Scavenging of black carbon in mixed phase clouds at the high alpine site Jungfraujoch

NASA Astrophysics Data System (ADS)

Cozic, J.; Verheggen, B.; Mertes, S.; Connolly, P.; Bower, K.; Petzold, A.; Baltensperger, U.; Weingartner, E.

2006-11-01

The scavenging of black carbon (BC) in liquid and mixed phase clouds was investigated during intensive experiments in winter 2004, summer 2004 and winter 2005 at the high alpine research station Jungfraujoch (3580 m a.s.l., Switzerland). Aerosol residuals were sampled behind two well characterized inlets; a total inlet which collected cloud particles (drops and ice particles) as well as interstitial aerosol particles; an interstitial inlet which collected only interstitial (unactivated) aerosol particles. BC concentrations were measured behind each of these inlets along with the submicrometer aerosol number size distribution, from which a volume concentration was derived. These measurements were complemented by in-situ measurements of cloud microphysical parameters. BC was found to be scavenged into the cloud phase to the same extent as the bulk aerosol, which suggests that BC was covered with soluble material through aging processes, rendering it more hygroscopic. The scavenged fraction of BC (FScav,BC), defined as the fraction of BC that is incorporated into cloud droplets and ice crystals, decreases with increasing cloud ice mass fraction (IMF) from FScav,BC=60% in liquid phase clouds to FScav,BC~10% in mixed-phase clouds with IMF>0.2. This is explained by the evaporation of liquid droplets in the presence of ice crystals (Wegener-Bergeron-Findeisen process), releasing BC containing cloud condensation nuclei back into the interstitial phase. In liquid clouds, the scavenged BC fraction is found to decrease with decreasing cloud liquid water content. The scavenged BC fraction is also found to decrease with increasing BC mass concentration since there is an increased competition for the available water vapour.

The single-particle mixing state and cloud scavenging of black carbon: a case study at a high-altitude mountain site in southern China

NASA Astrophysics Data System (ADS)

Zhang, Guohua; Lin, Qinhao; Peng, Long; Bi, Xinhui; Chen, Duohong; Li, Mei; Li, Lei; Brechtel, Fred J.; Chen, Jianxin; Yan, Weijun; Wang, Xinming; Peng, Ping'an; Sheng, Guoying; Zhou, Zhen

2017-12-01

In the present study, a ground-based counterflow virtual impactor (GCVI) was used to sample cloud droplet residual (cloud RES) particles, while a parallel PM2.5 inlet was used to sample cloud-free or cloud interstitial (cloud INT) particles. The mixing state of black carbon (BC)-containing particles and the mass concentrations of BC in the cloud-free, RES and INT particles were investigated using a single-particle aerosol mass spectrometer (SPAMS) and two aethalometers, respectively, at a mountain site (1690 m a. s. l. ) in southern China. The measured BC-containing particles were extensively internally mixed with sulfate and were scavenged into cloud droplets (with number fractions of 0.05-0.45) to a similar (or slightly lower) extent as all the measured particles (0.07-0.6) over the measured size range of 0.1-1.6 µm. The results indicate the preferential activation of larger particles and/or that the production of secondary compositions shifts the BC-containing particles towards larger sizes. BC-containing particles with an abundance of both sulfate and organics were scavenged less than those with sulfate but limited organics, implying the importance of the mixing state on the incorporation of BC-containing particles into cloud droplets. The mass scavenging efficiency of BC with an average of 33 % was similar for different cloud events independent of the air mass. This is the first time that both the mixing state and cloud scavenging of BC in China have been reported. Our results would improve the knowledge on the concentration, mixing state, and cloud scavenging of BC in the free troposphere.

Scavenging of black carbon in mixed phase clouds at the high alpine site Jungfraujoch

NASA Astrophysics Data System (ADS)

Cozic, J.; Verheggen, B.; Mertes, S.; Connolly, P.; Bower, K.; Petzold, A.; Baltensperger, U.; Weingartner, E.

2007-04-01

The scavenging of black carbon (BC) in liquid and mixed phase clouds was investigated during intensive experiments in winter 2004, summer 2004 and winter 2005 at the high alpine research station Jungfraujoch (3580 m a.s.l., Switzerland). Aerosol residuals were sampled behind two well characterized inlets; a total inlet which collected cloud particles (droplets and ice particles) as well as interstitial (unactivated) aerosol particles; an interstitial inlet which collected only interstitial aerosol particles. BC concentrations were measured behind each of these inlets along with the submicrometer aerosol number size distribution, from which a volume concentration was derived. These measurements were complemented by in-situ measurements of cloud microphysical parameters. BC was found to be scavenged into the condensed phase to the same extent as the bulk aerosol, which suggests that BC was covered with soluble material through aging processes, rendering it more hygroscopic. The scavenged fraction of BC (FScav,BC), defined as the fraction of BC that is incorporated into cloud droplets and ice crystals, decreases with increasing cloud ice mass fraction (IMF) from FScav,BC=60% in liquid phase clouds to FScav,BC~5-10% in mixed-phase clouds with IMF>0.2. This can be explained by the evaporation of liquid droplets in the presence of ice crystals (Wegener-Bergeron-Findeisen process), releasing BC containing cloud condensation nuclei back into the interstitial phase. In liquid clouds, the scavenged BC fraction is found to decrease with decreasing cloud liquid water content. The scavenged BC fraction is also found to decrease with increasing BC mass concentration since there is an increased competition for the available water vapour.

Parameterization of aerosol scavenging due to atmospheric ionization under varying relative humidity

NASA Astrophysics Data System (ADS)

Zhang, Liang; Tinsley, Brian A.

2017-05-01

Simulations and parameterizations of the modulation of aerosol scavenging by electric charges on particles and droplets for different relative humidities have been made for 3 μm radii droplets and a wide range of particle radii. For droplets and particles with opposite-sign charges, the attractive Coulomb force increases the collision rate coefficients above values due to other forces. With same-sign charges, the repulsive Coulomb force decreases the rate coefficients, and the short-range attractive image forces become important. The phoretic forces are attractive for relative humidity less than 100% and repulsive for relative humidity greater than 100% and have increasing overall effect for particle radii up to about 1 μm. There is an analytic solution for rate coefficients if only inverse square forces are present, but due to the presence of image forces, and for larger particles the intercept, weight, and the flow around the particle affecting the droplet trajectory, the simulated results usually depart far from the analytic solution. We give simple empirical parameterization formulas for some cases and more complex parameterizations for more exact fits to the simulated results. The results can be used in cloud models with growing droplets, as in updrafts, as well as with evaporating droplets in downdrafts. There is considered to be little scavenging of uncharged ice-forming nuclei in updrafts, but with charged ice-forming nuclei it is possible for scavenging in updrafts in cold clouds to produce contact ice nucleation. Scavenging in updrafts below the freezing level produces immersion nuclei that promote enhanced freezing as droplets rise above it.

Constraints from Airborne (210)Pb Observations on Aerosol Scavenging and Lifetime in a Global Chemical Transport Model

NASA Technical Reports Server (NTRS)

Zhang, Bo; Liu, Hongyu; Crawford, James H.; Fairlie, Duncan T.; Chen, Gao; Dibb, Jack E.; Shah, Viral; Sulprizio, Melissa P.; Yantosca, Robert M.

2016-01-01

Lead-210 distribution and lifetime in the atmosphere are not sensitive to ice in-cloud scavenging in convective updraft. Ice in-cloud scavenging in stratiform clouds reduce tropospheric (210)Pb lifetime by approximately 1 day and results in better agreements with observed surface observations and aircraft measured profiles. However, the process results in significant underestimate of (210)Pb in UT/LS.

Clouds, Aerosol, and Precipitation in the Marine Boundary Layer: An ARM Mobile Facility Deployment

NASA Technical Reports Server (NTRS)

Wood, Robert; Wyant, Matthew; Bretherton, Christopher S.; Remillard, Jasmine; Kollias, Pavlos; Fletcher, Jennifer; Stemmler, Jayson; de Szoeke, Simone; Yuter, Sandra; Miller, Matthew;

The pH and ionic composition of stratiform cloud water

NASA Astrophysics Data System (ADS)

Castillo, Raymond A.; Jiusto, James E.; Mclaren, Eugene

Over 50 cloud water samples were collected during five comprehensive case studies of the water chemistry of stratiform clouds at Whiteface Mountain, New York. The water samples were analyzed for pH, conductivity and ions of sodium, potassium, magnesium, calcium, ammonium, sulfate, chloride and nitrate. Trajectory analyses and cloud condensation nucleus concentrations at 0.5 % confirmed that the air masses in all five of these cases represented continental air that was relatively clean (low aerosol concentration) for the northeystern United States. The major ions related to cloud water pH were found to be sulfate, nitrate, potassium, ammonium and calcium. The results revealed a mean hydrogen ion concentration [ H+] = 0.239 meq ℓ -1 ( σ = ± 0.21) which converts to a mean pH = 3.6 for all collected cloud samples. The low pH values are related to a normal background of nitrate ions found in the rural continental air masses plus sulfate ions largely from the industrial emissions of the midwestern United States. The [NO -3], in two of the three cases presented, demonstrates the importance of the nitrate ions' contribution to the pH of cloud water. A dependent means analysis of 40 events yielded a significant difference (0.04 level of significance), with the mean pH of precipitation (4.2) being greater than the mean pH of cloud water (4.0) for event samples. The ion concentrations indicated that the cloud rainout process contributed from 67 % to almost 100% of the total ion concentration of the precipitation. The washout process, i.e. precipitation scavenging below the cloud base, contributed considerably less than the cloud/rainout process of those total precipitation anions associated with air pollution.

Microbial ice nucleators scavenged from the atmosphere during simulated rain events

NASA Astrophysics Data System (ADS)

Hanlon, Regina; Powers, Craig; Failor, Kevin; Monteil, Caroline L.; Vinatzer, Boris A.; Schmale, David G.

2017-08-01

Rain and snow collected at ground level have been found to contain biological ice nucleators. These ice nucleators have been proposed to have originated in clouds, where they may have participated in the formation of precipitation via ice phase nucleation. We conducted a series of field experiments to test the hypothesis that at least some of the microbial ice nucleators (prokaryotes and eukaryotes) present in rain may not originate in clouds but instead be scavenged from the lower atmosphere by rainfall. Thirty-three simulated rain events were conducted over four months off the side of the Smart Road Bridge in Blacksburg, VA, USA. In each event, sterile water was dispensed over the side of the bridge and recovered in sterile containers in an open fallow agricultural field below (a distance of ∼55 m). Microbes scavenged from the simulated rain events were cultured and their ice nucleation activity was examined. Putative microbial ice nucleators were cultured from 94% (31/33) of the simulated rain events, and represented 1.5% (121/8331) of the total colonies assayed. Putative ice nucleators were subjected to additional droplet freezing assays, and those confirmed through these repeated assays represented 0.4% (34/8331) of the total. Mean CFUs scavenged by simulated rain ranged from 2 to 267 CFUs/mL. Scavenged ice nucleators belong to a number of taxa including the bacterial genera Pseudomonas, Pantoea, and Xanthomonas, and the fungal genera Fusarium, Humicola, and Mortierella. An ice-nucleating strain of the fungal genus Penicillium was also recovered from a volumetric air sampler at the study site. This work expands our knowledge of the scavenging properties of rainfall, and suggests that at least some ice nucleators in natural precipitation events may have been scrubbed from the atmosphere during rainfall, and thus are not likely to be involved in precipitation.

Cloud Condensation Nuclei in FIRE III

NASA Technical Reports Server (NTRS)

Hudson, James G.; Delnore, Victor E. (Technical Monitor)

2002-01-01

Yum and Hudson showed that the springtime Arctic aerosol is probably a result of long-range transport at high altitudes. Scavenging of particles by clouds reduces the low level concentrations by a factor of 3. This produces a vertical gradient in particle concentrations when low-level clouds are present. Concentrations are uniform with height when clouds are not present. Low-level CCN (cloud condensation nuclei) spectra are similar to those in other maritime areas as found by previous projects including FIRE 1 and ASTEX, which were also supported on earlier NASA-FIRE grants. Wylie and Hudson carried this work much further by comparing the CCN spectra observed during ACE with back trajectories of air masses and satellite photographs. This showed that cloud scavenging reduces CCN concentrations at all altitudes over the springtime Arctic, with liquid clouds being more efficient scavengers than frozen clouds. The small size of the Arctic Ocean seems to make it more susceptible to continental and thus anthropogenic aerosol influences than any of the other larger oceans.

Unveiling aerosol-cloud interactions - Part 2: Minimising the effects of aerosol swelling and wet scavenging in ECHAM6-HAM2 for comparison to satellite data

NASA Astrophysics Data System (ADS)

Neubauer, David; Christensen, Matthew W.; Poulsen, Caroline A.; Lohmann, Ulrike

2017-11-01

Aerosol-cloud interactions (ACIs) are uncertain and the estimates of the ACI effective radiative forcing (ERFaci) magnitude show a large variability. Within the Aerosol_cci project the susceptibility of cloud properties to changes in aerosol properties is derived from the high-resolution AATSR (Advanced Along-Track Scanning Radiometer) data set using the Cloud-Aerosol Pairing Algorithm (CAPA) (as described in our companion paper) and compared to susceptibilities from the global aerosol climate model ECHAM6-HAM2 and MODIS-CERES (Moderate Resolution Imaging Spectroradiometer - Clouds and the Earth's Radiant Energy System) data. For ECHAM6-HAM2 the dry aerosol is analysed to mimic the effect of CAPA. Furthermore the analysis is done for different environmental regimes. The aerosol-liquid water path relationship in ECHAM6-HAM2 is systematically stronger than in AATSR-CAPA data and cannot be explained by an overestimation of autoconversion when using diagnostic precipitation but rather by aerosol swelling in regions where humidity is high and clouds are present. When aerosol water is removed from the analysis in ECHAM6-HAM2 the strength of the susceptibilities of liquid water path, cloud droplet number concentration and cloud albedo as well as ERFaci agree much better with those of AATSR-CAPA or MODIS-CERES. When comparing satellite-derived to model-derived susceptibilities, this study finds it more appropriate to use dry aerosol in the computation of model susceptibilities. We further find that the statistical relationships inferred from different satellite sensors (AATSR-CAPA vs. MODIS-CERES) as well as from ECHAM6-HAM2 are not always of the same sign for the tested environmental conditions. In particular the susceptibility of the liquid water path is negative in non-raining scenes for MODIS-CERES but positive for AATSR-CAPA and ECHAM6-HAM2. Feedback processes like cloud-top entrainment that are missing or not well represented in the model are therefore not well constrained by satellite observations. In addition to aerosol swelling, wet scavenging and aerosol processing have an impact on liquid water path, cloud albedo and cloud droplet number susceptibilities. Aerosol processing leads to negative liquid water path susceptibilities to changes in aerosol index (AI) in ECHAM6-HAM2, likely due to aerosol-size changes by aerosol processing. Our results indicate that for statistical analysis of aerosol-cloud interactions the unwanted effects of aerosol swelling, wet scavenging and aerosol processing need to be minimised when computing susceptibilities of cloud variables to changes in aerosol.

Characterization of soil and postlaunch pad debris from Cape Canaveral launch complex and analysis of soil interaction with aqueous HCl

NASA Technical Reports Server (NTRS)

Pellett, G. L.; Spangler, L. W.; Storey, R. W.; Bendura, R. J.

1982-01-01

Soil samples were fractionated and analyzed in order to assess the physical and chemical interactions of entrained soil with solid-rocket exhaust clouds. The sandy soil consisted primarily of quartz (silica) particles, 30 to 500 microns in diameter, and also contained seashell fragments. Differential and cumulative soil-mass size distributions are presented along with mineralogy, elemental compositions, and solution pH histories. About 90 percent of the soil mass consisted of particles 165 microns in diameter. Characteristic reaction times in aqueous HC1 slurries varied from a few minutes to several days, and capacities for reaction under acidic conditions varied from 10 to 40 g HCl/kg soil, depending on particle size. Airborne lifetimes of particles 165 microns are conservatively 30 min, and this major grouping is predicted to represent a small short-term chemical sink for up to 5% of the total HC1. The smaller and more minor fractions, below a 165 micron diameter, may act as giant cloud condensation nuclei over much longer airborne lifetimes. Finally, the demonstrated time dependency of neutralization is a complicating factor; it can influence the ability to deduce in-cloud HCl scavenging with reaction and can affect the accuracy of measured chemical compositions of near-field wet deposition.

Uncertainty associated with convective wet removal of entrained aerosols in a global climate model

NASA Astrophysics Data System (ADS)

Croft, B.; Pierce, J. R.; Martin, R. V.; Hoose, C.; Lohmann, U.

2012-11-01

The uncertainties associated with the wet removal of aerosols entrained above convective cloud bases are investigated in a global aerosol-climate model (ECHAM5-HAM) under a set of limiting assumptions for the wet removal of the entrained aerosols. The limiting assumptions for the wet removal of entrained aerosols are negligible scavenging and vigorous scavenging (either through activation, with size-dependent impaction scavenging, or with the prescribed fractions of the standard model). To facilitate this process-based study, an explicit representation of cloud-droplet-borne and ice-crystal-borne aerosol mass and number, for the purpose of wet removal, is introduced into the ECHAM5-HAM model. This replaces and is compared with the prescribed cloud-droplet-borne and ice-crystal-borne aerosol fraction scavenging scheme of the standard model. A 20% to 35% uncertainty in simulated global, annual mean aerosol mass burdens and optical depth (AOD) is attributed to different assumptions for the wet removal of aerosols entrained above convective cloud bases. Assumptions about the removal of aerosols entrained above convective cloud bases control modeled upper tropospheric aerosol concentrations by as much as one order of magnitude. Simulated aerosols entrained above convective cloud bases contribute 20% to 50% of modeled global, annual mean aerosol mass convective wet deposition (about 5% to 10% of the total dry and wet deposition), depending on the aerosol species, when including wet scavenging of those entrained aerosols (either by activation, size-dependent impaction, or with the prescribed fraction scheme). Among the simulations, the prescribed fraction and size-dependent impaction schemes yield the largest global, annual mean aerosol mass convective wet deposition (by about two-fold). However, the prescribed fraction scheme has more vigorous convective mixed-phase wet removal (by two to five-fold relative to the size-dependent impaction scheme) since nearly all entrained accumulation and coarse mode aerosols are assumed to be cloud-droplet borne or ice-crystal borne, and evaporation due to the Bergeron-Findeisen process is neglected. The simulated convective wet scavenging of entrained accumulation and coarse mode aerosols has feedbacks on new particle formation and the number of Aitken mode aerosols, which control stratiform and convective cloud droplet number concentrations and yield precipitation changes in the ECHAM5-HAM model. However, the geographic distribution of aerosol annual mean convective wet deposition change in the model is driven by changes to the assumptions regarding the scavenging of aerosols entrained above cloud bases rather than by precipitation changes, except for sea salt deposition in the tropics. Uncertainty in the seasonal, regional cycles of AOD due to assumptions about entrained aerosol wet scavenging is similar in magnitude to the estimated error in the AOD retrievals. The uncertainty in aerosol concentrations, burdens, and AOD attributed to different assumptions for the wet scavenging of aerosols entrained above convective cloud bases in a global model motivates the ongoing need to better understand and model the activation and impaction processes that aerosols undergo after entrainment into convective updrafts.

Aerosol processing in mixed-phase clouds in ECHAM5-HAM: Model description and comparison to observations

NASA Astrophysics Data System (ADS)

Hoose, C.; Lohmann, U.; Stier, P.; Verheggen, B.; Weingartner, E.

2008-04-01

The global aerosol-climate model ECHAM5-HAM has been extended by an explicit treatment of cloud-borne particles. Two additional modes for in-droplet and in-crystal particles are introduced, which are coupled to the number of cloud droplet and ice crystal concentrations simulated by the ECHAM5 double-moment cloud microphysics scheme. Transfer, production, and removal of cloud-borne aerosol number and mass by cloud droplet activation, collision scavenging, aqueous-phase sulfate production, freezing, melting, evaporation, sublimation, and precipitation formation are taken into account. The model performance is demonstrated and validated with observations of the evolution of total and interstitial aerosol concentrations and size distributions during three different mixed-phase cloud events at the alpine high-altitude research station Jungfraujoch (Switzerland). Although the single-column simulations cannot be compared one-to-one with the observations, the governing processes in the evolution of the cloud and aerosol parameters are captured qualitatively well. High scavenged fractions are found during the presence of liquid water, while the release of particles during the Bergeron-Findeisen process results in low scavenged fractions after cloud glaciation. The observed coexistence of liquid and ice, which might be related to cloud heterogeneity at subgrid scales, can only be simulated in the model when assuming nonequilibrium conditions.

A Cloud-Based Scavenger Hunt: Orienting Undergraduates to ACS National Meetings

ERIC Educational Resources Information Center

Kubasik, Matthew A.; Van Dyke, Aaron R.; Harper-Leatherman, Amanda S.; Miecznikowski, John R.; Steffen, L. Kraig; Smith-Carpenter, Jillian

2016-01-01

American Chemical Society (ACS) National Meetings are valuable for the development of undergraduate researchers but can be overwhelming for first-time attendees. To orient and engage students with the range of offerings at an ACS meeting, we developed a cloud-based scavenger hunt. Using their mobile devices, teams of undergraduates…

Observational and modeling studies of chemical species concentrations as a function of raindrop size

NASA Astrophysics Data System (ADS)

Wai, K. M.; Tam, C. W. F.; Tanner, P. A.

The Guttalgor method has been used to determine the chemical species concentrations in size-selected raindrops in nine rain events at Hong Kong from 1999 to 2001. The curve (concentration against raindrop radius) patterns for all the species are similar but depend on the starting time of sampling within a rain event. In these plots, the maximum concentration occurs at the same range of droplet radius, irrespective of the species, and this indicates the importance of coalescence and breakup processes. The maximum is located at a smaller droplet radius than was found in previous studies in Germany. All results show almost constant concentrations with size for large raindrops, and these indicate the in-cloud contributions. The pH of raindrops of similar size is linearly correlated with a function of the sulfate, nitrate, acetate, formate, calcium and ammonium ion species concentrations. Within a single raindrop, chloride depletion is not significant, and sulfate, ammonium and hydrogen ions are found in ratios compatible with the precursor solid-phase mixture of ammonium sulfate and ammonium bisulphate. When simulated by a below-cloud model, good agreement between the modeled and measured sodium and sulfate concentrations has been found. Below-cloud sulfur dioxide scavenging contributes at most 60% of the sulfate concentration in a single raindrop.

Cloud Condensation Nuclei in Fire-3

NASA Technical Reports Server (NTRS)

2000-01-01

The centerpiece of this research was the cloud condensation nuclei (CCN) measurements of the Desert Research Institute (DRI) CCN spectrometers on board the NCAR C-130 aircraft during the Arctic Cloud Experiment (ACE) in May, 1998. These instruments operated successfully throughout all eight 10-hour research flights based in Fairbanks and the two ferry flights between Colorado and Fairbanks. Within a few months of completion of ACE the CCN data was edited and put into the archives. A paper was completed and published on the CCN climatology during the previous two FIRE field projects-FIRE 1 based in San Diego in June and July, 1987 and ASTEX based in the Azores Islands in June, 1992. This showed distinct contrasts in concentrations and spectra between continental and maritime CCN concentrations, which depended on air mass trajectories. Pollution episodes from Europe had distinct influences on particle concentrations at low altitudes especially within the boundary layer. At higher altitudes concentrations were similar in the two air mass regimes. Cloudier atmospheres showed lower concentrations especially below the clouds, which were a result mostly of coalescence scavenging.

Atmospheric scavenging of hydrochloric acid. [from rocket exhaust

NASA Technical Reports Server (NTRS)

Knutson, E. O.; Fenton, D. L.

1975-01-01

The scavenging of hydrogen chloride from a solid rocket exhaust cloud was investigated. Water drops were caused to fall through a confined exhaust cloud and then analyzed to determine the amount of HCl captured during fall. Bubblers were used to measure HCl concentration within the chamber. The measured chamber HCl concentration, together with the measured HCl deposition on the chamber walls, accounted for 81 to 94% of the theoretical HCl. It was found that the amount of HCl captured was approximately one-half of that predicted by the Frossling correlation. No effect of humidity was detected through a range of 69-98% R.H.. The scavenging of HCl from a solid rocket exhaust cloud was calculated using an idealized Kennedy Space Center rain cycle. Results indicate that this cycle would reduce the cloud HCl concentration to 20.6% if its value in the absence of rain.

Direct and Indirect Effects of Precipitation on Particulate Matter Concentration in the Aburrá Valley

NASA Astrophysics Data System (ADS)

Roldán Henao, N.; Hoyos Ortiz, C. D.; Herrera, L.

2017-12-01

Wet deposition, including in-cloud scavenging (ICS) and below-cloud scavenging (BCS), is one of the most important processes of particulate matter (PM) removal from the atmosphere. ICS mainly refers to the growth of particulates into cloud droplets, whereas BCS consists of collisions and coalescence between raindrops and pollutants. The overall influence of precipitation in the concentration of fine particulate matter less than 2.5 microns in size (PM2.5) in the Medellín metropolitan area located in the narrow Aburrá Valley within the Colombian Andes is assessed using weather radar derived precipitation with 5 minutes resolution and hourly data from air quality monitoring stations from the Medellín Early Warning System ( Sistema de Alerta Temprana de Medellin y el Valle de Aburra -SIATA-) monitoring network. A non-parametric probabilistic analysis is proposed in order to understand the net influence of precipitation within the diurnal cycle. Probability density functions (PDF) of PM2.5 concentration during precipitations events as well as under dry conditions are analyzed for every hour of the day. The overlapping coefficient for these distributions was used, along with the Wilcoxon Mann-Whitney test, in order to summarized the net effect of precipitation in aerosol concentration. Evidence suggests that, while there is a clear and significant role of precipitation in aerosol concentration, the net effect is contrasting and strongly depends on the diurnal cycle of atmospheric stability. During stable conditions in the lower troposphere, typically occurring during the night and before midmorning, evidence suggest that precipitation reduces the near-surface PM2.5 concentration due to an effective BCS resulting in net negative forcing. On the other hand, when a precipitation event takes place during the day, when the lower troposphere is typically unstable, the PM2.5 concentration increases, suggesting an net positive forcing given that the BCS is offset by the atmospheric stabilization effect of precipitation, which in turns results in near-surface PM accumulation.

Effects of Wegener-Bergeron-Findeisen Process on Global Black Carbon Distribution

NASA Astrophysics Data System (ADS)

Qi, L.

2016-12-01

In mixed-phase clouds, the Wegener-Bergeron-Findeisen (WBF) process (ice crystals may grow while water drops evaporate, thereby releasing black carbon (BC) particles into the interstitial air) slows down wet scavenging of BC. Rimming (snowflakes fall and collect cloud water drops and the BC in them along their pathways), in contrast, results in more efficient wet scavenging. We systematically investigate the effects of WBF on BC scavenging efficiency, surface BCair, deposition flux, concentration in snow, and washout ratio using a global 3D chemical transport model. We differentiate riming- vs WBF-dominated in-cloud scavenging based on liquid water content and temperature. Specifically, we relate WBF to either temperature or ice mass fraction in mixed-phase clouds. We find that at Jungfraujoch, Switzerland and Abisko, Sweden, where WBF dominates, the discrepancies of simulated BC scavenging efficiency and washout ratio are significantly reduced (from a factor of 3 to 10% and from a factor of 4-5 to a factor of two). However, at Zeppelin, Norway, where riming dominates, simulation of BC scavenging efficiency, BCair, and washout ratio become worse (relative to observations) when WBF is included. There is thus an urgent need for extensive observations to distinguish and characterize riming- versus WBF-dominated aerosol scavenging in mixed-phase clouds and the associated BC scavenging efficiency. We find the reduction resulting from WBF to global BC scavenging efficiency varies substantially, from 8% in the tropics to 76% in the Arctic. The resulting annual mean BCair increases by up to 156% at high altitudes and at northern high latitudes. Overall, WBF halves the model-observation discrepancy (from -65% to -30%) of BCair across North America, Europe, China and the Arctic. Globally WBF increases BC burden from 0.22 to 0.29-0.35 mg m-2 yr-1, which partially explains the gap between observed and previous model simulated BC burdens over land (Bond et al., 2013). In addition, WBF significantly increases BC lifetime from 5.7 days to 8 days. We find that WBF decreases BCsnow at mid-latitudes (by 15%) but increases it in the Arctic (by 26%) while improving model comparisons with observations. In addition, WBF dramatically reduces the model-observation discrepancy of washout ratios in winter (from a factor of 16 to 4).

Reconciling the aerosol-liquid water path relationship in the ECHAM6-HAM GCM and the Aerosol_cci/Cloud_cci (A)ATSR dataset by minimizing the effect of aerosol swelling

NASA Astrophysics Data System (ADS)

Neubauer, D.; Christensen, M.; Lohmann, U.; Poulsen, C. A.

2016-12-01

Studies using present day variability to assess statistical relationships between aerosol and cloud properties find different strengths of these relationships between satellite data and general circulation model (GCM) data. This discrepancy can be explained by structural uncertainties due to differences in the analysis/observational scale and the process scale or spurious relationships between aerosol and cloud properties. Such spurious relationships are the growth of aerosol particles in the humid environment surrounding clouds, misclassification of partly cloudy satellite pixels as cloud free pixels, brightening of aerosol particles by sunlight reflected at cloud edges, or effects of clouds on aerosol like processing of aerosol particles in clouds by nucleation or impact scavenging and subsequent growth by heterogeneous chemistry and release by cloud droplet evaporation or wet scavenging of aerosol particles. To minimize the effects of spatial aggregation and spurious relationships we apply a new nearest neighbour approach to high resolution (A)ATSR datasets from the Aerosol_cci and Cloud_cci projects of the Climate Change Initiative (CCI) programme of ESA. For the ECHAM6-HAM GCM we quantify the impact of using dry aerosol (without aerosol water) in the analysis to mimic the effect of the nearest neighbour approach. The aerosol-liquid water path relationship in ECHAM6-HAM is systematically stronger than in (A)ATSR data and cannot be explained by an overestimation of autoconversion when using diagnostic precipitation but rather by aerosol swelling in regions where humidity is high and clouds are present. When aerosol water is removed from the analysis in ECHAM6-HAM the strength of the aerosol-liquid water path relationship agrees much better with the ones of (A)ATSR or MODIS. We further find that while the observed relationships of different satellite sensors ((A)ATSR vs. MODIS) are not always consistent for tested environmental conditions the relationships in ECHAM6-HAM are missing a strong dependence on environmental conditions which is critical for bridging the gap between satellite and model estimates of aerosol indirect forcing.

Electroscavenging and Inferred Effects on Precipitation Efficiency

NASA Astrophysics Data System (ADS)

Tinsley, B. A.

2002-12-01

The evaporation of charged droplets leaves charged aerosol particles that can act as cloud condensation nuclei and ice forming nuclei. New calculations of scavenging of such charged particles by droplets have been made, that now include the effects of inertia and variable particle density, and variable cloud altitudes ranging into the stratosphere. They show that the Greenfield Gap closes for particles of low density, or for high altitude clouds, or for a few hundred elementary charges on the particles. A few tens of elementary charges on the particles gives collision efficiencies typically an order of magnitude greater than that due to phoretic forces alone. The numerical integrations show that electroscavenging of ice forming nuclei leading to contact ice nucleation is competitive with deposition ice nucleation, for cloud top temperatures in the range 0§C to -15§C and droplet size distributions extending past 10-15 mm radius. This implies that for marine stratocumulus or nimbostratus clouds with tops just below freezing temperature, where precipitation is initiated by the Wegener-Bergeron-Findeisen process, the precipitation efficiency can be affected by the amount of charge on the ice-forming nuclei. This in turn depends on the extent of the (weak) electrification of the cloud. Similarly, electroscavenging of condensation nuclei can increase the average droplet size in successive cycles of cloud evaporation and formation, and can also affect precipitation efficiency.

A New Wet Deposition Module in SILAM Chemical Transport Model

NASA Astrophysics Data System (ADS)

Kouznetsov, R.; Sofiev, M.

2013-12-01

The System for Integrated modeLling of Atmopsheric coMposition SILAM (http://silam.fmi.fi/) is a CTM model of FMI air-quality research unit. SILAM is used for research, operational and emergency-response assessments and forecasting of the atmospheric composition within the scope of European and Finnish national projects. Characteristic scales of the SILAM applications vary from -mesoscale (grid spacing 1 km) up to the globe with characteristic resolution of 1 degree. Till recently, a simple approach based on scavenging coefficients and their species-dependent scaling was used in SILAM. Due to the lack of information on the vertical structure of precipitation in older meteorological datasets, it was prescribed. The new scheme uses a mechanistic description of the scavenging process and utilizes the vertical profiles of cloud water content. A simple model for dissociation of H2SO3 accounts for saturation of SO2 scavenging. As the vertical profiles of precipitation rates are rarely available from meteorological models, they are reconstructed from the profiles of cloud water and surface precipitation fields. The rain/snow increment in a 3D model grid cell is taken as a fraction of surface precipitation intensity equal to the cell's fraction of total cloud water column. The phase of precipitation (liquid/solid) is a function of air temperature. The fall speed is derived from the size of water drops given by a function of rain/snow intensity. In-cloud scavenging is considered as an equilibrium process: . the concentrations in cloud water are assumed to be in equilibrium with ambient air. The sub-cloud scavenging is driven by the precipitation that comes from above the cell. The scavenging by a single droplet is considered as a two-way equilibration process of in-water and in-air concentrations, controlled by the hydrometeors size, cross-section and a time the droplet falls through a cell, effective solubility and amount of already dissolved pollutant. The solubility for most species is given by their effective Henry factors as functions of temperature. An exception is SO2 since the in-water amount of [S(IV)] is not a linear function of SO2 partial pressure in the air. The effective Henry factor for SO2 is then calculated from a dissociation equation after all other species in a cell are processed and their in-water concentrations are known. The new scheme results in substantially more realistic vertical patterns for scavenging. The consideration of equilibration rather than one-way scavenging allows modelling the vertical redistribution of pollutants by precipitation. The scheme provides a simple and well-grounded means to account for saturation of scavenging for SO2.

Aerosol Processing in Mixed-Phase Clouds in ECHAM5-HAM: Comparison of Single-Column Model Simulations to Observations

NASA Astrophysics Data System (ADS)

Hoose, C.; Lohmann, U.; Stier, P.; Verheggen, B.; Weingartner, E.; Herich, H.

2007-12-01

The global aerosol-climate model ECHAM5-HAM (Stier et al., 2005) has been extended by an explicit treatment of cloud-borne particles. Two additional modes for in-droplet and in-crystal particles are introduced, which are coupled to the number of cloud droplet and ice crystal concentrations simulated by the ECHAM5 double-moment cloud microphysics scheme (Lohmann et al., 2007). Transfer, production and removal of cloud-borne aerosol number and mass by cloud droplet activation, collision scavenging, aqueous-phase sulfate production, freezing, melting, evaporation, sublimation and precipitation formation are taken into account. The model performance is demonstrated and validated with observations of the evolution of total and interstitial aerosol concentrations and size distributions during three different mixed-phase cloud events at the alpine high-altitude research station Jungfraujoch (Switzerland) (Verheggen et al, 2007). Although the single-column simulations can not be compared one-to-one with the observations, the governing processes in the evolution of the cloud and aerosol parameters are captured qualitatively well. High scavenged fractions are found during the presence of liquid water, while the release of particles during the Bergeron-Findeisen process results in low scavenged fractions after cloud glaciation. The observed coexistence of liquid and ice, which might be related to cloud heterogeneity at subgrid scales, can only be simulated in the model when forcing non-equilibrium conditions. References: U. Lohmann et al., Cloud microphysics and aerosol indirect effects in the global climate model ECHAM5-HAM, Atmos. Chem. Phys. 7, 3425-3446 (2007) P. Stier et al., The aerosol-climate model ECHAM5-HAM, Atmos. Chem. Phys. 5, 1125-1156 (2005) B. Verheggen et al., Aerosol partitioning between the interstitial and the condensed phase in mixed-phase clouds, Accepted for publication in J. Geophys. Res. (2007)

Impacts of ENSO events on cloud radiative effects in preindustrial conditions: Changes in cloud fraction and their dependence on interactive aerosol emissions and concentrations: IMPACT OF ENSO ON CLOUD RADIATIVE EFFECT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Yang; Russell, Lynn M.; Xu, Li

The impacts of the El Niño–Southern Oscillation (ENSO) events on shortwave and longwave cloud radiative effects (CRESW and CRELW) and the underlying changes in cloud fraction as well as aerosol emissions, wet scavenging and transport are quantified using three 150-year simulations in preindustrial conditions by the CESM model. Compared to recent observations from Clouds and the Earth’s Radiant Energy System (CERES), the model simulation successfully reproduced larger variations of CRESW over the tropical western and central Pacific, Indonesian regions, and the eastern Pacific Ocean, as well as large variations of CRELW located mainly within the tropics. The ENSO cycle ismore » found to dominate interannual variations of cloud radiative effects, especially over the tropics. Relative to those during La Niña events, simulated cooling (warming) effects from CRESW (CRELW) during El Niño events are stronger over the tropical western and central Pacific Ocean, with the largest difference exceeding 40 Wm–2 (30 Wm–2), with weaker effects of 10–30 Wm–2 over Indonesian regions and the subtropical Pacific Ocean. Sensitivity tests show that variations of cloud radiative effects are mainly driven by ENSO-related changes in cloud fraction. The variations in medium and high cloud fractions each account for about 20–50% of the interannual variations of CRESW over the tropics and almost all of the variations of CRELW between 60°S and 60°N. The variation of low cloud fraction contributes most interannual variations of CRESW over the mid-latitude oceans. Variations in natural aerosol concentrations considering emissions, wet scavenging and transport explained 10–30% of the interannual variations of both CRESW and CRELW over the tropical Pacific, Indonesian regions and the tropical Indian Ocean. Changes in wet scavenging of natural aerosol modulate the variations of cloud radiative effects. Because of increased (decreased) precipitation over the tropical western Pacific Ocean in El Niño (La Niña) events, increased (decreased) wet scavenging of natural aerosols dampens more than 4–6% of variations of cloud radiative effects averaged over the tropics. In contrast, increased surface winds cause feedbacks that increase sea spray emissions that enhance the variations by 3–4% averaged over the tropics.« less

Aerosol partitioning in mixed-phase clouds at the Jungfraujoch (3580 m asl)

NASA Astrophysics Data System (ADS)

Henning, S.; Bojinski, S.; Diehl, K.; Ghan, S.; Nyeki, S.; Weingartner, E.; Wurzler, S.; Baltensperger, U.

2003-04-01

Field measurements on the partitioning between the interstitial and the liquid/ice phase in natural clouds were performed at the high-alpine research station Jungfraujoch (3580 m asl, Switzerland) during a summer and a winter campaign. The size distributions of the total and the interstitial aerosol were determined by means of a scanning mobility particle sizer (SMPS). From these, size resolved scavenging ratios were calculated. Simultaneously, cloud water content (CWC) and cloud particle size distributions along with meteorological data were obtained. In cold mixed phase clouds (existing of liquid droplets and ice crystals), strong differences were found in comparison to the warm summer clouds. In the warm cloud types all particles above a certain diameter were activated and thereby the scavenging ratio (number of activated particles divided by the total number concentration) above a certain threshold diameter approached 1. In the winter clouds, the scavenging ratio never reached the value of 1 and could be as low as 0. These observations are explained by the Bergeron-Findeisen process: Here, particles are also activated to droplets in the first step, but after the formation of the ice phase droplets evaporate while the ice crystals grow, due to difference in the saturation vapor pressure over water and ice. This release of aerosol particles to the interstitial aerosol has significant implications for the climate forcing: It can be expected that the number of CCN is of less importance as soon as ice crystals are formed.

Effects of the Wegener-Bergeron-Findeisen process on global black carbon distribution

NASA Astrophysics Data System (ADS)

Qi, Ling; Li, Qinbin; He, Cenlin; Wang, Xin; Huang, Jianping

2017-06-01

We systematically investigate the effects of Wegener-Bergeron-Findeisen process (hereafter WBF) on black carbon (BC) scavenging efficiency, surface BCair, deposition flux, concentration in snow (BCsnow, ng g-1), and washout ratio using a global 3-D chemical transport model (GEOS-Chem). We differentiate riming- versus WBF-dominated in-cloud scavenging based on liquid water content (LWC) and temperature. Specifically, we implement an implied WBF parameterization using either temperature or ice mass fraction (IMF) in mixed-phase clouds based on field measurements. We find that at Jungfraujoch, Switzerland, and Abisko, Sweden, where WBF dominates in-cloud scavenging, including the WBF effect strongly reduces the discrepancies of simulated BC scavenging efficiency and washout ratio against observations (from a factor of 3 to 10 % and from a factor of 4-5 to a factor of 2). However, at Zeppelin, Norway, where riming dominates, simulation of BC scavenging efficiency, BCair, and washout ratio become worse (relative to observations) when WBF is included. There is thus an urgent need for extensive observations to distinguish and characterize riming- versus WBF-dominated aerosol scavenging in mixed-phase clouds and the associated BC scavenging efficiency. Our model results show that including the WBF effect lowers global BC scavenging efficiency, with a higher reduction at higher latitudes (8 % in the tropics and up to 76 % in the Arctic). The resulting annual mean BCair increases by up to 156 % at high altitudes and at northern high latitudes because of lower temperature and higher IMF. Overall, WBF halves the model-observation discrepancy (from -65 to -30 %) of BCair across North America, Europe, China and the Arctic. Globally WBF increases BC burden from 0.22 to 0.29-0.35 mg m-2 yr-1, which partially explains the gap between observed and previous model-simulated BC burdens over land. In addition, WBF significantly increases BC lifetime from 5.7 to ˜ 8 days. Additionally, WBF results in a significant redistribution of BC deposition in source and remote regions. Specifically, it lowers BC wet deposition (by 37-63 % at northern mid-latitudes and by 21-29 % in the Arctic), while it increases dry deposition (by 3-16 % at mid-latitudes and by 81-159 % in the Arctic). The resulting total BC deposition is lower at mid-latitudes (by 12-34 %) but higher in the Arctic (by 2-29 %). We find that WBF decreases BCsnow at mid-latitudes (by ˜ 15 %) but increases it in the Arctic (by 26 %) while improving model comparisons with observations. In addition, WBF dramatically reduces the model-observation discrepancy of washout ratios in winter (from a factor of 16 to 4). The remaining discrepancies in BCair, BCsnow and BC washout ratios suggest that in-cloud removal in mixed-phased clouds is likely still excessive over land.

Seasonality of Forcing by Carbonaceous Aerosols

NASA Astrophysics Data System (ADS)

Habib, G.; Bond, T.; Rasch, P. J.; Coleman, D.

2006-12-01

Aerosols can influence the energy balance of Earth-Atmosphere system with profound effect on regional climate. Atmospheric processes, such as convection, scavenging, wet and dry deposition, govern the lifetime and location of aerosol; emissions affect its quantity and location. Both affect climate forcing. Here we investigate the effect of seasonality in emissions and atmospheric processes on radiative forcing by carbonaceous aerosols, focusing on aerosol from fossil fuel and biofuel. Because aerosol lifetime is seasonal, ignoring the seasonality of sources such as residential biofuel may introduce a bias in aerosol burden and therefore in predicted climate forcing. We present a global emission inventory of carbonaceous aerosols with seasonality, and simulate atmospheric concentrations using the Community Atmosphere Model (CAM). We discuss where and when the seasonality of emissions and atmospheric processes has strong effects on atmospheric burden, lifetime, climate forcing and aerosol optical depth (AOD). Previous work has shown that aerosol forcing is higher in summer than in winter, and has identified the importance of aerosol above cloud in determining black carbon forcing. We show that predicted cloud height is a very important factor in determining normalized radiative forcing (forcing per mass), especially in summer. This can affect the average summer radiative forcing by nearly 50%. Removal by cloud droplets is the dominant atmospheric cleansing mechanism for carbonaceous aerosols. We demonstrate the modeled seasonality of removal processes and compare the importance of scavenging by warm and cold clouds. Both types of clouds contribute significantly to aerosol removal. We estimate uncertainty in direct radiative forcing due to scavenging by tagging the aerosol which has experienced cloud interactions. Finally, seasonal variations offer an opportunity to assess modeled processes when a single process dominates variability. We identify regions where aerosol burden is most sensitive to convection and scavenging in warm and cold clouds, and compare seasonally modeled AOD with that retrieved by the Moderate Resolution Imaging Spectroradiometer (MODIS).

Factors Influencing Aerosol Concentrations and Properties over the Tropical Eastern Pacific: Observations from TC4

NASA Astrophysics Data System (ADS)

Anderson, B. E.; Chen, G.; Thornhill, K. L.; Winstead, E. L.; Dibb, J.; Scheuer, E.; Lathem, T.

2007-12-01

The NASA Tropical Composition Cloud and Climate Coupling (TC4) mission was conducted during summer 2007 and had the primary objective of gaining a better understanding of composition and dynamics of the upper troposphere over the tropical eastern pacific region. Based in San Jose, Costa Rica, the mission employed instrumented aircraft along with ground, balloon, and satellite borne sensors to determine the spatial distribution of trace gas and aerosol species as well as moisture and clouds between the surface and roughly 16 km altitude over Central America, the eastern Pacific, the western Caribbean and northern South America. Because of its heavy payload and long endurance capability, the NASA DC-8 aircraft was the primary sampling platform for the lower-tropospheric altitude regime (i.e., below 12 km). It carried both remote and in situ instruments and was used to characterize cloud inflow and outflow as well as the microphysical properties of maritime convective systems. Because of their roles in regulating atmospheric radiation transfer and cloud formation and microphysics, flight plans placed particular emphasis on determining the sources and properties of the aerosol particles present within the region. A preliminary analysis of the DC-8 data set suggests that the following sources/processes had the greatest impact on aerosol number and mass loading: dust transport from Africa; sea salt production over the ocean; urban and biogenic emissions over the continent; secondary aerosol formation in volcanic plumes; nucleation in cloud outflow; and cloud scavenging. In this presentation, we will examine the microphysical, optical and hydration properties of each aerosol type and assess the overall impact of the source/sink processes to the regional aerosol budget. We will also contrast the microphysical properties of the Saharan Dust sampled over the Caribbean with those measured in fresh dust layers over the eastern Atlantic from the DC-8 during the summer 2006, NASA African Monsoon Multidisciplinary Activity (NAMMA).

Cloud processing of gases and aerosols in the Community Multiscale Air Quality (CMAQ) model: Impacts of extended chemistry

EPA Science Inventory

Clouds and fogs can significantly impact the concentration and distribution of atmospheric gases and aerosols through chemistry, scavenging, and transport. This presentation summarizes the representation of cloud processes in the Community Multiscale Air Quality (CMAQ) modeling ...

Aerosol processing in stratiform clouds in ECHAM6-HAM

NASA Astrophysics Data System (ADS)

Neubauer, David; Lohmann, Ulrike; Hoose, Corinna

2013-04-01

Aerosol processing in stratiform clouds by uptake into cloud particles, collision-coalescence, chemical processing inside the cloud particles and release back into the atmosphere has important effects on aerosol concentration, size distribution, chemical composition and mixing state. Aerosol particles can act as cloud condensation nuclei. Cloud droplets can take up further aerosol particles by collisions. Atmospheric gases may also be transferred into the cloud droplets and undergo chemical reactions, e.g. the production of atmospheric sulphate. Aerosol particles are also processed in ice crystals. They may be taken up by homogeneous freezing of cloud droplets below -38° C or by heterogeneous freezing above -38° C. This includes immersion freezing of already immersed aerosol particles in the droplets and contact freezing of particles colliding with a droplet. Many clouds do not form precipitation and also much of the precipitation evaporates before it reaches the ground. The water soluble part of the aerosol particles concentrates in the hydrometeors and together with the insoluble part forms a single, mixed, larger particle, which is released. We have implemented aerosol processing into the current version of the general circulation model ECHAM6 (Stevens et al., 2013) coupled to the aerosol module HAM (Stier et al., 2005). ECHAM6-HAM solves prognostic equations for the cloud droplet number and ice crystal number concentrations. In the standard version of HAM, seven modes are used to describe the total aerosol. The modes are divided into soluble/mixed and insoluble modes and the number concentrations and masses of different chemical components (sulphate, black carbon, organic carbon, sea salt and mineral dust) are prognostic variables. We extended this by an explicit representation of aerosol particles in cloud droplets and ice crystals in stratiform clouds similar to Hoose et al. (2008a,b). Aerosol particles in cloud droplets are represented by 5 tracers for the chemical components as well as 5 tracers for aerosol particles in ice crystals. This allows simulations of aerosol processing in warm, mixed-phase (e.g. through the Bergeron-Findeisen process) and ice clouds. The fixed scavenging ratios used for wet deposition in clouds in standard HAM are replaced by an explicit treatment of collision of cloud droplets/ice crystals with interstitial aerosol particles. Nucleation scavenging of aerosol particles by acting as cloud condensation nuclei or ice nuclei, freezing and evaporation of cloud droplets and melting and sublimation of ice crystals are treated explicitly. In extension to previous studies, aerosol particles from evaporating precipitation are released to modes which correspond to their size. Cloud processing of aerosol particles changes their size distribution and hence influences cloud droplet and ice crystal number concentrations as well as precipitation rate, which in turn affects aerosol concentrations. Results will be presented at the conference. Hoose et al., JGR, 2008a, doi: 10.1029/2007JD009251 Hoose et al., ACP, 2008b, doi: 10.5194/acp-8-6939-2008 Stevens et al., 2013, submitted Stier et al., ACP, 2005, doi: 10.5194/acp-5-1125-2005

Preparation of Ultracold Atom Clouds at the Shot Noise Level.

PubMed

Gajdacz, M; Hilliard, A J; Kristensen, M A; Pedersen, P L; Klempt, C; Arlt, J J; Sherson, J F

2016-08-12

We prepare number stabilized ultracold atom clouds through the real-time analysis of nondestructive images and the application of feedback. In our experiments, the atom number N∼10^{6} is determined by high precision Faraday imaging with uncertainty ΔN below the shot noise level, i.e., ΔN

Intercomparison between Individual Particles Scavenged as CCN and Those Collected at Ground-based Site on West Coast of Japan During Asian Dust Storm

NASA Astrophysics Data System (ADS)

Ma, C. J.; Tohno, S.; Kasahara, M.; Hayakawa, S.

2002-12-01

Asian dust storm particles can affect precipitation composition because they are either incorporated into cloud via condensation of water vapour (nucleation) or due to the uptake of particles by existing droplets. And subsequently they affect aquatic and terrestrial ecosystems. In order to study the intercorrelation between the chemical natures of both the particles collected at ground-based site and those scavenged as CCN, the intensive field measurement was carried out on west coast of Japan (Yasaka, Tango Peninsula, 35.62°N; 135.07°E) during dense Asian dust storm event on March 22, 2002. Due to the size dependence of the chemical composition of aerosol particle, size-segregated aerosol particles were collect using Low pressure Andersen impactor sampler. Also, to collect cloud droplets individually, a particular method for the cloud droplet replication was newly applied using collodion (nitrocellulose) film. Sampling of cloud droplets was performed at summit of a mountain (680 m) in Yasaka. To analyze the ambient individual aerosol particles and individual retained particles in cloud droplet, X-ray fluorescence (XRF) analytical method set at SPring-8 on BL39XU was applied. Analytical result enables us not only to compare the characteristics of individual particles scavenged as CCN and those collected at ground-based site, but also to estimate the influence of long-range transport.

An Eulerian model for scavenging of pollutants by raindrops

NASA Astrophysics Data System (ADS)

Kumar, Sudarshan

An Eulerian model for simulating the coupled processes of gas-phase depletion and aqueousphase accumulation of the pollutant species during a rain event has been formulated. The model is capable of taking into account any realistic vertical profile of pollutant species concentrations and time-dependent initial aqueous-phase concentrations at the cloud base. The model considers the processes of single species absorption and dissociation in the aqueous phase. The coupled partial differential equations constituting the model are discretized into a set of ordinary differential equations by using the Galerkin method with chapeau functions as the basis functions. These equations are solved to obtain the pollutant concentrations of the gas phase and raindrops as well as the pH of raindrops as a function of time and distance below cloud-base. Simulations are performed for scavenging of gaseous HNO 3, H 2O 2, SO 2, formaldehyde and NH 3. For the case of highly soluble HNO 3 and H 2O 2, raindrops are far from equilibrium with the gas phase and their capacity for absorption of these gases is undiminished even as they reach ground level. The gas-phase concentrations for these species decrease exponentially with time and the washout is determined primarily by the rain intensity and mass-transfer coefficient of the gaseous species to the raindrops. The pollutant species concentrations in raindrops are an almost linear function of the distance below the cloud base. For the simulation conditions considered in this study, the half-life periods of these gases for removal from the atmosphere range from 15 to 40 min. For SO 2 and formaldehyde, the aqueous-phase concentrations approach equilibrium as the drops fall to ground level and the gas-phase concentrations show large gradients in the vertical. Half-life periods for SO 2 range from 1.3 to 13 h depending on the initial raindrop pH and rain intensity. For formaldehyde, the half-life ranges from 19 to 63 min. Solubility of NH 3 is a strong function of the raindrop pH. As NH 3 is absorbed, the raindrop pH increases and NH 3 solubility decreases. For pre-acidified drops (pH = 4.6), ammonia solubility is very high and the drops are far from equilibrium with the gas phase throughout the falling period. The half-life for ammonia ranges from 11 min to over 3 h in our simulations.

Fog scavenging of organic and inorganic aerosol in the Po Valley

NASA Astrophysics Data System (ADS)

Gilardoni, S.; Massoli, P.; Giulianelli, L.; Rinaldi, M.; Paglione, M.; Pollini, F.; Lanconelli, C.; Poluzzi, V.; Carbone, S.; Hillamo, R.; Russell, L. M.; Facchini, M. C.; Fuzzi, S.

2014-07-01

The interaction of aerosol with atmospheric water affects the processing and wet removal of atmospheric particles. Understanding such interaction is mandatory to improve model description of aerosol lifetime and ageing. We analyzed the aerosol-water interaction at high relative humidity during fog events in the Po Valley within the framework of the Agenzia Regionale per la Prevenzione e l'Ambiente (ARPA) - Emilia Romagna supersite project. For the first time in this area, the changes in particle chemical composition caused by fog are discussed along with changes in particle microphysics. During the experiment, 14 fog events were observed. The average mass scavenging efficiency was 70% for nitrate, 68% for ammonium, 61% for sulfate, 50% for organics, and 39% for black carbon. After fog formation, the interstitial aerosol was dominated by particles smaller than 200 nm Dva (vacuum aerodynamic diameter) and enriched in carbonaceous aerosol, mainly black carbon and water-insoluble organic aerosol. For each fog event, the size-segregated scavenging efficiency of nitrate and organic aerosol (OA) was calculated by comparing chemical species size distribution before and after fog formation. For both nitrate and OA, the size-segregated scavenging efficiency followed a sigmoidal curve, with values close to zero below 100 nm Dva and close to 1 above 700 nm Dva. OA was able to affect scavenging efficiency of nitrate in particles smaller than 300 nm Dva. A linear correlation between nitrate scavenging and particle hygroscopicity (κ) was observed, indicating that 44-51% of the variability of nitrate scavenging in smaller particles (below 300 nm Dva) was explained by changes in particle chemical composition. The size-segregated scavenging curves of OA followed those of nitrate, suggesting that organic scavenging was controlled by mixing with water-soluble species. In particular, functional group composition and OA elemental analysis indicated that more oxidized OA was scavenged more efficiently than less oxidized OA. Nevertheless, the small variability of organic functional group composition during the experiment did not allow us to discriminate the effect of different organic functionalities on OA scavenging.

Wet scavenging of soluble gases in DC3 deep convective storms using WRF-Chem simulations and aircraft observations: DEEP CONVECTIVE WET SCAVENGING OF GASES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bela, Megan M.; Barth, Mary C.; Toon, Owen B.

We examine wet scavenging of soluble trace gases in storms observed during the Deep Convective Clouds and Chemistry (DC3) field campaign. We conduct high-resolution simulations with the Weather Research and Forecasting model with Chemistry (WRF-Chem) of a severe storm in Oklahoma. The model represents well the storm location, size, and structure as compared with Next Generation Weather Radar reflectivity, and simulated CO transport is consistent with aircraft observations. Scavenging efficiencies (SEs) between inflow and outflow of soluble species are calculated from aircraft measurements and model simulations. Using a simple wet scavenging scheme, we simulate the SE of each soluble speciesmore » within the error bars of the observations. The simulated SEs of all species except nitric acid (HNO3) are highly sensitive to the values specified for the fractions retained in ice when cloud water freezes. To reproduce the observations, we must assume zero ice retention for formaldehyde (CH2O) and hydrogen peroxide (H2O2) and complete retention for methyl hydrogen peroxide (CH3OOH) and sulfur dioxide (SO2), likely to compensate for the lack of aqueous chemistry in the model. We then compare scavenging efficiencies among storms that formed in Alabama and northeast Colorado and the Oklahoma storm. Significant differences in SEs are seen among storms and species. More scavenging of HNO3 and less removal of CH3OOH are seen in storms with higher maximum flash rates, an indication of more graupel mass. Graupel is associated with mixed-phase scavenging and lightning production of nitrogen oxides (NOx ), processes that may explain the observed differences in HNO3 and CH3OOH scavenging.« less

Analytical study of the Atmospheric Cloud Physics Laboratory (ACPL) experiments

NASA Technical Reports Server (NTRS)

Davis, M. H.

1977-01-01

The design specifications of the research laboratory as a Spacelab facility are discussed along with the types of planned experiments. These include cloud formation, freezing and scavenging, and electrical phenomena. A summary of the program conferences is included.

What Controls the Vertical Distribution of Aerosol? Relationships Between Process Sensitivity in HadGEM3-UKCA and Inter-Model Variation from AeroCom Phase II

NASA Technical Reports Server (NTRS)

Kipling, Zak; Stier, Philip; Johnson, Colin E.; Mann, Graham W.; Bellouin, Nicolas; Bauer, Susanne E.; Bergman, Tommi; Chin, Mian; Diehl, Thomas; Ghan, Steven J.;

Molecular composition of rainwater and aerosol during rain events in León, Spain, using high resolution mass spectrometry.

NASA Astrophysics Data System (ADS)

Fee, Anna

2017-04-01

Anna Fee (1), Markus Kalberer (1), Roberto Fraile (2), Amaya Castro (2), Ana. I. Calvo (2), Carlos Blanco-Alegre (2), Fernanda Oduber (2) and Mário Cerqueira (3). 1 Department of Chemistry, University of Cambridge, UK. 2 Department of Applied Chemistry and Physics, IMARENAB, University of León, Spain. 3 Department of Environmental Planning, University of Aveiro, Portugal. A wide range of atmospheric compounds which are present in rainwater are often also present in aerosol. They can be taken up during cloud droplet formation (in-cloud scavenging) or washed out during precipitation (below-cloud scavenging). Such compounds including aromatic hydrocarbons and organic nitrogen containing compounds are hazardous to health. In this study, the organic chemical composition of rainwater and aerosol from rain events in León, Spain, is being analysed using high resolution mass spectrometry. Collected rainwater along with high volume and low volume filters from rain events which occurred during spring, summer and winter of 2016 have been selected for analysis. Rainwater samples were prepared using Polymeric Reversed Phase Solid Phase Extraction (SPE) and filters have been extracted in water with and without SPE. Three different SPE polymer based sorbents were tested; one for extracting neutral compounds and two which are more suitable for extracting organic compounds containing sulphate and other polar functional groups. The sorbent for extracting neutral compounds was found to yield a higher number of compounds from the sample extraction than the other two varieties. Kendrick masses, Van Krevelen plots and carbon oxidation states have been investigated to identify compounds and patterns. Preliminary results show a predominance in peaks with O/C ratios between 0.2 and 0.7 and H/C ratios between 1 and 2 in both rain and aerosol samples which indicates substituted aromatic compounds. Cellulose material and fatty acids may also be present. The rain samples also have a significant number of peaks with O/C ratios of 0.0 and H/C ratios between 0.5 and 1 which appear to be absent from the aerosol. These may be due to condensed aromatic rings and considering local meteorological factors will aid interpretation. More preliminary results show that on average 70% of assigned compounds in the rainwater contain nitrogen and 28% contain sulphur. In the aerosol, 54% of compounds contain nitrogen and 41% contain sulphur. Further analysis is also predicted to reveal significant seasonal trends between rainwater and aerosol samples.

The washout of combustion-generated hydrogen chloride. [rocket exhaust raindrop scavenging quantification

NASA Technical Reports Server (NTRS)

Fenton, D. L.; Purcell, R. Y.; Hrdina, D.; Knutson, E. O.

1980-01-01

The coefficient for the washout from a rocket exhaust cloud of HCl generated by the combustion of an ammonium perchlorate-based solid rocket propellant such as that to be used for the Space Shuttle Booster is determined. A mathematical model of HCl scavenging by rain is developed taking into account rain droplet size, fall velocity and concentration under various rain conditions, partitioning of exhaust HCl between liquid and gaseous phases, the tendency of HCl to promote water vapor condensation and the concentration and size of droplets within the exhaust cloud. The washout coefficient is calculated as a function of total cloud water content, total HCl content at 100% relative humidity, condensation nuclei concentration and rain intensity. The model predictions are compared with experimental results obtained in scavenging tests with solid rocket exhaust and raindrops of different sizes, and the large reduction in washout coefficient at high relative humidities predicted by the model is not observed. A washout coefficient equal to 0.0000512 times the -0.176 power of the mass concentration of HCl times the 0.773 power of the rainfall intensity is obtained from the experimental data.

Wet deposition of mercury at Lhasa, the capital city of Tibet.

PubMed

Huang, Jie; Kang, Shichang; Wang, Shuxiao; Wang, Long; Zhang, Qianggong; Guo, Junming; Wang, Kang; Zhang, Guoshuai; Tripathee, Lekhendra

2013-03-01

Quantifying the contribution of mercury (Hg) in wet deposition is important for understanding Hg biogeochemical cycling and anthropogenic sources, and verifying atmospheric models. Mercury in wet deposition was measured over the year 2010, in Lhasa the capital and largest city in Tibet. Precipitation samples were analyzed for total Hg (HgT), particulate-bound Hg (HgP), and reactive Hg (HgR). The volume-weighted mean (VWM) concentrations and wet deposition fluxes of HgT, HgP and HgR in precipitation were 24.8 ng L-1 and 8.2 μg m-2 yr-1, 19.9 ng L-1 and 7.1 μg m-2 yr-1, and 0.5 ng L-1 and 0.19 μg m-2 yr-1, respectively. Concentrations of HgT and HgP were statistically higher during the non-monsoon season than during the monsoon season, while HgR concentrations were statistically higher during the monsoon season than during the non-monsoon season. Most HgT, HgP and HgR wet deposition occurred during the monsoon season. Concentrations of HgP and HgR were 77% and 5% of the HgT on average (VWM), respectively. Concentrations of HgT and HgP were weakly negatively correlated with precipitation amount (r2 = 0.09 and 0.10; p < 0.05), indicating that below-cloud scavenging of Hg from the local atmosphere was an important mechanism contributing Hg to precipitation. High HgP%, as well as a significant positive correlation between HgT and HgP, confirms that Hg wet deposition at Lhasa was primarily occurring in the form of atmospheric HgP below-cloud scavenging. Moreover, the HgT concentration, rather than the precipitation amount, was found to be the governing factor affecting HgT wet deposition flux. A comparison among modeled wet and dry deposition fluxes, and measurements suggested that estimates of both wet and dry Hg deposition fluxes by the GEOS-Chem model were 2 to 3 times higher than the measured annual wet flux. Copyright © 2013 Elsevier B.V. All rights reserved.

Modeling the partitioning of organic chemical species in cloud phases with CLEPS (1.1)

NASA Astrophysics Data System (ADS)

Rose, Clémence; Chaumerliac, Nadine; Deguillaume, Laurent; Perroux, Hélène; Mouchel-Vallon, Camille; Leriche, Maud; Patryl, Luc; Armand, Patrick

2018-02-01

The new detailed aqueous-phase mechanism Cloud Explicit Physico-chemical Scheme (CLEPS 1.0), which describes the oxidation of isoprene-derived water-soluble organic compounds, is coupled with a warm microphysical module simulating the activation of aerosol particles into cloud droplets. CLEPS 1.0 was then extended to CLEPS 1.1 to include the chemistry of the newly added dicarboxylic acids dissolved from the particulate phase. The resulting coupled model allows the prediction of the aqueous-phase concentrations of chemical compounds originating from particle scavenging, mass transfer from the gas-phase and in-cloud aqueous chemical reactivity. The aim of the present study was more particularly to investigate the effect of particle scavenging on cloud chemistry. Several simulations were performed to assess the influence of various parameters on model predictions and to interpret long-term measurements conducted at the top of Puy de Dôme (PUY, France) in marine air masses. Specific attention was paid to carboxylic acids, whose predicted concentrations are on average in the lower range of the observations, with the exception of formic acid, which is rather overestimated in the model. The different sensitivity runs highlight the fact that formic and acetic acids mainly originate from the gas phase and have highly variable aqueous-phase reactivity depending on the cloud acidity, whereas C3-C4 carboxylic acids mainly originate from the particulate phase and are supersaturated in the cloud.

Toward a more physical representation of precipitation scavenging in global chemistry models: cloud overlap and ice physics and their impact on tropospheric ozone

NASA Astrophysics Data System (ADS)

Neu, J. L.; Prather, M. J.

2011-08-01

Uptake and removal of soluble trace gases and aerosols by precipitation represents a major uncertainty in the processes that control the vertical distribution of atmospheric trace species. Model representations of precipitation scavenging vary greatly in their complexity, and most are divorced from the physics of precipitation formation and transformation. Here, we describe a new large-scale precipitation scavenging algorithm, developed for the UCI chemistry-transport model (UCI-CTM), that represents a step toward a more physical treatment of scavenging through improvements in the formulation of the removal in sub-gridscale cloudy and ambient environments and their overlap within the column as well as ice phase uptake of soluble species. The UCI algorithm doubles the lifetime of HNO3 in the upper troposphere relative to a scheme with commonly made assumptions about cloud overlap and ice uptake, and provides better agreement with HNO3 observations. We find that the process of ice phase scavenging of HNO3 is a critical component of the tropospheric O3 budget, but that differences in the formulation of ice phase removal, while generating large relative differences in HNO3 abundance, have little impact on NOx and O3. The O3 budget is much more sensitive to the lifetime of HNO4, highlighting the need for better understanding of its interactions with ice and for additional observational constraints.

Toward a more physical representation of precipitation scavenging in global chemistry models: cloud overlap and ice physics and their impact on tropospheric ozone

NASA Astrophysics Data System (ADS)

Neu, J. L.; Prather, M. J.

2012-04-01

Uptake and removal of soluble trace gases and aerosols by precipitation represents a major uncertainty in the processes that control the vertical distribution of atmospheric trace species. Model representations of precipitation scavenging vary greatly in their complexity, and most are divorced from the physics of precipitation formation and transformation. Here, we describe a new large-scale precipitation scavenging algorithm, developed for the UCI chemistry-transport model (UCI-CTM), that represents a step toward a more physical treatment of scavenging through improvements in the formulation of the removal in sub-gridscale cloudy and ambient environments and their overlap within the column as well as ice phase uptake of soluble species. The UCI algorithm doubles the lifetime of HNO3 in the upper troposphere relative to a scheme with commonly used fractional cloud cover assumptions and ice uptake determined by Henry's Law and provides better agreement with HNO3 observations. We find that the process of ice phase scavenging of HNO3 is a critical component of the tropospheric O3 budget, but that NOx and O3 mixing ratios are relatively insensitive to large differences in the removal rate. Ozone abundances are much more sensitive to the lifetime of HNO4, highlighting the need for better understanding of its interactions with ice and for additional observational constraints.

Hydroxy fatty acids in snow pit samples from Mount Tateyama in central Japan: Implications for atmospheric transport of microorganisms and plant waxes associated with Asian dust

NASA Astrophysics Data System (ADS)

Tyagi, Poonam; Kawamura, Kimitaka; Bikkina, Srinivas; Mochizuki, Tomoki; Aoki, Kazuma

2016-11-01

We report here the source apportionment of atmospheric soil microorganisms and higher plant metabolites based on chemical markers (hydroxy fatty acids: FAs) in the snowpack samples collected from Mount Tateyama in central Japan during spring 2009 (N = 6) and 2011 (N = 7). A homologous series of β-hydroxy FAs (C9-C20), constituents of Gram-negative bacteria (GNB), in snowpacks clearly suggest a long-range atmospheric transport of dust-associated bacteria followed by scavenging by snowflakes. Similarly, higher atmospheric abundances of α-(C16-C32) and ω-(C9-C30)-hydroxy FAs in the snow layers containing Asian dust revealed contributions from soil microbes and higher plant epicuticular waxes. Moreover, covariation between the concentrations of hydroxy FAs and water-soluble Ca2+ (dust tracer), together with calculated air mass backward trajectories, demonstrated their source regions such as the Taklamakan Desert, Gobi Desert, and Loess Plateau. A close match of molecular distributions of hydroxy FAs (with the predominance of ω- and β-isomers) is noteworthy between snowpack (present study) and springtime aerosols from Chichijima Island in the western North Pacific (WNP). This observation suggests a "below-cloud scavenging" of transported dust particles and associated soil microbes in the East Asian outflow by snowflakes. These distributions are, however, contrary to those observed in the fresh snow samples from Sapporo, northern Japan (predominance of α-hydroxy FAs), which could be explained by "in-cloud" microbial oxidation processes. This comparison, therefore, provides additional insights regarding the aeolian transport of soil microbes in the East Asian outflow to the WNP, which has not been available.

Evolution of trace elements in the planetary boundary layer in southern China: Effects of dust storms and aerosol-cloud interactions

NASA Astrophysics Data System (ADS)

Li, Tao; Wang, Yan; Zhou, Jie; Wang, Tao; Ding, Aijun; Nie, Wei; Xue, Likun; Wang, Xinfeng; Wang, Wenxing

2017-03-01

Aerosols and cloud water were analyzed at a mountaintop in the planetary boundary layer in southern China during March-May 2009, when two Asian dust storms occurred, to investigate the effects of aerosol-cloud interactions (ACIs) on chemical evolution of atmospheric trace elements. Fe, Al, and Zn predominated in both coarse and fine aerosols, followed by high concentrations of toxic Pb, As, and Cd. Most of these aerosol trace elements, which were affected by dust storms, exhibited various increases in concentrations but consistent decreases in solubility. Zn, Fe, Al, and Pb were the most abundant trace elements in cloud water. The trace element concentrations exhibited logarithmic inverse relationships with the cloud liquid water content and were found highly pH dependent with minimum concentrations at the threshold of pH 5.0. The calculation of Visual MINTEQ model showed that 80.7-96.3% of Fe(II), Zn(II), Pb(II), and Cu(II) existed in divalent free ions, while 71.7% of Fe(III) and 71.5% of Al(III) were complexed by oxalate and fluoride, respectively. ACIs could markedly change the speciation distributions of trace elements in cloud water by pH modification. The in-cloud scavenging of aerosol trace elements likely reached a peak after the first 2-3 h of cloud processing, with scavenging ratios between 0.12 for Cr and 0.57 for Pb. The increases of the trace element solubility (4-33%) were determined in both in-cloud aerosols and postcloud aerosols. These results indicated the significant importance of aerosol-cloud interactions to the evolution of trace elements during the first several cloud condensation/evaporation cycles.

Precipitation scavenging of aerosol particles at a rural site in the Czech Republic

NASA Astrophysics Data System (ADS)

Zikova, Nadezda; Zdimal, Vladimir

2017-04-01

Wet deposition is an important removal mechanism of atmospheric aerosol (AA) in the troposphere, transferring AA to the Earth surface in an aqueous form (Seinfeld and Pandis, 1998). Deposition consists of in-cloud (ICS) and below-cloud (BCS) scavenging, both processes depending on the size, chemical composition and concentration of the AA particles (e.g. Laakso et al., 2003; Ladino et al., 2011). Due to the complexity of the processes and high instrumentation and time demands, a complete understanding is still a challenge, although both phenomena have been extensively studied recently (e.g. Andronache et al. 2006; Chate et al. 2011; Collett et al. 2008). In this work, the influence of ICS and BCS, described by the obscurities (mist, fog and shallow fog) and precipitation (drizzle, rain, snow, rain with snow), on submicron atmospheric aerosol particle number size distributions (PNSD) was studied using 5 years of measurements at the rural background station Košetice. The typical PNSD during individual meteorological phenomena were compared, and the change in the concentrations before and after the beginning of the phenomenon, the scavenging coefficient lambda_s, and the rate of change of the AA concentrations with time were computed. It was found that both obscurities and precipitation have a strong influence on the AA concentrations, both on the total number concentrations and on the particle number size distributions. The scavenging not only lowers the total AA concentrations, it even changes the number of modes on the PNSDs. The PNSD main mode is shifted to the larger particles, and the concentrations of particles smaller than 50 nm in diameter are considerably lower. In nucleation mode, however, wet scavenging does not seem to be the main process influencing the AA concentrations, although its considerable effect on the concentration was proved. During obscurities, there is a typical PNSD to which the PNSD converge at any mist/fog/shallow fog event. The concentrations of AA particles smaller than 80 nm are lower than they are during periods without any phenomenon recorded. Also during liquid precipitation, PNSD are lower when compared to non-event periods, suggesting an effective AA deposition. Precipitation containing frozen hydrometeors behaves differently from liquid precipitation. Concentrations of AA particles larger than 200 nm during precipitation containing solid particles do not differ from non-event cases, suggesting insignificant scavenging. The results of the observed size dependent changes in AA concentrations and PNSD could be used to assess the expected changes in atmosphere during transport and scavenging of AA not only during experimental campaigns, but during modelling as well. This project has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement No. 654109. Andronache at al. 2006. Atmos. Chem. Phys. 6, 4739-54. Chate at al. 2011. Atmos. Res. 99(3-4), 528-536. Collett at al. 2008. Atmos. Res. 87(3-4), 232-241. Laakso et al. 2003. Atmos. Environ. 37(25), 3605-3613. Ladino at al. 2011. J. Atmos. Sci. 68(9), 1853-1864. Seinfeld and Pandis. 2012. Atmospheric Chemistry and Physics: From Air Pollution to Climate Change, Wiley.

Ice Nucleation in the Tropical Tropopause Layer: Implications for Cirrus Occurrence, Cirrus Microphysical Properties, and Dehydration of Air Entering the Stratosphere

NASA Technical Reports Server (NTRS)

Jensen, Eric; Kaercher, Bernd; Ueyama, Rei; Pfister, Leonhard

2017-01-01

Recent laboratory experiments have advanced our understanding of the physical properties and ice nucleating abilities of aerosol particles atlow temperatures. In particular, aerosols containing organics will transition to a glassy state at low temperatures, and these glassy aerosols are moderately effective as ice nuclei. These results have implications for ice nucleation in the cold Tropical Tropopause Layer (TTL; 13-19 km). We have developed a detailed cloud microphysical model that includes heterogeneous nucleation on a variety of aerosol types and homogeneous freezing of aqueous aerosols. This model has been incorporated into one-dimensional simulations of cirrus and water vapor driven by meteorological analysis temperature and wind fields. The model includes scavenging of ice nuclei by sedimenting ice crystals. The model is evaluated by comparing the simulated cloud properties and water vapor concentrations with aircraft and satellite measurements. In this presentation, I will discuss the relative importance of homogeneous and heterogeneous ice nucleation, the impact of ice nuclei scavenging as air slowly ascends through the TTL, and the implications for the final dehydration of air parcels crossing the tropical cold-point tropopause and entering the tropical stratosphere.

What controls the vertical distribution of aerosol? Relationships between process sensitivity in HadGEM3–UKCA and inter-model variation from AeroCom Phase II

DOE PAGES

Kipling, Zak; Stier, Philip; Johnson, Colin E.; ...

2016-02-26

The vertical profile of aerosol is important for its radiative effects, but weakly constrained by observations on the global scale, and highly variable among different models. To investigate the controlling factors in one particular model, we investigate the effects of individual processes in HadGEM3–UKCA and compare the resulting diversity of aerosol vertical profiles with the inter-model diversity from the AeroCom Phase II control experiment. In this way we show that (in this model at least) the vertical profile is controlled by a relatively small number of processes, although these vary among aerosol components and particle sizes. We also show that sufficientlymore » coarse variations in these processes can produce a similar diversity to that among different models in terms of the global-mean profile and, to a lesser extent, the zonal-mean vertical position. However, there are features of certain models' profiles that cannot be reproduced, suggesting the influence of further structural differences between models. In HadGEM3–UKCA, convective transport is found to be very important in controlling the vertical profile of all aerosol components by mass. In-cloud scavenging is very important for all except mineral dust. Growth by condensation is important for sulfate and carbonaceous aerosol (along with aqueous oxidation for the former and ageing by soluble material for the latter). The vertical extent of biomass-burning emissions into the free troposphere is also important for the profile of carbonaceous aerosol. Boundary-layer mixing plays a dominant role for sea salt and mineral dust, which are emitted only from the surface. Dry deposition and below-cloud scavenging are important for the profile of mineral dust only. In this model, the microphysical processes of nucleation, condensation and coagulation dominate the vertical profile of the smallest particles by number (e.g. total CN > 3 nm), while the profiles of larger particles (e.g. CN > 100 nm) are controlled by the same processes as the component mass profiles, plus the size distribution of primary emissions. Here, we also show that the processes that affect the AOD-normalised radiative forcing in the model are predominantly those that affect the vertical mass distribution, in particular convective transport, in-cloud scavenging, aqueous oxidation, ageing and the vertical extent of biomass-burning emissions.« less

Cloud water composition during HCCT-2010: Scavenging efficiencies, solute concentrations, and droplet size dependence of inorganic ions and dissolved organic carbon

NASA Astrophysics Data System (ADS)

van Pinxteren, Dominik; Wadinga Fomba, Khanneh; Mertes, Stephan; Müller, Konrad; Spindler, Gerald; Schneider, Johannes; Lee, Taehyoung; Collett, Jeffrey L.; Herrmann, Hartmut

2016-03-01

Cloud water samples were taken in September/October 2010 at Mt. Schmücke in a rural, forested area in Germany during the Lagrange-type Hill Cap Cloud Thuringia 2010 (HCCT-2010) cloud experiment. Besides bulk collectors, a three-stage and a five-stage collector were applied and samples were analysed for inorganic ions (SO42-,NO3-, NH4+, Cl-, Na+, Mg2+, Ca2+, K+), H2O2 (aq), S(IV), and dissolved organic carbon (DOC). Campaign volume-weighted mean concentrations were 191, 142, and 39 µmol L-1 for ammonium, nitrate, and sulfate respectively, between 4 and 27 µmol L-1 for minor ions, 5.4 µmol L-1 for H2O2 (aq), 1.9 µmol L-1 for S(IV), and 3.9 mgC L-1 for DOC. The concentrations compare well to more recent European cloud water data from similar sites. On a mass basis, organic material (as DOC × 1.8) contributed 20-40 % (event means) to total solute concentrations and was found to have non-negligible impact on cloud water acidity. Relative standard deviations of major ions were 60-66 % for solute concentrations and 52-80 % for cloud water loadings (CWLs). The similar variability of solute concentrations and CWLs together with the results of back-trajectory analysis and principal component analysis, suggests that concentrations in incoming air masses (i.e. air mass history), rather than cloud liquid water content (LWC), were the main factor controlling bulk solute concentrations for the cloud studied. Droplet effective radius was found to be a somewhat better predictor for cloud water total ionic content (TIC) than LWC, even though no single explanatory variable can fully describe TIC (or solute concentration) variations in a simple functional relation due to the complex processes involved. Bulk concentrations typically agreed within a factor of 2 with co-located measurements of residual particle concentrations sampled by a counterflow virtual impactor (CVI) and analysed by an aerosol mass spectrometer (AMS), with the deviations being mainly caused by systematic differences and limitations of the approaches (such as outgassing of dissolved gases during residual particle sampling). Scavenging efficiencies (SEs) of aerosol constituents were 0.56-0.94, 0.79-0.99, 0.71-98, and 0.67-0.92 for SO42-, NO3-, NH4+, and DOC respectively when calculated as event means with in-cloud data only. SEs estimated using data from an upwind site were substantially different in many cases, revealing the impact of gas-phase uptake (for volatile constituents) and mass losses across Mt. Schmücke likely due to physical processes such as droplet scavenging by trees and/or entrainment. Drop size-resolved cloud water concentrations of major ions SO42-, NO3-, and NH4+ revealed two main profiles: decreasing concentrations with increasing droplet size and "U" shapes. In contrast, profiles of typical coarse particle mode minor ions were often increasing with increasing drop size, highlighting the importance of a species' particle concentration size distribution for the development of size-resolved solute concentration patterns. Concentration differences between droplet size classes were typically < 2 for major ions from the three-stage collector and somewhat more pronounced from the five-stage collector, while they were much larger for minor ions. Due to a better separation of droplet populations, the five-stage collector was capable of resolving some features of solute size dependencies not seen in the three-stage data, especially sharp concentration increases (up to a factor of 5-10) in the smallest droplets for many solutes.

CALIPSO Observations of Transatlantic Dust: Vertical Stratification and Effect of Clouds

NASA Technical Reports Server (NTRS)

Yang, Weidong; Marshak, Alexander; Varnai, Tamas; Kalashnikova, Olga V.; Kostinski, Alexander B.

2014-01-01

We use CALIOP nighttime measurements of lidar backscatter, color and depolarization ratios, as well as particulate retrievals during the summer of 2007 to study transatlantic dust properties downwind of Saharan sources, and to examine the influence of nearby clouds on dust. Our analysis suggests that (1) under clear skies, while lidar backscatter and color ratio do not change much with altitude and longitude in the Saharan Air Layer (SAL), depolarization ratio increases with altitude and decreases westward in the SAL (2) the vertical lapse rate of dust depolarization ratio, introduced here, increases within SAL as plumes move westward (3) nearby clouds barely affect the backscatter and color ratio of dust volumes within SAL but not so below SAL. Moreover, the presence of nearby clouds tends to decrease the depolarization of dust volumes within SAL. Finally, (4) the odds of CALIOP finding dust below SAL next to clouds are about of those far away from clouds. This feature, together with an apparent increase in depolarization ratio near clouds, indicates that particles in some dust volumes loose asphericity in the humid air near clouds, and cannot be identified by CALIPSO as dust.

Prebiotic chemistry in clouds

NASA Technical Reports Server (NTRS)

Oberbeck, Verne R.; Marshall, John; Shen, Thomas

1991-01-01

The chemical evolution hypothesis of Woese (1979), according to which prebiotic reactions occurred rapidly in droplets in giant atmospheric reflux columns was criticized by Scherer (1985). This paper proposes a mechanism for prebiotic chemistry in clouds that answers Scherer's concerns and supports Woese's hypothesis. According to this mechanism, rapid prebiotic chemical evolution was facilitated on the primordial earth by cycles of condensation and evaporation of cloud drops containing clay condensation nuclei and nonvolatile monomers. For example, amino acids supplied by, or synthesized during entry of meteorites, comets, and interplanetary dust, would have been scavenged by cloud drops containing clay condensation nuclei and would be polymerized within cloud systems during cycles of condensation, freezing, melting, and evaporation of cloud drops.

Cloud radiative properties and aerosol - cloud interaction

NASA Astrophysics Data System (ADS)

Viviana Vladutescu, Daniela; Gross, Barry; Li, Clement; Han, Zaw

2015-04-01

The presented research discusses different techniques for improvement of cloud properties measurements and analysis. The need for these measurements and analysis arises from the high errors noticed in existing methods that are currently used in retrieving cloud properties and implicitly cloud radiative forcing. The properties investigated are cloud fraction (cf) and cloud optical thickness (COT) measured with a suite of collocated remote sensing instruments. The novel approach makes use of a ground based "poor man's camera" to detect cloud and sky radiation in red, green, and blue with a high spatial resolution of 30 mm at 1km. The surface-based high resolution photography provides a new and interesting view of clouds. As the cloud fraction cannot be uniquely defined or measured, it depends on threshold and resolution. However as resolution decreases, cloud fraction tends to increase if the threshold is below the mean, and vice versa. Additionally cloud fractal dimension also depends on threshold. Therefore these findings raise concerns over the ability to characterize clouds by cloud fraction or fractal dimension. Our analysis indicate that Principal Component analysis may lead to a robust means of quantifying cloud contribution to radiance. The cloud images are analyzed in conjunction with a collocated CIMEL sky radiometer, Microwave Radiometer and LIDAR to determine homogeneity and heterogeneity. Additionally, MFRSR measurements are used to determine the cloud radiative properties as a validation tool to the results obtained from the other instruments and methods. The cloud properties to be further studied are aerosol- cloud interaction, cloud particle radii, and vertical homogeneity.

Cloud water composition during HCCT-2010: Scavenging efficiencies, solute concentrations, and droplet size dependence of inorganic ions and dissolved organic carbon

NASA Astrophysics Data System (ADS)

van Pinxteren, D.; Fomba, K. W.; Mertes, S.; Müller, K.; Spindler, G.; Schneider, J.; Lee, T.; Collett, J.; Herrmann, H.

