Pre-form ceramic matrix composite cavity and method of forming and method of forming a ceramic matrix composite component

DOEpatents

Monaghan, Philip Harold; Delvaux, John McConnell; Taxacher, Glenn Curtis

2015-06-09

A pre-form CMC cavity and method of forming pre-form CMC cavity for a ceramic matrix component includes providing a mandrel, applying a base ply to the mandrel, laying-up at least one CMC ply on the base ply, removing the mandrel, and densifying the base ply and the at least one CMC ply. The remaining densified base ply and at least one CMC ply form a ceramic matrix component having a desired geometry and a cavity formed therein. Also provided is a method of forming a CMC component.

Improving Thermomechanical Properties of SiC/SiC Composites

NASA Technical Reports Server (NTRS)

DiCarlo, James A.; Bhatt, Ramakrishna T.

2006-01-01

Today, a major thrust toward improving the thermomechanical properties of engine components lies in the development of fiber-reinforced silicon carbide matrix composite materials, including SiC-fiber/SiC-matrix composites. These materials are lighter in weight and capable of withstanding higher temperatures, relative to state-of-the-art metallic alloys and oxide-matrix composites for which maximum use temperatures are in the vicinity of 1,100 C. In addition, the toughness or damage tolerance of the SiC-matrix composites is significantly greater than that of unreinforced silicon-based monolithic ceramics. For successful application in advanced engine systems, the SiC-matrix composites should be able to withstand component service stresses and temperatures for the desired component lifetimes. Inasmuch as the high-temperature structural lives of ceramic materials are typically limited by creep-induced growth of flaws, a key property required of such composite materials is high resistance to creep under conditions of use. Also, the thermal conductivity of the materials should be as high as possible so as to minimize component thermal gradients and thermal stresses. A state-of-the-art SiC-matrix composite is typically fabricated in a three-step process: (1) fabrication of a component-shaped architectural preform reinforced by thermally stable high-performance fibers, (2) chemical-vapor infiltration (CVI) of a fiber-coating material such as boron nitride (BN) into the preform, and (3) infiltration of an SiC-based matrix into the remaining porosity in the preform. Generally, the matrices of the highest-performing composites are fabricated by initial use of a CVI SiC matrix component that is typically more thermally stable and denser than matrix components formed by processes other than CVI. As such, the initial SiC matrix component made by CVI provides better environmental protection to the coated fibers embedded within it. Also, the denser CVI SiC imparts to the composite better resistance to propagation of cracks, enhanced thermal conductivity, and higher creep resistance.

Magnetic nanofiber composite materials and devices using same

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Xing; Zhou, Ziyao

2017-04-11

A nonreciprocal device is described. It includes a housing, a waveguide layer and at least one layer of magnetic nanofiber composite. The magnetic nanofiber composite layer is made up of a polymer base layer, a dielectric matrix comprising magnetic nanofibers. The nanofibers have a high aspect ratio and wherein said dielectric matrix is embedded in the polymer base layer.

FRCM and FRP composites for the repair of damaged PC girders.

DOT National Transportation Integrated Search

2015-01-01

Fabric-reinforced-cementitious-matrix (FRCM) and fiber-reinforced polymer (FRP) composites have : emerged as novel strengthening technologies. FRCM is a composite material consisting of a sequence of : one or more layers of cement-based matrix reinfo...

Novel, inorganic composites using porous, alkali-activated, aluminosilicate binders

NASA Astrophysics Data System (ADS)

Musil, Sean

Geopolymers are an inorganic polymeric material composed of alumina, silica, and alkali metal oxides. Geopolymers are chemical and fire resistant, can be used as refractory adhesives, and are processed at or near ambient temperature. These properties make geopolymer an attractive choice as a matrix material for elevated temperature composites. This body of research investigated numerous different reinforcement possibilities and variants of geopolymer matrix material and characterized their mechanical performance in tension, flexure and flexural creep. Reinforcements can then be chosen based on the resulting properties to tailor the geopolymer matrix composites to a specific application condition. Geopolymer matrix composites combine the ease of processing of polymer matrix composites with the high temperature capability of ceramic matrix composites. This study incorporated particulate, unidirectional fiber and woven fiber reinforcements. Sodium, potassium, and cesium based geopolymer matrices were evaluated with cesium based geopolymer showing great promise as a high temperature matrix material. It showed the best strength retention at elevated temperature, as well as a very low coefficient of thermal expansion when crystallized into pollucite. These qualities made cesium geopolymer the best choice for creep resistant applications. Cesium geopolymer binders were combined with unidirectional continuous polycrystalline mullite fibers (Nextel(TM) 720) and single crystal mullite fibers, then the matrix was crystallized to form cubic pollucite. Single crystal mullite fibers were obtained by the internal crystallization method and show excellent creep resistance up to 1400°C. High temperature flexural strength and flexural creep resistance of pollucite and polycrystalline/single-crystal fibers was evaluated at 1000-1400°C.

The development and mechanical characterization of aluminium copper-carbon fiber metal matrix hybrid composite

NASA Astrophysics Data System (ADS)

Manzoor, M. U.; Feroze, M.; Ahmad, T.; Kamran, M.; Butt, M. T. Z.

2018-04-01

Metal matrix composites (MMCs) come under advanced materials that can be used for a wide range of industrial applications. MMCs contain a non-metallic reinforcement incorporated into a metallic matrix which can enhance properties over base metal alloys. Copper-Carbon fiber reinforced aluminium based hybrid composites were prepared by compo casting method. 4 weight % copper was used as alloying element with Al because of its precipitation hardened properties. Different weight compositions of composites were developed and characterized by mechanical testing. A significant improvement in tensile strength and micro hardness were found, before and after heat treatment of the composite. The SEM analysis of the fractured surfaces showed dispersed and embedded Carbon fibers within the network leading to the enhanced strength.

Development of corn starch based green composites reinforced with Saccharum spontaneum L fiber and graft copolymers--evaluation of thermal, physico-chemical and mechanical properties.

PubMed

Kaith, B S; Jindal, R; Jana, A K; Maiti, M

2010-09-01

In this paper, corn starch based green composites reinforced with graft copolymers of Saccharum spontaneum L. (Ss) fiber and methyl methacrylates (MMA) and its mixture with acrylamide (AAm), acrylonitrile (AN), acrylic acid (AA) were prepared. Resorcinol-formaldehyde (Rf) was used as the cross-linking agent in corn starch matrix and different physico-chemical, thermal and mechanical properties were evaluated. The matrix and composites were found to be thermally more stable than the natural corn starch backbone. Further the matrix and composites were subjected for biodegradation studies through soil composting method. Different stages of biodegradation were evaluated through FT-IR and scanning electron microscopic (SEM) techniques. S. spontaneum L fiber-reinforced composites were found to exhibit better tensile strength. On the other hand Ss-g-poly (MMA) reinforced composites showed maximum compressive strength and wear resistance than other graft copolymers reinforced composite and the basic matrix. (c) 2010 Elsevier Ltd. All rights reserved.

Studies on microstructure and mechanical behaviour of A7075- Flyash/SiC hybrid metal matrix composites

NASA Astrophysics Data System (ADS)

Venkata Reddy, V.; Gopi Krishna, M.; Praveen Kumar, K.; Naga Kishore, B. S.; Babu Rao, J.; Bhargava, NRMR

2018-02-01

Experiments have been performed under laboratory condition to review the mechanical behaviour of the hybrid composites with aluminium matrix A7075 alloy, reinforced with silicon carbide (SiC) and Flyash. This has been possible by fabricating the samples through usual stir casting technique. Scanning electron microscopy was used for microstructure analysis. Chemical characterization of both matrix and composites was performed by using EDAX. Density, hardness, tensile and deformation studies were conceded out on both the base alloy and composites. Enhanced hardness and deformed properties were observed for all the composites. Interestingly improved tensile results were obtained for the composites than alloy. Dispersion of (SiC) and Flyash particles in aluminium matrix enhances the hardness of the composites.

Method of making metal matrix composites reinforced with ceramic particulates

DOEpatents

Cornie, James A.; Kattamis, Theodoulos; Chambers, Brent V.; Bond, Bruce E.; Varela, Raul H.

1989-01-01

Composite materials and methods for making such materials are disclosed in which dispersed ceramic particles are at chemical equilibrium with a base metal matrix, thereby permitting such materials to be remelted and subsequently cast or otherwise processed to form net weight parts and other finished (or semi-finished) articles while maintaining the microstructure and mechanical properties (e.g. wear resistance or hardness) of the original composite. The composite materials of the present invention are composed of ceramic particles in a base metal matrix. The ceramics are preferably carbides of titanium, zirconium, tungsten, molybdenum or other refractory metals. The base metal can be iron, nickel, cobalt, chromium or other high temperature metal and alloys thereof. For ferrous matrices, alloys suitable for use as the base metal include cast iron, carbon steels, stainless steels and iron-based superalloys.

Method of making metal matrix composites reinforced with ceramic particulates

DOEpatents

Cornie, J.A.; Kattamis, T.; Chambers, B.V.; Bond, B.E.; Varela, R.H.

1989-08-01

Composite materials and methods for making such materials are disclosed in which dispersed ceramic particles are at chemical equilibrium with a base metal matrix, thereby permitting such materials to be remelted and subsequently cast or otherwise processed to form net weight parts and other finished (or semi-finished) articles while maintaining the microstructure and mechanical properties (e.g. wear resistance or hardness) of the original composite. The composite materials of the present invention are composed of ceramic particles in a base metal matrix. The ceramics are preferably carbides of titanium, zirconium, tungsten, molybdenum or other refractory metals. The base metal can be iron, nickel, cobalt, chromium or other high temperature metal and alloys thereof. For ferrous matrices, alloys suitable for use as the base metal include cast iron, carbon steels, stainless steels and iron-based superalloys. 2 figs.

Microcrystalline-cellulose and polypropylene based composite: A simple, selective and effective material for microwavable packaging.

PubMed

Ummartyotin, S; Pechyen, C

2016-05-20

Cellulose based composite was successfully designed as active packaging with additional feature of microwavable properties. Small amount of cellulose with 10 μm in diameter was integrated into polypropylene matrix. The use of maleic anhydride was employed as coupling agent. Thermal and mechanical properties of cellulose based composite were superior depending on polypropylene matrix. Crystallization temperature and compressive strength were estimated to be 130 °C and 5.5 MPa. The crystal formation and its percentage were therefore estimated to be 50% and it can be predicted on the feasibility of microwavable packaging. Morphological properties of cellulose based composite presented the good distribution and excellent uniformity. It was remarkable to note that cellulose derived from cotton can be prepared as composite with polypropylene matrix. It can be used as packaging for microwave application. Copyright © 2016 Elsevier Ltd. All rights reserved.

Advanced composites: Fabrication processes for selected resin matrix materials

NASA Technical Reports Server (NTRS)

Welhart, E. K.

1976-01-01

This design note is based on present state of the art for epoxy and polyimide matrix composite fabrication technology. Boron/epoxy and polyimide and graphite/epoxy and polyimide structural parts can be successfully fabricated. Fabrication cycles for polyimide matrix composites have been shortened to near epoxy cycle times. Nondestructive testing has proven useful in detecting defects and anomalies in composite structure elements. Fabrication methods and tooling materials are discussed along with the advantages and disadvantages of different tooling materials. Types of honeycomb core, material costs and fabrication methods are shown in table form for comparison. Fabrication limits based on tooling size, pressure capabilities and various machining operations are also discussed.

Modeling the Stress Strain Behavior of Woven Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Morscher, Gregory N.

2006-01-01

Woven SiC fiber reinforced SiC matrix composites represent one of the most mature composite systems to date. Future components fabricated out of these woven ceramic matrix composites are expected to vary in shape, curvature, architecture, and thickness. The design of future components using woven ceramic matrix composites necessitates a modeling approach that can account for these variations which are physically controlled by local constituent contents and architecture. Research over the years supported primarily by NASA Glenn Research Center has led to the development of simple mechanistic-based models that can describe the entire stress-strain curve for composite systems fabricated with chemical vapor infiltrated matrices and melt-infiltrated matrices for a wide range of constituent content and architecture. Several examples will be presented that demonstrate the approach to modeling which incorporates a thorough understanding of the stress-dependent matrix cracking properties of the composite system.

Solidification of Magnesium (AM50A) / vol%. SiCp composite

NASA Astrophysics Data System (ADS)

Zhang, X.; Hu, H.

2012-01-01

Magnesium matrix composite is one of the advanced lightweight materials with high potential to be used in automotive and aircraft industries due to its low density and high specific mechanical properties. The magnesium composites can be fabricated by adding the reinforcements of fibers or/and particles. In the previous literature, extensive studies have been performed on the development of matrix grain structure of aluminum-based metal matrix composites. However, there is limited information available on the development of grain structure during the solidification of particulate-reinforced magnesium. In this work, a 5 vol.% SiCp particulate-reinforced magnesium (AM50A) matrix composite (AM50A/SiCp) was prepared by stir casting. The solidification behavior of the cast AM50A/SiCp composite was investigated by computer-based thermal analysis. Optical and scanning electron microscopies (SEM) were employed to examine the occurrence of nucleation and grain refinement involved. The results indicate that the addition of SiCp particulates leads to a finer grain structure in the composite compared with the matrix alloy. The refinement of grain structure should be attributed to both the heterogeneous nucleation and the restricted primary crystal growth.

Micro-mechanics modelling of smart materials

NASA Astrophysics Data System (ADS)

Shah, Syed Asim Ali

Metal Matrix ceramic-reinforced composites are rapidly becoming strong candidates as structural materials for many high temperature and engineering applications. Metal matrix composites (MMC) combine the ductile properties of the matrix with a brittle phase of the reinforcement, leading to high stiffness and strength with a reduction in structural weight. The main objective of using a metal matrix composite system is to increase service temperature or improve specific mechanical properties of structural components by replacing existing super alloys.The purpose of the study is to investigate, develop and implement second phase reinforcement alloy strengthening empirical model with SiCp reinforced A359 aluminium alloy composites on the particle-matrix interface and the overall mechanical properties of the material.To predict the interfacial fracture strength of aluminium, in the presence of silicon segregation, an empirical model has been modified. This model considers the interfacial energy caused by segregation of impurities at the interface and uses Griffith crack type arguments to predict the formation energies of impurities at the interface. Based on this, model simulations were conducted at nano scale specifically at the interface and the interfacial strengthening behaviour of reinforced aluminium alloy system was expressed in terms of elastic modulus.The numerical model shows success in making prediction possible of trends in relation to segregation and interfacial fracture strength behaviour in SiC particle-reinforced aluminium matrix composites. The simulation models using various micro scale modelling techniques to the aluminum alloy matrix composite, strengthenedwith varying amounts of silicon carbide particulate were done to predict the material state at critical points with properties of Al-SiC which had been heat treated.In this study an algorithm is developed to model a hard ceramic particle in a soft matrix with a clear distinct interface and a strain based relationship has been proposed for the strengthening behaviour of the MMC at the interface rather than stress based, by successfully completing the numerical modelling of particulate reinforced metal matrix composites.

Parametric studies to determine the effect of compliant layers on metal matrix composite systems

NASA Technical Reports Server (NTRS)

Caruso, J. J.; Chamis, C. C.; Brown, H. C.

1990-01-01

Computational simulation studies are conducted to identify compliant layers to reduce matrix stresses which result from the coefficient of thermal expansion mismatch and the large temperature range over which the current metal matrix composites will be used. The present study includes variations of compliant layers and their properties to determine their influence on unidirectional composite and constituent response. Two simulation methods are used for these studies. The first approach is based on a three-dimensional linear finite element analysis of a 9 fiber unidirectional composite system. The second approach is a micromechanics based nonlinear computer code developed to determine the behavior of metal matrix composite system for thermal and mechanical loads. The results show that an effective compliant layer for the SCS 6 (SiC)/Ti-24Al-11Nb (Ti3Al + Nb) and SCS 6 (SiC)/Ti-15V-3Cr-3Sn-3Al (Ti-15-3) composite systems should have modulus 15 percent that of the matrix and a coefficient of thermal expansion of the compliant layer roughly equal to that of the composite system without the CL. The matrix stress in the longitudinal and the transverse tangent (loop) direction are tensile for the Ti3Al + Nb and Ti-15-3 composite systems upon cool down from fabrication. The fiber longitudinal stress is compressive from fabrication cool down. Addition of a recommended compliant layer will result in a reduction in the composite modulus.

Investigations on Mechanical Behaviour of Micro Graphite Particulates Reinforced Al-7Si Alloy Composites

NASA Astrophysics Data System (ADS)

Nagaraj, N.; Mahendra, K. V.; Nagaral, Madeva

2018-02-01

Micro particulates reinforced metal matrix composites are finding wide range of applications in automotive and sports equipment manufacturing industries. In the present study, an attempt has been made to develop Al-7Si-micro graphite particulates reinforced composites by using liquid melt method. 3 and 6 wt. % of micro graphite particulates were added to the Al-7Si base matrix. Microstructural characterization was done by using scanning electron microscope and energy dispersive spectroscope. Mechanical behaviour of Al-7Si-3 and 6 wt. % composites were evaluated as per ASTM standards. Scanning electron micrographs revealed the uniform distribution of micro graphite particulates in the Al-7Si alloy matrix. EDS analysis confirmed the presence of B and C elements in graphite reinforced composites. Further, it was noted that ultimate tensile and yield strength of Al-7Si alloy increased with the addition of 3 and 6wt. % of graphite particulates. Hardness of graphite reinforced composites was lesser than the base matrix.

The oxidative stability of carbon fibre reinforced glass-matrix composites

NASA Technical Reports Server (NTRS)

Prewo, K. M.; Batt, J. A.

1988-01-01

The environmental stability of carbon fibre reinforced glass-matrix composites is assessed. Loss of composite strength due to oxidative exposure at elevated temperatures under no load, static load and cyclic fatigue as well as due to thermal cycling are all examined. It is determined that strength loss is gradual and predictable based on the oxidation of carbon fibres. The glass matrix was not found to prevent this degradation but simply to limit it to a gradual process progressing from the composite surfaces inward.

Structural materials for NASP

NASA Astrophysics Data System (ADS)

Ronald, Terence M. F.

1991-12-01

Structural materials for the NASP X-30 experimental vehicle are briefly reviewed including titanium alloys, titanium-based metal-matrix composites, carbon-carbon composites, ceramic-matrix composites, and copper-matrix composites. Areas of application of these materials include the airframe where these materials would be used as lightweight skin panels for honeycomb-core, truss-core, or integrally stiffened thin sheet configuration; and the engine, where they would be used in the hot gas path of the ramjet/scramjet, and in the inlet and nozzle areas.

Study of piezoelectric filler on the properties of PZT-PVDF composites

NASA Astrophysics Data System (ADS)

Matei, Alina; Å¢ucureanu, Vasilica; Vlǎzan, Paulina; Cernica, Ileana; Popescu, Marian; RomaniÅ£an, Cosmin

2017-12-01

The ability to obtain composites with desired functionalities is based on advanced knowledge of the processes synthesis and of the structure of piezoceramic materials, as well the incorporation of different fillers in selected polymer matrix. Polyvinylidene fluoride (PVDF) is a fluorinated polymer with excellent mechanical and electric properties, which it was chosen as matrix due to their applications in a wide range of industrial fields [1-4]. The present paper focuses on the development of composites based on PZT particles as filler obtained by conventional methods and PVDF as polymer matrix. The synthesis of PVDF-PZT composites was obtained by dispersing the ceramic powders in a solution of PVDF in N-methyl-pyrrolidone (NMP) under mechanical mixing and ultrasonication, until a homogenous mixture is obtained. The properties of the piezoceramic fillers before and after embedding into the polymeric matrix were investigated by Fourier transform infrared spectrometry, field emission scanning electron microscopy and X-ray diffraction. In the FTIR spectra, appear a large number of absorption bands which are exclusive of the phases from PVDF matrix confirming the total embedding of PZT filler into matrix. Also, the XRD pattern of the composites has confirmed the presence of crystalline phases of PVDF and the ceramic phase of PZT. The SEM results showed a good distribution of fillers in the matrix.

Fuzzy Reasoning to More Accurately Determine Void Areas on Optical Micrographs of Composite Structures

NASA Technical Reports Server (NTRS)

Dominquez, Jesus A.; Tate, Lanetra C.; Wright, M. Clara; Caraccio, Anne

2013-01-01

Accomplishing the best-performing composite matrix (resin) requires that not only the processing method but also the cure cycle generate low-void-content structures. If voids are present, the performance of the composite matrix will be significantly reduced. This is usually noticed by significant reductions in matrix-dominated properties, such as compression and shear strength. Voids in composite materials are areas that are absent of the composite components: matrix and fibers. The characteristics of the voids and their accurate estimation are critical to determine for high performance composite structures. One widely used method of performing void analysis on a composite structure sample is acquiring optical micrographs or Scanning Electron Microscope (SEM) images of lateral sides of the sample and retrieving the void areas within the micrographs/images using an image analysis technique. Segmentation for the retrieval and subsequent computation of void areas within the micrographs/images is challenging as the gray-scaled values of the void areas are close to the gray-scaled values of the matrix leading to the need of manually performing the segmentation based on the histogram of the micrographs/images to retrieve the void areas. The use of an algorithm developed by NASA and based on Fuzzy Reasoning (FR) proved to overcome the difficulty of suitably differentiate void and matrix image areas with similar gray-scaled values leading not only to a more accurate estimation of void areas on composite matrix micrographs but also to a faster void analysis process as the algorithm is fully autonomous.

Unified continuum damage model for matrix cracking in composite rotor blades

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pollayi, Hemaraju; Harursampath, Dineshkumar

This paper deals with modeling of the first damage mode, matrix micro-cracking, in helicopter rotor/wind turbine blades and how this effects the overall cross-sectional stiffness. The helicopter/wind turbine rotor system operates in a highly dynamic and unsteady environment leading to severe vibratory loads present in the system. Repeated exposure to this loading condition can induce damage in the composite rotor blades. These rotor/turbine blades are generally made of fiber-reinforced laminated composites and exhibit various competing modes of damage such as matrix micro-cracking, delamination, and fiber breakage. There is a need to study the behavior of the composite rotor system undermore » various key damage modes in composite materials for developing Structural Health Monitoring (SHM) system. Each blade is modeled as a beam based on geometrically non-linear 3-D elasticity theory. Each blade thus splits into 2-D analyzes of cross-sections and non-linear 1-D analyzes along the beam reference curves. Two different tools are used here for complete 3-D analysis: VABS for 2-D cross-sectional analysis and GEBT for 1-D beam analysis. The physically-based failure models for matrix in compression and tension loading are used in the present work. Matrix cracking is detected using two failure criterion: Matrix Failure in Compression and Matrix Failure in Tension which are based on the recovered field. A strain variable is set which drives the damage variable for matrix cracking and this damage variable is used to estimate the reduced cross-sectional stiffness. The matrix micro-cracking is performed in two different approaches: (i) Element-wise, and (ii) Node-wise. The procedure presented in this paper is implemented in VABS as matrix micro-cracking modeling module. Three examples are presented to investigate the matrix failure model which illustrate the effect of matrix cracking on cross-sectional stiffness by varying the applied cyclic load.« less

Modeling the Nonlinear, Strain Rate Dependent Deformation of Woven Ceramic Matrix Composites With Hydrostatic Stress Effects Included

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.; Carney, Kelly S.

2004-01-01

An analysis method based on a deformation (as opposed to damage) approach has been developed to model the strain rate dependent, nonlinear deformation of woven ceramic matrix composites with a plain weave fiber architecture. In the developed model, the differences in the tension and compression response have also been considered. State variable based viscoplastic equations originally developed for metals have been modified to analyze the ceramic matrix composites. To account for the tension/compression asymmetry in the material, the effective stress and effective inelastic strain definitions have been modified. The equations have also been modified to account for the fact that in an orthotropic composite the in-plane shear stiffness is independent of the stiffness in the normal directions. The developed equations have been implemented into a commercially available transient dynamic finite element code, LS-DYNA, through the use of user defined subroutines (UMATs). The tensile, compressive, and shear deformation of a representative plain weave woven ceramic matrix composite are computed and compared to experimental results. The computed values correlate well to the experimental data, demonstrating the ability of the model to accurately compute the deformation response of woven ceramic matrix composites.

Comparison Of Models Of Metal-Matrix Composites

NASA Technical Reports Server (NTRS)

Bigelow, C. A.; Johnson, W. S.; Naik, R. A.

1994-01-01

Report presents comparative review of four mathematical models of micromechanical behaviors of fiber/metal-matrix composite materials. Models differ in various details, all based on properties of fiber and matrix constituent materials, all involve square arrays of fibers continuous and parallel and all assume complete bonding between constituents. Computer programs implementing models used to predict properties and stress-vs.-strain behaviors of unidirectional- and cross-ply laminated composites made of boron fibers in aluminum matrices and silicon carbide fibers in titanium matrices. Stresses in fiber and matrix constituent materials also predicted.

Proceedings of the Japan - U.S. Conference on Composite Materials (6th) Held in Orlando, Florida on June 22-24, 1992

DTIC Science & Technology

1993-03-01

correlation was determined between the matrix microplastic flow and the global composite tensile stress-strain curve. Based on the knowledge of the...framentation of the elastic matrix to form remnant elastic pockets at Silw tip surrounded y the matrix plastic flow. The matrix microplasticity is also...Deformation of SiC-Al Composites.’ Mater. Sci. Engng., A131:55-68. 11. Hamann, R., P. F. Gobin, and R. Fougeres, 1990. "A Study of the Microplasticity of Some

Investigation of Laser Generation and Detection of Ultrasound in Ceramic Matrix Composites and Intermetallics

NASA Technical Reports Server (NTRS)

Ehrlich, Michael J.

1998-01-01

The goal of this program is to assess the feasibility of using laser based ultrasonic techniques for inspecting and characterizing materials of interest to NASA, specifically those used in propulsion and turbomachinery applications, such as ceramic composites, metal matrix composites, and intermetallics.

A Numerical Method for Simulating the Microscopic Damage Evolution in Composites Under Uniaxial Transverse Tension

NASA Astrophysics Data System (ADS)

Zhi, Jie; Zhao, Libin; Zhang, Jianyu; Liu, Zhanli

2016-06-01

In this paper, a new numerical method that combines a surface-based cohesive model and extended finite element method (XFEM) without predefining the crack paths is presented to simulate the microscopic damage evolution in composites under uniaxial transverse tension. The proposed method is verified to accurately capture the crack kinking into the matrix after fiber/matrix debonding. A statistical representative volume element (SRVE) under periodic boundary conditions is used to approximate the microstructure of the composites. The interface parameters of the cohesive models are investigated, in which the initial interface stiffness has a great effect on the predictions of the fiber/matrix debonding. The detailed debonding states of SRVE with strong and weak interfaces are compared based on the surface-based and element-based cohesive models. The mechanism of damage in composites under transverse tension is described as the appearance of the interface cracks and their induced matrix micro-cracking, both of which coalesce into transversal macro-cracks. Good agreement is found between the predictions of the model and the in situ experimental observations, demonstrating the efficiency of the presented model for simulating the microscopic damage evolution in composites.

Tribological properties and lubrication mechanism of in situ graphene-nickel matrix composite impregnated with lubricating oil

NASA Astrophysics Data System (ADS)

Lei, Yu; Du, Jinfang; Pang, Xianjuan; Wang, Haizhong; Yang, Hua; Jiang, Jinlong

2018-05-01

A solid-liquid synergetic lubricating system has been designed to develop a novel self-lubricating nickel matrix composite. The graphene-nickel (G-Ni) matrix composite with porous structure was fabricated by in situ growing graphene in bulk nickel using a powder metallurgy method. The porous structures of the composite were used to store polyalphaolefin (PAO) oil for self-lubricating. It is found that the G-Ni matrix composite under oil lubrication condition exhibited superior tribological properties as compared to pure nickel and the composite under dry sliding condition. The prestored oil was released from pores to the sliding surface forming a lubricating oil film during friction process. This lubricating oil film can protect the worn surface from severe oxidation, and help the formation and transfer of a carbon-based solid tribofilm derived from graphene and lubricating oil. This solid (graphene)-liquid (oil) synergistic lubricating mechanism is responsible for the reduction of friction coefficient and improvement of wear resistance of the in situ fabricated G-Ni matrix composite.

Computational Simulation of Continuous Fiber-Reinforced Ceramic Matrix Composites Behavior

NASA Technical Reports Server (NTRS)

Murthy, Pappu L. N.; Chamis, Christos C.; Mital, Subodh K.

1996-01-01

This report describes a methodology which predicts the behavior of ceramic matrix composites and has been incorporated in the computational tool CEMCAN (CEramic Matrix Composite ANalyzer). The approach combines micromechanics with a unique fiber substructuring concept. In this new concept, the conventional unit cell (the smallest representative volume element of the composite) of the micromechanics approach is modified by substructuring it into several slices and developing the micromechanics-based equations at the slice level. The methodology also takes into account nonlinear ceramic matrix composite (CMC) behavior due to temperature and the fracture initiation and progression. Important features of the approach and its effectiveness are described by using selected examples. Comparisons of predictions and limited experimental data are also provided.

USE OF COMBUSTION SYNTHESIS IN PREPARING CERAMIC-MATRIX AND METAL-MATRIX COMPOSITE POWDERS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weil, K. Scott; Hardy, John S.

A standard combustion-based approach typically used to synthesize nanosize oxide powders has been modified to prepare composite oxide-metal powders for subsequent densification via sintering or hot-pressing into ceramic- or metal-matrix composites. Copper and cerium nitrate salts were dissolved in the appropriate ratio in water and combined with glycine, then heated to cause autoignition. The ratio of glycine-to-total nitrate concentration was found to have the largest effect on the composition, agglomerate size, crystallite size, and dispersivity of phases in the powder product. After consolidation and sintering under reducing conditions, the resulting composite compact consists of a well-dispersed mixture of sub-micron sizemore » reinforcement particles in a fine-grained matrix.« less

Critical Needs for Robust and Reliable Database for Design and Manufacturing of Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Singh, M.

1999-01-01

Ceramic matrix composite (CMC) components are being designed, fabricated, and tested for a number of high temperature, high performance applications in aerospace and ground based systems. The critical need for and the role of reliable and robust databases for the design and manufacturing of ceramic matrix composites are presented. A number of issues related to engineering design, manufacturing technologies, joining, and attachment technologies, are also discussed. Examples of various ongoing activities in the area of composite databases. designing to codes and standards, and design for manufacturing are given.

Laminated Object Manufacturing-Based Design Ceramic Matrix Composites

DTIC Science & Technology

2001-04-01

components for DoD applications. Program goals included the development of (1) a new LOM based design methodology for CMC, (2) optimized preceramic polymer ...3.1.1-20 3.1.1-12 Detail of LOM Composites Forming System w/ glass fiber/ polymer laminate................ 3.1.1-21 3.1.1-13...such as polymer matrix composites have faced similar barriers to implementation. These barriers have been overcome through the development of suitable

Bio-Based Nanocomposites: An Alternative to Traditional Composites

ERIC Educational Resources Information Center

Tate, Jitendra S.; Akinola, Adekunle T.; Kabakov, Dmitri

2009-01-01

Polymer matrix composites (PMC), often referred to as fiber reinforced plastics (FRP), consist of fiber reinforcement (E-glass, S2-glass, aramid, carbon, or natural fibers) and polymer matrix/resin (polyester, vinyl ester, polyurethane, phenolic, and epoxies). Eglass/ polyester and E-glass/vinyl ester composites are extensively used in the marine,…

Stress and Damage in Polymer Matrix Composite Materials Due to Material Degradation at High Temperatures

NASA Technical Reports Server (NTRS)

McManus, Hugh L.; Chamis, Christos C.

1996-01-01

This report describes analytical methods for calculating stresses and damage caused by degradation of the matrix constituent in polymer matrix composite materials. Laminate geometry, material properties, and matrix degradation states are specified as functions of position and time. Matrix shrinkage and property changes are modeled as functions of the degradation states. The model is incorporated into an existing composite mechanics computer code. Stresses, strains, and deformations at the laminate, ply, and micro levels are calculated, and from these calculations it is determined if there is failure of any kind. The rationale for the model (based on published experimental work) is presented, its integration into the laminate analysis code is outlined, and example results are given, with comparisons to existing material and structural data. The mechanisms behind the changes in properties and in surface cracking during long-term aging of polyimide matrix composites are clarified. High-temperature-material test methods are also evaluated.

Concurrent tailoring of fabrication process and interphase layer to reduce residual stresses in metal matrix composites

NASA Technical Reports Server (NTRS)

Saravanos, D. A.; Chamis, C. C.; Morel, M.

1991-01-01

A methodology is presented to reduce the residual matrix stresses in continuous fiber metal matrix composites (MMC) by optimizing the fabrication process and interphase layer characteristics. The response of the fabricated MMC was simulated based on nonlinear micromechanics. Application cases include fabrication tailoring, interphase tailoring, and concurrent fabrication-interphase optimization. Two composite systems, silicon carbide/titanium and graphite/copper, are considered. Results illustrate the merits of each approach, indicate that concurrent fabrication/interphase optimization produces significant reductions in the matrix residual stresses and demonstrate the strong coupling between fabrication and interphase tailoring.

Ceramic matrix composite behavior -- Computational simulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chamis, C.C.; Murthy, P.L.N.; Mital, S.K.

Development of analytical modeling and computational capabilities for the prediction of high temperature ceramic matrix composite behavior has been an ongoing research activity at NASA-Lewis Research Center. These research activities have resulted in the development of micromechanics based methodologies to evaluate different aspects of ceramic matrix composite behavior. The basis of the approach is micromechanics together with a unique fiber substructuring concept. In this new concept the conventional unit cell (the smallest representative volume element of the composite) of micromechanics approach has been modified by substructuring the unit cell into several slices and developing the micromechanics based equations at themore » slice level. Main advantage of this technique is that it can provide a much greater detail in the response of composite behavior as compared to a conventional micromechanics based analysis and still maintains a very high computational efficiency. This methodology has recently been extended to model plain weave ceramic composites. The objective of the present paper is to describe the important features of the modeling and simulation and illustrate with select examples of laminated as well as woven composites.« less

A creep cavity growth model for creep-fatigue life prediction of a unidirectional W/Cu composite

NASA Astrophysics Data System (ADS)

Kim, Young-Suk; Verrilli, Michael J.; Halford, Gary R.

1992-05-01

A microstructural model was developed to predict creep-fatigue life in a (0)(sub 4), 9 volume percent tungsten fiber-reinforced copper matrix composite at the temperature of 833 K. The mechanism of failure of the composite is assumed to be governed by the growth of quasi-equilibrium cavities in the copper matrix of the composite, based on the microscopically observed failure mechanisms. The methodology uses a cavity growth model developed for prediction of creep fracture. Instantaneous values of strain rate and stress in the copper matrix during fatigue cycles were calculated and incorporated in the model to predict cyclic life. The stress in the copper matrix was determined by use of a simple two-bar model for the fiber and matrix during cyclic loading. The model successfully predicted the composite creep-fatigue life under tension-tension cyclic loading through the use of this instantaneous matrix stress level. Inclusion of additional mechanisms such as cavity nucleation, grain boundary sliding, and the effect of fibers on matrix-stress level would result in more generalized predictions of creep-fatigue life.

A creep cavity growth model for creep-fatigue life prediction of a unidirectional W/Cu composite

NASA Technical Reports Server (NTRS)

Kim, Young-Suk; Verrilli, Michael J.; Halford, Gary R.

1992-01-01

A microstructural model was developed to predict creep-fatigue life in a (0)(sub 4), 9 volume percent tungsten fiber-reinforced copper matrix composite at the temperature of 833 K. The mechanism of failure of the composite is assumed to be governed by the growth of quasi-equilibrium cavities in the copper matrix of the composite, based on the microscopically observed failure mechanisms. The methodology uses a cavity growth model developed for prediction of creep fracture. Instantaneous values of strain rate and stress in the copper matrix during fatigue cycles were calculated and incorporated in the model to predict cyclic life. The stress in the copper matrix was determined by use of a simple two-bar model for the fiber and matrix during cyclic loading. The model successfully predicted the composite creep-fatigue life under tension-tension cyclic loading through the use of this instantaneous matrix stress level. Inclusion of additional mechanisms such as cavity nucleation, grain boundary sliding, and the effect of fibers on matrix-stress level would result in more generalized predictions of creep-fatigue life.

Universal composition-structure-property maps for natural and biomimetic platelet-matrix composites and stacked heterostructures.

PubMed

Sakhavand, Navid; Shahsavari, Rouzbeh

2015-03-16

Many natural and biomimetic platelet-matrix composites--such as nacre, silk, and clay-polymer-exhibit a remarkable balance of strength, toughness and/or stiffness, which call for a universal measure to quantify this outstanding feature given the structure and material characteristics of the constituents. Analogously, there is an urgent need to quantify the mechanics of emerging electronic and photonic systems such as stacked heterostructures. Here we report the development of a unified framework to construct universal composition-structure-property diagrams that decode the interplay between various geometries and inherent material features in both platelet-matrix composites and stacked heterostructures. We study the effects of elastic and elastic-perfectly plastic matrices, overlap offset ratio and the competing mechanisms of platelet versus matrix failures. Validated by several 3D-printed specimens and a wide range of natural and synthetic materials across scales, the proposed universally valid diagrams have important implications for science-based engineering of numerous platelet-matrix composites and stacked heterostructures.

Composite materials: Fatigue and fracture. Vol. 3

NASA Technical Reports Server (NTRS)

O'Brien, T. K. (Editor)

1991-01-01

The present volume discusses topics in the fields of matrix cracking and delamination, interlaminar fracture toughness, delamination analysis, strength and impact characteristics, and fatigue and fracture behavior. Attention is given to cooling rate effects in carbon-reinforced PEEK, the effect of porosity on flange-web corner strength, mode II delamination in toughened composites, the combined effect of matrix cracking and free edge delamination, and a 3D stress analysis of plain weave composites. Also discussed are the compression behavior of composites, damage-based notched-strength modeling, fatigue failure processes in aligned carbon-epoxy laminates, and the thermomechanical fatigue of a quasi-isotropic metal-matrix composite.

Mechanics of Platelet-Matrix Composites across Scales: Theory, Multiscale Modeling, and 3D Fabrication

NASA Astrophysics Data System (ADS)

Sakhavand, Navid

Many natural and biomimetic composites - such as nacre, silk and clay-polymer - exhibit a remarkable balance of strength, toughness, and/or stiffness, which call for a universal measure to quantify this outstanding feature given the platelet-matrix structure and material characteristics of the constituents. Analogously, there is an urgent need to quantify the mechanics of emerging electronic and photonic systems such as stacked heterostructures, which are composed of strong in-plane bonding networks but weak interplanar bonding matrices. In this regard, development of a universal composition-structure-property map for natural platelet-matrix composites, and stacked heterostructures opens up new doors for designing materials with superior mechanical performance. In this dissertation, a multiscale bottom-up approach is adopted to analyze and predict the mechanical properties of platelet-matrix composites. Design guidelines are provided by developing universally valid (across different length scales) diagrams for science-based engineering of numerous natural and synthetic platelet-matrix composites and stacked heterostructures while significantly broadening the spectrum of strategies for fabricating new composites with specific and optimized mechanical properties. First, molecular dynamics simulations are utilized to unravel the fundamental underlying physics and chemistry of the binding nature at the atomic-level interface of organic-inorganic composites. Polymer-cementitious composites are considered as case studies to understand bonding mechanism at the nanoscale and open up new venues for potential mechanical enhancement at the macro-scale. Next, sophisticated mathematical derivations based on elasticity and plasticity theories are presented to describe pre-crack (intrinsic) mechanical performance of platelet-matrix composites at the microscale. These derivations lead to developing a unified framework to construct series of universal composition-structure-property maps that decode the interplay between various geometries and inherent material features, encapsulated in a few dimensionless parameters. Finally, after crack mechanical properties (extrinsic) of platelet-matrix composites until ultimate failure of the material at the macroscale is investigated via combinatorial finite element simulations. The effect of different composition-structure-property parameters on mechanical properties synergies are depicted via 2D and 3D maps. 3D-printed specimens are fabricated and tested against the theoretical prediction. The combination of the presented diagrams and guidelines paves the path toward platelet-matrix composites and stacked-heterostructures with superior and optimized mechanical properties.

Ceramics reinforced metal base composite coatings produced by CO II laser cladding

NASA Astrophysics Data System (ADS)

Yang, Xichen; Wang, Yu; Yang, Nan

2008-03-01

Due to the excellent performance in high strength, anti-temperature and anti-wear, ceramics reinforced metal base composite material was used in some important fields of aircraft, aerospace, automobile and defense. The traditional bulk metal base composite materials are the expensive cost, which is limited in its industrial application. Development of laser coating of ceramics reinforced metal base composite is very interesting in economy. This paper is focused on three laser cladding ceramics coatings of SiC particle /Al matrix , Al IIO 3 powder/ Al matrix and WC + Co/mild steel matrix. Powder particle sizes are of 10-60μm. Chemical contents of aluminum matrix are of 3.8-4.0% Cu, 1.2-1.8% Mg, 0.3-0.99% Mn and balance Al. 5KW CO II laser, 5 axes CNC table, JKF-6 type powder feeder and co-axis feeder nozzle are used in laser cladding. Microstructure and performance of laser composite coatings have been respectively examined with OM,SEM and X-ray diffraction. Its results are as follows : Microstructures of 3C-,6H- and 5H- SiC particles + Al + Al 4SiC 4 + Si in SiC/Al composite, hexagonal α-Al IIO 3 + cubic γ-Al IIO 3 + f.c.c Al in Al IIO 3 powder/ Al composite and original WC particles + separated WC particles + eutectic WC + γ-Co solid solution + W IIC particles in WC + Co/steel coatings are respectively recognized. New microstructures of 5H-SiC in SiC/Al composite, cubic γ-Al IIO 3 in Al IIO 3 composite and W IIC in WC + Co/ steel composite by laser cladding have been respectively observed.

Electrochemical Behavior of Al-B4C Metal Matrix Composites in NaCl Solution

PubMed Central

Han, Yu-Mei; Chen, X.-Grant

2015-01-01

Aluminum based metal matrix composites (MMCs) have received considerable attention in the automotive, aerospace and nuclear industries. One of the main challenges using Al-based MMCs is the influence of the reinforcement particles on the corrosion resistance. In the present study, the corrosion behavior of Al-B4C MMCs in a 3.5 wt.% NaCl solution were investigated using potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) techniques. Results indicated that the corrosion resistance of the composites decreased when increasing the B4C volume fraction. Al-B4C composite was susceptible to pitting corrosion and two types of pits were observed on the composite surface. The corrosion mechanism of the composite in the NaCl solution was primarily controlled by oxygen diffusion in the solution. In addition, the galvanic couples that formed between Al matrix and B4C particles could also be responsible for the lower corrosion resistance of the composites. PMID:28793574

Design and analysis of aerospace structures at elevated temperatures. [aircraft, missiles, and space platforms

NASA Technical Reports Server (NTRS)

Chang, C. I.

1989-01-01

An account is given of approaches that have emerged as useful in the incorporation of thermal loading considerations into advanced composite materials-based aerospace structural design practices. Sources of structural heating encompass not only propulsion system heat and aerodynamic surface heating at supersonic speeds, but the growing possibility of intense thermal fluxes from directed-energy weapons. The composite materials in question range from intrinsically nonheat-resistant polymer matrix systems to metal-matrix composites, and increasingly to such ceramic-matrix composites as carbon/carbon, which are explicitly intended for elevated temperature operation.

Influence of Sea Water Aging on the Mechanical Behaviour of Acrylic Matrix Composites

NASA Astrophysics Data System (ADS)

Davies, P.; Le Gac, P.-Y.; Le Gall, M.

2017-02-01

A new matrix resin was recently introduced for composite materials, based on acrylic resin chemistry allowing standard room temperature infusion techniques to be used to produce recyclable thermoplastic composites. This is a significant advance, particularly for more environmentally-friendly production of large marine structures such as boats. However, for such applications it is essential to demonstrate that composites produced with these resins resist sea water exposure in service. This paper presents results from a wet aging study of unreinforced acrylic and glass and carbon fibre reinforced acrylic composites. It is shown that the acrylic matrix resin is very stable in seawater, showing lower property losses after seawater aging than those of a commonly-used epoxy matrix resin. Carbon fibre reinforced acrylic also shows good property retention after aging, while reductions in glass fibre reinforced composite strengths suggest that specific glass fibre sizing may be required for optimum durability.

Mechanical properties of green composites based on thermoplastic starch

NASA Astrophysics Data System (ADS)

Fornes, F.; Sánchez-Nácher, L.; Fenollar, O.; Boronat, T.; Garcia-Sanoguera, D.

2010-06-01

The present work is focused on study of "green composites" elaborated from thermoplastic starch (TPS) as polymer matrix and a fiber from natural origin (rush) as reinforced fiber. The effect of the fiber content has been studied by means of the mechanical properties. The composite resulting presents a lack of interaction between matrix and fiber that represents a performance decrease. However the biodegradability behavior of the resulting composite raise this composite as useful an industrial level.

Computational Simulation of the High Strain Rate Tensile Response of Polymer Matrix Composites

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.

2002-01-01

A research program is underway to develop strain rate dependent deformation and failure models for the analysis of polymer matrix composites subject to high strain rate impact loads. Under these types of loading conditions, the material response can be highly strain rate dependent and nonlinear. State variable constitutive equations based on a viscoplasticity approach have been developed to model the deformation of the polymer matrix. The constitutive equations are then combined with a mechanics of materials based micromechanics model which utilizes fiber substructuring to predict the effective mechanical and thermal response of the composite. To verify the analytical model, tensile stress-strain curves are predicted for a representative composite over strain rates ranging from around 1 x 10(exp -5)/sec to approximately 400/sec. The analytical predictions compare favorably to experimentally obtained values both qualitatively and quantitatively. Effective elastic and thermal constants are predicted for another composite, and compared to finite element results.

Nonlinear behavior of matrix-inclusion composites under high confining pressure: application to concrete and mortar

NASA Astrophysics Data System (ADS)

Le, Tuan Hung; Dormieux, Luc; Jeannin, Laurent; Burlion, Nicolas; Barthélémy, Jean-François

2008-08-01

This paper is devoted to a micromechanics-based simulation of the response of concrete to hydrostatic and oedometric compressions. Concrete is described as a composite made up of a cement matrix in which rigid inclusions are embedded. The focus is put on the role of the interface between matrix and inclusion which represent the interfacial transition zone (ITZ). A plastic behavior is considered for both the matrix and the interfaces. The effective response of the composite is derived from the modified secant method adapted to the situation of imperfect interfaces. To cite this article: T.H. Le et al., C. R. Mecanique 336 (2008).

Technology Base Enhancement Program. Metal Matrix Composites

DTIC Science & Technology

1993-08-30

efficiency, improved structural reliability, and reduced maintenance when compared to carbon fiber reinforced composites . Aerospace engines (in particular...different materials. The composite consists of a metal matrix reinforced with particulates, flakes, whiskers,3 continuous fibers , filaments, wires, or...graphite and carbon to metals. They come in three general forms: particulates (or particles) with a length to diameter ratio of about 1; chopped fibers or

Ceramic matrix composite article and process of fabricating a ceramic matrix composite article

DOEpatents

Cairo, Ronald Robert; DiMascio, Paul Stephen; Parolini, Jason Robert

2016-01-12

A ceramic matrix composite article and a process of fabricating a ceramic matrix composite are disclosed. The ceramic matrix composite article includes a matrix distribution pattern formed by a manifold and ceramic matrix composite plies laid up on the matrix distribution pattern, includes the manifold, or a combination thereof. The manifold includes one or more matrix distribution channels operably connected to a delivery interface, the delivery interface configured for providing matrix material to one or more of the ceramic matrix composite plies. The process includes providing the manifold, forming the matrix distribution pattern by transporting the matrix material through the manifold, and contacting the ceramic matrix composite plies with the matrix material.

Preparation of SiC based Aluminium metal matrix nano composites by high intensity ultrasonic cavitation process and evaluation of mechanical and tribological properties

NASA Astrophysics Data System (ADS)

Murthy, N. V.; Prasad Reddy, A.; Selvaraj, N.; Rao, C. S. P.

2016-09-01

Request augments on a worldwide scale for the new materials. The metal matrix nano composites can be used in numerous applications of helicopter structural parts, gas turbine exit guide vane's, space shuttle, and other structural applications. The key mailman to ameliorate performance of composite matrix in aluminium alloy metal reinforces nano particles in the matrix of alloy uniformly, which ameliorates composite properties without affecting limit of ductility. The ultrasonic assisted stir casting helped agitation was successfully used to fabricate Al 2219 metal matrix of alloy reinforced with (0.5, 1, 1.5 and 2) wt.% of nano silicon carbide (SiC) particles of different sizes 50nm and 150nm. The micrographs of scanning electron microscopy of nano composite were investigated it reveals that the uniform dispersion of nano particles silicon carbide in aluminium alloy 2219 matrix and with the low porosity. How the specific wear rate was vary with increasing weight percentage of nano particles at constant load and speed as shown in results and discussions. And the mechanical properties showed that the ultimate tensile strength and hardness of metal matrix nano composite AA 2219 / nano SiC of 50nm and 150nm lean to augment with increase weight percentage of silicon carbide content in the matrix alloy.

Modeling Geometry and Progressive Failure of Material Interfaces in Plain Weave Composites

NASA Technical Reports Server (NTRS)

Hsu, Su-Yuen; Cheng, Ron-Bin

2010-01-01

A procedure combining a geometrically nonlinear, explicit-dynamics contact analysis, computer aided design techniques, and elasticity-based mesh adjustment is proposed to efficiently generate realistic finite element models for meso-mechanical analysis of progressive failure in textile composites. In the procedure, the geometry of fiber tows is obtained by imposing a fictitious expansion on the tows. Meshes resulting from the procedure are conformal with the computed tow-tow and tow-matrix interfaces but are incongruent at the interfaces. The mesh interfaces are treated as cohesive contact surfaces not only to resolve the incongruence but also to simulate progressive failure. The method is employed to simulate debonding at the material interfaces in a ceramic-matrix plain weave composite with matrix porosity and in a polymeric matrix plain weave composite without matrix porosity, both subject to uniaxial cyclic loading. The numerical results indicate progression of the interfacial damage during every loading and reverse loading event in a constant strain amplitude cyclic process. However, the composites show different patterns of damage advancement.

Material Processing and Design of Biodegradable Metal Matrix Composites for Biomedical Applications.

PubMed

Yang, Jingxin; Guo, Jason L; Mikos, Antonios G; He, Chunyan; Cheng, Guang

2018-06-04

In recent years, biodegradable metallic materials have played an important role in biomedical applications. However, as typical for the metal materials, their structure, general properties, preparation technology and biocompatibility are hard to change. Furthermore, biodegradable metals are susceptible to excessive degradation and subsequent disruption of their mechanical integrity; this phenomenon limits the utility of these biomaterials. Therefore, the use of degradable metals, as the base material to prepare metal matrix composite materials, it is an excellent alternative to solve the problems above described. Biodegradable metals can thus be successfully combined with other materials to form biodegradable metallic matrix composites for biomedical applications and functions. The present article describes the processing methods currently available to design biodegradable metal matrix composites for biomedical applications and provides an overview of the current existing biodegradable metal systems. At the end, the manuscript presents and discusses the challenges and future research directions for development of biodegradable metallic matrix composites for biomedical purposes.

Microtensile Test of AN Ordered-Reinforced Electrophoretic Polymer Matrix Composite Fabricated by Surface Micromachining

NASA Astrophysics Data System (ADS)

Yang, Zhuoqing; Wang, Hong; Zhang, Zhenjie; Ding, Guifu; Zhao, Xiaolin

A novel ordered-reinforced microscale polymer matrix composite based on electrophoresis and surface micromachining technologies has been proposed in the present work. The braid angle, volume content and width of the reinforcement in the composite has been designed and simulated by ANSYS finite element software. Based on the simulation and optimization, the Ni fibers reinforced polymer matrix composite sample (3 mm length × 0.6 mm width × 0.04 mm thickness) was successfully fabricated utilizing the surface micromachining process. The fabricated samples were characterized by microtensile test on the dynamic mechanical analysis (DMA) equipment. It is indicated that the tested tensile strength and Young's modulus are 285 MPa and 6.8 GPa, respectively. In addition, the fracture section of the composite sample has been observed by scanning electron microscope (SEM) and the corresponding fracture process was also explained and analyzed in detail. The new presented composite is promising for hot embossing mold in microfluidic chip and several transducers used in accurately controlled biomedical systems.

Analysis of Fiber Clustering in Composite Materials Using High-Fidelity Multiscale Micromechanics

NASA Technical Reports Server (NTRS)

Bednarcyk, Brett A.; Aboudi, Jacob; Arnold, Steven M.

2015-01-01

A new multiscale micromechanical approach is developed for the prediction of the behavior of fiber reinforced composites in presence of fiber clustering. The developed method is based on a coupled two-scale implementation of the High-Fidelity Generalized Method of Cells theory, wherein both the local and global scales are represented using this micromechanical method. Concentration tensors and effective constitutive equations are established on both scales and linked to establish the required coupling, thus providing the local fields throughout the composite as well as the global properties and effective nonlinear response. Two nondimensional parameters, in conjunction with actual composite micrographs, are used to characterize the clustering of fibers in the composite. Based on the predicted local fields, initial yield and damage envelopes are generated for various clustering parameters for a polymer matrix composite with both carbon and glass fibers. Nonlinear epoxy matrix behavior is also considered, with results in the form of effective nonlinear response curves, with varying fiber clustering and for two sets of nonlinear matrix parameters.

The prospects for composites based on boron fibers

NASA Technical Reports Server (NTRS)

Naslain, R.

1978-01-01

The fabrication of boron filaments and the production of composite materials consisting of boron filaments and organic or metallic matrices are discussed. Problem involving the use of tungsten substrates in the filament fabrication process, the protection of boron fibers with diffusion barrier cladings, and the application of alloy additives in the matrix to lessen the effects of diffusion are considered. Data on the kinetics of the boron fiber/matrix interaction at high temperatures, and the influence of the fiber/matrix interaction on the mechanical properties of the composite are presented.

Stress and Damage in Polymer Matrix Composite Materials Due to Material Degradation at High Temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mcmanus, H.L.; Chamis, C.C.

1996-01-01

This report describes analytical methods for calculating stresses and damage caused by degradation of the matrix constituent in polymer matrix composite materials. Laminate geometry, material properties, and matrix degradation states are specified as functions of position and time. Matrix shrinkage and property changes are modeled as functions of the degradation states. The model is incorporated into an existing composite mechanics computer code. Stresses, strains, and deformations at the laminate, ply, and micro levels are calculated, and from these calculations it is determined if there is failure of any kind. The rationale for the model (based on published experimental work) ismore » presented, its integration into the laminate analysis code is outlined, and example results are given, with comparisons to existing material and structural data. The mechanisms behind the changes in properties and in surface cracking during long-term aging of polyimide matrix composites are clarified. High-temperature-material test methods are also evaluated.« less

Implementation of Fiber Substructuring Into Strain Rate Dependent Micromechanics Analysis of Polymer Matrix Composites

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.

2001-01-01

A research program is in progress to develop strain rate dependent deformation and failure models for the analysis of polymer matrix composites subject to impact loads. Previously, strain rate dependent inelastic constitutive equations developed to model the polymer matrix were incorporated into a mechanics of materials based micromechanics method. In the current work, the micromechanics method is revised such that the composite unit cell is divided into a number of slices. Micromechanics equations are then developed for each slice, with laminate theory applied to determine the elastic properties, effective stresses and effective inelastic strains for the unit cell. Verification studies are conducted using two representative polymer matrix composites with a nonlinear, strain rate dependent deformation response. The computed results compare well to experimentally obtained values.

Electrical condition monitoring method for polymers

DOEpatents

Watkins, Jr., Kenneth S.; Morris, Shelby J [Hampton, VA; Masakowski, Daniel D [Worcester, MA; Wong, Ching Ping [Duluth, GA; Luo, Shijian [Boise, ID

2008-08-19

An electrical condition monitoring method utilizes measurement of electrical resistivity of an age sensor made of a conductive matrix or composite disposed in a polymeric structure such as an electrical cable. The conductive matrix comprises a base polymer and conductive filler. The method includes communicating the resistivity to a measuring instrument and correlating resistivity of the conductive matrix of the polymeric structure with resistivity of an accelerated-aged conductive composite.

High-Strain-Rate Constitutive Characterization and Modeling of Metal Matrix Composites

DTIC Science & Technology

2014-03-07

protective coatings. Even though most MMCs studied to date are aluminum matrix composites, magnesium and its alloys have also been considered to be... plastic response of the matrix. Based on a simple analysis of the effect of misalignments of microscale kinks, Argon estimated that the compressive... deformations ; if the fibers break into small enough pieces, their stiffening effect could be reduced. We are examining both possibilities to explain

Study of the structure of 3-D composites based on carbon nanotubes in bovine serum albumin matrix by X-ray microtomography

NASA Astrophysics Data System (ADS)

Ignatov, D.; Zhurbina, N.; Gerasimenko, A.

2017-01-01

3-D composites are widely used in tissue engineering. A comprehensive analysis by X-ray microtomography was conducted to study the structure of the 3-D composites. Comprehensive analysis of the structure of the 3-D composites consisted of scanning, image reconstruction of shadow projections, two-dimensional and three-dimensional visualization of the reconstructed images and quantitative analysis of the samples. Experimental samples of composites were formed by laser vaporization of the aqueous dispersion BSA and single-walled (SWCNTs) and multi-layer (MWCNTs) carbon nanotubes. The samples have a homogeneous structure over the entire volume, the percentage of porosity of 3-D composites based on SWCNTs and MWCNTs - 16.44%, 28.31%, respectively. An average pore diameter of 3-D composites based on SWCNTs and MWCNTs - 45 μm 93 μm. 3-D composites based on carbon nanotubes in bovine serum albumin matrix can be used in tissue engineering of bone and cartilage, providing cell proliferation and blood vessel sprouting.

Development and Validation of a Shear Punch Test Fixture

DTIC Science & Technology

2013-08-01

composites (MMC) manufactured by friction stir processing (FSP) that are being developed as part of a Technology Investment Fund (TIF) project, as the...leading a team of government departments and academics to develop a friction stir processing (FSP) based procedure to create metal matrix composite... friction stir process to fabricate surface metal matrix composites in aluminum alloys for potential application in light armoured vehicles. The

Properties Of Carbon/Carbon and Carbon/Phenolic Composites

NASA Technical Reports Server (NTRS)

Mathis, John R.; Canfield, A. R.

1993-01-01

Report presents data on physical properties of carbon-fiber-reinforced carbon-matrix and phenolic-matrix composite materials. Based on tests conducted on panels, cylinders, blocks, and formed parts. Data used by designers to analyze thermal-response and stress levels and develop structural systems ensuring high reliability at minimum weight.

Polymeric dental composites based on remineralizing amorphous calcium phosphate fillers

PubMed Central

Skrtic, Drago; Antonucci, Joseph M.

2017-01-01

For over two decades we have systematically explored structure-composition-property relationships of amorphous calcium phosphate (ACP)-based polymeric dental composites. The appeal of these bioactive materials stems from their intrinsic ability to prevent demineralization and/or restore defective tooth structures via sustained release of remineralizing calcium and phosphate ions. Due to the compositional similarity of the ACP to biological tooth mineral, ACP-based composites should exhibit excellent biocompatibility. Research described in this article has already yielded remineralizing sealants and orthodontic adhesives as well as a prototype root canal sealer. Our work has also contributed to a better understanding on how polymer matrix structure and filler/matrix interactions affect the critical properties of these polymeric composites and their overall performance. The addition of antimicrobial compounds to the formulation of ACP composites could increase their medical and dental regenerative treatment applications, thereby benefiting an even greater number of patients. PMID:29599572

Probabilistic micromechanics for metal matrix composites

NASA Astrophysics Data System (ADS)

Engelstad, S. P.; Reddy, J. N.; Hopkins, Dale A.

A probabilistic micromechanics-based nonlinear analysis procedure is developed to predict and quantify the variability in the properties of high temperature metal matrix composites. Monte Carlo simulation is used to model the probabilistic distributions of the constituent level properties including fiber, matrix, and interphase properties, volume and void ratios, strengths, fiber misalignment, and nonlinear empirical parameters. The procedure predicts the resultant ply properties and quantifies their statistical scatter. Graphite copper and Silicon Carbide Titanlum Aluminide (SCS-6 TI15) unidirectional plies are considered to demonstrate the predictive capabilities. The procedure is believed to have a high potential for use in material characterization and selection to precede and assist in experimental studies of new high temperature metal matrix composites.

Thermal Degradation, Mechanical Properties and Morphology of Wheat Straw Flour Filled Recycled Thermoplastic Composites

PubMed Central

Mengeloglu, Fatih; Karakus, Kadir

2008-01-01

Thermal behaviors of wheat straw flour (WF) filled thermoplastic composites were measured applying the thermogravimetric analysis and differential scanning calorimetry. Morphology and mechanical properties were also studied using scanning electron microscope and universal testing machine, respectively. Presence of WF in thermoplastic matrix reduced the degradation temperature of the composites. One for WF and one for thermoplastics, two main decomposition peaks were observed. Morphological study showed that addition of coupling agent improved the compatibility between WFs and thermoplastic. WFs were embedded into the thermoplastic matrix indicating improved adhesion. However, the bonding was not perfect because some debonding can also be seen on the interface of WFs and thermoplastic matrix. In the case of mechanical properties of WF filled recycled thermoplastic, HDPE and PP based composites provided similar tensile and flexural properties. The addition of coupling agents improved the properties of thermoplastic composites. MAPE coupling agents performed better in HDPE while MAPP coupling agents were superior in PP based composites. The composites produced with the combination of 50-percent mixture of recycled HDPE and PP performed similar with the use of both coupling agents. All produced composites provided flexural properties required by the ASTM standard for polyolefin-based plastic lumber decking boards. PMID:27879719

Role of segregation and precipitates on interfacial strengthening mechanisms in metal matrix composites when subjected to thermo-mechanical processing

NASA Astrophysics Data System (ADS)

Myriounis, Dimitrios

Metal Matrix ceramic-reinforced composites are rapidly becoming strong candidates as structural materials for many high temperatures and aerospace applications. Metal matrix composites combine the ductile properties of the matrix with a brittle phase of the reinforcement, leading to high stiffness and strength with a reduction in structural weight. The main objective of using a metal matrix composite system is to increase service temperature or improve specific mechanical properties of structural components by replacing existing superalloys.The satisfactory performance of metal matrix composites depends critically on their integrity, the heart of which is the quality of the matrix-reinforcement interface. The nature of the interface depends on the processing of the metal matrix composite component. At the micro-level the development of local stress concentration gradients around the ceramic reinforcement, as the metal matrix attempts to deform during processing, can be very different to the nominal conditions and play a crucial role in important microstructural events such as segregation and precipitation at the matrix-reinforcement interface. These events dominate the cohesive strength and subsequent mechanical properties of the interface.At present the relationship between the strength properties of metal matrix composites and the details of the thermo-mechanical forming processes is not well understood.The purpose of the study is to investigate several strengthening mechanisms and the effect of thermo-mechanical processing of SiCp reinforced A359 aluminium alloy composites on the particle-matrix interface and the overall mechanical properties of the material. From experiments performed on composite materials subjected to various thermo-mechanical conditions and by observation using SEM microanalysis and mechanical testing, data were obtained, summarised and mathematically/statistically analysed upon their significance.The Al/SiCp composites studied, processed in specific thermo-mechanical conditions in order to attain higher values of interfacial fracture strength, due to precipitation hardening and segregation mechanisms, also exhibited enhanced bulk mechanical and fracture resistant properties.An analytical model to predict the interfacial fracture strength in the presence of material segregation was also developed during this research effort. Its validity was determined based on the data gathered from the experiments.The tailoring of the properties due to the microstructural modification of the composites was examined in relation to the experimental measurements obtained, which define the macroscopical behaviour of the material.

Characterization of Al/crystallized Al-based metallic glass composites produced by repeated roll bonding process

NASA Astrophysics Data System (ADS)

Alizadeh, Morteza; Khoramkhorshid, Saba; Taghvaei, Amir Hossein; Gokuldoss, Prashanth Konda

2017-07-01

Devitrified Al84Gd6Ni7Co3 glassy particles have been used to reinforce Al-matrix composites through repeated roll bonding (RRB) process. Microstructural characterization of the produced composites after various rolling cycles was performed by scanning electron microscopy. Mechanical properties of the fabricated composites were evaluated by the tensile and microhardness tests. The results indicate that the RRB process is successful to produce composites with the negligible amount of flaws and porosity, and it is followed by homogeneous distribution of Al84Gd6Ni7Co3 particles in the Al matrix after nine rolling passes. Elongation of the composites improves significantly upon RRB cycles and the tensile strength and microhardness of them increase more than two times compared to unreinforced Al. According to fractography results, the enhanced mechanical properties are correlated with formation of excellent bonding at the interface of Al84Gd6Ni7Co3 particles and Al matrix. The theoretical values of composites hardness and yield strength calculated based on iso-strain model show a good agreement with respect to the experimental results.

