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Sample records for beams generating high-energy-density

  1. High-energy-density electron beam generation in ultra intense laser-plasma interaction

    NASA Astrophysics Data System (ADS)

    Liu, Jianxun; Ma, Yanyun; Yang, Xiaohu; Zhao, Jun; Yu, Tongpu; Shao, Fuqiu; Zhuo, Hongbin; Gan, Longfei; Zhang, Guobo; Zhao, Yuan; Yang, Jingkang

    2017-01-01

    By using a two-dimensional particle-in-cell simulation, we demonstrate a scheme for high-energy-density electron beam generation by irradiating an ultra intense laser pulse onto an aluminum (Al) target. With the laser having a peak intensity of 4 × 1023 W cm‑2, a high quality electron beam with a maximum density of 117nc and a kinetic energy density up to 8.79 × 1018 J m‑3 is generated. The temperature of the electron beam can be 416 MeV, and the beam divergence is only 7.25°. As the laser peak intensity increases (e.g., 1024 W cm‑2), both the beam energy density (3.56 × 1019 J m‑3) and the temperature (545 MeV) are increased, and the beam collimation is well controlled. The maximum density of the electron beam can even reach 180nc. Such beams should have potential applications in the areas of antiparticle generation, laboratory astrophysics, etc. This work is financially supported by the National Natural Science Foundation of China (Nos. 11475260, 11305264, 11622547, 91230205, and 11474360), the National Basic Research Program of China (No. 2013CBA01504), and the Research Project of NUDT (No. JC14-02-02).

  2. Large Hadron Collider at CERN: Beams generating high-energy-density matter.

    PubMed

    Tahir, N A; Schmidt, R; Shutov, A; Lomonosov, I V; Piriz, A R; Hoffmann, D H H; Deutsch, C; Fortov, V E

    2009-04-01

    This paper presents numerical simulations that have been carried out to study the thermodynamic and hydrodynamic responses of a solid copper cylindrical target that is facially irradiated along the axis by one of the two Large Hadron Collider (LHC) 7 TeV/ c proton beams. The energy deposition by protons in solid copper has been calculated using an established particle interaction and Monte Carlo code, FLUKA, which is capable of simulating all components of the particle cascades in matter, up to multi-TeV energies. These data have been used as input to a sophisticated two-dimensional hydrodynamic computer code BIG2 that has been employed to study this problem. The prime purpose of these investigations was to assess the damage caused to the equipment if the entire LHC beam is lost at a single place. The FLUKA calculations show that the energy of protons will be deposited in solid copper within about 1 m assuming constant material parameters. Nevertheless, our hydrodynamic simulations have shown that the energy deposition region will extend to a length of about 35 m over the beam duration. This is due to the fact that first few tens of bunches deposit sufficient energy that leads to high pressure that generates an outgoing radial shock wave. Shock propagation leads to continuous reduction in the density at the target center that allows the protons delivered in subsequent bunches to penetrate deeper and deeper into the target. This phenomenon has also been seen in case of heavy-ion heated targets [N. A. Tahir, A. Kozyreva, P. Spiller, D. H. H. Hoffmann, and A. Shutov, Phys. Rev. E 63, 036407 (2001)]. This effect needs to be considered in the design of a sacrificial beam stopper. These simulations have also shown that the target is severely damaged and is converted into a huge sample of high-energy density (HED) matter. In fact, the inner part of the target is transformed into a strongly coupled plasma with fairly uniform physical conditions. This work, therefore, has

  3. Laser-induced generation of ultraintense proton beams for high energy-density science

    NASA Astrophysics Data System (ADS)

    Badziak, J.; Antici, P.; Fuchs, J.; Jabłoński, S.; Mancic, A.; Parys, P.; Rosiński, M.; Suchańska, R.; Szydłowski, A.; Wołowski, J.

    2008-06-01

    Basic properties of high-current high-intensity ion beam generation using laser-induced skin-layer ponderomotive acceleration (SLPA) are discussed. The results of a recent experiment, in which 0.35-ps laser pulse of intensity up to 2×1019 W/cm2 irradiated a thin (1-3 μm) PS (plastic) or Au/PS target (PS covered by 0.1-0.2 μm Au front layer), are presented. It is shown that multi-MA proton beams of current densities >1 TA/cm2 and intensities > 1018 W/cm2 at the source can be produced when the laser-target interaction conditions approach the SLPA requirements. The proton beam parameters as well as the laser-protons energy conversion efficiency substantially depend on the target structure and can be significantly increased with the use of a double-layer Au/PS target. A prospect for the application of SLPA-driven proton beams in ICF fast ignition research is outlined.

  4. Plasma Focusing of High Energy Density Electron and Positron Beams

    SciTech Connect

    Ng, Johnny S.T.

    2000-10-09

    We present results from the SLAC E-150 experiment on plasma focusing of high energy density electron and, for the first time, positron beams. We also present results on plasma lens-induced synchrotron radiation, longitudinal dynamics of plasma focusing, and laser- and beam-plasma interactions.

  5. Highly Compressed Ion Beam for High Energy Density Science

    SciTech Connect

    Friedman, A.; Barnard, J.J.; Briggs, R.J.; Callahan, D.A.; Caporaso, G.J.; Celata, C.M.; Davidson, R.C.; Faltens, A.; Grisham, L.; Grote, D.P.; Henestroza, E.; Kaganovich I.; Lee, E.P.; Lee, R.W.; Leitner, M.; Logan, B.G.; Nelson, S.D.; Olson, C.L.; Penn, G.; Reginato,L.R.; Renk, T.; Rose, D.; Seessler, A.; Staples, J.W.; Tabak, M.; Thoma,C.; Waldron, W.; Welch, D.R.; Wurtele, J.; Yu, S.S.

    2005-05-16

    The Heavy Ion Fusion Virtual National Laboratory is developing the intense ion beams needed to drive matter to the High Energy Density regimes required for Inertial Fusion Energy and other applications. An interim goal is a facility for Warm Dense Matter studies, wherein a target is heated volumetrically without being shocked, so that well-defined states of matter at 1 to 10 eV are generated within a diagnosable region. In the approach they are pursuing, low to medium mass ions with energies just above the Bragg peak are directed onto thin target ''foils,'' which may in fact be foams with mean densities 1% to 10% of solid. This approach complements that being pursued at GSI Darmstadt, wherein high-energy ion beams deposit a small fraction of their energy in a cylindrically target. They present the beam requirements for Warm Dense Matter experiments. The authors discuss neutralized drift compression and final focus experiments and modeling. They describe suitable accelerator architectures based on Drift-Tube Linac, RF, single-gap, Ionization-Front Accelerator, and Pulse-Line Ion Accelerator concepts. The last of these is being pursued experimentally. Finally, they discuss plans toward a user facility for target experiments.

  6. Diagnostics for ion beam driven high energy density physics experiments.

    PubMed

    Bieniosek, F M; Henestroza, E; Lidia, S; Ni, P A

    2010-10-01

    Intense beams of heavy ions are capable of heating volumetric samples of matter to high energy density. Experiments are performed on the resulting warm dense matter (WDM) at the NDCX-I ion beam accelerator. The 0.3 MeV, 30 mA K(+) beam from NDCX-I heats foil targets by combined longitudinal and transverse neutralized drift compression of the ion beam. Both the compressed and uncompressed parts of the NDCX-I beam heat targets. The exotic state of matter (WDM) in these experiments requires specialized diagnostic techniques. We have developed a target chamber and fielded target diagnostics including a fast multichannel optical pyrometer, optical streak camera, laser Doppler-shift interferometer (Velocity Interferometer System for Any Reflector), beam transmission diagnostics, and high-speed gated cameras. We also present plans and opportunities for diagnostic development and a new target chamber for NDCX-II.

  7. DIAGNOSTICS FOR ION BEAM DRIVEN HIGH ENERGY DENSITY PHYSICS EXPERIMENTS

    SciTech Connect

    Bieniosek, F.M.; Henestroza, E.; Lidia, S.; Ni, P.A.

    2010-01-04

    Intense beams of heavy ions are capable of heating volumetric samples of matter to high energy density. Experiments are performed on the resulting warm dense matter (WDM) at the NDCX-I ion beam accelerator. The 0.3 MeV, 30-mA K{sup +} beam from NDCX-I heats foil targets by combined longitudinal and transverse neutralized drift compression of the ion beam. Both the compressed and uncompressed parts of the NDCX-I beam heat targets. The exotic state of matter (WDM) in these experiments requires specialized diagnostic techniques. We have developed a target chamber and fielded target diagnostics including a fast multi-channel optical pyrometer, optical streak camera, laser Doppler-shift interferometer (VISAR), beam transmission diagnostics, and high-speed gated cameras. We also present plans and opportunities for diagnostic development and a new target chamber for NDCX-II.

  8. Diagnostics for ion beam driven high energy density physics experimentsa)

    NASA Astrophysics Data System (ADS)

    Bieniosek, F. M.; Henestroza, E.; Lidia, S.; Ni, P. A.

    2010-10-01

    Intense beams of heavy ions are capable of heating volumetric samples of matter to high energy density. Experiments are performed on the resulting warm dense matter (WDM) at the NDCX-I ion beam accelerator. The 0.3 MeV, 30 mA K+ beam from NDCX-I heats foil targets by combined longitudinal and transverse neutralized drift compression of the ion beam. Both the compressed and uncompressed parts of the NDCX-I beam heat targets. The exotic state of matter (WDM) in these experiments requires specialized diagnostic techniques. We have developed a target chamber and fielded target diagnostics including a fast multichannel optical pyrometer, optical streak camera, laser Doppler-shift interferometer (Velocity Interferometer System for Any Reflector), beam transmission diagnostics, and high-speed gated cameras. We also present plans and opportunities for diagnostic development and a new target chamber for NDCX-II.

  9. Numerical simulations and theoretical analysis of High Energy Density experiments at the next generation of ion beam facilities at Darmstadt: The HEDgeHOB collaboration

    NASA Astrophysics Data System (ADS)

    Tahir, N. A.; Shutov, A.; Lomonosov, I. V.; Piriz, A. R.; Wouchuk, G.; Deutsch, C.; Hoffmann, D. H. H.; Fortov, V. E.

    2006-06-01

    This paper presents detailed numerical simulations and theoretical analysis of different possible experimental schemes to study the thermophysical and transport properties of High Energy Density ( HED) matter generated by the interaction of intense heavy ion beams. The considered beam parameters are those which will be available at the future Facility for Antiprotons and Ion Research ( FAIR) at Darmstadt [W.F. Henneing, Nucl. Instrum. Methods, B214, (2004) 211]. This work has shown that an intense heavy ion beam can be used employing two very different configurations to study HED states in matter. In the first scheme, a sample material is uniformly and isochorically heated by the beam and the heated material is subsequently allowed to expand isentropically. Depending on the specific energy deposited in the material, one may access all the interesting physical states, including that of an expanded hot liquid ( EHL), two-phase liquid-gas ( 2PLG) region, critical point ( CP) parameters as well as strongly coupled plasma ( SCP) states during the expansion. This scheme is named HIHEX ( Heavy Ion Heating and EXpansion). We have considered a 1 GeV/u uranium beam with an intensity, N = 10 10-10 12 ions that are delivered in a single bunch, 50 ns long. The particle intensity distribution in the transverse direction is assumed to be Gaussian with a full width at half maximum (FWHM) in the range of 1-4 mm. We note that the estimated critical temperatures for many metals are very high which are very difficult to access using traditional techniques of shock compression of matter. Employing the proposed HIHEX scheme, one can easily achieve the required temperature by depositing corresponding specific energy in the sample. Solid as well as porous targets have been used in our study. In the second scheme, a sample material like frozen hydrogen that is enclosed in a cylindrical shell of a high- Z material like gold or lead, is imploded by the ion beam. This scheme is specially

  10. HIGH ENERGY DENSITY PHYSICS EXPERIMENTS WITH INTENSE HEAVY ION BEAMS

    SciTech Connect

    Henestroza, E.; Leitner, M.; Logan, B.G.; More, R.M.; Roy, P.K.; Ni, P.; Seidl, P.A.; Waldron, W.L.; Barnard, J.J.

    2010-03-16

    The US heavy ion fusion science program has developed techniques for heating ion-beam-driven warm dense matter (WDM) targets. The WDM conditions are to be achieved by combined longitudinal and transverse space-charge neutralized drift compression of the ion beam to provide a hot spot on the target with a beam spot size of about 1 mm, and pulse length about 1-2 ns. As a technique for heating volumetric samples of matter to high energy density, intense beams of heavy ions are capable of delivering precise and uniform beam energy deposition dE/dx, in a relatively large sample size, and the ability to heat any solid-phase target material. Initial experiments use a 0.3 MeV K+ beam (below the Bragg peak) from the NDCX-I accelerator. Future plans include target experiments using the NDCX-II accelerator, which is designed to heat targets at the Bragg peak using a 3-6 MeV lithium ion beam. The range of the beams in solid matter targets is about 1 micron, which can be lengthened by using porous targets at reduced density. We have completed the fabrication of a new experimental target chamber facility for WDM experiments, and implemented initial target diagnostics to be used for the first target experiments in NDCX-1. The target chamber has been installed on the NDCX-I beamline. The target diagnostics include a fast multi-channel optical pyrometer, optical streak camera, VISAR, and high-speed gated cameras. Initial WDM experiments will heat targets by compressed NDCX-I beams and will explore measurement of temperature and other target parameters. Experiments are planned in areas such as dense electronegative targets, porous target homogenization and two-phase equation of state.

  11. The creation of high energy densities with antimatter beams

    SciTech Connect

    Gibbs, W.R.; Kruk, J.W.; Rice Univ., Houston, TX . Bonner Nuclear Labs.)

    1989-01-01

    The use of antiprotons (and antideuterons) for the study of the behavior of nuclear matter at high energy density is considered. It is shown that high temperatures and high energy densities can be achieved for small volumes. Also investigated is the strangeness production in antimatter annihilation. It is found that the high rate of Lambda production seen in a recent experiment is easily understood. The Lambda and K-short rapidity distributions are also reproduced by the model considered. 11 refs., 6 figs.

  12. Generation of Gigabar Pressures for High-Energy-Density Plasmas

    NASA Astrophysics Data System (ADS)

    Theobald, W.; Betti, R.; Bose, A.; Seka, W.; Stoeckl, C.; Mangino, D.; Casner, A.; Beg, F. N.; Llor Aisa, E.; Ribeyre, X.; Wei, M. S.; Schoff, M. E.; Florido, R.; Mancini, R. C.

    2016-10-01

    Experiments on the OMEGA laser were performed to study gigabar pressures in small (50- μm-diam) Ti and Cu target samples for high-energy-density plasma applications. The samples were precisely placed (better than 10 μm) at the center of a spherical plastic matrix that is irradiated at incident laser intensities of 5 ×1015 W /cm2 . The laser launches a spherical shock wave that converges in the center in order to reach Gbar pressures in the sample. The shock convergence produces a short burst ( 30ps) of x-ray emission. Time-resolved and time-integrated x-ray spectroscopy provides the means to diagnose the plasma conditions in the sample. The time-resolved spectra are compared to predictions from radiation-hydrodynamic simulations to infer the material conditions at Gbar pressures. A second x-ray flash delayed by 600ps caused by the breakout of the rebounded shock through the outer surface of the compressed plastic was observed. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944 and by the Fusion Science Center under Grant No. DE-FC02-04ER54789.

  13. Collective Focusing of Intense Ion Beam Pulses for High-energy Density Physics Applications

    SciTech Connect

    Dorf, Mikhail A.; Kaganovich, Igor D.; Startsev, Edward A.; Davidson, Ronald C.

    2011-04-27

    The collective focusing concept in which a weak magnetic lens provides strong focusing of an intense ion beam pulse carrying a neutralizing electron background is investigated by making use of advanced particle-in-cell simulations and reduced analytical models. The original analysis by Robertson Phys. Rev. Lett. 48, 149 (1982) is extended to the parameter regimes of particular importance for several high-energy density physics applications. The present paper investigates (1) the effects of non-neutral collective focusing in a moderately strong magnetic field; (2) the diamagnetic effects leading to suppression of the applied magnetic field due to the presence of the beam pulse; and (3) the influence of a finite-radius conducting wall surrounding the beam cross-section on beam neutralization. In addition, it is demonstrated that the use of the collective focusing lens can significantly simplify the technical realization of the final focusing of ion beam pulses in the Neutralized Drift Compression Experiment-I (NDCX-I) , and the conceptual designs of possible experiments on NDCX-I are investigated by making use of advanced numerical simulations. 2011 American Institute of Physics

  14. Activities on heavy ion inertial fusion and beam-driven high energy density science in Japan

    NASA Astrophysics Data System (ADS)

    Horioka, K.; Kawamura, T.; Nakajima, M.; Kondo, K.; Ogawa, M.; Oguri, Y.; Hasegawa, J.; Kawata, S.; Kikuchi, T.; Sasaki, T.; Murakami, M.; Takayama, K.

    2009-07-01

    Recent research activities in Japan relevant to heavy ion fusion (HIF) are presented. During the past two years, significant progress in HIF and high energy density (HED) physics research has been made by a number of research groups in universities and accelerator facilities. Evolutions in phase space during the longitudinal compression of intense beams were investigated at UU-NUT-TIT. Beam-plasma interaction experiments and related theoretical studies are in progress at RLNR-TIT. In the study, shock-heated hydrogen was used for the interaction experiments as a well-defined non-ideal-plasma target. In the beam-plasma interaction experiments, a special emphasis is placed on an evaluation of non-linear effects on the stopping power in a beam-heated plasma target. A direct-indirect hybrid scheme of a beam-driven ICF target has been proposed and discussed at UU. In the same group, a method for controlling the Rayleigh-Taylor instability in imploding fuel target has been proposed using oscillating heavy ion beams (HIBs). Core dynamics of the impact ignition has been investigated both experimentally and numerically at ILE—Osaka. Dense plasmas driven by intense ion beams and/or a pulse powered device, were evaluated by a group of DES-TIT, concerning the researches on HED and warm dense matter (WDM) physics. A quasi-statically tamped target was proposed to make a well-defined, warm dense state for equation-of-state (EOS) studies based on ion accelerators. The potentiality of the new facility planned at KEK was evaluated by a collaborating group of TIT-UU-KEK, which can extend the parameter regime for laboratory experiments to study the properties of matter under extreme conditions. A possible method to make a high-pressure condition for study of the planetary science was discussed as a short-term subject of intense HIBs.

  15. Final Report for Statistical Nonlinear Optics of High Energy Density Plasmas: The Physics of Multiple Crossing Laser Beams

    SciTech Connect

    Afeyan, Bedros; Hueller, Stefan; Montgomery, David S.; Hammer, James H.; Meezan, Nathan B.; Heebner, John E.

    2016-10-24

    The various implementations of the STUD pulse program (spike trains of uneven duration and delay) for LPI (laser-plasma instability) control were studied in depth, and novel regimes were found. How to generate STUD pulses with large time-bandwidth products, how to measure their optical scattering signatures, and how to experimentally demonstrate their usefulness were explored. Theoretical and numerical studies were conducted on Stimulated Brillouin Scattering (SBS) and Crossed Beam Energy Transfer (CBET) including statistical models. We established how LPI can be tamed and gain democratized in space and time. Implementing STUD pulses on NIF was also studied. Future high rep rate lasers and fast diagnostics will aid in the adoption of the whole STUD pulse program for LPI control in High Energy Density Plasmas (HEDP).

  16. Note: A high-energy-density Tesla-type pulse generator with novel insulating oil

    NASA Astrophysics Data System (ADS)

    Liu, Sheng; Su, Jiancang; Fan, Xuliang

    2017-09-01

    A 10-GW high-energy-density Tesla-type pulse generator is developed with an improved insulating liquid based on a modified Tesla pulser—TPG700, of which the pulse forming line (PFL) is filled with novel insulating oil instead of transformer oil. Properties of insulating oil determining the stored energy density of the PFL are analyzed, and a criterion for appropriate oil is proposed. Midel 7131 is chosen as an application example. The results of insulating property experiment under tens-of-microsecond pulse charging demonstrate that the insulation capability of Midel 7131 is better than that of KI45X transformer oil. The application test in Tesla pulser TPG700 shows that the output power is increased to 10.5 GW with Midel 7131. The output energy density of TPG700 increases for about 60% with Midel 7131.

  17. Monochromatic radiography of high energy density physics experiments on the MAGPIE generator

    SciTech Connect

    Hall, G. N. Burdiak, G. C.; Suttle, L.; Stuart, N. H.; Swadling, G. F.; Lebedev, S. V.; Smith, R. A.; Patankar, S.; Suzuki-Vidal, F.; Grouchy, P. de; Harvey-Thompson, A. J.; Bennett, M.; Bland, S. N.; Pickworth, L.; Skidmore, J.

    2014-11-15

    A monochromatic X-ray backlighter based on Bragg reflection from a spherically bent quartz crystal has been developed for the MAGPIE pulsed power generator at Imperial College (1.4 MA, 240 ns) [I. H. Mitchell et al., Rev. Sci. Instrum. 67, 1533 (2005)]. This instrument has been used to diagnose high energy density physics experiments with 1.865 keV radiation (Silicon He-α) from a laser plasma source driven by a ∼7 J, 1 ns pulse from the Cerberus laser. The design of the diagnostic, its characterisation and performance, and initial results in which the instrument was used to radiograph a shock physics experiment on MAGPIE are discussed.

  18. Monochromatic radiography of high energy density physics experiments on the MAGPIE generator.

    PubMed

    Hall, G N; Burdiak, G C; Suttle, L; Stuart, N H; Swadling, G F; Lebedev, S V; Smith, R A; Patankar, S; Suzuki-Vidal, F; de Grouchy, P; Harvey-Thompson, A J; Bennett, M; Bland, S N; Pickworth, L; Skidmore, J

    2014-11-01

    A monochromatic X-ray backlighter based on Bragg reflection from a spherically bent quartz crystal has been developed for the MAGPIE pulsed power generator at Imperial College (1.4 MA, 240 ns) [I. H. Mitchell et al., Rev. Sci. Instrum. 67, 1533 (2005)]. This instrument has been used to diagnose high energy density physics experiments with 1.865 keV radiation (Silicon He-α) from a laser plasma source driven by a ∼7 J, 1 ns pulse from the Cerberus laser. The design of the diagnostic, its characterisation and performance, and initial results in which the instrument was used to radiograph a shock physics experiment on MAGPIE are discussed.

  19. Note: A high-energy-density Tesla-type pulse generator with novel insulating oil.

    PubMed

    Liu, Sheng; Su, Jiancang; Fan, Xuliang

    2017-09-01

    A 10-GW high-energy-density Tesla-type pulse generator is developed with an improved insulating liquid based on a modified Tesla pulser-TPG700, of which the pulse forming line (PFL) is filled with novel insulating oil instead of transformer oil. Properties of insulating oil determining the stored energy density of the PFL are analyzed, and a criterion for appropriate oil is proposed. Midel 7131 is chosen as an application example. The results of insulating property experiment under tens-of-microsecond pulse charging demonstrate that the insulation capability of Midel 7131 is better than that of KI45X transformer oil. The application test in Tesla pulser TPG700 shows that the output power is increased to 10.5 GW with Midel 7131. The output energy density of TPG700 increases for about 60% with Midel 7131.

  20. Megagauss field generation for high-energy-density plasma science experiments.

    SciTech Connect

    Rovang, Dean Curtis; Struve, Kenneth William; Porter, John Larry Jr.

    2008-10-01

    There is a need to generate magnetic fields both above and below 1 megagauss (100 T) with compact generators for laser-plasma experiments in the Beamlet and Petawatt test chambers for focused research on fundamental properties of high energy density magnetic plasmas. Some of the important topics that could be addressed with such a capability are magnetic field diffusion, particle confinement, plasma instabilities, spectroscopic diagnostic development, material properties, flux compression, and alternate confinement schemes, all of which could directly support experiments on Z. This report summarizes a two-month study to develop preliminary designs of magnetic field generators for three design regimes. These are, (1) a design for a relatively low-field (10 to 50 T), compact generator for modest volumes (1 to 10 cm3), (2) a high-field (50 to 200 T) design for smaller volumes (10 to 100 mm3), and (3) an extreme field (greater than 600 T) design that uses flux compression. These designs rely on existing Sandia pulsed-power expertise and equipment, and address issues of magnetic field scaling with capacitor bank design and field inductance, vacuum interface, and trade-offs between inductance and coil designs.

  1. High energy density physics effects predicted in simulations of the CERN HiRadMat beam-target interaction experiments

    NASA Astrophysics Data System (ADS)

    Tahir, N. A.; Burkart, F.; Schmidt, R.; Shutov, A.; Wollmann, D.; Piriz, A. R.

    2016-12-01

    Experiments have been done at the CERN HiRadMat (High Radiation to Materials) facility in which large cylindrical copper targets were irradiated with 440 GeV proton beam generated by the Super Proton Synchrotron (SPS). The primary purpose of these experiments was to confirm the existence of hydrodynamic tunneling of ultra-relativistic protons and their hadronic shower in solid materials, that was predicted by previous numerical simulations. The experimental measurements have shown very good agreement with the simulation results. This provides confidence in our simulations of the interaction of the 7 TeV LHC (Large Hadron Collider) protons and the 50 TeV Future Circular Collider (FCC) protons with solid materials, respectively. This work is important from the machine protection point of view. The numerical simulations have also shown that in the HiRadMat experiments, a significant part of thetarget material is be converted into different phases of High Energy Density (HED) matter, including two-phase solid-liquid mixture, expanded as well as compressed hot liquid phases, two-phase liquid-gas mixture and gaseous state. The HiRadMat facility is therefore a unique ion beam facility worldwide that is currently available for studying the thermophysical properties of HED matter. In the present paper we discuss the numerical simulation results and present a comparison with the experimental measurements.

  2. Studies of equation of state properties of high-energy density matter using intense heavy ion beams at the future FAIR facility: The HEDgeHOB collaboration

    NASA Astrophysics Data System (ADS)

    Tahir, N. A.; Spiller, P.; Udrea, S.; Cortazar, O. D.; Deutsch, C.; Fortov, V. E.; Gryaznov, V.; Hoffmann, D. H. H.; Lomonosov, I. V.; Ni, P.; Piriz, A. R.; Shutov, A.; Temporal, M.; Varentsov, D.

    2006-04-01

    This paper shows with the help of numerical simulations the capabilities of intense heavy ion beams to induce states of high-energy density (HED) in matter. Two different experimental schemes are considered, namely, HIHEX (heavy ion heating and expansion) and LAPLAS (laboratory planetary sciences). The first scheme considers isochoric heating and subsequent isentropic expansion of matter while the latter deals with low entropy compression of matter using multiple shock reflection technique. This work has been done within the framework of the HEDgeHOB (high-energy density matter generated by heavy ion beams) collaboration that has been formed to organize and facilitate construction of experimental facilities and later to perform experimental work in the field of HED matter at the future FAIR (facility for antiprotons and ion research) facility.

  3. Laser-driven ultraintense proton beams for high energy-density physics

    NASA Astrophysics Data System (ADS)

    Jablonski, Slawomir; Badziak, Jan; Parys, Piotr; Rosinski, Marcin; Wolowski, Jerzy; Szydlowski, Adam; Antici, P.; Fuchs, J.; Mancic, A.

    2008-04-01

    The results of studies of high-intensity proton beam generation from thin (1 -- 3μm) solid targets irradiated by 0.35-ps laser pulse of energy up to 15J and intensity up to 2x10^19 W/cm^2 are reported. It is shown that the proton beams of multi-TW power and intensity above 10^18 W/cm^2 at the source can be produced when the laser-target interaction conditions approach the Skin-Layer Ponderomotive Acceleration requirements. The laser-protons energy conversion efficiency and proton beam parameters remarkably depend on the target structure. In particular, using a double-layer Au/PS target (plastic covered by 0.1 -- 0.2μm Au front layer) results in two-fold higher conversion efficiency and proton beam intensity than in the case of a plastic target. The values of proton beam intensities attained in our experiment are the highest among the ones measured so far.

  4. Beamed-Energy Propulsion (BEP): Considerations for Beaming High Energy-Density Electromagnetic Waves Through the Atmosphere

    NASA Technical Reports Server (NTRS)

    Manning, Robert M.

    2015-01-01

    A study to determine the feasibility of employing beamed electromagnetic energy for vehicle propulsion within and outside the Earth's atmosphere was co-funded by NASA and the Defense Advanced Research Projects Agency that began in June 2010 and culminated in a Summary Presentation in April 2011. A detailed report entitled "Beamed-Energy Propulsion (BEP) Study" appeared in February 2012 as NASA/TM-2012-217014. Of the very many nuances of this subject that were addressed in this report, the effects of transferring the required high energy-density electromagnetic fields through the atmosphere were discussed. However, due to the limitations of the length of the report, only a summary of the results of the detailed analyses were able to be included. It is the intent of the present work to make available the complete analytical modeling work that was done for the BEP project with regard to electromagnetic wave propagation issues. In particular, the present technical memorandum contains two documents that were prepared in 2011. The first one, entitled "Effects of Beaming Energy Through the Atmosphere" contains an overview of the analysis of the nonlinear problem inherent with the transfer of large amounts of energy through the atmosphere that gives rise to thermally-induced changes in the refractive index; application is then made to specific beamed propulsion scenarios. A brief portion of this report appeared as Appendix G of the 2012 Technical Memorandum. The second report, entitled "An Analytical Assessment of the Thermal Blooming Effects on the Propagation of Optical and Millimeter- Wave Focused Beam Waves For Power Beaming Applications" was written in October 2010 (not previously published), provides a more detailed treatment of the propagation problem and its effect on the overall characteristics of the beam such as its deflection as well as its radius. Comparisons are then made for power beaming using the disparate electromagnetic wavelengths of 1.06 microns and 2

  5. High Energy Density Physics Research Using Intense Ion Beams: the HEDgeHOB Collaboration

    NASA Astrophysics Data System (ADS)

    Tahir, N. A.; Shutov, A.; Lomonosov, I. V.; Piriz, A. R.; Hoffmann, D. H. H.; Deutsch, C.

    2008-11-01

    Intense particle beams provide a novel tool to generate large samples of HED matter with uniform physical conditions [1]. Theoretical studies have shown that an ion beam can be employed using different experimental schemes to study HED states in matter. These include HIHEX [2,3] and LAPLAS [4,5]. The former involves isochoric and uniform heating of matter by an ion beam that is followed by isentropic expansion of the heated material. This allows one to access the entire phase diagram including those regions which can not be accessed by traditional methods of shock waves. The latter considers a multiple shock reflection technique that leads to a low-entropy compression of a test material like H or water which generates physical conditions that are expected to exist in the interior of giant planets. Interesting problems like Rayleigh-Taylor and Richtmyer-Meshkov instabilities have also been investigated in detail.This work has provided the necessary basis for the HEDgeHOB proposal for future experiments at the FAIR facility at Darmstadt. [1] N.A. Tahir et al., PRE 60 (1999) 4715. [2] D.H.H. Hoffmann et al., PoP 9 (2002) 3652. [3] N.A. Tahir et al., PRL 95 (2005) 035001. [4] N.A. Tahir et al., PRE 62 (2001) 016402. [5] N.A. Tahir et al., Nucl. Instr. Meth. A 577 (2007) 238.

  6. Femtosecond laser-generated high-energy-density states studied by x-ray FELs

    NASA Astrophysics Data System (ADS)

    Nakatsutsumi, M.; Appel, K.; Baehtz, C.; Chen, B.; Cowan, T. E.; Göde, S.; Konopkova, Z.; Pelka, A.; Priebe, G.; Schmidt, A.; Sukharnikov, K.; Thorpe, I.; Tschentscher, Th; Zastrau, U.

    2017-01-01

    The combination of powerful optical lasers and an x-ray free-electron laser (XFEL) provides unique capabilities to study the transient behaviour of matter in extreme conditions. The high energy density science instrument (HED instrument) at the European XFEL will provide the experimental platform on which an unique x-ray source can be combined with various types of high-power optical lasers. In this paper, we highlight selected scientific examples together with the associated x-ray techniques, with particular emphasis on femtosecond (fs)-timescale pump-probe experiments. Subsequently, we present the current design status of the HED instrument, outlining how the experiments could be performed. First user experiments will start at the beginning of 2018, after which various optical lasers will be commissioned and made available to the international scientific community.

  7. High Energy Density Physics Research Using Intense Heavy Ion Beam at FAIR: The HEDgeHOB Program

    NASA Astrophysics Data System (ADS)

    Tahir, N. A.; Shutov, A.; Piriz, A. R.; Deutsch, C.; Stöhlker, Th.

    2016-03-01

    International project, Facility for Antiprotons and Ion Research (FAIR), has entered in its construction phase at Darmstadt. It is expected that the new powerful heavy ion synchrotron, SIS100 will deliver a strongly bunched intense beam of energetic uranium ions that will provide the scientists with an efficient and novel tool to research High Energy Density (HED) Physics in the laboratory. Over the past 15 years, substantial theoretical work has been done to design numerous experiments that can be done at this facility in this field. This work has resulted in an extensive scientific proposal named HEDgeHOB, that includes experiment proposals addressing various aspects of HED matter, for example, planetary physics, equation of state, hydrodynamic instabilities and others. In this paper we present a summary of this work.

  8. Numerical Modeling of Complex Targets for High-Energy- Density Experiments with Ion Beams and other Drivers

    NASA Astrophysics Data System (ADS)

    Koniges, Alice; Liu, Wangyi; Lidia, Steven; Schenkel, Thomas; Barnard, John; Friedman, Alex; Eder, David; Fisher, Aaron; Masters, Nathan

    2016-03-01

    We explore the simulation challenges and requirements for experiments planned on facilities such as the NDCX-II ion accelerator at LBNL, currently undergoing commissioning. Hydrodynamic modeling of NDCX-II experiments include certain lower temperature effects, e.g., surface tension and target fragmentation, that are not generally present in extreme high-energy laser facility experiments, where targets are completely vaporized in an extremely short period of time. Target designs proposed for NDCX-II range from metal foils of order one micron thick (thin targets) to metallic foam targets several tens of microns thick (thick targets). These high-energy-density experiments allow for the study of fracture as well as the process of bubble and droplet formation. We incorporate these physics effects into a code called ALE-AMR that uses a combination of Arbitrary Lagrangian Eulerian hydrodynamics and Adaptive Mesh Refinement. Inclusion of certain effects becomes tricky as we must deal with non-orthogonal meshes of various levels of refinement in three dimensions. A surface tension model used for droplet dynamics is implemented in ALE-AMR using curvature calculated from volume fractions. Thick foam target experiments provide information on how ion beam induced shock waves couple into kinetic energy of fluid flow. Although NDCX-II is not fully commissioned, experiments are being conducted that explore material defect production and dynamics.

  9. Numerical Modeling of Complex Targets for High-Energy- Density Experiments with Ion Beams and other Drivers

    DOE PAGES

    Koniges, Alice; Liu, Wangyi; Lidia, Steven; ...

    2016-04-01

    We explore the simulation challenges and requirements for experiments planned on facilities such as the NDCX-II ion accelerator at LBNL, currently undergoing commissioning. Hydrodynamic modeling of NDCX-II experiments include certain lower temperature effects, e.g., surface tension and target fragmentation, that are not generally present in extreme high-energy laser facility experiments, where targets are completely vaporized in an extremely short period of time. Target designs proposed for NDCX-II range from metal foils of order one micron thick (thin targets) to metallic foam targets several tens of microns thick (thick targets). These high-energy-density experiments allow for the study of fracture as wellmore » as the process of bubble and droplet formation. We incorporate these physics effects into a code called ALE-AMR that uses a combination of Arbitrary Lagrangian Eulerian hydrodynamics and Adaptive Mesh Refinement. Inclusion of certain effects becomes tricky as we must deal with non-orthogonal meshes of various levels of refinement in three dimensions. A surface tension model used for droplet dynamics is implemented in ALE-AMR using curvature calculated from volume fractions. Thick foam target experiments provide information on how ion beam induced shock waves couple into kinetic energy of fluid flow. Although NDCX-II is not fully commissioned, experiments are being conducted that explore material defect production and dynamics.« less

  10. Numerical Modeling of Complex Targets for High-Energy- Density Experiments with Ion Beams and other Drivers

    SciTech Connect

    Koniges, Alice; Liu, Wangyi; Lidia, Steven; Schenkel, Thomas; Barnard, John; Friedman, Alex; Eder, David; Fisher, Aaron; Masters, Nathan

    2016-04-01

    We explore the simulation challenges and requirements for experiments planned on facilities such as the NDCX-II ion accelerator at LBNL, currently undergoing commissioning. Hydrodynamic modeling of NDCX-II experiments include certain lower temperature effects, e.g., surface tension and target fragmentation, that are not generally present in extreme high-energy laser facility experiments, where targets are completely vaporized in an extremely short period of time. Target designs proposed for NDCX-II range from metal foils of order one micron thick (thin targets) to metallic foam targets several tens of microns thick (thick targets). These high-energy-density experiments allow for the study of fracture as well as the process of bubble and droplet formation. We incorporate these physics effects into a code called ALE-AMR that uses a combination of Arbitrary Lagrangian Eulerian hydrodynamics and Adaptive Mesh Refinement. Inclusion of certain effects becomes tricky as we must deal with non-orthogonal meshes of various levels of refinement in three dimensions. A surface tension model used for droplet dynamics is implemented in ALE-AMR using curvature calculated from volume fractions. Thick foam target experiments provide information on how ion beam induced shock waves couple into kinetic energy of fluid flow. Although NDCX-II is not fully commissioned, experiments are being conducted that explore material defect production and dynamics.

  11. A 1 MA, variable risetime pulse generator for high energy density plasma research.

    PubMed

    Greenly, J B; Douglas, J D; Hammer, D A; Kusse, B R; Glidden, S C; Sanders, H D

    2008-07-01

    COBRA is a 0.5 Omega pulse generator driving loads of order 10 nH inductance to >1 MA current. The design is based on independently timed, laser-triggered switching of four water pulse-forming lines whose outputs are added in parallel to drive the load current pulse. The detailed design and operation of the switching to give a wide variety of current pulse shapes and rise times from 95 to 230 ns is described. The design and operation of a simple inductive load voltage monitor are described which allows good accounting of load impedance and energy dissipation. A method of eliminating gas bubbles on the underside of nearly horizontal insulator surfaces in water was required for reliable operation of COBRA; a novel and effective solution to this problem is described.

  12. A 1 MA, variable risetime pulse generator for high energy density plasma research

    SciTech Connect

    Greenly, J. B.; Douglas, J. D.; Hammer, D. A.; Kusse, B. R.; Glidden, S. C.; Sanders, H. D.

    2008-07-15

    COBRA is a 0.5 {omega} pulse generator driving loads of order 10 nH inductance to >1 MA current. The design is based on independently timed, laser-triggered switching of four water pulse-forming lines whose outputs are added in parallel to drive the load current pulse. The detailed design and operation of the switching to give a wide variety of current pulse shapes and rise times from 95 to 230 ns is described. The design and operation of a simple inductive load voltage monitor are described which allows good accounting of load impedance and energy dissipation. A method of eliminating gas bubbles on the underside of nearly horizontal insulator surfaces in water was required for reliable operation of COBRA; a novel and effective solution to this problem is described.

  13. High-energy-density electron beam from interaction of two successive laser pulses with subcritical-density plasma

    NASA Astrophysics Data System (ADS)

    Wang, J. W.; Yu, W.; Yu, M. Y.; Xu, H.; Ju, J. J.; Luan, S. X.; Murakami, M.; Zepf, M.; Rykovanov, S.

    2016-02-01

    It is shown by particle-in-cell simulations that a narrow electron beam with high energy and charge density can be generated in a subcritical-density plasma by two consecutive laser pulses. Although the first laser pulse dissipates rapidly, the second pulse can propagate for a long distance in the thin wake channel created by the first pulse and can further accelerate the preaccelerated electrons therein. Given that the second pulse also self-focuses, the resulting electron beam has a narrow waist and high charge and energy densities. Such beams are useful for enhancing the target-back space-charge field in target normal sheath acceleration of ions and bremsstrahlung sources, among others.

  14. High-energy-density electron jet generation from an opening gold cone filled with near-critical-density plasma

    SciTech Connect

    Yu, T. P. Shao, F. Q.; Zou, D. B.; Ge, Z. Y.; Zhang, G. B.; Wang, W. Q.; Li, X. H.; Liu, J. X.; Ouyang, J. M.; Yu, W.; Luan, S. X.; Wang, J. W.; Wong, A. Y.

    2015-01-14

    By using two-dimensional particle-in-cell simulations, we propose a scheme for strong coupling of a petawatt laser with an opening gold cone filled with near-critical-density plasmas. When relevant parameters are properly chosen, most laser energy can be fully deposited inside the cone with only 10% leaving the tip opening. Due to the asymmetric ponderomotive acceleration by the strongly decayed laser pulse, high-energy-density electrons with net laser energy gain are accumulated inside the cone, which then stream out of the tip opening continuously, like a jet. The jet electrons are fully relativistic, with speeds around 0.98−0.998 c and densities at 10{sup 20}/cm{sup 3} level. The jet can keep for a long time over 200 fs, which may have diverse applications in practice.

  15. High Energy Density Laboratory Astrophysics

    SciTech Connect

    Remington, B A

    2004-11-11

    High-energy-density (HED) physics refers broadly to the study of macroscopic collections of matter under extreme conditions of temperature and density. The experimental facilities most widely used for these studies are high-power lasers and magnetic-pinch generators. The HED physics pursued on these facilities is still in its infancy, yet new regimes of experimental science are emerging. Examples from astrophysics include work relevant to planetary interiors, supernovae, astrophysical jets, and accreting compact objects (such as neutron stars and black holes). In this paper, we will review a selection of recent results in this new field of HED laboratory astrophysics and provide a brief look ahead to the coming decade.

  16. Frontiers for discovery in high energy density physics

    NASA Astrophysics Data System (ADS)

    Davidson, Ronald C.

    2005-07-01

    Recent advances in extending the energy, power, and brightness of lasers, particle beams, and Z-pinch generators make it possible to create matter with extremely high energy density in the laboratory. The collective interaction of this matter, often in the plasma state, with itself, intense particle beams, and radiation fields, is a rapidly growing field of research called high energy density physics. It is a field characterized by extreme states of matter, previously unattainable in laboratory experiments, and not unlike the conditions occurring in many astrophysical systems. It is also a field rich in opportunities for scientific discovery and compelling applications, propelled by advances in high-performance computing and advanced instrumentation and measuring techniques. This plenary presentation will summarize the results of two recent national studies of high energy density physics commissioned by the National Academies -- National Research Council, and the Office of Science and Technology Policy's Interagency Working Group on the Physics of the Universe. It will also provide an overview of the exciting research opportunities of high intellectual value in this highly interdisciplinary field, with examples ranging from fast ignition in inertial confinement fusion, to the creation of quark-gluon plasmas characteristic of the very early Universe using heavy ion accelerators. For purposes of this presentation, the working definition of high energy density refers to energy densities exceeding 100 kilojoules per cubic centimeter, or equivalently, pressures exceeding one megabar. For reference, the bulk moduli of solid materials under standard conditions are about 100 kilojoules per cubic centimeter.

  17. Simulations of beam-matter interaction experiments at the CERN HiRadMat facility and prospects of high-energy-density physics research.

    PubMed

    Tahir, N A; Burkart, F; Shutov, A; Schmidt, R; Wollmann, D; Piriz, A R

    2014-12-01

    In a recent publication [Schmidt et al., Phys. Plasmas 21, 080701 (2014)], we reported results on beam-target interaction experiments that have been carried out at the CERN HiRadMat (High Radiation to Materials) facility using extended solid copper cylindrical targets that were irradiated with a 440-GeV proton beam delivered by the Super Proton Synchrotron (SPS). On the one hand, these experiments confirmed the existence of hydrodynamic tunneling of the protons that leads to substantial increase in the range of the protons and the corresponding hadron shower in the target, a phenomenon predicted by our previous theoretical investigations [Tahir et al., Phys. Rev. ST Accel. Beams 25, 051003 (2012)]. On the other hand, these experiments demonstrated that the beam heated part of the target is severely damaged and is converted into different phases of high energy density (HED) matter, as suggested by our previous theoretical studies [Tahir et al., Phys. Rev. E 79, 046410 (2009)]. The latter confirms that the HiRadMat facility can be used to study HED physics. In the present paper, we give details of the numerical simulations carried out to understand the experimental measurements. These include the evolution of the physical parameters, for example, density, temperature, pressure, and the internal energy in the target, during and after the irradiation. This information is important in order to determine the region of the HED phase diagram that can be accessed in such experiments. These simulations have been done using the energy deposition code fluka and a two-dimensional hydrodynamic code, big2, iteratively.

  18. FY96-98 Summary Report Mercury: Next Generation Laser for High Energy Density Physics SI-014

    SciTech Connect

    Bayramian, A; Beach, R; Bibeau, C; Chanteloup, J; Ebbers, C; Emanuel, M; Freitas, B; Fulkerson, S; Kanz, K; Hinz, A; Marshall, C; Mills, S; Nakano, H; Orth, C; Rothenberg, J; Schaffers, K; Seppala, L; Skidmore, I; Smith, L; Sutton, S; Telford, S; Zapata, L

    2000-05-23

    The scope of the Mercury Laser project encompasses the research, development, and engineering required to build a new generation of diode-pumped solid-state lasers for Inertial Confinement Fusion (ICF). The Mercury Laser will be the first integrated demonstration of laser diodes, crystals, and gas cooling within a scalable laser architecture. This report is intended to summarize the progress accomplished during the first three years of the project. Due to the technological challenges associated with production of 900 nm diode-bars, heatsinks, and high optical-quality Yb:S-FAP crystals, the initial focus of the project was primarily centered on the R&D in these three areas. During the third year of the project, the R&D continued in parallel with the development of computer codes, partial activation of the laser, component testing, and code validation where appropriate.

  19. FY96-98 Summary Report Mercury: Next Generation Laser for High Energy Density Physics SI-014

    SciTech Connect

    Bayramian, A.; Beach, R.; Bibeau, C.; Chanteloup, J.-C.; Ebbers, C.; Emanuel, M.; Freitas, B.; Fulkerson, S.; Kanz, K.; Hinz, A.; Marshall, C.; Mills, S.; Nakano, H.; Orth, C.; Rothenberg, J.; Schaffers, K.; Seppala, L.; Skidmore, J.; Smith, L.; Sutton, S.; Telford, S.; Zapata, L.

    2000-05-25

    The scope of the Mercury Laser project encompasses the research, development, and engineering required to build a new generation of diode-pumped solid-state lasers for Inertial Confinement Fusion (ICF). The Mercury Laser will be the first integrated demonstration of laser diodes, crystals, and gas cooling within a scalable laser architecture. This report is intended to summarize the progress accomplished during the first three years of the project. Due to the technological challenges associated with production of 900 nm diode-bars, heatsinks, and high optical-quality Yb:S-FAP crystals, the initial focus of the project was primarily centered on the R&D in these three areas. During the third year of the project, the R&D continued in parallel with the development of computer codes, partial activation of the laser, component testing, and code validation where appropriate.

  20. High-energy-density plasmas generation on GEKKO-LFEX laser facility for fast-ignition laser fusion studies and laboratory astrophysics

    NASA Astrophysics Data System (ADS)

    Fujioka, S.; Zhang, Z.; Yamamoto, N.; Ohira, S.; Fujii, Y.; Ishihara, K.; Johzaki, T.; Sunahara, A.; Arikawa, Y.; Shigemori, K.; Hironaka, Y.; Sakawa, Y.; Nakata, Y.; Kawanaka, J.; Nagatomo, H.; Shiraga, H.; Miyanaga, N.; Norimatsu, T.; Nishimura, H.; Azechi, H.

    2012-12-01

    The world's largest peta watt (PW) laser LFEX, which delivers energy up to 2 kJ in a 1.5 ps pulse, has been constructed beside the GEKKO XII laser at the Institute of Laser Engineering, Osaka University. The GEKKO-LFEX laser facility enables the creation of materials having high-energy-density which do not exist naturally on the Earth and have an energy density comparable to that of stars. High-energy-density plasma is a source of safe, secure, environmentally sustainable fusion energy. Direct-drive fast-ignition laser fusion has been intensively studied at this facility under the auspices of the Fast Ignition Realization Experiment (FIREX) project. In this paper, we describe improvement of the LFEX laser and investigations of advanced target design to increase the energy coupling efficiency of the fast-ignition scheme. The pedestal of the LFEX pulse, which produces a long preformed plasma and results in the generation of electrons too energetic to heat the fuel core, was reduced by introducing an amplified optical parametric fluorescence quencher and saturable absorbers in the front-end system of the LFEX laser. Since fast electrons are scattered and stopped by the strong electric field of highly ionized high-Z (i.e. gold) ions, a low-Z cone was studied for reducing the energy loss of fast electrons in the cone tip region. A diamond-like carbon cone was fabricated for the fast-ignition experiment. An external magnetic field, which is demonstrated to be generated by a laser-driven capacitor-coil target, will be applied to the compression of the fuel capsule to form a strong magnetic field to guide the fast electrons to the fuel core. In addition, the facility offers a powerful means to test and validate astronomical models and computations in the laboratory. As well as demonstrating the ability to recreate extreme astronomical conditions by the facilities, our theoretical description of the laboratory experiment was compared with the generally accepted explanation

  1. Perspectives on High-Energy-Density Physics

    NASA Astrophysics Data System (ADS)

    Drake, R. Paul

    2008-11-01

    Much of 21st century plasma physics will involve work to produce, understand, control, and exploit very non-traditional plasmas. High-energy density (HED) plasmas are often examples, variously involving strong Coulomb interactions and few particles per Debeye sphere, dominant radiation effects, strongly relativistic effects, or strongly quantum-mechanical behavior. Indeed, these and other modern plasma systems often fall outside the early standard theoretical definitions of ``plasma''. This presentation will focus on two types of HED plasmas that exhibit non-traditional behavior. Our first example will be the plasmas produced by extremely strong shock waves. Shock waves are present across the entire realm of plasma densities, often in space or astrophysical contexts. HED shock waves (at pressures > 1 Mbar) enable studies in many areas, from equations of state to hydrodynamics to radiation hydrodynamics. We will specifically consider strongly radiative shocks, in which the radiative energy fluxes are comparable to the mechanical energy fluxes that drive the shocks. Modern HED facilities can produce such shocks, which are also present in dense, energetic, astrophysical systems such as supernovae. These shocks are also excellent targets for advanced simulations due to their range of spatial scales and complex radiation transport. Our second example will be relativistic plasmas. In general, these vary from plasmas containing relativistic particle beams, produced for some decades in the laboratory, to the relativistic thermal plasmas present for example in pulsar winds. Laboratory HED relativistic plasmas to date have been those produced by laser beams of irradiance ˜ 10^18 to 10^22 W/cm^2 or by accelerator-produced HED electron beams. These have applications ranging from generation of intense x-rays to production of proton beams for radiation therapy to acceleration of electrons. Here we will focus on electron acceleration, a spectacular recent success and a rare

  2. High Energy Density Physics and Exotic Acceleration Concepts

    SciTech Connect

    Katsouleas, T.

    2004-10-11

    The reported results and discussions in the Working Group on High Energy Density Physics and Exotic Acceleration Concepts are summarized. The working group focused largely on laser-generated proton and ion beams from solid targets, but also considered laser vacuum acceleration results, active media accelerator proposals, ferroelectric-based accelerator technology advances and beam conditioning concepts for free electron lasers. The charge to the working group was to develop a laser-based proton injector exceeding current capabilities in at least one important parameter.

  3. High energy density aluminum battery

    DOEpatents

    Brown, Gilbert M.; Paranthaman, Mariappan Parans; Dai, Sheng; Dudney, Nancy J.; Manthiram, Arumugan; McIntyre, Timothy J.; Sun, Xiao-Guang; Liu, Hansan

    2016-10-11

    Compositions and methods of making are provided for a high energy density aluminum battery. The battery comprises an anode comprising aluminum metal. The battery further comprises a cathode comprising a material capable of intercalating aluminum or lithium ions during a discharge cycle and deintercalating the aluminum or lithium ions during a charge cycle. The battery further comprises an electrolyte capable of supporting reversible deposition and stripping of aluminum at the anode, and reversible intercalation and deintercalation of aluminum or lithium at the cathode.

  4. Table-top Generation and Spectroscopic Study of ~10 TPa High-Energy Density Materials with C60+ Hypervelocity (v ~ 100 km/s) Impact

    NASA Astrophysics Data System (ADS)

    Bae, Young

    2013-06-01

    Intense bursts of soft x-rays were discovered by Bae et al. in hypervelocity (v ~ 100 km/s) impact of bio and water nanoparticles at the Brookhaven National Lab (BNL) in 1994. In the experiment, the nanoparticles were directly impacted on and detected by Si particle detectors that also detected the soft x-rays. Energy deposition measurements through thin films revealed that the impact generated pressures were ~10 TPa, and the photon energies in the range of 75-100 eV for Si targets. The conversion efficiency from the kinetic energy to the radiation energy was unexpectedly high, ~38%, which was attributed to Dicke Superradiance of collective quantum states in High-Energy Density Materials (HEDM), Metastable Innershell Molecular States (MIMS). This talk presents recent experimental results obtained in a table-top apparatus completely different from and orders of magnitude smaller than that at BNL. In the new setup, hypervelocity (v 100 km/s) C60+ ions impacted on Al targets, and the impact generated soft x-rays were detected off-axis and analyzed using three Si photodiode detectors with selective energy response curves. The photon energy was determined to be ~70 eV with the kinetic-energy to photon-energy conversion efficiency of ~35% in confirmation of the results by Bae et al. at BNL. The present results demonstrate a new way of generation and spectroscopic study of HEDM with pressures exceeding 10 TPa, and show the pathway to scaling up the soft x-ray generation method for a wide range of applications from lithography to inertial fusion. This work was supported by DTRA under the contract HDTRA1-12-C-0094.

  5. Table-top Generation and Spectroscopic Study of ~10 TPa High-Energy Density Materials with C60 Hypervelocity (v ~ 100 km/s) Impact

    NASA Astrophysics Data System (ADS)

    Bae, Young

    2013-06-01

    Intense bursts of soft x-rays were discovered by Bae et al. in hypervelocity (v ~ 100 km/s) impact of bio and water nanoparticles at the Brookhaven National Lab (BNL) in 1994. In the experiment, the nanoparticles were directly impacted on and detected by Si particle detectors that also detected the soft x-rays. Energy deposition measurements through thin films revealed that the impact generated pressures were ~10 TPa, and the photon energies in the range of 75-100 eV for Si targets. The conversion efficiency from the kinetic energy to the radiation energy was unexpectedly high, ~38%, which was attributed to Dicke Superradiance of collective quantum states in High-Energy Density Materials (HEDM), Metastable Innershell Molecular States (MIMS). This talk presents recent experimental results obtained in a table-top apparatus completely different from and orders of magnitude smaller than that at BNL. In the new setup, hypervelocity (v 100 km/s) C60+ ions impacted on Al targets, and the impact generated soft x-rays were detected off-axis and analyzed using three Si photodiode detectors with selective energy response curves. The photon energy was determined to be ~70 eV with the kinetic-energy to photon-energy conversion efficiency of ~35% in confirmation of the results by Bae et al. at BNL. The present results demonstrate a new way of generation and spectroscopic study of HEDM with pressures exceeding 10 TPa, and show the pathway to scaling up the soft x-ray generation method for a wide range of applications from lithography to inertial fusion. This work was supported by DTRA under the contract HDTRA1-12-C-0094.

  6. High Energy Density Film Capacitors (PREPRINT)

    DTIC Science & Technology

    2009-06-01

    capacitor film, and the test of our first generation prototype capacitors . II. HIGH-K POLYMER DIELECTRIC MATERIALS Commercial polypropylene (PP...metallized polypropylene energy storage capacitors ”, IEEE Trans. Plasma Sci., 30(5): 1939 (2002). [2] W. Clelland, et al., Paktron Division of...AFRL-RZ-WP-TP-2010-2127 HIGH ENERGY DENSITY FILM CAPACITORS (PREPRINT) Shihai Zhang, Brian Zellers, Jim Henrish, Shawn Rockey, and Dean

  7. High Energy Density Physics and Exotic Acceleration Schemes

    SciTech Connect

    Cowan, T.; Colby, E.; /SLAC

    2005-09-27

    The High Energy Density and Exotic Acceleration working group took as our goal to reach beyond the community of plasma accelerator research with its applications to high energy physics, to promote exchange with other disciplines which are challenged by related and demanding beam physics issues. The scope of the group was to cover particle acceleration and beam transport that, unlike other groups at AAC, are not mediated by plasmas or by electromagnetic structures. At this Workshop, we saw an impressive advancement from years past in the area of Vacuum Acceleration, for example with the LEAP experiment at Stanford. And we saw an influx of exciting new beam physics topics involving particle propagation inside of solid-density plasmas or at extremely high charge density, particularly in the areas of laser acceleration of ions, and extreme beams for fusion energy research, including Heavy-ion Inertial Fusion beam physics. One example of the importance and extreme nature of beam physics in HED research is the requirement in the Fast Ignitor scheme of inertial fusion to heat a compressed DT fusion pellet to keV temperatures by injection of laser-driven electron or ion beams of giga-Amp current. Even in modest experiments presently being performed on the laser-acceleration of ions from solids, mega-amp currents of MeV electrons must be transported through solid foils, requiring almost complete return current neutralization, and giving rise to a wide variety of beam-plasma instabilities. As keynote talks our group promoted Ion Acceleration (plenary talk by A. MacKinnon), which historically has grown out of inertial fusion research, and HIF Accelerator Research (invited talk by A. Friedman), which will require impressive advancements in space-charge-limited ion beam physics and in understanding the generation and transport of neutralized ion beams. A unifying aspect of High Energy Density applications was the physics of particle beams inside of solids, which is proving to

  8. High Energy Density Extended Solids

    NASA Astrophysics Data System (ADS)

    Yoo, Choong-Shik

    2009-06-01

    Application of high pressure significantly alters the interatomic distance and, thus, the nature of intermolecular interaction, chemical bonding, molecular configuration, crystal structure, and stability of solid. With modern advances in high-pressure technologies, it is feasible to achieve a large (often up to a several-fold) compression of lattice, at which condition material can be easily forced into a new physical and chemical configuration. The high-pressure thus offers enhanced opportunities to discover new phases, both stable and metastable ones, and to tune novel properties in a wide-range of atomistic length scale, substantially greater than (often being several orders of) those achieved by other thermal (varying temperatures) and chemical (varying composition or making alloys) means. Over the past decade or two, a large number of new materials and novel phenomena have been discovered and predicted at extreme pressure-temperature conditions. Commonly observed under extreme conditions is the transformation of solids into more compact structures with itinerant electrons such as metallic and nonmetallic extended phases. Nonmolecular extended solids, particularly made of low Z elements such as hydrogen, carbon, nitrogen, oxygen, and fluorine, constitute a new class of high energy density solids, which can store a large sum of energy in their three-dimensional network structure (˜ several eV/bond). Yet, a large cohesive energy of singly bonded (or sp3 hybridized) electrons gives rise to an extremely stiff lattice and novel electronic and optical properties. Broadly speaking, these molecular-to-nonmolecular transitions occur due to electron delocalization manifested as a rapid increase in electron kinetic energy at high density, but there are many outstanding questions as well regarding the exact nature of chemical bonding, phase stability, chemical mechanisms, and so on. These questions constitute fundamental chemistry unique to extreme pressure

  9. High-Energy-Density Capacitors

    NASA Technical Reports Server (NTRS)

    Slenes, Kirk

    2003-01-01

    Capacitors capable of storing energy at high densities are being developed for use in pulse-power circuits in such diverse systems as defibrillators, particle- beam accelerators, microwave sources, and weapons. Like typical previously developed energy-storage capacitors, these capacitors are made from pairs of metal/solid-dielectric laminated sheets that are wound and pressed into compact shapes to fit into cans, which are then filled with dielectric fluids. Indeed, these capacitors can be fabricated largely by conventional fabrication techniques. The main features that distinguish these capacitors from previously developed ones are improvements in (1) the selection of laminate materials, (2) the fabrication of the laminated sheets from these materials, and (3) the selection of dielectric fluids. In simplest terms, a high-performance laminated sheet of the type used in these capacitors is made by casting a dielectric polymer onto a sheet of aluminized kraft paper. The dielectric polymer is a siloxane polymer that has been modified with polar pendant groups to increase its permittivity and dielectric strength. Potentially, this polymer is capable of withstanding an energy density of 7.5 J/cm3, which is four times that of the previous state-of-the-art-capacitor dielectric film material. However, the full potential of this polymer cannot be realized at present because (1) at thicknesses needed for optimum performance (.8.0 m), the mechanical strength of a film of this polymer is insufficient for incorporation into a wound capacitor and (2) at greater thickness, the achievable energy density decreases because of a logarithmic decrease in dielectric strength with increasing thickness. The aluminized kraft paper provides the mechanical strength needed for processing of the laminate and fabrication of the capacitor, and the aluminum film serves as an electrode layer. Because part of the thickness of the dielectric is not occupied by the modified siloxane polymer, the

  10. Table-top generation and spectroscopic study of ~10 TPa high-energy density materials with C60+ hypervelocity (~100 km/s) impact

    NASA Astrophysics Data System (ADS)

    Bae, Y. K.

    2014-05-01

    The use of nanoparticles as flyers to create shock pressures exceeding 10 TPa and to investigate the matters in planetary or stellar interiors has been pursued by the author for two decades. Previous studies led by the author at Brookhaven National Lab (BNL) in 1994 proved that such ultra-strong shocks can be generated with charged bio and water nanoparticles by accelerating them with an electrostatic accelerator and impacting them on solids at ~ 100 km/s. The author in 2008 showed that the BNL nanoplasmas produced intense bursts of soft x-rays (hv ~ 100 eV) from optical decay of excimer-like Metastable Innershell Molecular State, MIMS, formed by inner-shell electron excitation. The conversion efficiency from the nano-flyer kinetic energy to the radiation energy was unexpectedly high, ~38%, which was attributed to high efficiency pressure ionization conversion of impact energy to MIMS excitation energy and MIMS collective optical decay in tens of fs via Dicke Superradiance. Now, this paper reports an experimental study performed with C60 as a nano-flyer that permitted reduction of the size and complexity of the apparatus by orders of magnitude compared with the BNL one. The present results confirm the BNL results unambiguously, demonstrate a pathway to scaling up of soft x-ray intensity, and open doors to a wide range of applications from lithography to inertial fusion.

  11. Preface: High Energy Density Laboratory Astrophysics 2014

    NASA Astrophysics Data System (ADS)

    Ciardi, Andrea

    2015-12-01

    This special issue marks the tenth High Energy Density Laboratory Astrophysics conference. Over 5 days in May 2014, 130 scientists from more than 20 countries gathered in Bordeaux (France) to present and discuss developments in this relatively young field. Testifying to its now well established international dimension, this was the first meeting held outside of the USA.

  12. Frontiers for Discovery in High Energy Density Physics

    SciTech Connect

    Davidson, R. C.; Katsouleas, T.; Arons, J.; Baring, M.; Deeney, C.; Di Mauro, L.; Ditmire, T.; Falcone, R.; Hammer, D.; Hill, W.; Jacak, B.; Joshi, C.; Lamb, F.; Lee, R.; Logan, B. G.; Melissinos, A.; Meyerhofer, D.; Mori, W.; Murnane, M.; Remington, B.; Rosner, R.; Schneider, D.; Silvera, I.; Stone, J.; Wilde, B.; Zajc. W.

    2004-07-20

    The report is intended to identify the compelling research opportunities of high intellectual value in high energy density physics. The opportunities for discovery include the broad scope of this highly interdisciplinary field that spans a wide range of physics areas including plasma physics, laser and particle beam physics, nuclear physics, astrophysics, atomic and molecular physics, materials science and condensed matter physics, intense radiation-matter interaction physics, fluid dynamics, and magnetohydrodynamics

  13. A promising high-energy-density material.

    PubMed

    Zhang, Wenquan; Zhang, Jiaheng; Deng, Mucong; Qi, Xiujuan; Nie, Fude; Zhang, Qinghua

    2017-08-03

    High-energy density materials represent a significant class of advanced materials and have been the focus of energetic materials community. The main challenge in this field is to design and synthesize energetic compounds with a highest possible density and a maximum possible chemical stability. Here we show an energetic compound, [2,2'-bi(1,3,4-oxadiazole)]-5,5'-dinitramide, is synthesized through a two-step reaction from commercially available reagents. It exhibits a surprisingly high density (1.99 g cm(-3) at 298 K), poor solubility in water and most organic solvents, decent thermal stability, a positive heat of formation and excellent detonation properties. The solid-state structural features of the synthesized compound are also investigated via X-ray diffraction and several theoretical techniques. The energetic and sensitivity properties of the explosive compound are similar to those of 2, 4, 6, 8, 10, 12-(hexanitrohexaaza)cyclododecane (CL-20), and the developed compound shows a great promise for potential applications as a high-energy density material.High energy density materials are of interest, but density is the limiting factor for many organic compounds. Here the authors show the formation of a high density energetic compound from a two-step reaction between commercially available compounds that exhibit good heat thermal stability and detonation properties.

  14. Laser-Plasma Interactions in High-Energy Density Plasmas

    SciTech Connect

    Constantin, C G; Baldis, H A; Schneider, M B; Hinkel, D E; Langdon, A B; Seka, W; Bahr, R; Depierreaux, S

    2005-08-24

    Laser-plasma interactions (LPI) have been studied experimentally in high-temperature, high-energy density plasmas. The studies have been performed using the Omega laser at the Laboratory for Laser Energetics (LLE), Rochester, NY. Up to 10 TW of power was incident upon reduced-scale hohlraums, distributed in three laser beam cones. The hot hohlraums fill quickly with plasma. Late in the laser pulse, most of the laser energy is deposited at the laser entrance hole, where most of the LPI takes place. Due to the high electron temperature, the stimulated Raman scattering (SRS) spectrum extends well beyond {omega}{sub 0}/2, due to the Bohm-Gross shift. This high-temperature, high-energy density regime provides a unique opportunity to study LPI beyond inertial confinement fusion (ICF) conditions.

  15. High-Energy-Density Physics, with Applications to Astrophysics*

    NASA Astrophysics Data System (ADS)

    Remington, Bruce A.

    2002-04-01

    High-energy-density (HED) physics broadly refers to the study of collections of matter under extreme conditions of pressure, temperature, and density. The experimental facilities used for these studies are high power lasers, magnetic pinch generators, and charged particle beams. The HED physics pursued on these facilities is still in its infancy, yet a broad user community has nucleated, and new regimes of experimental science are emerging. [1, 2] Examples drawn from astrophysics include work relevant to supernovae and supernova remnants, astrophysical jets, radiatively driven molecular clouds, accreting black holes, planetary interiors, and gamma-ray bursts. A selection of science highlights in this field from the past decade will be reviewed, and a look ahead to the coming decade will be given. *This work was performed under the auspices of the U.S. Department of Energy by the Lawrence Livermore National Laboratory under Contract No. W-7405-ENG-48. 1. B.A. Remington, D. Arnett, R.P. Drake, and H. Takabe, Science 284, 1488 (1999); Phys. Plasmas 7, 1641 (2000). 2. Hideaki Takabe, Prog. Theor. Phys. Suppl. 143, 202 (2001).

  16. Surprises in High Energy Density Physics

    NASA Astrophysics Data System (ADS)

    Rose, S. J.

    2010-01-01

    Edward Teller's work on what is now called High Energy Density Physics (HEDP) is not so well known as some of his work in other areas of physics. Yet he made substantial contributions since the 1940s and the models that he developed and the problems that he worked on are still relevant today. In this talk we shall look at two major areas in HEDP with the first treated more historically and the second more with a view to recent work that the author and others have undertaken which perhaps indicates future directions.

  17. Lithium-Based High Energy Density Flow Batteries

    NASA Technical Reports Server (NTRS)

    Bugga, Ratnakumar V. (Inventor); West, William C. (Inventor); Kindler, Andrew (Inventor); Smart, Marshall C. (Inventor)

    2014-01-01

    Systems and methods in accordance with embodiments of the invention implement a lithium-based high energy density flow battery. In one embodiment, a lithium-based high energy density flow battery includes a first anodic conductive solution that includes a lithium polyaromatic hydrocarbon complex dissolved in a solvent, a second cathodic conductive solution that includes a cathodic complex dissolved in a solvent, a solid lithium ion conductor disposed so as to separate the first solution from the second solution, such that the first conductive solution, the second conductive solution, and the solid lithium ionic conductor define a circuit, where when the circuit is closed, lithium from the lithium polyaromatic hydrocarbon complex in the first conductive solution dissociates from the lithium polyaromatic hydrocarbon complex, migrates through the solid lithium ionic conductor, and associates with the cathodic complex of the second conductive solution, and a current is generated.

  18. Diagnostic Spectrometers for High Energy Density X-Ray Sources

    NASA Astrophysics Data System (ADS)

    Hudson, L. T.; Henins, A.; Seely, J. F.; Holland, G. E.

