—22 km altitudes over Mt. Pinatubo (120.4°E, 15.1°N) on June 15th 1991. We compared the model results with space-borne and balloon-borne observations. Although our model overestimated a near-global mean (60°N—60°S) of stratospheric aerosol optical depth (SAOD) observed by SAGE II instrument until one year after the eruption, it reproduced the observed SAOD in the subsequent period. The model well captured the observed increase of effective radius at 20 km altitude in the northern midlatitudes. In addition, we analyzed the pathway of volcanic sulfur from SO2 to sulfate aerosol. The most amount of the volcanic sulfur was converted from SO2 to accumulation mode aerosol by 100 days after the eruption. The conversion into the accumulation mode aerosol is attributable to coagulation until the first 14 days and to condensation growth

A global, space-based stratospheric aerosol climatology: 1979 to 2014

NASA Astrophysics Data System (ADS)

Thomason, L. W.; Vernier, J. P.; Bourassa, A. E.; Millan, L.; Manney, G. L.

2016-12-01

Herein, we report on a global space-based stratospheric aerosol climatology (GloSSAC) that has been developed to support Coupled Model Intercomparison Project Phase 6 (CMIP6) (REF to CMIP6 and ETH work). GloSSAC is most closely related to the ASAP[SPARC, 2006] and CCMI data sets and follows a similar approach used to produce those data sets. It is primarily built using space-based measurements by a number of instruments including the SAGE series, OSIRIS, CALIPSO, CLAES and HALOE. The data set is presented as monthly depictions for 80S to 80N and from at least the tropopause to 40 km. The data set consists primarily of measurements by the instruments at their native wavelength and measurement type (e.g., extinction coefficient). However, every bin in these monthly grids receives measured or indirectly inferred values for aerosol extinction coefficient at 525 and 1020 nm. Generally, bins where no data are available are filled via simple linear interpolation in time only. The exceptions are in the SAGE I/II gap from 1982 to 1984 where data from SAM II and ground-based and airborne lidar data sets are used to span the 3 years between the end of the SAGE I mission in November 1981 and the beginning of the SAGE II mission in October 1984. Ground-based lidar also supplements space-based data in the months following the Pinatubo eruption when much of the lower stratosphere is too optically opaque for occultation measurements. This data set includes total aerosol surface area density and volume estimates based on Thomason et al.[2008] though these should be interpreted as bounding values (low and high) rather than functional aerosol parameters that are generally produced from this and predecessor data sets by other parties. Unlike previous versions of this data set, GloSSAC has been permanently archived at NASA's Atmospheric Science Data Center and a digital object identifier (doi) for GloSSAC is available. SPARC (2006), Assessment of Stratospheric Aerosol Properties (ASAP

Changing transport processes in the stratosphere by radiative heating of sulfate aerosols

NASA Astrophysics Data System (ADS)

Niemeier, Ulrike; Schmidt, Hauke

2017-12-01

The injection of sulfur dioxide (SO2) into the stratosphere to form an artificial stratospheric aerosol layer is discussed as an option for solar radiation management. Sulfate aerosol scatters solar radiation and absorbs infrared radiation, which warms the stratospheric sulfur layer. Simulations with the general circulation model ECHAM5-HAM, including aerosol microphysics, show consequences of this warming, including changes of the quasi-biennial oscillation (QBO) in the tropics. The QBO slows down after an injection of 4 Tg(S) yr-1 and completely shuts down after an injection of 8 Tg(S) yr-1. Transport of species in the tropics and sub-tropics depends on the phase of the QBO. Consequently, the heated aerosol layer not only impacts the oscillation of the QBO but also the meridional transport of the sulfate aerosols. The stronger the injection, the stronger the heating and the simulated impact on the QBO and equatorial wind systems. With increasing injection rate the velocity of the equatorial jet streams increases, and the less sulfate is transported out of the tropics. This reduces the global distribution of sulfate and decreases the radiative forcing efficiency of the aerosol layer by 10 to 14 % compared to simulations with low vertical resolution and without generated QBO. Increasing the height of the injection increases the radiative forcing only for injection rates below 10 Tg(S) yr-1 (8-18 %), a much smaller value than the 50 % calculated previously. Stronger injection rates at higher levels even result in smaller forcing than the injections at lower levels.

Thermal infrared properties of Titan's stratospheric aerosol

NASA Technical Reports Server (NTRS)

Samuelson, Robert E.; Mayo, Louis A.

1991-01-01

The monotonic increase with wavenumber of stratospheric IR opacities in the north polar neighborhood of Titan, in the 250-600/cm bandpass, becomes more extreme with decreasing altitude, consistent with an opacity that is primarily dependent on a high altitude photochemical aerosol, on the one hand, but which is moderated by condensed organics at lower altitudes. Because condensates exhibit a wavenumber dependence for opacity which is the opposite of that required, it is suggested that condensed nitriles may be prominent; either of these condensates may be acceptable for sufficiently large particles. While comparisons with low-latitude data indicate no clear dependence of vertically-integrated opacity on latitude above 80 km, indications of a particle size and/or composition gradient with latitude in the lower stratosphere are noted.

Modifications of the Quasi-biennial Oscillation by a Geoengineering Perturbation of the Stratospheric Aerosol Layer

NASA Technical Reports Server (NTRS)

Aquila, V.; Garfinkel, C. I.; Newman, P. A.; Oman, L. D.; Waugh, D. W.

2014-01-01

This paper examines the impact of geoengineering via stratospheric sulfate aerosol on the quasi-biennial oscillation (QBO) using the NASA Goddard Earth Observing System (GEOS-5) Chemistry Climate Model. We performed four 30-year simulations with a continuous injection of sulfur dioxide on the equator at 0 degree longitude. The four simulations differ by the amount of sulfur dioxide injected (5Tg per year and 2.5 Tg per year) and the altitude of the injection (16km-25km and 22km-25km). We find that such an injection dramatically alters the quasi-biennial oscillation, prolonging the phase of easterly shear with respect to the control simulation. In the case of maximum perturbation, i.e. highest stratospheric aerosol burden, the lower tropical stratosphere is locked into a permanent westerly QBO phase. This locked QBO westerly phase is caused by the increased aerosol heating and associated warming in the tropical lower stratosphere.

Long-range transport of stratospheric aerosols in the Southern Hemisphere following the 2015 Calbuco eruption

NASA Astrophysics Data System (ADS)

Bègue, Nelson; Vignelles, Damien; Berthet, Gwenaël; Portafaix, Thierry; Payen, Guillaume; Jégou, Fabrice; Benchérif, Hassan; Jumelet, Julien; Vernier, Jean-Paul; Lurton, Thibaut; Renard, Jean-Baptiste; Clarisse, Lieven; Duverger, Vincent; Posny, Françoise; Metzger, Jean-Marc; Godin-Beekmann, Sophie

2017-12-01

After 43 years of inactivity, the Calbuco volcano, which is located in the southern part of Chile, erupted on 22 April 2015. The space-time evolutions (distribution and transport) of its aerosol plume are investigated by combining satellite (CALIOP, IASI, OMPS), in situ aerosol counting (LOAC OPC) and lidar observations, and the MIMOSA advection model. The Calbuco aerosol plume reached the Indian Ocean 1 week after the eruption. Over the Reunion Island site (21° S, 55.5° E), the aerosol signal was unambiguously enhanced in comparison with background conditions, with a volcanic aerosol layer extending from 18 to 21 km during the May-July period. All the data reveal an increase by a factor of ˜ 2 in the SAOD (stratospheric aerosol optical depth) with respect to values observed before the eruption. The aerosol mass e-folding time is approximately 90 days, which is rather close to the value ( ˜ 80 days) reported for the Sarychev eruption. Microphysical measurements obtained before, during, and after the eruption reflecting the impact of the Calbuco eruption on the lower stratospheric aerosol content have been analyzed over the Reunion Island site. During the passage of the plume, the volcanic aerosol was characterized by an effective radius of 0.16 ± 0.02 µm with a unimodal size distribution for particles above 0.2 µm in diameter. Particle concentrations for sizes larger than 1 µm are too low to be properly detected by the LOAC OPC. The aerosol number concentration was ˜ 20 times higher that observed before and 1 year after the eruption. According to OMPS and lidar observations, a tendency toward conditions before the eruption was observed by April 2016. The volcanic aerosol plume is advected eastward in the Southern Hemisphere and its latitudinal extent is clearly bounded by the subtropical barrier and the polar vortex. The transient behavior of the aerosol layers observed above Reunion Island between May and July 2015 reflects an inhomogeneous spatio

A sensitivity analysis of volcanic aerosol dispersion in the stratosphere. [Mt. Fuego, Guatemala eruptions

NASA Technical Reports Server (NTRS)

Butler, C. F.

1979-01-01

A computer sensitivity analysis was performed to determine the uncertainties involved in the calculation of volcanic aerosol dispersion in the stratosphere using a 2 dimensional model. The Fuego volcanic event of 1974 was used. Aerosol dispersion processes that were included are: transport, sedimentation, gas phase sulfur chemistry, and aerosol growth. Calculated uncertainties are established from variations in the stratospheric aerosol layer decay times at 37 latitude for each dispersion process. Model profiles are also compared with lidar measurements. Results of the computer study are quite sensitive (factor of 2) to the assumed volcanic aerosol source function and the large variations in the parameterized transport between 15 and 20 km at subtropical latitudes. Sedimentation effects are uncertain by up to a factor of 1.5 because of the lack of aerosol size distribution data. The aerosol chemistry and growth, assuming that the stated mechanisms are correct, are essentially complete in several months after the eruption and cannot explain the differences between measured and modeled results.

Arctic climate response to geoengineering with stratospheric sulfate aerosols

NASA Astrophysics Data System (ADS)

McCusker, K. E.; Battisti, D. S.; Bitz, C. M.

2010-12-01

Recent warming and record summer sea-ice area minimums have spurred expressions of concern for arctic ecosystems, permafrost, and polar bear populations, among other things. Geoengineering by stratospheric sulfate aerosol injections to deliberately cancel the anthropogenic temperature rise has been put forth as a possible solution to restoring Arctic (and global) climate to modern conditions. However, climate is particularly sensitive in the northern high latitudes, responding easily to radiative forcing changes. To that end, we explore the extent to which tropical injections of stratospheric sulfate aerosol can accomplish regional cancellation in the Arctic. We use the Community Climate System Model version 3 global climate model to execute simulations with combinations of doubled CO2 and imposed stratospheric sulfate burdens to investigate the effects on high latitude climate. We further explore the sensitivity of the polar climate to ocean dynamics by running a suite of simulations with and without ocean dynamics, transiently and to equilibrium respectively. We find that, although annual, global mean temperature cancellation is accomplished, there is over-cooling on land in Arctic summer, but residual warming in Arctic winter, which is largely due to atmospheric circulation changes. Furthermore, the spatial extent of these features and their concurrent impacts on sea-ice properties are modified by the inclusion of ocean dynamical feedbacks.

Condensed nitrate, sulfate, and chloride in Antarctic stratospheric aerosols

NASA Technical Reports Server (NTRS)

Pueschel, R. F.; Snetsinger, K. G.; Toon, O. B.; Ferry, G. V.; Oberbeck, V. R.; Starr, W. L.; Chan, K. R.; Goodman, J. K.

1989-01-01

The 1987 Airborne Antarctic Ozone Experiment, in which the NO3, Cl, and SO4 contents of stratospheric aerosols were estimated, is discussed. The aerosol size and chemical composition measurements were carried out on samples collected during August 17 to September 4, 1987. The data indicate that condensed nitrate is found below a threshold temperature of 193.6 + or - 3.0 K, which is generally found at latitudes exceeding 64 deg S. A negative correlation exists between condensed nitrate and ozone correlation.

Aerosol measurements in the winter/spring Antarctic stratosphere. I - Correlative measurements with ozone. II - Impact on polar stratospheric cloud theories

NASA Technical Reports Server (NTRS)

Hofmann, D. J.; Rosen, J. M.; Harder, J. W.

1988-01-01

Aerosol measurements collected from August 25-November 3, 1986 at McMurdo Station using balloon-borne optical particle counters are examined in order to study the relationship between aerosol and ozone distribution and the formation of polar stratospheric clouds (PSCs). Ozone, aerosol, and condensation nuclei profiles, and pressure, temperature, and humidity measurements are analyzed. It is observed that the height of the stratospheric sulfate layer decreases over the period of measurement suggesting that upwelling in the votex is not important in the zone depletion process. Three theories on PSC formation are described, and the effects of the aerosol measurements on the theories are considered. The three theories are: (1) the original theory of water vapor pressure over a solution of H2SO4 of Steele et al. (1983) and Hamill and Mc Master (1984); (2) the nitric acid theory of PSCs of Toon et al. (1986) and Hamill et al. (1986); and (3) the quasi-cirrus cloud theory of Heymsfield (1986).

The NASA-Ames Research Center stratospheric aerosol model. 2. Sensitivity studies and comparison with observatories

NASA Technical Reports Server (NTRS)

Toon, O. B.; Turco, R. P.; Hamill, P.; Kiang, C. S.; Whitten, R. C.

1979-01-01

Sensitivity tests were performed on a one-dimensional, physical-chemical model of the unperturbed stratospheric aerosols, and model calculations were compared with observations. The tests and comparisons suggest that coagulation controls the particle number mixing ratio, although the number of condensation nuclei at the tropopause and the diffusion coefficient at high altitudes are also important. The sulfur gas source strength and the aerosol residence time are much more important than the supply of condensation nuclei in establishing mass and large particle concentrations. The particle size is also controlled mainly by gas supply and residence time. In situ observations of the aerosols and laboratory measurements of aerosols, parameters that can provide further information about the physics and chemistry of the stratosphere and the aerosols found there are provided.

Stratospheric aerosol acidity, density, and refractive index deduced from SAGE 2 and NMC temperature data

NASA Technical Reports Server (NTRS)

Yue, G. K.; Poole, L. R.; Wang, P.-H.; Chiou, E. W.

1994-01-01

Water vapor concentrations obtained by the Stratospheric Aerosol and Gas Experiment 2 (SAGE 2) and collocated temperatures provided by the National Meteorological Center (NMC) from 1986 to 1990 are used to deduce seasonally and zonally averaged acidity, density, and refractive index of stratospheric aerosols. It is found that the weight percentage of sulfuric acid in the aerosols increases from about 60 just above the tropopause to about 86 at 35 km. The density increases from about 1.55 to 1.85 g/cu cm between the same altitude limits. Some seasonal variations of composition and density are evident at high latitudes. The refractive indices at 1.02, 0.694, and 0.532 micrometers increase, respectively, from about 1.425, 1.430, and 1.435 just above the tropopause to about 1.445, 1.455, and 1.458 at altitudes above 27 km, depending on the season and latitude. The aerosol properties presented can be used in models to study the effectiveness of heterogeneous chemistry, the mass loading of stratospheric aerosols, and the extinction and backscatter of aerosols at different wavelengths. Computed aerosol surface areas, rate coefficients for the heterogeneous reaction ClONO2 + H2O yields HOCl + HNO3 and aerosol mass concentrations before and after the Pinatubo eruption in June 1991 are shown as sample applications.

Surface-based observations of volcanic emissions to the stratosphere

NASA Astrophysics Data System (ADS)

Hofmann, Dave; Barnes, John; Dutton, Ellsworth; Deshler, Terry; Jäger, Horst; Keen, Richard; Osborn, Mary

Long-term, surface-based observations of the stratospheric aerosol layer are presented and compared. These include three LIDAR aerosol backscatter measurements, at Mauna Loa Observatory (Hawaii), Langley Research Center (Virginia), and Garmisch-Partenkirchen (Germany); balloonborne in situ particle concentration measurements at Laramie, Wyoming, solar visible transmission measurements at Mauna Loa Observatory; aerosol optical depth measurements at South Pole Station and Mauna Loa Observatory; and lunar eclipse optical depth determinations, which is a globally integrating technique. Surface-based measurements have provided a useful historical record of volcanic effects on the stratospheric aerosol and the agreement between the various techniques is very good. However, some uncertainties exist when the stratosphere is relatively free of volcanic aerosol and some of the techniques are not able to easily resolve the very small amount of aerosol from natural and/or anthropogenic sources. The lunar eclipse data, which go back to the late 1800s, suggest that the Pinatubo eruption in 1991 probably perturbed the stratospheric aerosol layer at least as much as that of Krakatau in 1883. This is an important observation as it is one of the few ways to accurately compare the stratospheric effects of eruptions prior to modern measurements that began in the late 1950s. At the time of this writing (September 2002) the stratosphere appears to be at background with the lowest level of aerosol observed since the layer was discovered in 1959.

Stratospheric aerosol geoengineering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robock, Alan

2015-03-30

The Geoengineering Model Intercomparison Project, conducting climate model experiments with standard stratospheric aerosol injection scenarios, has found that insolation reduction could keep the global average temperature constant, but global average precipitation would reduce, particularly in summer monsoon regions around the world. Temperature changes would also not be uniform; the tropics would cool, but high latitudes would warm, with continuing, but reduced sea ice and ice sheet melting. Temperature extremes would still increase, but not as much as without geoengineering. If geoengineering were halted all at once, there would be rapid temperature and precipitation increases at 5–10 times the rates frommore » gradual global warming. The prospect of geoengineering working may reduce the current drive toward reducing greenhouse gas emissions, and there are concerns about commercial or military control. Because geoengineering cannot safely address climate change, global efforts to reduce greenhouse gas emissions and to adapt are crucial to address anthropogenic global warming.« less

Annual variations of water vapor in the stratosphere and upper troposphere observed by the Stratospheric Aerosol and Gas Experiment II

NASA Technical Reports Server (NTRS)

Mccormick, M. P.; Chiou, E. W.; Mcmaster, L. R.; Chu, W. P.; Larsen, J. C.; Rind, D.; Oltmans, S.

1993-01-01

Data collected by the Stratospheric Aerosol and Gas Experiment II are presented, showing annual variations of water vapor in the stratosphere and the upper troposphere. The altitude-time cross sections of water vapor were found to exhibit annually repeatable patterns in both hemispheres, with a yearly minimum in water vapor appearing in both hemispheres at about the same time, supporting the concept of a common source for stratospheric dry air. A linear regression analysis was applied to the three-year data set to elucidate global values and variations of water vapor ratio.

Volcanic-aerosol-induced changes in stratospheric ozone following the eruption of Mount Pinatubo

NASA Technical Reports Server (NTRS)

Grant, W. B.; Browell, E. V.; Fishman, J.; Brackett, V. G.; Fenn, M. A.; Butler, C. F.; Nganga, D.; Minga, A.; Cros, B.; Mayor, S. D.

1994-01-01

Measurements of lower stratospheric ozone in the Tropics using electrochemical concentrations cell (ECC) sondes and the airborne UV Differential Absorption Lidar (DIAL) system after the eruption of Mt. Pinatubo are compared with the Stratospheric Aerosol and Gas Experiment 2 (SAGE 2) and ECC sonde measurements from below the eruption to determine what changes have occurred as a result. Aerosol data from the Advanced Very High Resolution Radiometer (AVHRR) and the visible and IR wavelengths of the lidar system are used to examine the relationship between aerosols and ozone changes. Ozone decreases of 30 percent at altitudes between 19 and 26 km, partial column (16-28 km) decreases of about 27 D.U., and slight increases (5.4 D.U.) between 28 and 31 km are found in comparison with SAGE 2 climatological values.

Volcanic eruptions and the increases in the stratospheric aerosol content: Lidar measurements from 1982 to 1986

NASA Technical Reports Server (NTRS)

Hayashida, S.; Iikura, Y.; Shimizu, H.; Sasano, Y.; Nakane, H.; Sugimoto, N.; Matsui, I.; Takeuchi, N.

1986-01-01

The results of the observation for stratospheric aerosols which were carried out since the autumn of 1982 by using the NIES large lidar are described. Specifications of the lidar system are shown. The lidar has two wavelenghts of 1.06 and 0.53 micrometers. The 0.53 micrometer is mainly used for the stratospheric aerosols, because the PMT for 0.53 micrometers has higher sensitivity that that for 1.06 micrometers and the total efficiency is higher in the former. A switching circuit is used to control the PMT gain for avoiding signal induced noise in PMT. For the last four years, the stratospheric aerosol layer which was significantly perturbed by the El Chichon volcanic eruption was observed. The scattering ratio profiles observed from 1982 through 1983 are given.

The influence of volcanic stratospheric aerosols on interannual global climate variations. Ph.D. Thesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andsager, K.M.

A qualitative physical mechanism has been proposed to explain the forcing of the EI Nino/Southern Oscillation (ENSO) by low-latitude volcanic stratospheric aerosols. This mechanism is based on the normal global annual cycle resulting from the normal annual cycle in the distribution of incoming solar radiation. The presence of a volcanic stratospheric aerosol, which backscatters incoming solar radiation, is hypothesized to trigger the ENSO through an amplification of the normal annual decrease in wind strength and corresponding increase in sea surface temperatures (SST) in the eastern tropical Pacific Ocean. The observational evidence for an association between the record of volcanic eruptionsmore » and SST and the Southern Oscillation Index (SOI, Tahiti SLP minus Darwin SLP) over the last 120 years is examined using superposed epoch analysis. Composites using as key dates low-latitude volcanic eruptions suggest that these eruptions are followed by statistically significantly warm sea surface temperatures at least at the 1 percent level, if not higher, with the greatest warming generally occurring in the first three seasons after the eruption. Satellite data on the distribution of recent volcanic aerosols suggests that an aerosol must only be present over the tropics (about 20 deg S to 20 deg N) to trigger an ENSO event. For the physical mechanism by which an ENSO event may be triggered by a volcanic stratospheric aerosol, these results and the results of recent computer modeling studies imply the need for a shift away from past emphasis on surface cooling and SLP anomalies and toward consideration of stratospheric warming and changes in energy storage and transport.« less

Lidar Measurements of Aerosol and Ozone Distributions During the 1992 Airborne Arctic Stratospheric Expedition

NASA Technical Reports Server (NTRS)

Browell, E. V.; Butler, C. F.; Fenn, M. A.; Grant, W. B.; Carter, A. F.

1992-01-01

The LaRC airborne lidar system was operated from the ARC DC-8 aircraft during the 1992 Airborne Arctic Stratospheric Expedition (ASEE-2) to investigate the distribution of stratospheric aerosols and O3 across the Arctic vortex from Jan. to Mar. 1992. Monthly flights were made across the Arctic vortex from Anchorage, Alaska, to Stavanger, Norway, and then back to Bangor, Maine, and additional round-trip flights north into the vortex were made each month from either Stavanger or Bangor depending on the location of the vortex that month. The airborne lidar system uses the differential absorption lidar (DIAL) technique at laser wavelengths of 301.5 and 310.8 nm to measure O3 profiles above the DC-8 over the 12-25 km altitude range. Lidar measurements of aerosol backscatter and depolarization profiles over the 12-30 km altitude range are made simultaneously with the O3 measurements using infrared (IR) and visible (VIS) laser wavelengths of 603 and 1064 nm, respectively. The measurements of Pinatubo aerosols, polar stratospheric clouds, and O3 made with the airborne DIAL system during the AASE-2 expedition and to chemical and dynamical process that contribute to O3 depletion in the wintertime Arctic stratosphere.

Temperature dependence of the formation of sulfate aerosols in the stratosphere

NASA Technical Reports Server (NTRS)

Yue, G. K.; Deepak, A.

1982-01-01

Classical nucleation theory is used in calculations of the temperature dependence of the characteristics and nucleation rates of sulfate aerosols in the binary H2SO4-H2O vapor mixture, in order to assess the influence of temperature on the formation of sulfate aerosols in the stratosphere, and to explore the possibility of new particle formation through homogeneous nucleation processes at regions where temperature is as low as -75 C, rather than the often-assumed -50 or -55 C. Calculation results indicate that the number of particles formed at a lower temperature is larger by several orders of magnitude than at higher temperatures, when water and sulfuric acid vapor concentrations are kept constant, and that large quantities of ultrafine particles which cannot be detected by conventional methods may exist at low-temperature stratospheric regions.

First Simulations of Designing Stratospheric Sulfate Aerosol Geoengineering to Meet Multiple Simultaneous Climate Objectives: DESIGNING STRATOSPHERIC GEOENGINEERING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kravitz, Ben; MacMartin, Douglas G.; Mills, Michael J.

We describe the first simulations of stratospheric sulfate aerosol geoengineering using multiple injection locations to meet multiple simultaneous surface temperature objectives. Simulations were performed using CESM1(WACCM), a coupled atmosphere-ocean general circulation model with fully interactive stratospheric chemistry, dynamics (including an internally generated quasi-biennial oscillation), and a sophisticated treatment of sulfate aerosol formation, microphysical growth, and deposition. The objectives are defined as maintaining three temperature features at their 2020 levels against a background of the RCP8.5 scenario over the period 2020-2099. These objectives are met using a feedback mechanism in which the rate of sulfur dioxide injection at each of themore » four locations is adjusted independently every year of simulation. Even in the presence of uncertainties, nonlinearities, and variability, the objectives are met, predominantly by SO2 injection at 30°N and 30°S. By the last year of simulation, the feedback algorithm calls for a total injection rate of 51 Tg SO2 per year. The injections are not in the tropics, which results in a greater degree of linearity of the surface climate response with injection amount than has been found in many previous studies using injection at the equator. Because the objectives are defined in terms of annual mean temperature, the required geeongineering results in "overcooling" during summer and "undercooling" during winter. The hydrological cycle is also suppressed as compared to the reference values corresponding to the year 2020. The demonstration we describe in this study is an important step toward understanding what geoengineering can do and what it cannot do.« less

Development of algorithms for using satellite meteorological data sets to study global transport of stratospheric aerosols and ozone

NASA Technical Reports Server (NTRS)

Want, P. H.; Deepak, A.

1985-01-01

The utilization of stratospheric aerosol and ozone measurements obtained from the NASA developed SAM II and SAGE satellite instruments were investigated for their global scale transports. The stratospheric aerosols showed that during the stratospheric warming of the winter 1978 to 1979, the distribution of the zonal mean aerosol extinction ratio in the northern high latitude exhibited distinct changes. Dynamic processes might have played an important role in maintenance role in maintenance of this zonal mean distribution. As to the stratospheric ozone, large poleward ozone transports are shown to occur in the altitude region from 24 km to 38 km near 55N during this warming. This altitude region is shown to be a transition region of the phase relationship between ozone and temperature waves from an in-phase one above 38 km. It is shown that the ozone solar heating in the upper stratosphere might lead to enhancement of the damping rate of the planetary waves due to infrared radiation alone in agreement with theoretical analyses and an earlier observational study.

Intercomparison of stratospheric water vapor observed by satellite experiments - Stratospheric Aerosol and Gas Experiment II versus Limb Infrared Monitor of the Stratosphere and Atmospheric Trace Molecule Spectroscopy

NASA Technical Reports Server (NTRS)

Chiou, E. W.; Mccormick, M. P.; Mcmaster, L. R.; Chu, W. P.; Larsen, J. C.; Rind, D.; Oltmans, S.

1993-01-01

A comparison is made of the stratospheric water vapor measurements made by the satellite sensors of the Stratospheric Aerosol and Gas Experiment II (SAGE II), the Nimbus-7 LIMS, and the Spacelab 3 Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment. It was found that, despite differences in the measurement techniques, sampling bias, and observational periods, the three experiments have disclosed a generally consistent pattern of stratospheric water vapor distribution. The only significant difference occurs at high southern altitudes in May below 18 km, where LIMS measurements were 2-3 ppmv greater than those of SAGE II and ATMOS.

The impact of volcanic aerosol on the Northern Hemisphere stratospheric polar vortex: mechanisms and sensitivity to forcing structure

NASA Astrophysics Data System (ADS)

Toohey, M.; Krüger, K.; Bittner, M.; Timmreck, C.; Schmidt, H.

2014-12-01

Observations and simple theoretical arguments suggest that the Northern Hemisphere (NH) stratospheric polar vortex is stronger in winters following major volcanic eruptions. However, recent studies show that climate models forced by prescribed volcanic aerosol fields fail to reproduce this effect. We investigate the impact of volcanic aerosol forcing on stratospheric dynamics, including the strength of the NH polar vortex, in ensemble simulations with the Max Planck Institute Earth System Model. The model is forced by four different prescribed forcing sets representing the radiative properties of stratospheric aerosol following the 1991 eruption of Mt. Pinatubo: two forcing sets are based on observations, and are commonly used in climate model simulations, and two forcing sets are constructed based on coupled aerosol-climate model simulations. For all forcings, we find that simulated temperature and zonal wind anomalies in the NH high latitudes are not directly impacted by anomalous volcanic aerosol heating. Instead, high-latitude effects result from enhancements in stratospheric residual circulation, which in turn result, at least in part, from enhanced stratospheric wave activity. High-latitude effects are therefore much less robust than would be expected if they were the direct result of aerosol heating. Both observation-based forcing sets result in insignificant changes in vortex strength. For the model-based forcing sets, the vortex response is found to be sensitive to the structure of the forcing, with one forcing set leading to significant strengthening of the polar vortex in rough agreement with observation-based expectations. Differences in the dynamical response to the forcing sets imply that reproducing the polar vortex responses to past eruptions, or predicting the response to future eruptions, depends on accurate representation of the space-time structure of the volcanic aerosol forcing.

Lidar measurements of stratospheric aerosols over Menlo Park, California, October 1972 - March 1974

NASA Technical Reports Server (NTRS)

Russell, P. B.; Viezee, W.; Hake, R. D.

1974-01-01

During an 18-month period, 30 nighttime observations of stratospheric aerosols were made using a ground based ruby lidar located near the Pacific coast of central California (37.5 deg. N, 122.2 deg. W). Vertical profiles of the lidar scattering ratio and the particulate backscattering coefficient were obtained by reference to a layer of assumed negligible particulate content. An aerosol layer centered near 21 km was clearly evident in all observations, but its magnitude and vertical distribution varied considerably throughout the observation period. A reduction of particulate backscattering in the 23- to 30-km layer during late January 1973 appears to have been associated with the sudden stratospheric warming which occurred at that time.

Characteristics of Volcanic Stratospheric Aerosol Layer Observed by CALIOP and Ground Based Lidar at Equatorial Atmosphere Radar Site

NASA Astrophysics Data System (ADS)

Abo, Makoto; Shibata, Yasukuni; Nagasawa, Chikao

2018-04-01

We investigated the relation between major tropical volcanic eruptions in the equatorial region and the stratospheric aerosol data, which have been collected by the ground based lidar observations at at Equatorial Atmosphere Radar site between 2004 and 2015 and the CALIOP observations in low latitude between 2006 and 2015. We found characteristic dynamic behavior of volcanic stratospheric aerosol layers over equatorial region.

Stratospheric Sulfuric Acid and Black Carbon Aerosol Measured During POLARIS and its Role in Ozone Chemistry

NASA Technical Reports Server (NTRS)

Strawa, Anthony W.; Pueschel, R. F.; Drdla, K.; Verma, S.; Gore, Warren J. (Technical Monitor)

1998-01-01

Stratospheric aerosol can affect the environment in three ways. Sulfuric acid aerosol have been shown to act as sites for the reduction of reactive nitrogen and chlorine and as condensation sites to form Polar Stratospheric Clouds, under very cold conditions, which facilitate ozone depletion. Recently, modeling studies have suggested a link between BCA (Black Carbon Aerosol) and ozone chemistry. These studies suggest that HNO3, NO2, and O3 may be reduced heterogeneously on BCA particles. The ozone reaction converts ozone to oxygen molecules, while HNO3 and NO2 react to form NOx. Finally, a buildup of BCA could reduce the single-scatter albedo of aerosol below a value of 0.98, a critical value that has been postulated to change the effect of stratospheric aerosol from cooling to warming. Correlations between measured BCA amounts and aircraft usage have been reported. Attempts to link BCA to ozone chemistry and other stratospheric processes have been hindered by questions concerning the amount of BCA that exists in the stratosphere, the magnitude of reaction probabilities, and the scarcity of BCA measurements. The Ames Wire Impactors (AWI) participated in POLARIS as part of the complement of experiments on the NASA ER-2. One of our main objectives was to determine the amount of aerosol surface area, particularly BCA, available for reaction with stratospheric constituents and assess if possible, the importance of these reactions. The AWI collects aerosol and BCA particles on thin Palladium wires that are exposed to the ambient air in a controlled manner. The samples are returned to the laboratory for subsequent analysis. The product of the AWI analysis is the size, surface area, and volume distributions, morphology and elemental composition of aerosol and BCA. This paper presents results from our experiments during POLARIS and puts these measurements in the context of POLARIS and other missions in which we have participated. It describes modifications to the AWI data

Reactivity of stratospheric aerosols to small amounts of ammonia in the laboratory environment

NASA Technical Reports Server (NTRS)

Hayes, D.; Snetsinger, K.; Ferry, G.; Oberbeck, V.; Farlow, N.

1980-01-01

Trace ammonia in laboratory air reacts easily with sulfuric acid aerosol samples to form crystalline ammonium sulfate. Argon atmospheres, however, protect sampling surfaces from ammonia contamination. It is found that atmospheric aerosols treated in this way contain only sulfuric acid. After an hour exposed to laboratory air, these same samples convert to ammonium sulfate. Aerosol particles have been collected, using argon control, to determine if the absence of crystalline sulfate is common. But so far there is no evidence that aerosols are neutralized by ammonia in the stratosphere.

A stratospheric aerosol model with perturbations induced by the space shuttle particulate effluents

NASA Technical Reports Server (NTRS)

Rosen, J. M.; Hofmann, D. J.

1977-01-01

A one dimensional steady state stratospheric aerosol model is developed that considers the subsequent perturbations caused by including the expected space shuttle particulate effluents. Two approaches to the basic modeling effort were made: in one, enough simplifying assumptions were introduced so that a more or less exact solution to the descriptive equations could be obtained; in the other approach very few simplifications were made and a computer technique was used to solve the equations. The most complex form of the model contains the effects of sedimentation, diffusion, particle growth and coagulation. Results of the perturbation calculations show that there will probably be an immeasurably small increase in the stratospheric aerosol concentration for particles larger than about 0.15 micrometer radius.

A Risk-Based Framework for Assessing the Effectiveness of Stratospheric Aerosol Geoengineering

PubMed Central

Ferraro, Angus J.; Charlton-Perez, Andrew J.; Highwood, Eleanor J.

2014-01-01

Geoengineering by stratospheric aerosol injection has been proposed as a policy response to warming from human emissions of greenhouse gases, but it may produce unequal regional impacts. We present a simple, intuitive risk-based framework for classifying these impacts according to whether geoengineering increases or decreases the risk of substantial climate change, with further classification by the level of existing risk from climate change from increasing carbon dioxide concentrations. This framework is applied to two climate model simulations of geoengineering counterbalancing the surface warming produced by a quadrupling of carbon dioxide concentrations, with one using a layer of sulphate aerosol in the lower stratosphere, and the other a reduction in total solar irradiance. The solar dimming model simulation shows less regional inequality of impacts compared with the aerosol geoengineering simulation. In the solar dimming simulation, 10% of the Earth's surface area, containing 10% of its population and 11% of its gross domestic product, experiences greater risk of substantial precipitation changes under geoengineering than under enhanced carbon dioxide concentrations. In the aerosol geoengineering simulation the increased risk of substantial precipitation change is experienced by 42% of Earth's surface area, containing 36% of its population and 60% of its gross domestic product. PMID:24533155

The Role of Sulfur Dioxide in Stratospheric Aerosol Formation Evaluated Using In-Situ Measurements in the Tropical Lower Stratosphere

PubMed Central

Rollins, A. W.; Thornberry, T. D.; Watts, L. A.; Yu, P.; Rosenlof, K. H.; Mills, M.; Baumann, E.; Giorgetta, F. R.; Bui, T. V.; Höpfner, M.; Walker, K. A.; Boone, C.; Bernath, P. F.; Colarco, P. R.; Newman, P. A.; Fahey, D. W.; Gao, R. S.

2017-01-01

Stratospheric aerosols (SAs) are a variable component of the Earth's albedo that may be intentionally enhanced in the future to offset greenhouse gases (geoengineering). The role of tropospheric-sourced sulfur dioxide (SO2) in maintaining background SAs has been debated for decades without in-situ measurements of SO2 at the tropical tropopause to inform this issue. Here we clarify the role of SO2 in maintaining SAs by using new in-situ SO2 measurements to evaluate climate models and satellite retrievals. We then use the observed tropical tropopause SO2 mixing ratios to estimate the global flux of SO2 across the tropical tropopause. These analyses show that the tropopause background SO2 is about 5 times smaller than reported by the average satellite observations that have been used recently to test atmospheric models. This shifts the view of SO2 as a dominant source of SAs to a near-negligible one, possibly revealing a significant gap in the SA budget. PMID:29225384

The Role of Sulfur Dioxide in Stratospheric Aerosol Formation Evaluated Using In Situ Measurements in the Tropical Lower Stratosphere

NASA Technical Reports Server (NTRS)

Rollins, A. W.; Thornberry, T. D.; Watts, L. A.; Yu, P.; Rosenlof, K. H.; Mills, M.; Baumann, E.; Girogetta, F. R.; Bui, T. V.; Hopfner, M.;

The Role of Sulfur Dioxide in Stratospheric Aerosol Formation Evaluated Using In-Situ Measurements in the Tropical Lower Stratosphere.

PubMed

Rollins, A W; Thornberry, T D; Watts, L A; Yu, P; Rosenlof, K H; Mills, M; Baumann, E; Giorgetta, F R; Bui, T V; Höpfner, M; Walker, K A; Boone, C; Bernath, P F; Colarco, P R; Newman, P A; Fahey, D W; Gao, R S

2017-05-16

Stratospheric aerosols (SAs) are a variable component of the Earth's albedo that may be intentionally enhanced in the future to offset greenhouse gases (geoengineering). The role of tropospheric-sourced sulfur dioxide (SO 2 ) in maintaining background SAs has been debated for decades without in-situ measurements of SO 2 at the tropical tropopause to inform this issue. Here we clarify the role of SO 2 in maintaining SAs by using new in-situ SO 2 measurements to evaluate climate models and satellite retrievals. We then use the observed tropical tropopause SO 2 mixing ratios to estimate the global flux of SO 2 across the tropical tropopause. These analyses show that the tropopause background SO 2 is about 5 times smaller than reported by the average satellite observations that have been used recently to test atmospheric models. This shifts the view of SO 2 as a dominant source of SAs to a near-negligible one, possibly revealing a significant gap in the SA budget.

Intercomparison of in situ and remote sensing aerosol measurements in the lowermost stratosphere during varying volcanic influence

NASA Astrophysics Data System (ADS)

Sandvik, Oscar S.; Martinsson, Bengt G.; Friberg, Johan; Hermann, Markus; van Velthoven, Peter J. F.; Zahn, Andreas

2017-04-01

In this study two aerosol measurement platforms have been compared. Aerosol optical depth (AOD) per meter in the lowermost stratosphere was obtained with the "In-service Aircraft for a Global Observing System - Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container" (IAGOS-CARIBIC) platform and with the "Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation" (CALIPSO) satellite. The in situ measurements were taken from the IAGOS-CARIBIC platform, where sampling of aerosol and trace gases was undertaken in the altitude range 9 - 12 km from a passenger aircraft, usually on four intercontinental flights a month (Brenninkmeijer et al., 2007). Here we use impactor samples that were analyzed for elemental concentrations with Particle-Induced X-ray Emission (PIXE) and Particle Elastic Scattering Analysis (PESA) (Nguyen et al., 2006; Martinsson et al., 2014). The comparison was based on the sulfurous aerosol, which is the main component of the aerosol in the stratosphere. From the amount of sulfur, the AOD per meter could be estimated, assuming standard stratospheric aerosol composition (75% sulfuric acid and 25% water) and stratospheric background particle size distribution (Jäger and Deshler, 2002). The CALIPSO measurements were taken with a polarization-sensitive lidar with a high vertical resolution, of 30 m at most, using laser wavelengths of 532 nm and 1064 nm. In this study level 1b data was used to calculate AOD per meter. Clouds were removed based on depolarization ratio (Vernier et al., 2009). The results from the two measurement platforms were compared with each other for time periods after the volcanic eruptions of Sarychev (2009) and Nabro (2011) as well as the period from autumn 2013 to early spring of 2014 which had small volcanic influence. The measurements in this study were taken between 40°N and 75°N. Vertical profiles of AOD per meter were created for data above the tropopause. In this study the

SAGE ground truth plan: Correlative measurements for the Stratospheric Aerosol and Gas Experiment (SAGE) on the AEM-B satellite

NASA Technical Reports Server (NTRS)

Russell, P. B. (Editor); Cunnold, D. M.; Grams, G. W.; Laver, J.; Mccormick, M. P.; Mcmaster, L. R.; Murcray, D. G.; Pepin, T. J.; Perry, T. W.; Planet, W. G.

1979-01-01

The ground truth plan is outlined for correlative measurements to validate the Stratospheric Aerosol and Gas Experiment (SAGE) sensor data. SAGE will fly aboard the Applications Explorer Mission-B satellite scheduled for launch in early 1979 and measure stratospheric vertical profiles of aerosol, ozone, nitrogen dioxide, and molecular extinction between 79 N and 79 S. latitude. The plan gives details of the location and times for the simultaneous satellite/correlative measurements for the nominal launch time, the rationale and choice of the correlative sensors, their characteristics and expected accuracies, and the conversion of their data to extinction profiles. In addition, an overview of the SAGE expected instrument performance and data inversion results are presented. Various atmospheric models representative of stratospheric aerosols and ozone are used in the SAGE and correlative sensor analyses.

Toward a Combined SAGE II-HALOE Aerosol Climatology: An Evaluation of HALOE Version 19 Stratospheric Aerosol Extinction Coefficient Observations

NASA Technical Reports Server (NTRS)

Thomason, L. W.

2012-01-01

Herein, the Halogen Occultation Experiment (HALOE) aerosol extinction coefficient data is evaluated in the low aerosol loading period after 1996 as the first necessary step in a process that will eventually allow the production of a combined HALOE/SAGE II (Stratospheric Aerosol and Gas Experiment) aerosol climatology of derived aerosol products including surface area density. Based on these analyses, it is demonstrated that HALOE's 3.46 microns is of good quality above 19 km and suitable for scientific applications above that altitude. However, it is increasingly suspect at lower altitudes and should not be used below 17 km under any circumstances after 1996. The 3.40 microns is biased by about 10% throughout the lower stratosphere due to the failure to clear NO2 but otherwise appears to be a high quality product down to 15 km. The 2.45 and 5.26 micron aerosol extinction coefficient measurements are clearly biased and should not be used for scientific applications after the most intense parts of the Pinatubo period. Many of the issues in the aerosol data appear to be related to either the failure to clear some interfering gas species or doing so poorly. For instance, it is clear that the 3.40micronaerosol extinction coefficient measurements can be improved through the inclusion of an NO2 correction and could, in fact, end up as the highest quality overall HALOE aerosol extinction coefficient measurement. It also appears that the 2.45 and 5.26 micron channels may be improved by updating the Upper Atmosphere Pilot Database which is used as a resource for the removal of gas species otherwise not available from direct HALOE measurements. Finally, a simple model to demonstrate the promise of mixed visible/infrared aerosol extinction coefficient ensembles for the retrieval of bulk aerosol properties demonstrates that a combined HALOE/SAGE II aerosol climatology is feasible and may represent a substantial improvement over independently derived data sets.

Backscatter laser depolarization studies of simulated stratospheric aerosols - Crystallized sulfuric acid droplets

NASA Technical Reports Server (NTRS)

Sassen, Kenneth; Zhao, Hongjie; Yu, Bing-Kun

1989-01-01

The optical depolarizing properties of simulated stratospheric aerosols were studied in laboratory laser (0.633 micrometer) backscattering experiments for application to polarization lidar observations. Clouds composed of sulfuric acid solution droplets, some treated with ammonia gas, were observed during evaporation. The results indicate that the formation of minute ammonium sulfate particles from the evaporation of acid droplets produces linear depolarization ratios of beta equivalent to 0.02, but beta equivalent to 0.10 to 0.15 are generated from aged acid cloud aerosols and acid droplet crystalization effects following the introduction of ammonia gas into the chamber. It is concluded that partially crystallized sulfuric acid droplets are a likely candidate for explaining the lidar beta equivalent to 0.10 values that have been observed in the lower stratosphere in the absence of the relatively strong backscattering from homogeneous sulfuric acid droplet (beta equivalent to 0) or ice crystal (beta equivalent to 0.5) clouds.

Backscatter laser depolarization studies of simulated stratospheric aerosols: Crystallized sulfuric acid droplets

NASA Technical Reports Server (NTRS)

Sassen, Kenneth; Zhao, Hongjie; Yu, Bing-Kun

1988-01-01

The optical depolarizing properties of simulated stratospheric aerosols were studied in laboratory laser (0.633 micrometer) backscattering experiments for application to polarization lidar observations. Clouds composed of sulfuric acid solution droplets, some treated with ammonia gas, were observed during evaporation. The results indicate that the formation of minute ammonium sulfate particles from the evaporation of acid droplets produces linear depolarization ratios of beta equivalent to 0.02, but beta equivalent to 0.10 to 0.15 are generated from aged acid cloud aerosols and acid droplet crystallization effects following the introduction of ammonia gas into the chamber. It is concluded that partially crystallized sulfuric acid droplets are a likely candidate for explaining the lidar beta equivalent to 0.10 values that have been observed in the lower stratosphere in the absence of the relatively strong backscattering from homogeneous sulfuric acid droplet (beta equivalent to 0) or ice crystal (beta equivalent to 0.5) clouds.

