DOE Office of Scientific and Technical Information (OSTI.GOV)

Klein, Stefanie; Sommer, Anja; Distel, Luitpold V.R.

Highlights: Black-Right-Pointing-Pointer Ultrasmall citrate-coated SPIONs with {gamma}Fe{sub 2}O{sub 3} and Fe{sub 3}O{sub 4} structure were prepared. Black-Right-Pointing-Pointer SPIONs uptaken by MCF-7 cells increase the ROS production for about 240%. Black-Right-Pointing-Pointer The SPION induced ROS production is due to released iron ions and catalytically active surfaces. Black-Right-Pointing-Pointer Released iron ions and SPION surfaces initiate the Fenton and Haber-Weiss reaction. Black-Right-Pointing-Pointer X-ray irradiation of internalized SPIONs leads to an increase of catalytically active surfaces. -- Abstract: Internalization of citrate-coated and uncoated superparamagnetic iron oxide nanoparticles by human breast cancer (MCF-7) cells was verified by transmission electron microscopy imaging. Cytotoxicity studies employing metabolicmore » and trypan blue assays manifested their excellent biocompatibility. The production of reactive oxygen species in iron oxide nanoparticle loaded MCF-7 cells was explained to originate from both, the release of iron ions and their catalytically active surfaces. Both initiate the Fenton and Haber-Weiss reaction. Additional oxidative stress caused by X-ray irradiation of MCF-7 cells was attributed to the increase of catalytically active iron oxide nanoparticle surfaces.« less

Metal-assisted chemical etching using sputtered gold: a simple route to black silicon

NASA Astrophysics Data System (ADS)

Kurek, Agnieszka; Barry, Seán T.

2011-08-01

We report an accessible and simple method of producing 'black silicon' with aspect ratios as high as 8 using common laboratory equipment. Gold was sputtered to a thickness of 8 nm using a low-vacuum sputter coater. The structures were etched into silicon substrates using an aqueous H2O2/HF solution, and the gold was then removed using aqua regia. Ultrasonication was necessary to produce columnar structures, and an etch time of 24 min gave a velvety, non-reflective surface. The surface features after 24 min etching were uniformly microstructured over an area of square centimetres.

Speckle lithography for fabricating Gaussian, quasi-random 2D structures and black silicon structures.

PubMed

Bingi, Jayachandra; Murukeshan, Vadakke Matham

2015-12-18

Laser speckle pattern is a granular structure formed due to random coherent wavelet interference and generally considered as noise in optical systems including photolithography. Contrary to this, in this paper, we use the speckle pattern to generate predictable and controlled Gaussian random structures and quasi-random structures photo-lithographically. The random structures made using this proposed speckle lithography technique are quantified based on speckle statistics, radial distribution function (RDF) and fast Fourier transform (FFT). The control over the speckle size, density and speckle clustering facilitates the successful fabrication of black silicon with different surface structures. The controllability and tunability of randomness makes this technique a robust method for fabricating predictable 2D Gaussian random structures and black silicon structures. These structures can enhance the light trapping significantly in solar cells and hence enable improved energy harvesting. Further, this technique can enable efficient fabrication of disordered photonic structures and random media based devices.

Optimization of the Surface Structure on Black Silicon for Surface Passivation

NASA Astrophysics Data System (ADS)

Jia, Xiaojie; Zhou, Chunlan; Wang, Wenjing

2017-03-01

Black silicon shows excellent anti-reflection and thus is extremely useful for photovoltaic applications. However, its high surface recombination velocity limits the efficiency of solar cells. In this paper, the effective minority carrier lifetime of black silicon is improved by optimizing metal-catalyzed chemical etching (MCCE) method, using an Al2O3 thin film deposited by atomic layer deposition (ALD) as a passivation layer. Using the spray method to eliminate the impact on the rear side, single-side black silicon was obtained on n-type solar grade silicon wafers. Post-etch treatment with NH4OH/H2O2/H2O mixed solution not only smoothes the surface but also increases the effective minority lifetime from 161 μs of as-prepared wafer to 333 μs after cleaning. Moreover, adding illumination during the etching process results in an improvement in both the numerical value and the uniformity of the effective minority carrier lifetime.

Equilibrium configurations of perfect fluid orbiting Schwarzschild-de Sitter black holes

NASA Astrophysics Data System (ADS)

Stuchlík, Z.; Slaný, P.; Hledík, S.

2000-11-01

The hydrodynamical structure of perfect fluid orbiting Schwarzschild-de Sitter black holes is investigated for configurations with uniform distribution of angular momentum density. It is shown that in the black-hole backgrounds admitting the existence of stable circular geodesics, closed equipotential surfaces with a cusp, allowing the existence of toroidal accretion disks, can exist. Two surfaces with a cusp exist for the angular momentum density smaller than the one corresponding to marginally bound circular geodesics; the equipotential surface corresponding to the marginally bound circular orbit has just two cusps. The outer cusp is located nearby the static radius where the gravitational attraction is compensated by the cosmological repulsion. Therefore, due to the presence of a repulsive cosmological constant, the outflow from thick accretion disks can be driven by the same mechanism as the accretion onto the black hole. Moreover, properties of open equipotential surfaces in vicinity of the axis of rotation suggest a strong collimation effects of the repulsive cosmological constant acting on jets produced by the accretion disks.

Optimization of the Surface Structure on Black Silicon for Surface Passivation.

PubMed

Jia, Xiaojie; Zhou, Chunlan; Wang, Wenjing

2017-12-01

Black silicon shows excellent anti-reflection and thus is extremely useful for photovoltaic applications. However, its high surface recombination velocity limits the efficiency of solar cells. In this paper, the effective minority carrier lifetime of black silicon is improved by optimizing metal-catalyzed chemical etching (MCCE) method, using an Al 2 O 3 thin film deposited by atomic layer deposition (ALD) as a passivation layer. Using the spray method to eliminate the impact on the rear side, single-side black silicon was obtained on n-type solar grade silicon wafers. Post-etch treatment with NH 4 OH/H 2 O 2 /H 2 O mixed solution not only smoothes the surface but also increases the effective minority lifetime from 161 μs of as-prepared wafer to 333 μs after cleaning. Moreover, adding illumination during the etching process results in an improvement in both the numerical value and the uniformity of the effective minority carrier lifetime.

Functionalization of multi-walled carbon nanotubes by epoxide ring-opening polymerization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jin Fanlong; Rhee, Kyong Yop; Park, Soo-Jin, E-mail: sjpark@inha.ac.kr

2011-12-15

In this study, covalent functionalization of carbon nanotubes (CNTs) was accomplished by surface-initiated epoxide ring-opening polymerization. FT-IR spectra showed that polyether and epoxide group covalently attached to the sidewalls of CNTs. TGA results indicated that the polyether was successfully grown from the CNT surface, with the final products having a polymer weight percentage of ca. 14-74 wt%. The O/C ratio of CNTs increased significantly from 5.1% to 29.8% after surface functionalization of CNTs. SEM and TEM images of functionalized CNTs exhibited that the tubes were enwrapped by polymer chains with thickness of several nanometers, forming core-shell structures with CNTs atmore » the center. - Graphical abstract: Functionalized CNTs were enwrapped by polymer chains with thickness of several nanometers, forming core-shell structures with CNTs at the center. Highlights: Black-Right-Pointing-Pointer CNTs were functionalized by epoxide ring-opening polymerization. Black-Right-Pointing-Pointer Polyether and epoxide group covalently attached to the sidewalls of CNTs. Black-Right-Pointing-Pointer Functionalized CNTs have a polymer weight percentage of ca. 14-74 wt%. Black-Right-Pointing-Pointer Functionalized CNTs were enwrapped by polymer chains with thickness of several nanometers.« less

Analysis of Black Bearing Balls from a Space Shuttle Body Flap Actuator

NASA Technical Reports Server (NTRS)

Sovinski, Marjorie F.; Street, Kenneth W.

2005-01-01

A significantly deteriorated ball bearing mechanism from a body flap actuator on Space Shuttle OV-103 was disassembled and the balls submitted for analysis in conjunction with Return to Flight activities. The OV-103 balls, referred to as the "black balls", were subjected to X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FT-IR) and Raman micro spectroscopy, surface profilometry, and optical and electron microscopy. The spectroscopic results in combination with microscopy analysis allowed a determination of the lubricant degradation pathway. The chemical attack mechanism does not adequately explain the unique visual appearance of the black balls. Numerous efforts have unsuccessfully focused on duplication of the phenomena causing this unique surface structure and appearance of the black balls. Further detail will be presented supporting these conclusions along with plausible explanations of the unique black appearance to the balls.

Feather microstructure of the black-billed magpie (Pica pica sericea) and jungle crow (Corvus macrorhynchos).

PubMed

Lee, Eunok; Lee, Hang; Kimura, Junpei; Sugita, Shoei

2010-08-01

The jungle crow (Corvus macrorhynchos) distribution stretches from eastern Eurasia continent to southeastern Asia. The distribution of the black-billed magpie (Pica pica sericea) stretches from Korea and China to the Kyushu area in Japan. They are both in the Family, Corvidae, and have iridescent feather colors, but the iridescent feather color of the black-billed magpie is more remarkable than that of the jungle crow. We observed the feather microstructure of these birds using electron microscope. On the barbules surface, the barbules twist and prong between the jungle crow and black-billed magpie were not similar. In the barbules cross section, the black-billed magpie showed a complex structure of melanin granules, the jungle crow showed a simple structure of melanin granules.

Tailoring the morphology of raspberry-like carbon black/polystyrene composite microspheres for fabricating superhydrophobic surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bao, Yubin; Li, Qiuying, E-mail: liqy@ecust.edu.cn; Shanghai Key Laboratory Polymeric Materials

In our previous report, raspberry-like carbon black/polystyrene (CB/PS) composite microsphere was prepared through heterocoagulation process. Based on the previous study, in the present work, the morphology of raspberry-like CB/PS particle is tailored through adjusting the polarity and the concentration ratio of CB/PS colloidal suspension with the purpose to prepare particulate film for the fabrication of superhydrophobic surface. Scanning electron microscope (SEM) confirms the morphology of raspberry-like particle and the coverage of CB. Rough surfaces fabricated by raspberry-like particles with proper morphology are observed by SEM and clear evidence of superhydrophobic surface is shown. The structure of raspberry-like particle is analyzedmore » by atom force microscope. The proposed relationship between the hydrophobicity and the structure of CB aggregates on the surface of PS microsphere is discussed in details.« less

Bulk and surface structural investigations of diesel engine soot and carbon black.

PubMed

Müller, J-O; Su, D S; Wild, U; Schlögl, R

2007-08-14

The microstructure and electronic structure of environmentally relevant carbons such as Euro IV heavy duty diesel engine soot, soot from a black smoking diesel engine, spark discharge soot as model aerosol, commercial furnace soot and lamp black are investigated by transmission electron microscopy, electron energy-loss spectroscopy and X-ray photoelectron spectroscopy. The materials exhibit differences in the predominant bonding, which influences microstructure as well as surface functionalization. These chemical and physical properties depend on the formation history of the investigated carbonaceous materials. In this work, a correlation of the microstructure of the samples to the predominant bonding and incorporation of oxygen into the carbons is obtained. It is shown that a high amount of defects and the deviation of the carbons from a perfect graphitic structure results in a increased incorporation of oxygen and hydrogen. A correlation between the length and curvature of graphene layers with the bonding state of carbon atoms and incorporation of oxygen and hydrogen is established.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hou, Kun; Gao, Ziwei, E-mail: zwgao@snnu.edu.cn; Da, Min

Highlights: Black-Right-Pointing-Pointer Highly oriented and well-defined ZnO urchin-like crystals were successfully fabricated by a facile and effective hydrotherm method. Black-Right-Pointing-Pointer Polyvinylpyrrolidone- and hydrogen peroxide-assisted synthesis of ZnO could optimize its crystalline quality and the obtained ZnO have smooth surface, radial growth of morphology, obvious crystal edges and decreased defects. Black-Right-Pointing-Pointer The physicochemical properties of samples were studied by analysis of its structure, morphology, surface and optical properties. Black-Right-Pointing-Pointer This study represented a multistep mechanism based on [Zn(OH){sub 4}]{sup 2-} growth units about formation such urchin-like structure. -- Abstract: The urchin-like ZnO microcrystals with high crystallinity decomposed from [Zn(OH){sub 4}]{sup 2-}more » directly were obtained via a hydrothermal method. The morphology, particle size, crystalline structure and fluorescence of the as-prepared ZnO were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and photoluminescence (PL) analyses. The results demonstrated that the urchin-like ZnO crystals with wurtzite structure had a narrow distribution in size, which could be adjusted in the range of 30-80 {mu}m by varying reaction time. Broad visible light emission peak was also observed in the PL spectra of the synthesized ZnO products. A multistep growth process about how to form such a structure was proposed.« less

Black Sea thermohaline properties: Long‐term trends and variations

PubMed Central

Stips, A.; Garcia‐Gorriz, E.; Macias Moy, D.

2017-01-01

Abstract The current knowledge about spatial and temporal dynamics of the Black Sea's thermohaline structure is incomplete because of missing data and sparse distribution of existing measurements in space and time. This study presents 56 year continuous simulations of the Black Sea's hydrodynamics using the 3D General Estuarine Transport Model (GETM), without incorporating any relaxation toward climatological or observational data fields. This property of the model allows us to estimate independent temporal trends, in addition to resolving the spatial structure. The simulations suggest that the intermediate layer temperature is characterized by a weak positive trend (warming), whereas the surface temperature does not show a clear linear trend. Different salinity trends have been established at the surface (negative), upper (weaker negative) and main halocline (positive). Three distinct dynamic periods are identified (1960–1970, 1970–1995, 1995–2015), which exhibit pronounced changes in the Black Sea's thermohaline properties and basin circulation. Strengthening of the main cyclonic circulation, accompanied by intensification of the mesoscale anticyclonic eddy formation is found. Both events strongly affect the sea surface salinity but contribute in opposing directions. Specifically, strong composite large‐scale circulation leads to an increase in sea surface salinity, while enhanced formation of mesoscale anticyclones decreases it. Salinity evolution with time is thus the result of the competition of these two opposing yet interdependent processes. PMID:28989833

About complex refractive index of black Si

NASA Astrophysics Data System (ADS)

Pinčík, Emil; Brunner, Robert; Kobayashi, Hikaru; Mikula, Milan

2017-12-01

The paper deals with the complex refractive index in the IR light region of two types of samples (i) as prepared black silicon, and (ii) thermally oxidized black silicon (BSi) nano-crystalline specimens produced both by the surface structure chemical transfer method using catalytic Ag evaporated spots (as prepared sample) and by the catalytic Pt catalytic mesh (thermally oxidized sample). We present, compare, and discuss the values of the IR complex refractive index obtained by calculation using the Kramers-Krönig transformation. Results indicate that small differences between optical properties of as prepared black Si and thermally oxidized BSi are given by: (i) - oxidation procedure, (ii) - thickness of the formed black Si layer, mainly, not by utilization of different catalytic metals, and by iii) the different thickness. Contamination of the surface by different catalytic metals contributes almost equally to the calculated values of the corresponding complex refractive index.

Speckle lithography for fabricating Gaussian, quasi-random 2D structures and black silicon structures

PubMed Central

Bingi, Jayachandra; Murukeshan, Vadakke Matham

2015-01-01

Laser speckle pattern is a granular structure formed due to random coherent wavelet interference and generally considered as noise in optical systems including photolithography. Contrary to this, in this paper, we use the speckle pattern to generate predictable and controlled Gaussian random structures and quasi-random structures photo-lithographically. The random structures made using this proposed speckle lithography technique are quantified based on speckle statistics, radial distribution function (RDF) and fast Fourier transform (FFT). The control over the speckle size, density and speckle clustering facilitates the successful fabrication of black silicon with different surface structures. The controllability and tunability of randomness makes this technique a robust method for fabricating predictable 2D Gaussian random structures and black silicon structures. These structures can enhance the light trapping significantly in solar cells and hence enable improved energy harvesting. Further, this technique can enable efficient fabrication of disordered photonic structures and random media based devices. PMID:26679513

Bio-Inspired Bright Structurally Colored Colloidal Amorphous Array Enhanced by Controlling Thickness and Black Background.

PubMed

Iwata, Masanori; Teshima, Midori; Seki, Takahiro; Yoshioka, Shinya; Takeoka, Yukikazu

2017-07-01

Inspired by Steller's jay, which displays angle-independent structural colors, angle-independent structurally colored materials are created, which are composed of amorphous arrays of submicrometer-sized fine spherical silica colloidal particles. When the colloidal amorphous arrays are thick, they do not appear colorful but almost white. However, the saturation of the structural color can be increased by (i) appropriately controlling the thickness of the array and (ii) placing the black background substrate. This is similar in the case of the blue feather of Steller's jay. Based on the knowledge gained through the biomimicry of structural colored materials, colloidal amorphous arrays on the surface of a black particle as the core particle are also prepared as colorful photonic pigments. Moreover, a structural color on-off system is successfully built by controlling the background brightness of the colloidal amorphous arrays. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Structure and Formation Mechanism of Black TiO 2 Nanoparticles

DOE PAGES

Tian, Mengkun; Mahjouri-Samani, Masoud; Eres, Gyula; ...

2015-10-27

The remarkable properties of black TiO 2 are due to its disordered surface shell surrounding a crystalline core. However, the chemical composition and the atomic and electronic structure of the disordered shell and its relationship to the core remain poorly understood. Using advanced transmission electron microscopy methods, we show that the outermost layer of black TiO 2 nanoparticles consists of a disordered Ti 2O 3 shell. The measurements show a transition region that connects the disordered Ti 2O 3 shell to the perfect rutile core consisting first of four to five monolayers of defective rutile, containing clearly visible Ti interstitialmore » atoms, followed by an ordered reconstruction layer of Ti interstitial atoms. Our data suggest that this reconstructed layer presents a template on which the disordered Ti 2O 3 layers form by interstitial diffusion of Ti ions. In contrast to recent reports that attribute TiO 2 band-gap narrowing to the synergistic action of oxygen vacancies and surface disorder of nonspecific origin, our results point to Ti 2O 3, which is a narrow-band-gap semiconductor. In conclusion, as a stoichiometric compound of the lower oxidation state Ti 3+ it is expected to be a more robust atomic structure than oxygen-deficient TiO 2 for preserving and stabilizing Ti 3+ surface species that are the key to the enhanced photocatalytic activity of black TiO 2.« less

Enhanced optical absorbance and fabrication of periodic arrays on nickel surface using nanosecond laser

NASA Astrophysics Data System (ADS)

Fu, Jinxiang; Liang, Hao; Zhang, Jingyuan; Wang, Yibo; Liu, Yannan; Zhang, Zhiyan; Lin, Xuechun

2017-04-01

A hundred-nanosecond pulsed laser was employed to structure the nickel surface. The effects of laser spatial filling interval and laser scanning speed on the optical absorbance capacity and morphologies on the nickel surface were experimentally investigated. The black nickel surface covered with dense micro/nanostructured broccoli-like clusters with strong light trapping capacity ranging from the UV to the near IR was produced at a high laser scanning speed up to v=100 mm/s. The absorbance of the black nickel is as high as 98% in the UV range of 200-400 nm, more than 97% in the visible spectrum, ranging from 400 to 800 nm, and over 90% in the IR between 800 and 2000 nm. In addition, when the nickel surface was irradiated in two-dimensional crossing scans by laser with different processing parameters, self-organized and shape-controllable structures of three-dimensional (3D) periodic arrays can be fabricated. Compared with ultrafast laser systems previously used for such processing, the nanosecond fiber laser used in this work is more cost-effective, compact and allows higher processing rates. This nickel surface structured technique may be applicable in optoelectronics, batteries industry, solar/wave absorbers, and wettability materials.

The Potential Role Played by the Fullerene-Like Structures of Interstellar Carbon Dust in the Formation of Molecular Hydrogen in Space

NASA Astrophysics Data System (ADS)

Cataldo, Franco; Iglesias-Groth, Susana

After a general introduction to the problem of formation of molecular hydrogen from atomic hydrogen in the interstellar medium and in the dense molecular clouds in particular, and after the explanation of the key role played by the surfaces on this process, it is proposed that the most suitable carbon surface for the formation of molecular hydrogen (from the radiative association process of atomic hydrogen) can be represented by carbon black rather than by graphite. Furthermore, it is proposed that the fullerene-like structures present in the carbon black graphene sheets are the reaction sites where molecular hydrogen may be formed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pariona, Moises Meza, E-mail: mmpariona@uepg.br; Teleginski, Viviane; Santos, Kelly dos

Laser beam welding has recently been incorporated into the fabrication process of aircraft and automobile structures. Surface roughness is an important parameter of product quality that strongly affects the performance of mechanical parts, as well as production costs. This parameter influences the mechanical properties such as fatigue behavior, corrosion resistance, creep life, etc., and other functional characteristics such as friction, wear, light reflection, heat transmission, lubrification, electrical conductivity, etc. The effects of laser surface remelting (LSR) on the morphology of Al-Fe aerospace alloys were examined before and after surface treatments, using optical microscopy (OM), scanning electron microscopy (SEM), low-angle X-raymore » diffraction (LA-XRD), atomic force microscopy (AFM), microhardness measurements (Vickers hardness), and cyclic voltammetry. This analysis was performed on both laser-treated and untreated sanded surfaces, revealing significant differences. The LA-XRD analysis revealed the presence of alumina, simple metals and metastable intermetallic phases, which considerably improved the microhardness of laser-remelted surfaces. The morphology produced by laser surface remelting enhanced the microstructure of the Al-Fe alloys by reducing their roughness and increasing their hardness. The treated surfaces showed passivity and stability characteristics in the electrolytic medium employed in this study. - Highlights: Black-Right-Pointing-Pointer The samples laser-treated and untreated showed significant differences. Black-Right-Pointing-Pointer The La-XRD revealed the presence of alumina in Al-1.5 wt.% Fe. Black-Right-Pointing-Pointer The laser-treated reducing the roughness and increasing the hardness. Black-Right-Pointing-Pointer The laser-treated surfaces showed characteristic passive in the electrolytic medium. Black-Right-Pointing-Pointer The laser-treated is a promising technique for applications technological.« less

Optoelectronic properties of Black-Silicon generated through inductively coupled plasma (ICP) processing for crystalline silicon solar cells

NASA Astrophysics Data System (ADS)

Hirsch, Jens; Gaudig, Maria; Bernhard, Norbert; Lausch, Dominik

2016-06-01

The optoelectronic properties of maskless inductively coupled plasma (ICP) generated black silicon through SF6 and O2 are analyzed by using reflection measurements, scanning electron microscopy (SEM) and quasi steady state photoconductivity (QSSPC). The results are discussed and compared to capacitively coupled plasma (CCP) and industrial standard wet chemical textures. The ICP process forms parabolic like surface structures in a scale of 500 nm. This surface structure reduces the average hemispherical reflection between 300 and 1120 nm up to 8%. Additionally, the ICP texture shows a weak increase of the hemispherical reflection under tilted angles of incidence up to 60°. Furthermore, we report that the ICP process is independent of the crystal orientation and the surface roughness. This allows the texturing of monocrystalline, multicrystalline and kerf-less wafers using the same parameter set. The ICP generation of black silicon does not apply a self-bias on the silicon sample. Therefore, the silicon sample is exposed to a reduced ion bombardment, which reduces the plasma induced surface damage. This leads to an enhancement of the effective charge carrier lifetime up to 2.5 ms at 1015 cm-3 minority carrier density (MCD) after an atomic layer deposition (ALD) with Al2O3. Since excellent etch results were obtained already after 4 min process time, we conclude that the ICP generation of black silicon is a promising technique to substitute the industrial state of the art wet chemical textures in the solar cell mass production.

Patterns of Canopy and Surface Layer Consumption in a Boreal Forest Fire from Repeat Airborne Lidar

NASA Technical Reports Server (NTRS)

Alonzo, Michael; Morton, Douglas C.; Cook, Bruce D.; Andersen, Hans-Erik; Babcock, Chad; Pattison, Robert

2017-01-01

Fire in the boreal region is the dominant agent of forest disturbance with direct impacts on ecosystem structure, carbon cycling, and global climate. Global and biome-scale impacts are mediated by burn severity, measured as loss of forest canopy and consumption of the soil organic layer. To date, knowledge of the spatial variability in burn severity has been limited by sparse field sampling and moderate resolution satellite data. Here, we used pre- and post-fire airborne lidar data to directly estimate changes in canopy vertical structure and surface elevation for a 2005 boreal forest fire on Alaskas Kenai Peninsula. We found that both canopy and surface losses were strongly linked to pre-fire species composition and exhibited important fine-scale spatial variability at sub-30m resolution. The fractional reduction in canopy volume ranged from 0.61 in lowland black spruce stands to 0.27 in mixed white spruce and broad leaf forest. Residual structure largely reflects standing dead trees, highlighting the influence of pre-fire forest structure on delayed carbon losses from above ground biomass, post-fire albedo, and variability in understory light environments. Median loss of surface elevation was highest in lowland black spruce stands (0.18 m) but much lower in mixed stands (0.02 m), consistent with differences in pre-fire organic layer accumulation. Spatially continuous depth-of-burn estimates from repeat lidar measurements provide novel information to constrain carbon emissions from the surface organic layer and may inform related research on post-fire successional trajectories. Spectral measures of burn severity from Landsat were correlated with canopy (r = 0.76) and surface (r = -0.71) removal in black spruce stands but captured less of the spatial variability in fire effects for mixed stands (canopy r = 0.56, surface r = -0.26), underscoring the difficulty in capturing fire effects in heterogeneous boreal forest landscapes using proxy measures of burn severity from Landsat.

Patterns of canopy and surface layer consumption in a boreal forest fire from repeat airborne lidar

NASA Astrophysics Data System (ADS)

Alonzo, Michael; Morton, Douglas C.; Cook, Bruce D.; Andersen, Hans-Erik; Babcock, Chad; Pattison, Robert

2017-05-01

Fire in the boreal region is the dominant agent of forest disturbance with direct impacts on ecosystem structure, carbon cycling, and global climate. Global and biome-scale impacts are mediated by burn severity, measured as loss of forest canopy and consumption of the soil organic layer. To date, knowledge of the spatial variability in burn severity has been limited by sparse field sampling and moderate resolution satellite data. Here, we used pre- and post-fire airborne lidar data to directly estimate changes in canopy vertical structure and surface elevation for a 2005 boreal forest fire on Alaska’s Kenai Peninsula. We found that both canopy and surface losses were strongly linked to pre-fire species composition and exhibited important fine-scale spatial variability at sub-30 m resolution. The fractional reduction in canopy volume ranged from 0.61 in lowland black spruce stands to 0.27 in mixed white spruce and broadleaf forest. Residual structure largely reflects standing dead trees, highlighting the influence of pre-fire forest structure on delayed carbon losses from aboveground biomass, post-fire albedo, and variability in understory light environments. Median loss of surface elevation was highest in lowland black spruce stands (0.18 m) but much lower in mixed stands (0.02 m), consistent with differences in pre-fire organic layer accumulation. Spatially continuous depth-of-burn estimates from repeat lidar measurements provide novel information to constrain carbon emissions from the surface organic layer and may inform related research on post-fire successional trajectories. Spectral measures of burn severity from Landsat were correlated with canopy (r = 0.76) and surface (r = -0.71) removal in black spruce stands but captured less of the spatial variability in fire effects for mixed stands (canopy r = 0.56, surface r = -0.26), underscoring the difficulty in capturing fire effects in heterogeneous boreal forest landscapes using proxy measures of burn severity from Landsat.

Structure and properties of carbon black particles

NASA Astrophysics Data System (ADS)

Xu, Wei

Structure and properties of carbon black particles were investigated using atomic force microscopy, gas adsorption, Raman spectroscopy, and X-ray diffraction. Supplementary information was obtained using TEM and neutron scattering. The AFM imaging of carbon black aggregates provided qualitative visual information on their morphology, complementary to that obtained by 3-D modeling based on TEM images. Our studies showed that carbon black aggregates were relatively flat. The surface of all untreated carbon black particles was found to be rough and its fractal dimension was 2.2. Heating reduced the roughness and fractal dimension for all samples heat treated at above 1300 K to 2.0. Once the samples were heat treated rapid cooling did not affect the surface roughness. However, rapid cooling reduced crystallite sizes, and different Raman spectra were obtained for carbon blacks of various history of heat treatment. By analyzing the Raman spectra we determined the crystallite sizes and identified amorphous carbon. The concentration of amorphous carbon depends on hydrogen content. Once hydrogen was liberated at increased temperature, the concentration of amorphous carbon was reduced and crystallites started to grow. Properties of carbon blacks at high pressure were also studied. Hydrostatic pressure did not affect the size of the crystallites in carbon black particles. The pressure induced shift in Raman frequency of the graphitic component was a result of increased intermolecular forces and not smaller crystallites. Two methods of determining the fractal dimension, the FHH model and the yardstick technique based on the BET theory were used in the literature. Our study proved that the FHH model is sensitive to numerous assumptions and leads to wrong conclusions. On the other hand the yardstick method gave correct results, which agreed with the AFM results.

The Force-Free Magnetosphere of a Rotating Black Hole

NASA Technical Reports Server (NTRS)

Contopoulos, Ioannis; Kazanas, Demosthenes; Papadopoulos, Demetrios B.

2013-01-01

We revisit the Blandford-Znajek process and solve the fundamental equation that governs the structure of the steady-state force-free magnetosphere around a Kerr black hole. The solution depends on the distributions of the magnetic field angular velocity and the poloidal electric current. These are not arbitrary. They are determined self-consistently by requiring that magnetic field lines cross smoothly the two singular surfaces of the problem: the inner "light surface" located inside the ergosphere and the outer "light surface" which is the generalization of the pulsar light cylinder.We find the solution for the simplest possible magnetic field configuration, the split monopole, through a numerical iterative relaxation method analogous to the one that yields the structure of the steady-state axisymmetric force-free pulsar magnetosphere. We obtain the rate of electromagnetic extraction of energy and confirm the results of Blandford and Znajek and of previous time-dependent simulations. Furthermore, we discuss the physical applicability of magnetic field configurations that do not cross both "light surfaces."

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Hongfen, E-mail: wanghongfen11@163.com; Wang, Zhiqi; Chen, Shougang

Molybdenum carbides with surfactants as carbon sources were prepared using the carbothermal reduction of the appropriate precursors (molybdenum oxides deposited on surfactant micelles) at 1023 K under hydrogen gas. The carburized products were characterized using scanning electron microscopy (SEM), X-ray diffraction and BET surface area measurements. From the SEM images, hollow microspherical and rod-like molybdenum carbides were observed. X-ray diffraction patterns showed that the annealing time of carburization had a large effect on the conversion of molybdenum oxides to molybdenum carbides. And BET surface area measurements indicated that the difference of carbon sources brought a big difference in specific surfacemore » areas of molybdenum carbides. - Graphical abstract: Molybdenum carbides having hollow microspherical and hollow rod-like morphologies that are different from the conventional monodipersed platelet-like morphologies. Highlights: Black-Right-Pointing-Pointer Molybdenum carbides were prepared using surfactants as carbon sources. Black-Right-Pointing-Pointer The kinds of surfactants affected the morphologies of molybdenum carbides. Black-Right-Pointing-Pointer The time of heat preservation at 1023 K affected the carburization process. Black-Right-Pointing-Pointer Molybdenum carbides with hollow structures had larger specific surface areas.« less

Atomic and electronic structure of exfoliated black phosphorus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Ryan J.; Topsakal, Mehmet; Jeong, Jong Seok

2015-11-15

Black phosphorus, a layered two-dimensional crystal with tunable electronic properties and high hole mobility, is quickly emerging as a promising candidate for future electronic and photonic devices. Although theoretical studies using ab initio calculations have tried to predict its atomic and electronic structure, uncertainty in its fundamental properties due to a lack of clear experimental evidence continues to stymie our full understanding and application of this novel material. In this work, aberration-corrected scanning transmission electron microscopy and ab initio calculations are used to study the crystal structure of few-layer black phosphorus. Directly interpretable annular dark-field images provide a three-dimensional atomic-resolutionmore » view of this layered material in which its stacking order and all three lattice parameters can be unambiguously identified. In addition, electron energy-loss spectroscopy (EELS) is used to measure the conduction band density of states of black phosphorus, which agrees well with the results of density functional theory calculations performed for the experimentally determined crystal. Furthermore, experimental EELS measurements of interband transitions and surface plasmon excitations are also consistent with simulated results. Finally, the effects of oxidation on both the atomic and electronic structure of black phosphorus are analyzed to explain observed device degradation. The transformation of black phosphorus into amorphous PO{sub 3} or H{sub 3}PO{sub 3} during oxidation may ultimately be responsible for the degradation of devices exposed to atmosphere over time.« less

Low-temperature sintering behavior of nanocrystalline indium tin oxide prepared from polymer-containing sols

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koroesi, Laszlo, E-mail: l.korosi@chem.u-szeged.hu; Papp, Szilvia; Oszko, Albert

2012-04-15

Highlights: Black-Right-Pointing-Pointer The synthesis of ITO powders and thin films from PVP-containing sols is presented. Black-Right-Pointing-Pointer The nano- and microstructures of ITO are more compact when PVP is used. Black-Right-Pointing-Pointer PVP acts both as a steric stabilizer of the sol and as a pre-sintering agent. Black-Right-Pointing-Pointer The PVP-induced enhanced sintering results in ITO with lower electrical resistance. Black-Right-Pointing-Pointer The surface composition of the ITO films is independent of the initial PVP content. -- Abstract: Indium tin hydroxide (ITH) xerogel powders and thin films with different polyvinylpyrrolidone (PVP) contents (0-22%, w/w) were prepared by a classical sol-gel method. To obtain nanocrystallinemore » indium tin oxide (ITO), the ITH xerogels were calcined at 550 Degree-Sign C. The effect of the initial polymer content on the structure of the ITO powders was studied by means of N{sub 2}-sorption measurements, small-angle X-ray scattering (SAXS), transmission and scanning electron microscopy. The N{sub 2}-sorption measurements revealed that the ITO powders obtained contained micropores and both their porosity and specific surface area decreased with increasing PVP content of the ITH xerogels. The SAXS measurements confirmed the enhanced sintering of the particles in the presence of PVP. The calculated mass fractal dimensions of the ITO powders increased significantly, indicating a significant compaction in structure. The pre-sintered structure could be achieved at relatively low temperature, which induced a significant decreasing (three orders of magnitude) in the electrical resistance of the ITO films.« less

Performance evaluation of two black nickel and two black chrome solar collectors

NASA Technical Reports Server (NTRS)

Losey, R.

1977-01-01

The test program was based on the evaluation of four unique solar collectors described below: (1) black nickel collector surface with a desiccant drying bed, (2) black nickel collector surface without a desiccant drying bed, (3) black chrome collector surface with a dessicant drying bed, and (4) black chrome collector surface without a desiccant drying bed. The test program included three distinct phases: Initial performance evaluation, natural environmental aging, and post-aging performance evaluation. Results of Phase III testing conclusively indicated a higher normalized efficiency for Black Chrome surfaces when compared to Black Nickel.

A study on prevention of an electric discharge at an extraction electrode of an electron cyclotron resonance ion source for cancer therapy.

PubMed

Kishii, Y; Kawasaki, S; Kitagawa, A; Muramatsu, M; Uchida, T

2014-02-01

A compact ECR ion source has utilized for carbon radiotherapy. In order to increase beam intensity with higher electric field at the extraction electrode and be better ion supply stability for long periods, electric geometry and surface conditions of an extraction electrode have been studied. Focusing attention on black deposited substances on the extraction electrode, which were observed around the extraction electrode after long-term use, the relation between black deposited substances and the electrical insulation property is investigated. The black deposited substances were inspected for the thickness of deposit, surface roughness, structural arrangement examined using Raman spectroscopy, and characteristics of electric discharge in a test bench, which was set up to simulate the ECR ion source.

Comparison of carbon onions and carbon blacks as conductive additives for carbon supercapacitors in organic electrolytes

NASA Astrophysics Data System (ADS)

Jäckel, N.; Weingarth, D.; Zeiger, M.; Aslan, M.; Grobelsek, I.; Presser, V.

2014-12-01

This study investigates carbon onions (∼400 m2 g-1) as a conductive additive for supercapacitor electrodes of activated carbon and compares their performance with carbon black with high or low internal surface area. We provide a study of the electrical conductivity and electrochemical behavior between 2.5 and 20 mass% addition of each of these three additives to activated carbon. Structural characterization shows that the density of the resulting film electrodes depends on the degree of agglomeration and the amount of additive. Addition of low surface area carbon black (∼80 m2 g-1) enhances the power handling of carbon electrodes but significantly lowers the specific capacitance even when adding small amounts of carbon black. A much lower decrease in specific capacitance is observed for carbon onions and the best values are seen for carbon black with a high surface area (∼1390 m2 g-1). The overall performance benefits from the addition of any of the studied additives only at either high scan rates and/or electrolytes with high ion mobility. Normalization to the volume shows a severe decrease in volumetric capacitance and only at high current densities nearing 10 A g-1 we can see an improvement of the electrode capacitance.

AFM imaging of natural optical structures

NASA Astrophysics Data System (ADS)

Dallaeva, Dinara; Tománek, Pavel; Prokopyeva, Elena; Kaspar, Pavel; Grmela, Lubomír.; Škarvada, Pavel

2015-01-01

The colors of some living organisms assosiated with the surface structure. Irridesence butterfly wings is an example of such coloration. Optical effects such as interference, diffraction, polarization are responsible for physical colors appearance. Alongside with amazing beauty this structure represent interest for design of optical devices. Here we report the results of morphology investigation by atomic force microscopy. The difference in surface structure of black and blue wings areas is clearly observed. It explains the angle dependence of the wing blue color, since these micrometer and sub-micrometer quasiperiodical structures could control the light propagation, absorption and reflection.

Structural and electrochemical properties of nanostructured nickel silicides by reduction and silicification of high-surface-area nickel oxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Xiao; Zhang, Bingsen; Li, Chuang

Graphical abstract: Nanostructured nickel silicides have been synthesized by reduction and silification of high-surface-area nickel oxide, and exhibited remarkably like-noble metal property, lower electric resistivity, and ferromagnetism at room temperature. Highlights: Black-Right-Pointing-Pointer NiSi{sub x} have been prepared by reduction and silification of high-surface-area NiO. Black-Right-Pointing-Pointer The structure of nickel silicides changed with increasing reaction temperature. Black-Right-Pointing-Pointer Si doping into nickel changed the magnetic properties of metallic nickel. Black-Right-Pointing-Pointer NiSi{sub x} have remarkably lower electric resistivity and like-noble metal property. -- Abstract: Nanostructured nickel silicides have been prepared by reduction and silicification of high-surface-area nickel oxide (145 m{sup 2} g{sup -1})more » produced via precipitation. The prepared materials were characterized by nitrogen adsorption, X-ray diffraction, thermal analysis, FT-IR spectroscopy, scanning electron microscopy, transmission electron microscopy, magnetic and electrochemical measurements. The nickel silicide formation involves the following sequence: NiO (cubic) {yields} Ni (cubic) {yields} Ni{sub 2}Si (orthorhombic) {yields} NiSi (orthorhombic) {yields} NiSi{sub 2} (cubic), with particles growing from 13.7 to 21.3 nm. The nickel silicides are ferromagnetic at room temperature, and their saturation magnetization values change drastically with the increase of Si content. Nickel silicides have remarkably low electrical resistivity and noble metal-like properties because of a constriction of the Ni d band and an increase of the electronic density of states. The results suggest that such silicides are promising candidates as inexpensive yet functional materials for applications in electrochemistry as well as catalysis.« less

Proto-jet configurations in RADs orbiting a Kerr SMBH: symmetries and limiting surfaces

NASA Astrophysics Data System (ADS)

Pugliese, D.; Stuchlík, Z.

2018-05-01

Ringed accretion disks (RADs) are agglomerations of perfect-fluid tori orbiting around a single central attractor that could arise during complex matter inflows in active galactic nuclei. We focus our analysis to axi-symmetric accretion tori orbiting in the equatorial plane of a supermassive Kerr black hole; equilibrium configurations, possible instabilities, and evolutionary sequences of RADs were discussed in our previous works. In the present work we discuss special instabilities related to open equipotential surfaces governing the material funnels emerging at various regions of the RADs, being located between two or more individual toroidal configurations of the agglomerate. These open structures could be associated to proto-jets. Boundary limiting surfaces are highlighted, connecting the emergency of the jet-like instabilities with the black hole dimensionless spin. These instabilities are observationally significant for active galactic nuclei, being related to outflows of matter in jets emerging from more than one torus of RADs orbiting around supermassive black holes.

Dielectric and microstructure properties of polymer carbon black composites

NASA Astrophysics Data System (ADS)

Brosseau, C.; Boulic, F.; Queffelec, P.; Bourbigot, C.; Le Mest, Y.; Loaec, J.; Beroual, A.

1997-01-01

Dielectric and physicochemical properties of a composite material prepared by incorporating carbon black particles into a polymer matrix were investigated. Two types of carbon blacks, having very different structures of aggregates, were used. The volume fraction of the carbon blacks ranged from 0.2% to 7%, i.e. below and above the percolation threshold concentration observed from the measurements of dc conductivity. The composite samples were characterized in terms of: swelling by a compatible solvent, electron paramagnetic resonance (EPR) response, and frequency variation of permittivity. First, the article attempts to evaluate the diffusion coefficient of an appropriate solvent in these materials. Sorption kinetics experiments with toluene indicate that the initial uptake of solvent exhibits a square root dependence in time as a consequence of Fick's law and permit to evaluate the effective diffusion coefficient in the range 10-11-10-12 m2 s-1 depending on the volume fraction of the carbon black in the sample. Second, the analysis of the carbon black concentration dependence of the intensity and linewidth of the EPR signals indicates that EPR is an important experimental probe of the structure of the elasticity network. The most notable feature of the present work is that we find a correlation of the percolation threshold concentration which is detected from the dc electrical conductivity with moments of the EPR lines. The conclusions on the elasticity networks deduced from swelling measurements are confirmed by EPR data carried out on swollen samples. On qualitative grounds the role of the specific surface of carbon black is further analyzed. It is suggested that the elasticity network is mainly controlled by secondary (respectively primary) aggregates for samples containing low (respectively high) specific surface carbon blacks. Last, the article reports precise experimental data on the permittivity of these composite materials as a function of frequency. Thanks to a sensitive measurement technique using an impedance analyzer, we are able to measure the complex permittivity and permeability values of the samples in the frequency range from 108 to 1010 Hz. It is found that the real part of the permittivity is a function of frequency f, via a power law expression ɛ'=af-b, where a and b are two parameters depending upon carbon black concentration, in the range of frequency investigated. The data analysis reaffirms the result that percolation threshold is a key parameter for characterizing the topological arrangement in these structures.

Plasmonic Resonance Enhanced Polarization-Sensitive Photodetection by Black Phosphorus in Near Infrared.

PubMed

Venuthurumilli, Prabhu K; Ye, Peide D; Xu, Xianfan

2018-05-22

Black phosphorus, a recently intensely investigated two-dimensional material, is promising for electronic and optoelectronic applications due to its higher mobility and thickness-dependent direct band gap. With its low direct band gap and anisotropic properties in nature, black phosphorus is also suitable for near-infrared polarization-sensitive photodetection. To enhance photoresponsivity of a black phosphorus based photodetector, we demonstrate two designs of plasmonic structures. In the first design, plasmonic bowtie antennas are used to increase the photocurrent, particularly in the armchair direction, where the optical absorption is higher than that in the zigzag direction. The simulated electric field distribution with bowtie structures shows enhanced optical absorption by localized surface plasmons. In the second design, bowtie apertures are used to enhance the inherent polarization selectivity of black phosphorus. A high photocurrent ratio (armchair to zigzag) of 8.7 is obtained. We choose a near-infrared wavelength of 1550 nm to demonstrate the photosensitivity enhancement and polarization selectivity, as it is useful for applications including telecommunication, remote sensing, biological imaging, and infrared polarimetry imaging.

Direct observation of a surface resonance state and surface band inversion control in black phosphorus

NASA Astrophysics Data System (ADS)

Ehlen, N.; Sanna, A.; Senkovskiy, B. V.; Petaccia, L.; Fedorov, A. V.; Profeta, G.; Grüneis, A.

2018-01-01

We report a Cs-doping-induced band inversion and the direct observation of a surface resonance state with an elliptical Fermi surface in black phosphorus (BP) using angle-resolved photoemission spectroscopy. By selectively inducing a higher electron concentration (1.7 ×1014cm-2 ) in the topmost layer, the changes in the Coulomb potential are sufficiently large to cause surface band inversion between the parabolic valence band of BP and a parabolic surface state around the Γ point of the BP Brillouin zone. Tight-binding calculations reveal that band gap openings at the crossing points in the two high-symmetry directions of the Brillouin zone require out-of-plane hopping and breaking of the glide mirror symmetry. Ab initio calculations are in very good agreement with the experiment if a stacking fault on the BP surface is taken into account. The demonstrated level of control over the band structure suggests the potential application of few-layer phosphorene in topological field-effect transistors.

Surface passivation of n-type doped black silicon by atomic-layer-deposited SiO2/Al2O3 stacks

NASA Astrophysics Data System (ADS)

van de Loo, B. W. H.; Ingenito, A.; Verheijen, M. A.; Isabella, O.; Zeman, M.; Kessels, W. M. M.

2017-06-01

Black silicon (b-Si) nanotextures can significantly enhance the light absorption of crystalline silicon solar cells. Nevertheless, for a successful application of b-Si textures in industrially relevant solar cell architectures, it is imperative that charge-carrier recombination at particularly highly n-type doped black Si surfaces is further suppressed. In this work, this issue is addressed through systematically studying lowly and highly doped b-Si surfaces, which are passivated by atomic-layer-deposited Al2O3 films or SiO2/Al2O3 stacks. In lowly doped b-Si textures, a very low surface recombination prefactor of 16 fA/cm2 was found after surface passivation by Al2O3. The excellent passivation was achieved after a dedicated wet-chemical treatment prior to surface passivation, which removed structural defects which resided below the b-Si surface. On highly n-type doped b-Si, the SiO2/Al2O3 stacks result in a considerable improvement in surface passivation compared to the Al2O3 single layers. The atomic-layer-deposited SiO2/Al2O3 stacks therefore provide a low-temperature, industrially viable passivation method, enabling the application of highly n- type doped b-Si nanotextures in industrial silicon solar cells.

Tidal interaction of black holes and Newtonian viscous bodies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Poisson, Eric

The tidal interaction of a (rotating or nonrotating) black hole with nearby bodies produces changes in its mass, angular momentum, and surface area. Similarly, tidal forces acting on a Newtonian, viscous body do work on the body, change its angular momentum, and part of the transferred gravitational energy is dissipated into heat. The equations that describe the rate of change of the black-hole mass, angular momentum, and surface area as a result of the tidal interaction are compared with the equations that describe how the tidal forces do work, torque, and produce heat in the Newtonian body. The equations aremore » strikingly similar, and unexpectedly, the correspondence between the Newtonian-body and black-hole results is revealed to hold in near-quantitative detail. The correspondence involves the combination k{sub 2}{tau} of 'Love quantities' that incorporate the details of the body's internal structure; k{sub 2} is the tidal Love number, and {tau} is the viscosity-produced delay between the action of the tidal forces and the body's reaction. The combination k{sub 2}{tau} is of order GM/c{sup 3} for a black hole of mass M; it does not vanish, in spite of the fact that k{sub 2} is known to vanish individually for a nonrotating black hole.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Yu; School of Mechanical and Electrical Engineering, Wuhan Institute of Technology, Wuhan 430073; Guo, Zhiguang, E-mail: zguo@licp.cas.cn

Graphical abstract: A double-metal-assisted chemical etching method is employed to fabricate superhydrophobic surfaces, showing a good superhydrophobicity with the contact angle of about 170°, and the sliding angle of about 0°. Meanwhile, the potential formation mechanism about it is also presented. Highlights: ► A double-metal-assisted chemical etching method is employed to fabricate superhydrophobic surfaces. ► The obtained surfaces show good superhydrophobicity with a high contact angle and low sliding angle. ► The color of the etched substrate dark brown or black and it is so-called black silicon. -- Abstract: Silicon substrates treated by metal-assisted chemical etching have been studied formore » many years since they could be employed in a variety of electronic and optical devices such as integrated circuits, photovoltaics, sensors and detectors. However, to the best of our knowledge, the chemical etching treatment on the same silicon substrate with the assistance of two or more kinds of metals has not been reported. In this paper, we mainly focus on the etching time and finally obtain a series of superhydrophobic silicon surfaces with novel etching structures through two successive etching processes of Cu-assisted and Ag-assisted chemical etching. It is shown that large-scale homogeneous but locally irregular wire-like structures are obtained, and the superhydrophobic surfaces with low hysteresis are prepared after the modifications with low surface energy materials. It is worth noting that the final silicon substrates not only possess high static contact angle and low hysteresis angle, but also show a black color, indicating that the superhydrophobic silicon substrate has an extremely low reflectance in a certain range of wavelengths. In our future work, we will go a step further to discuss the effect of temperature, the size of Cu nanoparticles and solution concentration on the final topography and superhydrophobicity.« less

Mesostructure, electron paramagnetic resonance, and magnetic properties of polymer carbon black composites

NASA Astrophysics Data System (ADS)

Brosseau, C.; Molinié, P.; Boulic, F.; Carmona, F.

2001-06-01

Electron paramagnetic resonance (EPR) has now become firmly established as one of the methods of choice for analyzing the carbon network over a range of different volume fraction of the carbon black in the composite, i.e., below and above the respective conduction threshold concentration. In the present article, two types of carbon blacks, having very different primary structures, surface areas, and percolation thresholds, were used; Raven 7000 (of high surface area and high percolation threshold volume fraction) and Y50A (of low surface area and low percolation threshold volume fraction). A semiquantitative image analysis of the microstructure from transmission electron microscopy reveals information about the spatial distribution of the carbon aggregates and agglomerates inside the composite. We observe that the apparent surface of agglomerates increases significantly with increasing carbon black content for the two types of blacks investigated. Adsorbed oxygen on the carbon black cristallites and dynamic coalescence under mixing conditions can be responsible for the broadening of the dispersed phase surface distribution. The interagglomerate distance in two samples of concentrations f

Black painted pottery, Kildehuse II, Odense County, Denmark.

PubMed

Trąbska, Joanna; Wesełucha-Birczyńska, Aleksandra; Zięba-Palus, Janina; Runge, Mads Thagård

2011-08-15

This work aimed at characterization of a black layer covering a Bronze Age (period VI) pot surface. To solve research problems plane polarized light microscopy (PLM), scanning microscopy with X-ray microanalyser (SEM/EDS), Raman and FTIR microspectroscopies were applied. Observation of the black layer under the PLM suggests that we deal with an opaque, isotropic layer, purposely put on leather-hard, burnished surface of a pot. No traces of organic substances that might have modified a pot surface before painting were detected. The black layer coats the pot with a continuous 0.2-0.4 μm thick layer. The black layer must have been applied while warm or hot. It is recognized that the black layer is a true painting layer. Spectroscopic analyses (Raman and FTIR) point that birch tar or a birch-pine tar had been applied. Carbon black should be definitely excluded. The analyzed organic substance is structurally ordered in various degrees, due to varying temperature influence. Some Raman spectra reveal, in second-order region of the spectrum (>2000 cm(-1)), the graphite presence. Scarce points reveal the presence of inorganic admixtures: clay minerals, feldspars and quartz. The next question is: Is it an organic paint or a carbon-based, "mixed" paint? Inorganic admixtures are only casual. Relatively high concentration of alumina is expected to have appeared due to aluminum mobility in acidic environment and this was provided by organic tar/pitch substances. Phosphorus (usually with calcium) mostly concentrates together with clay minerals. Thus, hypothesis on bone powder or ash addition to tar/pitch should be excluded. Some elements may originate not only from inorganic substances but also from wood ashes. Copyright © 2010 Elsevier B.V. All rights reserved.

Black painted pottery, Kildehuse II, Odense County, Denmark

NASA Astrophysics Data System (ADS)

Trąbska, Joanna; Wesełucha-Birczyńska, Aleksandra; Zięba-Palus, Janina; Runge, Mads Thagård

2011-08-01

This work aimed at characterization of a black layer covering a Bronze Age (period VI) pot surface. To solve research problems plane polarized light microscopy (PLM), scanning microscopy with X-ray microanalyser (SEM/EDS), Raman and FTIR microspectroscopies were applied. Observation of the black layer under the PLM suggests that we deal with an opaque, isotropic layer, purposely put on leather-hard, burnished surface of a pot. No traces of organic substances that might have modified a pot surface before painting were detected. The black layer coats the pot with a continuous 0.2-0.4 μm thick layer. The black layer must have been applied while warm or hot. It is recognized that the black layer is a true painting layer. Spectroscopic analyses (Raman and FTIR) point that birch tar or a birch-pine tar had been applied. Carbon black should be definitely excluded. The analyzed organic substance is structurally ordered in various degrees, due to varying temperature influence. Some Raman spectra reveal, in second-order region of the spectrum (>2000 cm -1), the graphite presence. Scarce points reveal the presence of inorganic admixtures: clay minerals, feldspars and quartz. The next question is: Is it an organic paint or a carbon-based, "mixed" paint? Inorganic admixtures are only casual. Relatively high concentration of alumina is expected to have appeared due to aluminum mobility in acidic environment and this was provided by organic tar/pitch substances. Phosphorus (usually with calcium) mostly concentrates together with clay minerals. Thus, hypothesis on bone powder or ash addition to tar/pitch should be excluded. Some elements may originate not only from inorganic substances but also from wood ashes.

Surface charges for gravity and electromagnetism in the first order formalism

NASA Astrophysics Data System (ADS)

Frodden, Ernesto; Hidalgo, Diego

2018-02-01

A new derivation of surface charges for 3  +  1 gravity coupled to electromagnetism is obtained. Gravity theory is written in the tetrad-connection variables. The general derivation starts from the Lagrangian, and uses the covariant symplectic formalism in the language of forms. For gauge theories, surface charges disentangle physical from gauge symmetries through the use of Noether identities and the exactness symmetry condition. The surface charges are quasilocal, explicitly coordinate independent, gauge invariant and background independent. For a black hole family solution, the surface charge conservation implies the first law of black hole mechanics. As a check, we show the first law for an electrically charged, rotating black hole with an asymptotically constant curvature (the Kerr–Newman (anti-)de Sitter family). The charges, including the would-be mass term appearing in the first law, are quasilocal. No reference to the asymptotic structure of the spacetime nor the boundary conditions is required and therefore topological terms do not play a rôle. Finally, surface charge formulae for Lovelock gravity coupled to electromagnetism are exhibited, generalizing the one derived in a recent work by Barnich et al Proc. Workshop ‘ About Various Kinds of Interactions’ in honour of Philippe Spindel (4–5 June 2015, Mons, Belgium) C15-06-04 (2016 (arXiv:1611.01777 [gr-qc])). The two different symplectic methods to define surface charges are compared and shown equivalent.

Refinement in black chrome for use as a solar selective coating

NASA Technical Reports Server (NTRS)

Mcdonald, G. E.

1974-01-01

Black chrome is significant as a solar selective coating because the current extensive use of black chrome in the electroplating industry as a durable decorative finish makes black chrome widely available on a commercial scale and potentially low in cost as a solar selective coating. Black-chrome deposits were modified by underplating with dull nickel or by being plated on rough surfaces. Both of these procedures increased the visible absorptance. There was no change in the infrared reflectance for the dull-nickel - black-chrome combination from that reported for the bright-nickel - black-chrome combination. However, the bright-nickel - black-chrome coating plated on rough surfaces indicated a slight decrease in infrared reflectance. As integrated over the solar spectrum for air mass 2, the reflectance of the dull-nickel - black-chrome coating was 0.077, of the bright-nickel - black-chrome coating plated on a 0.75-micron (30-microinch) surface was 0.070, of the bright-nickel - black-chrome coating plated on a 2.5 micron (100-microinch) surface was 0.064. The corresponding values for the bright-nickel - black-chrome coating on a 0.0125-micron (0.5-microinch) surface, two samples of black nickel, and two samples of Nextrel black paint were 0.132, 0.123, 0.133, and 0.033, respectively.

Pyrolytic carbon coated black silicon

NASA Astrophysics Data System (ADS)

Shah, Ali; Stenberg, Petri; Karvonen, Lasse; Ali, Rizwan; Honkanen, Seppo; Lipsanen, Harri; Peyghambarian, N.; Kuittinen, Markku; Svirko, Yuri; Kaplas, Tommi

2016-05-01

Carbon is the most well-known black material in the history of man. Throughout the centuries, carbon has been used as a black material for paintings, camouflage, and optics. Although, the techniques to make other black surfaces have evolved and become more sophisticated with time, carbon still remains one of the best black materials. Another well-known black surface is black silicon, reflecting less than 0.5% of incident light in visible spectral range but becomes a highly reflecting surface in wavelengths above 1000 nm. On the other hand, carbon absorbs at those and longer wavelengths. Thus, it is possible to combine black silicon with carbon to create an artificial material with very low reflectivity over a wide spectral range. Here we report our results on coating conformally black silicon substrate with amorphous pyrolytic carbon. We present a superior black surface with reflectance of light less than 0.5% in the spectral range of 350 nm to 2000 nm.

Nonlinear calculations of the time evolution of black hole accretion disks

NASA Technical Reports Server (NTRS)

Luo, C.

1994-01-01

Based on previous works on black hole accretion disks, I continue to explore the disk dynamics using the finite difference method to solve the highly nonlinear problem of time-dependent alpha disk equations. Here a radially zoned model is used to develop a computational scheme in order to accommodate functional dependence of the viscosity parameter alpha on the disk scale height and/or surface density. This work is based on the author's previous work on the steady disk structure and the linear analysis of disk dynamics to try to apply to x-ray emissions from black candidates (i.e., multiple-state spectra, instabilities, QPO's, etc.).

Geoid undulations and gravity anomalies over the Aral Sea, the Black Sea and the Caspian Sea from a combined GEOS-3/SEASAT/GEOSAT altimeter data set

NASA Technical Reports Server (NTRS)

Au, Andrew Y.; Brown, Richard D.; Welker, Jean E.

1991-01-01

Satellite-based altimetric data taken by GOES-3, SEASAT, and GEOSAT over the Aral Sea, the Black Sea, and the Caspian Sea are analyzed and a least squares collocation technique is used to predict the geoid undulations on a 0.25x0.25 deg. grid and to transform these geoid undulations to free air gravity anomalies. Rapp's 180x180 geopotential model is used as the reference surface for the collocation procedure. The result of geoid to gravity transformation is, however, sensitive to the information content of the reference geopotential model used. For example, considerable detailed surface gravity data were incorporated into the reference model over the Black Sea, resulting in a reference model with significant information content at short wavelengths. Thus, estimation of short wavelength gravity anomalies from gridded geoid heights is generally reliable over regions such as the Black Sea, using the conventional collocation technique with local empirical covariance functions. Over regions such as the Caspian Sea, where detailed surface data are generally not incorporated into the reference model, unconventional techniques are needed to obtain reliable gravity anomalies. Based on the predicted gravity anomalies over these inland seas, speculative tectonic structures are identified and geophysical processes are inferred.

Nickel-Phosphorous Development for Total Solar Irradiance Measurement

NASA Astrophysics Data System (ADS)

Carlesso, F.; Berni, L. A.; Vieira, L. E. A.; Savonov, G. S.; Nishimori, M.; Dal Lago, A.; Miranda, E.

2017-10-01

The development of an absolute radiometer instrument is currently a effort at INPE for TSI measurements. In this work, we describe the development of black Ni-P coatings for TSI radiometers absorptive cavities. We present a study of the surface blackening process and the relationships between morphological structure, chemical composition and coating absorption. Ni-P deposits with different phosphorous content were obtained by electroless techniques on aluminum substrates with a thin zincate layer. Appropriate phosphorus composition and etching parameters process produce low reflectance black coatings.

First law of black hole mechanics as a condition for stationarity

NASA Astrophysics Data System (ADS)

McCormick, Stephen

2014-11-01

In earlier work, we provided a Hilbert manifold structure for the phase space for the Einstein-Yang-Mills equations, and used this to prove a condition for initial data to be stationary [S. McCormick, Adv. Theor. Math. Phys. 18, 799 (2014)]. Here we use the same phase space to consider the evolution of initial data exterior to some closed 2-surface boundary, and establish a condition for stationarity in this case. It is shown that the differential relationship given in the first law of black hole mechanics is exactly the condition required for the initial data to be stationary; this was first argued nonrigorously by Sudarsky and Wald [Phys. Rev. D 46, 1453 (1992)]. Furthermore, we give evidence to suggest that if this differential relationship holds then the boundary surface is the bifurcation surface of a bifurcate Killing horizon.

Surface characterization of ZnO/ZnMn{sub 2}O{sub 4} and Cu/Mn{sub 3}O{sub 4} powders obtained by thermal degradation of heterobimetallic complexes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barrault, Joeel, E-mail: joel.barrault@univ-poitiers.fr; Makhankova, Valeriya G., E-mail: leram@univ.kiev.ua; Khavryuchenko, Oleksiy V.

2012-03-15

From the selective transformation of the heterometallic (Zn-Mn or Cu-Mn) carboxylate complexes with 2,2 Prime -bipyridyl by thermal degradation at relatively low (350 Degree-Sign C) temperature, it was possible to get either well defined spinel ZnMn{sub 2}O{sub 4} over zinc oxide or well dispersed copper particles surrounded by a manganese oxide (Mn{sub 3}O{sub 4}) in a core-shell like structure. Morphology of the powder surface was examined by scanning electron microscopy with energy dispersive X-ray microanalysis (SEM/EDX). Surface composition was determined by X-ray photoelectron spectroscopy (XPS). Specific surface of the powders by nitrogen adsorption was found to be 33{+-}0.2 and 9{+-}0.06more » m{sup 2} g{sup -1} for Zn-Mn and Cu-Mn samples, respectively, which is comparable to those of commercial products. - Graphical abstract: From the selective transformation of heterometallic (Zn-Mn or Cu-Mn) carboxylate complexes, it was possible to get either well defined spinel ZnMn{sub 2}O{sub 4} over zinc oxide or well dispersed copper particles surrounded by a manganese oxide (Mn{sub 3}O{sub 4}) in a core-shell like structure. Highlights: Black-Right-Pointing-Pointer Thermal degradation of heterometallic complexes results in fine disperse particles. Black-Right-Pointing-Pointer Core-shell Cu/Mn{sub 3}O{sub 4} particles are obtained. Black-Right-Pointing-Pointer ZnMn{sub 2}O{sub 4} spinel layer covers ZnO particles.« less

Pyrolytic carbon coated black silicon

PubMed Central

Shah, Ali; Stenberg, Petri; Karvonen, Lasse; Ali, Rizwan; Honkanen, Seppo; Lipsanen, Harri; Peyghambarian, N.; Kuittinen, Markku; Svirko, Yuri; Kaplas, Tommi

2016-01-01

Carbon is the most well-known black material in the history of man. Throughout the centuries, carbon has been used as a black material for paintings, camouflage, and optics. Although, the techniques to make other black surfaces have evolved and become more sophisticated with time, carbon still remains one of the best black materials. Another well-known black surface is black silicon, reflecting less than 0.5% of incident light in visible spectral range but becomes a highly reflecting surface in wavelengths above 1000 nm. On the other hand, carbon absorbs at those and longer wavelengths. Thus, it is possible to combine black silicon with carbon to create an artificial material with very low reflectivity over a wide spectral range. Here we report our results on coating conformally black silicon substrate with amorphous pyrolytic carbon. We present a superior black surface with reflectance of light less than 0.5% in the spectral range of 350 nm to 2000 nm. PMID:27174890

Microstructure of a black chrome solar selective absorber

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lampert, C.M.

1978-08-01

The structure of Harshaw Chemicals' CHROM-ONYX type of black chrome/metal selective absorber was studied to gain a better understanding of its influence upon the mechanism of wavelength selectivity. Spectral reflectance measurements were performed on seven samples. In this study, the best selectivity was found by these measurements to be 1.0 micron of black chrome on copper and 0.7 micron of black chrome on nickel. Both transmission and scanning electron microscopy were employed to study microstructure and chemical composition. As a result of the combined studies, some effects of black chrome thickness and the metallic substrate were determined. It was foundmore » that black chrome consisted of a very fine metallic distribution of particles of chromium, possibly suspended within a matrix of an oxide of chromium. This combination was, in turn, agglomerated into larger particles within the 0.05--0.3 micron size range. These larger particles formed a network which constituted the surface coating.« less

Horizon structure of rotating Einstein-Born-Infeld black holes and shadow

NASA Astrophysics Data System (ADS)

Atamurotov, Farruh; Ghosh, Sushant G.; Ahmedov, Bobomurat

2016-05-01

We investigate the horizon structure of the rotating Einstein-Born-Infeld solution which goes over to the Einstein-Maxwell's Kerr-Newman solution as the Born-Infeld parameter goes to infinity (β → ∞). We find that for a given β , mass M, and charge Q, there exist a critical spinning parameter aE and rHE, which corresponds to an extremal Einstein-Born-Infeld black hole with degenerate horizons, and aE decreases and rHE increases with increase of the Born-Infeld parameter β , while a

Unexpected Attraction of Polarotactic Water-Leaving Insects to Matt Black Car Surfaces: Mattness of Paintwork Cannot Eliminate the Polarized Light Pollution of Black Cars

PubMed Central

Blaho, Miklos; Herczeg, Tamas; Kriska, Gyorgy; Egri, Adam; Szaz, Denes; Farkas, Alexandra; Tarjanyi, Nikolett; Czinke, Laszlo; Barta, Andras; Horvath, Gabor

2014-01-01

The horizontally polarizing surface parts of shiny black cars (the reflection-polarization characteristics of which are similar to those of water surfaces) attract water-leaving polarotactic insects. Thus, shiny black cars are typical sources of polarized light pollution endangering water-leaving insects. A new fashion fad is to make car-bodies matt black or grey. Since rough (matt) surfaces depolarize the reflected light, one of the ways of reducing polarized light pollution is to make matt the concerned surface. Consequently, matt black/grey cars may not induce polarized light pollution, which would be an advantageous feature for environmental protection. To test this idea, we performed field experiments with horizontal shiny and matt black car-body surfaces laid on the ground. Using imaging polarimetry, in multiple-choice field experiments we investigated the attractiveness of these test surfaces to various water-leaving polarotactic insects and obtained the following results: (i) The attractiveness of black car-bodies to polarotactic insects depends in complex manner on the surface roughness (shiny, matt) and species (mayflies, dolichopodids, tabanids). (ii) Non-expectedly, the matt dark grey car finish is much more attractive to mayflies (being endangered and protected in many countries) than matt black finish. (iii) The polarized light pollution of shiny black cars usually cannot be reduced with the use of matt painting. On the basis of these, our two novel findings are that (a) matt car-paints are highly polarization reflecting, and (b) these matt paints are not suitable to repel polarotactic insects. Hence, the recent technology used to make matt the car-bodies cannot eliminate or even can enhance the attractiveness of black/grey cars to water-leaving insects. Thus, changing shiny black car painting to matt one is a disadvantageous fashion fad concerning the reduction of polarized light pollution of black vehicles. PMID:25076137

Unexpected attraction of polarotactic water-leaving insects to matt black car surfaces: mattness of paintwork cannot eliminate the polarized light pollution of black cars.

PubMed

Blaho, Miklos; Herczeg, Tamas; Kriska, Gyorgy; Egri, Adam; Szaz, Denes; Farkas, Alexandra; Tarjanyi, Nikolett; Czinke, Laszlo; Barta, Andras; Horvath, Gabor

2014-01-01

The horizontally polarizing surface parts of shiny black cars (the reflection-polarization characteristics of which are similar to those of water surfaces) attract water-leaving polarotactic insects. Thus, shiny black cars are typical sources of polarized light pollution endangering water-leaving insects. A new fashion fad is to make car-bodies matt black or grey. Since rough (matt) surfaces depolarize the reflected light, one of the ways of reducing polarized light pollution is to make matt the concerned surface. Consequently, matt black/grey cars may not induce polarized light pollution, which would be an advantageous feature for environmental protection. To test this idea, we performed field experiments with horizontal shiny and matt black car-body surfaces laid on the ground. Using imaging polarimetry, in multiple-choice field experiments we investigated the attractiveness of these test surfaces to various water-leaving polarotactic insects and obtained the following results: (i) The attractiveness of black car-bodies to polarotactic insects depends in complex manner on the surface roughness (shiny, matt) and species (mayflies, dolichopodids, tabanids). (ii) Non-expectedly, the matt dark grey car finish is much more attractive to mayflies (being endangered and protected in many countries) than matt black finish. (iii) The polarized light pollution of shiny black cars usually cannot be reduced with the use of matt painting. On the basis of these, our two novel findings are that (a) matt car-paints are highly polarization reflecting, and (b) these matt paints are not suitable to repel polarotactic insects. Hence, the recent technology used to make matt the car-bodies cannot eliminate or even can enhance the attractiveness of black/grey cars to water-leaving insects. Thus, changing shiny black car painting to matt one is a disadvantageous fashion fad concerning the reduction of polarized light pollution of black vehicles.

Influence of the geometric configuration of accretion flow on the black hole spin dependence of relativistic acoustic geometry

NASA Astrophysics Data System (ADS)

Tarafdar, Pratik; Das, Tapas K.