    2007-08-01

    A new generation of advanced laser, accelerator, and plasma confinement devices are emerging that are producing extreme states of light and matter that are unprecedented for laboratory study. Examples of such sources that will produce laboratory x-ray emissions with unprecedented characteristics include megajoule-class and ultrafast, ultraintense petawatt laser-produced plasmas; tabletop high-harmonic-generation x-ray sources; high-brightness zeta-pinch and magnetically confined plasma sources; and coherent x-ray free electron lasers and compact inverse-Compton x-ray sources. Characterizing the spectra, time structure, and intensity of x rays emitted by these and other novel sources is critical to assessing system performance and progress as well as pursuing the new and unpredictable physical interactions of interest to basic and applied high-energy-density (HED) science. As these technologies mature, increased emphasis will need to be placed on advanced diagnostic instrumentation and metrology, standard reference data, absolute calibrations and traceability of results. We are actively designing, fabricating, and fielding wavelength-calibrated x-ray spectrometers that have been employed to register spectra from a variety of exotic x-ray sources (electron beam ion trap, electron cyclotron resonance ion source, terawatt pulsed-power-driven accelerator, laser-produced plasmas). These instruments employ a variety of curved-crystal optics, detector technologies, and data acquisition strategies. In anticipation of the trends mentioned above, this paper will focus primarily on optical designs that can accommodate the high background signals produced in HED experiments while also registering their high-energy spectral emissions. In particular, we review the results of recent laboratory testing that explores off-Rowland circle imaging in an effort to reclaim the instrumental resolving power that is increasingly elusive at higher energies when using wavelength

  19. Strongly Interacting Matter at High Energy Density

    SciTech Connect

    McLerran,L.

    2008-09-07

    This lecture concerns the properties of strongly interacting matter (which is described by Quantum Chromodynamics) at very high energy density. I review the properties of matter at high temperature, discussing the deconfinement phase transition. At high baryon density and low temperature, large N{sub c} arguments are developed which suggest that high baryonic density matter is a third form of matter, Quarkyonic Matter, that is distinct from confined hadronic matter and deconfined matter. I finally discuss the Color Glass Condensate which controls the high energy limit of QCD, and forms the low x part of a hadron wavefunction. The Glasma is introduced as matter formed by the Color Glass Condensate which eventually thermalizes into a Quark Gluon Plasma.

  20. High energy density redox flow device

    DOEpatents

    Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan Y; Duduta, Mihai; Limthongkul, Pimpa

    2014-05-13

    Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.

  1. Collapsing Bubble in Metal for High Energy Density Physics Study

    SciTech Connect

    Ng, S F; Barnard, J J; Leung, P T; Yu, S S

    2011-04-13

    This paper presents a new idea to produce matter in the high energy density physics (HEDP) regime in the laboratory using an intense ion beam. A gas bubble created inside a solid metal may collapse by driving it with an intense ion beam. The melted metal will compress the gas bubble and supply extra energy to it. Simulations show that the spherical implosion ratio can be about 5 and at the stagnation point, the maximum density, temperature and pressure inside the gas bubble can go up to nearly 2 times solid density, 10 eV and a few megabar (Mbar) respectively. The proposed experiment is the first to permit access into the Mbar regime with existing or near-term ion facilities, and opens up possibilities for new physics gained through careful comparisons of simulations with measurements of quantities like stagnation radius, peak temperature and peak pressure at the metal wall.

  2. High Energy Density Matter for Rocket Propulsion

    NASA Technical Reports Server (NTRS)

    Carrick, Patrick G.

    1996-01-01

    The objective of the High Energy Density Matter (HEDM) program is to identify, develop, and exploit high energy atomic and molecular systems as energetic sources for rocket propulsion applications. It is a high risk, high payoff program that incorporates both basic and applied research, experimental and theoretical efforts, and science and engineering efforts. The HEDM program is co-sponsored by the Air Force Office of Scientific Research (AFOSR) and the Phillips Laboratory (PURKS). It includes both in-house and contracted University/Industry efforts. Technology developed by the HEDM program offers the opportunity for significant breakthroughs in propulsion system capabilities over the current state-of-the-art. One area of great interest is the use of cryogenic solids to increase the density of the propellant and to act as a stable matrix for storage of energetic materials. No cryogenic solid propellant has ever been used in a rocket, and there remain engineering challenges to such a propellant. However, these solids would enable a wide class of highly energetic materials by providing an environment that is at very low temperatures and is a physical barrier to recombination or energy loss reactions. Previous to our experiments only hydrogen atoms had been isolated in solid hydrogen. To date we have succeeded in trapping B, Al, Li, N, and Mg atoms in solid H2. Small molecules, such as B2 and LiB, are also of interest. Current efforts involve the search for new energetic small molecules, increasing free radical concentrations up to 5 mole percent, and scale-up for propulsion testing.

  3. Alternative Approaches to High Energy Density Fusion

    NASA Astrophysics Data System (ADS)

    Hammer, J.

    2016-10-01

    This paper explores selected approaches to High Energy Density (HED) fusion, beginning with discussion of ignition requirements at the National Ignition Facility (NIF). The needed improvements to achieve ignition are closely tied to the ability to concentrate energy in the implosion, manifested in the stagnation pressure, Pstag. The energy that must be assembled in the imploded state to ignite varies roughly as Pstag-2, so among other requirements, there is a premium on reaching higher Pstag to achieve ignition with the available laser energy. The U.S. inertial confinement fusion program (ICF) is pursuing higher Pstag on NIF through improvements to capsule stability and symmetry. One can argue that recent experiments place an approximate upper bound on the ultimate ignition energy requirement. Scaling the implosions consistently in spatial, temporal and energy scales shows that implosions of the demonstrated quality ignite robustly at 9-15 times the current energy of NIF. While lasers are unlikely to reach that bounding energy, it appears that pulsed-power sources could plausibly do so, giving a range of paths forward for ICF depending on success in improving energy concentration. In this paper, I show the scaling arguments then discuss topics from my own involvement in HED fusion. The recent Viewfactor experiments at NIF have shed light on both the observed capsule drive deficit and errors in the detailed modelling of hohlraums. The latter could be important factors in the inability to achieve the needed symmetry and energy concentration. The paper then recounts earlier work in Fast Ignition and the uses of pulsed-power for HED and fusion applications. It concludes with a description of a method for improving pulsed-power driven hohlraums that could potentially provide a factor of 10 in energy at NTF-like drive conditions and reach the energy bound for indirect drive ICF.

  4. Strongly Interacting Matter at Very High Energy Density

    SciTech Connect

    McLerran, L.

    2011-06-05

    The authors discuss the study of matter at very high energy density. In particular: what are the scientific questions; what are the opportunities to makes significant progress in the study of such matter and what facilities are now or might be available in the future to answer the scientific questions? The theoretical and experimental study of new forms of high energy density matter is still very much a 'wild west' field. There is much freedom for developing new concepts which can have order one effects on the way we think about such matter. It is also a largely 'lawless' field, in that concepts and methods are being developed as new information is generated. There is also great possibility for new experimental discovery. Most of the exciting results from RHIC experiments were unanticipated. The methods used for studying various effects like flow, jet quenching, the ridge, two particle correlations etc. were developed as experiments evolved. I believe this will continue to be the case at LHC and as we use existing and proposed accelerators to turn theoretical conjecture into tangible reality. At some point this will no doubt evolve into a precision science, and that will make the field more respectable, but for my taste, the 'wild west' times are the most fun.

  5. Optimizing liner implosions for high energy density physics experiments

    SciTech Connect

    Ekdahl, C.; Humphries, S. Jr.

    1996-12-31

    Cylindrical metal shells imploded by magnetic fields - liners - are used as kinetic energy drivers for high energy density physics experiments in hydrodynamics and dynamic material property measurements. There are at least three ways in which liners have been, or are expected to be, used to produce high energy density, i.e., high pressure, in target materials. A common approach uses the liner as a convergent flyer plate, which impacts a material target cylinder after having been shocklessly accelerated across an intervening gap. The resultant shock and piston hydrodynamic flow in the target are used in exploration of a wide variety of phenomena and material properties. Another common method is to slowly compress a liner containing a material sample in a such fashion that little heating occurs. This technique is most useful for investigated physical properties at low temperature and extreme density. Finally, one can use a hybrid approach to shock heat with an impacting liner followed by slower adiabatic, if not isentropic, compression to explore material properties in extrema. The magnetic fields for driving these liners may be produced by either high explosive pulsed power generators or by capacitor banks. Here we will consider only capacitor banks.

  6. High energy density physics issues related to Future Circular Collider

    NASA Astrophysics Data System (ADS)

    Tahir, N. A.; Burkart, F.; Schmidt, R.; Shutov, A.; Wollmann, D.; Piriz, A. R.

    2017-07-01

    A design study for a post-Large Hadron Collider accelerator named, Future Circular Collider (FCC), is being carried out by the International Scientific Community. A complete design report is expected to be ready by spring 2018. The FCC will accelerate two counter rotating beams of 50 TeV protons in a tunnel having a length (circumference) of 100 km. Each beam will be comprised of 10 600 proton bunches, with each bunch having an intensity of 1011 protons. The bunch length is of 0.5 ns, and two neighboring bunches are separated by 25 ns. Although there is an option for 5 ns bunch separation as well, in the present studies, we consider the former case only. The total energy stored in each FCC beam is about 8.5 GJ, which is equivalent to the kinetic energy of Airbus 380 (560 t) flying at a speed of 850 km/h. Machine protection is a very important issue while operating with such powerful beams. It is important to have an estimate of the damage caused to the equipment and accelerator components due to the accidental release of a partial or total beam at a given point. For this purpose, we carried out numerical simulations of full impact of one FCC beam on an extended solid copper target. These simulations have been done employing an energy deposition code, FLUKA, and a two-dimensional hydrodynamic code, BIG2, iteratively. This study shows that although the static range of a single FCC proton and its shower is about 1.5 m in solid copper, the entire beam will penetrate around 350 m into the target. This substantial increase in the range is due to the hydrodynamic tunneling of the beam. Our calculations also show that a large part of the target will be converted into high energy density matter including warm dense matter and strongly coupled plasmas.

  7. Studies of high energy density physics and laboratory astrophysics driven by intense lasers

    NASA Astrophysics Data System (ADS)

    Zhang, J.

    2016-10-01

    Laser plasmas are capable of creating unique physical conditions with extreme high energy density, which are not only closely relevant to inertial fusion energy studies, but also to laboratory simulation of some astrophysical processes. In this paper, we highlight some recent progress made by our research teams. The first part is about directional hot electron beam generation and transport for fast ignition of inertial confinement fusion, as well as a new scheme of fast ignition by use of a strong external DC magnetic field. The second part concerns laboratory modeling of some astrophysical phenomena, including 1) studies of the topological structure of magnetic reconnection/annihilation that relates closely to geomagnetic substorms, loop-top X-ray source and mass ejection in solar flares, and 2) magnetic field generation and evolution in collisionless shock formation.

  8. High Energy Density Science at the Linac Coherent Light Source

    SciTech Connect

    Lee, R W

    2007-10-19

    more detailed plans for experiments (Ch. VI), highlighting the uniqueness the HEDS endstation will play in providing mission-relevant HED data and in the development of the field. One of the more exciting aspects of NNSA-relevant experiments on LCLS is that, given the extraordinary investment and consequent advances in accurate atomic-scale simulations of matter (to a large extent via the Accelerated Scientific Computing program sponsored by NNSA), the facility will provide a platform that, for the first time, will permit experiments in the regimes of interest at the time and spatial scales of the simulations. In Chapter III, the report places the potential of LCLS with an HED science endstation in the context of science required by NNSA, as well as explicating the relationship of NNSA and HED science in general. Chapter IV discusses 4th-generation light sources, like LCLS, in the context of other laboratory technologies presently utilized by NNSA. The report concludes, noting that an HED endstation on LCLS can provide access to data in regimes that are relevant to NNSA needs but no mechanism exists for providing such data. The endstation will also serve to build a broad-based community in the 'X-Games' of physics. The science generated by the facility will be a collaboration of NNSA-based laboratory scientists and university-based researchers. The LCLS endstation fulfills the need for an intermediate-scale facility capable of delivering fundamental advances and mission-relevant research in high energy density science.

  9. Anti-Ferroelectric Ceramics for High Energy Density Capacitors

    PubMed Central

    Chauhan, Aditya; Patel, Satyanarayan; Vaish, Rahul; Bowen, Chris R.

    2015-01-01

    With an ever increasing dependence on electrical energy for powering modern equipment and electronics, research is focused on the development of efficient methods for the generation, storage and distribution of electrical power. In this regard, the development of suitable dielectric based solid-state capacitors will play a key role in revolutionizing modern day electronic and electrical devices. Among the popular dielectric materials, anti-ferroelectrics (AFE) display evidence of being a strong contender for future ceramic capacitors. AFE materials possess low dielectric loss, low coercive field, low remnant polarization, high energy density, high material efficiency, and fast discharge rates; all of these characteristics makes AFE materials a lucrative research direction. However, despite the evident advantages, there have only been limited attempts to develop this area. This article attempts to provide a focus to this area by presenting a timely review on the topic, on the relevant scientific advancements that have been made with respect to utilization and development of anti-ferroelectric materials for electric energy storage applications. The article begins with a general introduction discussing the need for high energy density capacitors, the present solutions being used to address this problem, and a brief discussion of various advantages of anti-ferroelectric materials for high energy storage applications. This is followed by a general description of anti-ferroelectricity and important anti-ferroelectric materials. The remainder of the paper is divided into two subsections, the first of which presents various physical routes for enhancing the energy storage density while the latter section describes chemical routes for enhanced storage density. This is followed by conclusions and future prospects and challenges which need to be addressed in this particular field. PMID:28793694

  10. Anti-Ferroelectric Ceramics for High Energy Density Capacitors.

    PubMed

    Chauhan, Aditya; Patel, Satyanarayan; Vaish, Rahul; Bowen, Chris R

    2015-11-25

    With an ever increasing dependence on electrical energy for powering modern equipment and electronics, research is focused on the development of efficient methods for the generation, storage and distribution of electrical power. In this regard, the development of suitable dielectric based solid-state capacitors will play a key role in revolutionizing modern day electronic and electrical devices. Among the popular dielectric materials, anti-ferroelectrics (AFE) display evidence of being a strong contender for future ceramic capacitors. AFE materials possess low dielectric loss, low coercive field, low remnant polarization, high energy density, high material efficiency, and fast discharge rates; all of these characteristics makes AFE materials a lucrative research direction. However, despite the evident advantages, there have only been limited attempts to develop this area. This article attempts to provide a focus to this area by presenting a timely review on the topic, on the relevant scientific advancements that have been made with respect to utilization and development of anti-ferroelectric materials for electric energy storage applications. The article begins with a general introduction discussing the need for high energy density capacitors, the present solutions being used to address this problem, and a brief discussion of various advantages of anti-ferroelectric materials for high energy storage applications. This is followed by a general description of anti-ferroelectricity and important anti-ferroelectric materials. The remainder of the paper is divided into two subsections, the first of which presents various physical routes for enhancing the energy storage density while the latter section describes chemical routes for enhanced storage density. This is followed by conclusions and future prospects and challenges which need to be addressed in this particular field.

  11. The CERN Large Hadron Collider as a tool to study high-energy density matter.

    PubMed

    Tahir, N A; Kain, V; Schmidt, R; Shutov, A; Lomonosov, I V; Gryaznov, V; Piriz, A R; Temporal, M; Hoffmann, D H H; Fortov, V E

    2005-04-08

    The Large Hadron Collider (LHC) at CERN will generate two extremely powerful 7 TeV proton beams. Each beam will consist of 2808 bunches with an intensity per bunch of 1.15x10(11) protons so that the total number of protons in one beam will be about 3x10(14) and the total energy will be 362 MJ. Each bunch will have a duration of 0.5 ns and two successive bunches will be separated by 25 ns, while the power distribution in the radial direction will be Gaussian with a standard deviation, sigma=0.2 mm. The total duration of the beam will be about 89 mus. Using a 2D hydrodynamic code, we have carried out numerical simulations of the thermodynamic and hydrodynamic response of a solid copper target that is irradiated with one of the LHC beams. These calculations show that only the first few hundred proton bunches will deposit a high specific energy of 400 kJ/g that will induce exotic states of high energy density in matter.

  12. A high energy density relaxor antiferroelectric pulsed capacitor dielectric

    SciTech Connect

    Jo, Hwan Ryul; Lynch, Christopher S.

    2016-01-14

    Pulsed capacitors require high energy density and low loss, properties that can be realized through selection of composition. Ceramic (Pb{sub 0.88}La{sub 0.08})(Zr{sub 0.91}Ti{sub 0.09})O{sub 3} was found to be an ideal candidate. La{sup 3+} doping and excess PbO were used to produce relaxor antiferroelectric behavior with slim and slanted hysteresis loops to reduce the dielectric hysteresis loss, to increase the dielectric strength, and to increase the discharge energy density. The discharge energy density of this composition was found to be 3.04 J/cm{sup 3} with applied electric field of 170 kV/cm, and the energy efficiency, defined as the ratio of the discharge energy density to the charging energy density, was 0.920. This high efficiency reduces the heat generated under cyclic loading and improves the reliability. The properties were observed to degrade some with temperature increase above 80 °C. Repeated electric field cycles up to 10 000 cycles were applied to the specimen with no observed performance degradation.

  13. Frontiers in plasma science: a high energy density perspective

    NASA Astrophysics Data System (ADS)

    Remington, Bruce

    2015-11-01

    The potential for ground-breaking research in plasma physics in high energy density (HED) regimes is compelling. The combination of HED facilities around the world spanning microjoules to megajoules, with time scales ranging from femtoseconds to microseconds enables new regimes of plasma science to be experimentally probed. The ability to shock and ramp compress samples and simultaneously probe them allows dense, strongly coupled, Fermi degenerate plasmas relevant to planetary interiors to be studied. Shock driven hydrodynamic instabilities evolving into turbulent flows relevant to the dynamics of exploding stars are being probed. The physics and dynamics of magnetized plasmas relevant to astrophysics and inertial confinement fusion are also starting to be studied. High temperature, high velocity interacting flows are being probed for evidence of astrophysical collisionless shock formation. Turbulent, high magnetic Reynolds number flows are being experimentally generated to look for evidence of the turbulent magnetic dynamo effect. And new results from thermonuclear reactions in dense hot plasmas relevant to stellar interiors are starting to emerge. A selection of examples providing a compelling vision for frontier plasma science in the coming decade will be presented. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

  14. High energy density propulsion systems and small engine dynamometer

    NASA Astrophysics Data System (ADS)

    Hays, Thomas

    2009-07-01

    Scope and Method of Study. This study investigates all possible methods of powering small unmanned vehicles, provides reasoning for the propulsion system down select, and covers in detail the design and production of a dynamometer to confirm theoretical energy density calculations for small engines. Initial energy density calculations are based upon manufacturer data, pressure vessel theory, and ideal thermodynamic cycle efficiencies. Engine tests are conducted with a braking type dynamometer for constant load energy density tests, and show true energy densities in excess of 1400 WH/lb of fuel. Findings and Conclusions. Theory predicts lithium polymer, the present unmanned system energy storage device of choice, to have much lower energy densities than other conversion energy sources. Small engines designed for efficiency, instead of maximum power, would provide the most advantageous method for powering small unmanned vehicles because these engines have widely variable power output, loss of mass during flight, and generate rotational power directly. Theoretical predictions for the energy density of small engines has been verified through testing. Tested values up to 1400 WH/lb can be seen under proper operating conditions. The implementation of such a high energy density system will require a significant amount of follow-on design work to enable the engines to tolerate the higher temperatures of lean operation. Suggestions are proposed to enable a reliable, small-engine propulsion system in future work. Performance calculations show that a mature system is capable of month long flight times, and unrefueled circumnavigation of the globe.

  15. Fourth International Conference on High Energy Density Physics

    SciTech Connect

    Beg, Farhat

    2014-06-30

    The Fourth International Conference on High Energy Density Physics (ICHED 2013) was held in Saint Malo, France, at the Palais du Grand Large on 25-28 June 2013 (http://web.luli.polytechnique.fr/ICHED2013/). This meeting was the fourth in a series which was first held in 2008. This conference covered all the important aspects of High Energy Density Physics including fundamental topics from strong-field physics to creating new states of matter (including radiation-dominated, high-pressure quantum and relativistic plasmas) and ultra-fast lattice dynamics on the timescale of atomic transitions.

  16. Study of Volumetrically Heated Ultra-High Energy Density Plasmas

    SciTech Connect

    Rocca, Jorge J.

    2016-10-27

    Heating dense matter to millions of degrees is important for applications, but requires complex and expensive methods. The major goal of the project was to demonstrate using a compact laser the creation of a new ultra-high energy density plasma regime characterized by simultaneous extremely high temperature and high density, and to study it combining experimental measurements and advanced simulations. We have demonstrated that trapping of intense femtosecond laser pulses deep within ordered nanowire arrays can heat near solid density matter into a new ultra hot plasma regime. Extreme electron densities, and temperatures of several tens of million degrees were achieved using laser pulses of only 0.5 J energy from a compact laser. Our x-ray spectra and simulations showed that extremely highly ionized plasma volumes several micrometers in depth are generated by irradiation of gold and Nickel nanowire arrays with femtosecond laser pulses of relativistic intensities. We obtained extraordinarily high degrees of ionization (e.g. we peeled 52 electrons from gold atoms, and up to 26 electrons from nickel atoms). In the process we generated Gigabar pressures only exceeded in the central hot spot of highly compressed thermonuclear fusion plasmas.. The plasma created after the dissolved wires expand, collide, and thermalize, is computed to have a thermal energy density of 0.3 GJ cm-3 and a pressure of 1-2 Gigabar. These are pressures only exceeded in highly compressed thermonuclear fusion plasmas. Scaling these results to higher laser intensities promises to create plasmas with temperatures and pressures exceeding those in the center of the sun.

  17. High Energy Density Physics and Exotic Acceleration Schemes

    NASA Astrophysics Data System (ADS)

    Cowan, Thomas; Colby, Eric

    2002-12-01

    We summarize the reported results and the principal technical discussions that occurred in our Working Group on High Energy Density Physics and Exotic Acceleration Schemes at the 2002 workshop on Advanced Accelerator Concepts at the Mandalay Beach resort, June 22-28, 2002.

  18. Design for a High Energy Density Kelvin-Helmholtz Experiment

    SciTech Connect

    Hurricane, O A

    2007-10-29

    While many high energy density physics (HEDP) Rayleigh-Taylor and Richtmyer-Meshkov instability experiments have been fielded as part of basic HEDP and astrophysics studies, not one HEDP Kelvin-Helmholtz (KH) experiment has been successfully performed. Herein, a design for a novel HEDP x-ray driven KH experiment is presented along with supporting radiation-hydrodynamic simulation and theory.

  19. Equation of state for titanium at high energy densities

    NASA Astrophysics Data System (ADS)

    Khishchenko, K. V.

    2016-11-01

    A caloric equation-of-state model, which represents the relation of pressure with density and internal energy, is applied for titanium in the bcc and liquid phases. Thermodynamic characteristics along the cold-compression curve at T = 0 and Hugoniots are calculated for the metal and compared with available data from shock-wave experiments at high energy densities.

  20. Hydrodynamic Instabilities in High-Energy-Density Settings

    NASA Astrophysics Data System (ADS)

    Smalyuk, Vladimir

    2016-10-01

    Our understanding of hydrodynamic instabilities, such as the Rayleigh-Taylor (RT), Richtmyer-Meshkov (RM), and Kelvin-Helmholtz (KH) instabilities, in high-energy-density (HED) settings over past two decades has progressed enormously. The range of conditions where hydrodynamic instabilities are experimentally observed now includes direct and indirect drive inertial confinement fusion (ICF) where surprises continue to emerge, linear and nonlinear regimes, classical interfaces vs. stabilized ablation fronts, tenuous ideal plasmas vs. high density Fermi degenerate plasmas, bulk fluid interpenetration vs. mixing down to the atomic level, in the presence of magnetic fields and/or intense radiation, and in solid state plastic flow at high pressures and strain rates. Regimes in ICF can involve extreme conditions of matter with temperatures up to kilovolts, densities of a thousand times solid densities, and time scales of nanoseconds. On the other hand, scaled conditions can be generated that map to exploding stars (supernovae) with length and time scales of millions of kilometers and hours to days or even years of instability evolution, planetary formation dynamics involving solid-state plastic flow which severely modifies the RT growth and continues to challenge reliable theoretical descriptions. This review will look broadly at progress in probing and understanding hydrodynamic instabilities in these very diverse HED settings, and then will examine a few cases in more depth to illustrate the detailed science involved. Experimental results on large-scale HED facilities such as the Omega, Nike, Gekko, and Shenguang lasers will be reviewed and the latest developments at the National Ignition Facility (NIF) and Z machine will be covered. Finally, current overarching questions and challenges will be summarized to motivate research directions for future. This work was performed under the auspices of the U.S. Department of Energy by LLNL under Contract DE-AC52-07NA27344.

  1. Atlas Pulsed Power Facility for High Energy Density Physics Experiments

    SciTech Connect

    Miller, R.B.; Ballard, E.O.; Barr, G.W.; Bowman, D.W.; Chochrane, J.C.; Davis, H.A.; Elizondo, J.M.; Gribble, R.F.; Griego, J.R.; Hicks, R.D.; Hinckley, W.B.; Hosack, K.W.; Nielsen, K.E.; Parker, J.V.; Parsons, M.O.; Rickets, R.L.; Salazar, H.R.; Sanchez, P.G.; Scudder, D.W.; Shapiro, C.; Thompson, M.C.; Trainor, R.J.; Valdez, G.A.; Vigil, B.N.; Watt, R.G.; Wysock, F.J.

    1999-06-07

    The Atlas facility, now under construction at Los Alamos National Laboratory (LANL), will provide a unique capability for performing high-energy-density experiments in support of weapon-physics and basic-research programs. It is intended to be an international user facility, providing opportunities for researchers from national laboratories and academic institutions around the world. Emphasizing institutions around the world. Emphasizing hydrodynamic experiments, Atlas will provide the capability for achieving steady shock pressures exceeding 10-Mbar in a volume of several cubic centimeters. In addition, the kinetic energy associated with solid liner implosion velocities exceeding 12 km/s is sufficient to drive dense, hydrodynamic targets into the ionized regime, permitting the study of complex issues associated with strongly-coupled plasmas. The primary element of Atlas is a 23-MJ capacitor bank, comprised of 96 separate Marx generators housed in 12 separate oil-filled tanks, surrounding a central target chamber. Each tank will house two, independently-removable maintenance units, with each maintenance unit consisting of four Marx modules. Each Marx module has four capacitors that can each be charged to a maximum of 60 kilovolts. When railgap switches are triggered, the marx modules erect to a maximum of 240 kV. The parallel discharge of these 96 Marx modules will deliver a 30-MA current pulse with a 4-5-{micro}s risetime to a cylindrical, imploding liner via 24 vertical, tri-plate, oil-insulated transmission lines. An experimental program for testing and certifying all Marx and transmission line components has been completed. A complete maintenance module and its associated transmission line (the First Article) are now under construction and testing. The current Atlas schedule calls for construction of the machine to be complete by August, 2000. Acceptance testing is scheduled to begin in November, 2000, leading to initial operations in January, 2001.

  2. Relativistic electron beam generator

    DOEpatents

    Mooney, L.J.; Hyatt, H.M.

    1975-11-11

    A relativistic electron beam generator for laser media excitation is described. The device employs a diode type relativistic electron beam source having a cathode shape which provides a rectangular output beam with uniform current density.

  3. Hybrid system for rechargeable magnesium battery with high energy density

    PubMed Central

    Chang, Zheng; Yang, Yaqiong; Wang, Xiaowei; Li, Minxia; Fu, Zhengwen; Wu, Yuping; Holze, Rudolf

    2015-01-01

    One of the main challenges of electrical energy storage (EES) is the development of environmentally friendly battery systems with high safety and high energy density. Rechargeable Mg batteries have been long considered as one highly promising system due to the use of low cost and dendrite-free magnesium metal. The bottleneck for traditional Mg batteries is to achieve high energy density since their output voltage is below 2.0 V. Here, we report a magnesium battery using Mg in Grignard reagent-based electrolyte as the negative electrode, a lithium intercalation compound in aqueous solution as the positive electrode, and a solid electrolyte as a separator. Its average discharge voltage is 2.1 V with stable discharge platform and good cycling life. The calculated energy density based on the two electrodes is high. These findings open another door to rechargeable magnesium batteries. PMID:26173624

  4. High energy-density science on the National Ignition Facility

    SciTech Connect

    Campbell, E.M.; Cauble, R.; Remington, B.A.

    1997-08-01

    The National Ignition Facility, as well as its French counterpart Le Laser Megajoule, have been designed to confront one of the most difficult and compelling problem in shock physics - the creation of a hot, compassed DT plasma surrounded and confined by cold, nearly degenerate DT fuel. At the same time, these laser facilities will present the shock physics community with unique tools for the study of high energy density matter at states unreachable by any other laboratory technique. Here we describe how these lasers can contribute to investigations of high energy density in the area of material properties and equations of state, extend present laboratory shock techniques such as high-speed jets to new regimes, and allow study of extreme conditions found in astrophysical phenomena.

  5. High energy density nanocomposite capacitors using non-ferroelectric nanowires

    NASA Astrophysics Data System (ADS)

    Tang, Haixiong; Sodano, Henry A.

    2013-02-01

    A high energy density nanocomposite capacitor is fabricated by incorporating high aspect ratio functionalized TiO2 nanowires (NWs) into a polyvinylidene-fluoride matrix. These nanocomposites exhibited energy density as high as 12.4 J/cc at 450 MV/m, which is nine times larger than commercial biaxially oriented polypropylene polypropylene capacitors (1.2 J/cc at 640 MV/m). Also, the power density can reach 1.77 MW/cc with a discharge speed of 2.89 μs. The results presented here demonstrate that nanowires can be used to develop nanocomposite capacitors with high energy density and fast discharge speed for future pulsed-power applications.

  6. High Energy Density Non-Aqueous Battery System.

    DTIC Science & Technology

    1983-05-31

    otherwise attractive couple from use. In this report are included, the corrosion studies of calcium and calcium lithium alloys in thionyl chloride ... lithium battery systems have been developed to fulfill the need for long shelf life high energy density batteries. The lithium - thionyl chloride system has... lithium - thionyl chloride battery claimed one life and two injuries (2) (4th of August 1976, Ogden, Utah). Thus lithium batteries have not reached the

  7. High Energy Density Dielectrics for Pulsed Power Applications

    DTIC Science & Technology

    2008-09-01

    next page). 14. ABSTRACT This report was developed under a SBIR contract. Aluminum oxynitride (AlON) capacitors exhibit several promising...characteristics for high energy density capacitor applications in extreme environments. Dielectric constants in the range of 9 and dielectric strength in...properties remain stable from cryogenic temperatures of -200 °C to temperatures above 400 °C. Stacked capacitor devices have been developed and

  8. High energy density capacitor testing for the AFWL SHIVA

    NASA Astrophysics Data System (ADS)

    Smith, D. L.; Reinovsky, R. E.

    Lifetime testing and analysis of small samples of high energy density (HED) discharge capacitors at the AFWL were conducted to find a component suitable for upgrading the SHIVA capacitor bank to a 6 MJ facility. Evaluation was performed with discharge conditions of approximately 250 kA per capacitor at 60 to 70% reversal and 2 microsec quarter period. Dielectric systems including Kraft paper with caster oil impregnant and Kraft paper, polypropylene with DiOctyl Phthalate (DOP) impregnant were tested.

  9. High Energy Density Sciences with High Power Lasers at SACLA

    NASA Astrophysics Data System (ADS)

    Kodama, Ryosuke

    2013-10-01

    One of the interesting topics on high energy density sciences with high power lasers is creation of extremely high pressures in material. The pressures of more than 0.1 TPa are the energy density corresponding to the chemical bonding energy, resulting in expectation of dramatic changes in the chemical reactions. At pressures of more than TPa, most of material would be melted on the shock Hugoniot curve. However, if the temperature is less than 1eV or lower than a melting point at pressures of more than TPa, novel solid states of matter must be created through a pressured phase transition. One of the interesting materials must be carbon. At pressures of more than TPa, the diamond structure changes to BC and cubic at more than 3TPa. To create such novel states of matter, several kinds of isentropic-like compression techniques are being developed with high power lasers. To explore the ``Tera-Pascal Science,'' now we have a new tool which is an x-ray free electron laser as well as high power lasers. The XFEL will clear the details of the HED states and also efficiently create hot dense matter. We have started a new project on high energy density sciences using an XFEL (SACLA) in Japan, which is a HERMES (High Energy density Revolution of Matter in Extreme States) project.

  10. Ultra high energy density and fast discharge nanocomposite capacitors

    NASA Astrophysics Data System (ADS)

    Tang, Haixiong; Sodano, Henry A.

    2013-04-01

    Nanocomposites containing high dielectric permittivity ceramics embedded in high breakdown strength polymers are currently of considerable interest as a solution for the development of high energy density capacitors. However, the improvement of dielectric permittivity comes at expense of the breakdown strength leading to limit the final energy density. Here, an ultra-high energy density nanocomposite was fabricated based on high aspect ratio barium strontium titanate nanowires. The pyroelectric phase Ba0.2Sr0.8TiO3 was chosen for the nanowires combined with quenched PVDF to fabricate high energy density nanocomposite. The energy density with 7.5% Ba0.2Sr0.8TiO3 nanowires reached 14.86 J/cc at 450 MV/m, which represented a 42.9% increase in comparison to the PVDF with an energy density of 10.4 J/cc at the same electric field. The capacitors have 1138% greater than higher energy density than commercial biaxial oriented polypropylene capacitors (1.2 J/cc at 640). These results demonstrate that the high aspect ratio nanowires can be used to produce nanocomposite capacitors with greater performance than the neat polymers thus providing a novel process for the development of future pulsed-power capacitors.

  11. Magnetohydrodynamics of laser-produced high-energy-density plasma in a strong external magnetic field.

    PubMed

    Matsuo, Kazuki; Nagatomo, Hideo; Zhang, Zhe; Nicolai, Philippe; Sano, Takayoshi; Sakata, Shohei; Kojima, Sadaoki; Lee, Seung Ho; Law, King Fai Farley; Arikawa, Yasunobu; Sakawa, Youichi; Morita, Taichi; Kuramitsu, Yasuhiro; Fujioka, Shinsuke; Azechi, Hiroshi

    2017-05-01

    Recent progress in the generation in the laboratory of a strong (>100-T) magnetic field enables us to investigate experimentally unexplored magnetohydrodynamics phenomena of a high-energy-density plasma, which an external magnetic field of 200-300 T notably affects due to anisotropic thermal conduction, even when the magnetic field pressure is much lower than the plasma pressure. The external magnetic field reduces electron thermal conduction across the external magnetic field lines because the Larmor radius of the thermal electrons in the external magnetic field is much shorter than the mean free path of the thermal electrons. The velocity of a thin polystyrene foil driven by intense laser beams in the strong external magnetic field is faster than that in the absence of the external magnetic field. Growth of sinusoidal corrugation imposed initially on the laser-driven polystyrene surface is enhanced by the external magnetic field because the plasma pressure distribution becomes nonuniform due to the external magnetic-field structure modulated by the perturbed plasma flow ablated from the corrugated surface.

  12. Machine learning applied to proton radiography of high-energy-density plasmas

    NASA Astrophysics Data System (ADS)

    Chen, Nicholas F. Y.; Kasim, Muhammad Firmansyah; Ceurvorst, Luke; Ratan, Naren; Sadler, James; Levy, Matthew C.; Trines, Raoul; Bingham, Robert; Norreys, Peter

    2017-04-01

    Proton radiography is a technique extensively used to resolve magnetic field structures in high-energy-density plasmas, revealing a whole variety of interesting phenomena such as magnetic reconnection and collisionless shocks found in astrophysical systems. Existing methods of analyzing proton radiographs give mostly qualitative results or specific quantitative parameters, such as magnetic field strength, and recent work showed that the line-integrated transverse magnetic field can be reconstructed in specific regimes where many simplifying assumptions were needed. Using artificial neural networks, we demonstrate for the first time 3D reconstruction of magnetic fields in the nonlinear regime, an improvement over existing methods, which reconstruct only in 2D and in the linear regime. A proof of concept is presented here, with mean reconstruction errors of less than 5% even after introducing noise. We demonstrate that over the long term, this approach is more computationally efficient compared to other techniques. We also highlight the need for proton tomography because (i) certain field structures cannot be reconstructed from a single radiograph and (ii) errors can be further reduced when reconstruction is performed on radiographs generated by proton beams fired in different directions.

  13. Machine learning applied to proton radiography of high-energy-density plasmas.

    PubMed

    Chen, Nicholas F Y; Kasim, Muhammad Firmansyah; Ceurvorst, Luke; Ratan, Naren; Sadler, James; Levy, Matthew C; Trines, Raoul; Bingham, Robert; Norreys, Peter

    2017-04-01

    Proton radiography is a technique extensively used to resolve magnetic field structures in high-energy-density plasmas, revealing a whole variety of interesting phenomena such as magnetic reconnection and collisionless shocks found in astrophysical systems. Existing methods of analyzing proton radiographs give mostly qualitative results or specific quantitative parameters, such as magnetic field strength, and recent work showed that the line-integrated transverse magnetic field can be reconstructed in specific regimes where many simplifying assumptions were needed. Using artificial neural networks, we demonstrate for the first time 3D reconstruction of magnetic fields in the nonlinear regime, an improvement over existing methods, which reconstruct only in 2D and in the linear regime. A proof of concept is presented here, with mean reconstruction errors of less than 5% even after introducing noise. We demonstrate that over the long term, this approach is more computationally efficient compared to other techniques. We also highlight the need for proton tomography because (i) certain field structures cannot be reconstructed from a single radiograph and (ii) errors can be further reduced when reconstruction is performed on radiographs generated by proton beams fired in different directions.

  14. Magnetohydrodynamics of laser-produced high-energy-density plasma in a strong external magnetic field

    NASA Astrophysics Data System (ADS)

    Matsuo, Kazuki; Nagatomo, Hideo; Zhang, Zhe; Nicolai, Philippe; Sano, Takayoshi; Sakata, Shohei; Kojima, Sadaoki; Lee, Seung Ho; Law, King Fai Farley; Arikawa, Yasunobu; Sakawa, Youichi; Morita, Taichi; Kuramitsu, Yasuhiro; Fujioka, Shinsuke; Azechi, Hiroshi

    2017-05-01

    Recent progress in the generation in the laboratory of a strong (>100 -T) magnetic field enables us to investigate experimentally unexplored magnetohydrodynamics phenomena of a high-energy-density plasma, which an external magnetic field of 200-300 T notably affects due to anisotropic thermal conduction, even when the magnetic field pressure is much lower than the plasma pressure. The external magnetic field reduces electron thermal conduction across the external magnetic field lines because the Larmor radius of the thermal electrons in the external magnetic field is much shorter than the mean free path of the thermal electrons. The velocity of a thin polystyrene foil driven by intense laser beams in the strong external magnetic field is faster than that in the absence of the external magnetic field. Growth of sinusoidal corrugation imposed initially on the laser-driven polystyrene surface is enhanced by the external magnetic field because the plasma pressure distribution becomes nonuniform due to the external magnetic-field structure modulated by the perturbed plasma flow ablated from the corrugated surface.

  15. High-Energy Density science with an ultra-bright x-ray laser

    NASA Astrophysics Data System (ADS)

    Glenzer, Siegfried

    2015-11-01

    This talk will review recent progress in high-energy density physics using the world's brightest x-ray source, the Linac Coherent Light Source, SLAC's free electron x-ray laser. These experiments investigate laser-driven matter in extreme conditions where powerful x-ray scattering and imaging techniques have been applied to resolve ionic interactions at atomic (Ångstrom) scale lengths and to visualize the formation of dense plasma states. Major research areas include dynamic compression experiments of solid targets to determine structural properties and to discover and characterize phase transitions at mega-bar pressures. A second area studies extreme fields produced by high-intensity radiation where fundamental questions of laboratory plasmas can be related to cosmological phenomena. Each of these areas takes advantage of the unique properties of the LCLS x-ray beam. They include small foci for achieving high intensity or high spatial resolution, high photon flux for dynamic structure factor measurements in single shots, and high spectral bandwidth to resolve plasmon (Langmuir) waves or ion acoustic waves in dense plasmas. We will further describe new developments of ultrafast pump-probe technique at high repetition rates. These include studies on dense cryogenic hydrogen that have begun providing fundamental insights into the physical properties of matter in extreme conditions that are important for astrophysics, fusion experiments and generation of radiation sources. This work was supported by DOE Office of Science, Fusion Energy Science under FWP 100182.

  16. Massive parallel simulation of phenomena in condensed matter at high energy density

    NASA Astrophysics Data System (ADS)

    Fortov, Vladimir

    2005-03-01

    This talk deals with computational hydrodynamics, advanced material properties and phenomena at high energy density. New results of massive parallel 3D simulation done with method of individual particles in cells have been obtained. The gas dynamic code includes advanced physical models of matter such as multi-phase equations of state, elastic-plastic, spallation, optic properties and ion-beams stopping. Investigated are the influence on hypervelocity impact processes effects of equation of state, elastic-plastic and spallation. We also report results of numerical modeling of the action of intense heavy ion beams on metallic targets in comparison with new experimental data.

  17. High energy-density physics: From nuclear testing to the superlasers

    SciTech Connect

    Teller, E.; Campbell, E.M.; Holmes, N.C.; Libby, S.B.; Remington, B.A.

    1995-08-14

    The authors describe the role for the next-generation ``superlasers`` in the study of matter under extremely high energy density conditions, in comparison to previous uses of nuclear explosives for this purpose. As examples, the authors focus on three important areas of physics that have unresolved issues which must be addressed by experiment: equations of state, turbulent hydrodynamics, and the transport of radiation. They describe the advantages the large lasers will have in a comprehensive experimental program.

  18. Develop and Perform Experiments for High Energy Density Implosion Systems

    DTIC Science & Technology

    1978-09-20

    high energy density plasma implosion systems. In the area of laser-guided discharges the following tasks have been accomplished: a preliminary analysis of the laser-aerosol-air interactions, which are responsible for initiating laser breakdown, has been performed; and a detailed air chemistry code, CHMAIR, has been developed to follow the evolution of air plasmas created by CO2 lasers and other heating or ionization sources to determine their temperature and chemical composition. Simple hydrodynamic calculations have been performed to predict channel

  19. Rare isotope accelerator project in Korea and its application to high energy density sciences

    NASA Astrophysics Data System (ADS)

    Chung, M.; Chung, Y. S.; Kim, S. K.; Lee, B. J.; Hoffmann, D. H. H.

    2014-01-01

    As a national science project, the Korean government has recently established the Institute for Basic Science (IBS) with the goal of conducting world-class research in basic sciences. One of the core facilities for the IBS will be the rare isotope accelerator which can produce high-intensity rare isotope beams to investigate the fundamental properties of nature, and also to support a broad research program in material sciences, medical and biosciences, and future nuclear energy technologies. The construction of the accelerator is scheduled to be completed by approximately 2017. The design of the accelerator complex is optimized to deliver high average beam current on targets, and to maximize the production of rare isotope beams through the simultaneous use of Isotope Separation On-Line (ISOL) and In-Flight Fragmentation (IFF) methods. The proposed accelerator is, however, not optimal for high energy density science, which usually requires very high peak currents on the target. In this study, we present possible beam-plasma experiments that can be done within the scope of the current accelerator design, and we also investigate possible future extension paths that may enable high energy density science with intense pulsed heavy ion beams.

  20. High-Energy-Density Shear Flow and Instability Experiments

    NASA Astrophysics Data System (ADS)

    Doss, F. W.; Flippo, K. A.; Merritt, E. C.; di Stefano, C. A.; Devolder, B. G.; Kurien, S.; Kline, J. L.

    2016-10-01

    High-energy-density shear experiments have been performed by LANL at the OMEGA Laser Facility and National Ignition Facility (NIF). The experiments have been simulated using the LANL radiation-hydrocode RAGE and have been used to assess turbulence models' ability to function in the high-energy-density, inertial-fusion-relevant regime. Beginning with the basic configuration of two counter-oriented shock-driven flows of > 100 km/s, which initiate a strong shear instability across an initially solid-density, 20 μm thick Al plate, variations of the experiment to details of the initial conditions have been performed. These variations have included increasing the fluid densities (by modifying the plate material from Al to Ti and Cu), imposing sinusoidal seed perturbations on the plate, and directly modifying the plate's intrinsic surface roughness. Radiography of the unseeded layer has revealed the presence of emergent Kelvin-Helmholtz structures which may be analyzed to infer fluid-mechanical properties including turbulent energy density. This work is conducted by the US DOE by LANL under contract DE-AC52-06NA25396.

  1. The National Ignition Facility and the Golden Age of High Energy Density Science

    SciTech Connect

    Moses, E

    2007-08-14

    The National Ignition Facility (NIF) is a 192-beam Nd:glass laser facility being constructed at the Lawrence Livermore National Laboratory (LLNL) to conduct research in inertial confinement fusion (ICF) and high energy density (HED) science. When completed, NIF will produce 1.8 MJ, 500 TW of ultraviolet light, making it the world's largest and highest-energy laser system. The NIF is poised to become the world's preeminent facility for conducting ICF and fusion energy research and for studying matter at extreme densities and temperatures.

  2. The National Ignition Facility and the Golden Age of High Energy Density Science

    SciTech Connect

    Meier, W; Moses, E I; Newton, M

    2007-09-27

    The National Ignition Facility (NIF) is a 192-beam Nd:glass laser facility being constructed at the Lawrence Livermore National Laboratory (LLNL) to conduct research in inertial confinement fusion (ICF) and high energy density (HED) science. When completed, NIF will produce 1.8 MJ, 500 TW of ultraviolet light, making it the world's largest and highest-energy laser system. The NIF is poised to become the world's preeminent facility for conducting ICF and fusion energy research and for studying matter at extreme densities and temperatures.

  3. The Early Years of Indirect Drive Development for High Energy Density Physics Experiments at AWE

    NASA Astrophysics Data System (ADS)

    Thomas, Brian

    2016-10-01

    The importance of laser driven indirect drive for high energy density physics experiments was recognised at A WE in 1971. The two beam 1TW HELEN laser was procured to work in this area and experiments with this system began in 1980. Early experiments in hohlraum coupling and performance scaling with both l.06μm and 0.53μm will be described together with experiments specifically designed to confirm the understanding of radiation wave propagation, hohlraum heating and hohlraum plasma filling. The use of indirect drive for early experiments to study spherical and cylindrical implosions, opacity, EOS, mix and planar radiation hydrodynamics experiments will also be described.

  4. Edge-enriched, porous carbon-based, high energy density supercapacitors for hybrid electric vehicles.

    PubMed

    Kim, Yong Jung; Yang, Cheol-Min; Park, Ki Chul; Kaneko, Katsumi; Kim, Yoong Ahm; Noguchi, Minoru; Fujino, Takeshi; Oyama, Shigeki; Endo, Morinobu

    2012-03-12

    Supercapacitors can store and deliver energy by a simple charge separation, and thus they could be an attractive option to meet transient high energy density in operating fuel cells and in electric and hybrid electric vehicles. To achieve such requirements, intensive studies have been carried out to improve the volumetric capacitance in supercapacitors using various types and forms of carbons including carbon nanotubes and graphenes. However, conventional porous carbons are not suitable for use as electrode material in supercapacitors for such high energy density applications. Here, we show that edge-enriched porous carbons are the best electrode material for high energy density supercapacitors to be used in vehicles as an auxiliary powertrain. Molten potassium hydroxide penetrates well-aligned graphene layers vertically and consequently generates both suitable pores that are easily accessible to the electrolyte and a large fraction of electrochemically active edge sites. We expect that our findings will motivate further research related to energy storage devices and also environmentally friendly electric vehicles. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Sodium pentazolate: A nitrogen rich high energy density material

    NASA Astrophysics Data System (ADS)

    Steele, Brad A.; Oleynik, Ivan I.

    2016-01-01

    Sodium pentazolates NaN5 and Na2N5, new high energy density materials, are discovered during first principles crystal structure search for the compounds of varying amounts of elemental sodium and nitrogen. The pentazole anion (N5-) is stabilized in the condensed phase by sodium Na+ cations at pressures exceeding 20 GPa, and becomes metastable upon release of pressure. The sodium azide (NaN3) precursor is predicted to undergo a chemical transformation above 50 GPa into sodium pentazolates NaN5 and Na2N5. The calculated Raman spectrum of NaN5 is in agreement with the experimental Raman spectrum of a previously unidentified substance appearing upon compression and heating of NaN3.

  6. Local thermodynamic equilibrium in rapidly heated high energy density plasmas

    SciTech Connect

    Aslanyan, V.; Tallents, G. J.

    2014-06-15

    Emission spectra and the dynamics of high energy density plasmas created by optical and Free Electron Lasers (FELs) depend on the populations of atomic levels. Calculations of plasma emission and ionization may be simplified by assuming Local Thermodynamic Equilibrium (LTE), where populations are given by the Saha-Boltzmann equation. LTE can be achieved at high densities when collisional processes are much more significant than radiative processes, but may not be valid if plasma conditions change rapidly. A collisional-radiative model has been used to calculate the times taken by carbon and iron plasmas to reach LTE at varying densities and heating rates. The effect of different energy deposition methods, as well as Ionization Potential Depression are explored. This work shows regimes in rapidly changing plasmas, such as those created by optical lasers and FELs, where the use of LTE is justified, because timescales for plasma changes are significantly longer than the times needed to achieve an LTE ionization balance.

  7. L. V. Al'tshuler, and High Energy Density Research

    NASA Astrophysics Data System (ADS)

    Gibson, Carl H.; Krikorian, Nerses H.; Keeler, R. Norris

    2012-03-01

    Knowledge of high energy densities critical to cosmology and astrophysics was achieved and exchanged among a very few scientists at a time when science was even more constrained by political considerations that it is today. Resources for the early studies necessarily involved atomic weaponry. A history of L. V. Al'tshuler and some others in his science is given in cosmological context. In the beginning of cosmology and the Universe, negative Fortov-Planck1 pressures c7h-1G-2 of 4.6 10115 Pa are overcome by inertial-vortex anti-gravity (dark energy) pressures to achieve a turbulent big bang and the first turbulent combustion with power 1066 watts at the Kolmogorov-Planck scale 10-35 meters. The big bang event ceased when negative- pressure gluon-viscous-forces extracted 10100 kg of mass-energy from the vacuum to produce the observed fossil vorticity turbulence Universe and its inflation with power 10145 watts.

  8. Ammonia-(Dinitramido)boranes: High-Energy-Density Materials.

    PubMed

    Bélanger-Chabot, Guillaume; Rahm, Martin; Haiges, Ralf; Christe, Karl O

    2015-09-28

    Two ammonia-(dinitramido)boranes were synthesized by the reaction of dinitroamine with ammonia-borane. These compounds are the first reported examples of (dinitramido)boranes. Ammonia-mono(dinitramido)borane is a perfectly oxygen-balanced high-energy-density material (HEDM) composed of an ammonia-BH2 fuel group and a strongly oxidizing dinitramido ligand. Although it is thermally not stable enough for practical applications, its predicted specific impulse as a solid rocket propellant would be 333 s. Its predicted performance as an explosive matches that of pentaerythtritol tetranitrate (PETN) and significantly exceeds that of trinitrotoluene (TNT). Its structure was established by X-ray crystallography and vibrational and multinuclear NMR spectroscopy. Additionally, the over-oxidized ammoniabis(dinitramido)borane was detected by NMR spectroscopy. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. CENTER FOR PULSED POWER DRIVEN HIGH ENERGY DENSITY PLASMA STUDIES

    SciTech Connect

    Professor Bruce R. Kusse; Professor David A. Hammer

    2007-04-18

    This annual report summarizes the activities of the Cornell Center for Pulsed-Power-Driven High-Energy-Density Plasma Studies, for the 12-month period October 1, 2005-September 30, 2006. This period corresponds to the first year of the two-year extension (awarded in October, 2005) to the original 3-year NNSA/DOE Cooperative Agreement with Cornell, DE-FC03-02NA00057. As such, the period covered in this report also corresponds to the fourth year of the (now) 5-year term of the Cooperative Agreement. The participants, in addition to Cornell University, include Imperial College, London (IC), the University of Nevada, Reno (UNR), the University of Rochester (UR), the Weizmann Institute of Science (WSI), and the P.N. Lebedev Physical Institute (LPI), Moscow. A listing of all faculty, technical staff and students, both graduate and undergraduate, who participated in Center research activities during the year in question is given in Appendix A.

  10. Theoretically predicted Fox-7 based new high energy density molecules

    NASA Astrophysics Data System (ADS)

    Ghanta, Susanta

    2016-08-01

    Computational investigation of CHNO based high energy density molecules (HEDM) are designed with FOX-7 (1, 1-dinitro 2, 2-diamino ethylene) skeleton. We report structures, stability and detonation properties of these new molecules. A systematic analysis is presented for the crystal density, activation energy for nitro to nitrite isomerisation and the C-NO2 bond dissociation energy of these molecules. The Atoms in molecules (AIM) calculations have been performed to interpret the intra-molecular weak H-bonding interactions and the stability of C-NO2 bonds. The structure optimization, frequency and bond dissociation energy calculations have been performed at B3LYP level of theory by using G03 quantum chemistry package. Some of the designed molecules are found to be more promising HEDM than FOX-7 molecule, and are proposed to be candidate for synthetic purpose.

  11. Laboratory testing of high energy density capacitors for electric vehicles

    NASA Astrophysics Data System (ADS)

    Burke, A. F.

    1991-10-01

    Laboratory tests of advanced, high energy density capacitors in the Battery Test Laboratory of the Idaho National Engineering Laboratory have been performed to investigate their suitability for load-leveling the battery in an electric vehicle. Two types of devices were tested- 3 V, 70 Farad, spiral wound, carbon-based, single cell devices and 20 V, 3. 5 Farad, mixed-oxide, multi-cell bipolar devices. The energy density of the devices, based on energy stored during charge to the rated voltage, was found to be 1-2 W/kg, which agreed well with that claimed by the manufacturers. Constant power discharge tests were performed at power densities up to 1500 W/kg. Discharges at higher power densities could have been performed had equipment been available to maintain constant power during discharges of less than one second. It was found that the capacitance of the devices were rate dependent with the rate dependency of the carbon-based devices being higher than that of the mixed-oxide devices. The resistance of both types of devices were relatively low being 20-30 milliohms. Testing done in the study showed that the advanced high energy density capacitors can be charged and discharged over cycles which approximate the duty cycle that would be encountered if the devices are used to load-level the battery in an electric vehicle. Thermal tests of the advanced capacitors in an insulated environment using the PSFUDS cycle showed the devices do not overheat with their temperatures increasing only 4-5 C for tests that lasted 5-7 hours.

  12. Laser beam generating apparatus

    DOEpatents

    Warner, B.E.; Duncan, D.B.

    1994-02-15

    Laser beam generating apparatus including a septum segment disposed longitudinally within the tubular structure of the apparatus is described. The septum provides for radiatively dissipating heat buildup within the tubular structure and for generating relatively uniform laser beam pulses so as to minimize or eliminate radial pulse delays (the chevron effect). 7 figures.

  13. Laser beam generating apparatus

    DOEpatents

    Warner, Bruce E.; Duncan, David B.

    1994-01-01

    Laser beam generating apparatus including a septum segment disposed longitudinally within the tubular structure of the apparatus. The septum provides for radiatively dissipating heat buildup within the tubular structure and for generating relatively uniform laser beam pulses so as to minimize or eliminate radial pulse delays (the chevron effect).

  14. Laser beam generating apparatus

    DOEpatents

    Warner, Bruce E.; Duncan, David B.

    1993-01-01

    Laser beam generating apparatus including a septum segment disposed longitudinally within the tubular structure of the apparatus. The septum provides for radiatively dissipating heat buildup within the tubular structure and for generating relatively uniform laser beam pulses so as to minimize or eliminate radial pulse delays (the chevron effect).

  15. Laser beam generating apparatus

    DOEpatents

    Warner, B.E.; Duncan, D.B.

    1993-12-28

    Laser beam generating apparatus including a septum segment disposed longitudinally within the tubular structure of the apparatus. The septum provides for radiatively dissipating heat buildup within the tubular structure and for generating relatively uniform laser beam pulses so as to minimize or eliminate radial pulse delays (the chevron effect). 11 figures.

  16. High energy density Z-pinch plasmas using flow stabilization

    SciTech Connect

    Shumlak, U. Golingo, R. P. Nelson, B. A. Bowers, C. A. Doty, S. A. Forbes, E. G. Hughes, M. C. Kim, B. Knecht, S. D. Lambert, K. K. Lowrie, W. Ross, M. P. Weed, J. R.

    2014-12-15

    The ZaP Flow Z-Pinch research project[1] at the University of Washington investigates the effect of sheared flows on MHD instabilities. Axially flowing Z-pinch plasmas are produced that are 100 cm long with a 1 cm radius. The plasma remains quiescent for many radial Alfvén times and axial flow times. The quiescent periods are characterized by low magnetic mode activity measured at several locations along the plasma column and by stationary visible plasma emission. Plasma evolution is modeled with high-resolution simulation codes – Mach2, WARPX, NIMROD, and HiFi. Plasma flow profiles are experimentally measured with a multi-chord ion Doppler spectrometer. A sheared flow profile is observed to be coincident with the quiescent period, and is consistent with classical plasma viscosity. Equilibrium is determined by diagnostic measurements: interferometry for density; spectroscopy for ion temperature, plasma flow, and density[2]; Thomson scattering for electron temperature; Zeeman splitting for internal magnetic field measurements[3]; and fast framing photography for global structure. Wall stabilization has been investigated computationally and experimentally by removing 70% of the surrounding conducting wall to demonstrate no change in stability behavior.[4] Experimental evidence suggests that the plasma lifetime is only limited by plasma supply and current waveform. The flow Z-pinch concept provides an approach to achieve high energy density plasmas,[5] which are large, easy to diagnose, and persist for extended durations. A new experiment, ZaP-HD, has been built to investigate this approach by separating the flow Z-pinch formation from the radial compression using a triaxial-electrode configuration. This innovation allows more detailed investigations of the sheared flow stabilizing effect, and it allows compression to much higher densities than previously achieved on ZaP by reducing the linear density and increasing the pinch current. Experimental results and

  17. Plasma polymerized high energy density dielectric films for capacitors

    NASA Technical Reports Server (NTRS)

    Yamagishi, F. G.

    1983-01-01

    High energy density polymeric dielectric films were prepared by plasma polymerization of a variety of gaseous monomers. This technique gives thin, reproducible, pinhole free, conformable, adherent, and insoluble coatings and overcomes the processing problems found in the preparation of thin films with bulk polymers. Thus, devices are prepared completely in a vacuum environment. The plasma polymerized films prepared all showed dielectric strengths of greater than 1000 kV/cm and in some cases values of greater than 4000 kV/cm were observed. The dielectric loss of all films was generally less than 1% at frequencies below 10 kHz, but this value increased at higher frequencies. All films were self healing. The dielectric strength was a function of the polymerization technique, whereas the dielectric constant varied with the structure of the starting material. Because of the thin films used (thickness in the submicron range) surface smoothness of the metal electrodes was found to be critical in obtaining high dielectric strengths. High dielectric strength graft copolymers were also prepared. Plasma polymerized ethane was found to be thermally stable up to 150 C in the presence of air and 250 C in the absence of air. No glass transitions were observed for this material.

  18. Upgrading of biorenewables to high energy density fuels

    SciTech Connect

    Gordon, John C; Batista, Enrique R; Chen, Weizhong; Currier, Robert P; Dirmyer, Matthew R; John, Kevin D; Kim, Jin K; Keith, Jason; Martin, Richard L; Pierpont, Aaron W; Silks Ill, L. A. "" Pete; Smythe, Mathan C; Sutton, Andrew D; Taw, Felicia L; Trovitch, Ryan J; Vasudevan, Kalyan V; Waidmann, Christopher R; Wu, Ruilian; Baker, R. Thomas; Schlaf, Marcel

    2010-12-07

    According to a recent report, lignocellulose is the most abundant renewable biological resource on earth, with an annual production of {approx} 200 x 10{sup 9} tons. Conversion of lignocellulosics derived from wood, agricultural wastes, and woody grasses into liquid fuels and value-added chemical feedstocks is an active area of research that has seen an explosion of effort due to the need to replace petroleum based sources. The carbohydrates D-glucose (C{sub 6}), L-arabinose (C{sub 5}), and D-xylose (C{sub 5}) are readily obtained from the hydrolysis of lignocellulose and constitute the most abundant renewable organic carbon source on the planet. Because they are naturally produced on such a large scale, these sugars have the greatest potential to displace petrochemical derived transportation fuel. Recent efforts in our laboratories aimed towards the production of high energy density transportation fuels from carbohydrates have been structured around the parameters of selective carbohydrate carbon chain extension chemistries, low reaction temperatures, and the desired use of water or neat substrate as the solvent. Some of our efforts in this regard will be presented.

  19. Improving Robotic Assembly of Planar High Energy Density Targets

    NASA Astrophysics Data System (ADS)

    Dudt, D.; Carlson, L.; Alexander, N.; Boehm, K.

    2016-10-01

    Increased quantities of planar assemblies for high energy density targets are needed with higher shot rates being implemented at facilities such as the National Ignition Facility and the Matter in Extreme Conditions station of the Linac Coherent Light Source. To meet this growing demand, robotics are used to reduce assembly time. This project studies how machine vision and force feedback systems can be used to improve the quantity and quality of planar target assemblies. Vision-guided robotics can identify and locate parts, reducing laborious manual loading of parts into precision pallets and associated teaching of locations. On-board automated inspection can measure part pickup offsets to correct part drop-off placement into target assemblies. Force feedback systems can detect pickup locations and apply consistent force to produce more uniform glue bond thickness, thus improving the performance of the targets. System designs and performance evaluations will be presented. Work supported in part by the US DOE under the Science Undergraduate Laboratory Internships Program (SULI) and ICF Target Fabrication DE-NA0001808.

  20. THE IRON OPACITY PROJECT: High-Energy-Density Plasma Opacities

    NASA Astrophysics Data System (ADS)

    Palay, E.; Orban, C.; Nahar, S.; Pradhan, A.; Pinnsonoault, M.; Bailey, J.

    2013-05-01

    Opacity governs radiation flow in plasma sources. Accurate opacities are needed to model unobservable laboratory and astrophysical conditions. High-energy-density (HED) plasma conditions prevalent in stellar interiors can now be recreated in the laboratory. The Z-pinch fusion device at the Sandia National Lab can reproduce temperatures and densities near the boundary where radiation transport changes from diffusion to convection inside the Sun. To benchmark theoretical opacities experiments are essential to resolve the outstanding discrepancy in solar abundances. The most common volatile elements C, N, O, Ne, etc. have been spectroscopically measured to be up to 50% lower than the standard abundances. This introduces conflict in the derived values of basic solar parameters such as the radiation/convection boundary, sound speed, and the primordial He abundance with precisely measured oscillations of the Sun through Helioseismology. A potential solution is increment of stellar opacities, which has inverse but complex relation with abundacnes, at least 30%. New iron opacity calculations include hitherto neglected atomic physics of fine structure and resonances which are largely treated as lines in existing opacities calculations. Preliminary results on radiative transitions in Ne Partial support: DOE,NSF.

  1. High Energy Density Regenerative Fuel Cell Systems for Terrestrial Applications

    NASA Technical Reports Server (NTRS)

    Burke, Kenneth A.

    1999-01-01

    Regenerative Fuel Cell System (RFCS) technology for energy storage has been a NASA power system concept for many years. Compared to battery-based energy storage systems, RFCS has received relatively little attention or resources for development because the energy density and electrical efficiency were not sufficiently attractive relative to advanced battery systems. Even today, RFCS remains at a very low technology readiness level (TRL of about 2 indicating feasibility has been demonstrated). Commercial development of the Proton Exchange Membrane (PEM) fuel cells for automobiles and other terrestrial applications and improvements in lightweight pressure vessel design to reduce weight and improve performance make possible a high energy density RFCS energy storage system. The results from this study of a lightweight RFCS energy storage system for a remotely piloted, solar-powered, high altitude aircraft indicate an energy density up to 790 w-h/kg with electrical efficiency of 53.4% is attainable. Such an energy storage system would allow a solar-powered aircraft to carry hundreds of kilograms of payload and remain in flight indefinitely for use in atmospheric research, earth observation, resource mapping. and telecommunications. Future developments in the areas of hydrogen and oxygen storage, pressure vessel design, higher temperature and higher- pressure fuel cell operation, unitized regenerative fuel cells, and commercial development of fuel cell technology will improve both the energy density and electrical efficiency of the RFCS.

  2. X-ray Thomson scattering in high energy density plasmas

    SciTech Connect

    Glenzer, Siegfried H.; Redmer, Ronald

    2009-10-15

    Accurate x-ray scattering techniques to measure the physical properties of dense plasmas have been developed for applications in high energy density physics. This class of experiments produces short-lived hot dense states of matter with electron densities in the range of solid density and higher where powerful penetrating x-ray sources have become available for probing. Experiments have employed laser-based x-ray sources that provide sufficient photon numbers in narrow bandwidth spectral lines, allowing spectrally resolved x-ray scattering measurements from these plasmas. The backscattering spectrum accesses the noncollective Compton scattering regime which provides accurate diagnostic information on the temperature, density, and ionization state. The forward scattering spectrum has been shown to measure the collective plasmon oscillations. Besides extracting the standard plasma parameters, density and temperature, forward scattering yields new observables such as a direct measure of collisions and quantum effects. Dense matter theory relates scattering spectra with the dielectric function and structure factors that determine the physical properties of matter. Applications to radiation-heated and shock-compressed matter have demonstrated accurate measurements of compression and heating with up to picosecond temporal resolution. The ongoing development of suitable x-ray sources and facilities will enable experiments in a wide range of research areas including inertial confinement fusion, radiation hydrodynamics, material science, or laboratory astrophysics.

  3. Metrology Challenges for High Energy Density Science Target Manufacture

    SciTech Connect

    Seugling, R M; Bono, M J; Davis, P

    2009-02-19

    Currently, High Energy Density Science (HEDS) experiments are used to support and qualify predictive physics models. These models assume ideal conditions such as energy (input) and device (target) geometry. The experiments rely on precision targets constructed from components with dimensions in the millimeter range, while having micrometer-scale, functional features, including planar steps, sine waves, and step-joint geometry on hemispherical targets. Future target designs will likely have features and forms that rival or surpass current manufacturing and characterization capability. The dimensional metrology of these features is important for a number of reasons, including qualification of sub-components prior to assembly, quantification of critical features on the as-built assemblies and as a feedback mechanism for fabrication process development. Variations in geometry from part to part can lead to functional limitations, such as unpredictable instabilities during an experiment and the inability to assemble a target from poorly matched sub-components. Adding to the complexity are the large number and variety of materials, components, and shapes that render any single metrology technique difficult to use with low uncertainty. Common materials include metal and glass foams, doped transparent and opaque plastics and a variety of deposited and wrought metals. A suite of metrology tools and techniques developed to address the many critical issues relevant to the manufacture of HEDS targets including interferometry, x-ray radiography and contact metrology are presented including two sided interferometry for absolute thickness metrology and low force probe technology for micrometer feature coordinate metrology.

  4. Nuclear isomers as ultra-high-energy-density materials

    NASA Astrophysics Data System (ADS)

    Poppe, C. H.; Weiss, M. S.; Anderson, J. D.

    1992-09-01

    A major energy advance could result if the enormous potential of nuclear energy storage could be tapped without the penalty of radioactive by-products. Recent research has uncovered a new method for nuclear energy storage with high energy density and no residual radioactivity. Nuclear isomers are metastable states of atomic nuclei which release their energy in a prompt burst of electromagnetic radiation; in many cases the product remaining after decay of isomer is stable and no activity is produced by the electromagnetic decay. Two kinds of nuclear isomers are known: spin isomers and shape isomers. The former lacks a release mechanism. Theory has predicted the existence of shape isomers in the mass range around mercury and gold where decay by fission is prohibited. Experiments on the existence of fissionless shape isomers have resulted in evidence for 27 different shape isomers in isotopes of mercury, lead, and thallium. Three potential candidates for release mechanisms have been identified to date: neutron catalysis (Hf- 178), laser-electron-nuclear coupling (Th-229), and Stark-shift-induced mixing (speculative). Ways of producing nonfissioning shape isomers are discussed.

  5. Demonstration of x-ray fluorescence imaging of a high-energy-density plasma.

    PubMed

    MacDonald, M J; Keiter, P A; Montgomery, D S; Biener, M M; Fein, J R; Fournier, K B; Gamboa, E J; Klein, S R; Kuranz, C C; LeFevre, H J; Manuel, M J-E; Streit, J; Wan, W C; Drake, R P

    2014-11-01

    Experiments at the Trident Laser Facility have successfully demonstrated the use of x-ray fluorescence imaging (XRFI) to diagnose shocked carbonized resorcinol formaldehyde (CRF) foams doped with Ti. One laser beam created a shock wave in the doped foam. A second laser beam produced a flux of vanadium He-α x-rays, which in turn induced Ti K-shell fluorescence within the foam. Spectrally resolved 1D imaging of the x-ray fluorescence provided shock location and compression measurements. Additionally, experiments using a collimator demonstrated that one can probe specific regions within a target. These results show that XRFI is a capable alternative to path-integrated measurements for diagnosing hydrodynamic experiments at high energy density.

