GREEN CHEMISTRY AND ENGINEERING RESEARCH AT THE USEPA, NRMRL

EPA Science Inventory

The costs of handling, treating and disposing of wastes generated annually in the U.S. has reach to 2.2% of gross domestic product and continued to rise. The chemical manufacturing industry generates more than 1.5 billion tons of hazardous waste and 9 billion tons of non-hazardou...

In situ carbonation of peridotite for CO2 storage

PubMed Central

Kelemen, Peter B.; Matter, Jürg

2008-01-01

The rate of natural carbonation of tectonically exposed mantle peridotite during weathering and low-temperature alteration can be enhanced to develop a significant sink for atmospheric CO2. Natural carbonation of peridotite in the Samail ophiolite, an uplifted slice of oceanic crust and upper mantle in the Sultanate of Oman, is surprisingly rapid. Carbonate veins in mantle peridotite in Oman have an average 14C age of ≈26,000 years, and are not 30–95 million years old as previously believed. These data and reconnaissance mapping show that ≈104 to 105 tons per year of atmospheric CO2 are converted to solid carbonate minerals via peridotite weathering in Oman. Peridotite carbonation can be accelerated via drilling, hydraulic fracture, input of purified CO2 at elevated pressure, and, in particular, increased temperature at depth. After an initial heating step, CO2 pumped at 25 or 30 °C can be heated by exothermic carbonation reactions that sustain high temperature and rapid reaction rates at depth with little expenditure of energy. In situ carbonation of peridotite could consume >1 billion tons of CO2 per year in Oman alone, affording a low-cost, safe, and permanent method to capture and store atmospheric CO2.

Projections of highway vehicle population, energy demand, and CO{sub 2} emissions in India through 2040.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arora, S.; Vyas, A.; Johnson, L.

2011-02-22

This paper presents projections of motor vehicles, oil demand, and carbon dioxide (CO{sub 2}) emissions for India through the year 2040. The populations of highway vehicles and two-wheelers are projected under three different scenarios on the basis of economic growth and average household size in India. The results show that by 2040, the number of highway vehicles in India would be 206-309 million. The oil demand projections for the Indian transportation sector are based on a set of nine scenarios arising out of three vehicle-growth and three fuel-economy scenarios. The combined effects of vehicle-growth and fuel-economy scenarios, together with themore » change in annual vehicle usage, result in a projected demand in 2040 by the transportation sector in India of 404-719 million metric tons (8.5-15.1 million barrels per day). The corresponding annual CO{sub 2} emissions are projected to be 1.2-2.2 billion metric tons.« less

Assessing ocean alkalinity for carbon sequestration

NASA Astrophysics Data System (ADS)

Renforth, Phil; Henderson, Gideon

2017-09-01

Over the coming century humanity may need to find reservoirs to store several trillions of tons of carbon dioxide (CO2) emitted from fossil fuel combustion, which would otherwise cause dangerous climate change if it were left in the atmosphere. Carbon storage in the ocean as bicarbonate ions (by increasing ocean alkalinity) has received very little attention. Yet recent work suggests sufficient capacity to sequester copious quantities of CO2. It may be possible to sequester hundreds of billions to trillions of tons of C without surpassing postindustrial average carbonate saturation states in the surface ocean. When globally distributed, the impact of elevated alkalinity is potentially small and may help ameliorate the effects of ocean acidification. However, the local impact around addition sites may be more acute but is specific to the mineral and technology. The alkalinity of the ocean increases naturally because of rock weathering in which >1.5 mol of carbon are removed from the atmosphere for every mole of magnesium or calcium dissolved from silicate minerals (e.g., wollastonite, olivine, and anorthite) and 0.5 mol for carbonate minerals (e.g., calcite and dolomite). These processes are responsible for naturally sequestering 0.5 billion tons of CO2 per year. Alkalinity is reduced in the ocean through carbonate mineral precipitation, which is almost exclusively formed from biological activity. Most of the previous work on the biological response to changes in carbonate chemistry have focused on acidifying conditions. More research is required to understand carbonate precipitation at elevated alkalinity to constrain the longevity of carbon storage. A range of technologies have been proposed to increase ocean alkalinity (accelerated weathering of limestone, enhanced weathering, electrochemical promoted weathering, and ocean liming), the cost of which may be comparable to alternative carbon sequestration proposals (e.g., $20-100 tCO2-1). There are still many unanswered technical, environmental, social, and ethical questions, but the scale of the carbon sequestration challenge warrants research to address these.

Energy resources of the United States

USGS Publications Warehouse

Theobald, P.K.; Schweinfurth, Stanley P.; Duncan, Donald Cave

1972-01-01

Estimates are made of United States resources of coal, petroleum liquids, natural gas, uranium, geothermal energy, and oil from oil shale. The estimates, compiled by specialists of the U.S. Geological Survey, are generally made on geologic projections of favorable rocks and on anticipated frequency of the energy resource in the favorable rocks. Accuracy of the estimates probably ranges from 20 to 50 percent for identified-recoverable resources to about an order of magnitude for undiscovered-submarginal resources. The total coal resource base in the United States is estimated to be about 3,200 billion tons, of which 200-390 billion tons can be considered in the category identified and recoverable. More than 70 percent of current production comes from the Appalachian basin where the resource base, better known than for the United States as a whole, is about 330 billion tons, of which 22 billion tons is identified and recoverable. Coals containing less than 1 percent sulfur are the premium coals. These are abundant in the western coal fields, but in the Appalachian basin the resource base for low-sulfur coal is estimated to be only a little more than 100 billion tons, of which 12 billion tons is identified and recoverable. Of the many estimates of petroleum liquids and natural-gas resources, those of the U.S. Geological Survey are the largest because, in general, our estimates include the largest proportion of favorable ground for exploration. We estimate the total resource base for petroleum liquids to be about 2,900 billion barrels, of which 52 billion barrels is identified and recoverable. Of the total resource base, some 600 billion barrels is in Alaska or offshore from Alaska, 1,500 billion barrels is offshore from the United States, and 1,300 billion barrels is onshore in the conterminous United States. Identified-recoverable resources of petroleum liquids corresponding to these geographic units are 11, 6, and 36 billion barrels, respectively. The total natural-gas resource of the United States is estimated to be about 6,600 trillion cubic feet, of which 290 trillion cubic feet is identified and recoverable. In geographic units comparable to those for petroleum liquids, the resource bases are 1,400, 3,400, and 2,900 trillion cubic feet, and the identified-recoverable resources are 31, 40, and 220 trillion cubic feet, respectively. Uranium resources in conventional deposits, where uranium is the major product, are estimated at 1,600,000 tons of U3O8, of which 250,000 tons is identified and recoverable. A potential byproduct resource of more than 7 million tons of U3O8, is estimated for phosphate rock, but none of this resource is recoverable under present economic conditions. The resources of heat in potential geothermal energy sources are poorly known. The total resource base for the United States is certainly greater than 10 22 calories, of which only 2.5 ? 10 18 calories can be considered identified and recoverable at present. Oil shale is estimated to contain 26 trillion barrels of oil. None of this resource is economic at present, but if prices increase moderately, 160-600 billion barrels of this oil could be shifted into the identified-recoverable category.

Potential for reducing air pollution from oil refineries.

PubMed

Karbassi, A R; Abbasspour, M; Sekhavatjou, M S; Ziviyar, F; Saeedi, M

2008-10-01

Islamic Republic of Iran has to invest 95 billion US$ for her new oil refineries to the year 2045. At present, the emission factors for CO(2), NO( x ) and SO(2) are 3.5, 4.2 and 119 times higher than British refineries, respectively. In order to have a sustainable development in Iranian oil refineries, the government has to set emission factors of European Community as her goal. At present CO(2) per Gross Domestic Production (GDP) in the country is about 2.7 kg CO(2) as 1995's USD value that should be reduced to 1.25 kg CO(2)/GDP in the year 2015. Total capital investment for such reduction is estimated at 346 million USD which is equal to 23 USD/ton of CO(2). It is evident that mitigation of funds set by Clean Development Mechanism (3 to 7 USD/tons of CO(2)) is well below the actual capital investment needs. Present survey shows that energy efficiency promotion potential in all nine Iranian oil refineries is about 165,677 MWh/year through utilization of more efficient pumps and compressors. Better management of boilers in all nine refineries will lead to a saving of 273 million m(3) of natural gas per year.

Stabilization Wedges and the Management of Global Carbon for the next 50 years

ScienceCinema

Socolow, Robert

2018-05-24

More than 40 years after receiving a Ph.D. in physics, I am still working on problems where conservation laws matter. In particular, for the problems I work on now, the conservation of the carbon atom matters. I will tell the saga of an annual flow of 8 billion tons of carbon associated with the global extraction of fossil fuels from underground. Until recently, it was taken for granted that virtually all of this carbon will move within weeks through engines of various kinds and then into the atmosphere. For compelling environmental reasons, I and many others are challenging this complacent view, asking whether the carbon might wisely be directed elsewhere. To frame this and similar discussions, Steve Pacala and I introduced the 'stabilization wedge' in 2004 as a useful unit for discussing climate stabilization. Updating the definition, a wedge is the reduction of CO2 emissions by one billion tons of carbon per year in 2057, achieved by any strategy generated as a result of deliberate attention to global carbon. Each strategy uses already commercialized technology, generally at much larger scale than today. Implementing seven wedges should enable the world to achieve the interim goal of emitting no more CO2 globally in 2057 than today. This would place humanity, approximately, on a path to stabilizing CO2 at less than double the pre-industrial concentration, and it would put those at the helm in the following 50 years in a position to drive CO2 emissions to a net of zero in the following 50 years. Arguably, the tasks of the two half-centuries are comparably difficult.

Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Maine (Fact Sheet)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

2008-10-01

The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Maine. Although construction and operation of 1000 MW of wind power is a significant effort, six states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in Maine to be $1.3 billion, annual CO2 reductions are estimated at 2.8 million tons, and annual water savings are 1,387 million gallons.

Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Wisconsin (Fact Sheet)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

2008-10-01

The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Wisconsin. Although construction and operation of 1000 MW of wind power is a significant effort, six states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in Wisconsin to be $1.1 billion, annual CO2 reductions are estimated at 3.2 million tons, and annual water savings are 1,476 million gallons.

The automobile share

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fiala, E.

1996-12-31

Out of a conversion of 120 billions metric tons of fossil carbon per year 1 billion are traffic related. But this amount is growing steadily. The global automobile density is about 10 automobiles per capita. It grows with 1.7% per year, as fast as the population. The number of automobiles doubles in 25 years. In all groups of developed countries the automobile density increased from 5 to 50 automobiles per capita in less than 50 years so far. Where is the fuel for the 1 billion automobiles of the year 2030 or 2050? Can one reduce this number or whatmore » chances does one have to reduce the adverse consequences? Whatever the number of motor vehicles will be, man will have the chance to reduce fuel consumption and therefore CO{sub 2}-emission together with other emissions considerably.« less

Demonstrated reserve base for coal in New Mexico. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hoffman, G.K.

1995-02-01

The new demonstrated reserve base estimate of coal for the San Juan Basin, New Mexico, is 11.28 billion short tons. This compares with 4.429 billion short tons in the Energy Information Administration`s demonstrated reserve base of coal as of January 1, 1992 for all of New Mexico and 2.806 billion short tons for the San Juan Basin. The new estimate includes revised resource calculations in the San Juan Basin, in San Juan, McKinley, Sandoval, Rio Arriba, Bernalillo and Cibola counties, but does not include the Raton Basin and smaller fields in New Mexico. These estimated {open_quotes}remaining{close_quotes} coal resource quantities, however,more » include significant adjustments for depletion due to past mining, and adjustments for accessibility and recoverability.« less

Mining for metals in society's waste

USGS Publications Warehouse

Smith, Kathleen S.; Plumlee, Geoffrey S.; Hageman, Philip L.

2015-01-01

Metals and minerals are natural resources that human beings have been mining for thousands of years. Contemporary metal mining is dominated by iron ore, copper and gold, with 2 billion tons of iron ore, nearly 20 million tons of copper and 2,000 tons of gold produced every year. Tens to hundreds of tons of other metals that are essential components for electronics, green energy production, and high-technology products are produced annually.

2016 Billion-Ton Report: Environmental Sustainability Effects of Select Scenarios from Volume 1 (Volume 2)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Efroymson, R. A.; Langholtz, M. H.; Johnson, K. E.

On behalf of all the authors and contributors, it is a great privilege to present the 2016 Billion-Ton Report (BT16), volume 2: Environmental Sustainability Effects of Select Scenarios from volume 1. This report represents the culmination of several years of collaborative effort among national laboratories, government agencies, academic institutions, and industry. BT16 was developed to support the U.S. Department of Energy’s efforts towards national goals of energy security and associated quality of life.

Estimating current and future global urban domestic material consumption

NASA Astrophysics Data System (ADS)

Baynes, Timothy Malcolm; Kaviti Musango, Josephine

2018-06-01

Urban material resource requirements are significant at the global level and these are expected to expand with future urban population growth. However, there are no global scale studies on the future material consumption of urban areas. This paper provides estimates of global urban domestic material consumption (DMC) in 2050 using three approaches based on: current gross statistics; a regression model; and a transition theoretic logistic model. All methods use UN urban population projections and assume a simple ‘business-as-usual’ scenario wherein historical aggregate trends in income and material flow continue into the future. A collation of data for 152 cities provided a year 2000 world average DMC/capita estimate, 12 tons/person/year (±22%), which we combined with UN population projections to produce a first-order estimation of urban DMC at 2050 of ~73 billion tons/year (±22%). Urban DMC/capita was found to be significantly correlated (R 2 > 0.9) to urban GDP/capita and area per person through a power law relation used to obtain a second estimate of 106 billion tons (±33%) in 2050. The inelastic exponent of the power law indicates a global tendency for relative decoupling of direct urban material consumption with increasing income. These estimates are global and influenced by the current proportion of developed-world cities in the global population of cities (and in our sample data). A third method employed a logistic model of transitions in urban DMC/capita with regional resolution. This method estimated global urban DMC to rise from approximately 40 billion tons/year in 2010 to ~90 billion tons/year in 2050 (modelled range: 66–111 billion tons/year). DMC/capita across different regions was estimated to converge from a range of 5–27 tons/person/year in the year 2000 to around 8–17 tons/person/year in 2050. The urban population does not increase proportionally during this period and thus the global average DMC/capita increases from ~12 to ~14 tons/person/year, challenging resource decoupling targets.

Estimates of Monthly CO2 Emissions and Associated 13C/12C Values from Fossil-Fuel Consumption in the U.S.A. (1981-2003)

DOE Data Explorer

Blasing, T. J. [CDIAC, Oak Ridge National Laboratory (ORNL); Marland, Gregg [CDIAC, Oak Ridge National Laboratory (ORNL); Broniak, Christine [Oregon State University, Corvallis, Oregon

2004-07-01

The data from which these carbon-emissions estimates were derived are values of fuel consumed: in billions of cubic feet, for natural gas; in millions of barrels, for petroleum products; and in thousands of short tons, for coal. The resulting emissions estimates are expressed as teragrams of carbon. A teragram is 1012 grams, or 106 metric tons. To convert from carbon to carbon dioxide, multiply by 44/12 (=3.67). Data are available for over 30 different petroleum products, with the exact breakdown varying somewhat from year to year. These products have been treated separately here until the final step of the estimation, at which time CO2 emissions were summed and attributed to liquid petroleum products. These fuel-consumption data are available from the Energy Information Administration of the U.S. Department of Energy. They are published in the Monthly Energy Review, and are available electronically from the Energy Information Administration.

Space Based Measurements for Atmospheric Carbon Dioxide: a New Tool for Monitoring Our Environment

NASA Technical Reports Server (NTRS)

Crisp, David

2015-01-01

Fossil fuel combustion, deforestation, and other human activities are now adding almost 40 billion tons of carbon dioxide (CO2) to the atmosphere each year. Interestingly, as these emissions have increased over time, natural "sinks" in land biosphere and oceans have absorbed roughly half of this CO2, reducing the rate of atmospheric buildup by a half. Measurements of the increasing acidity (pH) of seawater indicate that the ocean absorbs one quarter of this CO2. Another quarter is apparently being absorbed by the land biosphere, but the identity and location of these natural land CO2 "sinks" are still unknown. The existing ground-based greenhouse gas monitoring network provides an accurate record of the atmospheric buildup, but still does not have the spatial resolution or coverage needed to identify or quantify CO2 sources and sinks.

USA: Economica, Politics, Ideology. Number 6, June 1977

DTIC Science & Technology

1977-07-07

important factors intensifying the contradictions and increasing the dif- ficulties in the American economy. It coincided with the most severe cyclical...energy resources. Since the beginning of the 1950’s, the energy needs of the United States have increased more rapidly than the domestic production...1.229 billion tons of fuel in 1950 to 2.592 billion tons in 1975; this was an increase of 111 percent. The average rate of increase in consumption

Regional Feedstock Partnership Summary Report: Enabling the Billion-Ton Vision

DOE Office of Scientific and Technical Information (OSTI.GOV)

Owens, Vance N.; Karlen, Douglas L.; Lacey, Jeffrey A.

2016-07-12

The U.S. Department of Energy (DOE) and the Sun Grant Initiative established the Regional Feedstock Partnership (referred to as the Partnership) to address information gaps associated with enabling the vision of a sustainable, reliable, billion-ton U.S. bioenergy industry by the year 2030 (i.e., the Billion-Ton Vision). Over the past 7 years (2008–2014), the Partnership has been successful at advancing the biomass feedstock production industry in the United States, with notable accomplishments. The Billion-Ton Study identifies the technical potential to expand domestic biomass production to offset up to 30% of U.S. petroleum consumption, while continuing to meet demands for food, feed,more » fiber, and export. This study verifies for the biofuels and chemical industries that a real and substantial resource base could justify the significant investment needed to develop robust conversion technologies and commercial-scale facilities. DOE and the Sun Grant Initiative established the Partnership to demonstrate and validate the underlying assumptions underpinning the Billion-Ton Vision to supply a sustainable and reliable source of lignocellulosic feedstock to a large-scale bioenergy industry. This report discusses the accomplishments of the Partnership, with references to accompanying scientific publications. These accomplishments include advances in sustainable feedstock production, feedstock yield, yield stability and stand persistence, energy crop commercialization readiness, information transfer, assessment of the economic impacts of achieving the Billion-Ton Vision, and the impact of feedstock species and environment conditions on feedstock quality characteristics.« less

Transportation Energy Futures Series: Freight Transportation Demand: Energy-Efficient Scenarios for a Low-Carbon Future

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grenzeback, L. R.; Brown, A.; Fischer, M. J.

2013-03-01

Freight transportation demand is projected to grow to 27.5 billion tons in 2040, and by extrapolation, to nearly 30.2 billion tons in 2050, requiring ever-greater amounts of energy. This report describes the current and future demand for freight transportation in terms of tons and ton-miles of commodities moved by truck, rail, water, pipeline, and air freight carriers. It outlines the economic, logistics, transportation, and policy and regulatory factors that shape freight demand; the possible trends and 2050 outlook for these factors, and their anticipated effect on freight demand and related energy use. After describing federal policy actions that could influencemore » freight demand, the report then summarizes the available analytical models for forecasting freight demand, and identifies possible areas for future action.« less

Transportation Energy Futures Series: Freight Transportation Demand: Energy-Efficient Scenarios for a Low-Carbon Future

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grenzeback, L. R.; Brown, A.; Fischer, M. J.

2013-03-01

Freight transportation demand is projected to grow to 27.5 billion tons in 2040, and to nearly 30.2 billion tons in 2050. This report describes the current and future demand for freight transportation in terms of tons and ton-miles of commodities moved by truck, rail, water, pipeline, and air freight carriers. It outlines the economic, logistics, transportation, and policy and regulatory factors that shape freight demand, the trends and 2050 outlook for these factors, and their anticipated effect on freight demand. After describing federal policy actions that could influence future freight demand, the report then summarizes the capabilities of available analyticalmore » models for forecasting freight demand. This is one in a series of reports produced as a result of the Transportation Energy Futures project, a Department of Energy-sponsored multi-agency effort to pinpoint underexplored strategies for reducing GHGs and petroleum dependence related to transportation.« less

Domestic phosphate deposits

USGS Publications Warehouse

McKelvey, V.E.; Cathcart, J.B.; Altschuler, Z.S.; Swanson, R.W.; Lutz, Katherine

1953-01-01

Most of the worlds phosphate deposits can be grouped into six types: 1) igneous apatite deposits; 2) marine phosphorites; 3) residual phosphorites; 4) river pebble deposits; 5) phosphatized rock; and 6) guano. The igneous apatites and marine phosphorites form deposits measurable in millions or billions of tons; the residual deposits are measurable in thousands or millions; and the other types generally only in thousands of tons. Igneous apatite deposits have been mined on a small scale in New York, New Jersey, and Virginia. Marine phosphorites have been mined in Montana, Idaho, Utah, Wyoming, Arkansas, Tennessee, North Carolina, South Carolina, Georgia, and Florida. Residual phosphorites have been mined in Tennessee, Pennsylvania, and Florida. River pebble has been produced in South Carolina and Florida; phosphatized rock in Tennessee and Florida; and guano in New Mexico and Texas. Present production is limited almost entirely to Florida, Tennessee, Montana, Idaho, and Wyoming. Incomplete but recently partly revised estimates indicate the presence of about 5 billion tons of phosphate deposits in the United States that is minable under present economic conditions. Deposits too lean in quality or thickness to compete with those in the western and southeastern fields probably contain tens of billions of tons.

Fuel Cells: Status and Technical/Economic Needs

NASA Technical Reports Server (NTRS)

Rambach, Glenn

1996-01-01

The need for fuel cell and alternative fuels has become increasingly important in that the U.S. spends 1 billion dollars per week to import oil, and is expected to import 80-100 billion per year in oil by the year 2010. These imports account for half of our oil supply. If 20% of the U.S. vehicle fleet were powered by fuel cells there would be: an offset 1.1 million barrels of oil per day; and a reduction of 2 million tons per year of regulated air pollutants. Fueling fuel cells with hydrogen from reformed natural gas results in more than 90% reduction in regulated emissions, and a 70% reduction in CO2, a greenhouse gas. And fueling fuel cells with hydrogen from renewables (wind, solar geothermal, hydro) results in total elimination of all emissions. When fuel cells become commercialized: they will improve America's economic competitiveness; and the regions where they are produced will benefit economically.

ENVIRONMENTALLY FRIENDLY TECHNOLOGIES AND THE USE OF LIFE CYCLE ANALYSIS TO EVALUATE THEIR "GREENNESS"

EPA Science Inventory

Currently, the chemical manufacturing industry generates more than one and a half billion tons of hazardous waste and nine billion tons of non-hazardous waste annually. Roughly one-third of the releases and transfers of chemicals reported through EPA's Toxic Release Inventory (T...

Weak economy and politics worry US coal operators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fiscor, S.

2009-01-15

A potential decrease in demand, a new administration, and production constraints have coal operators worried about prospects for 2009. This and other interesting facts are revealed in this 2009 forecast by the journal Coal Age. Results are presented of the survey answered by 69 of the 646 executives contacted, on such questions about expected coal production, coal use, attitude in the coal industry, capital expenditure on types of equipment and productive capacity. Coal Age forecasts a 2.3% decline in coal production in 2009, down to 1.145 billion tons from 1.172 billion tons. 8 figs.

Design Considerations for Financing a National Trust to Advance the Deployment of Geologic CO2 Storage and Motivate Best Practices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dooley, James J.; Trabucchi, Chiara; Patton , Lindene

2010-03-01

This paper explores how the flawed, widely held public policy view of an ever growing risk associated with long-term carbon dioxide (CO2) storage profoundly influences the public policy dialogue about how to best address the long term risk profile for geologic storage. In order to accomplish this, the authors present evidence from the rapidly emerging science and engineering of CO2 storage which demonstrates that, with proper site characterization and sound operating practices, retention of stored CO2 will increase with time thus invalidating the premise of an ever growing risk. The authors focus on key issues of fit, interplay, and scalabilitymore » associated with a trust fund funded by a hypothetical $1/tonCO2 tipping fee for each ton of CO2 stored in the United States under WRE450 and WRE550 climate policies. The authors conclude there is no intrinsic value in creating a trust fund predicated solely on collecting a fixed fee that is not mapped to site-specific risk profiles. If left to grow unchecked, a trust fund that is predicated on a constant stream of annual payments unrelated to the site’s risk profile could result in the accumulation of hundreds of billions to more than a trillion dollars in real terms contributing to significant opportunity cost of capital. Further, rather than mitigating the financial consequences of long-term CCS risks, this analysis suggests a blanket $1/tonCO2 tipping fee may increase the probability and frequency of long-term risk by eliminating financial incentives for sound operating behavior and site selection criteria – contribute to moral hazard. At a minimum, effective use of a trust fund requires: (1) strong oversight regarding site selection and fund management, and (2) a clear process by which the fund is periodically valued and funds collected are mapped to the risk profile of the pool of covered CCS sites. Without appropriate checks and balances, there is no a priori reason to believe that the amount of funds held in trust will map to the actual amount of funds needed to address long-term care expenses and delimited compensatory damages. For this reason, the authors conclude that the financing of a trust fund or other risk management instrument should be based on a site delimited estimate of future expected financial consequences rather than on the random adoption of a fixed funding stream, e.g., a blanket $1/ton , because it ‘sounds’ reasonable.« less

The Nation's top 25 construction aggregates producers

USGS Publications Warehouse

Willett, Jason Christopher

2013-01-01

U.S. production of construction aggregates in 2011 was 2.17 billion short tons, valued at $17.2 billion, free on board (f.o.b.) at plant. Construction aggregates production decreased by 37 percent, and the associated value decreased by 25 percent, compared with the record highs reported in 2006. In 2011, construction aggregates production increased for the first time since 2006, owing to a very slight increase in the production of both construction sand and gravel and crushed stone. The average unit value, which is the f.o.b. at plant price of a ton of material, increased slightly, but is still less than the average unit value of two years prior.

Assessment of coal geology, resources, and reserves in the Southwestern Powder River Basin, Wyoming

USGS Publications Warehouse

Osmonson, Lee M.; Scott, David C.; Haacke, Jon E.; Luppens, James A.; Pierce, Paul E.

2011-01-01

A total of 37 coal beds were identified during this assessment, 23 of which were modeled and evaluated to determine in-place coal resources. The total original coal resource in the Southwestern Powder River Basin assessment area for these 23 coal beds, with no restrictions applied was calculated to be 369 billion short tons. Available coal resources, which are part of the original resource that is accessible for potential mine development after subtracting all restrictions, are about 341 billion short tons (92.4 percent of the total original resource). Approximately 61 percent are at depths between 1,000 and 2,000 ft, with a modeled price of about $30 per short ton. Therefore, the majority of coal resources in the South-western Powder River Basin assessment area are considered sub-economic.

The Social Cost of Trading: Measuring the Increased Damages from Sulfur Dioxide Trading in the United States

ERIC Educational Resources Information Center

Henry, David D., III; Muller, Nicholas Z.; Mendelsohn, Robert O.

2011-01-01

The sulfur dioxide (SO[subscript 2]) cap and trade program established in the 1990 Clean Air Act Amendments is celebrated for reducing abatement costs ($0.7 to $2.1 billion per year) by allowing emissions allowances to be traded. Unfortunately, places with high marginal costs also tend to have high marginal damages. Ton-for-ton trading reduces…

The potential role of a carbon tax in U.S. fiscal reform

DOE Office of Scientific and Technical Information (OSTI.GOV)

McKibbin, Warwick; The Brookings Institution, Washington, DC; Morris, Adele

This paper examines fiscal reform options in the United States with an intertemporal computable general equilibrium model of the world economy called G-Cubed. Six policy scenarios explore two overarching issues: (1) the effects of a carbon tax under alternative assumptions about the use of the resulting revenue, and (2) the effects of alternative measures that could be used to reduce the budget deficit. We examine a simple excise tax on the carbon content of fossil fuels in the U.S. energy sector starting immediately at $15 per metric ton of carbon dioxide (CO2) and rising at 4 percent above inflation eachmore » year through 2050. We investigate policies that allow the revenue from the illustrative carbon tax to reduce the long run federal budget deficit or the marginal tax rates on labor and capital income. We also compare the carbon tax to other means of reducing the deficit by the same amount. We find that the carbon tax will raise considerable revenue: $80 billion at the outset, rising to $170 billion in 2030 and $310 billion by 2050. It also significantly reduces U.S. CO2 emissions by an amount that is largely independent of the use of the revenue. By 2050, annual CO2 emissions fall by 2.5 billion metric tons (BMT), or 34 percent, relative to baseline, and cumulative emissions fall by 40 BMT through 2050. The use of the revenue affects both broad economic impacts and the composition of GDP across consumption, investment and net exports. In most scenarios, the carbon tax lowers GDP slightly, reduces investment and exports, and increases imports. The effect on consumption varies across policies and can be positive if households receive the revenue as a lump sum transfer. Using the revenue for a capital tax cut, however, is significantly different than the other policies. In that case, investment booms, employment rises, consumption declines slightly, imports increase, and overall GDP rises significantly relative to baseline through about 2040. Thus, a tax reform that uses a carbon tax to reduce capital taxes would achieve two goals: reducing CO2 emissions significantly and expanding short-run employment and the economy. We examine three ways to reduce the deficit by an equal amount. We find that raising marginal tax rates on labor income has advantages over raising tax rates on capital income or establishing a carbon tax. A labor tax increase leaves GDP close to its baseline, reduces consumption very slightly and expands net exports slightly. Investment remains essentially unchanged. In contrast, a capital tax increase causes a significant and persistent drop in investment and much larger reductions in GDP. A carbon tax falls between the two: it lowers GDP more than a labor tax increase because it reduces investment. However, its effects on investment and GDP are more moderate than the capital tax increase, and it also significantly reduces CO2 emissions. A carbon tax thus offers a way to help reduce the deficit and improve the environment, and do so with minimal disturbance to overall economic activity.« less

The nation’s top 25 construction aggregates producers

USGS Publications Warehouse

Willett, Jason C.

2014-01-01

U.S. production of construction aggregates in 2012 was 2.18 billion short tons valued at $17.6 billion, free on board (f.o.b.) at plant. In 2012, construction aggregates production remained virtually unchanged from the levels of the last two years because of a very slight increase compared with that of 2011 in the production of both construction sand and gravel and crushed stone. The average unit value, which is the f.o.b. at the plant price of a metric ton of material, increased slightly. Construction aggregates production was 36 percent less than and the associated value was 23 percent less than the record highs reported in 2006.

Coal availability in the Hilight Quadrangle, Powder River Basin, Wyoming; a prototype study in a western coal field

USGS Publications Warehouse

Molnia, Carol L.; Biewick, Laura; Blake, Dorsey; Tewalt, Susan J.; Carter, M. Devereaux; Gaskill, Charlie

1997-01-01

The U.S. Geological Survey (USGS), in cooperation with the Bureau of Land Management (BLM), Geological Survey of Wyoming, and U.S. Bureau of Mines (USBM), has produced an estimate of the amount of available coal in an area about 35 miles south of Gillette, Wyo., where the Wyodak coal bed is, in places, more than 100 ft thick. Available coal is the quantity of the total coal resource that is accessible for mine development under current regulatory, land-use, and technologic constraints. This first western coal availability study, of the Hilight 7 1/2-minute quadrangle, indicates that approximately 60 percent (2.7 billion short tons) of the total 4.4 billion tons of coal in-place in the quadrangle is available for development. (There has been no commercial mining in the Hilight quadrangle.) Approximately 67 percent (1.9 billion tons) of the Main Wyodak coal bed is considered available. All tonnage measurements in this report are given in short tons. Coal-development considerations in the quadrangle include dwellings, railroads, pipelines, power lines, wildlife habitat (eagles), alluvial valley floors, cemeteries, and the Hilight oil and gas field and gas plant. Some of these considerations could be mitigated so that surface mining of the coal may proceed; others could not be mitigated and would preclude mining in their vicinity. Other technological constraints that influence the availability of the coal include overburden thickness, coal beds too thin, and areas of clinker.

Emissions of HC, CO, NOx, CO2, and SO2 from civil aviation in China in 2010

NASA Astrophysics Data System (ADS)

Fan, Weiyi; Sun, Yifei; Zhu, Tianle; Wen, Yi

2012-09-01

Civil aviation in China has developed rapidly in recent years, and the effects of civil aviation emissions on the atmospheric environment should not be neglected. The establishment of emission inventories of atmospheric pollutants from civil aviation contributes to related policy formation and pollution control. According to the 2010's China flight schedules, aircraft/engine combination information and revised emission indices from the International Civil Aviation Organization emission data bank based on meteorological data, the fuel consumption and HC, CO, NOx, CO2, SO2 emissions from domestic flights of civil aviation in China (excluding Taiwan Province) in 2010 are estimated in this paper. The results show that fuel consumption in 2010 on domestic flights in China is 12.12 million tons (metric tons), HC, CO, NOx, CO2 and SO2 emissions are 4600 tons, 39,700 tons, 154,100 tons, 38.21 million tons and 9700 tons, respectively. The fuel consumption and pollutant emissions of China Southern Airline are responsible for the largest national proportion of each, accounting for 27% and 25-28%, respectively.

Multiresource Inventories: Woody Biomass in North Carolina

Treesearch

Noel D. Cost

1986-01-01

North Carolina's 31.2 million acres of land area support 1.7 billion tons of woody biomass. Of this total, 94 percent is on timberland, 3 percent on nonforest areas, and 3 percent on reserved timberland and woodland areas. Over the next two decades, more than 12.8 million tons of woody biomass could be harvested annually from timberland without adversely...

Emission of greenhouse gases from waste incineration in Korea.

PubMed

Hwang, Kum-Lok; Choi, Sang-Min; Kim, Moon-Kyung; Heo, Jong-Bae; Zoh, Kyung-Duk

2017-07-01

Greenhouse gas (GHG) emission factors previously reported from various waste incineration plants have shown significant variations according to country-specific, plant-specific, and operational conditions. The purpose of this study is to estimate GHG emissions and emission factors at nine incineration facilities in Korea by measuring the GHG concentrations in the flue gas samples. The selected incineration plants had different operation systems (i.e., stoker, fluidized bed, moving grate, rotary kiln, and kiln & stoker), and different nitrogen oxide (NO x ) removal systems (i.e., selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR)) to treat municipal solid waste (MSW), commercial solid waste (CSW), and specified waste (SW). The total mean emission factors for A and B facilities for MSW incineration were found to be 134 ± 17 kg CO 2 ton -1 , 88 ± 36 g CH 4 ton -1 , and 69 ± 16 g N 2 O ton -1 , while those for CSW incineration were 22.56 g CH 4 ton -1 and 259.76 g N 2 O ton -1 , and for SW incineration emission factors were 2959 kg CO 2 ton -1 , 43.44 g CH 4 ton -1 and 401.21 g N 2 O ton -1 , respectively. Total emissions calculated using annual incineration for MSW were 3587 ton CO 2 -eq yr -1 for A facility and 11,082 ton CO 2 -eq yr -1 for B facility, while those of IPCC default values were 13,167 ton CO 2- eq yr -1 for A facility and 32,916 ton CO 2- eq yr -1 , indicating that the emissions of IPCC default values were estimated higher than those of the plant-specific emission factors. The emission of CSW for C facility was 1403 ton CO 2 -eq yr -1 , while those of SW for D to I facilities was 28,830 ton CO 2 -eq yr -1 . The sensitivity analysis using a Monte Carlo simulation for GHG emission factors in MSW showed that the GHG concentrations have a greater impact than the incineration amount and flow rate of flue gas. For MSW incineration plants using the same stoker type in operation, the estimated emissions and emission factors of CH 4 showed the opposite trend with those of NO 2 when the NO x removal system was used, whereas there was no difference in CO 2 emissions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Mineral resource assessment of the Iron River 1 degree x 2 degrees Quadrangle, Michigan and Wisconsin

USGS Publications Warehouse

Cannon, William F.

1983-01-01

The Iron River 1? x 2? quadrangle contains identified resources of copper and iron. Copper-rich shale beds in the north part of the quadrangle contain 12.2 billion pounds (5.5 billion kilograms) of copper in well-studied deposits including 9.2 billion pounds (4.2 billion kilograms) that are economically minable by 1980 standards. At least several billion pounds of copper probably exist in other parts of the same shale beds, but not enough data are available to measure the amount. A small amount, about 250 million pounds (113 million kilograms), of native copper is known to remain in one abandoned mine, and additional but unknown amounts remain in other abandoned mines. About 13.25 billion tons (12.02 billion metric tons) of banded iron-formation averaging roughly 30 percent iron are known within 500 feet (152.4 meters) of the surface in the Gogebic, Marquette, and Iron River-Crystal Falls districts. A small percentage of that might someday be minable as taconite, but none is now believed to be economic. Some higher grade iron concentrations exist in the same iron-formations. Such material was the basis of former mining of iron in the region, but a poor market for such ore and depletion of many deposits have led to the decline of iron mining in the quadrangle. Iron mines of the quadrangle were not being worked in 1980. Many parts of the quadrangle contain belts of favorable host rocks for mineral deposits. Although deposits are not known in these belts, undiscovered deposits of copper, zinc, lead, silver, uranium, phosphate, nickel, chromium, platinum, gold, and diamonds could exist.

Long time management of fossil fuel resources to limit global warming and avoid ice age onsets

NASA Astrophysics Data System (ADS)

Shaffer, Gary

2009-02-01

There are about 5000 billion tons of fossil fuel carbon in accessible reserves. Combustion of all this carbon within the next few centuries would force high atmospheric CO2 content and extreme global warming. On the other hand, low atmospheric CO2 content favors the onset of an ice age when changes in the Earth's orbit lead to low summer insolation at high northern latitudes. Here I present Earth System Model projections showing that typical reduction targets for fossil fuel use in the present century could limit ongoing global warming to less than one degree Celcius above present. Furthermore, the projections show that combustion pulses of remaining fossil fuel reserves could then be tailored to raise atmospheric CO2 content high and long enough to parry forcing of ice age onsets by summer insolation minima far into the future. Our present interglacial period could be extended by about 500,000 years in this way.

Spatial Distribution of Conventional Air Pollutant and GHGs from Land Transportation in Two Developing Cities and Main Co-Benefit Actions For Reducing It.

NASA Astrophysics Data System (ADS)

Huboyo, Haryono S.; Sutrisno, Endro; Sutrisno, Ana M.; Tiarani, Velida L.

2018-02-01

Surakarta and Yogyakarta are the emerging cities which now struggle to manage its pollution from transport sector. This study aims to calculate the emission, to describe spatial distribution and to analyze existing co-benefit actions related to land transportation in Surakarta and Yogyakarta in 2015. The main method used for this analysis comes from Ministry of Environment and Forestry. The VKT values were aggregated for Surakarta city and Yogyakarta city and it showed 27.36 km/day, 37.52 km/day and 27.71 km/day for motorcycle, car and truck respectively. At Surakarta city, the emission load from transport sector in 2014 were 449.95 tons/ year (TSP), 5134 ton/ year(NOx), 243 ton/year (SO2), 50,605 ton /year (CO) and 421,594 tons/year (CO2e). Villages of Kemlayan, Timuran and Keprabon showed the highest emission. While in Yogyakarta city in 2014, the burden of TSP was 58,409 tons/year, NOx was 8,058 tons/year, SO2 was 285.37 ton/year, CO was 75,008 tons/year and CO2e by 601,068 tons/year. The village of Pringgokusuman and Sosromeduran showed the highest emission. Several programs were adopted in Yogyakarta city and Surakarta city for mitigating air pollution i.e ITS-ATCS, BRT system, car free day.

Litter generated ammonia captured by activated carbon derived from broiler litter

USDA-ARS?s Scientific Manuscript database

In 2011, the production rate of broilers was 8.6 billion with a value of $23.2 billion (USDA 2012). Both CERCLA and EPCRA have reporting requirements for ammonia (NH3) of 100 lb of NH3/d or 18.3 tons/yr, a level that may affect large animal production facilities (NRC 2003). Although USEPA (2009) ha...

Multiresource inventories: woody biomass in Virginia

Treesearch

Noel D. Cost

1988-01-01

Virginia's 25 .. 4 million acres of land area support 1.5 billion J tons of woody biomass. Of this total, 93 percent is on timberland, I 5 percent on reserved timberland and woodland areas, and 2 percent I on nonforest areas. Over the next two decades, more than 9 million I t tons of woody biomass could be harvested annually from timberland I I without adversely...

Estimating usable resources from historical industry data

USGS Publications Warehouse

Cargill, S.M.; Root, D.H.; Bailey, E.H.

1981-01-01

Historical production statistics are used to predict the quantity of remaining usable resources. The commodities considered are mercury, copper and its byproducts gold and silver, and petroleum; the production and discovery data are for the United States. The results of the study indicate that the cumulative return per unit of effort, herein measured as grade of metal ores and discovery rate of recoverable petroleum, is proportional to a negative power of total effort expended, herein measured as total ore mined and total exploratory wells or footage drilled. This power relationship can be extended to some limiting point (a lower ore grade or a maximum number of exploratory wells or footage), and the apparent quantity of available remaining resource at that limit can be calculated. For mercury ore of grades at and above 0.1 percent, the remaining usable resource in the United States is calculated to be 54 million kg (1,567,000 flasks). For copper ore of grades at and above 0.2 percent, the remaining usable copper resource is calculated to be 270 million metric tons (298 million short tons); remaining resources of its by-products gold and silver are calculated to be 3,656 metric tons (118 million troy ounces) and 64,676 metric tons (2,079 million troy ounces), respectively. The undiscovered recoverable crude oil resource in the conterminous United States, at 3 billion feet of additional exploratory drilling, is calculated to be nearly 37.6 billion barrels; the undiscovered recoverable petroleum resource in the Permian basin of western Texas and southeastern New Mexico, at 300 million feet of additional exploratory drilling or 50,000 additional exploratory wells, is calculated to be about 6.2 billion BOE (barrels of oil equivalent).

40 CFR 98.218 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... emission factor(tons CO2/ton carbonate) Limestone—CaCO3 0.43971 Magnesite—MgCO3 0.52197 Dolomite—CaMg(CO3)2 0.47732 Siderite—FeCO3 0.37987 Ankerite—Ca(Fe, Mg, Mn)(CO3)2 0.47572 Rhodochrosite—MnCO3 0.38286...

Assessment of undiscovered technically recoverable conventional petroleum resources of northern Afghanistan

USGS Publications Warehouse

Klett, T.R.; Ulmishek, G.F.; Wandrey, C.J.; Agena, Warren F.; Steinshouer, Douglas

2006-01-01

Using a geology-based assessment methodology, the U.S. Geological Survey - Afghanistan Ministry of Mines and Industry Joint Oil and Gas Resource Assessment Team estimated mean volumes of undiscovered petroleum in northern Afghanistan; the resulting estimates are 1.6 billion barrels (0.2 billion metric tons) of crude oil, 16 trillion cubic feet (0.4 trillion cubic meters) of natural gas, and 0.5 billion barrels (0.8 billion metric tons) of natural gas liquids. Most of the undiscovered crude oil is in the Afghan-Tajik Basin and most of the undiscovered natural gas is in the Amu Darya Basin. Four total petroleum systems were identified, and these were subdivided into eight assessment units for the purpose of this resource assessment. The area with the greatest potential for undiscovered natural gas accumulations is in Upper Jurassic carbonate and reef reservoirs beneath an impermeable salt layer in relatively unexplored parts of northern Afghanistan. The Afghan-Tajik Basin has the greatest potential for undiscovered crude oil accumulations, and these are potentially in Cretaceous to Paleogene carbonate reservoir rocks associated with thrust faulting and folding.

40 CFR Table U-1 to Subpart U of... - CO2 Emission Factors for Common Carbonates

Code of Federal Regulations, 2011 CFR

2011-07-01

... Mineral name—carbonate CO2 emission factor(tons CO2/ton carbonate) Limestone—CaCO3 0.43971 Magnesite—MgCO3 0.52197 Dolomite—CaMg(CO3)2 0.47732 Siderite—FeCO3 0.37987 Ankerite—Ca(Fe, Mg, Mn)(CO3)2 0.47572...

40 CFR Table U-1 to Subpart U of... - CO2 Emission Factors for Common Carbonates

Code of Federal Regulations, 2014 CFR

2014-07-01

... Mineral name—carbonate CO2 emission factor(tons CO2/ton carbonate) Limestone—CaCO3 0.43971 Magnesite—MgCO3 0.52197 Dolomite—CaMg(CO3)2 0.47732 Siderite—FeCO3 0.37987 Ankerite—Ca(Fe, Mg, Mn)(CO3)2 0.47572...

40 CFR Table U-1 to Subpart U of... - CO2 Emission Factors for Common Carbonates

Code of Federal Regulations, 2013 CFR

2013-07-01

... Mineral name—carbonate CO2 emission factor(tons CO2/ton carbonate) Limestone—CaCO3 0.43971 Magnesite—MgCO3 0.52197 Dolomite—CaMg(CO3)2 0.47732 Siderite—FeCO3 0.37987 Ankerite—Ca(Fe, Mg, Mn)(CO3)2 0.47572...

40 CFR Table U-1 to Subpart U of... - CO2 Emission Factors for Common Carbonates

Code of Federal Regulations, 2012 CFR

2012-07-01

... Mineral name—carbonate CO2 emission factor(tons CO2/ton carbonate) Limestone—CaCO3 0.43971 Magnesite—MgCO3 0.52197 Dolomite—CaMg(CO3)2 0.47732 Siderite—FeCO3 0.37987 Ankerite—Ca(Fe, Mg, Mn)(CO3)2 0.47572...

Hazardous materials highlights : 2007 Commodity Flow Survey

DOT National Transportation Integrated Search

2011-01-01

Hazardous materials movement through the Nations transportation network in 2007 remained relatively unchanged from 2002 measures, according to data from the 2007 Commodity Flow Survey (CFS), released in 2010. The estimated 2.2 billion tons of haza...

40 CFR Table F-2 to Subpart F of... - Default Data Sources for Parameters Used for CO2 Emissions

Code of Federal Regulations, 2014 CFR

2014-07-01

... metric ton Al (metric tons C/metric tons Al) Individual facility records. Sa: sulfur content in baked anode (percent weight) 2.0. Asha: ash content in baked anode (percent weight) 0.4. CO2 Emissions From... records. Hw: annual hydrogen content in green anodes (metric tons) 0.005 × GA. BA: annual baked anode...

40 CFR Table F-2 to Subpart F of... - Default Data Sources for Parameters Used for CO2 Emissions

Code of Federal Regulations, 2013 CFR

2013-07-01

... metric ton Al (metric tons C/metric tons Al) Individual facility records. Sa: sulfur content in baked anode (percent weight) 2.0. Asha: ash content in baked anode (percent weight) 0.4. CO2 Emissions From... records. Hw: annual hydrogen content in green anodes (metric tons) 0.005 × GA. BA: annual baked anode...

40 CFR Table F-2 to Subpart F of... - Default Data Sources for Parameters Used for CO2 Emissions

Code of Federal Regulations, 2012 CFR

2012-07-01

... metric ton Al (metric tons C/metric tons Al) Individual facility records. Sa: sulfur content in baked anode (percent weight) 2.0. Asha: ash content in baked anode (percent weight) 0.4. CO2 Emissions From... records. Hw: annual hydrogen content in green anodes (metric tons) 0.005 × GA. BA: annual baked anode...

40 CFR Table F-2 to Subpart F of... - Default Data Sources for Parameters Used for CO2 Emissions

Code of Federal Regulations, 2011 CFR

2011-07-01

... metric ton Al (metric tons C/metric tons Al) Individual facility records. Sa: sulfur content in baked anode (percent weight) 2.0. Asha: ash content in baked anode (percent weight) 0.4. CO2 Emissions From... records. Hw: annual hydrogen content in green anodes (metric tons) 0.005 × GA. BA: annual baked anode...

JPRS Report, China, Qiushi Seeking Truth, No. 16, 16 August 1989

DTIC Science & Technology

1989-10-04

34 they require. Those tertiary students who are referred to as "the fourth generation" cannot compare in political quality, Marxist theoretical...920,000 tons;raw coal , 61.88 million tons; crude oil, 320,000 tons. Although old China was said to be an agricultural country, its highest annual...billion meters; steel by 64 times, to 59.18 million tons; raw coal by 16 times, to 980 million tons; crude oil by 428 times, to 137.05 million tons

Water and salt balance of Great Salt Lake, Utah, and simulation of water and salt movement through the causeway

USGS Publications Warehouse

Wold, Steven R.; Thomas, Blakemore E.; Waddell, Kidd M.

1997-01-01

The water and salt balance of Great Salt Lake primarily depends on the amount of inflow from tributary streams and the conveyance properties of a causeway constructed during 1957-59 that divides the lake into the south and north parts. The conveyance properties of the causeway originally included two culverts, each 15 feet wide, and the permeable rock-fill material.During 1980-86, the salt balance changed as a result of record high inflow that averaged 4,627,000 acre-feet annually and modifications made to the conveyance properties of the causeway that included opening a 300-foot-wide breach. In this study, a model developed in 1973 by Waddell and Bolke to simulate the water and salt balance of the lake was revised to accommodate the high water-surface altitude and modifications made to the causeway. This study, done by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of State Lands and Forestry, updates the model with monitoring data collected during 1980-86. This report describes the calibration of the model and presents the results of simulations for three hypothetical 10-year periods.During January 1, 1980, to July 31, 1984, a net load of 0.5 billion tons of dissolved salt flowed from the south to the north part of the lake primarily as a result of record inflows. From August 1, 1984, when the breach was opened, to December 31,1986, a net load of 0.3 billion tons of dissolved salt flowed from the north to the south part of the lake primarily as a result of the breach.For simulated inflow rates during a hypothetical 10-year period resulting in the water-surface altitude decreasing from about 4,200 to 4,192 feet, there was a net movement of about 1.0 billion tons of dissolved salt from the south to the north part, and about 1.7 billion tons of salt precipitated in the north part. For simulated inflow rates during a hypothetical 10-year period resulting in a rise in water-surface altitude from about 4,200 to 4,212 feet, there was a net movement of about 0.2 billion tons of dissolved salt from the south to the north part and no salt was precipitated in the north part of the lake.

Energy and emissions saving potential of additive manufacturing: the case of lightweight aircraft components

DOE PAGES

Huang, Runze; Riddle, Matthew; Graziano, Diane; ...

2015-05-08

Additive manufacturing (AM) holds great potential for improving materials efficiency, reducing life-cycle impacts, and enabling greater engineering functionality compared to conventional manufacturing (CM) processes. For these reasons, AM has been adopted by a growing number of aircraft component manufacturers to achieve more lightweight, cost-effective designs. This study estimates the net changes in life-cycle primary energy and greenhouse gas emissions associated with AM technologies for lightweight metallic aircraft components through the year 2050, to shed light on the environmental benefits of a shift from CM to AM processes in the U.S. aircraft industry. A systems modeling framework is presented, with integratesmore » engineering criteria, life-cycle environmental data, and aircraft fleet stock and fuel use models under different AM adoption scenarios. Estimated fleetwide life-cycle primary energy savings in a rapid adoption scenario reach 70-174 million GJ/year in 2050, with cumulative savings of 1.2-2.8 billion GJ. Associated cumulative emission reduction potentials of CO2e were estimated at 92.8-217.4 million metric tons. About 95% of the savings is attributed to airplane fuel consumption reductions due to lightweighting. In addition, about 4050 tons aluminum, 7600 tons titanium and 8100 tons of nickel alloys could be saved per year in 2050. The results indicate a significant role of AM technologies in helping society meet its long-term energy use and GHG emissions reduction goals, and highlight barriers and opportunities for AM adoption for the aircraft industry.« less

Energy and emissions saving potential of additive manufacturing: the case of lightweight aircraft components

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Runze; Riddle, Matthew; Graziano, Diane

Additive manufacturing (AM) holds great potential for improving materials efficiency, reducing life-cycle impacts, and enabling greater engineering functionality compared to conventional manufacturing (CM) processes. For these reasons, AM has been adopted by a growing number of aircraft component manufacturers to achieve more lightweight, cost-effective designs. This study estimates the net changes in life-cycle primary energy and greenhouse gas emissions associated with AM technologies for lightweight metallic aircraft components through the year 2050, to shed light on the environmental benefits of a shift from CM to AM processes in the U.S. aircraft industry. A systems modeling framework is presented, with integratesmore » engineering criteria, life-cycle environmental data, and aircraft fleet stock and fuel use models under different AM adoption scenarios. Estimated fleetwide life-cycle primary energy savings in a rapid adoption scenario reach 70-174 million GJ/year in 2050, with cumulative savings of 1.2-2.8 billion GJ. Associated cumulative emission reduction potentials of CO2e were estimated at 92.8-217.4 million metric tons. About 95% of the savings is attributed to airplane fuel consumption reductions due to lightweighting. In addition, about 4050 tons aluminum, 7600 tons titanium and 8100 tons of nickel alloys could be saved per year in 2050. The results indicate a significant role of AM technologies in helping society meet its long-term energy use and GHG emissions reduction goals, and highlight barriers and opportunities for AM adoption for the aircraft industry.« less

The carbon footprints of home and in-center maintenance hemodialysis in the United Kingdom.

PubMed

Connor, Andrew; Lillywhite, Robert; Cooke, Matthew W

2011-01-01

Climate change presents a global health threat. However, the provision of healthcare, including dialysis, is associated with greenhouse gas emissions. The aim of this study was to determine the carbon footprints of the differing modalities and treatment regimes used to deliver maintenance hemodialysis (HD), in order to inform carbon reduction strategies at the level of both individual treatments and HD programs. This was a component analysis study adhering to PAS2050. Emissions factors were applied to data that were collected for building energy use, travel and procurement. Thrice weekly in-center HD has a carbon footprint of 3.8 ton CO2 Eq per patient per year. The majority of emissions arise within the medical equipment (37%), energy use (21%), and patient travel (20%) sectors. The carbon footprint of providing home HD varies with the regime. For standard machines: 4 times weekly (4 days, 4.5 hours), 4.3 ton CO2 Eq; 5 times weekly (5 days, 4 hours), 5.1 ton CO2 Eq ; short daily (6 days, 2 hours), 5.2 ton CO2 Eq; nocturnal (3 nightly, 7 hours), 3.9 ton CO2 Eq; and nocturnal (6 nightly, 7 hours), 7.2 ton CO2 Eq. For NxStage equipment: short daily (5.5 days, 3 hours), 1.8 ton CO2 Eq; 6 nightly nocturnal (2.1 ton CO2 Eq). The carbon footprint of HD is influenced more by the frequency of treatments than by their duration. The anticipated rise in the prevalence of home HD patients, dialyzing more frequently and for longer than in-center patients, will increase the emissions associated with HD programs (despite reductions in patient travel emissions). Emerging technologies, such as NxStage, might offer a solution to this problem. © 2011 The Authors. Hemodialysis International © 2011 International Society for Hemodialysis.

The key to commercial-scale geological CO2 sequestration: Displaced fluid management

USGS Publications Warehouse

Surdam, R.C.; Jiao, Z.; Stauffer, P.; Miller, T.

2011-01-01

The Wyoming State Geological Survey has completed a thorough inventory and prioritization of all Wyoming stratigraphic units and geologic sites capable of sequestering commercial quantities of CO2 (5-15 Mt CO 2/year). This multi-year study identified the Paleozoic Tensleep/Weber Sandstone and Madison Limestone (and stratigraphic equivalent units) as the leading clastic and carbonate reservoir candidates for commercial-scale geological CO2 sequestration in Wyoming. This conclusion was based on unit thickness, overlying low permeability lithofacies, reservoir storage and continuity properties, regional distribution patterns, formation fluid chemistry characteristics, and preliminary fluid-flow modeling. This study also identified the Rock Springs Uplift in southwestern Wyoming as the most promising geological CO2 sequestration site in Wyoming and probably in any Rocky Mountain basin. The results of the WSGS CO2 geological sequestration inventory led the agency and colleagues at the UW School of Energy Resources Carbon Management Institute (CMI) to collect available geologic, petrophysical, geochemical, and geophysical data on the Rock Springs Uplift, and to build a regional 3-D geologic framework model of the Uplift. From the results of these tasks and using the FutureGen protocol, the WSGS showed that on the Rock Springs Uplift, the Weber Sandstone has sufficient pore space to sequester 18 billion tons (Gt) of CO2, and the Madison Limestone has sufficient pore space to sequester 8 Gt of CO2. ?? 2011 Published by Elsevier Ltd.

Central Appalachia: Production potential of low-sulfur coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Watkins, J.

The vast preponderance of eastern US low sulfur and 1.2-lbs SO{sub 2}/MMBtu compliance coal comes from a relatively small area composed of 14 counties located in eastern Kentucky, southern West Virginia and western Virginia. These 14 counties accounted for 68% of all Central Appalachian coal production in 1989 as well as 85% of all compliance coal shipped to electric utilities from this region. A property-by-property analysis of total production potential in 10 of the 14 counties (Floyd, Knott, Letcher, Harlan, Martin and Pike in Kentucky and Boone, Kanawha, Logan and Mingo in West Virginia) resulted in the following estimates ofmore » active and yet to be developed properties: (1) total salable reserves for all sulfur levels were 5.9 billion tons and (2) 1.2-lbs. SO{sub 2}/MMBtu compliance'' reserves totaled 2.38 billion tons. This potential supply of compliance coal is adequate to meet the expanded utility demand expected under acid rain for the next 20 years. Beyond 2010, compliance supplies will begin to reach depletion levels in some areas of the study region. A review of the cost structure for all active mines was used to categorize the cost structure for developing potential supplies. FOB cash costs for all active mines in the ten counties ranged from $15 per ton to $35 per ton and the median mine cost was about $22 per ton. A total of 47 companies with the ability to produce and ship coal from owned or leased reserves are active in the ten-county region. Identified development and expansion projects controlled by active companies are capable of expanding the region's current production level by over 30 million tons per year over the next twenty years. Beyond this period the issue of reserve depletion for coal of all sulfur levels in the ten county region will become a pressing issue. 11 figs., 12 tabs.« less

Energy and Economic Impacts of U.S. Federal Energy and Water Conservation Standards Adopted From 1987 Through 2015

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyers, Stephen; Williams, Alison; Chan, Peter

This paper presents estimates of the key impacts of Federal energy and water conservation standards adopted from 1987 through 2015. The standards for consumer products and commercial and industrial equipment include those set by legislation as well as standards adopted by DOE through rulemaking. In 2015, the standards saved an estimated 4.49 quads of primary energy, which is equivalent to 5% of total U.S. energy consumption. The savings in operating costs for households and businesses totaled $63.4 billion. The average household saved $320 in operating costs as a result of residential appliance standards. The estimated reduction in CO2 emissions associatedmore » with the standards in 2015 was 238 million metric tons, which is equivalent to 4.3% of total U.S. CO2 emissions. The estimated cumulative energy savings over the period 1990-2090 amount to 216.9 quads. Accounting for the increased upfront costs of more-efficient products and the operating cost (energy and water) savings over the products’ lifetime, the standards have a cumulative net present value (NPV) of consumer benefit of between $1,627 billion and $1,887 billion, using 7 percent and 3 percent discount rates, respectively. The water conservation standards, together with energy conservation standards that also save water, reduced water use by 1.9 trillion gallons in 2015 and estimated cumulative water savings by 2090 amount to 55 trillion gallons. The estimated consumer savings in 2015 from reduced water use amounted to $12 billon.« less

Energy and Economic Impacts of U.S. Federal Energy and Water Conservation Standards Adopted From 1987 Through 2013

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyers, Stephen; Williams, Alison; Chan, Peter

This paper presents estimates of the key impacts of Federal energy and water conservation standards adopted from 1987 through 2013. The standards for consumer products and commercial and industrial equipment include those set by legislation as well as standards adopted by DOE through rulemaking. In 2013, the standards saved an estimated 4.05 quads of primary energy, which is equivalent to 4% of total U.S. energy consumption. The savings in operating costs for households and businesses totaledmore » $56 billion. The average household saved $$361 in operating costs as a result of residential and plumbing product standards. The estimated reduction in CO{sub 2} emissions associated with the standards in 2013 was 218 million metric tons, which is equivalent to 4% of total U.S. CO{sub 2} emissions. The estimated cumulative energy savings over the period 1990-2090 amount to 181 quads. Accounting for the increased upfront costs of more-efficient products and the operating cost (energy and water) savings over the products’ lifetime, the standards have a past and projected cumulative net present value (NPV) of consumer benefit of between $$1,271 billion and $1,487 billion, using 7 percent and 3 percent discount rates, respectively. The water conservation standards, together with energy conservation standards that also save water, reduced water use by 1.9 trillion gallons in 2013, and will achieve cumulative water savings by 2090 of 55 trillion gallons. The estimated consumer savings in 2013 from reduced water use amounted to $16 billon.« less

Energy and Economic Impacts of U.S. Federal Energy and Water Conservation Standards Adopted From 1987 through 2012

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyers, Stephen; Williams, Alison; Chan, Peter

This paper presents estimates of the key impacts of Federal energy and water conservation standards adopted from 1987 through 2012. The standards for consumer products and commercial and industrial equipment include those set by legislation as well as standards adopted by DOE through rulemaking. In 2012, the standards saved an estimated 3.6 quads of primary energy, which is equivalent to 3% of total U.S. energy consumption. The savings in operating costs for households and businesses totaled $51.4 billion. The average household saved $347 in operating costs as a result of residential and plumbing product standards. The estimated reduction in CO2more » emissions associated with the standards in 2012 was 198 million metric tons, which is equivalent to 3% of total U.S. CO2 emissions. The estimated cumulative energy savings over the period 1990-2070 amount to 179 quads. Accounting for the increased upfront costs of more-efficient products and the operating cost (energy and water) savings over the products’ lifetime, the standards have a past and projected cumulative net present value (NPV) of consumer benefit of between $1,104 billion and $1,390 billion, using 7 percent and 3 percent discount rates, respectively. The water conservation standards, together with energy conservation standards that also save water, reduced water use by 1.8 trillion gallons in 2012, and will achieve cumulative water savings by 2040 of 54 trillion gallons. The estimated consumer savings in 2012 from reduced water use amounted to $13 billon.« less

A wedge-based approach to estimating health co-benefits of climate change mitigation activities in the United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Balbus, John M.; Greenblatt, Jeffery B.; Chari, Ramya

While it has been recognized that actions reducing greenhouse gas (GHG) emissions can have significant positive and negative impacts on human health through reductions in ambient fine particulate matter (PM2.5) concentrations, these impacts are rarely taken into account when analyzing specific policies. This study presents a new framework for estimating the change in health outcomes resulting from implementation of specific carbon dioxide (CO 2) reduction activities, allowing comparison of different sectors and options for climate mitigation activities. Our estimates suggest that in the year 2020, the reductions in adverse health outcomes from lessened exposure to PM2.5 would yield economic benefitsmore » in the range of $6 to $14 billion (in 2008 USD), depending on the specific activity. This equates to between $40 and $93 per metric ton of CO 2 in health benefits. Specific climate interventions will vary in the health co-benefits they provide as well as in potential harms that may result from their implementation. Rigorous assessment of these health impacts is essential for guiding policy decisions as efforts to reduce GHG emissions increase in scope and intensity.« less

Coal geology and assessment of coal resources and reserves in the Powder River Basin, Wyoming and Montana

USGS Publications Warehouse

Luppens, James A.; Scott, David C.

2015-01-01

This report presents the final results of the first assessment of both coal resources and reserves for all significant coal beds in the entire Powder River Basin, northeastern Wyoming and southeastern Montana. The basin covers about 19,500 square miles, exclusive of the part of the basin within the Crow and Northern Cheyenne Indian Reservations in Montana. The Powder River Basin, which contains the largest resources of low-sulfur, low-ash, subbituminous coal in the United States, is the single most important coal basin in the United States. The U.S. Geological Survey used a geology-based assessment methodology to estimate an original coal resource of about 1.16 trillion short tons for 47 coal beds in the Powder River Basin; in-place (remaining) resources are about 1.15 trillion short tons. This is the first time that all beds were mapped individually over the entire basin. A total of 162 billion short tons of recoverable coal resources (coal reserve base) are estimated at a 10:1 stripping ratio or less. An estimated 25 billion short tons of that coal reserve base met the definition of reserves, which are resources that can be economically produced at or below the current sales price at the time of the evaluation. The total underground coal resource in coal beds 10–20 feet thick is estimated at 304 billion short tons.

40 CFR 98.283 - Calculating GHG emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (metric tons CO2/metric ton of petroleum coke consumed). 0.65 = Adjustment factor for the amount of carbon... = Carbon content factor for petroleum coke consumed in month n from the supplier or as measured by the... = Petroleum coke consumption in month n (tons). EFCO2,n = CO2 emissions factor from month n (calculated in...

40 CFR 98.283 - Calculating GHG emissions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (metric tons CO2/metric ton of petroleum coke consumed). 0.65 = Adjustment factor for the amount of carbon... = Carbon content factor for petroleum coke consumed in month n from the supplier or as measured by the... = Petroleum coke consumption in month n (tons). EFCO2,n = CO2 emissions factor from month n (calculated in...

40 CFR 98.283 - Calculating GHG emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (metric tons CO2/metric ton of petroleum coke consumed). 0.65 = Adjustment factor for the amount of carbon... = Carbon content factor for petroleum coke consumed in month n from the supplier or as measured by the... = Petroleum coke consumption in month n (tons). EFCO2,n = CO2 emissions factor from month n (calculated in...