Linear perturbation of general relativistic accretion of low angular momentum hydrodynamic fluid onto a Kerr black hole leads to the formation of curved acoustic geometry embedded within the background flow. Characteristic features of such sonic geometry depend on the black hole spin. Such dependence can be probed by studying the correlation of the acoustic surface gravity κ with the Kerr parameter a. The κ-a relationship further gets influenced by the geometric configuration of the accretion flow structure. In this work, such influence has been studied for multitransonic shocked accretion where linear perturbation of general relativistic flow profile leads to the formation of two analogue black hole-type horizons formed at the sonic points and one analogue white hole-type horizon which is formed at the shock location producing divergent acoustic surface gravity. Dependence of the κ-a relationship on the geometric configuration has also been studied for monotransonic accretion, over the entire span of the Kerr parameter including retrograde flow. For accreting astrophysical black holes, the present work thus investigates how the salient features of the embedded relativistic sonic geometry may be determined not only by the background spacetime, but also by the flow configuration of the embedding matter.

Isoperimetric surfaces and area-angular momentum inequality in a rotating black hole in new massive gravity

NASA Astrophysics Data System (ADS)

Aceña, Andrés; López, Ericson; Llerena, Mario

2018-03-01

We study the existence and stability of isoperimetric surfaces in a family of rotating black holes in new massive gravity. We show that the stability of such surfaces is determined by the sign of the hair parameter. We use the isoperimetric surfaces to find a geometric inequality between the area and the angular momentum of the black hole, conjecturing geometric inequalities for more general black holes.

Gradient induced liquid motion on laser structured black Si surfaces

NASA Astrophysics Data System (ADS)

Paradisanos, I.; Fotakis, C.; Anastasiadis, S. H.; Stratakis, E.

2015-09-01

This letter reports on the femtosecond laser fabrication of gradient-wettability micro/nano-patterns on Si surfaces. The dynamics of directional droplet spreading on the surface tension gradients developed is systematically investigated and discussed. It is shown that microdroplets on the patterned surfaces spread at a maximum speed of 505 mm/s, which is the highest velocity demonstrated so far for liquid spreading on a surface tension gradient in ambient conditions. The application of the proposed laser patterning technique for the precise fabrication of surface tension gradients for open microfluidic systems, liquid management in fuel cells, and drug delivery is envisaged.

Evaluation of suitable porosity for sintered porous {beta}-tricalcium phosphate as a bone substitute

DOE Office of Scientific and Technical Information (OSTI.GOV)

Park, Jin-Hong; Bae, Ji-Yong; Shim, Jaebum

2012-09-15

Structural and mechanical characterization is performed for sintered porous beta tricalcium phosphate ({beta}-TCP) to determine the appropriate porosity for use as a bone substitute. Four different types of porous {beta}-TCP specimen with different porosities are fabricated through a sintering process. For structural characterization, scanning electron microscopy and a Microfocus X-ray computed tomography system are used to investigate the pore openings on the specimen's surface, pore size, pore distribution, and pore interconnections. Compression tests of the specimens are performed, and mechanical properties such as the elastic modulus and compressive strength are obtained. Also, the geometric shape and volume of the {beta}-TCPmore » around the contact region of two pores, which need to be initially resolved after implantation in order to increase the size of the pore openings, are evaluated through simple calculations. The results show that porous {beta}-TCP with 42.1% porosity may be a suitable bone substitute candidate in terms of sustaining external loads, and inducing and cultivating bone cells. - Highlights: Black-Right-Pointing-Pointer Structural and mechanical characterization was performed for sintered porous {beta}-TCP specimens. Black-Right-Pointing-Pointer For structural characterization, SEM and Microfocus X-ray CT system were used. Black-Right-Pointing-Pointer For mechanical characterization, compression tests were performed. Black-Right-Pointing-Pointer Porous {beta}-TCP with 42.1% porosity may be a suitable bone substitute.« less

Climate effects on fire regimes and tree recruitment in Black Hills ponderosa pine forests.

PubMed

Brown, Peter M

2006-10-01

Climate influences forest structure through effects on both species demography (recruitment and mortality) and disturbance regimes. Here, I compare multi-century chronologies of regional fire years and tree recruitment from ponderosa pine forests in the Black Hills of southwestern South Dakota and northeastern Wyoming to reconstructions of precipitation and global circulation indices. Regional fire years were affected by droughts and variations in both Pacific and Atlantic sea surface temperatures. Fires were synchronous with La Niñas, cool phases of the Pacific Decadal Oscillation (PDO), and warm phases of the Atlantic Multidecadal Oscillation (AMO). These quasi-periodic circulation features are associated with drought conditions over much of the western United States. The opposite pattern (El Niño, warm PDO, cool AMO) was associated with fewer fires than expected. Regional tree recruitment largely occurred during wet periods in precipitation reconstructions, with the most abundant recruitment coeval with an extended pluvial from the late 1700s to early 1800s. Widespread even-aged cohorts likely were not the result of large crown fires causing overstory mortality, but rather were caused by optimal climate conditions that contributed to synchronous regional recruitment and longer intervals between surface fires. Synchronous recruitment driven by climate is an example of the Moran effect. The presence of abundant fire-scarred trees in multi-aged stands supports a prevailing historical model for ponderosa pine forests in which recurrent surface fires affected heterogenous forest structure, although the Black Hills apparently had a greater range of fire behavior and resulting forest structure over multi-decadal time scales than ponderosa pine forests of the Southwest that burned more often.

The origin of black carbon on speleothems in tourist caves in South Korea: Chemical characterization and source discrimination by radiocarbon measurement

NASA Astrophysics Data System (ADS)

Chang, Sae Jung; Jeong, Gi Young; Kim, Soo Jin

Since the Gosu, Ondal, and Sungryu karst caves in South Korea became open to the public several decades ago, the surface of their speleothems has been turning black due to pollutants. The black pollutant is concentrated at the surface of speleothems, and the surface black layer is 0.1 to several millimeters thick. Elemental measurements of three bulk, acid-dissolved and oxidized fractions of the surface black layer show that the black pigment is a black carbon. The black carbon correlates positively with sulfates, nitrates, manganese, and lead, which are typical tracers of industrial and urban emissions. The 14C-measurement of the black carbon, using accelerator mass spectrometry, shows that the black carbon was derived from both fossil-fuel combustion and biomass burning in roughly equal amounts, evidenced by fC value ranging from 0.340 to 0.592 (<±0.004, 1 σ). Therefore, protection of speleothems from black coloration requires control of anthropogenic black carbons carried by visitors. Suitable measures might include closure of caves, air cleaning of visitors and regulation of visitor numbers. The application of radiocarbon measurement of black carbon suggests that the fC is a valuable proxy for tracing the blackening phenomenon of natural and cultural heritage sites such as caves.

The influence of iridium chemical oxidation state on the performance and durability of oxygen evolution catalysts in PEM electrolysis

NASA Astrophysics Data System (ADS)

Siracusano, S.; Baglio, V.; Grigoriev, S. A.; Merlo, L.; Fateev, V. N.; Aricò, A. S.

2017-10-01

Nanosized Ir-black (3 nm) and Ir-oxide (5 nm) oxygen evolution electrocatalysts showing high performance in polymer electrolyte membrane (PEM) water electrolysis based on Aquivion® short-side chain ionomer membrane are investigated to understand the role of the Ir oxidation state on the electrocatalytic activity and stability. Despite the smaller mean crystallite size, the Ir-black electrocatalyst shows significantly lower initial performance than the Ir-oxide. During operation at high current density, the Ir-black shows a decrease of cell potential with time whereas the Ir-oxide catalyst shows increasing cell potential resulting in a degradation rate of about 10 μV/h, approaching 1000 h. The unusual behaviour of the Ir-black results from the oxidation of metallic Ir to IrOx. The Ir-oxide catalyst shows instead a hydrated structure on the surface and a negative shift of about 0.5 eV for the Ir 4f binding energy after 1000 h electrolysis operation. This corresponds to the formation of a sub-stoichiometric Ir-oxide on the surface. These results indicate that a hydrated IrO2 with high oxidation state on the surface is favourable in decreasing the oxygen evolution overpotential. Modifications of the Ir chemical oxidation state during operation can affect significantly the catalytic activity and durability of the electrolysis system.

J-Black: a stray light coating for optical and infrared systems

NASA Astrophysics Data System (ADS)

Waddell, Patrick; Black, David S.

2016-07-01

A new stray light coating, called J-Black, has been developed for NASA's Stratospheric Observatory for Infrared Astronomy (SOFIA). The coating is a layered composition of Nextel-Suede 3101 primers and top coats and silicon carbide grit. J-Black has been applied to large areas of the SOFIA airborne telescope and is currently operating within the open cavity environment of the Boeing 747. Over a series of discrete filter bands, from 0.4 to 21 microns, J-Black optical and infrared reflectivity performance is compared with other available coatings. Measured total reflectance values are less than 2% at the longest wavelengths, including at high incidence angles. Detailed surface structure characteristics are also compared via electron and ion microscopy. Environmental tests applicable for aerospace applications are presented, as well as the detailed steps required to apply the coating.

Novel synthesis of core-shell Au-Pt dendritic nanoparticles supported on carbon black for enhanced methanol electro-oxidation

NASA Astrophysics Data System (ADS)

Cao, Ribing; Xia, Tiantian; Zhu, Ruizhi; Liu, Zhihua; Guo, Jinming; Chang, Gang; Zhang, Zaoli; Liu, Xiong; He, Yunbin

2018-03-01

Core-shell Au-Pt dendritic nanoparticles (Au-Pt NPs) has been synthesized via a facile seed-mediated growth method, in which dendritic Pt nanoparticles as shell grow on the surface of gold nanocores by using ascorbic acid (AA) as "green" reducing reagents. The morphologies and compositions of the as-prepared nanocomposites with core-shell structure are characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Electrochemical experiments, including cyclic voltammetry (CV) and chronoamperometry (CA) are performed to investigate the electrocatalytic properties of the Au-Pt NPs loaded carbon black composites (Au-Pt NPs/V) towards methanol oxidation in an alkaline solution. It is found that the reduction time of AA could regulate the thickness and amount of Pt on the Au nanocores, which significantly affect catalytic activity of the Au-Pt NPs/V toward methanol oxidation. Au-Pt NPs/V with optimum reduction time 4 h exhibit 2.3-times higher electrocatalytic activity than that of a commercial catalyst (Pt/carbon black) and an excellent CO tolerance toward methanol oxidation. This behavior is attributed to large active electrochemical area of the bimetallic nanocomposites and the change in the electronic structure of Pt when Au surface modified with fewer Pt nanoparticles.

Selective coating for solar panels. [using black chrome and black nickel

NASA Technical Reports Server (NTRS)

Mcdonald, G. E. (Inventor)

1977-01-01

The energy absorbing properties of solar heating panels are improved by depositing a black chrome coating of controlled thickness on a specially prepared surface of a metal substrate. The surface is prepared by depositing a dull nickel on the substrate, and the black chrome is plated on this low emittance surface to a thickness between 0.5 micron and 2.5 microns.

Dynamic recrystallization in friction surfaced austenitic stainless steel coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Puli, Ramesh, E-mail: rameshpuli2000@gmail.com; Janaki Ram, G.D.

2012-12-15

Friction surfacing involves complex thermo-mechanical phenomena. In this study, the nature of dynamic recrystallization in friction surfaced austenitic stainless steel AISI 316L coatings was investigated using electron backscattered diffraction and transmission electron microscopy. The results show that the alloy 316L undergoes discontinuous dynamic recrystallization under conditions of moderate Zener-Hollomon parameter during friction surfacing. - Highlights: Black-Right-Pointing-Pointer Dynamic recrystallization in alloy 316L friction surfaced coatings is examined. Black-Right-Pointing-Pointer Friction surfacing leads to discontinuous dynamic recrystallization in alloy 316L. Black-Right-Pointing-Pointer Strain rates in friction surfacing exceed 400 s{sup -1}. Black-Right-Pointing-Pointer Estimated grain size matches well with experimental observations in 316L coatings.

Micro-Textured Black Silicon Wick for Silicon Heat Pipe Array

NASA Technical Reports Server (NTRS)

Yee, Karl Y.; Sunada, Eric T.; Ganapathi, Gani B.; Manohara, Harish; Homyk, Andrew; Prina, Mauro

2013-01-01

Planar, semiconductor heat arrays have been previously proposed and developed; however, this design makes use of a novel, microscale black silicon wick structure that provides increased capillary pumping pressure of the internal working fluid, resulting in increased effective thermal conductivity of the device, and also enables operation of the device in any orientation with respect to the gravity vector. In a heat pipe, the efficiency of thermal transfer from the case to the working fluid is directly proportional to the surface area of the wick in contact with the fluid. Also, the primary failure mechanism for heat pipes operating within the temperature range of interest is inadequate capillary pressure for the return of fluid from the condenser to the wick. This is also what makes the operation of heat pipes orientation-sensitive. Thus, the two primary requirements for a good wick design are a large surface area and high capillary pressure. Surface area can be maximized through nanomachined surface roughening. Capillary pressure is largely driven by the working fluid and wick structure. The proposed nanostructure wick has characteristic dimensions on the order of tens of microns, which promotes menisci of very small radii. This results in the possibility of enormous pumping potential due to the inverse proportionality with radius. Wetting, which also enhances capillary pumping, can be maximized through growth of an oxide layer or material deposition (e.g. TiO2) to create a superhydrophilic surface.

Below the disappearing marshes of an urban estuary: historic nitrogen trends and soil structure

USGS Publications Warehouse

Wigand, Cathleen; Roman, Charles T.; Davey, Earl; Stolt, Mark; Johnson, Roxanne; Hanson, Alana; Watson, Elizabeth B.; Moran, S. Bradley; Cahoon, Donald R.; Lynch, James C.; Rafferty, Patricia

2014-01-01

Marshes in the urban Jamaica Bay Estuary, New York, USA are disappearing at an average rate of 13 ha/yr, and multiple stressors (e.g., wastewater inputs, dredging activities, groundwater removal, and global warming) may be contributing to marsh losses. Among these stressors, wastewater nutrients are suspected to be an important contributing cause of marsh deterioration. We used census data, radiometric dating, stable nitrogen isotopes, and soil surveys to examine the temporal relationships between human population growth and soil nitrogen; and we evaluated soil structure with computer-aided tomography, surface elevation and sediment accretion trends, carbon dioxide emissions, and soil shear strength to examine differences among disappearing (Black Bank and Big Egg) and stable marshes (JoCo). Radiometric dating and nitrogen isotope analyses suggested a rapid increase in human wastewater nutrients beginning in the late 1840s, and a tapering off beginning in the 1930s when wastewater treatment plants (WWTPs) were first installed. Current WWTPs nutrient loads to Jamaica Bay are approximately 13 995 kg N/d and 2767 kg P/d. At Black Bank, the biomass and abundance of roots and rhizomes and percentage of organic matter on soil were significantly lower, rhizomes larger in diameter, carbon dioxide emission rates and peat particle density significantly greater, and soil strength significantly lower compared to the stable JoCo Marsh, suggesting Black Bank has elevated decomposition rates, more decomposed peat, and highly waterlogged peat. Despite these differences, the rates of accretion and surface elevation change were similar for both marshes, and the rates of elevation change approximated the long term relative rate of sea level rise estimated from tide gauge data at nearby Sandy Hook, New Jersey. We hypothesize that Black Bank marsh kept pace with sea level rise by the accretion of material on the marsh surface, and the maintenance of soil volume through production of larger diameter rhizomes and swelling (dilation) of waterlogged peat. JoCo Marsh kept pace with sea-level rise through surface accretion and soil organic matter accumulation. Understanding the effects of multiple stressors, including nutrient enrichment, on soil structure, organic matter accumulation, and elevation change will better inform management decisions aimed at maintaining and restoring coastal marshes.

Below the disappearing marshes of an urban estuary: historic nitrogen trends and soil structure.

PubMed

Wigand, Cathleen; Roman, Charles T; Davey, Earl; Stolt, Mark; Johnson, Roxanne; Hanson, Alana; Watson, Elizabeth B; Moran, S Bradley; Cahoon, Donald R; Lynch, James C; Rafferty, Patricia

2014-06-01

Marshes in the urban Jamaica Bay Estuary, New York, USA are disappearing at an average rate of 13 ha/yr, and multiple stressors (e.g., wastewater inputs, dredging activities, groundwater removal, and global warming) may be contributing to marsh losses. Among these stressors, wastewater nutrients are suspected to be an important contributing cause of marsh deterioration. We used census data, radiometric dating, stable nitrogen isotopes, and soil surveys to examine the temporal relationships between human population growth and soil nitrogen; and we evaluated soil structure with computer-aided tomography, surface elevation and sediment accretion trends, carbon dioxide emissions, and soil shear strength to examine differences among disappearing (Black Bank and Big Egg) and stable marshes (JoCo). Radiometric dating and nitrogen isotope analyses suggested a rapid increase in human wastewater nutrients beginning in the late 1840s, and a tapering off beginning in the 1930s when wastewater treatment plants (WWTPs) were first installed. Current WWTPs nutrient loads to Jamaica Bay are approximately 13 995 kg N/d and 2767 kg P/d. At Black Bank, the biomass and abundance of roots and rhizomes and percentage of organic matter on soil were significantly lower, rhizomes larger in diameter, carbon dioxide emission rates and peat particle density significantly greater, and soil strength significantly lower compared to the stable JoCo Marsh, suggesting Black Bank has elevated decomposition rates, more decomposed peat, and highly waterlogged peat. Despite these differences, the rates of accretion and surface elevation change were similar for both marshes, and the rates of elevation change approximated the long-term relative rate of sea level rise estimated from tide gauge data at nearby Sandy Hook, New Jersey. We hypothesize that Black Bank marsh kept pace with sea level rise by the accretion of material on the marsh surface, and the maintenance of soil volume through production of larger diameter rhizomes and swelling (dilation) of waterlogged peat. JoCo Marsh kept pace with sea-level rise through surface accretion and soil organic matter accumulation. Understanding the effects of multiple stressors, including nutrient enrichment, on soil structure, organic matter accumulation, and elevation change will better inform management decisions aimed at maintaining and restoring coastal marshes.

Quantum information versus black hole physics: deep firewalls from narrow assumptions

NASA Astrophysics Data System (ADS)

Braunstein, Samuel L.; Pirandola, Stefano

2018-07-01

The prevalent view that evaporating black holes should simply be smaller black holes has been challenged by the firewall paradox. In particular, this paradox suggests that something different occurs once a black hole has evaporated to one-half its original surface area. Here, we derive variations of the firewall paradox by tracking the thermodynamic entropy within a black hole across its entire lifetime and extend it even to anti-de Sitter space-times. Our approach sweeps away many unnecessary assumptions, allowing us to demonstrate a paradox exists even after its initial onset (when conventional assumptions render earlier analyses invalid). The most natural resolution may be to accept firewalls as a real phenomenon. Further, the vast entropy accumulated implies a deep firewall that goes `all the way down' in contrast with earlier work describing only a structure at the horizon. This article is part of a discussion meeting issue `Foundations of quantum mechanics and their impact on contemporary society'.

Quantum information versus black hole physics: deep firewalls from narrow assumptions.

PubMed

Braunstein, Samuel L; Pirandola, Stefano

2018-07-13

The prevalent view that evaporating black holes should simply be smaller black holes has been challenged by the firewall paradox. In particular, this paradox suggests that something different occurs once a black hole has evaporated to one-half its original surface area. Here, we derive variations of the firewall paradox by tracking the thermodynamic entropy within a black hole across its entire lifetime and extend it even to anti-de Sitter space-times. Our approach sweeps away many unnecessary assumptions, allowing us to demonstrate a paradox exists even after its initial onset (when conventional assumptions render earlier analyses invalid). The most natural resolution may be to accept firewalls as a real phenomenon. Further, the vast entropy accumulated implies a deep firewall that goes 'all the way down' in contrast with earlier work describing only a structure at the horizon.This article is part of a discussion meeting issue 'Foundations of quantum mechanics and their impact on contemporary society'. © 2018 The Author(s).

General Relativistic Radiative Transfer and General Relativistic MHD Simulations of Accretion and Outflows of Black Holes

NASA Technical Reports Server (NTRS)

Fuerst, Steven V.; Mizuno, Yosuke; Nishikawa, Ken-Ichi; Wu, Kinwah

2007-01-01

We have calculated the emission from relativistic flows in black hole systems using a fully general relativistic radiative transfer, with flow structures obtained by general relativistic magnetohydrodynamic simulations. We consider thermal free-free emission and thermal synchrotron emission. Bright filament-like features are found protruding (visually) from the accretion disk surface, which are enhancements of synchrotron emission when the magnetic field is roughly aligned with the line-of-sight in the co-moving frame. The features move back and forth as the accretion flow evolves, but their visibility and morphology are robust. We propose that variations and location drifts of the features are responsible for certain X-ray quasi-periodic oscillations (QPOs) observed in black-hole X-ray binaries.

General Relativistic Radiative Transfer and GeneralRelativistic MHD Simulations of Accretion and Outflows of Black Holes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fuerst, Steven V.; /KIPAC, Menlo Park; Mizuno, Yosuke

2007-01-05

We calculate the emission from relativistic flows in black hole systems using a fully general relativistic radiative transfer formulation, with flow structures obtained by general relativistic magneto-hydrodynamic simulations. We consider thermal free-free emission and thermal synchrotron emission. Bright filament-like features protrude (visually) from the accretion disk surface, which are enhancements of synchrotron emission where the magnetic field roughly aligns with the line-of-sight in the co-moving frame. The features move back and forth as the accretion flow evolves, but their visibility and morphology are robust. We propose that variations and drifts of the features produce certain X-ray quasi-periodic oscillations (QPOs) observedmore » in black-hole X-ray binaries.« less

Low cost synthesis of TiO2-C nanocomposite powder for high efficiency visible light photocatalysis

NASA Astrophysics Data System (ADS)

Mohapatra, A. K.; Nayak, J.

2018-04-01

Titanium dioxide-carbon nanocomposite powder was synthesized via a low cost chemical route using oleic acid and titanium tetra-isopropoxide. Since the carbon remained mainly on the surface of the TiO2 nanoparticles, the powder had black color. The composition of the powder was analyzed by X-ray photoelectron spectroscopy and the structure was studied with X-ray diffraction and transmission electron microscopy. The visible photocatalytic activity of the black TiO2 powder was investigated by studying the photo-bleaching of methylene blue under visible light. Our experimental observation showed that the black-TiO2 powder had a higher visible photocatalytic activity compared to the commercial TiO2 powder (P25 Degussa).

Analysis of Ni-HYDRIDE Thin Film after Surface Plasmon Generation by Laser Technique

NASA Astrophysics Data System (ADS)

Violante, V.; Castagna, E.; Sibilia, C.; Paoloni, S.; Sarto, F.

2005-12-01

A nickel hydride thin film was studied by the attenuated total reflection method. The differences in behavior between a "black" film, and a pure nickel film "blank," are shown. The black nickel hydride film has been obtained by a short electrolysis with 1 M Li2SO4 electrolyte in light water, A shift in the minimum of the observed reflected light occurs, together with a change in the minimum shape (i.e. its half-height width increases). These two phenomenon are due to the change in the electronic band structure of the metal induced by electrons added to the lattice by hydrogen. The change of the electronic structure, revealed by the laser coupling conditions, leads us to consider that a hydride phase was created. Both the blank (not hydrogenated) and black (hydrogenated) specimens were taken under He-Ne laser beam at the reflectance minimum angle for about three hours. A SIMS analysis was also implemented to reveal differences in the isotopic composition of Cu, as marker element between the blank and black films, in order to study the coupled effect of electrolysis and plasmon-polariton excitation on LENR processes in condensed matter.

Metal-organic frameworks derived platinum-cobalt bimetallic nanoparticles in nitrogen-doped hollow porous carbon capsules as a highly active and durable catalyst for oxygen reduction reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ying, Jie; Li, Jing; Jiang, Gaopeng

Pt-based nanomaterials are regarded as the most efficient electrocatalysts for the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). However, widespread adoption of PEMFCs requires solutions to major challenges encountered with ORR catalysts, namely high cost, sluggish kinetics, and low durability. In this paper, a new efficient method utilizing Co-based metal-organic frameworks is developed to produce PtCo bimetallic nanoparticles embedded in unique nitrogen-doped hollow porous carbon capsules. The obtained catalyst demonstrates an outstanding ORR performance, with a mass activity that is 5.5 and 13.5 times greater than that of commercial Pt/C and Pt black, respectively. Most importantly,more » the product exhibits dramatically improved durability in terms of both electrochemically active surface area (ECAS) and mass activity compared to commercial Pt/C and Pt black catalysts. Finally, the remarkable ORR performance demonstrated here can be attributed to the structural features of the catalyst (its alloy structure, high dispersion and fine particle size) and the carbon support (its nitrogen dopant, large surface area and hollow porous structure).« less

Metal-organic frameworks derived platinum-cobalt bimetallic nanoparticles in nitrogen-doped hollow porous carbon capsules as a highly active and durable catalyst for oxygen reduction reaction

DOE PAGES

Ying, Jie; Li, Jing; Jiang, Gaopeng; ...

2017-11-29

Pt-based nanomaterials are regarded as the most efficient electrocatalysts for the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). However, widespread adoption of PEMFCs requires solutions to major challenges encountered with ORR catalysts, namely high cost, sluggish kinetics, and low durability. In this paper, a new efficient method utilizing Co-based metal-organic frameworks is developed to produce PtCo bimetallic nanoparticles embedded in unique nitrogen-doped hollow porous carbon capsules. The obtained catalyst demonstrates an outstanding ORR performance, with a mass activity that is 5.5 and 13.5 times greater than that of commercial Pt/C and Pt black, respectively. Most importantly,more » the product exhibits dramatically improved durability in terms of both electrochemically active surface area (ECAS) and mass activity compared to commercial Pt/C and Pt black catalysts. Finally, the remarkable ORR performance demonstrated here can be attributed to the structural features of the catalyst (its alloy structure, high dispersion and fine particle size) and the carbon support (its nitrogen dopant, large surface area and hollow porous structure).« less

Pyrite footprinting of RNA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schlatterer, Joerg C., E-mail: joerg.schlatterer@einstein.yu.edu; Wieder, Matthew S.; Jones, Christopher D.

2012-08-24

Highlights: Black-Right-Pointing-Pointer RNA structure is mapped by pyrite mediated {sup {center_dot}}OH footprinting. Black-Right-Pointing-Pointer Repetitive experiments can be done in a powdered pyrite filled cartridge. Black-Right-Pointing-Pointer High {sup {center_dot}}OH reactivity of nucleotides imply dynamic role in Diels-Alderase catalysis. -- Abstract: In RNA, function follows form. Mapping the surface of RNA molecules with chemical and enzymatic probes has revealed invaluable information about structure and folding. Hydroxyl radicals ({sup {center_dot}}OH) map the surface of nucleic acids by cutting the backbone where it is accessible to solvent. Recent studies showed that a microfluidic chip containing pyrite (FeS{sub 2}) can produce sufficient {sup {center_dot}}OH tomore » footprint DNA. The 49-nt Diels-Alder RNA enzyme catalyzes the C-C bond formation between a diene and a dienophile. A crystal structure, molecular dynamics simulation and atomic mutagenesis studies suggest that nucleotides of an asymmetric bulge participate in the dynamic architecture of the ribozyme's active center. Of note is that residue U42 directly interacts with the product in the crystallized RNA/product complex. Here, we use powdered pyrite held in a commercially available cartridge to footprint the Diels-Alderase ribozyme with single nucleotide resolution. Residues C39 to U42 are more reactive to {sup {center_dot}}OH than predicted by the solvent accessibility calculated from the crystal structure suggesting that this loop is dynamic in solution. The loop's flexibility may contribute to substrate recruitment and product release. Our implementation of pyrite-mediated {sup {center_dot}}OH footprinting is a readily accessible approach to gleaning information about the architecture of small RNA molecules.« less

Potentiometric surface of the Minnekahta Aquifer in the Black Hills area, South Dakota

USGS Publications Warehouse

Strobel, Michael L.; Galloway, Joel M.; Hamade, Ghaith R.; Jarrell, Gregory J.

2000-01-01

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers).The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and springs that originate from the confined aquifers are common around the periphery of the Black Hills.The purpose of this map is to show the potentiometric surface of the Minnekahta aquifer within the study area. The map provides a tool for evaluating ground-water flow directions and hydraulic gradients in the Minnekahta aquifer.

Potentiometric surface of the Inyan Kara Aquifer in the Black Hills area, South Dakota

USGS Publications Warehouse

Strobel, Michael L.; Galloway, Joel M.; Hamade, Ghaith R.; Jarrell, Gregory J.

2000-01-01

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers).The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and springs that originate from the confined aquifers are common around the periphery of the Black Hills.The purpose of this map is to show the potentiometric surface of the Inyan Kara aquifer within the study area. The map provides a tool for evaluating ground-water flow directions and hydraulic gradients in the Inyan Kara aquifer.

Potentiometric surface of the Deadwood Aquifer in the Black Hills area, South Dakota

USGS Publications Warehouse

Strobel, Michael L.; Galloway, Joel M.; Hamade, Ghaith R.; Jarrell, Gregory J.

2000-01-01

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers).The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and springs that originate from the confined aquifers are common around the periphery of the Black Hills.The purpose of this map is to show the potentiometric surface of the Deadwood aquifer within the study area. The map provides a tool for evaluating ground-water flow directions and hydraulic gradients in the Deadwood aquifer.

Potentiometric surface of the Minnelusa Aquifer in the Black Hills area, South Dakota

USGS Publications Warehouse

Strobel, Michael L.; Galloway, Joel M.; Hamade, Ghaith R.; Jarrell, Gregory J.

2000-01-01

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers).The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and springs that originate from the confined aquifers are common around the periphery of the Black Hills.The purpose of this map is to show the potentiometric surface of the Minnelusa aquifer within the study area. The map provides a tool for evaluating ground-water flow directions and hydraulic gradients in the Minnelusa aquifer.

Potentiometric surface of the Madison Aquifer in the Black Hills area, South Dakota

USGS Publications Warehouse

Strobel, Michael L.; Galloway, Joel M.; Hamade, Ghaith R.; Jarrell, Gregory L.

2000-01-01

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers).The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and springs that originate from the confined aquifers are common around the periphery of the Black Hills.The purpose of this map is to show the potentiometric surface of the Madison aquifer within the study area. The map provides a tool for evaluating ground-water flow directions and hydraulic gradients in the Madison aquifer.

In-vacuum scattered light reduction with black cupric oxide surfaces for sensitive fluorescence detection.

PubMed

Norrgard, E B; Sitaraman, N; Barry, J F; McCarron, D J; Steinecker, M H; DeMille, D

2016-05-01

We demonstrate a simple and easy method for producing low-reflectivity surfaces that are ultra-high vacuum compatible, may be baked to high temperatures, and are easily applied even on complex surface geometries. Black cupric oxide (CuO) surfaces are chemically grown in minutes on any copper surface, allowing for low-cost, rapid prototyping, and production. The reflective properties are measured to be comparable to commercially available products for creating optically black surfaces. We describe a vacuum apparatus which uses multiple blackened copper surfaces for sensitive, low-background detection of molecules using laser-induced fluorescence.

About the optical properties of oxidized black silicon structures

NASA Astrophysics Data System (ADS)

Pincik, E.; Brunner, R.; Kobayashi, H.; Mikula, M.; Kučera, M.; Švec, P.; Greguš, J.; Vojtek, P.; Zábudlá, Z.; Imamura, K.; Zahoran, M.

2017-02-01

The paper deals with the optical and morphological properties of thermally oxidized black silicon (OBSi) nano-crystalline specimens produced by the surface structure chemical transfer method (SSCT). This method can produce a nano-crystalline Si black color layer on c-Si with a range of thickness of ∼50 nm to ∼300 nm by the contact of c-Si immersed in chemical solutions HF + H2O2 with a catalytic mesh. We present and discuss mainly the photoluminescence properties of both polished c-Si and OBSi structures, respectively. The similar photoluminescence (PL) behaviors recorded at liquid helium (6 K) and room temperatures on both polished crystalline Si and OBSi samples, respectively, indicate the similar origin of recorded luminescence light. As the positions of PL maxima of OBSi structures are mainly related to the size of Si nanocrystallites and SiO(x), we therefore suppose that the size of the dominant parts of the luminated OBSi nanostructure is pre-determined by the used polishing Si procedure, and/or the distribution function of the number of formed crystallites on their size is very similar. The blue shift of both PL spectra reaching almost value of 0.40 eV observed after the decrease of the sample temperature to 6 K we relate also with the change of the semiconductor band gap width.

Green preparation using black soybeans extract for graphene-based porous electrodes and their applications in supercapacitors

NASA Astrophysics Data System (ADS)

Chu, Hwei-Jay; Lee, Chi-Young; Tai, Nyan-Hwa

2016-08-01

Adopting an in situ construction strategy, green reduction of graphene oxide (GO) and the formation of an open porous structure are simultaneously completed in a one-pot process using an aqueous extract of an anthocyanin-containing plant, black soybean, as a green reducing agent. The reduced GO prepared by the aqueous extract of black soybean (BRGO), and the hydrogel of BRGO are characterized to better understand the nature of BRGO and the evolution of BRGO from GO. Graphene-based porous electrodes for supercapacitors are fabricated using the BRGO hydrogel as a primary material, and the electrochemical performance of the electrodes are further improved when the BRGO porous electrodes are treated in a microwave oven. Owing to the formation of uniformly dispersed nanoparticles on the graphene surface during the microwave treatment, the electrical conductivity of the electrodes improves by four orders of magnitude and the electroactive surface area also increases by over four times, as a consequence, the capacitance is significantly enhanced, reaching a capacitance of 268.4 F g-1 at a charging current of 0.1 A g-1.

Black sea surface temperature anomaly on 5th August 1998 and the ozone layer thickness

NASA Astrophysics Data System (ADS)

Manev, A.; Palazov, K.; Raykov, St.; Ivanov, V.

2003-04-01

BLACK SEA SURFACE TEMPERATURE ANOMALY ON 5th AUGUST 1998 AND THE OZONE LAYER THICKNESS A. Manev , K. Palazov , St. Raykov, V. Ivanov Solar Terrestrial Influences Laboratory, Bulgarian Academy of Sciences amanev@abv.bg This paper focuses on the peculiarities of the Black Sea surface temperature anomaly on 05.08.1998. Researching the daily temperature changes in a number of control fields in the course of 8-10 years, we have found hidden correlations and anomalous deviations in the sea surface temperatures on a global scale. Research proves the statistical reliability of the temperature anomaly on the entire Black Sea surface registered on 04.-05.08.1998. In the course of six days around these dates the temperatures are up to 2°C higher than the maximum temperatures in this period in the other seven years. A more detailed analysis of the dynamics of the anomaly required the investigation of five Black Sea surface characteristic zones of 75x75 km. The analysis covers the period 20 days - 10 days before and 10 days after the anomaly. Investigations aimed at interpreting the reasons for the anomalous heating of the surface waters. We have tried to analyze the correlation between sea surface temperature and the global ozone above the Black Sea by using simultaneously data from the two satellite systems NOAA and TOMS. Methods of processing and comparing the data from the two satellite systems are described. The correlation coefficients values for the five characteristic zones are very high and close, which proves that the character of the correlation ozone - sea surface temperature is the same for the entire Black Sea surface. Despite the high correlation coefficient, we have proved that causality between the two phenomena at the time of the anomaly does not exit.

Thermodynamics of the adsorption of organic molecules on graphitized carbon black modified with a monolayer of 5-hydroxy-6-methyluracil

NASA Astrophysics Data System (ADS)

Gus'kov, V. Yu.; Ivanov, S. P.; Shaikhitdinova, Yu. F.; Kudasheva, F. Kh.

2016-10-01

Thermodynamic characteristics of the adsorption of alkanes, alcohols, arenes, and esters on graphitized carbon black with a deposited monolayer (0.17%) of 5-hydroxy-6-methyluracil are studied by means of inverse gas chromatography at infinite dilution. It is established that size effects (violation of the additivity of molar changes in internal energy and the entropy of adsorption for pairs of molecules of one homologous series that differ by one methyl group) are observed when organic molecules are adsorbed on the surface of the resulting adsorbent. The size effects are similar to those observed when 1% 5-hydroxy-6-methyluracil is deposited on graphitized carbon black. It is concluded that the observed violation of additivity is associated with cavities in the supramolecular structure.

Active black holes: Relevant plasma structures, regimes and processes involving all phase space

NASA Astrophysics Data System (ADS)

Coppi, Bruno

2011-03-01

The presented theory is motivated by the growing body of experimental information on the characteristics, connected with relevant spectral, time, and space resolutions, of the radiation emission from objects considered as rotating black holes. In the immediate surroundings of these objects, three plasma regions are identified: an innermost Buffer Region, an intermediate Three-regime Region, and a Structured Peripheral Region. In the last region, a Composite Disk Structure made of a sequence of plasma rings corresponding to the formation of closed magnetic surfaces is considered to be present and to allow intermittent accretion flows along the relevant separatrices. The nonlinear ``Master Equation'' describing composite disk structures is derived and solved in appropriate asymptotic limits. A ring configuration, depending on the state of the plasma at the microscopic level: (i) can be excluded from forming given the strongly nonthermal nature of the electron distribution (in momentum space) within the Three-regime Region allowing the onset of a spiral structure; the observed High Frequency Quasi Periodic Oscillations are associated with these tridimensional structures; (ii) may be allowed to propagate to the outer edge of the Buffer Region where successive rings carrying currents in opposite directions are ejected vertically (in opposite directions) and originate the observed jets; or (iii) penetrates in the Three-regime Region and is dissipated before reaching the outer edge of the Buffer Region. The absence of a coherent composite disk structure guiding accretion in the presence of a significant magnetic field background is suggested to characterize quiescent black holes.

Structural insight into the role of Streptococcus parasanguinis Fap1 within oral biofilm formation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garnett, James A.; Simpson, Peter J.; Taylor, Jonathan

2012-01-06

Highlights: Black-Right-Pointing-Pointer Crystal structure of Streptococcus parasanguinis Fap1-NR{sub {alpha}} at pH 5.0. Black-Right-Pointing-Pointer pH-dependent conformational changes mediated through electrostatic potential of Fap1-NR{sub {alpha}}. Black-Right-Pointing-Pointer Fap1 facilitates pH-dependent biofilms. Black-Right-Pointing-Pointer We model inter-Fap1 biofilm interactions. -- Abstract: The fimbriae-associated protein 1 (Fap1) is a major adhesin of Streptococcus parasanguinis, a primary colonizer of the oral cavity that plays an important role in the formation of dental plaque. Fap1 is an extracellular adhesive surface fibre belonging to the serine-rich repeat protein (SRRP) family, which plays a central role in the pathogenesis of streptococci and staphylococci. The N-terminal adhesive region of Fap1 (Fap1-NR)more » is composed of two domains (Fap1-NR{sub {alpha}} and Fap1-NR{sub {beta}}) and is projected away from the bacterial surface via the extensive serine-rich repeat region, for adhesion to the salivary pellicle. The adhesive properties of Fap1 are modulated through a pH switch in which a reduction in pH results in a rearrangement between the Fap1-NR{sub {alpha}} and Fap1-NR{sub {beta}} domains, which assists in the survival of S. parasanguinis in acidic environments. We have solved the structure of Fap1-NR{sub {alpha}} at pH 5.0 at 3.0 A resolution and reveal how subtle rearrangements of the 3-helix bundle combined with a change in electrostatic potential mediates 'opening' and activation of the adhesive region. Further, we show that pH-dependent changes are critical for biofilm formation and present an atomic model for the inter-Fap1-NR interactions which have been assigned an important role in the biofilm formation.« less

33 CFR 118.160 - Vertical clearance gauges.

Code of Federal Regulations, 2010 CFR

2010-07-01

... of the foot marks, read from top to bottom. Each gauge must be installed on the end of the right... directly on the bridge channel pier or pier protection structure if the surface is suitable and has... be marked by black numerals and foot marks on a white background. Paint, if used, must be of good...

33 CFR 118.160 - Vertical clearance gauges.

Code of Federal Regulations, 2011 CFR

2011-07-01

... of the foot marks, read from top to bottom. Each gauge must be installed on the end of the right... directly on the bridge channel pier or pier protection structure if the surface is suitable and has... be marked by black numerals and foot marks on a white background. Paint, if used, must be of good...

Initial Studies of the Bidirectional Reflectance Distribution Function of Multi-Walled Carbon Nanotube Structures for Stray Light Control Applications

NASA Technical Reports Server (NTRS)

Butler, J. J.; Tveekrem, J. L.; Quijada, M. A.; Getty, S. A.; Hagopian, J. G.; Georglev, G. T.

2010-01-01

The presentation examines the application of low reflectance surfaces in optical instruments, multi-walled carbon nanotubes (MWCNTs), research objects, MWCNT samples, measurement of 8 deg. directional/hemispherical reflectance, measurement of bidirectional reflectance distribution function (BRDF), and what is current the "blackest ever black".

Investigation of the surface composition of electrodeposited black chromium by X-ray photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Survilienė, S.; Češūnienė, A.; Jasulaitienė, V.; Jurevičiūtė, I.

2015-01-01

The paper reviews black chromium electrodeposited from a trivalent chromium bath containing ZnO as a second main component. The chemical compositions of the top layers of the black chromium coatings were studied by the X-ray photoelectron spectroscopy method. The surface of black chromium was found to be almost entirely covered with organic substances. To gain information on the state of each element in the deposit bulk, the layer-by-layer etching of the black chromium surface with argon gas was used. Analysis of XPS spectra has shown that the top layers of black chromium without zinc are composed of various Cr(III) components, organic substances and metallic Cr, whereas metallic Cr is almost absent in black chromium containing some amount of Zn(II) compounds. The ratios of metal/oxide phases were found to be 10/27 and 2/28 for black chromium without and with zinc, respectively. It has been determined that owing to the presence of ZnO in the Cr(III) bath, the percentage of metallic chromium is substantially reduced in black chromium which is quite important for good solar selective characteristics of the coating. The results confirm some of earlier observations and provide new information on the composition of the near-surface layers.

Cryo-Etched Black Silicon for Use as Optical Black

NASA Technical Reports Server (NTRS)

Yee, Karl Y.; White, Victor E.; Mouroulis, Pantazis; Eastwood, Michael L.

2011-01-01

Stray light reflected from the surface of imaging spectrometer components in particular, the spectrometer slit degrade the image quality. A technique has been developed for rapid, uniform, and cost-effective black silicon formation based on inductively coupled plasma (ICP) etching at cryogenic temperatures. Recent measurements show less than 1-percent total reflectance from 350 2,500 nm of doped black silicon formed in this way, making it an excellent option for texturing of component surfaces for reduction of stray light. Oxygen combines with SF6 + Si etch byproducts to form a passivation layer atop the Si when the etch is performed at cryogenic temperatures. Excess flow of oxygen results in micromasking and the formation of black silicon. The process is repeatable and reliable, and provides control over etch depth and sidewall profile. Density of the needles can be controlled to some extent. Regions to be textured can be patterned lithographically. Adhesion is not an issue as the nanotips are part of the underlying substrate. This is in contrast to surface growth/deposition techniques such as carbon nanotubes (CNTs). The black Si surface is compatible with wet processing, including processing with solvents, the textured surface is completely inorganic, and it does not outgas. In radiometry applications, optical absorbers are often constructed using gold black or CNTs. This black silicon technology is an improvement for these types of applications.

Blackfolds, plane waves and minimal surfaces

NASA Astrophysics Data System (ADS)

Armas, Jay; Blau, Matthias

2015-07-01

Minimal surfaces in Euclidean space provide examples of possible non-compact horizon geometries and topologies in asymptotically flat space-time. On the other hand, the existence of limiting surfaces in the space-time provides a simple mechanism for making these configurations compact. Limiting surfaces appear naturally in a given space-time by making minimal surfaces rotate but they are also inherent to plane wave or de Sitter space-times in which case minimal surfaces can be static and compact. We use the blackfold approach in order to scan for possible black hole horizon geometries and topologies in asymptotically flat, plane wave and de Sitter space-times. In the process we uncover several new configurations, such as black helicoids and catenoids, some of which have an asymptotically flat counterpart. In particular, we find that the ultraspinning regime of singly-spinning Myers-Perry black holes, described in terms of the simplest minimal surface (the plane), can be obtained as a limit of a black helicoid, suggesting that these two families of black holes are connected. We also show that minimal surfaces embedded in spheres rather than Euclidean space can be used to construct static compact horizons in asymptotically de Sitter space-times.

Crystal structure of the Candida albicans Kar3 kinesin motor domain fused to maltose-binding protein

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delorme, Caroline; Joshi, Monika; Allingham, John S., E-mail: allinghj@queensu.ca

2012-11-30

Highlights: Black-Right-Pointing-Pointer The Candida albicans Kar3 motor domain structure was solved as a maltose-binding protein fusion. Black-Right-Pointing-Pointer The electrostatic surface and part of the ATPase pocket of the motor domain differs markedly from other kinesins. Black-Right-Pointing-Pointer The MBP-Kar3 interface highlights a new site for intramolecular or intermolecular interactions. -- Abstract: In the human fungal pathogen Candida albicans, the Kinesin-14 motor protein Kar3 (CaKar3) is critical for normal mitotic division, nuclear fusion during mating, and morphogenic transition from the commensal yeast form to the virulent hyphal form. As a first step towards detailed characterization of this motor of potential medical significance,more » we have crystallized and determined the X-ray structure of the motor domain of CaKar3 as a maltose-binding protein (MBP) fusion. The structure shows strong conservation of overall motor domain topology to other Kar3 kinesins, but with some prominent differences in one of the motifs that compose the nucleotide-binding pocket and the surface charge distribution. The MBP and Kar3 modules are arranged such that MBP interacts with the Kar3 motor domain core at the same site where the neck linker of conventional kinesins docks during the 'ATP state' of the mechanochemical cycle. This site differs from the Kar3 neck-core interface in the recent structure of the ScKar3Vik1 heterodimer. The position of MBP is also completely distinct from the Vik1 subunit in this complex. This may suggest that the site of MBP interaction on the CaKar3 motor domain provides an interface for the neck, or perhaps a partner subunit, at an intermediate state of its motile cycle that has not yet been observed for Kinesin-14 motors.« less

On the existence of black holes in distorted Schwarzschild spacetime using marginally trapped surfaces

NASA Astrophysics Data System (ADS)

Pilkington, Terry

The classical definition of a black hole in terms of an event horizon relies on global properties of the spacetime. Realistic black holes have matter distributions surrounding them, which negates the asymptotic flatness needed for an event horizon. Using the (quasi-)local concept of marginally trapped surfaces, we investigate the Schwarzschild spacetime distorted by an axisymmetric matter distribution. We determine that it is possible to locate a future outer trapping horizon for a given foliation within certain value ranges of multipole moments. Furthermore, we show that there are no marginally trapped surfaces for arbitrary values of the multipole moment magnitudes. KEYWORDS: SCHWARZSCHILD; BLACK HOLE; DISTORTED SPACETIME; MARGINALLY TRAPPED SURFACE; FUTURE OUTER TRAPPING HORIZON

Black silicon with self-cleaning surface prepared by wetting processes

PubMed Central

2013-01-01

This paper reports on a simple method to prepare a hydrophobic surface on black silicon, which is fabricated by metal-assisted wet etching. To increase the reaction rate, the reaction device was placed in a heat collection-constant temperature type magnetic stirrer and set at room temperature. It was demonstrated that the micro- and nanoscale spikes on the black silicon made the surface become hydrophobic. As the reaction rate increases, the surface hydrophobicity becomes more outstanding and presents self-cleaning until the very end. The reflectance of the black silicon is drastically suppressed over a broad spectral range due to the unique geometry, which is effective for the enhancement of absorption. PMID:23941184

Geomorphic evidence of deformation in the northern part of the New Madrid seismic zone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fischer, K.J.; Schumm, S.A.

1993-03-01

A geomorphic evaluation of the northern portion of the New Madrid seismic zone between Hickman, KY and Osceola, AR has identified several locations where anomalous geomorphic conditions indicate possible surface deformation. For example, the slope, course, sinuosity and dimensions of the Mississippi River have been affected by the Lake County uplift and Tertiary-age sediments are exposed in its channel. Also, anomalous channel behavior near Caruthersville, MO and Barfield, AR suggests that these two reaches of the Mississippi River are structurally controlled. The Black River northeast of Pocahontas follows a peculiar angular course that suggests fracture control, and course changes ofmore » the Black, St. Francis, and Little Rivers may be related to subsurface faulting, uplift, or downwarping, as well as to differential compaction or the effects of groundwater withdrawal. The topography of Crowley's Ridge suggests that, between Jonesboro and Castor River, it is composed of at least three structural blocks, that are bounded by northeast-southwest trending faults. Near Jonesboro, river patterns appear to be affected by the Jonesboro, AR pluton. The geomorphic evaluation has identified anomalous surface features in the New Madrid seismic zone. Some can be directly linked to mapped structures in the region, whereas others may result from previously unidentified areas of surface deformation. The identification of these anomalies should provide direction for scientists who are employing subsurface techniques in order to locate tectonic deformation in the area.« less

Resolution of anisotropic and shielded highly conductive layers using 2-D electromagnetic modelling in the Rhine Graben and Black Forest

NASA Astrophysics Data System (ADS)

Tezkan, Bülent; Červ, Václav; Pek, Josef

1992-12-01

Anisotropy in magnetotelluric (MT) data has been found very often and has been explained as the result of local structures of different conductivities. In this paper, an observed anisotropy in MT data is not interpreted qualitatively in terms of local structures but is modelled quantitatively by a quasi-anisotropic layer. Besides the MT transfer functions, measurements of the vertical magnetic component are required. The second goal of this paper is to describe a method which permits the resolution of mid-crustal conductive layers in the presence of an additional high-conductivity layer at the surface. This method is possible in a two-dimensional (2-D) situation that limits the spatial extension of the surface structure. Again, vertical magnetic field recordings are necessary, but the phase of the E-polarization with respect to the 2-D structure is the most sensitive parameter. Using two field sites in Southern Germany, it has been possible to give a quantitative explanation of anisotropy and an improved depth resolution, and to derive an integrated conductivity of the highly conductive mid-crustal layers using MT and geomagnetic depth sounding data. The anisotropic highly conductive layer is located 12 km beneath the poorly conductive Black Forest crystalline rocks, whereas it is at a depth of 6 km beneath the highly conductive Rhine Graben sediments.

Spatial variability of the Black Sea surface temperature from high resolution modeling and satellite measurements

NASA Astrophysics Data System (ADS)

Mizyuk, Artem; Senderov, Maxim; Korotaev, Gennady

2016-04-01

Large number of numerical ocean models were implemented for the Black Sea basin during last two decades. They reproduce rather similar structure of synoptical variability of the circulation. Since 00-s numerical studies of the mesoscale structure are carried out using high performance computing (HPC). With the growing capacity of computing resources it is now possible to reconstruct the Black Sea currents with spatial resolution of several hundreds meters. However, how realistic these results can be? In the proposed study an attempt is made to understand which spatial scales are reproduced by ocean model in the Black Sea. Simulations are made using parallel version of NEMO (Nucleus for European Modelling of the Ocean). A two regional configurations with spatial resolutions 5 km and 2.5 km are described. Comparison of the SST from simulations with two spatial resolutions shows rather qualitative difference of the spatial structures. Results of high resolution simulation are compared also with satellite observations and observation-based products from Copernicus using spatial correlation and spectral analysis. Spatial scales of correlations functions for simulated and observed SST are rather close and differs much from satellite SST reanalysis. Evolution of spectral density for modelled SST and reanalysis showed agreed time periods of small scales intensification. Using of the spectral analysis for satellite measurements is complicated due to gaps. The research leading to this results has received funding from Russian Science Foundation (project № 15-17-20020)

77 FR 18997 - Rim Lakes Forest Restoration Project; Apache-Sitgreavese National Forest, Black Mesa Ranger...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-29

... uncharacteristicly high-severity wild fires, which can lead to loss of entire stands during one fire event. About 67..., fire, and wind. The purpose of the project is to restore forest health, move forests toward an uneven-aged forest structure with all age classes represented, and restore frequent, periodic surface fire as...

Rheological and electrical properties of hybrid nanocomposites of epoxy resins filled with graphite nanoplatelets and carbon black.

PubMed

Truong, Quang-Trung; Lee, Seon-Suk; Lee, Dai-Soo

2011-02-01

Graphite nanoplatelets (GNP) were prepared by microwave irradiation of natural graphites intercalated with ferric chloride in nitromethane (GIC). Intercalated structure of GIC was confirmed by X-ray diffraction patterns. SEM images of GIC after microwave irradiation showed the exfoliation of GIC, the formation of GNPs. Hybrid nanocomposites of bisphenol-A type epoxy resins filled with GNP and a conductive carbon black (CB) were prepared and rheological and electrical properties of the nanocomposites were investigated. Viscosity and electrical surface resistivity of the nanocomposites showed minima at certain mixtures of GNP and CB in the epoxy resins.

Antireflection and SiO2 Surface Passivation by Liquid-Phase Chemistry for Efficient Black Silicon Solar Cells: Preprint

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yuan, H. C.; Oh, J.; Zhang, Y.

2012-06-01

We report solar cells with both black Si antireflection and SiO2 surface passivation provided by inexpensive liquid-phase chemistry, rather than by conventional vacuum-based techniques. Preliminary cell efficiency has reached 16.4%. Nanoporous black Si antireflection on crystalline Si by aqueous etching promises low surface reflection for high photon utilization, together with lower manufacturing cost compared to vacuum-based antireflection coating. Ag-nanoparticle-assisted black Si etching and post-etching chemical treatment recently developed at NREL enables excellent control over the pore diameter and pore separation. Performance of black Si solar cells, including open-circuit voltage, short-circuit current density, and blue response, has benefited from these improvements.more » Prior to this study, our black Si solar cells were all passivated by thermal SiO2 produced in tube furnaces. Although this passivation is effective, it is not yet ideal for ultra-low-cost manufacturing. In this study, we report, for the first time, the integration of black Si with a proprietary liquid-phase deposition (LPD) passivation from Natcore Technology. The Natcore LPD forms a layer of <10-nm SiO2 on top of the black Si surface in a relatively mild chemical bath at room temperature. We demonstrate black Si solar cells with LPD SiO2 with a spectrum-weighted average reflection lower than 5%, similar to the more costly thermally grown SiO2 approach. However, LPD SiO2 provides somewhat better surface-passivation quality according to the lifetime analysis by the photo-conductivity decay measurement. Moreover, black Si solar cells with LPD SiO2 passivation exhibit higher spectral response at short wavelength compared to those passivated by thermally grown SiO2. With further optimization, the combination of aqueous black Si etching and LPD could provide a pathway for low-cost, high-efficiency crystalline Si solar cells.« less

Nuclear surface diffuseness revealed in nucleon-nucleus diffraction

NASA Astrophysics Data System (ADS)

Hatakeyama, S.; Horiuchi, W.; Kohama, A.

2018-05-01

The nuclear surface provides useful information on nuclear radius, nuclear structure, as well as properties of nuclear matter. We discuss the relationship between the nuclear surface diffuseness and elastic scattering differential cross section at the first diffraction peak of high-energy nucleon-nucleus scattering as an efficient tool in order to extract the nuclear surface information from limited experimental data involving short-lived unstable nuclei. The high-energy reaction is described by a reliable microscopic reaction theory, the Glauber model. Extending the idea of the black sphere model, we find one-to-one correspondence between the nuclear bulk structure information and proton-nucleus elastic scattering diffraction peak. This implies that we can extract both the nuclear radius and diffuseness simultaneously, using the position of the first diffraction peak and its magnitude of the elastic scattering differential cross section. We confirm the reliability of this approach by using realistic density distributions obtained by a mean-field model.

Improved passivation effect in multicrystalline black silicon by chemical solution pre-treatment

NASA Astrophysics Data System (ADS)

Jiang, Ye; Shen, Honglie; Pu, Tian; Zheng, Chaofan

2018-04-01

Though black silicon has excellent anti-reflectance property, its passivation is one of the main technical bottlenecks due to its large specific surface area. In this paper, multicrystalline black silicon is fabricated by metal assisted chemical etching, and is rebuilt in low concentration alkali solution. Different solution pre-treatment is followed to make surface modification on black silicon before Al2O3 passivation by atomic layer deposition. HNO3 and H2SO4 + H2O2 solution pre-treatment makes the silicon surface become hydrophilic, with contact angle decrease from 117.28° to about 30°. It is demonstrated that when the pre-treatment solution is nitric acid, formed ultrathin SiO x layer between Al2O3 layer and black silicon is found to increase effective carrier lifetime to 72.64 µs, which is obviously higher than that of the unpassivated black silicon. The passivation stacks of SiO x /Al2O3 are proved to be effective double layers for nanoscaled multicrystalline silicon surface.

Full-Color Biomimetic Photonic Materials with Iridescent and Non-Iridescent Structural Colors

PubMed Central

Kawamura, Ayaka; Kohri, Michinari; Morimoto, Gen; Nannichi, Yuri; Taniguchi, Tatsuo; Kishikawa, Keiki

2016-01-01

The beautiful structural colors in bird feathers are some of the brightest colors in nature, and some of these colors are created by arrays of melanin granules that act as both structural colors and scattering absorbers. Inspired by the color of bird feathers, high-visibility structural colors have been created by altering four variables: size, blackness, refractive index, and arrangement of the nano-elements. To control these four variables, we developed a facile method for the preparation of biomimetic core-shell particles with melanin-like polydopamine (PDA) shell layers. The size of the core-shell particles was controlled by adjusting the core polystyrene (PSt) particles’ diameter and the PDA shell thicknesses. The blackness and refractive index of the colloidal particles could be adjusted by controlling the thickness of the PDA shell. The arrangement of the particles was controlled by adjusting the surface roughness of the core-shell particles. This method enabled the production of both iridescent and non-iridescent structural colors from only one component. This simple and novel process of using core-shell particles containing PDA shell layers can be used in basic research on structural colors in nature and their practical applications. PMID:27658446

Full-Color Biomimetic Photonic Materials with Iridescent and Non-Iridescent Structural Colors.

PubMed

Kawamura, Ayaka; Kohri, Michinari; Morimoto, Gen; Nannichi, Yuri; Taniguchi, Tatsuo; Kishikawa, Keiki

2016-09-23

The beautiful structural colors in bird feathers are some of the brightest colors in nature, and some of these colors are created by arrays of melanin granules that act as both structural colors and scattering absorbers. Inspired by the color of bird feathers, high-visibility structural colors have been created by altering four variables: size, blackness, refractive index, and arrangement of the nano-elements. To control these four variables, we developed a facile method for the preparation of biomimetic core-shell particles with melanin-like polydopamine (PDA) shell layers. The size of the core-shell particles was controlled by adjusting the core polystyrene (PSt) particles' diameter and the PDA shell thicknesses. The blackness and refractive index of the colloidal particles could be adjusted by controlling the thickness of the PDA shell. The arrangement of the particles was controlled by adjusting the surface roughness of the core-shell particles. This method enabled the production of both iridescent and non-iridescent structural colors from only one component. This simple and novel process of using core-shell particles containing PDA shell layers can be used in basic research on structural colors in nature and their practical applications.

UNDERSTANDING SYSTEMATIC MEASUREMENT ERROR IN THERMAL-OPTICAL ANALYSIS FOR PM BLACK CARBON USING RESPONSE SURFACES AND SURFACE CONFIDENCE INTERVALS

EPA Science Inventory

Results from a NIST-EPA Interagency Agreement on Understanding Systematic Measurement Error in Thermal-Optical Analysis for PM Black Carbon Using Response Surfaces and Surface Confidence Intervals will be presented at the American Association for Aerosol Research (AAAR) 24th Annu...

Contribution of mesoscale eddies to Black Sea ventilation

NASA Astrophysics Data System (ADS)

Capet, Arthur; Mason, Evan; Pascual, Ananda; Grégoire, Marilaure

2017-04-01

The shoaling of the Black Sea oxycline is one of the most urgent environmental issues in the Black Sea. The permanent oxycline derives directly from the Black Sea permanent stratification and has shoaled alarmingly in the last decades, due to a shifting balance between oxygen consumption and ventilation processes (Capet et al. 2016). The understanding of this balance is thus of the utmost importance and requires to quantify 1) the export of nutrients and organic materials from the shelf regions to the open sea and 2) the ventilation processes. These two processes being influenced by mesoscale features, it is critical to understand the role of the semi-permanent mesoscale structures in horizontal (center/periphery) and vertical (diapycnal and isopycnal) exchanges. A useful insight can be obtained by merging observations from satellite altimeter and in situ profilers (ARGO). In such composite analyses, eddies are first automatically identified and tracked from altimeter data (Mason et al. 2014, py-eddy-tracker). Vertical ARGO profiles are then expressed in terms of their position relative to eddy centers and radii. Derived statistics indicate how consistently mesoscale eddies alter the vertical structure, and provide a deeper understanding of the associated horizontal and vertical fluxes. However, this data-based approach is limited in the Black Sea due to the lower quality of gridded altimetric products in the vicinity of the coast, where semi-permanent mesoscale structures prevail. To complement the difficult analysis of this sparse dataset, a compositing methodology. is also applied to model outputs from the 5km GHER-BHAMBI Black Sea implementation (CMEMS BS-MFC). Characteristic biogeochemical anomalies associated with eddies in the model are analyzed per se, and compared to the observation-based analysis. Capet, A., Stanev, E. V., Beckers, J.-M., Murray, J. W., and Grégoire, M.: Decline of the Black Sea oxygen inventory, Biogeosciences, 13, 1287-1297, doi:10.5194/bg-13-1287-2016, 2016. Mason, Evan, Ananda Pascual, and James C. McWilliams. "A new sea surface height-based code for oceanic mesoscale eddy tracking." Journal of Atmospheric and Oceanic Technology 31.5 (2014): 1181-1188.

Sulfur-carbon nanocomposite cathodes improved by an amphiphilic block copolymer for high-rate lithium-sulfur batteries.

PubMed

Fu, Yongzhu; Su, Yu-Sheng; Manthiram, Arumugam

2012-11-01

A sulfur-carbon nanocomposite consisting of a commercial high-surface-area carbon (i.e., Black Pearls 2000, BET surface area >1000 m² g⁻¹) and sulfur has been synthesized by an in situ deposition method. The nanocomposite is in the form of agglomerated nanoparticles, with the micropores within the carbon filled with sulfur and the mesopores on the carbon surface almost completely covered by sulfur. The BET surface area of the nanocomposite containing a sulfur content of 63.5 wt % is significantly reduced to only 40 m² g⁻¹. Cathodes containing the nanocomposite and Pluronic F-127 block copolymer, which partially replaces the polyvinylidene fluoride binder, were prepared and evaluated in lithium cells by cyclic voltammetry and galvanostatic cycling. The nanocomposite cathodes with the copolymer show improved electrochemical stability and cyclability. The Pluronic copolymer helps retain a uniform nanocomposite structure within the electrodes, improving the electrochemical contact, which was manifested by scanning electron microscopy and electrochemical impedance spectroscopy. The sulfur-Black Pearls nanocomposite with the Pluronic copolymer as an additive in the electrodes is promising for high-rate rechargeable lithium-sulfur batteries.

Surface oxidation: an effective way to induce piezoelectricity in 2D black phosphorus

NASA Astrophysics Data System (ADS)

Li, Jiabin; Zhao, Ting; He, Chaoyu; Zhang, Kaiwang

2018-03-01

In this letter, first-principles methods are employed to investigate the elastic stiffness and piezoelectric tensors of surface-oxidized black phosphorene. Our results show that the piezoelectric coefficients d 11 and d 12 for surface-oxidized black phosphorene are 88.54 pm V-1 and  -1.94 pm V-1, respectively, which are comparable to those of group-IV monochalcogenides and more remarkable than those of the experimentally viable h-BN and MoS2. These results indicate that surface-oxidization is an effective way to make black phosphorene into an excellent piezoelectric material for potential applications in sensors, actuators, electric field generators and any other applications requiring electrical and mechanical energy conversion. We expect further experimental exploration on this interesting result to confirm our predictions.

Use of isotopic and hydrometric monitoring methods to partition hydrologic contributions to forested wetlands in the Upper Peninsula of Michigan

NASA Astrophysics Data System (ADS)

Van Grinsven, M. J.; Pypker, T. G.; Kolka, R. K.

2012-12-01

As a result of their landscape position and physical soil properties, northern forested wetlands are capable of retaining springtime snowmelt, rain and near surface groundwater inputs into the growing season. Hydrological conditions such as source water chemistry, duration of inundation, and magnitude of water table fluctuations are affected by the relative contribution of snow, rain, and groundwater sources, and in turn these hydrological conditions strongly influence the structure and function of northern forested wetlands. Black ash (Fraxinus nigra) is a facultative wet tree species, and is known to occur in 23 U.S. states and 7 Canadian provinces in northeastern North America. Black ash trees have ecological, economic, and cultural significance, and are currently threatened by the rapid expansion of the exotic emerald ash borer (Burprestidae: Agrilus planipennis). Since its initial detection in 2002 near Detroit, MI, the emerald ash borer has killed millions of ash trees in 15 U.S. states and 2 Canadian provinces. There is very little known about black ash wetland hydrology and ecology, and as a result of the looming infestation, there is a critical need to gain a better understanding of the hydrology in undisturbed ecosystems. The main objective of this study is to partition source water contributions in black ash wetlands in the western Upper Peninsula of Michigan. We hypothesize that snowmelt and near surface groundwater supply the majority of water to these wetlands annually, and summer rain is readily removed from the system through the evapotranspiration pathway. Hydrometric monitoring methods were used in conjunction with isotopic analysis using a linear mixing model to characterize source water contributions in nine black ash wetlands. The results suggest a connection with near surface groundwater during spring and early summer, and a short residence time for rain water following summer storm events. The outcome of this research aims to inform land managers in northeastern North America about the natural hydrologic condition of black ash wetlands, and provide baseline data that underscores potential water and forest resource impacts of current and future emerald ash borer infestations.

Flexible thin-film black gold membranes with ultrabroadband plasmonic nanofocusing for efficient solar vapour generation.

PubMed

Bae, Kyuyoung; Kang, Gumin; Cho, Suehyun K; Park, Wounjhang; Kim, Kyoungsik; Padilla, Willie J

2015-12-14

Solar steam generation has been achieved by surface plasmon heating with metallic nanoshells or nanoparticles, which have inherently narrow absorption bandwidth. For efficient light-to-heat conversion from a wider solar spectrum, we employ adiabatic plasmonic nanofocusing to attain both polarization-independent ultrabroadband light absorption and high plasmon dissipation loss. Here we demonstrate large area, flexible thin-film black gold membranes, which have multiscale structures of varying metallic nanoscale gaps (0-200 nm) as well as microscale funnel structures. The adiabatic nanofocusing of self-aggregated metallic nanowire bundle arrays produces average absorption of 91% at 400-2,500 nm and the microscale funnel structures lead to average reflection of 7% at 2.5-17 μm. This membrane allows heat localization within the few micrometre-thick layer and continuous water provision through micropores. We efficiently generate water vapour with solar thermal conversion efficiency up to 57% at 20 kW m(-2). This new structure has a variety of applications in solar energy harvesting, thermoplasmonics and related technologies.

Flexible thin-film black gold membranes with ultrabroadband plasmonic nanofocusing for efficient solar vapour generation

PubMed Central

Bae, Kyuyoung; Kang, Gumin; Cho, Suehyun K.; Park, Wounjhang; Kim, Kyoungsik; Padilla, Willie J.

2015-01-01

Solar steam generation has been achieved by surface plasmon heating with metallic nanoshells or nanoparticles, which have inherently narrow absorption bandwidth. For efficient light-to-heat conversion from a wider solar spectrum, we employ adiabatic plasmonic nanofocusing to attain both polarization-independent ultrabroadband light absorption and high plasmon dissipation loss. Here we demonstrate large area, flexible thin-film black gold membranes, which have multiscale structures of varying metallic nanoscale gaps (0–200 nm) as well as microscale funnel structures. The adiabatic nanofocusing of self-aggregated metallic nanowire bundle arrays produces average absorption of 91% at 400–2,500 nm and the microscale funnel structures lead to average reflection of 7% at 2.5–17 μm. This membrane allows heat localization within the few micrometre-thick layer and continuous water provision through micropores. We efficiently generate water vapour with solar thermal conversion efficiency up to 57% at 20 kW m−2. This new structure has a variety of applications in solar energy harvesting, thermoplasmonics and related technologies. PMID:26657535

The 2.1 Ga old Francevillian biota: biogenicity, taphonomy and biodiversity.

PubMed

El Albani, Abderrazak; Bengtson, Stefan; Canfield, Donald E; Riboulleau, Armelle; Rollion Bard, Claire; Macchiarelli, Roberto; Ngombi Pemba, Lauriss; Hammarlund, Emma; Meunier, Alain; Moubiya Mouele, Idalina; Benzerara, Karim; Bernard, Sylvain; Boulvais, Philippe; Chaussidon, Marc; Cesari, Christian; Fontaine, Claude; Chi-Fru, Ernest; Garcia Ruiz, Juan Manuel; Gauthier-Lafaye, François; Mazurier, Arnaud; Pierson-Wickmann, Anne Catherine; Rouxel, Olivier; Trentesaux, Alain; Vecoli, Marco; Versteegh, Gerard J M; White, Lee; Whitehouse, Martin; Bekker, Andrey

2014-01-01

The Paleoproterozoic Era witnessed crucial steps in the evolution of Earth's surface environments following the first appreciable rise of free atmospheric oxygen concentrations ∼2.3 to 2.1 Ga ago, and concomitant shallow ocean oxygenation. While most sedimentary successions deposited during this time interval have experienced thermal overprinting from burial diagenesis and metamorphism, the ca. 2.1 Ga black shales of the Francevillian B Formation (FB2) cropping out in southeastern Gabon have not. The Francevillian Formation contains centimeter-sized structures interpreted as organized and spatially discrete populations of colonial organisms living in an oxygenated marine ecosystem. Here, new material from the FB2 black shales is presented and analyzed to further explore its biogenicity and taphonomy. Our extended record comprises variably sized, shaped, and structured pyritized macrofossils of lobate, elongated, and rod-shaped morphologies as well as abundant non-pyritized disk-shaped macrofossils and organic-walled acritarchs. Combined microtomography, geochemistry, and sedimentary analysis suggest a biota fossilized during early diagenesis. The emergence of this biota follows a rise in atmospheric oxygen, which is consistent with the idea that surface oxygenation allowed the evolution and ecological expansion of complex megascopic life.