  6. Demonstration of x-ray fluorescence imaging of a high-energy-density plasma

    SciTech Connect

    MacDonald, M. J. Gamboa, E. J.; Keiter, P. A.; Fein, J. R.; Klein, S. R.; Kuranz, C. C.; LeFevre, H. J.; Manuel, M. J.-E.; Wan, W. C.; Drake, R. P.; Montgomery, D. S.; Biener, M. M.; Fournier, K. B.; Streit, J.

    2014-11-15

    Experiments at the Trident Laser Facility have successfully demonstrated the use of x-ray fluorescence imaging (XRFI) to diagnose shocked carbonized resorcinol formaldehyde (CRF) foams doped with Ti. One laser beam created a shock wave in the doped foam. A second laser beam produced a flux of vanadium He-α x-rays, which in turn induced Ti K-shell fluorescence within the foam. Spectrally resolved 1D imaging of the x-ray fluorescence provided shock location and compression measurements. Additionally, experiments using a collimator demonstrated that one can probe specific regions within a target. These results show that XRFI is a capable alternative to path-integrated measurements for diagnosing hydrodynamic experiments at high energy density.

  7. Potential of FAIR at Darmstadt and LHC at CERN for High Energy Density Physics Research: the HEDgeHOB Collaboration

    NASA Astrophysics Data System (ADS)

    Tahir, Naeem A.; Shutov, Alexander; Lomonosov, Igor; Piriz, A. R.; Schmidt, Ruediger; Hoffmann, Dieter H. H.; Deutsch, Claude

    2009-11-01

    Substantial progress in the development of technology of high quality, well focused, strongly bunched intense partile beams have led to development of a novel, very efficient technique of studying High Energy Density Matter (HEDM) in the laboratory. This method involves generation of large samples of HEDM by isochoric and uniform heating of solid targets by these ion beams. Two huge accelerator projects are on the way in Europe. One is the Facility for Antiiprotons and Ion Research (FAIR), at Darmstadt and the other is the Large Hadron Collider (LHC) at CERN. Extensive theoretical work has been carried out over the past years to assess the potential of these accelerators to generate HEDM and several experimental schemes have been proposed [1-4]. A brief overview of this work is presented in this talk. [1] N.A. Tahir et al., PRL 95 (2005) 035001. [2] N.A. Tahir et al., PRL 94 (2005) 135004. [3] N.A. Tahir et al., Nucl. Instr. Meth. A 577 (2007) 238. [4] N.A. tahir et al., PRE 79 (2009) in print.

  8. High energy density capacitors using nano-structure multilayer technology

    SciTech Connect

    Barbee, T.W. Jr.; Johnson, G.W.; O`Brien, D.W.

    1992-08-01

    Today, many pulse power and industrial applications are limited by capacitor performance. While incremental improvements are anticipated from existing capacitor technologies, significant advances are needed in energy density to enable these applications for both the military and for American economic competitiveness. We propose a program to research and develop a novel technology for making high voltage, high energy density capacitors. Nano-structure multilayer technologies developed at LLNL may well provide a breakthrough in capacitor performance. Our controlled sputtering techniques are capable of laying down extraordinarily smooth sub-micron layers of dielectric and conductor materials. With this technology, high voltage capacitors with an order of magnitude improvement in energy density may be achievable. Well-understood dielectrics and new materials will be investigated for use with this technology. Capacitors developed by nano-structure multilayer technology are inherently solid state, exhibiting extraordinary mechanical and thermal properties. The conceptual design of a Notepad capacitor is discussed to illustrate capacitor and capacitor bank design and performance with this technology. We propose a two phase R&D program to address DNA`s capacitor needs for electro-thermal propulsion and similar pulse power programs. Phase 1 will prove the concept and further our understanding of dielectric materials and design tradeoffs with multilayers. Nano-structure multilayer capacitors will be developed and characterized. As our materials research and modeling prove successful, technology insertion in our capacitor designs will improve the possibility for dramatic performance improvements. In Phase 2, we will make Notepad capacitors, construct a capacitor bank and demonstrate its performance in a meaningful pulse power application. We will work with industrial partners to design full scale manufacturing and move this technology to industry for volume production.

  9. Characterizing high-energy-density propellants for space propulsion applications

    NASA Astrophysics Data System (ADS)

    Kokan, Timothy

    There exists wide ranging research interest in high-energy-density matter (HEDM) propellants as a potential replacement for existing industry standard fuels for liquid rocket engines. The U.S. Air Force Research Laboratory, the U.S. Army Research Lab, the NASA Marshall Space Flight Center, and the NASA Glenn Research Center each either recently concluded or currently has ongoing programs in the synthesis and development of these potential new propellants. In order to perform conceptual designs using these new propellants, most conceptual rocket engine powerhead design tools (e.g. NPSS, ROCETS, and REDTOP-2) require several thermophysical properties of a given propellant over a wide range of temperature and pressure. These properties include enthalpy, entropy, density, viscosity, and thermal conductivity. Very little thermophysical property data exists for most of these potential new HEDM propellants. Experimental testing of these properties is both expensive and time consuming and is impractical in a conceptual vehicle design environment. A new technique for determining these thermophysical properties of potential new rocket engine propellants is presented. The technique uses a combination of three different computational methods to determine these properties. Quantum mechanics and molecular dynamics are used to model new propellants at a molecular level in order to calculate density, enthalpy, and entropy. Additivity methods are used to calculate the kinematic viscosity and thermal conductivity of new propellants. This new technique is validated via a series of verification experiments of HEDM compounds. Results are provided for two HEDM propellants: quadricyclane and 2-azido-N,N-dimethylethanamine (DMAZ). In each case, the new technique does a better job than the best current computational methods at accurately matching the experimental data of the HEDM compounds of interest. A case study is provided to help quantify the vehicle level impacts of using HEDM

  10. High-Energy Density science at the Linac Coherent Light Source

    SciTech Connect

    Glenzer, S. H.; Fletcher, L. B.; Hastings, J. B.

    2016-04-01

    The Matter in Extreme Conditions end station at the Linac Coherent Light Source holds great promise for novel pump-probe experiments to make new discoveries in high- energy density science. Recently, our experiments have demonstrated the first spectrally- resolved measurements of plasmons using a seeded 8-keV x-ray laser beam. Forward x-ray Thomson scattering spectra from isochorically heated solid aluminum show a well-resolved plasmon feature that is down-shifted in energy by 19 eV from the incident 8 keV elastic scattering feature. In this spectral range, the simultaneously measured backscatter spectrum shows no spectral features indicating observation of collective plasmon oscillations on a scattering length comparable to the screening length. Moreover, this technique is a prerequisite for Thomson scattering measurements in compressed matter where the plasmon shift is a sensitive function of the free electron density and where the plasmon intensity provides information on temperature.

  11. Development of experimental platform for high energy density sciences using high-intensity optical lasers at the SACLA x-ray free electron laser facility

    NASA Astrophysics Data System (ADS)

    Yabuuchi, Toshinori; Yabashi, Makina; Inubushi, Yuichi; Kon, Akira; Togashi, Tadashi; Tomizawa, Hiromitsu

    2016-10-01

    Combinations of high intensity optical laser and x-ray free electron laser (XFEL) open new frontiers in high energy density (HED) sciences. An experimental platform equipped with high-power Ti:Sapphire laser systems is under commissioning for HED sciences at the XFEL facility, SACLA. The Ti:Sapphire laser system is designed to deliver two laser beams with a maximum power of 500 TW in each to the sample chamber. A hard x-ray beamline of SACLA is also transported to the chamber with a beam focusing capability down to a few microns using sets of compound refractive lenses. The second optical laser pulse or the energetic particles and photons generated by the laser pulse can provide additional flexibilities for HED-related pump-probe experiments, which have been generally performed using single optical laser and XFEL. The development status and future perspectives of the experimental platform will be presented.

  12. Monoenergetic proton backlighter for measuring E and B fields and for radiographing implosions and high-energy density plasmas (invited)

    SciTech Connect

    Li, C. K.; Seguin, F. H.; Frenje, J. A.; Rygg, J. R.; Petrasso, R. D.; Town, R. P. J.; Amendt, P. A.; Hatchett, S. P.; Landen, O. L.; Mackinnon, A. J.; Patel, P. K.; Smalyuk, V. A.; Knauer, J. P.; Sangster, T. C.; Stoeckl, C.

    2006-10-15

    A novel monoenergetic proton backlighter source and matched imaging detector have been utilized on the OMEGA laser system to study electric (E) and magnetic (B) fields generated by laser-plasma interactions and will be utilized in the future to radiograph implosions and high-energy density (HED) plasmas. The backlighter consists of an imploding glass microballoon with D {sup 3}He fuel, producing 14.7 MeV D {sup 3}He protons and 3 MeV DD protons that are then passed through a mesh that divides the protons into beamlets. For quantitative study of E+B field structure, monoenergetic protons have several unique advantages compared to the broad energy spectrum used in previous experiments. Recent experiments have been performed with a single laser beam (intensity of {approx}10{sup 14} W/cm{sup 2}) interacting with a CH foil, and B fields of {approx}0.5 MG and E fields of {approx}1.5x10{sup 8} V/m have been measured using proton deflectometry. LASNEX simulations are being used to interpret these experiments. Additional information will also be presented on the application of this technique to measuring E and B fields associated with Hohlraums and directly driven implosions, to radiographically mapping the areal density ({rho}R) distribution in imploded capsules, and to radiographing HED plasmas.

  13. Laser-Plasma Interactions in High-Energy-Density Plasmas

    SciTech Connect

    Baldis, H

    2006-10-17

    High temperature hohlraums (HTH) are designed to reach high radiation temperatures by coupling a maximum amount of laser energy into a small target in a short time. These 400-800 {micro}m diameter gold cylinders rapidly fill with hot plasma during irradiation with multiple beams in 1ns laser pulses. The high-Z plasmas are dense, (electron density, n{sub e}/n{sub c} {approx} 0.1-0.4), hot (electron temperature, T{sub e} {approx} 10keV) and are bathed in a high-temperature radiation field (radiation temperature, T{sub rad} {approx} 300eV). Here n{sub c}, the critical density, equals 9 x 10{sup 21}/cm{sup 3}. The laser beams heating this plasma are intense ({approx} 10{sup 15} - 10{sup 17} W/cm{sup 2}). The coupling of the laser to the plasma is a rich regime for Laser-Plasma Interaction (LPI) physics. The LPI mechanisms in this study include beam deflection and forward scattering. In order to understand the LPI mechanisms, the plasma parameters must be known. An L-band spectrometer is used to measure the and electron temperature. A ride-along experiment is to develop the x-radiation emitted by the thin back wall of the half-hohlraum into a thermal radiation source.

  14. High Energy Density Battery Lithium Thionyl Chloride Improved Reverse Voltage Design.

    DTIC Science & Technology

    1981-12-01

    BATTERY LITHIUM THIONYL CHLORIDE IMPROVED R-ETC(U) DEC 81 A E ZOLLA N660011-C-0310...HIGH ENERGY DENSITY BATTERY LITHIUM THIONYL CHLORIDE IMPROVED REVERSE VOLTAGE DESIGN Dr. A. E. Zolla Altus Corporation C:1 1610 Crane Court San Jose...reverse aide If necesary and identify by block number) Lithium Battery Lithium Thionyl Chloride High Energy Density Battery Voltage Reversal Battery

  15. TEMPO-based catholyte for high-energy density nonaqueous redox flow batteries.

    PubMed

    Wei, Xiaoliang; Xu, Wu; Vijayakumar, Murugesan; Cosimbescu, Lelia; Liu, Tianbiao; Sprenkle, Vincent; Wang, Wei

    2014-12-03

    A TEMPO-based non-aqueous electrolyte with the TEMPO concentration as high as 2.0 m is demonstrated as a high-energy-density catholyte for redox flow battery applications. With a hybrid anode, Li|TEMPO flow cells using this electrolyte deliver an energy efficiency of ca. 70% and an impressively high energy density of 126 W h L(-1) .

  16. Note: Experimental platform for magnetized high-energy-density plasma studies at the omega laser facility.

    PubMed

    Fiksel, G; Agliata, A; Barnak, D; Brent, G; Chang, P-Y; Folnsbee, L; Gates, G; Hasset, D; Lonobile, D; Magoon, J; Mastrosimone, D; Shoup, M J; Betti, R

    2015-01-01

    An upgrade of the pulsed magnetic field generator magneto-inertial fusion electrical discharge system [O. Gotchev et al., Rev. Sci. Instrum. 80, 043504 (2009)] is described. The device is used to study magnetized high-energy-density plasma and is capable of producing a pulsed magnetic field of tens of tesla in a volume of a few cubic centimeters. The magnetic field is created by discharging a high-voltage capacitor through a small wire-wound coil. The coil current pulse has a duration of about 1 μs and a peak value of 40 kA. Compared to the original, the updated version has a larger energy storage and improved switching system. In addition, magnetic coils are fabricated using 3-D printing technology which allows for a greater variety of the magnetic field topology.

  17. Note: Experimental platform for magnetized high-energy-density plasma studies at the omega laser facility

    NASA Astrophysics Data System (ADS)

    Fiksel, G.; Agliata, A.; Barnak, D.; Brent, G.; Chang, P.-Y.; Folnsbee, L.; Gates, G.; Hasset, D.; Lonobile, D.; Magoon, J.; Mastrosimone, D.; Shoup, M. J.; Betti, R.

    2015-01-01

    An upgrade of the pulsed magnetic field generator magneto-inertial fusion electrical discharge system [O. Gotchev et al., Rev. Sci. Instrum. 80, 043504 (2009)] is described. The device is used to study magnetized high-energy-density plasma and is capable of producing a pulsed magnetic field of tens of tesla in a volume of a few cubic centimeters. The magnetic field is created by discharging a high-voltage capacitor through a small wire-wound coil. The coil current pulse has a duration of about 1 μs and a peak value of 40 kA. Compared to the original, the updated version has a larger energy storage and improved switching system. In addition, magnetic coils are fabricated using 3-D printing technology which allows for a greater variety of the magnetic field topology.

  18. A 100 J-level nanosecond DPSSL for high energy density experiments

    NASA Astrophysics Data System (ADS)

    Butcher, Thomas; Mason, Paul; Banerjee, Saumyabrata; Ertel, Klaus; Phillips, P. Jonathan; Smith, Jodie; De Vido, Mariastefania; Chekhlov, Oleg; Divoky, Martin; Pilat, Jan; Priebe, Gerd; Toncian, Toma; Shaikh, Waseem; Hooker, Chris; Lucianetti, Antonio; Hernandez-Gomez, Cristina; Mocek, Tomas; Edwards, Chris; Collier, John

    2017-05-01

    We present an overview of the cryo-amplifier concept and design utilized in the DiPOLE100 laser system built for use at the HiLASE Center, which has been successfully tested operating at an average power of 1kW. Following this we describe the alterations made to the design in the second generation system being constructed for high energy density (HED) experiments in the HED beamline at the European XFEL. These changes are predominantly geometric in nature, however also include improved mount design and improved control over the temporal shape of the output pulse. Finally, we comment on future plans for development of the DiPOLE laser amplifier architecture.

  19. Note: Experimental platform for magnetized high-energy-density plasma studies at the omega laser facility

    SciTech Connect

    Fiksel, G.; Agliata, A.; Barnak, D.; Brent, G.; Chang, P. -Y.; Folnsbee, L.; Gates, G.; Hasset, D.; Lonobile, D.; Magoon, J.; Mastrosimone, D.; Shoup, III, M. J.; Betti, R.

    2015-01-12

    Here, an upgrade of the pulsed magnetic field generator magneto-inertial fusion electrical discharge system [O. Gotchev et al., Rev. Sci. Instrum. 80, 043504 (2009)] is described. The device is used to study magnetized high-energy-density plasma and is capable of producing a pulsed magnetic field of tens of tesla in a volume of a few cubic centimeters. The magnetic field is created by discharging a high-voltage capacitor through a small wire-wound coil. The coil current pulse has a duration of about 1 μs and a peak value of 40 kA. Compared to the original, the updated version has a larger energy storage and improved switching system. In addition, magnetic coils are fabricated using 3-D printing technology which allows for a greater variety of the magnetic field topology.

  20. Note: Experimental platform for magnetized high-energy-density plasma studies at the omega laser facility

    DOE PAGES

    Fiksel, G.; Agliata, A.; Barnak, D.; ...

    2015-01-12

    Here, an upgrade of the pulsed magnetic field generator magneto-inertial fusion electrical discharge system [O. Gotchev et al., Rev. Sci. Instrum. 80, 043504 (2009)] is described. The device is used to study magnetized high-energy-density plasma and is capable of producing a pulsed magnetic field of tens of tesla in a volume of a few cubic centimeters. The magnetic field is created by discharging a high-voltage capacitor through a small wire-wound coil. The coil current pulse has a duration of about 1 μs and a peak value of 40 kA. Compared to the original, the updated version has a larger energymore » storage and improved switching system. In addition, magnetic coils are fabricated using 3-D printing technology which allows for a greater variety of the magnetic field topology.« less

  1. A novel zirconium Kα imager for high energy density physics research.

    PubMed

    Akli, K U; Sanchez del Rio, M; Jiang, S; Storm, M S; Krygier, A; Stephens, R B; Pereira, N R; Baronova, E O; Theobald, W; Ping, Y; McLean, H S; Patel, P K; Key, M H; Freeman, R R

    2011-12-01

    We report on the development and characterization of a zirconium Kα imager for high energy density physics research. The imager consists of a spherically bent quartz crystal operating at 15.7 keV photon energy. We compare the performance of the imager in terms of integrated reflectivity (R(int)) and temperature dependent collection efficiency (η(Te)) to that of the widely used Cu Kα imager. Our collisional-radiative simulations show that the new imager can be reliably used up to 250 eV plasma temperature. Monte Carlo simulations show that for a 25 μm thick tracer layer of zirconium, the contribution to Kα production from photo-pumping is only 2%. We present, for the first time, 2D spatially resolved images of zirconium plasmas generated by a high intensity short pulse laser interacting with Zr solid targets.

  2. Ion beam generating apparatus

    DOEpatents

    Brown, Ian G.; Galvin, James

    1987-01-01

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam.

  3. High Energy Density Physics technical quarterly, October--December 1994. Volume 3

    SciTech Connect

    1995-09-01

    The High Energy Density Physics Technical Quarterly (formerly the AGEX 2 Technical Quarterly) publishes short technical contributions on above ground experiments that use pulsed power and laser drivers. The Quarterly is intended to provide rapid exposure of timely technical ideas and results as well as a means for documenting High Energy Density Physics progress and scientific quality for the High Energy Density Physics community. Two articles are included in this volume. They are ``Simulation and Analysis of PEGII-25`` and ``Resistor Developments for Atlas Marx Modules``.

  4. Light beam frequency comb generator

    DOEpatents

    Priatko, G.J.; Kaskey, J.A.

    1992-11-24

    A light beam frequency comb generator uses an acousto-optic modulator to generate a plurality of light beams with frequencies which are uniformly separated and possess common noise and drift characteristics. A well collimated monochromatic input light beam is passed through this modulator to produce a set of both frequency shifted and unshifted optical beams. An optical system directs one or more frequency shifted beams along a path which is parallel to the path of the input light beam such that the frequency shifted beams are made incident on the modulator proximate to but separated from the point of incidence of the input light beam. After the beam is thus returned to and passed through the modulator repeatedly, a plurality of mutually parallel beams are generated which are frequency-shifted different numbers of times and possess common noise and drift characteristics. 2 figs.

  5. Light beam frequency comb generator

    DOEpatents

    Priatko, Gordon J.; Kaskey, Jeffrey A.

    1992-01-01

    A light beam frequency comb generator uses an acousto-optic modulator to generate a plurality of light beams with frequencies which are uniformly separated and possess common noise and drift characteristics. A well collimated monochromatic input light beam is passed through this modulator to produce a set of both frequency shifted and unshifted optical beams. An optical system directs one or more frequency shifted beams along a path which is parallel to the path of the input light beam such that the frequency shifted beams are made incident on the modulator proximate to but separated from the point of incidence of the input light beam. After the beam is thus returned to and passed through the modulator repeatedly, a plurality of mutually parallel beams are generated which are frequency-shifted different numbers of times and possess common noise and drift characteristics.

  6. Development of novel cathodes for high energy density lithium batteries

    NASA Astrophysics Data System (ADS)

    Bhargav, Amruth

    Lithium based batteries have become ubiquitous with our everyday life. They have propelled a generation of smart personal electronics and electric transport. Their use is now percolating to various fields as a source of energy to facilitate the operation of devices from nanoscale to mega scale. This need for a portable energy source has led to tremendous scientific interest in this field to develop electrochemical devices like batteries with higher capacities, longer cycle life and increased safety at a low cost. To this end, the research presented in this thesis focuses on two emerging and promising technologies called lithium-oxygen (Li-O2) and lithium-sulfur (Li-S) batteries. These batteries can offer an order of magnitude higher capacities through cheap, environmentally safe and abundant elements namely oxygen and sulfur. The first work introduces the concept of closed system lithium-oxygen batteries wherein the cell contains the discharge product of Li-O2 batteries namely, lithium peroxide (Li2O2) as the starting active material. The reversibility of this system is analyzed along with its rate performance. The possible use of such a cathode in a full cell is explored. Also, this concept is used to verify if all the lithium can be extracted from the cathode in the first charge. In the following work, lithium peroxide is chemically synthesized and deposited in a carbon nanofiber matrix. This forms a free standing cathode that shows high reversibility. It can be cycled up to 20 times and while using capacity control protocol, a cycle life of 50 is obtained. The cause of cell degradation and failure is also analyzed. In the work on full cell lithium-sulfur system, a novel electrolyte is developed that can support reversible lithium insertion and extraction from a graphite anode. A method to deposit solid lithium polysulfide is developed for the cathode. Coupling a lithiated graphite anode with the cathode using the new electrolyte yields a full cell whose

  7. High energy density interpenetrating networks from ionic networks and silicone

    NASA Astrophysics Data System (ADS)

    Yu, Liyun; Madsen, Frederikke B.; Hvilsted, Søren; Skov, Anne L.

    2015-04-01

    The energy density of dielectric elastomers (DEs) is sought increased for better exploitation of the DE technology since an increased energy density means that the driving voltage for a certain strain can be lowered in actuation mode or alternatively that more energy can be harvested in generator mode. One way to increase the energy density is to increase dielectric permittivity of the elastomer. A novel silicone elastomer system with high dielectric permittivity was prepared through the development of interpenetrating networks from ionically assembled silicone polymers and covalently crosslinked silicones. The system has many degrees of freedom since the ionic network is formed from two polymers (amine and carboxylic acid functional, respectively) of which the chain lengths can be varied, as well as the covalent silicone elastomer with many degrees of freedom arising from amongst many the varying content of silica particles. A parameter study is performed to elucidate which compositions are most favorable for the use as dielectric elastomers. The elastomers were furthermore shown to be self-repairing upon electrical breakdown.

  8. Series asymmetric supercapacitors based on free-standing inner-connection electrodes for high energy density and high output voltage.

    PubMed

    Tao, Jiayou; Liu, Nishuang; Rao, Jiangyu; Ding, Longwei; Al Bahrani, Majid Raissan; Li, Luying; Su, Jun; Gao, Yihua

    2014-12-21

    Asymmetric supercapacitors (ASCs) based on free-standing membranes with high energy density and high output voltage are reported. MnO(2) nanowire/carbon nanotube (CNT) composites and MoO(3) nanobelt/CNT composites are selected as the anode and the cathode materials of the devices, respectively. The ASC has a high volumetric capacitance of 50.2 F cm(-3) at a scan rate of 2 mV s(-1) and a high operation voltage window of 2.0 V. Especially, after a middle layer with an inner-connection structure was inserted between the anode and the cathode, the output voltage of the whole device can achieve 4.0 V. The full cell of series ASCs (SASC) with an inner-connection middle layer has a high energy density of 28.6 mW h cm(-3) at a power density of 261.4 mW cm(-3), and exhibits excellent cycling performance of 99.6% capacitance retention over 10,000 cycles. This strategy of designing the hybridized structure for SASCs provides a promising route for next-generation SCs with high energy density and high output voltage.

  9. High-Energy-Density Metal-Oxygen Batteries: Lithium-Oxygen Batteries vs Sodium-Oxygen Batteries.

    PubMed

    Song, Kyeongse; Agyeman, Daniel Adjei; Park, Mihui; Yang, Junghoon; Kang, Yong-Mook

    2017-09-21

    The development of next-generation energy-storage devices with high power, high energy density, and safety is critical for the success of large-scale energy-storage systems (ESSs), such as electric vehicles. Rechargeable sodium-oxygen (Na-O2 ) batteries offer a new and promising opportunity for low-cost, high-energy-density, and relatively efficient electrochemical systems. Although the specific energy density of the Na-O2 battery is lower than that of the lithium-oxygen (Li-O2 ) battery, the abundance and low cost of sodium resources offer major advantages for its practical application in the near future. However, little has so far been reported regarding the cell chemistry, to explain the rate-limiting parameters and the corresponding low round-trip efficiency and cycle degradation. Consequently, an elucidation of the reaction mechanism is needed for both lithium-oxygen and sodium-oxygen cells. An in-depth understanding of the differences and similarities between Li-O2 and Na-O2 battery systems, in terms of thermodynamics and a structural viewpoint, will be meaningful to promote the development of advanced metal-oxygen batteries. State-of-the-art battery design principles for high-energy-density lithium-oxygen and sodium-oxygen batteries are thus reviewed in depth here. Major drawbacks, reaction mechanisms, and recent strategies to improve performance are also summarized. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. The National Ignition Facility: A New Era in High Energy Density Science

    SciTech Connect

    Moses, E

    2009-06-10

    The National Ignition Facility, the world's most energetic laser system, is now operational. This talk will describe NIF, the ignition campaign, and new opportunities in fusion energy and high energy density science enabled by NIF.

  11. High-Energy Density science at the Linac Coherent Light Source

    DOE PAGES

    Glenzer, S. H.; Fletcher, L. B.; Hastings, J. B.

    2016-04-01

    The Matter in Extreme Conditions end station at the Linac Coherent Light Source holds great promise for novel pump-probe experiments to make new discoveries in high- energy density science. Recently, our experiments have demonstrated the first spectrally- resolved measurements of plasmons using a seeded 8-keV x-ray laser beam. Forward x-ray Thomson scattering spectra from isochorically heated solid aluminum show a well-resolved plasmon feature that is down-shifted in energy by 19 eV from the incident 8 keV elastic scattering feature. In this spectral range, the simultaneously measured backscatter spectrum shows no spectral features indicating observation of collective plasmon oscillations on amore » scattering length comparable to the screening length. Moreover, this technique is a prerequisite for Thomson scattering measurements in compressed matter where the plasmon shift is a sensitive function of the free electron density and where the plasmon intensity provides information on temperature.« less

  12. The National Ignition Facility Status and Plans for Laser Fusion and High Energy Density Experimental Studies

    NASA Astrophysics Data System (ADS)

    Wuest, Craig R.

    2001-03-01

    The National Ignition Facility (NIF) currently under construction at the University of California Lawrence Livermore National Laboratory is 192-beam, 1.8 Megajoule, 500 Terawatt, 351 nm laser for inertial confinement fusion and high energy density experimental studies. NIF is being built by the Department of Energy and the National Nuclear Security Agency to provide an experimental test bed for the US Stockpile Stewardship Program to ensure the country’s nuclear deterrent without underground nuclear testing. The experimental program for NIF will encompass a wide range of physical phenomena from fusion energy production to materials science. Of the roughly 700 shots available per year, about 10% of the shots will be dedicated to basic science research. Additionally, most of the shots on NIF will be conducted in unclassified configurations that will allow participation from the greater scientific community in planned applied physics experiments. This presentation will provide a look at the status of the construction project as well as a description of the scientific uses of NIF. NIF is currently scheduled to provide first light in 2004 and will be completed in 2008. This work was performed under the auspices of the U.S. Department of Energy by University of California Lawrence Livermore National Laboratory under contract No. W-7405-Eng-48.

  13. Report of the Interagency Task Force on High Energy Density Physics

    SciTech Connect

    2007-08-01

    Identifies the needs for improving Federal stewardship of specific aspects of high energy density physics, particularly the study of high energy density plasmas in the laboratory, and strengthening university activities in this latter discipline. The report articulates how HEDP fits into the portfolio of federally funded missions and includes agency actions to be taken that are necessary to further this area of study consistent with Federal priorities and plans, while being responsive to the needs of the scientific community.

  14. Toward high-energy-density, high-efficiency, and moderate-temperature chip-scale thermophotovoltaics.

    PubMed

    Chan, Walker R; Bermel, Peter; Pilawa-Podgurski, Robert C N; Marton, Christopher H; Jensen, Klavs F; Senkevich, Jay J; Joannopoulos, John D; Soljacic, Marin; Celanovic, Ivan

    2013-04-02

    The challenging problem of ultra-high-energy-density, high-efficiency, and small-scale portable power generation is addressed here using a distinctive thermophotovoltaic energy conversion mechanism and chip-based system design, which we name the microthermophotovoltaic (μTPV) generator. The approach is predicted to be capable of up to 32% efficient heat-to-electricity conversion within a millimeter-scale form factor. Although considerable technological barriers need to be overcome to reach full performance, we have performed a robust experimental demonstration that validates the theoretical framework and the key system components. Even with a much-simplified μTPV system design with theoretical efficiency prediction of 2.7%, we experimentally demonstrate 2.5% efficiency. The μTPV experimental system that was built and tested comprises a silicon propane microcombustor, an integrated high-temperature photonic crystal selective thermal emitter, four 0.55-eV GaInAsSb thermophotovoltaic diodes, and an ultra-high-efficiency maximum power-point tracking power electronics converter. The system was demonstrated to operate up to 800 °C (silicon microcombustor temperature) with an input thermal power of 13.7 W, generating 344 mW of electric power over a 1-cm(2) area.

  15. Toward high-energy-density, high-efficiency, and moderate-temperature chip-scale thermophotovoltaics

    PubMed Central

    Chan, Walker R.; Bermel, Peter; Pilawa-Podgurski, Robert C. N.; Marton, Christopher H.; Jensen, Klavs F.; Senkevich, Jay J.; Joannopoulos, John D.; Soljačić, Marin; Celanovic, Ivan

    2013-01-01

    The challenging problem of ultra-high-energy-density, high-efficiency, and small-scale portable power generation is addressed here using a distinctive thermophotovoltaic energy conversion mechanism and chip-based system design, which we name the microthermophotovoltaic (μTPV) generator. The approach is predicted to be capable of up to 32% efficient heat-to-electricity conversion within a millimeter-scale form factor. Although considerable technological barriers need to be overcome to reach full performance, we have performed a robust experimental demonstration that validates the theoretical framework and the key system components. Even with a much-simplified μTPV system design with theoretical efficiency prediction of 2.7%, we experimentally demonstrate 2.5% efficiency. The μTPV experimental system that was built and tested comprises a silicon propane microcombustor, an integrated high-temperature photonic crystal selective thermal emitter, four 0.55-eV GaInAsSb thermophotovoltaic diodes, and an ultra-high-efficiency maximum power-point tracking power electronics converter. The system was demonstrated to operate up to 800 °C (silicon microcombustor temperature) with an input thermal power of 13.7 W, generating 344 mW of electric power over a 1-cm2 area. PMID:23440220

  16. Generation of monoenergetic ion beams via ionization dynamics (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Lin, Chen; Kim, I. Jong; Yu, Jinqing; Choi, Il Woo; Ma, Wenjun; Yan, Xueqing; Nam, Chang Hee

    2017-05-01

    The research on ion acceleration driven by high intensity laser pulse has attracted significant interests in recent decades due to the developments of laser technology. The intensive study of energetic ion bunches is particularly stimulated by wide applications in nuclear fusion, medical treatment, warm dense matter production and high energy density physics. However, to implement such compact accelerators, challenges are still existing in terms of beam quality and stability, especially in applications that require higher energy and narrow bandwidth spectra ion beams. We report on the acceleration of quasi-mono-energetic ion beams via ionization dynamics in the interaction of an intense laser pulse with a solid target. Using ionization dynamics model in 2D particle-in-cell (PIC) simulations, we found that high charge state contamination ions can only be ionized in the central spot area where the intensity of sheath field surpasses their ionization threshold. These ions automatically form a microstructure target with a width of few micron scale, which is conducive to generate mono-energetic beams. In the experiment of ultraintense (< 10^21 W/cm^2) laser pulses irradiating ultrathin targets each attracted with a contamination layer of nm-thickness, high quality < 100 MeV mono-energetic ion bunches are generated. The peak energy of the self-generated micro-structured target ions with respect to different contamination layer thickness is also examined This is relatively newfound respect, which is confirmed by the consistence between experiment data and the simulation results.

  17. Fully-kinetic simulations of the Rayleigh-Taylor instability in high-energy-density plasmas

    NASA Astrophysics Data System (ADS)

    Alves, E. Paulo; Mori, Warren B.; Fiuza, Frederico

    2016-10-01

    The Rayleigh-Taylor instability (RTI) in high-energy-density (HED) plasmas is a central problem in a wide range of scenarios. It dictates, for instance, the dynamics of supernovae in astrophysical plasmas, and is also recognized as a critical challenge to achieving ignition in inertial confinement fusion. In some of these conditions the Larmor radius or Coulomb mean free path (m.f.p.) is finite, allowing kinetic effects to become important, and it is not fully clear how the development of the RTI deviates from standard hydrodynamic behavior. In order to obtain an accurate description of the RTI in these HED conditions it is essential to capture the self-consistent interplay between collisional and collisionless plasma processes, and the role of self-generated electric and magnetic fields. We have explored the dynamics of the RTI in HED plasma conditions using first-principles particle-in-cell simulations combined with Monte Carlo binary collisions. Our simulations capture the role of kinetic diffusion as well as the self-generated electric (e.g. space-charge) and magnetic (e.g. Biermann battery) fields on the growth rate and nonlinear evolution of the RTI for different plasma conditions. We will discuss how different collisional m.f.p. relative to the collisionless plasma skin depth affect the RTI development. This work was supported by the DOE Office of Science, Fusion Energy Science (FWP 100182).

  18. Advanced High Energy Density Secondary Batteries with Multi-Electron Reaction Materials.

    PubMed

    Chen, Renjie; Luo, Rui; Huang, Yongxin; Wu, Feng; Li, Li

    2016-10-01

    Secondary batteries have become important for smart grid and electric vehicle applications, and massive effort has been dedicated to optimizing the current generation and improving their energy density. Multi-electron chemistry has paved a new path for the breaking of the barriers that exist in traditional battery research and applications, and provided new ideas for developing new battery systems that meet energy density requirements. An in-depth understanding of multi-electron chemistries in terms of the charge transfer mechanisms occuring during their electrochemical processes is necessary and urgent for the modification of secondary battery materials and development of secondary battery systems. In this Review, multi-electron chemistry for high energy density electrode materials and the corresponding secondary battery systems are discussed. Specifically, four battery systems based on multi-electron reactions are classified in this review: lithium- and sodium-ion batteries based on monovalent cations; rechargeable batteries based on the insertion of polyvalent cations beyond those of alkali metals; metal-air batteries, and Li-S batteries. It is noted that challenges still exist in the development of multi-electron chemistries that must be overcome to meet the energy density requirements of different battery systems, and much effort has more effort to be devoted to this.

  19. Pressure-driven, resistive magnetohydrodynamic interchange instabilities in laser-produced high-energy-density plasmas

    SciTech Connect

    Li, C. K.; Frenje, J. A.; Petrasso, R. D.; Seguin, F. H.; Amendt, P. A.; Landen, O. L.; Town, R. P. J.; Betti, R.; Knauer, J. P.; Meyerhofer, D. D.; Soures, J. M.

    2009-07-15

    Recent experiments using proton backlighting of laser-foil interactions provide unique opportunities for studying magnetized plasma instabilities in laser-produced high-energy-density plasmas. Time-gated proton radiograph images indicate that the outer structure of a magnetic field entrained in a hemispherical plasma bubble becomes distinctly asymmetric after the laser turns off. It is shown that this asymmetry is a consequence of pressure-driven, resistive magnetohydrodynamic (MHD) interchange instabilities. In contrast to the predictions made by ideal MHD theory, the increasing plasma resistivity after laser turn-off allows for greater low-mode destabilization (m>1) from reduced stabilization by field-line bending. For laser-generated plasmas presented herein, a mode-number cutoff for stabilization of perturbations with m>{approx}[8{pi}{beta}(1+D{sub m}k{sub perpendicular}{sup 2}{gamma}{sub max}{sup -1})]{sup 1/2} is found in the linear growth regime. The growth is measured and is found to be in reasonable agreement with model predictions.

  20. The formation of reverse shocks in magnetized high energy density supersonic plasma flows

    SciTech Connect

    Lebedev, S. V. E-mail: l.suttle10@imperial.ac.uk; Suttle, L.; Swadling, G. F.; Bennett, M.; Bland, S. N.; Burdiak, G. C.; Chittenden, J. P.; Grouchy, P. de; Hall, G. N.; Hare, J. D.; Kalmoni, N.; Niasse, N.; Patankar, S.; Smith, R. A.; Suzuki-Vidal, F.; Burgess, D.; Clemens, A.; Ciardi, A.; Sheng, L.; Yuan, J.; and others

    2014-05-15

    A new experimental platform was developed, based on the use of supersonic plasma flow from the ablation stage of an inverse wire array z-pinch, for studies of shocks in magnetized high energy density physics plasmas in a well-defined and diagnosable 1-D interaction geometry. The mechanism of flow generation ensures that the plasma flow (Re{sub M} ∼ 50, M{sub S} ∼ 5, M{sub A} ∼ 8, V{sub flow} ≈ 100 km/s) has a frozen-in magnetic field at a level sufficient to affect shocks formed by its interaction with obstacles. It is found that in addition to the expected accumulation of stagnated plasma in a thin layer at the surface of a planar obstacle, the presence of the magnetic field leads to the formation of an additional detached density jump in the upstream plasma, at a distance of ∼c/ω{sub pi} from the obstacle. Analysis of the data obtained with Thomson scattering, interferometry, and local magnetic probes suggests that the sub-shock develops due to the pile-up of the magnetic flux advected by the plasma flow.

  1. The impact of Hall physics on magnetized high energy density plasma jets

    SciTech Connect

    Gourdain, P.-A.; Seyler, C. E.; Atoyan, L.; Greenly, J. B.; Hammer, D. A.; Kusse, B. R.; Pikuz, S. A.; Potter, W. M.; Schrafel, P. C.; Shelkovenko, T. A.

    2014-05-15

    Hall physics is often neglected in high energy density plasma jets due to the relatively high electron density of such jets (n{sub e} ∼ 10{sup 19} cm{sup −3}). However, the vacuum region surrounding the jet has much lower densities and is dominated by Hall electric field. This electric field redirects plasma flows towards or away from the axis, depending on the radial current direction. A resulting change in the jet density has been observed experimentally. Furthermore, if an axial field is applied on the jet, the Hall effect is enhanced and ignoring it leads to serious discrepancies between experimental results and numerical simulations. By combining high currents (∼1 MA) and magnetic field helicity (15° angle) in a pulsed power generator such as COBRA, plasma jets can be magnetized with a 10 T axial field. The resulting field enhances the impact of the Hall effect by altering the density profile of current-free plasma jets and the stability of current-carrying plasma jets (e.g., Z-pinches)

  2. Characterization of magnetic reconnection in the high-energy-density regime.

    PubMed

    Xu, Z; Qiao, B; Chang, H X; Yao, W P; Wu, S Z; Yan, X Q; Zhou, C T; Wang, X G; He, X T

    2016-03-01

    The dynamics of magnetic reconnection (MR) in the high-energy-density (HED) regime, where the plasma inflow is strongly driven and the thermal pressure is larger than the magnetic pressure (β>1), is reexamined theoretically and by particle-in-cell simulations. Interactions of two colliding laser-produced plasma bubbles with self-generated poloidal magnetic fields of, respectively, antiparallel and parallel field lines are considered. Through comparison, it is found that the quadrupole magnetic field, bipolar poloidal electric field, plasma heating, and even the out-of-plane electric field can appear in both cases due to the mere plasma bubble collision, which may not be individually recognized as evidences of MR in the HED regime separately. The Lorentz-invariant scalar quantity D(e) ≃ γ(e)j · (E + v(e) × B) (γ(e) = [1-(v(e)/c)(2)](-1/2)) in the electron dissipation region is proposed as the key sign of MR occurrence in this regime.

  3. Development of high energy density fuels from mild gasification of coal

    SciTech Connect

    Not Available

    1990-10-01

    The overall objective of the program is the determination of the minimal processing requirements to produce High Energy Density Fuels (HEDF), meeting a minimal energy density of 130,000 Btu/gal (conventional jet fuels have energy densities in the vicinity of 115,000--120,000 Btu/gal) and having acceptable advanced fuel specifications in accordance with the three defined categories of HEDF. The program encompasses assessing current technology capability; selecting acceptable processing and refining schemes; and generating samples of advanced test fuels. A task breakdown structure was developed containing eight key tasks. This report summarizes the work that Amoco Oil Company (AOC), as key subcontractor, performed in the execution of Task 4, Proposed Upgrading Schemes for Advanced Fuel. The intent of the Task 4 study was to represent all the candidate processing options, that were either studied in the experimental efforts of Task 3 or were available from the prior art in the open literature, in a linear program (LP) model. The LP model would allow scaling of the bench-scale Task 3 results to commercial scale and would perform economic evaluations on any combination of the processes which might be used to make HEDF. Section 2.0 of this report summarizes the process and economic bases used. Sections 3.0 and 4.0 details the economics and processing sensitivities for HEDF production. 1 ref., 15 figs., 9 tabs.

  4. Parameter scaling toward high-energy density in a quasi-steady flow Z-pinch

    NASA Astrophysics Data System (ADS)

    Hughes, M. C.; Shumlak, U.; Nelson, B. A.; Golingo, R. P.; Claveau, E. L.; Doty, S. A.; Forbes, E. G.; Kim, B.; Ross, M. P.

    2016-10-01

    Sheared axial flows are utilized by the ZaP Flow Z-Pinch Experiment to stabilize MHD instabilities. The pinches formed are 50 cm long with radii ranging from 0.3 to 1.0 cm. The plasma is generated in a coaxial acceleration region, similar to a Marshall gun, which provides a steady supply of plasma for approximately 100 us. The power to the plasma is partially decoupled between the acceleration and pinch assembly regions through the use of separate power supplies. Adiabatic scaling of the Bennett relation gives targets for future devices to reach high-energy density conditions or fusion reactors. The applicability of an adiabatic assumption is explored and work is done experimentally to clarify the plasma compression process, which may be more generally polytropic. The device is capable of a much larger parameter space than previous machine iterations, allowing flexibility in the initial conditions of the compression process to preserve stability. This work is supported by DoE FES and NNSA.

  5. Experimental investigation of opacity models for stellar interior, inertial fusion, and high energy density plasmas

    SciTech Connect

    Bailey, J. E.; Rochau, G. A.; Mancini, R. C.; Iglesias, C. A.; MacFarlane, J. J.; Golovkin, I. E.; Blancard, C.; Cosse, Ph.; Faussurier, G.

    2009-05-15

    Theoretical opacities are required for calculating energy transport in plasmas. In particular, understanding stellar interiors, inertial fusion, and Z pinches depends on the opacities of mid-atomic-number elements over a wide range of temperatures. The 150-300 eV temperature range is particularly interesting. The opacity models are complex and experimental validation is crucial. For example, solar models presently disagree with helioseismology and one possible explanation is inadequate theoretical opacities. Testing these opacities requires well-characterized plasmas at temperatures high enough to produce the ion charge states that exist in the sun. Typical opacity experiments heat a sample using x rays and measure the spectrally resolved transmission with a backlight. The difficulty grows as the temperature increases because the heating x-ray source must supply more energy and the backlight must be bright enough to overwhelm the plasma self-emission. These problems can be overcome with the new generation of high energy density (HED) facilities. For example, recent experiments at Sandia's Z facility [M. K. Matzen et al., Phys. Plasmas 12, 055503 (2005)] measured the transmission of a mixed Mg and Fe plasma heated to 156{+-}6 eV. This capability will also advance opacity science for other HED plasmas. This tutorial reviews experimental methods for testing opacity models, including experiment design, transmission measurement methods, accuracy evaluation, and plasma diagnostics. The solar interior serves as a focal problem and Z facility experiments illustrate the techniques.

  6. Pressure-driven, resistive magnetohydrodynamic interchange instabilities in laser-produced high-energy-density plasmas.

    PubMed

    Li, C K; Frenje, J A; Petrasso, R D; Séguin, F H; Amendt, P A; Landen, O L; Town, R P J; Betti, R; Knauer, J P; Meyerhofer, D D; Soures, J M

    2009-07-01

    Recent experiments using proton backlighting of laser-foil interactions provide unique opportunities for studying magnetized plasma instabilities in laser-produced high-energy-density plasmas. Time-gated proton radiograph images indicate that the outer structure of a magnetic field entrained in a hemispherical plasma bubble becomes distinctly asymmetric after the laser turns off. It is shown that this asymmetry is a consequence of pressure-driven, resistive magnetohydrodynamic (MHD) interchange instabilities. In contrast to the predictions made by ideal MHD theory, the increasing plasma resistivity after laser turn-off allows for greater low-mode destabilization (m>1) from reduced stabilization by field-line bending. For laser-generated plasmas presented herein, a mode-number cutoff for stabilization of perturbations with m> approximately [8pibeta(1+D_{m}k_{ perpendicular};{2}gamma_{max};{-1})];{1/2} is found in the linear growth regime. The growth is measured and is found to be in reasonable agreement with model predictions.

  7. Advanced High Energy Density Secondary Batteries with Multi‐Electron Reaction Materials

    PubMed Central

    Luo, Rui; Huang, Yongxin; Li, Li

    2016-01-01

    Secondary batteries have become important for smart grid and electric vehicle applications, and massive effort has been dedicated to optimizing the current generation and improving their energy density. Multi‐electron chemistry has paved a new path for the breaking of the barriers that exist in traditional battery research and applications, and provided new ideas for developing new battery systems that meet energy density requirements. An in‐depth understanding of multi‐electron chemistries in terms of the charge transfer mechanisms occuring during their electrochemical processes is necessary and urgent for the modification of secondary battery materials and development of secondary battery systems. In this Review, multi‐electron chemistry for high energy density electrode materials and the corresponding secondary battery systems are discussed. Specifically, four battery systems based on multi‐electron reactions are classified in this review: lithium‐ and sodium‐ion batteries based on monovalent cations; rechargeable batteries based on the insertion of polyvalent cations beyond those of alkali metals; metal–air batteries, and Li–S batteries. It is noted that challenges still exist in the development of multi‐electron chemistries that must be overcome to meet the energy density requirements of different battery systems, and much effort has more effort to be devoted to this. PMID:27840796

  8. A high-energy-density sugar biobattery based on a synthetic enzymatic pathway.

    PubMed

    Zhu, Zhiguang; Kin Tam, Tsz; Sun, Fangfang; You, Chun; Percival Zhang, Y-H

    2014-01-01

    High-energy-density, green, safe batteries are highly desirable for meeting the rapidly growing needs of portable electronics. The incomplete oxidation of sugars mediated by one or a few enzymes in enzymatic fuel cells suffers from low energy densities and slow reaction rates. Here we show that nearly 24 electrons per glucose unit of maltodextrin can be produced through a synthetic catabolic pathway that comprises 13 enzymes in an air-breathing enzymatic fuel cell. This enzymatic fuel cell is based on non-immobilized enzymes that exhibit a maximum power output of 0.8 mW cm(-2) and a maximum current density of 6 mA cm(-2), which are far higher than the values for systems based on immobilized enzymes. Enzymatic fuel cells containing a 15% (wt/v) maltodextrin solution have an energy-storage density of 596 Ah kg(-1), which is one order of magnitude higher than that of lithium-ion batteries. Sugar-powered biobatteries could serve as next-generation green power sources, particularly for portable electronics.

  9. Magnetohydrodynamics of high-energy-density-plasma in strong magnetic field

    NASA Astrophysics Data System (ADS)

    Matsuo, Kazuki; Nagatomo, Hideo; Sano, Takayoshi; Zhang, Zhe; Sakawa, Youichi; Hara, Yukiko; Shimogawara, Hiroshi; Airikawa, Yasunobu; Sakata, Shouhei; Law, Kingfaifarley; Lee, Seungho; Kojima, Sadaoki; Katou, Hiroki; Shigemori, Keisuke; Fujioka, Shinsuke; Azechi, Hiroshi

    2016-10-01

    The magneto-hydrodynamics (MHD) of a high-energy-density-plasma (HEDP) in a strong external magnetic field contains a lot of fundamental and essential physics related to astro- and solar- physics and B-assisted inertial confinement fusion energy development. Especially, hydrodynamic instability in a strong magnetic field is a key physics for success of B-assisted inertial confinement fusion. Hydrodynamic instability growth is affected by strong magnetic field as a result of non-uniform heat flow. Experiments were conducted with a corrugated plastic target that is set between a pair of capacitor-coil. A pair of capacitor-coil targets was used to generate spatially uniform magnetic field. The plastic targets were irradiated by an intense laser pulse having 1013 W/cm2 of intensity. Temporal evolution of perturbation growth was observed with x-ray backlight technique. Enhancement of the perturbation growth in strong magnetic field was observed experimentally, and the result was consistent with hydrodynamic simulation.

  10. Exploration of Plasma Jets Approach to High Energy Density Physics. Final report

    SciTech Connect

    Chen, Chiping

    2013-08-26

    High-energy-density laboratory plasma (HEDLP) physics is an emerging, important area of research in plasma physics, nuclear physics, astrophysics, and particle acceleration. While the HEDLP regime occurs at extreme conditions which are often found naturally in space but not on the earth, it may be accessible by colliding high intensity plasmas such as high-energy-density plasma jets, plasmoids or compact toroids from plasma guns. The physics of plasma jets is investigated in the context of high energy density laboratory plasma research. This report summarizes results of theoretical and computational investigation of a plasma jet undergoing adiabatic compression and adiabatic expansion. A root-mean-squared (rms) envelope theory of plasma jets is developed. Comparison between theory and experiment is made. Good agreement between theory and experiment is found.

  11. An Ultraflexible Silicon-Oxygen Battery Fiber with High Energy Density.

    PubMed

    Zhang, Ye; Jiao, Yiding; Lu, Lijun; Wang, Lie; Chen, Taiqiang; Peng, Huisheng

    2017-09-21

    To satisfy the rapid development of portable and wearable electronics, it is highly desired to make batteries with both high energy densities and flexibility. Although some progress has been made in recent decades, the available batteries share critical problems of poor energy storage capacity and low flexibility. Herein, we have developed a silicon-oxygen battery fiber with high energy density and ultra-high flexibility by designing a coaxial architecture with a lithiated silicon/carbon nanotube hybrid fiber as inner anode, a polymer gel as middle electrolyte and a bare carbon nanotube sheet as outer cathode. The fiber showed a high energy density of 512 Wh kg(-1) and could effectively work after bending for 20 000 cycles. These battery fibers have been further woven into flexible textiles for a large-scale application. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Application of a high-energy-density permanent magnet material in underwater systems

    NASA Astrophysics Data System (ADS)

    Cho, C. P.; Egan, C.; Krol, W. P.

    1996-06-01

    This paper addresses the application of high-energy-density permanent magnet (PM) technology to (1) the brushless, axial-field PM motor and (2) the integrated electric motor/pump system for under-water applications. Finite-element analysis and lumped parameter magnetic circuit analysis were used to calculate motor parameters and performance characteristics and to conduct tradeoff studies. Compact, efficient, reliable, and quiet underwater systems are attainable with the development of high-energy-density PM material, power electronic devices, and power integrated-circuit technology.

  13. Atomic physics calculations in support of studies for high energy density plasmas

    SciTech Connect

    Wang, P.; MacFarlane, J.J.; Moses, G.A.; Mehlhorn, T.A.

    1995-12-31

    The studies of high energy density plasmas require basic atomic data, equations of state, opacities, and stopping power. Unfortunately, the related experimental data are very limited. To obtain these data for a wide domain of plasma conditions, one must rely on theoretical calculations. The authors have developed an atomic physics calculation package which can provide high quality atomic data for numerical simulations of high energy density plasmas. In this paper, they give detailed descriptions of physics models used in the package. Particular emphasis will be on a hybrid model for equations of state, a self-consistent field model for ion stopping power, and opacity calculations.

  14. Model of High-Energy-Density Battery Based on SiC Schottky Diodes

    DTIC Science & Technology

    2006-10-01

    ARL -D J M MILLER ATTN AMSRD- ARL -CI-OK-T TECHL PUB (2 COPIES ) ATTN AMSRD- ARL -CI-OK-TL TECHL LIB (2 COPIES) ATTN AMSRD- ARL -SE-DE M LITZ ...Model of High-Energy-Density Battery Based on SiC Schottky Diodes by Yves Ngu, Marc Litz , and Bruce Geil ARL -TR-3981 Ocotber 2006...Spectrum September 2004, 36-41. 6. Litz , M .; et al. On-Demand High Energy Density Materials. Amer. Inst. of Aero. and Astro. 7. Litz , M

  15. Intense ion beam generator

    DOEpatents

    Humphries, Jr., Stanley; Sudan, Ravindra N.

    1977-08-30

    Methods and apparatus for producing intense megavolt ion beams are disclosed. In one embodiment, a reflex triode-type pulsed ion accelerator is described which produces ion pulses of more than 5 kiloamperes current with a peak energy of 3 MeV. In other embodiments, the device is constructed so as to focus the beam of ions for high concentration and ease of extraction, and magnetic insulation is provided to increase the efficiency of operation.

  16. High energy density micro plasma bunch from multiple laser interaction with thin target

    SciTech Connect

    Xu, Han; Yu, Wei; Luan, S. X.; Xu, Z. Z.; Yu, M. Y.; Cai, H. B.; Zhou, C. T.; Yang, X. H.; Yin, Y.; Zhuo, H. B.; Wang, J. W.; Murakami, M.

    2014-01-13

    Three-dimensional particle-in-cell simulation is used to investigate radiation-pressure driven acceleration and compression of small solid-density plasma by intense laser pulses. It is found that multiple impacts by presently available short-pulse lasers on a small hemispheric shell target can create a long-living tiny quasineutral monoenergetic plasma bunch of very high energy density.

  17. Directing the Lithium–Sulfur Reaction Pathway via Sparingly Solvating Electrolytes for High Energy Density Batteries

    PubMed Central

    2017-01-01

    The lithium–sulfur battery has long been seen as a potential next generation battery chemistry for electric vehicles owing to the high theoretical specific energy and low cost of sulfur. However, even state-of-the-art lithium–sulfur batteries suffer from short lifetimes due to the migration of highly soluble polysulfide intermediates and exhibit less than desired energy density due to the required excess electrolyte. The use of sparingly solvating electrolytes in lithium–sulfur batteries is a promising approach to decouple electrolyte quantity from reaction mechanism, thus creating a pathway toward high energy density that deviates from the current catholyte approach. Herein, we demonstrate that sparingly solvating electrolytes based on compact, polar molecules with a 2:1 ratio of a functional group to lithium salt can fundamentally redirect the lithium–sulfur reaction pathway by inhibiting the traditional mechanism that is based on fully solvated intermediates. In contrast to the standard catholyte sulfur electrochemistry, sparingly solvating electrolytes promote intermediate- and short-chain polysulfide formation during the first third of discharge, before disproportionation results in crystalline lithium sulfide and a restricted fraction of soluble polysulfides which are further reduced during the remaining discharge. Moreover, operation at intermediate temperatures ca. 50 °C allows for minimal overpotentials and high utilization of sulfur at practical rates. This discovery opens the door to a new wave of scientific inquiry based on modifying the electrolyte local structure to tune and control the reaction pathway of many precipitation–dissolution chemistries, lithium–sulfur and beyond. PMID:28691072

  18. Directing the Lithium-Sulfur Reaction Pathway via Sparingly Solvating Electrolytes for High Energy Density Batteries.

    PubMed

    Lee, Chang-Wook; Pang, Quan; Ha, Seungbum; Cheng, Lei; Han, Sang-Don; Zavadil, Kevin R; Gallagher, Kevin G; Nazar, Linda F; Balasubramanian, Mahalingam

    2017-06-28

    The lithium-sulfur battery has long been seen as a potential next generation battery chemistry for electric vehicles owing to the high theoretical specific energy and low cost of sulfur. However, even state-of-the-art lithium-sulfur batteries suffer from short lifetimes due to the migration of highly soluble polysulfide intermediates and exhibit less than desired energy density due to the required excess electrolyte. The use of sparingly solvating electrolytes in lithium-sulfur batteries is a promising approach to decouple electrolyte quantity from reaction mechanism, thus creating a pathway toward high energy density that deviates from the current catholyte approach. Herein, we demonstrate that sparingly solvating electrolytes based on compact, polar molecules with a 2:1 ratio of a functional group to lithium salt can fundamentally redirect the lithium-sulfur reaction pathway by inhibiting the traditional mechanism that is based on fully solvated intermediates. In contrast to the standard catholyte sulfur electrochemistry, sparingly solvating electrolytes promote intermediate- and short-chain polysulfide formation during the first third of discharge, before disproportionation results in crystalline lithium sulfide and a restricted fraction of soluble polysulfides which are further reduced during the remaining discharge. Moreover, operation at intermediate temperatures ca. 50 °C allows for minimal overpotentials and high utilization of sulfur at practical rates. This discovery opens the door to a new wave of scientific inquiry based on modifying the electrolyte local structure to tune and control the reaction pathway of many precipitation-dissolution chemistries, lithium-sulfur and beyond.

  19. Directing the lithium–sulfur reaction pathway via sparingly solvating electrolytes for high energy density batteries

    DOE PAGES

    Lee, Chang -Wook; Pang, Quan; Ha, Seungbum; ...

    2017-05-25

    The lithium–sulfur battery has long been seen as a potential next generation battery chemistry for electric vehicles owing to the high theoretical specific energy and low cost of sulfur. However, even state-of-the-art lithium–sulfur batteries suffer from short lifetimes due to the migration of highly soluble polysulfide intermediates and exhibit less than desired energy density due to the required excess electrolyte. The use of sparingly solvating electrolytes in lithium–sulfur batteries is a promising approach to decouple electrolyte quantity from reaction mechanism, thus creating a pathway toward high energy density that deviates from the current catholyte approach. Herein, we demonstrate that sparinglymore » solvating electrolytes based on compact, polar molecules with a 2:1 ratio of a functional group to lithium salt can fundamentally redirect the lithium–sulfur reaction pathway by inhibiting the traditional mechanism that is based on fully solvated intermediates. In contrast to the standard catholyte sulfur electrochemistry, sparingly solvating electrolytes promote intermediate- and short-chain polysulfide formation during the first third of discharge, before disproportionation results in crystalline lithium sulfide and a restricted fraction of soluble polysulfides which are further reduced during the remaining discharge. Moreover, operation at intermediate temperatures ca. 50 °C allows for minimal overpotentials and high utilization of sulfur at practical rates. Finally, this discovery opens the door to a new wave of scientific inquiry based on modifying the electrolyte local structure to tune and control the reaction pathway of many precipitation–dissolution chemistries, lithium–sulfur and beyond.« less

  20. Experimental and Computational Studies of High Energy Density Plasma Streams Ablated from Fine Wires

    SciTech Connect

    Greenly, John B.; Seyler, Charles

    2014-03-30

    Experimental and computational studies of high energy density plasma streams ablated from fine wires. Laboratory of Plasma Studies, School of Electrical and Computer Engineering, Cornell University. Principal Investigators: Dr. John B. Greenly and Dr. Charles E. Seyler. This report summarizes progress during the final year of this project to study the physics of high energy density (HED) plasma streams of 10^17-10^20/cm3 density and high velocity (~100-500 km/s). Such streams are produced from 5-250 micrometer diameter wires heated and ionized by a 1 MA, 250 ns current pulse on the COBRA pulsed power facility at Cornell University. Plasma is ablated from the wires and is driven away to high velocity by unbalanced JxB force. A wire, or an array of wires, can persist as an essentially stationary, continuous source of this streaming plasma for >200 ns, even with driving magnetic fields of many Tesla and peak current densities in the plasma of many MA/cm2. At the heart of the ablation stream generation is the continuous transport of mass from the relatively cold, near-solid-density wire "core" into current-carrying plasma within 1 mm of the wire, followed by the magnetic acceleration of that plasma and its trapped flux to form a directed stream. In the first two years of this program, an advancing understanding of ablation physics led to the discovery of several novel wire ablation experimental regimes. In the final year, one of these new HED plasma regimes has been studied in quantitative detail. This regime studies highly reproducible magnetic reconnection in strongly radiating plasma with supersonic and superalfvenic flow, and shock structures in the outflow. The key discovery is that very heavy wires, e.g. 250 micrometer diameter Al or 150 micrometer Cu, behave in a qualitatively different way than the lighter wires typically used in wire-array Z-pinches. Such wires can be configured to produce a static magnetic X-point null geometry that stores magnetic and

  1. Generation of electron Airy beams.

    PubMed

    Voloch-Bloch, Noa; Lereah, Yossi; Lilach, Yigal; Gover, Avraham; Arie, Ady

    2013-02-21

    Within the framework of quantum mechanics, a unique particle wave packet exists in the form of the Airy function. Its counterintuitive properties are revealed as it propagates in time or space: the quantum probability wave packet preserves its shape despite dispersion or diffraction and propagates along a parabolic caustic trajectory, even though no force is applied. This does not contradict Newton's laws of motion, because the wave packet centroid propagates along a straight line. Nearly 30 years later, this wave packet, known as an accelerating Airy beam, was realized in the optical domain; later it was generalized to an orthogonal and complete family of beams that propagate along parabolic trajectories, as well as to beams that propagate along arbitrary convex trajectories. Here we report the experimental generation and observation of the Airy beams of free electrons. These electron Airy beams were generated by diffraction of electrons through a nanoscale hologram, which imprinted on the electrons' wavefunction a cubic phase modulation in the transverse plane. The highest-intensity lobes of the generated beams indeed followed parabolic trajectories. We directly observed a non-spreading electron wavefunction that self-heals, restoring its original shape after passing an obstacle. This holographic generation of electron Airy beams opens up new avenues for steering electronic wave packets like their photonic counterparts, because the wave packets can be imprinted with arbitrary shapes or trajectories.

  2. The Dawn of a New Era for High Energy Density Physics

    SciTech Connect

    Moses, E; McCrory, R; Meyerhofer, D; Keane, C

    2009-02-26

    The field of High Energy Density (HED) physics is on the verge of a revolutionary event - the achievement of fusion ignition in the laboratory. New laser facilities, the OMEGA Extended Performance (EP) laser at the University of Rochester and the National Ignition Facility (NIF) at Lawrence Livermore National Laboratory, greatly extend the range of high energy density (HED) plasma conditions (including ignition) accessible in the laboratory. These conditions are among the most extreme obtainable, with pressures in excess of {approx}1,000,000 atmospheres. Experiments at these facilities will elucidate fundamental new science in astrophysics, materials science, laser-matter interactions, and other areas. The demonstration of fusion ignition will be the culmination of decades of research, and for the first time, will open the burning plasma regime to laboratory exploration. Ignition will spur the development of advanced options for clean, environmentally sustainable energy.

  3. High energy density capacitors for power electronic applications using nano-structure multilayer technology

    SciTech Connect

    Barbee, T.W. Jr.; Johnson, G.W.

    1995-09-01

    Power electronics applications are currently limited by capacitor size and performance. Only incremental improvements are anticipated in existing capacitor technologies, while significant performance advances are required in energy density and overall performance to meet the technical needs of the applications which are important for U.S. economic competitiveness. One application, the Power Electronic Building Block (PEBB), promises a second electronics revolution in power electronic design. High energy density capacitors with excellent electrical thermal and mechanical performance represent an enabling technology in the PEBB concept. We propose a continuing program to research and develop LLNL`s nano-structure multilayer technologies for making high voltage, high energy density capacitors. Our controlled deposition techniques are capable of synthesizing extraordinarily smooth sub-micron thick layers of dielectric and conductor materials. We have demonstrated that, with this technology, high voltage capacitors with an order of magnitude improvement in energy density are achievable.

  4. Enhancing Understanding of High Energy Density Plasmas Using Fluid Modeling with Kinetic Closures

    NASA Astrophysics Data System (ADS)

    Hansen, David; Held, Eric; Srinivasan, Bhuvana; Masti, Robert; King, Jake

    2016-10-01

    This work seeks to understand possible stabilization mechanisms of the early-time electrothermal instability in the evolution of the Rayleigh-Taylor instability in MagLIF (Magnetized Liner Inertial Fusion) experiments. Such mechanisms may include electron thermal conduction, viscosity, and large magnetic fields. Experiments have shown that the high-energy density plasmas from wire-array implosions require physics modelling that goes well beyond simple models such as ideal MHD. The plan is to develop a multi-fluid extended-MHD model that includes kinetic closures for thermal conductivity, resistivity, and viscosity using codes that are easily available to the wider research community. Such an effort would provide the community with a well-benchmarked tool capable of advanced modeling of high-energy-density plasmas.

  5. High-energy-density Targets Fabricated by The University of Michigan

    NASA Astrophysics Data System (ADS)

    Klein, Sallee; Davis, J. S.; Gao, L.; Gillespie, R. S.; MacDonald, M. J.; Malamud, G.; Manuel, M. J.-E.; Wan, W. C.; Young, R. P.; Kuranz, C. C.; Keiter, P. A.; Drake, R. P.

    2016-10-01

    The University of Michigan has been fabricating their own targets for high-energy-density physics experiments for well over the past decade. We utilize the process of machined acrylic bodies and tightly toleranced mating components that serve as constraints, enabling our group to build repeatable targets. We favor traditional machining, utilizing 3D printing when it suits, taking advantage of the very best part of both of these methods of creating precision parts for our targets. Here we present several campaigns shot at the OMEGA, Titan and Trident facilities and methods used to those fabricate targets. This work is funded by the U.S. Department of Energy, through the NNSA-DS and SC-OFES Joint Program in High-Energy-Density Laboratory Plasmas, Grant Number DE-NA0002956, and the National Laser User Facility Program, Grant Number DE-NA0002719.

  6. Shock waves in a Z-pinch and the formation of high energy density plasma

    SciTech Connect

    Rahman, H. U.; Wessel, F. J.; Ney, P.; Presura, R.; Ellahi, Rahmat; Shukla, P. K.

    2012-12-15

    A Z-pinch liner, imploding onto a target plasma, evolves in a step-wise manner, producing a stable, magneto-inertial, high-energy-density plasma compression. The typical configuration is a cylindrical, high-atomic-number liner imploding onto a low-atomic-number target. The parameters for a terawatt-class machine (e.g., Zebra at the University of Nevada, Reno, Nevada Terawatt Facility) have been simulated. The 2-1/2 D MHD code, MACH2, was used to study this configuration. The requirements are for an initial radius of a few mm for stable implosion; the material densities properly distributed, so that the target is effectively heated initially by shock heating and finally by adiabatic compression; and the liner's thickness adjusted to promote radial current transport and subsequent current amplification in the target. Since the shock velocity is smaller in the liner, than in the target, a stable-shock forms at the interface, allowing the central load to accelerate magnetically and inertially, producing a magneto-inertial implosion and high-energy density plasma. Comparing the implosion dynamics of a low-Z target with those of a high-Z target demonstrates the role of shock waves in terms of compression and heating. In the case of a high-Z target, the shock wave does not play a significant heating role. The shock waves carry current and transport the magnetic field, producing a high density on-axis, at relatively low temperature. Whereas, in the case of a low-Z target, the fast moving shock wave preheats the target during the initial implosion phase, and the later adiabatic compression further heats the target to very high energy density. As a result, the compression ratio required for heating the low-Z plasma to very high energy densities is greatly reduced.

  7. Publications of Proceedings for the RF 2005 7th Workshop on High Energy Density and High Power RF

    SciTech Connect

    Luhmann, Jr, N C

    2006-01-01

    The University of California, Davis hosted the High Energy Density and High Power RF 7th Workshop on High Energy Density and High Power RF in Kalamata, Greece, 13-17 June, 2005. The Proceedings cost was supported by these funds from the U.S. Department of Energy. The Proceedings was published through the American Institute of Physics.

  8. From Swords to Plowshares: The US/Russian Collaboration in High Energy Density Physics Using Pulsed Power

    SciTech Connect

    Younger, S.M.; Fowler, C.M.; Lindemuth, I.; Chernyshev, V.K.; Mokhov, V.N.; Pavlovskii, A.I.

    1999-03-15

    Since 1992, the All-Russian Scientific Research Institute of Experimental Physics and the Los Alamos National Laboratory, the institutes that designed the first nuclear weapons of the Soviet Union and the US, respectively, have been working together in fundamental research related to pulsed power and high energy density science. This collaboration has enabled scientists formerly engaged in weapons activities to redirect their attention to peaceful pursuits of wide benefit to the technical community. More than thirty joint experiments have been performed at Sarov and Los Alamos in areas as diverse as solid state physics in high magnetic fields, fusion plasma formation, isentropic compression of noble gases, and explosively driven-high current generation technology. Expanding on the introductory comments of the conference plenary presentation, this paper traces the origins of this collaboration and briefly reviews the scientific accomplishments. Detailed reports of the scientific accomplishments can be found in other papers in these proceedings and in other publications.