2015-09-01

Cloud water samples were taken in September/October 2010 at Mt. Schmücke in a rural, forested area in Germany during the Lagrange-type Hill Cap Cloud Thuringia 2010 (HCCT-2010) cloud experiment. Besides bulk collectors, a 3-stage and a 5-stage collector were applied and samples were analysed for inorganic ions (SO42-, NO3-, NH4+, Cl-, Na+, Mg2+, Ca2+, K+), H2O2 (aq), S(IV), and dissolved organic carbon (DOC). Campaign volume-weighted mean concentrations were 191, 142, and 39 μmol L-1 for ammonium, nitrate, and sulfate, respectively, between 4 and 27 μmol L-1 for minor ions, 5.4 μmol L-1 for H2O2 (aq), 1.9 μmol L-1 for S(IV), and 3.9 mgC L-1 for DOC. The concentrations compare well to more recent European cloud water data from similar sites. On a mass basis, organic material (as DOC · 1.8) contributed 20-40 % (event means) to total solute concentrations and was found to have non-negligible impact on cloud water acidity. Relative standard deviations of major ions were 60-66 % for solute concentrations and 52-80 % for cloud water loadings (CWLs). Contrary to some earlier suggestions, the similar variability of solute concentrations and CWLs together with the results of back trajectory analysis and principal component analysis, suggests that concentrations in incoming air masses (i.e. air mass history), rather than cloud liquid water content (LWC) was the main factor controlling bulk solute concentrations at Mt. Schmücke. Droplet effective radius was found to be a somewhat better predictor for cloud water total ionic content (TIC) than LWC, even though no single explanatory variable can fully describe TIC (or solute concentration) variations in a simple functional relation due to the complex processes involved. Bulk concentrations typically agreed within a factor of 2 with co-located measurements of residual particle concentrations sampled by a counterflow virtual impactor (CV) and analysed by an aerosol mass spectrometer (AMS), with the deviations being mainly caused by systematic differences and limitations of the approaches (such as outgassing of dissolved gases during residual particle sampling). Scavenging efficiencies (SEs) of aerosol constituents were 0.56-0.94, 0.79-0.99, 0.71-98, and 0.67-0.92 for SO42-, NO3-, NH4+, and DOC, respectively, when calculated as event means with in-cloud data only. SEs estimated using data from an upwind site were substantially different in many cases, revealing the impact of gas-phase uptake (for volatile constituents) and mass losses across Mt. Schmücke likely due to physical processes such as droplet scavenging by trees and/or entrainment. Drop size-resolved cloud water concentrations of major ions SO42-, NO3-, and NH4+ revealed two main profiles: decreasing concentrations with increasing droplet size and "U"-shapes. In contrast, profiles of typical coarse particle mode minor ions were often increasing with increasing drop size, highlighting the importance of a species' particle concentration size distribution for the development of size-resolved solute concentration patterns. Concentration differences between droplet size classes were typically < 2 for major ions from the 3-stage collector and somewhat more pronounced from the 5-stage collector, while they were much larger for minor ions. Due to a better separation of droplet populations, the 5-stage collector was capable of resolving some features of solute size dependencies not seen in the 3-stage data, especially sharp concentration increases (up to a factor of 5-10) in the smallest droplets for many solutes.

Influences of drizzle on stratocumulus cloudiness and organization [Influences of drizzle on cloudiness and stratocumulus organization

DOE PAGES

Zhou, Xiaoli; Heus, Thijs; Kollias, Pavlos

2017-06-06

Large-eddy simulations are used to study the influence of drizzle on stratocumulus organization, based on measurements made as part of the Second Dynamics and Chemistry of the Marine Stratocumulus field study-II. Cloud droplet number concentration ( N c) is prescribed and considered as the proxy for different aerosol loadings. Our study shows that the amount of cloudiness does not decrease linearly with precipitation rate. An N c threshold is observed below which the removal of cloud water via precipitation efficiently reduces cloud depth, allowing evaporation to become efficient and quickly remove the remaining thin clouds, facilitating a fast transition frommore » closed cells to open cells. Using Fourier analysis, stratocumulus length scales are found to increase with drizzle rates. Raindrop evaporation below 300 m lowers the cloud bases and amplifies moisture variances in the subcloud layer, while it does not alter the horizontal scales in the cloud layer, suggesting that moist cold pool dynamic forcings are not essential for mesoscale organization of stratocumulus. Furthermore, the cloud scales are greatly increased when the boundary layer is too deep to maintain well mixed.« less

Influences of drizzle on stratocumulus cloudiness and organization [Influences of drizzle on cloudiness and stratocumulus organization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, Xiaoli; Heus, Thijs; Kollias, Pavlos

Large-eddy simulations are used to study the influence of drizzle on stratocumulus organization, based on measurements made as part of the Second Dynamics and Chemistry of the Marine Stratocumulus field study-II. Cloud droplet number concentration ( N c) is prescribed and considered as the proxy for different aerosol loadings. Our study shows that the amount of cloudiness does not decrease linearly with precipitation rate. An N c threshold is observed below which the removal of cloud water via precipitation efficiently reduces cloud depth, allowing evaporation to become efficient and quickly remove the remaining thin clouds, facilitating a fast transition frommore » closed cells to open cells. Using Fourier analysis, stratocumulus length scales are found to increase with drizzle rates. Raindrop evaporation below 300 m lowers the cloud bases and amplifies moisture variances in the subcloud layer, while it does not alter the horizontal scales in the cloud layer, suggesting that moist cold pool dynamic forcings are not essential for mesoscale organization of stratocumulus. Furthermore, the cloud scales are greatly increased when the boundary layer is too deep to maintain well mixed.« less

A new characterization of supercooled clouds below 10,000 feet AGL

NASA Technical Reports Server (NTRS)

Masters, C. O.

1985-01-01

Icing caused by supercooled clouds below 10,000 feet were characterized with a view toward a change in FAA standards for civil aircraft ice protection standards. Current techniques in cloud physics were employed.

“Towards building better linkages between aqueous phase ...

EPA Pesticide Factsheets

Currently, CMAQ’s aqueous phase chemistry routine (AQCHEM-base) assumes Henry’s Law equilibrium and employs a forward Euler method to solve a small set of oxidation equations, considering the additional processes of aitken scavenging and wet deposition in series and employing a bisection method to calculate H+ concentrations. With potentially hundreds of reactions that may be important in cloud water and only seven reactions in the current model, expansion of the existing mechanism is an important area of investigation. However, with the current mechanism hardwired into the solver code, the module is difficult to expand with additional chemistry. It also ignores the impacts of mass transfer limitations on cloud chemistry which may be significant. Here, the Kinetic PreProcessor has been applied to generate a Rosenbrock solver for the CMAQ v5.0.1 aqueous phase chemistry mechanism. The module has been updated to simultaneously solve kinetic mass transfer between the phases, dissociation/association, chemical kinetics, Aitken scavenging, and wet deposition. This will allow for easier expansion of the chemical mechanism in the future and a better link between aqueous phase chemistry and droplet microphysics. The National Exposure Research Laboratory (NERL) Atmospheric Modeling and Analysis Division (AMAD) conducts research in support of EPA mission to protect human health and the environment. AMAD research program is engaged in developing and evaluating pre

Black carbon mixing state impacts on cloud microphysical properties: effects of aerosol plume and environmental conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ching, Ping Pui; Riemer, Nicole; West, Matthew

2016-05-27

Black carbon (BC) is usually mixed with other aerosol species within individual aerosol particles. This mixture, along with the particles' size and morphology, determines the particles' optical and cloud condensation nuclei properties, and hence black carbon's climate impacts. In this study the particle-resolved aerosol model PartMC-MOSAIC was used to quantify the importance of black carbon mixing state for predicting cloud microphysical quantities. Based on a set of about 100 cloud parcel simulations a process level analysis framework was developed to attribute the response in cloud microphysical properties to changes in the underlying aerosol population ("plume effect") and the cloud parcelmore » cooling rate ("parcel effect"). It shows that the response of cloud droplet number concentration to changes in BC emissions depends on the BC mixing state. When the aerosol population contains mainly aged BC particles an increase in BC emission results in increasing cloud droplet number concentrations ("additive effect"). In contrast, when the aerosol population contains mainly fresh BC particles they act as sinks for condensable gaseous species, resulting in a decrease in cloud droplet number concentration as BC emissions are increased ("competition effect"). Additionally, we quantified the error in cloud microphysical quantities when neglecting the information on BC mixing state, which is often done in aerosol models. The errors ranged from -12% to +45% for the cloud droplet number fraction, from 0% to +1022% for the nucleation-scavenged black carbon (BC) mass fraction, from -12% to +4% for the effective radius, and from -30% to +60% for the relative dispersion.« less

Analysis of Rapidly Developing Low Cloud Ceilings in a Stable Environment

NASA Technical Reports Server (NTRS)

Bauman, William H., III; Barrett, Joe H., III; Case, Jonathan L.; Wheeler, Mark M.; Baggett, G. Wayne

2006-01-01

Forecasters at the Space Meteorology Group (SMG) issue 30 to 90 minute forecasts for low cloud ceilings at the Space Shuttle Landing Facility (TTS) to support Space Shuttle landings. Mission verification statistics have shown ceilings to be the number one forecast challenge for SMG. More specifically, forecasters at SMG are concerned with any rapidly developing clouds/ceilings below 8000 ft in a stable, capped thermodynamic environment. Therefore, the Applied Meteorology Unit (AMU) was tasked to examine archived events of rapid stable cloud formation resulting in ceilings below 8000 ft, and document the atmospheric regimes favoring this type of cloud development. The AMU examined the cool season months of November to March during the years of 1993-2003 for days that had low-level inversions and rapid, stable low cloud formation that resulted in ceilings violating the Space Shuttle Flight Rules. The AMU wrote and modified existing code to identify inversions from the morning (-10 UTC) Cape Canaveral, FL rawinsonde (XMR) during the cool season and output pertinent sounding information. They parsed all days with cloud ceilings below 8000 ft at TTS, forming a database of possible rapidly-developing low ceiling events. Days with precipitation or noticeable fog burn-off situations were excluded from the database. In the first phase of this work, only the daytime hours were examined for possible ceiling development events since low clouds are easier to diagnose with visible satellite imagery. Phase II of this work includes expanding the database to include nighttime cases which is underway as this abstract is being written. For the nighttime cases, the AMU will analyze both the 00 UTC soundings and the 10 UTC soundings to examine those data for the presence of a low-level inversion. The 00 UTC soundings will probably not have a surface-based inversion, but the presence of inversions or "neutral" layers aloft and below 8,000 ft will most likely help define the stable regime, being a thermodynamically "capped" environment. Occurrences of elevated low-level inversions or stable layers will be highlighted in conjunction with nights that experienced a possible development or onset of cloud ceilings below 8,000 ft. Using these criteria to narrow down the database, the AMU will then use archived IR satellite imagery for these possible events. This presentation summarizes the composite meteorological conditions for 20 daytime event days with rapid low cloud ceiling formation and 48 non-events days consisting of advection or widespread low cloud ceilings and describes two sample cases of daytime rapidly-developing low cloud ceilings. The authors will also summarize the work from the nighttime cases and describe a representative sample case from this data set.

Space Weather Connections to Clouds and Climate

NASA Astrophysics Data System (ADS)

Tinsley, B. A.

2004-12-01

There is now a considerable amount of observational data and theoretical work pointing to a link between space weather and atmospheric electricity, and then between atmospheric electricity and cloud cover and precipitation, which ultimately affect climate and the biosphere. Studies so far have been largely confined to the Earth, but may be applicable to all planets with clouds in their atmospheres. The current density Jz, that is the return current flowing downward through clouds in the global circuit, is modulated by the galactic cosmic ray flux; by solar energetic particles; by the dawn-dusk polar cap potential difference; and by the precipitation of relativistic electrons from the radiation belts. The flow of Jz through clouds generates unipolar space charge, which is positive at cloud tops and negative at cloud base. This charge attaches to aerosol particles, and affects their interaction with other particles and droplets. Ultrafine aerosol particles are formed around ions and are preserved from scavenging on background aerosols, and preserved for growth by vapor deposition, by space charge at the bases and tops of layer clouds. There is electro-preservation of both ultrafines and of existing CCN that leads to increases in CCN concentration, and increases in cloud cover and reduction in both droplet size and precipitation by the `indirect aerosol effect'. For cold clouds and larger aerosol particles that act as ice forming nuclei, the rate of scavenging of the IFN by large supercooled droplets varies with space charge. Changes in space weather affect both ion production and Jz in planetary atmospheres. In addition, changes in cosmic ray flux affect conductivity within thunderclouds and may affect the output of the thundercloud generators in the global circuit. Thus all four processes, (a) ion-induced nucleation, (b) electro-preservation of leading to increases in CCN concentration and the indirect aerosol effect, (c) contact ice nucleation affecting the production of ices, (d) cosmic ray effects on the generators of the global circuit, are potential links between space weather and life on planets.

Description and evaluation of GLOMAP-mode: a modal global aerosol microphysics model for the UKCA composition-climate model

NASA Astrophysics Data System (ADS)

Mann, G. W.; Carslaw, K. S.; Spracklen, D. V.; Ridley, D. A.; Manktelow, P. T.; Chipperfield, M. P.; Pickering, S. J.; Johnson, C. E.

2010-10-01

A new version of the Global Model of Aerosol Processes (GLOMAP) is described, which uses a two-moment pseudo-modal aerosol dynamics approach rather than the original two-moment bin scheme. GLOMAP-mode simulates the multi-component global aerosol, resolving sulfate, sea-salt, dust, black carbon (BC) and particulate organic matter (POM), the latter including primary and biogenic secondary POM. Aerosol processes are simulated in a size-resolved manner including primary emissions, secondary particle formation by binary homogeneous nucleation of sulfuric acid and water, particle growth by coagulation, condensation and cloud-processing and removal by dry deposition, in-cloud and below-cloud scavenging. A series of benchmark observational datasets are assembled against which the skill of the model is assessed in terms of normalised mean bias (b) and correlation coefficient (R). Overall, the model performs well against the datasets in simulating concentrations of aerosol precursor gases, chemically speciated particle mass, condensation nuclei (CN) and cloud condensation nuclei (CCN). Surface sulfate, sea-salt and dust mass concentrations are all captured well, while BC and POM are biased low (but correlate well). Surface CN concentrations compare reasonably well in free troposphere and marine sites, but are underestimated at continental and coastal sites related to underestimation of either primary particle emissions or new particle formation. The model compares well against a compilation of CCN observations covering a range of environments and against vertical profiles of size-resolved particle concentrations over Europe. The simulated global burden, lifetime and wet removal of each of the simulated aerosol components is also examined and each lies close to multi-model medians from the AEROCOM model intercomparison exercise.

Description and evaluation of GLOMAP-mode: a modal global aerosol microphysics model for the UKCA composition-climate model

NASA Astrophysics Data System (ADS)

Mann, G. W.; Carslaw, K. S.; Spracklen, D. V.; Ridley, D. A.; Manktelow, P. T.; Chipperfield, M. P.; Pickering, S. J.; Johnson, C. E.

2010-05-01

A new version of the Global Model of Aerosol Processes (GLOMAP) is described, which uses a two-moment modal aerosol scheme rather than the original two-moment bin scheme. GLOMAP-mode simulates the multi-component global aerosol, resolving sulphate, sea-salt, dust, black carbon (BC) and particulate organic matter (POM), the latter including primary and biogenic secondary POM. Aerosol processes are simulated in a size-resolved manner including primary emissions, secondary particle formation by binary homogeneous nucleation of sulphuric acid and water, particle growth by coagulation, condensation and cloud-processing and removal by dry deposition, in-cloud and below-cloud scavenging. A series of benchmark observational datasets are assembled against which the skill of the model is assessed in terms of normalised mean bias (b) and correlation coefficient (R). Overall, the model performs well against the datasets in simulating concentrations of aerosol precursor gases, chemically speciated particle mass, condensation nuclei (CN) and cloud condensation nuclei (CCN). Surface sulphate, sea-salt and dust mass concentrations are all captured well, while BC and POM are biased low (but correlate well). Surface CN concentrations compare reasonably well in free troposphere and marine sites, but are underestimated at continental and coastal sites related to underestimation of either primary particle emissions or new particle formation. The model compares well against a compilation of CCN observations covering a range of environments and against vertical profiles of size-resolved particle concentrations over Europe. The simulated global burden, lifetime and wet removal of each of the simulated aerosol components is also examined and each lies close to multi-model medians from the AEROCOM model intercomparison exercise.

Impact of capturing rainfall scavenging intermittency using cloud superparameterization on simulated continental scale wildfire smoke transport

NASA Astrophysics Data System (ADS)

Pritchard, M. S.; Kooperman, G. J.; Zhao, Z.; Wang, M.; Russell, L. M.; Somerville, R. C.; Ghan, S. J.

2011-12-01

Evaluating the fidelity of new aerosol physics in climate models is confounded by uncertainties in source emissions, systematic error in cloud parameterizations, and inadequate sampling of long-range plume concentrations. To explore the degree to which cloud parameterizations distort aerosol processing and scavenging, the Pacific Northwest National Laboratory (PNNL) Aerosol-Enabled Multi-Scale Modeling Framework (AE-MMF), a superparameterized branch of the Community Atmosphere Model Version 5 (CAM5), is applied to represent the unusually active and well sampled North American wildfire season in 2004. In the AE-MMF approach, the evolution of double moment aerosols in the exterior global resolved scale is linked explicitly to convective statistics harvested from an interior cloud resolving scale. The model is configured in retroactive nudged mode to observationally constrain synoptic meteorology, and Arctic wildfire activity is prescribed at high space/time resolution using data from the Global Fire Emissions Database. Comparisons against standard CAM5 bracket the effect of superparameterization to isolate the role of capturing rainfall intermittency on the bulk characteristics of 2004 Arctic plume transport. Ground based lidar and in situ aircraft wildfire plume constraints from the International Consortium for Atmospheric Research on Transport and Transformation field campaign are used as a baseline for model evaluation.

Individual aerosol particles in and below clouds along a Mt. Fuji slope: Modification of sea-salt-containing particles by in-cloud processing

NASA Astrophysics Data System (ADS)

Ueda, S.; Hirose, Y.; Miura, K.; Okochi, H.

2014-02-01

Sizes and compositions of atmospheric aerosol particles can be altered by in-cloud processing by absorption/adsorption of gaseous and particulate materials and drying of aerosol particles that were formerly activated as cloud condensation nuclei. To elucidate differences of aerosol particles before and after in-cloud processing, aerosols were observed along a slope of Mt. Fuji, Japan (3776 m a.s.l.) during the summer in 2011 and 2012 using a portable laser particle counter (LPC) and an aerosol sampler. Aerosol samples for analyses of elemental compositions were obtained using a cascade impactor at top-of-cloud, in-cloud, and below-cloud altitudes. To investigate composition changes via in-cloud processing, individual particles (0.5-2 μm diameter) of samples from five cases (days) collected at different altitudes under similar backward air mass trajectory conditions were analyzed using a transmission electron microscope (TEM) equipped with an energy dispersive X-ray analyzer. For most cases (four cases), most particles at all altitudes mainly comprised sea salts: mainly Na with some S and/or Cl. Of those, in two cases, sea-salt-containing particles with Cl were found in below-cloud samples, although sea-salt-containing particles in top-of-cloud samples did not contain Cl. This result suggests that Cl in the sea salt was displaced by other cloud components. In the other two cases, sea-salt-containing particles on samples at all altitudes were without Cl. However, molar ratios of S to Na (S/Na) of the sea-salt-containing particles of top-of-cloud samples were higher than those of below-cloud samples, suggesting that sulfuric acid or sulfate was added to sea-salt-containing particles after complete displacement of Cl by absorption of SO2 or coagulation with sulfate. The additional volume of sulfuric acid in clouds for the two cases was estimated using the observed S/Na values of sea-salt-containing particles. The estimation revealed that size changes by in-cloud processing from below-cloud to top-of-cloud altitudes were less than 6% for sizes of 0.5-2 μm diameter. The obtained results will be useful to evaluate the aging effect and transition of aerosol particles through in-cloud processing.

Shuttle landing facility cloud cover study: Climatological analysis and two tenths cloud cover rule evaluation

NASA Technical Reports Server (NTRS)

Atchison, Michael K.; Schumann, Robin; Taylor, Greg; Warburton, John; Wheeler, Mark; Yersavich, Ann

1993-01-01

The two-tenths cloud cover rule in effect for all End Of Mission (EOM) STS landings at the Kennedy Space Center (KSC) states: 'for scattered cloud layers below 10,000 feet, cloud cover must be observed to be less than or equal to 0.2 at the de-orbit burn go/no-go decision time (approximately 90 minutes before landing time)'. This rule was designed to protect against a ceiling (below 10,000 feet) developing unexpectedly within the next 90 minutes (i.e., after the de-orbit burn decision and before landing). The Applied Meteorological Unit (AMU) developed and analyzed a database of cloud cover amounts and weather conditions at the Shuttle Landing Facility for a five-year (1986-1990) period. The data indicate the best time to land the shuttle at KSC is during the summer while the worst time is during the winter. The analysis also shows the highest frequency of landing opportunities occurs for the 0100-0600 UTC and 1300-1600 UTC time periods. The worst time of the day to land a shuttle is near sunrise and during the afternoon. An evaluation of the two-tenths cloud cover rule for most data categorizations has shown that there is a significant difference in the proportions of weather violations one and two hours subsequent to initial conditions of 0.2 and 0.3 cloud cover. However, for May, Oct., 700 mb northerly wind category, 1500 UTC category, and 1600 UTC category there is some evidence that the 0.2 cloud cover rule may be overly conservative. This possibility requires further investigation. As a result of these analyses, the AMU developed nomograms to help the Spaceflight Meteorological Group (SMG) and the Cape Canaveral Forecast Facility (CCFF) forecast cloud cover for EOM and Return to Launch Site (RTLS) at KSC. Future work will include updating the two tenths database, further analysis of the data for several categorizations, and developing a proof of concept artificial neural network to provide forecast guidance of weather constraint violations for shuttle landings.

Processes that generate and deplete liquid water and snow in thin midlevel mixed-phase clouds

NASA Astrophysics Data System (ADS)

Smith, Adam J.; Larson, Vincent E.; Niu, Jianguo; Kankiewicz, J. Adam; Carey, Lawrence D.

2009-06-01

This paper uses a numerical model to investigate microphysical, radiative, and dynamical processes in mixed-phase altostratocumulus clouds. Three cloud cases are chosen for study, each of which was observed by aircraft during the fifth or ninth Complex Layered Cloud Experiment (CLEX). These three clouds are numerically modeled using large-eddy simulation (LES). The observed and modeled clouds consist of a mixed-phase layer with a quasi-adiabatic profile of liquid, and a virga layer below that consists of snow. A budget of cloud (liquid) water mixing ratio is constructed from the simulations. It shows that large-scale ascent/descent, radiative cooling/heating, turbulent transport, and microphysical processes are all significant. Liquid is depleted indirectly via depositional growth of snow (the Bergeron-Findeisen process). This process is more influential than depletion of liquid via accretional growth of snow. Also constructed is a budget of snow mixing ratio, which turns out to be somewhat simpler. It shows that snow grows by deposition in and below the liquid (mixed-phase) layer, and sublimates in the remainder of the virga region below. The deposition and sublimation are balanced primarily by sedimentation, which transports the snow from the growth region to the sublimation region below. In our three clouds, the vertical extent of the virga layer is influenced more by the profile of saturation ratio below the liquid (mixed-phase) layer than by the mixing ratio of snow at the top of the virga layer.

Occupational exposure to nitrous oxide - the role of scavenging and ventilation systems in reducing the exposure level in operating rooms.

PubMed

Krajewski, Wojciech; Kucharska, Malgorzata; Wesolowski, Wiktor; Stetkiewicz, Jan; Wronska-Nofer, Teresa

2007-03-01

The aim of this study was to assess the level of occupational exposure to nitrous oxide (N(2)O) in operating rooms (ORs), as related to different ventilation and scavenging systems used to remove waste anaesthetic gases from the work environment. The monitoring of N(2)O in the air covered 35 ORs in 10 hospitals equipped with different systems for ventilation and anaesthetic scavenging. The examined systems included: natural ventilation with supplementary fresh air provided by a pressure ventilation system (up to 6 air changes/h); pressure and exhaust ventilation systems equipped with ventilation units supplying fresh air to and discharging contaminated air outside the working area (more than 10 air changes/h); complete air-conditioning system with laminar air flow (more than 15 air changes/h). The measurements were carried out during surgical procedures (general anaesthesia induced intravenously and maintained with inhaled N(2)O and sevofluran delivered through cuffed endotracheal tubes) with connected or disconnected air scavenging. Air was collected from the breathing zone of operating personnel continuously through the whole time of anaesthesia to Tedlar((R)) bags, and N(2)O concentrations in air samples were analyzed by adsorption gas chromatography/mass spectrometry. N(2)O levels in excess of the occupational exposure limit (OEL) value of 180mg/m(3) were registered in all ORs equipped with ventilation systems alone. The OEL value was exceeded several times in rooms with natural ventilation plus supplementary pressure ventilations and twice or less in those with pressure/exhaust ventilation systems or air conditioning. N(2)O levels below or within the OEL value were observed in rooms where the system of air conditioning or pressure/exhaust ventilation was combined with scavenging systems. Systems combining natural/pressure ventilation with scavenging were inadequate to maintain N(2)O concentration below the OEL value. Air conditioning and an efficient pressure/exhaust ventilation (above 12 air exchanges/h) together with efficient active scavenging systems are sufficient to sustain N(2)O exposure in ORs at levels below or within the OEL value of 180mg/m(3).

Subvisual Cirrus cloud properties derived from a FIRE IFO case study

NASA Technical Reports Server (NTRS)

Sassen, Kenneth; Griffin, M. K.; Dodd, G. C.

1990-01-01

From the central Wisconsin IFO field at Wausau, the Mobile Polarization Lidar and a surface radiation station from the Lamont-Doherty Geological Observatory observed two very tenuous cirrus clouds on 21 October 1986. The clouds were present just below the height of the tropopause, between -60 to -70 C. The first cloud was not detected visually, and is classified as subvisual cirrus. The second, a relatively narrow cloud band that was probably the remnants of an aircraft contrail, can be termed zenith-subvisual since, although it was invisible in the zenith direction, it could be discerned when viewed at lower elevation angles and also due to strong solar forward-scattering and corona effects. The observations provide an opportunity to assess the threshold cloud optical thickness associated with cirrus cloud visibility. Ruby lidar backscattered signals were converted to isotropic volume backscatter coefficients by applying the pure-molecular scattering assumption just below the cloud base. The backscattering coefficient due to the cloud is then obtained and expressed in relation to the molecular backscattering coefficient in terms of the scattering ratio R. The linear depolarization ratio for the cloud is computed after removing the essentially parallel-polarized scattering contribution from air molecules. The values are also applied to determine the cloud optical thickness through the use of backscatter-to-extinction ratio, and the concentration of cloud particles using the backscattering gain, and the effective diameter of the particles obtained from the analysis of solar corona photographs. The sizes of the particles generating the corona are related to the angular separations between the centers of the red bands and the sun, yielding diameters of approximately 25 microns. The direct and diffuse components of shortwave radiation fluxes, measured by full hemispheric pyranometers, were used to compute the nadir optical thickness of the total atmosphere.

Cloud Chemistry in the United States: Problems and Prospects

NASA Astrophysics Data System (ADS)

Carlton, A. G.; Barth, M. C.; Lance, S.; Fahey, K.; McNeill, V. F.; Weber, R. J.

2017-12-01

Clouds cover 60% of the Earth's surface at a given time and are the primary means by which atmospheric trace species are lofted from the polluted boundary layer to the free troposphere. Clouds also play an important role as atmospheric aqueous phase reactors, scavenging soluble gas phase precursors and providing a medium for oxidation reactions that yield lower volatility products that contribute to increased aerosol mass when cloud drops evaporate. On a global average, most sulfate particles are formed during cloud processing, and organic particles known to form through aqueous phase pathways are found above clouds. However, atmospheric chemistry observations are generally biased for clear sky conditions. For example, aircraft field deployments typically avoid clouds. Satellite retrievals impacted by clouds are often screened from the final data products. This hinders knowledge of cloud chemistry and the impacts on tropospheric composition. In this work, we explore temporal and geospatial trends in trace species related to cloud processing in the U.S. with a focus on organic chemistry. We apply 3-dimensional and 0-dimensional models to recent campaigns and mountaintop cloud sampling sites, and compare to measurements.

Fluorescent pseudomonads isolated from Hebridean cloud and rain water produce biosurfactants but do not cause ice nucleation

NASA Astrophysics Data System (ADS)

Ahern, H. E.; Walsh, K. A.; Hill, T. C. J.; Moffett, B. F.

2007-02-01

Microorganisms were discovered in clouds over 100 years ago but information on bacterial community structure and function is limited. Clouds may not only be a niche within which bacteria could thrive but they might also influence dynamic processes using ice nucleating and cloud condensing abilities. Cloud and rain samples were collected from two mountains in the Outer Hebrides, NW Scotland, UK. Community composition was determined using a combination of amplified 16S ribosomal DNA restriction analysis and sequencing. 256 clones yielded 100 operational taxonomic units (OTUs) of which half were related to bacteria from terrestrial psychrophilic environments. Cloud samples were dominated by a mixture of fluorescent Pseudomonas spp., some of which have been reported to be ice nucleators. It was therefore possible that these bacteria were using the ice nucleation (IN) gene to trigger the Bergeron-Findeisen process of raindrop formation as a mechanism for dispersal. In this study the IN gene was not detected in any of the isolates using both polymerase chain reaction (PCR) and differential scanning calorimetry (DSC). Instead 55% of the total isolates from both cloud and rain samples displayed significant biosurfactant activity when analyzed using the drop-collapse technique. All isolates were characterised as fluorescent pseudomonads. Surfactants have been found to be very important in lowering atmospheric critical supersaturations required for the activation of aerosols into cloud condensation nuclei (CCN). It is also known that surfactants influence cloud droplet size and increase cloud lifetime and albedo. Some bacteria are known to act as CCN and so it is conceivable that these fluorescent pseudomonads are using surfactants to facilitate their activation from aerosols into CCN. This would allow water scavenging,~countering desiccation, and assist in their widespread dispersal.

Ice-nucleation negative fluorescent pseudomonads isolated from Hebridean cloud and rain water produce biosurfactants

NASA Astrophysics Data System (ADS)

Ahern, H. E.; Walsh, K. A.; Hill, T. C. J.; Moffett, B. F.

2006-10-01

Microorganisms were discovered in clouds over 100 years ago but information on bacterial community structure and function is limited. Clouds may not only be a niche within which bacteria could thrive but they might also influence dynamic processes using ice nucleating and cloud condensing abilities. Cloud and rain samples were collected from two mountains in the Outer Hebrides, NW Scotland, UK. Community composition was determined using a combination of amplified 16S ribosomal DNA restriction analysis and sequencing. 256 clones yielded 100 operational taxonomic units (OTUs) of which half were related to bacteria from terrestrial psychrophilic environments. Cloud samples were dominated by a mixture of fluorescent Pseudomonas spp., some of which have been reported to be ice nucleators. It was therefore possible that these bacteria were using the ice nucleation (IN) gene to trigger the Bergeron-Findeisen process of raindrop formation as a mechanism for dispersal. In this study the IN gene was not detected in any of the isolates using both polymerase chain reaction (PCR) and differential scanning calorimetry (DSC). Instead 55% of the total isolates from both cloud and rain samples displayed significant biosurfactant activity when analyzed using the drop-collapse technique. All were characterised as fluorescent pseudomonads. Surfactants have been found to be very important in lowering atmospheric critical supersaturations required for the activation of aerosols into cloud condensation nuclei (CCN). It is also known that surfactants influence cloud droplet size and increase cloud lifetime and albedo. Some bacteria are known to act as CCN and so it is conceivable that these fluorescent pseudomonads are using surfactants to facilitate their activation from aerosols into CCN. This would allow water scavenging, countering desiccation, and assist in their widespread dispersal.

Cloud Condensation Nuclei in Cumulus Humilis - Selected Case Study During the CHAPS Campaign

NASA Astrophysics Data System (ADS)

Yu, X.; Berg, L. K.; Berkowitz, C. M.; Alexander, M. L.; Lee, Y.; Laskin, A.; Ogren, J. A.; Andrews, B.

2009-12-01

The Cumulus Humilis Aerosol Processing Study (CHAPS) provided a unique opportunity to study aerosol and cloud processing. Clouds play an active role in the processing and cycling of atmospheric constituents. Gases and particles can partition to cloud droplets by absorption and condensation as well as activation and pact scavenging. The Department of Energy (DOE) G-1 aircraft was used as one of the main platforms in CHAPS. Flight tracks were designed and implemented to characterize freshly emitted aerosols on cloud top and cloud base as well as with cloud, i.e., cumulus humilis (or fair-weather cumulus), in the vicinity of Oklahoma City. Measurements of interstitial aerosols and residuals of activated condensation cloud nuclei were conducted simultaneously. The interstitial aerosols were determined downstream of an isokinetic inlet; and the activated particles downstream of a counter-flow virtual impactor (CVI). The sampling line to the Aerodyne Aerosol Mass Spectrometer was switched between the isokinetic inlet and the CVI to allow characterization of interstitial particles out of clouds in contrast to particles activated in clouds. Trace gases including ozone, carbon monoxide, sulfur dioxide, and a series of volatile organic compounds (VOCs) were also measured as were key meteorological state parameters including liquid water content, cloud drop size, and dew point temperature were measured. This work will focus on studying CCN properties in cumulus humilis. Several approaches will be taken. The first is single particle analysis of particles collected by the Time-Resolved Aerosol Sampler (TRAC) by SEM/TEM coupled with EDX. We will specifically look into differences in particle properties such as chemical composition and morphology between activated and interstitial ones. The second analysis will link in situ measurements with the snap shots observations by TRAC. For instance, by looking into the characteristic m/z obtained by AMS vs. CO or isoprene, one can gain more insight into the role of primary and secondary organic aerosols in CCNs and background aerosols. Combined with observations of cloud properties, an improved picture of CCN activation in cumulus humilis can be made.

Precipitation effects on aerosol concentration in the background EMEP station of Zarra (Valencia), Spain

NASA Astrophysics Data System (ADS)

Calvo, Ana Isabel; San Martín, Isabel; Castro, Amaya; Alonso-Blanco, Elisabeth; Alves, Célia; Duarte, Márcio; Fernández-González, Sergio; Fraile, Roberto

2014-05-01

Aerosols and precipitation are closely related, presenting a bidirectional influence and constituting an important source of uncertainties on climate change studies. However, they are usually studied independently and in general are only linked to one another for the development or validation of cloud models. The primary and secondary pollutants may be removed by wet and dry deposition. Wet deposition, including in-cloud and below-cloud scavenging processes, can efficiently remove atmospheric aerosols and it is considered a critical process for determining aerosol concentrations in the atmosphere. In this study, aerosols and precipitation data from a background Spanish EMEP (Cooperative Programme for the Monitoring and Evaluation of Long Range Transmission of Air Pollutants in Europe) station located in Zarra, Valencia (Spain) were analyzed (1° 06' W and 39° 05' N, 885 m asl). The effect of precipitation on aerosol concentration was studied and the correlation between the intensity of precipitation and scavenging effect was investigated. In order to evaluate the effects of precipitation on different aerosol size ranges three different aerosol fractions were studied: PM10, PM10-2.5 and PM2.5. In order to eliminate the influence of the air mass changes, only the days in which the air mass of the precipitation day and the previous day had the same origin were considered. Thus, from a total of 3586 rainy days registered from March 2001 to December 2010, 34 precipitation days satisfied this condition and were analyzed. During the period of study, daily precipitation ranged between 0.2 and 28.8 mm, with a mean value of 4 mm. Regarding the origin of the air masses, those from west were dominant at the three height levels investigated (500, 1500 and 3000 m). In order to obtain additional information, aerosol and precipitation chemical composition were also studied in relation to the days of precipitation and the previous days. Furthermore, in order to identify the type of weather associated with each particular synoptic situation, a Circulation Weather Type (CWT) classification was applied. Acknowledgment: This work has been funded by the Spanish Ministry of Science and Innovation (Grant TEC2010-19241-C02-01). S. Fernández-González acknowledges the grant from the "Programa de Formación de Profesorado Universitario (FPU)" awarded by the Spanish Ministry of Education.

Further evidence for particle nucleation in clear air adjacent to marine cumulus clouds

NASA Astrophysics Data System (ADS)

Perry, Kevin D.; Hobbs, Peter V.

1994-11-01

Observational evidence is presented for the nucleation of condensation nuclei (CN) in the clear air adjacent to an isolated, marine, cumulus cloud. Two separate regions of particle nucleation are identified: one located above the cloud top, and the second located downwind of the cloud near the level of the anvil outflow. The regions of high CN concentrations were located in extremely clean marine air, with unactivated aerosol surface area (excluding the nucleation mode) less than 2 sq micrometers/cu cm, air temperature -31 C, and higher relative humidities than the undisturbed environment. Vertical profile measurements downwind of the cloud showed that CN concentrations at the level of the anvil outflow (4.9 km) were 8 times greater than at any other level between the surface and 5.3 km. A conceptual model is formulated in which aerosol particles, sulfur dioxide (SO2), sulfuric acid vapor (H2SO4), dimethyl sulfide (DMS), and ozone (O3) from the boundary layer are entrained into the cumulus cloud. Total aerosol number concentrations and unactivated aerosol surface area decrease with height in the cloud due to Brownian diffusion and diffusiophoresis of cloud interstitial aerosol to hydrometeors, coalescence scavenging by cloud droplets, collisional scavenging by ice particles, and subsequent removal by precipitation. The air that is detrained from the cloud raises the relative humidity and vents the clean air, SO2, H2SO4, DMS, and O3 to the near-cloud environment. Hydroxyl radicals then oxidize the SO2 and DMS to H2SO4. Under the conditions of high relative humidity, low total aerosol surface area, low temperatures, and high SO2 concentrations near cloud top, significant concentrations of new particles can be produced by homogeneous-bimolecular nucleation of sulfuric acid solution droplets from H2SO4 and H2O vapor molecules. The concentration of CN as a function of time is calculated for the case described in this paper using a bimodal integral nucleation model. The model results show that significant numbers of CN could have been produced within a few hours by the homogeneous-bimolecular nucleation of sulfuric acid solution droplets under the observed conditions provided the concentration of SO2 near cloud top was enhanced by vertical transport.

Time dependent charging of layer clouds in the global electric circuit

NASA Astrophysics Data System (ADS)

Zhou, Limin; Tinsley, Brian A.

2012-09-01

There is much observational data consistent with the hypothesis that the ionosphere-earth current density (Jz) in the global electric circuit, which is modulated by both solar activity and thunderstorm activity, affects atmospheric dynamics and cloud cover. One candidate mechanism involves Jz causing the accumulation of space charge on droplets and aerosol particles, that affects the rate of scavenging of the latter, notably those of Cloud Condensation Nuclei (CCN) and Ice Forming Nuclei (IFN) (Tinsley, 2008, 2010). Space charge is the difference, per unit volume, between total positive and total negative electrical charge that is on droplets, aerosol particles (including the CCN and IFN) and air ions. The cumulative effects of the scavenging in stratiform clouds and aerosol layers in an air mass over the lifetime of the aerosol particles of 1-10 days affects the concentration and size distribution of the CCN, so that in subsequent episodes of cloud formation (including deep convective clouds) there can be effects on droplet size distribution, coagulation, precipitation processes, and even storm dynamics.Because the time scales for charging for some clouds can be long compared to cloud lifetimes, the amount of charge at a given time, and its effect on scavenging, depend more on the charging rate than on the equilibrium charge that would eventually be attained. To evaluate this, a new time-dependent charging model has been developed. The results show that for typical altostratus clouds with typical droplet radii 10 μm and aerosol particles of radius of 0.04 μm, the time constant for charging in response to a change in Jz is about 800 s, which is comparable to cloud formation and dissipation timescales for some cloud situations. The charging timescale is found to be strong functions of altitude and aerosol concentration, with the time constant for droplet charging at 2 km in air with a high concentration of aerosols being about an hour, and for clouds at 10 km in clean air being about a minute. The charging timescale is also a strong function of droplet size, with the rate for 15 μm radii droplets being about 70% longer than that for 10 μm droplets, and the rate for 5 μm radii droplets being about 50% smaller. The equilibrium charges accumulated on droplets ranged from tens to hundreds of elementary charges, which is comparable to observed values, and to vary approximately directly with Jz and inversely with the ion production rate q, which is due to the Galactic Cosmic Ray (GCR) flux and depends strongly on altitude.For the case of Jz varying directly with q, which to some extent is the case during Forbush decreases of the GCR flux, the effects on the equilibrium charge tend to cancel. In one run with the model, both q and Jz were decreased by 30%. There was little change in equilibrium charge, but the timescale for charging increased by about 40%, or equivalently, the rate of charging decreased by about 40%. Thus, for exploring the hypothesis that space charge provides a link between GCR (and other inputs that modulate Jz) and changes in clouds and atmospheric dynamics, it is necessary to consider variations in the rate of charging. The present work is intended to provide illustrative examples of time dependent charging for several different types of layer clouds.

Simultaneous and synergistic profiling of cloud and drizzle properties using ground-based observations

NASA Astrophysics Data System (ADS)

Rusli, Stephanie P.; Donovan, David P.; Russchenberg, Herman W. J.

2017-12-01

Despite the importance of radar reflectivity (Z) measurements in the retrieval of liquid water cloud properties, it remains nontrivial to interpret Z due to the possible presence of drizzle droplets within the clouds. So far, there has been no published work that utilizes Z to identify the presence of drizzle above the cloud base in an optimized and a physically consistent manner. In this work, we develop a retrieval technique that exploits the synergy of different remote sensing systems to carry out this task and to subsequently profile the microphysical properties of the cloud and drizzle in a unified framework. This is accomplished by using ground-based measurements of Z, lidar attenuated backscatter below as well as above the cloud base, and microwave brightness temperatures. Fast physical forward models coupled to cloud and drizzle structure parameterization are used in an optimal-estimation-type framework in order to retrieve the best estimate for the cloud and drizzle property profiles. The cloud retrieval is first evaluated using synthetic signals generated from large-eddy simulation (LES) output to verify the forward models used in the retrieval procedure and the vertical parameterization of the liquid water content (LWC). From this exercise it is found that, on average, the cloud properties can be retrieved within 5 % of the mean truth. The full cloud-drizzle retrieval method is then applied to a selected ACCEPT (Analysis of the Composition of Clouds with Extended Polarization Techniques) campaign dataset collected in Cabauw, the Netherlands. An assessment of the retrieval products is performed using three independent methods from the literature; each was specifically developed to retrieve only the cloud properties, the drizzle properties below the cloud base, or the drizzle fraction within the cloud. One-to-one comparisons, taking into account the uncertainties or limitations of each retrieval, show that our results are consistent with what is derived using the three independent methods.

The scavenging of volatile anesthetic agents in the cardiovascular intensive care unit environment: a technical report.

PubMed

Pickworth, Thomas; Jerath, Angela; DeVine, Rita; Kherani, Nazmin; Wąsowicz, Marcin

2013-01-01

The use of volatile-based sedation within critical care environments has been limited by difficulties of drug administration and safety concerns over environment pollution and staff exposure in an intensive care unit (ICU) with no scavenging. The aim of this study was to develop a simple scavenging system to be used with the Anesthesia Conserving Device (AnaConDa(®)) and to determine whether or not ambient concentrations of residual anesthetic are within current acceptable limits. The scavenging system consists of two Deltasorb(®) canisters attached to the ICU ventilator in series. AnaConDa is a miniature vaporizer designed to provide volatile-based sedation within an ICU. The first ten patients recruited into a larger randomized trial assessing outcomes after elective coronary graft bypass surgery were sedated within the cardiac ICU using either isoflurane or sevoflurane. Sedation was guided by the Sedation Agitation Scale, resulting in an end-tidal minimum anesthetic concentration of volatile agent ranging from 0.1-0.3. At one hour post ICU admission, infrared photometric analysis was used to assess environmental contamination at four points along the ventilator circuit and scavenging system and around the patient's head. All measurements taken within the patient's room were below 1 part per million, which satisfies criteria for occupational exposure. This study shows that volatile agents can be administered safely within critical care settings using a simple scavenging system. Our scavenging system used in conjunction with the AnaConDa device reduced the concentration of environmental contamination to a level that is acceptable to Canadian standards and standards in most Western countries and thus conforms to international safety standards. The related clinical trial was registered at www.clinicaltrials.gov (NCT01151254).

Impacts of WRF lightning assimilation on offline CMAQ simulations

EPA Science Inventory

Deep convective clouds vertically redistribute trace gases and aerosols and also provide a source for scavenging, aqueous phase chemistry, and wet deposition, making them important to air quality.? Regional air quality simulations are typically driven by meteorological models tha...

Red Cloud Reading Test: American Indian Form of the Test of Individual Needs in Reading, a Competency Based Test of Reading Skills [and] Instructor's Manual.

ERIC Educational Resources Information Center

Gilliland, Hap

The oral Red Cloud Reading Test provides a complete analysis of reading level and skills for American Indian students in grades 1-7 or for high school and adult students reading at or below high school levels. The test determines the basic and recreational reading levels, identifies reading problems, determines reading speeds, and analyzes the…

Photochemical ozone production in tropical squall line convection during NASA Global Tropospheric Experiment/Amazon Boundary Layer Experiment 2A

NASA Technical Reports Server (NTRS)

Pickering, Kenneth E.; Thompson, Anne M.; Tao, Wei-Kuo; Simpson, Joanne; Scala, John R.

1991-01-01

The role of convection was examined in trace gas transport and ozone production in a tropical dry season squall line sampled on August 3, 1985, during NASA Global Tropospheric Experiment/Amazon Boundary Layer Experiment 2A (NASA GTE/ABLE 2A) in Amazonia, Brazil. Two types of analyses were performed. Transient effects within the cloud are examined with a combination of two-dimensional cloud and one-dimensional photochemical modeling. Tracer analyses using the cloud model wind fields yield a series of cross sections of NO(x), CO, and O3 distribution during the lifetime of the cloud; these fields are used in the photochemical model to compute the net rate of O3 production. At noon, when the cloud was mature, the instantaneous ozone production potential in the cloud is between 50 and 60 percent less than in no-cloud conditions due to reduced photolysis and cloud scavenging of radicals. Analysis of cloud inflows and outflows is used to differentiate between air that is undisturbed and air that has been modified by the storm. These profiles are used in the photochemical model to examine the aftereffects of convective redistribution in the 24-hour period following the storm. Total tropospheric column O3 production changed little due to convection because so little NO(x) was available in the lower troposphere. However, the integrated O3 production potential in the 5- to 13-km layer changed from net destruction to net production as a result of the convection. The conditions of the August 3, 1985, event may be typical of the early part of the dry season in Amazonia, when only minimal amounts of pollution from biomass burning have been transported into the region.

CCN activity of secondary aerosols from terpene ozonolysis under atmospheric relevant conditions

NASA Astrophysics Data System (ADS)

Yuan, Cheng; Ma, Yan; Diao, Yiwei; Yao, Lei; Zhou, Yaoyao; Wang, Xing; Zheng, Jun

2017-04-01

Gas-phase ozonolysis of terpenes is an important source of atmospheric secondary organic aerosol. The contribution of terpene-derived aerosols to the atmospheric cloud condensation nucleus (CCN) burden under atmospheric conditions, however, remains highly uncertain. The results obtained in previous studies under simple laboratory conditions may not be applicable to atmospheric relevant conditions. Here we present that CCN activities of aerosols from terpene ozonolysis can be significantly affected by atmospheric relevant species that can act as stabilized Criegee intermediate (SCI) or OH scavengers. Ozonolysis reactions of α-pinene, limonene, α-cedrene, and α-humulene were conducted in a 4.5 m3 collapsible fluoropolymer chamber at near-atmospheric concentrations in the presence of different OH scavengers (cyclohexane, 2-butanol, or CO) and SCI scavengers (CH3COOH, H2O, or SO2). The number size distribution and CCN activity of aerosol particles formed during ozonolysis were simultaneously determined. Additionally, particulate products were chemically analyzed by using a Filter Inlet for Gases and AEROsols High-Resolution Time-of-Flight Chemical-Ionization Mass Spectrometer. Results showed that aerosol CCN activity following monoterpene ozonolysis was more sensitive to the choice of OH scavengers, while that from sesquiterpene ozonolysis was significantly affected by SCI scavengers. Combined with chemical analysis results, it was concluded that the unimolecular decomposition of CIs giving hygroscopic organic products can be largely suppressed by bimolecular reactions during sesquiterpene ozonolysis but was not significantly impacted in monoterpene ozonolysis. Our study underscores the key role of CIs in the CCN activity of terpene ozonolysis-derived aerosols. The effects of atmospheric relevant species (e.g., SO2, H2O, and CO) need to be considered when assessing the contribution of biogenic terpenes to the atmospheric CCN burden under ambient conditions.

Validation of GOME-2/MetOp-A total water vapour column using reference radiosonde data from the GRUAN network

NASA Astrophysics Data System (ADS)

Antón, M.; Loyola, D.; Román, R.; Vömel, H.

2015-03-01

The main goal of this paper is to validate the total water vapour column (TWVC) measured by the Global Ozone Monitoring Experiment-2 (GOME-2) satellite sensor and generated using the GOME Data Processor (GDP) retrieval algorithm developed by the German Aerospace Centre (DLR). For this purpose, spatially and temporally collocated TWVC data from highly accurate sounding measurements for the period January 2009-May 2014 at six sites are used. These balloon-borne data are provided by the GCOS Reference Upper-Air Network (GRUAN). The correlation between GOME-2 and sounding TWVC data is reasonably good (determination coefficient, R2, of 0.89) when all available radiosondes (1400) are employed in the inter-comparison. When cloud-free cases (544) are selected by means of the satellite cloud fraction (CF < 5%), the correlation exhibits a remarkable improvement (R2 ~ 0.95). Nevertheless, the analysis of the relative differences between GOME-2 and GRUAN data shows a mean absolute bias error (weighted with the combined uncertainty derived from the estimated errors of both data sets) of 15% for all-sky conditions (9% for cloud-free cases). These results evidence a notable bias in the satellite TWVC data against the reference balloon-borne measurements, partially related to the cloudy conditions during the satellite overpass. The detailed analysis of the influence of cloud properties - CF, cloud top albedo (CTA) and cloud top pressure (CTP) - on the satellite-sounding differences reveals, as expected, a large effect of clouds in the GOME-2 TWVC data. For instance, the relative differences exhibit a large negative dependence on CTA, varying from -6 to -23% when CTA rises from 0.3 to 0.8. Furthermore, the satellite-sounding TWVC differences show a strong dependence on the satellite solar zenith angle (SZA) for values above 50°. Hence the smallest relative differences found in this satellite-sounding comparison are achieved for those cloud-free cases with satellite SZA below 50°. Finally, the relative differences also show a negative dependence on the reference TWVC values, e.g. changing from +10% (TWVC below 10 mm) to -10% (TWVC above 40 mm) when cloud-free conditions with SZA below 50° are selected. Overall, relative differences within ±10% with respect to reference sounding data for a large range of TWVC values can be considered as a good result for satellite retrievals.

Featured Image: A Molecular Cloud Outside Our Galaxy

NASA Astrophysics Data System (ADS)

Kohler, Susanna

2018-06-01

What do molecular clouds look like outside of our own galaxy? See for yourself in the images above and below of N55, a molecular cloud located in the Large Magellanic Cloud (LMC). In a recent study led by Naslim Neelamkodan (Academia Sinica Institute of Astronomy and Astrophysics, Taiwan), a team of scientists explore N55 to determine how its cloud properties differ from clouds within the Milky Way. The image above reveals the distribution of infrared-emitting gas and dust observed in three bands by the Spitzer Space Telescope. Overplotted in cyan are observations from the Atacama Submillimeter Telescope Experiment tracing the clumpy, warm molecular gas. Below, new observations from the Atacama Large Millimeter/submillimeter Array (ALMA) reveal the sub-parsec-scale molecular clumps in greater detail, showing the correlation of massive clumps with Spitzer-identified young stellar objects (crosses). The study presented here indicates that this cloud in the LMC is the site of massive star formation, with properties similar to equivalent clouds in the Milky Way. To learn more about the authors findings, check out the article linked below.CitationNaslim N. et al 2018 ApJ 853 175. doi:10.3847/1538-4357/aaa5b0

A Study of Rapidly Developing Low Cloud Ceilings in a Stable Atmosphere at the Florida Spaceport

NASA Technical Reports Server (NTRS)

Wheeler, Mark M.; Case, Jonathan L.; Baggett, G. Wayne

2006-01-01

Forecasters at the Space Meteorology Group (SMG) issue 30 to 90 minute forecasts for low cloud ceilings at the Shuttle Landing Facility (KTTS) in Kennedy Space Center, FL for all Space Shuttle missions. Mission verification statistics have shown cloud ceilings to be the biggest forecast challenge. SMG forecasters are especially concerned with rapidly developing cloud ceilings below 8000 ft. in a stable, capped thermodynamic environment because ceilings below 8000 ft restrict Shuttle landing operations and are the most challenging to predict accurately. This project involves the development of a database of these cases over east-central Florida in order to identify the onset, location, and if possible, dissipation times of rapidly-developing low cloud ceilings. Another goal is to document the atmospheric regimes favoring this type of cloud development to improve forecast skill of such events during Space Shuttle launch and landing operations. A 10-year database of stable, rapid low cloud development days during the daylight hours was compiled for the Florida cool-season months by examining the Cape Canaveral Air Force Station sounding data, and identifying days that had high boundary layer relative humidity associated with a thermally-capped environment below 8000 ft. Archived hourly surface observations from KTTS and Melbourne, Orlando, Sanford, and Ocala, FL were then examined for the onset of cloud ceilings below 8000 ft between 1100 and 2000 UTC. Once the database was supplemented with the hourly surface cloud observations, visible satellite imagery was examined in 30-minute intervals to confirm event occurrences. This paper will present results from some of the rapidly developing cloud ceiling cases and the prevailing meteorological conditions associated with these events, focusing on potential pre-curser information that may help improve their prediction.

Snow precipitation on Mars driven by cloud-induced night-time convection

NASA Astrophysics Data System (ADS)

Spiga, Aymeric; Hinson, David P.; Madeleine, Jean-Baptiste; Navarro, Thomas; Millour, Ehouarn; Forget, François; Montmessin, Franck

2017-09-01

Although it contains less water vapour than Earth's atmosphere, the Martian atmosphere hosts clouds. These clouds, composed of water-ice particles, influence the global transport of water vapour and the seasonal variations of ice deposits. However, the influence of water-ice clouds on local weather is unclear: it is thought that Martian clouds are devoid of moist convective motions, and snow precipitation occurs only by the slow sedimentation of individual particles. Here we present numerical simulations of the meteorology in Martian cloudy regions that demonstrate that localized convective snowstorms can occur on Mars. We show that such snowstorms--or ice microbursts--can explain deep night-time mixing layers detected from orbit and precipitation signatures detected below water-ice clouds by the Phoenix lander. In our simulations, convective snowstorms occur only during the Martian night, and result from atmospheric instability due to radiative cooling of water-ice cloud particles. This triggers strong convective plumes within and below clouds, with fast snow precipitation resulting from the vigorous descending currents. Night-time convection in Martian water-ice clouds and the associated snow precipitation lead to transport of water both above and below the mixing layers, and thus would affect Mars' water cycle past and present, especially under the high-obliquity conditions associated with a more intense water cycle.

Detecting long-duration cloud contamination in hyper-temporal NDVI imagery

NASA Astrophysics Data System (ADS)

Ali, Amjad; de Bie, C. A. J. M.; Skidmore, A. K.

2013-10-01

Cloud contamination impacts on the quality of hyper-temporal NDVI imagery and its subsequent interpretation. Short-duration cloud impacts are easily removed by using quality flags and an upper envelope filter, but long-duration cloud contamination of NDVI imagery remains. In this paper, an approach that goes beyond the use of quality flags and upper envelope filtering is tested to detect when and where long-duration clouds are responsible for unreliable NDVI readings, so that a user can flag those data as missing. The study is based on MODIS Terra and the combined Terra-Aqua 16-day NDVI product for the south of Ghana, where persistent cloud cover occurs throughout the year. The combined product could be assumed to have less cloud contamination, since it is based on two images per day. Short-duration cloud effects were removed from the two products through using the adaptive Savitzky-Golay filter. Then for each 'cleaned' product an unsupervised classified map was prepared using the ISODATA algorithm, and, by class, plots were prepared to depict changes over time of the means and the standard deviations in NDVI values. By comparing plots of similar classes, long-duration cloud contamination appeared to display a decline in mean NDVI below the lower limit 95% confidence interval with a coinciding increase in standard deviation above the upper limit 95% confidence interval. Regression analysis was carried out per NDVI class in two randomly selected groups in order to statistically test standard deviation values related to long-duration cloud contamination. A decline in seasonal NDVI values (growing season) were below the lower limit of 95% confidence interval as well as a concurrent increase in standard deviation values above the upper limit of the 95% confidence interval were noted in 34 NDVI classes. The regression analysis results showed that differences in NDVI class values between the Terra and the Terra-Aqua imagery were significantly correlated (p < 0.05) with the corresponding standard deviation values of the Terra imagery in case of all NDVI classes of two selected NDVI groups. The method successfully detects long-duration cloud contamination that results in unreliable NDVI values. The approach offers scientists interested in time series analysis a method of masking by area (class) the periods when pre-cleaned NDVI values remain affected by clouds. The approach requires no additional data for execution purposes but involves unsupervised classification of the imagery to carry out the evaluation of class-specific mean NDVI and standard deviation values over time.

Nitric acid in polar stratospheric clouds - Similar temperature of nitric acid condensation and cloud formation

NASA Technical Reports Server (NTRS)

Pueschel, Rudolf F.; Snetsinger, Kenneth G.; Hamill, Patrick; Goodman, Jindra K.; Mccormick, M. Patrick

1990-01-01

As shown independently by two different techniques, nitric acid aerosols and polar stratospheric clouds (PSCs) both form below similar threshold temperatures. This supports the idea that the PSC particles involved in chlorine activation and ozone depletion in the winter polar stratosphere are composed of nitric acid. One technique used to show this is the inertial impaction of nitric acid aerosols using an Er-2 aircraft; the other method is remote sensing of PSCs by the Stratospheric Aerosol Measurement (SAM II) satellite borne optical sensor. Both procedures were in operation during the Arctic Airborne Stratospheric Expedition in 1989, and the Airborne Antarctic Ozone Experiment in 1987. Analysis of Arctic particles gathered in situ indicates the presence of nitric acid below a 'first appearance' temperature Tfa = 202 K. This is the same highest temperature at which PSCs are seen by the SAM II satellite. In comparison, a 'first appearance' temperature Tfa = 198 K as found for the Antarctic samples.

Examining the Impact of Overlying Aerosols on the Retrieval of Cloud Optical Properties from Passive Remote Sensing

NASA Technical Reports Server (NTRS)

Coddington, O. M.; Pilewskie, P.; Redemann, J.; Platnick, S.; Russell, P. B.; Schmidt, K. S.; Gore, W. J.; Livingston, J.; Wind, G.; Vukicevic, T.

2010-01-01

Haywood et al. (2004) show that an aerosol layer above a cloud can cause a bias in the retrieved cloud optical thickness and effective radius. Monitoring for this potential bias is difficult because space ]based passive remote sensing cannot unambiguously detect or characterize aerosol above cloud. We show that cloud retrievals from aircraft measurements above cloud and below an overlying aerosol layer are a means to test this bias. The data were collected during the Intercontinental Chemical Transport Experiment (INTEX-A) study based out of Portsmouth, New Hampshire, United States, above extensive, marine stratus cloud banks affected by industrial outflow. Solar Spectral Flux Radiometer (SSFR) irradiance measurements taken along a lower level flight leg above cloud and below aerosol were unaffected by the overlying aerosol. Along upper level flight legs, the irradiance reflected from cloud top was transmitted through an aerosol layer. We compare SSFR cloud retrievals from below ]aerosol legs to satellite retrievals from the Moderate Resolution Imaging Spectroradiometer (MODIS) in order to detect an aerosol ]induced bias. In regions of small variation in cloud properties, we find that SSFR and MODIS-retrieved cloud optical thickness compares within the uncertainty range for each instrument while SSFR effective radius tend to be smaller than MODIS values (by 1-2 microns) and at the low end of MODIS uncertainty estimates. In regions of large variation in cloud properties, differences in SSFR and MODIS ]retrieved cloud optical thickness and effective radius can reach values of 10 and 10 microns, respectively. We include aerosols in forward modeling to test the sensitivity of SSFR cloud retrievals to overlying aerosol layers. We find an overlying absorbing aerosol layer biases SSFR cloud retrievals to smaller effective radii and optical thickness while nonabsorbing aerosols had no impact.

Effect of Wegener-Bergeron-Findeisen Process to Black Carbon Simulation

NASA Astrophysics Data System (ADS)

Qi, Ling; Li, Qinbin; He, Cenlin; Wang, Xin; Huang, Jianping

2016-04-01

We systematically investigated the effect of Wegener-Bergeron-Findeisen (WBF) process to black carbon (BC) simulation by a global 3D chemical transport model GEOS-Chem constrained by measurements of BC scavenging efficiencies, concentration in air, deposition fluxes, concentration in snow and washout ratios. Including effect of WBF process reduces the annual mean BC scavenging efficiencies (the ratio of BC in cloud droplets to total BC) at all altitudes by 43-76% in the Arctic. For mid latitude BC scavenging efficiencies decrease by 8-22%, 23-39%, and 41-50% in lower (0-2 km), middle (2-5 km) and upper troposphere (5-10 km), respectively. Simulated BC in air in the Arctic and at mid altitude (˜4 km) in mid latitude increases by ˜40%, and the discrepancy reduces from -65% to -30%. Simulated median BC in snow decreases from 25.7 to 22.4 ng g-1, by 15% in mid latitude and increases from 8.7 to 11.0 ng g-1, by 26% in the Arctic and the comparison with observations improves. The model overestimates washout ratios (ratio of BC in fresh snow/rain to BC in surface air) at most of the sites by up to a factor of 165. With effect of WBF process included, the discrepancy decreases to a factor of 72. The simulated BC burden increases from 0.22 to 0.35 mg m-2 yr-1 when effect of WBF process is included, partly explains the scaled up of BC burden in Bond et al., 2013. Moreover, burden above 5 km increases from 22% to 27% when WBF process is included, indicating a higher forcing efficiency. We also found that BC simulation is insensitive to the temperature criteria between mixed phase clouds and ice clouds. The simulated BC burden is the same when the temperature is set as -15° C and -25° C. This study also suggests that more observations are needed to better distinguish riming dominated and WBF dominated conditions and better parameterize BC scavenging efficiency under the two conditions.

Atmospheric scavenging exhaust

NASA Technical Reports Server (NTRS)

Fenton, D. L.; Purcell, R. Y.

1977-01-01

Solid propellant rocket exhaust was directly utilized to ascertain raindrop scavenging rates for hydrogen chloride. The airborne HCl concentration varied from 0.2 to 10.0 ppm and the raindrop sizes tested included 0.55 mm, 1.1 mm, and 3.0 mm. Two chambers were used to conduct the experiments. A large, rigid walled, spherical chamber stored the exhaust constituents while the smaller chamber housing all the experiments was charged as required with rocket exhaust HCl. Surface uptake experiments demonstrated an HCl concentration dependence for distilled water. Sea water and brackish water HCl uptake was below the detection limit of the chlorine-ion analysis technique employed. Plant life HCl uptake experiments were limited to corn and soybeans. Plant age effectively correlated the HCl uptake data. Metallic corrosion was not significant for single 20 minute exposures to the exhaust HCl under varying relative humidity.

Atmospheric scavenging of solid rocket exhaust effluents

NASA Technical Reports Server (NTRS)

Fenton, D. L.; Purcell, R. Y.

1978-01-01

Solid propellant rocket exhaust was directly utilized to ascertain raindrop scavenging rates for hydrogen chloride. Two chambers were used to conduct the experiments; a large, rigid walled, spherical chamber stored the exhaust constituents, while the smaller chamber housing all the experiments was charged as required with rocket exhaust HCl. Surface uptake experiments demonstrated an HCl concentration dependence for distilled water. Sea water and brackish water HCl uptake was below the detection limit of the chlorine-ion analysis technique used. Plant life HCl uptake experiments were limited to corn and soybeans. Plant age effectively correlated the HCl uptake data. Metallic corrosion was not significant for single 20 minute exposures to the exhaust HCl under varying relative humidity. Characterization of the aluminum oxide particles substantiated the similarity between the constituents of the small scale rocket and the full size vehicles.

Tropical High Cloud Fraction Controlled by Cloud Lifetime Rather Than Clear-sky Convergence

NASA Astrophysics Data System (ADS)

Seeley, J.; Jeevanjee, N.; Romps, D. M.

2016-12-01

Observations and simulations show a peak in cloud fraction below the tropopause. This peak is usually attributed to a roughly co-located peak in radiatively-driven clear-sky convergence, which is presumed to force convective detrainment and thus promote large cloud fraction. Using simulations of radiative-convective equilibrium forced by various radiative cooling profiles, we refute this mechanism by showing that an upper-tropospheric peak in cloud fraction persists even in simulations with no peak in clear-sky convergence. Instead, cloud fraction profiles seem to be controlled by cloud lifetimes — i.e., how long it takes for clouds to dissipate after they have detrained. A simple model of cloud evaporation shows that the small saturation deficit in the upper troposphere greatly extends cloud lifetimes there, while the large saturation deficit in the lower troposphere causes condensate to evaporate quickly. Since cloud mass flux must go to zero at the tropopause, a peak in cloud fraction emerges at a "sweet spot" below the tropopause where cloud lifetimes are long and there is still sufficient mass flux to be detrained.

Wavelet Scale Analysis of Mesoscale Convective Systems for Detecting Deep Convection From Infrared Imagery

NASA Astrophysics Data System (ADS)

Klein, Cornelia; Belušić, Danijel; Taylor, Christopher M.

2018-03-01

Mesoscale convective systems (MCSs) are frequently associated with rainfall extremes and are expected to further intensify under global warming. However, despite the significant impact of such extreme events, the dominant processes favoring their occurrence are still under debate. Meteosat geostationary satellites provide unique long-term subhourly records of cloud top temperatures, allowing to track changes in MCS structures that could be linked to rainfall intensification. Focusing on West Africa, we show that Meteosat cloud top temperatures are a useful proxy for rainfall intensities, as derived from snapshots from the Tropical Rainfall Measuring Mission 2A25 product: MCSs larger than 15,000 km2 at a temperature threshold of -40°C are found to produce 91% of all extreme rainfall occurrences in the study region, with 80% of the storms producing extreme rain when their minimum temperature drops below -80°C. Furthermore, we present a new method based on 2-D continuous wavelet transform to explore the relationship between cloud top temperature and rainfall intensity for subcloud features at different length scales. The method shows great potential for separating convective and stratiform cloud parts when combining information on temperature and scale, improving the common approach of using a temperature threshold only. We find that below -80°C, every fifth pixel is associated with deep convection. This frequency is doubled when looking at subcloud features smaller than 35 km. Scale analysis of subcloud features can thus help to better exploit cloud top temperature data sets, which provide much more spatiotemporal detail of MCS characteristics than available rainfall data sets alone.

Kinetics of laser irradiated nanoparticles cloud

NASA Astrophysics Data System (ADS)

Mishra, S. K.; Upadhyay Kahaly, M.; Misra, Shikha

2018-02-01

A comprehensive kinetic model describing the complex kinetics of a laser irradiated nanoparticle ensemble has been developed. The absorbed laser radiation here serves dual purpose, viz., photoenhanced thermionic emission via rise in its temperature and direct photoemission of electrons. On the basis of mean charge theory along with the equations for particle (electron) and energy flux balance over the nanoparticles, the transient processes of charge/temperature evolution over its surface and mass diminution on account of the sublimation (phase change) process have been elucidated. Using this formulation phenomenon of nanoparticle charging, its temperature rise to the sublimation point, mass ablation, and cloud disintegration have been investigated; afterwards, typical timescales of disintegration, sublimation and complete evaporation in reference to a graphite nanoparticle cloud (as an illustrative case) have been parametrically investigated. Based on a numerical analysis, an adequate parameter space describing the nanoparticle operation below the sublimation temperature, in terms of laser intensity, wavelength and nanoparticle material work function, has been identified. The cloud disintegration is found to be sensitive to the nanoparticle charging through photoemission; as a consequence, it illustrates that radiation operating below the photoemission threshold causes disintegration in the phase change state, while above the threshold, it occurs with the onset of surface heating.

CloudSat Image of a Polar Night Storm Near Antarctica

NASA Technical Reports Server (NTRS)

2006-01-01

[figure removed for brevity, see original site] Figure 1

CloudSat image of a horizontal cross-section of a polar night storm near Antarctica. Until now, clouds have been hard to observe in polar regions using remote sensing, particularly during the polar winter or night season. The red colors are indicative of highly reflective particles such as water (rain) or ice crystals, while the blue indicates thinner clouds (such as cirrus). The flat green/blue lines across the bottom represent the ground signal. The vertical scale on the CloudSat Cloud Profiling Radar image is approximately 30 kilometers (19 miles). The blue line below the Cloud Profiling Radar image indicates that the data were taken over water; the brown line below the image indicates the relative elevation of the land surface. The inset image shows the CloudSat track relative to a Moderate Resolution Imaging Spectroradiometer (MODIS) infrared image taken at nearly the same time.

Depth zonation and bathymetric trends of deep-sea megafaunal scavengers of the Hawaiian Islands

NASA Astrophysics Data System (ADS)

Yeh, John; Drazen, Jeffrey C.

2009-02-01

The deep sea has been shown to exhibit strong depth zonation in species composition and abundance. Examination of these patterns can offer ecological insight into how organisms adapt and respond to changing environmental parameters that co-occur with depth. Here we provide the first tropical study on bathymetric zonation and other depth-related trends (size, abundance, and species richness) spanning shelf to abyssal depths of scavenging megafauna. Baited time-lapse free-vehicle cameras were used to examine the deep-sea benthic and demersal scavenging communities of the Hawaiian Islands, an area for which the biology and ecology have remained poorly studied below 2000 m. Twenty-two deployments ranging in depth from 250 to 4783 m yielded 37 taxa attracted to bait, including the first known occurrence of the family Zoarcidae in the Hawaiian Islands. Cluster analysis of Bray-Curtis similarity of species peak abundance ( nmax) revealed four main faunal zones (250-500, 1000, 1500-3000, and ⩾4000 m) with significant separation (ANOSIM, global R=0.907, p=0.001) between designated depth groups. A major faunal break was identified at the 500-1000 m transition where species turnover was greatest, coinciding with the location of the local oxygen minimum zone. Dominance in species assemblage shifted from decapod crustaceans to teleosts moving from shallow to deeper faunal zones. Significant size differences in total length with depth were found for two of the four fish species examined. A logarithmic decline was observed in scavenger relative abundance with depth. Evidence of interaction between scavenging species was also noted between Synaphobranchus affinis and Neolithodes sp. (competition) and Histiobranchus sp. and aristeid shrimp (predation), suggesting that interactions between scavengers could influence indices of abundance generated from baited camera data.

Roles of drizzle in a one-dimensional third-order turbulence closure model of the nocturnal stratus-topped marine boundary layer

NASA Technical Reports Server (NTRS)

Wang, Shouping; Wang, Qing

1994-01-01

This study focuses on the effects of drizzle in a one-dimensional third-order turbulence closure model of the nocturnal stratus-topped marine boundary layer. When the simulated drizzle rate is relatively small (maximum approximately equal to 0.6 mm/day), steady-state solutions are obtained. The boundary layer stabilizes essentially because drizzle causes evaporative cooling of the subcloud layer. This stabilization considerably reduces the buoyancy flux and turbulence kinetic energy below the stratus cloud. Thus, drizzle tends to decouple the cloud from the subcloud layer in the model, as suggested by many observational studies. In addition, the evaporation of drizzle in the subcloud layer creates small scattered clouds, which are likely to represent cumulus clouds, below the solid stratus cloud in the model. The sensitivity experiments show that these scattered clouds help maintain a coupled boundary layer. When the drizzle rate is relatively large (maximum approximately equal to 0.9 mm/day), the response of the model becomes transient with bursts in turbulent fluxes. This phenomenon is related to the formation of the scattered cloud layer below the solid stratus cloud. It appears that the model is inadequate to represent the heat and moisture transport by strong updrafts covering a small fractional area in cumulus convection.

Ozone, dust, smoke and humidity in nuclear winter

NASA Technical Reports Server (NTRS)

Turco, R. P.; Toon, O. B.; Ackerman, T. P.; Pollack, J. B.; Sagan, C.

1985-01-01

Recent correspondence on nuclear winter is commented on. Reasons are given for why the Tunguska meteor explosion may not be useful in calibrating the effects of a major nuclear exchange. The relationship between the optical depth of an aerosol cloud, the composition of the cloud, and its effect on sunlight intensity and climate are clarified. The significance of the Tambora eruption of 1815 and of historical fires for the nuclear winter theory are briefly discussed. The dispersion of smoke plumes from large fires is addressed, and water condensation and smoke scavenging are considered.

The Global Influence of Cloud Optical Thickness on Terrestrial Carbon Uptake

NASA Astrophysics Data System (ADS)

Zhu, P.; Cheng, S. J.; Keppel-Aleks, G.; Butterfield, Z.; Steiner, A. L.

2016-12-01

Clouds play a critical role in regulating Earth's climate. One important way is by changing the type and intensity of solar radiation reaching the Earth's surface, which impacts plant photosynthesis. Specifically, the presence of clouds modifies photosynthesis rates by influencing the amount of diffuse radiation as well as the spectral distribution of solar radiation. Satellite-derived cloud optical thickness (COT) may provide the observational constraint necessary to assess the role of clouds on ecosystems and terrestrial carbon uptake across the globe. Previous studies using ground-based observations at individual sites suggest that below a COT of 7, there is a greater increase in light use efficiency than at higher COT values, providing evidence for higher carbon uptake rates than expected given the reduction in radiation by clouds. However, the strength of the COT-terrestrial carbon uptake correlation across the globe remains unknown. In this study, we investigate the influence of COT on terrestrial carbon uptake on a global scale, which may provide insights into cloud conditions favorable for plant photosynthesis and improve our estimates of the land carbon sink. Global satellite-derived MODIS data show that tropical and subtropical regions tend to have COT values around or below the threshold during growing seasons. We find weak correlations between COT and GPP with Fluxnet MTE global GPP data, which may be due to the uncertainty of upscaling GPP from individual site measurements. Analysis with solar-induced fluorescence (SIF) as a proxy for GPP is also evaluated. Overall, this work constructs a global picture of the role of COT on terrestrial carbon uptake, including its temporal and spatial variations.

Cloud microphysical relationships and their implication on entrainment and mixing mechanism for the stratocumulus clouds measured during the VOCALS project

DOE PAGES

Yum, Seong Soo; Wang, Jian; Liu, Yangang; ...

2015-05-27

Cloud microphysical data obtained from G-1 aircraft flights over the southeastern pacific during the VOCALS-Rex field campaign were analyzed for evidence of entrainment mixing of dry air from above cloud top. Mixing diagram analysis was made for the horizontal flight data recorded at 1 Hz and 40 Hz. The dominant observed feature, a positive relationship between cloud droplet mean volume (V) and liquid water content (L), suggested occurrence of homogeneous mixing. On the other hand, estimation of the relevant scale parameters (i.e., transition length scale and transition scale number) consistently indicated inhomogeneous mixing. Importantly, the flight altitudes of the measurementsmore » were significantly below cloud top. We speculate that mixing of the entrained air near the cloud top may have indeed been inhomogeneous; but due to vertical circulation mixing, the correlation between V and L became positive at the measurement altitudes in mid-level of clouds, because during their descent, cloud droplets evaporate, faster in more diluted cloud parcels, leading to a positive correlation between V and L regardless of the mixing mechanism near the cloud top.« less

Evaluation of Multilayer Cloud Detection Using a MODIS CO2-Slicing Algorithm With CALIPSO-CloudSat Measurements

NASA Technical Reports Server (NTRS)

Viudez-Mora, Antonio; Kato, Seiji

2015-01-01

This work evaluates the multilayer cloud (MCF) algorithm based on CO2-slicing techniques against CALISPO-CloudSat (CLCS) measurement. This evaluation showed that the MCF underestimates the presence of multilayered clouds compared with CLCS and are retrained to cloud emissivities below 0.8 and cloud optical septs no larger than 0.3.

Stereographic cloud heights from the imagery of two scan-synchronized geostationary satellites

NASA Technical Reports Server (NTRS)

Minzner, R. A.; Teagle, R. D.; Steranka, J.; Shenk, W. E.

1979-01-01

Scan synchronization of the sensors of two SMS-GOES satellites yields imagery from which cloud heights can be derived stereographically with a theoretical two-sigma random uncertainty of + or - 0.25 km for pairs of satellites separated by 60 degrees of longitude. Systematic height errors due to cloud motion can be kept below 100 m for all clouds with east-west components of speed below hurricane speed, provided the scan synchronization is within 40 seconds at the mid-point latitude, and the spin axis of each satellite is parallel to that of the earth.

Water Ice Cloud Opacities and Temperatures Derived from the Viking IRTM Data Set

NASA Technical Reports Server (NTRS)

TamppariL. K.; Zurek, R. W.; Paige, D. A.

1999-01-01

The degree to which water ice clouds play a role in the Mars climate is unknown. Latent heating of water ice clouds is small and since most hazes appeared to be thin (tau less than or = 1) their radiative effects have been neglected. Condensation likely limits the vertical extent of water vapor in the water column and a lowering of the condensation altitude, as seen in the northern spring and summer, could increase the seasonal exchange of water between the atmosphere and the surface. It has been suggested that water ice cloud formation is more frequent and widespread in the aphelic hemisphere (currently the northern). This may limit water to the northern hemisphere through greater exchange with the regolith and through restricted southward transport of water vapor by the Mars Hadley circulation. In addition, it has been suggested that water ice cloud formation also controls the vertical distribution of atmospheric dust in some seasons. This scavenging of dust may Continuing from the IRTM cloud maps, derived cloud opacities and cloud temperatures for several locations and seasons will be presented. Sensitivities to cloud particle sizes, surface temperature, and dust opacity will be discussed.

Analysis of a jet stream induced gravity wave associated with an observed ice cloud over Greenland

NASA Astrophysics Data System (ADS)

Buss, S.; Hertzog, A.; Hostettler, C.; Bui, T. P.; Lüthi, T.; Wernli, H.

2003-11-01

A polar stratospheric ice cloud (PSC type II) was observed by airborne lidar above Greenland on 14 January 2000. Is was the unique observation of an ice cloud over Greenland during the SOLVE/THESEO 2000 campaign. Mesoscale simulations with the hydrostatic HRM model are presented which, in contrast to global analyses, are capable to produce a vertically propagating gravity wave that induces the low temperatures at the level of the PSC afforded for the ice formation. The simulated minimum temperature is ~8 K below the driving analyses and ~3 K below the frost point, exactly coinciding with the location of the observed ice cloud. Despite the high elevations of the Greenland orography the simulated gravity wave is not a mountain wave. Analyses of the horizontal wind divergence, of the background wind profiles, of backward gravity wave ray-tracing trajectories, of HRM experiments with reduced Greenland topography and of several instability diagnostics near the tropopause level provide consistent evidence that the wave is emitted by the geostrophic adjustment of a jet instability associated with an intense, rapidly evolving, anticyclonically curved jet stream. In order to evaluate the potential frequency of such non-orographic polar stratospheric cloud events, an approximate jet instability diagnostic is performed for the winter 1999/2000. It indicates that ice-PSCs are only occasionally generated by gravity waves emanating from an unstable jet.

Anisotropy of Observed and Simulated Turbulence in Marine Stratocumulus

NASA Astrophysics Data System (ADS)

Pedersen, J. G.; Ma, Y.-F.; Grabowski, W. W.; Malinowski, S. P.

2018-02-01

Anisotropy of turbulence near the top of the stratocumulus-topped boundary layer (STBL) is studied using large-eddy simulation (LES) and measurements from the POST and DYCOMS-II field campaigns. Focusing on turbulence ˜100 m below the cloud top, we see remarkable similarity between daytime and nocturnal flight data covering different inversion strengths and free-tropospheric conditions. With λ denoting wavelength and zt cloud-top height, we find that turbulence at λ/zt≃0.01 is weakly dominated by horizontal fluctuations, while turbulence at λ/zt>1 becomes strongly dominated by horizontal fluctuations. Between are scales at which vertical fluctuations dominate. Typical-resolution LES of the STBL (based on POST flight 13 and DYCOMS-II flight 1) captures observed characteristics of below-cloud-top turbulence reasonably well. However, using a fixed vertical grid spacing of 5 m, decreasing the horizontal grid spacing and increasing the subgrid-scale mixing length leads to increased dominance of vertical fluctuations, increased entrainment velocity, and decreased liquid water path. Our analysis supports the notion that entrainment parameterizations (e.g., in climate models) could potentially be improved by accounting more accurately for anisotropic deformation of turbulence in the cloud-top region. While LES has the potential to facilitate improved understanding of anisotropic cloud-top turbulence, sensitivity to grid spacing, grid-box aspect ratio, and subgrid-scale model needs to be addressed.

Implementation of aerosol-cloud interactions in the regional atmosphere-aerosol model COSMO-MUSCAT(5.0) and evaluation using satellite data

NASA Astrophysics Data System (ADS)

Dipu, Sudhakar; Quaas, Johannes; Wolke, Ralf; Stoll, Jens; Mühlbauer, Andreas; Sourdeval, Odran; Salzmann, Marc; Heinold, Bernd; Tegen, Ina

2017-06-01

The regional atmospheric model Consortium for Small-scale Modeling (COSMO) coupled to the Multi-Scale Chemistry Aerosol Transport model (MUSCAT) is extended in this work to represent aerosol-cloud interactions. Previously, only one-way interactions (scavenging of aerosol and in-cloud chemistry) and aerosol-radiation interactions were included in this model. The new version allows for a microphysical aerosol effect on clouds. For this, we use the optional two-moment cloud microphysical scheme in COSMO and the online-computed aerosol information for cloud condensation nuclei concentrations (Cccn), replacing the constant Cccn profile. In the radiation scheme, we have implemented a droplet-size-dependent cloud optical depth, allowing now for aerosol-cloud-radiation interactions. To evaluate the models with satellite data, the Cloud Feedback Model Intercomparison Project Observation Simulator Package (COSP) has been implemented. A case study has been carried out to understand the effects of the modifications, where the modified modeling system is applied over the European domain with a horizontal resolution of 0.25° × 0.25°. To reduce the complexity in aerosol-cloud interactions, only warm-phase clouds are considered. We found that the online-coupled aerosol introduces significant changes for some cloud microphysical properties. The cloud effective radius shows an increase of 9.5 %, and the cloud droplet number concentration is reduced by 21.5 %.

Characteristics of cloud occurrence using ceilometer measurements and its relationship to precipitation over Seoul

NASA Astrophysics Data System (ADS)

Lee, Sanghee; Hwang, Seung-On; Kim, Jhoon; Ahn, Myoung-Hwan

2018-03-01

Clouds are an important component of the atmosphere that affects both climate and weather, however, their contributions can be very difficult to determine. Ceilometer measurements can provide high resolution information on atmospheric conditions such as cloud base height (CBH) and vertical frequency of cloud occurrence (CVF). This study presents the first comprehensive analysis of CBH and CVF derived using Vaisala CL51 ceilometers at two urban stations in Seoul, Korea, during a three-year period from January 2014 to December 2016. The average frequency of cloud occurrence detected by the ceilometers is 54.3%. It is found that the CL51 is better able to capture CBH as compared to another ceilometer CL31 at a nearby meteorological station because it could detect high clouds more accurately. Frequency distributions for CBH up to 13,000 m providing detailed vertical features with 500-m interval show 55% of CBHs below 2 km for aggregated CBHs. A bimodal frequency distribution was observed for three-layers CBHs. A monthly variation of CVF reveals that frequency concentration of lower clouds is found in summer and winter, and higher clouds more often detected in spring and autumn. Monthly distribution features of cloud occurrence and precipitation are depending on seasons and it might be easy to define their relationship due to higher degree of variability of precipitation than cloud occurrence. However, a fluctuation of cloud occurrence frequency in summer is similar to precipitation in trend, whereas clouds in winter are relatively frequent but precipitation is not accompanied. In addition, recent decrease of summer precipitation could be mostly explained by a decrease of cloud occurrence. Anomalous precipitation recorded sometimes is considerably related to corresponding cloud occurrence. The diurnal and daily variations of CBH and CVF from ceilometer observations and the analysis of microwave radiometer measurements for two typical cloudiness cases are also reviewed in parallel. This analysis in finer temporal scale exhibits that utilization of ground-based observations together could help to analyze the cloud behaviors.

Global CALIPSO Observations of Aerosol Changes Near Clouds

NASA Technical Reports Server (NTRS)

Varnai, Tamas; Marshak, Alexander

2011-01-01

Several recent studies have found that clouds are surrounded by a transition zone of rapidly changing aerosol optical properties and particle size. Characterizing this transition zone is important for better understanding aerosol-cloud interactions and aerosol radiative effects, and also for improving satellite retrievals of aerosol properties. This letter presents a statistical analysis of a monthlong global data set of Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) lidar observations over oceans. The results show that the transition zone is ubiquitous over all oceans and extends up to 15 km away from clouds. They also show that near-cloud enhancements in backscatter and particle size are strongest at low altitudes, slightly below the top of the nearest clouds. Also, the enhancements are similar near illuminated and shadowy cloud sides, which confirms that the asymmetry of Moderate Resolution Imaging Spectroradiometer reflectances found in an earlier study comes from 3-D radiative processes and not from differences in aerosol properties. Finally, the effects of CALIPSO aerosol detection and cloud identification uncertainties are discussed. The findings underline the importance of accounting for the transition zone to avoid potential biases in studies of satellite aerosol products, aerosol-cloud interactions, and aerosol direct radiative effects.

NASA Experiment on Tropospheric-Stratospheric Water Vapor Transport in the Intertropical Convergence Zone

NASA Technical Reports Server (NTRS)

Page, William A.

1982-01-01

The following six papers report preliminary results obtained from a field experiment designed to study the role of tropical cumulo-nimbus clouds in the transfer of water vapor from the troposphere to the stratosphere over the region of Panama. The measurements were made utilizing special NOAA enhanced IR satellite images, radiosonde-ozonesondes and a NASA U-2 aircraft carrying. nine experiments. The experiments were provided by a group of NASA, NOAA, industry, and university scientists. Measurements included atmospheric humidity, air and cloud top temperatures, atmospheric tracer constituents, cloud particle characteristics and cloud morphology. The aircraft made a total of eleven flights from August 30 through September 18, 1980, from Howard Air Force Base, Panama; the pilots obtained horizontal and vertical profiles in and near convectively active regions and flew around and over cumulo-nimbus towers and through the extended anvils in the stratosphere. Cumulo-nimbus clouds in the tropics appear to play an important role in upward water vapor transport and may represent the principal source influencing the stratospheric water vapor budget. The clouds provide strong vertical circulation in the troposphere, mixing surface air and its trace materials (water vapor, CFM's sulfur compounds, etc.) quickly up to the tropopause. It is usually assumed that large scale mean motions or eddy scale motions transport the trace materials through the tropopause and into the stratosphere where they are further dispersed and react with other stratospheric constituents. The important step between the troposphere and stratosphere for water vapor appears to depend upon the processes occurring at or near the tropopause at the tops of the cumulo-nimbus towers. Several processes have been sugested: (1) The highest towers penetrate the tropopause and carry water in the form of small ice particles directly into the stratosphere. (2) Water vapor from the tops of the cumulonimbus clouds is transported somehow through the tropopause, the vapor pressure being controlled by the temperature at the tops of the clouds; the dryness of the stratosphere could be explained if most of the transport occurs in connection with very high clouds in regions with very high and cold tropopause. (3) Cumulo-nimbus anvils act as terrestrial-radiation shields allowing the ice particle temperatures near cloud tops to cool radiatively below the supersaturation point; this cooling would cause a vapor deposition on the ice particles which will settle out and thus act as water scavengers. The experiment was designed to collect information on these detailed physical processes near and above the tropopause in order to assess their importance and the role they play in controlling stratospheric water vapor humidity.