40 CFR 98.283 - Calculating GHG emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (metric tons CO2/metric ton of petroleum coke consumed). 0.65 = Adjustment factor for the amount of carbon... = Carbon content factor for petroleum coke consumed in month n from the supplier or as measured by the... = Petroleum coke consumption in month n (tons). EFCO2,n = CO2 emissions factor from month n (calculated in...

Kansas coal distribution, resources, and potential for coalbed methane

USGS Publications Warehouse

Brady, L.L.

2000-01-01

100 ft (>30 m)] determined from 32 different coal beds. Strippable coal resources at a depth Kansas has large amounts of bituminous coal both at the surface and in the subsurface of eastern Kansas. Preliminary studies indicate at least 53 billion tons (48 billion MT) of deep coal [>100 ft (>30 m)] determined from 32 different coal beds. Strippable coal resources at a depth < 100 ft (<30 m) total 2.8 billion tons (2.6 billion MT), and this total is determined from 17 coals. Coal beds present in the Cherokee Group (Middle Pennsylvanian) represent most of these coal resource totals. Deep coal beds with the largest resource totals include the Bevier, Mineral, "Aw" (unnamed coal bed), Riverton, and Weir-Pittsburg coals, all within the Cherokee Group. Based on chemical analyses, coals in the southeastern part of the state are generally high volatile A bituminous, whereas coals in the east-central and northeastern part of the state are high-volatile B bituminous coals. The primary concern of coal beds in Kansas for deep mining or development of coalbed methane is the thin nature [<2 ft (0.6 m)] of most coal beds. Present production of coalbed methane is centered mainly in the southern Wilson/northern Montgomery County area of southeastern Kansas where methane is produced from the Mulky, Weir-Pittsburg, and Riverton coals.

40 CFR 98.333 - Calculating GHG emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... in your calculation using Equation R-1 of § 98.183. ER30OC09.126 Where: ECO2k = Annual CO2 process emissions from individual Waelz kiln or electrothermic furnace “k” (metric tons). 44/12 = Ratio of molecular weights, CO2 to carbon. 2000/2205 = Conversion factor to convert tons to metric tons. (Zinc)k = Annual...

Winglets Save Billions of Dollars in Fuel Costs

NASA Technical Reports Server (NTRS)

2010-01-01

The upturned ends now featured on many airplane wings are saving airlines billions of dollars in fuel costs. Called winglets, the drag-reducing technology was advanced through the research of Langley Research Center engineer Richard Whitcomb and through flight tests conducted at Dryden Flight Research Center. Seattle-based Aviation Partners Boeing -- a partnership between Aviation Partners Inc., of Seattle, and The Boeing Company, of Chicago -- manufactures Blended Winglets, a unique design featured on Boeing aircraft around the world. These winglets have saved more than 2 billion gallons of jet fuel to date, representing a cost savings of more than $4 billion and a reduction of almost 21.5 million tons in carbon dioxide emissions.

Comet Christensen Has Carbon Gas

NASA Image and Video Library

2015-11-23

An expanded view of comet C/2006 W3 (Christensen) is shown here. The WISE spacecraft observed this comet on April 20th, 2010 as it traveled through the constellation Sagittarius. Comet Christensen was nearly 370 million miles (600 million kilometers) from Earth at the time. The extent of the dust, about a tenth of a degree across in this image, is about 2/3rds the diameter of the sun. The red contours show the signal from the gas emission observed by the WISE spacecraft in the 4.6 micron wavelength channel, which contains carbon monoxide (CO) and carbon dioxide (CO2) emission lines. The strength of the 4.6 micron signal indicates over half a metric ton per second of CO or CO2 was emitted from this comet at the time of the observations. The WISE spacecraft was put into hibernation in 2011 upon completing its goal of surveying the entire sky in infrared light. WISE cataloged three quarters of a billion objects, including asteroids, stars and galaxies. In August 2013, NASA decided to reinstate the spacecraft on a mission to find and characterize more asteroids. http://photojournal.jpl.nasa.gov/catalog/PIA20119

Plans moving to tap Rocky Mountain and Eastern US coal for innovative projects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1980-02-18

Energy Transition Corp. is conducting a study for W.R. Grace and Co. to determine the feasibility of using coal-derived methanol and liquefied carbon dioxide to transport coal in a proposed $500 million coal slurry pipeline from northwestern Colorado to an as-yet unchosen destination. If, as expected, the study shows that the three products can be separated upon delivery, and if suitable synthetic fuels legislation is passed, Grace would decide whether to proceed with the project, which would use technology developed by Koppers Co., Inc., to produce 5000 tons/day of fuel-grade methanol. Permitting and construction would probably take at least fivemore » years. With funding by the US Department of Energy for the initial stages, the Ashland Synthetic Fuels Inc./Airco Energy Co., Inc., Breckenridge Project will plan an H-Coal process plant that will convert 18,000 tons/day of coal to about 50,000 bbl/day of liquid hydrocarbons. The site will be Addison in Breckenridge County, Ky., and the project will probably use high-sulfur Illinois basin coal. The design and construction of the $1.5 billion commercial plant would require about 6.5 yr.« less

Fuel miles and the blend wall: costs and emissions from ethanol distribution in the United States.

PubMed

Strogen, Bret; Horvath, Arpad; McKone, Thomas E

2012-05-15

From 1991 to 2009, U.S. production of ethanol increased 10-fold, largely due to government programs motivated by climate change, energy security, and economic development goals. As low-level ethanol-gasoline blends have not consistently outperformed ethanol-free gasoline in vehicle performance or tailpipe emissions, national-level economic and environmental goals could be accomplished more efficiently by concentrating consumption of gasoline containing 10% ethanol (i.e., E10) near producers to minimize freight activity. As the domestic transportation of ethanol increased 10-fold in metric ton-kilometers (t-km) from 2000 to 2009, the portion of t-km potentially justified by the E10 blend wall increased from less than 40% to 80%. However, we estimate 10 billion t-km took place annually from 2004 to 2009 for reasons other than the blend wall. This "unnecessary" transportation resulted in more than $240 million in freight costs, 90 million L of diesel consumption, 300,000 metric tons of CO(2)-e emissions, and 440 g of human intake of PM(2.5). By 2009, the marginal savings from enabling Iowa to surpass E10 would have exceeded 2.5 g CO(2)-e/MJ and $0.12/gallon of ethanol, as the next-closest customer was 1600 km away. The use of a national network model enables estimation of marginal transportation impacts from subnational policies, and benefits from policies encouraging concentrated consumption of renewable fuels.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Malhotra, Vivak

The USA is embarking upon tackling the serious environmental challenges posed to the world by greenhouse gases, especially carbon dioxide (CO2). The dimension of the problem is daunting. In fact, according to the Energy Information Agency, nearly 6 billion metric tons of CO2 were produced in the USA in 2007 with coal-burning power plants contributing about 2 billion metric tons. To mitigate the concerns associated with CO2 emission, geological sequestration holds promise. Among the potential geological storage sites, unmineable coal seams and shale formations in particular show promise because of the probability of methane recovery while sequestering the CO2. However.more » the success of large-scale sequestration of CO2 in coal and shale would hinge on a thorough understanding of CO2's interactions with host reservoirs. An important parameter for successful storage of CO2 reservoirs would be whether the pressurized CO2 would remain invariant in coal and shale formations under reasonable internal and/or external perturbations. Recent research has brought to the fore the potential of induced seismicity, which may result in caprock compromise. Therefore, to evaluate the potential risks involved in sequestering CO2 in Illinois bituminous coal seams and shale, we studied: (i) the mechanical behavior of Murphysboro (Illinois) and Houchin Creek (Illinois) coals, (ii) thermodynamic behavior of Illinois bituminous coal at - 100oC ≤ T ≤ 300oC, (iii) how high pressure CO2 (up to 20.7 MPa) modifies the viscosity of the host, (iv) the rate of emission of CO2 from Illinois bituminous coal and shale cores if the cores, which were pressurized with high pressure (≤ 20.7 MPa) CO2, were exposed to an atmospheric pressure, simulating the development of leakage pathways, (v) whether there are any fractions of CO2 stored in these hosts which are resistance to emission by simply exposing the cores to atmospheric pressure, and (vi) how compressive shockwaves applied to the coal and shale cores, which were pressurized with high pressure CO2, determine the fate of sequestered CO2 in these cores. Our results suggested that Illinois bituminous coal in its unperturbed state, i.e., when not pressurized with CO2, showed large variations in the mechanical properties. Modulus varied from 0.7 GPa to 3.4 GPa even though samples were extracted from a single large chunk of coal. We did not observe any glass transition for Illinois bituminous coal at - 100oC ≤ T ≤ 300oC, however, when the coal was pressurized with CO2 at ambient ≤ P ≤ 20.7 MPa, the viscosity of the coal decreased and inversely scaled with the CO2 pressure. The decrease in viscosity as a function of pressure could pose CO2 injection problems for coal as lower viscosity would allow the solid coal to flow to plug the fractures, fissures, and cleats. Our experiments also showed a very small fraction of CO2 was absorbed in coal; and when CO2 pressurized coals were exposed to atmospheric conditions, the loss of CO2 from coals was massive. Half of the sequestered gas from the coal cores was lost in less than 20 minutes. Our shockwave experiments on Illinois bituminous coal, New Albany shale (Illinois), Devonian shale (Ohio), and Utica shale (Ohio) presented clear evidence that the significant emission of the sequestered CO2 from these formations cannot be discounted during seismic activity, especially if caprock is compromised. It is argued that additional shockwave studies, both compressive and transverse, would be required for successfully mapping the risks associated with sequestering high pressure CO2 in coal and shale formations.« less

The financial attractiveness assessment of large waste management projects registered as clean development mechanism.

PubMed

Bufoni, André Luiz; Oliveira, Luciano Basto; Rosa, Luiz Pinguelli

2015-09-01

This study illustrates the financial analyses for demonstration and assessment of additionality presented in the project design (PDD) and enclosed documents of the 431 large Clean Development Mechanisms (CDM) classified as the 'waste handling and disposal sector' (13) over the past ten years (2004-2014). The expected certified emissions reductions (CER) of these projects total 63.54 million metric tons of CO2eq, where eight countries account for 311 projects and 43.36 million metric tons. All of the projects declare themselves 'not financially attractive' without CER with an estimated sum of negative results of approximately a half billion US$. The results indicate that WM benchmarks and indicators are converging and reducing in variance, and the sensitivity analysis reveals that revenues have a greater effect on the financial results. This work concludes that an extensive financial database with simple standards for disclosure would greatly diminish statement problems and make information more comparable, reducing the risk and capital costs of WM projects. Copyright © 2015 Elsevier Ltd. All rights reserved.

Life cycle analyses of CO2, energy, and cost for four different routes of microalgal bioenergy conversion.

PubMed

Ventura, Jey-R S; Yang, Benqin; Lee, Yong-Woo; Lee, Kisay; Jahng, Deokjin

2013-06-01

With a target production of 1000 ton of dry algae/yr, lipid content of 30 wt.%, and productivity of 30 g/m(2)-d in a 340-day annual operation, four common scenarios of microalgae bioenergy routes were assessed in terms of cost, energy, and CO2 inputs and outputs. Scenario 1 (biodiesel production), Scenario 2 (Scenario 1 with integrated anaerobic digestion system), Scenario 3 (biogas production), and Scenario 4 (supercritical gasification) were evaluated. Scenario 4 outperformed other scenarios in terms of net energy production (1282.42 kWh/ton algae) and CO2 removal (1.32 ton CO2/ton algae) while Scenario 2 surpassed the other three scenarios in terms of net cost. Scenario 1 produced the lowest energy while Scenario 3 was the most expensive bioenergy system. This study evaluated critical parameters that could direct the proper design of the microalgae bioenergy system with an efficient energy production, CO2 removal, and economic feasibility. Copyright © 2013 Elsevier Ltd. All rights reserved.

40 CFR 98.476 - Data reporting requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... volumetric. (b) If you receive CO2 in containers, report: (1) The mass (in metric tons) or volume at standard... quarter. (3) The mass (in metric tons) or volume (in standard cubic meters) of contents in containers that... total mass of CO2 received (in metric tons) annually. (5) The standard or method used to calculate each...

Energy production for environmental issues in Turkey

NASA Astrophysics Data System (ADS)

Yuksel, Ibrahim; Arman, Hasan; Halil Demirel, Ibrahim

2017-11-01

Due to the diversification efforts of energy sources, use of natural gas that was newly introduced into Turkish economy, has been growing rapidly. Turkey has large reserves of coal, particularly of lignite. The proven lignite reserves are 8.0 billion tons. The estimated total possible reserves are 30 billion tons. Turkey, with its young population and growing energy demand per person, its fast growing urbanization, and its economic development, has been one of the fast growing power markets of the world for the last two decades. It is expected that the demand for electric energy in Turkey will be 580 billion kWh by the year 2020. Turkey's electric energy demand is growing about 6-8% yearly due to fast economic growing. This paper deals with energy demand and consumption for environmental issues in Turkey.

40 CFR 98.426 - Data reporting requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... flow meter in your process chain in relation to the points of CO2 stream capture, dehydration... measure CO2 concentration. (7) The location of the flow meter in your process chain in relation to the... through subsequent flow meter(s) in metric tons. (iii) The total annual CO2 mass supplied in metric tons...

Energy Information Administration quarterly coal report, October--December 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-05-21

The United States produced just over 1 billion short tons of coal in 1992, 0.4 percent more than in 1991. Most of the 4-million-short-ton increase in coal production occurred west of the Mississippi River, where a record level of 408 million short tons of coal was produced. The amount of coal received by domestic consumers in 1992 totaled 887 million short tons. This was 7 million short tons more than in 1991, primarily due to increased coal demand from electric utilities. The average price of delivered coal to each sector declined by about 2 percent. Coal consumption in 1992 wasmore » 893 million short tons, only 1 percent higher than in 1991, due primarily to a 1-percent increase in consumption at electric utility plants. Consumer coal stocks at the end of 1992 were 163 million short tons, a decrease of 3 percent from the level at the end of 1991, and the lowest year-end level since 1989. US coal exports fell 6 percent from the 1991 level to 103 million short tons in 1992. Less coal was exported to markets in Europe, Asia, and South America, but coal exports to Canada increased 4 million short tons.« less

40 CFR Table N-1 to Subpart N of... - CO2 Emission Factors for Carbonate-Based Raw Materials

Code of Federal Regulations, 2011 CFR

2011-07-01

...-Based Raw Materials N Table N-1 to Subpart N of Part 98 Protection of Environment ENVIRONMENTAL... Raw Materials Carbonate-basedraw material—mineral CO2 emission factor a Limestone—CaCO3 0.440 Dolomite... in units of metric tons of CO2 emitted per metric ton of carbonate-based raw material charged to the...

Monitoring Ocean CO2 Fluxes from Space: GOSAT and OCO-2

NASA Technical Reports Server (NTRS)

Crisp, David

2012-01-01

The ocean is a major component of the global carbon cycle, emitting over 330 billion tons of carbon dioxide (CO2) into the atmosphere each year, or about 10 times that emitted fossil fuel combustion and all other human activities [1, 2]. The ocean reabsorbs a comparable amount of CO2 each year, along with 25% of the CO2 emitted by these human activities. The nature and geographic distribution of the processes controlling these ocean CO2 fluxes are still poorly constrained by observations. A better understanding of these processes is essential to predict how this important CO2 sink may evolve as the climate changes.While in situ measurements of ocean CO2 fluxes can be very precise, the sampling density is far too sparse to quantify ocean CO2 sources and sinks over much of the globe. One way to improve the spatial resolution, coverage, and sampling frequency is to make observations of the column averaged CO2 dry air mole fraction, XCO2, from space [4, 5, 6]. Such measurements could provide global coverage at high resolution (< 100 km) on monthly time scales. High precision (< 1 part per million, ppm) is essential to resolve the small, near-surface CO2 variations associated with ocean fluxes and to better constrain the CO2 transport over the ocean. The Japanese Greenhouse gases Observing Satellite (GOSAT) and the NASA Orbiting Carbon Observatory (OCO) were first two space based sensors designed specifically for this task. GOSAT was successfully launched on January 23, 2009, and has been returning measurements of XCO2 since April 2009. The OCO mission was lost in February 2009, when its launch vehicle malfunctioned and failed to reach orbit. In early 2010, NASA authorized a re-flight of OCO, called OCO-2, which is currently under development.

Life cycle assessment on food waste and its application in China

NASA Astrophysics Data System (ADS)

Gao, Si; Bao, Jingling; Liu, Xiaojie; Stenmarck, Asa

2018-01-01

Food waste causes tremendous problems in terms of environment and economy, twined with big social influence, thus studies on food waste are essential and meanwhile very complicated According to Food and Agriculture Organization of the United Nations (FAO), 1.3 billion ton/year of food are wasted globally, which has a total carbon footprint of 4.4 GtCO2 eq per year with a cost of USD 411 billion. According to statistics, China has roughly 195 million tons food waste per year, which is huge. Life Cycle Assessment (LCA), which is an internationally standardized method by ISO for assessment of product and process, has been applied in food sectors to evaluate the different environmental influence, energy use etc. This paper analyzed some of the LCA application on the different parts of the food supply chain (production, post-harvest handling, the storage and transportation, processing, the retail, and consumption) where food waste is generated and on the food waste disposal stage, looked into what has been studied in the context of China, and gave recommendations for LCA application for Chinese food waste problems: 1) More application of LCA on food waste should be made on the early stage of the food cycle rather than just the kitchen waste; 2) Besides global warming potentials, other environmental influences should be studied more at the same time; 3) Food waste treatment can be studied using LCA broadly considering mixture with other substrates and using different recycling methods; 4) LCA based on a local context with local data/inventory are strongly needed; 5) further more detailed studies to support an elevated food waste management, such as food waste profile can be developed.

Estimation of potential biomass resource and biogas production from aquatic plants in Argentina

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fitzsimons, R.E.; Laurino, C.N.; Vallejos, R.H.

1982-01-01

The Argentine government's Agua y Energia Electrica is planning to construct a hydroelectric power-generation facility on the middle Parana River, which is already heavily infested with aquatic weeds such as water hyacinth. These species will probably proliferate in the lakes that will be formed by the power project and perhaps seriously interfere with the facility. As a solution to this problem, Argentine biochemists propose mechanical harvesting and anaerobic fermentation of the aquatic plants to produce biogas and fertilizer. According to an evaluation of this potential resource, gross methane production could reach 37-153 billion CF (1.0-4.1 billion m/sup 3/)/yr, and themore » digested residue could provide 60,500-244,000 tons (54,900-221,400 metric tons)/yr of nitrogen, which represents 2-8 times Argentina's current nitrogen fertilizer demand.« less

Changes in land use, climate and the environment during a period of rapid economic development in Jiangsu Province, China.

PubMed

Huang, Changchun; Zhang, Mingli; Zou, Jun; Zhu, A-Xing; Chen, Xia; Mi, Yin; Wang, Yanhua; Yang, Hao; Li, Yunmei

2015-12-01

Understanding changes in climate and environment on a regional scale can provide useful guidance for regional socio-economic development. The present study characterizes changes in the environment, climate, land use and cover types via in situ observed, statistical data and remote sensing images for Jiangsu Province, China, during the period 1980-2012. Statistical and spatial analyses indicate that the pace of urbanization in southern Jiangsu is more rapid than that in northern Jiangsu. Urbanization (92.7%) results primarily from the loss of farmland. While emissions of pollutants from industrial sources were well controlled, and wastewater, which more frequently derives from urban domestic sources, was found to be increasing. The rates of wastewater to population increased from 0.17±0.017 to 0.32±0.090 (billion ton/million persons) during the two periods of 1980-2000 and 2000-2012. However, the rates of wastewater to Gross Domestic Product (GDP) decreased from 0.26±0.20 to 0.014±0.009 (billion ton/billion Yuan), respectively. The significant increase in scattering radiance and Earth's albedo caused by the urbanization and its process (Pearson correlation coefficient (r) between urban land and scattering radiance=0.86, p<0.0001; r between farmland and scattering radiance=-0.92, p<0.0001) aggravates the warming in the regional scale. This correlation analysis indicates that temperature will decrease with the increase of woodland, grassland and farmland, and will increase with the increase of urbanized and unexploited lands. Added to warming caused by an increase in CO2, land use/cover change and human activities may be the primary reason for the rising temperatures in Jiangsu Province. The change in regional thermal conditions reduces both local humidity and land atmosphere flux exchange. The low atmosphere flux exhange contributes to the spread of atmospheric pollutants and the deposition of atmospheric particles. Copyright © 2015 Elsevier B.V. All rights reserved.

40 CFR 98.426 - Data reporting requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... flow meter in your process chain in relation to the points of CO2 stream capture, dehydration... concentration. (7) The location of the flow meter in your process chain in relation to the points of CO2 stream... meter(s) in metric tons. (iii) The total annual CO2 mass supplied in metric tons. (iv) The location of...

40 CFR 98.426 - Data reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... flow meter in your process chain in relation to the points of CO2 stream capture, dehydration... concentration. (7) The location of the flow meter in your process chain in relation to the points of CO2 stream... meter(s) in metric tons. (iii) The total annual CO2 mass supplied in metric tons. (iv) The location of...

40 CFR 98.426 - Data reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... flow meter in your process chain in relation to the points of CO2 stream capture, dehydration... concentration. (7) The location of the flow meter in your process chain in relation to the points of CO2 stream... meter(s) in metric tons. (iii) The total annual CO2 mass supplied in metric tons. (iv) The location of...

Mechanistic Sediment Quality Guidelines Based on Contaminant Bioavailability: Equilibrium Partitioning Sediment Benchmarks

EPA Science Inventory

Globally, billions of metric tons of contaminated sediments are present in aquatic systems representing a potentially significant ecological risk. Estimated costs to manage (i.e., remediate and monitor) these sediments are in the billions of U.S. dollars. Biologically-based app...

Freight Wing Trailer Aerodynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Graham, Sean; Bigatel, Patrick

2004-10-17

Freight Wing Incorporated utilized the opportunity presented by this DOE category one Inventions and Innovations grant to successfully research, develop, test, patent, market, and sell innovative fuel and emissions saving aerodynamic attachments for the trucking industry. A great deal of past scientific research has demonstrated that streamlining box shaped semi-trailers can significantly reduce a truck's fuel consumption. However, significant design challenges have prevented past concepts from meeting industry needs. Market research early in this project revealed the demands of truck fleet operators regarding aerodynamic attachments. Products must not only save fuel, but cannot interfere with the operation of the truck,more » require significant maintenance, add significant weight, and must be extremely durable. Furthermore, SAE/TMC J1321 tests performed by a respected independent laboratory are necessary for large fleets to even consider purchase. Freight Wing used this information to create a system of three practical aerodynamic attachments for the front, rear and undercarriage of standard semi trailers. SAE/TMC J1321 Type II tests preformed by the Transportation Research Center (TRC) demonstrated a 7% improvement to fuel economy with all three products. If Freight Wing is successful in its continued efforts to gain market penetration, the energy and environmental savings would be considerable. Each truck outfitted saves approximately 1,100 gallons of fuel every 100,000 miles, which prevents over 12 tons of CO2 from entering the atmosphere. If all applicable trailers used the technology, the country could save approximately 1.8 billion gallons of diesel fuel, 18 million tons of emissions and 3.6 billion dollars annually.« less

Iowa's forest resources in 2000

Treesearch

Joseph T. II Boykin

2003-01-01

Results of the 2000 annual inventory of Iowa show that there are as estimated 2.5 million acres of forest land; 3.2 billion cubic feet of all live volume on timberland; and 87 million dry tons of all live aboveground tree biomass on timberland. Known pathogens and pests in Iowa's forets include oak wilt and gypsy moth.

Tree biomass in the North Central Region.

Treesearch

Gerhard K. Raile; Pamela J. Jakes

1982-01-01

Methods for calculating tree biomass are outlined, and the biomass on commercial forest land is estimated for 11 north-central states. Tree biomass in the North Central Region totals 3.6 billion tons, or 50 tons per commercial forest acre. For all species, total tree biomass is concentrated in growing-stock boles.

Quantifying co-benefits of source-specific CO2 emission reductions in Canada and the US: An adjoint sensitivity analysis

NASA Astrophysics Data System (ADS)

Zhao, S.; Soltanzadeh, M.; Pappin, A. J.; Hakami, A.; Turner, M. D.; Capps, S.; Henze, D. K.; Percell, P.; Bash, J. O.; Napelenok, S. L.; Pinder, R. W.; Russell, A. G.; Nenes, A.; Baek, J.; Carmichael, G. R.; Stanier, C. O.; Chai, T.; Byun, D.; Fahey, K.; Resler, J.; Mashayekhi, R.

2016-12-01

Scenario-based studies evaluate air quality co-benefits by adopting collective measures introduced under a climate policy scenario cannot distinguish between benefits accrued from CO2 reductions among sources of different types and at different locations. Location and sector dependencies are important factors that can be captured in an adjoint-based analysis of CO2 reduction co-benefits. The present study aims to quantify how the ancillary benefits of reducing criteria co-pollutants vary spatially and by sector. The adjoint of USEPA's CMAQ was applied to quantify the health benefits associated with emission reduction of criteria pollutants (NOX) in on-road mobile, Electric Generation Units (EGUs), and other select sectors on a location-by-location basis across the US and Canada. These health benefits are then converted to CO2 emission reduction co-benefits by accounting for source-specific emission rates of criteria pollutants in comparison to CO2. We integrate the results from the adjoint of CMAQ with emission estimates from 2011 NEI at the county level, and point source data from EPA's Air Markets Program Data and National Pollutant Release Inventory (NPRI) for Canada. Our preliminary results show that the monetized health benefits (due to averted chronic mortality) associated with reductions of 1 ton of CO2 emissions is up to 65/ton in Canada and 200/ton in US for mobile on-road sector. For EGU sources, co-benefits are estimated at up to 100/ton and 10/ton for the US and Canada respectively. For Canada, the calculated co-benefits through gaseous pollutants including NOx is larger than those through PM2.5 due to the official association between NO2 exposure and chronic mortality. Calculated co-benefits show a great deal of spatial variability across emission locations for different sectors and sub-sectors. Implications of such spatial variability in devising control policy options that effectively address both climate and air quality objectives will be discussed.

Carbon dioxide and methane sorption in high volatile bituminous coals from Indiana, USA

USGS Publications Warehouse

Mastalerz, Maria; Gluskoter, Harold J.; Rupp, J.

2004-01-01

Samples of coals from several coalbeds in Indiana were analyzed for CO2 and CH4 sorption capacity using a high-pressure adsorption isotherm technique. Coal quality and petrographic composition of the coals were determined to study their relationships to the volume of CO2 and CH4 that could be sorbed into the coal. At the temperature of 17 ??C and 400 psi (??? 2.8 MPa), the coals can sorb (on dry ash-free basis) from 4 to 6.3 m3/ton (128-202 scf/ton) of CH4 and 19.5-24.6 m3/ton4 (624 to 788 scf/ton) of CO2. The ratio of CO2/CH4 at these conditions ranges from 3.5 to 5.3 and decreases with an increasing pressure for all coals. The coals studied are of a very similar coal rank (Ro from 0.48 to 0.62%) but of varying petrographic composition, and CO2 sorption volumes appear to be positively correlated to the content of maceral telocollinite. ?? 2004 Elsevier B.V. All rights reserved.

Activities of four bus terminals of Semarang City gateway and the related GHG emission

NASA Astrophysics Data System (ADS)

Huboyo, H. S.; Wardhana, I. W.; Sutrisno, E.; Wangi, L. S.; Lina, R. A.

2018-01-01

The activities of the bus terminal, including loading-unloading passengers, bus idling, and bus movements at the terminal, will emit GHG’s emission. This research analyzes GHG emission from four terminals, i.e., Mangkang, Terboyo, Penggaron, and Sukun in Semarang City. The emission was estimated by observing detail activities of public transport means, especially for moving and idling time. The emission was calculated by Tier 2 method based on the vehicle type as well as fuel consumption. The highest CO2e during vehicle movements at Sukun area was contributed by large bus about 2.08 tons/year, while at Terboyo terminal was contributed by medium bus about 347.97 tons/year. At Mangkang terminals, the highest emission for vehicle movements was attributed by medium bus as well of about 53.18 tons/year. At last, Penggaron terminal’s highest GHG emission was attributed by BRT about 26.47 tons/year. During idling time, the highest contributor to CO2e was the large bus at the three terminals, i.e., Sukun of 43.53 tons/year, Terboyo of 196.56 tons/year, and Mangkang of 84.26 tons/year, while at Penggaron, BRT dominated with CO2e of 26.47 tons/year. The management of public transport in terminals is crucial to mitigate the emission related to bus terminals activities.

Assessment of multimodal freight bottlenecks and alleviation strategies for upper Midwest region.

DOT National Transportation Integrated Search

2010-05-01

The freight that passes through the Mississippi Valley Region is high volume and has a substantial impact on the economy of the : region. According to the BTS-sponsored Commodity Flow Survey, trucks carried almost 2.5 billion tons of freight across t...

Investigate existing non-intrusive (NII) technologies for port cargo inspections.

DOT National Transportation Integrated Search

2011-09-01

"The quantity of cargo handled by United States ports has increased significantly in recent years. Based on : 2004 data, almost 2.7 billion tons of cargo passed through the ports in one year. To protect the U.S., all of this : cargo must be inspected...

Alternative Fuel Vehicle Adoption Increases Fleet Gasoline Consumption and Greenhouse Gas Emissions under United States Corporate Average Fuel Economy Policy and Greenhouse Gas Emissions Standards.

PubMed

Jenn, Alan; Azevedo, Inês M L; Michalek, Jeremy J

2016-03-01

The United States Corporate Average Fuel Economy (CAFE) standards and Greenhouse Gas (GHG) Emission standards are designed to reduce petroleum consumption and GHG emissions from light-duty passenger vehicles. They do so by requiring automakers to meet aggregate criteria for fleet fuel efficiency and carbon dioxide (CO2) emission rates. Several incentives for manufacturers to sell alternative fuel vehicles (AFVs) have been introduced in recent updates of CAFE/GHG policy for vehicles sold from 2012 through 2025 to help encourage a fleet technology transition. These incentives allow automakers that sell AFVs to meet less-stringent fleet efficiency targets, resulting in increased fleet-wide gasoline consumption and emissions. We derive a closed-form expression to quantify these effects. We find that each time an AFV is sold in place of a conventional vehicle, fleet emissions increase by 0 to 60 t of CO2 and gasoline consumption increases by 0 to 7000 gallons (26,000 L), depending on the AFV and year of sale. Using projections for vehicles sold from 2012 to 2025 from the Energy Information Administration, we estimate that the CAFE/GHG AFV incentives lead to a cumulative increase of 30 to 70 million metric tons of CO2 and 3 to 8 billion gallons (11 to 30 billion liters) of gasoline consumed over the vehicles' lifetimes - the largest share of which is due to legacy GHG flex-fuel vehicle credits that expire in 2016. These effects may be 30-40% larger in practice than we estimate here due to optimistic laboratory vehicle efficiency tests used in policy compliance calculations.

Climate, Health, Agricultural and Economic Impacts of Tighter Vehicle-Emission Standards

NASA Technical Reports Server (NTRS)

Shindell, Drew; Faluvegi, Greg; Walsh, Michael; Anenberg, Susan C.; VanDingen, Rita; Muller, Nicholas Z.; Austin, Jeff; Koch, Dorothy; Milly, George

2011-01-01

Non-CO2 air pollutants from motor vehicles have traditionally been controlled to protect air quality and health, but also affect climate. We use global composition climate modelling to examine the integrated impacts of adopting stringent European on-road vehicle-emission standards for these pollutants in 2015 in many developing countries. Relative to no extra controls, the tight standards lead to annual benefits in 2030 and beyond of 120,000-280,000 avoided premature air pollution-related deaths, 6.1-19.7 million metric tons of avoided ozone-related yield losses of major food crops, $US0.6-2.4 trillion avoided health damage and $US1.1-4.3 billion avoided agricultural damage, and mitigation of 0.20 (+0.14/-0.17) C of Northern Hemisphere extratropical warming during 2040-2070. Tighter vehicle-emission standards are thus extremely likely to mitigate short-term climate change in most cases, in addition to providing large improvements in human health and food security. These standards will not reduce CO2 emissions, however, which is required to mitigate long-term climate change.

40 CFR Appendix G to Part 75 - Determination of CO2 Emissions

Code of Federal Regulations, 2014 CFR

2014-07-01

... following procedures to estimate daily CO2 mass emissions from the combustion of fossil fuels. The optional... tons/day) from the combustion of fossil fuels. Where fuel flow is measured in a common pipe header (i.e... discharged to the atmosphere (in tons/day) as the sum of CO2 emissions from combustion and, if applicable...

40 CFR Appendix G to Part 75 - Determination of CO2 Emissions

Code of Federal Regulations, 2011 CFR

2011-07-01

... following procedures to estimate daily CO2 mass emissions from the combustion of fossil fuels. The optional... tons/day) from the combustion of fossil fuels. Where fuel flow is measured in a common pipe header (i.e... discharged to the atmosphere (in tons/day) as the sum of CO2 emissions from combustion and, if applicable...

40 CFR Appendix G to Part 75 - Determination of CO2 Emissions

Code of Federal Regulations, 2013 CFR

2013-07-01

... following procedures to estimate daily CO2 mass emissions from the combustion of fossil fuels. The optional... tons/day) from the combustion of fossil fuels. Where fuel flow is measured in a common pipe header (i.e... discharged to the atmosphere (in tons/day) as the sum of CO2 emissions from combustion and, if applicable...

40 CFR Appendix G to Part 75 - Determination of CO2 Emissions

Code of Federal Regulations, 2012 CFR

2012-07-01

... following procedures to estimate daily CO2 mass emissions from the combustion of fossil fuels. The optional... tons/day) from the combustion of fossil fuels. Where fuel flow is measured in a common pipe header (i.e... discharged to the atmosphere (in tons/day) as the sum of CO2 emissions from combustion and, if applicable...

Estimating the required logistical resources to support the development of a sustainable corn stover bioeconomy in the USA

DOE PAGES

Ebadian, Mahmood; Sokhansanj, Shahabaddine; Webb, Erin

2016-11-23

In this paper, the logistical resources required to develop a bioeconomy based on corn stover in the USA are quantified, including field equipment, storage sites, transportation and handling equipment, workforce, corn growers, and corn lands. These resources are essential to mobilize large quantities of corn stover from corn fields to biorefineries. The logistical resources are estimated over the lifetime of the biorefineries. Seventeen corn-growing states are considered for the logistical resource assessment. Over 6.8 billion gallons of cellulosic ethanol can be produced annually from 108 million dry tons of corn stover in these states. The maximum number of required fieldmore » equipment (i.e., choppers, balers, collectors, loaders, and tractors) is estimated to be 194 110 units with a total economic value of about 26 billion dollars. In addition, 40 780 trucks and flatbed trailers would be required to transport bales from corn fields and storage sites to biorefineries with a total economic value of 4.0 billion dollars. About 88 899 corn growers need to be contracted with an annual net income of over 2.1 billion dollars. About 1903 storage sites would be required to hold 53.1 million dry tons of inventory after the harvest season. These storage sites would take up about 35 320.2 acres and 4077 loaders with an economic value of 0.4 billion dollars would handle this inventory. The total required workforce to run the logistics operations is estimated to be 50 567. Furthermore, the magnitude of the estimated logistical resources demonstrates the economic and social significance of the corn stover bioeconomy in rural areas in the USA.« less

Estimating the required logistical resources to support the development of a sustainable corn stover bioeconomy in the USA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ebadian, Mahmood; Sokhansanj, Shahabaddine; Webb, Erin

In this paper, the logistical resources required to develop a bioeconomy based on corn stover in the USA are quantified, including field equipment, storage sites, transportation and handling equipment, workforce, corn growers, and corn lands. These resources are essential to mobilize large quantities of corn stover from corn fields to biorefineries. The logistical resources are estimated over the lifetime of the biorefineries. Seventeen corn-growing states are considered for the logistical resource assessment. Over 6.8 billion gallons of cellulosic ethanol can be produced annually from 108 million dry tons of corn stover in these states. The maximum number of required fieldmore » equipment (i.e., choppers, balers, collectors, loaders, and tractors) is estimated to be 194 110 units with a total economic value of about 26 billion dollars. In addition, 40 780 trucks and flatbed trailers would be required to transport bales from corn fields and storage sites to biorefineries with a total economic value of 4.0 billion dollars. About 88 899 corn growers need to be contracted with an annual net income of over 2.1 billion dollars. About 1903 storage sites would be required to hold 53.1 million dry tons of inventory after the harvest season. These storage sites would take up about 35 320.2 acres and 4077 loaders with an economic value of 0.4 billion dollars would handle this inventory. The total required workforce to run the logistics operations is estimated to be 50 567. Furthermore, the magnitude of the estimated logistical resources demonstrates the economic and social significance of the corn stover bioeconomy in rural areas in the USA.« less

National-level infrastructure and economic effects of switchgrass cofiring with coal in existing power plants for carbon mitigation.

PubMed

Morrow, William R; Griffin, W Michael; Matthews, H Scott

2008-05-15

We update a previously presented Linear Programming (LP) methodology for estimating state level costs for reducing CO2 emissions from existing coal-fired power plants by cofiring switchgrass, a biomass energy crop, and coal. This paper presents national level results of applying the methodology to the entire portion of the United States in which switchgrass could be grown without irrigation. We present incremental switchgrass and coal cofiring carbon cost of mitigation curves along with a presentation of regionally specific cofiring economics and policy issues. The results show that cofiring 189 million dry short tons of switchgrass with coal in the existing U.S. coal-fired electricity generation fleet can mitigate approximately 256 million short tons of carbon-dioxide (CO2) per year, representing a 9% reduction of 2005 electricity sector CO2 emissions. Total marginal costs, including capital, labor, feedstock, and transportation, range from $20 to $86/ton CO2 mitigated,with average costs ranging from $20 to $45/ton. If some existing power plants upgrade to boilers designed for combusting switchgrass, an additional 54 million tons of switchgrass can be cofired. In this case, total marginal costs range from $26 to $100/ton CO2 mitigated, with average costs ranging from $20 to $60/ton. Costs for states east of the Mississippi River are largely unaffected by boiler replacement; Atlantic seaboard states represent the lowest cofiring cost of carbon mitigation. The central plains states west of the Mississippi River are most affected by the boiler replacement option and, in general, go from one of the lowest cofiring cost of carbon mitigation regions to the highest. We explain the variation in transportation expenses and highlight regional cost of mitigation variations as transportation overwhelms other cofiring costs.

Specific storage volumes: A useful tool for CO2 storage capacity assessment

USGS Publications Warehouse

Brennan, S.T.; Burruss, R.C.

2006-01-01

Subsurface geologic strata have the potential to store billions of tons of anthropogenic CO2; therefore, geologic carbon sequestration can be an effective mitigation tool used to slow the rate at which levels of atmospheric CO2 are increasing. Oil and gas reservoirs, coal beds, and saline reservoirs can be used for CO2 storage; however, it is difficult to assess and compare the relative storage capacities of these different settings. Typically, CO2 emissions are reported in units of mass, which are not directly applicable to comparing the CO2 storage capacities of the various storage targets. However, if the emission values are recalculated to volumes per unit mass (specific volume) then the volumes of geologic reservoirs necessary to store CO2 emissions from large point sources can be estimated. The factors necessary to convert the mass of CO2 emissions to geologic storage volume (referred to here as Specific Storage Volume or 'SSV') can be reported in units of cubic meters, cubic feet, and petroleum barrels. The SSVs can be used to estimate the reservoir volume needed to store CO2 produced over the lifetime of an individual point source, and to identify CO2 storage targets of sufficient size to meet the demand from that given point source. These storage volumes also can then be projected onto the land surface to outline a representative "footprint," which marks the areal extent of storage. This footprint can be compared with the terrestrial carbon sequestration capacity of the same land area. The overall utility of this application is that the total storage capacity of any given parcel of land (from surface to basement) can be determined, and may assist in making land management decisions. ?? Springer Science+Business Media, LLC 2006.

Study of carbon dioxide emission inventory from transportation sector at Kualanamu International Airport

NASA Astrophysics Data System (ADS)

Suryati, I.; Indrawan, I.; Alihta, K. N.

2018-02-01

Transportation includes sources of greenhouse gas emission contributor in the form of carbon dioxide (CO2). CO2 is one of the air pollutant gases that cause climate change. The source of CO2 emissions at airports comes from road and air transportation. Kualanamu International Airport is one of the public service airports in North Sumatera Province. The purpose of this study is to inventory the emission loads generated by motor vehicles and aircraft and to forecast contributions of CO2 emissions from motor vehicles and aircraft. The research method used is quantitative and qualitative methods. The quantitative method used is to estimate emission loads of motor vehicles based on vehicle volume and emission factors derived from the literature and using the Tier-2 method to calculate the aircraft emission loads. The results for the maximum CO2 concentration were 6,206,789.37 μg/m3 and the minimal CO2 concentration was 4,070,674.84 μg/Nm3. The highest aircraft CO2 emission load is 200,164,424.5 kg/hr (1.75 x 109 ton/year) and the lowest is 38,884,064.5 kg/hr (3.40 x 108 ton/year). Meanwhile, the highest CO2 emission load from motor vehicles was 51,299.25 gr/hr (449,38 ton/year) and the lowest was 38,990.42 gr/hr (341,55 ton/year). CO2 contribution from a motor vehicle is 65% and 5% from aircraft in Kualanamu International Airport.

U.S. ARMY CORPS OF ENGINEERS ABANDONED MINE LAND REMEDIATION WORKSHOP

EPA Science Inventory

Mining activities in the US (not counting coal) produce 1-2 billion tons of mine waste annually. Since many of the ore mines involve sulfide minerals, the production of acid mine drainage (AMD) is a common problem from these abandoned mine sites. The combination of acidity, heavy...

2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy, Volume 2: Environmental Sustainability Effects of Select Scenarios from Volume 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Efroymson, Rebecca Ann; Langholtz, Matthew H.

With the goal of understanding environmental effects of a growing bioeconomy, the U.S. Department of Energy (DOE), national laboratories, and U.S. Forest Service research laboratories, together with academic and industry collaborators, undertook a study to estimate environmental effects of potential biomass production scenarios in the United States, with an emphasis on agricultural and forest biomass. Potential effects investigated include changes in soil organic carbon (SOC), greenhouse gas (GHG) emissions, water quality and quantity, air emissions, and biodiversity. Effects of altered land-management regimes were analyzed based on select county-level biomass-production scenarios for 2017 and 2040 taken from the 2016 Billion-Ton Report:more » Advancing Domestic Resources for a Thriving Bioeconomy (BT16), volume 1, which assumes that the land bases for agricultural and forestry would not change over time. The scenarios reflect constraints on biomass supply (e.g., excluded areas; implementation of management practices; and consideration of food, feed, forage, and fiber demands and exports) that intend to address sustainability concerns. Nonetheless, both beneficial and adverse environmental effects might be expected. To characterize these potential effects, this research sought to estimate where and under what modeled scenarios or conditions positive and negative environmental effects could occur nationwide. The report also includes a discussion of land-use change (LUC) (i.e., land management change) assumptions associated with the scenario transitions (but not including analysis of indirect LUC [ILUC]), analyses of climate sensitivity of feedstock productivity under a set of potential scenarios, and a qualitative environmental effects analysis of algae production under carbon dioxide (CO2) co-location scenarios. Because BT16 biomass supplies are simulated independent of a defined end use, most analyses do not include benefits from displacing fossil fuels or other products, with the exception of including a few illustrative cases on potential reductions in GHG emissions and fossil energy consumption associated with using biomass supplies for fuel, power, heat, and chemicals.« less

Cities, traffic, and CO2: A multidecadal assessment of trends, drivers, and scaling relationships

PubMed Central

Gately, Conor K.; Hutyra, Lucy R.; Sue Wing, Ian

2015-01-01

Emissions of CO2 from road vehicles were 1.57 billion metric tons in 2012, accounting for 28% of US fossil fuel CO2 emissions, but the spatial distributions of these emissions are highly uncertain. We develop a new emissions inventory, the Database of Road Transportation Emissions (DARTE), which estimates CO2 emitted by US road transport at a resolution of 1 km annually for 1980–2012. DARTE reveals that urban areas are responsible for 80% of on-road emissions growth since 1980 and for 63% of total 2012 emissions. We observe nonlinearities between CO2 emissions and population density at broad spatial/temporal scales, with total on-road CO2 increasing nonlinearly with population density, rapidly up to 1,650 persons per square kilometer and slowly thereafter. Per capita emissions decline as density rises, but at markedly varying rates depending on existing densities. We make use of DARTE’s bottom-up construction to highlight the biases associated with the common practice of using population as a linear proxy for disaggregating national- or state-scale emissions. Comparing DARTE with existing downscaled inventories, we find biases of 100% or more in the spatial distribution of urban and rural emissions, largely driven by mismatches between inventory downscaling proxies and the actual spatial patterns of vehicle activity at urban scales. Given cities’ dual importance as sources of CO2 and an emerging nexus of climate mitigation initiatives, high-resolution estimates such as DARTE are critical both for accurately quantifying surface carbon fluxes and for verifying the effectiveness of emissions mitigation efforts at urban scales. PMID:25847992

Analysis of Costs and Time Frame for Reducing CO2 Emissions by 70% in the U.S. Auto and Energy Sectors by 2050.

PubMed

Supekar, Sarang D; Skerlos, Steven J

2017-10-03

Using a least-cost optimization framework, it is shown that unless emissions reductions beyond those already in place begin at the latest by 2025 (±2 years) for the U.S. automotive sector, and by 2026 (-3 years) for the U.S. electric sector, 2050 targets to achieve necessary within-sector preventative CO 2 emissions reductions of 70% or more relative to 2010 will be infeasible. The analysis finds no evidence to justify delaying climate action in the name of reducing technological costs. Even without considering social and environmental damage costs, delaying aggressive climate action does not reduce CO 2 abatement costs even under the most optimistic trajectories for improvements in fuel efficiencies, demand, and technology costs in the U.S. auto and electric sectors. In fact, the abatement cost for both sectors is found to increase sharply with every year of delay beyond 2020. When further considering reasonable limits to technology turnover, retirements, and new capacity additions, these costs would be higher, and the feasible time frame for initiating successful climate action on the 70% by 2050 target would be shorter, perhaps having passed already. The analysis also reveals that optimistic business-as-usual scenarios in the U.S. will, conservatively, release 79-108 billion metric tons of CO 2 . This could represent up to 13% of humanity's remaining carbon budget through 2050.

40 CFR 1037.106 - Exhaust emission standards for CO2 for tractors above 26,000 pounds GVWR.

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS CONTROL OF EMISSIONS FROM NEW HEAVY-DUTY MOTOR VEHICLES... standard (g/ton-mile) for model years 2014-2016 CO2 standard (g/ton-mile) for model year 2017 and later 26...

40 CFR 1037.106 - Exhaust emission standards for CO2 for tractors above 26,000 pounds GVWR.

Code of Federal Regulations, 2014 CFR

2014-07-01

... PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS CONTROL OF EMISSIONS FROM NEW HEAVY-DUTY MOTOR VEHICLES... standard (g/ton-mile) for model years 2014-2016 CO2 standard (g/ton-mile) for model year 2017 and later 26...

40 CFR 1037.106 - Exhaust emission standards for CO2 for tractors above 26,000 pounds GVWR.

Code of Federal Regulations, 2012 CFR

2012-07-01

... PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS CONTROL OF EMISSIONS FROM NEW HEAVY-DUTY MOTOR VEHICLES... standard (g/ton-mile) for model years 2014-2016 CO2 standard (g/ton-mile) for model year 2017 and later 26...

An Analysis of Costs and Health Co-Benefits for a U.S. Power Plant Carbon Standard

PubMed Central

Buonocore, Jonathan J.; Lambert, Kathleen F.; Burtraw, Dallas; Sekar, Samantha; Driscoll, Charles T.

2016-01-01

Reducing carbon dioxide (CO2) emissions from power plants can have important “co-benefits” for public health by reducing emissions of air pollutants. Here, we examine the costs and health co-benefits, in monetary terms, for a policy that resembles the U.S. Environmental Protection Agency’s Clean Power Plan. We then examine the spatial distribution of the co-benefits and costs, and the implications of a range of cost assumptions in the implementation year of 2020. Nationwide, the total health co-benefits were $29 billion 2010 USD (95% CI: $2.3 to $68 billion), and net co-benefits under our central cost case were $12 billion (95% CI: -$15 billion to $51 billion). Net co-benefits for this case in the implementation year were positive in 10 of the 14 regions studied. The results for our central case suggest that all but one region should experience positive net benefits within 5 years after implementation. PMID:27270222

An Analysis of Costs and Health Co-Benefits for a U.S. Power Plant Carbon Standard.

PubMed

Buonocore, Jonathan J; Lambert, Kathleen F; Burtraw, Dallas; Sekar, Samantha; Driscoll, Charles T

2016-01-01

Reducing carbon dioxide (CO2) emissions from power plants can have important "co-benefits" for public health by reducing emissions of air pollutants. Here, we examine the costs and health co-benefits, in monetary terms, for a policy that resembles the U.S. Environmental Protection Agency's Clean Power Plan. We then examine the spatial distribution of the co-benefits and costs, and the implications of a range of cost assumptions in the implementation year of 2020. Nationwide, the total health co-benefits were $29 billion 2010 USD (95% CI: $2.3 to $68 billion), and net co-benefits under our central cost case were $12 billion (95% CI: -$15 billion to $51 billion). Net co-benefits for this case in the implementation year were positive in 10 of the 14 regions studied. The results for our central case suggest that all but one region should experience positive net benefits within 5 years after implementation.

Combustion characteristics and NO formation for biomass blends in a 35-ton-per-hour travelling grate utility boiler.

PubMed

Li, Zhengqi; Zhao, Wei; Li, Ruiyang; Wang, Zhenwang; Li, Yuan; Zhao, Guangbo

2009-04-01

Measurements were taken for a 35-ton-per-hour biomass-fired travelling grate boiler. Local mean concentrations of O(2), CO, SO(2) and NO gas species and gas temperatures were determined in the region above the grate. For a 28-ton-per-hour load, the mass ratios of biomass fly ash and boiler slag were 42% and 58%, the boiler efficiency was 81.56%, and the concentrations of NO(x) and SO(2) at 6% O(2) were 257 and 84 mg/m(3). For an 18-ton-per-hour load, the fuel burning zone was nearer to the inlet than it was for the 28-ton-per-hour load, and the contents of CO and NO in the fuel burning zone above the grate were lower.

Phosphate rock resources of the United States

USGS Publications Warehouse

Cathcart, James Bachelder; Sheldon, Richard Porter; Gulbrandsen, Robert A.

1984-01-01

In 1980, the United States produced about 54 million tons of phosphate rock, or about 40 percent of the world's production, of which a substantial amount was exported, both as phosphate rock and as chemical fertilizer. During the last decade, predictions have been made that easily ruinable, low-cost reserves of phosphate rock would be exhausted, and that by the end of this century, instead of being a major exporter of phosphate rock, the United States might become a net importer. Most analysts today, however, think that exports will indeed decline in the next one or two decades, but that resources of phosphate are sufficient to supply domestic needs for a long time into the future. What will happen in the future depends on the actual availability of low-cost phosphate rock reserves in the United States and in the world. A realistic understanding of future phosphate rock reserves is dependent on an accurate assessment, now, of national phosphate rock resources. Many different estimates of resources exist; none of them alike. The detailed analysis of past resource estimates presented in this report indicates that the estimates differ more in what is being estimated than in how much is thought to exist. The phosphate rock resource classification used herein is based on the two fundamental aspects of a mineral resource(l) the degree of certainty of existence and (2) the feasibility of economic recovery. The comparison of past estimates (including all available company data), combined with the writers' personal knowledge, indicates that 17 billion metric tons of identified, recoverable phosphate rock exist in the United States, of which about 7 billion metric tons are thought to be economic or marginally economic. The remaining 10 billion metric tons, mostly in the Northwestern phosphate district of Idaho, are considered to be subeconomic, ruinable when some increase in the price of phosphate occurs. More than 16 billion metric tons probably exist in the southeastern Coastal Plain phosphate province, principally in Florida and North Carolina and offshore in the shallow Atlantic Ocean from North Carolina to southern Florida. This resource is considered to be hypothetical because it is based on geologic inference combined with sparse drilling data. Total resources of phosphate rock in the United States are sufficient to supply domestic demands for the foreseeable future, provided that drilling is done to confirm hypothetical resources and the chemistry of the deposits is determined. Mining and beneficiation techniques will have to be modified or improved, and new techniques will have to be developed so that these deposits can be profitably exploited.

The role of vegetation in the CO2 flux from a tropical urban neighbourhood

NASA Astrophysics Data System (ADS)

Velasco, E.; Roth, M.; Tan, S. H.; Quak, M.; Nabarro, S. D. A.; Norford, L.

2013-03-01

Urban surfaces are usually net sources of CO2. Vegetation can potentially have an important role in reducing the CO2 emitted by anthropogenic activities in cities, particularly when vegetation is extensive and/or evergreen. Negative daytime CO2 fluxes, for example have been observed during the growing season at suburban sites characterized by abundant vegetation and low population density. A direct and accurate estimation of carbon uptake by urban vegetation is difficult due to the particular characteristics of the urban ecosystem and high variability in tree distribution and species. Here, we investigate the role of urban vegetation in the CO2 flux from a residential neighbourhood in Singapore using two different approaches. CO2 fluxes measured directly by eddy covariance are compared with emissions estimated from emissions factors and activity data. The latter includes contributions from vehicular traffic, household combustion, soil respiration and human breathing. The difference between estimated emissions and measured fluxes should approximate the biogenic flux. In addition, a tree survey was conducted to estimate the annual CO2 sequestration using allometric equations and an alternative model of the metabolic theory of ecology for tropical forests. Palm trees, banana plants and turfgrass were also included in the survey with their annual CO2 uptake obtained from published growth rates. Both approaches agree within 2% and suggest that vegetation captures 8% of the total emitted CO2 in the residential neighbourhood studied. A net uptake of 1.4 ton km-2 day-1 (510 ton km-2 yr-1 ) was estimated from the difference between the daily CO2 uptake by photosynthesis (3.95 ton km-2 ) and release by respiration (2.55 ton km-2). The study shows the importance of urban vegetation at the local scale for climate change mitigation in the tropics.

Development of sustainable corn stover harvest strategies for cellulosic ethanol

USDA-ARS?s Scientific Manuscript database

The U.S. EPA identified corn (Zea mays L.) stover as “the most economical agricultural feedstock…to meet the 16 billion gallon cellulosic biofuel requirement.” They estimated that 7.8 billion gallons of ethanol would come from 82 million tons of corn stover by 2022. POET-DSM Advanced Biofuels is con...

Assessment of Coal Geology, Resources, and Reserves in the Gillette Coalfield, Powder River Basin, Wyoming

USGS Publications Warehouse

Luppens, James A.; Scott, David C.; Haacke, Jon E.; Osmonson, Lee M.; Rohrbacher, Timothy J.; Ellis, Margaret S.

2008-01-01

The Gillette coalfield, within the Powder River Basin in east-central Wyoming, is the most prolific coalfield in the United States. In 2006, production from the coalfield totaled over 431 million short tons of coal, which represented over 37 percent of the Nation's total yearly production. The Anderson and Canyon coal beds in the Gillette coalfield contain some of the largest deposits of low-sulfur subbituminous coal in the world. By utilizing the abundance of new data from recent coalbed methane development in the Powder River Basin, this study represents the most comprehensive evaluation of coal resources and reserves in the Gillette coalfield to date. Eleven coal beds were evaluated to determine the in-place coal resources. Six of the eleven coal beds were evaluated for reserve potential given current technology, economic factors, and restrictions to mining. These restrictions included the presence of railroads, a Federal interstate highway, cities, a gas plant, and alluvial valley floors. Other restrictions, such as thickness of overburden, thickness of coal beds, and areas of burned coal were also considered. The total original coal resource in the Gillette coalfield for all eleven coal beds assessed, and no restrictions applied, was calculated to be 201 billion short tons. Available coal resources, which are part of the original coal resource that is accessible for potential mine development after subtracting all restrictions, are about 164 billion short tons (81 percent of the original coal resource). Recoverable coal, which is the portion of available coal remaining after subtracting mining and processing losses, was determined for a stripping ratio of 10:1 or less. After mining and processing losses were subtracted, a total of 77 billion short tons of coal were calculated (48 percent of the original coal resource). Coal reserves are the portion of the recoverable coal that can be mined, processed, and marketed at a profit at the time of the economic evaluation. With a discounted cash flow at 8 percent rate of return, the coal reserves estimate for the Gillette coalfield is10.1 billion short tons of coal (6 percent of the original resource total) for the 6 coal beds evaluated.

Air impacts from three alternatives for producing JP-8 jet fuel.

PubMed

Kositkanawuth, Ketwalee; Gangupomu, Roja Haritha; Sattler, Melanie L; Dennis, Brian H; MacDonnell, Frederick M; Billo, Richard; Priest, John W

2012-10-01

To increase U.S. petroleum energy independence, the University of Texas at Arlington (UT Arlington) has developed a direct coal liquefaction process which uses a hydrogenated solvent and a proprietary catalyst to convert lignite coal to crude oil. This sweet crude can be refined to form JP-8 military jet fuel, as well as other end products like gasoline and diesel. This paper presents an analysis of air pollutants resulting from using UT Arlington's liquefaction process to produce crude and then JP-8, compared with 2 alternative processes: conventional crude extraction and refining (CCER), and the Fischer-Tropsch process. For each of the 3 processes, air pollutant emissions through production of JP-8 fuel were considered, including emissions from upstream extraction/ production, transportation, and conversion/refining. Air pollutants from the direct liquefaction process were measured using a LandTEC GEM2000 Plus, Draeger color detector tubes, OhioLumex RA-915 Light Hg Analyzer, and SRI 8610 gas chromatograph with thermal conductivity detector. According to the screening analysis presented here, producing jet fuel from UT Arlington crude results in lower levels of pollutants compared to international conventional crude extraction/refining. Compared to US domestic CCER, the UTA process emits lower levels of CO2-e, NO(x), and Hg, and higher levels of CO and SO2. Emissions from the UT Arlington process for producing JP-8 are estimated to be lower than for the Fischer-Tropsch process for all pollutants, with the exception of CO2-e, which were high for the UT Arlington process due to nitrous oxide emissions from crude refining. When comparing emissions from conventional lignite combustion to produce electricity, versus UT Arlington coal liquefaction to make JP-8 and subsequent JP-8 transport, emissions from the UT Arlington process are estimated to be lower for all air pollutants, per MJ of power delivered to the end user. The United States currently imports two-thirds of its crude oil, leaving its transportation system especially vulnerable to disruptions in international crude supplies. At current use rates, U.S. coal reserves (262 billion short tons, including 23 billion short tons lignite) would last 236 years. Accordingly, the University of Texas at Arlington (UT Arlington) has developed a process that converts lignite to crude oil, at about half the cost of regular crude. According to the screening analysis presented here, producing jet fuel from UT Arlington crude generates lower levels of pollutants compared to international conventional crude extraction/refining (CCER).

Life cycle assessment of hemp cultivation and use of hemp-based thermal insulator materials in buildings.

PubMed

Zampori, Luca; Dotelli, Giovanni; Vernelli, Valeria

2013-07-02

The aim of this research is to assess the sustainability of a natural fiber, such as hemp (Cannabis sativa), and its use as thermal insulator for building applications. The sustainability of hemp was quantified by life cycle assessment (LCA) and particular attention was given to the amount of CO2eq of the whole process, and the indicator greenhouse gas protocol (GGP) was selected to quantify CO2eq emissions. In this study also CO2 uptake of hemp was considered. Two different allocation procedures (i.e., mass and economic) were adopted. Other indicators, such as Cumulative Energy Demand (CED) and EcoIndicator99 H were calculated. The production of 1 ha yielded 15 ton of hemp, whose global warming potential (GWP100) was equal to about -26.01 ton CO2eq: the amount allocated to the technical fiber (20% of the total amount of hemp biomass) was -5.52 ton CO2eq when mass allocation was used, and -5.54 ton CO2eq when economic allocation was applied. The sustainability for building applications was quantified by considering an insulation panel made by hemp fiber (85%) and polyester fiber (15%) in 1 m(2) of wall having a thermal transmittance (U) equal to 0.2 W/m(2)_K. The environmental performances of the hemp-based panel were compared to those of a rockwool-based one.

LAND REBORN: TOOLS FOR THE 21ST CENTURY/NATIONAL ASSOCIATION OF ABANDONED MINE LAND PROGRAMS

EPA Science Inventory

Mining activities in the US (not counting coal) produce 1-2 billion tons of mine waste annually. Since many of the ore mines involve sulfide minerals, the production of acid mine drainage (AMD) is a common problem from these abandoned mine sites. The combination of acidity, heavy...

Sustainable fuel for the transportation sector

PubMed Central

Agrawal, Rakesh; Singh, Navneet R.; Ribeiro, Fabio H.; Delgass, W. Nicholas

2007-01-01

A hybrid hydrogen-carbon (H2CAR) process for the production of liquid hydrocarbon fuels is proposed wherein biomass is the carbon source and hydrogen is supplied from carbon-free energy. To implement this concept, a process has been designed to co-feed a biomass gasifier with H2 and CO2 recycled from the H2-CO to liquid conversion reactor. Modeling of this biomass to liquids process has identified several major advantages of the H2CAR process. (i) The land area needed to grow the biomass is <40% of that needed by other routes that solely use biomass to support the entire transportation sector. (ii) Whereas the literature estimates known processes to be able to produce ≈30% of the United States transportation fuel from the annual biomass of 1.366 billion tons, the H2CAR process shows the potential to supply the entire United States transportation sector from that quantity of biomass. (iii) The synthesized liquid provides H2 storage in an open loop system. (iv) Reduction to practice of the H2CAR route has the potential to provide the transportation sector for the foreseeable future, using the existing infrastructure. The rationale of using H2 in the H2CAR process is explained by the significantly higher annualized average solar energy conversion efficiency for hydrogen generation versus that for biomass growth. For coal to liquids, the advantage of H2CAR is that there is no additional CO2 release to the atmosphere due to the replacement of petroleum with coal, thus eliminating the need to sequester CO2. PMID:17360377

Sustainable fuel for the transportation sector.

PubMed

Agrawal, Rakesh; Singh, Navneet R; Ribeiro, Fabio H; Delgass, W Nicholas

2007-03-20

A hybrid hydrogen-carbon (H(2)CAR) process for the production of liquid hydrocarbon fuels is proposed wherein biomass is the carbon source and hydrogen is supplied from carbon-free energy. To implement this concept, a process has been designed to co-feed a biomass gasifier with H(2) and CO(2) recycled from the H(2)-CO to liquid conversion reactor. Modeling of this biomass to liquids process has identified several major advantages of the H(2)CAR process. (i) The land area needed to grow the biomass is <40% of that needed by other routes that solely use biomass to support the entire transportation sector. (ii) Whereas the literature estimates known processes to be able to produce approximately 30% of the United States transportation fuel from the annual biomass of 1.366 billion tons, the H(2)CAR process shows the potential to supply the entire United States transportation sector from that quantity of biomass. (iii) The synthesized liquid provides H(2) storage in an open loop system. (iv) Reduction to practice of the H(2)CAR route has the potential to provide the transportation sector for the foreseeable future, using the existing infrastructure. The rationale of using H(2) in the H(2)CAR process is explained by the significantly higher annualized average solar energy conversion efficiency for hydrogen generation versus that for biomass growth. For coal to liquids, the advantage of H(2)CAR is that there is no additional CO(2) release to the atmosphere due to the replacement of petroleum with coal, thus eliminating the need to sequester CO(2).

40 CFR 98.68 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

.../metric tons Al) Individual facility records. Sa: sulfur content in baked anode (percent weight) 2.0. Asha: ash content in baked anode (percent weight) 0.4. CO2 Emissions from Sderberg Cells (VSS and HSS) MP... content in green anodes (metric tons) 0.005 × GA. BA: annual baked anode production (metric tons...

USDA's Vick tells radio audience wind farms mean huge water savings

USDA-ARS?s Scientific Manuscript database

Since most of the electricity in the U.S. is generated using coal and natural gas as fuel, almost every wind farm announcement includes the estimated amount of carbon dioxide which was not released to the atmosphere. According to Wikipedia, 2.25 tons of CO2 and 1.14 tons of CO2 were released for eve...

Quantifying and managing regional greenhouse gas emissions: waste sector of Daejeon, Korea.

PubMed

Yi, Sora; Yang, Heewon; Lee, Seung Hoon; An, Kyoung-Jin

2014-06-01

A credible accounting of national and regional inventories for the greenhouse gas (GHG) reduction has emerged as one of the most significant current discussions. This article assessed the regional GHG emissions by three categories of the waste sector in Daejeon Metropolitan City (DMC), Korea, examined the potential for DMC to reduce GHG emission, and discussed the methodology modified from Intergovernmental Panel on Climate Change and Korea national guidelines. During the last five years, DMC's overall GHG emissions were 239 thousand tons CO2 eq./year from eleven public environmental infrastructure facilities, with a population of 1.52 million. Of the three categories, solid waste treatment/disposal contributes 68%, whilst wastewater treatment and others contribute 22% and 10% respectively. Among GHG unit emissions per ton of waste treatment, the biggest contributor was waste incineration of 694 kg CO2 eq./ton, followed by waste disposal of 483 kg CO2 eq./ton, biological treatment of solid waste of 209 kg CO2 eq./ton, wastewater treatment of 0.241 kg CO2 eq./m(3), and public water supplies of 0.067 kg CO2 eq./m(3). Furthermore, it is suggested that the potential in reducing GHG emissions from landfill process can be as high as 47.5% by increasing landfill gas recovery up to 50%. Therefore, it is apparent that reduction strategies for the main contributors of GHG emissions should take precedence over minor contributors and lead to the best practice for managing GHGs abatement. Copyright © 2014 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Wisconsin's forest resources in 2002.