The effect of powder composition on the morphology of in situ TiC composite coating deposited by Laser-Assisted Powder Deposition (LAPD)

NASA Astrophysics Data System (ADS)

Emamian, Ali; Corbin, Stephen F.; Khajepour, Amir

2012-11-01

In this paper, the effect of powder composition on in situ TiC formation within an Fe-based matrix coating during laser cladding was studied. Different atomic ratios of C:Ti (45% and 55%) were selected in order to adjust the matrix from an Fesbnd Ti-based composition to an Fesbnd C-based one. Fe percentages of 70, 60, 50 and 10 wt% were explored to increase the volume fraction of TiC in the clad. Results showed that chemical composition affects the TiC morphology as well as the TiC distribution and hardness profile in the clad. By increasing the C:Ti ratio from 45 at% to 55 at%, the volume fraction of the formed TiC increases. A higher volume fraction of TiC in the clad resulted in increases clad hardness. SEM and EDS analyses were used to characterize the phases in the clad, while increasing the C ratio promoted the formation of excess graphite in the Fe matrix.

Method Developed for Improving the Thermomechanical Properties of Silicon Carbide Matrix Composites

NASA Technical Reports Server (NTRS)

Bhatt, Ramakrishna T.; DiCarlo, James A.

2004-01-01

Today, a major thrust for achieving engine components with improved thermal capability is the development of fiber-reinforced silicon-carbide (SiC) matrix composites. These materials are not only lighter and capable of higher use temperatures than state-of-the-art metallic alloys and oxide matrix composites (approx. 1100 C), but they can provide significantly better static and dynamic toughness than unreinforced silicon-based monolithic ceramics. However, for successful application in advanced engine systems, the SiC matrix composites should be able to withstand component service stresses and temperatures for the desired component lifetime. Since the high-temperature structural life of ceramic materials is typically controlled by creep-induced flaw growth, a key composite property requirement is the ability to display high creep resistance under these conditions. Also, because of the possibility of severe thermal gradients in the components, the composites should provide maximum thermal conductivity to minimize the development of thermal stresses. State-of-the-art SiC matrix composites are typically fabricated via a three-step process: (1) fabrication of a component-shaped architectural preform reinforced by high-performance fibers, (2) chemical vapor infiltration of a fiber coating material such as boron nitride (BN) into the preform, and (3) infiltration of a SiC matrix into the remaining porous areas in the preform. Generally, the highest performing composites have matrices fabricated by the CVI process, which produces a SiC matrix typically more thermally stable and denser than matrices formed by other approaches. As such, the CVI SiC matrix is able to provide better environmental protection to the coated fibers, plus provide the composite with better resistance to crack propagation. Also, the denser CVI SiC matrix should provide optimal creep resistance and thermal conductivity to the composite. However, for adequate preform infiltration, the CVI SiC matrix process typically has to be conducted at temperatures below 1100 C, which results in a SiC matrix that is fairly dense, but contains metastable atomic defects and is nonstoichiometric because of a small amount of excess silicon. Because these defects typically exist at the matrix grain boundaries, they can scatter thermal phonons and degrade matrix creep resistance by enhancing grain-boundary sliding. To eliminate these defects and improve the thermomechanical properties of ceramic composites with CVI SiC matrices, researchers at the NASA Glenn Research Center developed a high-temperature treatment process that can be used after the CVI SiC matrix is deposited into the fiber preform.

Manufacturing Techniques for Titanium Aluminide Based Alloys and Metal Matrix Composites

DTIC Science & Technology

2010-01-01

aluminides are being used in the low pressure turbine (LPT) blades . In addition, titanium aluminides were also investigated for use in High Speed Civil... Titanium aluminides are also being used in General Electric’s GEnex gas turbine engine for the 6th and the 7th stage of the low pressure turbine blades ...ABSTRACT Title of Dissertation: MANUFACTURING TECHNIQUES FOR TITANIUM ALUMINIDE BASED ALLOYS AND METAL MATRIX COMPOSITES

Reuse of EAF Slag as Reinforcing Filler for Polypropylene Matrix Composites

NASA Astrophysics Data System (ADS)

Cornacchia, G.; Agnelli, S.; Gelfi, M.; Ramorino, G.; Roberti, R.

2015-06-01

Electric-arc furnace (EAF) slag, the by-product of steel fabricated at the EAF, is in most cases still sent to dumps, with serious environmental consequences. This work shows an innovative, economically convenient application for EAF slag: its use as reinforcing filler for polypropylene. Composites based on polypropylene containing 10-40 wt.% of EAF slag particles were prepared by melt compounding followed by injection molding. A physical-chemical analysis of the EAF slag was performed to determine microstructural features and main component phases. Leaching tests demonstrated that, although EAF slag can release small amounts of toxic elements, such as heavy metals, incorporating such material into the polymeric matrix immobilizes the heavy metals inside that matrix. The mechanical characterization of the polymer-based composites was performed. Incorporating EAF slag particles raises the Young's modulus and the tensile strength at yield, whereas elongation at break and the impact strength of the polymer-based composite are significantly reduced only when large amounts of filler are added, i.e., 30% or more.

Corrosion behavior and pitting susceptibility of in-situ Ti-based metallic glass matrix composites in 3.5 wt.% NaCl solutions

NASA Astrophysics Data System (ADS)

Xu, K. K.; Lan, A. D.; Yang, H. J.; Han, P. D.; Qiao, J. W.

2017-11-01

The Ti62Zr12V13Cu4Be9, Ti58Zr16V10Cu4Be12, Ti46Zr20V12Cu5Be17, and Ti40Zr24V12Cu5Be19 metallic glass matrix composites (MGMCs) were prepared by copper mould casting. The corrosion resistance and the pitting susceptibility of Ti-based MGMCs were tested on their cross-sectional areas in 3.5 wt.% NaCl solutions by potentiodynamic polarization measurements. The composites with lower Ti contents (Ti40Zr24V12Cu5Be19 and Ti46Zr20V12Cu5Be17) exhibit a low resistance to the chloride induced pitting and local corrosion. The preferential dissolution of amorphous matrix is explained by the high chemical reactivity of beryllium element compared to that of stable dendrites and by the detected lower Ti and V contents. However, fairly good passivity was found in the composite with higher Ti contents (Ti62Zr12V13Cu4Be9). XPS measurements revealed that protective Ti-enriched oxide film was formed on the composite surface, additionally, lower content of beryllium element in amorphous matrix hinder the selective corrosion of amorphous matrix. The assessment of experimental observation leads to a proposed corrosion mechanism involving selective dissolution of amorphous matrix and chloride induced pitting process.

Repair process and a repaired component

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roberts, III, Herbert Chidsey; Simpson, Stanley F.

Matrix composite component repair processes are disclosed. The matrix composite repair process includes applying a repair material to a matrix composite component, securing the repair material to the matrix composite component with an external securing mechanism and curing the repair material to bond the repair material to the matrix composite component during the securing by the external securing mechanism. The matrix composite component is selected from the group consisting of a ceramic matrix composite, a polymer matrix composite, and a metal matrix composite. In another embodiment, the repair process includes applying a partially-cured repair material to a matrix composite component,more » and curing the repair material to bond the repair material to the matrix composite component, an external securing mechanism securing the repair material throughout a curing period, In another embodiment, the external securing mechanism is consumed or decomposed during the repair process.« less

A differential CDM model for fatigue of unidirectional metal matrix composites

NASA Technical Reports Server (NTRS)

Arnold, S. M.; Kruch, S.

1992-01-01

A multiaxial, isothermal, continuum damage mechanics (CDM) model for fatigue of a unidirectional metal matrix composite volume element is presented. The model is phenomenological, stress based, and assumes a single scalar internal damage variable, the evolution of which is anisotropic. The development of the fatigue damage model, (i.e., evolutionary law) is based on the definition of an initially transversely isotropic fatigue limit surface, a static fracture surface, and a normalized stress amplitude function. The anisotropy of these surfaces and function, and therefore the model, is defined through physically meaningful invariants reflecting the local stress and material orientation. This transversely isotropic model is shown, when taken to it's isotropic limit, to directly simplify to a previously developed and validated isotropic fatigue continuum damage model. Results of a nondimensional parametric study illustrate (1) the flexibility of the present formulation in attempting to characterize a class of composite materials, and (2) the capability of the formulation in predicting anticipated qualitative trends in the fatigue behavior of unidirectional metal matrix composites. Also, specific material parameters representing an initial characterization of the composite system SiC/Ti 15-3 and the matrix material (Ti 15-3) are reported.

Additive Manufacturing of Silicon Carbide-Based Ceramic Matrix Composites: Technical Challenges and Opportunities

NASA Technical Reports Server (NTRS)

Singh, Mrityunjay; Halbig, Michael C.; Grady, Joseph E.

2016-01-01

Advanced SiC-based ceramic matrix composites offer significant contributions toward reducing fuel burn and emissions by enabling high overall pressure ratio (OPR) of gas turbine engines and reducing or eliminating cooling air in the hot-section components, such as shrouds, combustor liners, vanes, and blades. Additive manufacturing (AM), which allows high value, custom designed parts layer by layer, has been demonstrated for metals and polymer matrix composites. However, there has been limited activity on additive manufacturing of ceramic matrix composites (CMCs). In this presentation, laminated object manufacturing (LOM), binder jet process, and 3-D printing approaches for developing ceramic composite materials are presented. For the laminated object manufacturing (LOM), fiber prepreg laminates were cut into shape with a laser and stacked to form the desired part followed by high temperature heat treatments. For the binder jet, processing optimization was pursued through silicon carbide powder blending, infiltration with and without SiC nano powder loading, and integration of fibers into the powder bed. Scanning electron microscopy was conducted along with XRD, TGA, and mechanical testing. Various technical challenges and opportunities for additive manufacturing of ceramics and CMCs will be presented.

Micromechanical Modeling of Woven Metal Matrix Composites

NASA Technical Reports Server (NTRS)

Bednarcyk, Brett A.; Pindera, Marek-Jerzy

1997-01-01

This report presents the results of an extensive micromechanical modeling effort for woven metal matrix composites. The model is employed to predict the mechanical response of 8-harness (8H) satin weave carbon/copper (C/Cu) composites. Experimental mechanical results for this novel high thermal conductivity material were recently reported by Bednarcyk et al. along with preliminary model results. The micromechanics model developed herein is based on an embedded approach. A micromechanics model for the local (micro-scale) behavior of the woven composite, the original method of cells (Aboudi), is embedded in a global (macro-scale) micromechanics model (the three-dimensional generalized method of cells (GMC-3D) (Aboudi). This approach allows representation of true repeating unit cells for woven metal matrix composites via GMC-3D, and representation of local effects, such as matrix plasticity, yarn porosity, and imperfect fiber-matrix bonding. In addition, the equations of GMC-3D were reformulated to significantly reduce the number of unknown quantities that characterize the deformation fields at the microlevel in order to make possible the analysis of actual microstructures of woven composites. The resulting micromechanical model (WCGMC) provides an intermediate level of geometric representation, versatility, and computational efficiency with respect to previous analytical and numerical models for woven composites, but surpasses all previous modeling work by allowing the mechanical response of a woven metal matrix composite, with an elastoplastic matrix, to be examined for the first time. WCGMC is employed to examine the effects of composite microstructure, porosity, residual stresses, and imperfect fiber-matrix bonding on the predicted mechanical response of 8H satin C/Cu. The previously reported experimental results are summarized, and the model predictions are compared to monotonic and cyclic tensile and shear test data. By considering appropriate levels of porosity, residual stresses, and imperfect fiber-matrix debonding, reasonably good qualitative and quantitative correlation is achieved between model and experiment.

Carbide-reinforced metal matrix composite by direct metal deposition

NASA Astrophysics Data System (ADS)

Novichenko, D.; Thivillon, L.; Bertrand, Ph.; Smurov, I.

Direct metal deposition (DMD) is an automated 3D laser cladding technology with co-axial powder injection for industrial applications. The actual objective is to demonstrate the possibility to produce metal matrix composite objects in a single-step process. Powders of Fe-based alloy (16NCD13) and titanium carbide (TiC) are premixed before cladding. Volume content of the carbide-reinforced phase is varied. Relationships between the main laser cladding parameters and the geometry of the built-up objects (single track, 2D coating) are discussed. On the base of parametric study, a laser cladding process map for the deposition of individual tracks was established. Microstructure and composition of the laser-fabricated metal matrix composite objects are examined. Two different types of structures: (a) with the presence of undissolved and (b) precipitated titanium carbides are observed. Mechanism of formation of diverse precipitated titanium carbides is studied.

Processing of Hybrid Structures Consisting of Al-Based Metal Matrix Composites (MMCs) With Metallic Reinforcement of Steel or Titanium

DTIC Science & Technology

2013-09-01

637 2. S.V. Prasad and R. Asthana, "Aluminum Metal-Matrix Composites for Automotive Applications : Tribological Considerations," Tribology Leiters, 11...seeing widespread use in thermal management, precision equipment, and automotive applications where composition and microstructure are tailored to...Key applications include high specific stiffuess panels and beams, fluid flow structures, thermal management substrates, and blast wave mitigation

Damage development in titanium metal matrix composites subjected to cyclic loading

NASA Technical Reports Server (NTRS)

Johnson, W. S.

1992-01-01

Several layups of SCS-6/Ti-15-3 composites were investigated. Fatigue tests were conducted and analyzed for both notched and unnotched specimens at room temperature and elevated temperatures. Thermo-mechanical fatigue results were analyzed. Test results indicated that the stress in the 0 degree fibers is the controlling factor in fatigue life. The static and fatigue strength of these materials is shown to be strongly dependent on the level of residual stresses and the fiber/matrix interfacial strength. Fatigue tests of notched specimens showed that cracks can initiate and grow many fiber spacings in the matrix materials without breaking fibers. Fiber bridging models were applied to characterize the crack growth behavior. The matrix cracks are shown to significantly reduce the residual strength of notched composites. The notch strength of these composites was accurately predicted using a micromechanics based methodology.

Damage development in titanium metal-matrix composites subjected to cyclic loading

NASA Technical Reports Server (NTRS)

Johnson, W. S.

1993-01-01

Several layups of SCS-6/Ti-15-3 composites were investigated. Fatigue tests were conducted and analyzed for both notched and unnotched specimens at room temperature and elevated temperatures. Thermo-mechanical fatigue results were analyzed. Test results indicated that the stress in the 0 degree fibers is the controlling factor in fatigue life. The static and fatigue strength of these materials is shown to be strongly dependent on the level of residual stresses and the fiber/matrix interfacial strength. Fatigue tests of notched specimens showed that cracks can initiate and grow many fiber spacings in the matrix materials without breaking fibers. Fiber bridging models were applied to characterize the crack growth behavior. The matrix cracks are shown to significantly reduce the residual strength of notched composites. The notch strength of these composites was accurately predicted using a micromechanics based methodology.

A 3/D finite element approach for metal matrix composites based on micromechanical models

DOE Office of Scientific and Technical Information (OSTI.GOV)

Svobodnik, A.J.; Boehm, H.J.; Rammerstorfer, F.G.

Based on analytical considerations by Dvorak and Bahel-El-Din, a 3/D finite element material law has been developed for the elastic-plastic analysis of unidirectional fiber-reinforced metal matrix composites. The material law described in this paper has been implemented in the finite element code ABAQUS via the user subroutine UMAT. A constitutive law is described under the assumption that the fibers are linear-elastic and the matrix is of a von Mises-type with a Prager-Ziegler kinematic hardening rule. The uniaxial effective stress-strain relationship of the matrix in the plastic range is approximated by a Ramberg-Osgood law, a linear hardening rule or a nonhardeningmore » rule. Initial yield surface of the matrix material and for the fiber reinforced composite are compared to show the effect of reinforcement. Implementation of this material law in a finite element program is shown. Furthermore, the efficiency of substepping schemes and stress corrections for the numerical integration of the elastic-plastic stress-strain relations for anisotropic materials are investigated. The results of uniaxial monotonic tests of a boron/aluminum composite are compared to some finite element analyses based on micromechanical considerations. Furthermore a complete 3/D analysis of a tensile test specimen made of a silicon-carbide/aluminum MMC and the analysis of an MMC inlet inserted in a homogenous material are shown. 12 refs.« less

Numerical simulation of elasto-plastic deformation of composites: evolution of stress microfields and implications for homogenization models

NASA Astrophysics Data System (ADS)

González, C.; Segurado, J.; LLorca, J.

2004-07-01

The deformation of a composite made up of a random and homogeneous dispersion of elastic spheres in an elasto-plastic matrix was simulated by the finite element analysis of three-dimensional multiparticle cubic cells with periodic boundary conditions. "Exact" results (to a few percent) in tension and shear were determined by averaging 12 stress-strain curves obtained from cells containing 30 spheres, and they were compared with the predictions of secant homogenization models. In addition, the numerical simulations supplied detailed information of the stress microfields, which was used to ascertain the accuracy and the limitations of the homogenization models to include the nonlinear deformation of the matrix. It was found that secant approximations based on the volume-averaged second-order moment of the matrix stress tensor, combined with a highly accurate linear homogenization model, provided excellent predictions of the composite response when the matrix strain hardening rate was high. This was not the case, however, in composites which exhibited marked plastic strain localization in the matrix. The analysis of the evolution of the matrix stresses revealed that better predictions of the composite behavior can be obtained with new homogenization models which capture the essential differences in the stress carried by the elastic and plastic regions in the matrix at the onset of plastic deformation.

Investigation on Mechanical and Fatigue behaviour of Aluminium Based SiC/ZrO2 Particle Reinforced MMC

NASA Astrophysics Data System (ADS)

Ramesh, S.; Govindaraju, N.; Suryanarayan, C. P.

2018-04-01

The study is the work on Aluminium Metal Matrix Composites (MMC’s), which have wider applications in automobile, aerospace and defense industries, hi-tech engineering and power transmission due to their lightweight, high strength and other unique properties. The Aluminium Matrix Composites (AMC’s) refer to a kind of light weight high performance Aluminium centric material system. AMC’s consist of a non-metallic reinforcement which when included into aluminium matrix offers an advantage over the base material. Reinforcements like SiC, B4C, Al2O3, TiC, TiB2, TiO2 are normally preferred to improve mechanical properties of such composites. Here Aluminium 6061 is preferred as matrix material, while silicon carbide (SiC) and Zirconium di-oxide (ZrO2) is selected as reinforcement compounds. Conventional Stir casting procedure is employed to fabricate the necessary composites compositions, which are I. Al:SiC::100:5 and II. Al:ZrO2:SiC::100:3:2. Experimental results depict that the composition II provides higher hardness of 53.6 RHN as opposed to 45.8 RHN of composition I. In tensile strength composition II demonstrates 96.43 N/mm2 as opposed to 67.229 N/mm2 tensile strength of composition II. The fatigue test indicate a expected number of life cycles to failure of 105 cycles for composition II and over 104 cycles for composition I, at stress ranges of 79.062 MPa and 150.651 MPa respectively.

Time-dependent deformation of titanium metal matrix composites

NASA Technical Reports Server (NTRS)

Bigelow, C. A.; Bahei-El-din, Y. A.; Mirdamadi, M.

1995-01-01

A three-dimensional finite element program called VISCOPAC was developed and used to conduct a micromechanics analysis of titanium metal matrix composites. The VISCOPAC program uses a modified Eisenberg-Yen thermo-viscoplastic constitutive model to predict matrix behavior under thermomechanical fatigue loading. The analysis incorporated temperature-dependent elastic properties in the fiber and temperature-dependent viscoplastic properties in the matrix. The material model was described and the necessary material constants were determined experimentally. Fiber-matrix interfacial behavior was analyzed using a discrete fiber-matrix model. The thermal residual stresses due to the fabrication cycle were predicted with a failed interface, The failed interface resulted in lower thermal residual stresses in the matrix and fiber. Stresses due to a uniform transverse load were calculated at two temperatures, room temperature and an elevated temperature of 650 C. At both temperatures, a large stress concentration was calculated when the interface had failed. The results indicate the importance of accuracy accounting for fiber-matrix interface failure and the need for a micromechanics-based analytical technique to understand and predict the behavior of titanium metal matrix composites.

Temperature Dependence of Electrical Resistance of Woven Melt-Infiltrated SiCf/SiC Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Appleby, Matthew P.; Morscher, Gregory N.; Zhu, Dongming

2016-01-01

Recent studies have successfully shown the use of electrical resistance (ER)measurements to monitor room temperature damage accumulation in SiC fiber reinforced SiC matrix composites (SiCf/SiC) Ceramic Matrix Composites (CMCs). In order to determine the feasibility of resistance monitoring at elevated temperatures, the present work investigates the temperature dependent electrical response of various MI (Melt Infiltrated)-CVI (Chemical Vapor Infiltrated) SiC/SiC composites containing Hi-Nicalon Type S, Tyranno ZMI and SA reinforcing fibers. Test were conducted using a commercially available isothermal testing apparatus as well as a novel, laser-based heating approach developed to more accurately simulate thermomechanical testing of CMCs. Secondly, a post-test inspection technique is demonstrated to show the effect of high-temperature exposure on electrical properties. Analysis was performed to determine the respective contribution of the fiber and matrix to the overall composite conductivity at elevated temperatures. It was concluded that because the silicon-rich matrix material dominates the electrical response at high temperature, ER monitoring would continue to be a feasible method for monitoring stress dependent matrix cracking of melt-infiltrated SiC/SiC composites under high temperature mechanical testing conditions. Finally, the effect of thermal gradients generated during localized heating of tensile coupons on overall electrical response of the composite is determined.

Stochastic-Strength-Based Damage Simulation Tool for Ceramic Matrix and Polymer Matrix Composite Structures

NASA Technical Reports Server (NTRS)

Nemeth, Noel N.; Bednarcyk, Brett A.; Pineda, Evan J.; Walton, Owen J.; Arnold, Steven M.

2016-01-01

Stochastic-based, discrete-event progressive damage simulations of ceramic-matrix composite and polymer matrix composite material structures have been enabled through the development of a unique multiscale modeling tool. This effort involves coupling three independently developed software programs: (1) the Micromechanics Analysis Code with Generalized Method of Cells (MAC/GMC), (2) the Ceramics Analysis and Reliability Evaluation of Structures Life Prediction Program (CARES/ Life), and (3) the Abaqus finite element analysis (FEA) program. MAC/GMC contributes multiscale modeling capabilities and micromechanics relations to determine stresses and deformations at the microscale of the composite material repeating unit cell (RUC). CARES/Life contributes statistical multiaxial failure criteria that can be applied to the individual brittle-material constituents of the RUC. Abaqus is used at the global scale to model the overall composite structure. An Abaqus user-defined material (UMAT) interface, referred to here as "FEAMAC/CARES," was developed that enables MAC/GMC and CARES/Life to operate seamlessly with the Abaqus FEA code. For each FEAMAC/CARES simulation trial, the stochastic nature of brittle material strength results in random, discrete damage events, which incrementally progress and lead to ultimate structural failure. This report describes the FEAMAC/CARES methodology and discusses examples that illustrate the performance of the tool. A comprehensive example problem, simulating the progressive damage of laminated ceramic matrix composites under various off-axis loading conditions and including a double notched tensile specimen geometry, is described in a separate report.

Damping mathematical modelling and dynamic responses for FRP laminated composite plates with polymer matrix

NASA Astrophysics Data System (ADS)

Liu, Qimao

2018-02-01

This paper proposes an assumption that the fibre is elastic material and polymer matrix is viscoelastic material so that the energy dissipation depends only on the polymer matrix in dynamic response process. The damping force vectors in frequency and time domains, of FRP (Fibre-Reinforced Polymer matrix) laminated composite plates, are derived based on this assumption. The governing equations of FRP laminated composite plates are formulated in both frequency and time domains. The direct inversion method and direct time integration method for nonviscously damped systems are employed to solve the governing equations and achieve the dynamic responses in frequency and time domains, respectively. The computational procedure is given in detail. Finally, dynamic responses (frequency responses with nonzero and zero initial conditions, free vibration, forced vibrations with nonzero and zero initial conditions) of a FRP laminated composite plate are computed using the proposed methodology. The proposed methodology in this paper is easy to be inserted into the commercial finite element analysis software. The proposed assumption, based on the theory of material mechanics, needs to be further proved by experiment technique in the future.

On the Role of Processing Parameters in Producing Recycled Aluminum AA6061 Based Metal Matrix Composite (MMC-AlR) Prepared Using Hot Press Forging (HPF) Process

PubMed Central

Ahmad, Azlan; Lajis, Mohd Amri

2017-01-01

Solid-state recycling, which involves the direct recycling of scrap metal into bulk material using severe plastic deformation, has emerged as a potential alternative to the conventional remelting and recycling techniques. Hot press forging has been identified as a sustainable direct recycling technique that has fewer steps and maintains excellent material performance. An experimental investigation was conducted to explore the hardness and density of a recycled aluminum-based metal matrix composite by varying operating temperature and holding time. A mixture of recycled aluminum, AA6061, and aluminum oxide were simultaneously heated to 430, 480, and 530 °C and forged for 60, 90, and 120 min. We found a positive increase in microhardness and density for all composites. The hardness increased approximately 33.85%, while density improved by about 15.25% whenever the temperature or the holding time were increased. Based on qualitative analysis, the composite endures substantial plastic deformation due to the presence of hardness properties due to the aluminum oxide embedded in the aluminum matrix. These increases were significantly affected by the operating temperature; the holding time also had a subordinate role in enhancing the metal matrix composite properties. Furthermore, in an effort to curb the shortage of primary resources, this study reviewed the promising performance of secondary resources produced by using recycled aluminum and aluminum oxide as the base matrix and reinforcement constituent, respectively. This study is an outline for machining practitioners and the manufacturing industry to help increase industry sustainability with the aim of preserving the Earth for our community in the future. PMID:28925963

On the Role of Processing Parameters in Producing Recycled Aluminum AA6061 Based Metal Matrix Composite (MMC-AlR) Prepared Using Hot Press Forging (HPF) Process.

PubMed

Ahmad, Azlan; Lajis, Mohd Amri; Yusuf, Nur Kamilah

2017-09-19

Solid-state recycling, which involves the direct recycling of scrap metal into bulk material using severe plastic deformation, has emerged as a potential alternative to the conventional remelting and recycling techniques. Hot press forging has been identified as a sustainable direct recycling technique that has fewer steps and maintains excellent material performance. An experimental investigation was conducted to explore the hardness and density of a recycled aluminum-based metal matrix composite by varying operating temperature and holding time. A mixture of recycled aluminum, AA6061, and aluminum oxide were simultaneously heated to 430, 480, and 530 °C and forged for 60, 90, and 120 min. We found a positive increase in microhardness and density for all composites. The hardness increased approximately 33.85%, while density improved by about 15.25% whenever the temperature or the holding time were increased. Based on qualitative analysis, the composite endures substantial plastic deformation due to the presence of hardness properties due to the aluminum oxide embedded in the aluminum matrix. These increases were significantly affected by the operating temperature; the holding time also had a subordinate role in enhancing the metal matrix composite properties. Furthermore, in an effort to curb the shortage of primary resources, this study reviewed the promising performance of secondary resources produced by using recycled aluminum and aluminum oxide as the base matrix and reinforcement constituent, respectively. This study is an outline for machining practitioners and the manufacturing industry to help increase industry sustainability with the aim of preserving the Earth for our community in the future.

A Study on 3-Body Abrasive Wear Behaviour of Aluminium 8011 / Graphite Metal Matrix Composite

NASA Astrophysics Data System (ADS)

Latha Shankar, B.; Anil, K. C.; Patil, Rahul

2016-09-01

Metals and alloys have found their vital role in many applications like structural, corrosive, tribological, etc., in engineering environment. The alloys/composites having high strength to low weight ratio have gained attention of many researchers recently. In this work, graphite reinforced Aluminium 8011 metal matrix composite was prepared by conventional stir casting route, by varying the weight % of reinforcement. Uniform distribution of Graphite in matrix alloy was confirmed by optical micrographs. Prepared composite specimens were subjected to 3-body abrasive testing by varying applied load and time, the silica particles of 400 grit size were used as abrasive particles. It was observed that with the increase of weight% of Graphite the wear resistance of composite was also increasing and on comparison it was found that reinforced composite gives good wear resistance than base alloy.

Analytical prediction of moisture absorption/desorption in resin matrix composites exposed to aircraft environments

NASA Technical Reports Server (NTRS)

Unnam, J.; Tenney, D. R.

1977-01-01

The moisture absorption/desorption behavior of resin matrix composites was mathematically modeled by classical diffusion theory using an effective diffusion coefficient. Good agreement was found between calculated moisture content and published data for T300/5208 graphite fiber reinforced epoxy matrix composite. Weather Bureau data for Langley Air Force Base and Norfolk, Va., were used to calculate the amount of moisture a T300/5208 composite panel would contain if exposed outdoors. Results obtained by using average monthly weather data for several high aircraft usage locations around the world suggest that, except for desert areas, geographical locations should have only minimal effect on the moisture absorption level reached in composites. Solar radiation data together with cloud and wind information were included in the analysis to estimate an effective temperature of the composite panel during ground exposure.

Phase Stability and Thermal Conductivity of Composite Environmental Barrier Coatings on SiC/SiC Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Benkel, Samantha; Zhu, Dongming

2011-01-01

Advanced environmental barrier coatings are being developed to protect SiC/SiC ceramic matrix composites in harsh combustion environments. The current coating development emphasis has been placed on the significantly improved cyclic durability and combustion environment stability in high-heat-flux and high velocity gas turbine engine environments. Environmental barrier coating systems based on hafnia (HfO2) and ytterbium silicate, HfO2-Si nano-composite bond coat systems have been processed and their stability and thermal conductivity behavior have been evaluated in simulated turbine environments. The incorporation of Silicon Carbide Nanotubes (SiCNT) into high stability (HfO2) and/or HfO2-silicon composite bond coats, along with ZrO2, HfO2 and rare earth silicate composite top coat systems, showed promise as excellent environmental barriers to protect the SiC/SiC ceramic matrix composites.

Nanocellular foam with solid flame retardant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Liang; Kelly-Rowley, Anne M.; Bunker, Shana P.

Prepare nanofoam by (a) providing an aqueous solution of a flame retardant dissolved in an aqueous solvent, wherein the flame retardant is a solid at 23.degree. C. and 101 kiloPascals pressure when in neat form; (b) providing a fluid polymer composition selected from a solution of polymer dissolved in a water-miscible solvent or a latex of polymer particles in a continuous aqueous phase; (c) mixing the aqueous solution of flame retardant with the fluid polymer composition to form a mixture; (d) removing water and, if present, solvent from the mixture to produce a polymeric composition having less than 74 weight-percentmore » flame retardant based on total polymeric composition weight; (e) compound the polymeric composition with a matrix polymer to form a matrix polymer composition; and (f) foam the matrix polymer composition into nanofoam having a porosity of at least 60 percent.« less

METCAN-PC - METAL MATRIX COMPOSITE ANALYZER

NASA Technical Reports Server (NTRS)

Murthy, P. L.

1994-01-01

High temperature metal matrix composites offer great potential for use in advanced aerospace structural applications. The realization of this potential however, requires concurrent developments in (1) a technology base for fabricating high temperature metal matrix composite structural components, (2) experimental techniques for measuring their thermal and mechanical characteristics, and (3) computational methods to predict their behavior. METCAN (METal matrix Composite ANalyzer) is a computer program developed to predict this behavior. METCAN can be used to computationally simulate the non-linear behavior of high temperature metal matrix composites (HT-MMC), thus allowing the potential payoff for the specific application to be assessed. It provides a comprehensive analysis of composite thermal and mechanical performance. METCAN treats material nonlinearity at the constituent (fiber, matrix, and interphase) level, where the behavior of each constituent is modeled accounting for time-temperature-stress dependence. The composite properties are synthesized from the constituent instantaneous properties by making use of composite micromechanics and macromechanics. Factors which affect the behavior of the composite properties include the fabrication process variables, the fiber and matrix properties, the bonding between the fiber and matrix and/or the properties of the interphase between the fiber and matrix. The METCAN simulation is performed as point-wise analysis and produces composite properties which are readily incorporated into a finite element code to perform a global structural analysis. After the global structural analysis is performed, METCAN decomposes the composite properties back into the localized response at the various levels of the simulation. At this point the constituent properties are updated and the next iteration in the analysis is initiated. This cyclic procedure is referred to as the integrated approach to metal matrix composite analysis. METCAN-PC is written in FORTRAN 77 for IBM PC series and compatible computers running MS-DOS. An 80286 machine with an 80287 math co-processor is required for execution. The executable requires at least 640K of RAM and DOS 3.1 or higher. The package includes sample executables which were compiled under Microsoft FORTRAN v. 5.1. The standard distribution medium for this program is one 5.25 inch 360K MS-DOS format diskette. The contents of the diskette are compressed using the PKWARE archiving tools. The utility to unarchive the files, PKUNZIP.EXE, is included. METCAN-PC was developed in 1992.

SiC/SiC Composites: The Effect of Fiber Type and Fiber Architecture on Mechanical Properties

NASA Technical Reports Server (NTRS)

Morscher, Gregory N.

2008-01-01

Woven SiC/SiC composites represent a broad family of composites with a broad range of properties which are of interest for many energy-based and aero-based applications. Two important features of SiC/SiC composites which one must consider are the reinforcing fibers themselves and the fiber-architecture they are formed into. The range of choices for these two features can result in a wide range of elastic, mechanical, thermal, and electrical properties. In this presentation, it will be demonstrated how the effect of fiber-type and fiber architecture effects the important property of "matrix cracking stress" for slurry-cast melt-infiltrated SiC matrix composites, which is often considered to be a critical design parameter for this system of composites.

A coupled/uncoupled deformation and fatigue damage algorithm utilizing the finite element method

NASA Technical Reports Server (NTRS)

Wilt, Thomas E.; Arnold, Steven M.

1994-01-01

A fatigue damage computational algorithm utilizing a multiaxial, isothermal, continuum based fatigue damage model for unidirectional metal matrix composites has been implemented into the commercial finite element code MARC using MARC user subroutines. Damage is introduced into the finite element solution through the concept of effective stress which fully couples the fatigue damage calculations with the finite element deformation solution. An axisymmetric stress analysis was performed on a circumferentially reinforced ring, wherein both the matrix cladding and the composite core were assumed to behave elastic-perfectly plastic. The composite core behavior was represented using Hill's anisotropic continuum based plasticity model, and similarly, the matrix cladding was represented by an isotropic plasticity model. Results are presented in the form of S-N curves and damage distribution plots.

Analysis of metal-matrix composite structures. I - Micromechanics constitutive theory. II - Laminate analyses

NASA Technical Reports Server (NTRS)

Arenburg, R. T.; Reddy, J. N.

1991-01-01

The micromechanical constitutive theory is used to examine the nonlinear behavior of continuous-fiber-reinforced metal-matrix composite structures. Effective lamina constitutive relations based on the Abouli micromechanics theory are presented. The inelastic matrix behavior is modeled by the unified viscoplasticity theory of Bodner and Partom. The laminate constitutive relations are incorporated into a first-order deformation plate theory. The resulting boundary value problem is solved by utilizing the finite element method. Attention is also given to computational aspects of the numerical solution, including the temporal integration of the inelastic strains and the spatial integration of bending moments. Numerical results the nonlinear response of metal matrix composites subjected to extensional and bending loads are presented.

Thermo-mechanical response predictions for metal matrix composite laminates

NASA Technical Reports Server (NTRS)

Aboudi, J.; Hidde, J. S.; Herakovich, C. T.

1991-01-01

An analytical micromechanical model is employed for prediction of the stress-strain response of metal matrix composite laminates subjected to thermomechanical loading. The predicted behavior of laminates is based upon knowledge of the thermomechanical response of the transversely isotropic, elastic fibers and the elastic-viscoplastic, work-hardening matrix. The method is applied to study the behavior of silicon carbide/titanium metal matrix composite laminates. The response of laminates is compared with that of unidirectional lamina. The results demonstrate the effect of cooling from a stress-free temperature and the mismatch of thermal and mechanical properties of the constituent phases on the laminate's subsequent mechanical response. Typical results are presented for a variety of laminates subjected to monotonic tension, monotonic shear and cyclic tensile/compressive loadings.

Feasibility study on development of metal matrix composite by microwave stir casting

NASA Astrophysics Data System (ADS)

Lingappa, S. M.; Srinath, M. S.; Amarendra, H. J.

2018-04-01

Need for better service oriented materials has boosted the demand for metal matrix composite materials, which can be developed to have necessary properties. One of the most widely utilized metal matrix composite is Al-SiC, which is having a matrix made of aluminium metal and SiC as reinforcement. Lightweight and conductivity of aluminium, when combined with hardness and wear resistance of SiC provides an excellent platform for various applications in the field of electronics, automotives, and aerospace and so on. However, uniform distribution of reinforcement particles is an issue and has to be addressed. The present study is an attempt made to develop Al-SiC metal matrix composite by melting base metal using microwave hybrid heating technique, followed by addition of reinforcement and stirring the mixture for obtaining homogenous mixture. X-Ray Diffraction analysis shows the presence of aluminium and SiC in the cast material. Further, microstructural study shows the distribution of SiC particles in the grain boundaries.

Dry sliding wear of heat treated hybrid metal matrix composites

NASA Astrophysics Data System (ADS)

Naveed, Mohammed; Khan, A. R. Anwar

2016-09-01

In recent years, there has been an ever-increasing demand for enhancing mechanical properties of Aluminum Matrix Composites (AMCs), which are finding wide applications in the field of aerospace, automobile, defence etc,. Among all available aluminium alloys, Al6061 is extensively used owing to its excellent wear resistance and ease of processing. Newer techniques of improving the hardness and wear resistance of Al6061 by dispersing an appropriate mixture of hard ceramic powder and whiskers in the aluminium alloy are gaining popularity. The conventional aluminium based composites possess only one type of reinforcements. Addition of hard reinforcements such as silicon carbide, alumina, titanium carbide, improves hardness, strength and wear resistance of the composites. However, these composites possessing hard reinforcement do posses several problems during their machining operation. AMCs reinforced with particles of Gr have been reported to be possessing better wear characteristics owing to the reduced wear because of formation of a thin layer of Gr particles, which prevents metal to metal contact of the sliding surfaces. Further, heat treatment has a profound influence on mechanical properties of heat treatable aluminium alloys and its composites. For a solutionising temperature of 5500C, solutionising duration of 1hr, ageing temperature of 1750C, quenching media and ageing duration significantly alters mechanical properties of both aluminium alloy and its composites. In the light of the above, the present paper aims at developing aluminium based hybrid metal matrix composites containing both silicon carbide and graphite and characterize their mechanical properties by subjecting it to heat treatment. Results indicate that increase of graphite content increases wear resistance of hybrid composites reinforced with constant SiC reinforcement. Further heat treatment has a profound influence on the wear resistance of the matrix alloy as well as its hybrid composites. For all the heat treatment processes studied ice quenching with ageing duration of 6hrs resulted in improved wear resistance of both the unreinforced matrix alloy and its hybrid composites.

Mechanical behavior of glass and Blackglas{reg_sign} ceramic matrix composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stawovy, R.H.; Kampe, S.L.; Curtin, W.A.

Room temperature tensile tests are reported on two low-cost ceramic matrix composite materials, comprised of matrices of Blackglas{reg_sign} and a proprietary glass composition each reinforced with Nicalon{reg_sign} SiC-based fibers. The measured mechanical behaviors, supplemented by post-fracture analysis of fiber pullout and fiber fracture mirrors, are compared in detail to the performance predicted theoretically. This allows for an assessment of the roles of the matrix, fiber strength, residual stresses, fiber geometry, and the fiber/matrix interfacial properties in determining mechanical response. The Blackglas{reg_sign} matrix cracks extensively during processing, and so the mechanical response is controlled by the deformation and fracture of themore » fiber bundle. The interfacial sliding resistance, {tau}, is determined to be {approx} 17 MPa and the in-situ (post-processed) fiber characteristic strength, {sigma}{sub c} is found to be {approx} 2.0 GPa, both similar to values reported in the literature for Nicalon{reg_sign}/CAS-glass systems. For the glass matrix, the unidirectional and cross-ply materials show marked differences in mechanical behavior. In the cross-ply composites, {tau} {approx} 14 MPa and {sigma}{sub c} {approx} 2.9 GPa; in the unidirectional variants, these values were 1.7 MPa and 1.6 GPa, respectively. With these data and other derived micromechanical parameters, the stress-strain and failure point of these materials was predicted using existing models, and excellent agreement with the experiments was obtained. These materials thus perform as expected given the in-situ fiber and interface properties. Notably, the cross-ply glass matrix composites exhibit high fiber strength retention and hence show tensile strengths that are better than other Nicalon{reg_sign}-based materials tested to date.« less

Diamond-Dispersed Fiber-Reinforced Composite for Superior Friction and Wear Properties in Extreme Environments and Method for Fabricating the Same

NASA Technical Reports Server (NTRS)

Voronov, Oleg A (Inventor); Street, Kenneth (Inventor); Kear, Bernard H (Inventor)

2017-01-01

Systems, methods, and articles of manufacture related to composite materials are discussed herein. These materials can be based on a mixture of diamond particles with a matrix and fibers or fabrics. The matrix can be formed into the composite material through optional pressurization and via heat treatment. These materials display exceptionally low friction coefficient and superior wear resistance in extreme environments.

MoSi2-Base Composites

NASA Technical Reports Server (NTRS)

Hebsur, Mohan G.

2003-01-01

Addition of 30 to 50 vol% of Si3N4 particulate to MoSi2 eliminated its low temperature catastrophic failure, improved room temperature fracture toughness and the creep resistance. The hybrid composite SCS-6/MoSi2-Si3N4 did not show any matrix cracking and exhibited excellent mechanical and environmental properties. Hi-Nicalon continuous fiber reinforced MoSi2-Si3N4 also showed good strength and toughness. A new MoSi2-base composite containing in-situ whisker-type (Beta)Si3N4 grains in a MoSi2 matrix is also described.

Material Property Characterization of Potential Nanocarbon Metal-Matrix Composite: An Investigational Study

NASA Astrophysics Data System (ADS)

Zavala, Mitchel

Metal-matrix composites (MMCs) are engineered combinations of two or more materials. Tailored properties are achieved by systematic combinations of different constituents. Specialized design and synthesis procedures allow unique sets of material properties in composites. Covetics are a new type of metal-matrix nano-composite (MMnC) material. These materials are formed from FCC metals which are super-saturated with up to 10 wt. % of activated nano-carbon powder. The idea is that the nano-carbon particles will enhance the material properties of the base metal matrix, however most of the physical and mechanical properties of covetics have not been well characterized. The foci of this study are to optimize the covetic casting synthesis process under controlled conditions, to understand and analyze the microstructures of the synthesized copper and aluminum covetic, to provide a thorough analysis of the chemical composition of the synthesized covetic materials, and to characterize physical and mechanical properties of both of these materials using meticulously prepared samples and test procedures.

Computational simulation of matrix micro-slip bands in SiC/Ti-15 composite

NASA Technical Reports Server (NTRS)

Mital, S. K.; Lee, H.-J.; Murthy, P. L. N.; Chamis, C. C.

1992-01-01

Computational simulation procedures are used to identify the key deformation mechanisms for (0)(sub 8) and (90)(sub 8) SiC/Ti-15 metal matrix composites. The computational simulation procedures employed consist of a three-dimensional finite-element analysis and a micromechanics based computer code METCAN. The interphase properties used in the analysis have been calibrated using the METCAN computer code with the (90)(sub 8) experimental stress-strain curve. Results of simulation show that although shear stresses are sufficiently high to cause the formation of some slip bands in the matrix concentrated mostly near the fibers, the nonlinearity in the composite stress-strain curve in the case of (90)(sub 8) composite is dominated by interfacial damage, such as microcracks and debonding rather than microplasticity. The stress-strain curve for (0)(sub 8) composite is largely controlled by the fibers and shows only slight nonlinearity at higher strain levels that could be the result of matrix microplasticity.

Microstructure and Mechanical Behavior of Microwave Sintered Cu50Ti50 Amorphous Alloy Reinforced Al Metal Matrix Composites

NASA Astrophysics Data System (ADS)

Reddy, M. Penchal; Ubaid, F.; Shakoor, R. A.; Mohamed, A. M. A.

2018-06-01

In the present work, Al metal matrix composites reinforced with Cu-based (Cu50Ti50) amorphous alloy particles synthesized by ball milling followed by a microwave sintering process were studied. The amorphous powders of Cu50Ti50 produced by ball milling were used to reinforce the aluminum matrix. They were examined by x-ray diffraction (XRD), scanning electron microscopy (SEM), microhardness and compression testing. The analysis of XRD patterns of the samples containing 5 vol.%, 10 vol.% and 15 vol.% Cu50Ti50 indicates the presence of Al and Cu50Ti50 peaks. SEM images of the sintered composites show the uniform distribution of reinforced particles within the matrix. Mechanical properties of the composites were found to increase with an increasing volume fraction of Cu50Ti50 reinforcement particles. The hardness and compressive strength were enhanced to 89 Hv and 449 MPa, respectively, for the Al-15 vol.% Cu50Ti50 composites.

Comparison of orthorhombic and alpha-two titanium aluminides as matrices for continuous SiC-reinforced composites

NASA Astrophysics Data System (ADS)

Smith, P. R.; Graves, J. A.; Rhodes, Cg.

1994-06-01

The attributes of an orthorhombic Ti aluminide alloy, Ti-21Al-22Nb (at. pct), and an alpha-two Ti aluminide alloy, Ti-24Al-11Nb (at. pct), for use as a matrix with continuous SiC (SCS-6) fiber reinforcement have been compared. Foil-fiber-foil processing was used to produce both unreinforced (“neat”) and unidirectional “SCS-6” reinforced panels. Microstructure of the Ti-24A1-11Nb matrix consisted of ordered Ti3Al ( α 2) + disordered beta (β), while the Ti-21 Al-22Nb matrix contained three phases: α2, ordered beta ( β 0), and ordered orthorhombic (O). Fiber/ matrix interface reaction zone growth kinetics at 982 °C were examined for each composite system. Although both systems exhibited similar interface reaction products (i.e., mixed Ti carbides, silicides, and Ti-Al carbides), growth kinetics in the α 2 + β matrix composite were much more rapid than in the O + β 0 + α 2 matrix composite. Additionally, interfacial reaction in the α 2 + β} composite resulted in a relatively large brittle matrix zone, depleted of beta phase, which was not present in the O + β 0+ α 2 matrix composite. Mechanical property measurements included room and elevated temperature tensile, thermal stability, thermal fatigue, thermo-mechanical fatigue (TMF), and creep. The three-phase orthorhombic-based alloy outperformed the α2+ β alloy in all of these mechanical behavioral areas, on both an absolute and a specific (i.e., density corrected) basis.

Quantitative characterization of the carbon/carbon composites components based on video of polarized light microscope.

PubMed

Li, Yixian; Qi, Lehua; Song, Yongshan; Chao, Xujiang

2017-06-01

The components of carbon/carbon (C/C) composites have significant influence on the thermal and mechanical properties, so a quantitative characterization of component is necessary to study the microstructure of C/C composites, and further to improve the macroscopic properties of C/C composites. Considering the extinction crosses of the pyrocarbon matrix have significant moving features, the polarized light microscope (PLM) video is used to characterize C/C composites quantitatively because it contains sufficiently dynamic and structure information. Then the optical flow method is introduced to compute the optical flow field between the adjacent frames, and segment the components of C/C composites from PLM image by image processing. Meanwhile the matrix with different textures is re-segmented by the length difference of motion vectors, and then the component fraction of each component and extinction angle of pyrocarbon matrix are calculated directly. Finally, the C/C composites are successfully characterized from three aspects of carbon fiber, pyrocarbon, and pores by a series of image processing operators based on PLM video, and the errors of component fractions are less than 15%. © 2017 Wiley Periodicals, Inc.

Thermal stress effects in intermetallic matrix composites

NASA Technical Reports Server (NTRS)

Wright, P. K.; Sensmeier, M. D.; Kupperman, D. S.; Wadley, H. N. G.

1993-01-01

Intermetallic matrix composites develop residual stresses from the large thermal expansion mismatch (delta-alpha) between the fibers and matrix. This work was undertaken to: establish improved techniques to measure these thermal stresses in IMC's; determine residual stresses in a variety of IMC systems by experiments and modeling; and, determine the effect of residual stresses on selected mechanical properties of an IMC. X ray diffraction (XRD), neutron diffraction (ND), synchrotron XRD (SXRD), and ultrasonics (US) techniques for measuring thermal stresses in IMC were examined and ND was selected as the most promising technique. ND was demonstrated on a variety of IMC systems encompassing Ti- and Ni-base matrices, SiC, W, and Al2O3 fibers, and different fiber fractions (Vf). Experimental results on these systems agreed with predictions of a concentric cylinder model. In SiC/Ti-base systems, little yielding was found and stresses were controlled primarily by delta-alpha and Vf. In Ni-base matrix systems, yield strength of the matrix and Vf controlled stress levels. The longitudinal residual stresses in SCS-6/Ti-24Al-llNb composite were modified by thermomechanical processing. Increasing residual stress decreased ultimate tensile strength in agreement with model predictions. Fiber pushout strength showed an unexpected inverse correlation with residual stress. In-plane shear yield strength showed no dependence on residual stress. Higher levels of residual tension led to higher fatigue crack growth rates, as suggested by matrix mean stress effects.

Relationships Between Abrasive Wear, Hardness, and Surface Grinding Characteristics of Titanium-Based Metal Matrix Composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blau, Peter Julian; Jolly, Brian C

2009-01-01

The objective of this work was to support the development of grinding models for titanium metal-matrix composites (MMCs) by investigating possible relationships between their indentation hardness, low-stress belt abrasion, high-stress belt abrasion, and the surface grinding characteristics. Three Ti-based particulate composites were tested and compared with the popular titanium alloy Ti-6Al-4V. The three composites were a Ti-6Al-4V-based MMC with 5% TiB{sub 2} particles, a Ti-6Al-4V MMC with 10% TiC particles, and a Ti-6Al-4V/Ti-7.5%W binary alloy matrix that contained 7.5% TiC particles. Two types of belt abrasion tests were used: (a) a modified ASTM G164 low-stress loop abrasion test, and (b)more » a higher-stress test developed to quantify the grindability of ceramics. Results were correlated with G-ratios (ratio of stock removed to abrasives consumed) obtained from an instrumented surface grinder. Brinell hardness correlated better with abrasion characteristics than microindentation or scratch hardness. Wear volumes from low-stress and high-stress abrasive belt tests were related by a second-degree polynomial. Grindability numbers correlated with hard particle content but were also matrix-dependent.« less

Vibrational response and mechanical properties characterization of aluminium alloy 6061/Sic composite

NASA Astrophysics Data System (ADS)

Kumbhar, A. P.; Vyavahare, R. T.; Kulkarni, S. G.

2018-05-01

Aluminium alloy based metal matrix composites (AAMMC) are mainly used in sliding wear application, automobile, Aircraft and aerospace components, Marine fittings, Transport and other industry are becoming highly advantageous due to their excellent wear resistance, lighter weight, higher strength and durability. In this paper the effect of reinforcement percentage on vibration response and mechanical properties of metal matrix composite has been investigated. Composite material was prepared by varying Sic (0, 3, 6, and 9 wt. %) by stir casting method. Natural frequency, tensile strength, rockwell hardness and compressive strength were analyzed. The result shows that, addition of sic in aluminium matrix increases natural frequency, hardness, tensile strength, compressive strength and 9 wt. % showed maximum natural frequency, hardness, tensile strength, compressive strength.

LS-DYNA Implementation of Polymer Matrix Composite Model Under High Strain Rate Impact

NASA Technical Reports Server (NTRS)

Zheng, Xia-Hua; Goldberg, Robert K.; Binienda, Wieslaw K.; Roberts, Gary D.

2003-01-01

A recently developed constitutive model is implemented into LS-DYNA as a user defined material model (UMAT) to characterize the nonlinear strain rate dependent behavior of polymers. By utilizing this model within a micromechanics technique based on a laminate analogy, an algorithm to analyze the strain rate dependent, nonlinear deformation of a fiber reinforced polymer matrix composite is then developed as a UMAT to simulate the response of these composites under high strain rate impact. The models are designed for shell elements in order to ensure computational efficiency. Experimental and numerical stress-strain curves are compared for two representative polymers and a representative polymer matrix composite, with the analytical model predicting the experimental response reasonably well.

Chemically modified graphene/polyimide composite films based on utilization of covalent bonding and oriented distribution.

PubMed

Huang, Ting; Lu, Renguo; Su, Chao; Wang, Hongna; Guo, Zheng; Liu, Pei; Huang, Zhongyuan; Chen, Haiming; Li, Tongsheng

2012-05-01

Herein, we have developed a rather simple composite fabrication approach to achieving molecular-level dispersion and planar orientation of chemically modified graphene (CMG) in the thermosetting polyimide (PI) matrix as well as realizing strong adhesion at the interfacial regions between reinforcing filler and matrix. The covalent adhesion of CMG to PI matrix and oriented distribution of CMG were carefully confirmed and analyzed by detailed investigations. Combination of covalent bonding and oriented distribution could enlarge the effectiveness of CMG in the matrix. Efficient stress transfer was found at the CMG/PI interfaces. Significant improvements in the mechanical performances, thermal stability, electrical conductivity, and hydrophobic behavior were achieved by addition of only a small amount of CMG. Furthermore, it is noteworthy that the hydrophilic-to-hydrophobic transition and the electrical percolation were observed at only 0.2 wt % CMG in this composite system. This facile methodology is believed to afford broad application potential in graphene-based polymer nanocomposites, especially other types of high-performance thermosetting systems.

Synergistic Effects of Temperature, Oxidation and Stress Level on Fatigue Damage Evolution and Lifetime Prediction of Cross-Ply SiC/CAS Ceramic-Matrix Composites Through Hysteresis-Based Parameters

NASA Astrophysics Data System (ADS)

Li, Longbiao

2017-12-01

The damage development and cyclic fatigue lifetime of cross-ply SiC/CAS ceramic-matrix composites have been investigated at different testing temperatures in air atmosphere. The relationships between the fatigue hysteresis-based damage parameters, i.e., fatigue hysteresis dissipated energy, fatigue hysteresis modulus and fatigue peak strain and the damage mechanisms of matrix multicracking, fiber/matrix interface debonding, interface sliding and fibers failure, have been established. With the increase in the cycle number, the evolution of the fatigue hysteresis modulus, fatigue peak strain and fatigue hysteresis dissipated energy depends upon the fatigue peak stress levels, interface and fibers oxidation and testing temperature. The fatigue life S-N curves of cross-ply SiC/CAS composite at room and elevated temperatures have been predicted, and the fatigue limit stresses at room temperature, 750 and 850 °C, are 50, 36 and 30% of the tensile strength, respectively.

Considerations concerning fatigue life of metal matrix composites

NASA Technical Reports Server (NTRS)

Radhakrishnan, V. M.; Bartolotta, Paul A.

1993-01-01

Since metal matrix composites (MMC) are composed from two very distinct materials each having their own physical and mechanical properties, it is feasible that the fatigue resistance depends on the strength of the weaker constituent. Based on this assumption, isothermal fatigue lives of several MMC's were analyzed utilizing a fatigue life diagram approach. For each MMC, the fatigue life diagram was quantified using the mechanical properties of its constituents. The fatigue life regions controlled by fiber fracture and matrix were also quantitatively defined.

Optimal fabrication processes for unidirectional metal-matrix composites: A computational simulation

NASA Technical Reports Server (NTRS)

Saravanos, D. A.; Murthy, P. L. N.; Morel, M.

1990-01-01

A method is proposed for optimizing the fabrication process of unidirectional metal matrix composites. The temperature and pressure histories are optimized such that the residual microstresses of the composite at the end of the fabrication process are minimized and the material integrity throughout the process is ensured. The response of the composite during the fabrication is simulated based on a nonlinear micromechanics theory. The optimal fabrication problem is formulated and solved with non-linear programming. Application cases regarding the optimization of the fabrication cool-down phases of unidirectional ultra-high modulus graphite/copper and silicon carbide/titanium composites are presented.

Optimal fabrication processes for unidirectional metal-matrix composites - A computational simulation

NASA Technical Reports Server (NTRS)

Saravanos, D. A.; Murthy, P. L. N.; Morel, M.

1990-01-01

A method is proposed for optimizing the fabrication process of unidirectional metal matrix composites. The temperature and pressure histories are optimized such that the residual microstresses of the composite at the end of the fabrication process are minimized and the material integrity throughout the process is ensured. The response of the composite during the fabrication is simulated based on a nonlinear micromechanics theory. The optimal fabrication problem is formulated and solved with nonlinear programming. Application cases regarding the optimization of the fabrication cool-down phases of unidirectional ultra-high modulus graphite/copper and silicon carbide/titanium composites are presented.

Matrix density effects on the mechanical properties of SiC fiber-reinforced silicon nitride matrix properties

NASA Technical Reports Server (NTRS)

Bhatt, Ramakrishna T.; Kiser, Lames D.

1990-01-01

The room temperature mechanical properties were measured for SiC fiber reinforced reaction-bonded silicon nitride composites (SiC/RBSN) of different densities. The composites consisted of approx. 30 vol percent uniaxially aligned 142 micron diameter SiC fibers (Textron SCS-6) in a reaction-bonded Si3N4 matrix. The composite density was varied by changing the consolidation pressure during RBSN processing and by hot isostatically pressing the SiC/RBSN composites. Results indicate that as the consolidation pressure was increased from 27 to 138 MPa, the average pore size of the nitrided composites decreased from 0.04 to 0.02 microns and the composite density increased from 2.07 to 2.45 gm/cc. Nonetheless, these improvements resulted in only small increases in the first matrix cracking stress, primary elastic modulus, and ultimate tensile strength values of the composites. In contrast, HIP consolidation of SiC/RBSN resulted in a fully dense material whose first matrix cracking stress and elastic modulus were approx. 15 and 50 percent higher, respectively, and ultimate tensile strength values were approx. 40 percent lower than those for unHIPed SiC/RBSN composites. The modulus behavior for all specimens can be explained by simple rule-of-mixture theory. Also, the loss in ultimate strength for the HIPed composites appears to be related to a degradation in fiber strength at the HIP temperature. However, the density effect on matrix fracture strength was much less than would be expected based on typical monolithic Si3N4 behavior, suggesting that composite theory is indeed operating. Possible practical implications of these observations are discussed.

A bio-material: mechanical behaviour of LDPE-Al2O3-TiO2

NASA Astrophysics Data System (ADS)

Dhabale, R.; Jatti, V. S.

2016-09-01

Polymer composites are prominent candidate for polymeric bio-composites due to its low cost, high strength and ease of manufacturing. However, they suffer from low mechanical properties such as high wear rate and low hardness. In view of this, present study focuses on the synthesis of hybrid bio polymer matrix composites using low density polyethylene as matrix material with reinforcing material namely, alumina and titanium oxide. The samples were fabricated as per ASTM standard by varying the percentage of reinforcing particles using injection moulding machine. Various tests namely, tensile, flexural, impact, hardness, wear, SEM and corrosion were conducted on the prepared samples. On the basis of the experimental results, it can be concluded that injection moulding process can fabricate defect free cast samples. Polymer matrix composites of 70%LDPE +10% TiO2 +20% Al2O3 composition is biocompatible and a good candidate for biomaterial. Thus based on the inference of this study the above polymer matrix composite is suitable for orthopaedic applications and can be applied on hard and soft tissues of implantable materials in a human body.

Polymer matrix composites research at NASA Lewis Research Center

NASA Technical Reports Server (NTRS)

Serafini, T. T.

1982-01-01

The in situ polymerization of monomer reactants (PMR) approach was demonstrated to be a powerful approach for solving many of the processing difficulties associated with the use of high temperature resistant polymers as matrix resins in high performance composites. The PMR-15 polyimide provides the best overall balance of processing characteristics and elevated temperature properties. The excellent properties and commercial availability of composite materials based on PMR-15 led to their acceptance as viable engineering materials. The PMR-15 composites are used to produce a variety of high quality structural components.

Additional results on space environmental effects on polymer matrix composites: Experiment A0180

NASA Technical Reports Server (NTRS)

Tennyson, R. C.

1992-01-01

Additional experimental results on the atomic oxygen erosion of boron, Kevlar, and graphite fiber reinforced epoxy matrix composites are presented. Damage of composite laminates due to micrometeoroid/debris impacts is also examined with particular emphasis on the relationship between damage area and actual hole size due to particle penetration. Special attention is given to one micrometeoroid impact on an aluminum base plate which resulted in ejecta visible on an adjoining vertical flange structure.

Thermal shock fracture in cross-ply fibre-reinforced ceramic-matrix composites

NASA Astrophysics Data System (ADS)

Kastritseas, C.; Smith, P. A.; Yeomans, J. A.

2010-11-01

The onset of matrix cracking due to thermal shock in a range of simple and multi-layer cross-ply laminates comprising a calcium aluminosilicate (CAS) matrix reinforced with Nicalon® fibres is investigated analytically. A comprehensive stress analysis under conditions of thermal shock, ignoring transient effects, is performed and fracture criteria based on either a recently derived model for the thermal shock resistance of unidirectional Nicalon®/glass ceramic-matrix composites or fracture mechanics considerations are formulated. The effect of material thickness on the apparent thermal shock resistance is also modelled. Comparison with experimental results reveals that the accuracy of the predictions is satisfactory and the reasons for some discrepancies are discussed. In addition, a theoretical argument based on thermal shock theory is formulated to explain the observed cracking patterns.

Oxidation and Corrosion of Ceramics and Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Jacobson, Nathan S.; Opila, Elizabeth J.; Lee, Kang N.

2000-01-01

Ceramics and ceramic matrix composites are candidates for numerous applications in high temperature environments with aggressive gases and possible corrosive deposits. There is a growing realization that high temperature oxidation and corrosion issues must be considered. There are many facets to these studies, which have been extensively covered in some recent reviews. The focus of this paper is on current research, over the past two years. In the authors' view, the most important oxidation and corrosion studies have focused on four major areas during this time frame. These are; (I) Oxidation of precursor-based ceramics; (II) Studies of the interphase material in ceramic matrix composites; (III) Water vapor interactions with ceramics, particularly in combustion environments; and (IV) Development of refractory oxide coatings for silicon-based ceramics. In this paper, we shall explore the most current work in each of these areas.

Characterization of Delaminations and Transverse Matrix Cracks in Composite Laminates Using Multiple-Angle Ultrasonic Inspection

NASA Technical Reports Server (NTRS)

Johnston, Patrick H.; Appleget, Chelsea D.; Odarczenko, Michael T.

2012-01-01

Delaminations and transverse matrix cracks often appear concurrently in composite laminates. Normal-incidence ultrasound is excellent at detecting delaminations, but is not optimum for matrix cracks. Non-normal incidence, or polar backscattering, has been shown to optimally detect matrix cracks oriented perpendicular to the ultrasonic plane of incidence. In this work, a series of six composite laminates containing slots were loaded in tension to achieve various levels of delamination and ply cracking. Ultrasonic backscattering was measured over a range of incident polar and azimuthal angles, in order to characterize the relative degree of damage of the two types. Sweptpolar- angle measurements were taken with a curved phased array, as a step toward an array-based approach to simultaneous measurement of combined flaws.

Factors affecting the microstructure and mechanical properties of Ti-Al3Ti core-shell-structured particle-reinforced Al matrix composites

NASA Astrophysics Data System (ADS)

Guo, Baisong; Yi, Jianhong; Ni, Song; Shen, Rujuan; Song, Min

2016-04-01

This work studied the effects of matrix powder and sintering temperature on the microstructure and mechanical properties of in situ formed Ti-Al3Ti core-shell-structured particle-reinforced pure Al-based composites. It has been shown that both factors have significant effects on the morphology of the reinforcements and densification behaviour of the composites. Due to the strong interfacial bonding and the limitation of the crack propagation in the intermetallic shell during deformation by soft Al matrix and Ti core, the composite fabricated using fine spherical-shaped Al powder and sintered at 570 °C for 5 h has the optimal combination of the overall mechanical properties. The study provides a direction for the optimum combination of high strength and ductility of the composites by adjusting the fabrication parameters.

Polymer/clay/wood nanocomposites: The effect of incorporation of nanoclay into the wood/polymer composites

NASA Astrophysics Data System (ADS)

Hetzer, Max E.