  9. High Energy Density Physics and Applications with a State-of-the-Art Compact X-Pinch

    SciTech Connect

    Beg, Farhat N

    2013-08-14

    Recent advances in technology has made possible to create matter with extremely high energy density (energy densities and pressure exceeding 1011 J/m3 and 1 Mbar respectively). The field is new and complex. The basic question for high energy density physics (HEDP) is how does matter behave under extreme conditions of temperature, pressure, density and electromagnetic radiation? The conditions for studying HEDP are normally produced using high intensity short pulse laser, x-rays, particle beams and pulsed power z-pinches. Most of these installations occupy a large laboratory floor space and require a team consisting of a large number of scientists and engineers. This limits the number of experiments that can be performed to explore and understand the complex physics. A novel way of studying HEDP is with a compact x-pinch in university scale laboratory. The x-pinch is a configuration in which a pulsed current is passed through two or more wires placed between the electrodes making the shape of the letter ‘X’. Extreme conditions of magnetic field (> 200 MGauss for less than 1 ns), temperature (1 keV) and density (~ 1022 cm-3) are produced at the cross-point, where two wires make contact. Further, supersonic jets are produced on either side of the cross-point. The physics of the formation of the plasma at the cross-point is complex. It is not clear what role radiation plays in the formation of high energy density plasma (>> 1011 J/m3) at the cross-point. Nor it is understood how the supersonic jets are formed. Present numerical codes do not contain complex physics that can take into account some of these aspects. Indeed, a comprehensive experimental study could answer some of the questions, which are relevant to wide-ranging fields such as inertial confinement fusion, astrophysical plasmas, high intensity laser plasma interactions and radiation physics. The main aim of the proposal was to increase the fundamental understanding of high energy density physics and

  10. Conceptual designs of two petawatt-class pulsed-power accelerators for high-energy-density-physics experiments

    DOE PAGES

    Stygar, W. A.; Awe, T. J.; Bennett, N L; ...

    2015-11-30

    ) simulations suggest Z 300 will deliver 4.3 MJ to the liner, and achieve a yield on the order of 18 MJ. Z 800 is 52 m in diameter and stores 130 MJ. This accelerator generates 890 TW at the output of its LTD system, and delivers 65 MA in 113 ns to a MagLIF target. The peak electrical power at the MagLIF liner is 2500 TW. The principal goal of Z 800 is to achieve high-yield thermonuclear fusion; i.e., a yield that exceeds the energy initially stored by the accelerator’s capacitors. 2D MHD simulations suggest Z 800 will deliver 8.0 MJ to the liner, and achieve a yield on the order of 440 MJ. Z 300 and Z 800, or variations of these accelerators, will allow the international high-energy-density-physics community to conduct advanced inertial-confinement-fusion, radiation-physics, material-physics, and laboratory-astrophysics experiments over heretofore-inaccessible parameter regimes.« less

  11. Conceptual designs of two petawatt-class pulsed-power accelerators for high-energy-density-physics experiments

    NASA Astrophysics Data System (ADS)

    Stygar, W. A.; Awe, T. J.; Bailey, J. E.; Bennett, N. L.; Breden, E. W.; Campbell, E. M.; Clark, R. E.; Cooper, R. A.; Cuneo, M. E.; Ennis, J. B.; Fehl, D. L.; Genoni, T. C.; Gomez, M. R.; Greiser, G. W.; Gruner, F. R.; Herrmann, M. C.; Hutsel, B. T.; Jennings, C. A.; Jobe, D. O.; Jones, B. M.; Jones, M. C.; Jones, P. A.; Knapp, P. F.; Lash, J. S.; LeChien, K. R.; Leckbee, J. J.; Leeper, R. J.; Lewis, S. A.; Long, F. W.; Lucero, D. J.; Madrid, E. A.; Martin, M. R.; Matzen, M. K.; Mazarakis, M. G.; McBride, R. D.; McKee, G. R.; Miller, C. L.; Moore, J. K.; Mostrom, C. B.; Mulville, T. D.; Peterson, K. J.; Porter, J. L.; Reisman, D. B.; Rochau, G. A.; Rochau, G. E.; Rose, D. V.; Rovang, D. C.; Savage, M. E.; Sceiford, M. E.; Schmit, P. F.; Schneider, R. F.; Schwarz, J.; Sefkow, A. B.; Sinars, D. B.; Slutz, S. A.; Spielman, R. B.; Stoltzfus, B. S.; Thoma, C.; Vesey, R. A.; Wakeland, P. E.; Welch, D. R.; Wisher, M. L.; Woodworth, J. R.

    2015-11-01

    suggest Z 300 will deliver 4.3 MJ to the liner, and achieve a yield on the order of 18 MJ. Z 800 is 52 m in diameter and stores 130 MJ. This accelerator generates 890 TW at the output of its LTD system, and delivers 65 MA in 113 ns to a MagLIF target. The peak electrical power at the MagLIF liner is 2500 TW. The principal goal of Z 800 is to achieve high-yield thermonuclear fusion; i.e., a yield that exceeds the energy initially stored by the accelerator's capacitors. 2D MHD simulations suggest Z 800 will deliver 8.0 MJ to the liner, and achieve a yield on the order of 440 MJ. Z 300 and Z 800, or variations of these accelerators, will allow the international high-energy-density-physics community to conduct advanced inertial-confinement-fusion, radiation-physics, material-physics, and laboratory-astrophysics experiments over heretofore-inaccessible parameter regimes.

  12. Conceptual designs of two petawatt-class pulsed-power accelerators for high-energy-density-physics experiments

    SciTech Connect

    Stygar, W. A.; Awe, T. J.; Bennett, N L; Breden, E. W.; Campbell, E. M.; Clark, R. E.; Cooper, R. A.; Cuneo, M. E.; Ennis, J. B.; Fehl, D. L.; Genoni, T. C.; Gomez, M. R.; Greiser, G. W.; Gruner, F. R.; Herrmann, M. C.; Hutsel, B. T.; Jennings, C. A.; Jobe, D. O.; Jones, B. M.; Jones, M. C.; Jones, P. A.; Knapp, P. F.; Lash, J. S.; LeChien, K. R.; Leckbee, J. J.; Leeper, R. J.; Lewis, S. A.; Long, F. W.; Lucero, D. J.; Madrid, E. A.; Martin, M. R.; Matzen, M. K.; Mazarakis, M. G.; McBride, R. D.; McKee, G. R.; Miller, C. L.; Moore, J. K.; Mostrom, C. B.; Mulville, T. D.; Peterson, K. J.; Porter, J. L.; Reisman, D. B.; Rochau, G. A.; Rochau, G. E.; Rose, D. V.; Savage, M. E.; Sceiford, M. E.; Schmit, P. F.; Schneider, R. F.; Schwarz, J.; Sefkow, A. B.; Sinars, D. B.; Slutz, S. A.; Spielman, R. B.; Stoltzfus, B. S.; Thoma, C.; Vesey, R. A.; Wakeland, P. E.; Welch, D. R.; Wisher, M. L.; Woodworth, J. R.; Bailey, J. E.; Rovang, D. C.

    2015-11-30

    ) simulations suggest Z 300 will deliver 4.3 MJ to the liner, and achieve a yield on the order of 18 MJ. Z 800 is 52 m in diameter and stores 130 MJ. This accelerator generates 890 TW at the output of its LTD system, and delivers 65 MA in 113 ns to a MagLIF target. The peak electrical power at the MagLIF liner is 2500 TW. The principal goal of Z 800 is to achieve high-yield thermonuclear fusion; i.e., a yield that exceeds the energy initially stored by the accelerator’s capacitors. 2D MHD simulations suggest Z 800 will deliver 8.0 MJ to the liner, and achieve a yield on the order of 440 MJ. Z 300 and Z 800, or variations of these accelerators, will allow the international high-energy-density-physics community to conduct advanced inertial-confinement-fusion, radiation-physics, material-physics, and laboratory-astrophysics experiments over heretofore-inaccessible parameter regimes.

  13. The high-energy-density counterpropagating shear experiment and turbulent self-heating

    SciTech Connect

    Doss, F. W.; Fincke, J. R.; Loomis, E. N.; Welser-Sherrill, L.; Flippo, K. A.

    2013-12-06

    The counterpropagating shear experiment has previously demonstrated the ability to create regions of shockdriven shear, balanced symmetrically in pressure and experiencing minimal net drift. This allows for the creation of a high-Mach-number high-energy-density shear environment. New data from the counterpropagating shear campaign is presented, and both hydrocode modeling and theoretical analysis in the context of a Reynolds-averaged-Navier-Stokes model suggest turbulent dissipation of energy from the supersonic flow bounding the layer is a significant driver in its expansion. A theoretical minimum shear flow Mach number threshold is suggested for substantial thermal-turbulence coupling.

  14. Differential heating: A versatile method for thermal conductivity measurements in high-energy-density matter

    DOE PAGES

    Ping, Y.; Fernandez-Panella, A.; Sio, H.; ...

    2015-09-04

    We propose a method for thermal conductivity measurements of high energy density matter based on differential heating. A temperature gradient is created either by surface heating of one material or at an interface between two materials by different energy deposition. The subsequent heat conduction across the temperature gradient is observed by various time-resolved probing techniques. Conceptual designs of such measurements using laser heating, proton heating, and x-ray heating are presented. As a result, the sensitivity of the measurements to thermal conductivity is confirmed by simulations.

  15. Ionic liquid enabled FeS2 for high-energy-density lithium-ion batteries.

    PubMed

    Evans, Tyler; Piper, Daniela Molina; Kim, Seul Cham; Han, Sang Sub; Bhat, Vinay; Oh, Kyu Hwan; Lee, Se-Hee

    2014-11-19

    High-energy-density FeS2 cathodes en-abled by a bis(trifluoromethanesulfonyl)imide (TFSI-) anion-based room temperature ionic liquid (RTIL) electrolyte are demonstrated. A TFSI-based ionic liquid (IL) significantly mitigates polysulfide dissolution, and therefore the parasitic redox shuttle mechanism, that plagues sulfur-based electrode chemistries. FeS2 stabilization with a TFSI(-) -based IL results in one of the highest energy density cathodes, 542 W h kg(-1) (normalized to cathode composite mass), reported to date.

  16. Differential heating: A versatile method for thermal conductivity measurements in high-energy-density matter

    NASA Astrophysics Data System (ADS)

    Ping, Y.; Fernandez-Panella, A.; Sio, H.; Correa, A.; Shepherd, R.; Landen, O.; London, R. A.; Sterne, P. A.; Whitley, H. D.; Fratanduono, D.; Boehly, T. R.; Collins, G. W.

    2015-09-01

    We propose a method for thermal conductivity measurements of high energy density matter based on differential heating. A temperature gradient is created either by surface heating of one material or at an interface between two materials by different energy deposition. The subsequent heat conduction across the temperature gradient is observed by various time-resolved probing techniques. Conceptual designs of such measurements using laser heating, proton heating, and x-ray heating are presented. The sensitivity of the measurements to thermal conductivity is confirmed by simulations.

  17. Strongly Interacting Matter Matter at Very High Energy Density: 3 Lectures in Zakopane

    SciTech Connect

    McLerran, L.

    2010-06-09

    These lectures concern the properties of strongly interacting matter at very high energy density. I begin with the Color Glass Condensate and the Glasma, matter that controls the earliest times in hadronic collisions. I then describe the Quark Gluon Plasma, matter produced from the thermalized remnants of the Glasma. Finally, I describe high density baryonic matter, in particular Quarkyonic matter. The discussion will be intuitive and based on simple structural aspects of QCD. There will be some discussion of experimental tests of these ideas.

  18. The high-energy-density counterpropagating shear experiment and turbulent self-heating

    SciTech Connect

    Doss, F. W.; Fincke, J. R.; Loomis, E. N.; Welser-Sherrill, L.; Flippo, K. A.

    2013-12-15

    The counterpropagating shear experiment has previously demonstrated the ability to create regions of shock-driven shear, balanced symmetrically in pressure, and experiencing minimal net drift. This allows for the creation of a high-Mach-number high-energy-density shear environment. New data from the counterpropagating shear campaign is presented, and both hydrocode modeling and theoretical analysis in the context of a Reynolds-averaged-Navier-Stokes model suggest turbulent dissipation of energy from the supersonic flow bounding the layer is a significant driver in its expansion. A theoretical minimum shear flow Mach number threshold is suggested for substantial thermal-turbulence coupling.

  19. A Discussion of the High Energy Density Primary Battery Employed in the FOTON M3 Mission

    NASA Astrophysics Data System (ADS)

    Bennetti, A.; Reece, D.; Spurrett, R.; Schautz, M.; Green, K.

    2008-09-01

    In 2005, ABSL Space Products (ABSL) was contracted by QinetiQ to deliver the lithium sulfuryl chloride primary battery system for the FOTON M3 ESA (European Space Agency) mission. FOTON M3 was led by the ESA Directorate of Human Spaceflight & Exploration and carried a number of materials science, fluid physics and biology experiments as well as technology demonstration payloads. A number of the experiments required a very high energy density primary battery power source. This battery was manufactured by ABSL, and the mission was successfully completed in September 2007 following a twelve days orbiting in Low Earth Orbit (LEO).

  20. High energy density in the collision of N kinks in the ϕ4 model

    NASA Astrophysics Data System (ADS)

    Marjaneh, Aliakbar Moradi; Saadatmand, Danial; Zhou, Kun; Dmitriev, Sergey V.; Zomorrodian, Mohammad Ebrahim

    2017-08-01

    Recently for the sine-Gordon equation it has been established that during collisions of N slow kinks maximal energy density increases as N2. In this numerical study, the same scaling rule is established for the non-integrable ϕ4 model for N ≤ 5. For odd (even) N the maximal energy density is in the form of potential (kinetic) energy density. Maximal elastic strain is also calculated. In addition, the effect of the kink's internal modes on the maximal energy density is analysed for N = 1 , 2, and 3. Our results suggest that in multi-soliton collisions very high energy density can be achieved in a controllable manner.

  1. Differential heating: A versatile method for thermal conductivity measurements in high-energy-density matter

    SciTech Connect

    Ping, Y.; Fernandez-Panella, A.; Correa, A.; Shepherd, R.; Landen, O.; London, R. A.; Sterne, P. A.; Whitley, H. D.; Fratanduono, D.; Collins, G. W.; Sio, H.; Boehly, T. R.

    2015-09-15

    We propose a method for thermal conductivity measurements of high energy density matter based on differential heating. A temperature gradient is created either by surface heating of one material or at an interface between two materials by different energy deposition. The subsequent heat conduction across the temperature gradient is observed by various time-resolved probing techniques. Conceptual designs of such measurements using laser heating, proton heating, and x-ray heating are presented. The sensitivity of the measurements to thermal conductivity is confirmed by simulations.

  2. Ambipolar zinc-polyiodide electrolyte for a high-energy density aqueous redox flow battery

    DOE PAGES

    Li, Bin; Nie, Zimin; Vijayakumar, M.; ...

    2015-02-24

    Large-scale energy storage systems are crucial for substantial deployment of renewable energy sources. Energy storage systems with high energy density, high safety, and low cost and environmental friendliness are desired. To overcome the major limitations of the current aqueous redox flow battery systems, namely lower energy density (~25 Wh L-1) and presence of strong acids and/or other hazardous, a high energy density aqueous zinc/polyiodide flow battery (ZIB) is designed with near neutral ZnI2 solutions as catholytes. The energy density of ZIB could reach 322 Wh L-1 at the solubility limit of ZnI2 in water (~7 M). We demonstrate charge andmore » discharge energy densities of 245.9 Wh/L and 166.7 Wh L-1 with ZnI2 electrolyte at 5.0 M, respectively. The addition of ethanol (EtOH) in ZnI2 electrolyte can effectively mitigate the growth of zinc dendrite at the anode and improve the stability of catholytes with wider temperature window (-20 to 50°C), which enable ZIB system to be a promising alternative as a high-energy and high- safety stationary energy storage system.« less

  3. High energy density rechargeable magnesium battery using earth-abundant and non-toxic elements

    NASA Astrophysics Data System (ADS)

    Orikasa, Yuki; Masese, Titus; Koyama, Yukinori; Mori, Takuya; Hattori, Masashi; Yamamoto, Kentaro; Okado, Tetsuya; Huang, Zhen-Dong; Minato, Taketoshi; Tassel, Cédric; Kim, Jungeun; Kobayashi, Yoji; Abe, Takeshi; Kageyama, Hiroshi; Uchimoto, Yoshiharu

    2014-07-01

    Rechargeable magnesium batteries are poised to be viable candidates for large-scale energy storage devices in smart grid communities and electric vehicles. However, the energy density of previously proposed rechargeable magnesium batteries is low, limited mainly by the cathode materials. Here, we present new design approaches for the cathode in order to realize a high-energy-density rechargeable magnesium battery system. Ion-exchanged MgFeSiO4 demonstrates a high reversible capacity exceeding 300 mAh.g-1 at a voltage of approximately 2.4 V vs. Mg. Further, the electronic and crystal structure of ion-exchanged MgFeSiO4 changes during the charging and discharging processes, which demonstrates the (de)insertion of magnesium in the host structure. The combination of ion-exchanged MgFeSiO4 with a magnesium bis(trifluoromethylsulfonyl)imide-triglyme electrolyte system proposed in this work provides a low-cost and practical rechargeable magnesium battery with high energy density, free from corrosion and safety problems.

  4. High energy density rechargeable magnesium battery using earth-abundant and non-toxic elements

    PubMed Central

    Orikasa, Yuki; Masese, Titus; Koyama, Yukinori; Mori, Takuya; Hattori, Masashi; Yamamoto, Kentaro; Okado, Tetsuya; Huang, Zhen-Dong; Minato, Taketoshi; Tassel, Cédric; Kim, Jungeun; Kobayashi, Yoji; Abe, Takeshi; Kageyama, Hiroshi; Uchimoto, Yoshiharu

    2014-01-01

    Rechargeable magnesium batteries are poised to be viable candidates for large-scale energy storage devices in smart grid communities and electric vehicles. However, the energy density of previously proposed rechargeable magnesium batteries is low, limited mainly by the cathode materials. Here, we present new design approaches for the cathode in order to realize a high-energy-density rechargeable magnesium battery system. Ion-exchanged MgFeSiO4 demonstrates a high reversible capacity exceeding 300 mAh·g−1 at a voltage of approximately 2.4 V vs. Mg. Further, the electronic and crystal structure of ion-exchanged MgFeSiO4 changes during the charging and discharging processes, which demonstrates the (de)insertion of magnesium in the host structure. The combination of ion-exchanged MgFeSiO4 with a magnesium bis(trifluoromethylsulfonyl)imide–triglyme electrolyte system proposed in this work provides a low-cost and practical rechargeable magnesium battery with high energy density, free from corrosion and safety problems. PMID:25011939

  5. Theory and High-Energy-Density Laser Experiments Relevant to Accretion Processes in Cataclysmic Variables

    NASA Astrophysics Data System (ADS)

    Krauland, Christine; Drake, R.; Loupias, B.; Falize, E.; Busschaert, C.; Ravasio, A.; Yurchak, R.; Pelka, A.; Koenig, M.; Kuranz, C. C.; Plewa, T.; Huntington, C. M.; Kaczala, D. N.; Klein, S.; Sweeney, R.; Villete, B.; Young, R.; Keiter, P. A.

    2012-05-01

    We present results from high-energy-density (HED) laboratory experiments that explore the contribution of radiative shock waves to the evolving dynamics of the cataclysmic variable (CV) systems in which they reside. CVs can be classified under two main categories, non-magnetic and magnetic. In the process of accretion, both types involve strongly radiating shocks that provide the main source of radiation in the binary systems. This radiation can cause varying structure to develop depending on the optical properties of the material on either side of the shock. The ability of high-intensity lasers to create large energy densities in targets of millimeter-scale volume makes it feasible to create similar radiative shocks in the laboratory. We provide an overview of both CV systems and their connection to the designed and executed laboratory experiments preformed on two laser facilities. Available data and accompanying simulations will likewise be shown. Funded by the NNSA-DS and SC-OFES Joint Prog. in High-Energy-Density Lab. Plasmas, by the Nat. Laser User Facility Prog. in NNSA-DS and by the Predictive Sci. Acad. Alliances Prog. in NNSA-ASC, under grant numbers are DE-FG52-09NA29548, DE-FG52-09NA29034, and DE-FC52-08NA28616.

  6. Advanced intermediate temperature sodium-nickel chloride batteries with ultra-high energy density

    SciTech Connect

    Li, Guosheng; Lu, Xiaochuan; Kim, Jin Yong; Meinhardt, Kerry D.; Chang, Hee -Jung; Canfield, Nathan L.; Sprenkle, Vincent L.

    2016-02-11

    Here we demonstrate for the first time that planar Na-NiCl2 batteries can be operated at an intermediate temperature of 190°C with ultra-high energy density. A specific energy density of 350 Wh/kg, which is 3 times higher than that of conventional tubular Na-NiCl2 batteries operated at 280°C, was obtained for planar Na-NiCl2 batteries operated at 190°C over a long-term cell test (1000 cycles). The high energy density and superior cycle stability are attributed to the slower particle growth of the cathode materials (NaCl and Ni) at 190°C. The results reported in this work demonstrate that planar Na-NiCl2 batteries operated at an intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs.

  7. High-Energy Density and Superhard Nitrogen-Rich B-N Compounds

    NASA Astrophysics Data System (ADS)

    Li, Yinwei; Hao, Jian; Liu, Hanyu; Lu, Siyu; Tse, John S.

    2015-09-01

    The pressure-induced transformation of diatomic nitrogen into nonmolecular polymeric phases may produce potentially useful high-energy-density materials. We combine first-principles calculations with structure searching to predict a new class of nitrogen-rich boron nitrides with a stoichiometry of B3N5 that are stable or metastable relative to solid N2 and h -BN at ambient pressure. The most stable phase at ambient pressure has a layered structure (h -B3N5 ) containing hexagonal B3N3 layers sandwiched with intercalated freely rotating N2 molecules. At 15 GPa, a three-dimensional C 2 2 21 structure with single N-N bonds becomes the most stable. This pressure is much lower than that required for triple-to-single bond transformation in pure solid nitrogen (110 GPa). More importantly, C 2 2 21-B3N5 is metastable, and can be recovered under ambient conditions. Its energy density of ˜3.44 kJ /g makes it a potential high-energy-density material. In addition, stress-strain calculations estimate a Vicker's hardness of ˜4 4 GPa . Structure searching reveals a new clathrate sodalitelike BN structure that is metastable under ambient conditions.

  8. Unique aqueous Li-ion/sulfur chemistry with high energy density and reversibility.

    PubMed

    Yang, Chongyin; Suo, Liumin; Borodin, Oleg; Wang, Fei; Sun, Wei; Gao, Tao; Fan, Xiulin; Hou, Singyuk; Ma, Zhaohui; Amine, Khalil; Xu, Kang; Wang, Chunsheng

    2017-06-13

    Leveraging the most recent success in expanding the electrochemical stability window of aqueous electrolytes, in this work we create a unique Li-ion/sulfur chemistry of both high energy density and safety. We show that in the superconcentrated aqueous electrolyte, lithiation of sulfur experiences phase change from a high-order polysulfide to low-order polysulfides through solid-liquid two-phase reaction pathway, where the liquid polysulfide phase in the sulfide electrode is thermodynamically phase-separated from the superconcentrated aqueous electrolyte. The sulfur with solid-liquid two-phase exhibits a reversible capacity of 1,327 mAh/(g of S), along with fast reaction kinetics and negligible polysulfide dissolution. By coupling a sulfur anode with different Li-ion cathode materials, the aqueous Li-ion/sulfur full cell delivers record-high energy densities up to 200 Wh/(kg of total electrode mass) for >1,000 cycles at ∼100% coulombic efficiency. These performances already approach that of commercial lithium-ion batteries (LIBs) using a nonaqueous electrolyte, along with intrinsic safety not possessed by the latter. The excellent performance of this aqueous battery chemistry significantly promotes the practical possibility of aqueous LIBs in large-format applications.

  9. Ambipolar zinc-polyiodide electrolyte for a high-energy density aqueous redox flow battery

    SciTech Connect

    Li, Bin; Nie, Zimin; Vijayakumar, M.; Li, Guosheng; Liu, Jun; Sprenkle, Vincent L.; Wang, Wei

    2015-02-24

    Large-scale energy storage systems are crucial for substantial deployment of renewable energy sources. Energy storage systems with high energy density, high safety, and low cost and environmental friendliness are desired. To overcome the major limitations of the current aqueous redox flow battery systems, namely lower energy density (~25 Wh L-1) and presence of strong acids and/or other hazardous, a high energy density aqueous zinc/polyiodide flow battery (ZIB) is designed with near neutral ZnI2 solutions as catholytes. The energy density of ZIB could reach 322 Wh L-1 at the solubility limit of ZnI2 in water (~7 M). We demonstrate charge and discharge energy densities of 245.9 Wh/L and 166.7 Wh L-1 with ZnI2 electrolyte at 5.0 M, respectively. The addition of ethanol (EtOH) in ZnI2 electrolyte can effectively mitigate the growth of zinc dendrite at the anode and improve the stability of catholytes with wider temperature window (-20 to 50°C), which enable ZIB system to be a promising alternative as a high-energy and high- safety stationary energy storage system.

  10. High energy density rechargeable magnesium battery using earth-abundant and non-toxic elements.

    PubMed

    Orikasa, Yuki; Masese, Titus; Koyama, Yukinori; Mori, Takuya; Hattori, Masashi; Yamamoto, Kentaro; Okado, Tetsuya; Huang, Zhen-Dong; Minato, Taketoshi; Tassel, Cédric; Kim, Jungeun; Kobayashi, Yoji; Abe, Takeshi; Kageyama, Hiroshi; Uchimoto, Yoshiharu

    2014-07-11

    Rechargeable magnesium batteries are poised to be viable candidates for large-scale energy storage devices in smart grid communities and electric vehicles. However, the energy density of previously proposed rechargeable magnesium batteries is low, limited mainly by the cathode materials. Here, we present new design approaches for the cathode in order to realize a high-energy-density rechargeable magnesium battery system. Ion-exchanged MgFeSiO4 demonstrates a high reversible capacity exceeding 300 Ah · g(-1) at a voltage of approximately 2.4 V vs. Mg. Further, the electronic and crystal structure of ion-exchanged MgFeSiO4 changes during the charging and discharging processes, which demonstrates the (de)insertion of magnesium in the host structure. The combination of ion-exchanged MgFeSiO4 with a magnesium bis(trifluoromethylsulfonyl)imide-triglyme electrolyte system proposed in this work provides a low-cost and practical rechargeable magnesium battery with high energy density, free from corrosion and safety problems.

  11. Design and simulation of high-energy-density shear experiments on OMEGA and the NIF

    NASA Astrophysics Data System (ADS)

    Doss, F. W.; Devolder, B.; di Stefano, C.; Flippo, K. A.; Kline, J. L.; Kot, L.; Loomis, E. N.; Merritt, E. C.; Perry, T. S.; MacLaren, S. A.; Wang, P.; Zhou, Y. K.

    2015-11-01

    High-energy-density shear experiments have been performed by LANL at the OMEGA Laser Facility and National Ignition Facility (NIF). The experiments have been simulated using the LANL radiation-hydrocode RAGE and have been used to assess turbulence models' ability to function in the high-energy-density, inertial-fusion-relevant regime. Beginning with the basic configuration of two counter-oriented shock-driven flows of > 100 km/s, which initiate a strong shear instability across an initially solid density, 20 micron thick Al plate, variations of the experiment have been performed and are studied. These variations have included increasing the fluid density (by modifying the metal plate material from Al to Ti), imposing sinusoidal perturbations on the plate, and directly modifying the plate's intrinsic surface roughness. In addition to examining the shear-induced mixing, the simulations reveal other physics, such as how the interaction of our indirect-drive halfraums with a mated shock tube's ablator impedes a stagnation-driven shock. This work is conducted by the US DOE by LANL under contract DE-AC52-06NA25396, and NIF facility operations by LLNL under contract DE-AC52-07NA27344.

  12. Ambipolar zinc-polyiodide electrolyte for a high-energy density aqueous redox flow battery

    PubMed Central

    Li, Bin; Nie, Zimin; Vijayakumar, M.; Li, Guosheng; Liu, Jun; Sprenkle, Vincent; Wang, Wei

    2015-01-01

    Redox flow batteries are receiving wide attention for electrochemical energy storage due to their unique architecture and advantages, but progress has so far been limited by their low energy density (~25 Wh l−1). Here we report a high-energy density aqueous zinc-polyiodide flow battery. Using the highly soluble iodide/triiodide redox couple, a discharge energy density of 167 Wh l−1 is demonstrated with a near-neutral 5.0 M ZnI2 electrolyte. Nuclear magnetic resonance study and density functional theory-based simulation along with flow test data indicate that the addition of an alcohol (ethanol) induces ligand formation between oxygen on the hydroxyl group and the zinc ions, which expands the stable electrolyte temperature window to from −20 to 50 °C, while ameliorating the zinc dendrite. With the high-energy density and its benign nature free from strong acids and corrosive components, zinc-polyiodide flow battery is a promising candidate for various energy storage applications. PMID:25709083

  13. Tin-based inorganic-organic hybrid polymers for high energy-density applications

    NASA Astrophysics Data System (ADS)

    Tran, Huan; Kuma, Arun; Pilania, Ghanshyam; Ramprasad, Rampi

    2014-03-01

    In one of our recent works[1], an organotin polymer was synthesized and suggested to be promising polymeric dielectric, simultaneously exhibiting a high dielectric constant ɛ and a high band gap Eg. Motivated by this result, we study a family of inorganic-organic hybrid polymers based on -(SnF2) x-(CH2) y - as the repeating structural unit (x = 2 , y = 4 , 8 , and 12). The stable structures of these hybrid polymers, predicted by the minima-hopping method, are studied by first-principles calculations at the level of density functional theory. Our calculations show that these polymers are wide band gap materials (up to 6.07 eV). In addition, their dielectric constants are between 4.6 and 7.8, well above that of polypropylene (ɛ ~= 2 . 2), the standard dielectric material for high energy-density capacitors. Therefore, we suggest that the hybrid polymers based on -(SnF2) x-(CH2) y - are promising candidates for high energy-density applications. Our work is supported by the Office of Naval Research through the Multidisciplinary University Research Initiative (MURI).

  14. Ambipolar zinc-polyiodide electrolyte for a high-energy density aqueous redox flow battery.

    PubMed

    Li, Bin; Nie, Zimin; Vijayakumar, M; Li, Guosheng; Liu, Jun; Sprenkle, Vincent; Wang, Wei

    2015-02-24

    Redox flow batteries are receiving wide attention for electrochemical energy storage due to their unique architecture and advantages, but progress has so far been limited by their low energy density (~25 Wh l(-1)). Here we report a high-energy density aqueous zinc-polyiodide flow battery. Using the highly soluble iodide/triiodide redox couple, a discharge energy density of 167 Wh l(-1) is demonstrated with a near-neutral 5.0 M ZnI2 electrolyte. Nuclear magnetic resonance study and density functional theory-based simulation along with flow test data indicate that the addition of an alcohol (ethanol) induces ligand formation between oxygen on the hydroxyl group and the zinc ions, which expands the stable electrolyte temperature window to from -20 to 50 °C, while ameliorating the zinc dendrite. With the high-energy density and its benign nature free from strong acids and corrosive components, zinc-polyiodide flow battery is a promising candidate for various energy storage applications.

  15. Advanced intermediate temperature sodium-nickel chloride batteries with ultra-high energy density

    DOE PAGES

    Li, Guosheng; Lu, Xiaochuan; Kim, Jin Yong; ...

    2016-02-11

    Here we demonstrate for the first time that planar Na-NiCl2 batteries can be operated at an intermediate temperature of 190°C with ultra-high energy density. A specific energy density of 350 Wh/kg, which is 3 times higher than that of conventional tubular Na-NiCl2 batteries operated at 280°C, was obtained for planar Na-NiCl2 batteries operated at 190°C over a long-term cell test (1000 cycles). The high energy density and superior cycle stability are attributed to the slower particle growth of the cathode materials (NaCl and Ni) at 190°C. The results reported in this work demonstrate that planar Na-NiCl2 batteries operated at anmore » intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs.« less

  16. The National Ignition Facility: Status and Plans for Laser Fusion and High-Energy-Density Experimental Studies

    SciTech Connect

    Wuest, C

    2001-10-29

    The National Ignition Facility (NIF) currently under construction at the University of California Lawrence Livermore National Laboratory (LLNL) is a 192-beam, 1.8-megajoule, 500-terawatt, 351-nm laser for inertial confinement fusion (ICF) and high-energy-density experimental studies. NIF is being built by the Department of Energy and the National Nuclear Security Agency (NNSA) to provide an experimental test bed for the U.S. Stockpile Stewardship Program to ensure the country's nuclear deterrent without underground nuclear testing. The experimental program will encompass a wide range of physical phenomena from fusion energy production to materials science. Of the roughly 700 shots available per year, about 10% will be dedicated to basic science research. Laser hardware is modularized into line replaceable units (LRUs) such as deformable mirrors, amplifiers, and multi-function sensor packages that are operated by a distributed computer control system of nearly 60,000 control points. The supervisory control room presents facility-wide status and orchestrates experiments using operating parameters predicted by physics models. A network of several hundred front-end processors (FEPs) implements device control. The object-oriented software system is implemented in the Ada and Java languages and emphasizes CORBA distribution of reusable software objects. NIF is currently scheduled to provide first light in 2004 and will be completed in 2008.

  17. Richtmyer-Meshkov evolution under steady shock conditions in the high-energy-density regime

    DOE PAGES

    Di Stefano, C. A.; Malamud, G.; Kuranz, C. C.; ...

    2015-03-17

    This work presents direct experimental evidence of long-predicted nonlinear aspects of the Richtmyer-Meshkov (RM) process, in which new modes first arise from the coupling of initially-present modes, and in which shorter-wavelength modes are eventually overtaken by longer-wavelength modes. This is accomplished using a technique we developed employing a long driving laser pulse to create a strong (Mach ~ 8) shock across a well-characterized material interface seeded by a two-mode sinusoidal perturbation. Furthermore, this technique further permits the shock to be sustained, without decay of the high-energy-density flow conditions, long enough for the system to evolve into the nonlinear phase.

  18. Measurements of ion stopping around the Bragg peak in high-energy-density plasmas

    SciTech Connect

    Frenje, J. A.; Grabowski, P. E.; Li, C. K.; Seguin, F. H.; Zylstra, A. B.; Gatu Johnson, M.; Petrasso, R. D.; Glebov, V. Yu; Sangster, T. C.

    2015-11-09

    For the first time, quantitative measurements of ion stopping at energies about the Bragg peak (or peak ion stopping, which occurs at an ion velocity comparable to the average thermal electron velocity), and its dependence on electron temperature (Te) and electron number density (ne) in the range of 0.5 – 4.0 keV and 3 × 1022 – 3 × 1023 cm-3 have been conducted, respectively. It is experimentally demonstrated that the position and amplitude of the Bragg peak varies strongly with Te with ne. As a result, the importance of including quantum diffraction is also demonstrated in the stopping-power modeling of High-Energy-Density Plasmas.

  19. Mixed metal oxides as alternate cathodes for high energy density electric propulsion

    SciTech Connect

    Papp, J.E.

    1995-12-31

    Silver (II) oxide is currently the Navy`s cathode of choice in high energy density, high rate batteries for torpedo and mobile target applications, for medium rate applications such as Seal Delivery Vehicles, and may be useful for low rate, long endurance UUV missions. While it is certainly a versatile material, silver (II) oxide is expensive to produce and has a lower faradaic (storage) capacity than desired. New research being conducted at the NUWC electric propulsion laboratory is focused toward developing new, lower cost cathode materials with energy densities at least comparable to silver (II) oxide. Mixed metal oxides, with silver (II) oxide as one component, are under investigation. Other materials, without a silver component, are also being considered. This poster will illustrate recent developments in the modification of the silver (II) oxide cathode for Navy applications.

  20. High Energy Density Additives for Hybrid Fuel Rockets to Improve Performance and Enhance Safety

    NASA Technical Reports Server (NTRS)

    Jaffe, Richard L.

    2014-01-01

    We propose a conceptual study of prototype strained hydrocarbon molecules as high energy density additives for hybrid rocket fuels to boost the performance of these rockets without compromising safety and reliability. Use of these additives could extend the range of applications for which hybrid rockets become an attractive alternative to conventional solid or liquid fuel rockets. The objectives of the study were to confirm and quantify the high enthalpy of these strained molecules and to assess improvement in rocket performance that would be expected if these additives were blended with conventional fuels. We confirmed the chemical properties (including enthalpy) of these additives. However, the predicted improvement in rocket performance was too small to make this a useful strategy for boosting hybrid rocket performance.

  1. Measurements of ion stopping around the Bragg peak in high-energy-density plasmas

    DOE PAGES

    Frenje, J. A.; Grabowski, P. E.; Li, C. K.; ...

    2015-11-09

    For the first time, quantitative measurements of ion stopping at energies about the Bragg peak (or peak ion stopping, which occurs at an ion velocity comparable to the average thermal electron velocity), and its dependence on electron temperature (Te) and electron number density (ne) in the range of 0.5 – 4.0 keV and 3 × 1022 – 3 × 1023 cm-3 have been conducted, respectively. It is experimentally demonstrated that the position and amplitude of the Bragg peak varies strongly with Te with ne. As a result, the importance of including quantum diffraction is also demonstrated in the stopping-power modelingmore » of High-Energy-Density Plasmas.« less

  2. Sparingly solvating electrolytes for high energy density Lithium–sulfur batteries

    SciTech Connect

    Cheng, Lei; Curtiss, Larry A.; Zavadil, Kevin R.; Gewirth, Andrew A.; Shao, Yuyan; Gallagher, Kevin G.

    2016-07-11

    Moving to lighter and less expensive battery chemistries compared to lithium-ion requires the control of energy storage mechanisms based on chemical transformations rather than intercalation. Lithium sulfur (Li/S) has tremendous theoretical specific energy, but contemporary approaches to control this solution-mediated, precipitation-dissolution chemistry requires using large excesses of electrolyte to fully solubilize the polysulfide intermediate. Achieving reversible electrochemistry under lean electrolyte operation is the only path for Li/S to move beyond niche applications to potentially transformational performance. An emerging topic for Li/S research is the use of sparingly solvating electrolytes and the creation of design rules for discovering new electrolyte systems that fundamentally decouple electrolyte volume from reaction mechanism. Furthermore, this perspective presents an outlook for sparingly solvating electrolytes as the key path forward for longer-lived, high-energy density Li/S batteries including an overview of this promising new concept and some strategies for accomplishing it.

  3. Ferroelectric polymer networks with high energy density and improved discharged efficiency for dielectric energy storage.

    PubMed

    Khanchaitit, Paisan; Han, Kuo; Gadinski, Matthew R; Li, Qi; Wang, Qing

    2013-01-01

    Ferroelectric polymers are being actively explored as dielectric materials for electrical energy storage applications. However, their high dielectric constants and outstanding energy densities are accompanied by large dielectric loss due to ferroelectric hysteresis and electrical conduction, resulting in poor charge-discharge efficiencies under high electric fields. To address this long-standing problem, here we report the ferroelectric polymer networks exhibiting significantly reduced dielectric loss, superior polarization and greatly improved breakdown strength and reliability, while maintaining their fast discharge capability at a rate of microseconds. These concurrent improvements lead to unprecedented charge-discharge efficiencies and large values of the discharged energy density and also enable the operation of the ferroelectric polymers at elevated temperatures, which clearly outperforms the melt-extruded ferroelectric polymer films that represents the state of the art in dielectric polymers. The simplicity and scalability of the described method further suggest their potential for high energy density capacitors.

  4. Infant-mortality testing of high-energy-density capacitors used on Nova

    SciTech Connect

    Merritt, B.T.; Whitham, K.

    1983-01-01

    Nova is a solid-state large laser for inertial-confinement fusion research. Its flashlamps are driven by a 60-MJ capacitor bank. Part of this bank is being built with high-energy-density capacitors, 52-..mu..F, 22 kV, 12.5 kJ. A total of 2645 of these capacitors have been purchased from two manufacturers. Each capacitor was infant-mortality tested. The first test consisted of a high-potential test, bushing-to-case, since these capacitors have dual bushings. Then the capacitors were discharged 500 times with circuit conditions approximating the capacitors normal flashlamp load. Failure of either of these tests or if the capacitor was leaking was cause for rejection.

  5. Reduced entropic model for studies of multidimensional nonlocal transport in high-energy-density plasmas

    NASA Astrophysics Data System (ADS)

    Del Sorbo, D.; Feugeas, J.-L.; Nicolaï, Ph.; Olazabal-Loumé, M.; Dubroca, B.; Guisset, S.; Touati, M.; Tikhonchuk, V.

    2015-08-01

    Hydrodynamic simulations of high-energy-density plasmas require a detailed description of energy fluxes. For low and intermediate atomic number materials, the leading mechanism is the electron transport, which may be a nonlocal phenomenon requiring a kinetic modeling. In this paper, we present and test the results of a nonlocal model based on the first angular moments of a simplified Fokker-Planck equation. This multidimensional model is closed thanks to an entropic relation (the Boltzman H-theorem). It provides a better description of the electron distribution function, thus enabling studies of small scale kinetic effects within the hydrodynamic framework. Examples of instabilities of electron plasma and ion-acoustic waves, driven by the heat flux, are presented and compared with the classical formula.

  6. High Energy Density Utracapacitors: Low-Cost, High Energy and Power Density, Nanotube-Enhanced Ultracapacitors

    SciTech Connect

    2010-04-01

    Broad Funding Opportunity Announcement Project: FastCAP is improving the performance of an ultracapacitor—a battery-like electronic device that can complement, and possibly even replace, an HEV or EV battery pack. Ultracapacitors have many advantages over conventional batteries, including long lifespans (over 1 million cycles, as compared to 10,000 for conventional batteries) and better durability. Ultracapacitors also charge more quickly than conventional batteries, and they release energy more quickly. However, ultracapacitors have fallen short of batteries in one key metric: energy density—high energy density means more energy storage. FastCAP is redesigning the ultracapacitor’s internal structure to increase its energy density. Ultracapacitors traditionally use electrodes made of irregularly shaped, porous carbon. FastCAP’s ultracapacitors are made of tiny, aligned carbon nanotubes. The nanotubes provide a regular path for ions moving in and out of the ultracapacitor’s electrode, increasing the overall efficiency and energy density of the device.

  7. Three-dimensional modeling and analysis of a high energy density Kelvin-Helmholtz experiment

    SciTech Connect

    Raman, K. S.; Hurricane, O. A.; Park, H.-S.; Remington, B. A.; Robey, H.; Smalyuk, V. A.; Drake, R. P.; Krauland, C. M.; Kuranz, C. C.; Hansen, J. F.; Harding, E. C.

    2012-09-15

    A recent series of experiments on the OMEGA laser provided the first controlled demonstration of the Kelvin-Helmholtz (KH) instability in a high-energy-density physics context [E. C. Harding et al., Phys. Rev. Lett. 103, 045005, (2009); O. A. Hurricane et al., Phys. Plasmas 16, 056305, (2009)]. We present 3D simulations which resolve previously reported discrepancies between those experiments and the 2D simulation used to design them. Our new simulations reveal a three-dimensional mechanism behind the low density 'bubble' structures which appeared in the experimental x-ray radiographs at late times but were completely absent in the 2D simulations. We also demonstrate that the three-dimensional expansion of the walls of the target is sufficient to explain the 20% overprediction by 2D simulation of the late-time growth of the KH rollups. The implications of these results for the design of future experiments are discussed.

  8. Schlieren technique applied to the arc temperature measurement in a high energy density cutting torch

    SciTech Connect

    Prevosto, L.; Mancinelli, B.; Artana, G.; Kelly, H.

    2010-01-15

    Plasma temperature and radial density profiles of the plasma species in a high energy density cutting arc have been obtained by using a quantitative schlieren technique. A Z-type two-mirror schlieren system was used in this research. Due to its great sensibility such technique allows measuring plasma composition and temperature from the arc axis to the surrounding medium by processing the gray-level contrast values of digital schlieren images recorded at the observation plane for a given position of a transverse knife located at the exit focal plane of the system. The technique has provided a good visualization of the plasma flow emerging from the nozzle and its interactions with the surrounding medium and the anode. The obtained temperature values are in good agreement with those values previously obtained by the authors on the same torch using Langmuir probes.

  9. Nuclear science research with dynamic high energy density plasmas at NIF

    NASA Astrophysics Data System (ADS)

    Shaughnessy, D. A.; Gharibyan, N.; Moody, K. J.; Despotopulos, J. D.; Grant, P. M.; Yeamans, C. B.; Berzak Hopkins, L.; Cerjan, C. J.; Schneider, D. H. G.; Faye, S.

    2016-05-01

    Nuclear reaction measurements are performed at the National Ignition Facility in a high energy density plasma environment by adding target materials to the outside of the hohlraum thermo-mechanical package on an indirect-drive exploding pusher shot. Materials are activated with 14.1-MeV neutrons and the post-shot debris is collected via the Solid Radiochemistry diagnostic, which consists of metal discs fielded 50 cm from target chamber center. The discs are removed post-shot and analyzed via radiation counting and mass spectrometry. Results from a shot using Nd and Tm foils as targets are presented, which indicate enhanced collection of the debris in the line of sight of a given collector. The capsule performance was not diminished due to the extra material. This provides a platform for future measurements of nuclear reaction data through the use of experimental packages mounted external to the hohlraum.

  10. A high-energy-density, high-Mach number single jet experiment

    SciTech Connect

    Hansen, J. F.; Dittrich, T. R.; Elliott, J. B.; Glendinning, S. G.; Cotrell, D. L.

    2011-08-15

    A high-energy-density, x-ray-driven, high-Mach number (M{>=} 17) single jet experiment shows constant propagation speeds of the jet and its bowshock into the late time regime. The jet assumes a characteristic mushroom shape with a stalk and a head. The width of the head and the bowshock also grow linearly in time. The width of the stalk decreases exponentially toward an asymptotic value. In late time images, the stalk kinks and develops a filamentary nature, which is similar to experiments with applied magnetic fields. Numerical simulations match the experiment reasonably well, but ''exterior'' details of the laser target must be included to obtain a match at late times.

  11. Evaluation of room-temperature chloroaluminate molten salts as electrolytes for high energy density batteries

    NASA Astrophysics Data System (ADS)

    Vaughn, R. L.

    1990-04-01

    This report reviews past battery studies using room-temperature chloroaluminate electrolytes, pointing out problems experienced. The report then summarizes attempts to circumvent these problems. A cell is described that uses a sodium anode, a copper (II) chloride cathode, and room-temperature chloroaluminate electrolyte buffered to the neutral composition. Cells give an open circuit voltage greater than 2.75 volts and discharge near 1 milliAmperes per centimeters squared at voltages greater than 2 volts for more than 20 hours. Cell failure is attributed to the formation of a nonconductive coating on the sodium electrode. Suggestions for future studies are presented. While the room-temperature chloroaluminates appear suitable for high-voltage, low-current batteries, their physical properties may limit their potential for high energy density batteries.

  12. Collaborative comparison of simulation codes for high-energy-density physics applications

    NASA Astrophysics Data System (ADS)

    Fatenejad, M.; Fryxell, B.; Wohlbier, J.; Myra, E.; Lamb, D.; Fryer, C.; Graziani, C.

    2013-03-01

    Advances in plasma physics, powerful lasers, and pulsed-power machines have made possible experiments allowing detailed exploration and discoveries about states of matter at high energy densities. Since these experiments are expensive to perform and difficult to diagnose, numerical simulations have played an important part in designing and understanding them. A number of sophisticated radiation-hydrodynamic codes have been developed to perform this task. We will describe a new collaboration to compare three of these codes for a variety of test problems. Current members of this collaboration are the Center for Radiative Shock Hydrodynamics (CRASH) at the University of Michigan, the FLASH Center at the University of Chicago, and Los Alamos National Laboratory (LANL). These code comparisons have enabled us to understand differences in numerical methods, physical approximations, microphysical parameters, etc. The net result has been an improvement in the codes and higher confidence in the simulation results. This paper presents the results of a subset of these comparison tests.

  13. Performance of bent-crystal x-ray microscopes for high energy density physics research.

    PubMed

    Schollmeier, Marius S; Geissel, Matthias; Shores, Jonathon E; Smith, Ian C; Porter, John L

    2015-06-01

    We present calculations for the field of view (FOV), image fluence, image monochromaticity, spectral acceptance, and image aberrations for spherical crystal microscopes, which are used as self-emission imaging or backlighter systems at large-scale high energy density physics facilities. Our analytic results are benchmarked with ray-tracing calculations as well as with experimental measurements from the 6.151 keV backlighter system at Sandia National Laboratories. The analytic expressions can be used for x-ray source positions anywhere between the Rowland circle and object plane. This enables quick optimization of the performance of proposed but untested, bent-crystal microscope systems to find the best compromise between FOV, image fluence, and spatial resolution for a particular application.

  14. Schlieren technique applied to the arc temperature measurement in a high energy density cutting torch

    NASA Astrophysics Data System (ADS)

    Prevosto, L.; Artana, G.; Mancinelli, B.; Kelly, H.

    2010-01-01

    Plasma temperature and radial density profiles of the plasma species in a high energy density cutting arc have been obtained by using a quantitative schlieren technique. A Z-type two-mirror schlieren system was used in this research. Due to its great sensibility such technique allows measuring plasma composition and temperature from the arc axis to the surrounding medium by processing the gray-level contrast values of digital schlieren images recorded at the observation plane for a given position of a transverse knife located at the exit focal plane of the system. The technique has provided a good visualization of the plasma flow emerging from the nozzle and its interactions with the surrounding medium and the anode. The obtained temperature values are in good agreement with those values previously obtained by the authors on the same torch using Langmuir probes.

  15. High-Energy-Density Laboratory Astrophysics Studies of Jets and Bow Shocks

    NASA Astrophysics Data System (ADS)

    Foster, J. M.; Wilde, B. H.; Rosen, P. A.; Williams, R. J. R.; Blue, B. E.; Coker, R. F.; Drake, R. P.; Frank, A.; Keiter, P. A.; Khokhlov, A. M.; Knauer, J. P.; Perry, T. S.

    2005-11-01

    We present the first results from high-energy-density laboratory astrophysics experiments that explore the interaction of supersonic jets/outflows with an ambient medium. Our experiments were conducted on the Omega laser facility, a large Inertial Confinement Fusion facility. In our experiments, a laser pulse drives a supersonic jet into foam. High-resolution X-ray radiography reveals the resulting highly structured bow shock. These are the first laboratory astrophysics experiments to capture the behavior of both the jet and the bow shock. We discuss the astrophysical relevance of the flow processes that we observe in the experiments and in the accompanying numerical models. Scaling arguments suggest that our experiments are most directly relevant to active galactic nucleus jets and planetary nebula outflows, while future work may allow our experiments to extend into regimes relevant to radiative outflows from young stellar objects. Contains material © British Crown Copyright 2005/MOD, reprinted with permission.

  16. Time- and space-resolved elliptical crystal spectrometers for high energy density physics research

    SciTech Connect

    Lake, P.W.; Bailey, J.E.; Rochau, G.A.; Moore, T.C.; Petmecky, D.; Gard, P.

    2004-10-01

    X-ray spectrometers used in high energy density plasma experiments must provide high time, space, and spectral resolution while overcoming the difficulties imposed by x-ray background, debris, and mechanical shocks. At the Z facility these problems are addressed using a suite of elliptical crystal spectrometers. The elliptical geometry isolates the detector from the line of sight with a slit placed at the elliptical focus, while the sensitivity enables locating the crystal 2-4 m from the plasma source. Space and time resolution are obtained by using an array of slits to project one dimensional plasma images onto the crystal and recording the spectrally dispersed images with a gated microchannel plate detector.

  17. Asymmetric battery having a semi-solid cathode and high energy density anode

    DOEpatents

    Tan, Taison; Chiang, Yet-Ming; Ota, Naoki; Wilder, Throop; Duduta, Mihai

    2016-09-06

    Embodiments described herein relate generally to devices, systems and methods of producing high energy density batteries having a semi-solid cathode that is thicker than the anode. An electrochemical cell can include a positive electrode current collector, a negative electrode current collector and an ion-permeable membrane disposed between the positive electrode current collector and the negative electrode current collector. The ion-permeable membrane is spaced a first distance from the positive electrode current collector and at least partially defines a positive electroactive zone. The ion-permeable membrane is spaced a second distance from the negative electrode current collector and at least partially defines a negative electroactive zone. The second distance is less than the first distance. A semi-solid cathode that includes a suspension of an active material and a conductive material in a non-aqueous liquid electrolyte is disposed in the positive electroactive zone, and an anode is disposed in the negative electroactive zone.

  18. Sparingly solvating electrolytes for high energy density Lithium–sulfur batteries

    SciTech Connect

    Cheng, Lei; Curtiss, Larry A.; Zavadil, Kevin R.; Gewirth, Andrew A.; Shao, Yuyan; Gallagher, Kevin G.

    2016-07-11

    Moving to lighter and less expensive battery chemistries compared to lithium-ion requires the control of energy storage mechanisms based on chemical transformations rather than intercalation. Lithium sulfur (Li/S) has tremendous theoretical specific energy, but contemporary approaches to control this solution-mediated, precipitation-dissolution chemistry requires using large excesses of electrolyte to fully solubilize the polysulfide intermediate. Achieving reversible electrochemistry under lean electrolyte operation is the only path for Li/S to move beyond niche applications to potentially transformational performance. An emerging topic for Li/S research is the use of sparingly solvating electrolytes and the creation of design rules for discovering new electrolyte systems that fundamentally decouple electrolyte volume from reaction mechanism. Furthermore, this perspective presents an outlook for sparingly solvating electrolytes as the key path forward for longer-lived, high-energy density Li/S batteries including an overview of this promising new concept and some strategies for accomplishing it.

  19. Reduced entropic model for studies of multidimensional nonlocal transport in high-energy-density plasmas

    SciTech Connect

    Del Sorbo, D.; Feugeas, J.-L.; Nicolaï, Ph.; Olazabal-Loumé, M.; Dubroca, B.; Guisset, S.; Touati, M.; Tikhonchuk, V.

    2015-08-15

    Hydrodynamic simulations of high-energy-density plasmas require a detailed description of energy fluxes. For low and intermediate atomic number materials, the leading mechanism is the electron transport, which may be a nonlocal phenomenon requiring a kinetic modeling. In this paper, we present and test the results of a nonlocal model based on the first angular moments of a simplified Fokker-Planck equation. This multidimensional model is closed thanks to an entropic relation (the Boltzman H-theorem). It provides a better description of the electron distribution function, thus enabling studies of small scale kinetic effects within the hydrodynamic framework. Examples of instabilities of electron plasma and ion-acoustic waves, driven by the heat flux, are presented and compared with the classical formula.

  20. Demonstration of repeatability in a high-energy-density planar shear mixing layer experiment

    NASA Astrophysics Data System (ADS)

    Merritt, E. C.; Doss, F. W.; Di Stefano, C. A.; Flippo, K. A.; Rasmus, A. M.; Schmidt, D. W.

    2017-06-01

    On laser-driven platforms the assumption of experiment repeatability is particularly important due to a typically low data acquisition rate that doesn't often allow for data redundancy. If the platform is repeatable, then measurements of the repeatable dynamics from multiple experiments can be treated as measurements of the same system. In high-energy-density hydrodynamic instability experiments the interface growth is assumed to be one of the repeatable aspects of the system. In this paper we demonstrate the repeatability of the instability growth in the counter-propagating shear experiment at the OMEGA laser facility, where the instability growth is characterized by the tracer layer thickness or mix-width evolution. In our previous experiment campaigns we have assumed the instability growth was repeatable enough to identify trends, but in this work we explicitly show that the mix-width measurements for nominally identical experiments are repeatable within the measurement error bars.

  1. Performance of bent-crystal x-ray microscopes for high energy density physics research

    DOE PAGES

    Schollmeier, Marius S.; Geissel, Matthias; Shores, Jonathon E.; ...

    2015-05-29

    We present calculations for the field of view (FOV), image fluence, image monochromaticity, spectral acceptance, and image aberrations for spherical crystal microscopes, which are used as self-emission imaging or backlighter systems at large-scale high energy density physics facilities. Our analytic results are benchmarked with ray-tracing calculations as well as with experimental measurements from the 6.151 keV backlighter system at Sandia National Laboratories. Furthermore, the analytic expressions can be used for x-ray source positions anywhere between the Rowland circle and object plane. We discovered that this enables quick optimization of the performance of proposed but untested, bent-crystal microscope systems to findmore » the best compromise between FOV, image fluence, and spatial resolution for a particular application.« less

  2. Measurements of Ion Stopping Around the Bragg Peak in High-Energy-Density Plasmas.

    PubMed

    Frenje, J A; Grabowski, P E; Li, C K; Séguin, F H; Zylstra, A B; Gatu Johnson, M; Petrasso, R D; Glebov, V Yu; Sangster, T C

    2015-11-13

    For the first time, quantitative measurements of ion stopping at energies around the Bragg peak (or peak ion stopping, which occurs at an ion velocity comparable to the average thermal electron velocity), and its dependence on electron temperature (T(e)) and electron number density (n(e)) in the range of 0.5-4.0 keV and 3×10(22) to 3×10(23) cm(-3) have been conducted, respectively. It is experimentally demonstrated that the position and amplitude of the Bragg peak varies strongly with T(e) with n(e). The importance of including quantum diffraction is also demonstrated in the stopping-power modeling of high-energy-density plasmas.

  3. Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur Batteries

    SciTech Connect

    Cheng, Lei; Curtiss, Larry A.; Zavadil, Kevin R.; Gewirth, Andrew A.; Shao, Yuyan; Gallagher, Kevin

    2016-07-11

    Moving to lighter and less expensive battery chemistries compared to lithium-ion requires the control of energy storage mechanisms based on chemical transformations rather than intercalation. Lithium sulfur (Li/S) has tremendous theoretical specific energy, but contemporary approaches to control this solution-mediated, precipitation-dissolution chemistry requires using large excesses of electrolyte to fully solubilize the polysulfide intermediate. Achieving reversible electrochemistry under lean electrolyte operation is the only path for Li/S to move beyond niche applications to potentially transformational performance. An emerging topic for Li/S research is the use of sparingly solvating electrolytes and the creation of design rules for discovering new electrolyte systems that fundamentally decouple electrolyte volume from reaction mechanism. This perspective presents an outlook for sparingly solvating electrolytes as the key path forward for longer-lived, high-energy density Li/S batteries including an overview of this promising new concept and some strategies for accomplishing it.

  4. First-principle Calculations of Equation of State for Metals at High Energy Density

    NASA Astrophysics Data System (ADS)

    Minakov, Dmitry; Levashov, Pavel; Khishchenko, Konstantin

    2012-02-01

    In this work, we present quantum molecular dynamics calculations of the shock Hugoniots of solid and porous samples as well as release isentropes and isentropic sound velocity behind the shock front for aluminum. Also we perform similar calculations for nickel and iron. We use the VASP code with ultrasoft and PAW pseudopotentials and GGA exchange-correlation functional. Up to 512 particles have been used in calculations. To calculate Hugoniots we solve the Hugoniot equation numerically. To obtain release isentropes, we use Zel'dovich's approach and integrate an ordinary differential equation for the temperature thus restoring all thermodynamic parameters. Isentropic sound velocity is calculated by differentiation of pressure along isentropes. The results of our calculations are in good agreement with experimental data at densities both higher and lower than the normal one. Thus, quantum molecular dynamics results can be effectively used for verification or calibration of semiempirical equations of state under conditions of lack of experimental information at high energy densities.

  5. High Energy Density Thermal Batteries: Thermoelectric Reactors for Efficient Automotive Thermal Storage

    SciTech Connect

    2011-11-15

    HEATS Project: Sheetak is developing a new HVAC system to store the energy required for heating and cooling in EVs. This system will replace the traditional refrigerant-based vapor compressors and inefficient heaters used in today’s EVs with efficient, light, and rechargeable hot-and-cold thermal batteries. The high energy density thermal battery—which does not use any hazardous substances—can be recharged by an integrated solid-state thermoelectric energy converter while the vehicle is parked and its electrical battery is being charged. Sheetak’s converters can also run on the electric battery if needed and provide the required cooling and heating to the passengers—eliminating the space constraint and reducing the weight of EVs that use more traditional compressors and heaters.

  6. Performance of bent-crystal x-ray microscopes for high energy density physics research

    SciTech Connect

    Schollmeier, Marius S.; Geissel, Matthias; Shores, Jonathon E.; Smith, Ian C.; Porter, John L.

    2015-05-29

    We present calculations for the field of view (FOV), image fluence, image monochromaticity, spectral acceptance, and image aberrations for spherical crystal microscopes, which are used as self-emission imaging or backlighter systems at large-scale high energy density physics facilities. Our analytic results are benchmarked with ray-tracing calculations as well as with experimental measurements from the 6.151 keV backlighter system at Sandia National Laboratories. Furthermore, the analytic expressions can be used for x-ray source positions anywhere between the Rowland circle and object plane. We discovered that this enables quick optimization of the performance of proposed but untested, bent-crystal microscope systems to find the best compromise between FOV, image fluence, and spatial resolution for a particular application.

  7. Stable High-Energy Density Super-Atom Clusters of Aluminum Hydride

    NASA Astrophysics Data System (ADS)

    Lian, Ke-yan; Jiang, Yuan-fei; Fei, De-hou; Feng, Wei; Jin, Ming-xing; Ding, Da-jun; Luo, Yi

    2012-04-01

    With the concept of super-atom, first principles calculations propose a new type of super stable cage clusters AlnH3n that are much more energetic stable than the well established clusters, AlnHn+2. In the new clusters, the aluminum core-frame acts as a super-atom with n vertexes and 2n Al-Al edges, which allow to adsorb n hydrogen atoms at the top-site and 2n at the bridge-site. Using Al12H36 as the basic unit, stable chain structures, (Al12H36)m, have been constructed following the same connection mechanism as for (AlH3)n linear polymeric structures. Apart from high hydrogen percentage per molecule, calculations have shown that these new clusters possess large heat of formation values and their combustion heat is about 4.8 times of the methane, making them a promising high energy density material.

  8. Generation of high-energy-density ion bunches by ultraintense laser-cone-target interaction

    SciTech Connect

    Yang, X. H.; Zhuo, H. B. Ma, Y. Y.; Zou, D. B.; Yu, T. P.; Ge, Z. Y.; Yin, Y.; Shao, F. Q.; Yu, W.; Xu, H.; Borghesi, M.

    2014-06-15

    A scheme in which carbon ion bunches are accelerated to a high energy and density by a laser pulse (∼10{sup 21} W/cm{sup 2}) irradiating cone targets is proposed and investigated using particle-in-cell simulations. The laser pulse is focused by the cone and drives forward an ultrathin foil located at the cone's tip. In the course of the work, best results were obtained employing target configurations combining a low-Z cone with a multispecies foil transversely shaped to match the laser intensity profile.

  9. Miniature Internal Combustion Engine-Generator for High Energy Density Portable Power

    DTIC Science & Technology

    2008-12-01

    operative combustion mechanism. We note that for most conditions, glow plug assist is currently necessary to sustain combustion during starting and warmup ...very effective at maintaining a constant voltage and stroke as the HCCI combustion pressure varies during engine warmup . The current is modulated by the

  10. The High Energy Density science instrument at the European XFEL, Hamburg, Germany: a new platform for shock compression research

    NASA Astrophysics Data System (ADS)

    Appel, Karen; Nakatsutsumi, Motoaki; Priebe, Gerd; Pelka, Alexander; Thorpe, Ian; Tschentscher, Thomas

    2015-06-01

    The High Energy Density science instrument (HED) at the European XFEL, Hamburg, Germany will provide unique experimental possibilities for the investigation of near solid material driven to extreme states and will also establish a new platform to study materials response to shock compression. HED is located at the SASE2 undulator, which provides up to 27000 pulses per second with about 1012 photons per pulse, photon energies between 3 and 24 keV and pulse lengths of 2 - 100 fs. Self-seeding is foreseen, as well as natural bandwidth (BW) SASE radiation. In addition, energy BW of 10-4 and 10-6 will be available through monochromators. Focussing is based on CRL optics, which will allow to provide beam sizes of 2 μm, 10-20 μm and 150 - 260 μm at the sample position. Samples will be driven to extreme states by different types of optical lasers (either 200 kHz/3 mJ/15 fs, 10 Hz/100 TW/30 fs or 10 Hz/100J/ns), the pump-probe FEL beam (delays of up to 2 -23 ps for 5 -20 keV using a split-and-delay unit) and pulsed magnetic fields (up to 50 T). Pump probe experiments can be performed at adapted repetition rates (4.5 MHz, 1 - 10 Hz, single shot). X-ray techniques comprise diffraction, imaging and spectroscopic methods. User operation is planned for fall 2017. We will present the science case of HED, the current layout and present ideas on first shock compression experiments.

  11. A High Energy Density Shock Driven Kelvin-Helmholtz Shear Layer Experiment

    NASA Astrophysics Data System (ADS)

    Hurricane, Omar

    2008-11-01

    In 2002, a high energy density Kelvin-Helmholtz (KH) instability experiment was designed (O.A. Hurricane, High Energy Density Phys., 2008) for the National Ignition Facility (NIF) Early Light experiment. However, the long backlighter delay, required for the experiments success, could not be accommodated by NIF at that time. In early 2008, this experiment proposal was resurrected by our team, the target was fabricated at Livermore with final assembly at the University of Michigan, and then fielded at the Omega laser facility. The data return from the four shots of the experiment series exceeded expectation. In this paper, we describe the theory and simulation behind the experiment design, the unusual target construction, and present the radiographic data from the Omega experiment in raw form and a preliminary analysis of the data. Discussion of the target design theory and simulations focuses on the key role played by baroclinic vorticity production in the functioning of the target and also illuminates the key design parameters. The data shows the complete evolution of large distinct KH eddies, from formation to turbulent break-up. The data appears to graphically confirm a theoretical fluid dynamics conjecture about the existence of supersonic bubbles over the vortical structure [transonic convective Mach numbers (D. Papamoschou and A. Roshko, J. Fluid Mech., 197, 1988)] that support localized shocks (shocklets) not extending into the free-stream^ (P.E. Dimotakis, AIAA 91-1724, Proc. 22^nd Fluid Dyn., Plasma Dyn., & Lasers Conf., 1991). The consequences of these observations on understanding the turbulent transition, growth-rates and mixing in compressible supersonic turbulent shear layers will be discussed. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. A National Laser Users Facility grant also supported this work. Collaborators: J.F. Hansen, E.C. Harding , R

  12. Aromatic poly(arylene ether urea) with high dipole moment for high thermal stability and high energy density capacitors

    NASA Astrophysics Data System (ADS)

    Cheng, Zhaoxi; Lin, Minren; Wu, Shan; Thakur, Yash; Zhou, Yue; Jeong, Dae-Yong; Shen, Qundong; Zhang, Q. M.

    2015-05-01

    Developing dielectric polymers with higher dielectric constant without sacrificing loss and thermal stability is of great importance for next generation of high energy density capacitors. We show here that by replacing the CH2 group in the aromatic polyurea (ArPU) with the polar ether group, thus raising the dipole moment of the molecular unit, poly(arylene ether urea) (PEEU) shows an increased dielectric constant of 4.7, compared with 4.2 of ArPU. Moreover, PEEU maintains the low dielectric loss and is thermally stable up to 250 °C. As a result, the polymer delivers 13 J/cm3 discharged energy density at room temperature and 9 J/cm3 at 120 °C. The high quality films perform well in terms of both breakdown strength (at 700 MV/m at room temperature) and leakage current from room temperature to elevated temperature. At 120 °C, the breakdown strength is 600 MV/m and the conductivity is 1.58 × 10-14 S/cm measured under 100 MV/m.

  13. Validation of a Turbulent Kelvin-Helmholtz Shear Layer Model Using a High-Energy-Density OMEGA Laser Experiment

    NASA Astrophysics Data System (ADS)

    Hurricane, O. A.; Smalyuk, V. A.; Raman, K.; Schilling, O.; Hansen, J. F.; Langstaff, G.; Martinez, D.; Park, H.-S.; Remington, B. A.; Robey, H. F.; Greenough, J. A.; Wallace, R.; Di Stefano, C. A.; Drake, R. P.; Marion, D.; Krauland, C. M.; Kuranz, C. C.

    2012-10-01

    Following the successful demonstration of an OMEGA laser-driven platform for generating and studying nearly two-dimensional unstable plasma shear layers [Hurricane et al., Phys. Plasmas 16, 056305 (2009)PHPAEN1070-664X10.1063/1.3096790; Harding et al., Phys. Rev. Lett. 103, 045005 (2009)PRLTAO0031-900710.1103/PhysRevLett.103.045005], this Letter reports on the first quantitative measurement of turbulent mixing in a high-energy-density plasma. As a blast wave moves parallel to an unperturbed interface between a low-density foam and a high-density plastic, baroclinic vorticity is deposited at the interface and a Kelvin-Helmholtz instability-driven turbulent mixing layer is created in the postshock flow due to surface roughness. The spatial scale and density profile of the turbulent layer are diagnosed using x-ray radiography with sufficiently small uncertainty so that the data can be used to constrain turbulent mixing models. The estimated Reynolds number (˜106), Liepmann-Taylor scale (˜0.5μm), and inner viscous scale (˜0.17μm) in the postshock plasma flow are consistent with an “inertial subrange,” within which a Kolmogorov turbulent energy cascade can be active. An illustration of comparing the data set with the predictions of a two-equation turbulence model in the ares radiation hydrodynamics code is also presented.