Treesearch

John S. Vissage; Gary J. Brand; Manfred E. Mielke

2004-01-01

Results of the 2002 annual inventory of Wisconsin show about 16.0 million acres of forest land, over 22.2 billion cubic feet of live volume on forest land, and nearly 598 million dry tons of all live aboveground tree biomass on timberland. Gypsy moth, forest tent caterpillar, twolined chestnut borer, bronze birch borer, ash yellows, and white pine blister rust were...

Cellulose nanomaterials as additives for cementitious materials

Treesearch

Tengfei Fu; Robert J. Moon; Pablo Zavatierri; Jeffrey Youngblood; William Jason Weiss

2017-01-01

Cementitious materials cover a very broad area of industries/products (buildings, streets and highways, water and waste management, and many others; see Fig. 20.1). Annual production of cements is on the order of 4 billion metric tons [2]. In general these industries want stronger, cheaper, more durable concrete, with faster setting times, faster rates of strength gain...

Manganese nodule resources in the northeastern equatorial Pacific

USGS Publications Warehouse

McKelvey, V.E.; Wright, Nancy A.; Rowland, Robert W.

1979-01-01

Recent publication of maps at scale 1:1,000,000 of the northeastern equatorial Pacific region showing publicly available information on the nickel plus copper content of manganese nodules has made it possible to outline the prime area between the Clarion and Clipperton fracture zones which has been the focus of several recent scientific and commercial studies. The area, defined as that in which the nodules contain more than 1.8 percent nickel plus copper, is about 2o5 million km2. The available evidence suggests that about half of it contains nodules in concentration (reported in wet weight units) greater than 5 kg/m2 and averaging 11.9 kg/m2. If we assume that 20 percent of the nodules in this area of 1.25 million km2 are recoverable, its potential recoverable resources are about 2.1 billion dry metric tons of nodules averaging about 25 percent Mn, 1.3 percent Ni, 1.0 percent Cu, 0.22 percent Co, and 0.05 percent Mo—enough to support about 27 mining operations each producing an average of 75 million metric tons of nodules over their lifetimes. Estimates based on other plausible assumptions would be higher or lower, but of the same order of magnitude. Thus it seems probable that the magnitude of the potentially recoverable nodule resources of the Clarion-Clipperton prime area—the most promising now known—is at most in the range of several tens of the average-size operations postulated.

Cities, traffic, and CO 2: A multidecadal assessment of trends, drivers, and scaling relationships

DOE PAGES

Gately, Conor K.; Hutyra, Lucy R.; Sue Wing, Ian

2015-04-06

Emissions of CO 2 from road vehicles were 1.57 billion metric tons in 2012, accounting for 28% of US fossil fuel CO 2 emissions, but the spatial distributions of these emissions are highly uncertain. We develop a new emissions inventory, the Database of Road Transportation Emissions (DARTE), which estimates CO 2 emitted by US road transport at a resolution of 1 km annually for 1980-2012. DARTE reveals that urban areas are responsible for 80% of on-road emissions growth since 1980 and for 63% of total 2012 emissions. We observe nonlinearities between CO 2 emissions and population density at broad spatial/temporalmore » scales, with total on-road CO 2 increasing nonlinearly with population density, rapidly up to 1,650 persons per square kilometer and slowly thereafter. Per capita emissions decline as density rises, but at markedly varying rates depending on existing densities. Here, we make use of DARTE's bottom-up construction to highlight the biases associated with the common practice of using population as a linear proxy for disaggregating national- or state-scale emissions. Comparing DARTE with existing downscaled inventories, we find biases of 100% or more in the spatial distribution of urban and rural emissions, largely driven by mismatches between inventory downscaling proxies and the actual spatial patterns of vehicle activity at urban scales. Here, given cities' dual importance as sources of CO 2 and an emerging nexus of climate mitigation initiatives, high-resolution estimates such as DARTE are critical both for accurately quantifying surface carbon fluxes and for verifying the effectiveness of emissions mitigation efforts at urban scales.« less

Energy consumption and CO2 emissions in Tibet and its cities in 2014

NASA Astrophysics Data System (ADS)

Shan, Yuli; Zheng, Heran; Guan, Dabo; Li, Chongmao; Mi, Zhifu; Meng, Jing; Schroeder, Heike; Ma, Jibo; Ma, Zhuguo

2017-08-01

Because of its low level of energy consumption and the small scale of its industrial development, the Tibet Autonomous Region has historically been excluded from China's reported energy statistics, including those regarding CO2 emissions. In this paper, we estimate Tibet's energy consumption using limited online documents, and we calculate the 2014 energy-related and process-related CO2 emissions of Tibet and its seven prefecture-level administrative divisions for the first time. Our results show that 5.52 million tons of CO2 were emitted in Tibet in 2014; 33% of these emissions are associated with cement production. Tibet's emissions per capita amounted to 1.74 tons in 2014, which is substantially lower than the national average, although Tibet's emission intensity is relatively high at 0.60 tons per thousand yuan in 2014. Among Tibet's seven prefecture-level administrative divisions, Lhasa City and Shannan Region are the two largest CO2 contributors and have the highest per capita emissions and emission intensities. The Nagqu and Nyingchi regions emit little CO2 due to their farming/pasturing-dominated economies. This quantitative measure of Tibet's regional CO2 emissions provides solid data support for Tibet's actions on climate change and emission reductions.

A Soil Service Index: Peatland soils as a case study for quantifying the value, vulnerability, and status of soils

NASA Astrophysics Data System (ADS)

Loisel, J.; Harden, J. W.; Hugelius, G.

2017-12-01

What are the most important soil services valued by land stewards and planners? Which soil-data metrics can be used to quantify each soil service? What are the steps required to quantitatively index the baseline value of soil services and their vulnerability under different land-use and climate change scenarios? How do we simulate future soil service pathways (or trajectories) under changing management regimes using process-based ecosystem models? What is the potential cost (economic, social, and other) of soil degradation under these scenarios? How sensitive or resilient are soil services to prescribed management practices, and how does sensitivity vary over space and time? We are bringing together a group of scientists and conservation organizations to answer these questions by launching Soil Banker, an open and flexible tool to quantify soil services that can be used at any scale, and by any stakeholder. Our overarching goals are to develop metrics and indices to quantify peatland soil ecosystem services, monitor change of these services, and guide management. This paper describes our methodology applied to peatlands and presents two case studies (Indonesia and Patagonia) demonstrating how Peatland Soil Banker can be deployed as an accounting tool of peatland stocks, a quantitative measure of peatland health, and as a projection of peatland degradation or enhancement under different land-use cases. Why peatlands? They store about 600 billion tons of carbon that account for ⅓ of the world's soil carbon. Peatlands have dynamic GHG exchanges of CO2, CH4, and NOx with the atmosphere, which plays a role in regulating global climate; studies indicate that peatland degradation releases about 2-3 billion tons of CO2 to the atmosphere annually. These ecosystems also provide local and regional ecosystem services: they constitute important components of the N and P cycles, store about 10% of the world's freshwater and buffer large fluxes of freshwater on an annual basis; they also support much biodiversity, including iconic species such as the orangutan in Indonesia and the guanaco in Chile. While these ecosystem services have been recognized in many sectors and a voluntary standard for a peatland carbon market is emerging, peatland services have not been systematically quantified, or accounted for, at the global level.

Managing the "other" forest: collecting and protecting nontimber forest products

Treesearch

Sally Duncan

2003-01-01

Wild harvest of nontimber forest products (NTFP) contributes to an international commercial trade in plant material—thought to be thousands of tons of raw product valued at billions of dollars. From 1991 through 1998, international trade in pharmaceutical plants alone was valued at over $1 billion, with the United States second only to China in value of...

[Valuation of forest damage cost from SO2 emission: a case study in Hunan Province].

PubMed

Hao, Jiming; Li, Ji; Duan, Lei; He, Kebin; Dai, Wennan

2002-11-01

Large amount SO2 emission caused serious damage of forest ecosystem in China and calculation of the damage cost is an important issue for policy-making. However, no applicable method was developed to estimate forest damage under different SO2 emission scenarios. Basing on previous field researches on sulfur-related forest impact in China and recent critical load mapping research, this paper presented a model for forest damage calculation by developing a dose-response function that related the damage to cumulative sulfur critical loads. This model was applied to the forests in Hunan, a province in acid rain control zone in China. Results showed that in the business-as-usual case, SO2 emission in Hunan will increase by 120% from 1995 (8.82 mil. ton) to 2020 (19.56 mil. ton), but damage cost will increase by 4.3 times, reaching 6.19 billion RMB in 2020. Results also showed the measures for SO2 control were cost-effective because the marginal damage cost will be about 6000 RMB per ton SO2 in 2020 in BAU case. At current SO2 emission level, marginal benefit will be about 1500 RMB per ton. Uncertainty analysis demonstrated that this model provides reasonable damage estimates and would therefore be applicable in a broad range of policy settings.

Radiocarbon as a Reactive Tracer for Tracking Permanent CO 2 Storage in Basaltic Rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matter, Juerg; Stute, Martin; Schlosser, Peter

In view of concerns about the long-term integrity and containment of CO 2 storage in geologic reservoirs, many efforts have been made to improve the monitoring, verification and accounting methods for geologically stored CO 2. Our project aimed to demonstrate that carbon-14 ( 14C) could be used as a reactive tracer to monitor geochemical reactions and evaluate the extent of mineral trapping of CO 2 in basaltic rocks. The capacity of a storage reservoir for mineral trapping of CO 2 is largely a function of host rock composition. Mineral carbonation involves combining CO 2 with divalent cations including Ca 2+,more » Mg 2+ and Fe 2+. The most abundant geological sources for these cations are basaltic rocks. Based on initial storage capacity estimates, we know that basalts have the necessary capacity to store million to billion tons of CO 2 via in situ mineral carbonation. However, little is known about CO2-fluid-rock reactions occurring in a basaltic storage reservoir during and post-CO 2 injection. None of the common monitoring and verification techniques have been able to provide a surveying tool for mineral trapping. The most direct method for quantitative monitoring and accounting involves the tagging of the injected CO 2 with 14C because 14C is not present in deep geologic reservoirs prior to injection. Accordingly, we conducted two CO 2 injection tests at the CarbFix pilot injection site in Iceland to study the feasibility of 14C as a reactive tracer for monitoring CO 2-fluid-rock reactions and CO 2 mineralization. Our newly developed monitoring techniques, using 14C as a reactive tracer, have been successfully demonstrated. For the first time, permanent and safe disposal of CO 2 as environmentally benign carbonate minerals in basaltic rocks could be shown. Over 95% of the injected CO 2 at the CarbFix pilot injection site was mineralized to carbonate minerals in less than two years after injection. Our monitoring results confirm that CO 2 mineralization in basaltic rocks is far faster than previously postulated.« less

Reducing CO2-Emission by using Eco-Cements

NASA Astrophysics Data System (ADS)

Voit, K.; Bergmeister, K.; Janotka, I.

2012-04-01

CO2 concentration in the air is rising constantly. Globally, cement companies are emitting nearly two billion tonnes/year of CO2 (or around 6 to 7 % of the planet's total CO2 emissions) by producing portland cement clinker. At this pace, by 2025 the cement industry will be emitting CO2 at a rate of 3.5 billion tones/year causing enormous environmental damage (Shi et al., 2011; Janotka et al., 2012). At the dawn of the industrial revolution in the mid-eighteenth century the concentration of CO2 was at a level of ca. 280 ppm. 200 years later at the time of World War II the CO2 level had risen to 310 ppm what results in a rate of increase of 0,15 ppm per year for that period (Shi et al., 2011). In November 2011 the CO2 concentration reached a value of 391 ppm (NOAA Earth System Research Laboratory, 2011), a rise of ca. 81 ppm in 66 years and an increased rate of around 1,2 ppm/year respectively. In the same period cement production in tons of cement has multiplied by a factor of ca. 62 (Kelly & Oss, US Geological Survey, 2010). Thus new CO2-saving eco-cement types are gaining in importance. In these cement types the energy-consuming portland cement clinker is partially replaced by latent hydraulic additives such as blast furnace slag, fly ash or zeolite. These hydraulic additives do not need to be fired in the rotary furnace. They ony need to be pulverized to the required grain size and added to the ground portland cement clinker. Hence energy is saved by skipping the engery-consuming firing process, in addition there is no CO2-degassing as there is in the case of lime burning. Therefore a research project between Austria and Slovakia, funded by the EU (Project ENVIZEO), was initiated in 2010. The main goal of this project is to develop new CEM V eco-types of cements and certificate them for common usage. CEM V is a portland clinker saving cement kind that allows the reduction of clinker to a proportion of 40-64% for CEM V/A and 20-39% for CEM V/B respectively by the input of slag sands, puzzolanes and fly ash (according to standard EN 197-1). In this context four new CEM V kinds have been created, two Austrian types based on slag and fly ash, and two Slovak types, one based on slag and fly ash, the other on slag and natural pozzolana. The pozzolana consist of zeolite of clinoptilolite type that is gained from a Slovak deposit.

Outsourcing CO2 Emissions

NASA Astrophysics Data System (ADS)

Davis, S. J.; Caldeira, K. G.

2009-12-01

CO2 emissions from the burning of fossil fuels are the primary cause of global warming. Much attention has been focused on the CO2 directly emitted by each country, but relatively little attention has been paid to the amount of emissions associated with consumption of goods and services in each country. This consumption-based emissions inventory differs from the production-based inventory because of imports and exports of goods and services that, either directly or indirectly, involved CO2 emissions. Using the latest available data and reasonable assumptions regarding trans-shipment of embodied carbon through third-party countries, we developed a global consumption-based CO2 emissions inventory and have calculated associated consumption-based energy and carbon intensities. We find that, in 2004, 24% of CO2 emissions are effectively outsourced to other countries, with much of the developed world outsourcing CO2 emissions to emerging markets, principally China. Some wealthy countries, including Switzerland and Sweden, outsource over half of their consumption-based emissions, with many northern Europeans outsourcing more than three tons of emissions per person per year. The United States is both a big importer and exporter of emissions embodied in trade, outsourcing >2.6 tons of CO2 per person and at the same time as >2.0 tons of CO2 per person are outsourced to the United States. These large flows indicate that CO2 emissions embodied in trade must be taken into consideration when considering responsibility for increasing atmospheric greenhouse gas concentrations.

The comparison of fossil carbon fraction and greenhouse gas emissions through an analysis of exhaust gases from urban solid waste incineration facilities.

PubMed

Kim, Seungjin; Kang, Seongmin; Lee, Jeongwoo; Lee, Seehyung; Kim, Ki-Hyun; Jeon, Eui-Chan

2016-10-01

In this study, in order to understand accurate calculation of greenhouse gas emissions of urban solid waste incineration facilities, which are major waste incineration facilities, and problems likely to occur at this time, emissions were calculated by classifying calculation methods into 3 types. For the comparison of calculation methods, the waste characteristics ratio, dry substance content by waste characteristics, carbon content in dry substance, and (12)C content were analyzed; and in particular, CO2 concentration in incineration gases and (12)C content were analyzed together. In this study, 3 types of calculation methods were made through the assay value, and by using each calculation method, emissions of urban solid waste incineration facilities were calculated then compared. As a result of comparison, with Calculation Method A, which used the default value as presented in the IPCC guidelines, greenhouse gas emissions were calculated for the urban solid waste incineration facilities A and B at 244.43 ton CO2/day and 322.09 ton CO2/day, respectively. Hence, it showed a lot of difference from Calculation Methods B and C, which used the assay value of this study. It is determined that this was because the default value as presented in IPCC, as the world average value, could not reflect the characteristics of urban solid waste incineration facilities. Calculation Method B indicated 163.31 ton CO2/day and 230.34 ton CO2/day respectively for the urban solid waste incineration facilities A and B; also, Calculation Method C indicated 151.79 ton CO2/day and 218.99 ton CO2/day, respectively. This study intends to compare greenhouse gas emissions calculated using (12)C content default value provided by the IPCC (Intergovernmental Panel on Climate Change) with greenhouse gas emissions calculated using (12)C content and waste assay value that can reflect the characteristics of the target urban solid waste incineration facilities. Also, the concentration and (12)C content were calculated by directly collecting incineration gases of the target urban solid waste incineration facilities, and greenhouse gas emissions of the target urban solid waste incineration facilities through this survey were compared with greenhouse gas emissions, which used the previously calculated assay value of solid waste.

How many people can China support?

PubMed

Mu, G

1999-10-01

Dr. Mu Guangzong, associate professor of the People's University of China, disagrees with the assumption that China can only sustain up to 1.6 billion people. This estimate was concluded by a group of researchers from the Chinese Academy of Sciences and 70 other institutions in their study conducted in the late 1980s. Based on the hypothesis that China can produce 830 million tons of grain at maximum, the researchers concluded that the region is able to support 1.66 billion people (assuming 500-550 kg/person/year). However, Dr. Guangzong says that this assumption seriously underestimates China's capabilities. He says that the country can support up to 2.075 billion people, assuming the land can produce 830 million tons of grain at maximum. A further explanation indicates that in order to live a person needs 213 kg of grain, 25 kg of meat, 10 kg of eggs, 6 kg of vegetables, and 8 kg of vegetable oil and sugar each. All these add up to 390-400 kg of grain. In addition, both per capita consumption figures and land productivity are variables subject to technological advances, and there are other sources of food other than the land resources. However, economic development is not just about feeding the population, it is also about providing decent living standards to them. Thus, control of population growth is still important for the country.

Step 2: Enter Baseline Energy Consumption Data | Climate Action Planning

Science.gov Websites

Scope 1: Emissions (Direct Combustion) T CO2e = Tonnes of Carbon Dioxide Equivalent* Gas (T CO2e) Oil (T CO2e) Coal (T CO2e) Fleet (T CO2e) Total (T CO2e) *Metric tons of CO2 equivalent or 2.204 lbs of CO2

Forest biomass and energy-wood potential in the southern United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saucier, J.R.

1993-12-31

Timber resource data were compiled from the most recent USDA Forest Service inventory data for the 12 Southern States from Virginia to Texas. Timber resource inventories traditionally include only trees 5 inches dbh and greater and their volumes to the prevailing merchantable top diameter expressed in cubic feet, board feet, or cords. For this paper, conversion factors were developed to express timber inventories in weight and to expand the inventories to include the crowns of merchantable trees and trees less than 5 inches dbh. By so doing, the total aboveground biomass is estimated for the timberlands in the South. Themore » region contains 185 million acres of timberland. Some 14.6 billion green tons of woody biomass are present on southern timberland -- about 79 tons per acre. When mature stands are harvested, the average acre in the South has 22.2 tons of woody material left in crowns and sapling, and 5.1 tons in cull stems. Thus, an average of 27.3 green tons per acre of potential energy wood are left after conventional harvests. Conversion factors that are presented permit estimates for specific tracts, areas, counties, or states.« less

Doctor Shopping Behavior and the Diversion of Prescription Opioids.

PubMed

Simeone, Ronald

2017-01-01

"Doctor shopping" as a means of prescription opioid diversion is examined. The number and percentage of prescriptions and morphine-equivalent milligrams diverted in this manner are estimated by state and molecule for the period 2008-2012. Eleven billion prescriptions with unique patient, doctor, and pharmacy identifiers were used to construct diversion "events" that involved between 1 and 6 unique doctors and between 1 and 6 unique pharmacies. Diversion thresholds were established based on the probability of each contingency. A geographically widespread decline occurred between 2008 and 2012. The number of prescriptions diverted fell from approximately 4.30 million (1.75% of all prescriptions) in 2008 to approximately 3.37 million (1.27% of all prescriptions) in 2012, and the number of morphine-equivalent milligrams fell from approximately 6.55 metric tons (2.95% of total metric tons) in 2008 to approximately 4.87 metric tons (2.19% of total metric tons) in 2012. Diversion control efforts have likely been effective. But given increases in opioid-related deaths, opioid-related drug treatment admissions, and the more specific resurgence of heroin-related events, it is clear that additional public health measures are required.

Achieving Negative CO2 Emissions by Protecting Ocean Chemistry

NASA Astrophysics Data System (ADS)

Cannara, A.

2016-12-01

Industrial Age CO2 added 1.8 trillion tons to the atmosphere. About ¼ has dissolved in seas. The rest still dissolves, bolstered by present emissions of >30 gigatons/year. Airborne & oceanic CO2 have induced sea warming & ocean acidification*. This paper suggests a way to induce a negative CO2-emissions environment for climate & oceans - preserve the planet`s dominant CO2-sequestration system ( 1 gigaton/year via calcifying sea life**) by promptly protecting ocean chemistry via expansion of clean power for both lime production & replacement of CO2-emitting sources. Provide natural alkali (CaO, MgO…) to oceans to maintain average pH above 8.0, as indicated by marine biologists. That alkali (lime) is available from past calcifying life's limestone deposits, so can be returned safely to seas once its CO2 is removed & permanently sequestered (Carbfix, BSCP, etc.***). Limestone is a dense source of CO2 - efficient processing per mole sequestered. Distribution of enough lime is possible via cargo-ship transits - 10,000 tons lime/transit, 1 million transits/year. New Panamax ships carry 120,000 tons. Just 10,000/transit allows gradual reduction of present & past CO2 emissions effects, if coupled with combustion-power reductions. CO2 separation from limestone, as in cement plants, consumes 400kWHrs of thermal energy per ton of output lime (or CO2). To combat yearly CO2 dissolution in seas, we must produce & distribute about 10gigatons of lime/year. Only nuclear power produces the clean energy (thousands of terawatt hours) to meet this need - 1000 dedicated 1GWe reactors, processing 12 cubic miles of limestone/year & sequestering CO2 into a similar mass of basalt. Basalt is common in the world. Researchers*** report it provides good, mineralized CO2 sequestration. The numbers above allow gradual CO2 reduction in air and seas, if we return to President Kennedy's energy path: http://tinyurl.com/6xgpkfa We're on an environmental precipice due to failure to eliminate combustion power by 2000, per JFK. Brewer says oceans are in "precarious balance". Robust action now gradually restores a safer environment through ocean protection. * "A short history of ocean acidification science in the 20th century", Brewer, MBARI, 2013. ** AAAS Science, Canfield & Kump, 1 Feb. 2013. *** AAAS Science, Mattcr et alia, 10 Jun 2016.

40 CFR 98.326 - Data reporting requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... information for each mine: (a) Quarterly CH4 liberated from each ventilation monitoring point (CH4Vm), (metric tons CH4). (b) Weekly CH4 liberated from each degasification system monitoring point (metric tons CH4... degasification systems (metric tons CH4). (e) Quarterly CO2 emissions from on-site destruction of coal mine gas...

40 CFR 98.326 - Data reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... information for each mine: (a) Quarterly CH4 liberated from each ventilation monitoring point (CH4Vm), (metric tons CH4). (b) Weekly CH4 liberated from each degasification system monitoring point (metric tons CH4... degasification systems (metric tons CH4). (e) Quarterly CO2 emissions from on-site destruction of coal mine gas...

40 CFR 98.326 - Data reporting requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... information for each mine: (a) Quarterly CH4 liberated from each ventilation monitoring point, (metric tons CH4). (b) Weekly CH4 liberated from each degasification system monitoring point (metric tons CH4). (c... degasification systems (metric tons CH4). (e) Quarterly CO2 emissions from on-site destruction of coal mine gas...

40 CFR 98.326 - Data reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... information for each mine: (a) Quarterly CH4 liberated from each ventilation monitoring point (CH4Vm), (metric tons CH4). (b) Weekly CH4 liberated from each degasification system monitoring point (metric tons CH4... degasification systems (metric tons CH4). (e) Quarterly CO2 emissions from on-site destruction of coal mine gas...

Vulnerability of Permafrost Carbon Research Coordination Network

NASA Astrophysics Data System (ADS)

Schuur, E. A.; McGuire, A. D.; Canadell, J.; Harden, J. W.; Kuhry, P.; Romanovsky, V. E.; Turetsky, M. R.; Schädel, C.

2011-12-01

Approximately 1700 Pg (billion tons) of soil carbon are stored in the northern circumpolar permafrost zone, more than twice as much carbon than currently contained in the atmosphere. Permafrost thaw, and the microbial decomposition of previously frozen organic carbon, is considered one of the most likely positive feedbacks from terrestrial ecosystems to the atmosphere in a warmer world. Yet, the rate and form of release is highly uncertain but crucial for predicting the strength and timing of this carbon cycle feedback this century and beyond. Here we report on the formation of a new research coordination network (RCN) whose objective is to link biological C cycle research with well-developed networks in the physical sciences focused on the thermal state of permafrost. We found that published literature in the Science Citation Index identified with the search terms 'permafrost' and 'carbon' have increased dramatically in the last decade. Of total publications including those keywords, 86% were published since 2000, 65% since 2005, and 36% since 2008. Interconnection through this RCN is designed to produce new knowledge through research synthesis that can be used to quantify the role of permafrost carbon in driving climate change in the 21st century and beyond. An expert elicitation conducted as part of the RCN activities revealed that the total effect of carbon release from permafrost zone soils on climate is expected to be up to 30-46 Pg C over the next three decades, reaching 242-324 Pg C by 2100 and potentially up to 551-710 Pg C over the next several centuries under the strongest warming scenario presented to the group. These values, expressed in billions of tons of C in CO2 equivalents, combine the effect of C released both as CO2 and as CH4 by accounting for the greater heat-trapping capacity of CH4. Much of the actual C release by weight is expected to be in the form of CO2, with only about 3.5% of that in the form of CH4. However, the higher global warming potential of CH4 means that almost half of the effect of future permafrost zone carbon emissions on climate forcing was expected by this group to be a result of CH4 emissions from wetlands, lakes, and other oxygen-limited environments where organic matter will be decomposing. These results demonstrate the vulnerability of organic C stored in near surface permafrost to increasing temperatures. Future activities of this network include synthesizing information in formats that can be assimilated by biospheric and climate models, and that will contribute to future assessments of the IPCC.

Federally owned coal and federal lands in the Colorado Plateau region

USGS Publications Warehouse

,

1999-01-01

Federally owned coal plays a major role in the energy supply of the United States. About 1.1 billion tons of coal were produced in the United States in 1997 (U.S. Department of Energy, 1998). About 30 percent of that total, or about 330 million tons, came from Federal lands. Almost all of the Federal coal production is from Wyoming, Montana, and three States in the Colorado Plateau Region—Utah, Colorado, and New Mexico.

Assessment of coal geology, resources, and reserves in the northern Wyoming Powder River Basin

USGS Publications Warehouse

Scott, David C.; Haacke, Jon E.; Osmonson, Lee M.; Luppens, James A.; Pierce, Paul E.; Rohrbacher, Timothy J.

2010-01-01

The abundance of new borehole data from recent coal bed natural gas development in the Powder River Basin was utilized by the U.S. Geological Survey for the most comprehensive evaluation to date of coal resources and reserves in the Northern Wyoming Powder River Basin assessment area. It is the second area within the Powder River Basin to be assessed as part of a regional coal assessment program; the first was an evaluation of coal resources and reserves in the Gillette coal field, adjacent to and south of the Northern Wyoming Powder River Basin assessment area. There are no active coal mines in the Northern Wyoming Powder River Basin assessment area at present. However, more than 100 million short tons of coal were produced from the Sheridan coal field between the years 1887 and 2000, which represents most of the coal production within the northwestern part of the Northern Wyoming Powder River Basin assessment area. A total of 33 coal beds were identified during the present study, 24 of which were modeled and evaluated to determine in-place coal resources. Given current technology, economic factors, and restrictions to mining, seven of the beds were evaluated for potential reserves. The restrictions included railroads, a Federal interstate highway, urban areas, and alluvial valley floors. Other restrictions, such as depth, thickness of coal beds, mined-out areas, and areas of burned coal, were also considered. The total original coal resource in the Northern Wyoming Powder River Basin assessment area for all 24 coal beds assessed, with no restrictions applied, was calculated to be 285 billion short tons. Available coal resources, which are part of the original coal resource that is accessible for potential mine development after subtracting all restrictions, are about 263 billion short tons (92.3 percent of the original coal resource). Recoverable coal, which is that portion of available coal remaining after subtracting mining and processing losses, was determined for seven coal beds with a stripping ratio of 10:1 or less. After mining and processing losses were subtracted, a total of 50 billion short tons of recoverable coal was calculated. Coal reserves are the portion of the recoverable coal that can be mined, processed, and marketed at a profit at the time of the economic evaluation. With a discounted cash flow at 8 percent rate of return, the coal reserves estimate for the Northern Wyoming Powder River Basin assessment area is 1.5 billion short tons of coal (1 percent of the original resource total) for the seven coal beds evaluated.

Comparing the magnitude of simulated residential rebound effects from electric end-use efficiency across the US

NASA Astrophysics Data System (ADS)

Thomas, Brinda A.; Hausfather, Zeke; Azevedo, Inês L.

2014-07-01

Many US states rely on energy efficiency goals as a strategy to reduce CO2e emissions and air pollution, to minimize investments in new power plants, and to create jobs. For those energy efficiency interventions that are cost-effective, i.e., saving money and reducing energy, consumers may increase their use of energy services, or re-spend cost savings on other carbon- and energy-intensive goods and services. In this paper, we simulate the magnitude of these ‘rebound effects’ in each of the 50 states in terms of CO2e emissions, focusing on residential electric end-uses under plausible assumptions. We find that a 10% reduction in annual electricity use by a household results in an emissions’ reduction penalty ranging from 0.1 ton CO2e in California to 0.3 ton CO2e in Alabama (from potential emissions reductions of 0.3 ton CO2e and 1.6 ton CO2e, respectively, in the no rebound case). Rebound effects, percentage-wise, range from 6% in West Virginia (which has a high-carbon electricity and low electricity prices), to as high as 40% in California (which has low-carbon electricity and high electricity prices). The magnitude of rebound effects percentage-wise depends on the carbon intensity of the grid: in states with low emissions factors and higher electricity prices, such as California, the rebound effects are much larger percentage-wise than in states like Pennsylvania. Conversely, the states with larger per cent rebound effects are the ones where the implications in terms of absolute emissions changes are the smallest.

Freight in America : a new national picture

DOT National Transportation Integrated Search

2006-01-01

According to new estimates by the Bureau of Transportation Statistics (BTS) of the U.S. Department of Transportations Research and Innovative Technology Administration (RITA) and the Federal Highway Administration (FHWA), over 19 billion tons of f...

Economic evaluation on CO₂-EOR of onshore oil fields in China

DOE PAGES

Wei, Ning; Li, Xiaochun; Dahowski, Robert T.; ...

2015-06-01

Carbon dioxide enhanced oil recovery (CO₂-EOR) and sequestration in depleted oil reservoirs is a plausible option for utilizing anthropogenic CO₂ to increase oil production while storing CO₂ underground. Evaluation of the storage resources and cost of potential CO₂-EOR projects is an essential step before the commencement of large-scale deployment of such activities. In this paper, a hybrid techno-economic evaluation method, including a performance model and cost model for onshore CO₂-EOR projects, has been developed based on previous studies. Total 296 onshore oil fields, accounting for about 70% of total mature onshore oil fields in China, were evaluated by the techno-economicmore » method. The key findings of this study are summarized as follows: (1) deterministic analysis shows there are approximately 1.1 billion tons (7.7 billion barrels) of incremental crude oil and 2.2 billion tons CO₂ storage resource for onshore CO₂-EOR at net positive revenue within the Chinese oil fields reviewed under the given operating strategy and economic assumptions. (2) Sensitivity study highlights that the cumulative oil production and cumulative CO₂ storage resource are very sensitive to crude oil price, CO₂ cost, project lifetime, discount rate and tax policy. High oil price, short project lifetime, low discount rate, low CO₂ cost, and low tax policy can greatly increase the net income of the oil enterprise, incremental oil recovery and CO₂ storage resource. (3) From this techno-economic evaluation, the major barriers to large-scale deployment of CO₂-EOR include complex geological conditions, low API of crude oil, high tax policy, and lack of incentives for the CO₂-EOR project.« less

Economic evaluation on CO₂-EOR of onshore oil fields in China

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wei, Ning; Li, Xiaochun; Dahowski, Robert T.

Carbon dioxide enhanced oil recovery (CO₂-EOR) and sequestration in depleted oil reservoirs is a plausible option for utilizing anthropogenic CO₂ to increase oil production while storing CO₂ underground. Evaluation of the storage resources and cost of potential CO₂-EOR projects is an essential step before the commencement of large-scale deployment of such activities. In this paper, a hybrid techno-economic evaluation method, including a performance model and cost model for onshore CO₂-EOR projects, has been developed based on previous studies. Total 296 onshore oil fields, accounting for about 70% of total mature onshore oil fields in China, were evaluated by the techno-economicmore » method. The key findings of this study are summarized as follows: (1) deterministic analysis shows there are approximately 1.1 billion tons (7.7 billion barrels) of incremental crude oil and 2.2 billion tons CO₂ storage resource for onshore CO₂-EOR at net positive revenue within the Chinese oil fields reviewed under the given operating strategy and economic assumptions. (2) Sensitivity study highlights that the cumulative oil production and cumulative CO₂ storage resource are very sensitive to crude oil price, CO₂ cost, project lifetime, discount rate and tax policy. High oil price, short project lifetime, low discount rate, low CO₂ cost, and low tax policy can greatly increase the net income of the oil enterprise, incremental oil recovery and CO₂ storage resource. (3) From this techno-economic evaluation, the major barriers to large-scale deployment of CO₂-EOR include complex geological conditions, low API of crude oil, high tax policy, and lack of incentives for the CO₂-EOR project.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robert Finley

The Midwest Geological Sequestration Consortium (MGSC) has investigated the options for geological carbon dioxide (CO{sub 2}) sequestration in the 155,400-km{sup 2} (60,000-mi{sup 2}) Illinois Basin. Within the Basin, underlying most of Illinois, western Indiana, and western Kentucky, are relatively deeper and/or thinner coal resources, numerous mature oil fields, and deep salt-water-bearing reservoirs that are potentially capable of storing CO{sub 2}. The objective of this Assessment was to determine the technical and economic feasibility of using these geological sinks for long-term storage to avoid atmospheric release of CO{sub 2} from fossil fuel combustion and thereby avoid the potential for adverse climatemore » change. The MGSC is a consortium of the geological surveys of Illinois, Indiana, and Kentucky joined by six private corporations, five professional business associations, one interstate compact, two university researchers, two Illinois state agencies, and two consultants. The purpose of the Consortium is to assess carbon capture, transportation, and storage processes and their costs and viability in the three-state Illinois Basin region. The Illinois State Geological Survey serves as Lead Technical Contractor for the Consortium. The Illinois Basin region has annual emissions from stationary anthropogenic sources exceeding 276 million metric tonnes (304 million tons) of CO{sub 2} (>70 million tonnes (77 million tons) carbon equivalent), primarily from coal-fired electric generation facilities, some of which burn almost 4.5 million tonnes (5 million tons) of coal per year. Assessing the options for capture, transportation, and storage of the CO{sub 2} emissions within the region has been a 12-task, 2-year process that has assessed 3,600 million tonnes (3,968 million tons) of storage capacity in coal seams, 140 to 440 million tonnes (154 to 485 million tons) of capacity in mature oil reservoirs, 7,800 million tonnes (8,598 million tons) of capacity in saline reservoirs deep beneath geological structures, and 30,000 to 35,000 million tonnes (33,069 to 38,580 million tons) of capacity in saline reservoirs on a regional dip >1,219 m (4,000 ft) deep. The major part of this effort assessed each of the three geological sinks: coals, oil reservoirs, and saline reservoirs. We linked and integrated options for capture, transportation, and geological storage with the environmental and regulatory framework to define sequestration scenarios and potential outcomes for the region. Extensive use of Geographic Information Systems (GIS) and visualization technology was made to convey results to project sponsors, other researchers, the business community, and the general public. An action plan for possible technology validation field tests involving CO{sub 2} injection was included in a Phase II proposal (successfully funded) to the U.S. Department of Energy with cost sharing from Illinois Clean Coal Institute.« less

Technical and Economic Assessment of Span-Distributed Loading Cargo Aircraft Concepts

NASA Technical Reports Server (NTRS)

Johnston, W. M.; Muehlbauer, J. C.; Eudaily, R. R.; Farmer, B. T.; Monrath, J. F.; Thompson, S. G.

1976-01-01

A 700,000 kg (1,540,000-lb) aircraft with a cruise Mach number of 0.75 was found to be optimum for the specified mission parameters of a 272 155-kg (600,000-lb) payload, a 5560-km (3000-n.mi.) range, and an annual productivity of 113 billion revenue-ton km (67 billion revenue-ton n. mi.). The optimum 1990 technology level spanloader aircraft exhibited the minimum 15-year life-cycle costs, direct operating costs, and fuel consumption of all candidate versions. Parametric variations of wing sweep angle, thickness ratio, rows of cargo, and cargo density were investigated. The optimum aircraft had two parallel rows of 2.44 x 2.44-m (8 x 8-ft) containerized cargo with a density of 160 kg/cu m (10 lb/ft 3) carried throughout the entire 101-m (331-ft) span of the constant chord, 22-percent thick, supercritical wing. Additional containers or outsized equipment were carried in the 24.4-m (80-ft) long fuselage compartment preceding the wing. Six 284,000-N (64,000-lb) thrust engines were mounted beneath the 0.7-rad (40-deg) swept wing. Flight control was provided by a 36.6-m (120-ft) span canard surface mounted atop the forward fuselage, by rudders on the wingtip verticals and by outboard wing flaperons.

76 FR 57105 - Greenhouse Gas Emissions Standards and Fuel Efficiency Standards for Medium- and Heavy-Duty...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-09-15

...EPA and NHTSA, on behalf of the Department of Transportation, are each finalizing rules to establish a comprehensive Heavy-Duty National Program that will reduce greenhouse gas emissions and fuel consumption for on-road heavy-duty vehicles, responding to the President's directive on May 21, 2010, to take coordinated steps to produce a new generation of clean vehicles. NHTSA's final fuel consumption standards and EPA's final carbon dioxide (CO2) emissions standards are tailored to each of three regulatory categories of heavy-duty vehicles: Combination Tractors; Heavy-duty Pickup Trucks and Vans; and Vocational Vehicles. The rules include separate standards for the engines that power combination tractors and vocational vehicles. Certain rules are exclusive to the EPA program. These include EPA's final hydrofluorocarbon standards to control leakage from air conditioning systems in combination tractors, and pickup trucks and vans. These also include EPA's final nitrous oxide (N2O) and methane (CH4) emissions standards that apply to all heavy- duty engines, pickup trucks and vans. EPA's final greenhouse gas emission standards under the Clean Air Act will begin with model year 2014. NHTSA's final fuel consumption standards under the Energy Independence and Security Act of 2007 will be voluntary in model years 2014 and 2015, becoming mandatory with model year 2016 for most regulatory categories. Commercial trailers are not regulated in this phase of the Heavy-Duty National Program. The agencies estimate that the combined standards will reduce CO2 emissions by approximately 270 million metric tons and save 530 million barrels of oil over the life of vehicles sold during the 2014 through 2018 model years, providing over $7 billion in net societal benefits, and $49 billion in net societal benefits when private fuel savings are considered. EPA is also finalizing provisions allowing light-duty vehicle manufacturers to use CO2 credits to meet the light-duty vehicle N2O and CH4 standards, technical amendments to the fuel economy provisions for light-duty vehicles, and a technical amendment to the criteria pollutant emissions requirements for certain switch locomotives.

40 CFR 98.146 - Data reporting requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Glass Production § 98.146 Data reporting requirements. In... glass melting furnace and for all furnaces combined (tons). (2) Annual quantity of glass produced (tons). (b) If a CEMS is not used to determine CO2 emissions from continuous glass melting furnaces, and...

Oil, Earth mass and gravitational force.

PubMed

Moustafa, Khaled

2016-04-01

Fossil fuels are intensively extracted from around the world faster than they are renewed. Regardless of direct and indirect effects of such extractions on climate change and biosphere, another issue relating to Earth's internal structure and Earth mass should receive at least some interest. According to the Energy Information Administration (EIA), about 34 billion barrels of oil (~4.7 trillion metric tons) and 9 billion tons of coal have been extracted in 2014 worldwide. Converting the amounts of oil and coal extracted over the last 3 decades and their respective reserves, intended to be extracted in the future, into mass values suggests that about 355 trillion tons, or ~5.86∗10(-9) (~0.0000000058)% of the Earth mass, would be 'lost'. Although this is a tiny percentage, modeling the potential loss of Earth mass may help figuring out a critical threshold of mass loss that should not be exceeded. Here, I briefly discuss whether such loss would have any potential consequences on the Earth's internal structure and on its gravitational force based on the Newton's law of gravitation that links the attraction force between planets to their respective masses and the distance that separate them. Copyright © 2016 Elsevier B.V. All rights reserved.

Achieving waste to energy through sewage sludge gasification using hot slags: syngas production.

PubMed

Sun, Yongqi; Nakano, Jinichiro; Liu, Lili; Wang, Xidong; Zhang, Zuotai

2015-06-15

To relieve the environmental issues of sewage sludge (SS) disposal and greenhouse gas (GHG) emission in China, we proposed an integrated method for the first time to simultaneously deal with these two problems. The hot slags below 920 °C could act as a good heat carrier for sludge gasification and the increasing CO2 concentration in CO2/O2 atmospheres enhanced the production of CO and H2 at 400-800 °C. Three stages of syngas release were clearly identified by Gaussian fittings, i.e., volatile release, char transformation and fixed carbon reaction. Additionally, the effect of sulfur retention of slags and the synergy effect of the stabilization of toxic elements in the solid residuals were discovered in this study. Furthermore, a novel prototype of multiple industrial and urban systems was put forward, in which the produced CO + H2 could be utilized for direct reduced iron (DRI) production and the solid residuals of sludge ash and glassy slags would be applied as cementitious materials. For a steel plant with an annual production of crude steel of 10 million tons in China, the total annual energy saving and GHG emission reduction achieved are 3.31*10(5) tons of standard coal and 1.74*10(6) tons of CO2, respectively.

A process for capturing CO 2 from the atmosphere

DOE PAGES

Keith, David W.; Holmes, Geoffrey; St. Angelo, David; ...

2018-06-07

Here, we describe a process for capturing CO 2 from the atmosphere in an industrial plant. The design captures ~1 Mt-CO 2/year in a continuous process using an aqueous KOH sorbent coupled to a calcium caustic recovery loop. We describe the design rationale, summarize performance of the major unit operations, and provide a capital cost breakdown developed with an independent consulting engineering firm. We report results from a pilot plant which provides data on performance of the major unit operations. We summarize the energy and material balance computed using an Aspen process simulation. When CO 2 is delivered at 15more » MPa the design requires either 8.81 GJ of natural gas, or 5.25 GJ of gas and 366 kWhr of electricity, per ton of CO 2 captured. Depending on financial assumptions, energy costs, and the specific choice of inputs and outputs, the levelized cost per ton CO 2 captured from the atmosphere ranges from 94 to 232 $/t-CO 2.« less

A process for capturing CO 2 from the atmosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keith, David W.; Holmes, Geoffrey; St. Angelo, David

Here, we describe a process for capturing CO 2 from the atmosphere in an industrial plant. The design captures ~1 Mt-CO 2/year in a continuous process using an aqueous KOH sorbent coupled to a calcium caustic recovery loop. We describe the design rationale, summarize performance of the major unit operations, and provide a capital cost breakdown developed with an independent consulting engineering firm. We report results from a pilot plant which provides data on performance of the major unit operations. We summarize the energy and material balance computed using an Aspen process simulation. When CO 2 is delivered at 15more » MPa the design requires either 8.81 GJ of natural gas, or 5.25 GJ of gas and 366 kWhr of electricity, per ton of CO 2 captured. Depending on financial assumptions, energy costs, and the specific choice of inputs and outputs, the levelized cost per ton CO 2 captured from the atmosphere ranges from 94 to 232 $/t-CO 2.« less

40 CFR 98.36 - Data reporting requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... consists entirely of non-biogenic CO2 (i.e., CO2 from fossil fuel combustion plus, if applicable, CO2 from... of each gas and in metric tons of CO2e. If any of the units burn both fossil fuels and biomass, report also the annual CO2 emissions from combustion of all fossil fuels combined and annual CO2...

40 CFR 98.36 - Data reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... consists entirely of non-biogenic CO2 (i.e., CO2 from fossil fuel combustion plus, if applicable, CO2 from... of each gas and in metric tons of CO2e. If any of the units burn both fossil fuels and biomass, report also the annual CO2 emissions from combustion of all fossil fuels combined and annual CO2...

40 CFR 98.36 - Data reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... consists entirely of non-biogenic CO2 (i.e., CO2 from fossil fuel combustion plus, if applicable, CO2 from... gas and in metric tons of CO2e. If any of the units burn both fossil fuels and biomass, report also the annual CO2 emissions from combustion of all fossil fuels combined and annual CO2 emissions from...

Assessing the coal resources of the United States

USGS Publications Warehouse

Gluskoter, Harold J.; Flores, R.M.; Hatch, J.; Kirschbaum, M.A.; Ruppert, L.F.; Warwick, Peter D.

1996-01-01

In 1994, coal production in the United States reached the highest level in history (slightly more than 909 million metric tons or one billion short tons), continuing the upward trend of coal production and utilization that began 34 years ago. Previous assessments of the coal resources of the United States, which were completed as early as 1909, clearly indicated that the total coal resources of the Nation are large and that utilization at the current rate will not soon deplete them.

The difference of level CO2 emissions from the transportation sector between weekdays and weekend days on the City Centre of Pemalang

NASA Astrophysics Data System (ADS)

Sawitri, E.; Hardiman, G.; Buchori, I.

2017-06-01

The high growth of human activity potentially increases the number of vehicles and the use of fossil fuels that contribute the increase of CO2 emissions in atmosphere. Controlling CO2 emission that causes greenhouse effect becomes the main agenda of Indonesian Government. The first step control CO2 emissions is by measuring the level of CO2 emissions, especially CO2 emissions from fossil fuel consumption in the transport sector. This research aims to assess the level of CO2 emissions from transportation sector on the main roads in the city centre of Pemalang both in weekdays and weekend days. The methods applied to calculate CO2 emissions using Intergovernmental Panel on Climate Change (IPCC) 2006 method. For this, a survey on the number of vehicles passing through the main roads using hand tally counter is firstly done. The results, CO2 emissions in working day, i.e. 49,006.95 tons/year compared to weekend i.e. 38,865.50 tons/year.

Methane in the Upper Silesian Coal Basin (Poland) - problem of reserves and exploitation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wojcik, A.J.

1995-08-01

The Upper Silesian Coal Basin (USCB) is the best recognized and the most productive coal basin in Poland. The USCB is primarily defined by the extent of Carboniferous coal-bearing formations. The sedimentary fill displays the stratigraphic record of major progressive inversion phases of the entire Moravo-Silesian basin during the late and post-geosynclinal period of the Variscan orogeny. According to the last estimates the coal reserves occurring above the depth limit of 1500 in are as follows: documented reserves - 58 billion tons, prognostic reserves - 46 billion tons, total - 104 billion tons. The coal type is predominantly vitrinitic, andmore » ash content is reported to be in the range of 11-17% and average sulphur content is 1.13%. The rank of USCB coal is largely controlled by complex coalification processes. It ranges from high volatile bituminous B, through medium volatile bituminous to high rank special coal semi anthracite and anthracite. The methane content of coal seams in USCB varies in a very broad range of 0-22 m{sup 3}/t coal (dry, ash free basis). The average gas content increases considerably within the depth range 600-1000 in from 0.99 to 4.68 m{sup 3}/t coal (daf). In deeper horizons it is more or less stable varying within the range of 4.7-7.0 m{sup 3}/t coal (daf). By this estimate, on average, the methane content is about 12,5 m{sup 3}/ton. There are several estimates of coal-bed methane resources in the USCB based on different methods. The resources are as follows: documented deposits in active mines to 1000 m: 370 BCM, undeveloped deposits to 1000 in: 340 BCM, deposit between 1000 and 1500 m: 590 BCM, total: 1300 BCM. The coalbed gas from this basin is primarily composed of saturated hydrocarbons and Nitrogen which amount to 97 volume percent. The rest is dominant by Carbon dioxide and Hydrogen.« less

The public health benefits of insulation retrofits in existing housing in the United States

PubMed Central

Levy, Jonathan I; Nishioka, Yurika; Spengler, John D

2003-01-01

Background Methodological limitations make it difficult to quantify the public health benefits of energy efficiency programs. To address this issue, we developed a risk-based model to estimate the health benefits associated with marginal energy usage reductions and applied the model to a hypothetical case study of insulation retrofits in single-family homes in the United States. Methods We modeled energy savings with a regression model that extrapolated findings from an energy simulation program. Reductions of fine particulate matter (PM2.5) emissions and particle precursors (SO2 and NOx) were quantified using fuel-specific emission factors and marginal electricity analyses. Estimates of population exposure per unit emissions, varying by location and source type, were extrapolated from past dispersion model runs. Concentration-response functions for morbidity and mortality from PM2.5 were derived from the epidemiological literature, and economic values were assigned to health outcomes based on willingness to pay studies. Results In total, the insulation retrofits would save 800 TBTU (8 × 1014 British Thermal Units) per year across 46 million homes, resulting in 3,100 fewer tons of PM2.5, 100,000 fewer tons of NOx, and 190,000 fewer tons of SO2 per year. These emission reductions are associated with outcomes including 240 fewer deaths, 6,500 fewer asthma attacks, and 110,000 fewer restricted activity days per year. At a state level, the health benefits per unit energy savings vary by an order of magnitude, illustrating that multiple factors (including population patterns and energy sources) influence health benefit estimates. The health benefits correspond to $1.3 billion per year in externalities averted, compared with $5.9 billion per year in economic savings. Conclusion In spite of significant uncertainties related to the interpretation of PM2.5 health effects and other dimensions of the model, our analysis demonstrates that a risk-based methodology is viable for national-level energy efficiency programs. PMID:12740041

40 CFR 98.36 - Data reporting requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... measured by the CEMS consists entirely of non-biogenic CO2 (i.e., CO2 from fossil fuel combustion plus, if... tons of CO2e. If any of the units burn both fossil fuels and biomass, report also the annual CO2 emissions from combustion of all fossil fuels combined and annual CO2 emissions from combustion of all...

Material Science

NASA Image and Video Library

2001-04-06

This is a macro photograph of an etched surface of the Mundrabilla meteorite, a small piece of the approximately 3.9 billion-year-old meteorite that was first discovered in Western Australia in 1911. Two more giant chunks, together weighing about 17 tons, were found in 1966. Researchers can learn much from this natural crystal growth experiment since it has spent several hundred million years cooling, and would be impossible to emulate in a lab. This single slice, taken from a 6 ton piece recovered in 1966, measures only 2 square inches. The macro photograph shows a metallic iron-nickel alloy phase of kamcite (38% Ni) and taenite (6% Ni) at bottom right, bottom left, and top left. The darker material is an iron sulfide (FeS or troilite) with a parallel precipitates of duabreelite (iron chromium sulfide (FeCr2S4).

Coal Mining, Germany

NASA Image and Video Library

2001-08-01

This simulated natural color ASTER image in the German state of North Rhine Westphalia covers an area of 30 by 36 km, and was acquired on August 26, 2000. On the right side of the image are 3 enormous opencast coalmines. The Hambach opencast coal mine has recently been brought to full output capacity through the addition of the No. 293 giant bucket wheel excavator. This is the largest machine in the world; it is twice as long as a soccer field and as tall as a building with 30 floors. To uncover the 2.4 billion tons of brown coal (lignite) found at Hambach, five years were required to remove a 200-m-thick layer of waste sand and to redeposit it off site. The mine currently yields 30 million tons of lignite annually, with annual capacity scheduled to increase to 40 million tons in coming years. The image is centered at 51 degrees north latitude, 6.4 degrees east longitude. http://photojournal.jpl.nasa.gov/catalog/PIA02676

Analyzing and forecasting CO2 emission reduction in China's steel industry

NASA Astrophysics Data System (ADS)

Gao, Chengkang; Wang, Dan; Zhao, Baohua; Chen, Shan; Qin, Wei

2015-03-01

Recent measures of carbon dioxide emissions from the steel industry of China have indicated a high rate of total CO2 emissions from the industry, even compared to the rest of the world. So, CO2 emission reduction in China's steel industry was analyzed, coupling the whole process and scenarios analysis. First, assuming that all available advanced technologies are almost adopted, this study puts forward some key potential-sectors and explores an optimal technical route for reducing CO2 emissions from the Chinese steel industry based on whole process analysis. The results show that in the stages of coking, sintering, and iron making, greater potential for reducing emissions would be fulfilled by taking some technological measures. If only would above well-developed technologies be fulfill, the CO2 emissions from 5 industry production stages would be reduced substantially, and CO2 emissions per ton of steel could be decreased to 1.24 (ton/ton-steel) by 2020. At the same time, the scenarios analysis indicates that if mature carbon-reducing technologies are adopted, and if the difference between steel output growth rate and the GDP growth rate could be controlled below 3%, CO2 emissions from China's steel industry would approach the goal of reducing CO2 emissions per GDP unit by 40%-45% of the 2005 level by 2020. This indicates that the focus of carbon dioxide emissions reduction in China lies in policy adjustments in order to enhance technological application, and lies in reasonably controlling the pace of growth of GDP and steel output.

Predicting the quantifiable impacts of ISO 50001 on climate change mitigation

DOE Office of Scientific and Technical Information (OSTI.GOV)

McKane, Aimee; Therkelsen, Peter; Scodel, Anna

The ISO 50001-Energy management standard provides a continual improvement framework for organizations to reduce their energy consumption, which in the industrial and commercial (service) sectors, accounts for nearly 40% of global greenhouse gas emissions. Reducing this energy consumption will be critical for countries to achieve their national greenhouse gas reduction commitments. Several national policies already support ISO 50001; however, there is no transparent, consistent process to estimate the potential impacts of its implementation. This paper presents the ISO 50001 Impacts Methodology, an internationally-developed methodology to calculate these impacts at a national, regional, or global scale suitable for use by policymakers.more » The recently-formed ISO 50001 Global Impacts Research Network provides a forum for policymakers to refine and encourage use of the methodology. Using this methodology, a scenario with 50% of projected global industrial and service sector energy consumption under ISO 50001 management by 2030 would generate cumulative primary energy savings of approximately 105 EJ, cost savings of nearly US $700 billion (discounted to 2016 net present value), and 6500 million metric tons (Mt) of avoided CO 2 emissions. The avoided annual CO 2 emissions in 2030 alone are equivalent to removing 210 million passenger vehicles from the road.« less

Natural Carbonation of Peridotite and Applications for Carbon Storage

NASA Astrophysics Data System (ADS)

Streit, E.; Kelemen, P.; Matter, J.

2009-05-01

Natural carbonation of peridotite in the Samail Ophiolite of Oman is surprisingly rapid and could be further enhanced to provide a safe, permanent method of CO2 storage through in situ formation of carbonate minerals. Carbonate veins form by low-temperature reaction between peridotite and groundwater in a shallow weathering horizon. Reaction with peridotite drives up the pH of the water, and extensive travertine terraces form where this groundwater emerges at the surface in alkaline springs. The potential sink for CO2 in peridotite is enormous: adding 1wt% CO2 to the peridotite in Oman could consume 1/4 of all atmospheric carbon, and several peridotite bodies of comparable size exist throughout the world. Thus carbonation rate and cost, not reservoir size, are the limiting factors on the usefulness of in situ mineral carbonation of peridotite for carbon storage. The carbonate veins in Oman are much younger than previously believed, yielding average 14C ages of 28,000 years. Age data plus estimated volumes of carbonate veins and terraces suggest 10,000 to 100,000 tons per year of CO2 are consumed by these peridotite weathering reactions in Oman. This rate can be enhanced by drilling, hydraulic fracture, injecting CO2-rich fluid, and increasing reaction temperature. Drilling and hydraulic fracture can increase volume of peridotite available for reaction. Additional fracture may occur due to the solid volume increase of the carbonation reaction, and field observations suggest that such reaction-assisted fracture may be responsible for hierarchical carbonate vein networks in peridotite. Natural carbonation of peridotite in Oman occurs at low pCO2, resulting in partial carbonation of peridotite, forming magnesite and serpentine. Raising pCO2 increases carbonation efficiency, forming of magnesite + talc, or at complete carbonation, magnesite + quartz, allowing ˜30wt% CO2 to be added to the peridotite. Increasing the temperature to 185°C can improve the reaction rate by a factor of more than 100,000. Thermal modeling suggests that after an initial heating stage, CO2-rich fluids injected at relatively low temperature can be heated by exothermic carbonation reactions, offsetting diffusive heat loss to maintain optimal temperatures for rapid carbonation without additional energy input. With these enhancements, in situ carbonation could consume more than 1 billion tons of CO2 per cubic kilometer of peridotite per year. Costs associated with this method include drilling, hydraulic fracture, initial heating, CO2 capture and transport, fluid injection and monitoring. The techniques for drilling, fracture and injection are routinely used by oil companies. Compared with other carbon storage methods, in situ mineral carbonation has several advantages. It offers permanent storage that is safer and easier to monitor than storage of CO2-rich fluids in porous underground reservoirs or in the ocean. It may also be less costly than ex situ mineral carbonation, which requires quarrying and transportation of peridotite, grinding and heat treatment, reactions in pressure vessels at elevated temperature, production of catalysts, and disposal of carbonated material. An alternative method, carbonation by reaction of offshore peridotite with shallow seawater rather than CO2-rich fluids, would consume less CO2, but would avoid the costs of CO2 capture and transport inherent in other CCS methods. Drilling to depths where rocks are already close to the optimal carbonation temperature would avoid pre-heating costs and circulate water by thermal convection rather than pumping fluids.

119. NORTH PLANT GB WAREHOUSE (BUILDING 1607), WITH DISCHARGED TON ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

119. NORTH PLANT GB WAREHOUSE (BUILDING 1607), WITH DISCHARGED TON CONTAINERS IN FOREGROUND. VIEW TO SOUTHEAST. - Rocky Mountain Arsenal, Bounded by Ninety-sixth Avenue & Fifty-sixth Avenue, Buckley Road, Quebec Street & Colorado Highway 2, Commerce City, Adams County, CO

U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Downing, Mark; Eaton, Laurence M; Graham, Robin Lambert

2011-08-01

The report, Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply (generally referred to as the Billion-Ton Study or 2005 BTS), was an estimate of 'potential' biomass based on numerous assumptions about current and future inventory, production capacity, availability, and technology. The analysis was made to determine if conterminous U.S. agriculture and forestry resources had the capability to produce at least one billion dry tons of sustainable biomass annually to displace 30% or more of the nation's present petroleum consumption. An effort was made to use conservative estimates to assure confidence inmore » having sufficient supply to reach the goal. The potential biomass was projected to be reasonably available around mid-century when large-scale biorefineries are likely to exist. The study emphasized primary sources of forest- and agriculture-derived biomass, such as logging residues, fuel treatment thinnings, crop residues, and perennially grown grasses and trees. These primary sources have the greatest potential to supply large, reliable, and sustainable quantities of biomass. While the primary sources were emphasized, estimates of secondary residue and tertiary waste resources of biomass were also provided. The original Billion-Ton Resource Assessment, published in 2005, was divided into two parts-forest-derived resources and agriculture-derived resources. The forest resources included residues produced during the harvesting of merchantable timber, forest residues, and small-diameter trees that could become available through initiatives to reduce fire hazards and improve forest health; forest residues from land conversion; fuelwood extracted from forests; residues generated at primary forest product processing mills; and urban wood wastes, municipal solid wastes (MSW), and construction and demolition (C&D) debris. For these forest resources, only residues, wastes, and small-diameter trees were considered. The 2005 BTS did not attempt to include any wood that would normally be used for higher-valued products (e.g., pulpwood) that could potentially shift to bioenergy applications. This would have required a separate economic analysis, which was not part of the 2005 BTS. The agriculture resources in the 2005 BTS included grains used for biofuels production; crop residues derived primarily from corn, wheat, and small grains; and animal manures and other residues. The cropland resource analysis also included estimates of perennial energy crops (e.g., herbaceous grasses, such as switchgrass, woody crops like hybrid poplar, as well as willow grown under short rotations and more intensive management than conventional plantation forests). Woody crops were included under cropland resources because it was assumed that they would be grown on a combination of cropland and pasture rather than forestland. In the 2005 BTS, current resource availability was estimated at 278 million dry tons annually from forestlands and slightly more than 194 million dry tons annually from croplands. These annual quantities increase to about 370 million dry tons from forestlands and to nearly 1 billion dry tons from croplands under scenario conditions of high-yield growth and large-scale plantings of perennial grasses and woody tree crops. This high-yield scenario reflects a mid-century timescale ({approx}2040-2050). Under conditions of lower-yield growth, estimated resource potential was projected to be about 320 and 580 million dry tons for forest and cropland biomass, respectively. As noted earlier, the 2005 BTS emphasized the primary resources (agricultural and forestry residues and energy crops) because they represent nearly 80% of the long-term resource potential. Since publication of the BTS in April 2005, there have been some rather dramatic changes in energy markets. In fact, just prior to the actual publication of the BTS, world oil prices started to increase as a result of a burgeoning worldwide demand and concerns about long-term supplies. By the end of the summer, oil prices topped $70 per barrel (bbl) and catastrophic hurricanes in the Gulf Coast shut down a significant fraction of U.S. refinery capacity. The following year, oil approached $80 per bbl due to supply concerns, as well as continued political tensions in the Middle East. The Energy Independence and Security Act of 2007 (EISA) was enacted in December of that year. By the end of December 2007, oil prices surpassed $100 per bbl for the first time, and by mid-summer 2008, prices approached $150 per bbl because of supply concerns, speculation, and weakness of the U.S. dollar. As fast as they skyrocketed, oil prices fell, and by the end of 2008, oil prices dropped below $50 per bbl, falling even more a month later due to the global economic recession. In 2009 and 2010, oil prices began to increase again as a result of a weak U.S. dollar and the rebounding of world economies.« less

Geospatial Analysis of Near-Term Technical Potential of BECCS in the U.S.

NASA Astrophysics Data System (ADS)

Baik, E.; Sanchez, D.; Turner, P. A.; Mach, K. J.; Field, C. B.; Benson, S. M.

2017-12-01

Atmospheric carbon dioxide (CO2) removal using bioenergy with carbon capture and storage (BECCS) is crucial for achieving stringent climate change mitigation targets. To date, previous work discussing the feasibility of BECCS has largely focused on land availability and bioenergy potential, while CCS components - including capacity, injectivity, and location of potential storage sites - have not been thoroughly considered in the context of BECCS. A high-resolution geospatial analysis of both biomass production and potential geologic storage sites is conducted to consider the near-term deployment potential of BECCS in the U.S. The analysis quantifies the overlap between the biomass resource and CO2 storage locations within the context of storage capacity and injectivity. This analysis leverages county-level biomass production data from the U.S. Department of Energy's Billion Ton Report alongside potential CO2 geologic storage sites as provided by the USGS Assessment of Geologic Carbon Dioxide Storage Resources. Various types of lignocellulosic biomass (agricultural residues, dedicated energy crops, and woody biomass) result in a potential 370-400 Mt CO2 /yr of negative emissions in 2020. Of that CO2, only 30-31% of the produced biomass (110-120 Mt CO2 /yr) is co-located with a potential storage site. While large potential exists, there would need to be more than 250 50-MW biomass power plants fitted with CCS to capture all the co-located CO2 capacity in 2020. Neither absolute injectivity nor absolute storage capacity is likely to limit BECCS, but the results show regional capacity and injectivity constraints in the U.S. that had not been identified in previous BECCS analysis studies. The state of Illinois, the Gulf region, and western North Dakota emerge as the best locations for near-term deployment of BECCS with abundant biomass, sufficient storage capacity and injectivity, and the co-location of the two resources. Future studies assessing BECCS potential should employ higher-resolution spatial datasets to identify near-term deployment opportunities, explicitly including the availability of co-located storage, regional capacity limitations, and integration of electricity produced with BECCS into local electricity grids.

40 CFR 98.473 - Calculating CO2 received.

Code of Federal Regulations, 2013 CFR

2013-07-01

.... (a) You must calculate and report the annual mass of CO2 received by pipeline using the procedures in... applicable. (1) For a mass flow meter, you must calculate the total annual mass of CO2 in a CO2 stream received in metric tons by multiplying the mass flow by the CO2 concentration in the flow, according to...

40 CFR 98.473 - Calculating CO2 received.

Code of Federal Regulations, 2014 CFR

2014-07-01

.... (a) You must calculate and report the annual mass of CO2 received by pipeline using the procedures in... applicable. (1) For a mass flow meter, you must calculate the total annual mass of CO2 in a CO2 stream received in metric tons by multiplying the mass flow by the CO2 concentration in the flow, according to...

40 CFR 98.473 - Calculating CO2 received.

Code of Federal Regulations, 2011 CFR

2011-07-01

.... (a) You must calculate and report the annual mass of CO2 received by pipeline using the procedures in... applicable. (1) For a mass flow meter, you must calculate the total annual mass of CO2 in a CO2 stream received in metric tons by multiplying the mass flow by the CO2 concentration in the flow, according to...