The Stratospheric Aerosol and Gas Experiment (SAGE III) on the International Space Station (ISS) Mission

NASA Technical Reports Server (NTRS)

Cisewski, Michael; Zawodny, Joseph; Gasbarre, Joseph; Eckman, Richard; Topiwala, Nandkishore; Rodriquez-Alvarez, Otilia; Cheek, Dianne; Hall, Steve

2014-01-01

The Stratospheric Aerosol and Gas Experiment III on the International Space Station (SAGE III/ISS) mission will provide the science community with high-vertical resolution and nearly global observations of ozone, aerosols, water vapor, nitrogen dioxide, and other trace gas species in the stratosphere and upper-troposphere. SAGE III/ISS measurements will extend the long-term Stratospheric Aerosol Measurement (SAM) and SAGE data record begun in the 1970s. The multi-decadal SAGE ozone and aerosol data sets have undergone intense scrutiny and are considered the international standard for accuracy and stability. SAGE data have been used to monitor the effectiveness of the Montreal Protocol. Key objectives of the mission are to assess the state of the recovery in the distribution of ozone, to re-establish the aerosol measurements needed by both climate and ozone models, and to gain further insight into key processes contributing to ozone and aerosol variability. The space station mid-inclination orbit allows for a large range in latitude sampling and nearly continuous communications with payloads. The SAGE III instrument is the fifth in a series of instruments developed for monitoring atmospheric constituents with high vertical resolution. The SAGE III instrument is a moderate resolution spectrometer covering wavelengths from 290 nm to 1550 nm. Science data is collected in solar occultation mode, lunar occultation mode, and limb scatter measurement mode. A SpaceX Falcon 9 launch vehicle will provide access to space. Mounted in the unpressurized section of the Dragon trunk, SAGE III will be robotically removed from the Dragon and installed on the space station. SAGE III/ISS will be mounted to the ExPRESS Logistics Carrier-4 (ELC-4) location on the starboard side of the station. To facilitate a nadir view from this location, a Nadir Viewing Platform (NVP) payload was developed which mounts between the carrier and the SAGE III Instrument Payload (IP).

Optical modeling of stratopheric aerosols - Present status

NASA Technical Reports Server (NTRS)

Rosen, J. M.; Hofmann, D. J.

1986-01-01

A stratospheric aerosol optical model is developed which is based on a size distribution conforming to direct measurements. Additional constraints are consistent with large data sets of independently measured macroscopic aerosol properties such as mass and backscatter. The period under study covers background as well as highly disturbed volcanic conditions and an altitude interval ranging from the tropopause to about 30 km. The predictions of the model are used to form a basis for interpreting and intercomparing several diverse types of stratospheric aerosol measurement.

Vertical transport of Kelut volcanic stratospheric aerosols observed by the equatorial lidar and the Equatorial Atmosphere Radar

NASA Astrophysics Data System (ADS)

Nagasawa, C.; Abo, M.; Shibata, Y.

2017-12-01

The transport of substance between stratosphere and troposphere in the equatorial region makes an impact to the global climate change, but it has a lot of unknown behaviors. We have performed the lidar observations for survey of atmospheric structure of troposphere, stratosphere, and mesosphere over Kototabang (0.2S, 100.3E), Indonesia in the equatorial region since 2004. Kelut volcano (7.9S, 112.3E) in the Java island of Indonesia erupted on 13 February 2014. The CALIOP observed that the eruption cloud reached 26km above sea level in the tropical stratosphere, but most of the plume remained at 19-20 km over the tropopause. By CALIOP data analysis, aerosol clouds spread in the longitude direction with the lapse of time and arrived at equator in 5 days. After aerosol clouds reached equator, they moved towards the east along the equator by strong eastward equatorial wind of QBO. In June 2014 (4 months after the eruption), aerosol transport from the stratosphere to the troposphere were observed by the polarization lidar at Kototabang. At the same time, we can clearly see down phase structure of vertical wind velocity observed by EAR (Equatorial Atmosphere Radar) generated by the equatorial Kelvin wave. We investigate the transport of substance between stratosphere and troposphere in the equatorial region by data which have been collected by the polarization lidar at Kototabang and the EAR after Kelut volcano eruption. Using combination of ground based lidar, satellite based lidar, and atmosphere radar, we can get valuable evidence of equatorial transport of substance between the troposphere and the lower stratosphere. This work was supported by Collaborative Research based on MU Radar and Equatorial Atmosphere Radar.

Physical and Chemical Characterization of Particles in the Upper Troposphere and Lower Stratosphere: Microanalysis of Aerosol Impactor Samples

NASA Technical Reports Server (NTRS)

Sheridan, Patrick J.

1999-01-01

Herein is reported activities to support the characterization of the aerosol in the upper troposphere (UT) and lower stratosphere (LS) collected during the Airborne Southern Hemisphere Ozone Experiment/Measurements for Assessing the Effects of Stratospheric Aircraft (ASHOE/MAESA) missions in 1994. Through a companion proposal, another group was to measure the size distribution of aerosols in the 0.008 to 2 micrometer diameter range and to collect for us impactor samples of particles larger than about 0.02 gm. In the first year, we conducted laboratory studies related to particulate deposition patterns on our collection substrates, and have performed the analysis of many ASHOE/MAESA aerosol samples from 1994 using analytical electron microscopy (AEM). We have been building an "aerosol climatology" with these data that documents the types and relative abundances of particles observed at different latitudes and altitudes. The second year (and non-funded extension periods) saw continued analyses of impactor aerosol samples, including more ASHOE/MAESA samples, some northern hemisphere samples from the NASA Stratospheric Photochemistry Aerosols and Dynamics Expedition (SPADE) program for comparison, and a few aerosol samples from the NASA Stratospheric TRacers of Atmospheric Transport (STRAT) program. A high-resolution field emission microscope was used for the analysis and re-analysis of a number of samples to determine if this instrument was superior in performance to our conventional electron microscope. In addition, some basic laboratory studies were conducted to determine the minimum detectable and analyzable particle size for different types of aerosols. In all, 61 aerosol samples were analyzed, with a total of over 30,000 individual particle analyses. In all analyzed samples, sulfate particles comprised the major aerosol number fraction. It must be stressed that particles composed of more than one species, for example sulfate and organic carbon, were classified

Optimal estimation retrieval of aerosol microphysical properties from SAGE~II satellite observations in the volcanically unperturbed lower stratosphere

NASA Astrophysics Data System (ADS)

Wurl, D.; Grainger, R. G.; McDonald, A. J.; Deshler, T.

2010-05-01

Stratospheric aerosol particles under non-volcanic conditions are typically smaller than 0.1 μm. Due to fundamental limitations of the scattering theory in the Rayleigh limit, these tiny particles are hard to measure by satellite instruments. As a consequence, current estimates of global aerosol properties retrieved from spectral aerosol extinction measurements tend to be strongly biased. Aerosol surface area densities, for instance, are observed to be about 40% smaller than those derived from correlative in situ measurements (Deshler et al., 2003). An accurate knowledge of the global distribution of aerosol properties is, however, essential to better understand and quantify the role they play in atmospheric chemistry, dynamics, radiation and climate. To address this need a new retrieval algorithm was developed, which employs a nonlinear Optimal Estimation (OE) method to iteratively solve for the monomodal size distribution parameters which are statistically most consistent with both the satellite-measured multi-wavelength aerosol extinction data and a priori information. By thus combining spectral extinction measurements (at visible to near infrared wavelengths) with prior knowledge of aerosol properties at background level, even the smallest particles are taken into account which are practically invisible to optical remote sensing instruments. The performance of the OE retrieval algorithm was assessed based on synthetic spectral extinction data generated from both monomodal and small-mode-dominant bimodal sulphuric acid aerosol size distributions. For monomodal background aerosol, the new algorithm was shown to fairly accurately retrieve the particle sizes and associated integrated properties (surface area and volume densities), even in the presence of large extinction uncertainty. The associated retrieved uncertainties are a good estimate of the true errors. In the case of bimodal background aerosol, where the retrieved (monomodal) size distributions naturally

Titan's Aerosol and Stratospheric Ice Opacities Between 18 and 500 Micrometers: Vertical and Spectral Characteristics from Cassini CIRS

NASA Technical Reports Server (NTRS)

Anderson, Carrie M.; Samuelson, Robert E.

2011-01-01

Vertical distributions and spectral characteristics of Titan's photochemical aerosol and stratospheric ices are determined between 20 and 560 per centimeter (500-18 micrometers) from the Cassini Composite Infrared Spectrometer (CIRS). Results are obtained for latitudes of 15 N, 15 S, and 58 S, where accurate temperature profiles can be independently determined. In addition, estimates of aerosol and ice abundances at 62 N relative to those at 15 S are derived. Aerosol abundances are comparable at the two latitudes, but stratospheric ices are approximately 3 times more abundant at 62 N than at 15 S. Generally, nitrile ice clouds (probably HCN and HC3N), as inferred from a composite emission feature at approximately 160 per centimeter, appear to be located over a narrow altitude range in the stratosphere centered at approximately 90 km. Although most abundant at high northern latitudes, these nitrile ice clouds extend down through low latitudes and into mid southern latitudes, at least as far as 58 S. There is some evidence of a second ice cloud layer at approximately 60 km altitude at 58 S associated with an emission feature at approximately 80 per centimeter. We speculate that the identify of this cloud may be due to C2H6 ice, which in the vapor phase is the most abundant hydrocarbon (next to CH4) in the stratosphere of Titan. Unlike the highly restricted range of altitudes (50-100 km) associated with organic condensate clouds, Titan's photochemical aerosol appears to be well-mixed from the surface to the top of the stratosphere near an altitude of 300 km, and the spectral shape does not appear to change between 15 N and 58 S latitude. The ratio of aerosol-to-gas scale heights range from 1.3-2.4 at about 160 km to 1.1-1.4 at 300 km, although there is considerable variability with latitude, The aerosol exhibits a very broad emission feature peaking at approximately 140 per centimeter. Due to its extreme breadth and low wavenumber, we speculate that this feature may

Comparing Simultaneous Stratospheric Aerosol and Ozone Lidar Measurements with SAGE 2 Data after the Mount Pinatubo Eruption

NASA Technical Reports Server (NTRS)

Yue, G. K.; Poole, L. R.; McCormick, M. P.; Veiga, R. E.; Wang, P.-H.; Rizi, V.; Masci, F.; DAltorio, A.; Visconti, G.

1995-01-01

Stratospheric aerosol and ozone profiles obtained simultaneously from the lidar station at the University of L'Aquila (42.35 deg N, 13.33 deg E, 683 m above sea level) during the first 6 months following the eruption of Mount Pinatubo are compared with corresponding nearby Stratospheric Aerosol and Gas Experiment (SAGE) 2 profiles. The agreement between the two data sets is found to be reasonably good. The temporal change of aerosol profiles obtained by both techniques showed the intrusion and growth of Pinatubo aerosols. In addition, ozone concentration profiles derived from an empirical time-series model based on SAGE 2 ozone data obtained before the Pinatubo eruption are compared with measured profiles. Good agreement is shown in the 1991 profiles, but ozone concentrations measured in January 1992 were reduced relative to time-series model estimates. Possible reasons for the differences between measured and model-based ozone profiles are discussed.

Efficient Formation of Stratospheric Aerosol for Climate Engineering by Emission of Condensible Vapor from Aircraft

NASA Technical Reports Server (NTRS)

Pierce, Jeffrey R.; Weisenstein, Debra K.; Heckendorn, Patricia; Peter. Thomas; Keith, David W.

2010-01-01

Recent analysis suggests that the effectiveness of stratospheric aerosol climate engineering through emission of non-condensable vapors such as SO2 is limited because the slow conversion to H2SO4 tends to produce aerosol particles that are too large; SO2 injection may be so inefficient that it is difficult to counteract the radiative forcing due to a CO2 doubling. Here we describe an alternate method in which aerosol is formed rapidly in the plume following injection of H2SO4, a condensable vapor, from an aircraft. This method gives better control of particle size and can produce larger radiative forcing with lower sulfur loadings than SO2 injection. Relative to SO2 injection, it may reduce some of the adverse effects of geoengineering such as radiative heating of the lower stratosphere. This method does not, however, alter the fact that such a geoengineered radiative forcing can, at best, only partially compensate for the climate changes produced by CO2.

Optical and physical properties of stratospheric aerosols from balloon measurements in the visible and near-infrared domains. I. Analysis of aerosol extinction spectra from the AMON and SALOMON balloonborne spectrometers

NASA Astrophysics Data System (ADS)

Berthet, Gwenaël; Renard, Jean-Baptiste; Brogniez, Colette; Robert, Claude; Chartier, Michel; Pirre, Michel

2002-12-01

Aerosol extinction coefficients have been derived in the 375-700-nm spectral domain from measurements in the stratosphere since 1992, at night, at mid- and high latitudes from 15 to 40 km, by two balloonborne spectrometers, Absorption par les Minoritaires Ozone et NOx (AMON) and Spectroscopie d'Absorption Lunaire pour l'Observation des Minoritaires Ozone et NOx (SALOMON). Log-normal size distributions associated with the Mie-computed extinction spectra that best fit the measurements permit calculation of integrated properties of the distributions. Although measured extinction spectra that correspond to background aerosols can be reproduced by the Mie scattering model by use of monomodal log-normal size distributions, each flight reveals some large discrepancies between measurement and theory at several altitudes. The agreement between measured and Mie-calculated extinction spectra is significantly improved by use of bimodal log-normal distributions. Nevertheless, neither monomodal nor bimodal distributions permit correct reproduction of some of the measured extinction shapes, especially for the 26 February 1997 AMON flight, which exhibited spectral behavior attributed to particles from a polar stratospheric cloud event.

Mount Saint Helens aerosol evolution

NASA Technical Reports Server (NTRS)

Oberbeck, V. R.; Farlow, N. H.; Snetsinger, K. G.; Ferry, G. V.; Fong, W.; Hayes, D. M.

1982-01-01

Stratospheric aerosol samples were collected using a wire impactor during the year following the eruption of Mt. St. Helens. Analysis of samples shows that aerosol volume increased for 6 months due to gas-to-particle conversion and then decreased to background levels in the following 6 months.

Stratosphere aerosol and cloud measurements at McMurdo Station Antarctica during the spring of 1987

NASA Technical Reports Server (NTRS)

Hofmann, D. J.; Rosen, J. M.; Harder, J. W.

1988-01-01

Measurements of stratospheric aerosols with balloonborne optical particle counters on 6 occasions at McMurdo Station (78 deg S) in the spring of 1986 indicated subsidence of the stratospheric sulfate layer during the time that the ozone hole was forming (Hofmann et al., 1988). Since dynamic models of ozone depletion involving upwelling in the spring polar vortex would suggest the opposite, we repeated the measurements with an increased frequency (about one sounding per week) in 1987. During 3 of the aerosol soundings in 1986, temperatures in the 15 to 20 km range were low enough (less than 80 C) for HNO3 to co-condense with water according to several theories of polar stratospheric cloud formation. However, particles were not observed with the characteristic size suggested by theory (approx. 0.5 microns). For this reason, it was proposed that polar stratospheric clouds may predominantly consist of large (approx. 5 to 50 microns) ice crystals at very low (approx. 10 sup 4- 10 sup 3 cm cubed) concentrations (Rosen et al., 1988). The particle counter employed would be relatively insensitive to these low concentrations. With the increased frequency of soundings in 1987, and adding additional size discrimination in the 1 to 2 micron region, this hypothesis could be verified if suitably low temperatures were encountered.

A consistent prescription of stratospheric aerosol for both radiation and chemistry in the Community Earth System Model (CESM1)

DOE PAGES

Neely, III, Ryan Reynolds; Conley, Andrew J.; Vitt, Francis; ...

2016-07-25

Here we describe an updated parameterization for prescribing stratospheric aerosol in the National Center for Atmospheric Research (NCAR) Community Earth System Model (CESM1). The need for a new parameterization is motivated by the poor response of the CESM1 (formerly referred to as the Community Climate System Model, version 4, CCSM4) simulations contributed to the Coupled Model Intercomparison Project 5 (CMIP5) to colossal volcanic perturbations to the stratospheric aerosol layer (such as the 1991 Pinatubo eruption or the 1883 Krakatau eruption) in comparison to observations. In particular, the scheme used in the CMIP5 simulations by CESM1 simulated a global mean surface temperature decreasemore » that was inconsistent with the GISS Surface Temperature Analysis (GISTEMP), NOAA's National Climatic Data Center, and the Hadley Centre of the UK Met Office (HADCRUT4). The new parameterization takes advantage of recent improvements in historical stratospheric aerosol databases to allow for variations in both the mass loading and size of the prescribed aerosol. An ensemble of simulations utilizing the old and new schemes shows CESM1's improved response to the 1991 Pinatubo eruption. Most significantly, the new scheme more accurately simulates the temperature response of the stratosphere due to local aerosol heating. Here, results also indicate that the new scheme decreases the global mean temperature response to the 1991 Pinatubo eruption by half of the observed temperature change, and modelled climate variability precludes statements as to the significance of this change.« less

Stratospheric Aerosol and Gas Experiments 1 and 2: Comparisons with ozonesondes

NASA Technical Reports Server (NTRS)

Veiga, Robert E.; Cunnold, Derek M.; Chu, William P.; McCormick, M. Patrick

1995-01-01

Ozone profiles measured by the Stratospheric Aerosol and Gas Experiments (SAGE) 1 and 2 are compared with ozonesonde profiles at 24 stations over the period extending from 1979 through 1991. Ozonesonde/satellite differences at 21 stations with SAGE 2 overpasses were computed down to 11.5 km in midlatitudes, to 15.5 km in the lower latitudes, and for nine stations with SAGE 1 overpasses down to 15.5 km. The set of individual satellite and ozonesonde profile comparisons most closely colocated in time and space shows mean absolute differences relative to the satellite measurement of 6 +/- 2% for SAGE 2 and 8 +/- 3% for SAGE 1. The ensemble of ozonesonde/satellite differences, when averaged over all altitudes, shows that for SAGE 2, 70% were less than 5%, whereas for SAGE 1, 50% were less than 5%. The best agreement occurred in the altitude region near the ozone density maximum where almost all the relative differences were less than 5%. Most of the statistically significant differences occurred below the ozone maximum down to the tropopause in the region of steepest ozone gradients and typically ranged between 0 and -20%. Correlations between ozone and aerosol extinction in the northern midlatitudes indicate that aerosols had no discernible impact on the ozonesonde/satellite differences and on the SAGE 2 ozone retrieval for the levels of extinction encountered in the lower stratosphere during 1984 to mid-1991.

Increase in upper tropospheric and lower stratospheric aerosol levels and its potential connection with Asian pollution.

PubMed

Vernier, J-P; Fairlie, T D; Natarajan, M; Wienhold, F G; Bian, J; Martinsson, B G; Crumeyrolle, S; Thomason, L W; Bedka, K M

2015-02-27

Satellite observations have shown that the Asian Summer Monsoon strongly influences the upper troposphere and lower stratosphere (UTLS) aerosol morphology through its role in the formation of the Asian Tropopause Aerosol Layer (ATAL). Stratospheric Aerosol and Gas Experiment II solar occultation and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) lidar observations show that summertime UTLS Aerosol Optical Depth (AOD) between 13 and 18 km over Asia has increased by three times since the late 1990s. Here we present the first in situ balloon measurements of aerosol backscatter in the UTLS from Western China, which confirm high aerosol levels observed by CALIPSO since 2006. Aircraft in situ measurements suggest that aerosols at lower altitudes of the ATAL are largely composed of carbonaceous and sulfate materials (carbon/sulfur elemental ratio ranging from 2 to 10). Back trajectory analysis from Cloud-Aerosol Lidar with Orthogonal Polarization observations indicates that deep convection over the Indian subcontinent supplies the ATAL through the transport of pollution into the UTLS. Time series of deep convection occurrence, carbon monoxide, aerosol, temperature, and relative humidity suggest that secondary aerosol formation and growth in a cold, moist convective environment could play an important role in the formation of ATAL. Finally, radiative calculations show that the ATAL layer has exerted a short-term regional forcing at the top of the atmosphere of -0.1 W/m 2 in the past 18 years. Increase of summertime upper tropospheric aerosol levels over Asia since the 1990s Upper tropospheric enhancement also observed by in situ backscatter measurements Significant regional radiative forcing of -0.1 W/m 2 .

First Simulations of Designing Stratospheric Sulfate Aerosol Geoengineering to Meet Multiple Simultaneous Climate Objectives

NASA Astrophysics Data System (ADS)

Kravitz, Ben; MacMartin, Douglas G.; Mills, Michael J.; Richter, Jadwiga H.; Tilmes, Simone; Lamarque, Jean-Francois; Tribbia, Joseph J.; Vitt, Francis

2017-12-01

We describe the first simulations of stratospheric sulfate aerosol geoengineering using multiple injection locations to meet multiple simultaneous surface temperature objectives. Simulations were performed using CESM1(WACCM), a coupled atmosphere-ocean general circulation model with fully interactive stratospheric chemistry, dynamics (including an internally generated quasi-biennial oscillation), and a sophisticated treatment of sulfate aerosol formation, microphysical growth, and deposition. The objectives are defined as maintaining three temperature features at their 2020 levels against a background of the RCP8.5 scenario over the period 2020-2099. These objectives are met using a feedback mechanism in which the rate of sulfur dioxide injection at each of the four locations is adjusted independently every year of simulation. Even in the presence of uncertainties, nonlinearities, and variability, the objectives are met, predominantly by SO2 injection at 30°N and 30°S. By the last year of simulation, the feedback algorithm calls for a total injection rate of 51 Tg SO2 per year. The injections are not in the tropics, which results in a greater degree of linearity of the surface climate response with injection amount than has been found in many previous studies using injection at the equator. Because the objectives are defined in terms of annual mean temperature, the required geongineering results in "overcooling" during summer and "undercooling" during winter. The hydrological cycle is also suppressed as compared to the reference values corresponding to the year 2020. The demonstration we describe in this study is an important step toward understanding what geoengineering can do and what it cannot do.

The NASA-AMES Research Center Stratospheric Aerosol Model. 1. Physical Processes and Computational Analogs

NASA Technical Reports Server (NTRS)

Turco, R. P.; Hamill, P.; Toon, O. B.; Whitten, R. C.; Kiang, C. S.

1979-01-01

A time-dependent one-dimensional model of the stratospheric sulfate aerosol layer is presented. In constructing the model, a wide range of basic physical and chemical processes are incorporated in order to avoid predetermining or biasing the model predictions. The simulation, which extends from the surface to an altitude of 58 km, includes the troposphere as a source of gases and condensation nuclei and as a sink for aerosol droplets. The size distribution of aerosol particles is resolved into 25 categories with particle radii increasing geometrically from 0.01 to 2.56 microns such that particle volume doubles between categories.

The Stratospheric Aerosol and Gas Experiment III/International Space Station Mission: Science Objectives and Mission Status

NASA Astrophysics Data System (ADS)

Eckman, R.; Zawodny, J. M.; Cisewski, M. S.; Flittner, D. E.; McCormick, M. P.; Gasbarre, J. F.; Damadeo, R. P.; Hill, C. A.

2015-12-01

The Stratospheric Aerosol and Gas Experiment III/International Space Station (SAGE III/ISS) is a strategic climate continuity mission which was included in NASA's 2010 plan, "Responding to the Challenge of Climate and Environmental Change: NASA's Plan for a Climate-Centric Architecture for Earth Observations and Applications from Space." SAGE III/ISS continues the long-term, global measurements of trace gases and aerosols begun in 1979 by SAGE I and continued by SAGE II and SAGE III on Meteor 3M. Using a well characterized occultation technique, the SAGE III instrument's spectrometer will measure vertical profiles of ozone, aerosols, water vapor, nitrogen dioxide, and other trace gases relevant to ozone chemistry. The mission will launch in 2016 aboard a Falcon 9 spacecraft.The primary objective of SAGE III/ISS is to monitor the vertical distribution of aerosols, ozone, and other trace gases in the Earth's stratosphere and troposphere to enhance our understanding of ozone recovery and climate change processes in the stratosphere and upper troposphere. SAGE III/ISS will provide data necessary to assess the state of the recovery in the distribution of ozone, extend the SAGE III aerosol measurement record that is needed by both climate models and ozone models, and gain further insight into key processes contributing to ozone and aerosol variability. The multi-decadal SAGE ozone and aerosol data sets have undergone intense community scrutiny for accuracy and stability. SAGE ozone data have been used to monitor the effectiveness of the Montreal Protocol.The ISS inclined orbit of 51.6 degrees is ideal for SAGE III measurements because the orbit permits solar occultation measurement coverage to approximately +/- 70 degrees of latitude. SAGE III/ISS will make measurements using the solar occultation measurement technique, lunar occultation measurement technique, and the limb scattering measurement technique. In this presentation, we describe the SAGE III/ISS mission, its

Black Carbon (Soot) Aerosol in the Lower Stratosphere and Upper Troposphere. Revised

NASA Technical Reports Server (NTRS)

Pueschel, R. F.; Black, D. F.; Snetsinger, K. G.; Hansen, A. D. A.; Verna, S.; Kato, K.

1992-01-01

We have used two approaches to measure BCA in the stratosphere. The first method consists of collecting aerosols by impaction on quartz rods, upon which are mounted strips of polystyrene filter material. Each 25 mm by 0.5 mm filter strip is alternately masked and exposed in 5 mm long sections. After sampling, the optical density of the exposed sections is measured and compared with the optical density of the masked (unexposed) sections. The filter strip is a Lambertian collector, the scattering property of which is not affected by the deposition of liquid sulfuric acid droplets which dominate the stratospheric aerosol. Hence, all attenuation greater in the exposed than in the non-exposed sections is due to absorption by BCA or rare opaque materials such as meteoritic iron. In a second approach we expose carbon-coated gold or palladium wires to air outside the aircraft boundary layer [Farlow et al., 1979; Pueschel et al., 1989]. With a field emission scanning electron microscope we are able to characterize BCA particles in addition to the dominant sulfuric acid droplets. Typically, soot is comprised of 20 nm diameter spheres linked together as branching chains or loosely packed aggregates (Figure 1a). The microscope has a lateral image resolution of 1.5 nm and can clearly resolve individual spheres making up BCA aggregates. Their morphology is uniquely different from that of the liquid sulfuric acid-water aerosol (Figure 1b). We approximate the size of each BCA particle by that of a sphere of equivalent volume and fit a lognormal size distribution to both the BCA and H2SO4/H2O aerosols. Both sampler types have been mounted on NASA's ER-2 high-altitude research aircraft (altitude ceiling of 70,000 feet), and on NASA's DC-8 (40,000 feet ceiling) aircraft to sample aerosols from a significant portion of the atmosphere.

Stratospheric Aerosol and Gas Experiment (SAGE) II and III Aerosol Extinction Measurements in the Arctic Middle and Upper Troposphere

NASA Technical Reports Server (NTRS)

Treffeisen, R. E.; Thomason, L. W.; Strom, J.; Herber, A. B.; Burton, S. P.; Yamanouchi, T.

2006-01-01

In recent years, substantial effort has been expended toward understanding the impact of tropospheric aerosols on Arctic climate and chemistry. A significant part of this effort has been the collection and documentation of extensive aerosol physical and optical property data sets. However, the data sets present significant interpretive challenges because of the diverse nature of these measurements. Among the longest continuous records is that by the spaceborne Stratospheric Aerosol and Gas Experiment (SAGE) II. Although SAGE tropospheric measurements are restricted to the middle and upper troposphere, they may be able to provide significant insight into the nature and variability of tropospheric aerosol, particularly when combined with ground and airborne observations. This paper demonstrates the capacity of aerosol products from SAGE II and its follow-on experiment SAGE III to describe the temporal and vertical variations of Arctic aerosol characteristics. We find that the measurements from both instruments are consistent enough to be combined. Using this combined data set, we detect a clear annual cycle in the aerosol extinction for the middle and upper Arctic troposphere.

Theoretical Investigations of Clouds and Aerosols in the Stratosphere and Upper Troposphere

NASA Technical Reports Server (NTRS)

Toon, Owen B.

2005-01-01

support of the Atmospheric Chemistry Modeling and Data Analysis Program. We investigated a wide variety of issues involving ambient stratospheric aerosols, polar stratospheric clouds or heterogeneous chemistry, analysis of laboratory data, and particles in the upper troposphere. The papers resulting from these studies are listed below. In addition, I participated in the 1999-2000 SOLVE mission as one of the project scientists and in the 2002 CRYSTAL field mission as one of the project scientists. Several CU graduate students and research associates also participated in these mission, under support from the ACMAP program, and worked to interpret data. During the past few years my group has completed a number of projects under the

Overview of the Stratospheric Aerosol and Gas Experiment II water vapor observations - Method, validation, and data characteristics

NASA Technical Reports Server (NTRS)

Rind, D.; Chiou, E.-W.; Chu, W.; Oltmans, S.; Lerner, J.; Larsen, J.; Mccormick, M. P.; Mcmaster, L.

1993-01-01

Results are presented of water vapor observations in the troposphere and stratosphere performed by the Stratospheric Aerosol and Gas Experiment II solar occultation instrument, and the analysis procedure, the instrument errors, and data characteristics are discussed. The results are compared with correlative in situ measurements and other satellite data. The features of the data set collected between 1985 and 1989 include an increase in middle- and upper-tropospheric water vapor during northern hemisphere summer and autumn; minimum water vapor values of 2.5-3 ppmv in the tropical lower stratosphere; slowly increasing water vapor values with altitude in the stratosphere, reaching 5-6 ppmv or greater near the stratopause; extratropical values with minimum profile amounts occurring above the conventionally defined tropopause; and higher extratropical than tropical water vapor values throughout the stratosphere except in locations of possible polar stratospheric clouds.

Long Term Stratospheric Aerosol Lidar Measurements in Kyushu

NASA Technical Reports Server (NTRS)

Fujiwara, Motowo

1992-01-01

Lidar soundings of the stratospheric aerosols have been made since 1972 at Fukuoka, Kyushu Island of Japan. Volcanic clouds from eruptions of La Soufriere, Sierra Negra, St. Helens, Uluwan, Alaid, unknown volcano, and El Chichon were detected one after another in only three years from 1979 to 1982. In july 1991 strong scattering layers which were originated from the serious eruptions of Pinatubo in June and were almost comparable to the El Chichon clouds were detected. Volcanic clouds from pinatubo and other volcanos mentioned are examined and carefully compared to each other and to the wind and temperature which was measured by Fukuoka Meteorological Observatory almost at the same time as the lidar observation was made.

Stratospheric sulfur and its implications for radiative forcing simulated by the chemistry climate model EMAC

PubMed Central

Brühl, C; Lelieveld, J; Tost, H; Höpfner, M; Glatthor, N

2015-01-01

Multiyear simulations with the atmospheric chemistry general circulation model EMAC with a microphysical modal aerosol module at high vertical resolution demonstrate that the sulfur gases COS and SO2, the latter from low-latitude and midlatitude volcanic eruptions, predominantly control the formation of stratospheric aerosol. Marine dimethyl sulfide (DMS) and other SO2 sources, including strong anthropogenic emissions in China, are found to play a minor role except in the lowermost stratosphere. Estimates of volcanic SO2 emissions are based on satellite observations using Total Ozone Mapping Spectrometer and Ozone Monitoring Instrument for total injected mass and Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on Envisat or Stratospheric Aerosol and Gases Experiment for the spatial distribution. The 10 year SO2 and COS data set of MIPAS is also used for model evaluation. The calculated radiative forcing of stratospheric background aerosol including sulfate from COS and small contributions by DMS oxidation, and organic aerosol from biomass burning, is about 0.07W/m2. For stratospheric sulfate aerosol from medium and small volcanic eruptions between 2005 and 2011 a global radiative forcing up to 0.2W/m2 is calculated, moderating climate warming, while for the major Pinatubo eruption the simulated forcing reaches 5W/m2, leading to temporary climate cooling. The Pinatubo simulation demonstrates the importance of radiative feedback on dynamics, e.g., enhanced tropical upwelling, for large volcanic eruptions. PMID:25932352

Ruby lidar observations and trajectory analysis of stratospheric aerosols injected by the volcanic eruptions of El Chichon

NASA Technical Reports Server (NTRS)

Uchino, O.; Tabata, T.; Akita, I.; Okada, Y.; Naito, K.

1985-01-01

Large amounts of aerosol particles and gases were injected into the lower stratosphere by the violet volcanic eruptions of El Chichon on March 28, and April 3 and 4, 1982. Observational results obtained by a ruby lidar at Tsukuba (36.1 deg N, 140.1 deg E) are shown, and some points of latitude dispersion processes of aerosols are discussed.

The impact of high altitude aircraft on the ozone layer in the stratosphere

NASA Technical Reports Server (NTRS)

Tie, Xue XI; Brasseur, Guy; Lin, Xing; Friedlingstein, P.; Granier, Claire; Rasch, Philip

1994-01-01

The paper discusses the potential effects on the ozone layer of gases released by the engines of proposed high altitude supersonic aircraft. The major problem arises from the emissions of nitrogen oxides which have the potential to destroy significant quantities of ozone in the stratosphere. The magnitude of the perturbation is highly dependent on the cruise altitude of the aircraft. Furthermore, the depletion of ozone is substantially reduced when heterogeneous conversion of nitrogen oxides into nitric acid on sulfate aerosol particles is taken into account in the calculation. The sensitivity of the aerosol load on stratospheric ozone is investigated. First, the model indicates that the aerosol load induced by the SO2 released by aircraft is increased by about 10-20% above the background aerosols at mid-high latitude of the Northern Hemisphere at 15 km for the NASA emission scenario A (the NASA emission scenarios are explained in Tables I to III). This increase in aerosol has small effects on stratospheric ozone. Second, when the aerosol load is increased following a volcanic eruption similar to the eruption of El Chichon (Mexico, April 1982), the ozone column in spring increases by as much as 9% in response to the injection of NOx from the aircraft with the NASA emission scenario A. Finally, the modeled suggests that significant ozone depletion could result from the formation of additional polar stratospheric clouds produced by the injection of H2O and HNO3 by the aircraft engines.

Asymmetric forcing from stratospheric aerosols impacts Sahelian rainfall

NASA Astrophysics Data System (ADS)

Haywood, Jim M.; Jones, Andy; Bellouin, Nicolas; Stephenson, David

2013-07-01

The Sahelian drought of the 1970s-1990s was one of the largest humanitarian disasters of the past 50 years, causing up to 250,000 deaths and creating 10 million refugees. It has been attributed to natural variability, over-grazing and the impact of industrial emissions of sulphur dioxide. Each mechanism can influence the Atlantic sea surface temperature gradient, which is strongly coupled to Sahelian precipitation. We suggest that sporadic volcanic eruptions in the Northern Hemisphere also strongly influence this gradient and cause Sahelian drought. Using de-trended observations from 1900 to 2010, we show that three of the four driest Sahelian summers were preceded by substantial Northern Hemisphere volcanic eruptions. We use a state-of-the-art coupled global atmosphere-ocean model to simulate both episodic volcanic eruptions and geoengineering by continuous deliberate injection into the stratosphere. In either case, large asymmetric stratospheric aerosol loadings concentrated in the Northern Hemisphere are a harbinger of Sahelian drought whereas those concentrated in the Southern Hemisphere induce a greening of the Sahel. Further studies of the detailed regional impacts on the Sahel and other vulnerable areas are required to inform policymakers in developing careful consensual global governance before any practical solar radiation management geoengineering scheme is implemented.

Evidence of Seasonally Dependent Stratosphere-Troposphere Exchange and Purging of Lower Stratospheric Aeroso from a Multi-Year Lidar Dataset

NASA Technical Reports Server (NTRS)

Menzies, R. T.; Tratt, D. M.

1994-01-01

Tropospheric and lower stratospheric aerosol backscatter data obtained from a calibrated backscatter lidar at Pasadena, California (34 deg N latitude)over the 1984-1993 period clearly indicate tightly coupled aerosol optical properties in the upper troposphere and lower stratosphere in the winter and early spring, due to the active mid-latitude stratospheric-tropospheric (ST) exchange processes occurring at this time of year.

Chemistry and Microphysics of Lower Stratospheric Aerosols Determined by Satellite Remote Sensing

NASA Astrophysics Data System (ADS)

Zasetsky, A. Y.; Khalizov, A.; Sloan, J.

2003-12-01

Observations of broadband Infrared satellites such as ILAS-II (Ministry of the Environment, Japan, launched 14 December 2002) and SciSat-1 (Canadian Space Agency, launched 12 August 2003) can provide details of the chemical composition and particle size of atmospheric aerosols by direct inversion without recourse to models. During the past decade, we have developed mathematical methods to achieve this inversion by working with FTIR observations of model atmospheric aerosols in cryogenic flowtubes. More recently, we have converted these to operational algorithms for use in the above missions. In this presentation, we will briefly outline these procedures and illustrate their capabilities using laboratory data. These laboratory results show that the chemical compositions, phases and sizes of ensembles of particles can be obtained simultaneously using these procedures. We will also report chemical and microphysical properties of lower stratospheric clouds and aerosols derived by applying these procedures to observations from space.

Stratospheric solar geoengineering without ozone loss.

PubMed

Keith, David W; Weisenstein, Debra K; Dykema, John A; Keutsch, Frank N

2016-12-27

Injecting sulfate aerosol into the stratosphere, the most frequently analyzed proposal for solar geoengineering, may reduce some climate risks, but it would also entail new risks, including ozone loss and heating of the lower tropical stratosphere, which, in turn, would increase water vapor concentration causing additional ozone loss and surface warming. We propose a method for stratospheric aerosol climate modification that uses a solid aerosol composed of alkaline metal salts that will convert hydrogen halides and nitric and sulfuric acids into stable salts to enable stratospheric geoengineering while reducing or reversing ozone depletion. Rather than minimizing reactive effects by reducing surface area using high refractive index materials, this method tailors the chemical reactivity. Specifically, we calculate that injection of calcite (CaCO 3 ) aerosol particles might reduce net radiative forcing while simultaneously increasing column ozone toward its preanthropogenic baseline. A radiative forcing of -1 W⋅m -2 , for example, might be achieved with a simultaneous 3.8% increase in column ozone using 2.1 Tg⋅y -1 of 275-nm radius calcite aerosol. Moreover, the radiative heating of the lower stratosphere would be roughly 10-fold less than if that same radiative forcing had been produced using sulfate aerosol. Although solar geoengineering cannot substitute for emissions cuts, it may supplement them by reducing some of the risks of climate change. Further research on this and similar methods could lead to reductions in risks and improved efficacy of solar geoengineering methods.

OCS, stratospheric aerosols and climate

NASA Technical Reports Server (NTRS)

Turco, R. P.; Whitten, R. C.; Toon, O. B.; Pollack, J. B.; Hamill, P.

1980-01-01

The carbonyl sulfide budget in the atmosphere is examined, and the effects of stratospheric sulfate aerosol particles, formed in part from atmospheric carbonyl sulfate, on global climate are considered. From tropospheric measurements of carbon disulfide and the rate constant for the conversion of carbon disulfide to carbonyl sulfide, it is estimated that five Tg of carbonyl sulfide/year could be generated from carbon disulfide in the atmosphere. Direct sources of OCS include the refining and combustion of fossil fuels (1 Tg/year), natural and agricultural fires (0.2 to 0.3 Tg/year), and soils (0.5 Tg/year), yielding a total influx of from 1 to 10 Tg/year, up to 50% of which may be anthropogenic. Considerations of carbonyl sulfide sinks and concentrations indicate an atmospheric lifetime of one year, with OCS the major atmospheric sulfur compound. It is estimated that a ten-fold increase in atmospheric carbonyl sulfide would cause an optical depth perturbation comparable to that of a modest volcanic eruption, leading to an average global surface temperature decrease of 0.1 K, in addition to a possible greenhouse effect.

The capability of satellite borne remote sensors to measure stratospheric trace constituents. Volume 2: Ozone and aerosol related missions

NASA Technical Reports Server (NTRS)

Keitz, E. L.

1978-01-01

Stratospheric trace constituent measurement requirements are separated into two somewhat overlapping areas. In the first area, it is assumed that the only problem of interest is ozone; its chemistry chain, environmental effects and measurement requirements. In like manner, in the second area it is assumed that the only problem of interest is stratospheric aerosols; their chemistry, effects and measurement requirements.

Quantifying the risks of solid aerosol geoengineering: the role of fundamental material properties

NASA Astrophysics Data System (ADS)

Dykema, J. A.; Keutsch, F. N.; Keith, D.

2017-12-01

Solid aerosols have been considered as an alternative to sulfate aerosols for solar geoengineering due to their optical and chemical properties, which lead to different and possibly more attractive risk profiles. Solid aerosols can achieve higher solar scattering efficiency due to their higher refractive index, and in some cases may also be less effective absorbers of thermal infrared radiation. The optical properties of solid aerosols are however sensitive functions of the detailed physical properties of solid materials in question. The relevant details include the exact crystalline structure of the aerosols, the physical size of the particles, and interactions with background stratospheric molecular and particulate constituents. In this work, we examine the impact of these detailed physical properties on the radiative properties of calcite (CaCO3) solid aerosols. We examine how crystal morphology, size, chemical reactions, and interaction with background stratospheric aerosol may alter the scattering and absorption properties of calcite aerosols for solar and thermal infrared radiation. For example, in small particles, crystal lattice vibrations associated with the particle surface may lead to substantially different infrared absorption properties than bulk materials. We examine the wavelength dependence of absorption by the particles, which may lead to altered patterns of stratospheric radiative heating and equilibrium temperatures. Such temperature changes can lead to dynamical changes, with consequences for both stratospheric composition and tropospheric climate. We identify important uncertainties in the current state of understanding, investigate risks associated with these uncertainties, and survey potential approaches to quantitatively improving our knowledge of the relevant material properties.

Formation of Polar Stratospheric Clouds in the Atmosphere

NASA Astrophysics Data System (ADS)

Aloyan, Artash; Yermakov, Alex; Arutyunyan, Vardan; Larin, Igor

2014-05-01

A new mathematical model of the global transport of gaseous species and aerosols in the atmosphere and the formation of polar stratospheric clouds (PSCs) in both hemispheres was constructed. PSCs play a significant role in ozone chemistry since heterogeneous reactions proceed on their particle surfaces and in the bulk, affecting the gas composition of the atmosphere, specifically, the content of chlorine and nitrogen compounds, which are actively involved in the destruction of ozone. Stratospheric clouds are generated by co-condensation of water vapor and nitric acid on sulfate particles and in some cases during the freezing of supercooled water as well as when nitric acid vapors are dissolved in sulfate aerosol particles [1]. These clouds differ in their chemical composition and microphysics [2]. In this study, we propose new kinetic equations describing the variability of species in the gas and condensed phases to simulate the formation of PSCs. Most models for the formation of PSCs use constant background values of sulfate aerosols in the lower stratosphere. This approach is too simplistic since sulfate aerosols in the stratosphere are characterized by considerably nonuniform spatial and temporal variations. Two PSC types are considered: Type 1 refers to the formation of nitric acid trihydrate (NAT) and Type 2 refers to the formation of particles composed of different proportions of H2SO4/HNO3/H2O. Their formation is coupled with the spatial problem of sulfate aerosol generation in the upper troposphere and lower stratosphere incorporating the chemical and kinetic transformation processes (photochemistry, nucleation, condensation/evaporation, and coagulation) and using a non-equilibrium particle-size distribution [3]. In this formulation, the system of equations is closed and allows an adequate description of the PSC dynamics in the stratosphere. Using the model developed, numerical experiments were performed to reproduce the spatial and temporal variability of

SAM-2 ground-truth plan: Correlative measurements for the Stratospheric Aerosol Measurement-2 (SAM 2) sensor on the Nimbus G satellite

NASA Technical Reports Server (NTRS)

Russell, P. B.; Mccormick, M. P.; Mcmaster, L. R.; Pepin, T. J.; Chu, W. P.; Swissler, T. J.

1978-01-01

The SAM-2 will fly aboard the Nimbus-G satellite for launch in the fall of 1978 and measure stratospheric vertical profiles of aerosol extinction in high latitude bands. The plan gives details of the location and times for the simultaneous satellite/correlative measurements for the nominal launch time, the rationale and choice of the correlative sensors, their characteristics and expected accuracies, and the conversion of their data to extinction profiles. The SAM-2 expected instrument performance and data inversion results are presented. Various atmospheric models representative of polar stratospheric aerosols are used in the SAM-2 and correlative sensor analyses.

NDSC and JPL stratospheric lidars

NASA Technical Reports Server (NTRS)

McDermid, I. Stuart

1995-01-01

The Network for the Detection of Stratospheric Change is an international cooperation providing a set of high-quality, remote-sensing instruments at observing stations around the globe. A brief description of the NDSC and its goals is presented. Lidar has been selected as the NDSC instrument for measurements of stratospheric profiles of ozone, temperature, and aerosol. The Jet Propulsion Laboratory has developed and implemented two stratospheric lidar systems for NDSC. These are located at Table Mountain, California, and at Mauna Loa, Hawaii. These systems, which utilize differential absorption lidar, Rayleigh lidar, raman lidar, and backscatter lidar, to measure ozone, temperature, and aerosol profiles in the stratosphere are briefly described. Examples of results obtained for both long-term and individual profiles are presented.

Stratospheric Ozone Response in Experiments G3 and G4 of the Geoengineering Model Intercomparison Project (GeoMIP)

NASA Technical Reports Server (NTRS)

Pitari, Giovanni; Aquila, Valentina; Kravitz, Ben; Watanabe, Shingo; Tilmes, Simone; Mancini, Eva; DeLuca, Natalia; DiGenova, Glauco

2013-01-01

Geoengineering with stratospheric sulfate aerosols has been proposed as a means of temporarily cooling the planet, alleviating some of the side effects of anthropogenic CO2 emissions. However, one of the known side effects of stratospheric injections of sulfate aerosols is a decrease in stratospheric ozone. Here we show results from two general circulation models and two coupled chemistry climate models that have simulated stratospheric sulfate aerosol geoengineering as part of the Geoengineering Model Intercomparison Project (GeoMIP). Changes in photolysis rates and upwelling of ozone-poor air in the tropics reduce stratospheric ozone, suppression of the NOx cycle increases stratospheric ozone, and an increase in available surfaces for heterogeneous chemistry modulates reductions in ozone. On average, the models show a factor 20-40 increase of the sulfate aerosol surface area density (SAD) at 50 hPa in the tropics with respect to unperturbed background conditions and a factor 3-10 increase at mid-high latitudes. The net effect for a tropical injection rate of 5 Tg SO2 per year is a decrease in globally averaged ozone by 1.1-2.1 DU in the years 2040-2050 for three models which include heterogeneous chemistry on the sulfate aerosol surfaces. GISS-E2-R, a fully coupled general circulation model, performed simulations with no heterogeneous chemistry and a smaller aerosol size; it showed a decrease in ozone by 9.7 DU. After the year 2050, suppression of the NOx cycle becomes more important than destruction of ozone by ClOx, causing an increase in total stratospheric ozone. Contribution of ozone changes in this experiment to radiative forcing is 0.23 W m-2 in GISS-E2-R and less than 0.1 W m-2 in the other three models. Polar ozone depletion, due to enhanced formation of both sulfate aerosol SAD and polar stratospheric clouds, results in an average 5 percent increase in calculated surface UV-B.