Thermoplastic composites play an important role in our society. The uses of these composites range from cookware to components for the space shuttle. In recent years, researchers at Toyota developed numerous methods of preparation for composites made from olefins and inorganic fillers such as clay and calcium carbonate. Wood fibers have been used as reinforcing filler in polymer matrices for the past several decades. The advantages of using wood fibers as reinforcing fillers are: the low cost of the fibers (or flour), low density, and resistance to breakage. The disadvantage of using wood as a filler is the thermal instability of wood above 200 °C. The majority of thermoplastics exhibit melting points between 160 and 220 °C, which is in the range of thermal decomposition of wood. Nanoclay was first successfully used as a filler in polyolefin materials by the Toyota research team in early 90s. It was found that the addition of a small amount (< 5 wt.%) of nanoclay increased the mechanical properties of a Nylon-6 matrix dramatically. Since Nylon-6 is a hydrophilic material no compatibilizer was necessary to exfoliate the nanoclay. The use of compatibilizers such as maleic modified polyethylenes (MAPEs) is necessary upon addition of nanoclay to a hydrophobic polyolefin systems such polyethylene (PE) or polypropylene (PP). Few researchers have attempted to reinforce the polymer matrix via the use of the nanoclay for use as a matrix in wood/polymer composites. High molecular weight and low molecular weight MAPEs have been used to enhance the bonding between the nanoclay and the polymer matrix as well as between the wood flour and the polymer matrix. The effects of combinations of the high and low molecular weight MAPEs on the mechanical and thermal properties of polymer/clay nanocomposites (PCNs) and of wood/polymer/clay composites (WPCs) were investigated. The effects of adding nanoclay to wood/polymer systems on the mechanical and thermal properties of the composites were also investigated. A model based on the Halpin-Tsai model was developed that predicts the (Young's) modulus-temperature relationship of the composites based on discontinuous fillers. It was found that the molecular weight of the compatibilizer significantly affects the exfoliation/dispersion of the nanoclay within the polymer matrix. A compatibilizer containing a high Mw fraction based on high density polyethylene (HDPE) and a low Mw fraction based on linear low density polyethylene (LLDPE) was found to be the most effective at enhancing the thermal and mechanical properties of PCNs and WPCs. A compatibilizer containing greater than 60 wt.% high Mw fraction resulted in a 30% increase of the modulus and a 15°C increase of the heat deflection temperature (HDT). The addition of the nanoclay had a detrimental effect on the moduli of PCNs and WPCs when a low Mw compatibilizer based on LLDPE was used. The moduli of these composites increased with increasing high Mw content of the compatibilizer and increasing nanoclay content. The addition of the nanoclay to wood/polymer composites resulted in an increased modulus of elasticity and HDT of these composites. The developed model quantitatively predicts the modulus-temperature relationship of the fiber containing composites. It was found that the modulus of the composites varies linearly with temperature and was highly dependent on the exfoliation of the nanoclay within the polymer matrix.

Tailoring of physical properties in highly filled experimental nanohybrid resin composites.

PubMed

Pick, Bárbara; Pelka, Matthias; Belli, Renan; Braga, Roberto R; Lohbauer, Ulrich

2011-07-01

To assess the elastic modulus (EM), volumetric shrinkage (VS), and polymerization shrinkage stress (PSS) of experimental highly filled nanohybrid composites as a function of matrix composition, filler distribution, and density. One regular viscosity nanohybrid composite (Grandio, VOCO, Germany) and one flowable nanohybrid composite (Grandio Flow, VOCO) were tested as references along with six highly filled experimental nanohybrid composites (four Bis-GMA-based, one UDMA-based, and one Ormocer®-based). The experimental composites varied in filler size and density. EM values were obtained from the "three-point bending" load-displacement curve. VS was calculated with Archimedes' buoyancy principle. PSS was determined in 1-mm thick specimens placed between two (poly)methyl methacrylate rods (Ø=6mm) attached to an universal testing machine. Data were analyzed using oneway ANOVA, Tukey's test (α=0.05), and linear regression analyses. The flowable composite exhibited the highest VS and PSS but lowest EM. The PSS was significantly lower with Ormocer. The EM was significantly higher among experimental composites with highest filler levels. No significant differences were found between all other experimental composites regarding VS and PSS. Filler density and size did not influence EM, VS, or PSS. Neither the filler configuration nor matrix composition in the investigated materials significantly influenced composite shrinkage and mechanical properties. The highest filled experimental composite seemed to increase EM by keeping VS and PSS low; however, matrix composition seemed to be the determinant factor for shrinkage and stress development. The Ormocer, with reduced PSS, deserves further investigation. Filler size and density did not influence the tested parameters. Copyright © 2011 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Effects of Interface Coating and Nitride Enhancing Additive on Properties of Hi-Nicalon SiC Fiber Reinforced Reaction-Bonded Silicon Nitride Composites

NASA Technical Reports Server (NTRS)

Bhatt, Ramakrishana T.; Hull, David R.; Eldridge, Jeffrey I.; Babuder, Raymond

2000-01-01

Strong and tough Hi-Nicalon SiC fiber reinforced reaction-bonded silicon nitride matrix composites (SiC/ RBSN) have been fabricated by the fiber lay-up approach. Commercially available uncoated and PBN, PBN/Si-rich PBN, and BN/SiC coated SiC Hi-Nicalon fiber tows were used as reinforcement. The composites contained approximately 24 vol % of aligned 14 micron diameter SiC fibers in a porous RBSN matrix. Both one- and two-dimensional composites were characterized. The effects of interface coating composition, and the nitridation enhancing additive, NiO, on the room temperature physical, tensile, and interfacial shear strength properties of SiC/RBSN matrix composites were evaluated. Results indicate that for all three coated fibers, the thickness of the coatings decreased from the outer periphery to the interior of the tows, and that from 10 to 30 percent of the fibers were not covered with the interface coating. In the uncoated regions, chemical reaction between the NiO additive and the SiC fiber occurs causing degradation of tensile properties of the composites. Among the three interface coating combinations investigated, the BN/SiC coated Hi-Nicalon SiC fiber reinforced RBSN matrix composite showed the least amount of uncoated regions and reasonably uniform interface coating thickness. The matrix cracking stress in SiC/RBSN composites was predicted using a fracture mechanics based crack bridging model.

Microstructure evolution and mechanical properties of TiCN-Cr nano/micro composite coatings prepared by reactive plasma spraying

NASA Astrophysics Data System (ADS)

Zhang, Fanyong; He, Jining; Chen, Kai; Qin, Yanfang; Li, Chao; Yin, Fuxing

2018-01-01

Nanostructured TiCN based composite coatings with various Cr content were prepared by reactive plasma spray (RPS) from mixed powder (Ti-graphite + Cr) under nitrogen atmosphere. Results showed that composite coatings consisted mainly of TiC0.7N0.3 phase and residual metal Cr. Metal Cr plates were homogeneously embedded in TiCN matrix with good interface bond. The TiCN-Cr composite coatings exhibited lower porosity than TiCN coatings, but increasing porosity with excess Cr addition (30 wt.%). The TiCN-20 wt.% Cr coating showed the highest hardness (1309 HV0.2) among composite coatings, slight lower than the TiCN matrix coating (1526 HV0.2). Compared with the TiCN matrix coating, the TiCN-Cr composite coatings showed higher variability in surface microhardness distribution. The TiCN-Cr composite coatings showed slight higher friction coefficients (0.4-0.6) than TiCN matrix coating (0.35). The wear resistance of TiCN-Cr composite coatings was improved with less mass loss compared with TiCN coating under the test load of 400 N. The TiCN-Cr composite coatings with high Cr content showed the mixture of abrasive and adhesive wear.

NiTi-Enabled Composite Design for Exceptional Performances

DOE PAGES

Shao, Yang; Guo, Fangmin; Ren, Yang; ...

2017-03-08

In an effort to further develop shape memory alloys (SMAs) for functional applications, much focus has been given in recent years to design and create innovative forms of SMAs, such as functionally graded SMAs, architecture SMAs, and SMA-based metallic composites. Here, we reports on the progress in creating NiTi-based composites of exceptional properties stimulated by the recent discovery of the principle of lattice strain matching between the SMA matrix and superelastic nanoinclusions embedded in the matrix. And based on this principle, different SMA–metal composites have been designed to achieve extraordinary shape memory performances, such as complete pseudoelastic behavior at asmore » low as 77 K and stress plateau as high as 1600 MPa, and exceptional mechanical properties, such as tensile strength as high as 2000 MPa and Young’s modulus as low as 28 GPa. Details are given for a NiTi–W micro-fiber composite prepared by melt infiltration, hot pressing, forging, and cold rolling. Furthermore, the composite contained 63% in volume of W micro-fibers of ~0.6 μm thickness. In situ synchrotron X-ray diffraction revealed that the NiTi matrix underwent martensite transformation during tensile deformation while the W micro-fiber deformed elastically with a maximum strain of 0.83% in the loading direction, implying a W fiber stress of 3280 MPa. The composite showed a maximum high tensile strength of 2300 MPa.« less

Process and Microstructure to Achieve Ultra-high Dielectric Constant in Ceramic-Polymer Composites.

PubMed

Zhang, Lin; Shan, Xiaobing; Bass, Patrick; Tong, Yang; Rolin, Terry D; Hill, Curtis W; Brewer, Jeffrey C; Tucker, Dennis S; Cheng, Z-Y

2016-10-21

Influences of process conditions on microstructure and dielectric properties of ceramic-polymer composites are systematically studied using CaCu 3 Ti 4 O 12 (CCTO) as filler and P(VDF-TrFE) 55/45 mol.% copolymer as the matrix by combining solution-cast and hot-pressing processes. It is found that the dielectric constant of the composites can be significantly enhanced-up to about 10 times - by using proper processing conditions. The dielectric constant of the composites can reach more than 1,000 over a wide temperature range with a low loss (tan δ ~ 10 -1 ). It is concluded that besides the dense structure of composites, the uniform distribution of the CCTO particles in the matrix plays a key role on the dielectric enhancement. Due to the influence of the CCTO on the microstructure of the polymer matrix, the composites exhibit a weaker temperature dependence of the dielectric constant than the polymer matrix. Based on the results, it is also found that the loss of the composites at low temperatures, including room temperature, is determined by the real dielectric relaxation processes including the relaxation process induced by the mixing.

Process and Microstructure to Achieve Ultra-high Dielectric Constant in Ceramic-Polymer Composites

NASA Astrophysics Data System (ADS)

Zhang, Lin; Shan, Xiaobing; Bass, Patrick; Tong, Yang; Rolin, Terry D.; Hill, Curtis W.; Brewer, Jeffrey C.; Tucker, Dennis S.; Cheng, Z.-Y.

2016-10-01

Influences of process conditions on microstructure and dielectric properties of ceramic-polymer composites are systematically studied using CaCu3Ti4O12 (CCTO) as filler and P(VDF-TrFE) 55/45 mol.% copolymer as the matrix by combining solution-cast and hot-pressing processes. It is found that the dielectric constant of the composites can be significantly enhanced-up to about 10 times - by using proper processing conditions. The dielectric constant of the composites can reach more than 1,000 over a wide temperature range with a low loss (tan δ ~ 10-1). It is concluded that besides the dense structure of composites, the uniform distribution of the CCTO particles in the matrix plays a key role on the dielectric enhancement. Due to the influence of the CCTO on the microstructure of the polymer matrix, the composites exhibit a weaker temperature dependence of the dielectric constant than the polymer matrix. Based on the results, it is also found that the loss of the composites at low temperatures, including room temperature, is determined by the real dielectric relaxation processes including the relaxation process induced by the mixing.

Process and Microstructure to Achieve Ultra-high Dielectric Constant in Ceramic-Polymer Composites

PubMed Central

Zhang, Lin; Shan, Xiaobing; Bass, Patrick; Tong, Yang; Rolin, Terry D.; Hill, Curtis W.; Brewer, Jeffrey C.; Tucker, Dennis S.; Cheng, Z.-Y.

2016-01-01

Influences of process conditions on microstructure and dielectric properties of ceramic-polymer composites are systematically studied using CaCu3Ti4O12 (CCTO) as filler and P(VDF-TrFE) 55/45 mol.% copolymer as the matrix by combining solution-cast and hot-pressing processes. It is found that the dielectric constant of the composites can be significantly enhanced–up to about 10 times – by using proper processing conditions. The dielectric constant of the composites can reach more than 1,000 over a wide temperature range with a low loss (tan δ ~ 10−1). It is concluded that besides the dense structure of composites, the uniform distribution of the CCTO particles in the matrix plays a key role on the dielectric enhancement. Due to the influence of the CCTO on the microstructure of the polymer matrix, the composites exhibit a weaker temperature dependence of the dielectric constant than the polymer matrix. Based on the results, it is also found that the loss of the composites at low temperatures, including room temperature, is determined by the real dielectric relaxation processes including the relaxation process induced by the mixing. PMID:27767184

Graphene-and-Copper Artificial Nacre Fabricated by a Preform Impregnation Process: Bioinspired Strategy for Strengthening-Toughening of Metal Matrix Composite.

PubMed

Xiong, Ding-Bang; Cao, Mu; Guo, Qiang; Tan, Zhanqiu; Fan, Genlian; Li, Zhiqiang; Zhang, Di

2015-07-28

Metals can be strengthened by adding hard reinforcements, but such strategy usually compromises ductility and toughness. Natural nacre consists of hard and soft phases organized in a regular "brick-and-mortar" structure and exhibits a superior combination of mechanical strength and toughness, which is an attractive model for strengthening and toughening artificial composites, but such bioinspired metal matrix composite has yet to be made. Here we prepared nacre-like reduced graphene oxide (RGrO) reinforced Cu matrix composite based on a preform impregnation process, by which two-dimensional RGrO was used as "brick" and inserted into "□-and-mortar" ordered porous Cu preform (the symbol "□" means the absence of "brick"), followed by compacting. This process realized uniform dispersion and alignment of RGrO in Cu matrix simultaneously. The RGrO-and-Cu artificial nacres exhibited simultaneous enhancement on yield strength and ductility as well as increased modulus, attributed to RGrO strengthening, effective crack deflection and a possible combined failure mode of RGrO. The artificial nacres also showed significantly higher strengthening efficiency than other conventional Cu matrix composites, which might be related to the alignment of RGrO.

Laser Surface Treatment and Modification of Aluminum Alloy Matrix Composites

NASA Astrophysics Data System (ADS)

Abbass, Muna Khethier

2018-02-01

The present work aimed to study the laser surface treatment and modification of Al-4.0%Cu-1.0%Mg alloy matrix composite reinforced with 10%SiC particles produced by stir casting. The specimens of the base alloy and composite were irradiated with an Nd:YAG laser of 1000 mJ, 1064 nm and 3 Hz . Dry wear test using the pin-on -disc technique at different sliding times (5-30 min) at a constant applied load and sliding speed were performed before and after laser treatment. Micro hardness and wear resistance were increased for all samples after laser hardening treatment. The improvement of these properties is explained by microstructural homogenization and grain refinement of the laser treated surface. Modification and refinement of SiC particles and grain refinement in the microstructure of the aluminum alloy matrix (α-Al) were observed by optical and SEM micrographs. The highest increase in hardness was 21.4% and 26.2% for the base alloy and composite sample respectively.

Amino acid-functionalized multi-walled carbon nanotubes for improving compatibility with chiral poly(amide-ester-imide) containing L-phenylalanine and L-tyrosine linkages

NASA Astrophysics Data System (ADS)

Abdolmaleki, Amir; Mallakpour, Shadpour; Borandeh, Sedigheh

2013-12-01

Amino acid functionalized multi-walled carbon nanotubes (f-MWCNTs)/poly(amide-ester-imide) (PAEI) composites were fabricated by solution mixing method. Proper functionalization and mixing strategy of MWCNTs provides the best opportunity for better distribution and bonding of nanoparticles to the polymer matrix. MWCNTs have been chemically modified with L-phenylalanine to improve their compatibility with L-phenylalanine based PAEI. Field emission scanning electron microscopy micrographs of composite revealed that f-MWCNTs made a good interaction with polymer chains by wrapping the polymer around them, and transmission electron microscopy results confirmed well dispersion with nano size of f-MWCNTs in the polymer matrix. In addition, thermal analysis showed good enhancement in thermal properties of composites compared to pure polymer. Thermal stability of the composites containing f-MWCNTs was enhanced due to their good dispersion and improved interfacial interaction between the amino acid based PAEI matrix and f-MWCNTs.

Simulation of Complex Cracking in Plain Weave C/SiC Composite under Biaxial Loading

NASA Technical Reports Server (NTRS)

Cheng, Ron-Bin; Hsu, Su-Yuen

2012-01-01

Finite element analysis is performed on a mesh, based on computed geometry of a plain weave C/SiC composite with assumed internal stacking, to reveal the pattern of internal damage due to biaxial normal cyclic loading. The simulation encompasses intertow matrix cracking, matrix cracking inside the tows, and separation at the tow-intertow matrix and tow-tow interfaces. All these dissipative behaviors are represented by traction-separation cohesive laws. Not aimed at quantitatively predicting the overall stress-strain relation, the simulation, however, does not take the actual process of fiber debonding into account. The fiber tows are represented by a simple rule-of-mixture model where the reinforcing phase is a hypothetical one-dimensional material. Numerical results indicate that for the plain weave C/SiC composite, 1) matrix-crack initiation sites are primarily determined by large intertow matrix voids and interlayer tow-tow contacts, 2) the pattern of internal damage strongly depends on the loading path and initial stress, 3) compressive loading inflicts virtually no damage evolution. KEY WORDS: ceramic matrix composite, plain weave, cohesive model, brittle failure, smeared crack model, progressive damage, meso-mechanical analysis, finite element.

Array-based disease diagnostics using lipid/polydiacetylene vesicles encapsulated in a sol-gel matrix.

PubMed

Kolusheva, S; Yossef, R; Kugel, A; Katz, M; Volinsky, R; Welt, M; Hadad, U; Drory, V; Kliger, M; Rubin, E; Porgador, A; Jelinek, R

2012-07-17

We demonstrate a novel array-based diagnostic platform comprising lipid/polydiacetylene (PDA) vesicles embedded within a transparent silica-gel matrix. The diagnostic scheme is based upon the unique chromatic properties of PDA, which undergoes blue-red transformations induced by interactions with amphiphilic or membrane-active analytes. We show that constructing a gel matrix array hosting PDA vesicles with different lipid compositions and applying to blood plasma obtained from healthy individuals and from patients suffering from disease, respectively, allow distinguishing among the disease conditions through application of a simple machine-learning algorithm, using the colorimetric response of the lipid/PDA/gel matrix as the input. Importantly, the new colorimetric diagnostic approach does not require a priori knowledge on the exact metabolite compositions of the blood plasma, since the concept relies only on identifying statistically significant changes in overall disease-induced chromatic response. The chromatic lipid/PDA/gel array-based "fingerprinting" concept is generic, easy to apply, and could be implemented for varied diagnostic and screening applications.

Effectiveness of metal matrix and ceramic matrix composites as orbital debris shield materials

NASA Technical Reports Server (NTRS)

Mcgill, Preston B.; Mount, Angela R.

1992-01-01

The effectiveness of two metal matrix composites and one ceramic matrix material in defeating hypervelocity impacts at about 3.8 km/s are evaluated to determine the potential of these composites as spacecraft shield materials. The metal matrix composites investigated consist of SiC particles (70 percent by volume) in an aluminum matrix and Al2O3 particles (50 percent by volume) in an Al matrix. The ceramic composite consists of ZrB2 platelets in a ZrC matrix. Both the metal matrix and ceramic matrix composites are found to perform as well or better than 6061-T6 aluminum, which is presently used in the Whipple type bumper shield of Space Station Freedom. Test results indicate that the composites tested may have applications as micrometeoroid/orbital debris shield materials.

Al2O3 fiber strength degradation in metal and intermetallic matrix composites

NASA Technical Reports Server (NTRS)

Draper, S. L.; Locci, I. E.

1994-01-01

The mechanisms for fiber damage in single crystal Al2O3 fiber-reinforced composites were investigated. Both fiber fragmentation and fiber strength degradation were observed in composites with a variety of matrix compositions. Four mechanisms that may be contributing to the fiber strength loss have been proposed and include matrix reaction, reaction with binders, residual stress-induced damage, and pressure from hot pressing. The effect of matrix reaction was separated from the other three effects by sputter-coating the matrices on cleaned fibers and annealing with a temperature profile that simulates processing conditions. These experiments revealed that Y and Cr in FeCrAlY base alloys and Zr in NiAl alloys reacted with the fiber, and grooves and adherent particles were formed on the fiber surface which were responsible for the strength loss. The effects of the matrix reaction appeared to dominate over the other possible mechanisms, although evidence for reaction with binders was also found. Ridges on the fiber surface, which reflected the grain boundaries of the matrix, were also observed. In order for single-crystal Al2O3 to be used as a fiber in MMC's and IMC's, a matrix or protective coating which minimizes matrix reaction during processing will be necessary. Of the matrices investigated, the Thermo-span(sup TM) alloy was the least damaging to fiber properties.

A simple laminate theory using the orthotropic viscoplasticity theory based on overstress. I - In-plane stress-strain relationships for metal matrix composites

NASA Technical Reports Server (NTRS)

Krempl, Erhard; Hong, Bor Zen

1989-01-01

A macromechanics analysis is presented for the in-plane, anisotropic time-dependent behavior of metal matrix laminates. The small deformation, orthotropic viscoplasticity theory based on overstress represents lamina behavior in a modified simple laminate theory. Material functions and constants can be identified in principle from experiments with laminae. Orthotropic invariants can be repositories for tension-compression asymmetry and for linear elasticity in one direction while the other directions behave in a viscoplastic manner. Computer programs are generated and tested for either unidirectional or symmetric laminates under in-plane loading. Correlations with the experimental results on metal matrix composites are presented.

A continuum model for damage evolution in laminated composites

NASA Technical Reports Server (NTRS)

Lo, D. C.; Allen, D. H.; Harris, C. E.

1991-01-01

The accumulation of matrix cracking is examined using continuum damage mechanics lamination theory. A phenomenologically based damage evolutionary relationship is proposed for matrix cracking in continuous fiber reinforced laminated composites. The use of material dependent properties and damage dependent laminate averaged ply stresses in this evolutionary relationship permits its application independently of the laminate stacking sequence. Several load histories are applied to crossply laminates using this model, and the results are compared to published experimental data. The stress redistribution among the plies during the accumulation of matrix damage is also examined. It is concluded that characteristics of the stress redistribution process could assist in the analysis of the progressive failure process in laminated composites.

Self-Repairing Fatigue Damage in Metallic Structures for Aerospace Vehicles Using Shape Memory Alloy Self-healing (SMASH) Technology

NASA Technical Reports Server (NTRS)

Wright, M. Clara; Manuel, Michele; Wallace, Terryl; Newman, Andy; Brinson, Kate

2015-01-01

This DAA is for the Phase II webinar presentation of the ARMD-funded SMASH technology. A self-repairing aluminum-based composite system has been developed using liquid-assisted healing theory in conjunction with the shape memory effect of wire reinforcements. The metal matrix composite was thermodynamically designed to have a matrix with a relatively even dispersion of low-melting phase, allowing for repair of cracks at a pre-determined temperature. Shape memory alloy wire reinforcements were used within the composite to provide crack closure. Investigators focused the research on fatigue cracks propagating through the matrix in order to optimize and computer model the SMASH technology for aeronautical applications.

Progressive delamination in polymer matrix composite laminates: A new approach

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Murthy, P. L. N.; Minnetyan, L.

1992-01-01

A new approach independent of stress intensity factors and fracture toughness parameters has been developed and is described for the computational simulation of progressive delamination in polymer matrix composite laminates. The damage stages are quantified based on physics via composite mechanics while the degradation of the laminate behavior is quantified via the finite element method. The approach accounts for all types of composite behavior, laminate configuration, load conditions, and delamination processes starting from damage initiation, to unstable propagation, and to laminate fracture. Results of laminate fracture in composite beams, panels, plates, and shells are presented to demonstrate the effectiveness and versatility of this new approach.

Effect of Manufacturing Method to Tensile Properties of Hybrid Composite Reinforced by Natural (Agel Leaf Fiber) and Glass Fibers

NASA Astrophysics Data System (ADS)

Nugroho, A.; Abdurohman, K.; Kusmono; Hestiawan, H.; Jamasri

2018-04-01

This paper described the effect of different type of manufacturing method to tensile properties of hybrid composite woven agel leaf fiber and glass fiber as an alternative of LSU structure material. The research was done by using 3 ply of woven agel leaf fiber (ALF) and 3 ply of glass fiber (wr200) while the matrix was using unsaturated polyester. Composite manufacturing method used hand lay-up and vacuum bagging. Tensile test conducted with Tensilon universal testing machine, specimen shape and size according to standard size ASTM D 638. Based on tensile test result showed that the tensile strength of agel leaf fiber composite with unsaturated polyester matrix is 54.5 MPa by hand lay-up and 84.6 MPa with vacuum bagging method. From result of tensile test, hybrid fiber agel composite and glass fiber with unsaturated polyester matrix have potential as LSU structure.

Designing novel bulk metallic glass composites with a high aluminum content

PubMed Central

Chen, Z. P.; Gao, J. E.; Wu, Y.; Wang, H.; Liu, X. J.; Lu, Z. P.

2013-01-01

The long-standing challenge for forming Al-based BMGs and their matrix composites with a critical size larger than 1 mm have not been answered over the past three decades. In this paper, we reported formation of a series of BMG matrix composites which contain a high Al content up to 55 at.%. These composites can be cast at extraordinarily low cooling rates, compatible with maximum rod diameters of over a centimetre in copper mold casting. Our results indicate that proper additions of transition element Fe which have a positive heat of mixing with the main constituents La and Ce can appreciably improve the formability of the BMG matrix composites by suppressing the precipitation of Al(La,Ce) phase resulted from occurrence of the phase separation. However, the optimum content of Fe addition is strongly dependant on the total amount of the Al content in the Al-(CoCu)-(La,Ce) alloys. PMID:24284800

Thermal conductivity and thermal expansion of graphite fiber/copper matrix composites

NASA Technical Reports Server (NTRS)

Ellis, David L.; Mcdanels, David L.

1991-01-01

The high specific conductivity of graphite fiber/copper matrix (Gr/Cu) composites offers great potential for high heat flux structures operating at elevated temperatures. To determine the feasibility of applying Gr/Cu composites to high heat flux structures, composite plates were fabricated using unidirectional and cross-plied pitch-based P100 graphite fibers in a pure copper matrix. Thermal conductivity of the composites was measured from room temperature to 1073 K, and thermal expansion was measured from room temperature to 1050 K. The longitudinal thermal conductivity, parallel to the fiber direction, was comparable to pure copper. The transverse thermal conductivity, normal to the fiber direction, was less than that of pure copper and decreased with increasing fiber content. The longitudinal thermal expansion decreased with increasing fiber content. The transverse thermal expansion was greater than pure copper and nearly independent of fiber content.

Thermal conductivity and thermal expansion of graphite fiber-reinforced copper matrix composites

NASA Technical Reports Server (NTRS)

Ellis, David L.; Mcdanels, David L.

1993-01-01

The high specific conductivity of graphite fiber/copper matrix (Gr/Cu) composites offers great potential for high heat flux structures operating at elevated temperatures. To determine the feasibility of applying Gr/Cu composites to high heat flux structures, composite plates were fabricated using unidirectional and cross-plied pitch-based P100 graphite fibers in a pure copper matrix. Thermal conductivity of the composites was measured from room temperature to 1073 K, and thermal expansion was measured from room temperature to 1050 K. The longitudinal thermal conductivity, parallel to the fiber direction, was comparable to pure copper. The transverse thermal conductivity, normal to the fiber direction, was less than that of pure copper and decreased with increasing fiber content. The longitudinal thermal expansion decreased with increasing fiber content. The transverse thermal expansion was greater than pure copper and nearly independent of fiber content.

Designing novel bulk metallic glass composites with a high aluminum content.

PubMed

Chen, Z P; Gao, J E; Wu, Y; Wang, H; Liu, X J; Lu, Z P

2013-11-27

The long-standing challenge for forming Al-based BMGs and their matrix composites with a critical size larger than 1 mm have not been answered over the past three decades. In this paper, we reported formation of a series of BMG matrix composites which contain a high Al content up to 55 at.%. These composites can be cast at extraordinarily low cooling rates, compatible with maximum rod diameters of over a centimetre in copper mold casting. Our results indicate that proper additions of transition element Fe which have a positive heat of mixing with the main constituents La and Ce can appreciably improve the formability of the BMG matrix composites by suppressing the precipitation of Al(La,Ce) phase resulted from occurrence of the phase separation. However, the optimum content of Fe addition is strongly dependant on the total amount of the Al content in the Al-(CoCu)-(La,Ce) alloys.

Influence of Binder in Iron Matrix Composites

NASA Astrophysics Data System (ADS)

Shamsuddin, S.; Jamaludin, S. B.; Hussain, Z.; Ahmad, Z. A.

2010-03-01

The ability to use iron and its alloys as the matrix material in composite systems is of great importance because it is the most widely used metallic material with a variety of commercially available steel grades [1]. The aim of this study is to investigate the influence of binder in particulate iron based metal matrix composites. There are four types of binder that were used in this study; Stearic Acid, Gummi Arabisch, Polyvinyl alcohol 15000 MW and Polyvinyl alcohol 22000 MW. Six different weight percentage of each binder was prepared to produce the composite materials using powder metallurgy (P/M) route; consists of dry mixing, uniaxially compacting at 750 MPa and vacuum sintering at 1100° C for two hours. Their characterization included a study of density, porosity, hardness and microstructure. Results indicate that MMC was affected by the binder and stearic acid as a binder produced better properties of the composite.

Age hardening of 6061/alumina-silica fiber composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khangaonkar, P.R.; Shamsul, J.B.; Azmi, R.

1994-12-31

Continuous alumina-silica fiber (Altex of Sumitomo) which yields high performance composites with some aluminium alloys was tried for squeeze cast 6061 based composites with volume fractions of 0.5 and 0.32, and the matrix microhardness and resistivity changes during age hardening were studied. The matrix in the composites hardened much more than the unreinforced alloy. Microhardness increases of up to 70 VPN above the solution treated condition at various aging temperatures were observed. The resistivity variation indicated an appreciable state of internal stress which continued to persist even when hardness fell by overaging. Energy dispersive X-ray analysis indicated that the regionsmore » close to the fibers had a higher silicon content than the matrix, and amorphous silica in the fiber may have a role in the formation of an enriched layer which may help the bonding and strength in the composite.« less

A Coupled/Uncoupled Computational Scheme for Deformation and Fatigue Damage Analysis of Unidirectional Metal-Matrix Composites

NASA Technical Reports Server (NTRS)

Wilt, Thomas E.; Arnold, Steven M.; Saleeb, Atef F.

1997-01-01

A fatigue damage computational algorithm utilizing a multiaxial, isothermal, continuum-based fatigue damage model for unidirectional metal-matrix composites has been implemented into the commercial finite element code MARC using MARC user subroutines. Damage is introduced into the finite element solution through the concept of effective stress that fully couples the fatigue damage calculations with the finite element deformation solution. Two applications using the fatigue damage algorithm are presented. First, an axisymmetric stress analysis of a circumferentially reinforced ring, wherein both the matrix cladding and the composite core were assumed to behave elastic-perfectly plastic. Second, a micromechanics analysis of a fiber/matrix unit cell using both the finite element method and the generalized method of cells (GMC). Results are presented in the form of S-N curves and damage distribution plots.

A unique set of micromechanics equations for high temperature metal matrix composites

NASA Technical Reports Server (NTRS)

Hopkins, D. A.; Chamis, C. C.

1985-01-01

A unique set of micromechanic equations is presented for high temperature metal matrix composites. The set includes expressions to predict mechanical properties, thermal properties and constituent microstresses for the unidirectional fiber reinforced ply. The equations are derived based on a mechanics of materials formulation assuming a square array unit cell model of a single fiber, surrounding matrix and an interphase to account for the chemical reaction which commonly occurs between fiber and matrix. A three-dimensional finite element analysis was used to perform a preliminary validation of the equations. Excellent agreement between properties predicted using the micromechanics equations and properties simulated by the finite element analyses are demonstrated. Implementation of the micromechanics equations as part of an integrated computational capability for nonlinear structural analysis of high temperature multilayered fiber composites is illustrated.

Modeling creep behavior of fiber composites

NASA Technical Reports Server (NTRS)

Chen, J. L.; Sun, C. T.

1988-01-01

A micromechanical model for the creep behavior of fiber composites is developed based on a typical cell consisting of a fiber and the surrounding matrix. The fiber is assumed to be linearly elastic and the matrix nonlinearly viscous. The creep strain rate in the matrix is assumed to be a function of stress. The nominal stress-strain relations are derived in the form of differential equations which are solved numerically for off-axis specimens under uniaxial loading. A potential function and the associated effective stress and effective creep strain rates are introduced to simplify the orthotropic relations.

Damage Accumulation in SiC/SiC Composites with 3D Architectures

NASA Technical Reports Server (NTRS)

Morscher, Gregory N.; Yun, Hee-Mann; DiCarlo, James A.

2003-01-01

The formation and propagation of multiple matrix cracks in relatively dense ceramic matrix composites when subjected to increasing tensile stress is necessary for high strength and tough composites. However, the occurrence of matrix cracks at low stresses may limit the usefulness of some non-oxide composite systems when subjected to oxidizing environments for long times at stresses sufficient to cause matrix cracking. For SiC fiber-reinforced composites with two-dimensional woven architectures and chemically vapor infiltrated (CVI) SiC matrix and melt-infiltrated (MI) Si/SiC matrix composites, the matrix cracking behavior has been fairly well characterized for different fiber-types and woven architectures. It was found that the occurrence, degree, and growth of matrix cracks depends on the material properties of the composite constituents as well as other physical properties of the composite or architecture, e.g., matrix porosity and size of the fiber bundle. In this study, matrix cracking in SiC fiber reinforced, melt-infiltrated SiC composites with a 3D orthogonal architecture was determined for specimens tested in tension at room temperature. Acoustic emission (AE) was used to monitor the matrix cracking activity, which was later confirmed by microscopic examination of specimens that had failed. The determination of the exact location of AE demonstrated that initial cracking occurred in the matrix rich regions when a large z-direction fiber bundle was used. For specimens with large z-direction fiber tows, the earliest matrix cracking could occur at half the stress for standard 2D woven composites with similar constituents. Damage accumulation in 3D architecture composites will be compared to damage accumulation in 2D architecture composites and discussed with respect to modeling composite stress-strain behavior and use of these composites at elevated temperatures.

Hybrid matrix fiber composites

DOEpatents

Deteresa, Steven J.; Lyon, Richard E.; Groves, Scott E.

2003-07-15

Hybrid matrix fiber composites having enhanced compressive performance as well as enhanced stiffness, toughness and durability suitable for compression-critical applications. The methods for producing the fiber composites using matrix hybridization. The hybrid matrix fiber composites include two chemically or physically bonded matrix materials, whereas the first matrix materials are used to impregnate multi-filament fibers formed into ribbons and the second matrix material is placed around and between the fiber ribbons that are impregnated with the first matrix material and both matrix materials are cured and solidified.

Metal matrix composite micromechanics: In-situ behavior influence on composite properties

NASA Technical Reports Server (NTRS)

Murthy, P. L. N.; Hopkins, D. A.; Chamis, C. C.

1989-01-01

Recent efforts in computational mechanics methods for simulating the nonlinear behavior of metal matrix composites have culminated in the implementation of the Metal Matrix Composite Analyzer (METCAN) computer code. In METCAN material nonlinearity is treated at the constituent (fiber, matrix, and interphase) level where the current material model describes a time-temperature-stress dependency of the constituent properties in a material behavior space. The composite properties are synthesized from the constituent instantaneous properties by virtue of composite micromechanics and macromechanics models. The behavior of metal matrix composites depends on fabrication process variables, in situ fiber and matrix properties, bonding between the fiber and matrix, and/or the properties of an interphase between the fiber and matrix. Specifically, the influence of in situ matrix strength and the interphase degradation on the unidirectional composite stress-strain behavior is examined. These types of studies provide insight into micromechanical behavior that may be helpful in resolving discrepancies between experimentally observed composite behavior and predicted response.

Fabrication and Characterization of Plasma-Sprayed Carbon-Fiber-Reinforced Aluminum Composites

NASA Astrophysics Data System (ADS)

Xiong, Jiang-tao; Zhang, Hao; Peng, Yu; Li, Jing-long; Zhang, Fu-sheng

2018-04-01

Carbon fiber ( C f)/Al specimens were fabricated by plasma-spraying aluminum powder on unidirectional carbon fiber bundles (CFBs) layer by layer, followed by a densification heat treatment process. The microstructure and chemical composition of the C f/Al composites were examined by scanning electron microscopy and energy-dispersive spectrometry. The CFBs were completely enveloped by aluminum matrix, and the peripheral regions of the CFBs were wetted by aluminum. In the wetted region, no significant Al4C3 reaction layer was found at the interface between the carbon fibers and aluminum matrix. The mechanical properties of the C f/Al specimens were evaluated. When the carbon fiber volume fraction (CFVF) was 9.2%, the ultimate tensile strength (UTS) of the C f/Al composites reached 138.3 MPa with elongation of 4.7%, 2.2 times the UTS of the Al matrix (i.e., 63 MPa). This strength ratio (between the UTS of C f/Al and the Al matrix) is higher than for most C f/Al composites fabricated by the commonly used method of liquid-based processing at the same CFVF level.

Damage Mechanics Model Development for Monocrystalline Superalloys (PREPRINT)

DTIC Science & Technology

2010-02-01

ferrite , austenite, martensite , and pearlite) colonies in alloy steels [17-20]  the structure of pitch-based carbon foams [21]  the γ-γ...reinforced metal-matrix composites [15, 16]  microstructure (cementite, ferrite , austenite, martensite , and pearlite) colonies in alloy steels [17-20... alloys [11, 12], and Pb-Sn alloys [13, 14]  reinforcement particle for particle -reinforced metal-matrix composites [15, 16] 

DOE Office of Scientific and Technical Information (OSTI.GOV)

Panwar, Ranvir Singh, E-mail: ranvir.panwar@thapar.edu; Pandey, O.P., E-mail: oppandey@thapar.edu

Particulate reinforced aluminum metal matrix composite is in high demand in automobile industry where the operational conditions vary from low to high temperature. In order to understand the wear mode at elevated temperature, this study was planned. For this purpose we developed a metal matrix composite containing aluminum alloy (LM13) as matrix and zircon sand as particulate reinforcement by stir casting process. Different amounts of zircon sand (5, 10, 15 and 20 wt.%) were incorporated in the matrix to study the effect of reinforcement on the wear resistance. Dispersion of zircon sand particles in the matrix was confirmed by usingmore » optical microscopy. Sliding wear tests were done to study the durability of the composite with respect to the base alloy. The effects of load and temperature on wear behavior from room temperature to 300 Degree-Sign C were studied to understand the wear mechanism deeply. Surface morphology of the worn surfaces after the wear tests as well as wear debris was observed under scanning electron microscope. Mild to severe wear transition was noticed in tests at high temperature and high load. However, there is interesting change in wear behavior of the composite near the critical temperature of the composite. All the observed behavior has been explained with reference to the observed microstructure of the wear track and debris. - Highlights: Black-Right-Pointing-Pointer Good interfacial bonding between zircon sand particles and Al matrix was observed. Black-Right-Pointing-Pointer The effect of temperature on the wear behavior of LM13/Zr composites was studied. Black-Right-Pointing-Pointer Wear resistance of the composite was improved with addition of zircon sand. Black-Right-Pointing-Pointer Transition temperature from mild to severe wear also improved in composite. Black-Right-Pointing-Pointer SEM analysis of the tracks and debris was done to establish wear mechanism.« less

Matrix density effects on the mechanical properties of SiC/RBSN composites

NASA Technical Reports Server (NTRS)

Bhatt, Ramakrishna T.; Kiser, James D.

1990-01-01

The room temperature mechanical properties were measured for SiC fiber reinforced reaction-bonded silicon nitride composites (SiC/RBSN) of different densities. The composites consisted of approx. 30 vol percent uniaxially aligned 142 micron diameter SiC fibers (Textron SCS-6) in a reaction-bonded Si3N4 matrix. The composite density was varied by changing the consolidation pressure during RBSN processing and by hot isostatically pressing the SiC/RBSN composites. Results indicate that as the consolidation pressure was increased from 27 to 138 MPa, the average pore size of the nitrided composites decreased from 0.04 to 0.02 microns and the composite density increased from 2.07 to 2.45 gm/cc. Nonetheless, these improvements resulted in only small increases in the first matrix cracking stress, primary elastic modulus, and ultimate tensile strength values of the composites. In contrast, HIP consolidation of SiC/RBSN resulted in a fully dense material whose first matrix cracking stress and elastic modulus were approx. 15 and 50 percent higher, respectively, and ultimate tensile strength values were approx. 40 percent lower than those for unHIPed SiC/RBSN composites. The modulus behavior for all specimens can be explained by simple rule-of-mixture theory. Also, the loss in ultimate strength for the HIPed composites appears to be related to a degradation in fiber strength at the HIP temperature. However, the density effect on matrix fracture strength was much less than would be expected based on typical monolithic Si3N4 behavior, suggesting that composite theory is indeed operating. Possible practical implications of these observations are discussed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shao, Yang; Guo, Fangmin; Ren, Yang

In an effort to further develop shape memory alloys (SMAs) for functional applications, much focus has been given in recent years to design and create innovative forms of SMAs, such as functionally graded SMAs, architecture SMAs, and SMA-based metallic composites. Here, we reports on the progress in creating NiTi-based composites of exceptional properties stimulated by the recent discovery of the principle of lattice strain matching between the SMA matrix and superelastic nanoinclusions embedded in the matrix. And based on this principle, different SMA–metal composites have been designed to achieve extraordinary shape memory performances, such as complete pseudoelastic behavior at asmore » low as 77 K and stress plateau as high as 1600 MPa, and exceptional mechanical properties, such as tensile strength as high as 2000 MPa and Young’s modulus as low as 28 GPa. Details are given for a NiTi–W micro-fiber composite prepared by melt infiltration, hot pressing, forging, and cold rolling. Furthermore, the composite contained 63% in volume of W micro-fibers of ~0.6 μm thickness. In situ synchrotron X-ray diffraction revealed that the NiTi matrix underwent martensite transformation during tensile deformation while the W micro-fiber deformed elastically with a maximum strain of 0.83% in the loading direction, implying a W fiber stress of 3280 MPa. The composite showed a maximum high tensile strength of 2300 MPa.« less

Nonleachable Imidazolium-Incorporated Composite for Disruption of Bacterial Clustering, Exopolysaccharide-Matrix Assembly, and Enhanced Biofilm Removal.

PubMed

Hwang, Geelsu; Koltisko, Bernard; Jin, Xiaoming; Koo, Hyun

2017-11-08

Surface-grown bacteria and production of an extracellular polymeric matrix modulate the assembly of highly cohesive and firmly attached biofilms, making them difficult to remove from solid surfaces. Inhibition of cell growth and inactivation of matrix-producing bacteria can impair biofilm formation and facilitate removal. Here, we developed a novel nonleachable antibacterial composite with potent antibiofilm activity by directly incorporating polymerizable imidazolium-containing resin (antibacterial resin with carbonate linkage; ABR-C) into a methacrylate-based scaffold (ABR-modified composite; ABR-MC) using an efficient yet simplified chemistry. Low-dose inclusion of imidazolium moiety (∼2 wt %) resulted in bioactivity with minimal cytotoxicity without compromising mechanical integrity of the restorative material. The antibiofilm properties of ABR-MC were assessed using an exopolysaccharide-matrix-producing (EPS-matrix-producing) oral pathogen (Streptococcus mutans) in an experimental biofilm model. Using high-resolution confocal fluorescence imaging and biophysical methods, we observed remarkable disruption of bacterial accumulation and defective 3D matrix structure on the surface of ABR-MC. Specifically, the antibacterial composite impaired the ability of S. mutans to form organized bacterial clusters on the surface, resulting in altered biofilm architecture with sparse cell accumulation and reduced amounts of EPS matrix (versus control composite). Biofilm topology analyses on the control composite revealed a highly organized and weblike EPS structure that tethers the bacterial clusters to each other and to the surface, forming a highly cohesive unit. In contrast, such a structured matrix was absent on the surface of ABR-MC with mostly sparse and amorphous EPS, indicating disruption in the biofilm physical stability. Consistent with lack of structural organization, the defective biofilm on the surface of ABR-MC was readily detached when subjected to low shear stress, while most of the biofilm biomass remained on the control surface. Altogether, we demonstrate a new nonleachable antibacterial composite with excellent antibiofilm activity without affecting its mechanical properties, which may serve as a platform for development of alternative antifouling biomaterials.

Low Cost Fabrication of Silicon Carbide Based Ceramics and Fiber Reinforced Composites

NASA Technical Reports Server (NTRS)

Singh, M.; Levine, S. R.

1995-01-01

A low cost processing technique called reaction forming for the fabrication of near-net and complex shaped components of silicon carbide based ceramics and composites is presented. This process consists of the production of a microporous carbon preform and subsequent infiltration with liquid silicon or silicon-refractory metal alloys. The microporous preforms are made by the pyrolysis of a polymerized resin mixture with very good control of pore volume and pore size thereby yielding materials with tailorable microstructure and composition. Mechanical properties (elastic modulus, flexural strength, and fracture toughness) of reaction-formed silicon carbide ceramics are presented. This processing approach is suitable for various kinds of reinforcements such as whiskers, particulates, fibers (tows, weaves, and filaments), and 3-D architectures. This approach has also been used to fabricate continuous silicon carbide fiber reinforced ceramic composites (CFCC's) with silicon carbide based matrices. Strong and tough composites with tailorable matrix microstructure and composition have been obtained. Microstructure and thermomechanical properties of a silicon carbide (SCS-6) fiber reinforced reaction-formed silicon carbide matrix composites are discussed.

Recycling of Aluminum Alloy with Dimox and Rheocasting Functionalize High Performance Structural Foam Composite

NASA Astrophysics Data System (ADS)

Rabeeh, Bakr Mohamed

Great efforts aiming towards the synthesis and the development of structural composite materials. Direct metal oxidation, DIMOX introduced for hybrid composite processing. However, oxidation temperatures around 1100°C lead to the formation of porous ceramic materials. To utilize this porosity intentionally for foam production, a new approach based on synergetic effect of alloying elements, DIMOX and semisolid (rheocsting) processing is developed. A semisolid reaction, rheocasting is introduced to control porosity shape and size. Aluminum alloy 6xxx (automobile scrap pistons) is recycled for this objective and DIMOX at 1100°C for 30 min, then rheocasting, at 750°C for 30 minutes. The effect of α-Fe powder, Mg powder, and Boric acid powder established for the objective of a hybrid structural metal matrix composite in bulk foam matrix. The kinetic of formation of hybrid metal matrix foam composite is introduced. Microstructural and mechanical characterization established for high performance Aluminum foam hybrid composite materials.

Thermographic imaging for high-temperature composite materials: A defect detection study

NASA Technical Reports Server (NTRS)

Roth, Don J.; Bodis, James R.; Bishop, Chip

1995-01-01

The ability of a thermographic imaging technique for detecting flat-bottom hole defects of various diameters and depths was evaluated in four composite systems (two types of ceramic matrix composites, one metal matrix composite, and one polymer matrix composite) of interest as high-temperature structural materials. The holes ranged from 1 to 13 mm in diameter and 0.1 to 2.5 mm in depth in samples approximately 2-3 mm thick. The thermographic imaging system utilized a scanning mirror optical system and infrared (IR) focusing lens in conjunction with a mercury cadmium telluride infrared detector element to obtain high resolution infrared images. High intensity flash lamps located on the same side as the infrared camera were used to heat the samples. After heating, up to 30 images were sequentially acquired at 70-150 msec intervals. Limits of detectability based on depth and diameter of the flat-bottom holes were defined for each composite material. Ultrasonic and radiographic images of the samples were obtained and compared with the thermographic images.

The effect of processing and compositional changes on the tribology of PM212 in air

NASA Technical Reports Server (NTRS)

Bogdanski, Michael S.; Sliney, Harold E.; Dellacorte, Christopher

1993-01-01

The effects of processing and compositional variations on the tribological performance of PM212 were studied. PM212 is a self lubricating powder metallurgy composite, comprised of a wear resistant metal bonded chromium carbide matrix, containing the solid lubricants barium fluoride/calcium fluoride eutectic and silver. Several composites were formulated which had lubricant, matrix, and processing variations. Processing variations included sintering and hot isostatic pressing. Pins fabricated from the composites were slid against superalloys disks in a pin-on-disk tribometer to study the tribological properties. Several composites exhibited low friction and wear in sliding against a nickel based superalloy. The tribological performance by several different composites showed that the composition of PM212 can be altered without dramatically affecting performance.

Resonance of electromagnetic absorption in a dielectric composite based on a high temperature superconductor

NASA Astrophysics Data System (ADS)

Grishin, A. M.; D'Iakonov, V. P.; Mezin, N. I.; Shapovalov, V. A.; Starostiuk, N. Iu.; Iarosh, G. S.

1992-10-01

A dielectric composite has been produced which is characterized by a sufficiently strong dependence of its microwave properties on weak magnetic fields. The composite is based on highly dispersed YBa2Cu3O(7-x) superconducting powder, with paraffin used as the matrix material. Results of a study of the magnetic and microwave properties of the composite are presented.

Effects of fiber and interfacial layer architectures on the thermoplastic response of metal matrix composites

NASA Technical Reports Server (NTRS)

Pindera, Marek-Jerzy; Freed, Alan D.; Arnold, Steven M.

1992-01-01

Examined here is the effect of fiber and interfacial layer morphologies on thermal fields in metal matrix composites (MMCs). A micromechanics model based on an arbitrarily layered concentric cylinder configuration is used to calculate thermal stress fields in MMCs subjected to spatially uniform temperature changes. The fiber is modelled as a layered material with isotropic or orthotropic elastic layers, whereas the surrounding matrix, including interfacial layers, is treated as a strain-hardening, elastoplastic, von Mises solid with temperature-dependent parameters. The solution to the boundary-value problem of an arbitrarily layered concentric cylinder under the prescribed thermal loading is obtained using the local/global stiffness matrix formulation originally developed for stress analysis of multilayered elastic media. Examples are provided that illustrate how the morphology of the SCS6 silicon carbide fiber and the use of multiple compliant layers at the fiber/matrix interface affect the evolution of residual stresses in SiC/Ti composites during fabrication cool-down.

Fatigue damage accumulation in various metal matrix composites

NASA Technical Reports Server (NTRS)

Johnson, W. S.

1987-01-01

The purpose of this paper is to review some of the latest understanding of the fatigue behavior of continuous fiber reinforced metal matrix composites. The emphasis is on the development of an understanding of different fatigue damage mechanisms and why and how they occur. The fatigue failure modes in continuous fiber reinforced metal matrix composites are controlled by the three constituents of the system: fiber, matrix, and fiber/matrix interface. The relative strains to fatigue failure of the fiber and matrix will determine the failure mode. Several examples of matrix, fiber, and self-similar damage growth dominated fatigue damage are given for several metal matrix composite systems. Composite analysis, failure modes, and damage modeling are discussed. Boron/aluminum, silicon-carbide/aluminum, FP/aluminum, and borsic/titanium metal matrix composites are discussed.

Twinning-induced plasticity (TWIP) and work hardening in Ti-based metallic glass matrix composites.

PubMed

Fan, J; Qiao, J W; Wang, Z H; Rao, W; Kang, G Z

2017-05-12

The present study demonstrates that Ti-based metallic glass matrix composites (MGMCs) with a normal composition of Ti 43 Zr 32 Ni 6 Ta 5 Be 14 containing ductile dendrites dispersed in the glass matrix has been developed, and deformation mechanisms about the tensile property have been investigated by focusing on twinning-induced plasticity (TWIP) effect. The Ti-based MGMC has excellent tensile properties and pronounced tensile work-hardening capacity, with a yield strength of 1100 MPa and homogeneous elongation of 4%. The distinguished strain hardening is ascribed to the formation of deformation twinning within the dendrites. Twinning generated in the dendrites works as an obstacle for the rapid propagation of shear bands, and then, the localized necking is avoided, which ensures the ductility of such kinds of composites. Besides, a finite-element model (FEM) has been established to explain the TWIP effect which brings out a work-hardening behavior in the present MGMC instead of a localized strain concentration. According to the plasticity theory of traditional crystal materials and some new alloys, TWIP effect is mainly controlled by stacking fault energy (SFE), which has been analyzed intensively in the present MGMC.

Method of producing a hybrid matrix fiber composite

DOEpatents

Deteresa, Steven J [Livermore, CA; Lyon, Richard E [Absecon, NJ; Groves, Scott E [Brentwood, CA

2006-03-28

Hybrid matrix fiber composites having enhanced compressive performance as well as enhanced stiffness, toughness and durability suitable for compression-critical applications. The methods for producing the fiber composites using matrix hybridization. The hybrid matrix fiber composites comprised of two chemically or physically bonded matrix materials, whereas the first matrix materials are used to impregnate multi-filament fibers formed into ribbons and the second matrix material is placed around and between the fiber ribbons that are impregnated with the first matrix material and both matrix materials are cured and solidified.

Inelastic response of metal matrix composites under biaxial loading

NASA Technical Reports Server (NTRS)

Lissenden, C. J.; Mirzadeh, F.; Pindera, M.-J.; Herakovich, C. T.

1991-01-01

Theoretical predictions and experimental results were obtained for inelastic response of unidirectional and angle ply composite tubes subjected to axial and torsional loading. The composite material consist of silicon carbide fibers in a titanium alloy matrix. This material is known to be susceptible to fiber matrix interfacial damage. A method to distinguish between matrix yielding and fiber matrix interfacial damage is suggested. Biaxial tests were conducted on the two different layup configurations using an MTS Axial/Torsional load frame with a PC based data acquisition system. The experimentally determined elastic moduli of the SiC/Ti system are compared with those predicted by a micromechanics model. The test results indicate that fiber matrix interfacial damage occurs at relatively low load levels and is a local phenomenon. The micromechanics model used is the method of cells originally proposed by Aboudi. Finite element models using the ABACUS finite element program were used to study end effects and fixture specimen interactions. The results to date have shown good correlation between theory and experiment for response prior to damage initiation.

Electrical Resistance of SiC/SiC Ceramic Matrix Composites for Damage Detection and Life-Prediction

NASA Technical Reports Server (NTRS)

Smith, Craig; Morscher, Gregory; Xia, Zhenhai

2009-01-01

Ceramic matrix composites (CMC) are suitable for high temperature structural applications such as turbine airfoils and hypersonic thermal protection systems due to their low density high thermal conductivity. The employment of these materials in such applications is limited by the ability to accurately monitor and predict damage evolution. Current nondestructive methods such as ultrasound, x-ray, and thermal imaging are limited in their ability to quantify small scale, transverse, in-plane, matrix cracks developed over long-time creep and fatigue conditions. CMC is a multifunctional material in which the damage is coupled with the material s electrical resistance, providing the possibility of real-time information about the damage state through monitoring of resistance. Here, resistance measurement of SiC/SiC composites under mechanical load at both room temperature monotonic and high temperature creep conditions, coupled with a modal acoustic emission technique, can relate the effects of temperature, strain, matrix cracks, fiber breaks, and oxidation to the change in electrical resistance. A multiscale model can in turn be developed for life prediction of in-service composites, based on electrical resistance methods. Results of tensile mechanical testing of SiC/SiC composites at room and high temperatures will be discussed. Data relating electrical resistivity to composite constituent content, fiber architecture, temperature, matrix crack formation, and oxidation will be explained, along with progress in modeling such properties.

High Temperature Mechanical Characterization and Analysis of Al2O3 /Al2O3 Composition

NASA Technical Reports Server (NTRS)

Gyekenyesi, John Z.; Jaskowiak, Martha H.

1999-01-01

Sixteen ply unidirectional zirconia coated single crystal Al2O3 fiber reinforced polycrystalline Al2O3 was tested in uniaxial tension at temperatures to 1400 C in air. Fiber volume fractions ranged from 26 to 31%. The matrix has primarily open porosity of approximately 40%. Theories for predicting the Young's modulus, first matrix cracking stress, and ultimate strength were applied and evaluated for suitability in predicting the mechanical behavior of Al2O3/Al2O3 composites. The composite exhibited pseudo tough behavior (increased area under the stress/strain curve relative to monolithic alumina) from 22 to 1400 C. The rule-of-mixtures provides a good estimate of the Young's modulus of the composite using the constituent properties from room temperature to approximately 1200 C for short term static tensile tests in air. The ACK theory provides the best approximation of the first matrix cracking stress while accounting for residual stresses at room temperature. Difficulties in determining the fiber/matrix interfacial shear stress at high temperatures prevented the accurate prediction of the first matrix cracking stress above room temperature. The theory of Cao and Thouless, based on Weibull statistics, gave the best prediction for the composite ultimate tensile strength.

A study of fiber volume fraction effects in notched unidirectional SCS-6/Ti-15V-3Cr-3Al-3Sn composite. Ph.D. Thesis Final Report

NASA Technical Reports Server (NTRS)

Covey, Steven J.

1993-01-01

Notched unidirectional SCS-6/Ti-15-3 composite of three different fiber volume fractions (vf = 0.15, 0.37, and 0.41) was investigated for various room temperature microstructural and material properties including: fatigue crack initiation, fatigue crack growth, and fracture toughness. While the matrix hardness is similar for all fiber volume fractions, the fiber/matrix interfacial shear strength and matrix residual stress increases with fiber volume fraction. The composite fatigue crack initiation stress is shown to be matrix controlled and occurs when the net maximum matrix stress approaches the endurance limit stress of the matrix. A model is presented which includes residual stresses and presents the composite initiation stress as a function of fiber volume fraction. This model predicts a maximum composite initiation stress at vf approximately 0.15 which agrees with the experimental data. The applied composite stress levels were increased as necessary for continued crack growth. The applied Delta(K) values at crack arrest increase with fiber volume fraction by an amount better approximated using an energy based formulation rather than when scaled linear with modulus. After crack arrest, the crack growth rate exponents for vf37 and vf41 were much lower and toughness much higher, when compared to the unreinforced matrix, because of the bridged region which parades with the propagating fatigue crack. However, the vf15 material exhibited a higher crack growth rate exponent and lower toughness than the unreinforced matrix because once the bridged fibers nearest the crack mouth broke, the stress redistribution broke all bridged fibers, leaving an unbridged crack. Degraded, unbridged behavior is modeled using the residual stress state in the matrix ahead of the crack tip. Plastic zone sizes were directly measured using a metallographic technique and allow prediction of an effective matrix stress intensity which agrees with the fiber pressure model if residual stresses are considered. The sophisticated macro/micro finite element models of the 0.15 and 0.37 fiber volume fractions presented show good agreement with experimental data and the fiber pressure model when an estimated effective fiber/matrix debond length is used.

Synthesis and Characterization of Novel Epoxy Geopolymer Hybrid Composites

PubMed Central

Roviello, Giuseppina; Ricciotti, Laura; Ferone, Claudio; Colangelo, Francesco; Cioffi, Raffaele; Tarallo, Oreste

2013-01-01

The preparation and the characterization of novel geopolymer-based hybrid composites are reported. These materials have been prepared through an innovative synthetic approach, based on a co-reticulation in mild conditions of commercial epoxy based organic resins and a metakaolin-based geopolymer inorganic matrix. This synthetic strategy allows the obtainment of a homogeneous dispersion of the organic particles in the inorganic matrix, up to 25% in weight of the resin. The materials obtained present significantly enhanced compressive strengths and toughness with respect to the neat geopolymer, suggesting their wide utilization for structural applications. A preliminary characterization of the porous materials obtained by removing the organic phase from the hybrid composites by means of heat treatments is also reported. Possible applications of these materials in the field of water purification, filtration, or as lightweight insulating materials are envisaged. PMID:28788310

Effect of Mechanical and Thermal Loading Histories on Residual Properties of SiCf/SiC Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Almansour, Amjad; Kiser, Doug; Smith, Craig; Bhatt, Ram; Gorican, Dan; Phillips, Ron; McCue, Terry R.

2017-01-01

Silicon Carbide based Ceramic Matrix Composites (CMCs) are attractive materials for use in high-temperature structural applications in the aerospace and nuclear industries. Under high stresses and temperatures, creep degradation is the dominant damage mechanism in CMCs. Consequently, chemical vapor infiltration (CVI) SiCf/SiC ceramic matrix composites (CMC) incorporating SylramicTM-iBN SiC fibers coated with boron nitride (BN) interphase and CVI-SiC matrix were tested to examine creep behavior in air at a range of elevated temperatures of (2200 - 2700 F). Samples that survived creep tests were evaluated via RT fast fracture tensile tests to determine residual properties, with the use of acoustic emission (AE) to assess stress dependent damage initiation and progression. Microscopy of regions within the gage section of the tested specimens was performed. Observed material degradation mechanisms are discussed.

Tension-Tension Fatigue Behavior of Unidirectional C/Sic Ceramic-Matrix Composite at Room Temperature and 800 °C in Air Atmosphere

PubMed Central

Li, Longbiao

2015-01-01

The tension-tension fatigue behavior of unidirectional C/SiC ceramic-matrix composite at room temperature and 800 °C under air has been investigated. The fatigue hysteresis modulus and fatigue hysteresis loss energy corresponding to different number of applied cycles have been analyzed. The fatigue hysteresis loops models for different interface slip cases have been derived based on the fatigue damage mechanism of fiber slipping relative to matrix in the interface debonded region upon unloading and subsequent reloading. The fiber/matrix interface shear stress has been estimated for different numbers of applied cycles. By combining the interface shear stress degradation model and fibers strength degradation model with fibers failure model, the tension-tension fatigue life S-N curves of unidirectional C/SiC composite at room temperature and 800 °C under air have been predicted.

Synthesis and crystalline properties of CdS incorporated polyvinylidene fluoride (PVDF) composite film

NASA Astrophysics Data System (ADS)

Patel, Arunendra Kumar; Sunder, Aishwarya; Mishra, Shweta; Bajpai, Rakesh

2018-05-01

This paper gives an insight on the synthesis and crystalline properties of Polyvinylidene Fluoride (PVDF) (host matrix) composites impregnated with Cadmium Sulphide (CdS) using Dimethyl formamide (DMF) as the base, prepared by the well known solvent casting technique. The effect of doping concentration of CdS in to the PVDF matrix was studied using X-ray diffraction technique. The structural properties like crystallinity Cr, interplanar distance d, average size of the crystalline region (D), and average inter crystalline separation (R) have been estimated for the developed composite. The crystallinity index, crystallite size and inter crystalline separation is increasing with increase in the concentration of CdS in to the PVDF matrix while the interplanar distance d is decreasing.

Continious production of exfoliated graphite composite compositions and flow field plates

DOEpatents

Shi, Jinjun; Zhamu, Aruna; Jang, Bor Z.

2010-07-20

A process of continuously producing a more isotropic, electrically conductive composite composition is provided. The process comprises: (a) continuously supplying a compressible mixture comprising exfoliated graphite worms and a binder or matrix material, wherein the binder or matrix material is in an amount of between 3% and 60% by weight based on the total weight of the mixture; (b) continuously compressing the compressible mixture at a pressure within the range of from about 5 psi or 0.035 MPa to about 50,000 psi or 350 MPa in at least a first direction into a cohered graphite composite compact; and (c) continuously compressing the composite compact in a second direction, different from the first direction, to form the composite composition in a sheet or plate form. The process leads to composite plates with exceptionally high thickness-direction electrical conductivity.

Thermoviscoplastic nonlinear constitutive relationships for structural analysis of high temperature metal matrix composites

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Hopkins, D. A.

1985-01-01

A set of thermoviscoplastic nonlinear constitutive relationships (1VP-NCR) is presented. The set was developed for application to high temperature metal matrix composites (HT-MMC) and is applicable to thermal and mechanical properties. Formulation of the TVP-NCR is based at the micromechanics level. The TVP-NCR are of simple form and readily integrated into nonlinear composite structural analysis. It is shown that the set of TVP-NCR is computationally effective. The set directly predicts complex materials behavior at all levels of the composite simulation, from the constituent materials, through the several levels of composite mechanics, and up to the global response of complex HT-MMC structural components.

Effects of Fiber/Matrix Interface and its Composition on Mechanical Properties of Hi Nicalon/Celsian Composites

NASA Technical Reports Server (NTRS)

Bansal, Narottam P.; Eldridge, Jeffrey I.

1998-01-01

Fiber-reinforced ceramic matrix composites (CMC) are prospective candidate materials for high temperature structural applications in aerospace, energy conservation, power generation, nuclear, petrochemical, and other industries. At NASA Lewis, we are investigating celsian matrix composites reinforced with various types of silicon carbide fibers. The objective of the present study was to investigate the effects of fiber/matrix interface and its composition on the mechanical properties of silicon carbide (Hi-Nicalon) fiber-reinforced celsian matrix composites.