  14. Validation of a turbulent Kelvin-Helmholtz shear layer model using a high-energy-density OMEGA laser experiment.

    PubMed

    Hurricane, O A; Smalyuk, V A; Raman, K; Schilling, O; Hansen, J F; Langstaff, G; Martinez, D; Park, H-S; Remington, B A; Robey, H F; Greenough, J A; Wallace, R; Di Stefano, C A; Drake, R P; Marion, D; Krauland, C M; Kuranz, C C

    2012-10-12

    Following the successful demonstration of an OMEGA laser-driven platform for generating and studying nearly two-dimensional unstable plasma shear layers [Hurricane et al., Phys. Plasmas 16, 056305 (2009); Harding et al., Phys. Rev. Lett. 103, 045005 (2009)], this Letter reports on the first quantitative measurement of turbulent mixing in a high-energy-density plasma. As a blast wave moves parallel to an unperturbed interface between a low-density foam and a high-density plastic, baroclinic vorticity is deposited at the interface and a Kelvin-Helmholtz instability-driven turbulent mixing layer is created in the postshock flow due to surface roughness. The spatial scale and density profile of the turbulent layer are diagnosed using x-ray radiography with sufficiently small uncertainty so that the data can be used to ~0.17 μm) in the postshock plasma flow are consistent with an "inertial subrange," within which a Kolmogorov turbulent energy cascade can be active. An illustration of comparing the data set with the predictions of a two-equation turbulence model in the ares radiation hydrodynamics code is also presented.

  15. High resolution 17 keV to 75 keV backlighters for High Energy Density experiments

    SciTech Connect

    Park, H; Maddox, B R; Giraldez, E; Hatchett, S P; Hudson, L; Izumi, N; Key, M H; Pape, S L; MacKinnon, A J; MacPhee, A G; Patel, P K; Phillips, T W; Remington, B A; Seely, J F; Tommasini, R; Town, R; Workman, J

    2008-02-25

    We have developed 17 keV to 75 keV 1-dimensional and 2-dimensional high-resolution (< 10 {micro}m) radiography using high-intensity short pulse lasers. High energy K-{alpha} sources are created by fluorescence from hot electrons interacting in the target material after irradiation by lasers with intensity I{sub L} > 10{sup 17} W/cm{sup 2}. We have achieved high resolution point projection 1-dimensional and 2-dimensional radiography using micro-foil and micro-wire targets attached to low-Z substrate materials. The micro-wire size was 10 {micro}m x 10 {micro}m x 300 {micro}m on a 300 {micro}m x 300 {micro}m x 5 {micro}m CH substrate. The radiography performance was demonstrated using the Titan laser at LLNL. We observed that the resolution is dominated by the micro-wire target size and there is very little degradation from the plasma plume, implying that the high energy x-ray photons are generated mostly within the micro-wire volume. We also observe that there are enough K{alpha} photons created with a 300 J, 1-{omega}, 40 ps pulse laser from these small volume targets, and that the signal-to-noise ratio is sufficiently high, for single shot radiography experiments. This unique technique will be used on future high energy density (HED) experiments at the new Omega-EP, ZR and NIF facilities.

  16. A quantum chemistry study on thermochemical properties of high energy-density endothermic hydrocarbon fuel JP-10.

    PubMed

    Qin, Xiao-Mei; Xie, Hu-Jun; Yue, Lei; Lu, Xiao-Xing; Fang, Wen-Jun

    2014-04-01

    The density functional theory (DFT) calculations at the M06-2X/6-31++G(d,p) level have been performed to explore the molecular structure, electronic structure, C-H bond dissociation enthalpy, and reaction enthalpies for five isodesmic reactions of a high energy-density endothermic hydrocarbon fuel JP-10. On the basis of the calculations, it is found that the carbonium ion C-6 isomer formed from the catalytic cracking at the C₆ site of JP-10 has the lowest energy, and the R-5 radical generated from the thermal cracking at the C₅ site of JP-10 is the most stable isomer. Furthermore, a series of hypothetical and isodesmic work reactions containing similar bond environments are used to calculate the reaction enthalpies for target compounds. For the same isodesmic reaction, the reaction enthalpy of each carbon site radical has also been calculated. The present work is of fundamental significance and strategic importance to provide some valuable insights into the component design and energy utilization of advanced endothermic fuels.

  17. Molecular design of 1,2,4,5-tetrazine-based high-energy density materials.

    PubMed

    Wei, Tao; Zhu, Weihua; Zhang, Xiaowen; Li, Yu-Fang; Xiao, Heming

    2009-08-20

    The heats of formation (HOFs) for a series of 1,2,4,5-tetrazine derivatives were calculated by using density functional theory (DFT), Hartree Fork (HF), and Møller-Plesset (MP2) as well as semiempirical methods. The effects of different basis bets on HOFs were also considered. Our results show that the -CN or -N3 group plays a very important role in increasing the HOF values of the 1,2,4,5-tetrazine derivatives. An analysis of the bond dissociation energies for the weakest bonds indicates that substitutions of the -N3, -NH2, -CN, -OH, or -Cl group are favorable for enhancing the thermal stability of 1,2,4,5-tetrazine, but the -NHNH2, -NHNO2, -NO2, -NF2, or -COOH group produces opposite effects. The calculated detonation velocities and pressures indicate that the -NF2 or -NO2 group is very helpful for enhancing the detonation performance for the derivatives, but the case is quite the contrary for the -CN, -NH2, or -OH group. Considered the detonation performance and thermal stability, three derivatives may be regarded as potential candidates of high-energy density materials (HEDMs).

  18. First-Principles Studies of Octacyclopropylcubane: A Novel High-Energy Density Material

    NASA Astrophysics Data System (ADS)

    Richardson, Steven L.; Allen, Reeshemah N.; Finkenstadt, Daniel; Mehl, Michael J.; Pederson, Mark R.

    2009-03-01

    The ongoing quest for synthesizing novel high-energy density materials (HEDMs) is clearly motivated by a search for new propellants and explosives. Recently de Meijere et al. have synthesized a new HEDM, octacyclopropylcubane (C32H40), in which the eight hydrogen atoms of cubane were replaced by cyclopropyl groups. In this work we report the results of a first-principles density-functional theory (DFT) calculation using the suite of codes known as NRLMOL (Naval Research Laboratory Molecular Orbital Library) to compute the structural, electronic, and vibrational properties of octacyclopropylcubane. We have calculated the vibrational properties of C32H40 and compare our results with experiment. We have also employed a DFT-based tight-binding scheme to compute the vibrational density of states for octacyclopropylcubane and compare our results with our full DFT-based results. Interesting enough, the geometry of the cyclopropyl groups in C32H40 does not allow for the quartic- concerted torsional mode (QCTM) that we and other workers have previously studied in octanitrocubane.

  19. First-principles investigation of high energy density in PVDF copolymers

    NASA Astrophysics Data System (ADS)

    Ranjan, V.; Lu, Liping; Buongiorno Nardelli, M.; Bernholc, J.

    2008-03-01

    PVDF and its copolymers exhibit excellent electromechanical properties and in the case of PVDF-CTFE also a very high energy density [1]. We have investigated the phase diagram of these systems and can quantitatively explain the observed energy density of PVDF-CTFE as due to a para to ferroelectric phase transition in a disordered, multidomain structure [2]. Our results show that pure PVDF prefers the α phase at zero field. Electric field lowers the free energy of the β phase, resulting in a structural phase transition at a sufficiently high field. Copolymer admixture lowers the critical field and eventually leads to an energetic preference for the β phase even at zero field. For PVDF-CTFE with CTFE content below 17 %, the α phase is still preferred and the field-induced phase transformation reversibly stores large amounts of energy. For PVDF-TeFE, the total energy difference between the two phases is much smaller, resulting in substantially smaller energy density. [1] B. Chu et al., Science 313, 334 (2006). [2] V. Ranjan et al., PRL 99, 047801 (2007).

  20. Demonstration of repeatability in a high-energy-density planar shear mixing layer experiment

    DOE PAGES

    Merritt, Elizabeth Catherine; Doss, Forrest William; Di Stefano, Carlos A.; ...

    2017-03-11

    On laser-driven platforms the assumption of experiment repeatability is particularly important due to a typically low data acquisition rate that doesn’t often allow for data redundancy. If the platform is repeatable, then measurements of the repeatable dynamics from multiple experiments can be treated as measurements of the same system. In high-energy-density hydrodynamic instability experiments the interface growth is assumed to be one of the repeatable aspects of the system. In this paper we demonstrate the repeatability of the instability growth in the counter-propagating shear experiment at the OMEGA laser facility, where the instability growth is characterized by the tracer layermore » thickness or mix-width evolution. Furthermore, in our previous experiment campaigns we have assumed the instability growth was repeatable enough to identify trends, but in this work we explicitly show that the mix-width measurements for nominally identical experiments are repeatable within the measurement error bars.« less

  1. Sparingly solvating electrolytes for high energy density Lithium–sulfur batteries

    DOE PAGES

    Cheng, Lei; Curtiss, Larry A.; Zavadil, Kevin R.; ...

    2016-07-11

    Moving to lighter and less expensive battery chemistries compared to lithium-ion requires the control of energy storage mechanisms based on chemical transformations rather than intercalation. Lithium sulfur (Li/S) has tremendous theoretical specific energy, but contemporary approaches to control this solution-mediated, precipitation-dissolution chemistry requires using large excesses of electrolyte to fully solubilize the polysulfide intermediate. Achieving reversible electrochemistry under lean electrolyte operation is the only path for Li/S to move beyond niche applications to potentially transformational performance. An emerging topic for Li/S research is the use of sparingly solvating electrolytes and the creation of design rules for discovering new electrolyte systemsmore » that fundamentally decouple electrolyte volume from reaction mechanism. Furthermore, this perspective presents an outlook for sparingly solvating electrolytes as the key path forward for longer-lived, high-energy density Li/S batteries including an overview of this promising new concept and some strategies for accomplishing it.« less

  2. Pulse Power Capability Of High Energy Density Capacitors Based on a New Dielectric Material

    NASA Technical Reports Server (NTRS)

    Winsor, Paul; Scholz, Tim; Hudis, Martin; Slenes, Kirk M.

    1999-01-01

    A new dielectric composite consisting of a polymer coated onto a high-density metallized Kraft has been developed for application in high energy density pulse power capacitors. The polymer coating is custom formulated for high dielectric constant and strength with minimum dielectric losses. The composite can be wound and processed using conventional wound film capacitor manufacturing equipment. This new system has the potential to achieve 2 to 3 J/cu cm whole capacitor energy density at voltage levels above 3.0 kV, and can maintain its mechanical properties to temperatures above 150 C. The technical and manufacturing development of the composite material and fabrication into capacitors are summarized in this paper. Energy discharge testing, including capacitance and charge-discharge efficiency at normal and elevated temperatures, as well as DC life testing were performed on capacitors manufactured using this material. TPL (Albuquerque, NM) has developed the material and Aerovox (New Bedford, MA) has used the material to build and test actual capacitors. The results of the testing will focus on pulse power applications specifically those found in electro-magnetic armor and guns, high power microwave sources and defibrillators.

  3. Fiber optic timing, firing and control system for high energy density physics experiments at Pegasus II

    SciTech Connect

    Hall, C.R.; Rohlev, L.; Earley, L.; Cochrane, J.

    1995-12-01

    Several fiber optic systems have been designed and implemented for the high energy density experiments at Pegasus II. The main fiber optic system developed for Pegasus II, remotely controls both the charging and discharging of the capacitor discharge unit (CDU). This fiber optic system is also used to distribute the timing and firing information specific to each experiment to the operators and experimenters. The timing and firing information includes the voltage on the CDU as it is being charged, a confirmation signal indicating the CDU has discharged and common timing signals based on the output signals on the load ring of the CDU. Various fiber optic systems were implemented to transfer diagnostic information related to the discharge of the main capacitor bank to the control room. The diagnostics include the current, electric field, and vacuum pressure at the target area. Not only do these fiber optic systems provide the control and monitor signals for the experiments at Pegasus II, they have the added value of preventing premature firing of the capacitor bank, eliminating ground loops between the test area and the control room and providing overall increased operator safety.

  4. High-Energy-Density, Laboratory-Astrophysics Studies of Jets and Bow Shocks

    SciTech Connect

    Foster, J M; Wilde, B H; Rosen, P A; Perry, T S; Khokhlov, A M; Coker, R F; Frank, A; Keiter, P A; Blue, B E; Drake, R P; Knauer, J P; Williams, R R

    2005-01-24

    Large-scale directional outflows of supersonic plasma, also known as ''jets'', are ubiquitous phenomena in astrophysics [1]. The interaction of such jets with surrounding matter often results in spectacular bow shocks, and intense radiation from radio to gamma-ray wavelengths. The traditional approach to understanding such phenomena is through theoretical analysis and numerical simulations. However, such numerical simulations have limited resolution, often assume axial symmetry, do not include all relevant physical processes, and fail to scale correctly in Reynolds number and perhaps other key dimensionless parameters. Additionally, they are frequently not tested by comparison with laboratory experiments. Recent advances in high-energy-density physics using large inertial-confinement-fusion devices now allow controlled laboratory experiments on macroscopic volumes of plasma of direct relevance relevant to astrophysics [2]. In this Letter we report the first results of experiments designed to study the evolution of supersonic plasma jets and the bow shocks they drive into a surrounding medium. Our experiments reveal both regular and highly complex flow patterns in the bow shock, thus opening a new window--complementary to computer simulations--into understanding the nature of three-dimensional astrophysical jets.

  5. Additions and improvements to the high energy density physics capabilities in the FLASH code

    NASA Astrophysics Data System (ADS)

    Lamb, D. Q.; Flocke, N.; Graziani, C.; Tzeferacos, P.; Weide, K.

    2016-10-01

    FLASH is an open source, finite-volume Eulerian, spatially adaptive radiation magnetohydrodynamics code that has the capabilities to treat a broad range of physical processes. FLASH performs well on a wide range of computer architectures, and has a broad user base. Extensive high energy density physics (HEDP) capabilities have been added to FLASH to make it an open toolset for the academic HEDP community. We summarize these capabilities, emphasizing recent additions and improvements. In particular, we showcase the ability of FLASH to simulate the Faraday Rotation Measure produced by the presence of magnetic fields; and proton radiography, proton self-emission, and Thomson scattering diagnostics with and without the presence of magnetic fields. We also describe several collaborations with the academic HEDP community in which FLASH simulations were used to design and interpret HEDP experiments. This work was supported in part at the University of Chicago by the DOE NNSA ASC through the Argonne Institute for Computing in Science under field work proposal 57789; and the NSF under Grant PHY-0903997.

  6. Additions and Improvements to the FLASH Code for Simulating High Energy Density Physics Experiments

    NASA Astrophysics Data System (ADS)

    Lamb, D. Q.; Daley, C.; Dubey, A.; Fatenejad, M.; Flocke, N.; Graziani, C.; Lee, D.; Tzeferacos, P.; Weide, K.

    2015-11-01

    FLASH is an open source, finite-volume Eulerian, spatially adaptive radiation hydrodynamics and magnetohydrodynamics code that incorporates capabilities for a broad range of physical processes, performs well on a wide range of computer architectures, and has a broad user base. Extensive capabilities have been added to FLASH to make it an open toolset for the academic high energy density physics (HEDP) community. We summarize these capabilities, with particular emphasis on recent additions and improvements. These include advancements in the optical ray tracing laser package, with methods such as bi-cubic 2D and tri-cubic 3D interpolation of electron number density, adaptive stepping and 2nd-, 3rd-, and 4th-order Runge-Kutta integration methods. Moreover, we showcase the simulated magnetic field diagnostic capabilities of the code, including induction coils, Faraday rotation, and proton radiography. We also describe several collaborations with the National Laboratories and the academic community in which FLASH has been used to simulate HEDP experiments. This work was supported in part at the University of Chicago by the DOE NNSA ASC through the Argonne Institute for Computing in Science under field work proposal 57789; and the NSF under grant PHY-0903997.

  7. High energy density strategies: from hydride-forming materials research to battery integration

    NASA Astrophysics Data System (ADS)

    Notten, P. H. L.; Ouwerkerk, M.; van Hal, H.; Beelen, D.; Keur, W.; Zhou, J.; Feil, H.

    Two different strategies are outlined to develop both high energy density and space-efficient batteries, including the most widely applied rechargeable nickel-metal hydride (NiMH) and Li-ion batteries. The hydrogen storage capacity of fluorite-structured Mg-containing compounds are shown to have a reversible electrochemical storage capacity of more than four times that of the commonly used MischMetal-based AB 5 compounds in NiMH, i.e. 1500 mAh/g (5.6 wt.%). The formation of octahedral sites within the crystal lattice is argued to be very crucial for the improved kinetics of hydrogen absorption and desorption. It is shown that the fluorite-structure can be conserved with both precious Sc and the less expensive Ti up to a Mg content of 80 at.%. Both thermodynamic and kinetic data are presented in relation to the materials composition. In addition, the development of preshaped batteries, as the first step to battery integration, has contributed to a much higher level of design freedom for portable electronic equipment. The manufacturing process of preshaped batteries will be described together with their electrochemical characteristics. Advantageously, the mechanical stability is provided locally by polymer rivets, allowing to get rid of heavy metallic casings and to make use of a much wider range of battery shapes.

  8. Observation of finite-wavelength screening in high-energy-density matter

    PubMed Central

    Chapman, D. A.; Vorberger, J.; Fletcher, L. B.; Baggott, R. A.; Divol, L.; Döppner, T.; Falcone, R. W.; Glenzer, S. H.; Gregori, G.; Guymer, T. M.; Kritcher, A. L.; Landen, O. L.; Ma, T.; Pak, A. E.; Gericke, D. O.

    2015-01-01

    A key component for the description of charged particle systems is the screening of the Coulomb interaction between charge carriers. First investigated in the 1920s by Debye and Hückel for electrolytes, charge screening is important for determining the structural and transport properties of matter as diverse as astrophysical and laboratory plasmas, nuclear matter such as quark-gluon plasmas, electrons in solids, planetary cores and charged macromolecules. For systems with negligible dynamics, screening is still mostly described using a Debye–Hückel-type approach. Here, we report the novel observation of a significant departure from the Debye–Hückel-type model in high-energy-density matter by probing laser-driven, shock-compressed plastic with high-energy X-rays. We use spectrally resolved X-ray scattering in a geometry that enables direct investigation of the screening cloud, and demonstrate that the observed elastic scattering amplitude is only well described within a more general approach. PMID:25904218

  9. Molecularly Engineered Azobenzene Derivatives for High Energy Density Solid-State Solar Thermal Fuels.

    PubMed

    Cho, Eugene N; Zhitomirsky, David; Han, Grace G D; Liu, Yun; Grossman, Jeffrey C

    2017-03-15

    Solar thermal fuels (STFs) harvest and store solar energy in a closed cycle system through conformational change of molecules and can release the energy in the form of heat on demand. With the aim of developing tunable and optimized STFs for solid-state applications, we designed three azobenzene derivatives functionalized with bulky aromatic groups (phenyl, biphenyl, and tert-butyl phenyl groups). In contrast to pristine azobenzene, which crystallizes and makes nonuniform films, the bulky azobenzene derivatives formed uniform amorphous films that can be charged and discharged with light and heat for many cycles. Thermal stability of the films, a critical metric for thermally triggerable STFs, was greatly increased by the bulky functionalization (up to 180 °C), and we were able to achieve record high energy density of 135 J/g for solid-state STFs, over a 30% improvement compared to previous solid-state reports. Furthermore, the chargeability in the solid state was improved, up to 80% charged from 40% charged in previous solid-state reports. Our results point toward molecular engineering as an effective method to increase energy storage in STFs, improve chargeability, and improve the thermal stability of the thin film.

  10. Probing matter at the extremes: new frontiers in high energy density physics

    NASA Astrophysics Data System (ADS)

    Remington, Bruce A.

    2008-04-01

    The ability to experimentally study scaled aspects of the explosion dynamics of core- collapse supernovae (massive stars that explode from the inside out) or the radiation kinetics of accreting neutron stars or black holes on high energy density (HED) facilities, such as high power lasers and magnetic pinch facilities, is an exciting scientific development over the last two decades. [2] Additional areas of research that become accessible on modern HED facilities are studies of fundamental properties of matter in conditions relevant to planetary and stellar interiors, protostellar jet dynamics, and with ultraintense short-pulse lasers, strong field effects, possibly relevant to gamma-ray burst dynamics. With the added tool of thermonuclear ignition on the National Ignition Facility, excited state (``multi-hit'') nuclear physics studies, possibly relevant to nucleosynthesis, may also become possible. Techniques and methodologies for studying aspects of the physics of such extreme phenomena of the universe in submillimeter scale parcels of matter in the laboratory will be discussed. [2] ``Experimental astrophysics with high power lasers and Z pinches,'' B.A. Remington, R.P. Drake, D.D. Ryutov, Rev. Mod. Phys. 78, 755 (2006).

  11. Collaborative comparison of high-energy-density physics codes (LA-UR-12-22121)

    NASA Astrophysics Data System (ADS)

    Fryxell, Bruce; Fatenejad, Milad; Wohlbier, John; Myra, Eric; Lamb, Don; Fryer, Chris; Graziani, Carlos; Medin, Zach; Rauenzahn, Rick

    2012-10-01

    Radiation-hydrodynamic simulations are vital to understanding high-energy-density physics (HEDP) experiments. We are in the process of comparing three HEDP codes, including CRASH (U. of Michigan), FLASH (U. of Chicago), and xRAGE (LANL) on a wide variety of problems, ranging from simple tests to full HEDP experiments. The goals are to understand the differences between the codes and how they influence the results, to determine which codes contain the most accurate algorithms and physics models, and where possible, to improve the other codes to produce more faithful representations of HEDP experiments. The calculations discussed here include simple temperature relaxation problems in an infinite, uniform medium, tests of the diffusion solvers (both conduction and radiation), and tests that add hydrodynamic effects, The eventual goal is to compare the results from all of the codes on simulations of radiative shock experiments being performed by The Center for Radiative Shock Hydrodynamics (CRASH) at the University of Michigan and to understand any discrepancies between the results of the simulations and the experiments.

  12. Development of a Big Area BackLighter for high energy density experiments.

    PubMed

    Flippo, K A; Kline, J L; Doss, F W; Loomis, E N; Emerich, M; Devolder, B; Murphy, T J; Fournier, K B; Kalantar, D H; Regan, S P; Barrios, M A; Merritt, E C; Perry, T S; Tregillis, I L; Welser-Sherrill, L; Fincke, J R

    2014-09-01

    A very large area (7.5 mm(2)) laser-driven x-ray backlighter, termed the Big Area BackLighter (BABL) has been developed for the National Ignition Facility (NIF) to support high energy density experiments. The BABL provides an alternative to Pinhole-Apertured point-projection Backlighting (PABL) for a large field of view. This bypasses the challenges for PABL in the equatorial plane of the NIF target chamber where space is limited because of the unconverted laser light that threatens the diagnostic aperture, the backlighter foil, and the pinhole substrate. A transmission experiment using 132 kJ of NIF laser energy at a maximum intensity of 8.52 × 10(14) W/cm(2) illuminating the BABL demonstrated good conversion efficiency of >3.5% into K-shell emission producing ~4.6 kJ of high energy x rays, while yielding high contrast images with a highly uniform background that agree well with 2D simulated spectra and spatial profiles.

  13. Development of optics for x-ray phase-contrast imaging of high energy density plasmas

    SciTech Connect

    Stutman, D.; Finkenthal, M.; Moldovan, N.

    2010-10-15

    Phase-contrast or refraction-enhanced x-ray radiography can be useful for the diagnostic of low-Z high energy density plasmas, such as imploding inertial confinement fusion (ICF) pellets, due to its sensitivity to density gradients. To separate and quantify the absorption and refraction contributions to x-ray images, methods based on microperiodic optics, such as shearing interferometry, can be used. To enable applying such methods with the energetic x rays needed for ICF radiography, we investigate a new type of optics consisting of grazing incidence microperiodic mirrors. Using such mirrors, efficient phase-contrast imaging systems could be built for energies up to {approx}100 keV. In addition, a simple lithographic method is proposed for the production of the microperiodic x-ray mirrors based on the difference in the total reflection between a low-Z substrate and a high-Z film. Prototype mirrors fabricated with this method show promising characteristics in laboratory tests.

  14. A journey from nuclear criticality methods to high energy density radflow experiments

    SciTech Connect

    Urbatsch, Todd James

    2016-11-08

    Los Alamos National Laboratory is a nuclear weapons laboratory supporting our nation's defense. In support of this mission is a high energy-density physics program in which we design and execute experiments to study radiationhydrodynamics phenomena and improve the predictive capability of our largescale multi-physics software codes on our big-iron computers. The Radflow project’s main experimental effort now is to understand why we haven't been able to predict opacities on Sandia National Laboratory's Z-machine. We are modeling an increasing fraction of the Z-machine's dynamic hohlraum to find multi-physics explanations for the experimental results. Further, we are building an entirely different opacity platform on Lawrence Livermore National Laboratory's National Ignition Facility (NIF), which is set to get results early 2017. Will the results match our predictions, match the Z-machine, or give us something entirely different? The new platform brings new challenges such as designing hohlraums and spectrometers. The speaker will recount his history, starting with one-dimensional Monte Carlo nuclear criticality methods in graduate school, radiative transfer methods research and software development for his first 16 years at LANL, and, now, radflow technology and experiments. Who knew that the real world was more than just radiation transport? Experiments aren't easy and they are as saturated with politics as a presidential election, but they sure are fun.

  15. High energy density laser interactions with planetary and astrophysical materials: methodology and data

    NASA Astrophysics Data System (ADS)

    Remo, John L.; Adams, Richard G.

    2008-05-01

    Sandia National Laboratories NLS (1064 nm) and Z-Beamlet (527 nm) pulsed lasers @ ~ 100 GW/cm2 and 10 TW/cm2 were used to attain pressures at 20 - 525 GPa on a variety of metallic and mineral targets. A simple, inexpensive and innovative electro-optical real-time methodology monitored rear surface mechanical deformation and associated particle and shock wave velocities that differ considerably between metals and non-metals. A reference calibration metal (Aluminum) and a reference non-metal (graphite) were used to demonstrate the validity of this methodology. Normative equations of state and momentum coupling coefficients were obtained for dunite, carbonaceous meteorites, graphite, iron and nickel. These experimental results on inhomogeneous materials can be applied to a variety of high energy density interactions involving stellar and planetary material formation, dynamic interactions, geophysical models, space propulsion systems, orbital debris, materials processing, near-earth space (lunar and asteroid) resource recovery, and near-earth object mitigation models.

  16. Energetic multifunctionalized nitraminopyrazoles and their ionic derivatives: ternary hydrogen-bond induced high energy density materials.

    PubMed

    Yin, Ping; Parrish, Damon A; Shreeve, Jean'ne M

    2015-04-15

    Diverse functionalization was introduced into the pyrazole framework giving rise to a new family of ternary hydrogen-bond induced high energy density materials. By incorporating extended cationic interactions, nitramine-based ionic derivatives exhibit good energetic performance and enhanced molecular stability. Performance parameters including heats of formation and detonation properties were calculated by using Gaussian 03 and EXPLO5 v6.01 programs, respectively. It is noteworthy to find that 5-nitramino-3,4-dinitropyrazole, 4, has a remarkable measured density of 1.97 g cm(-3) at 298 K, which is consistent with its crystal density (2.032 g cm(-3), 150 K), and ranks highest among azole-based CHNO compounds. Energetic evaluation indicates that, in addition to the molecular compound 4, some ionic derivatives, 9, 11, 12, 17, 19, and 22, also have high densities (1.83-1.97 g cm(-3)), excellent detonation pressures and velocities (P, 35.6-41.6 GPa; vD, 8880-9430 m s(-1)), as well as acceptable impact and friction sensitivities (IS, 4-30 J; FS, 40-240 N). These attractive features highlight the application potential of nitramino hydrogen-bonded interactions in the design of advanced energetic materials.

  17. Observation of finite-wavelength screening in high-energy-density matter

    NASA Astrophysics Data System (ADS)

    Chapman, D. A.; Vorberger, J.; Fletcher, L. B.; Baggott, R. A.; Divol, L.; Döppner, T.; Falcone, R. W.; Glenzer, S. H.; Gregori, G.; Guymer, T. M.; Kritcher, A. L.; Landen, O. L.; Ma, T.; Pak, A. E.; Gericke, D. O.

    2015-04-01

    A key component for the description of charged particle systems is the screening of the Coulomb interaction between charge carriers. First investigated in the 1920s by Debye and Hückel for electrolytes, charge screening is important for determining the structural and transport properties of matter as diverse as astrophysical and laboratory plasmas, nuclear matter such as quark-gluon plasmas, electrons in solids, planetary cores and charged macromolecules. For systems with negligible dynamics, screening is still mostly described using a Debye-Hückel-type approach. Here, we report the novel observation of a significant departure from the Debye-Hückel-type model in high-energy-density matter by probing laser-driven, shock-compressed plastic with high-energy X-rays. We use spectrally resolved X-ray scattering in a geometry that enables direct investigation of the screening cloud, and demonstrate that the observed elastic scattering amplitude is only well described within a more general approach.

  18. α MnMoO₄/graphene hybrid composite: high energy density supercapacitor electrode material.

    PubMed

    Ghosh, Debasis; Giri, Soumen; Moniruzzaman, Md; Basu, Tanya; Mandal, Manas; Das, Chapal Kumar

    2014-07-28

    A unique and cost effective hydrothermal procedure has been carried out for the synthesis of hexahedron shaped α MnMoO4 and its hybrid composite with graphene using three different weight percentages of graphene. Characterization techniques, such as XRD, Raman and FTIR analysis, established the phase and formation of the composite. The electrochemical characterization of the pseudocapacitive MnMoO4 and the MnMoO4/graphene composites in 1 M Na2SO4 displayed highest specific capacitances of 234 F g(-1) and 364 F g(-1), respectively at a current density of 2 A g(-1). Unlike many other pseudocapacitive electrode materials our prepared materials responded in a wide range of working potentials of (-)1 V to (+)1 V, which indeed resulted in a high energy density without substantial loss of power density. The highest energy densities of 130 Wh kg(-1) and 202.2 Wh kg(-1) were achieved, respectively for the MnMoO4 and the MnMoO4/graphene composite at a constant power delivery rate of 2000 W kg(-1). The synergistic effect of the graphene with the pseudocapacitive MnMoO4 caused an increased cycle stability of 88% specific capacitance retention after 1000 consecutive charge discharge cycles at 8 A g(-1) constant current density, which was higher than the virgin MnMoO4 with 84% specific capacitance retention.

  19. Extended CO Solid: A New Class of High Energy Density Material

    SciTech Connect

    Lipp, M J; Evans, W J; Baer, B J; Yoo, C

    2004-10-14

    Covalently bonded extended phases of molecular solids made of first- and second-row elements at high pressures are a new class of materials with advanced optical, mechanical and energetic properties. The existence of such extended solids has recently been demonstrated using diamond anvil cells in several systems, including N{sub 2}, CO{sub 2},and CO. However, the microscopic quantities produced at the formidable high-pressure/temperature conditions have limited the characterization of their predicted novel properties including high-energy content. In this paper, we present the first experimental evidence that these extended low-Z solids are indeed high energy density materials via milligram-scale high-pressure synthesis, recovery and characterization of polymeric CO (p-CO). Our spectroscopic data reveal that p-CO is a random polymer made of lactonic entities and conjugated C=C with an energy content rivaling or exceeding that of HMX. Solid p-CO explosively decomposes to CO{sub 2} and glassy carbon and thus might be used as an advanced energetic material.

  20. Talbot-Lau x-ray interferometry for high energy density plasma diagnostic

    SciTech Connect

    Stutman, D.; Finkenthal, M.

    2011-11-15

    High resolution density diagnostics are difficult in high energy density laboratory plasmas (HEDLP) experiments due to the scarcity of probes that can penetrate above solid density plasmas. Hard x-rays are one possible probe for such dense plasmas. We study the possibility of applying an x-ray method recently developed for medical imaging, differential phase-contrast with Talbot-Lau interferometers, for the diagnostic of electron density and small-scale hydrodynamic instabilities in HEDLP experiments. The Talbot method uses micro-periodic gratings to measure the refraction and ultra-small angle scatter of x-rays through an object and is attractive for HEDLP diagnostic due to its capability to work with incoherent and polychromatic x-ray sources such as the laser driven backlighters used for HEDLP radiography. Our paper studies the potential of the Talbot method for HEDLP diagnostic, its adaptation to the HEDLP environment, and its extension of high x-ray energy using micro-periodic mirrors. The analysis is illustrated with experimental results obtained using a laboratory Talbot interferometer.

  1. Talbot-Lau x-ray interferometry for high energy density plasma diagnostic.

    PubMed

    Stutman, D; Finkenthal, M

    2011-11-01

    High resolution density diagnostics are difficult in high energy density laboratory plasmas (HEDLP) experiments due to the scarcity of probes that can penetrate above solid density plasmas. Hard x-rays are one possible probe for such dense plasmas. We study the possibility of applying an x-ray method recently developed for medical imaging, differential phase-contrast with Talbot-Lau interferometers, for the diagnostic of electron density and small-scale hydrodynamic instabilities in HEDLP experiments. The Talbot method uses micro-periodic gratings to measure the refraction and ultra-small angle scatter of x-rays through an object and is attractive for HEDLP diagnostic due to its capability to work with incoherent and polychromatic x-ray sources such as the laser driven backlighters used for HEDLP radiography. Our paper studies the potential of the Talbot method for HEDLP diagnostic, its adaptation to the HEDLP environment, and its extension of high x-ray energy using micro-periodic mirrors. The analysis is illustrated with experimental results obtained using a laboratory Talbot interferometer. © 2011 American Institute of Physics

  2. Thulium heat source for high-endurance and high-energy density power systems

    NASA Astrophysics Data System (ADS)

    Walter, C. E.; Kammeraad, J. E.; Vankonynenburg, R.; Vansant, J. H.

    1991-05-01

    We are studying the performance characteristics of radioisotope heat source designs for high-endurance and high-energy-density power systems that use thulium-170. Heat sources in the power range of 5 to 50 kW(sub th) coupled with a power conversion efficiency of approximately 30 percent, can easily satisfy current missions for autonomous underwater vehicles. New naval missions will be possible because thulium isotope power systems have a factor of one-to-two hundred higher endurance and energy density than chemical and electrochemical systems. Thulium-170 also has several other attractive features, including the fact that it decays to stable ytterbium-170 with a half-life of four months. For terrestrial applications, refueling on that time scale should be acceptable in view of the advantage of its benign decay. The heat source designs we are studying account for the requirements of isotope production, shielding, and integration with power conversion components. These requirements are driven by environmental and safety considerations. Thulium is present in the form of thin refractory thulia disks that allow power conversion at high peak temperature. We give estimates of power system state points, performance, mass, and volume characteristics. Monte Carlo radiation analysis provides a detailed assessment of shield requirements and heat transfer under normal and distressed conditions is also considered.

  3. Inertial Fusion and High-Energy-Density Science in the United States

    SciTech Connect

    Tarter, C B

    2001-09-06

    Inertial fusion and high-energy density science worldwide is poised to take a great leap forward. In the US, programs at the University of Rochester, Sandia National Laboratories, Los Alamos National Laboratory, Lawrence Livermore National Laboratory (LLNL), the Naval Research Laboratory, and many smaller laboratories have laid the groundwork for building a facility in which fusion ignition can be studied in the laboratory for the first time. The National Ignition Facility (NIF) is being built by the Department of Energy's National Nuclear Security Agency to provide an experimental test bed for the US Stockpile Stewardship Program (SSP) to ensure the dependability of the country's nuclear deterrent without underground nuclear testing. NIF and other large laser systems being planned such as the Laser MegaJoule (LMJ) in France will also make important contributions to basic science, the development of inertial fusion energy, and other scientific and technological endeavors. NIF will be able to produce extreme temperatures and pressures in matter. This will allow simulating astrophysical phenomena (on a tiny scale) and measuring the equation of state of material under conditions that exist in planetary cores.

  4. Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics

    PubMed Central

    Kou, Liang; Huang, Tieqi; Zheng, Bingna; Han, Yi; Zhao, Xiaoli; Gopalsamy, Karthikeyan; Sun, Haiyan; Gao, Chao

    2014-01-01

    Yarn supercapacitors have great potential in future portable and wearable electronics because of their tiny volume, flexibility and weavability. However, low-energy density limits their development in the area of wearable high-energy density devices. How to enhance their energy densities while retaining their high-power densities is a critical challenge for yarn supercapacitor development. Here we propose a coaxial wet-spinning assembly approach to continuously spin polyelectrolyte-wrapped graphene/carbon nanotube core-sheath fibres, which are used directly as safe electrodes to assembly two-ply yarn supercapacitors. The yarn supercapacitors using liquid and solid electrolytes show ultra-high capacitances of 269 and 177 mF cm−2 and energy densities of 5.91 and 3.84 μWh cm−2, respectively. A cloth supercapacitor superior to commercial capacitor is further interwoven from two individual 40-cm-long coaxial fibres. The combination of scalable coaxial wet-spinning technology and excellent performance of yarn supercapacitors paves the way to wearable and safe electronics. PMID:24786366

  5. Investigating the Effects of Anisotropic Mass Transport on Dendrite Growth in High Energy Density Lithium Batteries

    SciTech Connect

    Tan, Jinwang; Tartakovsky, Alexandre M.; Ferris, Kim F.; Ryan, Emily M.

    2016-01-01

    Dendrite formation on the electrode surface of high energy density lithium (Li) batteries causes safety problems and limits their applications. Suppressing dendrite growth could significantly improve Li battery performance. Dendrite growth and morphology is a function of the mixing in the electrolyte near the anode interface. Most research into dendrites in batteries focuses on dendrite formation in isotropic electrolytes (i.e., electrolytes with isotropic diffusion coefficient). In this work, an anisotropic diffusion reaction model is developed to study the anisotropic mixing effect on dendrite growth in Li batteries. The model uses a Lagrangian particle-based method to model dendrite growth in an anisotropic electrolyte solution. The model is verified by comparing the numerical simulation results with analytical solutions, and its accuracy is shown to be better than previous particle-based anisotropic diffusion models. Several parametric studies of dendrite growth in an anisotropic electrolyte are performed and the results demonstrate the effects of anisotropic transport on dendrite growth and morphology, and show the possible advantages of anisotropic electrolytes for dendrite suppression.

  6. Characterization of magnetic reconnection in the high-energy-density regime

    NASA Astrophysics Data System (ADS)

    Qiao, B.; Xu, Z.; Chang, H. X.; Wu, S. Z.; Zhou, C. T.; Wang, X. G.; He, X. T.

    2015-11-01

    Magnetic reconnection (MR), breaking and reorganizing the topology of magnetic field dramatically, is a fundamental process observed in many space, laboratory and astrophysical plasmas. In this talk, we report recent investigations on characterization of magnetic reconnection (MR) in the high-energy-density (HED) regime, where the plasma inflow is strongly driven and the total thermal pressure is larger than the magnetic pressure (β > 1) . This extreme regime of MR occurs frequently in astrophysics and recent HED experiments. Comparing the particle-in-cell simulation results for the interactions of colliding laser-produced plasma bubbles with induced anti-parallel and parallel poloidal magnetic fields respectively, the consequences caused by MR are distinguished from those by plasma bubble collisions and two-fluid effects. It is found that the out-of-plane quadrupole magnetic field, bipolar poloidal electric field, plasma heating and even the out-of-plane electric field appear in both cases, which cannot be recognized as evidences of MR here as previously thought. The Lorentz-invariant scalar quantity De =γe \\Jdot ⇀ . (E ⇀ + v ⇀ × B ⇀) [γe = (1 -ve2 /c2)- 1 / 2 is the Lorentz factor] in the electron dissipation region is proposed as the key sign of MR occurrence in the HED regime.

  7. Aluminum manganese oxides with mixed crystal structure: high-energy-density cathodes for rechargeable sodium batteries.

    PubMed

    Han, Dong-Wook; Ku, Jun-Hwan; Kim, Ryoung-Hee; Yun, Dong-Jin; Lee, Seok-Soo; Doo, Seok-Gwang

    2014-07-01

    We report a new discovery for enhancing the energy density of manganese oxide (Nax MnO2 ) cathode materials for sodium rechargeable batteries by incorporation of aluminum. The Al incorporation results in NaAl(0.1) Mn(0.9) O2 with a mixture of tunnel and layered crystal structures. NaAl(0.1) Mn(0.9) O2 shows a much higher initial discharge capacity and superior cycling performance compared to pristine Na(0.65) MnO2 . We ascribe this enhancement in performance to the formation of a new orthorhombic layered NaMnO2 phase merged with a small amount of tunnel Na(0.44) MnO2 phase in NaAl(0.1) Mn(0.9) O2 , and to improvements in the surface stability of the NaAl(0.1) Mn(0.9) O2 particles caused by the formation of Al-O bonds on their surfaces. Our findings regarding the phase transformation and structure stabilization induced by incorporation of aluminum, closely related to the structural analogy between orthorhombic Na(0.44) MnO2 and NaAl(0.1) Mn(0.9) O2 , suggest a strategy for achieving sodium rechargeable batteries with high energy density and stability.

  8. Observation of finite-wavelength screening in high-energy-density matter

    DOE PAGES

    Chapman, D. A.; Vorberger, J.; Fletcher, L. B.; ...

    2015-04-23

    A key component for the description of charged particle systems is the screening of the Coulomb interaction between charge carriers. First investigated in the 1920s by Debye and Hückel for electrolytes, charge screening is important for determining the structural and transport properties of matter as diverse as astrophysical and laboratory plasmas, nuclear matter such as quark-gluon plasmas, electrons in solids, planetary cores and charged macromolecules. For systems with negligible dynamics, screening is still mostly described using a Debye–Hückel-type approach. Here, we report the novel observation of a significant departure from the Debye–Hückel-type model in high-energy-density matter by probing laser-driven, shock-compressedmore » plastic with high-energy X-rays. We use spectrally resolved X-ray scattering in a geometry that enables direct investigation of the screening cloud, and demonstrate that the observed elastic scattering amplitude is only well described within a more general approach.« less

  9. Observation of finite-wavelength screening in high-energy-density matter

    SciTech Connect

    Chapman, D. A.; Vorberger, J.; Fletcher, L. B.; Baggott, R. A.; Divol, L.; Döppner, T.; Falcone, R. W.; Glenzer, S. H.; Gregori, G.; Guymer, T. M.; Kritcher, A. L.; Landen, O. L.; Ma, T.; Pak, A. E.; Gericke, D. O.

    2015-04-23

    A key component for the description of charged particle systems is the screening of the Coulomb interaction between charge carriers. First investigated in the 1920s by Debye and Hückel for electrolytes, charge screening is important for determining the structural and transport properties of matter as diverse as astrophysical and laboratory plasmas, nuclear matter such as quark-gluon plasmas, electrons in solids, planetary cores and charged macromolecules. For systems with negligible dynamics, screening is still mostly described using a Debye–Hückel-type approach. Here, we report the novel observation of a significant departure from the Debye–Hückel-type model in high-energy-density matter by probing laser-driven, shock-compressed plastic with high-energy X-rays. We use spectrally resolved X-ray scattering in a geometry that enables direct investigation of the screening cloud, and demonstrate that the observed elastic scattering amplitude is only well described within a more general approach.

  10. Novel Quaternary Chalcogenide/Reduced Graphene Oxide-Based Asymmetric Supercapacitor with High Energy Density.

    PubMed

    Sarkar, Samrat; Howli, Promita; Das, Biswajit; Das, Nirmalya Sankar; Samanta, Madhupriya; Das, G C; Chattopadhyay, K K

    2017-07-12

    In this work we have synthesized quaternary chalcogenide Cu2NiSnS4 (QC) nanoparticles grown in situ on 2D reduced graphene oxide (rGO) for application as anode material of solid-state asymmetric supercapacitors (ASCs). Thorough characterization of the synthesized composite validates the proper phase, stoichiometry, and morphology. Detailed electrochemical study of the electrode materials and ASCs has been performed. The as-fabricated device delivers an exceptionally high areal capacitance (655.1 mF cm(-2)), which is much superior to that of commercial micro-supercapacitors. Furthermore, a remarkable volumetric capacitance of 16.38 F cm(-3) is obtained at a current density of 5 mA cm(-2) combined with a very high energy density of 5.68 mW h cm(-3), which is comparable to that of commercially available lithium thin film batteries. The device retains 89.2% of the initial capacitance after running for 2000 cycles, suggesting its long-term capability. Consequently, the enhanced areal and volumetric capacitances combined with decent cycle stability and impressive energy density endow the uniquely decorated QC/rGO composite material as a promising candidate in the arena of energy storage devices. Moreover, Cu2NiSnS4 being a narrow band gap photovoltaic material, this work offers a novel protocol for the development of self-charging supercapacitors in the days to come.

  11. Advanced intermediate temperature sodium-nickel chloride batteries with ultra-high energy density

    NASA Astrophysics Data System (ADS)

    Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y.; Meinhardt, Kerry D.; Chang, Hee Jung; Canfield, Nathan L.; Sprenkle, Vincent L.

    2016-02-01

    Sodium-metal halide batteries have been considered as one of the more attractive technologies for stationary electrical energy storage, however, they are not used for broader applications despite their relatively well-known redox system. One of the roadblocks hindering market penetration is the high-operating temperature. Here we demonstrate that planar sodium-nickel chloride batteries can be operated at an intermediate temperature of 190 °C with ultra-high energy density. A specific energy density of 350 Wh kg-1, higher than that of conventional tubular sodium-nickel chloride batteries (280 °C), is obtained for planar sodium-nickel chloride batteries operated at 190 °C over a long-term cell test (1,000 cycles), and it attributed to the slower particle growth of the cathode materials at the lower operating temperature. Results reported here demonstrate that planar sodium-nickel chloride batteries operated at an intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs.

  12. Observation of finite-wavelength screening in high-energy-density matter.

    PubMed

    Chapman, D A; Vorberger, J; Fletcher, L B; Baggott, R A; Divol, L; Döppner, T; Falcone, R W; Glenzer, S H; Gregori, G; Guymer, T M; Kritcher, A L; Landen, O L; Ma, T; Pak, A E; Gericke, D O

    2015-04-23

    A key component for the description of charged particle systems is the screening of the Coulomb interaction between charge carriers. First investigated in the 1920s by Debye and Hückel for electrolytes, charge screening is important for determining the structural and transport properties of matter as diverse as astrophysical and laboratory plasmas, nuclear matter such as quark-gluon plasmas, electrons in solids, planetary cores and charged macromolecules. For systems with negligible dynamics, screening is still mostly described using a Debye-Hückel-type approach. Here, we report the novel observation of a significant departure from the Debye-Hückel-type model in high-energy-density matter by probing laser-driven, shock-compressed plastic with high-energy X-rays. We use spectrally resolved X-ray scattering in a geometry that enables direct investigation of the screening cloud, and demonstrate that the observed elastic scattering amplitude is only well described within a more general approach.

  13. A high energy density shock driven Kelvin-Helmholtz shear layer experiment

    SciTech Connect

    Hurricane, O. A.; Hansen, J. F.; Robey, H. F.; Remington, B. A.; Bono, M. J.; Harding, E. C.; Drake, R. P.; Kuranz, C. C.

    2009-05-15

    Radiographic data from a novel and highly successful high energy density Kelvin-Helmholtz (KH) instability experiment is presented along with synapses of the theory and simulation behind the target design. Data on instability growth are compared to predictions from simulation and theory. The key role played by baroclinic vorticity production in the functioning of the target and the key design parameters are also discussed. The data show the complete evolution of large distinct KH eddies, from formation to turbulent break-up. Unexpectedly, low density bubbles comparable to the vortex size are observed forming in the free-stream region above each vortex at late time. These bubbles have the appearance of localized shocks, possibly supporting a theoretical fluid dynamics conjecture about the existence of supersonic bubbles over the vortical structure [transonic convective Mach numbers, D. Papamoschou and A. Roshko, J. Fluid Mech. 197, 453 (1988)] that support localized shocks (shocklets) not extending into the free stream (P. E. Dimotakis, Proceedings of the 22nd Fluid Dynamics, Plasma Dynamics and Lasers Conference, 1991, Paper No. AIAA 91-1724). However, it is also possible that these low density bubbles are the result of a cavitationlike effect. Hypothesis that may explain the appearance of low density bubbles will be discussed.

  14. Structured block copolymer thin film composites for ultra-high energy density capacitors

    NASA Astrophysics Data System (ADS)

    Samant, Saumil; Hailu, Shimelis; Grabowski, Christopher; Durstock, Michael; Raghavan, Dharmaraj; Karim, Alamgir

    2014-03-01

    Development of high energy density capacitors is essential for future applications like hybrid vehicles and directed energy weaponry. Fundamentally, energy density is governed by product of dielectric permittivity ɛ and breakdown strength Vbd. Hence, improvements in energy density are greatly reliant on improving either ɛ or Vbd or a combination of both. Polymer films are widely used in capacitors due to high Vbd and low loss but they suffer from very low permittivities. Composite dielectrics offer a unique opportunity to combine the high ɛ of inorganic fillers with the high Vbd of a polymer matrix. For enhancement of dielectric properties, it is essential to improve matrix-filler interaction and control the spatial distribution of fillers for which nanostructured block copolymers BCP act as ideal templates. We use Directed Self-assembly of block copolymers to rapidly fabricate highly aligned BCP-TiO2 composite nanostructures in thin films under dynamic thermal gradient field to synergistically combine the high ɛ of functionalized TiO2 and high Vbd of BCP matrix. The results of impact of BCP morphology, processing conditions and concentration of TiO2 on capacitor performance will be reported. U.S. Air Force of Scientific Research under contract FA9550-12-1-0306

  15. 2D quasi-ordered nitrogen-enriched porous carbon nanohybrids for high energy density supercapacitors.

    PubMed

    Kan, Kan; Wang, Lei; Yu, Peng; Jiang, Baojiang; Shi, Keying; Fu, Honggang

    2016-05-21

    Two-dimensional (2D) quasi-ordered nitrogen-enriched porous carbon (QNPC) nanohybrids, with the characteristics of an ultrathin graphite nanosheet framework and thick quasi-ordered nitrogen-doped carbon cladding with a porous texture, have been synthesized via an in situ polymerization assembly method. In the synthesis, the expandable graphite (EG) is enlarged by an intermittent microwave method, and then aniline monomers are intercalated into the interlayers of the expanded EG with the assistance of a vacuum. Subsequently, the intercalated aniline monomers could assemble on the interlayer surface of the expanded EG, accompanied by the in situ polymerization from aniline monomers to polyaniline. Meanwhile, the expanded EG could be exfoliated to graphite nanosheets. By subsequent pyrolysis and activation processes, the QNPC nanohybrids could be prepared. As supercapacitor electrodes, a typical QNPC12-700 sample derived from the precursor containing an EG content of 12%, with a high level of nitrogen doping of 5.22 at%, offers a high specific capacitance of 305.7 F g(-1) (1 A g(-1)), excellent rate-capability and long-term stability. Notably, an extremely high energy density of 95.7 Wh kg(-1) at a power density of 449.7 W kg(-1) in an ionic liquid electrolyte can be achieved. The unique structural features and moderate heteroatom doping of the QNPC nanohybrids combines electrochemical double layer and faradaic capacitance contributions, which make these nanohybrids ideal candidates as electrode materials for high-performance energy storage devices.

  16. Activated Microporous Carbon Derived from Almond Shells for High Energy Density Asymmetric Supercapacitors.

    PubMed

    Wu, Chun; Yang, Shaoran; Cai, Junjie; Zhang, Qiaobao; Zhu, Ying; Zhang, Kaili

    2016-06-22

    Via the activation treatment of carbonized almond shells with HNO3 and KOH, activated microporous carbon (AMC-3 and AMC-2) was successfully synthesized. These two AMC electrodes demonstrate remarkable electrochemical behaviors such as high rate capability, high specific capacitance, and excellent cycle stability when serving as electrodes for supercapacitors. More importantly, through the use of a Zn-Ni-Co ternary oxide (ZNCO) positive electrode and the AMC negative electrode, asymmetric supercapacitors (ASC) were assembled that deliver superior energy density (53.3 Wh kg(-1) at a power density of 1126.1 W kg(-1) for ASC-2 and 53.6 Wh kg(-1) at a power density of 1124.5 W kg(-1) for ASC-3) and excellent stability (82.7% and 83.4% specific capacitance retention for ZNCO//AMC ASC-2 and ZNCO//AMC ASC-3, respectively, after 5000 cycles). Through these two methods, low-cost, renewable, and environmentally friendly electrode materials can be provided for high energy density supercapacitors.

  17. Using Magnetic Fields to Create and Control High Energy Density Matter

    SciTech Connect

    Herrmann, Mark

    2012-05-09

    The recently refurbished Z facility at Sandia National Laboratories is the world’s largest pulsed power driver. Z can efficiently deliver currents as large as 26 Million Amperes to centimeter scale loads. These large currents create large magnetic fields that, in turn, create very large pressures in conducting materials. These very large pressures have been used to create unique conditions for high energy density science experiments for a variety of applications. Recently, we have been exploring the use of very strong magnetic fields to significantly relax the requirements for achieving inertial confinement fusion self heating1. The magnetized liner inertial fusion (MagLIF) concept relies on a cylindrically imploding liner, an axial magnetic field, and a laser heated fuel region. We hope to achieve significant fusion yield on the Z facility with this concept. Initial experiments assessing the growth of the Magneto-Rayleigh Taylor instability are promising and recent calculational work has identified an approach to achieving high gain with this concept.

  18. X-ray spectroscopy for high energy-density X pinch density and temperature measurements (invited)

    SciTech Connect

    Pikuz, S.A.; Shelkovenko, T.A.; Chandler, K.M.; Mitchell, M.D.; Hammer, D.A.; Skobelev, I.Y.; Shlyaptseva, A.S.; Hansen, S.B.

    2004-10-01

    X pinch plasmas produced from fine metal wires can reach near solid densities and temperatures of 1 keV or even more. Plasma conditions change on time scales as short as 5-10 ps as determined using an x-ray streak camera viewing a focusing crystal spectrograph or directly viewing the plasma through multiple filters on a single test. As a result, it is possible to determine plasma conditions from spectra with {approx}10 ps time resolution. Experiments and theory are now coming together to give a consistent picture of the dynamics and kinetics of these high energy density plasmas with very high temporal and spatial precision. A set of diagnostic techniques used in experiments for spectrally, temporally, and spatially resolved measurements of X pinch plasmas is described. Results of plasma parameter determination from these measurements are presented. X ray backlighting of one x-pinch by another with {approx}30 ps x-ray pulses enables the dynamics and kinetics to be correlated in time.

  19. Development of optics for x-ray phase-contrast imaging of high energy density plasmas.

    PubMed

    Stutman, D; Finkenthal, M; Moldovan, N

    2010-10-01

    Phase-contrast or refraction-enhanced x-ray radiography can be useful for the diagnostic of low-Z high energy density plasmas, such as imploding inertial confinement fusion (ICF) pellets, due to its sensitivity to density gradients. To separate and quantify the absorption and refraction contributions to x-ray images, methods based on microperiodic optics, such as shearing interferometry, can be used. To enable applying such methods with the energetic x rays needed for ICF radiography, we investigate a new type of optics consisting of grazing incidence microperiodic mirrors. Using such mirrors, efficient phase-contrast imaging systems could be built for energies up to ∼100 keV. In addition, a simple lithographic method is proposed for the production of the microperiodic x-ray mirrors based on the difference in the total reflection between a low-Z substrate and a high-Z film. Prototype mirrors fabricated with this method show promising characteristics in laboratory tests.

  20. Pulse Power Capability Of High Energy Density Capacitors Based on a New Dielectric Material

    NASA Technical Reports Server (NTRS)

    Winsor, Paul; Scholz, Tim; Hudis, Martin; Slenes, Kirk M.

    1999-01-01

    A new dielectric composite consisting of a polymer coated onto a high-density metallized Kraft has been developed for application in high energy density pulse power capacitors. The polymer coating is custom formulated for high dielectric constant and strength with minimum dielectric losses. The composite can be wound and processed using conventional wound film capacitor manufacturing equipment. This new system has the potential to achieve 2 to 3 J/cu cm whole capacitor energy density at voltage levels above 3.0 kV, and can maintain its mechanical properties to temperatures above 150 C. The technical and manufacturing development of the composite material and fabrication into capacitors are summarized in this paper. Energy discharge testing, including capacitance and charge-discharge efficiency at normal and elevated temperatures, as well as DC life testing were performed on capacitors manufactured using this material. TPL (Albuquerque, NM) has developed the material and Aerovox (New Bedford, MA) has used the material to build and test actual capacitors. The results of the testing will focus on pulse power applications specifically those found in electro-magnetic armor and guns, high power microwave sources and defibrillators.

  1. Highly Oriented Graphene Sponge Electrode for Ultra High Energy Density Lithium Ion Hybrid Capacitors.

    PubMed

    Ahn, Wook; Lee, Dong Un; Li, Ge; Feng, Kun; Wang, Xiaolei; Yu, Aiping; Lui, Gregory; Chen, Zhongwei

    2016-09-28

    Highly oriented rGO sponge (HOG) can be easily synthesized as an effective anode for application in high-capacity lithium ion hybrid capacitors. X-ray diffraction and morphological analyses show that successfully exfoliated rGO sponge on average consists of 4.2 graphene sheets, maintaining its three-dimensional structure with highly oriented morphology even after the thermal reduction procedure. Lithium-ion hybrid capacitors (LIC) are fabricated in this study based on a unique cell configuration which completely eliminates the predoping process of lithium ions. The full-cell LIC consisting of AC/HOG-Li configuration has resulted in remarkably high energy densities of 231.7 and 131.9 Wh kg(-1) obtained at 57 W kg(-1) and 2.8 kW kg(-1). This excellent performance is attributed to the lithium ion diffusivity related to the intercalation reaction of AC/HOG-Li which is 3.6 times higher that of AC/CG-Li. This unique cell design and configuration of LIC presented in this study using HOG as an effective anode is an unprecedented example of performance enhancement and improved energy density of LIC through successful increase in cell operation voltage window.

  2. Hydrate-melt electrolytes for high-energy-density aqueous batteries

    NASA Astrophysics Data System (ADS)

    Yamada, Yuki; Usui, Kenji; Sodeyama, Keitaro; Ko, Seongjae; Tateyama, Yoshitaka; Yamada, Atsuo

    2016-10-01

    Aqueous Li-ion batteries are attracting increasing attention because they are potentially low in cost, safe and environmentally friendly. However, their low energy density (<100 Wh kg-1 based on total electrode weight), which results from the narrow operating potential window of water and the limited selection of suitable negative electrodes, is problematic for their future widespread application. Here, we explore optimized eutectic systems of several organic Li salts and show that a room-temperature hydrate melt of Li salts can be used as a stable aqueous electrolyte in which all water molecules participate in Li+ hydration shells while retaining fluidity. This hydrate-melt electrolyte enables a reversible reaction at a commercial Li4Ti5O12 negative electrode with a low reaction potential (1.55 V versus Li+/Li) and a high capacity (175 mAh g-1). The resultant aqueous Li-ion batteries with high energy density (>130 Wh kg-1) and high voltage (˜2.3-3.1 V) represent significant progress towards performance comparable to that of commercial non-aqueous batteries (with energy densities of ˜150-400 Wh kg-1 and voltages of ˜2.4-3.8 V).

  3. High Energy Density and High Temperature Multilayer Capacitor Films for Electric Vehicle Applications

    NASA Astrophysics Data System (ADS)

    Treufeld, Imre; Song, Michelle; Zhu, Lei; Baer, Eric; Snyder, Joe; Langhe, Deepak

    2015-03-01

    Multilayer films (MLFs) with high energy density and high temperature capability (>120 °C) have been developed at Case Western Reserve University. Such films offer a potential solution for electric car DC-link capacitors, where high ripple currents and high temperature tolerance are required. The current state-of-the-art capacitors used in electric cars for converting DC to AC use biaxially oriented polypropylene (BOPP), which can only operate at temperatures up to 85 °C requiring an external cooling system. The polycarbonate (PC)/poly(vinylidene fluoride) (PVDF) MLFs have a higher permittivity compared to that of BOPP (2.3), leading to higher energy density. They have good mechanical stability and reasonably low dielectric losses at 120 °C. Nonetheless, our preliminary dielectric measurements show that the MLFs exhibit appreciable dielectric losses (20%) at 120 °C, which would, despite all the other advantages, make them not suitable for practical applications. Our preliminary data showed that dielectric losses of the MLFs at 120 °C up to 400 MV/m and 1000 Hz originate mostly from impurity ionic conduction. This work is supported by the NSF PFI/BIC Program (IIP-1237708).

  4. Advanced intermediate temperature sodium-nickel chloride batteries with ultra-high energy density.

    PubMed

    Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y; Meinhardt, Kerry D; Chang, Hee Jung; Canfield, Nathan L; Sprenkle, Vincent L

    2016-02-11

    Sodium-metal halide batteries have been considered as one of the more attractive technologies for stationary electrical energy storage, however, they are not used for broader applications despite their relatively well-known redox system. One of the roadblocks hindering market penetration is the high-operating temperature. Here we demonstrate that planar sodium-nickel chloride batteries can be operated at an intermediate temperature of 190 °C with ultra-high energy density. A specific energy density of 350 Wh kg(-1), higher than that of conventional tubular sodium-nickel chloride batteries (280 °C), is obtained for planar sodium-nickel chloride batteries operated at 190 °C over a long-term cell test (1,000 cycles), and it attributed to the slower particle growth of the cathode materials at the lower operating temperature. Results reported here demonstrate that planar sodium-nickel chloride batteries operated at an intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs.

  5. Graphene/heparin template-controlled polyaniline nanofibers composite for high energy density supercapacitor electrode

    NASA Astrophysics Data System (ADS)

    Moniruzzaman Sk, Md; Yue, Chee Yoon; Jena, Rajeeb Kumar

    2014-12-01

    Graphene/PANI nanofibers composites are prepared for the first time using a novel in situ polymerization method based on the chemical oxidative polymerization of aniline using heparin as a soft template. The even dispersion of individual graphene sheet within the polymer nanofibers matrix enhances the kinetics for both charge transfer and ion transport throughout the electrode. This novel G25PNF75 composite (weight ratio of GO:PANI = 25:75) shows a high specific capacitance of 890.79 F g-1 and an excellent energy density of 123.81 Wh kg-1 at a constant discharge current of 0.5 mA. The composite exhibits excellent cycle life with 88.78% specific capacitance retention after 1000 charge-discharge cycles. The excellent performance of the composite is due to the synergistic combination of graphene which provides good electrical conductivity and mechanical stability, and PANI nanofiber which provides good redox activity that consequently contributed such high energy density.

  6. High-Energy-Density Poly(styrene-co-acrylonitrile) Thin Films

    NASA Astrophysics Data System (ADS)

    Wen, Fei; Xu, Zhuo; Xia, Weimin; Ye, Hongjun; Wei, Xiaoyong; Zhang, Zhicheng

    2013-12-01

    The dielectric response of poly(styrene-co-acrylonitrile) (PSAN) thin films fabricated by a solution casting process was investigated in this work. Linear dielectric behavior was obtained in PSAN films under an electric field at frequencies from 100 Hz to 1 MHz and temperature of -50°C to 100°C. The polymer films exhibited an intermediate dielectric permittivity of 4 and low dielectric loss (tan δ) of 0.027. Under 400 MV/m, the energy density of the PSAN films was 6.8 J/cm3, which is three times higher than that of biaxially oriented polypropylene (BOPP) (about 1.6 J/cm3). However, their charge-discharge efficiency (about 90%) was rather close to that of BOPP. The calculated effective dielectric permittivity of the PSAN films under high electric field was as high as 9, which may be attributed to the improved displacement of the cyanide groups (-CN) polarized at high electric fields. These high-performance features make PSAN attractive for high-energy-density capacitor applications.

  7. Dense Plasma Focus - From Alternative Fusion Source to Versatile High Energy Density Plasma Source for Plasma Nanotechnology

    NASA Astrophysics Data System (ADS)

    Rawat, R. S.

    2015-03-01

    The dense plasma focus (DPF), a coaxial plasma gun, utilizes pulsed high current electrical discharge to heat and compress the plasma to very high density and temperature with energy densities in the range of 1-10 × 1010 J/m3. The DPF device has always been in the company of several alternative magnetic fusion devices as it produces intense fusion neutrons. Several experiments conducted on many different DPF devices ranging over several order of storage energy have demonstrated that at higher storage energy the neutron production does not follow I4 scaling laws and deteriorate significantly raising concern about the device's capability and relevance for fusion energy. On the other hand, the high energy density pinch plasma in DPF device makes it a multiple radiation source of ions, electron, soft and hard x-rays, and neutrons, making it useful for several applications in many different fields such as lithography, radiography, imaging, activation analysis, radioisotopes production etc. Being a source of hot dense plasma, strong shockwave, intense energetic beams and radiation, etc, the DPF device, additionally, shows tremendous potential for applications in plasma nanoscience and plasma nanotechnology. In the present paper, the key features of plasma focus device are critically discussed to understand the novelties and opportunities that this device offers in processing and synthesis of nanophase materials using, both, the top-down and bottom-up approach. The results of recent key experimental investigations performed on (i) the processing and modification of bulk target substrates for phase change, surface reconstruction and nanostructurization, (ii) the nanostructurization of PLD grown magnetic thin films, and (iii) direct synthesis of nanostructured (nanowire, nanosheets and nanoflowers) materials using anode target material ablation, ablated plasma and background reactive gas based synthesis and purely gas phase synthesis of various different types of

  8. Aerodynamic beam generator for large particles

    DOEpatents

    Brockmann, John E.; Torczynski, John R.; Dykhuizen, Ronald C.; Neiser, Richard A.; Smith, Mark F.

    2002-01-01

    A new type of aerodynamic particle beam generator is disclosed. This generator produces a tightly focused beam of large material particles at velocities ranging from a few feet per second to supersonic speeds, depending on the exact configuration and operating conditions. Such generators are of particular interest for use in additive fabrication techniques.

  9. Counter-facing plasma focus system as a repetitive and/or long-pulse high energy density plasma source

    SciTech Connect

    Aoyama, Yutaka; Nakajima, Mitsuo; Horioka, Kazuhiko

    2009-11-15

    A plasma focus system composed of a pair of counter-facing coaxial plasma guns is proposed as a long-pulse and/or repetitive high energy density plasma source. A proof-of-concept experiment demonstrated that with an assist of breakdown and outer electrode connections, current sheets evolved into a configuration for stable plasma confinement at the center of the electrodes. The current sheets could successively compress and confine the high energy density plasma every half period of the discharge current, enabling highly repetitive light emissions in extreme ultraviolet region with time durations in at least ten microseconds.

  10. Counter-facing plasma focus system as a repetitive and/or long-pulse high energy density plasma source

    NASA Astrophysics Data System (ADS)

    Aoyama, Yutaka; Nakajima, Mitsuo; Horioka, Kazuhiko

    2009-11-01

    A plasma focus system composed of a pair of counter-facing coaxial plasma guns is proposed as a long-pulse and/or repetitive high energy density plasma source. A proof-of-concept experiment demonstrated that with an assist of breakdown and outer electrode connections, current sheets evolved into a configuration for stable plasma confinement at the center of the electrodes. The current sheets could successively compress and confine the high energy density plasma every half period of the discharge current, enabling highly repetitive light emissions in extreme ultraviolet region with time durations in at least ten microseconds.

  11. 2D quasi-ordered nitrogen-enriched porous carbon nanohybrids for high energy density supercapacitors

    NASA Astrophysics Data System (ADS)

    Kan, Kan; Wang, Lei; Yu, Peng; Jiang, Baojiang; Shi, Keying; Fu, Honggang

    2016-05-01

    Two-dimensional (2D) quasi-ordered nitrogen-enriched porous carbon (QNPC) nanohybrids, with the characteristics of an ultrathin graphite nanosheet framework and thick quasi-ordered nitrogen-doped carbon cladding with a porous texture, have been synthesized via an in situ polymerization assembly method. In the synthesis, the expandable graphite (EG) is enlarged by an intermittent microwave method, and then aniline monomers are intercalated into the interlayers of the expanded EG with the assistance of a vacuum. Subsequently, the intercalated aniline monomers could assemble on the interlayer surface of the expanded EG, accompanied by the in situ polymerization from aniline monomers to polyaniline. Meanwhile, the expanded EG could be exfoliated to graphite nanosheets. By subsequent pyrolysis and activation processes, the QNPC nanohybrids could be prepared. As supercapacitor electrodes, a typical QNPC12-700 sample derived from the precursor containing an EG content of 12%, with a high level of nitrogen doping of 5.22 at%, offers a high specific capacitance of 305.7 F g-1 (1 A g-1), excellent rate-capability and long-term stability. Notably, an extremely high energy density of 95.7 Wh kg-1 at a power density of 449.7 W kg-1 in an ionic liquid electrolyte can be achieved. The unique structural features and moderate heteroatom doping of the QNPC nanohybrids combines electrochemical double layer and faradaic capacitance contributions, which make these nanohybrids ideal candidates as electrode materials for high-performance energy storage devices.Two-dimensional (2D) quasi-ordered nitrogen-enriched porous carbon (QNPC) nanohybrids, with the characteristics of an ultrathin graphite nanosheet framework and thick quasi-ordered nitrogen-doped carbon cladding with a porous texture, have been synthesized via an in situ polymerization assembly method. In the synthesis, the expandable graphite (EG) is enlarged by an intermittent microwave method, and then aniline monomers are

  12. Electron beam parallel X-ray generator

    NASA Technical Reports Server (NTRS)

    Payne, P.