The Climate Response to Stratospheric Aerosol Geoengineering Can Be Tailored Using Multiple Injection Locations

NASA Astrophysics Data System (ADS)

MacMartin, Douglas G.; Kravitz, Ben; Tilmes, Simone; Richter, Jadwiga H.; Mills, Michael J.; Lamarque, Jean-Francois; Tribbia, Joseph J.; Vitt, Francis

2017-12-01

By injecting different amounts of SO2 at multiple different latitudes, the spatial pattern of aerosol optical depth (AOD) can be partially controlled. This leads to the ability to influence the climate response to geoengineering with stratospheric aerosols, providing the potential for design. We use simulations from the fully coupled whole-atmosphere chemistry climate model CESM1(WACCM) to demonstrate that by appropriately combining injection at just four different locations, 30°S, 15°S, 15°N, and 30°N, then three spatial degrees of freedom of AOD can be achieved: an approximately spatially uniform AOD distribution, the relative difference in AOD between Northern and Southern Hemispheres, and the relative AOD in high versus low latitudes. For forcing levels that yield 1-2°C cooling, the AOD and surface temperature response are sufficiently linear in this model so that the response to different combinations of injection at different latitudes can be estimated from single-latitude injection simulations; nonlinearities associated with both aerosol growth and changes to stratospheric circulation will be increasingly important at higher forcing levels. Optimized injection at multiple locations is predicted to improve compensation of CO2-forced climate change relative to a case using only equatorial aerosol injection (which overcools the tropics relative to high latitudes). The additional degrees of freedom can be used, for example, to balance the interhemispheric temperature gradient and the equator to pole temperature gradient in addition to the global mean temperature. Further research is needed to better quantify the impacts of these strategies on changes to long-term temperature, precipitation, and other climate parameters.

Effects of Volcanic Eruptions on Stratospheric Ozone Recovery

NASA Technical Reports Server (NTRS)

Rosenfield, Joan E.

2002-01-01

The effects of the stratospheric sulfate aerosol layer associated with the Mt. Pinatubo volcano and future volcanic eruptions on the recovery of the ozone layer is studied with an interactive two-dimensional photochemical model. The time varying chlorine loading and the stratospheric cooling due to increasing carbon dioxide have been taken into account. The computed ozone and temperature changes associated with the Mt. Pinatubo eruption in 1991 agree well with observations. Long model runs out to the year 2050 have been carried out, in which volcanoes having the characteristics of the Mount Pinatubo volcano were erupted in the model at 10-year intervals starting in the year 2010. Compared to a non-volcanic run using background aerosol loading, transient reductions of globally averaged column ozone of 2-3 percent were computed as a result of each of these eruptions, with the ozone recovering to that computed for the non-volcanic case in about 5 years after the eruption. Computed springtime Arctic column ozone losses of from 10 to 18 percent also recovered to the non-volcanic case within 5 years. These results suggest that the long-term recovery of ozone would not be strongly affected by infrequent volcanic eruptions with a sulfur loading approximating Mt. Pinatubo. Sensitivity studies in which the Arctic lower stratosphere was forced to be 4 K and 10 K colder resulted in transient ozone losses of which also recovered to the non-volcanic case in 5 years. A case in which a volcano five times Mt. Pinatubo was erupted in the year 2010 led to maximum springtime column ozone losses of 45 percent which took 10 years to recover to the background case. Finally, in order to simulate a situation in which frequent smaller volcanic eruptions result in increasing the background sulfate loading, a simulation was made in which the background aerosol was increased by 10 percent per year. This resulted in a delay of the recovery of column ozone to 1980 values of more than 10 years.

Measuring the characteristics of stratospheric aerosol layer and total ozone concentration at Siberian Lidar Station in Tomsk

NASA Astrophysics Data System (ADS)

Nevzorov, Aleksey; Bazhenov, Oleg; Burlakov, Vladimir; Dolgii, Sergey

2015-11-01

We consider the results of long-term remote optical monitoring, obtained at the Siberian Lidar Station of Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences in Tomsk (56.5 °N, 85.0 °E). The scattering characteristics of stratospheric aerosol layer, obtained according to data of lidar measurements since 1986, are presented. We analyze the trends of changes in the total ozone (TO) content over Tomsk for the period 1996-2013 according to data of spectrophotometric measurements with employment of TOMS satellite data for the period 1979- 1994. We determined the periods of elevated content of stratospheric aerosol over Tomsk after a series of explosive eruptions of volcanoes of Pacific Ring of Fire and Iceland in 2006-2011. Since the second half of 1990s, researchers record an increasing TO trend, equaling 0.65 DU/yr for the period 1996-2013.

Tiny Ultraviolet Polarimeter for Earth Stratosphere from Space Investigation

NASA Astrophysics Data System (ADS)

Nevodovskyi, P. V.; Morozhenko, O. V.; Vidmachenko, A. P.; Ivakhiv, O.; Geraimchuk, M.; Zbrutskyi, O.

2015-09-01

One of the reasons for climate change (i.e., stratospheric ozone concentrations) is connected with the variations in optical thickness of aerosols in the upper sphere of the atmosphere (at altitudes over 30 km). Therefore, aerosol and gas components of the atmosphere are crucial in the study of the ultraviolet (UV) radiation passing upon the Earth. Moreover, a scrupulous study of aerosol components of the Earth atmosphere at an altitude of 30 km (i.e., stratospheric aerosol), such as the size of particles, the real part of refractive index, optical thickness and its horizontal structure, concentration of ozone or the upper border of the stratospheric ozone layer is an important task in the research of the Earth climate change. At present, the Main Astronomical Observatory of the National Academy of Sciences (NAS) of Ukraine, the National Technical University of Ukraine "KPI"and the Lviv Polytechnic National University are engaged in the development of methodologies for the study of stratospheric aerosol by means of ultraviolet polarimeter using a microsatellite. So fare, there has been created a sample of a tiny ultraviolet polarimeter (UVP) which is considered to be a basic model for carrying out space experiments regarding the impact of the changes in stratospheric aerosols on both global and local climate.

A study on characterization of stratospheric aerosol and gas parameters with the spacecraft solar occultation experiment

NASA Technical Reports Server (NTRS)

Chu, W. P.

1977-01-01

Spacecraft remote sensing of stratospheric aerosol and ozone vertical profiles using the solar occultation experiment has been analyzed. A computer algorithm has been developed in which a two step inversion of the simulated data can be performed. The radiometric data are first inverted into a vertical extinction profile using a linear inversion algorithm. Then the multiwavelength extinction profiles are solved with a nonlinear least square algorithm to produce aerosol and ozone vertical profiles. Examples of inversion results are shown illustrating the resolution and noise sensitivity of the inversion algorithms.

Volcanic aerosols: Chemistry, evolution, and effects

NASA Technical Reports Server (NTRS)

Turco, Richard

1991-01-01

Stratospheric aerosols have been the subject of scientific speculation since the 1880s, when the powerful eruption of Krakatoa attracted worldwide attention to the upper atmosphere through spectacular optical displays. The presence of a permanent tenuous dust layer in the lower stratosphere was postulated in the 1920s following studies of the twilight glow. Junge collected the first samples of these 'dust' particles and demonstrated that they were actually composed of sulfates, most likely concentrated sulfuric acid (Junge and Manson, 1961; Junge, 1963). Subsequent research has been spurred by the realization that stratospheric particles can influence the surface climate of earth through their effects on atmospheric radiation. Such aerosols can also influence, through chemical and physical effects, the trace composition of the atmosphere, ozone concentrations, and atmospheric electrical properties. The properties of stratospheric aerosols (both the background particles and those enhanced by volcanic eruptions) were measured in situ by balloon ascents and high altitude aircraft sorties. The aerosols were also observed remotely from the ground and from satellites using both active (lidar) and passive (solar occultation) techniques (remote sensing instruments were carried on aircraft and balloon platforms as well). In connection with the experimental work, models were developed to test theories of particle formation and evolution, to guide measurement strategies, to provide a means of connecting laboratory and field data, and to apply the knowledge gained to answer practical questions about global changes in climate, depletion of the ozone layer, and related environmental problems.

Stratospheric aluminum oxide.

PubMed

Brownlee, D E; Ferry, G V; Tomandl, D

1976-03-26

Balloons and U-2 aircraft were used to collect micrometer-sized strato-spheric aerosols. It was discovered that for the past 6 years at least, aluminum oxide spheres have been the major stratospheric particulate in the size range 3 to 8 micrometers. The most probable source of the spheres is the exhaust from solid-fuel rockets.

Estimated SAGE II ozone mixing ratios in early 1993 and comparisons with Stratospheric Photochemistry, Aerosols and Dynamic Expedition measurements

NASA Technical Reports Server (NTRS)

Yue, G. K.; Veiga, R. E.; Poole, L. R.; Zawodny, J. M.; Proffitt, M. H.

1994-01-01

An empirical time-series model for estimating ozone mixing ratios based on Stratospheric Aerosols and Gas Experiment II (SAGE II) monthly mean ozone data for the period October 1984 through June 1991 has been developed. The modeling results for ozone mixing ratios in the 10- to 30- km region in early months of 1993 are presented. In situ ozone profiles obtained by a dual-beam UV-absorption ozone photometer during the Stratospheric Photochemistry, Aerosols and Dynamics Expedition (SPADE) campaign, May 1-14, 1993, are compared with the model results. With the exception of two profiles at altitudes below 16 km, ozone mixing ratios derived by the model and measured by the ozone photometer are in relatively good agreement within their individual uncertainties. The identified discrepancies in the two profiles are discussed.

Observations of Stratospheric Gravity Waves During the WB57F Aerosol Mission and Modeling with Mesoscale Model 5

NASA Technical Reports Server (NTRS)

Mahoney, M.; Hicke, J.; Rosenlof, K.; Tuck, A.; Hovde, S.

2000-01-01

On April 11, 1998 WB57F aircraft flew northwest at lower stratospheric altitudes from Houston, Texas, over eastern Wyoming as part of the WB57F Aerosol Mission to sample a vortex filament forecast to pass over that region.

Algorithms and sensitivity analyses for Stratospheric Aerosol and Gas Experiment II water vapor retrieval

NASA Technical Reports Server (NTRS)

Chu, W. P.; Chiou, E. W.; Larsen, J. C.; Thomason, L. W.; Rind, D.; Buglia, J. J.; Oltmans, S.; Mccormick, M. P.; Mcmaster, L. M.

1993-01-01

The operational inversion algorithm used for the retrieval of the water-vapor vertical profiles from the Stratospheric Aerosol and Gas Experiment II (SAGE II) occultation data is presented. Unlike the algorithm used for the retrieval of aerosol, O3, and NO2, the water-vapor retrieval algorithm accounts for the nonlinear relationship between the concentration versus the broad-band absorption characteristics of water vapor. Problems related to the accuracy of the computational scheme, the accuracy of the removal of other interfering species, and the expected uncertainty of the retrieved profile are examined. Results are presented on the error analysis of the SAGE II water vapor retrieval, indicating that the SAGE II instrument produced good quality water vapor data.

Calibration correction of an active scattering spectrometer probe to account for refractive index of stratospheric aerosols

NASA Technical Reports Server (NTRS)

Pueschel, R. F.; Overbeck, V. R.; Snetsinger, K. G.; Russell, P. B.; Ferry, G. V.

1990-01-01

The use of the active scattering spectrometer probe (ASAS-X) to measure sulfuric acid aerosols on U-2 and ER-2 research aircraft has yielded results that are at times ambiguous due to the dependence of particles' optical signatures on refractive index as well as physical dimensions. The calibration correction of the ASAS-X optical spectrometer probe for stratospheric aerosol studies is validated through an independent and simultaneous sampling of the particles with impactors; sizing and counting of particles on SEM images yields total particle areas and volumes. Upon correction of calibration in light of these data, spectrometer results averaged over four size distributions are found to agree with similarly averaged impactor results to within a few percent: indicating that the optical properties or chemical composition of the sample aerosol must be known in order to achieve accurate optical aerosol spectrometer size analysis.

Solar Mesosphere Explorer satellite measurements of el Chichon stratospheric aerosols. 1: Cloud morphology

NASA Technical Reports Server (NTRS)

Rusch, D. W.; Clancy, R. T.; Eparvier, F. G.; Thomas, G. E.; Thomas, R. J.

1994-01-01

Data from the Solar Mesosphere Explorer (SME) is used to track the time, latitude, and altitude (above 18 km) development of the aerosol cloud injected into the stratosphere by the eruption of el Chichon. This unique data set, using scattering data from the near-infrared (1.27 and 1.87 microns) and visible (440 nm) spectrometers on SME, covers the period from the initial injection in April 1982 through the end of 1986. Although the bulk of the mass is contained in the latitude band from 10 deg S to 30 deg N for the entire duration of the measurements, transport of material to high latitudes is apparent in the data in the post eruption period. The times aerosol density maxima vary greatly as a function of altitude and latitude.

On the Stratospheric Aerosol and Gas Experiment III on the International Space Station

NASA Technical Reports Server (NTRS)

Hernandez, Gloria; Zawodny, Joseph M.; Cisewski, Michael S.; Thornton, Brooke M.; Panetta, Andrew D,; Roell, Marilee M.; Vernier, Jean-Paul

2014-01-01

The Stratospheric Aerosol and Gas Experiment III on International Space Station (SAGE3/ISS) is anticipated to be delivered to Cape Canaveral in the spring of 2015. This is the fourth generation, fifth instrument, of visible/near-IR solar occultation instruments operated by the National Aeronautics and Space Agency (NASA) to investigate the Earth's upper atmosphere. The instrument is a moderate resolution spectrometer covering wavelengths from 290 nm to 1550 nm. The nominal science products include vertical profiles of trace gases, such as ozone, nitrogen dioxide and water vapor, along with multi-wavelength aerosol extinction. The SAGE3/ISS validation program will be based upon internal consistency of the measurements, detailed analysis of the retrieval algorithm, and comparisons with independent correlative measurements. The Instrument Payload (IP), mission architecture, and major challenges are also discussed.

SPARC's Stratospheric Sulfur and its Role in Climate Activity (SSiRC)

NASA Technical Reports Server (NTRS)

Thomason, Larry

2015-01-01

The stratospheric aerosol layer is a key component in the climate system. It affects the radiative balance of the atmosphere directly through interactions with solar and terrestrial radiation, and indirectly through its effect on stratospheric ozone. Because the stratospheric aerosol layer is prescribed in many climate models and Chemistry-Climate Models (CCMs), model simulations of future atmospheric conditions and climate generally do not account for the interaction between the aerosol-sulfur cycle and changes in the climate system. The present understanding of how the stratospheric aerosol layer may be affected by future climate change and how the stratospheric aerosol layer may drive climate change is, therefore, very limited. The purposes of SSiRC (Stratospheric Sulfur and its Role in Climate) include: (i) providing a coordinating structure for the various individual activities already underway in different research centers; (ii) encouraging and supporting new instrumentation and measurements of sulfur containing compounds, such as COS, DMS, and non-volcanic SO2 in the UT/LS globally; and (iii) initiating new model/data inter-comparisons. SSiRC is developing collaborations with a number of other SPARC activities including CCMI and ACAM. This presentation will highlight the scientific goals of this project and on-going activities and propose potential interactions between SSiRC and ACAM.

Balloon profiles of stratospheric NO2 and HNO3 for testing the heterogeneous hydrolysis of N2O5 on sulfate aerosols

NASA Technical Reports Server (NTRS)

Webster, C. R.; May, R. D.; Allen, M.; Jaegle, L.; Mccormick, M. P.

1994-01-01

Simultaneous in situ measurements of stratospheric NO2, HNO3, HCl, and CH4 from 34 to 24 km were made in August 1992 from Palestine, Texas, using the Balloon-borne Laser In-Situ Sensor (BLISS) tunable diode laser spectrometer. Although the measurements of NO2, HNO3, and NO2/HNO3 agree well with gas-phase model calculations near 34 km where Stratospheric Aerosol and Gas Experiment (SAGE) 2 data show little sulfate aerosol, this is not true at the lower altitudes where SAGE 2 shows high aerosol loadings. At 24 km the BLISS NO2 and HNO3 measurements are 70% lower and 50% higher, respectively, than the gas phase model predictions, with a measured NO2/HNO3 ratio 5 times smaller. When the heterogeneous hydrolysis of N2O5 and ClONO2 on sulfate aerosol of surface area densities matching the SAGE 2 measurements is added to the model, good agreement with the BLISS measurements is found over the whole altitude range.

Condensed Acids In Antartic Stratospheric Clouds

NASA Technical Reports Server (NTRS)

Pueschel, R. F.; Snetsinger, K. G.; Toon, O. B.; Ferry, G. V.; Starr, W. L.; Oberbeck, V. R.; Chan, K. R.; Goodman, J. K.; Livingston, J. M.; Verma, S.;

Stratospheric Heterogeneous Chemistry and Microphysics: Model Development, Validation and Applications

NASA Technical Reports Server (NTRS)

Turco, Richard P.

1996-01-01

The objectives of this project are to: define the chemical and physical processes leading to stratospheric ozone change that involve polar stratospheric clouds (PSCS) and the reactions occurring on the surfaces of PSC particles; study the formation processes, and the physical and chemical properties of PSCS, that are relevant to atmospheric chemistry and to the interpretation of field measurements taken during polar stratosphere missions; develop quantitative models describing PSC microphysics and heterogeneous chemical processes; assimilate laboratory and field data into these models; and calculate the extent of chemical processing on PSCs and the impact of specific microphysical processes on polar composition and ozone depletion. During the course of the project, a new coupled microphysics/physical-chemistry/ photochemistry model for stratospheric sulfate aerosols and nitric acid and ice PSCs was developed and applied to analyze data collected during NASA's Arctic Airborne Stratospheric Expedition-II (AASE-II) and other missions. In this model, detailed treatments of multicomponent sulfate aerosol physical chemistry, sulfate aerosol microphysics, polar stratospheric cloud microphysics, PSC ice surface chemistry, as well as homogeneous gas-phase chemistry were included for the first time. In recent studies focusing on AASE measurements, the PSC model was used to analyze specific measurements from an aircraft deployment of an aerosol impactor, FSSP, and NO(y) detector. The calculated results are in excellent agreement with observations for particle volumes as well as NO(y) concentrations, thus confirming the importance of supercooled sulfate/nitrate droplets in PSC formation. The same model has been applied to perform a statistical study of PSC properties in the Northern Hemisphere using several hundred high-latitude air parcel trajectories obtained from Goddard. The rates of ozone depletion along trajectories with different meteorological histories are presently

Benefits, risks, and costs of stratospheric geoengineering

NASA Astrophysics Data System (ADS)

Robock, Alan; Marquardt, Allison; Kravitz, Ben; Stenchikov, Georgiy

2009-10-01

Injecting sulfate aerosol precursors into the stratosphere has been suggested as a means of geoengineering to cool the planet and reduce global warming. The decision to implement such a scheme would require a comparison of its benefits, dangers, and costs to those of other responses to global warming, including doing nothing. Here we evaluate those factors for stratospheric geoengineering with sulfate aerosols. Using existing U.S. military fighter and tanker planes, the annual costs of injecting aerosol precursors into the lower stratosphere would be several billion dollars. Using artillery or balloons to loft the gas would be much more expensive. We do not have enough information to evaluate more exotic techniques, such as pumping the gas up through a hose attached to a tower or balloon system. Anthropogenic stratospheric aerosol injection would cool the planet, stop the melting of sea ice and land-based glaciers, slow sea level rise, and increase the terrestrial carbon sink, but produce regional drought, ozone depletion, less sunlight for solar power, and make skies less blue. Furthermore it would hamper Earth-based optical astronomy, do nothing to stop ocean acidification, and present many ethical and moral issues. Further work is needed to quantify many of these factors to allow informed decision-making.

Aerosol in the Upper Troposphere Lower Stratosphere, decadal Simulations of Radiative Forcing using the Chemistry Circulation Model EMAC and MIPAS, GOMOS, IASI and other Satellite Data

NASA Astrophysics Data System (ADS)

Bruehl, C.; Schallock, J.; Lelieveld, J.; Bingen, C.; Robert, C. E.; Hoepfner, M.; Clarisse, L.

2017-12-01

The atmospheric chemistry - general circulation model EMAC with a modal interactive aerosol module is used to estimate radiative effects of UTLS aerosol for the ENVISAT period 2002 to 2012 in the framework of SPARC/SSIRC. Volcanic SO2 injections by about 230 explosive volcano eruptions are estimated mostly from MIPAS limb observations. For periods of data gaps, injected SO2 is estimated indirectly from extinctions observed by GOMOS. GOMOS extinctions in the UTLS and the seasonal component of radiative forcing can be only reproduced by the model if a comprehensive treatment of desert dust and organic and black carbon is included. Upward transport of particles and gases by the Asian Monsoon appears to contribute importantly. The time series of simulated stratospheric aerosol optical depth and radiative forcing agree with the corresponding quantities derived from different satellite data sets. Comparisons of total aerosol optical depth with IASI show that tropospheric and stratospheric aerosol in the model are consistently and realistically represented.

In-situ measurements of scattering phase functions of stratospheric aerosol particles in Alaska during July 1979

NASA Technical Reports Server (NTRS)

Grams, G. W.

1981-01-01

A laser nephelometer developed for airborne measurements of polar scattering diagrams of atmospheric aerosols was flown on the NCAR Sabreliner aircraft to obtain data on light-scattering parameters for stratospheric aerosol particles over Alaska during July 1979. Observed values of the angular variation of scattered-light intensity were compared with those calculated for different values of the asymmetry parameter g in the Henyey-Greenstein phase function. The observations indicate that, for the time and location of the experiments, the Henyey-Greenstein phase function could be used to calculate polar scattering diagrams to within experimental errors for an asymmetry parameter value of 0.49 plus or minus 0.07.

Preliminary assessment of possible aerosol contamination effects on SAGE ozone trends in the lower stratosphere

NASA Technical Reports Server (NTRS)

Cunnold, Derek M.; Veiga, Robert E.

1991-01-01

An investigation of the validity of long-term ozone trends in the lower stratosphere derived from SAGE I and II measurements is described. At altitudes below approximately 20 km, it is important to separate the ozone and aerosol contributions to SAGE extinction at 600 nm. The correlation between SAGE II measurements of ozone and aerosols indicates that most of the variability in these parameters is associated with physically induced variations resulting from quasi-horizontal motions of air parcels. The SAGE ozone measurements are however found to be as much as 20 percent larger than coincident ozonesonde measurements between 15 and 20 km altitude. A sudden change in the difference at approximately 14.5 km altitude for which there is a change in the SAGE aerosol retrieval procedure suggests that SAGE ozone trends below 20 km altitude may be more sensitive to aerosol variations. Between 20 and 25 km altitude, however, both SAGE and the ozonesondes indicate a reduction in ozone of approximately 0.5 percent/year over the period 1979 to 1989 at midlatitudes of the Northern Hemisphere.

Particulate sulfur in the upper troposphere and lowermost stratosphere - sources and climate forcing

NASA Astrophysics Data System (ADS)

Martinsson, Bengt G.; Friberg, Johan; Sandvik, Oscar S.; Hermann, Markus; van Velthoven, Peter F. J.; Zahn, Andreas

2017-09-01

This study is based on fine-mode aerosol samples collected in the upper troposphere (UT) and the lowermost stratosphere (LMS) of the Northern Hemisphere extratropics during monthly intercontinental flights at 8.8-12 km altitude of the IAGOS-CARIBIC platform in the time period 1999-2014. The samples were analyzed for a large number of chemical elements using the accelerator-based methods PIXE (particle-induced X-ray emission) and PESA (particle elastic scattering analysis). Here the particulate sulfur concentrations, obtained by PIXE analysis, are investigated. In addition, the satellite-borne lidar aboard CALIPSO is used to study the stratospheric aerosol load. A steep gradient in particulate sulfur concentration extends several kilometers into the LMS, as a result of increasing dilution towards the tropopause of stratospheric, particulate sulfur-rich air. The stratospheric air is diluted with tropospheric air, forming the extratropical transition layer (ExTL). Observed concentrations are related to the distance to the dynamical tropopause. A linear regression methodology handled seasonal variation and impact from volcanism. This was used to convert each data point into stand-alone estimates of a concentration profile and column concentration of particulate sulfur in a 3 km altitude band above the tropopause. We find distinct responses to volcanic eruptions, and that this layer in the LMS has a significant contribution to the stratospheric aerosol optical depth and thus to its radiative forcing. Further, the origin of UT particulate sulfur shows strong seasonal variation. We find that tropospheric sources dominate during the fall as a result of downward transport of the Asian tropopause aerosol layer (ATAL) formed in the Asian monsoon, whereas transport down from the Junge layer is the main source of UT particulate sulfur in the first half of the year. In this latter part of the year, the stratosphere is the clearly dominating source of particulate sulfur in the UT

Uniwavelength lidar sensitivity to spherical aerosol microphysical properties for the interpretation of Lagrangian stratospheric observations

NASA Astrophysics Data System (ADS)

Jumelet, Julien; David, Christine; Bekki, Slimane; Keckhut, Philippe

2009-01-01

The determination of stratospheric particle microphysical properties from multiwavelength lidar, including Rayleigh and/or Raman detection, has been widely investigated. However, most lidar systems are uniwavelength operating at 532 nm. Although the information content of such lidar data is too limited to allow the retrieval of the full size distribution, the coupling of two or more uniwavelength lidar measurements probing the same moving air parcel may provide some meaningful size information. Within the ORACLE-O3 IPY project, the coordination of several ground-based lidars and the CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) space-borne lidar is planned during measurement campaigns called MATCH-PSC (Polar Stratospheric Clouds). While probing the same moving air masses, the evolution of the measured backscatter coefficient (BC) should reflect the variation of particles microphysical properties. A sensitivity study of 532 nm lidar particle backscatter to variations of particles size distribution parameters is carried out. For simplicity, the particles are assumed to be spherical (liquid) particles and the size distribution is represented with a unimodal log-normal distribution. Each of the four microphysical parameters (i.e. log-normal size distribution parameters, refractive index) are analysed separately, while the three others are remained set to constant reference values. Overall, the BC behaviour is not affected by the initial values taken as references. The total concentration (N0) is the parameter to which BC is least sensitive, whereas it is most sensitive to the refractive index (m). A 2% variation of m induces a 15% variation of the lidar BC, while the uncertainty on the BC retrieval can also reach 15%. This result underlines the importance of having both an accurate lidar inversion method and a good knowledge of the temperature for size distribution retrieval techniques. The standard deviation ([sigma]) is the second

Biological aerosol background characterization

NASA Astrophysics Data System (ADS)

Blatny, Janet; Fountain, Augustus W., III

2011-05-01

To provide useful information during military operations, or as part of other security situations, a biological aerosol detector has to respond within seconds or minutes to an attack by virulent biological agents, and with low false alarms. Within this time frame, measuring virulence of a known microorganism is extremely difficult, especially if the microorganism is of unknown antigenic or nucleic acid properties. Measuring "live" characteristics of an organism directly is not generally an option, yet only viable organisms are potentially infectious. Fluorescence based instruments have been designed to optically determine if aerosol particles have viability characteristics. Still, such commercially available biological aerosol detection equipment needs to be improved for their use in military and civil applications. Air has an endogenous population of microorganisms that may interfere with alarm software technologies. To design robust algorithms, a comprehensive knowledge of the airborne biological background content is essential. For this reason, there is a need to study ambient live bacterial populations in as many locations as possible. Doing so will permit collection of data to define diverse biological characteristics that in turn can be used to fine tune alarm algorithms. To avoid false alarms, improving software technologies for biological detectors is a crucial feature requiring considerations of various parameters that can be applied to suppress alarm triggers. This NATO Task Group will aim for developing reference methods for monitoring biological aerosol characteristics to improve alarm algorithms for biological detection. Additionally, they will focus on developing reference standard methodology for monitoring biological aerosol characteristics to reduce false alarm rates.

Stratospheric changes caused by geoengineering applications: potential repercussions and uncertainties

NASA Astrophysics Data System (ADS)

Kenzelmann, P.; Weisenstein, D.; Peter, T.; Luo, B. P.; Rozanov, E.; Fueglistaler, S.; Thomason, L. W.

2009-04-01

Anthropogenic greenhouse gas emissions tend to warm the global climate, calling for significant rapid emission reductions. As potential support measures various ideas for geoengineering are currently being discussed. The assessment of the possible manifold and as yet substantially unexplored repercussions of implementing geoengineering ideas to ameliorate climate change poses enormous challenges not least in the realm of aerosol-cloud-climate interactions. Sulphur aerosols cool the Earth's surface by reflecting short wave radiation. By increasing the amount of sulphur aerosols in the stratosphere, for example by sulphur dioxide injections, part of the anthropogenic climate warming might be compensated due to enhanced albedo. However, we are only at the beginning of understanding possible side effects. One such effect that such aerosol might have is the warming of the tropical tropopause and consequently the increase of the amount of stratospheric water vapour. Using the 2D AER Aerosol Model we calculated the aerosol distributions for yearly injections of 1, 2, 5 and 10 Mt sulphur into the lower tropical stratosphere. The results serve as input for the 3D chemistry-climate model SOCOL, which allows calculating the aerosol effect on stratospheric temperatures and chemistry. In the injection region the continuously formed sulphuric acid condensates rapidly on sulphate aerosol, which eventually grow to such extent that they sediment down to the tropical tropopause region. The growth of the aerosol particles depends on non-linear processes: the more sulphur is emitted the faster the particles grow. As a consequence for the scenario with continuous sulphur injection of totally 10 Mt per year, only 6 Mt sulphur are in the stratosphere if equilibrium is reached. According to our model calculations this amount of sulphate aerosols leads to a net surface forcing of -3.4 W/m2, which is less then expected radiative forcing by doubling of carbon dioxide concentration. Hence

Inversion of solar extinction data from the Apollo-Soyuz Test Project Stratospheric Aerosol Measurement (ASTP/SAM) experiment

NASA Technical Reports Server (NTRS)

Pepin, T. J.

1977-01-01

The inversion methods are reported that have been used to determine the vertical profile of the extinction coefficient due to the stratospheric aerosols from data measured during the ASTP/SAM solar occultation experiment. Inversion methods include the onion skin peel technique and methods of solving the Fredholm equation for the problem subject to smoothing constraints. The latter of these approaches involves a double inversion scheme. Comparisons are made between the inverted results from the SAM experiment and near simultaneous measurements made by lidar and balloon born dustsonde. The results are used to demonstrate the assumptions required to perform the inversions for aerosols.

Arctic “ozone hole” in a cold volcanic stratosphere

PubMed Central

Tabazadeh, A.; Drdla, K.; Schoeberl, M. R.; Hamill, P.; Toon, O. B.

2002-01-01

Optical depth records indicate that volcanic aerosols from major eruptions often produce clouds that have greater surface area than typical Arctic polar stratospheric clouds (PSCs). A trajectory cloud–chemistry model is used to study how volcanic aerosols could affect springtime Arctic ozone loss processes, such as chlorine activation and denitrification, in a cold winter within the current range of natural variability. Several studies indicate that severe denitrification can increase Arctic ozone loss by up to 30%. We show large PSC particles that cause denitrification in a nonvolcanic stratosphere cannot efficiently form in a volcanic environment. However, volcanic aerosols, when present at low altitudes, where Arctic PSCs cannot form, can extend the vertical range of chemical ozone loss in the lower stratosphere. Chemical processing on volcanic aerosols over a 10-km altitude range could increase the current levels of springtime column ozone loss by up to 70% independent of denitrification. Climate models predict that the lower stratosphere is cooling as a result of greenhouse gas built-up in the troposphere. The magnitude of column ozone loss calculated here for the 1999–2000 Arctic winter, in an assumed volcanic state, is similar to that projected for a colder future nonvolcanic stratosphere in the 2010 decade. PMID:11854461

Sulfur deposition changes under sulfate geoengineering conditions: quasi-biennial oscillation effects on the transport and lifetime of stratospheric aerosols

NASA Astrophysics Data System (ADS)

Visioni, Daniele; Pitari, Giovanni; Tuccella, Paolo; Curci, Gabriele

2018-02-01

Sustained injection of sulfur dioxide (SO2) in the tropical lower stratosphere has been proposed as a climate engineering technique for the coming decades. Among several possible environmental side effects, the increase in sulfur deposition deserves additional investigation. In this study we present results from a composition-climate coupled model (University of L'Aquila Composition-Chemistry Model, ULAQ-CCM) and a chemistry-transport model (Goddard Earth Observing System Chemistry-Transport Model, GEOS-Chem), assuming a sustained lower-stratospheric equatorial injection of 8 Tg SO2 yr-1. Total S deposition is found to globally increase by 5.2 % when sulfate geoengineering is deployed, with a clear interhemispheric asymmetry (+3.8 and +10.3 % in the Northern Hemisphere (NH) and the Southern Hemisphere (SH), due to +2.2 and +1.8 Tg S yr-1, respectively). The two models show good consistency, both globally and on a regional scale under background and geoengineering conditions, except for S-deposition changes over Africa and the Arctic. The consistency exists with regard to time-averaged values but also with regard to monthly and interannual deposition changes. The latter is driven essentially by the variability in stratospheric large-scale transport associated with the quasi-biennial oscillation (QBO). Using an externally nudged QBO, it is shown how a zonal wind E shear favors aerosol confinement in the tropical pipe and a significant increase in their effective radius (+13 % with respect to W shear conditions). The net result is an increase in the downward cross-tropopause S flux over the tropics with dominant E shear conditions with respect to W shear periods (+0.61 Tg S yr-1, +42 %, mostly due to enhanced aerosol gravitational settling) and a decrease over the extratropics (-0.86 Tg S yr-1, -35 %, mostly due to decreased large-scale stratosphere-troposphere exchange of geoengineering sulfate). This translates into S-deposition changes that are significantly

Stratospheric Aerosol and Gas Experiment II measurements of the quasi-biennial oscillations in ozone and nitrogen dioxide

NASA Technical Reports Server (NTRS)

Zawodny, Joseph M.; Mccormick, M. P.

1991-01-01

The first measurements ever to show a quasi-biennial oscillation (QBO) in NO2 have been made by the Stratospheric Aerosol and Gas Experiment II) (SAGE II) and are presented in this work along with observations of the well-known QBO in stratospheric ozone. The SAGE II instrument was launched aboard the Earth Radiation Budget satellite near the end of 1984. Measurements of ozone and nitrogen dioxide through early 1990 are analyzed for the presence of a quasi-biennial oscillation. The measurements show the global extent of both the O3 and NO2 QBO in the 25- to 40-km region of the stratosphere. The SAGE II QBO results for ozone compare favorably to theory and previous measurements. The QBO in NO2 is found to be consistent with the vertical and horizontal transport of NOy. Both species exhibit a QBO at extratropical latitudes consistent with strong meridional transport into the winter hemisphere.

Certain Results of Measurements of Characteristics of Stratospheric Aerosol Layer and Total Ozone Content at Siberian Lidar Station in Tomsk

NASA Astrophysics Data System (ADS)

Nevzorov, Aleksey; Bazhenov, Oleg; Burlakov, Vladimir; Dolgii, Sergey

2016-06-01

We consider the results of long-term remote optical monitoring, obtained at the Siberian Lidar Station of Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences in Tomsk (56.5°N, 85.0°E). The scattering characteristics of stratospheric aerosol layer, obtained according to data of lidar measurements since 1986, are presented. We analyze the trends of changes in the total ozone (TO) content over Tomsk for the period 1996-2013 according to data of spectrophotometric measurements with employment of Total Ozone Mapping Spectrometer (TOMS) data for the period 1979-1994. We determined the periods of elevated content of stratospheric aerosol over Tomsk aftera series of explosive eruptions of volcanoes of Pacific Ring of Fire and Iceland in 2006-2011. Since the second half of 1990s, we record an increasing TO trend, equaling 0.65 DU/yr for the period 1996-2013.

Volcanic stratospheric sulfur injections and aerosol optical depth from 500 BCE to 1900 CE

NASA Astrophysics Data System (ADS)

Toohey, Matthew; Sigl, Michael

2017-11-01

The injection of sulfur into the stratosphere by explosive volcanic eruptions is the cause of significant climate variability. Based on sulfate records from a suite of ice cores from Greenland and Antarctica, the eVolv2k database includes estimates of the magnitudes and approximate source latitudes of major volcanic stratospheric sulfur injection (VSSI) events from 500 BCE to 1900 CE, constituting an update of prior reconstructions and an extension of the record by 1000 years. The database incorporates improvements to the ice core records (in terms of synchronisation and dating) and refinements to the methods used to estimate VSSI from ice core records, and it includes first estimates of the random uncertainties in VSSI values. VSSI estimates for many of the largest eruptions, including Samalas (1257), Tambora (1815), and Laki (1783), are within 10 % of prior estimates. A number of strong events are included in eVolv2k which are largely underestimated or not included in earlier VSSI reconstructions, including events in 540, 574, 682, and 1108 CE. The long-term annual mean VSSI from major volcanic eruptions is estimated to be ˜ 0.5 Tg [S] yr-1, ˜ 50 % greater than a prior reconstruction due to the identification of more events and an increase in the magnitude of many intermediate events. A long-term latitudinally and monthly resolved stratospheric aerosol optical depth (SAOD) time series is reconstructed from the eVolv2k VSSI estimates, and the resulting global mean SAOD is found to be similar (within 33 %) to a prior reconstruction for most of the largest eruptions. The long-term (500 BCE-1900 CE) average global mean SAOD estimated from the eVolv2k VSSI estimates including a constant background injection of stratospheric sulfur is ˜ 0.014, 30 % greater than a prior reconstruction. These new long-term reconstructions of past VSSI and SAOD variability give context to recent volcanic forcing, suggesting that the 20th century was a period of somewhat

Trends in aerosol abundances and distributions

NASA Technical Reports Server (NTRS)

Turco, R. P.; Mccormick, M. P.; Clancy, R. T.; Curran, R.; Deluisi, J.; Hamill, P.; Kent, G.; Rosen, J. M.; Toon, O. B.; Yue, G.

1989-01-01

The properties of aerosols that reside in the upper atmosphere are described. Special emphasis is given to the influence these aerosols have on ozone observation systems, mainly through radiative effects, and on ambient ozone concentrations, mainly through chemical effects. It has long been appreciated that stratospheric particles can interfere with the remote sensing of ozone distribution. The mechanism and magnitude of this interference are evaluated. Separate sections deal with the optical properties of upper atmospheric aerosols, long-term trends in stratospheric aerosols, perturbations of the stratospheric aerosol layer by volcanic eruptions, and estimates of the impacts that such particles have on remotely measured ozone concentrations. Another section is devoted to a discussion of the polar stratospheric clouds (PSC's). These unique clouds, recently discovered by satellite observation, are now thought to be intimately connected with the Antarctic ozone hole. Accordingly, interest in PSC's has grown considerably in recent years. This chapter describes what we know about the morphology, physical chemistry, and microphysics of PSC's.

Radicals and Aerosols in the Troposphere and Lower Stratosphere

NASA Astrophysics Data System (ADS)

Volkamer, Rainer; Koenig, Theodore; Dix, Barbara

2016-06-01

The remote tropical free troposphere (FT) is one of the most relevant atmospheric environments on Earth. About 75% of the global tropospheric O3 and CH4 loss occurs at tropical latitudes. Tropospheric bromine and iodine catalytically destroy tropospheric O3, oxidize atmospheric mercury, and modify oxidative capacity, and aerosols. Oxygenated VOCs (OVOC) modify HOx (= OH + HO2), NOx (= NO + NO2), tropospheric O3, aerosols, and are a sink for BrOx (= Br + BrO). Until recently, atmospheric models were untested for lack of vertically resolved measurements of BrO and IO radicals in the tropical troposphere. BrO and IO are highly reactive trace gases. Even very low concentrations (parts per trillion; 1 pptv = 10-12 volume mixing ratio) can significantly modify the lifetime of climate active gases, and determine (bromine) the rate limiting step of mercury oxidation in air (that is washed out, and subsequently bio-accumulates in fish). Analytical challenges arise when these radicals modify in sampling lines. Sensitive yet robust, portable, and inherently calibrated measurements directly in the open atmosphere have recently been demonstrated by means of limb-measurements of scattered solar photons by the University of Colorado Airborne Multi-AXis DOAS instrument (CU AMAX-DOAS) from research aircraft. The CU AMAX-DOAS instrument is optimized to (1) locate BrO, IO and glyoxal (a short lived OVOC) in the troposphere, (2) decouple stratospheric absorbers, (3) maximize sensitivity at instrument altitude, (4) facilitate altitude control and (5) enable observations over a wide range of solar zenith angles. Further, (6) the filling-in of Fraunhofer lines (Ring-effect) by Raman Scattering offers interesting opportunities for radiative closure studies to assess the effects of aerosols on Climate.

SAGE aerosol measurements. Volume 3: January 1, 1981 to November 18, 1981

NASA Technical Reports Server (NTRS)

Mccormick, M. Patrick

1987-01-01

The Stratospheric Aerosol and Gas Experiment (SAGE) satellite system, launched February 18, 1979, obtained profiles of aerosol extinction at 1.00 micron and 0.45 micron ozone concentration, and nitrogen dioxide concentration. Data taken during sunset events are presented in the form of zonal and seasonal averages of aerosol extinction of 1.00 micron and 0.45 micron, ratios of aerosol extinction to molecular extinction at 1.00 micron and ratios of aerosol extinction at 0.45 micron to aerosol extinction at 1.00 micron. Averages for 1981 are shown in tables, and in profile and contour plots (as a function of altitude and latitude). In addition, temperature data provided by NOAA for the time and location of each SAGE measurement are averaged and shown in a similar format. The stratospheric aerosol distribution for 1981 shows effects of volcanically injected material from eruptions of Ulawun, Alaid, and Pagan. Peak values of aerosol extinction at 0.45 micron and 1.00 micron were 2 to 4 times higher than typical peak values observed during near background conditions. Stratospheric aerosol optical depth values at 1.00 microns increased by a factor of about 2 from near background levels in regions of volcanic activity. During the year, these values ranged from between 0.001 and 0.006. The largest were near the location of a recent eruption. The distribution of the ratio of aerosol to molecular extinction at 1.00 microns also showed that maximum values are found in the vicinity of an eruption. These maximums varied in altitude, but remained below a height of about 25 km. No attempt has been made to give detailed explanations or interpretations of these data. The intent is to provide, in a ready-to-use visual format, representative zonal and seasonal averages of aerosol extinction data for the third calendar year of the SAGE data set to facilitate atmospheric and climatic studies.

Unexpected high 35S concentration revealing strong downward transport of stratospheric air during the monsoon transitional period in East Asia

NASA Astrophysics Data System (ADS)

Lin, Mang; Zhang, Zhisheng; Su, Lin; Su, Binbin; Liu, Lanzhong; Tao, Jun; Fung, Jimmy C. H.; Thiemens, Mark H.

2016-03-01

October is the monsoon transitional period in East Asia (EA) involving a series of synoptic activities that may enhance the downward transport of stratospheric air to the planetary boundary layer (PBL). Here we use cosmogenic 35S in sulfate aerosols (35SO42-) as a tracer for air masses originating from the stratosphere and transported downward to quantify these mixing processes. From 1 year 35SO42- measurements (March 2014 to February 2015) at a background station in EA we find remarkably enhanced 35SO42- concentration (3150 atoms m-3) in October, the highest value ever reported for natural sulfate aerosols. A four-box 1-D model and meteorological analysis reveal that strong downward transport from the free troposphere is a vital process entraining aged stratospheric air masses to the PBL. The aged stratospheric masses are accumulated in the PBL, accelerating the SO2 transformation to SO42-. Implications for the tropospheric O3 budget and the CO2 biogeochemical cycle are discussed.

A global three-dimensional model of the stratospheric sulfuric acid layer

NASA Technical Reports Server (NTRS)

Golombek, Amram; Prinn, Ronald G.

1993-01-01

A 3D model which encompasses SO2 production from OCS, followed by its oxidation to gaseous H2SO4, the condensation-evaporation equilibrium of gaseous and particulate H2SO4, and finally particle condensation and rainout, is presently used to study processes maintaining the nonvolcanically-perturbed stratosphere's sulfuric acid layer. A comparison of the results thus obtained with remotely sensed stratospheric aerosol extinction data shows the model to simulate the general behavior of stratospheric aerosol extinction.

Optical constants of ammonium sulfate in the infrared. [stratospheric aerosol refractive and absorption indices

NASA Technical Reports Server (NTRS)

Downing, H. D.; Pinkley, L. W.; Sethna, P. P.; Williams, D.

1977-01-01

The infrared spectral reflectance at near normal incidence has been measured for 3.2 M, 2.4 M, and 1.6 M solutions of ammonium sulfate, an aerosol abundant in the stratosphere and also present in the troposphere. Kramers-Kronig analysis was used to determine values of the refractive and absorption indices from the measured spectral reflectance. A synthetic spectrum of crystalline ammonium sulfate was obtained by extrapolation of the absorption index obtained for the solution to the absorber number densities of the NH4 and SO4 ions characteristic of the crystal.

The ASSET intercomparison of stratosphere and lower mesosphere humidity analyses

NASA Astrophysics Data System (ADS)

Thornton, H. E.; Jackson, D. R.; Bekki, S.; Bormann, N.; Errera, Q.; Geer, A. J.; Lahoz, W. A.; Rharmili, S.

