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Sample records for boiler tube coatings

  1. Evaluation of Iron Aluminide Weld Overlays for Erosion-Corrosion Resistant Boiler Tube Coatings in Low NOx Boilers

    SciTech Connect

    Regina, J.R.; Lim, M.; Barbosa, N., DuPont, J.N.; Marder, A.R.

    2000-04-28

    Iron aluminide weld overlays containing ternary additions and thermal spray coatings are being investigated for corrosion protection of boiler tubes in Low NO{sub x} burners. The primary objective of the research is to identify overlay and thermal spray compositions that provide corrosion protection of waterwall boiler tubes.

  2. Nickel-chromium plasma spray coatings: A way to enhance degradation resistance of boiler tube steels in boiler environment

    SciTech Connect

    Sidhu, B.S.; Prakash, S.

    2006-03-15

    Boiler tube steels, namely low carbon steel ASTM-SA210-Grade A1 (GrA1), 1Cr-0.5Mo steel ASTM-SA213-T-11 (T11), and 2.25Cr-1Mo steel ASTM-SA213-T-22 (T22), were used as substrate steels. Ni-22Cr-10AI-1Y powder was sprayed as a bond coat 150 {mu}m thick before a 200 {mu}m final coating of Ni-20Cr was applied. Coatings were characterized prior to testing in the environment of a coal fired boiler. The uncoated and coated steels were inserted in the platen superheater zone of a coal fired boiler at around 755{sup o}C for 10 cycles, each 100 h. Coated steels showed lower degradation (erosion-corrosion) rate than uncoated steels showed. The lowest rate was observed in the case of Ni-20Cr coated T11 steel. Among the uncoated steels, the observed rate of degradation was the lowest for the T22 steel.

  3. Evaluation of Iron Aluminide Weld Overlays for Erosion-Corrosion Resistant Boiler Tube Coatings in Low NOx Boilers

    SciTech Connect

    Regina, J.R.

    2000-05-16

    Iron aluminide weld overlays containing ternary additions and thermal spray coatings are being investigated for corrosion protection of boiler tubes in Low NOx burners. The primary objective of the research is to identify overlay and thermal spray compositions that provide corrosion protection of waterwall boiler tubes. In the current phase of work, preliminary corrosion tests were conducted on a binary Fe-Al alloy in multiple complex gases to determine which gases will be used for testing of the ternary alloys. Preliminary solid-state corrosion tests were also conducted to simulate slag-metal interactions seen in Low NOx furnaces. Two powder compositions were chosen for testing of the ternary alloys. A matrix of alloys to be tested in both gaseous and solid-state corrosion experiments was produced based on corrosion literature.

  4. Iron aluminide weld overlay coatings for boiler tube protection in coal-fired low NOx boilers

    SciTech Connect

    Banovic, S.W.; DuPont, J.N.; Marder, A.R.

    1997-12-01

    Iron aluminide weld overlay coatings are currently being considered for enhanced sulfidation resistance in coal-fired low NO{sub x} boilers. The use of these materials is currently limited due to hydrogen cracking susceptibility, which generally increases with an increase in aluminum concentration of the deposit. The overall objective of this program is to attain an optimum aluminum content with good weldability and improved sulfidation resistance with respect to conventional materials presently in use. Research has been initiated using Gas Tungsten Arc Welding (GTAW) in order to achieve this end. Under different sets of GTAW parameters (wire feed speed, current), both single and multiple pass overlays were produced. Characterization of all weldments was conducted using light optical microscopy, scanning electron microscopy, and electron probe microanalysis. Resultant deposits exhibited a wide range of aluminum contents (5--43 wt%). It was found that the GTAW overlays with aluminum contents above {approximately}10 wt% resulted in cracked coatings. Preliminary corrosion experiments of 5 to 10 wt% Al cast alloys in relatively simple H{sub 2}/H{sub 2}S gas mixtures exhibited corrosion rates lower than 304 stainless steel.

  5. Evaluation of iron aluminide weld overlays for erosion - corrosion resistant boiler tube coatings in low NO{sub x} boilers

    SciTech Connect

    DuPont, J.N.; Banovic, S.W.; Marder, A.R.

    1996-08-01

    Low NOx burners are being installed in many fossil fired power plants in order to comply with new Clean Air Regulations. Due to the operating characteristics of these burners, boiler tube sulfidation corrosion is often enhanced and premature tube failures can occur. Failures due to oxidation and solid particle erosion are also a concern. A program was initiated in early 1996 to evaluate the use of iron aluminide weld overlays for erosion/corrosion protection of boiler tubes in Low NOx boilers. Composite iron/aluminum wires will be used with the Gas Metal Arc Welding (GMAW) process to prepare overlays on boiler tubes steels with aluminum contents from 8 to 16wt%. The weldability of the composite wires will be evaluated as a function of chemical composition and welding parameters. The effect of overlay composition on corrosion (oxidation and sulfidation) and solid particle erosion will also be evaluated. The laboratory studies will be complemented by field exposures of both iron aluminide weld overlays and co-extruded tubing under actual boiler conditions.

  6. Boiler tube failure reduction program

    SciTech Connect

    Lamping, G.A. ); Jonas, O. ); Niebo, R.J. )

    1991-08-01

    Boiler tube failures are generally recognized as the major cause of forced outages of fossil power generating units for US electric utilities. In almost all cases of serious availability losses, the boiler tube failures are repeat in nature and result in multiple forced outages. Primary factors influencing repeat, rather than random, tube failures are usually found to result from not following state-of-the-art operating, maintenance and/or engineering practices, lack of proper tube failure analysis, wrong choice of corrective/preventive action or solution, and lack of a tube failure reporting and monitoring system. A proven way to prevent costly repeat failures is to implement a formalized Boiler Tube Failure Prevention Program that is supported by senior management and focuses attention and resources on operating, maintenance and engineering controllable parameters that influence repeat tube failures. This report describes such a program, implemented at sixteen utilities under EPRI Research Project RP 1890-7, Boiler Tube Failure Reduction Program.'' Results are presented for ten utilities that began the program in the summer of 1986 with over four years of participation, and for six additional utilities from June of 1988 through December 1990. Both sets of utilities have produced remarkable improvements, the most tangible being substantial reductions in equivalent availability factor losses due to BTF of between 1.5 to 4.5%. Failure mechanism data submitted to the North American Electric Reliability Council (NERC) over the project term has also made it possible to delineate the leading BTF mechanisms causing problems for the participating utilities. Corrosion fatigue, fly ash erosion and high temperature creep accounted for over 28% of the total reported. 3 figs.

  7. Maintenance aspects of boiler tube failures

    SciTech Connect

    Dooley, B.; McNaughton, W.

    1996-07-01

    Boiler tube failures (BTF) remain the number one availability problem in the fossil-fueled power industry. The authors have recently prepared a three-volume book on all aspects of BTF. One of the key areas in the ultimate alleviation of tube failures is proper maintenance activities. This paper thoroughly reviews the areas where improper maintenance leads directly to repeat failures. Problems typically develop from: (i) improper chemical cleaning, (ii) improper repairs, such as the use of palliative or {open_quotes}band-aid{close_quotes} repairs: coatings, pad welding, weld overlay, improper welding activities etc., or (iii) improperly executed maintenance procedures such as can occur with sootblowing. The paper discusses these three topics as they pertain to boiler tube failures. Also discussed are five boiler tube failure mechanisms and how they are influenced by maintenance activities: (i) flyash erosion, (ii) waterwall underdeposit corrosion mechanisms, (iii) short-term overheating in waterwalls, (iv) short-term overheating in SH/RH tubes, and (v) damage directly induced by maintenance operations. A vision of where the authors expect the industry will move over the next five years is presented.

  8. Alternate Materials for Recovery Boiler Superheater Tubes

    SciTech Connect

    Keiser, James R; Kish, Joseph; Singbeil, Douglas

    2009-01-01

    The ever escalating demands for increased efficiency of all types of boilers would most sensibly be realized by an increase in the steam parameters of temperature and pressure. However, materials and corrosion limitations in the steam generating components, particularly the superheater tubes, present major obstacles to boiler designers in achieving systems that can operate under the more severe conditions. This paper will address the issues associated with superheater tube selection for many types of boilers; particularly chemical recovery boilers, but also addressing the similarities in issues for biomass and coal fired boilers. It will also review our recent study of materials for recovery boiler superheaters. Additional, more extensive studies, both laboratory and field, are needed to gain a better understanding of the variables that affect superheater tube corrosion and to better determine the best means to control this corrosion to ultimately permit operation of recovery boilers at higher temperatures and pressures.

  9. Stress-Assisted Corrosion in Boiler Tubes

    SciTech Connect

    Preet M Singh; Steven J Pawel

    2006-05-27

    A number of industrial boilers, including in the pulp and paper industry, needed to replace their lower furnace tubes or decommission many recovery boilers due to stress-assisted corrosion (SAC) on the waterside of boiler tubes. More than half of the power and recovery boilers that have been inspected reveal SAC damage, which portends significant energy and economic impacts. The goal of this project was to clarify the mechanism of stress-assisted corrosion (SAC) of boiler tubes for the purpose of determining key parameters in its mitigation and control. To accomplish this in-situ strain measurements on boiler tubes were made. Boiler water environment was simulated in the laboratory and effects of water chemistry on SAC initiation and growth were evaluated in terms of industrial operations. Results from this project have shown that the dissolved oxygen is single most important factor in SAC initiation on carbon steel samples. Control of dissolved oxygen can be used to mitigate SAC in industrial boilers. Results have also shown that sharp corrosion fatigue and bulbous SAC cracks have similar mechanism but the morphology is different due to availability of oxygen during boiler shutdown conditions. Results are described in the final technical report.

  10. Benchmarking boiler tube failures - Part 1

    SciTech Connect

    Patrick, J.; Oldani, R.; von Behren, D.

    2005-10-01

    Boiler tube failures continue to be the leading cause of downtime for steam power plants. That should not be a surprise; a typical steam generator has miles of tubes that operate at high temperatures and pressures. Are your experiences comparable to those of your peers? Could you learn something from tube-leak benchmarking data that could improve the operation of your plant? The Electric Utility Cost Group (EUCG) recently completed a boiler-tube failure study that is available only to its members. But Power magazine has been given exclusive access to some of the results, published in this article. 4 figs.

  11. Chemical cleaning clears San Miguel's boiler tubes

    SciTech Connect

    Buecker, B.; Wofford, J. ); Magel, R. )

    1994-06-01

    This article describes chemical cleaning of the San Miguel Electric Cooperative (SMEC) boiler, an opposed-fired, natural circulation, reheat unit. At maximum continuous rating, steam flow is 3,054,000 lb/hr at a pressure of 2,925 psig. The superheater and reheater design temperatures are both 1,005 F. Boiler volume is 69,000 gallons. The Unit 1 boiler had not been cleaned since 1980, its original start-up date. Tube sample analyses indicated deposit densities ranging from 12 to 26 grams/ft[sup 2]. Utility boiler tubes will, over time, accumulate an internal layer of iron oxides and other deposits that inhibit flow and heat transfer, even with well-controlled water chemistry. Tube deposits can speed up corrosion, cause tube overheating, and be a precursor to tube failure. Deposits can influence such phenomena as phosphate hideout, and reduce boiler efficiency. For many utility boilers, a periodic cleaning is necessary to remove internal deposits before they can cause serious problems. Regardless of the benefits, chemical cleanings often make plant managers, engineers, and operators anxious because the process has been known to cause equipment damage or extend the length of an outage.

  12. Microphone Detects Boiler-Tube Leaks

    NASA Technical Reports Server (NTRS)

    Parthasarathy, S. P.

    1985-01-01

    Unit simple, sensitive, rugged, and reliable. Diaphragmless microphone detects leaks from small boiler tubes. Porous plug retains carbon granules in tube while allowing pressure changes to penetrate to granules. Has greater life expectancy than previous controllers and used in variety of hot corrosive atmospheres.

  13. Stress-enhanced corrosion of boiler tubing

    SciTech Connect

    Esmacher, M.J.

    1987-05-01

    Five case histories are presented on the effect of residual stresses (from fabrication or welding) on the waterside corrosion performance of carbon steel boiler tubing. Specifically, cases are reviewed in which tube swaging or tube bending operations (producing high forming stresses in deformed zones) resulted in the formation of stress-enhanced corrosion cells. In addition, the phenomenon of accelerated corrosion in welded support zones, membrane-welded panel sections, and weld-repaired areas is discussed.

  14. Digital radiographic systems detect boiler tube cracks

    SciTech Connect

    Walker, S.

    2008-06-15

    Boiler water wall leaks have been a major cause of steam plant forced outages. But conventional nondestructive evaluation techniques have a poor track record of detecting corrosion fatigue cracking on the inside surface of the cold side of waterwall tubing. EPRI is performing field trials of a prototype direct-digital radiographic system that promises to be a game changer. 8 figs.

  15. A vision for reducing boiler tube failures

    SciTech Connect

    Dooley, B. )

    1992-03-01

    This paper reports that the boiler tube failure (BTF) problem still ranks as the number one equipment problem in fossil power plants. According to the North American Electric Reliability Council, BTF has been in this position in North America for the 28 years that reliability statistics have been kept. Currently BTF represents about 3-4% of lost availability. Previous analysis has indicated that a disturbing feature of these failures is that most of them are repeats. They occur on the same tube, same material, or in the same boiler section over and over again. Assessing the multifunctional nature of BTF, it became apparent in 1985 that the only way to prevent forced outages due to repeat tube failure problems was to implement a formalized, company-wide BTF prevention program. Thus, in a parallel effort to the root cause determinations, 16 utilities demonstrated such an approach over a four-year period and achieved remarkable availability improvements.

  16. Some common corrosion mechanisms leading to boiler tube failure

    SciTech Connect

    Bain, D.I.; Haff, J.D.; Kelly, J.A.

    1996-10-01

    Corrosion mechanisms remain a major cause of tube failures in operating boiler units. Conditions resulting in caustic corrosion, acid corrosion, chelant corrosion and sulfate induced high temperature external corrosion of boiler tribes are reviewed. Three case histories are presented illustrating the impact of the conditions discussed on boiler tube failures.

  17. Stress Assisted Corrosion in Boiler Tubes - Failure Analysis

    SciTech Connect

    Singh, Preet M; Pawel, Steven J; Yang, Dong; Mahmood, Jamshad

    2007-01-01

    Stress assisted corrosion (SAC) of carbon steel boiler tubes is one of the major causes of waterside failure in industrial boilers. SAC is a major concern for kraft recovery boilers in the pulp and paper industry as any water leak into the furnace can cause a smelt-water explosion in the boiler. Failed carbon steel boiler tubes from different kraft recovery boilers were examined to understand the role of carbon steel microstructure on crack initiation and SAC crack morphology. A number of carbon steel tubes showed a deep decarburized layer on the inner surface (water-touched) and also an unusually large grain size at the inner tube surface. SAC cracks were found to initiate in these areas with large-graineddecarburized microstructure. Tubes without such microstructure were also found to have SAC cracks. It was found that the decarburization and large grained microstructure may facilitate initiation and growth but is not necessary for SAC of carbon steel boiler tubes.

  18. A Flexural Mode Tuning Technique for Membraned Boiler Tubing

    SciTech Connect

    Quarry, M J; Chinn, D J; Rose, J L

    2005-03-21

    Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the cold side or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications.

  19. Residual Strain Distribution in Bent Composite Boiler Tubes

    SciTech Connect

    Hubbard, Camden R; Gorti, Sarma B; Tang, Fei; Keiser, James R

    2006-01-01

    Kraft recovery boilers are typically constructed of carbon steel boiler tubes clad with a corrosion resistant layer, and these composite tubes are bent and welded together to form air port panels which enable the combustion air to enter the boiler. In this paper, the through-thickness residual strain in the carbon steel layer of non-heat-treated and heat-treated composite bent tubes were measured by neutron diffraction techniques and modeled by finite element modeling. The results can be used to optimize material selection and manufacturing processes to prevent stress corrosion and corrosion fatigue cracking in the boiler tubes.

  20. Guided wave acoustic monitoring of corrosion in recovery boiler tubing

    SciTech Connect

    Quarry, M J; Chinn, D J

    2004-02-19

    Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This Department of Energy, Office of Industrial Technologies project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the coldside or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications. This technique appears very promising for recovery boiler tube application, potentially expediting annual inspection of tube integrity.

  1. 18. View of Lancashire double tube boiler salvaged from another ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    18. View of Lancashire double tube boiler salvaged from another site. - Hacienda Azucarera La Esperanza, Steam Engine & Mill, 2.65 Mi. N of PR Rt. 2 Bridge over Manati River, Manati, Manati Municipio, PR

  2. 48. BOILER HOUSE, DOORS IN FRONT OF STEAM TUBES, HEATERS, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    48. BOILER HOUSE, DOORS IN FRONT OF STEAM TUBES, HEATERS, AND MUD DRUMS (SEE DRAWING No. 11 OF 13) - Delaware County Electric Company, Chester Station, Delaware River at South end of Ward Street, Chester, Delaware County, PA

  3. Ceramic coat furnace tubes for improved operations

    SciTech Connect

    Hellander, J.C.

    1997-01-01

    Ceramic materials and products have many uses in industry, government and the home, from abrasive and corrosion-resistant surfaces to preformed shapes. Thin-film ceramic coatings for metal process tubing with the dual characteristics of high emissivity and thermal conductivity were developed, successfully field tested and are being used to improve the energy efficiency and production capabilities of natural gas and oil-fired production units and steam-generating boilers in the chemical and petrochemical industries. The concept for developing the ceramic coating system was to formulate a coating system that would produce, upon application, a thermally conductive thin-film coating surface that would prevent oxidation and scale formation. The result of applying a coating system is increased heat transfer of the ceramic-coated process tubing that either increases the energy efficiency or throughput, depending on the process unit`s requirements. As reviewed here in the chemical and petrochemical plant applications, the ceramic coating system`s development has been successful.

  4. Development of clad boiler tubes extruded from bimetallic centrifugal castings

    SciTech Connect

    Sponseller, D.L.; Bakker, W.T.; Timmons, G.A.

    1998-04-01

    Wrought tubes of T-11 steel, externally clad with SS310, have been produced by a new method. The alloys were united directly from the molten state by centrifugal casting. In the optimum process, temperatures were controlled to prevent meltback of the SS310 outer layer by the higher melting T-11 stream. Hollow extrusion billets were prepared from the heavy-walled cast bimetallic tubes and successfully hot extruded to 84-mm OD x 64-mm ID tubes, and to 51-mm OD x 38-mm ID tubes. For the most part, thicknesses of the cladding and of the tube wall are rather uniform around the circumference and from end to end of the tubes. Hardness and tensile properties of annealed 51-mm tubes are uniform from end to end of a tube, and between tubes, and readily conform to ASTM A 213; tubes satisfy the flattening and flaring requirements of ASTM A 450. The cladding is metallurgically bonded to be base metal, as revealed by metallography, and by two tests developed for this study: a bond shear strength test and a twist test. In the latter test, rings 3.1 mm in thickness are slotted and severely twisted with a special tool. In tubes made by the optimum process, minute fissures that form adjacent to some of the pressure points during twist testing occupy just 3% of the bond-line length. Cost estimates for commercial production of 51-mm tubes via the centrifugal casting route suggest that such tubes should be considerably less expensive than conventionally clad tubes (extruded from composite billets assembled from heavy-walled wrought tubes). Such tubes should be attractive for the following applications in utility boilers: high-corrosion areas of existing coal-fired boilers, in both steam-generating tubes and superheaters; water walls, screen tubes, and superheater tubes of municipal waste-incineration boilers; future ultra super-critical boilers operating a higher temperatures and pressures; and steam-generating tubes of Syngas coolers of integrated coal gasification power plants.

  5. New software directs the fight against boiler tube failure

    SciTech Connect

    Abbott, R.C. ); Tilley, R.; Gehl, S. ); Singh, G.P.; Lamping, G.A. )

    1992-10-01

    Boiler Maintenance Workstation supplements formal prevention programs to dramatically reduce tube failure. This paper reports that boiler tube failure (BTF) is such a common experience (over 4000 occurrences are reported each year to the North American Electric Reliability Council) that plant managers have developed a variety of methods to aid tube repair and replacement. Although these methods, often ingenious, have steadily increased the speed of boiler tube failure diagnosis and repair, they may soon be obsolete. As a result of research and development by the Fossil Power Plants Department of the Electric Power Research Institute (EPRI), new software tools now are available and are proving to be effective at preventing failure and forced outages. One such software package, called the Boiler Maintenance Workstation (BMW), combines several modules to provide a foundation to help manage key BTF prevention activities. Research by EPRI and others has improved mechanistic understanding and uncovered prevention methods for nearly all types of failures. BMW provides guidance for applying newly developed NDE techniques, metallurgical analysis, quality control, welding, and water conditioning to a boiler availability improvement program.

  6. Boiler Tube Corrosion Characterization with a Scanning Thermal Line

    NASA Technical Reports Server (NTRS)

    Cramer, K. Elliott; Jacobstein, Ronald; Reilly, Thomas

    2001-01-01

    Wall thinning due to corrosion in utility boiler water wall tubing is a significant operational concern for boiler operators. Historically, conventional ultrasonics has been used for inspection of these tubes. Unfortunately, ultrasonic inspection is very manpower intense and slow. Therefore, thickness measurements are typically taken over a relatively small percentage of the total boiler wall and statistical analysis is used to determine the overall condition of the boiler tubing. Other inspection techniques, such as electromagnetic acoustic transducer (EMAT), have recently been evaluated, however they provide only a qualitative evaluation - identifying areas or spots where corrosion has significantly reduced the wall thickness. NASA Langley Research Center, in cooperation with ThermTech Services, has developed a thermal NDE technique designed to quantitatively measure the wall thickness and thus determine the amount of material thinning present in steel boiler tubing. The technique involves the movement of a thermal line source across the outer surface of the tubing followed by an infrared imager at a fixed distance behind the line source. Quantitative images of the material loss due to corrosion are reconstructed from measurements of the induced surface temperature variations. This paper will present a discussion of the development of the thermal imaging system as well as the techniques used to reconstruct images of flaws. The application of the thermal line source coupled with the analysis technique represents a significant improvement in the inspection speed and accuracy for large structures such as boiler water walls. A theoretical basis for the technique will be presented to establish the quantitative nature of the technique. Further, a dynamic calibration system will be presented for the technique that allows the extraction of thickness information from the temperature data. Additionally, the results of the application of this technology to actual water wall

  7. Tests of Turbulators for Fire-Tube Boilers.

    DTIC Science & Technology

    1982-10-01

    ARD-Ri57 0 538 TESTS OF TURBULATORS FOR FIRE-TUBE BOILERS(U) IOWR 1/1 STATE UNIV AMES HEAT TRANSFER LAB G H JUNKHAN ET AL. OCT 82 HTL-29 UNCLASSIFIED...FESA-E-83023 Heat Transfer LaboratoryA Department of Mechanical Engineering Engineering Research Institute ’ouci a enapoa Iowa tate niverity, mes...introduction of "turbulators" into the boiler tubes. These inserts increase gas-side heat transfer coefficients, thereby increasing the heat removed

  8. Prevent boiler tube failures -- Part 2: Water-side mechanisms

    SciTech Connect

    Colannino, J. )

    1993-11-01

    Boiler tubes can fail due to problems on either the fire-side or the water-side of the tube. Part 1 of this article discussed fire-side failure mechanisms and measures for preventing failures. Here the author focuses on the tubes' water-side. The term water-side mechanisms'' refers to damage on the water side of the boiler tube (as opposed to the fire side). However, the water itself is often not the culprit. Water-side corrosion mechanisms may be classified into two major categories: physical and chemical. Physical mechanisms include steam blanketing and overheating. Chemical mechanisms include: deposition; caustic, acidic, and chelant corrosion; oxidation; and hydrogen embrittlement.