Rain scavenging of solid rocket exhaust clouds

NASA Technical Reports Server (NTRS)

Dingle, A. N.

1978-01-01

An explicit model for cloud microphysics was developed for application to the problem of co-condensation/vaporization of HCl and H2O in the presence of Al2O3 particulate nuclei. Validity of the explicit model relative to the implicit model, which has been customarily applied to atmospheric cloud studies, was demonstrated by parallel computations of H2O condensation upon (NH4)2 SO4 nuclei. A mesoscale predictive model designed to account for the impact of wet processes on atmospheric dynamics is also under development. Input data specifying the equilibrium state of HC1 and H2O vapors in contact with aqueous HC1 solutions were found to be limited, particularly in respect to temperature range.

Vertical structure of tropospheric winds on gas giants

NASA Astrophysics Data System (ADS)

Scott, R. K.; Dunkerton, T. J.

2017-04-01

Zonal mean zonal velocity profiles from cloud-tracking observations on Jupiter and Saturn are used to infer latitudinal variations of potential temperature consistent with a shear stable potential vorticity distribution. Immediately below the cloud tops, density stratification is weaker on the poleward and stronger on the equatorward flanks of midlatitude jets, while at greater depth the opposite relation holds. Thermal wind balance then yields the associated vertical shears of midlatitude jets in an altitude range bounded above by the cloud tops and bounded below by the level where the latitudinal gradient of static stability changes sign. The inferred vertical shear below the cloud tops is consistent with existing thermal profiling of the upper troposphere. The sense of the associated mean meridional circulation in the upper troposphere is discussed, and expected magnitudes are given based on existing estimates of the radiative timescale on each planet.

SUCCESS Evidence for Cirrus Cloud Ice Nucleation Mechanisms

NASA Technical Reports Server (NTRS)

Jensen, Eric; Gore, Warren J. Y. (Technical Monitor)

1997-01-01

During the SUCCESS mission, several measurements were made which should improve our understanding of ice nucleation processes in cirrus clouds. Temperature and water vapor concentration were made with a variety of instruments on the NASA DC-8. These observations should provide accurate upper tropospheric humidities. In particular, we will evaluate what humidities are required for ice nucleation. Preliminary results suggest that substantial supersaturations frequently exist in the upper troposphere. The leading-edge region of wave-clouds (where ice nucleation occurs) was sampled extensively at temperatures near -40 and -60C. These observations should give precise information about conditions required for ice nucleation. In addition, we will relate the observed aerosol composition and size distributions to the ice formation observed to evaluate the role of soot or mineral particles on ice nucleation. As an alternative technique for determining what particles act as ice nuclei, numerous samples of aerosols inside ice crystals were taken. In some cases, large numbers of aerosols were detected in each crystal, indicating that efficient scavenging occurred. Analysis of aerosols in ice crystals when only one particle per crystal was detected should help with the ice nucleation issue. Direct measurements of the ice nucleating activity of ambient aerosols drawn into airborne cloud chambers were also made. Finally, measurements of aerosols and ice crystals in contrails should indicate whether aircraft exhaust soot particles are effective ice nuclei.

The use of marine cloud water samples as a diagnostic tool for aqueous chemistry, cloud microphysical processes and dynamics

NASA Astrophysics Data System (ADS)

Crosbie, E.; Ziemba, L. D.; Moore, R.; Shook, M.; Jordan, C.; Thornhill, K. L., II; Winstead, E.; Shingler, T.; Brown, M.; MacDonald, A. B.; Dadashazar, H.; Sorooshian, A.; Weiss-Penzias, P. S.; Anderson, B.

2017-12-01

Clouds play several roles in the Earth's climate system. In addition to their clear significance to the hydrological cycle, they strongly modulate the shortwave and longwave radiative balance of the atmosphere, with subsequent feedback on the atmospheric circulation. Furthermore, clouds act as a conduit for the fate and emergence of important trace chemical species and are the predominant removal mechanism for atmospheric aerosols. Marine boundary layer clouds cover large swaths of the global oceans. Because of their global significance, they have attracted significant attention into understanding how changes in aerosols are translated into changes in cloud macro- and microphysical properties. The circular nature of the influence of clouds-on-aerosols and aerosols-on-clouds has been used to explain the chaotic patterns often seen in marine clouds, however, this feedback also presents a substantial hurdle in resolving the uncertain role of anthropogenic aerosols on climate. Here we discuss ways in which the chemical constituents found in cloud water can offer insight into the physical and chemical processes inherent in marine clouds, through the use of aircraft measurements. We focus on observational data from cloud water samples collected during flights conducted over the remote North Atlantic and along coastal California across multiple campaigns. We explore topics related to aqueous processing, wet scavenging and source apportionment.

The free radical chemistry of cloud droplets and its impact upon the composition of rain

NASA Technical Reports Server (NTRS)

Chameides, W. L.; Davis, D. D.

1982-01-01

Calculations are presented that simulate the free radical chemistries of the gas phase and aqueous phase within a warm cloud during midday. It is demonstrated that in the presence of midday solar fluxes, the heterogeneous scavenging of OH and HO2 from the gas phase by cloud droplets can represent a major source of free radicals to cloud water, provided the accommodation or sticking coefficient for these species impinging upon water droplets is not less than 0.0001. The aqueous-phase of HO2 radicals are found to be converted to H2O2 by aqueous-phase chemical reactions at a rate that suggests that this mechanism could produce a significant fraction of the H2O2 found in cloud droplets. The rapid oxidation of sulfur species dissolved in cloudwater by this free-radical-produced H2O2 as well as by aqueous-phase OH radicals could conceivably have a significant impact upon the chemical composition of rain.

Structural analysis of stratocumulus convection

NASA Technical Reports Server (NTRS)

Siems, S. T.; Baker, M. B.; Bretherton, C. S.

1990-01-01

The 1 and 20 Hz data are examined from the Electra flights made on July 5, 1987. The flight legs consisted of seven horizontal turbulent legs at the inversion, midcloud, and below clouds, plus 4 soundings made within the same period. The Rosemont temperature sensor and the top and bottom dewpoint sensors were used to measure temperature and humidity at 1 Hz. Inversion structure and entrainment; local dynamics and large scale forcing; convective elements; and decoupling of cloud and subcloud are discussed in relationship to the results of the Electra flight.

Relating large-scale subsidence to convection development in Arctic mixed-phase marine stratocumulus

NASA Astrophysics Data System (ADS)

Young, Gillian; Connolly, Paul J.; Dearden, Christopher; Choularton, Thomas W.

2018-02-01

Large-scale subsidence, associated with high-pressure systems, is often imposed in large-eddy simulation (LES) models to maintain the height of boundary layer (BL) clouds. Previous studies have considered the influence of subsidence on warm liquid clouds in subtropical regions; however, the relationship between subsidence and mixed-phase cloud microphysics has not specifically been studied. For the first time, we investigate how widespread subsidence associated with synoptic-scale meteorological features can affect the microphysics of Arctic mixed-phase marine stratocumulus (Sc) clouds. Modelled with LES, four idealised scenarios - a stable Sc, varied droplet (Ndrop) or ice (Nice) number concentrations, and a warming surface (representing motion southwards) - were subjected to different levels of subsidence to investigate the cloud microphysical response. We find strong sensitivities to large-scale subsidence, indicating that high-pressure systems in the ocean-exposed Arctic regions have the potential to generate turbulence and changes in cloud microphysics in any resident BL mixed-phase clouds.Increased cloud convection is modelled with increased subsidence, driven by longwave radiative cooling at cloud top and rain evaporative cooling and latent heating from snow growth below cloud. Subsidence strengthens the BL temperature inversion, thus reducing entrainment and allowing the liquid- and ice-water paths (LWPs, IWPs) to increase. Through increased cloud-top radiative cooling and subsequent convective overturning, precipitation production is enhanced: rain particle number concentrations (Nrain), in-cloud rain mass production rates, and below-cloud evaporation rates increase with increased subsidence.Ice number concentrations (Nice) play an important role, as greater concentrations suppress the liquid phase; therefore, Nice acts to mediate the strength of turbulent overturning promoted by increased subsidence. With a warming surface, a lack of - or low - subsidence allows for rapid BL turbulent kinetic energy (TKE) coupling, leading to a heterogeneous cloud layer, cloud-top ascent, and cumuli formation below the Sc cloud. In these scenarios, higher levels of subsidence act to stabilise the Sc layer, where the combination of these two forcings counteract one another to produce a stable, yet dynamic, cloud layer.

Estimates for the Probabilities of Surface-to-Air Cloud-Free Lines-of-Sight and Low Cloud Statistics from Ship Observations. Part 1. Fifteen Marine Locations.

DTIC Science & Technology

1980-11-24

time before and after) or cumulus fractus of bad weath’er, or both ( pannus ), usually below altostratus or nimbostratus. 8 = Cumulus and stratocumulus...vibrous upper part by cumulus, stratocumulus, stratus or pannus . + . from Surface Marine Observations Tape Deck TDF-11 *Fog All clouds in the 0-50...Fractus of bad weather, cr V both ( pannus ), usually below Alto- stratus or N~imbostratus. The term "bad weather* denotes the conditions which coenerally

New photoionization models of intergalactic clouds

NASA Technical Reports Server (NTRS)

Donahue, Megan; Shull, J. M.

1991-01-01

New photoionization models of optically thin low-density intergalactic gas at constant pressure, photoionized by QSOs, are presented. All ion stages of H, He, C, N, O, Si, and Fe, plus H2 are modeled, and the column density ratios of clouds at specified values of the ionization parameter of n sub gamma/n sub H and cloud metallicity are predicted. If Ly-alpha clouds are much cooler than the previously assumed value, 30,000 K, the ionization parameter must be very low, even with the cooling contribution of a trace component of molecules. If the clouds cool below 6000 K, their final equilibrium must be below 3000 K, owing to the lack of a stable phase between 6000 and 3000 K. If it is assumed that the clouds are being irradiated by an EUV power-law continuum typical of WSOs, with J0 = 10 exp -21 ergs/s sq cm Hz, typical cloud thicknesses along the line of sight that are much smaller than would be expected from shocks, thermal instabilities, or gravitational collapse are derived.

Analysis of a jet stream induced gravity wave associated with an observed stratospheric ice cloud over Greenland

NASA Astrophysics Data System (ADS)

Buss, S.; Hertzog, A.; Hostettler, C.; Bui, T. B.; Lüthi, D.; Wernli, H.

2004-08-01

A polar stratospheric ice cloud (PSC type II) was observed by airborne lidar above Greenland on 14 January 2000. It was the unique observation of an ice cloud over Greenland during the SOLVE/THESEO 2000 campaign. Mesoscale simulations with the hydrostatic HRM model are presented which, in contrast to global analyses, are capable to produce a vertically propagating gravity wave that induces the low temperatures at the level of the PSC afforded for the ice formation. The simulated minimum temperature is ~8 K below the driving analyses and ~4.5 K below the frost point, exactly coinciding with the location of the observed ice cloud. Despite the high elevations of the Greenland orography the simulated gravity wave is not a mountain wave. Analyses of the horizontal wind divergence, of the background wind profiles, of backward gravity wave ray-tracing trajectories, of HRM experiments with reduced Greenland topography and of several diagnostics near the tropopause level provide evidence that the wave is emitted from an intense, rapidly evolving, anticyclonically curved jet stream. The precise physical process responsible for the wave emission could not be identified definitely, but geostrophic adjustment and shear instability are likely candidates.

In order to evaluate the potential frequency of such non-orographic polar stratospheric cloud events, the non-linear balance equation diagnostic is performed for the winter 1999/2000. It indicates that ice-PSCs are only occasionally generated by gravity waves emanating from spontaneous adjustment.

Theoretical Investigations of Clouds and Aerosols in the Stratosphere and Upper Troposphere

NASA Technical Reports Server (NTRS)

Toon, Owen B.

2005-01-01

support of the Atmospheric Chemistry Modeling and Data Analysis Program. We investigated a wide variety of issues involving ambient stratospheric aerosols, polar stratospheric clouds or heterogeneous chemistry, analysis of laboratory data, and particles in the upper troposphere. The papers resulting from these studies are listed below. In addition, I participated in the 1999-2000 SOLVE mission as one of the project scientists and in the 2002 CRYSTAL field mission as one of the project scientists. Several CU graduate students and research associates also participated in these mission, under support from the ACMAP program, and worked to interpret data. During the past few years my group has completed a number of projects under the

Single-footprint retrievals of temperature, water vapor and cloud properties from AIRS

NASA Astrophysics Data System (ADS)

Irion, Fredrick W.; Kahn, Brian H.; Schreier, Mathias M.; Fetzer, Eric J.; Fishbein, Evan; Fu, Dejian; Kalmus, Peter; Wilson, R. Chris; Wong, Sun; Yue, Qing

2018-02-01

Single-footprint Atmospheric Infrared Sounder spectra are used in an optimal estimation-based algorithm (AIRS-OE) for simultaneous retrieval of atmospheric temperature, water vapor, surface temperature, cloud-top temperature, effective cloud optical depth and effective cloud particle radius. In a departure from currently operational AIRS retrievals (AIRS V6), cloud scattering and absorption are in the radiative transfer forward model and AIRS single-footprint thermal infrared data are used directly rather than cloud-cleared spectra (which are calculated using nine adjacent AIRS infrared footprints). Coincident MODIS cloud data are used for cloud a priori data. Using single-footprint spectra improves the horizontal resolution of the AIRS retrieval from ˜ 45 to ˜ 13.5 km at nadir, but as microwave data are not used, the retrieval is not made at altitudes below thick clouds. An outline of the AIRS-OE retrieval procedure and information content analysis is presented. Initial comparisons of AIRS-OE to AIRS V6 results show increased horizontal detail in the water vapor and relative humidity fields in the free troposphere above the clouds. Initial comparisons of temperature, water vapor and relative humidity profiles with coincident radiosondes show good agreement. Future improvements to the retrieval algorithm, and to the forward model in particular, are discussed.

Analysis of Rapidly Developing Low Cloud Ceilings in a Stable Environment

NASA Technical Reports Server (NTRS)

Wheeler, Mark M.; Case, Jonathan L.

2005-01-01

This report describes the work done by the Applied Meteorology Unit (AMU) in developing a database of days that experienced rapid (< 90 minutes) low cloud formation in a stable atmosphere, resulting in ceilings at the Shuttle Landing Facility (TTS) that violated Space Shuttle Flight Rules (FR). The meteorological conditions favoring the rapid formation of low ceilings include the presence of any inversion below 8000 ft, high relative humidity beneath the inversion, and a clockwise turning of the winds from the surface to the middle troposphere (approx. 15000 ft). The AMU compared and contrasted the atmospheric and thermodynamic conditions between days with rapid low ceiling formation and days with low ceiling resulting from other mechanism. The AMU found that the vertical wind profile is the probable discerning factor between the rapidly-forming ceiling days and other low ceiling days at TTS. Most rapidly-developing low ceiling days had a clockwise turning of the winds with height, whereas other low ceiling days typically had a counter-clockwise turning of the winds with height or negligible vertical wind shear. Forecasters at the Space Meteorology Group (SMG) issue 30 to 90 minute forecasts for low cloud ceilings at TTS to support Space Shuttle landings. Mission verification statistics have shown ceilings to be the number one forecast challenge. More specifically, forecasters at SMG are concerned with any rapidly developing clouds ceilings below 8000 ft in a stable, capped thermodynamic environment, Therefore, the AMU was tasked to examine archived events of rapid stable cloud formation resulting in ceilings below 8000 ft, and document the atmospheric regimes favoring this type of cloud development. The AMU examined the cool season months of November to March during the years of 1993-2003 for days that had low-level inversions and rapid, stable low cloud formation that resulted in ceilings violating the Space Shuttle FR. The AMU wrote and modified existing code to identify inversions from the morning Cape Canaveral, FL rawinsonde (XMR) during the cool season and output pertinent sounding information. They parsed all days with cloud ceilings below 8000 ft at TTS, forming a database of possible rapidly-developing low ceiling events. Days with precipitation or noticeable fog bum-off situations were excluded from the database. Only the daytime hours were examined for possible ceiling development events since low clouds are easier to diagnose with visible satellite imagery. Follow-on work would expand the database to include nighttime cases, using a special enhancement of the infrared imagery for identifying areas of low clouds. The report presents two sample cases of rapidly-developing low cloud ceilings. These cases depict the representative meteorological and thermodynamic characteristics of such events. The cases also illustrate how quickly the cloud decks can develop, sometimes forming in 30 minutes or less. The report also summarizes the composite meteorological conditions for 20 event days with rapid low cloud ceiling formation and 48 non-events days consisting of advection or widespread low cloud ceilings. The meteorological conditions were quite similar for both the event and non-event days, since both types of days experienced low cloud ceilings. Both types of days had a relatively moist environment beneath the inversion based below 8000 ft. In the 20 events identified, de onset of low ceilings occurred between 1200-1800 UTC in every instance. The distinguishing factor between the event and non-event days appears to be the vertical wind profile in the XMR sounding. Eighty-five percent of the event days had a clockwise turning of the winds with height in the lower to middle troposphere whereas 83% of the non-events had a counter-clockwise turning of the winds with height or negligible vertical wind shear. A clockwise turning of the winds with height indicates a warm advection regime, which supports large-scale rising motn and possible cloud formation. Meanwhile, a counter-clockwise turning of the winds with height indicates cold advection or sinking motion in a post-cold frontal environment.

Microphysical response of cloud droplets in a fluctuating updraft. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Harding, D. D.

1977-01-01

The effect of a fluctuating updraft upon a distribution of cloud droplets is examined. Computations are performed for fourteen vertical velocity patterns; each allows a closed parcel of cloud air to undergo downward as well as upward motion. Droplet solution and curvature effects are included. The classical equations for the growth rate of an individual droplet by vapor condensation relies on simplifying assumptions. Those assumptions are isolated and examined. A unique approach is presented in which all energy sources and sinks of a droplet may be considered and is termed the explicit model. It is speculated that the explicit model may enhance the growth of large droplets at greater heights. Such a model is beneficial to the studies of pollution scavenging and acid rain.

Users' instructions for the NASA/MSFC cloud-rise preprocessor program, version 6, and the NASA/MSFC multilayer diffusion program, version 6: Research version for Univac 1108 system

NASA Technical Reports Server (NTRS)

Bjorklund, J. R.

1978-01-01

The cloud-rise preprocessor and multilayer diffusion computer programs were used by NASA in predicting concentrations and dosages downwind from normal and abnormal launches of rocket vehicles. These programs incorporated: (1) the latest data for the heat content and chemistry of rocket exhaust clouds; (2) provision for the automated calculation of surface water pH due to deposition of HCl from precipitation scavenging; (3) provision for automated calculation of concentration and dosage parameters at any level within the vertical grounds for which meteorological inputs have been specified; and (4) provision for execution of multiple cases of meteorological data. Procedures used to automatically calculate wind direction shear in a layer were updated.

Impact of Aerosol Processing on Orographic Clouds

NASA Astrophysics Data System (ADS)

Pousse-Nottelmann, Sara; Zubler, Elias M.; Lohmann, Ulrike

2010-05-01

Aerosol particles undergo significant modifications during their residence time in the atmosphere. Physical processes like coagulation, coating and water uptake, and aqueous surface chemistry alter the aerosol size distribution and composition. At this, clouds play a primary role as physical and chemical processing inside cloud droplets contributes considerably to the changes in aerosol particles. A previous study estimates that on global average atmospheric particles are cycled three times through a cloud before being removed from the atmosphere [1]. An explicit and detailed treatment of cloud-borne particles has been implemented in the regional weather forecast and climate model COSMO-CLM. The employed model version includes a two-moment cloud microphysical scheme [2] that has been coupled to the aerosol microphysical scheme M7 [3] as described by Muhlbauer and Lohmann, 2008 [4]. So far, the formation, transfer and removal of cloud-borne aerosol number and mass were not considered in the model. Following the parameterization for cloud-borne particles developed by Hoose et al., 2008 [5], distinction between in-droplet and in-crystal particles is made to more physically account for processes in mixed-phase clouds, such as the Wegener-Bergeron-Findeisen process and contact and immersion freezing. In our model, this approach has been extended to allow for aerosol particles in five different hydrometeors: cloud droplets, rain drops, ice crystals, snow flakes and graupel. We account for nucleation scavenging, freezing and melting processes, autoconversion, accretion, aggregation, riming and selfcollection, collisions between interstitial aerosol particles and hydrometeors, ice multiplication, sedimentation, evaporation and sublimation. The new scheme allows an evaluation of the cloud cycling of aerosol particles by tracking the particles even when scavenged into hydrometeors. Global simulations of aerosol processing in clouds have recently been conducted by Hoose et al. [6]. Our investigation regarding the influence of aerosol processing will focus on the regional scale using a cloud-system resolving model with a much higher resolution. Emphasis will be placed on orographic mixed-phase precipitation. Different two-dimensional simulations of idealized orographic clouds will be conducted to estimate the effect of aerosol processing on orographic cloud formation and precipitation. Here, cloud lifetime, location and extent as well as the cloud type will be of particular interest. In a supplementary study, the new parameterization will be compared to observations of total and interstitial aerosol concentrations and size distribution at the remote high alpine research station Jungfraujoch in Switzerland. In addition, our simulations will be compared to recent simulations of aerosol processing in warm, mixed-phase and cold clouds, which have been carried out at the location of Jungfraujoch station [5]. References: [1] Pruppacher & Jaenicke (1995), The processing of water vapor and aerosols by atmospheric clouds, a global estimate, Atmos. Res., 38, 283295. [2] Seifert & Beheng (2006), A two-moment microphysics parameterization for mixed-phase clouds. Part 1: Model description, Meteorol. Atmos. Phys., 92, 4566. [3] Vignati et al. (2004), An efficient size-resolved aerosol microphysics module for large-scale transport models, J. Geophys. Res., 109, D22202 [4] Muhlbauer & Lohmann (2008), Sensitivity studies of the role of aerosols in warm-phase orographic precipitation in different flow regimes, J. Atmos. Sci., 65, 25222542. [5] Hoose et al. (2008), Aerosol processing in mixed-phase clouds in ECHAM5HAM: Model description and comparison to observations, J. Geophys. Res., 113, D071210. [6] Hoose et al. (2008), Global simulations of aerosol processing in clouds, Atmos. Chem. Phys., 8, 69396963.

14 CFR 103.23 - Flight visibility and cloud clearance requirements.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 14 Aeronautics and Space 2 2010-01-01 2010-01-01 false Flight visibility and cloud clearance... Flight visibility and cloud clearance requirements. No person may operate an ultralight vehicle when the flight visibility or distance from clouds is less than that in the table found below. All operations in...

14 CFR 103.23 - Flight visibility and cloud clearance requirements.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 14 Aeronautics and Space 2 2011-01-01 2011-01-01 false Flight visibility and cloud clearance... Flight visibility and cloud clearance requirements. No person may operate an ultralight vehicle when the flight visibility or distance from clouds is less than that in the table found below. All operations in...

14 CFR 103.23 - Flight visibility and cloud clearance requirements.

Code of Federal Regulations, 2012 CFR

2012-01-01

... 14 Aeronautics and Space 2 2012-01-01 2012-01-01 false Flight visibility and cloud clearance... Flight visibility and cloud clearance requirements. No person may operate an ultralight vehicle when the flight visibility or distance from clouds is less than that in the table found below. All operations in...

14 CFR 103.23 - Flight visibility and cloud clearance requirements.

Code of Federal Regulations, 2014 CFR

2014-01-01

... 14 Aeronautics and Space 2 2014-01-01 2014-01-01 false Flight visibility and cloud clearance... Flight visibility and cloud clearance requirements. No person may operate an ultralight vehicle when the flight visibility or distance from clouds is less than that in the table found below. All operations in...

14 CFR 103.23 - Flight visibility and cloud clearance requirements.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 14 Aeronautics and Space 2 2013-01-01 2013-01-01 false Flight visibility and cloud clearance... Flight visibility and cloud clearance requirements. No person may operate an ultralight vehicle when the flight visibility or distance from clouds is less than that in the table found below. All operations in...

Description and evaluation of a new four-mode version of the Modal Aerosol Module (MAM4) within version 5.3 of the Community Atmosphere Model

NASA Astrophysics Data System (ADS)

Liu, X.; Ma, P.-L.; Wang, H.; Tilmes, S.; Singh, B.; Easter, R. C.; Ghan, S. J.; Rasch, P. J.

2016-02-01

Atmospheric carbonaceous aerosols play an important role in the climate system by influencing the Earth's radiation budgets and modifying the cloud properties. Despite the importance, their representations in large-scale atmospheric models are still crude, which can influence model simulated burden, lifetime, physical, chemical and optical properties, and the climate forcing of carbonaceous aerosols. In this study, we improve the current three-mode version of the Modal Aerosol Module (MAM3) in the Community Atmosphere Model version 5 (CAM5) by introducing an additional primary carbon mode to explicitly account for the microphysical ageing of primary carbonaceous aerosols in the atmosphere. Compared to MAM3, the four-mode version of MAM (MAM4) significantly increases the column burdens of primary particulate organic matter (POM) and black carbon (BC) by up to 40 % in many remote regions, where in-cloud scavenging plays an important role in determining the aerosol concentrations. Differences in the column burdens for other types of aerosol (e.g., sulfate, secondary organic aerosols, mineral dust, sea salt) are less than 1 %. Evaluating the MAM4 simulation against in situ surface and aircraft observations, we find that MAM4 significantly improves the simulation of seasonal variation of near-surface BC concentrations in the polar regions, by increasing the BC concentrations in all seasons and particularly in cold seasons. However, it exacerbates the overestimation of modeled BC concentrations in the upper troposphere in the Pacific regions. The comparisons suggest that, to address the remaining model POM and BC biases, future improvements are required related to (1) in-cloud scavenging and vertical transport in convective clouds and (2) emissions of anthropogenic and biomass burning aerosols.

Description and evaluation of a new four-mode version of the Modal Aerosol Module (MAM4) within version 5.3 of the Community Atmosphere Model

DOE PAGES

Liu, X.; Ma, P. -L.; Wang, H.; ...

2016-02-08

Atmospheric carbonaceous aerosols play an important role in the climate system by influencing the Earth's radiation budgets and modifying the cloud properties. Despite the importance, their representations in large-scale atmospheric models are still crude, which can influence model simulated burden, lifetime, physical, chemical and optical properties, and the climate forcing of carbonaceous aerosols. In this study, we improve the current three-mode version of the Modal Aerosol Module (MAM3) in the Community Atmosphere Model version 5 (CAM5) by introducing an additional primary carbon mode to explicitly account for the microphysical ageing of primary carbonaceous aerosols in the atmosphere. Compared to MAM3,more » the four-mode version of MAM (MAM4) significantly increases the column burdens of primary particulate organic matter (POM) and black carbon (BC) by up to 40 % in many remote regions, where in-cloud scavenging plays an important role in determining the aerosol concentrations. Differences in the column burdens for other types of aerosol (e.g., sulfate, secondary organic aerosols, mineral dust, sea salt) are less than 1 %. Evaluating the MAM4 simulation against in situ surface and aircraft observations, we find that MAM4 significantly improves the simulation of seasonal variation of near-surface BC concentrations in the polar regions, by increasing the BC concentrations in all seasons and particularly in cold seasons. However, it exacerbates the overestimation of modeled BC concentrations in the upper troposphere in the Pacific regions. As a result, the comparisons suggest that, to address the remaining model POM and BC biases, future improvements are required related to (1) in-cloud scavenging and vertical transport in convective clouds and (2) emissions of anthropogenic and biomass burning aerosols.« less

Effects of synoptic patterns on atmospheric chemistry and aerosols during the Arctic Ocean Expedition 1996

NASA Astrophysics Data System (ADS)

Nilsson, E. Douglas; Barr, Sumner

2001-12-01

The atmospheric program on the Arctic Ocean Expedition of July through September 1996 (AOE-96) was focused on aerosol climate feedback. The expedition took place close to the saddle point between a semipersistent anticyclonic ridge from near Scandinavia to the Arctic coast of eastern Siberia and a trough from the Canadian archipelago across the pole to north central Siberia. The weather varied from anticyclonic clear-sky conditions to cyclonic cloudy conditions, and 13 identifiable migratory features (frontal bands, wave disturbances) clearly influenced local weather, clouds, atmospheric transport, and chemistry. This includes an explosive polar cyclone, born at the lateral heat gradient between Greenland and the pack ice rather than between open sea and the pack ice. The synoptic scale weather systems caused the strongest variability in trace gases (O3 in particular) and aerosols, and also strong variability in the cloud cover. The formation of air masses over the pack ice primarily depends on if there is cyclonic (convergent) or anticyclonic (divergent) flow. Cyclonic flow resulted in a modified marine air mass loaded with vapor, but with low aerosol number concentrations owing to frequent clouds and fogs and efficient cloud scavenging of the aerosol. Anticyclonic flow resulted in almost continental air masses with clear sky, long residence time over the pack ice and subsidence slowly replacing the boundary layer with free tropospheric air, low vapor concentrations, but large aerosol number in lack of efficient cloud scavenging. The synoptic variability and advection from south of the ice edge were weaker than during the predecessor International Arctic Ocean Expedition in 1991 (IAOE-91), when on average the sampled air spent 55 hours over the pack ice compared to more than 120 hours during AOE-96, owing to exceptionally high cyclone activity in 1991. This caused a large difference in atmospheric transport, chemistry, and aerosols between the two expeditions.

Insights on Chemistry of Mercury Species in Clouds over Northern China: Complexation and Adsorption.

PubMed

Li, Tao; Wang, Yan; Mao, Huiting; Wang, Shuxiao; Talbot, Robert W; Zhou, Ying; Wang, Zhe; Nie, Xiaoling; Qie, Guanghao

2018-05-01

Cloud effects on heterogeneous reactions of atmospheric mercury (Hg) are poorly understood due to limited knowledge of cloudwater Hg chemistry. Here we quantified Hg species in cloudwater at the summit of Mt. Tai in northern China. Total mercury (THg) and methylmercury (MeHg) in cloudwater were on average 70.5 and 0.15 ng L -1 , respectively, and particulate Hg (PHg) contributed two-thirds of THg. Chemical equilibrium modeling simulations suggested that Hg complexes by dissolved organic matter (DOM) dominated dissolved Hg (DHg) speciation, which was highly pH dependent. Hg concentrations and speciation were altered by cloud processing, during which significant positive correlations of PHg and MeHg with cloud droplet number concentration ( N d ) were observed. Unlike direct contribution to PHg from cloud scavenging of aerosol particles, abiotic DHg methylation was the most likely source of MeHg. Hg adsorption coefficients K ad (5.9-362.7 L g -1 ) exhibited an inverse-power relationship with cloud residues content. Morphology analyses indicated that compared to mineral particles, fly ash particles could enhance Hg adsorption due to more abundant carbon binding sites on the surface. Severe particulate air pollution in northern China may bring substantial Hg into cloud droplets and impact atmospheric Hg geochemical cycling by aerosol-cloud interactions.

Saharan dust, convective lofting, aerosol enhancement zones, and potential impacts on ice nucleation in the tropical upper troposphere

NASA Astrophysics Data System (ADS)

Twohy, C. H.; Anderson, B. E.; Ferrare, R. A.; Sauter, K. E.; L'Ecuyer, T. S.; van den Heever, S. C.; Heymsfield, A. J.; Ismail, S.; Diskin, G. S.

2017-08-01

Dry aerosol size distributions and scattering coefficients were measured on 10 flights in 32 clear-air regions adjacent to tropical storm anvils over the eastern Atlantic Ocean. Aerosol properties in these regions were compared with those from background air in the upper troposphere at least 40 km from clouds. Median values for aerosol scattering coefficient and particle number concentration >0.3 μm diameter were higher at the anvil edges than in background air, showing that convective clouds loft particles from the lower troposphere to the upper troposphere. These differences are statistically significant. The aerosol enhancement zones extended 10-15 km horizontally and 0.25 km vertically below anvil cloud edges but were not due to hygroscopic growth since particles were measured under dry conditions. Number concentrations of particles >0.3 μm diameter were enhanced more for the cases where Saharan dust layers were identified below the clouds with airborne lidar. Median number concentrations in this size range increased from 100 l-1 in background air to 400 l-1 adjacent to cloud edges with dust below, with larger enhancements for stronger storm systems. Integration with satellite cloud frequency data indicates that this transfer of large particles from low to high altitudes by convection has little impact on dust concentrations within the Saharan Air Layer itself. However, it can lead to substantial enhancement in large dust particles and, therefore, heterogeneous ice nuclei in the upper troposphere over the Atlantic. This may induce a cloud/aerosol feedback effect that could impact cloud properties in the region and downwind.

Aerosol effect on the evolution of the thermodynamic properties of warm convective cloud fields

PubMed Central

Dagan, Guy; Koren, Ilan; Altaratz, Orit; Heiblum, Reuven H.

2016-01-01

Convective cloud formation and evolution strongly depend on environmental temperature and humidity profiles. The forming clouds change the profiles that created them by redistributing heat and moisture. Here we show that the evolution of the field’s thermodynamic properties depends heavily on the concentration of aerosol, liquid or solid particles suspended in the atmosphere. Under polluted conditions, rain formation is suppressed and the non-precipitating clouds act to warm the lower part of the cloudy layer (where there is net condensation) and cool and moisten the upper part of the cloudy layer (where there is net evaporation), thereby destabilizing the layer. Under clean conditions, precipitation causes net warming of the cloudy layer and net cooling of the sub-cloud layer (driven by rain evaporation), which together act to stabilize the atmosphere with time. Previous studies have examined different aspects of the effects of clouds on their environment. Here, we offer a complete analysis of the cloudy atmosphere, spanning the aerosol effect from instability-consumption to enhancement, below, inside and above warm clouds, showing the temporal evolution of the effects. We propose a direct measure for the magnitude and sign of the aerosol effect on thermodynamic instability. PMID:27929097

Aerosol effect on the evolution of the thermodynamic properties of warm convective cloud fields.

PubMed

Dagan, Guy; Koren, Ilan; Altaratz, Orit; Heiblum, Reuven H

2016-12-08

Convective cloud formation and evolution strongly depend on environmental temperature and humidity profiles. The forming clouds change the profiles that created them by redistributing heat and moisture. Here we show that the evolution of the field's thermodynamic properties depends heavily on the concentration of aerosol, liquid or solid particles suspended in the atmosphere. Under polluted conditions, rain formation is suppressed and the non-precipitating clouds act to warm the lower part of the cloudy layer (where there is net condensation) and cool and moisten the upper part of the cloudy layer (where there is net evaporation), thereby destabilizing the layer. Under clean conditions, precipitation causes net warming of the cloudy layer and net cooling of the sub-cloud layer (driven by rain evaporation), which together act to stabilize the atmosphere with time. Previous studies have examined different aspects of the effects of clouds on their environment. Here, we offer a complete analysis of the cloudy atmosphere, spanning the aerosol effect from instability-consumption to enhancement, below, inside and above warm clouds, showing the temporal evolution of the effects. We propose a direct measure for the magnitude and sign of the aerosol effect on thermodynamic instability.

A novel reactor for the simulation of gas and ash interactions in volcanic eruption plumes

NASA Astrophysics Data System (ADS)

Ayris, Paul M.; Cimarelli, Corrado; Delmelle, Pierre; Dingwell, Donald B.

2014-05-01

The chemical interactions between volcanic ash and the atmosphere, hydrosphere, pedosphere, cryosphere and biosphere are initially the result of rapid mobilisation of soluble salts and aqueous acids from wetted particle surfaces. Such surface features are attributable to the scavenging of sulphur and halide species by ash during its transport through the eruption plume and volcanic cloud. It has been historically considered (e.g., Rose, 1977) that the primary mechanism driving scavenging of sulphur and halide species is via condensation of acid aerosols onto ash surfaces within the cold volcanic cloud. However, for large explosive eruptions, insights from new experimental highlight the potential for scavenging via adsorption onto ash within the high-temperature eruption plume. In previous investigations on simple SO2 (Ayris et al. 2013a) and HCl systems (Ayris et al. 2013b), we identified ash composition, and the duration and temperature of gas-ash interaction as key determinants of adsorption-mode scavenging. However, the first generation of gas-ash reactors could not fully investigate the interactions between ash and the hydrous volcanic atmosphere; we have therefore developed an Advanced Gas Ash Reactor (AGAR), which can be fluxed with varying proportions of H2O, CO2, SO2 and HCl. The AGAR consists of a longitudinally-rotating quartz glass reaction bulb contained within a horizontal, three-stage tube furnace operating at temperatures of 25-900° C. A sample mass of up to 100 g can traverse a thermal gradient via manual repositioning of the reaction bulb within the furnace. In combination with existing melt synthesis capabilities in our laboratories, this facility permits a detailed investigation of the effects of ash and gas composition, and temperature on in-plume scavenging of SO2 and HCl. Additionally, the longitudinal rotation enables particle-particle interaction under an 'in-plume' atmosphere, and may yield insight into the effects of gas-ash interaction on aggregation processes. Large quantities of material can be processed in the AGAR. We invite discussions regarding collaboration with 'downstream' projects that would benefit from use of such materials, or from access to and further development of, the advanced gas-ash reactor. References Ayris, P. M., Lee, A. F., Wilson, K., Kueppers, U., Dingwell, D. B., & Delmelle, P. (2013a). SO2 sequestration in large volcanic eruptions: high-temperature scavenging by tephra. Geochimica et Cosmochimica Acta. Ayris, P. M., Delmelle, P., Maters, E., & Dingwell, D. B. (2013b). Quantifying HCl and SO2 adsorption by tephra in volcanic eruptions. In EGU General Assembly Conference Abstracts (Vol. 15, p. 2780). Rose, W. I. (1977). Scavenging of volcanic aerosol by ash: atmospheric and volcanologic implications. Geology, 5(10), 621-624.

On The Cloud Processing of Aerosol Particles: An Entraining Air Parcel Model With Two-dimensional Spectral Cloud Microphysics and A New Formulation of The Collection Kernel

NASA Astrophysics Data System (ADS)

Bott, Andreas; Kerkweg, Astrid; Wurzler, Sabine

A study has been made of the modification of aerosol spectra due to cloud pro- cesses and the impact of the modified aerosols on the microphysical structure of future clouds. For this purpose an entraining air parcel model with two-dimensional spectral cloud microphysics has been used. In order to treat collision/coalescence processes in the two-dimensional microphysical module, a new realistic and continuous formu- lation of the collection kernel has been developed. Based on experimental data, the kernel covers the entire investigated size range of aerosols, cloud and rain drops, that is the kernel combines all important coalescence processes such as the collision of cloud drops as well as the impaction scavenging of small aerosols by big raindrops. Since chemical reactions in the gas phase and in cloud drops have an important impact on the physico-chemical properties of aerosol particles, the parcel model has been extended by a chemical module describing gas phase and aqueous phase chemical reactions. However, it will be shown that in the numerical case studies presented in this paper the modification of aerosols by chemical reactions has a minor influence on the microphysical structure of future clouds. The major process yielding in a second cloud event an enhanced formation of rain is the production of large aerosol particles by collision/coalescence processes in the first cloud.

A comment on "Novel scavenger removal trials increase wind turbine-caused avian fatality estimates"

USGS Publications Warehouse

Huso, Manuela M.P.; Erickson, Wallace P.

2013-01-01

In a recent paper, Smallwood et al. (2010) conducted a study to compare their “novel” approach to conducting carcass removal trials with what they term the “conventional” approach and to evaluate the effects of the different methods on estimated avian fatality at a wind power facility in California. A quick glance at Table 3 that succinctly summarizes their results and provides estimated fatality rates and 80% confidence intervals calculated using the 2 methods reveals a surprising result. The confidence intervals of all of their estimates and most of the conventional estimates extend below 0. These results imply that wind turbines may have the capacity to create live birds. But a more likely interpretation is that a serious error occurred in the calculation of either the average fatality rate or its standard error or both. Further evaluation of their methods reveals that the scientific basis for concluding that “many estimates of scavenger removal rates prior to [their] study were likely biased low due to scavenger swamping” and “previously reported estimates of avian fatality rates … should be adjusted upwards” was not evident in their analysis and results. Their comparison to conventional approaches was not applicable, their statistical models were questionable, and the conclusions they drew were unsupported.

CALIPSO Observations of Transatlantic Dust: Vertical Stratification and Effect of Clouds

NASA Technical Reports Server (NTRS)

Yang, Weidong; Marshak, Alexander; Varnai, Tamas; Kalashnikova, Olga V.; Kostinski, Alexander B.

2012-01-01

CALIOP nighttime measurements of lidar backscatter, color and depolarization ratios during the summer of 2007 are used to study transatlantic dust properties downwind of Saharan sources, and to examine the interaction of clouds and dust. We discuss the following findings: (1) while lidar backscatter doesn't change much with altitude in the Saharan Air Layer (SAL), depolarization and color ratios both increase with altitude in the SAL; (2) lidar backscatter and color ratio increase as dust is transported westward in the SAL; (3) the vertical lapse rate of dust depolarization ratio increases within SAL as plumes move westward; (4) nearby clouds barely affect the backscatter and color ratio of dust volumes within SAL but not so below SAL. Finally, (5) the odds of CALIOP finding dust below SAL next to clouds are about 2/3 of those far away from clouds. This feature, together with an apparent increase in depolarization ratio near clouds, indicates that particles in some dusty volumes lose asphericity in the humid air near clouds, and cannot be identified by CALIPSO as dust.

Benzene, alkylated benzenes, chlorinated hydrocarbons and monoterpenes in snow/ice at Jungfraujoch (46.6 degrees N, 8.0 degrees E) during CLACE 4 and 5.

PubMed

Fries, Elke; Sieg, Karsten; Püttmann, Wilhelm; Jaeschke, Wolfgang; Winterhalter, Richard; Williams, Jonathan; Moortgat, Geert K

2008-03-01

Benzene, alkylated benzenes, chlorinated hydrocarbons and monoterpenes were measured in snow/ice collected directly in-cloud at Jungfraujoch (3580 m asl) in February and March 2005 and 2006 during the CLoud and Aerosol Characterization Experiments CLACE 4 and CLACE 5. Melted snow/ice samples were analyzed by headspace-solid-phase-dynamic-extraction (HS-SPDE) followed by gas chromatography/mass spectrometry (GC/MS). Generally, there was a tendency in the results that higher concentrations were found after longer precipitation-free periods, suggesting that higher concentrations in snow/ice may be caused by the washout effect of precipitation. High concentration variations in snow/ice samples taken at the same time at the same place highlight the heterogeneous nature of snow/ice. Air concentrations calculated by scavenging ratios and measured snow/ice values markedly exceed the typically reported concentrations of benzene and alkylbenzenes in air (Li Y, Campana M, Reimann S, Schaub KS, Staehlin J, Peter T. Hydrocarbon concentrations at the alpine mountain sites Jungfraujoch and Arosa. Atmos Environ 2005;39:1113-27). This argues for an efficient snow/ice scavenging of those compounds from the atmosphere during precipitation formation.

Marine biogenic source of atmospheric organic nitrogen in the subtropical North Atlantic

PubMed Central

Altieri, Katye E.; Fawcett, Sarah E.; Peters, Andrew J.; Sigman, Daniel M.; Hastings, Meredith G.

2016-01-01

Global models estimate that the anthropogenic component of atmospheric nitrogen (N) deposition to the ocean accounts for up to a third of the ocean’s external N supply and 10% of anthropogenic CO2 uptake. However, there are few observational constraints from the marine atmospheric environment to validate these findings. Due to the paucity of atmospheric organic N data, the largest uncertainties related to atmospheric N deposition are the sources and cycling of organic N, which is 20–80% of total N deposition. We studied the concentration and chemical composition of rainwater and aerosol organic N collected on the island of Bermuda in the western North Atlantic Ocean over 18 mo. Here, we show that the water-soluble organic N concentration ([WSON]) in marine aerosol is strongly correlated with surface ocean primary productivity and wind speed, suggesting a marine biogenic source for aerosol WSON. The chemical composition of high-[WSON] aerosols also indicates a primary marine source. We find that the WSON in marine rain is compositionally different from that in concurrently collected aerosols, suggesting that in-cloud scavenging (as opposed to below-cloud “washout”) is the main contributor to rain WSON. We conclude that anthropogenic activity is not a significant source of organic N to the marine atmosphere over the North Atlantic, despite downwind transport from large pollution sources in North America. This, in conjunction with previous work on ammonium and nitrate, leads to the conclusion that only 27% of total N deposition to the global ocean is anthropogenic, in contrast to the 80% estimated previously. PMID:26739561

The Venus SAGE Atmospheric Structure Investigation

NASA Technical Reports Server (NTRS)

Colaprete, Anthony; Crisp, Dave; LaBaw, Clayton; Morse, Stephanie

2005-01-01

Experiment goals and objectives are: a) To accurately define the state properties as a function of altitude from below the 10(exp -4) mb level (approx.150 km) to 92 bars (surface); b) To measure the stability of the atmosphere, and identify convective layers and stable layers, where they exist; c) To detect cloud levels from changes in the lapse rate at their boundaries; d) To provide state properties within the cloud levels, and thus provide supplementary information on cloud composition; e) To search for and characterize wave structure within the atmosphere; f) To search for and measure the intensity and scale of turbulence; g) To measure descent and surface wind speed and direction; h) To provide Lander altitude and attitude during decent for descent imaging analysis; and i) To provide a back-up landing sensor.

Systems analysis of the CO2 concentrating mechanism in cyanobacteria

PubMed Central

Mangan, Niall M; Brenner, Michael P

2014-01-01

Cyanobacteria are photosynthetic bacteria with a unique CO2 concentrating mechanism (CCM), enhancing carbon fixation. Understanding the CCM requires a systems level perspective of how molecular components work together to enhance CO2 fixation. We present a mathematical model of the cyanobacterial CCM, giving the parameter regime (expression levels, catalytic rates, permeability of carboxysome shell) for efficient carbon fixation. Efficiency requires saturating the RuBisCO reaction, staying below saturation for carbonic anhydrase, and avoiding wasteful oxygenation reactions. We find selectivity at the carboxysome shell is not necessary; there is an optimal non-specific carboxysome shell permeability. We compare the efficacy of facilitated CO2 uptake, CO2 scavenging, and HCO3− transport with varying external pH. At the optimal carboxysome permeability, contributions from CO2 scavenging at the cell membrane are small. We examine the cumulative benefits of CCM spatial organization strategies: enzyme co-localization and compartmentalization. DOI: http://dx.doi.org/10.7554/eLife.02043.001 PMID:24842993

Vertical profile of cloud optical parameters derived from airborne measurements above, inside and below clouds

NASA Astrophysics Data System (ADS)

Melnikova, Irina; Gatebe, Charles K.

2018-07-01

Past strategies for retrieving cloud optical properties from remote sensing assumed significant limits for desired parameters such as semi-infinite optical thickness, single scattering albedo equaling unity (non-absorbing scattering), absence of spectral dependence of the optical thickness, etc., and only one optical parameter could be retrieved (either optical thickness or single scattering albedo). Here, we demonstrate a new method based on asymptotic theory for thick atmospheres, and the presence of a diffusion domain within the clouds that does not put restrictions and makes it possible to get two or even three optical parameters (optical thickness, single scattering albedo and phase function asymmetry parameter) for every wavelength independently. We applied this method to measurements of angular distribution of solar radiation above, inside and below clouds, obtained with NASA's Cloud Absorption Radiometer (CAR) over two cases of marine stratocumulus clouds; first case, offshore of Namibia and the second case, offshore of California. The observational and retrieval errors are accounted for by regularization, which allows stable and smooth solutions. Results show good potential for parameterization of the shortwave radiative properties (reflection, transmission, radiative divergence and heating rate) of water clouds.

Temporal variation of the cloud top height over the tropical Pacific observed by geostationary satellites

NASA Astrophysics Data System (ADS)

Nishi, N.; Hamada, A.

2012-12-01

Stratiform clouds (nimbostratus and cirriform clouds) in the upper troposphere accompanied with cumulonimbus activity cover large part of the tropical region and largely affect the radiation and water vapor budgets there. Recently new satellites (CloudSat and CALIPSO) can give us the information of cloud height and cloud ice amount even over the open ocean. However, their coverage is limited just below the satellite paths; it is difficult to capture the whole shape and to trace the lifecycle of each cloud system by using just these datasets. We made, as a complementary product, a dataset of cloud top height and visible optical thickness with one-hour resolution over the wide region, by using infrared split-window data of the geostationary satellites (AGU fall meeting 2011) and released on the internet (http://database.rish.kyoto-u.ac.jp/arch/ctop/). We made lookup tables for estimating cloud top height only with geostationary infrared observations by comparing them with the direct cloud observation by CloudSat (Hamada and Nishi, 2010, JAMC). We picked out the same-time observations by MTSAT and CloudSat and regressed the cloud top height observation of CloudSat back onto 11μm brightness temperature (Tb) and the difference between the 11μm Tb and 12μm Tb. We will call our estimated cloud top height as "CTOP" below. The area of our coverage is 85E-155W (MTSAT2) and 80E-160W(MTSAT1R), and 20S-20N. The accuracy of the estimation with the IR split-window observation is the best in the upper tropospheric height range. We analyzed the formation and maintenance of the cloud systems whose top height is in the upper troposphere with our CTOP analysis, CloudSat 2B-GEOPROF, and GSMaP (Global Satellite Mapping of Precipitation) precipitation data. Most of the upper tropospheric stratiform clouds have their cloud top within 13-15 km range. The cloud top height decreases slowly when dissipating but still has high value to the end. However, we sometimes observe that a little lower cloud top height (6-10 km) is kept within one-two days. A typical example is observed on 5 January 2011 in a dissipating cloud system with 1000-km scale. This cluster located between 0-10N just west of the International Date Line and moved westward with keeping relatively lower cloud top (6-10 km) over one day. This top height is lower than the ubiquitous upper-tropospheric stratiform clouds but higher than the so-called 'congestus cloud' whose top height is around 0C. CloudSat data show the presence of convective rainfall. It suggests that this cloud system continuously kept making new anvil clouds in a little lower height than usual. We examined the seasonal variation of the distribution of cloud systems with a little lower cloud top height (6-11 km) during 2010-11. The number of such cloud systems is not constant with seasons but frequently increased in some specific seasons. Over the equatorial ocean region (east of 150E), they were frequently observed during the northern winter.

Atmospheric Polarization Imaging with Variable Aerosols and Clouds

DTIC Science & Technology

2010-12-10

aerosol sensors to study the effect of variable clouds and aerosols on skylight polarization in the 450 – 780 nm spectral region. Near the end the... skylight (either below the cloud or in a cloud-free portion of the sky), but that they often do not alter the angle of polarization beneath the clouds...relationship also was developed for an initial model of how increasing surface albedo reduces the overhead skylight polarization. 15. SUBJECT

Enhanced PM2.5 pollution in China due to aerosol-cloud interactions.

PubMed

Zhao, Bin; Liou, Kuo-Nan; Gu, Yu; Li, Qinbin; Jiang, Jonathan H; Su, Hui; He, Cenlin; Tseng, Hsien-Liang R; Wang, Shuxiao; Liu, Run; Qi, Ling; Lee, Wei-Liang; Hao, Jiming

2017-06-30

Aerosol-cloud interactions (aerosol indirect effects) play an important role in regional meteorological variations, which could further induce feedback on regional air quality. While the impact of aerosol-cloud interactions on meteorology and climate has been extensively studied, their feedback on air quality remains unclear. Using a fully coupled meteorology-chemistry model, we find that increased aerosol loading due to anthropogenic activities in China substantially increases column cloud droplet number concentration and liquid water path (LWP), which further leads to a reduction in the downward shortwave radiation at surface, surface air temperature and planetary boundary layer (PBL) height. The shallower PBL and accelerated cloud chemistry due to larger LWP in turn enhance the concentrations of particulate matter with diameter less than 2.5 μm (PM 2.5 ) by up to 33.2 μg m -3 (25.1%) and 11.0 μg m -3 (12.5%) in January and July, respectively. Such a positive feedback amplifies the changes in PM 2.5 concentrations, indicating an additional air quality benefit under effective pollution control policies but a penalty for a region with a deterioration in PM 2.5 pollution. Additionally, we show that the cloud processing of aerosols, including wet scavenging and cloud chemistry, could also have substantial effects on PM 2.5 concentrations.

Shallow cumulus rooted in photosynthesis

NASA Astrophysics Data System (ADS)

Vila-Guerau Arellano, J.; Ouwersloot, H.; Horn, G.; Sikma, M.; Jacobs, C. M.; Baldocchi, D.

2014-12-01

We investigate the interaction between plant evapotranspiration, controlled by photosynthesis (for a low vegetation cover by C3 and C4 grasses), and the moist thermals that are responsible for the formation and development of shallow cumulus clouds (SCu). We perform systematic numerical experiments at fine spatial scales using large-eddy simulations explicitly coupled to a plant-physiology model. To break down the complexity of the vegetation-atmospheric system at the diurnal scales, we design the following experiments with increasing complexity: (a) clouds that are transparent to radiation, (b) clouds that shade the surface from the incoming shortwave radiation and (c) plant stomata whose apertures react with an adjustment in time to cloud perturbations. The shading by SCu leads to a strong spatial variability in photosynthesis and the surface energy balance. As a result, experiment (b) simulates SCu that are characterized by less extreme and less skewed values of the liquid water path and cloud-base height. These findings are corroborated by the calculation of characteristics lengths scales of the thermals and clouds using autocorrelation and spectral analysis methods. We find that experiments (a) and (b) are characterized by similar cloud cover evolution, but different cloud population characteristics. Experiment (b), including cloud shading, is characterized by smaller clouds, but closer to each other. By performing a sensitivity analysis on the exchange of water vapor and carbon dioxide at the canopy level, we show that the larger water-use efficiency of C4 grass leads to two opposing effects that directly influence boundary-layer clouds: the thermals below the clouds are more vigorous and deeper driven by a larger buoyancy surface flux (positive effect), but are characterized by less moisture content (negative effect). We conclude that under the investigated mid-latitude atmospheric and well-watered soil conditions, SCu over C4 grass fields is characterized by larger cloud cover and an enhanced liquid water path compared to C3 grass fields.

Relationship between the lipophilicity of gallic acid n-alquil esters' derivatives and both myeloperoxidase activity and HOCl scavenging.

PubMed

Rosso, Rober; Vieira, Tiago O; Leal, Paulo C; Nunes, Ricardo J; Yunes, Rosendo A; Creczynski-Pasa, Tânia B

2006-09-15

The gallic acid and several n-alkyl gallates, with the same number of hydroxyl substituents, varying only in the side carbonic chain length, with respective lipophilicity defined through the C log P, were studied. It evidenced the structure-activity relationship of the myeloperoxidase activity inhibition and the hypochlorous acid scavenger property, as well as its low toxicity in rat hepatic tissue. The gallates with C log P below 3.0 (compounds 2-7) were more active against the enzyme activity, what means that the addition of 1-6 carbons (C log P between 0.92 and 2.92) at the side chain increased approximately 50% the gallic acid effect. However, a relationship between the HOCl scavenging capability and the lipophilicity was not observed. With these results it is possible to suggest that the gallates protect the HOCl targets through two mechanisms: inhibiting its production by the enzyme and scavenging the reactive specie.

Impact of meteorology on air quality modeling over the Po valley in northern Italy

NASA Astrophysics Data System (ADS)

Pernigotti, D.; Georgieva, E.; Thunis, P.; Bessagnet, B.

2012-05-01

A series of sensitivity tests has been performed using both a mesoscale meteorological model (MM5) and a chemical transport model (CHIMERE) to better understand the reasons why all models underestimate particulate matter concentrations in the Po valley in winter. Different options are explored to nudge meteorological observations from regulatory networks into MM5 in order to improve model performances, especially during the low wind speed regimes frequently present in this area. The sensitivity of the CHIMERE modeled particulate matter concentrations to these different meteorological inputs are then evaluated for the January 2005 time period. A further analysis of the CHIMERE model results revealed the need of improving the parametrization of the in-cloud scavenging and vertical diffusivity schemes; such modifications are relevant especially when the model is applied under mist, fog and low stratus conditions, which frequently occur in the Po valley during winter. The sensitivity of modeled particulate matter concentrations to turbulence parameters, wind, temperature and cloud liquid water content in one of the most polluted and complex areas in Europe is finally discussed.

Cloud residues and interstitial aerosols from non-precipitating clouds over an industrial and urban area in northern China

NASA Astrophysics Data System (ADS)

Li, Weijun; Li, Peiren; Sun, Guode; Zhou, Shengzhen; Yuan, Qi; Wang, Wenxing

2011-05-01

Most studies of aerosol-cloud interactions have been conducted in remote locations; few have investigated the characterization of cloud condensation nuclei (CCN) over highly polluted urban and industrial areas. The present work, based on samples collected at Mt. Tai, a site in northern China affected by nearby urban and industrial air pollutant emissions, illuminates CCN properties in a polluted atmosphere. High-resolution transmission electron microscopy (TEM) was used to obtain the size, composition, and mixing state of individual cloud residues and interstitial aerosols. Most of the cloud residues displayed distinct rims which were found to consist of soluble organic matter (OM). Nearly all (91.7%) cloud residues were attributed to sulfate-related salts (the remainder was mostly coarse crustal dust particles with nitrate coatings). Half the salt particles were internally mixed with two or more refractory particles (e.g., soot, fly ash, crustal dust, CaSO 4, and OM). A comparison between cloud residues and interstitial particles shows that the former contained more salts and were of larger particle size than the latter. In addition, a somewhat high number scavenging ratio of 0.54 was observed during cloud formation. Therefore, the mixtures of salts with OMs account for most of the cloud-nucleating ability of the entire aerosol population in the polluted air of northern China. We advocate that both size and composition - the two influential, controlling factors for aerosol activation - should be built into all regional climate models of China.

Cloud-Resolving Model Simulations of Aerosol-Cloud Interactions Triggered by Strong Aerosol Emissions in the Arctic

NASA Astrophysics Data System (ADS)

Wang, H.; Kravitz, B.; Rasch, P. J.; Morrison, H.; Solomon, A.

2014-12-01

Previous process-oriented modeling studies have highlighted the dependence of effectiveness of cloud brightening by aerosols on cloud regimes in warm marine boundary layer. Cloud microphysical processes in clouds that contain ice, and hence the mechanisms that drive aerosol-cloud interactions, are more complicated than in warm clouds. Interactions between ice particles and liquid drops add additional levels of complexity to aerosol effects. A cloud-resolving model is used to study aerosol-cloud interactions in the Arctic triggered by strong aerosol emissions, through either geoengineering injection or concentrated sources such as shipping and fires. An updated cloud microphysical scheme with prognostic aerosol and cloud particle numbers is employed. Model simulations are performed in pure super-cooled liquid and mixed-phase clouds, separately, with or without an injection of aerosols into either a clean or a more polluted Arctic boundary layer. Vertical mixing and cloud scavenging of particles injected from the surface is still quite efficient in the less turbulent cold environment. Overall, the injection of aerosols into the Arctic boundary layer can delay the collapse of the boundary layer and increase low-cloud albedo. The pure liquid clouds are more susceptible to the increase in aerosol number concentration than the mixed-phase clouds. Rain production processes are more effectively suppressed by aerosol injection, whereas ice precipitation (snow) is affected less; thus the effectiveness of brightening mixed-phase clouds is lower than for liquid-only clouds. Aerosol injection into a clean boundary layer results in a greater cloud albedo increase than injection into a polluted one, consistent with current knowledge about aerosol-cloud interactions. Unlike previous studies investigating warm clouds, the impact of dynamical feedback due to precipitation changes is small. According to these results, which are dependent upon the representation of ice nucleation processes in the employed microphysical scheme, Arctic geoengineering/shipping could have substantial local radiative effects, but is unlikely to be effective as the sole means of counterbalancing warming due to climate change.

Seasonal variations of trace elements in precipitation at the largest city in Tibet, Lhasa

NASA Astrophysics Data System (ADS)

Guo, Junming; Kang, Shichang; Huang, Jie; Zhang, Qianggong; Tripathee, Lekhendra; Sillanpää, Mika

2015-02-01

Precipitation samples were collected from March 2010 to August 2012 at an urban site in Lhasa, the capital and largest city of Tibet. The volume weighted mean (VWM) concentrations of 17 trace elements in precipitation were higher during the non-monsoon season than in the monsoon season, but inverse seasonal variations occurred for wet deposition fluxes of most of the trace elements. Concentrations for most of trace elements were negatively correlated with precipitation amount, indicating that below-cloud scavenging of trace elements was an important mechanism contributing to wet deposition of these elements. The elements Al, Sc, V, Cr, Mn, Fe, Mn, Ni, and U displayed low crustal enrichment factors (EFs), whereas Co, Cu, Zn, As, Cd Sn, Pb, and Bi showed high EF values in precipitation, suggesting that anthropogenic activities might be important contributors of these elements at Lhasa. However, this present work indicates a much lower anthropogenic emission at Lhasa than in seriously polluted regions. Our study will not only provide insights for assessing the current status of the atmospheric environment in Lhasa but also enhance our understanding for updating the baseline for environmental protection over the Tibetan Plateau.

Analysis of CCN activity of Remote and Combustion Aerosol over the South East Pacific during autumn 2008 and links to Sc cloud properties

NASA Astrophysics Data System (ADS)

Freitag, S.; Clarke, A. D.; Howell, S. G.; Twohy, C. H.; Snider, J. R.; Toohey, D. W.; Shank, L.; McNaughton, C. S.; Brekhovskikh, V.; Kapustin, V.

2013-12-01

The earth's most extensive Stratocumulus (Sc) deck, situated off the coast of Northern Chile and Southern Peru, strongly influences the radiation budget and climate over the South East Pacific (SEP) by enhancing solar reflection. This feature makes Sc clouds an important constituent for climate modeling, yet these clouds are poorly represented in models. A large uncertainty in understanding the variability in these low cloud fields arises from our deficit in understanding the role of aerosol. Hence, a major goal of the VOCALS (www.eol.ucar.edu/projects/vocals) campaign in 2008 was to further explore and assess interactions of natural and anthropogenic aerosol with Sc clouds in both the more polluted coastal environment and west of 80W where we encountered nearly pristine boundary layer clouds often exposed to cloud-top entrainment of pollution aerosol from the free troposphere. Extensive airborne measurements of size-resolved aerosol volatility and chemical composition collected aboard the NCAR C-130 were analyzed with an aerosol mass spectrometer (AMS) and a single particle soot photometer (SP2) to calculate aerosol hygroscopicity (κ) and predict cloud condensation nuclei (CCN) concentration for all observed air mass types above and below cloud utilizing estimated Sc cloud supersaturations deduced from cloud-processed aerosol size distribution information. The predicted CCN agree to within 10% to measured CCN. Results from this analysis are presented here and CCN variability observed along VOCALS flight tracks is discussed in conjunction with size-resolved cloud droplet information. This includes assessing the impact of aerosol perturbations on the shape of the cloud droplet size distribution parameterized in models and satellite algorithms such as cloud top effective radius retrievals. We will further discuss cloud droplet residual composition collected using a counterflow virtual impactor (CVI) and analyzed with the AMS and SP2. Size resolved variations in residual composition and its relation to CCN composition measured outside the cloud will be examined in terms of the influence of aerosol concentration, size, and chemical composition on Sc clouds.

Scavenging of acidic gases (HCOOH, CH3COOH, HNO3, HCl, and SO2) and ammonia in mixed liquid-solid water clouds at the Puy de Do‸me mountain (France)

NASA Astrophysics Data System (ADS)

Voisin, Didier; Legrand, Michel; Chaumerliac, Nadine

2000-03-01

In order to study scavenging processes of chemical species in mixed phase clouds, in-cloud field measurements were conducted in December 1997 at the Puy de Dôme mountain (center of France, 1465 m above sea level). Soluble species including NH+4, Cl-;, NO3-3, SO-4, HCOO-, CH3COO-, and C2O-4 present in the different phases (supercooled water droplets, rimed snowflakes, interstitial gases, and aerosols) of cold clouds have been investigated. Conducted in parallel to microphysical studies of clouds (liquid water and ice contents, and size distribution of hydrometeors), these chemical investigations allow us to examine the partitioning of strong (HNO3 and HCl) and weak (SO2, HCOOH, and CH3COOH) acids as well as ammonia between interstitial air and the condensed phases (liquid and solid water particles) in mixed clouds present during winter at midlatitude regions. From that, we discuss the processes by which these key atmospheric species are taken up from the gas phase by the condensed phases (liquid and ice) in these cold clouds. We examine several factors which are of importance in driving the final composition of cloud ice. They include the partitioning of species between gaseous and supercooled liquid phases, the amount of rimed ice collected by snowflakes, and the retention of gas during shock freezing of supercooled droplets onto ice particles. Strong acids (HCl and HNO3) as well as NH3, being sufficiently soluble in water, are mainly partitioned into supercooled water droplets. Furthermore, being subsaturated in liquid droplets, these species are well retained in rimed ice. For these species, riming is found to be the main process driving the final composition of snowflakes, direct incorporation from the gas phase during growth of snowflakes remaining insignificant because of low concentrations in the gas phase. For light carboxylic acids the riming process mainly determines the composition of the snowflakes, but an additional significant contribution by gas incorporation during the growth of snowflakes cannot be excluded. SO2 is also present at significant levels in the interstitial air and is poorly retained in ice during riming of supercooled water droplets. However, hydroxymethanesulfonate (HMSA) was likely present in supercooled liquid droplets, making it difficult to evaluate by which mechanism S(IV) (i.e., HMSA plus SO2) has been incorporated into snowflakes.

In search of the best match: probing a multi-dimensional cloud microphysical parameter space to better understand what controls cloud thermodynamic phase

NASA Astrophysics Data System (ADS)

Tan, Ivy; Storelvmo, Trude

2015-04-01

Substantial improvements have been made to the cloud microphysical schemes used in the latest generation of global climate models (GCMs), however, an outstanding weakness of these schemes lies in the arbitrariness of their tuning parameters, which are also notoriously fraught with uncertainties. Despite the growing effort in improving the cloud microphysical schemes in GCMs, most of this effort has neglected to focus on improving the ability of GCMs to accurately simulate the present-day global distribution of thermodynamic phase partitioning in mixed-phase clouds. Liquid droplets and ice crystals not only influence the Earth's radiative budget and hence climate sensitivity via their contrasting optical properties, but also through the effects of their lifetimes in the atmosphere. The current study employs NCAR's CAM5.1, and uses observations of cloud phase obtained by NASA's CALIOP lidar over a 79-month period (November 2007 to June 2014) guide the accurate simulation of the global distribution of mixed-phase clouds in 20∘ latitudinal bands at the -10∘ C, -20∘C and -30∘C isotherms, by adjusting six relevant cloud microphysical tuning parameters in the CAM5.1 via Quasi-Monte Carlo sampling. Among the parameters include those that control the Wegener-Bergeron-Findeisen (WBF) timescale for the conversion of supercooled liquid droplets to ice and snow in mixed-phase clouds, the fraction of ice nuclei that nucleate ice in the atmosphere, ice crystal sedimentation speed, and wet scavenging in stratiform and convective clouds. Using a Generalized Linear Model as a variance-based sensitivity analysis, the relative contributions of each of the six parameters are quantified to gain a better understanding of the importance of their individual and two-way interaction effects on the liquid to ice proportion in mixed-phase clouds. Thus, the methodology implemented in the current study aims to search for the combination of cloud microphysical parameters in a GCM that produce the most accurate reproduction of observations of cloud thermodynamic phase, while simultaneously assessing the weaknesses of the parameterizations in the model. We find that the simulated proportion of liquid to ice in mixed-phase clouds is dominated by the fraction of active ice nuclei in the atmosphere and the WBF timescale. In a follow-up to this study, we apply these results to a fully-coupled GCM, CESM, and find that cloud thermodynamic phase has profound ramifications for the uncertainty associated with climate sensitivity estimates.

Analysis of tethered balloon data from San Nicolas Island on 8 July 1987

NASA Technical Reports Server (NTRS)

Cox, Stephen K.; Duda, David P.; Guinn, Thomas A.; Johnson-Pasqua, Christopher M.; Schubert, Wayne H.; Snider, Jack B.

1990-01-01

Analysis of the 8 July 1987 (Julian Day 189) tethered balloon flight from San Nicolas Island is summarized. The flight commenced at about 14:30 UTC (7:30 Pacific Daylight Time) and lasted six and one-half hours. The position of the Colorado State University (CSU) instrument package as a function of time is shown. For the purpose of presentation of results, researchers divided the flight into 13 legs. These legs consist of 20 minute constant level runs, with the exception of leg 1, which is a sounding from the surface to just above 930 mb. The laser ceilometer record of cloud base is also shown. The cloud base averaged around 970 mb during much of the flight but was more variable near the end. Before the tethered balloon flight commenced, a Communications Link Analysis and Simulation System (CLASS) sounding was released at 12:11 UTC (5:11 PDT). Temperature and moisture data below 927 mb for this sounding is shown. The sounding indicates a cloud top around 955 mb at this time.

The zonal-mean and regional tropospheric pressure responses to changes in ionospheric potential

NASA Astrophysics Data System (ADS)

Zhou, Limin; Tinsley, Brian; Wang, Lin; Burns, Gary

2018-06-01

Global reanalysis data reveal daily surface pressure responses to changes in the global ionospheric potential in both polar and sub-polar regions. We use 21 years of data to show that the pressure response to externally-induced ionospheric potential changes, that are due to the interplanetary magnetic field east-west (IMF By) component, are present in two separate decadal intervals, and follow the opposite ionospheric potential changes in the Arctic and Antarctic for a given By. We use the 4 years of available data to show that the pressure responses to changes in internally generated ionospheric potential, that are caused by low-latitude thunderstorms and highly electrified clouds, agree in sign and sensitivity with those externally generated. We have determined that the daily varying pressure responses are stronger in local winter and spring. The pressure responses at polar latitudes are predominantly over the Antarctic and Greenland ice caps, and those at sub-polar latitudes are of opposite sign, mainly over oceans. A lead-lag analysis confirms that the responses maximize within two days of the ionospheric potential input. Regions of surface pressure fluctuating by about 4 hPa in winter are found with ionospheric potential changes of about 40 kV. The consistent pressure response to the independent external and internal inputs strongly supports the reality of a cloud microphysical mechanism affected by the global electric circuit. A speculative mechanism involves the ionosphere-earth current density Jz, which produces space charge at cloud boundaries and electrically charged droplets and aerosol particles. Ultrafine aerosol particles, under the action of electro-anti-scavenging, are enabled to grow to condensation nuclei size, affecting cloud microphysics and cloud opacity and surface pressure on time scales of hours.

Stable Low Cloud Phase II: Nocturnal Event Study

NASA Technical Reports Server (NTRS)

Bauman, William H., III; Barrett, Joe, III

2007-01-01

This report describes the work done by the Applied Meteorology Unit (AMU) in developing a database of nights that experienced rapid (< 90 minutes) low cloud formation in a stable atmosphere, resulting in ceilings at the Shuttle Landing Facility (TTS) that violated Space Shuttle Flight Rules (FR). This work is the second phase of a similar AMU task that examined the same phenomena during the day. In the first phase of this work, the meteorological conditions favoring the rapid formation of low ceilings include the presence of any inversion below 8000 ft, high relative humidity (RH) beneath the inversion and a clockwise turning of the winds from the surface to the middle troposphere (-15000 ft). The AMU compared and contrasted the atmospheric and thermodynamic conditions between nights with rapid low ceiling formation and nights with low ceilings resulting from other mechanisms. The AMU found that there was little to discern between the rapidly-forming ceiling nights and other low ceiling nights at TTS. When a rapid development occurred, the average RH below the inversions was 87% while non-events had an average RH of 79%. One key parameter appeared to be the vertical wind profile in the Cape Canaveral, FL radiosonde (XMR) sounding. Eighty-three percent of the rapid development events had veering winds with height from the surface to the middle troposphere (-15,000 ft) while 61% of the non-events had veering winds with height. Veering winds indicate a warm-advection regime, which supports large-scale rising motion and ultimately cloud formation in a moist environment. However, only six of the nights (out of 86 events examined) with low cloud ceilings had an occurrence of rapidly developing ceilings. Since only 7% rapid development events were observed in this dataset, it is likely that rapid low cloud development is not a common occurrence during the night, or at least not as common as during the day. In the AMU work on the daytime rapid low cloud development (Case and Wheeler 2005), nearly 30% of the low cloud ceiling cases investigated were identified as rapidly developing events. Forecasters at the Space Meteorology Group (SMG) issue 30 to 90 minute forecasts for low cloud ceilings at TTS to support Space Shuttle landings. Mission verification statistics have shown ceilings to be the number one forecast challenge. More specifically, forecasters at SMG are concerned with any rapidly developing clouds/ceilings below 8000 R in a stable, capped thermodynamic environment. Therefore, the AMU was tasked to examine archived events of rapid stable cloud formation resulting in ceilings below 8000 ft, and document the atmospheric regimes favoring this type of cloud development. The AMU examined the cool season months of November to March during the years of 1994-2005 for nights that had low-level inversions and rapid, stable low cloud formation that resulted in ceilings violating the Space Shuttle FR. The AMU wrote and modified existing code to identify inversions from the evening and morning XMR radiosonde during the cool season and output pertinent sounding information. They parsed all days with cloud ceilings below 8000 ft at TTS, forming a database of possible rapidly-developing low ceiling events. Nights with precipitation or noticeable fog burn-off situations were excluded from the database. Only the nighttime hours were examined for possible ceiling development events since the daytime events were examined in the first phase of this work. The report presents one sample case of rapidly-developing low cloud ceilings. The case depicts the representative meteorological and thermodynamic characteristics of such events. The case also illustrates how quickly the cloud decks can develop, sometimes forming in 30 minutes or less. The report also summarizes the composite meteorological conditions for 6 event nights with rapid low cloud ceiling formation and 80 non-events nights consisting of advection or widespread low cloud ceilings. The teorological conditions were quite similar for both the event and non-event nights, since both types of nights experienced low cloud ceilings. Both types of nights had a relatively moist environment beneath an inversion based below 8000 ft.

New Changes in Jupiter Great Red Spot

NASA Image and Video Library

2015-10-13

This image is one of two images from NASA Hubble Space Telescope comparing the movement of Jupiter clouds. The movement of Jupiter's clouds can be seen by comparing the first map to the second one in this animated pair of images. Zooming in on the Great Red Spot at blue (below, at left) and red (below, at right) wavelengths reveals a unique filamentary feature not previously seen. http://photojournal.jpl.nasa.gov/catalog/PIA19648

Sunrise, Earth Limb

NASA Technical Reports Server (NTRS)

1992-01-01

This sunrise scene (5.5S, 29.5E) was taken early in the morning, when the sun was still below the horizon and not yet illuminating the dark band of low level clouds on the Earth limb. Ranging from 13 to 18 km. above these low level clouds is a brown layer at the tropopause, an atmospheric temperature inversion which isolates the troposphere from the stratosphere and effectively concentrates particulates from both above and below this level.

Homogenizing Surface and Satellite Observations of Cloud. Aspects of Bias in Surface Data.

DTIC Science & Technology

1987-11-10

both ( pannus ), usually below fractus of bad weather, or both ( pannus ), usu- Altostratus or Nimbostratus ally below Altostratus or Nimbostratus 8 Cumulus...Stratocumulus, Stratus of an anvil; either accompanied or not by Cu- or pannus mulonimbus without anvil or fibrous upper part, by Cumulus, Stratocumulus...Stratus or pannus CL clouds invisible owing to darkness, fog, / Stratocumulus, Stratus, Cumulus and Cu- blowing dust or sand, or other similar mulonimbus

Characterizing the Retrieval of Cloud Optical Thickness and Droplet Effective Radius to Overlying Aerosols Using a General Inverse Theory Approach

NASA Astrophysics Data System (ADS)

Coddington, O.; Pilewskie, P.; Schmidt, S.

2013-12-01

The upwelling shortwave irradiance measured by the airborne Solar Spectral Flux Radiometer (SSFR) flying above a cloud and aerosol layer is influenced by the properties of the cloud and aerosol particles below, just as would the radiance measured from satellite. Unlike satellite measurements, those from aircraft provide the unique capability to fly a lower-level leg above the cloud, yet below the aerosol layer, to characterize the extinction of the aerosol layer and account for its impact on the measured cloud albedo. Previous work [Coddington et al., 2010] capitalized on this opportunity to test the effects of aerosol particles (or more appropriately, the effects of neglecting aerosols in forward modeling calculations) on cloud retrievals using data obtained during the Intercontinental Chemical Transport Experiment/Intercontinental Transport and Chemical Transformation of anthropogenic pollution (INTEX-A/ITCT) study. This work showed aerosols can cause a systematic bias in the cloud retrieval and that such a bias would need to be distinguished from a true aerosol indirect effect (i.e. the brightening of a cloud due to aerosol effects on cloud microphysics) as theorized by Haywood et al., [2004]. The effects of aerosols on clouds are typically neglected in forward modeling calculations because their pervasiveness, variable microphysical properties, loading, and lifetimes makes forward modeling calculations under all possible combinations completely impractical. Using a general inverse theory technique, which propagates separate contributions from measurement and forward modeling errors into probability distributions of retrieved cloud optical thickness and droplet effective radius, we have demonstrated how the aerosol presence can be introduced as a spectral systematic error in the distributions of the forward modeling solutions. The resultant uncertainty and bias in cloud properties induced by the aerosols is identified by the shape and peak of the posteriori retrieval distributions. In this work, we apply this general inverse theory approach to extend our analysis of the spectrally-dependent impacts of overlying aerosols on cloud properties over a broad range in cloud optical thickness and droplet effective radius. We investigate the relative impacts of this error source and compare and contrast results to biases and uncertainties in cloud properties induced by varying surface conditions (ocean, land, snow). We perform the analysis for two different measurement accuracies (3% and 0.3%) that are typical of current passive imagers, such as the Moderate Resolution Imaging Spectroradiometer (MODIS) [Platnick et al., 2003], and that are expected for future passive imagers, such as the HyperSpectral Imager for Climate Science (HySICS) [Kopp et al., 2010]. Coddington, O., P. Pilewskie, et al., 2010, J. Geophys. Res., 115, doi: 10.1029/2009JD012829. Haywood, J. M., S. R. Osborne, and S. J. Abel, 2004, Q. J. R. Meteorol. Soc., 130, 779-800. Kopp, G., et al., 2010, Hyperspectral Imagery Radiometry Improvements for Visible and Near-Infrared Climate Studies, paper presented at 2010 Earth Science Technology Forum, Arlington, VA, USA. Platnick, S., et al., 2003, IEEE Trans. Geosci. Remote Sens., 41(2), 459- 473.

Curious Clouds

NASA Image and Video Library

2006-06-13

Saturn atmosphere produces beautiful and sometimes perplexing features. Is the bright feature below center a rare crossing of a feature from a zone to a belt, or is it an illusion created by different cloud layers at different levels?

Impact of combustion products from Space Shuttle launches on ambient air quality

NASA Technical Reports Server (NTRS)

Dumbauld, R. K.; Bowers, J. F.; Cramer, H. E.

1974-01-01

The present work describes some multilayer diffusion models and a computer program for these models developed to predict the impact of ground clouds formed during Space Shuttle launches on ambient air quality. The diffusion models are based on the Gaussian plume equation for an instantaneous volume source. Cloud growth is estimated on the basis of measurable meteorological parameters: standard deviation of the wind azimuth angle, standard deviation of wind elevation angle, vertical wind-speed shear, vertical wind-direction shear, and depth of the surface mixing layer. Calculations using these models indicate that Space Shuttle launches under a variety of meteorological regimes at Kennedy Space Center and Vandenberg AFB are unlikely to endanger the exposure standards for HCl; similar results have been obtained for CO and Al2O3. However, the possibility that precipitation scavenging of the ground cloud might result in an acidic rain that could damage vegetation has not been investigated.

The Mixed-Phase Arctic Cloud Experiment (M-PACE)

NASA Technical Reports Server (NTRS)

Verlinde, J.; Harrington, J. Y.; McFarquhar, G. M.; Yannuzzi, V. T.; Avramov, A.; Greenberg, S.; Johnson, N.; Zhang, G.; Poellot, M. R.; Mather, J. H.;

Infrared Image of Low Clouds on Venus

NASA Technical Reports Server (NTRS)

1993-01-01

This false-color image is a near-infrared map of lower-level clouds on the night side of Venus, obtained by the Near Infrared Mapping Spectrometer aboard the Galileo spacecraft as it approached the planet's night side on February 10, 1990. Bright slivers of sunlit high clouds are visible above and below the dark, glowing hemisphere. The spacecraft is about 100,000 kilometers (60,000 miles) above the planet. An infrared wavelength of 2.3 microns (about three times the longest wavelength visible to the human eye) was used. The map shows the turbulent, cloudy middle atmosphere some 50-55 kilometers (30- 33 miles) above the surface, 10-16 kilometers or 6-10 miles below the visible cloudtops. The red color represents the radiant heat from the lower atmosphere (about 400 degrees Fahrenheit) shining through the sulfuric acid clouds, which appear as much as 10 times darker than the bright gaps between clouds. This cloud layer is at about -30 degrees Fahrenheit, at a pressure about 1/2 Earth's surface atmospheric pressure. Near the equator, the clouds appear fluffy and blocky; farther north, they are stretched out into East-West filaments by winds estimated at more than 150 mph, while the poles are capped by thick clouds at this altitude.

A statistical retrieval of cloud parameters for the millimeter wave Ice Cloud Imager on board MetOp-SG

NASA Astrophysics Data System (ADS)

Prigent, Catherine; Wang, Die; Aires, Filipe; Jimenez, Carlos

2017-04-01

The meteorological observations from satellites in the microwave domain are currently limited to below 190 GHz. However, the next generation of European Organisation for the Exploitation of Meteorological Satellites (EUMETSAT) Polar System-Second Generation-EPS-SG will carry an instrument, the Ice Cloud Imager (ICI), with frequencies up to 664 GHz, to improve the characterization of the cloud frozen phase. In this paper, a statistical retrieval of cloud parameters for ICI is developed, trained on a synthetic database derived from the coupling of a mesoscale cloud model and radiative transfer calculations. The hydrometeor profiles simulated with the Weather Research and Forecasting model (WRF) for twelve diverse European mid-latitude situations are used to simulate the brightness temperatures with the Atmospheric Radiative Transfer Simulator (ARTS) to prepare the retrieval database. The WRF+ARTS simulations have been compared to the Special Sensor Microwave Imager/Sounder (SSMIS) observations up to 190 GHz: this successful evaluation gives us confidence in the simulations at the ICI channels from 183 to 664 GHz. Statistical analyses have been performed on this simulated retrieval database, showing that it is not only physically realistic but also statistically satisfactory for retrieval purposes. A first Neural Network (NN) classifier is used to detect the cloud presence. A second NN is developed to retrieve the liquid and ice integrated cloud quantities over sea and land separately. The detection and retrieval of the hydrometeor quantities (i.e., ice, snow, graupel, rain, and liquid cloud) are performed with ICI-only, and with ICI combined with observations from the MicroWave Imager (MWI, with frequencies from 19 to 190 GHz, also on board MetOp-SG). The ICI channels have been optimized for the detection and quantification of the cloud frozen phases: adding the MWI channels improves the performance of the vertically integrated hydrometeor contents, especially for the cloud liquid phases. The relative error for the retrieved integrated frozen water content (FWP, i.e., ice+snow+graupel) is below 40% for 0.1kg/m2 < FWP < 0.5kg/m2 and below 20% for FWP > 0.5 kg/m2.

Marine boundary layer cloud regimes and POC formation in an LES coupled to a bulk aerosol scheme

NASA Astrophysics Data System (ADS)

Berner, A. H.; Bretherton, C. S.; Wood, R.; Muhlbauer, A.

2013-07-01

A large-eddy simulation (LES) coupled to a new bulk aerosol scheme is used to study long-lived regimes of aerosol-boundary layer cloud-precipitation interaction and the development of pockets of open cells (POCs) in subtropical stratocumulus cloud layers. The aerosol scheme prognoses mass and number concentration of a single log-normal accumulation mode with surface and entrainment sources, evolving subject to processing of activated aerosol and scavenging of dry aerosol by cloud and rain. The LES with the aerosol scheme is applied to a range of steadily-forced simulations idealized from a well-observed POC case. The long-term system evolution is explored with extended two-dimensional simulations of up to 20 days, mostly with diurnally-averaged insolation. One three-dimensional two-day simulation confirms the initial development of the corresponding two-dimensional case. With weak mean subsidence, an initially aerosol-rich mixed layer deepens, the capping stratocumulus cloud slowly thickens and increasingly depletes aerosol via precipitation accretion, then the boundary layer transitions within a few hours into an open-cell regime with scattered precipitating cumuli, in which entrainment is much weaker. The inversion slowly collapses for several days until the cumulus clouds are too shallow to efficiently precipitate. Inversion cloud then reforms and radiatively drives renewed entrainment, allowing the boundary layer to deepen and become more aerosol-rich, until the stratocumulus layer thickens enough to undergo another cycle of open-cell formation. If mean subsidence is stronger, the stratocumulus never thickens enough to initiate drizzle and settles into a steady state. With lower initial aerosol concentrations, this system quickly transitions into open cells, collapses, and redevelops into a different steady state with a shallow, optically thin cloud layer. In these steady states, interstitial scavenging by cloud droplets is the main sink of aerosol number. The system is described in a reduced two-dimensional phase plane with inversion height and boundary-layer average aerosol concentrations as the state variables. Simulations with a full diurnal cycle show similar evolutions, except that open-cell formation is phase-locked into the early morning hours. The same steadily-forced modeling framework is applied to the development and evolution of a POC and the surrounding overcast boundary layer. An initial aerosol perturbation applied to a portion of the model domain leads that portion to transition into open-cell convection, forming a POC. Reduced entrainment in the POC induces a negative feedback between areal fraction covered by the POC and boundary layer depth changes. This stabilizes the system by controlling liquid water path and precipitation sinks of aerosol number in the overcast region, while also preventing boundary-layer collapse within the POC, allowing the POC and overcast to coexist indefinitely in a quasi-steady equilibrium.