2008-07-01

This paper presents results from the first detailed intercomparison of stratosphere-lower mesosphere water vapour analyses; it builds on earlier results from the "Assimilation of ENVISAT Data" (ASSET) project. With the availability of high resolution, good quality Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) water vapour profiles, the ability of four different atmospheric models to assimilate these data is tested. MIPAS data have been assimilated over September 2003 into the models of the European Centre for Medium Range Weather Forecasts (ECMWF), the Belgian Institute for Space and Aeronomy (BIRA-IASB), the French Service d'Aéronomie (SA-IPSL) and the UK Met Office. The resultant middle atmosphere humidity analyses are compared against independent satellite data from the Halogen Occultation Experiment (HALOE), the Polar Ozone and Aerosol Measurement (POAM III) and the Stratospheric Aerosol and Gas Experiment (SAGE II). The MIPAS water vapour profiles are generally well assimilated in the ECMWF, BIRA-IASB and SA systems, producing stratosphere-mesosphere water vapour fields where the main features compare favourably with the independent observations. However, the models are less capable of assimilating the MIPAS data where water vapour values are locally extreme or in regions of strong humidity gradients, such as the Southern Hemisphere lower stratosphere polar vortex. Differences in the analyses can be attributed to the choice of humidity control variable, how the background error covariance matrix is generated, the model resolution and its complexity, the degree of quality control of the observations and the use of observations near the model boundaries. Due to the poor performance of the Met Office analyses the results are not included in the intercomparison, but are discussed separately. The Met Office results highlight the pitfalls in humidity assimilation, and provide lessons that should be learnt by developers of stratospheric humidity

Tracer transport in the tropical lower stratosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trepte, C.R.

1993-12-31

Distributions of aerosol extinction ratio ({beta}{sub r}) and ozone, derived from the Stratospheric Aerosol and Gas Experiment (SAGE I/II) satellite experiments (1979-1981 and 1984-1992), are used in conjunction with conventional meteorological analyses to deduce patterns of stratospheric tracer transport. Following volcanic eruptions at low latitudes, the aerosol observations suggest that two transport regimes exist in the tropical lower stratosphere. Aerosols disperse rapidly poleward and downward within a layer several kilometers above the tropopause. More pronounced transport is biased toward the winter hemisphere. At higher altitudes, however, volcanic aerosols tend to remain over the equator in a reservoir bounded by strongmore » meridional gradients near 20{degrees}N and S. Over the equator, enhanced lofting of aerosols occurs during QBO easterly shear, while subsidence relative to the mean meridional flow takes place during QBO westerly shear. While particle growth and evaporation effects are important, many interesting features of the aerosol distribution can only be explained by air motions. It is also shown that QBO induced ozone anomalies over the equator are also consistent with QBO aerosol variations. In the upper transport regime, the subtropical gradients of {beta}{sub r} coincide with the location of a meridional gradient in potential vorticity. Since isentropic transport is inhibited across potential vorticity gradients, the tropics are temporarily isolated from eddy mixing taking place in the winter extratropics. Zonal mean distributions of ozone; however, do not have similar meridional gradients in the subtropics. Detrainment of aerosol from the equatorial reservoir depends upon the phase of the QBO and the strength of winter eddy disturbances in the subtropics. Anticyclonic circulation systems form occasionally in the subtropics and can shear-off enhanced {beta}{sub r} air from the periphery of the aerosol reservoir.« less

Global volcanic aerosol properties derived from emissions, 1990-2014, using CESM1(WACCM): VOLCANIC AEROSOLS DERIVED FROM EMISSIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mills, Michael J.; Schmidt, Anja; Easter, Richard

Accurate representation of global stratospheric aerosol properties from volcanic and non-volcanic sulfur emissions is key to understanding the cooling effects and ozone-loss enhancements of recent volcanic activity. Attribution of climate and ozone variability to volcanic activity is of particular interest in relation to the post-2000 slowing in the apparent rate of global average temperature increases, and variable recovery of the Antarctic ozone hole. We have developed a climatology of global aerosol properties from 1990 to 2014 calculated based on volcanic and non-volcanic emissions of sulfur sources. We have complied a database of volcanic SO2 emissions and plume altitudes for eruptionsmore » between 1990 and 2014, and a new prognostic capability for simulating stratospheric sulfate aerosols in version 5 of the Whole Atmosphere Community Climate Model, a component of the Community Earth System Model. Our climatology shows remarkable agreement with ground-based lidar observations of stratospheric aerosol optical depth (SAOD), and with in situ measurements of aerosol surface area density (SAD). These properties are key parameters in calculating the radiative and chemical effects of stratospheric aerosols. Our SAOD climatology represents a significant improvement over satellite-based analyses, which ignore aerosol extinction below 15 km, a region that can contain the vast majority of stratospheric aerosol extinction at mid- and high-latitudes. Our SAD climatology significantly improves on that provided for the Chemistry-Climate Model Initiative, which misses 60% of the SAD measured in situ. Our climatology of aerosol properties is publicly available on the Earth System Grid.« less

Comparative measurements of stratospheric particulate content by aircraft and ground-based lidar. [aerosol sampling and scattering data analysis

NASA Technical Reports Server (NTRS)

Viezee, W.; Russell, P. B.; Hake, R. D., Jr.

1974-01-01

The matching method of lidar data analysis is explained, and the results from two flights studying the stratospheric aerosol using lidar techniques are summarized and interpreted. Support is lent to the matching method of lidar data analysis by the results, but it is not yet apparent that the analysis technique leads to acceptable results on all nights in all seasons.

The ASSET intercomparison of stratosphere and lower mesosphere humidity analyses

NASA Astrophysics Data System (ADS)

Thornton, H. E.; Jackson, D. R.; Bekki, S.; Bormann, N.; Errera, Q.; Geer, A. J.; Lahoz, W. A.; Rharmili, S.

2009-02-01

This paper presents results from the first detailed intercomparison of stratosphere-lower mesosphere water vapour analyses; it builds on earlier results from the EU funded framework V "Assimilation of ENVISAT Data" (ASSET) project. Stratospheric water vapour plays an important role in many key atmospheric processes and therefore an improved understanding of its daily variability is desirable. With the availability of high resolution, good quality Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) water vapour profiles, the ability of four different atmospheric models to assimilate these data is tested. MIPAS data have been assimilated over September 2003 into the models of the European Centre for Medium Range Weather Forecasts (ECMWF), the Belgian Institute for Space and Aeronomy (BIRA-IASB), the French Service d'Aéronomie (SA-IPSL) and the UK Met Office. The resultant middle atmosphere humidity analyses are compared against independent satellite data from the Halogen Occultation Experiment (HALOE), the Polar Ozone and Aerosol Measurement (POAM III) and the Stratospheric Aerosol and Gas Experiment (SAGE II). The MIPAS water vapour profiles are generally well assimilated in the ECMWF, BIRA-IASB and SA systems, producing stratosphere-mesosphere water vapour fields where the main features compare favourably with the independent observations. However, the models are less capable of assimilating the MIPAS data where water vapour values are locally extreme or in regions of strong humidity gradients, such as the southern hemisphere lower stratosphere polar vortex. Differences in the analyses can be attributed to the choice of humidity control variable, how the background error covariance matrix is generated, the model resolution and its complexity, the degree of quality control of the observations and the use of observations near the model boundaries. Due to the poor performance of the Met Office analyses the results are not included in the intercomparison

Physical chemistry of the H2SO4/HNO3/H2O system - Implications for polar stratospheric clouds

NASA Technical Reports Server (NTRS)

Molina, M. J.; Zhang, R.; Wooldridge, P. J.; Mcmahon, J. R.; Kim, J. E.; Chang, H. Y.; Beyer, K. D.

1993-01-01

Polar stratospheric clouds (PSCs) play a key role in stratospheric ozone depletion. Surface-catalyzed reactions on PSC particles generate chlorine compounds that photolyze readily to yield chlorine radicals, which in turn destroy ozone very efficiently. The most prevalent PSCs form at temperatures several degrees above the ice frost point and are believed to consist of HNO3 hydrates; however, their formation mechanism is unclear. Results of laboratory experiments are presented which indicate that the background stratospheric H2SO4/H2O aerosols provide an essential link in this mechanism: These liquid aerosols absorb significant amounts of HNO3 vapor, leading most likely to the crystallization of nitric acid trihydrate (NAT). The frozen particles then grow to form PSCs by condensation of additional amounts of HNO3 and H2O vapor. Furthermore, reaction probability measurements reveal that the chlorine radical precursors are formed readily at polar stratospheric temperatures not just on NAT and ice crystals, but also on liquid H2SO4 solutions and on solid H2SO4 hydrates. These results imply that the chlorine activation efficiency of the aerosol particles increases rapidly as the temperature approaches the ice frost point regardless of the phase or composition of the particles.

Earth Science With the Stratospheric Aerosol and Gas Experiment III (SAGE III) on the International Space Station

NASA Technical Reports Server (NTRS)

Zawodny, Joe; Vernier, Jean-Paul; Thomason, Larry; Roell, Marilee; Pitts, Mike; Moore, Randy; Hill, Charles; Flittner, David; Damadeo, Rob; Cisewski, Mike

2015-01-01

The Stratospheric Aerosol and Gas Experiment (SAGE) III is the fourth generation of solar occultation instruments operated by NASA, the first coming under a different acronym, to investigate the Earth's upper atmosphere. Three flight-ready SAGE III instruments were built by Ball Aerospace in the late 1990s, with one launched aboard the former Russian Aviation and Space Agency (now known as Roskosmos) Meteor-3M platform on 10 December 2001 (continuing until the platform lost power in 2006). Another of the original instruments was manifested for the ISS in the 2004 time frame, but was delayed because of budgetary considerations. Fortunately, that SAGE III/ISS mission was restarted in 2009 with a major focus upon filling an anticipated gap in ozone and aerosol observation in the second half of this decade. Here we discuss the mission architecture, its implementation, and data that will be produced by SAGE III/ISS, including their expected accuracy and coverage. The 52-degree inclined orbit of the ISS is well-suited for solar occultation and provides near-global observations on a monthly basis with excellent coverage of low and mid-latitudes. This is similar to that of the SAGE II mission (1985-2005), whose data set has served the international atmospheric science community as a standard for stratospheric ozone and aerosol measurements. The nominal science products include vertical profiles of trace gases, such as ozone, nitrogen dioxide and water vapor, along with multi-wavelength aerosol extinction. Though in the visible portion of the spectrum the brightness of the Sun is one million times that of the full Moon, the SAGE III instrument is designed to cover this large dynamic range and also perform lunar occultations on a routine basis to augment the solar products. The standard lunar products were demonstrated during the SAGE III/M3M mission and include ozone, nitrogen dioxide & nitrogen trioxide. The operational flexibility of the SAGE III spectrometer accomplishes

21 Layer troposphere-stratosphere climate model

NASA Technical Reports Server (NTRS)

Rind, D.; Suozzo, R.; Lacis, A.; Russell, G.; Hansen, J.

1984-01-01

The global climate model is extended through the stratosphere by increasing the vertical resolution and raising the rigid model top to the 0.01 mb (75 km) level. The inclusion of a realistic stratosphere is necessary for the investigation of the climate effects of stratospheric perturbations, such as changes of ozone, aerosols or solar ultraviolet irradiance, as well as for studying the effect on the stratosphere of tropospheric climate changes. The observed temperature and wind patterns throughout the troposphere and stratosphere are simulated. In addition to the excess planetary wave amplitude in the upper stratosphere, other model deficiences include the Northern Hemisphere lower stratospheric temperatures being 5 to 10 C too cold in winter at high latitudes and the temperature at 50 to 60 km altitude near the equator are too cold. Methods of correcting these deficiencies are discussed.

Laboratory and field studies of stratospheric aerosols: Phase changes under high supersaturation

NASA Technical Reports Server (NTRS)

Hallet, John

1991-01-01

It is well known that water in the form of isolated small droplets supercool as much as 40 C below their equilibrium melting point. Solutions similarly supercool (with respect to water) and supersaturate (with respect of the solute). Experiments are described in which bulk solutions typical of atmospheric aerosols (nitric acid, sulfuric acid, and hydrates; ammonium sulfate; ammonium bisulfate; sodium chloride) are supercooled and/or supersaturated and nucleated to initiate crystal growth. Supersaturation of 300 percent is readily attainable, with linear growth of crystals increasing roughly as (supercooling/supersaturation)sup 2. The implication of the experiments is that the situation of metastability in polar stratosphere clouds is very likely, with nucleation only occuring under a high degree of supercooling or supersaturation.

Stratospheric ozone variations in the equatorial region as seen in Stratiospheric Aerosol and Gas Experiment data

NASA Technical Reports Server (NTRS)

Shiotani, Masato; Hasebe, Fumio

1994-01-01

An analysis is made of equatorial ozone variations for 5 years, 1984-1989, using the ozone profile data derived from the Stratospheric Aerosol and Gas Experiment II (SAGE II) instrument. Attention is focused on the annual cycle and also on interannual variability, particularly the quasi-biennial oscillation (QBO) and El Nino-Southern Oscillation (ENSO) variations in the lower stratosphere, where the largest contribution to total column ozone takes place. The annual variation in zonal mean total ozone around the equator is composed of symmetric and asymmetric modes with respect to the equator, with maximum contributions being around 19 km for the symmetric mode and around 25 km for the asymmetric mode. The persistent zonal wavenumber 1 structure observed by the total ozone mapping spectrometer over the equator is almost missing in the SAGE-derived column amounts integrated in the stratosphere, suggesting a significant contribution from tropospheric ozone. Interannual variations in the equatorial ozone are dominated by the QBO above 20 km and the ENSO-related variation below 20 km. The ozone QBO is characterized by zonally uniform phase changes in association with the zonal wind QBO in the equatorial lower stratosphere. The ENSO-related ozone variation consists of both the east-west vacillation and the zonally uniform phase variation. During the El Nino event, the east-west contrast with positive (negative) deviations in the eastern (western) hemisphere is conspicuous, while the decreasing tendency of the zonal mean values is maximum at the same time.

Latitudinal distribution of black carbon soot in the upper troposphere and lower stratosphere

NASA Technical Reports Server (NTRS)

Blake, David F.; Kato, Katharine

1995-01-01

Black carbon soot from the upper troposphere and lower stratosphere has been systematically collected at latitudes from 90 deg N to 45 deg S. The measured latitudinal distribution of this soot at 10 to 11 km altitude is found to covary with commercial air traffic fuel use, suggesting that aircraft fuel combustion at altitude is the principal source. In addition, at latitudes where the commercial air traffic is high, measured black carbon soot values are high even at 20 km altitude, suggesting that aircraft-generated soot injected just above the tropopause may be transported to higher altitudes. During the volcanically influenced period in which these samples were collected, the number abundances, total mass, and calculated total surface area of black carbon soot are 2-3 orders of magnitude lower than similar measures of sulfuric acid aerosol. During volcanically quiescent periods, the calculated total surface area of black carbon soot aerosol is of the same order of magnitude as that of the background sulfuric acid aerosol. It appears from this comparison that black carbon soot is only capable of influencing lower stratosphere or upper troposphere chemistry during periods when the aerosol budget is not dominated by volcanic activity. It remains to determine the extent to which black carbon soot particles act as nuclei for sulfuric acid aerosol formation. However, mass balance calculations suggest that aircraft soot injected at altitude does not represent a significant source of condensation nuclei for sulfuric acid aerosols.

Aerosol microphysics simulations of the Mt.~Pinatubo eruption with the UM-UKCA composition-climate model

NASA Astrophysics Data System (ADS)

Dhomse, S. S.; Emmerson, K. M.; Mann, G. W.; Bellouin, N.; Carslaw, K. S.; Chipperfield, M. P.; Hommel, R.; Abraham, N. L.; Telford, P.; Braesicke, P.; Dalvi, M.; Johnson, C. E.; O'Connor, F.; Morgenstern, O.; Pyle, J. A.; Deshler, T.; Zawodny, J. M.; Thomason, L. W.

2014-10-01

) measurements from Laramie, Wyoming, USA (41° N). Overall, the model captures remarkably well the complex variations in particle concentration profiles across the different OPC size channels. However, for the 19 to 27 km injection height-range used here, both runs have a modest high bias in the lowermost stratosphere for the finest particles (radii less than 250 nm), and the decay timescale is longer in the model for these particles, with a much later return to background conditions. Also, whereas the 10 Tg run compared best to the satellite measurements, a significant low bias is apparent in the coarser size channels in the volcanically perturbed lower stratosphere. Overall, our results suggest that, with appropriate calibration, aerosol microphysics models are capable of capturing the observed variation in particle size distribution in the stratosphere across both volcanically perturbed and quiescent conditions. Furthermore, additional sensitivity simulations suggest that predictions with the models are robust to uncertainties in sub-grid particle formation and nucleation rates in the stratosphere.

Forcing of stratospheric chemistry and dynamics during the Dalton Minimum

NASA Astrophysics Data System (ADS)

Anet, J. G.; Muthers, S.; Rozanov, E.; Raible, C. C.; Peter, T.; Stenke, A.; Shapiro, A. I.; Beer, J.; Steinhilber, F.; Brönnimann, S.; Arfeuille, F.; Brugnara, Y.; Schmutz, W.

2013-06-01

The response of atmospheric chemistry and climate to volcanic eruptions and a decrease in solar activity during the Dalton Minimum is investigated with the fully coupled atmosphere-ocean-chemistry general circulation model SOCOL-MPIOM covering the time period 1780 to 1840 AD. We carried out several sensitivity ensemble experiments to separate the effects of (i) reduced solar ultra-violet (UV) irradiance, (ii) reduced solar visible and near infrared irradiance, (iii) enhanced galactic cosmic ray intensity as well as less intensive solar energetic proton events and auroral electron precipitation, and (iv) volcanic aerosols. The introduced changes of UV irradiance and volcanic aerosols significantly influence stratospheric climate in the early 19th century, whereas changes in the visible part of the spectrum and energetic particles have smaller effects. A reduction of UV irradiance by 15% causes global ozone decrease below the stratopause reaching 8% in the midlatitudes at 5 hPa and a significant stratospheric cooling of up to 2 °C in the midstratosphere and to 6 °C in the lower mesosphere. Changes in energetic particle precipitation lead only to minor changes in the yearly averaged temperature fields in the stratosphere. Volcanic aerosols heat the tropical lower stratosphere allowing more water vapor to enter the tropical stratosphere, which, via HOx reactions, decreases upper stratospheric and mesospheric ozone by roughly 4%. Conversely, heterogeneous chemistry on aerosols reduces stratospheric NOx leading to a 12% ozone increase in the tropics, whereas a decrease in ozone of up to 5% is found over Antarctica in boreal winter. The linear superposition of the different contributions is not equivalent to the response obtained in a simulation when all forcing factors are applied during the DM - this effect is especially well visible for NOx/NOy. Thus, this study highlights the non-linear behavior of the coupled chemistry-climate system. Finally, we conclude that

Ozone and the stratosphere

NASA Technical Reports Server (NTRS)

Shimazaki, Tatsuo

1987-01-01

It is shown that the stratospheric ozone is effective in absorbing almost all radiation below 300 nm at heights below 300 km. The distribution of global ozone in the troposphere and the lower stratosphere, and the latitudinal variations of the total ozone column over four seasons are considered. The theory of the ozone layer production is discussed together with catalytic reactions for ozone loss and the mechanisms of ozone transport. Special attention is given to the anthropogenic perturbations, such as SST exhaust gases and freon gas from aerosol cans and refrigerators, that may cause an extensive destruction of the stratospheric ozone layer and thus have a profound impact on the world climate and on life.

Features of tropospheric and stratospheric dust.

PubMed

Elterman, L; Wexler, R; Chang, D T

1969-05-01

A series of 119 profiles obtained over New Mexico comprise aerosol attenuation coefficients vs altitude to about 35 km. These profiles show the existence of several features. A surface convective dust layer extending up to about 5 km is seasonally dependent. Also, a turbidity maximum exists below the tropopause. The altitude of an aerosol maximum in the lower stratosphere is located just below that of the minimum temperature. The colder the minimum temperature, the greater is the aerosol content of the layer. This relationship suggests that the 20-km dust layer is due to convection in tropical air and advection to higher latitudes. Computed averages of optical thickness show that abatement of stratospheric dust from the Mt. Agung eruption became evident in April 1964. Results based on seventy-nine profiles characterizing volcanic dust abatement indicate that above 26 km, the aerosol scale height averages 3.75 km. Extrapolating with this scale height, tabulations are developed for uv, visible, and ir attenuation to 50 km. Optical mixing ratios are used to examine the aerosol concentrations at various altitudes, including a layer at 26 km having an optical thickness 10(-3) for 0.55-micro wavelength.

The Climate Response to Stratospheric Aerosol Geoengineering Can Be Tailored Using Multiple Injection Locations

DOE Office of Scientific and Technical Information (OSTI.GOV)

MacMartin, Douglas G.; Kravitz, Ben; Tilmes, Simone

The climate response to geoengineering with stratospheric aerosols has the potential to be designed to achieve some chosen objectives. By injecting different amounts of SO2 at multiple different latitudes, the spatial pattern of aerosol optical depth (AOD) can be partially controlled. We use simulations from the fully-coupled whole-atmosphere chemistry-climate model CESM1(WACCM), to demonstrate that three spatial degrees of freedom of AOD can be achieved by appropriately combining injection at different locations: an approximately spatially-uniform AOD distribution, the relative difference in AOD between Northern and Southern hemispheres, and the relative AOD in high versus low latitudes. For forcing levels that yieldmore » 1–2°C cooling, the AOD and surface temperature response are sufficiently linear in this model so that many climate effects can be predicted from single-latitude injection simulations. Optimized injection at multiple locations is predicted to improve compensation of CO2-forced climate change, relative to a case using only equatorial aerosol injection. The additional degrees of freedom can be used, for example, to balance interhemispheric temperature differences and the equator to pole temperature difference in addition to the global mean temperature; this is projected in this model to reduce the mean-square error in temperature compensation by 30%.« less

Ultra-Low Background Measurements Of Decayed Aerosol Filters

NASA Astrophysics Data System (ADS)

Miley, H.

2009-04-01

To experimentally evaluate the opportunity to apply ultra-low background measurement methods to samples collected, for instance, by the Comprehensive Test Ban Treaty International Monitoring System (IMS), aerosol samples collected on filter media were measured using HPGe spectrometers of varying low-background technology approaches. In this way, realistic estimates of the impact of low-background methodology can be assessed on the Minimum Detectable Activities obtained in systems such as the IMS. The current measurement requirement of stations in the IMS is 30 microBq per cubic meter of air for 140Ba, or about 106 fissions per daily sample. Importantly, this is for a fresh aerosol filter. Decay varying form 3 days to one week reduce the intrinsic background from radon daughters in the sample. Computational estimates of the improvement factor for these decayed filters for underground-based HPGe in clean shielding materials are orders of magnitude less, even when the decay of the isotopes of interest is included.

Glacier evolution in high-mountain Asia under stratospheric sulfate aerosol injection geoengineering

NASA Astrophysics Data System (ADS)

Zhao, Liyun; Yang, Yi; Cheng, Wei; Ji, Duoying; Moore, John C.

2017-06-01

Geoengineering by stratospheric sulfate aerosol injection may help preserve mountain glaciers by reducing summer temperatures. We examine this hypothesis for the glaciers in high-mountain Asia using a glacier mass balance model driven by climate simulations from the Geoengineering Model Intercomparison Project (GeoMIP). The G3 and G4 schemes specify use of stratospheric sulfate aerosols to reduce the radiative forcing under the Representative Concentration Pathway (RCP) 4.5 scenario for the 50 years between 2020 and 2069, and for a further 20 years after termination of geoengineering. We estimate and compare glacier volume loss for every glacier in the region using a glacier model based on surface mass balance parameterization under climate projections from three Earth system models under G3, five models under G4, and six models under RCP4.5 and RCP8.5. The ensemble projections suggest that glacier shrinkage over the period 2010-2069 is equivalent to sea-level rise of 9.0 ± 1.6 mm (G3), 9.8 ± 4.3 mm (G4), 15.5 ± 2.3 mm (RCP4.5), and 18.5 ± 1.7 mm (RCP8.5). Although G3 keeps the average temperature from increasing in the geoengineering period, G3 only slows glacier shrinkage by about 50 % relative to losses from RCP8.5. Approximately 72 % of glaciated area remains at 2069 under G3, as compared with about 30 % for RCP8.5. The widely reported reduction in mean precipitation expected for solar geoengineering is unlikely to be as important as the temperature-driven shift from solid to liquid precipitation for forcing Himalayan glacier change. The termination of geoengineering at 2069 under G3 leads to temperature rise of about 1.3 °C over the period 2070-2089 relative to the period 2050-2069 and corresponding increase in annual mean glacier volume loss rate from 0.17 to 1.1 % yr-1, which is higher than the 0.66 % yr-1 under RCP8.5 during 2070-2089.

Regional Simulations of Stratospheric Lofting of Smoke Plumes

NASA Astrophysics Data System (ADS)

Stenchikov, G. L.; Fromm, M.; Robock, A.

2006-12-01

The lifetime and spatial distribution of sooty aerosols from multiple fires that would cause major climate impact were debated in studies of climatic and environmental consequences of a nuclear war in the 1980s. The Kuwait oil fires in 1991 did not show a cumulative effect of multiple smoke plumes on large-scale circulation systems and smoke was mainly dispersed in the middle troposphere. However, recent observations show that smoke from large forest fires can be directly injected into the lower stratosphere by strong pyro-convective storms. Smoke plumes in the upper troposphere can be partially mixed into the lower stratosphere because of the same heating and lofting effect that was simulated in large-scale nuclear winter simulations with interactive aerosols. However nuclear winter simulations were conducted using climate models with grid spacing of more than 100 km, which do not account for the fine-scale dynamic processes. Therefore in this study we conduct fine-scale regional simulations of the aerosol plume using the Regional Atmospheric Modeling System (RAMS) mesoscale model which was modified to account for radiatively interactive tracers. To resolve fine-scale dynamic processes we use horizontal grid spacing of 25 km and 60 vertical layers, and initiate simulations with the NCEP reanalysis fields. We find that dense aerosol layers could be lofted from 1 to a few km per day, but this critically depends on the optical depth of aerosol layer, single scatter albedo, and how fast the plume is being diluted. Kuwaiti plumes from different small-area fires reached only 5-6 km altitude and were probably diffused and diluted in the lower and middle troposphere. A plume of 100 km spatial scale initially developed in the upper troposphere tends to penetrate into the stratosphere. Short-term cloud resolving simulations of such a plume show that aerosol heating intensifies small-scale motions that tend to mix smoke polluted air into the lower stratosphere. Regional

Physico-chemical characterization of Mediterranean background aerosol at the Capogranitola observatory (Sicily)

NASA Astrophysics Data System (ADS)

Rinaldi, Matteo; Gilardoni, Stefania; Paglione, Marco; Sandrini, Silvia; Decesari, Stefano; Zanca, Nicola; Marinoni, Angela; Cristofanelli, Paolo; Bonasoni, Paolo; Ielpo, Piera; Fossum, Kirsten; Gobbi, Gian Paolo; Facchini, Maria Cristina

2017-04-01

The Mediterranean basin is characterized by elevated aerosol amounts and co-existence of different aerosol types, both natural and anthropogenic, while it is one of the most climatically sensitive areas. Therefore, it offers ideal conditions for studying aerosol processes and aerosol-climate interactions. An intensive aerosol physico-chemical characterization campaign was held at the Environmental-Climatic Observatory at Capo Granitola (Sicily; 37.5753° N, 12.6595° E) during April 2016, under the framework of the project Air-Sea Lab. The Observatory is located at the coast-line, facing the Strait of Sicily, and is part of the national I-AMICA network (http://www.i-amica.it/i-amica/?lang=en). Sub-micrometer aerosol chemical composition was measured by high resolution time of flight aerosol mass spectrometer (HR-ToF-AMS), for the first time at Capogranitola. Sea-salt concentration was estimated from AMS measurements following Ovadnevaite et al. (2012). For a complete mass closure of the submicron aerosol, black carbon (BC) concentration was derived from multiangle absorption photometer (MAAP) measurements. Positive matrix factorization was deployed to investigate organic aerosol (OA) sources at the site. Aerosol chemical composition confirms that Capogranitola is a representative background site, with generally low contribution of BC and nitrate and highly oxidized OA. In particular, aerosol sampled in the marine sector (130-310°) is less affected by local sources and it is likely representative of the central Mediterranean background. Aerosol in background conditions is dominated by sulfate and OA (37% and 31%), followed by ammonium (12%), sea-salt (10%), BC (6%) and nitrate (3%). The average reconstructed sub-micrometer aerosol mass in background conditions is 3.7±2.3 μg m-3. OA source apportionment shows a minor contribution from primary sources, with hydrocarbon-like OA (HOA), from fossil fuel combustion, contributing for 3% and biomass burning OA (BBOA) for

A Chronology of Annual-Mean Effective Radii of Stratospheric Aerosols from Volcanic Eruptions During the Twentieth Century as Derived From Ground-based Spectral Extinction Measurements

NASA Technical Reports Server (NTRS)

Strothers, Richard B.; Hansen, James E. (Technical Monitor)

2001-01-01

Stratospheric extinction can be derived from ground-based spectral photometric observations of the Sun and other stars (as well as from satellite and aircraft measurements, available since 1979), and is found to increase after large volcanic eruptions. This increased extinction shows a characteristic wavelength dependence that gives information about the chemical composition and the effective (or area weighted mean) radius of the particles responsible for it. Known to be tiny aerosols constituted of sulfuric acid in a water solution, the stratospheric particles at midlatitudes exhibit a remarkable uniformity of their column-averaged effective radii r(sub eff) in the first few months after the eruption. Considering the seven largest eruptions of the twentieth century, r(sub eff) at this phase of peak aerosol abundance is approx. 0.3 micrometers in all cases. A year later, r(sub eff) either has remained about the same size (almost certainly in the case of the Katmai eruption of 1912) or has increased to approx. 0.5 micrometers (definitely so for the Pinatubo eruption of 1991). The reasons for this divergence in aerosol growth are unknown.

Stratospheric ozone variations in the equatorial region as seen in Stratiospheric Aerosol and Gas Experiment data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shiotani, M.; Hasebe, F.

1994-07-01

An analysis is made of equatorial ozone variations for 5 years, 1984-1989, using the ozone profile data derived from the Stratospheric Aerosol and Gas Experiment II (SAGE II) instrument. Attention is focused on the annual cycle and also on interannual variability, particularly the quasi-biennial oscillation (QBO) and El Nino-Southern Oscillation (ENSO) variations in the lower stratosphere, where the largest contribution to total column ozone takes place. The annual variation in zonal mean total ozone around the equator is composed of symmetric and asymmetric modes with respect to the equator, with maximum contributions being around 19 km for the symmetric modemore » and around 25 km for the asymmetric mode. The persistent zonal wavenumber 1 structure observed by the total ozone mapping spectrometer over the equator is almost missing in the SAGE-derived column amounts integrated in the stratosphere, suggesting a significant contribution from tropospheric ozone. Interannual variations in the equatorial ozone are dominated by the QBO above 20 km and the ENSO-related variation below 20 km. The ozone QBO is characterized by zonally uniform phase changes in association with the zonal wind QBO in the equatorial lower stratosphere. The ENSO-related ozone variation consists of both the east-west vacillation and the zonally uniform phase variation. During the El Nino event, the east-west contrast with positive (negative) deviations in the eastern (western) hemisphere is conspicuous, while the decreasing tendency of the zonal mean values is maximum at the same time.« less

Geochemistry of regional background aerosols in the Western Mediterranean

NASA Astrophysics Data System (ADS)

Pey, J.; Pérez, N.; Castillo, S.; Viana, M.; Moreno, T.; Pandolfi, M.; López-Sebastián, J. M.; Alastuey, A.; Querol, X.

2009-11-01

The chemical composition of regional background aerosols, and the time variability and sources in the Western Mediterranean are interpreted in this study. To this end 2002-2007 PM speciation data from an European Supersite for Atmospheric Aerosol Research (Montseny, MSY, located 40 km NNE of Barcelona in NE Spain) were evaluated, with these data being considered representative of regional background aerosols in the Western Mediterranean Basin. The mean PM 10, PM 2.5 and PM 1 levels at MSY during 2002-2007 were 16, 14 and 11 µg/m 3, respectively. After compiling data on regional background PM speciation from Europe to compare our data, it is evidenced that the Western Mediterranean aerosol is characterised by higher concentrations of crustal material but lower levels of OM + EC and ammonium nitrate than at central European sites. Relatively high PM 2.5 concentrations due to the transport of anthropogenic aerosols (mostly carbonaceous and sulphate) from populated coastal areas were recorded, especially during winter anticyclonic episodes and summer midday PM highs (the latter associated with the transport of the breeze and the expansion of the mixing layer). Source apportionment analyses indicated that the major contributors to PM 2.5 and PM 10 were secondary sulphate, secondary nitrate and crustal material, whereas the higher load of the anthropogenic component in PM 2.5 reflects the influence of regional (traffic and industrial) emissions. Levels of mineral, sulphate, sea spray and carbonaceous aerosols were higher in summer, whereas nitrate levels and Cl/Na were higher in winter. A considerably high OC/EC ratio (14 in summer, 10 in winter) was detected, which could be due to a combination of high biogenic emissions of secondary organic aerosol, SOA precursors, ozone levels and insolation, and intensive recirculation of aged air masses. Compared with more locally derived crustal geological dusts, African dust intrusions introduce relatively quartz-poor but clay

Quantifying stratospheric ozone trends: Complications due to stratospheric cooling

NASA Astrophysics Data System (ADS)

McLinden, C. A.; Fioletov, V.

2011-02-01

Recent studies suggest that ozone turnaround (the second stage of ozone recovery) is near. Determining precisely when this occurs, however, will be complicated by greenhouse gas-induced stratospheric cooling as ozone trends derived from profile data in different units and/or vertical co-ordinates will not agree. Stratospheric cooling leads to simultaneous trends in air density and layer thicknesses, confounding the interpretation of ozone trends. A simple model suggests that instruments measuring ozone in different units may differ as to the onset of turnaround by a decade, with some indicting a continued decline while others an increase. This concept was illustrated by examining the long-term (1979-2005) ozone trends in the SAGE (Stratospheric Aerosol and Gas Experiment) and SBUV (Solar Backscatter Ultraviolet) time series. Trends from SAGE, which measures number density as a function of altitude, and SBUV, which measures partial column as a function of pressure, are known to differ by 4-6%/decade in the upper stratosphere. It is shown that this long-standing difference can be reconciled to within 2%/decade when the trend in temperature is properly accounted for.

The Hemisphere-scale Stratospheric Impact of the Chisholm (Alberta) PyroCumulonimbus Eruption

NASA Astrophysics Data System (ADS)

Fromm, M.; Barnes, J.; Blum, U.; Diner, D.; Fricke, K. H.; Gerding, M.; Giehl, H.; Kahn, R.; Lablanc, T.; Massie, S.; Stuart, M.; O'Neill, M.; Ritter, C.; Servranckx, R.; Shettle, E.; Torres, O.; Trickl, T.

2006-12-01

Extreme pyrocumulonimbus (pyroCb) blowups that polluted the lower stratosphere with smoke and other biomass burning emissions have been documented in the literature to have occurred on at least five separate occasions. However our understanding of the frequency and scale of these events is still far from complete. One pyroCb case study in the literature, the Chisholm Fire in Alberta in May 2001, was restricted to the convective phase and its immediate aftermath (Fromm and Servranckx, Geophys. Res. Lett., 2003). Here we describe the stratospheric impact of the Chisholm pyroCb. We present nadir and imaging satellite views of the post-pyroCb plume by the Multi-angle Imaging Spectroradiometer (MISR), Moderate Resolution Imaging Spectroradiomenter (MODIS), Total Ozone Mapping Spectrometer (TOMS), and a broad array of profile measurements, space- and ground-based. These include the Polar Ozone and Aerosol Measurement (POAM) III, Stratospheric Aerosol and Gas Experiment (SAGE) II, Halogen Occultation Experiment (HALOE), and seven ground-based lidars. We report that the Chisholm pyroCb was the singular cause of a hemispheric stratospheric aerosol increase in northern spring/summer of 2001. The smoke plume on the day after the pyro-eruption reached heights of 15 km, 4 km above the tropopause, was optically opaque at the tropopause, and caused unprecedented, large values of TOMS aerosol index. This plume eventually resulted in a doubling of zonal-average aerosol optical depth in the stratospheric middleworld and overworld. The meridional spread of the plume is confirmed from the tropics (20°N) to the high Arctic (79°N) within the first month. The stratospheric Chisholm smoke became a hemispheric phenomenon in midlatitudes and persisted for at least three months there and in the northern tropics. This work contains the first reported stratospheric smoke layers measured by lidar at Ny Älesund, Kühlungsborn, Garmisch Partenkirchen, Boulder, and Mauna Loa, and the second

Stratospheric Smoke With Unprecedentedly High Backscatter Observed by Lidars Above Southern France

NASA Astrophysics Data System (ADS)

Khaykin, S. M.; Godin-Beekmann, S.; Hauchecorne, A.; Pelon, J.; Ravetta, F.; Keckhut, P.

2018-02-01

Extreme pyroconvection events triggered by wildfires in northwest Canada and United States during August 2017 resulted in vast injection of combustion products into the stratosphere. The plumes of stratospheric smoke were observed by lidars at Observatoire de Haute-Provence (OHP) for many weeks that followed the fires as distinct aerosol layers with backscatter reaching unprecedentedly high values for a nonvolcanic aerosol layer. We use spaceborne CALIOP lidar to track the spatiotemporal evolution of the smoke plumes before their detection at OHP. A remarkable agreement between ground- and spaced-based lidars sampling the same smoke plume on a particular date allowed us to extrapolate the OHP observations to a regional scale, where CALIOP reported extreme aerosol optical depth values as high as 0.21. On a monthly time scale, the lidar observations indicate that boreal summer 2017 forest fires had a hemisphere-scale impact on stratospheric aerosol load, similar to that of moderate volcanic eruptions.

Airborne lidar measurements of El Chichon stratospheric aerosols, October 1982 to November 1982

NASA Technical Reports Server (NTRS)

Mccormick, M. P.; Osborn, M. T.

1985-01-01

A coordinated flight mission to determine the spatial distribution and aerosol characteristics of the El Chichon produced stratospheric aerosol was flown in October to November 1982. The mission covered 46 deg N to 46 deg S and included rendezvous between balloon-, airplane-, and satellite-borne sensors. The lidar data from the flight mission are presented. Representative profiles of lidar backscatter ratio, plots of the integrated backscattering function versus latitude, and contours of backscatter mixing ratio versus altitude and latitude are given. In addition, tables containing numerical values of the backscatter ratio and backscattering functions versus altitude are supplied for each profile. The bulk of the material produced by the El Chichon eruptions of late March 10 to early April 1982 resided between latitudes from 5 to 7 deg S to 35 to 37 deg N and was concentrated above 21 km in a layer that peaked at 23 to 25 km. In this latitude region, peak scattering ratios at a wavelength of 0.6943 micron were approximately 24. The results of this mission are presented in a ready-to-use format for atmospheric and climatic studies.

Global volcanic aerosol properties derived from emissions, 1990-2014, using CESM1(WACCM)

NASA Astrophysics Data System (ADS)

Mills, Michael J.; Schmidt, Anja; Easter, Richard; Solomon, Susan; Kinnison, Douglas E.; Ghan, Steven J.; Neely, Ryan R.; Marsh, Daniel R.; Conley, Andrew; Bardeen, Charles G.; Gettelman, Andrew

2016-03-01

Accurate representation of global stratospheric aerosols from volcanic and nonvolcanic sulfur emissions is key to understanding the cooling effects and ozone losses that may be linked to volcanic activity. Attribution of climate variability to volcanic activity is of particular interest in relation to the post-2000 slowing in the rate of global average temperature increases. We have compiled a database of volcanic SO2 emissions and plume altitudes for eruptions from 1990 to 2014 and developed a new prognostic capability for simulating stratospheric sulfate aerosols in the Community Earth System Model. We used these combined with other nonvolcanic emissions of sulfur sources to reconstruct global aerosol properties from 1990 to 2014. Our calculations show remarkable agreement with ground-based lidar observations of stratospheric aerosol optical depth (SAOD) and with in situ measurements of stratospheric aerosol surface area density (SAD). These properties are key parameters in calculating the radiative and chemical effects of stratospheric aerosols. Our SAOD calculations represent a clear improvement over available satellite-based analyses, which generally ignore aerosol extinction below 15 km, a region that can contain the vast majority of stratospheric aerosol extinction at middle and high latitudes. Our SAD calculations greatly improve on that provided for the Chemistry-Climate Model Initiative, which misses about 60% of the SAD measured in situ on average during both volcanically active and volcanically quiescent periods.

Apparatus having reduced background for measuring radiation activity in aerosol particles

DOEpatents

Rodgers, John C.; McFarland, Andrew R.; Oritz, Carlos A.; Marlow, William H.

1992-01-01

Apparatus having reduced background for measuring radiation activity in aerosol particles. A continuous air monitoring sampler is described for use in detecting the presence of alpha-emitting aerosol particles. An inlet fractionating screen has been demonstrated to remove about 95% of freshly formed radon progeny from the aerosol sample, and approximately 33% of partially aged progeny. Addition of an electrical condenser and a modified dichotomous virtual impactor are expected to produce considerable improvement in these numbers, the goal being to enrich the transuranic (TRU) fraction of the aerosols. This offers the possibility of improving the signal-to-noise ratio for the detected alpha-particle energy spectrum in the region of interest for detecting TRU materials associated with aerosols, thereby enhancing the performance of background-compensation algorithms for improving the quality of alarm signals intended to warn personnel of potentially harmful quantities of TRU materials in the ambient air.

Optimal Aerosol Parameterization for Remote Sensing Retrievals

NASA Technical Reports Server (NTRS)

Newchurch, Michael J.

2004-01-01

We have developed a new algorithm for the retrieval of aerosol and gases from SAGE It1 solar transmission measurements. This algorithm improves upon the NASA operational algorithm in several key aspects, including solving the problem non-linearly and incorporating a new methodology for separating the contribution of aerosols and gases. In order to extract aerosol information we have built a huge database of aerosol models for both stratospheric and tropospheric aerosols, and polar stratospheric cloud particles. This set of models allows us to calculate a vast range of possible extinction spectra for aerosols. and from these, derive a set of eigenvectors which then provide the basis set used in our inversion algorithm. Our aerosol algorithm and retrievals are described in several articles (listed in References Section) published under this grant. In particular they allow us to analyze the spectral properties of aerosols and PSCs and ultimately derive their microphysical properties. We have found some considerable differences between our spectra and the ones derived from the SAGE III operational algorithm. These are interesting as they provide an independent check on the validity of published aerosol data and, in particular, on their associated uncertainties. In order to understand these differences, we are assembling independent aerosol data from other sources with which to make comparisons. We have carried out extensive comparisons of our ozone retrievals with both SAGE III and independent lidar, ozonesonde, and satellite measurements (Polyakov et al., 2004). These show very good agreement throughout the stratosphere and help to quantify differences which can be attributed to natural variation in ozone versus that produced by algorithmic differences. In the mid - upper stratosphere, agreement with independent data was generally within 5 - 20%. but in the lower stratosphere the differences were considerably larger. We believe that a large proportion of this

Atmospheric aerosols: Their Optical Properties and Effects (supplement)

NASA Technical Reports Server (NTRS)

1976-01-01

A digest of technical papers is presented. Topics include aerosol size distribution from spectral attenuation with scattering measurements; comparison of extinction and backscattering coefficients for measured and analytic stratospheric aerosol size distributions; using hybrid methods to solve problems in radiative transfer and in multiple scattering; blue moon phenomena; absorption refractive index of aerosols in the Denver pollution cloud; a two dimensional stratospheric model of the dispersion of aerosols from the Fuego volcanic eruption; the variation of the aerosol volume to light scattering coefficient; spectrophone in situ measurements of the absorption of visible light by aerosols; a reassessment of the Krakatoa volcanic turbidity, and multiple scattering in the sky radiance.

Global volcanic aerosol properties derived from emissions, 1990-2015, using CESM1(WACCM)

NASA Astrophysics Data System (ADS)

Mills, Michael; Schmidt, Anja; Easter, Richard; Solomon, Susan; Kinnison, Douglas; Ghan, Steven; Neely, Ryan; Marsh, Daniel; Conley, Andrew; Bardeen, Charles; Gettelman, Andrew

2016-04-01

Accurate representation of global stratospheric aerosols from volcanic and non-volcanic sulfur emissions is key to understanding the cooling effects and ozone-losses that may be linked to volcanic activity. Attribution of climate variability to volcanic activity is of particular interest in relation to the post-2000 slowing in the rate of global average temperature increases. We have compiled a database of volcanic SO2 emissions and plume altitudes for eruptions from 1990 to 2015, and developed a new prognostic capability for simulating stratospheric sulfate aerosols in the Community Earth System Model (CESM). We combined these with other non-volcanic emissions of sulfur sources to reconstruct global aerosol properties from 1990 to 2015. Our calculations show remarkable agreement with ground-based lidar observations of stratospheric aerosol optical depth (SAOD), and with in situ measurements of stratospheric aerosol surface area density (SAD). These properties are key parameters in calculating the radiative and chemical effects of stratospheric aerosols. Our SAOD calculations represent a clear improvement over available satellite-based analyses, which generally ignore aerosol extinction below 15 km, a region that can contain the vast majority of stratospheric aerosol extinction at mid- and high-latitudes. Our SAD calculations greatly improve on that provided for the Chemistry-Climate Model Initiative, which misses about 60% of the SAD measured in situ on average during both volcanically active and volcanically quiescent periods. The stark differences in SAOD and SAD compared to other data sets will have significant effects on calculations of the radiative forcing of climate and global stratospheric chemistry over the period 2005-2015. In light of these results, the impact of volcanic aerosols in reducing the rate of global average temperature increases since the year 2000 should be revisited. We have made our calculated aerosol properties from January 1990 to

Forcing of stratospheric chemistry and dynamics during the Dalton Minimum

NASA Astrophysics Data System (ADS)

Anet, J. G.; Muthers, S.; Rozanov, E.; Raible, C. C.; Peter, T.; Stenke, A.; Shapiro, A. I.; Beer, J.; Steinhilber, F.; Brönnimann, S.; Arfeuille, F.; Brugnara, Y.; Schmutz, W.