    1967-01-01

    Broad X ray source produces a highly collimated beam of low energy X rays - a beam with 2 to 5 arc minutes of divergence at energies between 1 and 6 keV in less than 5 feet. The X ray beam is generated by electron bombardment of a target from a large area electron gun.

  13. Pressure-induced stable BeN4 as a high-energy density material

    NASA Astrophysics Data System (ADS)

    Zhang, Shoutao; Zhao, Ziyuan; Liu, Lulu; Yang, Guochun

    2017-10-01

    Polynitrogens are the ideal rocket fuels or propellants. Due to strong triple N≡N bond in N2, the direct polymerization of nitrogen is rather difficult (i.e. extreme high temperature and high pressure). However, the use of nitrides as precursors or the reaction of N2 with other elements has been proved to be an effective way to obtain polynitrogens. Here, with assistance of the advanced first-principles swarm-intelligence structure searches, we found that P 1 bar -BeN4, containing infinite zigzag-like polymeric nitrogen chains, can be synthesized by compressing the mixture of Be3N2 and N2 at 25.4 GPa, which is greatly lower than 110 GPa for synthesizing cubic gauche nitrogen and other polynitrogen compounds (e.g. bulk CNO at 52 GPa and SN4 at 49 GPa). Its structural stability can be attributed to the coexistence of ionic Be-N and covalent N-N bonds. Intriguingly, this phase has high kinetic stability and remains metastable at ambient pressure. The exceptional properties, including high energy density (3.60 kJ g-1), high nitrogen content (86.1%), high dynamical stability, and low polymerization pressure, make P 1 bar -structured BeN4 a promising high energy material. Infinite nitrogen chains in P 1 bar -BeN4 transform to N10 rings network in P21/c phase at 115.1 GPa. P 1 bar -BeN4 is metallic, while P21/c-BeN4 is an insulator.

  14. The NIF: An international high energy density science and inertial fusion user facility

    NASA Astrophysics Data System (ADS)

    Moses, E. I.; Storm, E.

    2013-11-01

    The National Ignition Facility (NIF), a 1.8-MJ/500-TW Nd:Glass laser facility designed to study inertial confinement fusion (ICF) and high-energy-density science (HEDS), is operational at Lawrence Livermore National Laboratory (LLNL). A primary goal of NIF is to create the conditions necessary to demonstrate laboratory-scale thermonuclear ignition and burn. NIF experiments in support of indirect-drive ignition began late in FY2009 as part of the National Ignition Campaign (NIC), an international effort to achieve fusion ignition in the laboratory. To date, all of the capabilities to conduct implosion experiments are in place with the goal of demonstrating ignition and developing a predictable fusion experimental platform in 2012. The results from experiments completed are encouraging for the near-term achievement of ignition. Capsule implosion experiments at energies up to 1.6 MJ have demonstrated laser energetics, radiation temperatures, and symmetry control that scale to ignition conditions. Of particular importance is the demonstration of peak hohlraum temperatures near 300 eV with overall backscatter less than 15%. Important national security and basic science experiments have also been conducted on NIF. Successful demonstration of ignition and net energy gain on NIF will be a major step towards demonstrating the feasibility of laser-driven Inertial Fusion Energy (IFE). This paper will describe the results achieved so far on the path toward ignition, the beginning of fundamental science experiments and the plans to transition NIF to an international user facility providing access to HEDS and fusion energy researchers around the world.

  15. Experimental investigation of opacity models for stellar interiors, inertial fusion, and high energy density plasmas

    NASA Astrophysics Data System (ADS)

    Bailey, James

    2008-11-01

    Theoretical opacities are required for calculating energy transport in plasmas. In particular, understanding stellar interiors, inertial fusion, and Z-pinches depends on the opacities of mid-atomic-number elements in the 150-300 eV temperature range. These models are complex and experimental validation is crucial. For example, solar models presently disagree with helioseismology and one possible explanation is inadequate opacities. Testing these opacities requires a uniform plasma at temperatures high enough to produce the ion charge states that exist in the sun. Typical opacity experiments heat a sample using x-rays and measure the spectrally resolved transmission with a backlight. The difficulty grows as the temperature increases because the heating x-ray source must supply more energy and the backlighter source must be bright enough to overwhelm the plasma self emission. These problems were overcome using the dynamic hohlraum x-ray source at Sandia's Z facility to measure the transmission of a mixed Mg-Fe plasma heated above 150 eV. This capability will also advance opacity science for other high energy density plasmas. This tutorial describes opacity experiment challenges including accurate transmission measurements, plasma diagnostics, and quantitative model comparisons. The solar interior serves as a focal problem and Z facility experiments are used to illustrate the techniques. **In collaboration with C. Iglesias (LLNL), R. Mancini (U. Nevada), J.MacFarlane, I. Golovkin and P. Wang (Prism), C. Blancard, Ph. Cosse, G. Faussurier, F. Gilleron, and J.C. Pain (CEA), J. Abdallah Jr. (LANL), and G.A. Rochau and P.W. Lake (Sandia). ++Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy under contract DE-AC04-94AL85000.

  16. Observations of subsonic and supersonic shear flows in laser driven high-energy-density plasmas

    NASA Astrophysics Data System (ADS)

    Harding, E. C.

    2009-11-01

    Shear layers containing strong velocity gradients appear in many high-energy-density (HED) systems and play important roles in mixing and the transition to turbulence. Yet few laboratory experiments have been carried out to study their detailed evolution in this extreme environment where plasmas are compressible, actively ionizing, often involve strong shock waves and have complex material properties. Many shear flows produce the Kelvin-Helmholtz (KH) instability, which initiates the mixing at a fluid interface. We present results from two dedicated shear flow experiments that produced overall subsonic and supersonic flows using novel target designs. In the subsonic case, the Omega laser was used to drive a blast wave along a rippled interface between plastic and foam, shocking both the materials to produce two fluids separated by a sharp shear layer. The interface subsequently rolled-upped into large KH vortices that were accompanied by bubble-like structures of unknown origin. This was the first time the evolution of a well-resolved KH instability was observed in a HED plasma in the laboratory. We have analyzed the properties and dynamics of the plasma based on the data and fundamental models, without resorting to simulated values. In the second, supersonic experiment the Nike laser was used to drive a supersonic flow of Al plasma along a rippled, low-density foam surface. Here again the flowing plasma drove a shock into the second material, so that two fluids were separated by a shear layer. In contrast to the subsonic case, the flow developed shocks around the ripples in response to the supersonic flow of Al. Collaborators: R.P. Drake, O.A. Hurricane, J.F. Hansen, Y. Aglitskiy, T. Plewa, B.A. Remington, H.F. Robey, J.L. Weaver, A.L. Velikovich, R.S. Gillespie, M.J. Bono, M.J. Grosskopf, C.C. Kuranz, A. Visco.

  17. Measurements of Ion Stopping around the Bragg Peak in High-Energy-Density Plasmas

    NASA Astrophysics Data System (ADS)

    Frenje, Johan

    2015-11-01

    Over the last few decades, ion stopping in weakly- to strongly-coupled High-Energy-Density (HED) plasmas has been subject to extensive analytical and numerical studies, but only a limited set of experimental data exists to check the validity of these theories. Most of these experiments also did not probe the detailed characteristics of the Bragg peak (peak ion stopping) where the ion velocity is similar to the average thermal electron velocity. To the best of our knowledge, only one exploratory attempt to do this was conducted by Hicks et al., who were able to describe qualitatively the behavior of the Bragg peak for one plasma condition. The work described in this presentation makes significant advances over previous experimental efforts by quantitatively assessing the characteristics of the ion stopping, ranging from low-velocity stopping, through the Bragg peak, to high-velocity stopping for different HED plasma conditions. This was achieved by measuring the energy loss of DD-tritons, D3He-alphas, DD-protons and D3He-protons, with distinctly different velocities, and the results indicate that the stopping power varies strongly with Te and ne. This effort represents the first experimental test of state-of-art plasma-stopping-power theories around the Bragg peak, which is an important first step in our efforts of getting a fundamental understanding of DT-alpha stopping in HED plasmas, a prerequisite for understanding ignition margins in various implosion designs with varying hot spot areal density at the National Ignition Facility. The work described here was performed in part at the LLE National Laser User's Facility (NLUF), and was supported in part by US DOE (Grant No. DE-FG03- 03SF22691), LLNL (subcontract Grant No. B504974) and LLE (subcontract Grant No. 412160-001G).

  18. Scaling a High-Energy-Density Shear Experiment from Omega to the National Ignition Facility (NIF)

    NASA Astrophysics Data System (ADS)

    Doss, Forrest W.

    2014-10-01

    Shear instability in high-energy-density (HED) physics is important for elucidating issues in compressible turbulence and in understanding the late time quenching of, for example, inertial fusion capsules. A counterflowing shear experiment initially designed for the Omega Laser Facility studies shear instability in isolation by launching 100+ km/s shocks into opposite sides of a foam-filled shock tube bisected by an Al tracer plate. When the shocks cross at the tube center, a region of intense shear is created (~ 150 km/s velocity difference from one side of the plate to the other). As the tracer layer goes unstable it mixes with the surrounding foam and expands into the tube volume. Radiography recording the spreading of the mixing layer is compared to simulations using the LANL hydrocode RAGE. Analysis of this data demonstrated the likely presence of features, such as strong coupling between the thermodynamics and turbulence during the experiment, of special or unique importance to the HED regime. However, the Omega experiments are limited to 1 ns impulsive drive, compared to the 16 ns of observation times, and are dominated by transients, barely if at all reaching the state of developed turbulence. Our recent shots on the NIF take the experiment to larger volumes, to faster speeds, and to the use of indirect drive halfraums to launch steadily supported shocks. These improvements take advantage of the increased energy of the NIF to eliminate transients and drive more steadily the approach to turbulent transition. Analysis of radiographs confirms our ability to model the hydrodynamic drive and evolution, while comparing images of the developing turbulence between the two facilities suggests morphological differences related possibly to the change in drive conditions. This work was supported by the US DOE and operated by LANS under Contract No. DE-AC52-06NA25396.

  19. The POSEIDON electron beam generator. Final report

    SciTech Connect

    Sethian, J.D.; Mora, F.

    1982-09-27

    The POSEIDON electron beam generator was designed to perform a series of experiments to produce a closed field line plasma confinement system with two rotating relativistic electron beams. Previous experimental studies have shown that a single rotating beam (generated by the TRITON electron beam generator) can produce a plasma in a reversed field configuration inside an initially field free metal tube. The magnetic fields were maintained with induced plasma currents rather than the beam electrons themselves. However, because the beam was injected from one end of the system, a net axial current persisted which precluded axial containment. To eliminate this current, it was proposed to inject a second rotating beam from the opposite end of the system.

  20. A stencil printed, high energy density silver oxide battery using a novel photopolymerizable poly(acrylic acid) separator.

    PubMed

    Braam, Kyle; Subramanian, Vivek

    2015-01-27

    A novel photopolymerized poly(acrylic acid) separator is demonstrated in a printed, high-energy-density silver oxide battery. The printed battery demonstrates a high capacity of 5.4 mA h cm(-2) at a discharge current density of 2.75 mA cm(-2) (C/2 rate) while delivering good mechanical flexibility and robustness.

  1. High-Energy-Density Fuel Blending Strategies and Drop Dispersion for Fuel Cost Reduction and Soot Propensity Control

    NASA Technical Reports Server (NTRS)

    Bellan, J.; Harstad, K.

    1998-01-01

    The idea that low soot propensity of high-energy-density (HED) liquid sooting fuels and cost reduction of a multicomponent energetic fuel can be achieved by doping a less expensive, less sooting liquid fuel with HED is tested through numerical simulations.

  2. Applications of Robust, Radiation Hard AlGaN Optoelectronic Devices in Space Exploration and High Energy Density Physics

    SciTech Connect

    Sun, K.

    2011-05-04

    This slide show presents: space exploration applications; high energy density physics applications; UV LED and photodiode radiation hardness; UV LED and photodiode space qualification; UV LED AC charge management; and UV LED satellite payload instruments. A UV LED satellite will be launched 2nd half 2012.

  3. Transition metal sulfides grown on graphene fibers for wearable asymmetric supercapacitors with high volumetric capacitance and high energy density.

    PubMed

    Cai, Weihua; Lai, Ting; Lai, Jianwei; Xie, Haoting; Ouyang, Liuzhang; Ye, Jianshan; Yu, Chengzhong

    2016-06-01

    Fiber shaped supercapacitors are promising candidates for wearable electronics because they are flexible and light-weight. However, a critical challenge of the widespread application of these energy storage devices is their low cell voltages and low energy densities, resulting in limited run-time of the electronics. Here, we demonstrate a 1.5 V high cell voltage and high volumetric energy density asymmetric fiber supercapacitor in aqueous electrolyte. The lightweight (0.24 g cm(-3)), highly conductive (39 S cm(-1)), and mechanically robust (221 MPa) graphene fibers were firstly fabricated and then coated by NiCo2S4 nanoparticles (GF/NiCo2S4) via the solvothermal deposition method. The GF/NiCo2S4 display high volumetric capacitance up to 388 F cm(-3) at 2 mV s(-1) in a three-electrode cell and 300 F cm(-3) at 175.7 mA cm(-3) (568 mF cm(-2) at 0.5 mA cm(-2)) in a two-electrode cell. The electrochemical characterizations show 1000% higher capacitance of the GF/NiCo2S4 as compared to that of neat graphene fibers. The fabricated device achieves high energy density up to 12.3 mWh cm(-3) with a maximum power density of 1600 mW cm(-3), outperforming the thin-film lithium battery. Therefore, these supercapacitors are promising for the next generation flexible and wearable electronic devices.

  4. Transition metal sulfides grown on graphene fibers for wearable asymmetric supercapacitors with high volumetric capacitance and high energy density

    PubMed Central

    Cai, Weihua; Lai, Ting; Lai, Jianwei; Xie, Haoting; Ouyang, Liuzhang; Ye, Jianshan; Yu, Chengzhong

    2016-01-01

    Fiber shaped supercapacitors are promising candidates for wearable electronics because they are flexible and light-weight. However, a critical challenge of the widespread application of these energy storage devices is their low cell voltages and low energy densities, resulting in limited run-time of the electronics. Here, we demonstrate a 1.5 V high cell voltage and high volumetric energy density asymmetric fiber supercapacitor in aqueous electrolyte. The lightweight (0.24 g cm−3), highly conductive (39 S cm−1), and mechanically robust (221 MPa) graphene fibers were firstly fabricated and then coated by NiCo2S4 nanoparticles (GF/NiCo2S4) via the solvothermal deposition method. The GF/NiCo2S4 display high volumetric capacitance up to 388 F cm−3 at 2 mV s−1 in a three-electrode cell and 300 F cm−3 at 175.7 mA cm−3 (568 mF cm−2 at 0.5 mA cm−2) in a two-electrode cell. The electrochemical characterizations show 1000% higher capacitance of the GF/NiCo2S4 as compared to that of neat graphene fibers. The fabricated device achieves high energy density up to 12.3 mWh cm−3 with a maximum power density of 1600 mW cm−3, outperforming the thin-film lithium battery. Therefore, these supercapacitors are promising for the next generation flexible and wearable electronic devices. PMID:27248510

  5. Transition metal sulfides grown on graphene fibers for wearable asymmetric supercapacitors with high volumetric capacitance and high energy density

    NASA Astrophysics Data System (ADS)

    Cai, Weihua; Lai, Ting; Lai, Jianwei; Xie, Haoting; Ouyang, Liuzhang; Ye, Jianshan; Yu, Chengzhong

    2016-06-01

    Fiber shaped supercapacitors are promising candidates for wearable electronics because they are flexible and light-weight. However, a critical challenge of the widespread application of these energy storage devices is their low cell voltages and low energy densities, resulting in limited run-time of the electronics. Here, we demonstrate a 1.5 V high cell voltage and high volumetric energy density asymmetric fiber supercapacitor in aqueous electrolyte. The lightweight (0.24 g cm‑3), highly conductive (39 S cm‑1), and mechanically robust (221 MPa) graphene fibers were firstly fabricated and then coated by NiCo2S4 nanoparticles (GF/NiCo2S4) via the solvothermal deposition method. The GF/NiCo2S4 display high volumetric capacitance up to 388 F cm‑3 at 2 mV s‑1 in a three-electrode cell and 300 F cm‑3 at 175.7 mA cm‑3 (568 mF cm‑2 at 0.5 mA cm‑2) in a two-electrode cell. The electrochemical characterizations show 1000% higher capacitance of the GF/NiCo2S4 as compared to that of neat graphene fibers. The fabricated device achieves high energy density up to 12.3 mWh cm‑3 with a maximum power density of 1600 mW cm‑3, outperforming the thin-film lithium battery. Therefore, these supercapacitors are promising for the next generation flexible and wearable electronic devices.

  6. Highly biocompatible, nanocrystalline hydroxyapatite synthesized in a solvothermal process driven by high energy density microwave radiation

    PubMed Central

    Smolen, Dariusz; Chudoba, Tadeusz; Malka, Iwona; Kedzierska, Aleksandra; Lojkowski, Witold; Swieszkowski, Wojciech; Kurzydlowski, Krzysztof Jan; Kolodziejczyk-Mierzynska, Małgorzata; Lewandowska-Szumiel, Małgorzata

    2013-01-01

    A microwave, solvothermal synthesis of highly biocompatible hydroxyapatite (HAp) nanopowder was developed. The process was conducted in a microwave radiation field having a high energy density of 5 W/mL and over a time less than 2 minutes. The sample measurements included: powder X-ray diffraction, density, specific surface area, and chemical composition. The morphology and structure were investigated by scanning electron microscopy as well as transmission electron microscopy (TEM). The thermal behavior analysis was conducted using a simultaneous thermal analysis technique coupled with quadruple mass spectrometry. Additionally, Fourier transform infrared spectroscopy tests of heated samples were performed. A degradation test and a biocompatibility study in vitro using human osteoblast cells were also conducted. The developed method enables the synthesis of pure, fully crystalline hexagonal HAp nanopowder with a specific surface area close to 240 m2/g and a Ca/P molar ratio equal to 1.57. TEM measurements showed that this method results in particles with an average grain size below 6 nm. A 28-day degradation test conducted according to the ISO standard indicated a 22% loss of initial weight and a calcium ion concentration at 200 μmol/dm3 in the tris(hydroxymethyl)aminomethane hydrochloride test solution. The cytocompatibility of the obtained material was confirmed in a culture of human bone derived cells, both in an indirect test using the material extract, and in direct contact. A quantitative analysis was based on the 2,3-bis-(2-methoxy-4-nitro-5-sulfophenyl)-2H-tetrazolium-5-carboxanilide. Viability assay as well as on DNA content measurements in the PicoGreen test. Indirect observations were performed at one point in time according to the ISO standard for in vitro cytotoxicity (ie, after 24 hours of cell exposure to the extracts). The direct contact tests were completed at three time points: after 24 hours, on day 7, and on day 14 of a culture in an osteogenic

  7. Density Functional Theory in High Energy Density Physics: phase-diagram and electrical conductivity of water

    NASA Astrophysics Data System (ADS)

    Mattsson, Thomas R.

    2007-06-01

    Atomistic simulations employing Density Functional Theory (DFT) have recently emerged as a powerful way of increasing our understanding of materials and processes in high energy density physics. Knowledge of the properties of water (equation of state, electrical conductivity, diffusion, low-energy opacity) is essential for correctly describing the physics of giant planets as well as shock waves in water. Although a qualitative picture of water electrical conductivity has emerged, the necessary quantitative information is scarce over a wide range of temperature and density. Since experiments can only access certain areas of phase space, and often require modeling as a part of the analysis, Quantum Molecular Dynamics simulations play a vital role. Using finite-temperature density functional theory (FT-DFT), we have investigated the structure and electronic conductivity of water across three phase transitions (molecular liquid/ ionic liquid/ superionic/ electronic liquid). The ionic contribution to the conduction is calculated from proton diffusion and the electronic contribution is calculated using the Kubo-Greenwood formula. The calculations are performed with VASP, a plane-wave pseudo-potential code. There is a rapid transition to ionic conduction at 2000 K and 2 g/cm^3, whereas electronic conduction dominates at temperatures at and above 6000 K&[tilde;1]. Contrary to earlier results using the Car-Parrinello method&[tilde;2], we predict that the fluid bordering the superionic phase is conducting above 4000 K and 100 GPa. Our comprehensive use of FT-DFT explains the new findings. The calculated conductivity is compared to experimental data. I gratefully acknowledge Mike Desjarlais, my collaborator in this effort. The LDRD office at Sandia supported this work. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL

  8. High-Energy-Density, Low-Temperature Li/CFx Primary Cells

    NASA Technical Reports Server (NTRS)

    Whitacre, Jay; Bugga, Ratnakumar; Smart, Marshall; Prakash, G.; Yazami, Rachid

    2007-01-01

    High-energy-density primary (nonrechargeable) electrochemical cells capable of relatively high discharge currents at temperatures as low as -40 C have been developed through modification of the chemistry of commercial Li/CFx cells and batteries. The commercial Li/CFx units are not suitable for high-current and low-temperature applications because they are current limited and their maximum discharge rates decrease with decreasing temperature. The term "Li/CFx" refers to an anode made of lithium and a cathode made of a fluorinated carbonaceous material (typically graphite). In commercial cells, x typically ranges from 1.05 to 1.1. This cell composition makes it possible to attain specific energies up to 800 Wh/kg, but in order to prevent cell polarization and the consequent large loss of cell capacity, it is typically necessary to keep discharge currents below C/50 (where C is numerically equal to the current that, flowing during a charge or discharge time of one hour, would integrate to the nominal charge or discharge capacity of a cell). This limitation has been attributed to the low electronic conductivity of CFx for x approx. 1. To some extent, the limitation might be overcome by making cathodes thinner, and some battery manufacturers have obtained promising results using thin cathode structures in spiral configurations. The present approach includes not only making cathodes relatively thin [.2 mils (.0.051 mm)] but also using sub-fluorinated CFx cathode materials (x < 1) in conjunction with electrolytes formulated for use at low temperatures. The reason for choosing sub-fluorinated CFx cathode materials is that their electronic conductivities are high, relative to those for which x > 1. It was known from recent prior research that cells containing sub-fluorinated CFx cathodes (x between 0.33 and 0.66) are capable of retaining substantial portions of their nominal low-current specific energies when discharged at rates as high as 5C at room temperature. However

  9. Seeding magnetic fields for laser-driven flux compression in high-energy-density plasmas.

    PubMed

    Gotchev, O V; Knauer, J P; Chang, P Y; Jang, N W; Shoup, M J; Meyerhofer, D D; Betti, R

    2009-04-01

    A compact, self-contained magnetic-seed-field generator (5 to 16 T) is the enabling technology for a novel laser-driven flux-compression scheme in laser-driven targets. A magnetized target is directly irradiated by a kilojoule or megajoule laser to compress the preseeded magnetic field to thousands of teslas. A fast (300 ns), 80 kA current pulse delivered by a portable pulsed-power system is discharged into a low-mass coil that surrounds the laser target. A >15 T target field has been demonstrated using a <100 J capacitor bank, a laser-triggered switch, and a low-impedance (<1 Omega) strip line. The device has been integrated into a series of magnetic-flux-compression experiments on the 60 beam, 30 kJ OMEGA laser [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)]. The initial application is a novel magneto-inertial fusion approach [O. V. Gotchev et al., J. Fusion Energy 27, 25 (2008)] to inertial confinement fusion (ICF), where the amplified magnetic field can inhibit thermal conduction losses from the hot spot of a compressed target. This can lead to the ignition of massive shells imploded with low velocity-a way of reaching higher gains than is possible with conventional ICF.

  10. Seeding Magnetic Fields for Laser-Driven Flux Compression in High-Energy-Density Plasmas

    SciTech Connect

    Gotchev, O.V.; Knauer, J.P.; Chang, P.Y.; Jang, N.W.; Shoup III, M.J.; Meyerhofer, D.D.; Betti, R.

    2010-03-23

    A compact, self-contained magnetic-seed-field generator (5 to 16 T) is the enabling technology for a novel laser-driven flux-compression scheme in laser-driven targets. A magnetized target is directly irradiated by a kilojoule or megajoule laser to compress the preseeded magnetic field to thousands of teslas. A fast (300 ns), 80 kA current pulse delivered by a portable pulsed-power system is discharged into a low-mass coil that surrounds the laser target. A >15 T target field has been demonstrated using a <100 J capacitor bank, a laser-triggered switch, and a low-impedance (<1 Omega) strip line. The device has been integrated into a series of magnetic-flux-compression experiments on the 60 beam, 30 kJ OMEGA laser [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)]. The initial application is a novel magneto-inertial fusion approach [O. V. Gotchev et al., J. Fusion Energy 27, 25 (2008)] to inertial confinement fusion (ICF), where the amplified magnetic field can inhibit thermal conduction losses from the hot spot of a compressed target. This can lead to the ignition of massive shells imploded with low velocity—a way of reaching higher gains than is possible with conventional ICF.

  11. Seeding magnetic fields for laser-driven flux compression in high-energy-density plasmas

    SciTech Connect

    Gotchev, O. V.; Knauer, J. P.; Shoup, M. J. III; Chang, P. Y.; Jang, N. W.; Meyerhofer, D. D.; Betti, R.

    2009-04-15

    A compact, self-contained magnetic-seed-field generator (5 to 16 T) is the enabling technology for a novel laser-driven flux-compression scheme in laser-driven targets. A magnetized target is directly irradiated by a kilojoule or megajoule laser to compress the preseeded magnetic field to thousands of teslas. A fast (300 ns), 80 kA current pulse delivered by a portable pulsed-power system is discharged into a low-mass coil that surrounds the laser target. A >15 T target field has been demonstrated using a <100 J capacitor bank, a laser-triggered switch, and a low-impedance (<1 {Omega}) strip line. The device has been integrated into a series of magnetic-flux-compression experiments on the 60 beam, 30 kJ OMEGA laser [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)]. The initial application is a novel magneto-inertial fusion approach [O. V. Gotchev et al., J. Fusion Energy 27, 25 (2008)] to inertial confinement fusion (ICF), where the amplified magnetic field can inhibit thermal conduction losses from the hot spot of a compressed target. This can lead to the ignition of massive shells imploded with low velocity--a way of reaching higher gains than is possible with conventional ICF.

  12. Observation of a Kelvin-Helmholtz Instability in a High-Energy-Density Plasma on the Omega Laser

    SciTech Connect

    Harding, E C; Hansen, J F; Hurricane, O A; Drake, R P; Robey, H F; Kuranz, C C; Remington, B A; Bono, M J; Grosskopf, M J; Gillespie, R S

    2009-02-12

    A laser initiated experiment is described in which an unstable plasma shear layer is produced by driving a blast wave along a plastic surface with sinusoidal perturbations. In response to the vorticity deposited and the shear flow established by the blast wave, the interface rolls up into large vortices characteristic of the Kelvin-Helmholtz (KH) instability. The experiment used x ray radiography to capture the first well-resolved images of KH vortices in a high-energy-density plasma, and possibly the first images of transonic shocks generated by large-scale structures in a shear layer. The physical processes governing the evolution of a stratified fluid flow with a large velocity gradient (i.e., a shear flow) are of fundamental interest to a wide range of research areas including combustion, inertial confinement fusion (ICF), stellar supernovae, and geophysical fluid dynamics. Traditional experiments have used inclined tanks of fluid to initiate a flow, generally at low Reynolds numbers, or wind tunnels that combine two parallel gas flows at the end of a thin wedge, known as a splitter plate. The splitter plate experiments have explored flows with maximum shear velocities on the order of 10{sup 3} m/s and Reynolds numbers up to 10{sup 6}. Here we report the creation of a novel type of shear flow, achieved by confining a laser driven blast wave in a millimeter-sized shock tube, which produced shear velocities on the order of 10{sup 4} m/s and Reynolds numbers of 10{sup 6} in a plasma. This system enabled the first apparent observation of transonic shocklets, which are small, localized shocks believed to develop in response to a local supersonic flow occurring over a growing perturbation. These shocklets have been predicted previously in simulations, but have never to our knowledge been observed. These experiments are also the first to observe the growth of perturbations by the Kelvin-Helmholtz (KH) instability under high-energy-density (HED) conditions. In all

  13. Generation of plane shocks using intense heavy ion beams: Application to Richtmyer-Meshkov instability growth studies

    SciTech Connect

    Tahir, N. A.; Stoehlker, Th.; Shutov, A.; Zharkov, A. P.; Piriz, A. R.

    2011-03-15

    A design of a novel experiment that allows the generation of a well defined, steady, and strong plane shock wave employing an intense uranium ion beam that is incident on a wedge shaped compound target is presented. This technique will open up the possibility of carrying out unique high energy density physics experiments using these shock waves. One such experiment is to study the growth of Richtmyer-Meshkov instability in fluids as well as in solids, both in the linear and nonlinear regimes, as shown by detailed numerical simulations presented in this paper. The ion beam parameters used in this study correspond to those that will be available at the Facility for Antiprotons and Ion Research (FAIR) at Darmstadt.

  14. Optical fiber antenna generating spiral beam shapes

    SciTech Connect

    Sarkar Pal, S.; Mondal, S. K. Kumar, R.; Akula, A.; Ghosh, R.; Bhatnagar, R.; Kumbhakar, D.

    2014-01-20

    A simple method is proposed here to generate vortex beam and spiral intensity patterns from a Gaussian source. It uses a special type of optical fiber antenna of aperture ∼80 nm having naturally grown surface curvature along its length. The antenna converts linearly polarized Gaussian beam into a beam with spiral intensity patterns. The experimentally obtained spiral patterns with single and double spiral arms manifest the orbital angular momentum, l = ±1, 2, carried by the output beam. Such beam can be very useful for optical tweezer, metal machining, and similar applications.

  15. Radiation from Ag high energy density Z-pinch plasmas and applications to lasing

    SciTech Connect

    Weller, M. E. Safronova, A. S.; Kantsyrev, V. L.; Esaulov, A. A.; Shrestha, I.; Stafford, A.; Keim, S. F.; Shlyaptseva, V. V.; Osborne, G. C.; Petkov, E. E.; Apruzese, J. P.; Giuliani, J. L.; Chuvatin, A. S.

    2014-03-15

    Silver (Ag) wire arrays were recently introduced as efficient x-ray radiators and have been shown to create L-shell plasmas that have the highest electron temperature (>1.8 keV) observed on the Zebra generator so far and upwards of 30 kJ of energy output. In this paper, results of single planar wire arrays and double planar wire arrays of Ag and mixed Ag and Al that were tested on the UNR Zebra generator are presented and compared. To further understand how L-shell Ag plasma evolves in time, a time-gated x-ray spectrometer was designed and fielded, which has a spectral range of approximately 3.5–5.0 Å. With this, L-shell Ag as well as cold L{sub α} and L{sub β} Ag lines was captured and analyzed along with photoconducting diode (PCD) signals (>0.8 keV). Along with PCD signals, other signals, such as filtered XRD (>0.2 keV) and Si-diodes (SiD) (>9 keV), are analyzed covering a broad range of energies from a few eV to greater than 53 keV. The observation and analysis of cold L{sub α} and L{sub β} lines show possible correlations with electron beams and SiD signals. Recently, an interesting issue regarding these Ag plasmas is whether lasing occurs in the Ne-like soft x-ray range, and if so, at what gains? To help answer this question, a non-local thermodynamic equilibrium (LTE) kinetic model was utilized to calculate theoretical lasing gains. It is shown that the Ag L-shell plasma conditions produced on the Zebra generator at 1.7 maximum current may be adequate to produce gains as high as 6 cm{sup −1} for various 3p → 3s transitions. Other potential lasing transitions, including higher Rydberg states, are also included in detail. The overall importance of Ag wire arrays and plasmas is discussed.

  16. Investigation of the 2p_{32}-3d_{52} line emission of Au;{53+}-Au;{69+} for diagnosing high energy density plasmas.

    PubMed

    Brown, G V; Hansen, S B; Träbert, E; Beiersdorfer, P; Widmann, K; Chen, H; Chung, H K; Clementson, J H T; Gu, M F; Thorn, D B

    2008-06-01

    Measurements of the L -shell emission of highly charged gold ions were made under controlled laboratory conditions using the SuperEBIT electron beam ion trap, allowing detailed spectral observations of lines from Fe-like Au53+ through Ne-like Au69+ . Using atomic data from the Flexible Atomic Code, we have identified strong 3d_{52}-->2p_{32} emission features that can be used to diagnose the charge state distribution in high energy density plasmas, such as those found in the laser entrance hole of hot hohlraum radiation sources. We provide collisional-radiative calculations of the average ion charge Z as a function of temperature and density, which can be used to relate charge state distributions inferred from 3d_{52}-->2p_{32} emission features to plasma conditions, and investigate the effects of plasma density on calculated L -shell Au emission spectra.

  17. Ultra high energy density nanocomposite capacitors using surface-functionalized BaTiO3 nanowires and PVDF-TrFE-CFE

    NASA Astrophysics Data System (ADS)

    Tang, Haixiong; Lin, Yirong; Sodano, Henry A.

    2012-04-01

    High energy density capacitors are critically important in advanced electronic devices and electric power systems due to their reduced weight, size and cost to meet desired applications. Nanocomposites hold strong potential for increased performance, however, the energy density of most nanocomposites is still low compared to commercial capacitors and neat polymers. Here, high energy density nanocomposite capacitors are fabricated using surface-functionalized high aspect ratio barium titanate (BaTiO3) nanowires (NWs) in a poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) (P(VDF-TrFE-CFE)) matrix. These nanocomposites have 63.5% higher dielectric permittivity compared to previous nanocomposites with BaTiO3 nanoparticles and also have high breakdown strength. At a 17.5% volume fraction, the nanocomposites show more than 145.3% increase in energy density above that of the pure P(VDF-TrFE- CFE) polymer (10.48 J/cm3 compared to 7.21 J/cm3). This value is significant and exceeds those reported for the conventional polymer-ceramic composites; it is also more than two times larger than high performance commercial materials. The findings of this research could lead to broad interest due to the potential for fabricating next generation energy storage devices.

  18. Advanced Materials Enabled by Atomic Layer Deposition for High Energy Density Rechargeable Batteries

    NASA Astrophysics Data System (ADS)

    Chen, Lin

    In order to meet the ever increasing energy needs of society and realize the US Department of Energy (DOE)'s target for energy storage, acquiring a fundamental understanding of the chemical mechanisms in batteries for direct guidance and searching novel advanced materials with high energy density are critical. To realize rechargeable batteries with superior energy density, great cathodes and excellent anodes are required. LiMn2O4 (LMO) has been considered as a simpler surrogate for high energy cathode materials like NMC. Previous studies demonstrated that Al2O3 coatings prepared by atomic layer deposition (ALD) improved the capacity of LMO cathodes. This improvement was attributed to a reduction in surface area and diminished Mn dissolution. However, here we propose a different mechanism for ALD Al 2O3 on LMO based on in-situ and ex-situ investigations coupled with density functional theory calculations. We discovered that Al2O 3 not only coats the LMO, but also dopes the LMO surface with Al leading to changes in the Mn oxidation state. Different thicknesses of Al2O 3 were deposited on nonstoichiometric LiMn2O4 for electrochemical measurements. The LMO treated with one cycle of ALD Al2O3 (1xAl 2O3 LMO) to produce a sub-monolayer coating yielded a remarkable initial capacity, 16.4% higher than its uncoated LMO counterpart in full cells. The stability of 1xAl2O3 LMO is also much better as a result of stabilized defects with Al species. Furthermore, 4xAl 2O3 LMO demonstrates remarkable capacity retention. Stoichiometric LiMn2O4 was also evaluated with similar improved performance achieved. All superior results, accomplished by great stability and reduced Mn dissolution, is thanks to the synergetic effects of Al-doping and ALD Al2O 3 coating. Turning our attention to the anode, we again utilized aluminum oxide ALD to form conformal films on lithium. We elaborately designed and studied, for the first time, the growth mechanism during Al2O3 ALD on lithium metal in

  19. Short rise time intense electron beam generator

    DOEpatents

    Olson, C.L.

    1984-03-16

    A generator for producing an intense relativisitc electron beam having a subnanosecond current rise time includes a conventional generator of intense relativistic electrons feeding into a short electrically conductive drift tube including a cavity containing a working gas at a low enough pressure to prevent the input beam from significantly ionizing the working gas. Ionizing means such as a laser simultaneously ionize the entire volume of working gas in the cavity to generate an output beam having a rise time less than one nanosecond.

  20. Short rise time intense electron beam generator

    DOEpatents

    Olson, Craig L.

    1987-01-01

    A generator for producing an intense relativistic electron beam having a subnanosecond current rise time includes a conventional generator of intense relativistic electrons feeding into a short electrically conductive drift tube including a cavity containing a working gas at a low enough pressure to prevent the input beam from significantly ionizing the working gas. Ionizing means such as a laser simultaneously ionize the entire volume of working gas in the cavity to generate an output beam having a rise time less than one nanosecond.

  1. Incoherent pair generation in a beam-beam interaction simulation

    NASA Astrophysics Data System (ADS)

    Rimbault, C.; Bambade, P.; Mönig, K.; Schulte, D.

    2006-03-01

    This paper deals with two topics: the generation of incoherent pairs in two beam-beam simulation programs, GUINEA-PIG and CAIN, and the influence of the International Linear Collider (ILC) beam parameter choices on the background in the micro vertex detector (VD) induced by direct hits. One of the processes involved in incoherent pair creation (IPC) is equivalent to a four fermions interaction and its cross section can be calculated exactly with a dedicated generator, BDK. A comparison of GUINEA-PIG and CAIN results with BDK allows to identify and quantify the uncertainties on IPC background predictions and to benchmark the GUINEA-PIG calculation. Based on this simulation and different VD designs, the five currently suggested ILC beam parameter sets have been compared regarding IPC background induced in the VD by direct IPC hits. We emphasize that the high luminosity set, as it is currently defined, would constrain both the choices of magnetic field and VD inner layer radius.

  2. Tailoring the dipole properties in dielectric polymers to realize high energy density with high breakdown strength and low dielectric loss

    NASA Astrophysics Data System (ADS)

    Thakur, Yash; Lin, Minren; Wu, Shan; Cheng, Zhaoxi; Jeong, D.-Y.; Zhang, Q. M.

    2015-03-01

    High energy density polymer materials are desirable for a broad range of modern power electronic systems. Here, we report the development of a new class of polymer dielectrics based on polyurea and polythiourea, which possess high thermal stability. By increasing the dipole density, the dielectric constant of meta-phenylene polyurea and methylene polythiourea can be increased to 5.7, compared with aromatic polyurea and aromatic polythiourea, which have a dielectric constant in the range of 4.1-4.3. The random dipoles with high dipolar moment and amorphous structure of these polyurea and polythiourea based polymers provide strong scattering to the charge carriers, resulting in low losses even at high electric fields. Consequently, this new class of polymers exhibit a linear dielectric response to the highest field measured (>700 MV/m) with a high breakdown strength, achieving high energy density (>13 J/cm3) with high efficiency (>90%).

  3. Chemical mechanistic approaches for the suppression of soot formation in the combustion of high energy density fuels. Final technical report

    SciTech Connect

    Santoro, R.J.

    1996-09-01

    Significant advantages can be gained by the use of high energy density fuels in volume limited applications. However, excessive soot formation that accompanies the combustion of these fuels presently limits their application. Fuel additive approaches prove attractive as they require minimal modifications to already existing equipment. In the present study, a variety of flame configurations were used to study the additive effects on soot formation. Through tests conducted on laminar diffusion flames carbon disulfide (CS2) and methanol (CH3OH) were found to be the most effective soot suppressants. Chemical interaction by either additive was found to far surpass the physical influences. However, the exact nature of the chemical action could not be established with the current set of experiments. Additionally, both of these additives were found to reduce soot formation in at least one high energy density fuel - quadricyclane (C7H8). To further validate this approach, studies were conducted using droplet flames and high-pressure spray flames.

  4. Tailoring the dipole properties in dielectric polymers to realize high energy density with high breakdown strength and low dielectric loss

    SciTech Connect

    Thakur, Yash; Lin, Minren; Wu, Shan; Zhang, Q. M. E-mail: qxz1@psu.edu; Cheng, Zhaoxi; Jeong, D.-Y. E-mail: qxz1@psu.edu

    2015-03-21

    High energy density polymer materials are desirable for a broad range of modern power electronic systems. Here, we report the development of a new class of polymer dielectrics based on polyurea and polythiourea, which possess high thermal stability. By increasing the dipole density, the dielectric constant of meta-phenylene polyurea and methylene polythiourea can be increased to 5.7, compared with aromatic polyurea and aromatic polythiourea, which have a dielectric constant in the range of 4.1–4.3. The random dipoles with high dipolar moment and amorphous structure of these polyurea and polythiourea based polymers provide strong scattering to the charge carriers, resulting in low losses even at high electric fields. Consequently, this new class of polymers exhibit a linear dielectric response to the highest field measured (>700 MV/m) with a high breakdown strength, achieving high energy density (>13 J/cm{sup 3}) with high efficiency (>90%)

  5. Generation of low-divergence laser beams

    DOEpatents

    Kronberg, J.W.

    1993-09-14

    Apparatus for transforming a conventional beam of coherent light, having a Gaussian energy distribution and relatively high divergence, into a beam in which the energy distribution approximates a single, non-zero-order Bessel function and which therefore has much lower divergence. The apparatus comprises a zone plate having transmitting and reflecting zones defined by the pattern of light interference produced by the combination of a beam of coherent light with a Gaussian energy distribution and one having such a Bessel distribution. The interference pattern between the two beams is a concentric array of multiple annuli, and is preferably recorded as a hologram. The hologram is then used to form the transmitting and reflecting zones by photo-etching portions of a reflecting layer deposited on a plate made of a transmitting material. A Bessel beam, containing approximately 50% of the energy of the incident beam, is produced by passing a Gaussian beam through such a Bessel zone plate. The reflected beam, also containing approximately 50% of the incident beam energy and having a Bessel energy distribution, can be redirected in the same direction and parallel to the transmitted beam. Alternatively, a filter similar to the Bessel zone plate can be placed within the resonator cavity of a conventional laser system having a front mirror and a rear mirror, preferably axially aligned with the mirrors and just inside the front mirror to generate Bessel energy distribution light beams at the laser source. 11 figures.

  6. Generation of low-divergence laser beams

    DOEpatents

    Kronberg, James W.

    1993-01-01

    Apparatus for transforming a conventional beam of coherent light, having a Gaussian energy distribution and relatively high divergence, into a beam in which the energy distribution approximates a single, non-zero-order Bessel function and which therefore has much lower divergence. The apparatus comprises a zone plate having transmitting and reflecting zones defined by the pattern of light interference produced by the combination of a beam of coherent light with a Gaussian energy distribution and one having such a Bessel distribution. The interference pattern between the two beams is a concentric array of multiple annuli, and is preferably recorded as a hologram. The hologram is then used to form the transmitting and reflecting zones by photo-etching portions of a reflecting layer deposited on a plate made of a transmitting material. A Bessel beam, containing approximately 50% of the energy of the incident beam, is produced by passing a Gaussian beam through such a Bessel zone plate. The reflected beam, also containing approximately 50% of the incident beam energy and having a Bessel energy distribution, can be redirected in the same direction and parallel to the transmitted beam. Alternatively, a filter similar to the Bessel zone plate can be placed within the resonator cavity of a conventional laser system having a front mirror and a rear mirror, preferably axially aligned with the mirrors and just inside the front mirror to generate Bessel energy distribution light beams at the laser source.

  7. Observation of a Kelvin-helmholtz instability in a high-energy-density plasma on the omega laser.

    PubMed

    Harding, E C; Hansen, J F; Hurricane, O A; Drake, R P; Robey, H F; Kuranz, C C; Remington, B A; Bono, M J; Grosskopf, M J; Gillespie, R S

    2009-07-24

    A laser initiated experiment is described in which an unstable plasma shear layer is produced by driving a blast wave along a plastic surface with sinusoidal perturbations. In response to the vorticity deposited and the shear flow established by the blast wave, the interface rolls up into large vortices characteristic of the Kelvin-Helmholtz instability. The experiment used x-ray radiography to capture the first well-resolved images of Kelvin-Helmholtz vortices in a high-energy-density plasma.

  8. Tomographic reconstruction of high-energy-density plasmas with picosecond temporal resolution.

    PubMed

    Baker, K L

    2006-03-15

    Three-dimensional reconstruction of the electron density in a plasma can be obtained by passing multiple beams at different field angles simultaneously through a plasma and performing a tomographic reconstruction of the measured field-dependent phase profiles. A relatively simple experimental setup is proposed and simulations are carried out to verify the technique. The plasma distribution is modeled as a discrete number of phase screens, and a Zernike polynomial representation of the phase screens is used to reconstruct the plasma profile.

  9. Terahertz twisted beams generation in plasma

    NASA Astrophysics Data System (ADS)

    Sobhani, Hassan; Vaziri (Khamedi), Mohammad; Rooholamininejad, Hossien; Bahrampour, Alireza

    2016-08-01

    The resonant vortex terahertz beam generation by the cross-focusing of two twisted coaxial laser beams is investigated. For the resonant excitation of terahertz radiation, the rippled density in plasma and the ripple wave number is suitably chosen to satisfy the phase matching condition. The nonlinear current density at terahertz frequency arises due to the spatial variation of two Laguerre-Gaussian coupled field. The terahertz intensity scales as the ponderomotive force of laser beams which imparts an oscillatory velocity to the electrons and, in fact, input Laguerre-Gaussian laser beams properties such as vortex charge number and beam waist. Various laser and plasma parameters are employed to yield vortex terahertz radiation with higher efficiency. Also, it is shown that when the beating frequency approaches plasma frequency, the amplitude of THz radiation increases.

  10. Optical vortex beam generator at nanoscale level.

    PubMed

    Garoli, Denis; Zilio, Pierfrancesco; Gorodetski, Yuri; Tantussi, Francesco; De Angelis, Francesco

    2016-07-11

    Optical beams carrying orbital angular momentum (OAM) can find tremendous applications in several fields. In order to apply these particular beams in photonic integrated devices innovative optical elements have been proposed. Here we are interested in the generation of OAM-carrying beams at the nanoscale level. We design and experimentally demonstrate a plasmonic optical vortex emitter, based on a metal-insulator-metal holey plasmonic vortex lens. Our plasmonic element is shown to convert impinging circularly polarized light to an orbital angular momentum state capable of propagating to the far-field. Moreover, the emerging OAM can be externally adjusted by switching the handedness of the incident light polarization. The device has a radius of few micrometers and the OAM beam is generated from subwavelength aperture. The fabrication of integrated arrays of PVLs and the possible simultaneous emission of multiple optical vortices provide an easy way to the large-scale integration of optical vortex emitters for wide-ranging applications.

  11. Optical vortex beam generator at nanoscale level

    NASA Astrophysics Data System (ADS)

    Garoli, Denis; Zilio, Pierfrancesco; Gorodetski, Yuri; Tantussi, Francesco; de Angelis, Francesco

    2016-07-01

    Optical beams carrying orbital angular momentum (OAM) can find tremendous applications in several fields. In order to apply these particular beams in photonic integrated devices innovative optical elements have been proposed. Here we are interested in the generation of OAM-carrying beams at the nanoscale level. We design and experimentally demonstrate a plasmonic optical vortex emitter, based on a metal-insulator-metal holey plasmonic vortex lens. Our plasmonic element is shown to convert impinging circularly polarized light to an orbital angular momentum state capable of propagating to the far-field. Moreover, the emerging OAM can be externally adjusted by switching the handedness of the incident light polarization. The device has a radius of few micrometers and the OAM beam is generated from subwavelength aperture. The fabrication of integrated arrays of PVLs and the possible simultaneous emission of multiple optical vortices provide an easy way to the large-scale integration of optical vortex emitters for wide-ranging applications.

  12. Electron-beam welder circle generator

    NASA Technical Reports Server (NTRS)

    Burley, R. K.

    1980-01-01

    Generator rotates electron beam and performs other convenient functions during welding process. Device eliminates time-consuming techniques relying heavily on operator's skill. Welding speed is varied with frequency selector, and amplitudes of x- and y-axes are varied by adjusting phase shift. Both high and low-range adjustments are available, and each axis can be separately controlled. Crosshair is provided for set-up and beam alinements.

  13. Intense steady state electron beam generator

    DOEpatents

    Hershcovitch, Ady; Kovarik, Vincent J.; Prelec, Krsto

    1990-01-01

    An intense, steady state, low emittance electron beam generator is formed by operating a hollow cathode discharge plasma source at critical levels in combination with an extraction electrode and a target electrode that are operable to extract a beam of fast primary electrons from the plasma source through a negatively biased grid that is critically operated to repel bulk electrons toward the plasma source while allowing the fast primary electrons to move toward the target in the desired beam that can be successfully transported for relatively large distances, such as one or more meters away from the plasma source.

  14. Multi-Megajoule NIF: Ushering In a New Era in High Energy Density Science

    SciTech Connect

    Keane, C; Moses, E I

    2008-04-30

    This paper describes the status of the stadium-sized National Ignition Facility (NIF), the world's largest laser system and first operational multi-megajoule laser. The 192-beam NIF, located at Lawrence Livermore National Laboratory (LLNL), is 96% complete and scheduled for completion in March 2009. The NIF laser will produce nanosecond laser pulses with energies up to approximately 4 MJ in the infrared (laser wavelength = 1.053-{micro}m) and 2MJ in the ultraviolet (laser wavelength = 0.35-{micro}m). With these energies NIF will access conditions of pressure and temperature not previously available on earth, allowing it to conduct experiments in support of the nation's national security, energy, and fundamental science goals. First ignition experiments at NIF are scheduled for FY2010. This paper will provide an overview of the NIF laser and the ignition, energy, and fundamental science activities at NIF.

  15. Tomographic reconstruction of high energy density plasmas with picosecond temporal resolution

    SciTech Connect

    Baker, K L

    2005-09-20

    Three-dimensional reconstruction of the electron density in a plasma can be obtained by passing multiple beams at different field angles simultaneously through a plasma and performing a tomographic reconstruction of the measured field-dependent phase profiles. In this letter, a relatively simple experimental setup is proposed and simulations are carried out to verify the technique. The plasma distribution is modeled as a discreet number of phase screens and a Zernike polynomial representation of the phase screens is used to reconstruct the plasma profile. Using a subpicosecond laser, the complete three-dimensional electron density of the plasma can be obtained with a time resolution limited only by the transit time of the probe through the plasma.

  16. An Overview of the Los Alamos Inertial Confinement Fusion and High-Energy-Density Physics Research Programs

    SciTech Connect

    Batha, Steven H.

    2016-07-15

    The Los Alamos Inertial Confinement Fusion and Science Programs engage in a vigorous array of experiments, theory, and modeling. We use the three major High Energy Density facilities, NIF, Omega, and Z to perform experiments. These include opacity, radiation transport, hydrodynamics, ignition science, and burn experiments to aid the ICF and Science campaigns in reaching their stewardship goals. The ICF program operates two nuclear diagnostics at NIF, the neutron imaging system and the gamma reaction history instruments. Both systems are being expanded with significant capability enhancements.

  17. Characterization of spatially resolved high resolution x-ray spectrometers for high energy density physics and light source experiments.

    PubMed

    Hill, K W; Bitter, M; Delgado-Aparacio, L; Efthimion, P; Pablant, N A; Lu, J; Beiersdorfer, P; Chen, H; Magee, E

    2014-11-01

    A high resolution 1D imaging x-ray spectrometer concept comprising a spherically bent crystal and a 2D pixelated detector is being optimized for diagnostics of small sources such as high energy density physics (HEDP) and synchrotron radiation or x-ray free electron laser experiments. This instrument is used on tokamak experiments for Doppler measurements of ion temperature and plasma flow velocity profiles. Laboratory measurements demonstrate a resolving power, E/ΔE of order 10,000 and spatial resolution better than 10 μm. Initial tests of the high resolution instrument on HEDP plasmas are being performed.

  18. Characterization of spatially resolved high resolution x-ray spectrometers for high energy density physics and light source experiments

    SciTech Connect

    Hill, K. W. Bitter, M.; Delgado-Aparacio, L.; Efthimion, P.; Pablant, N. A.; Lu, J.; Beiersdorfer, P.; Chen, H.; Magee, E.

    2014-11-15

    A high resolution 1D imaging x-ray spectrometer concept comprising a spherically bent crystal and a 2D pixelated detector is being optimized for diagnostics of small sources such as high energy density physics (HEDP) and synchrotron radiation or x-ray free electron laser experiments. This instrument is used on tokamak experiments for Doppler measurements of ion temperature and plasma flow velocity profiles. Laboratory measurements demonstrate a resolving power, E/ΔE of order 10 000 and spatial resolution better than 10 μm. Initial tests of the high resolution instrument on HEDP plasmas are being performed.

  19. Generation of extreme ultraviolet vortex beams using computer generated holograms.

    PubMed

    Terhalle, Bernd; Langner, Andreas; Päivänranta, Birgit; Guzenko, Vitaliy A; David, Christian; Ekinci, Yasin

    2011-11-01

    We fabricate computer generated holograms for the generation of phase singularities at extreme ultraviolet (EUV) wavelengths using electron beam lithography and demonstrate their ability to generate optical vortices in the nonzero diffraction orders. To this end, we observe the characteristic intensity distribution of the vortex beam and verify the helical phase structure interferometrically. The presented method forms the basis for further studies on singular light fields in the EUV frequency range, i.e., in EUV interference lithography. Since the method is purely achromatic, it may also find applications in various fields of x ray optics.

  20. High energy density and extreme field physics in the transparent-overdense regime

    SciTech Connect

    Hegelich, Bjorn Manuel; Yin, Kin; Albright, Brian J; Bowers, Kevin J; Gautier, C; Huang, C; Jung, D; Letzring, S; Palaniyappan, S; Shah, R; Wu, H; Fernandez, J. C.; Dromey, B; Henig, A; Horlein, R; Kefer, D.; Tajima, T; Yan, X; Habs, D

    2011-01-31

    Conclusions of this report are: (1) high harmonics generated on solid surfaces are a very versatile source of intense coherent XUV radiation; (2) high harmonics can be used to probe and monitor the interaction of intense femtosecond laser pulses with nm-scale foil targets; (3) direct measurement of target density during relativistic interaction; (4) high harmonics generated with PW-scale short-pulse lasers could serve as unique backlighting sources for a wide range experiments; and (5) Trident can be a test bed to develop such experiments and the required instrumentation.

  1. Fabrication of bulk nanostructured permanent magnets with high energy density: challenges and approaches.

    PubMed

    Yue, Ming; Zhang, Xiangyi; Liu, J Ping

    2017-03-17

    Nanostructured permanent magnetic materials, including exchange-coupled nanocomposite permanent magnets, are considered as the next generation of high-strength magnets for future applications in energy-saving and renewable energy technologies. However, fabrication of bulk nanostructured magnets remains very challenging because conventional compaction and sintering techniques cannot be used for nanostructured bulk material processing. In this paper we review recent efforts at producing bulk nanostructured single-phase and composite magnetic materials with emphasis on grain size control, anisotropy generation and interface modification.

  2. Dancing with Energetic Nitrogen Atoms: Versatile N-Functionalization Strategies for N-Heterocyclic Frameworks in High Energy Density Materials.

    PubMed

    Yin, Ping; Zhang, Qinghua; Shreeve, Jean'ne M

    2016-01-19

    Nitrogen-rich heterocycles represent a unique class of energetic frameworks featuring high heats of formation and high nitrogen content, which have generated considerable research interest in the field of high energy density materials (HEDMs). Although traditional C-functionalization methodology of aromatic hydrocarbons has been fully established, studies on N-functionalization strategies of nitrogen-containing heterocycles still have great potential to be exploited by virtue of forming diverse N-X bonds (X = C, N, O, B, halogen, etc.), which are capable of regulating energy performance and the stability of the resulting energetic compounds. In this sense, versatile N-functionalization of N-heterocyclic frameworks offers a flexible strategy to meet the requirements of developing new-generation HEDMs. In this Account, the role of strategic N-functionalization in designing new energetic frameworks, including the formation of N-C, N-N, N-O, N-B and N-halogen bonds, is emphasized. In the family of N-functionalized HEDMs, energetic derivatives, by virtue of forming N-C bonds, are the most widely used type due to the good nucleophilic capacity of most heterocyclic backbones. Although introduction of carbon tends to decrease energetic performance, significant improvement in material sensitivity makes this strategy attractive for safety concerns. More importantly, most "explosophores" can be readily introduced into the N-C linkage, thus providing a promising route to various HEDMs. Formation of additional N-N bonds typically gives rise to higher heats of formation, implying the potential enhancement in detonation performance. In many cases, the increased hydrogen bonding interactions within N-N functionalized heterocycles also improve thermal stability accordingly. Introduction of a single N,N'-azo bridge into several azole moieties leads to an extended nitrogen chain, demonstrating a new strategy for designing high-nitrogen compounds. The strategy of N-O functionalization

  3. High-Energy-Density LCA-Coupled Structural Energetic Materials for Counter WMD Applications

    DTIC Science & Technology

    2014-04-01

    morphology , etc.) of reactants. In the case of the equivolumetric Ta+Fe2O3 powder mixtures, pre-densification results in generating Fe2O3 as the more...published in the following papers. • N.N. Thadhani and J.K. Cochran, "Energetic Materials", DTRA Basic and Applied Research Program Newsletter , V2, N3, p

  4. High energy density processing of a free form Nickel-alumina nanocomposite.

    PubMed

    Viswanathan, V; Agarwal, A; Ocelik, V; De Hosson, J T M; Sobczak, N; Seal, S

    2006-03-01

    The development of a free form bulk Nickel reinforced Alumina matrix nano composites using Air Plasma Spray and laser processing has been presented. The process consumes less time and requires further minimal machining and therefore is cost effective. The relative differences in using APS over laser processing in development of bulk metal-ceramic nanocomposites have been discussed. The process intricacies involved during processing such as material specific mandrel selection, plasma-particle interaction are highlighted. Electroless coating has been used to uniformly disperse Nickel in alumina matrix as a source material. The electroless Ni coated alumina particles are subjected to both laser processing and Air Plasma Spraying with optimized parameters. Consolidation by laser processing could not be achieved as the laser beam was reflective to Nickel. On the other hand, APS Ni-alumina nanocomposite with a cylindrical shape of 1.2" OD x 1" ID x 1.5" length has been fabricated with minimum or no surface defects. HRTEM pictures revealed the nanostructure retention thereby corroborating the fact that bulk nanostructures can be made using Air Plasma Spray. XRD analysis confirmed the phase transformation from alpha alumina to gamma alumina and oxidation of Ni to NiO. Subsequent reduction of NiO to metallic nickel using hydrogen atmosphere has also been demonstrated. Mechanical properties such as, hardness (1025 HV) and fracture toughness (5 MPa m1/2) for the nanocomposite are presented herein.

  5. A method for estimating the temperature in high energy density free electron laser experiments

    NASA Astrophysics Data System (ADS)

    Principi, Emiliano; Ferrante, Carino; Filipponi, Adriano; Bencivenga, Filippo; D'Amico, Francesco; Masciovecchio, Claudio; Di Cicco, Andrea

    2010-09-01

    Present and forthcoming free electron laser (FEL) large scale facilities deliver high fluence ultrafast soft and hard X-ray pulses able to create and probe warm dense matter (WDM). Proper diagnostic for basic physical quantities, like temperature and density, is necessary, but the short lifetime of the WDM state (few ps) makes their measurements a challenging task. In this work we propose a method to estimate the WDM temperature using the experimental information from a slow temperature pyrometric probe exploiting the properties of the heat diffusion equation. Numerical simulations show that for typical thin foil samples, a temperature measurement with 1-10 μs temporal resolution at the distance of about 300-500 μm from the beam center contains sufficient information to retrieve the initial spatial temperature distribution with sufficient accuracy providing information on the temperature reached in the WDM regime. The inversion of the experimental information is obtained by means of a Bayesian approach exploiting a Metropolis Monte Carlo numerical procedure. The model and calculations presented in this work provide the theoretical background for the development of a device for temperature diagnostics of the TIMEX end-station at the Fermi@Elettra FEL facility.

  6. Catenary nanostructures as compact Bessel beam generators

    PubMed Central

    Li, Xiong; Pu, Mingbo; Zhao, Zeyu; Ma, Xiaoliang; Jin, Jinjin; Wang, Yanqin; Gao, Ping; Luo, Xiangang

    2016-01-01

    Non-diffracting Bessel beams, including zero-order and high-order Bessel Beams which carry orbital angular momentum (OAM), enable a variety of important applications in optical micromanipulation, sub-diffraction imaging, high speed photonics/quantum communication, etc. The commonly used ways to create Bessel beams, including an axicon or a digital hologram written to a spatial light modulator (SLM), have great challenges to operate at the nanoscale. Here we theoretically design and experimentally demonstrate one kind of planar Bessel beam generators based on metasurfaces with analytical structures perforated in ultra-thin metallic screens. Continuous phase modulation between 0 to 2π is realized with a single element. In addition, due to the dispersionless phase shift stemming from spin-orbit interaction, the proposed device can work in a wide wavelength range. The results may find applications in future optical communication, nanofabrication and super-resolution imaging, etc. PMID:26843142

  7. Catenary nanostructures as compact Bessel beam generators.

    PubMed

    Li, Xiong; Pu, Mingbo; Zhao, Zeyu; Ma, Xiaoliang; Jin, Jinjin; Wang, Yanqin; Gao, Ping; Luo, Xiangang

    2016-02-04

    Non-diffracting Bessel beams, including zero-order and high-order Bessel Beams which carry orbital angular momentum (OAM), enable a variety of important applications in optical micromanipulation, sub-diffraction imaging, high speed photonics/quantum communication, etc. The commonly used ways to create Bessel beams, including an axicon or a digital hologram written to a spatial light modulator (SLM), have great challenges to operate at the nanoscale. Here we theoretically design and experimentally demonstrate one kind of planar Bessel beam generators based on metasurfaces with analytical structures perforated in ultra-thin metallic screens. Continuous phase modulation between 0 to 2π is realized with a single element. In addition, due to the dispersionless phase shift stemming from spin-orbit interaction, the proposed device can work in a wide wavelength range. The results may find applications in future optical communication, nanofabrication and super-resolution imaging, etc.

  8. Toward High-Energy-Density, High-Efficiency, and Moderate-Temperature Chip-Scale Thermophotovoltaics

    DTIC Science & Technology

    2013-04-02

    to simplify the test and character- ization. Thermal energy generated from chemical reaction inside the reactor heats up the Si and is consequently...for μTPV and TPV systems in general. As we shall see below, high-temperature material stability and reactivity of the Si reactor prompt the use of a Si...based photonic crystal thermal emitter. Experimental Results for Two Silicon Reactor Designs The theoretical formalism developed can accurately

  9. Holographic generation of highly twisted electron beams.

    PubMed

    Grillo, Vincenzo; Gazzadi, Gian Carlo; Mafakheri, Erfan; Frabboni, Stefano; Karimi, Ebrahim; Boyd, Robert W

    2015-01-23

    Free electrons can possess an intrinsic orbital angular momentum, similar to those in an electron cloud, upon free-space propagation. The wave front corresponding to the electron's wave function forms a helical structure with a number of twists given by the angular speed. Beams with a high number of twists are of particular interest because they carry a high magnetic moment about the propagation axis. Among several different techniques, electron holography seems to be a promising approach to shape a conventional electron beam into a helical form with large values of angular momentum. Here, we propose and manufacture a nanofabricated phase hologram for generating a beam of this kind with an orbital angular momentum up to 200ℏ. Based on a novel technique the value of orbital angular momentum of the generated beam is measured and then compared with simulations. Our work, apart from the technological achievements, may lead to a way of generating electron beams with a high quanta of magnetic moment along the propagation direction and, thus, may be used in the study of the magnetic properties of materials and for manipulating nanoparticles.

  10. Tuning Phase Composition of Polymer Nanocomposites toward High Energy Density and High Discharge Efficiency by Nonequilibrium Processing.

    PubMed

    Jiang, Jianyong; Zhang, Xin; Dan, Zhenkang; Ma, Jing; Lin, Yuanhua; Li, Ming; Nan, Ce-Wen; Shen, Yang

    2017-09-06

    Polymer nanocomposite dielectrics with high energy density and low loss are major enablers for a number of applications in modern electronic and electrical industry. Conventional fabrication of nanocomposites by solution routes involves equilibrium process, which is slow and results in structural imperfections, hence high leakage current and compromised reliability of the nanocomposites. We propose and demonstrate that a nonequilibrium process, which synergistically integrates electrospinning, hot-pressing and thermal quenching, is capable of yielding nanocomposites of very high quality. In the nonequilibrium nanocomposites of poly(vinylidene fluoride-co-hexafluoropropylene) (P(VDF-HFP)) and BaTiO3 nanoparticles (BTO_nps), an ultrahigh Weibull modulus β of ∼30 is achieved, which is comparable to the quality of the bench-mark biaxially oriented polypropylene (BOPP) fabricated with melt-extrusion process by much more sophisticated and expensive industrial apparatus. Favorable phase composition and small crystalline size are also induced by the nonequilibrium process, which leads to concomitant enhancement of electric displacement and breakdown strength of the nanocomposite hence a high energy density of ∼21 J/cm(3). Study on the polarization behavior and phase transformation at high electric field indicates that BTO_nps could facilitate the phase transformation from α- to β-polymorph at low electric field.

  11. Nanostructured Electrode Materials Derived from Metal-Organic Framework Xerogels for High-Energy-Density Asymmetric Supercapacitor.

    PubMed

    Mahmood, Asif; Zou, Ruqiang; Wang, Qingfei; Xia, Wei; Tabassum, Hassina; Qiu, Bin; Zhao, Ruo

    2016-01-27

    This work successfully demonstrates metal-organic framework (MOF) derived strategy to prepare nanoporous carbon (NPC) with or without Fe3O4/Fe nanoparticles by the optimization of calcination temperature as highly active electrode materials for asymmetric supercapacitors (ASC). The nanostructured Fe3O4/Fe/C hybrid shows high specific capacitance of 600 F/g at a current density of 1 A/g and excellent capacitance retention up to 500 F/g at 8 A/g. Furthermore, hierarchically NPC with high surface area also obtained from MOF gels displays excellent electrochemical performance of 272 F/g at 2 mV/s. Considering practical applications, aqueous ASC (aASC) was also assembled, which shows high energy density of 17.496 Wh/kg at the power density of 388.8 W/kg. The high energy density and excellent capacity retention of the developed materials show great promise for the practical utilization of these energy storage devices.

  12. Infrared-actuated recovery of polyurethane filled by reduced graphene oxide/carbon nanotube hybrids with high energy density.

    PubMed

    Feng, Yiyu; Qin, Mengmeng; Guo, Haiqiang; Yoshino, Katsumi; Feng, Wei

    2013-11-13

    Optically actuated shape recovery materials receive much interest because of their great ability to control the creation of mechanical motion remotely and precisely. An infrared (IR) triggered actuator based on shape recovery was fabricated using polyurethane (TPU) incorporated by sulfonated reduced graphene oxide (SRGO)/sulfonated carbon nanotube (SCNT) hybrid nanofillers. Interconnected SRGO/SCNT hybrid nanofillers at a low weight loading of 1% dispersed in TPU showed good IR absorption and improved the crystallization of soft segments for a large shape deformation. The output force, energy density and recovery time of IR-triggered actuators were dependent on weight ratios of SRGO to SCNT (SRGO:SCNT). TPU nanocomposites filled by a hybrid nanofiller with SRGO:SCNT of 3:1 showed the maximum IR-actuated stress recovery of lifting a 107.6 g weight up 4.7 cm in 18 s. The stress recovery delivered a high energy density of 0.63 J/g and shape recovery force up to 1.2 MPa due to high thermal conductivity (1.473 W/mK) and Young's modulus of 23.4 MPa. Results indicate that a trade-off between the stiffness and efficient heat transfer controlled by synergistic effect between SRGO and SCNT is critical for high mechanical power output of IR-triggered actuators. IR-actuated shape recovery of SRGO/SCNT/TPU nanocomposites combining high energy density and output forces can be further developed for advanced optomechanical systems.