Effects of different black mediators on the shear strength of orthodontic bracket to the enamel treated with Nd-Yag laser

NASA Astrophysics Data System (ADS)

Huang, Shun-Te; Lin, I.-Shueng; Tsai, Chi-Cheng

1995-04-01

The Nd:YAG laser has ablation, crack, and crater effects on the dental enamel through black mediators which are very similar to the acid etching effects of phosphoric acid. This study was designed for searching how the different black mediators influence the shear strengths of the brackets bound to the enamel surfaces which were treated with the Nd:YAG laser. 90 bovine enamels divided into 5 groups were painted with 5 kinds of black mediators including Chinese ink, oil ink, black ball pen, water ink and black transfer paper. The enamel surfaces painted with black mediators were then radiated by Nd:YAG laser (ADL; American Dental Laser 300dl, power: 20 pps, 87.5 mj). Orthodontic brackets were bonded to the radiated surfaces. Then the shear strengths of the brackets to the enamels were measured by Instron. The results showed that the Chinese ink group and oil ink group has the strongest shear strength, ball pen group and water ink group showed the second strength, and the transfer paper group has the lowest shear strength. In addition, scanning electronic microscope also was used to observe the topographic changes of the enamel surfaces induced by the laser ablation.

Wind and solar powered turbine

NASA Technical Reports Server (NTRS)

Wells, I. D.; Koh, J. L.; Holmes, M. (Inventor)

1984-01-01

A power generating station having a generator driven by solar heat assisted ambient wind is described. A first plurality of radially extendng air passages direct ambient wind to a radial flow wind turbine disposed in a centrally located opening in a substantially disc-shaped structure. A solar radiation collecting surface having black bodies is disposed above the fist plurality of air passages and in communication with a second plurality of radial air passages. A cover plate enclosing the second plurality of radial air passages is transparent so as to permit solar radiation to effectively reach the black bodies. The second plurality of air passages direct ambient wind and thermal updrafts generated by the black bodies to an axial flow turbine. The rotating shaft of the turbines drive the generator. The solar and wind drien power generating system operates in electrical cogeneration mode with a fuel powered prime mover.

Relativistic sonic geometry for isothermal accretion in the Kerr metric

NASA Astrophysics Data System (ADS)

Arif Shaikh, Md

2018-03-01

We linearly perturb advective isothermal transonic accretion onto rotating astrophysical black holes to study the emergence of the relativistic acoustic spacetime and to investigate how the salient features of this spacetime is influenced by the spin angular momentum of the black hole. We have perturbed three different quantities—the velocity potential, the mass accretion rate and the relativistic Bernoulli’s constant to show that the acoustic metric obtained for these three cases are the same up to a conformal factor. By constructing the required causal structures, it has been demonstrated that the acoustic black holes are formed at the transonic points of the flow and the acoustic white holes are formed at the shock location. The corresponding acoustic surface gravity has been computed in terms of the relevant accretion variables and the background metric elements. We have performed a linear stability analysis of the background stationary flow.

Amination of black liquor and the application in the ready-mixed wet mortar.

PubMed

Zheng, Dafeng; Zheng, Tao; Chen, Ran; Li, Xiaokang; Qiu, Xueqing

2018-01-01

In order to extend the application of black liquor (BL), amino group was introduced in lignin through Mannich reaction. The structure of the aminated black liquor (ABL) was characterized with FT-IR, elemental analysis, the zeta potential and the inherent viscosity. The foam generated by ABL was more stable, for the surface tension was lower. The results of the mortar test indicated that the water-retention rate of the fresh mortar incorporated with 0.3 wt% ABL was 89.1%; the consistency loss was about 39.7% after 4 h. When the dosage was less than 0.3 wt%, ABL could increase the bond strength of the hardened mortars. The results showed that ABL could be used as an effective ready-mixed wet mortar admixture. This study not only provided a new method to develop new mortar admixture, but also alleviated the pollution of BL.

Electronic structures at the interface between CuPc and black phosphorus

NASA Astrophysics Data System (ADS)

Wang, Can; Niu, Dongmei; Xie, Haipeng; Liu, Baoxing; Wang, Shitan; Zhu, Menglong; Gao, Yongli

2017-08-01

The electronic structure at the organic-inorganic semiconductor interface of π -conjugated copper phthalocyanine (CuPc) on a black phosphorus (BP) crystal surface is studied with photoemission spectroscopy and density functional theory calculations. From the photoemission spectra, we observe a shift of about 0.7 eV for the highest occupied molecular orbital, which originates from the transition of phase in the organic molecular thin film (from the interface phase to the bulk phase). On the other hand, we find 0.2 eV band bending at the CuPc/BP interface while the formation of an interface dipole is very small. According to our photoemission spectrum and theoretical simulation, we also define that the interaction between CuPc and BP is physisorption via van der Waals forces, rather than chemisorption. Our results provide a fundamental understanding of CuPc/BP interfacial interactions that could be important for future two-dimensional organic/inorganic heterostructure devices.

Electron Pair Repulsion Responsible for the Peculiar Edge Effects and Surface Chemistry of Black Phosphorus.

PubMed

Kong, Xiang-Peng; Shen, Xiaomei; Jang, Joonkyung; Gao, Xingfa

2018-03-01

The electronic and optical properties of black phosphorus (black-P) are significantly modulated by fabricating the edges of this two-dimensional material. Electron lone pairs (ELPs) are ubiquitous in black-P, but their role in creating the edge effects of black-P is poorly understood. Using first-principle calculations, we report ELPs of black-P experience severe Coulomb repulsion and play a central role in creating the edge effects of black-P. We discover the outermost P atoms of the zigzag edges of black-PQDs are free of the Coulomb repulsion, but the P atoms of the armchair edges do experience the Coulomb repulsion. The Coulomb repulsion serves as a new chemical driving force to make electron donor-acceptor bonds with chemical groups bearing vacant orbitals. Our results provide insights into the mechanism responsible for the peculiar edge effects of black-P and highlight the opportunity to use the ELPs of black-P for their damage-free surface functionalization.

Simultaneous high crystallinity and sub-bandgap optical absorptance in hyperdoped black silicon using nanosecond laser annealing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Franta, Benjamin, E-mail: bafranta@gmail.com; Pastor, David; Gandhi, Hemi H.

2015-12-14

Hyperdoped black silicon fabricated with femtosecond laser irradiation has attracted interest for applications in infrared photodetectors and intermediate band photovoltaics due to its sub-bandgap optical absorptance and light-trapping surface. However, hyperdoped black silicon typically has an amorphous and polyphasic polycrystalline surface that can interfere with carrier transport, electrical rectification, and intermediate band formation. Past studies have used thermal annealing to obtain high crystallinity in hyperdoped black silicon, but thermal annealing causes a deactivation of the sub-bandgap optical absorptance. In this study, nanosecond laser annealing is used to obtain high crystallinity and remove pressure-induced phases in hyperdoped black silicon while maintainingmore » high sub-bandgap optical absorptance and a light-trapping surface morphology. Furthermore, it is shown that nanosecond laser annealing reactivates the sub-bandgap optical absorptance of hyperdoped black silicon after deactivation by thermal annealing. Thermal annealing and nanosecond laser annealing can be combined in sequence to fabricate hyperdoped black silicon that simultaneously shows high crystallinity, high above-bandgap and sub-bandgap absorptance, and a rectifying electrical homojunction. Such nanosecond laser annealing could potentially be applied to non-equilibrium material systems beyond hyperdoped black silicon.« less

Increasing the hydrophobicity degree of stonework by means of laser surface texturing: An application on Zimbabwe black granites

NASA Astrophysics Data System (ADS)

Chantada, A.; Penide, J.; Riveiro, A.; del Val, J.; Quintero, F.; Meixus, M.; Soto, R.; Lusquiños, F.; Pou, J.

2017-10-01

Tailoring the wetting characteristics of materials has gained much interest in applications related to surface cleaning in both industry and home. Zimbabwe black granite is a middle-to-fine-grained natural stone commonly used as countertops in kitchens and bathrooms. In this study, the laser texturing of Zimbabwe black granite surfaces is investigated with the aim to enhance its hydrophobic character, thus reducing the attachment of contaminants on the surface. Two laser sources (λ = 1064 and 532 nm) were used for this purpose. The treatment is based on the irradiation of the stone by a laser focused on the surface of the targeting sample. The influence of different laser processing parameters on the surface characteristics of granite (wettability, roughness, and chemistry) was statistically assessed. Most suitable laser processing parameters required to obtain the highest hydrophobicity degree were identified. It has been possible to identify the 532 nm laser wavelength as the most effective one to increase the hydrophobic degree of Zimbabwe black granite surface. The phenomenon governing wettability changes was found to be the surface roughness patterns, given the unaltered chemical surface composition after laser processing.

Preparation of composite micro/nano structure on the silicon surface by reactive ion etching: Enhanced anti-reflective and hydrophobic properties

NASA Astrophysics Data System (ADS)

Zeng, Yu; Fan, Xiaoli; Chen, Jiajia; He, Siyu; Yi, Zao; Ye, Xin; Yi, Yougen

2018-05-01

A silicon substrate with micro-pyramid structure (black silicon) is prepared by wet chemical etching and then subjected to reactive ion etching (RIE) in the mixed gas condition of SF6, CHF3 and He. We systematically study the impacts of flow rates of SF6, CHF3 and He, the etching pressure and the etching time on the surface morphology and reflectivity through various characterizations. Meanwhile, we explore and obtain the optimal combination of parameters for the preparation of composite structure that match the RIE process based on the basis of micro-pyramid silicon substrate. The composite sample prepared under the optimum parameters exhibits excellent anti-reflective performance, hydrophobic, self-cleaning and anti-corrosive properties. Based on the above characteristics, the composite micro/nano structure can be applied to solar cells, photodetectors, LEDs, outdoor devices and other important fields.

Sodium Hypochlorite Treatment and Nitinol Performance for Medical Devices

NASA Astrophysics Data System (ADS)

Weaver, J. D.; Gutierrez, E. J.; Nagaraja, S.; Stafford, P. R.; Sivan, S.; Di Prima, M.

2017-09-01

Processing of nitinol medical devices has evolved over the years as manufacturers have identified methods of reducing surface defects such as inclusions. One recent method proposes to soak nitinol medical devices in a 6% sodium hypochlorite (NaClO) solution as a means of identifying surface inclusions. Devices with surface inclusions could in theory then be removed from production because inclusions would interact with NaClO to form a visible black material on the nitinol surface. To understand the effects of an NaClO soak on performance, we compared as-received and NaClO-soaked nitinol wires with two different surface finishes (black oxide and electropolished). Pitting corrosion susceptibility was equivalent between the as-received and NaClO-soaked groups for both surface finishes. Nickel ion release increased in the NaClO-soaked group for black oxide nitinol, but was equivalent for electropolished nitinol. Fatigue testing revealed a lower fatigue life for NaClO-soaked black oxide nitinol at all alternating strains. With the exception of 0.83% alternating strain, NaClO-soaked and as-received electropolished nitinol had similar average fatigue life, but the NaClO-soaked group showed higher variability. NaClO-soaked electropolished nitinol had specimens with the lowest number of cycles to fracture for all alternating strains tested with the exception of the highest alternating strain 1.2%. The NaClO treatment identified only one specimen with surface inclusions and caused readily identifiable surface damage to the black oxide nitinol. Damage from the NaClO soak to electropolished nitinol surface also appears to have occurred and is likely the cause of the increased variability of the fatigue results. Overall, the NaClO soak appears to not lead to an improvement in nitinol performance and seems to be damaging to the nitinol surface in ways that may not be detectable with a simple visual inspection for black material on the nitinol surface.

The Factor Structure of the Vocational Preference Inventory for Black and White College Students

ERIC Educational Resources Information Center

Yom, B. Lee; And Others

1975-01-01

In the present study, the Vocational Preference Inventory scores for a group of black students and white students were factor analyzed and the black structure was rotated to correspond to the white structure. The correspondence between the variables for black and white students was found to be very similar. (Author)

Accretion Disks Around Binary Black Holes of Unequal Mass: GRMHD Simulations Near Decoupling

NASA Technical Reports Server (NTRS)

Gold, Roman; Paschalidis, Vasileios; Etienne, Zachariah B.; Shapiro, Stuart L.; Pfeiffer, Harald, P.

2013-01-01

We report on simulations in general relativity of magnetized disks onto black hole binaries. We vary the binary mass ratio from 1:1 to 1:10 and evolve the systems when they orbit near the binary disk decoupling radius. We compare (surface) density profiles, accretion rates (relative to a single, non-spinning black hole), variability, effective alpha-stress levels and luminosities as functions of the mass ratio. We treat the disks in two limiting regimes: rapid radiative cooling and no radiative cooling. The magnetic field lines clearly reveal jets emerging from both black hole horizons and merging into one common jet at large distances. The magnetic fields give rise to much stronger shock heating than the pure hydrodynamic flows, completely alter the disk structure, and boost accretion rates and luminosities. Accretion streams near the horizons are among the densest structures; in fact, the 1:10 no-cooling evolution results in a refilling of the cavity. The typical effective temperature in the bulk of the disk is approx. 10(exp5) (M / 10(exp 8)M solar mass (exp -1/4(L/L(sub edd) (exp 1/4K) yielding characteristic thermal frequencies approx. 10 (exp 15) (M /10(exp 8)M solar mass) (exp -1/4(L/L (sub edd) (1+z) (exp -1)Hz. These systems are thus promising targets for many extragalactic optical surveys, such as LSST, WFIRST, and PanSTARRS.

Femtosecond laser fabricating black silicon in alkaline solution

NASA Astrophysics Data System (ADS)

Meng, Jiao; Song, Haiying; Li, Xiaoli; Liu, Shibing

2015-03-01

An efficient approach for enhancing the surface antireflection is proposed, in which a black silicon is fabricated by a femtosecond laser in alkaline solution. In the experiment, 2 wt% NaOH solution is formulated at room temperature (22 ± 1 °C). Then, a polished silicon is scanned via femtosecond laser irradiation in 2 wt% NaOH solution. Jungle-like microstructures on the black silicon surface are characterized using an atomic force microscopy. The reflectance of the black silicon is measured at the wavelengths ranging from 400 to 750 nm. Compared to the polished silicon, the black silicon can significantly suppress the optical reflection throughout the visible region (<5 %). Meanwhile, we also investigated the factors of the black silicon, including the femtosecond laser pulse energy and the scanning speed. This method is simple and effective to acquire the black silicon, which probably has a large advantage in fast and cost-effective black silicon fabrication.

Numerical analysis of the vibroacoustic properties of plates with embedded grids of acoustic black holes.

PubMed

Conlon, Stephen C; Fahnline, John B; Semperlotti, Fabio

2015-01-01

The concept of an Acoustic Black Hole (ABH) has been developed and exploited as an approach for passively attenuating structural vibration. The basic principle of the ABH relies on proper tailoring of the structure geometrical properties in order to produce a gradual reduction of the flexural wave speed, theoretically approaching zero. For practical systems the idealized "zero" wave speed condition cannot be achieved so the structural areas of low wave speed are treated with surface damping layers to allow the ABH to approach the idealized dissipation level. In this work, an investigation was conducted to assess the effects that distributions of ABHs embedded in plate-like structures have on both vibration and structure radiated sound, focusing on characterizing and improving low frequency performance. Finite Element and Boundary Element models were used to assess the vibration response and radiated sound power performance of several plate configurations, comparing baseline uniform plates with embedded periodic ABH designs. The computed modal loss factors showed the importance of the ABH unit cell low order modes in the overall vibration reduction effectiveness of the embedded ABH plates at low frequencies where the free plate bending wavelengths are longer than the scale of the ABH.

Requirements and design structure for Surya Satellite-1

NASA Astrophysics Data System (ADS)

Steven, H.; Huzain, M. F.

2018-05-01

Currently, there are various references on the manufacture of nanosatellite specifications weighing 1KG - 10KG.The Surya Satellite-1 is the first nanosatellite made by universities in Indonesia. The Surya Satellite-1 team gets a launch offer from Japan Aerospace Exploration Agency (JAXA) and, all the nanosatellites manufacturer racers at ICD (Interface Control Document) obtained from JAXA. The formation of the Satellite-1 Surya framework is also based on the provisions of JAXA. The various specifications and requirements specified by the JAXA space agency consisting of specific specifications such as the mass of nanosatellite 1U (10cm x 10cm x 11.65cm) size of at least 0.13KG and a maximum of 1.33KG, with the determination of a gravity point not exceeding 2 cm from the nanosatellite geometry center point. In the case of preventing solar radiation in space, there is a requirement that the structure of satellite structures on hard black anodization should be more than 10 meters in the surface of the satellite structure. In terms of detail, the satellite structure is a black hard anodized aluminum after its manufacturing process derived from the MIL-A-8625 document, type 3.

Black TiO2 synthesized via magnesiothermic reduction for enhanced photocatalytic activity

NASA Astrophysics Data System (ADS)

Wang, Xiangdong; Fu, Rong; Yin, Qianqian; Wu, Han; Guo, Xiaoling; Xu, Ruohan; Zhong, Qianyun

2018-04-01

Utilizing solar energy for hydrogen evolution is a great challenge for its insufficient visible-light power conversion. In this paper, we report a facile magnesiothermic reduction of commercial TiO2 nanoparticles under Ar atmosphere and at 550 °C followed by acid treatment to synthesize reduced black TiO2 powders, which possesses a unique crystalline core-amorphous shell structure composed of disordered surface and oxygen vacancies and shows significantly improved optical absorption in the visible region. The unique core-shell structure and high absorption enable the reduced black TiO2 powders to exhibit enhanced photocatalytic activity, including splitting of water in the presence of Pt as a cocatalyst and degradation of methyl blue (MB) under visible light irradiation. Photocatalytic evaluations indicate that the oxygen vacancies play key roles in the catalytic process. The maximum hydrogen production rates are 16.1 and 163 μmol h-1 g-1 under the full solar wavelength range of light and visible light, respectively. This facile and versatile method could be potentially used for large scale production of colored TiO2 with remarkable enhancement in the visible light absorption and solar-driven hydrogen production.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sato, Chikara, E-mail: ti-sato@aist.go.jp; Manaka, Sachie; Nakane, Daisuke

Highlights: Black-Right-Pointing-Pointer Mycoplasma mobile was observed in buffer with the Atmospheric Scanning Electron Microscope. Black-Right-Pointing-Pointer Characteristic protein localizations were visualized using immuno-labeling. Black-Right-Pointing-Pointer M. mobile attached to sialic acid on the SiN film surface within minutes. Black-Right-Pointing-Pointer Cells were observed at low concentrations. Black-Right-Pointing-Pointer ASEM should promote study and early-stage diagnosis of mycoplasma. -- Abstract: Mycoplasma is a genus of bacterial pathogen that causes disease in vertebrates. In humans, the species Mycoplasma pneumoniae causes 15% or more of community-acquired pneumonia. Because this bacterium is tiny, corresponding in size to a large virus, diagnosis using optical microscopy is not easy. Inmore » current methods, chest X-rays are usually the first action, followed by serology, PCR amplification, and/or culture, but all of these are particularly difficult at an early stage of the disease. Using Mycoplasma mobile as a model species, we directly observed mycoplasma in buffer with the newly developed Atmospheric Scanning Electron Microscope (ASEM). This microscope features an open sample dish with a pressure-resistant thin film window in its base, through which the SEM beam scans samples in solution, from below. Because of its 2-3 {mu}m-deep scanning capability, it can observe the whole internal structure of mycoplasma cells stained with metal solutions. Characteristic protein localizations were visualized using immuno-labeling. Cells were observed at low concentrations, because suspended cells concentrate in the observable zone by attaching to sialic acid on the silicon nitride (SiN) film surface within minutes. These results suggest the applicability of the ASEM for the study of mycoplasmas as well as for early-stage mycoplasma infection diagnosis.« less

Recent NASA/GSFC cryogenic measurements of the total hemispheric emissivity of black surface preparations

NASA Astrophysics Data System (ADS)

Tuttle, J.; Canavan, E.

2015-12-01

High-emissivity (black) surfaces are commonly used on deep-space radiators and thermal radiation absorbers in test chambers. Since 2011 NASA Goddard Space Flight Center has measured the total hemispheric emissivity of such surfaces from 20 to 300 K using a test apparatus inside a small laboratory cryostat. We report the latest data from these measurements, including Aeroglaze Z307 paint, Black Kapton, and a configuration of painted aluminum honeycomb that was not previously tested. We also present the results of batch-to- batch reproducibility studies in Ball Infrared BlackTM and painted aluminum honeycomb. Finally, we describe a recently-adopted temperature control method which significantly speeds the data acquisition, and we discuss efforts to reduce the noise in future data.

Insights into the attenuated sorption of organic compounds on black carbon aged in soil.

PubMed

Luo, Lei; Lv, Jitao; Chen, Zien; Huang, Rixiang; Zhang, Shuzhen

2017-12-01

Sorption of organic compounds on fresh black carbons (BCs) can be greatly attenuated in soil over time. We examined herein the changes in surface properties of maize straw-derived BCs (biochars) after aged in a black soil and their effects on the sorptive behaviors of naphthalene, phenanthrene and 1,3-dinitrobenzene. Dissolved fulvic and humic acids extracted from the soil were used to explore the role of dissolved organic carbon (DOC) in the aging of biochars. Chromatography analysis indicated that DOC molecules with relatively large molecular weight were preferentially adsorbed on the biochars during the aging processes. DOC sorption led to blockage of the biochar's micropores according to N 2 and CO 2 adsorption analyses. Surface chemistry of the biochars was also substantially modified, with more O-rich functional groups on the aged biochars compared to the original biochars, as evidenced by Near-edge X-ray absorption fine structure (NEXAFS) spectroscopy and X-ray photoelectron spectroscopy (XPS) analyses. The changes in both the physical and chemical surface properties of biochars by DOC led to significant attenuation of the sorption capacity and nonlinearity of the nonionic organic compounds on the aged biochars. Among the tested organic compounds, phenanthrene was the most attenuated in its sorption by the aging treatments, possibly because of its relatively large molecular size and hydrophobicity. The information can help gain a mechanistic understanding of interactions between BCs and organic compounds in soil environment. Copyright © 2017 Elsevier Ltd. All rights reserved.

Short-Range-Order Mineral Physical Protection On Black Carbon Stabilization

NASA Astrophysics Data System (ADS)

Liang, B.; Weng, Y. T.; Wang, C. C.; Song, Y. F.; Lehmann, J.; Wang, C. H.

2015-12-01

Soil organic matter is one of the largest reservoirs in global carbon cycle, and black carbon (BC) represents a chemical resistant component. Black C plays an important role in global climate change. Generally considered recalcitrant due to high aromaticity, the reactive surface and functional groups of BC are crucial for carbon sequestration in soils. Mineral sorption and physical protection is an important mechanism for BC long term stabilization and sequestration in environments. Previous studies on mineral protection of BC were limited to analysis techniques in two-dimensions, for example, by SEM, TEM, and NanoSIMS. Little is known about the scope of organo-mineral association, the in-situ distribution and forms of minerals, and the ultimate interplay of BC and minerals. The aim of this study is to investigate the three-dimensional interaction of organic C and minerals in submicron scale using synchrotron-based Transmission X-ray Microcopy (TXM) and Fourier-Transform Infrared Spectroscopy (FTIR). Abundant poorly-crystallined nano-minerals particles were observed. These short-range-order (SRO) minerals also aggregate into clusters and sheets, and form envelops-like structures on the surface of BC. On top of large surface contact area, the intimate interplay between BC and minerals reinforces the stability of both organic C and minerals, resulting from chemical bonding through cation bridging and ligand exchange. The mineral protection enhances BC stabilization and sequestration and lowers its bioavailability in environment. The results suggest that mineral physical protection for BC sequestration may be more important than previous understanding.

30 CFR 57.6901 - Black powder.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Black powder. 57.6901 Section 57.6901 Mineral...-Surface and Underground § 57.6901 Black powder. (a) Black powder shall be used for blasting only when a... dimension stone. (b) Containers of black powder shall be— (1) Nonsparking; (2) Kept in a totally enclosed...

30 CFR 57.6901 - Black powder.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Black powder. 57.6901 Section 57.6901 Mineral...-Surface and Underground § 57.6901 Black powder. (a) Black powder shall be used for blasting only when a... dimension stone. (b) Containers of black powder shall be— (1) Nonsparking; (2) Kept in a totally enclosed...

30 CFR 57.6901 - Black powder.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Black powder. 57.6901 Section 57.6901 Mineral...-Surface and Underground § 57.6901 Black powder. (a) Black powder shall be used for blasting only when a... dimension stone. (b) Containers of black powder shall be— (1) Nonsparking; (2) Kept in a totally enclosed...

30 CFR 57.6901 - Black powder.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Black powder. 57.6901 Section 57.6901 Mineral...-Surface and Underground § 57.6901 Black powder. (a) Black powder shall be used for blasting only when a... dimension stone. (b) Containers of black powder shall be— (1) Nonsparking; (2) Kept in a totally enclosed...

30 CFR 57.6901 - Black powder.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Black powder. 57.6901 Section 57.6901 Mineral...-Surface and Underground § 57.6901 Black powder. (a) Black powder shall be used for blasting only when a... dimension stone. (b) Containers of black powder shall be— (1) Nonsparking; (2) Kept in a totally enclosed...

Differences in Trabecular Microstructure Between Black and White Women Assessed by Individual Trabecular Segmentation Analysis of HR-pQCT Images

PubMed Central

Putman, Melissa S; Yu, Elaine W; Lin, David; Darakananda, Karin; Finkelstein, Joel S; Bouxsein, Mary L

2017-01-01

Black women have lower fracture risk compared with white women, which may be partly explained by improved volumetric bone mineral density (vBMD) and bone microarchitecture primarily within the cortical bone compartment. To determine if there are differences in trabecular microstructure, connectivity, and alignment according to race/ethnicity, we performed individual trabecular segmentation (ITS) analyses on high-resolution peripheral quantitative computed tomography (HR-pQCT) scans of the distal radius and tibia in 273 peri- and postmenopausal black (n = 100) and white (n = 173) women participating in the Study of Women’s Health Across the Nation in Boston. Unadjusted analyses showed that black women had greater trabecular plate volume fraction, plate thickness, plate number density, and plate surface area along with greater axial alignment of trabeculae, whereas white women had greater trabecular rod tissue fraction (p < 0.05 for all). Adjustment for clinical covariates augmented these race/ethnicity-related differences in plates and rods, such that white women had greater trabecular rod number density and rod-rod connectivity, whereas black women continued to have superior plate structural characteristics and axial alignment (p < 0.05 for all). These differences remained significant after adjustment for hip BMD and trabecular vBMD. In conclusion, black women had more plate-like trabecular morphology and higher axial alignment of trabeculae, whereas white women had more rod-like trabeculae. These differences may contribute to the improved bone strength and lower fracture risk observed in black women. PMID:27958659

Bright vigorous winds as signposts of supermassive black hole birth

NASA Astrophysics Data System (ADS)

Fiacconi, Davide; Rossi, Elena M.

2016-01-01

The formation of supermassive black holes is still an outstanding question. In the quasi-star scenario, black hole seeds experience an initial super-Eddington growth, that in less than a million years may leave a 104-105 M⊙ black hole at the centre of a protogalaxy at z ˜ 20-10. Super-Eddington accretion, however, may be accompanied by vigorous mass-loss that can limit the amount of mass that reaches the black hole. In this paper, we critically assess the impact of radiative driven winds, launched from the surface of the massive envelopes from which the black hole accretes. Solving the full wind equations coupled with the hydrostatic structure of the envelope, we find mass outflows with rates between a few tens and 104 M⊙ yr-1, mainly powered by advection luminosity within the outflow. We therefore confirm the claim by Dotan et al. that mass losses can severely affect the black hole seed early growth within a quasi-star. In particular, seeds with mass >104 M⊙ can only form within mass reservoirs ≳107 M⊙, unless they are refilled at huge rates (≳100 M⊙ yr-1). This may imply that only very massive haloes (>109 M⊙) at those redshifts can harbour massive seeds. Contrary to previous claims, these winds are expected to be relatively bright (1044-1047 erg s-1), blue (Teff ˜ 8000 K) objects, that while eluding the Hubble Space Telescope, could be observed by the James Webb Space Telescope.

An Investigation on a Crystalline-Silicon Solar Cell with Black Silicon Layer at the Rear.

PubMed

Zhou, Zhi-Quan; Hu, Fei; Zhou, Wen-Jie; Chen, Hong-Yan; Ma, Lei; Zhang, Chi; Lu, Ming

2017-12-15

Crystalline-Si (c-Si) solar cell with black Si (b-Si) layer at the rear was studied in order to develop c-Si solar cell with sub-band gap photovoltaic response. The b-Si was made by chemical etching. The c-Si solar cell with b-Si at the rear was found to perform far better than that of similar structure but with no b-Si at the rear, with the efficiency being increased relatively by 27.7%. This finding was interesting as b-Si had a large specific surface area, which could cause high surface recombination and degradation of solar cell performance. A graded band gap was found to form at the rear of the c-Si solar cell with b-Si layer at the rear. This graded band gap tended to expel free electrons away from the rear, thus reducing the probability of electron-hole recombination at b-Si and improving the performance of c-Si solar cell.

Review Application of Nanostructured Black Silicon

NASA Astrophysics Data System (ADS)

Lv, Jian; Zhang, Ting; Zhang, Peng; Zhao, Yingchun; Li, Shibin

2018-04-01

As a widely used semiconductor material, silicon has been extensively used in many areas, such as photodiode, photodetector, and photovoltaic devices. However, the high surface reflectance and large bandgap of traditional bulk silicon restrict the full use of the spectrum. To solve this problem, many methods have been developed. Among them, the surface nanostructured silicon, namely black silicon, is the most efficient and widely used. Due to its high absorption in the wide range from UV-visible to infrared, black silicon is very attractive for using as sensitive layer of photodiodes, photodetector, solar cells, field emission, luminescence, and other photoelectric devices. Intensive study has been performed to understand the enhanced absorption of black silicon as well as the response extended to infrared spectrum range. In this paper, the application of black silicon is systematically reviewed. The limitations and challenges of black silicon material are also discussed. This article will provide a meaningful introduction to black silicon and its unique properties.

Nanoscale Topography on Black Titanium Imparts Multi-biofunctional Properties for Orthopedic Applications

NASA Astrophysics Data System (ADS)

Hasan, Jafar; Jain, Shubham; Chatterjee, Kaushik

2017-01-01

We have developed a chlorine based reactive ion etching process to yield randomly oriented anisotropic nanostructures that render the titanium metal surface ‘black’ similar to that of black silicon. The surface appears black due to the nanostructures in contrast to the conventional shiny surface of titanium. The nanostructures were found to kill bacteria on contact by mechanically rupturing the cells as has been observed previously on wings of certain insects. The etching was optimized to yield nanostructures of ≈1 μm height for maximal bactericidal efficiency without compromising cytocompatibility. Within 4 hours of contact with the black titanium surface, 95% ± 5% of E. coli, 98% ± 2% of P. aeruginosa, 92% ± 5% of M. smegmatis and 22% ± 8% of S. aureus cells that had attached were killed. The killing efficiency for the S. aureus increased to 76% ± 4% when the cells were allowed to adhere up to 24 hours. The black titanium supported the attachment and proliferation of human mesenchymal stem cells and augmented osteogenic lineage commitment in vitro. Thus, the bioinspired nanostructures on black titanium impart multi-biofunctional properties toward engineering the next-generation biomaterials for orthopedic implants.

Nanoscale Topography on Black Titanium Imparts Multi-biofunctional Properties for Orthopedic Applications

PubMed Central

Hasan, Jafar; Jain, Shubham; Chatterjee, Kaushik

2017-01-01

We have developed a chlorine based reactive ion etching process to yield randomly oriented anisotropic nanostructures that render the titanium metal surface ‘black’ similar to that of black silicon. The surface appears black due to the nanostructures in contrast to the conventional shiny surface of titanium. The nanostructures were found to kill bacteria on contact by mechanically rupturing the cells as has been observed previously on wings of certain insects. The etching was optimized to yield nanostructures of ≈1 μm height for maximal bactericidal efficiency without compromising cytocompatibility. Within 4 hours of contact with the black titanium surface, 95% ± 5% of E. coli, 98% ± 2% of P. aeruginosa, 92% ± 5% of M. smegmatis and 22% ± 8% of S. aureus cells that had attached were killed. The killing efficiency for the S. aureus increased to 76% ± 4% when the cells were allowed to adhere up to 24 hours. The black titanium supported the attachment and proliferation of human mesenchymal stem cells and augmented osteogenic lineage commitment in vitro. Thus, the bioinspired nanostructures on black titanium impart multi-biofunctional properties toward engineering the next-generation biomaterials for orthopedic implants. PMID:28112235

Black ice detection and road closure control system for Oklahoma.

DOT National Transportation Integrated Search

2014-10-01

Black ice is a thin coating of glazed ice on roadways or other transportation surfaces. Black : ice has identical appearance with black pavement and wet road, and it often forms during calm : weather. It is highly transparent and thus difficult to se...

The origin of Cretaceous black shales: a change in the surface ocean ecosystem and its triggers

PubMed Central

OHKOUCHI, Naohiko; KURODA, Junichiro; TAIRA, Asahiko

2015-01-01

Black shale is dark-colored, organic-rich sediment, and there have been many episodes of black shale deposition over the history of the Earth. Black shales are source rocks for petroleum and natural gas, and thus are both geologically and economically important. Here, we review our recent progress in understanding of the surface ocean ecosystem during periods of carbonaceous sediment deposition, and the factors triggering black shale deposition. The stable nitrogen isotopic composition of geoporphyrins (geological derivatives of chlorophylls) strongly suggests that N2-fixation was a major process for nourishing the photoautotrophs. A symbiotic association between diatoms and cyanobacteria may have been a major primary producer during episodes of black shale deposition. The timing of black shale formation in the Cretaceous is strongly correlated with the emplacement of large igneous provinces such as the Ontong Java Plateau, suggesting that black shale deposition was ultimately induced by massive volcanic events. However, the process that connects these events remains to be solved. PMID:26194853

A Structural Decomposition of Black-White Earnings Differentials.

ERIC Educational Resources Information Center

Kaufman, Robert L.

1983-01-01

Two factors which create differences in Black-White earnings are: (1) differentials between Blacks and Whites within divisions of the labor market; and (2) differences between industries and occupations in earnings, combined with the differential distribution of Blacks and Whites across labor market divisions. The labor market structure is crucial…

Plasma carburizing with surface micro-melting

NASA Astrophysics Data System (ADS)

Balanovsky, A. E.; Grechneva, M. V.; Van Huy, Vu; Ponomarev, B. B.

2018-03-01

This paper presents carburizing the surface of 20 low carbon steel using electric arc and graphite prior. A carbon black solution was prepared with graphite powder and sodium silicate in water. A detailed analysis of the phase structure and the distribution profile of the sample hardness after plasma treatment were given. The hardened layer consists of three different zones: 1 – the cemented layer (thin white zone) on the surface, 2 – heat-affected zone (darkly etching structure), 3 – the base metal. The experimental result shows that the various microstructures and micro-hardness profiles were produced depending on the type of graphite coating (percentage of liquid glass) and processing parameters. The experiment proved that the optimum content of liquid glass in graphite coating is 50–87.5%. If the amount of liquid glass is less than 50%, adhesion to metal is insufficient. If liquid glass content is more than 87.5%, carburization of a metal surface does not occur. A mixture of the eutectic lamellar structure, martensite and austenite was obtained by using graphite prior with 67% sodium silicate and the levels of the hardness layer increased to around 1000 HV. The thickness of the cemented layer formed on the surface was around 200 μm. It is hoped that this plasma surface carburizing treatment could improve the tribological resistance properties.

Roles of Ferrous and Sulfide Ions in the Fromation of Algae—Induced Black Bloom in Hyper Eutrophic Freshwater Lakes in China

NASA Astrophysics Data System (ADS)

Shen, Q.; Gao, Q.; Yu, C.; Zhang, L.; Wang, Z.

2016-12-01

Water column hypoxia is one of the most serious threats from eutrophication to large water bodies. In the past several years, black bloom phenomenon has become a serious ecosystem disaster in some important severe eutrophic lakes in China, which caused not only environment degradation but also drinking water crisis. Black color and offensive odour of the water column are two notorious sensory features. High Fe2+ and ΣH2S (ΣS2-=S2-+HS-+H2S) were typical characteristics of the black bloom water. Analysis of the black substances of the black bloom water using X-ray photoelectron spectroscopy indicated that abundant FeS were included in these particulates. The black color of the black bloom water could be attributed to the formation of FeS in the anoxic/anaerobic water column. Field investigation and laboratory incubation experiment indicated that the formation of black bloom was closely related to the Fe2+ and ΣH2S in surface sediments. The Fe2+ concentration in surface sediment pore water was high and showed a release tendency from the sediment water interface to the overlying water during the formation of black bloom, while the similar trend was found in ΣH2S production at sediment water micro-interface. Both Fe2+ and ΣS2- affected by oxic and redox conditions, respectively, contributed to the formation of black bloom significantly. However, ΣS2- was found to be the limiting factor directly controlling the outbreak of black bloom. Analysis of microbioal community diversity demonstrated that sulfate reducing bacteria (SRB) were abundant in the surface sediment of black bloom, which strongly influenced the production and accumulation of ΣH2S and drove the formation of black bloom.

Comparison of the bidirectional reflectance distribution function of various surfaces

NASA Technical Reports Server (NTRS)

Fernandez, Rene; Seasholtz, Richard G.; Oberle, Lawrence G.; Kadambi, Jaikrishnan R.

1988-01-01

Described is the development and use of a system to measure the Bidirectional Reflectance Distribution Function (BRDF) of various surfaces. The BRDF measurements are used in the analysis and design of optical measurement systems, such as laser anemometers. An argon ion laser (514 nm) is the light source. Preliminary results are presented for eight samples: two glossy black paints, two flat black paints, black glass, sand blasted aluminum, unworked aluminum, and a white paint. A BaSO4 white reflectance standard was used as the reference sample throughout the tests. The reflectance characteristics of these surfaces are compared.

Satellite observations of eddies in the Baltic, Black and Caspian seas

NASA Astrophysics Data System (ADS)

Karimova, S.

2012-04-01

In the present paper mesoscale and sub-mesoscale eddies in the Baltic, Black and Caspian seas are studied by means of satellite radiometer and radar images. Using these data makes it possible to investigate the vortical structures of a wide spatial range, from the basin scale through mesoscale to a small scale with a few kilometers in size. Over 2000 Envisat ASAR and ERS-2 SAR images with two-year time coverage (2009-2010) and spatial resolution of 75 m obtained in different parts of the Baltic, Black and Caspian Seas were applied to study submesoscale (with a diameter less than ca. 20 km) eddies in the basins mentioned. As a result of the analysis performed the role of different mechanisms (ones due to surfactant films, wave/current interactions and thermal fronts) in eddy visualization in SAR imagery was revealed. In every basin studied the main eddy characteristics such as number of eddies, frequency of their occurrence in SAR imagery, sign of vorticity, typical length scale and lifetime as well as spatial distribution patterns were investigated. Spatio-temporal parameters of the vortices were subjected to statistical analysis. Interannual and seasonal variabilities of the eddy parameters were traced. Hypotheses about the most important mechanisms of generation of the eddies observed were proposed. Among them there are barotropic, baroclinic and topographic instabilities, convection in the surface layer and heterogeneous wind forcing. Satellite infrared and visible images were used for retrieving statistical information on the Black Sea mesoscale vortical structures. The dataset used included ~5000 AVHRR NOAA Sea Surface Temperature (SST) images covering the entire Black Sea with time coverage since September, 2004 to December, 2010 and ~1500 MODIS Aqua (SST, normalized water-leaving radiance at 551 nm, chlorophyll-a concentration) images obtained in 2006-2010. Spatial resolution of the images was 1 km. Analysis performed revealed that numerous vortical structures could be detected in the imagery mentioned. These structures were very different in their spatio-temporal scales and mechanisms of generation. It was discovered that the eddy types which could be especially frequently observed were the Rim Current meanders and rings, quasi-permanent anticyclonic eddies, near-shore anticyclonic eddies, mushroom-like currents (eddy dipoles), eddies of the Anatolian coast, and eddy chains. For each type of non-stationary eddies (the last four groups of eddies just mentioned), their spatio-temporal characteristics were retrieved such as areas of the most frequent generation and typical length scale as well as their seasonality and interannual variability. This work was implemented within the framework of the Federal Target Program "Scientific and scientific-pedagogical personnel of innovative Russia" in 2009-2013 and partly supported by the Russian Foundation for Basic Research (grants #10-05-00428, #11-07-12025).

Patterns of surface burrow plugging in a colony of black-tailed prairie dogs occupied by black-footed ferrets

USGS Publications Warehouse

Eads, David E.; Biggins, Dean E.

2012-01-01

Black-tailed prairie dogs (Cynomys ludovicianus) can surface-plug openings to a burrow occupied by a black-footed ferret (Mustela nigripes). At a coarse scale, surface plugs are more common in colonies of prairie dogs occupied by ferrets than in colonies without ferrets. However, little is known about spatial and temporal patterns of surface plugging in a colony occupied by ferrets. In a 452-ha colony of black-tailed prairie dogs in South Dakota, we sampled burrow openings for surface plugs and related those data to locations of ferrets observed during spotlight surveys. Of 67,574 burrow openings in the colony between June and September 2007, 3.7% were plugged. In a colony-wide grid of 80 m × 80 m cells, the occurrence of surface plugging (≥1 opening plugged) was greater in cells used by ferrets (93.3% of cells) than in cells not observably used by ferrets (70.6%). Rates of surface plugging (percentages of openings plugged) were significantly higher in cells used by ferrets (median = 3.7%) than in cells without known ferret use (median = 3.2%). Also, numbers of ferret locations in cells correlated positively with numbers of mapped surface plugs in the cells. To investigate surface plugging at finer temporal and spatial scales, we compared rates of surface plugging in 20-m-radius circle-plots centered on ferret locations and in random plots 1–4 days after observing a ferret (Jun–Oct 2007 and 2008). Rates of surface plugging were greater in ferret-plots (median = 12.0%) than in random plots (median = 0%). For prairie dogs and their associates, the implications of surface plugging could be numerous. For instance, ferrets must dig to exit or enter plugged burrows (suggesting energetic costs), and surface plugs might influence microclimates in burrows and consequently influence species that cannot excavate soil (e.g., fleas that transmit the plague bacterium Yersinia pestis).

Entropy bound of horizons for accelerating, rotating and charged Plebanski–Demianski black hole

DOE Office of Scientific and Technical Information (OSTI.GOV)

Debnath, Ujjal, E-mail: ujjaldebnath@yahoo.com

We first review the accelerating, rotating and charged Plebanski–Demianski (PD) black hole, which includes the Kerr–Newman rotating black hole and the Taub-NUT spacetime. The main feature of this black hole is that it has 4 horizons like event horizon, Cauchy horizon and two accelerating horizons. In the non-extremal case, the surface area, entropy, surface gravity, temperature, angular velocity, Komar energy and irreducible mass on the event horizon and Cauchy horizon are presented for PD black hole. The entropy product, temperature product, Komar energy product and irreducible mass product have been found for event horizon and Cauchy horizon. Also their sumsmore » are found for both horizons. All these relations are dependent on the mass of the PD black hole and other parameters. So all the products are not universal for PD black hole. The entropy and area bounds for two horizons have been investigated. Also we found the Christodoulou–Ruffini mass for extremal PD black hole. Finally, using first law of thermodynamics, we also found the Smarr relation for PD black hole.« less

Easy approach to assembling a biomimetic color film with tunable structural colors.

PubMed

Wang, Wentao; Tang, Bingtao; Ma, Wei; Zhang, Jian; Ju, Benzhi; Zhang, Shufen

2015-06-01

The self-assembly of silica microspheres into a close-packed array is a simple method of fabricating three-dimensional photonic crystal structural color films. However, the color is very dull because of the interferences of scattering and background light. In this study, we added a small quantity of surface-modified carbon black (CB) to the system of colloidal silica in n-propanol. The use of n-propanol as a dispersant is beneficial to the rapid development of photonic crystal films during the process of dip-coating. The doping of CB into silica microspheres can absorb background and scattering light, resulting in vivid structural colors.

Report on Carbon Nano Material Workshop: Challenges and Opportunities

DTIC Science & Technology

2013-01-22

trolyte fuel cells ( PEMFCs ) utilize the ability of the catalysts to initiate and maintain the oxygen reduction reaction on the cathode and the fuel...oxidation reaction on the anode. In order to increase the efficiency of the PEMFC catalysts, high-surface-area mesoporous carbons, carbon blacks, carbon...mechanical and thermal properties derived from a three-dimensional intercon- nected nanonetwork structure. The exceptional properties of CAs for PEMFC

Assessment of Tropical Cyclone Structure Variability

DTIC Science & Technology

2013-09-01

Oceanic and Atmospheric Administration, cited 2007: Background on the HRD surface wind analysis system . [Available from http://www.aoml.noaa.gov/ hrd... Atmospheric Administration (NOAA)-Atlantic Oceanographic and Meteorological Laboratory (AOML) Hurricane Wind Analysis System (H*Wind; Powell and Houston 1996...emissions from the ocean and atmosphere in the form of brightness temperatures (TB) for each of six frequencies from 4.55 to 7.22 GHz (Uhlhorn and Black 2003

Design and implementation of optical system for Placido-disc topography

NASA Astrophysics Data System (ADS)

Sui, Chenghua; Wo, Shengjie; Cai, Pinggen; Gao, Nan; Xu, Danyang; Han, Yonghao; Du, Chunnian

2017-11-01

Corneal topography provides powerful support in the diagnosis and treatment of corneal disease by displaying the corneal surface topography in data or image format. To realize the precise detection of corneal surface topography, an optical system for the corneal topography that is based on a Placido disc is designed, which includes a ring distribution on a Placido disc, an imaging system and a collimating illumination system. First, a mathematical model that is based on the corneal topography working principles is established with MATLAB to determine the distribution of white-and-black rings on the Placido disc, in which the ellipsoid facial rings-target of the Placido disc is utilized. Second, the imaging lens structure is designed and optimized by Zemax software. Last, the collimating illumination lens structure is designed by paraxial ray trace equations. The quality of the corneal topography, which is based on our designed optical system, is evaluated. The high-contrast image of uniformly distributed white-and-black rings is observed through the CCD camera. Our optical system for the corneal topography has high precision, with a measuring region of the cornea with a diameter of approximately 10 mm. Therefore, the creation of this optical system offers guidance for designing and improving the optical system of Placido-disc topography.

Feedbacks between Climate and Fire Emissions

DTIC Science & Technology

2011-11-29

CH4 2. Direct emission of short-lived climate forcers - Black Carbon - Particulate organic matter 3. Production of tropospheric ozone and secondary... tropospheric ozone and secondary organic particulate matter 4. Changes in land surface properties - Black carbon on snow - Albedo Radiative Forcing of Black...lived  climate forcers:  particles 3.  Ozone   production 4. Change in  surface properties Fires Impacts on the Climate System 1. Emission of long lived

Insight into the microscopic structure of an AdS black hole from a thermodynamical phase transition.

PubMed

Wei, Shao-Wen; Liu, Yu-Xiao

2015-09-11

Comparing with an ordinary thermodynamic system, we investigate the possible microscopic structure of a charged anti-de Sitter black hole completely from the thermodynamic viewpoint. The number density of the black hole molecules is introduced to measure the microscopic degrees of freedom of the black hole. We found that the number density suffers a sudden change accompanied by a latent heat when the black hole system crosses the small-large black hole coexistence curve, while when the system passes the critical point, it encounters a second-order phase transition with a vanishing latent heat due to the continuous change of the number density. Moreover, the thermodynamic scalar curvature suggests that there is a weak attractive interaction between two black hole molecules. These phenomena might cast new insight into the underlying microscopic structure of a charged anti-de Sitter black hole.

Relativistic tidal interaction of a white dwarf with a massive black hole

NASA Technical Reports Server (NTRS)

Frolov, V. P.; Khokhlov, A. M.; Novikov, I. D.; Pethick, C. J.

1994-01-01

We compute encounters of a realistic white dwarf model with a massive black hole in the regime where relativistic effects are important, using a three-dimensional, finite-difference, Eulerian, piecewise parabolic method (PPM) hydrodynamical code. Both disruptive and nondisruptive encounters are considered. We identify and discuss relativistic effects important for the problem: relativistic shift of the pericenter distance, time delay, relativistic precession, and the tensorial structure of the tidal forces. In the nondisruptive case, stripping of matter takes place. In the surface layers of the surviving core, complicated hydrodynamical phenomena are revealed. In both disruptive and nondispruptive encounters, material flows out in the form of two thin, S-shaped, supersonic jets. Our results provide realistic initial conditions for the subsequent investigation of the dynamics of the debris in the field of the black hole. We evaluate the critical conditions for complete disruption of the white dwarf, and compare our results with the corresponding results for nonrelativistic encounters.

Influence of EDTA{sup 2-} on the hydrothermal synthesis of CdTe nanocrystallites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gong Haibo; School of Materials Science and Engineering, University of Jinan, Jinan 250022; Hao Xiaopeng, E-mail: xphao@sdu.edu.cn

2011-12-15

Transformation from Te nanorods to CdTe nanoparticles was achieved with the assistance of EDTA as a ligand under hydrothermal conditions. Experimental results showed that at the beginning of reaction Te nucleated and grew into nanorods. With the proceeding of reaction, CdTe nucleus began to emerge on the surface, especially on the tips of Te nanorods. Finally, nearly monodispersed hexagonal CdTe nanoparticles with diameters of about 200 nm were obtained. The effects of EDTA on the morphology and formation of CdTe nanoparticles were discussed in consideration of the strong ligand-effect of EDTA, which greatly decreased the concentration of Cd{sup 2+}. Furthermore,more » the possible formation process of CdTe nanoparticles from Te nanorods was further proposed. The crystal structure and morphology of the products were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). - Graphical Abstract: Firstly, Te nucleated and grew into nanorods in the presence of EDTA{sup 2-}. Then CdTe nucleus began to emerge on Te nanorods and finally monodispersed CdTe nanoparticles were obtained. Highlights: Black-Right-Pointing-Pointer EDTA serves as a strong ligand with Cd{sup 2+}. Black-Right-Pointing-Pointer The existence of EDTA constrains the nucleation of CdTe and promotes the formation of Te nanorods. Black-Right-Pointing-Pointer With the proceeding of reaction, CdTe nucleus began to emerge on the surface, especially on the tips of Te nanorods. Black-Right-Pointing-Pointer Nearly monodispersed hexagonal CdTe nanoparticles with diameters of about 200 nm were finally obtained.« less

Black holes and global structures of spherical spacetimes in Horava-Lifshitz theory

NASA Astrophysics Data System (ADS)

Greenwald, Jared; Lenells, Jonatan; Lu, J. X.; Satheeshkumar, V. H.; Wang, Anzhong

2011-10-01

We systematically study black holes in the Horava-Lifshitz theory by following the kinematic approach, in which a horizon is defined as the surface at which massless test particles are infinitely redshifted. Because of the nonrelativistic dispersion relations, the speed of light is unlimited, and test particles do not follow geodesics. As a result, there are significant differences in causal structures and black holes between general relativity (GR) and the Horava-Lifshitz theory. In particular, the horizon radii generically depend on the energies of test particles. Applying them to the spherical static vacuum solutions found recently in the nonrelativistic general covariant theory of gravity, we find that, for test particles with sufficiently high energy, the radius of the horizon can be made as small as desired, although the singularities can be seen, in principle, only by observers with infinitely high energy. In these studies, we pay particular attention to the global structure of the solutions, and find that, because of the foliation-preserving-diffeomorphism symmetry, Diff(M,F), they are quite different from the corresponding ones given in GR, even though the solutions are the same. In particular, the Diff(M,F) does not allow Penrose diagrams. Among the vacuum solutions, some give rise to the structure of the Einstein-Rosen bridge, in which two asymptotically flat regions are connected by a throat with a finite nonzero radius. We also study slowly rotating solutions in such a setup, and obtain all the solutions characterized by an arbitrary function A0(r). The case A0=0 reduces to the slowly rotating Kerr solution obtained in GR.

Identification of black hole horizons using scalar curvature invariants

NASA Astrophysics Data System (ADS)

Coley, Alan; McNutt, David

2018-01-01

We introduce the concept of a geometric horizon, which is a surface distinguished by the vanishing of certain curvature invariants which characterize its special algebraic character. We motivate its use for the detection of the event horizon of a stationary black hole by providing a set of appropriate scalar polynomial curvature invariants that vanish on this surface. We extend this result by proving that a non-expanding horizon, which generalizes a Killing horizon, coincides with the geometric horizon. Finally, we consider the imploding spherically symmetric metrics and show that the geometric horizon identifies a unique quasi-local surface corresponding to the unique spherically symmetric marginally trapped tube, implying that the spherically symmetric dynamical black holes admit a geometric horizon. Based on these results, we propose a suite of conjectures concerning the application of geometric horizons to more general dynamical black hole scenarios.

Surface engineered two-dimensional and quasi-one-dimensional nanomaterials for electronic and optoelectronic devices

NASA Astrophysics Data System (ADS)

Du, Xiang

As the sizes of individual components in electronic and optoelectronic devices approach nano scale, the performance of the devices is often determined by surface properties due to their large surface-to-volume ratio. Surface phenomena have become one of the cornerstones in nanoelectronic industry. For this reason, research on the surface functionalization has been tremendous amount of growth over the past decades, and promises to be an increasingly important field in the future. Surface functionalization, as an effective technique to modify the surface properties of a material through a physical or chemical approach, exhibits great potential to solve the problems and challenges, and modulate the performance of nanomaterials based functional devices. Surface functionalization drives the developments and applications of modern electronic and optoelectronic devices fabricated by nanomaterials. In this thesis, I demonstrate two surface functionalization approaches, namely, surface transfer doping and H2 annealing, to effectively solve the problems and significantly enhance the performance of 2D (single structure black phosphorus (BP) and heterostructure graphene/Si Schottky junction), and quasi-1D (molybdenum trioxide (MoO 3) nanobelt) nanomaterials based functional devices, respectively. In situ photoelectron spectroscopy (PES) measurements were also carried out to explore the interfacial charge transfer occurring at the interface between the nanostructures and doping layers, and the gap states in MoO 3 thin films, which provides the underlying mechanism to understand and support our device measurement results. In the first part of this thesis, I will discuss the first surface functionalization approach, namely, surface transfer doping, to effectively modulate the ambipolar characteristics of 2D few-layer BP flakes based FETs. The ambipolar characteristics of BP transistors were effectively modulated through in situ surface functionalization with cesium carbonate (Cs2CO3) and MoO3, respectively. Cs2CO3 was found to strongly electron dope black phosphorus. The electron mobility of black phosphorus was significantly enhanced to ˜27 cm2V-1s-1 after 10 nm Cs2CO3 modification, indicating a greatly improved electron transport behavior. In contrast, MoO3 decoration demonstrated a giant hole doping effect. In situ PES characterization confirms the interfacial charge transfer between black phosphorus and doping layers. This doping can also modulate the Schottky junctions formed between metal contacts and black phosphorus flakes, and hence to enhance the responsivity of black phosphorus based photodetectors. These findings coupled with the tunable nature of the surface transfer doping scheme ensure black phosphorus as a promising candidate for further complementary logic electronics. Following the same surface transfer doping technique, I will demonstrate a remarkable performance enhancement of graphene/Si Schottky junction based self-powered photodetectors via surface modification with MoO3 thin film. It was found that the photocurrent responsivity of MoO3 doped graphene/Si photodetectors was highly increased under a wide spectrum of illuminated light from ultraviolet to near infrared. The current on-off ratio reached up to ˜104 under illumination of 500 nm light with intensity of ˜62 muWcm-2. More importantly, the external quantum efficiency of graphene/Si devices was significantly enhanced up to ˜80% by almost four times in the visible light region after MoO3 functionalization. The largely improved photodetecting performance originates from the increased Schottky barrier height at the graphene/Si interface as well as the reduced series resistance after MoO3 modification, which was further corroborated by the in situ PES and electrical transport characterizations. These observations promise a simple method to effectively modify the graphene/Si Schottky junction based self-powered photodetectors and thus significantly enhance their photodetecting performance. After discussion of the first surface functionalization method, next I will introduce the second approach which is H2 annealing, to greatly extend the photoresponse range of single MoO3 nanobelt based photodetector from UV to visible light by introducing substantial gap states. After annealing, the conductance of MoO3 nanobelt was largely enhanced; at the same time, the photodetector possessed wide visible spectrum response. As corroborated by in situ PES investigations, such strong wide spectrum photoresponse arises from the largely enriched oxygen vacancies and gap states in MoO3 nanobelt after H2 annealing. These results open up a new avenue to extend the wide bandgap metal oxide nanomaterials based optoelectronics devices with efficient visible light response through surface modification, i.e. the introduction of the high density of carefully engineered gap states.

The reflectance of Ames 24E, Infrablack, and Martin black. [anodizing coatings for far-infrared space telescopes

NASA Technical Reports Server (NTRS)

Smith, Sheldon M.

1989-01-01

Results are reported from measurements of the specular reflectances (SRs) and bidirectional reflectance distribution functions (BRDFs) of three black optical coatings in the FIR wavelength range. The nonspecular reflectometer apparatus described by Smith (1984) is employed, and the data are presented in tables and graphs and discussed in detail. It is found that Ames 24E has an FIR SR one order of magnitude lower than that of Martin black (MB), with BRDF values characteristic of a nearly Lambertian surface, while Infrablack has SR two orders lower than MB and a specular-diffuse surface; MB itself has a very specular surface.

Managing California black oak for tribal ecocultural restoration

Treesearch

Jonathan W. Long; Ron W. Goode; Raymond J. Gutteriez; Jessica J. Lackey; M. Kat Anderson

2017-01-01

Many tribes in California and Oregon value California black oak (Quercus kelloggii) as a traditional source of food and other values. Over centuries or millennia, Native Americans learned that they could enhance production of desired resources by regularly igniting low-intensity surface fires in stands of black oak. Although black oak is likely to...

Characterization of Structural and Pigmentary Colors in Common Emigrant (Catopsilia Pomona) Butterfly

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ghate, Ekata; Kulkarni, G. R.; Bhoraskar, S. V.

2011-10-20

Study of structural colors in case of insects and butterflies is important for their biomimic and biophotonics applications. Structural color is the color which is produced by physical structures and their interaction with light while pigmentary color is produced by absorption of light by pigments. Common Emigrant butterfly is widely distributed in India. It is of moderate size with wing span of about 60-80 mm. The wings are broadly white with yellow or sulphur yellow coloration at places as well as few dark black patches. It belongs to family Pieridae. A study of structural color in case of Common Emigrantmore » butterfly has been carried out in the present work. The characterization of wing color was performed using absorption spectroscopy. Scanning electron microscopic study of the wings of Common Emigrant butterfly showed that three different types of scales are present on the wing surface dorsally. Diffracting structures are present in certain parts of the surfaces of the various scales. Bead like structures are embedded in the intricate structures of the scales. Absorption spectra revealed that a strong absorption peak is seen in the UV-range. Crystalline structure of beads was confirmed by the X-ray diffraction analysis.« less

Area-angular-momentum inequality for axisymmetric black holes.

PubMed

Dain, Sergio; Reiris, Martin

2011-07-29

We prove the local inequality A≥8π|J|, where A and J are the area and angular momentum of any axially symmetric closed stable minimal surface in an axially symmetric maximal initial data. From this theorem it is proved that the inequality is satisfied for any surface on complete asymptotically flat maximal axisymmetric data. In particular it holds for marginal or event horizons of black holes. Hence, we prove the validity of this inequality for all dynamical (not necessarily near equilibrium) axially symmetric black holes.

"It's an Uphill Battle Everyday": Intersectionality, Low-Income Black Heterosexual Men, and Implications for HIV Prevention Research and Interventions.

PubMed

Bowleg, Lisa; Teti, Michelle; Malebranche, David J; Tschann, Jeanne M

2013-01-01

This interview study, the initial qualitative phase of a larger mixed methods HIV prevention study focused on Black heterosexual men, used intersectionality as a theoretical framework to explore: (1) How a sample of Black heterosexual men describe and experience the multiple intersections of race, gender, and SES; and (2) How these descriptions reflected interlocking systems of social inequality for Black men at the social-structural level. Participants were 30 predominantly low-income self-identified Black heterosexual men between the ages of 18 and 44. Analyses highlighted four themes that demonstrate how participants' individual-level experiences as Black men reflect macro social-structural inequality: (1) racial discrimination and microaggressions; (2) unemployment; (3) incarceration; and (4) police surveillance and harassment. We discuss the study's findings within the context of social-structural factors that disproportionately and adversely impact Black men. We also highlight the implications of the intersectionality perspective for HIV prevention research and interventions for Black heterosexual men.

“It’s an Uphill Battle Everyday”: Intersectionality, Low-Income Black Heterosexual Men, and Implications for HIV Prevention Research and Interventions

PubMed Central

Bowleg, Lisa; Teti, Michelle; Malebranche, David J.; Tschann, Jeanne M.

2012-01-01

This interview study, the initial qualitative phase of a larger mixed methods HIV prevention study focused on Black heterosexual men, used intersectionality as a theoretical framework to explore: (1) How a sample of Black heterosexual men describe and experience the multiple intersections of race, gender, and SES; and (2) How these descriptions reflected interlocking systems of social inequality for Black men at the social-structural level. Participants were 30 predominantly low-income self-identified Black heterosexual men between the ages of 18 and 44. Analyses highlighted four themes that demonstrate how participants’ individual-level experiences as Black men reflect macro social-structural inequality: (1) racial discrimination and microaggressions; (2) unemployment; (3) incarceration; and (4) police surveillance and harassment. We discuss the study’s findings within the context of social-structural factors that disproportionately and adversely impact Black men. We also highlight the implications of the intersectionality perspective for HIV prevention research and interventions for Black heterosexual men. PMID:23482810

Resistance to Black Dot in Potato

USDA-ARS?s Scientific Manuscript database

Black dot fungus can colonize tubers on the surface, in the stolon end, or in a combination of both.On the surface the fungus is prevalent as sclerotia, and in the stolon end the fungus colonizes the vascular tissuesas hyphae. The fungus is introduced to non-infested soils mostly by infected potato ...

Factorial Based Response Surface Modeling with Confidence Intervals for Optimizing Thermal Optical Transmission Analysis of Atmospheric Black Carbon

EPA Science Inventory

We demonstrate how thermal-optical transmission analysis (TOT) for refractory light-absorbing carbon in atmospheric particulate matter was optimized with empirical response surface modeling. TOT employs pyrolysis to distinguish the mass of black carbon (BC) from organic carbon (...

Syntheses, structures and photoelectric properties of a series of Cd(II)/Zn(II) coordination polymers and coordination supramolecules

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jin Jing; Han Xiao; Meng Qin

2013-01-15

Five Cd(II)/Zn(II) complexes [Cd(1,2-bdc)(pz){sub 2}(H{sub 2}O)]{sub n} (1), [Cd1Cd2(btec)(H{sub 2}O){sub 6}]{sub n} (2), [Cd(3,4-pdc) (H{sub 2}O)]{sub n} (3), [Zn(2,5-pdc)(H{sub 2}O){sub 4}]{center_dot}2H{sub 2}O (4) and {l_brace} [Zn(2,5-pdc)(H{sub 2}O){sub 2}]{center_dot}H{sub 2}O{r_brace} {sub n} (5) (H{sub 2}bdc=1,2-benzenedicarboxylic acid, pz=pyrazole, H{sub 4}btec=1,2,4,5-benzenetetracarboxylic acid, H{sub 2}pdc=pyridine-dicarboxylic acid) were hydrothermally synthesized and characterized by single-crystal X-ray diffraction, surface photovoltage spectroscopy, XRD, TG analysis, IR and UV-vis spectra and elemental analysis. Structural analyses show that complexes 1-3 are 1D, 2D and 3D Cd(II) coordination polymers, respectively. Complex 4 is a mononuclear Zn(II) complex. Complex 5 is a 3D Zn(II) coordination polymer. The surface photoelectric properties of complexesmore » were investigated by SPS. The results indicate that all complexes exhibit photoelectric responses in the range of 300-600 nm, which reveals that they all possess certain photoelectric conversion properties. By the comparative analyses, it can be found that the species and coordination micro-environment of central metal ion, the species and property of ligands affect the intensity and scope of photoelectric response. - Graphical abstract: Five Cd(II)/Zn(II) complexes have been hydrothermally synthesized and characterized. The photoelectric properties were studied with SPS. The species and coordination micro-environment of central metal ion, the species and property of ligands all affect the photoelectric responses. Highlights: Black-Right-Pointing-Pointer Five Cd/Zn complexes have been synthesized and characterized. Black-Right-Pointing-Pointer The SPS results indicate they possess obvious photoelectric conversion property. Black-Right-Pointing-Pointer The species and coordination environment of central metal ion affect SPS. Black-Right-Pointing-Pointer The species and property of ligands affect SPS. Black-Right-Pointing-Pointer By the energy-band theory and the crystal filed theory, the SPS are analyzed and assigned.« less

Gravitational surface Hamiltonian and entropy quantization

NASA Astrophysics Data System (ADS)

Bakshi, Ashish; Majhi, Bibhas Ranjan; Samanta, Saurav

2017-02-01

The surface Hamiltonian corresponding to the surface part of a gravitational action has xp structure where p is conjugate momentum of x. Moreover, it leads to TS on the horizon of a black hole. Here T and S are temperature and entropy of the horizon. Imposing the hermiticity condition we quantize this Hamiltonian. This leads to an equidistant spectrum of its eigenvalues. Using this we show that the entropy of the horizon is quantized. This analysis holds for any order of Lanczos-Lovelock gravity. For general relativity, the area spectrum is consistent with Bekenstein's observation. This provides a more robust confirmation of this earlier result as the calculation is based on the direct quantization of the Hamiltonian in the sense of usual quantum mechanics.

Decisions of black parents about infant bedding and sleep surfaces: a qualitative study.

PubMed

Ajao, Taiwo I; Oden, Rosalind P; Joyner, Brandi L; Moon, Rachel Y

2011-09-01

The goal of this qualitative study was to examine factors influencing decisions by black parents regarding use of soft bedding and sleep surfaces for their infants. We conducted focus groups and individual interviews with black mothers of lower and higher socioeconomic status (SES). Mothers were asked about many infant care practices, including sleep surface and bedding. Eighty-three mothers were interviewed, 73 (47 lower and 26 higher SES) in focus groups and 10 (7 lower and 3 higher SES) in individual interviews. The primary reason for using soft surfaces was infant comfort. Parents perceived that infants were uncomfortable if the surface was not soft. Many parents also interpreted "firm sleep surface" to mean taut; they were comfortable with and believed that they were following recommendations for a firm sleep surface when they placed pillows/blankets on the mattress as long as a sheet was pulled tautly over the pillows/blankets. The primary reasons for using soft bedding (including bumper pads) were comfort, safety, and aesthetics. In addition to using bedding to soften sleep surfaces, bedding was used to prevent infant rollover and falls, particularly for infants sleeping on a bed or sofa. Some parents used soft bedding to create an attractive space for the infant. Many black parents believe that soft bedding will keep their infant safe and comfortable. There is much misunderstanding about the meaning of a "firm" sleep surface. Additional educational messages apparently are needed to change parental perceptions and practices.

Holographic non-Fermi liquid in a background magnetic field

NASA Astrophysics Data System (ADS)

Basu, Pallab; He, Jianyang; Mukherjee, Anindya; Shieh, Hsien-Hang

2010-08-01

We study the effects of a nonzero magnetic field on a class of 2+1 dimensional non-Fermi liquids, recently found in [Hong Liu, John McGreevy, and David Vegh, arXiv:0903.2477.] by considering properties of a Fermionic probe in an extremal AdS4 black hole background. Introducing a similar fermionic probe in a dyonic AdS4 black hole geometry, we find that the effect of a magnetic field could be incorporated in a rescaling of the probe fermion’s charge. From this simple fact, we observe interesting effects like gradual disappearance of the Fermi surface and quasiparticle peaks at large magnetic fields and changes in other properties of the system. We also find Landau level like structures and oscillatory phenomena similar to the de-Haas-van Alphen effect.

Degradation of Direct Black 38 dye under visible light and sunlight irradiation by N-doped anatase TIO₂ as photocatalyst.