2013-11-01

The response of atmospheric chemistry and dynamics to volcanic eruptions and to a decrease in solar activity during the Dalton Minimum is investigated with the fully coupled atmosphere-ocean chemistry general circulation model SOCOL-MPIOM (modeling tools for studies of SOlar Climate Ozone Links-Max Planck Institute Ocean Model) covering the time period 1780 to 1840 AD. We carried out several sensitivity ensemble experiments to separate the effects of (i) reduced solar ultra-violet (UV) irradiance, (ii) reduced solar visible and near infrared irradiance, (iii) enhanced galactic cosmic ray intensity as well as less intensive solar energetic proton events and auroral electron precipitation, and (iv) volcanic aerosols. The introduced changes of UV irradiance and volcanic aerosols significantly influence stratospheric dynamics in the early 19th century, whereas changes in the visible part of the spectrum and energetic particles have smaller effects. A reduction of UV irradiance by 15%, which represents the presently discussed highest estimate of UV irradiance change caused by solar activity changes, causes global ozone decrease below the stratopause reaching as much as 8% in the midlatitudes at 5 hPa and a significant stratospheric cooling of up to 2 °C in the mid-stratosphere and to 6 °C in the lower mesosphere. Changes in energetic particle precipitation lead only to minor changes in the yearly averaged temperature fields in the stratosphere. Volcanic aerosols heat the tropical lower stratosphere, allowing more water vapour to enter the tropical stratosphere, which, via HOx reactions, decreases upper stratospheric and mesospheric ozone by roughly 4%. Conversely, heterogeneous chemistry on aerosols reduces stratospheric NOx, leading to a 12% ozone increase in the tropics, whereas a decrease in ozone of up to 5% is found over Antarctica in boreal winter. The linear superposition of the different contributions is not equivalent to the response obtained in a simulation

Tracer transport in the tropical lower stratosphere. Ph.D. Thesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trepte, C.R.

1993-01-01

Distributions of aerosol extinction ratio (beta r) and ozone, derived from the Stratospheric Aerosol and Gas Experiment (SAGE 1/2) satellite experiments (1979-1981 and 1984-1992), are used in conjunction with conventional meteorological analyses to deduce patterns of stratospheric tracer transport. Following volcanic eruptions at low latitudes, the aerosol observations suggest that two transport regimes exist in the tropical lower stratosphere. Aerosols disperse rapidly poleward and downward within a layer several kilometers above the tropopause. More pronounced transport is biased toward the winter hemisphere. At higher altitudes, however, volcanic aerosols tend to remain over the equator in a reservoir bounded by strongmore » meridional gradients near 20 deg N and S. Over the equator, enhanced lofting of aerosols occurs during QBO easterly shear, while subsidence relative to the mean meridional flow takes place during QBO westerly shear. While particle growth and evaporation effects are important, many interesting features of the aerosol distribution can only be explained by air motions. It is also shown that QBO induced ozone anomalies over the equator are also consistent with QBO aerosol variations. In the upper transport regime, the subtropical gradients of beta r coincide with the location of a meridional gradient in potential vorticity. Since isentropic transport is inhibited across potential vorticity gradients, the tropics are temporarily isolated from eddy mixing taking place in the winter extratropics. Zonal mean distributions of ozone; however, do not have similar meridional gradients in the subtropics. This difference probably reflects a different source/sink distribution for ozone in comparison to that for aerosol and potential vorticity. Detrainment of aerosol from the equatorial reservoir depends upon the phase of the QBO and the strength of winter eddy disturbances in the subtropics.« less

Raman Lidar Measurements of Pinatubo Aerosols over Southeastern Kansas During November-december 1991

NASA Technical Reports Server (NTRS)

Ferrare, R. A.; Melfi, S. H.; Whiteman, D. N.; Evans, K. D.

1992-01-01

The eruptions of the Philippine volcano Pinatubo during June 1991 produced large amounts of stratospheric aerosols that could significantly affect earth's climate as well as trigger stratospheric ozone depletion through heterogeneous chemical reactions. Information regarding the physical and optical properties of these aerosols is required to quantify those effects. By measuring both the elastically backscattered signal and the inelastic signal produced by Raman scattering from nitrogen molecules, Raman lidar can provide some of this information. In this presentation we discuss Raman lidar measurements of the scattering ratio, backscattering, extinction, extinction/backscattering ratio, and optical thickness of the Pinatubo aerosols over southeastern Kansas made on 10 nights during November and December, 1991. The Raman lidar developed at GSFC is a trailer-based system which uses an XeF excimer laser to transmit light at 351 nm. The light backscattered by molecules and aerosols at this wavelength is detected as well as Raman scattered light from water vapor, nitrogen, and oxygen molecules. Since background skylights interfere with the detection of the Raman signals the data discussed in this paper were acquired only at night.

Arctic polar stratospheric cloud measurements by means of a four wavelength depolarization lidar

NASA Technical Reports Server (NTRS)

Stefanutti, L.; Castagnoli, F.; Delguasta, M.; Flesia, C.; Godin, S.; Kolenda, J.; Kneipp, H.; Kyro, Esko; Matthey, R.; Morandi, M.

1994-01-01

A four wavelength depolarization backscattering lidar has been operated during the European Arctic Stratospheric Ozone Experiment (EASOE) in Sodankyl, in the Finnish Arctic. The lidar performed measurements during the months of December 1991, January, February and March 1992. The Finnish Meteorological Institute during the same period launched regularly three Radiosondes per day, and three Ozone sondes per week. Both Mt. Pinatubo aerosols and Polar Stratospheric Clouds were measured. The use of four wavelengths, respectively at 355 nm, 532 nm , 750 nm, and 850 nm permits an inversion of the lidar data to determine aerosol particle size. The depolarization technique permits the identification of Polar Stratospheric Clouds. Frequent correlation between Ozone minima and peaks in the Mt. Pinatubo aerosol maxima were detected. Measurements were carried out both within and outside the Polar Vortex.

Easy Volcanic Aerosol (EVA v1.0): an idealized forcing generator for climate simulations

NASA Astrophysics Data System (ADS)

Toohey, Matthew; Stevens, Bjorn; Schmidt, Hauke; Timmreck, Claudia

2016-11-01

Stratospheric sulfate aerosols from volcanic eruptions have a significant impact on the Earth's climate. To include the effects of volcanic eruptions in climate model simulations, the Easy Volcanic Aerosol (EVA) forcing generator provides stratospheric aerosol optical properties as a function of time, latitude, height, and wavelength for a given input list of volcanic eruption attributes. EVA is based on a parameterized three-box model of stratospheric transport and simple scaling relationships used to derive mid-visible (550 nm) aerosol optical depth and aerosol effective radius from stratospheric sulfate mass. Precalculated look-up tables computed from Mie theory are used to produce wavelength-dependent aerosol extinction, single scattering albedo, and scattering asymmetry factor values. The structural form of EVA and the tuning of its parameters are chosen to produce best agreement with the satellite-based reconstruction of stratospheric aerosol properties following the 1991 Pinatubo eruption, and with prior millennial-timescale forcing reconstructions, including the 1815 eruption of Tambora. EVA can be used to produce volcanic forcing for climate models which is based on recent observations and physical understanding but internally self-consistent over any timescale of choice. In addition, EVA is constructed so as to allow for easy modification of different aspects of aerosol properties, in order to be used in model experiments to help advance understanding of what aspects of the volcanic aerosol are important for the climate system.

Single-Particle Measurements of Midlatitude Black Carbon and Light-Scattering Aerosols from the Boundary Layer to the Lower Stratosphere

NASA Technical Reports Server (NTRS)

Schwartz, J. P.; Gao, R. S.; Fahey, D. W.; Thomson, D. S.; Watts, L. A.; Wilson, J. C.; Reeves, J. M.; Darbeheshti, M.; Baumgardner, D. G.; Kok, G. L.;

The Influence of Extremely Large Solar Proton Events in a Changing Stratosphere. Stratospheric Influence of Solar Proton Events

NASA Technical Reports Server (NTRS)

Jackman, Charles H.; Fleming, Eric L.; Vitt, Francis M.

1999-01-01

Two periods of extremely large solar proton events (SPEs) occurred in the past thirty years, which forced significant long-term polar stratospheric changes. The August 2-10, 1972 and October 19-27, 1989 SPEs happened in stratospheres that were quite different chemically. The stratospheric chlorine levels were relatively small in 1972 (approximately 1.2 ppbv) and were fairly substantial in 1989 at about (approximately 3 ppbv). Although these SPEs produced both HO(x) and NO(y) constituents in the mesosphere and stratosphere, only the NO(y) constituents had lifetimes long enough to affect ozone for several months to years past the events. Our recently improved two-dimensional chemistry and transport atmospheric model was used to compute the effects of these gigantic SPEs in a changing stratosphere. Significant upper stratospheric ozone depletions > 10% are computed to last for a few months past these SPEs. The long-lived SPE-produced NO(y) constituents were transported to lower levels during winter after these huge SPEs and caused impacts in the middle and lower stratosphere. During periods of high halogen loading these impacts resulted in interference with the chlorine and bromine loss cycles for ozone destruction. The chemical state of the atmosphere, including the stratospheric sulfate aerosol density, substantially affected the predicted stratospheric influence of these extremely large SPEs.

Nitric acid in polar stratospheric clouds - Similar temperature of nitric acid condensation and cloud formation

NASA Technical Reports Server (NTRS)

Pueschel, Rudolf F.; Snetsinger, Kenneth G.; Hamill, Patrick; Goodman, Jindra K.; Mccormick, M. Patrick

1990-01-01

As shown independently by two different techniques, nitric acid aerosols and polar stratospheric clouds (PSCs) both form below similar threshold temperatures. This supports the idea that the PSC particles involved in chlorine activation and ozone depletion in the winter polar stratosphere are composed of nitric acid. One technique used to show this is the inertial impaction of nitric acid aerosols using an Er-2 aircraft; the other method is remote sensing of PSCs by the Stratospheric Aerosol Measurement (SAM II) satellite borne optical sensor. Both procedures were in operation during the Arctic Airborne Stratospheric Expedition in 1989, and the Airborne Antarctic Ozone Experiment in 1987. Analysis of Arctic particles gathered in situ indicates the presence of nitric acid below a 'first appearance' temperature Tfa = 202 K. This is the same highest temperature at which PSCs are seen by the SAM II satellite. In comparison, a 'first appearance' temperature Tfa = 198 K as found for the Antarctic samples.

High-resolution Sulfur Isotopes in Ice Cores Identify Large Stratospheric Eruptions

NASA Astrophysics Data System (ADS)

Burke, A.; Sigl, M.; Moore, K.; Nita, D. C.; Adkins, J. F.; Paris, G.; McConnell, J.

2016-12-01

The record of the volcanic forcing of climate over the past 2500 years is reconstructed primarily from sulfate concentrations in ice cores. Of particular interest are stratospheric eruptions, as these afford sulfate aerosols the longest residence time and largest dispersion in the atmosphere, and thus the greatest impact on radiative forcing. Identification of stratospheric eruptions currently relies on the successful matching of the same volcanic sulfate peak in ice cores from both the Northern and Southern hemispheres (a "bipolar event"). These are interpreted to reflect the global distribution of sulfur aerosols by the stratospheric winds. Despite its recent success, this method relies on precise and accurate dating of ice cores, in order to distinguish between a true `bipolar event' and two separate eruptions that occurred in close temporal succession. Sulfur isotopes can been used to distinguish between these two scenarios since stratospheric sulfur aerosols are exposed to UV radiation which imparts a mass independent fractionation (Baroni et al., 2007). Mass independent fractionation of sulfate in ice cores thus offers a novel method of fingerprinting stratospheric eruptions, and thus refining the historic record of explosive volcanism and its forcing of climate. Here we present new high-resolution (sub-annual) sulfur isotope data from the Tunu Ice core in Greenland over seven eruptions. Sulfur isotopes were measured by MC-ICP-MS, which substantially reduces sample size requirements and allows high temporal resolution from a single ice core. We demonstrate the efficacy of the method on recent, well-known eruptions (including Pinatubo and Katmai/Novarupta), and then apply it to unidentified sulfate peaks, allowing us to identify new stratospheric eruptions. Baroni, M., Thiemens, M. H., Delmas, R. J., & Savarino, J. (2007). Mass-independent sulfur isotopic compositions in stratospheric volcanic eruptions. Science, 315(5808), 84-87. http://doi.org/10

The 1980 eruptions of Mount St. Helens - Physical and chemical processes in the stratospheric clouds

NASA Technical Reports Server (NTRS)

Turco, R. P.; Toon, O. B.; Whitten, R. C.; Hamill, P.; Keesee, R. G.

1983-01-01

The large and diverse set of observational data collected in the high-altitude plumes of the May 18, May 25, and June 13, 1980 eruptions is organized and analyzed with a view to discerning the processes at work. The data serve to guide and constrain detailed model simulations of the volcanic clouds. For this purpose, use is made of a comprehensive one-dimensional model of stratospheric sulfate aerosols, sulfur precursor gases, and volcanic ash and dust. The model takes into account gas-phase and condensed-phase (heterogeneous) chemistry in the clouds, aerosol nucleation and growth, and cloud expansion. Computational results are presented for the time histories of the gaseous species concentrations, aerosol size distributions, and ash burdens of the eruption clouds. Also investigated are the long-term buildup of stratospheric aerosols in the Northern Hemisphere and the persistent effects of injected chlorine and water vapor on stratospheric ozone. It is concluded that SO2, water vapor, and ash were probably the most important substances injected into the stratosphere by the Mount St. Helens volcano, both with respect to their widespread effects on composition and their effect on climate.

Aerosol Absorption Effects in the TOMS UV Algorithm

NASA Technical Reports Server (NTRS)

Torres, O.; Krotkov, N.; Bhartia, P. K.

2004-01-01

The availability of global long-term estimates of surface UV radiation is very important, not only for preventive medicine considerations, but also as an important tool to monitor the effects of the stratospheric ozone recovery expected to occur in the next few decades as a result of the decline of the stratospheric chlorine levels. In addition to the modulating effects of ozone and clouds, aerosols also affect the levels of UV-A and W-B radiation reaching the surface. Oscillations in surface W associated with the effects of aerosol absorption may be comparable in magnitude to variations associated with the stratospheric ozone recovery. Thus, the accurate calculation of surface W radiation requires that both the scattering and absorption effects of tropospheric aerosols be taken into account. Although absorption effects of dust and elevated carbonaceous aerosols are already accounted for using Aerosol Index technique, this approach does not work for urban/industrial aerosols in the planetary boundary layer. The use of the new TOMS long-term global data record on UV aerosol absorption optical depth, can improve the accuracy of TOMS spectral UV products, by properly including the spectral attenuation effects of carbonaceous, urban/industrial and mineral aerosols. The TOMS data set on aerosol properties will be discussed, and results of its use in the TOMS surface W algorithm will be presented.

Effects of a polar stratosphere cloud parameterization on ozone depletion due to stratospheric aircraft in a two-dimensional model

NASA Technical Reports Server (NTRS)

Considine, David B.; Douglass, Anne R.; Jackman, Charles H.

1994-01-01

A parameterization of Type 1 and 2 polar stratospheric cloud (PSC) formation is presented which is appropriate for use in two-dimensional (2-D) photochemical models of the stratosphere. The calculations of PSC frequency of occurrence and surface area density uses climatological temperature probability distributions obtained from National Meteorological Center data to avoid using zonal mean temperatures, which are not good predictors of PSC behavior. The parameterization does not attempt to model the microphysics of PSCs. The parameterization predicts changes in PSC formation and heterogeneous processing due to perturbations of stratospheric trace constituents. It is therefore useful in assessing the potential effects of a fleet of stratospheric aircraft (high speed civil transports, or HSCTs) on stratospheric composition. the model calculated frequency of PSC occurrence agrees well with a climatology based on stratospheric aerosol measurement (SAM) 2 observations. PSCs are predicted to occur in the tropics. Their vertical range is narrow, however, and their impact on model O3 fields is small. When PSC and sulfate aerosol heterogeneous processes are included in the model calculations, the O3 change for 1980 - 1990 is in substantially better agreement with the total ozone mapping spectrometer (TOMS)-derived O3 trend than otherwise. The overall changes in model O3 response to standard HSCT perturbation scenarios produced by the parameterization are small and tend to decrease the model sensitivity to the HSCT perturbation. However, in the southern hemisphere spring a significant increase in O3 sensitivity to HSCT perturbations is found. At this location and time, increased PSC formation leads to increased levels of active chlorine, which produce the O3 decreases.

Linkages Between Ozone-depleting Substances, Tropospheric Oxidation and Aerosols

NASA Technical Reports Server (NTRS)

Voulgarakis, A.; Shindell, D. T.; Faluvegi, G.

2013-01-01

Coupling between the stratosphere and the troposphere allows changes in stratospheric ozone abundances to affect tropospheric chemistry. Large-scale effects from such changes on chemically produced tropospheric aerosols have not been systematically examined in past studies. We use a composition-climate model to investigate potential past and future impacts of changes in stratospheric ozone depleting substances (ODS) on tropospheric oxidants and sulfate aerosols. In most experiments, we find significant responses in tropospheric photolysis and oxidants, with small but significant effects on methane radiative forcing. The response of sulfate aerosols is sizeable when examining the effect of increasing future nitrous oxide (N2O) emissions. We also find that without the regulation of chlorofluorocarbons (CFCs) through the Montreal Protocol, sulfate aerosols could have increased by 2050 by a comparable amount to the decreases predicted due to relatively stringent sulfur emissions controls. The individual historical radiative forcings of CFCs and N2O through their indirect effects on methane (-22.6mW/sq. m for CFCs and -6.7mW/sq. m for N2O) and sulfate aerosols (-3.0mW/sq. m for CFCs and +6.5mW/sq. m for N2O when considering the direct aerosol effect) discussed here are non-negligible when compared to known historical ODS forcing. Our results stress the importance of accounting for stratosphere-troposphere, gas-aerosol and composition-climate interactions when investigating the effects of changing emissions on atmospheric composition and climate.

Stratospheric CCN sampling program

NASA Technical Reports Server (NTRS)

Rogers, C. F.

1981-01-01

When Mt. St. Helens produced several major eruptions in the late spring of 1980, there was a strong interest in the characterization of the cloud condensation nuclei (CCN) activity of the material that was injected into the troposphere and stratosphere. The scientific value of CCN measurements is two fold: CCN counts may be directly applied to calculations of the interaction of the aerosol (enlargement) at atmospherically-realistic relative humidities or supersaturations; and if the chemical constituency of the aerosol can be assumed, the number-versus-critical supersaturation spectrum may be converted into a dry aerosol size spectrum covering a size region not readily measured by other methods. The sampling method is described along with the instrumentation used in the experiments.

Chlorofluoromethanes and the Stratosphere

NASA Technical Reports Server (NTRS)

Hudson, R. D. (Editor)

1977-01-01

The conclusions of a workshop held by the National Aeronautics and Space Administration to assess the current knowledge of the impact of chlorofluoromethane release in the troposphere on stratospheric ozone concentrations. The following topics are discussed; (1) Laboratory measurements; (2) Ozone measurements and trends; (3) Minor species and aerosol measurements; (4) One dimensional modeling; and (5) Multidimensional modeling.

SPICE Work Package 3: Modelling the Effects of Stratospheric Aerosol Geoengineering

NASA Astrophysics Data System (ADS)

Driscoll, Simon

2015-04-01

This talk presents the results of the SPICE Work Package 3. There is an obvious need for methods to verify the accuracy of geoengineering given no observations of a geoengineering programme. Accordingly, model ability in reproducing the observed dynamical response to volcanic eruptions is discussed using analysis of CMIP5 data and different configurations of the HadGEM2 model. With the HadGEM2-L60 model shown to be substantially better in reproducing the observed dynamical response to volcanic eruptions, simulations of GeoMIP's G4 scenario are performed. Simulated impacts of geoengineering are described, and asymmetries between the immediate onset and immediate cessation ('termination') of geoengineering are analysed. Whilst a rapid large increase in stratospheric sulphate aerosols (such as from volcanic eruptions) can cause substantial damage, most volcanic eruptions in general are not catastrophic. One may therefore suspect that an 'equal but opposite' change in radiative forcing from termination may therefore not be catastrophic, if the climatic response is simulated to be symmetric. HadGEM2 simulations reveal a substantially more rapid change in variables such as near-surface temperature and precipitation following termination than the onset, indicating that termination may be substantially more damaging and even catastrophic. Some suggestions for hemispherically asymmetric geoengineering have been proposed as a way to reduce Northern Hemisphere sea ice, for example, with lesser impacts on the rest of the climate. However, HadGEM2 simulations are performed and observations analysed following volcanic eruptions. Both indicate substantial averse consequences from hemispherically asymmetric loading of stratospheric loading on precipitation in the Sahelian region - a vulnerable region where drought has caused hundreds of thousands of deaths and created millions of refugees in the past.

A 2D Microphysical Analysis of Aerosol Nucleation in the Polar Winter Stratosphere: Implications for H2SO4 Photolysis and Nucleation Mechanisms

NASA Technical Reports Server (NTRS)

Mills, Michael J.; Toon, Owen B.; Mills, Michael J.; Solomon, Susan

1997-01-01

Each spring a layer of small particles forms between 20 and 30 km in the polar regions. Results are presented from a 2D microphysical model of sulfate aerosol, which provide the first self-consistent explanation of the observed "CN layer." Photochemical conversion of sulfuric acid to SO2 in the upper stratosphere and mesosphere is necessary for this layer to form. Recent laboratory measurements of H2SO4 and SO3 photolysis rates are consistent with such conversion, though an additional source of SO2 may be required. Nucleation throughout the polar winter extends the top of the aerosol layer to higher altitudes, despite strong downward transport of ambient air. This finding may be important to heterogeneous chemistry at the top of the aerosol layer in polar winter and spring.

Lower stratospheric observations from aircraft and satellite during the 2015/2016 El Nino

NASA Astrophysics Data System (ADS)

Rosenlof, K. H.; Avery, M. A.; Davis, S. M.; Gao, R. S.; Thornberry, T. D.

2016-12-01

Winter 2015/2016 experienced a strong El Nino that was heavily observed by aircraft, radiosonde and satellite platforms. During the National Oceanographic and Atmospheric Administration's (NOAA) Sensing Hazards with Operational Unmanned Technology (SHOUT)/El Nino Rapid Response (ENRR) flights of the NASA Global Hawk, in situ ozone measurements were made in the lower stratosphere over the Pacific. These will be contrasted with ozone measurements taken during La Nina and ENSO neutral conditions during past Global Hawk aircraft campaigns. Additionally, lower stratospheric water vapor and ozone measurements from the Microwave Limb Sounder satellite instrument and stratospheric ice measurements above the tropopause from the Cloud-Aerosol Aerosol Lidar with Orthogonal Polarization (CALIOP) will be presented. Our aircraft ozone measurements are higher for the El Nino flights than during other missions previously sampled, while zonally averaged lower stratospheric water vapor and central Pacific ice path above the tropopause reached record highs. Implications and possible reasons for these anomalous observations will be discussed. Winter 2015/2016 experienced a strong El Nino that was heavily observed by aircraft, radiosonde and satellite platforms. During the National Oceanographic and Atmospheric Administration's (NOAA) Sensing Hazards with Operational Unmanned Technology (SHOUT)/El Nino Rapid Response (ENRR) flights of the NASA Global Hawk, in situ ozone measurements were made in the upper troposphere and lower stratosphere (UTLS) over the Pacific. These will be contrasted with ozone measurements made during La Nina and ENSO neutral conditions during past Global Hawk aircraft campaigns. Additionally, UTLS water vapor and ozone measurements from the Microwave Limb Sounder (MLS) satellite instrument and stratospheric ice measurements above the tropopause from the Cloud-Aerosol Aerosol Lidar with Orthogonal Polarization (CALIOP) will be presented. Our aircraft ozone

Heterogeneous Chemistry of HONO on Liquid Sulfuric Acid: A New Mechanism of Chlorine Activation on Stratospheric Sulfate Aerosols

NASA Technical Reports Server (NTRS)

Zhang, Renyi; Leu, Ming-Taun; Keyser, Leon F.

1996-01-01

Heterogeneous chemistry of nitrous acid (HONO) on liquid sulfuric acid (H2SO4) Was investigated at conditions that prevail in the stratosphere. The measured uptake coefficient (gamma) of HONO on H2SO4 increased with increasing acid content, ranging from 0.03 for 65 wt % to about 0.1 for 74 wt %. In the aqueous phase, HONO underwent irreversible reaction with H2SO4 to form nitrosylsulfuric acid (NO(+)HSO4(-). At temperatures below 230 K, NO(+)HSO4(-) was observed to be stable and accumulated in concentrated solutions (less than 70 wt % H2SO4) but was unstable and quickly regenerated HONO in dilute solutions (less than 70 wt %). HCl reacted with HONO dissolved in sulfuric acid, releasing gaseous nitrosyl chloride (ClNO). The reaction probability between HCl and HONO varied from 0.01 to 0.02 for 60-72 wt % H2SO4. In the stratosphere, ClNO photodissociates rapidly to yield atomic chlorine, which catalytically destroys ozone. Analysis of the laboratory data reveals that the reaction of HCl with HONO on sulfate aerosols can affect stratospheric ozone balance during elevated sulfuric acid loadings after volcanic eruptions or due to emissions from the projected high-speed civil transport (HSCT). The present results may have important implications on the assessment of environmental acceptability of HSCT.

High-resolution sulfur isotopes in ice cores identify large stratospheric volcanic eruptions

NASA Astrophysics Data System (ADS)

Burke, Andrea; Sigl, Michael; Adkins, Jess; Paris, Guillaume; McConnell, Joe

2016-04-01

The record of the volcanic forcing of climate over the past 2500 years is reconstructed primarily from sulfate concentrations in ice cores. Of particular interest are stratospheric eruptions, as these afford sulfate aerosols the longest residence time and largest dispersion in the atmosphere, and thus the greatest impact on radiative forcing. Identification of stratospheric eruptions currently relies on the successful matching of the same volcanic sulphate peak in ice cores from both the Northern and Southern hemispheres (a "bipolar event"). These are interpreted to reflect the global distribution of sulfur aerosols by the stratospheric winds. Despite its recent success, this method relies on precise and accurate dating of ice cores, in order to distinguish between a true 'bipolar event' and two separate eruptions that occurred in close temporal succession. Sulfur isotopes can been used to distinguish between these two scenarios since stratospheric sulfur aerosols are exposed to UV radiation which imparts a mass independent fractionation (Baroni et al., 2007). Mass independent fractionation of sulfate in ice cores thus offers a novel method of fingerprinting stratospheric eruptions, and thus refining the historic record of explosive volcanism and its forcing of climate. Here we present new high-resolution (sub-annual) sulfur isotope data from the Tunu Ice core in Greenland over seven eruptions. Sulfur isotopes were measured by MC-ICP-MS, which substantially reduces sample size requirements and allows high temporal resolution from a single ice core. We demonstrate the efficacy of the method on recent, well-known eruptions (including Pinatubo and Katmai/Novarupta), and then apply it to unidentified sulfate peaks, allowing us to identify new stratospheric eruptions. Baroni, M., Thiemens, M. H., Delmas, R. J., & Savarino, J. (2007). Mass-independent sulfur isotopic compositions in stratospheric volcanic eruptions. Science, 315(5808), 84-87. http://doi.org/10

Impact of major volcanic eruptions on stratospheric water vapour

NASA Astrophysics Data System (ADS)

Löffler, Michael; Brinkop, Sabine; Jöckel, Patrick

2016-05-01

Volcanic eruptions can have a significant impact on the Earth's weather and climate system. Besides the subsequent tropospheric changes, the stratosphere is also influenced by large eruptions. Here changes in stratospheric water vapour after the two major volcanic eruptions of El Chichón in Mexico in 1982 and Mount Pinatubo on the Philippines in 1991 are investigated with chemistry-climate model simulations. This study is based on two simulations with specified dynamics of the European Centre for Medium-Range Weather Forecasts Hamburg - Modular Earth Submodel System (ECHAM/MESSy) Atmospheric Chemistry (EMAC) model, performed within the Earth System Chemistry integrated Modelling (ESCiMo) project, of which only one includes the long-wave volcanic forcing through prescribed aerosol optical properties. The results show a significant increase in stratospheric water vapour induced by the eruptions, resulting from increased heating rates and the subsequent changes in stratospheric and tropopause temperatures in the tropics. The tropical vertical advection and the South Asian summer monsoon are identified as sources for the additional water vapour in the stratosphere. Additionally, volcanic influences on tropospheric water vapour and El Niño-Southern Oscillation (ENSO) are evident, if the long-wave forcing is strong enough. Our results are corroborated by additional sensitivity simulations of the Mount Pinatubo period with reduced nudging and reduced volcanic aerosol extinction.

A comparison of the Stratospheric Aerosol and Gas Experiment II tropospheric water vapor to radiosonde measurements

NASA Technical Reports Server (NTRS)

Larsen, J. C.; Chiou, E. W.; Chu, W. P.; Mccormick, M. P.; Mcmaster, L. R.; Oltmans, S.; Rind, D.

1993-01-01

Results are presented of a comparison beteen observations of the upper-tropospheric water vapor data obtained from the Stratospheric Aerosol and Gas Experiment II (SAGE II) instrument and radiosonde observations for 1987 and radiosonde-based climatologies. Colocated SAGE II-radiosonde measurement pairs are compared individually and in a zonal mean sense. A straight comparison of monthly zonal means between SAGE II and radiosondes for 1987 and Global Atmospheric Statistics (1963-1973) indicates that the clear-sky SAGE II climatology is approximately half the level of clear/cloudy sky of both radiosonde climatologies. Annual zonal means calculated from the set of profile pairs again showed SAGE II to be significantly drier in many altitude bands.

Upper-atmosphere Aerosols: Properties and Natural Cycles

NASA Technical Reports Server (NTRS)

Turco, Richard P.

1992-01-01

The middle atmosphere is rich in its variety of particulate matter, which ranges from meteorite debris, to sulfate aerosols, to polar stratospheric ice clouds. Volcanic eruptions strongly perturb the stratospheric sulfate (Junge) layer. High-altitude 'noctilucent' ice clouds condense at the summer mesopause. The properties of these particles, including their composition, sizes, and geographical distribution, are discussed, and their global effects, including chemical, radiative, and climatic roles, are reviewed. Polar stratospheric clouds (PSCs) are composed of water and nitric acid in the form of micron-sized ice crystals. These particles catalyze reactions of chlorine compounds that 'activate' otherwise inert chlorine reservoirs, leading to severe ozone depletions in the southern polar stratosphere during austral spring. PSCs also modify the composition of the polar stratosphere through complex physiocochemical processes, including dehydration and denitrification, and the conversion of reactive nitrogen oxides into nitric acid. If water vapor and nitric acid concentrations are enhanced by high-altitude aircraft activity, the frequency, geographical range, and duration of PSCs might increase accordingly, thus enhancing the destruction of the ozone layer (which would be naturally limited in geographical extent by the same factors that confine the ozone hole to high latitudes in winter). The stratospheric sulfate aerosol layer reflects solar radiation and increases the planetary albedo, thereby cooling the surface and possibly altering the climate. Major volcanic eruptions, which increase the sulfate aerosol burden by a factor of 100 or more, may cause significant global climate anomalies. Sulfate aerosols might also be capable of activating stratospheric chlorine reservoirs on a global scale (unlike PCSs, which represent a localized polar winter phenomenon), although existing evidence suggests relatively minor perturbations in chlorine chemistry. Nevertheless, if

SAM II aerosol profile measurements, Poker Flat, Alaska; July 16-19, 1979

NASA Technical Reports Server (NTRS)

Mccormick, M. P.; Chu, W. P.; Mcmaster, L. R.; Grams, G. W.; Herman, B. M.; Pepin, T. J.; Russell, P. B.; Swissler, T. J.

1981-01-01

SAM II satellite measurements during the July 1979 Poker Flat mission, yielded an aerosol extinction coefficient of 0.0004/km at 1.0 micron wavelength, in the region of the stratospheric aerosol mixing ratio peak (12-16 km). The stratospheric aerosol optical depth for these data, calculated from the tropopause through 30 km, is approximately 0.001. These results are consistent with the average 1979 summertime values found throughout the Arctic.

Modulations of stratospheric ozone by volcanic eruptions

NASA Technical Reports Server (NTRS)

Blanchette, Christian; Mcconnell, John C.

1994-01-01

We have used a time series of aerosol surface based on the measurements of Hofmann to investigate the modulation of total column ozone caused by the perturbation to gas phase chemistry by the reaction N2O5(gas) + H2O(aero) yields 2HNO3(gas) on the surface of stratospheric aerosols. We have tested a range of values for its reaction probability, gamma = 0.02, 0.13, and 0.26 which we compared to unperturbed homogeneous chemistry. Our analysis spans a period from Jan. 1974 to Oct. 1994. The results suggest that if lower values of gamma are the norm then we would expect larger ozone losses for highly enhanced aerosol content that for larger values of gamma. The ozone layer is more sensitive to the magnitude of the reaction probability under background conditions than during volcanically active periods. For most conditions, the conversion of NO2 to HNO3 is saturated for reaction probability in the range of laboratory measurements, but is only absolutely saturated following major volcanic eruptions when the heterogeneous loss dominates the losses of N2O5. The ozone loss due to this heterogeneous reaction increases with the increasing chlorine load. Total ozone losses calculated are comparable to ozone losses reported from TOMS and Dobson data.

Elemental concentrations in tropospheric and lower stratospheric air in a Northeastern region of Poland

NASA Astrophysics Data System (ADS)

Braziewicz, Janusz; Kownacka, Ludwika; Majewska, Urszula; Korman, Andrzej

Element concentrations of K, Ca, Ti, Cr, Fe, Ni, Cu, Zn, Se, Br, Sr and Pb as well as the activity of natural radionuclides 210Pb and 226Ra in air were measured. The aerosol samples were collected during tropospheric and stratospheric aircraft flights over the Northeastern region of Poland, which is mostly an agricultural and wooded area. The air volumes were filtered using Petrianov filters at 1, 3, 6, 9, 12 and 15 km above the ground level by special equipment attached to a jet plane. Aircraft flights were provided from September 1997 to August 1998 in 5 separate sampling runs. The long sampling distances served as a good representation of mean aerosol composition and distribution. Concentrations of the same elements were also measured using stationary equipment near the ground level at the outskirts of Warsaw. The vertical profiles of element concentration were obtained and the elemental compositions for the tropospheric and stratospheric aerosols were compared with those from the near-ground level. Contribution of K, Ca, Ti and Fe, which are the main components of soil, in total mass of all detected ones was estimated. Relative concentrations of all measured elements, which show any differences in the composition of the aerosol were calculated. The results obtained confirm the fact that the stratospheric reservoir is observed in the bottom stratosphere. The XRF method based on molybdenum X-ray tube was used as an analytical tool in the determination of aerosols trace elements. The altitude distributions of radioactivity of 226Ra and 210Pb were determined using radiochemical methods.

Relevant climate response tests for stratospheric aerosol injection: A combined ethical and scientific analysis

NASA Astrophysics Data System (ADS)

Lenferna, Georges Alexandre; Russotto, Rick D.; Tan, Amanda; Gardiner, Stephen M.; Ackerman, Thomas P.

2017-06-01

In this paper, we focus on stratospheric sulfate injection as a geoengineering scheme, and provide a combined scientific and ethical analysis of climate response tests, which are a subset of outdoor tests that would seek to impose detectable and attributable changes to climate variables on global or regional scales. We assess the current state of scientific understanding on the plausibility and scalability of climate response tests. Then, we delineate a minimal baseline against which to consider whether certain climate response tests would be relevant for a deployment scenario. Our analysis shows that some climate response tests, such as those attempting to detect changes in regional climate impacts, may not be deployable in time periods relevant to realistic geoengineering scenarios. This might pose significant challenges for justifying stratospheric sulfate aerosol injection deployment overall. We then survey some of the major ethical challenges that proposed climate response tests face. We consider what levels of confidence would be required to ethically justify approving a proposed test; whether the consequences of tests are subject to similar questions of justice, compensation, and informed consent as full-scale deployment; and whether questions of intent and hubris are morally relevant for climate response tests. We suggest further research into laboratory-based work and modeling may help to narrow the scientific uncertainties related to climate response tests, and help inform future ethical debate. However, even if such work is pursued, the ethical issues raised by proposed climate response tests are significant and manifold.

Aerosols and polar stratospheric clouds measurements during the EASOE campaign

NASA Technical Reports Server (NTRS)

Haner, D.; Godin, S.; Megie, G.; David, C.; Mitev, V.

1992-01-01

Preliminary results of observations performed using two different lidar systems during the EASOE (European Arctic Stratospheric Ozone Experiment), which has taken place in the winter of 1991-1992 in the northern hemisphere lattitude regions, are presented. The first system is a ground based multiwavelength lidar intended to perform measurements of the ozone vertical distribution in the 5 km to 40 km altitude range. It was located in Sodankyla (67 degrees N, 27 degrees E) as part of the ELSA experiment. The objectives of the ELSA cooperative project is to study the relation between polar stratospheric cloud events and ozone depletion with high vertical resolution and temporal continuity, and the evolution of the ozone distribution in relation to the position of the polar vortex. The second system is an airborne backscatter lidar (Leandre) which allows for the study of the 3-D structure and the optical properties of polar stratospheric clouds. The Leandre instrument is a dual-polarization lidar system, emitting at 532 nm, which allows for the determination of the type of clouds observed, according to the usual classification of polar stratospheric clouds. More than 60 hours of flight were performed in Dec. 1991, and Jan. and Feb. 1992 in Kiruna, Sweden. The operation of the Leandre instrument has led to the observation of the short scale variability of the Pinatubo volcanic cloud in the high latitude regions and to several episodes of polar stratospheric clouds. Preliminary analysis of the data is presented.

Overshooting of Clean Tropospheric Air in the Tropical Lower Stratosphere as Seen by the CALIPSO Lidar

NASA Technical Reports Server (NTRS)

Vernier, J. P.; Pommereau, J. P.; Thomason, L. W.; Pelon, J.; Garnier, A.; Deshler, T.; Jumelet, J.; Nielsen, J. K.

2011-01-01

The evolution of aerosols in the tropical upper troposphere/lower stratosphere between June 2006 and October 2009 is examined using the observations of the space borne CALIOP lidar aboard the CALIPSO satellite. Superimposed on several volcanic plumes and soot from an extreme biomass-burning event in 2009, the measurements reveal the existence of fast cleansing episodes of the lower stratosphere to altitudes as high as 20 km. The cleansing of the full 14-20km layer takes place within 1-4 months. Its coincidence with the maximum of convective activity in the southern tropics, suggests that the cleansing is the result of a large number of overshooting towers, injecting aerosol-poor tropospheric air into the lower stratosphere. The enhancements of aerosols at the tropopause level during the NH summer may be due to the same transport process but associated with intense sources of aerosols at the surface. Since, the tropospheric air flux derived from CALIOP observations during North Hemisphere winter is 5 20 times larger than the slow ascent by radiative heating usually assumed, the observations suggest that convective overshooting is a major contributor to troposphere-to-stratosphere transport with concommitant implications to the Tropical Tropopause Layer top height, chemistry and thermal structure.

El Chichon and 'mystery cloud' aerosols between 30 and 55 km Global observations from the SME visible spectrometer

NASA Astrophysics Data System (ADS)

Clancy, R. T.

1986-09-01

Visible limb radiances measured by the Solar Mesosphere Explorer (SME) are used to obtain volume scattering ratios for aerosol loading in the 30-55 km altitude range of the stratosphere. Global maps of these ratios are presented for the period January 1982 to August 1984. Significant aerosol scattering from the 'mystery cloud' and El Chichon aerosol layers are found above 30 km. A timescale of approximately 2 months between the appearance of the aerosol at 30.5 km and at 37.5 km is consistent with vertical transport of aerosol or vapor by eddy diffusion above 30 km. An anticorrelation exists between aerosol scattering and stratospheric temperatures. Periods of lower stratospheric temperatures may account for the formation of aerosol between 40 and 55 km altitude.

El Chichon and 'mystery cloud' aerosols between 30 and 55 km Global observations from the SME visible spectrometer

NASA Technical Reports Server (NTRS)

Clancy, R. T.

1986-01-01

Visible limb radiances measured by the Solar Mesosphere Explorer (SME) are used to obtain volume scattering ratios for aerosol loading in the 30-55 km altitude range of the stratosphere. Global maps of these ratios are presented for the period January 1982 to August 1984. Significant aerosol scattering from the 'mystery cloud' and El Chichon aerosol layers are found above 30 km. A timescale of approximately 2 months between the appearance of the aerosol at 30.5 km and at 37.5 km is consistent with vertical transport of aerosol or vapor by eddy diffusion above 30 km. An anticorrelation exists between aerosol scattering and stratospheric temperatures. Periods of lower stratospheric temperatures may account for the formation of aerosol between 40 and 55 km altitude.

Sources of plutonium in the atmosphere and stratosphere-troposphere mixing

PubMed Central

Hirose, Katsumi; Povinec, Pavel P.

2015-01-01

Plutonium isotopes have primarily been injected to the stratosphere by the atmospheric nuclear weapon tests and the burn-up of the SNAP-9A satellite. Here we show by using published data that the stratospheric plutonium exponentially decreased with apparent residence time of 1.5 ± 0.5 years, and that the temporal variations of plutonium in surface air followed the stratospheric trends until the early 1980s. In the 2000s, plutonium and its isotope ratios in the atmosphere varied dynamically, and sporadic high concentrations of 239,240Pu reported for the lower stratospheric and upper tropospheric aerosols may be due to environmental events such as the global dust outbreaks and biomass burning. PMID:26508010

Arctic stratospheric dehydration - Part 1: Unprecedented observation of vertical redistribution of water

NASA Astrophysics Data System (ADS)

Khaykin, S. M.; Engel, I.; Vömel, H.; Formanyuk, I. M.; Kivi, R.; Korshunov, L. I.; Krämer, M.; Lykov, A. D.; Meier, S.; Naebert, T.; Pitts, M. C.; Santee, M. L.; Spelten, N.; Wienhold, F. G.; Yushkov, V. A.; Peter, T.

2013-11-01

We present high-resolution measurements of water vapour, aerosols and clouds in the Arctic stratosphere in January and February 2010 carried out by in situ instrumentation on balloon sondes and high-altitude aircraft combined with satellite observations. The measurements provide unparalleled evidence of dehydration and rehydration due to gravitational settling of ice particles. An extreme cooling of the Arctic stratospheric vortex during the second half of January 2010 resulted in a rare synoptic-scale outbreak of ice polar stratospheric clouds (PSCs) remotely detected by the lidar aboard the CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) satellite. The widespread occurrence of ice clouds was followed by sedimentation and consequent sublimation of ice particles, leading to vertical redistribution of water inside the vortex. A sequence of balloon and aircraft soundings with chilled mirror and Lyman- α hygrometers (Cryogenic Frostpoint Hygrometer, CFH; Fast In Situ Stratospheric Hygrometer, FISH; Fluorescent Airborne Stratospheric Hygrometer, FLASH) and backscatter sondes (Compact Optical Backscatter Aerosol Detector, COBALD) conducted in January 2010 within the LAPBIAT (Lapland Atmosphere-Biosphere Facility) and RECONCILE (Reconciliation of Essential Process Parameters for an Enhanced Predictability of Arctic Stratospheric Ozone Loss and its Climate Interactions) campaigns captured various phases of this phenomenon: ice formation, irreversible dehydration and rehydration. Consistent observations of water vapour by these independent measurement techniques show clear signatures of irreversible dehydration of the vortex air by up to 1.6 ppmv in the 20-24 km altitude range and rehydration by up to 0.9 ppmv in a 1 km thick layer below. Comparison with space-borne Aura MLS (Microwave Limb Sounder) water vapour observations allow the spatiotemporal evolution of dehydrated air masses within the Arctic vortex to be derived and upscaled.

Observations of lower-stratospheric ClONO2, HNO3, and aerosol by the UARS CLAES experiment between January 1992 and April 1993

NASA Technical Reports Server (NTRS)

Roche, A. E.; Kumer, J. B.; Mergenthaler, J. L.; Nightingale, R. W.; Uplinger, W. G.; Ely, G. A.; Potter, J. F.; Wuebbles, D. J.; Connell, P. S.; Kinnison, D. E.

1994-01-01

This paper discusses simultaneous measurements of stratospheric ClONO2, HNO3, temperature, and aerosol extinction coefficient by the Cryogenic Limb Array Etalon Spectrometer (CLAES) on the NASA Upper Atmosphere Research Satellite (UARS), obtained over the period 9 January 1992 through 23 April 1993. The discussion concentrates on the stratosphere region near 21 km of particular interest to heterogeneously driven ozone depletion. For periods between 12 June and 1 September 1992 at latitudes poleward of about 60 deg S, when temperatures were below type I polar stratospheric cloud (PSC) formation thresholds throughout the lower stratosphere, CLAES observed high levels of PSCs coincident with highly depleted fields of both HNO3 and ClONO2. By 17 September, the incidence of PSCs had greatly diminished in the lower stratosphere, but both CLONO2 and HNO3 remained highly depleted. These observations are consistent with the removal of gaseous HNO3 through the formation of nitric acid trihydrate (NAT) particles and the removal of ClONO2 through heterogeneous reactions on the particle surfaces. They also suggest substantial denitrification of the lower Antarctic vortex through sedimentation of PSC particles. In the Northern Hemisphere winter of 1992/93 far fewer PSCs were observed in the Arctic lower-stratosphere vortex, which had shorter periods and more localized regions of cold temperatures. Both HNO3 and ClONO2 maintained much higher levels inside the Arctic vortex than seen in the Antarctic throughout the winter/spring period. Following 28 February 1993 when Arctic vortex temperatures rose above 195 K, ClONO2 was observed in large quantities (greater than 2.1 ppbv near 21 km) inside the vortex. The persistence of relatively high levels of HNO3 inside the Arctic spring vortex compared with the low levels seen in the Antarctic spring vortex suggest a much lower level of denitrification in the Arctic.