  13. Graphene-wrapped sulfur nanospheres with ultra-high sulfur loading for high energy density lithium-sulfur batteries

    NASA Astrophysics Data System (ADS)

    Liu, Ya; Guo, Jinxin; Zhang, Jun; Su, Qingmei; Du, Gaohui

    2015-01-01

    Lithium-sulfur (Li-S) battery with high theoretical energy density is one of the most promising energy storage systems for electric vehicles and intermittent renewable energy. However, due to the poor conductivity of the active material, considerable weight of the electrode is occupied by the conductive additives. Here we report a graphene-wrapped sulfur nanospheres composite (S-nanosphere@G) with sulfur content up to 91 wt% as the high energy density cathode material for Li-S battery. The sulfur nanospheres with diameter of 400-500 nm are synthesized through a solution-based approach with the existence of polyvinylpyrrolidone (PVP). Then the sulfur nanospheres are uniformly wrapped by conductive graphene sheets through the electrostatic interaction between graphene oxide and PVP, followed by reducing of graphene oxide with hydrazine. The design of graphene wrapped sulfur nanoarchitecture provides flexible conductive graphene coating with void space to accommodate the volume expansion of sulfur and to minimize polysulfide dissolution. As a result, the S-nanosphere@G nanocomposite with 91 wt% sulfur shows a reversible initial capacity of 970 mA h g-1 and an average columbic efficiency > 96% over 100 cycles at a rate of 0.2 C. Taking the total mass of electrode into account, the S-nanosphere@G composite is a promising cathode material for high energy density Li-S batteries.

  14. Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries

    PubMed Central

    Li, Wangda; Dolocan, Andrei; Oh, Pilgun; Celio, Hugo; Park, Suhyeon; Cho, Jaephil; Manthiram, Arumugam

    2017-01-01

    Undesired electrode–electrolyte interactions prevent the use of many high-energy-density cathode materials in practical lithium-ion batteries. Efforts to address their limited service life have predominantly focused on the active electrode materials and electrolytes. Here an advanced three-dimensional chemical and imaging analysis on a model material, the nickel-rich layered lithium transition-metal oxide, reveals the dynamic behaviour of cathode interphases driven by conductive carbon additives (carbon black) in a common nonaqueous electrolyte. Region-of-interest sensitive secondary-ion mass spectrometry shows that a cathode-electrolyte interphase, initially formed on carbon black with no electrochemical bias applied, readily passivates the cathode particles through mutual exchange of surface species. By tuning the interphase thickness, we demonstrate its robustness in suppressing the deterioration of the electrode/electrolyte interface during high-voltage cell operation. Our results provide insights on the formation and evolution of cathode interphases, facilitating development of in situ surface protection on high-energy-density cathode materials in lithium-based batteries. PMID:28443608

  15. Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Li, Wangda; Dolocan, Andrei; Oh, Pilgun; Celio, Hugo; Park, Suhyeon; Cho, Jaephil; Manthiram, Arumugam

    2017-04-01

    Undesired electrode-electrolyte interactions prevent the use of many high-energy-density cathode materials in practical lithium-ion batteries. Efforts to address their limited service life have predominantly focused on the active electrode materials and electrolytes. Here an advanced three-dimensional chemical and imaging analysis on a model material, the nickel-rich layered lithium transition-metal oxide, reveals the dynamic behaviour of cathode interphases driven by conductive carbon additives (carbon black) in a common nonaqueous electrolyte. Region-of-interest sensitive secondary-ion mass spectrometry shows that a cathode-electrolyte interphase, initially formed on carbon black with no electrochemical bias applied, readily passivates the cathode particles through mutual exchange of surface species. By tuning the interphase thickness, we demonstrate its robustness in suppressing the deterioration of the electrode/electrolyte interface during high-voltage cell operation. Our results provide insights on the formation and evolution of cathode interphases, facilitating development of in situ surface protection on high-energy-density cathode materials in lithium-based batteries.

  16. Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries

    DOE PAGES

    Li, Wangda; Dolocan, Andrei; Oh, Pilgun; ...

    2017-04-26

    Undesired electrode–electrolyte interactions prevent the use of many high-energy-density cathode materials in practical lithium-ion batteries. Efforts to address their limited service life have predominantly focused on the active electrode materials and electrolytes. Here an advanced three-dimensional chemical and imaging analysis on a model material, the nickel-rich layered lithium transition-metal oxide, reveals the dynamic behaviour of cathode interphases driven by conductive carbon additives (carbon black) in a common nonaqueous electrolyte. Region-of-interest sensitive secondary-ion mass spectrometry shows that a cathode-electrolyte interphase, initially formed on carbon black with no electrochemical bias applied, readily passivates the cathode particles through mutual exchange of surface species.more » By tuning the interphase thickness, we demonstrate its robustness in suppressing the deterioration of the electrode/electrolyte interface during high-voltage cell operation. Finally, our results provide insights on the formation and evolution of cathode interphases, facilitating development of in situ surface protection on high-energy-density cathode materials in lithium-based batteries.« less

  17. High energy density and breakdown strength from β and γ phases in poly(vinylidene fluoride-co-bromotrifluoroethylene) copolymers.

    PubMed

    Gadinski, Matthew R; Han, Kuo; Li, Qi; Zhang, Guangzu; Reainthippayasakul, Wuttiichai; Wang, Qing

    2014-11-12

    Poly(vinylidene fluoride) PVDF-based copolymers represent the state of the art dielectric polymers for high energy density capacitors. Past work on these copolymers has been done with limited emphasis on the effects of copolymer composition and with a limited range of defect monomers, focusing primarily on the commercially available poly(vinylidene fluoride-co-chlorotrifluoroethylene), P(VDF-CTFE), and poly(vinylidene fluoride-co-hexafluoropropylene), P(VDF-HFP), and the processing thereof. To expand on this area of research, copolymers of VDF and bromotrifluoroethylene (BTFE) were synthesized examining the composition range where uniaxial stretching was possible. It is found that P(VDF-BTFE) copolymers with small BTFE contents (< 2 mol %) stabilize the γ phase, compared to P(VDF-CTFE)s and P(VDF-HFP)s that are largely α phase in composition. Furthermore, different from P(VDF-CTFE)s and P(VDF-HFP)s, whose energy storage capabilities depend on the reversibility of the α to β phases transformation, high discharged energy densities (i.e., 20.8 J/cm(3) at 716 MV/m) are also achievable through the β and γ phases in P(VDF-BTFE)s without significantly reducing crystallinity and breakdown strength. This study demonstrates new avenues to the development of high energy density ferroelectric copolymers via manipulation of the γ phase through variation of the structure and content of comonomers.

  18. Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries.

    PubMed

    Li, Wangda; Dolocan, Andrei; Oh, Pilgun; Celio, Hugo; Park, Suhyeon; Cho, Jaephil; Manthiram, Arumugam

    2017-04-26

    Undesired electrode-electrolyte interactions prevent the use of many high-energy-density cathode materials in practical lithium-ion batteries. Efforts to address their limited service life have predominantly focused on the active electrode materials and electrolytes. Here an advanced three-dimensional chemical and imaging analysis on a model material, the nickel-rich layered lithium transition-metal oxide, reveals the dynamic behaviour of cathode interphases driven by conductive carbon additives (carbon black) in a common nonaqueous electrolyte. Region-of-interest sensitive secondary-ion mass spectrometry shows that a cathode-electrolyte interphase, initially formed on carbon black with no electrochemical bias applied, readily passivates the cathode particles through mutual exchange of surface species. By tuning the interphase thickness, we demonstrate its robustness in suppressing the deterioration of the electrode/electrolyte interface during high-voltage cell operation. Our results provide insights on the formation and evolution of cathode interphases, facilitating development of in situ surface protection on high-energy-density cathode materials in lithium-based batteries.

  19. A Low Cost Neutral Zinc-Iron Flow Battery with High Energy Density for Stationary Energy Storage.

    PubMed

    Li, Xianfeng; Xie, Congxin; Duan, Yinqi; Xu, Wenbin; Zhang, Huamin

    2017-10-05

    Flow battery (FB) is one of the most promising stationary energy storage devices for storing renewable energies. However, commercial progress of the FBs is limited by their high cost and low energy density. Here we report a neutral zinc-iron FB with very low cost and high energy density. By using highly soluble FeCl2/ZnBr2 species, a charge energy density of 56.30 Wh/L can be achieved. DFT calculations demonstrated that glycine can combine with iron to suppress hydrolysis and crossover of Fe3+/Fe2+. The results indicated that an energy efficiency of 86.66% can be obtained at 40 mA/cm2 and the battery can run stably for more than 100 cycles. Furthermore, a porous membrane with low cost was employed to lower the capital cost to less than 50 $/kWh, which was the lowest value that has ever been reported. Combining the features of low cost, high energy density and high energy efficiency, the neutral zinc-iron FB becomes a promising candidate for stationary energy storage applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. A low cost, high energy density and long cycle life potassium-sulfur battery for grid-scale energy storage

    SciTech Connect

    Lu, Xiaochuan; Bowden, Mark E.; Sprenkle, Vincent L.; Liu, Jun

    2015-08-15

    Alkali metal-sulfur batteries are attractive for energy storage applications because of their high energy density. Among the batteries, lithium-sulfur batteries typically use liquid in the battery electrolyte, which causes problems in both performance and safety. Sodium-sulfur batteries can use a solid electrolyte such as beta alumina but this requires a high operating temperature. Here we report a novel potassium-sulfur battery with K+-conducting beta-alumina as the electrolyte. Our studies indicate that liquid potassium exhibits much better wettability on the surface of beta-alumina compared to liquid sodium at lower temperatures. Based on this observation, we develop a potassium-sulfur battery that can operate at as low as 150°C with excellent performance. In particular, the battery shows excellent cycle life with negligible capacity fade in 1000 cycles because of the dense ceramic membrane. This study demonstrates a new battery with a high energy density, long cycle life, low cost and high safety, which is ideal for grid-scale energy storage.

  1. Ion beams from laser-generated plasmas

    NASA Technical Reports Server (NTRS)

    Hughes, R. H.; Anderson, R. J.; Gray, L. G.; Rosenfeld, J. P.; Manka, C. K.; Carruth, M. R.

    1980-01-01

    The paper describes the space-charge-limited beams produced by the plasma blowoffs generated by 20-MW bursts of 1.06-micron radiation from an active Q-switched Nd:YAG laser. Laser power densities near 10 to the 11th/sq cm on solid targets generate thermalized plasma plumes which drift to a 15-kV gridded extraction gap where the ions are extracted, accelerated, and electrostatically focused; the spatially defined ion beams are then magnetically analyzed to determine the charge state content in the beams formed from carbon, aluminum, copper, and lead targets. This technique preserves time-of-flight (TOF) information in the plasma drift region, which permits plasma ion temperatures and mass flow velocities to be determined from the Maxwellian ion curve TOF shapes for the individual charge species.

  2. Development of x-ray radiography for high energy density physics

    SciTech Connect

    Morace, A.; Fedeli, L.; Batani, D.; Hulin, S.; Margarit, A.; Nicolai, P.; Vaisseau, X.; Volpe, L.; Santos, J. J.; Baton, S.; Nakatsutsumi, M.; Beg, F. N.; Jarrott, L. C.; Nakai, M.; Piovella, N.; Wei, M. S.

    2014-10-15

    We describe an experiment performed at the LULI laser facility using an advanced radiographic technique that allowed obtaining 2D, spatially resolved images of a shocked buried-code-target. The technique is suitable for applications on Fast Ignition as well as Warm Dense Matter research. In our experiment, it allowed to show cone survival up to Mbar pressures and to measure the shock front velocity and the fluid velocity associated to the laser-generated shock. This allowed obtaining one point on the shock polar of porous carbon.

  3. Development of high energy density fuels from mild gasification of coal. Final report

    SciTech Connect

    Not Available

    1991-12-01

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily ``skimmed`` from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  4. Development of high energy density fuels from mild gasification of coal

    SciTech Connect

    Greene, Marvin

    1991-12-01

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily skimmed'' from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  5. Hierarchical columnar silicon anode structures for high energy density lithium sulfur batteries

    NASA Astrophysics Data System (ADS)

    Piwko, Markus; Kuntze, Thomas; Winkler, Sebastian; Straach, Steffen; Härtel, Paul; Althues, Holger; Kaskel, Stefan

    2017-05-01

    Silicon is a promising anode material for next generation lithium secondary batteries. To significantly increase the energy density of state of the art batteries with silicon, new concepts have to be developed and electrode structuring will become a key technology. Structuring is essential to reduce the macroscopic and microscopic electrode deformation, caused by the volume change during cycling. We report pulsed laser structuring for the generation of hierarchical columnar silicon films with outstanding high areal capacities up to 7.5 mAh cm-2 and good capacity retention. Unstructured columnar electrodes form a micron-sized block structure during the first cycle to compensate the volume expansion leading to macroscopic electrode deformation. At increased silicon loading, without additional structuring, pronounced distortion and the formation of cracks through the current collector causes cell failure. Pulsed laser ablation instead is demonstrated to avoid macroscopic electrode deformation by initial formation of the block structure. A full cell with lithiated silicon versus a carbon-sulfur cathode is assembled with only 15% overbalanced anode and low electrolyte amount (8 μl mgsulfur-1). While the capacity retention over 50 cycles is identical to a cell with high excess lithium anode, the volumetric energy density could be increased by 30%.

  6. Design factors for a super high energy density Ni-MH battery for military uses

    SciTech Connect

    Brown, J.T.; Klein, M.G.

    1997-12-01

    The nickel-metal hydride battery is a relatively new commercial product which meets the needs for a more environmentally friendly battery than either the lead-acid or nickel-cadmium couples. While the presently available product also provides significantly improved performance over these other batteries, it is believed possible to develop a new generation of Ni-MH batteries with perhaps 80% greater density by using improved hydrogen storage alloys with the capability to store up to 2% by weight hydrogen, improved nickel electrodes which can stably cycle with an electron transfer of greater than 1.5 per nickel atom, and utilizing improved new cell and battery packaging designs which minimize inactive battery weight and volume. This could raise the energy density of today`s commercial product (55--70 Wh/kg) to greater than 120 Wh/kg.

  7. High-energy density nonaqueous all redox flow lithium battery enabled with a polymeric membrane.

    PubMed

    Jia, Chuankun; Pan, Feng; Zhu, Yun Guang; Huang, Qizhao; Lu, Li; Wang, Qing

    2015-11-01

    Redox flow batteries (RFBs) are considered one of the most promising large-scale energy storage technologies. However, conventional RFBs suffer from low energy density due to the low solubility of the active materials in electrolyte. On the basis of the redox targeting reactions of battery materials, the redox flow lithium battery (RFLB) demonstrated in this report presents a disruptive approach to drastically enhancing the energy density of flow batteries. With LiFePO4 and TiO2 as the cathodic and anodic Li storage materials, respectively, the tank energy density of RFLB could reach ~500 watt-hours per liter (50% porosity), which is 10 times higher than that of a vanadium redox flow battery. The cell exhibits good electrochemical performance under a prolonged cycling test. Our prototype RFLB full cell paves the way toward the development of a new generation of flow batteries for large-scale energy storage.

  8. Impact of the Hall effect on high-energy-density plasma jets.

    PubMed

    Gourdain, P-A; Seyler, C E

    2013-01-04

    Using a 1-MA, 100 ns-rise-time pulsed power generator, radial foil configurations can produce strongly collimated plasma jets. The resulting jets have electron densities on the order of 10(20) cm(-3), temperatures above 50 eV and plasma velocities on the order of 100 km/s, giving Reynolds numbers of the order of 10(3), magnetic Reynolds and Péclet numbers on the order of 1. While Hall physics does not dominate jet dynamics due to the large particle density and flow inside, it strongly impacts flows in the jet periphery where plasma density is low. As a result, Hall physics affects indirectly the geometrical shape of the jet and its density profile. The comparison between experiments and numerical simulations demonstrates that the Hall term enhances the jet density when the plasma current flows away from the jet compared to the case where the plasma current flows towards it.

  9. Laser-Driven Magnetic-Flux Compression in High-Energy-Density Plasmas

    SciTech Connect

    Gotchev, O.V.; Chang, P.Y.; Knauer, J.P.; Meyerhofer, D.D.; Polomarov, O.; Frenje, J.; Li, C.K.; Manuel, M.J.-E.; Petrasso, R.D.; Rygg, J.R.; Seguin, F.H.; Betti, R.

    2009-12-08

    The demonstration of magnetic field compression to many tens of megagauss in cylindrical implosions of inertial confinement fusion targets is reported for the first time. The OMEGA laser [T.R. Boehly et al., Opt. Commun. 133, 495 (1997)] was used to implode cylindrical CH targets filled with deuterium gas and seeded with a strong external field (>50 kG) from a specially developed magnetic pulse generator. This seed field was trapped (frozen) in the shock-heated gas fill and compressed by the imploding shell at a high implosion velocity, minimizing the effect of resistive flux diffusion. The magnetic fields in the compressed core were probed via proton deflectrometry using the fusion products from an imploding D3He target. Line-averaged magnetic fields between 30 and 40 MG were observed.

  10. Laser-Driven Magnetic-Flux Compression in High-Energy-Density Plasmas

    SciTech Connect

    Gotchev, O. V.; Polomarov, O.; Chang, P. Y.; Knauer, J. P.; Meyerhofer, D. D.; Betti, R.; Frenje, J.; Li, C. K.; Manuel, M. J.-E.; Petrasso, R. D.; Seguin, F. H.; Rygg, J. R.

    2009-11-20

    The demonstration of magnetic field compression to many tens of megagauss in cylindrical implosions of inertial confinement fusion targets is reported for the first time. The OMEGA laser [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)] was used to implode cylindrical CH targets filled with deuterium gas and seeded with a strong external field (>50 kG) from a specially developed magnetic pulse generator. This seed field was trapped (frozen) in the shock-heated gas fill and compressed by the imploding shell at a high implosion velocity, minimizing the effect of resistive flux diffusion. The magnetic fields in the compressed core were probed via proton deflectrometry using the fusion products from an imploding D{sub 3}He target. Line-averaged magnetic fields between 30 and 40 MG were observed.

  11. Laser-driven magnetic-flux compression in high-energy-density plasmas.

    PubMed

    Gotchev, O V; Chang, P Y; Knauer, J P; Meyerhofer, D D; Polomarov, O; Frenje, J; Li, C K; Manuel, M J-E; Petrasso, R D; Rygg, J R; Séguin, F H; Betti, R

    2009-11-20

    The demonstration of magnetic field compression to many tens of megagauss in cylindrical implosions of inertial confinement fusion targets is reported for the first time. The OMEGA laser [T. R. Boehly, Opt. Commun. 133, 495 (1997)10.1016/S0030-4018(96)00325-2] was used to implode cylindrical CH targets filled with deuterium gas and seeded with a strong external field (>50 kG) from a specially developed magnetic pulse generator. This seed field was trapped (frozen) in the shock-heated gas fill and compressed by the imploding shell at a high implosion velocity, minimizing the effect of resistive flux diffusion. The magnetic fields in the compressed core were probed via proton deflectrometry using the fusion products from an imploding D3He target. Line-averaged magnetic fields between 30 and 40 MG were observed.

  12. Integrated modelling framework for short pulse high energy density physics experiments

    NASA Astrophysics Data System (ADS)

    Sircombe, N. J.; Hughes, S. J.; Ramsay, M. G.

    2016-03-01

    Modelling experimental campaigns on the Orion laser at AWE, and developing a viable point-design for fast ignition (FI), calls for a multi-scale approach; a complete description of the problem would require an extensive range of physics which cannot realistically be included in a single code. For modelling the laser-plasma interaction (LPI) we need a fine mesh which can capture the dispersion of electromagnetic waves, and a kinetic model for each plasma species. In the dense material of the bulk target, away from the LPI region, collisional physics dominates. The transport of hot particles generated by the action of the laser is dependent on their slowing and stopping in the dense material and their need to draw a return current. These effects will heat the target, which in turn influences transport. On longer timescales, the hydrodynamic response of the target will begin to play a role as the pressure generated from isochoric heating begins to take effect. Recent effort at AWE [1] has focussed on the development of an integrated code suite based on: the particle in cell code EPOCH, to model LPI; the Monte-Carlo electron transport code THOR, to model the onward transport of hot electrons; and the radiation hydrodynamics code CORVUS, to model the hydrodynamic response of the target. We outline the methodology adopted, elucidate on the advantages of a robustly integrated code suite compared to a single code approach, demonstrate the integrated code suite's application to modelling the heating of buried layers on Orion, and assess the potential of such experiments for the validation of modelling capability in advance of more ambitious HEDP experiments, as a step towards a predictive modelling capability for FI.

  13. Pie-like electrode design for high-energy density lithium–sulfur batteries

    PubMed Central

    Li, Zhen; Zhang, Jin Tao; Chen, Yu Ming; Li, Ju; Lou, Xiong Wen (David)

    2015-01-01

    Owing to the overwhelming advantage in energy density, lithium–sulfur (Li–S) battery is a promising next-generation electrochemical energy storage system. Despite many efforts in pursuing long cycle life, relatively little emphasis has been placed on increasing the areal energy density. Herein, we have designed and developed a ‘pie' structured electrode, which provides an excellent balance between gravimetric and areal energy densities. Combining lotus root-like multichannel carbon nanofibers ‘filling' and amino-functionalized graphene ‘crust', the free-standing paper electrode (S mass loading: 3.6 mg cm−2) delivers high specific capacity of 1,314 mAh g−1 (4.7 mAh cm−2) at 0.1 C (0.6 mA cm−2) accompanied with good cycling stability. Moreover, the areal capacity can be further boosted to more than 8 mAh cm−2 by stacking three layers of paper electrodes with S mass loading of 10.8 mg cm−2. PMID:26608228

  14. High energy density capacitors for vacuum operation with a pulsed plasma load

    NASA Technical Reports Server (NTRS)

    Guman, W. J.

    1976-01-01

    Results of the effort of designing, fabricating, and testing of a 40 joules/lb (88.2 joules/Kg) high voltage energy storage capacitor suitable for operating a pulsed plasma thruster in a vacuum environment for millions of pulses are presented. Using vacuum brazing and heli-arc welding techniques followed by vacuum and high pressure helium leak tests it was possible to produce a hermetically sealed relatively light weight enclosure for the dielectric system. An energy density of 40 joules/lb was realized with a KF-polyvinylidene fluoride dielectric system. One capacitor was D.C. life tested at 4 KV (107.8 joules/lb) for 2,000 hours before it failed. Another exceeded 2,670 hours without failure at 38.3 joules/lb. Pulse life testing in a vacuum exceeded 300,000 discharges with testing still in progress. The D.C. life test data shows a small decrease in capacitance and an increase in dissipation factor with time. Heat transfer from the load to the capacitor must also be considered besides the self-heat generated by the capacitor.

  15. Pie-like electrode design for high-energy density lithium-sulfur batteries

    NASA Astrophysics Data System (ADS)

    Li, Zhen; Zhang, Jin Tao; Chen, Yu Ming; Li, Ju; Lou, Xiong Wen (David)

    2015-11-01

    Owing to the overwhelming advantage in energy density, lithium-sulfur (Li-S) battery is a promising next-generation electrochemical energy storage system. Despite many efforts in pursuing long cycle life, relatively little emphasis has been placed on increasing the areal energy density. Herein, we have designed and developed a `pie' structured electrode, which provides an excellent balance between gravimetric and areal energy densities. Combining lotus root-like multichannel carbon nanofibers `filling' and amino-functionalized graphene `crust', the free-standing paper electrode (S mass loading: 3.6 mg cm-2) delivers high specific capacity of 1,314 mAh g-1 (4.7 mAh cm-2) at 0.1 C (0.6 mA cm-2) accompanied with good cycling stability. Moreover, the areal capacity can be further boosted to more than 8 mAh cm-2 by stacking three layers of paper electrodes with S mass loading of 10.8 mg cm-2.

  16. Pie-like electrode design for high-energy density lithium-sulfur batteries.

    PubMed

    Li, Zhen; Zhang, Jin Tao; Chen, Yu Ming; Li, Ju; Lou, Xiong Wen David

    2015-11-26

    Owing to the overwhelming advantage in energy density, lithium-sulfur (Li-S) battery is a promising next-generation electrochemical energy storage system. Despite many efforts in pursuing long cycle life, relatively little emphasis has been placed on increasing the areal energy density. Herein, we have designed and developed a 'pie' structured electrode, which provides an excellent balance between gravimetric and areal energy densities. Combining lotus root-like multichannel carbon nanofibers 'filling' and amino-functionalized graphene 'crust', the free-standing paper electrode (S mass loading: 3.6 mg cm(-2)) delivers high specific capacity of 1,314 mAh g(-1) (4.7 mAh cm(-2)) at 0.1 C (0.6 mA cm(-2)) accompanied with good cycling stability. Moreover, the areal capacity can be further boosted to more than 8 mAh cm(-2) by stacking three layers of paper electrodes with S mass loading of 10.8 mg cm(-2).

  17. Surface modified CFx cathode material for ultrafast discharge and high energy density

    DOE PAGES

    Dai, Yang; Zhu, Yimei; Cai, Sendan; ...

    2014-11-10

    Li/CFx primary possesses the highest energy density of 2180 W h kg⁻¹ among all primary lithium batteries. However, a key limitation for the utility of this type of battery is in its poor rate capability because the cathode material, CFx, is an intrinsically poor electronic conductor. Here, we report on our development of a controlled process of surface de-fluorination under mild hydrothermal conditions to modify the highly fluorinated CFx. The modified CFx, consisting of an in situ generated shell component of F-graphene layers, possesses good electronic conductivity and removes the transporting barrier for lithium ions, yielding a high-capacity performance andmore » an excellent rate-capability. Indeed, a capacity of 500 mA h g⁻¹ and a maximum power density of 44 800 W kg⁻¹ can be realized at the ultrafast rate of 30 C (24 A g⁻¹), which is over one order of magnitude higher than that of the state-of-the-art primary lithium-ion batteries.« less

  18. Surface modified CFx cathode material for ultrafast discharge and high energy density

    SciTech Connect

    Dai, Yang; Zhu, Yimei; Cai, Sendan; Wu, Lijun; Yang, Weijing; Xie, Jingying; Wen, Wen; Zheng, Jin-Cheng; Zheng, Yi

    2014-11-10

    Li/CFx primary possesses the highest energy density of 2180 W h kg⁻¹ among all primary lithium batteries. However, a key limitation for the utility of this type of battery is in its poor rate capability because the cathode material, CFx, is an intrinsically poor electronic conductor. Here, we report on our development of a controlled process of surface de-fluorination under mild hydrothermal conditions to modify the highly fluorinated CFx. The modified CFx, consisting of an in situ generated shell component of F-graphene layers, possesses good electronic conductivity and removes the transporting barrier for lithium ions, yielding a high-capacity performance and an excellent rate-capability. Indeed, a capacity of 500 mA h g⁻¹ and a maximum power density of 44 800 W kg⁻¹ can be realized at the ultrafast rate of 30 C (24 A g⁻¹), which is over one order of magnitude higher than that of the state-of-the-art primary lithium-ion batteries.

  19. Generation of perfect vectorial vortex beams.

    PubMed

    Li, Peng; Zhang, Yi; Liu, Sheng; Ma, Chaojie; Han, Lei; Cheng, Huachao; Zhao, Jianlin

    2016-05-15

    We propose the concept of perfect vectorial vortex beams (VVBs), which not merely have intensity profile independent of the polarization order and the topological charge of spiral phase, but also have stable intensity profile and state of polarization (SoP) upon propagation. Utilizing a Sagnac interferometer, we approximately generate perfect VVBs with locally linear and elliptical polarizations, and demonstrate that such beams can keep their intensity profile and SoP at a certain propagation distance. These proposed VVBs can be expanded to encode information and quantum cryptography, as well as to enrich the conversion of spin and orbital angular momenta.

  20. Chloroaluminate molten salt electrolytes and vanadium pentoxide xerogel cathodes for high energy density batteries

    NASA Astrophysics Data System (ADS)

    Xie, Jian

    The work presented here is part of an effort to develop a new type of battery which uses an alkali metal such as lithium or sodium or the alkaline earth magnesium, as the anode, a V2O5 xerogel as cathode, and a 1-ethyl-3-methylimidazolium chloride/aluminum chloride room temperature molten salt as electrolyte. First, the stability of the electrolyte was studied. The electrochemistry of 1-ethyl-3-methylimidazolium chloride (EMIC), the organic component of the 1-ethyl-3-methylimidazolium chloride/aluminum chloride molten salt, was examined in acetonitrile. Cyclic voltammetry and differential pulse voltammetry were used to study the reduction of EMI+, the cation of EMIC. Controlled potential coulometry was used to determine the number of electrons involved in the EMI+ reduction process. EMI+ reduction was found to be a one-electron, diffusion controlled process occurring at -2.35V (vs. a reference electrode consisting of a Ag wire in 0.1 M tetra-n-butylammonium perchlorate (TBAP)/acetonitrile solution) in 0.1M TBAP/acetonitrile solution. Two products were generated from the reduction, which are oxidized at about -0.45 and -0.65V. Mass spectroscopy data for these two products suggest that they are degradation products of EMI+. The major products of EMI+ reduction are not electrochemically active within the available potential window. Thus, small amounts of these species should not have a serious effect on the operation of a cell using an EMIC/AlCl3 electrolyte. The second project was to develop a method for buffering a melt which contains free Mg2+ ion for insertion into a V2O 5 xerogel cathode. The buffering of melts with MgCl2 and Mg metal was investigated starting with both acidic and basic melts. The following reaction is proposed for the Mg ribbon in acidic melt: 8Al2Cl - 7+3Mg→2Al+3Mg2++14AlCl -4 This was verified by electrochemical and atomic emission spectroscopy inductively coupled plasma (AES/ICP) data. Finally, the intercalation of Li+, Na+, and Mg2+ ions

  1. Acoustic source for generating an acoustic beam

    DOEpatents

    Vu, Cung Khac; Sinha, Dipen N.; Pantea, Cristian

    2016-05-31

    An acoustic source for generating an acoustic beam includes a housing; a plurality of spaced apart piezo-electric layers disposed within the housing; and a non-linear medium filling between the plurality of layers. Each of the plurality of piezoelectric layers is configured to generate an acoustic wave. The non-linear medium and the plurality of piezo-electric material layers have a matching impedance so as to enhance a transmission of the acoustic wave generated by each of plurality of layers through the remaining plurality of layers.

  2. A platform for studying the Rayleigh-Taylor and Richtmyer-Meshkov instabilities in a planar geometry at high energy density at the National Ignition Facility

    NASA Astrophysics Data System (ADS)

    Nagel, S. R.; Raman, K. S.; Huntington, C. M.; MacLaren, S. A.; Wang, P.; Barrios, M. A.; Baumann, T.; Bender, J. D.; Benedetti, L. R.; Doane, D. M.; Felker, S.; Fitzsimmons, P.; Flippo, K. A.; Holder, J. P.; Kaczala, D. N.; Perry, T. S.; Seugling, R. M.; Savage, L.; Zhou, Y.

    2017-07-01

    A new experimental platform has been developed at the National Ignition Facility (NIF) for studying the Rayleigh-Taylor (RT) and Richtmyer-Meshkov (RM) instabilities in a planar geometry at high-energy-densities. The platform uses 60 beams of the NIF laser to drive an initially solid shock tube containing a pre-machined interface between dense and light materials. The strong shock turns the initially solid target into a plasma and the material boundary into a fluid interface with the imprinted initial condition. The interface evolves by action of the RT and RM instabilities, and the growth is imaged with backlit x-ray radiography. We present our first data involving sinusoidal interface perturbations driven from the heavy side to the light side. Late-time radiographic images show the initial conditions reaching the deeply nonlinear regime, and an evolution of fine structure consistent with a transition to turbulence. We show preliminary comparisons with post-shot numerical simulations and discuss the implications for future campaigns.

  3. Investigation of the 2p3/2-3d5/2 line emission of Au53+ -- Au69+ for diagnosing high energy density plasmas

    SciTech Connect

    Brown, G V; Hansen, S B; Trabert, E; Beiersdorfer, P; Widmann, K; Chen, H; Chung, H K; Clementson, J T; Gu, M F; Thorn, D B

    2008-01-29

    Measurements of the L-shell emission of highly charged gold ions were made under controlled laboratory conditions using the SuperEBIT electron beam ion trap, allowing detailed spectral observations of lines from ironlike Au{sup 53+} through neonlike Au{sup 69+}. Using atomic data from the Flexible Atomic Code, we have identified strong 3d{sub 5/2} {yields} 2p{sub 3/2} emission features that can be used to diagnose the charge state distribution in high energy density plasmas, such as those found in the laser entrance hole of hot hohlraum radiation sources. We provide collisional-radiative calculations of the average ion charge as a function of temperature and density, which can be used to relate charge state distributions inferred from 3d{sub 5/2} {yields} 2p{sub 3/2} emission features to plasma conditions, and investigate the effects of plasma density on calculated L-shell Au emission spectra.

  4. Late-Time Mixing Sensitivity to Initial Broadband Surface Roughness in High-Energy-Density Shear Layers

    DOE PAGES

    Flippo, K. A.; Doss, F. W.; Kline, J. L.; ...

    2016-11-23

    While using a large volume high-energy-density fluid shear experiment ( 8.5 cm 3 ) at the National Ignition Facility, we have demonstrated for the first time the ability to significantly alter the evolution of a supersonic sheared mixing layer by controlling the initial conditions of that layer. Furthermore, by altering the initial surface roughness of the tracer foil, we demonstrate the ability to transition the shear mixing layer from a highly ordered system of coherent structures to a randomly ordered system with a faster growing mix layer, indicative of strong mixing in the layer at a temperature of several tensmore » of electron volts and at near solid density. Moreover, simulations using a turbulent-mix model show good agreement with the experimental results and poor agreement without turbulent mix.« less

  5. Activated carbons derived from coconut shells as high energy density cathode material for Li-ion capacitors.

    PubMed

    Jain, Akshay; Aravindan, Vanchiappan; Jayaraman, Sundaramurthy; Kumar, Palaniswamy Suresh; Balasubramanian, Rajasekhar; Ramakrishna, Seeram; Madhavi, Srinivasan; Srinivasan, M P

    2013-10-21

    In this manuscript, a dramatic increase in the energy density of ~ 69 Wh kg⁻¹ and an extraordinary cycleability ~ 2000 cycles of the Li-ion hybrid electrochemical capacitors (Li-HEC) is achieved by employing tailored activated carbon (AC) of ~ 60% mesoporosity derived from coconut shells (CS). The AC is obtained by both physical and chemical hydrothermal carbonization activation process, and compared to the commercial AC powders (CAC) in terms of the supercapacitance performance in single electrode configuration vs. Li. The Li-HEC is fabricated with commercially available Li₄Ti₅O₁₂ anode and the coconut shell derived AC as cathode in non-aqueous medium. The present research provides a new routine for the development of high energy density Li-HEC that employs a mesoporous carbonaceous electrode derived from bio-mass precursors.

  6. Late-Time Mixing Sensitivity to Initial Broadband Surface Roughness in High-Energy-Density Shear Layers

    NASA Astrophysics Data System (ADS)

    Flippo, K. A.; Doss, F. W.; Kline, J. L.; Merritt, E. C.; Capelli, D.; Cardenas, T.; DeVolder, B.; Fierro, F.; Huntington, C. M.; Kot, L.; Loomis, E. N.; MacLaren, S. A.; Murphy, T. J.; Nagel, S. R.; Perry, T. S.; Randolph, R. B.; Rivera, G.; Schmidt, D. W.

    2016-11-01

    Using a large volume high-energy-density fluid shear experiment (8.5 cm3 ) at the National Ignition Facility, we have demonstrated for the first time the ability to significantly alter the evolution of a supersonic sheared mixing layer by controlling the initial conditions of that layer. By altering the initial surface roughness of the tracer foil, we demonstrate the ability to transition the shear mixing layer from a highly ordered system of coherent structures to a randomly ordered system with a faster growing mix layer, indicative of strong mixing in the layer at a temperature of several tens of electron volts and at near solid density. Simulations using a turbulent-mix model show good agreement with the experimental results and poor agreement without turbulent mix.

  7. Activated carbons derived from coconut shells as high energy density cathode material for Li-ion capacitors

    PubMed Central

    Jain, Akshay; Aravindan, Vanchiappan; Jayaraman, Sundaramurthy; Kumar, Palaniswamy Suresh; Balasubramanian, Rajasekhar; Ramakrishna, Seeram; Madhavi, Srinivasan; Srinivasan, M. P.

    2013-01-01

    In this manuscript, a dramatic increase in the energy density of ~ 69 Wh kg−1 and an extraordinary cycleability ~ 2000 cycles of the Li-ion hybrid electrochemical capacitors (Li-HEC) is achieved by employing tailored activated carbon (AC) of ~ 60% mesoporosity derived from coconut shells (CS). The AC is obtained by both physical and chemical hydrothermal carbonization activation process, and compared to the commercial AC powders (CAC) in terms of the supercapacitance performance in single electrode configuration vs. Li. The Li-HEC is fabricated with commercially available Li4Ti5O12 anode and the coconut shell derived AC as cathode in non-aqueous medium. The present research provides a new routine for the development of high energy density Li-HEC that employs a mesoporous carbonaceous electrode derived from bio-mass precursors. PMID:24141527

  8. Morphological and Chemical Tuning of High-Energy-Density Metal Oxides for Lithium Ion Battery Electrode Applications

    DOE PAGES

    Wang, Lei; Yue, Shiyu; Zhang, Qing; ...

    2017-05-31

    We present that metal oxides represent a set of promising materials for use as electrodes within lithium ion batteries, but unfortunately, these tend to suffer from limitations associated with poor ionic and electron conductivity as well as low cycling performance. Hence, to achieve the goal of creating economical, relatively less toxic, thermally stable, and simultaneously high-energy-density electrode materials, we have put forth a number of targeted strategies, aimed at rationally improving upon electrochemical performance. Specifically, in this Perspective, we discuss the precise roles and effects of controllably varying not only (i) morphology but also (ii) chemistry as a means ofmore » advancing, ameliorating, and fundamentally tuning the development and evolution of Fe3O4, Li4Ti5O12, TiO2, and LiV3O8 as viable and ubiquitous energy storage materials.« less

  9. Activated carbons derived from coconut shells as high energy density cathode material for Li-ion capacitors

    NASA Astrophysics Data System (ADS)

    Jain, Akshay; Aravindan, Vanchiappan; Jayaraman, Sundaramurthy; Kumar, Palaniswamy Suresh; Balasubramanian, Rajasekhar; Ramakrishna, Seeram; Madhavi, Srinivasan; Srinivasan, M. P.

    2013-10-01

    In this manuscript, a dramatic increase in the energy density of ~ 69 Wh kg-1 and an extraordinary cycleability ~ 2000 cycles of the Li-ion hybrid electrochemical capacitors (Li-HEC) is achieved by employing tailored activated carbon (AC) of ~ 60% mesoporosity derived from coconut shells (CS). The AC is obtained by both physical and chemical hydrothermal carbonization activation process, and compared to the commercial AC powders (CAC) in terms of the supercapacitance performance in single electrode configuration vs. Li. The Li-HEC is fabricated with commercially available Li4Ti5O12 anode and the coconut shell derived AC as cathode in non-aqueous medium. The present research provides a new routine for the development of high energy density Li-HEC that employs a mesoporous carbonaceous electrode derived from bio-mass precursors.

  10. Talbot-Lau X-ray Deflectometer electron density diagnostic for laser and pulsed power high energy density plasma experiments

    DOE PAGES

    Valdivia, M. P.; Stutman, D.; Stoeckl, C.; ...

    2016-04-21

    Talbot-Lau X-ray Deflectometry has been developed as an electron density diagnostic for High Energy Density plasmas. The technique can deliver x-ray refraction, attenuation, elemental composition, and scatter information from a single Moiré image. An 8 keV Talbot-Lau interferometer was deployed using laser and x-pinch backlighters. Grating survival and electron density mapping was demonstrated for 25-29 J, 8-30 ps laser pulses using copper foil targets. Moire pattern formation and grating survival was also observed using a copper x-pinch driven at 400 kA, ~1 kA/ns. Lastly, these results demonstrate the potential of TXD as an electron density diagnostic for HED plasmas.

  11. Development of a long cycle life sealed nickel-zinc battery for high energy-density applications

    SciTech Connect

    Coates, D.; Ferreira, E.; Charkey, A.

    1997-12-01

    Nickel-zinc battery technology is being developed for commercial applications requiring high energy density and high power capability. Current development cells have demonstrated the ability to deliver over 60 Watt-hours per kilogram at the one hour rate and more than 450 Watts per kilogram at the 12C rate. Cycle life has been improved to more than 600 cycles at 80% depth of discharge by using a patented, reduced solubility zinc electrode and an improved sealed cell design. More than 7,000 charge/discharge cycles at 10% depth-of-discharge have been completed. Large quantities of sealed prismatic cells have been manufactured, including a 220 V battery for a hybrid electric vehicle (HEV).

  12. A broadband high-resolution elliptical crystal x-ray spectrometer for high energy density physics experiments

    SciTech Connect

    Anderson, S G; Heeter, R F; Booth, R; Emig, J; Fulkerson, S; McCarville, T; Norman, D; Young, B F

    2006-03-31

    Spectroscopic investigation of high temperature laser produced plasmas in general, and x-ray opacity experiments in particular, often requires instruments with both a broad coverage of x-ray energies and high spectral, spatial, and temporal resolution. We analyze the design, model the response, and report the commissioning of a spectrometer using elliptical crystals in conjunction with a large format, gated microchannel plate detector. Measurements taken with this instrument at the JANUS laser facilities demonstrate the designed spectral range of 0.24 to 5.8 keV, and spectral resolution E/{Delta}E > 500, resulting in 2 to 3 times more spectral data than achieved by previous spectrometer designs. The observed 100 picosecond temporal resolution and 35 {micro}m spatial resolution are consistent with the requirements of high energy density opacity experiments.

  13. Computational investigation on the new high energy density material of aluminum enriched 1, 1-diamino-2, 2-dinitroethylene.

    PubMed

    Bian, Liang; Shu, Yuanjie; Xu, Jinbao; Wang, Lei

    2013-01-01

    Aluminum enriched 1, 1-diamino-2, 2-dinitroethylene (Al-FOX-7) crystal, as a new high energy density material (HEDM), was designed and investigated using grand canonical monte carlo (GCMC), NVT+NPT-molecular dynamics (MD) and GGA-PBE-density functional theory (DFT) methods. The results show that, Al atoms break out H-bond of functional group of FOX-7 crystal, and form new Al-H and Al-O bonds. Their atomic content (x) influences the surface electronic states, friction sensitivities and cj detonation properties of Al-FOX-7 crystals. While x is 4 atoms, the crystal has the highest friction sensitivities and cj detonation temperatures, which are about 1.5 times to that of FOX-7 crystal.

  14. Talbot-Lau X-ray Deflectometer electron density diagnostic for laser and pulsed power high energy density plasma experiments

    SciTech Connect

    Valdivia, M. P.; Stutman, D.; Stoeckl, C.; Mileham, C.; Begishev, I.; Theobald, W.; Bromage, J.; Regan, S. P.; Klein, S. R.; Munoz-Cordoves, G.; Vescovi, M.; Valenzuela-Villaseca, V.; Veloso, F.

    2016-04-21

    Talbot-Lau X-ray Deflectometry has been developed as an electron density diagnostic for High Energy Density plasmas. The technique can deliver x-ray refraction, attenuation, elemental composition, and scatter information from a single Moiré image. An 8 keV Talbot-Lau interferometer was deployed using laser and x-pinch backlighters. Grating survival and electron density mapping was demonstrated for 25-29 J, 8-30 ps laser pulses using copper foil targets. Moire pattern formation and grating survival was also observed using a copper x-pinch driven at 400 kA, ~1 kA/ns. Lastly, these results demonstrate the potential of TXD as an electron density diagnostic for HED plasmas.

  15. A Web 2.0 Interface to Ion Stopping Power and Other Physics Routines for High Energy Density Physics Applications

    NASA Astrophysics Data System (ADS)

    Stoltz, Peter; Veitzer, Seth

    2008-04-01

    We present a new Web 2.0-based interface to physics routines for High Energy Density Physics applications. These routines include models for ion stopping power, sputtering, secondary electron yields and energies, impact ionization cross sections, and atomic radiated power. The Web 2.0 interface allows users to easily explore the results of the models before using the routines within other codes or to analyze experimental results. We discuss how we used various Web 2.0 tools, including the Python 2.5, Django, and the Yahoo User Interface library. Finally, we demonstrate the interface by showing as an example the stopping power algorithms researchers are currently using within the Hydra code to analyze warm, dense matter experiments underway at the Neutralized Drift Compression Experiment facility at Lawrence Berkeley National Laboratory.

  16. Late-Time Mixing Sensitivity to Initial Broadband Surface Roughness in High-Energy-Density Shear Layers

    SciTech Connect

    Flippo, K. A.; Doss, F. W.; Kline, J. L.; Merritt, E. C.; Capelli, D.; Cardenas, T.; DeVolder, B.; Fierro, F.; Huntington, C. M.; Kot, L.; Loomis, E. N.; MacLaren, S. A.; Murphy, T. J.; Nagel, S. R.; Perry, T. S.; Randolph, R. B.; Rivera, G.; Schmidt, D. W.

    2016-11-23

    Using a large volume high-energy-density fluid shear experiment (8.5 cm3) at the National Ignition Facility, we have demonstrated for the first time the ability to significantly alter the evolution of a supersonic sheared mixing layer by controlling the initial conditions of that layer. By altering the initial surface roughness of the tracer foil, we demonstrate the ability to transition the shear mixing layer from a highly ordered system of coherent structures to a randomly ordered system with a faster growing mix layer, indicative of strong mixing in the layer at a temperature of several tens of electron volts and at near solid density. Simulations using a turbulent-mix model show good agreement with the experimental results and poor agreement without turbulent mix.

  17. Publication of Proceedings for the 6th Workshop on High Energy Density and High Power RF (RF 2003)

    SciTech Connect

    Victor L. Granatstein

    2004-08-08

    The 6th Workshop on High Energy Density and High Power RF (RF 2003) was held from June 22 to June 26 at the Coolfont Resort and Conference Center in Berkeley Springs, West Virginia. The Workshop was hosted by the Institute for Research in Electronics and Applied Physics (IREAP) of the University of Maryland, College Park and by the Naval Research Laboratory, Washington DC. As its name implies this was the sixth in a series of biennial workshops devoted to exchanging information and ideas on high power microwave sources and components. The applications addressed included particle accelerators, radar, HPM, space exploration, neutron sources and plasma heating and current driven in controlled thermonuclear fusion research. This Final Report includes a brief description of the RF 2003 Workshop and the distribution of the published proceedings.

  18. Understanding the implications of the data from recent high-energy-density Kelvin-Helmholtz shear layer experiments

    SciTech Connect

    Hurricane, O A; Hansen, J F; Harding, E C; Drake, R P; Robey, H F; Remington, B A; Kuranz, C C; Grosskopf, M J; Gillespie, R S; Park, H

    2009-10-26

    The first successful high energy density Kelvin-Helmholtz (KH) shear layer experiments (O.A. Hurricane, et al., Phys. Plasmas, 16, 056305, 2009; E.C. Harding, et al., Phys. Rev. Lett., 103, 045005, 2009) demonstrated the ability to design and field a target that produces an array of large diagnosable KH vortices in a controlled fashion. Data from these experiments vividly showed the complete evolution of large distinct eddies, from formation to apparent turbulent break-up. Unexpectedly, low-density bubbles/cavities comparable to the vortex size ({approx} 300 - 400 {micro}m) appeared to grow up in the free-stream flow above the unstable material interface. In this paper, the basic principles of the experiment will be discussed, the data reviewed, and the progress on understanding the origin of the above bubble structures through theory and simulation will be reported on.

  19. Second-harmonic generation with Bessel beams

    NASA Astrophysics Data System (ADS)

    Shatrovoy, Oleg

    We present the results of a numerical simulation tool for modeling the second-harmonic generation (SHG) interaction experienced by a diffracting beam. This code is used to study the simultaneous frequency and spatial profile conversion of a truncated Bessel beam that closely resembles a higher-order mode (HOM) of an optical fiber. SHG with Bessel beams has been investigated in the past and was determined have limited value because it is less efficient than SHG with a Gaussian beam in the undepleted pump regime. This thesis considers, for the first time to the best of our knowledge, whether most of the power from a Bessel-like beam could be converted into a second-harmonic beam (full depletion), as is the case with a Gaussian beam. We study this problem because using HOMs for fiber lasers and amplifiers allows reduced optical intensities, which mitigates nonlinearities, and is one possible way to increase the available output powers of fiber laser systems. The chief disadvantage of using HOM fiber amplifiers is the spatial profile of the output, but this can be transformed as part of the SHG interaction, most notably to a quasi-Gaussian profile when the phase mismatch meets the noncollinear criteria. We predict, based on numerical simulation, that noncollinear SHG (NC-SHG) can simultaneously perform highly efficient (90%) wavelength conversion from 1064 nm to 532 nm, as well as concurrent mode transformation from a truncated Bessel beam to a Gaussian-like beam (94% overlap with a Gaussian) at modest input powers (250 W, peak power or continuous-wave operation). These simulated results reveal two attractive features -- the feasibility of efficiently converting HOMs of fibers into Gaussian-like beams, and the ability to simultaneously perform frequency conversion. Combining the high powers that are possible with HOM fiber amplifiers with access to non-traditional wavelengths may offer significant advantages over the state of the art for many important applications

  20. Optical vortex beam generator at nanoscale level

    PubMed Central

    Garoli, Denis; Zilio, Pierfrancesco; Gorodetski, Yuri; Tantussi, Francesco; De Angelis, Francesco

    2016-01-01

    Optical beams carrying orbital angular momentum (OAM) can find tremendous applications in several fields. In order to apply these particular beams in photonic integrated devices innovative optical elements have been proposed. Here we are interested in the generation of OAM-carrying beams at the nanoscale level. We design and experimentally demonstrate a plasmonic optical vortex emitter, based on a metal-insulator-metal holey plasmonic vortex lens. Our plasmonic element is shown to convert impinging circularly polarized light to an orbital angular momentum state capable of propagating to the far-field. Moreover, the emerging OAM can be externally adjusted by switching the handedness of the incident light polarization. The device has a radius of few micrometers and the OAM beam is generated from subwavelength aperture. The fabrication of integrated arrays of PVLs and the possible simultaneous emission of multiple optical vortices provide an easy way to the large-scale integration of optical vortex emitters for wide-ranging applications. PMID:27404659

  1. Application of Laser-Generated Ion Beams for Isochoric Heating to Study Plasma Mix at Interfaces

    NASA Astrophysics Data System (ADS)

    Albright, B. J.; Fernández, J. C.; Bang, W.; Bradley, P. A.; Gautier, D. C.; Hamilton, C. E.; Palaniyappan, S.; Santiago Cordoba, M. A.; Vold, E. L.; Yin, L.; Hegelich, B. M.; Dyer, G.; Roycroft, R.

    2015-11-01

    The evolution and mixing of high-Z/low-Z interfaces in plasma media is of profound importance to high energy density physics and inertial fusion experiments. Recent experiments performed at the LANL Trident laser facility as part of the Plasma Interfacial Mix project have applied novel, laser-generated ion beams created under conditions of relativistic induced transparency to the heating of solid-density, multi-material targets isochorically and uniformly (over a few tens of ps), attaining plasma temperatures of several eV. Measurements have been made of the evolving plasma, including location of the material interface and the time-history of the temperature of the medium. Recent data and associated radiation hydrodynamic modeling from our Trident campaigns will be reported. Complementary kinetic simulations of interface evolution, showing anomalously rapid atomic mixing under conditions relevant to ICF experiments, will also be discussed. Work performed under the auspices of the U.S. DOE by the LANS, LLC, Los Alamos National Laboratory under Contract No. DE-AC52-06NA25396. Funding provided by the Los Alamos National Laboratory Directed Research and Development Program.

  2. Initial experiments using radial foils on the Cornell Beam Research Accelerator pulsed power generator

    SciTech Connect

    Gourdain, P.-A.; Blesener, I. C.; Greenly, J. B.; Hammer, D. A.; Knapp, P. F.; Kusse, B. R.; Schrafel, P. C.

    2010-01-15

    A novel technique involving radial foil explosions can produce high energy density plasmas. A current flows radially inward in a 5 mum thin aluminum foil from a circular anode, which contacts the foil on its outer rim, to the cathode, which connects to the foil at its geometrical center. When using small 'pin' cathodes (approx1 mm in diameter) on a medium size pulsed-current generator such as the Cornell Beam Research Accelerator, the central magnetic field approaches 400 T, yielding magnetic pressures larger than 0.5 Mbar. While the dynamics is similar to radial wire arrays, radial foil discharges have very distinct characteristics. First a plasma jet forms, with densities near 5x10{sup 18} cm{sup -3}. JxB forces lift the foil upward with velocities of approx200 km/s. A plasma bubble with electron densities superior to 5x10{sup 19} cm{sup -3} then develops, surrounding a central plasma column, carrying most of the cathode current. X-ray bursts coming from the center of this column were recorded at 1 keV photon energy. As the magnetic bubble explodes, ballistic plasma projectiles form and escape with velocities exceeding 300 km/s. Laser shadowgraphy and interferometry, gated extreme ultraviolet imaging and miniature Bdot probes are used to investigate the magnetohydrodynamics properties of such configurations.

  3. High Energy Density Capacitors

    SciTech Connect

    2010-07-01

    BEEST Project: Recapping is developing a capacitor that could rival the energy storage potential and price of today’s best EV batteries. When power is needed, the capacitor rapidly releases its stored energy, similar to lightning being discharged from a cloud. Capacitors are an ideal substitute for batteries if their energy storage capacity can be improved. Recapping is addressing storage capacity by experimenting with the material that separates the positive and negative electrodes of its capacitors. These separators could significantly improve the energy density of electrochemical devices.

  4. High Energy Density Materials

    DTIC Science & Technology

    2003-09-01

    nitrene equivalents such as organic azides, N-haloamines, N-acyl hydroxylamines N,O-diacyl hydroxylamines, and amides in the presence of lead tetra...cation and its analogues. These cations were reacted with a wide array of nucleophillic nitrene equivalents such as fluoronitramide anion or monobromo

  5. Summary Report on Beam and Radiation Generation, Monitoring and Control

    SciTech Connect

    Gordon, D. F.; Power, J. G.

    2009-01-22

    The discussions of the working group on beam and radiation generation, monitoring, and control (working group 6) at the 2008 advanced accelerator concepts workshop are summarized. The discussions concerned electron injectors, phase space manipulation, beam diagnostics, pulse train generation, intense beam physics, and radiation generation.

  6. Density functional calculations for a high energy density compound of formula C6H 6-n (NO 2) n.

    PubMed

    Chi, Wei-Jie; Li, Lu-Lin; Li, Bu-Tong; Wu, Hai-Shun

    2012-08-01

    A series of polynitroprismanes, C(6)H(6-n )(NO(2))(n) (n = 1-6) intended for use as high energy density compounds (HEDCs) were designed computationally. Their electronic structures, heats of formation, interactions between nitro groups, specific enthalpies of combustion, bond dissociation energies, and explosive performances (detonation velocities and detonation pressures) were calculated using density functional theory (DFT) with the 6-311 G** basis set. The results showed that all of the polynitroprismanes had high positive heats of formation that increased with the number of substitutions for the prismane derivatives, while the specific enthalpy of combustion decreased as the number of nitro groups increased. In addition, the range of enthalpy of combustion reducing is getting smaller. Interactions between ortho (vicinal) groups deviate from the group additivity rule and decrease as the number of nitro groups increases. In terms of thermodynamic stability, all of the polynitroprismanes had higher bond dissociation energies (BDEs) than RDX and HMX. Detonation velocities and detonation pressures were estimated using modified Kamlet-Jacobs equations based on the heat of detonation (Q) and the theoretical density of the molecule (ρ). It was found that ρ, D, and P are strongly linearly related to the number of nitro groups. Taking both their energetic properties and thermal stabilities into account, pentanitroprismane and hexanitroprismane are potential candidate HEDCs.

  7. DFT studies on a high energy density cage compound 4-trinitroethyl-2,6,8,10,12-pentanitrohezaazaisowurtzitane.

    PubMed

    Zhang, Jian-ying; Du, Hong-chen; Wang, Fang; Gong, Xue-dong; Huang, Yin-sheng

    2011-06-23

    Polynitro cage compound 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane has the same framework with but higher stability than CL-20 and is a potential new high energy density compound (HEDC). In this paper, the B3LYP/6-31G(d,p) method of density functional theory (DFT) has been used to study its heat of formation, IR spectrum, and thermodynamic properties. The stability of the compound was evaluated by the bond dissociation energies. The calculated results show that the first step of pyrolysis is the rupture of the N-NO(2) bond in the side chain and verify the experimental observation that the title compound has better stability than CL-20. The crystal structure obtained by molecular mechanics belongs to the P2(1)2(1)2(1) space group, with lattice parameters a = 12.59 Å, b = 10.52 Å, c = 12.89 Å, Z = 4, and ρ = 2.165 g·cm(-3). Both the detonation velocity of 9.767 km·s(-1) and the detonation pressure of 45.191 GPa estimated using the Kamlet-Jacobs equation are better than those of CL-20. Considering that this cage compound has a better detonation performance and stability than CL-20, it may be a superior HEDC.

  8. Molecular Design and Property Prediction for a Series of Novel Dicyclic Cyclotrimethylene Trinitramines (RDX) Derivatized as High Energy Density Materials.

    PubMed

    Shen, Cheng; Wang, Pengcheng; Lu, Ming

    2015-07-23

    Quantum chemistry calculations and thermodynamics methods were carried out to screen out novel high energy density materials (HEDMs) from several new derivatives with dicyclic structures of Cyclotrimethylene trinitramine (RDX). Their volumes, densities, heats of formation, detonation properties and impact sensitivities have been calculated with thermodynamics methods under DFT B3LYP 6-31++g (d, p) level and all of these compounds exhibit good performance as HEDMs. Especially, R4 has given outstanding values as a potential HEDM. Its crystal density (2.07 g/cm(3)), heat of detonation (1.67 kJ/g), detonation velocity (10051m/s), and detonation pressure (48.5 GPa) are even higher than those of CL-20 while its impact sensitivity (h50, 16 cm) remains a relative safety value. The results indicate that the derivative work in common explosives is a good strategy which can design novel HEDMs with high energetic properties and low sensitivity. And furthermore, some mature processes can be used to synthesize them.

  9. SC-CO2 assisted process for high energy density aerogel supercapacitor: the effect of GO loading.

    PubMed

    Sarno, Maria; Baldino, Lucia; Scudieri, Carmela; Cardea, Stefano; Ciambelli, Paolo; Reverchon, Ernesto

    2017-03-20

    Energy density, safety, simple and environmentally friendly preparation methods are very significant aspects in the realization of a compact supercapacitor. Herein we report the use of a supercritical CO2 assisted gel drying process (SC-CO2) for the preparation of porous electrodes containing dispersed graphene in a Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) binder membrane to sandwich in a new portable supercapacitor based on graphene oxide (GO). A GO loading of 60 wt.% has been found to give the better combination of factors (porosity, wettability, mechanical and electrochemical properties,..). Cycling voltammetry and charge/discharge studies showed an excellent capacitance behaviour and stability in a ionic liquid electrolyte, suggesting SC-CO2 processing as promising platform to produce highly bulky and porous films for supercapacitors. The supercapacitor device delivers a very high energy density of 79.2 Wh/Kg at a power density of 0.23 KW/kg (current density 0.5 A/g, specific capacitance 36.2 F/g) that steel remains 50.3 Wh/kg at a power density of 2.8 KW/kg (current density 6 A/g, specific capacitance 23.5 F/g).

  10. Fluorine-doped Fe(2)O(3) as high energy density electroactive material for hybrid supercapacitor applications.

    PubMed

    Karthikeyan, Kaliyappan; Amaresh, Samuthirapandian; Lee, Sol Nip; Aravindan, Vanchiappan; Lee, Yun Sung

    2014-03-01

    Nanostructured α-Fe2 O3 with and without fluorine substitution were successfully obtained by a green route, that is, microwave irradiation. The hematite phase materials were evaluated as a high-performance electrode material in a hybrid supercapacitor configuration along with activated carbon (AC). The presence of fluorine was confirmed through X-ray photoelectron spectroscopy and transmission electron microscopy. Fluorine-doped Fe2 O3 (F-Fe2 O3 ) exhibits an enhanced pseudocapacitive performance compared to that of the bare hematite phase. The F-Fe2 O3 /AC cell delivered a specific capacitance of 71 F g(-1) at a current density of 2.25 A g(-1) and retained approximately 90 % of its initial capacitance after 15 000 cycles. Furthermore, the F-Fe2 O3 /AC cell showed a very high energy density of about 28 W h kg(-1) compared to bare hematite phase (∼9 W h kg(-1) ). These data clearly reveal that the electrochemical performance of Fe2 O3 can be improved by fluorine doping, thereby dramatically improving the energy density of the system. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Understanding limiting factors in thick electrode performance as applied to high energy density Li-ion batteries

    DOE PAGES

    Du, Zhijia; Wood, David L.; Daniel, Claus; ...

    2017-02-09

    We present that increasing electrode thickness, thus increasing the volume ratio of active materials, is one effective method to enable the development of high energy density Li-ion batteries. In this study, an energy density versus power density optimization of LiNi0.8Co0.15Al0.05O2 (NCA)/graphite cell stack was conducted via mathematical modeling. The energy density was found to have a maximum point versus electrode thickness (critical thickness) at given discharging C rates. The physics-based factors that limit the energy/power density of thick electrodes were found to be increased cell polarization and underutilization of active materials. The latter is affected by Li-ion diffusion in activemore » materials and Li-ion depletion in the electrolyte phase. Based on those findings, possible approaches were derived to surmount the limiting factors. Finally, the improvement of the energy–power relationship in an 18,650 cell was used to demonstrate how to optimize the thick electrode parameters in cell engineering.« less

  12. Three- and Two- Dimensional Simulations of Re-shock Experiments at High Energy Densities at the National Ignition Facility

    NASA Astrophysics Data System (ADS)

    Wang, Ping; Raman, Kumar; MacLaren, Stephan; Huntington, Channing; Nagel, Sabrina

    2016-10-01

    We present simulations of recent high-energy-density (HED) re-shock experiments on the National Ignition Facility (NIF). The experiments study the Rayleigh-Taylor (RT) and Richtmyer-Meshkov (RM) instability growth that occurs after successive shocks transit a sinusoidally-perturbed interface between materials of different densities. The shock tube is driven at one or both ends using indirect-drive laser cavities or hohlraums. X-ray area-backlit imaging is used to visualize the growth at different times. Our simulations are done with the three-dimensional, radiation hydrodynamics code ARES, developed at LLNL. We show the instabilitygrowth rate, inferred from the experimental radiographs, agrees well with our 2D and 3D simulations. We also discuss some 3D geometrical effects, suggested by our simulations, which could deteriorate the images at late times, unless properly accounted for in the experiment design. Work supported by U.S. Department of Energy under Contract DE- AC52-06NA27279. LLNL-ABS-680789.

  13. An x-ray backlit Talbot-Lau deflectometer for high-energy-density electron density diagnostics

    SciTech Connect

    Valdivia, M. P.; Stutman, D.; Stoeckl, C.; Theobald, W.; Mileham, C.; Begishev, I. A.; Bromage, J.; Regan, S. P.

    2016-02-10

    X-ray phase-contrast techniques can measure electron density gradients in high-energy-density plasmas through refraction induced phase shifts. An 8 keV Talbot-Lau interferometer consisting of free standing ultrathin gratings was deployed at an ultra-short, high-intensity laser system using K-shell emission from a 1-30 J, 8 ps laser pulse focused on thin Cu foil targets. Grating survival was demonstrated for 30 J, 8 ps laser pulses. The first x-ray deflectometry images obtained under laser backlighting showed up to 25% image contrast and thus enabled detection of electron areal density gradients with a maximum value of 8.1 ± 0.5 × 1023 cm₋3 in a low-Z millimeter sized sample. An electron density profile was obtained from refraction measurements with an error of <8%. We found the 50 ± 15 μm spatial resolution achieved across the full field of view was limited by the x-ray source-size, similar to conventional radiography.

  14. Recent Progress on Ferroelectric Polymer-Based Nanocomposites for High Energy Density Capacitors: Synthesis, Dielectric Properties, and Future Aspects.

    PubMed

    Prateek; Thakur, Vijay Kumar; Gupta, Raju Kumar

    2016-04-13

    Dielectric polymer nanocomposites are rapidly emerging as novel materials for a number of advanced engineering applications. In this Review, we present a comprehensive review of the use of ferroelectric polymers, especially PVDF and PVDF-based copolymers/blends as potential components in dielectric nanocomposite materials for high energy density capacitor applications. Various parameters like dielectric constant, dielectric loss, breakdown strength, energy density, and flexibility of the polymer nanocomposites have been thoroughly investigated. Fillers with different shapes have been found to cause significant variation in the physical and electrical properties. Generally, one-dimensional and two-dimensional nanofillers with large aspect ratios provide enhanced flexibility versus zero-dimensional fillers. Surface modification of nanomaterials as well as polymers adds flavor to the dielectric properties of the resulting nanocomposites. Nowadays, three-phase nanocomposites with either combination of fillers or polymer matrix help in further improving the dielectric properties as compared to two-phase nanocomposites. Recent research has been focused on altering the dielectric properties of different materials while also maintaining their superior flexibility. Flexible polymer nanocomposites are the best candidates for application in various fields. However, certain challenges still present, which can be solved only by extensive research in this field.

  15. An x-ray backlit Talbot-Lau deflectometer for high-energy-density electron density diagnostics

    DOE PAGES

    Valdivia, M. P.; Stutman, D.; Stoeckl, C.; ...

    2016-02-10

    X-ray phase-contrast techniques can measure electron density gradients in high-energy-density plasmas through refraction induced phase shifts. An 8 keV Talbot-Lau interferometer consisting of free standing ultrathin gratings was deployed at an ultra-short, high-intensity laser system using K-shell emission from a 1-30 J, 8 ps laser pulse focused on thin Cu foil targets. Grating survival was demonstrated for 30 J, 8 ps laser pulses. The first x-ray deflectometry images obtained under laser backlighting showed up to 25% image contrast and thus enabled detection of electron areal density gradients with a maximum value of 8.1 ± 0.5 × 1023 cm₋3 in amore » low-Z millimeter sized sample. An electron density profile was obtained from refraction measurements with an error of <8%. We found the 50 ± 15 μm spatial resolution achieved across the full field of view was limited by the x-ray source-size, similar to conventional radiography.« less

  16. Laser-driven high-energy-density deuterium and tritium ions for neutron production in a double-cone configuration

    SciTech Connect

    Hu, Li-Xiang; Yu, Tong-Pu Shao, Fu-Qiu; Yin, Yan; Ma, Yan-Yun; Zhu, Qing-Jun

    2015-12-15

    By using two-dimensional particle-in-cell simulations, we investigate laser-driven ion acceleration and compression from a thin DT foil in a double-cone configuration. By using two counterpropagating laser pulses, it is shown that a double-cone structure can effectively guide, focus, and strengthen the incident laser pulses, resulting in the enhanced acceleration and compression of D{sup +} and T{sup +}. Due to the ion Coulomb repulsion and the effective screening from the external laser electric fields, the transverse diffusion of ions is significantly suppressed. Finally, the peak energy density of the compressed ions exceeds 2.73 × 10{sup 16 }J/m{sup 3}, which is about five orders of magnitude higher than the threshold for high energy density physics, 10{sup 11 }J/m{sup 3}. Under this condition, DT fusion reactions are initiated and the neutron production rate per volume is estimated to be as high as 7.473 × 10{sup 35}/m{sup 3} s according to Monte Carlo simulations. It is much higher than that of the traditional large neutron sources, which may facilitate many potential applications.

  17. VO2 Nanoflakes as the Cathode Material of Hybrid Magnesium-Lithium-Ion Batteries with High Energy Density.

    PubMed

    Pei, Cunyuan; Xiong, Fangyu; Sheng, Jinzhi; Yin, Yameng; Tan, Shuangshuang; Wang, Dandan; Han, Chunhua; An, Qinyou; Mai, Liqiang

    2017-05-24

    The hybrid magnesium-lithium-ion batteries (MLIBs) combining the dendrite-free deposition of the Mg anode and the fast Li intercalation cathode are better alternatives to Li-ion batteries (LIBs) in large-scale power storage systems. In this article, we reported hybrid MLIBs assembled with the VO2 cathode, dendrite-free Mg anode, and the Mg-Li dual-salt electrolyte. Satisfactorily, the VO2 cathode delivered a stable plateau at about 1.75 V, and a high specific discharge capacity of 244.4 mA h g(-1). To the best of our knowledge, the VO2 cathode displays the highest energy density of 427 Wh kg(-1) among reported MLIBs in coin-type batteries. In addition, an excellent rate performance and a wide operating temperature window from 0 to 55 °C have been obtained. The combination of VO2 cathode, dual-salt electrolyte, and Mg anode would pave the way for the development of high energy density, safe, and low-cost batteries.