Design of an optimized biomixture for the degradation of carbofuran based on pesticide removal and toxicity reduction of the matrix.

PubMed

Chin-Pampillo, Juan Salvador; Ruiz-Hidalgo, Karla; Masís-Mora, Mario; Carazo-Rojas, Elizabeth; Rodríguez-Rodríguez, Carlos E

2015-12-01

Pesticide biopurification systems contain a biologically active matrix (biomixture) responsible for the accelerated elimination of pesticides in wastewaters derived from pest control in crop fields. Biomixtures have been typically prepared using the volumetric composition 50:25:25 (lignocellulosic substrate/humic component/soil); nonetheless, formal composition optimization has not been performed so far. Carbofuran is an insecticide/nematicide of high toxicity widely employed in developing countries. Therefore, the composition of a highly efficient biomixture (composed of coconut fiber, compost, and soil, FCS) for the removal of carbofuran was optimized by means of a central composite design and response surface methodology. The volumetric content of soil and the ratio coconut fiber/compost were used as the design variables. The performance of the biomixture was assayed by considering the elimination of carbofuran, the mineralization of (14)C-carbofuran, and the residual toxicity of the matrix, as response variables. Based on the models, the optimal volumetric composition of the FCS biomixture consists of 45:13:42 (coconut fiber/compost/soil), which resulted in minimal residual toxicity and ∼99% carbofuran elimination after 3 days. This optimized biomixture considerably differs from the standard 50:25:25 composition, which remarks the importance of assessing the performance of newly developed biomixtures during the design of biopurification systems.

New composites of nanoparticle Cu (I) oxide and titania in a novel inorganic polymer (geopolymer) matrix for destruction of dyes and hazardous organic pollutants.

PubMed

Falah, Mahroo; MacKenzie, Kenneth J D; Knibbe, Ruth; Page, Samuel J; Hanna, John V

2016-11-15

New photoactive composites to efficiently remove organic dyes from water are reported. These consist of Cu2O/TiO2 nanoparticles in a novel inorganic geopolymer matrix modified by a large tertiary ammonium species (cetyltrimethylammonium bromide, CTAB) whose presence in the matrix is demonstrated by FTIR spectroscopy. The CTAB does not disrupt the tetrahedral geopolymer structural silica and alumina units as demonstrated by (29)Si and (27)Al MAS NMR spectroscopy. SEM/EDS, TEM and BET measurements suggest that the Cu2O/TiO2 nanoparticles are homogenously distributed on the surface and within the geopolymer pores. The mechanism of removal of methylene blue (MB) dye from solution consists of a combination of adsorption (under dark conditions) and photodegradation (under UV radiation). MB adsorption in the dark follows pseudo second-order kinetics and is described by Freundlich-Langmuir type isotherms. The performance of the CTAB-modified geopolymer based composites is superior to composites based on unmodified geopolymer hosts, the most effective composite containing 5wt% Cu2O/TiO2 in a CTAB-modified geopolymer host. These composites constitute a new class of materials with excellent potential in environmental protection applications. Copyright © 2016 Elsevier B.V. All rights reserved.

Meso-Scale Progressive Damage Behavior Characterization of Triaxial Braided Composites under Quasi-Static Tensile Load

NASA Astrophysics Data System (ADS)

Ren, Yiru; Zhang, Songjun; Jiang, Hongyong; Xiang, Jinwu

2018-04-01

Based on continuum damage mechanics (CDM), a sophisticated 3D meso-scale finite element (FE) model is proposed to characterize the progressive damage behavior of 2D Triaxial Braided Composites (2DTBC) with 60° braiding angle under quasi-static tensile load. The modified Von Mises strength criterion and 3D Hashin failure criterion are used to predict the damage initiation of the pure matrix and fiber tows. A combining interface damage and friction constitutive model is applied to predict the interface damage behavior. Murakami-Ohno stiffness degradation scheme is employed to predict the damage evolution process of each constituent. Coupling with the ordinary and translational symmetry boundary conditions, the tensile elastic response including tensile strength and failure strain of 2DTBC are in good agreement with the available experiment data. The numerical results show that the main failure modes of the composites under axial tensile load are pure matrix cracking, fiber and matrix tension failure in bias fiber tows, matrix tension failure in axial fiber tows and interface debonding; the main failure modes of the composites subjected to transverse tensile load are free-edge effect, matrix tension failure in bias fiber tows and interface debonding.

Insight into the Effects of Reinforcement Shape on Achieving Continuous Martensite Transformation in Phase Transforming Matrix Composites

NASA Astrophysics Data System (ADS)

Zhang, Xudong; Ren, Junqiang; Wang, Xiaofei; Zong, Hongxiang; Cui, Lishan; Ding, Xiangdong

2017-12-01

A continuous martensite transformation is indispensable for achieving large linear superelasticity and low modulus in phase transforming metal-based composites. However, determining how to accurately condition the residual martensite in a shape memory alloy matrix though the reinforcement shape to achieve continuous martensite transformation has been a challenge. Here, we take the finite element method to perform a comparative study of the effects of nanoinclusion shape on the interaction and martensite phase transformation in this new composite. Two typical samples are compared: one reinforced by metallic nanowires and the other by nanoparticles. We find that the residual martensite within the shape memory alloy matrix after a pretreatment can be tailored by the reinforcement shape. In particular, our results show that the shape memory alloy matrix can retain enough residual martensite phases to achieve continuous martensite transformation in the subsequent loading when the aspect ratio of nanoreinforcement is larger than 20. In contrast, the composites reinforced with spherical or low aspect ratio reinforcement show a typical nonlinear superelasticity as a result of a low stress transfer-induced discontinuous martensite transformation within the shape memory alloy matrix.

Development of Graphene Nanoplatelet-Reinforced AZ91 Magnesium Alloy by Solidification Processing

NASA Astrophysics Data System (ADS)

Kandemir, Sinan

2018-04-01

It is a challenging task to effectively incorporate graphene nanoplatelets (GNPs) which have recently emerged as potential reinforcement for strengthening metals into magnesium-based matrices by conventional solidification processes due to their large surface areas and poor wettability. A solidification processing which combines mechanical stirring and ultrasonic dispersion of reinforcements in liquid matrix was employed to develop AZ91 magnesium alloy matrix composites reinforced with 0.25 and 0.5 wt.% GNPs. The microstructural studies conducted with scanning and transmission electron microscopes revealed that fairly uniform distribution and dispersion of GNPs through the matrix were achieved due to effective combination of mechanical and ultrasonic stirring. The GNPs embedded into the magnesium matrix led to significant enhancement in the hardness, tensile strength and ductility of the composites compared to those of unreinforced AZ91 alloy. The strength enhancement was predominantly attributed to the grain refinement by the GNP addition and dislocation generation strengthening due to the coefficient of thermal expansion mismatch between the matrix and reinforcement. The improved ductility was attributed to the refinement of β eutectics by transforming from lamellar to the divorced eutectics due to the GNP additions. In addition, the strengthening efficiency of the composite with 0.25 wt.% GNP was found to be higher than those of the composite with 0.5 wt.% GNP as the agglomeration tendency of GNPs is increased with increasing GNP content. These results were compared with those of the GNP-reinforced magnesium composites reported in the literature, indicating the potential of the process introduced in this study in terms of fabricating light and high-performance metal matrix composites.

Organic matrix composite protective coatings for space applications

NASA Technical Reports Server (NTRS)

Dursch, Harry W.; George, Pete

1995-01-01

Successful use of composites in low earth orbit (LEO) depends on their ability to survive long-term exposure to atomic oxygen (AO), ultraviolet radiation, charged particle radiation, thermal cycling, and micrometeoroid and space debris. The AO environment is especially severe for unprotected organic matrix composites surfaces in LEO. Ram facing unprotected graphite/epoxy flown on the 69-month Long Duration Exposure Facility (LDEF) mission lost up to one ply of thickness (5 mils) resulting in decreased mechanical properties. The expected AO fluence of the 30 year Space Station Alpha mission is approximately 20 times that seen on LDEF. This exposure would result in significant material loss of unprotected ram facing organic matrix composites. Several protective coatings for composites were flown on LDEF including anodized aluminum, vacuum deposited coatings, a variety of thermal control coatings, metalized Teflon, and leafing aluminum. Results from the testing and analysis of the coated and uncoated composite specimens flown on LDEF's leading and trailing edges provide the baseline for determining the effectiveness of protectively coated composites in LEO. In addition to LDEF results, results from shuttle flight experiments and ground based testing will be discussed.

DARPA - Advanced Composite Materials Annual Presentation Held in Gainesville, Florida on 19-20 November 1992

DTIC Science & Technology

1992-11-20

34 and M.D. Sacks 13) "Fabrication of SiC -Based Composites by Reactive Infiltration of Metals (RIM)" K. Wang," G.W. Scheiffele, P.J. Sanchez-Soto, and...Ig I I keactive Infiltration of Metals (RIM) Ii * Densification with little or no shrinkage e SIC -based composites with little or no residual metal...M.D. Sacks I) Indicates Presenter Intermetallic: Matrix Composites 14) *Processing of Compositionally Tailored Silica-Free MoSi 2/ SiC Composites ’ S

Influence of particle size on Cutting Forces and Surface Roughness in Machining of B4Cp - 6061 Aluminium Matrix Composites

NASA Astrophysics Data System (ADS)

Hiremath, Vijaykumar; Badiger, Pradeep; Auradi, V.; Dundur, S. T.; Kori, S. A.

2016-02-01

Amongst advanced materials, metal matrix composites (MMC) are gaining importance as materials for structural applications in particular, particulate reinforced aluminium MMCs have received considerable attention due to their superior properties such as high strength to weight ratio, excellent low-temperature performance, high wear resistance, high thermal conductivity. The present study aims at studying and comparing the machinability aspects of B4Cp reinforced 6061Al alloy metal matrix composites reinforced with 37μm and 88μm particulates produced by stir casting method. The micro structural characterization of the prepared composites is done using Scanning Electron Microscopy equipped with EDX analysis (Hitachi Su-1500 model) to identify morphology and distribution of B4C particles in the 6061Al matrix. The specimens are turned on a conventional lathe machine using a Polly crystalline Diamond (PCD) tool to study the effect of particle size on the cutting forces and the surface roughness under varying machinability parameters viz., Cutting speed (29-45 m/min.), Feed rate (0.11-0.33 mm/rev.) and depth of cut (0.5-1mm). Results of micro structural characterization revealed fairly uniform distribution of B4C particles (in both cases i.e., 37μm and 88μm) in 6061Al matrix. The surface roughness of the composite is influenced by cutting speed. The feed rate and depth of cut have a negative influence on surface roughness. The cutting forces decreased with increase in cutting speed whereas cutting forces increased with increase in feed and depth of cut. Higher cutting forces are noticed while machining Al6061 base alloy compared to reinforced composites. Surface finish is high during turning of the 6061Al base alloy and surface roughness is high with 88μm size particle reinforced composites. As the particle size increases Surface roughness also increases.

Turbine component, turbine blade, and turbine component fabrication process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delvaux, John McConnell; Cairo, Ronald Ralph; Parolini, Jason Robert

A turbine component, a turbine blade, and a turbine component fabrication process are disclosed. The turbine component includes ceramic matrix composite plies and a feature configured for preventing interlaminar tension of the ceramic matrix composite plies. The feature is selected from the group consisting of ceramic matrix composite tows or precast insert tows extending through at least a portion of the ceramic matrix composite plies, a woven fabric having fiber tows or a precast insert preventing contact between a first set of the ceramic matrix composite plies and a second set of the ceramic matrix composite plies, and combinations thereof.more » The process includes laying up ceramic matrix composite plies in a preselected arrangement and securing a feature configured for interlaminar tension.« less

Low-Cost Resin Transfer Molding Process Developed for High-Temperature Polyimide Matrix Composites

NASA Technical Reports Server (NTRS)

1996-01-01

The use of high-temperature polymer matrix composites (PMC's) in aircraft engine applications can significantly reduce engine weight and improve performance and fuel efficiency. High-temperature PMC's, such as those based on the PMR-15 polyimide matrix resin developed by the NASA Lewis Research Center, have been used extensively in military applications where performance improvements have justified their use regardless of the cost involved in producing the component. However, in commercial engines cost is a primary driver, and PMC components must be produced at costs comparable to those of the metal components that they will replace.

Internal damping due to dislocation movements induced by thermal expansion mismatch between matrix and particles in metal matrix composites. [Al/SiC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Girand, C.; Lormand, G.; Fougeres, R.

In metal matrix composites (MMCs), the mechanical 1 of the reinforcement-matrix interface is an important parameter because it governs the load transfer from matrix to particles, from which the mechanical properties of these materials are derived. Therefore, it would be useful to set out an experimental method able to characterize the interface and the adjacent matrix behaviors. Thus, a study has been undertaken by means of internal damping (I.D.) measurements, which are well known to be very sensitive for studying irreversible displacements at the atomic scale. More especially, this investigation is based on the fact that, during cooling of MMC's,more » stress concentrations originating from differences in coefficients of thermal expansion (C.T.E.) of matrix and particles should induce dislocation movements in the matrix surrounding the reinforcement; that is, local microplastic strains occur. Therefore, during I.D. measurements vs temperature these movements should contribute to MMCs I.D. in a process similar to those involved around first order phase transitions in solids. The aim of this paper is to present, in the case of Al/SiC particulate composites, new developments of this approach that has previously led to promising results in the case of Al-Si alloys.« less

Metal- and Polymer-Matrix Composites: Functional Lightweight Materials for High-Performance Structures

NASA Astrophysics Data System (ADS)

Gupta, Nikhil; Paramsothy, Muralidharan

2014-06-01

The special topic "Metal- and Polymer-Matrix Composites" is intended to capture the state of the art in the research and practice of functional composites. The current set of articles related to metal-matrix composites includes reviews on functionalities such as self-healing, self-lubricating, and self-cleaning capabilities; research results on a variety of aluminum-matrix composites; and investigations on advanced composites manufacturing methods. In addition, the processing and properties of carbon nanotube-reinforced polymer-matrix composites and adhesive bonding of laminated composites are discussed. The literature on functional metal-matrix composites is relatively scarce compared to functional polymer-matrix composites. The demand for lightweight composites in the transportation sector is fueling the rapid development in this field, which is captured in the current set of articles. The possibility of simultaneously tailoring several desired properties is attractive but very challenging, and it requires significant advancements in the science and technology of composite materials. The progress captured in the current set of articles shows promise for developing materials that seem capable of moving this field from laboratory-scale prototypes to actual industrial applications.

Nanocrystal/sol-gel nanocomposites

DOEpatents

Petruska, Melissa A [Los Alamos, NM; Klimov, Victor L [Los Alamos, NM

2007-06-05

The present invention is directed to solid composites including colloidal nanocrystals within a sol-gel host or matrix and to processes of forming such solid composites. The present invention is further directed to alcohol soluble colloidal nanocrystals useful in formation of sol-gel based solid composites.

Nanocrystal/sol-gel nanocomposites

DOEpatents

Petruska, Melissa A [Los Alamos, NM; Klimov, Victor L [Los Alamos, NM

2012-06-12

The present invention is directed to solid composites including colloidal nanocrystals within a sol-gel host or matrix and to processes of forming such solid composites. The present invention is further directed to alcohol soluble colloidal nanocrystals useful in formation of sol-gel based solid composites

Fracture Mechanics of Transverse Cracks and Edge Delamination in Graphite-Epoxy Composite Laminates.

DTIC Science & Technology

1982-03-01

Fracture failure in multi-layer epoxy-based composite laminates seldom begins with breaking of the load-carrying reinforcing fibers. Rather, smeall...often observed sub-laminate fracture mudes in, e.g., glass-epoxy and graph- ite-epoxy composite laminates. Although these matrix-dominated crackings...the uicrostructures of any given fibrous composite , fracture analysis of sub-laminate cracks based on micro leanie [I Is almost Impossible If not

Mechanical Properties and Fatigue Behavior of Unitized Composite Airframe Structures at Elevated Temperature

DTIC Science & Technology

2016-09-01

investigated. The unitized composite consisted of a polymer matrix composite (PMC) co-cured with a ceramic matrix composite (CMC). The PMC portion...ply non- crimp 3D orthogonal weave composite consisting of a ceramic matrix reinforced with glass fibers. In order to assess the performance and...2.3 Ceramic Matrix Composites ...................................................................................5  2.4 2D vs 3D Reinforcement

Strong, Tough, and Pest Resistant MoSi2-Base Hybrid Composite for Structural Applications

NASA Technical Reports Server (NTRS)

Hebsur, M. G.; Nathal, M. V.

1997-01-01

Addition of about 30 to 50 vol % of Si3N4 particulate to MoSi2 improved resistance to low temperature accelerated oxidation by forming a Si2ON2 protective scale and thereby eliminating catastrophic 'pest failure'. The Si3N4 addition also improved the high temperature creep strength by nearly five orders of magnitude, doubled the room temperature toughness and significantly lowered the CTE of the MoSi2 and eliminated matrix cracking in SCS-6 reinforced composites even after thermal cycling. The SCS-6 fiber reinforcement improved the room temperature fracture toughness by seven times and impact resistance by five times. The composite exhibited excellent strength and toughness improvement up to 1400 C. More recently, tape casting was adopted as the preferred processing of MoSi2-base composites for improved fiber spacing, ability to use small diameter fibers, and for lower cost. Good strength and toughness values were also obtained with fine diameter Hi-Nicalon tow fibers. This hybrid composite remains competitive with ceramic matrix composites as a replacement for Ni-base superalloys in aircraft engine applications.

MoSi2-Base Hybrid Composites from Aeroengine Applications

NASA Technical Reports Server (NTRS)

Hebsur, Mohan G.

2000-01-01

Addition of about 30 to 50 vol % of Si3N4 particulate to MoSi2 improved low temperature accelerated oxidation resistance by forming a Si2ON2 protective scale and thereby eliminated catastrophic 'pest failure'. The Si3N4 addition also improved the high temperature creep strength by nearly five orders of magnitude, doubled the room temperature toughness, and significantly lowered the CTE of the MoSi2 which eliminated matrix cracking in SCS-6 reinforced composites even after thermal cycling. The SCS-6 fiber reinforcement improved the room temperature fracture toughness by seven times and impact resistance by five times. The composite exhibited this excellent strength and toughness improvement up to 1673 K. More recently, tape casting was adopted as the preferred processing of MoSi2-base composites due to improved fiber spacing, ability to use small diameter fibers, and for lower cost. Good strength and toughness values were also obtained with fine diameter Hi-Nicalon tow fibers. These hybrid composites remain competitive with ceramic matrix composites as a replacement for Ni-base superalloys in aircraft engine applications.

Method of forming a ceramic matrix composite and a ceramic matrix component

DOE Office of Scientific and Technical Information (OSTI.GOV)

de Diego, Peter; Zhang, James

A method of forming a ceramic matrix composite component includes providing a formed ceramic member having a cavity, filling at least a portion of the cavity with a ceramic foam. The ceramic foam is deposited on a barrier layer covering at least one internal passage of the cavity. The method includes processing the formed ceramic member and ceramic foam to obtain a ceramic matrix composite component. Also provided is a method of forming a ceramic matrix composite blade and a ceramic matrix composite component.

The Effect of Fiber Architecture on Matrix Cracking in Sic/sic Cmc's

NASA Technical Reports Server (NTRS)

Morscher, Gregory N.

2005-01-01

Applications incorporating silicon carbide fiber reinforced silicon carbide matrix composites (CMC's) will require a wide range of fiber architectures in order to fabricate complex shape. The stress-strain response of a given SiC/SiC system for different architectures and orientations will be required in order to design and effectively life-model future components. The mechanism for non-linear stress-strain behavior in CMC's is the formation and propagation of bridged-matrix cracks throughout the composite. A considerable amount of understanding has been achieved for the stress-dependent matrix cracking behavior of SiC fiber reinforced SiC matrix systems containing melt-infiltrated Si. This presentation will outline the effect of 2D and 3D architectures and orientation on stress-dependent matrix-cracking and how this information can be used to model material behavior and serve as the starting point foe mechanistic-based life-models.

The microstructure-processing-property relationships in an aluminum matrix composite system reinforced by aluminum-copper-iron alloy particles

NASA Astrophysics Data System (ADS)

Tang, Fei

Solid state vacuum sintering was studied in tap densified Al powder and in hot quasi-isostatically forged samples composed of commercial inert gas atomized or high purity Al powder, generated by a gas atomization reaction synthesis (GARS) technique. The GARS process results in spherical Al powder with a far thinner surface oxide. The overall results indicated the enhanced ability of GARS-processed Al and Al alloy powders for solid state sintering, which may lead to simplification of current Al powder consolidation processing methods. Elemental Al-based composites reinforced with spherical Al-Cu-Fe alloy powders were produced by quasi-isostatic forging and vacuum hot pressing (VHP) consolidation methods. It was proved that spherical Al-Cu-Fe alloy powders can serve as an effective reinforcement particulate for elemental Al-based composites, because of their high hardness and a preferred type of matrix/reinforcement interfacial bonding, with reduced strain concentration around the particles. Ultimate tensile strength and yield strength of the composites were increased over the corresponding Al matrix values, far beyond typical observations. This remarkable strengthening was achieved without precipitation hardening and without severe strain hardening during consolidation because of the matrix choice (elemental Al) and the "low shear" consolidation methods utilized. This reinforcement effectiveness is further evidenced by elastic modulus measurements of the composites that are very close to the upper bound predictions of the rule of mixtures. The load partitioning measurements by neutron diffraction showed that composite samples made from GARS powders present significantly higher load transfer efficiency than the composites made from commercially atomized powders. Further analysis of the load sharing measurements and the calculated values of the mismatch of coefficient of thermal expansion (CTE) and the geometrically necessary dislocation (GND) effects suggest that these strengthening mechanisms can be combined to predict accurately the strength of the composites. By neutron diffraction measurements, it also was found that the composites consolidated from Al and Al63Cu25Fe12 quasicrystal alloy reinforcement powders have compressive residual stress in the Al matrix, contrary to the tensile residual stress in typical Al/SiC composites. The composites made by the quasi-isostatic forging process exhibited higher tensile strengths and much higher compressive residual stresses than the composites made by the VHP process.

Preliminary Investigation to Determine the Suitable Mixture Composition for Corn Starch Matrix

NASA Astrophysics Data System (ADS)

Huzaimi Zakaria, Nazri; Ngali, Zamani; Zulkefli Selamat, Mohd

2017-01-01

The use of natural fiber as reinforcement in polymeric composites has been seen a dramatically increase over the last decades. The surge in the interest of natural fiber composite or biodegradable composite is mainly due to the attractive cost of production, improved of hardness, better fatigue endurance and good thermal and mechanical resistivity. In this work, corn starch in the form of powder is utilized as the matrix of the composite. However, starch is brittle and has low strength make it inappropriate candidate for matrix binder. The main objective of this study is to modify the mechanical properties of pure corn starch by mixing it with water, glycerol and vinegar. The composition ratio of water is 60~80%, corn starch 10~35%, glycerol is 5~15% and vinegar is 0~5%, ten samples (A-J) have been manufactured and the best mixture composition is selected based on few selection criteria. The selection criteria are visual impaction, hardness and density. From the results, the samples without vinegar are not suitable to be used because of the fungus availability on the surface. Meanwhile the results from the samples with 5 ml vinegar have no fungus on their surface even has been exposed to the ambient air. While the sample C has shown the best sample based on the visual, hardness and density test.

TiC-Fe-Based Composite Coating Prepared by Self-Propagating High-Temperature Synthesis

NASA Astrophysics Data System (ADS)

He, Shen; Fan, Xi'an; Chang, Qingming; Xiao, Lixiang

2017-06-01

TiC-Fe-based composite coatings were prepared in situ by self-propagating high-temperature synthesis combined with vacuum expendable pattern casting process. The band-like TiC phase embedded in a continuous Fe binder. There were no obvious defects and impurities at the interface between coatings and matrices. Fe presented consecutively in the coating zones and substrate zones without interruption and the microhardness in the cross-sectional area of the coating-matrix reduces continuously from the coating to the matrix area, indicating a good metallurgical bonding between the coatings and matrices. The effect of casting temperature on the microstructure and hardness of TiC-Fe-based composite coating was investigated in detail. The TiC particles formed at low casting temperature were nearly spherical in shape, and the size of TiC particles increased with increasing casting temperature due to more agglomeration. The hardness of the coatings increased first and then decreased with increasing casting temperature, and reached the highest value of 68 HRC when the casting temperature was 1773 K (1500 °C), which was twice more than that of the matrix.

Stochastic-Strength-Based Damage Simulation of Ceramic Matrix Composite Laminates

NASA Technical Reports Server (NTRS)

Nemeth, Noel N.; Mital, Subodh K.; Murthy, Pappu L. N.; Bednarcyk, Brett A.; Pineda, Evan J.; Bhatt, Ramakrishna T.; Arnold, Steven M.

2016-01-01

The Finite Element Analysis-Micromechanics Analysis Code/Ceramics Analysis and Reliability Evaluation of Structures (FEAMAC/CARES) program was used to characterize and predict the progressive damage response of silicon-carbide-fiber-reinforced reaction-bonded silicon nitride matrix (SiC/RBSN) composite laminate tensile specimens. Studied were unidirectional laminates [0] (sub 8), [10] (sub 8), [45] (sub 8), and [90] (sub 8); cross-ply laminates [0 (sub 2) divided by 90 (sub 2),]s; angled-ply laminates [plus 45 (sub 2) divided by -45 (sub 2), ]s; doubled-edge-notched [0] (sub 8), laminates; and central-hole laminates. Results correlated well with the experimental data. This work was performed as a validation and benchmarking exercise of the FEAMAC/CARES program. FEAMAC/CARES simulates stochastic-based discrete-event progressive damage of ceramic matrix composite and polymer matrix composite material structures. It couples three software programs: (1) the Micromechanics Analysis Code with Generalized Method of Cells (MAC/GMC), (2) the Ceramics Analysis and Reliability Evaluation of Structures Life Prediction Program (CARES/Life), and (3) the Abaqus finite element analysis program. MAC/GMC contributes multiscale modeling capabilities and micromechanics relations to determine stresses and deformations at the microscale of the composite material repeating-unit-cell (RUC). CARES/Life contributes statistical multiaxial failure criteria that can be applied to the individual brittle-material constituents of the RUC, and Abaqus is used to model the overall composite structure. For each FEAMAC/CARES simulation trial, the stochastic nature of brittle material strength results in random, discrete damage events that incrementally progress until ultimate structural failure.

A Nonlinear Three-Dimensional Micromechanics Model for Fiber-Reinforced Laminated Composites

DTIC Science & Technology

1993-11-01

Interfacial Properties Employed for the SCS6/Ti-15-3 Composite ......................... 150 11. Constants Employed for the LLFM Predictions of Quasi...Region m Matrix Property or Mean of the Interfacial Stress Distribution ml, m2, m3 Signifies Matrix Region n Normal to Interface r Signifies Equation...usage of the new class of titanium based com- posites in advanced aerospace structures and engines such as are targeted for the advanced tactical fighter

Mars Mission Analysis Trades Based on Legacy and Future Nuclear Propulsion Options

NASA Astrophysics Data System (ADS)

Joyner, Russell; Lentati, Andrea; Cichon, Jaclyn

2007-01-01

The purpose of this paper is to discuss the results of mission-based system trades when using a nuclear thermal propulsion (NTP) system for Solar System exploration. The results are based on comparing reactor designs that use a ceramic-metallic (CERMET), graphite matrix, graphite composite matrix, or carbide matrix fuel element designs. The composite graphite matrix and CERMET designs have been examined for providing power as well as propulsion. Approaches to the design of the NTP to be discussed will include an examination of graphite, composite, carbide, and CERMET core designs and the attributes of each in regards to performance and power generation capability. The focus is on NTP approaches based on tested fuel materials within a prismatic fuel form per the Argonne National Laboratory testing and the ROVER/NERVA program. NTP concepts have been examined for several years at Pratt & Whitney Rocketdyne for use as the primary propulsion for human missions beyond earth. Recently, an approach was taken to examine the design trades between specific NTP concepts; NERVA-based (UC)C-Graphite, (UC,ZrC)C-Composite, (U,Zr)C-Solid Carbide and UO2-W CERMET. Using Pratt & Whitney Rocketdyne's multidisciplinary design analysis capability, a detailed mission and vehicle model has been used to examine how several of these NTP designs impact a human Mars mission. Trends for the propulsion system mass as a function of power level (i.e. thrust size) for the graphite-carbide and CERMET designs were established and correlated against data created over the past forty years. These were used for the mission trade study. The resulting mission trades presented in this paper used a comprehensive modeling approach that captures the mission, vehicle subsystems, and NTP sizing.

ICAN/PART: Particulate composite analyzer, user's manual and verification studies

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.; Murthy, Pappu L. N.; Mital, Subodh K.

1996-01-01

A methodology for predicting the equivalent properties and constituent microstresses for particulate matrix composites, based on the micromechanics approach, is developed. These equations are integrated into a computer code developed to predict the equivalent properties and microstresses of fiber reinforced polymer matrix composites to form a new computer code, ICAN/PART. Details of the flowchart, input and output for ICAN/PART are described, along with examples of the input and output. Only the differences between ICAN/PART and the original ICAN code are described in detail, and the user is assumed to be familiar with the structure and usage of the original ICAN code. Detailed verification studies, utilizing dim dimensional finite element and boundary element analyses, are conducted in order to verify that the micromechanics methodology accurately models the mechanics of particulate matrix composites. ne equivalent properties computed by ICAN/PART fall within bounds established by the finite element and boundary element results. Furthermore, constituent microstresses computed by ICAN/PART agree in average sense with results computed using the finite element method. The verification studies indicate that the micromechanics programmed into ICAN/PART do indeed accurately model the mechanics of particulate matrix composites.

Size effects on magnetoelectric response of multiferroic composite with inhomogeneities

NASA Astrophysics Data System (ADS)

Yue, Y. M.; Xu, K. Y.; Chen, T.; Aifantis, E. C.

2015-12-01

This paper investigates the influence of size effects on the magnetoelectric performance of multiferroic composite with inhomogeneities. Based on a simple model of gradient elasticity for multiferroic materials, the governing equations and boundary conditions are obtained from an energy variational principle. The general formulation is applied to consider an anti-plane problem of multiferroic composites with inhomogeneities. This problem is solved analytically and the effective magnetoelectric coefficient is obtained. The influence of the internal length (grain size or particle size) on the effective magnetoelectric coefficients of piezoelectric/piezomagnetic nanoscale fibrous composite is numerically evaluated and analyzed. The results suggest that with the increase of the internal length of piezoelectric matrix (PZT and BaTiO3), the magnetoelectric coefficient increases, but the rate of increase is ratcheting downwards. If the internal length of piezoelectric matrix remains unchanged, the magnetoelectric coefficient will decrease with the increase of internal length scale of piezomagnetic nonfiber (CoFe2O3). In a composite consisiting of a piezomagnetic matrix (CoFe2O3) reinforced with piezoelectric nanofibers (BaTiO3), an increase of the internal length in the piezomagnetic matrix, results to a decrease of the magnetoelectric coefficient, with the rate of decrease diminishing.

Application of Analytic Hierarchy Process (AHP) in the analysis of the fuel efficiency in the automobile industry with the utilization of Natural Fiber Polymer Composites (NFPC)

NASA Astrophysics Data System (ADS)

Jayamani, E.; Perera, D. S.; Soon, K. H.; Bakri, M. K. B.

2017-04-01

A systematic method of material analysis aiming for fuel efficiency improvement with the utilization of natural fiber reinforced polymer matrix composites in the automobile industry is proposed. A multi-factor based decision criteria with Analytical Hierarchy Process (AHP) was used and executed through MATLAB to achieve improved fuel efficiency through the weight reduction of vehicular components by effective comparison between two engine hood designs. The reduction was simulated by utilizing natural fiber polymer composites with thermoplastic polypropylene (PP) as the matrix polymer and benchmarked against a synthetic based composite component. Results showed that PP with 35% of flax fiber loading achieved a 0.4% improvement in fuel efficiency, and it was the highest among the 27 candidate fibers.

Comparative Experimental Study on Ionic Polymer Mental Composite based on Nafion and Aquivion Membrane as Actuators

NASA Astrophysics Data System (ADS)

Luo, B.; Chen, Z.

2017-11-01

Most ionic polymer mental composites employ Nafion as the polymer matrix, Aquivion can also manufactured as ionic polymer mental composite while research was little. This paper researched on two kinds of ionic polymer mental composite based on Aquivion and Nafion matrix with palladium electrode called Aquivion-IPMC and Nafion-IPMC. The samples were fabricated by the same preparation process. The current and deformation responses of the samples were measured at voltage to characterize the mechano-electrical properties. The experimental observations revealed that shorter flexible side chains in Aquivion-IPMC provide a larger force than Nafion-IPMC, while the displacement properties were similar in two different samples. The results also showed that Aquivion membrane can also replace Nafion to reproduce IPMC application in soft robots, MEMS, and so on.

The High-Temperature Wear and Oxidation Behavior of CrC-Based HVOF Coatings

NASA Astrophysics Data System (ADS)

Houdková, Šárka; Česánek, Zdeněk; Smazalová, Eva; Lukáč, František

2018-01-01

Three commercially available chromium carbide-based powders with different kinds of matrix (Cr3C2-25%NiCr; Cr3C2-25%CoNiCrAlY and Cr3C2-50%NiCrMoNb) were deposited by an HVOF JP-5000 spraying gun, evaluated and compared. The influence of heat treatment on the microstructure and properties, as well as the oxidation resistance in a hot steam environment ( p = 24 MPa; T = 609 °C), was evaluated by SEM and XRD with respect to their potential application in the steam power industry. The sliding wear resistance measured at room and elevated ( T = 600 °C) temperatures according to ASTM G-133. For all three kinds of chromium carbide-based coatings, the precipitation of secondary carbides from the supersaturated matrix was observed during the heat treatment. For Cr3C2-25%NiCr coating annealed in hot steam environment as well as for Cr3C2-25%CoNiCrAlY coating in both environments, the inner carbide oxidation was recorded. The sliding wear resistance was found equal at room temperature, regardless of the matrix composition and content, while at elevated temperatures, the higher wear was measured, varying in dependence on the matrix composition and content. The chromium carbide-based coating with modified matrix composition Cr3C2-50%NiCrMoNb is suitable to replace the Cr3C2-25%NiCr coating in a hot steam environment to eliminate the risk of failure caused by inner carbide oxidation.

Corrosion and wear resistance of titanium- and aluminum-based metal matrix composites fabricated by direct metal laser deposition

NASA Astrophysics Data System (ADS)

Waldera, Benjamin L.

Titanium- and Aluminum-based metal matrix composites (MMC) have shown favorable properties for aerospace applications such as airframes, reinforcement materials and joining elements. In this research, such coatings were developed by direct metal laser deposition with a powder-fed fiber coupled diode laser. The MMC formulations consisted of pure titanium and aluminum matrices with reinforcing powder blends of chromium carbide and tungsten carbide nickel alloy. Two powder formulations were investigated for each matrix material (Ti1, Ti2, Al1 and Al2). Titanium based composites were deposited onto a Ti6Al4V plate while aluminum composites were deposited onto AA 7075 and AA 5083 for Al1 and Al2, respectively. Microstructures of the MMCs were studied by optical and scanning electron microscopy. The hardness and reduced Young's modulus (Er) were assessed through depth-sensing instrumented nanoindentation. microhardness (Vickers) was also analyzed for each composite. The corrosion resistance of the MMCs were compared by monitoring open circuit potential (OCP), polarization resistance (Rp) and potentiodynamic polarization in 0.5 M NaCl to simulate exposure to seawater. The Ti-MMCs demonstrated improvements in hardness between 205% and 350% over Ti6Al4V. Al-MMCs showed improvements between 47% and 79% over AA 7075 and AA 5083. The MMCs showed an increase in anodic current density indicating the formation of a less protective surface oxide than the base metals.

Comparative Studies on Al-Based Composite Powder Reinforced with Nano Garnet and Multi-wall Carbon Nanotubes

NASA Astrophysics Data System (ADS)

Basariya, M. Raviathul; Srivastava, V. C.; Mukhopadhyay, N. K.

2015-11-01

Effect of mechanical alloying/milling on microstructural evolution and hardness variations of garnet and multi-walled carbon nanotubes (MWCNTs)-reinforced Al-Mg-Si alloy (EN AW6082) composites are investigated. Structural and morphological studies revealed that the composite powders prepared by milling display a more homogenous distribution of the reinforcing particles. Improved nanoindentation hardness viz., 4.24 and 5.90 GPa are achieved for EN AW6082/Garnet and EN AW6082/MWCNTs composites, respectively, and it is attributed to severe deformation of the aluminum alloy powders and embedding of the harder reinforcement particles uniformly into the aluminum alloy matrix. However, enhancement in case of MWCNTs-reinforced composite makes apparent the effect of its nanosized uniform dispersion in the matrix, thereby resisting the plastic deformation at lower stress and increased dislocation density evolved during high-energy ball milling. The results of the present study indicate that carbon nanotubes and garnet can be effectively used as reinforcements for Al-based composites.

Design, fabrication, and properties of 2-2 connectivity cement/polymer based piezoelectric composites with varied piezoelectric phase distribution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dongyu, Xu; Department of Mechanical Engineering, University of South Carolina, Columbia, South Carolina 29208; Xin, Cheng

2014-12-28

The laminated 2-2 connectivity cement/polymer based piezoelectric composites with varied piezoelectric phase distribution were fabricated by employing Lead Zirconium Titanate ceramic as active phase, and mixture of cement powder, epoxy resin, and hardener as matrix phase with a mass proportion of 4:4:1. The dielectric, piezoelectric, and electromechanical coupling properties of the composites were studied. The composites with large total volume fraction of piezoelectric phase have large piezoelectric strain constant and relative permittivity, and the piezoelectric and dielectric properties of the composites are independent of the dimensional variations of the piezoelectric ceramic layer. The composites with small total volume fraction ofmore » piezoelectric phase have large piezoelectric voltage constant, but also large dielectric loss. The composite with gradually increased dimension of piezoelectric ceramic layer has the smallest dielectric loss, and that with the gradually increased dimension of matrix layer has the largest piezoelectric voltage constant. The novel piezoelectric composites show potential applications in fabricating ultrasonic transducers with varied surface vibration amplitude of the transducer.« less

The interface in tungsten fiber reinforced niobium metal-matrix composites. Final Report Ph.D. Thesis - Case Western Reserve Univ., Cleveland, OH

NASA Technical Reports Server (NTRS)

Grobstein, Toni L.

1989-01-01

The creep resistance of tungsten fiber reinforced niobium metal-matrix composites was evaluated. The interface region between the fiber and matrix was characterized by microhardness and electron probe microanalysis measurements which indicated that its properties were between those of fiber and matrix. However, the measured properties of the composite exceeded those calculated by the rule of mixtures even when the interface zone was assumed to retain all the strength of the fiber. The composite structure appeared to enhance the strengths of both the fibers and the matrix above what they exhibited in stand-alone tests. The effect of fiber orientation and matrix alloy composition on the fiber/matrix interface were also evaluated. Small alloying additions of zirconium and tungsten to the niobium matrix affected the creep resistance of the composites only slightly. A decrease in the creep resistance of the composite with increasing zirconium content in the matrix was ascribed to an increase in the diffusion rate of the fiber/matrix interdiffusion reaction, and a slight increase in the creep resistance of the composite was observed with an addition of 9 w percent tungsten to the matrix. In addition, Kirkendall void formation was observed at the fiber/matrix interface; the void distribution differed depending on the fiber orientation relative to the stress axis.

Monitoring Fiber Stress During Curing of Single Fiber Glass- and Graphite-Epoxy Composites

NASA Technical Reports Server (NTRS)

Madhukar, Madhu S.; Kosuri, Ranga P.; Bowles, Kenneth J.

1994-01-01

The difference in thermal expansion characteristics of epoxy matrices and graphite fibers can produce significant residual stresses in the fibers during curing of composite materials. Tests on single fiber glass-epoxy and graphite-epoxy composite specimens were conducted in which the glass and graphite fibers were preloaded in tension, and the epoxy matrix was cast around the fibers. The fiber tension was monitored while the matrix was placed around the fiber and subjected to the temperature-time curing cycle. Two mechanisms responsible for producing stress in embedded fibers were identified as matrix thermal expansion and contraction and matrix cure shrinkage. A simple analysis based on the change in fiber tension during the curing cycle was conducted to estimate the produced stresses. Experimental results on single fiber glass- and graphite-epoxy composites show that the fiber was subjected to significant tensile stresses when the temperature was raised from the first to the second dwell period. When initial fiber pretension is about 60 percent of the fiber failure load, these curing-induced stresses can cause tensile fracture of the embedded fiber.

Influence of the porosity on the dispersion of the phase velocity of longitudinal acoustic waves in isotropic metal-matrix composites

NASA Astrophysics Data System (ADS)

Karabutov, A. A.; Podymova, N. B.

2017-05-01

The influence of the volumetric porosity of isotropic metal-matrix composite materials, which are reinforced with ceramic microparticles, on the dispersion of the phase velocity of longitudinal acoustic waves is investigated. For this purpose, the method of broadband acoustic spectroscopy with a laser source of ultrasound and piezoelectric detection of nanosecond ultrasonic pulses is used. Composite samples based on a silumin matrix with added silicon carbide (SiC) microparticles in different mass concentrations (3.8-15.5%) were investigated. As the concentration of SiC particles in a sample increases, its porosity that is determined using the hydrostatic-weighing method also increases. The simultaneous increase in the filler concentration and porosity leads to the appearance of a dispersion of the phase velocity of longitudinal acoustic waves in the sample within the frequency range of 3-25 MHz. The obtained empirical relationship between the relative change in the phase velocity and the sample porosity can be used to obtain a proximate quantitative estimate of the bulk porosity of the isotropic metal-matrix composite materials.

High-Temperature, Lightweight, Self-Healing Ceramic Composites for Aircraft Engine Applications

NASA Technical Reports Server (NTRS)

Raj, Sai V.; Bhatt, Ramkrishna

2013-01-01

The use of reliable, high-temperature, lightweight materials in the manufacture of aircraft engines is expected to result in lower fossil and biofuel consumption, thereby leading to cost savings and lower carbon emissions due to air travel. Although nickel-based superalloy blades and vanes have been successfully used in aircraft engines for several decades, there has been an increased effort to develop high-temperature, lightweight, creep-resistant substitute materials under various NASA programs over the last two decades. As a result, there has been a great deal of interest in developing SiC/SiC ceramic matrix composites (CMCs) due to their higher damage tolerance compared to monolithic ceramics. Current-generation SiC/SiC ceramic matrix composites rely almost entirely on the SiC fibers to carry the load, owing to the premature cracking of the matrix during loading. Thus, the high-temperature usefulness of these CMCs falls well below their theoretical capabilities. The objective of this work is to develop a new class of high-temperature, lightweight, self-healing, SiC fiber-reinforced, engineered matrix ceramic composites.

Unveiling the Semicoherent Interface with Definite Orientation Relationships between Reinforcements and Matrix in Novel Al3BC/Al Composites.

PubMed

Zhao, Yongfeng; Qian, Zhao; Ma, Xia; Chen, Houwen; Gao, Tong; Wu, Yuying; Liu, Xiangfa

2016-10-05

High-strength lightweight Al-based composites are promising materials for a wide range of applications. To provide high performance, a strong bonding interface for effective load transfer from the matrix to the reinforcement is essential. In this work, the novel Al 3 BC reinforced Al composites have been in situ fabricated through a liquid-solid reaction method and the bonding interface between Al 3 BC and Al matrix has been unveiled. The HRTEM characterizations on the Al 3 BC/Al interface verify it to be a semicoherent bonding structure with definite orientation relationships: (0001) Al 3 BC //(11̅1) Al ;[112̅0] Al 3 BC //[011] Al . Periodic arrays of geometrical misfit dislocations are also observed along the interface at each (0001) Al 3 BC plane or every five (11̅1) Al planes. This kind of interface between the reinforcement and the matrix is strong enough for effective load transfer, which would lead to the evidently improved strength and stiffness of the introduced new Al 3 BC/Al composites.

Improved Mechanical and Tribological Properties of Metal-Matrix Composites Dispersion-Strengthened by Nanoparticles 

PubMed Central

Levashov, Evgenii; Kurbatkina, Victoria; Alexandr, Zaytsev

2009-01-01

Co- and Fe-based alloys produced by powder technology are being widely used as a matrix for diamond-containing composites in cutting, drilling, grinding pplications, etc. The severe service conditions demand that the mechanical and tribological properties of these alloys be improved. Development of metal-matrix composites (MMCs) and alloys reinforced with nanoparticles is a promising way to resolve this problem. In this work, we have investigated the effect of nano-sized WC, ZrO2, Al2O3, and Si3N4 additives on the properties of sintered dispersion-strengthened Co- and Fe-based MMCs. The results show an increase in the hardness (up to 10 HRB), bending strength (up to 50%), wear resistance (by a factor of 2–10) and a decrease in the friction coefficient (up to 4-fold) of the dispersion-strengthened materials. The use of designed alloys as a binder of cutting diamond tools gave a 4-fold increment in the service life, without reduction in their cutting speed.

Matrix cracking in laminated composites under monotonic and cyclic loadings

NASA Technical Reports Server (NTRS)

Allen, David H.; Lee, Jong-Won

1991-01-01

An analytical model based on the internal state variable (ISV) concept and the strain energy method is proposed for characterizing the monotonic and cyclic response of laminated composites containing matrix cracks. A modified constitution is formulated for angle-ply laminates under general in-plane mechanical loading and constant temperature change. A monotonic matrix cracking criterion is developed for predicting the crack density in cross-ply laminates as a function of the applied laminate axial stress. An initial formulation for a cyclic matrix cracking criterion for cross-ply laminates is also discussed. For the monotonic loading case, a number of experimental data and well-known models are compared with the present study for validating the practical applicability of the ISV approach.

Effect of Cutting Parameters on Thrust Force and Surface Roughness in Drilling of Al-2219/B4C/Gr Metal Matrix Composites

NASA Astrophysics Data System (ADS)

Ravindranath, V. M.; Basavarajappa, G. S. Shiva Shankar S.; Suresh, R.

2016-09-01

In aluminium matrix composites, reinforcement of hard ceramic particle present inside the matrix which causes tool wear, high cutting forces and poor surface finish during machining. This paper focuses on effect of cutting parameters on thrust force, surface roughness and burr height during drilling of MMCs. In the present work, discuss the influence of spindle speed and feed rate on drilling the pure base alloy (Al-2219), mono composite (Al- 2219+8% B4C) and hybrid composite (Al-2219+8%B4C+3%Gr). The composites were fabricated using liquid metallurgy route. The drilling experiments were conducted by CNC machine with TiN coated HSS tool, M42 (Cobalt grade) and carbide tools at various spindle speeds and feed rates. The thrust force, surface roughness and burr height of the drilled hole were investigated in mono composite and hybrid composite containing graphite particles, the experimental results show that the feed rate has more influence on thrust force and surface roughness. Lesser thrust force and discontinuous chips were produced during machining of hybrid composites when compared with mono and base alloy during drilling process. It is due to solid lubricant property of graphite which reduces the lesser thrust force, burr height and lower surface roughness. When machining with Carbide tool at low feed and high speeds good surface finish was obtained compared to other two types of cutting tool materials.

Advanced ceramic matrix composites for TPS

NASA Technical Reports Server (NTRS)

Rasky, Daniel J.

1992-01-01

Recent advances in ceramic matrix composite (CMC) technology provide considerable opportunity for application to future aircraft thermal protection system (TPS), providing materials with higher temperature capability, lower weight, and higher strength and stiffness than traditional materials. The Thermal Protection Material Branch at NASA Ames Research Center has been making significant progress in the development, characterization, and entry simulation (arc-jet) testing of new CMC's. This protection gives a general overview of the Ames Thermal Protection Materials Branch research activities, followed by more detailed descriptions of recent advances in very-high temperature Zr and Hf based ceramics, high temperature, high strength SiC matrix composites, and some activities in polymer precursors and ceramic coating processing. The presentation closes with a brief comparison of maximum heat flux capabilities of advanced TPS materials.

Experimental study of the fracture toughness of a ceramic/ceramic-matrix composite sandwich structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Z.; Taya, M.; Dunn, M.L.

A hybrid experimental-numerical approach has been used to measure the fracture resistance of a sandwich structure consisting of a 304 stainless steel/partially stabilized zirconia ceramic-matrix composite crack-arresting layer embedded in a partially stabilized zirconia ceramic specimen. The mode 1 fracture toughness increases significantly when the crack propagates from the ceramic into the ceramic-matrix composite region. The increased toughening due to the stainless steel particles is explained reasonably well by a toughening model based on processing-induced thermal residual stresses. In addition, several experimental modifications were made to the chevron-notch wedge-loaded double cantilever beam specimen to overcome numerous problems encountered in generatingmore » a precrack in the small, brittle specimens used in this study.« less

Characterization of Carbon Nanotube Reinforced Nickel

NASA Technical Reports Server (NTRS)

Gill, Hansel; Hudson, Steve; Bhat, Biliyar; Munafo, Paul M. (Technical Monitor)

2002-01-01

Carbon nanotubes are cylindrical molecules composed of carbon atoms in a regular hexagonal arrangement. If nanotubes can be uniformly dispersed in a supporting matrix to form structural materials, the resulting structures could be significantly lighter and stronger than current aerospace materials. Work is currently being done to develop an electrolyte-based self-assembly process that produces a Carbon Nanotube/Nickel composite material with high specific strength. This process is expected to produce a lightweight metal matrix composite material, which maintains it's thermal and electrical conductivities, and is potentially suitable for applications such as advanced structures, space based optics, and cryogenic tanks.

Associative Flow Rule Used to Include Hydrostatic Stress Effects in Analysis of Strain-Rate-Dependent Deformation of Polymer Matrix Composites

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.; Roberts, Gary D.

2004-01-01

designing reliable composite engine cases that are lighter than the metal cases in current use. The types of polymer matrix composites that are likely to be used in such an application have a deformation response that is nonlinear and that varies with strain rate. The nonlinearity and the strain-rate dependence of the composite response are due primarily to the matrix constituent. Therefore, in developing material models to be used in the design of impact-resistant composite engine cases, the deformation of the polymer matrix must be correctly analyzed. However, unlike in metals, the nonlinear response of polymers depends on the hydrostatic stresses, which must be accounted for within an analytical model. By applying micromechanics techniques along with given fiber properties, one can also determine the effects of the hydrostatic stresses in the polymer on the overall composite deformation response. First efforts to account for the hydrostatic stress effects in the composite deformation applied purely empirical methods that relied on composite-level data. In later efforts, to allow polymer properties to be characterized solely on the basis of polymer data, researchers at the NASA Glenn Research Center developed equations to model the polymers that were based on a non-associative flow rule, and efforts to use these equations to simulate the deformation of representative polymer materials were reasonably successful. However, these equations were found to have difficulty in correctly analyzing the multiaxial stress states found in the polymer matrix constituent of a composite material. To correct these difficulties, and to allow for the accurate simulation of the nonlinear strain-rate-dependent deformation analysis of polymer matrix composites, in the efforts reported here Glenn researchers reformulated the polymer constitutive equations from basic principles using the concept of an associative flow rule. These revised equations were characterized and validated in an experimental program carried out through a university grant with the Ohio State University, wherein tensile and shear deformation data were obtained for a representative polymer for strain rates ranging from quasi-static to high rates of several hundred per second. Tensile deformation data also were obtained over a variety of strain rates and fiber orientation angles for a representative polymer matrix composite composed using the polymer.

Interfacial Effects on the Thermal and Mechanical Properties of Graphite/Copper Composites. Final Contractor Report Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Devincent, Sandra Marie

1995-01-01

Graphite surfaces are not wet by pure copper. This lack of wetting has been responsible for a debonding phenomenon that has been found in continuous graphite fiber reinforced copper matrix composites subjected to elevated temperatures. By suitably alloying copper, its ability to wet graphite surfaces can be enhanced. Information obtained during sessile drop testing has led to the development of a copper-chromium alloy that suitably wets graphite. Unidirectionally reinforced graphite/copper composites have been fabricated using a pressure infiltration casting procedure. P100 pitch-based fibers have been used to reinforce copper and copper-chromium alloys. X-ray radiography and optical microscopy have been used to assess the fiber distribution in the cast composites. Scanning electron microscopy and Auger electron spectroscopy analyses were conducted to study the distribution and continuity of the chromium carbide reaction phase that forms at the fiber/matrix interface in the alloyed matrix composites. The effects of the chromium in the copper matrix on the mechanical and thermal properties of P100Gr/Cu composites have been evaluated through tensile testing, three-point bend testing, thermal cycling and thermal conductivity calculations. The addition of chromium has resulted in an increased shear modulus and essentially zero thermal expansion in the P100Gr/Cu-xCr composites through enhanced fiber/matrix bonding. The composites have longitudinal tensile strengths in excess of 700 MPa with elastic moduli of 393 GPa. After 100 hr at 760 deg C 84 percent of the as-cast strength is retained in the alloyed matrix composites. The elastic moduli are unchanged by the thermal exposure. It has been found that problems with spreading of the fiber tows strongly affect the long transverse tensile properties and the short transverse thermal conductivity of the P100Gr/Cu-xCr composites. The long transverse tensile strength is limited by rows of touching fibers which are paths of easy crack propagation under low tensile loads. The short transverse thermal conductivity is dictated by the fiber/matrix interface. Conduction across this interface has been estimated to be two orders of magnitude lower than that across the composite. This is due to the mechanical, and not chemical, nature of Gr/Cu bond.

Graphene-Reinforced Metal and Polymer Matrix Composites

NASA Astrophysics Data System (ADS)

Kasar, Ashish K.; Xiong, Guoping; Menezes, Pradeep L.

2018-03-01

Composites have tremendous applicability due to their excellent capabilities. The performance of composites mainly depends on the reinforcing material applied. Graphene is successful as an efficient reinforcing material due to its versatile as well as superior properties. Even at very low content, graphene can dramatically improve the properties of polymer and metal matrix composites. This article reviews the fabrication followed by mechanical and tribological properties of metal and polymer matrix composites filled with different kinds of graphene, including single-layer, multilayer, and functionalized graphene. Results reported to date in literature indicate that functionalized graphene or graphene oxide-polymer composites are promising materials offering significantly improved strength and frictional properties. A similar trend of improved properties has been observed in case of graphene-metal matrix composites. However, achieving higher graphene loading with uniform dispersion in metal matrix composites remains a challenge. Although graphene-reinforced composites face some challenges, such as understanding the graphene-matrix interaction or fabrication techniques, graphene-reinforced polymer and metal matrix composites have great potential for application in various fields due to their outstanding properties.

Graphene-Reinforced Metal and Polymer Matrix Composites

NASA Astrophysics Data System (ADS)

Kasar, Ashish K.; Xiong, Guoping; Menezes, Pradeep L.

2018-06-01

Composites have tremendous applicability due to their excellent capabilities. The performance of composites mainly depends on the reinforcing material applied. Graphene is successful as an efficient reinforcing material due to its versatile as well as superior properties. Even at very low content, graphene can dramatically improve the properties of polymer and metal matrix composites. This article reviews the fabrication followed by mechanical and tribological properties of metal and polymer matrix composites filled with different kinds of graphene, including single-layer, multilayer, and functionalized graphene. Results reported to date in literature indicate that functionalized graphene or graphene oxide-polymer composites are promising materials offering significantly improved strength and frictional properties. A similar trend of improved properties has been observed in case of graphene-metal matrix composites. However, achieving higher graphene loading with uniform dispersion in metal matrix composites remains a challenge. Although graphene-reinforced composites face some challenges, such as understanding the graphene-matrix interaction or fabrication techniques, graphene-reinforced polymer and metal matrix composites have great potential for application in various fields due to their outstanding properties.

Modeling and life prediction methodology for Titanium Matrix Composites subjected to mission profiles

NASA Technical Reports Server (NTRS)

Mirdamadi, M.; Johnson, W. S.

1994-01-01

Titanium matrix composites (TMC) are being evaluated as structural materials for elevated temperature applications in future generation hypersonic vehicles. In such applications, TMC components are subjected to complex thermomechanical loading profiles at various elevated temperatures. Therefore, thermomechanical fatigue (TMF) testing, using a simulated mission profile, is essential for evaluation and development of life prediction methodologies. The objective of the research presented in this paper was to evaluate the TMF response of the (0/90)2s SCS-6/Timetal-21S subjected to a generic hypersonic flight profile and its portions with a temperature ranging from -130 C to 816 C. It was found that the composite modulus, prior to rapid degradation, had consistent values for all the profiles tested. A micromechanics based analysis was used to predict the stress-strain response of the laminate and of the constituents in each ply during thermomechanical loading conditions by using only constituent properties as input. The fiber was modeled as elastic with transverse orthotropic and temperature dependent properties. The matrix was modeled using a thermoviscoplastic constitutive relation. In the analysis, the composite modulus degradation was assumed to result from matrix cracking and was modeled by reducing the matrix modulus. Fatigue lives of the composite subjected to the complex generic hypersonic flight profile were well correlated using the predicted stress in 0 degree fibers.

Spark plasma sintering of ceramic matrix composite based on alumina, reinforced by carbon nanotubes

NASA Astrophysics Data System (ADS)

Leonov, A. A.; Khasanov, A. O.; Danchenko, V. A.; Khasanov, O. L.

2017-12-01

Alumina composites reinforced with 3 vol.% multi-walled carbon nanotubes (MWCNTs) were prepared by spark plasma sintering (SPS). The influence of sintering temperature (1400-1600 °C) on the composites microstructure and mechanical properties was investigated. Microstructure observations of the composite shows that some CNTs site along alumina grains boundary, while others embed into the alumina grains and shows that CNTs bonded strongly with the alumina matrix contributing to fracture toughness and microhardness increase. MWCNTs reinforcing mechanisms including CNT pull-out and crack deflection were directly observed by scanning electron microscope (SEM). For Al2O3/CNT composite sintered at 1600 °C, fracture toughness and microhardness are 4.93 MPa·m1/2 and 23.26 GPa respectively.

Electron microscopy and microanalysis of the fiber-matrix interface in monolithic silicone carbide-based ceramic composite material for use in a fusion reactor application.

PubMed

Toplisek, Tea; Drazic, Goran; Novak, Sasa; Kobe, Spomenka

2008-01-01

A composite material made from continuous monolithic silicone carbide (SiC) fibers and a SiC-based matrix (SiC(f)/SiC), was prepared using a novel technique, i.e. adapted dip coating and infiltration of SiC fibers with a water suspension containing SiC particles and a sintering additive. This kind of material could be used in the first-wall blanket of a future fusion reactor. Using magnetron sputtering, the SiC fibers were coated with various thin layers (TiC, CrN, CrC, WC, DLC-diamond-like carbon) of the interface material by physical vapor deposition (PVD). Using scanning and transmission electron microscopy and microanalysis, detailed microstructural studies of the fiber-matrix interface were performed. Both samples, with coated and uncoated fibers, were examined under a load. The microcracks introduced by the Vickers indenter continued their path through the fibers, and thus caused the failure of the composite material, in the case of the uncoated fibers or deviated from their primary direction at the fiber-matrix interface in the case of the coated fibers.

Method of joining metallic and composite components

NASA Technical Reports Server (NTRS)

Semmes, Edmund B. (Inventor)

2010-01-01

A method is provided for joining a metallic member to a structure made of a composite matrix material. One or more surfaces of a portion of the metallic member that is to be joined to the composite matrix structure is provided with a plurality of outwardly projecting studs. The surface including the studs is brought into engagement with a portion of an uncured composite matrix material so that fibers of the composite matrix material intertwine with the studs, and the metallic member and composite structure form an assembly. The assembly is then companion cured so as to join the metallic member to the composite matrix material structure.

Influence of matrix and filler fraction on biofilm formation on the surface of experimental resin-based composites.

PubMed

Ionescu, Andrei; Brambilla, Eugenio; Wastl, Daniel S; Giessibl, Franz J; Cazzaniga, Gloria; Schneider-Feyrer, Sibylle; Hahnel, Sebastian

2015-01-01

The aim of this study was to investigate the impact of resin matrix chemistry and filler fraction on biofilm formation on the surface of experimental resin-based composites (RBCs). Specimens were prepared from eight experimental RBC formulations differing in resin matrix blend (BisGMA/TEGDMA in a 7:3 wt% ratio or UDMA/aliphatic dimethacrylate in a 1:1 wt% ratio) and filler fraction (no fillers; 65 wt% dental glass with an average diameter of 7 or 0.7 µm or 65 wt% SiO2 with an average diameter of 20 nm). Surface roughness, surface free energy, and chemical surface composition were determined; surface topography was visualized using atomic force microscopy. Biofilm formation was simulated under continuous flow conditions for a 48 h period using a monospecies Streptococcus mutans and a multispecies biofilm model. In the monospecies biofilm model, the impact of the filler fraction overruled the influence of the resin matrix, indicating lowest biofilm formation on RBCs with nano-scaled filler particles and those manufactured from the neat resin blends. The multispecies model suggested a more pronounced effect of the resin matrix blend, as significantly higher biofilm formation was identified on RBCs with a UDMA/dimethacrylate matrix blend than on those including a BisGMA/TEGDMA matrix blend but analogous filler fractions. Although significant differences in surface properties between the various materials were identified, correlations between the surface properties and biofilm formation were poor, which highlights the relevance of surface topography and chemistry. These results may help to tailor novel RBC formulations which feature reduced biofilm formation on their surface.

Composite blade structural analyzer (COBSTRAN) user's manual

NASA Technical Reports Server (NTRS)

Aiello, Robert A.

1989-01-01

The installation and use of a computer code, COBSTRAN (COmposite Blade STRuctrual ANalyzer), developed for the design and analysis of composite turbofan and turboprop blades and also for composite wind turbine blades was described. This code combines composite mechanics and laminate theory with an internal data base of fiber and matrix properties. Inputs to the code are constituent fiber and matrix material properties, factors reflecting the fabrication process, composite geometry and blade geometry. COBSTRAN performs the micromechanics, macromechanics and laminate analyses of these fiber composites. COBSTRAN generates a NASTRAN model with equivalent anisotropic homogeneous material properties. Stress output from NASTRAN is used to calculate individual ply stresses, strains, interply stresses, thru-the-thickness stresses and failure margins. Curved panel structures may be modeled providing the curvature of a cross-section is defined by a single value function. COBSTRAN is written in FORTRAN 77.

Effect of rolling on the high temperature tensile and stress-rupture properties of tungsten fiber-superalloy composites

NASA Technical Reports Server (NTRS)

Petrasek, D. W.

1974-01-01

An investigation was conducted to determine the effects of mechanical working on the 1093 C (2000 F) tensile and stress-rupture strength of tungsten alloy/superalloy composites. Hot pressed composites containing either conventional tungsten lamp filament wire or tungsten-1% ThO2 wire and a nickel base alloy matrix were hot rolled at 1093 C (2000 F). The hot pressed and rolled composite specimens were then tested in tension and stress-rupture at 1093 C (2000 F). Rolling decreased the degree of fiber-matrix reaction as a function of time of exposure at 1093 C (2000 F). The stress-rupture properties of the rolled composites were superior to hot pressed composites containing equivalent diameter fibers. Rolling did not appreciably affect the 1093 C (2000 F) ultimate tensile strength of the composites.

Design of starch functionalized biodegradable P(MAA-co-MMA) as carrier matrix for l-asparaginase immobilization.

PubMed

Ulu, Ahmet; Koytepe, Suleyman; Ates, Burhan

2016-11-20

We prepared biodegradable P(MAA-co-MMA)-starch composite as carrier matrix for the immobilization of l-asparaginase (l-ASNase), an important chemotherapeutic agent in acute lymphoblastic leukemia. Chemical characteristics and thermal stability of the prepared composites were determined by FT-IR, TGA, DTA and, DSC, respectively. Also, biodegradability measurements of P(MAA-co-MMA)-starch composites were carried out to examine the effects of degradation of the starch. Then, l-ASNase was immobilized on the P(MAA-co-MMA)-starch composites. The surface morphology of the composite before and after immobilization was characterized by SEM, EDX, and AFM. The properties of the immobilized l-ASNase were investigated and compared with the free enzyme. The immobilized l-ASNase had better showed thermal and pH stability, and remained stable after 30days of storage at 25°C. Thus, based on the findings of the present work, the P(MAA-co-MMA)-starch composite can be exploited as the biocompatible matrix used for l-ASNase immobilization for medical applications due to biocompatibility and biodegradability. Copyright © 2016 Elsevier Ltd. All rights reserved.