Albedo enhancement by stratospheric sulfur injections: More research needed

NASA Astrophysics Data System (ADS)

Robock, Alan

2016-12-01

Research on albedo enhancement by stratospheric sulfur injection inspired by Paul Crutzen's paper a decade ago has made clear that it may present serious risks and concerns as well as benefits if used to address the global warming problem. While volcanic eruptions were suggested as innocuous examples of stratospheric aerosols cooling the planet, the volcano analog also argues against stratospheric geoengineering because of ozone depletion and regional hydrologic responses. Continuous injection of SO2 into the lower stratosphere would reduce global warming and some of its negative impacts, and would increasing the uptake of CO2 by plants, but research in the past decade has pointed out a number of potential negative impacts of stratospheric geoengineering. More research is needed to better quantify the potential benefits and risks so that if society is tempted to implement geoengineering in the future it will be able to make an informed decision.

Size distribution and scattering phase function of aerosol particles retrieved from sky brightness measurements

NASA Technical Reports Server (NTRS)

Kaufman, Y. J.; Gitelson, A.; Karnieli, A.; Ganor, E. (Editor); Fraser, R. S.; Nakajima, T.; Mattoo, S.; Holben, B. N.

1994-01-01

Ground-based measurements of the solar transmission and sky radiance in a horizontal plane through the Sun are taken in several geographical regions and aerosol types: dust in a desert transition zone in Israel, sulfate particles in Eastern and Western Europe, tropical aerosol in Brazil, and mixed continental/maritime aerosol in California. Stratospheric aerosol was introduced after the eruption of Mount Pinatubo in June 1991. Therefore measurements taken before the eruption are used to analyze the properties of tropospheric aerosol; measurements from 1992 are also used to detect the particle size and concentration of stratospheric aerosol. The measurements are used to retrieve the size distribution and the scattering phase function at large scattering angles of the undisturbed aerosol particles. The retrieved properties represent an average on the entire atmospheric column. A comparison between the retrieved phase function for a scattering angle of 120 deg, with phase function predicted from the retrieved size distribution, is used to test the assumption of particle homogeneity and sphericity in radiative transfer models (Mie theory). The effect was found to be small (20% +/- 15%). For the stratospheric aerosol (sulfates), as expected, the phase function was very well predicted using the Mie theory. A model with a power law distribution, based on the spectral dependence of the optical thickness, alpha, cannot estimate accurately the phase function (up to 50% error for lambda = 0.87 microns). Before the Pinatubo eruption the ratio between the volumes of sulfate and coarse particles was very well correlated with alpha. The Pinatubo stratospheric aerosol destroyed this correlation. The aerosol optical properties are compared with analysis of the size, shape, and composition of the individual particles by electron microscopy of in situ samples. The measured volume size distribution before the injection of stratospheric aerosol consistently show two modes, sulfate

On the aliasing of the solar cycle in the lower stratospheric tropical temperature

NASA Astrophysics Data System (ADS)

Kuchar, Ales; Ball, William T.; Rozanov, Eugene V.; Stenke, Andrea; Revell, Laura; Miksovsky, Jiri; Pisoft, Petr; Peter, Thomas

2017-09-01

The double-peaked response of the tropical stratospheric temperature profile to the 11 year solar cycle (SC) has been well documented. However, there are concerns about the origin of the lower peak due to potential aliasing with volcanic eruptions or the El Niño-Southern Oscillation (ENSO) detected using multiple linear regression analysis. We confirm the aliasing using the results of the chemistry-climate model (CCM) SOCOLv3 obtained in the framework of the International Global Atmospheric Chemisty/Stratosphere-troposphere Processes And their Role in Climate Chemistry-Climate Model Initiative phase 1. We further show that even without major volcanic eruptions included in transient simulations, the lower stratospheric response exhibits a residual peak when historical sea surface temperatures (SSTs)/sea ice coverage (SIC) are used. Only the use of climatological SSTs/SICs in addition to background stratospheric aerosols removes volcanic and ENSO signals and results in an almost complete disappearance of the modeled solar signal in the lower stratospheric temperature. We demonstrate that the choice of temporal subperiod considered for the regression analysis has a large impact on the estimated profile signal in the lower stratosphere: at least 45 consecutive years are needed to avoid the large aliasing effect of SC maxima with volcanic eruptions in 1982 and 1991 in historical simulations, reanalyses, and observations. The application of volcanic forcing compiled for phase 6 of the Coupled Model Intercomparison Project (CMIP6) in the CCM SOCOLv3 reduces the warming overestimation in the tropical lower stratosphere and the volcanic aliasing of the temperature response to the SC, although it does not eliminate it completely.

Natural and anthropogenic perturbations of the stratospheric ozone layer

NASA Technical Reports Server (NTRS)

Brasseur, Guy P.

1992-01-01

The paper reviews potential causes for reduction in the ozone abundance. The response of stratospheric ozone to solar activity is discussed. Ozone changes are simulated in relation with the potential development of a fleet of high-speed stratospheric aircraft and the release in the atmosphere of chlorofluorocarbons. The calculations are performed by a two-dimensional chemical-radiative-dynamical model. The importance of heterogeneous chemistry in polar stratospheric clouds and in the Junge layer (sulfate aerosol) is emphasized. The recently reported ozone trend over the last decade is shown to have been largely caused by the simultaneous effects of increasing concentrations of chlorofluorocarbons and heterogeneous chemistry. The possibility for a reduction in stratospheric ozone following a large volcanic eruption such as that of Mount Pinatubo in 1991 is discussed.

Stratospheric Aerosol and Gas Experiment, SAGE III on ISS, An Earth Science Mission on the International Space Station, Schedule Risk Analysis, A Project Perspective

NASA Technical Reports Server (NTRS)

Bonine, Lauren

2015-01-01

The presentation provides insight into the schedule risk analysis process used by the Stratospheric Aerosol and Gas Experiment III on the International Space Station Project. The presentation focuses on the schedule risk analysis process highlighting the methods for identification of risk inputs, the inclusion of generic risks identified outside the traditional continuous risk management process, and the development of tailored analysis products used to improve risk informed decision making.

A new technique for measuring aerosols with moonlight observations and a sky background model

NASA Astrophysics Data System (ADS)

Jones, Amy; Noll, Stefan; Kausch, Wolfgang; Kimeswenger, Stefan; Szyszka, Ceszary; Unterguggenberger, Stefanie

2014-05-01

There have been an ample number of studies on aerosols in urban, daylight conditions, but few for remote, nocturnal aerosols. We have developed a new technique for investigating such aerosols using our sky background model and astronomical observations. With a dedicated observing proposal we have successfully tested this technique for nocturnal, remote aerosol studies. This technique relies on three requirements: (a) sky background model, (b) observations taken with scattered moonlight, and (c) spectrophotometric standard star observations for flux calibrations. The sky background model was developed for the European Southern Observatory and is optimized for the Very Large Telescope at Cerro Paranal in the Atacama desert in Chile. This is a remote location with almost no urban aerosols. It is well suited for studying remote background aerosols that are normally difficult to detect. Our sky background model has an uncertainty of around 20 percent and the scattered moonlight portion is even more accurate. The last two requirements are having astronomical observations with moonlight and of standard stars at different airmasses, all during the same night. We had a dedicated observing proposal at Cerro Paranal with the instrument X-Shooter to use as a case study for this method. X-Shooter is a medium resolution, echelle spectrograph which covers the wavelengths from 0.3 to 2.5 micrometers. We observed plain sky at six different distances (7, 13, 20, 45, 90, and 110 degrees) to the Moon for three different Moon phases (between full and half). Also direct observations of spectrophotometric standard stars were taken at two different airmasses for each night to measure the extinction curve via the Langley method. This is an ideal data set for testing this technique. The underlying assumption is that all components, other than the atmospheric conditions (specifically aerosols and airglow), can be calculated with the model for the given observing parameters. The scattered

Inter-Comparison of ILAS-II Version 1.4 Aerosol Extinction Coefficient at 780 nm with SAGE II, SAGE III, and POAM III Aerosol Data

NASA Technical Reports Server (NTRS)

Saitoh, Naoko; Hayashida, S.; Sugita, T.; Nakajima, H.; Yokota, T.; Hayashi, M.; Shiraishi, K.; Kanzawa, H.; Ejiri, M. K.; Irie, H.;

Lidar measurements of polar stratospheric clouds during the 1989 airborne Arctic stratospheric expedition

NASA Technical Reports Server (NTRS)

Ismail, Syed; Browell, Edward V.

1991-01-01

The Airborne Arctic Stratospheric Expedition (AASE) was conducted during January to February 1989 from the Sola Air Station, Norway. As part of this expedition, the NASA Langley Research Center's multiwavelength airborne lidar system was flown on the NASA Ames Research Center's DC-8 aircraft to measure ozone (O3) and aerosol profiles in the region of the polar vortex. The lidar system simultaneously transmitted laser beams at 1064, 603, 311, and 301.5 nm to measure atmospheric scattering, polarization and O3 profiles. Long range flights were made between Stavanger, Norway, and the North Pole, and between 40 deg W and 20 deg E meridians. Eleven flights were made, each flight lasting an average of 10 hours covering about 8000 km. Atmospheric scattering ratios, aerosol polarizations, and aerosol scattering ratio wavelength dependences were derived from the lidar measurements to altitudes above 27 km. The details of the aerosol scattering properties of lidar observations in the IR, VIS, and UV regions are presented along with correlations with the national meteorological Center's temperature profiles.

Constraining the long-term climate reponse to stratospheric sulfate aerosols injection by the short-term volcanic climate response

NASA Astrophysics Data System (ADS)

Plazzotta, M.; Seferian, R.; Douville, H.; Kravitz, B.; Tilmes, S.; Tjiputra, J.

2016-12-01

Rising greenhouse gas emissions are leading to global warming and climate change, which will have multiple impacts on human society. Geoengineering methods like solar radiation management by stratospheric sulfate aerosols injection (SSA-SRM) aim at treating the symptoms of climate change by reducing the global temperature. Since a real-world testing cannot be implemented, Earth System Models (ESMs) are useful tools to assess the climate impacts of such geoengineering methods. However, coordinated simulations performed with the Geoengineering Model Intercomparison Project (GeoMIP) have shown that climate cooling in response to a continuous injection of 5Tg of SO2 per year under RCP45 future projection (the so-called G4 experiment) differs substantially between ESMs. Here, we employ a volcano analog approach to constrain the climate response in SSA-SRM geoengineering simulations across an ensemble of 10 ESMs. We identify an emergent relationship between the long-term cooling in responses to the mitigation of the clear-sky surface downwelling shortwave radiation (RSDSCS), and the short-term cooling related to the change in RSDSCS during the major tropical volcanic eruptions observed over the historical period (1850-2005). This relationship explains almost 80% of the multi-model spread. Combined with contemporary observations of the latest volcanic eruptions (satellite observations and model reanalyzes), this relationship provides a tight constraint on the climate impacts of SSA-SRM. We estimate that a continuous injection of SO2 aerosols into the stratosphere will reduce the global average temperature of continental land surface by 0.47 K per W m-2, impacting both hydrological and carbon cycles. Compared with the unconstrained ESMs ensemble (range from 0.32 to 0.92 K per W m-2 ), our estimate represents much higher confidence ways to assess the impacts of SSA-SRM on the climate while ruling the most extreme projections of the unconstrained ensemble extremely unlikely.

Post-entry and volcanic contaminant abundances of zinc, copper, selenium, germanium and gallium in stratospheric micrometeorites

NASA Technical Reports Server (NTRS)

Rietmeijer, Frans J. M.

1995-01-01

Some fraction of Zn, Cu, Se, Ga and Ge in chondritic interplanetary dust particles (IDPs) collected in the lower stratosphere between 1981 May and 1984 June has a volcanic origin. I present a method to evaluate the extent of this unavoidable type of stratospheric contamination for individual particles. The mass-normalized abundances for Cu and Ge as a function of mass-normalized stratospheric residence time show their time-integrated stratospheric aerosol abundances. The Zn, Se and Ga abundances show a subdivision into two groups that span approximately two-year periods following the eruptions of the Mount St. Helens (1980 May) and El Chichon (1982 April) volcanoes. Elemental abundances in particles collected at the end of each two-year period indicate low, but not necessarily ambient, volcanic stratospheric abundances. Using this time-integrated baseline, I calculate the straospheric contaminant fractions in nine IDPs and show that Zn, SE and Ga abundances in chondritic IDPs derive in part from stratospheric aerosol contaminants. Post-entry elemental abundances (i.e., the amount that survived atmospheric entry heating of the IDP) show enrichments relative to the CI abundances but in a smaller number of particles than previously suggested.

The reaction probability of N2O5 with sulfuric acid aerosols at stratospheric temperatures and compositions

NASA Technical Reports Server (NTRS)

Fried, Alan; Henry, Bruce E.; Calvert, Jack G.; Mozurkewich, Michael

1994-01-01

We have measured the rate of reaction of N2O5 with H2O on monodisperse, submicrometer H2SO4 particles in a low-temperature flow reactor. Measurements were carried out at temperatures between 225 K and 293 K on aerosol particles with sizes and compositions comparable to those found in the stratosphere. At 273 K, the reaction probability was found to be 0.103 +/- 0.0006, independent of H2SO4 composition from 64 to 81 wt%. At 230 K, the reaction probability increased from 0.077 for compositions near 60% H2SO4 to 0.146 for compositions near 70% H2SO4. Intermediate conditions gave intermediate results except for low reaction probabilities of about 0.045 at 260 K on aerosols with about 78% H2SO4. The reaction probability did not depend on particle size. These results imply that the reaction occurs essentially at the surface of the particle. A simple model for this type of reaction that reproduces the general trends observed is presented. the presence of formaldehyde did not affect the reaction rate.

Geoengineering with stratospheric aerosols: What do we not know after a decade of research?: GEOENGINEERING: WHAT DO WE NOT KNOW?

DOE PAGES

MacMartin, Douglas G.; Kravitz, Ben; Long, Jane C. S.; ...

2016-11-17

Any well-informed future decision on whether and how to deploy solar geoengineering requires balancing the impacts (both intended and unintended) of intervening in the climate against the impacts of not doing so. In spite of the tremendous progress in the last decade, the current state of knowledge remains insufficient to support an assessment of this balance, even for stratospheric aerosol geoengineering (SAG), arguably the best understood (practical) geoengineering method. We then articulate key unknowns associated with SAG, including both climate-science and design questions, as an essential step toward developing a future strategic research program that could address outstanding uncertainties.

The function and response of an improved stratospheric condensation nucleus counter

NASA Technical Reports Server (NTRS)

Wilson, J. C.; Hyun, J. H.; Blackshear, E. D.

1983-01-01

An improved condensation nucleus counter (CNC) for use in the stratosphere is described. The University of Minnesota CNC (UMCNC) has a sequential saturator and condenser and uses n-butyl alcohol as the working fluid. The use of a coaxial saturator flow, with aerosol in the center and filtered, alcohol-laden air around it, speeds the response of this instrument and improves its stability as pressure changes. The counting efficiency has been studied as a function of particle size and pressure. The UMCNC provides an accurate measure of submicron aerosol concentration as long as the number distribution is not dominated by sub-0.02 micron diameter aerosol. The response of the UMCNC is compared with that of other stratospheric condensation nucleus counters, and the results of a (near) comparison with a balloon-borne condensation nucleus counter are presented. The UMCNC has operated 14 times on a NASA U-2 aircraft at altitudes from 8 to 21.5 km.

High Altitude Emissions of Black Carbon Aerosols: Potential Climate Implications

NASA Astrophysics Data System (ADS)

Satheesh, S. K.

2017-12-01

Synthesizing a series of ground-based and airborne measurements of aerosols over the Indian region during summer and pre-monsoon seasons have revealed the persistence of elevated absorbing aerosol layers over most of the Indian region; more than 50% of which located above clouds. Subsequent, in situ measurements of black carbon (BC) using high-altitude balloons, showed surprising layers with high concentrations in the middle and upper troposphere even at an altitude of 8 to 10 kms. Simultaneous measurements of the vertical thermal structure have shown localized warming due to BC absorption leading to large reduction in lapse rate and sharp temperature inversion, which in turn increases the atmospheric stability. This aerosol-induced stable layer is conducive for maintaining the black carbon layer longer at that level, leading thereby to further solar absorption and subsequently triggering dry convection. These observations support the `solar escalator' concept through which absorption-warming-convection cycles lead to self-lifting of BC to upper troposphere or even to lower stratosphere under favorable conditions in a matter of a few days. Employing an on-line regional chemistry transport model (WRF-Chem), incorporating aircraft emissions, it is shown that emissions from high-flying aircrafts as the most likely source of these elevated black carbon layers. These in-situ injected particles, produce significant warming of the thin air in those heights and lift these layers to even upper tropospheric/lower stratospheric heights, aided by the strong monsoonal convection occurring over the region, which are known to overshoot the tropical tropopause leading to injection of tropospheric air mass (along with its constituent aerosols) into the stratosphere, especially during monsoon season when the tropical tropopause layer is known to be thinnest. These simulations are further supported by the CALIPSO space-borne LIDAR derived extinction coefficient profiles. Based on

Climate change and the middle atmosphere. II - The impact of volcanic aerosols

NASA Technical Reports Server (NTRS)

Rind, D.; Balachandran, N. K.; Suozzo, R.

1992-01-01

The response of the middle atmosphere to an increase in stratospheric aerosols, normally associated with increased volcanic activity, is investigated. The aerosols are found to induce a direct stratospheric response, with warming in the tropical lower stratosphere, and cooling at higher latitudes. On the shorter time scales, this radiative effect increases tropospheric static stability at low- to midlatitudes, which reduces the intensity of the Hadley cell and Ferrel cell. There is an associated increase in tropospheric standing wave energy and a decrease in midlatitude west winds, which result in additional wave energy propagation into the stratosphere at lower midlatitudes in both hemispheres. On the longer time scale, a strong hemispheric asymmetry arises. In the Northern Hemisphere eddy energy decreases, as does the middle-atmosphere residual circulation, and widespread stratospheric cooling results. In the Southern Hemisphere, the large increase in sea ice increases the tropospheric latitudinal temperature gradient, leading to increased eddy energy, an increased middle-atmosphere residual circulation, and some high-latitude stratospheric warming.

Subsonic Aircraft Soot: A Tracer Documenting Stratospheric Vertical Mixing and Barriers to Inter-Hemispheric Exchanges

NASA Technical Reports Server (NTRS)

Pueschel, Rudolf F.; Gore, Warren J. (Technical Monitor)

1996-01-01

Pole-to-pole variability of soot aerosol from subsonic aircraft is evidence of two important aspects of stratospheric transport. Vertical transport to 20 km pressure altitude from flight levels near 10-12 km cannot be explained by isentropic mixing. Instead, lofting in the tropics is a possibility. A strong meridional gradient implies that stratospheric soot aerosol residence time is shorter than are mixing times between the hemispheres. Therefore, little if any of exhaust constituents (with residence times similar to that of aircraft soot aerosol), emitted in heavily traveled flight corridors in northern mid-latitudes by a future supersonic fleet, would be transported to the southern hemisphere. However, a significant fraction of NOx could be lofted to altitudes above flight levels where it would dominate ozone depletion.

Impacts of stratospheric sulfate geoengineering on tropospheric ozone

NASA Astrophysics Data System (ADS)

Xia, Lili; Nowack, Peer J.; Tilmes, Simone; Robock, Alan

2017-10-01

A range of solar radiation management (SRM) techniques has been proposed to counter anthropogenic climate change. Here, we examine the potential effects of stratospheric sulfate aerosols and solar insolation reduction on tropospheric ozone and ozone at Earth's surface. Ozone is a key air pollutant, which can produce respiratory diseases and crop damage. Using a version of the Community Earth System Model from the National Center for Atmospheric Research that includes comprehensive tropospheric and stratospheric chemistry, we model both stratospheric sulfur injection and solar irradiance reduction schemes, with the aim of achieving equal levels of surface cooling relative to the Representative Concentration Pathway 6.0 scenario. This allows us to compare the impacts of sulfate aerosols and solar dimming on atmospheric ozone concentrations. Despite nearly identical global mean surface temperatures for the two SRM approaches, solar insolation reduction increases global average surface ozone concentrations, while sulfate injection decreases it. A fundamental difference between the two geoengineering schemes is the importance of heterogeneous reactions in the photochemical ozone balance with larger stratospheric sulfate abundance, resulting in increased ozone depletion in mid- and high latitudes. This reduces the net transport of stratospheric ozone into the troposphere and thus is a key driver of the overall decrease in surface ozone. At the same time, the change in stratospheric ozone alters the tropospheric photochemical environment due to enhanced ultraviolet radiation. A shared factor among both SRM scenarios is decreased chemical ozone loss due to reduced tropospheric humidity. Under insolation reduction, this is the dominant factor giving rise to the global surface ozone increase. Regionally, both surface ozone increases and decreases are found for both scenarios; that is, SRM would affect regions of the world differently in terms of air pollution. In conclusion

Tropical stratospheric water vapor measured by the microwave limb sounder (MLS)

NASA Technical Reports Server (NTRS)

Carr, E. S.; Harwood, R. S.; Mote, P. W.; Peckham, G. E.; Suttie, R. A.; Lahoz, W. A.; O'Neill, A.; Froidevaux, L.; Jarnot, R. F.; Read, W. G.

1995-01-01

The lower stratospheric variability of equatorial water vapor, measured by the Microwave Limb Sounder (MLS), follows an annual cycle modulated by the quasi-biennial oscillation. At levels higher in the stratosphere, water vapor measurements exhibit a semi-annual oscillatory signal with the largest amplitudes at 2.2 and 1hPa. Zonal-mean cross sections of MLS water vapor are consistent with previous satellite measurements from the limb infrared monitor of the stratosphere (LIMS) and the stratospheric Aerosol and Gas Experiment 2 (SAGE 2) instruments in that they show water vapor increasing upwards and the polewards from a well defined minimum in the tropics. The minimum values vary in height between the retrieved 46 and 22hPa pressure levels.

Homogenous Surface Nucleation of Solid Polar Stratospheric Cloud Particles

NASA Technical Reports Server (NTRS)

Tabazadeh, A.; Hamill, P.; Salcedo, D.; Gore, Warren J. (Technical Monitor)

2002-01-01

A general surface nucleation rate theory is presented for the homogeneous freezing of crystalline germs on the surfaces of aqueous particles. While nucleation rates in a standard classical homogeneous freezing rate theory scale with volume, the rates in a surface-based theory scale with surface area. The theory is used to convert volume-based information on laboratory freezing rates (in units of cu cm, seconds) of nitric acid trihydrate (NAT) and nitric acid dihydrate (NAD) aerosols into surface-based values (in units of sq cm, seconds). We show that a surface-based model is capable of reproducing measured nucleation rates of NAT and NAD aerosols from concentrated aqueous HNO3 solutions in the temperature range of 165 to 205 K. Laboratory measured nucleation rates are used to derive free energies for NAT and NAD germ formation in the stratosphere. NAD germ free energies range from about 23 to 26 kcal mole, allowing for fast and efficient homogeneous NAD particle production in the stratosphere. However, NAT germ formation energies are large (greater than 26 kcal mole) enough to prevent efficient NAT particle production in the stratosphere. We show that the atmospheric NAD particle production rates based on the surface rate theory are roughly 2 orders of magnitude larger than those obtained from a standard volume-based rate theory. Atmospheric volume and surface production of NAD particles will nearly cease in the stratosphere when denitrification in the air exceeds 40 and 78%, respectively. We show that a surface-based (volume-based) homogeneous freezing rate theory gives particle production rates, which are (not) consistent with both laboratory and atmospheric data on the nucleation of solid polar stratospheric cloud particles.

Evidence for slowdown in stratospheric ozone loss: First stage of ozone recovery

NASA Technical Reports Server (NTRS)

Newchurch, M. J.; Yang, Eun-Su; Cunnold, D. M.; Reinsel, C.; Zawodny, J. M.; Russell, James M., III

2003-01-01

Global ozone trends derived from the Stratospheric Aerosol and Gas Experiment I and II (SAGE I/II) combined with the more recent Halogen Occultation Experiment (HALOE) observations provide evidence of a slowdown in stratospheric ozone losses since 1997. This evidence is quantified by the cumulative sum of residual differences from the predicted linear trend. The cumulative residuals indicate that the rate of ozone loss at 35- 45 km altitudes globally has diminished. These changes in loss rates are consistent with the slowdown of total stratospheric chlorine increases characterized by HALOE HCI measurements. These changes in the ozone loss rates in the upper stratosphere are significant and constitute the first stage of a recovery of the ozone layer.

Geochemical behaviour of the Tunisian background aerosols in Sirocco wind circulations

NASA Astrophysics Data System (ADS)

Azri, Chafai; Abida, Habib; Medhioub, Khaled

2009-05-01

This study examines spatial and time evolutions of the principal constituents of the Tunisian background aerosols under Sirocco wind circulations. Aerosols coming from the Sahara Desert were found to be loaded with particulate matter, especially silicon. The aerosols were shown to have varying geochemical behaviour along the "South-North" displacement of the Saharan plumes, depending on the wind flow characteristics, geomorphologic features and the nature of soils swept by the wind. In the south and the center part of the country, the transfer of aerosol constituents to the soil (by gravity and/or impaction) was probably predominated by localized enrichment phenomena. The latter are reinforced by the effect of turbulent winds over bare soils, wind wakes and probably selective disintegration, especially in the vicinity of the geomorphologic features of central Tunisia. These relatively high features, extending over important distances, appear to be of paramount importance for the phenomena of redistribution of aerosol constituents even during periods without Sirocco wind circulations. In the northern section of the country, aerosol constituent concentrations dropped to almost 50%, in spite of the abundance of localized turbulent winds. This may be explained by the effect of forests and the relatively dense vegetation cover, which clearly reinforces the transfer phenomena to the soil and the attenuate of dust entrainment.

Effects of Convective Transport on the Budget of Amazonian Aerosol under Background Conditions

NASA Astrophysics Data System (ADS)

Wang, J.; Krejci, R.; Giangrande, S. E.; Kuang, C.; Barbosa, H. M.; Brito, J.; Carbone, S.; Chi, X.; Comstock, J. M.; Ditas, F.; Lavric, J. V.; Manninen, H. E.; Mei, F.; Moran, D.; Pöhlker, C.; Pöhlker, M. L.; Saturno, J.; Schmid, B.; Souza, R. A. F. D.; Springston, S. R.; Tomlinson, J. M.; Toto, T.; Walter, D.; Wimmer, D.; Smith, J. N.; Machado, L.; Artaxo, P.; Andreae, M. O.; Martin, S. T.

2016-12-01

Aerosol particles can strongly influence the radiative properties of clouds, and they represent one of the largest uncertainties in computer simulations of climate change. The large uncertainty is in large part due to a poor understanding of processes under natural conditions, which serves as the baseline to measure change against. Understanding the processes under natural conditions is critical for a reliable assessment and quantification of ongoing and future climate change. The Amazon rainforest is one of the few continental regions where aerosol particles and their precursors can be studied under near-natural conditions. Here we examine the aerosol number and CCN budget under background conditions in the Amazon basin using data collected during the Observations and Modeling of the Green Ocean Amazon (GoAmazon 2014/5) campaign, which took place from January 2014 to December 2015 near Manaus, Brazil. The aerosol size spectrum was observed at the Amazon Tall Tower Observatory (ATTO), 150 km upwind of Manaus, and its variation with convection and precipitation during the wet season is presented. Air masses arriving at the ATTO during the wet season are typically brought by the northeasterly trade winds and travel across at least 1000 km of undeveloped tropical rainforest, therefore are generally clean. Also shown are vertical profiles of aerosol observed onboard the DOE Gulfstream-1 research aircraft. The impact of convective transport on the budget of boundary layer aerosol and CCN under the background conditions is discussed.

Ozone and aerosol distributions measured by airborne lidar during the 1988 Arctic Boundary Layer Experiment

NASA Technical Reports Server (NTRS)

Browell, Edward V.; Butler, Carolyn F.; Kooi, Susan A.

1991-01-01

Consideration is given to O3 and aerosol distributions measured from an aircraft using a DIAL system in order to study the sources and sinks of gases and aerosols over the tundra regions of Alaska during summer 1988. The tropospheric O3 budget over the Arctic was found to be strongly influenced by stratospheric intrusions. Regions of low aerosol scattering and enhanced O3 mixing ratios were usually correlated with descending air from the upper troposphere or lower stratosphere.

An experimental study of growth and phase change of polar stratospheric cloud particles

NASA Technical Reports Server (NTRS)

Hallett, John; Teets, Edward

1992-01-01

This report describes the progress made on understanding phase changes related to solutions which may comprise Polar Stratospheric Clouds. In particular, it is concerned with techniques for investigating specific classes of metastability and phase change which may be important not only in Polar Stratospheric Clouds but in all atmospheric aerosols in general. While the lower level atmospheric aerosol consists of mixtures of (NH4)(SO4)2, NH4HSO4, NaCl among others, there is evidence that aerosol at PSC levels is composed of acid aerosol, either injected from volcanic events (such as Pinatubo) or having diffused upward from the lower atmosphere. In particular, sulfuric acid and nitric acid are known to occur at PSC levels, and are suspected of catalyzing ozone destruction reactions by adsorption on surfaces of crystallized particles. The present study has centered on two approaches: (1) the extent of supercooling (with respect to ice) and supersaturation (with respect to hydrate) and the nature of crystal growth in acid solutions of specific molality; and (2) the nature of growth from the vapor of HNO3 - H2O crystals both on a substrate and on a pre-existing aerosol.

Influence of Tropospheric SO2 Emissions on Particle Formation and the Stratospheric Humidity

NASA Technical Reports Server (NTRS)

Notholt, J.; Luo, B. P.; Fueglistaler, S.; Weisenstein, D.; Rex, M.; Lawrence, M. G.; Bingemer, H.; Wohltmann, I.; Corti, T.; Warneke, T.;

Orbiting lidar simulations. I - Aerosol and cloud measurements by an independent-wavelength technique

NASA Technical Reports Server (NTRS)

Russell, P. B.; Morley, B. M.; Livingston, J. M.; Grams, G. W.; Patterson, E. M.

1982-01-01

Aerosol and cloud measurements have been simulated for a Space Shuttle lidar. Expected errors - in signal, transmission, density, and calibration - are calculated algebraically and checked by simulating measurements and retrievals using random-number generators. By day, vertical structure is retrieved for tenuous clouds, Saharan aerosols, and boundary layer aerosols (at 0.53 and 1.06 micron) as well as strong volcanic stratospheric aerosols (at 0.53 micron). By night, all these constituents are retrieved plus upper tropospheric and stratospheric aerosols (at 1.06 micron), mesospheric aerosols (at 0.53 micron), and noctilucent clouds (at 1.06 and 0.53 micron). The vertical resolution was 0.1-0.5 km in the troposphere, 0.5-2.0 km above, except 0.25-1.0 km in the mesospheric cloud and aerosol layers; horizontal resolution was 100-2000 km.

Asian Summer Monsoon Pollutes the Northern Hemispheric Stratosphere

NASA Astrophysics Data System (ADS)

Yu, P.; Gao, R. S.; Rosenlof, K. H.; Telg, H.; Liu, S.; Zhixuan, B.; Bian, J.

2016-12-01

An enhanced aerosol layer near the tropopause over Asia during the period of the Asian summer monsoon (ASM) was recently identified by satellites. Previous modeling studies suggest the layer is largely composed of organics and sulfate. However its source, detailed distribution, and climate implications are presently not well understood. To address this issue, in-situ measurements of aerosol size distribution during the 2015 ASM were made from Kunming, China. These showed a robust aerosol enhancement up to 2 km above the tropopause. We use a global climate model coupled with the Community Aerosol and Radiation Model for Atmospheres (CARMA) to show that these aerosol particles are transported to the entire 10°N - 50°N latitude band in the lower stratosphere. These transported particles, originally formed in the region of the ASM anticyclone, account for a significant fraction of total aerosol mass in the 10°N - 50°N latitude band between 16 to 20 km.

Perspectives on NO, NOy, and fine aerosol sources and variability during SONEX

NASA Astrophysics Data System (ADS)

Thompson, Anne M.; Sparling, Lynn C.; Kondo, Yutaka; Anderson, Bruce E.; Gregory, Gerald L.; Sachse, Glen W.

Distributions of upper tropospheric tracer data on each of the 14 science flights of SONEX (SASS [Subsonics Assessment] Ozone and Nitrogen Oxides Experiment) provide a statistical overview of NO, NOy and fine aerosol variability during SONEX (an aircraft mission conducted in October and November 1997). The wide range of variability of NO from all sources provides a perspective on the aircraft perturbation. Background distributions of NOy are somewhat elevated inside flight corridors relative to outside; fine aerosol and NO/NOy in and out of corridors are similar. The potential vorticity of air sampled during SONEX is low relative to the NAFC (North Atlantic Flight Corridor) as a whole, due either to advection of lower latitude air into the corridor or biases in sampling to avoid the stratosphere. High NO/NOy (>0.4) from fresh lightning and aircraft sources was usually associated with pv much lower than the NAFC as a whole. Air masses identified as tropospheric by a low ozone criterion nevertheless have high pv, a marker for stratospheric air. Thus, stratospheric and surface sources also contribute to overall variability. A statistically robust assessment of the relative aircraft NO contribution during SONEX, based on data alone, is unlikely, given the mixture of other NO sources within which the aircraft signal is embedded. This underscores the need for more data and modeling studies.

Sensitivity of the radiative forcing by stratospheric sulfur geoengineering to the amount and strategy of the SO2injection studied with the LMDZ-S3A model

NASA Astrophysics Data System (ADS)

Kleinschmitt, Christoph; Boucher, Olivier; Platt, Ulrich

2018-02-01

The enhancement of the stratospheric sulfate aerosol layer has been proposed as a method of geoengineering to abate global warming. Previous modelling studies found that stratospheric aerosol geoengineering (SAG) could effectively compensate for the warming by greenhouse gases on the global scale, but also that the achievable cooling effect per sulfur mass unit, i.e. the forcing efficiency, decreases with increasing injection rate. In this study we use the atmospheric general circulation model LMDZ with the sectional aerosol module S3A to determine how the forcing efficiency depends on the injected amount of SO2, the injection height, and the spatio-temporal pattern of injection. We find that the forcing efficiency may decrease more drastically for larger SO2 injections than previously estimated. As a result, the net instantaneous radiative forcing does not exceed the limit of -2 W m-2 for continuous equatorial SO2 injections and it decreases (in absolute value) for injection rates larger than 20 Tg S yr-1. In contrast to other studies, the net radiative forcing in our experiments is fairly constant with injection height (in a range 17 to 23 km) for a given amount of SO2 injected. Also, spreading the SO2 injections between 30° S and 30° N or injecting only seasonally from varying latitudes does not result in a significantly larger (i.e. more negative) radiative forcing. Other key characteristics of our simulations include a consequent stratospheric heating, caused by the absorption of solar and infrared radiation by the aerosol, and changes in stratospheric dynamics, with a collapse of the quasi-biennial oscillation at larger injection rates, which has impacts on the resulting spatial aerosol distribution, size, and optical properties. But it has to be noted that the complexity and uncertainty of stratospheric processes cause considerable disagreement among different modelling studies of stratospheric aerosol geoengineering. This may be addressed through detailed

Condensation nuclei measurement in the stratosphere for the NASA ACE program

NASA Astrophysics Data System (ADS)

Wilson, James Charles

1994-11-01

A condensation nucleus counter which operated at stratospheric pressures was developed, designed, and constructed. It was calibrated in the laboratory. Its response as a function of particle size and concentration was reported. This was the first time that the response of such an instrument was verified in the laboratory. An inlet was constructed which provided near isokinetic sampling. The resulting instrument, the U-2 CNC, was deployed on NASA U-2 aircraft in the study of the climatic effects of aerosol. These studies occurred in March, April, May, July, November, and December of 1992 and in April, May, June, and December of 1983. The U-2 CNC was used in the study of the aerosol cloud resulting from the eruption of El Chichon. It permitted the observation of new particle formation in the stratosphere.

Condensation nuclei measurement in the stratosphere for the NASA ACE program

NASA Technical Reports Server (NTRS)

Wilson, James Charles

1994-01-01

A condensation nucleus counter which operated at stratospheric pressures was developed, designed, and constructed. It was calibrated in the laboratory. Its response as a function of particle size and concentration was reported. This was the first time that the response of such an instrument was verified in the laboratory. An inlet was constructed which provided near isokinetic sampling. The resulting instrument, the U-2 CNC, was deployed on NASA U-2 aircraft in the study of the climatic effects of aerosol. These studies occurred in March, April, May, July, November, and December of 1992 and in April, May, June, and December of 1983. The U-2 CNC was used in the study of the aerosol cloud resulting from the eruption of El Chichon. It permitted the observation of new particle formation in the stratosphere.

A comparison of Solar Mesosphere Explorer and Stratosphere Aerosol and Gas Experiment II ozone densities near the stratopause

NASA Technical Reports Server (NTRS)

Rusch, D. W.; Clancy, R. T.; Mccormick, M. P.; Zawodny, J. M.

1990-01-01

Ozone measurements made by the SME UV Spectrometer and the Stratosphere Aerosol and Gas Experiment II (SAGE II) spectometer are compared at 1.0 mbar for the time period from October 1984 to December 1986, using a model of the diurnal variation of ozone to correct for the difference in local times of the two measurements. The absolute values of the ozone mixing ratio measured by the two spectrometers were found to agree to better than 5 percent, with no significant divergence between the instruments. It is concluded that, since the SAGE II data are not dependent on the absolute calibration of the instrument, these data can be used as time-dependent 'ground truth' measurements for comparisons with other instruments.

Easy Volcanic Aerosol

NASA Astrophysics Data System (ADS)

Toohey, Matthew; Stevens, Bjorn; Schmidt, Hauke; Timmreck, Claudia

2016-04-01

Radiative forcing by stratospheric sulfate aerosol of volcanic origin is one of the strongest drivers of natural climate variability. Transient model simulations attempting to match observed climate variability, such as the CMIP historical simulations, rely on volcanic forcing reconstructions based on observations of a small sample of recent eruptions and coarse proxy data for eruptions before the satellite era. Volcanic forcing data sets used in CMIP5 were provided either in terms of optical properties, or in terms of sulfate aerosol mass, leading to significant inter-model spread in the actual volcanic radiative forcing produced by models and in their resulting climate responses. It remains therefore unclear to what degree inter-model spread in response to volcanic forcing represents model differences or variations in the forcing. In order to isolate model differences, Easy Volcanic Aerosol (EVA) provides an analytic representation of volcanic stratospheric aerosol forcing, based on available observations and aerosol model results, prescribing the aerosol's radiative properties and primary modes of spatial and temporal variability. In contrast to regriddings of observational data, EVA allows for the production of physically consistent forcing for historic and hypothetical eruptions of varying magnitude, source latitude, and season. Within CMIP6, EVA will be used to reconstruct volcanic forcing over the past 2000 years for use in the Paleo-Modeling Intercomparison Project (PMIP), and will provide forcing sets for VolMIP experiments aiming to quantify model uncertainty in the response to volcanic forcing. Here, the functional form of EVA will be introduced, along with illustrative examples including the EVA-based reconstruction of volcanic forcing over the historical period, and that of the 1815 Tambora eruption.

Forecasting the climate response to volcanic eruptions: prediction skill related to stratospheric aerosol forcing

NASA Astrophysics Data System (ADS)

Ménégoz, M.; Bilbao, R.; Bellprat, O.; Guemas, V.; Doblas-Reyes, F. J.

2018-06-01

The last major volcanic eruptions, the Agung in 1963, El Chichon in 1982 and Pinatubo in 1991, were each associated with a cooling of the troposphere that has been observed over large continental areas and over the Western Pacific, the Indian Ocean and the Southern Atlantic. Simultaneously, Eastern tropical Pacific temperatures increased due to prevailing El Niño conditions. Here we show that the pattern of these near-surface temperature anomalies is partly reproduced with decadal simulations of the EC-Earth model initialised with climate observations and forced with an estimate of the observed volcanic aerosol optical thickness. Sensitivity experiments highlight a cooling induced by the volcanic forcing, whereas El Niño events following the eruptions would have occurred even without volcanic eruptions. Focusing on the period 1961–2001, the main source of skill of this decadal forecast system during the first 2 years is related to the initialisation of the model. The contribution of the initialisation to the skill becomes smaller than the contribution of the volcanic forcing after two years, the latter being substantial in the Western Pacific, the Indian Ocean and the Western Atlantic. Two simple protocols for real time forecasts are investigated: using the forcing of a past volcanic eruption to simulate the forcing of a new one, and applying a two-year exponential decay to the initial stratospheric aerosol load observed at the beginning of the forecast. This second protocol applied in retrospective forecasts allows a partial reproduction of the skill attained with observed forcing.

Volcanic Aerosol Radiative Properties

NASA Technical Reports Server (NTRS)

Lacis, Andrew

2015-01-01

Large sporadic volcanic eruptions inject large amounts of sulfur bearing gases into the stratosphere which then get photochemically converted to sulfuric acid aerosol droplets that exert a radiative cooling effect on the global climate system lasting for several years.

Initial operation and checkout of stratospheric aerosol gas experiment and Meteor-3M satellite

NASA Astrophysics Data System (ADS)

Habib, Shahid; Makridenko, Leonid; Chu, William P.; Salikhov, Rashid; Moore, Alvah S., Jr.; Trepte, Charles R.; Cisewski, Michael S.

2003-04-01

Under a joint agreement between the National Aeronautics and Space Agency (NASA) and the Russian Aviation and Space Agency (RASA), the Stratospheric Aerosol Gas Experiment III (SAGE III) instrument was launched in low earth orbit on December 10, 2001 aboard the Russian Meteor-3M(1) satellite from the Baikonur Cosmodrome. SAGE III is a spectrometer that measures attenuated radiation in the 282 nm to 1550 nm wavelength range to obtain the vertical profiles of ozone, aerosols, and other chemical species that are critical in studying the trends for the global climate change phenomena. This instrument version is more advanced than any of the previous versions and has more spectral bands, elaborate data gathering and storage, and intelligent terrestrial software. There are a number of Russian scientific instruments aboard the Meteor satellite in addition to the SAGE III instrument. These instruments deal with land imaging and biomass changes, hydro-meteorological monitoring, and helio-geophysical research. This mission was under development for over a period of six years and offered a number of unique technical and program management challenges for both Agencies. SAGE III has a long space heritage, and four earlier versions of this instrument have flown in space for nearly two decades now. In fact, SAGE II, the fourth instrument, is still flying in space on NASA's Earth Radiation Budget Satellite (ERBS), and has been providing important atmospheric data over the last 18 years. It has provided vital ozone and aerosol data in the mid latitudes and has contributed vastly in ozone depletion research. Ball Aerospace built the instrument under Langley Research Center's (LaRC) management. This paper presents the process and approach deployed by the SAGE III and the Meteor teams in performing the initial on-orbit checkout. It further documents a number of early science results obtained by deploying low risk, carefully coordinated procedures in resolving the serious operational

Data pre-processing: Stratospheric aerosol perturbing effect on the remote sensing of vegetation: Correction method for the composite NDVI after the Pinatubo eruption

NASA Technical Reports Server (NTRS)

Vermote, E.; Elsaleous, N.; Kaufman, Y. J.; Dutton, E.

1994-01-01

An operational stratospheric correction scheme used after the Mount Pinatubo (Phillipines) eruption (Jun. 1991) is presented. The stratospheric aerosol distribution is assumed to be only variable with latitude. Each 9 days the latitudinal distribution of the optical thickness is computed by inverting radiances observed in the NOAA AVHRR channel 1 (0.63 micrometers) and channel 2 (0.83 micrometers) over the Pacific Ocean. This radiance data set is used to check the validity of model used for inversion by checking consistency of the optical thickness deduced from each channel as well as optical thickness deduced from different scattering angles. Using the optical thickness profile previously computed and radiative transfer code assuming Lambertian boundary condition, each pixel of channel 1 and 2 are corrected prior to computation of NDVI (Normalized Difference Vegetation Index). Comparison between corrected, non corrected, and years prior to Pinatubo eruption (1989 to 1990) NDVI composite, shows the necessity and the accuracy of the operational correction scheme.

Simultaneous Observations fo Polar Stratospheric Clouds and HNO3 over Scandinavia in January, 1992

NASA Technical Reports Server (NTRS)

Massie, S. T.; Santee, M. L.; Read, W. G.; Grainger, R. G.; Lambert, A.; Mergenthaler, J. L.; Dye, J. E.; Baumbardner, D.; Randel, W. J.; Tabazadeh, A.;

Balloon-Borne Measurements of Total Reactive Nitrogen, Nitric Acid, and Aerosol in the Cold Arctic Stratosphere

NASA Technical Reports Server (NTRS)

Kondo, Y.; Aimedieu, P.; Matthews, W. A.; Fahey, D. W.; Murcray, D. G.; Hofmann, D. J.; Johnston, P. V.; Iwasaka, Y.; Iwata, A.; Sheldon, W. R.

1990-01-01

Total reactive nitrogen (NO(Y)) between 15 and 29 km was measured for the first time on board a balloon within the Arctic cold vortex. Observations of HNO3, aerosol, and ozone were made by instruments on the same balloon gondola which was launched from Esrange, Sweden (68 deg N, 20 deg E) on January 23, 1989. The NO(y) mixing ratio was observed to increase very rapidly from 6 ppbv at 18 km altitude to a maximum of 21 ppbv at 21 km, forming a sharp layer with a thickness of about 2 km. A minimum in the NO(y) mixing ratio of 5 ppbv was found at 27 km. The measured HNO3 profile shows broad similarities to that of NO(y). This observation, together with the observed very low column amount of NO2, shows that NO(x) had been almost totally converted to HNO3, and that NO(y) was composed mainly of HNO3. The enhanced aerosol concentration between 19 and 22 km suggests that the maximum abundance of HNO3 trapped in the form of nitric acid trihydrate (NAT) was about 6 ppbv at 21 km. The sampled air parcels were highly supersaturated with respect to NAT. Although extensive denitrification throughout the stratosphere did not prevail, an indication of denitrification was found at altitudes of 27 and 22 km, and between 18 and 15 km.