The dependence of entrainment and drizzle in marine stratiform clouds on biomass burning aerosols derived from stable isotope and thermodynamic profiles

NASA Astrophysics Data System (ADS)

Henze, D.; Noone, D.

2017-12-01

A third of the world's biomass burning aerosol (BBA) particles are generated in southern Africa, and these particles are swept into the midlevel troposphere over the southeast Atlantic Ocean. The presence of these aerosols over the marine environment of the south east Atlantic offers a unique natural laboratory for studying aerosol effects on climate, and specifically a modification to the hydrologic cycle and microphysical characteristics of clouds. Different rates of condensation with high aerosol numbers change the precipitation rates in drizzling stratiform clouds, while the mixing of aerosols into the cloud layer is synonymous with entrainment from above cloud top near the top of the subtropical inversion. To better understanding the magnitude of the aerosol influence on southeast Atlantic boundary layer clouds we analyze the cloud-top entrainment and drizzle as a function of aerosol loading to determine the impact of BBA. Entrainment was determined from mixing line analysis based on profile measurements of moist static energy, total water, and the two most common heavy isotopes of water - HDO and H218O. Data was collected on the P-3 Orion aircraft during the NASA 2017 ORACLES campaign. Using these measurements, a box model was constructed using the combined conservation laws associated with all four of these quantities to estimate the entrainment and rainout of cloud liquid. The population of profiles sampled by the aircraft over the course of the 30 day mission spans varying concentrations of BBA. Initial plots of the water isotope mixing lines show where and to what degree the BBA air mass has mixed into the boundary layer air mass from above. This is demonstrated by the fact that the mixing end-members are the same for the different areas sampled, but the rate at which the various mixing lines are traversed as a function of altitude varies. Further, the mixing lines as a function of height traverse back and forth between end members multiple times over one profile. This suggests that air masses are mixing by `layering' into each other, and helps us to better represent entrainment in our box model. Meanwhile, isotope ratios measured below vs above the cloud layer show that the air above the clouds is depleted of heavy water isotopes in comparison to below - the degree of depletion could correspond to drizzle amount.

Water Absorption in Galactic Translucent Clouds: Conditions and History of the Gas Derived from Herschel/HIFI PRISMAS Observations

NASA Astrophysics Data System (ADS)

Flagey, N.; Goldsmith, P. F.; Lis, D. C.; Gerin, M.; Neufeld, D.; Sonnentrucker, P.; De Luca, M.; Godard, B.; Goicoechea, J. R.; Monje, R.; Phillips, T. G.

2013-01-01

We present Herschel/HIFI observations of the three ground state transitions of H2O (556, 1669, and 1113 GHz) and H218O (547, 1655, and 1101 GHz)—as well as the first few excited transitions of H2O (987, 752, and 1661 GHz)—toward six high-mass star-forming regions, obtained as part of the PRISMAS (PRobing InterStellar Molecules with Absorption line Studies) Guaranteed Time Key Program. Water vapor associated with the translucent clouds in Galactic arms is detected in absorption along every line of sight in all the ground state transitions. The continuum sources all exhibit broad water features in emission in the excited and ground state transitions. Strong absorption features associated with the source are also observed at all frequencies except 752 GHz. We model the background continuum and line emission to infer the optical depth of each translucent cloud along the lines of sight. We derive the column density of H2O or H218O for the lower energy level of each transition observed. The total column density of water in translucent clouds is usually about a few 1013 cm-2. We find that the abundance of water relative to hydrogen nuclei is 1 × 10-8 in agreement with models for oxygen chemistry in which high cosmic ray ionization rates are assumed. Relative to molecular hydrogen, the abundance of water is remarkably constant through the Galactic plane with X(H2O) =5 × 10-8, which makes water a good traced of H2 in translucent clouds. Observations of the excited transitions of H2O enable us to constrain the abundance of water in excited levels to be at most 15%, implying that the excitation temperature, T ex, in the ground state transitions is below 10 K. Further analysis of the column densities derived from the two ortho ground state transitions indicates that T ex ~= 5 K and that the density n(H2) in the translucent clouds is below 104 cm-3. We derive the water ortho-to-para ratio for each absorption feature along the line of sight and find that most of the clouds show ratios consistent with the value of 3 expected in thermodynamic equilibrium in the high-temperature limit. However, two clouds with large column densities exhibit a ratio that is significantly below 3. This may argue that the history of water molecules includes a cold phase, either when the molecules were formed on cold grains in the well-shielded, low-temperature regions of the clouds, or when they later become at least partially thermalized with the cold gas (~25 K) in those regions; evidently, they have not yet fully thermalized with the warmer (~50 K) translucent portions of the clouds. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.

A framework for expanding aqueous chemistry in the ...

EPA Pesticide Factsheets

This paper describes the development and implementation of an extendable aqueous-phase chemistry option (AQCHEM − KMT(I)) for the Community Multiscale Air Quality (CMAQ) modeling system, version 5.1. Here, the Kinetic PreProcessor (KPP), version 2.2.3, is used to generate a Rosenbrock solver (Rodas3) to integrate the stiff system of ordinary differential equations (ODEs) that describe the mass transfer, chemical kinetics, and scavenging processes of CMAQ clouds. CMAQ's standard cloud chemistry module (AQCHEM) is structurally limited to the treatment of a simple chemical mechanism. This work advances our ability to test and implement more sophisticated aqueous chemical mechanisms in CMAQ and further investigate the impacts of microphysical parameters on cloud chemistry. Box model cloud chemistry simulations were performed to choose efficient solver and tolerance settings, evaluate the implementation of the KPP solver, and assess the direct impacts of alternative solver and kinetic mass transfer on predicted concentrations for a range of scenarios. Month-long CMAQ simulations for winter and summer periods over the US reveal the changes in model predictions due to these cloud module updates within the full chemical transport model. While monthly average CMAQ predictions are not drastically altered between AQCHEM and AQCHEM − KMT, hourly concentration differences can be significant. With added in-cloud secondary organic aerosol (SOA) formation from bio

Microphysical properties of the Shuttle exhaust cloud

NASA Technical Reports Server (NTRS)

Keller, V. W.; Anderson, B. J.

1983-01-01

A data base describing the properties of the exhaust cloud produced by the launch of the STS has been developed based on data from a series of ground and aircraft based measurements made during the launches of STS 2, 3, and 4. Aircraft observations were performed during the STS-3 launch with a NOAA WP-3D Orion hurricane research aircraft which contained instrumentation for cloud condensation nucleus and ice nucleus counting, Aitken particle counting, and pH determination. Ground observations were conducted at 50 different sites, as well as in the direct exhaust from the solid rocket booster flame trench at all three launches. The data is analyzed in order to determine any possible adverse impacts of the exhaust products on human health and/or the environment. Analyses of the exhaust cloud measurements indicate that in the case of the ground cloud where plenty of large water drops are present and considerable scavenging and fallout of aerosol takes place, possible adverse impacts of the remaining aerosols (CCN and IN) on natural precipitation processes which may occur in the launch area hours after the launch are remote. However, it is determined that under certain atmospheric conditions there could be short term adverse effects on visibility.

The clouds are hazes of Venus

NASA Technical Reports Server (NTRS)

Esposito, L. W.; Knollenberg, R. G.; Marov, M. IA.; Toon, O. B.; Turco, R. P.

1983-01-01

Pioneer Venus and Venera probe data for the clouds of Venus are considered. These clouds consist of a main cloud deck at 45-70 km altitude, with thinner hazes above and below, although the microphysical properties of the main cloud are further subdivided into upper, middle and lower cloud levels. Much of the cloud exhibits a multimodal particle size distribution, with the mode most visible from the earth being H2SO4 droplets having 2-3 micron diameters. Despite variations, the vertical structure of the clouds indicates persistent features at sites separated by years and by great distances. The clouds are more strongly affected by radiation than by latent heat release, and the small particle size and weak convective activity observed are incompatible with lightning of cloud origin.

Sensitivity of aerosol indirect forcing and autoconversion to cloud droplet parameterization: an assessment with the NASA Global Modeling Initiative.

NASA Astrophysics Data System (ADS)

Sotiropoulou, R. P.; Meshkhidze, N.; Nenes, A.

2006-12-01

The aerosol indirect forcing is one of the largest sources of uncertainty in assessments of anthropogenic climate change [IPCC, 2001]. Much of this uncertainty arises from the approach used for linking cloud droplet number concentration (CDNC) to precursor aerosol. Global Climate Models (GCM) use a wide range of cloud droplet activation mechanisms ranging from empirical [Boucher and Lohmann, 1995] to detailed physically- based formulations [e.g., Abdul-Razzak and Ghan, 2000; Fountoukis and Nenes, 2005]. The objective of this study is to assess the uncertainties in indirect forcing and autoconversion of cloud water to rain caused by the application of different cloud droplet parameterization mechanisms; this is an important step towards constraining the aerosol indirect effects (AIE). Here we estimate the uncertainty in indirect forcing and autoconversion rate using the NASA Global Model Initiative (GMI). The GMI allows easy interchange of meteorological fields, chemical mechanisms and the aerosol microphysical packages. Therefore, it is an ideal tool for assessing the effect of different parameters on aerosol indirect forcing. The aerosol module includes primary emissions, chemical production of sulfate in clear air and in-cloud aqueous phase, gravitational sedimentation, dry deposition, wet scavenging in and below clouds, and hygroscopic growth. Model inputs include SO2 (fossil fuel and natural), black carbon (BC), organic carbon (OC), mineral dust and sea salt. The meteorological data used in this work were taken from the NASA Data Assimilation Office (DAO) and two different GCMs: the NASA GEOS4 finite volume GCM (FVGCM) and the Goddard Institute for Space Studies version II' (GISS II') GCM. Simulations were carried out for "present day" and "preindustrial" emissions using different meteorological fields (i.e. DAO, FVGCM, GISS II'); cloud droplet number concentration is computed from the correlations of Boucher and Lohmann [1995], Abdul-Razzak and Ghan [2000], Feingold and Heymsfield [1992], Fountoukis and Nenes [2005] and Segal and Khain [2006]. Computed CDNC is used to calculate the cloud optical depth, the autoconversion rate and the mean top-of-the-atmosphere (TOA) short-wave radiative forcing using modified FAST-J algorithm [Meshkhidze et al., 2006]. Autoconversion of cloud water to precipitation is parameterized following the formulation of Khairoutdinov and Kogan [2000]. References Abdul-Razzak, H., and S. J. Ghan (2000), J. Geophys. Res., 105, 6837-6844. Boucher, O., and U. Lohmann (1995), Tellus, Ser. B, 47, 281- 300. Feingold, G. and A. Heymsfield (1992), J. Atmos. Sci., 49, 2325-2342. Fountoukis, C., and A. Nenes (2005), J. Geophys. Res., 110, D11212, doi:10.1029/ 2004JD005591. Intergovernmental Panel on Climate Change - IPCC (2001), Climate Change, The Scientific Basis, Cambridge University Press, UK. Khairoutdinov, M. and Y. Kogan (2000), Mon. Weather Rev., 128 (1), 229-243. Meshkhidze, N., A Nenes, J. Kouatchou, B. Das and J. Rodriguez, 7th International Aerosol Conference, American Association for Aerosol Research (IAC 2006), St. Paul, Minnesota, October 2006 Nenes, A., and J. H. Seinfeld (2003), J. Geophys. Res., 108, 4415, doi:10.1029/ 2002JD002911. Segal, Y., and A. Khain (2006), J. Geophys. Res., 111, D15204, doi:10.1029/2005JD006561.

How Often and Why MODIS Cloud Property Retrievals Fail for Liquid-Phase Clouds over Ocean? a Comprehensive Analysis Based on a-Train Observations

NASA Astrophysics Data System (ADS)

Zhang, Z.; Cho, H. M.; Platnick, S. E.; Meyer, K.; Lebsock, M. D.

2014-12-01

The cloud optical thickness (τ) and droplet effective radius (re) are two key cloud parameters retrieved by MODIS (Moderate Resolution Imaging Spectroradiometer). These MODIS cloud products are widely used in a broad range of earth system science applications. In this paper, we present a comprehensive analysis of the failed cloud τ and/or re retrievals for liquid-phase clouds over ocean in the Collection 6 MODIS cloud product. The main findings from this study are summarized as follows: MODIS retrieval failure rates for marine boundary layer (MBL) clouds have a strong dependence on the spectral combination used for retrieval (e.g., 0.86 + 2.1 µm vs. 0.8 + 3.7 µm) and the cloud morphology (i.e., "good" pixels vs. partly cloudy (PCL) pixels). Combining all clear-sky-restoral (CSR) categories (CSR=0,1 and 3), the 0.86 + 2.1 µm and 0.86 + 3.7 µm spectral combinations have an overall failure rate of about 20% and 12%, respectively (See figure below). The PCL pixels (CSR=1 & 3) have significantly higher failure rates and contribute more to the total failure population than the "good" (CSR=0) pixels. The majority of the failed retrievals are caused by the re too large failure, which explains about 85% and 70% of the failed 0.86 + 2.1 µm and 0.86 + 3.7 µm retrievals, respectively. The remaining failures are either due to the re too small failure or τ retrieval failure. The geographical distribution of failure rates has a significant dependence on cloud regime, lower over the coastal stratocumulus cloud regime and higher over the broken trade-wind cumulus cloud regime over open oceans. Enhanced retrieval failure rates are found when MBL clouds have high sub-pixel inhomogeneity , or are located at special Sun-satellite viewing geometries, such as sunglint, large viewing or solar zenith angle, or cloudbow and glory angles, or subject to cloud masking, cloud overlapping and/or cloud phase retrieval issues. About 80% of the failure retrievals can be attributed to at least one or more potential reasons mentioned above. Collocated radar reflectivity observations from CloudSat suggest that the remaining 20% are unlikely to be retrieval artifacts, but reflection of true cloud microphysics, i.e., the true is either truly very small or very large.

Geochemical and stable isotope characteristics of urban heavy rain in the downtown of Tokyo, Japan

NASA Astrophysics Data System (ADS)

Uchiyama, Ryunosuke; Okochi, Hiroshi; Ogata, Hiroko; Katsumi, Naoya; Asai, Daisuke; Nakano, Takanori

2017-09-01

In order to make clear the impact of air pollution on the formation of sudden and locally-distributed heavy rain in urban area (hereafter Urban Heavy Rain: UHR), we analyzed inorganic ion concentration and stable isotope ratio of water (δD and δ18O) in rainwater. Rainwater samples were collected in Shinjuku, which is a representative downtown of Tokyo, Japan, during four years from October 2012 to December 2015. The concentration and wet deposition fluxes of acidic components (H+, NH4+, NO3-, and nss-SO42 -) in UHR were especially higher than those in other types of rain events, i.e. normal rain, typhoon heavy rain, and frontal heavy rain. UHR had distinctly lower stable isotope ratios than those in other urban rains with same rainfall amount and summer precipitation systems. There was a high negative correlation between δ18O and the distances from the sampling point to the formation area of UHR within 10 km, while there were high positive correlations between δ18O and the concentration of acidic components in UHR. These findings indicate that UHR could effectively scavenge acidic substances within cloud and suggest the use of stable isotope ratios as tracers of an urban heavy rain's water and in-cloud scavenging process.

CCN activation and efficiency of nucleation and impaction removal process of biomass burning aerosols in Brazil: preliminary results.

NASA Astrophysics Data System (ADS)

Sánchez Gácita, Madeleine; Longo, Karla M.; Freitas, Saulo R.; Martin, Scot T.

2015-04-01

The biomass burning activity constitutes an important source of aerosols and trace gases to the atmosphere globally. In South America, during the dry season, aerosols prevenient from biomass burning are typically transported to long distances from its sources before being removed though contributing significantly to the aerosol budget on a continental scale. The uncertainties in the magnitude of the impacts on the hydrological cycle, the radiation budget and the biogeochemical cycles on a continental scale are still noteworthy. The still unknowns on the efficiency of biomass burning aerosol to act as cloud condensation nuclei (CCN) and the effectiveness of the nucleation and impaction scavenging mechanisms in removing them from the atmosphere contribute to such uncertainties. In the present work, the explicit modelling of the early stages of cloud development using a parcel model for the typical conditions of the dry season and dry-to-wet transition periods in Amazonia allowed an estimation of the efficiency of nucleation scavenging process and the ability of South American biomass burning aerosol to act as CCN. Additionally, the impaction scavenging was simulated for the same aerosol population following a method based on the widely used concept of the efficiency of collision between a raindrop and an aerosol particle. DMPS and H-TDMA data available in the literature for biomass burning aerosol population in the region indicated the presence of a nearly hydrophobic fraction (on average, with specific hygroscopic parameter κ=0.04, and relative abundance of 73 %) and nearly hygroscopic fraction (κ=0.13, 27 %), externally mixed. The hygroscopic parameters and relative abundances of each hygroscopic group, as well as the weighted average specific hygroscopic parameter for the entire population κ=0.06, were used in calculations of aerosol activation and population mass and number concentration scavenged by nucleation. Results from both groups of simulations are presented and discussed. This work provides an insight on the importance of the inclusion of these processes in regional/global models. The authors thank the Sao Paulo Research Foundation FAPESP for supporting this work through the projects DR 2012/09934-3 and BEPE-DR 2013/02101-9.

Modeling the Electric Potential and Surface Charge Density Near Charged Thunderclouds

NASA Astrophysics Data System (ADS)

Neel, Matthew Stephen

2018-03-01

Thundercloud charge separation, or the process by which the bottom portion of a cloud gathers charge and the top portion of the cloud gathers the opposite charge, is still not thoroughly understood. Whatever the mechanism, though, a charge separation definitely exists and can lead to electrostatic discharge via cloud-to-cloud lightning and cloud-to-ground lightning. We wish to examine the latter form, in which upward leaders from Earth connect with downward leaders from the cloud to form a plasma channel and produce lightning. Much of the literature indicates that the lower part of a thundercloud becomes negatively charged while the upper part becomes positively charged via convective charging, although the opposite polarity can certainly exist along with various, complex intra-cloud currents. It is estimated that >90% of cloud-to-ground lightning is "negative lightning," or the flow of charges from the bottom of the cloud, while the remaining <10% of lightning strikes is "positive lightning," or the flow of charges from the top of the cloud. We wish to understand the electric potential surrounding charged thunderclouds as well as the resulting charge density on the surface of Earth below them. In this paper we construct a simple and adaptable model that captures the very basic features of the cloud/ground system and that exhibits conditions favorable for both forms of lightning. In this way, we provide a practical application of electrostatic dipole physics as well as the method of images that can serve as a starting point for further modeling and analysis by students.

How do changes in warm-phase microphysics affect deep convective clouds?

NASA Astrophysics Data System (ADS)

Chen, Qian; Koren, Ilan; Altaratz, Orit; Heiblum, Reuven H.; Dagan, Guy; Pinto, Lital

2017-08-01

Understanding aerosol effects on deep convective clouds and the derived effects on the radiation budget and rain patterns can largely contribute to estimations of climate uncertainties. The challenge is difficult in part because key microphysical processes in the mixed and cold phases are still not well understood. For deep convective clouds with a warm base, understanding aerosol effects on the warm processes is extremely important as they set the initial and boundary conditions for the cold processes. Therefore, the focus of this study is the warm phase, which can be better resolved. The main question is: How do aerosol-derived changes in the warm phase affect the properties of deep convective cloud systems? To explore this question, we used a weather research and forecasting (WRF) model with spectral bin microphysics to simulate a deep convective cloud system over the Marshall Islands during the Kwajalein Experiment (KWAJEX). The model results were validated against observations, showing similarities in the vertical profile of radar reflectivity and the surface rain rate. Simulations with larger aerosol loading resulted in a larger total cloud mass, a larger cloud fraction in the upper levels, and a larger frequency of strong updrafts and rain rates. Enlarged mass both below and above the zero temperature level (ZTL) contributed to the increase in cloud total mass (water and ice) in the polluted runs. Increased condensation efficiency of cloud droplets governed the gain in mass below the ZTL, while both enhanced condensational and depositional growth led to increased mass above it. The enhanced mass loading above the ZTL acted to reduce the cloud buoyancy, while the thermal buoyancy (driven by the enhanced latent heat release) increased in the polluted runs. The overall effect showed an increased upward transport (across the ZTL) of liquid water driven by both larger updrafts and larger droplet mobility. These aerosol effects were reflected in the larger ratio between the masses located above and below the ZTL in the polluted runs. When comparing the net mass flux crossing the ZTL in the clean and polluted runs, the difference was small. However, when comparing the upward and downward fluxes separately, the increase in aerosol concentration was seen to dramatically increase the fluxes in both directions, indicating the aerosol amplification effect of the convection and the affected cloud system properties, such as cloud fraction and rain rate.

A Targeted "Capture" and "Removal" Scavenger toward Multiple Pollutants for Water Remediation based on Molecular Recognition.

PubMed

Wang, Jie; Shen, Haijing; Hu, Xiaoxia; Li, Yan; Li, Zhihao; Xu, Jinfan; Song, Xiufeng; Zeng, Haibo; Yuan, Quan

2016-03-01

For the water remediation techniques based on adsorption, the long-standing contradictories between selectivity and multiple adsorbability, as well as between affinity and recyclability, have put it on weak defense amid more and more severe environment crisis. Here, a pollutant-targeting hydrogel scavenger is reported for water remediation with both high selectivity and multiple adsorbability for several pollutants, and with strong affinity and good recyclability through rationally integrating the advantages of multiple functional materials. In the scavenger, aptamers fold into binding pockets to accommodate the molecular structure of pollutants to afford perfect selectivity, and Janus nanoparticles with antibacterial function as well as anisotropic surfaces to immobilize multiple aptamers allow for simultaneously handling different kinds of pollutants. The scavenger exhibits high efficiencies in removing pollutants from water and it can be easily recycled for many times without significant loss of loading capacities. Moreover, the residual concentrations of each contaminant are well below the drinking water standards. Thermodynamic behavior of the adsorption process is investigated and the rate-controlling process is determined. Furthermore, a point of use device is constructed and it displays high efficiency in removing pollutants from environmental water. The scavenger exhibits great promise to be applied in the next generation of water purification systems.

The Teton-Yellowstone Tornado of 21 July 1987

NASA Technical Reports Server (NTRS)

Fujita, T. Theodore

1989-01-01

The Teton-Yellowstone Tornado, rated F4, crossed the Continental Divide at 3070 m, leaving behind a damage swath 39.2-km long and 2.5-km wide. A detailed damage analysis by using stereo-pair and color photos revealed the existence of four spinup swirl marks and 72 microburst outflows inside the damage area. The tornado was spawned by a mesocyclone that formed at the intersection of a mesohigh boundary and a warm front. The parent cloud of the tornado, tracked on eight infrared-temperature maps from GOES East and West, moved at 25 m s-1 and the number of cold temperature pixels below -60 C reached a distinct peak during the tornado time. Identified and tracked also are two warm spots enclosed inside the cold anvil cloud. On the basis of their identity and movement, an attempt was made to explain the cause of these spots as being the stratospheric cirrus clouds.

Weather Avoidance Guidelines for NASA Global Hawk High-Altitude UAS

NASA Technical Reports Server (NTRS)

Cecil, Daniel J.; Zipser, Edward J.; Velden, Chris; Monette, Sarah; Heymsfield, Gerry; Braun, Scott; Newman, Paul; Black, Pete; Black, Michael; Dunion, Jason

2014-01-01

NASA operates two Global Hawk unmanned aircraft systems for Earth Science research projects. In particular, they are used in the Hurricane and Severe Storm Sentinel (HS3) project during 2012, 2013, and 2014 to take measurements from the environment around tropical cyclones, and from directly above tropical cyclones. There is concern that strict adherence to the weather avoidance rules used in 2012 may sacrifice the ability to observe important science targets. We have proposed modifications to these weather avoidance rules that we believe will improve the ability to observe science targets without compromising aircraft safety. The previous guidelines, used in 2012, specified: Do not approach thunderstorms within 25 nm during flight at FL500 or below. When flying above FL500: Do not approach reported lightning within 25NM in areas where cloud tops are reported at FL500 or higher. Aircraft should maintain at least 10000 ft vertical separation from reported lightning if cloud tops are below FL500. No over-flight of cumulus tops higher than FL500. No flight into forecast or reported icing conditions. No flight into forecast or reported moderate or severe turbulence Based on past experience with high-altitude flights over tropical cyclones, we have recommended changing this guidance to: Do not approach thunderstorms within 25 nm during flight at FL500 or below. Aircraft should maintain at least 5000 ft vertical separation from significant convective cloud tops except: a) When cloud tops above FL500: In the event of reported significant lightning activity or indicators of significant overshooting tops, do not approach within 10-25 nm, depending on pilot discretion and advice from Mission Scientist. b) When cloud tops are below FL500, maintain 10000 ft separation from reported significant lightning or indicators of significant overshooting tops. No flight into forecasted or reported icing conditions. No flight into forecasted or reported moderate or severe turbulence The key changes have to do with overflight of high convective cloud tops and those producing lightning. Experience shows that most tropical oceanic convection (including that in tropical cyclones) is relatively gentle even if the cloud tops are quite high, and can be safely overflown. Exceptions are convective elements producing elevated lightning flash rates (more than just the occasional flash, which would trigger avoidance under the previous rules) and significant overshooting cloud tops.

Atmospheric Polarization Imaging with Variable Aerosols and Clouds

DTIC Science & Technology

2010-12-10

based aerosol sensors to study the effect of variable clouds and aerosols on skylight polarization in the 450 – 780 nm spectral region. Near the end the...of skylight (either below the cloud or in a cloud-free portion of the sky), but that they often do not alter the angle of polarization beneath the...polarization. A relationship also was developed for an initial model of how increasing surface albedo reduces the overhead skylight polarization. 15

Intercomparison of Microphysical Properties Derived from In-Situ Cloud and Remote Sensing Probes over the South East Atlantic Ocean

NASA Astrophysics Data System (ADS)

Miller, R.; McFarquhar, G. M.; Gupta, S.; Poellot, M.; O'Brien, J.; Delene, D. J.

2017-12-01

During the Observations of Aerosols Above Clouds and their Interactions (ORACLES) field campaigns, the NASA P3-Orion was equipped with in-situ probes measuring aerosol and cloud microphysical properties, while the NASA ER-2 was equipped with remote sensors retrieving cloud and aerosol quantities. During ORACLES 2017, the P-3 aircraft was equipped with two Clouds Droplet Probes (CDPs) sizing droplets with diameters (D) between 2 and 50µm. The two CDPs were mounted on pylons with different designs, the CDP on the newly designed left wing pylon positioned further below and ahead of the wing, whereas that on the right wing pylon directly below the wing. The P-3 was also equipped with a Cloud and Aerosol Spectrometer (CAS) sizing droplets with 0.51 µm < D < 50 µm, and three optical array probes: a 2D-stero probe (2DS) for 10 µm < D < 1280 µm; a High Volume Precipitation Sampler (HVPS-3), for 150 µm < D < 1.92 cm; and a Cloud Imaging Probe (CIP) for 25 µm < D < 1600 µm. In addition, a Phase Doppler Interferometer (PDI) for 0.5 µm < D < 2500 µm was included. In this presentation, the number distribution functions n(D) derived from different probes in their overlap ranges and bulk quantities, such as liquid water content (LWC), effective radius (re), total number concentration, extinction, skewness, dispersion and kurtosis derived by different probes over equivalent size ranges are compared. Additional comparison with bulk parameters (e.g., LWC measured by King and hot wire probes) and remotely sensed values are also made. The effect of the software package used to process the data is also examined by using two different packages, the National Center for Atmospheric Research Software for OAP Data Analysis (SODA2), and the University of Oklahoma/Illinois' Processing Software (UIOOPS) to process the optical array probe data. These intercomparisons, as a function of aircraft parameters and environmental conditions, help quantify uncertainties in measurements, improve our understanding of conditions under which the probes best function, assist in the development of a probe-independent best estimate of cloud microphysical parameters, and evaluate the quality of remote sensing retrievals. This in turn, will allow the use of these data sets to quantify cloud-aerosol relationships in the southeast Atlantic.

Impacts of the cloud structure's latitudinal variation on the general circulation of the Venus atmosphere as modeled by the LMD-GCM

NASA Astrophysics Data System (ADS)

Garate-Lopez, Itziar; Lebonnois, Sébastien

2017-04-01

A new simulation of Venus atmospheric circulation obtained with the LMD Venus GCM is described and the impact of cloud's latitudinal structure on the general circulation is analyzed. The model used here is based on that presented in Lebonnois et al. (2016). However, in the present simulation we consider the latitudinal variation of the cloud structure (Haus et al., 2014) both for the solar heating and to compute the infrared net-exchange rate matrix used in the radiative transfer module. The new cloud treatment affects mainly the balance in the angular momentum and the zonal wind distribution. Consequently, the agreement between the vertical profile of the modeled mean zonal wind and the profiles measured by different probes, is clearly improved from previous simulations in which zonal winds below the clouds were weak (roughly half the observed values). Moreover, the equatorial jet obtained at the base of the cloud deck is now more consistent with the observations. In Lebonnois et al. (2016) it was too strong compared to mid-latitudes, but in the present simulation the equatorial jet is less intense than the mid-latitude jets, in concordance with cloud-tracking measurements (Hueso et al., 2015). Since the atmospheric waves play a crucial role in the angular momentum budget of the Venus's atmospheric circulation, we analyze the wave activity by means of the Fast Fourier Transform technique studying the frequency spectrum of temperature, zonal and meridional wind fields. Modifications in the activity of the different types of waves present in the Venusian atmosphere compared to Lebonnois et al. (2016) are discussed, in terms of horizontal and vertical transport of the angular momentum by diurnal and semi-diurnal tides, barotropic and baroclinic waves, and Rossby and Kelvin type waves. Haus R., Kappel D. and Arnold G., 2014. Atmospheric thermal structure and cloud features in the southern hemisphere of Venus as retrieved from VIRTIS/VEX radiation measurements. Icarus 232, 232-248. Hueso R., Peralta J., Garate-Lopez I., et al., 2015. Six years of Venus winds at the upper cloud level from UV, visible and near infrared observations from VIRTIS on Venus express. Planet. Space Sci. 113-114, 78-99. Lebonnois S., Sugimoto N., and Gilli G., 2016. Wave analysis in the atmosphere of Venus below 100km altitude, simulated by the LMD Venus GCM. Icarus 278, 38-51.

A numerical study of aerosol effects on the dynamics and microphysics of a deep convective cloud in a continental environment

NASA Astrophysics Data System (ADS)

Cui, Zhiqiang; Carslaw, Kenneth S.; Yin, Yan; Davies, Stewart

2006-03-01

The effects of aerosols on a deep convective cloud in a midlatitude continental environment are studied using an axisymmetric cloud model with a sectional treatment of aerosol and hydrometeor microphysical processes. Simulations are conducted using observations from the Cooperative Convective Precipitation Experiments (CCOPE). The isolated cloud occurred in an environment with low wind shear and with relatively dry air in the midtroposphere and upper troposphere. By varying the concentration of aerosol particles in the accumulation mode within realistic limits for a continental environment, the simulated cloud exhibited different properties. The overall impact as the aerosol concentration increased is that (1) the cloud development was inhibited; (2) the precipitation was suppressed; (3) the maximum values of liquid water content decreased, but the maximum values of droplet number concentration increased before the dissipating stage; (4) a clear tendency was found for ice crystals to be larger and less numerous in the anvil cloud; and (5) there was a significant reduction of the inflow in the lower 2 km of the atmosphere. In the relatively dry environment in the midtroposphere, the latent heat changes associated with the Wegener-Bergeron-Findeisen mechanism played an important role in the upper part of the cloud at altitudes below the homogeneous freezing level. In particular, immersion freezing and latent heat release were much more rapid in the base simulation than in the increased aerosol simulation. Less latent heat release and insufficient inflow together impeded the development of the cloud with the higher aerosol loading. Our simulations suggest that continental clouds existing below the homogeneous freezing level could show an opposite response of cloud top height and anvil crystal concentrations to changes in aerosol to what has previously been reported for clouds ascending to higher levels.

Radiative Effects of African Dust and Smoke Observed from CERES and CALIOP Data

NASA Technical Reports Server (NTRS)

Yorks, John E.; McGill, Matt; Rodier, Sharon; Vaughan, Mark; Xu, Yongxiang; Hlavka, Dennis

2009-01-01

Cloud and aerosol effects have a significant impact on the atmospheric radiation budget in the Tropical Atlantic because of the spatial and temporal extent of desert dust and smoke from biomass burning in the atmosphere. The influences of African dust and smoke aerosols on cloud radiative properties over the Tropical Atlantic Ocean were analyzed for the month of July for three years (2006-2008) using collocated data collected by the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and Clouds and the Earth s Radiant Energy System (CERES) instruments on the CALIPSO and Aqua satellites. Aerosol layer height and type can be more accurately determined using CALIOP data, through parameters such as cloud and aerosol layer height, optical depth and depolarization ratio, than data from atmospheric imagers used in previous cloud-aerosol interaction studies. On average, clouds below 5 km had a daytime instantaneous shortwave (SW) radiative flux of 270.2 +/- 16.9 W/sq m and thin cirrus clouds had a SW radiative flux of 208.0 +/- 12.7 W/sq m. When dust aerosols interacted with clouds below 5 km, as determined from CALIPSO, the SW radiative flux decreased to 205.4 +/- 13.0 W/sq m. Similarly, smoke aerosols decreased the SW radiative flux of low clouds to a value of 240.0 +/- 16.6 W/sq m. These decreases in SW radiative flux were likely attributed to the aerosol layer height and changes in cloud microphysics. CALIOP lidar observations, which more accurately identify aerosol layer height than passive instruments, appear essential for better understanding of cloud-aerosol interactions, a major uncertainty in predicting the climate system.

Intercomparison of vertical structure of storms revealed by ground-based (NMQ) and spaceborne radars (CloudSat-CPR and TRMM-PR).

PubMed

Fall, Veronica M; Cao, Qing; Hong, Yang

2013-01-01

Spaceborne radars provide great opportunities to investigate the vertical structure of clouds and precipitation. Two typical spaceborne radars for such a study are the W-band Cloud Profiling Radar (CPR) and Ku-band Precipitation Radar (PR), which are onboard NASA's CloudSat and TRMM satellites, respectively. Compared to S-band ground-based radars, they have distinct scattering characteristics for different hydrometeors in clouds and precipitation. The combination of spaceborne and ground-based radar observations can help in the identification of hydrometeors and improve the radar-based quantitative precipitation estimation (QPE). This study analyzes the vertical structure of the 18 January, 2009 storm using data from the CloudSat CPR, TRMM PR, and a NEXRAD-based National Mosaic and Multisensor QPE (NMQ) system. Microphysics above, within, and below the melting layer are studied through an intercomparison of multifrequency measurements. Hydrometeors' type and their radar scattering characteristics are analyzed. Additionally, the study of the vertical profile of reflectivity (VPR) reveals the brightband properties in the cold-season precipitation and its effect on the radar-based QPE. In all, the joint analysis of spaceborne and ground-based radar data increases the understanding of the vertical structure of storm systems and provides a good insight into the microphysical modeling for weather forecasts.

Intercomparison of Vertical Structure of Storms Revealed by Ground-Based (NMQ) and Spaceborne Radars (CloudSat-CPR and TRMM-PR)

PubMed Central

Fall, Veronica M.; Hong, Yang

2013-01-01

Spaceborne radars provide great opportunities to investigate the vertical structure of clouds and precipitation. Two typical spaceborne radars for such a study are the W-band Cloud Profiling Radar (CPR) and Ku-band Precipitation Radar (PR), which are onboard NASA's CloudSat and TRMM satellites, respectively. Compared to S-band ground-based radars, they have distinct scattering characteristics for different hydrometeors in clouds and precipitation. The combination of spaceborne and ground-based radar observations can help in the identification of hydrometeors and improve the radar-based quantitative precipitation estimation (QPE). This study analyzes the vertical structure of the 18 January, 2009 storm using data from the CloudSat CPR, TRMM PR, and a NEXRAD-based National Mosaic and Multisensor QPE (NMQ) system. Microphysics above, within, and below the melting layer are studied through an intercomparison of multifrequency measurements. Hydrometeors' type and their radar scattering characteristics are analyzed. Additionally, the study of the vertical profile of reflectivity (VPR) reveals the brightband properties in the cold-season precipitation and its effect on the radar-based QPE. In all, the joint analysis of spaceborne and ground-based radar data increases the understanding of the vertical structure of storm systems and provides a good insight into the microphysical modeling for weather forecasts. PMID:24459424

Copernicus observations of C I: pressures and carbon abundances in diffuse interstellar clouds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jenkins, E.B.; Jura, M.; Loewenstein, M.

1983-07-01

Using the Copernicus satellite, we observed ultraviolet absorption lines of interstellar neutral carbon atoms toward 27 stars. In addition to deriving column densities of C I (both in its ground state and the two excited fine-structure levels), we used our equivalent widths to revise the f-values of some of the C I transitions measured by other investigators. We also observed H/sub 2/ from the J = 4 level so that we could compare the rotational excitation of H/sub 2/ with the fine-structure excitation of C I. From the amount of fine-structure excitation of C I in each case, we havemore » derived information on the thermal gas pressures within the diffuse clouds. Most clouds have p/k between 10/sup 3/ cm/sup -3/ K and 10/sup 4/ cm/sup -3/ K, but we found that at least 6% of the C I-bearing material is at p/k>10/sup 4/ cm/sup -3/ K, and one-third of the gas has upper limits for pressure below 10/sup 3/ cm/sup -3/ K, assuming temperatures are not appreciably below 20 K. An analysis of radial velocities for the absorption lines showed no distinctive trends for the kinematics of high- or low-pressure gas components. From the apparent lack of acceleration of high-pressure clouds, we conclude that it is unlikely that streaming intercloud material is causing significant ram pressurization. We have compared our results with the predictions for pressure fluctuations caused by supernova explosions in the theory of McKee and Ostriker.« less

Laboratory chemistry and stratospheric clouds

NASA Technical Reports Server (NTRS)

Molina, Mario J.

1989-01-01

Results are presented from laboratory experiments on the chemistry of ice particles to study the role of HCl and ClONO2 from CFCs in stratospheric ozone depletion over Antarctica. It is found that gaseous HCl is scavenged with high efficiency by the ice and the gas phase chlorine nitrate may react with the HCL-containing ice to produce Cl2. Also, consideration is given ot the behavior of solid nitric acid trihydrate and sulfuric acid aerosols.

Cirrus clouds as seen by the CALIPSO satellite and ECHAM-HAM global climate model

NASA Astrophysics Data System (ADS)

Gasparini, Blaz; Meyer, Angela; Neubauer, David; Münch, Steffen; Lohmann, Ulrike

2017-04-01

Ice clouds impact the planetary energy balance and upper tropospheric water vapour transport and are therefore relevant for climate. In this study ice clouds at temperatures below -40°C simulated by the ECHAM-HAM global climate model are compared to CALIPSO/CALIOP satellite data. The model reproduces well the mean occurrence of ice clouds, while the ice water path, ice crystal radius, cloud optical depth and extinction are overestimated in terms of annual means and temperature dependent frequency histograms. Two distinct types of cirrus clouds are found: in-situ formed cirrus dominating at temperatures below -60°C and liquid-origin cirrus, dominating at temperatures warmer than -55°C. The latter form in anvils of deep convective clouds or by glaciation of mixed-phase clouds. They are associated with ice water contents of up to 0.1 g m-3 and extinctions of up to 0.1 km-1, while the in-situ formed cirrus are optically thinner and contain at least an order of magnitude less ice. The ice cloud properties do not differ significantly between the southern and the northern hemisphere. In-situ formed ice clouds are further divided into homogeneously and heterogeneously nucleated ones. The simulated liquid-origin ice crystals mainly form in convective outflow in large number concentrations, similar to in-situ homogeneously nucleated ice crystals. On the contrary, heterogeneously nucleated ice crystals are associated with smaller number concentrations. However, ice crystal aggregation and depositional growth smooth the differences between several formation mechanisms making the attribution to a specific ice nucleation mechanism challenging.

Daytime variations of absorbing aerosols above clouds in the southeast Atlantic

NASA Astrophysics Data System (ADS)

Chang, Y. Y.; Christopher, S. A.

2016-12-01

The daytime variation of aerosol optical depth (AOD) above maritime stratocumulus clouds in the southeast Atlantic is investigated by merging geostationary data from the Spinning Enhanced Visible and Infrared Imager (SEVIRI) with NASA A-Train data sets. SEVIRI's 15-minute above cloud AOD and below aerosol cloud optical depth (COD) retrieval provides the opportunity to assess their direct radiative forcing using actual cloud and aerosol properties instead of using fixed values from polar-orbiting measurements. The impact of overlying aerosols above clouds on the cloud mask products are compared with active spaceborne lidar to examine the performance of the product. Uncertainty analyses of aerosol properties on the estimation of optical properties and radiative forcing are addressed.

Detection of supercooled liquid water-topped mixed-phase clouds >from shortwave-infrared satellite observations

NASA Astrophysics Data System (ADS)

NOH, Y. J.; Miller, S. D.; Heidinger, A. K.

2015-12-01

Many studies have demonstrated the utility of multispectral information from satellite passive radiometers for detecting and retrieving the properties of cloud globally, which conventionally utilizes shortwave- and thermal-infrared bands. However, the satellite-derived cloud information comes mainly from cloud top or represents a vertically integrated property. This can produce a large bias in determining cloud phase characteristics, in particular for mixed-phase clouds which are often observed to have supercooled liquid water at cloud top but a predominantly ice phase residing below. The current satellite retrieval algorithms may report these clouds simply as supercooled liquid without any further information regarding the presence of a sub-cloud-top ice phase. More accurate characterization of these clouds is very important for climate models and aviation applications. In this study, we present a physical basis and preliminary results for the algorithm development of supercooled liquid-topped mixed-phase cloud detection using satellite radiometer observations. The detection algorithm is based on differential absorption properties between liquid and ice particles in the shortwave-infrared bands. Solar reflectance data in narrow bands at 1.6 μm and 2.25 μm are used to optically probe below clouds for distinction between supercooled liquid-topped clouds with and without an underlying mixed phase component. Varying solar/sensor geometry and cloud optical properties are also considered. The spectral band combination utilized for the algorithm is currently available on Suomi NPP Visible/Infrared Imaging Radiometer Suite (VIIRS), Himawari-8 Advanced Himawari Imager (AHI), and the future GOES-R Advance Baseline Imager (ABI). When tested on simulated cloud fields from WRF model and synthetic ABI data, favorable results were shown with reasonable threat scores (0.6-0.8) and false alarm rates (0.1-0.2). An ARM/NSA case study applied to VIIRS data also indicated promising potential of the algorithm.

A Comprehensive Two-moment Warm Microphysical Bulk Scheme :

NASA Astrophysics Data System (ADS)

Caro, D.; Wobrock, W.; Flossmann, A.; Chaumerliac, N.

The microphysic properties of gaz, aerosol particles, and hydrometeors have impli- cations at local scale (precipitations, pollution peak,..), at regional scale (inundation, acid rains,...), and also, at global scale (radiative forcing,...). So, a multi-scale study is necessary to understand and forecast in a good way meteorological phenomena con- cerning clouds. However, it cannot be carried with detailed microphysic model, on account of computers limitations. So, microphysical bulk schemes have to estimate the n´ large scale z properties of clouds due to smaller scale processes and charac- teristics. So, the development of such bulk scheme is rather important to go further in the knowledge of earth climate and in the forecasting of intense meteorological phenomena. Here, a quasi-spectral microphysic warm scheme has been developed to predict the concentrations and mixing ratios of aerosols, cloud droplets and raindrops. It considers, explicitely and analytically, the nucleation of droplets (Abdul-Razzak et al., 2000), condensation/evaporation (Chaumerliac et al., 1987), the breakup and collision-coalescence processes with the Long (1974) Ss kernels and the Berry and ´ Reinhardt (1974) Ss autoconversion parameterization, but also, the aerosols and gaz ´ scavenging. First, the parameterization has been estimated in the simplest dynamic framework of an air parcel model, with the results of the detailed scavenging model, DESCAM (Flossmann et al., 1985). Then, it has been tested, in the dynamic frame- work of a kinematic model (Szumowski et al., 1998) dedicated to the HaRP cam- paign (Hawaiian Rainband Project, 1990), with the observations and with the results of the two dimensional detailed microphysic scheme, DESCAM 2-D (Flossmann et al., 1988), implement in the CLARK model (Clark and Farley, 1984).

CloudSat Image of Tropical Thunderstorms Over Africa

NASA Technical Reports Server (NTRS)

2006-01-01

[figure removed for brevity, see original site] Figure 1

CloudSat image of a horizontal cross-section of tropical clouds and thunderstorms over east Africa. The red colors are indicative of highly reflective particles such as water (rain) or ice crystals, which the blue indicates thinner clouds (such as cirrus). The flat green/blue lines across the bottom represent the ground signal. The vertical scale on the CloudS at Cloud Profiling Radar image is approximately 30 kilometers (19 miles). The brown line below the image indicates the relative elevation of the land surface. The inset image shows the CloudSat track relative to a Moderate Resolution Imaging Spectroradiometer (MODIS) visible image taken at nearly the same time.

Efficacy of the ejector flow-meter. A scavenging device for anaesthetic gases.

PubMed

Obel, D; Jørgensen, S; Ferguson, A; Frandsen, K

1985-01-01

Measurements of air concentrations of nitrous oxide and halothane in the breathing zone of the anaesthetist and the operating-room nurse were carried out during inhalation anaesthesia with a Mapleson D system. Gas removal was performed from inside the breathing system at the same rate as that of the fresh gas inflow by means of an ejector flow-meter. The concentrations of nitrous oxide and halothane were maintained below the Danish Threshold Limit Values of 100 and 5 parts per million, respectively, by using this type of scavenging. When these anaesthetics were used simultaneously, the reduced Threshold Limit Values were not exceeded during endotracheal anaesthesia.

A Comprehensive Analysis about the Aerosol's Albedo Effect at SGP Site

NASA Astrophysics Data System (ADS)

Qiu, Y.

2016-12-01

Positive relationship between cloud droplet effective radius (DER) and aerosol amount has been found in early studies based on limited observation samples over the Southern Great Plain (SGP) in Oklahoma of US. Using 8-year cloud and aerosol observations by the Atmospheric Radiation Measurement (ARM) program, We here carry out a comprehensive analysis about the seasonal variation of aerosol effect on cloud DER at the SGP site. It shows that cloud DER is larger under polluted conditions than that under clean conditions in all seasons other than summer, indicating a positive aerosol first indirect effect (also called Twomey effect) only in summer. Note that the pollution conditions are classified based on the surface observation of aerosol optical depth (AOD). Different factors that influence the AOD-DER relationship have been shown in many early studies, we analyze the potential effects of various factors on the AOD-DER relationship and find that cloud types and precipitable water vapor (PWV) play more important roles.We limit our study to clouds with bases below 1 km and tops about 3 km which make sure what we study are low liquid clouds. The correlation between AOD and DER is negative in all seasons in lower one-third of PWV, and positive in other seasons except negative in summer under higher one-third of PWV. It suggests the increase of PWV could promote the relationship of AOD-Re from negative to positive. Restricting NCEP reanalysis data to limit the variation in the meteorological conditions, the correlation of AOD-Re is -0.3054 in lower PWV and -0.2327 in higher PWV( p<0.05 in two cases), which shows that the increase of PWV can weaken the Twomey effect.

The Cloud Ice Mountain Experiment (CIME) 1998: experiment overview and modelling of the microphysical processes during the seeding by isentropic gas expansion

NASA Astrophysics Data System (ADS)

Wobrock, Wolfram; Flossmann, Andrea I.; Monier, Marie; Pichon, Jean-Marc; Cortez, Laurent; Fournol, Jean-François; Schwarzenböck, Alfons; Mertes, Stephan; Heintzenberg, Jost; Laj, Paolo; Orsi, Giordano; Ricci, Loretta; Fuzzi, Sandro; Brink, Harry Ten; Jongejan, Piet; Otjes, René

The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H 2O 2 and NH 3 in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud. In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron-Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron-Findeisen process when acting also in natural clouds.

Biogenic Aerosols – Effects on Climate and Clouds. Cloud Optical Depth (COD) Sensor Three-Waveband Spectrally-Agile Technique (TWST) Field Campaign Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Niple, E. R.; Scott, H. E.

2016-04-01

This report describes the data collected by the Three-Waveband Spectrally-agile Technique (TWST) sensor deployed at Hyytiälä, Finland from 16 July to 31 August 2014 as a guest on the Biogenic Aerosols Effects on Climate and Clouds (BAECC) campaign. These data are currently available from the Atmospheric Radiation Measurement (ARM) Data Archive website and consists of Cloud Optical Depth (COD) measurements for the clouds directly overhead approximately every second (with some dropouts described below) during the daylight periods. A good range of cloud conditions were observed from clear sky to heavy rainfall.

Aerosol-cloud feedbacks in a turbulent environment: Laboratory measurements representative of conditions in boundary layer clouds

NASA Astrophysics Data System (ADS)

Cantrell, W. H.; Chandrakar, K. K.; Karki, S.; Kinney, G.; Shaw, R.

2017-12-01

Many of the climate impacts of boundary layer clouds are modulated by aerosol particles. As two examples, their interactions with incoming solar and upwelling terrestrial radiation and their propensity for precipitation are both governed by the population of aerosol particles upon which the cloud droplets formed. In turn, clouds are the primary removal mechanism for aerosol particles smaller than a few micrometers and larger than a few nanometers. Aspects of these interconnected phenomena are known in exquisite detail (e.g. Köhler theory), but other parts have not been as amenable to study in the laboratory (e.g. scavenging of aerosol particles by cloud droplets). As a complicating factor, boundary layer clouds are ubiquitously turbulent, which introduces fluctuations in the water vapor concentration and temperature, which govern the saturation ratio which mediates aerosol-cloud interactions. We have performed laboratory measurements of aerosol-cloud coupling and feedbacks, using Michigan Tech's Pi Chamber (Chang et al., 2016). In conditions representative of boundary layer clouds, our data suggest that the lifetime of most interstitial particles in the accumulation mode is governed by cloud activation - particles are removed from the Pi Chamber when they activate and settle out of the chamber as cloud droplets. As cloud droplets are removed, these interstitial particles activate until the initially polluted cloud cleans itself and all particulates are removed from the chamber. At that point, the cloud collapses. Our data also indicate that smaller particles, Dp < ˜ 20 nm are not activated, but are instead removed through diffusion, enhanced by the fact that droplets are moving relative to the suspended aerosol. I will discuss results from both warm (i.e. liquid water only) and mixed phase clouds, showing that cloud and aerosol properties are coupled through fluctuations in the supersaturation, and that threshold behaviors can be defined through the use of the Dämkohler number, the ratio of the characteristic turbulence timescale to the cloud's microphysical response time. Chang, K., et al., 2016. A laboratory facility to study gas-aerosol-cloud interactions in a turbulent environment: The Π Chamber. Bull. Amer. Meteor. Soc., doi:10.1175/BAMS-D-15-00203.1

Analysis of Cloud-resolving Simulations of a Tropical Mesoscale Convective System Observed during TWP-ICE: Vertical Fluxes and Draft Properties in Convective and Stratiform Regions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mrowiec, Agnieszka A.; Rio, Catherine; Fridlind, Ann

2012-10-02

We analyze three cloud-resolving model simulations of a strong convective event observed during the TWP-ICE campaign, differing in dynamical core, microphysical scheme or both. Based on simulated and observed radar reflectivity, simulations roughly reproduce observed convective and stratiform precipitating areas. To identify the characteristics of convective and stratiform drafts that are difficult to observe but relevant to climate model parameterization, independent vertical wind speed thresholds are calculated to capture 90% of total convective and stratiform updraft and downdraft mass fluxes. Convective updrafts are fairly consistent across simulations (likely owing to fixed large-scale forcings and surface conditions), except that hydrometeor loadingsmore » differ substantially. Convective downdraft and stratiform updraft and downdraft mass fluxes vary notably below the melting level, but share similar vertically uniform draft velocities despite differing hydrometeor loadings. All identified convective and stratiform downdrafts contain precipitation below ~10 km and nearly all updrafts are cloudy above the melting level. Cold pool properties diverge substantially in a manner that is consistent with convective downdraft mass flux differences below the melting level. Despite differences in hydrometeor loadings and cold pool properties, convective updraft and downdraft mass fluxes are linearly correlated with convective area, the ratio of ice in downdrafts to that in updrafts is ~0.5 independent of species, and the ratio of downdraft to updraft mass flux is ~0.5-0.6, which may represent a minimum evaporation efficiency under moist conditions. Hydrometeor loading in stratiform regions is found to be a fraction of hydrometeor loading in convective regions that ranges from ~10% (graupel) to ~90% (cloud ice). These findings may lead to improved convection parameterizations.« less

Crank case scavenging of a two-stroke-cycle engine

NASA Technical Reports Server (NTRS)

Holm, Otto

1928-01-01

Experiments with a two-stroke-cycle, crank case scavenging engine. Effect of systematic variation of the height of the scavenge and exhaust ports on the scavenging, as determined by gas analysis. The best results were obtained under conditions differing from the usual ones.

Optical properties of marine stratocumulus clouds modified by ships

DOE Office of Scientific and Technical Information (OSTI.GOV)

King, M.D.; Radke, L.F.; Hobbs, P.V.

1993-02-20

The angular distribution of scattered radiation deep within a cloud layer was measured in marine stratocumulus clouds modified by the emissions from ships. These observations, obtained at 13 discrete wavelengths between 0.5 and 2.3 [mu]m, were acquired as the University of Washington C-131A aircraft flew through a pair of roughly parallel ship track signatures produced in clouds off the coast of southern California on July 10, 1987. In the first of these ship tracks, the nadir (upwelling) intensity increased from 40 to 110 W m[sup [minus]2] [mu]m[sup [minus]1] sr[sup [minus]1] at 0.744 [mu]m. The second ship track produced a lessmore » dramatic, but more uniform, increase in the upwelling intensity. In contrast, the nadir intensity at 2.20 [mu]m decreased from 1 to 0.13 W m[sup [minus]2] [mu]m[sup [minus]1] sr[sup [minus]1] in the first ship track and to 0.6 W m[sup [minus]2] [mu]m[sup [minus]1] sr[sup [minus]1] in the second ship track. The relative angular distribution of the intensity field at each wavelength was used to determine the similarity parameter, and hence single scattering albedo, of the cloud using the diffusion domain method. Besides the spectral similarity parameter, these measurements provide a good estimate of the optical depth of the cloud layer both above and below the aircraft. Results of this analysis are presented for a 120-km section of marine stratocumulus cloud including both ship tracks. This analysis shows that the total optical thickness of the cloud layer increased in the ship tracks, in contrast to the similarity parameter which decreased. The decrease in absorption was a direct consequence of the reduction in cloud droplet size that occurred within the ship tracks. 34 refs., 11 figs., 2 tabs.« less

Odd cloud in the Ross Sea, Antarctica

NASA Technical Reports Server (NTRS)

2002-01-01

On January 28, 2002, MODIS captured this image of an interesting cloud formation in the boundary waters between Antarctica's Ross Sea and the Southern Ocean. A dragon? A snake? A fish? No, but it is an interesting example of the atmospheric physics of convection. The 'eye' of this dragon-looking cloud is likely a small spot of convection, the process by which hot moist air rises up into the atmosphere, often producing big, fluffy clouds as moisture in the air condenses as rises into the colder parts of the atmosphere. A false color analysis that shows different kinds of clouds in different colors reveals that the eye is composed of ice crystals while the 'body' is a liquid water cloud. This suggests that the eye is higher up in the atmosphere than the body. The most likely explanation for the eye feature is that the warm, rising air mass had enough buoyancy to punch through the liquid water cloud. As a convective parcel of air rises into the atmosphere, it pushes the colder air that is higher up out of its way. That cold air spills down over the sides of the convective air mass, and in this case has cleared away part of the liquid cloud layer below in the process. This spilling over of cold air from higher up in the atmosphere is the reason why thunderstorms are often accompanied by a cool breeze. Credit: Jacques Descloitres, MODIS Land Rapid Response Team, NASA/GSFC

Laser-filament-induced snow formation in a subsaturated zone in a cloud chamber: experimental and theoretical study.

PubMed

Ju, Jingjing; Sun, Haiyi; Sridharan, Aravindan; Wang, Tie-Jun; Wang, Cheng; Liu, Jiansheng; Li, Ruxin; Xu, Zhizhan; Chin, See Leang

2013-12-01

1 kHz, 2 mJ, 45 fs, 800 nm laser pulses were fired into a laboratory diffusion cloud chamber through a subsaturated zone (relative humidity ∼73%, T ∼ 4.3 °C). After 60 min of laser irradiation, an oval-shaped snow pile was observed right below the filament center and weighed ∼12.0 mg. The air current velocity at the edge of the vortices was estimated to be ∼16.5 cm/s. Scattering scenes recorded from the side show that filament-induced turbulence were formed inside the cloud chamber with two vortices below the filament. Two-dimensional simulations of the air flow motion in two cross sections of the cloud chamber confirm that the turbulent vortices exist below the filament. Based upon this simulation, we deduce that the vortices indeed have a three-dimensional elliptical shape. Hence, we propose that inside vortices where the humidity was supersaturated or saturated the condensation nuclei, namely, HNO(3), N(2)(+), O(2)(+) and other aerosols and impurities, were activated and grew in size. Large-sized particles would eventually be spun out along the fast moving direction towards the cold plate and formed an oval-shaped snow pile at the end.

Lightning data study in conjunction with geostationary satellite data

NASA Technical Reports Server (NTRS)

Auvine, Brian; Martin, David W.

1987-01-01

During the summer of 1985, cloud-to-ground stroke lightning were collected. Thirty minute samples of lightning were compared with GOES IR fractional cold cloud coverage computed for three temperature thresholds (213, 243, and 273 K) twice daily (morning and evening). It was found that satellite measurements of cold cloud have a relationship to the flashrate and, in a more limited way, to the polarity and numbers of return strokes. Results varied little by location. Lightning, especially positive strokes, was found to be correlated with fractional cloud coverage, especially for clouds at or below 213 K. Other data and correlations are discussed.

Thermodynamic and cloud parameter retrieval using infrared spectral data

NASA Technical Reports Server (NTRS)

Zhou, Daniel K.; Smith, William L., Sr.; Liu, Xu; Larar, Allen M.; Huang, Hung-Lung A.; Li, Jun; McGill, Matthew J.; Mango, Stephen A.

2005-01-01

High-resolution infrared radiance spectra obtained from near nadir observations provide atmospheric, surface, and cloud property information. A fast radiative transfer model, including cloud effects, is used for atmospheric profile and cloud parameter retrieval. The retrieval algorithm is presented along with its application to recent field experiment data from the NPOESS Airborne Sounding Testbed - Interferometer (NAST-I). The retrieval accuracy dependence on cloud properties is discussed. It is shown that relatively accurate temperature and moisture retrievals can be achieved below optically thin clouds. For optically thick clouds, accurate temperature and moisture profiles down to cloud top level are obtained. For both optically thin and thick cloud situations, the cloud top height can be retrieved with an accuracy of approximately 1.0 km. Preliminary NAST-I retrieval results from the recent Atlantic-THORPEX Regional Campaign (ATReC) are presented and compared with coincident observations obtained from dropsondes and the nadir-pointing Cloud Physics Lidar (CPL).

Boundary-layer cumulus over heterogeneous landscapes: A subgrid GCM parameterization. Final report, December 1991--November 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stull, R.B.; Tripoli, G.

1996-01-08

The authors developed single-column parameterizations for subgrid boundary-layer cumulus clouds. These give cloud onset time, cloud coverage, and ensemble distributions of cloud-base altitudes, cloud-top altitudes, cloud thickness, and the characteristics of cloudy and clear updrafts. They tested and refined the parameterizations against archived data from Spring and Summer 1994 and 1995 intensive operation periods (IOPs) at the Southern Great Plains (SGP) ARM CART site near Lamont, Oklahoma. The authors also found that: cloud-base altitudes are not uniform over a heterogeneous surface; tops of some cumulus clouds can be below the base-altitudes of other cumulus clouds; there is an overlap regionmore » near cloud base where clear and cloudy updrafts exist simultaneously; and the lognormal distribution of cloud sizes scales to the JFD of surface layer air and to the shape of the temperature profile above the boundary layer.« less

Development of methods for inferring cloud thickness and cloud-base height from satellite radiance data

NASA Technical Reports Server (NTRS)

Smith, William L., Jr.; Minnis, Patrick; Alvarez, Joseph M.; Uttal, Taneil; Intrieri, Janet M.; Ackerman, Thomas P.; Clothiaux, Eugene

1993-01-01

Cloud-top height is a major factor determining the outgoing longwave flux at the top of the atmosphere. The downwelling radiation from the cloud strongly affects the cooling rate within the atmosphere and the longwave radiation incident at the surface. Thus, determination of cloud-base temperature is important for proper calculation of fluxes below the cloud. Cloud-base altitude is also an important factor in aircraft operations. Cloud-top height or temperature can be derived in a straightforward manner using satellite-based infrared data. Cloud-base temperature, however, is not observable from the satellite, but is related to the height, phase, and optical depth of the cloud in addition to other variables. This study uses surface and satellite data taken during the First ISCCP Regional Experiment (FIRE) Phase-2 Intensive Field Observation (IFO) period (13 Nov. - 7 Dec. 1991, to improve techniques for deriving cloud-base height from conventional satellite data.

Peering through Jupiter’s clouds with radio spectral imaging

NASA Astrophysics Data System (ADS)

de Pater, Imke; Sault, R. J.; Butler, Bryan; DeBoer, David; Wong, Michael H.

2016-06-01

Radio wavelengths can probe altitudes in Jupiter’s atmosphere below its visible cloud layers. We used the Very Large Array to map this unexplored region down to ~8 bar, ~100 kilometers below the visible clouds. Our maps reveal a dynamically active planet at pressures less than 2 to 3 bar. A radio-hot belt exists, consisting of relatively transparent regions (a low ammonia concentration, NH3 being the dominant source of opacity) probing depths to over ~8 bar; these regions probably coincide with 5-micrometer hot spots. Just to the south we distinguish an equatorial wave, bringing up ammonia gas from Jupiter’s deep atmosphere. This wave has been theorized to produce the 5-micrometer hot spots; we observed the predicted radio counterpart of such hot spots.

Environmental Effects of an Impact-Generated Dust Cloud: Implications for the Cretaceous-Tertiary Extinctions

NASA Astrophysics Data System (ADS)

Pollack, James B.; Toon, Owen B.; Ackerman, Thomas P.; McKay, Christopher P.; Turco, Richard P.

1983-01-01

A model of the evolution and radiative effects of a debris cloud from a hypothesized impact event at the Cretaceous-Tertiary boundary suggests that the cloud could have reduced the amount of light at the earth's surface below that required for photosynthesis for several months and, for a somewhat shorter interval, even below that needed for many animals to see. For 6 months to 1 year, the surface would cool; the oceans would cool only a few degrees Celsius at most, but the continents might cool a maximum of 40 Kelvin. Extinctions in the ocean may have been caused primarily by the temporary cessation of photosynthesis, but those on land may have been primarily induced by a combination of lowered temperatures and reduced light.

Environmental effects of an impact-generated dust cloud - Implications for the Cretaceous-Tertiary extinctions

NASA Technical Reports Server (NTRS)

Pollack, J. B.; Toon, O. B.; Ackerman, T. P.; Mckay, C. P.; Turco, R. P.

1983-01-01

A model of the evolution and radiative effects of a debris cloud from a hypothesized impact event at the Cretaceous-Tertiary boundary suggests that the cloud could have reduced the amount of light at the earth's surface below that required for photosynthesis for several months and, for a somewhat shorter interval, even below that needed for many animals to see. For 6 months to 1 year, the surface would cool; the oceans could cool only a few degrees Celsius at most, but the continents might cool a maximum of 40 Kelvin. Extinctions in the ocean may have been caused primarily by the temporary cessation of photosynthesis, but those on land may have been primarily induced by a combination of lowered temperatures and reduced light.

The Fate of Saharan Dust Across the Atlantic and Implications for a Central American Dust Barrier

NASA Technical Reports Server (NTRS)

Nowottnick, E.; Colarco, P.; da Silva, A.; Hlavka, D.; McGill, M.

2011-01-01

Saharan dust was observed over the Caribbean basin during the summer 2007 NASA Tropical Composition, Cloud, and Climate Coupling (TC4) field experiment. Airborne Cloud Physics Lidar (CPL) and satellite observations from MODIS suggest a barrier to dust transport across Central America into the eastern Pacific. We use the NASA GEOS-5 atmospheric transport model with online aerosol tracers to perform simulations of the TC4 time period in order to understand the nature of this barrier. Our simulations are driven by the Modem Era Retrospective-Analysis for Research and Applications (MERRA) meteorological analyses. We evaluate our baseline simulated dust distributions using MODIS and CALIOP satellite and ground-based AERONET sun photometer observations. GEOS-5 reproduces the observed location, magnitude, and timing of major dust events, but our baseline simulation does not develop as strong a barrier to dust transport across Central America as observations suggest. Analysis of the dust transport dynamics and lost processes suggest that while both mechanisms play a role in defining the dust transport barrier, loss processes by wet removal of dust are about twice as important as transport. Sensitivity analyses with our model showed that the dust barrier would not exist without convective scavenging over the Caribbean. The best agreement between our model and the observations was obtained when dust wet removal was parameterized to be more aggressive, treating the dust as we do hydrophilic aerosols.

Simulations of Variability and Waves at Cloud Altitudes Using a Venus Middle Atmosphere General Circulation Model

NASA Astrophysics Data System (ADS)

Parish, H. F.; Mitchell, J.

2017-12-01

We have developed a Venus general circulation model, the Venus Middle atmosphere Model (VMM), to simulate the atmosphere from just below the cloud deck 40 km altitude to around 100 km altitude. Our primary goal is to assess the influence of waves on the variability of winds and temperatures observed around Venus' cloud deck. Venus' deep atmosphere is not simulated directly in the VMM model, so the effects of waves propagating upwards from the lower atmosphere is represented by forcing at the lower boundary of the model. Sensitivity tests allow appropriate amplitudes for the wave forcing to be determined by comparison with Venus Express and probe measurements and allow the influence of waves on the cloud-level atmosphere to be investigated. Observations at cloud altitudes are characterized by waves with a wide variety of periods and wavelengths, including gravity waves, thermal tides, Rossby waves, and Kelvin waves. These waves may be generated within the cloud deck by instabilities, or may propagate up from the deep atmosphere. Our development of the VMM is motivated by the fact that the circulation and dynamics between the surface and the cloud levels are not well measured and wind velocities below 40 km altitude cannot be observed remotely, so we focus on the dynamics at cloud levels and above. Initial results from the VMM with a simplified radiation scheme have been validated by comparison with Pioneer Venus and Venus Express observations and show reasonable agreement with the measurements.

Cloud Inhomogeneity from MODIS

NASA Technical Reports Server (NTRS)

Oreopoulos, Lazaros; Cahalan, Robert F.

2004-01-01

Two full months (July 2003 and January 2004) of MODIS Atmosphere Level-3 data from the Terra and Aqua satellites are analyzed in order to characterize the horizontal variability of cloud optical thickness and water path at global scales. Various options to derive cloud variability parameters are discussed. The climatology of cloud inhomogeneity is built by first calculating daily parameter values at spatial scales of l degree x 1 degree, and then at zonal and global scales, followed by averaging over monthly time scales. Geographical, diurnal, and seasonal changes of inhomogeneity parameters are examined separately for the two cloud phases, and separately over land and ocean. We find that cloud inhomogeneity is weaker in summer than in winter, weaker over land than ocean for liquid clouds, weaker for local morning than local afternoon, about the same for liquid and ice clouds on a global scale, but with wider probability distribution functions (PDFs) and larger latitudinal variations for ice, and relatively insensitive to whether water path or optical thickness products are used. Typical mean values at hemispheric and global scales of the inhomogeneity parameter nu (roughly the mean over the standard deviation of water path or optical thickness), range from approximately 2.5 to 3, while for the inhomogeneity parameter chi (the ratio of the logarithmic to linear mean) from approximately 0.7 to 0.8. Values of chi for zonal averages can occasionally fall below 0.6 and for individual gridpoints below 0.5. Our results demonstrate that MODIS is capable of revealing significant fluctuations in cloud horizontal inhomogenity and stress the need to model their global radiative effect in future studies.

A sensitivity study of diffusional mass transfer of gases in tropical storm hydrometeors

NASA Astrophysics Data System (ADS)

Ghosh, Satyajit; Gumber, Siddharth; Varotsos, C.

2017-11-01

This paper quantifies mass transfer and diffusional uptake rates of gases in liquid and solid hydrometeors within a cyclonic system. The non-availability of transfer rates for trace gases diffusing into storm hydrometeors, particularly over polluted urban conurbations, often constrain modellers the world over; however, this is an essential requirement to quantify the scavenging rates over the region concerned. The present paper seeks to provide modellers with such rates. Further, all of the earlier studies apply only to temperate regimes, and surprisingly identical formulations are assumed even for tropical conditions. The present analysis fills this research gap and couples cloud morphology with the associated thermodynamics through Weather Research and Forecasting (WRF) runs for cyclone Chapala (27 October 2015-04 November 2015) which battered the coasts of Yemen (Skamarock et al. 2008). It was a good example for undertaking this sensitivity study because the vertical extent spanned from around 0.75 to 16 km—enabling uptake rate calculations over both droplet and ice phases. Many of the diffusing gases were polar; the dipole moment of sulphur dioxide (SO2) and water vapour (H2O) was also included using a full Lennard-Jones model to compute the binary diffusivities of these gases as they diffused into the droplets mixed with water vapour. The first-order uptake rate constants ranged from 2.08 × 10-07 to 3.44 × 10-06 (s-1) and 1.97 × 10-07 to 7.81 × 10-07 (s-1) for H2O and SO2 respectively. The rates are of the order of 10-09 (s-1) for diffusion of water vapour into ice crystals further aloft. Closely linked with the gas uptake rates is another crucial parameter—the mass accommodation coefficient, α. The most widely used values are 1 and 0.036 (Pruppacher and Klett 1998)—the chosen values are restrictive and warrants a closer look. In storm systems, the vertical extents are in the kilometre range. Chapala with a large vertical extent warrants a full profile calculation. This study shows that for H2O vapour, α values range from a low of 0.004 reaching up to 0.046, and for SO2 impacting the liquid droplets, they are 0.004 to 0.077. Using these values in cloud droplet growth equations showed large changes in the positioning of the cloud base height up to about a maximum of 30%—a classic example illustrating the coupling of microphysics with dynamics suggesting that even large-scale models should cautiously use standard un-corrected accommodation and diffusion coefficients. Over polluted environments, aerosol number concentrations are very high—several hundreds of particles in a cubic centimetre—the cumulative effect involving such large-scale scavenging ends up in causing substantive changes in the actual scavenging rates. This is likely to affect overall radiative transfer calculations and must be corrected.

The effect of ice nuclei on a deep convective cloud in South China

NASA Astrophysics Data System (ADS)

Deng, Xin; Xue, Huiwen; Meng, Zhiyong

2018-07-01

This study uses the Weather Research and Forecasting Model to simulate a deep convective cloud under a relatively polluted condition in South China. Ice nuclei (IN) aerosols near the surface are effectively transported upwards to above the 0 °C level by the strong updrafts in the convective cloud. Four cases with initial surface IN aerosol concentrations of 1, 10, 100, and 1000 L-1 are simulated. All simulations can well reproduce the major characteristics of the deep convective cloud in terms of the evolution, spatial distribution, and its track. IN aerosols have little effect on these macrophysical characteristics but can significantly affect ice formation. When IN concentration is increased, all heterogeneous nucleation modes are significantly enhanced, whereas the homogeneous freezing of cloud droplets is unchanged or weakened depending on the IN concentration and the development stages of the deep convective cloud. The homogeneous freezing of haze particles is generally not affected by increased IN but is slightly weakened in the extremely high IN case. As IN concentration is increased by 10 and 100 times, the enhanced heterogeneous nucleation is still not strong enough to compete with homogeneous freezing. Ice formation is hence still dominated by the homogenous freezing of cloud droplets and haze particles in the layer of 9-14 km, where most of the ice crystals are produced. The microphysical properties are generally unaffected in all the stages of cloud evolution. As IN concentration is increased by 1000 times and heterogeneous nucleation is further enhanced, the homogeneous freezing of cloud droplets and haze particles dominates only in the mature and dissipating stages, leading to unaffected ice number mixing ratio in the anvil region (approximately above 9 km) for these two stages. However, in the developing stage, when the supply of cloud droplets is limited, the homogeneous freezing of cloud droplets is weakened or even suppressed due to the very strong competition for liquid water with heterogeneous nucleation, leading to significantly lower ice number mixing ratio in the anvil regions. In addition, the microphysical properties in the convective core regions below the cloud anvil (approximately below 9 km) are also affected in the case of 1000 L-1. The enhanced heterogeneous nucleation produces more ice crystals below 9 km, leading to a stronger conversion from ice crystals to snow particles, and hence higher number and mass mixing ratios of snow. The IN effect on the spatial distributions and temporal evolutions of the surface precipitation and updraft velocity is generally insignificant.

Net Thermal Radiation in the Atmosphere of Venus

NASA Technical Reports Server (NTRS)

Revercomb, H. E.; Sromovsky, L. A.; Suomi, V. E.; Boese, R. W.

1985-01-01

The four entry probes of the Pioneer Venus mission measured the radiative net flux in the atmosphere of Venus at latitudes of 60 deg. N, 31 deg. S, 27 deg. S, and 4 deg. N. The three higher latitude probes carried instruments (small probe net flux radiometers; SNFR) with external sensors. The measured SNFR net fluxes are too large below the clouds, but an error source and correction scheme have been found (H. E. Revercomb, L. A. Sromovsky, and V. E. Suomi, 1982, Icarus 52, 279-300). The near-equatorial probe carried an infrared radiometer (LIR) which viewed the atmosphere through a window in the probe. The LIR measurements are reasonable in the clouds, but increase to physically unreasonable levels shortly below the clouds. The probable error source and a correction procedure are identified. Three main conclusions can be drawn from comparisons of the four corrected flux profiles with radiative transfer calculations: (1) thermal net fluxes for the sounder probe do not require a reduction in the Mode 3 number density as has been suggested by O.B. Toon, B. Ragent, D. Colburn, J. Blamont, and C. Cot (1964. Icarus 37, 143-160), but the probe measurements as a whole are most consistent with a significantly reduced mode 3 contribution to the cloud opacity; (2) at all probe sites, the fluxes imply that the upper cloud contains a yet undetected source of IR opacity; and (3) beneath the clouds the fluxes at a given altitude increase with latitude, suggesting greater IR cooling below the clouds a( high latitudes and water vapor mixing ratios of about 2-5 x 10(exp -5) near 6 deg., 2-5 x 10(exp -11) near 30 deg., and less than 5 x 10(exp -4 ) near the equator. The suggested latitudinal variation of IR cooling is consistent with descending motions at high latitudes, and it is speculated that it could provide an important additional drive for the general circulation.

Scattering in infrared radiative transfer: A comparison between the spectrally averaging model JURASSIC and the line-by-line model KOPRA

NASA Astrophysics Data System (ADS)

Griessbach, Sabine; Hoffmann, Lars; Höpfner, Michael; Riese, Martin; Spang, Reinhold

2013-09-01

The viability of a spectrally averaging model to perform radiative transfer calculations in the infrared including scattering by atmospheric particles is examined for the application of infrared limb remote sensing measurements. Here we focus on the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) aboard the European Space Agency's Envisat. Various spectra for clear air and cloudy conditions were simulated with a spectrally averaging radiative transfer model and a line-by-line radiative transfer model for three atmospheric window regions (825-830, 946-951, 1224-1228 cm-1) and compared to each other. The results are rated in terms of the MIPAS noise equivalent spectral radiance (NESR). The clear air simulations generally agree within one NESR. The cloud simulations neglecting the scattering source term agree within two NESR. The differences between the cloud simulations including the scattering source term are generally below three and always below four NESR. We conclude that the spectrally averaging approach is well suited for fast and accurate infrared radiative transfer simulations including scattering by clouds. We found that the main source for the differences between the cloud simulations of both models is the cloud edge sampling. Furthermore we reasoned that this model comparison for clouds is also valid for atmospheric aerosol in general.

Changes in Clouds Under a Combined CO2 Increase and Solar Decrease

NASA Astrophysics Data System (ADS)

Russotto, R. D.; Ackerman, T. P.

2017-12-01

The Geoengineering Model Intercomparison Project (GeoMIP) provides an excellent opportunity to study the response of clouds and the large-scale circulation to opposing solar and greenhouse gas forcings. This study analyzes changes in cloud fraction in 10 fully coupled atmosphere-ocean global climate models in GeoMIP Experiment G1, in which CO2 concentrations are quadrupled and the solar constant is reduced in order to keep global mean temperature at preindustrial levels. There is general agreement among the models that the area coverage of low clouds (below the 680 hPa pressure level) decreases in this experiment compared to preindustrial conditions over most ocean and vegetated land areas. This reduction in low cloud fraction is related to decreases in boundary layer inversion strength over the ocean, and to plant physiological responses to increased CO2. Mid-level clouds (680-440 hPa) and high clouds (< 440 hPa) are reduced over the Atlantic and Pacific Oceans to the north and south of the ITCZ, while high clouds also increase over the center of the ITCZ. These changes are related to a weakening of the seasonal migration of the ITCZ in G1, which happens because the summer hemisphere is preferentially cooled by the solar reduction. To explore the link between clouds and the ITCZ migration, we examine changes in the seasonal cycle of cloud cover and in the instantaneous ITCZ width throughout the year. High cloud fraction increases in the global mean in most models, likely due to upper tropospheric cooling. An analysis of radiative effects using the Approximate Partial Radiation Perturbation method shows that, in the shortwave, cloud changes in G1 have a warming effect in most areas, mainly due to the reduction in low cloud fraction. This effect, along with the warming effect from the increase in high clouds, results in a larger solar reduction being necessary to compensate for the CO2 increase.

GCM Simulations of the Aerosol Indirect Effect: Sensitivity to Cloud Parameterization and Aerosol Burden

NASA Technical Reports Server (NTRS)

Menon, Surabi; DelGenio, Anthony D.; Koch, Dorothy; Tselioudis, George; Hansen, James E. (Technical Monitor)

2001-01-01

We describe the coupling of the Goddard Institute for Space Studies (GISS) general circulation model (GCM) to an online sulfur chemistry model and source models for organic matter and sea-salt that is used to estimate the aerosol indirect effect. The cloud droplet number concentration is diagnosed empirically from field experiment datasets over land and ocean that observe droplet number and all three aerosol types simultaneously; corrections are made for implied variations in cloud turbulence levels. The resulting cloud droplet number is used to calculate variations in droplet effective radius, which in turn allows us to predict aerosol effects on cloud optical thickness and microphysical process rates. We calculate the aerosol indirect effect by differencing the top-of-the-atmosphere net cloud radiative forcing for simulations with present-day vs. pre-industrial emissions. Both the first (radiative) and second (microphysical) indirect effects are explored. We test the sensitivity of our results to cloud parameterization assumptions that control the vertical distribution of cloud occurrence, the autoconversion rate, and the aerosol scavenging rate, each of which feeds back significantly on the model aerosol burden. The global mean aerosol indirect effect for all three aerosol types ranges from -1.55 to -4.36 W m(exp -2) in our simulations. The results are quite sensitive to the pre-industrial background aerosol burden, with low pre-industrial burdens giving strong indirect effects, and to a lesser extent to the anthropogenic aerosol burden, with large burdens giving somewhat larger indirect effects. Because of this dependence on the background aerosol, model diagnostics such as albedo-particle size correlations and column cloud susceptibility, for which satellite validation products are available, are not good predictors of the resulting indirect effect.

GCM Simulations of the Aerosol Indirect Effect: Sensitivity to Cloud Parameterization and Aerosol Burden

NASA Technical Reports Server (NTRS)

Menon, Surabi; DelGenio, Anthony D.; Koch, Dorothy; Tselioudis, George; Hansen, James E. (Technical Monitor)

2001-01-01

We describe the coupling of the Goddard Institute for Space Studies (GISS) general circulation model (GCM) to an online sulfur chemistry model and source models for organic matter and sea-salt that is used to estimate the aerosol indirect effect. The cloud droplet number concentration is diagnosed empirically from field experiment datasets over land and ocean that observe droplet number and all three aerosol types simultaneously; corrections are made for implied variations in cloud turbulence levels. The resulting cloud droplet number is used to calculate variations in droplet effective radius, which in turn allows us to predict aerosol effects on cloud optical thickness and microphysical process rates. We calculate the aerosol indirect effect by differencing the top-of-the-atmosphere net cloud radiative forcing for simulations with present-day vs. pre-industrial emissions. Both the first (radiative) and second (microphysical) indirect effects are explored. We test the sensitivity of our results to cloud parameterization assumptions that control the vertical distribution of cloud occurrence, the autoconversion rate, and the aerosol scavenging rate, each of which feeds back significantly on the model aerosol burden. The global mean aerosol indirect effect for all three aerosol types ranges from -1.55 to -4.36 W/sq m in our simulations. The results are quite sensitive to the pre-industrial background aerosol burden, with low pre-industrial burdens giving strong indirect effects, and to a lesser extent to the anthropogenic aerosol burden, with large burdens giving somewhat larger indirect effects. Because of this dependence on the background aerosol, model diagnostics such as albedo-particle size correlations and column cloud susceptibility, for which satellite validation products are available, are not good predictors of the resulting indirect effect.

Atmospheric chemistry of a 33-34 hour old volcanic cloud from Hekla Volcano (Iceland): Insights from direct sampling and the application of chemical box modeling

USGS Publications Warehouse

Rose, William I.; Millard, G.A.; Mather, T.A.; Hunton, D.E.; Anderson, B.; Oppenheimer, C.; Thornton, B.F.; Gerlach, T.M.; Viggiano, A.A.; Kondo, Y.; Miller, T.M.; Ballenthin, J.O.

2006-01-01

On 28 February 2000, a volcanic cloud from Hekla volcano, Iceland, was serendipitously sampled by a DC-8 research aircraft during the SAGE III Ozone Loss and Validation Experiment (SOLVE I). It was encountered at night at 10.4 km above sea level (in the lower stratosphere) and 33-34 hours after emission. The cloud is readily identified by abundant SO2 (???1 ppmv), HCl (???70 ppbv), HF (???60 ppbv), and particles (which may have included fine silicate ash). We compare observed and modeled cloud compositions to understand its chemical evolution. Abundances of sulfur and halogen species indicate some oxidation of sulfur gases but limited scavenging and removal of halides. Chemical modeling suggests that cloud concentrations of water vapor and nitric acid promoted polar stratospheric cloud (PSC) formation at 201-203 K, yielding ice, nitric acid trihydrate (NAT), sulfuric acid tetrahydrate (SAT), and liquid ternary solution H2SO4/H2O/HNO3 (STS) particles. We show that these volcanically induced PSCs, especially the ice and NAT particles, activated volcanogenic halogens in the cloud producing >2 ppbv ClOx. This would have destroyed ozone during an earlier period of daylight, consistent with the very low levels of ozone observed. This combination of volcanogenic PSCs and chlorine destroyed ozone at much faster rates than other PSCs that Arctic winter. Elevated levels of HNO3 and NOy in the cloud can be explained by atmospheric nitrogen fixation in the eruption column due to high temperatures and/or volcanic lightning. However, observed elevated levels of HOx remain unexplained given that the cloud was sampled at night. Copyright 2006 by the American Geophysical Union.

Aerosol Chemical Composition and its Effects on Cloud-Aerosol Interactions during the 2007 CHAPS Experiment

NASA Astrophysics Data System (ADS)

Lee, Y.; Alexander, L.; Newburn, M.; Jayne, J.; Hubbe, J.; Springston, S.; Senum, G.; Andrews, B.; Ogren, J.; Kleinman, L.; Daum, P.; Berg, L.; Berkowitz, C.

2007-12-01

Chemical composition of submicron aerosol particles was determined using an Aerodyne Time-of-Flight Aerosol Mass Spectrometer (AMS) outfitted on the DOE G-1 aircraft during the Cumulus Humilis Aerosol Processing Study (CHAPS) conducted in Oklahoma City area in June 2007. The primary objective of CHAPS was to investigate the effects of urban emissions on cloud aerosol interactions as a function of processing of the emissions. Aerosol composition was typically determined at three different altitudes: below, in, and above cloud, in both upwind and downwind regions of the urban area. Aerosols were sampled from an isokinetic inlet with an upper size cut-off of ~1.5 micrometer. During cloud passages, the AMS also sampled particles that were dried from cloud droplets collected using a counter-flow virtual impactor (CVI) sampler. The aerosol mass concentrations were typically below 10 microgram per cubic meter, and were dominated by organics and sulfate. Ammonium was often less than required for complete neutralization of sulfate. Aerosol nitrate levels were very low. We noted that nitrate levels were significantly enhanced in cloud droplets compared to aerosols, most likely resulting from dissolution of gaseous nitric acid. Organic to sulfate ratios appeared to be lower in cloud droplets than in aerosols, suggesting cloud condensation nuclei properties of aerosol particles might be affected by loading and nature of the organic components in aerosols. In-cloud formation of sulfate was considered unimportant because of the very low SO2 concentration in the region. A detailed examination of the sources of the aerosol organic components (based on hydrocarbons determined using a proton transfer reaction mass spectrometer) and their effects on cloud formation as a function of atmospheric processing (based on the degree of oxidation of the organic components) will be presented.

Transport of infrared radiation in cuboidal clouds

NASA Technical Reports Server (NTRS)

HARSHVARDHAN; Weinman, J. A.; Davies, R.