  9. Boiler tube failures: Case histories of steam blanketing and underdeposit corrosion

    SciTech Connect

    Hargrave, R.E.

    1994-12-31

    Case histories in which boiler tube failures resulted from a combination of steam blanketing and underdeposit corrosion are reviewed. Steam blanketing originates from inadequate circulation and commonly occurs in horizontal or sloped boiler tube circuits in the root of a boiler. It can lead to boiler tube corrosion failures by providing a mechanism for concentration of normally soluble species at or above a liquid/vapor interface.

  10. Boiler tube failures: Case histories of steam blanketing and underdeposit corrosion

    SciTech Connect

    Hargrave, R.E. )

    1994-08-01

    Case histories in which boiler tube failures resulted from a combination of steam blanketing and underdeposit corrosion are reviewed. Steam blanketing originates from inadequate circulation and commonly occurs in horizontal or sloped boiler tube circuits in the roof of a boiler. It can lead to boiler tube corrosion failures by providing a mechanism for concentration of normally soluble species at or above a liquid/vapor interface.

  11. Metallurgical Analysis of Cracks Formed on Coal Fired Boiler Tube

    NASA Astrophysics Data System (ADS)

    Kishor, Rajat; Kyada, Tushal; Goyal, Rajesh K.; Kathayat, T. S.

    2015-02-01

    Metallurgical failure analysis was carried out for cracks observed on the outer surface of a boiler tube made of ASME SA 210 GR A1 grade steel. The cracks on the surface of the tube were observed after 6 months from the installation in service. A careful visual inspection, chemical analysis, hardness measurement, detailed microstructural analysis using optical and scanning electron microscopy coupled with energy dispersive X-ray spectroscopy were carried out to ascertain the cause for failure. Visual inspection of the failed tube revealed the presence of oxide scales and ash deposits on the surface of the tube exposed to fire. Many cracks extending longitudinally were observed on the surface of the tube. Bulging of the tube was also observed. The results of chemical analysis, hardness values and optical micrographs did not exhibit any abnormality at the region of failure. However, detailed SEM with EDS analysis confirmed the presence of various oxide scales. These scales initiated corrosion at both the inner and outer surfaces of the tube. In addition, excessive hoop stress also developed at the region of failure. It is concluded that the failure of the boiler tube took place owing to the combined effect of the corrosion caused by the oxide scales as well as the excessive hoop stress.

  12. Thermal Behavior of Floor Tubes in a Kraft Recovery Boiler

    SciTech Connect

    Barker, R.E.; Choudhury, K.A.; Gorog, J.P.; Hall, L.M.; Keiser, J.R.; Sarma, G.B.

    1999-09-12

    The temperatures of floor tubes in a slope-floored black liquor recovery boiler were measured using an array of thermocouples located on the tube crowns. It was found that sudden, short duration temperature increases occurred with a frequency that increased with distance from the spout wall. To determine if the temperature pulses were associated with material falling from the convective section of the boiler, the pattern of sootblower operation was recorded and compared with the pattern of temperature pulses. During the period from September, 1998, through February, 1999, it was found that more than 2/3 of the temperature pulses occurred during the time when one of the fast eight sootblowers, which are directed at the back of the screen tubes and the leading edge of the first superheater bank, was operating.

  13. Boiler tube failures in municipal waste-to-energy plants

    SciTech Connect

    Krause, H.H.; Wright, I.G.

    1996-01-01

    Waste-to-energy plants experienced increased boiler tube failures when the design changed from waste-heat boilers to radiant furnace waterwalls using superheat. Fireside attack by chlorine and sulfur compounds in refuse combustion products caused many forced outages in early European plants operating at high steam temperatures and pressures. Despite conservative steam conditions in the first US plants, failures occurred. As steam temperatures increased, corrosion problems multiplied. The problems have been alleviated by covering the waterwalls with either refractory or weld overlays of nickel-based alloys and using high nickel-chromium alloys for superheater tubes. Changes in furnace design to provide uniform combustion and avoid reducing conditions in the waterwall zone and to lower the gas temperature in the superheater also have helped minimize corrosion.

  14. High Temperature Behavior of Cr3C2-NiCr Coatings in the Actual Coal-Fired Boiler Environment

    NASA Astrophysics Data System (ADS)

    Bhatia, Rakesh; Sidhu, Hazoor Singh; Sidhu, Buta Singh

    2015-03-01

    Erosion-corrosion is a serious problem observed in steam-powered electricity generation plants, and industrial waste incinerators. In the present study, four compositions of Cr3C2-(Ni-20Cr) alloy coating powder were deposited by high-velocity oxy-fuel spray technique on T-91 boiler tube steel. The cyclic studies were performed in a coal-fired boiler at 1123 K ± 10 K (850 °C ± 10 °C). X-ray diffraction, scanning electron microscopy/energy dispersive X-ray analysis and elemental mapping analysis techniques were used to analyze the corrosion products. All the coatings deposited on T-91 boiler tube steel imparted hot corrosion resistance. The 65 pctCr3C2 -35 pct (Ni-20Cr)-coated T-91 steel sample performed better than all other coated samples in the given environment.

  15. Benchmarking boiler tube failures - Part 2

    SciTech Connect

    James Patrick; Robert Oldani; Daryl Von Behren

    2005-12-01

    Part 1 of this article characterised the EUCG (formerly the Electric Utility Cost Group) Fossil Productivity Committee's study of 14 utilities with 219 baseload coal-fired steam plants (about 20% of the total number of coal plants in the USA) and their experience fighting tube leaks. Part 2 characterizes the sample of plants studied and summarises the data at the fleet level. The next study is scheduled for summer 2006. 3 figs., 2 tabs.

  16. High-performance nanoscale composite coatings for boiler applications

    NASA Astrophysics Data System (ADS)

    Branagan, D. J.; Breitsameter, M.; Meacham, B. E.; Belashchenko, V.

    2005-06-01

    In this article, we will show how unconventional nanoscale composite coatings can be formed using conventional wire-arc thermal spray systems. The as-sprayed SHS7170 wire-arc coatings are found to develop an amorphous matrix structure containing starburst-shaped boride and carbide crystallites with sizes ranging from 60 to 140 nm. After heating to temperatures above the peak crystalline temperature (566 °C), a solid/state transformation occurs that results in the formation of an intimate three-phase matrix structure consisting of the same complex boride and carbide phases, along with α-iron interdispersed on a structural scale from 60 to 110 nm. The nanocomposite microstructure contains clean grain boundaries, which are found to be extremely stable and resist coarsening throughout the range of temperatures found in boilers. Additionally, the properties of the coating are presented including the bond strength, hardness, bend resistance, and impact resistance. The sprayability, forgiveness, and repairability of the SHS7170 wire-arc coatings are explained in detail, with an emphasis on field applicability in boiler environments. The performance of the SHS7170 coatings in boiler environments is measured via elevated temperature-erosion experiments conducted at 300, 450, and 600 °C using bed ash from an operating circulating fluidized-bed combustor boiler, and the results are compared with those for existing boiler coatings.

  17. Development of Erosion-Corrosion-Resistant Cold-Spray Nanostructured Ni-20Cr Coating for Coal-Fired Boiler Applications

    NASA Astrophysics Data System (ADS)

    Kumar, M.; Singh, H.; Singh, N.; Chavan, N. M.; Kumar, S.; Joshi, S. V.

    2015-12-01

    The erosion-corrosion (E-C) behavior of a cold-spray nanostructured Ni-20Cr coating was studied under cyclic conditions in a coal-fired boiler. This study was done for 15 cycles (1500 h), in which each cycle comprised 100 h of heating in the boiler environment, followed by 1 h of cooling under ambient air conditions. The E-C extent was evaluated in terms of thickness loss data of the samples. The eroded-corroded samples were characterized using XRD, SEM/EDS, and x-ray mapping analyses. The nanostructured coating offered excellent E-C protection to boiler tube material (SA 516 steel) under harsh live conditions of the boiler. This E-C resistance offered by investigated coating may be attributed to the presence of protective NiO and Cr2O3 phases in its oxide scale and its superior as-sprayed microhardness.

  18. Evaluation of the behavior of shrouded plasma spray coatings in the platen superheater of coal-fired boilers

    NASA Astrophysics Data System (ADS)

    Sidhu, Buta Singh; Prakash, S.

    2006-06-01

    Nickel- and cobalt-based coatings were formulated by a shrouded plasma spray process on boiler tube steels, namely, ASTM-SA210-grade A1 (GrA1), ASTM-SA213-T-11 (T11), and ASTM-SA213-T-22 (T22). The Ni-22Cr-10Al-1Y alloy powder was sprayed as a bond in each case before the final coating. The degradation behavior of the bared and coated steels was studied in the platen superheater of the coal-fired boiler. The samples were inserted through the soot blower dummy points with the help of stainless steel wires. The coatings were found to be effective in increasing resistance to degradation in the given boiler environment. The maximum protection was observed in the case of Stellite-6 (St-6) coating.

  19. Computational prediction of tube erosion in coal fired power utility boilers

    SciTech Connect

    Lee, B.E.; Fletcher, C.A.J.; Behnia, M.

    1999-10-01

    Erosion of boiler tubes causes serious operational problems in many pulverized coal-fired utility boilers. A new erosion model has been developed in the present study for the prediction of boiler tube erosion. The Lagrangian approach is employed to predict the behavior of the particulate phase. The results of computational prediction of boiler tube erosion and the various parameters causing erosion are discussed in this paper. Comparison of the numerical predictions for a single tube erosion with experimental data shows very good agreement.

  20. Study to reduce the cost of bimetallic boiler tubes. Final report

    SciTech Connect

    Sponseller, D.L.

    1994-06-01

    This report describes a new method of producing low-alloy steel boiler tubes, clad with stainless steel. In this method the two metals are united directly in the casting stage by centrifugal casting; the hollow bimetallic casting is then cut into billets that are hot extruded. By this method, high-quality clad tubes can be produced at markedly lower cost than by the conventional method of producing clad tubes. This brings the cost down to a level where clad tubes can be considered for applications, such as the following, in U.S. electric utility boilers: (1) High-corrosion areas of existing coal-fired boilers, in both steam-generating tubes and superheaters. (2) Future boilers designed to achieve higher efficiency levels (i.e., ultra supercritical boilers operating at higher pressures and temperatures). (3) The steam-generating tubes of Syngas coolers of integrated coal gasification/electric power generating plants.

  1. Prevent boiler tube failures--Part 1: Fire-side mechanisms

    SciTech Connect

    Colannino, J.

    1993-10-01

    A boiler tube fails when the structural integrity of the tube is compromised. For boilers that have been previously operating, some change must occur to effect tube failure. Usually this change is wrought through some combination of corrosion and erosion acting on the boiler tube to weaken it. Boiler tubes depend on a complex metal oxide layer for protection from the hot furnace environment. Fire-side corrosion and erosion remove or alter the oxide layer, rendering the tube vulnerable to attack. Corrosion and erosion are destructive mechanisms that ravage boiler tubes. They are distinguished by the cause of the destruction--corrosion is caused by chemical or electrochemical attack, whereas erosion is caused by abrasive action of a moving fluid or solid. Both mechanisms can and often do operate simultaneously. This article focuses on the fire side of the tube. It explains the major mechanisms responsible for fire-side boiler tube failures, how to recognize the underlying cause of the failure, and how to avoid such problems. Fuel oil, coal, and municipal solid waste boilers are discussed.

  2. Final Report: Guided Acoustic Wave Monitoring of Corrosion in Recovery Boiler Tubing

    SciTech Connect

    Chinn, D J; Quarry, M J; Rose, J L

    2005-03-31

    Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This Department of Energy, Office of Industrial Technologies project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the cold side or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications. This technique appears very promising for recovery boiler tube application, potentially expediting annual inspection of tube integrity.

  3. Investigations on the Behavior of HVOF and Cold Sprayed Ni-20Cr Coating on T22 Boiler Steel in Actual Boiler Environment

    NASA Astrophysics Data System (ADS)

    Bala, Niraj; Singh, Harpreet; Prakash, Satya; Karthikeyan, J.

    2012-01-01

    High temperature corrosion accompanied by erosion is a severe problem, which may result in premature failure of the boiler tubes. One countermeasure to overcome this problem is the use of thermal spray protective coatings. In the current investigation high velocity oxy-fuel (HVOF) and cold spray processes have been used to deposit commercial Ni-20Cr powder on T22 boiler steel. To evaluate the performance of the coatings in actual conditions the bare as well as the coated steels were subjected to cyclic exposures, in the superheater zone of a coal fired boiler for 15 cycles. The weight change and thickness loss data were used to establish kinetics of the erosion-corrosion. X-ray diffraction, surface and cross-sectional field emission scanning electron microscope/energy dispersive spectroscopy (FE-SEM/EDS) and x-ray mapping techniques were used to analyse the as-sprayed and corroded specimens. The HVOF sprayed coating performed better than its cold sprayed counterpart in actual boiler environment.

  4. Sensing system for detection and control of deposition on pendant tubes in recovery and power boilers

    DOEpatents

    Kychakoff, George; Afromowitz, Martin A; Hugle, Richard E

    2005-06-21

    A system for detection and control of deposition on pendant tubes in recovery and power boilers includes one or more deposit monitoring sensors operating in infrared regions and about 4 or 8.7 microns and directly producing images of the interior of the boiler. An image pre-processing circuit (95) in which a 2-D image formed by the video data input is captured, and includes a low pass filter for performing noise filtering of said video input. An image segmentation module (105) for separating the image of the recovery boiler interior into background, pendant tubes, and deposition. An image-understanding unit (115) matches derived regions to a 3-D model of said boiler. It derives a 3-D structure the deposition on pendant tubes in the boiler and provides the information about deposits to the plant distributed control system (130) for more efficient operation of the plant pendant tube cleaning and operating systems.

  5. Proceedings: International conference on boiler tube failures in fossil plants

    SciTech Connect

    Dooley, R.B.

    1992-04-01

    An international conference on boiler tube failures (BTF) in fossil plants was conducted on November 5--7, 1991, at the Hyatt Regency Hotel in La Jolla, California. The objectives of the conference were to review, document and transfer technology on all aspects of BTF. To meet these objectives, papers and presentations were provided on the following topics: general overview of BTF around the world; corrosion fatigue in waterwalls of drum units; thermal fatigue in supercritical waterwalls; superheater/reheater failures; flyash erosion; waterwall mechanisms; life assessment; NDE; BTF in the USSR; predictive/maintenance planning; waterside mechanisms; BTF reduction programs. Each topic was discussed in a separate conference session. Discussions followed each paper and are included in the proceedings. A questionaire was completed by the attendees on BTF and the remaining needs for research and development, the results are provided in Appendix A.

  6. Composite tube cracking in kraft recovery boilers: A state-of-the-art review

    SciTech Connect

    Singbeil, D.L.; Prescott, R.; Keiser, J.R.; Swindeman, R.W.

    1997-07-01

    Beginning in the mid-1960s, increasing energy costs in Finland and Sweden made energy recovery more critical to the cost-effective operation of a kraft pulp mill. Boiler designers responded to this need by raising the steam operating pressure, but almost immediately the wall tubes in these new boilers began to corrode rapidly. Test panels installed in the walls of the most severely corroding boiler identified austenitic stainless steel as sufficiently resistant to the new corrosive conditions, and discussions with Sandvik AB, a Swedish tube manufacturer, led to the suggestion that coextruded tubes be used for water wall service in kraft recovery boilers. Replacement of carbon steel by coextruded tubes has solved most of the corrosion problems experienced by carbon steel wall tubes, however, these tubes have not been problem-free. Beginning in early 1995, a multidisciplinary research program funded by the US Department of Energy was established to investigate the cause of cracking in coextruded tubes and to develop improved materials for use in water walls and floors of kraft recovery boilers. One portion of that program, a state-of-the-art review of public- and private-domain documents related to coextruded tube cracking in kraft recovery boilers is reported here. Sources of information that were consulted for this review include the following: tube manufacturers, boiler manufacturers, public-domain literature, companies operating kraft recovery boilers, consultants and failure analysis laboratories, and failure analyses conducted specifically for this project. Much of the information contained in this report involves cracking problems experienced in recovery boiler floors and those aspects of spout and air-port-opening cracking not readily attributable to thermal fatigue. 61 refs.

  7. The use of laser-induced plasma spectroscopy technique for the characterization of boiler tubes

    NASA Astrophysics Data System (ADS)

    Nicolas, G.; Mateo, M. P.; Yañez, A.

    2007-12-01

    The present work focuses on the characterization of boiler tube walls using laser-induced plasma spectroscopy technique with visual inspection by optical and scanning electron microscopy of the cross-sections of these tubes. In a watertube boiler, water runs through tubes that are surrounded by a heating source. As a result, the water is heated to very high temperatures, causing accumulation of deposits on the inside surfaces of the tubes. These deposits play an important role in the efficiency of the boiler tube because they produce a reduction of the boiler heat rate and an increase in the number of tube failures. The objectives are to determine the thickness and arrangement of deposits located on the highest heat area of the boiler and compare them with tube parts where the heat flux is lower. The major deposits found were copper and magnetite. These deposits come mainly from the boiler feedwater and from the reaction between iron and water, and they do not form on the tube walls at a uniform rate over time. Their amount depends on the areas where they are collected. A Nd:YAG laser operating at 355 nm has been used to perform laser-induced plasma spectra and depth profiles of the deposits.

  8. Prediction of performance for a fire-tube boiler with and without turbulators

    SciTech Connect

    Didion, D.; Chern, L.

    1984-08-01

    A series of computer runs were made using DEPAB2 (the boiler simulation computer program). They include the runs for a fire-tube boiler as is (i.e., without turbulators), with wire-coil type turbulators, and with twisted-tape type turbulators, respectively. Output from these runs are used to evaluate the boiler seasonal performance values under the Washington, D.C. weather conditions. Results show that the turbulator increases the boiler seasonal efficiency from 2.87 to 6.08%.

  9. The Characterization of Twin-Wire Arc-Sprayed FeCrBSi Coating and the Application in Sewage Sludge Boilers

    NASA Astrophysics Data System (ADS)

    Qin, Enwei; Huang, Qian; Shao, Yumin; Chen, Guoxing; Ye, Lin; Gu, Qin; Wu, Shuhui

    2014-12-01

    Incineration in boilers is an environment-friendly treatment for industrial and civil sewage sludge. However, due to the aggressive nature of the sludge, the boiler fireside-surface is subjected to severe wear, erosive, and high temperature corrosion problems during incineration. In this study, we developed an economical FeCrBSi wire material with iron weight content as high as 80%. The coating was prepared by twin-wire arc spraying processing. The chemical compositions of the coating, as well as phase components were analyzed by energy-dispersive spectroscopy and x-ray diffraction method. The surface roughness, porosity, and cross-sectional morphology were further characterized. The coating hardness is close to that of the commercial Armacor M and Armacor C materials. In-boiler test was also carried out. The low thickness loss of the tube indicates a promising application future in sludge boilers.

  10. Alloy 33 weld overlay extends boiler tube life and saves money

    SciTech Connect

    Paul, L.; Clark, G.; Ossenberg-Engels, A.

    2007-09-15

    Low-NOx burners installed in coal-fired utility boilers cause problems with boiler tube cracking. Materials with increased corrosion resistance such as the new Alloy 33 should be more resistant to this type of 'circumferential cracking'. Alloy 33 is cheaper and has lower nickel and molybdenum content than the traditional Alloy 622 and 625. The article describes extensive corrosion testing experiments carried out by ThyssenKrupp VDM on Alloy 33 and Alloy 622. In the lab, in environments representative of coal-fired boilers operating under low-NOx combustion conditions, Alloy 33 was found to be better than Alloy 622. Field tests compared Alloy 33 and Alloy 622 in two supercritical tangentially-fired boilers and one tangentially-fired high pressure drum boiler. After up to 23 months of exposure there was no evidence of cracks and only slight evidence of corrosion in Alloy 33. 1 fig., 2 tabs., 2 photos.

  11. Development of composite tube protective coatings

    NASA Technical Reports Server (NTRS)

    Dursch, H.; Hendricks, C.

    1986-01-01

    Protective coatings for graphite/epoxy (Gr/Ep) tubular structures proposed for the Space Station are evaluated. The program was divided into four parts; System Definition, Coating Concept Selection and Evaluation, Scale-up and Assembly, and Reporting. System Definition involved defining the structural and environmental properties required of the Gr/Ep tubes. The prepreg and ply sequence selected was a P75S/934 (O2, + or - 20, O2)sub s layup which meets the various structural requirements of the Space Station. Coating Concept and Selection comprised the main emphasis of the effort. Concepts for protectively coating the Gr/Ep tubes included the use of metal foil and electroplating. The program results demonstrated that both phosphoric and chromic acid anodized Al foil provided adequate adhesion to the Gr/Ep tubes and stability of optical properties when subjected to atomic oxygen and thermal cycling representative of the LEO environment. SiO2/Al coatings sputtered onto Al foils also resulted in an excellent protective coating. The electroplated Ni possessed unacceptable adhesion loss to the Gr/Ep tubes during atomic oxygen testing. Scale-Up and Assembly involved fabricating and wrapping 8-ft-long by 2-in-diameter Gr/EP tubes with chromic acid anodized foil and delivering these tubes, along with representative Space Station erectable end fittings, to NASA LaRC.

  12. Fracture analysis of tube boiler for physical explosion accident.

    PubMed

    Kim, Eui Soo

    2017-09-01

    Material and failure analysis techniques are key tools for determining causation in case of explosive and bursting accident result from material and process defect of product in the field of forensic science. The boiler rupture generated by defect of the welding division, corrosion, overheating and degradation of the material have devastating power. If weak division of boiler burner is fractured by internal pressure, saturated vapor and water is vaporized suddenly. At that time, volume of the saturated vapor and water increases up to thousands of volume. This failure of boiler burner can lead to a fatal disaster. In order to prevent an explosion and of the boiler, it is critical to introduce a systematic investigation and prevention measures in advance. In this research, the cause of boiler failure is investigated through forensic engineering method. Specifically, the failure mechanism will be identified by fractography using scanning electron microscopes (SEM) and Optical Microscopes (OM) and mechanical characterizations. This paper presents a failure analysis of household welding joints for the water tank of a household boiler burner. Visual inspection was performed to find out the characteristics of the fracture of the as-received material. Also, the micro-structural changes such as grain growth and carbide coarsening were examined by optical microscope. Detailed studies of fracture surfaces were made to find out the crack propagation on the weld joint of a boiler burner. It was concluded that the rupture may be caused by overheating induced by insufficient water on the boiler, and it could be accelerated by the metal temperature increase. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Analysis of cracking of co-extruded recovery boiler floor tubes

    SciTech Connect

    Keiser, J.R.; Taljat, B.; Wang, X.L.