Factors Controlling Elevated Temperature Strength Degradation of Silicon Carbide Composites

NASA Technical Reports Server (NTRS)

2005-01-01

For 5 years, the cooperative agreement NCC3-763 has focused on the development and understanding of Sic-based composites. Most of the work was performed in the area of SiC fiber-reinforced composites for UEET and NGLT and in collaboration with Goodrich Corporation under a partially reimbursable Space Act Agreement. A smaller amount of work was performed on C fiber-reinforced SiC matrix composites for NGLT. Major accomplishments during this agreement included: Improvements to the interphase used in melt-infiltrated (MI) SiC/SiC composites which increases the life under stressed-oxidation at intermediate temperatures referred to as "outside-debonding". This concept is currently in the patent process and received a Space Act Award. Mechanistic-based models of intermediate temperature degradation for MI SiC/SiC Quantification and relatively robust relationships for matrix crack evolution under stress in SiC/SiC composites which serve as the basis for stress-strain and elevated temperature life models The furthering of acoustic emission as a useful tool in composite damage evolution and the extension of the technique to other composite systems Development of hybrid C-SiC fiber-reinforced SiC matrix composites Numerous presentations at conferences, industry partners, and government centers and publications in recognized proceedings and journals. Other recognition of the author's accomplishments by NASA with a TGIR award (2004), NASA's Medal for Public Service (2004), and The American Ceramic Society s Richard M. Fulrath Award (2005). The following will briefly describe the work of the past five years in the three areas of interest: SiC/SiC composite development, mechanistic understanding and modeling of SiC/SiC composites, and environmental durability of C/SiC composites. More detail can be found in the publications cited at the end of this report.

Multi-Length Scale-Enriched Continuum-Level Material Model for Kevlar-Fiber-Reinforced Polymer-Matrix Composites

DTIC Science & Technology

2012-08-03

is unlimited. Multi-Length Scale-Enriched Continuum-Level Material Model for Kevlar ®-Fiber-Reinforced Polymer-Matrix Composites The views, opinions...12211 Research Triangle Park, NC 27709-2211 ballistics, composites, Kevlar , material models, microstructural defects REPORT DOCUMENTATION PAGE 11... Kevlar ®-Fiber-Reinforced Polymer-Matrix Composites Report Title Fiber-reinforced polymer matrix composite materials display quite complex deformation

Impact Strength and Flexural Properties Enhancement of Methacrylate Silane Treated Oil Palm Mesocarp Fiber Reinforced Biodegradable Hybrid Composites

PubMed Central

Ibrahim, Nor Azowa; Ariffin, Hidayah; Yunus, Wan Md. Zin Wan

2014-01-01

Natural fiber as reinforcement filler in polymer composites is an attractive approach due to being fully biodegradable and cheap. However, incompatibility between hydrophilic natural fiber and hydrophobic polymer matrix restricts the application. The current studies focus on the effects of incorporation of silane treated OPMF into polylactic acid (PLA)/polycaprolactone (PCL)/nanoclay/OPMF hybrid composites. The composites were prepared by melt blending technique and characterize the composites with Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). FTIR spectra indicated that peak shifting occurs when silane treated OPMF was incorporated into hybrid composites. Based on mechanical properties results, incorporation of silane treated OPMF enhances the mechanical properties of unmodified OPMF hybrid composites with the enhancement of flexural and impact strength being 17.60% and 48.43%, respectively, at 10% fiber loading. TGA thermogram shows that incorporation of silane treated OPMF did not show increment in thermal properties of hybrid composites. SEM micrographs revealed that silane treated OPMF hybrid composites show good fiber/matrix adhesion as fiber is still embedded in the matrix and no cavity is present on the surface. Water absorption test shows that addition of less hydrophilic silane treated OPMF successfully reduces the water uptake of hybrid composites. PMID:25254230

Impact strength and flexural properties enhancement of methacrylate silane treated oil palm mesocarp fiber reinforced biodegradable hybrid composites.

PubMed

Eng, Chern Chiet; Ibrahim, Nor Azowa; Zainuddin, Norhazlin; Ariffin, Hidayah; Yunus, Wan Md Zin Wan

2014-01-01

Natural fiber as reinforcement filler in polymer composites is an attractive approach due to being fully biodegradable and cheap. However, incompatibility between hydrophilic natural fiber and hydrophobic polymer matrix restricts the application. The current studies focus on the effects of incorporation of silane treated OPMF into polylactic acid (PLA)/polycaprolactone (PCL)/nanoclay/OPMF hybrid composites. The composites were prepared by melt blending technique and characterize the composites with Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). FTIR spectra indicated that peak shifting occurs when silane treated OPMF was incorporated into hybrid composites. Based on mechanical properties results, incorporation of silane treated OPMF enhances the mechanical properties of unmodified OPMF hybrid composites with the enhancement of flexural and impact strength being 17.60% and 48.43%, respectively, at 10% fiber loading. TGA thermogram shows that incorporation of silane treated OPMF did not show increment in thermal properties of hybrid composites. SEM micrographs revealed that silane treated OPMF hybrid composites show good fiber/matrix adhesion as fiber is still embedded in the matrix and no cavity is present on the surface. Water absorption test shows that addition of less hydrophilic silane treated OPMF successfully reduces the water uptake of hybrid composites.

Graphene-copper composite with micro-layered grains and ultrahigh strength

PubMed Central

Wang, Lidong; Yang, Ziyue; Cui, Ye; Wei, Bing; Xu, Shichong; Sheng, Jie; Wang, Miao; Zhu, Yunpeng; Fei, Weidong

2017-01-01

Graphene with ultrahigh intrinsic strength and excellent thermal physical properties has the potential to be used as the reinforcement of many kinds of composites. Here, we show that very high tensile strength can be obtained in the copper matrix composite reinforced by reduced graphene oxide (RGO) when micro-layered structure is achieved. RGO-Cu powder with micro-layered structure is fabricated from the reduction of the micro-layered graphene oxide (GO) and Cu(OH)2 composite sheets, and RGO-Cu composites are sintered by spark plasma sintering process. The tensile strength of the 5 vol.% RGO-Cu composite is as high as 608 MPa, which is more than three times higher than that of the Cu matrix. The apparent strengthening efficiency of RGO in the 2.5 vol.% RGO-Cu composite is as high as 110, even higher than that of carbon nanotube, multilayer graphene, carbon nano fiber and RGO in the copper matrix composites produced by conventional MLM method. The excellent tensile and compressive strengths, high hardness and good electrical conductivity are obtained simultaneously in the RGO-Cu composites. The results shown in the present study provide an effective method to design graphene based composites with layered structure and high performance. PMID:28169306

A composites-based hyperelastic constitutive model for soft tissue with application to the human annulus fibrosus

NASA Astrophysics Data System (ADS)

Guo, Z. Y.; Peng, X. Q.; Moran, B.

2006-09-01

This paper presents a composites-based hyperelastic constitutive model for soft tissue. Well organized soft tissue is treated as a composite in which the matrix material is embedded with a single family of aligned fibers. The fiber is modeled as a generalized neo-Hookean material in which the stiffness depends on fiber stretch. The deformation gradient is decomposed multiplicatively into two parts: a uniaxial deformation along the fiber direction and a subsequent shear deformation. This permits the fiber-matrix interaction caused by inhomogeneous deformation to be estimated by using effective properties from conventional composites theory based on small strain linear elasticity and suitably generalized to the present large deformation case. A transversely isotropic hyperelastic model is proposed to describe the mechanical behavior of fiber-reinforced soft tissue. This model is then applied to the human annulus fibrosus. Because of the layered anatomical structure of the annulus fibrosus, an orthotropic hyperelastic model of the annulus fibrosus is developed. Simulations show that the model reproduces the stress-strain response of the human annulus fibrosus accurately. We also show that the expression for the fiber-matrix shear interaction energy used in a previous phenomenological model is compatible with that derived in the present paper.

Synthesis and Examination of Nanocomposites Based on Poly(2-hydroxyethyl methacrylate) for Medicinal Use

NASA Astrophysics Data System (ADS)

Kukolevska, Olena S.; Gerashchenko, Igor I.; Borysenko, Mykola V.; Pakhlov, Evgenii M.; Machovsky, Michal; Yushchenko, Tetyana I.

2017-02-01

Preparation of poly(2-hydroxyethyl methacrylate) (PHEMA) based nanocomposites using different approaches such as synthesis with water as the porogen, filling of polymer matrix by silica and formation of interpenetrating polymer networks with polyurethane was demonstrated. Incorporation of various biologically active compounds (BAC) such as metronidazole, decamethoxin, zinc sulphate, silver nitrate or amino acids glycine and tryptophan into nanocomposites was achieved. BAC were introduced into the polymer matrix either (1) directly, or (2) with a solution of colloidal silica, or (3) through immobilization on silica (sol-densil). Morphology of prepared materials was investigated by laser scanning microscopy and low-vacuum scanning electron microscopy. In vacuum freeze-drying, prior imaging was proposed for improving visualization of the porous structure of composites. The interaction between PHEMA matrix and silica filler was investigated by IR spectroscopy. Adsorption of 2-hydroxyethyl methacrylate and BAC from aqueous solution on the silica surface was also examined. Phase composition and thermal stability of composites were studied by the differential thermogravimetry/differential thermal analysis. Release of BAC into water medium from prepared composites were shown to depend on the synthetic method and differed significantly. Obtained PHEMA-base materials which are characterized by controlled release of BAC have a strong potential for application in manufacturing of different surgical devices like implants, catheters and drainages.

Metal-matrix composites: Status and prospects

NASA Technical Reports Server (NTRS)

1974-01-01

Applications of metal matrix composites for air frames and jet engine components are discussed. The current state of the art in primary and secondary fabrication is presented. The present and projected costs were analyzed to determine the cost effectiveness of metal matrix composites. The various types of metal matrix composites and their characteristics are described.

Analysis of Mechanical and Thermogravimetric Properties of Composite Materials Based on PVA/MWCNT and Styrene-Acrylic Copolymer/MWCNT

NASA Astrophysics Data System (ADS)

Volynets, N. I.; Poddubskaya, O. G.; Demidenko, M. I.; Lyubimov, A. G.; Kuzhir, P. P.; Suslyaev, V. I.; Pletnev, M. A.; Zicans, Janis

2017-08-01

Mechanical and thermogravimetric properties of polymer composite materials with various concentrations of multiwalled carbon nanotubes effectively shielding radiation in the radio frequency (20 Hz - 1 MHz) and microwave (26-36 GHz) frequency ranges are studied. As a matrix, widely available polymeric materials, such as polyvinyl acetate and styrene-acrylate, were used in the form of dispersions. From the analysis of the obtained experimental data, it was shown that the introduction of carbon nanotubes into the polymer matrix makes it possible to increase mechanical properties and thermal stability of composite materials.

Advanced composite materials for optomechanical systems

NASA Astrophysics Data System (ADS)

Zweben, Carl

2013-09-01

Polymer matrix composites (PMCs) have been well established in optomechanical systems for several decades. The other three classes of composites; metal matrix composites (MMCs), ceramic matrix composites (CMCs), and carbon matrix composites (CAMCs) are making significant inroads. The latter include carbon/carbon (C/C) composites (CCCs). The success of composites has resulted in increasing use in consumer, industrial, scientific, and aerospace/defense optomechanical applications. Composites offer significant advantages over traditional materials, including high stiffnesses and strengths, near-zero and tailorable coefficients of thermal expansion (CTEs), tailorable thermal conductivities (from very low to over twice that of copper), and low densities. In addition, they lack beryllium's toxicity problems. Some manufacturing processes allow parts consolidation, reducing machining and joining operations. At present, PMCs are the most widely used composites. Optomechanical applications date from the 1970s. The second High Energy Astrophysical Observatory spacecraft, placed in orbit in 1978, had an ultrahigh-modulus carbon fiber-reinforced epoxy (carbon/epoxy) optical bench metering structure. Since then, fibers and matrix materials have advanced significantly, and use of carbon fiber-reinforced polymers (CFRPs) has increased steadily. Space system examples include the Hubble Space Telescope metering truss and instrument benches, Upper Atmosphere Research Satellite (UARS), James Webb Space Telescope and many others. Use has spread to airborne applications, such as SOFIA. Perhaps the most impressive CFRP applications are the fifty-four 12m and twelve 7m moveable ground-based ALMA antennas. The other three classes of composites have a number of significant advantages over PMCs, including no moisture absorption or outgassing of organic compounds. CCC and CMC components have flown on a variety of spacecraft. MMCs have been used in space, aircraft, military and industrial applications. In this paper, we review key PMC, MMC, CCC, and CMC optomechanical system materials, including properties, advantages, disadvantages, applications and future developments. These topics are covered in more detail in SPIE short courses SC218 and SC1078.

Strain Rate Dependent Deformation and Strength Modeling of a Polymer Matrix Composite Utilizing a Micromechanics Approach. Degree awarded by Cincinnati Univ.

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.

1999-01-01

Potential gas turbine applications will expose polymer matrix composites to very high strain rate loading conditions, requiring an ability to understand and predict the material behavior under extreme conditions. Specifically, analytical methods designed for these applications must have the capability of properly capturing the strain rate sensitivities and nonlinearities that are present in the material response. The Ramaswamy-Stouffer constitutive equations, originally developed to analyze the viscoplastic deformation of metals, have been modified to simulate the nonlinear deformation response of ductile, crystalline polymers. The constitutive model is characterized and correlated for two representative ductile polymers. Fiberite 977-2 and PEEK, and the computed results correlate well with experimental values. The polymer constitutive equations are implemented in a mechanics of materials based composite micromechanics model to predict the nonlinear, rate dependent deformation response of a composite ply. Uniform stress and uniform strain assumptions are applied to compute the effective stresses of a composite unit cell from the applied strains. The micromechanics equations are successfully verified for two polymer matrix composites. IM7/977-2 and AS4/PEEK. The ultimate strength of a composite ply is predicted with the Hashin failure criteria that were implemented in the composite micromechanics model. The failure stresses of the two composite material systems are accurately predicted for a variety of fiber orientations and strain rates. The composite deformation model is implemented in LS-DYNA, a commercially available transient dynamic explicit finite element code. The matrix constitutive equations are converted into an incremental form, and the model is implemented into LS-DYNA through the use of a user defined material subroutine. The deformation response of a bulk polymer and a polymer matrix composite are predicted by finite element analyses. The results compare reasonably well to experimental values, with some discrepancies. The discrepancies are at least partially caused by the method used to integrate the rate equations in the polymer constitutive model.

Innovative Structural Materials and Sections with Strain Hardening Cementitious Composites

NASA Astrophysics Data System (ADS)

Dey, Vikram

The motivation of this work is based on development of new construction products with strain hardening cementitious composites (SHCC) geared towards sustainable residential applications. The proposed research has three main objectives: automation of existing manufacturing systems for SHCC laminates; multi-level characterization of mechanical properties of fiber, matrix, interface and composites phases using servo-hydraulic and digital image correlation techniques. Structural behavior of these systems were predicted using ductility based design procedures using classical laminate theory and structural mechanics. SHCC sections are made up of thin sections of matrix with Portland cement based binder and fine aggregates impregnating continuous one-dimensional fibers in individual or bundle form or two/three dimensional woven, bonded or knitted textiles. Traditional fiber reinforced concrete (FRC) use random dispersed chopped fibers in the matrix at a low volume fractions, typically 1-2% to avoid to avoid fiber agglomeration and balling. In conventional FRC, fracture localization occurs immediately after the first crack, resulting in only minor improvement in toughness and tensile strength. However in SHCC systems, distribution of cracking throughout the specimen is facilitated by the fiber bridging mechanism. Influence of material properties of yarn, composition, geometry and weave patterns of textile in the behavior of laminated SHCC skin composites were investigated. Contribution of the cementitious matrix in the early age and long-term performance of laminated composites was studied with supplementary cementitious materials such as fly ash, silica fume, and wollastonite. A closed form model with classical laminate theory and ply discount method, coupled with a damage evolution model was utilized to simulate the non-linear tensile response of these composite materials. A constitutive material model developed earlier in the group was utilized to characterize and correlate the behavior of these structural composites under uniaxial tension and flexural loading responses. Development and use of analytical models enables optimal design for application of these materials in structural applications. Another area of immediate focus is the development of new construction products from SHCC laminates such as angles, channels, hat sections, closed sections with optimized cross sections. Sandwich composites with stress skin-cellular core concept were also developed to utilize strength and ductility of fabric reinforced skin in addition to thickness, ductility, and thermal benefits of cellular core materials. The proposed structurally efficient and durable sections promise to compete with wood and light gage steel based sections for lightweight construction and panel application.

Understanding the interdiffusion behavior and determining the long term stability of tungsten fiber reinforced niobium-base matrix composite systems

NASA Technical Reports Server (NTRS)

Tien, John K.

1990-01-01

The long term interdiffusional stability of tungsten fiber reinforced niobium alloy composites is addressed. The matrix alloy that is most promising for use as a high temperature structural material for reliable long-term space power generation is Nb1Zr. As an ancillary project to this program, efforts were made to assess the nature and kinetics of interphase reaction between selected beryllide intermetallics and nickel and iron aluminides.

Effect of flaw size and temperature on the matrix cracking behavior of a brittle ceramic matrix composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anandakumar, U.; Webb, J.E.; Singh, R.N.

The matrix cracking behavior of a zircon matrix - uniaxial SCS 6 fiber composite was studied as a function of initial flaw size and temperature. The composites were fabricated by a tape casting and hot pressing technique. Surface flaws of controlled size were introduced using a vicker`s indenter. The composite samples were tested in three point flexure at three different temperatures to study the non steady state and steady state matrix cracking behavior. The composite samples exhibited steady state and non steady matrix cracking behavior at all temperatures. The steady state matrix cracking stress and steady state crack size increasedmore » with increasing temperature. The results of the study correlated well with the results predicted by the matrix cracking models.« less

Creep of Heat-Resistant Composites of an Oxide-Fiber/Ni-Matrix Family

NASA Astrophysics Data System (ADS)

Mileiko, S. T.

2001-09-01

A creep model of a composite with a creeping matrix and initially continuous elastic brittle fibers is developed. The model accounts for the fiber fragmentation in the stage of unsteady creep of the composite, which ends with a steady-state creep, where a minimum possible average length of the fiber is achieved. The model makes it possible to analyze the creep rate of the composite in relation to such parameters of its structure as the statistic characteristics of the fiber strength, the creep characteristics of the matrix, and the strength of the fiber-matrix interface, the latter being of fundamental importance. A comparison between the calculation results and the experimental ones obtained on composites with a Ni-matrix and monocrystalline and eutectic oxide fibers as well as on sapphire fiber/TiAl-matrix composites shows that the model is applicable to the computer simulation of the creep behavior of heat-resistant composites and to the optimization of the structure of such composites. By combining the experimental data with calculation results, it is possible to evaluate the heat resistance of composites and the potential of oxide-fiber/Ni-matrix composites. The composite specimens obtained and tested to date reveal their high creep resistance up to a temperature of 1150°C. The maximum operating temperature of the composites can be considerably raised by strengthening the fiber-matrix interface.

Elastic-plastic finite element analyses of an unidirectional, 9 vol percent tungsten fiber reinforced copper matrix composite

NASA Technical Reports Server (NTRS)

Sanfeliz, Jose G.

1993-01-01

Micromechanical modeling via elastic-plastic finite element analyses were performed to investigate the effects that the residual stresses and the degree of matrix work hardening (i.e., cold-worked, annealed) have upon the behavior of a 9 vol percent, unidirectional W/Cu composite, undergoing tensile loading. The inclusion of the residual stress-containing state as well as the simulated matrix material conditions proved to be significant since the Cu matrix material exhibited plastic deformation, which affected the subsequent tensile response of the composite system. The stresses generated during cooldown to room temperature from the manufacturing temperature were more of a factor on the annealed-matrix composite, since they induced the softened matrix to plastically flow. This event limited the total load-carrying capacity of this matrix-dominated, ductile-ductile type material system. Plastic deformation of the hardened-matrix composite during the thermal cooldown stage was not considerable, therefore, the composite was able to sustain a higher stress before showing any appreciable matrix plasticity. The predicted room temperature, stress-strain response, and deformation stages under both material conditions represented upper and lower bounds characteristic of the composite's tensile behavior. The initial deformation stage for the hardened material condition showed negligible matrix plastic deformation while for the annealed state, its initial deformation stage showed extensive matrix plasticity. Both material conditions exhibited a final deformation stage where the fiber and matrix were straining plastically. The predicted stress-strain results were compared to the experimental, room temperature, tensile stress-strain curve generated from this particular composite system. The analyses indicated that the actual thermal-mechanical state of the composite's Cu matrix, represented by the experimental data, followed the annealed material condition.

Functional Metal Matrix Composites: Self-lubricating, Self-healing, and Nanocomposites-An Outlook

NASA Astrophysics Data System (ADS)

Dorri Moghadam, Afsaneh; Schultz, Benjamin F.; Ferguson, J. B.; Omrani, Emad; Rohatgi, Pradeep K.; Gupta, Nikhil

2014-06-01

Many different types of advanced metal matrix composites are now available, some of which possess functional properties. Recent work on particle-reinforced, self-lubricating and self-healing metals and metal matrix nanocomposites (MMNCs) synthesized by solidification synthesis is reviewed. Particle-based MMNCs have been developed by several modern processing tools based on either solid- or liquid-phase synthesis techniques that are claimed to exhibit exciting mechanical properties including improvements of modulus, yield strength, and ultimate tensile strength. This article presents a brief and objective review of the work done over the last decade to identify the challenges and future opportunities in the area of functional nanocomposites. Increasing interest in lightweight materials has resulted in studies on hollow particle-filled metal matrix syntactic foams. Syntactic foams seem especially suitable for development with functional properties such as self-healing and self-lubrication. The metal matrix micro and nanocomposites, and syntactic foams having combinations of ultrahigh strength and wear resistance, self-lubricating, and/or self-healing properties can lead to increased energy efficiency, reliability, comfort of operation, reparability, and safety of vehicles. The focus of the present review is aluminum and magnesium matrix functional materials.

Manufacturing Methods and Technology Project Summary Reports

DTIC Science & Technology

1984-06-01

was selected as the composite material. This selection was based upon the following advantages in comparison to aluminum: 0 Stiffness to weight...closer to titanium than aluminum. Other composite candidate materials considered ( glass , Kevlar and metal matrix) did not offer all of these...of the bearing support ring, and the attachment of the bearing support ring to the composite gimbal base plate. A thermal test structure, which

The role of rapid solidification processing in the fabrication of fiber reinforced metal matrix composites

NASA Technical Reports Server (NTRS)

Locci, Ivan E.; Noebe, Ronald D.

1989-01-01

Advanced composite processing techniques for fiber reinforced metal matrix composites require the flexibility to meet several widespread objectives. The development of uniquely desired matrix microstructures and uniformly arrayed fiber spacing with sufficient bonding between fiber and matrix to transmit load between them without degradation to the fiber or matrix are the minimum requirements necessary of any fabrication process. For most applications these criteria can be met by fabricating composite monotapes which are then consolidated into composite panels or more complicated components such as fiber reinforced turbine blades. Regardless of the end component, composite monotapes are the building blocks from which near net shape composite structures can be formed. The most common methods for forming composite monotapes are the powder cloth, foil/fiber, plasma spray, and arc spray processes. These practices, however, employ rapid solidification techniques in processing of the composite matrix phase. Consequently, rapid solidification processes play a vital and yet generally overlooked role in composite fabrication. The future potential of rapid solidification processing is discussed.

Nonlinear laminate analysis for metal matrix fiber composites

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Sinclair, J. H.

1981-01-01

A nonlinear laminate analysis is described for predicting the mechanical behavior (stress-strain relationships) of angleplied laminates in which the matrix is strained nonlinearly by both the residual stress and the mechanical load and in which additional nonlinearities are induced due to progressive fiber fractures and ply relative rotations. The nonlinear laminate analysis (NLA) is based on linear composite mechanics and a piece wise linear laminate analysis to handle the nonlinear responses. Results obtained by using this nonlinear analysis on boron fiber/aluminum matrix angleplied laminates agree well with experimental data. The results shown illustrate the in situ ply stress-strain behavior and synergistic strength enhancement.

Processing of a fiber-reinforced transparent glass matrix composite and study of micromechanics of load transfer from matrix to fiber using micro-fluorescence spectroscopy

NASA Astrophysics Data System (ADS)

Banerjee, Debangshu

The brittleness of monolithic ceramic materials can be overcome by reinforcing them with high strength, high modulus ceramic fibers. These ceramic matrix composites exhibit improved strength, toughness, and work of fracture. Successful design of a ceramic matrix composite (CMC) depends on two factors: proper choice of fiber, matrix, and interface material, and understanding the mechanics of fracture. The conventional techniques for measuring stress and strain at a local level in CMCs are based on indirect experiments and analytical models. In recent years a couple of optical techniques have been explored for non- contact and direct evaluation of the stress and strain in materials, such as laser Raman spectroscopy and fluorescence spectroscopy. In order to employ spectroscopy to study stress in a composite, a transparent matrix was needed. In this study a SiC fiber reinforced transparent glass matrix composite was developed. A tape casting, binder burnout, and sintering route was adopted to achieve the optimum transparency with proper fiber alignment and interfacial properties. Sapphire fibers were used to act as probe to generate fluorescence signals for measuring stress. A fugitive carbon coating was developed to act as a weak interface for the sapphire fiber, which otherwise, forms a strong bond with the matrix. A fixture was designed to apply stress on the composite specimen, in situ, under the microscope of the spectrometer. Using fluorescence spectroscopy, the micromechanics of load transfer from matrix to fibers were studied. Studies were conducted on both strongly and weakly bonded fibers, as well as on single fiber, and multi fiber situations. Residual stresses arising from thermal expansion mismatch have been mapped along the fiber length with resolution in microns. Residual axial stress was found to follow a shear lag profile along the fiber length. A finite residual axial stress was detected at the fiber ends. Correction of the measured stress for sample probe interaction could not eliminate this finite stress completely. Residual axial stress was also found to vary across the fiber cross section. Analytical models predicting the stress variation along the fiber length and across fiber cross section were developed. (Abstract shortened by UMI.)

Characterizing fiber-reinforced composite structures using AC-impedance spectroscopy (AC-IS)

NASA Astrophysics Data System (ADS)

Woo, Leta Y.

Property enhancement in composites depends largely on the reinforcement. For fiber-reinforced composites, the distribution of fibers is crucial in determining the electrical and mechanical performance. Image analysis methods for characterization can be time-consuming and/or destructive. This work explores the capability of AC-impedance spectroscopy (AC-IS), an electrical measurement technique, to serve as a rapid, non-destructive tool for characterizing composite microstructure. The composite requirements include a filler that is electrically conducting or semi-conducting with higher conductivity than the matrix, and a high-impedance interface or coating between the filler and the matrix. To establish an AC-IS characterization method, cement-matrix composites with steel reinforcement were employed as both a technologically important and a model system to investigate how fibers affect the electrical response. Beginning with spherical particulates and then fibers, composites were examined using composite theory and an "intrinsic conductivity" approach. The intrinsic conductivity approach applies to composites with low volume fractions of fibers (i.e., in the dilute regime) and relates how the composite conductivity varies relative to the matrix as a function of volume fraction. A universal equivalent circuit model was created to understand the AC-IS response of composites based on the geometry and volume fraction of the filler. Deviation from predicted behavior was assessed using a developed f-function, which quantifies how fibers contribute to the overall electrical response of the composite. Using the f-function, an AC-IS method for investigating fiber dispersion was established to characterize alignment, settling/segregation, and aggregation. Alignment was investigated using measurements made in three directions. A point-probe technique characterized settling and/or large-scale inhomogeneous mixing in samples. Aggregation was quantified using a "dispersion factor" that compared theoretical with measured values and served as an upper limit for how well the fibers were dispersed. The AC-IS method was then extended to two different cement-matrix composite systems, low resistivity fresh-paste cement composites (confirmed by time domain reflectometry) and high resistivity cement composites, both of which required additional analysis to apply the AC-IS characterization method.

Production and Characterization of WC-Reinforced Co-Based Superalloy Matrix Composites

NASA Astrophysics Data System (ADS)

Özgün, Özgür; Dinler, İlyas

2018-05-01

Cobalt-based superalloy matrix composite materials were produced through the powder metallurgy technique using element powders at high purity and nano-sized wolfram carbide (WC) reinforcement in this study. An alloy that had the same chemical composition as the Stellite 6 alloy but not containing carbon was selected as the matrix alloy. The powder mixtures obtained as a result of mixing WC reinforcing member and element powders at the determined ratio were shaped by applying 300 MPa of pressure. The green components were sintered under argon atmosphere at 1240 °C for 120 minutes. The densities of the sintered components were determined by the Archimedes' principle. Microstructural characterization was performed via X-ray diffraction analysis, scanning electron microscope examinations, and energy-dispersive spectrometry. Hardness measurements and tensile tests were performed for determining mechanical characteristics. The relative density values of the sintered components increased by increasing the WC reinforcement ratio and they could almost reach the theoretical density. It was determined from the microstructural examinations that the composite materials consisted of fine and equiaxed grains and coarse carbides demonstrating a homogeneous dispersion along the microstructure at the grain boundaries. As it was the case in the density values, the hardness and strength values of the composites increased by increasing the WC ratio.

Production and Characterization of WC-Reinforced Co-Based Superalloy Matrix Composites

NASA Astrophysics Data System (ADS)

Özgün, Özgür; Dinler, İlyas

2018-07-01

Cobalt-based superalloy matrix composite materials were produced through the powder metallurgy technique using element powders at high purity and nano-sized wolfram carbide (WC) reinforcement in this study. An alloy that had the same chemical composition as the Stellite 6 alloy but not containing carbon was selected as the matrix alloy. The powder mixtures obtained as a result of mixing WC reinforcing member and element powders at the determined ratio were shaped by applying 300 MPa of pressure. The green components were sintered under argon atmosphere at 1240 °C for 120 minutes. The densities of the sintered components were determined by the Archimedes' principle. Microstructural characterization was performed via X-ray diffraction analysis, scanning electron microscope examinations, and energy-dispersive spectrometry. Hardness measurements and tensile tests were performed for determining mechanical characteristics. The relative density values of the sintered components increased by increasing the WC reinforcement ratio and they could almost reach the theoretical density. It was determined from the microstructural examinations that the composite materials consisted of fine and equiaxed grains and coarse carbides demonstrating a homogeneous dispersion along the microstructure at the grain boundaries. As it was the case in the density values, the hardness and strength values of the composites increased by increasing the WC ratio.

Influence of tool pin in friction stir welding on activated carbon reinforced aluminium metal matrix composite

NASA Astrophysics Data System (ADS)

DijuSamuel, G.; Raja Dhas, J. Edwin

2017-10-01

This paper focus on impact of tool pin in friction stir welding on activated carbon reinforced aluminium metal matrix composite. For fabrication of metal matrix composite AA6061 is used as matrix and activated carbon is used as reinforcement and it is casted using modified stir casting technique. After casting metal matrix composite has undergone various microstructure tests like SEM,EDAX and XRD. FSW is carried out in this metal matrix composite by choosing various tool pin profile like square,round,Threaded round, hexagon and taper. The quality of welded plates is measured in terms of ultimate tensile strength and hardness.

Lightweight armor system and process for producing the same

DOEpatents

Chu, Henry S.; Bruck, H. Alan; Strempek, Gary C.; Varacalle, Jr., Dominic J.

2004-01-20

A lightweight armor system may comprise a substrate having a graded metal matrix composite layer formed thereon by thermal spray deposition. The graded metal matrix composite layer comprises an increasing volume fraction of ceramic particles imbedded in a decreasing volume fraction of a metal matrix as a function of a thickness of the graded metal matrix composite layer. A ceramic impact layer is affixed to the graded metal matrix composite layer.

Catalytic transformation of persistent contaminants using a new composite material based on nanosized zero-valent metal - field experiment results

NASA Astrophysics Data System (ADS)

Dror, I.; Merom Jacov, O.; Berkowitz, B.

2010-12-01

A new composite material based on deposition of nanosized zero valent iron (ZVI) particles and cyanocobalamine (vitamin B12) on a diatomite matrix is presented. Cyanocobalamine is known to be an effective electron mediator, having strong synergistic effects with ZVI for reductive dehalogenation reactions. This composite material also improves the reducing capacity of nanosized ZVI by preventing agglomeration of iron particles, thus increasing their active surface area. The porous structure of the diatomite matrix allows high hydraulic conductivity, which favors channeling of contaminated water to the reactive surface of the composite material and in turn faster rates of remediation. The ability of the material to degrade or transform rapidly and completely a large spectrum of water pollutants will be demonstrated, based on results from two field site experiments where polluted groundwater containing a mixture of industrial and agricultural persistent pollutants was treated. In addition a set of laboratory experiments using individual contaminant solutions to analyze chemical transformations under controlled conditions will be presented.

Conference on Aerospace Transparent Materials and Enclosures Held in San Diego, California on 9-13 August 1993. Volume 1.

DTIC Science & Technology

1994-03-01

existing baseline aircraft requirements which were modified based on updated threat Information, lessons learned, and composite mission profiles. Composite ...BIRD IMPACT RESISTANT COMPOSITE WINDSHIELD FRAME DEVELOPMENT S. Hargis, SM-ALCITIEC McClellan Air Force Base 0. J. Stenger University of Dayton 190 T... composite windshield frame with an arch consisting of Slaminated S-2 glass fabric and stainless steel sheets in an epoxy matrix has -. been successfully

Matrix- and tensor-based recommender systems for the discovery of currently unknown inorganic compounds

NASA Astrophysics Data System (ADS)

Seko, Atsuto; Hayashi, Hiroyuki; Kashima, Hisashi; Tanaka, Isao

2018-01-01

Chemically relevant compositions (CRCs) and atomic arrangements of inorganic compounds have been collected as inorganic crystal structure databases. Machine learning is a unique approach to search for currently unknown CRCs from vast candidates. Herein we propose matrix- and tensor-based recommender system approaches to predict currently unknown CRCs from database entries of CRCs. Firstly, the performance of the recommender system approaches to discover currently unknown CRCs is examined. A Tucker decomposition recommender system shows the best discovery rate of CRCs as the majority of the top 100 recommended ternary and quaternary compositions correspond to CRCs. Secondly, systematic density functional theory (DFT) calculations are performed to investigate the phase stability of the recommended compositions. The phase stability of the 27 compositions reveals that 23 currently unknown compounds are newly found to be stable. These results indicate that the recommender system has great potential to accelerate the discovery of new compounds.

Tungsten wire-nickel base alloy composite development

NASA Technical Reports Server (NTRS)

Brentnall, W. D.; Moracz, D. J.

1976-01-01

Further development and evaluation of refractory wire reinforced nickel-base alloy composites is described. Emphasis was placed on evaluating thermal fatigue resistance as a function of matrix alloy composition, fabrication variables and reinforcement level and distribution. Tests for up to 1,000 cycles were performed and the best system identified in this current work was 50v/o W/NiCrAlY. Improved resistance to thermal fatigue damage would be anticipated for specimens fabricated via optimized processing schedules. Other properties investigated included 1,093 C (2,000 F) stress rupture strength, impact resistance and static air oxidation. A composite consisting of 30v/o W-Hf-C alloy fibers in a NiCrAlY alloy matrix was shown to have a 100-hour stress rupture strength at 1,093 C (2,000 F) of 365 MN/square meters (53 ksi) or a specific strength advantage of about 3:1 over typical D.S. eutectics.

Preparation and Characterisation of Linear Low-Density Polyethylene / Thermoplastic Starch Blends Filled with Banana Fibre

NASA Astrophysics Data System (ADS)

Kahar, A. W. M.; Ann, L. Ju

2017-06-01

In this study, the influence of banana fibre (BF) loading using sodium hydroxide (NaOH) pre-treated and succinic anhydride-treated (SA) BF on the mechanical properties of linear low-density polyethylene (LLDPE)/thermoplastic starch (TPS) matrix is investigated. LLDPE/TPS/BF composites were developed under different BF conditions, with and without chemical modifications with the BF content ranging from 5% to 30% based on the total composite. The tensile strength showed an increase with an increase of fibre content up to 10%, thereby decreasing gradually beyond this level. NaOH pre-treated and SA treated BF added with LLDPE/TPS composite displays a higher tensile strength as compared to untreated BF in LLDPE/TPS composites. Thermal behaviour of the BF incorporated in LLDPE/TPS composite was characterised using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). This showed that SA treated BF exhibits better thermal stability, compared to other composites. This is because of the improvement in interfacial adhesion existing between both the fibre and matrix. In addition, a morphology study confirmed that pre-treated and treated BF had excellent interfacial adhesion with LLDPE/TPS matrix, leading to better mechanical properties of resultant composites.

The optimal fiber volume fraction and fiber-matrix property compatibility in fiber reinforced composites

NASA Technical Reports Server (NTRS)

Pan, Ning

1992-01-01

Although the question of minimum or critical fiber volume fraction beyond which a composite can then be strengthened due to addition of fibers has been dealt with by several investigators for both continuous and short fiber composites, a study of maximum or optimal fiber volume fraction at which the composite reaches its highest strength has not been reported yet. The present analysis has investigated this issue for short fiber case based on the well-known shear lag (the elastic stress transfer) theory as the first step. Using the relationships obtained, the minimum spacing between fibers is determined upon which the maximum fiber volume fraction can be calculated, depending on the fiber packing forms within the composites. The effects on the value of this maximum fiber volume fraction due to such factors as fiber and matrix properties, fiber aspect ratio and fiber packing forms are discussed. Furthermore, combined with the previous analysis on the minimum fiber volume fraction, this maximum fiber volume fraction can be used to examine the property compatibility of fiber and matrix in forming a composite. This is deemed to be useful for composite design. Finally some examples are provided to illustrate the results.

Crystallization kinetics and thermal resistance of bamboo fiber reinforced biodegradable polymer composites

NASA Astrophysics Data System (ADS)

Thumsorn, S.; Srisawat, N.; On, J. Wong; Pivsa-Art, S.; Hamada, H.

2014-05-01

Bamboo fiber reinforced biodegradable polymer composites were prepared in this study. Biodegradable poly(butylene succinate) (PBS) was blended with bamboo fiber in a twin screw extruder with varied bamboo content from 20-0wt%. PBS/bamboo fiber composites were fabricated by compression molding process. The effect of bamboo fiber contents on properties of the composites was investigated. Non-isothermal crystallization kinetic study of the composites was investigated based on Avrami equation. The kinetic parameters indicated that bamboo fiber acted as heterogeneous nucleation and enhanced crystallinity of the composites. Bamboo fiber was well dispersed on PBS matrix and good adhered with the matrix. Tensile strength of the composites slightly deceased with adding bamboo fiber. However, tensile modulus and impact strength of the composites increased when increasing bamboo fiber contents. It can be noted that bamboo fiber promoted crystallization and crystallinity of PBS in the composites. Therefore, the composites were better in impact load transferring than neat PBS, which exhibited improving on impact performance of the composites.

Matrix coatings based on anodic alumina with carbon nanostructures in the pores

NASA Astrophysics Data System (ADS)

Gorokh, G. G.; Pashechko, M. I.; Borc, J. T.; Lozovenko, A. A.; Kashko, I. A.; Latos, A. I.

2018-03-01

The nanoporous anodic alumina matrixes thickness of 1.5 mm and pore sizes of 45, 90 and 145 nm were formed on Si substrates. The tubular carbon nanostructures were synthesized into the matrixes pores by pyrolysis of fluid hydrocarbon xylene with 1% ferrocene. The structure and composition of the matrix coatings were examined by scanning electron microscopy, Auger analysis and Raman spectroscopy. The carbon nanostructures completely filled the pores of templates and uniformly covered the tops. The structure of carbon nanostructures corresponded to the structure of multiwall carbon nanotubes. Investigations of mechanical and tribological properties of nanostructured oxide-carbon composite performed by scratching and nanoindentation showed nonlinear dependencies of the frictional force, penetration depth of the cantilever, hardness and plane strain modulus on the load. It was found that the microhardness of the samples increases with reduced of alumina pore diameter, and the penetration depth of the cantilever into the film grows with carbon nanostructures size. The results showed the high mechanical strength of nanostructured oxide-carbon composite.

A Bi-Modal Distribution of ALHA77307 Matrix Olivine: Evidence for Fine-Grained Mixing from Multiple Reservoirs in the CO Formation Zone

NASA Technical Reports Server (NTRS)

Frank, D.; Zolensky, Michael E.; Brearley, A.; Le, L.

2011-01-01

The CO 3.0 chondrite ALHA77307 is thought to be the least metamorphosed of all the CO chondrites [1]. As such, the fine-grained (<30 m) olivine found in its matrix is a valuable resource for investigating the CO formation environment since its compositions should be primary. In the CO matrix, we indeed find a wide range of major element compositions (Fa(0.5-71)). However, more importantly, we find that the olivines make up two compositionally distinct populations (Fa(0.5-5) and Fa(21-71)). Grains from both populations are found within an extremely close proximity and we see no obvious evidence of two distinct lithologies within our samples. Therefore, we conclude that the olivine grains found in the ALHA77307 matrix must have crystallized within two unique formation conditions and were later mixed at a very fine scale during the accretion epoch. Here, we propose a possible explanation based on Cr and Mn concentrations in the olivine.

Neutron diffraction measurements and modeling of residual strains in metal matrix composites

NASA Technical Reports Server (NTRS)

Saigal, A.; Leisk, G. G.; Hubbard, C. R.; Misture, S. T.; Wang, X. L.

1996-01-01

Neutron diffraction measurements at room temperature are used to characterize the residual strains in tungsten fiber-reinforced copper matrix, tungsten fiber-reinforced Kanthal matrix, and diamond particulate-reinforced copper matrix composites. Results of finite element modeling are compared with the neutron diffraction data. In tungsten/Kanthal composites, the fibers are in compression, the matrix is in tension, and the thermal residual strains are a strong function of the volume fraction of fibers. In copper matrix composites, the matrix is in tension and the stresses are independent of the volume fraction of tungsten fibers or diamond particles and the assumed stress free temperature because of the low yield strength of the matrix phase.

Recursive flexible multibody system dynamics using spatial operators

NASA Technical Reports Server (NTRS)

Jain, A.; Rodriguez, G.

1992-01-01

This paper uses spatial operators to develop new spatially recursive dynamics algorithms for flexible multibody systems. The operator description of the dynamics is identical to that for rigid multibody systems. Assumed-mode models are used for the deformation of each individual body. The algorithms are based on two spatial operator factorizations of the system mass matrix. The first (Newton-Euler) factorization of the mass matrix leads to recursive algorithms for the inverse dynamics, mass matrix evaluation, and composite-body forward dynamics for the systems. The second (innovations) factorization of the mass matrix, leads to an operator expression for the mass matrix inverse and to a recursive articulated-body forward dynamics algorithm. The primary focus is on serial chains, but extensions to general topologies are also described. A comparison of computational costs shows that the articulated-body, forward dynamics algorithm is much more efficient than the composite-body algorithm for most flexible multibody systems.

Micromechanics Modeling of Composites Subjected to Multiaxial Progressive Damage in the Constituents

NASA Technical Reports Server (NTRS)

Bednarcyk, Brett A.; Aboudi, Jacob; Amold, Steven M.

2010-01-01

The high-fidelity generalized method of cells composite micromechanics model is extended to include constituent-scale progressive damage via a proposed damage model. The damage model assumes that all material nonlinearity is due to damage in the form of reduced stiffness, and it uses six scalar damage variables (three for tension and three for compression) to track the damage. Damage strains are introduced that account for interaction among the strain components and that also allow the development of the damage evolution equations based on the constituent material uniaxial stress strain response. Local final-failure criteria are also proposed based on mode-specific strain energy release rates and total dissipated strain energy. The coupled micromechanics-damage model described herein is applied to a unidirectional E-glass/epoxy composite and a proprietary polymer matrix composite. Results illustrate the capability of the coupled model to capture the vastly different character of the monolithic (neat) resin matrix and the composite in response to far-field tension, compression, and shear loading.

Comparison of Cyclic Hysteresis Behavior between Cross-Ply C/SiC and SiC/SiC Ceramic-Matrix Composites

PubMed Central

Li, Longbiao

2016-01-01

In this paper, the comparison of cyclic hysteresis behavior between cross-ply C/SiC and SiC/SiC ceramic-matrix composites (CMCs) has been investigated. The interface slip between fibers and the matrix existed in the matrix cracking mode 3 and mode 5, in which matrix cracking and interface debonding occurred in the 0° plies are considered as the major reason for hysteresis loops of cross-ply CMCs. The hysteresis loops of cross-ply C/SiC and SiC/SiC composites corresponding to different peak stresses have been predicted using present analysis. The damage parameter, i.e., the proportion of matrix cracking mode 3 in the entire matrix cracking modes of the composite, and the hysteresis dissipated energy increase with increasing peak stress. The damage parameter and hysteresis dissipated energy of C/SiC composite under low peak stress are higher than that of SiC/SiC composite; However, at high peak stress, the damage extent inside of cross-ply SiC/SiC composite is higher than that of C/SiC composite as more transverse cracks and matrix cracks connect together. PMID:28787861

Comparison of Cyclic Hysteresis Behavior between Cross-Ply C/SiC and SiC/SiC Ceramic-Matrix Composites.

PubMed

Li, Longbiao

2016-01-19

In this paper, the comparison of cyclic hysteresis behavior between cross-ply C/SiC and SiC/SiC ceramic-matrix composites (CMCs) has been investigated. The interface slip between fibers and the matrix existed in the matrix cracking mode 3 and mode 5, in which matrix cracking and interface debonding occurred in the 0° plies are considered as the major reason for hysteresis loops of cross-ply CMCs. The hysteresis loops of cross-ply C/SiC and SiC/SiC composites corresponding to different peak stresses have been predicted using present analysis. The damage parameter, i.e. , the proportion of matrix cracking mode 3 in the entire matrix cracking modes of the composite, and the hysteresis dissipated energy increase with increasing peak stress. The damage parameter and hysteresis dissipated energy of C/SiC composite under low peak stress are higher than that of SiC/SiC composite; However, at high peak stress, the damage extent inside of cross-ply SiC/SiC composite is higher than that of C/SiC composite as more transverse cracks and matrix cracks connect together.

Pendulum impact resistance of tungsten fiber/metal matrix composites.

NASA Technical Reports Server (NTRS)

Winsa, E. A.; Petrasek, D. W.

1972-01-01

The impact properties of copper, copper-10 nickel, and a superalloy matrix reinforced with tungsten fibers were studied. In most cases the following increased composite impact strength: increased fiber or matrix toughness, decreased fiber-matrix reaction, increased test temperature, hot working and heat treatment. Notch sensitivity was reduced by increasing fiber or matrix toughness. The effect of fiber content depended on the relative toughness of the fibers and matrix. Above 530 K a 60 volume per cent superalloy matrix composite had a greater impact strength than a turbine blade superalloy, whereas below 530 K a hot worked 56 volume per cent composite had a greater impact strength than the superalloy.

Constitutive Modeling and Testing of Polymer Matrix Composites Incorporating Physical Aging at Elevated Temperatures

NASA Technical Reports Server (NTRS)

Veazie, David R.

1998-01-01

Advanced polymer matrix composites (PMC's) are desirable for structural materials in diverse applications such as aircraft, civil infrastructure and biomedical implants because of their improved strength-to-weight and stiffness-to-weight ratios. For example, the next generation military and commercial aircraft requires applications for high strength, low weight structural components subjected to elevated temperatures. A possible disadvantage of polymer-based composites is that the physical and mechanical properties of the matrix often change significantly over time due to the exposure of elevated temperatures and environmental factors. For design, long term exposure (i.e. aging) of PMC's must be accounted for through constitutive models in order to accurately assess the effects of aging on performance, crack initiation and remaining life. One particular aspect of this aging process, physical aging, is considered in this research.

Stress-Dependent Matrix Cracking in 2D Woven SiC-Fiber Reinforced Melt-Infiltrated SiC Matrix Composites

NASA Technical Reports Server (NTRS)

Morscher, Gregory N.

2003-01-01

The matrix cracking of a variety of SiC/SiC composites has been characterized for a wide range of constituent variation. These composites were fabricated by the 2-dimensional lay-up of 0/90 five-harness satin fabric consisting of Sylramic fiber tows that were then chemical vapor infiltrated (CVI) with BN, CVI with SiC, slurry infiltrated with SiC particles followed by molten infiltration of Si. The composites varied in number of plies, the number of tows per length, thickness, and the size of the tows. This resulted in composites with a fiber volume fraction in the loading direction that ranged from 0.12 to 0.20. Matrix cracking was monitored with modal acoustic emission in order to estimate the stress-dependent distribution of matrix cracks. It was found that the general matrix crack properties of this system could be fairly well characterized by assuming that no matrix cracks originated in the load-bearing fiber, interphase, chemical vapor infiltrated Sic tow-minicomposites, i.e., all matrix cracks originate in the 90 degree tow-minicomposites or the large unreinforced Sic-Si matrix regions. Also, it was determined that the larger tow size composites had a much narrower stress range for matrix cracking compared to the standard tow size composites.

Ballistic Performance of Alimina/S-2 Glass-Reinforced Polymer-Matrix Composite Hybrid Lightweight Armor Against Armor Piercing (AP) and Non-AP Projectiles

DTIC Science & Technology

2007-01-01

and a phenolic -resin based polymeric matrix. Such armor panels offer superior protection against fragmented ballistic threats when compared to...database does not contain a material model for the HJ1 composite but provides a model for a Kevlar Fiber Reinforced Polymer (KFRP) containing 53 vol... phenolic resin and epoxy yield stresses and then with a ratio of the S-2 glass and aramid fibers volume fractions. To test the validity of the

Study of Erosive Wear Behaviour on SIC/SIC Composites

NASA Astrophysics Data System (ADS)

Suh, Min-Soo

In the field of aerospace propulsion system, erosive wear on continuous silicon carbide (SiC) fibre-reinforced SiC (SiC/SiC) composites is of significant issue to achieve high energy efficiency. This paper proposes a crucial factor and a design guideline of SiC/SiC composites for higher erosion performance regarding cost effectiveness. Fabrication and evaluation of impacts and wear on SiC/SiC composites are successfully carried out. Erosive wear behaviours of the CVI and the LPS composites evidently show that the crucial fabrication factor against solid particle erosion (SPE). Erosive wear mechanisms on various SiC/SiC composites are determined based on the analysis of erosive wear behaviour. Designing guideline for the SiC/SiC composites for pursuit of high erosion performance is also proposed as focusing on the followings; volume fraction of matrix, strength of the matrix, bonding strength, and PyC interface.

High temperature insulation for ceramic matrix composites

DOEpatents

Merrill, Gary B.; Morrison, Jay Alan

2001-01-01

A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composition comprises a plurality of hollow oxide-based spheres of various dimensions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substrates are also provided.

High temperature insulation for ceramic matrix composites

DOEpatents

Merrill, Gary B.; Morrison, Jay Alan

2000-01-01

A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composite comprises a plurality of hollow oxide-based spheres of varios dimentions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substates are also provided.

High temperature insulation for ceramic matrix composites

DOEpatents

Merrill, Gary B.; Morrison, Jay Alan

2004-01-13

A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composition comprises a plurality of hollow oxide-based spheres of various dimensions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substrates are also provided.

Standard test evaluation of graphite fiber/resin matrix composite materials for improved toughness

NASA Technical Reports Server (NTRS)

Chapman, Andrew J.

1984-01-01

Programs sponsored by NASA with the commercial transport manufacturers to develop a technology data base are required to design and build composite wing and fuselage structures. To realize the full potential of composite structures in these strength critical designs, material systems having improved ductility and interlaminar toughness are being sought. To promote systematic evaluation of new materials, NASA and the commercial transport manufacturers have selected and standardized a set of five common tests. These tests evaluate open hole tension and compression performance, compression performance after impact at an energy level of 20 ft-lb, and resistance to delamination. Ten toughened resin matrix/graphite fiber composites were evaluated using this series of tests, and their performance is compared with a widely used composite system.

Model Determined for Predicting Fatigue Lives of Metal Matrix Composites Under Mean Stresses

NASA Technical Reports Server (NTRS)

Lerch, Bradley

1997-01-01

Aircraft engine components invariably are subjected to mean stresses over and above the cyclic loads. In monolithic materials, it has been observed that tensile mean stresses are detrimental and compressive mean stresses are beneficial to fatigue life in comparison to a base of zero mean stress. Several mean stress models exist for monolithic metals, but each differ quantitatively in the extent to which detrimental or beneficial effects are ascribed. There have been limited attempts to apply these models to metal matrix composites. At the NASA Lewis Research Center, several mean stress models--the Smith-Watson- Topper, Walker, Normalized Goodman, and Soderberg models--were examined for applicability to this class of composite materials. The Soderberg approach, which normalizes the mean stress to a 0.02-percent yield strength, was shown to best represent the effect of mean stresses over the range covered. The other models varied significantly in their predictability and often failed to predict the composite behavior at very high tensile mean stresses. This work is the first to systematically demonstrate the influence of mean stresses on metal matrix composites and model their effects. Attention also was given to fatigue-cracking mechanisms in the Ti-15-3 matrix and to micromechanics analyses of mean stress effects.

Implementation of an Associative Flow Rule Including Hydrostatic Stress Effects Into the High Strain Rate Deformation Analysis of Polymer Matrix Composites

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.; Roberts, Gary D.; Gilat, Amos

2003-01-01

A previously developed analytical formulation has been modified in order to more accurately account for the effects of hydrostatic stresses on the nonlinear, strain rate dependent deformation of polymer matrix composites. State variable constitutive equations originally developed for metals have been modified in order to model the nonlinear, strain rate dependent deformation of polymeric materials. To account for the effects of hydrostatic stresses, which are significant in polymers, the classical J2 plasticity theory definitions of effective stress and effective inelastic strain, along with the equations used to compute the components of the inelastic strain rate tensor, are appropriately modified. To verify the revised formulation, the shear and tensile deformation of two representative polymers are computed across a wide range of strain rates. Results computed using the developed constitutive equations correlate well with experimental data. The polymer constitutive equations are implemented within a strength of materials based micromechanics method to predict the nonlinear, strain rate dependent deformation of polymer matrix composites. The composite mechanics are verified by analyzing the deformation of a representative polymer matrix composite for several fiber orientation angles across a variety of strain rates. The computed values compare well to experimentally obtained results.

Modeling damage evolution in a hybrid ceramic matrix composite under static tensile load

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bonora, N.; Newaz, G.

In this investigation, damage evolution in a unidirectional hybrid ceramic composite made from Nicalon and SiC fibers in a Lithium Aluminosilicate (LAS) glass matrix was studied. The static stress-strain response of the composite exhibited a linear response followed by load drop in a progressive manner. Careful experiments were conducted stopping the tests at various strain levels and using replication technique, scanning and optical microscopy to monitor the evolution of damage in these composites. It was observed that the constituents of the composite failed in a sequential manner at increasing strain levels. The matrix cracks were followed by SiC fiber failuresmore » near ultimate tensile stress. After that, the load drop was associated with progressive failure of the Nicalon fibers. Identification of these failure modes were critical to the development of a concentric cylinder model representing all three constituent phases to predict the constitutive response of the CMC computationally. The strain-to-failure of the matrix and fibers were used to progressively fail the constituents in the model and the overall experimental constitutive response of the CMC was recovered. A strain based analytical representation was developed relating stiffness loss to applied strain. Based on this formulation, damage evolution and its consequence on tensile stress-strain response was predicted for room temperature behavior of hybrid CMCs. The contribution of the current work is that the proposed strain-damage phenomenological model can capture the damage evolution and the corresponding material response for continuous fiber-reinforced CMCs. The modeling approach shows much promise for the complex damage processes observed in hybrid CMCs.« less

Polyluminol/hydrogel composites as new electrochemiluminescent-active sensing layers.

PubMed

Leca-Bouvier, Béatrice D; Sassolas, Audrey; Blum, Loïc J

2014-09-01

This paper reports on electrochemiluminescent sensors and biosensors based on polyluminol/hydrogel composite sensing layers using chemical or biological membranes as hydrogel matrices. In this work, luminol is electropolymerized under near-neutral conditions onto screen-printed electrode (SPE)-supported hydrogel films. The working electrode coated with a hydrogel film is soaked in a solution containing monomeric luminol units, allowing the monomeric luminol units to diffuse inside the porous matrix to the electrode surface where they are electropolymerized by cyclic voltammetry (CV). Sensors and enzymatic biosensors for H2O2 and choline detection, respectively, have been developed, using choline oxidase (ChOD) as a model enzyme. In this case, hydrogel is used both as the enzymatic immobilization matrix and as a template for the electrosynthesis of polyluminol. The enzyme was immobilized by entrapment in the gel matrix during its formation before electropolymerization of the monomer. Several parameters have been optimized in terms of polymerization conditions, enzyme loading, and average pore size. Using calcium alginate or tetramethoxysilane (TMOS)-based silica as porous matrix, H2O2 and choline detection are reported down to micromolar concentrations with three orders of magnitude wide dynamic ranges starting from 4 × 10(-7) M. Polyluminol/hydrogel composites appear as suitable electrochemiluminescence (ECL)-active sensing layers for the design of new reagentless and disposable easy-to-use optical sensors and biosensors, using conventional TMOS-based silica gel or the more original and easier to handle calcium alginate, reported here for the first time in such a configuration, as the biocompatible hydrogel matrix.

Polyhedral Oligomeric Silsesquioxane (POSS) Dianiline as a Replacement for Toxic Methylenedianiline in PMR-15: Chemistry and Properties

DTIC Science & Technology

2016-08-22

POSS dinadic composite cross-section. Prior to aging, a few voids are seen in the matrix , but no cracks. After the same time aging as with the PMR-15...the composite , fiber and matrix , respectively; σc, σf, and σm are stress in the composite , fiber and matrix , respectively; Vf and Vm are volume...fraction of the fiber and matrix , respectively; Ec, Ef and Em are the moduli of the composite , fiber and matrix , respectively

Progressive Failure And Life Prediction of Ceramic and Textile Composites

NASA Technical Reports Server (NTRS)

Xue, David Y.; Shi, Yucheng; Katikala, Madhu; Johnston, William M., Jr.; Card, Michael F.

1998-01-01

An engineering approach to predict the fatigue life and progressive failure of multilayered composite and textile laminates is presented. Analytical models which account for matrix cracking, statistical fiber failures and nonlinear stress-strain behavior have been developed for both composites and textiles. The analysis method is based on a combined micromechanics, fracture mechanics and failure statistics analysis. Experimentally derived empirical coefficients are used to account for the interface of fiber and matrix, fiber strength, and fiber-matrix stiffness reductions. Similar approaches were applied to textiles using Repeating Unit Cells. In composite fatigue analysis, Walker's equation is applied for matrix fatigue cracking and Heywood's formulation is used for fiber strength fatigue degradation. The analysis has been compared with experiment with good agreement. Comparisons were made with Graphite-Epoxy, C/SiC and Nicalon/CAS composite materials. For textile materials, comparisons were made with triaxial braided and plain weave materials under biaxial or uniaxial tension. Fatigue predictions were compared with test data obtained from plain weave C/SiC materials tested at AS&M. Computer codes were developed to perform the analysis. Composite Progressive Failure Analysis for Laminates is contained in the code CPFail. Micromechanics Analysis for Textile Composites is contained in the code MicroTex. Both codes were adapted to run as subroutines for the finite element code ABAQUS and CPFail-ABAQUS and MicroTex-ABAQUS. Graphic user interface (GUI) was developed to connect CPFail and MicroTex with ABAQUS.

Smart Natural Fiber Reinforced Plastic (NFRP) Composites Based On Recycled Polypropylene in The Presence Kaolin

NASA Astrophysics Data System (ADS)

Suharty, N. S.; Ismail, H.; Diharjo, K.; Handayani, D. S.; Lestari, W. A.

2017-07-01

Composites contain double filler material which act as reinforcement and flame retardants of recycled polypropylene (rPP)/kaolin(Kao)/palm oil empty bunch fiber (PEBF) have been succesfully prepared. The composites were synthesized through reactively solution method, using coupling agent PP-g-AA and compatibilizer DVB. The effect of double filler [Kao/PEBF] were investigated flexural strength (FS), inflammability, and morphology. Mechanical testing result in accordance to ASTM D790, the FS of rPP/DVB/PP-g-AA/Kao+ZB/PEBF composite was 48% higher than that of rPP matrix. Moreover, flexural modulus (FM) was significantly improved by 56% as compared to that of rPP matrix. The scanning electron images (SEM) shown good dispersion of [Ka/PEBF] and good filler-matrix interaction. The inflammability testing result which is tested using ASTM D635, showed that the flame resistance of rPP/DVB/PP-g-AA/Kao+ZB/PEBF composite was improve by increasing of time to ignition (TTI) about 857% and burning rate (BR) decreasing to 66% compared to the raw material rPP matrix. In the same time, the addition of 20% (w/w) PEBF as a second filler to form rPP/DVB/PP-g-AA/Kao+ZB/PEBF composites (F5) is able to increase: the FS by 17.5%, the FM by 19%, the TTI by 7.6% and the BR by 3.7% compared to the composite without PEBF (F2).

Auger analysis of a fiber/matrix interface in a ceramic matrix composite

NASA Technical Reports Server (NTRS)

Honecy, Frank S.; Pepper, Stephen V.

1988-01-01

Auger electron spectroscopy (AES) depth profiling was used to characterize the fiber/matrix interface of an SiC fiber, reaction bonded Si3N4 matrix composite. Depth profiles of the as received double coated fiber revealed concentration oscillations which disappeared after annealing the fiber in the environment used to fabricate the composite. After the composite was fractured, the Auger depth profiles showed that failure occurred in neither the Beta-SiC fiber body nor in the Si3N4 matrix but, concurrently, at the fiber coating/matrix interface and within the fiber coating itself.

Method of making silicon carbide-silicon composite having improved oxidation resistance

NASA Technical Reports Server (NTRS)

Wang, Hongyu (Inventor); Luthra, Krishan Lal (Inventor)

2002-01-01

A Silicon carbide-silicon matrix composite having improved oxidation resistance at high temperatures in dry or water-containing environments is provided. A method is given for sealing matrix cracks in situ in melt infiltrated silicon carbide-silicon matrix composites. The composite cracks are sealed by the addition of various additives, such as boron compounds, into the melt infiltrated silicon carbide-silicon matrix.

Silicon carbide-silicon composite having improved oxidation resistance and method of making

NASA Technical Reports Server (NTRS)

Wang, Hongyu (Inventor); Luthra, Krishan Lal (Inventor)

1999-01-01

A Silicon carbide-silicon matrix composite having improved oxidation resistance at high temperatures in dry or water-containing environments is provided. A method is given for sealing matrix cracks in situ in melt infiltrated silicon carbide-silicon matrix composites. The composite cracks are sealed by the addition of various additives, such as boron compounds, into the melt infiltrated silicon carbide-silicon matrix.

An evaluation of fiber-reinforced titanium matrix composites for advanced high-temperature aerospace applications

NASA Astrophysics Data System (ADS)

Larsen, James M.; Russ, Stephan M.; Jones, J. W.

1995-12-01

The current capabilities of continuous silicon-carbide fiber-reinforced titanium matrix composites (TMCs) are reviewed with respect to application needs and compared to the capabilities of conventional high-temperature monolithic alloys and aluminides. In particular, the properties of a firstgeneration titanium aluminide composite, SCS-6/Ti-24Al-11Nb, and a second-generation metastable beta alloy composite, SCS-6/TIMETAL 21S, are compared with the nickel-base superalloy IN100, the high-temperature titanium alloy Ti-1100, and a relatively new titanium aluminide alloy. Emphasis is given to life-limiting cyclic and monotonie properties and to the influence of time-dependent deformation and environmental effects on these properties. The composite materials offer a wide range of performance capabilities, depending on laminate architecture. In many instances, unidirectional composites exhibit outstanding properties, although the same materials loaded transverse to the fiber direction typically exhibit very poor properties, primarily due to the weak fiber/matrix interface. Depending on the specific mechanical property under consideration, composite cross-ply laminates often show no improvement over the capability of conventional monolithic materials. Thus, it is essential that these composite materials be tailored to achieve a balance of properties suitable to the specific application needs if these materials are to be attractive candidates to replace more conventional materials.

Fabrication of tungsten wire reinforced nickel-base alloy composites

NASA Technical Reports Server (NTRS)

Brentnall, W. D.; Toth, I. J.

1974-01-01

Fabrication methods for tungsten fiber reinforced nickel-base superalloy composites were investigated. Three matrix alloys in pre-alloyed powder or rolled sheet form were evaluated in terms of fabricability into composite monotape and multi-ply forms. The utility of monotapes for fabricating more complex shapes was demonstrated. Preliminary 1093C (2000F) stress rupture tests indicated that efficient utilization of fiber strength was achieved in composites fabricated by diffusion bonding processes. The fabrication of thermal fatigue specimens is also described.

Ultrasonic assessment of bonding integrity in foam-based hybrid composite materials

NASA Astrophysics Data System (ADS)

Chen, M. Y.; Ko, R. T.; Hoppe, W. C.; Blackshire, J. L.