1981-01-01

The transport of infrared radiation in a single cuboidal cloud using a vertical two steam approximation was modeled. The emittance of the top face of the model cloud is always less than that for a plane parallel cloud of the same optical depth. The hemisphere flux escaping from the cloud top has a gradient from the center to the edges which brighten when the cloud is over warmer ground. Cooling rate calculations in the 8 to 13.6 micrometer region show that there is cooling from the sides of the cloud at all levels even when there is heating of the core from the ground below. The radiances exiting from model cuboidal clouds were computed by path integration over the source function obtained with the two stream approximation. It is suggested that the brightness temperature measured from finite clouds will overestimate the cloud top temperature.

Stormy Day at Jupiter

NASA Image and Video Library

2017-05-25

Small bright clouds dot Jupiter's entire south tropical zone in this image acquired by JunoCam on NASA's Juno spacecraft on May 19, 2017, at an altitude of 7,990 miles (12,858 kilometers). Although the bright clouds appear tiny in this vast Jovian cloudscape, they actually are cloud towers roughly 30 miles (50 kilometers) wide and 30 miles (50 kilometers) high that cast shadows on the clouds below. On Jupiter, clouds this high are almost certainly composed of water and/or ammonia ice, and they may be sources of lightning. This is the first time so many cloud towers have been visible, possibly because the late-afternoon lighting is particularly good at this geometry. https://photojournal.jpl.nasa.gov/catalog/PIA21647

Effect of acidification on carrot (Daucus carota) juice cloud stability.

PubMed

Schultz, Alison K; Barrett, Diane M; Dungan, Stephanie R

2014-11-26

Effects of acidity on cloud stability in pasteurized carrot juice were examined over the pH range of 3.5-6.2. Cloud sedimentation, particle diameter, and ζ potential were measured at each pH condition to quantify juice cloud stability and clarification during 3 days of storage. Acidification below pH 4.9 resulted in a less negative ζ potential, an increased particle size, and an unstable cloud, leading to juice clarification. As the acidity increased, clarification occurred more rapidly and to a greater extent. Only a weak effect of ionic strength was observed when sodium salts were added to the juice, but the addition of calcium salts significantly reduced the cloud stability.

Measurement of Atmospheric CO2 Column Concentrations to Cloud Tops With a Pulsed Multi-Wavelength Airborne Lidar

NASA Technical Reports Server (NTRS)

Mao, Jianping; Ramanathan, Anand; Abshire, James B.; Kawa, Stephan R.; Riris, Haris; Allan, Graham R.; Rodriguez, Michael R.; Hasselbrack, William E.; Sun, Xiaoli; Numata, Kenji;

Measurement of atmospheric CO2 column concentrations to cloud tops with a pulsed multi-wavelength airborne lidar

NASA Astrophysics Data System (ADS)

Mao, Jianping; Ramanathan, Anand; Abshire, James B.; Kawa, Stephan R.; Riris, Haris; Allan, Graham R.; Rodriguez, Michael; Hasselbrack, William E.; Sun, Xiaoli; Numata, Kenji; Chen, Jeff; Choi, Yonghoon; Yang, Mei Ying Melissa

2018-01-01

We have measured the column-averaged atmospheric CO2 mixing ratio to a variety of cloud tops by using an airborne pulsed multi-wavelength integrated-path differential absorption (IPDA) lidar. Airborne measurements were made at altitudes up to 13 km during the 2011, 2013 and 2014 NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) science campaigns flown in the United States West and Midwest and were compared to those from an in situ sensor. Analysis of the lidar backscatter profiles shows the average cloud top reflectance was ˜ 5 % for the CO2 measurement at 1572.335 nm except to cirrus clouds, which had lower reflectance. The energies for 1 µs wide laser pulses reflected from cloud tops were sufficient to allow clear identification of CO2 absorption line shape and then to allow retrievals of atmospheric column CO2 from the aircraft to cloud tops more than 90 % of the time. Retrievals from the CO2 measurements to cloud tops had minimal bias but larger standard deviations when compared to those made to the ground, depending on cloud top roughness and reflectance. The measurements show this new capability helps resolve CO2 horizontal and vertical gradients in the atmosphere. When used with nearby full-column measurements to ground, the CO2 measurements to cloud tops can be used to estimate the partial-column CO2 concentration below clouds, which should lead to better estimates of surface carbon sources and sinks. This additional capability of the range-resolved CO2 IPDA lidar technique provides a new benefit for studying the carbon cycle in future airborne and space-based CO2 missions.

Chemical Processing of Organics within Clouds: Pilot Study at Whiteface Mountain in Upstate NY

NASA Astrophysics Data System (ADS)

Lance, S.; Carlton, A. G.; Barth, M. C.; Schwab, J. J.; Minder, J. R.; Freedman, J. M.; Zhang, J.; Brandt, R. E.; Casson, P.; Brewer, M.; Orlowski, D.; Christiansen, A.

2017-12-01

Aqueous chemical processing within cloud and fog water has been identified as a key process in the formation of secondary organic aerosol (SOA) mass, which is found abundantly throughout the troposphere. Yet, significant uncertainty remains regarding the organic chemical reactions taking place within clouds and the conditions under which those reactions occur. Routine longterm measurements from the Whiteface Mountain (WFM) Research Observatory in upstate NY provide a unique and broad view of regional air quality relevant to the formation of particulate matter within clouds, largely due to the fact that the summit of WFM is within non-precipitating clouds 30-50% in summertime and the site is undisturbed by local sources. An NSF-funded Cloud Chemistry Workshop in Sept 2016 brought together key researchers at WFM to lay out the most pertinent scientific questions relevant to heterogeneous chemistry occurring within fogs and clouds and to discuss preliminary model intercomparisons. The workshop culminated in a plan to coordinate chemical analyses of cloud water samples focused on chemical constituents thought to be most relevant for SOA formation. Workshop participants also recommended that a pilot study be conducted at WFM to better characterize the meteorological conditions, airflow patterns and clouds intercepting the site, in preparation for future intensive field operations focused on the chemical processing of organics within clouds. This presentation will highlight the experimental design and preliminary observations from the pilot study taking place at WFM in August 2017. Upwind below-cloud measurements of aerosol CCN activation efficiency, size distribution and chemical composition will be compared with similar measurements made at the summit. Under certain conditions, we anticipate that aerosols measured at the summit between cloud events will be representative of cloud droplet residuals recently detrained from the frequent shallow cumulus intercepting the summit. Wind LIDAR and radiosonde observations will be used to link the below-cloud and summit observations. These pre- and post- `cloud processed' aerosols will also be compared with the chemical composition of cloud water samples to evaluate changes to the organic partitioning in the aqueous and aerosol phases.

Low Clouds and Fog Characterization over Iberian Peninsula using Meteosat Second Generation Images

NASA Astrophysics Data System (ADS)

Sánchez, Beatriz; Maqueda, Gregorio

2014-05-01

Fog is defined as a collection of suspended water droplets or ice crystals in the air near the Earth's surface that lead to a reduction of horizontal visibility below 1 km (National Oceanic and Atmospheric Administration, 1995). Fog is a stratiform cloud with similar radiative characteristics, for this reason the difference between fog and low stratus clouds is of little importance for remote sensing applications. Fog and low clouds are important atmospheric phenomena, mainly because of their impact on traffic safety and air quality, acting as an obstruction to traffic at land, sea and in the air. The purpose of this work is to develop the method of fog/low clouds detection and analysis on nighttime using Meteosat Second Generation data. This study is focused on the characterization of these atmospheric phenomena in different study cases over the Iberian Peninsula with distinct orography. Firstly, fog/low clouds detection is implemented as a composition of three infrared channels 12.0, 10.8 and 3.9 µm from SEVIRI radiometer on board European geostationary satellite Meteosat (Meteosat-9). The algorithm of detection makes use of a combination of these channels and their differences by creating RGB composites images. On this way, it displays the spatial coverage and location of fog entities. Secondly, this technique allows separating pixels which are indicated as fog/low clouds from clear pixels, assessing the properties of individual pixels using appropriated thresholds of brightness temperature. Thus, it achieves a full analysis of the extent and distribution of fog and its evolution over time. The results of this study have been checked by using ground-based point measurements available as METAR data. Despite the flaws in this sort of inter-comparison approach, the outcome produces to accurate fog/low clouds detection. This work encompasses the way to obtain spatial information from this atmospheric phenomenon by means of satellite imagery.

IRAM 30 m large scale survey of {sup 12}CO(2-1) and {sup 13}CO(2-1) emission in the Orion molecular cloud

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berné, O.; Cernicharo, J.; Marcelino, N., E-mail: olivier.berne@irap.omp.eu

2014-11-01

Using the IRAM 30 m telescope, we have surveyed a 1 × 0.°8 part of the Orion molecular cloud in the {sup 12}CO and {sup 13}CO (2-1) lines with a maximal spatial resolution of ∼11'' and spectral resolution of ∼0.4 km s{sup –1}. The cloud appears filamentary, clumpy, and with a complex kinematical structure. We derive an estimated mass of the cloud of 7700 M {sub ☉} (half of which is found in regions with visual extinctions A{sub V} below ∼10) and a dynamical age for the nebula of the order of 0.2 Myr. The energy balance suggests that magneticmore » fields play an important role in supporting the cloud, at large and small scales. According to our analysis, the turbulent kinetic energy in the molecular gas due to outflows is comparable to turbulent kinetic energy resulting from the interaction of the cloud with the H II region. This latter feedback appears negative, i.e., the triggering of star formation by the H II region is inefficient in Orion. The reduced data as well as additional products such as the column density map are made available online (http://userpages.irap.omp.eu/∼oberne/Olivier{sub B}erne/Data).« less

On the unified estimation of turbulence eddy dissipation rate using Doppler cloud radars and lidars: Radar and Lidar Turbulence Estimation

DOE PAGES

Borque, Paloma; Luke, Edward; Kollias, Pavlos

2016-05-27

Coincident profiling observations from Doppler lidars and radars are used to estimate the turbulence energy dissipation rate (ε) using three different data sources: (i) Doppler radar velocity (DRV), (ii) Doppler lidar velocity (DLV), and (iii) Doppler radar spectrum width (DRW) measurements. Likewise, the agreement between the derived ε estimates is examined at the cloud base height of stratiform warm clouds. Collocated ε estimates based on power spectra analysis of DRV and DLV measurements show good agreement (correlation coefficient of 0.86 and 0.78 for both cases analyzed here) during both drizzling and nondrizzling conditions. This suggests that unified (below and abovemore » cloud base) time-height estimates of ε in cloud-topped boundary layer conditions can be produced. This also suggests that eddy dissipation rate can be estimated throughout the cloud layer without the constraint that clouds need to be nonprecipitating. Eddy dissipation rate estimates based on DRW measurements compare well with the estimates based on Doppler velocity but their performance deteriorates as precipitation size particles are introduced in the radar volume and broaden the DRW values. And, based on this finding, a methodology to estimate the Doppler spectra broadening due to the spread of the drop size distribution is presented. Furthermore, the uncertainties in ε introduced by signal-to-noise conditions, the estimation of the horizontal wind, the selection of the averaging time window, and the presence of precipitation are discussed in detail.« less

On the unified estimation of turbulence eddy dissipation rate using Doppler cloud radars and lidars: Radar and Lidar Turbulence Estimation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borque, Paloma; Luke, Edward; Kollias, Pavlos

Coincident profiling observations from Doppler lidars and radars are used to estimate the turbulence energy dissipation rate (ε) using three different data sources: (i) Doppler radar velocity (DRV), (ii) Doppler lidar velocity (DLV), and (iii) Doppler radar spectrum width (DRW) measurements. Likewise, the agreement between the derived ε estimates is examined at the cloud base height of stratiform warm clouds. Collocated ε estimates based on power spectra analysis of DRV and DLV measurements show good agreement (correlation coefficient of 0.86 and 0.78 for both cases analyzed here) during both drizzling and nondrizzling conditions. This suggests that unified (below and abovemore » cloud base) time-height estimates of ε in cloud-topped boundary layer conditions can be produced. This also suggests that eddy dissipation rate can be estimated throughout the cloud layer without the constraint that clouds need to be nonprecipitating. Eddy dissipation rate estimates based on DRW measurements compare well with the estimates based on Doppler velocity but their performance deteriorates as precipitation size particles are introduced in the radar volume and broaden the DRW values. And, based on this finding, a methodology to estimate the Doppler spectra broadening due to the spread of the drop size distribution is presented. Furthermore, the uncertainties in ε introduced by signal-to-noise conditions, the estimation of the horizontal wind, the selection of the averaging time window, and the presence of precipitation are discussed in detail.« less

Water Ice Clouds in the Martian Atmosphere: A View from MGS TES

NASA Technical Reports Server (NTRS)

Hale, A. S.; Tamppari, L. K.; Christensen, P. R.; Smith, M. D.; Bass, Deborah; Qu, Zheng; Pearl, J. C.

2005-01-01

We use the method of Tamppari et al. to map water ice clouds in the Martian atmosphere. This technique was originally developed to analyze the broadband Viking IRTM channels and we have now applied it to the TES data. To do this, the TES spectra are convolved to the IRTM bandshapes and spatial resolutions, enabling use of the same processing techniques as were used in Tamppari et al.. This retrieval technique relies on using the temperature difference recorded in the 20 micron and 11 micron IRTM bands (or IRTM convolved TES bands) to map cold water ice clouds above the warmer Martian surface. Careful removal of surface contributions to the observed radiance is therefore necessary, and we have used both older Viking-derived basemaps of the surface emissivity and albedo, and new MGS derived basemaps in order the explore any possible differences on cloud retrieval due to differences in surface contribution removal. These results will be presented in our poster. Our previous work has concentrated primarily on comparing MGS TES to Viking data; that work saw that large-scale cloud features, such as the aphelion cloud belt, are quite repeatable from year to year, though small scale behavior shows some variation. Comparison of Viking and MGS era cloud maps will be presented in our poster. In the current stage of our study, we have concentrated our efforts on close analysis of water ice cloud behavior in the northern summer of the three MGS mapping years on relatively small spatial scales, and present our results below. Additional information is included in the original extended abstract.

Low clouds suppress Arctic air formation and amplify high-latitude continental winter warming.

PubMed

Cronin, Timothy W; Tziperman, Eli

2015-09-15

High-latitude continents have warmed much more rapidly in recent decades than the rest of the globe, especially in winter, and the maintenance of warm, frost-free conditions in continental interiors in winter has been a long-standing problem of past equable climates. We use an idealized single-column atmospheric model across a range of conditions to study the polar night process of air mass transformation from high-latitude maritime air, with a prescribed initial temperature profile, to much colder high-latitude continental air. We find that a low-cloud feedback--consisting of a robust increase in the duration of optically thick liquid clouds with warming of the initial state--slows radiative cooling of the surface and amplifies continental warming. This low-cloud feedback increases the continental surface air temperature by roughly two degrees for each degree increase of the initial maritime surface air temperature, effectively suppressing Arctic air formation. The time it takes for the surface air temperature to drop below freezing increases nonlinearly to ∼ 10 d for initial maritime surface air temperatures of 20 °C. These results, supplemented by an analysis of Coupled Model Intercomparison Project phase 5 climate model runs that shows large increases in cloud water path and surface cloud longwave forcing in warmer climates, suggest that the "lapse rate feedback" in simulations of anthropogenic climate change may be related to the influence of low clouds on the stratification of the lower troposphere. The results also indicate that optically thick stratus cloud decks could help to maintain frost-free winter continental interiors in equable climates.

Low clouds suppress Arctic air formation and amplify high-latitude continental winter warming

PubMed Central

Cronin, Timothy W.; Tziperman, Eli

2015-01-01

High-latitude continents have warmed much more rapidly in recent decades than the rest of the globe, especially in winter, and the maintenance of warm, frost-free conditions in continental interiors in winter has been a long-standing problem of past equable climates. We use an idealized single-column atmospheric model across a range of conditions to study the polar night process of air mass transformation from high-latitude maritime air, with a prescribed initial temperature profile, to much colder high-latitude continental air. We find that a low-cloud feedback—consisting of a robust increase in the duration of optically thick liquid clouds with warming of the initial state—slows radiative cooling of the surface and amplifies continental warming. This low-cloud feedback increases the continental surface air temperature by roughly two degrees for each degree increase of the initial maritime surface air temperature, effectively suppressing Arctic air formation. The time it takes for the surface air temperature to drop below freezing increases nonlinearly to ∼10 d for initial maritime surface air temperatures of 20 °C. These results, supplemented by an analysis of Coupled Model Intercomparison Project phase 5 climate model runs that shows large increases in cloud water path and surface cloud longwave forcing in warmer climates, suggest that the “lapse rate feedback” in simulations of anthropogenic climate change may be related to the influence of low clouds on the stratification of the lower troposphere. The results also indicate that optically thick stratus cloud decks could help to maintain frost-free winter continental interiors in equable climates. PMID:26324919

Use of In Situ Cloud Condensation Nuclei, Extinction, and Aerosol Size Distribution Measurements to Test a Method for Retrieving Cloud Condensation Nuclei Profiles From Surface Measurements

NASA Technical Reports Server (NTRS)

Ghan, Stephen J.; Rissman, Tracey A.; Ellman, Robert; Ferrare, Richard A.; Turner, David; Flynn, Connor; Wang, Jian; Ogren, John; Hudson, James; Jonsson, Haflidi H.;

Whey protein film with oxygen scavenging function by incorporation of ascorbic acid.

PubMed

Janjarasskul, Theeranun; Tananuwong, Kanitha; Krochta, John M

2011-01-01

Residual O(2) in a package headspace can be removed by an O(2)-absorbing sachet, which can be harmful if swallowed by the consumer, or by a chemically-active plastic packaging film, which is difficult to recycle. An edible, O(2)-absorbing film would avoid these disadvantages. The objective of our research was to assess the O(2)-scavenging potential of an edible whey protein isolate (WPI) film incorporating ascorbic acid (AA). AA at 0.05, 0.1, or 0.2 M was added to 5% (w/w) heat-denatured WPI film-forming solutions with WPI : glycerol (Gly) ratio of 1: 1.00, 1: 0.80, or 1: 0.67. The pH of solutions was then adjusted to 3.5 (below pK(a1) of AA), to stabilize AA against oxidation, before film casting. The mechanical properties, O(2) permeabilities, and thermal transitions of films were measured. Activation of the O(2)-scavenging function of the AA-incorporated films was accomplished by adjustment of the films to pH ≥ 7. O(2)-scavenging ability of AA-incorporated WPI films was determined by measuring residual O(2) in the headspace of a high-barrier container. Incorporation of AA into WPI film decreased film tensile strength and further reduced O(2) permeability at each WPI : Gly ratio. AA-containing films adjusted to pH ≥ 7 demonstrated O(2) absorption proportional to AA content, consistent with theoretical O(2)-scavenging capacity. Thermal transition measurements indicated that AA was involved in WPI structural modification and decreased the degradation temperature of WPI-based film. The demonstrated O(2)-scavenging function, improved O(2) barrier and acceptable mechanical properties of AA-incorporated films indicate potential commercial usefulness. Ascorbic acid-incorporated whey protein film with oxygen scavenging function can be used to extend shelf lives of a wide variety of oxygen-sensitive products by eliminating headspace oxygen as well as oxygen permeating through the packaging wall over time. Edible oxygen-scavenger film has the advantages of avoiding both accidental consumption and nonrecyclability of conventional oxygen scavenger systems. © 2011 Institute of Food Technologists®

[Results for SHEBA/FIRE

NASA Technical Reports Server (NTRS)

Valero, Francisco P. J.

2003-01-01

The Atmospheric Research Laboratory's Radiation Measurement System (RAMS) was on the NCAR C-130 aircraft in May and July 1998, collecting radiometric data on the science flights conducted in the vicinity of the Surface Heat Budget of the Arctic Ocean (SHEBA) ship. These measurements were part of the FIRE Arctic Cloud Experiment (FIRE ACE). Analysis of some of the data focused on the absorption, reflection, and transmittance of Arctic clouds, especially compared to model results. In order to assess the absorption of solar radiation by the clear and cloudy atmosphere in the Arctic the measurements from the radiometers were combined in pairs of above-cloud segments and below-cloud segments. To get these pairs, the data for all sixteen of the flights (8 in May and 8 in July) were examined for occurrences of low-altitude segments in proximity to high-altitude segments. The low-altitude data are then treated as measurements of the bottom of a layer and the high-altitude data are taken as measurements of the top of the layer. With measurements of the upwelling and downwelling irradiances above and below a layer one can determine the reflectance, transmittance, and absorptance of the layer. Attachment: Doelling, D.R., P. Minnis, D.A. Spangenberg, V. Chakrapani, A. Mahesh, S.K. Pope, and F.P.J. Valero, Cloud radiative forcing at the top of the atmosphere during FIRE ACE derived from AVHRR data, J. Geophys. Res. 106, 15,279-15,296,2001. Minnis, P., D.R. Doelling, D.A. Spangenberg, A. Mahesh, S.K. Pope, and F.P.J. Valero, AVHRR-derived cloud radiative forcing over the ARM NSA and SHEBA site during FIRE ACE, abstract submitted to the ARM Science Team Meeting, San Antonio, TX, M a . 13-17,2000. Pope, S.K., and F.P.J. Valero, Measured and modeled radiometric fluxes in the Arctic during FIRE-ACE, presented as a poster at the American Geophysical Union meeting, San Francisco, CA, Dec. 13-17, 1999. Pope, S.K., and F.P.J. Valero, Measured and modeled radiometric fluxes in the Arctic during FIRE-ACEy paper presented at SHEBA/FIRE Workshop, National Center for Atmospheric Research, Boulder, Colo., Apr. 17-20,2000.

Cloud deposition of PAHs at Mount Lushan in southern China.

PubMed

Wang, Ruixia; Wang, Yan; Li, Hongli; Yang, Minmin; Sun, Lei; Wang, Tao; Wang, Wenxing

2015-09-01

Cloud water samples were collected from Mount Lushan, a high alpine area of southern China, and analyzed using GC-MS to investigate the concentration levels, seasonal variations, particle-dissolved phase partitioning, ecological risk of PAHs and its relationship to the atmosphere and rainwater. The average concentration of total (dissolved+particle) PAHs in cloud water was 819.90 ng/L, which ranged from 2.30 ng/L for DbA to 295.38 ng/L for PhA. PhA (33.11%) contributed the most individual PAHs, followed by Flu (28.24%). Distinct seasonal variations in the total PAHs measured in this research had a higher concentration during the spring and a lower concentration during the summer. When cloud events occurred, the concentration of the atmospheric PAHs of the two phases decreased. The contribution from the gaseous phase of total PAHs in the air to the dissolved phase in cloud water was up to 60.43%, but the particulate phase in the air only contributed 39.57% to the total scavenging. The contribution of total PAHs from the atmosphere to clouds is higher in the gaseous phase than in the particulate phase. A comparative study of the concentrations of cloud water and the closest rain water revealed that the PAH concentration in rainwater was 1.80 times less than that of cloud water and that the dominant individual compounds in cloud water and rainwater were PhA and Flu. A total of 81.27% of the PAHs in cloud samples and 72.21% of the PAHs in rain samples remained in the dissolved phase. Ecological risk assessment indicated that PAHs in cloud water in spring and summer caused a certain degree of ecosystem risk and the mean ecosystem risk in spring was higher than that in summer. Copyright © 2015 Elsevier B.V. All rights reserved.

Correlations of oriented ice and precipitation in marine midlatitude low clouds using collocated CloudSat, CALIOP, and MODIS observations

NASA Astrophysics Data System (ADS)

Ross, Alexa; Holz, Robert E.; Ackerman, Steven A.

2017-08-01

In April 2006, the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) launched aboard the CALIPSO satellite and into the A-Train constellation of satellites with its transmitter pointed near nadir. This proved problematic due to specular reflection from horizontally oriented ice crystals occurring more frequently than expected. Because the specular backscatter from oriented ice crystals has large attenuated backscatter and almost no depolarization, the standard lidar inversions cannot be applied. To mitigate this issue, the CALIOP transmitter was moved to 3° off nadir in November 2007. Though problematic for global CALIOP retrievals, the sensitivity to oriented ice during the first year of observations provides a unique data set to investigate scenes of this ice crystal signature. This study focuses on the CALIOP-oriented signature that occurs in midlatitude ocean regions whose cloud tops are relatively warm and low, existing below 6 km. A significant seasonal dependence is found in the Northern Hemisphere with up to 19% of clouds below 6 km yielding specular reflection by CALIOP during the colder months. In contrast, the Southern Hemisphere lacks such seasonal dependence and sees fewer oriented ice crystals. Using collocated CloudSat observations with both CALIOP and Moderate Resolution Imaging Spectroradiometer (MODIS), we investigate the correlations of the oriented signature with MODIS cloud properties. Comparing with CloudSat precipitation retrievals, we find that the oriented signature is strongly correlated with surface precipitation with 64% of CALIOP-oriented ice crystal cases precipitating compared to 40% for nonoriented cases.

Earth Observations taken by Expedition 34 crewmember

NASA Image and Video Library

2013-01-05

ISS034-E-024622 (5 Jan. 2013) --- Polar mesospheric clouds over the South Pacific Ocean are featured in this image photographed by an Expedition 34 crew member on the International Space Station. Polar mesospheric clouds—also known as noctilucent, or “night shining” clouds—are formed 76 to 85 kilometers above Earth’s surface near the mesosphere-thermosphere boundary of the atmosphere, a region known as the mesopause. At these altitudes, water vapor can freeze into clouds of ice crystals. When the sun is below the horizon such that the ground is in darkness, these high clouds may still be illuminated—lending them their ethereal, “night shining” qualities. Noctilucent clouds have been observed from all human vantage points in both the Northern and Southern Hemispheres – from the surface, in aircraft, and in orbit from the space station—and tend to be most visible during the late spring and early summer seasons. Polar mesospheric clouds also are of interest to scientists studying the atmosphere. While some scientists seek to understand their mechanisms of formation, others have identified them as potential indicators of atmospheric changes resulting from increases in greenhouse gas concentrations. This photograph was taken when the station was over the Pacific Ocean south of French Polynesia. While most polar mesospheric cloud images are taken from the orbital complex with relatively short focal length lens to maximize the field of view, this image was taken with a long lens (400 mm) allowing for additional detail of the cloud forms to be seen. Below the brightly-lit noctilucent clouds in the center of the image, the pale orange band indicates the stratosphere.

The effect of aerosol-derived changes in the warm phase on the properties of deep convective clouds

NASA Astrophysics Data System (ADS)

Chen, Qian; Koren, Ilan; Altaratz, Orit; Heiblum, Reuven; Dagan, Guy

2017-04-01

The aerosol impact on deep convective clouds starts in an increased number of cloud droplets in higher aerosol loading environment. This change drives many others, like enhanced condensational growth, delay in collision-coalescence and others. Since the warm processes serve as the initial and boundary conditions for the mixed and cold-phase processes in deep clouds, it is highly important to understand the aerosol effect on them. The weather research and forecasting model (WRF) with spectral bin microphysics was used to study a deep convective system over the Marshall Islands, during the Kwajalein Experiment (KWAJEX). Three simulations were conducted with aerosol concentrations of 100, 500 and 2000 cm-3, to reflect clean, semipolluted, and polluted conditions. The results of the clean run agreed well with the radar profiles and rain rate observations. The more polluted simulations resulted in larger total cloud mass, larger upper level cloud fraction and rain rates. There was an increased mass both below and above the zero temperature level. It indicates of more efficient growth processes both below and above the zero level. In addition the polluted runs showed an increased upward transport (across the zero level) of liquid water due to both stronger updrafts and larger droplet mobility. In this work we discuss the transport of cloud mass crossing the zero temperature level (in both directions) in order to gain a process level understanding of how aerosol effects on the warm processes affect the macro- and micro-properties of deep convective clouds.

Sensitivity of UV Erythemal Radiation to Total Ozone Changes under Different Sky Conditions: Results for Granada, Spain.

PubMed

Antón, Manuel; Cazorla, Alberto; Mateos, David; Costa, Maria J; Olmo, Francisco J; Alados-Arboledas, Lucas

2016-01-01

This study focuses on the analysis of the sensitivity of UV erythemal radiation (UVER) to variations in the total ozone column (TOC) under different sky conditions at Granada (southeastern Spain). The sensitivity is studied both in relative terms by means of the Radiation Amplification Factor (RAF) and in absolute terms using the Ozone Efficiency (OE). These two variables are determined for diverse sky conditions characterized by the cloud cover information given by a sky camera (in oktas) and the cloud optical depth (COD) estimated from global solar radiation measurements. As expected, in absolute terms, the TOC variations cause substantially smaller UVER changes during completely overcast situations than during cloud-free cases. For instance, the OE (SZA = 30°, TOC = 290 DU) decreases from 0.68 mW m(-2) per unit of TOC (0 oktas) to 0.50 mW m(-2) per unit of TOC (8 oktas). However, the opposite is observed when the analysis is performed in relative terms. Thus, the RAF (determined for SZA cases below 80°) increases from 1.1 for cloud-free cases (0 oktas) to 1.4 for completely overcast situations (8 oktas). This opposite behavior is also found when both RAF and OE are analyzed as functions of COD. Thus, while the OE strongly decreases with increasing COD, the RAF increases as COD increases. © 2015 The American Society of Photobiology.

Influence of long-range anthropogenic transport on arctic cloud phase transition

NASA Astrophysics Data System (ADS)

Riedi, J.; Coopman, Q.; Garrett, T. J.; Finch, D.

2016-12-01

A decrease in precipitation during winter allows polluted air parcels from mid-latitudes to reach the Arctic. Low vertical mixing in the region concentrates aerosols and decreases scavenging. Aerosol impacts on cloud microphysical parameters remain poorly understood. However, cloud properties and pollution concentrations also vary with meteorological state, which poses the challenge of how to disentangle the impact of aerosols on clouds from that of natural thermodynamic variability. In this study we combine measurements from satellite instruments POLDER-3 and MODIS to temporally and spatially co-locate cloud properties over 65º in latitude with carbon monoxide concentrations, passive tracer of aerosol content, from GEOS-Chem between 2005 and 2010. We also add ERA-I reanalysis of meteorological parameters to stratify meteorological parameters, such as specific humidity and lower tropospheric stability. The goal is to determine the extent to which differences in cloud phase can be attributed to differences in aerosol content and not in meteorological parameters.We evaluated the amount of supercooling ΔT50 that is required for 50% of a chosen ensemble of low-level clouds to be in the ice phase. Consistent with Rangno & Hobbs (2001), our results suggest that small droplet effective radii are related to high values of ΔT50. Also, anthropogenic pollution plumes lower the degree of supercooling by approximately 5°C, independent of the decrease in effective radius and change of meteorological regime. This effect of anthropogenic aerosol on the transition temperature to freezing has not been reported before to our knowledge and lacks clear explanation. Rangno, A. L., & Hobbs, P. V. (2001). Ice particles in stratiform clouds in the Arctic and possible mechanisms for the production of high ice concentrations. Journal of geophysical research, 106, 15.

A framework for expanding aqueous chemistry in the Community Multiscale Air Quality (CMAQ) model version 5.1

NASA Astrophysics Data System (ADS)

Fahey, Kathleen M.; Carlton, Annmarie G.; Pye, Havala O. T.; Baek, Jaemeen; Hutzell, William T.; Stanier, Charles O.; Baker, Kirk R.; Wyat Appel, K.; Jaoui, Mohammed; Offenberg, John H.

2017-04-01

This paper describes the development and implementation of an extendable aqueous-phase chemistry option (AQCHEM - KMT(I)) for the Community Multiscale Air Quality (CMAQ) modeling system, version 5.1. Here, the Kinetic PreProcessor (KPP), version 2.2.3, is used to generate a Rosenbrock solver (Rodas3) to integrate the stiff system of ordinary differential equations (ODEs) that describe the mass transfer, chemical kinetics, and scavenging processes of CMAQ clouds. CMAQ's standard cloud chemistry module (AQCHEM) is structurally limited to the treatment of a simple chemical mechanism. This work advances our ability to test and implement more sophisticated aqueous chemical mechanisms in CMAQ and further investigate the impacts of microphysical parameters on cloud chemistry. Box model cloud chemistry simulations were performed to choose efficient solver and tolerance settings, evaluate the implementation of the KPP solver, and assess the direct impacts of alternative solver and kinetic mass transfer on predicted concentrations for a range of scenarios. Month-long CMAQ simulations for winter and summer periods over the US reveal the changes in model predictions due to these cloud module updates within the full chemical transport model. While monthly average CMAQ predictions are not drastically altered between AQCHEM and AQCHEM - KMT, hourly concentration differences can be significant. With added in-cloud secondary organic aerosol (SOA) formation from biogenic epoxides (AQCHEM - KMTI), normalized mean error and bias statistics are slightly improved for 2-methyltetrols and 2-methylglyceric acid at the Research Triangle Park measurement site in North Carolina during the Southern Oxidant and Aerosol Study (SOAS) period. The added in-cloud chemistry leads to a monthly average increase of 11-18 % in cloud SOA at the surface in the eastern United States for June 2013.

An assessment of seabird influence on Arctic coastal benthic communities

NASA Astrophysics Data System (ADS)

Zmudczyńska-Skarbek, Katarzyna; Balazy, Piotr; Kuklinski, Piotr

2015-04-01

It is well recognized that seabirds, particularly those nesting in coastal colonies, can provide significant nutrient enrichment to Arctic terrestrial ecosystems. However, little is known about the fate of bird-derived nutrients that return to the marine environment and potentially concentrate below the colonies. To attempt to assess the influence of this potential nutrient enrichment of the coastal benthic community, samples of macroalgae, sea urchins (mainly algivores), and hermit crabs (scavengers) were collected at two Arctic localities (Spitsbergen), (1) below a mixed colony of guillemots and kittiwakes, and (2) in an adjacent geomorphologically similar location not influenced by the seabird colony. A much higher nitrogen stable isotope ratio (δ15N) and total nitrogen content were found in terrestrial plants sampled below the colony than away from it. In benthic macroalgae, however, there were no δ15N differences. This might result from the timing of an intensive growth period in macroalgae in late winter/early spring, when there is little or no runoff from the land, and/or ornithogenic nutrients being directly incorporated by phytoplankton. Sea urchins showed higher δ15N and total N in the control site comparing to the colony-influenced area, suggesting differential food sources in their diet and a role of scavenging/carnivory on higher trophic levels there. Opportunistically feeding hermit crabs showed δ15N and total N enrichment below the seabird colony, suggesting dependence on detritus derived from food chains originating from pelagic producers. Our results indicate that seabirds in the Arctic may fertilize coastal benthic communities through pelagic-benthic coupling, while having no direct impact on bottom primary production.

Water in dense molecular clouds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wannier, P.G.; Kuiper, T.B.H.; Frerking, M.A.

1991-08-01

The G.P. Kuiper Airborne Observatory (KAO) was used to make initial observations of the half-millimeter ground-state transition of water in seven giant molecular clouds and in two late-type stars. No significant detections were made, and the resulting upper limits are significantly below those expected from other, indirect observations and from several theoretical models. The implied interstellar H2O/CO abundance is less than 0.003 in the cores of three giant molecular clouds. This value is less than expected from cloud chemistry models and also than estimates based on HDO and H3O(+) observations. 78 refs.

The Impact of Aerosols on Cloud and Precipitation Processes: Cloud-Resolving Model Simulations

NASA Technical Reports Server (NTRS)

Tao, Wei-Kuo; Li, X.; Khain, A.; Simpson, S.

2005-01-01

Cloud microphysics are inevitable affected by the smoke particle (CCN, cloud condensation nuclei) size distributions below the clouds, Therefore, size distributions parameterized as spectral bin microphysics are needed to explicitly study the effect of atmospheric aerosol concentration on cloud development, rainfall production, and rainfall rates for convective clouds. Recently, a detailed spectral-bin microphysical scheme was implemented into the the Goddard Cumulus Ensemble (GCE) model. The formulation for the explicit spectral-bim microphysical processes is based on solving stochastic kinetic equations for the size distribution functions of water droplets (i.e., cloud droplets and raindrops), and several types of ice particles [i.e., pristine ice crystals (columnar and plate-like), snow (dendrites and aggregates), graupel and frozen drops/hail]. Each type is described by a special size distribution function containing many categories (i.e., 33 bins). Atmospheric aerosols are also described using number density size-distribution functions.

CloudSat First Image of a Warm Front Storm Over the Norwegian Sea

NASA Technical Reports Server (NTRS)

2006-01-01

[figure removed for brevity, see original site] Figure 1

CloudSat's first image, of a warm front storm over the Norwegian Sea, was obtained on May 20, 2006. In this horizontal cross-section of clouds, warm air is seen rising over colder air as the satellite travels from right to left. The red colors are indicative of highly reflective particles such as water droplets (or rain) or larger ice crystals (or snow), while the blue indicates thinner clouds (such as cirrus). The flat green/blue lines across the bottom represent the ground signal. The vertical scale on the CloudSat Cloud Profiling Radar image is approximately 30 kilometers (19 miles). The blue line below the Cloud Profiling Radar image indicates that the data were taken over water. The inset image shows the CloudSat track relative to a Moderate Resolution Imaging Spectroradiometer (MODIS) infrared image taken at nearly the same time.

DMSP Special Sensor Microwave/Imager Calibration/Validation. Volume 1

DTIC Science & Technology

1990-01-01

each channel samples the hot load on every scan and commands a gain change up when the hot load is below 7/16th of the analog to digital converter range...OLS imagery. A threshold blanking technique was used to convert the manual analyses into synthetic digital images containing the cloud truth...should include OLS digital thermal infrared into the analysis. While this will be of use only in clear, relatively dry atmospheric conditions, the

Scavenging of black carbon in Chilean coastal fogs.

PubMed

Heintzenberg, Jost; Cereceda-Balic, Francisco; Vidal, Victor; Leck, Caroline

2016-01-15

In November/December 2013 a pilot experiment on aerosol/fog interaction was conducted on a coastal hill in the suburbs of Valparaíso, Chile. Passages of garúa fog were monitored with continuous recordings of a soot photometer and an optical aerosol spectrometer. An optical fog sensor and an automatic weather station provided meteorological data with which the aerosol could be classified. High-resolution back trajectories added meteorological information. From filter samples, optical and chemical aerosol information was derived. Scavenging coefficients of black carbon (BC) and measured particulate mass below 1 μm diameter (PM1) were estimated with three approaches. Averaging over all fog periods of the campaign yielded a scavenging coefficient of only 6% for BC and 40% for PM1. Dividing the data into four 90°-wind sectors gave scavenging factors for BC ranging from 13% over the Valparaíso, Viña del Mar conurbation to 50% in the marine sector (180°-270°). The third, and independent approach was achieved with two pairs of chemical aerosol samples taken inside and outside fogs, which yielded a scavenging coefficient of 25% for BC and 70% for nonseasalt sulfate. Whereas fogs occurred rather infrequently in the beginning of the campaign highly regular daily fog cycles appeared towards the end of the experiment, which allowed the calculation of typical diurnal cycles of the aerosol in relation to a fog passage. Copyright © 2015 Elsevier B.V. All rights reserved.

The chemical composition of fogs and intercepted clouds in the United States

NASA Astrophysics Data System (ADS)

Collett, Jeffrey L.; Bator, Aaron; Sherman, D. Eli; Moore, Katharine F.; Hoag, Katherine J.; Demoz, Belay B.; Rao, Xin; Reilly, Jill E.

Over the past decade, the chemical compositions of fogs and intercepted clouds have been investigated at more than a dozen locations across the United States. Sampling sites have been located in the northeast, southeast, Rocky Mountain, and west coast regions of the US. They include both pristine and heavily polluted locations. Frontal/orographic clouds (warm and supercooled), intercepted coastal stratiform clouds, and radiation fogs have all been examined. Sample pH values range from below 3 to above 7. Major ions also exhibit a wide concentration range, with clouds at some locations exhibiting high sea salt concentrations, while composition at other locations is dominated by ammonium and sulfate or nitrate.

Constraints on the Longevity of the 2010 Eyjaföll Eruption Cloud From Analog Experiments and Modeling

NASA Astrophysics Data System (ADS)

Carazzo, G.; Jellinek, M.

2010-12-01

The prolonged disruption of global air travel as a result of the 2010 Eyjafjöll eruption in Iceland underscores the value of discerning the dynamics of volcanic ash-clouds in the atmosphere. Understanding the longevity of these clouds is a particularly long standing problem that bears not only on volcanic hazards to humans but also on the nature and time scale of volcanic forcings on climate change. Since early work on the subject, the common practice to tackle the problem of cloud longevity has been to account for the dynamics of sedimentation by individual particle settling. We use 1D modeling and analog experiments of a turbulent particle-laden umbrella cloud to show that this classical view can be misleading and that the residence times of these ash-clouds in the atmosphere depends strongly on the collective behavior of the solid fraction. Diffusive convection driven by the differential diffusion of constituents altering the cloud density (ash, temperature, sulfur dioxide) may enhance particle scavenging and extend the cloud longevity over time scales orders of magnitude longer than currently expected (i.e., years rather than days for powerful eruptions). Records of this behavior can be found in real-time measurements of stratospheric post-volcanic aerosols following the 1974 Fuego, the 1982 El Chichon, the 1991 Hudson and Pinatubo events, and more recently, from the 14 April 2010 Eyjafjöll eruption. The importance of diffusive convection in volcanic ash-clouds depends strongly on particle size distribution and concentration. For the 2010 Eyjafjöll eruption, we predict that particles larger than 10 microns should settle individually as commonly assumed, but particles smaller than 1 micron should diffuse slowly in layers extending the cloud longevity to several weeks rather than days. These predictions are found to be in good agreement with a number of satellite and ground-based lidar data on ash size and mass estimates performed at different locations across Europe.

Water clouds and dust aerosols observations with PFS MEX at Mars

NASA Astrophysics Data System (ADS)

Zasova, L.; Formisano, V.; Moroz, V.; Grassi, D.; Ignatiev, N.; Giuranna, M.; Hansen, G.; Blecka, M.; Ekonomov, A.; Lellouch, E.; Fonti, S.; Grigoriev, A.; Hirsch, H.; Khatuntsev, I.; Mattana, A.; Maturilli, A.; Moshkin, B.; Patsaev, D.; Piccioni, G.; Rataj, M.; Saggin, B.

2005-08-01

Observations of water ice clouds and dust are among the main scientific goals of the Planetary Fourier Spectrometer (PFS), a payload instrument of the European Mars Express mission. We report some results, obtained in three orbits: 37, 41 and 68. The temperature profile, and dust and water ice cloud opacities are retrieved from the thermal infrared (long-wavelength channel of PFS) in a self-consistent way using the same spectrum. Orographic ice clouds are identified above Olympus (orbit 37) and Ascraeus Mons (orbit 68). Both volcanoes were observed near noon at Ls=337° and 342°, respectively. The effective radius of ice particles is preliminary estimated as 1-3 μm, changing along the flanks. The corresponding visual opacity changes in the interval 0.2-0.4 above Olympus and 0.1-0.6 above Ascraeus Mons. In the case of Ascraeus Mons, the ice clouds were observed mainly above the Southern flank of the volcano with maximum opacity near the summit. In the case of Olympus, the clouds were found above both sides of the top. A different type of ice cloud is observed at latitudes above 50°N (orbit 68) in the polar hood: the effective particle radius is estimated to be 4 μm. Below the 1 mb level an inversion in the temperature profiles is found with maximum temperature at around 0.6 mb. Along orbit 68 it appears above Alba Patera, then it increases to the north and decreases above the CO 2 polar cap. Beginning from latitude 20°S above Tharsis (orbit 68), the ice clouds and dust contribute equally to the spectral shape. Further on, the ice clouds are found everywhere along orbit 68 up to the Northern polar cap, except the areas between the Northern flank of Ascraeus Mons (below 10 km) and the edge of Alba Patera. Orbit 41 is shifted from the orbit 68 by roughly 180° longitude and passes through Hellas. Ice clouds are not visible in this orbit at latitudes below 80°S. The dust opacity is anticorrelated with the surface altitude. From 70°S to 25°N latitude the vertical dust distribution follows an exponential law with a scale height of 11.5±0.5 km, which corresponds to the gaseous scale height near noon and indicates a well-mixed condition. The 9 μm dust opacity, reduced to zero surface altitude, is found to be 0.25±0.05, which corresponds to a visual opacity of 0.5-0.7 (depending on the particle size).

UV Raman lidar measurements of relative humidity for the characterization of cirrus cloud microphysical properties

NASA Astrophysics Data System (ADS)

di Girolamo, P.; Summa, D.; Lin, R.-F.; Maestri, T.; Rizzi, R.; Masiello, G.

2009-11-01

Raman lidar measurements performed in Potenza by the Raman lidar system BASIL in the presence of cirrus clouds are discussed. Measurements were performed on 6 September 2004 in the frame of the Italian phase of the EAQUATE Experiment. The major feature of BASIL is represented by its capability to perform high-resolution and accurate measurements of atmospheric temperature and water vapour, and consequently relative humidity, both in daytime and night-time, based on the application of the rotational and vibrational Raman lidar techniques in the UV. BASIL is also capable to provide measurements of the particle backscatter and extinction coefficient, and consequently lidar ratio (at the time of these measurements, only at one wavelength), which are fundamental to infer geometrical and microphysical properties of clouds. A case study is discussed in order to assess the capability of Raman lidars to measure humidity in presence of cirrus clouds, both below and inside the cloud. While air inside the cloud layers is observed to be always under-saturated with respect to water, both ice super-saturation and under-saturation conditions are found inside these clouds. Upper tropospheric moistening is observed below the lower cloud layer. The synergic use of the data derived from the ground based Raman Lidar and of spectral radiances measured by the NAST-I Airborne Spectrometer allows the determination of the temporal evolution of the atmospheric cooling/heating rates due to the presence of the cirrus cloud. Lidar measurements beneath the cirrus cloud layer have been interpreted using a 1-D cirrus cloud model with explicit microphysics. The 1-D simulations indicate that sedimentation-moistening has contributed significantly to the moist anomaly, but other mechanisms are also contributing. This result supports the hypothesis that the observed mid-tropospheric humidification is a real feature which is strongly influenced by the sublimation of precipitating ice crystals. Results illustrated in this study demonstrate that Raman lidars, like the one used in this study, can resolve the spatial and temporal scales required for the study of cirrus cloud microphysical processes and appear sensitive enough to reveal and quantify upper tropospheric humidification associated with cirrus cloud sublimation.

UV Raman lidar measurements of relative humidity for the characterization of cirrus cloud microphysical properties

NASA Astrophysics Data System (ADS)

di Girolamo, P.; Summa, D.; Lin, R.-F.; Maestri, T.; Rizzi, R.; Masiello, G.

2009-07-01

Raman lidar measurements performed in Potenza by the Raman lidar system BASIL in the presence of cirrus clouds are discussed. Measurements were performed on 6 September 2004 in the frame of Italian phase of the EAQUATE Experiment. The major feature of BASIL is represented by its capability to perform high-resolution and accurate measurements of atmospheric temperature and water vapour, and consequently relative humidity, both in daytime and night-time, based on the application of the rotational and vibrational Raman lidar techniques in the UV. BASIL is also capable to provide measurements of the particle backscatter and extinction coefficient, and consequently lidar ratio (at the time of these measurements only at one wavelength), which are fundamental to infer geometrical and microphysical properties of clouds. A case study is discussed in order to assess the capability of Raman lidars to measure humidity in presence of cirrus clouds, both below and inside the cloud. While air inside the cloud layers is observed to be always under-saturated with respect to water, both ice super-saturation and under-saturation conditions are found inside these clouds. Upper tropospheric moistening is observed below the lower cloud layer. The synergic use of the data derived from the ground based Raman Lidar and of spectral radiances measured by the NAST-I Airborne Spectrometer allows to determine the temporal evolution of the atmospheric cooling/heating rates due to the presence of the cirrus cloud anvil. Lidar measurements beneath the cirrus cloud layer have been interpreted using a 1-D cirrus cloud model with explicit microphysics. The 1-D simulations indicates that sedimentation-moistening has contributed significantly to the moist anomaly, but other mechanisms are also contributing. This result supports the hypothesis that the observed mid-tropospheric humidification is a real feature which is strongly influenced by the sublimation of precipitating ice crystals. Results illustrated in this study demonstrate that Raman lidars, like the one used in this study, can resolve the spatial and temporal scales required for the study of cirrus cloud microphysical processes and appears sensitive enough to reveal and quantify upper tropospheric humidification associated with cirrus cloud sublimation.

Radiative transfer in shallow cumulus cloud fields: Observations and first analysis with the Diram instrument during the BBC-2 field campaign in May 2003

NASA Astrophysics Data System (ADS)

van Dop, Han; Wilson, Keith M.

2006-11-01

The cloud albedo is a crucial parameter in radiation budget studies, and is one of the main forcings in climate. We have designed and made a device, Diram (directional radiance distribution measurement device), which not only measures reflection and transmission of solar radiation through clouds, but which also determines the radiance distribution. The construction contains 42 sensors, consisting of a collimation system and a detector, which are mounted in two domes (21 in each). The collimators reduce the field of view of each sensor to ˜7°. The domes were mounted on top and below of the Meteo France Merlin IV research aircraft. The 42 signals were continuously logged with a frequency of 10 Hz during a number of flights in the framework of the Baltex Bridge-2 campaign at Cabauw (The Netherlands) in May 2003. The Diram instrument provided radiances during in situ observations of cumulus and (broken) stratocumulus clouds and detected anisotropic effects in solar radiation scattered by clouds which are due to different cloud geometries and which are related to microphysical cloud properties. Microphysical cloud properties were obtained from the Gerber PVM100A optical sensor aboard the aircraft. Liquid water content and particle surface area were logged with a frequency of 200 Hz. Data have been collected from a total of 10 days in different weather conditions (clear sky, broken cumulus, stratocumulus and multilayered cloud). A clear sky test of the Diram indicated that the device was able to reproduce the Rayleigh scattering pattern. During flights in stratocumulus fields, strongly anisotropic patterns were observed. The DIRAM observations confirm that in thin clouds a strong preference for forward scattering is observed in the transmitted radiation field while for thicker clouds the pattern becomes more isotropic, with a slightly brighter centre relative to the limb direction.

Influence of Saharan dust on cloud glaciation in southern Morocco during the Saharan Mineral Dust Experiment

NASA Astrophysics Data System (ADS)

Ansmann, A.; Tesche, M.; Althausen, D.; Müller, D.; Seifert, P.; Freudenthaler, V.; Heese, B.; Wiegner, M.; Pisani, G.; Knippertz, P.; Dubovik, O.

2008-02-01

Multiwavelength lidar, Sun photometer, and radiosonde observations were conducted at Ouarzazate (30.9°N, 6.9°W, 1133 m above sea level, asl), Morocco, in the framework of the Saharan Mineral Dust Experiment (SAMUM) in May-June 2006. The field site is close to the Saharan desert. Information on the depolarization ratio, backscatter and extinction coefficients, and lidar ratio of the dust particles, estimates of the available concentration of atmospheric ice nuclei at cloud level, profiles of temperature, humidity, and the horizontal wind vector as well as backward trajectory analysis are used to study cases of cloud formation in the dust with focus on heterogeneous ice formation. Surprisingly, most of the altocumulus clouds that form at the top of the Saharan dust layer, which reaches into heights of 4-7 km asl and has layer top temperatures of -8°C to -18°C, do not show any ice formation. According to the lidar observations the presence of a high number of ice nuclei (1-20 cm-3) does not automatically result in the obvious generation of ice particles, but the observations indicate that cloud top temperatures must typically reach values as low as -20°C before significant ice production starts. Another main finding is that liquid clouds are obviously required before ice crystals form via heterogeneous freezing mechanisms, and, as a consequence, that deposition freezing is not an important ice nucleation process. An interesting case with cloud seeding in the free troposphere above the dust layer is presented in addition. Small water clouds formed at about -30°C and produced ice virga. These virga reached water cloud layers several kilometers below the initiating cloud cells and caused strong ice production in these clouds at temperatures as high as -12°C to -15°C.

Effect of selected organic and inorganic snow and cloud components on the photochemical generation of nitrite by nitrate irradiation.

PubMed

Minero, Claudio; Maurino, Valter; Bono, Francesca; Pelizzetti, Ezio; Marinoni, Angela; Mailhot, Gilles; Carlotti, Maria Eugenia; Vione, Davide

2007-08-01

The effect of selected organic and inorganic compounds, present in snow and cloudwater was studied. Photolysis of solutions of nitrate to nitrite was carried out in the laboratory using a UVB light source. The photolysis and other reactions were then modelled. It is shown that formate, formaldehyde, methanesulphonate, and chloride to a lesser extent, can increase the initial formation rate of nitrite. The effect, particularly significant for formate and formaldehyde, is unlikely to be caused by scavenging of hydroxyl radicals. The experimental data obtained in this work suggest that possible causes are the reduction of nitrogen dioxide and nitrate by radical species formed on photooxidation of the organic compounds. Hydroxyl scavenging by organic and inorganic compounds would not affect the initial formation rate of nitrite, but would protect it from oxidation, therefore, increasing the concentration values reached at long irradiation times. The described processes can be relevant to cloudwater and the quasi-liquid layer on the surface of ice and snow, considering that in the polar regions irradiated snow layers are important sources of nitrous acid to the atmosphere. Formate and (at a lesser extent) formaldehyde are the compounds that play the major role in the described processes of nitrite/nitrous acid photoformation by initial rate enhancement and hydroxyl scavenging.

Retrieving Neptune's aerosol properties from Keck OSIRIS observations. I. Dark regions

NASA Astrophysics Data System (ADS)

Luszcz-Cook, S. H.; de Kleer, K.; de Pater, I.; Adamkovics, M.; Hammel, H. B.

2016-09-01

We present and analyze three-dimensional data cubes of Neptune from the OSIRIS integral-field spectrograph on the 10-m W.M. Keck II telescope, from 26 July 2009. These data have a spatial resolution of 0.035/pixel and spectral resolution of R ∼3800 in the H (1.47-1.80 μm) and K (1.97-2.38 μm) broad bands. We focus our analysis on regions of Neptune's atmosphere that are near-infrared dark - that is, free of discrete bright cloud features. We use a forward model coupled to a Markov chain Monte Carlo algorithm to retrieve properties of Neptune's aerosol structure and methane profile above ∼4 bar in these near-infrared dark regions. We construct a set of high signal-to-noise spectra spanning a range of viewing geometries to constrain the vertical structure of Neptune's aerosols in a cloud-free latitude band from 2-12°N. We find that Neptune's cloud opacity at these wavelengths is dominated by a compact, optically thick cloud layer with a base near 3 bar. Using the pyDISORT algorithm for the radiative transfer and assuming a Henyey-Greenstein phase function, we observe this cloud to be composed of low albedo (single scattering albedo = 0.45-0.01+0.01), forward scattering (asymmetry parameter g = 0.50-0.02+0.02) particles, with an assumed characteristic size of ∼1μm. Above this cloud, we require an aerosol layer of smaller (∼0.1μm) particles forming a vertically extended haze, which reaches from the upper troposphere (0.59-0.03+0.04 bar) into the stratosphere. The particles in this haze are brighter (single scattering albedo = 0.91-0.05+0.06) and more isotropically scattering (asymmetry parameter g = 0.24-0.03+0.02) than those in the deep cloud. When we extend our analysis to 18 cloud-free locations from 20°N to 87°S, we observe that the optical depth in aerosols above 0.5 bar decreases by a factor of 2-3 or more at mid- and high-southern latitudes relative to low latitudes. We also consider Neptune's methane (CH4) profile, and find that our retrievals indicate a strong preference for a low methane relative humidity at pressures where methane is expected to condense. When we include in our fits a parameter for methane depletion below the CH4 condensation pressure, our preferred solution at most locations is for a methane relative humidity below 10% near the tropopause in addition to methane depletion down to 2.0-2.5 bar. We tentatively identify a trend of lower CH4 columns above 2.5 bar at mid- and high-southern latitudes over low latitudes, qualitatively consistent with what is found by Karkoschka and Tomasko (2011), and similar to, but weaker than, the trend observed for Uranus.

Characterization of AVHRR global cloud detection sensitivity based on CALIPSO-CALIOP cloud optical thickness information: demonstration of results based on the CM SAF CLARA-A2 climate data record

NASA Astrophysics Data System (ADS)

Karlsson, Karl-Göran; Håkansson, Nina

2018-02-01

The sensitivity in detecting thin clouds of the cloud screening method being used in the CM SAF cloud, albedo and surface radiation data set from AVHRR data (CLARA-A2) cloud climate data record (CDR) has been evaluated using cloud information from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) onboard the CALIPSO satellite. The sensitivity, including its global variation, has been studied based on collocations of Advanced Very High Resolution Radiometer (AVHRR) and CALIOP measurements over a 10-year period (2006-2015). The cloud detection sensitivity has been defined as the minimum cloud optical thickness for which 50 % of clouds could be detected, with the global average sensitivity estimated to be 0.225. After using this value to reduce the CALIOP cloud mask (i.e. clouds with optical thickness below this threshold were interpreted as cloud-free cases), cloudiness results were found to be basically unbiased over most of the globe except over the polar regions where a considerable underestimation of cloudiness could be seen during the polar winter. The overall probability of detecting clouds in the polar winter could be as low as 50 % over the highest and coldest parts of Greenland and Antarctica, showing that a large fraction of optically thick clouds also remains undetected here. The study included an in-depth analysis of the probability of detecting a cloud as a function of the vertically integrated cloud optical thickness as well as of the cloud's geographical position. Best results were achieved over oceanic surfaces at mid- to high latitudes where at least 50 % of all clouds with an optical thickness down to a value of 0.075 were detected. Corresponding cloud detection sensitivities over land surfaces outside of the polar regions were generally larger than 0.2 with maximum values of approximately 0.5 over the Sahara and the Arabian Peninsula. For polar land surfaces the values were close to 1 or higher with maximum values of 4.5 for the parts with the highest altitudes over Greenland and Antarctica. It is suggested to quantify the detection performance of other CDRs in terms of a sensitivity threshold of cloud optical thickness, which can be estimated using active lidar observations. Validation results are proposed to be used in Cloud Feedback Model Intercomparison Project (CFMIP) Observation Simulation Package (COSP) simulators for cloud detection characterization of various cloud CDRs from passive imagery.

Exploiting Cloud Radar Doppler Spectra of Mixed-Phase Clouds during ACCEPT Field Experiment to Identify Microphysical Processes

NASA Astrophysics Data System (ADS)

Kalesse, H.; Myagkov, A.; Seifert, P.; Buehl, J.

2015-12-01

Cloud radar Doppler spectra offer much information about cloud processes. By analyzing millimeter radar Doppler spectra from cloud-top to -base in mixed-phase clouds in which super-cooled liquid-layers are present we try to tell the microphysical evolution story of particles that are present by disentangling the contributions of the solid and liquid particles to the total radar returns. Instead of considering vertical profiles, dynamical effects are taken into account by following the particle population evolution along slanted paths which are caused by horizontal advection of the cloud. The goal is to identify regions in which different microphysical processes such as new particle formation (nucleation), water vapor deposition, aggregation, riming, or sublimation occurr. Cloud radar measurements are supplemented by Doppler lidar and Raman lidar observations as well as observations with MWR, wind profiler, and radio sondes. The presence of super-cooled liquid layers is identified by positive liquid water paths in MWR measurements, the vertical location of liquid layers (in non-raining systems and below lidar extinction) is derived from regions of high-backscatter and low depolarization in Raman lidar observations. In collocated cloud radar measurements, we try to identify cloud phase in the cloud radar Doppler spectrum via location of the Doppler peak(s), the existence of multi-modalities or the spectral skewness. Additionally, within the super-cooled liquid layers, the radar-identified liquid droplets are used as air motion tracer to correct the radar Doppler spectrum for vertical air motion w. These radar-derived estimates of w are validated by independent estimates of w from collocated Doppler lidar measurements. A 35 GHz vertically pointing cloud Doppler radar (METEK MIRA-35) in linear depolarization (LDR) mode is used. Data is from the deployment of the Leipzig Aerosol and Cloud Remote Observations System (LACROS) during the Analysis of the Composition of Clouds with Extended Polarization Techniques (ACCEPT) field experiment in Cabauw, Netherlands in Fall 2014. There, another MIRA-35 was operated in simultaneous transmission and simultaneous reception (STSR) mode for obtaining measurements of differential reflectivity (ZDR) and correlation coefficient ρhv.

Vertical variation of ice particle size in convective cloud tops.

PubMed

van Diedenhoven, Bastiaan; Fridlind, Ann M; Cairns, Brian; Ackerman, Andrew S; Yorks, John E

2016-05-16

A novel technique is used to estimate derivatives of ice effective radius with respect to height near convective cloud tops ( dr e / dz ) from airborne shortwave reflectance measurements and lidar. Values of dr e / dz are about -6 μ m/km for cloud tops below the homogeneous freezing level, increasing to near 0 μ m/km above the estimated level of neutral buoyancy. Retrieved dr e / dz compares well with previously documented remote sensing and in situ estimates. Effective radii decrease with increasing cloud top height, while cloud top extinction increases. This is consistent with weaker size sorting in high, dense cloud tops above the level of neutral buoyancy where fewer large particles are present, and with stronger size sorting in lower cloud tops that are less dense. The results also confirm that cloud-top trends of effective radius can generally be used as surrogates for trends with height within convective cloud tops. These results provide valuable observational targets for model evaluation.

Vertical Variation of Ice Particle Size in Convective Cloud Tops

NASA Technical Reports Server (NTRS)

Van Diedenhoven, Bastiaan; Fridlind, Ann M.; Cairns, Brian; Ackerman, Andrew S.; Yorks, John E.

2016-01-01

A novel technique is used to estimate derivatives of ice effective radius with respect to height near convective cloud tops (dr(sub e)/dz) from airborne shortwave reflectance measurements and lidar. Values of dr(sub e)/dz are about -6 micrometer/km for cloud tops below the homogeneous freezing level, increasing to near 0 micrometer/km above the estimated level of neutral buoyancy. Retrieved dr(sub e)/dz compares well with previously documented remote sensing and in situ estimates. Effective radii decrease with increasing cloud top height, while cloud top extinction increases. This is consistent with weaker size sorting in high, dense cloud tops above the level of neutral buoyancy where fewer large particles are present and with stronger size sorting in lower cloud tops that are less dense. The results also confirm that cloud top trends of effective radius can generally be used as surrogates for trends with height within convective cloud tops. These results provide valuable observational targets for model evaluation.

Entrainment in Laboratory Simulations of Cumulus Cloud Flows

NASA Astrophysics Data System (ADS)

Narasimha, R.; Diwan, S.; Subrahmanyam, D.; Sreenivas, K. R.; Bhat, G. S.

2010-12-01

A variety of cumulus cloud flows, including congestus (both shallow bubble and tall tower types), mediocris and fractus have been generated in a water tank by simulating the release of latent heat in real clouds. The simulation is achieved through ohmic heating, injected volumetrically into the flow by applying suitable voltages between diametral cross-sections of starting jets and plumes of electrically conducting fluid (acidified water). Dynamical similarity between atmospheric and laboratory cloud flows is achieved by duplicating values of an appropriate non-dimensional heat release number. Velocity measurements, made by laser instrumentation, show that the Taylor entrainment coefficient generally increases just above the level of commencement of heat injection (corresponding to condensation level in the real cloud). Subsequently the coefficient reaches a maximum before declining to the very low values that characterize tall cumulus towers. The experiments also simulate the protected core of real clouds. Cumulus Congestus : Atmospheric cloud (left), simulated laboratory cloud (right). Panels below show respectively total heat injected and vertical profile of heating in the laboratory cloud.

The global aerosol-climate model ECHAM-HAM, version 2: sensitivity to improvements in process representations

NASA Astrophysics Data System (ADS)

Zhang, K.; O'Donnell, D.; Kazil, J.; Stier, P.; Kinne, S.; Lohmann, U.; Ferrachat, S.; Croft, B.; Quaas, J.; Wan, H.; Rast, S.; Feichter, J.

2012-03-01

This paper introduces and evaluates the second version of the global aerosol-climate model ECHAM-HAM. Major changes have been brought into the model, including new parameterizations for aerosol nucleation and water uptake, an explicit treatment of secondary organic aerosols, modified emission calculations for sea salt and mineral dust, the coupling of aerosol microphysics to a two-moment stratiform cloud microphysics scheme, and alternative wet scavenging parameterizations. These revisions extend the model's capability to represent details of the aerosol lifecycle and its interaction with climate. Sensitivity experiments are carried out to analyse the effects of these improvements in the process representation on the simulated aerosol properties and global distribution. The new parameterizations that have largest impact on the global mean aerosol optical depth and radiative effects turn out to be the water uptake scheme and cloud microphysics. The former leads to a significant decrease of aerosol water contents in the lower troposphere, and consequently smaller optical depth; the latter results in higher aerosol loading and longer lifetime due to weaker in-cloud scavenging. The combined effects of the new/updated parameterizations are demonstrated by comparing the new model results with those from the earlier version, and against observations. Model simulations are evaluated in terms of aerosol number concentrations against measurements collected from twenty field campaigns as well as from fixed measurement sites, and in terms of optical properties against the AERONET measurements. Results indicate a general improvement with respect to the earlier version. The aerosol size distribution and spatial-temporal variance simulated by HAM2 are in better agreement with the observations. Biases in the earlier model version in aerosol optical depth and in the Ångström parameter have been reduced. The paper also points out the remaining model deficiencies that need to be addressed in the future.

Numerical simulations of Jupiter’s moist convection layer: Structure and dynamics in statistically steady states

NASA Astrophysics Data System (ADS)

Sugiyama, K.; Nakajima, K.; Odaka, M.; Kuramoto, K.; Hayashi, Y.-Y.

2014-02-01

A series of long-term numerical simulations of moist convection in Jupiter’s atmosphere is performed in order to investigate the idealized characteristics of the vertical structure of multi-composition clouds and the convective motions associated with them, varying the deep abundances of condensable gases and the autoconversion time scale, the latter being one of the most questionable parameters in cloud microphysical parameterization. The simulations are conducted using a two-dimensional cloud resolving model that explicitly represents the convective motion and microphysics of the three cloud components, H2O, NH3, and NH4SH imposing a body cooling that substitutes the net radiative cooling. The results are qualitatively similar to those reported in Sugiyama et al. (Sugiyama, K. et al. [2011]. Intermittent cumulonimbus activity breaking the three-layer cloud structure of Jupiter. Geophys. Res. Lett. 38, L13201. doi:10.1029/2011GL047878): stable layers associated with condensation and chemical reaction act as effective dynamical and compositional boundaries, intense cumulonimbus clouds develop with distinct temporal intermittency, and the active transport associated with these clouds results in the establishment of mean vertical profiles of condensates and condensable gases that are distinctly different from the hitherto accepted three-layered structure (e.g., Atreya, S.K., Romani, P.N. [1985]. Photochemistry and clouds of Jupiter, Saturn and Uranus. In: Recent Advances in Planetary Meteorology. Cambridge Univ. Press, London, pp. 17-68). Our results also demonstrate that the period of intermittent cloud activity is roughly proportional to the deep abundance of H2O gas. The autoconversion time scale does not strongly affect the results, except for the vertical profiles of the condensates. Changing the autoconversion time scale by a factor of 100 changes the intermittency period by a factor of less than two, although it causes a dramatic increase in the amount of condensates in the upper troposphere. The moist convection layer becomes potentially unstable with respect to an air parcel rising from below the H2O lifting condensation level (LCL) well before the development of cumulonimbus clouds. The instability accumulates until an appropriate trigger is provided by the H2O condensate that falls down through the H2O LCL; the H2O condensate drives a downward flow below the H2O LCL as a result of the latent cooling associated with the re-evaporation of the condensate, and the returning updrafts carry moist air from below to the moist convection layer. Active cloud development is terminated when the instability is completely exhausted. The period of intermittency is roughly equal to the time obtained by dividing the mean temperature increase, which is caused by active cumulonimbus development, by the body cooling rate.

Lidar observations of high altitude cirrus near the tropical tropopause

NASA Astrophysics Data System (ADS)

Parameswaran, K.; Kumar, S. Sunil; Krishna Murthy, B.

High altitude cirrus plays a significant role in atmospheric chemistry, radiation and troposphere-stratosphere exchanges. Studies on their global morphology using satellite data (SAGE) suggests that over the tropics these clouds occur quite frequently in the altitude region around 14 to 16 km with favoured locations centred over Southern Asia, India and Mexico. A monostatic Nd:YAG lidar (operating at 532 nm wavelength) located at National MST Radar Facility (NMRF), Gadanki (13.5°N, 79.2°E) provides an excellent opportunity to study the properties of these clouds. Lidar observations for ~120 nights during the period January 1999 to March 2000 are used to investigate the physical and optical properties of these clouds aswell as their spatial (altitude) and temporal variability. Based on optical depth ( c ) cirrus clouds are classified as Sub-visual Cirrus (SVC) with c 0.03, Thin Cirrus (TC) with 0.030.3. While SVCs are observed anywhere in the altitude region 12 to 18 km, with favoured altitude above 15 km, TCs and DCs usually occur around 14.5+/-1km. The altitude region 14 to 16km appears to be more conducive for cirrus formation. Even though the geometrical thickness (vertical extent) of these clouds varies from 0.3 to 3 km, they are mostly confined to altitudes below the level of tropopause temperature inversion. The cloud optical depth maximises around the post-mid-night period. These clouds also introduce significant depolarisation for the backscattered radiation indicating presence of abundant non-spherical particles presumably ice-crystals. Under favourable conditions these ice-crystals get aligned horizontally to enhance the co - polarized component of lidar backscatter signal through specular reflection, leading to a decrease in cloud depolarisation () below the ambient molecular depolarisation (m ). Such conditions are usually encountered in the case of optically dense clouds. Altitude profile of backscatter ratio within the cloud shows that the cloud is not optically symmetric with respect to the geometric centre. This asymmetry parameter () of the cloud shows significant temporal variability. For clouds with> m , as c increases, the optical centre descends in altitude and for clouds with< m the optical centre ascends as c increases. Occurrence of cirrus clouds and their optical properties are found to be closely associated with the characteristics of atmospheric turbulence in the upper troposphere.

The acceleration of dissolved cobalt's ecological stoichiometry due to biological uptake, remineralization, and scavenging in the Atlantic Ocean

NASA Astrophysics Data System (ADS)

Saito, Mak A.; Noble, Abigail E.; Hawco, Nicholas; Twining, Benjamin S.; Ohnemus, Daniel C.; John, Seth G.; Lam, Phoebe; Conway, Tim M.; Johnson, Rod; Moran, Dawn; McIlvin, Matthew

2017-10-01

The stoichiometry of biological components and their influence on dissolved distributions have long been of interest in the study of the oceans. Cobalt has the smallest oceanic inventory of inorganic micronutrients and hence is particularly vulnerable to influence by internal oceanic processes including euphotic zone uptake, remineralization, and scavenging. Here we observe not only large variations in dCo : P stoichiometry but also the acceleration of those dCo : P ratios in the upper water column in response to several environmental processes. The ecological stoichiometry of total dissolved cobalt (dCo) was examined using data from a US North Atlantic GEOTRACES transect and from a zonal South Atlantic GEOTRACES-compliant transect (GA03/3e and GAc01) by Redfieldian analysis of its statistical relationships with the macronutrient phosphate. Trends in the dissolved cobalt to phosphate (dCo : P) stoichiometric relationships were evident in the basin-scale vertical structure of cobalt, with positive dCo : P slopes in the euphotic zone and negative slopes found in the ocean interior and in coastal environments. The euphotic positive slopes were often found to accelerate towards the surface and this was interpreted as being due to the combined influence of depleted phosphate, phosphorus-sparing (conserving) mechanisms, increased alkaline phosphatase metalloenzyme production (a zinc or perhaps cobalt enzyme), and biochemical substitution of Co for depleted Zn. Consistent with this, dissolved Zn (dZn) was found to be drawn down to only 2-fold more than dCo, despite being more than 18-fold more abundant in the ocean interior. Particulate cobalt concentrations increased in abundance from the base of the euphotic zone to become ˜ 10 % of the overall cobalt inventory in the upper euphotic zone with high stoichiometric values of ˜ 400 µmol Co mol-1 P. Metaproteomic results from the Bermuda Atlantic Time-series Study (BATS) station found cyanobacterial isoforms of the alkaline phosphatase enzyme to be prevalent in the upper water column, as well as a sulfolipid biosynthesis protein indicative of P sparing. The negative dCo : P relationships in the ocean interior became increasingly vertical with depth, and were consistent with the sum of scavenging and remineralization processes (as shown by their dCo : P vector sums). Attenuation of the remineralization with depth resulted in the increasingly vertical dCo : P relationships. Analysis of particulate Co with particulate Mn and particulate phosphate also showed positive linear relationships below the euphotic zone, consistent with the presence and increased relative influence of Mn oxide particles involved in scavenging. Visualization of dCo : P slopes across an ocean section revealed hotspots of scavenging and remineralization, such as at the hydrothermal vents and below the oxygen minimum zone (OMZ) region, respectively, while that of an estimate of Co* illustrated stoichiometrically depleted values in the mesopelagic and deep ocean due to scavenging. This study provides insights into the coupling between the dissolved and particulate phase that ultimately creates Redfield stoichiometric ratios, demonstrating that the coupling is not an instantaneous process and is influenced by the element inventory and rate of exchange between phases. Cobalt's small water column inventory and the influence of external factors on its biotic stoichiometry can erode its limited inertia and result in an acceleration of the dissolved stoichiometry towards that of the particulate phase in the upper euphotic zone. As human use of cobalt grows exponentially with widespread adoption of lithium ion batteries, there is a potential to affect the limited biogeochemical inertia of cobalt and its resultant ecology in the oceanic euphotic zone.

Reduction and analysis of seasons 15 and 16 (1991 - 1992) Pioneer Venus radio occultation data and correlative studies with observations of the near-infrared emission of Venus

NASA Technical Reports Server (NTRS)

Jenkins, Jon M.

1992-01-01

Radio occultation experiments, and radio astronomical observations have suggested that significant variations (both spatial and temporal) in the abundances of sulfur-bearing gases are occurring below the Venus cloud layers. In addition, recent Near Infra-Red images of the nightside of Venus revealed large-scale features which sustain their shape over multiple rotations (the rotation periods of the features are 6.0 +/- 0.5 days). Presumably, the contrast variations in the NIR images are caused by variations in the abundance of large particles in the cloud deck. If these particles are composed of liquid sulfuric acid, one would expect a strong anticorrelation between regions with a high abundance of sulfuric acid vapor, and regions where there are large particles. One technique for monitoring the abundance and distribution of sulfuric acid vapor (H2SO4) at and below the main Venus cloud layer (altitudes below 50 km) is to measure the 13-cm wavelength opacity using Pioneer Venus Orbiter Radio Occultation Studies (PV-ORO). We are working to characterize variations in the abundance and distribution of subcloud H2SO4(g) in the Venus atmosphere by using a number of 13-cm radio occultation measurements conducted with the Pioneer Venus Orbiter near the inferior conjunction of 1991. When retrieved, the vertical profiles of the abundance of H2SO4(g) will be compared and correlated with NIR images of the night side of Venus made during the same period of time. Hopefully, the combination of these two different types of data will make it possible to constrain or identify the composition of the large particles causing the features observed in the NIR images. Considered on their own, however, the parameters retrieved from the radio occultation experiments are valuable science products.

Component analysis and free radicals scavenging activity of Cicer arietinum L. husk pectin.

PubMed

Urias-Orona, Vania; Huerta-Oros, Joselina; Carvajal-Millán, Elizabeth; Lizardi-Mendoza, Jaime; Rascón-Chu, Agustin; Gardea, Alfonso A

2010-10-11

A pectin (CAP) was extracted from the husk of Cicer arietinum L. Monosaccharide analysis of CAP revealed the dominance of galacturonic acid and smaller amounts of galactose, arabinose, rhamnose, glucose, xylose and mannose. Viscosimetric analysis showed that the intrinsic viscosity ([η]) and the molecular weight (MW) of CAP were 296 mL/g and 105 kDa, respectively. The degree of esterification (DE = 10%) was determined by FTIR spectroscopy. CAP exhibited a dose-dependent free radical scavenging activity, as shown by its DPPH radical inhibition. At 1.0 mg/mL CAP exhibited a scavenging rate of 29% on DPPH radicals. The evaluation of antioxidant activity suggested that CAP had good potential for DPPH radical scavenging activity and should be explored as a novel potential antioxidant.

Measured Black Carbon Deposition on the Sierra Nevada Snow Pack and Implication for Snow Pack Retreat

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hadley, O.L.; Corrigan, C.E.; Kirchstetter, T.W.

2010-01-12

Modeling studies show that the darkening of snow and ice by black carbon deposition is a major factor for the rapid disappearance of arctic sea ice, mountain glaciers and snow packs. This study provides one of the first direct measurements for the efficient removal of black carbon from the atmosphere by snow and its subsequent deposition to the snow packs of California. The early melting of the snow packs in the Sierras is one of the contributing factors to the severe water problems in California. BC concentrations in falling snow were measured at two mountain locations and in rain atmore » a coastal site. All three stations reveal large BC concentrations in precipitation, ranging from 1.7 ng/g to 12.9 ng/g. The BC concentrations in the air after the snow fall were negligible suggesting an extremely efficient removal of BC by snow. The data suggest that below cloud scavenging, rather than ice nuclei, was the dominant source of BC in the snow. A five-year comparison of BC, dust, and total fine aerosol mass concentrations at multiple sites reveals that the measurements made at the sampling sites were representative of large scale deposition in the Sierra Nevada. The relative concentration of iron and calcium in the mountain aerosol indicates that one-quarter to one-third of the BC may have been transported from Asia.« less

Comparison of Cell Regeneration Mechanisms Between Isolated Cb Clouds Moving Along A Valley and Over Flat Terrain

NASA Astrophysics Data System (ADS)

Curic, M.; Janc, D.; Vuckovic, V.; Vujovic, D.

Cell regeneration mechanism within air-mass Cb cloud moving along the river valley is investigated by three-dimensional mesoscale ARPS model with improved micro- physics. Simulated cloud characteristics are then compared with those performed for the flat terrain conditions. The Western Morava valley area (Serbia) has selected as an important place for formation of such clouds in agreement with observations. Ana- lyzed results suggest that the river valley plays an important role for the cell regenera- tion mechanism in front of the mother cloud. Futher, it contributes to the fast Cb cloud propagation along the valley. In contrast, the front-side cell regeneration mechanism is absent for the flat terrain conditions since the cold air below cloud base deverges in all directions without any restrictions. This investigation gives us more complete insight in cell regeneration mechanisms than classic approach.

Ortho-para-hydrogen equilibration on Jupiter

NASA Technical Reports Server (NTRS)

Carlson, Barbara E.; Lacis, Andrew A.; Rossow, William B.

1992-01-01

Voyager IRIS observations reveal that the Jovian para-hydrogen fraction is not in thermodynamic equilibrium near the NH3 cloud top, implying that a vertical gradient exists between the high-temperature equilibrium value of 0.25 at depth and the cloud top values. The height-dependent para-hydrogen profile is obtained using an anisotropic multiple-scattering radiative transfer model. A vertical correlation is found to exist between the location of the para-hydrogen gradient and the NH3 cloud, strongly suggesting that paramagnetic conversion on NH3 cloud particle surfaces is the dominant equilibration mechanism. Below the NH3 cloud layer, the para fraction is constant with depth and equal to the high-temperature equilibrium value of 0.25. The degree of cloud-top equilibration appears to depend on the optical depth of the NH3 cloud layer. Belt-zone variations in the para-hydrogen profile seem to be due to differences in the strength of the vertical mixing.

Consistency of ARESE II Cloud Absorption Estimates and Sampling Issues

NASA Technical Reports Server (NTRS)

Oreopoulos, L.; Marshak, A.; Cahalan, R. F.; Lau, William K. M. (Technical Monitor)

2002-01-01

Data from three cloudy days (March 3, 21, 29, 2000) of the ARM Enhanced Shortwave Experiment II (ARESE II) were analyzed. Grand averages of broadband absorptance among three sets of instruments were compared. Fractional solar absorptances were approx. 0.21-0.22 with the exception of March 3 when two sets of instruments gave values smaller by approx. 0.03-0.04. The robustness of these values was investigated by looking into possible sampling problems with the aid of 500 nm spectral fluxes. Grand averages of 500 nm apparent absorptance cover a wide range of values for these three days, namely from a large positive (approx. 0.011) average for March 3, to a small negative (approximately -0.03) for March 21, to near zero (approx. 0.01) for March 29. We present evidence suggesting that a large part of the discrepancies among the three days is due to the different nature of clouds and their non-uniform sampling. Hence, corrections to the grand average broadband absorptance values may be necessary. However, application of the known correction techniques may be precarious due to the sparsity of collocated flux measurements above and below the clouds. Our analysis leads to the conclusion that only March 29 fulfills all requirements for reliable estimates of cloud absorption, that is, the presence of thick, overcast, homogeneous clouds.

A Herschel-SPIRE Survey of the MonR2 Giant Molecular Cloud

NASA Astrophysics Data System (ADS)

Pokhrel, Riwaj; Gutermuth, Robert A.; Ali, Babar; Megeath, S. Thomas; Pipher, Judith; Myers, Philip C.; Fischer, William J.; Henning, Thomas; Wolk, Scott J.; Allen, Lori; Tobin, John J.

2014-06-01

We present a new survey of the MonR2 giant molecular cloud with SPIRE on the Herschel Space Observatory. We cross-calibrated SPIRE data with Planck-HFI and accounted for its absolute offset and zero point correction. We fixed emissivity with the help of flux-error and flux ratio plots. As the best representation of cold dusty molecular clouds, we did greybody fits of the SEDs. We studied the nature of distribution of column densities above and below certain critical limit, followed by the mass and temperature distributions for different regions. We isolated the filaments and studied radial column density profile in this cloud.

Glory over clouds off West Africa

NASA Image and Video Library

2017-12-08

On April 23, 2013 NASA’s Terra satellite passed off the coast of West Africa, allowing the Moderate Resolution Imaging Spectroradiometer (MODIS) flying aboard to capture a curious phenomenon over the cloud deck below. The rainbow-like discoloration that can be seen streaking across the bank of marine cumulus clouds near the center of this image is known as a “glory”. A glory is caused by the scattering of sunlight by a cloud made of water droplets that are all roughly the same size, and is only produced when the light is just right. In order for a glory to be viewed, the observer’s anti-solar point must fall on the cloud deck below. In this case the observer is the Terra satellite, and the anti-solar point is where the sun is directly behind you – 180° from the MODIS line of sight. Water and ice particles in the cloud bend the light, breaking it into all its wavelengths, and the result is colorful flare, which may contain all of the colors of the rainbow. Credit: NASA/GSFC/Jeff Schmaltz/MODIS Land Rapid Response Team NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

The Impact of Aerosols on Cloud and Precipitation Processes: Cloud-Resolving Model Simulations

NASA Technical Reports Server (NTRS)

Tao, Wei-Kuo; Khain, A.; Simpson, S.; Johnson, D.; Li, X.; Remer, L.

2003-01-01

Cloud microphysics are inevitable affected by the smoke particle (CCN, cloud condensation nuclei) size distributions below the clouds. Therefore, size distribution parameterized as spectral bin microphysics are needed to explicitly study the effect of atmospheric aerosol concentration on cloud development, rainfall production, and rainfall rates convective clouds. Recently, two detailed spectral-bin microphysical schemes were implemented into the Goddard Cumulus Ensembel (GCE) model. The formulation for the explicit spectral-bim microphysical processes is based on solving stochastic kinetic equations for the size distribution functions of water droplets (i.e., cloud droplets and raindrops), and several types of ice particles [i.e., pristine ice crystals (columnar and plate-like), snow (dendrites and aggregates), groupel and frozen drops/hall] Each type is described by a special size distribution function containing many categories (i.e., 33 bins). Atmospheric aerosols are also described using number density size-distribution functions.A spectral-bin microphysical model is very expensive from a computational point of view and has only been implemented into the 2D version of the GCE at the present time. The model is tested by studying the evolution of deep cloud systems in the west Pacific warm pool region and in the mid-latitude using identical thermodynamic conditions but with different concentrations of CCN: a low "clean" concentration and a high "dirty" concentration. Besides the initial differences in aerosol concentration, preliminary results indicate that the low CCN concentration case produces rainfall at the surface sooner than the high CCN case but has less cloud water mass aloft. Because the spectral-bim model explicitly calculates and allows for the examination of both the mass and number concentration of cpecies in each size category, a detailed analysis of the instantaneous size spectrum can be obtained for the two cases. It is shown that since the low CCN case produces fever droplets, larger size develop due to greater condencational and collectional growth, leading to a broader size spectrum in comparison to the high CCN case.

The Impact of Aerosols on Cloud and Precipitation Processes: Cloud-Resolving Model Simulations

NASA Technical Reports Server (NTRS)

Tao, Wei-Kuo; Khain, A.; Simpson, S.; Johnson, D.; Li, X.; Remer, L.

2003-01-01

Cloud microphysics are inevitably affected by the smoke particle (CCN, cloud condensation nuclei) size distributions below the clouds. Therefore, size distributions parameterized as spectral bin microphysics are needed to explicitly study the effects of atmospheric aerosol concentration on cloud development, rainfall production, and rainfall rates for convective clouds. Recently, two detailed spectral-bin microphysical schemes were implemented into the Goddard Cumulus Ensemble (GCE) model. The formulation for the explicit spectral-bin microphysical processes is based on solving stochastic kinetic equations for the size distribution functions of water droplets (i.e., cloud droplets and raindrops), and several types of ice particles [i.e.,pristine ice crystals (columnar and plate-like), snow (dendrites and aggregates), graupel and frozen drops/hail]. Each type is described by a special size distribution function containing many categories (i.e. 33 bins). Atmospheric aerosols are also described using number density size-distribution functions.A spectral-bin microphysical model is very expensive from a from a computational point of view and has only been implemented into the 2D version of the GCE at the present time. The model is tested by studying the evolution of deep tropical clouds in the west Pacific warm pool region using identical thermodynamic conditions but with different concentrations of CCN: a low "clean" concentration and a high "dirty" concentration. Besides the initial differences in aerosol concentration, preliminary results indicate that the low CCN concentration case produces rainfall at the surface sooner than the high CCN case but has less cloud water mass aloft. Because the spectral-bin model explicitly calculates and allows for the examination of both the mass and number concentration of species in each size categor, a detailed analysis of the instantaneous size spectrum can be obtained for the two cases. It is shown that since the low CCN case produces fewer droplets, larger sized develop due to the greater condensational and collectional growth, leading to a broader size spectrum in comparison to the high CCN case.