    1997-08-01

    Cracking of the stainless steel layer in co-extruded 304L/SA210 tubing used in black liquor recovery boilers is being found in an ever-increasing number of North American pulp and paper mills. Because of the possibility of a tube failure, this is a significant safety issue, and, because of the extra time required for tube inspection and repair, this can become an economic issue as well. In a project funded by the U.S. Department of Energy and given wide support among paper companies, boiler manufacturers, and tube fabricators, studies are being conducted to determine the cause of the cracking and to identify alternate materials and/or operating procedures to prevent tube cracking. Examination of cracked tubes has permitted characterization of crack features, and transmission electron microscopy is providing information about the thermal history, particularly cyclic thermal exposures, that tubes have experienced. Neutron and x-ray diffraction techniques are being used to determine the residual stresses in as-fabricated tube panels and exposed tubes, and finite element modeling is providing information about the stresses the tubes experience during operation. Laboratory studies are being conducted to determine the susceptibility of the co-extruded 304L/SA210 tubes to stress corrosion cracking, thermal fatigue, and corrosion in molten smelt. This paper presents the current status of these studies. On the basis of all of these studies, recommendations for means to prevent tube cracking will be offered.

  14. Investigation into Cause of High Temperature Failure of Boiler Superheater Tube

    NASA Astrophysics Data System (ADS)

    Ghosh, D.; Ray, S.; Roy, H.; Shukla, A. K.

    2015-04-01

    The failure of the boiler tubes occur due to various reasons like creep, fatigue, corrosion and erosion. This paper highlights a case study of typical premature failure of a final superheater tube of 210 MW thermal power plant boiler. Visual examination, dimensional measurement, chemical analysis, oxide scale thickness measurement, microstructural examination are conducted as part of the investigations. Apart from these investigations, sulfur print, Energy Dispersive spectroscopy (EDS) and X ray diffraction analysis (XRD) are also conducted to ascertain the probable cause of failure of final super heater tube. Finally it has been concluded that the premature failure of the super heater tube can be attributed to the combination of localized high tube metal temperature and loss of metal from the outer surface due to high temperature corrosion. The corrective actions have also been suggested to avoid this type of failure in near future.

  15. Features of brittle damages and hydrogen impregnation of high-pressure boiler tube metal

    SciTech Connect

    Vainman, A.B.; Smiyan, O.D.; Girnyi, S.I.; Kostyuchenko, N.P.; Vasilik, A.V.; Melekhov, R.K.

    1988-01-01

    A significant number of failures encountered in high-pressure steam boilers of thermal electric power stations are caused by damage of the tubes of the steam superheaters, which are made of 20, 12Kh1MF, 12Kh2MFSR and 12Kh18N10T steels. A statistical analysis made by the authors determined that a large number of the failures result from the action of hydrogen on the tubes. In this paper, the mechanisms of hydrogen diffusion, corrosion crack propagation, and brittle failure for steam superheater tubes were analyzed. Hydrogen-related intergranular cracking and thermal fatigue were assessed for the tube steels. It was concluded that hydrogen had a significant effect on processes of crack origin and propagation both in the superheater and in the unheated tubes of the boilers.

  16. Sensing system for detection and control of deposition on pendant tubes in recovery and power boilers

    DOEpatents

    Kychakoff, George [Maple Valley, WA; Afromowitz, Martin A [Mercer Island, WA; Hogle, Richard E [Olympia, WA

    2008-10-14

    A system for detection and control of deposition on pendant tubes in recovery and power boilers includes one or more deposit monitoring sensors operating in infrared regions of about 4 or 8.7 microns and directly producing images of the interior of the boiler, or producing feeding signals to a data processing system for information to enable a distributed control system by which the boilers are operated to operate said boilers more efficiently. The data processing system includes an image pre-processing circuit in which a 2-D image formed by the video data input is captured, and includes a low pass filter for performing noise filtering of said video input. It also includes an image compensation system for array compensation to correct for pixel variation and dead cells, etc., and for correcting geometric distortion. An image segmentation module receives a cleaned image from the image pre-processing circuit for separating the image of the recovery boiler interior into background, pendant tubes, and deposition. It also accomplishes thresholding/clustering on gray scale/texture and makes morphological transforms to smooth regions, and identifies regions by connected components. An image-understanding unit receives a segmented image sent from the image segmentation module and matches derived regions to a 3-D model of said boiler. It derives a 3-D structure the deposition on pendant tubes in the boiler and provides the information about deposits to the plant distributed control system for more efficient operation of the plant pendant tube cleaning and operating systems.

  17. Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks

    SciTech Connect

    Lopez-Lopez, D.; Wong-Moreno, A.

    1998-12-31

    Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

  18. A study of LNCFS III coal burners on boiler waterwall tube wastage

    SciTech Connect

    Abbott, R.C.; Gordon, C.M.; Saunders, M.M.; Bray, A.J.

    1996-07-01

    Ultrasonic Testing (UT) of waterwall tubing of a tangentially-fired, sub-critical boiler at Milliken Station of New York State Electric and Gas (NYSEG) was undertaken to determine the effects of the newly installed low NO{sub x} firing system on waterwall tube wastage. During a 1993 outage, the pulverized coal-fired boiler was equipped with an ABB CE Low NO, Concentric Firing System (LNCFS) of the third generation (III) including Staged Overfire Air (SOFA) and a coal pulverizing system capable of improving mill fineness by approximately 30 percent. The study was in conjunction with a Department of Energy Clean Coal Demonstration Project. Three separate thickness, surveys were compared using the Electric Power Research Institute`s (EPRI) Boiler Maintenance Workstation (BMW). The Tube Condition Module of BMW compared a total of 20,556 test locations of the three surveys. The evaluations of the surveys indicate that the short-term effect of low NO{sub x} firing with LNCFS III and increased fineness has moderately reduced the remaining life of the carbon steel boiler tubing in selected locations of the waterfall. Approximately 5 percent of the test locations are experiencing an annual tube wastage of 0.008 inches or greater. Additional testing and analyses are recommended to better understand the longer term effects of the low NO{sub x} firing system and the wastage of selected tubing The influence of boiler operating parameters, such as cyclic duty, proportioning of secondary air, or fuel changes, on waterwall tube wastage should also be evaluated over a longer operating period.

  19. Development of clad boiler tubes extruded from bimetallic centrifugal castings

    NASA Astrophysics Data System (ADS)

    Sponseller, D. L.; Timmons, G. A.; Bakker, W. T.

    1998-04-01

    Wrought tubes of T-11 steel, externally clad with SS310, have been produced by a new method (U.S. Patent 5,558,150). The alloys were united directly from the molten state by centrifugal casting. In the optimum process, temperatures were controlled to prevent meltback of the SS310 outer layer by the higher melting T-11 stream. Hollow extrusion billets were prepared from the heavy-walled cast bimetallic tubes and successfully hot extruded (at a ratio of 13.4) to 84-mm (3.3 in.) OD X 64-mm (2.5-in.) ID tubes, and (at a ratio of 37.6) to 51-mm (2-in.) OD X 38-mm (1.5-in.) ID tubes. In all, 10 castings were produced, and 12 billets were extruded to tubes. For the most part, thicknesses of the cladding and of the tube wall are rather uniform around the circumference and from end to end of the tubes. Hardness and tensile properties of annealed 51-mm (2-in.) tubes are uniform from end to end of a tube, and between tubes, and readily conform to ASTM A 213; tubes satisfy the flattening and flaring requirements of ASTM A 450. The cladding is metallurgically bonded to the base metal, as revealed by metallography, and by two tests developed for this study: a bond shear strength test and a twist test. In the latter test, rings 3.1 mm (0.125 in.) in thickness are slotted and severely twisted with a special tool. In tubes made by the optimum process, minute fissures that form adjacent to some of the pressure points during twist testing occupy just 3 % of the bond-line length. Cost estimates for commercial production of 51-mm (2-in.) tubes via the centrifugal casting route suggest that such tubes should be considerably less expensive than conventionally clad tubes (extruded from composite billets assembled from heavy-walled wrought tubes).

  20. Development of clad boiler tubes extruded from bimetallic centrifugal castings

    SciTech Connect

    Sponseller, D.L.; Timmons, G.A.; Bakker, W.T.

    1995-12-31

    Wrought tubes of T-11 steel, externally clad with SS310, have been produced by a new method. The alloys were united directly from the molten state by centrifugal casting. In the optimum process, temperatures are controlled to prevent meltback of the SS310 outer layer by the higher-melting T-11 stream. Hollow extrusion billets were prepared from the heavy-walled cast bimetallic tubes and successfully hot extruded (at a ratio of 13.4) to 3.3-inch OD x 2.5-inch ID tubes, and (at a ratio of 37.6) to 2-inch OD x 1.5-inch ID tubes. In all, ten castings were produced, and 12 billets were extruded to tubes. For the most part, thicknesses of the cladding and tube wall are rather uniform around the circumference and from end to end of the tubes. Hardness and tensile Properties of annealed 2-inch tubes are uniform from end to 6nd of a tube, and between tubes, and readily conform to ASTM A 213; tubes satisfy the flattening and flaring requirements of ASTM A 450. The cladding is metallurgically bonded to the base metal, as revealed by metallography, and by two tests developed for this study: a bond hear-strength test and a twist test. In the latter test, rings 0.125 inch in thickness are slotted and severely twisted with a special tool. In tubes made by the optimum process, minute fissures that form adjacent to some of the pressure points during twist testing just 2.7 percent of the bond-line length. Cost estimates OCCUPY for commercial production of 2-inch tubes via the centrifugal casting route suggest that such tubes should be considerably less expensive than conventionally clad tubes (extruded from composite billets assembled from heavy-walled wrought tubes).

  1. Thermal Nondestructive Characterization of Corrosion in Boiler Tubes by Application fo a Moving Line Heat Source

    NASA Technical Reports Server (NTRS)

    Cramer, K. Elliott; Winfree, William P.

    2000-01-01

    Wall thinning in utility boiler waterwall tubing is a significant inspection concern for boiler operators. Historically, conventional ultrasonics has been used lor inspection of these tubes. This technique has proved to be very labor intensive and slow. This has resulted in a "spot check" approach to inspections, making thickness measurements over a relatively small percentage of the total boiler wall area. NASA Langley Research Center has developed a thermal NDE technique designed to image and quantitatively characterize the amount of material thinning present in steel tubing. The technique involves the movement of a thermal line source across the outer surface of the tubing followed by an infrared imager at a fixed distance behind the line source. Quantitative images of the material loss due to corrosion are reconstructed from measurements of the induced surface temperature variations. This paper will present a discussion of the development of the thermal imaging system as well as the techniques used to reconstruct images of flaws. The application of the thermal line source, coupled with this analysis technique, represents a significant improvement in the inspection speed for large structures such as boiler waterwalls while still providing high-resolution thickness measurements. A theoretical basis for the technique will be presented thus demonstrating the quantitative nature of the technique. Further, results of laboratory experiments on flat Panel specimens with fabricated material loss regions will be presented.

  2. MANAGING OXIDE SCALE EXFOLIATION IN BOILERS WITH TP347H SUPERHEATER TUBES

    SciTech Connect

    Sabau, Adrian S; Wright, Ian G.; Shingledecker, John P.; Tortorelli, Peter F

    2014-01-01

    A model based on a concept of fraction of exfoliated area as a function of oxide scale strain energy was developed to predict the extent of exfoliation of steam-side scale from boiler tube superheater loops. As compared with the Armitt diagram, which can be used to predict when scale damage and exfoliation would be likely to occur, a fraction of exfoliated area approach provides an estimation of mass of scale released and the fraction of tube likely to be blocked by the exfoliation. This paper show results for the extent of blockage expected in a single bend of a superheater loop was predicted as a function of operating time, bend geometry, and outlet steam temperature under realistic service conditions that include outages. The deposits of exfoliated scale were assumed to be distributed horizontally the tubes bends. Three types of bends were considered: regular bends, short bends, and hairpin bends. The progressive increase in steam and tube temperatures along a single loop of superheater tubing and the ensuing variation of oxide scale thickness are considered. Numerical simulation results for a superheater loop made of TP347H austenitic steel indicated that tube blockage fractions larger than 50% are likely to occur within the first two years of boiler operation (with regularly scheduled outages) for outlet tube temperatures of 540-570oC, which is consistent with practical experience. Higher blockage fractions were predicted for tubes with short bends and hairpin bends than for tubes with regular bends, of length that are larger than five internal tube diameters. Finally, the blockage model presented can be used with some confidence to devise operating schedules for managing the consequences of oxide scale exfoliation based on projections of time to some critical blockage fraction for specific boiler operating conditions.

  3. Acoustic Resonance and Vortex Shedding from Tube Banks of Boiler Plant

    NASA Astrophysics Data System (ADS)

    Hamakawa, Hiromitsu; Matsue, Hiroto; Nishida, Eiichi; Fukano, Tohru

    This paper focuses on the relationship between acoustic resonance and vortex shedding from the tube banks of a boiler plant. We have built a model similar to the actual boiler plant to clarify the characteristics of acoustic resonance phenomena and vortex shedding. The model used in-line tube banks with a small tube pitch ratio. We examined the relationship between the acoustic resonance of the actual plant and that of the model, and measured the sound pressure level, acoustic pressure mode shape, spectrum of velocity fluctuation, and gap velocity. Gap velocity was defined as the mean velocity in the smallest gaps between two neighboring tubes in the transverse direction. As a result, the resonant frequencies and mode shapes of the acoustic resonances in the actual boiler plant agreed well with those in the similar model. We found many peak frequencies in the sound pressure level spectrum when acoustic resonances occurred. The typical Strouhal numbers at the onset velocity of acoustic resonances were about 0.19, 0.26 and 0.52. Periodic velocity fluctuation caused by vortex shedding was observed inside the tube banks without acoustic resonance. The Strouhal number measured for vortex shedding was 0.15. Acoustic resonances of higher-order modes were generated in this plant.

  4. Modelling of thermal behaviour of iron oxide layers on boiler tubes

    NASA Astrophysics Data System (ADS)

    Angelo, J. D.; Bennecer, A.; Kaczmarczyk, S.; Picton, P.

    2016-05-01

    Slender boiler tubes are subject to localised swelling when they are expose to excessive heat. The latter is due to the formation of an oxide layer, which acts as an insulation barrier. This excessive heat can lead to microstructural changes in the material that would reduce the mechanical strength and would eventually lead to critical and catastrophic failure. Detecting such creep damage remains a formidable challenge for boiler operators. It involves a costly process of shutting down the plant, performing electromagnetic and ultrasonic non-destructive inspection, repairing or replacing damaged tubes and finally restarting the plant to resume its service. This research explores through a model developed using a finite element computer simulation platform the thermal behaviour of slender tubes under constant temperature exceeding 723 °K. Our simulation results demonstrate that hematite layers up to 15 μm thickness inside the tubes do not act as insulation. They clearly show the process of long term overheating on the outside of boiler tubes which in turn leads to initiation of flaws.

  5. Creep-Rupture Behavior and Recrystallization in Cold-Bent Boiler Tubing for USC Applications

    SciTech Connect

    Shingledecker, John P

    2008-01-01

    Creep-rupture experiments were conducted on candidate Ultrasupercritical (USC) alloy tubes to evaluate the effects of cold-work and recrystallization during high-temperature service. These creep tests were performed by internally pressurizing cold-bent boiler tubes at 775 C for times up to 8000 hours. The bends were fabricated with cold-work levels beyond the current ASME Boiler and Pressure Vessel (ASME B&PV) Code Section I limits for austenitic stainless steels. Destructive metallographic evaluation of the crept tube bends was used to determine the effects of cold-work and the degree of recrystallization. The metallographic analysis combined with an evaluation of the creep and rupture data suggest that solid-solution strengthened nickel-based alloys can be fabricated for high-temperature service at USC conditions utilizing levels of cold-work higher than the current allowed levels for austenitic stainless steels.

  6. A Novel Low-Temperature Fiffusion Aluminide Coating for Ultrasupercritical Coal-Fried Boiler Applications

    SciTech Connect

    Zhang, Ying

    2009-12-31

    An ultrasupercritical (USC) boiler with higher steam temperature and pressure is expected to increase the efficiency of the coal-fired power plant and also decrease emissions of air pollutants. Ferritic/martensitic alloys have been developed with good creep strength for the key components in coal-fired USC plants. However, they typically suffer excessive steam-side oxidation, which contributes to one of main degradation mechanisms along with the fire-side corrosion in coal-fired boilers. As the steam temperature further increases in USC boilers, oxidation of the tube internals becomes an increasing concern, and protective coatings such as aluminide-based diffusion coatings need to be considered. However, conventional aluminizing processes via pack cementation or chemical vapor deposition are typically carried out at elevated temperatures (1000-1150 C). Thermochemical treatment of ferritic/martensitic alloys at such high temperatures could severely degrade their mechanical properties, particularly the alloy's creep resistance. The research focus of this project was to develop an aluminide coating with good oxidation resistance at temperatures {le} 700 C so that the coating processing would not detrimentally alter the creep performance of the ferritic/martensitic alloys. Nevertheless, when the aluminizing temperature is lowered, brittle Al-rich intermetallic phases, such as Fe{sub 2}Al{sub 5} and FeAl{sub 3}, tend to form in the coating, which may reduce the resistance to fatigue cracking. Al-containing binary masteralloys were selected based on thermodynamic calculations to reduce the Al activity in the pack cementation process and thus to prevent the formation of brittle Al-rich intermetallic phases. Thermodynamic computations were carried out using commercial software HSC 5.0 for a series of packs containing various Cr-Al binary masteralloys. The calculation results indicate that the equilibrium partial pressures of Al halides at 700 C were a function of Al

  7. Manual for investigation and correction of boiler tube failures. Final report

    SciTech Connect

    Lamping, G.A.; Arrowood, R.M. Jr.

    1985-04-01

    The manual is for use by electric utility power plant personnel during the investigation into the cause of a boiler tube failure and during the evaluation of corrective actions to prevent future boiler tube failures. It is intended to aid plant personnel in their understanding of the basic failure mechanisms that can produce a boiler tube failure. Information is provided on ways to identify the specific failure mechanisms, to determine the root cause of the failure, and to evaluate the corrective action that can be taken. The Manual contains information on the current methods to control the root causes of tube failures with the understanding that current and future research is necessary on many of these mechanisms to fully understand the factors which can prevent their recurrence. The Manual does not eliminate the need for a thorough metallurgical analysis during the failure investigation but is intended to enhance the investigative process by providing descriptive information for use during communications with technical specialists. The Manual encourages the comprehensive acquisition of failure data and pertinent records to document the failure for immediate and future reference. 80 figs., 10 tabs.

  8. Creep-Rupture Behavior of Ni-Based Alloy Tube Bends for A-USC Boilers

    NASA Astrophysics Data System (ADS)

    Shingledecker, John

    Advanced ultrasupercritical (A-USC) boiler designs will require the use of nickel-based alloys for superheaters and reheaters and thus tube bending will be required. The American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code Section II PG-19 limits the amount of cold-strain for boiler tube bends for austenitic materials. In this summary and analysis of research conducted to date, a number of candidate nickel-based A-USC alloys were evaluated. These alloys include alloy 230, alloy 617, and Inconel 740/740H. Uniaxial creep and novel structural tests and corresponding post-test analysis, which included physical measurements, simplified analytical analysis, and detailed microscopy, showed that different damage mechanisms may operate based on test conditions, alloy, and cold-strain levels. Overall, creep strength and ductility were reduced in all the alloys, but the degree of degradation varied substantially. The results support the current cold-strain limits now incorporated in ASME for these alloys for long-term A-USC boiler service.

  9. Prediction of remaining lifetime of superheater/reheater tubes in boilers burning high-sulfur coal

    SciTech Connect

    Not Available

    1987-02-01

    The secondary superheater and reheater tubes in steam boilers are susceptible to a form of accelerated corrosion which is related to the formation of complex sulfates of sodium, potassium, and iron which may have melting temperatures as low as 552/sup 0/C. The conditions required for this form of corrosion to occur include the deposition on the tubes of alkali- and sulfur- (and possibly iron-) containing species (from the coal), sufficient time and a temperature gradient in the deposit to allow the formation and migration of the corrosive species to the tube surface, and a tube surface temperature above the melting temperature of the complex sulfates. The factors that must be considered in a life expectancy calculation are: oxidation rate, molten salt corrosion rate, trisulfate melting point, original tube diameter, loss of outside diameter, internal scale thickness, and operating time. A computer program has been developed to carry out the life expectancy calculation based on these factors. This program was tested on the reheater of a 600 MW coal-fired boiler of General Public Utilities (GPU) which operates with 540/sup 0/C and 4.83 MPa reheat. Tube sections were removed from the vertical section of the reheater for evaluation. The output indicated that after 90,000 hours the tubes would be thinned to 3.4 mm (135 mils), which agreed with actual measurements. Tube failure was predicted at 108,000 hours, when the tube wall would be reduced to 2.8 mm (111 mils). In this case tube replacement within two years was recommended to avoid forced outages. 3 figures, 1 table.

  10. Characterization of single-tube model-boiler dented intersection specimens. Final report. [PWR

    SciTech Connect

    Varsanik, R.G.; Gibbon, D.L.

    1983-05-01

    Crevice denting, caused by the uncontrolled growth of magnetite in the space between carbon-steel tube-support plates and Inconel heat-exchange tubes is a major cause of concern in nuclear steam generators. This particular form of localized corrosion has been modeled experimentally by the Westinghouse Electric Corporation using prototypical boiler systems. In this study, three corrosion specimens from these model-boiler systems have been characterized by Calgon Corporation using light and scanning electron microscopy along with both energy- and wave-length-dispersive x-ray spectrophotometry. Samples examined consisted of specimens which had been exposed to a known corrosive environment and then either left untreated, treated with calcium hydroxide, or treated with boric acid in an attempt to halt the corrosion process. The destructive examination of the samples was conducted on both polished sections as well as sections fractured in liquid nitrogen to expose uncontaminated interfaces between the multiple phases involved.

  11. Cracking and Corrosion of Composite Tubes in Black Liquor Recovery Boiler Primary Air Ports

    SciTech Connect

    Keiser, James R.; Singbeil, Douglas L.; Sarma, Gorti B.; Kish, Joseph R.; Yuan, Jerry; Frederick, Laurie A.; Choudhury, Kimberly A.; Gorog, J. Peter; Jetté, Francois R.; Hubbard, Camden R.; Swindeman, Robert W.; Singh, Prett M.; Maziasz, Phillip J.

    2006-10-01

    Black liquor recovery boilers are an essential part of kraft mills. Their design and operating procedures have changed over time with the goal of providing improved boiler performance. These performance improvements are frequently associated with an increase in heat flux and/or operating temperature with a subsequent increase in the demand on structural materials associated with operation at higher temperatures and/or in more corrosive environments. Improvements in structural materials have therefore been required. In most cases the alternate materials have provided acceptable solutions. However, in some cases the alternate materials have solved the original problem but introduced new issues. This report addresses the performance of materials in the tubes forming primary air port openings and, particularly, the problems associated with use of stainless steel clad carbon steel tubes and the solutions that have been identified.

  12. Fossil-fired boiler tube inspection. Volume 1: nondestructive testing guidelines. Final report

    SciTech Connect

    Lamping, G.A.; Birring, A.S.; Meredith, W.R.; Singh, G.P.