PubMed

Collazzo, Gabriela Carvalho; Foletto, Edson Luiz; Jahn, Sérgio Luiz; Villetti, Marcos Antônio

2012-05-15

The N-doped TiO(2) photocatalyst was prepared by calcination of a hydrolysis product composed of titanium (IV) isopropoxide with ammonia as the precipitator. X-ray diffraction, surface area, XPS and UV-vis spectra analyses showed a nanosized anatase structure and the appearance of a new absorption band in the visible region caused by nitrogen doping. The degradation of Direct Black 38 dye on the nitrogen-doped TiO(2) photocatalyst was investigated under visible light and sunlight irradiation. The N-doped anatase TiO(2) demonstrated excellent photocatalytic activity under visible light. Under sunlight irradiation, the N-doped sample showed slightly higher activity than that of the non-doped sample. Copyright © 2012 Elsevier Ltd. All rights reserved.

Measurement and image processing evaluation of surface modifications of dental implants G4 pure titanium created by different techniques

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bulutsuz, A. G., E-mail: asligunaya@gmail.com; Demircioglu, P., E-mail: pinar.demircioglu@adu.edu.tr; Bogrekci, I., E-mail: ismail.bogrekci@adu.edu.tr

Foreign substances and organic tissue interaction placed into the jaw in order to eliminate tooth loss involves a highly complex process. Many biological reactions take place as well as the biomechanical forces that influence this formation. Osseointegration denotes to the direct structural and functional association between the living bone and the load-bearing artificial implant's surface. Taking into consideration of the requirements in the manufacturing processes of the implants, surface characterizations with high precise measurement techniques are investigated and thus long-term success of dental implant is emphasized on the importance of these processes in this study. In this research, the detailedmore » surface characterization was performed to identify the dependence of the manufacturing techniques on the surface properties by using the image processing methods and using the scanning electron microscope (SEM) for morphological properties in 3D and Taylor Hobson stylus profilometer for roughness properties in 2D. Three implant surfaces fabricated by different manufacturing techniques were inspected, and a machined surface was included into the study as a reference specimen. The results indicated that different surface treatments were strongly influenced surface morphology. Thus 2D and 3D precise inspection techniques were highlighted on the importance for surface characterization. Different image analyses techniques such as Dark-light technique were used to verify the surface measurement results. The computational phase was performed using image processing toolbox in Matlab with precise evaluation of the roughness for the implant surfaces. The relationship between the number of black and white pixels and surface roughness is presented. FFT image processing and analyses results explicitly imply that the technique is useful in the determination of surface roughness. The results showed that the number of black pixels in the image increases with increase in surface roughness.« less

Active Black Holes: Relevant Plasma Structures, Regimes and Processes Involving All Phase Space*

NASA Astrophysics Data System (ADS)

Coppi, B.

2010-11-01

The presented theory is motivated by the growing body of experimental information on the characteristics, connected with relevant spectral, time and space resolutions, of the radiation emission from objects considered as rotating black holes. In the immediate surroundings of these objects three plasma regions [1] are identified: an innermost Buffer Region, an intermediate Three-regime Region and a Structured Peripheral Region. In the last region a Composite Disk Structure that is a sequence of plasma rings corresponding to closed magnetic surfaces is considered to be present and to allow intermittent accretion flows along the relevant separatrices. The non-linear ``Master Equation'' describing this structure is derived and solved in appropriate asymptotic limits. The rings structure, depending on microscopic plasma characteristics: i) can be excluded from forming in the intermediate region allowing the onset of a spiral structure with which High Frequency Quasi Periodic Oscillations are associated; ii) may be allowed to propagate to the outer edge of the Buffer Region where successive rings with opposite currents are ejected vertically (in opposite directions) and originate the observed jets; iii) is dissipated well before the Buffer Region. *Sponsored in part by the U.S. D.O.E. [1] B. Coppi, Plasmas in the Laboratory and in the Universe, Eds. G. Bertin et al. (Publ. American Institute of Physics, New York, 2010).

Measurement invariance of the Eating Disorder Examination in black and white children and adolescents.

PubMed

Burke, Natasha L; Tanofsky-Kraff, Marian; Crosby, Ross; Mehari, Rim D; Marwitz, Shannon E; Broadney, Miranda M; Shomaker, Lauren B; Kelly, Nichole R; Schvey, Natasha A; Cassidy, Omni; Yanovski, Susan Z; Yanovski, Jack A

2017-07-01

The Eating Disorder Examination (EDE) was originally developed and validated in primarily white female samples. Since data indicate that eating pathology impacts black youth, elucidating the psychometric appropriateness of the EDE for black youth is crucial. A convenience sample was assembled from seven pediatric obesity studies. The EDE was administered to all youth. Confirmatory factor analyses (CFA) were conducted to examine the original four-factor model fit and two alternative factor structures for black and white youth. With acceptable fit, multiple-group CFAs were conducted. For measurement invariant structures, the interactive effects of race with sex, BMIz, adiposity, and age were explored (all significance levels p < .05). For both black and white youth (N = 820; 41% black; 37% male; 6-18 years; BMIz -3.11 to 3.40), the original four-factor EDE structure and alternative eight-item one-factor structure had mixed fit via CFA. However, a seven-item, three-factor structure reflecting Dietary Restraint, Shape/Weight Overvaluation, and Body Dissatisfaction had good fit and held at the level of strict invariance. Girls reported higher factor scores than boys. BMIz and adiposity were positively associated with each subscale. Age was associated with Dietary Restraint and Body Dissatisfaction. The interactional effects between sex, BMIz, and age with race were not significant; however, the interaction between adiposity and race was significant. At higher adiposity, white youth reported greater pathology than black youth. An abbreviated seven-item, three-factor version of the EDE captures eating pathology equivalently across black and white youth. Full psychometric testing of the modified EDE factor structure in black youth is warranted. 2017 Wiley Periodicals, Inc.

Altitude of the Top of the Madison Limestone in the Black Hills area, South Dakota, 1999

USGS Publications Warehouse

Carter, Janet M.; Redden, Jack A.

2000-01-01

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and groundwater in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers).The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study arca arc Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and artesian springs that originate from confined aquifers are common around the periphery of the Black Hills.The purpose of this map is to show the altitude of the top (structure contours) of the Madison Limestone within the area of the Black Hills Hydrology Study. The depth to the top of the Madison Limestone can be estimated at a specific site by subtracting the altitude of the top of the formation from the topographic elevation. However, caution is urged in determining the depth to the top of the formation in areas on the map where the contours are approximately located.

Altitude of the Top of the Deadwood Formation in the Black Hills area, South Dakota, 1999

USGS Publications Warehouse

Carter, Janet M.; Redden, Jack A.

2000-01-01

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers).The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and artesian springs that originate from confined aquifers are common around the periphery of the Black Hills.The purpose of this map is to show the altitude of the top (structure contours) of the Deadwood Formation within the area of the Black Hills Hydrology Study. The depth to the top of the Deadwood Formation can be estimated at a specific site by subtracting the altitude of the top of the formation from the topographic elevation, However, caution is urged in determining the depth to the top of the formation in areas on the map where the contours are approximately located.

Altitude of the Top of the Minnelusa Formation in the Black Hills area, South Dakota, 1999

USGS Publications Warehouse

Carter, Janet M.; Redden, Jack A.

2000-01-01

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers).The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and artesian springs that originate from confined aquifers are common around the periphery of the Black Hills.The purpose of this map is to show the altitude of the top (structure contours) of the Minnelusa Formation within the area of the Black Hills Hydrology Study. The depth to the top of the Minnelusa Formation can be estimated at a specific site by subtracting the altitude of the top of the formation from the topographic elevation. However, caution is urged in determining the depth to the top of the formation in areas on the map where the contours are approximately located.

Altitude of the Top of the Minnekahta Limestone in the Black Hills area, South Dakota, 1999

USGS Publications Warehouse

Carter, Janet M.; Redden, Jack A.

2000-01-01

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and groundwater in the Black Hills area of South Dakota (Driscoli, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of environment and Natural Resources, and the West Dakota Water development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara. Minnekahta, Minnelusa, Madison, and Deadwood aquifers).The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and artesian springs that originate from confined aquifers are common around the periphery of the Black Hills.The purpose of this map is to show the altitude of the top(structure contours) of the Minnekahta limestone within the area of the Black Hills Hydrology Study. The depth to the top of the Minnekahta Limestone can be estimated at a specific site by subtracting the altitude of the top of the formation from the topographic elevation. However, caution is urged in determining the depth to the top of the formation in areas on the map where the contours are approximately located.

Transmembrane myosin chitin synthase involved in mollusc shell formation produced in Dictyostelium is active

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schoenitzer, Veronika; Universitaet Regensburg, Biochemie I, Universitaetsstrasse 31, D-93053 Regensburg; Eichner, Norbert

Highlights: Black-Right-Pointing-Pointer Dictyostelium produces the 264 kDa myosin chitin synthase of bivalve mollusc Atrina. Black-Right-Pointing-Pointer Chitin synthase activity releases chitin, partly associated with the cell surface. Black-Right-Pointing-Pointer Membrane extracts of transgenic slime molds produce radiolabeled chitin in vitro. Black-Right-Pointing-Pointer Chitin producing Dictyostelium cells can be characterized by atomic force microscopy. Black-Right-Pointing-Pointer This model system enables us to study initial processes of chitin biomineralization. -- Abstract: Several mollusc shells contain chitin, which is formed by a transmembrane myosin motor enzyme. This protein could be involved in sensing mechanical and structural changes of the forming, mineralizing extracellular matrix. Here we report themore » heterologous expression of the transmembrane myosin chitin synthase Ar-CS1 of the bivalve mollusc Atrina rigida (2286 amino acid residues, M.W. 264 kDa/monomer) in Dictyostelium discoideum, a model organism for myosin motor proteins. Confocal laser scanning immunofluorescence microscopy (CLSM), chitin binding GFP detection of chitin on cells and released to the cell culture medium, and a radiochemical activity assay of membrane extracts revealed expression and enzymatic activity of the mollusc chitin synthase in transgenic slime mold cells. First high-resolution atomic force microscopy (AFM) images of Ar-CS1 transformed cellulose synthase deficient D. discoideumdcsA{sup -} cell lines are shown.« less

Modeling of Carbon Mortar Color Expression Using Artificial Neural Network.

PubMed

Jang, Hong-Seok; Kim, Ju-Hee; Shuli, Xing; So, Seung-Young

2018-09-01

Colored concrete uses pigments and white Portland cement (WPC) to perform decorative functions together with structural function. Pigments are used in permanent coloring of concrete with colors different from the natural color of the cement or the aggregates with mixing WPC. In this study, an artificial neural networks study was carried out to predict the color evaluation of black mortar using pigment and carbon black. A data set of a laboratory work, in which a total of 9 mortars were produced, was utilized in the Artificial Neural Networks (ANNs) study. The mortar mixture parameters were nine different pigment and carbon black ratios. Each mortar was measured at ten locations on the surface and averaged. Color can be evaluated by measurements of tristimulus values L* , a* and b* , represented in the chromatic space CIELAB. The L* value is a measure of luminosity (0 darkness), from completely opaque (0) to completely transparent (100); a* is a measure of redness (-a* greenness) and b* of yellowness (-b* blueness). ANN model is constructed, trained and tested using these data. The data used in the ANN model are arranged in a format of three input parameters that cover the pigment, carbon black and WPC and, an output parameter which is the color parameters of the black colored mortar. The results showed that ANN can be an alternative approach for the predicting the color parameters using mortar ingredients as input parameters.

In the Absence of Ideology: Blacks in Colonial America and the Modern Black Experience.

ERIC Educational Resources Information Center

Jones, Rhett S.

1988-01-01

The experiences of Whites and Blacks in the American Colonial period were strikingly different. Blacks were committed to Whites' Enlightenment ideology, which did not reflect Black experience. Blacks in the Colonial era were unable to create political structures capable of making sense of the Black experience. (BJV)

Nearly extremal apparent horizons in simulations of merging black holes

NASA Astrophysics Data System (ADS)

Lovelace, Geoffrey; Scheel, Mark A.; Owen, Robert; Giesler, Matthew; Katebi, Reza; Szilágyi, Béla; Chu, Tony; Demos, Nicholas; Hemberger, Daniel A.; Kidder, Lawrence E.; Pfeiffer, Harald P.; Afshari, Nousha

2015-03-01

The spin angular momentum S of an isolated Kerr black hole is bounded by the surface area A of its apparent horizon: 8π S≤slant A, with equality for extremal black holes. In this paper, we explore the extremality of individual and common apparent horizons for merging, rapidly spinning binary black holes. We consider simulations of merging black holes with equal masses M and initial spin angular momenta aligned with the orbital angular momentum, including new simulations with spin magnitudes up to S/{{M}2}=0.994. We measure the area and (using approximate Killing vectors) the spin on the individual and common apparent horizons, finding that the inequality 8π S\\lt A is satisfied in all cases but is very close to equality on the common apparent horizon at the instant it first appears. We also evaluate the Booth-Fairhurst extremality, whose value for a given apparent horizon depends on the scaling of the horizon’s null normal vectors. In particular, we introduce a gauge-invariant lower bound on the extremality by computing the smallest value that Booth and Fairhurst’s extremality parameter can take for any scaling. Using this lower bound, we conclude that the common horizons are at least moderately close to extremal just after they appear. Finally, following Lovelace et al (2008 Phys. Rev. D 78 084017), we construct quasiequilibrium binary-black hole initial data with ‘overspun’ marginally trapped surfaces with 8π S\\gt A. We show that the overspun surfaces are indeed superextremal: our lower bound on their Booth-Fairhurst extremality exceeds unity. However, we confirm that these superextremal surfaces are always surrounded by marginally outer trapped surfaces (i.e., by apparent horizons) with 8π S\\lt A. The extremality lower bound on the enclosing apparent horizon is always less than unity but can exceed the value for an extremal Kerr black hole.

Mass-deformed ABJM and black holes in AdS4

NASA Astrophysics Data System (ADS)

Bobev, Nikolay; Min, Vincent S.; Pilch, Krzysztof

2018-03-01

We find a class of new supersymmetric dyonic black holes in four-dimensional maximal gauged supergravity which are asymptotic to the SU(3) × U(1) invariant AdS4 Warner vacuum. These black holes can be embedded in eleven-dimensional supergravity where they describe the backreaction of M2-branes wrapped on a Riemann surface. The holographic dual description of these supergravity backgrounds is given by a partial topological twist on a Riemann surface of a three-dimensional N=2 SCFT that is obtained by a mass-deformation of the ABJM theory. We compute explicitly the topologically twisted index of this SCFT and show that it accounts for the entropy of the black holes.

Spectroscopic and solubility characteristics of oxidized soots

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chughtai, A.R.; Jassim, J.A.; Peterson, J.H.

1991-01-01

Spectroscopic and solubility studies of reaction products of soot (black carbon) with O{sub 3}, NO{sub 2}/N{sub 2}O{sub 4}, and SO{sub 2} have revealed a relationship between reactivity and product solubility and structure. A remarkably high solubility of ozonated n-hexane soot has its origin in the formation of anhydride and lactone surface structures and their subsequent hydrolysis to carboxylic acid species. Calculations indicate that the rate of surface carboxylation of 0.1-{mu}m diameter spheroidal soot particles, in the presence of 50 ppbv ozone at ambient temperature, is such that solubilization may occur within a 30-minute time frame. Measurements on ambient air aerosolmore » samples in metropolitan Denver are consistent with these observations and demonstrate the high reactivity of soot with ozone even at very low levels in natural systems.« less

Pixel-wise deblurring imaging system based on active vision for structural health monitoring at a speed of 100 km/h

NASA Astrophysics Data System (ADS)

Hayakawa, Tomohiko; Moko, Yushi; Morishita, Kenta; Ishikawa, Masatoshi

2018-04-01

In this paper, we propose a pixel-wise deblurring imaging (PDI) system based on active vision for compensation of the blur caused by high-speed one-dimensional motion between a camera and a target. The optical axis is controlled by back-and-forth motion of a galvanometer mirror to compensate the motion. High-spatial-resolution image captured by our system in high-speed motion is useful for efficient and precise visual inspection, such as visually judging abnormal parts of a tunnel surface to prevent accidents; hence, we applied the PDI system for structural health monitoring. By mounting the system onto a vehicle in a tunnel, we confirmed significant improvement in image quality for submillimeter black-and-white stripes and real tunnel-surface cracks at a speed of 100 km/h.

Black hole mass measurement using molecular gas kinematics: what ALMA can do

NASA Astrophysics Data System (ADS)

Yoon, Ilsang

2017-04-01

We study the limits of the spatial and velocity resolution of radio interferometry to infer the mass of supermassive black holes (SMBHs) in galactic centres using the kinematics of circum-nuclear molecular gas, by considering the shapes of the galaxy surface brightness profile, signal-to-noise ratios (S/Ns) of the position-velocity diagram (PVD) and systematic errors due to the spatial and velocity structure of the molecular gas. We argue that for fixed galaxy stellar mass and SMBH mass, the spatial and velocity scales that need to be resolved increase and decrease, respectively, with decreasing Sérsic index of the galaxy surface brightness profile. We validate our arguments using simulated PVDs for varying beam size and velocity channel width. Furthermore, we consider the systematic effects on the inference of the SMBH mass by simulating PVDs including the spatial and velocity structure of the molecular gas, which demonstrates that their impacts are not significant for a PVD with good S/N unless the spatial and velocity scale associated with the systematic effects are comparable to or larger than the angular resolution and velocity channel width of the PVD from pure circular motion. Also, we caution that a bias in a galaxy surface brightness profile owing to the poor resolution of a galaxy photometric image can largely bias the SMBH mass by an order of magnitude. This study shows the promise and the limits of ALMA observations for measuring SMBH mass using molecular gas kinematics and provides a useful technical justification for an ALMA proposal with the science goal of measuring SMBH mass.

Solitary Ring Pairs and Non-Thermal Regimes in Plasmas Connected with Black Holes*

NASA Astrophysics Data System (ADS)

Coppi, Bruno

2011-10-01

The two-dimensional plasma and field configurations that can be associated with compact objects such as black holes are described, (in the limit where assuming a scalar pressure can be justified), by two characteristic non-linear equations: i) one that connects the plasma density profile to that of the relevant magnetic surfaces and is called the ``master equation'': ii) the other, the ``vertical equilibrium equation,'' connects the plasma pressure to the density and the magnetic surfaces and is closely related to the G-S equation for magnetically confined laboratory plasmas. Two kinds of solutions are found that consist of: i) a periodic sequence of plasma rings; ii) solitary pairs of rings. Experimental observations support the presence of rings around collapsed objects. Tridimensional configuration are found in the linear approximation as consisting of trailing spirals. Observations of High Frequency Quasi-Periodic oscillations implies that they originate from 3-dimentional structures. The existing theory is extended to involve non-thermal particle distributions in order to comply with relevant experimental observations. *Sponsored in part by the U.S. DOE.

Cluster structure of anaerobic aggregates of an expanded granular sludge bed reactor.

PubMed

Gonzalez-Gil, G; Lens, P N; Van Aelst, A; Van As, H; Versprille, A I; Lettinga, G

2001-08-01

The metabolic properties and ultrastructure of mesophilic aggregates from a full-scale expanded granular sludge bed reactor treating brewery wastewater are described. The aggregates had a very high methanogenic activity on acetate (17.19 mmol of CH(4)/g of volatile suspended solids [VSS].day or 1.1 g of CH(4) chemical oxygen demand/g of VSS.day). Fluorescent in situ hybridization using 16S rRNA probes of crushed granules showed that 70 and 30% of the cells belonged to the archaebacterial and eubacterial domains, respectively. The spherical aggregates were black but contained numerous whitish spots on their surfaces. Cross-sectioning these aggregates revealed that the white spots appeared to be white clusters embedded in a black matrix. The white clusters were found to develop simultaneously with the increase in diameter. Energy-dispersed X-ray analysis and back-scattered electron microscopy showed that the whitish clusters contained mainly organic matter and no inorganic calcium precipitates. The white clusters had a higher density than the black matrix, as evidenced by the denser cell arrangement observed by high-magnification electron microscopy and the significantly higher effective diffusion coefficient determined by nuclear magnetic resonance imaging. High-magnification electron microscopy indicated a segregation of acetate-utilizing methanogens (Methanosaeta spp.) in the white clusters from syntrophic species and hydrogenotrophic methanogens (Methanobacterium-like and Methanospirillum-like organisms) in the black matrix. A number of physical and microbial ecology reasons for the observed structure are proposed, including the advantage of segregation for high-rate degradation of syntrophic substrates.

BINARY BLACK HOLES, GAS SLOSHING, AND COLD FRONTS IN THE X-RAY HALO HOSTING 4C+37.11

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andrade-Santos, Felipe; Bogdán, Ákos; Forman, William R.

We analyzed deep Chandra ACIS-I exposures of the cluster-scale X-ray halo surrounding the radio source 4C+37.11. This remarkable system hosts the closest resolved pair of super-massive black holes and an exceptionally luminous elliptical galaxy, the likely product of a series of past mergers. We characterize the halo with r {sub 500} ∼ 0.95 Mpc, M {sub 500} = 2.5 ± 0.2 × 10{sup 14} M {sub ⊙}, kT = 4.6 ± 0.2 keV, and a gas mass of M {sub g,500} = 2.2 ± 0.1 × 10{sup 13} M {sub ⊙}. The gas mass fraction within r {sub 500} ismore » f {sub g} = 0.09 ± 0.01. The entropy profile shows large non-gravitational heating in the central regions. We see several surface brightness jumps, associated with substantial temperature and density changes but approximate pressure equilibrium, implying that these are sloshing structures driven by a recent merger. A residual intensity image shows a core spiral structure closely matching that seen in the Perseus cluster, although at z = 0.055 the spiral pattern is less distinct. We infer that the most recent merger occurred 1–2 Gyr ago and that the event that brought the two observed super-massive black holes to the system core is even older. Under this interpretation, the black hole binary pair has, unusually, remained at a parsec-scale separation for more than 2 Gyr.« less

Cluster Structure of Anaerobic Aggregates of an Expanded Granular Sludge Bed Reactor

PubMed Central

Gonzalez-Gil, G.; Lens, P. N. L.; Van Aelst, A.; Van As, H.; Versprille, A. I.; Lettinga, G.

2001-01-01

The metabolic properties and ultrastructure of mesophilic aggregates from a full-scale expanded granular sludge bed reactor treating brewery wastewater are described. The aggregates had a very high methanogenic activity on acetate (17.19 mmol of CH4/g of volatile suspended solids [VSS]·day or 1.1 g of CH4 chemical oxygen demand/g of VSS·day). Fluorescent in situ hybridization using 16S rRNA probes of crushed granules showed that 70 and 30% of the cells belonged to the archaebacterial and eubacterial domains, respectively. The spherical aggregates were black but contained numerous whitish spots on their surfaces. Cross-sectioning these aggregates revealed that the white spots appeared to be white clusters embedded in a black matrix. The white clusters were found to develop simultaneously with the increase in diameter. Energy-dispersed X-ray analysis and back-scattered electron microscopy showed that the whitish clusters contained mainly organic matter and no inorganic calcium precipitates. The white clusters had a higher density than the black matrix, as evidenced by the denser cell arrangement observed by high-magnification electron microscopy and the significantly higher effective diffusion coefficient determined by nuclear magnetic resonance imaging. High-magnification electron microscopy indicated a segregation of acetate-utilizing methanogens (Methanosaeta spp.) in the white clusters from syntrophic species and hydrogenotrophic methanogens (Methanobacterium-like and Methanospirillum-like organisms) in the black matrix. A number of physical and microbial ecology reasons for the observed structure are proposed, including the advantage of segregation for high-rate degradation of syntrophic substrates. PMID:11472948

Two-Dimensional Dirac Fermions Protected by Space-Time Inversion Symmetry in Black Phosphorus

NASA Astrophysics Data System (ADS)

Kim, Jimin; Baik, Seung Su; Jung, Sung Won; Sohn, Yeongsup; Ryu, Sae Hee; Choi, Hyoung Joon; Yang, Bohm-Jung; Kim, Keun Su

2017-12-01

We report the realization of novel symmetry-protected Dirac fermions in a surface-doped two-dimensional (2D) semiconductor, black phosphorus. The widely tunable band gap of black phosphorus by the surface Stark effect is employed to achieve a surprisingly large band inversion up to ˜0.6 eV . High-resolution angle-resolved photoemission spectra directly reveal the pair creation of Dirac points and their movement along the axis of the glide-mirror symmetry. Unlike graphene, the Dirac point of black phosphorus is stable, as protected by space-time inversion symmetry, even in the presence of spin-orbit coupling. Our results establish black phosphorus in the inverted regime as a simple model system of 2D symmetry-protected (topological) Dirac semimetals, offering an unprecedented opportunity for the discovery of 2D Weyl semimetals.

Kinetics, Thermodynamics and Modelling of Amido Black Dye Photodegradation in Water Using Co/TiO2 Nanoparticles.

PubMed

Ali, Imran; M L Alharbi, Omar; A Alothman, Zeid; Badjah, Ahmad Yacine

2018-05-16

Titanium oxide nanoparticles were doped with copper and characterized by XRD, FT-IR, TEM and SEM. The surface morphology was spherical with 15-26 nm as particle size. The doped titanium oxide (Co/TiO 2 ) nanomaterial was used for photodegradation of amido black dye in water. The maximum photodegradation of amido black obtained was 90%. The values of free energy, and enthalpy were negative, indicating spontaneous photodegradation of amido black dye. The photodegradation of amido black dye obeyed first order kinetic model. The photodegradation mechanism of amido black involved adsorption of the dye on the surface of cobalt doped titanium oxide and its degradation under UV radiation. The electron (e - ) and hole (h + ) pairs are generated by Co/TiO 2 , which consequently generated superoxide oxygen anion and hydroxyl free radical. These species degraded amido black dye. The reported method is fast, effective and economic, which may be utilized to remove amido black in water. The doped TiO 2 catalyst was quite stable and can be used up to 5 cycles. This article is protected by copyright. All rights reserved. This article is protected by copyright. All rights reserved.

Regional Responses to Black Carbon Aerosols: The Importance of Air-Sea Interaction

NASA Astrophysics Data System (ADS)

Gnanadesikan, A.; Scott, A. A.; Pradal, M.-A.; Seviour, W. J. M.; Waugh, D. W.

2017-12-01

The impact of modern black carbon aerosols on climate via their changes in radiative balance is studied using a coupled model where sea surface temperatures (SSTs) are allowed to vary and an atmosphere-only version of the same model where SSTs are held fixed. Allowing the ocean to respond is shown to have a profound impact on the pattern of temperature change. Particularly, large impacts are found in the North Pacific (which cools by up to 1 K in the coupled model) and in north central Asia (which warms in the coupled simulation and cools in the fixed SST simulation). Neither set of experiments shows large changes in surface temperatures in the Southeast Asian region where the atmospheric burden of black carbon is highest. These results are related to the stabilization of the atmosphere and changes in oceanic heat transport. Over the North Pacific, atmospheric stabilization results in an increase in stratiform clouds. The resulting shading reduces evaporation, freshening the surface layer of the ocean and reducing the inflow of warm subtropical waters. Over the land, a delicate balance between greater atmospheric absorption, shading of the surface and changes in latent cooling of the surface helps to determine whether warming or cooling is seen. Our results emphasize the importance of coupling in determining the response of the climate system to black carbon and suggest that black carbon may play an important role in modulating climate change over the North Pacific.

Nanoalloying and phase transformations during thermal treatment of physical mixtures of Pd and Cu nanoparticles

PubMed Central

Mukundan, Vineetha; Yin, Jun; Joseph, Pharrah; Luo, Jin; Shan, Shiyao; Zakharov, Dmitri N; Zhong, Chuan-Jian; Malis, Oana

2014-01-01

Nanoscale alloying and phase transformations in physical mixtures of Pd and Cu ultrafine nanoparticles are investigated in real time with in situ synchrotron-based x-ray diffraction complemented by ex situ high-resolution transmission electron microscopy. The combination of metal–support interaction and reactive/non-reactive environment was found to determine the thermal evolution and ultimate structure of this binary system. At 300 °C, the nanoparticles supported on silica and carbon black intermix to form a chemically ordered CsCl-type (B2) alloy phase. The B2 phase transforms into a disordered fcc alloy at higher temperature (> 450 °C). The alloy nanoparticles supported on silica and carbon black are homogeneous in volume, but evidence was found of Pd surface enrichment. In sharp contrast, when supported on alumina, the two metals segregated at 300 °C to produce almost pure fcc Cu and Pd phases. Upon further annealing of the mixture on alumina above 600 °C, the two metals interdiffused, forming two distinct disordered alloys of compositions 30% and 90% Pd. The annealing atmosphere also plays a major role in the structural evolution of these bimetallic nanoparticles. The nanoparticles annealed in forming gas are larger than the nanoparticles annealing in helium due to reduction of the surface oxides that promotes coalescence and sintering. PMID:27877663

Seasonal and interannual changes in zooplankton community in the coastal zone of the North-Eastern Black Sea.

NASA Astrophysics Data System (ADS)

Nikishina, A. B.; Arashkevich, E. G.; Louppova, N. E.; Soloviev, K. A.

2009-04-01

The phenological response of zooplankton community is a result of simultaneous effect of several factors: feeding conditions, predation abundance, periods of reproduction of common species and hydrodynamic regime. The Black sea ecosystem is one of the best studied in the world, otherwise there is still some illegibility about ecosystem functioning and especially about environmental factors influence on zooplankton dynamics. For the last twenty years pelagic system of the Black Sea has changed dramatically. The invasion of ctenophore Mnemiopsis leidyi in the middle of eighties caused significant decrease in zooplankton biomass. It also altered plankton structure and shifted periods of mass reproduction of the abundant species and biomass maximums. For instance, before the invasion of Mnemiopsis the maximum of zooplankton biomass was observed in autumn (data by A. Pasternak, 1983), and after that the maximum moved to the spring (data by V.S. Khoroshilov, 1999). The incursion of ctenophore Beroe ovata feeding on Mnemiopsis in the nineties has led to the enhancement of zooplankton community. Although the detailed analysis of seasonal zooplankton dynamics wasn't performed in the recent years. The object of our research was to study seasonal and interannual changes in zooplankton community in the coastal area of the North-Eastern Black Sea. Analysis of interannual, seasonal and spatial changes in zooplankton distribution, abundance and species composition along with age structure of dominant populations were performed based on investigations during 2005-2008 years in the North-Eastern Black Sea. Plankton samples were obtained monthly since June 2005 till December 2008. Plankton was collected at three stations at depths 25m, 50m and 500-1000m along the transect from the Blue Bay to the open sea. Sampling of gelatinous animals was conducted in parallel to the zooplankton sampling. Simultaneously with plankton sampling CTD data were obtained. The feeding conditions were obtained using SSC satellite data. For studying vertical distribution of zooplankton depth stratified samples were collected in different seasons. To evaluate seasonal variations in reproduction and offspring development of dominant mesozooplankton populations, we analyzed age structure of five species: four herbivorous copepods - Acartia clausi, Pseudocalanus elongatus, Paracalanus parvus and Calanus euxinus, and carnivorous chaethognaths Parasagitta setosa. Periods of mass reproduction varied in different years. The possible reason for this variation is the effect of climate change and top-predators on seasonal shift in zooplankton dynamics. Whereas timing of reproduction is related to life strategy of species, an intensity of reproduction and success of new generations depend on food supply. The impact of food conditions on abundance and age structure of herbivores was studied in the different seasons. Vertical distribution of different species also altered from year to year. Thus, in "warm" July 2007 (sea surface temperature 27°C) most of the Calanus euxinus population concentrated in the deeper layers than in "cold" July 2005 (sea surface temperature 22°C).

The Effect of Overstory Removal Upon Surface WInd in a Black Spruce Bog

Treesearch

James M. Brown

1972-01-01

Wind passage was measured over a black spruce canopy, at the surface under the canopy, and in a clearcut strip in a northern Minnesota bog. During a 40-day period wind below the canopy was 10 percent of that above the canopy while the wind in the clearcut strip was 45 percent of the total above the canopy. Wind at the surface of the clearcut strip was of longer...

Comparison of the bidirectional reflectance distribution function of various surfaces

NASA Astrophysics Data System (ADS)

Fernandez, Rene; Seasholtz, Richard G.; Oberle, Lawrence G.; Kadambi, Jaikrishnan R.

1989-04-01

This paper describes the development and use of a system to measure the bidirectional reflectance distribution function (BRDF) of various surfaces. The BRDF measurements are to be used in the analysis and design of optical measurement systems such as laser anemometers. An Ar-ion laser (514 nm) was the light source. Preliminary results are presented for eight samples: two glossy black paints, two flat black paints, black glass, sand-blasted Al, unworked Al, and a white paint. A BaSO4 white reflectance standard was used as the reference sample throughout the tests.

Enhanced performance of VOx-based bolometer using patterned gold black absorber

NASA Astrophysics Data System (ADS)

Smith, Evan M.; Panjwani, Deep; Ginn, James; Warren, Andrew; Long, Christopher; Figuieredo, Pedro; Smith, Christian; Perlstein, Joshua; Walter, Nick; Hirschmugl, Carol; Peale, Robert E.; Shelton, David J.

2015-06-01

Patterned highly absorbing gold black film has been selectively deposited on the active surfaces of a vanadium-oxide-based infrared bolometer array. Patterning by metal lift-off relies on protection of the fragile gold black with an evaporated oxide, which preserves gold black's near unity absorption. This patterned gold black also survives the dry-etch removal of the sacrificial polyimide used to fabricate the air-bridge bolometers. Infrared responsivity is substantially improved by the gold black coating without significantly increasing noise. The increase in the time constant caused by the additional mass of gold black is a modest 14%.

Demographic connectivity for ursid populations at wildlife crossing structures in Banff National Park.

PubMed

Sawaya, Michael A; Clevenger, Anthony P; Kalinowski, Steven T

2013-08-01

Wildlife crossing structures are one solution to mitigating the fragmentation of wildlife populations caused by roads, but their effectiveness in providing connectivity has only been superficially evaluated. Hundreds of grizzly (Ursus arctos) and black bear (Ursus americanus) passages through under and overpasses have been recorded in Banff National Park, Alberta, Canada. However, the ability of crossing structures to allow individual and population-level movements across road networks remains unknown. In April 2006, we initiated a 3-year investigation into whether crossing structures provide demographic connectivity for grizzly and black bears in Banff National Park. We collected hair with multiple noninvasive methods to obtain genetic samples from grizzly and black bears around the Bow Valley. Our objectives were to determine the number of male and female grizzly and black bears that use crossing structures; examine spatial and temporal patterns of crossings; and estimate the proportions of grizzly and black bear populations in the Bow Valley that use crossing structures. Fifteen grizzly (7 female, 8 male) and 17 black bears (8 female, 9 male) used wildlife crossing structures. The number of individuals detected at wildlife crossing structures was highly correlated with the number of passages in space and time. Grizzly bears used open crossing structures (e.g., overpasses) more often than constricted crossings (e.g., culverts). Peak use of crossing structures for both bear species occurred in July, when high rates of foraging activity coincide with mating season. We compared the number of bears that used crossings with estimates of population abundance from a related study and determined that substantial percentages of grizzly (15.0% in 2006, 19.8% in 2008) and black bear (17.6% in 2006, 11.0% in 2008) populations used crossing structures. On the basis of our results, we concluded wildlife crossing structures provide demographic connectivity for bear populations in Banff National Park. © 2013 Society for Conservation Biology.

Nanoscale size dependence parameters on lattice thermal conductivity of Wurtzite GaN nanowires

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mamand, S.M., E-mail: soran.mamand@univsul.net; Omar, M.S.; Muhammad, A.J.

2012-05-15

Graphical abstract: Temperature dependence of calculated lattice thermal conductivity of Wurtzite GaN nanowires. Highlights: Black-Right-Pointing-Pointer A modified Callaway model is used to calculate lattice thermal conductivity of Wurtzite GaN nanowires. Black-Right-Pointing-Pointer A direct method is used to calculate phonon group velocity for these nanowires. Black-Right-Pointing-Pointer 3-Gruneisen parameter, surface roughness, and dislocations are successfully investigated. Black-Right-Pointing-Pointer Dislocation densities are decreases with the decrease of wires diameter. -- Abstract: A detailed calculation of lattice thermal conductivity of freestanding Wurtzite GaN nanowires with diameter ranging from 97 to 160 nm in the temperature range 2-300 K, was performed using a modified Callaway model.more » Both longitudinal and transverse modes are taken into account explicitly in the model. A method is used to calculate the Debye and phonon group velocities for different nanowire diameters from their related melting points. Effect of Gruneisen parameter, surface roughness, and dislocations as structure dependent parameters are successfully used to correlate the calculated values of lattice thermal conductivity to that of the experimentally measured curves. It was observed that Gruneisen parameter will decrease with decreasing nanowire diameters. Scattering of phonons is assumed to be by nanowire boundaries, imperfections, dislocations, electrons, and other phonons via both normal and Umklapp processes. Phonon confinement and size effects as well as the role of dislocation in limiting thermal conductivity are investigated. At high temperatures and for dislocation densities greater than 10{sup 14} m{sup -2} the lattice thermal conductivity would be limited by dislocation density, but for dislocation densities less than 10{sup 14} m{sup -2}, lattice thermal conductivity would be independent of that.« less

Layered inorganic/organic mercaptopropyl pendant chain hybrid for chelating heavy cations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Macedo, Thais R.; Petrucelli, Giovanni C.; Pinto, Alane A.

2011-12-15

Graphical abstract: Crystalline lamellar silicate RUB-18 was immobilized with mercaptopropyl groups at the surface and then used as support for cadmium and lead removal from aqueous solutions. Highlights: Black-Right-Pointing-Pointer Synthetic methodology requires intercalation. Black-Right-Pointing-Pointer Organofunctionalized ilerite compound as sorbent. Black-Right-Pointing-Pointer Active mercaptopropyl groups remove cations. Black-Right-Pointing-Pointer High maximum sorption capacity for cadmium. -- Abstract: Heavy metal sorbents with uptake capacities for divalent cadmium and lead cation removal from aqueous solutions have been synthesized by grafting mercaptopropyltrimethoxysilane onto the surface of two different precursors obtained from lamellar ilerite, its acidic and the cetyltrimethylammonium exchanged forms. The organofunctionalization was carried out bymore » two different procedures: reflux and solvent evaporation methodologies. Elemental analysis data based on carbon content gave 1.37 and 3.53 mmol of organic pendant groups per gram of hybrid by the reflux method, when starting from acidic ilerite and the surfactant form. X-ray diffraction corroborated the maintenance of the original crystallinity. Infrared spectroscopy and nuclear magnetic resonance for {sup 29}Si and {sup 13}C nuclei are in agreement with the success of the proposed method. The sulfur basic centers attached to the lamellar structure are used to coordinate both cations at the solid/liquid interface. The isotherms were obtained through the batchwise process and the experimental data were adjusted to the Freundlich model. The maximum sorption capacities of 5.55 and 5.12 mmol g{sup -1} for lead and 6.10 and 7.10 mmol g{sup -1} for cadmium were obtained for organofunctionalized ilerite and its surfactant form, synthesized by reflux methodology. This behavior suggested that these hybrids could be employed as promising sorbents with a polluted system.« less

Black holes and global structures of spherical spacetimes in Horava-Lifshitz theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Greenwald, Jared; Satheeshkumar, V. H.; Lenells, Jonatan

We systematically study black holes in the Horava-Lifshitz theory by following the kinematic approach, in which a horizon is defined as the surface at which massless test particles are infinitely redshifted. Because of the nonrelativistic dispersion relations, the speed of light is unlimited, and test particles do not follow geodesics. As a result, there are significant differences in causal structures and black holes between general relativity (GR) and the Horava-Lifshitz theory. In particular, the horizon radii generically depend on the energies of test particles. Applying them to the spherical static vacuum solutions found recently in the nonrelativistic general covariant theorymore » of gravity, we find that, for test particles with sufficiently high energy, the radius of the horizon can be made as small as desired, although the singularities can be seen, in principle, only by observers with infinitely high energy. In these studies, we pay particular attention to the global structure of the solutions, and find that, because of the foliation-preserving-diffeomorphism symmetry, Diff(M,F), they are quite different from the corresponding ones given in GR, even though the solutions are the same. In particular, the Diff(M,F) does not allow Penrose diagrams. Among the vacuum solutions, some give rise to the structure of the Einstein-Rosen bridge, in which two asymptotically flat regions are connected by a throat with a finite nonzero radius. We also study slowly rotating solutions in such a setup, and obtain all the solutions characterized by an arbitrary function A{sub 0}(r). The case A{sub 0}=0 reduces to the slowly rotating Kerr solution obtained in GR.« less

Testing the Association Between Traditional and Novel Indicators of County-Level Structural Racism and Birth Outcomes among Black and White Women.

PubMed

Chambers, Brittany D; Erausquin, Jennifer Toller; Tanner, Amanda E; Nichols, Tracy R; Brown-Jeffy, Shelly

2017-12-07

Despite decreases in infants born premature and at low birth weight in the United States (U.S.), racial disparities between Black and White women continue. In response, the purpose of this analysis was to examine associations between both traditional and novel indicators of county-level structural racism and birth outcomes among Black and White women. We merged individual-level data from the California Birth Statistical Master Files 2009-2013 with county-level data from the United States (U.S.) Census American Community Survey. We used hierarchical linear modeling to examine Black-White differences among 531,170 primiparous women across 33 California counties. Traditional (e.g., dissimilarity index) and novel indicators (e.g., Black to White ratio in elected office) were associated with earlier gestational age and lower birth weight among Black and White women. A traditional indicator was more strongly associated with earlier gestational age for Black women than for White women. This was the first study to empirically demonstrate that structural racism, measured by both traditional and novel indicators, is associated with poor health and wellbeing of infants born to Black and White women. However, findings indicate traditional indicators of structural racism, rather than novel indicators, better explain racial disparities in birth outcomes. Results also suggest the need to develop more innovative approaches to: (1) measure structural racism at the county-level and (2) reform public policies to increase integration and access to resources.

Novel platinum black electroplating technique improving mechanical stability.

PubMed

Kim, Raeyoung; Nam, Yoonkey

2013-01-01

Platinum black microelectrodes are widely used as an effective neural signal recording sensor. The simple fabrication process, high quality signal recording and proper biocompatibility are the main advantages of platinum black microelectrodes. When microelectrodes are exposed to actual biological system, various physical stimuli are applied. However, the porous structure of platinum black is vulnerable to external stimuli and destroyed easily. The impedance level of the microelectrode increases when the microelectrodes are damaged resulting in decreased recording performance. In this study, we developed mechanically stable platinum black microelectrodes by adding polydopamine. The polydopamine layer was added between the platinum black structures by electrodeposition method. The initial impedance level of platinum black only microelectrodes and polydopamine added microelectrodes were similar but after applying ultrasonication the impedance value dramatically increased for platinum black only microelectrodes, whereas polydopamine added microelectrodes showed little increase which were nearly retained initial values. Polydopamine added platinum black microelectrodes are expected to extend the availability as neural sensors.

Abundance of Black-backed woodpeckers and other birds in relation to disturbance and forest structure in the Black Hills and Bear Lodge Mountains of South Dakota and Wyoming

Treesearch

Elizabeth A. Matseur

2017-01-01

Natural disturbances, such as wildfire and mountain pine beetle (Dentroctonus ponderosae, hereafter MPB) infestations, are two sources of large-scale disturbance that can significantly alter forest structure in the Black Hills. The Black Hills has recently experienced one of the largest MPB outbreaks in the last 100 years, along with varying levels of wildfires...

Structural racism and myocardial infarction in the United States

PubMed Central

Lukachko, Alicia; Hatzenbuehler, Mark L.; Keyes, Katherine M.

2014-01-01

There is a growing research literature suggesting that racism is an important risk factor undermining the health of Blacks in the United States. Racism can take many forms, ranging from interpersonal interactions to institutional/structural conditions and practices. Existing research, however, tends to focus on individual forms of racial discrimination using self-report measures. Far less attention has been paid to whether structural racism may disadvantage the health of Blacks in the United States. The current study addresses gaps in the existing research by using novel measures of structural racism and by explicitly testing the hypothesis that structural racism is a risk factor for myocardial infarction among Blacks in the United States. State-level indicators of structural racism included four domains: (1) political participation; (2) employment and job status; (3) educational attainment; and (4) judicial treatment. State-level racial disparities across these domains were proposed to represent the systematic exclusion of Blacks from resources and mobility in society. Data on past-year myocardial infarction were obtained from the National Epidemiologic Survey on Alcohol and Related Conditions (non-Hispanic Black: N = 8245; non-Hispanic White: N = 24,507), a nationally representative survey of the U.S. civilian, non-institutionalized population aged 18 and older. Models were adjusted for individual-level confounders (age, sex, education, household income, medical insurance) as well as for state-level disparities in poverty. Results indicated that Blacks living in states with high levels of structural racism were generally more likely to report past-year myocardial infarction than Blacks living in low-structural racism states. Conversely, Whites living in high structural racism states experienced null or lower odds of myocardial infarction compared to Whites living in low-structural racism states. These results raise the provocative possibility that structural racism may not only harm the targets of stigma but also benefit those who wield the power to enact stigma and discrimination. PMID:24507909

Structural racism and myocardial infarction in the United States.

PubMed

Lukachko, Alicia; Hatzenbuehler, Mark L; Keyes, Katherine M

2014-02-01

There is a growing research literature suggesting that racism is an important risk factor undermining the health of Blacks in the United States. Racism can take many forms, ranging from interpersonal interactions to institutional/structural conditions and practices. Existing research, however, tends to focus on individual forms of racial discrimination using self-report measures. Far less attention has been paid to whether structural racism may disadvantage the health of Blacks in the United States. The current study addresses gaps in the existing research by using novel measures of structural racism and by explicitly testing the hypothesis that structural racism is a risk factor for myocardial infarction among Blacks in the United States. State-level indicators of structural racism included four domains: (1) political participation; (2) employment and job status; (3) educational attainment; and (4) judicial treatment. State-level racial disparities across these domains were proposed to represent the systematic exclusion of Blacks from resources and mobility in society. Data on past-year myocardial infarction were obtained from the National Epidemiologic Survey on Alcohol and Related Conditions (non-Hispanic Black: N = 8245; non-Hispanic White: N = 24,507), a nationally representative survey of the U.S. civilian, non-institutionalized population aged 18 and older. Models were adjusted for individual-level confounders (age, sex, education, household income, medical insurance) as well as for state-level disparities in poverty. Results indicated that Blacks living in states with high levels of structural racism were generally more likely to report past-year myocardial infarction than Blacks living in low-structural racism states. Conversely, Whites living in high structural racism states experienced null or lower odds of myocardial infarction compared to Whites living in low-structural racism states. These results raise the provocative possibility that structural racism may not only harm the targets of stigma but also benefit those who wield the power to enact stigma and discrimination. Copyright © 2013 Elsevier Ltd. All rights reserved.

Image processing of metal surface with structured light

NASA Astrophysics Data System (ADS)

Luo, Cong; Feng, Chang; Wang, Congzheng

2014-09-01

In structured light vision measurement system, the ideal image of structured light strip, in addition to black background , contains only the gray information of the position of the stripe. However, the actual image contains image noise, complex background and so on, which does not belong to the stripe, and it will cause interference to useful information. To extract the stripe center of mental surface accurately, a new processing method was presented. Through adaptive median filtering, the noise can be preliminary removed, and the noise which introduced by CCD camera and measured environment can be further removed with difference image method. To highlight fine details and enhance the blurred regions between the stripe and noise, the sharping algorithm is used which combine the best features of Laplacian operator and Sobel operator. Morphological opening operation and closing operation are used to compensate the loss of information.Experimental results show that this method is effective in the image processing, not only to restrain the information but also heighten contrast. It is beneficial for the following processing.

[FATTY ACID COMPOSITION ALTEROMONAS-LIKE BACTERIA ISOLATED FROM THE BLACK SEA WATER].

PubMed

Klochko, V V; Avdeeva, L V

2015-01-01

Alteromonas macleodii strains isolated from the Black sea water were similar in their fatty acids composition with the type strain of this species. Analysis of lipid composition of 10 A. macleodii strains isolated from the deep and surface water layers in different World ocean regions including the Black sea water has shown that the deep and surface isolates of this species formed two groups different in their fatty acids profiles. The Black sea isolates of Pseudoalteromonas haloplanktis, P. citrea, P. flavipulchra conformed to these species type strains in their fatty acids composition. On the basis of the fatty acids spectra similarity of three Pseudoalteromonas species strains with Plipolytica described in 2010 has been established. Presence of three isomers C16:1ψ7, C 16:1ψ9 and C16:1ψ6--components of hexadecenic acid in the Black sea isolates of Shewanella baltica has been shown.

Existence of initial data containing isolated black holes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dain, Sergio; Krishnan, Badri; Jaramillo, Jose Luis

2005-03-15

We present a general construction of initial data for Einstein's equations containing an arbitrary number of black holes, each of which is instantaneously in equilibrium. Each black hole is taken to be a marginally trapped surface and plays the role of the inner boundary of the Cauchy surface. The black hole is taken to be instantaneously isolated if its outgoing null rays are shear-free. Starting from the choice of a conformal metric and the freely specifiable part of the extrinsic curvature in the bulk, we give a prescription for choosing the shape of the inner boundaries and the boundary conditionsmore » that must be imposed there. We show that with these choices, the resulting nonlinear elliptic system always admits solutions.« less

The distribution of stars around the Milky Way's central black hole. I. Deep star counts

NASA Astrophysics Data System (ADS)

Gallego-Cano, E.; Schödel, R.; Dong, H.; Nogueras-Lara, F.; Gallego-Calvente, A. T.; Amaro-Seoane, P.; Baumgardt, H.

2018-01-01

Context. The existence of dynamically relaxed stellar density cusps in dense clusters around massive black holes is a long-standing prediction of stellar dynamics, but it has so far escaped unambiguous observational confirmation. Aims: In this paper we aim to revisit the problem of inferring the innermost structure of the Milky Way's nuclear star cluster via star counts, to clarify whether it displays a core or a cusp around the central black hole. Methods: We used judiciously selected adaptive optics assisted high angular resolution images obtained with the NACO instrument at the ESO VLT. Through image stacking and improved point spread function fitting we pushed the completeness limit about one magnitude deeper than in previous, comparable work. Crowding and extinction corrections were derived and applied to the surface density estimates. Known young, and therefore dynamically not relaxed stars, are excluded from the analysis. Contrary to previous work, we analyse the stellar density in well-defined magnitude ranges in order to be able to constrain stellar masses and ages. Results: We focus on giant stars, with observed magnitudes K = 12.5-16, and on stars with observed magnitudes K ≈ 18, which may have similar mean ages and masses than the former. The giants display a core-like surface density profile within a projected radius R ≤ 0.3 pc of the central black hole, in agreement with previous studies, but their 3D density distribution is not inconsistent with a shallow cusp if we take into account the extent of the entire cluster, beyond the radius of influence of the central black hole. The surface density of the fainter stars can be described well by a single power-law at R < 2 pc. The cusp-like profile of the faint stars persists even if we take into account the possible contamination of stars in this brightness range by young pre-main sequence stars. The data are inconsistent with a core-profile for the faint stars. Finally, we show that a 3D Nuker law provides a good description of the cluster structure. Conclusions: We conclude that the observed density of the faintest stars detectable with reasonable completeness at the Galactic centre, is consistent with the existence of a stellar cusp around the Milky Way's central black hole, Sagittarius A*. This cusp is well developed inside the influence radius of Sagittarius A* and can be described by a single three-dimensional power-law with an exponent γ = 1.43 ± 0.02 ± 0.1sys. This corroborates existing conclusions from Nbody simulations performed in a companion paper. An important caveat is that the faint stars analysed here may be contaminated significantly by dynamically unrelaxed stars that formed about 100 Myr ago. The apparent lack of giants at projected distances of R ≲ 0.3 pc (R ≲ 8'') of the massive black hole may indicate that some mechanism may have altered their distribution or intrinsic luminosity. We roughly estimate the number of possibly missing giants to about 100. 19 additional tables are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/609/A26

Rapid-Response Low Infrared Emission Broadband Ultrathin Plasmonic Light Absorber

PubMed Central

Tagliabue, Giulia; Eghlidi, Hadi; Poulikakos, Dimos

2014-01-01

Plasmonic nanostructures can significantly advance broadband visible-light absorption, with absorber thicknesses in the sub-wavelength regime, much thinner than conventional broadband coatings. Such absorbers have inherently very small heat capacity, hence a very rapid response time, and high light power-to-temperature sensitivity. Additionally, their surface emissivity can be spectrally tuned to suppress infrared thermal radiation. These capabilities make plasmonic absorbers promising candidates for fast light-to-heat applications, such as radiation sensors. Here we investigate the light-to-heat conversion properties of a metal-insulator-metal broadband plasmonic absorber, fabricated as a free-standing membrane. Using a fast IR camera, we show that the transient response of the absorber has a characteristic time below 13 ms, nearly one order of magnitude lower than a similar membrane coated with a commercial black spray. Concurrently, despite the small thickness, due to the large absorption capability, the achieved absorbed light power-to-temperature sensitivity is maintained at the level of a standard black spray. Finally, we show that while black spray has emissivity similar to a black body, the plasmonic absorber features a very low infra-red emissivity of almost 0.16, demonstrating its capability as selective coating for applications with operating temperatures up to 400°C, above which the nano-structure starts to deform. PMID:25418040

Enhanced structural color generation in aluminum metamaterials coated with a thin polymer layer

DOE PAGES

Cheng, Fei; Yang, Xiaodong; Rosenmann, Daniel; ...

2015-09-18

A high-resolution and angle-insensitive structural color generation platform is demonstrated based on triple-layer aluminum-silica-aluminum metamaterials supporting surface plasmon resonances tunable across the entire visible spectrum. The color performances of the fabricated aluminum metamaterials can be strongly enhanced by coating a thin transparent polymer layer on top. The results show that the presence of the polymer layer induces a better impedance matching for the plasmonic resonances to the free space so that strong light absorption can be obtained, leading to the generation of pure colors in cyan, magenta, yellow and black (CMYK) with high color saturation.

Exotic Lifshitz transitions in topological materials

NASA Astrophysics Data System (ADS)

Volovik, G. E.

2018-01-01

Topological Lifshitz transitions involve many types of topological structures in momentum and frequency-momentum spaces, such as Fermi surfaces, Dirac lines, Dirac and Weyl points, etc., each of which has its own stability-supporting topological invariant ( N_1, N_2, N_3, {\\tilde N}_3, etc.). The topology of the shape of Fermi surfaces and Dirac lines and the interconnection of objects of different dimensionalities produce a variety of Lifshitz transition classes. Lifshitz transitions have important implications for many areas of physics. To give examples, transition-related singularities can increase the superconducting transition temperature; Lifshitz transitions are the possible origin of the small masses of elementary particles in our Universe, and a black hole horizon serves as the surface of the Lifshitz transition between vacua with type-I and type-II Weyl points.

Preliminary report on the Black Thunder, Wyoming CTBT R and D experiment quicklook report: LLNL input from regional stations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harben, P.E.; Glenn, L.A.

This report presents a preliminary summary of the data recorded at three regional seismic stations from surface blasting at the Black Thunder Coal Mine in northeast Wyoming. The regional stations are part of a larger effort that includes many more seismic stations in the immediate vicinity of the mine. The overall purpose of this effort is to characterize the source function and propagation characteristics of large typical surface mine blasts. A detailed study of source and propagation features of conventional surface blasts is a prerequisite to attempts at discriminating this type of blasting activity from other sources of seismic events.more » The Black Thunder Seismic experiment is a joint verification effort to determine seismic source and path effects that result from very large, but routine ripple-fired surface mining blasts. Studies of the data collected will be for the purpose of understanding how the near-field and regional seismic waveforms from these surface mining blasts are similar to, and different from, point shot explosions and explosions at greater depth. The Black Hills Station is a Designated Seismic Station that was constructed for temporary occupancy by the Former Soviet Union seismic verification scientists in accordance with the Threshold Test Ban Treaty protocol.« less

Reaching Black Men. Commentary

ERIC Educational Resources Information Center

Gassman, Marybeth

2010-01-01

Journalist Elizabeth Redden brings to the surface several salient issues in her article entitled, "Reaching Black Men." First, she illuminates that fact that access is not enough when it comes to educating African American men. Second, she points to the importance of having campus-wide initiatives to support the success of Black men. And…

Static black hole and vacuum energy: thin shell and incompressible fluid

NASA Astrophysics Data System (ADS)

Ho, Pei-Ming; Matsuo, Yoshinori

2018-03-01

With the back reaction of the vacuum energy-momentum tensor consistently taken into account, we study static spherically symmetric black-hole-like solutions to the semi-classical Einstein equation. The vacuum energy is assumed to be given by that of 2-dimensional massless scalar fields, as a widely used model in the literature for black holes. The solutions have no horizon. Instead, there is a local minimum in the radius. We consider thin shells as well as incompressible fluid as the matter content of the black-hole-like geometry. The geometry has several interesting features due to the back reaction of vacuum energy. In particular, Buchdahl's inequality can be violated without divergence in pressure, even if the surface is below the Schwarzschild radius. At the same time, the surface of the star can not be far below the Schwarzschild radius for a density not much higher than the Planck scale, and the proper distance from its surface to the origin can be very short even for very large Schwarzschild radius. The results also imply that, contrary to the folklore, in principle the Boulware vacuum can be physical for black holes.

Simultaneous measurement of the surface temperature and the release of atomic sodium from a burning black liquor droplet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saw, Woei L.; Nathan, Graham J.; School of Mechanical Engineering, The University of Adelaide

2010-04-15

Simultaneous measurement of the concentration of released atomic sodium, swelling, surface and internal temperature of a burning black liquor droplet under a fuel lean and rich condition has been demonstrated. Two-dimensional two-colour optical pyrometry was employed to determine the distribution of surface temperature and swelling of a burning black liquor droplet while planar laser-induced fluorescence (PLIF) was used to assess the temporal release of atomic sodium. The key findings of these studies are: (i) the concentration of atomic sodium released during the drying and devolatilisation stages was found to be correlated with the external surface area; and (ii) the insignificantmore » presence of atomic sodium during the char consumption stage shows that sodium release is suppressed by the lower temperature and by the high CO{sub 2} content in and around the particle. (author)« less

Alteration of the mode of antibacterial action of a defensin by the amino-terminal loop substitution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, Bin; Zhu, Shunyi, E-mail: Zhusy@ioz.ac.cn

Highlights: Black-Right-Pointing-Pointer Al-M is an engineered fungal defensin with the n-loop of an insect defensin. Black-Right-Pointing-Pointer Al-M adopts a native defensin-like structure with high antibacterial potency. Black-Right-Pointing-Pointer Al-M kills bacteria through a membrane disruptive mechanism. Black-Right-Pointing-Pointer This work sheds light on the functional evolution of CS{alpha}{beta}-type defensins. -- Abstract: Ancient invertebrate-type and classical insect-type defensins (AITDs and CITDs) are two groups of evolutionarily related antimicrobial peptides (AMPs) that adopt a conserved cysteine-stabilized {alpha}-helical and {beta}-sheet (CS{alpha}{beta}) fold with a different amino-terminal loop (n-loop) size and diverse modes of antibacterial action. Although they both are identified as inhibitors of cell wallmore » biosynthesis, only CITDs evolved membrane disruptive ability by peptide oligomerization to form pores. To understand how this occurred, we modified micasin, a fungus-derived AITDs with a non-membrane disruptive mechanism, by substituting its n-loop with that of an insect-derived CITDs. After air oxidization, the synthetic hybrid defensin (termed Al-M) was structurally identified by circular dichroism (CD) and functionally evaluated by antibacterial and membrane permeability assays and electronic microscopic observation. Results showed that Al-M folded into a native-like defensin structure, as determined by its CD spectrum that is similar to that of micasin. Al-M was highly efficacious against the Gram-positive bacterium Bacillus megaterium with a lethal concentration of 1.76 {mu}M. As expected, in contrast to micasin, Al-M killed the bacteria through a membrane disruptive mechanism of action. The alteration in modes of action supports a key role of the n-loop extension in assembling functional surface of CITDs for membrane disruption. Our work provides mechanical evidence for evolutionary relationship between AITDs and CITDs.« less

Characterization of nephelium mutabile blume-like structure of carbon nanotubes prepared from palm oil by CVD method

NASA Astrophysics Data System (ADS)

Maryam, M.; Shamsudin, M. S.; Rusop, M.

2017-09-01

A new structure of carbon nanotube was produced from the Single furnace Aerosol-assisted Catalytic CVD (SFAACVD) method using Palm Oil (PO) as the precursor and Ferrocene (Fe) as the catalyst. A nephelium mutabile blume (rambutan)-like structure of CNTs was found from the black substance collected from the Alumina boat substrate placed inside the furnace. Temperature of furnace which was heated at 600 °C - 800 °C plays an important role in determining the formation of structure. The formation rambutan-like structure of CNTs was optimized at 700 °C and the samples collected were characterized by Field Emission Scanning Electron Microscope (FE-SEM) to obtain the surface morphologies. Raman Spectroscopy (RS) and Thermogravimetric Analysis (TGA) were then used to further study the Raman Spectra and purity of samples.

Dilatonic BTZ black holes with power-law field

NASA Astrophysics Data System (ADS)

Hendi, S. H.; Eslam Panah, B.; Panahiyan, S.; Sheykhi, A.

2017-04-01

Motivated by low energy effective action of string theory and numerous applications of BTZ black holes, we will consider minimal coupling between dilaton and nonlinear electromagnetic fields in three dimensions. The main goal is studying thermodynamical structure of black holes in this set up. Temperature and heat capacity of these black holes are investigated and a picture regarding their phase transitions is given. In addition, the role and importance of studying the mass of black holes is highlighted. We will see how different parameters modify thermodynamical quantities, hence thermodynamical structure of these black holes. In addition, geometrical thermodynamics is used to investigate thermodynamical properties of these black holes. In this regard, the successful method is presented and the nature of interaction around bound and phase transition points is studied.

Decisions of Black Parents About Infant Bedding and Sleep Surfaces: A Qualitative Study

PubMed Central

Ajao, Taiwo I.; Oden, Rosalind P.; Joyner, Brandi L.

2011-01-01

OBJECTIVE: The goal of this qualitative study was to examine factors influencing decisions by black parents regarding use of soft bedding and sleep surfaces for their infants. METHODS: We conducted focus groups and individual interviews with black mothers of lower and higher socioeconomic status (SES). Mothers were asked about many infant care practices, including sleep surface and bedding. RESULTS: Eighty-three mothers were interviewed, 73 (47 lower and 26 higher SES) in focus groups and 10 (7 lower and 3 higher SES) in individual interviews. The primary reason for using soft surfaces was infant comfort. Parents perceived that infants were uncomfortable if the surface was not soft. Many parents also interpreted “firm sleep surface” to mean taut; they were comfortable with and believed that they were following recommendations for a firm sleep surface when they placed pillows/blankets on the mattress as long as a sheet was pulled tautly over the pillows/blankets. The primary reasons for using soft bedding (including bumper pads) were comfort, safety, and aesthetics. In addition to using bedding to soften sleep surfaces, bedding was used to prevent infant rollover and falls, particularly for infants sleeping on a bed or sofa. Some parents used soft bedding to create an attractive space for the infant. CONCLUSIONS: Many black parents believe that soft bedding will keep their infant safe and comfortable. There is much misunderstanding about the meaning of a “firm” sleep surface. Additional educational messages apparently are needed to change parental perceptions and practices. PMID:21859921

Dependence of the optical conductivity on the uniaxial and biaxial strains in black phosphorene

NASA Astrophysics Data System (ADS)

Yang, C. H.; Zhang, J. Y.; Wang, G. X.; Zhang, C.

2018-06-01

By using the Kubo formula, the optical conductivity of strained black phosphorene was studied. The anisotropic band dispersion gives rise to an orientation dependent optical conductivity. The energy gap can be tuned by the uniaxial and biaxial strains which can be observed from the interband optical conductivity polarized along the armchair (x ) direction. The preferential conducting direction is along the x direction. The dependence of the intraband optical conductivity along the zigzag (y ) direction on the Fermi energy and strain exhibits increasing or decreasing monotonously. However, along the x direction this dependence is complicated which originates from the carriers' inverse-direction movements obtained by two types of the nearest phosphorus atom interactions. The modification of the biaxial strain on the energy structure and optical-absorption property is more effective. The imaginary part of the total optical conductivity (Im σ ) can be negative around the threshold of the interband optical transition by modifying the chemical potential. Away from this frequency region, Im σ exhibits positive value. It can be used in the application of the surface plasmon propagations in multilayer dielectric structures.

Optical properties of ion beam textured metals. [using copper, silicon, aluminum, titanium and stainless steels

NASA Technical Reports Server (NTRS)

Hudson, W. R.; Weigand, A. J.; Mirtich, M. J.

1977-01-01

Copper, silicon, aluminum, titanium and 316 stainless steel were textured by 1000 eV xenon ions from an 8 cm diameter electron bombardment ion source. Simultaneously sputter-deposited tantalum was used to facilitate the development of the surface microstructure. Scanning electron microscopy of the ion textured surfaces revealed two types of microstructure. Copper, silicon, and aluminum developed a cone structure with an average peak-to-peak distance ranging from 1 micron for silicon to 6 microns for aluminum. Titanium and 316 stainless steel developed a serpentine ridge structure. The average peak-to-peak distance for both of these materials was 0.5 micron. Spectral reflectance was measured using an integrating sphere and a holraum reflectometer. Total reflectance for air mass 0 and 2, solar absorptance and total emittance normalized for a 425 K black body were calculated from the reflectance measurements.

Advantages of using microbial technology over traditional chemical technology in removal of black crusts from stone surfaces of historical monuments.

PubMed

Cappitelli, Francesca; Toniolo, Lucia; Sansonetti, Antonio; Gulotta, Davide; Ranalli, Giancarlo; Zanardini, Elisabetta; Sorlini, Claudia

2007-09-01

This study compares two cleaning methods, one involving an ammonium carbonate-EDTA mixture and the other involving the sulfate-reducing bacterium Desulfovibrio vulgaris subsp. vulgaris ATCC 29579, for the removal of black crust (containing gypsum) on marble of the Milan Cathedral (Italy). In contrast to the chemical cleaning method, the biological procedure resulted in more homogeneous removal of the surface deposits and preserved the patina noble under the black crust. Whereas both of the treatments converted gypsum to calcite, allowing consolidation, the chemical treatment also formed undesirable sodium sulfate.

Advantages of Using Microbial Technology over Traditional Chemical Technology in Removal of Black Crusts from Stone Surfaces of Historical Monuments▿

PubMed Central

Cappitelli, Francesca; Toniolo, Lucia; Sansonetti, Antonio; Gulotta, Davide; Ranalli, Giancarlo; Zanardini, Elisabetta; Sorlini, Claudia

2007-01-01

This study compares two cleaning methods, one involving an ammonium carbonate-EDTA mixture and the other involving the sulfate-reducing bacterium Desulfovibrio vulgaris subsp. vulgaris ATCC 29579, for the removal of black crust (containing gypsum) on marble of the Milan Cathedral (Italy). In contrast to the chemical cleaning method, the biological procedure resulted in more homogeneous removal of the surface deposits and preserved the patina noble under the black crust. Whereas both of the treatments converted gypsum to calcite, allowing consolidation, the chemical treatment also formed undesirable sodium sulfate. PMID:17601804

Spacetime topology change and black hole information

NASA Astrophysics Data System (ADS)

Hsu, Stephen D. H.

2007-01-01

Topology change-the creation of a disconnected baby universe-due to black hole collapse may resolve the information loss paradox. Evolution from an early time Cauchy surface to a final surface which includes a slice of the disconnected region can be unitary and consistent with conventional quantum mechanics. We discuss the issue of cluster decomposition, showing that any violations thereof are likely to be unobservably small. Topology change is similar to the black hole remnant scenario and only requires assumptions about the behavior of quantum gravity in Planckian regimes. It does not require non-locality or any modification of low-energy physics.

Dynamics of Dwarf Galaxies Disfavor Stellar-Mass Black Holes as Dark Matter.

PubMed

Koushiappas, Savvas M; Loeb, Abraham

2017-07-28

We study the effects of black hole dark matter on the dynamical evolution of stars in dwarf galaxies. We find that mass segregation leads to a depletion of stars in the center of dwarf galaxies and the appearance of a ring in the projected stellar surface density profile. Using Segue 1 as an example we show that current observations of the projected surface stellar density rule out at the 99.9% confidence level the possibility that more than 6% of the dark matter is composed of black holes with a mass of few tens of solar masses.

Topographic controls on black carbon accumulation in Alaskan black spruce forest soils: implications for organic matter dynamics

Treesearch

E.S. Kane; W.C. Hockaday; M.R. Turetsky; C.A. Masiello; D.W. Valentine; B.P. Finney; J.A. Badlock

2010-01-01

There is still much uncertainty as to how wildfire affects the accumulation of burn residues (such as black carbon [BC]) in the soil, and the corresponding changes in soil organic carbon (SOC) composition in boreal forests. We investigated SOC and BC composition in black spruce forests on different landscape positions in Alaska, USA. Mean BC stocks in surface mineral...

16 CFR 1632.31 - Mattresses/mattress pads-labeling, recordkeeping, guaranties and “one of a kind” exemption.

Code of Federal Regulations, 2012 CFR

2012-01-01

... the Standard. (3) Photograph (color or black and white) of the bare surface of each mattress or... (color or black and white) of the bare surface of each mattress or mattress pad tested in accordance with... shall manufacture for sale, import, distribute, or otherwise market or handle any mattress or mattress...