A satellite-based 13-year climatology of net cloud radiative forcing over the Indian monsoon region

NASA Astrophysics Data System (ADS)

Saud, Trailokya; Dey, Sagnik; Das, Sushant; Dutta, Soumi

2016-12-01

We present a satellite-based 13-year (Mar. 2000-Feb. 2013) climatology of net cloud radiative forcing (CRF) over the Indian monsoon region (0-40°N, 60-100°E) using the Clouds and Earth's Radiant Energy System (CERES) radiation data and explained the net CRF variability in terms of cloud properties retrieved by Moderate Resolution Imaging Spectroradiometer (MODIS). Mean (± 1σ) seasonal shortwave (SW) CRF values averaged over the region are - 82.7 ± 24.5, - 32.1 ± 12.1, - 17.2 ± 5.3 and - 30.2 ± 16.2 W m- 2 respectively for the monsoon (JJAS), post-monsoon (ON), winter (DJF) and pre-monsoon (MAM) seasons; while the corresponding longwave (LW) CRF values are 53.7 ± 14.2, 27.9 ± 10.0, 15.8 ± 7.0 and 25.2 ± 9.1 W m- 2. Regional analysis reveals the largest (least) negative net CRF over the northeast (northwest) rainfall homogeneous zone throughout the year due to the dominance of optically thick high clouds (low cloud fraction, fc). Mean JJAS fc is found to increase (by > 0.01 per year) over large parts of the Arabian Sea, Bay of Bengal and the northwest region. Mean annual net CRF values for cumulus, stratocumulus and stratus (low level), altocumulus, altostratus and nimbostratus (mid-level clouds) and cirrus, cirrostratus and deep-convective (high level) clouds over the Indian monsoon region are estimated to be - 0.8, - 4.7, - 6.9, + 3.3, - 6.3, - 23.3, + 5.4, - 23.3 and - 42.1 W m- 2 respectively. Across a wide range of cloud optical depth (COD) and fc < 0.6, near cancellation of SW cooling by LW warming, is observed for low clouds. Net CRF drops below - 15 W m- 2 for clouds evolving above 400 hPa, mainly in the monsoon season. Our results demonstrate that net CRF variability in the Indian monsoon region can be explained by variability in Cloud Top Pressure (CTP), COD and fc. The study highlights the need for resolving a multi-layer cloud field in the future.

A Satellite Survey of Cloud Cover and Water Vapor in the Southwestern USA and Northern Mexico

NASA Astrophysics Data System (ADS)

Carrasco, E.; Avila, R.; Erasmus, A.; Djorgovski, S. G.; Walker, A. R.; Blum, R.

2017-03-01

Cloud cover and water vapor conditions in the southwestern USA and northern Mexico were surveyed as a preparatory work for the Thirty Meter Telescope (TMT) in situ site testing program. Although the telescope site is already selected, the TMT site testing team decided to make public these results for its usefulness for the community. Using 58 months of meteorological satellite observations between 1993 July and 1999 September, different atmospheric parameters were quantified from data of the 10.7 μm and of 6.7 μm windows. In particular, cloud cover and water vapor conditions were identified in preferred areas. As a result of the aerial analysis, 15 sites of existing and potential telescope were selected, compared, and ranked in terms of their observing quality. The clearest sites are located along the spine of the Baja peninsula and into southern California on mountain peaks above the temperature inversion layer. A steep gradient of cloudiness was observed along the coast where coastal cloud and fog are trapped below the inversion layer. Moving from west to east over the continent, a significant increase in cloudiness was observed. The analysis shows that San Pedro Mártir, San Gorgonio Mountain and San Jacinto Peak have the largest fraction of clear sky conditions (˜74%). The site with the optimal combination of clear skies and low precipitable water vapor is Boundary Peak, Nevada. An approach based in satellite data provided a reliable method for sites comparison.

A Detailed Analysis of the Physical Conditions in the Infrared Dark Clouds in the Region IGGC 16/23

NASA Astrophysics Data System (ADS)

Scibelli, Samantha; Tolls, Volker

2017-01-01

There is an ongoing debate about why the star formation rate is low in the Galactic Center and Galactic Bar region of the Milky Way. Clump 2 is located at a distance of ~400 pc from the Galactic Center in the Galactic Bar region near the edge of the Central Molecular Zone (CMZ). Molecular clouds in this region are too distant to be influenced by the central black hole. However, despite of its location, Clump 2 is comprised of molecular clouds that show the same low star formation rate as those in the Galactic Center. Using Herschel PACS and SPIRE and APEX dust continuum emission data, our measurements indicate that cores in the IGGC 16/23 region have dust masses and densities comparable to those of more typical star-forming molecular clouds in the solar neighborhood. In addition, we analyzed Herschel HIFI high-J 12CO emission line observations supplemented by MOPRA molecular line observations. We find that the IGGC 16/23 region is composed of many smaller cores with different systemic velocities in the same line of sight advocating that additional analysis should be done to provide better constraints on the core sizes and masses to confirm that the core masses are below their virial masses and, thus, are not collapsing.The SAO REU program is funded in part by the National Science Foundation REU and Department of Defense ASSURE programs under NSF Grant no. 1262851, and by the Smithsonian Institution.

Characterizations of wet mercury deposition on a remote high-elevation site in the southeastern Tibetan Plateau.

PubMed

Huang, Jie; Kang, Shichang; Zhang, Qianggong; Guo, Junming; Sillanpää, Mika; Wang, Yongjie; Sun, Shiwei; Sun, Xuejun; Tripathee, Lekhendra

2015-11-01

Accurate measurements of wet mercury (Hg) deposition are critically important for the assessment of ecological responses to pollutant loading. The Hg in wet deposition was measured over a 3-year period in the southeastern Tibetan Plateau. The volume-weighted mean (VWM) total Hg (HgT) concentration was somewhat lower than those reported in other regions of the Tibetan Plateau, but the VWM methyl-Hg concentration and deposition flux were among the highest globally reported values. The VWM HgT concentration was higher in non-monsoon season than in monsoon season, and wet HgT deposition was dominated by the precipitation amount rather than the scavenging of atmospheric Hg by precipitation. The dominant Hg species in precipitation was mainly in the form of dissolved Hg, which indicates the pivotal role of reactive gaseous Hg within-cloud scavenging to wet Hg deposition. Moreover, an increasing trend in precipitation Hg concentrations was synchronous with the recent economic development in South Asia. Copyright © 2015 Elsevier Ltd. All rights reserved.

Tropical cloud buoyancy is the same in a world with or without ice

NASA Astrophysics Data System (ADS)

Seeley, Jacob T.; Romps, David M.

2016-04-01

When convective clouds grow above the melting line, where temperatures fall below 0°C, condensed water begins to freeze and water vapor is deposited. These processes release the latent heat of fusion, which warms cloud air, and many previous studies have suggested that this heating from fusion increases cloud buoyancy in the upper troposphere. Here we use numerical simulations of radiative-convective equilibrium with and without ice processes to argue that tropical cloud buoyancy is not systematically higher in a world with fusion than in a world without it. This insensitivity results from the fact that the environmental temperature profile encountered by developing tropical clouds is itself determined by convection. We also offer a simple explanation for the large reservoir of convective available potential energy in the tropical upper troposphere that does not invoke ice.

The 90 GHz radiometric imaging. [for terrain analysis

NASA Technical Reports Server (NTRS)

King, H. E.; White, J. D.; Wilson, W. J.; Mori, T. T.; Hollinger, J. P.; Troy, B. E.; Kenney, J. E.; Mcgoogan, J. T.

1976-01-01

A 90-GHz (3 mm wavelength) radiometer with a noise output fluctuation of 0.22 K (RMS), with a scanning antenna beam mirror, and the data processing system are described. Real-time radiometric imaging of terrain and man-made objects are shown. Flying at an altitude of 1500 ft a radiometer antenna with a 2 degrees halfpower beamwidth can distinguish landforms, waterways, roads, runways, bridges, ships at sea and their wakes, aircraft on runways, and athletic fields. A flight taken at an altitude of 3000 ft with approximately 2000 ft of clouds below the radiometer demonstrates the ability to distinguish bridges, rivers, marshland and other landforms even though the clouds are optically opaque. The radiometric images of a few representative scenes along with photographs of the corresponding scenes are presented to demonstrate the resolution of the imager system.

Aircraft measurements and analysis of severe storms: 1976 field experiment

NASA Technical Reports Server (NTRS)

Sinclair, P. C.

1982-01-01

Severe storm aircraft measurements are documented, as well as the instrumentation and operational features of aircraft mobility capabilities. The measurements and data analyses indicate that the concept of a highly mobile research aircraft capability for obtaining detailed measurements of wind, temperature, moisture, spherics, etc., near and within severe storm systems, forecast 48 hours in advance in a 1000 nm operating radius, is feasible, and was successfully demonstrated. The measurements and analyses reveal several severe storm features and insights with respect to storm air flow circulations and inflow-outflow orientation. Precipitation downdraft air is recirculated back into the updraft core below the scud cloud in both back and front feeder type storms. In a back feeder type storm, the downdraft outflow air ahead of the storm is also recirculated back into the updraft region near cloud base.

Characterization of clouds in Titan's tropical atmosphere

USGS Publications Warehouse

Griffith, C.A.; Penteado, P.; Rodriguez, S.; Le, Mouelic S.; Baines, K.H.; Buratti, B.; Clark, R.; Nicholson, P.; Jaumann, R.; Sotin, Christophe

2009-01-01

Images of Titan's clouds, possible over the past 10 years, indicate primarily discrete convective methane clouds near the south and north poles and an immense stratiform cloud, likely composed of ethane, around the north pole. Here we present spectral images from Cassini's Visual Mapping Infrared Spectrometer that reveal the increasing presence of clouds in Titan's tropical atmosphere. Radiative transfer analyses indicate similarities between summer polar and tropical methane clouds. Like their southern counterparts, tropical clouds consist of particles exceeding 5 ??m. They display discrete structures suggestive of convective cumuli. They prevail at a specific latitude band between 8??-20?? S, indicative of a circulation origin and the beginning of a circulation turnover. Yet, unlike the high latitude clouds that often reach 45 km altitude, these discrete tropical clouds, so far, remain capped to altitudes below 26 km. Such low convective clouds are consistent with the highly stable atmospheric conditions measured at the Huygens landing site. Their characteristics suggest that Titan's tropical atmosphere has a dry climate unlike the south polar atmosphere, and despite the numerous washes that carve the tropical landscape. ?? 2009. The American Astronomical Society.

Negative Aerosol-Cloud re Relationship From Aircraft Observations Over Hebei, China

NASA Astrophysics Data System (ADS)

Zhao, Chuanfeng; Qiu, Yanmei; Dong, Xiaobo; Wang, Zhien; Peng, Yiran; Li, Baodong; Wu, Zhihui; Wang, Yang

2018-01-01

Using six flights observations in September 2015 over Hebei, China, this study shows a robust negative aerosol-cloud droplet effective radius (re) relationship for liquid clouds, which is different from previous studies that found positive aerosol-cloud re relationship over East China using satellite observations. A total of 27 cloud samples was analyzed with the classification of clean and polluted conditions using lower and upper 1/3 aerosol concentration at 200 m below the cloud bases. By normalizing the profiles of cloud droplet re, we found significant smaller values under polluted than under clean condition at most heights. Moreover, the averaged profiles of cloud liquid water content (LWC) show larger values under polluted than clean conditions, indicating even stronger negative aerosol-cloud re relationship if LWC is kept constant. The droplet size distributions further demonstrate that more droplets concentrate within smaller size ranges under polluted conditions. Quantitatively, the aerosol-cloud interaction is found around 0.10-0.19 for the study region.

Case study of a solid-waste-scavenger community with respect to health and environment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kungskulniti, Nipapun.

1991-01-01

This study was an investigation of a solid waste scavenger community at the On-Nooch Dump Site in Bangkok, Thailand. The purpose was to identify the dimensions of the public health conditions of solid waste scavengers and their community. Cross-sectional field surveys and measurements were undertaken to characterize the distribution and magnitude of health-related problems and environmental conditions. Scavengers were found to be exposed to hazardous conditions due to the waste materials at the dump site. Cuts and punctures from sharp materials were the most common complaints among scavengers. Health symptoms like headache, diarrhea, respiratory illness, skin diseases and back painmore » were also reported. There was a high prevalence of childhood respiratory illness especially among those children of households where cigarette smoking was present. Children had poor nutritional status and were commonly infected by intestinal protozoa and helminths. An appreciable proportion of adult respondents was below the normal range for lung function performance. Seroprevalence of HBV infection was found to be high among male respondents in addition to six respondents that had possible HIV infections. The quality of the community water supply was low. Air pollution measurements showed acceptable ambient air levels except for particulate levels (TSP and RSP). Levels of indoor, outdoor, and personal exposure NO{sub 2} were found to be similar. Data for an inner-city project apartment community named Din-Dang were also collected for comparison. A priority rating index and recommendations for public health condition improvements were presented.« less

A Simple Model of Cirrus Horizontal Inhomogeneity and Cloud Fraction

NASA Technical Reports Server (NTRS)

Smith, Samantha A.; DelGenio, Anthony D.

1998-01-01

A simple model of horizontal inhomogeneity and cloud fraction in cirrus clouds has been formulated on the basis that all internal horizontal inhomogeneity in the ice mixing ratio is due to variations in the cloud depth, which are assumed to be Gaussian. The use of such a model was justified by the observed relationship between the normalized variability of the ice water mixing ratio (and extinction) and the normalized variability of cloud depth. Using radar cloud depth data as input, the model reproduced well the in-cloud ice water mixing ratio histograms obtained from horizontal runs during the FIRE2 cirrus campaign. For totally overcast cases the histograms were almost Gaussian, but changed as cloud fraction decreased to exponential distributions which peaked at the lowest nonzero ice value for cloud fractions below 90%. Cloud fractions predicted by the model were always within 28% of the observed value. The predicted average ice water mixing ratios were within 34% of the observed values. This model could be used in a GCM to produce the ice mixing ratio probability distribution function and to estimate cloud fraction. It only requires basic meteorological parameters, the depth of the saturated layer and the standard deviation of cloud depth as input.

Composition and Chemistry of the Neutral Atmosphere of Venus

NASA Astrophysics Data System (ADS)

Marcq, Emmanuel; Mills, Franklin P.; Parkinson, Christopher D.; Vandaele, Ann Carine

2018-02-01

This paper deals with the composition and chemical processes occurring in the neutral atmosphere of Venus. Since the last synthesis, observers as well as modellers have emphasised the spatial and temporal variability of minor species, going beyond a static and uniform picture that may have prevailed in the past. The outline of this paper acknowledges this situation and follows closely the different dimensions along which variability in composition can be observed: vertical, latitudinal, longitudinal, temporal. The strong differences between the atmosphere below and above the cloud layers also dictate the structure of this paper. Observational constraints, obtained from both Earth and Venus Express, as well as 1D, 2D and 3D models results obtained since 1997 are also extensively referred and commented by the authors. An non-exhaustive list of topics included follows: modelled and observed latitudinal and vertical profiles of CO and OCS below the clouds of Venus; vertical profiles of CO and SO2 above the clouds as observed by solar occultation and modelled; temporal and spatial variability of sulphur oxides above the clouds. As a conclusion, open questions and topics of interest for further studies are discussed.

On the chemical dynamics of extracellular polysaccharides in the high Arctic surface microlayer

NASA Astrophysics Data System (ADS)

Gao, Q.; Leck, C.; Rauschenberg, C.; Matrai, P. A.

2012-07-01

The surface microlayer (SML) represents a unique system of which the physicochemical characteristics may differ from those of the underlying subsurface seawater (SSW). Within the Arctic pack ice area, the SML has been characterized as enriched in small colloids of biological origin, resulting from extracellular polymeric secretions (EPS). During the Arctic Summer Cloud Ocean Study (ASCOS) in August 2008, particulate organic matter (POM, with size range > 0.22 μm) and dissolved organic matter (DOM, < 0.22 μm, obtained after filtration) samples were collected and chemically characterized from the SML and the corresponding SSW at an open lead centered at 87.5° N and 5° E. Total organic carbon was persistently enriched in the SML with a mean enrichment factor (EF) of 1.45 ± 0.41, whereas sporadic depletions of dissolved carbohydrates and amino acids were observed. Monosaccharide compositional analysis reveals that EPS in the Arctic lead was formed mainly of distinctive heteropolysaccharides, enriched in xylose, fucose and glucose. The mean concentrations of total hydrolysable neutral sugars in SSW were 94.9 ± 37.5 nM in high molecular weight (HMW) DOM (> 5 kDa) and 64.4 ± 14.5 nM in POM. The enrichment of polysaccharides in the SML appeared to be a common feature, with EFs ranging from 1.7 to 7.0 for particulate polysaccharides and 3.5 to 12.1 for polysaccharides in the HMW DOM fraction. A calculated monosaccharide yield suggests that polymers in the HMW DOM fraction were scavenged, without substantial degradation, into the SML. Bubble scavenging experiments showed that newly aggregated particles could be formed abiotically by coagulation of low molecular weight nanometer-sized gels. Aerosol particles, artificially generated by bubbling experiments, were enriched in polysaccharides by factors of 22-70, relative to the source seawater. We propose that bubble scavenging of surface-active polysaccharides could be one of the possible mechanisms for the enrichment of polysaccharides in the high Arctic open lead SML.

On the chemical dynamics of extracellular polysaccharides in the high Arctic surface microlayer

NASA Astrophysics Data System (ADS)

Gao, Q.; Leck, C.; Rauschenberg, C.; Matrai, P. A.

2012-01-01

The surface microlayer (SML) represents a unique system of which the physicochemical characteristics may differ from those of the underlying subsurface seawater (SSW). Within the Arctic pack ice area, the SML has been characterized as enriched in small colloids of biological origin, resulting from extracellular polymeric secretions (EPS). During the Arctic Summer Cloud-Ocean Study (ASCOS) in August 2008, particulate and dissolved organic matter (POM, DOM) samples were collected and chemically characterized from the SML and the corresponding SSW at an open lead centered at 87.5° N and 5° E. Total organic carbon was persistently enriched in the SML with a mean enrichment factor (EF) of 1.45 ± 0.41, whereas sporadic depletions of dissolved carbohydrates and amino acids were observed. Monosaccharide compositional analysis reveals that EPS in the Arctic lead was formed mainly of distinctive heteropolysaccharides, enriched in xylose, fucose and glucose. The mean concentrations of total hydrolysable neutral sugars in SSW were 94.9 ± 37.5 nM in high molecular weight (HMW) DOM and 64.4 ± 14.5 nM in POM. The enrichment of polysaccharides in the SML appeared to be a common feature, with EFs ranging from 1.7 to 7.0 for particulate polysaccharides and 3.5 to 12.1 for polysaccharides in the HMW DOM fraction. A calculated monosaccharide yield suggests that polymers in the HMW DOM fraction were scavenged, without substantial degradation, into the SML. Bubble scavenging experiments showed that newly aggregated particles could be formed abiotically by coagulation of low molecular weight nanometer-sized gels. Experimentally-generated aerosol particles were enriched in polysaccharides by factors of 22-70, relative to the source seawater. We propose that bubble scavenging of surface-active polysaccharides was one of the possible mechanisms for the enrichment of polysaccharides in the SML.

Modelling ice microphysics of mixed-phase clouds

NASA Astrophysics Data System (ADS)

Ahola, J.; Raatikainen, T.; Tonttila, J.; Romakkaniemi, S.; Kokkola, H.; Korhonen, H.

2017-12-01

The low-level Arctic mixed-phase clouds have a significant role for the Arctic climate due to their ability to absorb and reflect radiation. Since the climate change is amplified in polar areas, it is vital to apprehend the mixed-phase cloud processes. From a modelling point of view, this requires a high spatiotemporal resolution to capture turbulence and the relevant microphysical processes, which has shown to be difficult.In order to solve this problem about modelling mixed-phase clouds, a new ice microphysics description has been developed. The recently published large-eddy simulation cloud model UCLALES-SALSA offers a good base for a feasible solution (Tonttila et al., Geosci. Mod. Dev., 10:169-188, 2017). The model includes aerosol-cloud interactions described with a sectional SALSA module (Kokkola et al., Atmos. Chem. Phys., 8, 2469-2483, 2008), which represents a good compromise between detail and computational expense.Newly, the SALSA module has been upgraded to include also ice microphysics. The dynamical part of the model is based on well-known UCLA-LES model (Stevens et al., J. Atmos. Sci., 56, 3963-3984, 1999) which can be used to study cloud dynamics on a fine grid.The microphysical description of ice is sectional and the included processes consist of formation, growth and removal of ice and snow particles. Ice cloud particles are formed by parameterized homo- or heterogeneous nucleation. The growth mechanisms of ice particles and snow include coagulation and condensation of water vapor. Autoconversion from cloud ice particles to snow is parameterized. The removal of ice particles and snow happens by sedimentation and melting.The implementation of ice microphysics is tested by initializing the cloud simulation with atmospheric observations from the Indirect and Semi-Direct Aerosol Campaign (ISDAC). The results are compared to the model results shown in the paper of Ovchinnikov et al. (J. Adv. Model. Earth Syst., 6, 223-248, 2014) and they show a good match. One of the advantages of UCLALES-SALSA is that it can be used to quantify the effect of aerosol scavenging on cloud properties in a precise way.

Distribution and Sources of Black Carbon in the Arctic

NASA Astrophysics Data System (ADS)

Qi, Ling

The Arctic is warming at twice the global rate over recent decades. To slow down this warming trend, there is growing interest in reducing the impact from short-lived climate forcers, such as black carbon (BC), because the benefits of mitigation are seen more quickly relative to CO2 reduction. To propose efficient mitigation policies, it is imperative to improve our understanding of BC distribution in the Arctic and to identify the sources. In this dissertation, we investigate the sensitivity of BC in the Arctic, including BC concentrations in snow (BCsnow) and BC concentrations in air (BCair), to emissions, dry deposition and wet scavenging using a global 3-D chemical transport model (CTM) GEOS-Chem. By including flaring emissions, estimating dry deposition velocity using resistance-in-series method, and including Wegener-Bergeron-Findeisen (WBF) in wet scavenging, simulated BCsnow in the eight Arctic sub-regions agree with the observations within a factor of two, and simulated BCair fall within the uncertainty range of observations. Specifically, we find that natural gas flaring emissions in Western Extreme North of Russia (WENR) strongly enhance BCsnow (by up to ?50%) and BCair (by 20-32%) during snow season in the so-called 'Arctic front', but has negligible impact on BC in the free troposphere. The updated dry deposition velocity over snow and ice is much larger than those used in most of global CTMs and agrees better with observation. The resulting BCsnow changes marginally because of the offsetting of higher dry and lower wet deposition fluxes. In contrast, surface BCair decreases strongly due to the faster dry deposition (by 27-68%). WBF occurs when the environmental vapor pressure is in between the saturation vapor pressure of ice crystals and water drops in mixed-phase clouds. As a result, water drops evaporate and releases BC particles in them back into the interstitial air. In most CTMs, WBF is either missing or represented by a uniform and low BC scavenging efficiency. In this dissertation, we relate WBF with temperature and ice mass fraction based on long-term observations in mixed-phase clouds. We find that WBF reduces BC scavenging efficiency globally, with larger decrease at higher latitude and altitude (from 8% in the tropics to 76% in the Arctic). WBF slows down and reduces wet deposition of BC and leave more BC in the atmosphere. Higher BC air results in larger dry deposition. The resulting total deposition is lower in mid-latitudes (by 12-34%) and higher in the Arctic (2-29%). Globally, including WBF significantly reduces the discrepancy of BCsnow (by 50%), BCair (by 50%), and washout ratios (by a factor of two to four). The remaining discrepancies in these variables suggest that in-cloud removal is likely still excessive over land. In the last part, we identify sources of surface atmospheric BC in the Arctic in springtime, when radiative forcing is the largest due to the high insolation and surface albedo. We find a large contribution from Asian anthropogenic sources (40-43%) and open biomass burning emissions from forest fires in South Siberia (29-41%). Outside the Arctic front, BC is strongly enhanced by episodic, direct transport events from Asia and Siberia after 12 days of transport. In contrast, in the Arctic front, a large fraction of the Asian contribution is in the form of 'chronic' pollution on 1-2 month timescale. As such, it is likely that previous studies using 5- or 10-day trajectory analyses strongly underestimated the contribution from Asia to surface BC in the Arctic. Our results point toward an urgent need for better characterization of flaring emissions of BC (e.g. the emission factors, temporal and spatial distribution), extensive measurements of both the dry deposition of BC over snow and ice, and the scavenging efficiency of BC in mixed-phase clouds, particularly over Ocean. More measurements of 14C are needed to better understand sources of BC (fossil fuel combustion versus biomass burning) and to provide additional constrain on BC simulations.

Jovian meterology: Large-scale moist convection without a lower boundary

NASA Technical Reports Server (NTRS)

Gierasch, P. J.

1975-01-01

It is proposed that Jupiter's cloud bands represent large scale convection whose character is determined by the phase change of water at a level where the temperature is about 275K. It is argued that there are three important layers in the atmosphere: a tropopause layer where emission to space occurs; an intermediate layer between the tropopause and the water cloud base; and the deep layer below the water cloud. All arguments are only semi-quantitative. It is pointed out that these ingredients are essential to Jovian meteorology.

On the existence of tropical anvil clouds

NASA Astrophysics Data System (ADS)

Seeley, J.; Jeevanjee, N.; Langhans, W.; Romps, D.

2017-12-01

In the deep tropics, extensive anvil clouds produce a peak in cloud cover below the tropopause. The dominant paradigm for cloud cover attributes this anvil peak to a layer of enhanced mass convergence in the clear-sky upper-troposphere, which is presumed to force frequent detrainment of convective anvils. However, cloud cover also depends on the lifetime of cloudy air after it detrains, which raises the possibility that anvil clouds may be the signature of slow cloud decay rather than enhanced detrainment. Here we measure the cloud decay timescale in cloud-resolving simulations, and find that cloudy updrafts that detrain in the upper troposphere take much longer to dissipate than their shallower counterparts. We show that cloud lifetimes are long in the upper troposphere because the saturation specific humidity becomes orders of magnitude smaller than the typical condensed water loading of cloudy updrafts. This causes evaporative cloud decay to act extremely slowly, thereby prolonging cloud lifetimes in the upper troposphere. As a consequence, extensive anvil clouds still occur in a convecting atmosphere that is forced to have no preferential clear-sky convergence layer. On the other hand, when cloud lifetimes are fixed at a characteristic lower-tropospheric value, extensive anvil clouds do not form. Our results support a revised understanding of tropical anvil clouds, which attributes their existence to the microphysics of slow cloud decay rather than a peak in clear-sky convergence.

A case study on large-scale dynamical influence on bright band using cloud radar during the Indian summer monsoon

NASA Astrophysics Data System (ADS)

Jha, Ambuj K.; Kalapureddy, M. C. R.; Devisetty, Hari Krishna; Deshpande, Sachin M.; Pandithurai, G.

2018-02-01

The present study is a first of its kind attempt in exploring the physical features (e.g., height, width, intensity, duration) of tropical Indian bright band using a Ka-band cloud radar under the influence of large-scale cyclonic circulation and attempts to explain the abrupt changes in bright band features, viz., rise in the bright band height by 430 m and deepening of the bright band by about 300 m observed at around 14:00 UTC on Sep 14, 2016, synoptically as well as locally. The study extends the utility of cloud radar to understand how the bright band features are associated with light precipitation, ranging from 0 to 1.5 mm/h. Our analysis of the precipitation event of Sep 14-15, 2016 shows that the bright band above (below) 3.7 km, thickness less (more) than 300 m can potentially lead to light drizzle of 0-0.25 mm/h (drizzle/light rain) at the surface. It is also seen that the cloud radar may be suitable for bright band study within light drizzle limits than under higher rain conditions. Further, the study illustrates that the bright band features can be determined using the polarimetric capability of the cloud radar. It is shown that an LDR value of - 22 dB can be associated with the top height of bright band in the Ka-band observations which is useful in the extraction of the bright band top height and its width. This study is useful for understanding the bright band phenomenon and could be potentially useful in establishing the bright band-surface rain relationship through the perspective of a cloud radar, which would be helpful to enhance the cloud radar-based quantitative estimates of precipitation.

Development of a novel passive top-down uniflow scavenged two-stroke GDI engine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ciccarelli, G.; Reynolds, Steve; Oliver, Phillip

2010-02-15

The design and performance characteristics of a novel top-down uniflow scavenged gasoline direct-injection two-stroke engine are presented. The novelty of the engine lies in the cylinder head that contains multiple check valves that control scavenging airflow into the cylinder from a supercharged air plenum. When the cylinder pressure drops below the intake plenum pressure during the expansion stroke, air flows into the cylinder through the check valves. During compression the cylinder pressure increases to a level above the intake plenum pressure and the check valves close preventing back-flow into the intake plenum. The engine head design provides asymmetrical intake valvemore » timing without the use of poppet valves and the associated valve-train. In combination with an external Roots-type supercharger that supplies the plenum and exhaust ports at the bottom of the cylinder wall, the novel head provides top-down uniflow air scavenging. Motoring tests indicated that the check valves seal and the peak pressure is governed by the compression ratio. The only drawback observed is that valve closing is delayed as the engine speed increases. In order to investigate the valve dynamics, additional tests were performed in an optically-accessible cold flow test rig that enabled the direct measurement of valve opening and closing time under various conditions. (author)« less

Cross-polar transport and scavenging of Siberian aerosols containing black carbon during the 2012 ACCESS summer campaign

NASA Astrophysics Data System (ADS)

Raut, Jean-Christophe; Marelle, Louis; Fast, Jerome D.; Thomas, Jennie L.; Weinzierl, Bernadett; Law, Katharine S.; Berg, Larry K.; Roiger, Anke; Easter, Richard C.; Heimerl, Katharina; Onishi, Tatsuo; Delanoë, Julien; Schlager, Hans

2017-09-01

During the ACCESS airborne campaign in July 2012, extensive boreal forest fires resulted in significant aerosol transport to the Arctic. A 10-day episode combining intense biomass burning over Siberia and low-pressure systems over the Arctic Ocean resulted in efficient transport of plumes containing black carbon (BC) towards the Arctic, mostly in the upper troposphere (6-8 km). A combination of in situ observations (DLR Falcon aircraft), satellite analysis and WRF-Chem simulations is used to understand the vertical and horizontal transport mechanisms of BC with a focus on the role of wet removal. Between the northwestern Norwegian coast and the Svalbard archipelago, the Falcon aircraft sampled plumes with enhanced CO concentrations up to 200 ppbv and BC mixing ratios up to 25 ng kg-1. During transport to the Arctic region, a large fraction of BC particles are scavenged by two wet deposition processes, namely wet removal by large-scale precipitation and removal in wet convective updrafts, with both processes contributing almost equally to the total accumulated deposition of BC. Our results underline that applying a finer horizontal resolution (40 instead of 100 km) improves the model performance, as it significantly reduces the overestimation of BC levels observed at a coarser resolution in the mid-troposphere. According to the simulations at 40 km, the transport efficiency of BC (TEBC) in biomass burning plumes was larger (60 %), because it was impacted by small accumulated precipitation along trajectory (1 mm). In contrast TEBC was small (< 30 %) and accumulated precipitation amounts were larger (5-10 mm) in plumes influenced by urban anthropogenic sources and flaring activities in northern Russia, resulting in transport to lower altitudes. TEBC due to large-scale precipitation is responsible for a sharp meridional gradient in the distribution of BC concentrations. Wet removal in cumulus clouds is the cause of modeled vertical gradient of TEBC, especially in the mid-latitudes, reflecting the distribution of convective precipitation, but is dominated in the Arctic region by the large-scale wet removal associated with the formation of stratocumulus clouds in the planetary boundary layer (PBL) that produce frequent drizzle.

Properties of Arctic Aerosol Particles and Residuals of Warm Clouds: Cloud Activation Efficiency and the Aerosol Indirect Effect

NASA Astrophysics Data System (ADS)

Zelenyuk, A.; Imre, D. G.; Leaitch, R.; Ovchinnikov, M.; Liu, P.; Macdonald, A.; Strapp, W.; Ghan, S. J.; Earle, M. E.

2012-12-01

Single particle mass spectrometer, SPLAT II, was used to characterize the size, composition, number concentration, density, and shape of individual Arctic spring aerosol. Background particles, particles above and below the cloud, cloud droplet residuals, and interstitial particles were characterized with goal to identify the properties that separate cloud condensation nuclei (CCN) from background aerosol particles. The analysis offers a comparison between warm clouds formed on clean and polluted days, with clean days having maximum particle concentrations (Na) lower than ~250 cm-3, as compared with polluted days, in which maximum concentration was tenfold higher. On clean days, particles were composed of organics, organics mixed with sulfates, biomass burning (BB), sea salt (SS), and few soot and dust particles. On polluted days, BB, organics associated with BB, and their mixtures with sulfate dominated particle compositions. Based on the measured compositions and size distributions of cloud droplet residuals, background aerosols, and interstitial particles, we conclude that these three particle types had virtually the same compositions, which means that cloud activation probabilities were surprisingly nearly composition independent. Moreover, these conclusions hold in cases in which less than 20% or more than 90% of background particles got activated. We concluded that for the warm clouds interrogated in this study particle size played a more important factor on aerosol CCN activity. Comparative analysis of all studied clouds reveals that aerosol activation efficiency strongly depends on the aerosol concentrations, such that at Na <200 cm-3, nearly all particles activate, and at higher concentrations the activation efficiency is lower. For example, when Na was greater than 1500 cm-3, less than ~30% of particles activated. The data suggest that as the number of nucleated droplets increases, condensation on existing droplets effectively competes with particle activation, limiting maximum droplet concentrations Nd = 525 ± 50 cm-3, which is lower than the 750 cm-3 limit found by Leaitch et al. (1986) for mid-latitude continental cloud that had generally larger updraft speeds than the clouds interrogated in Arctic. These findings are important for the aerosol indirect effect, in which increase in aerosol particle number concentrations is expected to result in increase in Nd and decrease in droplet size, leading to increased cloud albedo and potentially lifetimes. Our conclusions point to limited susceptibility to changes in ambient aerosol concentrations, providing simple explanation for the finding of weaker than expected indirect effect. In summary, the data presented here show that Nd increases as the cloud base particle number concentration increases; however, they also show a limit on Nd that is in the range of 500-600 cm-3.

Evaluation and Assimilation of Cloud Cleared Radiances for AIRS in GEOS-5

NASA Technical Reports Server (NTRS)

Liu, Hui-chun

2008-01-01

The use of clear (cloud-free) channels for AIRS in GEOS-5 had shown positive impact on forecast skills in both hemispheres. However, improvements in forecast skills due to the assimilation of AIRS data are less impressive since the number of assimilated channels from AIRS is much larger than that from other Infrared sounders such as HIRS-3 onboard NOAA 15-17 satellites. This limitation of AIRS radiance data to improve the forecast skill is mainly due to the fact that channels capable of peaking below clouds are not used in the assimilation and yet those have highest vertical resolving capability of AIRS instrument are concentrated in the lower troposphere. On average, the percentage of AIRS footprints completely clear for all channels is less than 10%. The percentage of assimilated AIRS channel radiances however ranges from 100% for channels peaking in the upper stratosphere, above the cloud, to no more that 5% in the lower atmosphere due to cloud contamination. Our current ability to model and predict clouds accurately in global model, and to fully characterize and parameterize optical properties of cloud particles in radiative transfer model are the two major obstacles prohibiting us to use cloudy radiance directly in the assimilation. To further improve forecast skill using AIRS data, we ought to use the channels peaking below the clouds in the troposphere, which can be accomplished by assimilating cloud-cleared radiance. The cloud-cleared radiance data for AIRS used in this study were obtained from optimal cloud clearing procedures developed by researchers at CIMSS of University of Wisconsin at Madison to retrieve clear column radiances for all AIRS channels by collocating multi-band MODIS IR clear radiance observations with the AIRS cloudy radiances on a single footprint basis. Two adjacent AIRS cloudy footprints are used to retrieve one AIRS cloud-cleared radiance spectrum and no background information (first guess) is needed. To assimilate the cloud-cleared radiance data, the errors of the cloud-cleared radiances need to be addressed. The details of convolving AIRS radiances with MODIS spectral response function and comparison with MODIS-measured cloud-free radiance will be presented. The range of errors of cloud-cleared radiances for AIRS using collocated MODIS clear and near-by AIRS clear data will be shown. The NASA. global data assimilation model, GEOS-5, is used to evaluate and assimilate the cloud-cleared radiance for AIRS. The residues between the cloud-cleared brightness temperature and the simulated brightness temperature from background (i.e., OMFs) will be investigated. The quality control procedures will be documented based on error estimation and the OMFs. Finally, the impacts between assimilation of clear channel radiances and cloud-cleared radiances will be addressed.

Aqueous Processing of Atmospheric Organic Particles in Cloud Water Collected via Aircraft Sampling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boone, Eric J.; Laskin, Alexander; Laskin, Julia

2015-07-21

Cloud water and below-cloud atmospheric particle samples were collected onboard a research aircraft during the Southern Oxidant and Aerosol Study (SOAS) over a forested region of Alabama in June 2013. The organic molecular composition of the samples was studied to gain insights into the aqueous-phase processing of organic compounds within cloud droplets. High resolution mass spectrometry with nanospray desorption electrospray ionization and direct infusion electrospray ionization were utilized to compare the organic composition of the particle and cloud water samples, respectively. Isoprene and monoterpene-derived organosulfates and oligomers were identified in both the particles and cloud water, showing the significant influencemore » of biogenic volatile organic compound oxidation above the forested region. While the average O:C ratios of the organic compounds were similar between the atmospheric particle and cloud water samples, the chemical composition of these samples was quite different. Specifically, hydrolysis of organosulfates and formation of nitrogen-containing compounds were observed for the cloud water when compared to the atmospheric particle samples, demonstrating that cloud processing changes the composition of organic aerosol.« less

The structure and phase of cloud tops as observed by polarization lidar

NASA Technical Reports Server (NTRS)

Spinhirne, J. D.; Hansen, M. Z.; Simpson, J.

1983-01-01

High-resolution observations of the structure of cloud tops have been obtained with polarization lidar operated from a high altitude aircraft. Case studies of measurements acquired from cumuliform cloud systems are presented, two from September 1979 observations in the area of Florida and adjacent waters and a third during the May 1981 CCOPE experiment in southeast Montana. Accurate cloud top height structure and relative density of hydrometers are obtained from the lidar return signal intensity. Correlation between the signal return intensity and active updrafts was noted. Thin cirrus overlying developing turrets was observed in some cases. Typical values of the observed backscatter cross section were 0.1-5 (km/sr) for cumulonimbus tops. The depolarization ratio of the lidar signals was a function of the thermodynamic phase of cloud top areas. An increase of the cloud top depolarization with decreasing temperature was found for temperatures above and below -40 C.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Deng, Min; Kollias, Pavlos; Feng, Zhe

The motivation for this research is to develop a precipitation classification and rain rate estimation method using cloud radar-only measurements for Atmospheric Radiation Measurement (ARM) long-term cloud observation analysis, which are crucial and unique for studying cloud lifecycle and precipitation features under different weather and climate regimes. Based on simultaneous and collocated observations of the Ka-band ARM zenith radar (KAZR), two precipitation radars (NCAR S-PolKa and Texas A&M University SMART-R), and surface precipitation during the DYNAMO/AMIE field campaign, a new cloud radar-only based precipitation classification and rain rate estimation method has been developed and evaluated. The resulting precipitation classification ismore » equivalent to those collocated SMART-R and S-PolKa observations. Both cloud and precipitation radars detected about 5% precipitation occurrence during this period. The convective (stratiform) precipitation fraction is about 18% (82%). The 2-day collocated disdrometer observations show an increased number concentration of large raindrops in convective rain compared to dominant concentration of small raindrops in stratiform rain. The composite distributions of KAZR reflectivity and Doppler velocity also show two distinct structures for convective and stratiform rain. These indicate that the method produces physically consistent results for two types of rain. The cloud radar-only rainfall estimation is developed based on the gradient of accumulative radar reflectivity below 1 km, near-surface Ze, and collocated surface rainfall (R) measurement. The parameterization is compared with the Z-R exponential relation. The relative difference between estimated and surface measured rainfall rate shows that the two-parameter relation can improve rainfall estimation.« less

Occupational exposure to nitrous oxide during procedural pain control in children: a comparison of different inhalation techniques and scavenging systems.

PubMed

Messeri, Andrea; Amore, Elena; Dugheri, Stefano; Bonari, Alessandro; Pompilio, Ilenia; Arcangeli, Giulio; Rizzo, Giuliana

2016-09-01

Nitrous oxide (N2 O 50% in oxygen) is commonly used for painful procedures in children. Potential negative health effects associated with chronic workplace exposure limit its use. Safe occupational N2 O exposure concentrations are below 25 ppm environmental concentration as a time-weighted average (TWA) and below 200 ppm as a short-time exposure level (STEL) of 15 min. The aim was to assess occupational exposure of staff during nitrous oxide administration to children using different inhalation delivery devices and scavenging systems. Staff nitrous oxide exposure during use of a double face mask (DFM) with or without a demand valve (DV) was compared with a conventional single face mask (FM). We also compared exposure using the hospital central scavenging system with a portable evacuation system. N2 O concentrations, representing exposure values, were monitored within proximity to staff. Urine N2 O concentration was measured in staff administering the N2 O at the end of the procedural session. The mean and median values of TWA and STEL within the working area were lower than recommended values in the DFM (10.8, 11.6 ppm for TWA; 13.9, 11.0 ppm for STEL) and DFM-DV groups (2.3, 2.8 ppm for TWA; 4.4, 3.5 ppm for STEL) using the portable evacuation system. The N2 O urine exposure in DFM-DV group was lower than DFM group: a mean difference of 9.56 ppm (95% CI 2.65-16.46). Staff N2 O urinary concentrations were within safe biological limits in both the DFM and DFM-DV groups. High exposure concentrations to N2 O were recorded in all FM and FM-DV environmental and biological samples. The DFM system, with or without a DV, connected to a portable evacuation system during N2 O administration to children for painful procedures kept N2 O levels within the local environment below recommended limits. © 2016 John Wiley & Sons Ltd.

The influence of aerosol particle number and hygroscopicity on the evolution of convective cloud systems and their precipitation

NASA Astrophysics Data System (ADS)

Planche, C.; Flossmann, A. I.; Wobrock, W.

2009-04-01

A 3D cloud model with detailed microphysics for ice, water and aerosol particles (AP) is used to study the role of AP on the evolution of summertime convective mixed phase clouds and the subsequent precipitation. The model couples the dynamics of the NCAR Clark-Hall cloud scale model (Clark et al., 1996) with the detailed scavenging model (DESCAM) of Flossmann and Pruppacher (1988) and the ice phase module of Leroy et al. (2007). The microphysics follows the evolution of AP, drop, and ice crystal spectra each with 39 bins. Aerosol mass in drops and ice crystals is also predicted by two distribution functions to close the aerosol budget. The simulated cases are compared with radar observations over the northern Vosges mountains and the Rhine valley which were performed on 12 and 13 August 2007 during the COPS field campaign. Using a 3D grid resolution of 250m, our model, called DESCAM-3D, is able to simulate very well the dynamical, cloud and precipitation features observed for the two different cloud systems. The high horizontal grid resolution provides new elements for the understanding of the formation of orographic convection. In addition the fine numerical scale compares well with the high resolved radar observation given by the LaMP X-band radar and Poldirad. The prediction of the liquid and ice hydrometeor spectra allows a detailed calculation of the cloud radar reflectivity. Sensitivity studies realized by the use of different mass-diameter relationships for ice crystals demonstrate the role of the crystal habits on the simulated reflectivities. In order to better understand the role of AP on cloud evolution and precipitation formation several sensitivity studies were performed by modifying not only aerosol number concentration but also their physico-chemical properties. The numerical results show a strong influence of the aerosol number concentration on the precipitation intensity but no effect of the aerosol particle solubility on the rain formation can be found.

Corrigendum to Aerosol impacts on California winter clouds and precipitation during CalWater 2011: local pollution versus long-range transported dust published in Atmos. Chem. Phys., 14, 81–101, 2014

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fan, Jiwen; Leung, Lai-Yung R.; DeMott, Paul J.

2014-05-01

In the paper “Aerosol impacts on California winter clouds and precipitation during CalWater 2011: local pollution versus long-range transported dust” by J. Fan et al., wrong versions of Fig. 8 and Fig. 12 were published. Please find the correct figures below.

OZONE-SCAVENGING REAGENTS SUITABLE FOR USE IN THE QUANTITATIVE DETERMINATION OF ALDEHYDES AS THE O-(2,3,4,5,6-PENTAFLUOROBENZYL)OXIMES BY GC-ECD

EPA Science Inventory

Previously, we reported interference due to several ozone-scavenging reagents (OSRs) in the quantitation of aldehydes using 0-(2,3,4,5,6-pentafluorobenzyl)oxylamine (PFBOA) in the analysis of ozonated waters. Scavenging ozone is essential if ozonation byproduct concentrations ar...

The composition of the atmosphere of Venus below 100 km altitude: An overview

NASA Astrophysics Data System (ADS)

de Bergh, C.; Moroz, V. I.; Taylor, F. W.; Crisp, D.; Bézard, B.; Zasova, L. V.

2006-11-01

We review the progress in our understanding of the composition of the Venus atmosphere since the publication of the COSPAR Venus International Reference Atmosphere volume in 1985. Results presented there were derived from data compiled in 1982-1983. More recent progress has resulted in large part from Earth-based studies of the near-infrared radiation from the nightside of the planet. These observations allow us to probe the atmosphere between the cloud tops and the surface. Additional insight has been gained through: (i) the analysis of ultraviolet radiation by satellites and rockets; (ii) data collected by the Vega 1 and 2 landers; (iii) complementary analyses of Venera 15 and 16 data; (iv) ground-based and Magellan radio occultation measurements, and (v) re-analyses of some spacecraft measurements made before 1983, in particular the Pioneer Venus and Venera 11, 13 and 14 data. These new data, and re-interpretations of older data, provide a much better knowledge of the vertical profile of water vapor, and more information on sulfur species above and below the clouds, including firm detections of OCS and SO. In addition, some spatial and/or temporal variations have been observed for CO, H 2O, H 2SO 4, SO 2, and OCS. New values of the D/H ratio have also been obtained.

Novel Transport Characterizations in Layered Two-Dimensional Materials and Bulk Chalcogenides

NASA Astrophysics Data System (ADS)

Pennypacker, Sam

We present a case study (September 20 - October 13, 2015) of synergistic, multi-instrument observations of aerosols, clouds and the marine boundary layer (MBL) at the Eastern North Atlantic (ENA) ARM site centered on a period of exceptionally low (20 - 50 cm-3) surface accumulation mode (0.1 - 1 mum) aerosol particle number concentrations. We divide the case study into three regimes (high, clean and ultra-clean) based on daily median number concentrations, and compare finer resolution (hourly or less) observations between these regimes. The analysis focuses on the possibility of using these ultra-clean events to study pristine conditions in the remote MBL, as well as examining evidence for a recently proposed conceptual model for the large-scale depletion of CCN-sized particles in post-frontal air masses. Relative to the high and clean regimes, the ultra-clean regime tends to exhibit significantly fewer particles between 0.1 and 0.4 mum in diameter and a relatively increased prevalence of larger accumulation mode particles. In addition, supermicron particles tend to dominate total scattering in the ultra-clean regime, and there is little evidence for absorbing aerosol. These observations are more in line with a heavily scavenged but natural marine aerosol population and minimal contribution from continental sources such as anthropogenic pollution, biomass burning or dust. The air masses with the consistently lowest accumulation mode aerosol number concentrations are largely dominated by heavily drizzling clouds with high liquid water path (LWP) cores, deep decoupled boundary layers, open cellular organization and notable surface forcing of sub-cloud turbulence, even at night. We end with a discussion of the implications of this work the second aerosol indirect effect and pristine conditions in the remote MBL.

Slow Cooling in Low Metallicity Clouds: An Origin of Globular Cluster Bimodality?

NASA Astrophysics Data System (ADS)

Fernandez, Ricardo; Bryan, Greg L.

2018-05-01

We explore the relative role of small-scale fragmentation and global collapse in low-metallicity clouds, pointing out that in such clouds the cooling time may be longer than the dynamical time, allowing the cloud to collapse globally before it can fragment. This, we suggest, may help to explain the formation of the low-metallicity globular cluster population, since such dense stellar systems need a large amount of gas to be collected in a small region (without significant feedback during the collapse). To explore this further, we carry out numerical simulations of low-metallicity Bonner-Ebert stable gas clouds, demonstrating that there exists a critical metallicity (between 0.001 and 0.01 Z⊙) below which the cloud collapses globally without fragmentation. We also run simulations including a background radiative heating source, showing that this can also produce clouds that do not fragment, and that the critical metallicity - which can exceed the no-radiation case - increases with the heating rate.

Toward Global Harmonization of Derived Cloud Products

NASA Technical Reports Server (NTRS)

Wu, Dong L.; Baum, Bryan A.; Choi, Yong-Sang; Foster, Michael J.; Karlsson, Karl-Goeran; Heidinger, Andrew; Poulsen, Caroline; Pavolonis, Michael; Riedi, Jerome; Roebeling, Robert

2017-01-01

Formerly known as the Cloud Retrieval Evaluation Workshop (CREW; see the list of acronyms used in this paper below) group (Roebeling et al. 2013, 2015), the International Cloud Working Group (ICWG) was created and endorsed during the 42nd Meeting of CGMS. The CGMS-ICWG provides a forum for space agencies to seek coherent progress in science and applications and also to act as a bridge between space agencies and the cloud remote sensing and applications community. The ICWG plans to serve as a forum to exchange and enhance knowledge on state-of-the-art cloud parameter retrievals algorithms, to stimulate support for training in the use of cloud parameters, and to encourage space agencies and the cloud remote sensing community to share knowledge. The ICWG plans to prepare recommendations to guide the direction of future research-for example, on observing severe weather events or on process studies-and to influence relevant programs of the WMO, WCRP, GCOS, and the space agencies.

The role of ice nuclei recycling in the maintenance of cloud ice in Arctic mixed-phase stratocumulus

DOE PAGES

Solomon, Amy; Feingold, G.; Shupe, M. D.

2015-09-25

This study investigates the maintenance of cloud ice production in Arctic mixed-phase stratocumulus in large eddy simulations that include a prognostic ice nuclei (IN) formulation and a diurnal cycle. Balances derived from a mixed-layer model and phase analyses are used to provide insight into buffering mechanisms that maintain ice in these cloud systems. We find that, for the case under investigation, IN recycling through subcloud sublimation considerably prolongs ice production over a multi-day integration. This effective source of IN to the cloud dominates over mixing sources from above or below the cloud-driven mixed layer. Competing feedbacks between dynamical mixing andmore » recycling are found to slow the rate of ice lost from the mixed layer when a diurnal cycle is simulated. Furthermore, the results of this study have important implications for maintaining phase partitioning of cloud ice and liquid that determine the radiative forcing of Arctic mixed-phase clouds.« less

The role of ice nuclei recycling in the maintenance of cloud ice in Arctic mixed-phase stratocumulus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Solomon, Amy; Feingold, G.; Shupe, M. D.

This study investigates the maintenance of cloud ice production in Arctic mixed-phase stratocumulus in large eddy simulations that include a prognostic ice nuclei (IN) formulation and a diurnal cycle. Balances derived from a mixed-layer model and phase analyses are used to provide insight into buffering mechanisms that maintain ice in these cloud systems. We find that, for the case under investigation, IN recycling through subcloud sublimation considerably prolongs ice production over a multi-day integration. This effective source of IN to the cloud dominates over mixing sources from above or below the cloud-driven mixed layer. Competing feedbacks between dynamical mixing andmore » recycling are found to slow the rate of ice lost from the mixed layer when a diurnal cycle is simulated. Furthermore, the results of this study have important implications for maintaining phase partitioning of cloud ice and liquid that determine the radiative forcing of Arctic mixed-phase clouds.« less

The Role of Aerosols on Precipitation Processes: Cloud Resolving Model Simulations

NASA Technical Reports Server (NTRS)

Tao, Wei-Kuo; Li, X.; Matsui, T.

2012-01-01

Cloud microphysics is inevitably affected by the smoke particle (CCN, cloud condensation nuclei) size distributions below the clouds. Therefore, size distributions parameterized as spectral bin microphysics are needed to explicitly study the effects of atmospheric aerosol concentration on cloud development, rainfall production, and rainfall rates for convective clouds. Recently, a detailed spectral-bin microphysical scheme was implemented into the Goddard Cumulus Ensemble (GCE) model. The formulation for the explicit spectral bin microphysical processes is based on solving stochastic kinetic equations for the size distribution functions of water droplets (i.e., cloud droplets and raindrops), and several types of ice particles [i.e. pristine ice crystals (columnar and plate-like), snow (dendrites and aggregates), graupel and frozen drops/hail]. Each type is described by a special size distribution function containing many categories (i.e., 33 bins). Atmospheric aerosols are also described using number density size-distribution functions. The model is tested by studying the evolution of deep cloud systems in the west Pacific warm pool region, the sub-tropics (Florida) and midlatitudes using identical thermodynamic conditions but with different concentrations of CCN: a low "clean" concentration and a high "dirty" concentration. Results indicate that the low CCN concentration case produces rainfall at the surface sooner than the high CeN case but has less cloud water mass aloft. Because the spectral-bin model explicitly calculates and allows for the examination of both the mass and number concentration of species in each size category, a detailed analysis of the instantaneous size spectrum can be obtained for these cases. It is shown that since the low (CN case produces fewer droplets, larger sizes develop due to greater condensational and collection growth, leading to a broader size spectrum in comparison to the high CCN case. Sensitivity tests were performed to identify the impact of ice processes, radiation and large-scale influence on cloud-aerosol interactive processes, especially regarding surface rainfall amounts and characteristics (i.e., heavy or convective versus light or stratiform types). In addition, an inert tracer was included to follow the vertical redistribution of aerosols by cloud processes. We will also give a brief review from observational evidence on the role of aerosol on precipitation processes.

Characteristics of Moderately Deep Tropical Convection Observed by Dual-Polarimetric Radar

NASA Astrophysics Data System (ADS)

Powell, Scott

2017-04-01

Moderately deep cumulonimbus clouds (often erroneously called congestus) over the tropical warm pool play an important role in large-scale dynamics by moistening the free troposphere, thus allowing for the upscale growth of convection into mesoscale convective systems. Direct observational analysis of such convection has been limited despite a wealth of radar data collected during several field experiments in the tropics. In this study, the structure of isolated cumulonimbus clouds, particularly those in the moderately deep mode with heights of up to 8 km, as observed by RHI scans obtained with the S-PolKa radar during DYNAMO is explored. Such elements are first identified following the algorithm of Powell et al (2016); small contiguous regions of echo are considered isolated convection. Within isolated echo objects, echoes are further subdivided into core echoes, which feature vertical profiles reflectivity and differential reflectivity that is similar to convection embedded in larger cloud complexes, and fringe echoes, which contain vertical profiles of differential reflectivity that are more similar to stratiform regions. Between the surface and 4 km, reflectivities of 30-40 (10-20) dBZ are most commonly observed in isolated convective core (fringe) echoes. Convective cores in echo objects too wide to be considered isolated have a ZDR profile that peaks near the surface (with values of 0.5-1 dB common), and decays linearly to about 0.3 dB at and above an altitude of 6 km. Stratiform echoes have a minimum ZDR below of 0-0.5 dB below the bright band and a constant distribution centered on 0.5 dB above the bright band. The isolated convective core and fringe respectively possess composite vertical profiles of ZDR that resemble convective and stratiform echoes. The mode of the distribution of aspect ratios of isolated convection is approximately 2.3, but the long axis of isolated echo objects demonstrates no preferred orientation. An early attempt at illustrating composite radial velocity profiles within isolated convection is made. When the mean flow (determined from sounding data) is subtracted, a clear picture of radial velocities inside a composite representation of convection is obtained. As expected, Doppler radar data shows convergence in the lowest 1-2 km of isolated convective elements and divergence in the upper portions of the clouds. The composite velocity profiles can be used to compute crude profiles of horizontal divergence. Because the analysis uses data along radar rays (with gate size of 150 m) instead of data interpolated to a Cartesian grid, features in composited clouds can be observed at high vertical and horizontal resolution.

Forecasting the Northern African Dust Outbreak Towards Europe in April 2011: A Model Intercomparison

NASA Technical Reports Server (NTRS)

Huneeus, N.; Basart, S.; Fiedler, S.; Morcrette, J.-J.; Benedetti, A.; Mulcahy, J.; Terradellas, E.; Pérez García-Pando, C.; Pejanovic, G.; Nickovic, S.

2016-01-01

In the framework of the World Meteorological Organisation's Sand and Dust Storm Warning Advisory and Assessment System, we evaluated the predictions of five state-of-the-art dust forecast models during an intense Saharan dust outbreak affecting western and northern Europe in April 2011. We assessed the capacity of the models to predict the evolution of the dust cloud with lead times of up to 72 hours using observations of aerosol optical depth (AOD) from the AErosol RObotic NETwork (AERONET) and the Moderate Resolution Imaging Spectroradiometer (MODIS) and dust surface concentrations from a ground-based measurement network. In addition, the predicted vertical dust distribution was evaluated with vertical extinction profiles from the Cloud and Aerosol Lidar with Orthogonal Polarization (CALIOP). To assess the diversity in forecast capability among the models, the analysis was extended to wind field (both surface and profile), synoptic conditions, emissions and deposition fluxes. Models predict the onset and evolution of the AOD for all analysed lead times. On average, differences among the models are larger than differences among lead times for each individual model. In spite of large differences in emission and deposition, the models present comparable skill for AOD. In general, models are better in predicting AOD than near-surface dust concentration over the Iberian Peninsula. Models tend to underestimate the long-range transport towards northern Europe. Our analysis suggests that this is partly due to difficulties in simulating the vertical distribution dust and horizontal wind. Differences in the size distribution and wet scavenging efficiency may also account for model diversity in long-range transport.

Microbial ice nucleators are scavenged from the atmosphere during artificial rain events

NASA Astrophysics Data System (ADS)

Hanlon, Regina; Powers, Craig; Failor, Kevin; Vinatzer, Boris; Schmale, David

2016-04-01

Some microorganisms associated with rain may catalyze the nucleation of ice crystals at significantly warmer temperatures than would normally be required for ice formation, suggesting that they may play an important role in the onset of precipitation. Rain samples collected near the surface of the earth contain an array of microbial ice nucleators, but the little is known about their source(s) and life history. We conducted a series of field experiments to test the hypothesis that microbial ice nucleators are scavenged from the atmosphere by rainfall. Thirty three artificial rain events were conducted over four months (Nov 2014, Dec 2014, April 2015, and June 2015) off the side of the Smart Road Bridge in Blacksburg, VA, USA. In each event, sterile water was dispensed over the side of the bridge and recovered in sterile containers following gravitational settling from the bridge to an open fallow agricultural field below (a distance of ~55m). Microbes scavenged from the artificial rain events were cultured on six different types of agar media (R2A, TSA, CA; +/-cycloheximide), and the ice nucleation activity was examined for colonies cultured from the different media types. Mean CFUs scavenged by artificial rain ranged from 2 to 267 CFUs/mL. Microbial ice nucleators were cultured from 94% (31/33) of the simulated rain events, and represented 1.4% (121/8871) of the total number of colonies assayed. This percentage is similar to the percentage of culturable microbial ice nucleators occurring in about half of the natural rain events studied in Blacksburg, VA. Sequence-assisted identification of the repeatable microbial ice nucleators that were scavenged from the atmosphere showed a number of unique prokaryotic and eukaryotic taxa. This work expands our knowledge of the scavenging properties of rainfall, and suggests that at least some ice nucleators in natural precipitation events may have been scrubbed from the atmosphere during rainfall, and thus are not likely to be involved in the onset of precipitation.

Scavenging of ice-nucleating microorganisms from the atmosphere by artificial rain events

NASA Astrophysics Data System (ADS)

Hanlon, Regina; Powers, Craig; Failor, Kevin; Vinatzer, Boris; Schmale, David

2015-04-01

Little is known about how microorganisms are scavenged from the atmosphere during rainfall. Microorganisms are abundant and diverse in rain (precipitation) collected near the surface of the earth. Some of these rain-associated microorganisms produce proteins that catalyze the nucleation of ice crystals at significantly warmer temperatures than would normally be required for ice formation, suggesting that they may play important roles in weather, including the onset of precipitation. We conducted a series of field experiments to test the hypothesis that ice-nucleating microorganisms are scavenged from the atmosphere by rainfall. Thirteen artificial rain events were conducted off the side of the Smart Road Bridge in Blacksburg, VA, USA. In each event, sterile water was dispensed over the side of the bridge (simulated rainfall), and recovered in sterile containers following gravitational settling from the side of the bridge to an open fallow agricultural field below (a distance of ~55m from the release site to the collection site). Microbes scavenged from the artificial rain events were cultured on six different types of agar media (R2A, TSA, CA; +/- cycloheximide) and the ice nucleation activity was examined for colonies cultured from the different media types. Mean CFUs scavenged by artificial rain ranged from 83 to 196 CFUs/mL across all six media types. Ice-nucleating microorganisms were recovered from 85% (11/13) of the simulated rain events, and represented about 1% of the total number of colonies assayed from each event. Strikingly, this percentage is nearly identical to the percentage of culturable ice-nucleating microorganisms occurring in about half of the natural rain events studied to date in Blacksburg, Virginia. This work expands our knowledge of the scavenging properties of rain, and suggests that at least some ice nucleators in natural precipitation events may have been stripped from the atmosphere during rainfall, thus negating their potential role in the onset of precipitation.

Effects of surface-active organic matter on carbon dioxide nucleation in atmospheric wet aerosols: a molecular dynamics study.

PubMed

Daskalakis, Vangelis; Charalambous, Fevronia; Panagiotou, Fostira; Nearchou, Irene

2014-11-21

Organic matter (OM) uptake in cloud droplets produces water-soluble secondary organic aerosols (SOA) via aqueous chemistry. These play a significant role in aerosol properties. We report the effects of OM uptake in wet aerosols, in terms of the dissolved-to-gas carbon dioxide nucleation using molecular dynamics (MD) simulations. Carbon dioxide has been implicated in the natural rainwater as well as seawater acidity. Variability of the cloud and raindrop pH is assumed in space and time, as regional emissions, local human activities and geophysical characteristics differ. Rain scavenging of inorganic SOx, NOx and NH3 plays a major role in rain acidity in terms of acid-base activity, however carbon dioxide solubility also remains a key parameter. Based on the MD simulations we propose that the presence of surface-active OM promotes the dissolved-to-gas carbon dioxide nucleation in wet aerosols, even at low temperatures, strongly decreasing carbon dioxide solubility. A discussion is made on the role of OM in controlling the pH of a cloud or raindrop, as a consequence, without involving OM ionization equilibrium. The results are compared with experimental and computational studies in the literature.

Significance of aerosol radiative effect in energy balance control on global precipitation change

DOE Office of Scientific and Technical Information (OSTI.GOV)

Suzuki, Kentaroh; Stephens, Graeme L.; Golaz, Jean-Christophe

Historical changes of global precipitation in the 20th century simulated by a climate model are investigated. The results simulated with alternate configurations of cloud microphysics are analyzed in the context of energy balance controls on global precipitation, where the latent heat changes associated with the precipitation change is nearly balanced with changes to atmospheric radiative cooling. The atmospheric radiative cooling is dominated by its clear-sky component, which is found to correlate with changes to both column water vapor and aerosol optical depth (AOD). The water vapor-dependent component of the clear-sky radiative cooling is then found to scale with global temperaturemore » change through the Clausius–Clapeyron relationship. This component results in a tendency of global precipitation increase with increasing temperature at a rate of approximately 2%K -1. Another component of the clear-sky radiative cooling, which is well correlated with changes to AOD, is also found to vary in magnitude among different scenarios with alternate configurations of cloud microphysics that controls the precipitation efficiency, a major factor influencing the aerosol scavenging process that can lead to different aerosol loadings. These results propose how different characteristics of cloud microphysics can cause different aerosol loadings that in turn perturb global energy balance to significantly change global precipitation. This implies a possible coupling of aerosol–cloud interaction with aerosol–radiation interaction in the context of global energy balance.« less

Significance of aerosol radiative effect in energy balance control on global precipitation change

DOE PAGES

Suzuki, Kentaroh; Stephens, Graeme L.; Golaz, Jean-Christophe

2017-10-17

Historical changes of global precipitation in the 20th century simulated by a climate model are investigated. The results simulated with alternate configurations of cloud microphysics are analyzed in the context of energy balance controls on global precipitation, where the latent heat changes associated with the precipitation change is nearly balanced with changes to atmospheric radiative cooling. The atmospheric radiative cooling is dominated by its clear-sky component, which is found to correlate with changes to both column water vapor and aerosol optical depth (AOD). The water vapor-dependent component of the clear-sky radiative cooling is then found to scale with global temperaturemore » change through the Clausius–Clapeyron relationship. This component results in a tendency of global precipitation increase with increasing temperature at a rate of approximately 2%K -1. Another component of the clear-sky radiative cooling, which is well correlated with changes to AOD, is also found to vary in magnitude among different scenarios with alternate configurations of cloud microphysics that controls the precipitation efficiency, a major factor influencing the aerosol scavenging process that can lead to different aerosol loadings. These results propose how different characteristics of cloud microphysics can cause different aerosol loadings that in turn perturb global energy balance to significantly change global precipitation. This implies a possible coupling of aerosol–cloud interaction with aerosol–radiation interaction in the context of global energy balance.« less

Characterization of the 2012-044C BRIZ-M Upper Stage Breakup

NASA Astrophysics Data System (ADS)

Matney, M. J.; Hamilton, J.; Horstman, M.; Papanyan, V.

2013-08-01

On 6 August 2012, Russia launched two commercial satellites aboard a Proton rocket, and attempted to place them in geosynchronous orbit using a Briz-M upper stage (2012-044C, SSN 38746). Unfortunately, the upper stage failed early in its burn and was left stranded in an elliptical orbit with a perigee in low Earth orbit (LEO). Because the stage failed with much of its fuel on board, it was deemed a significant breakup risk. These fears were confirmed when it broke up 16 October, creating a large cloud of debris with perigees below that of the International Space Station. The debris cloud was tracked by the U.S. Space Surveillance Network (SSN), which can reliably detect and track objects down to about 10 cm in size. Because of the unusual geometry of the breakup, there was an opportunity for the NASA Orbital Debris Program Office to use specialized radar assets to characterize the extent of the debris cloud in sizes smaller than the standard debris tracked by the SSN. This paper describes the observation campaign to measure the small particle distributions of this cloud and presents the results of the data analysis. We shall compare the data to the modelled size distribution, number, and shape of the cloud, and what implications this may have for future breakup debris models. We shall conclude the paper with a discussion about how this measurement process can be improved for future breakups.

Characterization of the 2012-044C Briz-M Upper Stage Breakup

NASA Technical Reports Server (NTRS)

Matney, M. J.; Hamilton, J.; Horstman, M.; Papanyan, V.

2013-01-01

On 6 August, 2012, Russia launched two commercial satellites aboard a Proton rocket, and attempted to place them in geosynchronous orbit using a Briz-M upper stage (2012-044C, SSN 38746). Unfortunately, the upper stage failed early in its burn and was left stranded in an elliptical orbit with a perigee in low Earth orbit (LEO). Because the stage failed with much of its fuel on board, it was deemed a significant breakup risk. These fears were confirmed when it broke up 16 October, creating a large cloud of debris with perigees below that of the International Space Station. The debris cloud was tracked by the US Space Surveillance Network (SSN), which can reliably detect and track objects down to about 10 cm in size. Because of the unusual geometry of the breakup, there was an opportunity for NASA Orbital Debris Program Office to use specialized radar assets to characterize the extent of the debris cloud in sizes smaller than the standard debris tracked by the SSN. This paper will describe the observation campaign to measure the small particle distributions of this cloud, and presents the results of the analysis of the data. We shall compare the data to the modelled size distribution, number, and shape of the cloud, and what implications this may have for future breakup debris models. We shall conclude the paper with a discussion how this measurement process can be improved for future breakups.

Characterization of the 2012-044c Briz-M Upper Stage Breakup

NASA Technical Reports Server (NTRS)

Matney, M. J.; Hamilton, Joseph; Papanyan, Valen

2013-01-01

On 6 August, 2012, Russia launched two commercial satellites aboard a Proton rocket, and attempted to place them in geosynchronous orbit using a Briz-M upper stage (2012-044C, SSN 38746). Unfortunately, the upper stage failed early in its burn and was left stranded in an elliptical orbit with a perigee in low Earth orbit (LEO). Because the stage failed with much of its fuel on board, it was deemed a significant breakup risk. These fears were confirmed when it broke up 16 October, creating a large cloud of debris with perigees below that of the International Space Station. The debris cloud was tracked by the US Space Surveillance Network (SSN), which can reliably detect and track objects down to about 10 cm in size. Because of the unusual geometry of the breakup, there was an opportunity for NASA Orbital Debris Program Office to request radar assets to characterize the extent of the debris cloud in sizes smaller than the standard debris tracked by the SSN. This paper will describe the observation campaign to measure the small particle distributions of this cloud, and presents the results of the analysis of the data. We shall compare the data to the modelled size distribution, number, and shape of the cloud, and what implications this may have for future breakup debris models. We shall conclude the paper with a discussion how this measurement process can be improved for future breakups.

A Chain of Modeling Tools For Gas and Aqueous Phase Chemstry

NASA Astrophysics Data System (ADS)

Audiffren, N.; Djouad, R.; Sportisse, B.

Atmospheric chemistry is characterized by the use of large set of chemical species and reactions. Handling with the set of data required for the definition of the model is a quite difficult task. We prsent in this short article a preprocessor for diphasic models (gas phase and aqueous phase in cloud droplets) named SPACK. The main interest of SPACK is the automatic generation of lumped species related to fast equilibria. We also developped a linear tangent model using the automatic differentiation tool named ODYSSEE in order to perform a sensitivity analysis of an atmospheric multi- phase mechanism based on RADM2 kinetic scheme.Local sensitivity coefficients are computed for two different scenarii. We focus in this study on the sensitivity of the ozone,NOx,HOx, system with respect to some aqueous phase reactions and we inves- tigate the influence of the reduction in the photolysis rates in the area below the cloud region.

The 27-28 October 1986 FIRE IFO Cirrus Case Study: Cirrus Parameter Relationships Derived from Satellite and Lidar Data

NASA Technical Reports Server (NTRS)

Minnis, Patrick; Young, David F.; Sassen, Kenneth; Alvarez, Joseph M.; Grund, Christian J.

1996-01-01

Cirrus cloud radiative and physical characteristics are determined using a combination of ground based, aircraft, and satellite measurements taken as part of the First ISCCP Region Experiment (FIRE) cirrus intensive field observations (IFO) during October and November 1986. Lidar backscatter data are used with rawinsonde data to define cloud base, center and top heights and the corresponding temperatures. Coincident GOES-4 4-km visible (0.65 micrometer) and 8-km infrared window (11.5 micrometer) radiances are analyzed to determine cloud emittances and reflectances. Infrared optical depth is computed from the emittance results. Visible optical depth is derived from reflectance using a theoretical ice crystal scattering model and an empirical bidirectional reflectance model. No clouds with visible optical depths greater than 5 or infrared optical depths less than 0.1 were used in the analysis. Average cloud thickness ranged from 0.5 km to 8.0 km for the 71 scenes. Mean vertical beam emittances derived from cloud-center temperatures were 062 for all scenes compared to 0.33 for the case study (27-28 October) reflecting the thinner clouds observed for the latter scenes. Relationships between cloud emittance , extinction coefficients, and temperature for the case study are very similar to those derived from earlier surface-based studies. The thicker clouds seen during the other IFO days yield different results. Emittances derived using cloud-top temperature wer ratioed to those determined from cloud-center temperature. A nearly linear relationship between these ratios and cloud-center temperature holds promise for determining actual cloud-top temperature and cloud thickness from visible and infrared radiance pairs. The mean ratio of the visible scattering optical depth to the infrared absorption optical depth was 2.13 for these data. This scattering efficiency ratio shows a significant dependence on cloud temperature. Values of mean scattering efficiency as high as 2.6 suggest the presence of small ice particles at temperatures below 230 K. the parameterization of visible reflectance in terms of cloud optical depth and clear sky reflectance shows promise as a simplified method for interpreting visible satellite data reflected from cirrus clouds. Large uncertainties in the optical parameters due to cloud reflectance anisotropy and shading were found by analyzing data for various solar zenith angles and for simultaneous advanced very high resolution radiometer (AVHRR) data. Inhomogeneities in the cloud fields result in uneven cloud shading that apparently causes the occurrence of anomalously dark, cloud pixels in the GOES data. These shading effects complicate the interpretation of the satellite data. The results highlight the need for additional study or cirrus cloud scattering processes and remote sensing techniques.

Vertical Cloud Climatology During TC4 Derived from High-Altitude Aircraft Merged Lidar and Radar Profiles

NASA Technical Reports Server (NTRS)

Hlavka, Dennis; Tian, Lin; Hart, William; Li, Lihua; McGill, Matthew; Heymsfield, Gerald

2009-01-01

Aircraft lidar works by shooting laser pulses toward the earth and recording the return time and intensity of any of the light returning to the aircraft after scattering off atmospheric particles and/or the Earth s surface. The scattered light signatures can be analyzed to tell the exact location of cloud and aerosol layers and, with the aid of a few optical assumptions, can be analyzed to retrieve estimates of optical properties such as atmospheric transparency. Radar works in a similar fashion except it sends pulses toward earth at a much larger wavelength than lidar. Radar records the return time and intensity of cloud or rain reflection returning to the aircraft. Lidar can measure scatter from optically thin cirrus and aerosol layers whose particles are too small for the radar to detect. Radar can provide reflection profiles through thick cloud layers of larger particles that lidar cannot penetrate. Only after merging the two instrument products can accurate measurements of the locations of all layers in the full atmospheric column be achieved. Accurate knowledge of the vertical distribution of clouds is important information for understanding the Earth/atmosphere radiative balance and for improving weather/climate forecast models. This paper describes one such merged data set developed from the Tropical Composition, Cloud and Climate Coupling (TC4) experiment based in Costa Rica in July-August 2007 using the nadir viewing Cloud Physics Lidar (CPL) and the Cloud Radar System (CRS) on board the NASA ER-2 aircraft. Statistics were developed concerning cloud probability through the atmospheric column and frequency of the number of cloud layers. These statistics were calculated for the full study area, four sub-regions, and over land compared to over ocean across all available flights. The results are valid for the TC4 experiment only, as preferred cloud patterns took priority during mission planning. The TC4 Study Area was a very cloudy region, with cloudy profiles occurring 94 percent of the time during the ER-2 flights. One to three cloud layers were common, with the average calculated at 2.03 layers per profile. The upper troposphere had a cloud frequency generally over 30%, reaching 42 percent near 13 km during the study. There were regional differences. The Caribbean was much clearer than the Pacific regions. Land had a much higher frequency of high clouds than ocean areas. One region just south and west of Panama had a high probability of clouds below 15 km altitude with the frequency never dropping below 25% and reaching a maximum of 60% at 11-13 km altitude. These cloud statistics will help characterize the cloud volume for TC4 scientists as they try to understand the complexities of the tropical atmosphere.

In-vitro free radical scavenging activity of biosynthesized gold and silver nanoparticles using Prunus armeniaca (apricot) fruit extract

NASA Astrophysics Data System (ADS)

Dauthal, Preeti; Mukhopadhyay, Mausumi

2013-01-01

In-vitro free radical scavenging activity of biosynthesized gold (Au-NPs) and silver (Ag-NPs) nanoparticles was investigated in the present study. Natural precursor Prunus armeniaca (apricot) fruit extract was used as a reducing agent for the nanoparticle synthesis. The free radical scavenging activity of the nanoparticles were observed by modified 1,1'-diphynyl-2-picrylhydrazyl, DPPH and 2,2'-azinobis (3-ethylbenzothiazoline-6-sulfonic acid), ABTS assay. The synthesized nanoparticles were characterized by UV-Visible spectroscopy, dynamic light scattering, transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive spectroscopy, and fourier transform infrared spectroscopy (FTIR). Appearance of optical absorption peak at 537 nm (2.20 keV) and 435 nm (3 keV) within 0.08 and 0.5 h of reaction time was confirmed the presence of metallic Au and Ag nanoclusters, respectively. Nearly spherical nanoparticles with majority of particle below 20 nm (TEM) for both Au-NPs and Ag-NPs were synthesized. XRD pattern confirmed the existence of pure nanocrystalline Au-NPs while few additional peaks in the vicinity of fcc silver-speculated crystallization of metalloproteins of fruit extract on the surface of the Ag-NPs and vice versa. FTIR spectra was supported the role of amino acids of protein/enzymes of fruit extract for synthesis and stabilization of nanoparticles. Dose-dependent scavenging activity was observed for Au-NPs and Ag-NPs in both DPPH and ABTS in-vitro assay. 50 % scavenging activity for DPPH were 11.27 and 16.18 mg and for ABTS 3.40 and 7.12 mg with Au-NPs and Ag-NPs, respectively.

Cloud Occurrence Measurements Over Sea during the 2nd 7 Southeast Asian Studies (7SEAS) Field Campaign in Palawan Archipelago

NASA Astrophysics Data System (ADS)

Antioquia, C. T.; Uy, S. N.; Caballa, K.; Lagrosas, N.

2014-12-01

Ground based sky imaging cameras have been used to measure cloud cover over an area to aid in radiation budget models. During daytime, certain clouds tend to help decrease atmospheric temperature by obstructing sunrays in the atmosphere. Thus, the detection of clouds plays an important role in the formulation of radiation budget in the atmosphere. In this study, a wide angled sky imager (GoPro Hero 2) was brought on board M/Y Vasco to detect and quantity cloud occurrence over sea during the 2nd 7SEAS field campaign. The camera is just a part of a number of scientific instruments used to measure weather, aerosol chemistry and solar radiation among others. The data collection started during the departure from Manila Bay on 05 September 2012 and went on until the end of the cruise (29 September 2012). The camera was placed in a weather-proof box that is then affixed on a steel mast where other instruments are also attached during the cruise. The data has a temporal resolution of 1 minute, and each image is 500x666 pixels in size. Fig. 1a shows the track of the ship during the cruise. The red, blue, hue, saturation, and value of the pixels are analysed for cloud occurrence. A pixel is considered to "contain" thick cloud if it passes all four threshold parameters (R-B, R/B, R-B/R+B, HSV; R is the red pixel color value, blue is the blue pixel color value, and HSV is the hue saturation value of the pixel) and considered thin cloud if it passes two or three parameters. Fig. 1b shows the daily analysis of cloud occurrence. Cloud occurrence here is quantified as the ratio of the pixels with cloud to the total number of pixels in the data image. The average cloud cover for the days included in this dataset is 87%. These measurements show a big contrast when compared to cloud cover over land (Manila Observatory) which is usually around 67%. During the duration of the cruise, only one day (September 6) has an average cloud occurrence below 50%; the rest of the days have averages of 66% or higher - 98% being the highest. This result would then give a general trend of how cloud occurrences over land and over sea differ in the South East Asian region. In this study, these cloud occurrences come from local convection and clouds brought about by Southwest Monsoon winds.

Experimental measurements of the ground cloud effluents and cloud growth for the May 20, 1975, Titan 3C launch at Air Force Eastern Test Range, Florida

NASA Technical Reports Server (NTRS)

Gregory, G. L.; Storey, R. W., Jr.

1977-01-01

The experiment included surface level and airborne in situ cloud measurements of the exhaust effluents from the Titan IIIC solid rocket boosters. Simultaneous visible spectrum photographic pictures of the ground cloud as well as infrared imaging of the cloud were obtained to study the cloud rise, growth, and direction of travel within the earth's surface mixing layer. The NASA multilayer diffusion model predictions of cloud growth, direction of travel, and expected surface level effluent concentrations were made prior to launch and after launch using measured meteorological conditions. Prelaunch predictions were used to position the effluent monitoring instruments, and the postlaunch predictions were compared with the measured data. Measurement results showed that surface level effluent values were low, often below the detection limits of the instrumentation. The maximum surface level hydrogen chloride concentration measured 50 parts per billion at about 8 km from the launch pad. The maximum observed in-cloud (airborne measurement) hydrogen chloride concentration was 7 per million.

Photolysis frequency and cloud dynamics during DC3 and SEAC4RS

NASA Astrophysics Data System (ADS)

Hall, S. R.; Ullmann, K.; Madronich, S.; Hair, J. W.; Butler, C. F.; Fenn, M. A.

2013-12-01

Cloud shading plays a critical role in extending the lifetime of short-lived chemical species. During convection, photochemistry is reduced such that short-lived species may be transported from the boundary layer to the upper troposphere/ lower stratosphere. In the anvil outflow, shading continues within and below the cloud. However, near the highly scattering cloud top, the chemistry is greatly accelerated. In this rapidly evolving environment, accurate photolysis frequencies are required to study photochemical evolution of the complex composition. During the Deep Convective Clouds and Chemistry (DC3, 2012) and the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS, 2013) campaigns, photolysis frequencies were determined by measurement of spectrally resolved actinic flux by the Charge-coupled device Actinic Flux Spectroradiometer (CAFS) on the NASA DC-8 and the HIAPER Airborne Radiation Package (HARP) on the NCAR G-V aircraft. Vertical flight profiles allowed in situ characterization of the radiation environment. Input of geometrical cloud characteristics into the Tropospheric Ultraviolet and Visible (TUV) Radiation was used to constrain cloud optical depths for more spatially and temporally stable conditions.

Detailed source term estimation of the atmospheric release for the Fukushima Daiichi Nuclear Power Station accident by coupling simulations of atmospheric dispersion model with improved deposition scheme and oceanic dispersion model

NASA Astrophysics Data System (ADS)

Katata, G.; Chino, M.; Kobayashi, T.; Terada, H.; Ota, M.; Nagai, H.; Kajino, M.; Draxler, R.; Hort, M. C.; Malo, A.; Torii, T.; Sanada, Y.

2014-06-01

Temporal variations in the amount of radionuclides released into the atmosphere during the Fukushima Dai-ichi Nuclear Power Station (FNPS1) accident and their atmospheric and marine dispersion are essential to evaluate the environmental impacts and resultant radiological doses to the public. In this paper, we estimate a detailed time trend of atmospheric releases during the accident by combining environmental monitoring data with atmospheric model simulations from WSPEEDI-II (Worldwide version of System for Prediction of Environmental Emergency Dose Information), and simulations from the oceanic dispersion model SEA-GEARN-FDM, both developed by the authors. A sophisticated deposition scheme, which deals with dry and fogwater depositions, cloud condensation nuclei (CCN) activation and subsequent wet scavenging due to mixed-phase cloud microphysics (in-cloud scavenging) for radioactive iodine gas (I2 and CH3I) and other particles (CsI, Cs, and Te), was incorporated into WSPEEDI-II to improve the surface deposition calculations. The fallout to the ocean surface calculated by WSPEEDI-II was used as input data for the SEA-GEARN-FDM calculations. Reverse and inverse source-term estimation methods based on coupling the simulations from both models was adopted using air dose rates and concentrations, and sea surface concentrations. The results revealed that the major releases of radionuclides due to FNPS1 accident occurred in the following periods during March 2011: the afternoon of 12 March due to the wet venting and hydrogen explosion at Unit 1, the morning of 13 March after the venting event at Unit 3, midnight of 14 March when the SRV (Safely Relief Valve) at Unit 2 was opened three times, the morning and night of 15 March, and the morning of 16 March. According to the simulation results, the highest radioactive contamination areas around FNPS1 were created from 15 to 16 March by complicated interactions among rainfall, plume movements, and the temporal variation of release rates associated with reactor pressure changes in Units 2 and 3. The modified WSPEEDI-II simulation using the new source term reproduced local and regional patterns of cumulative surface deposition of total 131I and 137Cs and air dose rate obtained by airborne surveys. The new source term was also tested using three atmospheric dispersion models (MLDP0, HYSPLIT, and NAME) for regional and global calculations and showed good agreement between calculated and observed air concentration and surface deposition of 137Cs in East Japan. Moreover, HYSPLIT model using the new source term also reproduced the plume arrivals at several countries abroad showing a good correlation with measured air concentration data. A large part of deposition pattern of total 131I and 137Cs in East Japan was explained by in-cloud particulate scavenging. However, for the regional scale contaminated areas, there were large uncertainties due to the overestimation of rainfall amounts and the underestimation of fogwater and drizzle depositions. The computations showed that approximately 27% of 137Cs discharged from FNPS1 deposited to the land in East Japan, mostly in forest areas.

Hurricane Karl's Structure and Some Thoughts for 2014 Strategy

NASA Technical Reports Server (NTRS)

Cecil, Dan; Leppert, Ken, II

2014-01-01

Karl has interesting data, but far below the standards we should be able to achieve in HS3. We need to fly AV-1 over hurricanes in 2014. Most of the cold cloud shield in the inner core of hurricanes should be safe for AV-1 to fly. Significant convection occupies a small region, but we sometimes unnecessarily apply the 5000-ft separation rule to the entire cold cloud shield.

The 27-28 October 1986 FIRE IFO Cirrus Case Study: Cirrus Parameter Relationships Derived from Satellite and Lidar Data

NASA Technical Reports Server (NTRS)

Minnis, Patrick; Young, David F.; Sassen, Kenneth; Alvarez, Joseph M.; Grund, Christian J.