    1986-08-01

    This Guideline report is for use by electric utility power plant personnel to plan and conduct ultrasonic examinations of tubes in fossil-fired power boilers. Extensive economic benefits in the operation of steam generating equipment can be realized from ultrasonic examinations. Economic benefits of ultrasonic examinations can be calculated and justified using the software package called BEAP (Boiler Economic Analysis Program), developed under this project. The BEAP software package calculates the optimum time for each examination which will maximize the economic benefits to be obtained. The BEAP software also takes into consideration wastage rate, costs of examinations and repairs, and probability of tube failures and associated repair costs. The Guideline report recommends a series of activities for performance by plant personnel to achieve beneficial results. These activities include determining equipment and manpower resources, soliciting proposals from contractors, and monitoring performance during tube examinations. Details are given on ultrasonic testing techniques, procedures, personnel, standards, and equipment employed by nondestructive examination agencies to conduct either tube wall thickness surveys or flaw detection and sizing examinations. The report also discusses a software package called BOTS (Boiler Tube Status) developed during this project to document and analyze the thickness data obtained from ultrasonic examinations. This software displays the thickness data and can be used to determine the condition of the tubes and predict the remaining life and the thickness at a future time. The Guidelines encourage the application of quality control measures to monitor examination activities and obtain the pertinent records for immediate and future reference. The guidelines are contained in Volume 1 of the final report. A computer manual for the BEAP and BOTS codes will be contained in Volume 2. 61 figs., 13 tabs.

  13. Selection of stainless steel tubes to minimize hot corrosion in utility boilers

    SciTech Connect

    Fujikawa, H.; Makiura, H.

    1982-12-01

    Austenitic stainless steel tubes of AISI 304, 316, 321, and 347 types are sometimes exposed to severe hot corrosion environments in superheaters and reheaters of utility boilers. Hot corrosion depends on the existence of V/sub 2/O/sub 5/ and Na/sub 2/SO/sub 4/ in the oil-fired boilers, and of Na/sub 2/SO/sub 4/ and K/sub 2/SO/sub 4/ in the coal-fired boilers. Among various kinds of ash corrosions, the alkali sulphate-side corrosion has been mainly studied. Type 347 steel better resistance to alkali sulphate-side corrosion than 304, 316, and 321 steels. Alloying with Nb was more effective than Mo or Ti. A (Cr, Fe, Ni)-spinel oxide layer with little ash content formed at the scale-metal interface in 347 steel. In field tests, 347 tubes have maintained good resistance to both fire-side and steam-side corrosion for five years. However, 321 tubes were removed after three years of service, because of severe fire-side corrosion.

  14. Biofilm formation on coated silicone tympanostomy tubes.

    PubMed

    Ojano-Dirain, Carolyn P; Silva, Rodrigo C; Antonelli, Patrick J

    2013-02-01

    Tympanostomy tube (TT) surface modifications have been promoted as a means of reducing biofilm formation, otorrhea, and occlusion. The goal of this study was to determine if biofilm formation on silicone TTs could be prevented by commercially available surface coatings. Silicone TTs with and without polyvinylpyrrolidone (PVP) or/and silver oxide were exposed to human plasma and cultured with Pseudomonas aeruginosa or Staphylococcus aureus (22 TTs per group). After 4 days, antibiotics were added to kill planktonic bacteria. Biofilm formation was assessed by quantitative bacterial counts and scanning electron microscopy. PVP, silver, and PVP-silver coatings reduced P. aeruginosa biofilm formation relative to silicone by over 1 log (p<0.0001). PVP was superior to silver (p=0.04) and PVP-silver (p<0.0001). PVP and PVP-silver coatings increased S. aureus biofilm formation nominally (p=0.01 & 0.003). PVP and silver coatings reduce P. aeruginosa biofilm formation on silicone TTs. Combining PVP and silver coatings does not further improve biofilm resistance. TT surface coatings warrant further study through clinical trials. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

  15. Failure Investigation of Radiant Platen Superheater Tube of Thermal Power Plant Boiler

    NASA Astrophysics Data System (ADS)

    Ghosh, D.; Ray, S.; Mandal, A.; Roy, H.

    2015-04-01

    This paper highlights a case study of typical premature failure of a radiant platen superheater tube of 210 MW thermal power plant boiler. Visual examination, dimensional measurement and chemical analysis, are conducted as part of the investigations. Apart from these, metallographic analysis and fractography are also conducted to ascertain the probable cause of failure. Finally it has been concluded that the premature failure of the super heater tube can be attributed to localized creep at high temperature. The corrective actions has also been suggested to avoid this type of failure in near future.

  16. Investigations of the Failure in Boilers Economizer Tubes Used in Power Plants

    NASA Astrophysics Data System (ADS)

    Moakhar, Roozbeh Siavash; Mehdipour, Mehrad; Ghorbani, Mohammad; Mohebali, Milad; Koohbor, Behrad

    2013-09-01

    In this study, failure of a high pressure economizer tube of a boiler used in gas-Mazut combined cycle power plants was studied. Failure analysis of the tube was accomplished by taking into account visual inspection, thickness measurement, and hardness testing as well as microstructural observations using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and x-ray diffraction (XRD). Optical microscopy images indicate that there is no phase transformation during service, and ferrite-pearlite remained. The results of XRD also revealed Iron sulfate (FeSO4) and Iron hydroxide sulfate (FeOH(SO4)) phases formed on the steel surface. A considerable amount of Sulfur was also detected on the outer surface of the tube by EDS analysis. Dew-point corrosion was found to be the principal reason for the failure of the examined tube while it has been left out-of-service.

  17. Thermal Spray Coatings for High-Temperature Corrosion Protection in Biomass Co-Fired Boilers

    NASA Astrophysics Data System (ADS)

    Oksa, M.; Metsäjoki, J.; Kärki, J.

    2015-01-01

    There are over 1000 biomass boilers and about 500 plants using waste as fuel in Europe, and the numbers are increasing. Many of them encounter serious problems with high-temperature corrosion due to detrimental elements such as chlorides, alkali metals, and heavy metals. By HVOF spraying, it is possible to produce very dense and well-adhered coatings, which can be applied for corrosion protection of heat exchanger surfaces in biomass and waste-to-energy power plant boilers. Four HVOF coatings and one arc sprayed coating were exposed to actual biomass co-fired boiler conditions in superheater area with a probe measurement installation for 5900 h at 550 and 750 °C. The coating materials were Ni-Cr, IN625, Fe-Cr-W-Nb-Mo, and Ni-Cr-Ti. CJS and DJ Hybrid spray guns were used for HVOF spraying to compare the corrosion resistance of Ni-Cr coating structures. Reference materials were ferritic steel T92 and nickel super alloy A263. The circulating fluidized bed boiler burnt a mixture of wood, peat and coal. The coatings showed excellent corrosion resistance at 550 °C compared to the ferritic steel. At higher temperature, NiCr sprayed with CJS had the best corrosion resistance. IN625 was consumed almost completely during the exposure at 750 °C.

  18. Thermal Spray Coatings for High-Temperature Corrosion Protection in Biomass Co-Fired Boilers

    NASA Astrophysics Data System (ADS)

    Oksa, M.; Metsäjoki, J.; Kärki, J.

    2014-09-01

    There are over 1000 biomass boilers and about 500 plants using waste as fuel in Europe, and the numbers are increasing. Many of them encounter serious problems with high-temperature corrosion due to detrimental elements such as chlorides, alkali metals, and heavy metals. By HVOF spraying, it is possible to produce very dense and well-adhered coatings, which can be applied for corrosion protection of heat exchanger surfaces in biomass and waste-to-energy power plant boilers. Four HVOF coatings and one arc sprayed coating were exposed to actual biomass co-fired boiler conditions in superheater area with a probe measurement installation for 5900 h at 550 and 750 °C. The coating materials were Ni-Cr, IN625, Fe-Cr-W-Nb-Mo, and Ni-Cr-Ti. CJS and DJ Hybrid spray guns were used for HVOF spraying to compare the corrosion resistance of Ni-Cr coating structures. Reference materials were ferritic steel T92 and nickel super alloy A263. The circulating fluidized bed boiler burnt a mixture of wood, peat and coal. The coatings showed excellent corrosion resistance at 550 °C compared to the ferritic steel. At higher temperature, NiCr sprayed with CJS had the best corrosion resistance. IN625 was consumed almost completely during the exposure at 750 °C.

  19. Automating data analysis during the inspection of boiler tubes using line scanning thermography

    NASA Astrophysics Data System (ADS)

    Ley, Obdulia; Momeni, Sepand; Ostroff, Jason; Godinez, Valery

    2012-05-01

    Failures in boiler waterwalls can occur when a relatively small amount of corrosion and loss of metal have been experienced. This study presents our efforts towards the application of Line Scanning Thermography (LST) for the analysis of thinning in boiler waterwall tubing. LST utilizes a line heat source to thermally excite the surface to be inspected and an infrared detector to record the transient surface temperature increase observed due to the presence of voids, thinning or other defects. In waterwall boiler tubes the defects that can be detected using LST correspond to corrosion pitting, hydrogen damage and wall thinning produced by inadequate burner heating or problems with the water chemistry. In this paper we discuss how the LST technique is implemented to determine thickness from the surface temperature data, and we describe our efforts towards developing a semiautomatic analysis tool to speed up the time between scanning, reporting and implementing repairs. We compare the density of data produced by the common techniques used to assess wall thickness and the data produced by LST.

  20. Utilization of coal-water fuels in fire-tube boilers. Final report, October 1990--August 1994

    SciTech Connect

    Sommer, T.; Melick, T.; Morrison, D.

    1994-12-31

    The objective of this DOE sponsored project was to successfully fire coal-water slurry in a fire-tube boiler that was designed for oil/gas firing and establish a data base that will be relevant to a large number of existing installations. Firing slurry in a fire-tube configuration is a very demanding application because of the extremely high heat release rates and the correspondingly low furnace volume where combustion can be completed. Recognizing that combustion efficiency is the major obstacle when firing slurry in a fire-tube boiler, the program was focused on innovative approaches for improving carbon burnout without major modifications to the boiler. The boiler system was successfully designed and operated to fire coal-water slurry for extended periods of time with few slurry related operational problems. The host facility was a 3.8 million Btu/hr Cleaver-Brooks fire-tube boiler located on the University of Alabama Campus. A slurry atomizer was designed that provided outstanding atomization and was not susceptible to pluggage. The boiler was operated for over 1000 hours and 12 shipments of slurry were delivered. The new equipment engineered for the coal-water slurry system consisted of the following: combustion air and slurry heaters; cyclone; baghouse; fly ash reinjection system; new control system; air compressor; CWS/gas burner and gas valve train; and storage tank and slurry handling system.

  1. Development of remaining wall thickness measurement system for boiler wall tube using gamma scattering technique

    NASA Astrophysics Data System (ADS)

    Durongsak, K.; Yenjai, C.; Rassame, S.

    2017-06-01

    In this study, the General Monte Carlo N-Particle version 5 (MCNP5) simulation of the measuring system for the remaining thickness of the wall tube using gamma scattering technique is performed to investigate the applicability of this technique and to find the optimum geometrical setup for the experimental setup. The numerical results show that the optimal geometry condition to provide the highest ratio between the gamma flux changes per thickness variation, namely, the measurement sensitivity, is the alignment of the source incidence angle of 30 degree and detector scattering angle of 30 degrees. Sequentially, the preliminary experiment of thickness measurement system for the tube using the gamma scattering technique is conducted based on the selected geometrical test setup by the simulation. It is found that the experimental results have generally a good agreement with the calculated results. Conclusively, it is suggested that the gamma scattering technique has a potential method to measure the remaining wall thickness in the boiler wall tube.

  2. The compact circulating fluidized bed boiler with a finned tube impact separator and a uniflow square cyclone

    SciTech Connect

    Li Xiaodong; Chi Yong; Yan Jianhua; Jiang Xuguang; Yang Jialin; Huang Guoquan; Ni Mingjiang; Cen Kefa

    1999-07-01

    Institute for Thermal Power Engineering, Zhejiang University has introduced a circulating fluidized bed boiler with two stage compact separation. A finned tube impact separator is located at the outlet of the furnace and a uniflow square cyclone is adopted behind the superheater. The flow characteristics of the finned tube separator are measured using a three dimensional particles dynamics analyzer. The measurements show that the reflux flow existing near the front of a finned tube has a very important effect on particle separation. The shape of a uniflow square cyclone is different with a conventional uniflow cyclone and can be laid conveniently in the flue duct of the boiler. A lot of experimental studies have been done focusing on the above separators' performances. The experimental results show that separation efficiency of the uniflow square cyclone can be up to 99% for particles with mean size 0.167 mm and its pressure drop is lower than 1,000 Pa. To change the shape of the cyclone's exhaust pipe is very effective. Based on the results, the optimization design of the separators is reported. The finned tube impact separator has been successfully applied in several circulating fluidized bed boilers. Institute for Thermal Power Engineering, Zhejiang University has designed a compact circulating fluidized bed boiler with the finned tube impact separator and a uniflow square cyclone, and the boilers capacity is 65 t/h (12 MWe).

  3. Role of Ash Deposits in the High Temperature Corrosion of Boiler Tubes

    SciTech Connect

    Covino, B.S., Jr.; Russell, J.H.; Cramer, S.D.; Holcomb, G.R.; Bullard, S.J.; Ziomek-Moroz, M.; Matthes, S.A.; White, M.L.

    2003-03-16

    Ash deposits cause accelerated corrosion of waterwall boiler tubes in waste to energy (WTE) incinerators. To study this effect, a series of experiments were planned to determine the mechanism of corrosion of carbon steel boiler tubes under ash deposits. Results reported here were for carbon steel tubes exposed to an environment consisting of O{sub 2}, CO{sub 2}, N{sub 2}, and water vapor. Future experiments will include HCl and SO{sub 2}. Test procedures included both isothermal and thermal gradient tests. Temperatures ranged from 300 C to 510 C for the isothermal tests and a metal/gas temperature of 450/670 C for the thermal gradient test. Initial results indicated that increasing temperature caused the isothermal corrosion rates of ash-covered samples to increase. A shakedown test of a thermal gradient test apparatus was conducted at a metal/gas temperature of 450/670 C, a more severe environment than normally encountered in WTE waterwalls. Results showed that the corrosion rate under those conditions exceeds the isothermal corrosion rates at the same metal temperature by a factor of 2 or more.

  4. ANSYS Fluent Modelling of an Underexpanded Supersonic Sootblower Jet Impinging into Recovery Boiler Tube Geometries

    NASA Astrophysics Data System (ADS)

    Doroudi, Shahed

    Sootblowers generate high pressure supersonic steam jets to control fireside deposition on heat transfer tubes of a kraft recovery boiler. Sootblowing is energy expensive, using 3-12% of the mill's total steam production. This motivates research on the dynamics of sootblower jet interaction with tubes and deposits, to optimize their use. A CFD investigation was performed using ANSYS Fluent 15.0 to model three-dimensional steady-state impingement of a Mach 2.5 mildly underexpanded (PR 1.2) air jet onto arrays of cylindrical tubes with and without fins, at various nozzle-to-tube centerline offsets. A free jet and four impingement cases for each of the economizer and generating bank geometries are compared to experimental visualizations. Pressure distributions on impinging surfaces suggest that the fins in the economizer produce a reduced but uniform sootblowing force. Pressure contours along the tubes (in the vertical direction) show a sharp decline one tube diameter away from the jet mid-plane.

  5. Proceedings: Third international conference on boiler tube failures in fossil plants

    SciTech Connect

    1998-04-01

    The objectives of the conference were to review, document and transfer technology on all aspects of BTF. To meet these objectives, papers and presentations were provided on the following topics: general overview of BTF around the world; waterwall fireside corrosion; corrosion fatigue; root cause analysis; non-destructive evaluation for BTF; superheater failures; condition assessment and data acquisition; and boiler tube failure reduction programs. Each topic was discussed in a separate conference session. Discussions followed each paper and are included in the proceedings. A questionnaire was completed by the attendees on BTF and the remaining needs for research and development. The results are provided in Appendix A.

  6. Protective coatings for composite tubes in space applications

    NASA Technical Reports Server (NTRS)

    Dursch, Harry W.; Hendricks, Carl L.

    1987-01-01

    Protective coatings for graphite/epoxy (Gr/Ep) tubular structures for a Manned Space Station truss structure were evaluated. The success of the composite tube truss structure depends on its stability to long-term exposure to the Low Earth Orbit (LEO) environment with particular emphasis placed on atomic oxygen. Concepts for protectively coating Gr/Ep tubes include use of inorganic coated metal foils and electroplating. These coatings were applied to Gr/Ep tubes and then subjected to simulated LEO environmnet to evaluate survivability of coatings and coated tubes. Evaluation included: atomic oxygen resistance, changes in optical properties and adhesion, abrasion resistancem surface preparation required, coating uniformity, and formation of microcracks in the Gr/Ep tubes caused by thermal cycling. Program results demonstrated that both phosphoric and chromic acid anodized Al foil provided excellent adhesion to Gr/Ep tubes and exhibited stable optical properties when subjected to simulated LEO environment. The SiO2/Al coatings speuttered onto Al foils also resulted in an excellent protective coating. Electroplated Ni exhibited unaccepatble adhesion loss to Gr/Ep tubes during atomic oxygen exposure.

  7. Development of Computational Capabilities to Predict the Corrosion Wastage of Boiler Tubes in Advanced Combustion Systems

    SciTech Connect

    Kung, Steven; Rapp, Robert

    2014-08-31

    coal-fired boilers resulting from the coexistence of sulfur and chlorine in the fuel. A new corrosion mechanism, i.e., “Active Sulfidation Corrosion Mechanism,” has been proposed to account for the accelerated corrosion wastage observed on the furnace walls of utility boilers burning coals containing sulfur and chlorine. In addition, a second corrosion mechanism, i.e., “Active Sulfide-to-Oxide Corrosion Mechanism,” has been identified to account for the rapid corrosion attack on superheaters and reheaters. Both of the newly discovered corrosion mechanisms involve the formation of iron chloride (FeCl2) vapor from iron sulfide (FeS) and HCl, followed by the decomposition of FeCl2 via self-sustaining cycling reactions. For higher alloys containing sufficient chromium, the attack on superheaters and reheaters is dominated by Hot Corrosion in the presence of a fused salt. Furthermore, two stages of the hot corrosion mechanism have been identified and characterized in detail. The initiation of hot corrosion attack induced by molten sulfate leads to Stage 1 “acidic” fluxing and re-precipitation of the protective scale formed initially on the deposit-covered alloy surfaces. Once the protective scale is penetrated, Stage 2 Hot Corrosion is initiated, which is dominated by “basic” fluxing and re-precipitation of the scale in the fused salt. Based on the extensive corrosion information generated from this project, corrosion modeling was performed using non-linear regression analysis. As a result of the modeling efforts, two predictive equations have been formulated, one for furnace walls and the other for superheaters and reheaters. These first-of-the-kind equations can be used to estimate the corrosion rates of boiler tubes based on coal chemistry, alloy compositions, and boiler operating conditions for advanced boiler systems.

  8. The use of Medpor coated tear drainage tube in conjunctivodacryocystorhinostomy.

    PubMed

    Fan, X; Bi, X; Fu, Y; Zhou, H

    2008-09-01

    To analyse outcomes of lacrimal bypass surgery with the Medpor coated tear drainage tube. A total of 26 eyes in 26 patients with persistent epiphora who failed canaliculoanastomosis and dacryocystorhinostomy were treated by the lacrimal bypass surgery with the Medpor coated tear drainage tubes. Ten cases of severe obstruction of punctum and canaliculi and 16 cases with both upper system and lacrimal sac obstruction comprised this cohort of patients. No tube extrusion or displacement was observed after 6-28 months of follow-up. Complete or significant resolution of epiphora was achieved in 23/26 cases (88.5%). Luminal obstruction by debris was noted in nine eyes, ocular discomfort in four, improper tube size selection in two, malposition in one, infection in one, diplopia in one, corneal abrasion in one, and reflux of intranasal secretion into fornix in another. Medpor coated tear drainage tube offers tube stabilization in minimizing tube extrusion and displacement.

  9. Thermographic Imaging of Material Loss in Boiler Water-Wall Tubing by Application of Scanning Line Source

    NASA Technical Reports Server (NTRS)

    Cramer, K. Elliott; Winfree, William P.

    2000-01-01

    Localized wall thinning due to corrosion in utility boiler water-wall tubing is a significant inspection concern for boiler operators. Historically, conventional ultrasonics has been used for inspection of these tubes. This technique has proven to be very manpower and time intensive. This has resulted in a spot check approach to inspections, documenting thickness measurements over a relatively small percentage of the total boiler wall area. NASA Langley Research Center has developed a thermal NDE technique designed to image and quantitatively characterize the amount of material thinning present in steel tubing. The technique involves the movement of a thermal line source across the outer surface of the tubing followed by an infrared imager at a fixed distance behind the line source. Quantitative images of the material loss due to corrosion are reconstructed from measurements of the induced surface temperature variations. This paper will present a discussion of the development of the thermal imaging system as well as the techniques used to reconstruct images of flaws. The application of the thermal line source coupled with the analysis technique represents a significant improvement in the inspection speed for large structures such as boiler water-walls. A theoretical basis for the technique will be presented which explains the quantitative nature of the technique. Further, a dynamic calibration system will be presented for the technique that allows the extraction of thickness information from the temperature data. Additionally, the results of applying this technology to actual water-wall tubing samples and in situ inspections will be presented.

  10. Model boiler testing to evaluate inhibitors for caustic induced stress corrosion cracking of Alloy 600 tubes

    SciTech Connect

    Daret, J.; Paine, J.P.N.; Partridge, M.J.

    1995-12-31

    A series of model boiler tests, using a mixture of precracked and non-precracked (virgin) tube-to-tube support plate intersections was performed. The testing supported the qualification of inhibitors for mitigating the secondary side corrosion of alloy 600 steam generator tubes. Many utilities suspect that the caustic impurities come from the feedwater. Candidate inhibitors included boric acid (as a reference), cerous acetate, and two forms of titanium dioxide: a laboratory produced titania-silica sol-gel, and manometer sized anatase The latter was combined with a 150 C pre-soaking with a titanium lactate, and was tested with and without a zeta potential treatment by sodium aluminate. Effectiveness of boric acid to prevent and retard caustic induced intergranular corrosion was confirmed in all crevice configurations (open and packed). The cerous acetate treatment multiplied by two to four the time necessary to detect a primary-to-secondary leak on virgin tubes, and reduced the propagation rate on precracked tubes. Cerium was found intimately mixed, as cerianite, with the free span and crevice deposits, when the crevices were sufficiently accessible. Due to its very low solubility and large particle size, the titania-silica sol-gel was unable to penetrate the crevices and had no effect on the degradation process. The nanometric particle size titania treatment and/or the preceding soaking with soluble titanium lactate drastically increased the titanium concentration in free span and open crevice deposit (with no added sodium aluminate, titania reacted with magnetite to form ilmenite) and showed undeniable capacity to prevent tubing degradation. Its effectiveness, in the case of packed crevices and for arresting cracks, was not so conclusive.

  11. Corrosion/erosion detection of boiler tubes utilizing pulsed infrared imaging

    NASA Astrophysics Data System (ADS)

    Bales, Maurice J.; Bishop, Chip C.