2013-01-01

Ultrasonic assessment of the bonding integrity between a composite layer and a foam substrate in foam-based hybrid composite materials was explored. The challenges of this task are: (1) the foam has air-like acoustic impedance and (2) contact surface wave generation on polymer matrix composites (PMC) is not conventional. To meet these challenges, a novel wedge made of a low velocity material was developed. The results showed that the bonding condition in these composites can be identified by monitoring the amplitude of the ultrasonic signals received.

Cure Cycle Design Methodology for Fabricating Reactive Resin Matrix Fiber Reinforced Composites: A Protocol for Producing Void-free Quality Laminates

NASA Technical Reports Server (NTRS)

Hou, Tan-Hung

2014-01-01

For the fabrication of resin matrix fiber reinforced composite laminates, a workable cure cycle (i.e., temperature and pressure profiles as a function of processing time) is needed and is critical for achieving void-free laminate consolidation. Design of such a cure cycle is not trivial, especially when dealing with reactive matrix resins. An empirical "trial and error" approach has been used as common practice in the composite industry. Such an approach is not only costly, but also ineffective at establishing the optimal processing conditions for a specific resin/fiber composite system. In this report, a rational "processing science" based approach is established, and a universal cure cycle design protocol is proposed. Following this protocol, a workable and optimal cure cycle can be readily and rationally designed for most reactive resin systems in a cost effective way. This design protocol has been validated through experimental studies of several reactive polyimide composites for a wide spectrum of usage that has been documented in the previous publications.

Effective thermoelastic properties of discrete-fiber reinforced materials with transversally-isotropic components

NASA Astrophysics Data System (ADS)

Nazarenko, Lidiya; Khoroshun, Leonid; Müller, Wolfgang H.; Wille, Ralf

2009-02-01

In the present paper, we will illustrate the application of the method of conditional moments by constructing the algorithm for determination of the effective elastic properties of composites from the given elastic constants of the components and geometrical parameters of inclusions. A special case of two-component matrix composite with randomly distributed unidirectional spheroidal inclusions is considered. To this end it is assumed that the components of the composite show transversally isotropic symmetry of thermoelastic properties and that the axes of symmetry of the thermoelastic properties of the matrix and inclusions coincide with the coordinate axis x 3. As a numerical example a composite based on carbon inclusions and epoxide matrix is investigated. The dependencies of Young’s moduli, Poisson’s ratios and shear modulus from the concentration of inclusions and for certain values which characterize the shape of inclusions are analyzed. The results are compared and discussed in context with other theoretical predictions and experimental data.

The effect of weak interface on transverse properties of a ceramic matrix composite

NASA Technical Reports Server (NTRS)

Shimansky, R. A.; Hahn, H. T.; Salamon, N. J.

1990-01-01

Experimental studies conducted at NASA Lewis on SiC reaction-bonded Si3N4 composite system showed that transverse stiffness and strength were much lower than those predicted from existing analytical models based on good interfacial bonding. It was believed that weakened interfaces were responsible for the decrease in tranverse properties. To support this claim, a two-dimensional FEM analysis was performed for a transverse representative volume element. Specifically, the effect of fiber/matrix displacement compatibility at the interface was studied under both tensile and compressive transverse loadings. Interface debonding was represented using active gap elements connecting the fiber and matrix. The analyses show that the transverse tensile strength and stiffness are best predicted when a debonded interface is assumed for the composite. In fact, the measured properties can be predicted by simply replacing the fibers by voids. Thus, it is found that little or no interfacial bonding exists in the composite, and that an elastic analysis can predict the transverse stiffness and strength.

Fatigue Resistance of Liquid-assisted Self-repairing Aluminum Alloys Reinforced with Shape Memory Alloys

NASA Technical Reports Server (NTRS)

Wright, M. Clara; Manuel, Michele; Wallace, Terryl

2013-01-01

A self-repairing aluminum-based composite system has been developed using a liquid-assisted healing theory in conjunction with the shape memory effect of wire reinforcements. The metal-metal composite was thermodynamically designed to have a matrix with a relatively even dispersion of a low-melting eutectic phase, allowing for repair of cracks at a predetermined temperature. Additionally, shape memory alloy (SMA) wire reinforcements were used within the composite to provide crack closure. Investigators focused the research on fatigue cracks propagating through the matrix in order to show a proof-of-concept Shape Memory Alloy Self-Healing (SMASH) technology for aeronautical applications.

Incorporation of Mean Stress Effects into the Micromechanical Analysis of the High Strain Rate Response of Polymer Matrix Composites

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.; Roberts, Gary D.; Gilat, Amos

2002-01-01

The results presented here are part of an ongoing research program, to develop strain rate dependent deformation and failure models for the analysis of polymer matrix composites subject to high strain rate impact loads. A micromechanics approach is employed in this work, in which state variable constitutive equations originally developed for metals have been modified to model the deformation of the polymer matrix, and a strength of materials based micromechanics method is used to predict the effective response of the composite. In the analysis of the inelastic deformation of the polymer matrix, the definitions of the effective stress and effective inelastic strain have been modified in order to account for the effect of hydrostatic stresses, which are significant in polymers. Two representative polymers, a toughened epoxy and a brittle epoxy, are characterized through the use of data from tensile and shear tests across a variety of strain rates. Results computed by using the developed constitutive equations correlate well with data generated via experiments. The procedure used to incorporate the constitutive equations within a micromechanics method is presented, and sample calculations of the deformation response of a composite for various fiber orientations and strain rates are discussed.

Application of Pulse Processes in Fabrication of Metal Matrix Composites

NASA Astrophysics Data System (ADS)

Sudnik, L. V.; Vityaz', P. A.; Il'yushchenko, A. F.; Smirnov, G. V.; Petrov, I. V.; Konoplyanik, V. N.; Komornyi, A. A.; Luchenok, A. R.

2016-05-01

Special features and advantages of metal matrix composites obtained by pulse loading are considered. Examples of effective use of metal matrix composites in various fields of engineering are presented.

The Particle Shape of WC Governing the Fracture Mechanism of Particle Reinforced Iron Matrix Composites.

PubMed

Li, Zulai; Wang, Pengfei; Shan, Quan; Jiang, Yehua; Wei, He; Tan, Jun

2018-06-11

In this work, tungsten carbide particles (WC p , spherical and irregular particles)-reinforced iron matrix composites were manufactured utilizing a liquid sintering technique. The mechanical properties and the fracture mechanism of WC p /iron matrix composites were investigated theoretically and experimentally. The crack schematic diagram and fracture simulation diagram of WC p /iron matrix composites were summarized, indicating that the micro-crack was initiated both from the interface for spherical and irregular WC p /iron matrix composites. However, irregular WC p had a tendency to form spherical WC p . The micro-cracks then expanded to a wide macro-crack at the interface, leading to a final failure of the composites. In comparison with the spherical WC p , the irregular WC p were prone to break due to the stress concentration resulting in being prone to generating brittle cracking. The study on the fracture mechanisms of WC p /iron matrix composites might provide a theoretical guidance for the design and engineering application of particle reinforced composites.

Analysis of the Microstructure and Mechanical Properties of Titanium-Based Composites Reinforced by Secondary Phases and B4C Particles Produced via Direct Hot Pressing

PubMed Central

Montealegre-Melendez, Isabel; Arévalo, Cristina; Ariza, Enrique; Rubio-Escudero, Cristina; Kitzmantel, Michael; Neubauer, Erich

2017-01-01

In the last decade, titanium metal matrix composites (TMCs) have received considerable attention thanks to their interesting properties as a consequence of the clear interface between the matrix and the reinforcing phases formed. In this work, TMCs with 30 vol % of B4C are consolidated by hot pressing. This technique is a powder metallurgy rapid process. Incorporation of the intermetallic to the matrix, 20 vol % (Ti-Al), is also evaluated. Here, the reinforcing phases formed by the reaction between the titanium matrix and the ceramic particles, as well as the intermetallic addition, promote substantial variations to the microstructure and to the properties of the fabricated composites. The influences of the starting materials and the consolidation temperature (900 °C and 1000 °C) are investigated. By X-ray diffraction, scanning and transmission electron microscopy analysis, the in-situ-formed phases in the matrix and the residual ceramic particles were studied. Furthermore, mechanical properties are studied through tensile and bending tests in addition to other properties, such as Young’s modulus, hardness, and densification of the composites. The results show the significant effect of temperature on the microstructure and on the mechanical properties from the same starting powder. Moreover, the Ti-Al addition causes variation in the interface between the reinforcement and the matrix, thereby affecting the behaviour of the TMCs produced at the same temperature. PMID:29077066

Joining and Assembly of Silicon Carbide-based Advanced Ceramics and Composites for High Temperature Applications

NASA Technical Reports Server (NTRS)

Singh, M.

2004-01-01

Silicon carbide based advanced ceramics and fiber reinforced composites are under active consideration for use in wide variety of high temperature applications within the aeronautics, space transportation, energy, and nuclear industries. The engineering designs of ceramic and composite component require fabrication and manufacturing of large and complex shaped parts of various thicknesses. In many instances, it is more economical to build up complex shapes by joining simple geometrical shapes. In addition these components have to be joined or assembled with metallic sub-components. Thus, joining and attachment have been recognized as enabling technologies for successful utilization of ceramic components in various demanding applications. In this presentation, various challenges and opportunities in design, fabrication, and testing o high temperature joints in ceramic matrix composites will be presented. Silicon carbide based advanced ceramics (CVD and hot pressed), and C/SiC and SiC/SiC composites, in different shapes and sizes, have been joined using an affordable, robust ceramic joining technology (ARCJoinT). Microstructure and high temperature mechanical properties of joints in silicon carbide ceramics and CVI and melt infiltrated SiC matrix composites will,be reported. Various joint design philosophies and design issues in joining of ceramics and composites well be discussed.

Gamma irradiation assisted fungal degradation of the polypropylene/biomass composites

NASA Astrophysics Data System (ADS)

Butnaru, Elena; Darie-Niţă, Raluca Nicoleta; Zaharescu, Traian; Balaeş, Tiberius; Tănase, Cătălin; Hitruc, Gabriela; Doroftei, Florica; Vasile, Cornelia

2016-08-01

White-rot fungus Bjerkandera adusta has been tested for its ability to degrade some biocomposites materials based on polypropylene and biomass (Eucalyptus globulus, pine cones, and Brassica rapa). γ-irradiation was applied to initiate the degradation of relatively inert polypropylene matrix. The degradation process has been studied by scanning electron microscopy, atomic force microscopy, infrared spectroscopy, contact angle measurements, rheological and chemiluminescence tests. These analyses showed that the polypropylene/biomass composites properties are worsen under the action of the selected microorganism. The formation of cracks and scrap particles over the entire matrix surface and the decrease of the complex viscosity values, as well as the dynamic moduli of gamma irradiated PP/biomass composite and exposed to Bjerkandera adusta fungus, indicate fungal efficiency in composite degradation.

Intermediate Temperature Stress Rupture of Woven SiC Fiber, BN Interphase, SiC Matrix Composites in Air

NASA Technical Reports Server (NTRS)

Morscher, Gregory N.; Levine, Stanley (Technical Monitor)

2000-01-01

Tensile stress-rupture experiments were performed on woven Hi-Nicalon reinforced SiC matrix composites with BN interphases in air. Modal acoustic emission (AE) was used to monitor the damage accumulation in the composites during the tests and microstructural analysis was performed to determine the amount of matrix cracking that occurred for each sample. Fiber fractograph), was also performed for individual fiber failures at the specimen fracture surface to determine the strengths at which fibers failed. The rupture strengths were significantly worse than what would have been expected front the inherent degradation of the fibers themselves when subjected to similar rupture conditions. At higher applied stresses the rate of rupture "?as larger than at lower applied stresses. It was observed that the change in rupture rate corresponded to the onset of through-thickness cracking in the composites themselves. The primary cause of the sen,ere degradation was the ease with which fibers would bond to one another at their closest separation distances, less than 100 nanometers, when exposed to the environment. The near fiber-to-fiber contact in the woven tows enabled premature fiber failure over large areas of matrix cracks due to the stress-concentrations created b), fibers bonded to one another after one or a few fibers fail. i.e. the loss of global load sharing. An@, improvement in fiber-to-fiber separation of this composite system should result in improved stress- rupture properties. A model was den,eloped in order to predict the rupture life-time for these composites based on the probabilistic nature of indin,idual fiber failure at temperature. the matrix cracking state during the rupture test, and the rate of oxidation into a matrix crack. Also incorporated into the model were estimates of the stress-concentration that would occur between the outer rim of fibers in a load-bearing bundle and the unbridged region of a matrix crack after Xia et al. For the lower stresses, this source of stress-concentration was the likely cause for initial fiber failure that would trigger catastrophic failure of the composite.

Understanding the Percolation Characteristics of Nonlinear Composite Dielectrics

PubMed Central

Yang, Xiao; Hu, Jun; Chen, Shuiming; He, Jinliang

2016-01-01

Nonlinear composite dielectrics can function as smart materials for stress control and field grading in all fields of electrical insulations. The percolation process is a significant issue of composite dielectrics. However, the classic percolation theory mainly deals with traditional composites in which the electrical parameters of both insulation matrix and conducting fillers are independent of the applied electric field. This paper measured the nonlinear V-I characteristics of ZnO microvaristors/silicone rubber composites with several filler concentrations around an estimated percolation threshold. For the comparison with the experiment, a new microstructural model is proposed to simulate the nonlinear conducting behavior of the composite dielectrics modified by metal oxide fillers, which is based on the Voronoi network and considers the breakdown feature of the insulation matrix for near percolated composites. Through both experiment and simulation, the interior conducting mechanism and percolation process of the nonlinear composites were presented and a specific percolation threshold was determined as 33%. This work has provided a solution to better understand the characteristics of nonlinear composite dielectrics. PMID:27476998

Understanding the Percolation Characteristics of Nonlinear Composite Dielectrics

NASA Astrophysics Data System (ADS)

Yang, Xiao; Hu, Jun; Chen, Shuiming; He, Jinliang

2016-08-01

Nonlinear composite dielectrics can function as smart materials for stress control and field grading in all fields of electrical insulations. The percolation process is a significant issue of composite dielectrics. However, the classic percolation theory mainly deals with traditional composites in which the electrical parameters of both insulation matrix and conducting fillers are independent of the applied electric field. This paper measured the nonlinear V-I characteristics of ZnO microvaristors/silicone rubber composites with several filler concentrations around an estimated percolation threshold. For the comparison with the experiment, a new microstructural model is proposed to simulate the nonlinear conducting behavior of the composite dielectrics modified by metal oxide fillers, which is based on the Voronoi network and considers the breakdown feature of the insulation matrix for near percolated composites. Through both experiment and simulation, the interior conducting mechanism and percolation process of the nonlinear composites were presented and a specific percolation threshold was determined as 33%. This work has provided a solution to better understand the characteristics of nonlinear composite dielectrics.

Fracture-Based Mesh Size Requirements for Matrix Cracks in Continuum Damage Mechanics Models

NASA Technical Reports Server (NTRS)

Leone, Frank A.; Davila, Carlos G.; Mabson, Gerald E.; Ramnath, Madhavadas; Hyder, Imran

2017-01-01

This paper evaluates the ability of progressive damage analysis (PDA) finite element (FE) models to predict transverse matrix cracks in unidirectional composites. The results of the analyses are compared to closed-form linear elastic fracture mechanics (LEFM) solutions. Matrix cracks in fiber-reinforced composite materials subjected to mode I and mode II loading are studied using continuum damage mechanics and zero-thickness cohesive zone modeling approaches. The FE models used in this study are built parametrically so as to investigate several model input variables and the limits associated with matching the upper-bound LEFM solutions. Specifically, the sensitivity of the PDA FE model results to changes in strength and element size are investigated.

Self-actuating and self-diagnosing plastically deforming piezo-composite flapping wing MAV

NASA Astrophysics Data System (ADS)

Harish, Ajay B.; Harursampath, Dineshkumar; Mahapatra, D. Roy

2011-04-01

In this work, we propose a constitutive model to describe the behavior of Piezoelectric Fiber Reinforced Composite (PFRC) material consisting of elasto-plastic matrix reinforced by strong elastic piezoelectric fibers. Computational efficiency is achieved using analytical solutions for elastic stifness matrix derived from Variational Asymptotic Methods (VAM). This is extended to provide Structural Health Monitoring (SHM) based on plasticity induced degradation of flapping frequency of PFRC. Overall this work provides an effective mathematical tool that can be used for structural self-health monitoring of plasticity induced flapping degradation of PFRC flapping wing MAVs. The developed tool can be re-calibrated to also provide SHM for other forms of failures like fatigue, matrix cracking etc.

Temperature dependent nonlinear metal matrix laminae behavior

NASA Technical Reports Server (NTRS)

Barrett, D. J.; Buesking, K. W.

1986-01-01

An analytical method is described for computing the nonlinear thermal and mechanical response of laminated plates. The material model focuses upon the behavior of metal matrix materials by relating the nonlinear composite response to plasticity effects in the matrix. The foundation of the analysis is the unidirectional material model which is used to compute the instantaneous properties of the lamina based upon the properties of the fibers and matrix. The unidirectional model assumes that the fibers properties are constant with temperature and assumes that the matrix can be modelled as a temperature dependent, bilinear, kinematically hardening material. An incremental approach is used to compute average stresses in the fibers and matrix caused by arbitrary mechanical and thermal loads. The layer model is incorporated in an incremental laminated plate theory to compute the nonlinear response of laminated metal matrix composites of general orientation and stacking sequence. The report includes comparisons of the method with other analytical approaches and compares theoretical calculations with measured experimental material behavior. A section is included which describes the limitations of the material model.

Composites Based on Polytetrafluoroethylene and Detonation Nanodiamonds: Filler-Matrix Chemical Interaction and Its Effect on a Composite's Properties

NASA Astrophysics Data System (ADS)

Koshcheev, A. P.; Perov, A. A.; Gorokhov, P. V.; Zaripov, N. V.; Tereshenkov, A. V.; Khatipov, S. A.

2018-06-01

Specific properties of PTFE composites filled with ultradisperse detonation diamonds (UDDs) with different surface chemistries are studied. It is found for the first time that filler in the form of UDDs affects not only the rate of PTFE thermal decomposition in vacuum pyrolysis, but also the chemical composition of the products of degradation. The wear resistance of UDD/PTFE composites is shown to depend strongly on the UDD surface chemistry. The presence of UDDs in a PTFE composite is found to result in perfluorocarbon telomeres, released as a readily condensable fraction upon composite pyrolysis. The chemical interaction between PTFE and UDDs, characterized by an increase in the rate of gas evolution and a change in the desorbed gas's composition, is found to occur at temperature as low as 380°C. It is shown that the intensity of this interaction depends on the concentration of oxygen-containing surface groups, the efficiency of UDDs in terms of the composite's wear resistance being reduced due to the presence of these groups. Based on the experimental data, a conclusion is reached about the chemical interaction between UDDs and a PTFE matrix, its dependence on the nanodiamond surface chemistry, and its effect on a composite's tribology.

Effect of Composite Fabrication on the Strength of Single Crystal Al2O3 Fibers in Two Fe-Base Alloy Composites

NASA Technical Reports Server (NTRS)

Draper, Susan L.; Aiken, Beverly J. M.

1998-01-01

Continuous single-crystal Al2O3 fibers have been incorporated into a variety of metal and intermetallic matrices and the results have consistently indicated that the fiber strength had been reduced by 32 to 50% during processing. Two iron-based alloys, FeNiCoCrAl and FeAlVCMn, were chosen as matrices for Al2O3 fiber reinforced metal matrix composites (MMC) with the goal of maintaining Al2O3 fiber strength after composite processing. The feasibility of Al2O3/FeNiCoCrAl and Al2O3/FeAlVCMn composite systems for high temperature applications were assessed in terms of fiber-matrix chemical compatibility, interfacial bond strength, and composite tensile properties. The strength of etched-out fibers was significantly improved by choosing matrices containing less reactive elements. The ultimate tensile strength (UTS) values of the composites could generally be predicted with existing models using the strength of etched-out fibers. However, the UTS of the composites were less than desired due to a low fiber Weibull modulus. Acoustic emission analysis during tensile testing was a useful tool for determining the efficiency of the fibers in the composite and for determining the failure mechanism of the composites.

Tissue Anisotropy Modeling Using Soft Composite Materials.

PubMed

Chanda, Arnab; Callaway, Christian

2018-01-01

Soft tissues in general exhibit anisotropic mechanical behavior, which varies in three dimensions based on the location of the tissue in the body. In the past, there have been few attempts to numerically model tissue anisotropy using composite-based formulations (involving fibers embedded within a matrix material). However, so far, tissue anisotropy has not been modeled experimentally. In the current work, novel elastomer-based soft composite materials were developed in the form of experimental test coupons, to model the macroscopic anisotropy in tissue mechanical properties. A soft elastomer matrix was fabricated, and fibers made of a stiffer elastomer material were embedded within the matrix material to generate the test coupons. The coupons were tested on a mechanical testing machine, and the resulting stress-versus-stretch responses were studied. The fiber volume fraction (FVF), fiber spacing, and orientations were varied to estimate the changes in the mechanical responses. The mechanical behavior of the soft composites was characterized using hyperelastic material models such as Mooney-Rivlin's, Humphrey's, and Veronda-Westmann's model and also compared with the anisotropic mechanical behavior of the human skin, pelvic tissues, and brain tissues. This work lays the foundation for the experimental modelling of tissue anisotropy, which combined with microscopic studies on tissues can lead to refinements in the simulation of localized fiber distribution and orientations, and enable the development of biofidelic anisotropic tissue phantom materials for various tissue engineering and testing applications.

Tissue Anisotropy Modeling Using Soft Composite Materials

PubMed Central

Callaway, Christian

2018-01-01

Soft tissues in general exhibit anisotropic mechanical behavior, which varies in three dimensions based on the location of the tissue in the body. In the past, there have been few attempts to numerically model tissue anisotropy using composite-based formulations (involving fibers embedded within a matrix material). However, so far, tissue anisotropy has not been modeled experimentally. In the current work, novel elastomer-based soft composite materials were developed in the form of experimental test coupons, to model the macroscopic anisotropy in tissue mechanical properties. A soft elastomer matrix was fabricated, and fibers made of a stiffer elastomer material were embedded within the matrix material to generate the test coupons. The coupons were tested on a mechanical testing machine, and the resulting stress-versus-stretch responses were studied. The fiber volume fraction (FVF), fiber spacing, and orientations were varied to estimate the changes in the mechanical responses. The mechanical behavior of the soft composites was characterized using hyperelastic material models such as Mooney-Rivlin's, Humphrey's, and Veronda-Westmann's model and also compared with the anisotropic mechanical behavior of the human skin, pelvic tissues, and brain tissues. This work lays the foundation for the experimental modelling of tissue anisotropy, which combined with microscopic studies on tissues can lead to refinements in the simulation of localized fiber distribution and orientations, and enable the development of biofidelic anisotropic tissue phantom materials for various tissue engineering and testing applications. PMID:29853996

Update on dental nanocomposites.

PubMed

Chen, M-H

2010-06-01

Dental resin-composites are comprised of a photo-polymerizable organic resin matrix and mixed with silane-treated reinforcing inorganic fillers. In the development of the composites, the three main components can be modified: the inorganic fillers, the organic resin matrix, and the silane coupling agents. The aim of this article is to review recent studies of the development of dental nanocomposites and their clinical applications. In nanocomposites, nanofillers are added and distributed in a dispersed form or as clusters. For increasing the mineral content of the tooth, calcium and phosphate ion-releasing composites and fluoride-releasing nanocomposites were developed by the addition of DCPA-whiskers or TTCP-whiskers or by the use of calcium fluoride or kaolinite. For enhancing mechanical properties, nanocomposites reinforced with nanofibers or nanoparticles were investigated. For reducing polymerization shrinkage, investigators modified the resin matrix by using methacrylate and epoxy functionalized nanocomposites based on silsesquioxane cores or epoxy-resin-based nanocomposites. The effects of silanization were also studied. Clinical consideration of light-curing modes and mechanical properties of nanocomposites, especially strength durability after immersion, was also addressed.

Acid-doped polymer nanofiber framework: Three-dimensional proton conductive network for high-performance fuel cells

NASA Astrophysics Data System (ADS)

Tanaka, Manabu; Takeda, Yasushi; Wakiya, Takeru; Wakamoto, Yuta; Harigaya, Kaori; Ito, Tatsunori; Tarao, Takashi; Kawakami, Hiroyoshi

2017-02-01

High-performance polymer electrolyte membranes (PEMs) with excellent proton conductivity, gas barrier property, and membrane stability are desired for future fuel cells. Here we report the development of PEMs based on our proposed new concept "Nanofiber Framework (NfF)." The NfF composite membranes composed of phytic acid-doped polybenzimidazole nanofibers (PBINf) and Nafion matrix show higher proton conductivity than the recast-Nafion membrane without nanofibers. A series of analyses reveal the formation of three-dimensional network nanostructures to conduct protons and water effectively through acid-condensed layers at the interface of PBINf and Nafion matrix. In addition, the NfF composite membrane achieves high gas barrier property and distinguished membrane stability. The fuel cell performance by the NfF composite membrane, which enables ultra-thin membranes with their thickness less than 5 μm, is superior to that by the recast-Nafion membrane, especially at low relative humidity. Such NfF-based high-performance PEM will be accomplished not only by the Nafion matrix used in this study but also by other polymer electrolyte matrices for future PEFCs.

A Study of the Critical Factors Controlling the Synthesis of Ceramic Matrix Composites from Preceramic Polymers.

DTIC Science & Technology

1988-04-15

physical properties of a polycarbosilane preceramic polymer as a function of temperature to derive synthesis methodology for SiC matrix composites , (2...investigate the role of interface modification in creating tough carbon fiber reinforced SiC matrix composites . RESEARCH PROGRESS Preceramic Polymer ...Classfication) A STUDY OF THE CRITICAL FACTORS CONTROLLING THE SYNTHESIS OF CERAMIC MATRIX COMPOSITES FROM PRECERAMIC POLYMERS 12. PERSONAL AUTHOR(S

Mechanical and Impact Characterization of Poly-Dicyclopentadiene (p-DCPD) Matrix Composites Using Novel Glass Fibers and Sizings

DTIC Science & Technology

2016-08-01

Matrix Composites Using Novel Glass Fibers and Sizings by Steven E Boyd Approved for public release; distribution is...Research Laboratory Mechanical and Impact Characterization of Poly-Dicyclopentadiene (p-DCPD) Matrix Composites Using Novel Glass Fibers and Sizings...p-DCPD) Matrix Composites Using Novel Glass Fibers and Sizings 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR

High Temperature Mechanical Characterization of Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Gyekenyesi, John Z.

1998-01-01

A high temperature mechanical characterization laboratory has been assembled at NASA Lewis Research Center. One contribution of this work is to test ceramic matrix composite specimens in tension in environmental extremes. Two high temperature tensile testing systems were assembled. The systems were assembled based on the performance and experience of other laboratories and meeting projected service conditions for the materials in question. The systems use frames with an electric actuator and a center screw. A PC based data acquisition and analysis system is used to collect and analyze the data. Mechanical extensometers are used to measure specimen strain. Thermocouples, placed near the specimen, are used to measure the specimen gage section temperature. The system for testing in air has a resistance element furnace with molybdenum disilicide elements and pneumatic grips with water cooling attached to hydraulic alignment devices. The system for testing in an inert gas has a graphite resistance element furnace in a chamber with rigidly mounted, water cooled, hydraulically actuated grips. Unidirectional SiC fiber reinforced reaction bonded Si3N4 and triaxially woven, two dimensional, SiC fiber reinforced enhanced SiC composites were tested in unidirectional tension. Theories for predicting the Young's modulus, modulus near the ultimate strength, first matrix cracking stress, and ultimate strength were applied and evaluated for suitability in predicting the mechanical behavior of SiC/RBSN and enhanced SiC/SiC composites. The SiC/RBSN composite exhibited pseudo tough behavior (increased area under the stress/strain curve) from 22 C to 1500 C. The rule of mixtures provides a good estimate of the Young's modulus of the SiC/RBSN composite using the constituent properties from room temperature to 1440 C for short term static tensile tests in air or nitrogen. The rule of mixtures significantly overestimates the secondary modulus near the ultimate strength. The ACK theory provides the best approximation of the first matrix cracking stress when residual stresses are ignored. The theory of Cao and Thouless, based on Weibull statistics, gave the best prediction for the composite ultimate strength. The enhanced SiC/SiC composite exhibited nonlinear stress/strain behavior from 24 C to 1370 C in air with increased ultimate strain when compared to monolithic SiC. The theory of Yang and Chou with the assumption of a frictional fiber/matrix interface provided the best estimate of the Young's modulus. The theory of Cao and Thouless gave the best estimate for the ultimate strength.

Mechanical property characterization of polymeric composites reinforced by continuous microfibers

NASA Astrophysics Data System (ADS)

Zubayar, Ali

Innumerable experimental works have been conducted to study the effect of polymerization on the potential properties of the composites. Experimental techniques are employed to understand the effects of various fibers, their volume fractions and matrix properties in polymer composites. However, these experiments require fabrication of various composites which are time consuming and cost prohibitive. Advances in computational micromechanics allow us to study the various polymer based composites by using finite element simulations. The mechanical properties of continuous fiber composite strands are directional. In traditional continuous fiber laminated composites, all fibers lie in the same plane. This provides very desirable increases in the in-plane mechanical properties, but little in the transverse mechanical properties. The effect of different fiber/matrix combinations with various orientations is also available. Overall mechanical properties of different micro continuous fiber reinforced composites with orthogonal geometry are still unavailable in the contemporary research field. In this research, the mechanical properties of advanced polymeric composite reinforced by continuous micro fiber will be characterized based on analytical investigation and FE computational modeling. Initially, we have chosen IM7/PEEK, Carbon Fiber/Nylon 6, and Carbon Fiber/Epoxy as three different case study materials for analysis. To obtain the equivalent properties of the micro-hetero structures, a concept of micro-scale representative volume elements (RVEs) is introduced. Five types of micro scale RVEs (3 square and 2 hexagonal) containing a continuous micro fiber in the polymer matrix were designed. Uniaxial tensile, lateral expansion and transverse shear tests on each RVE were designed and conducted by the finite element computer modeling software ANSYS. The formulae based on elasticity theory were derived for extracting the equivalent mechanical properties (Young's moduli, shear moduli, and Poisson's ratios) from the numerical solutions of the RVEs undergone these three load tests. Validation of the obtained micro-scale mechanical properties will be performed using rule of mixture (ROM), 1st, and 2nd order of the mathematical model and experimental data.

Self-healing polymers and composites based on thermal activation

NASA Astrophysics Data System (ADS)

Wang, Ying; Bolanos, Ed; Wudl, Fred; Hahn, Thomas; Kwok, Nathan

2007-04-01

Structural polymer composites are susceptible to premature failure in the form of microcracks in the matrix. Although benign initially when they form, these matrix cracks tend to coalesce and lead in service to critical damage modes such as ply delamination. The matrix cracks are difficult to detect and almost impossible to repair because they form inside the composite laminate. Therefore, polymers with self-healing capability would provide a promising potential to minimize maintenance costs while extending the service lifetime of composite structures. In this paper we report on a group of polymers and their composites which exhibit mendable property upon heating. The failure and healing mechanisms of the polymers involve Diels-Alder (DA) and retro-Diels-Alder (RDA) reactions on the polymer back-bone chain, which are thermally reversible reactions requiring no catalyst. The polymers exhibited good healing property in bulk form. Composite panels were prepared by sandwiching the monomers between carbon fiber fabric layers and cured in autoclave. Microcracks were induced on the resin-rich surface of composite with Instron machine at room temperature by holding at 1% strain for 1 min. The healing ability of the composite was also demonstrated by the disappearance of microcracks after heating. In addition to the self-healing ability, the polymers and composites also exhibited shape memory property. These unique properties may provide the material multi-functional applications. Resistance heating of traditional composites and its applicability in self-healing composites is also studied to lay groundwork for a fully integrated self-healing composite.

Multiscale Modeling of Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Bednarcyk, Brett A.; Mital, Subodh K.; Pineda, Evan J.; Arnold, Steven M.

2015-01-01

Results of multiscale modeling simulations of the nonlinear response of SiC/SiC ceramic matrix composites are reported, wherein the microstructure of the ceramic matrix is captured. This micro scale architecture, which contains free Si material as well as the SiC ceramic, is responsible for residual stresses that play an important role in the subsequent thermo-mechanical behavior of the SiC/SiC composite. Using the novel Multiscale Generalized Method of Cells recursive micromechanics theory, the microstructure of the matrix, as well as the microstructure of the composite (fiber and matrix) can be captured.

Investigation of Micro-Scale Architectural Effects on Damage of Composites

NASA Technical Reports Server (NTRS)

Stier, Bertram; Bednarcyk, Brett A.; Simon, Jaan W.; Reese, Stefanie

2015-01-01

This paper presents a three-dimensional, energy based, anisotropic, stiffness reduction, progressive damage model for composite materials and composite material constituents. The model has been implemented as a user-defined constitutive model within the Abaqus finite element software package and applied to simulate the nonlinear behavior of a damaging epoxy matrix within a unidirectional composite material. Three different composite microstructures were considered as finite element repeating unit cells, with appropriate periodicity conditions applied at the boundaries. Results representing predicted transverse tensile, longitudinal shear, and transverse shear stress-strain curves are presented, along with plots of the local fields indicating the damage progression within the microstructure. It is demonstrated that the damage model functions appropriately at the matrix scale, enabling localization of the damage to simulate failure of the composite material. The influence of the repeating unit cell geometry and the effect of the directionality of the applied loading are investigated and discussed.

Oxygen Diffusion and Reaction Kinetics in Continuous Fiber Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Halbig, Michael C.; Eckel, Andrew J.; Cawley, James D.

1999-01-01

Previous stressed oxidation tests of C/SiC composites at elevated temperatures (350 C to 1500 C) and sustained stresses (69 MPa and 172 MPa) have led to the development of a finite difference cracked matrix model. The times to failure in the samples suggest oxidation occurred in two kinetic regimes defined by the rate controlling mechanisms (i.e. diffusion controlled and reaction controlled kinetics). Microstructural analysis revealed preferential oxidation along as-fabricated, matrix microcracks and also suggested two regimes of oxidation kinetics dependent on the oxidation temperature. Based on experimental results, observation, and theory, a finite difference model was developed. The model simulates the diffusion of oxygen into a matrix crack bridged by carbon fibers. The model facilitates the study of the relative importance of temperature, the reaction rate constant, and the diffusion coefficient on the overall oxidation kinetics.

Waveform Based Acoustic Emission Detection and Location of Matrix Cracking in Composites

NASA Technical Reports Server (NTRS)

Prosser, W. H.

1995-01-01

The operation of damage mechanisms in a material or structure under load produces transient acoustic waves. These acoustic waves are known as acoustic emission (AE). In composites they can be caused by a variety of sources including matrix cracking, fiber breakage, and delamination. AE signals can be detected and analyzed to determine the location of the acoustic source by triangulation. Attempts are also made to analyze the signals to determine the type and severity of the damage mechanism. AE monitoring has been widely used for both laboratory studies of materials, and for testing the integrity of structures in the field. In this work, an advanced, waveform based AE system was used in a study of transverse matrix cracking in cross-ply graphite/epoxy laminates. This AE system featured broad band, high fidelity sensors, and high capture rate digital acquisition and storage of acoustic signals. In addition, analysis techniques based on plate wave propagation models were employed. These features provided superior source location and noise rejection capabilities.

Functionalized gold nanoparticles as additive to form polymer/metal composite matrix for improved DNA sequencing by capillary electrophoresis.

PubMed

Zhou, Dan; Yang, Liping; Yang, Runmiao; Song, Weihua; Peng, Shuhua; Wang, Yanmei

2009-11-15

A new matrix additive, poly (N,N-dimethylacrylamide)-functionalized gold nanoparticle (GNP-PDMA), was prepared by "grafting-to" approach, and then incorporated into quasi-interpenetrating network (quasi-IPN) composed of linear polyacrylamide (LPA, 3.3 MDa) and PDMA to form novel polymer/metal composite sieving matrix (quasi-IPN/GNP-PDMA) for DNA sequencing by capillary electrophoresis. Without complete optimization, quasi-IPN/GNP-PDMA yielded a readlength of 801 bases at 98% accuracy in about 64 min by using the ABI 310 Genetic Analyzer at 50 degrees C and 150 V/cm. Compared with previous quasi-IPN/GNPs, quasi-IPN/GNP-PDMA can further improve DNA sequencing performances. This is because the presence of GNP-PDMA can improve the compatibility of GNPs with the whole sequencing system, enhance the entanglement degree of networks, and increase the GNP concentration in system, which consequently lead to higher restriction and stability, higher apparent molecular weight (MW), and smaller pore size of the total sieving networks. Furthermore, the composite matrix was also compared with quasi-IPN containing higher-MW LPA and commercial POP-6. The results indicate that the composite matrix is a promising one for DNA sequencing to achieve full automation due to the separation provided with high resolution, speediness, excellent reproducibility, and easy loading in the presence of GNP-PDMA.

Utilization of the Generalized Method of Cells to Analyze the Deformation Response of Laminated Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.

2012-01-01

In order to practically utilize ceramic matrix composites in aircraft engine components, robust analysis tools are required that can simulate the material response in a computationally efficient manner. The MAC/GMC software developed at NASA Glenn Research Center, based on the Generalized Method of Cells micromechanics method, has the potential to meet this need. Utilizing MAC/GMC, the effective stiffness properties, proportional limit stress and ultimate strength can be predicted based on the properties and response of the individual constituents. In this paper, the effective stiffness and strength properties for a representative laminated ceramic matrix composite with a large diameter fiber are predicted for a variety of fiber orientation angles and laminate orientations. As part of the analytical study, methods to determine the in-situ stiffness and strength properties of the constituents required to appropriately simulate the effective composite response are developed. The stiffness properties of the representative composite have been adequately predicted for all of the fiber orientations and laminate configurations examined in this study. The proportional limit stresses and strains and ultimate stresses and strains were predicted with varying levels of accuracy, depending on the laminate orientation. However, for the cases where the predictions did not have the desired level of accuracy, the specific issues related to the micromechanics theory were identified which could lead to difficulties that were encountered that could be addressed in future work.

Implementation of Laminate Theory Into Strain Rate Dependent Micromechanics Analysis of Polymer Matrix Composites

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.

2000-01-01

A research program is in progress to develop strain rate dependent deformation and failure models for the analysis of polymer matrix composites subject to impact loads. Previously, strain rate dependent inelastic constitutive equations developed to model the polymer matrix were implemented into a mechanics of materials based micromechanics method. In the current work, the computation of the effective inelastic strain in the micromechanics model was modified to fully incorporate the Poisson effect. The micromechanics equations were also combined with classical laminate theory to enable the analysis of symmetric multilayered laminates subject to in-plane loading. A quasi-incremental trapezoidal integration method was implemented to integrate the constitutive equations within the laminate theory. Verification studies were conducted using an AS4/PEEK composite using a variety of laminate configurations and strain rates. The predicted results compared well with experimentally obtained values.

Fatigue Lifetime of Ceramic Matrix Composites at Intermediate Temperature by Acoustic Emission

PubMed Central

Racle, Elie; Godin, Nathalie; Reynaud, Pascal; Fantozzi, Gilbert

2017-01-01

The fatigue behavior of a Ceramic Matrix Composite (CMC) at intermediate temperature under air is investigated. Because of the low density and the high tensile strength of CMC, they offer a good technical solution to design aeronautical structural components. The aim of the present study is to compare the behavior of this composite under static and cyclic loading. Comparison between incremental static and cyclic tests shows that cyclic loading with an amplitude higher than 30% of the ultimate tensile strength has significant effects on damage and material lifetimes. In order to evaluate the remaining lifetime, several damage indicators, mainly based on the investigation of the liberated energy, are introduced. These indicators highlight critical times or characteristic times, allowing an evaluation of the remaining lifetime. A link is established with the characteristic time around 25% of the total test duration and the beginning of the matrix cracking during cyclic fatigue. PMID:28773019

Effect of Fiber Poisson Contraction on Matrix Multicracking Evolution of Fiber-Reinforced Ceramic-Matrix Composites

NASA Astrophysics Data System (ADS)

Longbiao, Li

2015-12-01

An analytical methodology has been developed to investigate the effect of fiber Poisson contraction on matrix multicracking evolution of fiber-reinforced ceramic-matrix composites (CMCs). The modified shear-lag model incorporated with the Coulomb friction law is adopted to solve the stress distribution in the interface slip region and intact region of the damaged composite. The critical matrix strain energy criterion which presupposes the existence of an ultimate or critical strain energy limit beyond which the matrix fails has been adopted to describe matrix multicracking of CMCs. As more energy is placed into the composite, matrix fractures and the interface debonding occurs to dissipate the extra energy. The interface debonded length under the process of matrix multicracking is obtained by treating the interface debonding as a particular crack propagation problem along the fiber/matrix interface. The effects of the interfacial frictional coefficient, fiber Poisson ratio, fiber volume fraction, interface debonded energy and cycle number on the interface debonding and matrix multicracking evolution have been analyzed. The theoretical results are compared with experimental data of unidirectional SiC/CAS, SiC/CAS-II and SiC/Borosilicate composites.

A methodology to predict damage initiation, damage growth and residual strength in titanium matrix composites

NASA Technical Reports Server (NTRS)

Bakuckas, J. G., Jr.; Johnson, W. S.

1994-01-01

In this research, a methodology to predict damage initiation, damage growth, fatigue life, and residual strength in titanium matrix composites (TMC) is outlined. Emphasis was placed on micromechanics-based engineering approaches. Damage initiation was predicted using a local effective strain approach. A finite element analysis verified the prevailing assumptions made in the formulation of this model. Damage growth, namely, fiber-bridged matrix crack growth, was evaluated using a fiber bridging (FB) model which accounts for thermal residual stresses. This model combines continuum fracture mechanics and micromechanics analyses yielding stress-intensity factor solutions for fiber-bridged matrix cracks. It is assumed in the FB model that fibers in the wake of the matrix crack are idealized as a closure pressure, and an unknown constant frictional shear stress is assumed to act along the debond length of the bridging fibers. This frictional shear stress was used as a curve fitting parameter to the available experimental data. Fatigue life and post-fatigue residual strength were predicted based on the axial stress in the first intact 0 degree fiber calculated using the FB model and a three-dimensional finite element analysis.

Tribological properties of the babbit B83-based composite materials fabricated by powder metallurgy

NASA Astrophysics Data System (ADS)

Kalashnikov, I. E.; Bolotova, L. K.; Bykov, P. A.; Kobeleva, L. I.; Katin, I. V.; Mikheev, R. S.; Kobernik, N. V.

2016-07-01

Technological processes are developed to fabricate composite materials based on B83 babbit using hot pressing of a mixture of powders in the presence of a liquid phase. As a result, the structure of the matrix B83 alloy is dispersed, the morphology of intermetallic phases is changed, and reinforcing micro- and nanosized fillers are introduced and uniformly distributed in the matrix. The tribological properties of the synthesized materials are studied. The friction of the B83 babbit + 0.5 wt % MSR + 3 wt % SiC (MSR is modified schungite rock) composite material at high loads is characterized by an increase in the stability coefficient, and the wear resistance of the material increases by a factor of 1.8 as compared to the as-cast alloy at comparable friction coefficients.

Program For Analysis Of Metal-Matrix Composites

NASA Technical Reports Server (NTRS)

Murthy, P. L. N.; Mital, S. K.

1994-01-01

METCAN (METal matrix Composite ANalyzer) is computer program used to simulate computationally nonlinear behavior of high-temperature metal-matrix composite structural components in specific applications, providing comprehensive analyses of thermal and mechanical performances. Written in FORTRAN 77.

Reflexive composites: self-healing composite structures

NASA Astrophysics Data System (ADS)

Margraf, Thomas W., Jr.; Barnell, Thomas J.; Havens, Ernie; Hemmelgarn, Christopher D.

2008-03-01

Cornerstone Research Group Inc. has developed reflexive composites achieving increased vehicle survivability through integrated structural awareness and responsiveness to damage. Reflexive composites can sense damage through integrated piezoelectric sensing networks and respond to damage by heating discrete locations to activate the healable polymer matrix in areas of damage. The polymer matrix is a modified thermoset shape memory polymer that heals based on phenomena known as reptation. In theory, the reptation healing phenomena should occur in microseconds; however, during experimentation, it has been observed that to maximize healing and restore up to 85 % of mechanical properties a healing cycle of at least three minutes is required. This paper will focus on work conducted to determine the healing mechanisms at work in CRG's reflexive composites, the optimal healing cycles, and an explanation of the difference between the reptation model and actual healing times.

Structural characterization of high temperature composites

NASA Technical Reports Server (NTRS)

Mandell, J. F.; Grande, D. H.

1991-01-01

Glass, ceramic, and carbon matrix composite materials have emerged in recent years with potential properties and temperature resistance which make them attractive for high temperature applications such as gas turbine engines. At the outset of this study, only flexural tests were available to evaluate brittle matrix composites at temperatures in the 600 to 1000 C range. The results are described of an ongoing effort to develop appropriate tensile, compression, and shear test methods for high temperature use. A tensile test for unidirectional composites was developed and used to evaluate the properties and behavior of ceramic fiber reinforced glass and glass-ceramic matrix composites in air at temperatures up to 1000 C. The results indicate generally efficient fiber reinforcement and tolerance to matrix cracking similar to polymer matrix composites. Limiting properties in these materials may be an inherently very low transverse strain to failure, and high temperature embrittlement due to fiber/matrix interface oxidation.

A study of the diffusional behavior of a two-phase metal matrix composite exposed to a high temperature environment

NASA Technical Reports Server (NTRS)

Tenney, D. R.

1974-01-01

The progress of diffusion-controlled filament-matrix interaction in a metal matrix composite where the filaments and matrix comprise a two-phase binary alloy system was studied by mathematically modeling compositional changes resulting from prolonged elevated temperature exposure. The analysis treats a finite, diffusion-controlled, two-phase moving-interface problem by means of a variable-grid finite-difference technique. The Ni-W system was selected as an example system. Modeling was carried out for the 1000 to 1200 C temperature range for unidirectional composites containing from 6 to 40 volume percent tungsten filaments in a Ni matrix. The results are displayed to show both the change in filament diameter and matrix composition as a function of exposure time. Compositional profiles produced between first and second nearest neighbor filaments were calculated by superposition of finite-difference solutions of the diffusion equations.

Fabrication of Poly(ε-caprolactone) Scaffolds Reinforced with Cellulose Nanofibers, with and without the Addition of Hydroxyapatite Nanoparticles.

PubMed

Morouço, Pedro; Biscaia, Sara; Viana, Tânia; Franco, Margarida; Malça, Cândida; Mateus, Artur; Moura, Carla; Ferreira, Frederico C; Mitchell, Geoffrey; Alves, Nuno M

2016-01-01

Biomaterial properties and controlled architecture of scaffolds are essential features to provide an adequate biological and mechanical support for tissue regeneration, mimicking the ingrowth tissues. In this study, a bioextrusion system was used to produce 3D biodegradable scaffolds with controlled architecture, comprising three types of constructs: (i) poly( ε -caprolactone) (PCL) matrix as reference; (ii) PCL-based matrix reinforced with cellulose nanofibers (CNF); and (iii) PCL-based matrix reinforced with CNF and hydroxyapatite nanoparticles (HANP). The effect of the addition and/or combination of CNF and HANP into the polymeric matrix of PCL was investigated, with the effects of the biomaterial composition on the constructs (morphological, thermal, and mechanical performances) being analysed. Scaffolds were produced using a single lay-down pattern of 0/90°, with the same processing parameters among all constructs being assured. The performed morphological analyses showed a satisfactory distribution of CNF within the polymer matrix and high reliability was obtained among the produced scaffolds. Significant effects on surface wettability and thermal properties were observed, among scaffolds. Regarding the mechanical properties, higher scaffold stiffness in the reinforced scaffolds was obtained. Results from the cytotoxicity assay suggest that all the composite scaffolds presented good biocompatibility. The results of this first study on cellulose and hydroxyapatite reinforced constructs with controlled architecture clearly demonstrate the potential of these 3D composite constructs for cell cultivation with enhanced mechanical properties.

Additive Manufacturing of Reactive In Situ Zr Based Ultra-High Temperature Ceramic Composites

NASA Astrophysics Data System (ADS)

Sahasrabudhe, Himanshu; Bandyopadhyay, Amit

2016-03-01

Reactive in situ multi-material additive manufacturing of ZrB2-based ultra-high-temperature ceramics in a Zr metal matrix was demonstrated using LENS™. Sound metallurgical bonding was achieved between the Zr metal and Zr-BN composites with Ti6Al4V substrate. Though the feedstock Zr power had α phase, LENS™ processing of the Zr powder and Zr-BN premix powder mixture led to the formation of some β phase of Zr. Microstructure of the Zr-BN composite showed primary grains of zirconium diboride phase in zirconium metal matrix. The presence of ZrB2 ceramic phase was confirmed by X-ray diffraction (XRD) analysis. Hardness of pure Zr was measured as 280 ± 12 HV and, by increasing the BN content in the feedstock, the hardness was found to increase. In Zr-5%BN composite, the hardness was 421 ± 10 HV and the same for Zr-10%BN composite was 562 ± 10 HV. It is envisioned that such multi-materials additive manufacturing will enable products in the future that cannot be manufactured using traditional approaches particularly in the areas of high-temperature metal-ceramic composites with compositional and functional gradation.

Microstructure Characterization of Al-TiC Surface Composite Fabricated by Friction Stir Processing

NASA Astrophysics Data System (ADS)

Shiva, Apireddi; Cheepu, Muralimohan; Charan Kantumuchu, Venkata; Kumar, K. Ravi; Venkateswarlu, D.; Srinivas, B.; Jerome, S.

2018-03-01

Titanium carbide (TiC) is an exceedingly hard and wear refractory ceramic material. The surface properties of the material are very important and the corrosion, wear and fatigue resistance behaviour determines its ability and applications. It is necessary to modify the surface properties of the materials to enhance their performance. The present work aims on developing a new surface composite using commercially pure aluminum and TiC reinforcement powder with a significant fabrication technique called friction stir processing (FSP). The metal matrix composite of Al/TiC has been developed without any defects formation to investigate the particles distribution in the composite, microstructural changes and mechanical properties of the material. The microstructural observations exhibited that the grain refinement in the nugget compared to the base metal and FSP without TiC particles. The developed composite properties showed substantial improvement in micro-hardness, friction factor, wear resistance and microstructural characteristics in comparison to parent metal. On the other side, the ductility of the composite specimens was diminished over the substrate. The FSPed specimens were characterised using X-ray diffraction technique and revealed that the formation of AlTi compounds and the presence of Ti phases in the matrix. The microstructures of the samples illustrated the uniform distribution of particles in the newly developed metal matrix composite.

Surface characterization of LDEF carbon fiber/polymer matrix composites

NASA Technical Reports Server (NTRS)

Grammer, Holly L.; Wightman, James P.; Young, Philip R.; Slemp, Wayne S.

1995-01-01

XPS (x-ray photoelectron spectroscopy) and SEM (scanning electron microscopy) analysis of both carbon fiber/epoxy matrix and carbon fiber/polysulfone matrix composites revealed significant changes in the surface composition as a result of exposure to low-earth orbit. The carbon 1s curve fit XPS analysis in conjunction with the SEM photomicrographs revealed significant erosion of the polymer matrix resins by atomic oxygen to expose the carbon fibers of the composite samples. This erosion effect on the composites was seen after 10 months in orbit and was even more obvious after 69 months.

Fatigue Life Prediction of 2D Woven Ceramic-Matrix Composites at Room and Elevated Temperatures

NASA Astrophysics Data System (ADS)

Longbiao, Li

2017-03-01

In this paper, the fatigue life of 2D woven ceramic-matrix composites, i.e., SiC/SiC, SiC/Si-N-C, SiC/Si-B4C, and Nextel 610™/Aluminosilicate, at room and elevated temperatures has been predicted using the micromechanics approach. An effective coefficient of the fiber volume fraction along the loading direction (ECFL) was introduced to describe the fiber architecture of preforms. The Budiansky-Hutchinson-Evans shear-lag model was used to describe the microstress field of the damaged composite considering fibers failure. The statistical matrix multicracking model and fracture mechanics interface debonding criterion were used to determine the matrix crack spacing and interface debonded length. The interface shear stress and fibers strength degradation model and oxidation region propagation model have been adopted to analyze the fatigue and oxidation effects on fatigue life of the composite, which is controlled by interface frictional slip and diffusion of oxygen gas through matrix multicrackings. Under cyclic fatigue loading, the fibers broken fraction was determined by combining the interface/fiber oxidation model, interface wear model and fibers statistical failure model at elevated temperatures, based on the assumption that the fiber strength is subjected to two-parameter Weibull distribution and the load carried by broken and intact fibers satisfy the Global Load Sharing (GLS) criterion. When the broken fibers fraction approaches to the critical value, the composites fatigue fractures. The fatigue life S- N curves of 2D SiC/SiC, SiC/Si-N-C, SiC/Si-B4C, and Nextel 610™/Aluminosilicate composites at room temperature and 800, 1000 and 1200 °C in air and steam have been predicted.

Testing of self-repairing composite airplane components by use of CAI and the release of the repair chemicals from carefully inserted small tubes

NASA Astrophysics Data System (ADS)

Dry, Carolyn

2007-04-01

The research on self repair of airplane components, under an SBIR phase II with Wright Patterson Air Force Base, has investigated the attributes and best end use applications for such a technology. These attributes include issues related to manufacturability, cost, potential benefits such as weight reduction, and cost reduction. The goal of our research has been to develop self-repairing composites with unique strength for air vehicles. Our revolutionary approach involves the autonomous release of repair chemicals from within the composite matrix itself. The repair agents are contained in hollow, structural fibers that are embedded within the matrix. Under stress, the composite senses external environmental factors and reacts by releasing the repair agents from within the hollow vessels. This autonomous response occurs wherever and whenever cracking, debonding or other matrix damage transpires. Superior performance over the life of the composite is achieved through this self-repairing mechanism. The advantages to the military would be safely executed missions, fewer repairs and eventually lighter vehicles. In particular the research has addressed the issues by correlating the impact of the various factors, such as 1) delivery vessel placement, shape/size and effect on composite strength, chemicals released and their effect on the matrix, release trigger and efficacy and any impact on matrix properties 2) impact of composite processing methods that involve heat and pressure on the repair vessels. Our self repairing system can be processed at temperatures of 300-350F, repairs in less than 30 seconds and does not damage the composite by repair fiber insertion or chemical release. Scaling up and manufacture of components has revealed that anticipating potential problems allowed us to avoid those associated with processing temperatures and pressures. The presentation will focus on compression after impact testing and the placement of repair fibers/tubes into prepreg laminates.

Fabrication of borassus fruit lignocellulose fiber/PP composites and comparison with jute, sisal and coir fibers.

PubMed

Sudhakara, P; Jagadeesh, Dani; Wang, YiQi; Prasad, C Venkata; Devi, A P Kamala; Balakrishnan, G; Kim, B S; Song, J I

2013-10-15

Novel composites based on borassus fruit fine fiber (BFF) and polypropylene (PP) were fabricated with variable fiber composition (5, 10, 15 and 20 wt%) by injection molding. Maleated PP (MAPP) was also used as compatibilizer at 5 wt% for effective fiber-matrix adhesion. FTIR analysis confirms the evidence of a chemical bonding between the fiber and polymeric matrix through esterification in presence of MAPP. The tensile and flexural properties were found to increase with 15 and 10 wt% fiber loadings respectively, and decreased thereafter. Coir, jute and sisal fiber composites were also fabricated with 15 wt% fiber loading under the same conditions as used for BFF/PP composites. It was found that the mechanical properties of BFF (15 wt%)/PP composites were equivalent to jute/PP, sisal/PP and superior to coir/PP composites. Jute/PP and sisal/PP composites showed higher water absorption than BFF/PP and coir/PP composites. These results have demonstrated that the BFF/PP composites can also be an alternative material for composites applications. Copyright © 2013 Elsevier Ltd. All rights reserved.

Revealing Slip Bands In A Metal-Matrix/Fiber Composite

NASA Technical Reports Server (NTRS)

Lerch, Bradley A.

1995-01-01

Experimental procedure includes heat treatments and metallographic techniques developed to facilitate studies of deformation of metal-matrix/fiber composite under stress. Reveals slip bands, indicative of plastic flow occurring in matrix during mechanical tests of specimens of composite.

Characterizing the Properties of a Woven SiC/SiC Composite Using W-CEMCAN Computer Code

NASA Technical Reports Server (NTRS)

Murthy, Pappu L. N.; Mital, Subodh K.; DiCarlo, James A.

1999-01-01

A micromechanics based computer code to predict the thermal and mechanical properties of woven ceramic matrix composites (CMC) is developed. This computer code, W-CEMCAN (Woven CEramic Matrix Composites ANalyzer), predicts the properties of two-dimensional woven CMC at any temperature and takes into account various constituent geometries and volume fractions. This computer code is used to predict the thermal and mechanical properties of an advanced CMC composed of 0/90 five-harness (5 HS) Sylramic fiber which had been chemically vapor infiltrated (CVI) with boron nitride (BN) and SiC interphase coatings and melt-infiltrated (MI) with SiC. The predictions, based on the bulk constituent properties from the literature, are compared with measured experimental data. Based on the comparison. improved or calibrated properties for the constituent materials are then developed for use by material developers/designers. The computer code is then used to predict the properties of a composite with the same constituents but with different fiber volume fractions. The predictions are compared with measured data and a good agreement is achieved.

Influence of additional coupling agent on the mechanical properties of polyester–agave cantala roxb based composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ubaidillah, E-mail: ubaidillah@uns.ac.id; Malaysia-Japan International Institute of Technology, Universiti Teknologi Malaysia, Jalan Sultan Yahya Petra, Kuala Lumpur; Raharjo, Wijang W.

The mechanical and morphological properties of the unsaturated polyester resins (UPRs)-agave cantala roxb based composite are investigated in this paper. The cantala fiber woven in 3D angle interlock was utilized as the composite reinforcement. Surface grafting of the cantala fiber through chemical treatment was performed by introducing silane coupling agent to improving the compatibility with the polymer matrix. The fabrication of the composite specimens was conducted using vacuum bagging technique. The effect of additional coupling agent to the morphological appearance of surface fracture was observed using scanning electron microscopy. Meanwhile, the influence of additional silane to the mechanical properties wasmore » examined using tensile, bending and impact test. The photograph of surface fracture on the treated specimens showed the residual matrix left on the fibers in which the phenomenon was not found in the untreated specimens. Based on mechanical tests, the treated specimens were successfully increased their mechanical properties by 55%, 9.67%, and 92.4% for tensile strength, flexural strength, and impact strength, respectively, at 1.5% silane coupling agent.« less

Ceramic matrix and resin matrix composites: A comparison

NASA Technical Reports Server (NTRS)

Hurwitz, Frances I.

1987-01-01

The underlying theory of continuous fiber reinforcement of ceramic matrix and resin matrix composites, their fabrication, microstructure, physical and mechanical properties are contrasted. The growing use of organometallic polymers as precursors to ceramic matrices is discussed as a means of providing low temperature processing capability without the fiber degradation encountered with more conventional ceramic processing techniques. Examples of ceramic matrix composites derived from particulate-filled, high char yield polymers and silsesquioxane precursors are provided.

Ceramic matrix and resin matrix composites - A comparison

NASA Technical Reports Server (NTRS)

Hurwitz, Frances I.

1987-01-01

The underlying theory of continuous fiber reinforcement of ceramic matrix and resin matrix composites, their fabrication, microstructure, physical and mechanical properties are contrasted. The growing use of organometallic polymers as precursors to ceramic matrices is discussed as a means of providing low temperature processing capability without the fiber degradation encountered with more conventional ceramic processing techniques. Examples of ceramic matrix composites derived from particulate-filled, high char yield polymers and silsesquioxane precursors are provided.

Multiple cracking of unidirectional and cross-ply ceramic matrix composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuo, W.S.; Chou, T.W.

1995-03-01

This paper examines the multiple cracking behavior of unidirectional and cross-ply ceramic matrix composites. For unidirectional composites, a model of concentric cylinders with finite crack spacing and debonding length is introduced. Stresses in the fiber and matrix are found and then applied to predict the composite moduli. Using an energy balance method, critical stresses for matrix cracking initiation are predicted. Effects of interfacial shear stress, debonding length and bonding energy on the critical stress are studied. All the three composite systems examined show that the critical stress for the completely debonded case is lower than that for the perfectly bondedmore » case. For crossply composites, an extensive study has been made for the transverse cracking in 90{degree} plies and the matrix cracking in 0{degree} plies. One transverse cracking and four matrix cracking modes are studied, and closed-form solutions of the critical stresses are obtained. The results indicate that the case of combined matrix and transverse crackings with associated fiber/matrix interfacial sliding in the 0{degree} plies gives the lowest critical stress for matrix cracking. The theoretical predictions are compared with experimental data of SiC/CAS cross-ply composites; both results demonstrated that an increase in the transverse ply thickness reduces the critical stress for matrix cracking in the longitudinal plies. The effects of fiber volume fraction and fiber modulus on the critical stress have been quantified. Thermal residual stresses are included in the analysis.« less

Improving the interlaminar shear strength of carbon fiber-epoxy composites through carbon fiber bromination

NASA Technical Reports Server (NTRS)

Jaworske, Donald A.; Maciag, Carolyn

1987-01-01

The use of bromine to improve the interlaminar shear strength of PAN-based carbon fibers was investigated. Composite test specimens fabicated from brominated T-300 fibers and a MY720 matrix exhibited on average a 30% improvement in ILSS over their pristine counterparts. Mass, electrical resistivity, density, contact angle, and scanning Auger microscopy results suggested a mechanism in which the bromine was covalently bonded to the surface of the fiber, and this resulted in an increased van der Waal's adhesion between fiber and matrix.

Performance Enhancement Using Selective Reinforcement for Metallic Single- and Multi-Pin Loaded Holes

NASA Technical Reports Server (NTRS)

Farley, Gary L.; Seshadri, Banavara R.

2005-01-01

An analysis based investigation of aluminum with metal matrix composite selectively reinforced single- and multi-hole specimens was performed and their results compared with results from geometrically comparable non-reinforced specimens. All reinforced specimens exhibited a significant increase in performance. Performance increase of up to 170 percent was achieved. Specimen failure modes were consistent with results from reinforced polymeric matrix composite specimens. Localized reinforcement application (circular) proved as effective as a broader area (strip) reinforcement. Also, selective reinforcement is an excellent method of increasing the performance of multi-hole specimens.

Metal- matrix composite processing technologies for aircraft engine applications

NASA Astrophysics Data System (ADS)

Pank, D. R.; Jackson, J. J.

1993-06-01

Titanium metal-matrix composites (MMC) are prime candidate materials for aerospace applications be-cause of their excellent high-temperature longitudinal strength and stiffness and low density compared with nickel- and steel-base materials. This article examines the steps GE Aircraft Engines (GEAE) has taken to develop an induction plasma deposition (IPD) processing method for the fabrication of Ti6242/SiC MMC material. Information regarding process methodology, microstructures, and mechani-cal properties of consolidated MMC structures will be presented. The work presented was funded under the GE-Aircraft Engine IR & D program.

Unidirectional fibers and polyurethane elastomer matrix based composites synthesis and properties. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Chakar, A.

1984-01-01

A study of the properties and manufacturing techniques for long-fiber reinforced elastomeric composites for flexible and damping structural materials is presented. Attention is given to the usage of polyurethane in the matrix to obtain plastic elastomeric matrices and vitreous transition temperatures which vary from -80 C to 10 C, as well as assure good fiber adhesion. Various polyurethane formulations synthesized from diisocyanate prepolymers are examined in terms of mechanical and thermal properties. The principal reinforcing fiber selected is a unidirectional glass cloth.

Factors affecting miniature Izod impact strength of tungsten-fiber-metal-matrix

NASA Technical Reports Server (NTRS)

Winsa, E. A.; Petrasek, D. W.

1973-01-01

The miniature Izod and Charpy impact strengths of copper, copper-nickel, and nickel-base superalloy uniaxially reinforced with continuous tungsten fibers were studied. In most cases, impact strength was increased by increasing fiber or matrix toughness, decreasing fibermatrix reaction, increasing test temperature, hot working, or heat treating. Notch sensitivity was reduced by increasing fiber content or matrix toughness. An equation relating impact strength to fiber and matrix properties and fiber content was developed. Program results imply that tungsten alloy-fiber/superalloy matrix composites can be made with adequate impact resistance for turbine blade or vane applications.