1990-01-01

Cirrus cloud radiative and physical characteristics are determined using a combination of ground-based, aircraft, and satellite measurements taken as part of the FIRE Cirrus Intensive Field Observations (IFO) during October and November 1986. Lidar backscatter data are used with rawinsonde data to define cloud base, center, and top heights and the corresponding temperatures. Coincident GOES 4-km visible (0.65 micro-m) and 8-km infrared window (11.5 micro-m) radiances are analyzed to determine cloud emittances and reflectances. Infrared optical depth is computed from the emittance results. Visible optical depth is derived from reflectance using a theoretical ice crystal scattering model and an empirical bidirectional reflectance model. No clouds with visible optical depths greater than 5 or infrared optical depths less than 0.1 were used in the analysis. Average cloud thickness ranged from 0.5 km to 8.0 km for the 71 scenes. Mean vertical beam emittances derived from cloud-center temperatures were 0.62 for all scenes compared to 0.33 for the case study (27-28 October) reflecting the thinner clouds observed for the latter scenes. Relationships between cloud emittance, extinction coefficients, and temperature for the case study are very similar to those derived from earlier surface- based studies. The thicker clouds seen during the other IFO days yield different results. Emittances derived using cloud-top temperature were ratioed to those determined from cloud-center temperature. A nearly linear relationship between these ratios and cloud-center temperature holds promise for determining actual cloud-top temperatures and cloud thicknesses from visible and infrared radiance pairs. The mean ratio of the visible scattering optical depth to the infrared absorption optical depth was 2.13 for these data. This scattering efficiency ratio shows a significant dependence on cloud temperature. Values of mean scattering efficiency as high as 2.6 suggest the presence of small ice particles at temperatures below 230 K. The parameterization of visible reflectance in terms of cloud optical depth and clear-sky reflectance shows promise as a simplified method for interpreting visible satellite data reflected from cirrus clouds. Large uncertainties in the optical parameters due to cloud reflectance anisotropy and shading were found by analyzing data for various solar zenith angles and for simultaneous AVHRR data. Inhomogeneities in the cloud fields result in uneven cloud shading that apparently causes the occurrence of anomalously dark, cloudy pixels in the GOES data. These shading effects complicate the interpretation of the satellite data. The results highlight the need for additional study of cirrus cloud scattering processes and remote sensing techniques.

A simple model for the cloud adjacency effect and the apparent bluing of aerosols near clouds

NASA Astrophysics Data System (ADS)

Marshak, Alexander; Wen, Guoyong; Coakley, James A.; Remer, Lorraine A.; Loeb, Norman G.; Cahalan, Robert F.

2008-07-01

In determining aerosol-cloud interactions, the properties of aerosols must be characterized in the vicinity of clouds. Numerous studies based on satellite observations have reported that aerosol optical depths increase with increasing cloud cover. Part of the increase comes from the humidification and consequent growth of aerosol particles in the moist cloud environment, but part comes from 3-D cloud-radiative transfer effects on the retrieved aerosol properties. Often, discerning whether the observed increases in aerosol optical depths are artifacts or real proves difficult. The paper only addresses the cloud-clear sky radiative transfer interaction part. It provides a simple model that quantifies the enhanced illumination of cloud-free columns in the vicinity of clouds that are used in the aerosol retrievals. This model is based on the assumption that the enhancement in the cloud-free column radiance comes from enhanced Rayleigh scattering that results from the presence of the nearby clouds. This assumption leads to a larger increase of AOT for shorter wavelengths, or to a "bluing" of aerosols near clouds. The assumption that contribution from molecular scattering dominates over aerosol scattering and surface reflection is justified for the case of shorter wavelengths, dark surfaces, and an aerosol layer below the cloud tops. The enhancement in Rayleigh scattering is estimated using a stochastic cloud model to obtain the radiative flux reflected by broken clouds and comparing this flux with that obtained with the molecules in the atmosphere causing extinction, but no scattering.

ALMA Reveals Molecular Cloud N55 in the Large Magellanic Cloud as a Site of Massive Star Formation

NASA Astrophysics Data System (ADS)

Naslim, N.; Tokuda, K.; Onishi, T.; Kemper, F.; Wong, T.; Morata, O.; Takada, S.; Harada, R.; Kawamura, A.; Saigo, K.; Indebetouw, R.; Madden, S. C.; Hony, S.; Meixner, M.

2018-02-01

We present the molecular cloud properties of N55 in the Large Magellanic Cloud using 12CO(1–0) and 13CO(1–0) observations obtained with Atacama Large Millimeter Array. We have done a detailed study of molecular gas properties, to understand how the cloud properties of N55 differ from Galactic clouds. Most CO emission appears clumpy in N55, and molecular cores that have young stellar objects (YSOs) show larger linewidths and masses. The massive clumps are associated with high and intermediate mass YSOs. The clump masses are determined by local thermodynamic equilibrium and virial analysis of the 12CO and 13CO emissions. These mass estimates lead to the conclusion that (a) the clumps are in self-gravitational virial equilibrium, and (b) the 12CO(1–0)-to-H2 conversion factor, {X}{CO}, is 6.5 × 1020 cm‑2 (K km s‑1)‑1. This CO-to-H2 conversion factor for N55 clumps is measured at a spatial scale of ∼0.67 pc, which is about two times higher than the {X}{CO} value of the Orion cloud at a similar spatial scale. The core mass function of N55 clearly show a turnover below 200 {M}ȯ , separating the low-mass end from the high-mass end. The low-mass end of the 12CO mass spectrum is fitted with a power law of index 0.5 ± 0.1, while for 13CO it is fitted with a power law index 0.6 ± 0.2. In the high-mass end, the core mass spectrum is fitted with a power index of 2.0 ± 0.3 for 12CO, and with 2.5 ± 0.4 for 13CO. This power law behavior of the core mass function in N55 is consistent with many Galactic clouds.

Reaction of chlorine nitrate with hydrogen chloride and water at Antarctic stratospheric temperatures

NASA Technical Reports Server (NTRS)

Tolbert, Margaret A.; Rossi, Michel J.; Malhotra, Ripudaman; Golden, David M.

1987-01-01

Laboratory studies of heterogeneous reactions important for ozone depletion over Antarctica are reported. The reaction of chlorine nitrate (ClONO2) with H2O and HCl on surfacers that simulate polar stratospheric clouds are studied at temperatures relevant to the Antarctic stratosphere. The gaseous products of the resulting reactions, HOCl, Cl2O, and Cl2, could readily photolyze in the Antarctic spring to produce active chlorine for ozone depletion. Furthermore, the additional formation of condensed-phase HNO3 could serve as a sink for odd nitrogen species that would otherwise scavenge the active chlorine.

Low-CCN concentration air masses over the eastern North Atlantic: Seasonality, meteorology, and drivers

NASA Astrophysics Data System (ADS)

Wood, Robert; Stemmler, Jayson D.; Rémillard, Jasmine; Jefferson, Anne

2017-01-01

A 20 month cloud condensation nucleus concentration (NCCN) data set from Graciosa Island (39°N, 28°W) in the remote North Atlantic is used to characterize air masses with low cloud condensation nuclei (CCN) concentrations. Low-CCN events are defined as 6 h periods with mean NCCN<20 cm-3 (0.1% supersaturation). A total of 47 low-CCN events are identified. Surface, satellite, and reanalysis data are used to explore the meteorological and cloud context for low-CCN air masses. Low-CCN events occur in all seasons, but their frequency was 3 times higher in December-May than during June-November. Composites show that many of the low-CCN events had a common meteorological basis that involves southerly low-level flow and rather low wind speeds at Graciosa. Anomalously low pressure is situated to the west of Graciosa during these events, but back trajectories and lagged SLP composites indicate that low-CCN air masses often originate as cold air outbreaks to the north and west of Graciosa. Low-CCN events were associated with low cloud droplet concentrations (Nd) at Graciosa, but liquid water path (LWP) during low-CCN events was not systematically different from that at other times. Satellite Nd and LWP estimates from MODIS collocated with Lagrangian back trajectories show systematically lower Nd and higher LWP several days prior to arrival at Graciosa, consistent with the hypothesis that observed low-CCN air masses are often formed by coalescence scavenging in thick warm clouds, often in cold air outbreaks.

Cloud radiative effect, cloud fraction and cloud type at two stations in Switzerland using hemispherical sky cameras

NASA Astrophysics Data System (ADS)

Aebi, Christine; Gröbner, Julian; Kämpfer, Niklaus; Vuilleumier, Laurent

2017-11-01

The current study analyses the cloud radiative effect during the daytime depending on cloud fraction and cloud type at two stations in Switzerland over a time period of 3 to 5 years. Information on fractional cloud coverage and cloud type is retrieved from images taken by visible all-sky cameras. Cloud-base height (CBH) data are retrieved from a ceilometer and integrated water vapour (IWV) data from GPS measurements. The longwave cloud radiative effect (LCE) for low-level clouds and a cloud coverage of 8 oktas has a median value between 59 and 72 Wm-2. For mid- and high-level clouds the LCE is significantly lower. It is shown that the fractional cloud coverage, the CBH and IWV all have an influence on the magnitude of the LCE. These observed dependences have also been modelled with the radiative transfer model MODTRAN5. The relative values of the shortwave cloud radiative effect (SCErel) for low-level clouds and a cloud coverage of 8 oktas are between -90 and -62 %. Also here the higher the cloud is, the less negative the SCErel values are. In cases in which the measured direct radiation value is below the threshold of 120 Wm-2 (occulted sun) the SCErel decreases substantially, while cases in which the measured direct radiation value is larger than 120 Wm-2 (visible sun) lead to a SCErel of around 0 %. In 14 and 10 % of the cases in Davos and Payerne respectively a cloud enhancement has been observed with a maximum in the cloud class cirrocumulus-altocumulus at both stations. The calculated median total cloud radiative effect (TCE) values are negative for almost all cloud classes and cloud coverages.

The Role of Clouds: An Introduction and Rapporteur Report

NASA Technical Reports Server (NTRS)

Taylor, Patrick C.

2012-01-01

This paper presents an overview of discussions during the Cloud s Role session at the Observing and Modelling Earth s Energy Flows Workshop. N. Loeb and B. Soden convened this session including 10 presentations by B. Stevens, B. Wielicki, G. Stephens, A. Clement, K. Sassen, D. Hartmann, T. Andrews, A. Del Genio, H. Barker, and M. Sugi addressing critical aspects of the role of clouds in modulating Earth energy flows. Presentation topics covered a diverse range of areas from cloud microphysics and dynamics, cloud radiative transfer, and the role of clouds in large-scale atmospheric circulations patterns in both observations and atmospheric models. The presentations and discussions, summarized below, are organized around several key questions raised during the session. (1) What is the best way to evaluate clouds in climate models? (2) How well do models need to represent clouds to be acceptable for making climate predictions? (3) What are the largest uncertainties in clouds? (4) How can these uncertainties be reduced? (5) What new observations are needed to address these problems? Answers to these critical questions are the topics of ongoing research and will guide the future direction of this area of research.

The Role of Clouds: An Introduction and Rapporteur Report

NASA Astrophysics Data System (ADS)

Taylor, Patrick C.

2012-07-01

This paper presents an overview of discussions during the Cloud's Role session at the Observing and Modelling Earth's Energy Flows Workshop. N. Loeb and B. Soden convened this session including 10 presentations by B. Stevens, B. Wielicki, G. Stephens, A. Clement, K. Sassen, D. Hartmann, T. Andrews, A. Del Genio, H. Barker, and M. Sugi addressing critical aspects of the role of clouds in modulating Earth energy flows. Presentation topics covered a diverse range of areas from cloud microphysics and dynamics, cloud radiative transfer, and the role of clouds in large-scale atmospheric circulations patterns in both observations and atmospheric models. The presentations and discussions, summarized below, are organized around several key questions raised during the session. (1) What is the best way to evaluate clouds in climate models? (2) How well do models need to represent clouds to be acceptable for making climate predictions? (3) What are the largest uncertainties in clouds? (4) How can these uncertainties be reduced? (5) What new observations are needed to address these problems? Answers to these critical questions are the topics of ongoing research and will guide the future direction of this area of research.

A Review of Spatial and Seasonal Changes in Condensation Clouds Observed During Aerobraking by MGS TES

NASA Technical Reports Server (NTRS)

Pearl, J. C.; Smith, M. D.; Conrath, B. J.; Bandfield, J. L.; Christensen, P. R.

1999-01-01

Successful operation of the Mars Global Surveyor spacecraft beginning in September 1997, has permitted extensive infrared observations of condensation clouds during the martian southern summer and fall seasons (184 deg

Jupiter Eruptions Captured in Infrared

NASA Technical Reports Server (NTRS)

2008-01-01

[figure removed for brevity, see original site] Click on the image for high resolution image of Nature Cover

Detailed analysis of two continent-sized storms that erupted in Jupiter's atmosphere in March 2007 shows that Jupiter's internal heat plays a significant role in generating atmospheric disturbances. Understanding these outbreaks could be the key to unlock the mysteries buried in the deep Jovian atmosphere, say astronomers.

This infrared image shows two bright plume eruptions obtained by the NASA Infrared Telescope Facility on April 5, 2007.

Understanding these phenomena is important for Earth's meteorology where storms are present everywhere and jet streams dominate the atmospheric circulation. Jupiter is a natural laboratory where atmospheric scientists study the nature and interplay of the intense jets and severe atmospheric phenomena.

According to the analysis, the bright plumes were storm systems triggered in Jupiter's deep water clouds that moved upward in the atmosphere vigorously and injected a fresh mixture of ammonia ice and water about 20 miles (30 kilometers) above the visible clouds. The storms moved in the peak of a jet stream in Jupiter's atmosphere at 375 miles per hour (600 kilometers per hour). Models of the disturbance indicate that the jet stream extends deep in the buried atmosphere of Jupiter, more than 60 miles (approximately100 kilometers) below the cloud tops where most sunlight is absorbed.

Jupiter Eruptions

NASA Technical Reports Server (NTRS)

2008-01-01

[figure removed for brevity, see original site] Click on the image for high resolution image of Nature Cover

Detailed analysis of two continent-sized storms that erupted in Jupiter's atmosphere in March 2007 shows that Jupiter's internal heat plays a significant role in generating atmospheric disturbances. Understanding these outbreaks could be the key to unlock the mysteries buried in the deep Jovian atmosphere, say astronomers.

This visible-light image is from NASA's Hubble Space Telescope taken on May 11, 2007. It shows the turbulent pattern generated by the two plumes on the upper left part of Jupiter.

Understanding these phenomena is important for Earth's meteorology where storms are present everywhere and jet streams dominate the atmospheric circulation. Jupiter is a natural laboratory where atmospheric scientists study the nature and interplay of the intense jets and severe atmospheric phenomena.

According to the analysis, the bright plumes were storm systems triggered in Jupiter's deep water clouds that moved upward in the atmosphere vi gorously and injected a fresh mixture of ammonia ice and water about 20 miles (30 kilometers) above the visible clouds. The storms moved in the peak of a jet stream in Jupiter's atmosphere at 375 miles per hour (600 kilometers per hour). Models of the disturbance indicate that the jet stream extends deep in the buried atmosphere of Jupiter, more than 60 miles (approximately100 kilometers) below the cloud tops where most sunlight is absorbed.

DSCOVR/EPIC observations of SO2 reveal dynamics of young volcanic eruption clouds

NASA Astrophysics Data System (ADS)

Carn, S. A.; Krotkov, N. A.; Taylor, S.; Fisher, B. L.; Li, C.; Bhartia, P. K.; Prata, F. J.

2017-12-01

Volcanic emissions of sulfur dioxide (SO2) and ash have been measured by ultraviolet (UV) and infrared (IR) sensors on US and European polar-orbiting satellites since the late 1970s. Although successful, the main limitation of these observations from low Earth orbit (LEO) is poor temporal resolution (once per day at low latitudes). Furthermore, most currently operational geostationary satellites cannot detect SO2, a key tracer of volcanic plumes, limiting our ability to elucidate processes in fresh, rapidly evolving volcanic eruption clouds. In 2015, the launch of the Earth Polychromatic Imaging Camera (EPIC) aboard the Deep Space Climate Observatory (DSCOVR) provided the first opportunity to observe volcanic clouds from the L1 Lagrange point. EPIC is a 10-band spectroradiometer spanning UV to near-IR wavelengths with two UV channels sensitive to SO2, and a ground resolution of 25 km. The unique L1 vantage point provides continuous observations of the sunlit Earth disk, from sunrise to sunset, offering multiple daily observations of volcanic SO2 and ash clouds in the EPIC field of view. When coupled with complementary retrievals from polar-orbiting UV and IR sensors such as the Ozone Monitoring Instrument (OMI), the Ozone Mapping and Profiler Suite (OMPS), and the Atmospheric Infrared Sounder (AIRS), we demonstrate how the increased observation frequency afforded by DSCOVR/EPIC permits more timely volcanic eruption detection and novel analyses of the temporal evolution of volcanic clouds. Although EPIC has detected several mid- to high-latitude volcanic eruptions since launch, we focus on recent eruptions of Bogoslof volcano (Aleutian Islands, AK, USA). A series of EPIC exposures from May 28-29, 2017, uniquely captures the evolution of SO2 mass in a young Bogoslof eruption cloud, showing separation of SO2- and ice-rich regions of the cloud. We show how analyses of these sequences of EPIC SO2 data can elucidate poorly understood processes in transient eruption clouds, such as the relative roles of H2S oxidation and ice scavenging in modifying volcanic SO2 emissions. Detection of these relatively small events also proves EPIC's ability to provide timely detection of volcanic clouds in the upper troposphere and lower stratosphere.

Iodide accumulation provides kelp with an inorganic antioxidant impacting atmospheric chemistry

PubMed Central

Küpper, Frithjof C.; Carpenter, Lucy J.; McFiggans, Gordon B.; Palmer, Carl J.; Waite, Tim J.; Boneberg, Eva-Maria; Woitsch, Sonja; Weiller, Markus; Abela, Rafael; Grolimund, Daniel; Potin, Philippe; Butler, Alison; Luther, George W.; Kroneck, Peter M. H.; Meyer-Klaucke, Wolfram; Feiters, Martin C.

2008-01-01

Brown algae of the Laminariales (kelps) are the strongest accumulators of iodine among living organisms. They represent a major pump in the global biogeochemical cycle of iodine and, in particular, the major source of iodocarbons in the coastal atmosphere. Nevertheless, the chemical state and biological significance of accumulated iodine have remained unknown to this date. Using x-ray absorption spectroscopy, we show that the accumulated form is iodide, which readily scavenges a variety of reactive oxygen species (ROS). We propose here that its biological role is that of an inorganic antioxidant, the first to be described in a living system. Upon oxidative stress, iodide is effluxed. On the thallus surface and in the apoplast, iodide detoxifies both aqueous oxidants and ozone, the latter resulting in the release of high levels of molecular iodine and the consequent formation of hygroscopic iodine oxides leading to particles, which are precursors to cloud condensation nuclei. In a complementary set of experiments using a heterologous system, iodide was found to effectively scavenge ROS in human blood cells. PMID:18458346

Evaluation of the Physical and Chemical Properties of Eyjafjallajökull Volcanic Plume Using a Cloud-Resolving Model

NASA Astrophysics Data System (ADS)

Spiridonov, Vlado; Curic, Mladjen

2013-11-01

The Eyjafjallajökull volcanic eruption, which occurred on April 14, 2010, caused many environmental, air traffic and health problems. An attempt has been made to demonstrate for the first time that certain improvements could be made in the quantitative prediction of the volcanic ash parameters, and in the accounting of the processes in the immediate vicinity of the volcano, using a cloud-resolving model. This type of explicit modeling by treatment of volcanic ash and sulfate chemistry parameterization, with input of a number parameters describing the volcanic source, is the way forward for understanding the complex processes in plumes and in the future plume dispersion modeling. Results imply that the most significant microphysical processes are those related to accretion of cloud water, cloud ice and rainwater by snow, and accretion of rain and snow by hail. The dominant chemical conversion rates that give a great contribution to the sulfate budget are nucleation and dynamic scavenging and oxidation processes. A three-dimensional numerical experiment has shown a very realistic simulation of volcanic ash and other chemical compounds evolution, with a sloping structure strongly influenced by the meteorological conditions. In-cloud oxidation by H2O2 is the dominant pathway for SO2 oxidation and allows sulfate to be produced within the SO2 source region. The averaged cloud water pH of about 5.8 and rainwater pH of 4.5 over simulation time show quantitatively how the oxidation may strongly influence the sulfate budget and acidity of volcanic cloud. Compared to observations, model results are close in many aspects. Information on the near field volcanic plume behavior is essential for early preparedness and evacuation. This approach demonstrates a potential improvement in quantitative predictions regarding the volcanic plume distribution at different altitudes. It could be a useful tool for modeling volcanic plumes for better emergency measures planning.

Melatonin and its precursors scavenge nitric oxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Noda, Y.; Mori, A.; Liburdy, R.

Nitric oxide (NO) scavenging activity of melatonin, N-acetyl-5-hydroxytryptamine, serotonin, 5-hydroxytryptophan and L-tryptophan was examined by the Griess reaction using flow injection analysis. 1-Hydroxy-2-oxo-3-(N-methyl-3-aminopropyl)-3-methyl-1-triazene(NOC-7) was used as NO generator. The Griess reagent stoichiometrically reacts with NO2-, which was converted by a cadmium-copper reduction column from the stable end products of NO oxidation. Except for tryptophan, all the compounds examined scavenged NO in a dose-dependent manner. Melatonin, which has a methoxy group in the 5-position and an acetyl side chain, exhibited the most potent scavenging activity among the compounds tested. Serotonin, N-acetyl-5-hydroxytryptamine, and 5-hydroxytryptophan, respectively, showed moderate scavenging activity compared to melatonin.more » Tryptophan, which has neither a methoxy nor a hydroxyl group in the 5-position, exhibited the least NO scavenging activity.« less

Precombination Cloud Collapse and Baryonic Dark Matter

NASA Technical Reports Server (NTRS)

Hogan, Craig J.

1993-01-01

A simple spherical model of dense baryon clouds in the hot big bang 'strongly nonlinear primordial isocurvature baryon fluctuations' is reviewed and used to describe the dependence of cloud behavior on the model parameters, baryon mass, and initial over-density. Gravitational collapse of clouds before and during recombination is considered including radiation diffusion and trapping, remnant type and mass, and effects on linear large-scale fluctuation modes. Sufficiently dense clouds collapse early into black holes with a minimum mass of approx. 1 solar mass, which behave dynamically like collisionless cold dark matter. Clouds below a critical over-density, however, delay collapse until recombination, remaining until then dynamically coupled to the radiation like ordinary diffuse baryons, and possibly producing remnants of other kinds and lower mass. The mean density in either type of baryonic remnant is unconstrained by observed element abundances. However, mixed or unmixed spatial variations in abundance may survive in the diffuse baryon and produce observable departures from standard predictions.

"Ask Argonne" - Edwin Campos, Research Meteorologist, Part 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edwin Campos

2013-05-08

Dr. Edwin Campos is a Research Meteorologist at Argonne National Laboratory. For the last two decades, he has studied weather, and in particular, clouds. Clouds are one of the most uncertain variables in climate predictions and are often related to transportation hazards. Clouds can also impact world-class sporting events like the Olympics. You may have questions about the role of clouds, or weather, on our daily lives. How is severe weather monitored for airports? What is the impact of clouds and wind on the generation of electricity? One of the projects Edwin is working on is short-term forecasting as itmore » relates to solar electricity. For this, Edwin's team is partnering with industry and academia to study new ways of forecasting clouds, delivering technologies that will allow the incorporation of more solar power into the electric grid. Post a question for Edwin as a comment below, and it might get answered in the follow-up video we'll post in the next few weeks.« less

Motion-Compensated Compression of Dynamic Voxelized Point Clouds.

PubMed

De Queiroz, Ricardo L; Chou, Philip A

2017-05-24

Dynamic point clouds are a potential new frontier in visual communication systems. A few articles have addressed the compression of point clouds, but very few references exist on exploring temporal redundancies. This paper presents a novel motion-compensated approach to encoding dynamic voxelized point clouds at low bit rates. A simple coder breaks the voxelized point cloud at each frame into blocks of voxels. Each block is either encoded in intra-frame mode or is replaced by a motion-compensated version of a block in the previous frame. The decision is optimized in a rate-distortion sense. In this way, both the geometry and the color are encoded with distortion, allowing for reduced bit-rates. In-loop filtering is employed to minimize compression artifacts caused by distortion in the geometry information. Simulations reveal that this simple motion compensated coder can efficiently extend the compression range of dynamic voxelized point clouds to rates below what intra-frame coding alone can accommodate, trading rate for geometry accuracy.

HCl in rocket exhaust clouds - Atmospheric dispersion, acid aerosol characteristics, and acid rain deposition

NASA Technical Reports Server (NTRS)

Pellett, G. L.; Sebacher, D. I.; Bendura, R. J.; Wornom, D. E.

1983-01-01

Both measurements and model calculations of the temporal dispersion of peak HCl (g + aq) concentration in Titan III exhaust clouds are found to be well characterized by one-term power-law decay expressions. The respective coefficients and decay exponents, however, are found to vary widely with meteorology. The HCl (g), HCl (g + aq), dewpoint, and temperature-pressure-altitude data for Titan III exhaust clouds are consistent with accurately calculated HCl/H2O vapor-liquid compositions for a model quasi-equilibrated flat surface aqueous aerosol. Some cloud evolution characteristics are also defined. Rapid and extensive condensation of aqueous acid clearly occurs during the first three min of cloud rise. Condensation is found to be intensified by the initial entrainment of relatively moist ambient air from lower levels, that is, from levels below eventual cloud stabilization. It is pointed out that if subsequent dilution air at stabilization altitude is significantly drier, a state of maximum condensation soon occurs, followed by an aerosol evaporation phase.

"Ask Argonne" - Edwin Campos, Research Meteorologist, Part 1

ScienceCinema

Edwin Campos

2017-12-09

Dr. Edwin Campos is a Research Meteorologist at Argonne National Laboratory. For the last two decades, he has studied weather, and in particular, clouds. Clouds are one of the most uncertain variables in climate predictions and are often related to transportation hazards. Clouds can also impact world-class sporting events like the Olympics. You may have questions about the role of clouds, or weather, on our daily lives. How is severe weather monitored for airports? What is the impact of clouds and wind on the generation of electricity? One of the projects Edwin is working on is short-term forecasting as it relates to solar electricity. For this, Edwin's team is partnering with industry and academia to study new ways of forecasting clouds, delivering technologies that will allow the incorporation of more solar power into the electric grid. Post a question for Edwin as a comment below, and it might get answered in the follow-up video we'll post in the next few weeks.

Still from High-Clouds Jupiter Movie

NASA Technical Reports Server (NTRS)

2000-01-01

This image is one of seven from the narrow-angle camera on NASA's Cassini spacecraft assembled as a brief movie of high-altitude cloud movements on Jupiter. It was taken in early October 2000.

The images were taken at a wavelength that is absorbed by methane, one chemical in Jupiter's lower clouds. So, dark areas are relatively free of high clouds, and the camera sees through to the methane in a lower level. Bright areas are places with high, thick clouds that shield the methane below.

The area shown covers latitudes from 50 degrees north to 50 degrees south and a 100-degree sweep of longitude.

Cassini is a cooperative project of NASA, the European Space Agency and the Italian Space Agency. The Jet Propulsion Laboratory, a division of the California Institute of Technology in Pasadena, manages the Cassini mission for NASA's Office of Space Science, Washington, D.C.

A rigorous detection of interstellar CH3NCO: An important missing species in astrochemical networks.

PubMed

Cernicharo, J; Kisiel, Z; Tercero, B; Kolesniková, L; Medvedev, I R; López, A; Fortman, S; Winnewisser, M; de Lucia, F C; Alonso, J L; Guillemin, J-C

2016-03-01

The recent analysis of the composition of the frozen surface of comet 67P/Churyumov-Gerasimenko has revealed a significant number of complex organic molecules. Methyl isocyanate (CH 3 NCO) is one of the more abundant species detected on the comet surface. In this work we report extensive characterization of its rotational spectrum resulting in a list of 1269 confidently assigned laboratory lines and its detection in space towards the Orion clouds where 399 lines of the molecule have been unambiguously identified. We find that the limited mm-wave laboratory data reported prior to our work require some revision. The abundance of CH 3 NCO in Orion is only a factor of ten below those of HNCO and CH 3 CN. Unlike the molecular abundances in the coma of comets, which correlate with those of warm molecular clouds, molecular abundances in the gas phase in Orion are only weakly correlated with those measured on the comet surface. We also compare our abundances with those derived recently for this molecule towards Sgr B2 (Halfen et al. 2015). A more accurate abundance of CH 3 NCO is provided for this cloud based on our extensive laboratory work.

A rigorous detection of interstellar CH3NCO: An important missing species in astrochemical networks⋆,⋆⋆

PubMed Central

Cernicharo, J.; Kisiel, Z.; Tercero, B.; Kolesniková, L.; Medvedev, I.R.; López, A.; Fortman, S.; Winnewisser, M.; de Lucia, F. C.; Alonso, J. L.; Guillemin, J.-C.

2016-01-01

The recent analysis of the composition of the frozen surface of comet 67P/Churyumov-Gerasimenko has revealed a significant number of complex organic molecules. Methyl isocyanate (CH3NCO) is one of the more abundant species detected on the comet surface. In this work we report extensive characterization of its rotational spectrum resulting in a list of 1269 confidently assigned laboratory lines and its detection in space towards the Orion clouds where 399 lines of the molecule have been unambiguously identified. We find that the limited mm-wave laboratory data reported prior to our work require some revision. The abundance of CH3NCO in Orion is only a factor of ten below those of HNCO and CH3CN. Unlike the molecular abundances in the coma of comets, which correlate with those of warm molecular clouds, molecular abundances in the gas phase in Orion are only weakly correlated with those measured on the comet surface. We also compare our abundances with those derived recently for this molecule towards Sgr B2 (Halfen et al. 2015). A more accurate abundance of CH3NCO is provided for this cloud based on our extensive laboratory work. PMID:27274565

Retrieval Of Cloud Pressure And Chlorophyll Content Using Raman Scattering In GOME Ultraviolet Spectra

NASA Technical Reports Server (NTRS)

Atlas, Robert (Technical Monitor); Joiner, Joanna; Vasikov, Alexander; Flittner, David; Gleason, James; Bhartia, P. K.

2002-01-01

Reliable cloud pressure estimates are needed for accurate retrieval of ozone and other trace gases using satellite-borne backscatter ultraviolet (buv) instruments such as the global ozone monitoring experiment (GOME). Cloud pressure can be derived from buv instruments by utilizing the properties of rotational-Raman scattering (RRS) and absorption by O2-O2. In this paper we estimate cloud pressure from GOME observations in the 355-400 nm spectral range using the concept of a Lambertian-equivalent reflectivity (LER) surface. GOME has full spectral coverage in this range at relatively high spectral resolution with a very high signal-to-noise ratio. This allows for much more accurate estimates of cloud pressure than were possible with its predecessors SBUV and TOMS. We also demonstrate the potential capability to retrieve chlorophyll content with full-spectral buv instruments. We compare our retrieved LER cloud pressure with cloud top pressures derived from the infrared ATSR instrument on the same satellite. The findings confirm results from previous studies that showed retrieved LER cloud pressures from buv observations are systematically higher than IR-derived cloud-top pressure. Simulations using Mie-scattering radiative transfer algorithms that include O2-O2 absorption and RRS show that these differences can be explained by increased photon path length within and below cloud.

Comparison of cloud top heights derived from FY-2 meteorological satellites with heights derived from ground-based millimeter wavelength cloud radar

NASA Astrophysics Data System (ADS)

Wang, Zhe; Wang, Zhenhui; Cao, Xiaozhong; Tao, Fa

2018-01-01

Clouds are currently observed by both ground-based and satellite remote sensing techniques. Each technique has its own strengths and weaknesses depending on the observation method, instrument performance and the methods used for retrieval. It is important to study synergistic cloud measurements to improve the reliability of the observations and to verify the different techniques. The FY-2 geostationary orbiting meteorological satellites continuously observe the sky over China. Their cloud top temperature product can be processed to retrieve the cloud top height (CTH). The ground-based millimeter wavelength cloud radar can acquire information about the vertical structure of clouds-such as the cloud base height (CBH), CTH and the cloud thickness-and can continuously monitor changes in the vertical profiles of clouds. The CTHs were retrieved using both cloud top temperature data from the FY-2 satellites and the cloud radar reflectivity data for the same time period (June 2015 to May 2016) and the resulting datasets were compared in order to evaluate the accuracy of CTH retrievals using FY-2 satellites. The results show that the concordance rate of cloud detection between the two datasets was 78.1%. Higher consistencies were obtained for thicker clouds with larger echo intensity and for more continuous clouds. The average difference in the CTH between the two techniques was 1.46 km. The difference in CTH between low- and mid-level clouds was less than that for high-level clouds. An attenuation threshold of the cloud radar for rainfall was 0.2 mm/min; a rainfall intensity below this threshold had no effect on the CTH. The satellite CTH can be used to compensate for the attenuation error in the cloud radar data.

Detection of hydrogen sulfide above the clouds in Uranus's atmosphere

NASA Astrophysics Data System (ADS)

Irwin, Patrick G. J.; Toledo, Daniel; Garland, Ryan; Teanby, Nicholas A.; Fletcher, Leigh N.; Orton, Glenn A.; Bézard, Bruno

2018-04-01

Visible-to-near-infrared observations indicate that the cloud top of the main cloud deck on Uranus lies at a pressure level of between 1.2 bar and 3 bar. However, its composition has never been unambiguously identified, although it is widely assumed to be composed primarily of either ammonia or hydrogen sulfide (H2S) ice. Here, we present evidence of a clear detection of gaseous H2S above this cloud deck in the wavelength region 1.57-1.59 μm with a mole fraction of 0.4-0.8 ppm at the cloud top. Its detection constrains the deep bulk sulfur/nitrogen abundance to exceed unity (>4.4-5.0 times the solar value) in Uranus's bulk atmosphere, and places a lower limit on the mole fraction of H2S below the observed cloud of (1.0 -2.5 ) ×1 0-5. The detection of gaseous H2S at these pressure levels adds to the weight of evidence that the principal constituent of 1.2-3-bar cloud is likely to be H2S ice.

Detection of hydrogen sulfide above the clouds in Uranus's atmosphere

NASA Astrophysics Data System (ADS)

Irwin, Patrick G. J.; Toledo, Daniel; Garland, Ryan; Teanby, Nicholas A.; Fletcher, Leigh N.; Orton, Glenn A.; Bézard, Bruno

2018-05-01

Visible-to-near-infrared observations indicate that the cloud top of the main cloud deck on Uranus lies at a pressure level of between 1.2 bar and 3 bar. However, its composition has never been unambiguously identified, although it is widely assumed to be composed primarily of either ammonia or hydrogen sulfide (H2S) ice. Here, we present evidence of a clear detection of gaseous H2S above this cloud deck in the wavelength region 1.57-1.59 μm with a mole fraction of 0.4-0.8 ppm at the cloud top. Its detection constrains the deep bulk sulfur/nitrogen abundance to exceed unity (>4.4-5.0 times the solar value) in Uranus's bulk atmosphere, and places a lower limit on the mole fraction of H2S below the observed cloud of (1.0 -2.5 ) ×1 0-5. The detection of gaseous H2S at these pressure levels adds to the weight of evidence that the principal constituent of 1.2-3-bar cloud is likely to be H2S ice.

Sensitivity of liquid clouds to homogenous freezing parameterizations.

PubMed

Herbert, Ross J; Murray, Benjamin J; Dobbie, Steven J; Koop, Thomas

2015-03-16

Water droplets in some clouds can supercool to temperatures where homogeneous ice nucleation becomes the dominant freezing mechanism. In many cloud resolving and mesoscale models, it is assumed that homogeneous ice nucleation in water droplets only occurs below some threshold temperature typically set at -40°C. However, laboratory measurements show that there is a finite rate of nucleation at warmer temperatures. In this study we use a parcel model with detailed microphysics to show that cloud properties can be sensitive to homogeneous ice nucleation as warm as -30°C. Thus, homogeneous ice nucleation may be more important for cloud development, precipitation rates, and key cloud radiative parameters than is often assumed. Furthermore, we show that cloud development is particularly sensitive to the temperature dependence of the nucleation rate. In order to better constrain the parameterization of homogeneous ice nucleation laboratory measurements are needed at both high (>-35°C) and low (<-38°C) temperatures. Homogeneous freezing may be significant as warm as -30°CHomogeneous freezing should not be represented by a threshold approximationThere is a need for an improved parameterization of homogeneous ice nucleation.

Behavior of predicted convective clouds and precipitation in the high-resolution Unified Model over the Indian summer monsoon region

NASA Astrophysics Data System (ADS)

Jayakumar, A.; Sethunadh, Jisesh; Rakhi, R.; Arulalan, T.; Mohandas, Saji; Iyengar, Gopal R.; Rajagopal, E. N.

2017-05-01

National Centre for Medium Range Weather Forecasting high-resolution regional convective-scale Unified Model with latest tropical science settings is used to evaluate vertical structure of cloud and precipitation over two prominent monsoon regions: Western Ghats (WG) and Monsoon Core Zone (MCZ). Model radar reflectivity generated using Cloud Feedback Model Intercomparison Project Observation Simulator Package along with CloudSat profiling radar reflectivity is sampled for an active synoptic situation based on a new method using Budyko's index of turbulence (BT). Regime classification based on BT-precipitation relationship is more predominant during the active monsoon period when convective-scale model's resolution increases from 4 km to 1.5 km. Model predicted precipitation and vertical distribution of hydrometeors are found to be generally in agreement with Global Precipitation Measurement products and BT-based CloudSat observation, respectively. Frequency of occurrence of radar reflectivity from model implies that the low-level clouds below freezing level is underestimated compared to the observations over both regions. In addition, high-level clouds in the model predictions are much lesser over WG than MCZ.

A Herschel-SPIRE Survey of the MonR2 Giant Molecular Cloud

NASA Astrophysics Data System (ADS)

Pokhrel, Riwaj; Gutermuth, Robert; Ali, Babar; Megeath, Thomas; Pipher, Judith; Myers, Philip; Fischer, William; Henning, Thomas; Wolk, Scott; Allen, Lori; Tobin, John

2015-08-01

We present a new survey of the MonR2 giant molecular cloud with SPIRE on the Herschel Space Observatory. We cross-calibrated SPIRE data with Planck-HFI and accounted for its absolute offset and zero point correction. We fixed emissivity with the help of flux-error and flux ratio plots. As the best representation of cold dusty molecular clouds, we did greybody fits of the SEDs. We studied the nature of distribution of column densities above and below certain critical limit, followed by the mass and temperature distributions for different regions. We used dendrograms as a technique to study the hierarchical structures in the GMC.

Short-term variability of gamma radiation at the ARM Eastern North Atlantic facility (Azores).

PubMed

Barbosa, S M; Miranda, P; Azevedo, E B

2017-06-01

This work addresses the short-term variability of gamma radiation measured continuously at the Eastern North Atlantic (ENA) facility located in the Graciosa island (Azores, 39N; 28W), a fixed site of the Atmospheric Radiation Measurement programme (ARM). The temporal variability of gamma radiation is characterized by occasional anomalies over a slowly-varying signal. Sharp peaks lasting typically 2-4 h are coincident with heavy precipitation and result from the scavenging effect of precipitation bringing radon progeny from the upper levels to the ground surface. However the connection between gamma variability and precipitation is not straightforward as a result of the complex interplay of factors such as the precipitation intensity, the PBL height, the cloud's base height and thickness, or the air mass origin and atmospheric concentration of sub-micron aerosols, which influence the scavenging processes and therefore the concentration of radon progeny. Convective precipitation associated with cumuliform clouds forming under conditions of warming of the ground relative to the air does not produce enhancements in gamma radiation, since the drop growing process is dominated by the fast accretion of liquid water, resulting in the reduction of the concentration of radionuclides by dilution. Events of convective precipitation further contribute to a reduction in gamma counts by inhibiting radon release from the soil surface and by attenuating gamma rays from all gamma-emitting elements on the ground. Anomalies occurring in the absence of precipitation are found to be associated with a diurnal cycle of maximum gamma counts before sunrise decreasing to a minimum in the evening, which are observed in conditions of thermal stability and very weak winds enabling the build-up of near surface radon progeny during the night. Copyright © 2017 Elsevier Ltd. All rights reserved.

Seasonality of global and Arctic black carbon processes in the Arctic Monitoring and Assessment Programme models: Global and Arctic Black Carbon Processes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mahmood, Rashed; von Salzen, Knut; Flanner, Mark

2016-06-22

This study quantifies black carbon (BC) processes in three global climate models and one chemistry transport model, with focus on the seasonality of BC transport, emissions, wet and dry deposition in the Arctic. In the models, transport of BC to the Arctic from lower latitudes is the major BC source for this region while Arctic emissions are very small. All models simulated a similar annual cycle of BC transport from lower latitudes to the Arctic, with maximum transport occurring in July. Substantial differences were found in simulated BC burdens and vertical distributions, with CanAM (NorESM) producing the strongest (weakest) seasonalmore » cycle. CanAM also has the shortest annual mean residence time for BC in the Arctic followed by SMHI-MATCH, CESM and NorESM. The relative contribution of wet and dry deposition rates in removing BC varies seasonally and is one of the major factors causing seasonal variations in BC burdens in the Arctic. Overall, considerable differences in wet deposition efficiencies in the models exist and are a leading cause of differences in simulated BC burdens. Results from model sensitivity experiments indicate that scavenging of BC in convective clouds acts to substantially increase the overall efficiency of BC wet deposition in the Arctic, which leads to low BC burdens and a more pronounced seasonal cycle compared to simulations without convective BC scavenging. In contrast, the simulated seasonality of BC concentrations in the upper troposphere is only weakly influenced by wet deposition in stratiform (layer) clouds whereas lower tropospheric concentrations are highly sensitive.« less

Major Characteristics of Southern Ocean Cloud Regimes and Their Effects on the Energy Budget

NASA Technical Reports Server (NTRS)

Haynes, John M.; Jakob, Christian; Rossow, William B.; Tselioudis, George; Brown, Josephine

2011-01-01

Clouds over the Southern Ocean are often poorly represented by climate models, but they make a significant contribution to the top-of-atmosphere (TOA) radiation balance, particularly in the shortwave portion of the energy spectrum. This study seeks to better quantify the organization and structure of Southern Hemisphere midlatitude clouds by combining measurements from active and passive satellite-based datasets. Geostationary and polar-orbiter satellite data from the International Satellite Cloud Climatology Project (ISCCP) are used to quantify large-scale, recurring modes of cloudiness, and active observations from CloudSat and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) are used to examine vertical structure, radiative heating rates, and precipitation associated with these clouds. It is found that cloud systems are organized into eight distinct regimes and that ISCCP overestimates the midlevel cloudiness of these regimes. All regimes contain a relatively high occurrence of low cloud, with 79%of all cloud layers observed having tops below 3 km, but multiple-layered clouds systems are present in approximately 34% of observed cloud profiles. The spatial distribution of regimes varies according to season, with cloud systems being geometrically thicker, on average, during the austral winter. Those regimes found to be most closely associated with midlatitude cyclones produce precipitation the most frequently, although drizzle is extremely common in low-cloud regimes. The regimes associated with cyclones have the highest in-regime shortwave cloud radiative effect at the TOA, but the low-cloud regimes, by virtue of their high frequency of occurrence over the oceans, dominate both TOA and surface shortwave effects in this region as a whole.

Low-cloud characteristics over the tropical western Pacific from ARM observations and CAM5 simulations

DOE PAGES

Chandra, Arunchandra S.; Zhang, Chidong; Klein, Stephen A.; ...

2015-09-10

Here, this study evaluates the ability of the Community Atmospheric Model version 5 (CAM5) to reproduce low clouds observed by the Atmospheric Radiation Measurement (ARM) cloud radar at Manus Island of the tropical western Pacific during the Years of Tropical Convection. Here low clouds are defined as clouds with their tops below the freezing level and bases within the boundary layer. Low-cloud statistics in CAM5 simulations and ARM observations are compared in terms of their general occurrence, mean vertical profiles, fraction of precipitating versus nonprecipitating events, diurnal cycle, and monthly time series. Other types of clouds are included to putmore » the comparison in a broader context. The comparison shows that the model overproduces total clouds and their precipitation fraction but underestimates low clouds in general. The model, however, produces excessive low clouds in a thin layer between 954 and 930 hPa, which coincides with excessive humidity near the top of the mixed layer. This suggests that the erroneously excessive low clouds stem from parameterization of both cloud and turbulence mixing. The model also fails to produce the observed diurnal cycle in low clouds, not exclusively due to the model coarse grid spacing that does not resolve Manus Island. Lastly, this study demonstrates the utility of ARM long-term cloud observations in the tropical western Pacific in verifying low clouds simulated by global climate models, illustrates issues of using ARM observations in model validation, and provides an example of severe model biases in producing observed low clouds in the tropical western Pacific.« less

Antarctica Cloud Cover for October 2003 from GLAS Satellite Lidar Profiling

NASA Technical Reports Server (NTRS)

Spinhirne, J. D.; Palm, S. P.; Hart, W. D.

2005-01-01

Seeing clouds in polar regions has been a problem for the imagers used on satellites. Both clouds and snow and ice are white, which makes clouds over snow hard to see. And for thermal infrared imaging both the surface and the clouds cold. The Geoscience Laser Altimeter System (GLAS) launched in 2003 gives an entirely new way to see clouds from space. Pulses of laser light scatter from clouds giving a signal that is separated in time from the signal from the surface. The scattering from clouds is thus a sensitive and direct measure of the presence and height of clouds. The GLAS instrument orbits over Antarctica 16 times a day. All of the cloud observations for October 2003 were summarized and compared to the results from the MODIS imager for the same month. There are two basic cloud types that are observed, low stratus with tops below 3 km and high cirrus form clouds with cloud top altitude and thickness tending at 12 km and 1.3 km respectively. The average cloud cover varies from over 93 % for ocean and coastal regions to an average of 40% over the East Antarctic plateau and 60-90% over West Antarctica. When the GLAS monthly average cloud fractions are compared to the MODIS cloud fraction data product, differences in the amount of cloud cover are as much as 40% over the continent. The results will be used to improve the way clouds are detected from the imager observations. These measurements give a much improved understanding of distribution of clouds over Antarctica and may show how they are changing as a result of global warming.

Close-up view of 20 March 1976 tornadoes - Sinking cloud tops to suction vortices

NASA Technical Reports Server (NTRS)

Fujita, T. T.; Forbes, G. S.; Umenhofer, T. A.

1976-01-01

The article describes an airborne mission using a Learjet to secure direct data on a family of tornadoes spawned by a rotating thunderstorm in the Missouri-Illinois-Indiana area in March 1976 following an unusually warm February. Weakening of the tornado following increased cloud-scale vertical motion, predicted by a model constructed by Fujita (1972), was confirmed. The aircraft inspected overshooting cloud tops, examined subsidence (holes and depressions) in anvil tops it overflew, and surveyed footprints left by the tornadoes and tornado-blown litter on the ground traversed by the disturbances. Subsidence of cloud tops in advance of violent tornadoes below was confirmed. Isolated and multiple suction vortices left their characteristic ground marks; three scales of motion: tornado cyclone, tornado, and suction vortex, are evidenced by the ground truth.

An upper limit to the abundance of lightning-produced amino acids in the Jovian water clouds

NASA Astrophysics Data System (ADS)

Bar-Nun, A.; Noy, N.; Podolak, M.

1984-08-01

The effect of excess hydrogen on the synthesis of amino acids by high-temperature shock waves in a hydrogen/methane/ammonia/water vapor mixture was studied experimentally. The energy efficiency results, together with the best estimate of the lightning energy dissipation rate on Jupiter from the Voyage data, were used to calculate an upper limit to the rate of amino acid production by lightning in Jovian water clouds. Using reasonable values for the eddy diffusion coefficients within and below the water clouds, the column abundance of lightning-produced amino acids in the clouds was estimated to be 6.2 x 10 to the -6th cm-am. Hence, concentration of amino acids in water droplets would be 8 x 10 to the -8th mole/liter.

ARC-1979-AC79-7081

NASA Image and Video Library

1979-07-08

P-21747 C Range: 2,200,000 miles This image shows a region of the Jovian atmosphere from approximately 25° N to the equatorial region. The north temperate jet, at approximately 23° N, where the wind speed is about 150 meters per second, is seen as a dark brown line from the left-hand edge to the right-hand corner of the picture. The wispy clouds of the north equatorial belt appear as shades of brown. The lower right-hand corner of the image shows the brighter (white) clouds of the equatorial region. A small blue area is apparent near the lower edge, which corresponds to a region free of the upper clouds, where it is possible to penetrate to cloud layers approximately 60 kilometers below the visible surface.

ARC-1979-A79-7081

NASA Image and Video Library

1979-07-08

P-21747 BW Range: 2,200,000 miles This image shows a region of the Jovian atmosphere from approximately 25° N to the equatorial region. The north temperate jet, at approximately 23° N, where the wind speed is about 150 meters per second, is seen as a dark brown line from the left-hand edge to the right-hand corner of the picture. The wispy clouds of the north equatorial belt appear as shades of brown. The lower right-hand corner of the image shows the brighter (white) clouds of the equatorial region. A small blue area is apparent near the lower edge, which corresponds to a region free of the upper clouds, where it is possible to penetrate to cloud layers approximately 60 kilometers below the visible surface.

Aerosol concentration and size distribution measured below, in, and above cloud from the DOE G-1 during VOCALS-REx

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kleinman L. I.; Daum, P. H.; Lee, Y.-N.

2012-01-04

During the VOCALS Regional Experiment, the DOE G-1 aircraft was used to sample a varying aerosol environment pertinent to properties of stratocumulus clouds over a longitude band extending 800 km west from the Chilean coast at Arica. Trace gas and aerosol measurements are presented as a function of longitude, altitude, and dew point in this study. Spatial distributions are consistent with an upper atmospheric source for O{sub 3} and South American coastal sources for marine boundary layer (MBL) CO and aerosol, most of which is acidic sulfate. Pollutant layers in the free troposphere (FT) can be a result of emissionsmore » to the north in Peru or long range transport from the west. At a given altitude in the FT (up to 3 km), dew point varies by 40 C with dry air descending from the upper atmospheric and moist air having a boundary layer (BL) contribution. Ascent of BL air to a cold high altitude results in the condensation and precipitation removal of all but a few percent of BL water along with aerosol that served as CCN. Thus, aerosol volume decreases with dew point in the FT. Aerosol size spectra have a bimodal structure in the MBL and an intermediate diameter unimodal distribution in the FT. Comparing cloud droplet number concentration (CDNC) and pre-cloud aerosol (D{sub p} > 100 nm) gives a linear relation up to a number concentration of {approx}150 cm{sup -3}, followed by a less than proportional increase in CDNC at higher aerosol number concentration. A number balance between below cloud aerosol and cloud droplets indicates that {approx}25 % of aerosol with D{sub p} > 100 nm are interstitial (not activated). A direct comparison of pre-cloud and in-cloud aerosol yields a higher estimate. Artifacts in the measurement of interstitial aerosol due to droplet shatter and evaporation are discussed. Within each of 102 constant altitude cloud transects, CDNC and interstitial aerosol were anti-correlated. An examination of one cloud as a case study shows that the interstitial aerosol appears to have a background, upon which is superimposed a high frequency signal that contains the anti-correlation. The anti-correlation is a possible source of information on particle activation or evaporation.« less

Aerosol concentration and size distribution measured below, in, and above cloud from the DOE G-1 during VOCALS-REx

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kleinman, L.I.; Daum, P. H.; Lee, Y.-N.

2011-06-21

During the VOCALS Regional Experiment, the DOE G-1 aircraft was used to sample a varying aerosol environment pertinent to properties of stratocumulus clouds over a longitude band extending 800 km west from the Chilean coast at Arica. Trace gas and aerosol measurements are presented as a function of longitude, altitude, and dew point in this study. Spatial distributions are consistent with an upper atmospheric source for O{sub 3} and South American coastal sources for marine boundary layer (MBL) CO and aerosol, most of which is acidic sulfate in agreement with the dominant pollution source being SO{sub 2} from Cu smeltersmore » and power plants. Pollutant layers in the free troposphere (FT) can be a result of emissions to the north in Peru or long range transport from the west. At a given altitude in the FT (up to 3 km), dew point varies by 40 C with dry air descending from the upper atmospheric and moist air having a BL contribution. Ascent of BL air to a cold high altitude results in the condensation and precipitation removal of all but a few percent of BL water along with aerosol that served as CCN. Thus, aerosol volume decreases with dew point in the FT. Aerosol size spectra have a bimodal structure in the MBL and an intermediate diameter unimodal distribution in the FT. Comparing cloud droplet number concentration (CDNC) and pre-cloud aerosol (Dp > 100 nm) gives a linear relation up to a number concentration of {approx}150 cm{sup -3}, followed by a less than proportional increase in CDNC at higher aerosol number concentration. A number balance between below cloud aerosol and cloud droplets indicates that {approx}25% of aerosol in the PCASP size range are interstitial (not activated). One hundred and two constant altitude cloud transects were identified and used to determine properties of interstitial aerosol. One transect is examined in detail as a case study. Approximately 25 to 50% of aerosol with D{sub p} > 110 nm were not activated, the difference between the two approaches possibly representing shattered cloud droplets or unknown artifact. CDNC and interstitial aerosol were anti-correlated in all cloud transects, consistent with the occurrence of dry in-cloud areas due to entrainment or circulation mixing.« less

Green Bank Telescope Detection of HI Clouds in the Fermi Bubble Wind

NASA Astrophysics Data System (ADS)

Lockman, Felix; Di Teodoro, Enrico M.; McClure-Griffiths, Naomi M.

2018-01-01

We used the Robert C. Byrd Green Bank Telescope to map HI 21cm emission in two large regions around the Galactic Center in a search for HI clouds that might be entrained in the nuclear wind that created the Fermi bubbles. In a ~160 square degree region at |b|>4 deg. and |long|<10 deg we detect 106 HI clouds that have large non-circular velocities consistent with their acceleration by the nuclear wind. Rapidly moving clouds are found as far as 1.5 kpc from the center; there are no detectable asymmetries in the cloud populations above and below the Galactic Center. The cloud kinematics is modeled as a population with an outflow velocity of 330 km/s that fills a cone with an opening angle ~140 degrees. The total mass in the clouds is ~10^6 solar masses and we estimate cloud lifetimes to be between 2 and 8 Myr, implying a cold gas mass-loss rate of about 0.1 solar masses per year into the nuclear wind.The Green Bank Telescope is a facility of the National Science Foundation, operated under a cooperative agreement by Associated Universities, Inc.

The evaporatively driven cloud-top mixing layer

NASA Astrophysics Data System (ADS)

Mellado, Juan Pedro

2010-11-01

Turbulent mixing caused by the local evaporative cooling at the top cloud-boundary of stratocumuli will be discussed. This research is motivated by the lack of a complete understanding of several phenomena in that important region, which translates into an unacceptable variability of order one in current models, including those employed in climate research. The cloud-top mixing layer is a simplified surrogate to investigate, locally, particular aspects of the fluid dynamics at the boundary between the stratocumulus clouds and the upper cloud-free air. In this work, direct numerical simulations have been used to study latent heat effects. The problem is the following: When the cloud mixes with the upper cloud-free layer, relatively warm and dry, evaporation tends to cool the mixture and, if strong enough, the buoyancy reversal instability develops. This instability leads to a turbulent convection layer growing next to the upper boundary of the cloud, which is, in several aspects, similar to free convection below a cold horizontal surface. In particular, results show an approximately self-preserving behavior that is characterized by the molecular buoyancy flux at the inversion base, fact that helps to explain the difficulties found when doing large-eddy simulations of this problem using classical subgrid closures.

Polarized View of Supercooled Liquid Water Clouds

NASA Technical Reports Server (NTRS)

Alexandrov, Mikhail D.; Cairns, Brian; Van Diedenhoven, Bastiaan; Ackerman, Andrew S.; Wasilewski, Andrzej P.; McGill, Matthew J.; Yorks, John E.; Hlavka, Dennis L.; Platnick, Steven E.; Arnold, G. Thomas

2016-01-01

Supercooled liquid water (SLW) clouds, where liquid droplets exist at temperatures below 0 C present a well known aviation hazard through aircraft icing, in which SLW accretes on the airframe. SLW clouds are common over the Southern Ocean, and climate-induced changes in their occurrence is thought to constitute a strong cloud feedback on global climate. The two recent NASA field campaigns POlarimeter Definition EXperiment (PODEX, based in Palmdale, California, January-February 2013) and Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS, based in Houston, Texas in August- September 2013) provided a unique opportunity to observe SLW clouds from the high-altitude airborne platform of NASA's ER-2 aircraft. We present an analysis of measurements made by the Research Scanning Polarimeter (RSP) during these experiments accompanied by correlative retrievals from other sensors. The RSP measures both polarized and total reflectance in 9 spectral channels with wavelengths ranging from 410 to 2250 nm. It is a scanning sensor taking samples at 0.8deg intervals within 60deg from nadir in both forward and backward directions. This unique angular resolution allows for characterization of liquid water droplet size using the rainbow structure observed in the polarized reflectances in the scattering angle range between 135deg and 165deg. Simple parametric fitting algorithms applied to the polarized reflectance provide retrievals of the droplet effective radius and variance assuming a prescribed size distribution shape (gamma distribution). In addition to this, we use a non-parametric method, Rainbow Fourier Transform (RFT),which allows retrieval of the droplet size distribution without assuming a size distribution shape. We present an overview of the RSP campaign datasets available from the NASA GISS website, as well as two detailed examples of the retrievals. In these case studies we focus on cloud fields with spatial features varying between glaciated and liquid phases at altitudes as high as 10 km, which correspond to temperatures close to the homogeneous freezing temperature of pure water drops (about -35 C or colder). The multimodal droplet size distributions retrieved from RSP data in these cases are consistent with the multi-layer cloud structure observed by correlative Cloud Physics Lidar (CPL) measurements.

A Numerical Study of Convection in a Condensing CO2 Atmosphere under Early Mars-Like Conditions

NASA Astrophysics Data System (ADS)

Nakajima, Kensuke; Yamashita, Tatsuya; Odaka, Masatsugu; Sugiyama, Ko-ichiro; Ishiwatari, Masaki; Nishizawa, Seiya; Takahashi, Yoshiyuki O.; Hayashi, Yoshi-Yuki

2017-10-01

Cloud convection of a CO2 atmosphere where the major constituent condenses is numerically investigated under a setup idealizing a possible warm atmosphere of early Mars, utilizing a two-dimensional cloud-resolving model forced by a fixed cooling profile as a substitute for a radiative process. The authors compare two cases with different critical saturation ratios as condensation criteria and also examine sensitivity to number mixing ratio of condensed particles given externally.When supersaturation is not necessary for condensation, the entire horizontal domain above the condensation level is continuously covered by clouds irrespective of number mixing ratio of condensed particles. Horizontal-mean cloud mass density decreases exponentially with height. The circulations below and above the condensation level are dominated by dry cellular convection and buoyancy waves, respectively.When 1.35 is adopted as the critical saturation ratio, clouds appear exclusively as intense, short-lived, quasi-periodic events. Clouds start just above the condensation level and develop upward, but intense updrafts exist only around the cloud top; they do not extend to the bottom of the condensation layer. The cloud layer is rapidly warmed by latent heat during the cloud events, and then the layer is slowly cooled by the specified thermal forcing, and supersaturation gradually develops leading to the next cloud event. The periodic appearance of cloud events does not occur when number mixing ratio of condensed particles is large.

A cloud model simulation of space shuttle exhaust clouds in different atmospheric conditions

NASA Technical Reports Server (NTRS)

Chen, C.; Zak, J. A.

1989-01-01

A three-dimensional cloud model was used to characterize the dominant influence of the environment on the Space Shuttle exhaust cloud. The model was modified to accept the actual heat and moisture from rocket exhausts and deluge water as initial conditions. An upper-air sounding determined the ambient atmosphere in which the cloud could grow. The model was validated by comparing simulated clouds with observed clouds from four actual Shuttle launches. The model successfully produced clouds with dimensions, rise, decay, liquid water contents and vertical motion fields very similar to observed clouds whose dimensions were calculated from 16 mm film frames. Once validated, the model was used in a number of different atmospheric conditions ranging from very unstable to very stable. In moist, unstable atmospheres simulated clouds rose to about 3.5 km in the first 4 to 8 minutes then decayed. Liquid water contents ranged from 0.3 to 1.0 g kg-1 mixing ratios and vertical motions were from 2 to 10 ms-1. An inversion served both to reduce entrainment (and erosion) at the top and to prevent continued cloud rise. Even in the most unstable atmospheres, the ground cloud did not rise beyond 4 km and in stable atmospheres with strong low level inversions the cloud could be trapped below 500 m. Wind shear strongly affected the appearance of both the ground cloud and vertical column cloud. The ambient low-level atmospheric moisture governed the amount of cloud water in model clouds. Some dry atmospheres produced little or no cloud water. One case of a simulated TITAN rocket explosion is also discussed.

Electric jets following the occurrence of sprites

NASA Astrophysics Data System (ADS)

Lee, L.; Chou, J.; Huang, S.; Chang, S.; Wu, Y.; Lee, Y.; Kuo, C.; Chen, A. B.; Su, H.; Hsu, R.; Frey, H. U.; Mende, S. B.; Takahashi, Y.; Lee, L.

2010-12-01

Sprites are discharges occurring at the altitudes ~40 to 90 km, which are usually associated with positive cloud-to-ground lightning (+CGs). Electric jets, which include blue jets (BJs) with the terminal altitude of ~40km and gigantic jets (GJs) emanating to the lower ionosphere, are upward discharges from the cloud tops toward the upper atmosphere. From previous ground observations, it has been reported that the secondary discharges (“palm-tree” [Heavner, 2000] or “sprite-initiated secondary TLEs” [Marshall and Inan, 2007]) following sprites occurred in altitudes between the cloud top and the bottom of the sprite. From July 2004 to June 2010, ISUAL has recorded dozens of events which resemble the secondary TLEs. From image and photometric data recorded by ISUAL, all these secondary TLEs have the characteristics of jets, so we call these events “secondary jets”. These secondary jets are categorized into two groups according to their emanating horizontal positions in relative to the sprites. Group-I secondary jets occurred in the cloud top region which is directly below the sprites. The terminal altitude is ~ 40-50km for most of group-I secondary jets. Several group-I secondary jets appear to originate from the cloud top region below the symmetric center of the clustering sprites and then propagate toward the lower ionosphere. While the group-II secondary jets originate from region outside the shielding area of the clustering sprites. In this paper, the image and the photometric characteristics of the secondary jets will be presented and the possible generating mechanisms will be discussed.

A review of observations of organic matter in fogs and clouds: Origin, processing and fate

NASA Astrophysics Data System (ADS)

Herckes, Pierre; Valsaraj, Kalliat T.; Collett, Jeffrey L.

2013-10-01

While fog and cloud composition has been studied for decades, most of the research was limited to inorganic species and fog acidity. Recently the focus has shifted towards organic matter in the atmospheric aqueous phase of fogs and clouds: its origin, reactivity and fate. An impressive number of fog and cloud chemistry observational studies have been performed over the last decade throughout the world. In the present work we will review the state of knowledge of atmospheric organic matter processing by fogs, with a focus on field observations. We start by reviewing observational studies in general and then discuss our knowledge on the occurrence of organic matter in fogs, its solubility, characterization and molecular speciation. Organic carbon concentrations can vary widely from approximately 1 mg C/L in remote marine environments to more than 100 mg C/L in polluted radiation fogs, accounting for a substantial part of fogwater solutes. The carbonaceous material can enter the droplets from the gas and particle phase and the scavenging behavior of fogs will be detailed. Observational studies showed evidence of aqueous phase transformation of organic material, in particular secondary organic aerosol (SOA) generation, in fog. Recent observations of biological material in fog suggest also an impact of biological processing within the droplets on fog organic matter. The review will end with a discussion of the impact of fog on the deposition fluxes of organic material and hence its atmospheric lifetime.

multi-dimensional Cloud-aERosol Exploratory Study using RPAS (mCERES): Bottom-up and top-down closure of aerosol-cloud interactions

NASA Astrophysics Data System (ADS)

Roberts, Greg; Calmer, Radiance; Sanchez, Kevin; Cayez, Grégoire; Nicoll, Kerianne; Hashimshoni, Eyal; Rosenfeld, Daniel; Ansmann, Albert; Sciare, Jean; Ovadneite, Jurgita; Bronz, Murat; Hattenberger, Gautier; Preissler, Jana; Buehl, Johannes; Ceburnis, Darius; O'Dowd, Colin

2016-04-01

Clouds are omnipresent in earth's atmosphere and constitute an important role in regulating the radiative budget of the planet. However, the response of clouds to climate change remains uncertain, in particular, with respect to aerosol-cloud interactions and feedback mechanisms between the biosphere and atmosphere. Aerosol-cloud interactions and their feedbacks are the main themes of the European project FP7 BACCHUS (Impact of Biogenic versus Anthropogenic Emissions on Clouds and Climate: towards a Holistic Understanding). The National Center for Meteorological Research (CNRM-GAME, Toulouse, France) conducted airborne experiments in Cyprus and Ireland in March and August 2015 respectively to link ground-based and satellite observations. Multiple RPAS (remotely piloted aircraft systems) were instrumented for a specific scientific focus to characterize the vertical distribution of aerosol, cloud microphysical properties, radiative fluxes, 3D wind vectors and meteorological state parameters. Flights below and within clouds were coordinated with satellite overpasses to perform 'top-down' closure of cloud micro-physical properties. Measurements of cloud condensation nuclei spectra at the ground-based site have been used to determine cloud microphyical properties using wind vectors and meteorological parameters measured by the RPAS at cloud base. These derived cloud properties have been validated by in-situ RPAS measurements in the cloud and compared to those derived by the Suomi-NPP satellite. In addition, RPAS profiles in Cyprus observed the layers of dust originating from the Arabian Peninsula and the Sahara Desert. These profiles generally show a well-mixed boundary layer and compare well with ground-based LIDAR observations.

Phytochemical profile and free radical nitric oxide (NO) scavenging activity of Averrhoa bilimbi L. fruit extract.

PubMed

Suluvoy, Jagadish Kumar; Berlin Grace, V M

2017-05-01

Averrhoa bilimbi L. belongs to family Oxalidaceae. Traditionally, people use this plant (root, bark, leaves and fruits) for treating several illnesses include itches, boils, syphilis, whooping cough, hypertension, fever and inflammation. The aim of the study was to evaluate the nitric oxide (NO) scavenging activity and GC-MS analysis of A. bilimbi L. fruit extract. Averrhoa bilimbi L. fruits were collected for the preliminary phytochemical analysis, antioxidant scavenging activity and biologically important compounds were identified by GC-MS analysis. The preliminary phytochemicals, GC-MS, total phenolic content and NO scavenging activity of the plant were analysed. In the present investigation, the A. bilimbi L. fruit extract has major phytochemicals. Among the 151 compounds identified in GC-MS, 15 compounds are found to have diverse biological activity. We also observed that the A. bilimbi L. fruit extract has high level of total phenolic compounds at a concentration of 209.25 GAE mg/g. Presence of phenolic compound apparently explains the antioxidant activity of the plant. Antioxidant activity of A. bilimbi L. fruit extract is proven from its high level of NO scavenging activity of potent IC50 value of 108.10. From the above study, it is apparent that the A. bilimbi L. fruit extract is a rich source of phytochemicals (natural products) with biological activity. The GC-MS report on this fruit proves that natural products have pharmacologically and biologically active compounds. A high phenolic content is observed in our study. A. bilimbi L. fruit extract is also found to have NO scavenging activity in our study.

A Review of Spatial and Seasonal Changes in Condensation Clouds Observed During Aerobraking by MGS TES

NASA Technical Reports Server (NTRS)

Pearl, J. C.; Smith, M. D.; Conrath, B. J.; Bandfield, J. L.; Christensen, P. R.

1999-01-01

Successful operation of the Mars Global Surveyor spacecraft, beginning in September 1997, has permitted extensive infrared observations of condensation clouds during the martian southern summer and fall seasons (184 deg less than L(sub s) less than 28 deg). Initially, thin (normal optical depth less than 0.06 at 825/ cm) ice clouds and hazes were widespread, showing a latitudinal gradient. With the onset of a regional dust storm at L(sub s) = 224 deg, ice clouds essentially vanished in the southern hemisphere, to reappear gradually after the decay of the storm. The thickest clouds (optical depth approx. 0.6) were associated with major volcanic features. At L(exp s) = 318 deg, the cloud at Ascraeus Mons was observed to disappear between 21:30 and 09:30, consistent with historically recorded diurnal behavior for clouds of this type. Limb observations showed extended optically thin (depth less than 0.04) stratiform clouds at altitudes up to 55 km. A water ice haze was present in the north polar night at altitudes up to 40 km; this probably provided heterogeneous nucleation sites for the formation of CO2 clouds at altitudes below the 1 mbar pressure level, where atmospheric temperatures dropped to the condensation point of CO2.

Using sky radiances measured by ground based AERONET Sun-Radiometers for cirrus cloud detection

NASA Astrophysics Data System (ADS)

Sinyuk, A.; Holben, B. N.; Eck, T. F.; Slutsker, I.; Lewis, J. R.

2013-12-01

Screening of cirrus clouds using observations of optical depth (OD) only has proven to be a difficult task due mostly to some clouds having temporally and spatially stable OD. On the other hand, the sky radiances measurements which in AERONET protocol are taken throughout the day may contain additional cloud information. In this work the potential of using sky radiances for cirrus cloud detection is investigated. The detection is based on differences in the angular shape of sky radiances due to cirrus clouds and aerosol (see Figure). The range of scattering angles from 3 to 6 degrees was selected due to two primary reasons: high sensitivity to cirrus clouds presence, and close proximity to the Sun. The angular shape of sky radiances was parametrized by its curvature, which is a parameter defined as a combination of the first and second derivatives as a function of scattering angle. We demonstrate that a slope of the logarithm of curvature versus logarithm of scattering angle in this selected range of scattering angles is sensitive to cirrus cloud presence. We also demonstrate that restricting the values of the slope below some threshold value can be used for cirrus cloud screening. The threshold value of the slope was estimated using collocated measurements of AERONET data and MPLNET lidars.

Case Study Analyses of the SUCCESS DC-8 Scanning Lidar Database

NASA Technical Reports Server (NTRS)

Uthe, Edward E.

2000-01-01

Under project SUCCESS (Subsonic Aircraft Contrail and Cloud Effects Special Study) funded by the Atmospheric Effects of Aviation Program, SRI International (SRI) developed an angular scanning backscatter lidar for operation on the NASA DC-8 research aircraft and deployed the scanning lidar during the SUCCESS field campaign. The primary purpose of the lidar was to generate real-time video displays of clouds and contrails above, ahead of, and below the DC-8 as a means to help position the aircraft for optimum cloud and contrail sampling by onboard in situ sensors, and to help extend the geometrical domain of the in situ sampling records. A large, relatively complex lidar database was collected and several data examples were processed to illustrate the value of the lidar data for interpreting the other data records collected during SUCCESS. These data examples were used to develop a journal publication for the special SUCCESS Geophysical Research Letters issue. The data examples justified data analyses of a larger part of the DC-8 lidar database and is the objective of the current study. Efficient processing of the SUCCESS DC-8 scanning lidar database required substantial effort to enhance hardware and software components of the data system that was used for the initial analyses. MATLAB instructions are used to generate altitude and distance color-coded lidar displays corrected for effects introduced by aircraft pitch and forward movement during an angular scan time interval. Onboard in situ sensor atmospheric measurements are propagated to distances ahead of the DC-8 using recorded aircraft velocity so that they can be plotted on the lidar displays for comparison with lidar remotely observed aerosol distributions. Resulting lidar and in situ sensor polar scan displays over extended sampling intervals are integrated into a time series movie format for 36 case studies. Contrails and clouds were detected to ranges of 15 km by the forward-viewing angular scanning lidar and were progressively mapped as the aircraft approached and penetrated them. Near aircraft lidar observations were much better correlated with in situ sensor observations than lidar observations at greater distances ahead of the aircraft. The major cause of this difference was thought to be the about 2 deg. offset of the lidar viewing direction from the flight direction. Contrail spatial distributions were not of the quality obtainable from ground-based lidar observations. This results because contrails tend to become horizontally stratified, vertical distance between angular lidar observations increases with increased distance from the aircraft, and erratic aircraft motions during an angular scan. The most useful lidar observations were made with lidar viewing directions of vertically upward or vertically downward. These provided real-time information on aircraft altitudes to achieve optimum in situ cloud and contrail sampling. At sampling altitudes, the forward viewing angular scanning observations were useful for fine-tuning the aircraft altitude for cloud and contrail penetration. Best information on cloud and contrail properties were obtained from vertically directed lidar observations as the aircraft performed a series of upward and downward penetrations of contrails. This operational mode was especially well suited for lidar and radiometric evaluation of cloud and contrail optical and radiative properties. The vertical viewing lidar detected ice crystals thought to be precipitating from an aircraft contrail and their scavenging by a cirrus cloud layer. The lidar display indicates that the crystals are effective for increasing cirrus cloud density. Vertical angular scanning observations can evaluate the sharp decrease in lidar backscatter for small off-vertical viewing directions that result from horizontally aligned ice crystals and perhaps can provide additional information on crystal shapes. The about 2 deg. offset of the lidar viewing direction from the flight direction is thought to have greatly degraded the forward-viewing angular scanning observations and this mode of operation was not fully evaluated. However, the reasoning for this capability remains valid and the angular scan presentations collected during this program justifies modification of the lidar pod for true forward direction lidar viewing during future cloud and contrail studies.

RTE: A UNIX library with on-line documentation and sample programs for microwave radiative transfer calculations

NASA Astrophysics Data System (ADS)

Reynolds, J. C.; Schroeder, J. A.

1993-03-01

The FORTRAN library that the NOAA Wave Propagation Laboratory (WPL) developed to perform radiative transfer calculations for an upward-looking microwave radiometer is described. Although the theory and algorithms have been used for many years in WPL radiometer research, the Radiative Transfer Equation (RTE) software has combined them into a toolbox that is portable, readable, application independent, and easy to update. RTE has been optimized for the UNIX environment. However, the FORTRAN source code can be compiled on any platform that provides a Standard FORTRAN 77 compiler. RTE allows a user to do cloud modeling, calibrate radiometers, simulate hypothetical radiometer systems, develop retrieval techniques, and compute weighting functions. The radiative transfer model used is valid for channel frequencies below 1000 GHz in clear conditions and for frequencies below 100 GHz when clouds are present.

Forecasting the northern African dust outbreak towards Europe in April 2011: A model intercomparison

DOE PAGES

Huneeus, N.; Basart, S.; Fiedler, S.; ...

2016-04-21

In the framework of the World Meteorological Organisation's Sand and Dust Storm Warning Advisory and Assessment System, we evaluated the predictions of five state-of-the-art dust forecast models during an intense Saharan dust outbreak affecting western and northern Europe in April 2011. We assessed the capacity of the models to predict the evolution of the dust cloud with lead times of up to 72 h using observations of aerosol optical depth (AOD) from the AErosol RObotic NETwork (AERONET) and the Moderate Resolution Imaging Spectroradiometer (MODIS) and dust surface concentrations from a ground-based measurement network. In addition, the predicted vertical dust distributionmore » was evaluated with vertical extinction profiles from the Cloud and Aerosol Lidar with Orthogonal Polarization (CALIOP). To assess the diversity in forecast capability among the models, the analysis was extended to wind field (both surface and profile), synoptic conditions, emissions and deposition fluxes. Models predict the onset and evolution of the AOD for all analysed lead times. On average, differences among the models are larger than differences among lead times for each individual model. In spite of large differences in emission and deposition, the models present comparable skill for AOD. In general, models are better in predicting AOD than near-surface dust concentration over the Iberian Peninsula. Models tend to underestimate the long-range transport towards northern Europe. In this paper, our analysis suggests that this is partly due to difficulties in simulating the vertical distribution dust and horizontal wind. Differences in the size distribution and wet scavenging efficiency may also account for model diversity in long-range transport.« less

Biological aerosol particles in the atmosphere and their impact on clouds (BIOCLOUDS)

NASA Astrophysics Data System (ADS)

Amato, Pierre; Attard, Eleonore; Deguillaume, Laurent; Delort, Anne-Marie; Flossmann, Andrea; Good, Nicholas; Joly, Muriel; Koop, Thomas; Möhler, Ottmar; Monier, Marie; Morris, Cindy; Oehm, Caroline; Pöschl, Ulrich; Sancelme, Martine

2015-04-01

The project BIOCLOUDS aimed at investigating and quantifying the role of bioaerosols in tropospheric clouds. We focused on the studies on microorganisms, mainly bacteria. To reach our objective we (1) isolated and identified INA bacterial strains in cloud waters, (2) studied in more details IN properties of bacteria isolated from cloud waters in laboratories and cloud chamber, (3) used new data as input to cloud models. 1. Isolation and Identification of INA bacterial strains in cloud waters Cloud water samples were collected at the puy de Dôme station under sterile conditions, microorganisms were cultured on agar plates and further identified by DNA sequencing coding for16SrRNA. 257 bacterial strains isolated from 25 cloud events were screened and 44 isolates were selected as they belonged to Pseudomonas, Xanthomonas and Erwinia genera which are potential INA candidates. Using the classical "Droplet Freezing method" as ice nucleation test, 7 strains were shown INA+. Their cumulative IN frequency profiles were established and showed that some of them are very efficient, for example the strain Pseudomonas syringae 13b74 started to nucleate a t-3°C and 4% of the cells were active at- 5°C. 2. Further laboratory investigations of IN properties of cloud bacterial strains All the experiments presented in this section were carried out with 3 Pseudomonas syringae strains. We tested the influence of O3, NO, UV and pH, which are atmospheric markers of anthropogenic activity, on the IN activity of the Pseudomonas strains. It was clearly shown that pH had a main influence, acidic pHs decreased the IN activity of the strains. This suggests a negative impact of human emissions on the natural capacity of bacteria to precipitate with rain. The 3 Pseudomas strains were sprayed in the AIDA cloud chamber. The survival of these strains with time before cloud formation was measured and will be used in the future to parameterize models for bacterial transport. After cloud formation, IN activity of bacteria was followed with time, our results suggest that bacteria are precipitated in the cloud chamber as a result of their IN activity. Also the coating of bacteria with sulfates decreased their IN activity, pointing out the negative potential anthropogenic influence on IN bacteria activity. 3. Modeling study to see if any impact of bacteria on cloud development and/or precipitation is realistic. Modeling studies were performed with DESCAM (Detailed SCAvenging Model) using as an input the new data from the different campaigns in AIDA. M. VAÏTILINGOM et al. Atmospheric Environment, 2012, 56, 88-100. E. ATTARD et al. Atmospheric Chemistry and Physics, 2012, 12, 10667-10677. M. JOLY et al. Atmospheric Environment, 2013, 70, 392-400.

Detection of water vapor on Jupiter

NASA Technical Reports Server (NTRS)

Larson, H. P.; Fink, U.; Treffers, R.; Gautier, T. N., III

1975-01-01

High-altitude (12.4 km) spectroscopic observations of Jupiter at 5 microns from the NASA 91.5 cm airborne infrared telescope have revealed 14 absorptions assigned to the rotation-vibration spectrum of water vapor. Preliminary analysis indicates a mixing ratio about 1 millionth for the vapor phase of water. Estimates of temperature (greater than about 300 K) and pressure (less than 20 atm) suggest observation of water deep in Jupiter's hot spots responsible for its 5 micron flux. Model-atmosphere calculations based on radiative-transfer theory may change these initial estimates and provide a better physical picture of Jupiter's atmosphere below the visible cloud tops.

Image Analysis Based Estimates of Regolith Erosion Due to Plume Impingement Effects

NASA Technical Reports Server (NTRS)

Lane, John E.; Metzger, Philip T.

2014-01-01

Characterizing dust plumes on the moon's surface during a rocket landing is imperative to the success of future operations on the moon or any other celestial body with a dusty or soil surface (including cold surfaces covered by frozen gas ice crystals, such as the moons of the outer planets). The most practical method of characterizing the dust clouds is to analyze video or still camera images of the dust illuminated by the sun or on-board light sources (such as lasers). The method described below was used to characterize the dust plumes from the Apollo 12 landing.

Role of Free Radicals/Reactive Oxygen Species in MeHg Photodegradation: Importance of Utilizing Appropriate Scavengers.

PubMed

Han, Xiaoxiao; Li, Yanbin; Li, Dan; Liu, Chang

2017-04-04

A variety of free radicals (FR)/reactive oxygen species (ROS) have been proposed to dominate methylmercury (MeHg) photodegradation, primarily based on the results of FR/ROS scavenger addition experiments. However, in addition to eliminating FR/ROS, the added scavengers may also affect the experimental results by altering some water chemical properties, resulting in a misleading assessment of the importance of FR/ROS. In this study, 20 common FR/ROS scavengers were evaluated in terms of their influence on light absorbance, pH, MeHg analysis, MeHg-dissolved organic matter (DOM) complexation, and the scavenger-induced degradation of MeHg. Only nine scavengers were identified to be appropriate for investigating MeHg photodegradation. By utilizing these appropriate scavengers, direct photodegradation of MeHg-DOM complexes was found to be the major pathway of MeHg photodegradation in Laoshan Reservoir water and Stone Old Beach seawater. In contrast, MeHg photodegradation in Ink River water primarily occurs through both ·OH and 3 DOM* mediated indirect pathways and direct photodegradation of MeHg-DOM complexes. The diverse pathways of MeHg photodegradation in the tested water may be due to differences in water chemical properties. A severe overestimation of the role of FR/ROS was observed when several improper but commonly used scavengers were adopted, highlighting the necessity of utilizing appropriate scavengers.

Extraction of Profile Information from Cloud Contaminated Radiances. Appendixes 2

NASA Technical Reports Server (NTRS)

Smith, W. L.; Zhou, D. K.; Huang, H.-L.; Li, Jun; Liu, X.; Larar, A. M.

2003-01-01

Clouds act to reduce the signal level and may produce noise dependence on the complexity of the cloud properties and the manner in which they are treated in the profile retrieval process. There are essentially three ways to extract profile information from cloud contaminated radiances: (1) cloud-clearing using spatially adjacent cloud contaminated radiance measurements, (2) retrieval based upon the assumption of opaque cloud conditions, and (3) retrieval or radiance assimilation using a physically correct cloud radiative transfer model which accounts for the absorption and scattering of the radiance observed. Cloud clearing extracts the radiance arising from the clear air portion of partly clouded fields of view permitting soundings to the surface or the assimilation of radiances as in the clear field of view case. However, the accuracy of the clear air radiance signal depends upon the cloud height and optical property uniformity across the two fields of view used in the cloud clearing process. The assumption of opaque clouds within the field of view permits relatively accurate profiles to be retrieved down to near cloud top levels, the accuracy near the cloud top level being dependent upon the actual microphysical properties of the cloud. The use of a physically correct cloud radiative transfer model enables accurate retrievals down to cloud top levels and below semi-transparent cloud layers (e.g., cirrus). It should also be possible to assimilate cloudy radiances directly into the model given a physically correct cloud radiative transfer model using geometric and microphysical cloud parameters retrieved from the radiance spectra as initial cloud variables in the radiance assimilation process. This presentation reviews the above three ways to extract profile information from cloud contaminated radiances. NPOESS Airborne Sounder Testbed-Interferometer radiance spectra and Aqua satellite AIRS radiance spectra are used to illustrate how cloudy radiances can be used in the profile retrieval process.

Synthesis and Free Radical Scavenging Activity of New Hydroxybenzylidene Hydrazines.

PubMed

Sersen, Frantisek; Gregan, Fridrich; Kotora, Peter; Kmetova, Jarmila; Filo, Juraj; Loos, Dusan; Gregan, Juraj

2017-05-29

Hydroxybenzylidene hydrazines exhibit a wide spectrum of biological activities. Here, we report synthesis and free radical scavenging activity of nine new N-(hydroxybenzylidene)-N'-[2,6-dinitro-4-(trifluoromethyl)]phenylhydrazines. The chemical structures of these compounds were confirmed by 1H-NMR, 13C-NMR, 19F-NMR, IR spectroscopy, LC-MS, and elemental analysis. The prepared compounds were tested for their activity to scavenge 2,2-diphenyl-1-picrylhydrazyl (DPPH), galvinoxyl radical (GOR), and 2,2'-azino-bis(3-ethylbenzothiazoline)-6-sulphonic acid (ABTS) radicals. The free radical scavenging activity expressed as SC50 values of these compounds varied in a wide range, from a strong to no radical scavenging effect. The most effective radical scavengers were hydroxybenzylidene hydrazines containing three hydroxyl groups in the benzylidene part of their molecules. The prepared compounds were also tested for their activity to inhibit photosynthetic electron transport in spinach chloroplasts. IC50 values of these compounds varied in wide range, from an intermediate to no inhibitory effect.

Health risk reduction behaviors model for scavengers exposed to solid waste in municipal dump sites in Nakhon Ratchasima Province, Thailand

PubMed Central

Thirarattanasunthon, Phiman; Siriwong, Wattasit; Robson, Mark; Borjan, Marija

2012-01-01

The aim of this study was to evaluate the effect of comprehensive health risk protection behaviors, knowledge, attitudes, and practices among scavengers in open dump sites. A control group of 44 scavengers and an intervention group of 44 scavengers participated in this study. Interventions included the use of personal protective equipment, health protection training, and other measures. The analysis showed significant differences before and after the intervention program and also between the control and intervention groups. These observations suggest that further action should be taken to reduce adverse exposure during waste collection. To reduce health hazards to workers, dump site scavenging should be incorporated into the formal sector program. Solid waste and the management of municipal solid waste has become a human and environmental health issue and future research should look at constructing a sustainable model to help protect the health of scavengers and drive authorities to adopt safer management techniques. PMID:22969307

Study of wind retrieval from space-borne infrared coherent lidar in cloudy atmosphere.