    1995-05-01

    This paper discusses a new technique for locating and detecting wall thickness reduction in boiler tubes caused by erosion/corrosion. Traditional means for this type of defect detection utilizes ultrasonics (UT) to perform a point by point measurement at given intervals of the tube length, which requires extensive and costly shutdown or `outage' time to complete the inspection, and has led to thin areas going undetected simply because they were located in between the sampling points. Pulsed infrared imaging (PII) can provide nearly 100% inspection of the tubes in a fraction of the time needed for UT. The IR system and heat source used in this study do not require any special access or fixed scaffolding, and can be remotely operated from a distance of up to 100 feet. This technique has been tried experimentally in a laboratory environment and verified in an actual field application. Since PII is a non-contact technique, considerable time and cost savings should be realized as well as the ability to predict failures rather than repairing them once they have occurred.

  12. Status Report on Studies of Recovery Boiler Composite Floor Tube Cracking

    SciTech Connect

    Eng, P.; Frederick, L.A.; Hoffmann, C.M.; Keiser, J.R.; Mahmood, J.; Maziasz, P.J.; Prescott, R.; Sarma, G.B.; Singbeil, D.L.; Singh, P.M.; Swindeman, R.W.; Wang, X.-L.

    1999-09-12

    Cracking of the stainless steel layer of co-extruded 304L stainless steel/SA210 Gd A 1 carbon steel black liquor recovery boiler floor tubes has been identified as one of the most serious material problems in the pulp and paper industry. A DOE-funded study was initiated in 1995 with the goal of determining the cause of and possible solutions to this cracking problem. These studies have characterized tube cracking as well as the chemical and thermal environment and stress state of floor tubes. Investigations of possible cracking mechanisms indicate that stress corrosion cracking rather than thermal fatigue is a more likely cause of crack initiation. The cracking mechanism appears to require the presence of hydrated sodium sulfide and is most likely active during shut-downs and/or start-ups. Based on these results and operating experience, certain alloys appear to be more resistant than others to cracking in the floor environment, and certain operating practices appear to significantly lessen the likelihood of cracking. This report is the latest in a series of progress reports presented on this project.

  13. Experimental investigation on heat transfer and frictional characteristics of vertical upward rifled tube in supercritical CFB boiler

    SciTech Connect

    Yang, Dong; Pan, Jie; Zhu, Xiaojing; Bi, Qincheng; Chen, Tingkuan; Zhou, Chenn Q.

    2011-02-15

    Water wall design is a key issue for supercritical Circulating Fluidized Bed (CFB) boiler. On account of the good heat transfer performance, rifled tube is applied in the water wall design of a 600 MW supercritical CFB boiler in China. In order to investigate the heat transfer and frictional characteristics of the rifled tube with vertical upward flow, an in-depth experiment was conducted in the range of pressure from 12 to 30 MPa, mass flux from 230 to 1200 kg/(m{sup 2} s), and inner wall heat flux from 130 to 720 kW/m{sup 2}. The wall temperature distribution and pressure drop in the rifled tube were obtained in the experiment. The normal, enhanced and deteriorated heat transfer characteristics were also captured. In this paper, the effects of pressure, inner wall heat flux and mass flux on heat transfer characteristics are analyzed, the heat transfer mechanism and the frictional resistance performance are discussed, and the corresponding empirical correlations are presented. The experimental results show that the rifled tube can effectively prevent the occurrence of departure from nucleate boiling (DNB) and keep the tube wall temperature in a permissible range under the operating condition of supercritical CFB boiler. (author)

  14. Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semi-annual technical progress report, February 1996--July 1996

    SciTech Connect

    Banovic, S.W.; Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1996-08-01

    Present coal-fired boiler environments remain hostile to the materials of choice since corrosion and erosion can be a serious problem in certain regions of the boiler. Recently, the Clean Air Act Amendment is requiring electric power plants to reduce NO{sub x}, emissions to the environment. To reduce NO{sub x}, emissions, new low NO{sub x}, combustors are utilized which burn fuel with a substoichiometric amount of oxygen (i.e., low oxygen partial pressure). In these low NO{sub x} environments, H{sub 2}S gas is a major source of sulfur. Due to the sulfidation process, corrosion rates in reducing parts of boilers have increased significantly and existing boiler tube materials do not always provide adequate corrosion resistance. Combined attack due to corrosion and erosion is a concern because of the significantly increased operating costs which result in material failures. One method to combat corrosion and erosion in coal-fired boilers is to apply coatings to the components subjected to aggressive environments. Thermal spray coatings, a cermet composite comprised of hard ceramic phases of oxide and/or carbide in a metal binder, have been used with some success as a solution to the corrosion and erosion problems in boilers. However, little is known on the effect of the volume fraction, size, and shape of the hard ceramic phase on the erosion and corrosion resistance of the thermally sprayed coatings. It is the objective of this research to investigate metal matrix composite (cermet) coatings in order to determine the optimum ceramic/metal combination that will give the best erosion and corrosion resistance in new advanced coal-fired boilers.

  15. Method of coating graphite tubes with refractory metal carbides

    DOEpatents

    Wohlberg, C.

    1973-12-11

    A method of coating graphite tubes with a refractory metal carbide is described. An alkali halide is reacted with a metallic oxide, the metallic portion being selected from the IVth or Vth group of the Periodic Table, the resulting salt reacting in turn with the carbon to give the desired refractory metal carbide coating. (Official Gazette)

  16. Causes and solutions for cracking of coextruded and weld overlay floor tubes in black liquor recovery boilers

    SciTech Connect

    Keiser, J.R.; Taljat, B.; Wang, X.L.

    1998-09-01

    Cracking of coextruded, black liquor recovery boiler floor tubes is both a safety and an economic issue to mill operators. In an effort to determine the cause of the cracking and to identify a solution, extensive studies, described in this and three accompanying papers, are being conducted. In this paper, results of studies to characterize both the cracking and the chemical and thermal environment are reported. Based on the results described in this series of papers, a possible mechanism is presented and means to lessen the likelihood of cracking or to totally avoid cracking of floor tubes are offered.

  17. Etching of Copper Coated Mylar Tubes With CF-4 Gas

    DOE PAGES

    Ecklund, Karl M.; Hartman, Keith W.; Hebert, Michael J.; ...

    1996-04-01

    Using 5 mm diameter copper coated mylar straw tubes at a potential of 2.30 KV relative to a concentric 20 (mu)m diameter gold-plated tungsten anode, it has been observed that with very low flow rates of CF4-based gases the conductive copper cathode material may be removed entirely from the mylar surface.

  18. Degradation behavior of Ni{sub 3}Al plasma-sprayed boiler tube steels in an energy generation system

    SciTech Connect

    Sidhu, B.S.; Prakash, S.

    2005-06-01

    Boiler steels, namely, low-C steel, ASTM-SA210-Grade A1 (GrA1), 1Cr-0.5Mo steel, ASTM-SA213-T-11 (T11) and 2.25Cr-1Mo steel, ASTM-SA213-T-22 (T22) were plasma sprayed with Ni3Al. The alloy powder was prepared by mixing Ni and Al in the stoichiometric ratio of 3 to 1. The Ni-22Cr-10Al-1Y alloy powder was used as a bond coat, with a 150{mu} m thick layer sprayed onto the surface before applying the 200{mu}m coating of Ni{sub 3}Al. Exposure studies have been performed in the platen superheater zone of a coal-fired boiler at around 755{sup o}C for 10 cycles, each of 100 h duration. The protection to the base steel was minimal for the three steels. Scale spallation and the formation of a porous and nonadherent NiO scale were probably the main reasons for the lack of protection. In the case of T22-coated steel, cracks in the coatings have been observed after the first 100 h exposure cycle.

  19. Assessment of current NDI techniques for determining the type, location, and extent of fossil-fired boiler tube damage. Final report

    SciTech Connect

    Reinhart, E.R.; Johnson, D.; Sarian, S.

    1980-10-01

    Assessment of state-of-the-art nondestructive evaluation techniques for detecting the type, location, and extent of fossil-fired boiler tube damage was made through on-site visits and canvassing by questionnaire. The results of this survey indicate that state-of-the-art for fossil fired boiler tube NDE practice is limited almost exclusively, in order of use frequency, to: (1) magnetic particle/dye penetrant, (2) ultrasonic testing (UT), (3) visual, including fiber-optic/borescope and TV, and (4) radiography. None of these techniques are adequate for reliably detecting and sizing boiler tube damage, and they suffer from low inspection volume coverage, i.e., they are limited to small localized checking of suspect troublespots. Our survey shows that boiler inspection using even these four methods is not practiced routinely but only after a forced outage has occurred. While there is a wide spectrum of boiler tube damage which results in failures forcing complete or partial outages, our survey indicates that: (1) wall thinning and wastage by erosion/corrosion, (2) overheating, and (3) hydrogen damage are the most prevalent failure modes for fossil fired boilers. Our survey also shows that at least one-quarter to one-third of the failures forcing a full outage occur in the furnace wall tube bank and reducing the number of these failures alone would result in considerable savings to the utilities. We recommend that EPRI undertake a research and development program for the purpose of providing the utilities with a practical NDE capability for inspecting boiler tubes.

  20. Development of a low-NO{sub x} fire-tube boiler based on enhanced flame cooling

    SciTech Connect

    Varga, Z.; Novak, P.

    1997-12-31

    This paper addresses a method of reducing nitrogen oxide (NO{sub x}) emissions from commercial and industrial fire-tube gas- and oil-fired boilers operating with higher static pressure burners. For boilers in this class, internal or external flue gas recirculation is a popular NO{sub x} reduction strategy. The main disadvantages are high costs, due to the introduction of redesigned burners and external gas recirculation equipment, and increased complexity of operation and control. Coordinated design of the combustion chamber is another tool that can be used to affect the NO{sub x} emissions. In this study, the approach of increasing flame cooling by simple mechanical means has been evaluated. Tests show that this approach can reduce NO{sub x} emissions up to 40% with gas and oil firing. Additionally, these changes in the combustion chamber increased the thermal efficiency of the boiler over the entire load range and especially at reduced loads, leading to significant annual fuel savings.

  1. Single Wall Carbon Nano Tube Films and Coatings

    NASA Astrophysics Data System (ADS)

    Sreekumar, T. V.; Kumar, Satish; Ericson, Lars M.; Smalley, Richard E.

    2002-03-01

    Purified single wall carbon nano tubes (SWNTs) produced from the high-pressure carbon monoxide (HiPCO) process have been dissolved /dispersed in oleum. These solutions /dispersions were optically homogeneous and have been used to form stand-alone SWNT films. The washed, dried, and heat-treated films are isotropic. The scanning electron micrographs of the film surface shows that the nanotube ropes (or fibrils) of about 20 nm diameters are arranged just like macroscopic fibers in a non-woven fabric. Polarized Raman spectroscopy of the SWNT film confirms the isotropic nature of these films. The films are being characterized for their thermal, mechanical as well electrical properties. Thin nano tube coatings, including optically transparent coatings, have also been made on a variety of substrates such as glass, polyethylene, polystyrene, polypropylene, silicon wafer, as well as stainless steel.

  2. Oxidation study by Mössbauer and optic microscopy of steels from boiler tubes used in sugar industry

    NASA Astrophysics Data System (ADS)

    Fajardo, M.; Pérez Alcázar, G. A.; Aguilar, Y.

    1998-08-01

    Optic microscopy and Mössbauer spectroscopy were used to study the fail and the inner rusted surface of two boiler tubes used in the sugar industry, respectively. The studied tubes, of the type ASTM A 192, were found to have cracks. By optic microscopy it was observed that the failure begins in the inner surface with circumferential cracking. Also, inside and around the surface close to the cracks a rusted layer was detected. Powder from these layers was collected for Mössbauer spectroscopy analysis. By this method the presence of two or three types of Fe oxides such as wüstite, magnetite and hematite, was proved. These results permit to conclude that the failure mechanism was the thermal fatigue due to a hot work in an O2 -rich vapor atmosphere. The rusted products are stable at high temperatures.

  3. Halloysite tubes as nanocontainers for anticorrosion coating with benzotriazole.

    PubMed

    Abdullayev, Elshad; Price, Ronald; Shchukin, Dmitry; Lvov, Yuri

    2009-07-01

    Halloysite clay nanotubes were investigated as a tubular container for the corrosion inhibitor benzotriazole. Halloysite is a naturally occurring cylindrical clay mineral with an internal diameter in the nanometer range and a length up to several micrometers, yielding a high-aspect-ratio hollow tube structure. Halloysite may be used as an additive in paints to produce a functional composite coating material. A maximum benzotriazole loading of 5% by weight was achieved for clay tubes of 50 nm external diameters and lumen of 15 nm. Variable release rates of the corrosion inhibitor were possible in a range between 5 and 100 h, as was demonstrated by formation of stoppers at tube openings. The anticorrosive performance of the sol-gel coating and paint loaded with 2-5% of halloysite-entrapped benzotriazole was tested on copper and on 2024-aluminum alloy by direct exposure of the metal plates to corrosive media. Kinetics of the corrosion spot formation at the coating defects was analyzed by the scanning vibrating electrode technique, and an essential damping of corrosion development was demonstrated for halloysite-loaded samples.

  4. IGA/SCC crack propagation rate measurements on Alloy 600 SG tubing and evaluation of crevice environments using a side stream model boiler

    SciTech Connect

    Tsuruta, T.; Okamoto, S.; Kitera, T.; Takamatsu, H.; Matsunaga, T.

    1995-12-31

    Two major research objectives, IGA/SCC crack propagation rate measurement using predefected Alloy 600 tubes and the evaluation of crevice environments, were tested in side stream model boilers at Ohi Unit 1. The results of IGA/SCC propagation rate measurements using several types of predefected tubes were previously reported at the 6th symposium. The results of crevice environment evaluation by analyzing the directly sampled concentrated crevice solutions were also previously reported at the 5th symposium. These measurements have been continued using side stream model boilers at Ohi unit 1, and interim results are presented in this report.

  5. Life assessment of boiler pressure parts. Volume 7, Life assessment technology for superheater/reheater tubes: Final report

    SciTech Connect

    Grunloh, H.J.; Ryder, R.H.

    1993-11-01

    The severe environment in which superheater and reheater tubes operate can lead to premature failure by the interaction of possible damage mechanisms. One such mechanism, creep-rupture, has been studied extensively and the means of measuring the extent of such damage and the methods of assessing its effects on the remaining service life of superheater/reheater tubes are the subjects of this volume. A study was initially performed to identify techniques in current use in industry for measuring parameters that are pertinent to the creep-rupture damage mechanisms. A plan was implemented to apply these techniques in the field, at two selected host utility boilers, and in the laboratory. The field studies included tracking failure histories, assembling representative sets of plant operating data, installing inlet and outlet pad-type thermocouples, designing and installing in-furnace chordal-type thermocouples, conducting component-wide steamside oxide and tube wall thickness surveys, and selecting and extracting tube samples for laboratory evaluations. The laboratory studies included metallographic measurement of steamside oxide and tube wall thicknesses, accelerated creep-rupture testing, including tube burst tests and miniature uniaxial creep-rupture tests, and ultimate tensile strength testing. Evaluations on the use of ultrasonic methods for measuring oxide and tube wall thickness are offered, newly-developed creep-rupture life and creep strain rate models are presented, and recommendations are made concerning the optimal stress formula for use in damage assessment and remaining life calculations. Recommendations are made for use of an integrated application of inspection and calculational methods incorporating simplified probabilistic techniques to efficiently conduct component-wide evaluations.

  6. Comparison of Medpor Coated Tear Drainage Tube versus Silicon Tear Drainage Tube in Conjunctivodacryocystorhinostomy: Problems and Solutions

    PubMed Central

    Sendul, Selam Yekta; Cagatay, Halil Huseyin; Dirim, Burcu; Demir, Mehmet; Yıldız, Ali Atakhan; Acar, Zeynep; Cinar, Sonmez; Guven, Dilek

    2014-01-01

    Purpose. This study aims at comparing two different types of drainage tubes in conjunctivodacryocystorhinostomy, which are used for upper lacrimal system obstruction or damage, with respect to their respective postoperative problems and solutions. Methods. Nineteen eyes of 17 patients who underwent conjunctivodacryocystorhinostomy (CDCR) or conjunctivorhinostomy (CR) surgery with a Medpor coated tear drainage tube or silicon tube placement between October, 2010, and February, 2014, were included in this retrospective comparative study. Results. In the initial surgery, Medpor coated tear drainage tubes were used in 11 eyes by CDCR, whereas silicon tear drainage tubes were implanted into 2 eyes by CR and 6 eyes by CDCR. In group 1, proximal and distal obstructions developed postoperatively in 4 eyes, while 1 eye showed tube malposition and 3 eyes developed luminal obstruction by debris 3 times. In group 2, tube extrusion developed in 4 eyes, whereas tube malposition developed in 6 eyes and luminal obstruction by debris developed in 6 eyes at different times, for a total of 20 times. Conclusions. In our study, the most significant complication we observed in the use of silicon tear drainage tubes was tube extrusion,whereas the leading complication related to the use of Medpor coated tear drainage tubes was tube obstruction. PMID:25379518

  7. Comparison of Medpor coated tear drainage tube versus silicon tear drainage tube in conjunctivodacryocystorhinostomy: problems and solutions.

    PubMed

    Sendul, Selam Yekta; Cagatay, Halil Huseyin; Dirim, Burcu; Demir, Mehmet; Yıldız, Ali Atakhan; Acar, Zeynep; Cinar, Sonmez; Guven, Dilek

    2014-01-01

    This study aims at comparing two different types of drainage tubes in conjunctivodacryocystorhinostomy, which are used for upper lacrimal system obstruction or damage, with respect to their respective postoperative problems and solutions. Nineteen eyes of 17 patients who underwent conjunctivodacryocystorhinostomy (CDCR) or conjunctivorhinostomy (CR) surgery with a Medpor coated tear drainage tube or silicon tube placement between October, 2010, and February, 2014, were included in this retrospective comparative study. In the initial surgery, Medpor coated tear drainage tubes were used in 11 eyes by CDCR, whereas silicon tear drainage tubes were implanted into 2 eyes by CR and 6 eyes by CDCR. In group 1, proximal and distal obstructions developed postoperatively in 4 eyes, while 1 eye showed tube malposition and 3 eyes developed luminal obstruction by debris 3 times. In group 2, tube extrusion developed in 4 eyes, whereas tube malposition developed in 6 eyes and luminal obstruction by debris developed in 6 eyes at different times, for a total of 20 times. In our study, the most significant complication we observed in the use of silicon tear drainage tubes was tube extrusion,whereas the leading complication related to the use of Medpor coated tear drainage tubes was tube obstruction.

  8. Ionic liquid coated copper wires and tubes for fiber-in-tube solid-phase microextraction.

    PubMed

    Sun, Min; Feng, Juanjuan; Bu, Yanan; Luo, Chuannan

    2016-08-05

    A fiber-in-tube solid-phase microextraction (SPME) device was developed by filling eleven copper wires into a copper tube, and all of those were functionalized with ionic liquids. Its morphology and surface properties were characterized by scanning electron microscopy. It was connected into high performance liquid chromatography (HPLC) equipment by replacing the sample loop of six-port injection valve, building the online SPME-HPLC system. In the optimization of extraction conditions, sampling rate, sample volume, pH of sample and desorption time were investigated with five estrogens as model analytes. Under the optimum conditions, an online SPME-HPLC analysis method was achieved, showing enrichment efficiency from 611 to 1661 and a good linearity of 0.06-60μgL(-1) with low detection limits of 0.02-0.05μgL(-1). It was applied to detect estrogens analytes in two water samples, with recoveries in the range of 85-114%. Relative standard deviation (n=3) of extraction repeatability is in the range of 1.9-3.0%. Relative standard deviation of extraction tubes (n=3) is in the range of 12-19%. The extraction mechanism is probably related to hydrophobic, π-π and dipole-dipole interactions between ionic liquids coating and estrogens analytes.

  9. Superior Corrosion Resistance Properties of TiN-Based Coatings on Zircaloy Tubes in Supercritical Water

    SciTech Connect

    Fauzia Khatkhatay; Liang Jiao; Jie Jian; Zhijie Jiao; Hongbin Zhang; Jian Gan; Haiyan Wang; Wenrui Zhang; Xinghang Zhang

    2014-08-01

    Thin films of TiN and Ti0.35Al0.65N nanocomposite were deposited on polished Zircaloy-4 tubes. After exposure to supercritical water for 48 h, the coated tubes are remarkably intact, while the bare uncoated tube shows severe oxidation and breakaway corrosion. X-ray diffraction patterns, secondary electron images, backscattered electron images, and energy dispersive X-ray spectroscopy data from the tube surfaces and cross-sections show that a protective oxide, formed on the film surface, effectively prevents further oxidation and corrosion to the Zircaloy-4 tubes. This result demonstrates the effectiveness of thin film ceramics as protective coatings under extreme environments.

  10. Substantiation of causes for damage of water-wall tubes of an external salt compartment of a high-pressure boiler

    NASA Astrophysics Data System (ADS)

    Fedorov, A. I.

    2014-10-01

    The damageability for water-wall tubes of an external salt compartment of a TPE-208 boiler is analyzed. The general cause for tube damage is the intensive underslime corrosion of the inner surface, which is caused by a local increase in the salt concentration in boiler water. The experiment-calculated method showed that continuous bleeding from an external cyclone being the first in water downstream causes a substantial increase in the concentration of salts (more than by a factor of three) and scale-forming agents within a contour of the loop of a distant cyclone in comparison with the variant of bleeding from a loop being the second in water downstream.

  11. Design Model for the Heat Transfer in a Short Straight Tube Boiler.

    DTIC Science & Technology

    1981-06-01

    in vertical upflow for Re򒾐. Water properties are evaluated at the film tempera- ture; Prw, at the wall temperature. The work done by Sieder and...Boiling and Condensation, McGraw-Hill Book Co., New York, 1972. 16. Sieder , E.N., and Tate, C.E., Heat Transfer and Pressure Drop of Liquids in Tubes, Inc

  12. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings - phase II

    SciTech Connect

    Blough, J.L.; Stanko, G.J.

    1996-08-01

    In Phase I a variety of developmental and commercial tubing alloys and claddings were exposed to laboratory fireside corrosion testing simulating a superheater or reheater in a coal-fired boiler. Phase II (in situ testing) has exposed samples of 347, RA-8511, HR3C, 253MA, Fe{sub 3}Al + 5Cr, 310 modified, 800HT, NF 709, 690 clad, and 671 clad for over 10,000 hours to the actual operating conditions of a 250-MW coal-fired boiler. The samples were installed on an air-cooled, retractable corrosion probe, installed in the reheater cavity, and controlled to the operating metal temperatures of an existing and advanced-cycle coal-fired boiler. Samples of each alloy will be exposed for 4000, 12,000, and 16,000 hours of operation. The results will be presented for the metallurgical examination of the corrosion probe samples after 4000 hours of exposure.

  13. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings -- Phase 2 field testing

    SciTech Connect

    Blough, J.L.