Metal Matrix Composite LOX Turbopump Housing Via Novel Tool-Less Net-Shape Pressure Infiltration Casting Technology

NASA Technical Reports Server (NTRS)

Shah, Sandeep; Lee, Jonathan; Bhat, Biliyar; Wells, Doug; Gregg, Wayne; Marsh, Matthew; Genge, Gary; Forbes, John; Salvi, Alex; Cornie, James A.;

Fatigue Life Prediction of Fiber-Reinforced Ceramic-Matrix Composites with Different Fiber Preforms at Room and Elevated Temperatures

PubMed Central

Li, Longbiao

2016-01-01

In this paper, the fatigue life of fiber-reinforced ceramic-matrix composites (CMCs) with different fiber preforms, i.e., unidirectional, cross-ply, 2D (two dimensional), 2.5D and 3D CMCs at room and elevated temperatures in air and oxidative environments, has been predicted using the micromechanics approach. An effective coefficient of the fiber volume fraction along the loading direction (ECFL) was introduced to describe the fiber architecture of preforms. The statistical matrix multicracking model and fracture mechanics interface debonding criterion were used to determine the matrix crack spacing and interface debonded length. Under cyclic fatigue loading, the fiber broken fraction was determined by combining the interface wear model and fiber statistical failure model at room temperature, and interface/fiber oxidation model, interface wear model and fiber statistical failure model at elevated temperatures, based on the assumption that the fiber strength is subjected to two-parameter Weibull distribution and the load carried by broken and intact fibers satisfies the Global Load Sharing (GLS) criterion. When the broken fiber fraction approaches the critical value, the composites fatigue fracture. PMID:28773332

Advanced High-Temperature Engine Materials Technology Progresses

NASA Technical Reports Server (NTRS)

1995-01-01

The objective of the Advanced High Temperature Engine Materials Technology Program (HITEMP) is to generate technology for advanced materials and structural analysis that will increase fuel economy, improve reliability, extend life, and reduce operating costs for 21st century civil propulsion systems. The primary focus is on fan and compressor materials (polymer-matrix composites--PMC's), compressor and turbine materials (superalloys, and metal-matrix and intermetallic-matrix composites--MMC's and IMC's) and turbine materials (ceramic-matrix composites--CMC's). These advanced materials are being developed by in-house researchers and on grants and contracts. NASA considers this program to be a focused materials and structures research effort that builds on our base research programs and supports component-development projects. HITEMP is coordinated with the Advanced Subsonic Technology (AST) Program and the Department of Defense/NASA Integrated High-Performance Turbine Engine Technology (IHPTET) Program. Advanced materials and structures technologies from HITEMP may be used in these future applications. Recent technical accomplishments have not only improved the state-of-the-art but have wideranging applications to industry. A high-temperature thin-film strain gage was developed to measure both dynamic and static strain up to 1100 C (2000 F). The gage's unique feature is that it is minimally intrusive. This technology, which received a 1995 R&D 100 Award, has been transferred to AlliedSignal Engines, General Electric Company, and Ford Motor Company. Analytical models developed at the NASA Lewis Research Center were used to study Textron Specialty Materials' manufacturing process for titanium-matrix composite rings. Implementation of our recommendations on tooling and processing conditions resulted in the production of defect free rings. In the Lincoln Composites/AlliedSignal/Lewis cooperative program, a composite compressor case is being manufactured with a Lewis-developed matrix, VCAP. The compressor case, which will reduce weight by 30 percent and costs by 50 percent, is scheduled to be engine tested in the near future.

Simple preparation of fluorescent composite films based on cerium and europium doped LaF3 nanoparticles

NASA Astrophysics Data System (ADS)

Secco, Henrique de L.; Ferreira, Fabio F.; Péres, Laura O.

2018-03-01

The combination of materials to form hybrids with unique properties, different from those of the isolated components, is a strategy used to prepare functional materials with improved properties aiming to allow their application in specific fields. The doping of lanthanum fluoride with other rare earth elements is used to obtain luminescent particles, which may be useful to the manufacturing of electronic devices' displays and biological markers, for instance. The application of the powder of nanoparticles has limitations in some fields; to overcome this, the powder may be incorporated in a suitable polymeric matrix. In this work, lanthanum fluoride nanoparticles, undoped and doped with cerium and europium, were synthesized through the co-precipitation method in aqueous solution. Aiming the formation of solid state films, composites of nanoparticles in an elastomeric matrix, the nitrile rubber (NBR), were prepared. The flexibility and the transparency of the matrix in the regions of interest are advantages for the application of the luminescent composites. The composites were applied as films using the casting and the spin coating techniques and luminescent materials were obtained in the samples doped with europium and cerium. Scanning electron microscopy images showed an adequate dispersion of the particles in the matrix in both film formation techniques. Aggregates of the particles were detected in the samples which may affect the uniformity of the emission of the composites.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Okumus, S. Cem, E-mail: cokumus@sakarya.edu.tr; Karslioglu, Ramazan, E-mail: cokumus@sakarya.edu.tr; Akbulut, Hatem, E-mail: cokumus@sakarya.edu.tr

Aluminum-lithium based unreinforced (Al-8090) alloy and Al-8090/SiCp/17 vol.% metal matrix composite produced by extrusion after spray co-deposition. A dry ball-on disk wear test was carried out for both alloy and composite. The tests were performed against an Al{sub 2}O{sub 3} ball, 10 mm in diameter, at room temperature and in laboratory air conditions with a relative humidity of 40-60%. Sliding speed was chosen as 1.0 ms{sup −1} and normal loads of 1.0, 3.0 and 5.0 N were employed at a constant sliding distance of 1000 m. The wear damage on the specimens was evaluated via measurement of wear depth andmore » diameter. Microstructural and wear characterization was carried out via scanning electron microscopy (SEM). The results showed that wear loss of the Al-8090/SiC composite was less than that of the Al-8090 matrix alloy. Plastic deformation observed on the wear surface of the composite and the matrix alloy, and the higher the applied load the greater the plastic deformation. Scanning electron microscopy examinations of wear tracks also reveal that delamination fracture was the dominant wear mechanism during the wear progression. Friction coefficient was maximum at the low applied load in the case of the Al-8090/SiC composite while a gradual increase was observed with applied load for the matrix alloy.« less

Low-Earth orbit effects on organic composite materials flown on LDEF

NASA Technical Reports Server (NTRS)

George, Pete E.; Dursch, Harry W.

1993-01-01

Over 35 different types of organic matrix composites were flown as part of 11 different experiments onboard the NASA Long Duration Exposure Facility (LDEF) satellite. This materials and systems experiment satellite flew in low-earth orbit (LEO) for 69 months. For that period, the experiments were subjected to the LEO environment including atomic oxygen (AO), ultraviolet (UV) radiation, thermal cycling, microvacuum, meteoroid and space debris (M&D), and particle radiation. Since retrieval of the satellite in January of 1990, the principal experiment investigators have been deintegrating, examining, and testing the materials specimens flown. The most detrimental environmental effect on all organic matrix composites was material loss due to AO erosion. AO erosion of uncoated organic matrix composites (OMC) facing the satellite ram direction was responsible for significant mechanical property degradations. Also, thermal cycling-induced microcracking was observed in some nonunidirectional reinforced OMC's. Thermal cycling and outgassing caused significant but predictable dimensional changes as measured in situ on one experiment. Some metal and metal oxide-based coatings were found to be very effective at preventing AO erosion of OMC's. However, M&D impacts and coating fractures which compromised these coatings allowed AO erosion of the underlying OMC substrates. The findings for organic matrix composites flown on the LDEF are summarized and the LEO environmental factors, their effects, and the influence on space hardware design factors for LEO applications are identified.

Composition for absorbing hydrogen

DOEpatents

Heung, L.K.; Wicks, G.G.; Enz, G.L.

1995-05-02

A hydrogen absorbing composition is described. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

Composition for absorbing hydrogen

DOEpatents

Heung, Leung K.; Wicks, George G.; Enz, Glenn L.

1995-01-01

A hydrogen absorbing composition. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

Advanced Constituents and Processes for Ceramic Composite Engine Components

NASA Technical Reports Server (NTRS)

Yun, H. M.; DiCarlo, J. A.; Bhatt, R. T.

2004-01-01

The successful replacement of metal alloys by ceramic matrix composites (CMC) in hot-section engine components will depend strongly on optimizing the processes and properties of the CMC microstructural constituents so that they can synergistically provide the total CMC system with improved temperature capability and with the key properties required by the components for long-term structural service. This presentation provides the results of recent activities at NASA aimed at developing advanced silicon carbide (Sic) fiber-reinforced hybrid Sic matrix composite systems that can operate under mechanical loading and oxidizing conditions for hundreds of hours at 2400 and 2600 F, temperatures well above current metal capability. These SiC/SiC composite systems are lightweight (-30% metal density) and, in comparison to monolithic ceramics and carbon fiber-reinforced ceramic composites, are able to reliably retain their structural properties for long times under aggressive engine environments. It is shown that the improved temperature capability of the SiC/SiC systems is related first to the NASA development of the Sylramic-iBN Sic fiber, which displays high thermal stability, creep resistance, rupture resistance, and thermal conductivity, and possesses an in-situ grown BN surface layer for added environmental durability. This fiber is simply derived from Sylramic Sic fiber type that is currently produced at ATK COI Ceramics. Further capability is then derived by using chemical vapor infiltration (CVI) to form the initial portion of the hybrid Sic matrix. Because of its high creep resistance and thermal conductivity, the CVI Sic matrix is a required base constituent for all the high temperature SiC/SiC systems. By subsequently thermo- mechanical-treating the CMC preform, which consists of the S ylramic-iBN fibers and CVI Sic matrix, process-related defects in the matrix are removed, further improving matrix and CMC creep resistance and conductivity.

Chemical variations within and between the clasts, and the matrix of the Abee enstatite chondrite suggest an impact-based differentiation mechanism

NASA Astrophysics Data System (ADS)

Higgins, Michael D.; Martin, Pierre-Etienne M. C.

2018-01-01

Abee is an enstatite chondrite breccia dominantly composed of kamacite, enstatite, silica, plagioclase, troilite and niningerite. Clasts are up to 220 mm long and vary in shape from angular to rounded. Some clasts are zoned with kamacite-enriched rims that follow the edge of the clast. Spatial compositional variations were examined in a small block to find out more about the petrological processes that produced this rock, particularly the relationship between the clasts, the matrix and the cores/rims of the zoned clasts. Compositional maps produced using a focussed-beam XRF were segmented into clasts and matrix, and rims and cores where possible. Compositions of most clasts, matrix and rim/cores define a simple, linear trend on simple variation diagrams. If it is assumed that all components were derived from an original homogeneous composition then the variation can be explained either by addition of kamacite or by loss of all other phases. Within this overall compositional variation the kamacite content generally increases as follows: matrix < large homogeneous clasts ≈ zoned clast cores < small homogeneous clasts ≈ zoned clast rims. Production of diversity by addition of kamacite to clasts and rim seems to require a complex history as the source cannot have been the current matrix. It is also difficult to produce the observed chemical variations and zoning by partial melting. However, differentiation by removal of all non-metallic phases may result from repeated impacts: Shock waves would deform kamacite whilst fracturing all other phases. The broken grains would then migrate towards the surface of the clasts where they would spall off into the matrix. This process would also lead to the observed rounding of some clasts. We propose that this shock-differentiation process be called 'smithing', as it resembles the ancient process of iron refining.

Alumina Matrix Composites with Non-Oxide Nanoparticle Addition and Enhanced Functionalities

PubMed Central

Galusek, Dušan; Galusková, Dagmar

2015-01-01

The addition of SiC or TiC nanoparticles to polycrystalline alumina matrix has long been known as an efficient way of improving the mechanical properties of alumina-based ceramics, especially strength, creep, and wear resistance. Recently, new types of nano-additives, such as carbon nanotubes (CNT), carbon nanofibers (CNF), and graphene sheets have been studied in order not only to improve the mechanical properties, but also to prepare materials with added functionalities, such as thermal and electrical conductivity. This paper provides a concise review of several types of alumina-based nanocomposites, evaluating the efficiency of various preparation methods and additives in terms of their influence on the properties of composites. PMID:28347002

Micromechanical combined stress analysis: MICSTRAN, a user manual

NASA Technical Reports Server (NTRS)

Naik, R. A.

1992-01-01

Composite materials are currently being used in aerospace and other applications. The ability to tailor the composite properties by the appropriate selection of its constituents, the fiber and matrix, is a major advantage of composite materials. The Micromechanical Combined Stress Analysis (MICSTRAN) code provides the materials engineer with a user-friendly personal computer (PC) based tool to calculate overall composite properties given the constituent fiber and matrix properties. To assess the ability of the composite to carry structural loads, the materials engineer also needs to calculate the internal stresses in the composite material. MICSTRAN is a simple tool to calculate such internal stresses with a composite ply under combined thermomechanical loading. It assumes that the fibers have a circular cross-section and are arranged either in a repeating square or diamond array pattern within a ply. It uses a classical elasticity solution technique that has been demonstrated to calculate accurate stress results. Input to the program consists of transversely isotropic fiber properties and isotropic matrix properties such as moduli, Poisson's ratios, coefficients of thermal expansion, and volume fraction. Output consists of overall thermoelastic constants and stresses. Stresses can be computed under the combined action of thermal, transverse, longitudinal, transverse shear, and longitudinal shear loadings. Stress output can be requested along the fiber-matrix interface, the model boundaries, circular arcs, or at user-specified points located anywhere in the model. The MICSTRAN program is Windows compatible and takes advantage of the Microsoft Windows graphical user interface which facilitates multitasking and extends memory access far beyond the limits imposed by the DOS operating system.

Analytical Modeling of the High Strain Rate Deformation of Polymer Matrix Composites

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.; Roberts, Gary D.; Gilat, Amos

2003-01-01

The results presented here are part of an ongoing research program to develop strain rate dependent deformation and failure models for the analysis of polymer matrix composites subject to high strain rate impact loads. State variable constitutive equations originally developed for metals have been modified in order to model the nonlinear, strain rate dependent deformation of polymeric matrix materials. To account for the effects of hydrostatic stresses, which are significant in polymers, the classical 5 plasticity theory definitions of effective stress and effective plastic strain are modified by applying variations of the Drucker-Prager yield criterion. To verify the revised formulation, the shear and tensile deformation of a representative toughened epoxy is analyzed across a wide range of strain rates (from quasi-static to high strain rates) and the results are compared to experimentally obtained values. For the analyzed polymers, both the tensile and shear stress-strain curves computed using the analytical model correlate well with values obtained through experimental tests. The polymer constitutive equations are implemented within a strength of materials based micromechanics method to predict the nonlinear, strain rate dependent deformation of polymer matrix composites. In the micromechanics, the unit cell is divided up into a number of independently analyzed slices, and laminate theory is then applied to obtain the effective deformation of the unit cell. The composite mechanics are verified by analyzing the deformation of a representative polymer matrix composite (composed using the representative polymer analyzed for the correlation of the polymer constitutive equations) for several fiber orientation angles across a variety of strain rates. The computed values compare favorably to experimentally obtained results.

Mechanical and dielectric characterization of lead zirconate titanate(PZT)/polyurethane(PU) thin film composite for energy harvesting

NASA Astrophysics Data System (ADS)

Aboubakr, S.; Rguiti, M.; Hajjaji, A.; Eddiai, A.; Courtois, C.; d'Astorg, S.

2014-04-01

The Lead Zirconate titanate (PZT) ceramic is known by its piezoelectric feature, but also by its stiffness, the use of a composite based on a polyurethane (PU) matrix charged by a piezoelectric material, enable to generate a large deformation of the material, therefore harvesting more energy. This new material will provide a competitive alternative and low cost manufacturing technology of autonomous systems (smart clothes, car seat, boat sail, flag ...). A thin film of the PZT/PU composite was prepared using up to 80 vol. % of ceramic. Due to the dielectric nature of the PZT, inclusions of this one in a PU matrix raises the permittivity of the composite, on other hand this latter seems to decline at high frequencies.

Modeling of Melt-Infiltrated SiC/SiC Composite Properties

NASA Technical Reports Server (NTRS)

Mital, Subodh K.; Bednarcyk, Brett A.; Arnold, Steven M.; Lang, Jerry

2009-01-01

The elastic properties of a two-dimensional five-harness melt-infiltrated silicon carbide fiber reinforced silicon carbide matrix (MI SiC/SiC) ceramic matrix composite (CMC) were predicted using several methods. Methods used in this analysis are multiscale laminate analysis, micromechanics-based woven composite analysis, a hybrid woven composite analysis, and two- and three-dimensional finite element analyses. The elastic properties predicted are in good agreement with each other as well as with the available measured data. However, the various methods differ from each other in three key areas: (1) the fidelity provided, (2) the efforts required for input data preparation, and (3) the computational resources required. Results also indicate that efficient methods are also able to provide a reasonable estimate of local stress fields.

Development of a Cr-Based Hard Composite Processed by Spark Plasma Sintering

NASA Astrophysics Data System (ADS)

García-Junceda, A.; Sáez, I.; Deng, X. X.; Torralba, J. M.

2018-04-01

This investigation analyzes the feasibility of processing a composite material comprising WC particles randomly dispersed in a matrix in which Cr is the main metallic binder. Thus, a new composite material is processed using a commercial, economic, and easily available Cr-based alloy, assuming that there is a certain Cr solubility in the WC particles acting as reinforcement. The processing route followed includes mechanical milling of the powders and consolidation by spark plasma sintering.

Environmental durability of ceramics and ceramic composites

NASA Technical Reports Server (NTRS)

Fox, Dennis S.

1992-01-01

An account is given of the current understanding of the environmental durability of both monolithic ceramics and ceramic-matrix composites, with a view to the prospective development of methods for the characterization, prediction, and improvement of ceramics' environmental durability. Attention is given to the environmental degradation behaviors of SiC, Si3N4, Al2O3, and glass-ceramic matrix compositions. The focus of corrosion prevention in Si-based ceramics such as SiC and Si3N4 is on the high and low sulfur fuel combustion-product effects encountered in heat engine applications of these ceramics; sintering additives and raw material impurities are noted to play a decisive role in ceramics' high temperature environmental response.

Temperature distribution of thick thermoset composites

NASA Astrophysics Data System (ADS)

Guo, Zhan-Sheng; Du, Shanyi; Zhang, Boming

2004-05-01

The development of temperature distribution of thick polymeric matrix laminates during an autoclave vacuum bag process was measured and compared with numerically calculated results. The finite element formulation of the transient heat transfer problem was carried out for polymeric matrix composite materials from the heat transfer differential equations including internal heat generation produced by exothermic chemical reactions. Software based on the general finite element software package was developed for numerical simulation of the entire composite process. From the experimental and numerical results, it was found that the measured temperature profiles were in good agreement with the numerical ones, and conventional cure cycles recommended by prepreg manufacturers for thin laminates should be modified to prevent temperature overshoot.

Simulation of Low Velocity Impact Induced Inter- and Intra-Laminar Damage of Composite Beams Based on XFEM

NASA Astrophysics Data System (ADS)

Sun, Wei; Guan, Zhidong; Li, Zengshan

2017-12-01

In this paper, the Inter-Fiber Fracture (IFF) criterion of Puck failure theory based on the eXtended Finite Element Method (XFEM) was implemented in ABAQUS code to predict the intra-laminar crack initiation of unidirectional (UD) composite laminate. The transverse crack path in the matrix can be simulated accurately by the presented method. After the crack initiation, the propagation of the crack is simulated by Cohesive Zoom Model (CZM), in which the displacement discontinuities and stress concentration caused by matrix crack is introduced into the finite element (FE) model. Combined with the usage of the enriched element interface, which can be used to simulate the inter-laminar delamination crack, the Low Velocity Impact (LVI) induced damage of UD composite laminate beam with a typical stacking of composite laminates [05/903]S is studied. A complete crack initiation and propagation process was simulated and the numerical results obtained by the XFEM are consistent with the experimental results.

Experimental investigation of the ordering pathway in a Ni-33 at.%Cr alloy

DOE PAGES

Gwalani, B.; Alam, T.; Miller, C.; ...

2016-06-17

The present study involves a detailed experimental investigation of the concurrent compositional clustering and long-range ordering tendencies in a Ni-33 at.%Cr alloy, carried out by coupling synchrotron-based X-ray diffraction (XRD), transmission electron microscopy (TEM), and atom probe tomography (APT). Synchrotron-based XRD results clearly exhibited progressively increasing lattice contraction in the matrix with increasing isothermal aging time, at 475 degrees C, eventually leading to the development of long-range ordering (LRO) of the Pt2Mo-type. Detailed TEM and APT investigations revealed that this LRO in the matrix is manifested in the form of nanometer-scale ordered domains, and the spatial distribution, size, morphology andmore » compositional evolution of these domains have been carefully investigated. Here, the APT results also revealed the early stages of compositional clustering prior to the onset of long-range ordering in this alloy and such compositional clustering can potentially be correlated to the lattice contraction and previously proposed short-range ordering tendencies.« less

A Comprehensive Study of the Polypropylene Fiber Reinforced Fly Ash Based Geopolymer

PubMed Central

Ranjbar, Navid; Mehrali, Mehdi; Behnia, Arash; Javadi Pordsari, Alireza; Mehrali, Mohammad; Alengaram, U. Johnson; Jumaat, Mohd Zamin

2016-01-01

As a cementitious material, geopolymers show a high quasi-brittle behavior and a relatively low fracture energy. To overcome such a weakness, incorporation of fibers to a brittle matrix is a well-known technique to enhance the flexural properties. This study comprehensively evaluates the short and long term impacts of different volume percentages of polypropylene fiber (PPF) reinforcement on fly ash based geopolymer composites. Different characteristics of the composite were compared at fresh state by flow measurement and hardened state by variation of shrinkage over time to assess the response of composites under flexural and compressive load conditions. The fiber-matrix interface, fiber surface and toughening mechanisms were assessed using field emission scan electron microscopy (FESEM) and atomic force microscopy (AFM). The results show that incorporation of PPF up to 3 wt % into the geopolymer paste reduces the shrinkage and enhances the energy absorption of the composites. While, it might reduce the ultimate flexural and compressive strength of the material depending on fiber content. PMID:26807825

A Comprehensive Study of the Polypropylene Fiber Reinforced Fly Ash Based Geopolymer.

PubMed

Ranjbar, Navid; Mehrali, Mehdi; Behnia, Arash; Javadi Pordsari, Alireza; Mehrali, Mohammad; Alengaram, U Johnson; Jumaat, Mohd Zamin

2016-01-01

As a cementitious material, geopolymers show a high quasi-brittle behavior and a relatively low fracture energy. To overcome such a weakness, incorporation of fibers to a brittle matrix is a well-known technique to enhance the flexural properties. This study comprehensively evaluates the short and long term impacts of different volume percentages of polypropylene fiber (PPF) reinforcement on fly ash based geopolymer composites. Different characteristics of the composite were compared at fresh state by flow measurement and hardened state by variation of shrinkage over time to assess the response of composites under flexural and compressive load conditions. The fiber-matrix interface, fiber surface and toughening mechanisms were assessed using field emission scan electron microscopy (FESEM) and atomic force microscopy (AFM). The results show that incorporation of PPF up to 3 wt % into the geopolymer paste reduces the shrinkage and enhances the energy absorption of the composites. While, it might reduce the ultimate flexural and compressive strength of the material depending on fiber content.

Thermal and mechanical behavior of metal matrix and ceramic matrix composites

NASA Technical Reports Server (NTRS)

Kennedy, John M. (Editor); Moeller, Helen H. (Editor); Johnson, W. S. (Editor)

1990-01-01

The present conference discusses local stresses in metal-matrix composites (MMCs) subjected to thermal and mechanical loads, the computational simulation of high-temperature MMCs' cyclic behavior, an analysis of a ceramic-matrix composite (CMC) flexure specimen, and a plasticity analysis of fibrous composite laminates under thermomechanical loads. Also discussed are a comparison of methods for determining the fiber-matrix interface frictional stresses of CMCs, the monotonic and cyclic behavior of an SiC/calcium aluminosilicate CMC, the mechanical and thermal properties of an SiC particle-reinforced Al alloy MMC, the temperature-dependent tensile and shear response of a graphite-reinforced 6061 Al-alloy MMC, the fiber/matrix interface bonding strength of MMCs, and fatigue crack growth in an Al2O3 short fiber-reinforced Al-2Mg matrix MMC.

Insights from the Lattice-Strain Evolution on Deformation Mechanisms in Metallic-Glass-Matrix Composites

DOE PAGES

Jia, Haoling; Zheng, Lili; Li, Weidong; ...

2015-02-18

In this paper, in situ high-energy synchrotron X-ray diffraction experiments and micromechanics-based finite element simulations have been conducted to examine the lattice-strain evolution in metallic-glass-matrix composites (MGMCs) with dendritic crystalline phases dispersed in the metallic-glass matrix. Significant plastic deformation can be observed prior to failure from the macroscopic stress–strain curves in these MGMCs. The entire lattice-strain evolution curves can be divided into elastic–elastic (denoting deformation behavior of matrix and inclusion, respectively), elastic–plastic, and plastic–plastic stages. Characteristics of these three stages are governed by the constitutive laws of the two phases (modeled by free-volume theory and crystal plasticity) and geometric informationmore » (crystalline phase morphology and distribution). The load-partitioning mechanisms have been revealed among various crystalline orientations and between the two phases, as determined by slip strain fields in crystalline phase and by strain localizations in matrix. Finally, implications on ductility enhancement of MGMCs are also discussed.« less

Effect of Magnetic Inclusions on the Effective Magnetostriction of Bulk Superconductors

NASA Astrophysics Data System (ADS)

Zhao, Yufeng; Pan, Baocai; Liu, Zhiguo

2018-07-01

A simple model is presented based on the Kim-Anderson model to further investigate the dependence of the effective magnetostriction of magnetic inclusion-superconducting matrix system on both the elastic and magnetic parameters including the elastic modulus, permeability, and volume fraction. The effect of the permeability on the magnetostriction is also obtained by implementing the continuity conditions of displacement and strain at the interface between the inclusion and the matrix through the magnetostriction loop. The results indicate that a stiffer inclusion can decrease the effective magnetostriction no matter whether the inclusion is magnetic or not and a larger effective magnetostriction can be obtained by choosing the matrix with a higher permeability, which gives an explanation about why the composite made from a matrix with a high permeability but a negligibly small magnetostriction yields unexpectedly low magnetostriction. Of particular interest is that in a certain range the effective magnetostriction of composites can be enhanced until it is saturated by increasing the permeability of matrix.

Boron nitride composites

DOEpatents

Kuntz, Joshua D.; Ellsworth, German F.; Swenson, Fritz J.; Allen, Patrick G.

2017-02-21

According to one embodiment, a composite product includes: a matrix material including hexagonal boron nitride and one or more borate binders; and a plurality of cubic boron nitride particles dispersed in the matrix material. According to another embodiment, a composite product includes: a matrix material including hexagonal boron nitride and amorphous boron nitride; and a plurality of cubic boron nitride particles dispersed in the matrix material.

Catalytic transformation of persistent contaminants using a new composite material based on nanosized zero-valent iron.

PubMed

Dror, Ishai; Jacov, Osnat Merom; Cortis, Andrea; Berkowitz, Brian

2012-07-25

A new composite material based on deposition of nanosized zerovalent iron (nZVI) particles and cyanocobalamine (vitamin B12) on a diatomite matrix is presented, for catalytic transformation of organic contaminants in water. Cyanocobalamine is known to be an effective electron mediator, having strong synergistic effects with nZVI for reductive dehalogenation reactions. This composite material also improves the reducing capacity of nZVI by preventing agglomeration of iron nanoparticles, thus increasing their active surface area. The porous structure of the diatomite matrix allows high hydraulic conductivity, which favors channeling of contaminated water to the reactive surface of the composite material resulting in faster rates of remediation. The composite material rapidly degrades or transforms completely a large spectrum of water contaminants, including halogenated solvents like TCE, PCE, and cis-DCE, pesticides like alachlor, atrazine and bromacyl, and common ions like nitrate, within minutes to hours. A field experiment where contaminated groundwater containing a mixture of industrial and agricultural persistent pollutants was conducted together with a set of laboratory experiments using individual contaminant solutions to analyze chemical transformations under controlled conditions.

Analytical Modelling of Transverse Matrix Cracking of [plus or minus Theta/90(sub n)](sub s) Composite Laminates Under Multiaxial Loading

NASA Technical Reports Server (NTRS)

Mayugo, J A.; Camanho, P. P.; Maimi, P.; Davila, C. G.

2010-01-01

An analytical model based on the analysis of a cracked unit cell of a composite laminate subjected to multiaxial loads is proposed to predict the onset and accumulation of transverse matrix cracks in the 90(sub n) plies of uniformly stressed [plus or minus Theta/90(sub n)](sub s) laminates. The model predicts the effect of matrix cracks on the stiffness of the laminate, as well as the ultimate failure of the laminate, and it accounts for the effect of the ply thickness on the ply strength. Several examples describing the predictions of laminate response, from damage onset up to final failure under both uniaxial and multiaxial loads, are presented.

In-situ deformation studies of an aluminum metal-matrix composite in a scanning electron microscope

NASA Technical Reports Server (NTRS)

Manoharan, M.; Lewandowski, J. J.

1989-01-01

Tensile specimens made of a metal-matrix composite (cast and extruded aluminum alloy-based matrix reinforced with Al2O3 particulate) were tested in situ in a scanning electron microscope equipped with a deformation stage, to directly monitor the crack propagation phenomenon. The in situ SEM observations revealed the presence of microcracks both ahead of and near the crack-tip region. The microcracks were primarily associated with cracks in the alumina particles. The results suggest that a region of intense deformation exists ahead of the crack and corresponds to the region of microcracking. As the crack progresses, a region of plastically deformed material and associated microcracks remains in the wake of the crack.

A Large-scale Finite Element Model on Micromechanical Damage and Failure of Carbon Fiber/Epoxy Composites Including Thermal Residual Stress

NASA Astrophysics Data System (ADS)

Liu, P. F.; Li, X. K.

2018-06-01

The purpose of this paper is to study micromechanical progressive failure properties of carbon fiber/epoxy composites with thermal residual stress by finite element analysis (FEA). Composite microstructures with hexagonal fiber distribution are used for the representative volume element (RVE), where an initial fiber breakage is assumed. Fiber breakage with random fiber strength is predicted using Monte Carlo simulation, progressive matrix damage is predicted by proposing a continuum damage mechanics model and interface failure is simulated using Xu and Needleman's cohesive model. Temperature dependent thermal expansion coefficients for epoxy matrix are used. FEA by developing numerical codes using ANSYS finite element software is divided into two steps: 1. Thermal residual stresses due to mismatch between fiber and matrix are calculated; 2. Longitudinal tensile load is further exerted on the RVE to perform progressive failure analysis of carbon fiber/epoxy composites. Numerical convergence is solved by introducing the viscous damping effect properly. The extended Mori-Tanaka method that considers interface debonding is used to get homogenized mechanical responses of composites. Three main results by FEA are obtained: 1. the real-time matrix cracking, fiber breakage and interface debonding with increasing tensile strain is simulated. 2. the stress concentration coefficients on neighbouring fibers near the initial broken fiber and the axial fiber stress distribution along the broken fiber are predicted, compared with the results using the global and local load-sharing models based on the shear-lag theory. 3. the tensile strength of composite by FEA is compared with those by the shear-lag theory and experiments. Finally, the tensile stress-strain curve of composites by FEA is applied to the progressive failure analysis of composite pressure vessel.

A Large-scale Finite Element Model on Micromechanical Damage and Failure of Carbon Fiber/Epoxy Composites Including Thermal Residual Stress

NASA Astrophysics Data System (ADS)

Liu, P. F.; Li, X. K.

2017-09-01

The purpose of this paper is to study micromechanical progressive failure properties of carbon fiber/epoxy composites with thermal residual stress by finite element analysis (FEA). Composite microstructures with hexagonal fiber distribution are used for the representative volume element (RVE), where an initial fiber breakage is assumed. Fiber breakage with random fiber strength is predicted using Monte Carlo simulation, progressive matrix damage is predicted by proposing a continuum damage mechanics model and interface failure is simulated using Xu and Needleman's cohesive model. Temperature dependent thermal expansion coefficients for epoxy matrix are used. FEA by developing numerical codes using ANSYS finite element software is divided into two steps: 1. Thermal residual stresses due to mismatch between fiber and matrix are calculated; 2. Longitudinal tensile load is further exerted on the RVE to perform progressive failure analysis of carbon fiber/epoxy composites. Numerical convergence is solved by introducing the viscous damping effect properly. The extended Mori-Tanaka method that considers interface debonding is used to get homogenized mechanical responses of composites. Three main results by FEA are obtained: 1. the real-time matrix cracking, fiber breakage and interface debonding with increasing tensile strain is simulated. 2. the stress concentration coefficients on neighbouring fibers near the initial broken fiber and the axial fiber stress distribution along the broken fiber are predicted, compared with the results using the global and local load-sharing models based on the shear-lag theory. 3. the tensile strength of composite by FEA is compared with those by the shear-lag theory and experiments. Finally, the tensile stress-strain curve of composites by FEA is applied to the progressive failure analysis of composite pressure vessel.

Continuous fiber ceramic matrix composites for heat engine components

NASA Technical Reports Server (NTRS)

Tripp, David E.

1988-01-01

High strength at elevated temperatures, low density, resistance to wear, and abundance of nonstrategic raw materials make structural ceramics attractive for advanced heat engine applications. Unfortunately, ceramics have a low fracture toughness and fail catastrophically because of overload, impact, and contact stresses. Ceramic matrix composites provide the means to achieve improved fracture toughness while retaining desirable characteristics, such as high strength and low density. Materials scientists and engineers are trying to develop the ideal fibers and matrices to achieve the optimum ceramic matrix composite properties. A need exists for the development of failure models for the design of ceramic matrix composite heat engine components. Phenomenological failure models are currently the most frequently used in industry, but they are deterministic and do not adequately describe ceramic matrix composite behavior. Semi-empirical models were proposed, which relate the failure of notched composite laminates to the stress a characteristic distance away from the notch. Shear lag models describe composite failure modes at the micromechanics level. The enhanced matrix cracking stress occurs at the same applied stress level predicted by the two models of steady state cracking. Finally, statistical models take into consideration the distribution in composite failure strength. The intent is to develop these models into computer algorithms for the failure analysis of ceramic matrix composites under monotonically increasing loads. The algorithms will be included in a postprocessor to general purpose finite element programs.

Coating effects on thermal properties of carbon carbon and carbon silicon carbide composites for space thermal protection systems

NASA Astrophysics Data System (ADS)

Albano, M.; Morles, R. B.; Cioeta, F.; Marchetti, M.

2014-06-01

Many are the materials for hot structures, but the most promising one are the carbon based composites nowadays. This is because they have good characteristics with a high stability at high temperatures, preserving their mechanical properties. Unfortunately, carbon reacts rapidly with oxygen and the composites are subjected to oxidation degradation. From this point of view CC has to be modified in order to improve its thermal and oxidative resistance. The most common solutions are the use of silicon carbide into the carbon composites matrix (SiC composites) to make the thermal properties increase and the use of coating on the surface in order to protect the composite from the space plasma effects. Here is presented an experimental study on coating effects on these composites. Thermal properties of coated and non coated materials have been studied and the thermal impact on the matrix and surface degradation is analyzed by a SEM analysis.

Electrically and Thermally Conductive Carbon Fibre Fabric Reinforced Polymer Composites Based on Nanocarbons and an In-situ Polymerizable Cyclic Oligoester.

PubMed

Jang, Ji-Un; Park, Hyeong Cheol; Lee, Hun Su; Khil, Myung-Seob; Kim, Seong Yun

2018-05-16

There is growing interest in carbon fibre fabric reinforced polymer (CFRP) composites based on a thermoplastic matrix, which is easy to rapidly produce, repair or recycle. To expand the applications of thermoplastic CFRP composites, we propose a process for fabricating conductive CFRP composites with improved electrical and thermal conductivities using an in-situ polymerizable and thermoplastic cyclic butylene terephthalate oligomer matrix, which can induce good impregnation of carbon fibres and a high dispersion of nanocarbon fillers. Under optimal processing conditions, the surface resistivity below the order of 10 +10 Ω/sq, which can enable electrostatic powder painting application for automotive outer panels, can be induced with a low nanofiller content of 1 wt%. Furthermore, CFRP composites containing 20 wt% graphene nanoplatelets (GNPs) were found to exhibit an excellent thermal conductivity of 13.7 W/m·K. Incorporating multi-walled carbon nanotubes into CFRP composites is more advantageous for improving electrical conductivity, whereas incorporating GNPs is more beneficial for enhancing thermal conductivity. It is possible to fabricate the developed thermoplastic CFRP composites within 2 min. The proposed composites have sufficient potential for use in automotive outer panels, engine blocks and other mechanical components that require conductive characteristics.

Spectroscopic studies of clusterization of methanol molecules isolated in a nitrogen matrix

NASA Astrophysics Data System (ADS)

Vaskivskyi, Ye.; Doroshenko, I.; Chernolevska, Ye.; Pogorelov, V.; Pitsevich, G.

2017-12-01

IR absorption spectra of methanol isolated in a nitrogen matrix are recorded at temperatures ranging from 9 to 34 K. The changes in the spectra with increasing matrix temperature are analyzed. Based on quantum-chemical calculations of the geometric and spectral parameters of different methanol clusters, the observed absorption bands are identified. The cluster composition of the sample is determined at each temperature. It is shown that as the matrix is heated there is a redistribution among the different cluster structures in the sample, from smaller to larger clusters.

Microscopic Scale Simulation of the Ablation of Fibrous Materials

NASA Technical Reports Server (NTRS)

Lachaud, Jean Romain; Mansour, Nagi N.

2010-01-01

Ablation by oxidation of carbon-fiber preforms impregnated in carbonized phenolic matrix is modeled at microscopic scale. Direct numerical simulations show that the carbonized phenolic matrix ablates in volume leaving the carbon fibers exposed. This is due to the fact that the reactivity of carbonized phenolic is higher than the reactivity of carbon fibers. After the matrix is depleted, the fibers ablate showing progressive reduction of their diameter. The overall material recession occurs when the fibers are consumed. Two materials with the same carbon-fiber preform, density and chemical composition, but with different matrix distributions are studied. These studies show that at moderate temperatures (< 1000 K) the microstructure of the material influences its recession rate; a fact that is not captured by current models that are based on chemical composition only. Surprisingly, the response of these impregnated-fiber materials is weakly dependent on the microstructure at very high temperatures (e.g., Stardust peak heating conditions: 3360K).

Influence of the intramedullary nail preparation method on nail's mechanical properties and degradation rate.

PubMed

Morawska-Chochół, Anna; Chłopek, Jan; Szaraniec, Barbara; Domalik-Pyzik, Patrycja; Balacha, Ewa; Boguń, Maciej; Kucharski, Rafael

2015-06-01

When it comes to the treatment of long bone fractures, scientists are still investigating new materials for intramedullary nails and different manufacturing methods. Some of the most promising materials used in the field are resorbable polymers and their composites, especially since there is a wide range of potential manufacturing and processing methods. The aim of this work was to select the best manufacturing method and technological parameters to obtain multiphase, and multifunctional, biodegradable intramedullary nails. All composites were based on a poly(l-lactide) matrix. Either magnesium alloy wires or carbon and alginate fibres were introduced in order to reinforce the nails. The polylactide matrix was also modified with tricalcium phosphate and gentamicin sulfate. The composite nails were manufactured using three different methods: forming from solution, injection moulding and hot pressing. The effect of each method of manufacturing on mechanical properties and degradation rate of the nails was evaluated. The study showed that injection moulding provides higher uniformity and homogeneity of the particle-modified polylactide matrix, whereas hot pressing favours applying higher volume fractions of fibres and their better impregnation with the polymer matrix. Thus, it was concluded that the fabrication method should be individually selected dependently on the nail's desired phase composition. Copyright © 2015 Elsevier B.V. All rights reserved.

Effect of TiC addition on fracture toughness of Al6061 alloy

NASA Astrophysics Data System (ADS)

Raviraj, M. S.; Sharanprabhu, C. M.; Mohankumar, G. C.

2018-04-01

Al 6061 matrix was reinforced with different proportions of TiC particles such as 3wt%, 5wt% and 7wt% and the effect on fracture toughness was studied. Al-TiC metal matrix composites were produced by stir casting method to ensure uniform distribution of the TiC particulates in the Al matrix. LEFM (Linear Elastic Fracture Mechanics) has been used to characterize the fracture toughness using various specimen geometries. The compact tension (CT) specimens with straight through notch were machined as per ASTM E399 specifications. All the specimens were machined to have constant a/W=0.5 and B/W was varied from 0.2 to 0.7. A sharp crack initiation was done at the end of notch by fatigue loading using servo-hydraulic controlled testing machine. Load v/s crack mouth opening displacement (CMOD) data was plotted and stress intensity factor, KQ determined. Critical stress intensity factor KIC was obtained by plotting KQ v/s thickness of specimen data. The fracture toughness of the composites varied between 16-19 MPa√m as compared to 23MPa√m for base alloy Al6061. Composites with 3wt% and 7wt% TiC showed better fracture toughness than 5wt% TiC reinforced Al metal matrix composites.

Characterization of SiC Fiber (SCS-6) Reinforced-Reaction-Formed Silicon Carbide Matrix Composites

NASA Technical Reports Server (NTRS)

Singh, M.; Dickerson, R. M.

1996-01-01

Silicon carbide fiber (SCS-6) reinforced-reaction-formed silicon carbide matrix composites were fabricated using a reaction-forming process. Silicon-2 at.% niobium alloy was used as an infiltrant instead of pure silicon to reduce the amount of free silicon in the matrix after reaction forming. The matrix primarily consists of silicon carbide with a bimodal grain size distribution. Minority phases dispersed within the matrix are niobium disilicide (NbSi2), carbon, and silicon. Fiber pushout tests on these composites determined a debond stress of approximately 67 MPa and a frictional stress of approximately 60 MPa. A typical four-point flexural strength of the composite is 297 MPa (43.1 KSi). This composite shows tough behavior through fiber pullout.

A review of failure models for unidirectional ceramic matrix composites under monotonic loads

NASA Technical Reports Server (NTRS)

Tripp, David E.; Hemann, John H.; Gyekenyesi, John P.

1989-01-01

Ceramic matrix composites offer significant potential for improving the performance of turbine engines. In order to achieve their potential, however, improvements in design methodology are needed. In the past most components using structural ceramic matrix composites were designed by trial and error since the emphasis of feasibility demonstration minimized the development of mathematical models. To understand the key parameters controlling response and the mechanics of failure, the development of structural failure models is required. A review of short term failure models with potential for ceramic matrix composite laminates under monotonic loads is presented. Phenomenological, semi-empirical, shear-lag, fracture mechanics, damage mechanics, and statistical models for the fast fracture analysis of continuous fiber unidirectional ceramic matrix composites under monotonic loads are surveyed.

Inelastic deformation of metal matrix composites

NASA Technical Reports Server (NTRS)

Lissenden, C. J.; Herakovich, C. T.; Pindera, M-J.

1993-01-01

A theoretical model capable of predicting the thermomechanical response of continuously reinforced metal matrix composite laminates subjected to multiaxial loading was developed. A micromechanical model is used in conjunction with nonlinear lamination theory to determine inelastic laminae response. Matrix viscoplasticity, residual stresses, and damage to the fiber/matrix interfacial zone are explicitly included in the model. The representative cell of the micromechanical model is considered to be in a state of generalized plane strain, enabling a quasi two-dimensional analysis to be performed. Constant strain finite elements are formulated with elastic-viscoplastic constitutive equations. Interfacial debonding is incorporated into the model through interface elements based on the interfacial debonding theory originally presented by Needleman, and modified by Tvergaard. Nonlinear interfacial constitutive equations relate interfacial tractions to displacement discontinuities at the interface. Theoretical predictions are compared with the results of an experimental program conducted on silicon carbide/titanium (SiC/Ti) unidirectional, (O4), and angle-ply, (+34)(sub s), tubular specimens. Multiaxial loading included increments of axial tension, compression, torque, and internal pressure. Loadings were chosen in an effort to distinguish inelastic deformation due to damage from matrix plasticity and separate time-dependent effects from time-independent effects. Results show that fiber/matrix debonding is nonuniform throughout the composite and is a major factor in the effective response. Also, significant creep behavior occurs at relatively low applied stress levels at room temperature.

Polylactic acid composites incorporating casein functionalized cellulose nanowhiskers

PubMed Central

2013-01-01

Background Polylactic acid (PLA) is considered to be a sustainable alternative to petroleum-based polymers for many applications. Using cellulose fiber to reinforce PLA is of great interest recently due to its complete biodegradability and potential improvement of the mechanical performance. However, the dispersion of hydrophilic cellulose fibers in the hydrophobic polymer matrix is usually poor without using hazardous surfactants. The goal of this study was to develop homogenously dispersed cellulose nanowhisker (CNW) reinforced PLA composites using whole milk casein protein, which is an environmentally compatible dispersant. Results In this study, whole milk casein was chosen as a dispersant in the PLA-CNW system because of its potential to interact with the PLA matrix and cellulose. The affinity of casein to PLA was studied by surface plasmon resonance (SPR) imaging. CNWs were functionalized with casein and used as reinforcements to make PLA composites. Fluorescent staining of CNWs in the PLA matrix was implemented as a novel and simple way to analyze the dispersion of the reinforcements. The dispersion of CNWs in PLA was improved when casein was present. The mechanical properties of the composites were studied experimentally. Compared to pure PLA, the PLA composites had higher Young’s modulus. Casein (CS) functionalized CNW reinforced PLA (PLA-CS-CNW) at 2 wt% filler content maintained higher strain at break compared to normal CNW reinforced PLA (PLA-CNW). The Young’s modulus of PLA-CS-CNW composites was also higher than that of PLA-CNW composites at higher filler content. However, all composites exhibited lower strain at break and tensile strength at high filler content. Conclusions The presence of whole milk casein improved the dispersion of CNWs in the PLA matrix. The improved dispersion of CNWs provided higher modulus of the PLA composites at higher reinforcement loading and maintained the strain and stress at break of the composites at relatively low reinforcement loading. The affinity of the dispersant to PLA is important for the ultimate strength and stiffness of the composites. PMID:24341897

Symposium Review: Metal and Polymer Matrix Composites at MS&T 2013

NASA Astrophysics Data System (ADS)

Gupta, Nikhil; Paramsothy, Muralidharan

2014-06-01

This article reflects on the presentations made during the Metal and Polymer Matrix Composites symposium at Materials Science and Technology 2013 (MS&T'13) held in Montreal (Quebec, Canada) from October 27 to 31. The symposium had three sessions on metal matrix composites and one session on polymer matrix composites containing a total of 23 presentations. While the abstracts and full-text papers are available through databases, the discussion that took place during the symposium is often not captured in writing and gets immediately lost. We have tried to recap some of the discussion in this article and hope that it will supplement the information present in the proceedings. The strong themes in the symposium were porous composites, aluminum matrix composites, and nanocomposites. The development of processing methods was also of interest to the speakers and attendees.

Robust Joining and Integration Technologies for Advanced Metallic, Ceramic, and Composite Systems

NASA Technical Reports Server (NTRS)

Singh, M.; Shpargel, Tarah; Morscher, Gregory N.; Halbig, Michael H.; Asthana, Rajiv

2006-01-01

Robust integration and assembly technologies are critical for the successful implementation of advanced metallic, ceramic, carbon-carbon, and ceramic matrix composite components in a wide variety of aerospace, space exploration, and ground based systems. Typically, the operating temperature of these components varies from few hundred to few thousand Kelvin with different working times (few minutes to years). The wide ranging system performance requirements necessitate the use of different integration technologies which includes adhesive bonding, low temperature soldering, active metal brazing, diffusion bonding, ARCJoinT, and ultra high temperature joining technologies. In this presentation, a number of joining examples and test results will be provided related to the adhesive bonding and active metal brazing of titanium to C/C composites, diffusion bonding of silicon carbide to silicon carbide using titanium interlayer, titanium and hastelloy brazing to silicon carbide matrix composites, and ARCJoinT joining of SiC ceramics and SiC matrix composites. Various issues in the joining of metal-ceramic systems including thermal expansion mismatch and resulting residual stresses generated during joining will be discussed. In addition, joint design and testing issues for a wide variety of joints will be presented.

Implementation of Improved Transverse Shear Calculations and Higher Order Laminate Theory Into Strain Rate Dependent Analyses of Polymer Matrix Composites

NASA Technical Reports Server (NTRS)

Zhu, Lin-Fa; Kim, Soo; Chattopadhyay, Aditi; Goldberg, Robert K.

2004-01-01

A numerical procedure has been developed to investigate the nonlinear and strain rate dependent deformation response of polymer matrix composite laminated plates under high strain rate impact loadings. A recently developed strength of materials based micromechanics model, incorporating a set of nonlinear, strain rate dependent constitutive equations for the polymer matrix, is extended to account for the transverse shear effects during impact. Four different assumptions of transverse shear deformation are investigated in order to improve the developed strain rate dependent micromechanics model. The validities of these assumptions are investigated using numerical and theoretical approaches. A method to determine through the thickness strain and transverse Poisson's ratio of the composite is developed. The revised micromechanics model is then implemented into a higher order laminated plate theory which is modified to include the effects of inelastic strains. Parametric studies are conducted to investigate the mechanical response of composite plates under high strain rate loadings. Results show the transverse shear stresses cannot be neglected in the impact problem. A significant level of strain rate dependency and material nonlinearity is found in the deformation response of representative composite specimens.

Structural Polymer-Based Carbon Nanotube Composite Fibers: Understanding the Processing–Structure–Performance Relationship

PubMed Central

Song, Kenan; Zhang, Yiying; Meng, Jiangsha; Green, Emily C.; Tajaddod, Navid; Li, Heng; Minus, Marilyn L.

2013-01-01

Among the many potential applications of carbon nanotubes (CNT), its usage to strengthen polymers has been paid considerable attention due to the exceptional stiffness, excellent strength, and the low density of CNT. This has provided numerous opportunities for the invention of new material systems for applications requiring high strength and high modulus. Precise control over processing factors, including preserving intact CNT structure, uniform dispersion of CNT within the polymer matrix, effective filler–matrix interfacial interactions, and alignment/orientation of polymer chains/CNT, contribute to the composite fibers’ superior properties. For this reason, fabrication methods play an important role in determining the composite fibers’ microstructure and ultimate mechanical behavior. The current state-of-the-art polymer/CNT high-performance composite fibers, especially in regards to processing–structure–performance, are reviewed in this contribution. Future needs for material by design approaches for processing these nano-composite systems are also discussed. PMID:28809290

Prepreg and Melt Infiltration Technology Developed for Affordable, Robust Manufacturing of Ceramic Matrix Composites

NASA Technical Reports Server (NTRS)

Singh, Mrityunjay; Petko, Jeannie F.

2004-01-01

Affordable fiber-reinforced ceramic matrix composites with multifunctional properties are critically needed for high-temperature aerospace and space transportation applications. These materials have various applications in advanced high-efficiency and high-performance engines, airframe and propulsion components for next-generation launch vehicles, and components for land-based systems. A number of these applications require materials with specific functional characteristics: for example, thick component, hybrid layups for environmental durability and stress management, and self-healing and smart composite matrices. At present, with limited success and very high cost, traditional composite fabrication technologies have been utilized to manufacture some large, complex-shape components of these materials. However, many challenges still remain in developing affordable, robust, and flexible manufacturing technologies for large, complex-shape components with multifunctional properties. The prepreg and melt infiltration (PREMI) technology provides an affordable and robust manufacturing route for low-cost, large-scale production of multifunctional ceramic composite components.

Microstructure and Interfacial Shear Strength in W/(Zr55Cu30Al10Ni5)100- x Nb x Composites

NASA Astrophysics Data System (ADS)

Mahmoodan, M.; Gholamipour, R.; Mirdamadi, Sh.; Nategh, S.

2017-11-01

In the present study, (Zr55Cu30Al10Ni5)100- x Nb( x=0,1,2,3) bulk metallic glass matrix/tungsten wire composites were fabricated by a gas pressure infiltration process at temperature 950 °C for 5 min. Microstructural studies and mechanical behaviors of the materials have been investigated by scanning electron microscopy, transmission electron microscopy and pullout tests. The mechanical results showed that the interface shear strength in the composite sample with X = 2 increased more than twice compared to the composite sample with X = 0. Based on the microstructural results, the addition of two atomic percent Nb in the matrix composite causes an increase in the diffusion band thickness during the melt infiltration and change in the interface fracture mode as a result of pullout test.

Progressive fracture of polymer matrix composite structures: A new approach

NASA Technical Reports Server (NTRS)

Chamis, C. C.; Murthy, P. L. N.; Minnetyan, L.

1992-01-01

A new approach independent of stress intensity factors and fracture toughness parameters has been developed and is described for the computational simulation of progressive fracture of polymer matrix composite structures. The damage stages are quantified based on physics via composite mechanics while the degradation of the structural behavior is quantified via the finite element method. The approach account for all types of composite behavior, structures, load conditions, and fracture processes starting from damage initiation, to unstable propagation and to global structural collapse. Results of structural fracture in composite beams, panels, plates, and shells are presented to demonstrate the effectiveness and versatility of this new approach. Parameters and guidelines are identified which can be used as criteria for structural fracture, inspection intervals, and retirement for cause. Generalization to structures made of monolithic metallic materials are outlined and lessons learned in undertaking the development of new approaches, in general, are summarized.

Thermal expansion of selected graphite reinforced polyimide-, epoxy-, and glass-matrix composite

NASA Technical Reports Server (NTRS)

Tompkins, S. S.

1985-01-01

The thermal expansion of three epoxy-matrix composites, a polyimide-matrix composite and a borosilicate glass-matrix composite, each reinforced with continuous carbon fibers, has been measured and compared. The expansion of a composite with a rubber toughened epoxy-matrix and P75S carbon fibers was very different from the expansion of two different single phase epoxy-matrix composites with P75S fibers although all three had the same stacking sequence. Reasonable agreement was obtained between measured thermal-expansion data and results from classical laminate theory. The thermal expansion of a material may change markedly as a result of thermal cycling. Microdamage, induced by 250 cycles between -156 C and 121 C in the graphite/polyimide laminate, caused a 53 percent decrease in the coefficient of thermal expansion. The thermal expansion of the graphite/glass laminate was not changed by 100 thermal cycles from -129 C to 38 C; however, a residual strain of about 10 x 10 to the minus 6 power was measured for the laminate tested.

Modeling the Mechanical Behavior of Ceramic Matrix Composite Materials

NASA Technical Reports Server (NTRS)

Jordan, William

1998-01-01

Ceramic matrix composites are ceramic materials, such as SiC, that have been reinforced by high strength fibers, such as carbon. Designers are interested in using ceramic matrix composites because they have the capability of withstanding significant loads while at relatively high temperatures (in excess of 1,000 C). Ceramic matrix composites retain the ceramic materials ability to withstand high temperatures, but also possess a much greater ductility and toughness. Their high strength and medium toughness is what makes them of so much interest to the aerospace community. This work concentrated on two different tasks. The first task was to do an extensive literature search into the mechanical behavior of ceramic matrix composite materials. This report contains the results of this task. The second task was to use this understanding to help interpret the ceramic matrix composite mechanical test results that had already been obtained by NASA. Since the specific details of these test results are subject to the International Traffic in Arms Regulations (ITAR), they are reported in a separate document (Jordan, 1997).

Parameters Identification of Interface Friction Model for Ceramic Matrix Composites Based on Stress-Strain Response

NASA Astrophysics Data System (ADS)

Han, Xiao; Gao, Xiguang; Song, Yingdong

2017-10-01

An approach to identify parameters of interface friction model for Ceramic Matrix composites based on stress-strain response was developed. The stress distribution of fibers in the interface slip region and intact region of the damaged composite was determined by adopting the interface friction model. The relation between maximum strain, secant moduli of hysteresis loop and interface shear stress, interface de-bonding stress was established respectively with the method of symbolic-graphic combination. By comparing the experimental strain, secant moduli of hysteresis loop with computation values, the interface shear stress and interface de-bonding stress corresponding to first cycle were identified. Substituting the identification of parameters into interface friction model, the stress-strain curves were predicted and the predicted results fit experiments well. Besides, the influence of number of data points on identifying the value of interface parameters was discussed. And the approach was compared with the method based on the area of hysteresis loop.

Fracture surface analysis in composite and titanium bonding

NASA Technical Reports Server (NTRS)

Devilbiss, T. A.; Wightman, J. P.

1985-01-01

To understand the mechanical properties of fiber-reinforced composite materials, it is necessary to understand the mechanical properties of the matrix materials and of the reinforcing fibers. Another factor that can affect the mechanical properties of a composite material is the interaction between the fiber and the matrix. In general, composites with strong fiber matrix bonding will give higher modulus, lower toughness composites. Composites with weak bonding will have a lower modulus and more ductility. The situation becomes a bit more complex when all possibilities are examined. To be considered are the following: the properties of the surface layer on the fiber, the interactive forces between polymer and matrix, the surface roughness and porosity of the fiber, and the morphology of the matrix polymer at the fiber surface. In practice, the surface of the fibers is treated to enhance the mechanical properties of a composite. These treatments include anodization, acid etching, high temperature oxidation, and plasma oxidation, to name a few. The goal is to be able to predict the surface properties of carbon fibers treated in various ways, and then to relate surface properties to fiber matrix bonding.

Composite material making from empty fruit bunches of palm oil (EFB) and Ijuk (Arengapinnata) using plastic bottle waste as adhesives

NASA Astrophysics Data System (ADS)

Rihayat, T.; Salim, S.; Audina, N.; Khan, N. S. P.; Zaimahwati; Sami, M.; Yunus, M.; Salisah, Z.; Alam, P. N.; Saifuddin; Yusuf, I.

2018-03-01

Reviewed from the current technological required a new methods to capable offering a high profit value without overriding the quality. The development of composite technology is now beginning to shift from traditional composite materials based petroleum to natural fibers composite. In the present study, aim to made specimens using natural fibers in form of EFB as a composite reinforcedment with Polyethylene Terephtalate (PET) derived from Plastic bottles waste as matrix with mixed composition parameters and time-tolerance in the mixing process to build a biocomposite material. The characterization of mechanical properties includes tensile test (ASTM D638-01) and bending test (ASTM D790-02) followed by thermal analysis using Thermogravimetric Analysis (TGA), and morphological analysis using scanning electron microscope (SEM). The analysis effect of EFB, Ijuk and PET mixtures on the composite matrix is very influential with mechanical properties characterization, including tensile test and bending strength. The results demonstrated that from the sample named : 50 : 25: 25, hybrid composites showed improved properties such as tensile strength of 167 MPa while the 90:05:05 based composites exhibited tensile strength values of 30 MPa, respectively. In term the flexural test the best result of composition on the properties with 10 minutes duration time its load value 7,5 Mpa for 80:10:10.

3D tissue engineered micro-tumors for optical-based therapeutic screening platform

NASA Astrophysics Data System (ADS)

Spano, Joseph L.; Schmitt, Trevor J.; Bailey, Ryan C.; Hannon, Timothy S.; Elmajdob, Mohamed; Mason, Eric M.; Ye, Guochang; Das, Soumen; Seal, Sudipta; Fenn, Michael B.

2016-03-01

Melanoma is an underserved area of cancer research, with little focus on studying the effects of tumor extracellular matrix (ECM) properties on melanoma tumor progression, metastasis, and treatment efficacy. We've developed a Raman spectral mapping-based in-vitro screening platform that allows for nondestructive in-situ, multi-time point assessment of a novel potential nanotherapeutic adjuvant, nanoceria (cerium oxide nanoparticles), for treating melanoma. We've focused primarily on understanding melanoma tumor ECM composition and how it influences cell morphology and ICC markers. Furthermore, we aim to correlate this with studies on nanotherapeutic efficacy to coincide with the goal of predicting and preventing metastasis based on ECM composition. We've compiled a Raman spectral database for substrates containing varying compositions of fibronectin, elastin, laminin, and collagens type I and IV. Furthermore, we've developed a machine learning-based semi-quantitative analysis platform utilizing dimensionality reduction with subsequent pixel classification and semi-quantitation of ECM composition using Direct Classical Least Squares for classification and estimation of the reorganization of these components by taking 2D maps using Raman spectroscopy. Gaining an understanding of how tissue properties influence ECM organization has laid the foundation for future work utilizing Raman spectroscopy to assess therapeutic efficacy and matrix reorganization imparted by nanoceria. Specifically, this will allow us to better understand the role of HIF1a in matrix reorganization of the tumor microenvironment. By studying the relationship between substrate modulus and nanoceria's ability to inhibit an ECM that is conducive to tumor formation, we endeavor to show that nanoceria may prevent or even revert tumor conducive microenvironments.

Development of highly sensitive amperometric biosensor for glucose using carbon nanosphere/sodium alginate composite matrix for enzyme immobilization.

PubMed

Han, En; Li, Xia; Cai, Jian-Rong; Cui, Hai-Ying; Zhang, Xing-Ai

2014-01-01

In this study, we developed a highly sensitive amperometric biosensor for glucose detection based on glucose oxidase immobilized in a novel carbon nanosphere (CNS)/sodium alginate (SA) composite matrix. This hybrid material combined the advantages of CNS and natural biopolymer SA. This composite film was characterized by scanning electron microscope, electrochemical impedance spectroscopy and UV-vis, which indicated that the hybrid material was suitable for immobilization of glucose oxidase. Various experimental conditions were investigated that influenced the performance of the biosensor, such as pH, applied potential and temperature. Under the optimum conditions, the biosensor showed excellent performance for glucose over a wide linear concentration range from 1.0 × 10(-6) to 4.6 × 10(-3) M with a detection limit of 0.5 μM based on a signal-to-noise ratio of 3. Furthermore, the biosensor exhibited excellent long-term stability and satisfactory reproducibility.

Development of a metal-based composite actuator

NASA Astrophysics Data System (ADS)

Asanuma, Hiroshi; Haga, Osamu; Ishii, Toshio; Kurihara, Haruki; Ohira, Junichiro; Hakoda, Genji

2000-06-01

This paper describes a basic concept and elemental developments to realize a metal based composite actuator to be used for smart structures. In this study, CFRP prepreg was laminated on aluminum plate to develop an actuator and this laminate could perform unidirectional actuation. SiC continuous fiber/Al composite thin plate could also be used for form a modified type of actuator instead of using CFRP. As sensors to be embedded in this actuator, the following ones wee developed. (1) A pre-notched optical fiber filament could be embedded in aluminum matrix without fracture by the interphase forming/bonding method with copper insert and could be fractured in it at the notch, which enabled forming of an optical interference type strain sensor. (2) Nickel wire could be uniformly oxidized and embedded in aluminum matrix without fracture, which could successfully work as a temperature sensor and a strain sensor.

Modeling of stress/strain behavior of fiber-reinforced ceramic matrix composites including stress redistribution

NASA Technical Reports Server (NTRS)

Mital, Subodh K.; Murthy, Pappu L. N.; Chamis, Christos C.

1994-01-01

A computational simulation procedure is presented for nonlinear analyses which incorporates microstress redistribution due to progressive fracture in ceramic matrix composites. This procedure facilitates an accurate simulation of the stress-strain behavior of ceramic matrix composites up to failure. The nonlinearity in the material behavior is accounted for at the constituent (fiber/matrix/interphase) level. This computational procedure is a part of recent upgrades to CEMCAN (Ceramic Matrix Composite Analyzer) computer code. The fiber substructuring technique in CEMCAN is used to monitor the damage initiation and progression as the load increases. The room-temperature tensile stress-strain curves for SiC fiber reinforced reaction-bonded silicon nitride (RBSN) matrix unidirectional and angle-ply laminates are simulated and compared with experimentally observed stress-strain behavior. Comparison between the predicted stress/strain behavior and experimental stress/strain curves is good. Collectively the results demonstrate that CEMCAN computer code provides the user with an effective computational tool to simulate the behavior of ceramic matrix composites.

The isothermal fatigue behavior of a unidirectional SiC/Ti composite and the Ti alloy matrix

NASA Technical Reports Server (NTRS)

Gayda, John, Jr.; Gabb, Timothy P.; Freed, Alan D.

1989-01-01

The high temperature fatigue behavior of a metal matrix composite (MMC) consisting of Ti-15V-3Cr-3Al-3Sn (Ti-15-3) matrix reinforced by 33 vol percent of continuous unidirectional SiC fibers was experimentally and analytically evaluated. Isothermal MMC fatigue tests with constant amplitude loading parallel to the fiber direction were performed at 300 and 550 C. Comparative fatigue tests of the Ti-15-3 matrix alloy were also conducted. Composite fatigue behavior and the in-situ stress state of the fiber and matrix were analyzed with a micromechanical model, the Concentric Cylinder Model (CCM). The cyclic stress-strain response of the composite was stable at 300 C. However, an increase in cyclic mean strain foreshortened MMC fatigue life at high strain ranges at 550 C. Fatigue tests of the matrix alloy and CCM analyses indicated this response was associated with stress relaxation of the matrix in the composite.