16 CFR 1632.31 - Mattresses/mattress pads-labeling, recordkeeping, guaranties and “one of a kind” exemption.

Code of Federal Regulations, 2011 CFR

2011-01-01

... the Standard. (3) Photograph (color or black and white) of the bare surface of each mattress or... (color or black and white) of the bare surface of each mattress or mattress pad tested in accordance with... shall manufacture for sale, import, distribute, or otherwise market or handle any mattress or mattress...

16 CFR 1632.31 - Mattresses/mattress pads-labeling, recordkeeping, guaranties and “one of a kind” exemption.

Code of Federal Regulations, 2014 CFR

2014-01-01

... the Standard. (3) Photograph (color or black and white) of the bare surface of each mattress or... (color or black and white) of the bare surface of each mattress or mattress pad tested in accordance with... shall manufacture for sale, import, distribute, or otherwise market or handle any mattress or mattress...

16 CFR § 1632.31 - Mattresses/mattress pads-labeling, recordkeeping, guaranties and “one of a kind” exemption.

Code of Federal Regulations, 2013 CFR

2013-01-01

... carried out in accordance with the Standard. (3) Photograph (color or black and white) of the bare surface...) Photograph (color or black and white) of the bare surface of each mattress or mattress pad tested in... Flammable Fabrics Act shall manufacture for sale, import, distribute, or otherwise market or handle any...

16 CFR 1632.31 - Mattresses/mattress pads-labeling, recordkeeping, guaranties and “one of a kind” exemption.

Code of Federal Regulations, 2010 CFR

2010-01-01

... the Standard. (3) Photograph (color or black and white) of the bare surface of each mattress or... (color or black and white) of the bare surface of each mattress or mattress pad tested in accordance with... shall manufacture for sale, import, distribute, or otherwise market or handle any mattress or mattress...

Au@Pd core-shell nanobricks with concave structures and their catalysis of ethanol oxidation.

PubMed

Wang, Wenjin; Zhang, Jie; Yang, Shengchun; Ding, Bingjun; Song, Xiaoping

2013-10-01

Au@Pd core-shell nanobricks (CNBs) with concave surfaces and Pd shells with a thickness of approximately 5 nm were synthesized by co-reduction of HAuCl4 and H2 PdCl4 in the presence of Au seeds and Ag ions. These as-synthesized concave CNBs exhibit significantly enhanced catalytic activity for the electrooxidation of ethanol in alkaline media compared to the commercially-used Pd black. The improved performance of the Au@Pd CNBs can be attributed to the exposed stepped surfaces, high-index facets, and the synergistic effects of the core and shell metals. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Accretion geometry in the persistent Be/X-ray binary RXJ0440.9+4431

NASA Astrophysics Data System (ADS)

Ferrigno, C.; Farinelli, R.; Bozzo, E.; Pottschmidt, K.; Klochkov, D.; Kretschmar, P.

2014-01-01

The persistent Be/X-ray binary RXJ0440.9+4431 flared in 2010 and 2011 and has been followed by various X-ray facilities (Swift, RXTE, XMM-Newton, and INTEGRAL). We studied the source timing and spectral properties as a function of its X-ray luminosity to investigate the transition from normal to flaring activity. The source spectrum can always be described by a bulk-motion Comptonization model of black body seed photons attenuated by a moderate photoelectric absorption. At the highest luminosity, we measured a curvature of the spectrum, which we attribute to a significant contribution of the radiation pressure in the accretion process. This allows us to estimate that the transition from a bulk-motion-dominated flow to a radiatively dominated one happens at a luminosity of ~ 2 × 1036 erg s-1. The luminosity dependency of the size of the black body emission region is found to be rBB ∝ LX0.39±0.02. This suggests that either matter accreting onto the neutron star hosted in RXJ0440.9+4431 penetrates through closed magnetic field lines at the border of the compact object magnetosphere or that the size of the black-body emitting hotspot is larger than the footprint of the accretion column. This phenomenon can be due to illumination of the surface by a growing column or by a a structure of the neutron star magnetic field more complicated than a simple dipole at least close to the surface.

Pt-black catalysts sintered at different temperatures: Surface analysis and activity in reactions of n-hexane

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paal, Z.; Xu, X.L.; Paal-Lukacs, J.

Pt-black catalysts sintered at 473 and 633 K ({open_quotes}Pt-473{close_quotes} and {open_quotes}Pt-633{close_quotes}), respectively, have been characterized by X-ray diffraction and analyzed by XPS, UPS, and AES after carrying out n-hexane reactions. The analysis has been repeated after O{sub 2}-H{sub 2} regeneration in the preparation chamber of the UHV apparatus. The surface of the blacks contains some carbon and oxygen impurities even after regeneration. Both Pt-473 and Pt-633 show high Pt 4f line intensity. Decomposition of the C 1s line reveals a higher amount of oxidized carbon polymers on Pt-633. This sample is free from lattice strain. The likely higher abundance ofmore » exposed hexagonal symmetry faces, namely the (111) plane and analogous stepped and kinked structures, may be one of the reasons why fragmentation and aromatization are favored on Pt-633, as opposed to the higher selectivity of isomerization and C{sub 5}-cyclization on Pt-473. The higher amount of oxidized carbonaceous polymer overlayer (serving as {open_quotes}hydrogen catcher{close_quotes}) on Pt-633 as well as the less-retained hydrogen by its crystallites without lattice strain may also contribute to the different selectivity and hydrogen pressure response of the n-hexane reaction over the two samples. Product ratios are suggested as an additional diagnostic tool for characterizing the hydrogen availability on the catalysts. 59 refs., 9 figs., 5 tabs.« less

Age structure and growth of California black oak (Quercus kelloggii) in the central Sierra Nevada, California

Treesearch

Barrett A. Garrison; Christopher D. otahal; Matthew L. Triggs

2002-01-01

Age structure and growth of California black oak (Quercus kelloggii) was determined from tagged trees at four 26.1-acre study stands in Placer County, California. Stands were dominated by large diameter (>20 inch dbh) California black oak and ponderosa pine (Pinus ponderosa). Randomly selected trees were tagged in June-August...

The Causes of the Worsening Employment Situation of Black Youth.

ERIC Educational Resources Information Center

Osterman, Paul

A study was conducted to examine why black youth unemployment has increased and participation rates decreased. The study was conducted in three parts. The first employs 1960 and 1970 census data to examine the impact of local labor market structure and changes in the structure upon the employment growth of black and white youth. The second part…

Poverty among Young Children in Black Immigrant, US-Born Black, and Non-Black Immigrant Families: The Role of Familial Contexts. Discussion Paper Series. DP 2010-02

ERIC Educational Resources Information Center

Thomas, Kevin J. A.

2010-01-01

This study examines how familial contexts affect poverty disparities between the children of immigrant and US-born Blacks, and among Black and non-Black children of immigrants. Despite lower gross child poverty rates in immigrant than US-born Black families, accounting for differences in family structure reveals that child poverty risks among…

Detection of DNA hybridization using graphene-coated black phosphorus surface plasmon resonance sensor

NASA Astrophysics Data System (ADS)

Pal, Sarika; Verma, Alka; Raikwar, S.; Prajapati, Y. K.; Saini, J. P.

2018-05-01

In this paper, graphene-coated black phosphorus at the metal surface for the detection of DNA hybridization event is numerically demonstrated. The strategy consists of placing the sensing medium on top of black phosphorus-graphene-coated SPR which interfaces with phosphate-buffered saline solution carrying single-stranded DNA. Upon hybridization with its complementary DNA, desorption of the nanostructures takes place and thus enables the sensitive detection of the DNA hybridization event. The proposed sensor exhibits a sensitivity (125 ο/RIU), detection accuracy (0.95) and quality factor (13.62 RIU-1) for complementary DNA. In comparison with other reported papers, our suggested sensor provides much better performance. Thus, this label-free DNA detection platform should spur off new interest towards the use of black phosphorus-graphene-coated SPR interfaces.

Biogeochemical Processes That Produce Dissolved Organic Matter From Wheat Straw

USGS Publications Warehouse

Wershaw, Robert L.; Rutherford, David W.; Leenheer, Jerry A.; Kennedy, Kay R.; Cox, Larry G.; Koci, Donald R.

2003-01-01

The chemical reactions that lead to the formation of dissolved organic matter (DOM) in natural waters are poorly understood. Studies on the formation of DOM generally are complicated because almost all DOM isolates have been derived from mixtures of plant species composed of a wide variety of different types of precursor compounds for DOM formation. This report describes a study of DOM derived mainly from bales of wheat straw that had been left in a field for several years. During this period of time, black water from the decomposing wheat straw accumulated in pools in the field. The nuclear magnetic resonance and infrared spectra of the black water DOM indicate that it is composed almost entirely of lignin and carbohydrate polymeric units. Analysis by high-performance size-exclusion chromatography with multi-angle laser-light scattering detection indicates that the number average molecular weight of the DOM is 124,000 daltons. The results presented in this report indicate that the black water DOM is composed of hemicellulose chains cross-linked to lignin oligomers. These types of structures have been shown to exist in the hemicellulose matrix of plant cell walls. The cross-linked lignin-hemicellulose complexes apparently were released from partially degraded wheat-straw cell walls with little alteration. In solution in the black water, these lignin-hemicellulose polymers fold into compact globular particles in which the nonpolar parts of the polymer form the interiors of the particles and the polar groups are on the exterior surfaces of the particles. The tightly folded, compact conformation of these particles probably renders them relatively resistant to microbial degradation. This should be especially the case for the aromatic lignin structures that will be buried in the interiors of the particles.

Resource Letter BH-1: Black Holes.

ERIC Educational Resources Information Center

Detweiler, Steven

1981-01-01

Lists resources on black holes, including: (1) articles of historical interest; (2) books and journal articles on elementary expositions; (3) elementary and advanced textbooks; and (4) research articles on analytic structure of black holes, black hole dynamics, and astrophysical processes. (SK)

Locating Black Mixed-Raced Males in the Black Supplementary School Movement

ERIC Educational Resources Information Center

Joseph-Salisbury, Remi; Andrews, Kehinde

2017-01-01

This article draws upon data from semi-structured interviews conducted with black mixed-race males in the UK and the US, to argue that a revival of the black supplementary school movement could play an important role in the education of black mixed-race males. The article contends that a strong identification with blackness, and a concomitant…

Separate and unequal: Structural racism and infant mortality in the US.

PubMed

Wallace, Maeve; Crear-Perry, Joia; Richardson, Lisa; Tarver, Meshawn; Theall, Katherine

2017-05-01

We examined associations between state-level measures of structural racism and infant mortality among black and white populations across the US. Overall and race-specific infant mortality rates in each state were calculated from national linked birth and infant death records from 2010 to 2013. Structural racism in each state was characterized by racial inequity (ratio of black to white population estimates) in educational attainment, median household income, employment, imprisonment, and juvenile custody. Poisson regression with robust standard errors estimated infant mortality rate ratios (RR) and 95% confidence intervals (CI) associated with an IQR increase in indicators of structural racism overall and separately within black and white populations. Across all states, increasing racial inequity in unemployment was associated with a 5% increase in black infant mortality (RR=1.05, 95% CI=1.01, 1.10). Decreasing racial inequity in education was associated with an almost 10% reduction in the black infant mortality rate (RR=0.92, 95% CI=0.85, 0.99). None of the structural racism measures were significantly associated with infant mortality among whites. Structural racism may contribute to the persisting racial inequity in infant mortality. Copyright © 2017 Elsevier Ltd. All rights reserved.

Two-dimensional adiabatic flows on to a black hole - I. Fluid accretion

NASA Astrophysics Data System (ADS)

Blandford, Roger D.; Begelman, Mitchell C.

2004-03-01

When gas accretes on to a black hole, at a rate either much less than or much greater than the Eddington rate, it is likely to do so in an `adiabatic' or radiatively inefficient manner. Under fluid (as opposed to magnetohydrodynamic) conditions, the disc should become convective and evolve toward a state of marginal instability. We model the resulting disc structure as `gyrentropic', with convection proceeding along common surfaces of constant angular momentum, Bernouilli function and entropy, called `gyrentropes'. We present a family of two-dimensional, self-similar models that describes the time-averaged disc structure. We then suppose that there is a self-similar, Newtonian torque, which dominates the angular momentum transport and that the Prandtl number is large so that convection dominates the heat transport. The torque drives inflow and meridional circulation and the resulting flow is computed. Convective transport will become ineffectual near the disc surface. It is conjectured that this will lead to a large increase of entropy across a `thermal front', which we identify as the effective disc surface and the base of an outflow. The conservation of mass, momentum and energy across this thermal front permits a matching of the disc models to self-similar outflow solutions. We then demonstrate that self-similar disc solutions can be matched smoothly on to relativistic flows at small radius and thin discs at large radius. This model of adiabatic accretion is contrasted with some alternative models that have been discussed recently. The disc models developed in this paper should be useful for interpreting numerical, fluid dynamical simulations. Related principles to those described here may govern the behaviour of astrophysically relevant, magnetohydrodynamic disc models.

Altitude of the top of the Inyan Kara Group in the Black Hills area, South Dakota

USGS Publications Warehouse

Carter, Janet M.; Redden, Jack A.

2000-01-01

This map is a product of the Black Hills Hydrology Study, which was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota (Driscoll, 1992). This long-term study is a cooperative effort between the U.S. Geological Survey (USGS), the South Dakota Department of Environment and Natural Resources, and the West Dakota Water Development District, which represents various local and county cooperators. This map is part of a series of 1:100,000-scale maps for the study. The maps include a hydrogeologic map, structure-contour maps (altitudes of the tops of formations) for five formations that contain major aquifers in the study area, and potentiometric maps for these five major aquifers (the Inyan Kara, Minnekahta, Minnelusa, Madison, and Deadwood aquifers).The study area consists of the topographically defined Black Hills and adjacent areas located in western South Dakota. The Black Hills area is an elongated, dome-shaped feature, about 125 miles long and 60 miles wide, which was uplifted during the Laramide orogeny (Feldman and Heimlich, 1980). The oldest geologic units in the study area are Precambrian metamorphic and igneous rocks, which are exposed in the central core of the Black Hills. Surrounding the Precambrian core is a layered series of sedimentary rocks including limestones, sandstones, and shales that are exposed in roughly concentric rings around the uplifted flanks of the Black Hills. The bedrock sedimentary units typically dip away from the uplifted Black Hills at angles that approach or exceed 10 degrees near the outcrops, and decrease with distance from the uplift. Many of the sedimentary units contain aquifers, both within and beyond the study area. Recharge to these aquifers occurs from infiltration of precipitation upon the outcrops and, in some cases, from infiltration of streamflow (Hortness and Driscoll, 1998). Artesian conditions generally exist within these aquifers where an upper confining layer is present. Flowing wells and artesian springs that originate from confined aquifers are common around the periphery of the Black Hills.The purpose of this map is to show the altitude of the top (structure contours) of the Inyan Kara Group within the area of the Black Hills Hydrology Study. The depth to the top of the Inyan Kara Group can be estimated at a specific site by subtracting the altitude of the top of the formation from the topographic elevation. However, caution is urged in determining the depth to the top of the formation in areas on the map where the contours are approximately located.

Materials and structures

NASA Astrophysics Data System (ADS)

Saito, Theodore T.; Langenbeck, Sharon L.; Al-Jamily, Ghanim; Arnold, Joe; Barbee, Troy; Coulter, Dan; Dolgin, Ben; Fichter, Buck; George, Patricia; Gorenstein, Paul

1992-08-01

Materials and structures technology covers a wide range of technical areas. Some of the most pertinent issues for the Astrotech 21 missions include dimensionally stable structural materials, advanced composites, dielectric coatings, optical metallic coatings for low scattered light applications, low scattered light surfaces, deployable and inflatable structures (including optical), support structures in 0-g and 1-g environments, cryogenic optics, optical blacks, contamination hardened surfaces, radiation hardened glasses and crystals, mono-metallic telescopes and instruments, and materials characterization. Some specific examples include low coefficients of thermal expansion (CTE) structures (0.01 ppm/K), lightweight thermally stable mirror materials, thermally stable optical assemblies, high reliability/accuracy (1 micron) deployable structures, and characterization of nanometer level behavior of materials/structures for interferometry concepts. Large filled-aperture concepts will require materials with CTE's of 10(exp 9) at 80 K, anti-contamination coatings, deployable and erectable structures, composite materials with CTE's less than 0.01 ppm/K and thermal hysteresis, 0.001 ppm/K. Gravitational detection systems such as LAGOS will require rigid/deployable structures, dimensionally stable components, lightweight materials with low conductivity, and high stability optics. The Materials and Structures panel addressed these issues and the relevance of the Astrotech 21 mission requirements by dividing materials and structures technology into five categories. These categories, the necessary development, and applicable mission/program development phasing are summarized. For each of these areas, technology assessments were made and development plans were defined.

Chemical analysis of black crust on the Angkor sandstone at the Bayon temple, Cambodia

NASA Astrophysics Data System (ADS)

Song, Wonsuh; Oguchi, Chiaki; Waragai, Tetsuya

2014-05-01

The Angkor complex is the one of the greatest cultural heritages in the world. It is constructed in the early 12th century, designated as a world cultural heritage by UNESCO in 1992. The temples at the Angkor complex are mainly made of sandstone and laterite. However, due to the tropical climate, plants, lichens and various microorganisms are growing well on the rock surface. Black crusts are also easily found on the stone surface. The 21st technical session of the International Coordinating Committee for the Safeguarding and Development of the Historic Site of Angkor (ICC-Angkor) held in 2012 recommended that to preserve both the biofilms and the forest cover and to prohibit the biocides (chlorine-based) and organic biocides. However, there are many reports that lichens and microorganisms accelerate rock weathering. It is important to clarify that how the biofilm on the Angkor temples affect Angkor sandstones. We sampled Angkor sandstone covered by black crust at the Bayon temple, Angkor complex, and observed the section and the surface of the rock sample by using SEM. Surfaces of the samples are not polished in order to observe the original condition. The samples are coated with gold for 180 seconds. The depth of the black crust is up to 1 mm. Many filamentous materials were found on the black crust. Average energy-dispersive X-ray spectroscopy data of the five areas of ca. 20 μm ×15 μm in the black crusts shows that over 80 % of the filamentous materials are compounds of carbon. It seems that these materials are hyphae. The shape of the hypha is like a thread and its size is few μm in diameter and up to several centimeters in length. Black crusts are consisted of elements and compounds of carbon, Na, Mg, Al, Si, Cl, K, Ca, and Fe. Further research has to be done to find out the better and proper way of conservation for the Angkor complex.

The Black Community: Diversity and Unity.

ERIC Educational Resources Information Center

Blackwell, James E.

The black community is defined in this book as a diversified set of interrelated structures and aggregates of people who are held together by the forces of racism. The need for theoretical perspectives for understanding black-white relations and for analyzing the nature of the black community is explained. The black family, patterns of family…

Black Ethnicity and the Persistence of Ethnogenesis.

ERIC Educational Resources Information Center

Taylor, Ronald L.

1979-01-01

Reviews past research which demonstrates that neither Black corporate pride nor Black ethnicity is a recent phenomenon in American life. Rather, Black ethnogenesis was inspired by the same structural conditions as the development of ethnic identity among White ethnic populations. (Author/KC)

The Structural Relationship between Out-of-School Time Enrichment and Black Student Participation in Advanced Science

ERIC Educational Resources Information Center

Young, Jamaal; Young, Jemimah

2018-01-01

The researchers tested a model of the structural relationship between Black student engagement in out-of-school time (OST) science enrichment and participation in advanced science courses in high school. The participants in the sample were Black students (N = 3,173) who participated in the High School Longitudinal Study of 2009/2012. The student…

Discovery of black dye crystal structure polymorphs: Implications for dye conformational variation in dye-sensitized solar cells

DOE PAGES

Cole, Jacqueline M.; Low, Kian Sing; Gong, Yun

2015-11-24

Here, we present the discovery of a new crystal structure polymorph (1) and pseudopolymorph (2) of the Black Dye, one of the world’s leading dyes for dye-sensitized solar cells, DSSCs (10.4% device performance efficiency). This reveals that Black Dye molecules can adopt multiple low-energy conformers. This is significant since it challenges existing models of the Black Dye···TiO 2 adsorption process that renders a DSSC working electrode; these have assumed a single molecular conformation that refers to the previously reported Black Dye crystal structure (3). The marked structural differences observed between 1, 2, and 3 make the need for modeling multiplemore » conformations more acute. Additionally, the ordered form of the Black Dye (1) provides a more appropriate depiction of its anionic structure, especially regarding its anchoring group and NCS bonding descriptions. The tendency toward NCS ligand isomerism, evidenced via the disordered form 2, has consequences for electron injection and electron recombination in Black Dye embedded DSSC devices. Dyes 2 and 3 differ primarily by the absence or presence of a solvent of crystallization, respectively; solvent environment effects on the dye are thereby elucidated. This discovery of multiple Black Dye conformers from diffraction, with atomic-level definition, complements recently reported nanoscopic evidence for multiple dye conformations existing at a dye···TiO 2 interface, for a chemically similar DSSC dye; those results emanated from imaging and spectroscopy, but were unresolved at the submolecular level. Taken together, these findings lead to the general notion that multiple dye conformations should be explicitly considered when modeling dye···TiO 2 interfaces in DSSCs, at least for ruthenium-based dye complexes.« less

Out on a limb: Thermal microenvironments in the tropical forest canopy and their relevance to ants.

PubMed

Stark, Alyssa Y; Adams, Benjamin J; Fredley, Jennifer L; Yanoviak, Stephen P

2017-10-01

Small, cursorial ectotherms like ants often are immersed in the superheated air layers that develop millimeters above exposed, insolated surfaces (i.e., the thermal boundary layer). We quantified the thermal microenvironments around tree branches in the tropical rainforest canopy, and explored the effects of substrate color on the internal body temperature and species composition of arboreal ants. Branch temperatures during the day (09:00-16:00) were hottest (often > 50°C) and most variable on the upper surface, while the lowest and least variable temperatures occurred on the underside. Temperatures on black substrates declined with increasing distance above the surface in both the field and the laboratory. By contrast, a micro-scale temperature inversion occurred above white substrates. Wind events (ca. 2ms -1 ) eliminated these patterns. Internal temperatures of bodies of Cephalotes atratus workers experimentally heated in the laboratory were 6°C warmer on white vs. black substrates, and 6°C cooler than ambient in windy conditions. The composition of ant species foraging at baits differed between black-painted and unpainted tree branches, with a tendency for smaller ants to avoid the significantly hotter black surfaces. Collectively, these outcomes show that ants traversing canopy branches experience very heterogeneous thermal microenvironments that are partly influenced in predictable ways by branch surface coloration and breezy conditions. Copyright © 2017 Elsevier Ltd. All rights reserved.

Band Structure of the IV-VI Black Phosphorus Analog and Thermoelectric SnSe

NASA Astrophysics Data System (ADS)

Pletikosić, I.; von Rohr, F.; Pervan, P.; Das, P. K.; Vobornik, I.; Cava, R. J.; Valla, T.

2018-04-01

The success of black phosphorus in fast electronic and photonic devices is hindered by its rapid degradation in the presence of oxygen. Orthorhombic tin selenide is a representative of group IV-VI binary compounds that are robust and isoelectronic and share the same structure with black phosphorus. We measure the band structure of SnSe and find highly anisotropic valence bands that form several valleys having fast dispersion within the layers and negligible dispersion across. This is exactly the band structure desired for efficient thermoelectric generation where SnSe has shown great promise.

Band Structure of the IV-VI Black Phosphorus Analog and Thermoelectric SnSe

DOE PAGES

Pletikosic, Ivo; von Rohr, F.; Pervan, P.; ...

2018-04-10

Here, the success of black phosphorus in fast electronic and photonic devices is hindered by its rapid degradation in the presence of oxygen. Orthorhombic tin selenide is a representative of group IV-VI binary compounds that are robust and isoelectronic and share the same structure with black phosphorus. We measure the band structure of SnSe and find highly anisotropic valence bands that form several valleys having fast dispersion within the layers and negligible dispersion across. This is exactly the band structure desired for efficient thermoelectric generation where SnSe has shown great promise.

Band Structure of the IV-VI Black Phosphorus Analog and Thermoelectric SnSe

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pletikosic, Ivo; von Rohr, F.; Pervan, P.

Here, the success of black phosphorus in fast electronic and photonic devices is hindered by its rapid degradation in the presence of oxygen. Orthorhombic tin selenide is a representative of group IV-VI binary compounds that are robust and isoelectronic and share the same structure with black phosphorus. We measure the band structure of SnSe and find highly anisotropic valence bands that form several valleys having fast dispersion within the layers and negligible dispersion across. This is exactly the band structure desired for efficient thermoelectric generation where SnSe has shown great promise.

Impact of an Environmental Cleaning Intervention on the Presence of Methicillin-Resistant Staphylococcus aureus and Vancomycin-Resistant Enterococci on Surfaces in Intensive Care Unit Rooms

PubMed Central

Goodman, Eric R.; Platt, Richard; Bass, Richard; Onderdonk, Andrew B.; Yokoe, Deborah S.; Huang, Susan S.

2009-01-01

OBJECTIVES To evaluate the adequacy of discharge room cleaning and the impact of a cleaning intervention on the presence of methicillin-resistant Staphylococcus aureus (MRSA) and vancomycin-resistant enterococci (VRE) on environmental surfaces in intensive care unit (ICU) rooms. DESIGN Prospective environmental study. SETTING AND SAMPLE Convenience sample of ICU rooms in an academic hospital. METHODS AND INTERVENTION The intervention consisted of (1) a change from the use of pour bottles to bucket immersion for applying disinfectant to cleaning cloths, (2) an educational campaign, and (3) feedback regarding adequacy of discharge cleaning. Cleaning of 15 surfaces was evaluated by inspecting for removal of a preapplied mark, visible only with an ultraviolet lamp (“black light”). Six surfaces were cultured for MRSA or VRE contamination. Outcomes of mark removal and culture positivity were evaluated by χ2 testing and generalized linear mixed models, clustering by room. RESULTS The black-light mark was removed from 44% of surfaces at baseline, compared with 71% during the intervention (P <.001). The intervention increased the likelihood of removal of black-light marks after discharge cleaning (odds ratio, 4.4; P < .001), controlling for ICU type (medical vs surgical) and type of surface. The intervention reduced the likelihood of an environmental culture positive for MRSA or VRE (proportion of cultures positive, 45% at baseline vs 27% during the intervention; adjusted odds ratio, 0.4; P = .02). Broad, flat surfaces were more likely to be cleaned than were doorknobs and sink or toilet handles. CONCLUSIONS Increasing the volume of disinfectant applied to environmental surfaces, providing education for Environmental Services staff, and instituting feedback with a black-light marker improved cleaning and reduced the frequency of MRSA and VRE contamination. PMID:18624666

What Is Acne?

MedlinePlus

... skin’s oil glands and hair follicles. The small holes in your skin (pores) connect to oil glands ... that rise to the skin’s surface and look black (the black color is not from dirt). Papules: ...

Structure of Black Male Students Academic Achievement in Science

NASA Astrophysics Data System (ADS)

Rascoe, Barbara

Educational policies and practices have been largely unsuccessful in closing the achievement gap between Black and White students "Schwartz, 2001". This achievement gap is especially problematic for Black students in science "Maton, Hrabrowski, - Schmitt, 2000. Given the fact that the Black-White achievement gap is still an enigma, the purpose of this article is to address the Black female-Black male academic achievement gap in science majors. Addressing barriers that Black male students may experience as college science and engineering majors, this article presents marketing strategies relative to politics, emotional intelligence, and issues with respect to how science teaching, and Black male students' responses to it, are different. Many Black male students may need to experience a paradigm shift, which structures and enhances their science achievement. Paradigm shifts are necessary because exceptional academic ability and motivation are not enough to get Black males from their first year in a science, technology, education, and mathematics "STEM" major to a bachelor's degree in science and engineering. The conclusions focus on the balance of truth-slippery slopes concerning the confluence of science teachers' further ado and Black male students' theories, methods, and values that position their academic achievement in science and engineering majors.

Recent Progress on Stability and Passivation of Black Phosphorus.

PubMed

Abate, Yohannes; Akinwande, Deji; Gamage, Sampath; Wang, Han; Snure, Michael; Poudel, Nirakar; Cronin, Stephen B

2018-05-11

From a fundamental science perspective, black phosphorus (BP) is a canonical example of a material that possesses fascinating surface and electronic properties. It has extraordinary in-plane anisotropic electrical, optical, and vibrational states, as well as a tunable band gap. However, instability of the surface due to chemical degradation in ambient conditions remains a major impediment to its prospective applications. Early studies were limited by the degradation of black phosphorous surfaces in air. Recently, several robust strategies have been developed to mitigate these issues, and these novel developments can potentially allow researchers to exploit the extraordinary properties of this material and devices made out of it. Here, the fundamental chemistry of BP degradation and the tremendous progress made to address this issue are extensively reviewed. Device performances of encapsulated BP are also compared with nonencapsulated BP. In addition, BP possesses sensitive anisotropic photophysical surface properties such as excitons, surface plasmons/phonons, and topologically protected and Dirac semi-metallic surface states. Ambient degradation as well as any passivation method used to protect the surface could affect the intrinsic surface properties of BP. These properties and the extent of their modifications by both the degradation and passivation are reviewed. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Black Holes as Brains: Neural Networks with Area Law Entropy

NASA Astrophysics Data System (ADS)

Dvali, Gia

2018-04-01

Motivated by the potential similarities between the underlying mechanisms of the enhanced memory storage capacity in black holes and in brain networks, we construct an artificial quantum neural network based on gravity-like synaptic connections and a symmetry structure that allows to describe the network in terms of geometry of a d-dimensional space. We show that the network possesses a critical state in which the gapless neurons emerge that appear to inhabit a (d-1)-dimensional surface, with their number given by the surface area. In the excitations of these neurons, the network can store and retrieve an exponentially large number of patterns within an arbitrarily narrow energy gap. The corresponding micro-state entropy of the brain network exhibits an area law. The neural network can be described in terms of a quantum field, via identifying the different neurons with the different momentum modes of the field, while identifying the synaptic connections among the neurons with the interactions among the corresponding momentum modes. Such a mapping allows to attribute a well-defined sense of geometry to an intrinsically non-local system, such as the neural network, and vice versa, it allows to represent the quantum field model as a neural network.

Engineering Lipid Bilayer Membranes for Protein Studies

PubMed Central

Khan, Muhammad Shuja; Dosoky, Noura Sayed; Williams, John Dalton

2013-01-01

Lipid membranes regulate the flow of nutrients and communication signaling between cells and protect the sub-cellular structures. Recent attempts to fabricate artificial systems using nanostructures that mimic the physiological properties of natural lipid bilayer membranes (LBM) fused with transmembrane proteins have helped demonstrate the importance of temperature, pH, ionic strength, adsorption behavior, conformational reorientation and surface density in cellular membranes which all affect the incorporation of proteins on solid surfaces. Much of this work is performed on artificial templates made of polymer sponges or porous materials based on alumina, mica, and porous silicon (PSi) surfaces. For example, porous silicon materials have high biocompatibility, biodegradability, and photoluminescence, which allow them to be used both as a support structure for lipid bilayers or a template to measure the electrochemical functionality of living cells grown over the surface as in vivo. The variety of these media, coupled with the complex physiological conditions present in living systems, warrant a summary and prospectus detailing which artificial systems provide the most promise for different biological conditions. This study summarizes the use of electrochemical impedance spectroscopy (EIS) data on artificial biological membranes that are closely matched with previously published biological systems using both black lipid membrane and patch clamp techniques. PMID:24185908

Compact blackbody calibration sources for in-flight calibration of spaceborne infrared instruments

NASA Astrophysics Data System (ADS)

Scheiding, S.; Driescher, H.; Walter, I.; Hanbuch, K.; Paul, M.; Hartmann, M.; Scheiding, M.

2017-11-01

High-emissivity blackbodies are mandatory as calibration sources in infrared radiometers. Besides the requirements on the high spectral emissivity and low reflectance, constraints regarding energy consumption, installation space and mass must be considered during instrument design. Cavity radiators provide an outstanding spectral emissivity to the price of installation space and mass of the calibration source. Surface radiation sources are mainly limited by the spectral emissivity of the functional coating and the homogeneity of the temperature distribution. The effective emissivity of a "black" surface can be optimized, by structuring the substrate with the aim to enlarge the ratio of the surface to its projection. Based on the experiences of the Mercury Radiometer and Thermal Infrared Spectrometer (MERTIS) calibration source MBB3, the results of the surface structuring on the effective emissivity are described analytically and compared to the experimental performance. Different geometries are analyzed and the production methods are discussed. The high-emissivity temperature calibration source features values of 0.99 for wavelength from 5 μm to 10 μm and emissivity larger than 0.95 for the spectral range from 10 μm to 40 μm.

Floatable, Self-Cleaning, and Carbon-Black-Based Superhydrophobic Gauze for the Solar Evaporation Enhancement at the Air-Water Interface.

PubMed

Liu, Yiming; Chen, Jingwei; Guo, Dawei; Cao, Moyuan; Jiang, Lei

2015-06-24

Efficient solar evaporation plays an indispensable role in nature as well as the industry process. However, the traditional evaporation process depends on the total temperature increase of bulk water. Recently, localized heating at the air-water interface has been demonstrated as a potential strategy for the improvement of solar evaporation. Here, we show that the carbon-black-based superhydrophobic gauze was able to float on the surface of water and selectively heat the surface water under irradiation, resulting in an enhanced evaporation rate. The fabrication process of the superhydrophobic black gauze was low-cost, scalable, and easy-to-prepare. Control experiments were conducted under different light intensities, and the results proved that the floating black gauze achieved an evaporation rate 2-3 times higher than that of the traditional process. A higher temperature of the surface water was observed in the floating gauze group, revealing a main reason for the evaporation enhancement. Furthermore, the self-cleaning ability of the superhydrophobic black gauze enabled a convenient recycling and reusing process toward practical application. The present material may open a new avenue for application of the superhydrophobic substrate and meet extensive requirements in the fields related to solar evaporation.

Single Particle Tracking reveals two distinct environments for CD4 receptors at the surface of living T lymphocytes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mascalchi, Patrice; Lamort, Anne Sophie; Salome, Laurence

2012-01-06

Highlights: Black-Right-Pointing-Pointer We studied the diffusion of single CD4 receptors on living lymphocytes. Black-Right-Pointing-Pointer This study reveals that CD4 receptors have either a random or confined diffusion. Black-Right-Pointing-Pointer The dynamics of unconfined CD4 receptors was accelerated by a temperature raise. Black-Right-Pointing-Pointer The dynamics of confined CD4 receptors was unchanged by a temperature raise. Black-Right-Pointing-Pointer Our results suggest the existence of two different environments for CD4 receptors. -- Abstract: We investigated the lateral diffusion of the HIV receptor CD4 at the surface of T lymphocytes at 20 Degree-Sign C and 37 Degree-Sign C by Single Particle Tracking using Quantum Dots. Wemore » found that the receptors presented two major distinct behaviors that were not equally affected by temperature changes. About half of the receptors showed a random diffusion with a diffusion coefficient increasing upon raising the temperature. The other half of the receptors was permanently or transiently confined with unchanged dynamics on raising the temperature. These observations suggest that two distinct subpopulations of CD4 receptors with different environments are present at the surface of living T lymphocytes.« less

The region interior to the event horizon of the regular Hayward black hole

NASA Astrophysics Data System (ADS)

Perez-Roman, Ivan; Bretón, Nora

2018-06-01

The Painlevé-Gullstrand coordinates allow us to explore the interior of the regular Hayward black hole. The behavior of an infalling particle in traversing the Hayward black hole is compared with the one inside the Schwarzschild and Reissner-Nordstrom singular black holes. When approaching the origin the test particle trajectories present differences depending if the center is regular or singular. The velocities of the infalling test particle into the modified Hayward black hole are analyzed as well. As compared with the normal Hayward, in the modified Hayward black hole the particle moves faster and the surface gravity is smaller.

Structural and optical properties of copper-coated substrates for solar thermal absorbers

NASA Astrophysics Data System (ADS)

Pratesi, Stefano; De Lucia, Maurizio; Meucci, Marco; Sani, Elisa

2016-10-01

Spectral selectivity, i.e. merging a high absorbance at sunlight wavelengths to a low emittance at the wavelengths of thermal spectrum, is a key characteristics for materials to be used for solar thermal receivers. It is known that spectrally selective absorbers can raise the receiver efficiency for all solar thermal technologies. Tubular sunlight receivers for parabolic trough collector (PTC) systems can be improved by the use of spectrally selective coatings. Their absorbance is increased by deposing black films, while the thermal emittance is minimized by the use of properly-prepared substrates. In this work we describe the intermediate step in the fabrication of black-chrome coated solar absorbers, namely the fabrication and characterization of copper coatings on previously nickel-plated stainless steel substrates. We investigate the copper surface features and optical properties, correlating them to the coating thickness and to the deposition process, in the perspective to assess optimal conditions for solar absorber applications.

Isolation of an alpha-methylene-gamma-butyrolactone derivative, a toxin from the plant pathogen Lasiodiplodia theobromae.

PubMed

He, Guochun; Matsuura, Hideyuki; Yoshihara, Teruhiko

2004-10-01

Lasiodiplodia theobromae is known as a multi-infectious microorganism that causes considerable crop damage, particularly to tropical fruits. When the fruits are infected by L. theobromae, the typical symptom is the appearance of black spots on the surface of the infected fruit. When injected in to the peel of banana, the culture filtrate of L. theobromae induced formation of black spots. The structure of the isolated compound responsible for this effect was determined to be (3S,4R)-3-carboxy-2-methylene-heptan-4-olide on the basis of analysis of MS, IR, and 1H and 13C NMR spectroscopic data, including HMQC, HMBC, and 1H-1H COSY experiments. The active compound was not only isolated from the culture filtrate derived from potato dextrose medium, but also from the extract of infected peels of bananas.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Petiteau, Antoine; Shang Yu; Babak, Stanislav

Coalescing massive black hole binaries are the strongest and probably the most important gravitational wave sources in the LISA band. The spin and orbital precessions bring complexity in the waveform and make the likelihood surface richer in structure as compared to the nonspinning case. We introduce an extended multimodal genetic algorithm which utilizes the properties of the signal and the detector response function to analyze the data from the third round of mock LISA data challenge (MLDC3.2). The performance of this method is comparable, if not better, to already existing algorithms. We have found all five sources present in MLDC3.2more » and recovered the coalescence time, chirp mass, mass ratio, and sky location with reasonable accuracy. As for the orbital angular momentum and two spins of the black holes, we have found a large number of widely separated modes in the parameter space with similar maximum likelihood values.« less

Dynamic molecular structure of plant biomass-derived black carbon (biochar)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keiluweit, M.; Nico, P.S.; Johnson, M.G.

2009-11-15

Char black carbon (BC), the solid residue of incomplete combustion, is continuously being added to soils and sediments due to natural vegetation fires, anthropogenic pollution, and new strategies for carbon sequestration ('biochar'). Here we present a molecular-level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures. BET-N{sub 2} surface area, X-ray diffraction (XRD), synchrotron-based Near-edge X-ray Absorption Fine Structure (NEXAFS), and Fourier transform infrared (FT-IR) spectroscopy are used to show how two plant materials (wood and grass) undergo analogous, but quantitatively different physical-chemical transitions as charring temperature increases frommore » 100 to 700 C. These changes suggest the existence of four distinct categories of char consisting of a unique mixture of chemical phases and physical states: (i) in transition chars the crystalline character of the precursor materials is preserved, (ii) in amorphous chars the heat-altered molecules and incipient aromatic polycondensates are randomly mixed, (iii) composite chars consist of poorly ordered graphene stacks embedded in amorphous phases, and (iv) turbostratic chars are dominated by disordered graphitic crystallites. The molecular variations among the different char categories translate into differences in their ability to persist in the environment and function as environmental sorbents.« less

ARC-1979-AC79-7104

NASA Image and Video Library

1979-07-07

Range : 1,094,666 km (677,000 mi.) This false color picture of Callisto was taken by Voyager 2 and is centered on 11 degrees N and 171 degrees W. This rendition uses an ultraviolet image for the blue component. Because the surface displays regional contrast in UV, variations in surface materials are apparent. Notice in particular the dark blue haloes which surround bright craters in the eastern hemisphere. The surface of Callisto is the most heavily cratered of the Galilean satellites and resembles ancient heavily cratered terrains on the moon, Mercury and Mars. The bright areas are ejecta thrown out by relatively young impact craters. A large ringed structure, probably an impact basin, is shown in the upper left part of the picture. The color version of this picture was constructed by compositing black and white images taken through the ultraviolet, clear and orange filters.

Freestanding palladium nanosheets with plasmonic and catalytic properties

NASA Astrophysics Data System (ADS)

Huang, Xiaoqing; Tang, Shaoheng; Mu, Xiaoliang; Dai, Yan; Chen, Guangxu; Zhou, Zhiyou; Ruan, Fangxiong; Yang, Zhilin; Zheng, Nanfeng

2011-01-01

Ultrathin metal films can exhibit quantum size and surface effects that give rise to unique physical and chemical properties. Metal films containing just a few layers of atoms can be fabricated on substrates using deposition techniques, but the production of freestanding ultrathin structures remains a significant challenge. Here we report the facile synthesis of freestanding hexagonal palladium nanosheets that are less than 10 atomic layers thick, using carbon monoxide as a surface confining agent. The as-prepared nanosheets are blue in colour and exhibit a well-defined but tunable surface plasmon resonance peak in the near-infrared region. The combination of photothermal stability and biocompatibility makes palladium nanosheets promising candidates for photothermal therapy. The nanosheets also exhibit electrocatalytic activity for the oxidation of formic acid that is 2.5 times greater than that of commercial palladium black catalyst.

Black Families and the Struggle for Survival.

ERIC Educational Resources Information Center

Billingsley, Andrew; And Others

Breaking away from those who see the structure of family life in the black community as pathological, this study wishes to assist a lay audience in identifying the strengths of black families. The book provides both insights and resources for engaging churches and black families in the common task of enhancing black family life. Where the church's…

The Effect of Long-Term Continuous Cropping of Black Pepper on Soil Bacterial Communities as Determined by 454 Pyrosequencing.

PubMed

Xiong, Wu; Li, Zhigang; Liu, Hongjun; Xue, Chao; Zhang, Ruifu; Wu, Huasong; Li, Rong; Shen, Qirong

2015-01-01

In the present study, 3 replanted black pepper orchards with continuously cropping histories for 10, 21, and 55 years in tropical China, were selected for investigating the effect of monoculture on soil physiochemical properties, enzyme activities, bacterial abundance, and bacterial community structures. Results showed long-term continuous cropping led to a significant decline in soil pH, organic matter contents, enzymatic activities, and resulted in a decrease in soil bacterial abundance. 454 pyrosequencing analysis of 16S rRNA genes revealed that the Acidobacteria and Proteobacteria were the main phyla in the replanted black pepper orchard soils, comprising up to 73.82% of the total sequences; the relative abundances of Bacteroidetes and Firmicutes phyla decreased with long-term continuous cropping; and at genus level, the Pseudomonas abundance significantly depleted after 21 years continuous cropping. In addition, bacterial diversity significantly decreased after 55 years black pepper continuous cropping; obvious variations for community structures across the 3 time-scale replanted black pepper orchards were observed, suggesting monoculture duration was the major determinant for bacterial community structure. Overall, continuous cropping during black pepper cultivation led to a significant decline in soil pH, organic matter contents, enzymatic activities, resulted a decrease in soil bacterial abundance, and altered soil microbial community membership and structure, which in turn resulted in black pepper poor growth in the continuous cropping system.

The Effect of Long-Term Continuous Cropping of Black Pepper on Soil Bacterial Communities as Determined by 454 Pyrosequencing

PubMed Central

Xiong, Wu; Li, Zhigang; Liu, Hongjun; Xue, Chao; Zhang, Ruifu; Wu, Huasong; Li, Rong; Shen, Qirong

2015-01-01

In the present study, 3 replanted black pepper orchards with continuously cropping histories for 10, 21, and 55 years in tropical China, were selected for investigating the effect of monoculture on soil physiochemical properties, enzyme activities, bacterial abundance, and bacterial community structures. Results showed long-term continuous cropping led to a significant decline in soil pH, organic matter contents, enzymatic activities, and resulted in a decrease in soil bacterial abundance. 454 pyrosequencing analysis of 16S rRNA genes revealed that the Acidobacteria and Proteobacteria were the main phyla in the replanted black pepper orchard soils, comprising up to 73.82% of the total sequences; the relative abundances of Bacteroidetes and Firmicutes phyla decreased with long-term continuous cropping; and at genus level, the Pseudomonas abundance significantly depleted after 21 years continuous cropping. In addition, bacterial diversity significantly decreased after 55 years black pepper continuous cropping; obvious variations for community structures across the 3 time-scale replanted black pepper orchards were observed, suggesting monoculture duration was the major determinant for bacterial community structure. Overall, continuous cropping during black pepper cultivation led to a significant decline in soil pH, organic matter contents, enzymatic activities, resulted a decrease in soil bacterial abundance, and altered soil microbial community membership and structure, which in turn resulted in black pepper poor growth in the continuous cropping system. PMID:26317364

The Relationship Between Structural Racism and Black-White Disparities in Fatal Police Shootings at the State Level.

PubMed

Mesic, Aldina; Franklin, Lydia; Cansever, Alev; Potter, Fiona; Sharma, Anika; Knopov, Anita; Siegel, Michael

2018-04-01

The objective of this study was to discern the relationship between state-level structural racism and Black-White disparities in police shootings of victims not known to be armed. Using a Poisson regression, we evaluated the effect of structural racism on differences between states in Black-White disparities in fatal police shootings involving victims not known to be armed during the period from January 1, 2013 through June 30, 2017. We created a state racism index, which was comprised of five dimensions: (1) residential segregation; and gaps in (2) incarceration rates; (3) educational attainment; (4) economic indicators; and (5) employment status. After controlling for numerous state-level factors and for the underlying rate of fatal shootings of black victims in each state, the state racism index was a significant predictor of the Black-White disparity in police shooting rates of victims not known to be armed (incidence rate ratio: 1.24; 95% confidence interval, 1.02-1.50). For every 10-point increase in the state racism index, the Black-White disparity ratio of police shooting rates of people not known to be armed increased by 24%. These findings suggest that structural racism is an important predictor of the Black-White disparity in rates of police shootings of unarmed victims across states. Copyright © 2018 National Medical Association. Published by Elsevier Inc. All rights reserved.

Hawking radiation in a d-dimensional static spherically symmetric black hole surrounded by quintessence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen Songbai; Wang Bin; Su Rukeng

2008-06-15

We present a solution of Einstein equations with quintessential matter surrounding a d-dimensional black hole, whose asymptotic structures are determined by the state of the quintessential matter. We examine the thermodynamics of this black hole and find that the mass of the black hole depends on the equation of state of the quintessence, while the first law is universal. Investigating the Hawking radiation in this black hole background, we observe that the Hawking radiation dominates on the brane in the low-energy regime. For different asymptotic structures caused by the equation of state of the quintessential matter surrounding the black hole,more » we learn that the influences by the state parameter of the quintessence on Hawking radiation are different.« less

Electrochemical and kinetic studies of ultrafast laser structured LiFePO4 electrodes

NASA Astrophysics Data System (ADS)

Mangang, M.; Gotcu-Freis, P.; Seifert, H. J.; Pfleging, W.

2015-03-01

Due to a growing demand of cost-efficient lithium-ion batteries with an increased energy and power density as well as an increased life-time, the focus is set on intercalation cathode materials like LiFePO4. It has a high practical capacity, is environmentally friendly and has low material costs. However, its low electrical conductivity and low ionic diffusivity are major drawbacks for its use in electrochemical storage devices or electric vehicles. By adding conductive agents, the electrical conductivity can be enhanced. By increasing the surface of the cathode material which is in direct contact with the liquid electrolyte the lithium-ion diffusion kinetics can be improved. A new approach to increase the surface of the active material without changing the active particle packing density or the weight proportion of carbon black is the laser-assisted generation of 3D surface structures in electrode materials. In this work, ultrafast laser radiation was used to create a defined surface structure in LiFePO4 electrodes. It was shown that by using ultrashort laser pulses instead of nanosecond laser pulses, the ablation efficiency could be significantly increased. Furthermore, melting and debris formation were reduced. To investigate the diffusion kinetics, electrochemical methods such as cyclic voltammetry and galvanostatic intermittent titration technique were applied. It could be shown that due to a laser generated 3D structure, the lithium-ion diffusion kinetic, the capacity retention and cell life-time can be significantly improved.

Enhancement of life cycle assessment (LCA) methodology to include the effect of surface albedo on climate change: Comparing black and white roofs.

PubMed

Susca, Tiziana

2012-04-01

Traditionally, life cycle assessment (LCA) does not estimate a key property: surface albedo. Here an enhancement of the LCA methodology has been proposed through the development and employment of a time-dependent climatological model for including the effect of surface albedo on climate. The theoretical findings derived by the time-dependent model have been applied to the case study of a black and a white roof evaluated in the time-frames of 50 and 100 years focusing on the impact on global warming potential. The comparative life cycle impact assessment of the two roofs shows that the high surface albedo plays a crucial role in offsetting radiative forcings. In the 50-year time horizon, surface albedo is responsible for a decrease in CO(2)eq of 110-184 kg and 131-217 kg in 100 years. Furthermore, the white roof compared to the black roof, due to the high albedo, decreases the annual energy use of about 3.6-4.5 kWh/m(2). Copyright © 2011 Elsevier Ltd. All rights reserved.

Impact of Assimilating Surface Velocity Observations on the Model Sea Surface Height Using the NCOM-4DVAR

DTIC Science & Technology

2016-09-26

statistical analysis is done by not only examining the SSH forecast error across the entire do- main, but also by concentrating on the areamost densely covered...over (b) entire GoM domain and (d) GLAD region only. Statistics shown for FR (thin black), SSH1 (thick black), and VEL (gray) experiment 96-h SSH...coefficient. To statistically FIG. 9. Sea surface height (m) for AVISO (a) 1 Aug, (b) 20 Aug, (c) 10 Sep, and (d) 30 Sep; for SSH1 experiment (e) 1

Evaluation of the genetic structure present in natural populations of four subspecies of black cherry (Prunus serotina Ehrh.) from North America using SSR markers

USDA-ARS?s Scientific Manuscript database

Black cherry (Prunus serotina) is a fruit tree native to North America, and almost all parts of this plant have some use. This species is a complex of five subspecies with morphological differences and distinctive habitats. The genetic structure of 18 natural populations of black cherry was evaluate...

3D surface topography study of the biofunctionalized nanocrystalline Ti-6Zr-4Nb/Ca-P

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jakubowicz, J., E-mail: jaroslaw.jakubowicz@put.poznan.pl; Adamek, G.; Jurczyk, M.U.

2012-08-15

In this work surface of the sintered Ti-6Zr-4Nb nanocrystalline alloy was electrochemically biofunctionalized. The porous surface was produced by anodic oxidation in 1 M H{sub 3}PO{sub 4} + 2%HF electrolyte at 10 V for 30 min. Next the calcium-phosphate (Ca-P) layer was deposited, onto the formed porous surface, using cathodic potential - 5 V kept for 60 min in 0.042 M Ca(NO{sub 3}){sub 2} + 0.025 M (NH{sub 4}){sub 2}HPO{sub 4} + 0.1 M HCl electrolyte. The deposited Ca-P layer anchored in the pores. The biofunctionalized surface was studied by XRD, SEM and EDS. In vitro tests culture of normalmore » human osteoblast (NHOst) cells showed very good cells proliferation, colonization and multilayering. Using optical profiler, roughness and hybrid 3D surface topography parameters were estimated. Correlation between surface composition, morphology, roughness and biocompatibility results was done. It has been shown by us that surface with appropriate chemical composition and topography, after combined electrochemical anodic and cathodic surface treatment, supports osteoblast adhesion and proliferation. 3D topography measurements using optical profiler play a key role in the biomaterials surface analysis. - Highlights: Black-Right-Pointing-Pointer Nanocrystalline Ti-6Zr-4Nb/Ca-P material was produced for hard tissue implant applications. Black-Right-Pointing-Pointer Calcium-phosphate results in surface biofunctionalization. Black-Right-Pointing-Pointer The biofunctionalized surface shows good in-vitro behavior.« less

Why do red and dark-coloured cars lure aquatic insects? The attraction of water insects to car paintwork explained by reflection–polarization signals

PubMed Central

Kriska, György; Csabai, Zoltán; Boda, Pál; Malik, Péter; Horváth, Gábor

2006-01-01

We reveal here the visual ecological reasons for the phenomenon that aquatic insects often land on red, black and dark-coloured cars. Monitoring the numbers of aquatic beetles and bugs attracted to shiny black, white, red and yellow horizontal plastic sheets, we found that red and black reflectors are equally highly attractive to water insects, while yellow and white reflectors are unattractive. The reflection–polarization patterns of black, white, red and yellow cars were measured in the red, green and blue parts of the spectrum. In the blue and green, the degree of linear polarization p of light reflected from red and black cars is high and the direction of polarization of light reflected from red and black car roofs, bonnets and boots is nearly horizontal. Thus, the horizontal surfaces of red and black cars are highly attractive to red-blind polarotactic water insects. The p of light reflected from the horizontal surfaces of yellow and white cars is low and its direction of polarization is usually not horizontal. Consequently, yellow and white cars are unattractive to polarotactic water insects. The visual deception of aquatic insects by cars can be explained solely by the reflection–polarizational characteristics of the car paintwork. PMID:16769639

Sensitivity of Stratospheric Geoengineering with Black Carbon to Aerosol Size and Altitude of Injection

NASA Technical Reports Server (NTRS)

Kravitz, Ben; Robock, Alan; Shindell, Drew T.; Miller, Mark A.

2012-01-01

Simulations of stratospheric geoengineering with black carbon (BC) aerosols using a general circulation model with fixed sea surface temperatures show that the climate effects strongly depend on aerosol size and altitude of injection. 1 Tg BC/a injected into the lower stratosphere would cause little surface cooling for large radii but a large amount of surface cooling for small radii and stratospheric warming of over 60 C. With the exception of small particles, increasing the altitude of injection increases surface cooling and stratospheric warming. Stratospheric warming causes global ozone loss by up to 50% in the small radius case. The Antarctic shows less ozone loss due to reduction of polar stratospheric clouds, but strong circumpolar winds would enhance the Arctic ozone hole. Using diesel fuel to produce the aerosols is likely prohibitively expensive and infeasible. Although studying an absorbing aerosol is a useful counterpart to previous studies involving sulfate aerosols, black carbon geoengineering likely carries too many risks to make it a viable option for deployment.

Characteristics of organic soil in black spruce forests: implications for the application of land surface and ecosystem models in cold regions

Treesearch

Shuhua Yi; Kristen Manies; Jennifer Harden; David McGuire

2009-01-01

Soil organic layers (OL) play an important role in land-atmosphere exchanges of water, energy and carbon in cold environments. The proper implementation of OL in land surface and ecosystem models is important for predicting dynamic responses to climate warming. Based on the analysis of OL samples of black spruce (Picea mariana), we recommend that...

Observable Emission Features of Black Hole GRMHD Jets on Event Horizon Scales

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pu, Hung-Yi; Wu, Kinwah; Younsi, Ziri

The general-relativistic magnetohydrodynamical (GRMHD) formulation for black hole-powered jets naturally gives rise to a stagnation surface, where inflows and outflows along magnetic field lines that thread the black hole event horizon originate. We derive a conservative formulation for the transport of energetic electrons, which are initially injected at the stagnation surface and subsequently transported along flow streamlines. With this formulation the energy spectra evolution of the electrons along the flow in the presence of radiative and adiabatic cooling is determined. For flows regulated by synchrotron radiative losses and adiabatic cooling, the effective radio emission region is found to be finite,more » and geometrically it is more extended along the jet central axis. Moreover, the emission from regions adjacent to the stagnation surface is expected to be the most luminous as this is where the freshly injected energetic electrons are concentrated. An observable stagnation surface is thus a strong prediction of the GRMHD jet model with the prescribed non-thermal electron injection. Future millimeter/submillimeter (mm/sub-mm) very-long-baseline interferometric observations of supermassive black hole candidates, such as the one at the center of M87, can verify this GRMHD jet model and its associated non-thermal electron injection mechanism.« less

Nonlinear Conductivities and Electrochemical Performances of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Electrodes

DOE PAGES

Su, Xin; Ha, Seonbaek; Ishwait, Manar B.; ...

2016-01-01

There is increasing research attention on optimizing the carbon black nanoparticles’ structure and loading procedure for improving conductivities and thus, electrochemical performances of cathodes in lithium-ion batteries. Recently, LiNi 0.5Co 0.2Mn 0.3O 2 (NCM523) has been actively investigated due to its larger specific capacity and lower cost compared to conventional cathode materials. Presented here is a high energy density NCM523 cathode obtained by reducing the carbon content using the state-of-the-art carbon nanoparticles developed at Cabot Corporation. It is the first time that the nonlinear conductivity of NCM523 electrodes has been discovered, which is significantly impacted by the dispersion and surface crystalline quality of carbon black nanoparticles, especially when the loading of carbon black is only 1 wt%. The nonlinear conductivity of the cathodes can dramatically affect their electrochemical performances at high rates (more » $$\\geqq$$3C), which is close to the tunneling saturated current. In addition, there is no discernable difference in terms of the rate and cycle performance of the NCM523 electrodes, when reducing the loading of novel carbon black nanoparticles from 5 wt% to 1 wt% in the cathode. Therefore, the energy density of the electrode can be increased by 9% by using existing commercially available electrode materials.« less

Testing strong-field gravity with tidal Love numbers

NASA Astrophysics Data System (ADS)

Cardoso, Vitor; Franzin, Edgardo; Maselli, Andrea; Pani, Paolo; Raposo, Guilherme

2017-04-01

The tidal Love numbers (TLNs) encode the deformability of a self-gravitating object immersed in a tidal environment and depend significantly both on the object's internal structure and on the dynamics of the gravitational field. An intriguing result in classical general relativity is the vanishing of the TLNs of black holes. We extend this result in three ways, aiming at testing the nature of compact objects: (i) we compute the TLNs of exotic compact objects, including different families of boson stars, gravastars, wormholes, and other toy models for quantum corrections at the horizon scale. In the black-hole limit, we find a universal logarithmic dependence of the TLNs on the location of the surface. (ii) We compute the TLNs of black holes beyond vacuum general relativity, including Einstein-Maxwell, Brans-Dicke, and Chern-Simons gravity. (iii) We assess the ability of present and future gravitational-wave detectors to measure the TLNs of these objects, including the first analysis of TLNs with LISA. Both LIGO, ET, and LISA can impose interesting constraints on boson stars, while LISA is able to probe even extremely compact objects. We argue that the TLNs provide a smoking gun of new physics at the horizon scale and that future gravitational-wave measurements of the TLNs in a binary inspiral provide a novel way to test black holes and general relativity in the strong-field regime.

Inactivation of lipoprotein lipase occurs on the surface of THP-1 macrophages where oligomers of angiopoietin-like protein 4 are formed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Makoveichuk, Elena; Sukonina, Valentina; Kroupa, Olessia

2012-08-24

Highlights: Black-Right-Pointing-Pointer Lipoprotein lipase (LPL) activity is controlled by ANGPTL4 in THP-1 macrophages. Black-Right-Pointing-Pointer Both LPL and ANGPTL4 bind to THP-1 macrophages in a heparin-releasable fashion. Black-Right-Pointing-Pointer Only monomers of ANGPTL4 are present within THP-1 macrophages. Black-Right-Pointing-Pointer Covalent oligomers of ANGPTL4 appear on cell surface and in medium. Black-Right-Pointing-Pointer Inactivation of LPL coincide with ANGPTL4 oligomer formation on cell surfaces. -- Abstract: Lipoprotein lipase (LPL) hydrolyzes triglycerides in plasma lipoproteins causing release of fatty acids for metabolic purposes in muscles and adipose tissue. LPL in macrophages in the artery wall may, however, promote foam cell formation and atherosclerosis. Angiopoietin-like proteinmore » (ANGPTL) 4 inactivates LPL and ANGPTL4 expression is controlled by peroxisome proliferator-activated receptors (PPAR). The mechanisms for inactivation of LPL by ANGPTL4 was studied in THP-1 macrophages where active LPL is associated with cell surfaces in a heparin-releasable form, while LPL in the culture medium is mostly inactive. The PPAR{delta} agonist GW501516 had no effect on LPL mRNA, but increased ANGPTL4 mRNA and caused a marked reduction of the heparin-releasable LPL activity concomitantly with accumulation of inactive, monomeric LPL in the medium. Intracellular ANGPTL4 was monomeric, while dimers and tetramers of ANGPTL4 were present in the heparin-releasable fraction and medium. GW501516 caused an increase in the amount of ANGPTL4 oligomers on the cell surface that paralleled the decrease in LPL activity. Actinomycin D blocked the effects of GW501516 on ANGPTL4 oligomer formation and prevented the inactivation of LPL. Antibodies against ANGPTL4 interfered with the inactivation of LPL. We conclude that inactivation of LPL in THP-1 macrophages primarily occurs on the cell surface where oligomers of ANGPTL4 are formed.« less

Labor Market Structure, Intragenerational Mobility, and Discrimination: Black Male Advancement out of Low-Paying Occupations, 1962-1973

ERIC Educational Resources Information Center

Power, Marshall I.

1986-01-01

Comparison of intragenerational mobility of black and white men shows the following: (1) black upward mobility is less frequent and more restricted; (2) blacks within the public sector have substantial rates of upward mobility to nonmanagerial positions; and (3) discrimination against blacks in the labor market has not disappeared. (Author/PS)

(Un)Intended Consequences? The Impact of the Brown v. Board of Education Decision on the Employment Status of Black Educators

ERIC Educational Resources Information Center

Tillman, Linda C.

2004-01-01

The displacement of Black educators after the "Brown v. Board of Education" decision was an extraordinary social injustice. The wholesale firing of Black educators threatened the economic, social, and cultural structure of the Black community, and ultimately the social, emotional, and academic success of Black children. The author presents a…

Subtle Variations in Surface Properties of Black Silicon Surfaces Influence the Degree of Bactericidal Efficiency

NASA Astrophysics Data System (ADS)

Bhadra, Chris M.; Werner, Marco; Baulin, Vladimir A.; Truong Khanh, Vi; Kobaisi, Mohammad Al; Nguyen, Song Ha; Balcytis, Armandas; Juodkazis, Saulius; Wang, James Y.; Mainwaring, David E.; Crawford, Russell J.; Ivanova, Elena P.

2018-06-01

One of the major challenges faced by the biomedical industry is the development of robust synthetic surfaces that can resist bacterial colonization. Much inspiration has been drawn recently from naturally occurring mechano-bactericidal surfaces such as the wings of cicada ( Psaltoda claripennis) and dragonfly ( Diplacodes bipunctata) species in fabricating their synthetic analogs. However, the bactericidal activity of nanostructured surfaces is observed in a particular range of parameters reflecting the geometry of nanostructures and surface wettability. Here, several of the nanometer-scale characteristics of black silicon (bSi) surfaces including the density and height of the nanopillars that have the potential to influence the bactericidal efficiency of these nanostructured surfaces have been investigated. The results provide important evidence that minor variations in the nanoarchitecture of substrata can substantially alter their performance as bactericidal surfaces.[Figure not available: see fulltext.

Laser shock peening studies on SS316LN plate with various sacrificial layers

NASA Astrophysics Data System (ADS)

Yella, Pardhu; Venkateswarlu, P.; Buddu, Ramesh K.; Vidyasagar, D. V.; Sankara Rao, K. Bhanu; Kiran, P. Prem; Rajulapati, Koteswararao V.

2018-03-01

Laser shock peening (LSP) has been utilized to modify the surface characteristics of SS316LN plates of 6 mm thickness. Laser pulse widths employed are 30 ps and 7 ns and the laser energy was varied in the range 5-90 mJ. Peening was performed in direct ablation mode as well as with various sacrificial layers such as black paint, transparent adhesive tape and absorbing adhesive tape. The surface characteristics were greatly influenced by the type of sacrificial layer employed. The average surface roughness values are about 0.4 μm when the black paint and transparent adhesive tape were used as sacrificial layers. In contrast to this, using absorbent adhesive tape as a sacrificial layer has resulted in an average surface roughness of about 0.04 μm. Irrespective of pulse durations (30 ps or 7 ns), absorbent adhesive tape has always resulted in compressive residual stresses whereas other layers appear to be not that effective. In case of 30 ps pulse, as the laser energy was increased from 5 mJ to 25 mJ, there was a texture observed in (111) reflection of X-ray diffractograms and the center of the peak has also gradually shifted to left. X-ray line profile analysis suggests that with the increase in laser energy, lattice microstrain also has increased. This lattice microstrain appears to be resulting from the increased dislocation density in the peened sample as evidenced during transmission electron microscopic investigations. Cross-sectional scanning electron microscopy performed on peened samples suggests that absorbing adhesive tape brings no surface damage to the samples whereas other sacrificial layers have resulted in some surface damage. Based on all these structural and microstructural details, it is recommended that absorbent tape could be used as a sacrificial layer during LSP process which induces surface residual stresses with no damage to the sample surface.

37 CFR 212.3 - Registration of claims for protection of eligible designs.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Drawings must be in black ink on white 81/2″ × 11″ unruled paper. A drawing of a design should include... of the design. Solid black surface shading is not permitted except when used to represent the black... included as a separate figure, in addition to other figures which fully disclose the subject matter of the...

37 CFR 212.3 - Registration of claims for protection of eligible designs.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) Drawings must be in black ink on white 81/2″ × 11″ unruled paper. A drawing of a design should include... of the design. Solid black surface shading is not permitted except when used to represent the black... included as a separate figure, in addition to other figures which fully disclose the subject matter of the...

37 CFR 212.3 - Registration of claims for protection of eligible designs.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Drawings must be in black ink on white 81/2″×11″ unruled paper. A drawing of a design should include... of the design. Solid black surface shading is not permitted except when used to represent the black... included as a separate figure, in addition to other figures which fully disclose the subject matter of the...

Reintroducing fire into the Blacks Mountain Research Natural Area: effects on fire hazard

Treesearch

Carl N. Skinner

2005-01-01

Frequent, low-intensity, surface fires were an integral ecological process in the Blacks Mountain Experimental Forest (BMEF) prior to the 20th Century. With rare exception, fires have been successfully excluded from BMEF since the early 1900s. The Blacks Mountain Research Natural Area (BMRNA) covers approximately 521 acres of BMEF in 5 compartments of approximately 100...

Smarr formula for Lovelock black holes: A Lagrangian approach

NASA Astrophysics Data System (ADS)

Liberati, Stefano; Pacilio, Costantino

2016-04-01

The mass formula for black holes can be formally expressed in terms of a Noether charge surface integral plus a suitable volume integral, for any gravitational theory. The integrals can be constructed as an application of Wald's formalism. We apply this formalism to compute the mass and the Smarr formula for static Lovelock black holes. Finally, we propose a new prescription for Wald's entropy in the case of Lovelock black holes, which takes into account topological contributions to the entropy functional.

Tribological properties of sputtered MoS sub 2 films in relation to film morphology

NASA Technical Reports Server (NTRS)

Spalvins, T.

1980-01-01

Thin sputter deposited MoS2 films in the 2000 to 6000 A thickness range have shown excellent lubricating properties, when sputtering parameters and substrate conditions are properly selected and precisely controlled. The lubricating properties of sputtered MoS2 films are strongly influenced by their crystalline-amorphous structure, morphology and composition. The coefficient of friction can range from 0.04 which is effective lubrication to 0.4 which reflects an absence of lubricating properties. Visual screening and slight wiping of the as-sputtered MoS2 film can identify the integrity of the film. An acceptable film displays a black-sooty surface appearance whereas an unacceptable film has a highly reflective, gray surface and the film is hard and brittle.

Micro Galvanic Cell To Generate PtO and Extend the Triple-Phase Boundary during Self-Assembly of Pt/C and Nafion for Catalyst Layers of PEMFC.

PubMed

Long, Zhi; Gao, Liqin; Li, Yankai; Kang, Baotao; Lee, Jin Yong; Ge, Junjie; Liu, Changpeng; Ma, Shuhua; Jin, Zhao; Ai, Hongqi

2017-11-08

The self-assembly powder (SAP) with varying Nafion content was synthesized and characterized by XRD, XPS, HRTEM, and mapping. It is observed that the oxygen from oxygen functional groups transfers to the surface of Pt and generate PtO during the process of self-assembly with the mechanism of micro galvanic cell, where Pt, carbon black, and Nafion act as the anode, cathode and electrolyte, respectively. The appearance of PtO on the surface of Pt leads to a turnover of Nafion structure, and therefore more hydrophilic sulfonic groups directly contact with Pt, and thus the triple-phase boundary (TPB) has been expanded.

Comparative study of pulsed laser cleaning applied to weathered marble surfaces

NASA Astrophysics Data System (ADS)

Ortiz, P.; Antúnez, V.; Ortiz, R.; Martín, J. M.; Gómez, M. A.; Hortal, A. R.; Martínez-Haya, B.

2013-10-01

The removal of unwanted matter from surface stones is a demanding task in the conservation of cultural heritage. This paper investigates the effectiveness of near-infrared (IR) and ultraviolet (UV) laser pulses for the cleaning of surface deposits, iron oxide stains and different types of graffiti (black, red and green sprays and markers, and black cutting-edge ink) on dolomitic white marble. The performance of the laser techniques is compared to common cleaning methods on the same samples, namely pressurized water and chemical treatments. The degree of cleaning achieved with each technique is assessed by means of colorimetric measurements and X-ray microfluorescence. Eventual morphological changes induced on the marble substrate are monitored with optical and electronic microscopy. It is found that UV pulsed laser ablation at 266 nm manages to clean all the stains except the cutting-edge ink, although some degree of surface erosion is produced. The IR laser pulses at 1064 nm can remove surface deposits and black spray acceptably, but a yellowing is observed on the stone surface after treatment. An economic evaluation shows that pulsed laser cleaning techniques are advantageous for the rapid cleaning of small or inaccessible surface areas, although their extensive application becomes expensive due to the long operating times required.