    1996-08-01

    In Phase 1 of this project, a variety of developmental and commercial tubing alloys and claddings was exposed to laboratory fireside corrosion testing simulating a superheater or reheater in a coal-fired boiler. Phase 2 (in situ testing) has exposed samples of 347, RA85H, HR3C, 253MA, Fe{sub 3}Al + 5Cr, 310 modified, NF 709, 690 clad, and 671 clad for over 10,000 hours to the actual operating conditions of a 250-MW coal-fired boiler. The samples were installed on air-cooled, retractable corrosion probes, installed in the reheater cavity, controlled to the operating metal temperatures of an existing and advanced-cycle, coal-fired boiler. Samples of each alloy are being exposed for 4,000, 12,000, and 16,000 hours of operation. The present results are for the metallurgical examination of the corrosion probe samples after approximately 4,400 hours of exposure.

  14. A numerical model prediction for boiling multi channel flow rate distribution and application in 600MW supercritical variable-pressure once-through boiler with vertical tube coils

    NASA Astrophysics Data System (ADS)

    Chen, Tingkuan; Xu, Jinliang; Wu, Lucheng

    1996-04-01

    Flow rate distribution is important in a multi channel system when the flow is heated non-uniformly. This paper describes a steady state approach for obtaining the flow distribution among various tubes of complex multi channel system. Based on the present approach, a program has been developed, which is directly applied in thermal hydraulic design and investigation of 600MW supercritical variable-pressure once through boiler.

  15. Combustion monitoring of a water tube boiler using a discriminant radial basis network.

    PubMed

    Sujatha, K; Pappa, N

    2011-01-01

    This research work includes a combination of Fisher's linear discriminant (FLD) analysis and a radial basis network (RBN) for monitoring the combustion conditions for a coal fired boiler so as to allow control of the air/fuel ratio. For this, two-dimensional flame images are required, which were captured with a CCD camera; the features of the images-average intensity, area, brightness and orientation etc of the flame-are extracted after preprocessing the images. The FLD is applied to reduce the n-dimensional feature size to a two-dimensional feature size for faster learning of the RBN. Also, three classes of images corresponding to different burning conditions of the flames have been extracted from continuous video processing. In this, the corresponding temperatures, and the carbon monoxide (CO) emissions and those of other flue gases have been obtained through measurement. Further, the training and testing of Fisher's linear discriminant radial basis network (FLDRBN), with the data collected, have been carried out and the performance of the algorithms is presented.

  16. PLASMA SPRAYED Ni-Al COATINGS FOR SAFE ENDING HEAT EXCHANGER TUBES

    SciTech Connect

    ALLAN,M.L.; OTTERSON,D.; BERNDT,C.C.

    1998-11-01

    Brookhaven National Laboratory (BNL) has developed thermally conductive composite liners for corrosion and scale protection in heat exchanger tubes exposed to geothermal brine. The liners cannot withstand roller expansion to connect the tubes to the tubesheet. It is not possible to line the ends of the tubes with the same material after roller expansion due to the nature of the current liner application process. It was requested that BNL evaluate plasma sprayed Ni-Al coatings for safe ending heat exchanger tubes exposed to geothermal brine. The tubes of interest had an internal diameter of 0.875 inches. It is not typical to thermal spray small diameter components or use such small standoff distances. In this project a nozzle extension was developed by Zatorski Coating Company to spray the tube ends as well as flat coupons for testing. Four different Ni-Al coatings were investigated. One of these was a ductilized Ni-AIB material developed at Oak Ridge National Laboratory. The coatings were examined by optical and scanning electron microscopy. In addition, the coatings were analyzed by X-ray diffraction and subjected to corrosion, tensile adhesion, microhardness and field tests in a volcanic pool in New Zealand. It was determined that the Ni-Al coatings could be applied to a depth of two inches on the tube ends. When sprayed on flat coupons the coatings exhibited relatively high adhesion strength and microhardness. Polarization curves showed that the coating performance was variable. Measured corrosion potentials indicated that the Ni-Al coatings are active towards steel coated with thermally conductive polymers, thereby suggesting preferential corrosion. Corrosion also occurred on the coated coupons tested in the volcanic pool. This may have been exacerbated by the difficulty in applying a uniform coating to the coupon edges. The Ni-Al coatings applied to the tubes had significant porosity and did not provide adequate corrosion protection. This is associated with

  17. Linear regression analysis of emissions factors when firing fossil fuels and biofuels in a commercial water-tube boiler

    SciTech Connect

    Sharon Falcone Miller; Bruce G. Miller

    2007-12-15

    This paper compares the emissions factors for a suite of liquid biofuels (three animal fats, waste restaurant grease, pressed soybean oil, and a biodiesel produced from soybean oil) and four fossil fuels (i.e., natural gas, No. 2 fuel oil, No. 6 fuel oil, and pulverized coal) in Penn State's commercial water-tube boiler to assess their viability as fuels for green heat applications. The data were broken into two subsets, i.e., fossil fuels and biofuels. The regression model for the liquid biofuels (as a subset) did not perform well for all of the gases. In addition, the coefficient in the models showed the EPA method underestimating CO and NOx emissions. No relation could be studied for SO{sub 2} for the liquid biofuels as they contain no sulfur; however, the model showed a good relationship between the two methods for SO{sub 2} in the fossil fuels. AP-42 emissions factors for the fossil fuels were also compared to the mass balance emissions factors and EPA CFR Title 40 emissions factors. Overall, the AP-42 emissions factors for the fossil fuels did not compare well with the mass balance emissions factors or the EPA CFR Title 40 emissions factors. Regression analysis of the AP-42, EPA, and mass balance emissions factors for the fossil fuels showed a significant relationship only for CO{sub 2} and SO{sub 2}. However, the regression models underestimate the SO{sub 2} emissions by 33%. These tests illustrate the importance in performing material balances around boilers to obtain the most accurate emissions levels, especially when dealing with biofuels. The EPA emissions factors were very good at predicting the mass balance emissions factors for the fossil fuels and to a lesser degree the biofuels. While the AP-42 emissions factors and EPA CFR Title 40 emissions factors are easier to perform, especially in large, full-scale systems, this study illustrated the shortcomings of estimation techniques. 23 refs., 3 figs., 8 tabs.

  18. Pool boiling of nanofluids on rough and porous coated tubes: experimental and correlation

    NASA Astrophysics Data System (ADS)

    Cieśliński, Janusz T.; Kaczmarczyk, Tomasz Z.

    2014-06-01

    The paper deals with pool boiling of water-Al2O3 and water- Cu nanofluids on rough and porous coated horizontal tubes. Commercially available stainless steel tubes having 10 mm outside diameter and 0.6 mm wall thickness were used to fabricate the test heater. The tube surface was roughed with emery paper 360 or polished with abrasive compound. Aluminium porous coatings of 0.15 mm thick with porosity of about 40% were produced by plasma spraying. The experiments were conducted under different absolute operating pressures, i.e., 200, 100, and 10 kPa. Nanoparticles were tested at the concentration of 0.01, 0.1, and 1% by weight. Ultrasonic vibration was used in order to stabilize the dispersion of the nanoparticles. It was observed that independent of operating pressure and roughness of the stainless steel tubes addition of even small amount of nanoparticles augments heat transfer in comparison to boiling of distilled water. Contrary to rough tubes boiling heat transfer coefficient of tested nanofluids on porous coated tubes was lower compared to that for distilled water while boiling on porous coated tubes. A correlation equation for prediction of the average heat transfer coefficient during boiling of nanofluids on smooth, rough and porous coated tubes is proposed. The correlation includes all tested variables in dimensionless form and is valid for low heat flux, i.e., below 100 kW/m2.

  19. Performance of Detonation Gun-Sprayed Ni-20Cr Coating on ASTM A213 TP347H Steel in a Boiler Environment

    NASA Astrophysics Data System (ADS)

    Kaushal, G.; Singh, H.; Prakash, S.

    2012-09-01

    Detonation gun-sprayed coatings are known for their high density, high bond strength, moderate substrate heating, superior surface finish, better wear/corrosion resistance, and low cost. In this study, detonation gun-spraying technique was used to deposit Ni-20Cr coating on a commonly used boiler steel ASTM A213 TP347H. The specimens with and without coating were subjected to cyclic oxidation testing at an elevated temperature of 700 °C in actual boiler environment to ascertain the usefulness of the coating. The mass change technique was used to establish the kinetics of erosion-corrosion. XRD and SEM/EDS techniques were used to analyze the exposed samples. The uncoated sample suffered from erosion, and a significant mass loss was recorded. It was observed that overall mass loss was reduced by 83% and thickness loss by 53% after the application of the coating. The detonation gun-sprayed Ni-20 Cr coating was found to be suitable to impart erosion resistance to the given steel in the actual boiler environment.

  20. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings -- Phase 2

    SciTech Connect

    Blough, J.L.; Seitz, W.W.

    1997-12-01

    In Phase 1 a variety of developmental and commercial tubing alloys and claddings were exposed to laboratory fireside corrosion testing simulating a superheater or reheater in a coal-fired boiler. Phase 2 (in situ testing) has exposed samples of 347 RA-85H, HR3C, 253MA, Fe{sub 3}Al + 5Cr, 310 Ta modified, NF 709, 690 clad, and 671 clad for approximately 4,000, 12,000, and 16,000 hours to the actual operating conditions of a 250-MW coal-fired boiler. The samples were assembled on an air-cooled, retractable corrosion probe, the probe was installed in the reheater activity of the boiler and controlled to the operating metal temperatures of an existing and advanced-cycle coal-fired boiler. The results will be presented for the preliminary metallurgical examination of the corrosion probe samples after 16,000 hours of exposure. Continued metallurgical and interpretive analysis is still on going.

  1. A randomized double-blind controlled trial of phosphorylcholine-coated tympanostomy tube versus standard tympanostomy tube in children with recurrent acute and chronic otitis media.

    PubMed

    Hong, Paul; Smith, Neil; Johnson, Liane B; Corsten, Gerard

    2011-01-01

    To compare the postoperative complication rates of phosphorylcholine-coated fluoroplastic tympanostomy tubes versus uncoated fluoroplastic tympanostomy tubes. A prospective randomized double-blind controlled trial in children with recurrent acute otitis media and chronic otitis media with effusion; 240 children were randomized to receive a phosphorylcholine-coated tube in one ear and an uncoated tube in the other. Postoperatively, patients were assessed at 2 weeks and 4, 8, 12, 18, and 24 months to ascertain the incidence of otorrhea, tube lumen blockage, and early extrusion. Out of 240 children, 5 withdrew and 16 were lost to early follow-up. The mean age was 43.8 months. There were no statistically significant differences in the incidence of postoperative otorrhea, tube blockage, and extrusion. Phosphorylcholine-coated fluoroplastic ventilation tubes do not offer any advantages over uncoated standard fluoroplastic tympanostomy tubes.

  2. Plasma Sprayed Ni-Al Coatings for Safe Ending Heat Exchanger Tubes

    SciTech Connect

    Allen, M.L.; Berndt, C.C.; Otterson, D.

    1998-11-01

    Brookhaven National Laboratory (BNL) has developed thermally conductive composite liners for corrosion and scale protection in heat exchanger tubes exposed to geothermal brine. The liners cannot withstand roller expansion to connect the tubes to the tubesheet. It is not possible to line the ends of the tubes with the same material after roller expansion due to the nature of the current liner application process. It was requested that BNL evaluate plasma sprayed Ni-Al coatings for safe ending heat exchanger tubes exposed to geothermal brine. The tubes of interest had an internal diameter of 0.875 inches. It is not typical to thermal spray small diameter components or use such small standoff distances. In this project a nozzle extension was developed by Zatorski Coating Company to spray the tube ends as well as flat coupons for testing. Four different Ni-Al coatings were investigated. One of these was a ductilized Ni-AlB material developed at Oak Ridge National Laboratory. The coatings were examined by optical and scanning electron microscopy. In addition, the coatings were analyzed by X-ray diffraction and subjected to corrosion, tensile adhesion, microhardness and field tests in a volcanic pool in New Zealand.

  3. [Preparation and antithrombogenicity of oxidated low molecular weight heparin-antithrombin complex coated-polyvinyl chloride tubing].

    PubMed

    Luo, Peng; Liu, Weiyong; Yang, Chun; Zhou, Hua; Cao, Ruijun; Yang, Jian

    2011-02-01

    Based on non-enzymatic protein glycated reaction, the sodium periodate-oxidated low molecular weight heparin-antithrombin covalent complex (SPLMWATH) was produced. By using polyethyleneimine-glutaraldehyde bonding technique, polyvinyl chloride (PVC) tubings were coated with SPLMWATH, heparin and low molecular weight heparin (LMWH). Spectrophotometry and dynamic clotting time experiment were used to determine the synthetic ratio of SPLMWATH, graft density, coating leaching ratio and to evaluate the antithrombogenicity of different coating on the PVC tubings. The results showed that the synthetic ratio of SPLMWATH was approximately 55%, and compared with heparin coating and LMWH coating, the graft density of SPLMWATH coating on the PVC tubing was smaller, but its coating stability and antithrombogenicity were significantly better than that of heparin coating and LMWH coating on the PVC tubings.

  4. Comparative High-Temperature Corrosion Behavior of Ni-20Cr Coatings on T22 Boiler Steel Produced by HVOF, D-Gun, and Cold Spraying

    NASA Astrophysics Data System (ADS)

    Kaushal, Gagandeep; Bala, Niraj; Kaur, Narinder; Singh, Harpreet; Prakash, Satya

    2014-01-01

    To protect materials from surface degradations such as wear, corrosion, and thermal flux, a wide variety of materials can be deposited on the materials by several spraying processes. This paper examines and compares the microstructure and high-temperature corrosion of Ni-20Cr coatings deposited on T22 boiler steel by high velocity oxy-fuel (HVOF), detonation gun spray, and cold spraying techniques. The coatings' microstructural features were characterized by means of XRD and FE-SEM/EDS analyses. Based upon the results of mass gain, XRD, and FE-SEM/EDS analyses it may be concluded that the Ni-20Cr coating sprayed by all the three techniques was effective in reducing the corrosion rate of the steel. Among the three coatings, D-gun spray coating proved to be better than HVOF-spray and cold-spray coatings.

  5. New configuration for efficient and durable copper coating on the outer surface of a tube

    NASA Astrophysics Data System (ADS)

    Ahmad, Irfan; Chapman, Steven F.; Velas, Katherine M.; Krishnan, Mahadevan

    2017-03-01

    A well-adhered copper coating on stainless steel power coupler parts is required in superconducting radio frequency (SRF) accelerators. Radio frequency power coupler parts are complex, tubelike stainless steel structures, which require copper coating on their outer and inner surfaces. Conventional copper electroplating sometimes produces films with inadequate adhesion strength for SRF applications. Electroplating also requires a thin nickel strike layer under the copper coating, whose magnetic properties can be detrimental to SRF applications. Coaxial energetic deposition (CED) and sputtering methods have demonstrated efficient conformal coating on the inner surfaces of tubes but coating the outer surface of a tube is challenging because these coating methods are line of sight. When the substrate is off axis and the plasma source is on axis, only a small section of the substrate's outer surface is exposed to the source cathode. The conventional approach is to rotate the tube to achieve uniformity across the outer surface. This method results in poor film thickness uniformity and wastes most of the source plasma. Alameda Applied Sciences Corporation (AASC) has developed a novel configuration called hollow external cathode CED (HEC-CED) to overcome these issues. HEC-CED produces a film with uniform thickness and efficiently uses all eroded source material. The Cu film deposited on the outside of a stainless steel tube using the new HEC-CED configuration survived a high pressure water rinse adhesion test. HEC-CED can be used to coat the outside of any cylindrical structure.

  6. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect

    Gandy, David W.; Shingledecker, John P.

    2011-05-11

    Coal-fired power plants are a significant part of the nation's power generating capacity, currently accounting for more than 55% of the country's total electricity production. Extending the reliable lifetimes of fossil fired boiler components and reducing the maintenance costs are essential for economic operation of power plants. Corrosion and erosion are leading causes of superheater and reheater boiler tube failures leading to unscheduled costly outages. Several types of coatings and weld overlays have been used to extend the service life of boiler tubes; however, the protection afforded by such materials was limited approximately one to eight years. Power companies are more recently focused in achieving greater plant efficiency by increasing steam temperature and pressure into the advanced-ultrasupercritical (A-USC) condition with steam temperatures approaching 760°C (1400°F) and operating pressures in excess of 35MPa (5075 psig). Unfortunately, laboratory and field testing suggests that the resultant fireside environment when operating under A-USC conditions can potentially cause significant corrosion to conventional and advanced boiler materials1-2. In order to improve reliability and availability of fossil fired A-USC boilers, it is essential to develop advanced nanostructured coatings that provide excellent corrosion and erosion resistance without adversely affecting the other properties such as toughness and thermal fatigue strength of the component material.

  7. ECUT energy data reference series: boilers

    SciTech Connect

    Chockie, A.D.; Johnson, D.R.

    1984-09-01

    Information on the population and fuel consumption of water-tube, fire-tube and cast iron boilers is summarized. The use of each boiler type in the industrial and commercial sector is examined. Specific information on each boiler type includes (for both 1980 and 2000) the average efficiency of the boiler, the capital stock, the amount of fuel consumed, and the activity level as measured by operational load factor.

  8. Plasma Sputtering Robotic Device for In-Situ Thick Coatings of Long, Small Diameter Vacuum Tubes

    NASA Astrophysics Data System (ADS)

    Hershcovitch, Ady

    2014-10-01

    A novel robotic plasma magnetron mole with a 50 cm long cathode was designed fabricated & operated. Reason for this endeavor is to alleviate the problems of unacceptable ohmic heating of stainless steel vacuum tubes and of electron clouds, due to high secondary electron yield (SEY), in the BNL Relativistic Heavy Ion Collider (RHIC). The magnetron mole was successfully operated to copper coat an assembly containing a full-size, stainless steel, cold bore, RHIC magnet tubing connected to two types of RHIC bellows, to which two additional pipes made of RHIC tubing were connected. To increase cathode lifetime, movable magnet package was developed, and thickest possible cathode was made, with a rather challenging target to substrate (de facto anode) distance of less than 1.5 cm. Achieving reliable steady state magnetron discharges at such a short cathode to anode gap was rather challenging, when compared to commercial coating equipment, where the target to substrate distance is 10's cm; 6.3 cm is the lowest experimental target to substrate distance found in the literature. Additionally, the magnetron developed during this project provides unique omni-directional uniform coating. The magnetron is mounted on a carriage with spring loaded wheels that successfully crossed bellows and adjusted for variations in vacuum tube diameter, while keeping the magnetron centered. Electrical power and cooling water were fed through a cable bundle. The umbilical cabling system is driven by a motorized spool. Excellent coating adhesion was achieved. Measurements indicated that well-scrubbed copper coating reduced SEY to 1, i.e., the problem of electron clouds can be eliminated. Room temperature RF resistivity measurement indicated that 10 μm Cu coated stainless steel RHIC tube has conductivity close to that of pure copper tubing. Excellent coating adhesion was achieved. Device detail and experimental results will be presented. Work supported by Brookhaven Science Associates, LLC under

  9. Plasma sputtering robotic device for in-situ thick coatings of long, small diameter vacuum tubes

    SciTech Connect

    Hershcovitch, A. Blaskiewicz, M.; Brennan, J. M.; Fischer, W.; Liaw, C.-J.; Meng, W.; Todd, R.; Custer, A.; Dingus, A.; Erickson, M.; Jamshidi, N.; Laping, R.; Poole, H. J.

    2015-05-15

    A novel robotic plasma magnetron mole with a 50 cm long cathode was designed, fabricated, and operated. The reason for this endeavor is to alleviate the problems of unacceptable resistive heating of stainless steel vacuum tubes in the BNL Relativistic Heavy Ion Collider (RHIC). The magnetron mole was successfully operated to copper coat an assembly containing a full-size, stainless steel, cold bore, RHIC magnet tubing connected to two types of RHIC bellows, to which two additional pipes made of RHIC tubing were connected. To increase the cathode lifetime, a movable magnet package was developed, and the thickest possible cathode was made, with a rather challenging target to substrate (de facto anode) distance of less than 1.5 cm. Achieving reliable steady state magnetron discharges at such a short cathode to anode gap was rather challenging, when compared to commercial coating equipment, where the target to substrate distance is 10's cm; 6.3 cm is the lowest experimental target to substrate distance found in the literature. Additionally, the magnetron developed during this project provides unique omni-directional uniform coating. The magnetron is mounted on a carriage with spring loaded wheels that successfully crossed bellows and adjusted for variations in vacuum tube diameter, while keeping the magnetron centered. Electrical power and cooling water were fed through a cable bundle. The umbilical cabling system is driven by a motorized spool. Excellent coating adhesion was achieved. Measurements indicated that well-scrubbed copper coating reduced secondary electron yield to 1, i.e., the problem of electron clouds can be eliminated. Room temperature RF resistivity measurement indicated that a 10 μm copper coated stainless steel RHIC tube has a conductivity close to that of pure copper tubing. Excellent coating adhesion was achieved. The device details and experimental results are described.

  10. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings - Phase II

    SciTech Connect

    Blough, J.L.; Krawchuk, M.T.; Van Weele, S.F.

    1995-08-01

    A number of developmental and commercial tubing alloys and claddings have previously been exposed in Phase I to laboratory fireside corrosion testing simulating a superheater or reheater in a coal-fired boiler. This program is exposing samples of TP 347, RA-85H, HR-3C, 253MA, Fe{sub 3}Al + 5Cr, 310 modified, NF-709, 690 clad, and 671 clad, which showed good corrosion resistance from Phase 1, to the actual operating conditions of a 250-MW, coal-fired boiler. The samples were installed on air-cooled, retractable corrosion probes, installed in the reheater cavity, and are being controlled to the operating metal temperatures of an existing and advanced-cycle coal-fired boiler. The exposure will continue for 4000, 12,000, and 16,000 hours of operation. After the three exposure times, the samples will be metallurgically examined to determine the wastage rates and mode of attack. The probes were commissioned November 16, 1994. The temperatures are being recorded every 15 minutes, and the weighted average temperature calculated for each sample. Each of the alloys is being exposed to a temperature in each of two temperature bands-1150 to 1260{degrees}F and 1260 to 1325{degrees}F. After 2000 hours of exposure, one of the corrosion probes was cleaned and the wall thicknesses were ultrasonically measured. The alloy performance from the field probes will be discussed.

  11. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings -- Phase 2 field testing

    SciTech Connect

    Blough, J.L.; Seitz, W.W.; Girshik, A.

    1998-06-01

    In Phase 1 of this project, laboratory experiments were performed on a variety of developmental and commercial tubing alloys and claddings by exposing them to fireside corrosion tests which simulated a superheater or reheater in a coal-fired boiler. Phase 2 (in situ testing) has exposed samples of 347, RA85H, HR3C, RA253MA, Fe{sub 3}Al + 5Cr, Ta-modified 310, NF 709, 690 clad, 671 clad, and 800HT for up to approximately 16,000 hours to the actual operating conditions of a 250-MW, coal-fired boiler. The samples were installed on air-cooled, retractable corrosion probes, installed in the reheater cavity, and controlled to the operating metal temperatures of an existing and advanced-cycle, coal-fired boiler. Samples of each alloy were exposed for 4,483, 11,348, and 15,883 hours of operation. The present results are for the metallurgical examination of the corrosion probe samples after the full 15,883 hours of exposure. A previous topical report has been issued for the 4,483 hours of exposure.