Estimation of polar stratospheric cloud infrared extinction climatology using visible satellite observations

NASA Technical Reports Server (NTRS)

Pitts, Michael C.; Thomason, Larry W.

1995-01-01

Polar stratospheric clouds (PSC's) provide surfaces for heterogeneous processes which can dramatically alter the normal partitioning of odd nitrogen and chlorine families in the winter polar stratospheres, setting up conditions for significant ozone depletion as manifested in the springtime Antarctic ozone hole. The spatial and temporal distribution of PSC's is important for parameterizing PSC occurrence in multidimensional photochemical models whose use is essential for fully understanding observed Antarctic ozone losses as well as for accessing the possibility of a similar phemonenon occurring in the future in the Arctic. The Stratospheric Aerosol Measurement (SAM) 2 sensor, a single-channel (1mu m) photometer launched into a Sun-synchronous orbit aboard the Nimbus 7 satellite in October 1978, provided a unique database to establish the climatology of PSC's. Poole and Pitts (1994) used the record of high-latitude aerosol extinction obtained by SAM II from 1979-1989 to establish the climatology of PSC occurrences in the Arctic and Antarctic. Unfortunately, little information about PSC composition or type was detectable from the single-wavelength SAM II data.

Carbon Isotopic Measurements and Aerosol Optical Determinations during CARES: Indications of the Importance of Background Biogenic Aerosols

NASA Astrophysics Data System (ADS)

Gaffney, J. S.; Marley, N. A.; Begum, M.; Sturchio, N. C.; Guilderson, T. P.

2011-12-01

High volume size-fractionated aerosol samples were obtained in Cool, CA during the Carbonaceous Aerosol and Radiative Effects Study (CARES) in June of 2010. This site was chosen to study the regional impacts of carbonaceous aerosols originating from the Sacramento area. Samples were collected for 6 to 24 hour time periods on quartz fiber filters by using slotted impactors to allow for collection of sample size cuts above and below one micron. Both total carbon content and carbon isotopic composition, including 13C/12C and 14C, were determined on the samples. In addition, Ångstrom absorption exponents (AAEs) were determined for the region of 300-900 nm on the sub-micron size cut by using state of the art diffuse reflectance UV-visible spectroscopy with integrating sphere technology. The overall carbonaceous aerosol loadings were found to be quite low and relatively constant during the study, suggesting that most of the aerosols at the site were locally formed background aerosols. The 14C data is consistent with a substantial fraction (~80 %) being from modern carbon sources and 13C/12C results indicate that the carbon source was from C-3 plants. This is consistent with a significant fraction of the aerosols in the area arising from secondary formation from biogenic precursor emissions from trees, most likely mono- and sesquiterpenes. These results are compared to past results obtained in Mexico City and discussed in terms of the potential importance of biogenic emissions to UV absorbing aerosols as these are anticipated to increase with climate change. This work was supported by the Office of Science (BER), U.S. Department of Energy, Grant No. DE-FG02-07ER64328 and Grant No. DE-FG02-07-ER64329 as part of the Atmospheric Systems Research program.

Impacts of Stratospheric Sulfate Geoengineering on PM2.5

NASA Astrophysics Data System (ADS)

Robock, A.; Xia, L.; Tilmes, S.; Mills, M. J.; Richter, J.; Kravitz, B.; MacMartin, D.

2017-12-01

Particulate matter (PM) includes sulfate, nitrate, organic carbon, elemental carbon, soil dust, and sea salt. The first four components are mostly present near the ground as fine particulate matter with a diameter less than 2.5 µm (PM2.5), and these are of the most concern for human health. PM is efficiently scavenged by precipitation, which is its main atmospheric sink. Here we examine the impact of stratospheric climate engineering on this important pollutant and health risk, taking advantage of two sets of climate model simulations conducted at the National Center for Atmospheric Research. We use the full tropospheric and stratospheric chemistry version of the Community Earth System Model - Community Atmospheric Model 4 (CESM CAM4-chem) with a horizontal resolution of 0.9° x 1.25° lat-lon to simulate a stratospheric sulfate injection climate intervention of 8 Tg SO2 yr-1 combined with an RCP6.0 global warming forcing, the G4 Specified Stratospheric Aerosol (G4SSA) scenario. We also analyze the output from a 20-member ensemble of Community Earth System Model, version 1 with the Whole Atmosphere Community Climate Model as its atmospheric component (CESM1(WACCM)) simulations, also at 0.9° x 1.25° lat-lon resolution, with sulfur dioxide injection at 15°N, 15°S, 30°N, and 30°S varying in time to balance RCP8.5 forcing. While the CESM CAM4-chem model has full tropospheric and stratospheric chemistry, CESM1(WACCM) has an internally generated quasi-biennial oscillation and a comprehensive tropospheric and stratospheric sulfate aerosol treatment, but only stratospheric chemistry. For G4SSA, there are a global temperature reduction of 0.8 K and global averaged precipitation decrease of 3% relative to RCP6.0. The global averaged surface PM2.5 reduces about 1% compared with RCP6.0, mainly over Eurasian and East Asian regions in Northern Hemisphere winter. The PM2.5 concentration change is a combination of effects from tropospheric chemistry and precipitation

Pyro-cumulonimbus injection of smoke to the stratosphere: Observations and impact of a super blowup in northwestern Canada on 3-4 August 1998

NASA Astrophysics Data System (ADS)

Fromm, Michael; Bevilacqua, Richard; Servranckx, René; Rosen, James; Thayer, Jeffrey P.; Herman, Jay; Larko, David

2005-04-01

We report observations and analysis of a pyro-cumulonimbus event in the midst of a boreal forest fire blowup in Northwest Territories Canada, near Norman Wells, on 3-4 August 1998. We find that this blowup caused a five-fold increase in lower stratospheric aerosol burden, as well as multiple reports of anomalous enhancements of tropospheric gases and aerosols across Europe 1 week later. Our observations come from solar occultation satellites (POAM III and SAGE II), nadir imagers (GOES, AVHRR, SeaWiFS, DMSP), TOMS, lidar, and backscattersonde. First, we provide a detailed analysis of the 3 August eruption of extreme pyro-convection. This includes identifying the specific pyro-cumulonimbus cells that caused the lower stratospheric aerosol injection, and a meteorological analysis. Next, we characterize the altitude, composition, and opacity of the post-convection smoke plume on 4-7 August. Finally, the stratospheric impact of this injection is analyzed. Satellite images reveal two noteworthy pyro-cumulonimbus phenomena: (1) an active-convection cloud top containing enough smoke to visibly alter the reflectivity of the cloud anvil in the Upper Troposphere Lower Stratosphere (UTLS) and (2) a smoke plume, that endured for at least 2 hours, atop an anvil. The smoke pall deposited by the Norman Wells pyro-convection was a very large, optically dense, UTLS-level plume on 4 August that exhibited a mesoscale cyclonic circulation. An analysis of plume color/texture from SeaWiFS data, aerosol index, and brightness temperature establishes the extreme altitude and "pure" smoke composition of this unique plume. We show what we believe to be a first-ever measurement of strongly enhanced ozone in the lower stratosphere mingled with smoke layers. We conclude that two to four extreme pyro-thunderstorms near Norman Wells created a smoke injection of hemispheric scope that substantially increased stratospheric optical depth, transported aerosols 7 km above the tropopause (above ˜430 K

Detection of deep stratospheric intrusions by cosmogenic 35S

PubMed Central

Su, Lin; Shaheen, Robina; Fung, Jimmy C. H.; Thiemens, Mark H.

2016-01-01

The extent to which stratospheric intrusions on synoptic scales influence the tropospheric ozone (O3) levels remains poorly understood, because quantitative detection of stratospheric air has been challenging. Cosmogenic 35S mainly produced in the stratosphere has the potential to identify stratospheric air masses at ground level, but this approach has not yet been unambiguously shown. Here, we report unusually high 35S concentrations (7,390 atoms m−3; ∼16 times greater than annual average) in fine sulfate aerosols (aerodynamic diameter less than 0.95 µm) collected at a coastal site in southern California on May 3, 2014, when ground-level O3 mixing ratios at air quality monitoring stations across southern California (43 of 85) exceeded the recently revised US National Ambient Air Quality Standard (daily maximum 8-h average: 70 parts per billion by volume). The stratospheric origin of the significantly enhanced 35S level is supported by in situ measurements of air pollutants and meteorological variables, satellite observations, meteorological analysis, and box model calculations. The deep stratospheric intrusion event was driven by the coupling between midlatitude cyclones and Santa Ana winds, and it was responsible for the regional O3 pollution episode. These results provide direct field-based evidence that 35S is an additional sensitive and unambiguous tracer in detecting stratospheric air in the boundary layer and offer the potential for resolving the stratospheric influences on the tropospheric O3 level. PMID:27655890

Chemical composition of the atmospheric aerosol in the troposphere over the Hudson Bay lowlands and Quebec-Labrador regions of Canada

NASA Technical Reports Server (NTRS)

Gorzelska, K.; Talbot, R. W.; Klemm, K.; Lefer, B.; Klemm, O.; Gregory, G. L.; Anderson, B.; Barrie, L. A.

1994-01-01

Atmospheric aerosols were collected in the boundary layer and free troposphere over continental and coastal subarctic regions of Canada during the July - August 1990 joint U.S.-Canadian Arctic Boundary Layer Expedition (ABLE) 3B/Northern Wetlands Study (NOWES). The samples were analyzed for the following water soluble species: sulfate, nitrate, ammonium, potassium, sodium, chloride, oxalate, methylsulfonate, and total amine nitrogen. Ammonium and sulfate were the major water soluble components of these aerosols. The nearly neutral (overall) chemical composition of summertime aerosol particles contrasts their strongly acidic wintertime composition. Aerosol samples were separated into several air mass categories and characterized in terms of chemical composition, associated mixing ratios of gaseous compounds, and meteorological parameters. The fundamental category represented particles associated with 'background' air masses. The summertime atmospheric aerosols in background air over the North American subarctic and Arctic regions were characterized by relatively small and spatially uniform mixing ratios of the measured species. These aerosol particles were aged to the extent that they had lost their primary source signature. The chemical profile of the background air aerosols was frequently modified by additions from biomass fire plumes, aged tropical marine air, and intrusions of upper tropospheric/lower stratospheric air. Aerosols in boundary layer background air over the boreal forest region of Quebec-Labrador had significantly larger mixing ratios of ammonium and sulfate relative to the Hudson Bay region. This may reflect infiltration of anthropogenic pollution or be due to natural emissions from this region.

Laboratory chemistry and stratospheric clouds

NASA Technical Reports Server (NTRS)

Molina, Mario J.

1989-01-01

Results are presented from laboratory experiments on the chemistry of ice particles to study the role of HCl and ClONO2 from CFCs in stratospheric ozone depletion over Antarctica. It is found that gaseous HCl is scavenged with high efficiency by the ice and the gas phase chlorine nitrate may react with the HCL-containing ice to produce Cl2. Also, consideration is given ot the behavior of solid nitric acid trihydrate and sulfuric acid aerosols.

Variability in regional background aerosols within the Mediterranean

NASA Astrophysics Data System (ADS)

Querol, X.; Alastuey, A.; Pey, J.; Cusack, M.; Pérez, N.; Mihalopoulos, N.; Theodosi, C.; Gerasopoulos, E.; Kubilay, N.; Koçak, M.

2009-04-01

The main objective of this study is the identification of major factors controlling levels and chemical composition of aerosols in the regional background (RB) along the Mediterranean Basin (MB). To this end, data on PM levels and speciation from Montseny (MSY, Northeastern Spain), Finokalia (FKL, Southern Greece) and Erdemli (ERL, Southern Turkey) for the period 2001 to 2008 are evaluated. Important differences on PM levels and composition are evident when comparing the Western and Eastern MBs. The results manifest W-E and N-S PM10 and PM2.5 gradients along the MB, attributed to the higher frequency and intensity of African dust outbreaks in the EMB, while for PM1 very similar levels are encountered. PM in the EMB is characterized by higher levels of crustal material and sulphate as compared to WMB (and central European sites), however, RB nitrate and OC+EC levels are relatively constant across the Mediterranean and lower than other European sites. Marked seasonal trends are evidenced for PM levels, nitrate (WMB), ammonium and sulphate. Also relatively higher levels of V and Ni (WMB) are measured in the Mediterranean basin, probably as a consequence of high emissions from fuel-oil combustion (power generation, industrial and shipping emissions). Enhanced sulphate levels in EMB compared to WMB were measured. The high levels of sulphate in the EMB may deplete the available gas-phase NH3 so that little ammonium nitrate can form due to the low NH3 levels. This study illustrates the existence of three very important features within the Mediterranean that need to be accounted for when modeling climate effects of aerosols in the area, namely: (a) the increasing gradient of dust from WMB to EMB; (b) the change of hygroscopic behavior of mineral aerosols (dust) via nitration and sulphation; and (c) the abundance of highly hygroscopic aerosols during high insolation (low cloud formation) periods.

Variability in regional background aerosols within the Mediterranean

NASA Astrophysics Data System (ADS)

Querol, X.; Alastuey, A.; Pey, J.; Cusack, M.; Pérez, N.; Mihalopoulos, N.; Theodosi, C.; Gerasopoulos, E.; Kubilay, N.; Koçak, M.

2009-07-01

The main objective of this study is the identification of major factors controlling levels and chemical composition of aerosols in the regional background (RB) along the Mediterranean Basin (MB). To this end, data on PM levels and speciation from Montseny (MSY, NE Spain), Finokalia (FKL, Southern Greece) and Erdemli (ERL, Southern Turkey) for the period 2001 to 2008 are evaluated. Important differences on PM levels and composition are evident when comparing the Western and Eastern MBs. The results manifest W-E and N-S PM10 and PM2.5 gradients along the MB, attributed to the higher frequency and intensity of African dust outbreaks in the EMB, while for PM1 very similar levels are encountered. PM in the EMB is characterized by higher levels of crustal material and sulphate as compared to WMB (and central European sites), however, RB nitrate and OC + EC levels are relatively constant across the Mediterranean and lower than other European sites. Marked seasonal trends are evidenced for PM levels, nitrate (WMB), ammonium and sulphate. Also relatively higher levels of V and Ni (WMB) are measured in the Mediterranean basin, probably as a consequence of high emissions from fuel-oil combustion (power generation, industrial and shipping emissions). Enhanced sulphate levels in EMB compared to WMB were measured. The high levels of sulphate in the EMB may deplete the available gas-phase NH3 so that little ammonium nitrate can form due to the low NH3 levels. This study illustrates the existence of three very important features within the Mediterranean that need to be accounted for when modeling climate effects of aerosols in the area, namely: a) the increasing gradient of dust from WMB to EMB; b) the change of hygroscopic behavior of mineral aerosols (dust) via nitration and sulfation; and c) the abundance of highly hygroscopic aerosols during high insolation (low cloud formation) periods.

Evaluating the Information Content of Newly Retrieved SAGEII NO2 Measurements in the Lower Stratosphere

NASA Technical Reports Server (NTRS)

Newchurch, Michael J.; Cunnold, Derek M.; Zawodny, Joseph M.

2000-01-01

The objective of this research project is: to calculate ozone trends in the stratosphere from Dobson Umkehr measurements, to determine the vertical profile of trends at Arosa by using a sophisticated statistical model (MARCH) to separate solar, aerosol, and QBO effects on Dobson Umkehr measurements, and to compare Umkehr trends with SBUV and SAGE I/II trends in the stratosphere.

The influence of stratospheric dynamics on the forcing efficacy of tropical volcanic SO2 injection: a case study around the 1991 Mount Pinatubo eruption

NASA Astrophysics Data System (ADS)

Dhomse, Sandip; Mann, Graham; Marshall, Lauren; Schmidt, Anja; Carslaw, Kenneth; Chipperfield, Martyn; Bellouin, Nicolas; Morgenstern, Olaf; Johnson, Colin; O'Connor, Fiona

2016-04-01

Major tropical volcanic eruptions exert significant climate impacts principally via enhanced scattering of solar radiation due to the injected SO2 elevating particle concentrations in the stratospheric aerosol layer. The size distribution of stratospheric aerosol particles also shifts to larger sizes in volcanically-enhanced conditions, which promotes absorption and subsequent stratospheric heating as well as causing faster sedimentation. How the volcanic sulphur cloud is dispersed also strongly affects the longevity of its radiative effects. In this presentation we investigate the role of stratospheric dynamical variability in affecting the temporal evolution of the volcanic aerosol, and also its feedback on subsequent chemical and dynamical ozone changes. Among various processes, the Quasi-Biennial Oscillation (QBO), the dominant mode of dynamical variability in the tropical stratosphere, is known to play a key role in determining the meridional dispersion of the volcanic cloud generated by major tropical eruptions. We have carried out a series of interactive stratospheric aerosol simulations with the UM-UKCA composition-climate model, to explore how different QBO phase impact volcanic radiative forcing, with a test case based around Mount Pinatubo. We will present results from an ensemble of simulations for different easterly and westerly phases of QBO, comparing simulated stratospheric aerosol properties (e.g. extinction, AOD, effective radius, particle size distribution) against a range of satellite and in-situ observational datasets. Changes in dynamics and temperatures would be compared against reanalysis (e.g. ERA-interim, HaDCRUT4) datasets followed by an analysis of radiative and dynamical changes for contrasting phases of QBO. References: Dhomse SS, Chipperfield MP, Feng W, Hossaini R, Mann GW, Santee ML (2015) Revisiting the hemispheric asymmetry in midlatitude ozone changes following the Mount Pinatubo eruption: A 3-D model study, Geophysical Research

Aerosol and gamma background measurements at Basic Environmental Observatory Moussala

NASA Astrophysics Data System (ADS)

Angelov, Christo; Arsov, Todor; Penev, Ilia; Nikolova, Nina; Kalapov, Ivo; Georgiev, Stefan

2016-03-01

Trans boundary and local pollution, global climate changes and cosmic rays are the main areas of research performed at the regional Global Atmospheric Watch (GAW) station Moussala BEO (2925 m a.s.l., 42°10'45'' N, 23°35'07'' E). Real time measurements and observations are performed in the field of atmospheric chemistry and physics. Complex information about the aerosol is obtained by using a threewavelength integrating Nephelometer for measuring the scattering and backscattering coefficients, a continuous light absorption photometer and a scanning mobile particle sizer. The system for measuring radioactivity and heavy metals in aerosols allows us to monitor a large scale radioactive aerosol transport. The measurements of the gamma background and the gamma-rays spectrum in the air near Moussala peak are carried out in real time. The HYSPLIT back trajectory model is used to determine the origin of the data registered. DREAM code calculations [2] are used to forecast the air mass trajectory. The information obtained combined with a full set of corresponding meteorological parameters is transmitted via a high frequency radio telecommunication system to the Internet.

Persistence of Antarctic polar stratospheric clouds

NASA Technical Reports Server (NTRS)

Mccormick, M. Patrick; Trepte, C. R.

1988-01-01

The persistence of Polar Stratospheric Clouds (PSCs) observed by the Stratospheric Aerosol Measurement (SAM) 2 satellite sensor over a 9-year period is compared and contrasted. Histograms of the SAM 2 1.0 micron extinction ratio data (aerosol extinction normalized by the molecular extinction) at an altitude of 18 km in the Antarctic have been generated for three 10-day periods in the month of September. Statistics for eight different years (1979 to 1982 and 1984 to 1987) are shown in separate panels for each figure. Since the SAM 2 system is a solar occultation experiment, observations are limited to the edge of the polar night and no measurements are made deep within the vortex where temperatures could be colder. For this reason, use is made of the NMC global gridded fields and the known temperature-extinction relationship to infer additional information on the occurrence and areal coverage of PSCs. Calculations of the daily areal coverage of the 195 K isotherm will be presented for this same period of data. This contour level lies in the range of the predicted temperature for onset of the Type 1 particle enhancement mode at 50 mb (Poole and McCormick, 1988b) and should indicate approximately when formation of the binary HNO3-H2O particles begins.

Atmospheric Sampling of Aerosols to Stratospheric Altitudes using High Altitude Balloons

NASA Astrophysics Data System (ADS)

Jerde, E. A.; Thomas, E.

2010-12-01

Although carbon dioxide represents a long-lived atmospheric component relevant to global climate change, it is also understood that many additional contributors influence the overall climate of Earth. Among these, short-lived components are more difficult to incorporate into models due to uncertainties in the abundances of these both spatially and temporally. Possibly the most significant of these short-lived components falls under the heading of “black carbon” (BC). There are numerous overlapping definitions of BC, but it is basically carbonaceous in nature and light absorbing. Due to its potential as a climate forcer, an understanding of the BC population in the atmosphere is critical for modeling of radiative forcing. Prior measurements of atmospheric BC generally consist of airplane- and ground-based sampling, typically below 5000 m and restricted in time and space. Given that BC has a residence time on the order of days, short-term variability is easily missed. Further, since the radiative forcing is a result of BC distributed through the entire atmospheric column, aircraft sampling is by definition incomplete. We are in the process of planning a more comprehensive sampling of the atmosphere for BC using high-altitude balloons. Balloon-borne sampling is a highly reliable means to sample air through the entire troposphere and into the lower stratosphere. Our system will incorporate a balloon and a flight train of two modules. One module will house an atmospheric sampler. This sampler will be single-stage (samples all particle sizes together), and will place particles directly on an SEM sample stub for analysis. The nozzle depositing the sample will be offset from the center of the stub, placing the aerosol particles toward the edge. At various altitudes, the stub will be rotated 45 degrees, providing 6-8 sample “cuts” of particle populations through the atmospheric column. The flights will reach approximately 27 km altitude, above which the balloons

Analysis of the physical state of one Arctic polar stratospheric cloud based on observations

NASA Technical Reports Server (NTRS)

Drdla, K.; Tabazadeh, A.; Turco, R. P.; Jacobson, M. Z.; Dye, J. E.; Twohy, C.; Baumgardner, D.

1994-01-01

During the Arctic Airborne Stratospheric Expedition (AASE) simultaneous measurements of aerosol size distribution and NO(y)(HN03 + NO + NO2 + 2(N205)) were made along ER-2 flight paths. The flow characteristics of the NO(y) instrument allow us to derive the condensed NO(y) amount (assumed to be HN03) present during polar stratospheric cloud (PSC) events. Analysis of the January 24th flight indicates that this condensed HN03 amount does not agree well with the aerosol volume if the observed PSCs are composed of solid nitric acid trihydrate (NAT), as is generally assumed. However, the composition agrees well with that predicted for liquid H2S04/HN03/H20 solution droplets using a new Aerosol Physical Chemistry Model (APCM). The agreement corresponds in detail to variations in temperature and humidity. The weight percentages of H2SO4, HN03, and H2O derived from the measurements all correspond to those predicted for ternary, liquid solutions.

Guidelines for the aerosol climatic effects special study: An element of the NASA climate research program

NASA Technical Reports Server (NTRS)

1979-01-01

Research to help develop better understanding of the role of aerosols in the Earth's radiative balance is summarized. Natural volcanic injections of aerosols into the stratosphere to understand and model any resultant evidence of climate change are considered. The approach involves: (1) measurements from aircraft, balloon and ground based platforms which complement and enhance the aerosol information derived from satellite data; (2) development of instruments required for some of these measurements; (3) theoretical and laboratory work to aid in interpreting and utilizing space based and in situ data; and (4) preparation for and execution of concentrated observations of stratospheric aerosols following a future large volcanic eruption.

On the size and composition of particles in polar stratospheric clouds

NASA Technical Reports Server (NTRS)

Kinne, Stefan; Toon, Owen B.; Toon, Goeff C.; Farmer, Crofton B.; Browell, Edward V.

1988-01-01

Attenuation measurements of the solar radiation between 1.5 and 15 micron wavelengths were performed with the airborne (DC-8) JPL MARK 4 interferometer during the 1987 Antarctic Expedition. The opacities not only provide information about the abundance of stratospheric gases but also about the optical depths of polar stratospheric clouds (PSCs) at wavelengths of negligible gas absorption (windows). The optical depth of PSCs can be determined for each window once the background attenuation, due to air-molecules and aerosol has been filtered out with a simple extinction law. The ratio of optical thicknesses at different wavelengths reveals information about particle size and particle composition. Among the almost 700 measured spectra only a few PSC cases exist. PSC events are identified by sudden reductions in the spectrally integrated intensity value and are also verified with backscattering data from an upward directed lidar instrument, that was mounted on the DC-8. For the selected case on September 21st at 14.40 GMT, lidar data indicate an optically thin cloud at 18k and later an additional optically thick cloud at 15 km altitude. All results still suffer from: (1) often arbitrary definitions of a clear case, that often already may have contained PSC particles and (2) noise problems that restrict the calculations of optical depths to values larger than 0.001. Once these problems are handled, this instrument may become a valuable tool towards a better understanding of the role PSCs play in the Antarctic stratosphere.

Stratospheric sulfuric acid fraction and mass estimate for the 1982 volcanic eruption of El Chichon

NASA Technical Reports Server (NTRS)

Hofmann, D. J.; Rosen, J. M.

1983-01-01

The stratospheric sulfuric acid fraction and mass for the 1982 volcanic eruptions of El Chichon are investigated using data from balloon soundings at Laramie (41 deg N) and in southern Texas (27-29 deg N). The total stratospheric mass of these eruptions is estimated to be approximately 8 Tg about 6.5 months after the eruption with possibly as much as 20 Tg in the stratosphere about 45 days after the eruption. Observations of the aerosol in Texas revealed two primary layers, both highly volatile at 150 C. Aerosol in the upper layer at about 25 km was composed of an approximately 80 percent H2SO4 solution while the lower layer at approximately 18 km was composed of a 60-65 percent H2SO4 solution aerosol. It is calculated that an H2SO4 vapor concentration of at least 3 x 10 to the 7th molecules/cu cm is needed to sustain the large droplets in the upper layer. An early bi-modal nature in the size distribution indicates droplet nucleation from the gas phase during the first 3 months, while the similarity of the large particle profiles 2 months apart shows continued particle growth 6.5 months after the explosion.

Source regions of stratospheric VSLS in the Indian Ocean

NASA Astrophysics Data System (ADS)

Quack, Birgit; Hepach, Helmke; Atlas, Elliot; Bracher, Astrid; Endres, Sonja; Arevalo-Martinez, Damian; Bange, Hermann; Lennartz, Sinikka; Steinhoff, Tobias; Booge, Dennis; Zarvasky, Alexander; Marandino, Christa; Patey, Matt; Achterberg, Eric; Dengler, Markus; Fiehn, Alina; Tegtmeier, Susann; Krüger, Kirstin

2016-04-01

Halogenated very-short-lived substances (VSLS), which are naturally produced in the ocean, play a significant role in present day ozone depletion, in particular in combination with enhanced stratospheric sulfate aerosol, which is also partly derived from oceanic VSLS. The decline of anthropogenic chlorine in the stratosphere within the 21st century will increase the relative importance of the natural emissions on stratospheric ozone destruction. Especially, oceanic sources and source regions of the compounds need to be better constrained, in order to improve the future prediction. During boreal summer the Asian monsoon circulation transports air masses from the Indian Ocean to the stratosphere, while the contribution of VSLS from this ocean to stratospheric halogen and sulfur is unknown. During the research cruises SO 234/2 and SO 235 in July-August 2014 onboard RV SONNE oceanic and atmospheric halogenated VSLS such as bromoform (CHBr3), dibromomethane (CH2Br2) and methyl iodide (CH3I) were measured in the subtropical and tropical West Indian Ocean for the first time. Here we present the oceanic sources of the halogenated compounds and their relation to other biogeochemical parameters (short- and longlived trace gases, phytoplankton and nutrients) along the cruise track, which covered coastal, upwelling and open ocean regimes and the Seychelles-Chagos thermocline ridge as important source region for stratospheric bromine.

Aerosols in the Atmosphere: Sources, Transport, and Multi-decadal Trends

NASA Technical Reports Server (NTRS)

Chin, M.; Diehl, T.; Bian, H.; Kucsera, T.

2016-01-01

We present our recent studies with global modeling and analysis of atmospheric aerosols. We have used the Goddard Chemistry Aerosol Radiation and Transport (GOCART) model and satellite and in situ data to investigate (1) long-term variations of aerosols over polluted and dust source regions and downwind ocean areas in the past three decades and the cause of the changes and (2) anthropogenic and volcanic contributions to the sulfate aerosol in the upper tropospherelower stratosphere.

Solubility of HCL in sulfuric acid at stratospheric temperatures

NASA Technical Reports Server (NTRS)

Williams, Leah R.; Golden, David M.

1993-01-01

The solubility of HCl in sulfuric acid was measured using a Knudsen cell technique. Effective Henry's law constants are reported for sulfuric acid concentrations between 50 and 60 weight percent and for temperatures between 220 and 230 K. The measured values indicate that very little HCl will be dissolved in the stratospheric sulfate aerosol particles.

Simulation of the Pinatubo aerosol cloud in general circulation model

NASA Technical Reports Server (NTRS)

Boville, Byron A.; Holton, James R.; Mote, Philip W.

1991-01-01

The global transport and dispersion of the Pinatubo aerosol cloud are simulated by means of a high-resolution stratospheric version of the NCAR Community Climate Model (CCM2) with an annual cycle. A passive tracer was injected into the model stratosphere over the Philippine Islands on June 15, and the transport was simulated for 180 d using an accurate semi-Lagrangian advection scheme. The simulated volcanic aerosol cloud initially drifted westward and expanded in longitude and latitude. The bulk of the aerosol cloud dispersed zonally to form a continuous belt in longitude, and remained confined to the tropics, centered near the 20-mb level for the entire 180-d model run, although a small amount was transported episodically into the upper troposphere in association with convective disturbances. Aerosol transported to the troposphere was dispersed within a few weeks into the Northern Hemisphere extratropics. In the Southern Hemisphere, the aerosol was mixed into the region equatorward of the core of the polar night jet during the first 50 d, but penetration into southern polar latitudes was delayed until the final warming in November.

Stratospheric controlled perturbation experiment (SCoPEx): overview, status, and results from related laboratory experiments

NASA Astrophysics Data System (ADS)

Keith, D.; Dykema, J. A.; Keutsch, F. N.

2017-12-01

Stratospheric Controlled Perturbation Experiment (SCoPEx), is a scientific experiment to advance understanding of stratospheric aerosols. It aims to make quantitative measurements of aerosol microphysics and atmospheric chemistry to improve large-scale models used to assess the risks and benefits of solar geoengineering. A perturbative experiment requires: (a) means to create a well-mixed, small perturbed volume, and (b) observation of time evolution of chemistry and aerosols in the volume. SCoPEx will used a propelled balloon gondola containing all instruments and drive system. The propeller wake forms a well-mixed volume (roughly 1 km long and 100 meters in diameter) that serves as an experimental `beaker' into which aerosols (e.g., < 1 kg of 0.3 µm radius CaCO3 particles) at can be injected; while, the propellers allow the gondola to move at speeds up to 3 m/sec relative to the local air mass driving the gondola back forth through the volume to measure properties of the perturbed air mass. This presentation will provide an overview of the experiment including (a) a systems engineering perspective from high-level scientific questions through instrument selection, mission design, and proposed operations and data analysis; (b) instruments, include current status of integration testing; (c) payload engineering including structure, power and mass budget, etc; (d) results from CFD simulation of propeller wake and simulation of chemistry and aerosol microphysics; and finally (e) proposed concept of operations and schedule. We will also provide an overview of the plans for governance including management of health safety and environmental risks, transparency, public engagement, and larger questions about governance of solar geoengineering experiments. Finally, we will briefly present results of laboratory experiments of the interaction of chemical such as ClONO2 and HCl on particle surfaces relevant for stratospheric solar geoengineering.

Heterogeneous reaction of N2O5 with airborne TiO2 particles and its implication for stratospheric particle injection

NASA Astrophysics Data System (ADS)

Tang, M. J.; Telford, P. J.; Pope, F. D.; Rkiouak, L.; Abraham, N. L.; Archibald, A. T.; Braesicke, P.; Pyle, J. A.; McGregor, J.; Watson, I. M.; Cox, R. A.; Kalberer, M.

2014-06-01

Injection of aerosol particles (or their precursors) into the stratosphere to scatter solar radiation back into space has been suggested as a solar-radiation management scheme for the mitigation of global warming. TiO2 has recently been highlighted as a possible candidate particle because of its high refractive index, but its impact on stratospheric chemistry via heterogeneous reactions is as yet unknown. In this work the heterogeneous reaction of airborne sub-micrometre TiO2 particles with N2O5 has been investigated for the first time, at room temperature and different relative humidities (RH), using an atmospheric pressure aerosol flow tube. The uptake coefficient of N2O5 onto TiO2, γ(N2O5), was determined to be ~1.0 × 10-3 at low RH, increasing to ~3 × 10-3 at 60% RH. The uptake of N2O5 onto TiO2 is then included in the UKCA chemistry-climate model to assess the impact of this reaction on stratospheric chemistry. While the impact of TiO2 on the scattering of solar radiation is chosen to be similar to the aerosol from the Mt Pinatubo eruption, the impact of TiO2 injection on stratospheric N2O5 is much smaller.

Chemical Composition and Dynamics of the Upper Troposphere and the Lower Stratosphere: Overview of the Project

NASA Astrophysics Data System (ADS)

Sofieva, V. F.; Liu, C.; Huang, F.; Kyrola, E.; Liu, Y.; Ialongo, I.; Hakkarainen, J.; Zhang, Y.

2016-08-01

The DRAGON-3 cooperation study on the upper troposphere and the lower stratosphere (UTLS) is based on new satellite data and modern atmospheric models. The objectives of the project are: (i) assessment of satellite data on chemical composition in UTLS, (ii) dynamical and chemical structures of the UTLS and its variability, (iii) multi-scale variability of stratospheric ozone, (iv) climatology of the stratospheric aerosol layer and its variability, and (v) updated ozone climatology and its relation to tropopause/multiple tropopauses.In this paper, we present the main results of the project.

1984-1995 Evolution of Stratospheric Aerosol Size, Surface Area, and Volume Derived by Combining SAGE II and CLAES Extinction Measurements

NASA Technical Reports Server (NTRS)

Russell, Philip B.; Bauman, Jill J.

2000-01-01

This SAGE II Science Team task focuses on the development of a multi-wavelength, multi- sensor Look-Up-Table (LUT) algorithm for retrieving information about stratospheric aerosols from global satellite-based observations of particulate extinction. The LUT algorithm combines the 4-wavelength SAGE II extinction measurements (0.385 <= lambda <= 1.02 microns) with the 7.96 micron and 12.82 micron extinction measurements from the Cryogenic Limb Array Etalon Spectrometer (CLAES) instrument, thus increasing the information content available from either sensor alone. The algorithm uses the SAGE II/CLAES composite spectra in month-latitude-altitude bins to retrieve values and uncertainties of particle effective radius R(sub eff), surface area S, volume V and size distribution width sigma(sub g).

Cosmogenic 35S as a Novel Detector of Stratospheric Air at the Earth's Surface: Key Findings from the Western United States and New Insights into the Seasonal Variations of Ozone and Sulfate in East Asia

NASA Astrophysics Data System (ADS)

Lin, M.; Thiemens, M. H.; Shaheen, R.; Biglari, S.; Crocker, D.; Zhang, Z.; Tao, J.; Su, L.; Fung, J. C. H.; Su, B.; Liu, L.

2016-12-01

The extent to which stratospheric intrusions on synoptic scales influence the tropospheric ozone (O3) levels remains poorly understood because quantitative detection of stratosphere air at the Earth's surface has been challenging. Cosmogenic 35S is invaluable in such quantification, but this has not yet been unambiguously demonstrated. As a global hot spot for stratospheric intrusions, the western United States (US) is a natural laboratory for testing the validity of this approach. Here, we present measurements of 35S in sulfate aerosols during a well-defined deep stratospheric intrusion event in the western US, which led to a regional O3 pollution event across southern California. The surprisingly high 35S activity in this episode is greater than any other natural radiogenic sulfate aerosols reported in the literature, providing the first and direct field-based evidence that 35S is a sensitive tracer for air mass of stratospheric origin and transported downward. Using this novel tracer, we quantify the seasonal variation for the strength of downward transport of stratospheric air to the planetary boundary layer in East Asia (EA) and what it may mean for surface O3 and sulfate levels. Our 35S measurements in sulfate aerosols collected from a background site (Mount Wuyi; 27.72°N, 117.68°E) during 2014-2015 show peaks in spring and autumn and the temporal variations of 35S were in tandem with surface O3 levels. These results imply that stratospheric O3 in aged stratospheric air masses may contribute to surface O3 levels in the study region in these two seasons. Along with radiogenic 35S analysis, measuring all seven stable isotopes (16O, 17O, 18O, 32S, 33S, 34S and 36S) in the same sulfate samples provides significantly deeper understanding of the atmospheric sulfur cycle in this region. Triple oxygen isotopes are being measured and preliminary results show that the relative importance of different formation pathways of secondary sulfate in EA is likely altitude

Complex chemical composition of colored surface films formed from reactions of propanal in sulfuric acid at upper troposphere/lower stratosphere aerosol acidities.

PubMed

Van Wyngarden, A L; Pérez-Montaño, S; Bui, J V H; Li, E S W; Nelson, T E; Ha, K T; Leong, L; Iraci, L T

Particles in the upper troposphere and lower stratosphere (UT/LS) consist mostly of concentrated sulfuric acid (40-80 wt %) in water. However, airborne measurements have shown that these particles also contain a significant fraction of organic compounds of unknown chemical composition. Acid-catalyzed reactions of carbonyl species are believed to be responsible for significant transfer of gas phase organic species into tropospheric aerosols and are potentially more important at the high acidities characteristic of UT/LS particles. In this study, experiments combining sulfuric acid (H 2 SO 4 ) with propanal and with mixtures of propanal with glyoxal and/or methylglyoxal at acidities typical of UT/LS aerosols produced highly colored surface films (and solutions) that may have implications for aerosol properties. In order to identify the chemical processes responsible for the formation of the surface films, attenuated total reflectance-Fourier transform infrared (ATR-FTIR) and 1 H nuclear magnetic resonance (NMR) spectroscopies were used to analyze the chemical composition of the films. Films formed from propanal were a complex mixture of aldol condensation products, acetals and propanal itself. The major aldol condensation products were the dimer (2-methyl-2-pentenal) and 1,3,5-trimethylbenzene that was formed by cyclization of the linear aldol condensation trimer. Additionally, the strong visible absorption of the films indicates that higher-order aldol condensation products must also be present as minor species. The major acetal species were 2,4,6-triethyl-1,3,5-trioxane and longer-chain linear polyacetals which are likely to separate from the aqueous phase. Films formed on mixtures of propanal with glyoxal and/or methylglyoxal also showed evidence of products of cross-reactions. Since cross-reactions would be more likely than self-reactions under atmospheric conditions, similar reactions of aldehydes like propanal with common aerosol organic species like glyoxal

Complex chemical composition of colored surface films formed from reactions of propanal in sulfuric acid at upper troposphere/lower stratosphere aerosol acidities

PubMed Central

Van Wyngarden, A. L.; Pérez-Montaño, S.; Bui, J. V. H.; Li, E. S. W.; Nelson, T. E.; Ha, K. T.; Leong, L.; Iraci, L. T.

2016-01-01

Particles in the upper troposphere and lower stratosphere (UT/LS) consist mostly of concentrated sulfuric acid (40–80 wt %) in water. However, airborne measurements have shown that these particles also contain a significant fraction of organic compounds of unknown chemical composition. Acid-catalyzed reactions of carbonyl species are believed to be responsible for significant transfer of gas phase organic species into tropospheric aerosols and are potentially more important at the high acidities characteristic of UT/LS particles. In this study, experiments combining sulfuric acid (H2SO4) with propanal and with mixtures of propanal with glyoxal and/or methylglyoxal at acidities typical of UT/LS aerosols produced highly colored surface films (and solutions) that may have implications for aerosol properties. In order to identify the chemical processes responsible for the formation of the surface films, attenuated total reflectance–Fourier transform infrared (ATR-FTIR) and 1H nuclear magnetic resonance (NMR) spectroscopies were used to analyze the chemical composition of the films. Films formed from propanal were a complex mixture of aldol condensation products, acetals and propanal itself. The major aldol condensation products were the dimer (2-methyl-2-pentenal) and 1,3,5-trimethylbenzene that was formed by cyclization of the linear aldol condensation trimer. Additionally, the strong visible absorption of the films indicates that higher-order aldol condensation products must also be present as minor species. The major acetal species were 2,4,6-triethyl-1,3,5-trioxane and longer-chain linear polyacetals which are likely to separate from the aqueous phase. Films formed on mixtures of propanal with glyoxal and/or methylglyoxal also showed evidence of products of cross-reactions. Since cross-reactions would be more likely than self-reactions under atmospheric conditions, similar reactions of aldehydes like propanal with common aerosol organic species like glyoxal and

Stratospheric ozone variations in the equatorial region as seen in Stratospheric and Gas Experiment data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Masato Shiotani; Fumio Hasebe

1994-07-20

An analysis is made of equatorial ozone variations for 5 years, 1984-1989, using the ozone profile data derived from the Stratospheric Aerosol and Gas Experiment II (SAGE II) instrument. Attention is focused on the annual cycle and also on interannual variability, particularly the quasi-biennial oscillation (QBO) and El Nino-Southern Oscillation (ENSO) variations in the lower stratosphere, where the largest contribution to total column ozone takes place. The annual variation in zonal mean total ozone around the equator is composed of symmetric and asymmetric modes with respect to the equator, with maximum contributions being around 19 km for the symmetric modemore » and around 25 km for the asymmetric mode. The persistent zonal wavenumber 1 structure observed by the total ozone mapping spectrometer over the equator is almost missing in the SAGE-derived column amounts integrated in the stratosphere, suggesting a significant contribution from tropospheric ozone. Interannual variations in the equatorial ozone are dominated by the QBO above 20 km and the ENSO-related variation below 20 km. The ozone QBO is characterized by zonally uniform phase changes in association with the zonal wind QBO in the equatorial lower stratosphere. The ENSO-related ozone variation consists of both the east-west vacillation and the zonally uniform phase variation. During the El Nino event, the east-west contrast with positive (negative) deviations in the eastern (western) hemisphere is conspicuous, while the decreasing tendency of the zonal mean values is maximum at the same time. 28 refs., 13 figs.« less

Drift-corrected Odin-OSIRIS ozone product: algorithm and updated stratospheric ozone trends

NASA Astrophysics Data System (ADS)

Bourassa, Adam E.; Roth, Chris Z.; Zawada, Daniel J.; Rieger, Landon A.; McLinden, Chris A.; Degenstein, Douglas A.

2018-01-01

A small long-term drift in the Optical Spectrograph and Infrared Imager System (OSIRIS) stratospheric ozone product, manifested mostly since 2012, is quantified and attributed to a changing bias in the limb pointing knowledge of the instrument. A correction to this pointing drift using a predictable shape in the measured limb radiance profile is implemented and applied within the OSIRIS retrieval algorithm. This new data product, version 5.10, displays substantially better both long- and short-term agreement with Microwave Limb Sounder (MLS) ozone throughout the stratosphere due to the pointing correction. Previously reported stratospheric ozone trends over the time period 1984-2013, which were derived by merging the altitude-number density ozone profile measurements from the Stratospheric Aerosol and Gas Experiment (SAGE) II satellite instrument (1984-2005) and from OSIRIS (2002-2013), are recalculated using the new OSIRIS version 5.10 product and extended to 2017. These results still show statistically significant positive trends throughout the upper stratosphere since 1997, but at weaker levels that are more closely in line with estimates from other data records.

Systematic stratospheric observations on the Antarctic continent at Dumont d'Urville

NASA Technical Reports Server (NTRS)

Godin, S.; Sarkissian, A.; David, C.; Megie, G.; Pommereau, J. P.; Goutail, F.; Aimedieu, P.; Piquard, J.; Lebouar, E.; Stefanutti, L.

1994-01-01

Results of different routine measurements performed in Dumont d'Urville (66 deg S, 140 deg E) since 1988 are presented. They include the seasonal variation of total ozone and NO2 as measured by a SAOZ UV-Visible spectrometer, Polar Stratospheric Cloud observations by a backscatter lidar and more recently, vertical ozone profiles by ECC sondes and ozone and aerosols stratospheric profiles by a DIAL lidar. The particular results of 1991 in relation with the volcanic events of Mount Pinatubo and Mount Hudson, and the position of the polar vortex over Dumont d'Urville are discussed.

A continuous sampler with background suppression for monitoring alpha-emitting aerosol particles.

PubMed

McFarland, A R; Rodgers, J C; Ortiz, C A; Moore, M E

1992-05-01

A continuous air monitor has been developed that includes provisions for improving the detection of alpha-emitting aerosol particles in the presence of radon/thoron progeny that are unattached to ambient aerosol particles. Wind tunnel tests show that 80% of 10-microns aerodynamic equivalent diameter particles penetrate the flow system from the ambient air to the collection filter when the flow rate is 57 L min-1 (2 cfm) and the wind speed is 1 m s-1. Uniformity of aerosol collection on the filter, as characterized by the coefficient of variation of the areal density deposits, is less than 15% for 10-microns aerodynamic-equivalent-diameter aerosol particles. Tests with unattached radon daughters in a flow-through chamber showed that approximately 99% of the 218Po was removed by an inlet screen that is designed to collect radon daughters that are in the size range of molecular clusters. The inlet screen offers the opportunity to improve the signal-to-noise ratio of energy spectra in the regions of interest (subranges of the energy spectrum) of transuranic elements and thereby enhance the performance of background compensation algorithms.