Thermodynamic studies of different black holes with modifications of entropy

NASA Astrophysics Data System (ADS)

Haldar, Amritendu; Biswas, Ritabrata

2018-02-01

In recent years, the thermodynamic properties of black holes are topics of interests. We investigate the thermodynamic properties like surface gravity and Hawking temperature on event horizon of regular black holes viz. Hayward Class and asymptotically AdS (Anti-de Sitter) black holes. We also analyze the thermodynamic volume and naive geometric volume of asymptotically AdS black holes and show that the entropy of these black holes is simply the ratio of the naive geometric volume to thermodynamic volume. We plot the different graphs and interpret them physically. We derive the `cosmic-Censorship-Inequality' for both type of black holes. Moreover, we calculate the thermal heat capacity of aforesaid black holes and study their stabilities in different regimes. Finally, we compute the logarithmic correction to the entropy for both the black holes considering the quantum fluctuations around the thermal equilibrium and study the corresponding thermodynamics.

Flexible all-solid-state supercapacitors based on graphene/carbon black nanoparticle film electrodes and cross-linked poly(vinyl alcohol)-H2SO4 porous gel electrolytes

NASA Astrophysics Data System (ADS)

Fei, Haojie; Yang, Chongyang; Bao, Hua; Wang, Gengchao

2014-11-01

Flexible all-solid-state supercapacitors (SCs) are fabricated using graphene/carbon black nanoparticle (GCB) film electrodes and cross-linked poly(vinyl alcohol)-H2SO4 porous gel electrolytes (gPVAP-H2SO4). The GCB composite films, with carbon black (CB) nanoparticles uniformly distributed in the graphene nanosheets, greatly improve the active surface areas and ion transportation of pristine graphene film. The porous structure of as-prepared gPVAP-H2SO4 membrane improves the equilibrium swelling ratio in electrolyte and provides interconnected ion transport channels. The chemical crosslinking solves the fluidity problem of PVA-H2SO4 gel electrolyte at high temperature. As-fabricated GCB//gPVAP(20)-H2SO4//GCB flexible SC displays an increased specific capacitance (144.5 F g-1 at 0.5 A g-1) and a higher specific capacitance retention (67.9% from 0.2 to 4 A g-1). More importantly, the flexible SC possesses good electrochemical performance at high temperature (capacitance retention of 78.3% after 1000 cycles at 70 °C).

The Effects of High Density on the X-ray Spectrum Reflected from Accretion Discs Around Black Holes

NASA Technical Reports Server (NTRS)

Garcia, Javier A.; Fabian, Andrew C.; Kallman, Timothy R.; Dauser, Thomas; Parker, Micahel L.; McClintock, Jeffrey E.; Steiner, James F.; Wilms, Jorn

2016-01-01

Current models of the spectrum of X-rays reflected from accretion discs around black holes and other compact objects are commonly calculated assuming that the density of the disc atmosphere is constant within several Thomson depths from the irradiated surface. An important simplifying assumption of these models is that the ionization structure of the gas is completely specified by a single, fixed value of the ionization parameter (xi), which is the ratio of the incident flux to the gas density. The density is typically fixed at n(sub e) = 10(exp 15) per cu cm. Motivated by observations, we consider higher densities in the calculation of the reflected spectrum. We show by computing model spectra for n(sub e) approximately greater than 10(exp 17) per cu cm that high-density effects significantly modify reflection spectra. The main effect is to boost the thermal continuum at energies 2 approximately less than keV. We discuss the implications of these results for interpreting observations of both active galactic nuclei and black hole binaries. We also discuss the limitations of our models imposed by the quality of the atomic data currently available.

The Dynamics of a Viscous Gas Ring around a Kerr Black Hole

NASA Astrophysics Data System (ADS)

Riffert, H.

2000-01-01

The dynamics of a rotationally symmetric viscous gas ring around a Kerr black hole is calculated in the thin-disk approximation. An evolution equation for the surface density Σ(t,r) is derived, which is the relativistic extension of a classical equation obtained by R. Lüst. A singular point appears at the radius of the last stable circular orbit r=rc. The nature of this point is investigated, and it turns out that the solution is always bounded at rc, and no boundary condition can be obtained at this radius. A unique solution of an initial value problem requires a matching condition at rc which follows from the flow structure between rc and the horizon. In the model presented here, the density in this domain is zero, and the resulting boundary condition leads to a vanishing shear stress at r=rc, which is the condition used in the standard stationary thin-disk model of Novikov & Thorne. Numerical solutions of the evolution equation are presented for two different angular momenta of the black hole. The time evolution of the resulting accretion rate depends strongly on this angular momentum.

Contemporary genetic structure and postglacial demographic history of the black scorpionfish, Scorpaena porcus, in the Mediterranean and the Black Seas.

PubMed

Boissin, E; Micu, D; Janczyszyn-Le Goff, M; Neglia, V; Bat, L; Todorova, V; Panayotova, M; Kruschel, C; Macic, V; Milchakova, N; Keskin, Ç; Anastasopoulou, A; Nasto, I; Zane, L; Planes, S

2016-05-01

Understanding the distribution of genetic diversity in the light of past demographic events linked with climatic shifts will help to forecast evolutionary trajectories of ecosystems within the current context of climate change. In this study, mitochondrial sequences and microsatellite loci were analysed using traditional population genetic approaches together with Bayesian dating and the more recent approximate Bayesian computation scenario testing. The genetic structure and demographic history of a commercial fish, the black scorpionfish, Scorpaena porcus, was investigated throughout the Mediterranean and Black Seas. The results suggest that the species recently underwent population expansions, in both seas, likely concomitant with the warming period following the Last Glacial Maximum, 20 000 years ago. A weak contemporaneous genetic differentiation was identified between the Black Sea and the Mediterranean Sea. However, the genetic diversity was similar for populations of the two seas, suggesting a high number of colonizers entered the Black Sea during the interglacial period and/or the presence of a refugial population in the Black Sea during the glacial period. Finally, within seas, an east/west genetic differentiation in the Adriatic seems to prevail, whereas the Black Sea does not show any structured spatial genetic pattern of its population. Overall, these results suggest that the Black Sea is not that isolated from the Mediterranean, and both seas revealed similar evolutionary patterns related to climate change and changes in sea level. © 2016 John Wiley & Sons Ltd.

Black hole formation from the gravitational collapse of a nonspherical network of structures

NASA Astrophysics Data System (ADS)

Delgado Gaspar, Ismael; Hidalgo, Juan Carlos; Sussman, Roberto A.; Quiros, Israel

2018-05-01

We examine the gravitational collapse and black hole formation of multiple nonspherical configurations constructed from Szekeres dust models with positive spatial curvature that smoothly match to a Schwarzschild exterior. These configurations are made of an almost spherical central core region surrounded by a network of "pancake-like" overdensities and voids with spatial positions prescribed through standard initial conditions. We show that a full collapse into a focusing singularity, without shell crossings appearing before the formation of an apparent horizon, is not possible unless the full configuration becomes exactly or almost spherical. Seeking for black hole formation, we demand that shell crossings are covered by the apparent horizon. This requires very special fine-tuned initial conditions that impose very strong and unrealistic constraints on the total black hole mass and full collapse time. As a consequence, nonspherical nonrotating dust sources cannot furnish even minimally realistic toy models of black hole formation at astrophysical scales: demanding realistic collapse time scales yields huge unrealistic black hole masses, while simulations of typical astrophysical black hole masses collapse in unrealistically small times. We note, however, that the resulting time-mass constraint is compatible with early Universe models of primordial black hole formation, suitable in early dust-like environments. Finally, we argue that the shell crossings appearing when nonspherical dust structures collapse are an indicator that such structures do not form galactic mass black holes but virialize into stable stationary objects.

Structurally coloured secondary particles composed of black and white colloidal particles.

PubMed

Takeoka, Yukikazu; Yoshioka, Shinya; Teshima, Midori; Takano, Atsushi; Harun-Ur-Rashid, Mohammad; Seki, Takahiro

2013-01-01

This study investigated the colourful secondary particles formed by controlling the aggregation states of colloidal silica particles and the enhancement of the structural colouration of the secondary particles caused by adding black particles. We obtained glossy, partially structurally coloured secondary particles in the absence of NaCl, but matte, whitish secondary particles were obtained in the presence of NaCl. When a small amount of carbon black was incorporated into both types of secondary particles, the incoherent multiple scattering of light from the amorphous region was considerably reduced. However, the peak intensities in the reflection spectra, caused by Bragg reflection and by coherent single wavelength scattering, were only slightly decreased. Consequently, a brighter structural colour of these secondary particles was observed with the naked eye. Furthermore, when magnetite was added as a black particle, the coloured secondary particles could be moved and collected by applying an external magnetic field.

Structurally Coloured Secondary Particles Composed of Black and White Colloidal Particles

PubMed Central

Takeoka, Yukikazu; Yoshioka, Shinya; Teshima, Midori; Takano, Atsushi; Harun-Ur-Rashid, Mohammad; Seki, Takahiro

2013-01-01

This study investigated the colourful secondary particles formed by controlling the aggregation states of colloidal silica particles and the enhancement of the structural colouration of the secondary particles caused by adding black particles. We obtained glossy, partially structurally coloured secondary particles in the absence of NaCl, but matte, whitish secondary particles were obtained in the presence of NaCl. When a small amount of carbon black was incorporated into both types of secondary particles, the incoherent multiple scattering of light from the amorphous region was considerably reduced. However, the peak intensities in the reflection spectra, caused by Bragg reflection and by coherent single wavelength scattering, were only slightly decreased. Consequently, a brighter structural colour of these secondary particles was observed with the naked eye. Furthermore, when magnetite was added as a black particle, the coloured secondary particles could be moved and collected by applying an external magnetic field. PMID:23917891

Establishing A Geologic Baseline of Cape Canaveral''s Natural Landscape: Black Point Drive

NASA Technical Reports Server (NTRS)

Parkinson, Randall W.

2002-01-01

The goal of this project is to identify the process responsible for the formation of geomorphic features in the Black Point Drive area of Merritt Island National Wildlife Refuge/Kennedy Space Center (MINWR/KSC), northwest Cape Canaveral. This study confirms the principal landscape components (geomorphology) of Black Point Drive reflect interaction between surficial sediments deposited in association with late-Quaternary sea-level highstands and the chemical evolution of late-Cenozoic sub-surface limestone formations. The Black Point Drive landscape consists of an undulatory mesic terrain which dips westward into myriad circular and channel-like depression marshes and lakes. This geomorphic gradient may reflect: (1) spatial distinctions in the elevation, character or age of buried (pre-Miocene) limestone formations, (2) dissolution history of late-Quaternary coquina and/or (3) thickness of unconsolidated surface sediment. More detailed evaluation of subsurface data will be necessary before this uncertain0 can be resolved.

The rising star of 2D black phosphorus beyond graphene: synthesis, properties and electronic applications

NASA Astrophysics Data System (ADS)

Chen, Pengfei; Li, Neng; Chen, Xingzhu; Ong, Wee-Jun; Zhao, Xiujian

2018-01-01

Black phosphorus, which is a relatively rare allotrope of phosphorus, was first discovered by Bridgman in 1914. Since the advent of two-dimensional (2D) black phosphorus (which is known as phosphorene due to its resembling graphene sheets) in early 2014, research interest in the arena of black phosphorus was reignited in the scientific and technological communities. Henceforth, a myriad of research studies on this new member of the 2D world have been extensively emerged. Fascinatingly, 2D black phosphorus exhibits a distinctive wrinkled structure with the high hole mobility up to 1000 cm2 V-1 s-1, excellent mechanical properties, tunable band structures, anisotropic thermal, electrical and optical properties, thus leading to its marvelous prospects in device applications. This review firstly introduces the state-of-the-art development, structural properties and preparation routes of black phosphorus. In particular, anisotropy involved in mechanical properties, thermal conductivity, carrier transport as well as optical properties is comprehensively discussed. Apart from discussing the recent progress in black phosphorus which is applied to devices (i.e. field effect transistors and optoelectronic), the review also highlights the bottlenecks encountered by the society and finally casts an invigorating perspective and insightful outlook on the future direction of the next-generation 2D black phosphorus by harnessing its remarkable characteristics for energy production.

A universal counting of black hole microstates in AdS4

NASA Astrophysics Data System (ADS)

Azzurli, Francesco; Bobev, Nikolay; Crichigno, P. Marcos; Min, Vincent S.; Zaffaroni, Alberto

2018-02-01

Many three-dimensional N=2 SCFTs admit a universal partial topological twist when placed on hyperbolic Riemann surfaces. We exploit this fact to derive a universal formula which relates the planar limit of the topologically twisted index of these SCFTs and their three-sphere partition function. We then utilize this to account for the entropy of a large class of supersymmetric asymptotically AdS4 magnetically charged black holes in M-theory and massive type IIA string theory. In this context we also discuss novel AdS2 solutions of eleven-dimensional supergravity which describe the near horizon region of large new families of supersymmetric black holes arising from M2-branes wrapping Riemann surfaces.

Advanced Photogrammetry to Assess Lichen Colonization in the Hyper-Arid Namib Desert.

PubMed

Hinchliffe, Graham; Bollard-Breen, Barbara; Cowan, Don A; Doshi, Ashray; Gillman, Len N; Maggs-Kolling, Gillian; de Los Rios, Asuncion; Pointing, Stephen B

2017-01-01

The hyper-arid central region of the Namib Desert is characterized by quartz desert pavement terrain that is devoid of vascular plant covers. In this extreme habitat the only discernible surface covers are epilithic lichens that colonize exposed surfaces of quartz rocks. These lichens are highly susceptible to disturbance and so field surveys have been limited due to concerns about disturbing this unusual desert feature. Here we present findings that illustrate how non-destructive surveys based upon advanced photogrammetry techniques can yield meaningful and novel scientific data on these lichens. We combined 'structure from motion analysis,' computer vision and GIS to create 3-dimensional point clouds from two-dimensional imagery. The data were robust in its application to estimating absolute lichen cover. An orange Stellarangia spp. assemblage had coverage of 22.8% of available substrate, whilst for a black Xanthoparmelia spp. assemblage coverage was markedly lower at 0.6% of available substrate. Hyperspectral signatures for both lichens were distinct in the near-infra red range indicating that Xanthoparmelia spp. was likely under relatively more moisture stress than Stellarangia spp. at the time of sampling, and we postulate that albedo effects may have contributed to this in the black lichen. Further transformation of the data revealed a colonization preference for west-facing quartz surfaces and this coincides with prevailing winds for marine fog that is the major source of moisture in this system. Furthermore, a three-dimensional 'fly through' of the lichen habitat was created to illustrate how the application of computer vision in microbiology has further potential as a research and education tool. We discuss how advanced photogrammetry could be applied in astrobiology using autonomous rovers to add quantitative ecological data for visible surface colonization on the surface of Mars.

Advanced Photogrammetry to Assess Lichen Colonization in the Hyper-Arid Namib Desert

PubMed Central

Hinchliffe, Graham; Bollard-Breen, Barbara; Cowan, Don A.; Doshi, Ashray; Gillman, Len N.; Maggs-Kolling, Gillian; de Los Rios, Asuncion; Pointing, Stephen B.

2017-01-01

The hyper-arid central region of the Namib Desert is characterized by quartz desert pavement terrain that is devoid of vascular plant covers. In this extreme habitat the only discernible surface covers are epilithic lichens that colonize exposed surfaces of quartz rocks. These lichens are highly susceptible to disturbance and so field surveys have been limited due to concerns about disturbing this unusual desert feature. Here we present findings that illustrate how non-destructive surveys based upon advanced photogrammetry techniques can yield meaningful and novel scientific data on these lichens. We combined ‘structure from motion analysis,’ computer vision and GIS to create 3-dimensional point clouds from two-dimensional imagery. The data were robust in its application to estimating absolute lichen cover. An orange Stellarangia spp. assemblage had coverage of 22.8% of available substrate, whilst for a black Xanthoparmelia spp. assemblage coverage was markedly lower at 0.6% of available substrate. Hyperspectral signatures for both lichens were distinct in the near-infra red range indicating that Xanthoparmelia spp. was likely under relatively more moisture stress than Stellarangia spp. at the time of sampling, and we postulate that albedo effects may have contributed to this in the black lichen. Further transformation of the data revealed a colonization preference for west-facing quartz surfaces and this coincides with prevailing winds for marine fog that is the major source of moisture in this system. Furthermore, a three-dimensional ‘fly through’ of the lichen habitat was created to illustrate how the application of computer vision in microbiology has further potential as a research and education tool. We discuss how advanced photogrammetry could be applied in astrobiology using autonomous rovers to add quantitative ecological data for visible surface colonization on the surface of Mars. PMID:29312153

Discovery of riblets in a bird beak (Rynchops) for low fluid drag

PubMed Central

2016-01-01

Riblet structures found on fast-swimming shark scales, such as those found on a mako shark, have been shown to reduce fluid drag. In previous experimental and modelling studies, riblets have been shown to provide drag reduction by lifting vortices formed in turbulent flow, decreasing overall shear stresses. Skimmer birds (Rynchops) are the only birds to catch fish in flight by flying just above the water surface with a submerged beak to fish for food. Because they need to quickly catch prey, reducing drag on their beak is advantageous. For the first time, riblet structures found on the beak of the skimmer bird have been studied experimentally and computationally for low fluid drag properties. In this study, skimmer replicas were studied for drag reduction through pressure drop in closed-channel, turbulent water flow. Pressure drop measurements are compared for black and yellow skimmer beaks in two configurations, and mako shark skin. In addition, two configurations of skimmer beak were modelled to compare drag properties and vortex structures. Results are discussed, and a conceptual model is presented to explain a possible drag reduction mechanism in skimmers. This article is part of the themed issue ‘Bioinspired hierarchically structured surfaces for green science’. PMID:27354734

Electronic transport properties of suspended few-nm black phosphorus nanoribbons

NASA Astrophysics Data System (ADS)

Masih Das, Paul; Danda, Gopinath; Cupo, Andrew; Jothi Thiruraman, Priyanka; Meunier, Vincent; Drndic, Marija

Theoretical studies of few-nm wide black phosphorus nanoribbons have revealed highly tunable, width-dependent properties such as modulation of bandgap magnitude and carrier mobility. Due to the atmospheric instability of black phosphorus in the few-layer regime and a lack of suitable lithographic patterning techniques, these structures have yet to be reported. Here, we demonstrate the fabrication of few-nm wide and thick black phosphorus nanoribbons via in situ electron beam nanosculpting. We also present in situ orientation- and width-dependent two-terminal electronic transport measurements of these structures. These measurements yield valuable insight into the semiconducting properties of black phosphorus and its associated lower-dimensional nanostructures. NIH Grant R21HG007856, NSF Grant EFRI 2-DARE (EFRI-1542707).

Dual band sensitivity enhancements of a VO(x) microbolometer array using a patterned gold black absorber.

PubMed

Smith, Evan M; Panjwani, Deep; Ginn, James; Warren, Andrew P; Long, Christopher; Figuieredo, Pedro; Smith, Christian; Nath, Janardan; Perlstein, Joshua; Walter, Nick; Hirschmugl, Carol; Peale, Robert E; Shelton, David

2016-03-10

Infrared-absorbing gold black has been selectively patterned onto the active surfaces of a vanadium-oxide-based infrared bolometer array. Patterning by metal lift-off relies on protection of the fragile gold black with an evaporated oxide, which preserves much of gold black's high absorptance. This patterned gold black also survives the dry-etch removal of the sacrificial polyimide used to fabricate the air-bridge bolometers. For our fabricated devices, infrared responsivity is improved 22% in the long-wave IR and 70% in the mid-wave IR by the gold black coating, with no significant change in detector noise, using a 300°C blackbody and 80 Hz chopping rate. The increase in the time constant caused by the additional mass of gold black is ∼15%.

Controlled drug release on amine functionalized spherical MCM-41

DOE Office of Scientific and Technical Information (OSTI.GOV)

Szegedi, Agnes, E-mail: szegedi@chemres.hu; Popova, Margarita; Goshev, Ivan

2012-10-15

MCM-41 silica with spherical morphology and small particle sizes (100 nm) was synthesized and modified by post-synthesis method with different amounts of 3-aminopropyltriethoxysilane (APTES). A comparative study of the adsorption and release of a model drug, ibuprofen, was carried out. The modified and drug loaded mesoporous materials were characterized by XRD, TEM, N{sub 2} physisorption, elemental analysis, thermal analysis and FT-IR spectroscopy. A new method was developed for the quantitative determination of amino groups in surface modified mesoporous materials by the ninhydrin reaction. Good correlation was found between the amino content of the MCM-41 materials determined by the ninhydrin methodmore » and their ibuprofen adsorption capacity. Amino modification resulted in high degree of ibuprofen loading and slow release rate in comparison to the parent non-modified MCM-41. - Graphical abstract: Determination of surface amino groups by ninhidrin method. Highlights: Black-Right-Pointing-Pointer Spherical MCM-41 modified by different amounts of APTES was studied. Black-Right-Pointing-Pointer Ibuprofen (IBU) adsorption and release characteristics was tested. Black-Right-Pointing-Pointer The ninhydrin reaction was used for the quantitative determination of amino groups. Black-Right-Pointing-Pointer Stoichiometric amount of APTES is enough for totally covering the surface with amino groups. Black-Right-Pointing-Pointer Good correlation was found between the amino content and IBU adsorption capacity.« less

Phototaxis and polarotaxis hand in hand: night dispersal flight of aquatic insects distracted synergistically by light intensity and reflection polarization.

PubMed

Boda, Pál; Horváth, Gábor; Kriska, György; Blahó, Miklós; Csabai, Zoltán

2014-05-01

Based on an earlier observation in the field, we hypothesized that light intensity and horizontally polarized reflected light may strongly influence the flight behaviour of night-active aquatic insects. We assumed that phototaxis and polarotaxis together have a more harmful effect on the dispersal flight of these insects than they would have separately. We tested this hypothesis in a multiple-choice field experiment using horizontal test surfaces laid on the ground. We offered simultaneously the following visual stimuli for aerial aquatic insects: (1) lamplit matte black canvas inducing phototaxis alone, (2) unlit shiny black plastic sheet eliciting polarotaxis alone, (3) lamplit shiny black plastic sheet inducing simultaneously phototaxis and polarotaxis, and (4) unlit matte black canvas as a visually unattractive control. The unlit matte black canvas trapped only a negligible number (13) of water insects. The sum (16,432) of the total numbers of water beetles and bugs captured on the lamplit matte black canvas (7,922) and the unlit shiny black plastic sheet (8,510) was much smaller than the total catch (29,682) caught on the lamplit shiny black plastic sheet. This provides experimental evidence for the synergistic interaction of phototaxis (elicited by the unpolarized direct lamplight) and polarotaxis (induced by the strongly and horizontally polarized plastic-reflected light) in the investigated aquatic insects. Thus, horizontally polarizing artificial lamplit surfaces can function as an effective ecological trap due to this synergism of optical cues, especially in the urban environment.

Phototaxis and polarotaxis hand in hand: night dispersal flight of aquatic insects distracted synergistically by light intensity and reflection polarization

NASA Astrophysics Data System (ADS)

Boda, Pál; Horváth, Gábor; Kriska, György; Blahó, Miklós; Csabai, Zoltán

2014-05-01

Based on an earlier observation in the field, we hypothesized that light intensity and horizontally polarized reflected light may strongly influence the flight behaviour of night-active aquatic insects. We assumed that phototaxis and polarotaxis together have a more harmful effect on the dispersal flight of these insects than they would have separately. We tested this hypothesis in a multiple-choice field experiment using horizontal test surfaces laid on the ground. We offered simultaneously the following visual stimuli for aerial aquatic insects: (1) lamplit matte black canvas inducing phototaxis alone, (2) unlit shiny black plastic sheet eliciting polarotaxis alone, (3) lamplit shiny black plastic sheet inducing simultaneously phototaxis and polarotaxis, and (4) unlit matte black canvas as a visually unattractive control. The unlit matte black canvas trapped only a negligible number (13) of water insects. The sum (16,432) of the total numbers of water beetles and bugs captured on the lamplit matte black canvas (7,922) and the unlit shiny black plastic sheet (8,510) was much smaller than the total catch (29,682) caught on the lamplit shiny black plastic sheet. This provides experimental evidence for the synergistic interaction of phototaxis (elicited by the unpolarized direct lamplight) and polarotaxis (induced by the strongly and horizontally polarized plastic-reflected light) in the investigated aquatic insects. Thus, horizontally polarizing artificial lamplit surfaces can function as an effective ecological trap due to this synergism of optical cues, especially in the urban environment.

Mechanochemical synthesis of nanostructured Sr(Ti{sub 1-x}Fe{sub x})O{sub 3-{delta}} solid-solution powders and their surface photovoltage responses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen Xiaofeng; Luo Qiong; GlobalFoundries Singapore Pte Ltd, 60 Woodlands Industrial Park D Street 2, Singapore 738406

2012-05-15

A series of nanostructure Sr(Ti{sub 1-x}Fe{sub x})O{sub 3-{delta}} (STFx, x=0.4, 0.6, 0.8) solid-solution powders were synthesized by mechanochemical approach milling from the mixture of SrO, Fe{sub 2}O{sub 3} and TiO{sub 2} metal oxides at room temperature. The XRD results revealed that the perovskite STFx nanoparticles were finally formed with few residual {alpha}-Fe{sub 2}O{sub 3} detected dependent on the milling conditions. The structure evolution suggested that the mechanochemical synthesis underwent via a solid-state reaction route to initially form Ti-rich perovskite and then incorporate with the residual {alpha}-Fe{sub 2}O{sub 3} to achieve the estimated composition. The synthesized STF08 powders exhibited the significantmore » Surface Photovoltage (SPV) spectrum response both in UV and in visible-light region with p-type semiconductor behavior. This finding suggested that the synthesized STF nanopowders could potentially utilize more solar spectrum energy effectively for photo-oxidation and photo-catalysis applications. - Graphical abstract: It is demonstrated that Sr(Ti{sub 1-x}Fe{sub x})O{sub 3-{delta}} perovskite nanopowders were successfully synthesized by mechanochemical reaction approach at room temerpature, and the synthesized STF08 powders showed the significant SPV response in UV-VIS region with p-type semiconductor behaviors. Highlights: Black-Right-Pointing-Pointer Sr(Ti{sub 1-x}Fe{sub x})O{sub 3-{delta}} nanopowders synthesized by mechanochemical reaction approach. Black-Right-Pointing-Pointer The reaction process was shorten by introduce high impact energy. Black-Right-Pointing-Pointer Synthesized STF08 powders show the significant SPV response in UV-VIS region. Black-Right-Pointing-Pointer Synthesized STFx powders show p-type semiconductor behaviors.« less

Suppression of dendritic cells' maturation and functions by daidzein, a phytoestrogen

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yum, Min Kyu; Jung, Mi Young; Cho, Daeho

2011-12-15

Isoflavones are ubiquitous compounds in foods and in the environment in general. Daidzein and genistein, the best known of isoflavones, are structurally similar to 17{beta}-estradiol and known to exert estrogenic effects. They also evidence a broad variety of biological properties, including antioxidant, anti-carcinogenic, anti-atherogenic and anti-osteoporotic activities. Previously, daidzein was reported to increase the phagocytic activity of peritoneal macrophages and splenocyte proliferation, and to inhibit nitric oxide (NO) production in macrophages. However, its potential impacts on immune response in dendritic cells (DCs), antigen-presenting cells that link innate and adaptive immunity, have yet to be clearly elucidated. In this study, wemore » evaluated the effects of isoflavones on the maturation and activation of DCs. Isoflavones (formononetin, daidzein, equol, biochanin A, genistein) were found to differentially affect the expression of CD86, a costimulatory molecule, on lipopolysaccharide (LPS)-stimulated DCs. In particular, daidzein significantly and dose-dependently inhibited the expression levels of maturation-associated cell surface markers including CD40, costimulatory molecules (CD80, CD86), and major histocompatibility complex class II (I-A{sup b}) molecule on LPS-stimulated DCs. Daidzein also suppressed pro-inflammatory cytokine production such as IL-12p40, IL-6 and TNF-{alpha}, whereas it didn't affect IL-10 and IL-1{beta} expression. Furthermore, daidzein enhanced endocytosis and inhibited the allo-stimulatory ability of LPS-stimulated DCs on T cells, indicating that daidzein treatment can inhibit the functional maturation of DCs. These results demonstrate that daidzein may exhibit immunosuppressive activity by inhibiting the maturation and activation of DCs. -- Highlights: Black-Right-Pointing-Pointer Daidzein inhibited expression of maturation-associated cell surface markers in DCs. Black-Right-Pointing-Pointer Daidzein suppressed expression of pro-inflammatory cytokines in LPS-stimulated DCs. Black-Right-Pointing-Pointer Daidzein enhanced endocytosis and inhibited allo-stimulatory ability of DCs. Black-Right-Pointing-Pointer Daidzein exhibited immunosuppressive activity by inhibiting the activation of DCs.« less

A High Resolution Look at Black Sand Particles from Sand Dunes of Saudi Arabia Using Electron Microscopy

NASA Astrophysics Data System (ADS)

Hussain, M. M.; Aburizaiza, O. S.; Siddique, A.; Hershey, D. L.; Guerrieri, D. A.; Qurashi, J.; Abbass, M.; Blake, D. R.; Khwaja, H. A.

2013-12-01

Particulate air pollution is a problem of health concern. The microscopic make-up of different varieties of sand particles found and collected at a sand dune site in Badr, Saudi Arabia has been determined. Primary emphasis is given to the use of multiple high resolution electron microscopy (viz., Scanning Electron Microscopy with Energy Dispersive X-ray spectrometry (SEM/EDS) and Laser Scanning Microscopy (LSM)) to study the morphologies, emission source types, size, and elemental composition of the particles, and to evaluate the presence of ';coatings or contaminants' adsorbed or carried on by the black sand particles. White sand contains natural coarse particles associated with wind-blown releases from crustal surfaces, weathering of an igneous/metamorphic rock source, and volcanic activities. Silicates (alumino-silicates) and quartz (clear, milky, rose) dominate white sand and rest appears to contain calcite, olivine, feldspar, and magnetite. Black sand particles exhibit very different morphologies and microstructures (surface roughness) compared with white sand and volcanic ash. Morphological analyses have shown that the black sand contain ultrafine particles. Black sand is strongly magnetic, which indicates the mineral magnetite (strongly magnetic) or elemental iron. Iron, C, O, Ti, Si, V, and S particles dominate the black sand. Natural and anthropogenic sources have been implicated for the observed particles. Analysis revealed that the surface of white sand particles is mainly covered with the fine particles. It is known that emissions from combustion contain carbon soot and other contaminants that are easily absorbed by soil particles during a long-range transport.

Sacrificial Protective Coating Materials that can be Regenerated In-Situ to Enable High Performance Membranes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Malati, Peter; Ganguli, Rahul; Mehrotra, Vivek

In the pulp and paper industry, weak black liquor concentration is carried out using energy intensive evaporators. Briefly, after wood digestion, water is evaporated to concentrate weak black liquor to the point where the black liquor can be burned in a recovery boiler, which ultimately leads to the recovery of digestion chemicals. Because it is less energy intensive than heat-driven separation, pressure-driven separation of water from black liquor using membranes could reduce the energy usage by 55 trillion Btu yr -1 and carbon dioxide emissions by more than 11 million metric tons CO 2 per year if the first twomore » evaporators are replaced. However, weak black liquor is a hot, corrosive, and highly fouling feed with organic molecules, colloids, and ions that clog membranes within hours of operation. We have shown that membrane-based concentration of weak black liquor is feasible, but only with our antifouling and anti-clogging technology that is based on a sacrificial Bio-inspired Living Skin concept. This concept is based on a conformal coating that is formed at the membrane surface and within the pores. Weak foulant adhesion dramatically decreases membrane fouling while the superhydrophilicity of the coating increases the water permeability. Moreover, the coating can be completely removed during backflushing, which removes foulants that may irreversibly adhere to the coating over long periods of time. The skin shedding completely regenerates the membrane surface and pores, restoring the original flux. This is followed by in-situ recoating, using the existing membrane plumbing and pumps, which essentially creates a brand new membrane surface.« less

Study on wind wave variability by inhomogeneous currents in the closed seas

NASA Astrophysics Data System (ADS)

Bakhanov, Victor V.; Bogatov, Nikolai A.; Ermoshkin, Aleksei V.; Ivanov, Andrei Yu.; Kemarskaya, Olga N.; Titov, Victor I.

2012-09-01

Complex experiments were performed in the north-eastern part of the Black Sea and in the south-eastern part of the White Sea to study variability of the current fields and other characteristics of the sea, wind waves, and parameters of the near-surface atmospheric layer. Measurements were carried out from the onboard of the scientific research vessels by optical, radar and acoustic sensors. The heterogeneity of bottom topography in Black Sea had quasi-one-dimensional character. The case of the two-dimensionally heterogeneous relief of the bottom was investigated in the White Sea. The peculiarity of these experiments was simultaneous measurements from onboard of vessel synchronously with acquisitions of synthetic aperture radar (SAR) images of the Envisat and TerraSAR-X satellites. We have detected for the case of the quasi-one-dimensionally heterogeneous current a difference between the sea surface roughness above the shelf zone and the roughness at the deep bottom. We found that the inhomogeneities of the bottom topography can manifest as a change not only in the amplitude of different characteristics of surface wave and atmospheric near-water layer, but also in their frequency spectrum. In White Sea the special features of the flow of the powerful tidal current (up to 1 m/s) around the secluded underwater elevation and the spatial structure of surface anomalies in the field of these two-dimensional-heterogeneous currents are analyzed. The numerical simulation of the wind wave transformation in the field of two-dimensional- heterogeneous flows is carried out. The qualitative agreement of the calculation results with the experimental data is shown.

Anti-graffiti nanocomposite materials for surface protection of a very porous stone

NASA Astrophysics Data System (ADS)

Licchelli, Maurizio; Malagodi, Marco; Weththimuni, Maduka; Zanchi, Chiara

2014-09-01

The preservation of stone substrates from defacement induced by graffiti represents a very challenging task, which can be faced by applying suitable protective agents on the surface. Although different anti-graffiti materials have been developed, it is often found that their effectiveness is unsatisfactory, most of all when applied on very porous stones, e.g. Lecce stone. The aim of this work was to study the anti-graffiti behaviour of new nanocomposite materials obtained by dispersing montmorillonite nanoparticles (layered aluminosilicates with a high-aspect ratio) into a fluorinated polymer matrix (a fluorinated polyurethane based on perfluoropolyether blocks). Polymeric structure was modified by inducing a cross-linking process, in order to produce a durable anti-graffiti coating with enhanced barrier properties. Several composites were prepared using a naturally occurring and an organically modified montmorillonite clay (1, 3, and 5 % w/w concentrations). Materials were applied on Lecce stone specimens, and then their treated surfaces were soiled by a black ink permanent marker or by a black acrylic spray paint. Several repeated staining/cleaning cycles were performed in order to evaluate anti-graffiti effectiveness. Colorimetric measurements were selected to assess the anti-graffiti performance. It was found that the presence of 3 % w/w organically modified montmorillonite in the polymer coating is enough to induce a durable anti-graffiti effect when the stone surface is stained by acrylic paint. Less promising results are obtained when staining by permanent marker is considered as all the investigated treatments afford a reasonable protection from ink only for the first staining/cleaning cycle.

On the Bioeconomic potential of the Black Sea

NASA Astrophysics Data System (ADS)

Gomoiu, Marian-Traian

2015-04-01

The paper is a plea for the need to engage in more intensive researches on the Black Sea region bioeconomy so that they should keep pace with the researches taking place in other European seas. Bioeconomy offers Europe a unique opportunity to address complex inter-connected challenges, while achieving economic growth. Bioeconomy refers to the set of economic activities relating to the invention, development, production and use of biological products and processes. According to the European Commission, bioeconomy can be found in societal challenge category entitled "Food security, sustainable agriculture and forestry, marine, maritime and inland water research, and the Bioeconomy" (http://ec.europa.eu/research/bioeconomy/h2020/index_en.htm); a transition is needed towards an optimal and renewable use of biological resources and towards sustainable primary production and processing systems. The author makes a brief overview of the European preoccupations concerning scientific research into bioeconomy and, equally, presents Romanian thinking in the field, launched several decades ago, but never applied and developed in practice. In 1933 Dr. Gr. Antipa, former outstanding student of Ernst Haeckel at Jena, expounded his conception of general biology and the biological structure of the Black Sea introducing the concepts of "biosociology" and "bioeconomy", drawing conclusions on the natural mechanism of fish production in this sea and specifying the determining factors in functioning. Antipa notes the lack of uniformity of the living conditions in the Black Sea and draws conclusions based on indices and faunal aspects found in different areas and at different depths: 1. The Black Sea, to an even greater extent than the Baltic Sea, with which it has some similarity both of them having a continuous surface and homogeneous appearance, is divided into more zones or biotypes, bounded horizontally and vertically - i.e. depending on areas and depths - each with distinct and well-defined physical and biological characteristics of environment. 2. Each of these biotopes hosts a special "association of organisms", whose composition differs in the number and type of species and individuals associated, and which constitutes a series of as many biocoenoses, different from each other. Antipa arrived at the belief that "organism sociability" is a basic property of all living things - it is therefore a general fact which cannot be denied - and "biosociology" is the basis of the principles of construction and functioning of this living mechanism. The "biosociological structure" of a certain water, being itself determined by the bionomic conditions of external factors, past and present, varies from one water body to another, depending on the variations that influence the physical structure. That applies to ponds, lakes and river systems and also to seas and oceans. Biosociological structure is the one that requires, in turn, "biotechnology" (in the special case of fish "ichthyo-technology"), that is it dictates the procedures and detailed way of how the system functions, naturally transforming raw material (nutritive salts in water) into the final product (plankton, various lower animals, fish). At the same time, bio-sociological structure also secures "bioeconomy", i.e. the general natural organization, from an economic point of view, of production, distribution, circulation and consumption of water within each category and their classification in the general economy of nature. The Black Sea region must consolidate and enhance its position as an important region for research and cooperative initiatives addressing the multiple dimensions of sustainable fishery, aquaculture and use of aquatic resources. The fundamental mission of the Black Sea marine researches should be to enhance regional benefit by: • promoting research collaboration and networks focused on sustainable fishery, aquaculture and use of marine biological resources; • providing reliable, relevant, and current research contributions to the Black Sea biodiversity policies; • being a significant stakeholder in interdisciplinary Black Sea region initiatives to address key challenges facing the marine biological resources sector; and • strengthening the position of the Black Sea region within marine research in both European and international contexts. Strategies to achieve the targets for the Black Sea region bioeconomy in the near future: 1. Strengthen research of the Black Sea and South European Seas common interest for sustainable management of the marine environment, particularly for the economic valuation of biodiversity. 2. Provide research-based policy advice to promote a sustainable future for the ecosystems of the Black Sea region. 3. Disseminate research results and develop communication activities that will increase interactions between researchers, industrialists, and politicians.

Analysis of internal structure changes in black human hair keratin fibers resulting from bleaching treatments using Raman spectroscopy

NASA Astrophysics Data System (ADS)

Kuzuhara, Akio

2013-09-01

In order to investigate in detail the internal structure changes in virgin black human hair keratin fibers resulting from bleaching treatments, the structure of cross-sections at various depths of black human hair, which had been impossible due to high melanin grande content, was directly analyzed using Raman spectroscopy. The gauche-gauche-gauche (GGG) content of the sbnd SSsbnd groups existing from the cuticle region to the center of cortex region of the virgin black human hair remarkably decreased, while the gauche-gauche-trans and trans-gauche-trans contents were not changed by performing the excessive bleaching treatment. In particular, it was found that not only the β-sheet and/or random coil content, but also the α-helix content existing throughout the cortex region of virgin black human hair decreased. In addition, the transmission electron microscope observation shows that the proteins in the cell membrane complex, the cuticle and cortex of the virgin black human hair were remarkably eluted by performing the excessive bleaching treatment. From these experiments, the author concluded that the sbnd SSsbnd groups, which have a GGG conformation were decomposed and finally converted to cysteic acid, and the α-helix structure of some of the proteins existing in the keratin was changed to the random coil structure, or eluted from the cortex region, thereby leading to the reduction in the protein density of the virgin human hair after the excessive bleaching treatment.

Black hole shadows and invariant phase space structures

NASA Astrophysics Data System (ADS)

Grover, J.; Wittig, A.

2017-07-01

Utilizing concepts from dynamical systems theory, we demonstrate how the existence of light rings, or fixed points, in a spacetime will give rise to families of periodic orbits and invariant manifolds in phase space. It is shown that these structures can define the shape of the black hole shadow as well as a number of salient features of the spacetime lensing. We illustrate this through the analysis of lensing by a hairy black hole.

Never judge a black hole by its area

NASA Astrophysics Data System (ADS)

Ong, Yen Chin

2015-04-01

Christodoulou and Rovelli have shown that black holes have large interiors that grow asymptotically linearly in advanced time, and speculated that this may be relevant to the information loss paradox. We show that there is no simple relation between the interior volume of an arbitrary black hole and its horizon area. That is, the volume enclosed is not necessarily a monotonically increasing function of the surface area.

Afro-American Language and Culture in the Classroom.

ERIC Educational Resources Information Center

Abrahams, Roger D.

An awareness of the culture and social structure of the lower class Black American community is crucial for understanding "Black English," and therefore is vital for those engaged in educating Black Americans. An in-group means of communication and expression of group solidarity, Black English does not however represent a single code, but rather,…

Themes, Style and Language Patterns of Selected Modern Black Poets.

ERIC Educational Resources Information Center

Moore-Smith, Mary

Modern black poetry has emerged as an art form whose viewpoint (theme), style (structure), and language (diction and usage) focus on a particular kind of sensibility and consciousness in conflict with the world in which the poetry moves. The black aesthetic addresses the consciousness of blackness and deplores traditional poetic niceties in favor…

Testing the Factorial Invariance of the Black Racial Identity Scale across Gender

ERIC Educational Resources Information Center

Lott, Joe L., II

2011-01-01

Given that over 50 studies have been published using the Black Racial Identity Scale (BRIAS), the study of its dimensions and structural components are important to understanding Black people and the evolution of Black racial identity theory. Unconstrained and constrained confirmatory factor analysis models were estimated across males and females…

Social Structure and Black Family Life: An Analysis of Current Trends.

ERIC Educational Resources Information Center

Staples, Robert

1987-01-01

The crisis of the Black family is actually the crisis of the Black male and his inability to carry out the normative responsibilities of husband and father in the nuclear family. The family's disintegration is a symptom of the institutional decimation of Black males, the legacy of institutional racism. (LHW)

HIV prevention for Black women: structural barriers and opportunities.

PubMed

Newman, Peter A; Williams, Charmaine C; Massaquoi, Notisha; Brown, Marsha; Logie, Carmen

2008-08-01

Black women bear a disproportionate burden of HIV/AIDS in North America. The purpose of this investigation was to explore Black Canadian women's perspectives on HIV risk and prevention. Four 90-minute focus groups (n=26) and six key informant interviews were conducted in Toronto with Black women of African and Caribbean descent and low socioeconomic status. Data analysis revealed a number of potent barriers to existing HIV preventive interventions: stigma, cultural disconnections, lack of engagement of Black religious institutions, and multiple intersecting forms of discrimination. Recommended HIV prevention opportunities included the Black church, mainstreaming, health care providers, and ethno-specific agencies. HIV prevention strategies for North American Black women, rather than focusing on HIV and individual risk behaviors, may benefit from a primary focus on social and structural factors (e.g., promoting gender equality, economic opportunity, women-controlled prevention technologies and combating racism in health care) thereby integrating HIV prevention into the larger context of community health and survival.

Soil Profile Observations Relating to Drouth Damage in Black Willow Stands

Treesearch

WIlliam R. Beaufait

1955-01-01

During drouth, black willow (Salix nigra Karsh.) is quite sensitive to subsoil differences. Surface inspection alone rarely gives an adequate clue to the quality of the variously stratified alluvial soils on which willow may occur.

Polyextremotolerant black fungi: oligotrophism, adaptive potential, and a link to lichen symbioses

PubMed Central

Gostinčar, Cene; Muggia, Lucia; Grube, Martin

2012-01-01

Black meristematic fungi can survive high doses of radiation and are resistant to desiccation. These adaptations help them to colonize harsh oligotrophic habitats, e.g., on the surface and subsurface of rocks. One of their most characteristic stress-resistance mechanisms is the accumulation of melanin in the cell walls. This, production of other protective molecules and a plastic morphology further contribute to ecological flexibility of black fungi. Increased growth rates of some species after exposure to ionizing radiation even suggest yet unknown mechanisms of energy production. Other unusual metabolic strategies may include harvesting UV or visible light or gaining energy by forming facultative lichen-like associations with algae or cyanobacteria. The latter is not entirely surprising, since certain black fungal lineages are phylogenetically related to clades of lichen-forming fungi. Similar to black fungi, lichen-forming fungi are adapted to growth on exposed surfaces with low availability of nutrients. They also efficiently use protective molecules to tolerate frequent periods of extreme stress. Traits shared by both groups of fungi may have been important in facilitating the evolution and radiation of lichen-symbioses. PMID:23162543

Q ‑ Φ criticality and microstructure of charged AdS black holes in f(R) gravity

NASA Astrophysics Data System (ADS)

Deng, Gao-Ming; Huang, Yong-Chang

2017-12-01

The phase transition and critical behaviors of charged AdS black holes in f(R) gravity with a conformally invariant Maxwell (CIM) source and constant curvature are further investigated. As a highlight, this research is carried out by employing new state parameters (T,Q, Φ) and contributes to deeper understanding of the thermodynamics and phase structure of black holes. Our analyses manifest that the charged f(R)-CIM AdS black hole undergoes a first-order small-large black hole phase transition, and the critical behaviors qualitatively behave like a Van der Waals liquid-vapor system. However, differing from the case in Einstein’s gravity, phase structures of the black holes in f(R) theory exhibit an interesting dependence on gravity modification parameters. Moreover, we adopt the thermodynamic geometry to probe the black hole microscopic properties. The results show that, on the one hand, both the Ruppeiner curvature and heat capacity diverge exactly at the critical point, on the other hand, the f(R)-CIM AdS black hole possesses the property as ideal Fermi gases. Of special interest, we discover a microscopic similarity between the black holes and a Van der Waals liquid-vapor system.

Black layers on historical architecture.

PubMed

Toniolo, Lucia; Zerbi, Carlotta M; Bugini, Roberto

2009-03-01

The external surface of any building in urban polluted environment is unavoidably destined to be covered with layers that assume a grey to black colour and are generally called 'black crusts'. These, according to standard protocols and glossary, are deteriorated surface layers of stone material; they can have variable thickness, are hard and fragile and can detach spontaneously from the substrate, which, in general, is quite decayed. Plain visual examination may lead to consider 'black crusts' all similar, whilst only a careful diagnostic investigation can distinguish 'black crusts' and the consequences of their formation on stone substrates. In this paper, various black layers on marble are studied and compared and the morphological and compositional characteristics discussed according to the related mechanisms of formation. Differences between old (hundred years) and recent crusts (30 years) are investigated and pointed out. Samples of black crusts collected from the Milan Cathedral façade (Candoglia Marble) have been studied and compared with the careful and synergic employ of traditional techniques: optical (transmission and reflected VIS light) and electron microscopy, X-ray spectrometry and micro-Fourier transform infrared spectroscopy. Visual examination of loose fragments does not allow to point out outstanding differences amongst the various samples; black layers have similar main mineral components, gypsum and airborne particles, with different spatial distribution. The microscopic studies allowed to point out the porosity differences, the gypsum crystallisation habit, different amount of embedded particles, level and progress of marble decay. The observations lead to define three main types of black crusts: black crust deriving from marble sulphation, compact deposit and encrustation due to exogenic materials deposition. Black crusts show evidence of sulphation in progress, without a clear continuity solution between crust and marble; the lack of separation is particularly evident in 'recent' crust, where the sulphation process is more active. Black compact deposits show a higher porosity than black crusts because gypsum is not coming from the chemical corrosion of the substrate but from outside; actually, in the former case, the substrate is sound. Encrustations show a highly regular crystal organisation of gypsum (close packed tabular crystals) that cannot be traced back to casual atmospheric deposit or to corrosion of the substrate but rather to the crystallisation of a solution coming from an external source. Also in this case, the marble is sound; evidence of the effect of some protection treatment is pointed out. In spite of the apparent similarity of the examined samples, analytical results have evidenced three main types of black crusts: black crust with decayed substrate, compact deposit and black encrustation showing a sound substrate underneath. Experimental evidence of calcite grains sulphation in progress, taking place according to a model recently proposed, has been observed. Sulphation process is prevented where particular conservation treatments had been applied in the past. New experimental studies can be focussed to understand the specific conditions (measurements of micro-climatic and thermodynamic parameters) and mechanisms for black crusts formation in situ. The problem of the kinetic of the sulphation process of marble, the assessment of black layers formation in the case of different carbonate stone materials and the study of acid attack in presence of surface protecting layers deserve further investigation.

Split off-specular reflection and surface scattering from woven materials

NASA Astrophysics Data System (ADS)

Pont, Sylvia C.; Koenderink, Jan J.

2003-03-01

We measured radiance distributions for black lining cloth and copper gauze using the convenient technique of wrapping the materials around a circular cylinder, irradiating it with a parallel light source and collecting the scattered radiance by a digital camera. One family of parallel threads (weave or weft) was parallel to the cylinder generator. The most salient features for such glossy plane weaves are a splitting up of the reflection peak due to the wavy variations in local slopes of the threads around the cylinders and a surface scattering lobe due to the threads that run along the cylinder. These scattering characteristics are quite different from the (off-)specular peaks and lobes that were found before for random rough specular surfaces. The split off-specular reflection is due to the regular structures in our samples of man-made materials. We derived simple approximations for these reflectance characteristics using geometrical optics.

Callisto False Color

NASA Image and Video Library

1996-09-26

This false color picture of Callisto was taken by NASA's Voyager 2 on July 7, 1979 at a range of 1,094,666 kilometers (677,000 miles) and is centered on 11 degrees N and 171 degrees W. This rendition uses an ultraviolet image for the blue component. Because the surface displays regional contrast in UV, variations in surface materials are apparent. Notice in particular the dark blue haloes which surround bright craters in the eastern hemisphere. The surface of Callisto is the most heavily cratered of the Galilean satellites and resembles ancient heavily cratered terrains on the moon, Mercury and Mars. The bright areas are ejecta thrown out by relatively young impact craters. A large ringed structure, probably an impact basin, is shown in the upper left part of the picture. The color version of this picture was constructed by compositing black and white images taken through the ultraviolet, clear and orange filters. http://photojournal.jpl.nasa.gov/catalog/PIA00457

Synthesis of Pd₃Co₁@Pt/C core-shell catalysts for methanol-tolerant cathodes of direct methanol fuel cells.

PubMed

Aricò, Antonino S; Stassi, Alessandro; D'Urso, Claudia; Sebastián, David; Baglio, Vincenzo

2014-08-18

A composite Pd-based electrocatalyst consisting of a surface layer of Pt (5 wt.%) supported on a core Pd3Co1 alloy (95 wt.%) and dispersed as nanoparticles on a carbon black support (50 wt.% metal content) was prepared by using a sulphite-complex route. The structure, composition, morphology, and surface properties of the catalyst were investigated by XRD, XRF, TEM, XPS and low-energy ion scattering spectroscopy (LE-ISS). The catalyst showed an enrichment of Pt on the surface and a smaller content of Co in the outermost layers. These characteristics allow a decrease the Pt content in direct methanol fuel cell cathode electrodes (from 1 to 0.06 mg cm(-2)) without significant decay in performance, due also to a better tolerance to methanol permeated through the polymer electrolyte membrane. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Metallographic assessment of Al-12Si high-pressure die casting escalator steps.

PubMed

Vander Voort, George Frederic; Suárez-Peña, Beatriz; Asensio-Lozano, Juan

2014-10-01

A microstructural characterization study was performed on high-pressure die cast specimens extracted from escalator steps manufactured from an Al-12 wt.% Si alloy designed for structural applications. Black and white, color light optical imaging and scanning electron microscopy techniques were used to conduct the microstructural analysis. Most regions in the samples studied contained globular-rosette primary α-Al grains surrounded by an Al-Si eutectic aggregate, while primary dendritic α-Al grains were present in the surface layer. This dendritic microstructure was observed in the regions where the melt did not impinge directly on the die surface during cavity filling. Consequently, microstructures in the surface layer were nonuniform. Utilizing physical metallurgy principles, these results were analyzed in terms of the applied pressure and filling velocity during high-pressure die casting. The effects of these parameters on solidification at different locations of the casting are discussed.

Infrared fingerprints of few-layer black phosphorus.

PubMed

Zhang, Guowei; Huang, Shenyang; Chaves, Andrey; Song, Chaoyu; Özçelik, V Ongun; Low, Tony; Yan, Hugen

2017-01-06

Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Although highly desirable, a comprehensive infrared characterization is still lacking. Here we report a systematic infrared study of mechanically exfoliated few-layer black phosphorus, with thickness ranging from 2 to 15 layers and photon energy spanning from 0.25 to 1.36 eV. Each few-layer black phosphorus exhibits a thickness-dependent unique infrared spectrum with a series of absorption resonances, which reveals the underlying electronic structure evolution and serves as its infrared fingerprints. Surprisingly, unexpected absorption features, which are associated with the forbidden optical transitions, have been observed. Furthermore, we unambiguously demonstrate that controllable uniaxial strain can be used as a convenient and effective approach to tune the electronic structure of few-layer black phosphorus. Our study paves the way for black phosphorus applications in infrared photonics and optoelectronics.

Mass inflation followed by Belinskii-Khalatnikov-Lifshitz collapse inside accreting, rotating black holes

NASA Astrophysics Data System (ADS)

Hamilton, Andrew J. S.

2017-10-01

Numerical evidence is presented that the Poisson-Israel mass inflation instability at the inner horizon of an accreting, rotating black hole is generically followed by Belinskii-Khalatnikov-Lifshitz oscillatory collapse to a spacelike singularity. The computation involves following all 6 degrees of freedom of the gravitational field. To simplify the problem, the computation takes as initial conditions the conformally separable solutions of Andrew J. S. Hamilton and Gavin Polhemus [Interior structure of rotating black holes. I. Concise derivation, Phys. Rev. D 84, 124055 (2011), 10.1103/PhysRevD.84.124055] and Andrew J. S. Hamilton [Interior structure of rotating black holes. II. Uncharged black holes, Phys. Rev. D 84, 124056 (2011), 10.1103/PhysRevD.84.124056] just above the inner horizon of a slowly accreting, rotating black hole and integrates the equations inward along single latitudes.

Three-dimensional simulation of gas and dust in Io's Pele plume

NASA Astrophysics Data System (ADS)

McDoniel, William J.; Goldstein, David B.; Varghese, Philip L.; Trafton, Laurence M.

2015-09-01

Io's giant Pele plume rises high above the moon's surface and produces a complex deposition pattern. We use the direct simulation Monte Carlo (DSMC) method to model the flow of SO2 gas and silicate ash from the surface of the lava lake, into the umbrella-shaped canopy of the plume, and eventually onto the surface where the flow leaves black "butterfly wings" surrounded by a large red ring. We show how the geometry of the lava lake, from which the gas is emitted, is responsible for significant asymmetry in the plume and for the shape of the red deposition ring by way of complicated gas-dynamic interactions between parts of the gas flow arising from different areas in the lava lake. We develop a model for gas flow in the immediate vicinity of the lava lake and use it to show that the behavior of ash particles of less than about 2 μm in diameter in the plume is insensitive to the details of how they are introduced into the flow because they are coupled to the gas at low altitudes. We simulate dust particles in the plume to show how particle size determines the distance from the lava lake at which particles deposit on the surface, and we use this dependence to find a size distribution of black dust particles in the plume that provides the best explanation for the observed black fans to the east and west of the lava lake. This best-fit particle size distribution suggests that there may be two distinct mechanisms of black dust creation at Pele, and when two log-normal distributions are fit to our results we obtain a mean particle diameter of 88 nm. We also propose a mechanism by which the condensible plume gas might overlay black dust in areas where black coloration is not observed and compare this to the observed overlaying of Pillanian dust by Pele's red ring.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu Qin, E-mail: zhuqin@fudan.edu.cn; Peng Xizhe, E-mail: xzpeng@fudan.edu.cn

This study examines the impacts of population size, population structure, and consumption level on carbon emissions in China from 1978 to 2008. To this end, we expanded the stochastic impacts by regression on population, affluence, and technology model and used the ridge regression method, which overcomes the negative influences of multicollinearity among independent variables under acceptable bias. Results reveal that changes in consumption level and population structure were the major impact factors, not changes in population size. Consumption level and carbon emissions were highly correlated. In terms of population structure, urbanization, population age, and household size had distinct effects onmore » carbon emissions. Urbanization increased carbon emissions, while the effect of age acted primarily through the expansion of the labor force and consequent overall economic growth. Shrinking household size increased residential consumption, resulting in higher carbon emissions. Households, rather than individuals, are a more reasonable explanation for the demographic impact on carbon emissions. Potential social policies for low carbon development are also discussed. - Highlights: Black-Right-Pointing-Pointer We examine the impacts of population change on carbon emissions in China. Black-Right-Pointing-Pointer We expand the STIRPAT model by containing population structure factors in the model. Black-Right-Pointing-Pointer The population structure includes age structure, urbanization level, and household size. Black-Right-Pointing-Pointer The ridge regression method is used to estimate the model with multicollinearity. Black-Right-Pointing-Pointer The population structure plays a more important role compared with the population size.« less

Black dimensional stones: Geology, technical properties and deposit characterization of the dolerites from Uruguay

NASA Astrophysics Data System (ADS)

Morales Demarco, M.; Oyhantçabal, P.; Stein, K.-J.; Siegesmund, S.

2012-04-01

Dimensional stones with a black color occupy a prominent place on the international market. Uruguayan dolerite dikes of andesitic and andesitic-basaltic composition are mined for commercial blocks of black dimensional stones. A total of 16 dikes of both compositions were studied and samples collected for geochemical and petrographical analysis. Color measurements were performed on different black dimensional stones in order to compare them with the Uruguayan dolerites. Samples of the two commercial varieties (Absolute Black and Moderate Black) were obtained for petrophysical analysis (e.g. density, porosity, uniaxial compressive strength, tensile strength, etc.). Detailed structural analyses were performed in several quarries. Geochemistry and petrography determines the intensity of the black color. When compared with commercial samples from China, Brazil, India and South Africa, among others, the Uruguayan dolerite Absolute Black is the darkest black dimensional stone analyzed. In addition, the petrophysical properties of the Uruguayan dolerites make them one of the highest quality black dimensional stones. Structural analyses show that five joint sets have been recognized: two sub-vertical joints, one horizontal and two diagonal. These joint sets are one of the most important factors that control the deposits, since they control the block size distribution and the amount of waste material.

Mass of a black hole firewall.

PubMed

Abramowicz, M A; Kluźniak, W; Lasota, J-P

2014-03-07

Quantum entanglement of Hawking radiation has been supposed to give rise to a Planck density "firewall" near the event horizon of old black holes. We show that Planck density firewalls are excluded by Einstein's equations for black holes of mass exceeding the Planck mass. We find an upper limit of 1/(8πM) to the surface density of a firewall in a Schwarzschild black hole of mass M, translating for astrophysical black holes into a firewall density smaller than the Planck density by more than 30 orders of magnitude. A strict upper limit on the firewall density is given by the Planck density times the ratio M(Pl)/(8πM).

Nearly extremal apparent horizons in simulations of merging black holes

NASA Astrophysics Data System (ADS)

Lovelace, Geoffrey; Scheel, Mark; Owen, Robert; Giesler, Matthew; Katebi, Reza; Szilagyi, Bela; Chu, Tony; Demos, Nicholas; Hemberger, Daniel; Kidder, Lawrence; Pfeiffer, Harald; Afshari, Nousha; SXS Collaboration

2015-04-01

The spin S of a Kerr black hole is bounded by the surface area A of its apparent horizon: 8 πS <= A . We present recent results (arXiv:1411.7297) for the extremality of apparent horizons for merging, rapidly rotating black holes with equal masses and equal spins aligned with the orbital angular momentum. Measuring the area and (using approximate Killing vectors) the spin on the individual and common apparent horizons, we find that the inequality 8 πS < A is satisfied but is very close to equality on the common apparent horizon at the instant it first appears--even for initial spins as large as S /M2 = 0 . 994 . We compute the smallest value e0 that Booth and Fairhurst's extremality parameter can take for any scaling of the horizon's null normal vectors, concluding that the common horizons are at least moderately close to extremal just after they appear. We construct binary-black-hole initial data with marginally trapped surfaces with 8 πS > A and e0 > 1 , but these surfaces are always surrounded by apparent horizons with 8 πS < A and e0 < 1 .

Dark, Infrared Reflective, and Superhydrophobic Coatings by Waterborne Resins.

PubMed

Zhang, Jing; Lin, Weiqiang; Zhu, Chenxi; Lv, Jian; Zhang, Weicheng; Feng, Jie

2018-05-15

Recently, infrared reflective pigments possessing deep colors have attracted much attention. However, in polluted air, the coatings consisting of such pigments are easily contaminated which abates infrared reflectivity. In this work, black and infrared reflective pigments, fluorine silicon sol and a small number of SiO 2 nanoparticles were introduced into waterborne epoxy resin emulsion and then coated on an aluminum plate. After drying, black coatings with infrared reflective and superhydrophobic (SH) properties were obtained. The average near-infrared (NIR) reflectivity of the coating over wavelength range of 780-2600 nm can reach 68%, which is much larger than that of carbon black coatings and even approaches that of white nano SiO 2 coatings. Under the irradiation of a 275-W infrared lamp (with height 40 cm), the surface temperature of the coating is 63 °C, which is much lower than that of the carbon black coating (90 °C) and only 7 °C higher than that of the white nano SiO 2 coating. Furthermore, the NIR reflective coating exhibited a typical SH property due to its low surface energy and high surface roughness, which may allow for self-cleaning performance in a practical environment, maintaining the coating's NIR reflective property.

Dynamics of marginally trapped surfaces in a binary black hole merger: Growth and approach to equilibrium

NASA Astrophysics Data System (ADS)

Gupta, Anshu; Krishnan, Badri; Nielsen, Alex B.; Schnetter, Erik

2018-04-01

The behavior of quasilocal black hole horizons in a binary black hole merger is studied numerically. We compute the horizon multipole moments, fluxes, and other quantities on black hole horizons throughout the merger. These lead to a better qualitative and quantitative understanding of the coalescence of two black holes: how the final black hole is formed, initially grows, and then settles down to a Kerr black hole. We calculate the rate at which the final black hole approaches equilibrium in a fully nonperturbative situation and identify a time at which the linear ringdown phase begins. Finally, we provide additional support for the conjecture that fields at the horizon are correlated with fields in the wave zone by comparing the in-falling gravitational wave flux at the horizon to the outgoing flux as estimated from the gravitational waveform.

Understanding Chemical Sensitivity and Surface Response in Detecting Trace Levels of Explosives Using Vibrational Sum Frequency Spectroscopy

DTIC Science & Technology

2013-11-04

coated with enamel paint containing black, blue, red, and yellow pigment. The chemical compositions of the pigments are not known, but they show... enamel paint containing black pigment. VSFS signal intensities, ISFG,, has been normalized to constant incident laser power for each spectra. RDX...surface that has been coated with a 1 mm thick layer of enamel paint containing blue pigment. VSFS signal intensities, ISFG,, has been normalized to

Rigidly rotating zero-angular-momentum observer surfaces in the Kerr spacetime

NASA Astrophysics Data System (ADS)

Frolov, Andrei V.; Frolov, Valeri P.

2014-12-01

A stationary observer in the Kerr spacetime has zero angular momentum if their angular velocity ω has a particular value, which depends on the position of the observer. Worldlines of such zero-angular-momentum observers (ZAMOs) with the same value of the angular velocity ω form a three-dimensional surface, which has the property that the Killing vectors generating time translation and rotation are tangent to it. We call such a surface a rigidly rotating ZAMO surface. This definition allows for a natural generalization to the surfaces inside the black hole, where ZAMO trajectories formally become spacelike. A general property of such a surface is that there exist linear combinations of the Killing vectors with constant coefficients which make them orthogonal on it. In this paper we discuss properties of the rigidly rotating ZAMO surfaces both outside and inside the black hole and the relevance of these objects to a couple of interesting physical problems.

Morphology of Nano and Micro Fiber Structures in Ultrafine Particles Filtration

NASA Astrophysics Data System (ADS)

Kimmer, Dusan; Vincent, Ivo; Fenyk, Jan; Petras, David; Zatloukal, Martin; Sambaer, Wannes; Zdimal, Vladimir

2011-07-01

Selected procedures permitting to prepare homogeneous nanofibre structures of the desired morphology by employing a suitable combination of variables during the electrospinning process are presented. A comparison (at the same pressure drop) was made of filtration capabilities of planar polyurethane nanostructures formed exclusively by nanofibres, space polycarbonate nanostructures having bead spacers, structures formed by a combination of polymethyl methacrylate micro- and nanofibres and polypropylene meltblown microstructures, through which ultrafine particles of ammonium sulphate 20-400 nm in size were filtered. The structures studied were described using a new digital image analysis technique based on black and white images obtained by scanning electron microscopy. More voluminous structures modified with distance microspheres and having a greater thickness and mass per square area of the material, i.e. structures possessing better mechanical properties, demanded so much in nanostructures, enable preparation of filters having approximately the same free volume fraction as flat nanofibre filters but an increased effective fibre surface area, changed pore size morphology and, consequently, a higher filter quality.

Entropy in the interior of a higher-dimensional black hole

NASA Astrophysics Data System (ADS)

Yang, Jian-Zhi; Liu, Wen-Biao

2018-07-01

Recently Christodoulou and Rovelli brought out a sensible description for the black hole volume as the largest volume. Later the entropy related to this volume in a 4-dimensional Schwarzschild black hole was investigated, which showed that such entropy is proportional to the surface area of the black hole. We will probe into these issues in the context of higher-dimensional case. It is found that the proportion between this entropy and the Bekenstein-Hawking entropy will go down through dramatic change along with the increase of spacetime dimension.

Physical and Chemical Properties of Seasonal Snow and the Impacts on Albedo in New Hampshire, USA

NASA Astrophysics Data System (ADS)

Adolph, A. C.; Albert, M. R.; Amante, J.; Dibb, J. E.

2014-12-01

Snow albedo is critical to surface energy budgets and thus to the timing of mid-winter and vernal melt events in seasonal snow packs. Timing of these melt events is important in predicting flooding, understanding plant and animal phenology, and the availability of winter recreational activity. The state of New Hampshire experiences large spatial and temporal variability in snow albedo as a result of differences in meteorological conditions, physical snow structure, and chemical impurities in the snow, particularly highly absorptive black carbon (BC) and dust particles. This work focuses on the winters of 2012-2013 and 2013-2014, comparing three intensive study sites. Data collected at these sites include sub-hourly meteorological data, near daily measurements of snow depth, snow density, surface IR temperature, specific surface area (SSA) from contact spectroscopy, and spectrally resolved snow albedo using an ASD FieldSpec4 throughout the winter season. Additionally, snow samples were analyzed for black carbon content and other chemical impurities including Cl-, NO3-, NH4 , K , Na , Mg2+ , Ca2+ and SO42-. For each storm event at the three intensive sites, moisture sources and paths were determined using HYPLIT back trajectory modeling to determine potential sources of black carbon and other impurities in the snow. Storms with terrestrial-based paths across the US Midwest and Canada resulted in higher BC content than storms with ocean-based paths and sources. In addition to the variable storm path between sites and between years, the second year of study was on average 2.5°C colder than the first year, impacting duration of snow cover at each site and the SSA of surface snow which is sensitive to frequency of snow events and relies on cold temperatures to reduce grain metamorphism. Combining an understanding of storm frequency and path with physical and chemical attributes of the snow allows us to investigate snow albedo sensitivities with implications for understanding the impacts of future climate change on snow albedo in the Northeastern US.

Holographic shell model: Stack data structure inside black holes?

NASA Astrophysics Data System (ADS)

Davidson, Aharon

2014-03-01

Rather than tiling the black hole horizon by Planck area patches, we suggest that bits of information inhabit, universally and holographically, the entire black core interior, a bit per a light sheet unit interval of order Planck area difference. The number of distinguishable (tagged by a binary code) configurations, counted within the context of a discrete holographic shell model, is given by the Catalan series. The area entropy formula is recovered, including Cardy's universal logarithmic correction, and the equipartition of mass per degree of freedom is proven. The black hole information storage resembles, in the count procedure, the so-called stack data structure.

Event-horizon-scale structure in the supermassive black hole candidate at the Galactic Centre.