  12. Anti-Reflective Coating On Borosilicate Long Tubes Industrial Process And Quality Control

    NASA Astrophysics Data System (ADS)

    Eisenberg, N.; Ben-Dor, Y.; Warschawski, J. P.

    1989-07-01

    It has been shown that in order to improve the optical efficiency of a solar trough evacuated pipe used for Luz solar electricity generating systems, an appropriate low cost anti-reflective coating process should be implemented in the solar collector production line, and that a dip process is the optimal choice for this application. It is shown in this paper that pumping the coating solution out of the coating container rather than withdrawing the tubes is the most appropriate coating process for Luz's needs. The same method was employed for the second coating solution which was used both for mechanical abrasion resistance improvement and for increasing optical transmissivity. The measuring procedure for quality insurance of the coated tube was investigated thoroughly and an "in-house" technique, including solar simulation and spiral movement of the tested tube, was chosen in preference to the other standard procedures (spectrophotometry, reflectometry). The complete AR coating facility and production procedure is described and the results of the industrial process are analyzed.

  13. The antimicrobial effect of Octenidine-dihydrochloride coated polymer tracheotomy tubes on Staphylococcus aureus and Pseudomonas aeruginosa colonisation.

    PubMed

    Zumtobel, Michaela; Assadian, Ojan; Leonhard, Matthias; Stadler, Maria; Schneider, Berit

    2009-07-25

    The surface of polymeric tracheotomy tubes is a favourable environment for biofilm formation and therefore represents a potential risk factor for the development of pneumonia after tracheotomy. The aim of this in-vitro study was to develop octenidine-dihydrochloride (OCT) coated polymer tracheotomy tubes and investigate any effects on Staphylococcus (S.) aureus and Pseudomonas (P.) aeruginosa colonization. Additionally the resistance of the OCT coating was tested using reprocessing procedures like brushing, rinsing and disinfection with glutaraldehyde Contamination with S. aureus: Before any reprocessing, OCT coated tracheotomy tubes were colonized with 103 cfu/ml and uncoated tracheotomy tubes with 105 cfu/ml (P = 0.045). After reprocessing, no differences in bacterial concentration between modified and conventional tubes were observed.Contamination with P. aeruginosa: Before reprocessing, OCT coated tubes were colonized with 106 cfu/ml and uncoated tubes with 107 cfu/ml (P = 0.006). After reprocessing, no significant differences were observed. OCT coating initially inhibits S. aureus and P. aeruginosa colonisation on tracheotomy tubes. This effect, however, vanishes quickly after reprocessing of the tubes due to poor adhesive properties of the antimicrobial compound. Despite the known antimicrobial effect of OCT, its use for antimicrobial coating of tracheotomy tubes is limited unless methods are developed to allow sustained attachment to the tube.

  14. The antimicrobial effect of Octenidine-dihydrochloride coated polymer tracheotomy tubes on Staphylococcus aureus and Pseudomonas aeruginosa colonisation

    PubMed Central

    2009-01-01

    Background The surface of polymeric tracheotomy tubes is a favourable environment for biofilm formation and therefore represents a potential risk factor for the development of pneumonia after tracheotomy. The aim of this in-vitro study was to develop octenidine-dihydrochloride (OCT) coated polymer tracheotomy tubes and investigate any effects on Staphylococcus (S.) aureus and Pseudomonas (P.) aeruginosa colonization. Additionally the resistance of the OCT coating was tested using reprocessing procedures like brushing, rinsing and disinfection with glutaraldehyde Results Contamination with S. aureus: Before any reprocessing, OCT coated tracheotomy tubes were colonized with 103 cfu/ml and uncoated tracheotomy tubes with 105 cfu/ml (P = 0.045). After reprocessing, no differences in bacterial concentration between modified and conventional tubes were observed. Contamination with P. aeruginosa: Before reprocessing, OCT coated tubes were colonized with 106 cfu/ml and uncoated tubes with 107 cfu/ml (P = 0.006). After reprocessing, no significant differences were observed. Conclusion OCT coating initially inhibits S. aureus and P. aeruginosa colonisation on tracheotomy tubes. This effect, however, vanishes quickly after reprocessing of the tubes due to poor adhesive properties of the antimicrobial compound. Despite the known antimicrobial effect of OCT, its use for antimicrobial coating of tracheotomy tubes is limited unless methods are developed to allow sustained attachment to the tube. PMID:19630994

  15. New configuration for efficient and durable copper coating on the outer surface of a tube

    DOE PAGES

    Ahmad, Irfan; Chapman, Steven F.; Velas, Katherine M.; ...

    2017-03-27

    A well-adhered copper coating on stainless steel power coupler parts is required in superconducting radio frequency (SRF) accelerators. Radio frequency power coupler parts are complex, tubelike stainless steel structures, which require copper coating on their outer and inner surfaces. Conventional copper electroplating sometimes produces films with inadequate adhesion strength for SRF applications. Electroplating also requires a thin nickel strike layer under the copper coating, whose magnetic properties can be detrimental to SRF applications. Coaxial energetic deposition (CED) and sputtering methods have demonstrated efficient conformal coating on the inner surfaces of tubes but coating the outer surface of a tube ismore » challenging because these coating methods are line of sight. When the substrate is off axis and the plasma source is on axis, only a small section of the substrate’s outer surface is exposed to the source cathode. The conventional approach is to rotate the tube to achieve uniformity across the outer surface. This method results in poor film thickness uniformity and wastes most of the source plasma. Alameda Applied Sciences Corporation (AASC) has developed a novel configuration called hollow external cathode CED (HEC-CED) to overcome these issues. HEC-CED produces a film with uniform thickness and efficiently uses all eroded source material. Furthermore, the Cu film deposited on the outside of a stainless steel tube using the new HEC-CED configuration survived a high pressure water rinse adhesion test. HEC-CED can be used to coat the outside of any cylindrical structure.« less

  16. Computational Modeling and Assessment Of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect

    David W. Gandy; John P. Shingledecker

    2011-04-11

    Forced outages and boiler unavailability in conventional coal-fired fossil power plants is most often caused by fireside corrosion of boiler waterwalls. Industry-wide, the rate of wall thickness corrosion wastage of fireside waterwalls in fossil-fired boilers has been of concern for many years. It is significant that the introduction of nitrogen oxide (NOx) emission controls with staged burners systems has increased reported waterwall wastage rates to as much as 120 mils (3 mm) per year. Moreover, the reducing environment produced by the low-NOx combustion process is the primary cause of accelerated corrosion rates of waterwall tubes made of carbon and low alloy steels. Improved coatings, such as the MCrAl nanocoatings evaluated here (where M is Fe, Ni, and Co), are needed to reduce/eliminate waterwall damage in subcritical, supercritical, and ultra-supercritical (USC) boilers. The first two tasks of this six-task project-jointly sponsored by EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)-have focused on computational modeling of an advanced MCrAl nanocoating system and evaluation of two nanocrystalline (iron and nickel base) coatings, which will significantly improve the corrosion and erosion performance of tubing used in USC boilers. The computational model results showed that about 40 wt.% is required in Fe based nanocrystalline coatings for long-term durability, leading to a coating composition of Fe-25Cr-40Ni-10 wt.% Al. In addition, the long term thermal exposure test results further showed accelerated inward diffusion of Al from the nanocrystalline coatings into the substrate. In order to enhance the durability of these coatings, it is necessary to develop a diffusion barrier interlayer coating such TiN and/or AlN. The third task 'Process Advanced MCrAl Nanocoating Systems' of the six-task project jointly sponsored by the Electric Power Research Institute, EPRI and the U.S. Department of Energy (DE-FC26-07NT43096)- has focused on processing of

  17. Preparation and characterization of coatings with a high reflectivity on planar substrates and inside silica tubes

    NASA Astrophysics Data System (ADS)

    Bartoň, Ivo; Matějec, Vlastimil; Mrázek, Jan; Podrazký, Ondřej

    2015-01-01

    The paper presents results on preparation and characterization of highly reflective coatings on planar substrates and inside silica tubes. Coatings are designed for a maximum reflectivity at a wavelength of 550 nm and consist of several pairs of oxide layers. Each pair is composed of one layer with a high refractive index and one layer with a low refractive index with a refractive-index contrast of about 1.1. The layers were prepared by the sol-gel method. High-index layers were applied from a sol based on titanium butoxide while a sol of tetramethoxysilane was use for low-index layers. The sols were deposited onto silica slides or onto walls of silica tubes by using the dip-coating technique. Applied gel layers were thermally treated at temperatures up to 450 °C in order to obtain densified layers with thicknesses 50-100 nm. Coatings with one to five pairs of layers were fabricated. Prepared coatings were characterized by transmission and reflection spectrometry in a wavelength range from 190 to- 1100 nm, by contact profilometry, and by spectral ellipsometry. Thicknesses and refractive indices of coatings were determined from these measurements. For normal light incidence a reflectivity higher than 99% in a wavelength range of 500-650 nm was measured by transmission spectrometry on coatings prepared from four or five pairs of layers. Similar reflectivity values were determined for angles of incidence of 15, 30, 45 and 60 degrees by using reflection spectrometry. Transmission spectra measured on the coated tubes which show interference bands are also presented in the paper.

  18. High temperature nanostructured MoA1Si coatings on Alloys for ultrasupercritical coal-fired boilers: Final Technical Report DOE/SBIR/Phase I

    SciTech Connect

    Reddy, Ganta S.

    2012-11-21

    The goal of improving the efficiency of pulverized coal power plants has been pursued for decades. The need for greater fuel efficiency and reduced environmental impact is pushing utilities to Ultra Supercritical Steam Conditions (USC) of 760°C and 35 MPa. USC plants can operate at energy efficiencies in excess of 55%, while the conventional boilers are operating at 538°C and 17 MPa with an efficiency of 36 to 39%. Each percentage increase in energy efficiency gives rise to about an effective 2% reduction in CO2 and SO2 emissions. However USC boiler component life is limited by air oxidation, steam oxidation and erosion. Improving this life with an adherent MoSiAl nanostructure coating has been the focus of this research during the Phase I.

  19. 49 CFR 230.61 - Arch tubes, water bar tubes, circulators and thermic siphons.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 4 2013-10-01 2013-10-01 false Arch tubes, water bar tubes, circulators and... MAINTENANCE STANDARDS Boilers and Appurtenances Washing Boilers § 230.61 Arch tubes, water bar tubes, circulators and thermic siphons. (a) Frequency of cleaning. Each time the boiler is washed, arch tubes...

  20. 49 CFR 230.61 - Arch tubes, water bar tubes, circulators and thermic siphons.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 4 2014-10-01 2014-10-01 false Arch tubes, water bar tubes, circulators and... MAINTENANCE STANDARDS Boilers and Appurtenances Washing Boilers § 230.61 Arch tubes, water bar tubes, circulators and thermic siphons. (a) Frequency of cleaning. Each time the boiler is washed, arch tubes...

  1. 49 CFR 230.61 - Arch tubes, water bar tubes, circulators and thermic siphons.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 4 2012-10-01 2012-10-01 false Arch tubes, water bar tubes, circulators and... MAINTENANCE STANDARDS Boilers and Appurtenances Washing Boilers § 230.61 Arch tubes, water bar tubes, circulators and thermic siphons. (a) Frequency of cleaning. Each time the boiler is washed, arch tubes...

  2. 49 CFR 230.61 - Arch tubes, water bar tubes, circulators and thermic siphons.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 4 2011-10-01 2011-10-01 false Arch tubes, water bar tubes, circulators and... MAINTENANCE STANDARDS Boilers and Appurtenances Washing Boilers § 230.61 Arch tubes, water bar tubes, circulators and thermic siphons. (a) Frequency of cleaning. Each time the boiler is washed, arch tubes...

  3. Adhesion property and high-temperature oxidation behavior of Cr-coated Zircaloy-4 cladding tube prepared by 3D laser coating

    NASA Astrophysics Data System (ADS)

    Kim, Hyun-Gil; Kim, Il-Hyun; Jung, Yang-Il; Park, Dong-Jun; Park, Jeong-Yong; Koo, Yang-Hyun

    2015-10-01

    A 3D laser coating technology using Cr powder was developed for Zr-based alloys considering parameters such as: the laser beam power, inert gas flow, cooling of Zr-based alloys, and Cr powder control. This technology was then applied to Zr cladding tube samples to study the effect of Cr coating on the high-temperature oxidation of Zr-based alloys in a steam environment of 1200 °C for 2000s. It was revealed that the oxide layer thickness formed on the Cr-coated tube surface was about 25-times lower than that formed on a Zircaloy-4 tube surface. In addition, both the ring compression and the tensile tests were performed to evaluate the adhesion properties of the Cr-coated sample. Although some cracks were formed on the Cr-coated layer, the Cr-coated layer had not peeled off after the two tests.

  4. Coded excitation speeds up the detection of the fundamental flexural guided wave in coated tubes

    NASA Astrophysics Data System (ADS)

    Song, Xiaojun; Moilanen, Petro; Zhao, Zuomin; Ta, Dean; Pirhonen, Jalmari; Salmi, Ari; Hæeggström, Edward; Myllylä, Risto; Timonen, Jussi; Wang, Weiqi

    2016-09-01

    The fundamental flexural guided wave (FFGW) permits ultrasonic assessment of the wall thickness of solid waveguides, such as tubes or, e.g., long cortical bones. Recently, an optical non-contact method was proposed for ultrasound excitation and detection with the aim of facilitating the FFGW reception by suppressing the interfering modes from the soft coating. This technique suffers from low SNR and requires iterative physical scanning across the source-receiver distance for 2D-FFT analysis. This means that SNR improvement achieved by temporal averaging becomes time-consuming (several minutes) which reduces the applicability of the technique, especially in time-critical applications such as clinical quantitative ultrasound. To achieve sufficient SNR faster, an ultrasonic excitation by a base-sequence-modulated Golay code (BSGC, 64-bit code pair) on coated tube samples (1-5 mm wall thickness and 5 mm soft coating layer) was used. This approach improved SNR by 21 dB and speeded up the measurement by a factor of 100 compared to using a classical pulse excitation with temporal averaging. The measurement now took seconds instead of minutes, while the ability to determine the wall thickness of the phantoms was maintained. The technique thus allows rapid noncontacting assessment of the wall thickness in coated solid tubes, such as the human bone.

  5. Final Scientific/Technical Report "Arc Tube Coating System for Color Consistency"

    SciTech Connect

    Buelow, Roger; Jenson, Chris; Kazenski, Keith

    2013-03-21

    DOE has enabled the use of coating materials using low cost application methods on light sources to positively affect the output of those sources. The coatings and light source combinations have shown increased lumen output of LED fixtures (1.5%-2.0%), LED arrays (1.4%) and LED powered remote phosphor systems Philips L-Prize lamp (0.9%). We have also demonstrated lifetime enhancements (3000 hrs vs 8000 hrs) and shifting to higher CRI (51 to 65) in metal halide high intensity discharge lamps with metal oxide coatings. The coatings on LEDs and LED products are significant as the market is moving increasingly more towards LED technology. Enhancements in LED performance are demonstrated in this work through the use of available materials and low cost application processes. EFOI used low refractive index fluoropolymers and low cost dipping processes for application of the material to surfaces related to light transmission of LEDs and LED products. Materials included Teflon AF, an amorphous fluorinated polymer and fluorinated acrylic monomers. The DOE SSL Roadmap sets goals for LED performance moving into the future. EFOI's coating technology is a means to shift the performance curve for LEDs. This is not limited to one type of LED, but is relevant across LED technologies. The metal halide work included the use of sol-gel solutions resulting in silicon dioxide and titanium dioxide coatings on the quartz substrates of the metal halide arc tubes. The coatings were applied using low cost dipping processes.

  6. Oxy-Combustion Boiler Material Development

    SciTech Connect

    Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year

  7. Oxy-Combustion Boiler Material Development

    SciTech Connect

    Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to

  8. [Study on antibacterial property of silver loaded titanium dioxide antibacterial coated endotracheal intubation tube].

    PubMed

    Jiang, Xuhong; Wang, Yuan; Hua, Junyi; Lyu, Bin

    2014-05-01

    To study the antibacterial property of silver loaded titanium dioxide (TiO2) antibacterial coated endotracheal intubation tube, and to determine the minimum effective antibacterial concentration. Intubation tubes coated with different concentrations of antibacterial agents were prepared with sol gel method. Polyethylene endotracheal intubation tubes were used as substrate, and silver loaded TiO2 was used as the antibacterial agent. According to the different antibacterial concentrations of the antibacterial agent, the tubes were divided into nine groups: 10.0% group, 5.0% group, 2.0% group, 1.5% group, 1.0% group, 0.8% group, 0.6% group, 0.2% group, and control group. They were respectively immersed in three standard bacteria suspensions with 1.0×10(5) cfu/mL: Pseudomonas aeruginosa, Staphylococcus aureus, and Escherichia coli. Together with standard bacteria liquid group, there were 10 experimental groups. They were kept overnight for 24 hours. 10 μL of respective culture medium was smeared on blood agar culture medium. After being cultured overnight in 35 centigrade, the number of bacteria colonies was respectively counted. In 1.0×10(5) cfu/mL of three standard bacteria liquids with antibacterial agent concentration ≥1.0%, three bacterial colonies had un-obviously growth rate. Almost the same strong antibacterial effects to achieve sterilizing rates of more than 98% was shown in each group of the antibacterial coating endotracheal intubation tubes (all P>0.05). As the antibacterial agent concentration decreased, three bacterial colonies were increasing gradually. Intermediate antibacterial effects were shown in tubes of 0.8% group, with significant statistic difference as compared with 1.0% and 0.6% groups [Pseudomonas aeruginosa: 7.300 (4.050, 8.350) vs. 0.200 (0.050, 1.200), 9.700(9.000, 10.000); Staphylococcus aureus: 4.100 (3.300, 4.650) vs. 0.000 (0.000, 0.150), 5.800 (5.350, 7.650); Escherichia coli: 1.400 (0.750, 3.750) vs. 0.050 (0.025, 0.050), 9

  9. Conduction cooled tube supports

    DOEpatents

    Worley, Arthur C.; Becht, IV, Charles

    1984-01-01

    In boilers, process tubes are suspended by means of support studs that are in thermal contact with and attached to the metal roof casing of the boiler and the upper bend portions of the process tubes. The support studs are sufficiently short that when the boiler is in use, the support studs are cooled by conduction of heat to the process tubes and the roof casing thereby maintaining the temperature of the stud so that it does not exceed 1400.degree. F.

  10. [Determination of trace barium in soil and sediment by Zeeman graphite AAS with coated graphite tube].

    PubMed

    Ji, Hai-Bing; Liu, Jin-Song; Pang, Xiao-Lu

    2007-11-01

    The sample was decomposed by HNO3-HF-HClO4. Using a tungsten-coated graphite tube, trace barium in soil and sediment was determined by Zeeman graphite AAS. To avoid producing carbide, the graphite tube was coated with tungsten. Tungsten and carbon in the surface layer of graphite tube became tungsten carbide. Tungsten carbide prevented barium and carbon from forming barium carbide, which in turn not only led to a long service life for the tube, but also increased greatly the sensitivity and precision of the determination Ba. Tungsten carbide belongs to internal filled type and can give reduction environment. To some extent, the common interfering elements co-existing in the soil and sediment had little chance to form oxides to interfere the determination of Ba in the atomization period. The method was easy and sensitive. The detection limit of Ba was 4.2 x 10(-10) g x g(-1). The relative standard deviation (RSD) was in the range of 2.0%-6.5% (n = 4). The relative deviations from the certificated values of standard soils were under 5%.

  11. Versatile device for in-situ discharge cleaning and multiple coatings of long, small diameter tubes

    SciTech Connect

    Hershcovitch, A.; Blaskiewicz, M.; Brennan, J.M.; Custer, A.; Erickson, M.; Liaw, C.J.; Fischer, Jamshidi, N.; W.; Meng, W.; Poole, H.J.; Sochugov, N.

    2010-05-23

    Electron clouds, which can limit machine performance, have been observed in many accelerators including RHIC at BNL. Additional concern for the RHIC machine, whose vacuum chamber is made from relatively high resistivity 316LN stainless steel, is high wall resistivity that can result in unacceptably high ohmic heating for superconducting magnets. The high resistivity can be addressed with a copper (Cu) coating; a reduction in the secondary electron yield can be achieved with a TiN or amorphous carbon (a-C) coating. Applying such coatings in an already constructed machine is rather challenging. We have been developing a robotic plasma deposition technique for in-situ coating of long, small diameter tubes. The technique entails fabricating a device comprising of staged magnetrons mounted on a mobile mole for deposition of about 5 ?m of Cu followed by about 0.1 ?m of a-C. As a first step, a 15-cm Cu cathode magnetron was designed, fabricated, and 30-cm long samples of the RHIC pipe have been coated with 2 ?m to 5.6 ?m of copper. Deposition rates of up to 92 A/sec with an average coating rate of 30 A/sec were measured. Effects on RF resistivity is also to be measured.

  12. Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semiannual technical report, January 14, 1997--August 14, 1997

    SciTech Connect

    Schorr, B.S.; Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1997-08-31

    Research is presently being conducted to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The research will be accomplished by producing model cermet composites using powder metallurgy and electrodeposition methods in which the effect of ceramic/metal combination for the erosion and corrosion resistance will be determined. These results will provide the basis for determining the optimum hard phase constituent size and volume percent in thermal spray coatings. Thermal spray coatings will be applied by our industrial sponsor and tested in our erosion and corrosion laboratories. Bulk powder processed Ni-Al{sub 2}O{sub 3} composites were produced at Idaho National Engineering Laboratory. The composite samples contained 0, 21, 27, 37, and 45 volume percent Al{sub 2}O{sub 3} with an average particle size of 12 um. Also, to deposit model Ni-Al{sub 2}O{sub 3} coatings, an electrodeposition technique was developed and coatings with various volume fractions (0-35%) of Al{sub 2}O{sub 3} were produced. The powder and electrodeposition processing of Ni-Al{sub 2}O{sub 3} Composites provide the ability to produce two phase microstructure without changing the microstructure of the matrix material. Therefore, the effect of hard second phase particles size and volume fraction on erosion resistance could be analyzed.

  13. Looking northwest at central boiler house, with 16" skelp mill ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking northwest at central boiler house, with 16" skelp mill furnace building in foreground. - U.S. Steel National Tube Works, Central Boiler House, Along Monongahela River, McKeesport, Allegheny County, PA

  14. 20. FIREMAN'S END OF FIRETUBE BOILER. MANUFACTURED BY LUCEY. THE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    20. FIREMAN'S END OF FIRE-TUBE BOILER. MANUFACTURED BY LUCEY. THE BOILER CREATED APPROXIMATELY 150 POUNDS OF PRESSURE. - Dredge CINCINNATI, Docked on Ohio River at foot of Lighthill Street, Pittsburgh, Allegheny County, PA

  15. The effect of coatings on retention and permeation in SS 316L APT tritium production tubes

    NASA Astrophysics Data System (ADS)

    Hertz, K. L.; Causey, R. A.; Cowgill, D. F.