40 CFR 98.473 - Calculating CO2 received.

Code of Federal Regulations, 2012 CFR

2012-07-01

.... (a) You must calculate and report the annual mass of CO2 received by pipeline using the procedures in... applicable. (1) For a mass flow meter, you must calculate the total annual mass of CO2 in a CO2 stream received in metric tons by multiplying the mass flow by the CO2 concentration in the flow, according to...

Sub-Saharan Africa Report No. 2809.

DTIC Science & Technology

1983-06-13

The fiscal receipts for off-shore oil in fact provide two thirds of the Congo’s finances. In 1982 4.5 million tons were produced. The beginning of...company has spent 40 billion CFA francs on exploration. The pursuit of that effort will depend on the new fiscal terms. In particular with regard...project is expected to cost a total of $48.5 mil- lion, or about 4.8 billion escudos . The Portuguese companies (SOMACO, SOMEC, J. J. Bento Pedroso and

Biochemical characterization of predicted Precambrian RuBisCO

PubMed Central

Shih, Patrick M.; Occhialini, Alessandro; Cameron, Jeffrey C.; Andralojc, P John; Parry, Martin A. J.; Kerfeld, Cheryl A.

2016-01-01

The antiquity and global abundance of the enzyme, RuBisCO, attests to the crucial and longstanding role it has played in the biogeochemical cycles of Earth over billions of years. The counterproductive oxygenase activity of RuBisCO has persisted over billions of years of evolution, despite its competition with the carboxylase activity necessary for carbon fixation, yet hypotheses regarding the selective pressures governing RuBisCO evolution have been limited to speculation. Here we report the resurrection and biochemical characterization of ancestral RuBisCOs, dating back to over one billion years ago (Gyr ago). Our findings provide an ancient point of reference revealing divergent evolutionary paths taken by eukaryotic homologues towards improved specificity for CO2, versus the evolutionary emphasis on increased rates of carboxylation observed in bacterial homologues. Consistent with these distinctions, in vivo analysis reveals the propensity of ancestral RuBisCO to be encapsulated into modern-day carboxysomes, bacterial organelles central to the cyanobacterial CO2 concentrating mechanism. PMID:26790750

Biochemical characterization of predicted Precambrian RuBisCO.

PubMed

Shih, Patrick M; Occhialini, Alessandro; Cameron, Jeffrey C; Andralojc, P John; Parry, Martin A J; Kerfeld, Cheryl A

2016-01-21

The antiquity and global abundance of the enzyme, RuBisCO, attests to the crucial and longstanding role it has played in the biogeochemical cycles of Earth over billions of years. The counterproductive oxygenase activity of RuBisCO has persisted over billions of years of evolution, despite its competition with the carboxylase activity necessary for carbon fixation, yet hypotheses regarding the selective pressures governing RuBisCO evolution have been limited to speculation. Here we report the resurrection and biochemical characterization of ancestral RuBisCOs, dating back to over one billion years ago (Gyr ago). Our findings provide an ancient point of reference revealing divergent evolutionary paths taken by eukaryotic homologues towards improved specificity for CO2, versus the evolutionary emphasis on increased rates of carboxylation observed in bacterial homologues. Consistent with these distinctions, in vivo analysis reveals the propensity of ancestral RuBisCO to be encapsulated into modern-day carboxysomes, bacterial organelles central to the cyanobacterial CO2 concentrating mechanism.

Synergies of wind power and electrified space heating: case study for Beijing.

PubMed

Chen, Xinyu; Lu, Xi; McElroy, Michael B; Nielsen, Chris P; Kang, Chongqing

2014-01-01

Demands for electricity and energy to supply heat are expected to expand by 71% and 47%, respectively, for Beijing in 2020 relative to 2009. If the additional electricity and heat are supplied solely by coal as is the current situation, annual emissions of CO2 may be expected to increase by 59.6% or 99 million tons over this interval. Assessed against this business as usual (BAU) background, the present study indicates that significant reductions in emissions could be realized using wind-generated electricity to provide a source of heat, employed either with heat pumps or with electric thermal storage (ETS) devices. Relative to BAU, reductions in CO2 with heat pumps assuming 20% wind penetration could be as large as 48.5% and could be obtained at a cost for abatement of as little as $15.6 per ton of avoided CO2. Even greater reductions, 64.5%, could be realized at a wind penetration level of 40% but at a higher cost, $29.4 per ton. Costs for reduction of CO2 using ETS systems are significantly higher, reflecting the relatively low efficiency for conversion of coal to power to heat.

Energy balances and greenhouse gas emissions of crude palm oil production system in Indonesia (Case study: Mill P, PT X, Sumatera Island)

NASA Astrophysics Data System (ADS)

Andarani, Pertiwi; Nugraha, Winardi Dwi; Wieddya

2017-03-01

Indonesia is one of the largest palm oil producers in the world. The total exported crude palm oil (CPO) and its derivatives in 2015 reached about 26.40 million tons or increase at 21% compared to the previous year (2014). However, the further expansion of the CPO production system could potentially have environmental impacts. The objective of this study is to analyze the energy balances and greenhouse gas emissions at mill P, PT X located in Sumatera Island. System analysis approaches was applied to this study and the assessment was focused on a CPO production system in PT XYZ located on the Sumatera Island. The system boundary was determined based on the field study. The data collection consisted of all the input and output energy which involving all input materials (including fertilizers, herbicides, pesticides, water, etc.) and energy consumption (consumption of diesel, electricity, etc.) starting from plantation activities (at the oil palm plantation) to the conversion process (at the palm oil mill). The energy output from biodiesel was 480.46 GJ/ha (2014) and decreased to 450.79 GJ/ha (2015). Surplus energy from biogas was 15.21 GJ/ha (2014) and 13.57 GJ/ha (2015). The NEP was 494.56 GJ/ha and decreased to 317.84 GJ/ha. Meanwhile, the NER decreased from 3.27 (2014) to 3.17 (2015). The NEP in this mill is significantly higher than other related studies of similar palm oil production system in other companies. The emission of the activities in the palm estate increased from 12.50 kgCO2eq/ton FFB to 22.057 kgCO2eq/ton FFB. In the palm oil mill, the emission decreased from 2,509.93 kgCO2eq/ton CPO to 2,057.14 kgCO2eq/ton CPO.

Towards a zero-waste oxidative coupling of nonactivated aromatics by supported gold nanoparticles.

PubMed

Serna, Pedro; Corma, Avelino

2014-08-01

We show that gold nanoparticles are able to perform the direct oxidative coupling of nonactivated aromatics with O2 as the only co-reagent. In this reaction, the aromatic acts both as reactant and solvent. Biphenyl, for example, can be obtained from benzene with high selectivity and a turnover number (TON) of 230 per pass. Similarly, several substituted biaryls can be prepared. Pd performs only one TON and even when a second catalytic functionality is introduced, together with strong acidic conditions, TON is always lower than 100. Other catalysts require iodine for performing the reaction, leading to 2 kg of waste for 1 kg of biphenyl formed, whereas no waste is created by the oxidative coupling with gold nanoparticles. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Achieving waste to energy through sewage sludge gasification using hot slags: syngas production

PubMed Central

Sun, Yongqi; Nakano, Jinichiro; Liu, Lili; Wang, Xidong; Zhang, Zuotai

2015-01-01

To relieve the environmental issues of sewage sludge (SS) disposal and greenhouse gas (GHG) emission in China, we proposed an integrated method for the first time to simultaneously deal with these two problems. The hot slags below 920 °C could act as a good heat carrier for sludge gasification and the increasing CO2 concentration in CO2/O2 atmospheres enhanced the production of CO and H2 at 400–800 °C. Three stages of syngas release were clearly identified by Gaussian fittings, i.e., volatile release, char transformation and fixed carbon reaction. Additionally, the effect of sulfur retention of slags and the synergy effect of the stabilization of toxic elements in the solid residuals were discovered in this study. Furthermore, a novel prototype of multiple industrial and urban systems was put forward, in which the produced CO + H2 could be utilized for direct reduced iron (DRI) production and the solid residuals of sludge ash and glassy slags would be applied as cementitious materials. For a steel plant with an annual production of crude steel of 10 million tons in China, the total annual energy saving and GHG emission reduction achieved are 3.31*105 tons of standard coal and 1.74*106 tons of CO2, respectively. PMID:26074060

Achieving waste to energy through sewage sludge gasification using hot slags: syngas production

NASA Astrophysics Data System (ADS)

Sun, Yongqi; Nakano, Jinichiro; Liu, Lili; Wang, Xidong; Zhang, Zuotai

2015-06-01

To relieve the environmental issues of sewage sludge (SS) disposal and greenhouse gas (GHG) emission in China, we proposed an integrated method for the first time to simultaneously deal with these two problems. The hot slags below 920 °C could act as a good heat carrier for sludge gasification and the increasing CO2 concentration in CO2/O2 atmospheres enhanced the production of CO and H2 at 400-800 °C. Three stages of syngas release were clearly identified by Gaussian fittings, i.e., volatile release, char transformation and fixed carbon reaction. Additionally, the effect of sulfur retention of slags and the synergy effect of the stabilization of toxic elements in the solid residuals were discovered in this study. Furthermore, a novel prototype of multiple industrial and urban systems was put forward, in which the produced CO + H2 could be utilized for direct reduced iron (DRI) production and the solid residuals of sludge ash and glassy slags would be applied as cementitious materials. For a steel plant with an annual production of crude steel of 10 million tons in China, the total annual energy saving and GHG emission reduction achieved are 3.31*105 tons of standard coal and 1.74*106 tons of CO2, respectively.

A Field Study on Simulation of CO 2 Injection and ECBM Production and Prediction of CO 2 Storage Capacity in Unmineable Coal Seam

DOE PAGES

He, Qin; Mohaghegh, Shahab D.; Gholami, Vida

2013-01-01

CO 2 sequestration into a coal seam project was studied and a numerical model was developed in this paper to simulate the primary and secondary coal bed methane production (CBM/ECBM) and carbon dioxide (CO 2 ) injection. The key geological and reservoir parameters, which are germane to driving enhanced coal bed methane (ECBM) and CO 2 sequestration processes, including cleat permeability, cleat porosity, CH 4 adsorption time, CO 2 adsorption time, CH 4 Langmuir isotherm, CO 2 Langmuir isotherm, and Palmer and Mansoori parameters, have been analyzed within a reasonable range. The model simulation results showed good matches for bothmore » CBM/ECBM production and CO 2 injection compared with the field data. The history-matched model was used to estimate the total CO 2 sequestration capacity in the field. The model forecast showed that the total CO 2 injection capacity in the coal seam could be 22,817 tons, which is in agreement with the initial estimations based on the Langmuir isotherm experiment. Total CO 2 injected in the first three years was 2,600 tons, which according to the model has increased methane recovery (due to ECBM) by 6,700 scf/d.« less

In-place oil shale resources examined by grade in the major basins of the Green River Formation, Colorado, Utah, and Wyoming

USGS Publications Warehouse

Birdwell, Justin E.; Mercier, Tracey J.; Johnson, Ronald C.; Brownfield, Michael E.

2013-01-01

Using a geology-based assessment methodology, the U.S. Geological Survey estimated a total of 4.285 trillion barrels of oil in-place in the oil shale of the three principal basins of the Eocene Green River Formation. Using oil shale cutoffs of potentially viable (15 gallons per ton) and high grade (25 gallons per ton), it is estimated that between 353 billion and 1.146 trillion barrels of the in-place resource have a high potential for development.

Emissions from Coal Fires and Their Impact on the Environment

USGS Publications Warehouse

Kolker, Allan; Engle, Mark; Stracher, Glenn; Hower, James; Prakash, Anupma; Radke, Lawrence; ter Schure, Arnout; Heffern, Ed

2009-01-01

Self-ignited, naturally occurring coal fires and fires resulting from human activities persist for decades in underground coal mines, coal waste piles, and unmined coal beds. These uncontrolled coal fires occur in all coal-bearing parts of the world (Stracher, 2007) and pose multiple threats to the global environment because they emit greenhouse gases - carbon dioxide (CO2), and methane (CH4) - as well as mercury (Hg), carbon monoxide (CO), and other toxic substances (fig. 1). The contribution of coal fires to the global pool of atmospheric CO2 is little known but potentially significant. For China, the world's largest coal producer, it is estimated that anywhere between 10 million and 200 million metric tons (Mt) of coal reserves (about 0.5 to 10 percent of production) is consumed annually by coal fires or made inaccessible owing to fires that hinder mining operations (Rosema and others, 1999; Voigt and others, 2004). At this proportion of production, coal amounts lost to coal fires worldwide would be two to three times that for China. Assuming this coal has mercury concentrations similar to those in U.S. coals, a preliminary estimate of annual Hg emissions from coal fires worldwide is comparable in magnitude to the 48 tons of annual Hg emissions from all U.S. coal-fired power-generating stations combined (U.S. Environmental Protection Agency, 2002). In the United States, the combined cost of coal-fire remediation projects, completed, budgeted, or projected by the U.S. Department of the Interior's Office of Surface Mining Reclamation and Enforcement (OSM), exceeds $1 billion, with about 90% of that in two States - Pennsylvania and West Virginia (Office of Surface Mining Enforcement and Reclamation, 2008; fig. 2). Altogether, 15 States have combined cumulative OSM coal-fire project costs exceeding $1 million, with the greatest overall expense occurring in States where underground coal fires are predominant over surface fires, reflecting the greater cost of extinguishing underground fires (fig. 2) (see 'Controlling Coal Fires'). In this fact sheet we review how coal fires occur, how they can be detected by airborne and remote surveys, and, most importantly, the impact coal-fire emissions may have on the environment and human health. In addition, we describe recent efforts by the U.S. Geological Survey (USGS) and collaborators to measure fluxes of CO2, CO, CH4, and Hg, using groundbased portable detectors, and combining these approaches with airborne thermal imaging and CO2 measurements. The goal of this research is to develop approaches that can be extrapolated to large fires and to extrapolate results for individual fires in order to estimate the contribution of coal fires as a category of global emissions.

Bio-based production of methacrylic acid

USDA-ARS?s Scientific Manuscript database

Methacrylic acid (MAA) is an important industrial chemical commodity, with annual production exceeding 3 million metric tons and a market value surpassing $9 billion. The primary use of MAA is the conversion to ester derivatives, which are further converted into numerous useful polymers. Despite the...

Truck Transport of Hazardous Chemicals : Acetone

DOT National Transportation Integrated Search

1997-03-01

The transport of hazardous materials by all modes is a major concern of the U.S. Department of Transportation. Estimates place the total amount of hazardous materials transported in the U.S. in excess of 1.5 billion tons per year. Highway, water, and...

Truck Transport of Hazardous Chemicals : Isopropanol

DOT National Transportation Integrated Search

1997-12-01

The transport of hazardous materials by all modes is a major concern of the U.S. Department of Transportation. Estimates place the total amount of hazardous materials transported in the U.S. in excess of 1.5 billion tons per year. Highway, water, and...

Analysis of emission data from global commercial aviation : 2004 and 2006

DOT National Transportation Integrated Search

2010-07-14

The global commercial aircraft fleet in 2006 flew 31.26 million flights, burned 188.20 million metric tons of fuel, and covered 38.68 billion kilometers. This activity emitted substantial amounts of fossil-fuel combustion products within the upper tr...

Truck Transport of Hazardous Chemicals : Phosphorus Pentasulfide

DOT National Transportation Integrated Search

1996-08-01

The transport of hazardous materials by all modes is a major concern of the U.S. Department of Transportation. Estimates place the total amount of hazardous materials transported in the U.S. in excess of 1.5 billion tons per year. Highway, water, and...

Truck Transport of Hazardous Chemicals: 1-Butanol

DOT National Transportation Integrated Search

1995-09-01

The transport of hazardous materials by all modes is a major concern of the U.S. Department of Transportation. Estimates place the total amount of hazardous materials transported in the U.S. in excess of 1.5 billion tons per year. Highway, water, and...

Truck Transport of Hazardous Chemicals : Dodecene-1

DOT National Transportation Integrated Search

1996-09-01

The transport of hazardous materials by all modes is a major concern of the U.S. Department of Transportation. Estimates place the total amount of hazardous materials transported in the U.S. in excess of 1.5 billion tons per year. Highway, water, and...

Reduction of Greenhouse Gas and Criteria Pollutant Emissions by Direct Conversion of Associated Flare Gas to Synthetic Fuels at Oil Wellheads

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tan, Eric C; Zhang, Yi Min; Schuetzle, Dennis

This study describes the results of a 'well-to-wheel' life cycle assessment (LCA) carried out to determine the potential greenhouse gas and criteria pollutant emission reductions that could be achieved by converting associated flare gas directly to synthetic fuels at oil wellheads in the US and globally. A Greyrock Flare Gas-to-Fuels(TM) conversion process at an Ohio oil well was used as the base case for this LCA. The liquid fuel produced directly from associated gas is comprised primarily of premium synthetic diesel with a small amount of synthetic gasoline. In this LCA scenario, the synthetic diesel and synthetic gasoline are blendedmore » at 20 and 10 vol% with petroleum diesel and gasoline, respectively. While the synthetic diesel fuel can be used as is (100%), the 20 vol% synthetic diesel blend (with petroleum diesel) was found to significantly improve engine performance, increase fuel economy, and reduce emissions. The direct conversion of associated gas to synthetic diesel fuels globally could reduce emissions of CO2 and CH4 by up to 356 and 5.96 million metric tons/year, respectively, resulting in the reduction of greenhouse gases (GHGs) by about 113.3 and 92.2% (20 year global warming potential) and 73.8 and 50.7% (100 year global warming potential) for synthetic diesel and gasoline fuels when compared to petroleum-derived gasoline fuels, respectively. Likewise, diesel criteria emissions could be reduced globally by up to 23.3, 0.374, 42.4, and 61.3 million metric tons/year globally for CO, particulates, NOx, and hydrocarbons, respectively. The potential economic benefit of this approach is that up to 5.30 and 71.1 billion liters of synthetic fuels could be produced each year in the US and globally from associated gas, respectively.« less

The green operating room: simple changes to reduce cost and our carbon footprint.

PubMed

Wormer, Blair A; Augenstein, Vedra A; Carpenter, Christin L; Burton, Patrick V; Yokeley, William T; Prabhu, Ajita S; Harris, Beth; Norton, Sujatha; Klima, David A; Lincourt, Amy E; Heniford, B Todd

2013-07-01

Generating over four billion pounds of waste each year, the healthcare system in the United States is the second largest contributor of trash with one-third produced by operating rooms. Our objective is to assess improvement in waste reduction and recycling after implementation of a Green Operating Room Committee (GORC) at our institution. A surgeon and nurse-initiated GORC was formed with members from corporate leadership, nursing, anesthesia, and OR staff. Initiatives for recycling opportunities, reduction of energy and water use as well as solid waste were implemented and the results were recorded. Since formation of GORC in 2008, our OR has diverted 6.5 tons of medical waste. An effort to recycle all single-use devices was implemented with annual solid waste reduction of approximately 12,860 lbs. Disposable OR foam padding was replaced with reusable gel pads at greater than $50,000 per year savings. Over 500 lbs of previously discarded batteries were salvaged from the OR and donated to charity or redistributed in the hospital ($9,000 annual savings). A "Power Down" initiative to turn off all anesthesia and OR lights and equipment not in use resulted in saving $33,000 and 234.3 metric tons of CO2 emissions reduced per year. Converting from soap to alcohol-based waterless scrub demonstrated a potential saving of 2.7 million liters of water annually. Formation of an OR committee dedicated to ecological initiatives can provide a significant opportunity to improve health care's impact on the environment and save money.

Burden shifting of water quantity and quality stress from megacity Shanghai

NASA Astrophysics Data System (ADS)

Zhao, Xu; Liu, Junguo; Yang, Hong; Duarte, Rosa; Tillotson, Martin R.; Hubacek, Klaus

2016-09-01

Much attention has been paid to burden shifting of CO2 emissions from developed regions to developing regions through trade. However, less discussed is that trade also acts as a mechanism enabling wealthy consumers to shift water quantity and quality stress to their trading partners. In this study, we investigate how Shanghai, the largest megacity in China, draws water resources from all over China and outsources its pollution through virtual quantity and quality water flows associated with trade. The results show that Shanghai's consumption of goods and services in 2007 led to 11.6 billion m3 of freshwater consumption, 796 thousand tons of COD, and 16.2 thousand tons of NH3-N in discharged wastewater. Of this, 79% of freshwater consumption, 82.9% of COD and 82.5% of NH3-N occurred in other Chinese Provinces which provide goods and services to Shanghai. Thirteen Provinces with severe and extreme water quantity stress accounted for 60% of net virtual water import to Shanghai, while 19 Provinces experiencing water quality stress endured 79% of net COD outsourcing and 75.5% of net NH3-N outsourcing from Shanghai. In accordance with the three "redlines" recently put forward by the Chinese central government to control water pollution and cap total water use in all provinces, we suggest that Shanghai should share its responsibility for reducing water quantity and quality stress in its trading partners through taking measures at provincial, industrial, and consumer levels. In the meantime, Shanghai needs to enhance demand side management by promoting low water intensity consumption.

CarbFix I: Rapid CO2 mineralization in basalt for permanent carbon storage

NASA Astrophysics Data System (ADS)

Matter, J. M.; Stute, M.; Snæbjörnsdóttir, S.; Gíslason, S. R.; Oelkers, E. H.; Sigfússon, B.; Gunnarsson, I.; Aradottir, E. S.; Gunnlaugsson, E.; Broecker, W. S.

2015-12-01

Carbon dioxide mineralization via CO2-fluid-rock reactions provides the most permanent solution for geologic CO2 storage. Basalts, onshore or offshore, have the potential to store million metric tons of CO2 as (Ca, Mg, Fe) carbonates [1, 2]. However, as of today it was unclear how fast CO2 is converted to carbonate minerals in-situ in a basalt storage reservoir. The CarbFix I project in Iceland was designed to verify in-situ CO2 mineralization in basaltic rocks. Two injection tests were performed at the CarbFix I pilot injection site near the Hellisheidi geothermal power plant in 2012. 175 tons of pure CO2 and 73 tons of a CO2+H2S mixture were injection from January to March 2012 and in June 2013, respectively. The gases were injected fully dissolved in groundwater into a permeable basalt formation between 400 and 800 m depth using a novel CO2 injection system. Using conservative (SF6, SF5CF3) and reactive (14C) tracers, we quantitatively monitor and detect dissolved and chemically transformed CO2. Tracer breakthrough curves obtained from the first monitoring well indicate that the injected solution arrived in a fast short pulse and a late broad peak. Ratios of 14C/SF6, 14C/SF5CF3 or DIC/SF6 and DIC/SF5CF3 are significantly lower in the monitoring well compared to the injection well, indicating that the injected dissolved CO2 reacted. Mass balance calculations using the tracer data reveal that >95% of the injected CO2 has been mineralized over a period of two years. Evidence of carbonate precipitation has been found in core samples that were collected from the storage reservoir using wireline core drilling as well as in and on the submersible pump in the monitoring well. Results from the core analysis will be presented with emphasis on the CO2 mineralization. [1] McGrail et al. (2006) JGR 111, B12201; [2] Goldberg et al. (2008) PNAS 105(29), 9920-9925.

40 CFR 98.476 - Data reporting requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... section. (a) If you receive CO2 by pipeline, report the following for each receiving flow meter: (1) The total net mass of CO2 received (metric tons) annually. (2) If a volumetric flow meter is used to receive CO2: (i) The volumetric flow through a receiving flow meter at standard conditions (in standard cubic...

40 CFR 98.446 - Data reporting requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... receive CO2 in containers, report: (1) The mass (in metric tons) or volume at standard conditions (in standard cubic meters) of contents in containers received in each quarter. (2) The concentration of CO2 of contents in containers (volume or wt. percent CO2 expressed as a decimal fraction) in each quarter. (3) The...

40 CFR 98.446 - Data reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... receive CO2 in containers, report: (1) The mass (in metric tons) or volume at standard conditions (in standard cubic meters) of contents in containers received in each quarter. (2) The concentration of CO2 of contents in containers (volume or wt. percent CO2 expressed as a decimal fraction) in each quarter. (3) The...

40 CFR 98.446 - Data reporting requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... receive CO2 in containers, report: (1) The mass (in metric tons) or volume at standard conditions (in standard cubic meters) of contents in containers received in each quarter. (2) The concentration of CO2 of contents in containers (volume or wt. percent CO2 expressed as a decimal fraction) in each quarter. (3) The...

40 CFR 98.446 - Data reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... receive CO2 in containers, report: (1) The mass (in metric tons) or volume at standard conditions (in standard cubic meters) of contents in containers received in each quarter. (2) The concentration of CO2 of contents in containers (volume or wt. percent CO2 expressed as a decimal fraction) in each quarter. (3) The...

3D Geological Modeling of CoalBed Methane (CBM) Resources in the Taldykuduk Block Karaganda Coal Basin, Kazakhstan

NASA Astrophysics Data System (ADS)

Sadykov, Raman; Kiponievich Ogay, Evgeniy; Royer, Jean-Jacques; Zhapbasbayev, Uzak; Panfilova, Irina

2015-04-01

Coal Bed Methane (CBM) is gas stored in coal layers. It can be extracted from wells after hydraulic fracturing and/or solvent injection, and secondary recovery techniques such as CO2 injection. Karaganda Basin is a very favorable candidate region to develop CBM production for the following reasons: (i) Huge gas potential; (ii) Available technologies for extracting and commercializing the gas produced by CBM methods; (iii) Experience in degassing during underground mining operations for safety reasons; (iv) Local needs in energy for producing electricity for the industrial and domestic market. The objectives of this work are to model the Taldykuduk block coal layers and their properties focusing on Coal Bed Methane production. It is motivated by the availability of large coal bed methane resources in Karaganda coal basin which includes 4 300 Bm3 equivalent 2 billion tons of coal (B = billion = 109) with gas content 15-25 m3/t of coal (for comparison San Juan basin (USA) has < 20 m3/t). The CBM reserves estimations are about: Saransk block, 26.3 Bm3 and Taldykuduk block, 23.5 Bm3. Methane (CH4) can be considered as an environmentally-friendly fuel compared to coal. Actually, the methane extracted during mining is released in the atmosphere, collecting it for recovering energy will reduce CO2 equivalent emissions by 36 Mt, good news regarding climate warming issues. The exploitation method will be based on a EOR technology consisting in injecting CO2 which replaces methane in pores because it has a higher adsorption capacity than CH4; exploiting CBM by CO2 injection provides thus a safe way to sequestrate CO2 in adsorbed form. The 3D geological model was built on Gocad/Skua using the following available data set: 926 wells and large area (7 x 12 km). No seismic data; coal type and chemical components (S, ash, …); unreliable available cross-section & maps due to old acquisition; quality mature coal; complex heterogeneous fractures network reported on geological cross sections; and utilization issues of the water extracted in the early stages of exploitation. The resulting 3D faulted model which includes more than 100 of faults will be further used to simulate the secondary recovery of methane by injecting CO2. The simulation will be carried out on a flow simulator assuming a two phase dimensionless formulation of CBM production in a double porosity model considering two domains: the matrix (m) and the fracture (f) for which the initial and boundary conditions are different. The resulting comprehensive 3D models had helped in better understanding the tectonic structures of the region, especially the relationships between the fault systems.

The financial attractiveness assessment of large waste management projects registered as clean development mechanism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bufoni, André Luiz, E-mail: bufoni@facc.ufrj.br; Oliveira, Luciano Basto; Rosa, Luiz Pinguelli

Highlights: • Projects are not financially attractive without registration as CDMs. • WM benchmarks and indicators are converging and reducing in variance. • A sensitivity analysis reveal that revenue has more of an effect on the financial results. • Results indicate that an extensive database would reduce WM project risk and capital costs. • Disclosure standards would make information more comparable worldwide. - Abstract: This study illustrates the financial analyses for demonstration and assessment of additionality presented in the project design (PDD) and enclosed documents of the 431 large Clean Development Mechanisms (CDM) classified as the ‘waste handling and disposalmore » sector’ (13) over the past ten years (2004–2014). The expected certified emissions reductions (CER) of these projects total 63.54 million metric tons of CO{sub 2}eq, where eight countries account for 311 projects and 43.36 million metric tons. All of the projects declare themselves ‘not financially attractive’ without CER with an estimated sum of negative results of approximately a half billion US$. The results indicate that WM benchmarks and indicators are converging and reducing in variance, and the sensitivity analysis reveals that revenues have a greater effect on the financial results. This work concludes that an extensive financial database with simple standards for disclosure would greatly diminish statement problems and make information more comparable, reducing the risk and capital costs of WM projects.« less

Randolph Plant passes 60-million-ton milestone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sprouls, M.W.; Adam, B.O.

1983-09-01

Peabody Coal Co.'s Randolph coal preparation plant has processed 60 million tons of coal during 10 years of operation. The plant, which is in Illinois, receives coal from 3 mines and 2 more will eventually send their output for cleaning. Coal from one mine travels 2 miles overland to a 30,000 ton conical bunker constructed of Reinforced Earth. Clean coal is supplied for electricity generation. The plant uses water-only processes, with a jig and three stages of hydrocyclones. A flowsheet of the scalper circuit is given.

Ocean sequestration of carbon dioxide: modeling the deep ocean release of a dense emulsion of liquid Co2-in-water stabilized by pulverized limestone particles.

PubMed

Golomb, D; Pennell, S; Ryan, D; Barry, E; Swett, P

2007-07-01

The release into the deep ocean of an emulsion of liquid carbon dioxide-in-seawater stabilized by fine particles of pulverized limestone (CaCO3) is modeled. The emulsion is denser than seawater, hence, it will sink deeper from the injection point, increasing the sequestration period. Also, the presence of CaCO3 will partially buffer the carbonic acid that results when the emulsion eventually disintegrates. The distance that the plume sinks depends on the density stratification of the ocean, the amount of the released emulsion, and the entrainment factor. When released into the open ocean, a plume containing the CO2 output of a 1000 MW(el) coal-fired power plant will typically sink hundreds of meters below the injection point. When released from a pipe into a valley on the continental shelf, the plume will sink about twice as far because of the limited entrainment of ambient seawater when the plume flows along the valley. A practical system is described involving a static mixer for the in situ creation of the CO2/seawater/pulverized limestone emulsion. The creation of the emulsion requires significant amounts of pulverized limestone, on the order of 0.5 tons per ton of liquid CO2. That increases the cost of ocean sequestration by about $13/ ton of CO2 sequestered. However, the additional cost may be compensated by the savings in transportation costs to greater depth, and because the release of an emulsion will not acidify the seawater around the release point.

NANO-SCALE PALLADIUM DOPED MAGNESIUM BIMETALLICS FOR DECHLORINATING PCBS

EPA Science Inventory

Polychlorinated biphenyls (PCBs) are toxic and recalcitrant pollutants found in rivers; coastal waters and in 500 of the nation's 1598 Superfund waste sites. According to an EPA estimate, the existing 525 million tons of PCB wastes will cost $394 billion to be incinerated, curren...

40 CFR 98.333 - Calculating GHG emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Zinc Production § 98.333 Calculating GHG emissions. You must... your facility used for zinc production, you must determine the mass of carbon in each carbon-containing... weights, CO2 to carbon. 2000/2205 = Conversion factor to convert tons to metric tons. (Zinc)k = Annual...

40 CFR Table Mm-2 to Subpart Mm of... - Default Factors for Biomass-Based Fuels and Biomass

Code of Federal Regulations, 2011 CFR

2011-07-01

... Fuels and Biomass MM Table MM-2 to Subpart MM of Part 98 Protection of Environment ENVIRONMENTAL... Biomass-Based Fuels and Biomass Biomass-based fuel and biomass Column A:Density (metric tons/bbl) Column B: Carbon share(% of mass) Column C:Emission factor (metric tons CO2/bbl) Ethanol (100%) 0.1267 52.14 0.2422...

40 CFR Table Mm-2 to Subpart Mm of... - Default Factors for Biomass-Based Fuels and Biomass

Code of Federal Regulations, 2013 CFR

2013-07-01

... Fuels and Biomass MM Table MM-2 to Subpart MM of Part 98 Protection of Environment ENVIRONMENTAL... Biomass-Based Fuels and Biomass Biomass-based fuel and biomass Column A:Density (metric tons/bbl) Column B: Carbon share(% of mass) Column C:Emission factor (metric tons CO2/bbl) Ethanol (100%) 0.1267 52.14 0.2422...

40 CFR Table Mm-2 to Subpart Mm of... - Default Factors for Biomass-Based Fuels and Biomass

Code of Federal Regulations, 2014 CFR

2014-07-01

... Fuels and Biomass MM Table MM-2 to Subpart MM of Part 98 Protection of Environment ENVIRONMENTAL... Biomass-Based Fuels and Biomass Biomass-based fuel and biomass Column A:Density (metric tons/bbl) Column B: Carbon share(% of mass) Column C:Emission factor (metric tons CO2/bbl) Ethanol (100%) 0.1267 52.14 0.2422...

40 CFR Table Mm-2 to Subpart Mm of... - Default Factors for Biomass-Based Fuels and Biomass

Code of Federal Regulations, 2012 CFR

2012-07-01

... Fuels and Biomass MM Table MM-2 to Subpart MM of Part 98 Protection of Environment ENVIRONMENTAL... Biomass-Based Fuels and Biomass Biomass-based fuel and biomass Column A:Density (metric tons/bbl) Column B: Carbon share(% of mass) Column C:Emission factor (metric tons CO2/bbl) Ethanol (100%) 0.1267 52.14 0.2422...

Inventory and projection of greenhouse gases emissions for Sumatera Utara Province

NASA Astrophysics Data System (ADS)

Ambarita, H.; Soeharwinto; Ginting, N.; Basyuni, M.; Zen, Z.

2018-03-01

Greenhouse Gases (GHGs) emissions which result in global warming is a serious problem for the human being. Total globally anthropogenic GHG emissions were the highest in the history of the year 2000 to 2010 and reached 49 (4.5) Giga ton CO2eq per year in 2010. Many governments addressed their commitment to reducing GHG emission. The Government of Indonesia (GoI) has released a target in reducing its GHG emissions by 26% from level business as usual by 2020, and this target can be increased up to 41% by international aid. In this study, the GHG emissions for Sumatera Utara province are assessed and divided into six sectors. They are Agricultural, Land Use and Forestry, Energy, Transportation, Industrial, and Waste sectors. The results show that total GHG emissions for Sumatera Utara province in the baseline year 2010 is 191.4 million tons CO2eq. The business-as-usual projection of the GHG emission in 2020 is 354.5 million tons CO2eq. Mitigation actions will reduce GHG emissions up to 30.5% from business as usual emission in 2020.

Carbon Capture and Sequestration (CCS)

DTIC Science & Technology

2009-06-19

tons of CO2 underground each year to help recover oil and gas resources (enhanced oil recovery , or EOR).1 Also, potentially large amounts of CO2 ... CO2 will be used for enhanced gas recovery at a nearby natural gas field. See http://www.vattenfall.com/www/co2_en/ co2_en/Gemeinsame_Inhalte...for enhanced oil recovery (EOR).18 Transporting CO2 in pipelines is similar to transporting petroleum products like natural gas and oil; it requires

77 FR 11039 - Proposed Confidentiality Determinations for the Petroleum and Natural Gas Systems Source Category...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-24

... CO 2 carbon dioxide CO 2 e carbon dioxide equivalent CBI confidential business information CFR Code... RFA Regulatory Flexibility Act T-D transmission--distribution UIC Underground Injection Control UMRA... to or greater than 25,000 metric tons carbon dioxide equivalent (mtCO 2 e). The proposed...

Gas composition and soil CO2 flux at Changbaishan intra-plate volcano, NE China

NASA Astrophysics Data System (ADS)

wen, H.; Yang, T. F.; Guo, Z.; Fu, C.; Zhang, M.

2011-12-01

Changbaishan, located on the border of China and North Korea, is one of the most active volcanoes in China. This volcano violently erupted 1000 years ago and produced massive magma and widespread volcanic ash, resulting in one of the largest explosive eruptions during the last 2000 years. Recent gas emissions and seismic events in the Tianchi area suggested potential increasing volcanic activities. If that is so, then 1 million residents living on the crater flank shall be endangered by enormous volcanic hazards, including the threat of 2 billion tons of water in the crater lake . In order to better understand current status of Changbaishan, we investigated gas geochemistry in samples from the Tianchi crater lake and surrounding areas. Bubbling gas from hot springs were collected and analyzed. The results show that CO2 is the major component gas for most samples. The maximum value of helium isotopic ratio 5.8 RA (where RA = 3He/4He in air) implies more than 60% of helium is contributed by mantle component, while carbon isotope values fall in the range of -5.8 to -2.0% (vs. PDB), indicating magmatic source signatures as well. Nitrogen dominated samples, 18Dawgo, have helium isotopic ratio 0.7 RA and carbon isotope value -11.4% implying the gas source might be associated with regional crustal components in 18Dawgo. The first-time systematic soil CO2 flux measurements indicate the flux is 22.8 g m-2 day-1 at the western flank of Changbaishan, which is at the same level as the background value in the Tatun Volcano Group (24.6 g m-2 day-1), implying that it may not be as active as TVG.

Logistics, Costs, and GHG Impacts of Utility-Scale Co-Firing with 20% Biomass

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nichol, Corrie Ian

This study analyzes the possibility that biopower in the U.S. is a cost-competitive option to significantly reduce greenhouse gas emissions. In 2009, net greenhouse gas (GHG) emitted in the United States was equivalent to 5,618 million metric tons CO 2, up 5.6% from 1990 (EPA 2011). Coal-fired power generation accounted for 1,748 million metric tons of this total. Intuitively, life-cycle CO 2 emissions in the power sector could be reduced by substituting renewable biomass for coal. If just 20% of the coal combusted in 2009 had been replaced with biomass, CO 2 emissions would have been reduced by 350 millionmore » metric tons, or about 6% of net annual GHG emission. This would have required approximately 225 million tons of dry biomass. Such an ambitious fuel substitution would require development of a biomass feedstock production and supply system tantamount to coal. This material would need to meet stringent specifications to ensure reliable conveyance to boiler burners, efficient combustion, and no adverse impact on heat transfer surfaces and flue gas cleanup operations. Therefore, this report addresses the potential cost/benefit tradeoffs of co-firing 20% specification-qualified biomass (on an energy content basis) in large U.S. coal-fired power plants. The dependence and sensitivity of feedstock cost on source of material, location, supply distance, and demand pressure was established. Subsequently, the dependence of levelized cost of electricity (LCOE) on feedstock costs, power plant feed system retrofit, and impact on boiler performance was determined. Overall life-cycle assessment (LCA) of greenhouse gas emissions saving were next evaluated and compared to wind and solar energy to benchmark the leading alternatives for meeting renewable portfolio standards (or RPS).« less

West Europe Report, Science and Technology

DTIC Science & Technology

1986-03-26

over the loss of Challenger. Aerospace executives feel, however, that a major delay in the American program will help Europe’s program by securing it...8217cubic meter hold volume, 3 m max diameter, and 9 tons empty weight . Its crew will’number four to six astronauts, their missions will last 3 to 4...discussions between Kohl and Mitterrand, Bonn had placed weight on the fact that the Fed- eral Republic would be spending 2.7 billion marks in 10 years

Pivot to the Homeland - An Escalated Maritime Interdictions Approach Towards Combating Transnational Criminal Networks in the Western Hemisphere

DTIC Science & Technology

2015-06-03

not focus on other illicit drugs such as heroin, methamphetamines, synthetics, or marijuana that are primarily trafficked across the U.S./Mexico...disruption of the trafficking of more than 132 metric tons of cocaine valued at over $2.6 billion, seizure of over 32,000 pounds of marijuana , $3.5 million...cocaine and 8,500 pounds of marijuana during 22 law enforcement interdictions as part of Operation Unified Resolve, in partnership with regional law

Consumption of materials in the United States, 1900-1995

USGS Publications Warehouse

Matos, G.; Wagner, L.

1998-01-01

The flows of nonfood and nonfuel materials through the economy have significant impact on our lives and the world around us. Growing populations and economies demand more goods, services, and infrastructure. Since the beginning of the twentieth century, the types of materials consumed in the United States have significantly changed. In 1900, on a per-weight basis, almost half of the materials consumed were from renewable resources, such as wood, fibers, and agricultural products, the rest being derived from nonrenewable resources. By 1995, the consumption of renewable resources had declined dramatically, to only 8% of total consumption. During this century, the quantity of materials consumed has grown, from 161 million metric tons in 1900 to 2.8 billion metric tons by 1995, an equivalent of 10 metric tons per person per year. Of all the materials consumed during this century, more than half were consumed in the last 25 years. This paper examines the general historical shifts in materials consumption and presents an analysis of different measurements of materials use and the significance of their trends.

Uranium Adsorbent Fibers Prepared by Atom-Transfer Radical Polymerization (ATRP) from Poly(vinyl chloride)- co -chlorinated Poly(vinyl chloride) (PVC- co -CPVC) Fiber

DOE PAGES

Brown, Suree; Yue, Yanfeng; Kuo, Li-Jung; ...

2016-03-11

The need to secure future supplies of energy attracts researchers in several countries to a vast resource of nuclear energy fuel: uranium in seawater (estimated at 4.5 billion tons in seawater). In this study, we developed effective adsorbent fibers for the recovery of uranium from seawater via atom-transfer radical polymerization (ATRP) from a poly-(vinyl chloride)-co-chlorinated poly(vinyl chloride) (PVC-co-CPVC) fiber. ATRP was employed in the surface graft polymerization of acrylonitrile (AN) and tert-butyl acrylate (tBA), precursors for uranium-interacting functional groups, from PVC-co-CPVC fiber. The [tBA]/[AN] was systematically varied to identify the optimal ratio between hydrophilic groups (from tBA) and uranyl-binding ligandsmore » (from AN). The best performing adsorbent fiber, the one with the optimal [tBA]/[AN] ratio and a high degree of grafting (1390%), demonstrated uranium adsorption capacities that are significantly greater than those of the Japan Atomic Energy Agency (JAEA) reference fiber in natural seawater tests (2.42 3.24 g/kg in 42 days of seawater exposure and 5.22 g/kg in 49 days of seawater exposure, versus 1.66 g/kg in 42 days of seawater exposure and 1.71 g/kg in 49 days of seawater exposure for JAEA). Lastly, adsorption of other metal ions from seawater and their corresponding kinetics were also studied. The grafting of alternative monomers for the recovery of uranium from seawater is now under development by this versatile technique of ATRP.« less

Uranium Adsorbent Fibers Prepared by Atom-Transfer Radical Polymerization (ATRP) from Poly(vinyl chloride)- co -chlorinated Poly(vinyl chloride) (PVC- co -CPVC) Fiber

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, Suree; Yue, Yanfeng; Kuo, Li-Jung

The need to secure future supplies of energy attracts researchers in several countries to a vast resource of nuclear energy fuel: uranium in seawater (estimated at 4.5 billion tons in seawater). In this study, we developed effective adsorbent fibers for the recovery of uranium from seawater via atom-transfer radical polymerization (ATRP) from a poly-(vinyl chloride)-co-chlorinated poly(vinyl chloride) (PVC-co-CPVC) fiber. ATRP was employed in the surface graft polymerization of acrylonitrile (AN) and tert-butyl acrylate (tBA), precursors for uranium-interacting functional groups, from PVC-co-CPVC fiber. The [tBA]/[AN] was systematically varied to identify the optimal ratio between hydrophilic groups (from tBA) and uranyl-binding ligandsmore » (from AN). The best performing adsorbent fiber, the one with the optimal [tBA]/[AN] ratio and a high degree of grafting (1390%), demonstrated uranium adsorption capacities that are significantly greater than those of the Japan Atomic Energy Agency (JAEA) reference fiber in natural seawater tests (2.42 3.24 g/kg in 42 days of seawater exposure and 5.22 g/kg in 49 days of seawater exposure, versus 1.66 g/kg in 42 days of seawater exposure and 1.71 g/kg in 49 days of seawater exposure for JAEA). Lastly, adsorption of other metal ions from seawater and their corresponding kinetics were also studied. The grafting of alternative monomers for the recovery of uranium from seawater is now under development by this versatile technique of ATRP.« less

Uranium Adsorbent Fibers Prepared by Atom-Transfer Radical Polymerization (ATRP) from Poly(vinyl chloride)- co -chlorinated Poly(vinyl chloride) (PVC- co -CPVC) Fiber

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, Suree; Yue, Yanfeng; Kuo, Li-Jung

The need to secure future supplies of energy attracts researchers in several countries to a vast resource of nuclear energy fuel: uranium in seawater (estimated at 4.5 billion tons in seawater). In this study, we developed effective adsorbent fibers for the recovery of uranium from seawater via atom-transfer radical polymerization (ATRP) from a poly- (vinyl chloride)-co-chlorinated poly(vinyl chloride) (PVC-co-CPVC) fiber. ATRP was employed in the surface graft polymerization of acrylonitrile (AN) and tert-butyl acrylate (tBA), precursors for uranium-interacting functional groups, from PVC-co-CPVC fiber. The [tBA]/[AN] was systematically varied to identify the optimal ratio between hydrophilic groups (from tBA) and uranyl-bindingmore » ligands (from AN). The best performing adsorbent fiber, the one with the optimal [tBA]/[AN] ratio and a high degree of grafting (1390%), demonstrated uranium adsorption capacities that are significantly greater than those of the Japan Atomic Energy Agency (JAEA) reference fiber in natural seawater tests (2.42-3.24 g/kg in 42 days of seawater exposure and 5.22 g/kg in 49 days of seawater exposure, versus 1.66 g/kg in 42 days of seawater exposure and 1.71 g/kg in 49 days of seawater exposure for JAEA). Adsorption of other metal ions from seawater and their corresponding kinetics were also studied. The grafting of alternative monomers for the recovery of uranium from seawater is now under development by this versatile technique of ATRP.« less

Water and Food in the Twenty-First Century

NASA Astrophysics Data System (ADS)

de Marsily, Ghislain; Abarca-del-Rio, Rodrigo

2016-03-01

In 2000, the World population was 6.2 billion people; it reached 7 billion in 2012 and is expected to reach 9.5 billion (±0.4) in 2050 and 11 billion (±1.5) in 2100, according to the 2012 UN projections (Gerland et al. in Science 346:234-237, 2014). The trend after 2100 is still one of the global demographic growths, but after 2060, Africa is the only continent where the population would still increase. The amount of water consumed annually to produce the food necessary to meet the needs of the populations varies greatly between countries, from about 600 to 2500 m3/year per capita (Zimmer in L'empreinte eau. Les faces cachées d'une ressource vitale. Charles Léopold Meyer, Paris, 2013), depending on their wealth, their food habits, and the percentage of food waste they generate (on average, 30 % of the food produced is wasted). In 2000, the total food production was on the order of 3300 million tons (in cereal equivalents). In 2014, it is estimated that about 0.8 billion inhabitants of the planet suffer from hunger (FAO in World agriculture: towards 2030-2050. FAO, Rome, 2014. http://www.fao.org/docrep/004/Y3557E/y3557e00.HTM) and do not get the nutrition they need to be in good health or, in the case of children, to grow properly (both physically and intellectually). This food deficit was on the order of 40 million tons of cereal equivalents in 2014. The number of inhabitants with a food deficit was about 0.85 billion before the 2008 crisis and was decreasing annually, but it increased abruptly after 2008 up to 1 billion inhabitants and is slowly decreasing now. Assuming a World average water consumption for food of 1300 m3/year per capita in 2000, 1400 m3/year in 2050, and 1500 m3/year in 2100, a volume of water of around 8200 km3/year was needed in 2000, 13,000 km3/year will be needed in 2050, and 16,500 km3/year in 2100 (Marsily in L'eau, un trésor en partage. Dunod, Paris, 2009). Can bioenergy be added to food production? Will that much water be available on Earth, and where will it come from? Is climate change going to modify the answers to these questions? Can severe droughts occur? Can there be conflicts related to a food deficit? Some preliminary answers and scenarios for food production will be given in this paper from a hydrologist's viewpoint.

Mineral resource of the month: steel

USGS Publications Warehouse

Fenton, Michael D.

2007-01-01

About 96 million metric tons of steel was produced in the United States last year — more than any other metal. And the $3.46 billion of iron and steel scrap exported was also the highest of any metal scrap export, helping to reduce the U.S. trade deficit.

Cost Effective Analysis of Recycled Products for Use in Highway Construction.

DOT National Transportation Integrated Search

1998-04-01

Over 4.5 billion of non-hazardous wastes are generated in the United States each year. Out of these wastes over 200 million tons of post consumer waste is generated. The disposal of post consumer waste is the responsibility of municipality and societ...

Development of freight policy analysis tool for northeastern Illinois and the United States.

DOT National Transportation Integrated Search

2010-10-01

Freight transportation is a vital element in the economic prosperity of any country. According to the : nationwide commodity flow survey, over 12 billion tons of goods, valued at more than $11.6 trillion, were moved in : America in the year 2007(Bure...

Nanostructured enzyme assemblies for lignocellulosic biomass breakdown for bioproduct and bioenergy applications

USDA-ARS?s Scientific Manuscript database

The continued reliance on fossil fuels to supply our chemical feedstock and energy requirements is unsustainable. However, it is estimated that there are greater than 220 billion tons of lignocellulosic biomass available globally which represents a tremendous renewable source for society’s chemical...

40 CFR 98.476 - Data reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) of this section. (c) If you use more than one receiving flow meter, report the net total mass of CO2... section. (a) If you receive CO2 by pipeline, report the following for each receiving flow meter: (1) The total net mass of CO2 received (metric tons) annually. (2) If a volumetric flow meter is used to receive...

40 CFR 98.476 - Data reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) of this section. (c) If you use more than one receiving flow meter, report the net total mass of CO2... section. (a) If you receive CO2 by pipeline, report the following for each receiving flow meter: (1) The total net mass of CO2 received (metric tons) annually. (2) If a volumetric flow meter is used to receive...

Volcanic CO2 mapping and flux measurements at Campi Flegrei by Tunable Diode Laser absorption Spectroscopy

NASA Astrophysics Data System (ADS)

Pedone, Maria; Aiuppa, Alessandro; Giudice, Gaetano; Grassa, Fausto; Chiodini, Giovanni; Valenza, Mariano

2014-05-01

Near-infrared room-temperature Tunable Diode Lasers (TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in Volcanology are still limited to a few examples. Here, we explored the potentiality of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) to measurement of volcanic CO2 flux emissions. Our field tests were conducted at Campi Flegrei (near Pozzuoli, Southern Italy), where the GasFinder was used (during three campaigns in October 2012, January 2013 and May 2013) to repeatedly measure the path-integrated concentrations of CO2 along cross-sections of the atmospheric plumes of the two main fumarolic fields in the area (Solfatara and Pisciarelli). By using ad-hoc designed field-set-up and a tomographic post-processing routine, we resolved, for each of the 2 manifestations, the contour maps of CO2 concentrations in their atmospheric plumes, from the integration of which (and after multiplication by the plumes' transport speeds) the CO2 fluxes were finally obtained [1]. The so-calculated fluxes average of 490 tons/day, which agrees well with independent evaluations of Aiuppa et al. (2013) [2] (460 tons/day on average), and support a significant contribution of fumaroles to the total CO2 budget. The cumulative (fumarole [this study] +soil [2]) CO2 output from Campi Flegrei is finally evaluated at 1600 tons/day. The application of lasers to volcanic gas studies is still an emerging (though intriguing) research field, and requires more testing and validation experiments. We conclude that TDL technique may valuably assist CO2 flux quantification at a number of volcanic targets worldwide. [1] Pedone M. et al. (2013) Gold2013:abs:5563, Goldschmidt Conference, session 11a. [2] Aiuppa A. et al. (2013) Geochemistry Geophysics Geosystems. doi: 10.1002/ggge.20261. [3] Chiodini G. et al. (2010) Journal of Geophysical Research, Volume 115, B03205. doi:10.1029/2008JB006258.

Catalytic Formylation of Primary and Secondary Amines with CO2 and H2 Using Abundant-Metal Catalysts.

PubMed

Affan, Mohammad A; Jessop, Philip G

2017-06-19

Catalytic hydrogenation of CO 2 is an efficient and selective way to prepare formic acid derivatives, but most of the highly active catalysts used for this purpose require precious metals. In this study, in situ abundant-metal complexes have been evaluated as potential catalysts for CO 2 hydrogenation to prepare formamides, including N-formylmorpholine, 2-ethylhexylformamide, and dimethylformamide, from the corresponding amines. From these initial screening results, the most active catalysts for these reactions were found to be MX 2 /dmpe in situ catalysts (M = Fe(II), Ni(II); X = Cl - , CH 3 CO 2 - , acac - ; dmpe = 1,2-bis(dimethylphosphino)ethane) in DMSO. The optimal reaction conditions were found to be 100-135 °C and a total pressure of 100 bar. Morpholine was formylated with a TON value of up to 18000, which is the highest TON for the hydrogenation of CO 2 to formamides using any abundant-metal-phosphine complex. With an appropriate selection of catalyst and reaction conditions, >90-98% conversion of amine to formamide could be achieved.

Potential for reduced methane and carbon dioxide emissions from livestock and pasture management in the tropics

PubMed Central

Thornton, Philip K.; Herrero, Mario

2010-01-01

We estimate the potential reductions in methane and carbon dioxide emissions from several livestock and pasture management options in the mixed and rangeland-based production systems in the tropics. The impacts of adoption of improved pastures, intensifying ruminant diets, changes in land-use practices, and changing breeds of large ruminants on the production of methane and carbon dioxide are calculated for two levels of adoption: complete adoption, to estimate the upper limit to reductions in these greenhouse gases (GHGs), and optimistic but plausible adoption rates taken from the literature, where these exist. Results are expressed both in GHG per ton of livestock product and in Gt CO2-eq. We estimate that the maximum mitigation potential of these options in the land-based livestock systems in the tropics amounts to approximately 7% of the global agricultural mitigation potential to 2030. Using historical adoption rates from the literature, the plausible mitigation potential of these options could contribute approximately 4% of global agricultural GHG mitigation. This could be worth on the order of $1.3 billion per year at a price of $20 per t CO2-eq. The household-level and sociocultural impacts of some of these options warrant further study, however, because livestock have multiple roles in tropical systems that often go far beyond their productive utility. PMID:20823225

Carbon dioxide hydrogenation catalysed by well-defined Mn(i) PNP pincer hydride complexes.

PubMed

Bertini, Federica; Glatz, Mathias; Gorgas, Nikolaus; Stöger, Berthold; Peruzzini, Maurizio; Veiros, Luis F; Kirchner, Karl; Gonsalvi, Luca

2017-07-01

The catalytic reduction of carbon dioxide is of great interest for its potential as a hydrogen storage method and to use carbon dioxide as C-1 feedstock. In an effort to replace expensive noble metal-based catalysts with efficient and cheap earth-abundant counterparts, we report the first example of Mn(i)-catalysed hydrogenation of CO 2 to HCOOH. The hydride Mn(i) catalyst [Mn(PNP NH - i Pr)(H)(CO) 2 ] showed higher stability and activity than its Fe(ii) analogue. TONs up to 10 000 and quantitative yields were obtained after 24 h using DBU as the base at 80 °C and 80 bar total pressure. At catalyst loadings as low as 0.002 mol%, TONs greater than 30 000 could be achieved in the presence of LiOTf as the co-catalyst, which are among the highest activities reported for base-metal catalysed CO 2 hydrogenations to date.

A model to evaluate 100-year energy mix scenarios to facilitate deep decarbonization in the southeastern United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adkisson, Mary A.; Qualls, A. L.

The Southeast United States consumes approximately one billion megawatt-hours of electricity annually; roughly two-thirds from carbon dioxide (CO 2) emitting sources. The balance is produced by non-CO 2 emitting sources: nuclear power, hydroelectric power, and other renewables. Approximately 40% of the total CO 2 emissions come from the electric grid. The CO 2 emitting sources, coal, natural gas, and petroleum, produce approximately 372 million metric tons of CO 2 annually. The rest is divided between the transportation sector (36%), the industrial sector (20%), the residential sector (3%), and the commercial sector (2%). An Energy Mix Modeling Analysis (EMMA) tool wasmore » developed to evaluate 100-year energy mix strategies to reduce CO 2 emissions in the southeast. Current energy sector data was gathered and used to establish a 2016 reference baseline. The spreadsheet-based calculation runs 100-year scenarios based on current nuclear plant expiration dates, assumed electrical demand changes from the grid, assumed renewable power increases and efficiency gains, and assumed rates of reducing coal generation and deployment of new nuclear reactors. Within the model, natural gas electrical generation is calculated to meet any demand not met by other sources. Thus, natural gas is viewed as a transitional energy source that produces less CO 2 than coal until non-CO 2 emitting sources can be brought online. The annual production of CO 2 and spent nuclear fuel and the natural gas consumed are calculated and summed. A progression of eight preliminary scenarios show that nuclear power can substantially reduce or eliminate demand for natural gas within 100 years if it is added at a rate of only 1000 MWe per year. Any increases in renewable energy or efficiency gains can offset the need for nuclear power. However, using nuclear power to reduce CO 2 will result in significantly more spent fuel. More efficient advanced reactors can only marginally reduce the amount of spent fuel generated in the next 100 years if they are assumed to be available beginning around 2040. Thus closing the nuclear fuel cycle to reduce nuclear spent fuel inventories should be considered. Future work includes the incorporation of economic features into the model and the extension of the evaluation to the industrial sector. It will also be necessary to identify suitable sites for additional reactors.« less

Pragmatic consideration of geologic carbon storage design based upon historic pressure response to oil and gas production in the southern San Joaquin basin

NASA Astrophysics Data System (ADS)

Jordan, P. D.

2015-12-01

Annual CO2 emissions from large fixed sources in the southern San Joaquin Valley and vicinity in California are about 20 million metric tons per year (MMT/Y). Cumulative net fluid production due to oil and gas extracted from below the minimum depth for geologic carbon storage (taken as 1,500 m) was 1.4 billion m3 at reservoir conditions as of 2010. At an average CO2 storage density of 0.5 metric tons per m3, this implies 35 years of storage capacity at current emission rates just to refill the vacated volume, neglecting possible reservoir consolidation. However, the production occurred from over 300 pools. The production rate relative to average pressure decline in the more productive pools analyzed suggests they could receive about 2 MMT/Y raising the field average pressure to nearly the fracturing pressure. This would require well fields as extensive as those used for production, instead of the single to few wells per project typically envisioned. Even then, the actual allowable injection rate to the larger pools would be less than 2 MMT/Y in order to keep pressures at the injection well below the fracture pressure. This implies storing 20 MMT/Y would require developing storage operations in tens of pools with hundreds, if not over a thousand, wells. This utilization of one of the basins with the most storage capacity in the state would result in reducing the state's fixed source emissions by only one eighth relative to current emissions. The number of fields and wells involved in achieving this suggests a different strategy might provide more capacity at similar cost. Specifically, staging wells that initially produce water in the vicinity of fewer injection wells could result in both more storage. This water could be directed to a shallower zone, or supplied to the surface at a similar cost. The commencement of ocean water desalination in the state indicates the economics of water supply might support treating this water for beneficial use, particularly if it has a lower salinity than sea water.

Case study - Dynamic pressure-limited capacity and costs of CO2 storage in the Mount Simon sandstone

USGS Publications Warehouse

Anderson, Steven T.; Jahediesfanjani, Hossein

2017-01-01

Widespread deployment of carbon capture and storage (CCS) is likely necessary to be able to satisfy baseload electricity demand, to maintain diversity in the energy mix, and to achieve climate and other objectives at the lowest cost. If all of the carbon dioxide (CO2) emissions from stationary sources (such as fossil-fuel burning power plants, and other industrial plants) in the United States needed to be captured and stored, it could be possible to store only a small fraction of this CO2 in oil and natural gas reservoirs, including as a result of CO2 utilization for enhanced oil recovery. The vast majority would have to be stored in saline-filled reservoirs (Dahowski et al., 2005). Given a lack of long-term commercial-scale CCS projects, there is considerable uncertainty in the risks, dynamic capacity, and their cost implications for geologic storage of CO2. Pressure buildup in the storage reservoir is expected to be a primary source of risk associated with CO2 storage, and could severely limit CO2 injection rates (dynamic storage capacities). Most cost estimates for commercial-scale deployment of CCS estimate CO2 storage costs under assumed availability of a theoretical capacity to store tens, hundreds, or even thousands of gigatons of CO2, without considering geologic heterogeneities, pressure limitations, or the time dimension. This could lead to underestimation of the costs of CO2 storage (Anderson, 2017). This paper considers the impacts of pressure limitations and geologic heterogeneity on the dynamic CO2 storage capacity and storage (injection) costs. In the U.S. Geological Survey (USGS)’s National Assessment of Geologic CO2 Storage Resources (USGS, 2013), the mean estimate of the theoretical storage capacity in the Mount Simon Sandstone was about 94 billion metric tons of CO2. However, our results suggest that the pressure-limited capacity after 50 years of injection could be only about 4% of the theoretical geologic storage capacity in this formation. Because this is far less than emissions of CO2 from stationary sources in the region around the Mount Simon Sandstone, the costs to accommodate the potential annual demand for CO2 storage in this formation could be significantly greater than current estimates. Our results could have implications for how long and to what extent decision makers can expect to be able to deploy CCS before transitioning to other low- or zero-carbon energy technologies.

Economic Analysis of Planting Forests on Rice Lands in Texas: Sequestering Carbon and Avoiding Methane Production

NASA Astrophysics Data System (ADS)

Kronrad, G. D.; Huang, C.

2005-12-01

Global climate change is predicted due to increases in greenhouse gasses (i.e. CO2, CH4, CFCs, N2O, O3) in the atmosphere caused by human activities. The atmospheric concentration of methane (CH4), which absorbs and retains heat 21 times more effectively than CO2, has increased. Anaerobic bacterial activity in rice paddies constitutes one of major emission sources of CH4. The rice fields of Texas, for example, accounted for an annual CH4 emission of between 1.1 and 1.6 million tons of CO2 equivalent between 1990 and 2000. Converting marginal rice fields to forests plantations will remove CO2 from the atmosphere, sequester carbon in the forests and prevent the production of CH4. Therefore, carbon credits can be claimed for the carbon sequestered and the avoidance of CH4 production. Analyses were conducted to calculate the amount of carbon sequestered and methane avoided, and the profitability, measured in net present worth (NPW), of managing loblolly pine plantation for 1) timber production only, 2) the dual products of timber products and carbon credits in forests planted on marginal agricultural and unused pastureland and 3) the dual products of timber and carbon storage in forests planted on marginal rice lands. Calculations were performed using three discount rates, three site qualities and five prices for carbon credits. The results indicate that on average quality land, using a discount rate of 8 percent, forests planted on marginal agricultural and unused pastureland earn a NPW of 346 per acre from timber production only; a NPW of 438 per acre from timber and carbon credits (54.4 tons of carbon sequestered), assuming carbon is worth 10 per ton, during one rotation (32 years). The profitability of forest management increases due to the inclusion of carbon credits. The profitability of planting forests on marginal rice fields is even higher, earning a NPW of 566 per acre from timber and carbon credits (54.4 tons of C sequestered and 33.3 tons of C emission avoided).

ANTHROPOGENIC COPPER INVENTORIES AND MERCURY PROFILES FROM LAKE SUPERIOR: EVIDENCE FOR MINING IMPACTS

EPA Science Inventory

During the past 150 years, the mining indstry discharged more than a billion tons of tailings along Lake Superior shorelines and constructed numerous smelters in the watershed. Given the vast size of Lake Superior, were sediment profiles at locations far offshore impacted by near...

Biodegradable bioplastics from food wastes

USDA-ARS?s Scientific Manuscript database

An estimated 1.8 billion tons of waste are created annually from food processing in the US, including the peels, pulp, and pomace (PPP) generated from fruits and vegetables when they are converted into frozen or canned products or pressed into juice. PPP currently is sold as animal feed at low cost,...

A research update for the Stuttgart National Aquaculture Research Center

USDA-ARS?s Scientific Manuscript database

Aquaculture (fish farming) has played an ever-increasing role in providing people with fish, shrimp, and shellfish. Aquaculture is currently the fastest growing sector of global food production and in 2016 totaled 90 million tons valued at $180 billion. The production of food-fish from aquaculture...

ASSESSING AND MANAGING MERCURY FROM HISTORIC AND CURRENT MINING ACTIVITIES

EPA Science Inventory

Mining activities in the US (not counting coal) produce between one and two billion tons of mine waste annually. Since many of the ore mines involve sulfide minerals, the production of acid mine drainage (AMD) is a common problem from these abandoned mine sites. The combination o...

Combating the Sigatoka disease complex on banana

USDA-ARS?s Scientific Manuscript database

Banana is the fourth most important staple food in the world behind rice, wheat and maize, with more than 100 million tons produced annually. Although the majority of bananas produced are consumed locally, banana export is a multi-billion dollar business. Bananas are grown in more than 100 countri...

Rapid Field Measurement of Rubber Content in Russian Dandelion

USDA-ARS?s Scientific Manuscript database

Natural rubber is a critical and strategic raw material for industrial manufacturing and national defense. In 2008, 10 million tons of NR were produced for commercial use, most of it from Hevea brasiliensis in tropical countries. The annual US import deficit for NR is approximately $1 billion. Devel...

A Research Update for the Stuttgart National Aquaculture Research Center

USDA-ARS?s Scientific Manuscript database

Aquaculture (fish farming) has played an ever-increasing role in providing people with fish, shrimp, and shellfish. Aquaculture is currently the fastest growing sector of global food production and in 2014 totaled 80 million tons valued at $140 billion. The production of food-fish from aquaculture...