PubMed

Doeleman, Sheperd S; Weintroub, Jonathan; Rogers, Alan E E; Plambeck, Richard; Freund, Robert; Tilanus, Remo P J; Friberg, Per; Ziurys, Lucy M; Moran, James M; Corey, Brian; Young, Ken H; Smythe, Daniel L; Titus, Michael; Marrone, Daniel P; Cappallo, Roger J; Bock, Douglas C-J; Bower, Geoffrey C; Chamberlin, Richard; Davis, Gary R; Krichbaum, Thomas P; Lamb, James; Maness, Holly; Niell, Arthur E; Roy, Alan; Strittmatter, Peter; Werthimer, Daniel; Whitney, Alan R; Woody, David

2008-09-04

The cores of most galaxies are thought to harbour supermassive black holes, which power galactic nuclei by converting the gravitational energy of accreting matter into radiation. Sagittarius A* (Sgr A*), the compact source of radio, infrared and X-ray emission at the centre of the Milky Way, is the closest example of this phenomenon, with an estimated black hole mass that is 4,000,000 times that of the Sun. A long-standing astronomical goal is to resolve structures in the innermost accretion flow surrounding Sgr A*, where strong gravitational fields will distort the appearance of radiation emitted near the black hole. Radio observations at wavelengths of 3.5 mm and 7 mm have detected intrinsic structure in Sgr A*, but the spatial resolution of observations at these wavelengths is limited by interstellar scattering. Here we report observations at a wavelength of 1.3 mm that set a size of 37(+16)(-10) microarcseconds on the intrinsic diameter of Sgr A*. This is less than the expected apparent size of the event horizon of the presumed black hole, suggesting that the bulk of Sgr A* emission may not be centred on the black hole, but arises in the surrounding accretion flow.

Echoes from the abyss: Tentative evidence for Planck-scale structure at black hole horizons

NASA Astrophysics Data System (ADS)

Abedi, Jahed; Dykaar, Hannah; Afshordi, Niayesh

2017-10-01

In classical general relativity (GR), an observer falling into an astrophysical black hole is not expected to experience anything dramatic as she crosses the event horizon. However, tentative resolutions to problems in quantum gravity, such as the cosmological constant problem, or the black hole information paradox, invoke significant departures from classicality in the vicinity of the horizon. It was recently pointed out that such near-horizon structures can lead to late-time echoes in the black hole merger gravitational wave signals that are otherwise indistinguishable from GR. We search for observational signatures of these echoes in the gravitational wave data released by the advanced Laser Interferometer Gravitational-Wave Observatory (LIGO), following the three black hole merger events GW150914, GW151226, and LVT151012. In particular, we look for repeating damped echoes with time delays of 8 M log M (+spin corrections, in Planck units), corresponding to Planck-scale departures from GR near their respective horizons. Accounting for the "look elsewhere" effect due to uncertainty in the echo template, we find tentative evidence for Planck-scale structure near black hole horizons at false detection probability of 1% (corresponding to 2.5 σ

The surface modification of clay particles by RF plasma technique

NASA Astrophysics Data System (ADS)

Lee, Sang-Keol

In this study, the surface coatings of ball clay, organoclay and exfoliated clay prepared by sol-gel process were done by RF plasma polymerization to improve the surface activity of the clay filler. Characterization of the above plasma-treated clays has been carried out by various techniques. The effects of plasma-treated clays as substitute of carbon black in styrene-butadiene rubber (SBR) and ethylene-propylene-diene monomer (EPDM) on the curing and mechanical properties were investigated. After plasma treatment, the tensile properties of organo and exfoliated clay were not unsatisfactory to that of carbon black filler system. Moreover, only 10 phr filler loading of plasma-treated organoclay in EPDM vulcanizates showed better results than 40 phr filler loading of carbon black in EPDM vulcanizates. The main objective of this study was to verify the applicability of the plasma technique for modifying clay surfaces for their use in the tire manufacturing industry. Another purpose was to reveal the advantage of the plasma technique used to obtain modified-clay and improved properties that those materials can display.

Black-hole Merger Simulations for LISA Science

NASA Technical Reports Server (NTRS)

Kelly, Bernard J.; Baker, John G.; vanMeter, James R.; Boggs, William D.; Centrella, Joan M.; McWilliams, Sean T.

2009-01-01

The strongest expected sources of gravitational waves in the LISA band are the mergers of massive black holes. LISA may observe these systems to high redshift, z>10, to uncover details of the origin of massive black holes, and of the relationship between black holes and their host structures, and structure formation itself. These signals arise from the final stage in the development of a massive black-hole binary emitting strong gravitational radiation that accelerates the system's inspiral toward merger. The strongest part of the signal, at the point of merger, carries much information about the system and provides a probe of extreme gravitational physics. Theoretical predictions for these merger signals rely on supercomputer simulations to solve Einstein's equations. We discuss recent numerical results and their impact on LISA science expectations.

Reconciling Epidemiology and Social Justice in the Public Health Discourse Around the Sexual Networks of Black Men Who Have Sex With Men

PubMed Central

Smith, Justin C.; Brown, Andre L.; Malebranche, David J.

2016-01-01

Several studies have implicated the sexual networks of Black men who have sex with men (MSM) as facilitating disproportionally high rates of new HIV infections within this community. Although structural disparities place these networks at heightened risk for infection, HIV prevention science continues to describe networks as the cause for HIV disparities, rather than an effect of structures that pattern infection. We explore the historical relationship between public health and Black MSM, arguing that the current articulation of Black MSM networks is too often incomplete and counterproductive. Public health can offer a counternarrative that reconciles epidemiology with the social justice that informs our discipline, and that is required for an effective response to the epidemic among Black MSM. PMID:26890175

Educating in a "Regressive Era": Exploring the Race-Full Ideological Standpoint of Black Women Teachers

ERIC Educational Resources Information Center

Watson, Wanda

2017-01-01

The purpose of this 2-year phenomenological study was to build on the legacy of Black women educators before and after "Brown v. Board of Education" and examine the ideological standpoint of early career Black women educators from the millennial generation. Semi-structured interviews were conducted with three Black women educators…

The Black Urban Population of the Pre-civil War South

ERIC Educational Resources Information Center

Wilkie, Jane Riblett

1976-01-01

Examines the urbanization of blacks in the slave states from 1790 to 1860. Changes in the geographic distribution and demographic structure of the black urban population provide new evidence to evaluate the causes of the decline of urban blacks and reveal the likelihood of a disproportionate incidence of incomplete families for both slave and free…

Bentonite deposits of the northern Black Hills district, Wyoming, Montana, and South Dakota

USGS Publications Warehouse

Knechtel, Maxwell M.; Patterson, Sam H.

1962-01-01

The northern Black Hills bentonite mining district includes parts of Crook County, Wyo., Carter County, Mont., and Butte County, S. Dak. Within this district, many beds of bentonite occur interspersed with sedimentary strata of Cretaceous age that have an average total thickness of about 3,000 feet and consist chiefly of marine shale, marl, and argillaceous sandstone. The bentonite beds occur in formations ranging upward from the Newcastle sandstone to the lower part of the Mitten black shale member of the Pierre shale. Tertiary (?) and Quaternary deposits of gravel, sand, and silt are present on extensive terraces, and deposits of such materials also extend along stream courses in all parts of the district. The overall geologic structure of the district is that of a broad northwestward- plunging anticline, in which the strata dip gently toward the northeast, north, and northwest. The overall structure is interrupted, however, by several subordinate folds which bring the bentonite beds to the surface repeatedly, so that large resources of bentonite are present under light overburden. The northern Black Hills district is an important source of commercial gel-forming sodium-type bentonite. During the period 1941-56 more than 5 million tons of raw bentonite was mined, most of which came from the Clay Spur bed near the top of the Mowry shale; a few thousand tons was mined from bed A in the Newcastle sandstone. Calcium-type bentonite occurs in bed B in the Mowry shale and in bed I at the base of the Mitten black shale member. Seven other beds are sufficiently thick and continuous to warrant consideration as prospective sources of bentonite for industrial use. Most of the bentonite produced is sold for use (a) as an ingredient of drilling mud; (b) for preparing metallurgical molding sand of superior dry strength; and (c) for the bonding material used in pelletizing taconite iron ore of the Lake Superior region. The results of drilling-mud and foundry-sand bonding-clay tests of several hundred samples, as well as analyses of selected samples, chiefly by X-ray, differential thermal, base exchange and spectrographic methods, are included in this report.

Actuators based on polyurethanes with different types of polyol

NASA Astrophysics Data System (ADS)

Lim, Hyun-Ok; Bark, Geong-Mi; Jo, Nam-Ju

2007-07-01

This study dealt with the electrostrictive responses of polyurethane (PU) actuators with different microphase separation structure, which was a promising candidate for a material used in polymer actuators. In order to construct PUs with different higher-order structure, we synthesized PUs with different diols; poly(neopentyl glycol adipate) (PNAD), poly(tetramethylene glycol) (PTMG), and poly(dimethyl siloxnae) (PDMS). Synthesized PU was characterized by FT-IR spectroscopy and GPC. Thermal analysis and mechanical properties of PU films were carried out with DSC and UTM, respectively. And PU actuator was formed in a monomorph type which made by carbon black electrodes on the both surfaces of PU film by spin coating method. Actuation behavior was mainly influenced on microphase separation structure and mechanical property of PU. In result, PU actuator with PNAD, polyester urethane, had the largest field-induced displacement.

Impact of winter cooling on the northern part of the Black Sea.

NASA Astrophysics Data System (ADS)

Savchenko, Anatolii

2016-07-01

Climate change in the future may have a negative impact on many countries due to the increasing surface temperature and sea level rise. Probably, unprecedented largest positive trend of surface temperature, which observed since the mid XX century, has associated with increasing human activities around the world. Moreover, this warming will continue in this century, and at the end of the XXI century will be 2 - 5 ºC. Thus, investigation and monitoring of current climate are very important and necessary tasks. Regional model data (downscaling) and satellite data are used, because of underdeveloped network of meteorological stations in the northern part of the Black Sea region. Experiment of downscaling was carried out for the Black Sea region with a high spatial resolution of 0.22° x 0.22° for 1958 - 2007(daily values). For the Black Sea were also used satellite data of sea surface temperature(SST) from MyOcean-2 Project, which CNR(Rome) has reprocessed Pathfinder V5.2 (PFV52) AVHRR data over period 1981 - 2012 with daily gap-free maps (L4) at the original PFV52 resolution at 0.04° x 0.04°. Correlation between satellite SST and surface temperature from regional model climate are amounted 0,99. Thus, surface temperature of model and satellite data for the Black Sea is much correlated between yourself. The following integral characteristics of the Black Sea are referred to the area of sea limited by the 44 - 47º N and 28 - 34º E. Maximum cooling of the north-western part of the Black Sea in winter is occurs after invasion of cold air across the northern border of the basin. In addition, this water area is also interesting in the presence of her huge oil and gas reserves, as well as the construction of liquefied gas (crude oil) terminals. The maximum values of total heat flux (sensible + latent heat fluxes= Q) corresponding to the minimum values of SST are observed during the periods of the negative phase of the NAO. Besides, fluxes with extreme days P (Q) = 95% (the number of which is 5% of the total number of winter days) contribute ≈ 16 - 18% of the total heat flux during the winter, and with P (Q) = 90% - approximately 30%. Typical synoptic situation of extreme winter cooling P (Q) = 95% is presence of anticyclone in the district of Carpathian Mountains. North-easterly flow of cold air at high velocities near-surface wind leads to extreme total heat flux and decreasing SST. Satellite images of clouds well illustrate such cases as, for example, cold air invasion to the Black Sea area on January 23, 2006 (Satellite TERRA). Because of increase of risk associated with climate change, this topic is particularly relevant for the marine area, which is subjected to strong weathering during extreme events in winter. The monitoring of this area will allow reducing the damage from extreme natural events in the future.

Can mixed star-plus-wormhole systems mimic black holes?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dzhunushaliev, Vladimir; Folomeev, Vladimir; Kleihaus, Burkhard

We consider mixed strongly gravitating configurations consisting of a wormhole threaded by two types of ordinary matter. For such systems, the possibility of obtaining static spherically symmetric solutions describing compact massive central objects enclosed by high-redshift surfaces (black-hole-like configurations) is studied. Using the standard thin accretion disk model, we exhibit potentially observable differences allowing to distinguish the mixed systems from ordinary black holes with the same masses.

Evaluation of black crust formation and soiling process on historical buildings from the Bilbao metropolitan area (north of Spain) using SEM-EDS and Raman microscopy.

PubMed

Calparsoro, Estefanía; Maguregui, Maite; Giakoumaki, Anastasia; Morillas, Héctor; Madariaga, Juan Manuel

2017-04-01

In the present work, several building materials suffering from black crusts and soiled surfaces were evaluated by scanning electron microscopy energy dispersive X-ray spectrometry (SEM-EDS) and micro-Raman spectroscopy. The goal was to examine the elemental and molecular composition, the distribution on the samples, and the morphology of endogenous and exogenous compounds on those black crusts and soiled surfaces. The black crusts were deposited over different building materials such as limestone, sandstone, and brick that constitute a small construction called "malacate" as well as over a limestone substrate of a cemetery gate. Both constructions are dated back to the beginning of the twentieth century. The samples of soiling were taken from the façade of a building constructed in the 1980s. The analytical evaluation allowed in a first stage the determination of the composition and the observation of the morphology of soiling and black crusts. In addition, the evaluation of the compositions of the soiling and black crusts of different grade and formation allowed the assessment of the main weathering phenomena that the buildings have suffered, which were found to be sulfate impact, marine aerosol impact, depositions of metallic particles, crustal particulate matter depositions, carbonaceous particles, biodeterioration, and vandalism.

Evaluation and improvement of sticky traps as monitoring tools for Glossina austeni and G. brevipalpis (Diptera: Glossinidae) in north-eastern KwaZulu-Natal, South Africa.

PubMed

Green, K Kappmeier; Venter, G J

2007-12-01

The attractiveness of various colours, colour combinations and sizes of sticky traps of the 3-dimensional trap (3DT), cross-shaped target (XT), rectangular screen (RT) and monopanels were evaluated for their efficacy to capture Glossina austeni Newstead and G. brevipalpis Newstead in north-eastern KwaZulu-Natal, South Africa. The 3-dimensional shapes of the XT and 3DT in light blue (l.blue) and white were significantly (ca. 3.1-6.9 times) better than the RT for G. austeni. On bicoloured XTs, G. austeni landed preferentially on electric blue (e.blue) (58%) and black (63%) surfaces when used with white; while for G. brevipalpis, significantly more landed on e.blue (60-66%) surfaces when used with l.blue, black or white surfaces. Increased trap size increased the catches of G. brevipalpis females and both sexes of G. austeni significantly. Temoocid and polybutene sticky materials were equally effective and remained durable for 2-3 weeks. The glossy shine of trap surfaces did not have any significant effect on the attraction and landing responses of the two species. The overall trap efficiency of the e.blue/l.blue XT was 23% for G. brevipalpis and 28% for G. austeni, and that of the e.blue/black XT was 16% for G. brevipalpis and 51% for G. austeni. Larger monopanels, painted e.blue/black on both sides, increased the catches of G. austeni females significantly by up to four times compared to the standard e.blue/black XT. This monopanel would be recommended for use as a simple and cost effective survey tool for both species in South Africa.

Characterisation of Ga-coated and Ga-brazed aluminium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ferchaud, E.; Christien, F., E-mail: frederic.christien@univ-nantes.fr; Barnier, V.

This work is devoted to the brazing of aluminium using liquid gallium. Gallium was deposited on aluminium samples at {approx} 50 Degree-Sign C using a liquid gallium 'polishing' technique. Brazing was undertaken for 30 min at 500 Degree-Sign C in air. EDS (Energy Dispersive X-ray Spectroscopy) and AES (Auger Electron Spectroscopy) characterisation of Ga-coated samples has shown that the Ga surface layer thickness is of ten (or a few tens of) nanometres. Furthermore, aluminium oxide layer (Al{sub 2}O{sub 3}) was shown to be 'descaled' during Ga deposition, which ensures good conditions for further brazing. Cross-section examination of Ga-coated samples showsmore » that liquid gallium penetrates into the aluminium grain boundaries during deposition. The thickness of the grain boundary gallium film was measured using an original EDS technique and is found to be of a few tens of nanometres. The depth of gallium grain boundary penetration is about 300 {mu}m at the deposition temperature. The fracture stress of the brazed joints was measured from tensile tests and was determined to be 33 MPa. Cross-section examination of brazed joints shows that gallium has fully dissolved into the bulk and that the joint is really autogenous. - Highlights: Black-Right-Pointing-Pointer Aluminium can be brazed using liquid gallium deposited by a 'polishing' technique. Black-Right-Pointing-Pointer The aluminium oxide layer is 'descaled' during liquid Ga 'polishing' deposition. Black-Right-Pointing-Pointer EDS can be used for determination of surface and grain boundary Ga film thickness. Black-Right-Pointing-Pointer The surface and grain boundary Ga film thickness is of a few tens of nm. Black-Right-Pointing-Pointer Surface and grain boundary gallium dissolves in the bulk during brazing.« less

Coccolithophore assemblage response to Black Sea Water inflow into the North Aegean Sea (NE Mediterranean)

NASA Astrophysics Data System (ADS)

Karatsolis, B.-Th.; Triantaphyllou, M. V.; Dimiza, M. D.; Malinverno, E.; Lagaria, A.; Mara, P.; Archontikis, O.; Psarra, S.

2017-10-01

This study aims to presents the species composition of living coccolithophore communities in the NE Aegean Sea, investigating their spatial and temporal variations along a north-south transect in the area receiving the inflowing surface Black Sea Water (BSW) over the deeper Levantine Water (LW) layer. Coccolithophores in the area were relatively diverse and a total of 95 species over 3 sampling periods studied were recognized using Scanning Electron Microscope (SEM) techniques. R-mode hierarchical cluster analysis distinguished two coccolithophore Groups (I, IIa, IIb, IIc) with different ecological preferences. Emiliania huxleyi was the most abundant species of Group I, whereas Syracosphaera spp., Rhabdosphaera spp. and holococcolithophores were prevailing in the highly diversified Group II assemblages. Biometric analysis conducted on E. huxleyi coccoliths from Aegean water column and Black Sea sediment trap samples, indicated that during autumn, NE Aegean specimens in samples under BSW influence were featured by unimodal distribution concerning the coccolith relative tube width, with values similar to those provided by the Black Sea specimens. In early spring, coccoliths in the stations with increased BSW influx displayed a bimodal pattern of relative tube width with smaller values found mostly in the surface layers, while the distribution became again unimodal and dominated by larger values within the deeper LW layers. In the summer period, the typical LW holococcolithophore species (Group II) presented low cell numbers in the surface layer (<20 m), which is their usual ecological niche in the Aegean Sea, compared to greater depths, therefore marking LW mass flowing beneath the less saline BSW surface lid. In contrast to Black Sea early summer bloom conditions, E. huxleyi was almost absent in the NE Aegean during the summer sampling period.

Constructing Black Titania with Unique Nanocage Structure for Solar Desalination.

PubMed

Zhu, Guilian; Xu, Jijian; Zhao, Wenli; Huang, Fuqiang

2016-11-23

Solar desalination driven by solar radiation as heat source is freely available, however, hindered by low efficiency. Herein, we first design and synthesize black titania with a unique nanocage structure simultaneously with light trapping effect to enhance light harvesting, well-crystallized interconnected nanograins to accelerate the heat transfer from titania to water and with opening mesopores (4-10 nm) to facilitate the permeation of water vapor. Furthermore, the coated self-floating black titania nanocages film localizes the temperature increase at the water-air interface rather than uniformly heating the bulk of the water, which ultimately results in a solar-thermal conversion efficiency as high as 70.9% under a simulated solar light with an intensity of 1 kW m -2 (1 sun). This finding should inspire new black materials with rationally designed structure for superior solar desalination performance.

Biotic and abiotic correlates with black bullhead population characteristics in Nebraska sandhill lakes

USGS Publications Warehouse

Phelps, Q.E.; Ward, M.J.; Paukert, C.P.; Chipps, S.R.; Willis, D.W.

2005-01-01

We explored relationships among black bullhead (Ameiurus melas) population characteristics and physicochemical attributes in shallow lakes and quantified relationships between population characteristics of black bullhead and sport fishes. Lake characteristics and fisheries survey data were collected from the Sandhills region of northcentral Nebraska from May through June, 1998 and 1999. Relative abundance of black bullheads was inversely related to proportional stock density (r=-0.672, df=15, P=0.004); however, neither relative weight nor growth was significantly (P ??? 0.20) related to black bullhead relative abundance. Population characteristics of common panfish species such as bluegill (Lepomis macrochirus), green sunfish (L. cyanellus), pumpkinseed (L. gibbosus), and yellow perch (Perca flavescens) were not correlated with black bullhead relative abundance or size structure. Rather, proportional stock density (r=0.655, df=10, P=0.029) and growth (r=0.59, df=11, P=0.04) of black bullhead were positively related to relative abundance of largemouth bass (Micropterus salmoides). Similarly, black bullhead relative abundance was inversely related to largemouth bass size structure (r=-0.51, df=14, P= 0.05). Black bullhead mean length at age 3 was positively related to total phosphorous concentration (r=0.65, df=16, P=0.004), and bullhead relative abundance was positively related to shoreline development index (r=0.46, df=22, P=0.03). Population characteristics of black bullhead appeared to have little influence on panfish communities. Rather, black bullhead abundance, predator density, and lake productivity exhibited stronger relationships with black bullhead population characteristics.

Nanoporous Au: An experimental study on the porosity of dealloyed AuAg leafs

NASA Astrophysics Data System (ADS)

Grillo, R.; Torrisi, V.; Ruffino, F.

2016-12-01

We present a study on the fraction of porosity for dealloyed nanoporous Au leafs. Nanoporous Au is attracting great scientific interest due to its peculiar plasmonic properties and the high exposed surface (∼10 m2/g). As examples, it was used in prototypes of chemical and biological devices. However, the maximization of the devices sensitivity is subjected to the maximization of the exposed surface by the nanoporous Au, i. e. maximization of the porosity fraction. So, we report on the analyses of the porosity fraction in nanoporous Au leafs as a function of the fabrication process parameters. We dealloyed 60 μm-thick Au23Ag77 at.% leafs and we show that: a) for dealloying time till to 6 h, only a 450 nm-thick surface layer of the leafs assumes a nanoporous structure with a porosity fraction of 32%. For a dealloying time of 20 h the leafs result fragmented in small black pieces with a porosity fraction increased to 60%. b) After 600 °C-30 minutes annealing of the previous samples, the nanopores disappear due to the Au/residual Ag inter-diffusion. c) After a second dealloying process on the previously annealed samples, the surface nanoporous structure is, again, obtained with the porosity fraction increased to 50%.

Why Black Officers Still Fail

DTIC Science & Technology

2010-03-01

perspective with regard to Black officer professional mobility . More poignantly stated, black officers feel as though there are structural barriers to...still failing. Dr. Darlene Iskra described the phenomenon whereby some groups fail to achieve upward professional mobility in the military as a

Process for the production of star-tracking reticles

NASA Technical Reports Server (NTRS)

Toft, A. R.; Smith, W. O.

1974-01-01

Reticles designed with quartz bases are masked with desired pattern and then are coated with highly adherent layers of chromium, chromium silver alloy, silver, copper, and black chromium (mixture of chromium and chromium oxides). Black chromium final layer produces required nonreflective surface.

7 CFR 51.1318 - Black end.

Code of Federal Regulations, 2011 CFR

2011-01-01

... Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards, Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE REGULATIONS AND STANDARDS UNDER THE AGRICULTURAL MARKETING ACT OF 1946... green color around the calyx, or black spots usually occurring on the one-third of the surface nearest...

Post-formation copper-nitrogen species on carbon black: their chemical structures and active sites for oxygen reduction reaction.

PubMed

Xie, Xin; Liu, Jingjun; Li, Tuanfeng; Song, Ye; Wang, Feng

2018-05-16

Note that 3d transition metal and nitrogen co-doped carbon materials (TM-N-C) are considered as the most promising next-generation electrocatalysts alternative to precious Pt for oxygen reduction reaction (ORR). Herein, we have fabricated a Cu-N-C catalyst through directly grafting copper-nitrogen complexes composed by cuprous chloride and ammonia water onto the surface of an industrial carbon black at 500℃. In an alkaline environment, the synthesized catalyst exhibits excellent ORR catalytic activity, which is comparable to the state-of-the-art Pt/C catalyst but far exceeding that obtained by the original carbon. Moreover, the catalyst displays much better stability than the Pt/C. The enhanced ORR performance is proven to originate from the post-formation Cu(I)-N2 and Cu(II)-N4 sites at the carbon surface, as evidenced by X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS). The possible ORR process catalyzed by these Cu-Nx species is discussed at atomic level. This work provides a simple and fast synthesis strategy for efficient TM-N-C catalysts on a large scale for energy storage and conversion systems. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Nanofabrication of ultra-low reflectivity black silicon surfaces and devices (Presentation Recording)

NASA Astrophysics Data System (ADS)

White, Victor E.; Yee, Karl Y.; Balasubramanian, Kunjithapatham; Echternach, Pierre M.; Muller, Richard E.; Dickie, Matthew R.; Cady, Eric; Ryan, Daniel J.; Eastwood, Michael; van Gorp, Byron; Riggs, A. J. Eldorado; Zimmerman, Niel; Kasdin, N. Jeremy

2015-08-01

Optical devices with features exhibiting ultra low reflectivity on the order of 10-7 specular reflectance in the visible spectrum are required for coronagraph instruments and some spectrometers employed in space research. Nanofabrication technologies have been developed to produce such devices with various shapes and feature dimensions to meet these requirements. Infrared reflection is also suppressed significantly with chosen wafers and processes. Particularly, devices with very high (>0.9) and very low reflectivity (<10-7) on adjacent areas have been fabricated and characterized. Significantly increased surface area due to the long needle like nano structures also provides some unique applications in other technology areas. We present some of the approaches, challenges and achieved results in producing and characterizing such devices currently employed in laboratory testbeds and instruments.

The effect of surface colour on the formation of marine micro and macrofouling communities.

PubMed

Dobretsov, Sergey; Abed, Raeid M M; Voolstra, Christian R

2013-01-01

The effect of substratum colour on the formation of micro- and macro fouling communities was investigated. Acrylic tiles, painted either black or white were covered with transparent sheets in order to ensure similar surface properties. All substrata were exposed to biofouling at 1 m depth for 40 d in the Marina Bandar al Rowdha (Muscat, Sea of Oman). Studies were conducted in 2010 over a time course of 5, 10 and 20 d, and in 2012 samples were collected at 7, 14 and 21 d. The densities of bacteria on the black and white substrata were similar with the exception of day 10, when the black substrata had a higher abundance than white ones. Pyrosequencing via 454 of 16S rRNA genes of bacteria from white and black substrata revealed that Alphaproteobacteria and Firmicutes were the dominant groups. SIMPER analysis demonstrated that bacterial phylotypes (uncultured Gammaproteobacteria, Actibacter, Gaetbulicola, Thalassobius and Silicibacter) and the diatoms (Navicula directa, Navicula sp. and Nitzschia sp.) contributed to the dissimilarities between communities developed on white and black substrata. At day 20, the highest amount of chlorophyll a was recorded in biofilms developed on black substrata. SIMPER analysis showed that Folliculina sp., Ulva sp. and Balanus amphitrite were the major macro fouling species that contributed to the dissimilarities between the communities formed on white and black substrata. Higher densities of these species were observed on black tiles. The results emphasise the effect of substratum colour on the formation of micro and macro fouling communities; substratum colour should to be taken into account in future studies.

Porous Structures in Stacked, Crumpled and Pillared Graphene-Based 3D Materials.

PubMed

Guo, Fei; Creighton, Megan; Chen, Yantao; Hurt, Robert; Külaots, Indrek

2014-01-01

Graphene, an atomically thin material with the theoretical surface area of 2600 m 2 g -1 , has great potential in the fields of catalysis, separation, and gas storage if properly assembled into functional 3D materials at large scale. In ideal non-interacting ensembles of non-porous multilayer graphene plates, the surface area can be adequately estimated using the simple geometric law ~ 2600 m 2 g -1 /N, where N is the number of graphene sheets per plate. Some processing operations, however, lead to secondary plate-plate stacking, folding, crumpling or pillaring, which give rise to more complex structures. Here we show that bulk samples of multilayer graphene plates stack in an irregular fashion that preserves the 2600/N surface area and creates regular slot-like pores with sizes that are multiples of the unit plate thickness. In contrast, graphene oxide deposits into films with massive area loss (2600 to 40 m 2 g -1 ) due to nearly perfect alignment and stacking during the drying process. Pillaring graphene oxide sheets by co-deposition of colloidal-phase particle-based spacers has the potential to partially restore the large monolayer surface. Surface areas as high as 1000 m 2 g -1 are demonstrated here through colloidal-phase deposition of graphene oxide with water-dispersible aryl-sulfonated ultrafine carbon black as a pillaring agent.

Thermal evaporation and condensation synthesis of metallic Zn layered polyhedral microparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khan, Waheed S.; Cao, Chuanbao, E-mail: cbcao@bit.edu.cn; Usman, Zahid

2011-12-15

Highlights: Black-Right-Pointing-Pointer Zn polyhedral microparticles prepared by thermal evaporation and condensation route. Black-Right-Pointing-Pointer Vapour-solid process based growth model governs the formation of Zn microparticles. Black-Right-Pointing-Pointer A strong PL emission band is observed at 369 nm in UV region. Black-Right-Pointing-Pointer Radiative recombination of electrons in the s, p conduction band and the holes in the d bands causes this emission. -- Abstract: Metallic zinc layered polyhedral microparticles have been fabricated by thermal evaporation and condensation technique using zinc as precursor at 750 Degree-Sign C for 120 min and NH{sub 3} as a carrier gas. The zinc polyhedral microparticles with oblate sphericalmore » shape are observed to be 2-9 {mu}m in diameter along major axes and 1-7 {mu}m in thickness along minor axes. The structural, compositional and morphological characterizations were performed by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and selected area electron diffraction (SAED). A vapour-solid (VS) mechanism based growth model has been proposed for the formation of Zn microparticles. Room temperature photoluminescence (PL) emission spectrum of the product exhibited a strong emission band at 369 nm attributed to the radiative recombination of electrons in the s, p conduction band near Fermi surface and the holes in the d bands generated by the optical excitation.« less

Laser irradiation in water for the novel, scalable synthesis of black TiOx photocatalyst for environmental remediation

PubMed Central

Zimbone, Massimo; Boutinguiza, Mohamed; Privitera, Vittorio; Grimaldi, Maria Grazia

2017-01-01

Since 1970, TiO2 photocatalysis has been considered a possible alternative for sustainable water treatment. This is due to its material stability, abundance, nontoxicity and high activity. Unfortunately, its wide band gap (≈3.2 eV) in the UV portion of the spectrum makes it inefficient under solar illumination. Recently, so-called “black TiO2” has been proposed as a candidate to overcome this issue. However, typical synthesis routes require high hydrogen pressure and long annealing treatments. In this work, we present an industrially scalable synthesis of TiO2-based material based on laser irradiation. The resulting black TiOx shows a high activity and adsorbs visible radiation, overcoming the main concerns related to the use of TiO2 under solar irradiation. We employed a commercial high repetition rate green laser in order to synthesize a black TiOx layer and we demonstrate the scalability of the present methodology. The photocatalyst is composed of a nanostructured titanate film (TiOx) synthetized on a titanium foil, directly back-contacted to a layer of Pt nanoparticles (PtNps) deposited on the rear side of the same foil. The result is a monolithic photochemical diode with a stacked, layered structure (TiOx/Ti/PtNps). The resulting high photo-efficiency is ascribed to both the scavenging of electrons by Pt nanoparticles and the presence of trap surface states for holes in an amorphous hydrogenated TiOx layer. PMID:28243557

Fracture morphologies of carbon-black-loaded SBR (styrene-butadiene rubber) subjected to low-cycle, high-stress fatigue. [Styrene-butadiene rubber

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goldberg, A.; Lesuer, D.R.; Patt, J.

Experimental results, together with an analytical model, related to the loss in tensile strength of styrene-butadiene rubber (SBR) loaded with carbon black (CB) that had been subjected to low-cycle, high-stress fatigue tests were presented in a prior paper. The drop in tensile strength relative to that of a virgin sample was considered to be a measure of damage induced during the fatigue test. The present paper is a continuation of this study dealing with the morphological interpretations of the fractured surfaces, whereby the cyclic-tearing behavior, resulting in the damage, is related to the test and material parameters. It was foundmore » that failure is almost always initiated in the bulk of a sample at a material flaw. The size and definition of a flaw increase with an increase in carbon-black loading. Initiation flaw sites are enveloped by fan-shaped or penny-shaped regions which develop during cycling. The size and morphology of a fatigue-tear region appears to be independent of the fatigue load or the extent of the damage (strength loss). By contrast, either an increase in cycling load or an increase in damage at constant load increases the definition of the fatigue-region morphology for all formulations of carbon-black. On the finest scale, the morphology can be described in terms of tearing of individual groups of rubber strands, collapsing to form a cell-like structure. 18 refs., 13 figs.« less

Implementation of Black Sea numerical model based on NEMO and 3DVAR data assimilation scheme for operational forecasting

NASA Astrophysics Data System (ADS)

Ciliberti, Stefania Angela; Peneva, Elisaveta; Storto, Andrea; Rostislav, Kandilarov; Lecci, Rita; Yang, Chunxue; Coppini, Giovanni; Masina, Simona; Pinardi, Nadia

2016-04-01

This study describes a new model implementation for the Black Sea, which uses data assimilation, towards operational forecasting, based on NEMO (Nucleus for European Modelling of the Ocean, Madec et al., 2012). The Black Sea domain is resolved with 1/27°×1/36° horizontal resolution (~3 km) and 31 z-levels with partial steps based on the GEBCO bathymetry data (Grayek et al., 2010). The model is forced by momentum, water and heat fluxes interactively computed by bulk formulae using high resolution atmospheric forcing provided by the European Centre for Medium-Range Forecast (ECMWF). The initial condition is calculated from long-term climatological temperature and salinity 3D fields. Precipitation field over the basin has been computed from the climatological GPCP rainfall monthly data (Adler et al., 2003; Huffman et al., 2009), while the evaporation is derived from the latent heat flux. The climatological monthly mean runoff of the major rivers in the Black Sea is computed using the hydrological dataset provided by SESAME project (Ludvig et al., 2009). The exchange with Mediterranean Sea through the Bosporus Straits is represented by a surface boundary condition taking into account the barotropic transport calculated to balance the fresh water fluxes on monthly bases (Stanev and Beckers, 1999, Peneva et al., 2001). A multi-annual run 2011-2015 has been completed in order to describe the main characteristics of the Black Sea circulation dynamics and thermohaline structure and the numerical results have been validated using in-situ (ARGO) and satellite (SST, SLA) data. The Black Sea model represents also the core of the new Black Sea Forecasting System, implemented at CMCC operationally since January 2016, which produces at daily frequency 10-day forecasts, 3-days analyses and 1-day simulation. Once a week, the system is run 15-day in the past in analysis mode to compute the new optimal initial condition for the forecast cycle. The assimilation is performed by a three-dimensional variational data assimilation system (3DVAR) that ingests all hydrographic profiles (mostly ARGO floats), sea level anomaly data from available altimetry missions and sea surface temperature measurements retrieved from infrared sensors on-board polar-orbiting satellites (Storto et al., 2014). All the data are taken from the CMEMS catalogue. The 3DVAR system implements a recursive filter to model horizontal correlations while vertical covariances are formulated through multivariate empirical orthogonal functions. The system produces hourly and daily means for temperature, salinity, currents and sea surface height with online validation against satellite observations for SST and in-situ ARGO measurements. Grayek, S., Stanev, E., Kandilarov, R., 2010. On the response of Black Sea level to external forcing: altimeter data and numerical modelling. Ocean Dyn. 60, 123-140. Ludwig W., E. Dumont, M. Meybeck, and S. Heussner, 2009. River discharges of water and nutrients to the Mediterranean and Black Sea: Major drivers for ecosystem changes during past and future decades? Progress in Oceanography, 80, 199-217. Peneva, E. L., E. Stanev, V. Belokopytov, and P.Y. Le Traon, 2001. Water transport in the Bosporus Straits estimated from hydro-meteorologycal and altimeter data: Seasonal to decadal variability. J. Mar. Sys., 31, 1-3, 21-35. Stanev E. and J.M. Beckers, 1999. Barotropic and baroclinic oscillations in strongly stratified ocean basins: Numerical study of the Black Sea. Journal of Marine Systems, 19, 65-112. Storto A., Masina S., Dobricic S., 2014. Estimation and impact of nonuniform horizontal correlation length scales for Global Ocean physical analyses. J. Atmos. Ocean. Technol., 31: 2330-2349.

First principles investigation of structural, vibrational and thermal properties of black and blue phosphorene

NASA Astrophysics Data System (ADS)

Arif Khalil, R. M.; Ahmad, Javed; Rana, Anwar Manzoor; Bukhari, Syed Hamad; Tufiq Jamil, M.; Tehreem, Tuba; Nissar, Umair

2018-05-01

In this investigation, structural, dynamical and thermal properties of black and blue phosphorene (P) are presented through the first principles calculations based on the density functional theory (DFT). These DFT calculations depict that due to the approximately same values of ground state energy at zero Kelvin and Helmholtz free energy at room-temperature, it is expected that both structures can coexist at transition temperature. Lattice dynamics of both phases were investigated by using the finite displacement supercell approach. It is noticed on the basis of harmonic approximation thermodynamic calculations that the blue phase is thermodynamically more stable than the black phase above 155 K.

Enhanced performance of solar cells with optimized surface recombination and efficient photon capturing via anisotropic-etching of black silicon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, H. Y.; Peng, Y., E-mail: gdyuan@semi.ac.cn, E-mail: py@usst.edu.cn; Hong, M.

2014-05-12

We report an enhanced conversion efficiency of femtosecond-laser treated silicon solar cells by surface modification of anisotropic-etching. The etching improves minority carrier lifetime inside modified black silicon area substantially; moreover, after the etching, an inverted pyramids/upright pyramids mixed texture surface is obtained, which shows better photon capturing capability than that of conventional pyramid texture. Combing of these two merits, the reformed solar cells show higher conversion efficiency than that of conventional pyramid textured cells. This work presents a way for fabricating high performance silicon solar cells, which can be easily applied to mass-production.

Recent advances in spacecraft thermal-control materials research.

NASA Technical Reports Server (NTRS)

Zerlaut, G. A.; Gilligan, J. E.; Gates, D. W.

1972-01-01

The state-of-the-art of spacecraft thermal-control materials technology has been significantly advanced during the past 4 years. Selective black coatings are discussed together with black paints, dielectric films on metal surfaces, and white radiator coatings. Criteria for the selection of thermal-control surfaces are considered, giving attention to prelaunch protection, the capability of being measured, reproducibility, simulator response, and aspects of a nonindigenous space environment. Progress in space simulation is related to vacuum technology, ultraviolet sources, solar wind simulation, and the production of protons. Advances have been made in the protection against space environmental effects, and in the development of thermal-control surfaces and pigments.

Iron repletion relocalizes hephaestin to a proximal basolateral compartment in polarized MDCK and Caco2 cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Seung-Min; Department of Nutritional Science and Toxicology, University of California, Berkeley, CA; Attieh, Zouhair K.

2012-05-11

Highlights: Black-Right-Pointing-Pointer Hephaestin localizes in the perinuclear space in non-polarized cells. Black-Right-Pointing-Pointer Hephaestin localizes in the perinuclear space in iron deficient and polarized cells. Black-Right-Pointing-Pointer Hephaestin with apical iron moves near to basolateral membrane of polarized cells. Black-Right-Pointing-Pointer Peri-basolateral location of hephaestin is accessible to the extracellular space. Black-Right-Pointing-Pointer Hephaestin is involved in iron mobilization from the intestine to circulation. -- Abstract: While intestinal cellular iron entry in vertebrates employs multiple routes including heme and non-heme routes, iron egress from these cells is exclusively channeled through the only known transporter, ferroportin. Reduced intestinal iron export in sex-linked anemia mice implicatesmore » hephaestin, a ferroxidase, in this process. Polarized cells are exposed to two distinct environments. Enterocytes contact the gut lumen via the apical surface of the cell, and through the basolateral surface, to the body. Previous studies indicate both local and systemic control of iron uptake. We hypothesized that differences in iron availability at the apical and/or basolateral surface may modulate iron uptake via cellular localization of hephaestin. We therefore characterized the localization of hephaestin in two models of polarized epithelial cell lines, MDCK and Caco2, with varying iron availability at the apical and basolateral surfaces. Our results indicate that hephaestin is expressed in a supra-nuclear compartment in non-polarized cells regardless of the iron status of the cells and in iron deficient and polarized cells. In polarized cells, we found that both apical (as FeSO{sub 4}) and basolateral iron (as the ratio of apo-transferrin to holo-transferrin) affect mobilization of hephaestin from the supra-nuclear compartment. We find that the presence of apical iron is essential for relocalization of hephaestin to a cellular compartment in close proximity but not overlapping with the basolateral surface. Surface biotinylation studies indicate that hephaestin in the peri-basolateral location is accessible to the extra-cellular environment. These results support the hypothesis that hephaestin is involved in iron mobilization of iron from the intestine to circulation.« less

Black holes with surrounding matter in scalar-tensor theories.

PubMed

Cardoso, Vitor; Carucci, Isabella P; Pani, Paolo; Sotiriou, Thomas P

2013-09-13

We uncover two mechanisms that can render Kerr black holes unstable in scalar-tensor gravity, both associated with the presence of matter in the vicinity of the black hole and the fact that this introduces an effective mass for the scalar. Our results highlight the importance of understanding the structure of spacetime in realistic, astrophysical black holes in scalar-tensor theories.

"You Make Me Wanna Holler and Throw up Both My Hands!": Campus Culture, Black Misandric Microaggressions, and Racial Battle Fatigue

ERIC Educational Resources Information Center

Smith, William A.; Mustaffa, Jalil Bishop; Jones, Chantal M.; Curry, Tommy J.; Allen, Walter R.

2016-01-01

Black males are scarce on White campuses. Still, they experience hypervisibility and are targets of hypersurveillance. This study used focus groups and semi-structured interviews to examine the experiences of 36 Black male students attending seven "elite" historically White Research I institutions. Two themes emerged: (a) anti-Black male…

Petrology, sedimentology and stratigraphic implications of Black Dragon Member of the Triassic Moenkopi Formation, San Rafael Swell, Utah

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chan, M.A.; Ochs, S.

1990-01-01

Deposition was partly controlled by paleotopographic relief of underlying Permian strata. Triassic Black Dragon sediments filled lowlands on an erosion surface (unconformity) cut into the Permian White Rim Sandstone and Kaibab Limestone. The Black Dragon Member consists of four distinct facies containing a wide variety of sedimentary structures that characterize both fluvial and tidal environments. The facies are: (1) a Chert Pebble Conglomerate (CPC) facies, characterized by calcite-cemented channel-fills of nodular and banded chert pebbles; (2) an Interbedded Sandstone, Siltstone, and Shale (SSS) facies, containing oscillation ripples and flaser bedding; (3) a large-scale Trough Cross-Stratified Sandstone (TXS) facies, consisting ofmore » 6.6-13.1 ft (2-4 m) thick sets of fine- to medium-grained sandstone; and (4) an Oolitic and Algal Limestone (OAL) facies, with cross-stratified oolitic beds, fenestral fabric, and laminated algal rip-up clasts. The CPC facies and the TXS facies were deposited by braided streams when the shoreline lay west of the San Rafael Swell. Rivers drained off and eroded localized Permian highlands, located most likely within a 62 mi (100 km) distance to the south and southeast of the study area. The SSS facies which constitutes the bulk of the Black Dragon Member, and the OAL facies are inter- and supratidal deposits formed during relative sea level highstands, when the shoreline lay within or east of the San Rafael Swell. A decrease in continent-derived sand supply and a corresponding increase in carbonate production within the OAL facies characterizes the end of Black Dragon deposition and the gradation into the overlying Sinbad Limestone Member.« less

Aerial gamma ray and magnetic survey: Powder River II Project, Gillette Quadrangle, Wyoming. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1979-04-01

The Gillette quadrangle in northeastern Wyoming and western South Dakota contains approximately equal portions of the Powder River Basin and the Black Hills Uplift. In these two structures, a relatively thick sequence of Paleozoic and Mesozoic strata represent nearly continuous deposition over the Precambrian basement complex. The Powder River Basin also contains a thick sequence of early Tertiary rocks which cover about 50% of the surface. A stratigraphic sequence from Upper Cretaceous to Precambrian is exposed in the Black Hills Uplift to the east. Magnetic data apparently illustrate the relative depth to the Precambrian crystalline rocks, but only weakly definemore » the boundary between the Powder River Basin and the Black Hills Uplift. The positions of some small isolated Tertiary intrusive bodies in the Black Hills Uplift are relatively well expressed. The Gillette quadrangle has been productive in terms of uranium mining, but its current status is uncertain. The producing uranium deposits occur within the Lower Cretaceous Inyan Kara Group and the Jurassic Morrison Formation in the Black Hills Uplift. Other prospects occur within the Tertiary Wasatch and Fort Union Formations in the Pumpkin Buttes - Turnercrest district, where it extends into the quadrangle from the Newcastle quadrangle to the south. These four formations, all predominantly nonmarine, contain all known uranium deposits in the Gillette quadrangle. A total of 108 groups of sample responses in the uranium window constitute anomalies as defined in Volume I. The anomalies are most frequently found in the Inyan Kara-Morrison, Wasatch and Fort Union Formations. Many anomalies occur over known mines or prospects. Others may result from unmapped uranium mines or areas where material other than uranium is mined. The remainder may relate to natural geologic features.« less

The use of novel biodegradable, optically active and nanostructured poly(amide-ester-imide) as a polymer matrix for preparation of modified ZnO based bionanocomposites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abdolmaleki, Amir, E-mail: abdolmaleki@cc.iut.ac.ir; Nanotechnology and Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran; Mallakpour, Shadpour, E-mail: mallak@cc.iut.ac.ir

Highlights: Black-Right-Pointing-Pointer A novel biodegradable and nanostructured PAEI based on two amino acids, was synthesized. Black-Right-Pointing-Pointer ZnO nanoparticles were modified via two different silane coupling agents. Black-Right-Pointing-Pointer PAEI/modified ZnO BNCs were synthesized through ultrasound irradiation. Black-Right-Pointing-Pointer ZnO particles were dispersed homogeneously in PAEI matrix on nanoscale. Black-Right-Pointing-Pointer The effect of ZnO nanoparticles on the properties of synthesized polymer was examined. -- Abstract: A novel biodegradable and nanostructured poly(amide-ester-imide) (PAEI) based on two different amino acids, was synthesized via direct polycondensation of biodegradable N,N Prime -bis[2-(methyl-3-(4-hydroxyphenyl)propanoate)]isophthaldiamide and N,N Prime -(pyromellitoyl)-bis-L-phenylalanine diacid. The resulting polymer was characterized by FT-IR, {sup 1}H NMR,more » specific rotation, elemental analysis, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM) analysis. The synthesized polymer showed good thermal stability with nano and sphere structure. Then PAEI/ZnO bionanocomposites (BNCs) were fabricated via interaction of pure PAEI and ZnO nanoparticles. The surface of ZnO was modified with two different silane coupling agents. PAEI/ZnO BNCs were studied and characterized by FT-IR, XRD, UV/vis, FE-SEM and TEM. The TEM and FE-SEM results indicated that the nanoparticles were dispersed homogeneously in PAEI matrix on nanoscale. Furthermore the effect of ZnO nanoparticle on the thermal stability of the polymer was investigated with TGA and DSC technique.« less

Titanate nanotube thin films with enhanced thermal stability and high-transparency prepared from additive-free sols

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koroesi, Laszlo, E-mail: korosi@enviroinvest.hu; Department of Biotechnology, Nanophage Therapy Center, Enviroinvest Corporation, Kertvaros utca 2, H-7632 Pecs; Papp, Szilvia

2012-08-15

Titanate nanotubes were synthesized from TiO{sub 2} in alkaline medium by a conventional hydrothermal method (150 Degree-Sign C, 4.7 bar). To obtain hydrogen titanates, the as-prepared sodium titanates were treated with either HCl or H{sub 3}PO{sub 4} aqueous solutions. A simple synthesis procedure was devised for stable titanate nanotube sols without using any additives. These highly stable ethanolic sols can readily be used to prepare transparent titanate nanotube thin films of high quality. The resulting samples were studied by X-ray diffraction, N{sub 2}-sorption measurements, Raman spectroscopy, transmission and scanning electron microscopy, X-ray photoelectron spectroscopy and spectroscopic ellipsometry. The comparative resultsmore » of using two kinds of acids shed light on the superior thermal stability of the H{sub 3}PO{sub 4}-treated titanate nanotubes (P-TNTs). X-ray photoelectron spectroscopy revealed that P-TNTs contains P in the near-surface region and the thermal stability was enhanced even at a low ({approx}0.5 at%) concentration of P. After calcination at 500 Degree-Sign C, the specific surface areas of the HCl- and H{sub 3}PO{sub 4}-treated samples were 153 and 244 m{sup 2} g{sup -1}, respectively. The effects of H{sub 3}PO{sub 4} treatment on the structure, morphology and porosity of titanate nanotubes are discussed. - Graphical Abstract: TEM picture (left) shows P-TNTs with diameters about 5-6 nm. Inset shows a stable titanate nanotube sol illuminated by a 532 nm laser beam. Due to the presence of the nanoparticles the way of the light is visible in the sol. Cross sectional SEM picture (right) as well as ellipsometry revealed the formation of optical quality P-TNT films with thicknesses below 50 nm. Highlights: Black-Right-Pointing-Pointer H{sub 3}PO{sub 4} treatment led to TNTs with high surface area even after calcination at 500 Degree-Sign C. Black-Right-Pointing-Pointer H{sub 3}PO{sub 4}-treated TNTs preserved their nanotube morphology up to 500 Degree-Sign C. Black-Right-Pointing-Pointer Stable TNT sols can be prepared by the peptization of TNT gels. Black-Right-Pointing-Pointer High-transparency TNT thin films of high quality were fabricated.« less

Study of structural, elastic, electronic and optical properties of seven SrZrO{sub 3} phases: First-principles calculations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Qi-Jun, E-mail: dianerliu@yahoo.com.cn; Liu, Zheng-Tang; Feng, Li-Ping

2012-12-15

On the plane-wave ultrasoft pseudopotential technique based on the first-principles density functional theory (DFT), we calculated the structural, elastic, electronic and optical properties of the seven different phases of SrZrO{sub 3}. The obtained ground-state properties are in good agreement with previous experiments and calculations, which indicate that the most stable phase is orthorhombic Pnma structure. Seven phases of SrZrO{sub 3} are mechanically stable with cubic, tetragonal and orthorhombic structures. The mechanical and thermodynamic properties have been obtained by using the Voigt-Reuss-Hill approach and Debye-Grueneisen model. The electronic structures and optical properties are obtained and compared with the available experimental andmore » theoretical data. - Graphical abstract: Energy versus volume of seven phases SrZrO{sub 3} shows the Pnma phase has the minimum ground-state energy. Highlights: Black-Right-Pointing-Pointer We calculated the physical and chemical properties of seven SrZrO{sub 3} polymorphs. Black-Right-Pointing-Pointer The order of stability is Pnma>Imma>Cmcm>I4/mcm>P4/mbm>P4mm>Pm3-bar m. Black-Right-Pointing-Pointer The most stable phase is orthorhombic Pnma structure. Black-Right-Pointing-Pointer Seven phases of SrZrO{sub 3} are mechanically stable. Black-Right-Pointing-Pointer The relationship between n and {rho}{sub m} is n=1+0.18{rho}{sub m}.« less

Microwave-assisted hydrothermal synthesis of marigold-like ZnIn{sub 2}S{sub 4} microspheres and their visible light photocatalytic activity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen Zhixin, E-mail: czx@fzu.edu.cn; Analysis and Test Center, Fuzhou University, Fuzhou 350002; Li Danzhen

Marigold-like ZnIn{sub 2}S{sub 4} microspheres were synthesized by a microwave-assisted hydrothermal method with the temperature ranging from 80 to 195 Degree-Sign C. X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen sorption analysis, UV-visible spectroscopy, scanning electron microscopy and transmission electron microscopy were used to characterize the products. It was found that the crystallographic structure and optical property of the products synthesized at different temperatures were almost the same. The degradation of methyl orange (MO) under the visible light irradiation has been used as a probe reaction to investigate the photocatalytic activity of as-prepared ZnIn{sub 2}S{sub 4}, which shows that the ZnIn{sub 2}S{submore » 4} sample synthesized at 195 Degree-Sign C shows the best photocatalytic activity for MO degradation. In addition, the photocatalytic activities of all the samples prepared by the microwave-assisted hydrothermal method are better than those prepared by a normal hydrothermal method, which could be attributed to the formation of more defect sites during the microwave-assisted hydrothermal treatment. - Graphical abstract: Marigold-like ZnIn{sub 2}S{sub 4} microspheres were synthesized by a fast microwave-assisted hydrothermal method at 80-195 Degree-Sign C with a very short reaction time of 10 min. The as-prepared ZnIn{sub 2}S{sub 4} sample can be used as visible light photocatalyst for degradation of organic dyes. Highlights: Black-Right-Pointing-Pointer ZnIn{sub 2}S{sub 4} microspheres were synthesized by microwave-assisted hydrothermal method. Black-Right-Pointing-Pointer The crystal structure and optical property of the products were almost the same. Black-Right-Pointing-Pointer Increment of the temperature renders high surface area due to the bubbling effect. Black-Right-Pointing-Pointer The ZnIn{sub 2}S{sub 4} synthesized at 195 Degree-Sign C shows the best visible catalytic activity for MO.« less

A theoretical study on the optical properties of black silicon

NASA Astrophysics Data System (ADS)

Ma, Shijun; Liu, Shuang; Xu, Qinwei; Xu, Junwen; Lu, Rongguo; Liu, Yong; Zhong, Zhiyong

2018-03-01

There is a wide application prospect in black silicon, especially in solar cells and photoelectric detectors. For further optimization of black silicon, it is important to study its optical properties. Especially, the influence of the surface nanostructures on these properties and the light propagation within the nanostructures are relevant. In this paper, two kinds of black silicon models are studied via the finite differences time domain method. The simulated reflectance spectra matches well with the measured curve. Also, the light intensity distribution within the nanostructures shows that near 80% of the incident light are redirected and subjected to internal reflection, which provides powerful support for the good light trapping properties of black silicon.

Nitrogen-doped hierarchical lamellar porous carbon synthesized from the fish scale as support material for platinum nanoparticle electrocatalyst toward the oxygen reduction reaction.

PubMed

Liu, Haijing; Cao, Yinliang; Wang, Feng; Huang, Yaqin

2014-01-22

Novel hierarchical lamellar porous carbon (HLPC) with high BET specific surface area of 2730 m(2) g(-1) and doped by nitrogen atoms has been synthesized from the fish scale without any post-synthesis treatment, and applied to support the platinum (Pt) nanoparticle (NP) catalysts (Pt/HLPC). The Pt NPs could be highly dispersed on the porous surface of HLPC with a narrow size distribution centered at ca. 2.0 nm. The results of the electrochemical analysis reveal that the electrochemical active surface area (ECSA) of Pt/HLPC is larger than the Pt NP electrocatalyst supported on the carbon black (Pt/Vulcan XC-72). Compared with the Pt/Vulcan XC-72, the Pt/HLPC exhibits larger current density, lower overpotential, and enhanced catalytic activity toward the oxygen reduction reaction (ORR) through the direct four-electron pathway. The improved catalytic activity is mainly attributed to the high BET specific surface area, hierarchical porous structures and the nitrogen-doped surface property of HLPC, indicating the superiority of HLPC as a promising support material for the ORR electrocatalysts.

Acoustic black holes: recent developments in the theory and applications.

PubMed

Krylov, Victor

2014-08-01

Acoustic black holes are relatively new physical objects that have been introduced and investigated mainly during the last decade. They can absorb almost 100% of the incident wave energy, and this makes them very attractive for such traditional engineering applications as vibration damping in different engineering structures and sound absorption in gases and liquids. They also could be useful for some ultrasonic devices using Lamb wave propagation to provide anechoic termination for such waves. So far, acoustic black holes have been investigated mainly for flexural waves in thin plates, for which the required gradual changes in local wave velocity with distance can be easily achieved by changing the plates' local thickness. The present paper provides a brief review of the theory of acoustic black holes, including their comparison with optic black holes introduced about five years ago. Review is also given of the recent experimental work carried out at Loughborough University on damping structural vibrations using the acoustic black hole effect. This is followed by the discussion on potential applications of the acoustic black hole effect for sound absorption in air.

The Heat Strain of Various Athletic Surfaces: A Comparison Between Observed and Modeled Wet-Bulb Globe Temperatures.

PubMed

Pryor, J Luke; Pryor, Riana R; Grundstein, Andrew; Casa, Douglas J

2017-11-01

  The National Athletic Trainers' Association recommends using onsite wet-bulb globe temperature (WBGT) measurement to determine whether to modify or cancel physical activity. However, not all practitioners do so and instead they may rely on the National Weather Service (NWS) to monitor weather conditions.   To compare regional NWS WBGT estimates with local athletic-surface readings and compare WBGT measurements among various local athletic surfaces.   Observational study.   Athletic fields.   Measurements from 2 identical WBGT devices were averaged on 10 athletic surfaces within an NWS station reporting radius. Athletic surfaces consisted of red and black all-weather tracks (track), blue and black hard tennis courts (tennis), nylon-knit artificial green turf, green synthetic turfgrass, volleyball sand, softball clay, natural grass (grass), and a natural lake (water). Measurements (n = 143 data pairs) were taken over 18 days (May through September) between 1 pm and 4:30 pm in direct sunlight 1.2 m above ground. The starting location was counterbalanced across surfaces. The NWS weather data were entered into an algorithm to model NWS WBGT.   Black tennis, black track, red track, and volleyball sand WBGT recordings were greater than NWS estimates ( P ≤ .05). When all athletic-surface measurements were combined, NWS (26.85°C ± 2.93°C) underestimated athletic-surface WBGT measurements (27.52°C ± 3.13°C; P < .001). The range of difference scores (-4.42°C to 6.14°C) and the absolute mean difference (1.71°C ± 1.32°C) were large. The difference between the onsite and NWS WBGT measurements resulted in misclassification of the heat-safety activity category 45% (65/143) of the time ([Formula: see text]= 3.857, P = .05). The WBGT of water was 1.4°C to 2.7°C lower than that of all other athletic surfaces ( P = .04). We observed no other differences among athletic surfaces but noted large WBGT measurement variability among athletic playing surfaces.   Clinicians should use an onsite WBGT device to determine environmental conditions and the need for modification of athletic events, especially as environmental conditions worsen. Given the large WBGT variability among athletic surfaces, WBGT measurements should be obtained from each athletic surface.

Use of carbon black in bituminous concrete in Virginia.

DOT National Transportation Integrated Search

1981-01-01

In an attempt to verify the claim that the addition of carbon black to bituminous concrete increases its stability and performance, a test section placed on a deformed bridge deck surface near Altavista and one on Route 360 near Richmond are being ev...

Development of test procedure for the design of black base : final report.

DOT National Transportation Integrated Search

1976-01-01

There is no standard design procedure available for black base mixes containing aggregates larger than 1" (25.4 mm) This investigation dealt with the use of stability testing equipment similar to that used in the design of surface mixes and developme...

The black hole interior and the type II Weyl fermions

NASA Astrophysics Data System (ADS)

Zubkov, M. A.

2018-03-01

It was proposed recently that the black hole may undergo a transition to the state, where inside the horizon the Fermi surface is formed that reveals an analogy with the recently discovered type II Weyl semimetals. In this scenario, the low energy effective theory outside of the horizon is the Standard Model, which describes excitations that reside near a certain point P(0) in momentum space of the hypothetical unified theory. Inside the horizon the low energy physics is due to the excitations that reside at the points in momentum space close to the Fermi surface. We argue that those points may be essentially distant from P(0) and, therefore, inside the black hole the quantum states are involved in the low energy dynamics that are not described by the Standard Model. We analyze the consequences of this observation for the physics of the black holes and present the model based on the direct analogy with the type II Weyl semimetals, which illustrates this pattern.

Pulmonary toxicity of manufactured nanoparticles

NASA Astrophysics Data System (ADS)

Peebles, Brian Christopher

Manufactured nanomaterials have become ubiquitous in science, industry, and medicine. Although electron microscopy and surface probe techniques have improved understanding of the physicochemical properties of nanomaterials, much less is known about what makes nanomaterials toxic. Particulate matter less than 2.5 mum in effective aerodynamic diameter is easily inhaled and taken deep into the lungs. The toxicity of inhaled particulate matter is related to its size and surface chemistry; for instance, the smaller the size of particles, the greater their specific surface area. The chemistry and toxicity of insoluble particles depends on their surface area, since chemical reactions may happen with the environment on the surface. Oxidation and reduction may occur on the surfaces of particles after they are produced. For instance, it is known that carbonaceous particles from vehicle exhaust and industrial emission may interact with reactive species like ozone in their ambient environment, altering the surface chemistry of the particles. Reaction with species in the environment may cause changes in the chemical functionality of the surface and change the toxic properties of the particles when they are inhaled. Furthermore, metals on the surface of inhalable particles can contribute to their toxicity. Much attention has been given to the presence of iron on the surfaces of inhalable particles in the environment. After particle inhalation, particles are endocytosed by alveolar macrophages in the immune response to foreign matter. They are exposed to hydrogen peroxide in the oxidative burst, which can cause the iron-mediated production of hydroxyl free radicals via the Fenton reaction, causing oxidative stress that leads to inflammation and cell death. The toxicity of particles that contain metals depends on the redox activity and bioavailability of the metals, the causes of thich have not yet been adequately explored. In this thesis, electron paramagnetic spectroscopy showed that carbon blacks contain free radical and other surface functionality as manufactured, and that exposure to ozone further functionalizes the surface. Samples of carbon black that have been exposed to ozone react with their ambient environment so that acid anhydride and cyclic ether functionality hydrolyze to form carboxylic acid functionality, observable by transmission Fourier transform infrared spectroscopy. Persistent free radical content, but not free radical content from ozone exposure, may mediate the toxic response of cells to carbon blacks in vitro. Results showed that macrophages exposed to carbon blacks that had been exposed to ozone were not less viable in vitro than macrophages exposed to carbon blacks as manufactured because the free radical content that resulted from ozone exposure was not persistent in an aqueous medium. Furthermore, concurrent exposure to ozonated carbon blacks and ozone was less lethal to macrophages than carbon black exposure alone, possibly because the ozone oxidatively preconditioned the macrophages to resist oxidative stress. The nature of redox-active iron species on the surface of iron-loaded synthetic carbon particles was explored. The particles had been shown in previous studies to provoke an inflammatory response involving the release of tumor necrosis factor (TNF)-alpha, which was correlated with their production of hydroxyl free radicals via the Fenton reaction in the presence of hydrogen peroxide. It was found that the source of bioavailable Fenton-active iron on the surfaces of the particles was fluoride species that were byproducts of a step in the synthetic process. Fluoride ligated the iron already on the surface, forming a complex that resisted precipitation in the biological medium and thus made the iron more bioavailable. The results of this thesis aim to clarify whether the size and surface chemistry of nanoparticles should be considered more closely as criteria with which to develop better environmental controls for occupational health. Permissible exposure limits to micrometer-size particulate matter in the workplace are in place, but current limits do not specifically address the role of surface chemistry and the potentially higher toxicity of nanomaterials. The size, agglomeration characteristics, and surface chemistry of carbon nanoparticles are being studied and manipulated to explore the causes of their toxicity. Inflammatory response and cytotoxicity following exposure of human and murine macrophages to nanoparticles are being employed as indicators of the ability of particles to cause respiratory harm. The results are expected to lead to more effective standards for nanomaterial exposure in the workplace and pathways to toxicity mitigation.

Racial and Ethnic Disparities in Structural Disadvantage and Crime: White, Black, and Hispanic Comparisons*

PubMed Central

Ulmer, Jeffery T.; Harris, Casey T.; Steffensmeier, Darrell

2014-01-01

Objectives The objective of this study is to advance knowledge on racial/ethnic disparities in violence and the structural sources of those disparities. We do so by extending scarce and limited research exploring the relationship between race/ethnic gaps in disadvantage and differences in violent crime across groups. Methods Using census place-level data from California and New York, we construct White, Black, and Hispanic “gap” measures that take as a given the existence of disparities across race/ethnic groups in structural disadvantage and crime and subsequently utilize seemingly unrelated regression models to assess the extent to which gaps in disadvantage are predictive of gaps in homicide and index violence. Results Our results suggest that (1) there is considerable heterogeneity in the size of White-Black, White-Hispanic, and Black-Hispanic gaps in structural disadvantage and crime and (2) that race/ethnic disparities in structural disadvantage, particularly poverty and female headship, are positively associated with race/ethnic gaps in homicide and index violence. Conclusion In light of recent scholarship on the racial invariance hypothesis and on the relationship between structural inequality and crime, the current study demonstrates that disparities in disadvantage, particularly family structure and poverty, are important in driving racial and ethnic disparities in crime. PMID:25035523

Latitudinal distribution of black carbon soot in the upper troposphere and lower stratosphere

NASA Technical Reports Server (NTRS)

Blake, David F.; Kato, Katharine

1995-01-01

Black carbon soot from the upper troposphere and lower stratosphere has been systematically collected at latitudes from 90 deg N to 45 deg S. The measured latitudinal distribution of this soot at 10 to 11 km altitude is found to covary with commercial air traffic fuel use, suggesting that aircraft fuel combustion at altitude is the principal source. In addition, at latitudes where the commercial air traffic is high, measured black carbon soot values are high even at 20 km altitude, suggesting that aircraft-generated soot injected just above the tropopause may be transported to higher altitudes. During the volcanically influenced period in which these samples were collected, the number abundances, total mass, and calculated total surface area of black carbon soot are 2-3 orders of magnitude lower than similar measures of sulfuric acid aerosol. During volcanically quiescent periods, the calculated total surface area of black carbon soot aerosol is of the same order of magnitude as that of the background sulfuric acid aerosol. It appears from this comparison that black carbon soot is only capable of influencing lower stratosphere or upper troposphere chemistry during periods when the aerosol budget is not dominated by volcanic activity. It remains to determine the extent to which black carbon soot particles act as nuclei for sulfuric acid aerosol formation. However, mass balance calculations suggest that aircraft soot injected at altitude does not represent a significant source of condensation nuclei for sulfuric acid aerosols.

The erosive effect of herbal tea on dental enamel.

PubMed

Brunton, P A; Hussain, A

2001-11-01

The aim of this study was to determine whether conventional black tea and a herbal tea were capable of eroding dental enamel. A further aim was to investigate whether herbal tea of the type tested eroded dental hard tissues to a greater or lesser extent than conventional black tea. Three groups of 21 teeth were exposed to a conventional black tea Typhoo (Group A), a herbal tea Twinings Blackcurrant, Ginsing and Vanilla (Group B) and water, which acted as a control (Group C). Sequential profilometric tracings of the specimens were taken, superimposed and the degree of enamel loss calculated as the area of disparity between the tracings before and after exposure. Conventional black tea and herbal tea, of the type tested, both resulted in tooth surface loss. Tooth surface loss, which resulted from exposure to herbal tea (mean 0.05mm(2), s.d. 0.02), however, was significantly greater (P=0.00) than that which resulted from exposure to conventional black tea (mean 0.01mm(2), s.d. 0.00) and water (mean 0.00mm(2), s.d. 0.00). It was concluded that herbal tea and conventional black tea of the type tested result in erosion of dental enamel. The erosive effect of the herbal tea of the type tested was five times more severe than that of the conventional black tea tested. The cumulative effects of regular consumption of herbal tea of the type tested are likely, therefore, to be of clinical significance.

Black Molecular Adsorber Coatings for Spaceflight Applications

NASA Technical Reports Server (NTRS)

Abraham, Nithin Susan; Hasegawa, Mark Makoto; Straka, Sharon A.

2014-01-01

The molecular adsorber coating is a new technology that was developed to mitigate the risk of on-orbit molecular contamination on spaceflight missions. The application of this coating would be ideal near highly sensitive, interior surfaces and instruments that are negatively impacted by outgassed molecules from materials, such as plastics, adhesives, lubricants, epoxies, and other similar compounds. This current, sprayable paint technology is comprised of inorganic white materials made from highly porous zeolite. In addition to good adhesion performance, thermal stability, and adsorptive capability, the molecular adsorber coating offers favorable thermal control characteristics. However, low reflectivity properties, which are typically offered by black thermal control coatings, are desired for some spaceflight applications. For example, black coatings are used on interior surfaces, in particular, on instrument baffles for optical stray light control. Similarly, they are also used within light paths between optical systems, such as telescopes, to absorb light. Recent efforts have been made to transform the white molecular adsorber coating into a black coating with similar adsorptive properties. This result is achieved by optimizing the current formulation with black pigments, while still maintaining its adsorption capability for outgassing control. Different binder to pigment ratios, coating thicknesses, and spray application techniques were explored to develop a black version of the molecular adsorber coating. During the development process, coating performance and adsorption characteristics were studied. The preliminary work performed on black molecular adsorber coatings thus far is very promising. Continued development and testing is necessary for its use on future contamination sensitive spaceflight missions.

Black molecular adsorber coatings for spaceflight applications

NASA Astrophysics Data System (ADS)

Abraham, Nithin S.; Hasegawa, Mark M.; Straka, Sharon A.