Recent lidar measurements of stratospheric ozone and temperature within the network for the detection of stratospheric change

NASA Technical Reports Server (NTRS)

Mcgee, Thomas J.; Ferrare, Richard; Butler, James J.; Frost, Robert L.; Gross, Michael; Margitan, James

1991-01-01

The Goddard mobile lidar was deployed at Cannon Air Force Base near Clovis, New Mexico during the Spring of 1990. Measurements of stratospheric ozone and temperature were made over a period of six weeks. Data from the lidar system is compared with data from a balloon-borne, ultraviolet instrument launched from nearby Ft. Sumner, New Mexico. Along with several improvements to this instrument which are now underway, a second lidar dedicated to temperature and aerosol measurements is now being developed.

Nitrogen oxides in the arctic stratosphere: Implications for ozone abundances. Ph.D. Thesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Slusser, J.R.

1994-01-01

In the high latitude winter stratosphere, NO2 sequesters chlorine compounds which are extremely efficient at destroying ozone. During the nighttime, NO2 reacts with ozone to form N2O5 which acts as a reservoir of NO2. Under heavy aerosol loading, N2O5 may react with water on aerosol surfaces to form HNO3, a reservoir more resistant to photolysis. This heterogeneous reaction results in reduced NO2 concentration when the sun returns at the end of the winter. A spectrograph system has been developed to measure scattered zenith skylight and thereby determine stratospheric NO2 slant column abundance. Conversion of the measured slant column abundance tomore » vertical column abundance requires dividing by the air mass. The air mass is the enhancement in the optical path for the scattered twilight as compared to a vertical path. Air mass values determined using a multiple scattering radiative transfer code have been compared to those derived using a Monte Carlo code and were found to agree to within 6% at a 90 deg solar zenith angle for a stratospheric absorber. Six months of NO2 vertical column abundance measured over Fairbanks during the winter 1992-93 exhibited the daylight diminished and increased as the sunlight hours lengthened. The overall seasonal behavior was similar to high-latitude measurements made in the Southern Hemisphere. The ratios of morning to evening column abundance were consistent with predictions based on gas-phase chemistry. The possible heterogeneous reaction of N2O5 on sulfate aerosols was investigated using FTIR Spectrometer measurements of HNO3 column abundance and lidar determinations of the aerosol profile. Using an estimated N2O5 column abundance and aerosol profile as input to a simple model, significant HNO3 production was expected. No increase in HNO3 column abundance was measured. From this set of data, it was not possible to determine whether significant amounts of N2O5 were converted to HNO3 by this heterogeneous reaction.« less

Use of radon and cosmogenic radionuclides as indicators of exchange between troposphere and stratosphere

NASA Technical Reports Server (NTRS)

Kritz, Mark A.

1994-01-01

This research grant covered participation in the operational phase of NASA's Stratosphere-Troposphere Exchange Project (STEP), a multi-agency airborne science program conducted aboard NASA U-2 and ER-2 high altitude research aircraft. The primary goals of STEP were to investigate the mechanisms of irreversible movement of mass, trace gases, and aerosols from the troposphere into the stratosphere, and to explain the observed dryness of the stratosphere. Three flight experiments were conducted to address these questions: two extratropical experiments, in 1984 and 1986, and a tropical experiment, in 1987. The cosmogenic radionuclides Be-7 and P-32, produced in the stratosphere by cosmic rays, and Rn-222 (radon), emitted from continental soils, were well-suited as tracers of intra-stratospheric air mass movements, and to follow episodes of troposphere to stratosphere exchange. Measurements of Be-7 and P-32 were made in all three STEP experiments. Measurements of radon were made in the tropical experiment only. The equipment worked well, and produced a valuable data set in support of the STEP objectives, as indicated by the 'quick-look' results outlined.

Forty-eight-inch lidar aerosol measurements taken at the Langley Research Center, May 1974 to December 1987

NASA Technical Reports Server (NTRS)

Fuller, W. H., Jr.; Osborn, M. T.; Hunt, W. H.

1988-01-01

A ground based lidar system located at NASA Langley Research Center in Hampton, Va., was used to obtain high resolution vertical profiles of the stratospheric and upper tropospheric aerosol since 1974. More than 200 measurements obtained at a wavelength of 0.6943 microns during 1974 to 1987 are summarized. Plots of peak backscatter mixing ratio and integrated backscatter vs time are presented for the entire measurement sequence. The plots highlight the influence of several major volcanic eruptions on the long term stratospheric aerosol layer. In particular, the eruptions of El Chichon in late Mar. to early Apr. 1982, produced a massive aerosol layer. Aerosol enhancement from El Chichon reached Hampton, Va. by May 1982, with a scattering ratio of approx. 50 detected on Jul. 1, 1982. In addition, scattering ratio profiles for June 1982 to December 1987, along with tables containing numerical values of the backscatter ratio and backscattering function versus altitude, are included to further describe the upper tropospheric and stratospheric aerosol layer. A 14 year summary is presented, in a ready to use format, of lidar observations at a fixed midlatitude location to be used for further study.

Atmospheric aerosol compositions and sources at two national background sites in northern and southern China

NASA Astrophysics Data System (ADS)

Zhu, Qiao; He, Ling-Yan; Huang, Xiao-Feng; Cao, Li-Ming; Gong, Zhao-Heng; Wang, Chuan; Zhuang, Xin; Hu, Min

2016-08-01

Although China's severe air pollution has become a focus in the field of atmospheric chemistry and the mechanisms of urban air pollution there have been researched extensively, few field sampling campaigns have been conducted at remote background sites in China, where air pollution characteristics on a larger scale are highlighted. In this study, an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS), together with an Aethalometer, was deployed at two of China's national background sites in northern (Lake Hongze site; 33.23° N, 118.33° E; altitude 21 m) and southern (Mount Wuzhi site; 18.84° N, 109.49° E; altitude 958 m) China in the spring seasons in 2011 and 2015, respectively, in order to characterize submicron aerosol composition and sources. The campaign-average PM1 concentration was 36.8 ± 19.8 µg m-3 at the northern China background (NCB) site, which was far higher than that at the southern China background (SCB) site (10.9 ± 7.8 µg m-3). Organic aerosol (OA) (27.2 %), nitrate (26.7 %), and sulfate (22.0 %) contributed the most to the PM1 mass at NCB, while OA (43.5 %) and sulfate (30.5 %) were the most abundant components of the PM1 mass at SCB, where nitrate only constituted a small fraction (4.7 %) and might have contained a significant amount of organic nitrates (5-11 %). The aerosol size distributions and organic aerosol elemental compositions all indicated very aged aerosol particles at both sites. The OA at SCB was more oxidized with a higher average oxygen to carbon (O / C) ratio (0.98) than that at NCB (0.67). Positive matrix factorization (PMF) analysis was used to classify OA into three components, including a hydrocarbon-like component (HOA, attributed to fossil fuel combustion) and two oxygenated components (OOA1 and OOA2, attributed to secondary organic aerosols from different source areas) at NCB. PMF analysis at SCB identified a semi-volatile oxygenated component (SV-OOA) and a low-volatility oxygenated

An Analysis of Neptune's Stratospheric Haze Using High-Phase-Angle Voyager Images

NASA Technical Reports Server (NTRS)

Moses, Julianne I.; Rages, Kathy; Pollack, James B.

1995-01-01

We have inverted high-phase-angle Voyager images of Neptune to determine the atmospheric extinction coefficient as a function of altitude and the scattering phase function at a reference altitude. Comparisons between theoretical model and observations help separate the contributions from molecular Rayleigh and aerosol scattering and help determine the variation of the aerosol size, concentration, and scattering properties with altitude. Further comparisons between models and data allow us to place constraints on the location and composition of the hazes, the concentration and downward flux of certain condensible hydrocarbon gases, the eddy diffusion coefficient in the lower stratosphere, and the thermal profile in parts of Neptune's stratosphere. We find that a distinct stratospheric haze layer exists near 12(sub -1, sup +1) mbar in Neptune's lower stratosphere, most probably due to condensed ethane. The derived stratospheric haze production rate of 1.0(sub -0.3, sup +0.2) x 10(exp -15) g cm(exp -2) sec(exp -1) is substantially lower than photochemical model predictions. Evidence for hazes at higher altitudes also exists. Unlike the situation on Uranus, large particles (0.08-0.11 microns) may be present at high altitudes on Neptune (e.g., near 0.5 mbar), well above the region in which we expect the major hydrocarbon species to condense. Near 28 mbar, the mean particle size is about 0.13(sub -0.02, sup +0.02) microns with a concentration of 5(sub -3, sup +3) particles cm(exp -3). The cumulative haze extinction optical depth above 15 mbar in the clear filter is approx. 3 x 10(exp -3), and much of this extinction is due to scattering rather than absorption; thus, if our limb-scan sites are typical, the hazes cannot account for the stratospheric temperature inversion on Neptune and may not contribute significantly to atmospheric heating. We compare the imaging results with the results from other observations, including those of the Voyager Photopolarimeter Subsystem

Connections Between Stratospheric Pollution and the Asian Summer Monsoon

NASA Technical Reports Server (NTRS)

Bauer, Susanne E.; Tsigaridis, Konstas

2015-01-01

The Asian Monsoon leads to rapid vertical transport of gases and aerosols into the upper troposphere. Some of the pollution might be transported above cloud levels, which will allow it to spread globally and possibly at some occasions reach into the stratosphere. In this study we will use the GISS climate model to investigate the interactions between pollution and convective transport as well as secondary aerosol formation. Pollution resulting from anthropogenic activity as well as from natural sources such as small and large volcanic eruptions, dust storms and forest fires will be quantified. This modeling study will be accompanied by satellite observations from space that monitor aerosol optical thickness (AOT), and absorption AOT (AAOT) in two and three dimensions. Our goal is a better process level understanding of the evolution of natural and anthropogenic aerosol plumes in conjunction with the Asian Monsoon. Hence, we aim to explain their large-scale expansion, which eventually determines their impacts on climate.

Simulation of Aerosols and Chemistry with a Unified Global Model

NASA Technical Reports Server (NTRS)

Chin, Mian

2004-01-01

This project is to continue the development of the global simulation capabilities of tropospheric and stratospheric chemistry and aerosols in a unified global model. This is a part of our overall investigation of aerosol-chemistry-climate interaction. In the past year, we have enabled the tropospheric chemistry simulations based on the GEOS-CHEM model, and added stratospheric chemical reactions into the GEOS-CHEM such that a globally unified troposphere-stratosphere chemistry and transport can be simulated consistently without any simplifications. The tropospheric chemical mechanism in the GEOS-CHEM includes 80 species and 150 reactions. 24 tracers are transported, including O3, NOx, total nitrogen (NOy), H2O2, CO, and several types of hydrocarbon. The chemical solver used in the GEOS-CHEM model is a highly accurate sparse-matrix vectorized Gear solver (SMVGEAR). The stratospheric chemical mechanism includes an additional approximately 100 reactions and photolysis processes. Because of the large number of total chemical reactions and photolysis processes and very different photochemical regimes involved in the unified simulation, the model demands significant computer resources that are currently not practical. Therefore, several improvements will be taken, such as massive parallelization, code optimization, or selecting a faster solver. We have also continued aerosol simulation (including sulfate, dust, black carbon, organic carbon, and sea-salt) in the global model to cover most of year 2002. These results have been made available to many groups worldwide and accessible from the website http://code916.gsfc.nasa.gov/People/Chin/aot.html.

Balloon profiles of stratospheric NO[sub 2] and HNO[sub 3] for testing the heterogeneous hydrolysis of N[sub 2]O[sub 5] on sulfate aerosols

DOE Office of Scientific and Technical Information (OSTI.GOV)

Webster, C.R.; May, R.D.; Allen, M.

1994-01-01

Simultaneous in situ measurements of stratospheric NO[sub 2], HNO[sub 3], HCl, and CH[sub 4] from 34 to 24 km were made in August 1992 from Palestine, Texas, using the Balloon-borne Laser In-Situ Sensor (BLISS) tunable diode laser spectrometer. Although the measurements of NO[sub 2], HNO[sub 3], and NO[sub 2]/HNO[sub 3] agree well with gas-phase model calculations near 34 km where SAGE II data show little sulfate aerosol, this is not true at the lower altitudes where SAGE II shows high aerosol loadings. At 24 km the BLISS NO[sub 2] and HNO[sub 3] measurements are 70% lower, and 50% higher, respectively,more » than the gas phase model predictions, with a measured NO[sub 2]/HNO[sub 3] ratio 5 times smaller. When the heterogeneous hydrolysis of N[sub 2]O[sub 5] and ClONO[sub 2] on sulfate aerosol of surface area densities matching the SAGE II measurements is added to the model, good agreement with the BLISS measurements is found over the whole altitude range. 24 refs., 4 figs., 1 tab.« less

Impact of idealized future stratospheric aerosol injection on the large-scale ocean and land carbon cycles

NASA Astrophysics Data System (ADS)

Tjiputra, J. F.; Grini, A.; Lee, H.

2016-01-01

Using an Earth system model, we simulate stratospheric aerosol injection (SAI) on top of the Representative Concentration Pathways 8.5 future scenario. Our idealized method prescribes aerosol concentration, linearly increasing from 2020 to 2100, and thereafter remaining constant until 2200. In the aggressive scenario, the model projects a cooling trend toward 2100 despite warming that persists in the high latitudes. Following SAI termination in 2100, a rapid global warming of 0.35 K yr-1 is simulated in the subsequent 10 years, and the global mean temperature returns to levels close to the reference state, though roughly 0.5 K cooler. In contrast to earlier findings, we show a weak response in the terrestrial carbon sink during SAI implementation in the 21st century, which we attribute to nitrogen limitation. The SAI increases the land carbon uptake in the temperate forest-, grassland-, and shrub-dominated regions. The resultant lower temperatures lead to a reduction in the heterotrophic respiration rate and increase soil carbon retention. Changes in precipitation patterns are key drivers for variability in vegetation carbon. Upon SAI termination, the level of vegetation carbon storage returns to the reference case, whereas the soil carbon remains high. The ocean absorbs nearly 10% more carbon in the geoengineered simulation than in the reference simulation, leading to a ˜15 ppm lower atmospheric CO2 concentration in 2100. The largest enhancement in uptake occurs in the North Atlantic. In both hemispheres' polar regions, SAI delays the sea ice melting and, consequently, export production remains low. In the deep water of North Atlantic, SAI-induced circulation changes accelerate the ocean acidification rate and broaden the affected area.

Heterogeneous reactions in a stratospheric box model: A sensitivity study

NASA Astrophysics Data System (ADS)

Danilin, Michael Y.; McConnell, John C.

1994-12-01

Recent laboratory data concerning the reactions of HCl and HOx on/in sulfuric acid aerosol (Hanson et al., 1994), N2O5 and ClONO2 hydrolysis on the frozen aerosol (Hanson and Ravishankara, 1993a) and the temperature dependence of the HNO3 absorption cross section (Burkholder et al., 1993) indicate that a reevaluation of the role of heterogeneous reactions in the chemical balance of the stratosphere is required. A chemical module prepared for a three-dimensional (3-D) global chemistry transport model (CTM) and a general circulation model (GCM) has been used to carry out a sensitivity study of the effects of heterogeneous reactions on/in the sulfate aerosol and on the polar stratospheric cloud (PSC) particles. We present here results for the latitudes 60°S, 70°S and 75°S at the 50-mbar level. Our findings indicate that (1) the new values of the HNO3 cross sections result in lower mixing ratios for NOx and make ozone more vulnerable to catalytic destruction by ClOx; (2) the effect of the heterogeneous reactions OH + HNO3(a) → H2O + NO3 and HO2 +HO2(a) → H2O2 + O2 are small in comparison with the same gas phase reactions and play a negligible role for the ozone balance; (3) the HCl reactions in the sulfuric acid aerosol at 60°S and 70°S increase the chlorine activation up to 0.53 parts per billion by volume (ppbv) and 0.72 ppbv, respectively, for liquid aerosol and up to 0.87 ppbv for frozen aerosol at 70°S for volcanic conditions and this results in considerable ozone depletion at these latitudes; (4) studying the ozone "hole" phenomenon, we have considered the different initial ratios of ClONO2/HCl, of N2O5, galactic cosmic rays (GCRs), and longer lifetimes for the PSC. We have speculated an existence of the reaction N2O5 + HCl(a) → ClNO2 + HNO3.

The Influence of the 2006 Indonesian Biomass Burning Aerosols on Tropical Dynamics Studied with the GEOS-5 AGCM

NASA Technical Reports Server (NTRS)

Ott, Lesley; Duncan, Bryan; Pawson, Steven; Colarco, Peter; Chin, Mian; Randles, Cynthia; Diehl, Thomas; Nielsen, Eric

2009-01-01

The direct and semi-direct effects of aerosols produced by Indonesian biomass burning (BB) during August November 2006 on tropical dynamics have been examined using NASA's Goddard Earth Observing System, Version 5 (GEOS-5) atmospheric general circulation model (AGCM). The AGCM includes CO, which is transported by resolved and sub-grid processes and subject to a linearized chemical loss rate. Simulations were driven by two sets of aerosol forcing fields calculated offline, one that included Indonesian BB aerosol emissions and one that did not. In order to separate the influence of the aerosols from internal model variability, the means of two ten-member ensembles were compared. Diabatic heating from BB aerosols increased temperatures over Indonesia between 150 and 400 hPa. The higher temperatures resulted in strong increases in upward grid-scale vertical motion, which increased water vapor and CO over Indonesia. In October, the largest increases in water vapor were found in the mid-troposphere (25%) while the largest increases in CO occurred just below the tropopause (80 ppbv or 50%). Diabatic heating from the Indonesian BB aerosols caused CO to increase by 9% throughout the tropical tropopause layer in November and 5% in the lower stratosphere in December. The results demonstrate that aerosol heating plays an important role in the transport of BB pollution and troposphere-to-stratosphere transport. Changes in vertical motion and cloudiness induced by aerosol heating can also alter the transport and phase of water vapor in the upper troposphere/lower stratosphere.

Aerosol microphysics simulations of the Mt. Pinatubo eruption with the UKCA composition-climate model

NASA Astrophysics Data System (ADS)

Dhomse, S. S.; Emmerson, K. M.; Mann, G. W.; Bellouin, N.; Carslaw, K. S.; Chipperfield, M. P.; Hommel, R.; Abraham, N. L.; Telford, P.; Braesicke, P.; Dalvi, M.; Johnson, C. E.; O'Connor, F.; Morgenstern, O.; Pyle, J. A.; Deshler, T.; Zawodny, J. M.; Thomason, L. W.

2014-01-01

We have enhanced the capability of a microphysical aerosol-chemistry module to simulate the atmospheric aerosol and precursor gases for both tropospheric and stratospheric conditions. Using the Mount Pinatubo eruption (June 1991) as a test case, we evaluate simulated aerosol properties in a composition-climate model against a range of satellite and in-situ observations. Simulations are performed assuming an injection of 20 Tg SO2 at 19-27 km in tropical latitudes, without any radiative feedback from the simulated aerosol. In both quiescent and volcanically perturbed conditions, simulated aerosol properties in the lower stratosphere show reasonable agreement with the observations. The model captures the observed timing of the maximum aerosol optical depth (AOD) and its decay timescale in both tropics and Northern Hemisphere (NH) mid-latitudes. There is also good qualitative agreement with the observations in terms of spatial and temporal variation of the aerosol effective radius (Reff), which peaks 6-8 months after the eruption. However, the model shows significant biases against some observational data sets. Simulated AOD and Surface Area Density (SAD) in the tropics are substantially higher than the gap-filled satellite data products during the first 6 months after the eruption. The model shows consistently weaker enhancement in Reff compared to satellite and in-situ measurements. Simulated aerosol particle size distribution is also compared to NH mid-latitude in-situ balloon sounding measurements of size-resolved number concentrations. Before the eruption, the model captures the observed profiles of lower stratospheric particle number concentrations with radii larger than 5, 150 and 250 nm (N5, N150 and N250) very well. However, in the first 6 months after the eruption, the model shows high bias in N5 concentrations in the lower stratosphere, suggesting too strong nucleation. Following particle growth via condensation and coagulation, this bias in the finest

Observations of stratospheric aerosols associated with the El Chichon eruption

NASA Technical Reports Server (NTRS)

Thomas, L.; Vaughan, G.; Jenkins, D. B.; Wareing, D.; Farrington, M.

1986-01-01

Lidar observations of aerosols were carried out at Aberystwyth between Nov. 1982 and Dec. 1985 using a frequency doubled and frequency tripled Nd/Yag laser and a receiver incorporating a 1 m diameter in a Newtonian telescope configuration. In analyses of the experimental data attention is paid to the magnitude of the coefficient relating extinction and backscatter, the choice being related to the possible presence of aerosols in the upper troposphere and the atmospheric densities employed in the normalisation procedure. The aerosol loading showed marked day to day changes in early months and an overall decay was apparent only after April 1983, this decay being consistent with an e sup -1 time of about 7 months. The general decay was accompanied by a lowering of the layer but layers of aerosols were shown intermittently at heights above the main layer in winter months. The height variations of photon counts corrected for range, or of aerosol backscatter ratio, showed clear signatures of the tropopause. A strong correlation was found between the heights of the tropopause identified from the lidar measurements and from radiosonde-borne temperature measurements. A notable feature of the observations is the appearance of very sharp height gradients of backscatter ratio which seem to be produced by differential advection.

The stratosphere perturbed by propulsion effluents. CIAP monograph 3. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1975-09-01

The Climatic Impact Assessment Program (CIAP) of the U.S. Department of Transportation is charged with the assessment of the impact of future aircraft fleets and other vehicles operating in, or transiting through, the stratosphere. Monograph 3 considers the perturbations of the radiation fluxes, and therefore the composition of the stratosphere, that are produced by the emission of engine effluents from potential, large-scale operations of aircraft in the lower stratosphere (e.g., 29 to 69 kft or 9 to 21 km). The important engine emissions are the odd nitrogen oxides (NO/sub x/ or NO and NO/sub 2/), sulfur dioxide (SO/sub 2/), andmore » water vapor (H/sub 2/O). Monograph 3 considers the significant perturbations in the composition of the radiative species in the stratosphere, which include ozone (O/sub 3/), nitrogen dioxide (NO/sub 2/), sulfuric acid aerosols (75 percent H/sub 2/SO/sub 4/), and water vapor. These considerations require an understanding of complex phenomena involving radiative, chemical, dynamic, and thermodynamic processes in the stratosphere. Since CIAP is concerned with predictions of effects that take place in the distant future, the methodology used for this purpose is based on models of atmospheric phenomena. (GRA)« less

Impacts on Global Agriculture of Stratospheric Sulfate Injection

NASA Astrophysics Data System (ADS)

Robock, A.; Xia, L.

2014-12-01

Impacts on global food supply are one of the most important concerns in the discussion of stratospheric sulfate geoengineering. Stratospheric sulfate injection could reduce surface temperature, precipitation, and insolation, which could affect agricultural production. We use output from climate model simulations using the two most "realistic" scenarios from the Geoengineering Model Intercomparison Project, G3 and G4. G3 posits balancing the increasing radiative forcing from the RCP4.5 business-as-usual scenario with stratospheric sulfate aerosols from 2020 through 2070. The G4 scenario also uses RCP4.5, but models simulate the stratospheric injection of 5 Tg SO2 per year from 2020 to 2070. In total, there are three modeling groups which have completed G3 and four for G4. We use two crop models, the global gridded Decision Support System for Agrotechnology Transfer (gDSSAT) crop model and the crop model in the NCAR Community Land Model (CLM-crop), to predict global maize yield changes. Without changing agricultural technology, we find that compared to the reference run forced by the RCP4.5 scenario, maize yields could increase in both G3 and G4 due to both the cooling effect of stratospheric sulfate injection and the CO2 fertilization effect, with the cooling effect contributing more to the increased productivity. However, the maize yield changes are not much larger than natural variability under G3, since the temperature reduction is smaller in G3 than in G4. Both crop models show similar results.

Impact of Idealized Stratospheric Aerosol Injection on the Future Ocean and Land Carbon Cycles

NASA Astrophysics Data System (ADS)

Tjiputra, J.; Lauvset, S.

2017-12-01

Using a state-of-the-art Earth system model, we simulate stratospheric aerosol injection (SAI) on top of the Representative Concentration Pathways 8.5 future scenario. Our idealized method prescribes aerosol concentration, linearly increasing from 2020 to 2100, and thereafter remaining constant until 2200. In one of the scenarios, the model able to project future warming below 2 degree toward 2100, despite greatier warming persists in the high latitudes. When SAI is terminated in 2100, a rapid global warming of 0.35 K yr-1 (as compared to 0.05 K yr-1 under RCP8.5) is simulated in the subsequent 10 years, and the global mean temperature rapidly returns to levels close to the reference state. In contrast to earlier findings, we show a weak response in the terrestrial carbon sink during SAI implementation in the 21st century, which we attribute to nitrogen limitation. The SAI increases the land carbon uptake in the temperate forest-, grassland-, and shrub-dominated regions. The resultant lower temperatures lead to a reduction in the heterotrophic respiration rate and increase soil carbon retention. Changes in precipitation patterns are key drivers for variability in vegetation carbon. Upon SAI termination, the level of vegetation carbon storage returns to the reference case, whereas the soil carbon remains high. The ocean absorbs nearly 10% more carbon in the geoengineered simulation than in the reference simulation, leading to a ˜15 ppm lower atmospheric CO2 concentration in 2100. The largest enhancement in uptake occurs in the North Atlantic. In both hemispheres' polar regions, SAI delays the sea ice melting and, consequently, export production remains low. Despite inducing little impact on surface acidification, in the deep water of North Atlantic, SAI-induced circulation changes accelerate the ocean acidification rate and broaden the affected area. Since the deep ocean provides vital ecosystem function and services, e.g., fish stocks, this accelerated changes

Pinatubo Emulation in Multiple Models (POEMs): co-ordinated experiments in the ISA-MIP model intercomparison activity component of the SPARC Stratospheric Sulphur and it's Role in Climate initiative (SSiRC)

NASA Astrophysics Data System (ADS)

Lee, Lindsay; Mann, Graham; Carslaw, Ken; Toohey, Matthew; Aquila, Valentina

2016-04-01

The World Climate Research Program's SPARC initiative has a new international activity "Stratospheric Sulphur and its Role in Climate" (SSiRC) to better understand changes in stratospheric aerosol and precursor gaseous sulphur species. One component of SSiRC involves an intercomparison "ISA-MIP" of composition-climate models that simulate the stratospheric aerosol layer interactively. Within PoEMS each modelling group will run a "perturbed physics ensemble" (PPE) of interactive stratospheric aerosol (ISA) simulations of the Pinatubo eruption, varying several uncertain parameters associated with the eruption's SO2 emissions and model processes. A powerful new technique to quantify and attribute sources of uncertainty in complex global models is described by Lee et al. (2011, ACP). The analysis uses Gaussian emulation to derive a probability density function (pdf) of predicted quantities, essentially interpolating the PPE results in multi-dimensional parameter space. Once trained on the ensemble, a Monte Carlo simulation with the fast Gaussian emulator enabling a full variance-based sensitivity analysis. The approach has already been used effectively by Carslaw et al., (2013, Nature) to quantify the uncertainty in the cloud albedo effect forcing from a 3D global aerosol-microphysics model allowing to compare the sensitivy of different predicted quantities to uncertainties in natural and anthropogenic emissions types, and structural parameters in the models. Within ISA-MIP, each group will carry out a PPE of runs, with the subsequent analysis with the emulator assessing the uncertainty in the volcanic forcings predicted by each model. In this poster presentation we will give an outline of the "PoEMS" analysis, describing the uncertain parameters to be varied and the relevance to further understanding differences identified in previous international stratospheric aerosol assessments.

Observations of the loss of stratospheric NO2 following volcanic eruptions

NASA Technical Reports Server (NTRS)

Coffey, M. T.; Mankin, William G.

1993-01-01

Observations of stratospheric column amounts of nitrogen dioxide (NO2), nitric oxide (NO) and nitric acid (HNO3) have been made following major eruptions of the El Chichon and Mt. Pintatubo volcanoes. Midlatitude abundances of NO2 and NO were reduced by as much as 70% in the months following the appearance of the volcanic aerosols as compared to volcanically quite periods. There are heterogeneous reactions which could occur on the volcanic aerosols to convert NO2 into HNO3 but no commensurate increase in HNO3 column amounts was observed at the times of NO2 decrease.

Lidar investigations of ozone in the upper troposphere - lower stratosphere: technique and results of measurements

NASA Astrophysics Data System (ADS)

Romanovskii, Oleg A.; Nevzorov, Alexey A.; Nevzorov, Alexey V.; Kharchenko, Olga V.

2018-04-01

The main aim of the research is to develop the technique for laser remote ozone sensing in the upper troposphere - lower stratosphere by differential absorption method for temperature and aerosol correction and analysis of measurement results. The authors have determined wavelengths, promising to measure ozone profiles in the upper troposphere - lower stratosphere. We present the results of DIAL measurements of the vertical ozone distribution at the Siberian lidar station in Tomsk. The recovered ozone profiles were compared with IASI satellite data and Kruger model.

Lifting options for stratospheric aerosol geoengineering: advantages of tethered balloon systems.

PubMed

Davidson, Peter; Burgoyne, Chris; Hunt, Hugh; Causier, Matt

2012-09-13

The Royal Society report 'Geoengineering the Climate' identified solar radiation management using albedo-enhancing aerosols injected into the stratosphere as the most affordable and effective option for geoengineering, but did not consider in any detail the options for delivery. This paper provides outline engineering analyses of the options, both for batch-delivery processes, following up on previous work for artillery shells, missiles, aircraft and free-flying balloons, as well as a more lengthy analysis of continuous-delivery systems that require a pipe connected to the ground and supported at a height of 20 km, either by a tower or by a tethered balloon. Towers are shown not to be practical, but a tethered balloon delivery system, with high-pressure pumping, appears to have much lower operating and capital costs than all other delivery options. Instead of transporting sulphuric acid mist precursors, such a system could also be used to transport slurries of high refractive index particles such as coated titanium dioxide. The use of such particles would allow useful experiments on opacity, coagulation and atmospheric chemistry at modest rates so as not to perturb regional or global climatic conditions, thus reducing scale-up risks. Criteria for particle choice are discussed, including the need to minimize or prevent ozone destruction. The paper estimates the time scales and relatively modest costs required if a tethered balloon system were to be introduced in a measured way with testing and development work proceeding over three decades, rather than in an emergency. The manufacture of a tether capable of sustaining the high tensions and internal pressures needed, as well as strong winds, is a significant challenge, as is the development of the necessary pumping and dispersion technologies. The greatest challenge may be the manufacture and launch of very large balloons, but means have been identified to significantly reduce the size of such balloons or aerostats.

Ozone Depletion at Mid-Latitudes: Coupling of Volcanic Aerosols and Temperature Variability to Anthropogenic Chlorine

NASA Technical Reports Server (NTRS)

Solomon, S.; Portmann, R. W.; Garcia, R. R.; Randel, W.; Wu, F.; Nagatani, R.; Gleason, J.; Thomason, L.; Poole, L. R.; McCormick, M. P.

1998-01-01

Satellite observations of total ozone at 40-60 deg N are presented from a variety of instruments over the time period 1979-1997. These reveal record low values in 1992-3 (after Pinatubo) followed by partial but incomplete recovery. The largest post-Pinatubo reductions and longer-term trends occur in spring, providing a critical test for chemical theories of ozone depletion. The observations are shown to be consistent with current understanding of the chemistry of ozone depletion when changes in reactive chlorine and stratospheric aerosol abundances are considered along with estimates of wave-driven fluctuations in stratospheric temperatures derived from global temperature analyses. Temperature fluctuations are shown to make significant contributions to model calculated northern mid-latitude ozone depletion due to heterogeneous chlorine activation on liquid sulfate aerosols at temperatures near 200-210 K (depending upon water vapor pressure), particularly after major volcanic eruptions. Future mid-latitude ozone recovery will hence depend not only on chlorine recovery but also on temperature trends and/or variability, volcanic activity, and any trends in stratospheric sulfate aerosol.

Ozone loss in the lower stratosphere over the United States in 1992-1993: Evidence for heterogeneous chemistry on the Pinatubo aerosol

NASA Technical Reports Server (NTRS)

Hofmann, D. J.; Oltmans, S. J.; Komhyr, W. D.; Harris, J. M.; Lathrop, J. A.; Langford, A. O.; Deshler, T.; Johnson, B. J.; Torres, A.; Matthews, W. A.

1994-01-01

Ozone profiles obtained at Boulder, Colorado and Wallops Island, Virginia indicate that ozone was about 25% below normal during the winter and spring of 1992-93 in the 12-22 km region. This large ozone reduction in the lower stratosphere, though sometimes partially compensated by higher than normal ozone above 24 km, was responsible for the low total column ozone values observed across the United States during this period. Normal temperatures throughout the low ozone region suggest that transport-related effects are probably not the most important cause of the ozone deficits. This region of low ozone at Boulder corresponds closely with the location of the enhanced H2SO4/H2O aerosol from the Pinatubo eruption of 1991 as measured near Boulder and at Laramie, Wyoming. Trajectory analyses suggest that except at low altitudes in spring, air parcels on the days of the ozone measurements generally arrived at Boulder from higher latitude, although seldom higher than 60 deg N, and hence may have been subjected to heterogeneous chemical processing on the surface of Pinatubo aerosol droplets resulting in chlorine-catalyzed ozone destruction, a process which is believed to be more effective under the lower winter temperatures and sunlight levels of higher latitudes.

Environmental Temperature Effect on the Far-Infrared Absorption Features of Aromatic-Based Titan's Aerosol Analogs

NASA Technical Reports Server (NTRS)

Gautier, Thomas; Trainer, Melissa G.; Loeffler, Mark J.; Sebree, Joshua A.; Anderson, Carrie M.

2016-01-01

Benzene detection has been reported in Titans atmosphere both in the stratosphere at ppb levels by remote sensing and in the thermosphere at ppm levels by the Cassini's Ion and Neutral Mass Spectrometer. This detection supports the idea that aromatic and heteroaromatic reaction pathways may play an important role in Titans atmospheric chemistry, especially in the formation of aerosols. Indeed, aromatic molecules are easily dissociated by ultraviolet radiation and can therefore contribute significantly to aerosol formation. It has been shown recently that aerosol analogs produced from a gas mixture containing a low concentration of aromatic and/or heteroaromatic molecules (benzene, naphthalene, pyridine, quinoline and isoquinoline) have spectral signatures below 500/cm, a first step towards reproducing the aerosol spectral features observed by Cassini's Composite InfraRed Spectrometer (CIRS) in the far infrared. In this work we investigate the influence of environmental temperature on the absorption spectra of such aerosol samples, simulating the temperature range to which aerosols, once formed, are exposed during their transport through Titans stratosphere. Our results show that environmental temperature does not have any major effect on the spectral shape of these aerosol analogs in the far-infrared, which is consistent with the CIRS observations.

New Insight into Polar Stratospheric Cloud Processes from A-Train Observations

NASA Astrophysics Data System (ADS)

Pitts, M. C.; Poole, L. R.

2016-12-01

Polar stratospheric clouds (PSCs) play essential roles in the chemical depletion of stratospheric ozone at high latitudes. Heterogeneous reactions occurring on PSC particles, primarily supercooled ternary (H2SO4-H2O-HNO3) solution (STS) droplets, convert stable chlorine reservoir species to highly reactive ozone-destructive forms. Also, sedimentation and evaporation of large nitric acid trihydrate (NAT) particles irreversibly redistributes odd nitrogen and prolongs ozone depletion by slowing the reformation of stable chlorine reservoirs. Even after three decades of research, significant gaps in our understanding of PSC processes still exist, particularly concerning NAT nucleation and the extent to which chlorine is activated on cold background aerosol prior to PSC formation. These uncertainties limit our ability to represent PSCs accurately in global models and call into question predictions of ozone recovery in a changing climate. PSC observations from the A-Train satellite constellation have stimulated a number of new research activities that have both extended and challenged our knowledge of PSC processes and modeling capabilities. Specifically, the CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) lidar on the CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations) satellite is providing information on PSC morphology and composition in unprecedented detail, while the Microwave Limb Sounder (MLS) on the Aura satellite is providing nearly coincident measurements of gas-phase HNO3 and H2O, the major constituents of all PSC particles. The combined analyses of these datasets enable better PSC composition discrimination and provide valuable new insight into processes such as PSC-catalyzed chlorine activation and PSC particle growth kinetics. The more than ten years of CALIOP and MLS measurements have uniquely captured the primary aspects of the seasonal and multi-year variability of PSCs in the Arctic and Antarctic and are enabling the

Balloon-borne measurements of middle atmosphere aerosols and trace gases in Antarctica

NASA Technical Reports Server (NTRS)

Hofmann, D. J.

1988-01-01

This paper reviews data on in situ balloon-borne measurements on stratospheric ozone concentrations and aerosol contents obtained prior to 1986, along with the measurements obtained in 1986 during the National Ozone Expedition. The data indicate that the phenomenon of ozone depletion appears to be shaped spatially and temporally by dynamical stratospheric phenomena. In terms of Antarctic stratospheric research, it appears that the most important problems at the moment involve delineating the springtime ozone depletion through accurate in situ measurements of temperature, trace gas, and particle size (in addition to remote sensing from space).

Background aerosol over the Himalayas and Tibetan Plateau: observed characteristics of aerosol mass loading

NASA Astrophysics Data System (ADS)

Liu, B.; Cong, Z.; Wang, Y.; Xin, J.; Wan, X.; Pan, Y.; Liu, Z.; Wang, Y.; Zhang, G.; Kang, S.

2016-12-01

To investigate the atmospheric aerosols of the Himalayas and Tibetan Plateau (HTP), an observation network was established within the region's various ecosystems, including at Ngari, Qomolangma (QOMS), Nam Co, and SouthEastern Tibetan (SET) stations. In this paper we illustrate aerosol mass loadings by integrating in situ measurements with satellite and ground-based remote sensing datasets for the 2011-2013 period, on both local and large scales. Mass concentrations of these surface atmospheric aerosols were relatively low and varied with land cover, showing a general tendency of Ngari and QOMS (barren sites) > Nam Co (grassland site) > SET (forest site). Bimodal mass distributions of size-segregated particles were found at all sites, with a relatively small peak in accumulation mode and a more notable peak in coarse mode. Diurnal variations in fine aerosol masses generally displayed a bi-peak pattern at the QOMS, Nam Co and SET stations and a single-peak pattern at the Ngari station, controlled by the effects of local geomorphology, mountain-valley breeze circulation and aerosol emissions. Combining surface aerosols data and atmospheric-column aerosol optical properties, the TSP mass and aerosol optical depth (AOD) of the Multi-angle Imaging Spectroradiometer (MISR) generally decreased as land cover changed from barren to forest, in inverse relation to the PM2.5 ratios. The seasonality of aerosol mass parameters was land-cover dependent. Over forest and grassland areas, TSP mass, PM2.5 mass, MISR-AOD and fine-mode AOD were higher in spring and summer, followed by relatively lower values in autumn and winter. At the barren site (the QOMS station), there were inconsistent seasonal variations between surface TSP mass (PM2.5 mass) and atmospheric column AOD (fine-mode AOD). Our findings implicate that, HTP aerosol masses (especially their reginal characteristics and fine particle emissions) need to be treated sensitively in relation to assessments of their climatic

On the accuracy of stratospheric aerosol extinction derived from in situ size distribution measurements and surface area density derived from remote SAGE II and HALOE extinction measurements

DOE PAGES

Kovilakam, Mahesh; Deshler, Terry

2015-08-26

In situ stratospheric aerosol measurements, from University of Wyoming optical particle counters (OPCs), are compared with Stratospheric Aerosol Gas Experiment (SAGE) II (versions 6.2 and 7.0) and Halogen Occultation Experiment (HALOE) satellite measurements to investigate differences between SAGE II/HALOE-measured extinction and derived surface area and OPC-derived extinction and surface area. Coincident OPC and SAGE II measurements are compared for a volcanic (1991-1996) and nonvolcanic (1997-2005) period. OPC calculated extinctions agree with SAGE II measurements, within instrumental uncertainty, during the volcanic period, but have been a factor of 2 low during the nonvolcanic period. Three systematic errors associated with the OPCmore » measurements, anisokineticity, inlet particle evaporation, and counting efficiency, were investigated. An overestimation of the OPC counting efficiency is found to be the major source of systematic error. With this correction OPC calculated extinction increases by 15-30% (30-50%) for the volcanic (nonvolcanic) measurements. These changes significantly improve the comparison with SAGE II and HALOE extinctions in the nonvolcanic cases but slightly degrade the agreement in the volcanic period. These corrections have impacts on OPC-derived surface area density, exacerbating the poor agreement between OPC and SAGE II (version 6.2) surface areas. Furthermore, this disparity is reconciled with SAGE II version 7.0 surface areas. For both the volcanic and nonvolcanic cases these changes in OPC counting efficiency and in the operational SAGE II surface area algorithm leave the derived surface areas from both platforms in significantly better agreement and within the ± 40% precision of the OPC moment calculations.« less

On the accuracy of stratospheric aerosol extinction derived from in situ size distribution measurements and surface area density derived from remote SAGE II and HALOE extinction measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kovilakam, Mahesh; Deshler, Terry

In situ stratospheric aerosol measurements, from University of Wyoming optical particle counters (OPCs), are compared with Stratospheric Aerosol Gas Experiment (SAGE) II (versions 6.2 and 7.0) and Halogen Occultation Experiment (HALOE) satellite measurements to investigate differences between SAGE II/HALOE-measured extinction and derived surface area and OPC-derived extinction and surface area. Coincident OPC and SAGE II measurements are compared for a volcanic (1991-1996) and nonvolcanic (1997-2005) period. OPC calculated extinctions agree with SAGE II measurements, within instrumental uncertainty, during the volcanic period, but have been a factor of 2 low during the nonvolcanic period. Three systematic errors associated with the OPCmore » measurements, anisokineticity, inlet particle evaporation, and counting efficiency, were investigated. An overestimation of the OPC counting efficiency is found to be the major source of systematic error. With this correction OPC calculated extinction increases by 15-30% (30-50%) for the volcanic (nonvolcanic) measurements. These changes significantly improve the comparison with SAGE II and HALOE extinctions in the nonvolcanic cases but slightly degrade the agreement in the volcanic period. These corrections have impacts on OPC-derived surface area density, exacerbating the poor agreement between OPC and SAGE II (version 6.2) surface areas. Furthermore, this disparity is reconciled with SAGE II version 7.0 surface areas. For both the volcanic and nonvolcanic cases these changes in OPC counting efficiency and in the operational SAGE II surface area algorithm leave the derived surface areas from both platforms in significantly better agreement and within the ± 40% precision of the OPC moment calculations.« less

Evolution of Pinatubo aerosol near 19 km altitude over western North America

NASA Technical Reports Server (NTRS)

Goodman, Jindra; Snetsinger, K. G.; Pueschel, R. F.; Ferry, G. V.; Verma, S.

1994-01-01

Stratospheric aerosols, collected near 19 km altitude on wire impactors over western North America from August 20, 1991 to May 11, 1993, show strong influence of the June 1991 Mt. Pinatubo eruption. Lognormal size distributions are bimodal; each of the mode radii increases and reaches maximum value at about 15 months after eruption. The second (large particle) mode becomes well developed then, and about 40% of the droplets are larger than 0.4 micron radius. The eruption of Mt. Spurr (Alaska) may also have contributed to this. Sulfate mass loading decays exponentially (e-folding 216 days), similar to El Chichon. Silicates are present in samples only immediately after eruption. Two years after eruption, sulfate mass loading is about 0.4 micrograms/cu m, about an order of magnitude higher than background pre-volcanic values. Aerosol size distributions are still bimodal with a very well-defined large droplet mode.

Model simulations of the chemical and aerosol microphysical evolution of the Sarychev Peak 2009 eruption cloud compared to in situ and satellite observations

NASA Astrophysics Data System (ADS)

Lurton, Thibaut; Jégou, Fabrice; Berthet, Gwenaël; Renard, Jean-Baptiste; Clarisse, Lieven; Schmidt, Anja; Brogniez, Colette; Roberts, Tjarda J.

2018-03-01

Volcanic eruptions impact climate through the injection of sulfur dioxide (SO2), which is oxidized to form sulfuric acid aerosol particles that can enhance the stratospheric aerosol optical depth (SAOD). Besides large-magnitude eruptions, moderate-magnitude eruptions such as Kasatochi in 2008 and Sarychev Peak in 2009 can have a significant impact on stratospheric aerosol and hence climate. However, uncertainties remain in quantifying the atmospheric and climatic impacts of the 2009 Sarychev Peak eruption due to limitations in previous model representations of volcanic aerosol microphysics and particle size, whilst biases have been identified in satellite estimates of post-eruption SAOD. In addition, the 2009 Sarychev Peak eruption co-injected hydrogen chloride (HCl) alongside SO2, whose potential stratospheric chemistry impacts have not been investigated to date. We present a study of the stratospheric SO2-particle-HCl processing and impacts following Sarychev Peak eruption, using the Community Earth System Model version 1.0 (CESM1) Whole Atmosphere Community Climate Model (WACCM) - Community Aerosol and Radiation Model for Atmospheres (CARMA) sectional aerosol microphysics model (with no a priori assumption on particle size). The Sarychev Peak 2009 eruption injected 0.9 Tg of SO2 into the upper troposphere and lower stratosphere (UTLS), enhancing the aerosol load in the Northern Hemisphere. The post-eruption evolution of the volcanic SO2 in space and time are well reproduced by the model when compared to Infrared Atmospheric Sounding Interferometer (IASI) satellite data. Co-injection of 27 Gg HCl causes a lengthening of the SO2 lifetime and a slight delay in the formation of aerosols, and acts to enhance the destruction of stratospheric ozone and mono-nitrogen oxides (NOx) compared to the simulation with volcanic SO2 only. We therefore highlight the need to account for volcanic halogen chemistry when simulating the impact of eruptions such as Sarychev on