MERCURY IN STAMP SAND DISCHARGES: IMPLICATIONS FOR LAKE SUPERIOR MERCURY CYCLING

EPA Science Inventory

Approximately a half billion tons of waste rock from the extraction of native copper and silver ores was discharged into the Lake Superior basin. Stamping was the method of choice to recover these metals from the surrounding poor rock. This process created large amounts of extre...

40 CFR 98.33 - Calculating GHG emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... you co-fire biomass fuels with fossil fuels, report CO2 emissions from the combustion of biomass... quarterly totals are summed to determine the annual CO2 mass emissions. (vii) If both biomass and fossil... by 1.1 to convert it to metric tons. (D) If both biomass and fossil fuel are combusted during the...

The impact of biomass energy consumption on pollution: evidence from 80 developed and developing countries.

PubMed

Solarin, Sakiru Adebola; Al-Mulali, Usama; Gan, Gerald Goh Guan; Shahbaz, Muhammad

2018-05-30

The aim of this research is to explore the effect of biomass energy consumption on CO 2 emissions in 80 developed and developing countries. To achieve robustness, the system generalised method of moment was used and several control variables were incorporated into the model including real GDP, fossil fuel consumption, hydroelectricity production, urbanisation, population, foreign direct investment, financial development, institutional quality and the Kyoto protocol. Relying on the classification of the World Bank, the countries were categorised to developed and developing countries. We also used a dynamic common correlated effects estimator. The results consistently show that biomass energy as well as fossil fuel consumption generate more CO 2 emissions. A closer look at the results show that a 100% increase in biomass consumption (tonnes per capita) will increase CO 2 emissions (metric tons per capita) within the range of 2 to 47%. An increase of biomass energy intensity (biomass consumption in tonnes divided by real gross domestic product) of 100% will increase CO 2 emissions (metric tons per capita) within the range of 4 to 47%. An increase of fossil fuel consumption (tonnes of oil equivalent per capita) by 100% will increase CO 2 emissions (metric tons per capita) within the range of 35 to 55%. The results further show that real GDP urbanisation and population increase CO 2 emissions. However, hydroelectricity and institutional quality decrease CO 2 emissions. It is further observed that financial development, foreign direct investment and openness decrease CO 2 emissions in the developed countries, but the opposite results are found for the developing nations. The results also show that the Kyoto Protocol reduces emission and that Environmental Kuznets Curve exists. Among the policy implications of the foregoing results is the necessity of substituting fossil fuels with other types of renewable energy (such as hydropower) rather than biomass energy for reduction of emission to be achieved.

MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tim Merkel; Karl Amo; Richard Baker

2009-03-31

The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris™) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris™ membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plantmore » energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris™ CO2 capture membrane was scaled up with MTR’s commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Service’s Cholla coal-fired power plant, as part of a new DOE NETL funded program.« less

40 CFR 98.38 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 0.138 74.49 Fossil fuel-derived fuels (solid) mmBtu/short ton kg CO2/mmBtu Municipal Solid Waste 1 9.95 90.7 Tires 26.87 85.97 Fossil fuel-derived fuels (gaseous) mmBtu/scf kg CO2/mmBtu Blast Furnace...

SYSTEM LEVEL IMPLICATIONS OF FLEXIBLE CO2 CAPTURE OPERATION

EPA Science Inventory

In ERCOT, turning flexible CO₂ capture systems off during infrequent periods of peak electricity demand can avoid hundreds of millions to billions of dollars in capital costs to replace the power output lost to CO₂ capture energy requirements.  When CO...

Geology and undiscovered resource assessment of the potash-bearing Pripyat and Dnieper-Donets Basins, Belarus and Ukraine

USGS Publications Warehouse

Cocker, Mark D.; Orris, Greta J.; Dunlap, Pamela; Lipin, Bruce R.; Ludington, Steve; Ryan, Robert J.; Słowakiewicz, Mirosław; Spanski, Gregory T.; Wynn, Jeff; Yang, Chao

2017-08-03

Undiscovered potash resources in the Pripyat Basin, Belarus, and Dnieper-Donets Basin, Ukraine, were assessed as part of a global mineral resource assessment led by the U.S. Geological Survey (USGS). The Pripyat Basin (in Belarus) and the Dnieper-Donets Basin (in Ukraine and southern Belarus) host stratabound and halokinetic Upper Devonian (Frasnian and Famennian) and Permian (Cisuralian) potash-bearing salt. The evaporite basins formed in the Donbass-Pripyat Rift, a Neoproterozoic continental rift structure that was reactivated during the Late Devonian and was flooded by seawater. Though the rift was divided, in part by volcanic deposits, into the separate Pripyat and Dnieper-Donets Basins, both basins contain similar potash‑bearing evaporite sequences. An Early Permian (Cisuralian) sag basin formed over the rift structure and was also inundated by seawater resulting in another sequence of evaporite deposition. Halokinetic activity initiated by basement faulting during the Devonian continued at least into the Permian and influenced potash salt deposition and structural evolution of potash-bearing salt in both basins.Within these basins, four areas (permissive tracts) that permit the presence of undiscovered potash deposits were defined by using geological criteria. Three tracts are permissive for stratabound potash-bearing deposits and include Famennian (Upper Devonian) salt in the Pripyat Basin, and Famennian and Cisuralian (lower Permian) salt in the Dnieper-Donets Basin. In addition, a tract was delineated for halokinetic potash-bearing Famennian salt in the Dnieper-Donets Basin.The Pripyat Basin is the third largest source of potash in the world, producing 6.4 million metric tons of potassium chloride (KCl) (the equivalent of about 4.0 million metric tons of potassium oxide or K2O) in 2012. Potash production began in 1963 in the Starobin #1 mine, near the town of Starobin, Belarus, in the northwestern corner of the basin. Potash is currently produced from six potash mines in the Starobin area. Published reserves in the Pripyat Basin area are about 7.3 billion metric tons of potash ore (about 1.3 billion metric tons of K2O) mostly from potash-bearing salt horizons in the Starobin and Petrikov mine areas. The 15,160-square-kilometer area of the Pripyat Basin underlain by Famennian potash-bearing salt contains as many as 60 known potash-bearing salt horizons. Rough estimates of the total mineral endowment associated with stratabound Famennian salt horizons in the Pripyat Basin range from 80 to 200 billion metric tons of potash-bearing salt that could contain 15 to 30 billion metric tons of K2O.Parameters (including the number of economic potash horizons, grades, and depths) for these estimates are not published so the estimates are not easily confirmed. Historically, reserves have been estimated above a depth of 1,200 meters (m) (approximately the depths of conventional underground mining). Additional undiscovered K2O resources could be significantly greater in the remainder of the Fammenian salt depending on the extents and grades of the 60 identified potash horizons above the USGS assessment depth of 3,000 m in the remainder of the tract. Increasing ambient temperatures with increasing depths in the eastern parts of the Pripyat Basin may require a solution mining process which is aided by higher temperatures.No resource or reserve data have been published and little is known about stratabound Famennian and Frasnian salt in the Dnieper-Donets Basin. These Upper Devonian salt units dip to the southeast and extend to depths of 15–19 kilometers (km) or greater. The tract of stratabound Famennian salt that lies above a depth of 3 km, the depth above which potash is technically recoverable by solution mining, underlies an area of about 15,600 square kilometers (km2). If Upper Devonian salt units in the Dnieper-Donets Basin contain potash-bearing strata similar to salt of the same age in the Pripyat Basin, then the stratabound Famennian tract in the Dnieper-Donets Basin could contain significant undiscovered potash resources.The Cisuralian evaporite sequence in the Dnieper-Donets Basin consists of 10 evaporite cycles with the upper 3 cycles containing potash-bearing salt (mainly as sylvite and carnallite) in several subbasins and polyhalite in the sulfate bearing parts of the identified tract. The area of the Cisuralian tract is 62,700 km2. Potash-bearing cycles are as much as 40 m thick. One subbasin is reported to contain 794 million metric tons of “raw or crude” potash-bearing salt which could contain 50 to 150 million metric tons of K2O, depending on the grade. Undiscovered potash resources in the remainder of this permissive tract may be significantly greater. Depths to the Permian salt range from less than 100 to about 1,500 m.Undiscovered resources of halokinetic potash-bearing salt in the Dnieper-Donets Basin were assessed quantitatively for this study by using the standard USGS three-part form of mineral resource assessment (Singer, 2007a; Singer and Menzie, 2010). Delineation of the permissive tract was based on distributions of mapped halokinetic salt structures. This tract contains at least 248 diapiric salt structures with a total area of 7,840 km2 that occupies approximately 8 percent of the basin area. The vertical extent of these salt structures is hundreds of meters to several kilometers. This assessment estimated that a total mean of 11 undiscovered deposits contain an arithmetic mean estimate of about 840 million metric tons of K2O in the halokinetic salt structures of the Dnieper-Donets Basin for which the probabilistic estimate was made.

Monitoring and assessment of ocean acidification in the Arctic Ocean-A scoping paper

USGS Publications Warehouse

Robbins, Lisa L.; Yates, Kimberly K.; Feely, Richard; Fabry, Victoria

2010-01-01

Carbon dioxide (CO2) in the atmosphere is absorbed at the ocean surface by reacting with seawater to form a weak, naturally occurring acid called carbonic acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution. Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats. The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

40 CFR 1037.105 - Exhaust emission standards for CO2 for vocational vehicles.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) AIR POLLUTION CONTROLS CONTROL OF EMISSIONS FROM NEW HEAVY-DUTY MOTOR VEHICLES Emission Standards... CO2 standard (g/ton-mile) for model year 2017 and later GVWR ≤ 19,500 388 373 19,500 < GVWR ≤ 33,000...

40 CFR 1037.105 - Exhaust emission standards for CO2 for vocational vehicles.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) AIR POLLUTION CONTROLS CONTROL OF EMISSIONS FROM NEW HEAVY-DUTY MOTOR VEHICLES Emission Standards... CO2 standard (g/ton-mile) for model year 2017 and later GVWR ≤ 19,500 388 373 19,500 < GVWR ≤ 33,000...

40 CFR 1037.105 - Exhaust emission standards for CO2 for vocational vehicles.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) AIR POLLUTION CONTROLS CONTROL OF EMISSIONS FROM NEW HEAVY-DUTY MOTOR VEHICLES Emission Standards... CO2 standard (g/ton-mile) for model year 2017 and later GVWR ≤19,500 388 373 19,500

Current Perspective in the International Trade of Medicinal Plants Material: An Update.

PubMed

Vasisht, Karan; Sharma, Neetika; Karan, Maninder

2016-01-01

The recent years have seen an increased interest in medicinal plants together with the therapeutic use of phytochemicals. Medicinal plants are utilized by the industry for the production of extracts, phytopharmaceuticals, nutraceuticals and cosmeceuticals and their use is expected to grow faster than the conventional drugs. The enormous demand of medicinal plant material has resulted in huge trade both at domestic and international levels. The trade data of medicinal plant material with commodity code HS 1211 (SITC.4, code 292.4) and their derived/related products which are traded under different commodity codes has been acquired from COMTRADE, Trade Map, country reports, technical documents etc for the period 2001 to 2014. The data was analyzed using statistical tools to draw conclusions. The significant features of the global trade; the leading source, consumer, import and export countries; and the striking trends are presented. The trade of the ten key countries and the selected important items is also discussed in detail. The conservative figure of trade of medicinal plants materials and their derived/related products including extracts, essential oils, phytopharmaceuticals, gums, spices used in medicine, tannins for pharmaceutical use, ingredients for cosmetics etc. as calculated from the global export data for the year 2014 is estimated at USD 33 billion. The average global export in medicinal plants under HS 1211 for the fourteen year period was USD 1.92 billion for 601,357 tons per annum and for the year 2014 it stood at 702,813 tons valued at USD 3.60 billion. For the studied period, an annual average growth rate (AAGR) of 2.4% in volumes and 9.2% in values of export was observed. Nearly 30% of the global trade is made up by top two countries of the import and export. China and India from Asia; Egypt and Morocco from Africa; Poland, Bulgaria and Albania from Europe; Chile and Peru from South America are important supply sources. The USA, Japan and Europe are the major consumers of the world.

Copper-catalyzed formic acid synthesis from CO2 with hydrosilanes and H2O.

PubMed

Motokura, Ken; Kashiwame, Daiki; Miyaji, Akimitsu; Baba, Toshihide

2012-05-18

A copper-catalyzed formic acid synthesis from CO2 with hydrosilanes has been accomplished. The Cu(OAc)2·H2O-1,2-bis(diphenylphosphino)benzene system is highly effective for the formic acid synthesis under 1 atm of CO2. The TON value approached 8100 in 6 h. The reaction pathway was revealed by in situ NMR analysis and isotopic experiments.

Pilot-Scale Silicone Process for Low-Cost Carbon Dioxide Capture Preliminary Techno-Economic Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Surinder; Spiry, Irina; Wood, Benjamin

This report presents system and economic analysis for a carbon-capture unit which uses an aminosilicone-based solvent for CO{sub 2} capture in a pulverized coal (PC) boiler. The aminosilicone solvent is a 60/40 wt/wt mixture of 3-aminopropyl end-capped polydimethylsiloxane (GAP-1m) with tri-ethylene glycol (TEG) as a co-solvent. For comparison purposes, the report also shows results for a carbon-capture unit based on a conventional approach using mono-ethanol amine (MEA). The first year removal cost of CO{sub 2} for the aminosilicone-based carbon-capture process ismore » $46.04/ton of CO2 as compared to $$60.25/ton of CO{sub 2} when MEA is used. The aminosilicone-based process has <77% of the CAPEX of a system using MEA solvent. The lower CAPEX is due to several factors, including the higher working capacity of the aminosilicone solvent compared the MEA, which reduces the solvent flow rate required, reducing equipment sizes. If it is determined that carbon steel can be used in the rich-lean heat exchanger in the carbon capture unit, the first year removal cost of CO{sub 2} decreases to $$44.12/ton. The aminosilicone-based solvent has a higher thermal stability than MEA, allowing desorption to be conducted at higher temperatures and pressures, decreasing the number of compressor stages needed. The aminosilicone-based solvent also has a lower vapor pressure, allowing the desorption to be conducted in a continuous-stirred tank reactor versus a more expensive packed column. The aminosilicone-based solvent has a lower heat capacity, which decreases the heat load on the desorber. In summary, the amino-silicone solvent has significant advantages over conventional systems using MEA.« less

Maize kernel evolution:From teosinte to maize

USDA-ARS?s Scientific Manuscript database

Maize is the most productive and highest value commodity in the US and around the world: over 1 billion tons were produced each year in 2013 and 2014. Together, maize, rice and wheat comprise over 60% of the world’s caloric intake, with wide regional variability in the importance of each crop. The i...

Dealing with frost damage and climate change in tree fruit crops

USDA-ARS?s Scientific Manuscript database

Each year, the U.S. produces about 15 million tons of deciduous fruit crops that have a combined value of >$10 billion. Unpredictable cold damage to these nutritionally important crops is a major threat to industry profitability. Over the last six years, cold damage has accounted for almost half o...

The global transport of dust

USGS Publications Warehouse

Griffin, Dale W.; Kellogg, C.A.; Garrison, V.H.; Shinn, E.A.

2002-01-01

By some estimates as much as two billion metric tons of dust are lifted into the Earth's atmosphere every year. Most of this dust is stirred up by storms, the more dramatic of which are aptly named dust storms. But more than mere dirt is carried aloft. Drifting with the suspended dust particles are soil pollutants such as herbicides and pesticides and a significant number of microorganisms-bacteria, viruses and fungi. We can gain some appreciation of how much microbial life is actually floating in our atmosphere by performing a quick calculation. There are typically about one million bacteria per gram of soil, but let's be conservative and suppose there are only 10,000 bacteria per gram of airborne sediment. Assuming a modest one billion metric tons of sediment in the atmosphere, these numbers translate into a quintillion (1018) sediment-borne bacteria moving around the planet each year-enough to form a microbial bridge between Earth and Jupiter. Here we consider what we've learned about the airborne transport of sediment across the globe, and review some of the remarkable studies in this reemerging field that had it origins more than 100 years ago.

Energy-efficient drinking water disinfection for greenhouse gas mitigation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gadgil, A.J.; Greene, D.M.; Rosenfeld, A.

Anecdotal evidence suggests that approximately one billion people worldwide use cookstoves to boil their drinking water. About half of this population is in China. Some populations (e.g. Jakarta) spend 1% of their GDP on boiling drinking water. Impoverished and/or ignorant populations not yet boiling their drinking water will do so when they can both afford it and understand the risks of unsafe drinking water. A recently developed water disinfection technology (UV Waterworks) can produce safe drinking water while earning tradable carbon credits (or credit as a clean development mechanism) when implemented as part of national energy, health, and carbon emissionsmore » trading policy, UV Waterworks uses approximately 6,000 times less energy than boiling over a biomass cookstove. Each unit that replaces boiling may save up to 175 or 300 tons/year of carbon-equivalent GHG emissions, depending on if it replaces sustainably harvested biomass (SHB) or non-SHB. For the approximately 500M Chinese boiling their drinking water over biomass (assumed SHB), this suggests a technical potential (that is, potential under the limiting case of 100% market adoption) of saving 87M tons/year of carbon-equivalent non-CO{sub 2} GHG emissions. The energy savings and corresponding emissions reductions will vary with cookstove fuels and stove efficiency: non-SHB and kerosene represent the most and least GHG-producing cookstove fuels, respectively, among those readily available to the populations of interest. The authors bracket the global technical potential for carbon emission reductions resulting from implementation of UV Waterworks, and estimate the value of tradable carbon credits earned from these reductions.« less

[Air pollutant emissions of aircraft in China in recent 30 years].

PubMed

He, Ji-Cheng

2012-01-01

Although aircrafts are of great importance in transportation in China, there has been rare study on air pollutant emissions of aircrafts until now. Based on the annually statistical data collected by the Statistic Center of Civil Aviation of China, using the emission factor method derived from fuel consumption, the air pollutant emissions of aircrafts during 1980-2009 were calculated, and their emission intensities and dynamic characteristics were analyzed. The results show that the emissions of SO2, CO, NO(x) and HC from aircrafts of China Civil Aviation increased from 0.31 thousand, 1.89 thousand, 2.25 thousand and 3.14 thousand tons in 1980 to 11.83 thousand, 72.98 thousand, 87.05 thousand and 121.59 thousand tons in 2009, indicating a increase of 0.397 thousand, 2.45 thousand, 2.92 thousand and 4.08 thousand tons per year, respectively. The emission intensities of SO2, CO, NO(x) and HC decreased significantly from 0.624, 3.806, 4.53 and 6.322 g x (t x km)(-1) in 1980 to 0.275, 1.697, 2.025 and 2.828 g x (t x km)(-1) in 2009, respectively. SO2, CO, NO(x) emissions of aircrafts of China Civil Aviation accounted very little of each total emissions in China, and the air pollutant emissions from aircrafts of China Civil Aviation was less than those from other industries in China.

10. SOUTH BAY SHOWING 300TON R.D. WOOD CO. HYDRAULIC CRIMPING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

10. SOUTH BAY SHOWING 300-TON R.D. WOOD CO. HYDRAULIC CRIMPING PRESS. VIEW EAST ALSO SHOWING NORTHWEST CORNER OF OFFICE/MACHINE SHOP - Oldman Boiler Works, Fabricating Shop, 32 Illinois Street, Buffalo, Erie County, NY

Blasting CME

NASA Image and Video Library

2017-12-08

This LASCO C2 image, taken 8 January 2002, shows a widely spreading coronal mass ejection (CME) as it blasts more than a billion tons of matter out into space at millions of kilometers per hour. The C2 image was turned 90 degrees so that the blast seems to be pointing down. An EIT 304 Angstrom image from a different day was enlarged and superimposed on the C2 image so that it filled the occulting disk for effect. Credit: NASA/GSFC/SOHO/ESA To learn more go to the SOHO website: sohowww.nascom.nasa.gov/home.html To learn more about NASA's Sun Earth Day go here: sunearthday.nasa.gov/2010/index.php

ZnSe quantum dots modified with a Ni(cyclam) catalyst for efficient visible-light driven CO2 reduction in water.

PubMed

Kuehnel, Moritz F; Sahm, Constantin D; Neri, Gaia; Lee, Jonathan R; Orchard, Katherine L; Cowan, Alexander J; Reisner, Erwin

2018-03-07

A precious metal and Cd-free photocatalyst system for efficient CO 2 reduction in water is reported. The hybrid assembly consists of ligand-free ZnSe quantum dots (QDs) as a visible-light photosensitiser combined with a phosphonic acid-functionalised Ni(cyclam) catalyst, NiCycP. This precious metal-free photocatalyst system shows a high activity for aqueous CO 2 reduction to CO (Ni-based TON CO > 120), whereas an anchor-free catalyst, Ni(cyclam)Cl 2 , produced three times less CO. Additional ZnSe surface modification with 2-(dimethylamino)ethanethiol (MEDA) partially suppresses H 2 generation and enhances the CO production allowing for a Ni-based TON CO of > 280 and more than 33% selectivity for CO 2 reduction over H 2 evolution, after 20 h visible light irradiation ( λ > 400 nm, AM 1.5G, 1 sun). The external quantum efficiency of 3.4 ± 0.3% at 400 nm is comparable to state-of-the-art precious metal photocatalysts. Transient absorption spectroscopy showed that band-gap excitation of ZnSe QDs is followed by rapid hole scavenging and very fast electron trapping in ZnSe. The trapped electrons transfer to NiCycP on the ps timescale, explaining the high performance for photocatalytic CO 2 reduction. With this work we introduce ZnSe QDs as an inexpensive and efficient visible light-absorber for solar fuel generation.

Quantification of Shipping Emissions in the Eastern Mediterranean and Comparison with Satellite Observations

NASA Astrophysics Data System (ADS)

Kilic, A.; Unal, A.; Kindap, T.; Karaca, M.; Khan, M. N.

2010-12-01

Shipping is considered as one of the main emission sources worldwide. Recent studies suggest that, in the Mediterrenean, ship emissions are responsible for 10-50% of black carbon, 2-12% ozone in the surface layer and 5-20% for nitrogen dioxide atmospheric column burden (Marmer et al., 2009). It is, therefore, essential to have an accurate emissions estimation for ships. Marmara Sea, an inland sea connecting the Mediterrenean to the Black Sea, has significant marine activity. Marmara region, surrounding the Marmara Sea, has over 30 million population (including Istanbul megacity) with significant emission sources (e.g., on-road traffic, industry). Emission amounts from ships can be calculated based on two different methodologies, one is according to the total amount of bunker fuels for maritime transport sold which is called top down approach and the other is shipping activity-based bottom-up approach. The top-down estimation method is not suitable for calculations of shipping emissions in Turkey since fuel sales cannot be accurately obtained. Also, top-down approaches possibly have some errors, since data assumptions for the average engine power, engine operating hours and emission factors are the most important uncertain inputs. Previously, a few studies based on bottom-up aproach have been carried on about shipping emissions in Marmara Sea according to the shipping statistics belong to Istanbul and Canakkale Straits and port regions. These studies were mainly depending on very rough assumptions such as avearage ship speed, fixed ships routes, generalized engine types and average fuel consumptions. Deniz C. (2008) estimated shipping emissions in 2003, for Marmara Sea and Turkish Straits as 111,000 tons for NOx, 87,000 tons for SO2, 5,451,000 tons for CO2, 4762 tons for PM. Although- between 2003 and 2008- there is approximately 15% increase in number of ships passsing through Turkish Straits, this study shows that, shippings emissions for the same region are estimated to be more than 3 times of previous studies. In this study, Automatic Information System (AIS) records of marine vessels (having 1 minute temporal resolution) for over 10,000 ships operating at the study area (including Marmara Sea, Istanbul and Canakkale Straits and some parts of Black Sea and Aegian Sea) were obtained from Turkish Undersecretariat for Maritime Affairs for the period between August 2008 and August 2009. These records include the position of the ships, gross tonnage and ship types. Using energy based emission factors for each operation mode, minute-by-minute emissions were estimated. Annual emission totals for merchant ships were estimated as 605,000 tons for NOX; 495,000 tons for SO2; 25,600 tons for HC; 53,300 tons for PM and 29,630,000 tons for CO2. This paper presents the methodology and the findings of the emissions estimates for ships. The results will also be compared to satellite observations. For this purpose, CO measurements from MOPITT and SO2 measurements from OMI will be utilized.

Evolution of Earth Like Planets

NASA Astrophysics Data System (ADS)

Monroy-Rodríguez, M. A.; Vega, K. M.

2017-07-01

In order to study and explain the evolution of our own planet we have done a review of works related to the evolution of Earth-like planets. From the stage of proto-planet to the loss of its atmosphere. The planetary formation from the gas and dust of the proto-planetary disk, considering the accretion by the process of migration, implies that the material on the proto-planet is very mixed. The newborn planet is hot and compact, it begins its process of stratification by gravity separation forming a super dense nucleus, an intermediate layer of convective mantle and an upper mantle that is less dense, with material that emerges from zones at very high pressure The surface with low pressure, in this process the planet expands and cools. This process also releases gas to the surface, forming the atmosphere, with the gas gravitationally bounded. The most important thing for the life of the planet is the layer of convective mantle, which produces the magnetic field, when it stops the magnetic field disappears, as well as the rings of van allen and the solar wind evaporates the atmosphere, accelerating the evolution and cooling of the planet. In a natural cycle of cataclysms and mass extinctions, the solar system crosses the galactic disk every 30 million years or so, the increase in the meteorite fall triggers the volcanic activity and the increase in the release of CO2 into the atmosphere reaching critical levels (4000 billion tons) leads us to an extinction by overheating that last 100 000 years, the time it takes CO2 to sediment to the ocean floor. Human activity will lead us to reach critical levels of CO2 in approximately 300 years.

USDA Agriculture and Forestry Greenhouse Gas Inventory: 1990-2013

USDA-ARS?s Scientific Manuscript database

Carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) concentrations in the atmosphere have increased by approximately 43%, 152%, and 20% respectively since about 1750. In 2013, total U.S. greenhouse gas emissions were 6,673 million metric tons of carbon dioxide equivalents (MMT CO2 eq.), ris...

The Greenhouse Gas Emission from Portland Cement Concrete Pavement Construction in China

PubMed Central

Ma, Feng; Sha, Aimin; Yang, Panpan; Huang, Yue

2016-01-01

This study proposes an inventory analysis method to evaluate the greenhouse gas (GHG) emissions from Portland cement concrete pavement construction, based on a case project in the west of China. The concrete pavement construction process was divided into three phases, namely raw material production, concrete manufacture and pavement onsite construction. The GHG emissions of the three phases are analyzed by a life cycle inventory method. The CO2e is used to indicate the GHG emissions. The results show that for 1 km Portland cement concrete pavement construction, the total CO2e is 8215.31 tons. Based on the evaluation results, the CO2e of the raw material production phase is 7617.27 tons, accounting for 92.7% of the total GHG emissions; the CO2e of the concrete manufacture phase is 598,033.10 kg, accounting for 7.2% of the total GHG emissions. Lastly, the CO2e of the pavement onsite construction phase is 8396.59 kg, accounting for only 0.1% of the total GHG emissions. The main greenhouse gas is CO2 in each phase, which accounts for more than 98% of total emissions. N2O and CH4 emissions are relatively insignificant. PMID:27347987

Technical/commercial feasibility study of the production of fuel-grade ethanol from corn: 100-million-gallon-per-year production facility in Myrtle Grove, Louisiana. Volume 1: Executive summary

NASA Astrophysics Data System (ADS)

1982-05-01

An executive summary is given of a detailed feasibility study for a 100 million gallon per year power alcohol plant using corn as feedstock. The proposed plant will ultimately have the capability to produce 100 million gallons per year of anhydrous alcohol from an estimated 40 million bushels of corn and will be designed so as to allow construction in modules of 25 million gallons each. Alcohol produced at this plant is intended essentially for use as a gasoline octane booster, a motor fuel in gasoline/alcohol blends and as a chemical feedstock. In addition, the plant will produce a number of by-products, each of which has existing commercial markets; namely, 236,400 tons of CO2, 237,600 tons of protein meal mixture (40.2% protein), or 124,000 tons of gluten meal (41% protein), 20,000 tons of yeast, 68,400 tons of corn bran, 89,600 tons of corn germ cake and 4,584,000 gallons of corn oil (food grade).

Vehicular volatile organic compounds losses due to refueling and diurnal process in China: 2010-2050.

PubMed

Yang, Xiaofan; Liu, Huan; Cui, Hongyang; Man, Hanyang; Fu, Mingliang; Hao, Jiming; He, Kebin

2015-07-01

Volatile organic compounds (VOCs) are crucial to control air pollution in major Chinese cities since VOCs are the dominant factor influencing ambient ozone level, and also an important precursor of secondary organic aerosols. Vehicular evaporative emissions have become a major and growing source of VOC emissions in China. This study consists of lab tests, technology evaluation, emissions modeling, policy projections and cost-benefit analysis to draw a roadmap for China for controlling vehicular evaporative emissions. The analysis suggests that evaporative VOC emissions from China's light-duty gasoline vehicles were approximately 185,000 ton in 2010 and would peak at 1,200,000 ton in 2040 without control. The current control strategy implemented in China, as shown in business as usual (BAU) scenario, will barely reduce the long-term growth in emissions. Even if Stage II gasoline station vapor control policies were extended national wide (BAU+extended Stage II), there would still be over 400,000 ton fuel loss in 2050. In contrast, the implementation of on-board refueling vapor recovery (ORVR) on new cars could reduce 97.5% of evaporative VOCs by 2050 (BAU+ORVR/BAU+delayed ORVR). According to the results, a combined Stage II and ORVR program is a comprehensive solution that provides both short-term and long-term benefits. The net cost to achieve the optimal total evaporative VOC control is approximately 62 billion CNY in 2025 and 149 billion CNY in 2050. Copyright © 2015. Published by Elsevier B.V.

Global cost estimates of reducing carbon emissions through avoided deforestation

PubMed Central

Kindermann, Georg; Obersteiner, Michael; Sohngen, Brent; Sathaye, Jayant; Andrasko, Kenneth; Rametsteiner, Ewald; Schlamadinger, Bernhard; Wunder, Sven; Beach, Robert

2008-01-01

Tropical deforestation is estimated to cause about one-quarter of anthropogenic carbon emissions, loss of biodiversity, and other environmental services. United Nations Framework Convention for Climate Change talks are now considering mechanisms for avoiding deforestation (AD), but the economic potential of AD has yet to be addressed. We use three economic models of global land use and management to analyze the potential contribution of AD activities to reduced greenhouse gas emissions. AD activities are found to be a competitive, low-cost abatement option. A program providing a 10% reduction in deforestation from 2005 to 2030 could provide 0.3–0.6 Gt (1 Gt = 1 × 105 g) CO2·yr−1 in emission reductions and would require $0.4 billion to $1.7 billion·yr−1 for 30 years. A 50% reduction in deforestation from 2005 to 2030 could provide 1.5–2.7 Gt CO2·yr−1 in emission reductions and would require $17.2 billion to $28.0 billion·yr−1. Finally, some caveats to the analysis that could increase costs of AD programs are described. PMID:18650377

The impact of municipal solid waste treatment methods on greenhouse gas emissions in Lahore, Pakistan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Batool, Syeda Adila; Chuadhry, Muhammad Nawaz

2009-01-15

The contribution of existing municipal solid waste management to emission of greenhouse gases and the alternative scenarios to reduce emissions were analyzed for Data Ganj Bukhsh Town (DGBT) in Lahore, Pakistan using the life cycle assessment methodology. DGBT has a population of 1,624,169 people living in 232,024 dwellings. Total waste generated is 500,000 tons per year with an average per capita rate of 0.84 kg per day. Alternative scenarios were developed and evaluated according to the environmental, economic, and social atmosphere of the study area. Solid waste management options considered include the collection and transportation of waste, collection of recyclablesmore » with single and mixed material bank container systems (SMBCS, MMBCS), material recovery facilities (MRF), composting, biogasification and landfilling. A life cycle inventory (LCI) of the six scenarios along with the baseline scenario was completed; this helped to quantify the CO{sub 2} equivalents, emitted and avoided, for energy consumption, production, fuel consumption, and methane (CH{sub 4}) emissions. LCI results showed that the contribution of the baseline scenario to the global warming potential as CO{sub 2} equivalents was a maximum of 838,116 tons. The sixth scenario had a maximum reduction of GHG emissions in terms of CO{sub 2} equivalents of -33,773 tons, but the most workable scenario for the current situation in the study area is scenario 5. It saves 25% in CO{sub 2} equivalents compared to the baseline scenario.« less

Gas geochemistry and preliminary CO2 output estimation from the island of Kos (Greece)

NASA Astrophysics Data System (ADS)

D'Alessandro, Walter; Daskalopoulou, Kyriaki; Calabrese, Sergio; Longo, Manfredi; Kyriakopoulos, Konstantinos; Gagliano, Antonina Lisa

2017-04-01

Several gas samples have been collected from natural gas manifestations at the island of Kos. Most of them are found underwater along the southern coast of the island. On land two anomalous degassing areas have been recognized. These are characterised by lack of vegetation and after long dry periods by the presence of sulfate salts efflorescences. Almost all the gases are CO2-dominated (CO2 ranging from 88 to 99%) with minor amounts of N2 (up to 7%) and CH4 (up to 2.6%). Only the on-land manifestations have also significant contents of H2 (up to 0.2%) and H2S (up to 0.3%). Only one underwater manifestation is N2-dominated (61-99%) with CH4 (0.6-11%) and low CO2 (0.1-26%). The isotopic composition of He shows values ranging from 0.84 to 6.72 R/RA indicating a sometimes strong mantle contribution with the highest values measured in two of the most strongly degassing areas (Paradise Beach and Volcania). C-isotopic composition of CO2 is in the range from -3.6 to 0.6 ‰ vs V-PDB with most of the values around -1‰ indicating a mixed mantle - limestones origin. Isotopic composition of CH4, ranging from -21.5 to 2.8‰ for C and from -143 to 36‰ for H, points to a geothermal origin with sometimes evident secondary oxidation processes. CO2-flux measurements showed values up to about 10,000 g/m2/day in the areas of Volcania and Kokkino Nero and up to about 50,000 g/m2/day at Paradise beach. Preliminary CO2 output estimations gave values of 8.8 and 4 tons/day for the first two areas respectively and of 2.7 tons/day for the latter. The total output of the island (15.5 tons/day) should be considered a minimum estimation because of the incomplete coverage of the area and is comparable to the other active volcanic/geothermal systems of Greece (Nisyros, Nea Kameni and Methana).

The impacts of electricity dispatch protocols on the emission reductions due to wind power and carbon tax.

PubMed

Yu, Yang; Rajagopal, Ram

2015-02-17

Two dispatch protocols have been adopted by electricity markets to deal with the uncertainty of wind power but the effects of the selection between the dispatch protocols have not been comprehensively analyzed. We establish a framework to compare the impacts of adopting different dispatch protocols on the efficacy of using wind power and implementing a carbon tax to reduce emissions. We suggest that a market has high potential to achieve greater emission reduction by adopting the stochastic dispatch protocol instead of the static protocol when the wind energy in the market is highly uncertain or the market has enough adjustable generators, such as gas-fired combustion generators. Furthermore, the carbon-tax policy is more cost-efficient for reducing CO2 emission when the market operates according to the stochastic protocol rather than the static protocol. An empirical study, which is calibrated according to the data from the Electric Reliability Council of Texas market, confirms that using wind energy in the Texas market results in a 12% CO2 emission reduction when the market uses the stochastic dispatch protocol instead of the 8% emission reduction associated with the static protocol. In addition, if a 6$/ton carbon tax is implemented in the Texas market operated according to the stochastic protocol, the CO2 emission is similar to the emission level from the same market with a 16$/ton carbon tax operated according to the static protocol. Correspondingly, the 16$/ton carbon tax associated with the static protocol costs 42.6% more than the 6$/ton carbon tax associated with the stochastic protocol.

Wisconsin's forest resources in 2001.

Treesearch

John S. Vissage; Gery J. Brand; Manfred E. Mielke

2003-01-01

Results of the 2001 annual inventory of Wisconsin show about 15.8 million acres of forest land, more than 21.6 billion cubic feet of live volume on forest land, and nearly 584 million dry tons of all live aboveground tree biomass on timberland. Gypsy moth, forest tent caterpillar, twolined chestnut borer, bronze birch borer, ash yellows, and white pine blister rust...

Forest-Based Biomass Supply Curves for the United States

Treesearch

Kenneth Skog; Jamie Barbour; Marilyn Buford; Dennis Drykstra; Patti Lebow; Pat Miles; Bob Perlack; Bryce Stokes

2013-01-01

Nationwide, county-level supply curves have been estimated for forest-based biomass to evaluate their potential contributions to producing biofuels. This study builds on the estimates of potential supply in the Billion Ton Supply study prepared by the U.S. Department of Agriculture and the U.S. Department of Energy. Forest biomass sources include logging...

Minnesota Forest Resources in 2000.

Treesearch

David E. Haugen; Manfred E. Mielke

2002-01-01

Results of the 2000 annual inventory of Minnesota show over 16.5 million acres of forest land, over 17.6 billion cubic feet of all live volume on timberland, and an estimated 429 million dry tons of all live aboveground tree biomass on timberland. Known pests in Minnesota forests include the forest tent caterpillar, spruce budworm, large aspen tortrix, and introduced...

Host-Induced Gene Silencing (HIGS) of aflatoxin synthesis genes in peanut and maize: use of RNA interference and genetic diversity of Aspergillus

USDA-ARS?s Scientific Manuscript database

Approximately 4.5 billion people are chronically exposed to aflatoxins, these are powerful carcinogens produced by Aspergillus flavus and A. parasiticus. High levels of aflatoxins in crops result in approximately 100 million metric tons of cereals, ¬nuts, root crops and other agricultural products ...

Emissions of halocarbons from mobile vehicle air conditioning system in Hong Kong.

PubMed

Yan, H H; Guo, H; Ou, J M

2014-08-15

During the implementation of Montreal Protocol, emission inventories of halocarbons in different sectors at regional scale are fundamental to the formulation of relevant management strategy and inspection of the implementation efficiency. This study investigated the emission profile of halocarbons used in the mobile vehicle air conditioning system, the leading sector of refrigeration industry in terms of the refrigerant bank, market and emission, in the Hong Kong Special Administrative Region, using a bottom-up approach developed by 2006 IPCC Good Practice Guidance. The results showed that emissions of CFC-12 peaked at 53 tons ODP (Ozone Depletion Potential) in 1992 and then gradually diminished, whereas HFC-134a presented an increasing emission trend since 1990s and the emissions of HFC-134a reached 65,000 tons CO2-equivelant (CO2-eq) by the end of 2011. Uncertainty analysis revealed relatively high levels of uncertainties for special-purpose vehicles and government vehicles. Moreover, greenhouse gas (GHG) abatements under different scenarios indicated that potential emission reduction of HFC-134a ranged from 4.1 to 8.4 × 10(5)tons CO2-eq. The findings in this study advance our knowledge of halocarbon emissions from mobile vehicle air conditioning system in Hong Kong. Copyright © 2014 Elsevier B.V. All rights reserved.

New Manufacturing Method for Paper Filler and Fiber Material

DOE Office of Scientific and Technical Information (OSTI.GOV)

Doelle, Klaus

2013-08-25

The use of fillers in printing and writing papers has become a prerequisite for competing in a global market to reduce the cost of materials. Use of calcium carbonates (ranging from 18% to 30%) as filler is a common practice in the paper industry but the choices of fillers for each type of papers vary widely according to its use. The market for uncoated digital printing paper is one that continues to introduce exciting growth projections. and it is important to understand the effect that new manufacturing methods of calcium carbonates have on the energy efficiency and paper production. Research conducted under this award showed that the new fiber filler composite material has the potential to increase the paper filler content by up to 5% without losing mechanical properties. Benefits of the technology can be summarized as follows for a 1% filler increase per metric ton of paper produced: (i) production cost savings overmore » $$12, (ii) Energy savings of 100,900 btu, (iii) CO{sub 2} emission savings of 33 lbs, and additional savings for wood preparation, pulping, recovery of 203593 btu with a 46lbs of CO{sub 2} emission savings per 1% filler increase. In addition the technology has the potential to save: (i) additional $$3 per ton of bleached pulp produced, (ii) bleaching energy savings of 170,000 btu, (iii) bleaching CO{sub 2} emission savings of 39 lbs, and (iv) additional savings for replacing conventional bleaching chemicals with a sustainable bleaching chemical is estimated to be 900,000 btu with a 205 lbs of CO{sub 2} emission savings per ton of bleached pulp produced. All the above translates to a estimated annual savings for a 12% filler increase of 296 trillion buts or 51 million barrel of oil equivalent (BOE) or 13.7% of the industries energy demand. This can lead to a increase of renewable energy usage from 56% to close to 70% for the industry sector. CO{sub 2} emission of the industry at a 12% filler increase could be lowered by over 39 million tons annually. If the new technology could be implemented for bleaching process a total annual estimated energy savings potential of 64 trillion buts or 11 million barrel of oil equivalent (BOE) equal to 3% of the paper industries energy demand could be realized. This could lead to a increase of renewable energy usage from 56% to close to 60% for the industry. CO{sub 2} emissions could be lowered by over 7.4 million tons annually. It is estimated that an installed system could also yield a 75 to 100% return of investment (ROI) rate for the capital equipment that need to be installed for the fiber filler composite manufacturing process.« less

Waste-to-Chemicals for a Circular Economy: The Case of Urea Production (Waste-to-Urea).

PubMed

Antonetti, Elena; Iaquaniello, Gaetano; Salladini, Annarita; Spadaccini, Luca; Perathoner, Siglinda; Centi, Gabriele

2017-03-09

The economics and environmental impact of a new technology for the production of urea from municipal solid waste, particularly the residue-derived fuel (RdF) fraction, is analyzed. Estimates indicate a cost of production of approximately €135 per ton of urea (internal rate of return more than 10 %) and savings of approximately 0.113 tons of CH 4 and approximately 0.78 tons of CO 2 per ton of urea produced. Thus, the results show that this waste-to-urea (WtU) technology is both economically valuable and environmentally advantageous (in terms of saving resources and limiting carbon footprint) for the production of chemicals from municipal solid waste in comparison with both the production of urea with conventional technology (starting from natural gas) and the use of RdF to produce electrical energy (waste-to-energy). A further benefit is the lower environmental impact of the solid residue produced from RdF conversion. The further benefit of this technology is the possibility to realize distributed fertilizer production. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

CO{sub 2} Reuse in Petrochemical Facilities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jason Trembly; Brian Turk; Maruthi Pavani

2010-12-31

To address public concerns regarding the consequences of climate change from anthropogenic carbon dioxide (CO{sub 2}) emissions, the U.S. Department of Energy's National Energy Technology Laboratory (DOE/NETL) is actively funding a CO{sub 2} management program to develop technologies capable of mitigating CO{sub 2} emissions from power plant and industrial facilities. Over the past decade, this program has focused on reducing the costs of carbon capture and storage technologies. Recently, DOE/NETL launched an alternative CO{sub 2} mitigation program focused on beneficial CO{sub 2} reuse to support the development of technologies that mitigate emissions by converting CO{sub 2} into valuable chemicals andmore » fuels. RTI, with DOE/NETL support, has been developing an innovative beneficial CO{sub 2} reuse process for converting CO{sub 2} into substitute natural gas (SNG) by using by-product hydrogen (H{sub 2)-containing fuel gas from petrochemical facilities. This process leveraged commercial reactor technology currently used in fluid catalytic crackers in petroleum refining and a novel nickel (Ni)-based catalyst developed by RTI. The goal was to generate an SNG product that meets the pipeline specifications for natural gas, making the SNG product completely compatible with the existing natural gas infrastructure. RTI's technology development efforts focused on demonstrating the technical feasibility of this novel CO{sub 2} reuse process and obtaining the necessary engineering information to design a pilot demonstration unit for converting about 4 tons per day (tons/day) of CO{sub 2} into SNG at a suitable host site. This final report describes the results of the Phase I catalyst and process development efforts. The methanation activity of several commercial fixed-bed catalysts was evaluated under fluidized-bed conditions in a bench-scale reactor to identify catalyst performance targets. RTI developed two fluidizable Ni-based catalyst formulations (Cat-1 and Cat-3) that demonstrated equal or better performance than that of commercial methanation catalysts. The Cat-1 and Cat-3 formulations were successfully scaled up using commercial manufacturing equipment at the Sud-Chemie Inc. pilot-plant facility in Louisville, KY. Pilot transport reactor testing with RTI's Cat-1 formulation at Kellog Brown & Root's Technology Center demonstrated the ability of the process to achieve high single-pass CO{sub 2} conversion. Using information acquired from bench- and pilot-scale testing, a basic engineering design package was prepared for a 4-ton/day CO{sub 2} pilot demonstration unit, including process and instrumentation diagrams, equipment list, control philosophy, and preliminary cost estimate.« less

40 CFR 98.117 - Records that must be retained.

Code of Federal Regulations, 2014 CFR

2014-07-01

... year. (b) If the carbon mass balance procedure is used to determine CO2 emissions according to the... annual process CO2 emissions (tons). (5) Average carbon content determined and records of the supplier... company records of measurements are used to estimate the carbon input and output to each EAF, including...

40 CFR 98.117 - Records that must be retained.

Code of Federal Regulations, 2012 CFR

2012-07-01

... year. (b) If the carbon mass balance procedure is used to determine CO2 emissions according to the... annual process CO2 emissions (tons). (5) Average carbon content determined and records of the supplier... company records of measurements are used to estimate the carbon input and output to each EAF, including...

40 CFR 98.117 - Records that must be retained.

Code of Federal Regulations, 2013 CFR

2013-07-01

... year. (b) If the carbon mass balance procedure is used to determine CO2 emissions according to the... annual process CO2 emissions (tons). (5) Average carbon content determined and records of the supplier... company records of measurements are used to estimate the carbon input and output to each EAF, including...

40 CFR 98.117 - Records that must be retained.

Code of Federal Regulations, 2011 CFR

2011-07-01

... year. (b) If the carbon mass balance procedure is used to determine CO2 emissions according to the... annual process CO2 emissions (tons). (5) Average carbon content determined and records of the supplier... company records of measurements are used to estimate the carbon input and output to each EAF, including...

Efficient electrochemical CO2 conversion powered by renewable energy.

PubMed

Kauffman, Douglas R; Thakkar, Jay; Siva, Rajan; Matranga, Christopher; Ohodnicki, Paul R; Zeng, Chenjie; Jin, Rongchao

2015-07-22

The catalytic conversion of CO2 into industrially relevant chemicals is one strategy for mitigating greenhouse gas emissions. Along these lines, electrochemical CO2 conversion technologies are attractive because they can operate with high reaction rates at ambient conditions. However, electrochemical systems require electricity, and CO2 conversion processes must integrate with carbon-free, renewable-energy sources to be viable on larger scales. We utilize Au25 nanoclusters as renewably powered CO2 conversion electrocatalysts with CO2 → CO reaction rates between 400 and 800 L of CO2 per gram of catalytic metal per hour and product selectivities between 80 and 95%. These performance metrics correspond to conversion rates approaching 0.8-1.6 kg of CO2 per gram of catalytic metal per hour. We also present data showing CO2 conversion rates and product selectivity strongly depend on catalyst loading. Optimized systems demonstrate stable operation and reaction turnover numbers (TONs) approaching 6 × 10(6) molCO2 molcatalyst(-1) during a multiday (36 h total hours) CO2 electrolysis experiment containing multiple start/stop cycles. TONs between 1 × 10(6) and 4 × 10(6) molCO2 molcatalyst(-1) were obtained when our system was powered by consumer-grade renewable-energy sources. Daytime photovoltaic-powered CO2 conversion was demonstrated for 12 h and we mimicked low-light or nighttime operation for 24 h with a solar-rechargeable battery. This proof-of-principle study provides some of the initial performance data necessary for assessing the scalability and technical viability of electrochemical CO2 conversion technologies. Specifically, we show the following: (1) all electrochemical CO2 conversion systems will produce a net increase in CO2 emissions if they do not integrate with renewable-energy sources, (2) catalyst loading vs activity trends can be used to tune process rates and product distributions, and (3) state-of-the-art renewable-energy technologies are sufficient to power larger-scale, tonne per day CO2 conversion systems.

Physical and economic potential of geological CO2 storage in saline aquifers.

PubMed

Eccles, Jordan K; Pratson, Lincoln; Newell, Richard G; Jackson, Robert B

2009-03-15

Carbon sequestration in sandstone saline reservoirs holds great potential for mitigating climate change, but its storage potential and cost per ton of avoided CO2 emissions are uncertain. We develop a general model to determine the maximum theoretical constraints on both storage potential and injection rate and use it to characterize the economic viability of geosequestration in sandstone saline aquifers. When applied to a representative set of aquifer characteristics, the model yields results that compare favorably with pilot projects currently underway. Over a range of reservoir properties, maximum effective storage peaks at an optimal depth of 1600 m, at which point 0.18-0.31 metric tons can be stored per cubic meter of bulk volume of reservoir. Maximum modeled injection rates predict minima for storage costs in a typical basin in the range of $2-7/ ton CO2 (2005 U.S.$) depending on depth and basin characteristics in our base-case scenario. Because the properties of natural reservoirs in the United States vary substantially, storage costs could in some cases be lower or higher by orders of magnitude. We conclude that available geosequestration capacity exhibits a wide range of technological and economic attractiveness. Like traditional projects in the extractive industries, geosequestration capacity should be exploited starting with the low-cost storage options first then moving gradually up the supply curve.

Land-Use Change and the Billion Ton 2016 Resource Assessment: Understanding the Effects of Land Management on Environmental Indicators

NASA Astrophysics Data System (ADS)

Kline, K. L.; Eaton, L. M.; Efroymson, R.; Davis, M. R.; Dunn, J.; Langholtz, M. H.

2016-12-01

The federal government, led by the U.S. Department of Energy (DOE), quantified potential U.S. biomass resources for expanded production of renewable energy and bioproducts in the 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy (BT16) (DOE 2016). Volume 1 of the report provides analysis of projected supplies from 2015 to2040. Volume 2 (forthcoming) evaluates changes in environmental indicators for water quality and quantity, carbon, air quality, and biodiversity associated with production scenarios in BT16 volume 1. This presentation will review land-use allocations under the projected biomass production scenarios and the changes in land management that are implied, including drivers of direct and indirect LUC. National and global concerns such as deforestation and displacement of food production are addressed. The choice of reference scenario, input parameters and constraints (e.g., regarding land classes, availability, and productivity) drive LUC results in any model simulation and are reviewed to put BT16 impacts into context. The principal LUC implied in BT16 supply scenarios involves the transition of 25-to-47 million acres (net) from annual crops in 2015 baseline to perennial cover by 2040 under the base case and 3% yield growth case, respectively. We conclude that clear definitions of land parameters and effects are essential to assess LUC. A lack of consistency in parameters and outcomes of historic LUC analysis in the U.S. underscores the need for science-based approaches.

Assessing urban forest effects and values, Los Angeles' urban forest

Treesearch

David J. Nowak; Robert E. III Hoehn; Daniel E. Crane; Lorraine Weller; Antonio Davila

2011-01-01

An analysis of trees in Los Angeles, CA, reveals that this area has about 6 million trees with tree and shrub canopies that cover 24.9 percent of the city. The most common tree species are Italian cypress, scrub oak, laurel sumac, Mexican fan palm, and Indian laurel, Trees in Los Angeles currently store about 1.3 million tons of carbon (4.7 million tons CO2...

Consumption-based accounting of CO2 emissions

PubMed Central

Davis, Steven J.; Caldeira, Ken

2010-01-01

CO2 emissions from the burning of fossil fuels are the primary cause of global warming. Much attention has been focused on the CO2 directly emitted by each country, but relatively little attention has been paid to the amount of emissions associated with the consumption of goods and services in each country. Consumption-based accounting of CO2 emissions differs from traditional, production-based inventories because of imports and exports of goods and services that, either directly or indirectly, involve CO2 emissions. Here, using the latest available data, we present a global consumption-based CO2 emissions inventory and calculations of associated consumption-based energy and carbon intensities. We find that, in 2004, 23% of global CO2 emissions, or 6.2 gigatonnes CO2, were traded internationally, primarily as exports from China and other emerging markets to consumers in developed countries. In some wealthy countries, including Switzerland, Sweden, Austria, the United Kingdom, and France, >30% of consumption-based emissions were imported, with net imports to many Europeans of >4 tons CO2 per person in 2004. Net import of emissions to the United States in the same year was somewhat less: 10.8% of total consumption-based emissions and 2.4 tons CO2 per person. In contrast, 22.5% of the emissions produced in China in 2004 were exported, on net, to consumers elsewhere. Consumption-based accounting of CO2 emissions demonstrates the potential for international carbon leakage. Sharing responsibility for emissions among producers and consumers could facilitate international agreement on global climate policy that is now hindered by concerns over the regional and historical inequity of emissions. PMID:20212122

An estimation of traffic related CO2 emissions from motor vehicles in the capital city of, Iran

PubMed Central

2012-01-01

Vehicle exhaust is a major source of anthropogenic carbon dioxide (CO2) in metropolitan cities. Popular community mode (buses and taxies) and about 2.4 million private cars are the main emission sources of air pollution in Tehran. A case survey has conducted to measure CO2 in four popular vehicles, bus, taxi, private car and motorcycle, which moved in the city with respectively 7800, 82358, 560000 and 2.4 million per day in 2012. Results indicated that the contribution of CO2 emissions increased in the following order: private car, motorcycle, bus and taxi. The overall average for the contribution of CO2 emissions in the private car, motorcycle, bus, and taxi were 26372, 1648, 1433 and 374 tons per day, respectively. Our results also showed that the urban transport operation consume an estimated 178 and 4224 million liter diesel and petrol per year, respectively, that have released about 10 million tons of CO2. The average contribution of CO2 emissions of private cars in Tehran was higher (88%) than other vehicles. It was concluded that high volume of traffic, transport consumption of fossil fuels and shortage of adequate public transport system are responsible for the high CO2 level in environment in Tehran. Thus, it is to be expected that CO2 as a greenhouse gas has risen in Tehran more than ever in the following years and this would be a matter of concern for the authorities to have a comprehensive plan to mitigate this phenomena. PMID:23369252

An estimation of traffic related CO2 emissions from motor vehicles in the capital city of, Iran.

PubMed

Kakouei, Aliakbar; Vatani, Ali; Idris, Ahmed Kamal Bin

2012-11-28

Vehicle exhaust is a major source of anthropogenic carbon dioxide (CO2) in metropolitan cities. Popular community mode (buses and taxies) and about 2.4 million private cars are the main emission sources of air pollution in Tehran. A case survey has conducted to measure CO2 in four popular vehicles, bus, taxi, private car and motorcycle, which moved in the city with respectively 7800, 82358, 560000 and 2.4 million per day in 2012. Results indicated that the contribution of CO2 emissions increased in the following order: private car, motorcycle, bus and taxi. The overall average for the contribution of CO2 emissions in the private car, motorcycle, bus, and taxi were 26372, 1648, 1433 and 374 tons per day, respectively. Our results also showed that the urban transport operation consume an estimated 178 and 4224 million liter diesel and petrol per year, respectively, that have released about 10 million tons of CO2. The average contribution of CO2 emissions of private cars in Tehran was higher (88%) than other vehicles. It was concluded that high volume of traffic, transport consumption of fossil fuels and shortage of adequate public transport system are responsible for the high CO2 level in environment in Tehran. Thus, it is to be expected that CO2 as a greenhouse gas has risen in Tehran more than ever in the following years and this would be a matter of concern for the authorities to have a comprehensive plan to mitigate this phenomena.

Global Biogenic Emission of Carbon Dioxide from Landfills

NASA Astrophysics Data System (ADS)

Lima, R.; Nolasco, D.; Meneses, W.; Salazar, J.; Hernández, P.; Pérez, N.

2002-12-01

Human-induced increases in the atmospheric concentrations of greenhouse gas components have been underway over the past century and are expected to drive climate change in the coming decades. Carbon dioxide was responsible for an estimated 55 % of the antropogenically driven radiactive forcing of the atmosphere in the 1980s and is predicted to have even greater importance over the next century (Houghton et al., 1990). A highly resolved understanding of the sources and sinks of atmospheric CO2, and how they are affected by climate and land use, is essential in the analysis of the global carbon cycle and how it may be impacted by human activities. Landfills are biochemical reactors that produce CH4 and CO2 emissions due to anaerobic digestion of solid urban wastes. Estimated global CH4 emission from landfills is about 44 millions tons per year and account for a 7.4 % of all CH4 sources (Whiticar, 1989). Observed CO2/CH4 molar ratios from landfill gases lie within the range of 0.7-1.0; therefore, an estimated global biogenic emission of CO2 from landfills could reach levels of 11.2-16 millions tons per year. Since biogas extraction systems are installed for extracting, purifying and burning the landfill gases, most of the biogenic gas emission to the atmosphere from landfills occurs through the surface environment in a diffuse and disperse form, also known as non-controlled biogenic emission. Several studies of non-controlled biogenic gas emission from landfills showed that CO2/CH4 weight ratios of surface landfill gases, which are directly injected into the atmosphere, are about 200-300 times higher than those observed in the landfill wells, which are usually collected and burned by gas extraction systems. This difference between surface and well landfill gases is mainly due to bacterial oxidation of the CH4 to CO2 inducing higher CO2/CH4 ratios for surface landfill gases than those well landfill gases. Taking into consideration this observation, the global biogenic CO2 emission from landfills could be estimated about 8.8-13.2\\times103 million tons per year, equivalent to a 0.04-0.06 % of the fossil fuel emission of CO2.

Carbon dioxide capture from atmospheric air using sodium hydroxide spray.

PubMed

Stolaroff, Joshuah K; Keith, David W; Lowry, Gregory V

2008-04-15

In contrast to conventional carbon capture systems for power plants and other large point sources, the system described in this paper captures CO2 directly from ambient air. This has the advantages that emissions from diffuse sources and past emissions may be captured. The objective of this research is to determine the feasibility of a NaOH spray-based contactor for use in an air capture system by estimating the cost and energy requirements per unit CO2 captured. A prototype system is constructed and tested to measure CO2 absorption, energy use, and evaporative water loss and compared with theoretical predictions. A numerical model of drop collision and coalescence is used to estimate operating parameters for a full-scale system, and the cost of operating the system per unit CO2 captured is estimated. The analysis indicates that CO2 capture from air for climate change mitigation is technically feasible using off-the-shelf technology. Drop coalescence significantly decreases the CO2 absorption efficiency; however, fan and pump energy requirements are manageable. Water loss is significant (20 mol H2O/mol CO2 at 15 degrees C and 65% RH) but can be lowered by appropriately designing and operating the system. The cost of CO2 capture using NaOH spray (excluding solution recovery and CO2 sequestration, which may be comparable) in the full-scale system is 96 $/ton-CO2 in the base case, and ranges from 53 to 127 $/ton-CO2 under alternate operating parameters and assumptions regarding capital costs and mass transfer rate. The low end of the cost range is reached by a spray with 50 microm mean drop diameter, which is achievable with commercially available spray nozzles.

[Direct and indirect costs associated with respiratory allergic diseases in Italy. A probabilistic cost of illness study].

PubMed

Marcellusi, Andrea; Viti, Raffaella; Incorvaia, Cristoforo; Mennini, Francesco Saverio

2015-10-01

The respiratory allergies, including allergic rhinitis and allergic asthma, represent a substantial medical and economic burden worldwide. Despite their dimension and huge economic-social burden, no data are available on the costs associated with the management of respiratory allergic diseases in Italy. The objective of this study was to estimate the average annual cost incurred by the National Health Service (NHS), as well as society, due to respiratory allergies and their main co-morbidities in Italy. A probabilistic prevalence-based cost of illness model was developed to estimate an aggregate measure of the economic burden associated with respiratory allergies and their main co-morbidities in terms of direct and indirect costs. A systematic literature review was performed in order to identify both the cost per case (expressed in present value) and the number of affected patients, by applying an incidence-based estimation method. Direct costs were estimated multiplying the hospitalization, drugs and management costs derived by the literature with the Italian epidemiological data. Indirect costs were calculated based on lost productivity according to the human capital approach. Furthermore, a one-way and probabilistic sensitivity analysis with 5,000 Monte Carlo simulations were performed, in order to test the robustness of the results and define the proper 95% Confidence Interval (CI). Overall, the total economic burden associated with respiratory allergies and their main co-morbidities was € 7.33 billion (95% CI: € 5.99-€ 8.82). A percentage of 27.5% was associated with indirect costs (€ 2.02; 95% CI: € 1.72-€ 2.34 billion) and 72.5% with direct costs (€ 5.32; 95% CI: € 4.04-€ 6.77 billion). In allergic asthma, allergic rhinitis, combined allergic rhinitis and asthma, turbinate hypertrophy and allergic conjunctivitis, the model estimate an average annual economic burden of € 1,35 (95% CI: € 1,14-€ 1,58) billion, € 1,72 (95% CI: € 1,14-€ 2,43) billion, € 1,62 billion (€ 0,91-€ 2,53) billion, € 0,12 (€ 0,07-€ 0,17) billion, € 0,46 (€ 0,16-€ 0,92) billion respectively. To our knowledge, this is the first study in which direct costs (incurred by NHS) and indirect ones (incurred by the society) were taken into account to estimate the overall burden associated with respiratory allergies and their main co-morbidities in our Country. In conclusion, this work may be considered an efficient tool for public decision-makers to correctly understand the economic aspects involved by the management and treatment of respiratory allergies-induced diseases in Italy.

Room-temperature ionic liquids and composite materials: platform technologies for CO(2) capture.

PubMed

Bara, Jason E; Camper, Dean E; Gin, Douglas L; Noble, Richard D

2010-01-19

Clean energy production has become one of the most prominent global issues of the early 21st century, prompting social, economic, and scientific debates regarding energy usage, energy sources, and sustainable energy strategies. The reduction of greenhouse gas emissions, specifically carbon dioxide (CO(2)), figures prominently in the discussions on the future of global energy policy. Billions of tons of annual CO(2) emissions are the direct result of fossil fuel combustion to generate electricity. Producing clean energy from abundant sources such as coal will require a massive infrastructure and highly efficient capture technologies to curb CO(2) emissions. Current technologies for CO(2) removal from other gases, such as those used in natural gas sweetening, are also capable of capturing CO(2) from power plant emissions. Aqueous amine processes are found in the vast majority of natural gas sweetening operations in the United States. However, conventional aqueous amine processes are highly energy intensive; their implementation for postcombustion CO(2) capture from power plant emissions would drastically cut plant output and efficiency. Membranes, another technology used in natural gas sweetening, have been proposed as an alternative mechanism for CO(2) capture from flue gas. Although membranes offer a potentially less energy-intensive approach, their development and industrial implementation lags far behind that of amine processes. Thus, to minimize the impact of postcombustion CO(2) capture on the economics of energy production, advances are needed in both of these areas. In this Account, we review our recent research devoted to absorptive processes and membranes. Specifically, we have explored the use of room-temperature ionic liquids (RTILs) in absorptive and membrane technologies for CO(2) capture. RTILs present a highly versatile and tunable platform for the development of new processes and materials aimed at the capture of CO(2) from power plant flue gas and in natural gas sweetening. The desirable properties of RTIL solvents, such as negligible vapor pressures, thermal stability, and a large liquid range, make them interesting candidates as new materials in well-known CO(2) capture processes. Here, we focus on the use of RTILs (1) as absorbents, including in combination with amines, and (2) in the design of polymer membranes. RTIL amine solvents have many potential advantages over aqueous amines, and the versatile chemistry of imidazolium-based RTILs also allows for the generation of new types of CO(2)-selective polymer membranes. RTIL and RTIL-based composites can compete with, or improve upon, current technologies. Moreover, owing to our experience in this area, we are developing new imidazolium-based polymer architectures and thermotropic and lyotropic liquid crystals as highly tailorable materials based on and capable of interacting with RTILs.

Some field experience with subsynchronous vibration of centrifugal compressors

NASA Technical Reports Server (NTRS)

Wang, Xi-Xuan; Gu, Jin-Chu; Shen, Qin-Gen; Hua, Yong-Li; Zhu, Lan-Sheng; Du, Yun-Tian

1989-01-01

A lot of large chemical fertilizer plants producing 1000 ton NH3/day and 1700 ton urea/day were constructed in the 1970's in China. During operation, subsynchronous vibration takes place occasionally in some of the large turbine-compressor sets and has resulted in heavy economic losses. Two cases of subsynchronous vibration are described: Self-excited vibration of the low-pressure (LP) cylinder of one kind of N2-H2 multistage compressor; and Forced subsynchronous vibration of the high-pressure (HP) cylinder of the CO2 compressor.

Estimates of in-place oil shale of various grades in federal lands, Piceance Basin, Colorado

USGS Publications Warehouse

Mercier, Tracey J.; Johnson, Ronald C.; Brownfield, Michael E.