NASA Astrophysics Data System (ADS)

Baron, Philippe; Ishii, Shoken; Mizutani, Kohei; Okamoto, Kozo; Ochiai, Satoshi

2015-04-01

Future spaceborne tropospheric wind missions using infrared coherent lidar are currently being studied in Japan and in the United States [1,2]. The line-of-sight wind velocity is retrieved from the Doppler shift frequency of the signal returned by aerosol particles. However a large percentage (70-80%) of the measured single-shot intensity profiles are expected to be contaminated by clouds [3]. A large number of cloud contaminated profiles (>40%) will be characterized by a cloud-top signal intensity stronger than the aerosol signal by a factor of one order of magnitude, and by a strong attenuation of the signal backscattered from below the clouds. Profiles including more than one cloud layer are also expected. This work is a simulation study dealing with the impacts of clouds on wind retrieval. We focus on the three following points: 1) definition of an algorithm for optimizing the wind retrieval from the cloud-top signal, 2) assessment of the clouds impact on the measurement performance and, 3) definition of a method for averaging the measurements before the retrieval. The retrieval simulations are conducted considering the instrumental characteristics selected for the Japanese study: wavelength at 2 µm, PRF of 30 Hz, pulse power of 0.125 mJ and platform altitude between 200-400 km. Liquid and ice clouds are considered. The analysis uses data from atmospheric models and statistics of cloud effects derived from CALIPSO measurements such as in [3]. A special focus is put on the average method of the measurements before retrieval. Good retrievals in the mid-upper troposphere implie the average of measured single-range power spectra over large horizontal (100 km) and vertical (1 km) ranges. Large differences of signal intensities due to the presence of clouds and the clouds non-uniform distribution have to be taken into account when averaging the data to optimize the measurement performances. References: [1] S. Ishii, T. Iwasaki, M. Sato, R. Oki, K. Okamoto, T. Ishibashi, P. Baron, and T. Nishizawa: Future Doppler lidar wind measurement from space in Japan, Proc. of SPIE Vol. 8529, 2012 [2] D. Wu, J. Tang, Z. Liu, and Y. Hu: Simulation of coherent doppler wind lidar measurement from space based on CALIPSO lidar global aerosol observations. Journal of Quantitative Spectroscopy and Radiative Transfer, 122(0), 79-86, 2013 [3] G.D Emmitt: CFLOS and cloud statistics from satellite and their impact on future space-based Doppler Wind Lidar development. Symposium on Recent Developments in Atmospheric Applications of Radar and Lidar, 2008

Global surface-based cloud observation for ISCCP

NASA Technical Reports Server (NTRS)

1994-01-01

Visual observations of cloud cover are hindered at night due to inadequate illumination of the clouds. This usually leads to an underestimation of the average cloud cover at night, especially for the amounts of middle and high clouds, in climatologies on surface observations. The diurnal cycles of cloud amounts, if based on all the surface observations, are therefore in error, but they can be obtained more accurately if the nighttime observations are screened to select those made under sufficient moonlight. Ten years of nighttime weather observations from the northern hemisphere in December were classified according to the illuminance of moonlight or twilight on the cloud tops, and a threshold level of illuminance was determined, above which the clouds are apparently detected adequately. This threshold corresponds to light from a full moon at an elevation angle of 6 degrees or from a partial moon at higher elevation, or twilight from the sun less than 9 degrees below the horizon. It permits the use of about 38% of the observations made with the sun below the horizon. The computed diurnal cycles of total cloud cover are altered considerably when this moonlight criterion is imposed. Maximum cloud cover over much of the ocean is now found to be at night or in the morning, whereas computations obtained without benefit of the moonlight criterion, as in our published atlases, showed the time of maximum to be noon or early afternoon in many regions. Cloud cover is greater at night than during the day over the open oceans far from the continents, particularly in summer. However, near noon maxima are still evident in the coastal regions, so that the global annual average oceanic cloud cover is still slightly greater during the day than at night, by 0.3%. Over land, where daytime maxima are still obtained but with reduced amplitude, average cloud cover is 3.3% greater during the daytime. The diurnal cycles of total cloud cover we obtain are compared with those of ISCCP for a few regions; they are generally in better agreement if the moonlight criterion is imposed on the surface observations. Using the moonlight criterion, we have analyzed ten years (1982-1991) of surface weather observations over land and ocean, worldwide, for total cloud cover and for the frequency of occurrence of clear sky, fog and precipitation The global average cloud cover (average of day and night) is about 2% higher if we impose the moonlight criterion than if we use all observations. The difference is greater in winter than in summer, because of the fewer hours of darkness in the summer. The amplitude of the annual cycle of total cloud cover over the Arctic Ocean and at the South Pole is diminished by a few percent when the moonlight criterion is imposed. The average cloud cover for 1982-1991 is found to be 55% for northern hemisphere land, 53% for southern hemisphere land, 66% for northern hemisphere ocean, and 70% for southern hemisphere ocean, giving a global average of 64%. The global average for daytime is 64.6% for nighttime 63.3%.

Factors Controlling Black Carbon Deposition in Snow in the Arctic

NASA Astrophysics Data System (ADS)

Qi, L.; Li, Q.; He, C.; Li, Y.

2015-12-01

This study evaluates the sensitivity of black carbon (BC) concentration in snow in the Arctic to BC emissions, dry deposition and wet scavenging efficiency using a 3D global chemical transport model GEOS-Chem driven by meteorological field GEOS-5. With all improvements, simulated median BC concentration in snow agrees with observation (19.2 ng g-1) within 10%, down from -40% in the default GEOS-Chem. When the previously missed gas flaring emissions (mainly located in Russia) are included, the total BC emission in the Arctic increases by 70%. The simulated BC in snow increases by 1-7 ng g-1, with the largest improvement in Russia. The discrepancy of median BC in snow in the whole Arctic reduces from -40% to -20%. In addition, recent measurements of BC dry deposition velocity suggest that the constant deposition velocity of 0.03 cm s-1 over snow and ice used in the GEOS-Chem is too low. So we apply resistance-in-series method to calculate the dry deposition velocity over snow and ice and the resulted dry deposition velocity ranges from 0.03 to 0.24 cm s-1. However, the simulated total BC deposition flux in the Arctic and BC in snow does not change, because the increased dry deposition flux has been compensated by decreased wet deposition flux. However, the fraction of dry deposition to total deposition increases from 16% to 25%. This may affect the mixing of BC and snow particles and further affect the radative forcing of BC deposited in snow. Finally, we reduced the scavenging efficiency of BC in mixed-phase clouds to account for the effect of Wegener-Bergeron-Findeisen (WBF) process based on recent observations. The simulated BC concentration in snow increases by 10-100%, with the largest increase in Greenland (100%), Tromsø (50%), Alaska (40%), and Canadian Arctic (30%). Annual BC loading in the Arctic increases from 0.25 to 0.43 mg m-2 and the lifetime of BC increases from 9.2 to 16.3 days. This indicates that BC simulation in the Arctic is really sensitive to the representation of BC scavenging efficiency. More measurements are needed to better understand the BC-cloud interaction and to constrain the model.

Toward the Characterization of Mixed-Phase Clouds Using Remote Sensing

NASA Astrophysics Data System (ADS)

Andronache, C.

2015-12-01

Mixed-phase clouds consist of a mixture of ice particles and liquid droplets at temperatures below 0 deg C. They are present in all seasons in many regions of the world, account for about 30% of the global cloud coverage, and are linked to cloud electrification and aircraft icing. The mix of ice particles, liquid droplets, and water vapor is unstable, and such clouds are thought to have a short lifetime. A characteristic parameter is the phase composition of mixed-phase clouds. It affects the cloud life cycle and the rate of precipitation. This parameter is important for cloud parameters retrievals by radar, lidar, and satellite and is relevant for climate modeling. The phase transformation includes the remarkable Wegener-Bergeron-Findeisen (WBF) process. The direction and the rate of the phase transformations depend on the local thermodynamic and microphysical properties. Cloud condensation nuclei (CCN) and ice nuclei (IN) particles determine to a large extent cloud microstructure and the dynamic response of clouds to aerosols. The complexity of dynamics and microphysics involved in mixed-phase clouds requires a set of observational and modeling tools that continue to be refined. Among these techniques, the remote sensing methods provide an increasing number of parameters, covering large regions of the world. Thus, a series of studies were dedicated to stratiform mixed-phase clouds revealing longer lifetime than previously thought. Satellite data and aircraft in situ measurements in deep convective clouds suggest that highly supercooled water often occurs in vigorous continental convective storms. In this study, we use cases of convective clouds to discuss the feasibility of mixed-phase clouds characterization and potential advantages of remote sensing.

The observed influence of local anthropogenic pollution on northern Alaskan cloud properties

NASA Astrophysics Data System (ADS)

Maahn, Maximilian; de Boer, Gijs; Creamean, Jessie M.; Feingold, Graham; McFarquhar, Greg M.; Wu, Wei; Mei, Fan

2017-12-01

Due to their importance for the radiation budget, liquid-containing clouds are a key component of the Arctic climate system. Depending on season, they can cool or warm the near-surface air. The radiative properties of these clouds depend strongly on cloud drop sizes, which are governed in part by the availability of cloud condensation nuclei. Here, we investigate how cloud drop sizes are modified in the presence of local emissions from industrial facilities at the North Slope of Alaska. For this, we use aircraft in situ observations of clouds and aerosols from the 5th Department of Energy Atmospheric Radiation Measurement (DOE ARM) Program's Airborne Carbon Measurements (ACME-V) campaign obtained in summer 2015. Comparison of observations from an area with petroleum extraction facilities (Oliktok Point) with data from a reference area relatively free of anthropogenic sources (Utqiaġvik/Barrow) represents an opportunity to quantify the impact of local industrial emissions on cloud properties. In the presence of local industrial emissions, the mean effective radii of cloud droplets are reduced from 12.2 to 9.4 µm, which leads to suppressed drizzle production and precipitation. At the same time, concentrations of refractory black carbon and condensation nuclei are enhanced below the clouds. These results demonstrate that the effects of anthropogenic pollution on local climate need to be considered when planning Arctic industrial infrastructure in a warming environment.

Ion chemistry of phosphorus in hydrocarbon flames : Part 1. electron scavenging by negative ion formation

NASA Astrophysics Data System (ADS)

Goodings, John M.; Hassanali, Carl S.

1990-12-01

Premixed methane--oxygen flames at atmospheric pressure of both fuel-rich (FR) and fuel-lean (FL; i.e. oxygen-rich) composition were doped with small amounts ( < 0.1 mol %) of volatile phosphorus alkyl triesters. It was demonstrated that these organo phosphorus compounds lead to efficient scavenging of the free electrons, normally present in the burnt gas of hydrocarbon flames, by negative ion formation. The anions produced by chemical ionization reactions were observed by sampling the flame gas through a nozzle into a mass spectrometer. Under both FR and FL conditions, the mass spectrum of phosphorus anions was dominated by PO-3, with a lesser contribution from PO-2. Also, H2PO-4 and PO- were observed below 100 u, as well as HPO-4 and PO-4 in the FL flame, and H2CPO-2 in the FR case. Above 100 u, the identity of the additive survivedin the FR flame to give anions of the type (RO)xPOy(OH)-z, where R is the alkyl group. However, these were replaced in the FL flame by anions of the type PO-n (n = 5-8) below 160 u. The formation chemistry of this considerable variety of phosphorus anions is discussed in detail, involving mainly three-body association, nucleophilic displacement (SN2) and proton abstraction reactions.

Effect of kilning on the antioxidant and pro-oxidant activities of pale malts.

PubMed

Woffenden, Helen M; Ames, Jennifer M; Chandra, Sachin; Anese, Monica; Nicoli, M Cristina

2002-08-14

Pale malts were prepared using standard and rapid kilning regimes that differed in the temperature and moisture profiles in the kiln. Samples were taken over the last 9 h of kilning, that is, at 18, 20, 22, 25, and 27 h. Antioxidant activity, assessed by redox potential, scavenging of the 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) radical cation (ABTS*+), and ferric reducing/antioxidant power (FRAP), increased at moisture levels below 6.7% for both regimes. The 27 h malt exposed to the rapid regime (moisture content of 4.8%) had a higher activity than the 27 h standard regime sample (moisture content of 4.8%). None of the malts scavenged oxygen. Pro-oxidant activity profiles were different for the malts obtained using each regime and, at 27 h, the rapid procedure gave malt with higher activity. Levels of (+)-catechin and ferulic acid (the most abundant phenolic compounds identified) generally increased as the moisture content of malt fell below 6.7%. Differences in antioxidant and pro-oxidant activities of the 27 h malts are partly attributed to the Maillard reaction, as evidenced by lower L* and higher b* values and higher levels of Maillard-derived flavor compounds, in the sample obtained by the rapid procedure. Levels of lipid-derived flavor compounds were significantly higher after 27 h of kilning using the rapid procedure.

Serenity Above, Tempests Below

NASA Image and Video Library

2006-01-10

Whiffs of cloud dance in Saturn atmosphere, while the dim crescent of Rhea 1,528 kilometers, or 949 miles across hangs in the distance. The dark ringplane cuts a diagonal across the top left corner of this view

Photographer : JPL Range : 12 million km. ( 7.56 million miles) P-23057C & BW This Voyager 1

NASA Technical Reports Server (NTRS)

1980-01-01

Photographer : JPL Range : 12 million km. ( 7.56 million miles) P-23057C & BW This Voyager 1 photograph of Titan, the largest of Saturn's 14 known satellites, shows little more than the upper layers of clouds covering the moon. The orange colored haze, is believed to be composed of photochemically produced hydrocarbons, hides Titan's solid surface from Voyager's camera. Some weak shadings in the clouds are becoming visible. However, note that the satellite's southern, lower, hemisphere is brighter than the northern. It is not known whether these subtle shadings are on the surface or are due to clouds below a high haze layer.

Resolving nanoparticle growth mechanisms from size- and time-dependent growth rate analysis

NASA Astrophysics Data System (ADS)

Pichelstorfer, Lukas; Stolzenburg, Dominik; Ortega, John; Karl, Thomas; Kokkola, Harri; Laakso, Anton; Lehtinen, Kari E. J.; Smith, James N.; McMurry, Peter H.; Winkler, Paul M.

2018-01-01

Atmospheric new particle formation occurs frequently in the global atmosphere and may play a crucial role in climate by affecting cloud properties. The relevance of newly formed nanoparticles depends largely on the dynamics governing their initial formation and growth to sizes where they become important for cloud microphysics. One key to the proper understanding of nanoparticle effects on climate is therefore hidden in the growth mechanisms. In this study we have developed and successfully tested two independent methods based on the aerosol general dynamics equation, allowing detailed retrieval of time- and size-dependent nanoparticle growth rates. Both methods were used to analyze particle formation from two different biogenic precursor vapors in controlled chamber experiments. Our results suggest that growth rates below 10 nm show much more variation than is currently thought and pin down the decisive size range of growth at around 5 nm where in-depth studies of physical and chemical particle properties are needed.

Cross-polar transport and scavenging of Siberian aerosols containing black carbon during the 2012 ACCESS summer campaign

DOE Office of Scientific and Technical Information (OSTI.GOV)

Raut, Jean -Christophe; Marelle, Louis; Fast, Jerome D.

During the ACCESS airborne campaign in July 2012, extensive boreal forest fires resulted in significant aerosol transport to the Arctic. A 10-day episode combining intense biomass burning over Siberia and low-pressure systems over the Arctic Ocean resulted in efficient transport of plumes containing black carbon (BC) towards the Arctic, mostly in the upper troposphere (6–8 km). Here, a combination of in situ observations (DLR Falcon aircraft), satellite analysis and WRF-Chem simulations is used to understand the vertical and horizontal transport mechanisms of BC with a focus on the role of wet removal. Between the northwestern Norwegian coast and the Svalbardmore » archipelago, the Falcon aircraft sampled plumes with enhanced CO concentrations up to 200 ppbv and BC mixing ratios up to 25 ng kg –1. During transport to the Arctic region, a large fraction of BC particles are scavenged by two wet deposition processes, namely wet removal by large-scale precipitation and removal in wet convective updrafts, with both processes contributing almost equally to the total accumulated deposition of BC. Our results underline that applying a finer horizontal resolution (40 instead of 100 km) improves the model performance, as it significantly reduces the overestimation of BC levels observed at a coarser resolution in the mid-troposphere. According to the simulations at 40 km, the transport efficiency of BC (TE BC) in biomass burning plumes was larger (60 %), because it was impacted by small accumulated precipitation along trajectory (1 mm). In contrast TE BC was small (< 30 %) and accumulated precipitation amounts were larger (5–10 mm) in plumes influenced by urban anthropogenic sources and flaring activities in northern Russia, resulting in transport to lower altitudes. TE BC due to large-scale precipitation is responsible for a sharp meridional gradient in the distribution of BC concentrations. Wet removal in cumulus clouds is the cause of modeled vertical gradient of TE BC, especially in the mid-latitudes, reflecting the distribution of convective precipitation, but is dominated in the Arctic region by the large-scale wet removal associated with the formation of stratocumulus clouds in the planetary boundary layer (PBL) that produce frequent drizzle.« less

Cross-polar transport and scavenging of Siberian aerosols containing black carbon during the 2012 ACCESS summer campaign

DOE PAGES

Raut, Jean -Christophe; Marelle, Louis; Fast, Jerome D.; ...

2017-09-15

During the ACCESS airborne campaign in July 2012, extensive boreal forest fires resulted in significant aerosol transport to the Arctic. A 10-day episode combining intense biomass burning over Siberia and low-pressure systems over the Arctic Ocean resulted in efficient transport of plumes containing black carbon (BC) towards the Arctic, mostly in the upper troposphere (6–8 km). Here, a combination of in situ observations (DLR Falcon aircraft), satellite analysis and WRF-Chem simulations is used to understand the vertical and horizontal transport mechanisms of BC with a focus on the role of wet removal. Between the northwestern Norwegian coast and the Svalbardmore » archipelago, the Falcon aircraft sampled plumes with enhanced CO concentrations up to 200 ppbv and BC mixing ratios up to 25 ng kg –1. During transport to the Arctic region, a large fraction of BC particles are scavenged by two wet deposition processes, namely wet removal by large-scale precipitation and removal in wet convective updrafts, with both processes contributing almost equally to the total accumulated deposition of BC. Our results underline that applying a finer horizontal resolution (40 instead of 100 km) improves the model performance, as it significantly reduces the overestimation of BC levels observed at a coarser resolution in the mid-troposphere. According to the simulations at 40 km, the transport efficiency of BC (TE BC) in biomass burning plumes was larger (60 %), because it was impacted by small accumulated precipitation along trajectory (1 mm). In contrast TE BC was small (< 30 %) and accumulated precipitation amounts were larger (5–10 mm) in plumes influenced by urban anthropogenic sources and flaring activities in northern Russia, resulting in transport to lower altitudes. TE BC due to large-scale precipitation is responsible for a sharp meridional gradient in the distribution of BC concentrations. Wet removal in cumulus clouds is the cause of modeled vertical gradient of TE BC, especially in the mid-latitudes, reflecting the distribution of convective precipitation, but is dominated in the Arctic region by the large-scale wet removal associated with the formation of stratocumulus clouds in the planetary boundary layer (PBL) that produce frequent drizzle.« less

Improving the representation of clouds, radiation, and precipitation using spectral nudging in the Weather Research and Forecasting model

NASA Astrophysics Data System (ADS)

Spero, Tanya L.; Otte, Martin J.; Bowden, Jared H.; Nolte, Christopher G.

2014-10-01

Spectral nudging—a scale-selective interior constraint technique—is commonly used in regional climate models to maintain consistency with large-scale forcing while permitting mesoscale features to develop in the downscaled simulations. Several studies have demonstrated that spectral nudging improves the representation of regional climate in reanalysis-forced simulations compared with not using nudging in the interior of the domain. However, in the Weather Research and Forecasting (WRF) model, spectral nudging tends to produce degraded precipitation simulations when compared to analysis nudging—an interior constraint technique that is scale indiscriminate but also operates on moisture fields which until now could not be altered directly by spectral nudging. Since analysis nudging is less desirable for regional climate modeling because it dampens fine-scale variability, changes are proposed to the spectral nudging methodology to capitalize on differences between the nudging techniques and aim to improve the representation of clouds, radiation, and precipitation without compromising other fields. These changes include adding spectral nudging toward moisture, limiting nudging to below the tropopause, and increasing the nudging time scale for potential temperature, all of which collectively improve the representation of mean and extreme precipitation, 2 m temperature, clouds, and radiation, as demonstrated using a model-simulated 20 year historical period. Such improvements to WRF may increase the fidelity of regional climate data used to assess the potential impacts of climate change on human health and the environment and aid in climate change mitigation and adaptation studies.

Structure and extent of the giant molecular cloud near M17

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elmegreen, B.G.; Lada, C.J.; Dickinson, D.F.

1979-06-01

Carbon monoxide emission at ..nu../sub LSR/ = 20 +- 2 km s/sup -1/ is found to extend 4/sup 0/ (approx.170 pc) southwest of M17, and is studied in an attempt to understand the internal structure and dynamics of a giant molecular cloud complex. The region contains two primary clouds. The first has at least 2 x 10/sup 5/ M/sub sun/ of molecular gas and extends for 1./sup 0/8 (72 pc) parallel to, but below the galactic plane southwest of M17. The second, located above the plane approximately 2./sup 0/5 southwest of M17, is about 1./sup 0/7 in extent, but containsmore » considerably less molecular mass (> or approx. =3 x 10/sup 4/ M/sub sun/). Between these two clouds is a 1/sup 0/ long region of relatively low intensity, clumpy CO emission which appears to bridge the two main clouds. The molecular mass within this bridge is estimated to be 2 x 10/sup 4/ M/sub sun/. The cloud associated with M17 is itself divided into four discrete fragments of approximately equal mass (4 x 10/sup 4/ M/sub sun/). The /sup 12/CO and /sup 13/CO line widths are higher in these four fragments than they are between the fragments. OB star formation is active only in the northeastern two of these fragments. The /sup 13/CO line widths in the discrete fragments satisfy the virial theorem for the derived masses. (b) The /sup 13/CO velocity structure in the large complex containing M17 shows a gradual change from regularity in the northeast to irregularity and occasionally multipeaked profiles in the southwest. This change corresponds to a gradient in the degree of compactness and intensity of star formation in the four fragments. A massive (10/sup 5/ M/sub sun/) molecular cloud complex associated with M16, 2/sup 0/ north of M17, and the two clouds southwest of M17, form a pattern of equally spaced star-forming clouds whose positions alternate above and below the galactic plane. Patchy CO emission is found between these three objects. The entire region of molecular emission is approx.250 pc long.« less

GEM-AC, a stratospheric-tropospheric global and regional model for air quality and climate change: evaluation of gas phase properties

NASA Astrophysics Data System (ADS)

Kaminski, J. W.; Semeniuk, K.; McConnell, J. C.; Lupu, A.; Mamun, A.

2012-12-01

The Global Environmental Multiscale model for Air Quality and climate change (GEM-AC) is a global general circulation model based on the GEM model developed by the Meteorological Service of Canada for operational weather forecasting. It can be run with a global uniform (GU) grid or a global variable (GV) grid where the core has uniform grid spacing and the exterior grid expands. With a GV grid high resolution regional runs can be accomplished without a concern for boundary conditions. The work described here uses GEM version 3.3.2. The gas-phase chemistry consists in detailed reactions of Ox, NOx, HOx, CO, CH4, NMVOCs, halocarbons, ClOx and BrO. We have recently added elements of the Global Modal-aerosol eXtension (GMXe) scheme to address aerosol microphysics and gas-aerosol partitioning. The evaluation of the MESSY GMXe aerosol scheme is addressed in another poster. The Canadian aerosol module (CAM) is also available. Tracers are advected using the semi-Lagrangian scheme native to GEM. The vertical transport includes parameterized subgrid scale turbulence and large scale convection. Dry deposition is implemented as a flux boundary condition in the vertical diffusion equation. For climate runs the GHGs CO2, CH4, N2O, CFCs in the radiation scheme are adjusted to the scenario considered. In GV regional mode at high resolutions a lake model, FLAKE is also included. Wet removal comprises both in-cloud and below-cloud scavenging. With the gas phase chemistry the model has been run for a series of ten year time slices on a 3°×3° global grid with 77 hybrid levels from the surface to 0.15 hPa. The tropospheric and stratospheric gas phase results are compared with satellite measurements including, ACE, MIPAS, MOPITT, and OSIRIS. Current evaluations of the ozone field and other stratospheric fields are encouraging and tropospheric lifetimes for CH4 and CH3CCl3 are in reasonable accord with tropospheric models. We will present results for current and future climate conditions forced by SST for 2050.

The vertical structure of Jupiter and Saturn zonal winds from nonlinear simulations of major vortices and planetary-scale disturbances

NASA Astrophysics Data System (ADS)

Garcia-Melendo, E.; Legarreta, J.; Sanchez-Lavega, A.

2012-12-01

Direct measurements of the structure of the zonal winds of Jupiter and Saturn below the upper cloud layer are very difficult to retrieve. Except from the vertical profile at a Jupiter hot spot obtained from the Galileo probe in 1995 and measurements from cloud tracking by Cassini instruments just below the upper cloud, no other data are available. We present here our inferences of the vertical structure of Jupiter and Saturn zonal wind across the upper troposphere (deep down to about 10 bar level) obtained from nonlinear simulations using the EPIC code of the stability and interactions of large-scale vortices and planetary-scale disturbances in both planets. Acknowledgements: This work has been funded by Spanish MICIIN AYA2009-10701 with FEDER support, Grupos Gobierno Vasco IT-464-07 and UPV/EHU UFI11/55. [1] García-Melendo E., Sánchez-Lavega A., Dowling T.., Icarus, 176, 272-282 (2005). [2] García-Melendo E., Sánchez-Lavega A., Hueso R., Icarus, 191, 665-677 (2007). [3] Sánchez-Lavega A., et al., Nature, 451, 437- 440 (2008). [4] Sánchez-Lavega A., et al., Nature, 475, 71-74 (2011).

Challenges for Cloud Modeling in the Context of Aerosol–Cloud–Precipitation Interactions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lebo, Zachary J.; Shipway, Ben J.; Fan, Jiwen

The International Cloud Modeling Workshop (CMW) has been a longstanding tradition in the cloud microphysics modeling community and is typically held the week prior to the International Conference on Clouds and Precipitation (ICCP). For the Ninth CMW, more than 40 participants from 10 countries convened at the Met Office in Exeter, United Kingdom. The workshop included 4 detailed case studies (described in more detail below) rooted in recent field campaigns. The overarching objective of these cases was to utilize new observations to better understand inter-model differences and model deficiencies, explore new modeling techniques, and gain physical insight into the behaviormore » of clouds. As was the case at the Eighth CMW, there was a general theme of understanding the role of aerosol impacts in the context of cloud-precipitation interactions. However, an additional objective was the focal point of several cases at the most recent workshop: microphysical-dynamical interactions. Many of the cases focused less on idealized small-domain simulations (as was the general focus of previous workshops) and more on large-scale nested configurations examining effects at various scales.« less

Recent Findings in EPA’s Lead Scavengers Evaluation

EPA Science Inventory

In response to continued concerns about the concentrations of 1,2-dibromoethane (EDB) in ground water from spills of leaded gasoline, OUST formed a Lead Scavengers Team with assistance from ASTSWMO. ASTSWMO and EPA Regions solicited participation from state agencies. Analysis w...

Turnover of Village Chickens Undermines Vaccine Coverage to Control HPAI H5N1.

PubMed

Villanueva-Cabezas, J P; Campbell, P T; McCaw, J M; Durr, P A; McVernon, J

2017-02-01

Highly pathogenic avian influenza (HPAI) subtype H5N1 remains an enzootic disease of village chickens in Indonesia, posing ongoing risk at the animal-human interface. Previous modelling showed that the fast natural turnover of chicken populations might undermine herd immunity after vaccination, although actual details of how this effect applies to Indonesia's village chicken population have not been determined. We explored the turnover effect in Indonesia's scavenging and mixed populations of village chickens using an extended Leslie matrix model parameterized with data collected from village chicken flocks in Java region, Indonesia. Population dynamics were simulated for 208 weeks; the turnover effect was simulated for 16 weeks after vaccination in two 'best case' scenarios, where the whole population (scenario 1), or birds aged over 14 days (scenario 2), were vaccinated. We found that the scavenging and mixed populations have different productive traits. When steady-state dynamics are reached, both populations are dominated by females (54.5%), and 'growers' and 'chicks' represent the most abundant age stages with 39% and 38% in the scavenging, and 60% and 25% in the mixed population, respectively. Simulations showed that the population turnover might reduce the herd immunity below the critical threshold that prevents the re-emergence of HPAI H5N1 4-8 weeks (scavenging) and 6-9 weeks (mixed population) after vaccination in scenario 1, and 2-6 weeks (scavenging) and 4-7 weeks (mixed population) after vaccination in scenario 2. In conclusion, we found that Indonesia's village chicken population does not have a unique underlying population dynamic and therefore, different turnover effects on herd immunity may be expected after vaccination; nonetheless, our simulations carried out in best case scenarios highlight the limitations of current vaccine technologies to control HPAI H5N1. This suggests that the improvements and complementary strategies are necessary and must be explored. © 2016 Blackwell Verlag GmbH.

Homogeneous Aerosol Freezing in the Tops of High-Altitude Tropical Cumulonimbus Clouds

NASA Technical Reports Server (NTRS)

Jensen, E. J.; Ackerman, A. S.

2006-01-01

Numerical simulations of deep, intense continental tropical convection indicate that when the cloud tops extend more than a few kilometers above the liquid water homogeneous freezing level, ice nucleation due to freezing of entrained aqueous sulfate aerosols generates large concentrations of small crystals (diameters less than approx. equal to 20 micrometers). The small crystals produced by aerosol freezing have the largest impact on cloud-top ice concentration for convective clouds with strong updrafts but relatively low aerosol concentrations. An implication of this result is that cloud-top ice concentrations in high anvil cirrus can be controlled primarily by updraft speeds in the tops of convective plumes and to a lesser extent by aerosol concentrations in the uppermost troposphere. While larger crystals precipitate out and sublimate in subsaturated air below, the population of small crystals can persist in the saturated uppermost troposphere for many hours, thereby prolonging the lifetime of remnants from anvil cirrus in the tropical tropopause layer.

Anisotropy Changes of a Fluorescent Probe during the Micellar Growth and Clouding of a Nonionic Detergent.

PubMed

Komaromy-Hiller; von Wandruszka R

1996-01-15

The effects of temperature and Triton X-114 (TX-114) concentration on the fluorescence anisotropy of perylene were investigated before and after detergent clouding. The measured anisotropy values were used to estimate the microviscosity of the micellar interior. In the lower detergent concentration range, an anisotropy maximum was observed at the critical micelle concentration (CMC), while the values decreased in the range immediately above the CMC. This was ascribed to the micellar volume increase, which, in the case of TX-114, was not accompanied by a more ordered internal environment. A gradual decrease of anisotropy and microviscosity with increasing temperature below the cloud point was observed. At the cloud point, no abrupt changes were found to occur. Compared to detergents with more flexible hydrophobic moieties, TX-114 micelles have a relatively ordered micellar interior indicated by the microviscosity and calculated fusion energy values. In the separated micellar phase formed after clouding, the probe anisotropy increased as water was eliminated at higher temperatures.

Factors controlling black carbon distribution in the Arctic

NASA Astrophysics Data System (ADS)

Qi, Ling; Li, Qinbin; Li, Yinrui; He, Cenlin

2017-01-01

We investigate the sensitivity of black carbon (BC) in the Arctic, including BC concentration in snow (BCsnow, ng g-1) and surface air (BCair, ng m-3), as well as emissions, dry deposition, and wet scavenging using the global three-dimensional (3-D) chemical transport model (CTM) GEOS-Chem. We find that the model underestimates BCsnow in the Arctic by 40 % on average (median = 11.8 ng g-1). Natural gas flaring substantially increases total BC emissions in the Arctic (by ˜ 70 %). The flaring emissions lead to up to 49 % increases (0.1-8.5 ng g-1) in Arctic BCsnow, dramatically improving model comparison with observations (50 % reduction in discrepancy) near flaring source regions (the western side of the extreme north of Russia). Ample observations suggest that BC dry deposition velocities over snow and ice in current CTMs (0.03 cm s-1 in the GEOS-Chem) are too small. We apply the resistance-in-series method to compute a dry deposition velocity (vd) that varies with local meteorological and surface conditions. The resulting velocity is significantly larger and varies by a factor of 8 in the Arctic (0.03-0.24 cm s-1), which increases the fraction of dry to total BC deposition (16 to 25 %) yet leaves the total BC deposition and BCsnow in the Arctic unchanged. This is largely explained by the offsetting higher dry and lower wet deposition fluxes. Additionally, we account for the effect of the Wegener-Bergeron-Findeisen (WBF) process in mixed-phase clouds, which releases BC particles from condensed phases (water drops and ice crystals) back to the interstitial air and thereby substantially reduces the scavenging efficiency of clouds for BC (by 43-76 % in the Arctic). The resulting BCsnow is up to 80 % higher, BC loading is considerably larger (from 0.25 to 0.43 mg m-2), and BC lifetime is markedly prolonged (from 9 to 16 days) in the Arctic. Overall, flaring emissions increase BCair in the Arctic (by ˜ 20 ng m-3), the updated vd more than halves BCair (by ˜ 20 ng m-3), and the WBF effect increases BCair by 25-70 % during winter and early spring. The resulting model simulation of BCsnow is substantially improved (within 10 % of the observations) and the discrepancies of BCair are much smaller during the snow season at Barrow, Alert, and Summit (from -67-47 % to -46-3 %). Our results point toward an urgent need for better characterization of flaring emissions of BC (e.g., the emission factors, temporal, and spatial distribution), extensive measurements of both the dry deposition of BC over snow and ice, and the scavenging efficiency of BC in mixed-phase clouds. In addition, we find that the poorly constrained precipitation in the Arctic may introduce large uncertainties in estimating BCsnow. Doubling precipitation introduces a positive bias approximately as large as the overall effects of flaring emissions and the WBF effect; halving precipitation produces a similarly large negative bias.

Improved Arctic Cloud and Aerosol Research and Model Parameterizations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kenneth Sassen

2007-03-01

In this report are summarized our contributions to the Atmospheric Measurement (ARM) program supported by the Department of Energy. Our involvement commenced in 1990 during the planning stages of the design of the ARM Cloud and Radiation Testbed (CART) sites. We have worked continuously (up to 2006) on our ARM research objectives, building on our earlier findings to advance our knowledge in several areas. Below we summarize our research over this period, with an emphasis on the most recent work. We have participated in several aircraft-supported deployments at the SGP and NSA sites. In addition to deploying the Polarization Diversitymore » Lidar (PDL) system (Sassen 1994; Noel and Sassen 2005) designed and constructed under ARM funding, we have operated other sophisticated instruments W-band polarimetric Doppler radar, and midinfrared radiometer for intercalibration and student training purposes. We have worked closely with University of North Dakota scientists, twice co-directing the Citation operations through ground-to-air communications, and serving as the CART ground-based mission coordinator with NASA aircraft during the 1996 SUCCESS/IOP campaign. We have also taken a leading role in initiating case study research involving a number of ARM coinvestigators. Analyses of several case studies from these IOPs have been reported in journal articles, as we show in Table 1. The PDL has also participated in other major field projects, including FIRE II and CRYSTAL-FACE. In general, the published results of our IOP research can be divided into two categories: comprehensive cloud case study analyses to shed light on fundamental cloud processes using the unique CART IOP measurement capabilities, and the analysis of in situ data for the testing of remote sensing cloud retrieval algorithms. One of the goals of the case study approach is to provide sufficiently detailed descriptions of cloud systems from the data-rich CART environment to make them suitable for application to cloud modeling groups, such as the GEWEX Cloud Simulation Study (GCSS) Cirrus Working Groups. In this paper we summarize our IOP-related accomplishments.« less

Aerosol and cloud microphysics covariability in the northeast Pacific boundary layer estimated with ship-based and satellite remote sensing observations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Painemal, David; Chiu, J. -Y. Christine; Minnis, Patrick

We utilized ship measurements collected over the northeast Pacific along transects between the port of Los Angeles (33.7°N, 118.2°W) and Honolulu (21.3°N, 157.8°W) during May to August 2013 in order to investigate the covariability between marine low cloud microphysical and aerosol properties. Ship-based retrievals of cloud optical depth (τ) from a Sun photometer and liquid water path (LWP) from a microwave radiometer were combined to derive cloud droplet number concentration N d and compute a cloud-aerosol interaction (ACI) metric defined as ACI CCN=∂ ln(N d)/∂ ln(CCN), with CCN denoting the cloud condensation nuclei concentration measured at 0.4% (CCN 0.4) andmore » 0.3% (CCN 0.3) supersaturation. Analysis of CCN 0.4, accumulation mode aerosol concentration (N a), and extinction coefficient (σ ext) indicates that N a and σ ext can be used as CCN 0.4 proxies for estimating ACI. ACI CCN derived from 10 min averaged N d and CCN 0.4 and CCN 0.3, and CCN 0.4 regressions using N a and σ ext, produce high ACI CCN: near 1.0, that is, a fractional change in aerosols is associated with an equivalent fractional change in Nd. ACI CCN computed in deep boundary layers was small (ACI CCN=0.60), indicating that surface aerosol measurements inadequately represent the aerosol variability below clouds. Satellite cloud retrievals from MODerate-resolution Imaging Spectroradiometer and GOES-15 data were compared against ship-based retrievals and further analyzed to compute a satellite-based ACI CCN. We found that the satellite data correlated well with their ship-based counterparts with linear correlation coefficients equal to or greater than 0.78. Combined satellite Nd and ship-based CCN 0.4 and Na yielded a maximum ACI CCN=0.88–0.92, a value slightly less than the ship-based ACI CCN, but still consistent with aircraft-based studies in the eastern Pacific.« less

Aerosol and cloud microphysics covariability in the northeast Pacific boundary layer estimated with ship-based and satellite remote sensing observations

DOE PAGES

Painemal, David; Chiu, J. -Y. Christine; Minnis, Patrick; ...

2017-02-27

We utilized ship measurements collected over the northeast Pacific along transects between the port of Los Angeles (33.7°N, 118.2°W) and Honolulu (21.3°N, 157.8°W) during May to August 2013 in order to investigate the covariability between marine low cloud microphysical and aerosol properties. Ship-based retrievals of cloud optical depth (τ) from a Sun photometer and liquid water path (LWP) from a microwave radiometer were combined to derive cloud droplet number concentration N d and compute a cloud-aerosol interaction (ACI) metric defined as ACI CCN=∂ ln(N d)/∂ ln(CCN), with CCN denoting the cloud condensation nuclei concentration measured at 0.4% (CCN 0.4) andmore » 0.3% (CCN 0.3) supersaturation. Analysis of CCN 0.4, accumulation mode aerosol concentration (N a), and extinction coefficient (σ ext) indicates that N a and σ ext can be used as CCN 0.4 proxies for estimating ACI. ACI CCN derived from 10 min averaged N d and CCN 0.4 and CCN 0.3, and CCN 0.4 regressions using N a and σ ext, produce high ACI CCN: near 1.0, that is, a fractional change in aerosols is associated with an equivalent fractional change in Nd. ACI CCN computed in deep boundary layers was small (ACI CCN=0.60), indicating that surface aerosol measurements inadequately represent the aerosol variability below clouds. Satellite cloud retrievals from MODerate-resolution Imaging Spectroradiometer and GOES-15 data were compared against ship-based retrievals and further analyzed to compute a satellite-based ACI CCN. We found that the satellite data correlated well with their ship-based counterparts with linear correlation coefficients equal to or greater than 0.78. Combined satellite Nd and ship-based CCN 0.4 and Na yielded a maximum ACI CCN=0.88–0.92, a value slightly less than the ship-based ACI CCN, but still consistent with aircraft-based studies in the eastern Pacific.« less

Insights into Aqueous-phase processing through Comparison of the Organic Chemical Composition of Atmospheric Particles and Cloud Water in the Southeast United States

NASA Astrophysics Data System (ADS)

Boone, E.; Laskin, J.; Laskin, A.; Wirth, C.; Shepson, P. B.; Stirm, B. H.; Pratt, K.

2014-12-01

Organic compounds comprise a significant mass fraction of submicron atmospheric particles with considerable contribution from secondary organic aerosol (SOA), a large fraction of which is formed from the oxidation of biogenic volatile organic compounds. Aqueous-phase reactions in particles and cloud droplets are suggested to increase SOA mass and change the chemical composition the particles following cloud evaporation. Aqueous-phase processing may also explain discrepancies between measurements and models. To gain a better understanding of these processes, cloud water and below-cloud atmospheric particles were collected onboard a research aircraft during the Southeast Oxidants and Aerosol Study (SOAS) over Alabama in June 2013. Nanospray desorption electrospray ionization (nano-DESI) and direct electrospray ionization (ESI) coupled with high resolution mass spectrometry were utilized to compare the organic molecular composition of the particle and cloud water samples, respectively. Several hundred unique compounds have been identified in the particle and cloud water samples, allowing possible aqueous-phase reactions to be examined. Hydrolysis of organosulfate compounds, aqueous-phase formation of nitrogen-containing compounds, and possible fragmentation of oligomeric compounds will be discussed, with comparisons to previous laboratory studies. This study provides insights into aqueous-phase reactions in ambient cloud droplets.

Analysis of in situ measurements of cirrus anvil outflow dynamics

NASA Astrophysics Data System (ADS)

Lederman, J. I.; Whiteway, J. A.

2012-12-01

The airborne campaign, EMERALD 2 (Egrett Microphysics Experiment with Radiation, Lidar, and Dynamics,) was conducted out of Darwin, Australia in 2002. Objectives included characterization of the dynamics in the cirrus anvil outflow from tropical deep convection. Two aircraft, the Egrett and King Air, were flown in tandem in the upper troposphere (7 km - 15 km) to collect in situ measurements in the anvil outflow from a storm named "Hector" that occurs on a regular basis over the Tiwi Islands north of Darwin during November and December. Turbulence probes mounted on the wings of the Egrett aircraft were used to measure the wind fluctuations across the anvil and along its length with a spatial resolution of 2 meters. The in situ measurements from the Egrett were coincident with lidar measurements of the cloud structure from the King Air aircraft flying directly below. The presentation will show results of the analysis of the measurements with an emphasis on the turbulence, gravity waves, and coherent structures that are particular to the cirrus anvil outflow environment. Emphasis is placed on the dynamics associated with the generation of mammatus formations at the base of the anvil clouds.

ERBE S10 WFOV SF NAT

Atmospheric Science Data Center

2016-06-13

... warming caused by greenhouse gases. Absorption of Solar Radiation by Clouds The results of the study demonstrate the present ... spacecraft, as described below. WFOV Instruments: these two fixed detectors continuously view the earth disc (plus a small ring of ...

Continuous Lidar Monitoring of Polar Stratospheric Clouds at the South Pole

NASA Technical Reports Server (NTRS)

Campbell, James R.; Welton, Ellsworth J.; Spinhirne, James D

2009-01-01

Polar stratospheric clouds (PSC) play a primary role in the formation of annual ozone holes over Antarctica during the austral sunrise. Meridional temperature gradients in the lower stratosphere and upper troposphere, caused by strong radiative cooling, induce a broad dynamic vortex centered near the South Pole that decouples and insulates the winter polar airmass. PSC nucleate and grow as vortex temperatures gradually fall below equilibrium saturation and frost points for ambient sulfate, nitrate, and water vapor concentrations (generally below 197 K). Cloud surfaces promote heterogeneous reactions that convert stable chlorine and bromine-based molecules into photochemically active ones. As spring nears, and the sun reappears and rises, photolysis decomposes these partitioned compounds into individual halogen atoms that react with and catalytically destroy thousands of ozone molecules before they are stochastically neutralized. Despite a generic understanding of the ozone hole paradigm, many key components of the system, such as cloud occurrence, phase, and composition; particle growth mechanisms; and denitrification of the lower stratosphere have yet to be fully resolved. Satellite-based observations have dramatically improved the ability to detect PSC and quantify seasonal polar chemical partitioning. However, coverage directly over the Antarctic plateau is limited by polar-orbiting tracks that rarely exceed 80 degrees S. In December 1999, a NASA Micropulse Lidar Network instrument (MPLNET) was first deployed to the NOAA Earth Systems Research Laboratory (ESRL) Atmospheric Research Observatory at the Amundsen-Scott South Pole Station for continuous cloud and aerosol profiling. MPLNET instruments are eye-safe, capable of full-time autonomous operation, and suitably rugged and compact to withstand long-term remote deployment. With only brief interruptions during the winters of 2001 and 2002, a nearly continuous data archive exists to the present.

KSC-84PC-0228

NASA Image and Video Library

1984-07-13

CAPE CANAVERAL, Fla. -- At Cape Canaveral Air Force Station in Florida, British engineers conduct tests on the United Kingdom Subsatellite, part of the three-spacecraft international Active Magnetospheric Particle Tracer Explorer AMPTE mission scheduled for launch on Aug. 9, 1984 aboard a Delta rocket. The 172-pound UKS contains a comprehensive set of plasma measuring instruments to record the effects of chemical clouds released by the West German built Ion Release Module. The other AMPTE spacecraft – the Charged Composition Explorer CCEUnited States) – will operate far below, from inside the Earth’s magnetosphere, where it will track the ionized clouds as it is swept along by the solar wind. With the CCE studying this activity from below, and the IRM and UKS studying it from above, scientists expect to acquire valuable new data on exactly how the solar wind interacts with the Earth’s magnetic fields. Photo Credit: NASA

DIRBE obtained at infrared wavelengths of 25, 60 and 100 Aum

NASA Technical Reports Server (NTRS)

2002-01-01

This image combines data from the DIRBE obtained at infrared wavelengths of 25, 60 and 100 Aum. The sky brightness at these wavelengths is represented respectively by blue, green, and red colors in the image. The plane of the Milky Way Galaxy lies horizontally across the middle of the image with the Galactic center at the center. The image is dominated by the thermal emission from interstellar dust in the Milky Way. The wispy-looking dust features are called 'infrared cirrus.' The structured, warmer emission from interplanetary dust, shown in blue, is also prominent. The image shows a number of well-known dusty regions in the Milky Way, such as the Orion molecular clouds (below the plane, far right) which are active 'stellar nurseries' in our Galaxy. Two neighboring galaxies, the Large and Small Magellanic Clouds also can be distinguished (below the plane, approximately halfway between the center and right edge of the image).

Phytochemical Analysis and Free Radical Scavenging Activity of Medicinal Plants Gnidia glauca and Dioscorea bulbifera

PubMed Central

Ghosh, Sougata; Derle, Abhishek; Ahire, Mehul; More, Piyush; Jagtap, Soham; Phadatare, Suvarna D.; Patil, Ajay B.; Jabgunde, Amit M.; Sharma, Geeta K.; Shinde, Vaishali S.; Pardesi, Karishma; Dhavale, Dilip D.; Chopade, Balu A.

2013-01-01

Gnidia glauca and Dioscorea bulbifera are traditional medicinal plants that can be considered as sources of natural antioxidants. Herein we report the phytochemical analysis and free radical scavenging activity of their sequential extracts. Phenolic and flavonoid content were determined. Scavenging activity was checked against pulse radiolysis generated ABTS•+ and OH radical, in addition to DPPH, superoxide and hydroxyl radicals by biochemical methods followed by principal component analysis. G. glauca leaf extracts were rich in phenolic and flavonoid content. Ethyl acetate extract of D. bulbifera bulbs and methanol extract of G. glauca stem exhibited excellent scavenging of pulse radiolysis generated ABTS•+ radical with a second order rate constant of 2.33×106 and 1.72×106, respectively. Similarly, methanol extract of G. glauca flower and ethyl acetate extract of D. bulbifera bulb with second order rate constants of 4.48×106 and 4.46×106 were found to be potent scavengers of pulse radiolysis generated OH radical. G. glauca leaf and stem showed excellent reducing activity and free radical scavenging activity. HPTLC fingerprinting, carried out in mobile phase, chloroform: toluene: ethanol (4: 4: 1, v/v) showed presence of florescent compound at 366 nm as well as UV active compound at 254 nm. GC-TOF-MS analysis revealed the predominance of diphenyl sulfone as major compound in G. glauca. Significant levels of n-hexadecanoic acid and octadecanoic acid were also present. Diosgenin (C27H42O3) and diosgenin (3á,25R) acetate were present as major phytoconstituents in the extracts of D. bulbifera. G. glauca and D. bulbifera contain significant amounts of phytochemicals with antioxidative properties that can be exploited as a potential source for herbal remedy for oxidative stress induced diseases. These results rationalize further investigation in the potential discovery of new natural bioactive principles from these two important medicinal plants. PMID:24367520

Phytochemical analysis and free radical scavenging activity of medicinal plants Gnidia glauca and Dioscorea bulbifera.

PubMed

Ghosh, Sougata; Derle, Abhishek; Ahire, Mehul; More, Piyush; Jagtap, Soham; Phadatare, Suvarna D; Patil, Ajay B; Jabgunde, Amit M; Sharma, Geeta K; Shinde, Vaishali S; Pardesi, Karishma; Dhavale, Dilip D; Chopade, Balu A

2013-01-01

Gnidia glauca and Dioscorea bulbifera are traditional medicinal plants that can be considered as sources of natural antioxidants. Herein we report the phytochemical analysis and free radical scavenging activity of their sequential extracts. Phenolic and flavonoid content were determined. Scavenging activity was checked against pulse radiolysis generated ABTS(•+) and OH radical, in addition to DPPH, superoxide and hydroxyl radicals by biochemical methods followed by principal component analysis. G. glauca leaf extracts were rich in phenolic and flavonoid content. Ethyl acetate extract of D. bulbifera bulbs and methanol extract of G. glauca stem exhibited excellent scavenging of pulse radiolysis generated ABTS(•+) radical with a second order rate constant of 2.33 × 10(6) and 1.72 × 10(6), respectively. Similarly, methanol extract of G. glauca flower and ethyl acetate extract of D. bulbifera bulb with second order rate constants of 4.48 × 10(6) and 4.46 × 10(6) were found to be potent scavengers of pulse radiolysis generated OH radical. G. glauca leaf and stem showed excellent reducing activity and free radical scavenging activity. HPTLC fingerprinting, carried out in mobile phase, chloroform: toluene: ethanol (4: 4: 1, v/v) showed presence of florescent compound at 366 nm as well as UV active compound at 254 nm. GC-TOF-MS analysis revealed the predominance of diphenyl sulfone as major compound in G. glauca. Significant levels of n-hexadecanoic acid and octadecanoic acid were also present. Diosgenin (C₂₇H₄₂O₃) and diosgenin (3á,25R) acetate were present as major phytoconstituents in the extracts of D. bulbifera. G. glauca and D. bulbifera contain significant amounts of phytochemicals with antioxidative properties that can be exploited as a potential source for herbal remedy for oxidative stress induced diseases. These results rationalize further investigation in the potential discovery of new natural bioactive principles from these two important medicinal plants.

Updates on the EPA Study of Lead Scavengers (EDB and DCA)

EPA Science Inventory

In response to continued concerns about the concentrations of 1,2-dibromoethane (EDB) in ground water from spills of leaded gasoline, OUST formed a Lead Scavengers Team with assistance from ASTSWMO. ASTSWMO and EPA Regions solicited participation from state agencies. Analysis w...

Properties and rotation of molecular clouds in M 33

NASA Astrophysics Data System (ADS)

Braine, J.; Rosolowsky, E.; Gratier, P.; Corbelli, E.; Schuster, K.-F.

2018-04-01

The sample of 566 molecular clouds identified in the CO(2-1) IRAM survey covering the disk of M 33 is explored in detail. The clouds were found using CPROPS and were subsequently catalogued in terms of their star-forming properties as non-star-forming (A), with embedded star formation (B), or with exposed star formation (C, e.g., presence of Hα emission). We find that the size-linewidth relation among the M 33 clouds is quite weak but, when comparing with clouds in other nearby galaxies, the linewidth scales with average metallicity. The linewidth and particularly the line brightness decrease with galactocentric distance. The large number of clouds makes it possible to calculate well-sampled cloud mass spectra and mass spectra of subsamples. As noted earlier, but considerably better defined here, the mass spectrum steepens (i.e., higher fraction of small clouds) with galactocentric distance. A new finding is that the mass spectrum of A clouds is much steeper than that of the star-forming clouds. Further dividing the sample, this difference is strong at both large and small galactocentric distances and the A vs. C difference is a stronger effect than the inner vs. outer disk difference in mass spectra. Velocity gradients are identified in the clouds using standard techniques. The gradients are weak and are dominated by prograde rotation; the effect is stronger for the high signal-to-noise clouds. A discussion of the uncertainties is presented. The angular momenta are low but compatible with at least some simulations. Finally, the cloud velocity gradients are compared with the gradient of disk rotation. The cloud and galactic gradients are similar; the cloud rotation periods are much longer than cloud lifetimes and comparable to the galactic rotation period. The rotational kinetic energy is 1-2% of the gravitational potential energy and the cloud edge velocity is well below the escape velocity, such that cloud-scale rotation probably has little influence on the evolution of molecular clouds.

Cloud layer thicknesses from a combination of surface and upper-air observations

NASA Technical Reports Server (NTRS)

Poore, Kirk D.; Wang, Junhong; Rossow, William B.

1995-01-01

Cloud layer thicknesses are derived from base and top altitudes by combining 14 years (1975-1988) of surface and upper-air observations at 63 sites in the Northern Hemisphere. Rawinsonde observations are employed to determine the locations of cloud-layer top and base by testing for dewpoint temperature depressions below some threshold value. Surface observations serve as quality checks on the rawinsonde-determined cloud properties and provide cloud amount and cloud-type information. The dataset provides layer-cloud amount, cloud type, high, middle, or low height classes, cloud-top heights, base heights and layer thicknesses, covering a range of latitudes from 0 deg to 80 deg N. All data comes from land sites: 34 are located in continental interiors, 14 are near coasts, and 15 are on islands. The uncertainties in the derived cloud properties are discussed. For clouds classified by low-, mid-, and high-top altitudes, there are strong latitudinal and seasonal variations in the layer thickness only for high clouds. High-cloud layer thickness increases with latitude and exhibits different seasonal variations in different latitude zones: in summer, high-cloud layer thickness is a maximum in the Tropics but a minimum at high latitudes. For clouds classified into three types by base altitude or into six standard morphological types, latitudinal and seasonal variations in layer thickness are very small. The thickness of the clear surface layer decreases with latitude and reaches a summer minimum in the Tropics and summer maximum at higher latitudes over land, but does not vary much over the ocean. Tropical clouds occur in three base-altitude groups and the layer thickness of each group increases linearly with top altitude. Extratropical clouds exhibit two groups, one with layer thickness proportional to their cloud-top altitude and one with small (less than or equal to 1000 m) layer thickness independent of cloud-top altitude.

Clouds and Hazes in Saturn's Troposphere and Stratosphere

NASA Astrophysics Data System (ADS)

Merlet, Cecile; Irwin, P.; Fletcher, L.

2012-10-01

We present new results from the analysis of Saturn's near-infrared spectra measured with the Visual and Infrared Mapping Spectrometer (VIMS) instrument on the Cassini orbiter. VIMS near-infrared data are particularly relevant for the study of clouds and hazes in the troposphere and stratosphere of Saturn. Thermal emission in the 4.5-5.1 wavelength range is absorbed and scattered mainly by tropospheric clouds and radiatively active gases. The vertical structure as well as the optical and physical properties of tropospheric aerosols are obtained from Saturn's thermal emission spectra by using the retrieval algorithm Nemesis. The distribution of tropospheric phosphine and ammonia in gas phase will also be presented here. We managed to break the degeneracies inherent to the retrieval problem by analysing Saturn's thermal emission simultaneously at various viewing geometries. By using this method, we found that VIMS spectra at 4.5-5.1 microns are also sensitive to the hazes formed above the cloud layers. Saturn's reflected sunlight spectra at 0.8-3.5 microns measured with VIMS were also analysed in order to constrain the haze properties in the upper troposphere and lower stratosphere of the planet. Results from both the 0.8-3.5 and 4.5-5.1 wavelength ranges were combined to determine the cloud and haze model most consistent with VIMS spectroscopy over a wide range of viewing geometries and lighting conditions. An increase of temperature below the tropopause, often referred to as the temperature knee, was retrieved from Cassini/CIRS spectra. Seasonal variations of the knee and haze structure are compared, and as a result the assumption of local heating by the hazes to explain this feature will be discussed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Buenzli, Esther; Marley, Mark S.; Apai, Daniel

The re-emergence of the 0.99 μm FeH feature in brown dwarfs of early- to mid-T spectral type has been suggested as evidence for cloud disruption where flux from deep, hot regions below the Fe cloud deck can emerge. The same mechanism could account for color changes at the L/T transition and photometric variability. We present the first observations of spectroscopic variability of brown dwarfs covering the 0.99 μm FeH feature. We observed the spatially resolved very nearby brown dwarf binary WISE J104915.57–531906.1 (Luhman 16AB), a late-L and early-T dwarf, with Hubble Space Telescope/WFC3 in the G102 grism at 0.8–1.15 μm.more » We find significant variability at all wavelengths for both brown dwarfs, with peak-to-valley amplitudes of 9.3% for Luhman 16B and 4.5% for Luhman 16A. This represents the first unambiguous detection of variability in Luhman 16A. We estimate a rotational period between 4.5 and 5.5 hr, very similar to Luhman 16B. Variability in both components complicates the interpretation of spatially unresolved observations. The probability for finding large amplitude variability in any two brown dwarfs is less than 10%. Our finding may suggest that a common but yet unknown feature of the binary is important for the occurrence of variability. For both objects, the amplitude is nearly constant at all wavelengths except in the deep K i feature below 0.84 μm. No variations are seen across the 0.99 μm FeH feature. The observations lend strong further support to cloud height variations rather than holes in the silicate clouds, but cannot fully rule out holes in the iron clouds. Here, we re-evaluate the diagnostic potential of the FeH feature as a tracer of cloud patchiness.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Buenzli, Esther; Marley, Mark S.; Apai, Dániel

The re-emergence of the 0.99 μm FeH feature in brown dwarfs of early- to mid-T spectral type has been suggested as evidence for cloud disruption where flux from deep, hot regions below the Fe cloud deck can emerge. The same mechanism could account for color changes at the L/T transition and photometric variability. We present the first observations of spectroscopic variability of brown dwarfs covering the 0.99 μm FeH feature. We observed the spatially resolved very nearby brown dwarf binary WISE J104915.57–531906.1 (Luhman 16AB), a late-L and early-T dwarf, with Hubble Space Telescope/WFC3 in the G102 grism at 0.8–1.15 μm.more » We find significant variability at all wavelengths for both brown dwarfs, with peak-to-valley amplitudes of 9.3% for Luhman 16B and 4.5% for Luhman 16A. This represents the first unambiguous detection of variability in Luhman 16A. We estimate a rotational period between 4.5 and 5.5 hr, very similar to Luhman 16B. Variability in both components complicates the interpretation of spatially unresolved observations. The probability for finding large amplitude variability in any two brown dwarfs is less than 10%. Our finding may suggest that a common but yet unknown feature of the binary is important for the occurrence of variability. For both objects, the amplitude is nearly constant at all wavelengths except in the deep K i feature below 0.84 μm. No variations are seen across the 0.99 μm FeH feature. The observations lend strong further support to cloud height variations rather than holes in the silicate clouds, but cannot fully rule out holes in the iron clouds. We re-evaluate the diagnostic potential of the FeH feature as a tracer of cloud patchiness.« less

Assessing cloud radiative effects on tropospheric photolysis rates and key oxidants during aircraft campaigns using satellite cloud observations and a global chemical transport model

NASA Astrophysics Data System (ADS)

Zhang, B.; Liu, H.; Crawford, J. H.; Chen, G.; Voulgarakis, A.; Fairlie, T. D.; Duncan, B. N.; Ham, S. H.; Kato, S.; Payer Sulprizio, M.; Yantosca, R.

2017-12-01

Clouds affect tropospheric photochemistry through modifying solar radiation that determines photolysis rates. Observational and modeling studies have indicated that photolysis rates are enhanced above and in the upper portion of cloud layers and are reduced below optically thick clouds due to their dominant backscattering effect. However, large uncertainties exist in the representation of cloud spatiotemporal (especially vertical) distributions in global models, which makes understanding of cloud radiative effects on tropospheric chemistry challenging. Our previous study using a global 3-D chemical transport model (GEOS-Chem) driven by various meteorological data sets showed that the radiative effects of clouds on photochemistry are more sensitive to the differences in the vertical distribution of clouds than to those in the magnitude of column cloud optical depths. In this work, we evaluate monthly mean cloud optical properties and distributions in the MERRA-2 reanalysis with those in C3M, a 3-D cloud data product developed at NASA Langley Research Center and merged from multiple A-Train satellite (CERES, CloudSat, CALIPSO, and MODIS) observations. We conduct tropospheric chemistry simulations for the periods of several aircraft campaigns, including ARCTAS (April, June-July, 2008), DC3 (May-June, 2012), and SEAC4RS (August-September, 2013) with GEOS-Chem driven by MERRA-2. We compare model simulations with and without constraints of cloud optical properties and distributions from C3M, and evaluate model photolysis rates (J[O1D] and J[NO2]) and key oxidants (e.g., OH and ozone) with aircraft profile measurements. We will assess whether the constraints provided by C3M improve model simulations of photolysis rates and oxidants as well as their variabilities.

The Impact of Aerosols on Cloud and Precipitation Processes: Cloud-Resolving Model Simulations

NASA Technical Reports Server (NTRS)

Tao, Wei-Kuo; Li, X.; Khain, A.; Simpson, S.

2004-01-01

Cloud microphysics are inevitably affected by the smoke particle (CCN, cloud condensation nuclei) size distributions below the clouds. Therefore, size distributions parameterized as spectral bin microphysics are needed to explicitly study the effects of atmospheric aerosol concentration on cloud development, rainfall production, and rainfall rates for convective clouds. Recently, two detailed spectral-bin microphysical schemes were implemented into the Goddard Cumulus Ensemble (GCE) model. The formulation for the explicit spectral-bin microphysical processes is based on solving stochastic kinetic equations for the size distribution functions of water droplets (i.e., cloud droplets and raindrops), and several types of ice particles (i.e., pristine ice crystals (columnar and plate-like), snow (dendrites and aggregates), graupel and frozen drops/hail). Each type is described by a special size distribution function containing many categories (i.e. 33 bins). Atmospheric aerosols are also described using number density size-distribution functions. A spectral-bin microphysical model is very expensive from a computational point of view and has only been implemented into the 2D version of the GCE at the present time. The model is tested by studying the evolution of deep cloud systems in the west Pacific warm pool region, in the sub-tropics (Florida) and in the mid-latitude using identical thermodynamic conditions but with different concentrations of CCN: a low 'clean' concentration and a high 'dirty' concentration.

Short wavelength abedo, contrasts and micro-organisms on Venus

NASA Astrophysics Data System (ADS)

Limaye, Sanjay; Słowik, Grzegorgz; Ansari, Arif; Smith, David; Mogul, Rakesh; Vaishampayan, Parag

2017-04-01

The decrease in the amount of sunlight reflected by Venus at wavelengths below 500 nm, and the presence of contrast features prominent at ultraviolet wavelengths (270 - 410 nm) are two properties of the Venus clouds that despite numerous attempts, remain unexplained. Additional uncertainties include why the contrasts exist at all, and why the substance responsible for the contrasts does not appear well mixed. Nearly a century after the ultraviolet contrasts were discovered using Earth-based photographs, the substance or mechanisms responsible for the lower albedo and contrast patterns are still unknown. Many physical and chemical explanations have been proposed, but none of the hypotheses explain decrease of albedo below 500 nm, the spectral dependence of contrasts, and plausible mechanisms for presence or transport of those substances - transport from surface if the absorber is a condensation nuclei or transformations if in dissolved form due to photochemistry and the observed rapid changes in the contrasts. Considering the ultraviolet absorption shown by some terrestrial microorganisms, we speculate whether airborne bacteria (indigenous or introduced through meteoritic impact debris transported from Earth) could explain the mysterious contrast or the absorption cloud features on Venus. Plumes of cloud-borne aeroplankton, analogous to phytoplankton in Earth's oceans which are in dense enough concentrations to be observed from space, may have evolved on Venus when the planet had liquid water on its early surface, eventually migrating to a habitable zone in the clouds 50-70 km above the inhospitably hot surface today.

Quantification of trace elements and speciation of iron in atmospheric particulate matter

NASA Astrophysics Data System (ADS)

Upadhyay, Nabin

Trace metal species play important roles in atmospheric redox processes and in the generation of oxidants in cloud systems. The chemical impact of these elements on atmospheric and cloud chemistry is dependent on their occurrence, solubility and speciation. First, analytical protocols have been developed to determine trace elements in particulate matter samples collected for carbonaceous analysis. The validated novel protocols were applied to the determination of trace elements in particulate samples collected in the remote marine atmosphere and urban areas in Arizona to study air pollution issues. The second part of this work investigates on solubility and speciation in environmental samples. A detailed study on the impact of the nature and strength of buffer solutions on solubility and speciation of iron lead to a robust protocol, allowing for comparative measurements in matrices representative of cloud water conditions. Application of this protocol to samples from different environments showed low iron solubility (less than 1%) in dust-impacted events and higher solubility (5%) in anthropogenically impacted urban samples. In most cases, Fe(II) was the dominant oxidation state in the soluble fraction of iron. The analytical protocol was then applied to investigate iron processing by fogs. Field observations showed that only a small fraction (1%) of iron was scavenged by fog droplets for which each of the soluble and insoluble fraction were similar. A coarse time resolution limited detailed insights into redox cycling within fog system. Overall results suggested that the major iron species in the droplets was Fe(1I) (80% of soluble iron). Finally, the occurrence and sources of emerging organic pollutants in the urban atmosphere were investigated. Synthetic musk species are ubiquitous in the urban environment (less than 5 ng m-3) and investigations at wastewater treatment plants showed that wastewater aeration basins emit a substantial amount of these species to the atmosphere.

Trans-Pacific transport of Asian dust: the CESM model analysis and comparison with satellite observations

NASA Astrophysics Data System (ADS)

Wu, M.; Liu, X.; Luo, T.; Wang, Z.; Yang, K.; Wu, C.; Wang, H.; Zhang, K.

2017-12-01

Mineral dust plays an important role in the Earth's climate system due to its effects on radiation budgets, clouds, chemistry and biosphere. However, modeled dust aerosol is not well constrained and large uncertainties exist in modeled dust lifecycles. We evaluate dust spatial distributions in the Community Earth System Model (CESM) with new dust extinction retrievals (Luo et al., 2015a, b) based on the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite (CALIPSO) and CloudSat measurement, with special focus on the Asian dust transport across the Pacific. It is shown that the default CESM underestimates the dust extinction over the Pacific by 1-2 order of magnitude. Especially, the model fails to capture the observed high values of dust extinction occurring from 850 to 500 hPa across the North Pacific (20°N-50°N). Modeled dust optical depth (DOD) decreases faster across the Pacific compared to the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Multi-angle Imaging SpectroRadiometer (MISR) observations. Sensitivity experiments with altered emission, vertical transport and deposition schemes have been conducted to identify the key process impacting dust transport. For that purpose, two new dust emission schemes by Kok et al. (2014a, b) and Ginoux et al. (2001), a new dry deposition scheme by Petroff and Zhang (2010) are implemented to the CESM. In addition, a new unified scheme for convective transport and wet removal of aerosols (Wang et al., 2013) is implemented to the same version of CESM to examine the influence of convective transport and wet deposition on dust transport. It is found that changes in wet scavenging and convective transport can strongly impact dust transport over the Pacific compared to changes in other processes. One of the new emission schemes further decreases the dust extinction across the Pacific. Dust extinction across the Pacific slightly increases when dry deposition velocity for fine particles is reduced.

A comparison between CloudSat and aircraft data for a multilayer, mixed phase cloud system during the Canadian CloudSat-CALIPSO Validation Project

NASA Astrophysics Data System (ADS)

Barker, H. W.; Korolev, A. V.; Hudak, D. R.; Strapp, J. W.; Strawbridge, K. B.; Wolde, M.

2008-04-01

Reflectivities recorded by the W-band Cloud Profiling Radar (CPR) aboard NASA's CloudSat satellite and some of CloudSat's retrieval products are compared to Ka-band radar reflectivities and in situ cloud properties gathered by instrumentation on the NRC's Convair-580 aircraft. On 20 February 2007, the Convair flew several transects along a 60 nautical mile stretch of CloudSat's afternoon ground track over southern Quebec. On one of the transects it was well within CloudSat's radar's footprint while in situ sampling a mixed phase boundary layer cloud. A cirrus cloud was also sampled before and after overpass. Air temperature and humidity profiles from ECMWF reanalyses, as employed in CloudSat's retrieval stream, agree very well with those measured by the Convair. The boundary layer cloud was clearly visible, to the eye and lidar, and dominated the region's solar radiation budget. It was, however, often below or near the Ka-band's distance-dependent minimum detectable signal. In situ samples at overpass revealed it to be composed primarily of small, supercooled droplets at the south end and increasingly intermixed with ice northward. Convair and CloudSat CPR reflectivities for the low cloud agree well, but while CloudSat properly ascribed it as overcast, mixed phase, and mostly liquid near the south end, its estimates of liquid water content LWC (and visible extinction coefficient κ) and droplet effective radii are too small and large, respectively. The cirrus consisted largely of irregular crystals with typical effective radii ˜150 μm. While both CPR reflectivities agree nicely, CloudSat's estimates of crystal number concentrations are too large by a factor of 5. Nevertheless, distributions of ice water content and κ deduced from in situ data agree quite well with values retrieved from CloudSat algorithms.

Simulations of the Vertical Redistribution of HNO3 by NAT or NAD PSCs: The Sensitivity to the Number of Cloud Particles Formed and the Cloud Lifetime

NASA Technical Reports Server (NTRS)

Jensen, Eric J.; Tabazadeh, Azadeh; Drdla, Katja; Toon, Owen B.; Gore, Warren J. (Technical Monitor)

2000-01-01

Recent satellite and in situ measurements have indicated that limited denitrification can occur in the Arctic stratosphere. In situ measurements from the SOLVE campaign indicate polar stratospheric clouds (PSCs) composed of small numbers (about 3 x 10^ -4 cm^-3) of 10-20 micron particles (probably NAT or NAD). These observations raise the issue of whether low number density NAT PSCs can substantially denitrify the air with reasonable cloud lifetimes. In this study, we use a one dimensional cloud model to investigate the verticle redistribution of HNO3 by NAT/NAD PSCs. The cloud formation is driven by a temperature oscillation which drops the temperature below the NAT/NAD formation threshold (about 195 K) for a few days. We assume that a small fraction of the available aerosols act as NAT nuclei when the saturation ratio of HNO3 over NAT(NAD) exceeds 10(l.5). The result is a cloud between about 16 and 20 km in the model, with NAT/NAD particle effective radii as large as about 10 microns (in agreement with the SOLVE data). We find that for typical cloud lifetimes of 2-3 days or less, the net depletion of HNO3 is no more than 1-2 ppbv, regardless of the NAT or NAD particle number density. Repeated passes of the air column through the cold pool build up the denitrification to 3-4 ppbv, and the cloud altitude steadily decreases due to the downward transport of nitric acid. Increasing the cloud lifetime results in considerably more effective denitrification, even with very low cloud particle number densities. As expected, the degree of denitrification by NAT clouds is much larger than that by NAD Clouds. Significant denitrification by NAD Clouds is only possible if the cloud lifetime is several days or more. The clouds also cause a local maximum HNO3 mixing ratio at cloud base where the cloud particles sublimate.

Cloud structure of the nearest brown dwarfs. II: High-amplitude variability for Luhman 16 A and B in and out of the 0.99 μm FeH feature

DOE PAGES

Buenzli, Esther; Marley, Mark S.; Apai, Daniel; ...

2015-10-20

The re-emergence of the 0.99 μm FeH feature in brown dwarfs of early- to mid-T spectral type has been suggested as evidence for cloud disruption where flux from deep, hot regions below the Fe cloud deck can emerge. The same mechanism could account for color changes at the L/T transition and photometric variability. We present the first observations of spectroscopic variability of brown dwarfs covering the 0.99 μm FeH feature. We observed the spatially resolved very nearby brown dwarf binary WISE J104915.57–531906.1 (Luhman 16AB), a late-L and early-T dwarf, with Hubble Space Telescope/WFC3 in the G102 grism at 0.8–1.15 μm.more » We find significant variability at all wavelengths for both brown dwarfs, with peak-to-valley amplitudes of 9.3% for Luhman 16B and 4.5% for Luhman 16A. This represents the first unambiguous detection of variability in Luhman 16A. We estimate a rotational period between 4.5 and 5.5 hr, very similar to Luhman 16B. Variability in both components complicates the interpretation of spatially unresolved observations. The probability for finding large amplitude variability in any two brown dwarfs is less than 10%. Our finding may suggest that a common but yet unknown feature of the binary is important for the occurrence of variability. For both objects, the amplitude is nearly constant at all wavelengths except in the deep K i feature below 0.84 μm. No variations are seen across the 0.99 μm FeH feature. The observations lend strong further support to cloud height variations rather than holes in the silicate clouds, but cannot fully rule out holes in the iron clouds. Here, we re-evaluate the diagnostic potential of the FeH feature as a tracer of cloud patchiness.« less

The observed influence of local anthropogenic pollution on northern Alaskan cloud properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maahn, Maximilian; de Boer, Gijs; Creamean, Jessie M.

Due to their importance for the radiation budget, liquid-containing clouds are a key component of the Arctic climate system. Depending on season, they can cool or warm the near-surface air. The radiative properties of these clouds depend strongly on cloud drop sizes, which are governed in part by the availability of cloud condensation nuclei. Here, we investigate how cloud drop sizes are modified in the presence of local emissions from industrial facilities at the North Slope of Alaska. For this, we use aircraft in situ observations of clouds and aerosols from the 5th Department of Energy Atmospheric Radiation Measurement (DOE ARM)more » Program's Airborne Carbon Measurements (ACME-V) campaign obtained in summer 2015. Comparison of observations from an area with petroleum extraction facilities (Oliktok Point) with data from a reference area relatively free of anthropogenic sources (Utqiaġvik/Barrow) represents an opportunity to quantify the impact of local industrial emissions on cloud properties. In the presence of local industrial emissions, the mean effective radii of cloud droplets are reduced from 12.2 to 9.4 µm, which leads to suppressed drizzle production and precipitation. At the same time, concentrations of refractory black carbon and condensation nuclei are enhanced below the clouds. These results demonstrate that the effects of anthropogenic pollution on local climate need to be considered when planning Arctic industrial infrastructure in a warming environment.« less

Fragmentation of a Filamentary Cloud Permeated by a Perpendicular Magnetic Field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hanawa, Tomoyuki; Kudoh, Takahiro; Tomisaka, Kohji

We examine the linear stability of an isothermal filamentary cloud permeated by a perpendicular magnetic field. Our model cloud is assumed to be supported by gas pressure against self-gravity in the unperturbed state. For simplicity, the density distribution is assumed to be symmetric around the axis. Also for simplicity, the initial magnetic field is assumed to be uniform, and turbulence is not taken into account. The perturbation equation is formulated to be an eigenvalue problem. The growth rate is obtained as a function of the wavenumber for fragmentation along the axis and the magnetic field strength. The growth rate dependsmore » critically on the outer boundary. If the displacement vanishes in regions very far from the cloud axis (fixed boundary), cloud fragmentation is suppressed by a moderate magnetic field, which means the plasma beta is below 1.67 on the cloud axis. If the displacement is constant along the magnetic field in regions very far from the cloud, the cloud is unstable even when the magnetic field is infinitely strong. The cloud is deformed by circulation in the plane perpendicular to the magnetic field. The unstable mode is not likely to induce dynamical collapse, since it is excited even when the whole cloud is magnetically subcritical. For both boundary conditions, the magnetic field increases the wavelength of the most unstable mode. We find that the magnetic force suppresses compression perpendicular to the magnetic field especially in regions of low density.« less

The observed influence of local anthropogenic pollution on northern Alaskan cloud properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maahn, Maximilian; de Boer, Gijs; Creamean, Jessie M.

Due to their importance for the radiation budget, liquid-containing clouds are a key component of the Arctic climate system. Depending on season, they can cool or warm the near-surface air. The radiative properties of these clouds depend strongly on cloud drop sizes, which are governed in part by the availability of cloud condensation nuclei. Here, we investigate how cloud drop sizes are modified in the presence of local emissions from industrial facilities at the North Slope of Alaska. For this, we use aircraft in situ observations of clouds and aerosols from the 5th Department of Energy Atmospheric Radiation Measurement (DOE ARM)more » Program's Airborne Carbon Measurements (ACME-V) campaign obtained in summer 2015. Comparison of observations from an area with petroleum extraction facilities (Oliktok Point) with data from a reference area relatively free of anthropogenic sources (Utqiagvik/Barrow) represents an opportunity to quantify the impact of local industrial emissions on cloud properties. In the presence of local industrial emissions, the mean effective radii of cloud droplets are reduced from 12.2 to 9.4 µm, which leads to suppressed drizzle production and precipitation. At the same time, concentrations of refractory black carbon and condensation nuclei are enhanced below the clouds. These results demonstrate that the effects of anthropogenic pollution on local climate need to be considered when planning Arctic industrial infrastructure in a warming environment.« less

Cloud remote sensing from space in the era of the A-Train

NASA Astrophysics Data System (ADS)

Stephens, Graeme L.; Vane, Deborah G.

2006-09-01

The clouds of Earth are fundamental to most aspects of human life. Through production of precipitation, they are essential for delivering and sustaining the supplies of fresh water upon which human life depends. Clouds further exert a principal influence on the planet's energy balance. It is in clouds that latent heat is released through the process of condensation and the formation of precipitation affecting the development and evolution of the planet's storm systems. Clouds further exert a profound influence on the solar and infrared radiation that enters and leaves the atmosphere, further exerting profound effects on climate and on forces that affect climate change (Stephens, 2005). It is for these reasons, among others, that the need to observe the distribution and variability of the properties of clouds and precipitation has emerged as a priority in Earth observations. Most past and current observational programs are contructed in such a way that clouds and precipitation are treated as separate entities. Nature does not work this way and there is much to be gained scientifically in moving away from these artificial practices toward observing clouds and precipitation properties jointly. We are now embarking on a new age of remote sensing of clouds and precipitation using active sensors, starting with the tropical rainfall measurement mission (TRMM) and continuing on with the A-Train (described below). This new age provides us with the opportunity to move away from past and present artificial observing practices offering a more unified approach to observing clouds and precipitation properties jointly.

The observed influence of local anthropogenic pollution on northern Alaskan cloud properties

DOE PAGES

Maahn, Maximilian; de Boer, Gijs; Creamean, Jessie M.; ...

2017-12-11

Due to their importance for the radiation budget, liquid-containing clouds are a key component of the Arctic climate system. Depending on season, they can cool or warm the near-surface air. The radiative properties of these clouds depend strongly on cloud drop sizes, which are governed in part by the availability of cloud condensation nuclei. Here, we investigate how cloud drop sizes are modified in the presence of local emissions from industrial facilities at the North Slope of Alaska. For this, we use aircraft in situ observations of clouds and aerosols from the 5th Department of Energy Atmospheric Radiation Measurement (DOE ARM)more » Program's Airborne Carbon Measurements (ACME-V) campaign obtained in summer 2015. Comparison of observations from an area with petroleum extraction facilities (Oliktok Point) with data from a reference area relatively free of anthropogenic sources (Utqiagvik/Barrow) represents an opportunity to quantify the impact of local industrial emissions on cloud properties. In the presence of local industrial emissions, the mean effective radii of cloud droplets are reduced from 12.2 to 9.4 µm, which leads to suppressed drizzle production and precipitation. At the same time, concentrations of refractory black carbon and condensation nuclei are enhanced below the clouds. These results demonstrate that the effects of anthropogenic pollution on local climate need to be considered when planning Arctic industrial infrastructure in a warming environment.« less

3.6 cm signal attenuation in Venus' lower and middle atmosphere observed by the Radio Science experiment VeRa onboard Venus Express

NASA Astrophysics Data System (ADS)

Oschlisniok, J.; Tellmann, S.; Pätzold, M.; Häusler, B.; Andert, T.; Bird, M.; Remus, S.

2012-09-01

The planet Venus is shrouded within a roughly 20 km thick cloud layer, which extends from the lower to the middle atmosphere (ca. 50 - 70 km). While the clouds are mostly composed of sulfuric acid droplets, a haze layer of sulfuric acid vapor exists below the clouds. Within the cloud and the sub - cloud region Radio signal strength variations (intensity scintillations) caused by atmospheric waves and a decrease in the signal intensity caused by absorption by H2SO4 are observed by radio occultation experiments. The Venus Express spacecraft is orbiting Venus since 2006. The Radio Science Experiment VeRa probes the atmosphere with radio signals at 3.6 cm (XBand) and 13 cm (S-Band) wavelengths. The disturbance of the radio signal intensity is used to investigate the cloud region with respect to atmospheric waves. The absorption of the signal is used to determine the abundance of H2SO4 near the cloud base. This way a detailed study of the H2SO4 abundance within the cloud and sub - cloud region is possible. Results from the intensity scintillations within the cloud deck are presented and compared with gravity wave studies based on temperature variations inferred from VeRa soundings. Vertical absorptivity profiles and resulting sulfuric acid vapor profiles are presented and compared with previous missions. A distinct latitudinal dependence and a southern northern symmetry are clearly visible.

ERBE S10N WFOV SF Edition 2

Atmospheric Science Data Center

2016-06-09

... warming caused by greenhouse gases. Absorption of Solar Radiation by Clouds The results of the study demonstrate the present ... spacecraft, as described below. WFOV Instruments: these two fixed detectors continuously view the earth disc (plus a small ring of ...

ERBE S10N WFOV NF Edition 3

Atmospheric Science Data Center

2016-06-09

... warming caused by greenhouse gases. Absorption of Solar Radiation by Clouds The results of the study demonstrate the present ... spacecraft, as described below. WFOV Instruments: these two fixed detectors continuously view the earth disc (plus a small ring of ...

ERBE S10N WFOV NF Edition 2

Atmospheric Science Data Center

2016-06-08

... warming caused by greenhouse gases. Absorption of Solar Radiation by Clouds The results of the study demonstrate the present ... spacecraft, as described below. WFOV Instruments: these two fixed detectors continuously view the earth disc (plus a small ring of ...

ERBE S10N WFOV SF Edition 3

Atmospheric Science Data Center

2016-06-09

... warming caused by greenhouse gases. Absorption of Solar Radiation by Clouds The results of the study demonstrate the present ... spacecraft, as described below. WFOV Instruments: these two fixed detectors continuously view the earth disc (plus a small ring of ...

Classification of Arctic, Mid-Latitude and Tropical Clouds in the Mixed-Phase Temperature Regime

NASA Astrophysics Data System (ADS)

Costa, Anja; Afchine, Armin; Luebke, Anna; Meyer, Jessica; Dorsey, James R.; Gallagher, Martin W.; Ehrlich, André; Wendisch, Manfred; Krämer, Martina

2016-04-01

The degree of glaciation and the sizes and habits of ice particles formed in mixed-phase clouds remain not fully understood. However, these properties define the mixed clouds' radiative impact on the Earth's climate and thus a correct representation of this cloud type in global climate models is of importance for an improved certainty of climate predictions. This study focuses on the occurrence and characteristics of two types of clouds in the mixed-phase temperature regime (238-275K): coexistence clouds (Coex), in which both liquid drops and ice crystals exist, and fully glaciated clouds that develop in the Wegener-Bergeron-Findeisen regime (WBF clouds). We present an extensive dataset obtained by the Cloud and Aerosol Particle Spectrometer NIXE-CAPS, covering Arctic, mid-latitude and tropical regions. In total, we spent 45.2 hours within clouds in the mixed-phase temperature regime during five field campaigns (Arctic: VERDI, 2012 and RACEPAC, 2014 - Northern Canada; mid-latitude: COALESC, 2011 - UK and ML-Cirrus, 2014 - central Europe; tropics: ACRIDICON, 2014 - Brazil). We show that WBF and Coex clouds can be identified via cloud particle size distributions. The classified datasets are used to analyse temperature dependences of both cloud types as well as range and frequencies of cloud particle concentrations and sizes. One result is that Coex clouds containing supercooled liquid drops are found down to temperatures of -40 deg C only in tropical mixed clouds, while in the Arctic and mid-latitudes no liquid drops are observed below about -20 deg C. In addition, we show that the cloud particles' aspherical fractions - derived from polarization signatures of particles with diameters between 20 and 50 micrometers - differ significantly between WBF and Coex clouds. In Coex clouds, the aspherical fraction of cloud particles is generally very low, but increases with decreasing temperature. In WBF clouds, where all cloud particles are ice, about 20-40% of the cloud particles are nevertheless classified as spherical for all temperatures, possibly indicating columnar ice crystals (see Järvinen et al, submitted to JAS 2016).

Cloud vertical distribution from combined surface and space radar-lidar observations at two Arctic atmospheric observatories

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Yinghui; Shupe, Matthew D.; Wang, Zhien

Detailed and accurate vertical distributions of cloud properties (such as cloud fraction, cloud phase, and cloud water content) and their changes are essential to accurately calculate the surface radiative flux and to depict the mean climate state. Surface and space-based active sensors including radar and lidar are ideal to provide this information because of their superior capability to detect clouds and retrieve cloud microphysical properties. In this study, we compare the annual cycles of cloud property vertical distributions from space-based active sensors and surface-based active sensors at two Arctic atmospheric observatories, Barrow and Eureka. Based on the comparisons, we identifymore » the sensors' respective strengths and limitations, and develop a blended cloud property vertical distribution by combining both sets of observations. Results show that surface-based observations offer a more complete cloud property vertical distribution from the surface up to 11 km above mean sea level (a.m.s.l.) with limitations in the middle and high altitudes; the annual mean total cloud fraction from space-based observations shows 25-40 % fewer clouds below 0.5 km than from surface-based observations, and space-based observations also show much fewer ice clouds and mixed-phase clouds, and slightly more liquid clouds, from the surface to 1 km. In general, space-based observations show comparable cloud fractions between 1 and 2 km a.m.s.l., and larger cloud fractions above 2 km a.m.s.l. than from surface-based observations. A blended product combines the strengths of both products to provide a more reliable annual cycle of cloud property vertical distributions from the surface to 11 km a.m.s.l. This information can be valuable for deriving an accurate surface radiative budget in the Arctic and for cloud parameterization evaluation in weather and climate models. Cloud annual cycles show similar evolutions in total cloud fraction and ice cloud fraction, and lower liquid-containing cloud fraction at Eureka than at Barrow; the differences can be attributed to the generally colder and drier conditions at Eureka relative to Barrow.« less

Evaluating stratiform cloud base charge remotely

NASA Astrophysics Data System (ADS)

Harrison, R. Giles; Nicoll, Keri A.; Aplin, Karen L.

2017-06-01

Stratiform clouds acquire charge at their upper and lower horizontal boundaries due to vertical current flow in the global electric circuit. Cloud charge is expected to influence microphysical processes, but understanding is restricted by the infrequent in situ measurements available. For stratiform cloud bases below 1 km in altitude, the cloud base charge modifies the surface electric field beneath, allowing a new method of remote determination. Combining continuous cloud height data during 2015-2016 from a laser ceilometer with electric field mill data, cloud base charge is derived using a horizontal charged disk model. The median daily cloud base charge density found was -0.86 nC m-2 from 43 days' data. This is consistent with a uniformly charged region 40 m thick at the cloud base, now confirming that negative cloud base charge is a common feature of terrestrial layer clouds. This technique can also be applied to planetary atmospheres and volcanic plumes.