Modeling the Nonlinear, Strain Rate Dependent Deformation of Shuttle Leading Edge Materials with Hydrostatic Stress Effects Included

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.; Carney, Kelly S.

2004-01-01

An analysis method based on a deformation (as opposed to damage) approach has been developed to model the strain rate dependent, nonlinear deformation of woven ceramic matrix composites, such as the Reinforced Carbon Carbon (RCC) material used on the leading edges of the Space Shuttle. In the developed model, the differences in the tension and compression deformation behaviors have also been accounted for. State variable viscoplastic equations originally developed for metals have been modified to analyze the ceramic matrix composites. To account for the tension/compression asymmetry in the material, the effective stress and effective inelastic strain definitions have been modified. The equations have also been modified to account for the fact that in an orthotropic composite the in-plane shear response is independent of the stiffness in the normal directions. The developed equations have been implemented into LS-DYNA through the use of user defined subroutines (UMATs). Several sample qualitative calculations have been conducted, which demonstrate the ability of the model to qualitatively capture the features of the deformation response present in woven ceramic matrix composites.

Enhanced plastic deformations of nanofibrillated cellulose film by adsorbed moisture and protein-mediated interactions.

PubMed

Malho, Jani-Markus; Ouellet-Plamondon, Claudiane; Rüggeberg, Markus; Laaksonen, Päivi; Ikkala, Olli; Burgert, Ingo; Linder, Markus B

2015-01-12

Biological composites are typically based on an adhesive matrix that interlocks rigid reinforcing elements in fiber composite or brick-and-mortar assemblies. In nature, the adhesive matrix is often made up of proteins, which are also interesting model systems, as they are unique among polymers in that we know how to engineer their structures with atomic detail and to select protein elements for specific interactions with other components. Here we studied how fusion proteins that consist of cellulose binding proteins linked to proteins that show a natural tendency to form multimer complexes act as an adhesive matrix in combination with nanofibrillated cellulose. We found that the fusion proteins are retained with the cellulose and that the proteins mainly affect the plastic yield behavior of the cellulose material as a function of water content. Interestingly, the proteins increased the moisture absorption of the composite, but the well-known plastifying effect of water was clearly decreased. The work helps to understand the functional basis of nanocellulose composites as materials and aims toward building model systems for molecular biomimetic materials.

Scanning and Transmission Electron Microscopy of High Temperature Materials

NASA Technical Reports Server (NTRS)

1994-01-01

Software and hardware updates to further extend the capability of the electron microscope were carried out. A range of materials such as intermetallics, metal-matrix composites, ceramic-matrix composites, ceramics and intermetallic compounds, based on refractory elements were examined under this research. Crystal structure, size, shape and volume fraction distribution of various phases which constitute the microstructures were examined. Deformed materials were studied to understand the effect of interfacial microstructure on the deformation and fracture behavior of these materials. Specimens tested for a range of mechanical property requirements, such as stress rupture, creep, low cycle fatigue, high cycle fatigue, thermomechanical fatigue, etc. were examined. Microstructural and microchemical stability of these materials exposed to simulated operating environments were investigated. The EOIM Shuttle post-flight samples were also examined to understand the influence of low gravity processing on microstructure. In addition, fractographic analyses of Nb-Zr-W, titanium aluminide, molybdenum silicide and silicon carbide samples were carried out. Extensive characterization of sapphire fibers in the fiber-reinforced composites made by powder cloth processing was made. Finally, pressure infiltration casting of metal-matrix composites was carried out.

Pulsed co-electrodeposition and characterization of Ni-based nanocomposites reinforced with combustion-synthesized, undoped, tetragonal-ZrO(2) particulates.

PubMed

Reddy, B S B; Das, Karabi; Datta, Amal Kumar; Das, Siddhartha

2008-03-19

Nanostructured nickel matrix composites reinforced with nanosized, undoped, tetragonal zirconia has been synthesized by cathodic pulsed electrodeposition. The reinforcement is synthesized by the aqueous combustion synthesis route with glycine as the fuel and zirconyl nitrate as the oxidizer. The reinforcement and composite have been characterized by XRD, TEM and SEM coupled with EDS. The microhardness and thermal stability (Kissinger method) of the composite are evaluated. These values are compared with those of pure nickel deposited under the same conditions. The results show that the microhardness of the nickel matrix is enhanced by the presence of the reinforcement from 450 to 575 VHN. Also the strengthening due to grain size effects and dispersion strengthening effect are evaluated individually and the interparticle separation is estimated to be around 85 nm. The volume fraction of the reinforcement is estimated to be 12-15% and the particles are uniformly distributed and monodispersed in the nickel matrix. The thermal stability of the composite is better than that of pure nickel in contrast to some of the reported literature.

Characterization of Metal Matrix Composites

NASA Technical Reports Server (NTRS)

Daniel, I. M.; Chun, H. J.; Karalekas, D.

1994-01-01

Experimental methods were developed, adapted, and applied to the characterization of a metal matrix composite system, namely, silicon carbide/aluminim (SCS-2/6061 Al), and its constituents. The silicon carbide fiber was characterized by determining its modulus, strength, and coefficient of thermal expansion. The aluminum matrix was characterized thermomechanically up to 399 C (750 F) at two strain rates. The unidirectional SiC/Al composite was characterized mechanically under longitudinal, transverse, and in-plane shear loading up to 399 C (750 F). Isothermal and non-isothermal creep behavior was also measured. The applicability of a proposed set of multifactor thermoviscoplastic nonlinear constitutive relations and a computer code was investigated. Agreement between predictions and experimental results was shown in a few cases. The elastoplastic thermomechanical behavior of the composite was also described by a number of new analytical models developed or adapted for the material system studied. These models include the rule of mixtures, composite cylinder model with various thermoelastoplastic analyses and a model based on average field theory. In most cases satisfactory agreement was demonstrated between analytical predictions and experimental results for the cases of stress-strain behavior and thermal deformation behavior at different temperatures. In addition, some models yielded detailed three-dimensional stress distributions in the constituents within the composite.

Preparation and characterization of aluminium-silica metal matrix composite

NASA Astrophysics Data System (ADS)

Mallikarjuna, G. B.; Basavaraj, E.

2018-04-01

Aluminum alloys are widely used in aerospace and automobile industries due to their low density and good mechanical properties, better corrosion resistance and wear, low thermal coefficient of expansion as compared to conventional metals and alloys. The excellent properties of these materials and relatively low production cost make them a very attractive for a variety of applications. In this present work, Al alloy LM13-SiO2 composites were produced by stir casting method. The reinforcement SiO2 particle size used for preparation of composites are 106 µm, 150 µm, 250 µm and 355 µm with varying amount of 3 to 12 wt% in steps of 3. The prepared composite specimens were machined as per test standards. Effects of weight percentage of SiO2 particles on wear, tensile strength of Al alloy LM13-SiO2 composites have been investigated. The microstructures of the composites were studied to know the dispersion of the SiO2 particles in matrix. Experimental results shows that there is enhanced mechanical properties, when silica weighing 9% was added to the base aluminium alloy and also similar trend exists in all four different micron size of silica and also it has been observed that addition of SiO2 particles significantly improves wear resistance properties as compared with that of unreinforced matrix.

Nonlinearity and Strain-Rate Dependence in the Deformation Response of Polymer Matrix Composites Modeled

NASA Technical Reports Server (NTRS)

Goldberg, Robert K.

2000-01-01

There has been no accurate procedure for modeling the high-speed impact of composite materials, but such an analytical capability will be required in designing reliable lightweight engine-containment systems. The majority of the models in use assume a linear elastic material response that does not vary with strain rate. However, for containment systems, polymer matrix composites incorporating ductile polymers are likely to be used. For such a material, the deformation response is likely to be nonlinear and to vary with strain rate. An analytical model has been developed at the NASA Glenn Research Center at Lewis Field that incorporates both of these features. A set of constitutive equations that was originally developed to analyze the viscoplastic deformation of metals (Ramaswamy-Stouffer equations) was modified to simulate the nonlinear, rate-dependent deformation of polymers. Specifically, the effects of hydrostatic stresses on the inelastic response, which can be significant in polymers, were accounted for by a modification of the definition of the effective stress. The constitutive equations were then incorporated into a composite micromechanics model based on the mechanics of materials theory. This theory predicts the deformation response of a composite material from the properties and behavior of the individual constituents. In this manner, the nonlinear, rate-dependent deformation response of a polymer matrix composite can be predicted.

Intermediate Temperature Strength Degradation in SiC/SiC Composites

NASA Technical Reports Server (NTRS)

Morscher, Gregory N.; Cawley, James D.; Levine, Stanley (Technical Monitor)

2001-01-01

Woven silicon carbide fiber-reinforced, silicon carbide matrix composites are leading candidate materials for an advanced jet engine combustor liner application. Although the use temperature in the hot region for this application is expected to exceed 1200 C, a potential life-limiting concern for this composite system exists at intermediate temperatures (800 +/- 200 C), where significant time-dependent strength degradation has been observed under stress-rupture loading. A number of factors control the degree of stress-rupture strength degradation, the major factor being the nature of the interphase separating the fiber and the matrix. BN interphases are superior to carbon interphases due to the slower oxidation kinetics of BN. A model for the intermediate temperature stress-rupture of SiC/BN/SiC composites is presented based on the observed mechanistic process that leads to strength degradation for the simple case of through-thickness matrix cracks. The approach taken has much in common with that used by Curtin and coworkers, for two different composite systems. The predictions of the model are in good agreement with the rupture data for stress-rupture of both precracked and as-produced composites. Also, three approaches that dramatically improve the intermediate temperature stress-rupture properties are described: Si-doped BN, fiber spreading, and 'outside debonding'.

Interface Bond Improvement of Sisal Fibre Reinforced Polylactide Composites with Added Epoxy Oligomer

PubMed Central

Hao, Mingyang; Qiu, Feng; Wang, Xiwen

2018-01-01

To improve the interfacial bonding of sisal fiber-reinforced polylactide biocomposites, polylactide (PLA) and sisal fibers (SF) were melt-blended to fabricate bio-based composites via in situ reactive interfacial compatibilization with addition of a commercial grade epoxy-functionalized oligomer Joncryl ADR@-4368 (ADR). The FTIR (Fourier Transform infrared spectroscopy) analysis and SEM (scanning electron microscope) characterization demonstrated that the PLA molecular chain was bonded to the fiber surface and the epoxy-functionalized oligomer played a hinge-like role between the sisal fibers and the PLA matrix, which resulted in improved interfacial adhesion between the fibers and the PLA matrix. The interfacial reaction and microstructures of composites were further investigated by thermal and rheological analyses, which indicated that the mobility of the PLA molecular chain in composites was restricted because of the introduction of the ADR oligomer, which in turn reflected the improved interfacial interaction between SF and the PLA matrix. These results were further justified with the calculation of activation energies of glass transition relaxation (∆Ea) by dynamic mechanical analysis. The mechanical properties of PLA/SF composites were simultaneously reinforced and toughened with the addition of ADR oligomer. The interfacial interaction and structure–properties relationship of the composites are the key points of this study. PMID:29518949

Interface Bond Improvement of Sisal Fibre Reinforced Polylactide Composites with Added Epoxy Oligomer.

PubMed

Hao, Mingyang; Wu, Hongwu; Qiu, Feng; Wang, Xiwen

2018-03-07

To improve the interfacial bonding of sisal fiber-reinforced polylactide biocomposites, polylactide (PLA) and sisal fibers (SF) were melt-blended to fabricate bio-based composites via in situ reactive interfacial compatibilization with addition of a commercial grade epoxy-functionalized oligomer Joncryl ADR @ -4368 (ADR). The FTIR (Fourier Transform infrared spectroscopy) analysis and SEM (scanning electron microscope) characterization demonstrated that the PLA molecular chain was bonded to the fiber surface and the epoxy-functionalized oligomer played a hinge-like role between the sisal fibers and the PLA matrix, which resulted in improved interfacial adhesion between the fibers and the PLA matrix. The interfacial reaction and microstructures of composites were further investigated by thermal and rheological analyses, which indicated that the mobility of the PLA molecular chain in composites was restricted because of the introduction of the ADR oligomer, which in turn reflected the improved interfacial interaction between SF and the PLA matrix. These results were further justified with the calculation of activation energies of glass transition relaxation (∆ E a ) by dynamic mechanical analysis. The mechanical properties of PLA/SF composites were simultaneously reinforced and toughened with the addition of ADR oligomer. The interfacial interaction and structure-properties relationship of the composites are the key points of this study.

Development and Application of a Tool for Optimizing Composite Matrix Viscoplastic Material Parameters

NASA Technical Reports Server (NTRS)

Murthy, Pappu L. N.; Naghipour Ghezeljeh, Paria; Bednarcyk, Brett A.

2018-01-01

This document describes a recently developed analysis tool that enhances the resident capabilities of the Micromechanics Analysis Code with the Generalized Method of Cells (MAC/GMC) and its application. MAC/GMC is a composite material and laminate analysis software package developed at NASA Glenn Research Center. The primary focus of the current effort is to provide a graphical user interface (GUI) capability that helps users optimize highly nonlinear viscoplastic constitutive law parameters by fitting experimentally observed/measured stress-strain responses under various thermo-mechanical conditions for braided composites. The tool has been developed utilizing the MATrix LABoratory (MATLAB) (The Mathworks, Inc., Natick, MA) programming language. Illustrative examples shown are for a specific braided composite system wherein the matrix viscoplastic behavior is represented by a constitutive law described by seven parameters. The tool is general enough to fit any number of experimentally observed stress-strain responses of the material. The number of parameters to be optimized, as well as the importance given to each stress-strain response, are user choice. Three different optimization algorithms are included: (1) Optimization based on gradient method, (2) Genetic algorithm (GA) based optimization and (3) Particle Swarm Optimization (PSO). The user can mix and match the three algorithms. For example, one can start optimization with either 2 or 3 and then use the optimized solution to further fine tune with approach 1. The secondary focus of this paper is to demonstrate the application of this tool to optimize/calibrate parameters for a nonlinear viscoplastic matrix to predict stress-strain curves (for constituent and composite levels) at different rates, temperatures and/or loading conditions utilizing the Generalized Method of Cells. After preliminary validation of the tool through comparison with experimental results, a detailed virtual parametric study is presented wherein the combined effects of temperature and loading rate on the predicted response of a braided composite is investigated.

Making the case for high temperature low sag (htls) overhead transmission line conductors

NASA Astrophysics Data System (ADS)

Banerjee, Koustubh

The future grid will face challenges to meet an increased power demand by the consumers. Various solutions were studied to address this issue. One alternative to realize increased power flow in the grid is to use High Temperature Low Sag (HTLS) since it fulfills essential criteria of less sag and good material performance with temperature. HTLS conductors like Aluminum Conductor Composite Reinforced (ACCR) and Aluminum Conductor Carbon Composite (ACCC) are expected to face high operating temperatures of 150-200 degree Celsius in order to achieve the desired increased power flow. Therefore, it is imperative to characterize the material performance of these conductors with temperature. The work presented in this thesis addresses the characterization of carbon composite core based and metal matrix core based HTLS conductors. The thesis focuses on the study of variation of tensile strength of the carbon composite core with temperature and the level of temperature rise of the HTLS conductors due to fault currents cleared by backup protection. In this thesis, Dynamic Mechanical Analysis (DMA) was used to quantify the loss in storage modulus of carbon composite cores with temperature. It has been previously shown in literature that storage modulus is correlated to the tensile strength of the composite. Current temperature relationships of HTLS conductors were determined using the IEEE 738-2006 standard. Temperature rise of these conductors due to fault currents were also simulated. All simulations were performed using Microsoft Visual C++ suite. Tensile testing of metal matrix core was also performed. Results of DMA on carbon composite cores show that the storage modulus, hence tensile strength, decreases rapidly in the temperature range of intended use. DMA on composite cores subjected to heat treatment were conducted to investigate any changes in the variation of storage modulus curves. The experiments also indicates that carbon composites cores subjected to temperatures at or above 250 degree Celsius can cause permanent loss of mechanical properties including tensile strength. The fault current temperature analysis of carbon composite based conductors reveal that fault currents eventually cleared by backup protection in the event of primary protection failure can cause damage to fiber matrix interface.

Deformation, Failure, and Fatigue Life of SiC/Ti-15-3 Laminates Accurately Predicted by MAC/GMC

NASA Technical Reports Server (NTRS)

Bednarcyk, Brett A.; Arnold, Steven M.

2002-01-01

NASA Glenn Research Center's Micromechanics Analysis Code with Generalized Method of Cells (MAC/GMC) (ref.1) has been extended to enable fully coupled macro-micro deformation, failure, and fatigue life predictions for advanced metal matrix, ceramic matrix, and polymer matrix composites. Because of the multiaxial nature of the code's underlying micromechanics model, GMC--which allows the incorporation of complex local inelastic constitutive models--MAC/GMC finds its most important application in metal matrix composites, like the SiC/Ti-15-3 composite examined here. Furthermore, since GMC predicts the microscale fields within each constituent of the composite material, submodels for local effects such as fiber breakage, interfacial debonding, and matrix fatigue damage can and have been built into MAC/GMC. The present application of MAC/GMC highlights the combination of these features, which has enabled the accurate modeling of the deformation, failure, and life of titanium matrix composites.

Matrices of radiation-protective composites using bismuth oxide

NASA Astrophysics Data System (ADS)

Yashkina, S. Yu; Doroganov, V. A.; Trepalina, Yu N.; Loktionov, V. A.; Evtushenko, E. I.

2018-03-01

The article presents the results of investigations of radiation-protective composites with two types of matrices based on chamotte and aluminous binders. The synthesis of binders was carried out according to the principles of the production of ceramic concrete based on the artificial ceramic binders (ACB). Bismuth oxide was selected as filler. Basic physical and mechanical, as well as radiation-protective characteristics, of composites with different ratios of ACB and Bi2O3 were shown. It was found out that binder of high-alumina chamotte can be used as an optimal matrix base. Composites on its basis have higher structural and radiation-protective properties.

Geometry of modified release formulations during dissolution--influence on performance of dosage forms with diclofenac sodium.

PubMed

Dorożyński, Przemysław; Kulinowski, Piotr; Jamróz, Witold; Juszczyk, Ewelina

2014-12-30

The objectives of the work included: presentation of magnetic resonance imaging (MRI) and fractal analysis based approach to comparison of dosage forms of different composition, structure, and assessment of the influence of the compositional factors i.e., matrix type, excipients etc., on properties and performance of the dosage form during drug dissolution. The work presents the first attempt to compare MRI data obtained for tablet formulations of different composition and characterized by distinct differences in hydration and drug dissolution mechanisms. The main difficulty, in such a case stems from differences in hydration behavior and tablet's geometry i.e., swelling, cracking, capping etc. A novel approach to characterization of matrix systems i.e., quantification of changes of geometrical complexity of the matrix shape during drug dissolution has been developed. Using three chosen commercial modified release tablet formulations with diclofenac sodium we present the method of parameterization of their geometrical complexity on the base of fractal analysis. The main result of the study is the correlation between the hydrating tablet behavior and drug dissolution - the increase of geometrical complexity expressed as fractal dimension relates to the increased variability of drug dissolution results. Copyright © 2014 Elsevier B.V. All rights reserved.

Optoelectronics of inverted type-I CdS/CdSe core/crown quantum ring

NASA Astrophysics Data System (ADS)

Bose, Sumanta; Fan, Weijun; Zhang, Dao Hua

2017-10-01

Inverted type-I heterostructure core/crown quantum rings (QRs) are quantum-efficient luminophores, whose spectral characteristics are highly tunable. Here, we study the optoelectronic properties of type-I core/crown CdS/CdSe QRs in the zincblende phase—over contrasting lateral size and crown width. For this, we inspect their strain profiles, transition energies, transition matrix elements, spatial charge densities, electronic bandstructures, band-mixing probabilities, optical gain spectra, maximum optical gains, and differential optical gains. Our framework uses an effective-mass envelope function theory based on the 8-band k ṡ p method employing the valence force field model for calculating the atomic strain distributions. The gain calculations are based on the density-matrix equation and take into consideration the excitonic effects with intraband scattering. Variations in the QR lateral size and relative widths of core and crown (ergo the composition) affect their energy levels, band-mixing probabilities, optical transition matrix elements, emission wavelengths/intensities, etc. The optical gain of QRs is also strongly dimension and composition dependent with further dependency on the injection carrier density causing the band-filling effect. They also affect the maximum and differential gain at varying dimensions and compositions.

A novel wood flour-filled composite based on microfibrillar high-density polyethylene (HDPE)/Nylon-6 blends.

PubMed

Liu, Hongzhi; Yao, Fei; Xu, Yanjun; Wu, Qinglin

2010-05-01

A novel wood flour (WF)-filled composite based on the microfibrillar high-density polyethylene (HDPE) and Nylon-6 co-blend, in which both in situ formed Nylon-6 microfibrils and WF acted as reinforcing elements, was successfully developed using a two-step extrusion method. At the 30wt.% WF loading level, WF-filled composite based on the microfibrillized HDPE/Nylon-6 blend exhibited higher strengths and moduli than the corresponding HDPE-based composite. The incorporation of WF reduced short-term creep response of HDPE matrix and the presence of Nylon-6 microfibrils further contributed to the creep reduction. Copyright 2009 Elsevier Ltd. All rights reserved.

Modification of natural matrix lac-bagasse for matrix composite films

NASA Astrophysics Data System (ADS)

Nurhayati, Nanik Dwi; Widjaya, Karna; Triyono

2016-02-01

Material technology continues to be developed in order to a material that is more efficient with composite technology is a combination of two or more materials to obtain the desired material properties. The objective of this research was to modification and characterize the natural matrix lac-bagasse as composite films. The first step, natural matrix lac was changed from solid to liquid using an ethanol as a solvent so the matrix homogenly. Natural matrix lac was modified by adding citric acid with concentration variation. Secondly, the bagasse delignification using acid hydrolysis method. The composite films natural matrix lac-bagasse were prepared with optimum modified the addition citric acid 5% (v/v) and delignification bagasse optimum at 1,5% (v/v) in hot press at 80°C 6 Kg/cm-1. Thirdly, composite films without and with modification were characterized functional group analysis using FTIR spectrophotometer and mechanical properties using Universal Testing Machine. The result of research showed natural matrix lac can be modified by reaction with citric acid. FTIR spectra showed without and with modification had functional groups wide absorption 3448 cm-1 group -OH, C=O ester strong on 1712 cm-1 and the methylene group -CH2 on absorption 1465 cm-1. The mechanical properties showed tensile strength 0,55 MPa and elongation at break of 0,95 %. So that composite films natural matrix lac can be made with reinforcement bagasse for material application.

Micromechanics effects in creep of metal-matrix composites

NASA Astrophysics Data System (ADS)

Davis, L. C.; Allison, J. E.

1995-12-01

The creep of metal-matrix composites is analyzed by finite element techniques. An axisymmetric unit-cell model with spherical reinforcing particles is used. Parameters appropriate to TiC particles in a precipitation-hardened (2219) Al matrix are chosen. The effects of matrix plasticity and residual stresses on the creep of the composite are calculated. We confirm (1) that the steady-state rate is independent of the particle elastic moduli and the matrix elastic and plastic properties, (2) that the ratio of composite to matrix steady-state rates depends only on the volume fraction and geometry of the reinforcing phase, and (3) that this ratio can be determined from a calculation of the stress-strain relation for the geometrically identical composite (same phase volume and geometry) with rigid particles in the appropriate power-law hardening matrix. The values of steady-state creep are compared to experimental ones (Krajewski et al.). Continuum mechanics predictions give a larger reduction of the composite creep relative to the unreinforced material than measured, suggesting that the effective creep rate of the matrix is larger than in unreinforced precipitation-hardened Al due to changes in microstructure, dislocation density, or creep mechanism. Changes in matrix creep properties are also suggested by the comparison of calculated and measured creep strain rates in the primary creep regime, where significantly different time dependencies are found. It is found that creep calculations performed for a timeindependent matrix creep law can be transformed to obtain the creep for a time-dependent creep law.

Mechanical characterization of SiC particulate & E-glass fiber reinforced Al 3003 hybrid metal matrix composites

NASA Astrophysics Data System (ADS)

Narayana, K. S. Lakshmi; Shivanand, H. K.

2018-04-01

Metal matrix composites constitute a class of low cost high quality materials which offer high performance for various industrial applications. The orientation of this research is towards the study of mechanical properties of as cast silicon carbide (SiC) particulates and Short E-Glass fibers reinforced Aluminum matrix composites (AMCs). The Hybrid metal matrix composite is developed by reinforcing SiC particulates of 100 microns and short E-Glass fibers of 2-3 mm length with Al 3003 in different compositions. The vortex method of stir casting was employed, in which the reinforcements were introduced into the vortex created by the molten metal by means of mechanical stirrer. The mechanical properties of the prepared metal matrix composites were analyzed. From the studies it was noticed that an improvement in mechanical properties of the reinforced alloys compared to unreinforced alloys.

Combined bending and thermal fatigue of high-temperature metal-matrix composites - Computational simulation

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.; Chamis, Christos C.

1992-01-01

The nonlinear behavior of a high-temperature metal-matrix composite (HT-MMC) was simulated by using the metal matrix composite analyzer (METCAN) computer code. The simulation started with the fabrication process, proceeded to thermomechanical cyclic loading, and ended with the application of a monotonic load. Classical laminate theory and composite micromechanics and macromechanics are used in METCAN, along with a multifactor interaction model for the constituents behavior. The simulation of the stress-strain behavior from the macromechanical and the micromechanical points of view, as well as the initiation and final failure of the constituents and the plies in the composite, were examined in detail. It was shown that, when the fibers and the matrix were perfectly bonded, the fracture started in the matrix and then propagated with increasing load to the fibers. After the fibers fractured, the composite lost its capacity to carry additional load and fractured.

Combined thermal and bending fatigue of high-temperature metal-matrix composites: Computational simulation

NASA Technical Reports Server (NTRS)

Gotsis, Pascal K.

1991-01-01

The nonlinear behavior of a high-temperature metal-matrix composite (HT-MMC) was simulated by using the metal matrix composite analyzer (METCAN) computer code. The simulation started with the fabrication process, proceeded to thermomechanical cyclic loading, and ended with the application of a monotonic load. Classical laminate theory and composite micromechanics and macromechanics are used in METCAN, along with a multifactor interaction model for the constituents behavior. The simulation of the stress-strain behavior from the macromechanical and the micromechanical points of view, as well as the initiation and final failure of the constituents and the plies in the composite, were examined in detail. It was shown that, when the fibers and the matrix were perfectly bonded, the fracture started in the matrix and then propagated with increasing load to the fibers. After the fibers fractured, the composite lost its capacity to carry additional load and fractured.

76 FR 2243 - List of Approved Spent Fuel Storage Casks: NUHOMS ® HD System Revision 1

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-13

... the requirements of reconstituted fuel assemblies; add requirements to qualify metal matrix composite... requirements to qualify metal matrix composite neutron absorbers with integral aluminum cladding; clarify the... requirements to qualify metal matrix composite neutron absorbers with integral aluminum cladding; clarify the...

Raw materials for wood-polymer composites.

Treesearch

Craig Clemons

2008-01-01

To understand wood-plastic composites (WPCs) adequately, we must first understand the two main constituents. Though both are polymer based, they are very different in origin, structure, and performance. Polymers are high molecular weight materials whose performance is largely determined by its molecular architecture. In WPCs, a polymer matrix forms the continuous phase...

Interphase for ceramic matrix composites reinforced by non-oxide ceramic fibers

NASA Technical Reports Server (NTRS)

DiCarlo, James A. (Inventor); Bhatt, Ramakrishna (Inventor); Morscher, Gregory N. (Inventor); Yun, Hee-Mann (Inventor)

2008-01-01

A ceramic matrix composite material is disclosed having non-oxide ceramic fibers, which are formed in a complex fiber architecture by conventional textile processes; a thin mechanically weak interphase material, which is coated on the fibers; and a non-oxide or oxide ceramic matrix, which is formed within the interstices of the interphase-coated fiber architecture. During composite fabrication or post treatment, the interphase is allowed to debond from the matrix while still adhering to the fibers, thereby providing enhanced oxidative durability and damage tolerance to the fibers and the composite material.

Characterization of SiC (SCS-6) Fiber Reinforced Reaction-Formed Silicon Carbide Matrix Composites

NASA Technical Reports Server (NTRS)

Singh, Mrityunjay; Dickerson, Robert M.

1995-01-01

Silicon carbide (SCS-6) fiber reinforced-reaction formed silicon carbide matrix composites were fabricated using NASA's reaction forming process. Silicon-2 at a percent of niobium alloy was used as an infiltrant instead of pure silicon to reduce the amount of free silicon in the matrix after reaction forming. The matrix primarily consists of silicon carbide with a bi-modal grain size distribution. Minority phases dispersed within the matrix are niobium disilicide (NbSi2), carbon and silicon. Fiber push-out tests on these composites determined a debond stress of approx. 67 MPa and a frictional stress of approx. 60 MPa. A typical four point flexural strength of the composite is 297 MPa (43.1 KSi). This composite shows tough behavior through fiber pull out.

Aircraft Fire Safety

DTIC Science & Technology

1982-05-01

these composites are bound with polymeric resins which burn even though the matrix such as Fiberglas or boron graphite will not. The third souce of...fuels, programs are underway to determine compatibility of the antimist additive with changes in base fuel compositions , such as increased aromatics...storage or an onboard oxygen/nitrogen separation unit. T se units are essentially based on semi-permeable hollow fibres and membranes together ith

Biological degradation of gas-filled composite materials on the base of polyethylene

NASA Astrophysics Data System (ADS)

Grigoreva, E. A.; Kolesnikova, N. N.; Popov, A. A.; Olkhov, A. A.

2017-12-01

Gas-filled composite materials based on polyethylene were obtained. It was assumed that introduction of porosity in polyethylene will improve the biodegradability of synthetic materials. The morphological and structural changes were estimated, physical and mechanical properties, stability in water and soil of these materials were determined. It is stated that filling the polymer matrix with pores increases the ability to degrade in nature.

Novel Precursor Approached for CMC Derived by Polymer Pyrolysis

DTIC Science & Technology

1994-02-15

to remove signals from probe polymer materials. C. Pyrolysis Methods The conversion of polymeric PMVS to SiC -containing ceramic was studied by... Composite Fabrication Methods Ceramic matrix composites with different matrix compositions were fabricated using the Polymer Impregnation- Pyrolysis (PIP...Pyrolyzed composites were re- infiltrated with the appropriate polymer matrix source under vacuum, and cured in an autoclave under 100 psi overpressure of N2

Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating.

PubMed

Liang, Zheng; Lin, Dingchang; Zhao, Jie; Lu, Zhenda; Liu, Yayuan; Liu, Chong; Lu, Yingying; Wang, Haotian; Yan, Kai; Tao, Xinyong; Cui, Yi

2016-03-15

Lithium metal-based battery is considered one of the best energy storage systems due to its high theoretical capacity and lowest anode potential of all. However, dendritic growth and virtually relative infinity volume change during long-term cycling often lead to severe safety hazards and catastrophic failure. Here, a stable lithium-scaffold composite electrode is developed by lithium melt infusion into a 3D porous carbon matrix with "lithiophilic" coating. Lithium is uniformly entrapped on the matrix surface and in the 3D structure. The resulting composite electrode possesses a high conductive surface area and excellent structural stability upon galvanostatic cycling. We showed stable cycling of this composite electrode with small Li plating/stripping overpotential (<90 mV) at a high current density of 3 mA/cm(2) over 80 cycles.

Tungsten fiber reinforced copper matrix composites: A review

NASA Technical Reports Server (NTRS)

Mcdanels, David L.

1989-01-01

Tungsten fiber reinforced copper matrix (W/Cu) composites have served as an ideal model system with which to analyze the properties of metal matrix composites. A series of research programs were conducted to investigate the stress-strain behavior of W/Cu composites; the effect of fiber content on the strength, modulus, and conductivity of W/Cu composites; and the effect of alloying elements on the behavior of tungsten wire and of W/Cu composites. Later programs investigated the stress-rupture, creep, and impact behavior of these composites at elevated temperatures. Analysis of the results of these programs as allows prediction of the effects of fiber properties, matrix properties, and fiber content on the properties of W/Cu composites. These analyses form the basis for the rule-of-mixtures prediction of composite properties which was universally adopted as the criteria for measuring composite efficiency. In addition, the analyses allows extrapolation of potential properties of other metal matrix composites and are used to select candidate fibers and matrices for development of tungsten fiber reinforced superalloy composite materials for high temperature aircraft and rocket engine turbine applications. The W/Cu composite efforts are summarized, some of the results obtained are described, and an update is provided on more recent work using W/Cu composites as high strength, high thermal conductivity composite materials for high heat flux, elevated temperature applications.

Fracture Toughness and Reliability in High-Temperature Structural Ceramics and Composites: Prospects and Challenges for the 21st Century

NASA Technical Reports Server (NTRS)

Dutta, Sunil

1999-01-01

The importance of high fracture toughness and reliability in Si3N4, and SiC-based structural ceramics and ceramic matrix composites is reviewed. The potential of these ceramics and ceramic matrix composites for high temperature applications in defense and aerospace applications such as gas turbine engines, radomes, and other energy conversion hardware have been well recognized. Numerous investigations were pursued to improve fracture toughness and reliability by incorporating various reinforcements such as particulate-, whisker-, and continuous fiber into Si3N4 and SiC matrices. All toughening mechanisms, e.g. crack deflection, crack branching, crack bridging, etc., essentially redistribute stresses at the crack tip and increase the energy needed to propagate a crack through the composite material, thereby resulting in improved fracture toughness and reliability. Because of flaw insensitivity, continuous fiber reinforced ceramic composite (CFCC) was found to have the highest potential for higher operating temperature and longer service conditions. However, the ceramic fibers should display sufficient high temperature strength and creep resistance at service temperatures above 1000 'C. The greatest challenge to date is the development of high quality ceramic fibers with associate coatings able to maintain their high strength in oxidizing environment at high temperature. In the area of processing, critical issues are, preparation of optimum matrix precursors, precursor infiltration into fiber array, and matrix densification at a temperature, where grain crystallization and fiber degradation do not occur. A broad scope of effort is required for improved processing and properties with a better understanding of all candidate composite systems.

Stratospheric experiments on curing of composite materials

NASA Astrophysics Data System (ADS)

Chudinov, Viacheslav; Kondyurin, Alexey; Svistkov, Alexander L.; Efremov, Denis; Demin, Anton; Terpugov, Viktor; Rusakov, Sergey

2016-07-01

Future space exploration requires a large light-weight structure for habitats, greenhouses, space bases, space factories and other constructions. A new approach enabling large-size constructions in space relies on the use of the technology of polymerization of fiber-filled composites with a curable polymer matrix applied in the free space environment on Erath orbit. In orbit, the material is exposed to high vacuum, dramatic temperature changes, plasma of free space due to cosmic rays, sun irradiation and atomic oxygen (in low Earth orbit), micrometeorite fluence, electric charging and microgravitation. The development of appropriate polymer matrix composites requires an understanding of the chemical processes of polymer matrix curing under the specific free space conditions to be encountered. The goal of the stratospheric flight experiment is an investigation of the effect of the stratospheric conditions on the uncured polymer matrix of the composite material. The unique combination of low residual pressure, high intensity UV radiation including short-wave UV component, cosmic rays and other aspects associated with solar irradiation strongly influences the chemical processes in polymeric materials. We have done the stratospheric flight experiments with uncured composites (prepreg). A balloon with payload equipped with heater, temperature/pressure/irradiation sensors, microprocessor, carrying the samples of uncured prepreg has been launched to stratosphere of 25-30 km altitude. After the flight, the samples have been tested with FTIR, gel-fraction, tensile test and DMA. The effect of cosmic radiation has been observed. The composite was successfully cured during the stratospheric flight. The study was supported by RFBR grants 12-08-00970 and 14-08-96011.

Polymer blends based on epoxy resin and polyphenylene ether as a matrix material for high-performance composites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Venderbosch, R.W.; Nelissen, J.G.L.; Peijs, A.A.J.M.

1993-12-31

The application of poly(2,6-dimethyl-1,4-phenylene ether), PPE, as a matrix material for continuous carbon fiber reinforced composites was studied. PPE is an amorphous thermoplastic exhibiting a high glass transition temperature (220 C) and outstanding mechanical properties with respect to e.g. toughness. However, due to the limited thermal stability at temperatures above T{sub g}, PPE can be regarded as an intractable polymer. Consequently, the introduction of PPE in a composite structure via a melt impregnation route is not feasible. In this investigation a solution impregnation route, using epoxy resin as a reactive solvent, was developed. During impregnation epoxy resin acts as amore » solvent which results in enhanced flow and a reduced processing temperature enabling the preparation of high quality composites, avoiding any degradation. Upon curing of the neat system, phase separation and phase inversion occurs resulting in a continuous PPE matrix filled with glassy epoxy spheres. As a result of this morphology the mechanical and thermal properties of the final material are mainly dominated by the PPE component. In composite applications, a strong influence of the polarity of the carbon fiber surface on the resulting matrix morphology was found. Upon curing, phase separation is initiated at the fiber surface resulting in an epoxy `interlayer` at the fiber surface. This phenomenon can provide a high level of interfacial adhesion. A preliminary investigation of the resulting composite materials revealed outstanding mechanical properties with respect to e.g. interlaminar toughness and strength.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhamu, Aruna; Shi, Jinjun; Guo, Jiusheng

An electrically conductive laminate composition for fuel cell flow field plate or bipolar plate applications. The laminate composition comprises at least a thin metal sheet having two opposed exterior surfaces and a first exfoliated graphite composite sheet bonded to the first of the two exterior surfaces of the metal sheet wherein the exfoliated graphite composite sheet comprises: (a) expanded or exfoliated graphite and (b) a binder or matrix material to bond the expanded graphite for forming a cohered sheet, wherein the binder or matrix material is between 3% and 60% by weight based on the total weight of the firstmore » exfoliated graphite composite sheet. Preferably, the first exfoliated graphite composite sheet further comprises particles of non-expandable graphite or carbon in the amount of between 3% and 60% by weight based on the total weight of the non-expandable particles and the expanded graphite. Further preferably, the laminate comprises a second exfoliated graphite composite sheet bonded to the second surface of the metal sheet to form a three-layer laminate. Surface flow channels and other desired geometric features can be built onto the exterior surfaces of the laminate to form a flow field plate or bipolar plate. The resulting laminate has an exceptionally high thickness-direction conductivity and excellent resistance to gas permeation.« less

An Experimental Study on Slurry Erosion Resistance of Single and Multilayered Deposits of Ni-WC Produced by Laser-Based Powder Deposition Process

NASA Astrophysics Data System (ADS)

Balu, Prabu; Hamid, Syed; Kovacevic, Radovan

2013-11-01

Single and multilayered deposits containing different mass fractions of tungsten carbide (WC) in nickel (Ni)-matrix (NT-20, NT-60, NT-80) are deposited on a AISI 4140 steel substrate using a laser-based powder deposition process. The transverse cross section of the coupons reveals that the higher the mass fraction of WC in Ni-matrix leads to a more uniform distribution through Ni-matrix. The slurry erosion resistance of the fabricated coupons is tested at three different impingement angles using an abrasive water jet cutting machine, which is quantified based on the erosion rate. The top layer of a multilayered deposit (i.e., NT-60 in a two-layer NT-60 over NT-20 deposit) exhibits better erosion resistance at all three tested impingement angles when compared to a single-layer (NT-60) deposit. A definite increase in the erosion resistance is noted with an addition of nano-size WC particles. The relationship between the different mass fractions of reinforcement (WC) in the deposited composite material (Ni-WC) and their corresponding matrix (Ni) hardness on the erosion rate is studied. The eroded surface is analyzed in the light of a three-dimensional (3-D) profilometer and a scanning electron microscope (SEM). The results show that a volume fraction of approximately 62% of WC with a Ni-matrix hardness of 540 HV resulting in the gouging out of WC from the Ni-matrix by the action of slurry. It is concluded that the slurry erosion resistance of the AISI 4140 steel can be significantly enhanced by introducing single and multilayered deposits of Ni-WC composite material fabricated by the laser-based powder deposition process.

ASTM and VAMAS activities in titanium matrix composites test methods development

NASA Technical Reports Server (NTRS)

Johnson, W. S.; Harmon, D. M.; Bartolotta, P. A.; Russ, S. M.

1994-01-01

Titanium matrix composites (TMC's) are being considered for a number of aerospace applications ranging from high performance engine components to airframe structures in areas that require high stiffness to weight ratios at temperatures up to 400 C. TMC's exhibit unique mechanical behavior due to fiber-matrix interface failures, matrix cracks bridged by fibers, thermo-viscoplastic behavior of the matrix at elevated temperatures, and the development of significant thermal residual stresses in the composite due to fabrication. Standard testing methodology must be developed to reflect the uniqueness of this type of material systems. The purpose of this paper is to review the current activities in ASTM and Versailles Project on Advanced Materials and Standards (VAMAS) that are directed toward the development of standard test methodology for titanium matrix composites.

Characterization of SWNT based Polystyrene Nanocomposites

NASA Astrophysics Data System (ADS)

Mitchell, Cynthia; Bahr, Jeffrey; Tour, James; Arepalli, Sivaram; Krishnamoorti, Ramanan

2003-03-01

Polystyrene nanocomposites with functionalized single walled carbon nanotubes (SWNTs), prepared by the in-situ generation and addition of organic diazonium compounds, were characterized using a range of structural and dynamic methods. These were contrasted to the properties of polystyrene composites prepared with unfunctionalized SWNTs at the same loadings. The functionalized nanocomposites demonstrated a percolated SWNT network structure at concentrations of 1 vol SWNT based composites at similar loadings of SWNT exhibited behavior comparable to that of the unfilled polymer. This formation of the SWNT network structure is because of the improved compatibility between the SWNTs and the polymer matrix due to the functionalization. Further structural evidence for the compatibility of the modified SWNTs and the polymer matrix will be discussed in the presentation.

Synergistic Effects of Temperature and Oxidation on Matrix Cracking in Fiber-Reinforced Ceramic-Matrix Composites

NASA Astrophysics Data System (ADS)

Longbiao, Li

2017-06-01

In this paper, the synergistic effects of temperatrue and oxidation on matrix cracking in fiber-reinforced ceramic-matrix composites (CMCs) has been investigated using energy balance approach. The shear-lag model cooperated with damage models, i.e., the interface oxidation model, interface debonding model, fiber strength degradation model and fiber failure model, has been adopted to analyze microstress field in the composite. The relationships between matrix cracking stress, interface debonding and slipping, fiber fracture, oxidation temperatures and time have been established. The effects of fiber volume fraction, interface properties, fiber strength and oxidation temperatures on the evolution of matrix cracking stress versus oxidation time have been analyzed. The matrix cracking stresses of C/SiC composite with strong and weak interface bonding after unstressed oxidation at an elevated temperature of 700 °C in air condition have been predicted for different oxidation time.

Green synthesis of tea Ag nanocomposite hydrogels via mint leaf extraction for effective antibacterial activity.

PubMed

Jayaramudu, Tippabattini; Varaprasad, Kokkarachedu; Raghavendra, Gownolla Malegowd; Sadiku, E R; Mohana Raju, Konduru; Amalraj, John

2017-10-01

In this report, we investigated the swelling behavior and antibacterial property of nanosilver composite hydrogels made from tea with polyacrylamide via a free-radical polymerization and green process technique. This is probably for the first time; tea-based nano silver composite hydrogels were developed. The composite hydrogels comprise embedded nano silver particles in the tea hydrogel matrix via a green process with mint leaf extract. The size of the nano silver particles in the hydrogel matrix was found to be < 10 nm. The nano silver composite hydrogels formed and their blank hydrogels from the mint leaf were characterized by using ultraviolet-visible spectroscopy, scanning electron microscopy with energy dispersive spectroscopy, transmission electron microscopy, thermogravimetric analysis and X-ray diffraction studies. The nano silver composite hydrogels developed exhibit eminent antibacterial activity against Escherichia coli and Staphylococcus aureus. This clearly indicates that the nano silver composite hydrogels are potential candidates for antimicrobial applications.

The Effect of ZrO₂ Nanoparticles on the Microstructure and Properties of Sintered WC-Bronze-Based Diamond Composites.

PubMed

Sun, Youhong; Wu, Haidong; Li, Meng; Meng, Qingnan; Gao, Ke; Lü, Xiaoshu; Liu, Baochang

2016-05-06

Metal matrix-impregnated diamond composites are widely used in diamond tool manufacturing. In order to satisfy the increasing engineering requirements, researchers have paid more and more attention to enhancing conventional metal matrices by applying novel methods. In this work, ZrO₂ nanoparticles were introduced into the WC-bronze matrix with and without diamond grits via hot pressing to improve the performance of conventional diamond composites. The effects of ZrO₂ nanoparticles on the microstructure, density, hardness, bending strength, and wear resistance of diamond composites were investigated. The results indicated that the hardness and relative density increased, while the bending strength decreased when the content of ZrO₂ nanoparticles increased. The grinding ratio of diamond composites increased significantly by 60% as a result of nano-ZrO₂ addition. The enhancement mechanism was discussed. Diamond composites showed the best overall properties with the addition of 1 wt % ZrO₂ nanoparticles, thus paving the way for further applications.

The Effect of ZrO2 Nanoparticles on the Microstructure and Properties of Sintered WC–Bronze-Based Diamond Composites

PubMed Central

Sun, Youhong; Wu, Haidong; Li, Meng; Meng, Qingnan; Gao, Ke; Lü, Xiaoshu; Liu, Baochang

2016-01-01

Metal matrix-impregnated diamond composites are widely used in diamond tool manufacturing. In order to satisfy the increasing engineering requirements, researchers have paid more and more attention to enhancing conventional metal matrices by applying novel methods. In this work, ZrO2 nanoparticles were introduced into the WC–bronze matrix with and without diamond grits via hot pressing to improve the performance of conventional diamond composites. The effects of ZrO2 nanoparticles on the microstructure, density, hardness, bending strength, and wear resistance of diamond composites were investigated. The results indicated that the hardness and relative density increased, while the bending strength decreased when the content of ZrO2 nanoparticles increased. The grinding ratio of diamond composites increased significantly by 60% as a result of nano-ZrO2 addition. The enhancement mechanism was discussed. Diamond composites showed the best overall properties with the addition of 1 wt % ZrO2 nanoparticles, thus paving the way for further applications. PMID:28773469

Research on Extrusion of Rubber Composites Reinforced by Short Fibers Orientation Based on FEA

NASA Astrophysics Data System (ADS)

Zhang, Dewei; Wang, Chuansheng; Shen, Bo; Li, Shaoming; Bian, Huiguang

2018-06-01

In recent years, rubber composites reinforced by short fibers has been researched deeply, because of its good performances such as higher wear resistance, higher cut resistance and so on. Some research results indicated that if short fibers get orientation in rubber composites, the performances of rubber products could be promoted greatly. But how to make short fibers get orientation in rubber matrix during extrusion is still a real problem. And there are many parameters affect the short fibers orientation. So, in this paper, the effects of die structure including expansion-die and dam-expansion-die on extrusion flow field of short fiber and rubber composite material during extrusion process has been researched by Polyflow. And the FEA results about the pressure field, velocity field and the velocity vector of the rubber composites flow field indicate that, comparing with expansion-die and the dam-expansion-die, the latter one is better for the extrusion process of rubber composites and making short fibers get radial orientation in rubber matrix.

Effect of chemical treatment of Kevlar fibers on mechanical interfacial properties of composites.

PubMed

Park, Soo-Jin; Seo, Min-Kang; Ma, Tae-Jun; Lee, Douk-Rae

2002-08-01

In this work, the effects of chemical treatment on Kevlar 29 fibers have been studied in a composite system. The surface characteristics of Kevlar 29 fibers were characterized by pH, acid-base value, X-ray photoelectron spectroscopy (XPS), and FT-IR. The mechanical interfacial properties of the final composites were studied by interlaminar shear strength (ILSS), critical stress intensity factor (K(IC)), and specific fracture energy (G(IC)). Also, impact properties of the composites were investigated in the context of differentiating between initiation and propagation energies and ductile index (DI) along with maximum force and total energy. As a result, it was found that chemical treatment with phosphoric acid solution significantly affected the degree of adhesion at interfaces between fibers and resin matrix, resulting in improved mechanical interfacial strength in the composites. This was probably due to the presence of chemical polar groups on Kevlar surfaces, leading to an increment of interfacial binding force between fibers and matrix in a composite system.

Novel Approach for Positioning Sensor Lead Wires on SiC-Based Monolithic Ceramic and FRCMC Components/Subcomponents Having Flat and Curved Surfaces

NASA Technical Reports Server (NTRS)

Kiser, J. Douglas; Singh, Mrityunjay; Lei, Jin-Fen; Martin, Lisa C.

1999-01-01

A novel attachment approach for positioning sensor lead wires on silicon carbide-based monolithic ceramic and fiber reinforced ceramic matrix composite (FRCMC) components has been developed. This approach is based on an affordable, robust ceramic joining technology, named ARCJoinT, which was developed for the joining of silicon carbide-based ceramic and fiber reinforced composites. The ARCJoinT technique has previously been shown to produce joints with tailorable thickness and good high temperature strength. In this study, silicon carbide-based ceramic and FRCMC attachments of different shapes and sizes were joined onto silicon carbide fiber reinforced silicon carbide matrix (SiC/ SiC) composites having flat and curved surfaces. Based on results obtained in previous joining studies. the joined attachments should maintain their mechanical strength and integrity at temperatures up to 1350 C in air. Therefore they can be used to position and secure sensor lead wires on SiC/SiC components that are being tested in programs that are focused on developing FRCMCs for a number of demanding high temperature applications in aerospace and ground-based systems. This approach, which is suitable for installing attachments on large and complex shaped monolithic ceramic and composite components, should enhance the durability of minimally intrusive high temperature sensor systems. The technology could also be used to reinstall attachments on ceramic components that were damaged in service.

Numerical simulation on semi-solid die-casting of magnesium matrix composite based on orthogonal experiment

NASA Astrophysics Data System (ADS)

Liu, Huihui; He, Xiongwei; Guo, Peng

2017-04-01

Three factors (pouring temperature, injection speed and mold temperature) were selected to do three levels L9 (33)orthogonal experiment, then simulate processing of semi-solid die-casting of magnesium matrix composite by Flow-3D software. The stress distribution, temperature field and defect distribution of filling process were analyzed to find the optimized processing parameter with the help of orthogonal experiment. The results showed that semi-solid has some advantages of well-proportioned stress and temperature field, less defect concentrated in the surface. The results of simulation were the same as the experimental results.

Enhanced health monitoring of fibrous composites with aligned carbon nanotube networks and electrical impedance tomography

NASA Astrophysics Data System (ADS)

Tallman, T.; Semperlotti, F.; Wang, K. W.

2012-04-01

The high strength to weight ratio of fibrous composites such as glass-fiber reinforced polymers (GFRP) makes them prominent structural materials. However, their laminar nature is susceptible to delamination failure the onset of which traditional structural health monitoring (SHM) techniques cannot reliably and accurately detect. Carbon nano-tubes (CNT) have been recently used to tailor the electrical conductivity of polymer based materials that otherwise behave as insulators. The occurrence of damage in the polymer matrix produces localized changes in conductivity which can be tracked using electrical impedance tomography (EIT). This paper explores combining advances in composite manufacturing with EIT to develop a SHM technique that exploits anisotropic conductance monitoring for enhanced delamination and matrix crack detection.

Microstructure, Mechanical and Tribological Properties of Oxide Dispersion Strengthened High-Entropy Alloys.

PubMed

Liu, Xinyu; Yin, Hangboce; Xu, Yi

2017-11-15

A novel metal matrix composite CrMnFeCoNi with Y₂O₃ as reinforcement phase was designed and manufactured by mechanical alloying and spark plasma sintering. After sintering at 900 °C for 5 min, the microstructure consisted of a FCC matrix and Y₂O₃ nanoparticles. The addition of 0.25 wt % Y₂O₃ increased the room temperature tensile strength of the CrMnFeCoNi base from 868 MPa to 1001 MPa, while the mechanical properties of the addition of 0.5 wt % Y₂O₃ composite decreased. In the meantime, the addition of Y₂O₃ had no significant influence on the coefficient of friction, while the addition of 0.25 wt % Y₂O₃ composite shows excellent wear-resistance.

CSpace: an integrated workplace for the graphical and algebraic analysis of phase assemblages on 32-bit wintel platforms

NASA Astrophysics Data System (ADS)

Torres-Roldan, Rafael L.; Garcia-Casco, Antonio; Garcia-Sanchez, Pedro A.

2000-08-01

CSpace is a program for the graphical and algebraic analysis of composition relations within chemical systems. The program is particularly suited to the needs of petrologists, but could also prove useful for mineralogists, geochemists and other environmental scientists. A few examples of what can be accomplished with CSpace are the mapping of compositions into some desired set of system/phase components, the estimation of reaction/mixing coefficients and assessment of phase-rule compatibility relations within or between complex mineral assemblages. The program also allows dynamic inspection of compositional relations by means of barycentric plots. CSpace provides an integrated workplace for data management, manipulation and plotting. Data management is done through a built-in spreadsheet-like editor, which also acts as a data repository for the graphical and algebraic procedures. Algebraic capabilities are provided by a mapping engine and a matrix analysis tool, both of which are based on singular-value decomposition. The mapping engine uses a general approach to linear mapping, capable of handling determined, underdetermined and overdetermined problems. The matrix analysis tool is implemented as a task "wizard" that guides the user through a number of steps to perform matrix approximation (finding nearest rank-deficient models of an input composition matrix), and inspection of null-reaction space relationships (i.e. of implicit linear relations among the elements of the composition matrix). Graphical capabilities are provided by a graph engine that directly links with the contents of the data editor. The graph engine can generate sophisticated 2-D ternary (triangular) and 3D quaternary (tetrahedral) barycentric plots and includes features such as interactive re-sizing and rotation, on-the-fly coordinate scaling and support for automated drawing of tie lines.

Filler particle size and composite resin classification systems.

PubMed

Lang, B R; Jaarda, M; Wang, R F

1992-11-01

The currently used composite resin classification systems need review if they are to continue to serve as descriptives and quantitative parameters denoting the filler particle content of these materials. Examination of the particles in 12 composite resins using a technique of washing the filler particles from the matrix of the composite resin was presented as yet another method of grouping composites according to filler particle content. Light microscopic examination of the filler particles that remained provided a separation of the 12 materials into four easily distinguished groups based on filler particle sizes. The wear of the 12 composite resins determined in a previous study was examined in relation to the classification of the materials by the currently available systems. The wear values were also examined using the groupings of the materials according to their filler particle sizes as determined by separating the particles from the matrix by the washing technique. Grouping composites on the basis of the filler particle sizes found after washing was easily correlated with wear and supported the suggestion that composites with smaller filler particles wear less.

Impact of change of matrix crystallinity and polymorphism on ovalbumin release from lipid-based implants.

PubMed

Duque, Luisa; Körber, Martin; Bodmeier, Roland

2018-05-30

The objectives of this study were to prepare lipid-based implants by hot melt extrusion (HME) for the prolonged release of ovalbumin (OVA), and to relate protein release to crystallinity and polymorphic changes of the lipid matrix. Two lipids, glycerol tristearate and hydrogenated palm oil, with different composition and degree of crystallinity were studied. Solid OVA was dispersed within the lipid matrixes, which preserved its stability during extrusion. This was partially attributed to a protective effect of the lipidic matrix. The incorporation of OVA decreased the mechanical strength of the implants prepared with the more crystalline matrix, glycerol tristearate, whereas it remained comparable for the hydrogenated palm oil because of stronger physical and non-covalent interactions between the protein and this lipid. This was also the reason for the faster release of OVA from the glycerol tristearate matrix when compared to the hydrogenated palm oil (8 vs. 28 weeks). Curing induced and increased crystallinity, and changes in the release rate, especially for the more crystalline matrix. In this case, both an increase and a decrease in release, were observed depending on the tempering condition. Curing at higher temperatures induced a melt-mediated crystallization and solid state transformation of the glycerol tristearate matrix and led to rearrangements of the inner structure with the formation of larger pores, which accelerated the release. In contrast, changes in the hydrogenated palm oil under the same curing conditions were less noticeable leading to a more robust formulation, because of less polymorphic changes over time. This study helps to understand the effect of lipid matrix composition and crystallinity degree on the performance of protein-loaded implants, and to establish criteria for the selection of a lipid carrier depending on the release profile desired. Copyright © 2018. Published by Elsevier B.V.

Effects of copper amine treatments on mechanical, biological and surface/interphase properties of poly (vinyl chloride)/wood composites

NASA Astrophysics Data System (ADS)

Jiang, Haihong

2005-11-01

The copper ethanolamine (CuEA) complex was used as a wood surface modifier and a coupling agent for wood-PVC composites. Mechanical properties of composites, such as unnotched impact strength, flexural strength and flexural toughness, were significantly increased, and fungal decay weight loss was dramatically decreased by wood surface copper amine treatments. It is evident that copper amine was a very effective coupling agent and decay inhibitor for PVC/wood flour composites, especially in high wood flour loading level. A DSC study showed that the heat capacity differences (DeltaCp) of composites before and after PVC glass transition were reduced by adding wood particles. A DMA study revealed that the movements of PVC chain segments during glass transition were limited and obstructed by the presence of wood molecule chains. This restriction effect became stronger by increasing wood flour content and by using Cu-treated wood flour. Wood flour particles acted as "physical cross-linking points" inside the PVC matrix, resulting in the absence of the rubbery plateau of PVC and higher E', E'' above Tg, and smaller tan delta peaks. Enhanced mechanical performances were attributed to the improved wetting condition between PVC melts and wood surfaces, and the formation of a stronger interphase strengthened by chemical interactions between Cu-treated wood flour and the PVC matrix. Contact angles of PVC solution drops on Cu-treated wood surfaces were decreased dramatically compared to those on the untreated surfaces. Acid-base (polar), gammaAB, electron-acceptor (acid) (gamma +), electron-donor (base) (gamma-) surface energy components and the total surface energies increased after wood surface Cu-treatments, indicating a strong tendency toward acid-base or polar interactions. Improved interphase and interfacial adhesion were further confirmed by measuring interfacial shear strength between wood and the PVC matrix.

Prediction of thermal cycling induced matrix cracking

NASA Technical Reports Server (NTRS)

Mcmanus, Hugh L.

1992-01-01

Thermal fatigue has been observed to cause matrix cracking in laminated composite materials. A method is presented to predict transverse matrix cracks in composite laminates subjected to cyclic thermal load. Shear lag stress approximations and a simple energy-based fracture criteria are used to predict crack densities as a function of temperature. Prediction of crack densities as a function of thermal cycling is accomplished by assuming that fatigue degrades the material's inherent resistance to cracking. The method is implemented as a computer program. A simple experiment provides data on progressive cracking of a laminate with decreasing temperature. Existing data on thermal fatigue is also used. Correlations of the analytical predictions to the data are very good. A parametric study using the analytical method is presented which provides insight into material behavior under cyclical thermal loads.

Test method development for structural characterization of fiber composites at high temperatures

NASA Technical Reports Server (NTRS)

Mandell, J. F.; Grande, D. H.; Edwards, B.

1985-01-01

Test methods used for structural characterization of polymer matrix composites can be applied to glass and ceramic matrix composites only at low temperatures. New test methods are required for tensile, compressive, and shear properties of fiber composites at high temperatures. A tensile test which should be useful to at least 1000 C has been developed and used to characterize the properties of a Nicalon/glass composite up to the matrix limiting temperature of 600 C. Longitudinal and transverse unidirectional composite data are presented and discussed.

A review on mechanical properties of magnesium based nano composites

NASA Astrophysics Data System (ADS)

Tarafder, Nilanjan; Prasad, M. Lakshmi Vara

2018-04-01

A review was done on Magnesium (Mg) based composite materials reinforced with different nano particles such as TiO2, Cu, Y2O3, SiC, ZrO2 and Al2O3. TiO2 and Al2O3 nanoparticles were synthesised by melt deposition process. Cu, Y2O3, SiC and ZrO2 nanoparticles were synthesised by powder metallurgy process. Composite microstructural characteristics shows that the nano-size reinforcements are uniformly distributed in the composite matrix and also minimum porosity with solid interfacial integrity. The mechanical properties showed yield strength improvement by 0.2 percentage and Ultimate tensile strength (UTS) was also improved for all the nano-particles. But UTS was adversely affected with TiO2 reinforcement while ductility was increased. With Cu reinforcement elastic modulus, hardness and fracture resistance increased and improved the co-efficient of thermal expansion (CTE) of Mg based matrix. By Y2O3 reinforcement hardness, fracture resistance was improved and ductility reached maximum by 0.22 volume percentage of Y2O3 and decreased with succeeding increase in Y2O3 reinforcement. The readings exposed that mechanical properties were gathered from the composite comprising 2.0 weight percentage of Y2O3. Ductility and fracture resistance increased with ZrO2 reinforcement in Mg matrix. Using Al2O3 as reinforcement in Mg composite matrix hardness, elastic modulus and ductility was increased but porosity reduced with well interfacial integrity. Dissipation of energy in the form of damping capacity was resolved by classical vibration theory. The result showed that an increasing up to 0.4 volume percentage alumina content increases the damping capacity up to 34 percent. In another sample, addition of 2 weight percentage nano-Al2O3 particles showed big possibility in reducing CTE from 27.9-25.9×10-6 K-1 in Magnesium, tensile and yield strength amplified by 40MPa. In another test, Mg/1.1Al2O3 nanocomposite was manufactured by solidification process followed by hot extrusion. Results showed that strengthening effect was maintained up to 150°C and fracture characteristics of Mg composite transformed from brittle to mixed ductile mode and fully ductile in attendance of nano-Al2O3 particulates.

Fabrication of Fe-Based Diamond Composites by Pressureless Infiltration

PubMed Central

Li, Meng; Sun, Youhong; Meng, Qingnan; Wu, Haidong; Gao, Ke; Liu, Baochang

2016-01-01

A metal-based matrix is usually used for the fabrication of diamond bits in order to achieve favorable properties and easy processing. In the effort to reduce the cost and to attain the desired bit properties, researchers have brought more attention to diamond composites. In this paper, Fe-based impregnated diamond composites for drill bits were fabricated by using a pressureless infiltration sintering method at 970 °C for 5 min. In addition, boron was introduced into Fe-based diamond composites. The influence of boron on the density, hardness, bending strength, grinding ratio, and microstructure was investigated. An Fe-based diamond composite with 1 wt % B has an optimal overall performance, the grinding ratio especially improving by 80%. After comparing with tungsten carbide (WC)-based diamond composites with and without 1 wt % B, results showed that the Fe-based diamond composite with 1 wt % B exhibits higher bending strength and wear resistance, being satisfactory to bit needs. PMID:28774124

Modeling Cyclic Fatigue Hysteresis Loops of 2D Woven Ceramic Matrix Composites at Elevated Temperatures in Steam

PubMed Central

Li, Longbiao

2016-01-01

In this paper, the cyclic fatigue hysteresis loops of 2D woven SiC/SiC ceramic matrix composites (CMCs) at elevated temperatures in steam have been investigated. The interface slip between fibers and the matrix existing in matrix cracking modes 3 and 5, in which matrix cracking and interface debonding occurred in longitudinal yarns, is considered as the major reason for hysteresis loops of 2D woven CMCs. The hysteresis loops of 2D SiC/SiC composites corresponding to different peak stresses, test conditions, and loading frequencies have been predicted using the present analysis. The damage parameter, i.e., the proportion of matrix cracking mode 3 in the entire matrix cracking modes of the composite, and the hysteresis dissipated energy increase with increasing fatigue peak stress. With increasing cycle number, the interface shear stress in the longitudinal yarns decreases, leading to transition of interface slip types of matrix cracking modes 3 and 5. PMID:28773544

Method of making carbon fiber-carbon matrix reinforced ceramic composites

NASA Technical Reports Server (NTRS)

Williams, Brian (Inventor); Benander, Robert (Inventor)

2007-01-01

A method of making a carbon fiber-carbon matrix reinforced ceramic composite wherein the result is a carbon fiber-carbon matrix reinforcement is embedded within a ceramic matrix. The ceramic matrix does not penetrate into the carbon fiber-carbon matrix reinforcement to any significant degree. The carbide matrix is a formed in situ solid carbide of at least one metal having a melting point above about 1850 degrees centigrade. At least when the composite is intended to operate between approximately 1500 and 2000 degrees centigrade for extended periods of time the solid carbide with the embedded reinforcement is formed first by reaction infiltration. Molten silicon is then diffused into the carbide. The molten silicon diffuses preferentially into the carbide matrix but not to any significant degree into the carbon-carbon reinforcement. Where the composite is intended to operate between approximately 2000 and 2700 degrees centigrade for extended periods of time such diffusion of molten silicon into the carbide is optional and generally preferred, but not essential.