2010-01-01

The entire oil shale interval in the Piceance Basin is subdivided into seventeen “rich” and “lean” zones that were assessed separately. These zones are roughly time-stratigraphic units consisting of distinctive, laterally continuous sequences of oil shale beds that can be traced throughout much of the Piceance Basin. Several subtotals of the 1.5 trillion barrels total were calculated: (1) about 920 billion barrels (60 percent) exceed 15 gallons per ton (GPT); (2) about 352 billion barrels (23 percent) exceed 25 GPT; (3) more than one trillion barrels (70 percent) underlie Federally-managed lands; and (4) about 689 billion barrels (75 percent) of the 15 GPT total and about 284 billion barrels (19 percent) of the 25 GPT total are under Federal mineral (subsurface) ownership. These 15 and 25 GPT estimates include only those areas where the weighted average of an entire zone exceeds those minimum cutoffs. In areas where the entire zone does not meet the minimum criteria, some oil shale intervals of significant thicknesses could exist within the zone that exceed these minimum cutoffs. For example, a 30-ft interval within an oil shale zone might exceed 25 GPT but if the entire zone averages less than 25 GPT, these resources are not included in the 15 and 25 GPT subtotals, although they might be exploited in the future.

In-place oil shale resources of the Mahogany zone sorted by grade, overburden thickness and stripping ratio, Green River Formation, Piceance Basin, Colorado and Uinta Basin, Utah

USGS Publications Warehouse

Birdwell, Justin E.; Mercier, Tracey J.; Johnson, Ronald C.; Brownfield, Michael E.

2015-01-01

A range of geological parameters relevant to mining oil shale have been examined for the Mahogany zone of the Green River Formation in the Piceance Basin, Colorado, and Uinta Basin, Utah, using information available in the U.S. Geological Survey Oil Shale Assessment database. Basinwide discrete and cumulative distributions of resource in-place as a function of (1) oil shale grade, (2) Mahogany zone thickness, (3) overburden thickness, and (4) stripping ratio (overburden divided by zone thickness) were determined for both basins on a per-acre basis, and a resource map showing the areal distribution of these properties was generated. Estimates of how much of the Mahogany zone resource meets various combinations of these parameters were also determined. Of the 191.7 billion barrels of Mahogany zone oil in-place in the Piceance Basin, 32.3 percent (61.8 billion barrels) is associated with oil shale yielding at least 25 gallons of oil per ton (GPT) of rock processed, is covered by overburden 1,000 feet thick or less, and has a stripping ratio of less than 10. In the Uinta Basin, 14.0 percent (29.9 billion barrels) of the 214.5 billion barrels of Mahogany zone oil in-place meets the same overburden and stripping ratio criteria but only for the lower grade cutoff of 15 GPT.

Wisconsin's forest resources in 2004

Treesearch

Charles H. Perry

2006-01-01

Results of the 2000-2004 annual inventory of Wisconsin show about 16.0 million acres of forest land, more than 22.1 billion cubic feet of live volume on forest land, and nearly 593 million dry tons of all live aboveground tree biomass on timberland. Populations of jack pine budworm are increasing, and it remains a significant pest in Wisconsin forests. A complete...

Projections of forest contributions to global carbon cycles

Treesearch

Michael E. Goerndt; Stephen R. Shifley; Patrick D. Miles; Dave Wear; Francisco X. Aguilar

2016-01-01

Forests cover 42 percent of the Northern United States, and collectively they store 13 billion tons of carbon in live trees (29 percent), roots (6 percent), forest floor (9 percent), dead trees (6 percent), and soils (50 percent). About half the biomass of a live tree (dry weight basis) is sequestered carbon (Woodall et al. 2011) - not the largest but the most dynamic...

Wisconsin's forest resources in 2003

Treesearch

John S. Vissage; Gary J. Brand; J.E. Cummings-Carlson,

2005-01-01

Results of the 2003 annual inventory of Wisconsin show about 15.9 million acres of forest land, over 21.9 billion cubic feet of live volume on forest land, and nearly 591 million dry tons of all live aboveground tree biomass on timberland. Gypsy moth, forest tent caterpillar, twolined chestnut borer, bronze birch borer, ash yellows, and oak wilt were among the pests of...

Updating FRCS, the Fuel Reduction Cost Simulator, for national biomass assessments

Treesearch

Dennis Dykstra; Bruce Hartsough; Bryce. Stokes

2009-01-01

In 2005 the USDA and DOE jointly published a report concluding that it would be technically feasible to supply a billion dry tons of biomass annually from farms and forests throughout the United States in support of an emerging bioenergy and bioproducts industry. The report was criticized because it defined "supply" largely in terms of physical availability...

Detection of pathogens, indicators, and antibiotic resistance genes following land application of poultry litter

USDA-ARS?s Scientific Manuscript database

The United States (U.S.) is the world’s largest producer of poultry with over eight billion broilers produced yearly. Poultry litter (PL) is a mixture of manure, bedding, feathers, and spilled feed that is a by-product of broiler production. In 2009, the U.S. produced more than 50 million tons of PL...

Preliminary report on the coal resources of the National Petroleum Reserve in Alaska

USGS Publications Warehouse

Martin, G.C.; Callahan, J.E.

1978-01-01

NPR-A, located on the Arctic slope of Northern Alaska, is underlain by a thick sequence of sedimentary rocks of Cretaceous age which attain a thickness of as much as 4600 m (15,000 feet). The bulk of the coal resources occurs in rocks of the Nanushuk Group of Early and Late Cretaceous age. The Nanushuk Group is a wedge-shaped unit of marginal marine and nonmarine rocks that is as thick as 3300 m (11,000 feet) just west of NPR-A. Within the reserve, coal occurs primarily in the middle and thicker portions of this clastic wedge and occurs stratigraphically in the upper half of the section. Specific data on individual coal beds or zones are scarce, and estimates of identified coal resources of about 49.5 billion tons represent a sampling of coal resources too small to give a realistic indication of the potential resources for an area so large. Estimates of undiscovered resources suggest hypothetical resources of between 330 billion and 3.3 trillion tons. The wide range in the undiscovered resource estimates reflects the scarcity and ambiguity of the available data but also suggests the presence of a potentially large coal resource.

USGS Arctic Ocean carbon cruise 2010: field activity H-03-10-AR to collect carbon data in the Arctic Ocean, August - September 2010

USGS Publications Warehouse

Robbins, Lisa L.; Yates, Kimberly K.; Gove, Matthew D.; Knorr, Paul O.; Wynn, Jonathan; Byrne, Robert H.; Liu, Xuewu

2013-01-01

Carbon dioxide (CO2) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form carbonic acid, a weak, naturally occurring acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

USGS Arctic Ocean carbon cruise 2011: field activity H-01-11-AR to collect carbon data in the Arctic Ocean, August - September 2011

USGS Publications Warehouse

Robbins, Lisa L.; Yates, Kimberly K.; Knorr, Paul O.; Wynn, Jonathan; Lisle, John; Buczkowski, Brian J.; Moore, Barbara; Mayer, Larry; Armstrong, Andrew; Byrne, Robert H.; Liu, Xuewu

2013-01-01

Carbon dioxide (CO2) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form a weak, naturally occurring acid called carbonic acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

Gas measurements from the Costa Rica-Nicaragua volcanic segment suggest possible along-arc variations in volcanic gas chemistry

NASA Astrophysics Data System (ADS)

Aiuppa, A.; Robidoux, P.; Tamburello, G.; Conde, V.; Galle, B.; Avard, G.; Bagnato, E.; De Moor, J. M.; Martínez, M.; Muñóz, A.

2014-12-01

Obtaining accurate estimates of the CO2 output from arc volcanism requires a precise understanding of the potential along-arc variations in volcanic gas chemistry, and ultimately of the magmatic gas signature of each individual arc segment. In an attempt to more fully constrain the magmatic gas signature of the Central America Volcanic Arc (CAVA), we present here the results of a volcanic gas survey performed during March and April 2013 at five degassing volcanoes within the Costa Rica-Nicaragua volcanic segment (CNVS). Observations of the volcanic gas plume made with a multicomponent gas analyzer system (Multi-GAS) have allowed characterization of the CO2/SO2-ratio signature of the plumes at Poás (0.30±0.06, mean ± SD), Rincón de la Vieja (27.0±15.3), and Turrialba (2.2±0.8) in Costa Rica, and at Telica (3.0±0.9) and San Cristóbal (4.2±1.3) in Nicaragua (all ratios on molar basis). By scaling these plume compositions to simultaneously measured SO2 fluxes, we estimate that the CO2 outputs at CNVS volcanoes range from low (25.5±11.0 tons/day at Poás) to moderate (918 to 1270 tons/day at Turrialba). These results add a new information to the still fragmentary volcanic CO2 output data set, and allow estimating the total CO2 output from the CNVS at 2835±1364 tons/day. Our novel results, with previously available information about gas emissions in Central America, are suggestive of distinct volcanic gas CO2/ST (= SO2 + H2S)-ratio signature for magmatic volatiles in Nicaragua (∼3) relative to Costa Rica (∼0.5-1.0). We also provide additional evidence for the earlier theory relating the CO2-richer signature of Nicaragua volcanism to increased contributions from slab-derived fluids, relative to more-MORB-like volcanism in Costa Rica. The sizeable along-arc variations in magmatic gas chemistry that the present study has suggested indicate that additional gas observations are urgently needed to more-precisely confine the volcanic CO2 from the CAVA, and from global arc volcanism.

The Characteristics of Peats and Co2 Emission Due to Fire in Industrial Plant Forests

NASA Astrophysics Data System (ADS)

Ratnaningsih, Ambar Tri; Rayahu Prasytaningsih, Sri

2017-12-01

Riau Province has a high threat to forest fire in peat soils, especially in industrial forest areas. The impact of fires will produce carbon (CO2) emissions in the atmosphere. The magnitude of carbon losses from the burning of peatlands can be estimated by knowing the characteristics of the fire peat and estimating CO2 emissions produced. The objectives of the study are to find out the characteristics of fire-burning peat, and to estimate carbon storage and CO2 emissions. The location of the research is in the area of industrial forest plantations located in Bengkalis Regency, Riau Province. The method used to measure peat carbon is the method of lost in ignation. The results showed that the research location has a peat depth of 600-800 cm which is considered very deep. The Peat fiber content ranges from 38 to 75, classified as hemic peat. The average bulk density was 0.253 gram cm-3 (0.087-0,896 gram cm-3). The soil ash content is 2.24% and the stored peat carbon stock with 8 meter peat thickness is 10723,69 ton ha-1. Forest fire was predicted to burn peat to a depth of 100 cm and produced CO2 emissions of 6,355,809 tons ha-1.

Geopolymers in Construction / Zastosowanie Geopolimerów W Budownictwie

NASA Astrophysics Data System (ADS)

Błaszczyński, Tomasz Z.; Król, Maciej R.

2015-03-01

Within the framework of quests of supplementary and "healthier" binders to the production of concrete followed the development of geopolymers in construction. However the practical application of these materials is still very limited. The production of each ton of cement introduces one ton of CO2 into the atmosphere. According to various estimations, the synthesis of geopolymers absorbs 2-3 times less energy than the Portland cement and causes a generation of 4-8 times less of CO2. Geopolymeric concretes possess a high compressive strength, very small shrinkage and small creep, and they possess a high resistance to acid and sulphate corrosion. These concretes are also resistant to carbonate corrosion and possess a very high fire resistance and also a high resistance to UV radiation. W ramach poszukiwania zastępczych i "zdrowszych" spoiw do produkcji betonu nastąpił rozwój geopolimerów w budownictwie. Jednakże praktyczne zastosowanie tych materiałów jest jeszcze nadal bardzo ograniczone. Produkcja każdej tony cementu wprowadza do atmosfery tonę CO2. Według różnych szacunków, synteza geopolimerów pochłania 2-3 razy mniej energii, niż cementu portlandzkiego oraz powoduje wydzielenie 4-8 razy mniejszej ilości CO2. Do tego betony geopolimerowe posiadają wysoką wytrzymałość na ściskanie, bardzo mały skurcz i małe pełzanie oraz dają wysoką odporność na korozję kwasową i siarczanową. Betony te są także odporne na korozję węglanową i posiadają bardzo wysoką odporność ogniową, a także wysoką odporność na promieniowanie UV.

Development of Novel Porous Sorbents for Extraction of Uranium from Seawater

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, Wenbin

Climate disruption is one of the greatest crises the global community faces in the 21st century. Alarming increases in CO 2, NO, SO 2 and particulate matter levels will have catastrophic consequences on the environment, food supplies, and human health if no action is taken to lessen their worldwide prevalence. Nuclear energy remains the only mature technology capable of continuous base-load power generation with ultralow carbon dioxide, nitric oxide, and sulfur dioxide emissions. Over the lifetime of the technology, nuclear energy outputs less than 1.5% the carbon dioxide emissions per gigawatt hour relative to coal—about as much as onshore windmore » power.1 However, in order for nuclear energy to be considered a viable option in the future, a stable supply of uranium must be secured. Current estimates suggest there is less than 100 years’ worth of uranium left in terrestrial ores (6.3 million tons) if current consumption levels remain unchanged.2 It is likely, however, that demand for nuclear fuel will rise as a direct consequence of the ratification of global climate accords. The oceans, containing approximately 4.5 billion tons of uranium (U) at a uniform concentration of ~3 ppb, represent a virtually limitless supply of this resource.3 Development of technologies to recover uranium from seawater would greatly improve the U resource availability, providing a U price ceiling for the current generation and sustaining the nuclear fuel supply for future generations. Several methods have been previously evaluated for uranium sequestration including solvent extraction, ion exchange, flotation, biomass collection, and adsorption; however, none have been found to be suitable for reasons including cost effectiveness, long term stability, and selectivity.4,5 While polymer beads and fibers have been functionalized with amidoxime functional groups to afford U adsorption capacities as high as 1.5 g U/kg,6 further discoveries are needed to make uranium extraction from seawater economically feasible.« less

Life cycle assessment of Chinese shrimp farming systems targeted for export and domestic sales.

PubMed

Cao, Ling; Diana, James S; Keoleian, Gregory A; Lai, Qiuming

2011-08-01

We conducted surveys of six hatcheries and 18 farms for data inputs to complete a cradle-to-farm-gate life cycle assessment (LCA) to evaluate the environmental performance for intensive (for export markets in Chicago) and semi-intensive (for domestic markets in Shanghai) shrimp farming systems in Hainan Province, China. The relative contribution to overall environmental performance of processing and distribution to final markets were also evaluated from a cradle-to-destination-port perspective. Environmental impact categories included global warming, acidification, eutrophication, cumulative energy use, and biotic resource use. Our results indicated that intensive farming had significantly higher environmental impacts per unit production than semi-intensive farming in all impact categories. The grow-out stage contributed between 96.4% and 99.6% of the cradle-to-farm-gate impacts. These impacts were mainly caused by feed production, electricity use, and farm-level effluents. By averaging over intensive (15%) and semi-intensive (85%) farming systems, 1 metric ton (t) live-weight of shrimp production in China required 38.3 ± 4.3 GJ of energy, as well as 40.4 ± 1.7 t of net primary productivity, and generated 23.1 ± 2.6 kg of SO(2) equiv, 36.9 ± 4.3 kg of PO(4) equiv, and 3.1 ± 0.4 t of CO(2) equiv. Processing made a higher contribution to cradle-to-destination-port impacts than distribution of processed shrimp from farm gate to final markets in both supply chains. In 2008, the estimated total electricity consumption, energy consumption, and greenhouse gas emissions from Chinese white-leg shrimp production would be 1.1 billion kW·h, 49 million GJ, and 4 million metric tons, respectively. Improvements suggested for Chinese shrimp aquaculture include changes in feed composition, farm management, electricity-generating sources, and effluent treatment before discharge. Our results can be used to optimize market-oriented shrimp supply chains and promote more sustainable shrimp production and consumption.

Air pollution removal by trees in public green spaces in Strasbourg city, France

Treesearch

Wissal Selmi; Christiane Weber; Emmanuel Riviere; Nadege Blond; Lotfi Mehdi; David Nowak

2016-01-01

This study integrates i-Tree Eco model in order to estimate air pollution removal by urban trees in Strasbourg city, France. Applied for the first time in a French city, the model shows that public trees, i.e., trees managed by the city, removed about 88 t of pollutants during one year period (from July 2012 to June 2013): about 1 ton for CO; 14 tons for NO2...

An Investigation on the Effects of Ship Sourced Emissions in Izmir Port, Turkey

PubMed Central

Saraçoğlu, Halil; Kılıç, Alper

2013-01-01

Maritime transportation is a major source of climate change and air pollution. Shipping emissions cause severe impacts on health and environment. These effects of emissions are emerged especially in territorial waters, inland seas, canals, straits, bays, and port regions. In this paper, exhaust gas emissions from ships in Izmir Port, which is one of the main ports in Turkey, are calculated by the ship activity-based methodology. Total emissions from ships in the port is estimated as 1923 ton y−1 for NOx, 1405 ton y−1 for SO2, 82753 ton y−1 for CO2, ton y−1 for HC, and 165 ton y−1 for PM in the year 2007. These emissions are classified regarding operation modes and types of ships. The results are compared with the other studies including amounts of exhaust pollutants generated by ships. According to the findings, it is clear that the ships calling the Izmir Port are important air polluting causes of the Izmir city and its surroundings. PMID:24198720

75 FR 81952 - Greenhouse Gas Emissions Standards and Fuel Efficiency Standards for Medium- and Heavy-Duty...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-29

.... The correct values that should have been used in the document are a factor of 1,018 grams of CO 2 per gallon of diesel for conversion of diesel fuel, and a factor of 8,887 grams of CO 2 per gallon of... Sleeper cab Class 7 Class 8 Class 8 2014 Model Year CO2 Grams per Ton-Mile Low Roof 104 79 65 Mid Roof 104...

Carbon footprint of a music festival

NASA Astrophysics Data System (ADS)

Schafer, K. V.

2009-12-01

In an effort to curb CO2 and by extension, greenhouse gas emissions various initiatives have been taken statewide, nationally and internationally. However, benchmarks and metrics are not clearly defined for CO2 and CO2 equivalent accounting. The objective of this study is to estimate the carbon footprint of the Lincoln Park Music Festival which occurs annually in Newark, NJ. This festival runs for three days each summer and consists of music, food vendors, merchandise and a green marketplace. In order to determine the carbon footprint generated by transportation, surveys of participants were analyzed. Of the approximately 40,000 participants in 2009, 3.3% were surveyed. About 30% of respondents commuted to the festival by car with an average of 10 miles traveling distance. Transportation emission amounted to an estimated CO2 emission of 188 metric tons for all three days combined. Trash at the music festival was weighed, components estimated, and potential CO2 emission calculated if incinerated. 63% of the trash was found to be carbon based, which is the equivalent of three metric tons of CO2 if incinerated. The majority of the trash (>60%) could have been recycled, thus significantly reducing the carbon footprint. In order to limit the carbon footprint of this festival, alternative transport options would be advisable as transport accounted for the largest proportion of the carbon footprint at this festival.

Pollutant in palm oil production process.

PubMed

Hosseini, Seyed Ehsan; Abdul Wahid, Mazlan

2015-07-01

Palm oil mill effluent (POME) is a by-product of the palm industry and it releases large amounts of greenhouse gases (GHGs). Water systems are also contaminated by POME if it is released into nonstandard ponds or rivers where it endangers the lives of fish and water fowl. In this paper, the environmental bottlenecks faced by palm oil production were investigated by analyzing the data collected from wet extraction palm oil mills (POMs) located in Malaysia. Strategies for reducing pollution and technologies for GHG reduction from the wet extraction POMs were also proposed. Average GHG emissions produced from processing 1 ton of crude palm oil (CPO) was 1100 kg CO2eq. This amount can be reduced to 200 kg CO2eq by capturing biogases. The amount of GHG emissions from open ponds could be decreased from 225 to 25 kg CO2eq/MT CPO by covering the ponds. Installation of biogas capturing system can decrease the average of chemical oxygen demand (COD) to about 17,100 mg/L and stabilizing ponds in the final step could decrease COD to 5220 mg/L. Using a biogas capturing system allows for the reduction of COD by 80% and simultaneously using a biogas capturing system and by stabilizing ponds can mitigate COD by 96%. Other ways to reduce the pollution caused by POME, including the installation of wet scrubber vessels and increasing the performance of biogas recovery and biogas upgrading systems, are studied in this paper. Around 0.87 m3 POME is produced per 1 ton palm fruit milled. POME consists of around 2% oil, 2-4% suspended solid, 94-96% water. In palm oil mills, more than 90% of GHGs were emitted from POME. From 1 ton crude palm oil, 1100 kg CO2eq GHGs are generated, which can be reduced to 200 kg CO2eq by installation of biogas capturing equipment.

A study on the impact of nuclear power plant construction relative to decommissioning Fossil Fuel Power Plant in order to reduce carbon dioxide emissions using a modified Nordhaus Vensim DICE model

NASA Astrophysics Data System (ADS)

Colpetzer, Jason Lee

The current levels of CO2 emissions and high levels accumulating in the atmosphere have climate scientists concerned. The Dynamic Integrated Climate Economy Model or "DICE" for short is a highly developed model that has been used to simulate climate change and evaluate factors addressing global warming. The model was developed by Yale's Nordhaus along with collaborators and the compilation of numerous scientific publications. The purpose of this study is to recreate DICE using Vensim and modify it to evaluate the use of nuclear power plants (NPPs) as a means to counter global temperature increases in the atmosphere and oceans and the associated cost of damages. The amount of greenhouse gas emissions from a NPP are about 6% per Megawatt as that from a Fossil Fuel Power Plant (FFPP). Based on this, a model was developed to simulate construction of NPPs with subsequent decommissioning of FFPPs with an equivalent power output. The results produced through multiple simulation runs utilizing variable NPP construction rates show that some minor benefit is achievable if all of the more than 10,000 FFPPs currently in operation in the U.S. are replaced with NPPs. The results show that a reduction in CO 2 emissions of 2.48% will occur if all of the FFPPs are decommissioned. At a minimum rate of 50 NPPs constructed per year, the largest reduction in CO2 in the atmosphere, 1.94% or 44.5 billion tons of carbon, is possible. This results in a reduction in global warming of 0.068°C or 1.31%. The results also show that this reduction in global warming will be equivalent to a reduction of 8.2% or $148 B in anticipated annual spending as a result of climate change damages. Further results indicate that using NPPs to address climate change will provide a small benefit; ultimately, it will not be enough to reduce CO2 emissions or atmospheric CO 2 to control global warming. The amount of CO2 in the atmosphere is predicted to be 1055 parts per million (ppm) even in the best case scenario, which is well above the current limit of 350 ppm proposed by Hansen et. al.

Greenhouse gas emissions and energy efficiencies for soybeans and maize cultivated in different agronomic zones: A case study of Argentina.

PubMed

Arrieta, E M; Cuchietti, A; Cabrol, D; González, A D

2018-06-01

Of all human activities, agriculture has one of the highest environmental impacts, particularly related to Greenhouse Gas (GHG) emissions, energy use and land use change. Soybean and maize are two of the most commercialized agricultural commodities worldwide. Argentina contributes significantly to this trade, being the third major producer of soybeans, the first exporter of soymeal and soybean oil, and the third exporter of maize. Despite the economic importance of these crops and the products derived, there are very few studies regarding GHG emissions, energy use and efficiencies associated to Argentinean soybean and maize production. Therefore, the aim of this work is to determine the carbon and energy footprint, as well as the carbon and energy efficiencies, of soybeans and maize produced in Argentina, by analyzing 18 agronomic zones covering an agricultural area of 1.53millionkm 2 . Our results show that, for both crops, the GHG and energy efficiencies at the Pampean region were significantly higher than those at the extra-Pampean region. The national average for production of soybeans in Argentina results in 6.06ton/ton CO 2 -eq emitted to the atmosphere, while 0.887ton of soybean were produced per GJ of energy used; and for maize 5.01ton/ton CO 2 -eq emitted to the atmosphere and 0.740ton of maize were produced per each GJ of energy used. We found that the large differences on yields, GHGs and energy efficiencies between agronomic regions for soybean and maize crop production are mainly driven by climate, particularly mean annual precipitation. This study contributes for the first time to understand the carbon and energy footprint of soybean and maize production throughout several agronomic zones in Argentina. The significant differences found in the productive efficiencies questions on the environmental viability of expanding the agricultural frontier to less suitable lands for crop production. Copyright © 2017 Elsevier B.V. All rights reserved.

Gas-to-gasoline plant half complete

DOE Office of Scientific and Technical Information (OSTI.GOV)

Williams, B.

New Zealand has reached the midpoint in construction of the world's first commercial natural gas-to-gasoline (GTG) plant. Plans call for mid-1985 mechanical completion of the $1.475 billion GTG project in Motunui; limited production would begin by year-end 1985 with the plant fully on-stream by 1986, yielding about 628,000 tons (570,000 metric tons)/yr or about 14,450 bbl/stream-day of high-octane, low-sulfur gasoline. The process configuration combines for the first time on a commercial scale the ICI low-pressure gas-to-methanol scheme with Mobil's fixed bed zeolite catalyst process for converting methanol to gasoline. The GTG plant will be the world's biggest methanol plant andmore » New Zealand's largest grassroots industrial facility.« less

Aboveground tree biomass on productive forest land in Alaska.

Treesearch

John Yarie; Delbert Mead

1982-01-01

Total aboveground woody biomass of trees on forest land that can produce 1.4 cubic m eters per hectare per year of industrial wood in Alaska is 1.33 billion metric tons green weight. The estimated energy value of the standing woody biomass is 11.9 x 10'5 Btu's. Statewide tables of biomass and energy values for softwoods, hardwoods, and species groups are...

All the coal in China.

PubMed

Lenssen, N

1993-01-01

China is emerging as a serious producer of carbon emissions from its burning of coal. China contributes 11% of global carbon emissions, which is still less than its population share. Economic reforms are likely to boost emissions. 33% of all fuel burned in China produces useful energy compared to 50-60% in the USA and Japan. Low prices encourage wasteful use. The Chinese government responds to energy shortages by investing scarce capital in building more mines, power plants, and oil wells. It is unlikely that investing in expanding conventional energy supplies will be a viable solution, regardless of the availability of capital to invest, because air pollution threatens life. Particulate suspension is 14 times greater in China than in the USA. 14% of the country is affected by acid rain. Global warming may be affecting the northern drought prone areas. The solutions must involve greater efficiency. Industrial consumption of energy is more than 66% of energy produced. Energy use for a typical steel or cement factory is 7-75% greater per ton than Western countries, i.e., 55-60% efficiency versus 80% in Europe. The inefficiency is due to poor maintenance and operating procedures and old or obsolete technology. The savings in building a compact, fluorescent light bulb factory is compared to the cost of building coal-fired power plants and transmission facilities. Conservation of heat in northern buildings could be accomplished with boiler improvements, insulation, and double- glazed windows. A $3 billion/year investment could yield a cut in energy demand by nearly 50%. The carbon emissions would be reduced from 1.4 billion tons to 1 billion tons in 2025. Between 1980 and 1985 the energy efficiency program was able to reduce growth in energy from 7% to 4% without slowing growth in industrial production. Since 1985, the government has directed expenditures toward expanding the energy supply, which reduced efficiency expenditures from 10% to 6% of total investment. Alternatives are natural gas or solar, wind, biomass, and geothermal energy. Alternatives are natural gas or solar, wind, biomass, and geothermal energy. International lending agencies must now shift their support to renewable resource development and efficiency improvement and education; an example from industrialized countries would also be very persuasive.

Marine viruses discovered via metagenomics shed light on viral strategies throughout the oceans

NASA Astrophysics Data System (ADS)

Coutinho, Felipe H.; Silveira, Cynthia B.; Gregoracci, Gustavo B.; Thompson, Cristiane C.; Edwards, Robert A.; Brussaard, Corina P. D.; Dutilh, Bas E.; Thompson, Fabiano L.

2017-07-01

Marine viruses are key drivers of host diversity, population dynamics and biogeochemical cycling and contribute to the daily flux of billions of tons of organic matter. Despite recent advancements in metagenomics, much of their biodiversity remains uncharacterized. Here we report a data set of 27,346 marine virome contigs that includes 44 complete genomes. These outnumber all currently known phage genomes in marine habitats and include members of previously uncharacterized lineages. We designed a new method for host prediction based on co-occurrence associations that reveals these viruses infect dominant members of the marine microbiome such as Prochlorococcus and Pelagibacter. A negative association between host abundance and the virus-to-host ratio supports the recently proposed Piggyback-the-Winner model of reduced phage lysis at higher host densities. An analysis of the abundance patterns of viruses throughout the oceans revealed how marine viral communities adapt to various seasonal, temperature and photic regimes according to targeted hosts and the diversity of auxiliary metabolic genes.

76 FR 70429 - Notice of Intent To Prepare an Environmental Impact Statement and Notice of Potential Floodplain...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-11-14

... associated with delivery of feed materials and distribution of products (e.g., access roads, pipelines... Generating Station (Parish Plant) in Fort Bend County, Texas; deliver the CO 2 via a new pipeline to the... tons) of the CO 2 annually from a 250-megawatt equivalent (MWe) flue gas slip stream taken from the 617...

40 CFR 98.276 - Data reporting requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... CO2, CH4, biogenic CH4 N2O, and biogenic N2O (metric tons per year). (b) Annual quantities fossil... weight, expressed as a decimal fraction, e.g., 95% = 0.95). (g) Annual quantities of fossil fuels by type...

Revised Final Environmental Review for the Construction of a New Base Exchange at Kadena Air Base, Okinawa, Japan

DTIC Science & Technology

2007-05-01

factors depending on the corresponding years. Year 2005 through 2009: VOCE = .016 * Trips NOxE = .015 * Trips PM10E = .0022 * Trips COE = .262...Trips Year 2010 and beyond: VOCE = .012 * Trips NOxE = .013 * Trips PM10E = .0022 * Trips COE = .262 * Trips To convert from pounds per day to...tons per year: VOC (tons/yr) = VOCE * DPYII/2000 Nox (tons/yr) = NOxE * DPYII/2000 PM10(tons/yr) = PM10E * DPYII/2000 CO (tons/yr) = COE * DPYII

Navy Explosive Ordnance Disposal School Master Development Plan for Test Area D-51, Eglin Air Force Base, Florida

DTIC Science & Technology

2008-01-25

depending on the corresponding years. Year 2005 through 2009: VOCE = .016 * Trips NOxE = .015 * Trips PM10E = .0022 * Trips COE = .262 * Trips Year...2010 and beyond: VOCE = .012 * Trips NOxE = .013 * Trips PM10E = .0022 * Trips COE = .262 * Trips To convert from pounds per day to tons per year...VOC (tons/yr) = VOCE * DPYII/2000 NOx (tons/yr) = NOxE * DPYII/2000 PM10 (tons/yr) = PM10E * DPYII/2000 CO (tons/yr) = COE * DPYII/2000

Hydrogen recovery from the thermal plasma gasification of solid waste.

PubMed

Byun, Youngchul; Cho, Moohyun; Chung, Jae Woo; Namkung, Won; Lee, Hyeon Don; Jang, Sung Duk; Kim, Young-Suk; Lee, Jin-Ho; Lee, Carg-Ro; Hwang, Soon-Mo

2011-06-15

Thermal plasma gasification has been demonstrated as one of the most effective and environmentally friendly methods for solid waste treatment and energy utilization in many of studies. Therefore, the thermal plasma process of solid waste gasification (paper mill waste, 1.2 ton/day) was applied for the recovery of high purity H(2) (>99.99%). Gases emitted from a gasification furnace equipped with a nontransferred thermal plasma torch were purified using a bag-filter and wet scrubber. Thereafter, the gases, which contained syngas (CO+H(2)), were introduced into a H(2) recovery system, consisting largely of a water gas shift (WGS) unit for the conversion of CO to H(2) and a pressure swing adsorption (PSA) unit for the separation and purification of H(2). It was successfully demonstrated that the thermal plasma process of solid waste gasification, combined with the WGS and PSA, produced high purity H(2) (20 N m(3)/h (400 H(2)-Nm(3)/PMW-ton), up to 99.99%) using a plasma torch with 1.6 MWh/PMW-ton of electricity. The results presented here suggest that the thermal plasma process of solid waste gasification for the production of high purity H(2) may provide a new approach as a future energy infrastructure based on H(2). Copyright © 2011 Elsevier B.V. All rights reserved.

Technical/commercial feasibility study of the production of fuel-grade ethanol from corn: 100-million-gallon-per-year production facility in Myrtle Grove, Louisiana. Volume one. Executive summary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1982-05-31

This Executive Summary is Volume I of 7 volumes of a detailed feasibility study for a 100 million gallon/year Power Alcohol plant using corn as feedstock to be constructed in the vicinity of Belle Chaise, Louisiana, adjacent to an existing grain elevator complex. The proposed plant will ultimately have the capability to produce 100 million gallons/year of anhydrous alcohol from an estimated 40 million bushels of corn and will be designed so as to allow construction in modules of 25 million gallons each. Alcohol produced at this plant is intended essentially for use as a gasoline octane booster, a motormore » fuel in gasoline/alcohol blends and as a chemical feedstock. In addition, the plant will produce a number of by-products, each of which has existing commercial markets; namely, 236,400 tons of CO/sub 2/ 237,600 tons of Protein Meal Mixture (40.2% Protein) or 124,000 tons of Gluten Meal (41% Protein), 20,000 tons of yeast, 68,400 tons of Corn Bran, 89,600 tons of Corn Germ Cake and 4,584,000 gallons of Corn Oil (food grade).« less

Efficient electrochemical CO 2 conversion powered by renewable energy

DOE PAGES

Kauffman, Douglas R.; Thakkar, Jay; Siva, Rajan; ...

2015-06-29

Here, the catalytic conversion of CO 2 into industrially relevant chemicals is one strategy for mitigating greenhouse gas emissions. Along these lines, electrochemical CO 2 conversion technologies are attractive because they can operate with high reaction rates at ambient conditions. However, electrochemical systems require electricity, and CO 2 conversion processes must integrate with carbon-free, renewable-energy sources to be viable on larger scales. We utilize Au 25 nanoclusters as renewably powered CO 2 conversion electrocatalysts with CO 2 → CO reaction rates between 400 and 800 L of CO 2 per gram of catalytic metal per hour and product selectivities betweenmore » 80 and 95%. These performance metrics correspond to conversion rates approaching 0.8–1.6 kg of CO 2 per gram of catalytic metal per hour. We also present data showing CO 2 conversion rates and product selectivity strongly depend on catalyst loading. Optimized systems demonstrate stable operation and reaction turnover numbers (TONs) approaching 6 × 10 6 mol CO 2 molcatalyst–1 during a multiday (36 hours total hours) CO 2electrolysis experiment containing multiple start/stop cycles. TONs between 1 × 10 6 and 4 × 10 6 molCO 2 molcatalyst–1 were obtained when our system was powered by consumer-grade renewable-energy sources. Daytime photovoltaic-powered CO 2 conversion was demonstrated for 12 h and we mimicked low-light or nighttime operation for 24 h with a solar-rechargeable battery. This proof-of-principle study provides some of the initial performance data necessary for assessing the scalability and technical viability of electrochemical CO 2 conversion technologies. Specifically, we show the following: (1) all electrochemical CO 2 conversion systems will produce a net increase in CO 2 emissions if they do not integrate with renewable-energy sources, (2) catalyst loading vs activity trends can be used to tune process rates and product distributions, and (3) state-of-the-art renewable-energy technologies are sufficient to power larger-scale, tonne per day CO 2 conversion systems.« less

Climate and Ocean Circulation During "The Boring Billion" Simulated by CCSM3

NASA Astrophysics Data System (ADS)

Liu, P.; Hu, Y.; Liu, Y.

2017-12-01

The Boring Billion is referred to the era between approximately 1.8 and 0.8 billion years ago. Geological evidence suggests that no dramatic climate changes in the billions of years, at least in terms of permanent glaciation. The atmospheric oxygen maintained at a relatively low level without significant perturbations. Life had a certain degree of evolution with a quite gentle pace. Relative to the Great Oxidation Event occurred previously, and the Snowball Earth Event and Cambrian Explosion occurred afterwards, this billion years was calm in all aspects so it's often referred to as "the Boring Billion". Why were both the climate and oxygen concentration so stable, and how the anoxic condition in the deep ocean maintained are the questions that motivated our research. We use the Atmosphere Ocean General Circulation Model CCSM3 in this study. The climate of the Boring Billion is simulated for two distinct continental configurations reconstructed for 1540 Ma and 1420 Ma, with continental fragments concentrating towards the North Pole and equator, respectively. The solar constant is set to be 10% weaker than that of the present day. The results show that when the concentration of CO2 is 20 times the present atmospheric level (PAL), the global mean surface temperatures are 19 ° C and 20 ° C for the 1540 Ma and 1420 Ma continental configuration, respectively. Large scale permanent glaciers cannot develop in such a warm climate even for the continents at the polar region. The largest mixed-layer depth in the high-latitude ocean is approximately 1200 m and meridional overturning circulation can reach depth of 3000 m with strength of 40 Sv for both continental configuration. This implies that the material and energy exchange between shallow and deep ocean, as well as atmosphere and ocean, is efficient. When CO2 concentration is reduced to 10 PAL, 5 PAL or 2.5 PAL, global average temperature becomes 16 ° C, 13 ° C and 2 ° C respectively, and permanent glaciers start to form at the polar regions. Therefore, our simulations suggest that the CO2 concentration had to be close to or higher than 20 PAL in order for the simulated climate to be consistent with the observations. Moreover, the oceans were not dynamically stratified, to maintain an anoxic deep ocean biogeochemical processes which are not included in the model have to be invoked.

Economic analysis of atmospheric mercury emission control for coal-fired power plants in China.

PubMed

Ancora, Maria Pia; Zhang, Lei; Wang, Shuxiao; Schreifels, Jeremy; Hao, Jiming

2015-07-01

Coal combustion and mercury pollution are closely linked, and this relationship is particularly relevant in China, the world's largest coal consumer. This paper begins with a summary of recent China-specific studies on mercury removal by air pollution control technologies and then provides an economic analysis of mercury abatement from these emission control technologies at coal-fired power plants in China. This includes a cost-effectiveness analysis at the enterprise and sector level in China using 2010 as a baseline and projecting out to 2020 and 2030. Of the control technologies evaluated, the most cost-effective is a fabric filter installed upstream of the wet flue gas desulfurization system (FF+WFGD). Halogen injection (HI) is also a cost-effective mercury-specific control strategy, although it has not yet reached commercial maturity. The sector-level analysis shows that 193 tons of mercury was removed in 2010 in China's coal-fired power sector, with annualized mercury emission control costs of 2.7 billion Chinese Yuan. Under a projected 2030 Emission Control (EC) scenario with stringent mercury limits compared to Business As Usual (BAU) scenario, the increase of selective catalytic reduction systems (SCR) and the use of HI could contribute to 39 tons of mercury removal at a cost of 3.8 billion CNY. The economic analysis presented in this paper offers insights on air pollution control technologies and practices for enhancing atmospheric mercury control that can aid decision-making in policy design and private-sector investments. Copyright © 2015. Published by Elsevier B.V.

Water requirements of the iron and steel industry

USGS Publications Warehouse

Walling, Faulkner B.; Otts, Louis Ethelbert

1967-01-01

Twenty-nine steel plants surveyed during 1957 and 1958 withdrew from various sources about 1,400 billion gallons of water annually and produced 40.8 million tons of ingot steel. This is equivalent to about 34,000 gallons of water per ton of steel. Fifteen iron ore mines and fifteen ore concentration plants together withdrew annually about 89,000 million gallons to produce 15 million tons of iron ore concentrate, or 5,900 gallons per ton of concentrate. About 97 percent of the water used in the steel plants came from surface sources, 2.2 percent was reclaimed sewage, and 1.2 percent was ground water. Steel plants supplied about 96 percent of their own water requirements, although only three plants used self-supplied water exclusively. Water used by the iron ore mines and concentration plants was also predominantly self supplied from surface source. Water use in the iron and steel industry varied widely and depended on the availability of water, age and condition of plants and equipment, kinds of processes, and plant operating procedures. Gross water use in integrated steel plants ranged from 11,200 to 110,000 gallons per ton of steel ingots, and in steel processing plants it ranged from 4,180 to 26,700 gallons per ton. Water reuse also varied widely from 0 to 18 times in integrated steel plants and from 0 to 44 times in steel processing plants. Availability of water seemed to be the principal factor in determining the rate of reuse. Of the units within steel plants, a typical (median) blast furnace required 20,500 gallons of water per ton of pig iron. At the 1956-60 average rate of pig iron consumption, this amounts to about 13,000 gallons per ton of steel ingots or about 40 percent of that required by a typical integrated steel plant 33,200 gallons per ton. Different processes of iron ore concentration are devised specifically for the various kinds of ore. These processes result in a wide range of water use from 124 to 11,300 gallons of water per ton of iron ore concentrate. Water use in concentration plants is related to the physical state of the ore. The data in this report indicate that grain size of the ore is the most important factor; the very fine grained taconite and jasper required the greatest amount of water. Reuse was not widely practiced in the iron ore industry.Consumption of water by integrated steel plants ranged from 0 to 2,010 gallons per ton of ingot steel and by steel processing plants from 120 to 3,420 gallons per ton. Consumption by a typical integrated steel plant was 681 gallons per ton of ingot steel, about 1.8 percent of the intake and about 1 percent of the gross water use. Consumption by a typical steel processing plant was 646 gallons per ton, 18 percent of the intake, and 3.2 percent of the gross water use. The quality of available water was found not to be a critical factor in choosing the location of steel plants, although changes in equipment and in operating procedures are necessary when poor-quality water is used. The use of saline water having a concentration of dissolved solids as much as 10,400 ppm (parts per million) was reported. This very saline water was used for cooling furnaces and for quenching slag. In operations such as rolling steel in which the water comes into contact with the steel being processed, better quality water is used, although water containing as much as 3,410 ppm dissolved solids has been used for this purpose. Treatment of water for use in the iron and steel industry was not widely practiced. Disinfection and treatment for scale and corrosion control were the most frequently used treatment methods.

Immersion Freezing of Coal Combustion Ash Particles from the Texas Panhandle

NASA Astrophysics Data System (ADS)

Whiteside, C. L.; Tobo, Y.; Mulamba, O.; Brooks, S. D.; Mirrielees, J.; Hiranuma, N.

2017-12-01

Coal combustion aerosol particles contribute to the concentrations of ice-nucleating particles (INPs) in the atmosphere. Especially, immersion freezing can be considered as one of the most important mechanisms for INP formation in supercooled tropospheric clouds that exist at temperatures between 0°C and -38°C. The U.S. contains more than 550 operating coal-burning plants consuming 7.2 x 108 metric tons of coal (in 2016) to generate a total annual electricity of >2 billion MW-h, resulting in the emission of at least 4.9 x 105 metric tons of PM10 (particulate matter smaller than 10 µm in diameter). In Texas alone, 19 combustion plants generate 0.15 billion MW-h electricity and >2.4 x 104 metric tons of PM10. Here we present the immersion freezing behavior of combustion fly ash and bottom ash particles collected in the Texas Panhandle region. Two types of particulate samples, namely <45 µm sieved bottom ash (B_Ash_TX_PH) and <45 µm sieved fly ash (F_Ash_TX_PH), were prepared. Afterwards, their immersion freezing abilities were measured using the Cryogenic Refrigerator Applied to Freezing Test (CRAFT) system covering the heterogeneous freezing temperature down to -30 °C. The results were generated and are reported through two metrics, frozen fraction, ffrozen(T), and ice nucleation active site density per unit mass, nm(T) as a function of temperature. Our preliminary results show that an onset increase in ffrozen(T) for B_Ash_TX_PH (ffrozen) occurred as high as at -15°C, whereas the onset for F_Ash_TX_PH is at -18°C. Secondly, B_Ash_TX_PH exhibited a higher nm(-20 °C) of 105 g-1 than that of F_Ash_TX_PH ( 5 x 103 g-1). On the other hand, previous studies on different combustion ash samples have reported that the opposite trend (i.e., ice nucleation efficiency of fly ash is greater than that of bottom ash; Grawe et al., 2016, ACP; Umo et al., 2015, ACP). We will discuss possible reasons for the observed differences. In addition, the results of complementary physico-chemical analyses via X-ray diffraction technique, Raman microscopy and scanning electron microscopy on both ash types will also be presented to relate the crystallographic and chemical properties to their ice nucleation abilities.

Chemistry and fluxes of magmatic gases powering the explosive trachyandesitic phase of Eyjafjallajokull 2010 eruption: constraints on degassing magma volumes and processes

NASA Astrophysics Data System (ADS)

Allard, P.; Burton, M. R.; Oskarsson, N.; Michel, A.; Polacci, M.

2010-12-01

The 2010 Eyjafjallajökull eruption developed in two distinct phases, with initial lateral effusion of alkali basalt since March 20, followed by highly explosive extrusion of a quite homogenous and crystal-poor trachyandesitic magma [1] through the central volcano ice cap between April 14 and May 24. As usual, magmatic volatiles played a key role in the eruption dynamics. Here we report on the chemical composition and the mass output of magmatic gases powering intense explosive activity during the second eruptive phase in early May. On May 8 we could measure the composition of magmatic gases directly issuing from the eruptive vents, by using OP-FTIR spectroscopy from the crater rim (~900 m distance) and molten lava blocks as IR radiation source. FTIR spectra reveal a variable mixture between two gas components equally rich in H2O (91.3 mol%) and CO2 (8%) but differing in their SO2/HCl ratio (up to 3.5 for the main one and 0.5 for the Cl-richer second one). Analysis of S-Cl-F in ash leachates and in ash and lava bomb samples (pyrohydrolysis) show that this second component was generated by greater chlorine loss during extensive magma fragmentation into fine ash. S/Cl and Cl/F ratios from both these analyses and solar occultation FTIR plume sensing indicate a modest fluorine content in emitted gas and its preferential adsorption onto solid particles during plume transport. DOAS traverses under the volcanic plume (4-6 km height), though hampered by dense ash load, gave most reliable SO2 fluxes of 4500-6600 tons d-1 on May 9, consistent with OMI satellite data [2]. These imply the daily co-emission of 7.2x105 tons of H2O, 1.5x105 tons of CO2, 2000 tons of HCl and ≤200 tons of HF. Eyjafjallajökull thus produced more hydrous and relatively CO2-poorer gas, in much greater quantities, during that stage than during its first basaltic phase [3]. Linear variations of dissolved S with TiO2/FeO ratio in nearby Katla alkali magmas [4] suggest possible pre-eruptive S contents of 0.17-0.19 and 0.14-0.16 wt% in Eyjafjallajökull alkali basalt and trachyandesite, respectively. With 0.03 wt% of residual S measured in erupted lavas, we compute the degassing of ~106 m3 d-1 of trachyandesite in early May, compared to only ~3.5x105 m3 d-1 of basalt in early April. The alkali basalt was petrologically equilibrated at ≤2 kbar and 1150°C [1] but, given the CO2/S ratio of basaltic gases from the first phase [3], might have initially contained ≥1 wt% of carbon dioxide at greater depth. Early CO2 exsolution from this uprising basalt and its interaction with more evolved magma in a shallower reservoir beneath Eyjafjallajökull could have generated enough overpressure for triggering the eruption. [1] N. Oskarsson, 2010, http://www.earthice.hi.is/; [2] P. Labazuy et al., OPGC-LMV, Clermont-Ferrand, France, April 2010, http://wwwobs.univ-bpclermont.fr/; [3] Burton et al., Gas composition and flux report, March 2010, http://www.earthice.hi.is/; [4] Thordarson et al., In: Volcanic Degassing, Geol. Soc. London, special public. 213, 2006.

Antimatter Economy

NASA Astrophysics Data System (ADS)

Hansen, Norm

2004-05-01

The Antimatter Economy will bring every country into the 21st century without destroying our environment and turn the Star Trek dream into reality by using antimatter from comets. At the April 2002 joint meeting of the American Physical Society and American Astronomical Society, I announced that comets were composed of antimatter, there were 109 antimatter elements, and the Periodic Table of Elements had been updated to include the antimatter elements. When matter and antimatter come together, energy is produce according to Einstein's equation of mass times the speed of light squared or E = mc2. Antimatter energy creates incredible opportunities for humanity. People in spacecraft will travel to the moon in hours, planets in days, and stars in weeks. Antimatter power will replace fossil plants and produce hydrogen from off-peak electrical power. Hydrogen will supplant gas in cars, trucks, and other vehicles. The billions of ton of coal, billions of barrels of oil, and trillions of cubic feet of natural gas will be used to make trillions of dollars of products to bring countries into the 21st century. Within this millennium, the Worlds Gross National Product will increase from 30 trillion to 3,000 trillion plus 1,500 trillion from space commercialization bringing the Total Gross National Product to 4,500 trillion. Millions of businesses and billions of jobs will be created. However, the real benefits will come from taking billions of people out of poverty and empowering them to pursue their dreams of life, liberty and pursuit of happiness. Please visit www.AntimatterEnergy.com.

Easing food waste could reduce pressure on natural resources

NASA Astrophysics Data System (ADS)

Showstack, Randy

2012-09-01

Calls to reduce food waste and enhance agricultural water efficiency were among the points raised during the 27 August opening session of World Water Week in Stockholm, Sweden. “More than one fourth of all the water we use worldwide is taken to grow over one billion tons of food that nobody eats. That water, together with the billions of dollars spent to grow, ship, package, and purchase the food, is sent down the drain,” said Torgny Holmgren, executive director of the Stockholm International Water Institute, which organizes World Water Week. “Reducing the waste of food is the smartest and most direct route to relieve pressure on water and land resources. It's an opportunity we cannot afford to overlook,” he added.

An Environmental and Economic Evaluation of Pyrolysis for Energy Generation in Taiwan with Endogenous Land Greenhouse Gases Emissions

PubMed Central

Kung, Chih-Chun; McCarl, Bruce A.; Chen, Chi-Chung

2014-01-01

Taiwan suffers from energy insecurity and the threat of potential damage from global climate changes. Finding ways to alleviate these forces is the key to Taiwan’s future social and economic development. This study examines the economic and environmental impacts when ethanol, conventional electricity and pyrolysis-based electricity are available alternatives. Biochar, as one of the most important by-product from pyrolysis, has the potential to provide significant environmental benefits. Therefore, alternative uses of biochar are also examined in this study. In addition, because planting energy crops would change the current land use pattern, resulting in significant land greenhouse gases (GHG) emissions, this important factor is also incorporated. Results show that bioenergy production can satisfy part of Taiwan’s energy demand, but net GHG emissions offset declines if ethanol is chosen. Moreover, at high GHG price conventional electricity and ethanol will be driven out and pyrolysis will be a dominant technology. Fast pyrolysis dominates when ethanol and GHG prices are low, but slow pyrolysis is dominant at high GHG price, especially when land GHG emissions are endogenously incorporated. The results indicate that when land GHG emission is incorporated, up to 3.8 billion kWh electricity can be produced from fast pyrolysis, while up to 2.2 million tons of CO2 equivalent can be offset if slow pyrolysis is applied. PMID:24619159

An environmental and economic evaluation of pyrolysis for energy generation in Taiwan with endogenous land greenhouse gases emissions.

PubMed

Kung, Chih-Chun; McCarl, Bruce A; Chen, Chi-Chung

2014-03-11

Taiwan suffers from energy insecurity and the threat of potential damage from global climate changes. Finding ways to alleviate these forces is the key to Taiwan's future social and economic development. This study examines the economic and environmental impacts when ethanol, conventional electricity and pyrolysis-based electricity are available alternatives. Biochar, as one of the most important by-product from pyrolysis, has the potential to provide significant environmental benefits. Therefore, alternative uses of biochar are also examined in this study. In addition, because planting energy crops would change the current land use pattern, resulting in significant land greenhouse gases (GHG) emissions, this important factor is also incorporated. Results show that bioenergy production can satisfy part of Taiwan's energy demand, but net GHG emissions offset declines if ethanol is chosen. Moreover, at high GHG price conventional electricity and ethanol will be driven out and pyrolysis will be a dominant technology. Fast pyrolysis dominates when ethanol and GHG prices are low, but slow pyrolysis is dominant at high GHG price, especially when land GHG emissions are endogenously incorporated. The results indicate that when land GHG emission is incorporated, up to 3.8 billion kWh electricity can be produced from fast pyrolysis, while up to 2.2 million tons of CO2 equivalent can be offset if slow pyrolysis is applied.

Updated State Air Emissions Regulations (released in AEO2010)

EIA Publications

2010-01-01

The Regional Greenhouse Gas Initiative (RGGI) is a program that includes 10 Northeast states that have agreed to curtail and reverse growth in their carbon dioxide (CO2) emissions. The RGGI program includes all electricity generating units with a capacity of at least 25 megawatts and requires an allowance for each ton of CO2 emitted. The first year of mandatory compliance was in 2009.

2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy (Executive Summary)

DOE PAGES

Langholtz, Matthew; Stokes, Bryce; Eaton, Laurence

2016-10-01

We report that consumption of renewable energy in the United States is the highest in history, contributing to energy security, greenhouse gas reductions, and other social, economic, and environmental benefits. The largest single source of renewable energy is biomass, representing 3.9 quadrillion of 9.6 quadrillion British thermal units (Btu) in 2015. Biomass includes agricultural and forestry resources, municipal solid waste (MSW), and algae.

R&D100: CO2 Memzyme

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rempe, Susan; Brinker, Jeff; Jiang, Ying-Bing

2015-11-19

By combining a water droplet loaded with CO2 enzymes in an ultrathin nanopore on a flexible substrate, researchers at Sandia National Laboratories realized the first technology that meets and exceeds DOE targets for cost-effective CO2 capture. When compared with the nearest membrane competitor, this technology delivers a three times permeation rate, twenty times higher selectivity, and ten time lower fabrication cost. The CO2 Memzyme has the potential to remove 90% of CO2 emissions and is forecasted to save the U.S. coal industry $90 billion a year compared to conventional technology.

R&D100: CO2 Memzyme

ScienceCinema

Rempe, Susan; Brinker, Jeff; Jiang, Ying-Bing; Vanegas, Juan

2018-06-25

By combining a water droplet loaded with CO2 enzymes in an ultrathin nanopore on a flexible substrate, researchers at Sandia National Laboratories realized the first technology that meets and exceeds DOE targets for cost-effective CO2 capture. When compared with the nearest membrane competitor, this technology delivers a three times permeation rate, twenty times higher selectivity, and ten time lower fabrication cost. The CO2 Memzyme has the potential to remove 90% of CO2 emissions and is forecasted to save the U.S. coal industry $90 billion a year compared to conventional technology.

Historical evaluation of vehicle emission control in Guangzhou based on a multi-year emission inventory

NASA Astrophysics Data System (ADS)

Zhang, Shaojun; Wu, Ye; Liu, Huan; Wu, Xiaomeng; Zhou, Yu; Yao, Zhiliang; Fu, Lixin; He, Kebin; Hao, Jiming

2013-09-01

The Guangzhou government adopted many vehicle emission control policies and strategies during the five-year preparation (2005-2009) to host the 2010 Asian Games. This study established a multi-year emission inventory for vehicles in Guangzhou during 2005-2009 and estimated the uncertainty in total vehicle emissions by taking the assumed uncertainties in fleet-average emission factors and annual mileage into account. In 2009, the estimated total vehicle emissions in Guangzhou were 313 000 (242 000-387 000) tons of CO, 60 900 (54 000-70 200) tons of THC, 65 600 (56 800-74 100) tons of NOx and 2740 (2100-3400) tons of PM10. Vehicle emissions within the urban area of Guangzhou were estimated to be responsible for ˜40% of total gaseous pollutants and ˜25% of total PM10 in the entire city. Although vehicle use intensity increased rapidly in Guangzhou during 2005-2009, vehicle emissions were estimated to have been reduced by 12% for CO, 21% for THC and 20% for PM10 relative to those in 2005. NOx emissions were estimated to have remained almost constant during this period. Compared to the "without control" scenario, 19% (15%-23%) of CO, 20% (18%-23%) of THC, 9% (8%-10%) of NOx and 16% (12%-20%) of PM10 were estimated to have been mitigated from a combination of the implementation of Euro III standards for light-duty vehicles (LDVs) and heavy-duty diesel vehicles and improvement of fuel quality. This study also evaluated several enhanced vehicle emission control actions taken recently. For example, the enhanced I/M program for LDVs was estimated to reduce 11% (9%-14%) of CO, 9% (8%-10%) of THC and 2% (2%-3%) of NOx relative to total vehicle emissions in 2009. Total emission reductions by temporary traffic controls for the Asian Games were estimated equivalent to 9% (7%-11%) of CO, 9% (8%-10%) of THC, 5% (5%-6%) of NOx and 10% (8%-13%) of PM10 estimated total vehicle emissions in 2009. Those controls are essential to further vehicle emission mitigation in Guangzhou required by the new National Ambient Air Quality Standards.

Continuous multi-plot measurements of CO2, CH4, N2O and H2O in a managed boreal forest - The importance of accounting for all greenhouse gases

NASA Astrophysics Data System (ADS)

Vestin, P.; Mölder, M.; Sundqvist, E.; Båth, A.; Lehner, I.; Weslien, P.; Klemedtsson, L.; Lindroth, A.

2015-12-01

In order to assess the effects of different management practices on the exchange of greenhouse gases (GHG), it is desirable to perform repeated and parallel measurements on both experimental and control plots. Here we demonstrate how a system system combining eddy covariance and gradient techniques can be used to perform this assessment in a managed forest ecosystem.The net effects of clear-cutting and stump harvesting on GHG fluxes were studied at the ICOS site Norunda, Sweden. Micrometeorological measurements (i.e., flux-gradient measurements in 3 m tall towers) allowed for quantification of CO2, CH4 and H2O fluxes (from May 2010) as well as N2O and H2O fluxes (from June 2011) at two stump harvested plots and two control plots. There was one wetter and one drier plot of each treatment. Air was continuously sampled at two heights in the towers and gas concentrations were analyzed for CH4, CO2, H2O (LGR DLT-100, Los Gatos Research) and N2O, H2O (QCL Mini Monitor, Aerodyne Research). Friction velocities and sensible heat fluxes were measured by sonic anemometers (Gill Windmaster, Gill Instruments Ltd). Automatic chamber measurements (CO2, CH4, H2O) were carried out in the adjacent forest stand and at the clear-cut during 2010.Average CO2 emissions for the first year ranged between 14.4-20.2 ton CO2 ha-1 yr-1. The clear-cut became waterlogged after harvest and a comparison of flux-gradient data and chamber data (from the adjacent forest stand) indicated a switch from a weak CH4 sink to a significant source at all plots. The CH4 emissions ranged between 0.8-4.5 ton CO2-eq. ha-1 yr-1. N2O emissions ranged between 0.4-2.6 ton CO2-eq. ha-1 yr-1. Enhanced N2O emission on the drier stump harvested plot was the only clear treatment effect on GHG fluxes that was observed. Mean CH4 and N2O emissions for the first year of measurements amounted up to 29% and 20% of the mean annual CO2 emissions, respectively. This highlights the importance of including all GHGs when assessing the climate impacts of different forest management options. Our results show that continuous multi-plot measurements of the main GHGs are possible also at sites where GHG fluxes are low, at a reasonable cost and with reduced plot inter-comparison uncertainties.

Atmospheric carbon dioxide: a driver of photosynthetic eukaryote evolution for over a billion years?

PubMed Central

Beerling, David J.

2012-01-01

Exciting evidence from diverse fields, including physiology, evolutionary biology, palaeontology, geosciences and molecular genetics, is providing an increasingly secure basis for robustly formulating and evaluating hypotheses concerning the role of atmospheric carbon dioxide (CO2) in the evolution of photosynthetic eukaryotes. Such studies span over a billion years of evolutionary change, from the origins of eukaryotic algae through to the evolution of our present-day terrestrial floras, and have relevance for plant and ecosystem responses to future global CO2 increases. The papers in this issue reflect the breadth and depth of approaches being adopted to address this issue. They reveal new discoveries pointing to deep evidence for the role of CO2 in shaping evolutionary changes in plants and ecosystems, and establish an exciting cross-disciplinary research agenda for uncovering new insights into feedbacks between biology and the Earth system. PMID:22232760

Atmospheric carbon dioxide: a driver of photosynthetic eukaryote evolution for over a billion years?

PubMed

Beerling, David J

2012-02-19

Exciting evidence from diverse fields, including physiology, evolutionary biology, palaeontology, geosciences and molecular genetics, is providing an increasingly secure basis for robustly formulating and evaluating hypotheses concerning the role of atmospheric carbon dioxide (CO(2)) in the evolution of photosynthetic eukaryotes. Such studies span over a billion years of evolutionary change, from the origins of eukaryotic algae through to the evolution of our present-day terrestrial floras, and have relevance for plant and ecosystem responses to future global CO(2) increases. The papers in this issue reflect the breadth and depth of approaches being adopted to address this issue. They reveal new discoveries pointing to deep evidence for the role of CO(2) in shaping evolutionary changes in plants and ecosystems, and establish an exciting cross-disciplinary research agenda for uncovering new insights into feedbacks between biology and the Earth system.

Net Carbon Emissions from Deforestation in Bolivia during 1990-2000 and 2000-2010: Results from a Carbon Bookkeeping Model.

PubMed

Andersen, Lykke E; Doyle, Anna Sophia; del Granado, Susana; Ledezma, Juan Carlos; Medinaceli, Agnes; Valdivia, Montserrat; Weinhold, Diana

2016-01-01

Accurate estimates of global carbon emissions are critical for understanding global warming. This paper estimates net carbon emissions from land use change in Bolivia during the periods 1990-2000 and 2000-2010 using a model that takes into account deforestation, forest degradation, forest regrowth, gradual carbon decomposition and accumulation, as well as heterogeneity in both above ground and below ground carbon contents at the 10 by 10 km grid level. The approach permits detailed maps of net emissions by region and type of land cover. We estimate that net CO2 emissions from land use change in Bolivia increased from about 65 million tons per year during 1990-2000 to about 93 million tons per year during 2000-2010, while CO2 emissions per capita and per unit of GDP have remained fairly stable over the sample period. If we allow for estimated biomass increases in mature forests, net CO2 emissions drop to close to zero. Finally, we find these results are robust to alternative methods of calculating emissions.

Net Carbon Emissions from Deforestation in Bolivia during 1990-2000 and 2000-2010: Results from a Carbon Bookkeeping Model

PubMed Central

Andersen, Lykke E.; Doyle, Anna Sophia; del Granado, Susana; Ledezma, Juan Carlos; Medinaceli, Agnes; Valdivia, Montserrat; Weinhold, Diana

2016-01-01

Accurate estimates of global carbon emissions are critical for understanding global warming. This paper estimates net carbon emissions from land use change in Bolivia during the periods 1990–2000 and 2000–2010 using a model that takes into account deforestation, forest degradation, forest regrowth, gradual carbon decomposition and accumulation, as well as heterogeneity in both above ground and below ground carbon contents at the 10 by 10 km grid level. The approach permits detailed maps of net emissions by region and type of land cover. We estimate that net CO2 emissions from land use change in Bolivia increased from about 65 million tons per year during 1990–2000 to about 93 million tons per year during 2000–2010, while CO2 emissions per capita and per unit of GDP have remained fairly stable over the sample period. If we allow for estimated biomass increases in mature forests, net CO2 emissions drop to close to zero. Finally, we find these results are robust to alternative methods of calculating emissions. PMID:26990865

Carbon footprint hotspots of prefabricated sandwich panels for hostel construction in Perlis

NASA Astrophysics Data System (ADS)

Razali, Norashikin; Ayob, Afizah; Chandra, Muhammad Erwan Shah; Zaki, Mohd Faiz Mohammad; Ahmad, Abdul Ghapar

2017-10-01

Sustainable design and construction have gained increasing research interest, and reduction of carbon from building construction has become the main focus of environmental strategies in Malaysia. This study uses life cycle assessment and life cycle inventory analysis frameworks to estimate the amount of carbon footprint expressed in carbon dioxide equivalent tons (CO2e) produced by manufacturing prefabricated Industrialized Building System sandwich panels and its installation for a five-story hostel in Perlis, Malaysia. Results show that the carbon footprint hotspots were centered on boiler machine operation and cement with 4.52 and 369.04 tons CO2e, respectively. This finding is due to the extensive energy used for steam heating and high engine rating for the boiler. However, for cement, the carbon footprint hotspots are caused by the large quantity of cement applied in shotcrete mixture and its high extraction and production CO2 emission values. The overall onsite materials generated 96.36% of the total carbon footprint. These carbon footprint hotspot results constitute a necessary base for the Malaysian government in accomplishing an adequate dimensioning of carbon emissions in the building sector.

Sharing global CO2 emission reductions among one billion high emitters

PubMed Central

Chakravarty, Shoibal; Chikkatur, Ananth; de Coninck, Heleen; Pacala, Stephen; Socolow, Robert; Tavoni, Massimo

2009-01-01

We present a framework for allocating a global carbon reduction target among nations, in which the concept of “common but differentiated responsibilities” refers to the emissions of individuals instead of nations. We use the income distribution of a country to estimate how its fossil fuel CO2 emissions are distributed among its citizens, from which we build up a global CO2 distribution. We then propose a simple rule to derive a universal cap on global individual emissions and find corresponding limits on national aggregate emissions from this cap. All of the world's high CO2-emitting individuals are treated the same, regardless of where they live. Any future global emission goal (target and time frame) can be converted into national reduction targets, which are determined by “Business as Usual” projections of national carbon emissions and in-country income distributions. For example, reducing projected global emissions in 2030 by 13 GtCO2 would require the engagement of 1.13 billion high emitters, roughly equally distributed in 4 regions: the U.S., the OECD minus the U.S., China, and the non-OECD minus China. We also modify our methodology to place a floor on emissions of the world's lowest CO2 emitters and demonstrate that climate mitigation and alleviation of extreme poverty are largely decoupled. PMID:19581586

Highly efficient hydrogenation of carbon dioxide to formate catalyzed by iridium(iii) complexes of imine-diphosphine ligands.