  18. An x-ray backlit Talbot-Lau deflectometer for high-energy-density electron density diagnostics.

    PubMed

    Valdivia, M P; Stutman, D; Stoeckl, C; Theobald, W; Mileham, C; Begishev, I A; Bromage, J; Regan, S P

    2016-02-01

    X-ray phase-contrast techniques can measure electron density gradients in high-energy-density plasmas through refraction induced phase shifts. An 8 keV Talbot-Lau interferometer consisting of free standing ultrathin gratings was deployed at an ultra-short, high-intensity laser system using K-shell emission from a 1-30 J, 8 ps laser pulse focused on thin Cu foil targets. Grating survival was demonstrated for 30 J, 8 ps laser pulses. The first x-ray deflectometry images obtained under laser backlighting showed up to 25% image contrast and thus enabled detection of electron areal density gradients with a maximum value of 8.1 ± 0.5 × 10(23) cm(-3) in a low-Z millimeter sized sample. An electron density profile was obtained from refraction measurements with an error of <8%. The 50 ± 15 μm spatial resolution achieved across the full field of view was found to be limited by the x-ray source-size, similar to conventional radiography.

  19. Structure evolution and thermal stability of high-energy density Li-ion battery cathode Li2VO2F

    DOE PAGES

    Wang, Xiaoya; Huang, Yiqing; Ji, Dongsheng; ...

    2017-05-24

    Lithium-ion batteries (LIBs) provide high-energy-density electrochemical energy storage, which plays a central role in advancing technologies ranging from portable electronics to electric vehicles (EVs). However, a demand for lighter, more compact devices and for extended range EVs continues to fuel the need for higher energy density storage systems. Li2VO2F, which is synthesized in its lithiated state, allows two-electron transfer per formula during the electrochemical reaction providing a high theoretical capacity of 462 mAh/g. Herein, the synthesis and electrochemical performance of Li2VO2F are optimized. The thermal stability of Li2VO2F, which is related to the safety of a battery is studied bymore » thermal gravimetric analysis. The structure and vanadium oxidation state evolution along Li cycling are studied by ex-situ X-ray diffraction and absorption techniques. It is shown that the rock-salt structure of pristine Li2VO2F is stable up to at least 250°C, and is preserved upon Li cycling, which proceeds by the solid-solution mechanism. However, not all Li can be removed from the structure upon charge to 4.5 V, limiting the experimentally obtained capacity.« less

  20. Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries

    DOEpatents

    Deng, Haixia; Belharouak, Ilias; Amine, Khalil

    2012-10-02

    Nano-sized structured dense and spherical layered positive active materials provide high energy density and high rate capability electrodes in lithium-ion batteries. Such materials are spherical second particles made from agglomerated primary particles that are Li.sub.1+.alpha.(Ni.sub.xCo.sub.yMn.sub.z).sub.1-tM.sub.tO.sub.2-dR.sub.d- , where M is selected from can be Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, Zr, or a mixture of any two or more thereof, R is selected from F, Cl, Br, I, H, S, N, or a mixture of any two or more thereof, and 0.ltoreq..alpha..ltoreq.0.50; 0

  1. Observation and modeling of mixing-layer development in high-energy-density, blast-wave-driven shear flow

    SciTech Connect

    Di Stefano, C. A. Kuranz, C. C.; Klein, S. R.; Drake, R. P.; Malamud, G.; Henry de Frahan, M. T.; Johnsen, E.; Shimony, A.; Shvarts, D.; Smalyuk, V. A.; Martinez, D.

    2014-05-15

    In this work, we examine the hydrodynamics of high-energy-density (HED) shear flows. Experiments, consisting of two materials of differing density, use the OMEGA-60 laser to drive a blast wave at a pressure of ∼50 Mbar into one of the media, creating a shear flow in the resulting shocked system. The interface between the two materials is Kelvin-Helmholtz unstable, and a mixing layer of growing width develops due to the shear. To theoretically analyze the instability's behavior, we rely on two sources of information. First, the interface spectrum is well-characterized, which allows us to identify how the shock front and the subsequent shear in the post-shock flow interact with the interface. These observations provide direct evidence that vortex merger dominates the evolution of the interface structure. Second, simulations calibrated to the experiment allow us to estimate the time-dependent evolution of the deposition of vorticity at the interface. The overall result is that we are able to choose a hydrodynamic model for the system, and consequently examine how well the flow in this HED system corresponds to a classical hydrodynamic description.

  2. SC-CO2-assisted process for a high energy density aerogel supercapacitor: the effect of GO loading

    NASA Astrophysics Data System (ADS)

    Sarno, Maria; Baldino, Lucia; Scudieri, Carmela; Cardea, Stefano; Ciambelli, Paolo; Reverchon, Ernesto

    2017-05-01

    Energy density, safety, and simple and environmentally friendly preparation methods are very significant aspects in the realization of a compact supercapacitor. Herein we report the use of a supercritical CO2-assisted gel drying process (SC-CO2) for the preparation of porous electrodes containing dispersed graphene in a poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) binder membrane to sandwich in a new portable supercapacitor based on graphene oxide (GO). A GO loading of 60 wt.% was found to give the best combination of factors (porosity, wettability, mechanical and electrochemical properties). Cycling voltammetry and charge/discharge studies showed an excellent capacitance behaviour and stability in an ionic liquid electrolyte, suggesting SC-CO2 processing as a promising platform to produce highly bulky and porous films for supercapacitors. The supercapacitor device delivers a very high energy density of 79.2 Wh kg-1 at a power density of 0.23 KW kg-1 (current density 0.5 A g-1, specific capacitance 36.2 F g-1) while that of steel remains at 50.3 Wh kg-1 at a power density of 2.8 KW kg-1 (current density 6 A g-1, specific capacitance 23.5 F g-1).

  3. Talbot-Lau based Moiré deflectometry with non-coherent sources as potential High Energy Density plasma diagnostic

    SciTech Connect

    Valdivia, M. P.; Stutman, D.; Finkenthal, M.

    2013-10-28

    X-ray phase-contrast radiography could better characterize highly localized density gradients expected in High Energy Density (HED) plasma experiments than conventional attenuation radiography. In particular, the Talbot-Lau (TL) grating interferometer, which works with extended and polychromatic x-ray sources, is a potentially attractive HED diagnostic due to its high sensitivity. For HED characterization the TL setup and imaging techniques must be changed from the recently studied medical system. The object magnification must be increased greatly in order to resolve μm scale gradients while the Talbot magnification must be increased in order to keep the gratings away from the plasma. Additionally, techniques for retrieving the density profile from a single plasma image must be developed. We thus study the performance of high magnification TL interferometers, in conjunction with Moiré fringe deflectometry for single image phase retrieval. The results show a very good interferometer contrast (≤30%) at high magnification. The Moiré technique enables measuring both sharp and mild density gradients with good accuracy and spatial resolution. Both the laboratory and simulation studies indicate that the TL based Moiré deflectometry is more sensitive than the propagation phase-contrast method when utilizing an extended x-ray source (∼80 μm). In HED experiments this would allow for less demanding X-ray backlighters than those used at present.

  4. Ag incorporated Mn3O4/AC nanocomposite based supercapacitor devices with high energy density and power density.

    PubMed

    Nagamuthu, S; Vijayakumar, S; Muralidharan, G

    2014-12-14

    Silver incorporated Mn3O4/amorphous carbon (AC) nanocomposites are synthesized by a green chemistry method. X-ray diffraction studies revealed the structural changes in Mn3O4/AC nanocomposites attributable to the addition of silver. Cyclic voltammetry, charge-discharge and ac-impedance studies indicated that the Ag-Mn3O4/AC-5 electrode was the most suitable candidate for supercapacitor applications. From the galvanostatic charge-discharge studies, a higher specific capacitance of 981 F g(-1) at a specific current of 1 A g(-1) was obtained. An Ag-Mn3O4/AC-symmetric supercapacitor consisting of an Ag-incorporated Mn3O4/AC composite as an anode as well as a cathode, and an asymmetric supercapacitor consisting of an Ag-incorporated Mn3O4/AC composite as a cathode and an activated carbon as an anode have been fabricated. The symmetric device exhibits a specific cell capacitance of 72 F g(-1) at a specific current of 1 A g(-1) whereas the asymmetric device delivers a specific cell capacitance of 180 F g(-1) at a high current rate of 10 A g(-1). The asymmetric supercapacitor device yields a high energy density of 81 W h kg(-1). This is higher than that of lead acid batteries and comparable with that of nickel hydride batteries.

  5. High-energy density experiments on planetary materials using high-power lasers and X-ray free electron laser

    NASA Astrophysics Data System (ADS)

    Ozaki, Norimasa

    2015-06-01

    Laser-driven dynamic compression allows us to investigate the behavior of planetary and exoplanetary materials at extreme conditions. Our high-energy density (HED) experiments for applications to planetary sciences began over five years ago. We measured the equation-of-state of cryogenic liquid hydrogen under laser-shock compression up to 55 GPa. Since then, various materials constituting the icy giant planets and the Earth-like planets have been studied using laser-driven dynamic compression techniques. Pressure-volume-temperature EOS data and optical property data of water and molecular mixtures were obtained at the planetary/exoplanetary interior conditions. Silicates and oxides data show interesting behaviors in the warm-dense matter regime due to their phase transformations. Most recently the structural changes of iron were observed for understanding the kinetics under the bcc-hcp transformation phenomena on a new HED science platform coupling power-lasers and the X-ray free electron laser (SACLA). This work was performed under the joint research project at the Institute of Laser Engineering, Osaka University. It was partially supported by a Grant-in-Aid for Scientific Research (Grant Nos. 20654042, 22224012, 23540556, and 24103507) and also by grants from the Core-to-Core Program of JSPS on International Alliance for Material Science in Extreme States with High Power Laser and XFEL, and the X-ray Free Electron Laser Priority Strategy Program of MEXT.

  6. 3D strain engineered self-rolled thin-film architecture for high-energy density lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Godbey, Griffin; Gong, Chen; Yu, Cynthia; Blythe, Clayton; Leite, Marina

    Recently, multiple 3D geometries have been implemented into energy storage devices (e . g . nanowire anodes and arrays of interdigitated rods) in order to better accommodate the large volume expansion experienced by the anode during lithiation and to increase the structure energy density. However, most approached structures are difficult to scale up. Here we show how self-rolled thin-films can maintain a high energy density and can potentially accommodate the volume expansion suffered by the anode. The self-rolled tubes are fabricated by physical deposition of the active layers, creating a stress gradient between thin-film stack due to differences in coefficient of thermal expansion. Upon a sacrificial layer removal, the thin-film rolls to relieve this built-in stress. We predict the final dimension of self-rolled battery tubes using known elastic properties of materials commonly used as the active layers of the device. We will discuss an appropriate figure-of-merit that defines how the winding process can ultimately affect the volumetric capacity of 3D self-rolled batteries.

  7. Amodal brain activation and functional connectivity in response to high-energy-density food cues in obesity.

    PubMed

    Carnell, Susan; Benson, Leora; Pantazatos, Spiro P; Hirsch, Joy; Geliebter, Allan

    2014-11-01

    The obesogenic environment is pervasive, yet only some people become obese. The aim was to investigate whether obese individuals show differential neural responses to visual and auditory food cues, independent of cue modality. Obese (BMI 29-41, n = 10) and lean (BMI 20-24, n = 10) females underwent fMRI scanning during presentation of auditory (spoken word) and visual (photograph) cues representing high-energy-density (ED) and low-ED foods. The effect of obesity on whole-brain activation, and on functional connectivity with the midbrain/VTA, was examined. Obese compared with lean women showed greater modality-independent activation of the midbrain/VTA and putamen in response to high-ED (vs. low-ED) cues, as well as relatively greater functional connectivity between the midbrain/VTA and cerebellum (P < 0.05 corrected). Heightened modality-independent responses to food cues within the midbrain/VTA and putamen, and altered functional connectivity between the midbrain/VTA and cerebellum, could contribute to excessive food intake in obese individuals. © 2014 The Obesity Society.

  8. Origins of Large Voltage Hysteresis in High-Energy-Density Metal Fluoride Lithium-Ion Battery Conversion Electrodes.

    PubMed

    Li, Linsen; Jacobs, Ryan; Gao, Peng; Gan, Liyang; Wang, Feng; Morgan, Dane; Jin, Song

    2016-03-02

    Metal fluorides and oxides can store multiple lithium ions through conversion chemistry to enable high-energy-density lithium-ion batteries. However, their practical applications have been hindered by an unusually large voltage hysteresis between charge and discharge voltage profiles and the consequent low-energy efficiency (<80%). The physical origins of such hysteresis are rarely studied and poorly understood. Here we employ in situ X-ray absorption spectroscopy, transmission electron microscopy, density functional theory calculations, and galvanostatic intermittent titration technique to first correlate the voltage profile of iron fluoride (FeF3), a representative conversion electrode material, with evolution and spatial distribution of intermediate phases in the electrode. The results reveal that, contrary to conventional belief, the phase evolution in the electrode is symmetrical during discharge and charge. However, the spatial evolution of the electrochemically active phases, which is controlled by reaction kinetics, is different. We further propose that the voltage hysteresis in the FeF3 electrode is kinetic in nature. It is the result of ohmic voltage drop, reaction overpotential, and different spatial distributions of electrochemically active phases (i.e., compositional inhomogeneity). Therefore, the large hysteresis can be expected to be mitigated by rational design and optimization of material microstructure and electrode architecture to improve the energy efficiency of lithium-ion batteries based on conversion chemistry.

  9. Toward Low-Cost, High-Energy Density, and High-Power Density Lithium-Ion Batteries

    NASA Astrophysics Data System (ADS)

    Li, Jianlin; Du, Zhijia; Ruther, Rose E.; AN, Seong Jin; David, Lamuel Abraham; Hays, Kevin; Wood, Marissa; Phillip, Nathan D.; Sheng, Yangping; Mao, Chengyu; Kalnaus, Sergiy; Daniel, Claus; Wood, David L.

    2017-06-01

    Reducing cost and increasing energy density are two barriers for widespread application of lithium-ion batteries in electric vehicles. Although the cost of electric vehicle batteries has been reduced by 70% from 2008 to 2015, the current battery pack cost (268/kWh in 2015) is still >2 times what the USABC targets (125/kWh). Even though many advancements in cell chemistry have been realized since the lithium-ion battery was first commercialized in 1991, few major breakthroughs have occurred in the past decade. Therefore, future cost reduction will rely on cell manufacturing and broader market acceptance. This article discusses three major aspects for cost reduction: (1) quality control to minimize scrap rate in cell manufacturing; (2) novel electrode processing and engineering to reduce processing cost and increase energy density and throughputs; and (3) material development and optimization for lithium-ion batteries with high-energy density. Insights on increasing energy and power densities of lithium-ion batteries are also addressed.

  10. Toward Low-Cost, High-Energy Density, and High-Power Density Lithium-Ion Batteries

    NASA Astrophysics Data System (ADS)

    Li, Jianlin; Du, Zhijia; Ruther, Rose E.; AN, Seong Jin; David, Lamuel Abraham; Hays, Kevin; Wood, Marissa; Phillip, Nathan D.; Sheng, Yangping; Mao, Chengyu; Kalnaus, Sergiy; Daniel, Claus; Wood, David L.

    2017-09-01

    Reducing cost and increasing energy density are two barriers for widespread application of lithium-ion batteries in electric vehicles. Although the cost of electric vehicle batteries has been reduced by 70% from 2008 to 2015, the current battery pack cost (268/kWh in 2015) is still >2 times what the USABC targets (125/kWh). Even though many advancements in cell chemistry have been realized since the lithium-ion battery was first commercialized in 1991, few major breakthroughs have occurred in the past decade. Therefore, future cost reduction will rely on cell manufacturing and broader market acceptance. This article discusses three major aspects for cost reduction: (1) quality control to minimize scrap rate in cell manufacturing; (2) novel electrode processing and engineering to reduce processing cost and increase energy density and throughputs; and (3) material development and optimization for lithium-ion batteries with high-energy density. Insights on increasing energy and power densities of lithium-ion batteries are also addressed.

  11. A multi-dimensional Vlasov-Fokker-Planck code for arbitrarily anisotropic high-energy-density plasmas

    SciTech Connect

    Tzoufras, M.; Tableman, A.; Tsung, F. S.; Mori, W. B.; Bell, A. R.

    2013-05-15

    To study the kinetic physics of High-Energy-Density Laboratory Plasmas, we have developed the parallel relativistic 2D3P Vlasov-Fokker-Planck code Oshun. The numerical scheme uses a Cartesian mesh in configuration-space and incorporates a spherical harmonic expansion of the electron distribution function in momentum-space. The expansion is truncated such that the necessary angular resolution of the distribution function is retained for a given problem. Finite collisionality causes rapid decay of the high-order harmonics, thereby providing a natural truncation mechanism for the expansion. The code has both fully explicit and implicit field-solvers and employs a linearized Fokker-Planck collision operator. Oshun has been benchmarked against well-known problems, in the highly kinetic limit to model collisionless relativistic instabilities, and in the hydrodynamic limit to recover transport coefficients. The performance of the code, its applicability, and its limitations are discussed in the context of simple problems with relevance to inertial fusion energy.

  12. High energy density sodium-ion capacitors through co-intercalation mechanism in diglyme-based electrolyte system

    NASA Astrophysics Data System (ADS)

    Han, Pengxian; Han, Xiaoqi; Yao, Jianhua; Zhang, Lixue; Cao, Xiaoyan; Huang, Changshui; Cui, Gunglei

    2015-11-01

    A novel sodium-ion capacitor (NIC) was assembled using graphitic mesocarbon microbead anode and activated carbon cathode in diglyme-based electrolyte. Charge/discharge tests indicate that sodium ions can reversibly co-intercalated with diglyme solvent into graphite anode and show good rate performance. The energy densities of the NICs are as high as 93.5 and 86.5 Wh kg-1 at 573 and 2832 W kg-1 (equal to 4 C and 50 C) in the voltage window at 1-4 V, respectively. By optimizing the voltage ranges, the capacity retention of the NIC at 20 C is 98.3% even after 3000 cycles. Such superior electrochemical performance should be attributed to the reversible intercalated/deintercalated reaction of sodium ions and the formation of ternary graphite intercalation compounds in diglyme-based electrolyte. The present work pioneers new realms of hybrid energy storage system with high energy density, high power density and long cycle life.

  13. Flexible all solid state supercapacitor with high energy density employing black titania nanoparticles as a conductive agent

    NASA Astrophysics Data System (ADS)

    Zhi, Jian; Yang, Chongyin; Lin, Tianquan; Cui, Houlei; Wang, Zhou; Zhang, Hui; Huang, Fuqiang

    2016-02-01

    Increasing the electrical conductivity of pseudocapacitive materials without changing their morphology is an ideal structural solution to realize both high electrochemical performance and superior flexibility for an all solid state supercapacitor (ASSSC). Herein, we fabricate a flexible ASSSC device employing black titania (TiO2-x:N) decorated two-dimensional (2D) NiO nanosheets as the positive electrode and mesoporous graphene as the negative electrode. In this unique design, NiO nanosheets are used as pseudocapacitive materials and TiO2-x:N nanoparticles serve as the conductive agent. Owing to the excellent electrical conductivity of TiO2-x:N and well defined ``particle on sheet'' planar structure of NiO/TiO2-x:N composites, the 2D morphology of the decorated NiO nanosheets is completely retained, which efficiently reinforces the pseudocapacitive activity and flexibility of the whole all solid state device. The maximum specific capacitance of fabricated the NiO/TiO2-x:N//mesoporous graphene supercapacitor can reach 133 F g-1, which is 2 and 4 times larger than the values of the NiO based ASSSC employing graphene and carbon black as the conductive agent, respectively. In addition, the optimized ASSSC displays intriguing performances with an energy density of 47 W h kg-1 in a voltage region of 0-1.6 V, which is, to the best of our knowledge, the highest value for flexible ASSSC devices. The impressive results presented here may pave the way for promising applications of black titania in high energy density flexible storage systems.Increasing the electrical conductivity of pseudocapacitive materials without changing their morphology is an ideal structural solution to realize both high electrochemical performance and superior flexibility for an all solid state supercapacitor (ASSSC). Herein, we fabricate a flexible ASSSC device employing black titania (TiO2-x:N) decorated two-dimensional (2D) NiO nanosheets as the positive electrode and mesoporous graphene as the

  14. Generation of nondiffracting Bessel beam using digital micromirror device.

    PubMed

    Gong, Lei; Ren, Yu-Xuan; Xue, Guo-Sheng; Wang, Qian-Chang; Zhou, Jin-Hua; Zhong, Min-Cheng; Wang, Zi-Qiang; Li, Yin-Mei

    2013-07-01

    We experimentally demonstrated Bessel-like beams utilizing digital micromirror device (DMD). DMD with images imitating the equivalent axicon can shape the collimated Gaussian beam into Bessel beam. We reconstructed the 3D spatial field of the generated beam through a stack of measured cross-sectional images. The output beams have the profile of Bessel function after intensity modulation, and the beams extend at least 50 mm while the lateral dimension of the spot remains nearly invariant. Furthermore, the self-healing property has also been investigated, and all the experimental results agree well with simulated results numerically calculated through beam propagation method. Our observations demonstrate that the DMD offers a simple and efficient method to generate Bessel beams with distinct nondiffracting and self-reconstruction behaviors. The generated Bessel beams will potentially expand the applications to the optical manipulation and high-resolution fluorescence imaging owing to the unique nondiffracting property.

  15. First-principles equation-of-state table of silicon and its effects on high-energy-density plasma simulations

    DOE PAGES

    Hu, S. X.; Gao, R.; Princeton Univ., Princeton, NJ; ...

    2017-04-21

    Using density-functional theory–based molecular-dynamics simulations, we have investigated the equation of state for silicon in a wide range of plasma density and temperature conditions of ρ=0.001–500g/cm3 and T=2000–108K. With these calculations, we have established a first-principles equation-of-state (FPEOS) table of silicon for high-energy-density (HED) plasma simulations. When compared with the widely used SESAME-EOS model (Table 3810), we find that the FPEOS-predicted Hugoniot is ~20% softer; for off-Hugoniot plasma conditions, the pressure and internal energy in FPEOS are lower than those of SESAME EOS for temperatures above T ≈ 1–10 eV (depending on density), while the former becomes higher in themore » low-T regime. The pressure difference between FPEOS and SESAME 3810 can reach to ~50%, especially in the warm-dense-matter regime. Implementing the FPEOS table of silicon into our hydrocodes, we have studied its effects on Si-target implosions. When compared with the one-dimensional radiation-hydrodynamics simulation using the SESAME 3810 EOS model, the FPEOS simulation showed that (1) the shock speed in silicon is ~10% slower; (2) the peak density of an in-flight Si shell during implosion is ~20% higher than the SESAME 3810 simulation; (3) the maximum density reached in the FPEOS simulation is ~40% higher at the peak compression; and (4) the final areal density and neutron yield are, respectively, ~30% and ~70% higher predicted by FPEOS versus the traditional simulation using SESAME 3810. All of these features can be attributed to the larger compressibility of silicon predicted by FPEOS. Furthermore, these results indicate that an accurate EOS table, like the FPEOS presented here, could be essential for the precise design of targets for HED experiments.« less

  16. High Energy Density Plasmas (HEDP) for studies of basic nuclear science relevant to Stellar and Big Bang Nucleosynthesis

    NASA Astrophysics Data System (ADS)

    Frenje, Johan

    2014-06-01

    Thermonuclear reaction rates and nuclear processes have been explored traditionally by means of conventional accelerator experiments, which are difficult to execute at conditions relevant to stellar nucleosynthesis. Thus, nuclear reactions at stellar energies are often studied through extrapolations from higher-energy data or in low-background underground experiments. Even when measurements are possible using accelerators at relevant energies, thermonuclear reaction rates in stars are inherently different from those in accelerator experiments. The fusing nuclei are surrounded by bound electrons in accelerator experiments, whereas electrons occupy mainly continuum states in a stellar environment. Nuclear astrophysics research will therefore benefit from an enlarged toolkit for studies of nuclear reactions. In this presentation, we report on the first use of High Energy Density Plasmas for studies of nuclear reactions relevant to basic nuclear science, stellar and Big Bang nucleosynthesis. These experiments were carried out at the OMEGA laser facility at University of Rochester and the National Ignition Facility (NIF) at Lawrence Livermore National Laboratory, in which spherical capsules were irradiated with powerful lasers to compress and heat the fuel to high enough temperatures and densities for nuclear reactions to occur. Four experiments will be highlighted in this presentation. In the first experiment, the differential cross section for the elastic neutron-triton (n-T) scattering at 14.1 MeV was measured with significantly higher accuracy than achieved in accelerator experiments. In the second experiment, the T(t,2n)4He reaction, a mirror reaction to the 3He(3He,2p)4He reaction that plays an important role in the proton-proton chain that transforms hydrogen into ordinary 4He in stars like our Sun, was studied at energies in the range 15-40 keV. In the third experiment, the 3He+3He solar fusion reaction was studied directly, and in the fourth experiment, we

  17. Theoretical Studies of Possible Synthetic Routes for the High Energy Density Material Td N4: Excited Electronic States

    NASA Technical Reports Server (NTRS)

    Lee, Timothy J.; Dateo, Christopher E.

    2001-01-01

    Vertical electronic excitation energies for single states have been computed for the high energy density material (HEDM) Td N4 in order to assess possible synthetic routes that originate from excited electronic states of N2 molecules. Several ab initio theoretical approaches have been used, including complete active space self-consistent field (CASSCF), state averaged CASSCF (SA-CASSCF), singles configuration interaction (CIS), CIS with second-order and third-order correlation corrections [CIS(D)) and CIS(3)], and linear response singles and doubles coupled-cluster (LRCCSD), which is the highest level of theory employed. Standard double zeta polarized (DZP) and triple zeta double polarized (TZ2P) one-particle basis sets were used. The CASSCF calculations are found to overestimate the excitation energies, while the SA-CASSCF approach rectifies this error to some extent, but not completely. The accuracy of the CIS calculations varied depending on the particular state, while the CIS(D), CIS(3), and LRCCSD results are in generally good agreement. Based on the LRCCSD calculations, the lowest six excited singlet states are 9.35(l(sup)T1), 10.01(l(sup)T2), 10.04(1(sup)A2), 10.07(1(sup)E), 10.12(2(sup)T1), and 10.42(2(sup)T2) eV above the ground state, respectively. Comparison of these excited state energies with the energies of possible excited states of N2+N2 fragments, leads us to propose that the most likely synthetic route for Td N4 involving this mechanism arises from combination of two bound quintet states of N2.

  18. First-principles equation-of-state table of silicon and its effects on high-energy-density plasma simulations

    NASA Astrophysics Data System (ADS)

    Hu, S. X.; Gao, R.; Ding, Y.; Collins, L. A.; Kress, J. D.

    2017-04-01

    Using density-functional theory-based molecular-dynamics simulations, we have investigated the equation of state for silicon in a wide range of plasma density and temperature conditions of ρ =0.001 -500 g /c m3 and T =2000 -108K . With these calculations, we have established a first-principles equation-of-state (FPEOS) table of silicon for high-energy-density (HED) plasma simulations. When compared with the widely used SESAME-EOS model (Table 3810), we find that the FPEOS-predicted Hugoniot is ˜20% softer; for off-Hugoniot plasma conditions, the pressure and internal energy in FPEOS are lower than those of SESAME EOS for temperatures above T ≈ 1-10 eV (depending on density), while the former becomes higher in the low-T regime. The pressure difference between FPEOS and SESAME 3810 can reach to ˜50%, especially in the warm-dense-matter regime. Implementing the FPEOS table of silicon into our hydrocodes, we have studied its effects on Si-target implosions. When compared with the one-dimensional radiation-hydrodynamics simulation using the SESAME 3810 EOS model, the FPEOS simulation showed that (1) the shock speed in silicon is ˜10% slower; (2) the peak density of an in-flight Si shell during implosion is ˜20% higher than the SESAME 3810 simulation; (3) the maximum density reached in the FPEOS simulation is ˜40% higher at the peak compression; and (4) the final areal density and neutron yield are, respectively, ˜30% and ˜70% higher predicted by FPEOS versus the traditional simulation using SESAME 3810. All of these features can be attributed to the larger compressibility of silicon predicted by FPEOS. These results indicate that an accurate EOS table, like the FPEOS presented here, could be essential for the precise design of targets for HED experiments.

  19. First-principles equation-of-state table of silicon and its effects on high-energy-density plasma simulations.

    PubMed

    Hu, S X; Gao, R; Ding, Y; Collins, L A; Kress, J D

    2017-04-01

    Using density-functional theory-based molecular-dynamics simulations, we have investigated the equation of state for silicon in a wide range of plasma density and temperature conditions of ρ=0.001-500g/cm^{3} and T=2000-10^{8}K. With these calculations, we have established a first-principles equation-of-state (FPEOS) table of silicon for high-energy-density (HED) plasma simulations. When compared with the widely used SESAME-EOS model (Table 3810), we find that the FPEOS-predicted Hugoniot is ∼20% softer; for off-Hugoniot plasma conditions, the pressure and internal energy in FPEOS are lower than those of SESAME EOS for temperatures above T ≈ 1-10 eV (depending on density), while the former becomes higher in the low-T regime. The pressure difference between FPEOS and SESAME 3810 can reach to ∼50%, especially in the warm-dense-matter regime. Implementing the FPEOS table of silicon into our hydrocodes, we have studied its effects on Si-target implosions. When compared with the one-dimensional radiation-hydrodynamics simulation using the SESAME 3810 EOS model, the FPEOS simulation showed that (1) the shock speed in silicon is ∼10% slower; (2) the peak density of an in-flight Si shell during implosion is ∼20% higher than the SESAME 3810 simulation; (3) the maximum density reached in the FPEOS simulation is ∼40% higher at the peak compression; and (4) the final areal density and neutron yield are, respectively, ∼30% and ∼70% higher predicted by FPEOS versus the traditional simulation using SESAME 3810. All of these features can be attributed to the larger compressibility of silicon predicted by FPEOS. These results indicate that an accurate EOS table, like the FPEOS presented here, could be essential for the precise design of targets for HED experiments.

  20. Slow positron beam generator for lifetime studies

    NASA Technical Reports Server (NTRS)

    Singh, Jag J. (Inventor); Eftekhari, Abe (Inventor); St.clair, Terry L. (Inventor)

    1991-01-01

    A slow positron beam generator uses a conductive source residing between two test films. Moderator pieces are placed next to the test film on the opposite side of the conductive source. A voltage potential is applied between the moderator pieces and the conductive source. Incident energetic positrons: (1) are emitted from the conductive source; (2) are passed through test film; and (3) isotropically strike moderator pieces before diffusing out of the moderator pieces as slow positrons, respectively. The slow positrons diffusing out of moderator pieces are attracted to the conductive source which is held at an appropriate potential below the moderator pieces. The slow positrons have to pass through the test films before reaching the conductive source. A voltage is adjusted so that the potential difference between the moderator pieces and the conductive source forces the positrons to stop in the test films. Measurable annihilation radiation is emitted from the test film when positrons annihilate (combine) with electrons in the test film.

  1. The study of hard x-ray emission and electron beam generation in wire array Z-pinch and X-pinch plasmas at university-scale generators

    NASA Astrophysics Data System (ADS)

    Shrestha, Ishor Kumar

    The studies of hard x-ray (HXR) emission and electron beam generation in Z-pinch plasmas are very important for Inertial Confinement Fusion (ICF) research and HXR emission application for sources of K-shell and L-shell radiation. Energetic electron beams from Z-pinch plasmas are potentially a problem in the development of ICF. The electron beams and the accompanying HXR emission can preheat the fuel of a thermonuclear target, thereby preventing the fuel compression from reaching densities required for the ignition of a fusion reaction. The photons above 3-4 keV radiated from a Z pinch can provide detailed information about the high energy density plasmas produced at stagnation. Hence, the investigation of characteristics of hard x-rays and electron beams produced during implosions of wire array loads on university scale-generators may provide important data for future ICF, sources of K-shell and L-shell radiations and basic plasma research. This dissertation presents the results of experimental studies of HXR and electron beam generation in wire-array and X-pinch on the 1.7 MA, 100-ns current rise time Zebra generator at University of Nevada, Reno and 1-MA 100-ns current rise-time Cornell Beam Research Accelerator (COBRA) at Cornell University. The experimental study of characteristics of HXR produced by multi-planar wire arrays, compact cylindrical wire array (CCWA) and nested cylindrical wire array (NCWA) made from Al, Cu, Mo, Ag, W and Au were analyzed. The dependence of the HXR yield and power on geometry of the load, the wire material, and load mass was observed. The presence of aluminum wires in the load with the main material such as stainless steel, Cu, Mo, Ag, W or Au in combined wire array decreases HXR yield. The comparison of emission characteristics of HXR and generation of electron beams in CCWA and NCWA on both the high impedance Zebra generator and low impedance COBRA generator were investigated. Some of the "cold" K- shell spectral lines (0.7-2.3

  2. AlGaN UV LED and Photodiodes Radiation Hardness and Space Qualifications and Their Applications in Space Science and High Energy Density Physics

    SciTech Connect

    Sun, K. X.

    2011-05-31

    This presentation provides an overview of robust, radiation hard AlGaN optoelectronic devices and their applications in space exploration & high energy density physics. Particularly, deep UV LED and deep UV photodiodes are discussed with regard to their applications, radiation hardness and space qualification. AC charge management of UV LED satellite payload instruments, which were to be launched in late 2012, is covered.

  3. Layer by layer assembly of ultrathin V2O5 anchored MWCNTs and graphene on textile fabrics for fabrication of high energy density flexible supercapacitor electrodes

    NASA Astrophysics Data System (ADS)

    Shakir, Imran; Ali, Zahid; Bae, Jihyun; Park, Jongjin; Kang, Dae Joon

    2014-03-01

    Among transition metal oxides, vanadium oxides have received relatively modest attention for supercapacitor applications. Yet, this material is abundant, relatively inexpensive and offer several oxidation states which can provide a broad range of redox reactions suitable for supercapacitor operation. Electrochemical supercapacitors based on nanostructured vanadium oxide (V2O5) suffer from relatively low energy densities as they have low surface area and poor electrical conductivities. To overcome these problems, we developed a layer by layer assembly (LBL) technique in which a graphene layer was alternatively inserted between MWCNT films coated with ultrathin (3 nm) V2O5. The insertion of a conductive spacer of graphene between the MWCNT films coated with V2O5 not only prevents agglomeration between the MWCNT films but also substantially enhances the specific capacitance by 67%, to as high as ~2590 F g-1. Furthermore, the LBL assembled multilayer supercapacitor electrodes exhibited an excellent cycling performance of >97%, capacitance retention over 5000 cycles and a high energy density of 96 W h kg-1 at a power density of 800 W kg-1. Our approach clearly offers an exciting opportunity for enhancing the device performance of metal oxide-based electrochemical supercapacitors suitable for next-generation flexible energy storage devices by employing a facile LBL assembly technique.Among transition metal oxides, vanadium oxides have received relatively modest attention for supercapacitor applications. Yet, this material is abundant, relatively inexpensive and offer several oxidation states which can provide a broad range of redox reactions suitable for supercapacitor operation. Electrochemical supercapacitors based on nanostructured vanadium oxide (V2O5) suffer from relatively low energy densities as they have low surface area and poor electrical conductivities. To overcome these problems, we developed a layer by layer assembly (LBL) technique in which a graphene layer

  4. OZSPEC-2: An improved broadband high-resolution elliptical crystal x-ray spectrometer for high-energy density physics experiments (invited)

    SciTech Connect

    Heeter, R. F.; Anderson, S. G.; Booth, R.; Brown, G. V.; Emig, J.; Fulkerson, S.; McCarville, T.; Norman, D.; Schneider, M. B.; Young, B. K. F.

    2008-10-15

    A novel time, space, and energy-resolved x-ray spectrometer has been developed which produces, in a single snapshot, a broadband and relatively calibrated spectrum of the x-ray emission from a high-energy density laboratory plasma. The opacity zipper spectrometer (OZSPEC-1) records a nearly continuous spectrum for x-ray energies from 240 to 5800 eV in a single shot. The second-generation OZSPEC-2, detailed in this work, records fully continuous spectra on a single shot from any two of these three bands: 270-650, 660-1580, and 1960-4720 eV. These instruments thus record thermal and line radiation from a wide range of plasmas. These instruments' single-shot bandwidth is unmatched in a time-gated spectrometer; conversely, other broadband instruments are either time-integrated (using crystals or gratings), lack spectral resolution (diode arrays), or cover a lower energy band (gratings). The OZSPECs are based on the zipper detector, a large-format (100x35 mm) gated microchannel plate detector, with spectra dispersed along the 100 mm dimension. OZSPEC-1 and -2 both use elliptically bent crystals of OHM, RAP, and/or PET. Individual spectra are gated in 100 ps. OZSPEC-2 provides one-dimensional spatial imaging with 30-50 {mu}m resolution over a 1500 {mu}m field of view at the source. The elliptical crystal design yields broad spectral coverage with resolution E/{delta}E>500, strong rejection of hard x-ray backgrounds, and negligible source broadening for extended sources. Near-term applications include plasma opacity measurements, detailed spectra of inertial fusion Hohlraums, and laboratory astrophysics experiments.

  5. OZSPEC-2: an improved broadband high-resolution elliptical crystal x-ray spectrometer for high-energy density physics experiments (invited).

    PubMed

    Heeter, R F; Anderson, S G; Booth, R; Brown, G V; Emig, J; Fulkerson, S; McCarville, T; Norman, D; Schneider, M B; Young, B K F

    2008-10-01

    A novel time, space, and energy-resolved x-ray spectrometer has been developed which produces, in a single snapshot, a broadband and relatively calibrated spectrum of the x-ray emission from a high-energy density laboratory plasma. The opacity zipper spectrometer (OZSPEC-1) records a nearly continuous spectrum for x-ray energies from 240 to 5800 eV in a single shot. The second-generation OZSPEC-2, detailed in this work, records fully continuous spectra on a single shot from any two of these three bands: 270-650, 660-1580, and 1960-4720 eV. These instruments thus record thermal and line radiation from a wide range of plasmas. These instruments' single-shot bandwidth is unmatched in a time-gated spectrometer; conversely, other broadband instruments are either time-integrated (using crystals or gratings), lack spectral resolution (diode arrays), or cover a lower energy band (gratings). The OZSPECs are based on the zipper detector, a large-format (100x35 mm) gated microchannel plate detector, with spectra dispersed along the 100 mm dimension. OZSPEC-1 and -2 both use elliptically bent crystals of OHM, RAP, and/or PET. Individual spectra are gated in 100 ps. OZSPEC-2 provides one-dimensional spatial imaging with 30-50 microm resolution over a 1500 microm field of view at the source. The elliptical crystal design yields broad spectral coverage with resolution E/DeltaE>500, strong rejection of hard x-ray backgrounds, and negligible source broadening for extended sources. Near-term applications include plasma opacity measurements, detailed spectra of inertial fusion Hohlraums, and laboratory astrophysics experiments.

  6. Generation of attenuation-compensating Airy beams.

    PubMed

    Preciado, Miguel A; Dholakia, Kishan; Mazilu, Michael

    2014-08-15

    We present an attenuation-corrected "nondiffracting" Airy beam. The correction factor can be adjusted to deliver a beam that exhibits an adjustable exponential intensity increase or decrease over a finite distance. A digital micromirror device that shapes both amplitude and phase is used to experimentally verify the propagation of these beams through air and partially absorbing media.

  7. Generation and control of Bessel beams based on annular reflections

    NASA Astrophysics Data System (ADS)

    Wang, Yongdong; Qu, Weijuan; Jiao, Lishi; Zhang, Yilei

    2015-05-01

    A straightforward but powerful method to generate Bessel beams with continuous control of spot size, intensity and non-diffraction zone length has been successfully developed and verified based on annular reflections using a digital micromirror device (DMD). Reflective circular ring patterns were loaded in a DMD placed in the focal point of a converging lens to generate Bessel beams with tremendous flexibility and control. A Mach-Zehnder interferometer method was applied to reconstruct the wavefront of the generated beam to prove the successful generation of the Bessel beam. This simple but powerful method has great potential in many applications, such as imaging and particle manipulation.

  8. Electron beam generation in Tevatron electron lenses

    SciTech Connect

    Kamerdzhiev, V.; Kuznetsov, G.; Shiltsev, V.; Solyak, N.; Tiunov, M.; /Novosibirsk, IYF

    2006-08-01

    New type of high perveance electron guns with convex cathode has been developed. Three guns described in this article are built to provide transverse electron current density distributions needed for Electron Lenses for beam-beam compensation in the Tevatron collider. The current distribution can be controlled either by the gun geometry or by voltage on a special control electrode located near cathode. We present the designs of the guns and report results of beam measurements on the test bench. Because of their high current density and low transverse temperature of electrons, electron guns of this type can be used in electron cooling and beam-beam compensation devices.

  9. Efficient Generation of Truncated Bessel Beams using Cylindrical Waveguides

    NASA Technical Reports Server (NTRS)

    Ilchenko, Vladimir S.; Mohageg, Makan; Savchenkov, Anatoliy A.; Matsko, Andrey B.; Maleki, Lute

    2007-01-01

    In this paper we address efficient conversion between a Gaussian beam (a truncated plane wave) and a truncated Bessel beam of agiven order, using cylindrical optical waveguides and whispering gallery mode resonators. Utilizing a generator based on waveguides combined with whispering gallery mode resonators, we have realized Bessel beams of the order of 200 with a conversion efficiency exceeding 10 %.

  10. Design method of coaxial reflex hollow beam generator

    NASA Astrophysics Data System (ADS)

    Wang, Jiake; Xu, Jia; Fu, Yuegang; He, Wenjun; Zhu, Qifan

    2016-10-01

    In view of the light energy loss in central obscuration of coaxial reflex optical system, the design method of a kind of hollow beam generator is introduced. First of all, according to the geometrical parameter and obscuration ratio of front-end coaxial reflex optical system, calculate the required physical dimension of hollow beam, and get the beam expanding rate of the hollow beam generator according to the parameters of the light source. Choose the better enlargement ratio of initial expanding system using the relational expression of beam expanding rate and beam expanding rate of initial system; the traditional design method of the reflex optical system is used to design the initial optical system, and then the position of rotation axis of the hollow beam generator can be obtained through the rotation axis translation formula. Intercept the initial system bus bar using the rotation axis after the translation, and rotate the bus bar around the rotation axis for 360°, so that two working faces of the hollow beam generator can be got. The hollow beam generator designed by this method can get the hollow beam that matches the front-end coaxial reflex optical system, improving the energy utilization ratio of beam and effectively reducing the back scattering of transmission system.

  11. Generation and application of bessel beams in electron microscopy.

    PubMed

    Grillo, Vincenzo; Harris, Jérémie; Gazzadi, Gian Carlo; Balboni, Roberto; Mafakheri, Erfan; Dennis, Mark R; Frabboni, Stefano; Boyd, Robert W; Karimi, Ebrahim

    2016-07-01

    We report a systematic treatment of the holographic generation of electron Bessel beams, with a view to applications in electron microscopy. We describe in detail the theory underlying hologram patterning, as well as the actual electron-optical configuration used experimentally. We show that by optimizing our nanofabrication recipe, electron Bessel beams can be generated with relative efficiencies reaching 37±3%. We also demonstrate by tuning various hologram parameters that electron Bessel beams can be produced with many visible rings, making them ideal for interferometric applications, or in more highly localized forms with fewer rings, more suitable for imaging. We describe the settings required to tune beam localization in this way, and explore beam and hologram configurations that allow the convergences and topological charges of electron Bessel beams to be controlled. We also characterize the phase structure of the Bessel beams generated with our technique, using a simulation procedure that accounts for imperfections in the hologram manufacturing process.

  12. Transverse Mode Electron Beam Microwave Generator

    NASA Technical Reports Server (NTRS)

    Wharton, Lawrence E.

    1994-01-01

    An electron beam microwave device having an evacuated interaction chamber to which are coupled a resonant cavity which has an opening between the resonant cavity and the evacuated interaction chamber and an electron gun which causes a narrow beam of electrons to traverse the evacuated interaction chamber. The device also contains a mechanism for feeding back a microwave electromagnetic field from the resonant cavity to the evacuated interaction chamber in such a way as to modulate the direction of propagation of the electron beam, thereby further amplifyjng the microwave electromagnetic field. Furthermore, provision is made for coupling the electromagnetic field out of the electron beam microwave device.

  13. Note: a simple experimental arrangement to generate optical vortex beams.

    PubMed

    Kumar, Dhirendra; Das, Abhijit; Boruah, Bosanta R

    2013-02-01

    In this Note, we present a simple experimental arrangement to generate optical vortex beams. We have demonstrated how by taking print of an interferogram on a transparent sheet, vortex beams with various topological charges can be generated. Experimental results show that the vortex beam indeed carries the topological charge that is used to compute the interferograms. In addition to being simple and inexpensive, one major advantage of the arrangement is that it makes it possible to generate different vortex beams quickly, unlike using the photographic process to create the holograms.

  14. Plasmonic Airy beam generated by in-plane diffraction.

    PubMed

    Li, L; Li, T; Wang, S M; Zhang, C; Zhu, S N

    2011-09-16

    We report an experimental realization of a plasmonic Airy beam, which is generated thoroughly on a silver surface. With a carefully designed nanoarray structure, such Airy beams come into being from an in-plane propagating surface plasmon polariton wave, exhibiting nonspreading, self-bending, and self-healing properties. Besides, a new phase-tuning method based on nonperfectly matched diffraction processes is proposed to generate and modulate the beam almost at will. This unique plasmonic Airy beam as well as the generation method would significantly promote the evolutions in in-plane surface plasmon polariton manipulations and indicate potential applications in lab-on-chip photonic integrations.

  15. Nitrogen-doped carbon spheres: A new high-energy-density and long-life pseudo-capacitive electrode material for electrochemical flow capacitor.

    PubMed

    Hou, Shujin; Wang, Miao; Xu, Xingtao; Li, Yandong; Li, Yanjiang; Lu, Ting; Pan, Likun

    2017-04-01

    One of the most challenging issues in developing electrochemical flow capacitor (EFC) technology is the design and synthesis of active electrode materials with high energy density and long cycle life. However, in practical cases, the energy density and cycle ability obtained currently cannot meet the practical need. In this work, we propose a new active material, nitrogen-doped carbon spheres (NCSs), as flowable electrodes for EFC application. The NCSs were prepared via one-pot hydrothermal synthesis in the presence of resorcinol/formaldehyde as carbon precursors and melamine as nitrogen precursor, followed by carbonization in nitrogen flow at various temperatures. The results of EFC experiments demonstrate that NCSs obtained at 800°C exhibit a high energy density of 13.5Whkg(-1) and an excellent cycle ability, indicating the superiority of NCSs for EFC application.

  16. Generation of singular optical beams from fundamental Gaussian beam using Sagnac interferometer

    NASA Astrophysics Data System (ADS)

    Naik, Dinesh N.; Viswanathan, Nirmal K.

    2016-09-01

    We propose a simple free-space optics recipe for the controlled generation of optical vortex beams with a vortex dipole or a single charge vortex, using an inherently stable Sagnac interferometer. We investigate the role played by the amplitude and phase differences in generating higher-order Gaussian beams from the fundamental Gaussian mode. Our simulation results reveal how important the control of both the amplitude and the phase difference between superposing beams is to achieving optical vortex beams. The creation of a vortex dipole from null interference is unveiled through the introduction of a lateral shear and a radial phase difference between two out-of-phase Gaussian beams. A stable and high quality optical vortex beam, equivalent to the first-order Laguerre-Gaussian beam, is synthesized by coupling lateral shear with linear phase difference, introduced orthogonal to the shear between two out-of-phase Gaussian beams.

  17. Beam splitter and method for generating equal optical path length beams

    DOEpatents

    Qian, Shinan; Takacs, Peter

    2003-08-26

    The present invention is a beam splitter for splitting an incident beam into first and second beams so that the first and second beams have a fixed separation and are parallel upon exiting. The beam splitter includes a first prism, a second prism, and a film located between the prisms. The first prism is defined by a first thickness and a first perimeter which has a first major base. The second prism is defined by a second thickness and a second perimeter which has a second major base. The film is located between the first major base and the second major base for splitting the incident beam into the first and second beams. The first and second perimeters are right angle trapezoidal shaped. The beam splitter is configured for generating equal optical path length beams.

  18. Novel vortex generator and mode converter for electron beams.

    PubMed

    Schattschneider, P; Stöger-Pollach, M; Verbeeck, J

    2012-08-24

    A mode converter for electron vortex beams is described. Numerical simulations, confirmed by experiment, show that the converter transforms a vortex beam with a topological charge m=±1 into beams closely resembling Hermite-Gaussian HG(10) and HG(01) modes. The converter can be used as a mode discriminator or filter for electron vortex beams. Combining the converter with a phase plate turns a plane wave into modes with topological charge m=±1. This combination serves as a generator of electron vortex beams of high brilliance.

  19. Gaussian entanglement generation from coherence using beam-splitters

    NASA Astrophysics Data System (ADS)

    Wang, Zhong-Xiao; Wang, Shuhao; Ma, Teng; Wang, Tie-Jun; Wang, Chuan

    2016-11-01

    The generation and quantification of quantum entanglement is crucial for quantum information processing. Here we study the transition of Gaussian correlation under the effect of linear optical beam-splitters. We find the single-mode Gaussian coherence acts as the resource in generating Gaussian entanglement for two squeezed states as the input states. With the help of consecutive beam-splitters, single-mode coherence and quantum entanglement can be converted to each other. Our results reveal that by using finite number of beam-splitters, it is possible to extract all the entanglement from the single-mode coherence even if the entanglement is wiped out before each beam-splitter.

  20. Pulsed electron beam generator for application in materials science

    NASA Astrophysics Data System (ADS)

    Geerk, J.; Ratzel, F.

    1980-08-01

    A pulsed electron beam generator for the purpose of transient annealing was developed. The principle of operation of the generator is the production of an electron beam by means of a triggered vacuum discharge burning between metallic electrodes. The maximum energy of the electrons of a pulsed beam may be varied between 10 keV and 25 keV. The pulse length is about 300 nsec. The energy density at the sample location can be easily adjusted between 0.3 and 2.5 Joules/cm(2). The diameter of the electron beam is about 5 cm.

  1. Development and characterization of high temperature, high energy density dielectric materials to establish routes towards power electronics capacitive devices

    NASA Astrophysics Data System (ADS)

    Shay, Dennis P.

    The maximum electrostatic energy density of a capacitor is a function of the relative permittivity (epsilonr) and the square of the dielectric breakdown strength (Eb). Currently, state-of-the art high temperature (>200 °C), SiC-based power electronics utilize CaZrO3-rich NP0/C0G-type capacitors, which have low relative permittivities of epsilonr ˜ 30-40, high breakdown strengths (> 1.0 MV/cm), and are chosen for their minimal change in energy storage with temperature. However, with operating temperatures exceeding the rated temperatures for such capacitors, there is an opportunity to develop new dielectric ceramics having higher energy densities and volumetric efficiencies at high temperatures (>200 °C) by utilizing higher permittivity dielectrics while maintaining high breakdown strengths via doping. The solid solution behavior of was characterized in order to determine the optimal composition for balancing permittivity and dielectric breakdown strength to obtain high energy densities at elevated temperatures. Characterization by X-ray diffraction (XRD) showed Vegard's law behavior across the solid solution with minimal 2nd phases. To determine a Ca(TixZr1-x)O3 composition that will also minimize electronic or band conduction, the optical properties of the Ca(TixZr1-x)O3 solid solution were investigated to identify a composition on the CaTiO3 - rich end of the solid solution with a large band gap. Both ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis) and spectroscopic ellipsometry were utilized to determine the Ca(TixZr1-x)O3 band gaps and optical properties. The resistivity at 250 °C scaled with the band gap energy across the solid solution. Comparing the current-voltage (I--V) behavior at 250 °C for Ca(Tix-yMnyZr0.2)O3 (CTZ + Mn) where x = 0.7, 0.8, 0.9, and y = 0.005, it was found that the Ca(Ti 0.795Mn0.005Zr0.2)O3 composition showed the lowest current density and a decrease in current density of 5 orders of magnitude compared to the un

  2. A reflex electron beam discharge as a plasma source for electron beam generation

    SciTech Connect

    Murray, C.S.; Rocca, J.J.; Szapiro, B. )

    1988-10-01

    A reflex electron beam glow discharge has been used as a plasma source for the generation of broad-area electron beams. An electron current of 120 A (12 A/cm/sup 2/) was extracted from the plasma in 10 ..mu..s pulses and accelerated to energies greater than 1 keV in the gap between two grids. The scaling of the scheme for the generation of multikiloamp high-energy beams is discussed.

  3. Generation of pulsed ion beams by an inductive storage pulsed power generator

    NASA Astrophysics Data System (ADS)

    Katsuki, Sunao; Akiyama, Hidenori; Maeda, Sadao

    1990-10-01

    A pulsed power generator by an inductive energy storage system is extremely compact and light in comparison with a conventional pulsed power generator, which consists of a Marx bank and a water pulse forming line. A compact and light pulse power generator is applied to the generation of pulsed ion beams. A thin copper fuse is used an an opening switch, which is necessary in the inductive storage pulsed power generator. A magnetically insulated diode is used for the generation of ion beams. The pulsed ion beams are successfully generated by the inductive storage pulsed power generator for the first time.

  4. Generation of tunable radially polarized array beams by controllable coherence

    NASA Astrophysics Data System (ADS)

    Wang, Jing; Zhang, Jipeng; Zhu, Shijun; Li, Zhenhua

    2017-05-01

    In this paper, a new method for converting a single radial polarization beam into an arbitrary radially polarized array (RPA) beam such as a radial or rectangular symmetry array in the focal plane by modulating a periodic correlation structure is introduced. The realizability conditions for such source and the beam condition for radiation generated by such source are derived. It is illustrated that both the amplitude and the polarization are controllable by means of initial correlation structure and coherence parameter. Furthermore, by designing the source correlation structure, a tunable NUST-shaped RPA beam is demonstrated, which can find widespread applications in micro-nano engineering. Such a method for generation of arbitrary vector array beams is useful in beam shaping and optical tweezers.

  5. Generating a cylindrical vector beam interferometrically for ellipsometric measurement

    NASA Astrophysics Data System (ADS)

    Chen, Jing-Heng; Chang, Ruey-Shyan; Han, Chien-Yuan

    2016-02-01

    Cylindrical vector beams have been widely used in material processing, lithography, optical trapping and manipulating. However, few works discussed their application in polarization metrology. A cylindrical vector beam generated by a concrete interferometer setup is employed to determine the ellipsometric parameters of thin films, which was discussed in this work. A TEM01 mode beam was applied as the light source impinging into a modified Michelson interferometer with contiguous optical elements. The mode of light beam was transformed and the polarization states were coordinated with the optical configuration that made the output beam a doughnut-shaped axially symmetric polarized beam. In addition, the output beam plays the same role as rotating polarization element configuration of an ellipsometer. However, the polarization modulation was in spatial domain instead of temporal domain. By making use of this configuration, ellipsometric parameters of thin films were deduced and the results were very close to theoretical values.

  6. Generation of stochastic electromagnetic beams with complete controllable coherence.

    PubMed

    Chen, Xudong; Chang, Chengcheng; Chen, Ziyang; Lin, Zhili; Pu, Jixiong

    2016-09-19

    We generate a stochastic electromagnetic beam (SEB) with complete controllable coherence, that is, the coherence degree can be controlled independently along two mutually perpendicular directions. We control the coherence of the SEB by adjusting the phase modulation magnitude applied onto two crossed phase only spatial light modulators. We measure the beam's coherence properties using Young's interference experiment, as well as the beam propagation factor. It is shown that the experimental results are consistent with our theoretical predictions.

  7. Highly efficient electron vortex beams generated by nanofabricated phase holograms

    SciTech Connect

    Grillo, Vincenzo; Mafakheri, Erfan; Frabboni, Stefano

    2014-01-27

    We propose an improved type of holographic-plate suitable for the shaping of electron beams. The plate is fabricated by a focused ion beam on a silicon nitride membrane and introduces a controllable phase shift to the electron wavefunction. We adopted the optimal blazed-profile design for the phase hologram, which results in the generation of highly efficient (25%) electron vortex beams. This approach paves the route towards applications in nano-scale imaging and materials science.

  8. BMEWS Radar Beam Generation and Projection Clear Air Force ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    BMEWS Radar Beam Generation and Projection - Clear Air Force Station, Ballistic Missile Early Warning System Site II, One mile west of mile marker 293.5 on Parks Highway, 5 miles southwest of Anderson, Anderson, Denali Borough, AK

  9. The National Ignition Facility: Status and Plans for Laser Fusion and High-Energy-Density Experimental Studies

    SciTech Connect

    Moses, Edward I.; Wuest, Craig R.

    2003-05-15

    The National Ignition Facility (NIF), currently under construction at the University of California's Lawrence Livermore National Laboratory, is a stadium-sized facility containing a 192-beam, 1.8-MJ, 500-TW, 351-nm laser system and a 10-m-diam target chamber with room for nearly 100 experimental diagnostics. NIF is being built by the National Nuclear Security Administration and when completed will be the world's largest laser experimental system, providing a national center to study inertial confinement fusion and the physics of matter at extreme energy densities and pressures. NIF will provide 192 energetic laser beams that will compress small fusion targets to conditions where they will ignite and burn, liberating more energy than is required to initiate the fusion reactions. NIF experiments will allow the study of physical processes at temperatures approaching 100 million K and 100 billion times atmospheric pressure. These conditions exist naturally only in the interior of stars and in nuclear weapons explosions. In the course of designing the world's most energetic laser system, a number of significant technology breakthroughs have been achieved. Research is also underway to develop a shorter pulse capability on NIF for very high power and extreme electromagnetic field research and applications. We discuss here the technology challenges and solutions that have made NIF possible, along with enhancements to NIF's design that could lead to near-exawatt power levels.

  10. The National Ignition Facility: Status and Plans for Laser Fusion and High-Energy-Density Experimental Studies

    SciTech Connect

    Moses, E I; Wuest, C R

    2002-10-16

    The National Ignition Facility (NIF), currently under construction at the University of California's Lawrence Livermore National Laboratory, is a stadium-sized facility containing a 192-beam, 1.8-Megajoule, 500-Terawatt, 351-nm laser system and a 10-meter diameter target chamber with room for nearly 100 experimental diagnostics. NIF is being built by the National Nuclear Security Administration and when completed will be the world's largest laser experimental system, providing a national center to study inertial confinement fusion and the physics of matter at extreme energy densities and pressures. NIF will provide 192 energetic laser beams that will compress small fusion targets to conditions where they will ignite and burn, liberating more energy than is required to initiate the fusion reactions. NIF experiments will allow the study of physical processes at temperatures approaching 100 million K and 100 billion times atmospheric pressure. These conditions exist naturally only in the interior of stars and in nuclear weapons explosions. In the course of designing the world's most energetic laser system, a number of significant technology breakthroughs have been achieved. Research is also underway to develop a shorter pulse capability on NIF for very high power and extreme electromagnetic field research and applications. We discuss here the technology challenges and solutions that have made NIF possible, along with enhancements to NIF's design that could lead to near-exawatt power levels.

  11. The National Ignition Facility: Status and Plans for Laser Fusion and High-Energy-Density Experimental Studies

    SciTech Connect

    Moses, E I

    2002-01-11

    The National Ignition Facility (NIF), currently under construction at the University of California's Lawrence Livermore National Laboratory is a $2.25B stadium-sized facility containing a 192-beam, 1.8-Megajoule, 500-Terawatt, 351-nm laser system. NIF is being built by the National Nuclear Security Agency and when completed will be the world's largest laser system, providing a national center to study inertial confinement fusion and the physics of extreme energy densities and pressures. In NIF up to 192 energetic laser beams will compress small fusion targets to conditions where they will ignite and burn, liberating more energy than is required to initiate the fusion reactions. NIF experiments will allow the study of physical processes at temperatures approaching 100 million K and 100 billion times atmospheric pressure. These conditions exist naturally only in the interior of stars and in nuclear weapons explosions. In the course of designing the world's most energetic laser system, a number of significant technology breakthroughs have been achieved. Research is also underway to develop a shorter pulse capability on NIF for high power applications. We discuss here the technology challenges and solutions that have made NIF possible along with enhancements to NIF's design that could lead to exawatt power levels.

  12. Dispensing targets for ion beam particle generators

    NASA Technical Reports Server (NTRS)

    Miller, C. G. (Inventor)

    1974-01-01

    A target for dispensing high energy protons or neutrons or ionized atoms or ionized molecules is provided which comprises a container for the target gas, which is at atmospheric or higher pressure. The container material can release the target gas in the spot where the container is heated above a predetermined temperature by the impact of an ion beam where protons or neutrons are desired, or by electrons where ionized atoms or molecules are desired. On the outside of the container, except for the region where the beam is to impact, there is deposited a layer of a metal which is imperious to gaseous diffusion. A further protective coating of a material is placed over the layer of metal, except at the region of the ion impact area in order to adsorb any unreacted gas in the vacuum in which the target is placed, to thereby prevent reduction of the high vacuum, as well as contamination of the interior of the vacuum chamber.

  13. Two-color beam generation based on wakefield excitation

    NASA Astrophysics Data System (ADS)

    Bettoni, S.; Prat, E.; Reiche, S.

    2016-05-01

    Several beam manipulation methods have been studied and experimentally tested to generate two-color photon beams in free electron laser facilities to accommodate the user requests. We propose to use the interaction of the beam with an oscillating longitudinal wakefield source to obtain a suitable electron beam structure. The bunch generates two subpulses with different energies and delayed in time passing through a magnetic chicane after its longitudinal phase space has been modulated by the wakefield source. According to this approach the power of the emitted radiation is not degraded compared to the monochromatic beam, and the setup in the machine is quite simple because the bunch is manipulated only in the high energy section, where it is more rigid. We present the design applied to SwissFEL. We identified the parameters and the corresponding range of tunability of the time and energy separation among the two subbunches.

  14. Hybrid generation and analysis of vector vortex beams.

    PubMed

    Mamani, Sandra; Bendau, Ethan; Secor, Jeff; Ashrafi, Solyman; Tu, Jiufeng J; Alfano, Robert R

    2017-03-10

    A method is described for generating optical vector vortex beams carrying superpositions of orbital angular momentum states by using a tandem application of a spatial light modulator with a vortex retarder. The vortex component has a spatially inhomogeneous phase front that can carry orbital angular momentum, and the vector nature is a spatially inhomogeneous state of polarization in the laser beam profile. The vector vortex beams are characterized experimentally by imaging the beams at points across the focal plane in an astigmatic system using a tilted lens. Mathematical analysis of the Gouy phase shows good agreement with the phase structure obtained in the experimental images. The polarization structure of the vector beam and the orbital angular momentum of the vortex beam are shown to be preserved.

  15. Development of a long-life, high-reliability, high-energy-density, repetitive-pulse, capacitor technology

    NASA Astrophysics Data System (ADS)

    Mauldin, G. H.; Nunnally, W. C.; Thompson, M. C.; Sarjeant, W. J.

    Evolving power conditioning system requirements in the areas of magnetic confinement fusion, inertial confinement fusion, ion propulsion engines, particle beam technology, radar, communications, and medical electronics will place severe demands upon repetitive pulse power system components. The energy storage capacitor is one principal system pacing component. A unique capacitor technology which is reliable and space efficient was developed. This technology is based upon impregnation of plastic film capacitor rolls with perfluorocarbon insulating liquids. A 300-kW capacitor discharge test facility was activated. This facility allows testing at high average powers and high repetition rates. It employs extensive diagnostic instrumentation which allows sophisticated analysis of the test results. The test facility and test results are described.

  16. Preparation of silicon@silicon oxide core-shell nanowires from a silica precursor toward a high energy density Li-ion battery anode.

    PubMed

    Zhang, Chuanjian; Gu, Lin; Kaskhedikar, Nitin; Cui, Guanglei; Maier, Joachim

    2013-12-11

    Bulk-quantity silicon@silicon oxide nanowires have been successfully synthesized via a facile high-temperature approach using environment-friendly silica mixed with titanium powders. It is confirmed that the obtained nanowires process a crystalline core and amorphous oxide sheath. The obtained nanowires grow along the [111] direction which catalyzed by spherical silicon@siilcon oxide nanoparticles. The unique one-dimensional structure and thin oxide sheath result in the favorable electrochemical performances, which may be beneficial to the high energy density silicon anode for lithium ion batteries.

  17. Particle beam generator using a radioactive source

    DOEpatents

    Underwood, D.G.

    1993-03-30

    The apparatus of the present invention selects from particles emitted by a radioactive source those particles having momentum within a desired range and focuses the selected particles in a beam having at least one narrow cross-dimension, and at the same time attenuates potentially disruptive gamma rays and low energy particles. Two major components of the present invention are an achromatic bending and focusing system, which includes sector magnets and quadrupole, and a quadrupole doublet final focus system. Permanent magnets utilized in the apparatus are constructed of a ceramic (ferrite) material which is inexpensive and easily machined.

  18. Particle beam generator using a radioactive source

    DOEpatents

    Underwood, David G.

    1993-01-01

    The apparatus of the present invention selects from particles emitted by a radioactive source those particles having momentum within a desired range and focuses the selected particles in a beam having at least one narrow cross-dimension, and at the same time attenuates potentially disruptive gamma rays and low energy particles. Two major components of the present invention are an achromatic bending and focusing system, which includes sector magnets and quadrupole, and a quadrupole doublet final focus system. Permanent magnets utilized in the apparatus are constructed of a ceramic (ferrite) material which is inexpensive and easily machined.

  19. Radiation sources with planar wire arrays and planar foils for inertial confinement fusion and high energy density physics research

    NASA Astrophysics Data System (ADS)

    Kantsyrev, V. L.; Chuvatin, A. S.; Safronova, A. S.; Rudakov, L. I.; Esaulov, A. A.; Velikovich, A. L.; Shrestha, I.; Astanovitsky, A.; Osborne, G. C.; Shlyaptseva, V. V.; Weller, M. E.; Keim, S.; Stafford, A.; Cooper, M.

    2014-03-01

    This article reports on the joint success of two independent lines of research, each of them being a multi-year international effort. One of these is the development of innovative sources, such as planar wire arrays (PWAs). PWAs turned out to be a prolific radiator, which act mainly as a resistor, even though the physical mechanism of efficient magnetic energy conversion into radiation still remains unclear. We review the results of our extensive studies of PWAs. We also report the new results of the experimental comparison PWAs with planar foil liners (another promising alternative to wire array loads at multi-mega-ampere generators). Pioneered at UNR, the PWA Z-pinch loads have later been tested at the Sandia National Laboratories (SNL) on the Saturn generator, on GIT-12 machine in Russia, and on the QiangGuang-1 generator in China, always successfully. Another of these is the drastic improvement in energy efficiency of pulsed-power systems, which started in early 1980s with Zucker's experiments at Naval Research Laboratory (NRL). Successful continuation of this approach was the Load Current Multiplier (LCM) proposed by Chuvatin in collaboration with Rudakov and Weber from NRL. The 100 ns LCM was integrated into the Zebra generator, which almost doubled the plasma load current, from 0.9 to 1.7 MA. The two above-mentioned innovative approaches were used in combination to produce a new compact hohlraum radiation source for ICF, as jointly proposed by SNL and UNR [Jones et al., Phys. Rev. Lett. 104, 125001 (2010)]. The first successful proof-of-the-principle experimental implementation of new hohlraum concept at university-scale generator Zebra/LCM is demonstrated. A numerical simulation capability with VisRaD code (from PRISM Co.) established at UNR allowed for the study of hohlraum coupling physics and provides the possibility of optimization of a new hohlraum. Future studies are discussed.

  20. Radiation sources with planar wire arrays and planar foils for inertial confinement fusion and high energy density physics research

    SciTech Connect

    Kantsyrev, V. L.; Safronova, A. S.; Esaulov, A. A.; Shrestha, I.; Astanovitsky, A.; Osborne, G. C.; Shlyaptseva, V. V.; Weller, M. E.; Keim, S.; Stafford, A.; Cooper, M.; Chuvatin, A. S.; Rudakov, L. I.; Velikovich, A. L.

    2014-03-15

    This article reports on the joint success of two independent lines of research, each of them being a multi-year international effort. One of these is the development of innovative sources, such as planar wire arrays (PWAs). PWAs turned out to be a prolific radiator, which act mainly as a resistor, even though the physical mechanism of efficient magnetic energy conversion into radiation still remains unclear. We review the results of our extensive studies of PWAs. We also report the new results of the experimental comparison PWAs with planar foil liners (another promising alternative to wire array loads at multi-mega-ampere generators). Pioneered at UNR, the PWA Z-pinch loads have later been tested at the Sandia National Laboratories (SNL) on the Saturn generator, on GIT-12 machine in Russia, and on the QiangGuang-1 generator in China, always successfully. Another of these is the drastic improvement in energy efficiency of pulsed-power systems, which started in early 1980s with Zucker's experiments at Naval Research Laboratory (NRL). Successful continuation of this approach was the Load Current Multiplier (LCM) proposed by Chuvatin in collaboration with Rudakov and Weber from NRL. The 100 ns LCM was integrated into the Zebra generator, which almost doubled the plasma load current, from 0.9 to 1.7 MA. The two above-mentioned innovative approaches were used in combination to produce a new compact hohlraum radiation source for ICF, as jointly proposed by SNL and UNR [Jones et al., Phys. Rev. Lett. 104, 125001 (2010)]. The first successful proof-of-the-principle experimental implementation of new hohlraum concept at university-scale generator Zebra/LCM is demonstrated. A numerical simulation capability with VisRaD code (from PRISM Co.) established at UNR allowed for the study of hohlraum coupling physics and provides the possibility of optimization of a new hohlraum. Future studies are discussed.