2014-09-01

The molecular adsorber coating is a new technology that was developed to mitigate the risk of on-orbit molecular contamination on spaceflight missions. The application of this coating would be ideal near highly sensitive, interior surfaces and instruments that are negatively impacted by outgassed molecules from materials, such as plastics, adhesives, lubricants, epoxies, and other similar compounds. This current, sprayable paint technology is comprised of inorganic white materials made from highly porous zeolite. In addition to good adhesion performance, thermal stability, and adsorptive capability, the molecular adsorber coating offers favorable thermal control characteristics. However, low reflectivity properties, which are typically offered by black thermal control coatings, are desired for some spaceflight applications. For example, black coatings are used on interior surfaces, in particular, on instrument baffles for optical stray light control. Similarly, they are also used within light paths between optical systems, such as telescopes, to absorb light. Recent efforts have been made to transform the white molecular adsorber coating into a black coating with similar adsorptive properties. This result is achieved by optimizing the current formulation with black pigments, while still maintaining its adsorption capability for outgassing control. Different binder to pigment ratios, coating thicknesses, and spray application techniques were explored to develop a black version of the molecular adsorber coating. During the development process, coating performance and adsorption characteristics were studied. The preliminary work performed on black molecular adsorber coatings thus far is very promising. Continued development and testing is necessary for its use on future contamination sensitive spaceflight missions.

Phase structure of higher spin black hole

NASA Astrophysics Data System (ADS)

Chen, Bin; Long, Jiang; Wang, Yi-Nan

2013-03-01

In this paper, we investigate the phase structure of the black holes with one single higher spin hair, focusing specifically on the spin 3 and spin widetilde{4} black holes. Based on dimensional analysis and the requirement of thermodynamic consistency, we derive a universal formula relating the entropy with the conserved charges for arbitrary AdS 3 higher spin black holes. Then we use it to study the phase structure of the higher spin black holes. We find that there are six branches of solutions in the spin 3 gravity, eight branches of solutions in the spin widetilde{4} gravity and twelve branches of solutions in the G 2 gravity. In each case, all the branches are related by a simple angle shift in the entropy functions. In the spin 3 case, we reproduce all the results found before. In the spin widetilde{4} case, we find that at low temperature it lies in the BTZ branch while at high temperature it undergoes a phase transition to one of the two other branches, depending on the signature of the chemical potential, a reflection of charge conjugate asymmetry found before.

Combustion properties of Kraft Black Liquors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frederick, W.J. Jr.; Hupa, M.

1993-04-01

In a previous study of the phenomena involved in the combustion of black liquor droplets a numerical model was developed. The model required certain black liquor specific combustion information which was then not currently available, and additional data were needed for evaluating the model. The overall objectives of the project reported here was to provide experimental data on key aspects of black liquor combustion, to interpret the data, and to put it into a form which would be useful for computational models for recovery boilers. The specific topics to be investigated were the volatiles and char carbon yields from pyrolysismore » of single black liquor droplets; a criterion for the onset of devolatilization and the accompanying rapid swelling; and the surface temperature of black liquor droplets during pyrolysis, combustion, and gasification. Additional information on the swelling characteristics of black liquor droplets was also obtained as part of the experiments conducted.« less

Towards black-box calculations of tunneling splittings obtained from vibrational structure methods based on normal coordinates.

PubMed

Neff, Michael; Rauhut, Guntram

2014-02-05

Multidimensional potential energy surfaces obtained from explicitly correlated coupled-cluster calculations and further corrections for high-order correlation contributions, scalar relativistic effects and core-correlation energy contributions were generated in a fully automated fashion for the double-minimum benchmark systems OH3(+) and NH3. The black-box generation of the potentials is based on normal coordinates, which were used in the underlying multimode expansions of the potentials and the μ-tensor within the Watson operator. Normal coordinates are not the optimal choice for describing double-minimum potentials and the question remains if they can be used for accurate calculations at all. However, their unique definition is an appealing feature, which removes remaining errors in truncated potential expansions arising from different choices of curvilinear coordinate systems. Fully automated calculations are presented, which demonstrate, that the proposed scheme allows for the determination of energy levels and tunneling splittings as a routine application. Copyright © 2013 Elsevier B.V. All rights reserved.

Photocatalytic hydrogen evolution of palladium nanoparticles decorated black TiO2 calcined in argon atmosphere

NASA Astrophysics Data System (ADS)

Wu, Ming-Chung; Hsiao, Kai-Chi; Chang, Yin-Hsuan; Chan, Shun-Hsiang

2018-02-01

Black TiO2 nanoparticles (BTN) was prepared by sol-gel derived precursor calcined in an argon atmosphere. The synthesized BTN with trivalent titanium ion, structural defect, and oxygen vacancy shows a remarkably high absorbance in the visible light spectrum. BTN thus behaves a higher visible-active nanoreactor than white TiO2 nanoparticles (WTN) in the aqueous solution for organic pollutant degradation. Moreover, palladium decoration on the BTN surface (Pd-BTN) demonstrates a fascinating clean energy application. The obtained Pd-BTN fulfills a satisfied green material demand in the photocatalytic hydrogen production application. Pd-BTN calcined at 400 °C (Pd-BTN-400) shows the high photocatalytic hydrogen generation rate of 5200 μmol/g h under UV-A irradiation and 9300 μmol/g h under UV-B irradiation, respectively. The well-developed material, Pd-BTN-400, could be one of the best solutions in the concern of clean energy and water-purification with regard to the continuous environmental issue.

Ca2+-induced phase separation in black lipid membranes and its effect on the transport of a hydrophobic ion.

PubMed

Miller, A; Schmidt, G; Eibl, H; Knoll, W

1985-03-14

Voltage jump-current relaxation studies have been performed with dipicrylamine-doped black membranes of binary lipid mixtures. As in the case of the carrier-mediated ion transport (Schmidt, G., Eibl, H. and Knoll, W. (1982) J. Membrane Biol. 70, 147-155) no evidence was found that the neutral lipid phosphatidylcholine (DPMPC) and the charged phosphatidic acid (DPMPA) are heterogeneously distributed in the membrane over the whole range of composition. However, besides a continuous dilution of the surface charges of DPMPA by the addition of DPMPC molecules, different structural properties of mixed membranes influence the kinetics of the dipicrylamine transport. The addition of Ca2+ to the electrolyte induces a lipid phase separation within the membrane into two fluid phases of distinctly different characteristics of the translocation of hydrophobic ions. Thus, it is possible to determine a preliminary composition phase diagram for the DPMPA/DPMPC mixtures as a function of the Ca2+ concentration.

Photoinduced Nonequilibrium Topological States in Strained Black Phosphorus

NASA Astrophysics Data System (ADS)

Liu, Hang; Sun, Jia-Tao; Cheng, Cai; Liu, Feng; Meng, Sheng

2018-06-01

Black phosphorus (BP), an elemental semiconductor, has attracted tremendous interest because it exhibits a wealth of interesting electronic and optoelectronic properties in equilibrium condition. The nonequilibrium electronic structures of bulk BP under a periodic field of laser remain unexplored, but can lead to intriguing topological optoelectronic properties. Here we show that, under the irradiation of circularly polarized light (CPL), BP exhibits a photon-dressed Floquet-Dirac semimetal state, which can be continuously tuned by changing the direction, intensity, and frequency of the incident laser. The topological phase transition from type-I to type-II Floquet-Dirac fermions manifests a new form of type-III phase, which exists in a wide range of intensities and frequencies of the incident laser. Furthermore, topological surface states exhibit nonequilibrium electron transport in a direction locked by the helicity of CPL. Our findings not only deepen our understanding of fundamental properties of BP in relation to topology but also extend optoelectronic device applications of BP to the nonequilibrium regime.

Microscopic search for the carrier phase Q of the trapped planetary noble gases in Allende, Leoville, and Vigarano

NASA Astrophysics Data System (ADS)

Vis, R. D.; Mrowiec, A.; Kooyman, P. J.; Matsubara, K.; Heymann, D.

2002-10-01

High-resolution transmission electron microscopy micrographs of acid-resistant residues of the Allende, Leoville, and Vigarano meteorites show a great variety of carbon structures: curved and frequently twisted and intertwined graphene sheets, abundant carbon black-like particles, and hollow "sacs". It is suggested that perhaps all of these are carriers for the planetary Q-noble gases in these meteorites. Most of these materials are pyrocarbons that probably formed by the pyrolysis of hydrocarbons either in a gas phase, or on hot surfaces of minerals. An attempt was made to analyze for argon with particle-induced x-ray emission in 143 spots of grains of floating and suspended matter from freeze-dry cycles of an Allende bulk sample in water, and floating "black balls" from sonication in water of samples from the Allende meteorite. The chemical compositions of these particles were obtained, but x-ray signals at the wavelength of argon were obtained on only a few spots.

Development of Tailorable Electrically Conductive Thermal Control Material Systems

NASA Technical Reports Server (NTRS)

Deshpande, M. S.; Harada, Y.

1997-01-01

The optical characteristics of surfaces on spacecraft are fundamental parameters in controlling its temperature. Passive thermal control coatings with designed solar absorptance and infrared emittance properties have been developed and have been in use for some time. In this total space environment, the coating must be stable and maintain its desired optical properties as well as mechanical properties for the course of the mission lifetime. The mission lifetimes are increasing and in our quest to save weight, newer substrates are being integrated which limit electrical grounding schemes. All of this has added to already existing concerns about spacecraft charging and related spacecraft failures or operational failures. The concern is even greater for thermal control surfaces that are very large. One way of alleviating such concerns is to design new thermal control material systems (TCMS) that can help to mitigate charging via providing charge leakage paths. The objective of this program was to develop two types of passive electrically conductive TCMS. The first was a highly absorbing/emitting black surface and the second was a low (alpha(sub s)/epsilon(sub N)) type white surface. The surface resistance goals for the black absorber was 10(exp 4) to 10(exp 9) Omega/square, and for the white surfaces it was 10(exp 6) to 10(exp 10) Omega/square. Several material system concepts were suggested and evaluated for space environment stability and electrical performance characterization. Our efforts in designing and evaluating these material systems have resulted in several developments. New concepts, pigments and binders have been developed to provide new engineering quality TCMS. Some of these have already found application on space hardware, some are waiting to be recognized by thermal designers, and some require further detailed studies to become state-of-the-art for future space hardware and space structures. Our studies on baseline state-of-the-art materials and conductive concepts have resulted in several important findings that are of interest to all thermal designers and systems integrators.

Southern Dobrogea coastal potable water sources and Upper Quaternary Black Sea level changes

NASA Astrophysics Data System (ADS)

Caraivan, Glicherie; Stefanescu, Diana

2013-04-01

Southern Dobrogea is a typical geologic platform unit, placed in the south-eastern part of Romania, with a Pre-Cambrian crystalline basement and a Paleozoic - Quaternary sedimentary cover. It is bordered to the north by the Capidava - Ovidiu fault and by the Black Sea to the east. A regional WNW - ESE and NNE - SSW fault system divides the Southern Dobrogea structure in several tectonic blocks. Four drinking water sources have been identified: surface water, phreatic water, medium depth Sarmatian aquifer, and deep Upper Jurassic - Lower Cretaceous aquifer. Surface water sources are represented by several springs emerged from the base of the loess cliff, and a few small rivers, barred by coastal beaches. The phreatic aquifer develops at the base of the loess deposits, on the impervious red clay, overlapping the Sarmatian limestones. The medium depth aquifer is located in the altered and karstified Sarmatian limestones, and discharges into the Black Sea. The Sarmatian aquifer is unconfined where covered by silty loess deposits, and locally confined, where capped by clayey loess deposits. The aquifer is supplied from the Pre-Balkan Plateau. The Deep Upper Jurassic - Lower Cretaceous aquifer, located in the limestone and dolomite deposits, is generally confined and affected by the regional WNW - ESE and NNE - SSW fault system. In the south-eastern Dobrogea, the deep aquifer complex is separated from the Sarmatian aquifer by a Senonian aquitard (chalk and marls). The natural boundary of the Upper Jurassic - Lower Cretaceous aquifer is the Capidava - Ovidiu Fault. The piezometric heads show that the Upper Jurassic - Lower Cretaceous aquifer is supplied from the Bulgarian territory, where the Upper Jurassic deposits crop out. The aquifer discharges into the Black Sea to the east and into Lake Siutghiol to the northeast. The cyclic Upper Quaternary climate changes induced drastic remodeling of the Black Sea level and the corresponding shorelines. During the Last Glacial Maximum (MIS 2), the shoreline retreats eastwards, reaching the 100-120 m isobaths. In these conditions, the surface drainage base level was very low. Phreatic nape closely followed the river valleys dynamics. Mean depth aquifer discharged on the inner shelf , where Sarmatian limestones outcrop. The deep aquifer discharge was restricted by the Capidava- Ovidiu Fault to the north-east and by a presumed seawards longitudinal Fault. This process enabled the migration of the prehistoric human communities, from Asia to Europe, who established settlements on the newly created alluvial plain on the western Black Sea shelf. The Holocene Transgression (MIS 1) determined a sea level rise up to the modern one, and probably higher. Under the pressure of these environmental changes, the Neolithic settlements slowly retreated upstream. During the Greek colonization, the rising sea level caused the salinisation of the previous drinking water phreatic sources. In these conditions, in the Roman Age, a new hydraulic infrastructure had to be developed, using aqueducts for available inland water delivery.

Black Studies: A Key to the Future

ERIC Educational Resources Information Center

Johnson, Whittington B.; Nichols, Ted

1977-01-01

Concludes that black studies programs should develop an octopus-like academic structure which reaches out in several directions, simultaneously: initiating and illuminating, discerning and fostering, observing and directing, collecting and disseminating; all with one goal in view, exploring the black experience within a universal perspective.…

Demographic Correlates of Relationship Status among Black Americans.

ERIC Educational Resources Information Center

Tucker, M. Belinda; Taylor, Robert Joseph

1989-01-01

Analyzed National Survey of Black Americans data (N=2,107) to determine extent and structural correlates of marriage, romantic involvements, and preference for romantic involvement. Found marriage among Blacks dependent on male economic readiness and "traditionality"; fewer marital options for economically disadvantaged males, older…

Infrared fingerprints of few-layer black phosphorus

PubMed Central

Zhang, Guowei; Huang, Shenyang; Chaves, Andrey; Song, Chaoyu; Özçelik, V. Ongun; Low, Tony; Yan, Hugen

2017-01-01

Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Although highly desirable, a comprehensive infrared characterization is still lacking. Here we report a systematic infrared study of mechanically exfoliated few-layer black phosphorus, with thickness ranging from 2 to 15 layers and photon energy spanning from 0.25 to 1.36 eV. Each few-layer black phosphorus exhibits a thickness-dependent unique infrared spectrum with a series of absorption resonances, which reveals the underlying electronic structure evolution and serves as its infrared fingerprints. Surprisingly, unexpected absorption features, which are associated with the forbidden optical transitions, have been observed. Furthermore, we unambiguously demonstrate that controllable uniaxial strain can be used as a convenient and effective approach to tune the electronic structure of few-layer black phosphorus. Our study paves the way for black phosphorus applications in infrared photonics and optoelectronics. PMID:28059084

LDEF active optical system components experiment

NASA Technical Reports Server (NTRS)

Blue, M. D.

1992-01-01

A preliminary report on the Active Optical System Components Experiment is presented. This experiment contained 136 components in a six inch deep tray including lasers, infrared detectors and arrays, ultraviolet light detectors, light-emitting diodes, a light modulator, flash lamps, optical filters, glasses, and samples of surface finishes. Thermal, mechanical, and structural considerations leading to the design of the tray hardware are discussed. In general, changes in the retested component characteristics appear as much related to the passage of time as to the effects of the space environment, but organic materials, multilayer optical interference filters, and extreme-infrared reflectivity of black paints show unexpected changes.

pH-dependence of pesticide adsorption by wheat-residue-derived black carbon.

PubMed

Yang, Yaning; Chun, Yuan; Sheng, Guangyao; Huang, Minsheng

2004-08-03

The potential of black carbon as an adsorbent for pesticides in soils may be strongly influenced by the properties of the adsorbent and pesticides and by the environmental conditions. This study evaluated the effect of pH on the adsorption of diuron, bromoxynil, and ametryne by a wheat (Triticum aestivum L.) residue derived black carbon (WC) as compared to a commercial activated carbon (AC). The pH drift method indicated that WC had a point of zero charge of 4.2, much lower than that of 7.8 for AC. The density of oxygen-containing surface functional groups, measured by the Boehm titration, on WC was 5.4 times higher than that on AC, resulting in a pesticide adsorption by WC being 30-50% of that by AC, due to the blockage of WC surface by the waters associated with the functional groups. A small decrease (5.5%/unit pH) in diuron adsorption by WC with increase in pH resulted from increased deprotonation of surface functional groups at higher pH values. A much larger decrease (14-21%/unit pH) in bromoxynil adsorption by WC with increase in pH resulted from the deprotonation of both the adsorbate and surface functional groups of the adsorbent. The deprotonation reduced the adsorptive interaction between bromoxynil and the neutral carbon surface and increased the electrical repulsion between the negatively charged WC surface and bromoxynil anions. Deprotonation of ametryne with increase in pH over the low pH range increased its fraction of molecular form and thus adsorption on WC by 15%/unit pH. Further increase in pH resulted in a 20%/unit pH decrease in ametryne adsorption by WC due primarily to the development of a negative charge on the surface of WC. The pH-dependent adsorption of pesticides by black carbon may significantly influence their environmental fate in soils.

Relationships between soil microbial communities and soil carbon turnover along a vegetation and moisture gradient in interior Alaska

NASA Astrophysics Data System (ADS)

Waldrop, M. P.; Harden, J. W.; Turetsky, M. R.; Petersen, D. G.; McGuire, A. D.; Briones, M. J.; Churchill, A. C.; Doctor, D. H.; Pruett, L. E.

2010-12-01

Boreal landscapes are characterized by a mosaic of uplands and lowlands, which differ in plant species composition, litter biochemistry, and biogeochemical cycling rates. Boreal ecosystems, from upland black spruce stands to lowland fens, are structured largely by water table position and contain quantitatively and qualitatively different forms of soil organic matter. Differences in carbon (C) availability among ecosystems likely translate to differences in the structure of soil microbial communities, which in turn could affect rates of organic matter decomposition and turnover. We examined relationships between microbial communities and soil C turnover in near-surface soils along a topographic soil moisture and vegetation gradient in interior Alaska. We tested the hypothesis that upland black spruce sites would be dominated by soil fungi and have slow rates of C turnover, whereas lowland ecosystems would be dominated by bacteria and mesofauna (enchytraeids) and have more rapid rates of C turnover. We utilized several isotopic measures of soil C turnover including bomb radiocarbon techniques, the δ15N of SOM, and the difference between δ13C of SOM, DOC, and respired CO2. All three measures indicated greater C turnover rates in the surface soils of the lowland fen sites compared to the more upland locations. Quantitative PCR analyses of soil bacteria and archaea, combined with enchytraed counts, confirmed that surface soils from the lowland fen ecosystems had the highest abundances of these functional groups. Fungal biomass was highly variable and tended to be more abundant in the upland forest sites. Soil enzymatic results were mixed: potential cellulase activities were higher in the more upland soils even though rates of microbial activity were generally lower. Oxidative enzyme activities were higher in fens, even though these ecosystems are saturated and partly anaerobic. Overall our data support soil food web theory which argues that rapidly cycling systems are bacterial dominated with mesofaunal grazing, whereas slowly cycling systems have characteristic higher fungal:bacterial ratios.

Discrimination of acoustically similar conspecific and heterospecific vocalizations by black-capped chickadees (Poecile atricapillus).

PubMed

Hahn, Allison H; Campbell, Kimberley A; Congdon, Jenna V; Hoang, John; McMillan, Neil; Scully, Erin N; Yong, Joshua J H; Elie, Julie E; Sturdy, Christopher B

2017-07-01

Chickadees produce a multi-note chick-a-dee call in multiple socially relevant contexts. One component of this call is the D note, which is a low-frequency and acoustically complex note with a harmonic-like structure. In the current study, we tested black-capped chickadees on a between-category operant discrimination task using vocalizations with acoustic structures similar to black-capped chickadee D notes, but produced by various songbird species, in order to examine the role that phylogenetic distance plays in acoustic perception of vocal signals. We assessed the extent to which discrimination performance was influenced by the phylogenetic relatedness among the species producing the vocalizations and by the phylogenetic relatedness between the subjects' species (black-capped chickadees) and the vocalizers' species. We also conducted a bioacoustic analysis and discriminant function analysis in order to examine the acoustic similarities among the discrimination stimuli. A previous study has shown that neural activation in black-capped chickadee auditory and perceptual brain regions is similar following the presentation of these vocalization categories. However, we found that chickadees had difficulty discriminating between forward and reversed black-capped chickadee D notes, a result that directly corresponded to the bioacoustic analysis indicating that these stimulus categories were acoustically similar. In addition, our results suggest that the discrimination between vocalizations produced by two parid species (chestnut-backed chickadees and tufted titmice) is perceptually difficult for black-capped chickadees, a finding that is likely in part because these vocalizations contain acoustic similarities. Overall, our results provide evidence that black-capped chickadees' perceptual abilities are influenced by both phylogenetic relatedness and acoustic structure.

Peer social support is associated with recent HIV testing among young black men who have sex with men.

PubMed

Scott, Hyman M; Pollack, Lance; Rebchook, Gregory M; Huebner, David M; Peterson, John; Kegeles, Susan M

2014-05-01

Resiliency factors such as social support have been associated with more frequent HIV testing among MSM. We examined the association between social support and delayed HIV testing in the context of structural discrimination and individual factors among young Black MSM. We combined two independent cross-sectional samples recruited 1 year apart from a venue-based, modified time-location sampling study of young Black MSM aged 18-29 years in the US South. Our subsample (N = 813) was men who self-reported not being HIV positive and who indicated they had one or more male sex partners in the past 2 months. Using a social epidemiology framework we estimated associations of structural (racism and homophobia), social (social support from other Black MSM friends) and individual factors with delayed HIV testing (>6 months ago) using logistic regression. Bivariate analyses demonstrated that individual level variables as well as experiences of racism (OR 1.20, 95% CI 1.02-1.41) and homophobia (OR 1.49, 95 % CI 1.02-2.17) were associated with higher risk of delayed HIV testing. Receiving social support from other Black MSM friends was associated with lower risk of delayed HIV testing (OR 0.80, 95 % CI 0.67-0.95). In multivariable models, social support remained significantly associated with lower risk of delayed HIV testing after inclusion of structural and individual level variables. Social support has a positive and robust association with HIV testing among young Black MSM. Whether community building and development of resiliency factors can overcome structural, social, and individual-level barriers to HIV prevention and care for young Black MSM warrants further study.

Template directed assembly of nanoelements in viscous polymer environments

NASA Astrophysics Data System (ADS)

Modi, Satyamkumar

Polymer melt-based manufacturing methods, such as injection molding, offer the potential of directly fabricating three-dimensional parts with nanostructured surfaces in a one-step, high-rate, and solventless process. Electrophoretic deposition has the potential to produce in-mold assembly of nanoparticles during injection molding. The process is fast, is cost effective and can be automated. This electrophoretic deposition, however, has been performed from low-viscosity media and polymer melts are far more viscous. This research provided a fundamental understanding of the electrophoretic deposition process in viscous media. Electrophoresis was performed using a model system of carbon black and polystyrene in tetrahydrofuran (THF). Examined were the effects of processing parameters, polystyrene molecular weight, and carbon black charge. The presence of polystyrene did not prevent deposition of carbon black, but deposition rates decreased at shorter deposition times; deposition was not linear with increasing applied voltage; and greater solution concentrations reduced the critical voltages. A comparison of experimental data with Hamaker's model showed that about 1.6% of the available polystyrene was initially deposited with the carbon black. At voltages above the critical voltage, the deposited mass indicated formation of electrically insulating layers on the electrodes. Increases in polystyrene molecular weight reduced the electrophoretic deposition of the carbon black particles due to increases in suspension viscosity and preferential adsorption of the longer polystyrene chains on the carbon black particles. At low deposition times (≤ 5 seconds), only carbon black deposited onto the electrodes. For longer deposition times, polystyrene co-deposited with the carbon black, with the amount of polystyrene increasing with molecular weight and decreasing with greater charge on the polystyrene molecules. The additional of function groups to the carbon black surface decoupled the carbon black and polystyrene, however, the deposition of the carbon black particles, followed by deposition of a thick layer of polystyrene was observed. This polystyrene deposition was present regardless of the applied voltage, the deposition time, the polystyrene molecular weight, polystyrene material (i.e., charge), and solvent polarity. This deposition behavior suggests that use of lower molecular polymers and unmodified carbon blacks, and control of electrical properties will permit electrophoretic deposition of nanoparticles from polymer melts.

Synthesis of hydrophobic cross-linked polyzwitterionic acid for simultaneous sorption of Eriochrome black T and chromium ions from binary hazardous waters.

PubMed

Saleh, Tawfik A; Muhammad, Auwal M; Ali, Shaikh A

2016-04-15

Hydrophobic cross-linked polyzwitterionic acid (HCPZA) containing long chain (C18) hydrophobes and residues of a glutamic acid having unquenched nitrogen valency was synthesized. Exploiting the chelating ability of the amino acid residues to scavenge toxic metals and the hydrophobic surface to scoop up the organic contaminants, the resin HCPZA was evaluated for simultaneous removal of chromium and Eriochrome black T (EBT) from wastewaters. The structure and morphology of the polymer before and after sorption were characterized by using FTIR, TGA, EDX and SEM. The effect of various parameters such as contact time, pH and initial concentrations were investigated to arrive at optimum conditions. The adsorption of Eriochrome black T and Cr (III) on HCPZA reached equilibrium in 30 min. The mechanism of adsorption was investigated using kinetic, diffusion and isotherm models. The adsorption kinetic data were described well by the pseudo-second order model and by the Freundlich isotherm model. EDX analysis confirmed the adsorption of Cr (III) and EBT on the polymer. The hydrophobic resin exhibited a remarkable simultaneous adsorption capacity for EBT and Cr (III) and thus demonstrated its potential to be a promising adsorbent for removal of dyes and heavy metal ions from wastewaters. Copyright © 2016 Elsevier Inc. All rights reserved.

Successful nesting by a Bald Eagle pair in prairie grasslands of the Texas Panhandle

USGS Publications Warehouse

Boal, G.W.; Giovanni, M.D.; Beall, B.N.

2006-01-01

We observed a breeding Bald Eagle (Haliaeetus leitcocephalus) pair nesting in a short-grass prairie and agricultural community on the southern Great Plains of the Texas Panhandle in 2004 and 2005. The nesting eagles produced 1 fledgling in 2004 and 2 fledglings in 2005. Our assessment of landcover types within a 5-km radius of the nest indicated that grasslands accounted for most of the area (90%), followed by agricultural lands (8%). Black-tailed prairie dog (Cynomys ludovicianus) colonies occupied 2.5% of the area, and single human residences with associated structures (i.e., barns) occupied 2.5 ha in surface area was 51 km from the nest. An analysis of regurgitated castings collected near the nest revealed a mammalian-dominated, breeding-season diet with black-tailed prairie dogs occurring in 80.9% of the castings. Other identified prey included cottontails (Sylvilagus spp., 15.9%), black-tailed jackrabbits (Lepus californicus, 3.2%), pronghorn (Antilocapra americana, 3.2%), and plains pocket gopher (Geomys bursarius, 1.6%). Bird remains were also present in 34.9% of the castings. This is the first reported successful nesting of Bald Eagles in the panhandle region of Texas since 1916; the nest is particularly unique because of its distance from any substantial body of water.

Ascorbic acid deficiency, iron overload and alcohol abuse underlie the severe osteoporosis in black African patients with hip fractures--a bone histomorphometric study.

PubMed

Schnitzler, C M; Schnaid, E; MacPhail, A P; Mesquita, J M; Robson, H J

2005-02-01

Osteoporosis and femoral neck fractures (FNF) are uncommon in black Africans although osteoporosis accompanying iron overload (from traditional beer brewed in iron containers) associated with ascorbic acid deficiency (oxidative catabolism by iron) has been described from sub-Saharan Africa. This study describes histomorphometric findings of iliac crest bone biopsies and serum biochemical markers of iron overload and of alcohol abuse and ascorbic acid levels in 50 black patients with FNFs (29 M, 21 F), age 62 years (40-95) years (median [min-max]), and in age- and gender-matched black controls. We found evidence of iron overload in 88% of patients and elevated markers of alcohol abuse in 72%. Significant correlations between markers of iron overload and of alcohol abuse reflect a close association between the two toxins. Patients had higher levels of iron markers, i.e., siderin deposits in bone marrow (P < 0.0001), chemical non-heme bone iron (P = 0.012), and serum ferritin (P = 0.017) than controls did. Leukocyte ascorbic acid levels were lower (P = 0.0008) than in controls. The alcohol marker mean red blood cell volume was elevated (P = 0.002) but not liver enzymes or uric acid. Bone volume, trabecular thickness, and trabecular number were lower, and trabecular separation was greater in patients than in controls, all at P < 0.0005; volume, surface, and thickness of osteoid were lower and eroded surface was greater, all at P < 0.0001. There was no osteomalacia. Ascorbic acid deficiency accounted significantly for decrease in bone volume and trabecular number, and increase in trabecular separation, osteoid surface, and eroded surface; iron overload accounted for a reduction in mineral apposition rate. Alcohol markers correlated negatively with osteoblast surface and positively with eroded surface. Relative to reported data in white FNF patients, the osteoporosis was more severe, showed lower osteoid variables and greater eroded surface; FNFs occurred 12 years earlier and were more common among men. We conclude that the osteoporosis underlying FNFs in black Africans is severe, with marked uncoupling of resorption and formation in favor of resorption. All three factors--ascorbic acid deficiency, iron overload, and alcohol abuse--contributed to the osteoporosis, in that order.

Effects of Religious Involvement on Parent-child Communication Regarding Schooling: A Study of Black Youth in the United States

ERIC Educational Resources Information Center

Madyun, Na'im; Lee, Moosung

2010-01-01

A growing number of Black teens are becoming religiously involved. This undoubtedly intersects with another trend in Black communities, the changing structure of the Black family. Research has shown that school-related dialogue between parent and child is an important factor in educational outcomes. This study set out to determine if there might…

Black Student School Success: An Ethnographic Study in a Large Urban Public School System. A Preliminary Report Submitted to the Spencer Foundation.

ERIC Educational Resources Information Center

Fordham, Signithia

This preliminary report examines the complex relationship between black adolescents' school performance and black Americans' intragroup social organization, as well as the intrusive influence of the larger social structure. It is based on a two-year ethnographic study of high school students in a black section of Washington, D.C. Emphasis is on…

Electromagnetic Chirps from Neutron Star–Black Hole Mergers

NASA Astrophysics Data System (ADS)

Schnittman, Jeremy D.; Dal Canton, Tito; Camp, Jordan; Tsang, David; Kelly, Bernard J.

2018-02-01

We calculate the electromagnetic signal of a gamma-ray flare coming from the surface of a neutron star shortly before merger with a black hole companion. Using a new version of the Monte Carlo radiation transport code Pandurata that incorporates dynamic spacetimes, we integrate photon geodesics from the neutron star surface until they reach a distant observer or are captured by the black hole. The gamma-ray light curve is modulated by a number of relativistic effects, including Doppler beaming and gravitational lensing. Because the photons originate from the inspiraling neutron star, the light curve closely resembles the corresponding gravitational waveform: a chirp signal characterized by a steadily increasing frequency and amplitude. We propose to search for these electromagnetic chirps using matched filtering algorithms similar to those used in LIGO data analysis.

Electromagnetic Chirps from Neutron Star-Black Hole Mergers

NASA Technical Reports Server (NTRS)

Schnittman, Jeremy D.; Dal Canton, Tito; Camp, Jordan B.; Tsang, David; Kelly, Bernard J.

2018-01-01

We calculate the electromagnetic signal of a gamma-ray flare coming from the surface of a neutron star shortly before merger with a black hole companion. Using a new version of the Monte Carlo radiation transport code Pandurata that incorporates dynamic spacetimes, we integrate photon geodesics from the neutron star surface until they reach a distant observer or are captured by the black hole. The gamma-ray light curve is modulated by a number of relativistic effects, including Doppler beaming and gravitational lensing. Because the photons originate from the inspiraling neutron star, the light curve closely resembles the corresponding gravitational waveform: a chirp signal characterized by a steadily increasing frequency and amplitude. We propose to search for these electromagnetic chirps using matched filtering algorithms similar to those used in LIGO data analysis.

c-axis preferential orientation of hydroxyapatite accounts for the high wear resistance of the teeth of black carp (Mylopharyngodon piceus)

PubMed Central

Fu, Jimin; He, Chong; Xia, Biao; Li, Yan; Feng, Qiong; Yin, Qifang; Shi, Xinghua; Feng, Xue; Wang, Hongtao; Yao, Haimin

2016-01-01

Biological armors such as mollusk shells have long been recognized and studied for their values in inspiring novel designs of engineering materials with higher toughness and strength. However, no material is invincible and biological armors also have their rivals. In this paper, our attention is focused on the teeth of black carp (Mylopharyngodon piceus) which is a predator of shelled mollusks like snails and mussels. Nanoscratching test on the enameloid, the outermost layer of the teeth, indicates that the natural occlusal surface (OS) has much higher wear resistance compared to the other sections. Subsequent X-ray diffraction analysis reveals that the hydroxyapatite (HAp) crystallites in the vicinity of OS possess c-axis preferential orientation. The superior wear resistance of black carp teeth is attributed to the c-axis preferential orientation of HAp near the OS since the (001) surface of HAp crystal, which is perpendicular to the c-axis, exhibits much better wear resistance compared to the other surfaces as demonstrated by the molecular dynamics simulation. Our results not only shed light on the origin of the good wear resistance exhibited by the black carp teeth but are of great value to the design of engineering materials with better abrasion resistance. PMID:27001150

Mechanisms initiating deep convection over complex terrain during COPS.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kottmeier, C.; Kalthoff, N.; Barthlott, C.

2008-12-01

Precipitating convection in a mountain region of moderate topography is investigated, with particular emphasis on its initiation in response to boundary-layer and mid- and upper-tropospheric forcing mechanisms. The data used in the study are from COPS (Convective and Orographically-induced Precipitation Study) that took place in southwestern Germany and eastern France in the summer of 2007. It is found that the initiation of precipitating convection can be roughly classified as being due to either: (i) surface heating and low-level flow convergence; (ii) surface heating and moisture supply overcoming convective inhibition during latent and/or potential instability; or (iii) mid-tropospheric dynamical processes duemore » to mesoscale convergence lines and forced mean vertical motion. These phenomena have to be adequately represented in models in order to improve quantitative precipitation forecast. Selected COPS cases are analyzed and classified into these initiation categories. Although only a subset of COPS data (mainly radiosondes, surface weather stations, radar and satellite data) are used here, it is shown that convective systems are captured in considerable detail by sensor synergy. Convergence lines were observed by Doppler radar in the location where deep convection is triggered several hours later. The results suggest that in many situations, observations of the location and timing of convergence lines will facilitate the nowcasting of convection. Further on, forecasting of the initiation of convection is significantly complicated if advection of potentially convective air masses over changing terrain features plays a major role. The passage of a frontal structure over the Vosges - Rhine valley - Black Forest orography was accompanied by an intermediate suppression of convection over the wide Rhine valley. Further downstream, an intensification of convection was observed over the Black Forest due to differential surface heating, a convergence line, and the flow generated by a gust front.« less

Solar shutter arrangement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fulkerson, P.L.

1988-02-02

In a structure having a roof with a skylight including a glass panel which transmits solar energy, a shutter arrangement supported on the roof is described comprising an insulative flat one-piece solid shutter in the form of a panel selectively and linearly slidable on tracks which conceal the side edges thereof from a position blocking transmittal of solar energy through the glass panel of the skylight into an area within the structure to a position permitting transmittal of solar energy through the glass panel of the skylight into the area within the structure. The skylight presents a space between themore » glass panel and the selectively and linearly slidable insulative flat one-piece solid shutter, where the latter serves as the selective inner wall of the space contiguous with the area within the structure and the glass panel serves as the fixed outer wall of the space, where temperature responsive means is disposed within the space and in direct engagement with the inner surface of the glass panel, where the temperature responsive means is a black thermocouple operating a motor in a driving relationship with the insulative flat one-piece solid shutter. The insulative flat one-piece solid shutter is supported by a cable secured to a rotatable shaft controlled by the motor, where bi-directional movement of the rotatable shaft achieves raising and lowering of the insulative flat one-piece solid shutter to each of the solar energy blocking and transmittal positions, and where the insulative flat one-piece solid shutter includes a reflective surface facing the skylight and a decorative surface facing the area within the structure.« less

An easily implemented static condensation method for structural sensitivity analysis

NASA Technical Reports Server (NTRS)

Gangadharan, S. N.; Haftka, R. T.; Nikolaidis, E.

1990-01-01

A black-box approach to static condensation for sensitivity analysis is presented with illustrative examples of a cube and a car structure. The sensitivity of the structural response with respect to joint stiffness parameter is calculated using the direct method, forward-difference, and central-difference schemes. The efficiency of the various methods for identifying joint stiffness parameters from measured static deflections of these structures is compared. The results indicate that the use of static condensation can reduce computation times significantly and the black-box approach is only slightly less efficient than the standard implementation of static condensation. The ease of implementation of the black-box approach recommends it for use with general-purpose finite element codes that do not have a built-in facility for static condensation.

Investigation on imperfection sensitivity of composite cylindrical shells using the nonlinearity reduction technique and the polynomial chaos method

NASA Astrophysics Data System (ADS)

Liang, Ke; Sun, Qin; Liu, Xiaoran

2018-05-01

The theoretical buckling load of a perfect cylinder must be reduced by a knock-down factor to account for structural imperfections. The EU project DESICOS proposed a new robust design for imperfection-sensitive composite cylindrical shells using the combination of deterministic and stochastic simulations, however the high computational complexity seriously affects its wider application in aerospace structures design. In this paper, the nonlinearity reduction technique and the polynomial chaos method are implemented into the robust design process, to significantly lower computational costs. The modified Newton-type Koiter-Newton approach which largely reduces the number of degrees of freedom in the nonlinear finite element model, serves as the nonlinear buckling solver to trace the equilibrium paths of geometrically nonlinear structures efficiently. The non-intrusive polynomial chaos method provides the buckling load with an approximate chaos response surface with respect to imperfections and uses buckling solver codes as black boxes. A fast large-sample study can be applied using the approximate chaos response surface to achieve probability characteristics of buckling loads. The performance of the method in terms of reliability, accuracy and computational effort is demonstrated with an unstiffened CFRP cylinder.

Physical process first law and increase of horizon entropy for black holes in Einstein-Gauss-Bonnet gravity.

PubMed

Chatterjee, Ayan; Sarkar, Sudipta

2012-03-02

We establish the physical process version of the first law by studying small perturbations of a stationary black hole with a regular bifurcation surface in Einstein-Gauss-Bonnet gravity. Our result shows that when the stationary black hole is perturbed by a matter stress energy tensor and finally settles down to a new stationary state, the Wald entropy increases as long as the matter satisfies the null energy condition.

Medicine Delivery Device with Integrated Sterilization and Detection

NASA Technical Reports Server (NTRS)

Sheam, Michael J.; Greer, Harold F.; Manohara, Harish

2013-01-01

Sterile delivery devices can be created by integrating a medicine delivery instrument with surfaces that are coated with germicidal and anti-fouling material. This requires that a large-surface-area template be developed within a constrained volume to ensure good contact between the delivered medicine and the germicidal material. Both of these can be integrated using JPL-developed silicon nanotip or cryo-etch black silicon technologies with atomic layer deposition (ALD) coating of specific germicidal layers. Nanofabrication techniques that are used to produce a microfluidics device are also capable of synthesizing extremely hig-hsurface-area templates in precise locations, and coating those surfaces with conformal films to manipulate their surface properties. This methodology has been successfully applied at JPL to produce patterned and coated silicon nanotips (also known as black silicon) to manipulate the hydrophilicity of surfaces to direct the spreading of fluids in microdevices. JPL s ALD technique is an ideal method to produce the highly conformal coatings required for this type of application. Certain materials, such as TiO2, have germicidal and anti-fouling properties when they are illuminated with UV light. The proposed delivery device contacts medicine with this high-surface-area black silicon surface coated with a thin-film germicidal deposited conformally with ALD. The coating can also be illuminated with ultraviolet light for the purpose of sterilization or identification of the medicine itself. This constrained volume that is located immediately prior to delivery into a patient, ensures that the medicine delivery device is inherently sterile.

Mechanisms and chemistry of dye adsorption on manganese oxides-modified diatomite.

PubMed

Al-Ghouti, Mohammad A; Al-Degs, Yehya S; Khraisheh, Majeda A M; Ahmad, Mohammad N; Allen, Stephen J

2009-08-01

The investigations into structural changes which occur during adsorbent modification and the adsorption mechanisms are essential for an effective design of adsorption systems. Manganese oxides were impregnated onto diatomite to form the type known as delta-birnessite. Initial investigations established the effectiveness of manganese oxides-modified diatomite (MOMD) to remove basic and reactive dyes from aqueous solution. The adsorption capacity of MOMD for methylene blue (MB), hydrolysed reactive black (RB) and hydrolysed reactive yellow (RY) was 320, 419, and 204mg/g, respectively. Various analytical techniques were used to characterise the structure and the mechanisms of the dye adsorption process onto MOMD such as Fourier transform infrared (FTIR), X-ray diffraction (XRD) and atomic absorption spectrometry (A.A.). A small shift to higher values of the d-spacing of dye/MOMD was observed indicating that a small amount of the dye molecules were intercalated in the MOMD structure and other molecules were adsorbed on the external surface of MOMD. Two mechanisms of dye adsorption onto MOMD were proposed; intercalation of the dye in the octahedral layers and adsorption of the dye on the MOMD external surface. Moreover, the results demonstrated that the MOMD structure was changed upon insertion of MB and RY with an obvious decrease in the intensity of the second main peak of the MOMD X-ray pattern.

Discovery of riblets in a bird beak (Rynchops) for low fluid drag.

PubMed

Martin, Samuel; Bhushan, Bharat

2016-08-06

Riblet structures found on fast-swimming shark scales, such as those found on a mako shark, have been shown to reduce fluid drag. In previous experimental and modelling studies, riblets have been shown to provide drag reduction by lifting vortices formed in turbulent flow, decreasing overall shear stresses. Skimmer birds (Rynchops) are the only birds to catch fish in flight by flying just above the water surface with a submerged beak to fish for food. Because they need to quickly catch prey, reducing drag on their beak is advantageous. For the first time, riblet structures found on the beak of the skimmer bird have been studied experimentally and computationally for low fluid drag properties. In this study, skimmer replicas were studied for drag reduction through pressure drop in closed-channel, turbulent water flow. Pressure drop measurements are compared for black and yellow skimmer beaks in two configurations, and mako shark skin. In addition, two configurations of skimmer beak were modelled to compare drag properties and vortex structures. Results are discussed, and a conceptual model is presented to explain a possible drag reduction mechanism in skimmers.This article is part of the themed issue 'Bioinspired hierarchically structured surfaces for green science'. © 2016 The Author(s).

Chandra Uncovers New Evidence For Event Horizons Surrounding Black Holes

NASA Astrophysics Data System (ADS)

2001-01-01

SAN DIEGO -- Astronomers have used NASA's Chandra X-ray Observatory to study some of the darkest black holes yet observed. Their work strongly confirms the reality of the "event horizon," the one-way membrane around black holes predicted by Einstein's theory of relativity. The findings were presented today at the American Astronomical Society meeting by Drs. Michael Garcia, Jeffrey McClintock, Ramesh Narayan, and Stephen Murray of the Harvard-Smithsonian Center for Astrophysics and Dr. Paul Callanan of University College, Cork, Ireland. With results that fundamentally differ from earlier black hole studies, Garcia and his colleagues have shown that some recently discovered black holes are not only ultra-dense, but actually possess event horizons that "vacuum up" energy from their surroundings. "It is a bit odd to say we've discovered something by seeing almost nothing at all -- less than the smile of the Cheshire cat, so to speak," said Garcia, lead author on a paper submitted to the Astrophysical Journal, "but, in essence, this is what we have done." Using data from Chandra and previous X-ray satellites like ROSAT, the Chandra team studied a dozen "X-ray novas," so named because they occasionally erupt as brilliant X-ray sources then settle into decades of dormancy. The great outpouring of X rays is due to a stream of gas that is pulled from the surface of a Sun-like companion star onto a compact object, either a black hole or a neutron star. By comparing the energy output from the dormant X-ray novas, the team discovered that the sources with black holes emitted only one percent as much energy while dormant as did the X-ray novae with neutron stars. "The most straightforward explanation of these observations is that the black hole candidates we have studied have event horizons that swallow just about all of the energy that surrounds them," said Murray. "Indeed, one could even say that this work shows why black holes deserve to be called ‘black.’" "The event horizon is the defining characteristic of a black hole, but obviously it is very difficult to detect since any infalling material at the event horizon is observable for only an instant as it plunges inward at the speed of light," said McClintock. "The comparison of black holes and their close cousins, the neutron stars, may be the most promising way to get a handle on the event horizon." If the collapsed star is a neutron star with a solid surface, energy must be released when infalling matter strikes that surface. In contrast, if the accreting object is a black hole, there is no surface for the matter to strike. Instead, both the energy and the matter will be lost from view forever once they cross the event horizon. A small amount of energy can escape just before the matter crosses the event horizon, but the scientists believe that it should be much less than the energy released by matter hitting a neutron star surface. "Watching matter flowing into a black hole is like sitting upstream of a waterfall and watching the water seemingly vanish over the edge," said Narayan, chairman of the Harvard Astronomy Department. "However, if the waterfall were replaced by a dam -- the analog of a neutron star surface -- then the water would pile up and one would see a mighty lake". Why are dormant black hole sources a hundred times fainter than the neutron star sources? The amount of material falling towards the collapsed star and the subsequent energy release are believed to be nearly the same, whether the compact object is a black hole or a neutron star. Therefore, the remarkable difference in brightness comes, according to the team, because of the event horizon, where the inward pull of gravity becomes infinitely strong. This is in contrast to the situation of neutron stars that have a more normal surface. By observing the motion of the companion star in an X-ray nova, the mass of the collapsed star can be estimated. In some cases, this mass is more than three times that of the Sun. Over that limit, gravitational forces would crush a neutron star or any compact object into a black hole, according to Einstein’s relativity theory. This provides a crucial test for identifying black holes. "It is difficult to appreciate the astounding sensitivity of Chandra to X rays," said Callanan. "For the faintest black hole we detected, Chandra measured literally a handful of photons." The researchers used the Advanced CCD Imaging Spectrometer (ACIS) on the Chandra X-ray Observatory for exposure times varying roughly from 10,000 to 40,000 seconds per object. The ACIS X-ray camera was developed for NASA by Pennsylvania State University and MIT. NASA's Marshall Space Flight Center in Huntsville, AL, manages the Chandra program. TRW, Inc., Redondo Beach, California, is the prime contractor for the spacecraft. The Smithsonian's Chandra X-ray Center controls science and flight operations from Cambridge, MA. This work was supported by funds from NASA and NSF. During the AAS meeting, the scientists involved in this release can be reached at the AAS Press Room at the Town & Country Resort in San Diego, CA. The phone numbers for the Press Room are (619) 908-5057, (619) 908-5040, and (619) 908-5041 from January 8-11. Images associated with this release are available on the World Wide Web at: http://chandra.harvard.edu AND http://chandra.nasa.gov

Analytical high resolution microscopic investigation of organic coating on co-composted biochar

NASA Astrophysics Data System (ADS)

Albu, Mihaela; Mayrhofer, Claudia; Hagemann, Nikolas; Joseph, Stephen; Hofer, Ferdinand; Kothleitner, Gerald

2017-04-01

Aged and/or co-composted biochar amendment improves soil fertility by changing certain proprieties like the porosity and sorption capacity, the redox properties, water holding capacity and nutrient transformations in soil. The beneficial properties have been correlated with surface functional groups resulting from the interactions between black carbon particles, inorganic and organic matter in the soil and soil biota, manure or other compost feedstock. As a result, porous organic layer and organo-mineral phases on the biochar surfaces are formed. This paper presents a detailed analysis of the porous layer and organo-mineral phases formed on co-composted biochar by using high resolution scanning transmission electron microscopy (STEM) and electron energy loss (EELS) as well as energy dispersive X-ray spectroscopy (EDX). The fine structure fingerprints of carbon and nitrogen edges have been used to identify the functional groups, while EDX was used to identify the mineral phases. However, in order to achieve undoubtable results a novel preparation technic of the sample has been developed. The preparation involved 3D gold sputtering on the black carbon particles in order to preserve the surface intact, embedding in resin and, ultrathin microtome cutting. The investigation was carried out using a probe corrected Titan 3G, at a voltage of 60 kV and in cryo-condition, with an EELS energy resolution of 0.15 eV and a spatial resolution down to atomic layers. We proved the presence of both C and N functional groups in the porous, heterogeneous and hydrophilic organic layer and organo-mineral agglomerates. The organic layer fully covered the outer surface of the black carbon piece, but also the surface of internal pores. Its thickness varied from 500-1000 nm on the outer surface down to a couple of nanometres on internal pores. The observed C functional groups have been identified to correspond to: aromatic, aromatic with side chain, ketone, aliphatic, carboxyl/amine carbon and, carbonyl while the N functional groups were: pyridine, imine, amide/peptide, pyrrole, and NO2-/oxidised N. The STEM analysis also revealed the formation of complex organo-mineral agglomerates involving Ca but also the redox-active Fe as iron oxide nnanoparticles and P as magnesium phosphate nnanoparticles. These findings are valuable information which contributes to the understanding of biochar reactions with soil and plants as a function of agronomic practice and environmental factors. Acknowledgment This research received funding from the European Union Seventh Framework Programme under Grant Agreement 312483 - ESTEEM2 (Integrated Infrastructure Initiative-I3).

New Method to Synthesize Highly Active and Durable Chemically Ordered fct-PtCo Cathode Catalyst for PEMFCs.

PubMed

Jung, Won Suk; Popov, Branko N

2017-07-19

In the bottom-up synthesis strategy performed in this study, the Co-catalyzed pyrolysis of chelate-complex and activated carbon black at high temperatures triggers the graphitization reaction which introduces Co particles in the N-doped graphitic carbon matrix and immobilizes N-modified active sites for the oxygen reduction reaction (ORR) on the carbon surface. In this study, the Co particles encapsulated within the N-doped graphitic carbon shell diffuse up to the Pt surface under the polymer protective layer and forms a chemically ordered face-centered tetragonal (fct) Pt-Co catalyst PtCo/CCCS catalyst as evidenced by structural and compositional studies. The fct-structured PtCo/CCCS at low-Pt loading (0.1 mg Pt cm -2 ) shows 6% higher power density than that of the state-of-the-art commercial Pt/C catalyst. After the MEA durability test of 30 000 potential cycles, the performance loss of the catalyst is negligible. The electrochemical surface area loss is less than 40%, while that of commercial Pt/C is nearly 80%. After the accelerated stress test, the uniform catalyst distribution is retained and the mean particle size increases approximate 1 nm. The results obtained in this study indicated that highly stable compositional and structural properties of chemically ordered PtCo/CCCS catalyst contribute to its exceptional catalyst durability.

Highly damped quasinormal modes and the small scale structure of quantum corrected black hole exteriors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Babb, James; Kunstatter, Gabor; Daghigh, Ramin

2011-10-15

Quasinormal modes provide valuable information about the structure of spacetime outside a black hole. There is also a conjectured relationship between the highly damped quasinormal modes and the semiclassical spectrum of the horizon area/entropy. In this paper, we show that for spacetimes characterized by more than one scale, the 'infinitely damped' modes in principle probe the structure of spacetime outside the horizon at the shortest length scales. We demonstrate this with the calculation of the highly damped quasinormal modes of the nonsingular, single-horizon, quantum corrected black hole derived in [A. Peltola and G. Kunstatter, Phys. Rev. D 79, 061501 (2009);more » ].« less

Black soiling of an architectural limestone during two-year term exposure to urban air in the city of Granada (S Spain).

PubMed

Urosevic, Maja; Yebra-Rodríguez, Africa; Sebastián-Pardo, Eduardo; Cardell, Carolina

2012-01-01

A two-year term aging test was carried out on a building limestone under different urban conditions in the city of Granada (Southern Spain) to assess its Cultural Heritage sustainability. For this purpose stone tablets were placed vertically at four sites with contrasting local pollution micro-environments and exposure conditions (rain-sheltered and unsheltered). The back (rain-sheltered) and the front (rain-unsheltered) faces of the stone tablets were studied for each site. The soiling process (surface blackening) was monitored through lightness (ΔL*) and chroma changes (ΔC*). Additionally atmospheric particles deposited on the stone surfaces and on PM10 filters during the exposure time were studied through a multianalytical approach including scanning electron microscopy (SEM-EDX), transmission electron microscopy (TEM) and micro-Raman spectroscopy. The identified atmospheric particles (responsible for stone soiling) were mainly soot and soil dust particles; also fly ash and aged salt particles were found. The soiling process was related to surface texture, exposure conditions and proximity to dense traffic streets. On the front faces of all stones, black soiling and surface roughness promoted by differential erosion between micritic and sparitic calcite were noticed. Moreover, it was found that surface roughness enhanced a feedback process that triggers further black soiling. The calculated effective area coverage (EAC) by light absorbing dust ranged from 10.2 to 20.4%, exceeding by far the established value of 2% EAC (limit perceptible to the human eye). Soiling coefficients (SC) were estimated based on square-root and bounded exponential fittings. Estimated black carbon (BC) concentration resulted in relatively similar SC for all studied sites and thus predicts the soiling process better than using particulate matter (PM10) concentration. Copyright © 2011 Elsevier B.V. All rights reserved.

The microstructure and formation of duplex and black plessite in iron meteorites

NASA Technical Reports Server (NTRS)

Zhang, J.; Williams, D. B.; Goldstein, J. I.

1993-01-01

Two of the most common plessite structures, duplex and black plessite, in the taenite region of the Windmanstatten pattern of two iron meteorites (Grant and Carlton) are characterized using high-resolution electron microscopy and microanalysis techniques. Two types of gamma precipitates, found in the duplex plessite and black plessite regions, respectively, are identified, and their morphologies are described. The formation of the plessite structure is discussed using the information obtained in this study and results of a parallel investigation of decomposed martensitic Fe-Ni laboratory alloys.

Properties of the instantaneous ergo surface of a Kerr black hole

NASA Astrophysics Data System (ADS)

Pelavas, Nicos; Neary, Nicholas; Lake, Kayll

2001-04-01

{This paper explores properties of the instantaneous ergo surface of a Kerr black hole. The surface area is evaluated in closed form. In terms of the mass (m) and angular velocity (a), to second order in a, the area of the ergo surface is given by 16πm2 + 4πa2 (compared to the familiar 16πm2-4πa2 for the event horizon). Whereas the total curvature of the instantaneous event horizon is 4π, on the ergo surface it ranges from 4π (for a = 0) to 0 (for a = m) due to conical singularities on the axis (θ = 0,π) of deficit angle 2π(1-(1-(a/m)2)1/2). A careful application of the Gauss-Bonnet theorem shows that the ergo surface remains topologically spherical. Isometric embeddings of the ergo surface in Euclidean 3-space are defined for 0≤a/m≤1 (compared to 0≤a/m≤(3)1/2/2 for the horizon).

Microtextured metals for stray-light suppression in the Clementine startracker

NASA Technical Reports Server (NTRS)

Johnson, E. A.

1993-01-01

Anodized blacks for suppressing stray light in optical systems can now be replaced by microscopically textured metal surfaces. An application of these black surfaces to the Clementine star-tracker navigational system, which will be launched in early 1994 to examine the Moon, en route to intercept an asteroid, is detailed. Rugged black surfaces with Lambertian BRDF less than 10(exp -2) srad(sup -1) are critical for suppressing stray light in the star-tracker optical train. Previously available materials spall under launch vibrations to contaminate mirrors and lenses. Microtextured aluminum is nearly as dark, but much less fragile. It is made by differential ion beam sputtering, which generates light-trapping pores and cones slightly smaller than the wavelength to be absorbed. This leaves a sturdy but light-absorbing surface that can survive challenging conditions without generating debris or contaminants. Both seeded ion beams and plasma immersion (from ECR plasmas) extraction can produce these microscopic textures without fragile interfaces. Process parameters control feature size, spacing, and optical effects (THR, BRDF). Both broad and narrow absorption bands can be engineered with tuning for specific wavelengths and applications. Examples are presented characterized by FTIR in reflection librators (0.95 normal emissivity), heat rejection, and enhanced nucleate boiling.

Noble metal free photocatalytic H 2 generation on black TiO 2: On the influence of crystal facets vs. crystal damage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Ning; Steinrück, Hans-Georg; Osvet, Andres

In this study, we investigate noble metal free photocatalytic water splitting on natural anatase single crystal facets and on wafer slices of the [001] plane before and after these surfaces have been modified by high pressure hydrogenation and hydrogen ion-implantation. Here, we find that on the natural, intact low index planes, photocatalytic H 2 evolution (in the absence of a noble metal co-catalyst) can only be achieved when the hydrogenation treatment is accompanied by the introduction of crystal damage, such as simple scratching and miscut in the crystal, or by implantation damage. X-ray reflectivity, Raman, and optical reflection measurements showmore » that plain hydrogenation leads to a ≈ 1 nm thick black titania surface layer without activity, while a colorless, density modified, and ≈7 nm thick layer with broken crystal symmetry is present on the ion implanted surface. These results demonstrate that (i) the H-treatment of an intact anatase surface needs to be combined with defect formation for catalytic activation and (ii) activation does not necessarily coincide with the presence of black color.« less

Noble metal free photocatalytic H 2 generation on black TiO 2: On the influence of crystal facets vs. crystal damage

DOE PAGES

Liu, Ning; Steinrück, Hans-Georg; Osvet, Andres; ...

2017-02-13

In this study, we investigate noble metal free photocatalytic water splitting on natural anatase single crystal facets and on wafer slices of the [001] plane before and after these surfaces have been modified by high pressure hydrogenation and hydrogen ion-implantation. Here, we find that on the natural, intact low index planes, photocatalytic H 2 evolution (in the absence of a noble metal co-catalyst) can only be achieved when the hydrogenation treatment is accompanied by the introduction of crystal damage, such as simple scratching and miscut in the crystal, or by implantation damage. X-ray reflectivity, Raman, and optical reflection measurements showmore » that plain hydrogenation leads to a ≈ 1 nm thick black titania surface layer without activity, while a colorless, density modified, and ≈7 nm thick layer with broken crystal symmetry is present on the ion implanted surface. These results demonstrate that (i) the H-treatment of an intact anatase surface needs to be combined with defect formation for catalytic activation and (ii) activation does not necessarily coincide with the presence of black color.« less

Nitric Acid Uptake and Decomposition on Black Carbon (Soot) Surfaces: Its Implications for the Upper Troposphere and Lower Stratosphere

NASA Technical Reports Server (NTRS)

Choi, W.; Leu, M. T.

1998-01-01

Black carbon particles (soot) are formed as a result of incomplete combustion processes and are ubiquitous in the atmosphere. The lower troposphere contains plenty of soot particles whose principal sources are fossil fuel and biomass combustion at the ground level.

Job Orientation of Black and White College Graduates in Business.

ERIC Educational Resources Information Center

Brenner, O. C.; Tomkiewicz, Joseph

1982-01-01

Examined differences in job orientation between Black and White male and female business college graduates. Significant race differences were found. Factor analysis indicates that Blacks value long-range career objectives and structure considerably more than do Whites, while their preference for intrinsic and extrinsic factors was less pronounced.…

Sex Role Socialization and Perception of Opportunity Structure: Impact on Educational and Occupational Decisions of Black Females.

ERIC Educational Resources Information Center

McRae, Mary B.

1990-01-01

The overrepresentation of Black females in traditional occupations stems from the emotions, beliefs, and environmental factors affecting their decision making. Conflicts between sex role socialization and that of Black subculture, as well as discrimination in hiring, are contributing factors. (SK)

Black holes and the multiverse

NASA Astrophysics Data System (ADS)

Garriga, Jaume; Vilenkin, Alexander; Zhang, Jun

2016-02-01

Vacuum bubbles may nucleate and expand during the inflationary epoch in the early universe. After inflation ends, the bubbles quickly dissipate their kinetic energy; they come to rest with respect to the Hubble flow and eventually form black holes. The fate of the bubble itself depends on the resulting black hole mass. If the mass is smaller than a certain critical value, the bubble collapses to a singularity. Otherwise, the bubble interior inflates, forming a baby universe, which is connected to the exterior FRW region by a wormhole. A similar black hole formation mechanism operates for spherical domain walls nucleating during inflation. As an illustrative example, we studied the black hole mass spectrum in the domain wall scenario, assuming that domain walls interact with matter only gravitationally. Our results indicate that, depending on the model parameters, black holes produced in this scenario can have significant astrophysical effects and can even serve as dark matter or as seeds for supermassive black holes. The mechanism of black hole formation described in this paper is very generic and has important implications for the global structure of the universe. Baby universes inside super-critical black holes inflate eternally and nucleate bubbles of all vacua allowed by the underlying particle physics. The resulting multiverse has a very non-trivial spacetime structure, with a multitude of eternally inflating regions connected by wormholes. If a black hole population with the predicted mass spectrum is discovered, it could be regarded as evidence for inflation and for the existence of a multiverse.

Black holes and the multiverse

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garriga, Jaume; Vilenkin, Alexander; Zhang, Jun, E-mail: jaume.garriga@ub.edu, E-mail: vilenkin@cosmos.phy.tufts.edu, E-mail: jun.zhang@tufts.edu

Vacuum bubbles may nucleate and expand during the inflationary epoch in the early universe. After inflation ends, the bubbles quickly dissipate their kinetic energy; they come to rest with respect to the Hubble flow and eventually form black holes. The fate of the bubble itself depends on the resulting black hole mass. If the mass is smaller than a certain critical value, the bubble collapses to a singularity. Otherwise, the bubble interior inflates, forming a baby universe, which is connected to the exterior FRW region by a wormhole. A similar black hole formation mechanism operates for spherical domain walls nucleatingmore » during inflation. As an illustrative example, we studied the black hole mass spectrum in the domain wall scenario, assuming that domain walls interact with matter only gravitationally. Our results indicate that, depending on the model parameters, black holes produced in this scenario can have significant astrophysical effects and can even serve as dark matter or as seeds for supermassive black holes. The mechanism of black hole formation described in this paper is very generic and has important implications for the global structure of the universe. Baby universes inside super-critical black holes inflate eternally and nucleate bubbles of all vacua allowed by the underlying particle physics. The resulting multiverse has a very non-trivial spacetime structure, with a multitude of eternally inflating regions connected by wormholes. If a black hole population with the predicted mass spectrum is discovered, it could be regarded as evidence for inflation and for the existence of a multiverse.« less

Gender Differences in the Structure and Support Characteristics of Black Adolescents' Social Networks.

ERIC Educational Resources Information Center

Coates, Deborah L.

1987-01-01

Examination of 390 Black American adolescents demonstrates that males and females experience very different structured forms of social support. Females report more frequent contact with network members, who were both male and female, slightly older, and met in private settings. Males report larger groups of intimate friends, who are overwhelmingly…

Economic distress and cause-of-death patterns for black and non-black men in Chicago: reconsidering the relevance of classic epidemiological transition theory.

PubMed

Palazzo, Lorella; Guest, Avery; Almgren, Gunnar

2003-01-01

The mortality disadvantage of African Americans is well documented, but previous studies have not considered its implications for population theory in the general case of industrialized nation states with high levels of income inequality. This paper examines the relevance of classic epidemiological theory to the extremes of income and mortality observed in Chicago, one of America's most racially divided cities. We analyze cause-specific death rates for black and non-black male populations residing in Chicago's community areas by using linked data from the 1990 Census and from 1989-1991 individual death certificates. The same cause-of-death patterns explain much of the mortality of black and non-black men. These two major structures include one, degenerative diseases, the other, "tough-living" causes (accidents, homicides, and liver disease). Community socioeconomic status is strongly related to tough-living deaths within each racial group, and to degenerative deaths for African Americans. Black men's tough-living mortality is much greater than non-blacks', but their younger age structure suppresses their degenerative death rates. Aggregate unemployment and social disorganization account for the most salient disparities in mortality across racial groups. This patterning of mortality along a socioeconomic continuum supports epidemiological theory and extends its applicability to highly unequal populations within industrialized countries.

Distinguishability of black hole microstates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bao, Ning; Ooguri, Hirosi

We use the Holevo information to estimate distinguishability of microstates of a black hole in anti-de Sitter space by measurements one can perform on a subregion of a Cauchy surface of the dual conformal field theory. We find that microstates are not distinguishable at all until the subregion reaches a certain size and that perfect distinguishability can be achieved before the subregion covers the entire Cauchy surface. We will then compare our results with expectations from the entanglement wedge reconstruction, tensor network models, and the bit threads interpretation of the Ryu-Takayanagi formula.

Distinguishability of black hole microstates

DOE PAGES

Bao, Ning; Ooguri, Hirosi

2017-09-01

We use the Holevo information to estimate distinguishability of microstates of a black hole in anti-de Sitter space by measurements one can perform on a subregion of a Cauchy surface of the dual conformal field theory. We find that microstates are not distinguishable at all until the subregion reaches a certain size and that perfect distinguishability can be achieved before the subregion covers the entire Cauchy surface. We will then compare our results with expectations from the entanglement wedge reconstruction, tensor network models, and the bit threads interpretation of the Ryu-Takayanagi formula.

Self-organized, effective medium black silicon antireflection structures for silicon optics in the mid-infrared

NASA Astrophysics Data System (ADS)

Steglich, Martin; Käsebier, Thomas; Kley, Ernst-Bernhard; Tünnermann, Andreas

2016-09-01

Thanks to its high quality and low cost, silicon is the material of choice for optical devices operating in the mid-infrared (MIR; 2 μm to 6 μm wavelength). Unfortunately in this spectral region, the refractive index is comparably high (about 3.5) and leads to severe reflection losses of about 30% per interface. In this work, we demonstrate that self-organized, statistical Black Silicon structures, fabricated by Inductively Coupled Plasma Reactive Ion Etching (ICP-RIE), can be used to effectively suppress interface reflection. More importantly, it is shown that antireflection can be achieved in an image-preserving, non-scattering way. This enables Black Silicon antireflection structures (ARS) for imaging applications in the MIR. It is demonstrated that specular transmittances of 97% can be easily achieved on both flat and curved substrates, e.g. lenses. Moreover, by a combined optical and morphological analysis of a multitude of different Black Silicon ARS, an effective medium criterion for the examined structures is derived that can also be used as a design rule for maximizing sample transmittance in a desired wavelength range. In addition, we show that the mechanical durability of the structures can be greatly enhanced by coating with hard dielectric materials like diamond-like carbon (DLC), hence enabling practical applications. Finally, the distinct advantages of statistical Black Silicon ARS over conventional AR layer stacks are discussed: simple applicability to topological substrates, absence of thermal stress and cost-effectiveness.

Spacetime and orbits of bumpy black holes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vigeland, Sarah J.; Hughes, Scott A.

2010-01-15

Our Universe contains a great number of extremely compact and massive objects which are generally accepted to be black holes. Precise observations of orbital motion near candidate black holes have the potential to determine if they have the spacetime structure that general relativity demands. As a means of formulating measurements to test the black hole nature of these objects, Collins and Hughes introduced ''bumpy black holes'': objects that are almost, but not quite, general relativity's black holes. The spacetimes of these objects have multipoles that deviate slightly from the black hole solution, reducing to black holes when the deviation ismore » zero. In this paper, we extend this work in two ways. First, we show how to introduce bumps which are smoother and lead to better behaved orbits than those in the original presentation. Second, we show how to make bumpy Kerr black holes--objects which reduce to the Kerr solution when the deviation goes to zero. This greatly extends the astrophysical applicability of bumpy black holes. Using Hamilton-Jacobi techniques, we show how a spacetime's bumps are imprinted on orbital frequencies, and thus can be determined by measurements which coherently track the orbital phase of a small orbiting body. We find that in the weak field, orbits of bumpy black holes are modified exactly as expected from a Newtonian analysis of a body with a prescribed multipolar structure, reproducing well-known results from the celestial mechanics literature. The impact of bumps on strong-field orbits is many times greater than would be predicted from a Newtonian analysis, suggesting that this framework will allow observations to set robust limits on the extent to which a spacetime's multipoles deviate from the black hole expectation.« less

The Canadian war on drugs: structural violence and unequal treatment of Black Canadians.

PubMed

Khenti, Akwatu

2014-03-01

This paper examines the impact of Canada's war on drugs on segments of the Black community, specifically with respect to the impact of structural violence, over-policing, and high incarceration rates. It offers evidence of the systemic nature of these dynamics by examining the early context of the war, growing stigma against Blacks, globalizing influences, and the punitive focus of funding and policy. The paper also explores how Black men have been identified as the main enemy and how drug control efforts have served to diminish the health, well-being, and self-image of Black men via discriminatory and inequitable treatment before the law. The current high rates of imprisonment of Black men are an indicator of systematic deprivation of significant social capital, which will perpetuate socioeconomic harm and cycles of violence. This commentary calls for an immediate dissolution of policies regulating the war on drugs as the first step in remedying the injustices experienced by Black Canadians. Due to the lack of Canadian data in this important area, the paper also emphasizes the critical need for more research to shed more light on the Canadian-specific complexities. Copyright © 2013 Elsevier B.V. All rights reserved.