PubMed

Liu, Chong; Xie, Jian-Hua; Tian, Gui-Long; Li, Wei; Zhou, Qi-Lin

2015-05-01

A new iridium catalyst containing an imine-diphosphine ligand has been developed, which showed high efficiency for the hydrogenation of CO 2 to formate (yield up to 99%, TON up to 450 000). A possible catalytic mechanism is proposed, in which the imine group of the catalyst plays a key role in the cleavage of H 2 and the activation of CO 2 .

A Highly Selective and Robust Co(II)-Based Homogeneous Catalyst for Reduction of CO2 to CO in CH3CN/H2O Solution Driven by Visible Light.

PubMed

Ouyang, Ting; Hou, Cheng; Wang, Jia-Wei; Liu, Wen-Ju; Zhong, Di-Chang; Ke, Zhuo-Feng; Lu, Tong-Bu

2017-07-03

Visible-light driven reduction of CO 2 into chemical fuels has attracted enormous interest in the production of sustainable energy and reversal of the global warming trend. The main challenge in this field is the development of efficient, selective, and economic photocatalysts. Herein, we report a Co(II)-based homogeneous catalyst, [Co(NTB)CH 3 CN](ClO 4 ) 2 (1, NTB = tris(benzimidazolyl-2-methyl)amine), which shows high selectivity and stability for the catalytic reduction of CO 2 to CO in a water-containing system driven by visible light, with turnover number (TON) and turnover frequency (TOF) values of 1179 and 0.032 s -1 , respectively, and selectivity to CO of 97%. The high catalytic activity of 1 for photochemical CO 2 -to-CO conversion is supported by the results of electrochemical investigations and DFT calculations.

Opportunities for Saving Energy and Improving Air Quality in Urban Heat Islands

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akbari, Hashem

2007-07-01

World energy use is the main contributor to atmospheric CO2. In 2002, about 7.0 giga metric tons of carbon (GtC) were emitted internationally by combustion of gas, liquid, and solid fuels (CDIAC, 2006), 2 to 5 times the amount contributed by deforestation (Brown et al., 1988). The share of atmospheric carbon emissions for the United States from fossil fuel combustion was 1.6 GtC. Increasing use of fossil fuel and deforestation together have raised atmospheric CO{sub 2} concentration some 25% over the last 150 years. According to global climate models and preliminary measurements, these changes in the composition of the atmospheremore » have already begun raising the Earth's average temperature. If current energy trends continue, these changes could drastically alter the Earth's temperature, with unknown but potentially catastrophic physical and political consequences. During the last three decades, increased energy awareness has led to conservation efforts and leveling of energy consumption in the industrialized countries. An important byproduct of this reduced energy use is the lowering of CO{sub 2} emissions. Of all electricity generated in the United States, about one-sixth is used to air-condition buildings. The air-conditioning use is about 400 tera-watt-hours (TWh), equivalent to about 80 million metric tons of carbon (MtC) emissions, and translating to about $40 billion (B) per year. Of this $40 B/year, about half is used in cities that have pronounced 'heat islands'. The contribution of the urban heat island to the air-conditioning demand has increased over the last 40 years and it is currently at about 10%. Metropolitan areas in the United States (e.g., Los Angeles, Phoenix, Houston, Atlanta, and New York City) have typically pronounced heat islands that warrant special attention by anyone concerned with broad-scale energy efficiency (HIG, 2006). The ambient air is primarily heated through three processes: direct absorption of solar radiation, convection of heat from hot surfaces, and man-made heat (exhaust from cars, buildings, etc.). Air is fairly transparent to light--the direct absorption of solar radiation in atmospheric air only raises the air temperature by a small amount. Typically about 90% of solar radiation reaches the Earth's surface and then is either absorbed or reflected. The absorbed radiation on the surface increases the surface temperature. And in turn the hot surfaces heat the air. This convective heating is responsible for the majority of the diurnal temperature range. The contribution of man-made heat (e.g., air conditioning, cars) is very small, compared to the heating of air by hot surfaces, except for the downtown high-rise areas.« less

Feasibility of atmospheric methane removal using methanotrophic biotrickling filters.

PubMed

Yoon, Sukhwan; Carey, Jeffrey N; Semrau, Jeremy D

2009-07-01

Methane is a potent greenhouse gas with a global warming potential ~23 times that of carbon dioxide. Here, we describe the modeling of a biotrickling filtration system composed of methane-consuming bacteria, i.e., methanotrophs, to assess the utility of these systems in removing methane from the atmosphere. Model results indicate that assuming the global average atmospheric concentration of methane, 1.7 ppmv, methane removal is ineffective using these methanotrophic biofilters as the methane concentration is too low to enable cell survival. If the concentration is increased to 500-6,000 ppmv, however, similar to that found above landfills and in concentrated animal feeding operations (factory farms), 4.98-35.7 tons of methane can be removed per biofilter per year assuming biotrickling filters of typical size (3.66 m in diameter and 11.5 m in height). Using reported ranges of capital, operational, and maintenance costs, the cost of the equivalent ton of CO(2) removal using these systems is $90-$910 ($2,070-$20,900 per ton of methane), depending on the influent concentration of methane and if heating is required. The use of methanotrophic biofilters for controlling methane emissions is technically feasible and, provided that either the costs of biofilter construction and operation are reduced or the value of CO(2) credits is increased, can also be economically attractive.

Carbon dioxide hydrogenation catalysed by well-defined Mn(i) PNP pincer hydride complexes† †Electronic supplementary information (ESI) available: Experimental procedures, NMR and IR spectra, atomic coordinates for DFT optimized structures and computational details, and crystallographic data for 2. CCDC 1520528. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00209b Click here for additional data file. Click here for additional data file.

PubMed Central

Bertini, Federica; Glatz, Mathias; Gorgas, Nikolaus; Stöger, Berthold; Peruzzini, Maurizio; Veiros, Luis F.

2017-01-01

The catalytic reduction of carbon dioxide is of great interest for its potential as a hydrogen storage method and to use carbon dioxide as C-1 feedstock. In an effort to replace expensive noble metal-based catalysts with efficient and cheap earth-abundant counterparts, we report the first example of Mn(i)-catalysed hydrogenation of CO2 to HCOOH. The hydride Mn(i) catalyst [Mn(PNPNH-iPr)(H)(CO)2] showed higher stability and activity than its Fe(ii) analogue. TONs up to 10 000 and quantitative yields were obtained after 24 h using DBU as the base at 80 °C and 80 bar total pressure. At catalyst loadings as low as 0.002 mol%, TONs greater than 30 000 could be achieved in the presence of LiOTf as the co-catalyst, which are among the highest activities reported for base-metal catalysed CO2 hydrogenations to date. PMID:28970889

Methanol from Wood Waste: A Technical and Economic Study.

DTIC Science & Technology

1977-06-01

percent of the gas is converted to methanol , the balance passing as inerts to the boiler. The reaction is as follows: catalyst 2H + CO ’ CH3OH 2 *-3...the boiler. Catalyst life is expected to be 6 years for methanol synthesis and 2 to 3 years for the shift reactor . PLANT SIZE In a chemical processing...percent of methyl alcohol ( methanol ) in gasoline for automotive use. / At a current consumption rate of 110 billion gallons per year (gpy), 11 billion

Accelerated carbonation using municipal solid waste incinerator bottom ash and cold-rolling wastewater: Performance evaluation and reaction kinetics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chang, E-E; Pan, Shu-Yuan; Yang, Liuhanzi

2015-09-15

Highlights: • Carbonation was performed using CO{sub 2}, wastewater and bottom ash in a slurry reactor. • A maximum capture capacity of 102 g CO{sub 2} per kg BA was achieved at mild conditions. • A maximum carbonation conversion of MSWI-BA was predicted to be 95% by RSM. • The CO{sub 2} emission from Bali incinerator could be expected to reduce by 6480 ton/y. • The process energy consumption per ton CO{sub 2} captured was estimated to be 180 kW h. - Abstract: Accelerated carbonation of alkaline wastes including municipal solid waste incinerator bottom ash (MSWI-BA) and the cold-rolling wastewatermore » (CRW) was investigated for carbon dioxide (CO{sub 2}) fixation under different operating conditions, i.e., reaction time, CO{sub 2} concentration, liquid-to-solid ratio, particle size, and CO{sub 2} flow rate. The MSWI-BA before and after carbonation process were analyzed by the thermogravimetry and differential scanning calorimetry, X-ray diffraction, and scanning electron microscopy equipped with energy dispersive X-ray spectroscopy. The MSWI-BA exhibits a high carbonation conversion of 90.7%, corresponding to a CO{sub 2} fixation capacity of 102 g per kg of ash. Meanwhile, the carbonation kinetics was evaluated by the shrinking core model. In addition, the effect of different operating parameters on carbonation conversion of MSWI-BA was statistically evaluated by response surface methodology (RSM) using experimental data to predict the maximum carbonation conversion. Furthermore, the amount of CO{sub 2} reduction and energy consumption for operating the proposed process in refuse incinerator were estimated. Capsule abstract: CO{sub 2} fixation process by alkaline wastes including bottom ash and cold-rolling wastewater was developed, which should be a viable method due to high conversion.« less

New technologies reduce greenhouse gas emissions from nitrogenous fertilizer in China

PubMed Central

Dou, Zheng-xia; He, Pan; Ju, Xiao-Tang; Powlson, David; Chadwick, Dave; Norse, David; Lu, Yue-Lai; Zhang, Ying; Wu, Liang; Chen, Xin-Ping; Cassman, Kenneth G.; Zhang, Fu-Suo

2013-01-01

Synthetic nitrogen (N) fertilizer has played a key role in enhancing food production and keeping half of the world’s population adequately fed. However, decades of N fertilizer overuse in many parts of the world have contributed to soil, water, and air pollution; reducing excessive N losses and emissions is a central environmental challenge in the 21st century. China’s participation is essential to global efforts in reducing N-related greenhouse gas (GHG) emissions because China is the largest producer and consumer of fertilizer N. To evaluate the impact of China’s use of N fertilizer, we quantify the carbon footprint of China’s N fertilizer production and consumption chain using life cycle analysis. For every ton of N fertilizer manufactured and used, 13.5 tons of CO2-equivalent (eq) (t CO2-eq) is emitted, compared with 9.7 t CO2-eq in Europe. Emissions in China tripled from 1980 [131 terrogram (Tg) of CO2-eq (Tg CO2-eq)] to 2010 (452 Tg CO2-eq). N fertilizer-related emissions constitute about 7% of GHG emissions from the entire Chinese economy and exceed soil carbon gain resulting from N fertilizer use by several-fold. We identified potential emission reductions by comparing prevailing technologies and management practices in China with more advanced options worldwide. Mitigation opportunities include improving methane recovery during coal mining, enhancing energy efficiency in fertilizer manufacture, and minimizing N overuse in field-level crop production. We find that use of advanced technologies could cut N fertilizer-related emissions by 20–63%, amounting to 102–357 Tg CO2-eq annually. Such reduction would decrease China’s total GHG emissions by 2–6%, which is significant on a global scale. PMID:23671096

New technologies reduce greenhouse gas emissions from nitrogenous fertilizer in China.

PubMed

Zhang, Wei-Feng; Dou, Zheng-Xia; He, Pan; Ju, Xiao-Tang; Powlson, David; Chadwick, Dave; Norse, David; Lu, Yue-Lai; Zhang, Ying; Wu, Liang; Chen, Xin-Ping; Cassman, Kenneth G; Zhang, Fu-Suo

2013-05-21

Synthetic nitrogen (N) fertilizer has played a key role in enhancing food production and keeping half of the world's population adequately fed. However, decades of N fertilizer overuse in many parts of the world have contributed to soil, water, and air pollution; reducing excessive N losses and emissions is a central environmental challenge in the 21st century. China's participation is essential to global efforts in reducing N-related greenhouse gas (GHG) emissions because China is the largest producer and consumer of fertilizer N. To evaluate the impact of China's use of N fertilizer, we quantify the carbon footprint of China's N fertilizer production and consumption chain using life cycle analysis. For every ton of N fertilizer manufactured and used, 13.5 tons of CO2-equivalent (eq) (t CO2-eq) is emitted, compared with 9.7 t CO2-eq in Europe. Emissions in China tripled from 1980 [131 terrogram (Tg) of CO2-eq (Tg CO2-eq)] to 2010 (452 Tg CO2-eq). N fertilizer-related emissions constitute about 7% of GHG emissions from the entire Chinese economy and exceed soil carbon gain resulting from N fertilizer use by several-fold. We identified potential emission reductions by comparing prevailing technologies and management practices in China with more advanced options worldwide. Mitigation opportunities include improving methane recovery during coal mining, enhancing energy efficiency in fertilizer manufacture, and minimizing N overuse in field-level crop production. We find that use of advanced technologies could cut N fertilizer-related emissions by 20-63%, amounting to 102-357 Tg CO2-eq annually. Such reduction would decrease China's total GHG emissions by 2-6%, which is significant on a global scale.

Forest Resources

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2016-06-01

Forest biomass is an abundant biomass feedstock that complements the conventional forest use of wood for paper and wood materials. It may be utilized for bioenergy production, such as heat and electricity, as well as for biofuels and a variety of bioproducts, such as industrial chemicals, textiles, and other renewable materials. The resources within the 2016 Billion-Ton Report include primary forest resources, which are taken directly from timberland-only forests, removed from the land, and taken to the roadside.

A Go-to-Market Strategy: Promoting Private Sector Solutions to the Threat of Proliferation

DTIC Science & Technology

2013-04-01

indicators reveal that these problems, often subsumed under the seemingly innocuous heading of “transnational threats,” are a growing cancer on the...trade is worth an estimated $322 billion annually with 52,356 metric tons of opium, cannabis , cocaine, and amphetamine-type stimulant (ATS...of medical isotopes to the sites that secure the material. 30 Regulators are also now starting to consider another critical component in the

Plasma for electrification of chemical industry: a case study on CO2 reduction

NASA Astrophysics Data System (ADS)

van Rooij, G. J.; Akse, H. N.; Bongers, W. A.; van de Sanden, M. C. M.

2018-01-01

Significant growth of the share of (intermittent) renewable power in the chemical industry is imperative to meet increasingly stricter limits on CO2 exhaust that are being implemented within Europe. This paper aims to evaluate the potential of a plasma process that converts input CO2 into a pure stream of CO to aid in renewable energy penetration in this sector. A realistic process design is constructed to serve as a basis for an economical analysis. The manufacturing cost price of CO is estimated at 1.2 kUS ton-1 CO. A sensitivity analysis shows that separation is the dominant cost factor, so that improving conversion is currently more effective to lower the price than e.g. energy efficiency.

Feasibility of lunar Helium-3 mining

NASA Astrophysics Data System (ADS)

Kleinschneider, Andreas; Van Overstraeten, Dmitry; Van der Reijnst, Roy; Van Hoorn, Niels; Lamers, Marvin; Hubert, Laurent; Dijk, Bert; Blangé, Joey; Hogeveen, Joel; De Boer, Lennaert; Noomen, Ron

With fossil fuels running out and global energy demand increasing, the need for alternative energy sources is apparent. Nuclear fusion using Helium-3 may be a solution. Helium-3 is a rare isotope on Earth, but it is abundant on the Moon. Throughout the space community lunar Helium-3 is often cited as a major reason to return to the Moon. Despite the potential of lunar Helium-3 mining, little research has been conducted on a full end-to-end mission. This abstract presents the results of a feasibility study conducted by students from Delft University of Technology. The goal of the study was to assess whether a continuous end-to-end mission to mine Helium-3 on the Moon and return it to Earth is a viable option for the future energy market. The set requirements for the representative end-to-end mission were to provide 10% of the global energy demand in the year 2040. The mission elements have been selected with multiple trade-offs among both conservative and novel concepts. A mission architecture with multiple decoupled elements for each transportation segment (LEO, transfer, lunar surface) was found to be the best option. It was found that the most critical element is the lunar mining operation itself. To supply 10% of the global energy demand in 2040, 200 tons of Helium-3 would be required per year. The resulting regolith mining rate would be 630 tons per second, based on an optimistic concentration of 20 ppb Helium-3 in lunar regolith. Between 1,700 to 2,000 Helium-3 mining vehicles would be required, if using University of Wisconsin’s Mark III miner. The required heating power, if mining both day and night, would add up to 39 GW. The resulting power system mass for the lunar operations would be in the order of 60,000 to 200,000 tons. A fleet of three lunar ascent/descent vehicles and 22 continuous-thrust vehicles for orbit transfer would be required. The costs of the mission elements have been spread out over expected lifetimes. The resulting profits from Helium-3 fusion were calculated using a predicted minimum energy price in 2040 of 30.4 Euro/MWh. Annual costs are between 427.7 to 1,347.9 billion Euro, with annual expected profit ranging from -724.0 to 260.0 billion Euro. Due to the large scale of the mission, it has also been evaluated for providing 0.1% and 1% of the global energy demand in 2040. For 1%, the annual costs are 45.6 to 140.3 billion Euro and the expected annual profits are -78.0 to 23.1 billion Euro. For 0.1%, the annual costs are 7.7 to 20.5 billion Euro. The annual expected profits are -14.3 to -0.8 billion Euro. Feasibility has been addressed in three aspects. Technically, the mission is extremely challenging and complex. However, most required technologies exist or could be developed within a reasonable time span. From a political and legal perspective, the current international treaties hardly provide any framework for a lunar mining operation. Financially, the mission only produces a net profit in the best case, and only for medium- to large-scale operations, which require a very large initial investment. To make lunar Helium-3 usage possible, further research should concentrate on the mining operation and costs of fusion plants, as their impact by far outranks all other mission elements. Different transportation concepts may be investigated nevertheless. Many - not only technical - challenges concerning Helium-3 mining are still to be addressed. Although only a starting point for further investigations, this study shows that, despite popular claims, lunar Helium-3 is unsuitable to provide a significant percentage of the global energy demand in 2040.

Final Environmental Assessment to Implement the Defense Base Closure and Realignment Commission Recommendations for Shaw Air Force Base, South Carolina

DTIC Science & Technology

2007-07-01

corresponding years. Year 2005 through 2009: VOCE = .016 * Trips NOxE = .015 * Trips PM10E = .0022 * Trips COE = .262 * Trips Year 2010 and beyond: VOCE ... VOCE * DPYII/2000 Nox (tons/yr) = NOxE * DPYII/2000 PM10(tons/yr) = PM10E * DPYII/2000 CO (tons/yr) = COE * DPYII/2000 Where: Commercial

Climate change mitigation by recovery of energy from the water cycle: a new challenge for water management.

PubMed

van der Hoek, J P

2012-01-01

Waternet is responsible for drinking water treatment and distribution, wastewater collection and treatment, and surface water management and control (quality and quantity) in and around Amsterdam. Waternet has the ambition to operate climate neutral in 2020. To realise this ambition, measures are required to compensate for the emission of 53,000 ton CO(2)-eq/year. Energy recovery from the water cycle looks very promising. First, calculations reveal that energy recovery from the water cycle in and around Amsterdam may contribute to a total reduction in greenhouse gas emissions up to 148,000 ton CO(2)-eq/year. The challenge for the coming years is to choose combinations of all the possibilities to fulfil the energy demand as much as possible. Only then the use of fossil fuel can be minimized and inevitable greenhouse gas emissions can be compensated, supporting the target to operate climate neutral in 2020.

Increase in observed net carbon dioxide uptake by land and oceans during the past 50 years.

PubMed

Ballantyne, A P; Alden, C B; Miller, J B; Tans, P P; White, J W C

2012-08-02

One of the greatest sources of uncertainty for future climate predictions is the response of the global carbon cycle to climate change. Although approximately one-half of total CO(2) emissions is at present taken up by combined land and ocean carbon reservoirs, models predict a decline in future carbon uptake by these reservoirs, resulting in a positive carbon-climate feedback. Several recent studies suggest that rates of carbon uptake by the land and ocean have remained constant or declined in recent decades. Other work, however, has called into question the reported decline. Here we use global-scale atmospheric CO(2) measurements, CO(2) emission inventories and their full range of uncertainties to calculate changes in global CO(2) sources and sinks during the past 50 years. Our mass balance analysis shows that net global carbon uptake has increased significantly by about 0.05 billion tonnes of carbon per year and that global carbon uptake doubled, from 2.4 ± 0.8 to 5.0 ± 0.9 billion tonnes per year, between 1960 and 2010. Therefore, it is very unlikely that both land and ocean carbon sinks have decreased on a global scale. Since 1959, approximately 350 billion tonnes of carbon have been emitted by humans to the atmosphere, of which about 55 per cent has moved into the land and oceans. Thus, identifying the mechanisms and locations responsible for increasing global carbon uptake remains a critical challenge in constraining the modern global carbon budget and predicting future carbon-climate interactions.

Study on new biomass energy systems

NASA Astrophysics Data System (ADS)

1992-03-01

A biomass energy total system is proposed, and its feasibility is studied. It is the system in which liquid fuel is produced from eucalyptuses planted in the desert area in Australia for production of biomass resource. Eucalyptus tree planting aims at a growth amount of 40 cu m/ha. per year and a practical application area of 45,000ha. CO2 fixation in the biomass plantation becomes 540,000 tons at a 12 ton/ha. rate. Assuming that 0.55 ton of liquid fuel is produced from 1 ton of biomass, a petrochemical plant having a production of 2.5 million bbl/year per unit (equivalent to the fuel used in the 100,000kW class power plant) is needed. Moreover, survey is made on practicality of diesel substitution fuel by esterification of palm oil, and a marked effect of reduction in soot/smoke and particulates in exhaust gas is confirmed. The biomass conversion process technology and the technology for afforestation at the arid land and irrigation are important as future subjects, and the technology development using a bench plant and a pilot plant is needed.

Synthesis of high-purity precipitated calcium carbonate during the process of recovery of elemental sulphur from gypsum waste.

PubMed

de Beer, M; Doucet, F J; Maree, J P; Liebenberg, L

2015-12-01

We recently showed that the production of elemental sulphur and calcium carbonate (CaCO3) from gypsum waste by thermally reducing the waste into calcium sulphide (CaS) followed by its direct aqueous carbonation yielded low-grade carbonate products (i.e. <90 mass% as CaCO3). In this study, we used the insight gained from our previous work and developed an indirect aqueous CaS carbonation process for the production of high-grade CaCO3 (i.e. >99 mass% as CaCO3) or precipitated calcium carbonate (PCC). The process used an acid gas (H2S) to improve the aqueous dissolution of CaS, which is otherwise poorly soluble. The carbonate product was primarily calcite (99.5%) with traces of quartz (0.5%). Calcite was the only CaCO3 polymorph obtained; no vaterite or aragonite was detected. The product was made up of micron-size particles, which were further characterised by XRD, TGA, SEM, BET and true density. Results showed that about 0.37 ton of high-grade PCC can be produced from 1.0 ton of gypsum waste, and generates about 0.19 ton of residue, a reduction of 80% from original waste gypsum mass to mass of residue that needs to be discarded off. The use of gypsum waste as primary material in replacement of mined limestone for the production of PPC could alleviate waste disposal problems, along with converting significant volumes of waste materials into marketable commodities. Copyright © 2015 Elsevier Ltd. All rights reserved.

Bituminous coal production in the Appalachian Basin; past, present, and future

USGS Publications Warehouse

Milici, R.C.

1999-01-01

This report on Appalachian basin coal production consists of four maps and associated graphs and tables, with links to the basic data that were used to construct the maps. Plate 1 shows the time (year) of maximum coal production, by county. For illustration purposes, the years of maximum production are grouped into decadal units. Plate 2 shows the amount of coal produced (tons) during the year of maximum coal production for each county. Plate 3 illustrates the cumulative coal production (tons) for each county since about the beginning of the 20th century. Plate 4 shows 1996 annual production by county. During the current (third) cycle of coal production in the Appalachian basin, only seven major coal-producing counties (those with more than 500 million tons cumulative production), including Greene County, Pa.; Boone, Kanawha, Logan, Mingo, and Monongalia Counties, W.Va.; and Pike County, Ky., exhibit a general increase in coal production. Other major coal-producing counties have either declined to a small percentage of their maximum production or are annually maintaining a moderate level of production. In general, the areas with current high coal production have large blocks of coal that are suitable for mining underground with highly efficient longwall methods, or are occupied by very large scale, relatively low cost surface mining operations. The estimated cumulative production for combined bituminous and anthracite coal is about 100 billion tons or less for the Appalachian basin. In general, it is anticipated that the remaining resources will be progressively of lower quality, will cost more to mine, and will become economical only as new technologies for extraction, beneficiation, and consumption are developed, and then only if prices for coal increase.

RECONNAISSANCE ASSESSMENT OF CO2 SEQUESTRATION POTENTIAL IN THE TRIASSIC AGE RIFT BASIN TREND OF SOUTH CAROLINA, GEORGIA, AND NORTHERN FLORIDA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blount, G.; Millings, M.

2011-08-01

A reconnaissance assessment of the carbon dioxide (CO{sub 2}) sequestration potential within the Triassic age rift trend sediments of South Carolina, Georgia and the northern Florida Rift trend was performed for the Office of Fossil Energy, National Energy Technology Laboratory (NETL). This rift trend also extends into eastern Alabama, and has been termed the South Georgia Rift by previous authors, but is termed the South Carolina, Georgia, northern Florida, and eastern Alabama Rift (SGFAR) trend in this report to better describe the extent of the trend. The objectives of the study were to: (1) integrate all pertinent geologic information (literaturemore » reviews, drilling logs, seismic data, etc.) to create an understanding of the structural aspects of the basin trend (basin trend location and configuration, and the thickness of the sedimentary rock fill), (2) estimate the rough CO{sub 2} storage capacity (using conservative inputs), and (3) assess the general viability of the basins as sites of large-scale CO{sub 2} sequestration (determine if additional studies are appropriate). The CO{sub 2} estimates for the trend include South Carolina, Georgia, and northern Florida only. The study determined that the basins within the SGFAR trend have sufficient sedimentary fill to have a large potential storage capacity for CO{sub 2}. The deeper basins appear to have sedimentary fill of over 15,000 feet. Much of this fill is likely to be alluvial and fluvial sedimentary rock with higher porosity and permeability. This report estimates an order of magnitude potential capacity of approximately 137 billion metric tons for supercritical CO{sub 2}. The pore space within the basins represent hundreds of years of potential storage for supercritical CO{sub 2} and CO{sub 2} stored in aqueous form. There are many sources of CO{sub 2} within the region that could use the trend for geologic storage. Thirty one coal fired power plants are located within 100 miles of the deepest portions of these basins. There are also several cement and ammonia plants near the basins. Sixteen coal fired power plants are present on or adjacent to the basins which could support a low pipeline transportation cost. The current geological information is not sufficient to quantify specific storage reservoirs, seals, or traps. There is insufficient hydrogeologic information to quantify the saline nature of the water present within all of the basins. Water data in the Dunbarton Basin of the Savannah River Site indicates dissolved solids concentrations of greater than 10,000 parts per million (not potential drinking water). Additional reservoir characterization is needed to take advantage of the SGFAR trend for anthropogenic CO{sub 2} storage. The authors of this report believe it would be appropriate to study the reservoir potential in the deeper basins that are in close proximity to the current larger coal fired power plants (Albany-Arabi, Camilla-Ocilla, Alamo-Ehrhardt, and Jedburg basin).« less

Palm oil mill effluent treatment and utilization to ensure the sustainability of palm oil industries.

PubMed

Hasanudin, U; Sugiharto, R; Haryanto, A; Setiadi, T; Fujie, K

2015-01-01

The purpose of this study was to evaluate the current condition of palm oil mill effluent (POME) treatment and utilization and to propose alternative scenarios to improve the sustainability of palm oil industries. The research was conducted through field survey at some palm oil mills in Indonesia, in which different waste management systems were used. Laboratory experiment was also carried out using a 5 m(3) pilot-scale wet anaerobic digester. Currently, POME is treated through anaerobic digestion without or with methane capture followed by utilization of treated POME as liquid fertilizer or further treatment (aerobic process) to fulfill the wastewater quality standard. A methane capturing system was estimated to successfully produce renewable energy of about 25.4-40.7 kWh/ton of fresh fruit bunches (FFBs) and reduce greenhouse gas (GHG) emissions by about 109.41-175.35 kgCO2e/tonFFB (CO2e: carbon dioxide equivalent). Utilization of treated POME as liquid fertilizer increased FFB production by about 13%. A palm oil mill with 45 ton FFB/hour capacity has potential to generate about 0.95-1.52 MW of electricity. Coupling the POME-based biogas digester and anaerobic co-composting of empty fruit bunches (EFBs) is capable of adding another 0.93 MW. The utilization of POME and EFB not only increases the added value of POME and EFB by producing renewable energy, compost, and liquid fertilizer, but also lowers environmental burden.

Lean and Green Hand Surgery.

PubMed

Van Demark, Robert E; Smith, Vanessa J S; Fiegen, Anthony

2018-02-01

Health care in the United States is both expensive and wasteful. The cost of health care in the United States continues to increase every year. Health care spending for 2016 is estimated at $3.35 trillion. Per capita spending ($10,345 per person) is more than twice the average of other developed countries. The United States also leads the world in solid waste production (624,700 metric tons of waste in 2011). The health care industry is second only to the food industry in annual waste production. Each year, health care facilities in the United States produce 4 billion pounds of waste (660 tons per day), with as much as 70%, or around 2.8 billion pounds, produced directly by operating rooms. Waste disposal also accounts for up to 20% of a hospital's annual environmental services budget. Since 1992, waste production by hospitals has increased annually by a rate of at least 15%, due in part to the increased usage of disposables. Reduction in operating room waste would decrease both health care costs and potential environmental hazards. In 2015, the American Association for Hand Surgery along with the American Society for Surgery of the Hand, American Society for Peripheral Nerve Surgery, and the American Society of Reconstructive Microsurgery began the "Lean and Green" surgery project to reduce the amount of waste generated by hand surgery. We recently began our own "Lean and Green" project in our institution. Using "minor field sterility" surgical principles and Wide Awake Local Anesthesia No Tourniquet (WALANT), both surgical costs and surgical waste were decreased while maintaining patient safety and satisfaction. As the current reimbursement model changes from quantity to quality, "Lean and Green" surgery will play a role in the future health care system. Copyright © 2018 American Society for Surgery of the Hand. Published by Elsevier Inc. All rights reserved.

A perspective on cost-effectiveness of greenhouse gas reduction solutions in water distribution systems

NASA Astrophysics Data System (ADS)

Hendrickson, Thomas P.; Horvath, Arpad

2014-01-01

Water distribution systems (WDSs) face great challenges as aging infrastructures require significant investments in rehabilitation, replacement, and expansion. Reducing environmental impacts as WDSs develop is essential for utility managers and policy makers. This study quantifies the existing greenhouse gas (GHG) footprint of common WDS elements using life-cycle assessment (LCA) while identifying the greatest opportunities for emission reduction. This study addresses oversights of the related literature, which fails to capture several WDS elements and to provide detailed life-cycle inventories. The life-cycle inventory results for a US case study utility reveal that 81% of GHGs are from pumping energy, where a large portion of these emissions are a result of distribution leaks, which account for 270 billion l of water losses daily in the United States. Pipe replacement scheduling is analyzed from an environmental perspective where, through incorporating leak impacts, a tool reveals that optimal replacement is no more than 20 years, which is in contrast to the US average of 200 years. Carbon abatement costs (CACs) are calculated for different leak reduction scenarios for the case utility that range from -130 to 35 t-1 CO2(eq). Including life-cycle modeling in evaluating pipe materials identified polyvinyl chloride (PVC) and cement-lined ductile iron (DICL) as the Pareto efficient options, however; utilizing PVC presents human health risks. The model developed for the case utility is applied to California and Texas to determine the CACs of reducing leaks to 5% of distributed water. For California, annual GHG savings from reducing leaks alone (3.4 million tons of CO2(eq)) are found to exceed California Air Resources Board’s estimate for energy efficiency improvements in the state’s water infrastructure.

The CO2 Flux and the Chemistry of the Crater lake in 2013-2015 Evidence for the Enhanced Activity of El Chichon volcano, Mexico.

NASA Astrophysics Data System (ADS)

Taran, Y.; Jácome Paz, M. P.; Inguaggiato, S.; Collard, N.

2015-12-01

During 2013-2015, four CO2 flux surveys were performed in the El Chichon crater both, from the lake surface and from the soil of the crater. The chemistry of the lake water, as well as its physical parameters (surface area, depth, temperature) were also determined. The CO2 flux in 2014-2015 compared to the 2007-2008 data (Mazot et al., 2011, BV, 73: 423-441) increased almost one order of magnitude (from ~ 140 ton d-1 in 2008 to ~ 840 ton d-1 in 2014). During the last two years the lake became the largest for the whole time of observations with the maximum surface area more than 18 ha covering completely the NE fumarolic field and all thermal springs feeding the lake with mineralized water. Despite the maximum volume of the lake it was characterized in 2015 by the highest since 2007 chloride content (~2500 ppm) and temperature (34°C). A large degassing spot in the middle of the lake for the first time was observed in April 2015 with more than 10,000 g m-2 d-1 of the CO2 flux. These observations evidence that the volcano-hydrothermal system of El Chichon volcano came into a new stage of activity associated most probably with changes in the magmatic activity at depth.

An economic assessment of the health effects and crop yield losses caused by air pollution in mainland China.

PubMed

Miao, Weijie; Huang, Xin; Song, Yu

2017-06-01

Air pollution is severe in China, and pollutants such as PM 2.5 and surface O 3 may cause major damage to human health and crops, respectively. Few studies have considered the health effects of PM 2.5 or the loss of crop yields due to surface O 3 using model-simulated air pollution data in China. We used gridded outputs from the WRF-Chem model, high resolution population data, and crop yield data to evaluate the effects on human health and crop yield in mainland China. Our results showed that outdoor PM 2.5 pollution was responsible for 1.70-1.99 million cases of all-cause mortality in 2006. The economic costs of these health effects were estimated to be 151.1-176.9 billion USD, of which 90% were attributed to mortality. The estimated crop yield losses for wheat, rice, maize, and soybean were approximately 9, 4.6, 0.44, and 0.34 million tons, respectively, resulting in economic losses of 3.4 billion USD. The total economic losses due to ambient air pollution were estimated to be 154.5-180.3 billion USD, accounting for approximately 5.7%-6.6% of the total GDP of China in 2006. Our results show that both population health and staple crop yields in China have been significantly affected by exposure to air pollution. Measures should be taken to reduce emissions, improve air quality, and mitigate the economic loss. Copyright © 2016. Published by Elsevier B.V.

Sequestration and Enhanced Coal Bed Methane: Tanquary Farms Test Site, Wabash County, Illinois

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frailey, Scott; Parris, Thomas; Damico, James

The Midwest Geological Sequestration Consortium (MGSC) carried out a pilot project to test storage of carbon dioxide (CO{sub 2}) in the Springfield Coal Member of the Carbondale Formation (Pennsylvanian System), in order to gauge the potential for large-scale CO{sub 2} sequestration and/or enhanced coal bed methane recovery from Illinois Basin coal beds. The pilot was conducted at the Tanquary Farms site in Wabash County, southeastern Illinois. A four-well design an injection well and three monitoring wells was developed and implemented, based on numerical modeling and permeability estimates from literature and field data. Coal cores were taken during the drilling processmore » and were characterized in detail in the lab. Adsorption isotherms indicated that at least three molecules of CO{sub 2} can be stored for each displaced methane (CH{sub 4}) molecule. Microporosity contributes significantly to total porosity. Coal characteristics that affect sequestration potential vary laterally between wells at the site and vertically within a given seam, highlighting the importance of thorough characterization of injection site coals to best predict CO{sub 2} storage capacity. Injection of CO{sub 2} gas took place from June 25, 2008, to January 13, 2009. A continuous injection period ran from July 21, 2008, to December 23, 2008, but injection was suspended several times during this period due to equipment failures and other interruptions. Injection equipment and procedures were adjusted in response to these problems. Approximately 92.3 tonnes (101.7 tons) of CO{sub 2} were injected over the duration of the project, at an average rate of 0.93 tonne (1.02 tons) per day, and a mode injection rate of 0.6-0.7 tonne/day (0.66-0.77 ton/day). A Monitoring, Verification, and Accounting (MVA) program was set up to detect CO{sub 2 leakage. Atmospheric CO{sub 2} levels were monitored as were indirect indicators of CO{sub 2} leakage such as plant stress, changes in gas composition at wellheads, and changes in several shallow groundwater characteristics (e.g., alkalinity, pH, oxygen content, dissolved solids, mineral saturation indices, and isotopic distribution). Results showed that there was no CO{sub 2} leakage into groundwater or CO{sub 2} escape at the surface. Post-injection cased hole well log analyses supported this conclusion. Numerical and analytical modeling achieved a relatively good match with observed field data. Based on the model results the plume was estimated to extend 152 m (500 ft) in the face cleat direction and 54.9 m (180 ft) in the butt cleat direction. Using the calibrated model, additional injection scenarios-injection and production with an inverted five-spot pattern and a line drive pattern could yield CH{sub 4} recovery of up to 70%.« less

Carbon monoxide degassing from seismic fault zones in the Basin and Range province, west of Beijing, China

NASA Astrophysics Data System (ADS)

Sun, Yutao; Zhou, Xiaocheng; Zheng, Guodong; Li, Jing; Shi, Hongyu; Guo, Zhengfu; Du, Jianguo

2017-11-01

Degassing of carbon monoxide (CO), which plays a significant role in the contribution of deep carbon to the atmosphere, commonly occurs within active fault zones. CO degassing from soil to the atmosphere in the Basin and Range province, west of Beijing (BRPB), China, was investigated by in-situ field measurements in the active fault zones. The measured concentrations of CO in soil gas in the BRPB ranged from 0.29 × 10-6 to 1.1 × 10-6 with a mean value of 0.6 × 10-6, which is approximately twice as large as that in the atmosphere. Net fluxes of CO degassing ranged from -48.6 mg m-2 d-1 to 12.03 mg m-2 d-1. The diffusion of CO from soil to the atmosphere in the BRPB was estimated to be at least 7.6 × 103 ton/a, which is comparable to the corresponding result of about 1.2 × 104 ton/a for CO2. CO concentrations were spatially heterogeneous with clearly higher concentrations along the NE-SW trending in the BRPB. These elevated values of CO concentrations were also coincident with the region with low-velocity and high conductivity in deep mantle, and high Poisson's ratio in the crust, thereby suggesting that CO degassing from the soil might be linked to upwelling of the asthenospheric mantle. Other sources of CO in the soil gas are suggested to be dominated by chemical reactions between deep fluids and carbonate minerals (e.g., dolomite, limestone, and siderite) in country rocks. Biogenic processes may also contribute to the CO in soil gas. The spatial distribution patterns of CO concentrations are coincident with the stress field, suggesting that the concentrations of CO could be a potential indicator for crustal stress field and, hence is potential useful for earthquake monitoring in the BRPB.

Modeling cumulative effects in life cycle assessment: the case of fertilizer in wheat production contributing to the global warming potential.

PubMed

Laratte, Bertrand; Guillaume, Bertrand; Kim, Junbeum; Birregah, Babiga

2014-05-15

This paper aims at presenting a dynamic indicator for life cycle assessment (LCA) measuring cumulative impacts over time of greenhouse gas (GHG) emissions from fertilizers used for wheat cultivation and production. Our approach offers a dynamic indicator of global warming potential (GWP), one of the most used indicator of environmental impacts (e.g. in the Kyoto Protocol). For a case study, the wheat production in France was selected and considered by using data from official sources about fertilizer consumption and production of wheat. We propose to assess GWP environmental impact based on LCA method. The system boundary is limited to the fertilizer production for 1 ton of wheat produced (functional unit) from 1910 to 2010. As applied to wheat production in France, traditional LCA shows a maximum GWP impact of 500 kg CO2-eq for 1 ton of wheat production, whereas the GWP impact of wheat production over time with our approach to dynamic LCA and its cumulative effects increases to 18,000 kg CO2-eq for 1 ton of wheat production. In this paper, only one substance and one impact assessment indicator are presented. However, the methodology can be generalized and improved by using different substances and indicators. Copyright © 2014 Elsevier B.V. All rights reserved.

Impact of alcohol fuel production on agricultural markets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gardiner, W.H.

1986-01-01

Production of alcohol from biomass feedstocks, such as corn, was given Federal and State support which resulted in alcohol production rising from 20 million gallons in 1979 to 430 million gallons in 1984. This study estimates the impacts of alcohol production from corn on selected agricultural markets. The tool of analysis was a three region (United States, the European Community and the rest of the world) econometric model of the markets for corn, soybeans, soybean meal, soybean oil, wheat and corn byproduct feeds. Three alternative growth paths for alcohol production (totalling 1.1, 2.0, and 3.0 billion gallons) were analyzed withmore » the model in the context of three different trade environments. The results of this analysis indicate that alcohol production of 1.1 billion gallons by 1980 would have caused moderate adjustments to commodity markets while 3.0 billion gallons would have caused major adjustments. Corn prices rose sharply with increased alcohol production as did wheat prices but to a somewhat lesser extent. The substitution of corn for soybeans on the supply side was not sufficient to offset the demand depressing effects of corn byproduct feeds on soybean meal which translated into slightly lower soybean prices. A quota limiting imports of corn gluten feed into the EC to three million tons annually would cause reductions in export earnings for corn millers.« less

40 CFR 98.147 - Records that must be retained.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Glass Production § 98.147 Records that must be retained. In... paragraphs (a)(1) and (a)(2) of this section: (1) Monthly glass production rate for each continuous glass... glass melting furnace (tons). (b) If process CO2 emissions are calculated according to the procedures...

40 CFR 98.147 - Records that must be retained.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) MANDATORY GREENHOUSE GAS REPORTING Glass Production § 98.147 Records that must be retained. In... paragraphs (a)(1) and (a)(2) of this section: (1) Monthly glass production rate for each continuous glass... glass melting furnace (tons). (b) If process CO2 emissions are calculated according to the procedures...

40 CFR 98.210 - Definition of the source category.

Code of Federal Regulations, 2013 CFR

2013-07-01

... considered to emit CO2 if they consume at least 2,000 tons per year of carbonates heated to a temperature... that uses carbonates or carbonate containing minerals that are consumed in the production of cement... technology used to control emissions from stationary fuel combustion equipment. Emissions from carbonates...

40 CFR 98.210 - Definition of the source category.

Code of Federal Regulations, 2014 CFR

2014-07-01

... considered to emit CO2 if they consume at least 2,000 tons per year of carbonates heated to a temperature... that uses carbonates or carbonate containing minerals that are consumed in the production of cement... technology used to control emissions from stationary fuel combustion equipment. Emissions from carbonates...

40 CFR 98.210 - Definition of the source category.

Code of Federal Regulations, 2011 CFR

2011-07-01

... considered to emit CO2 if they consume at least 2,000 tons per year of carbonates heated to a temperature... that uses carbonates or carbonate containing minerals that are consumed in the production of cement... technology used to control emissions from stationary fuel combustion equipment. Emissions from carbonates...

40 CFR 98.210 - Definition of the source category.

Code of Federal Regulations, 2012 CFR

2012-07-01

... considered to emit CO2 if they consume at least 2,000 tons per year of carbonates heated to a temperature... that uses carbonates or carbonate containing minerals that are consumed in the production of cement... technology used to control emissions from stationary fuel combustion equipment. Emissions from carbonates...

2. NORTH AND WEST SIDES OF BUILDING 1601/1606/1607, WITH DISCHARGED ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. NORTH AND WEST SIDES OF BUILDING 1601/1606/1607, WITH DISCHARGED TON CONTAINERS IN FOREGROUND. VIEW TO SOUTH. - Rocky Mountain Arsenal, Cluster Bomb Assembly-Filling-Storage Building, 3500 feet South of Ninth Avenue; 2870 feet East of D Street, Commerce City, Adams County, CO

40 CFR 98.2 - Who must report?

Code of Federal Regulations, 2010 CFR

2010-07-01

... products that is equivalent to 25,000 metric tons CO2e or more. (iii) Natural gas and natural gas liquids... or oxidation of the volume of petroleum products and natural gas liquids that are imported during the... GREENHOUSE GAS REPORTING General Provision § 98.2 Who must report? (a) The GHG reporting requirements and...

21. INTERIOR DETAIL OF TON CONTAINER DEMILITARIZATION EQUIPMENT IN BUILDING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

21. INTERIOR DETAIL OF TON CONTAINER DEMILITARIZATION EQUIPMENT IN BUILDING 1606. VIEW TO SOUTHWEST. - Rocky Mountain Arsenal, Cluster Bomb Assembly-Filling-Storage Building, 3500 feet South of Ninth Avenue; 2870 feet East of D Street, Commerce City, Adams County, CO

75 FR 68265 - Approval and Promulgation of Implementation Plans; Tennessee: Prevention of Significant...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-05

.... Different GHGs have different heat-trapping capacities. The concept of Global Warming Potential (GWP) was... as much impact on global warming over a 100-year time horizon as 1 ton of CO 2 emissions. Thus, on...

75 FR 68259 - Approval and Promulgation of Implementation Plans; Mississippi: Prevention of Significant...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-05

... different heat-trapping capacities. The concept of Global Warming Potential (GWP) was developed to compare... global warming over a 100-year time horizon as 1 ton of CO 2 emissions. Thus, on the basis of heat...

Final Environmental Assessment for the Military Family Housing Privatization Initiative

DTIC Science & Technology

2006-09-01

Year 2005 through 2009: VOCE = .016 * Trips NOxE = .015 * Trips PM10E = .0022 * Trips COE = .262 * Trips Appendix A Additional Materials Final...Environmental Assessment Page A-39 Military Family Housing Privatization Initiative Robins Air Force Base, Georgia Year 2010 and beyond: VOCE ...yr) = VOCE * DPYII/2000 NOx (tons/yr) = NOxE * DPYII/2000 PM10 (tons/yr) = PM10E * DPYII/2000 CO (tons/yr) = COE * DPYII/2000 Where: Area of

40 CFR Table C-1 to Subpart C of... - Default CO2 Emission Factors and High Heat Values for Various Types of Fuel

Code of Federal Regulations, 2011 CFR

2011-07-01

... Heat Values for Various Types of Fuel C Table C-1 to Subpart C of Part 98 Protection of Environment... Stationary Fuel Combustion Sources Pt. 98, Subpt. C, Table C-1 Table C-1 to Subpart C of Part 98—Default CO2... input from MSW and/or tires; and (c) small batch incinerators that combust no more than 1,000 tons of...

Integrated, Geothermal-CO2 Storage: An Adaptable, Hybrid, Multi-Stage, Energy-Recovery Approach to Reduce Carbon Intensity and Environmental Risk

NASA Astrophysics Data System (ADS)

Buscheck, T. A.; Chen, M.; Lu, C.; Sun, Y.; Hao, Y.; Elliot, T. R.; Celia, M. A.; Bielicki, J. M.

2012-12-01

The challenges of mitigating climate change and generating sustainable renewable energy are inseparable and can be addressed by synergistic integration of geothermal energy production with secure geologic CO2 storage (GCS). Pressure buildup can be a limiting factor for GCS and geothermal reservoir operations, due to a number of concerns, including the potential for CO2 leakage and induced seismicity, while pressure depletion can limit geothermal energy recovery. Water-use demands can also be a limiting factor for GCS and geothermal operations, particularly where water resources are already scarce. Economic optimization of geothermal-GCS involves trade-offs of various benefits and risks, along with their associated costs: (1) heat extraction per ton of delivered CO2, (2) permanent CO2 storage, (3) energy recovery per unit well (and working-fluid recirculation) costs, and (4) economic lifetime of a project. We analyze a hybrid, multi-stage approach using both formation brine and injected CO2 as working fluids to attempt to optimize the benefits of sustainable energy production and permanent CO2 storage, while conserving water resources and minimizing environmental risks. We consider a range of well-field patterns and operational schemes. Initially, the fluid production is entirely brine. After CO2 breakthrough, the fraction of CO2 in production, which is called the CO2 "cut", increases with time. Thus, brine is the predominant working fluid for early time, with the contribution of CO2 to heat extraction increasing with CO2 cut (and time). We find that smaller well spacing between CO2 injectors and producers favors earlier CO2 breakthrough and a more rapid rise in CO2 cut, which increases the contribution of recirculated CO2, thereby improving the heat extraction per ton of delivered CO2. On the other hand, larger well spacing increases permanent CO2 storage, energy production per unit well cost, while reducing the thermal drawdown rate, which extends the economic lifetime of a project. For the range of cases considered, we were never able to eliminate the co-production of brine; thus, brine management is likely to be important for reservoir operations, whether or not brine is considered as a candidate working fluid. Future work will address site-specific reservoir conditions and infrastructure factors, such as proximity to potential CO2 sources. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Rates of volcanic CO2 degassing from airborne determinations of SO2 Emission rates and plume CO2SO2: test study at Pu′u ′O′o Cone, Kilauea Volcano, Hawaii

USGS Publications Warehouse

Gerlach, Terrence M.; McGee, Kenneth A.; Sutton, A. Jefferson; Elias, Tamar

1998-01-01

We present an airborne method that eliminates or minimizes several disadvantages of the customary plume cross-section sampling method for determining volcanic CO2 emission rates. A LI-COR CO2analyzer system (LICOR), a Fourier transform infrared spectrometer system (FTIR), and a correlation spectrometer (COSPEC) were used to constrain the plume CO2/SO2 and the SO2 emission rate. The method yielded a CO2 emission rate of 300 td−1 (metric tons per day) for Pu′u ′O′o cone, Kilauea volcano, on 19 September 1995. The CO2/SO2 of 0.20 determined from airborne LICOR and FTIR plume measurements agreed with the CO2/SO2 of 204 ground-based samples collected from vents over a 14-year period since the Pu′u ′O′o eruption began in January 1983.

Robust Exploration and Commercial Missions to the Moon Using LANTR Propulsion and In-Situ Propellants Derived From Lunar Polar Ice (LPI) Deposits

NASA Technical Reports Server (NTRS)

Borowski, Stanley K.; Ryan, Stephen W.; Burke, Laura M.; McCurdy, David R.; Fittje, James E.; Joyner, Claude R.

2017-01-01

Since the 1960s, scientists have conjectured that water icecould survive in the cold, permanently shadowed craters located at the Moons poles Clementine (1994), Lunar Prospector (1998),Chandrayaan-1 (2008), and Lunar Reconnaissance Orbiter (LRO) and Lunar CRater Observation and Sensing Satellite(LCROSS) (2009) lunar probes have provided data indicating the existence of large quantities of water ice at the lunar poles The Mini-SAR onboard Chandrayaan-1discovered more than 40 permanently shadowed craters near the lunar north pole that are thought to contain 600 million metric tons of water ice. Using neutron spectrometer data, the Lunar Prospector science team estimated a water ice content (1.5 +-0.8 wt in the regolith) found in the Moons polar cold trap sand estimated the total amount of water at both poles at 2 billion metric tons Using Mini-RF and spectrometry data, the LRO LCROSS science team estimated the water ice content in the regolith in the south polar region to be 5.6 +-2.9 wt. On the basis of the above scientific data, it appears that the water ice content can vary from 1-10 wt and the total quantity of LPI at both poles can range from 600 million to 2 billion metric tons NTP offers significant benefits for lunar missions and can take advantage of the leverage provided from using LDPs when they become available by transitioning to LANTR propulsion. LANTR provides a variablethrust and Isp capability, shortens burn times and extends engine life, and allows bipropellant operation The combination of LANTR and LDP has performance capability equivalent to that of a hypothetical gaseousfuel core NTR (effective Isp 1575 s) and can lead to a robust LTS with unique mission capabilities that include short transit time crewed cargo transports and routine commuter flights to the Moon The biggest challenge to making this vision a reality will be the production of increasing amounts of LDP andthe development of propellant depots in LEO, LLO and LPO. An industry-operated, privately financed venture, with NASA as its initial customer, might provide a possible blueprint for future development and operation With industry interested in developing cislunar space and commerce, and competitive forces at work, the timeline for developing this capability could well be accelerated, quicker than any of us can imagine, and just the beginning of things to come.

U. S. food and fiber: abundance or austerity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

The US exports 40% of its agricultural products, which makes it interdependent with the world's need for food and fiber. World population growth projections indicate that US production will have to more than double to 920 billion metric tons of grain. Developing countries, where most of the world population growth is occurring, must produce a larger share too, but the US has the productive capacity and economic advantage to dominate the feedgrains and oilseed market. Uncertainties about world output of agricultural goods and the effects of an unequal distribution of natural resources and economic wealth are examined in this report,more » which assesses productive capacities and economic policy needs to the year 2020. The report anticipates that the world could be better able to feed 6.1 billion people in 2000 than the 4.3 billion in 1980 if the proper investments are made in agricultural infrastructure, research, and education, and if the economic policies provide appropriate incentives. Underlying this projection are the assumptions that world peace and global weather patterns will continue. 6 figures, 9 tables.« less

Selective oxidation of benzyl alcohols to benzoic acid catalyzed by eco-friendly cobalt thioporphyrazine catalyst supported on silica-coated magnetic nanospheres.

PubMed

Li, Huan; Cao, Lan; Yang, Changjun; Zhang, Zhehui; Zhang, Bingguang; Deng, Kejian

2017-10-01

A novel magnetically recoverable thioporphyrazine catalyst (CoPz(S-Bu) 8 /SiO 2 @Fe 3 O 4 ) was prepared by immobilization of the cobalt octkis(butylthio) porphyrazine complex (CoPz(S-Bu) 8 ) on silica-coated magnetic nanospheres (SiO 2 @Fe 3 O 4 ). The composite CoPz(S-Bu) 8 /SiO 2 @Fe 3 O 4 appeared to be an active catalyst in the oxidation of benzyl alcohol in aqueous solution using hydrogen peroxide (H 2 O 2 ) as oxidant under Xe-lamp irradiation, with 36.4% conversion of benzyl alcohol, about 99% selectivity for benzoic acid and turnover number (TON) of 61.7 at ambient temperature. The biomimetic catalyst CoPz(S-Bu) 8 was supported on the magnetic carrier SiO 2 @Fe 3 O 4 so as to suspend it in aqueous solution to react with substrates, utilizing its lipophilicity. Meanwhile the CoPz(S-Bu) 8 can use its unique advantages to control the selectivity of photocatalytic oxidation without the substrate being subjected to deep oxidation. The influence of various reaction parameters on the conversion rate of benzyl alcohol and selectivity of benzoic acid was investigated in detail. Moreover, photocatalytic oxidation of substituted benzyl alcohols was obtained with high conversion and excellent selectivity, specifically conversion close to 70%, selectivity close to 100% and TON of 113.6 for para-position electron-donating groups. The selectivity and eco-friendliness of the biomimetic photocatalyst give it great potential for practical applications. Copyright © 2017. Published by Elsevier B.V.

Research, Development and Demonstration of Bio-Mass Boiler for Food Industry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fisher, Steve; Knapp, David

2012-07-01

Frito-Lay is working to reduce carbon emissions from their manufacturing plants. As part of this effort, they invested in a biomass-fired boiler at the Topeka, Kansas, plant. Frito-Lay partnered with Burns & McDonnell Engineering, Inc. and CPL Systems, Inc., to design and construct a steam producing boiler using carbon neutral fuels such as wood wastes (e.g. tree bark), shipping pallets, and used rubber vehicle tires. The U.S. Department of Energy (DOE) joined with Frito-Lay, Burns & McDonnell, and CPL to analyze the reductions in carbon dioxide (CO 2) emissions that result from use of biomass-fired boilers in the food manufacturingmore » environment. DOE support provided for the data collection and analysis, and reporting necessary to evaluate boiler efficiencies and reductions in CO 2 emissions. The Frito-Lay biomass-fired boiler has resulted in significant reductions in CO 2 emissions from the Topeka production facility. The use of natural gas has been reduced by 400 to 420 million standard cubic feet per year with corresponding reductions of 24,000 to 25,000 tons of CO 2. The boiler does require auxiliary functions, however, that are unnecessary for a gas-fired boiler. These include heavy motors and fans for moving fuel and firing the boiler, trucks and equipment for delivering the fuel and moving at the boiler plant, and chippers for preparing the fuel prior to delivery. Each of these operations requires the combustion of fossil fuels or electricity and has associated CO 2 emissions. Even after accounting for each of these auxiliary processes, however, the biomass-fired boiler results in net emission reductions of 22,500 to 23,500 tons of CO 2 per year.« less

Solar H2 evolution in water with modified diketopyrrolopyrrole dyes immobilised on molecular Co and Ni catalyst-TiO2 hybrids.

PubMed

Warnan, Julien; Willkomm, Janina; Ng, Jamues N; Godin, Robert; Prantl, Sebastian; Durrant, James R; Reisner, Erwin

2017-04-01

A series of diketopyrrolopyrrole (DPP) dyes with a terminal phosphonic acid group for attachment to metal oxide surfaces were synthesised and the effect of side chain modification on their properties investigated. The organic photosensitisers feature strong visible light absorption ( λ = 400 to 575 nm) and electrochemical and fluorescence studies revealed that the excited state of all dyes provides sufficient driving force for electron injection into the TiO 2 conduction band. The performance of the DPP chromophores attached to TiO 2 nanoparticles for photocatalytic H 2 evolution with co-immobilised molecular Co and Ni catalysts was subsequently studied, resulting in solar fuel generation with a dye-sensitised semiconductor nanoparticle system suspended in water without precious metal components. The performance of the DPP dyes in photocatalysis did not only depend on electronic parameters, but also on properties of the side chain such as polarity, steric hinderance and hydrophobicity as well as the specific experimental conditions and the nature of the sacrificial electron donor. In an aqueous pH 4.5 ascorbic acid solution with a phosphonated DuBois-type Ni catalyst, a DPP-based turnover number (TON DPP ) of up to 205 was obtained during UV-free simulated solar light irradiation (100 mW cm -2 , AM 1.5G, λ > 420 nm) after 1 day. DPP-sensitised TiO 2 nanoparticles were also successfully used in combination with a hydrogenase or platinum instead of the synthetic H 2 evolution catalysts and the platinum-based system achieved a TON DPP of up to 2660, which significantly outperforms an analogous system using a phosphonated Ru tris(bipyridine) dye (TON Ru = 431). Finally, transient absorption spectroscopy was performed to study interfacial recombination and dye regeneration kinetics revealing that the different performances of the DPP dyes are most likely dictated by the different regeneration efficiencies of the oxidised chromophores.

Revisiting the social cost of carbon.

PubMed

Nordhaus, William D

2017-02-14

The social cost of carbon (SCC) is a central concept for understanding and implementing climate change policies. This term represents the economic cost caused by an additional ton of carbon dioxide emissions or its equivalent. The present study presents updated estimates based on a revised DICE model (Dynamic Integrated model of Climate and the Economy). The study estimates that the SCC is $31 per ton of CO 2 in 2010 US$ for the current period (2015). For the central case, the real SCC grows at 3% per year over the period to 2050. The paper also compares the estimates with those from other sources.

Revisiting the social cost of carbon

NASA Astrophysics Data System (ADS)

Nordhaus, William D.

2017-02-01

The social cost of carbon (SCC) is a central concept for understanding and implementing climate change policies. This term represents the economic cost caused by an additional ton of carbon dioxide emissions or its equivalent. The present study presents updated estimates based on a revised DICE model (Dynamic Integrated model of Climate and the Economy). The study estimates that the SCC is 31 per ton of CO2 in 2010 US for the current period (2015). For the central case, the real SCC grows at 3% per year over the period to 2050. The paper also compares the estimates with those from other sources.

Enabling the Billion-Ton Bioeconomy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baumes, Harry; Csonka, Steve; Sayre, Richard

2016-08-08

The United States is rich in non-food ‎biomass that can fuel the development of a thriving ‎bioeconomy where renewable and sustainable resources power cars and planes instead of petroleum. The ‎transportation and aviation industry is actively seeking ways to reduce its carbon footprint by powering planes with solid municipal waste, woody biomass, purpose-grown crops, and ‎algae. Watch this short video to learn how biomass is being used to make our country greener, provide new employment opportunities, and reduce our dependence on foreign oil.

Biomass as Feedstock for A Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply

DTIC Science & Technology

2005-04-01

Approximately 20 percent of the corn kernel is not utilized in the production of ethanol and other starch based products, such as sweeteners and high - fructose ...under high yields. The amount of corn and soybeans available for ethanol, biodiesel or other bioproducts was calculated by first subtracting amounts...because of increasing demand for animal feed. This evaluation assumes that corn exports rise by another 10 percent in the high corn yield scenarios

Toward an energy efficient community

NASA Astrophysics Data System (ADS)

Horn, M.

1980-10-01

The current oil policy of the OPEC countries means that a substantial oil shortage may be expected in the future. Conservative estimates indicate an oil shortage of 65 billion tons in the year 2000. The results of numerous new studies show that (from the technological point of view) the savings potential is high enough to achieve an absolute decrease in total energy consumption by the year 2000, provided better use is made of secondary energy sources in the form of electric power, gas, and solar heat.

Properties of concrete containing scrap-tire rubber--an overview.

PubMed

Siddique, Rafat; Naik, Tarun R

2004-01-01

Solid waste management is one of the major environmental concerns in the United States. Over 5 billion tons of non-hazardous solid waste materials are generated in USA each year. Of these, more than 270 million scrap-tires (approximately 3.6 million tons) are generated each year. In addition to this, about 300 million scrap-tires have been stockpiled. Several studies have been carried out to reuse scrap-tires in a variety of rubber and plastic products, incineration for production of electricity, or as fuel for cement kilns, as well as in asphalt concrete. Studies show that workable rubberized concrete mixtures can be made with scrap-tire rubber. This paper presents an overview of some of the research published regarding the use of scrap-tires in portland cement concrete. The benefits of using magnesium oxychloride cement as a binder for rubberized concrete mixtures are also presented. The paper details the likely uses of rubberized concrete.

Intelligent monitoring system for real-time geologic CO2 storage, optimization and reservoir managemen

NASA Astrophysics Data System (ADS)

Dou, S.; Commer, M.; Ajo Franklin, J. B.; Freifeld, B. M.; Robertson, M.; Wood, T.; McDonald, S.

2017-12-01

Archer Daniels Midland Company's (ADM) world-scale agricultural processing and biofuels production complex located in Decatur, Illinois, is host to two industrial-scale carbon capture and storage projects. The first operation within the Illinois Basin-Decatur Project (IBDP) is a large-scale pilot that injected 1,000,000 metric tons of CO2 over a three year period (2011-2014) in order to validate the Illinois Basin's capacity to permanently store CO2. Injection for the second operation, the Illinois Industrial Carbon Capture and Storage Project (ICCS), started in April 2017, with the purpose of demonstrating the integration of carbon capture and storage (CCS) technology at an ethanol plant. The capacity to store over 1,000,000 metric tons of CO2 per year is anticipated. The latter project is accompanied by the development of an intelligent monitoring system (IMS) that will, among other tasks, perform hydrogeophysical joint analysis of pressure, temperature and seismic reflection data. Using a preliminary radial model assumption, we carry out synthetic joint inversion studies of these data combinations. We validate the history-matching process to be applied to field data once CO2-breakthrough at observation wells occurs. This process will aid the estimation of permeability and porosity for a reservoir model that best matches monitoring observations. The reservoir model will further be used for forecasting studies in order to evaluate different leakage scenarios and develop appropriate early-warning mechanisms. Both the inversion and forecasting studies aim at building an IMS that will use the seismic and pressure-temperature data feeds for providing continuous model calibration and reservoir status updates.

Biodiesel production potential of wastewater treatment high rate algal pond biomass.

PubMed

Mehrabadi, Abbas; Craggs, Rupert; Farid, Mohammed M

2016-12-01

This study investigates the year-round production potential and quality of biodiesel from wastewater treatment high rate algal pond (WWT HRAP) biomass and how it is affected by CO 2 addition to the culture. The mean monthly pond biomass and lipid productivities varied between 2.0±0.3 and 11.1±2.5gVSS/m 2 /d, and between 0.5±0.1 and 2.6±1.1g/m 2 /d, respectively. The biomass fatty acid methyl esters were highly complex which led to produce low-quality biodiesel so that it cannot be used directly as a transportation fuel. Overall, 0.9±0.1g/m 2 /d (3.2±0.5ton/ha/year) low-quality biodiesel could be produced from WWT HRAP biomass which could be further increased to 1.1±0.1g/m 2 /d (4.0ton/ha/year) by lowering culture pH to 6-7 during warm summer months. CO 2 addition, had little effect on both the biomass lipid content and profile and consequently did not change the quality of biodiesel. Copyright © 2016. Published by Elsevier Ltd.

Costs for integrating wind into the future ERCOT system with related costs for savings in CO2 emissions.

PubMed

Lu, Xi; McElroy, Michael B; Sluzas, Nora A

2011-04-01

Wind power can make an important contribution to the goal of reducing emissions of CO2. The major problem relates to the intrinsic variability of the source and the difficulty of reconciling the supply of electricity with demand particularly at high levels of wind penetration. This challenge is explored for the case of the ERCOT system in Texas. Demand for electricity in Texas is projected to increase by approximately 60% by 2030. Considering hourly load data reported for 2006, assuming that the pattern of demand in 2030 should be similar to 2006, and adopting as a business as usual (BAU) reference an assumption that the anticipated additional electricity should be supplied by a combination of coal and gas with prices, discounted to 2007 dollars of $2 and $6 per MMBTU respectively, we conclude that the bus-bar price for electricity would increase by about 1.1 ¢/kWh at a wind penetration level of 30%, by about 3.4 ¢/kWh at a penetration level of 80%. Corresponding costs for reductions in CO2 range from $20/ton to $60/ton. A number of possibilities are discussed that could contribute to a reduction in these costs including the impact of an expanded future fleet of electrically driven vehicles.

40 CFR 98.213 - Calculating GHG emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... calcination fractions with Equation U-1 of this section. ER30OC09.077 Where: ECO2 = Annual CO2 mass emissions... ton carbonate consumed. Fi = Fraction calcination achieved for each particular carbonate type i (decimal fraction). As an alternative to measuring the calcination fraction, a value of 1.0 can be used. n...

Polycyclic aromatic hydrocarbon (PAH)-containing soils from coal gangue stacking areas contribute to epithelial to mesenchymal transition (EMT) modulation on cancer cell metastasis.

PubMed

Yun, Yang; Gao, Rui; Yue, Huifeng; Liu, Xiaofang; Li, Guangke; Sang, Nan

2017-02-15

The total accumulative stockpiles of gangue in China comprise 4.5billion metric tons, and approximately 659million tons of additional gangue are generated per year. Considering the stacking characteristics are highly heterogeneous, the potential cancer risks from the presence of polycyclic aromatic hydrocarbons (PAHs) remain elusive. This study aimed to determine whether PAH-containing soil around coal gangue stacking areas poses a potential cancer risk and contributes to cancer cell metastasis. The results indicate that eighteen PAHs, primarily originated from coal gangue, exhibited distance variations from the coal gangues to the downstream villages, and the abandoned colliery posed increased potential carcinogenic risks for humans as a result of long-term stacking of coal gangue. Furthermore, soil samples stimulated HepG2 cell migration and invasion in a PAH-dependent manner, and the action was involved in PPARγ-mediated epithelial to mesenchymal transition (EMT) modulation. These findings highlight the potential cancer risk of PAH-containing soil samples around coal gangue stacking areas, and identify important biomarkers underlying the risk and targets preventing the outcomes in polluted areas. Copyright © 2016 Elsevier B.V. All rights reserved.

Melting mountains of Appalachia: exceptionally high weathering rates in mined watersheds

NASA Astrophysics Data System (ADS)

Ross, M. R.; Nippgen, F.; Hassett, B.; McGlynn, B. L.; Bernhardt, E. S.

2016-12-01

Mountaintop mining operations excavate ridges as deep as 200 m and bury adjacent valleys and streams beneath fractured bedrock and coal residues. Post-mining, landscapes have lower slopes, greatly increased water storage potential, and an abundance of acid-generating pyrite, which is intentionally mixed with neutralizing calcareous bedrock. Together these design features of mountaintop mined lands create ideal conditions for long water residence times and rapid weathering rates, leading to widely documented and substantial increases in streamwater ion concentrations. To date, these concentration changes have not been linked to rates of watershed scale element flux. In a paired catchment study, we documented a 4,000% increase in the export of total dissolved solids from a mined watershed, and estimate that pyrite and carbonate weathering in reclaimed mines can export 9,000 kg ha-1 y-1 of dissolved rock to receiving streams. Such high rates of element flux after a disturbance are not only much higher than other watershed disturbances, but are among the highest rates of weathering ever reported globally. Sulfuric acid weathering of carbonate rock drives these patterns of chemical erosion. This strong acid weathering changes Appalachian geology from a slight net geologic CO2 sink-sequestering 800-1,500 kg CO2 km-2 yr-1 through carbonic acid weathering of carbonates-to a substantial net geologic source of CO2, releasing 170,000 kg CO2 km-2 yr-1. Over the more than 4,000 km2 area of Central Appalachia that has undergone mountaintop mining, this rapid weathering represents 4 million tons of dissolved rock being delivered to the streams of West Virginia, potentially releasing 680,000 tons of CO2 in the process.

AgI /TMG-Promoted Cascade Reaction of Propargyl Alcohols, Carbon Dioxide, and 2-Aminoethanols to 2-Oxazolidinones.

PubMed

Li, Xue-Dong; Song, Qing-Wen; Lang, Xian-Dong; Chang, Yao; He, Liang-Nian

2017-11-17

Chemical valorization of CO 2 to access various value-added compounds has been a long-term and challenging objective from the viewpoint of sustainable chemistry. Herein, a one-pot three-component reaction of terminal propargyl alcohols, CO 2 , and 2-aminoethanols was developed for the synthesis of 2-oxazolidinones and an equal amount of α-hydroxyl ketones promoted by Ag 2 O/TMG (1,1,3,3-tetramethylguanidine) with a TON (turnover number) of up to 1260. By addition of terminal propargyl alcohol, the thermodynamic disadvantage of the conventional 2-aminoethanol/CO 2 coupling was ameliorated. Mechanistic investigations including control experiments, DFT calculation, kinetic and NMR studies suggest that the reaction proceeds through a cascade pathway and TMG could activate propargyl alcohol and 2-aminoethanol through the formation of hydrogen bonds and also activate CO 2 . © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Estimation of automobile emissions and control strategies in India.

PubMed

Nesamani, K S

2010-03-15

Rapid, but unplanned urban development and the consequent urban sprawl coupled with economic growth have aggravated auto dependency in India over the last two decades. This has resulted in congestion and pollution in cities. The central and state governments have taken many ameliorative measures to reduce vehicular emissions. However, evolution of scientific methods for emission inventory is crucial. Therefore, an attempt has been made to estimate the emissions (running and start) from on-road vehicles in Chennai using IVE model in this paper. GPS was used to collect driving patterns. The estimated emissions from motor vehicles in Chennai in 2005 were 431, 119, 46, 7, 4575, 29, and 0.41 tons/days respectively for CO, VOC, NO(x), PM, CO(2,) CH(4) and N(2)O. It is observed from the results that air quality in Chennai has degraded. The estimation revealed that two and three-wheelers emitted about 64% of the total CO emissions and heavy-duty vehicles accounted for more than 60% and 36% of the NO(x) and PM emissions respectively. About 19% of total emissions were that of start emissions. It is also estimated that on-road transport contributes about 6637 tons/day CO(2) equivalent in Chennai. This paper has further examined various mitigation options to reduce vehicular emissions. The study has concluded that advanced vehicular technology and augmentation of public transit would have significant impact on reducing vehicular emissions.

Analysis of Geologic CO2 Sequestration at Farnham Dome, Utah, USA

NASA Astrophysics Data System (ADS)

Lee, S.; Han, W.; Morgan, C.; Lu, C.; Esser, R.; Thorne, D.; McPherson, B.

2008-12-01

The Farnham Dome in east-central Utah is an elongated, Laramide-age anticline along the northern plunge of the San Rafael uplift and the western edge of the Uinta Basin. We are helping design a proposed field demonstration of commercial-scale geologic CO2 sequestration, including injection of 2.9 million tons of CO2 over four years time. The Farnham Dome pilot site stratigraphy includes a stacked system of saline formations alternating with low-permeability units. Facilitating the potential sequestration demonstration is a natural CO2 reservoir at depth, the Jurassic-age Navajo formation, which contains an estimated 50 million tons of natural CO2. The sequestration test design includes two deep formations suitable for supercritical CO2 injection, the Jurassic-age Wingate sandstone and the Permian-age White Rim sandstone. We developed a site-specific geologic model based on available geophysical well logs and formation tops data for use with numerical simulation. The current geologic model is limited to an area of approximately 6.5x4.5 km2 and 2.5 km thick, which contains 12 stacked formations starting with the White Rim formation at the bottom (>5000 feet bgl) and extending to the Jurassic Curtis formation at the top of the model grid. With the detail of the geologic model, we are able to estimate the Farnham Dome CO2 capacity at approximately 36.5 million tones within a 5 mile radius of a single injection well. Numerical simulation of multiphase, non- isothermal CO2 injection and flow suggest that the injected CO2 plume will not intersect nearby fault zones mapped in previous geologic studies. Our simulations also examine and compare competing roles of different trapping mechanisms, including hydrostratigraphic, residual gas, solubility, and mineralization trapping. Previous studies of soil gas flux at the surface of the fault zones yield no significant evidence of CO2 leakage from the natural reservoir at Farnham Dome, and thus we use these simulations to evaluate what factors make this natural reservoir so effective for CO2 storage. Our characterization and simulation efforts are producing a CO2 sequestration framework that incorporates production and capacity estimation, area-of-review, injectivity, and trapping mechanisms. Likewise, mitigation and monitoring strategies have been formulated from the site characterization and modeling results.

Volcanic gas emissions and degassing dynamics at Ubinas and Sabancaya volcanoes; implications for the volatile budget of the central volcanic zone

NASA Astrophysics Data System (ADS)

Moussallam, Yves; Tamburello, Giancarlo; Peters, Nial; Apaza, Fredy; Schipper, C. Ian; Curtis, Aaron; Aiuppa, Alessandro; Masias, Pablo; Boichu, Marie; Bauduin, Sophie; Barnie, Talfan; Bani, Philipson; Giudice, Gaetano; Moussallam, Manuel

2017-09-01

Emission of volcanic gas is thought to be the dominant process by which volatiles transit from the deep earth to the atmosphere. Volcanic gas emissions, remain poorly constrained, and volcanoes of Peru are entirely absent from the current global dataset. In Peru, Sabancaya and Ubinas volcanoes are by far the largest sources of volcanic gas. Here, we report the first measurements of the compositions and fluxes of volcanic gases emitted from these volcanoes. The measurements were acquired in November 2015. We determined an average SO2 flux of 15.3 ± 2.3 kg s- 1 (1325-ton day- 1) at Sabancaya and of 11.4 ± 3.9 kg s- 1 (988-ton day- 1) at Ubinas using scanning ultraviolet spectroscopy and dual UV camera systems. In-situ Multi-GAS analyses yield molar proportions of H2O, CO2, SO2, H2S and H2 gases of 73, 15, 10 1.15 and 0.15 mol% at Sabancaya and of 96, 2.2, 1.2 and 0.05 mol% for H2O, CO2, SO2 and H2S at Ubinas. Together, these data imply cumulative fluxes for both volcanoes of 282, 30, 27, 1.2 and 0.01 kg s- 1 of H2O, CO2, SO2, H2S and H2 respectively. Sabancaya and Ubinas volcanoes together contribute about 60% of the total CO2 emissions from the Central Volcanic zone, and dominate by far the total revised volatile budget of the entire Central Volcanic Zone of the Andes.

Current use of carbonate rocks and lime for controlling emissions from coal-fired plants in Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dever, G.R. Jr.

1993-03-01

Seven coal-fired power plants in Kentucky currently are operating wet-scrubbing systems for flue-gas desulfurization. Atmospheric fluidized-bed combustion (AFBC) units are being used for SO[sub 2] emission control at a petroleum refinery, and a 160-MW utility-scale AFBC demonstration plant is being operated by the Tennessee Valley Authority. A lime-based spray-dryer reactor system has been installed on an industrial boiler, and a spray-dryer system is being tested at a utility pilot-plant facility. Four of the seven power plants operate limestone-based wet-scrubbing systems and require about 885,000 tons of stone per year. Stone is obtained from Mississippian limestones, principally the Ste. Genevieve Limestone,more » produced at four quarries in Kentucky, Indiana, and Illinois. Scrubber limestone specifications include CaCO[sub 3] content (minimum 88--90%), MgCO[sub 3] content (maximum 4--6%), and grindability (maximum Bond Work Index of 11--12). Three power plants operate lime-based scrubbers, requiring about 250,000 tons of lime per year. The scrubbers currently use (1) lime manufactured from an Ordovician dolomitic limestone, mined in north-central Kentucky, and (2) carbide lime, a chemical-industry byproduct. Fluidized-bed units at the petroleum refinery require about 100,000 tons of sorbent stone per year. The sorbent consists of about equal amounts of Silurian dolomite from Ohio and Ordovician dolomitic limestone from Kentucky. The utility-scale AFBC demonstration plant uses a limestone sorbent and currently requires about 200,000 tons of stone per year. Limestone is obtained from the Ste. Genevieve in western Kentucky.« less

Impact of a University-Based Outpatient Telemedicine Program on Time Savings, Travel Costs, and Environmental Pollutants.

PubMed

Dullet, Navjit W; Geraghty, Estella M; Kaufman, Taylor; Kissee, Jamie L; King, Jesse; Dharmar, Madan; Smith, Anthony C; Marcin, James P

2017-04-01

The objective of this study was to estimate travel-related and environmental savings resulting from the use of telemedicine for outpatient specialty consultations with a university telemedicine program. The study was designed to retrospectively analyze the telemedicine consultation database at the University of California Davis Health System (UCDHS) between July 1996 and December 2013. Travel distances and travel times were calculated between the patient home, the telemedicine clinic, and the UCDHS in-person clinic. Travel cost savings and environmental impact were calculated by determining differences in mileage reimbursement rate and emissions between those incurred in attending telemedicine appointments and those that would have been incurred if a visit to the hub site had been necessary. There were 19,246 consultations identified among 11,281 unique patients. Telemedicine visits resulted in a total travel distance savings of 5,345,602 miles, a total travel time savings of 4,708,891 minutes or 8.96 years, and a total direct travel cost savings of $2,882,056. The mean per-consultation round-trip distance savings were 278 miles, average travel time savings were 245 minutes, and average cost savings were $156. Telemedicine consultations resulted in a total emissions savings of 1969 metric tons of CO 2 , 50 metric tons of CO, 3.7 metric tons of NO x , and 5.5 metric tons of volatile organic compounds. This study demonstrates the positive impact of a health system's outpatient telemedicine program on patient travel time, patient travel costs, and environmental pollutants. Copyright © 2017 International Society for Pharmacoeconomics and Outcomes Research (ISPOR). Published by Elsevier Inc. All rights reserved.

Improved Characterization and Modeling of Tight Oil Formations for CO 2 Enhanced Oil Recovery Potential and Storage Capacity Estimation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sorensen, James; Smith, Steven; Kurz, Bethany

Tight oil formations such as those in the Bakken petroleum system are known to hold hundreds of billions of barrels of oil in place; however, the primary recovery factor for these plays is typically less than 10%. Tight oil formations, including the Bakken Formation, therefore, may be attractive candidates for enhanced oil recovery (EOR) using CO 2. Multiphase fluid behavior and flow in fluid-rich shales can vary substantially depending on the size of pore throats, and properties such as fluid viscosity and density are much different in nanoscale pores than in macroscale pores. Thus it is critical to understand themore » nature and distribution of nano-, micro-, and macroscale pores and fracture networks. To address these issues, the Energy & Environmental Research Center (EERC) has been conducting a research program entitled “Improved Characterization and Modeling of Tight Oil Formations for CO 2 Enhanced Oil Recovery Potential and Storage Capacity Estimation.” The objectives of the project are 1) the use of advanced characterization methods to better understand and quantify the petrophysical and geomechanical factors that control CO 2 and oil mobility within tight oil formation samples, 2) the determination of CO 2 permeation and oil extraction rates in tight reservoir rocks and organic-rich shales of the Bakken, and 3) the integration of the laboratory-based CO 2 permeation and oil extraction data and the characterization data into geologic models and dynamic simulations to develop predictions of CO 2 storage resource and EOR in the Bakken tight oil formation. A combination of standard and advanced petrophysical characterization techniques were applied to characterize samples of Bakken Formation tight reservoir rock and shales from multiple wells. Techniques included advanced computer tomography (CT) imaging, scanning electron microscopy (SEM) techniques, whole-core and micro x-ray CT imaging, field emission (FE) SEM, and focused ion beam (FIB) SEM. Selected samples were also analyzed for geomechanical properties. X-ray CT imaging yielded information on the occurrence of fractures, bedding planes, fossils, and bioturbation in core, as well as data on bulk density and photoelectric factor logs, which were used to interpret porosity, organic content, and mineralogy. FESEM was used for characterization of nano- and microscale features, including nanoscale pore visualization and micropore and pore throat mineralogy. FIBSEM yielded micro- to nanoscale visualization of fracture networks, porosity and pore-size distribution, connected versus isolated porosity, and distribution of organics. Results from the characterization activities provide insight on nanoscale fracture properties, pore throat mineralogy and connectivity, rock matrix characteristics, mineralogy, and organic content. Laboratory experiments demonstrated that CO 2 can permeate the tight matrix of Bakken shale and nonshale reservoir samples and mobilize oil from those samples. Geologic models were created at scales ranging from the core plug to the reservoir, and dynamic simulations were conducted. The data from the characterization and laboratory-based activities were integrated into modeling research activities to determine the fundamental mechanisms controlling fluid transport in the Bakken, which support EOR scheme design and estimation of CO 2 storage potential in tight oil formations. Simulation results suggest a CO 2 storage resource estimate range of 169 million to 1.5 billion tonnes for the Bakken in North Dakota, possibly resulting in 1.8 billion to 16 billion barrels of incremental oil.« less

CO2 Adsorption in Low-Rank Coals: Progress Toward Assessing the National Capacity to Store CO2 in the Subsurface

NASA Astrophysics Data System (ADS)

Stanton, R. W.; Burruss, R. C.; Flores, R. M.; Warwick, P. D.

2001-05-01

Subsurface environments for geologic storage of CO2 from combustion of fossil fuel include saline formations, depleted oil and gas reservoirs, and unmineable coalbeds. Of these environments, storage in petroleum reservoirs and coal beds offers a potential economic benefit of enhanced recovery of energy resources. Meaningful assessment of the volume and geographic distribution of storage sites requires quantitative estimates of geologic factors that control storage capacity. The factors that control the storage capacity of unmineable coalbeds are poorly understood. In preparation for a USGS assessment of CO2 storage capacity we have begun new measurements of CO2 and CH4 adsorption isotherms of low-rank coal samples from 4 basins. Initial results for 13 samples of low-rank coal beds from the Powder River Basin (9 subbituminous coals), Greater Green River Basin (1 subbituminous coal), Williston Basin (2 lignites) and the Gulf Coast (1 lignite) indicate that their adsorption capacity is up to 10 times higher than it is for CH4. These values contrast with published measurements of the CO2 adsorption capacity of bituminous coals from the Fruitland Formation, San Juan basin, and Gates Formation, British Columbia, that indicate about twice as much carbon dioxide as methane can be adsorbed on coals. Because CH4 adsorption isotherms are commonly measured on coals, CO2 adsorption capacity can be estimated if thecorrect relationship between the gases is known. However, use a factor to predict CO2 adsorption that is twice that of CH4 adsorption, which is common in the published literature, grossly underestimates the storage capacity of widely distributed, thick low-rank coal beds. Complete petrographic and chemical characterization of these low-rank coal samples is in progress. Significant variations in adsorption measurements among samples are depicted depending on the reporting basis used. Properties were measured on an "as received" (moist) basis but can be converted to a dry basis, ash-free basis (moist), or dry ash-free basis to emphasize the property having the greatest effect on the adsorption isotherm. Initial results show that moisture content has a strong effect on CO2 adsorption. Our current sample base covers a limited range of coal rank and composition. Full characterization of the storage capacity of coalbeds in the US will require additional samples that cover a broader range of coal compositions, ranks, and depositional environments. Even at this preliminary stage, we can use results from the recent USGS assessment of the Powder River Basin (Wyoming and Montana) to examine the impact of these new measurements on estimates of storage capacity. At depths greater than 500 feet, the Wyodak-Anderson coal zone contains 360 billion metric tons of coal. Using the new measurements of CO2 storage capacity, this coal zone could, theoretically, sequester about 290 trillion cubic feet (TCF) of CO2. This estimate contrasts sharply with an estimated capacity of 70 TCF based on the published values for bituminous coals.

Performance evaluation of integrated solid-liquid wastes treatment technology in palm oil industry

NASA Astrophysics Data System (ADS)

Amelia, J. R.; Suprihatin, S.; Indrasti, N. S.; Hasanudin, U.; Fujie, K.

2017-05-01

The oil palm industry significantly contributes to environmental degradation if without waste management properly. The newest alternative waste management that might be developed is by utilizing the effluent of POME anaerobic digestion with EFB through integrated anaerobic decomposition process. The aim of this research was to examine and evaluate the integrated solid-liquid waste treatment technology in the view point of greenhouse gasses emission, compost, and biogas production. POME was treated in anaerobic digester with loading rate about 1.65 gCOD/L/day. Treated POME with dosis of 15 and 20 L/day was sprayed to the anaerobic digester that was filled of 25 kg of EFB. The results of research showed that after 60 days, the C/N ratio of EFB decreased to 12.67 and 10.96 for dosis of treated POME 15 and 20 L/day, respectively. In case of 60 day decomposition, the integrated waste treatment technology could produce 51.01 and 34.34 m3/Ton FFB which was equivalent with 636,44 and 466,58 kgCO2e/ton FFB for dosis of treated POME 15 and 20 L/day, respectively. The results of research also showed that integrated solid-liquid wastes treatment technology could reduce GHG emission about 421.20 and 251.34 kgCO2e/ton FFB for dosis of treated POME 15 and 20 L/day, respectively.

Understanding of the carbon dioxide sequestration in extremely low-permeability saline aquifers in the Ordos Basin

NASA Astrophysics Data System (ADS)

Zhang, K.; Xie, J.; Hu, L.; Wang, Y.; Chen, M.

2014-12-01

A full-chain CCS demonstration project was started in 2010 by capturing and injecting around 100,000 tons of CO2 per annum into extremely low-permeability sandstone formations in the northeastern Ordos basin, Inner Mongonia, China. It is the first demonstration project in China for the purpose of public interests by sequestrating in the deep saline aquifers massive amount of CO2 captured from a coal liquefaction company. The injection takes place in overall five brine-bearing geological units that are composed of four sandstones and one carbonate, which are interbedded with various mudstone caprocks. A single vertical well was drilled to the depth of 2826m. Injection screens are opened to more than 20 thin aquifers distributed between the depth 1690m-2453m with a total of 88 m injecting thickness. The permeability for all the storage formations is less 10 md and porosity is in the range of 1-12%. Hydraulic fracturing and formation acidizing were conducted at 10 layers for reservoir improvement. Up to present, total injection of CO2 is about 280,000 tons. Injection pressure drops from around 8.5 MP at the beginning to less than 5MP at present and most CO2 goes to shallowest injection formation at the depth interval 1690-1699 m, which has not been conducted any reservoir improvement. We intend to understand the improving injectivity of such low permeability reservoirs with numerical simulations. The modeling results reasonably describe the spreading of the CO2 plume. After 3 years of injection of CO2, the maximum migrating distance of CO2 plume is about 500 m and the pore pressure build-up is slightly less than 15 MPa. The major storage reservoir at the depth interval 1690-1699 m contributes over 80% of the storage capacity of the entire reservoir system.

Chapter 1: Introduction and Summary

USDA-ARS?s Scientific Manuscript database

In 2013, total U.S. greenhouse gas emissions measured 6,673 million metric tons of carbon dioxide equivalents (MMT CO2 eq.), rising 5.9 percent from 1990 estimates. Global concentrations of the three most important long-lived greenhouse gases (GHG) in the atmosphere have increased measurably since t...

In-place oil shale resources in the saline-mineral and saline-leached intervals, Parachute Creek Member of the Green River Formation, Piceance Basin, Colorado

USGS Publications Warehouse

Birdwell, Justin E.; Mercier, Tracey J.; Johnson, Ronald C.; Brownfield, Michael E.; Dietrich, John D.

2014-01-01

A recent U.S. Geological Survey analysis of the Green River Formation of the Piceance Basin in western Colorado shows that about 920 and 352 billion barrels of oil are potentially recoverable from oil shale resources using oil-yield cutoffs of 15 and 25 gallons per ton (GPT), respectively. This represents most of the high-grade oil shale in the United States. Much of this rich oil shale is found in the dolomitic Parachute Creek Member of the Green River Formation and is associated with the saline minerals nahcolite and halite, or in the interval where these minerals have been leached by groundwater. The remaining high-grade resource is located primarily in the underlying illitic Garden Gulch Member of the Green River Formation. Of the 352 billion barrels of potentially recoverable oil resources in high-grade (≥25 GPT) oil shale, the relative proportions present in the illitic interval, non-saline R-2 zone, saline-mineral interval, leached interval (excluding leached Mahogany zone), and Mahogany zone were 3.1, 4.5, 36.6, 23.9, and 29.9 percent of the total, respectively. Only 2 percent of high-grade oil shale is present in marginal areas where saline minerals were never deposited.

The "Escarot" gas seep, French Massif Central: CO2 discharge from a quiescent volcanic system - Characterization and quantification of gas emissions

NASA Astrophysics Data System (ADS)

Gal, F.; Leconte, S.; Gadalia, A.

2018-03-01

Natural CO2 emissions from the volcanic rocks of the French Massif Central are poorly constrained. It is of interest better to assess the emission of such non-anthropogenic gases that may significantly contribute to the global carbon budget. We quantified the CO2 emissions to the atmosphere in a small area (0.052 km2) located in the Massif Central close to Lake Pavin, the most recent volcanic edifice in metropolitan France. The specific character of this area, known as the Escarot mofette, was earlier studied for soil-gas concentrations only. In June 2017, we used the accumulation chamber method for measuring CO2 flux and related O2 depletion in the gases emitted at the soil/atmosphere interface, resulting in 176 data acquisitions over four days. In addition, 44 soil-gas concentration measurements were made at selected locations. CO2 emission rates are estimated at 8100 ± 1800 tons/year of deep-seated CO2 and at 660 ± 440 tons/year of biologically produced CO2. The uncertainty on these evaluations comes from the high-frequency variability of CO2 efflux in the more emissive areas and from the occurrence of heavy precipitation events. Though unexpected, these events were used for quantifying the decreases in CO2 efflux, which were as high as 500% over a few hours or even days in some locations. However, repeat acquisitions performed under more favourable weather conditions showed errors of commonly accepted amplitude (±15%). The area showed several degassing centres aligned along a NNW-SSE direction that correlates well with known geological structures, proving the ability of soil-gas methods to map hidden faults. The whole area is characterized by strong CO2 enrichment and related O2 depletion, but it is nonetheless possible to detect areas influenced by the rise of deep-seated gases and a few peripheral areas where biological processes dominate (CO2 up to 10% vol.). This study of gas emissions in a non-urban area also provides complementary information that is of use when extrapolated to similar structures in urban areas, where the occurrence of such gas releases, and its potential hazard may be more difficult to assess.

UT/LS chemistry and transport

DOT National Transportation Integrated Search

2008-01-24

The global commercial aircraft fleet currently numbers about 10,000 and flies several billion kilometres per year while burning more than 100 MT of fuel per year at high temperatures producing mostly water and CO2. However, NOx (=NO+NO2), other minor...

USGS capabilities for interdisciplinary investigations in coastal and nearshore ecosystems of the Great Lakes

USGS Publications Warehouse

Myers, Donna N.

2002-01-01

People choose to reside, work, and vacation in coastal areas of the Great Lakes because of the lakes' scenic beauty and their historic and cultural features. Great Lakes nearshore areas also constitute a valuable economic resource. Two million anglers added \\$1 billion to the region's economy in 1996. More than 300 million tons of goods were transported out of major Great Lakes ports at a value of \\$3 billion in 1996. A 1998 survey of Lake Erie beaches estimated contributions of $5 million per year to each local economy with a public beach. More than 70 million people yearly visit national, state and provincial parks in the Great Lakes area. Uncontrolled land development, recreational development, invasive species, climate change, water availability, and water-level changes and fluctuations lead a long list of current and potential issues in coastal and nearshore areas. To be effectively addressed, these complex issues require an interdisciplinary approach.

Porphyry copper deposit model: Chapter B in Mineral deposit models for resource assessment

USGS Publications Warehouse

Ayuso, Robert A.; Barton, Mark D.; Blakely, Richard J.; Bodnar, Robert J.; Dilles, John H.; Gray, Floyd; Graybeal, Fred T.; Mars, John L.; McPhee, Darcy K.; Seal, Robert R.; Taylor, Ryan D.; Vikre, Peter G.; John, David A.

2010-01-01

This report contains a revised descriptive model of porphyry copper deposits (PCDs), the world's largest source (about 60 percent) and resource (about 65 percent) of copper and a major source of molybdenum, gold and silver. Despite relatively low grades (average 0.44 percent copper in 2008), PCDs have significant economic and societal impacts due to their large size (commonly hundreds of millions to billions of metric tons), long mine lives (decades), and high production rates (billions of kilograms of copper per year). The revised model describes the geotectonic setting of PCDs, and provides extensive regional- to deposit-scale descriptions and illustrations of geological, geochemical, geophysical, and geoenvironmental characteristics. Current genetic theories are reviewed and evaluated, knowledge gaps are identified, and a variety of exploration and assessment guides are presented. A summary is included for users seeking overviews of specific topics.

Evaluation of handling and reuse approaches for the waste generated from MEA-based CO2 capture with the consideration of regulations in the UAE.

PubMed

Nurrokhmah, Laila; Mezher, Toufic; Abu-Zahra, Mohammad R M

2013-01-01

A waste slip-stream is generated from the reclaiming process of monoethanolamine (MEA) based Post-Combustion Capture (PCC). It mainly consists of MEA itself, ammonium, heat-stable salts (HSS), carbamate polymers, and water. In this study, the waste quantity and nature are characterized for Fluor's Econamine FGSM coal-fired CO2 capture base case. Waste management options, including reuse, recycling, treatment, and disposal, are investigated due to the need for a more environmentally sound handling. Regulations, economic potential, and associated costs are also evaluated. The technical, economic, and regulation assessment suggests waste reuse for NOx scrubbing. Moreover, a high thermal condition is deemed as an effective technique for waste destruction, leading to considerations of waste recycling into a coal burner or incineration. As a means of treatment, three secondary-biological processes covering Complete-Mix Activated Sludge (CMAS), oxidation ditch, and trickling filter are designed to meet the wastewater standards in the United Arab Emirates (UAE). From the economic point of view, the value of waste as a NOx scrubbing agent is 6,561,600-7,348,992 USD/year. The secondary-biological treatment cost is 0.017-0.02 USD/ton of CO2, while the cost of an on-site incinerator is 0.031 USD/ton of CO2 captured. In conclusion, secondary biological treatment is found to be the most economical option.

Air Emission Reduction Benefits of Biogas Electricity Generation at Municipal Wastewater Treatment Plants.

PubMed

Gingerich, Daniel B; Mauter, Meagan S

2018-02-06

Conventional processes for municipal wastewater treatment facilities are energy and materially intensive. This work quantifies the air emission implications of energy consumption, chemical use, and direct pollutant release at municipal wastewater treatment facilities across the U.S. and assesses the potential to avoid these damages by generating electricity and heat from the combustion of biogas produced during anaerobic sludge digestion. We find that embedded and on-site air emissions from municipal wastewater treatment imposed human health, environmental, and climate (HEC) damages on the order of $1.63 billion USD in 2012, with 85% of these damages attributed to the estimated consumption of 19 500 GWh of electricity by treatment processes annually, or 0.53% of the US electricity demand. An additional 11.8 million tons of biogenic CO 2 are directly emitted by wastewater treatment and sludge digestion processes currently installed at plants. Retrofitting existing wastewater treatment facilities with anaerobic sludge digestion for biogas production and biogas-fueled heat and electricity generation has the potential to reduce HEC damages by up to 24.9% relative to baseline emissions. Retrofitting only large plants (>5 MGD), where biogas generation is more likely to be economically viable, would generate HEC benefits of $254 annually. These findings reinforce the importance of accounting for use-phase embedded air emissions and spatially resolved marginal damage estimates when designing sustainable infrastructure systems.

A Full-Featured User Friendly CO 2-EOR and Sequestration Planning Software

DOE Office of Scientific and Technical Information (OSTI.GOV)

Savage, Bill

A Full-Featured, User Friendly CO 2-EOR and Sequestration Planning Software This project addressed the development of an integrated software solution that includes a graphical user interface, numerical simulation, visualization tools and optimization processes for reservoir simulation modeling of CO 2-EOR. The objective was to assist the industry in the development of domestic energy resources by expanding the application of CO 2-EOR technologies, and ultimately to maximize the CO 2} sequestration capacity of the U.S. The software resulted in a field-ready application for the industry to address the current CO 2-EOR technologies. The software has been made available to the publicmore » without restrictions and with user friendly operating documentation and tutorials. The software (executable only) can be downloaded from NITEC’s website at www.nitecllc.com. This integrated solution enables the design, optimization and operation of CO 2-EOR processes for small and mid-sized operators, who currently cannot afford the expensive, time intensive solutions that the major oil companies enjoy. Based on one estimate, small oil fields comprise 30% of the of total economic resource potential for the application of CO 2-EOR processes in the U.S. This corresponds to 21.7 billion barrels of incremental, technically recoverable oil using the current “best practices”, and 31.9 billion barrels using “next-generation” CO 2-EOR techniques. The project included a Case Study of a prospective CO 2-EOR candidate field in Wyoming by a small independent, Linc Energy Petroleum Wyoming, Inc. NITEC LLC has an established track record of developing innovative and user friendly software. The Principle Investigator is an experienced manager and engineer with expertise in software development, numerical techniques, and GUI applications. Unique, presently-proprietary NITEC technologies have been integrated into this application to further its ease of use and technical functionality.« less

Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paul Imhoff; Ramin Yazdani; Don Augenstein

Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by aboutmore » 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).« less

40 CFR 98.360 - Definition of the source category.

Code of Federal Regulations, 2010 CFR

2010-07-01

...,000 metric tons CO2e or more per year. (1) Table JJ-1 presents the minimum average annual animal... Table JJ-1 do not need to report under this rule. A facility with an annual animal population that exceeds those listed in Table JJ-1 should conduct a more thorough analysis to determine applicability. (2...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nelson, W.J.; DeMaris, P.J.; Bauer, R.A.

One of the largest deposits of low-sulfur coal in the Illinois Basin is in the so-called Hornsby District of Christian, Macoupin, and Montgomery Counties. An estimated resource of 1.17 billion tons of Herrin (No. 6) Coal, containing less than 2.5% sulfur, occurs here. Although the Hornsby deposit is thick, lies at moderate depth, and is close to market and labor supply, it has been barely touched by mining. The primary deterrent to mining this high-quality product has been fear of unstable roof conditions. Low-sulfur Hornsby coal contains about 1.5% less ash and 2% more moisture than does adjacent high-sulfur coal.more » The lower ash content probably reflects scarcity of pyrite. The reason for the difference in moisture content is unknown. High- and low-sulfur coal are nearly identical in heating value.« less

Estimation of weathering rates and CO2 drawdown based on solute load: Significance of granulites and gneisses dominated weathering in the Kaveri River basin, Southern India

NASA Astrophysics Data System (ADS)

Pattanaik, J. K.; Balakrishnan, S.; Bhutani, R.; Singh, P.

2013-11-01

The solute load of the Kaveri River (South India) and its tributaries draining diverse Precambrian terrains during pre-monsoon and monsoon periods was determined. Using average annual flow, total drainage area and atmospheric input corrected major ion concentrations of these rivers chemical weathering rates, annual fluxes of different ionic species to the ocean and CO2 consumption rates were estimated. Bicarbonate is the most dominant ion (27-79% of anion budget) in all the river samples collected during monsoon period followed by Ca2+, whereas, in case of pre-monsoon water samples Na+ is the most dominant ion (in meq/l). Two approaches were adopted to estimate silicate and carbonate weathering rates in the drainage basin. At Musuri silicate weathering rate (SWR) is 9.44 ± 0.29 tons/km2/a and carbonate weathering rate (CWR) is 1.46 ± 0.16 tons/km2/a. More than 90% of the total ionic budget is derived from weathering of silicates in the Kaveri basin. CO2 consumption rate in the basin for silicate weathering FCO2sil is 3.83 ± 0.12 × 105 mol/km2/a (upper limit), which is comparable with the Himalayan rivers at upper reaches. For carbonate weathering (FCO2carb) CO2 consumption rate is 0.15 ± 0.03 × 105 mol/km2/a in the Kaveri basin. The lower limit of CO2 consumption rate corrected for H2SO4 during silicate and carbonate weathering is FCO2sil is 3.24 × 1005 mol/km2/a and FCO2carb 0.13 × 105 mol/km2/a respectively. CO2 sequestered due to silicate weathering in the Kaveri basin is 25.41 (±0.82) × 109 mol/a which represents 0.21 (±0.01)% of global CO2 drawdown. This may be due to tropical climatic condition, high rainfall during both SW and NE monsoon and predominance of silicate rocks in the Kaveri basin.

Revisiting the social cost of carbon

PubMed Central

Nordhaus, William D.

2017-01-01

The social cost of carbon (SCC) is a central concept for understanding and implementing climate change policies. This term represents the economic cost caused by an additional ton of carbon dioxide emissions or its equivalent. The present study presents updated estimates based on a revised DICE model (Dynamic Integrated model of Climate and the Economy). The study estimates that the SCC is $31 per ton of CO2 in 2010 US$ for the current period (2015). For the central case, the real SCC grows at 3% per year over the period to 2050. The paper also compares the estimates with those from other sources. PMID:28143934

40 CFR 98.187 - Records that must be retained.

Code of Federal Regulations, 2013 CFR

2013-07-01

... carbon mass balance procedure is used to determine process CO2 emissions according to the requirements in... subpart (tons). (5) Average carbon content determined and records of the supplier provided information or... of how company records of measurements are used to estimate the carbon input to each smelting furnace...

40 CFR 98.187 - Records that must be retained.

Code of Federal Regulations, 2014 CFR

2014-07-01

... carbon mass balance procedure is used to determine process CO2 emissions according to the requirements in... subpart (tons). (5) Average carbon content determined and records of the supplier provided information or... of how company records of measurements are used to estimate the carbon input to each smelting furnace...

40 CFR 98.187 - Records that must be retained.

Code of Federal Regulations, 2010 CFR

2010-07-01

... carbon mass balance procedure is used to determine process CO2 emissions according to the requirements in... subpart (tons). (5) Average carbon content determined and records of the supplier provided information or... of how company records of measurements are used to estimate the carbon input to each smelting furnace...

40 CFR 98.187 - Records that must be retained.

Code of Federal Regulations, 2012 CFR

2012-07-01

... carbon mass balance procedure is used to determine process CO2 emissions according to the requirements in... subpart (tons). (5) Average carbon content determined and records of the supplier provided information or... of how company records of measurements are used to estimate the carbon input to each smelting furnace...

40 CFR 98.187 - Records that must be retained.

Code of Federal Regulations, 2011 CFR

2011-07-01

... carbon mass balance procedure is used to determine process CO2 emissions according to the requirements in... subpart (tons). (5) Average carbon content determined and records of the supplier provided information or... of how company records of measurements are used to estimate the carbon input to each smelting furnace...

215. Photocopy of photograph, U.S. Army, ca. 1970 (original print ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

215. Photocopy of photograph, U.S. Army, ca. 1970 (original print located at Rocky Mountain Arsenal, Commerce City, Colorado). CLEANING TON CONTAINERS IN BUILDING 1606. - Rocky Mountain Arsenal, Bounded by Ninety-sixth Avenue & Fifty-sixth Avenue, Buckley Road, Quebec Street & Colorado Highway 2, Commerce City, Adams County, CO

40 CFR 98.236 - Data reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... each gas, for all absorbent desiccant dehydrators combined. (5) For well venting for liquids unloading... gas emitted from produced oil sent to atmospheric tanks: (i) For wellhead gas-liquid separator with... atmosphere, expressed in metric tons CO2e for each gas, for all wellhead gas-liquid separators or storage...

40 CFR 98.236 - Data reporting requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... each gas, for all absorbent desiccant dehydrators combined. (5) For well venting for liquids unloading... gas emitted from produced oil sent to atmospheric tanks: (i) For wellhead gas-liquid separator with... atmosphere, expressed in metric tons CO2e for each gas, for all wellhead gas-liquid separators or storage...

40 CFR 98.236 - Data reporting requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... each gas, for all absorbent desiccant dehydrators combined. (5) For well venting for liquids unloading... gas emitted from produced oil sent to atmospheric tanks: (i) For wellhead gas-liquid separator with... atmosphere, expressed in metric tons CO2e for each gas, for all wellhead gas-liquid separators or storage...

40 CFR 98.121 - Reporting threshold.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Reporting threshold. 98.121 Section 98...) MANDATORY GREENHOUSE GAS REPORTING Fluorinated Gas Production § 98.121 Reporting threshold. You must report...). To calculate GHG emissions for comparison to the 25,000 metric ton CO2e per year emission threshold...

Impact on carbon footprint: a life cycle assessment of disposable versus reusable sharps containers in a large US hospital.

PubMed

Grimmond, Terry; Reiner, Sandra

2012-06-01

Hospitals are striving to reduce their greenhouse gas (GHG) emissions. Targeting supply chain points and replacing disposable with reusable items are among recommendations to achieve this. Annually, US hospitals use 35 million disposable (DSC) or reusable sharps containers (RSC) generating GHG in their manufacture, use, and disposal. Using a life cycle assessment we assessed the global warming potential (GWP) of both systems at a large US hospital which replaced DSC with RSC. GHG emissions (CO(2), CH(4), N(2)O) were calculated in metric tons of CO(2) equivalents (MTCO(2)eq). Primary energy input data was used wherever possible and region-specific conversions used to calculate the GWP of each activity. Unit process GHGs were collated into manufacture, transport, washing, and treatment and disposal. The DSC were not recycled nor had recycled content. Chemotherapy DSC were used in both systems. Emission totals were workload-normalized per 100 occupied beds-yr and rate ratio analyzed using Fisher's test with P ≤0.05 and 95% confidence level. With RSC, the hospital reduced its annual GWP by 127 MTCO(2)eq (-83.5%) and diverted 30.9 tons of plastic and 5.0 tons of cardboard from landfill. Using RSC reduced the number of containers manufactured from 34,396 DSC annually to 1844 RSC in year one only. The study indicates sharps containment GWP in US hospitals totals 100,000 MTCO(2)eq and if RSC were used nationally the figure could fall by 64,000 MTCO(2)eq which, whilst only a fraction of total hospital GWP, is a positive, sustainable step.

Characterization of spent nickel-metal hydride batteries and a preliminary economic evaluation of the recovery processes.

PubMed

Lin, Sheng-Lun; Huang, Kuo-Lin; Wang, I-Ching; Chou, I-Cheng; Kuo, Yi-Ming; Hung, Chung-Hsien; Lin, Chitsan

2016-03-01

Valuable metal materials can be recovered from spent nickel-metal hydride (NiMH) batteries. However, little attention has been paid to the metal compositions of individual components of NiMH batteries, although this is important for the selection of the appropriate recycling process. In this study, NiMH batteries were manually disassembled to identify the components and to characterize the metals in each of these. A preliminary economic analysis was also conducted to evaluate the recovery of valuable metals from spent NiMH batteries using thermal melting versus simple mechanical separation. The results of this study show that metallic components account for more than 60% of battery weight. The contents of Ni, Fe, Co, and rare earth elements (REEs) (i.e., valuable metals of interest for recovery) in a single battery were 17.9%, 15.4%, 4.41%, and 17.3%, respectively. Most of the Fe was in the battery components of the steel cathode collector, cathode cap, and anode metal grid, while Ni (>90%) and Co (>90%) were mainly in the electrode active materials (anode and cathode metal powders). About 1.88 g of REEs (Ce, La, and Y) could be obtained from one spent NiMH battery. The estimated profits from recovering valuable metals from spent NiMH batteries by using thermal melting and mechanical processes are 2,329 and 2,531 USD/ton, respectively, when including a subsidy of 1,710 USD/ton. The findings of this study are very useful for further research related to technical and economic evaluations of the recovery of valuable metals from spent NiMH batteries. The spent nickel-metal hydride (NiMH) batteries were manually disassembled and their components were identified. The metals account for more than 60% of battery weight, when Ni, Fe, Co, and rare earth elements (REEs) were 17.9%, 15.4%, 4.41%, and 17.3%, respectively, in a single battery. The estimated profits of recovering valuable metals from NiMH batteries by using thermal melting and mechanical processing are 2,329 and 2,531 USD/ton, respectively, when including a subsidy of 1,710 USD/ton. These findings are very useful to develop or select the recovery methods of valuable metals from spent NiMH batteries.

Remediation of uranium in-situ leaching area at Straz Pod Ralskem, Czech Republic

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vokal, Vojtech; Muzak, Jiri; Ekert, Vladimir

2013-07-01

A large-scale development in exploration and production of uranium ores in the Czech Republic was done in the 2nd half of the 20. century. Many uranium deposits were discovered in the territory of the Czech Republic. One of the most considerable deposits in the Czech Republic is the site Hamr na Jezere - Straz pod Ralskem where both mining methods - the underground mining and the acidic in-situ leaching - were used. The extensive production of uranium led to widespread environmental impacts and contamination of ground waters. Over the period of 'chemical' leaching of uranium (ca. 32 years), a totalmore » of more than 4 million tons of sulphuric acid and other chemicals have been injected into the ground. Most of the products (approx. 99.5 %) of the acids reactions with the rocks are located in the Cenomanian aquifer. The contamination of Cenomanian aquifer covers the area larger then 27 km{sup 2}. The influenced volume of groundwater is more than 380 million m{sup 3}. The total amount of dissolved SO{sub 4}{sup 2-} is about 3.6 million tons. After 1990 a large-scale environmental program was established and the Czech government decided to liquidate the ISL Mine and start the remediation in 1996. The remediation consists of contaminated groundwater pumping, removing of the contaminants and discharging or reinjection of treated water. Nowadays four main remedial technological installations with sufficient capacity for reaching of the target values of remedial parameters in 2037 are used - the 'Station for Acid Solutions Liquidation No. One', the 'Mother liquor reprocessing' station, the 'Neutralization and Decontamination Station NDS 6' and the 'Neutralization and Decontamination Station NDS 10'. It is expected that the amount of withdrawn contaminants will vary from 80 000 to 120 000 tons per year. Total costs of all remediation activities are expected to be in excess of 2 billion EUR. (authors)« less

A new MODIS based approach for gas flared volumes estimation: the case of the Val d'Agri Oil Center (Southern Italy)

NASA Astrophysics Data System (ADS)

Lacava, T.; Faruolo, M.; Coviello, I.; Filizzola, C.; Pergola, N.; Tramutoli, V.

2014-12-01

Gas flaring is one of the most controversial energetic and environmental issues the Earth is facing, moreover contributing to the global warming and climate change. According to the World Bank, each year about 150 Billion Cubic Meter of gas are being flared globally, that is equivalent to the annual gas use of Italy and France combined. Besides, about 400 million tons of CO2 (representing about 1.2% of global CO2 emissions) are added annually into the atmosphere. Efforts to evaluate the impact of flaring on the surrounding environment are hampered by lack of official information on flare locations and volumes. Suitable satellite based techniques could offers a potential solution to this problem through the detection and subsequent mapping of flare locations as well as gas emissions estimation. In this paper a new methodological approach, based on the Robust Satellite Techniques (RST), a multi-temporal scheme of satellite data analysis, was developed to analyze and characterize the flaring activity of the largest Italian gas and oil pre-treatment plant (ENI-COVA) located in Val d'Agri (Basilicata) For this site, located in an anthropized area characterized by a large environmental complexity, flaring emissions are mainly related to emergency conditions (i.e. waste flaring), being the industrial process regulated by strict regional laws. With reference to the peculiar characteristics of COVA flaring, the RST approach was implemented on 13 years of EOS-MODIS (Earth Observing System - Moderate Resolution Imaging Spectroradiometer) infrared data to detect COVA-related thermal anomalies and to develop a regression model for gas flared volume estimation. The methodological approach, the whole processing chain and the preliminarily achieved results will be shown and discussed in this paper. In addition, the possible implementation of the proposed approach on the data acquired by the SUOMI NPP - VIIRS (National Polar-orbiting Partnership - Visible Infrared Imaging Radiometer Suite) and the expected improvements will be also discussed.

CO 2 Hydrogenation Catalysts with Deprotonated Picolinamide Ligands

DOE PAGES

Kanega, Ryoichi; Onishi, Naoya; Szalda, David J.; ...

2017-08-21

In an effort to design concepts for highly active catalysts for the hydrogenation of CO 2 to formate in basic water, we have prepared in this paper several catalysts with picolinic acid, picolinamide, and its derivatives, and we investigated their catalytic activity. The CO 2 hydrogenation catalyst having a 4-hydroxy-N-methylpicolinamidate ligand exhibited excellent activity even under ambient conditions (0.1 MPa, 25 °C) in basic water, exhibiting a TON of 14700, a TOF of 167 h –1, and producing a 0.64 M formate concentration. Finally, its high catalytic activity originates from strong electron donation by the anionic amide moiety in additionmore » to the phenolic O – functionality.« less

The ocean blues. Navigating the course of population growth.

PubMed

Sarkar, D

1996-01-01

Oceans and their role in environmental balance are discussed in this article. Coastal waters within 200 miles from land are identified as providing over half the ocean's total biological productivity and supply of nearly all of the world's fish catch. Almost 3.6 billion people live in coastal areas or within 90 miles of coastal waters, which accounts for about 66% of world population. Coastal land areas account for about 8% of the earth's total land area. 8.3 billion people are expected by 2025 to live in coastal areas. 9 of the 10 largest cities in the world are located on coasts. 7 of the 10 largest cities in the US are coastal cities (54% of the US population or 142 million people). Almost all of the marine pollution is derived from land-based sources, such as sewage, nutrients, sediments, litter, and plastics. Mangroves in coastal waters have been reduced by about 50% to about 90,000 sq. miles worldwide. Global consumption of fish is responsible for depleting fish supplies and the loss of mangroves due to aquaculture of shrimp or other seafood. The US National Fisheries Service is cited for its report that 67 of the 156 fish stocks are overexploited. About 1 billion people, mostly in developing countries, rely on fish as their main food source. If imbalances in demand and supply continue, the rising price of fish and seafood will threaten the lives of about 1 billion or more people. Numerous international and national actions have been taken in order to protect supplies and reduce pollution. Sound resource management practices need to be instituted. Small and large fisheries can begin by reducing the 27 million tons of unintentional fish captures and by converting 29 million tons of fish used for animal feed into food for human consumption. Management of US coastal lands in most coastal states, with the exception of California and Rhode Island, is weak. Maryland has adopted a community-level approach for management of the Chesapeake Bay. Other environmental impacts on oceans are attributed to a weakened ozone layer, which reduces phytoplankton, and to greenhouse effects on sea levels. Phytoplankton is key to supplying oxygen, converting excess carbon dioxide into simple sugars for sustaining life, and supporting aquatic life. Overpopulation has a negative impact on oceans and their life.

Chewing gum--facts and fiction: a review of gum-chewing and oral health.

PubMed

Imfeld, T

1999-01-01

The world market for chewing gum is estimated to be 560,000 tons per year, representing approximately US $5 billion. Some 374 billion pieces of chewing gum are sold worldwide every year, representing 187 billion hours of gum-chewing if each piece of gum is chewed for 30 minutes. Chewing gum can thus be expected to have an influence on oral health. The labeling of sugar-substituted chewing gum as "safe for teeth" or "tooth-friendly" has been proven beneficial to the informed consumer. Such claims are allowed for products having been shown in vivo not to depress plaque pH below 5.7, neither during nor for 30 minutes after the consumption. However, various chewing gum manufacturers have recently begun to make distinct health promotion claims, suggesting, e.g., reparative action or substitution for mechanical hygiene. The aim of this critical review--covering the effects of the physical properties of chewing gum and those of different ingredients both of conventional and of functional chewing gum--is to provide a set of guidelines for the interpretation of such claims and to assist oral health care professionals in counseling patients.

Feasibility of Applying Clean Development Mechanism and GHGs Emission Reductions in the Gold Mining Industry: A Case of Thailand

NASA Astrophysics Data System (ADS)

Kittipongvises, Suthirat

2015-12-01

There is presently overwhelming scientific consensus that global climate change is indeed occurring, and that human activities are the primary driver. An increasingly resource and carbon constrained world will continue to pose formidable challenges to major industries, including mining. Understanding the implications of climate change mitigation for the mining industry, however, remains limited. This paper presents the results of a feasibility study on the implementation of a clean development mechanism and greenhouse gases (GHGs) emission reductions in the gold mining industry. It draws upon and extends the analysis of a case study conducted on gold mining operations in Thailand. The results from the case study indicated that total GHGs emissions by company A were approximately 36,886 tons carbon dioxide equivalents (tCO2e) per annual gold production capacity that meet the eligibility criteria for small-scaled clean development mechanism (CDM) projects. The electrostatic separation process was found to release the lowest amount of GHGs, whereas comminution (i.e. crushing and grinding) generated the highest GHGs emissions. By scope, the emission from purchased electricity (scope 2) is the most significant source. Opportunities for CDM projects implementation in the gold mining sector can be found in employing energy efficiency measures. Through innovation, some technical efficiency and technological development in gold processing (i.e. high pressure grinding rolls (HPGR), vertical roller mills (VRM), gravity pre-concentration and microwave heating technologies) that have the potential to reduce energy use and also lower carbon footprint of the gold mining were further discussed. The evidence reviews found that HPGR and VRM abatement technologies have shown energy and climate benefits as electricity savings and CO2 reduction of about 8-25.93 kWh/ton ore processed and 1.8-26.66 kgCO2/ton ore processed, respectively. Implications for further research and practice were finally raised.

Opportunity for offshore wind to reduce future demand for coal-fired power plants in China with consequent savings in emissions of CO2.

PubMed

Lu, Xi; McElroy, Michael B; Chen, Xinyu; Kang, Chongqing

2014-12-16

Although capacity credits for wind power have been embodied in power systems in the U.S. and Europe, the current planning framework for electricity in China continues to treat wind power as a nondispatchable source with zero contribution to firm capacity. This study adopts a rigorous reliability model for the electric power system evaluating capacity credits that should be recognized for offshore wind resources supplying power demands for Jiangsu, China. Jiangsu is an economic hub located in the Yangtze River delta accounting for 10% of the total electricity consumed in China. Demand for electricity in Jiangsu is projected to increase from 331 TWh in 2009 to 800 TWh by 2030. Given a wind penetration level of 60% for the future additional Jiangsu power supply, wind resources distributed along the offshore region of five coastal provinces in China (Shandong, Jiangsu, Shanghai, Zhejiang, and Fujian) should merit a capacity credit of 12.9%, the fraction of installed wind capacity that should be recognized to displace coal-fired systems without violating the reliability standard. In the high-coal-price scenario, with 60% wind penetration, reductions in CO2 emissions relative to a business as usual reference could be as large as 200.2 million tons of CO2 or 51.8% of the potential addition, with a cost for emissions avoided of $29.0 per ton.

Negative CO2 emissions via subsurface mineral carbonation in fractured peridotite

NASA Astrophysics Data System (ADS)

Kelemen, P. B.; Matter, J.

2014-12-01

Uptake of CO2 from surface water via mineral carbonation in peridotite can be engineered to achieve negative CO2 emissions. Reaction with peridotite, e.g., CO2 + olivine (A), serpentine (B) and brucite (C), forms inert, non-toxic, solid carbonates such as magnesite. Experimental studies show that A can be 80% complete in a few hours with 30 micron powders and elevated P(CO2) [1,2,3]. B is slower, but in natural systems the rate of B+C is significant [4]. Methods for capture of dilute CO2 via mineral carbonation [4,5,6,7] are not well known, though CO2 storage via mineral carbonation has been discussed for decades [8,9]. Where crushed peridotite is available, as in mine tailings, increased air or water flow could enhance CO2 uptake at a reasonable cost [4,5]. Here we focus on enhancing subsurface CO2 uptake from surface water flowing in fractured peridotite, in systems driven by thermal convection such as geothermal power plants. Return of depleted water to the surface would draw down CO2 from the air [6,7]. CO2 uptake from water, rate limited by flow in input and output wells, could exceed 1000 tons CO2/yr [7]. If well costs minus power sales were 0.1M to 1M and each system lasts 10 years this costs < 10 to 100 per ton CO2. As for other CCS methods, upscaling requires infrastructure resembling the oil industry. Uptake of 1 Gt CO2/yr at 1000 t/well/yr requires 1M wells, comparable to the number of producing oil and gas wells in the USA. Subsurface CO2 uptake could first be applied in coastal, sub-seafloor peridotite with onshore drilling. Sub-seafloor peridotite is extensive off Oman, New Caledonia and Papua New Guinea, with smaller amounts off Spain, Morocco, USA, etc. This would be a regional contribution, used in parallel with other methods elsewhere. To achieve larger scale is conceivable. There is a giant mass of seafloor peridotite along slow-spreading mid-ocean ridges. Could robotic drills enhance CO2 uptake at a reasonable cost, while fabric chimneys transport CO2-depleted water to the sea surface? Does anyone know James Cameron's phone number? [1] O'Connor et al DOE Report 04 [2] Chizmeshya et al DOE Report 07 [3] Gadikota et al Phys Chem Chem Phys 14 [4] Wilson et al IJGHGC 14 [5] Schuiling & Krijgsman Climate Change 06 [6] Kelemen & Matter PNAS 08 [7] Kelemen et al AREPS 11 [8] Seifritz Nature 90 [9] Lackner et al Energy 95

Enabling the Billion-Ton Bioeconomy

ScienceCinema

Baumes, Harry; Csonka, Steve; Sayre, Richard; Steen, Eric; Kenney, Kevin; Labbe, Nicole

2018-01-16

The United States is rich in non-food ‎biomass that can fuel the development of a thriving ‎bioeconomy where renewable and sustainable resources power cars and planes instead of petroleum. The ‎transportation and aviation industry is actively seeking ways to reduce its carbon footprint by powering planes with solid municipal waste, woody biomass, purpose-grown crops, and ‎algae. Watch this short video to learn how biomass is being used to make our country greener, provide new employment opportunities, and reduce our dependence on foreign oil.

China’s Expansion into the Middle East and Its Effects on U.S. Foreign Policy

DTIC Science & Technology

2007-03-01

and gas assessment report assessed that China has more than 102 billion tons of oil resources, only 26% of onshore oil have been verified which...Reserves Source: Oil and Gas Journal Volume 101.49 December 22, 2003, pp. 43-4732 D. U.S. STANCE REGARDING CHINESE ENERGY SECURITY POLICIES There have...Tu rke y So uth A fric a Ta iw an Gr ee ce Reporting Country B ar re ls (b bl )/D ay 2003 2004 2005 Table 4. Top Ten Iranian Crude Oil Export

Excessive red and processed meat intake: relations with health and environment in Brazil.

PubMed

Carvalho, Aline Martins de; Selem, Soraya Sant'ana de Castro; Miranda, Andreia Machado; Marchioni, Dirce Maria

2016-06-01

The aims of the present study were to verify the proportion of population that consumed more red and processed meat than the World Cancer Research Fund (WCRF) dietary recommendation, to estimate the environmental impact of beef intake and the possible reduction of greenhouse gas emissions if the dietary recommendation was followed. We used the largest, cross-sectional, population-based survey entitled the National Dietary Survey (34 003 participants aged 10-104 years). The usual meat intake was obtained by two food records completed on 2 non-consecutive days. The usual intake was estimated by the multiple source method. The environmental impact was analysed according to estimates of CO2 equivalent emissions from beef intake as a proxy for beef production in Brazil. The red and processed meat intake mean was 88 g/d. More than 80 % of the population consumed more red and processed meat than the WCRF recommendation. Beef was the type of meat most consumed, accounting to almost 50 %. Each person contributed 1005 kg of CO2 equivalents from beef intake in 2008, the same quantity of CO2 produced if a car travelled a distance between the extreme north and south of Brazil (5370 km). The entire Brazilian population contributed more than 191 million tons of CO2 equivalents, which could have been reduced to more than 131 million tons if the dietary recommendation was followed. The present study shows that the magnitude of the excessive red and processed meat intake in Brazil can impact on health and the environment, pointing to the urgency of promoting a sustainable diet.

Assessment of Environmental Impacts of Limestone Quarrying Operations in Thailand

NASA Astrophysics Data System (ADS)

Kittipongvises, Suthirat

2017-11-01

Environmental impacts of the mineral extraction have been a public concern. Presently, there is widespread global interest in the area of mining and its sustainability that focused on the need to shift mining industry to a more sustainable framework. The aim of this study was to systematically assess all possible environmental and climate change related impacts of the limestone quarrying operation in Thailand. By considering the life cycle assessment method, the production processes were divided into three phases: raw material extraction, transportation, and comminution. Both IMPACT 2002+ and the Greenhouse Gas Protocol methods were used. Results of IMPACT 2002+ analysis showed that per 1 ton crushed limestone rock production, the total depletion of resource and GHGs emissions were 79.6 MJ and 2.76 kg CO2 eq., respectively. Regarding to the four damage categories, `resources' and `climate change' categories were the two greatest environmental impacts of the limestone rock production. Diesel fuel and electricity consumption in the mining processes were the main causes of those impacts. For climate change, the unit of CO2 eq. was expressed to quantify the total GHGs emissions. Estimated result was about 3.13 kg CO2 eq. per ton limestone rock product. The results obtained by the Greenhouse Gas Protocol were also similar to IMPACT 2002+ method. Electrical energy consumption was considered as the main driver of GHGs, accounting for approximately 46.8 % of total fossil fuel CO2 emissions. A final point should be noted that data uncertainties in environmental assessment over the complete life cycle of limestone quarrying operation have to be carefully considered.

CO2 condensation and the climate of early Mars.

PubMed

Kasting, J F

1991-01-01

A one-dimensional, radiative-convective climate model was used to reexamine the question of whether early Mars could have been kept warm by the greenhouse effect of a dense, CO2 atmosphere. The new model differs from previous models by considering the influence of CO2 clouds on the convective lapse rate and on the the planetary radiation budget. Condensation of CO2 decreases the lapse rate and, hence, reduces the magnitude of the greenhouse effect. This phenomenon becomes increasingly important at low solar luminosities and may preclude warm (0 degree C), globally averaged surface temperatures prior to approximately 2 billion years ago unless other greenhouse gases were present in addition to CO2 and H2O. Alternative mechanisms for warming early Mars and explaining channel formation are discussed.

Early stages in the evolution of the atmosphere and climate on the Earth-group planets

NASA Technical Reports Server (NTRS)

Moroz, V. I.; Mukhin, L. M.

1977-01-01

The early evolution of the atmospheres and climate of the Earth, Mars and Venus is discussed, based on a concept of common initial conditions and main processes (besides known differences in chemical composition and outgassing rate). It is concluded that: (1) liquid water appeared on the surface of the earth in the first few hundred million years; the average surface temperature was near the melting point for about the first two eons; CO2 was the main component of the atmosphere in the first 100-500 million years; (2) much more temperate outgassing and low solar heating led to the much later appearance of liquid water on the Martian surface, only one to two billion years ago; the Martian era of rivers, relatively dense atmosphere and warm climate ended as a result of irreversible chemical bonding of CO2 by Urey equilibrium processes; (3) a great lack of water in the primordial material of Venus is proposed; liquid water never was present on the surface of the planet, and there was practically no chemical bonding of CO2; the surface temperature was over 600 K four billion years ago.

System Assessment of Carbon Dioxide Used as Gas Oxidant and Coolant in Vanadium-Extraction Converter

NASA Astrophysics Data System (ADS)

Du, Wei Tong; Wang, Yu; Liang, Xiao Ping

2017-10-01

With the aim of reducing carbon dioxide (CO2) emissions and of using waste resources in steel plants, the use of CO2 as a gas oxidant and coolant in the converter to increase productivity and energy efficiency was investigated in this study. Experiments were performed in combination with thermodynamic theory on vanadium-extraction with CO2 and oxygen (O2) mixed injections. The results indicate that the temperature of the hot metal bath decreased as the amount of CO2 introduced into O2 increased. At an injection of 85 vol.% O2 and 15 vol.% CO2, approximately 12% of additional carbon was retained in the hot metal. Moreover, the content of vanadium trioxide in the slag was higher. In addition, the O2 consumption per ton of hot metal was reduced by 8.5% and additional chemical energy was recovered by the controlled injection of CO2 into the converter. Therefore, using CO2 as a gas coolant was conducive to vanadium extraction, and O2 consumption was reduced.

Conditions to generate Steam Fog Occurred around the Chungju Lake in the South Korea

NASA Astrophysics Data System (ADS)

Byungwoo, J.

2017-12-01

We have collected the field observation data of the steam fog occurred around the Chungju Lake in the South Korea for 3 years(2014 2016) and analyzed conditions in which the steam fog occurred. The Chungju Lake is an artificial lake made by the Chungju Dam with a water storage of 2.7 billion tons, which is the second largest in South Korea. The Chungju Dam have discharged water of the average 2.2 million tons downstream to produce electricity per day. The drainage water heats downstream of the Chungju dam and the air above water surface of downstream of that. When the warm, humid air above the downstream water mixed with cold air mass, it caused "steam fog" around the downstream of Chungju lake regardless of amount of the discharged water. The condition that promote the generation of steam fog in autumn and winter is as follows: (1) cloudless night with light winds below 1.5 m/s. (2) The differences between the temperature of discharged water from the Chungju Dam and the air temperature above the discharged water varied from 3° to 15° in autumn, from 15° to 20° in winter respectively. (3) When stream fog was generated, sensible heat flux ranged in autumn from 5 to 15 W/m2, in winter from 15 to 20 W/m2 respectively. Latent heat flux ranged in autumn from 15 to 20 W/m2, in winter from 10 to 15 W/m2 respectively.

40 CFR Table A-5 to Subpart A of... - Supplier Category List for § 98.2(a)(4)

Code of Federal Regulations, 2013 CFR

2013-07-01

... crude oil. (B) Importers of an annual quantity of petroleum products and natural gas liquids that is... natural gas liquids that is equivalent to 25,000 metric tons CO2e or more. Natural gas and natural gas liquids suppliers (subpart NN): (A) All fractionators. (B) Local natural gas distribution companies that...