    2004-01-01

    The accelerator production of tritium (APT) design calls for thousands of thin-walled tubes to be filled with 3He gas. The reaction of the spallation neutrons with this gas will result in the bombardment of the interior of these tubes with energetic tritons and protons. For APT to be able to meet its tritium production goals, it is necessary that the holdup of the tritium in the tube walls be minimized. To examine the tritium retention characteristics of stainless steel, one of the tube reference materials, accelerator implantation experiments were performed. In these experiments, deuterium was used in place of tritium to eliminate the problem of tritium contamination. Deuterons with energies up to 200 keV and protons with energies up to 600 keV were implanted into stainless steel (SS 316L) samples to fluences as high as 5 × 10 22 D/m 2 and 5 × 10 22 p/m 2. Thermal desorption spectroscopy showed that approximately 3% of the deuterium was retained within the sample. Approximately 0.5% of the deuterium permeated through to the back surface of the sample where a zirconium getter trapped the deuterium. The deuterium trapped in the zirconium layer was measured by nuclear reaction analysis. Eight-micron thick copper and nickel coatings were applied to the implantation side of the stainless steel substrate in an attempt to reduce the retention and permeation of the deuterium. The copper-coated stainless steel was not successful in reducing the retention and permeation, however the nickel coated stainless steel reduced both the retention and permeation substantially.

  16. Water cannon apparatus and method for cleaning a tube bundle heat exchanger, boiler, condenser, or the like

    SciTech Connect

    Scharton, T.D.; Taylor, G.B.

    1988-09-27

    This patent describes a method of dislodging sludge from the tube sheet of a heat exchanger using a water cannon which provides exit velocities for water through its nozzle in the range of 10 to 1000 feet per second and mass flow rates of water in the range of 100 to 30,000 gallons per minute, comprising: a. inserting the nozzle of the water cannon into the heat exchanger at an opening in the heat exchanger shell located above the tube sheet; b. charging the water cannon with pressurized gas confined in an air gun having a pressurized gas valve, a gas storage plenum, at least one gas port, and a firing mechanism; c. charging the water cannon with water; d. firing the air gun by discharging pressurized gas through at least one gas port, thereby explosively discharging water from the nozzle of the water cannon such that the water is traveling at exit velocities in the range of 10 to 1000 feet per second and is being discharged through the nozzle at mass flow rates in the range of 100 to 30,000 gallons per minute, and being directed at the tube sheet; and e. continuously recharging the air gun and recharging the water cannong with water and providing automatic repetitive firing blasts of the water cannon with each firing blast having a duration in the range of 0.001 to 1 second and with repetition intervals in the range of 0.1 to 100 seconds; f. whereby the firing blasts of water from the water cannon serve to cause sludge resting on or above the tube sheet area to be moved to a location from which it can be removed from the heat exchanger.

  17. Feasibility study of aluminum beam tube for the collider: An option for no-coating and no-liner

    SciTech Connect

    Chou, W.

    1994-07-01

    This report proposes to use a single-layer beam tube made of high strength, high resistivity aluminum alloy (such as 7039-T61 or A7N01) to replace the double-layer copper coated stainless steel tube in the SSC Collider. The main reasons are: (1) a potential saving of about $23 million which is basically the baseline cost of the copper coating and (2) the use of an extruded aluminum tube consisting of a beam chamber and a pumping chamber may solve the vacuum problem without any liner.

  18. In-tube magnetic solid phase microextraction of some fluoroquinolones based on the use of sodium dodecyl sulfate coated Fe3O4 nanoparticles packed tube.

    PubMed

    Manbohi, Ahmad; Ahmadi, Seyyed Hamid

    2015-07-23

    In-tube magnetic solid phase microextraction (in-tube MSPME) of fluoroquinolones from water and urine samples based on the use of sodium dodecyl sulfate (SDS) coated Fe3O4 nanoparticles packed tube has been reported. After the preparation of Fe3O4 nanoparticles (NPs) by a batch synthesis, these NPs were introduced into a stainless steel tube by a syringe and then a strong magnet was placed around the tube, so that the Fe3O4 NPs were remained in the tube and the tube was used in the in-tube SPME-HPLC/UV for the analysis of fluoroquinolones in water and urine samples. Plackett-Burman design was employed for screening the variables significantly affecting the extraction efficiency. Then, the significant factors were more investigated by Box-Behnken design. Calibration curves were linear (R(2)>0.990) in the range of 0.1-1000μgL(-1) for ciprofloxacin (CIP) and 0.5-500μgL(-1) for enrofloxacin (ENR) and ofloxacin (OFL), respectively. LODs for all studied fluoroquinolones ranged from 0.01 to 0.05μgL(-1). The main advantages of this method were rapid and easy automation and analysis, short extraction time, high sensitivity, possibility of fully sorbent collection after analysis, wide linear range and no need to organic solvents in extraction. Copyright © 2015 Elsevier B.V. All rights reserved.

  19. Computation Modeling and Assessment of Nanocoatings for Ultra Supercritical Boilers

    SciTech Connect

    J. Shingledecker; D. Gandy; N. Cheruvu; R. Wei; K. Chan

    2011-06-21

    Forced outages and boiler unavailability of coal-fired fossil plants is most often caused by fire-side corrosion of boiler waterwalls and tubing. Reliable coatings are required for Ultrasupercritical (USC) application to mitigate corrosion since these boilers will operate at a much higher temperatures and pressures than in supercritical (565 C {at} 24 MPa) boilers. Computational modeling efforts have been undertaken to design and assess potential Fe-Cr-Ni-Al systems to produce stable nanocrystalline coatings that form a protective, continuous scale of either Al{sub 2}O{sub 3} or Cr{sub 2}O{sub 3}. The computational modeling results identified a new series of Fe-25Cr-40Ni with or without 10 wt.% Al nanocrystalline coatings that maintain long-term stability by forming a diffusion barrier layer at the coating/substrate interface. The computational modeling predictions of microstructure, formation of continuous Al{sub 2}O{sub 3} scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. Advanced coatings, such as MCrAl (where M is Fe, Ni, or Co) nanocrystalline coatings, have been processed using different magnetron sputtering deposition techniques. Several coating trials were performed and among the processing methods evaluated, the DC pulsed magnetron sputtering technique produced the best quality coating with a minimum number of shallow defects and the results of multiple deposition trials showed that the process is repeatable. scale, inward Al diffusion, grain growth, and sintering behavior were validated with experimental results. The cyclic oxidation test results revealed that the nanocrystalline coatings offer better oxidation resistance, in terms of weight loss, localized oxidation, and formation of mixed oxides in the Al{sub 2}O{sub 3} scale, than widely used MCrAlY coatings. However, the ultra-fine grain structure in these coatings, consistent with the computational model predictions, resulted in accelerated Al

  20. HVOF Thermal Spray TiC/TiB2 Coatings for AUSC Boiler/Turbine Components for Enhanced Corrosion Protection

    SciTech Connect

    Mondal, Kanchan; Koc, Rasit; Fan, Chinbay

    2016-12-07

    The high temperatures of operations still pose significant risk of degradation and fatigue from oxidizing, corroding and eroding environment. In addition to unused O2, water from combustion and SOx from the coal sulfur oxidation that result in highly corrosive environment, acid gases such as HCl and other sulfur compounds may also be present. These adverse effects are further accelerated due to the elevated temperatures. In addition, ash particulates and unburnt carbon and pyritic sulfur can cause erosion of the surface and thus loss of material. Unburnt carbon and pyritic sulfur may also cause localized reduction sites. Thus, fireside corrosion protection and steam oxidation protection alternatives to currently used Ni-Cr overlays need to be identified and evaluated. Titanium carbide (TiC) is a suitable alternative on account of the material features such as the high hardness, the high melting point, the high strength and the low density for the substitution or to be used in conjunction with NiCr for enhancing the fireside corrosion and erosion of the materials. Another alternative is the use of titanium boride as a coating for chemical stability required for long-term service and high erosion resistance over the state-of-the-art, high fracture toughness (K1C ~12 MPam1/2) and excellent corrosion resistance (kp~1.9X10-11 g2/cm4/s at 800°C in air). The overarching aim of the research endeavor was to synthesize oxidation, corrosion and wear resistant TiC and TiB2 coating powders, apply thermal spray coating on existing boiler materials and characterize the coated substrates for corrosion resistance for applications at high temperatures (500 -750 °C) and high pressures (~350 bars) using the HVOF process and to demonstrate the feasibility of these coating to be used in AUSC boilers and turbines.

  1. Study of mechanical properties and high temperature oxidation behavior of a novel cold-spray Ni-20Cr coating on boiler steels

    NASA Astrophysics Data System (ADS)

    Kaur, Narinder; Kumar, Manoj; Sharma, Sanjeev K.; Kim, Deuk Young; Kumar, S.; Chavan, N. M.; Joshi, S. V.; Singh, Narinder; Singh, Harpreet

    2015-02-01

    In the current investigation, high temperature oxidation behavior of a novel cold-spray Ni-20Cr nanostructured coating was studied. The nanocrystalline Ni-20Cr powder was synthesized by the investigators using ball milling, which was deposited on T22 and SA 516 steels by cold spraying. The crystallite size based upon Scherrer's formula for the developed coatings was found to be in nano-range for both the substrates. The accelerated oxidation testing was performed in a laboratory tube furnace at a temperature 900 °C under thermal cyclic conditions. Each cycle comprised heating for one hour at 900 °C followed by cooling for 20 min in ambient air. The kinetics of oxidation was established using weight change measurements for the bare and the coated steels. The oxidation products were characterized by X-ray Diffraction (XRD), Scanning Electron Microscopy/Energy Dispersive Spectroscopy (SEM/EDS) and X-ray mapping techniques. It was found from the results that the coating was successful in reducing the weight gain of SA213-T22 and SA 516-Grade 70 steel by 71% and 94%, respectively. This may be attributed to relatively denser structure, lower porosity and lower oxide content of the coating. Moreover, the developed nano-structured Ni-20Cr powder coating was found to perform better than its counterpart micron-sized Ni-20Cr powder coating, in terms of offering higher oxidation resistance and hardness.

  2. TiN-based coatings on fuel cladding tubes for advanced nuclear reactors

    SciTech Connect

    Ickchan Kim; Fauzia Khatkhatay; Liang Jiao; Greg Swadener; James Cole; Jian Gan; Haiyan Wang

    2012-10-01

    Titanium nitride (TiN) thin films are coated on HT-9 and MA957 fuel cladding tubes and bars to explore their mechanical strength, thermal stability, diffusion barrier properties, and thermal conductivity properties. The ultimate goal is to implement TiN as an effective diffusion barrier to prevent the inter-diffusion between the nuclear fuel and the cladding material, and thus lead to a longer life time of the cladding tubes. Mechanical tests including hardness and scratch tests for the samples before and after thermal cycle tests show that the films have a high hardness of 28 GPa and excellent adhesion properties despite the thermal treatment. Thermal conductivity measurements demonstrate that the thin TiN films have very minimal impact on the overall thermal conductivity of the MA957 and HT9 substrates, i.e., the thermal conductivity of the uncoated HT-9 and MA957 substrates was 26.25 and 28.44 W m-1K-1 , and that of the coated ones was 26.21 and 28.38 W m-1K-1, respectively. A preliminary Ce diffusion test on the couple of Ce/TiN/HT-9 suggests that TiN has excellent material compatibility and good diffusion barrier properties.

  3. Sampling artifacts from the use of denuder tubes with glycerol based coatings in the measurement of atmospheric particulate matter.

    PubMed

    Finn, D; Rumburg, B; Claiborn, C; Bamesberger, L; Siems, W F; Koenig, J; Larson, T; Norris, G

    2001-01-01

    Chemical speciation studies use sampling configurations that often require the deployment of denuder tubes of various types to measure certain species or control particulate sampling artifacts. Concurrent sets of measurements on Teflon membrane and quartz filters in specific sampling configurations were used to evaluate the potential influence of denuder tubes with glycerol-based coatings on particulate mass and carbon measurements on downstream filters. Positive biases were observed in the measurement of gravimetric mass and carbon on Teflon and quartz filters, respectively, downstream of sodium carbonate/ glycerol and citric acid/glycerol coated denuder tubes relative to those without upstream denuder tubes. The magnitude of the bias is dependent on the level of ambient particulate loading.

  4. Instructions on the Design of Boiler Installations SN 350-66.

    DTIC Science & Technology

    1980-05-19

    boiler water treatment, as a rule, must be Frovided fcr fcr following boilers : steam shielded water- tube independent cf their ccefficient of...of saturated steam for boilers with steam superheaters should be accepted: a) for nominal pressure 8-13 Itm(gage) - 1000 pg/kg; b) for nominal pressure...of the niasting cf boilers . 2. Boilers with steam superheaters , as a rule, are equipped by stepped evaporation ant cuisine clclcnes. 3. In boilers

  5. 35. VIEW LOOKING EAST IN SOUTH END OF EAST BOILER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    35. VIEW LOOKING EAST IN SOUTH END OF EAST BOILER ROOM. CYLINDRICAL TANKS ARE WORTHINGTON DEAERATORS. THESE REMOVED AIR FROM BOILER FEED WATER TO MINIMIZE CORROSION AND PITTING OF THE BOILER TUBES. AIR REMOVAL ALSO HELPED AVOID THE FORMATION OF FOAM IN THE SYSTEM. - New York, New Haven & Hartford Railroad, Cos Cob Power Plant, Sound Shore Drive, Greenwich, Fairfield County, CT

  6. 49 CFR 230.61 - Arch tubes, water bar tubes, circulators and thermic siphons.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Arch tubes, water bar tubes, circulators and... MAINTENANCE STANDARDS Boilers and Appurtenances Washing Boilers § 230.61 Arch tubes, water bar tubes... water bar tubes shall thoroughly be cleaned mechanically, washed, and inspected. Circulators and...

  7. Corrosion resistant coatings for silicon carbide heat exchanger tubes -- Volume 3. Final report

    SciTech Connect

    Boss, D.E.

    1996-06-07

    The development of a silicon carbide (SiC) heat exchanger is a critical step in the development of the Externally-Fired Combined Cycle (EFCC) power system. SiC is the only material that provides the necessary combination of resistance to creep, thermal shock, and oxidation. While the SiC structure materials provide the thermomechanical and thermophysical properties needed for an efficient system, the mechanical properties of the SiC tubes are severely degraded through corrosion by the coal combustion products. To obtain the necessary service life of thousands of hours at temperature, a protective coating is needed that is stable with both the SiC tube and the coal combustion products, resists erosion from the particle laden gas stream, is thermal shock resistant, adheres to SiC during repeated thermal shocks (start-up, process upsets, shut-down), and allows the EFCC system to be cost competitive. This demanding set of technical performance and cost drivers was used in reviewing and selecting candidate protective materials. After a review of open literature, discussion with leading researchers in materials for coal combustion environments, and preliminary thermodynamic studies, a total of ten materials were identified for future study that were grouped into three categories: alumina-based materials, materials stable with SiO{sub 2}, and low expansion materials.

  8. Stability of viscous film flow coating the interior of a vertical tube with a porous wall

    NASA Astrophysics Data System (ADS)

    Liu, Rong; Ding, Zijing

    2017-05-01

    The stability of the gravity-driven flow of a viscous film coating the inside of a tube with a porous wall is studied theoretically. We used Darcy's law to describe the motion of fluids in a porous medium. The Beaver-Joseph condition is used to describe the discontinuity of velocity at the porous-fluid interface. We derived an evolution equation for the film thickness using a long-wave approximation. The effect of velocity slip at the porous wall is identified by a parameter β . We examine the effect of β on the temporal stability, the absolute-convective instability (AI-CI), and the nonlinear evolution of the interface deformation. The results of the temporal stability reveal that the effect of velocity slip at the porous wall is destabilizing. The parameter β plays an important role in determining the AI-CI behavior and the nonlinear evolution of the interface. The presence of the porous wall promotes the absolute instability and the formation of the plug in the tube.

  9. Synthesis and applications of diethylstilbestrol-based molecularly imprinted polymer-coated hollow fiber tube.

    PubMed

    Liu, Meihua; Li, Meijin; Qiu, Bin; Chen, Xi; Chen, Guonan

    2010-03-17

    A novel molecularly imprinted polymer-coated polypropylene hollow fiber tube (MIP-HFT) was photoinitiated for the copolymerization of diethylstilbestrol (DES) as a template molecule, alpha-methacrylic acid as a functional monomer, and ethylene glycol dimethacrylate as a crosslinking agent. The characteristics and applications of the MIP-HFT were investigated. In order to compare its characteristics with those of a non-imprinted polymer-immersed hollow fiber tube, the selectivity of the MIP-HFT was investigated using dienestrol and hexestrol as the structural analogues of a DES template, and phenol and methylbenzene were taken as reference compounds. The MIP-HFT was employed in the HPLC analysis of spiked milk samples. The detection limits of the method were found to be in the range 2.5-3.3microgL(-1) for DES, dienestrol and hexestrol and the RSD% were in the range 6.4-8.9. The limits of quantitation were found to be in the range 8.7-9.4microgL(-1) in milk for DES, dienestrol and hexestrol, and their average recoveries were 83.7-90.6% in the spiked milk samples. The experimental results revealed that the MIP-HFT provides a good carrier for the selective adsorption of DES and its chemical structure analogs, and can be used for the preconcentration of these compounds in complicated samples. Copyright 2010 Elsevier B.V. All rights reserved.

  10. Design features of first of its kind AFBC high pressure boiler for Kutch lignite fuel in Gujarat, India

    SciTech Connect

    Diwakar, K.K.; Mokashi, A.H.

    1999-11-01

    Gujarat Heavy Chemicals Limited (GHCL) in Gujarat State in India is one of the largest manufacturers of Soda Ash with modern most technology from Akzo of Neitherland. GHCL with earlier experience of firing of kind of lignite on travagrate boiler and with converted fluidized bed boiler has very clearly identified the problem areas for review and with that rich experience awarded contract to Thermax Babcock and Wilcox Limited (TBW), Pune, India a joint venture company of Thermax Limited, Pune, India and Babcock and Wilcox, USA. Accordingly, boiler has been designed to suit Kutch Lignite and Coal with AFBC Technology, Single Drum Design, top supported with underbed feeding system. Capacity of boiler is 90 Ton/Hr with design pressure of 130 kg/cm{sup 2} with superheated steam temperature of 510 C. This is the first boiler in India with such a high pressure and temperature conditions for this capacity firing lignite. Other first of its kind features include single drum boiler convection bank made with headers and tubes, riffled inbed evaporator tubes, erosion protection by surface coating and not by studs, line bed system for inert material, no soot blowers, specially designed double hinged SS supports for inbed superheater coils etc. This boiler also has a provision of over fire air arrangement for better combustion split. Other unique features include the start-up arrangement by HSD burners which can take the boiler up to 30% load, provision for flue gas recirculation system, specially designed SS air distribution nozzles, separate compartments for under feed, ash drain and air cooled distribution plate with 1:5 turndown. The paper discusses all the above design features.

  11. Numerical simulation of tube-tooling cable-coating with polymer melts

    NASA Astrophysics Data System (ADS)

    Al-Muslimawi, A.; Tamaddon-Jahromi, H. R.; Webster, M. F.

    2013-11-01

    This study investigates the numerical solution of viscous and viscoelastic flows for tube-tooling die-extrusion coating using a hybrid nite element/nite volume discretisation ( fe/fv). Such a complex polymer melt extrusion-draw-coating flow displays a dynamic contact line, slip, die-swell and two separate free-surfaces, presenting an inner and outer conduit surface to the melt-coating. The practical interest lies in determining efficient windows for process control over variation in material properties, stressing levels generated and vacuum pressure levels imposed. The impact of shear-thinning is also considered. Extensive reference is made throughout to viscous inelastic counterpart solutions. Attention is paid to the influence and variation in relevant parameters of Weissenberg number ( We), solvent-fraction (β) and second normal difference ( N 2) (ξ parameter for EPTT). The impact of model choice and parameters upon field response is described in situ through, pressure-drops, rates of deformation and stress. Various numerical alternative strategies, their stability and convergence issues are also addressed. The numerical scheme solves the momentum-continuity-surface equations by a semi-implicit time-stepping Taylor-Galerkin/pressure-correction (TGPC) finite element (parent-cell) method, whilst invoking a sub-cell cell-vertex fluctuation distribution finite volume scheme for the constitutive stress equation. The hyperbolic aspects of the constitutive equation are addressed discretely through upwind Fluctuation Distribution techniques, whilst temporal and source terms are consistently accommodated through medium-dual-cell schemes. The dynamic solution of the moving boundary problem may be resolved by either separating the solution process for each free-surface section (decoupling), or coupling both sections and solving simultaneously. Each involves a surface height location method, with dependency on surface nodal velocities and surface element sections; two

  12. 13. RW Meyer Sugar Mill: 18761889. Engine and boiler house, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    13. RW Meyer Sugar Mill: 1876-1889. Engine and boiler house, ca. 1881. Locomotive-type, fire-tube, portable boiler, no. I model. Manufactured by Ames Iron Works, Oswego, New York, 1879. 120 lbs./sq. in. working pressure, 66 sq. ft. heating surface in tubes. View: Historical view, 1934, from T.T. Waterman Collection, Hawaiian Sugar Planters' Association. View shows engine and boiler house structure intact. The water and pressure gauge to the right of the boiler are in more complete condition than in 1978 views. - R. W. Meyer Sugar Mill, State Route 47, Kualapuu, Maui County, HI

  13. Novel Surface Modification Method for Ultrasupercritical Coal-Fired Boilers

    SciTech Connect

    Xiao, T. Danny

    2013-05-22

    US Department of Energy seeks an innovative coating technology for energy production to reduce the emission of SOx, NOx, and CO2 toxic gaseous species. To realize this need, Inframat Corporation (IMC) proposed an SPS thermal spray coating technique to produce ultrafine/nanocoatings that can be deposited onto the surfaces of high temperature boiler tubes, so that higher temperatures of boiler operation becomes possible, leading to significantly reduced emission of toxic gaseous species. It should be noted that the original PI was Dr. Xinqing Ma, who after 1.5 year conducting this project left Inframat in December, 2008. Thus, the PI was transferred to Dr. Danny Xiao, who originally co-authored the proposal with Dr. Ma, in order to carry the project into a completion. Phase II Objectives: The proposed technology has the following attributes, including: (1). Dispersion of a nanoparticle or alloyed particle in a solvent to form a uniform slurry feedstock; (2). Feeding of the slurry feedstock into a thermal spray flame, followed by deposition of the slurry feedstock onto substrates to form tenacious nanocoatings; (3). High coating performance: including high bonding strength, and high temperature service life in the temperature range of 760oC/1400oF. Following the above premises, our past Phase I project has demonstrated the feasibility in small scale coatings on boiler substrates. The objective of this Phase II project was to focus on scale-up the already demonstrated Phase I work for the fabrication of SPS coatings that can satisfy DOE's emission reduction goals for energy production operations. Specifically, they are: (1). Solving engineering problems to scale-up the SPS-HVOF delivery system to a prototype production sub-delivery system; (2). Produce ultrafine/nanocoatings using the scale-up prototype system; (3). Demonstrate the coated components using the scale-up device having superior properties. Proposed Phase II Tasks: In the original Phase II proposal, we have

  14. Characterization of mechanical properties of hydroxyapatite-silicon-multi walled carbon nano tubes composite coatings synthesized by EPD on NiTi alloys for biomedical application.

    PubMed

    Khalili, Vida; Khalil-Allafi, Jafar; Sengstock, Christina; Motemani, Yahya; Paulsen, Alexander; Frenzel, Jan; Eggeler, Gunther; Köller, Manfred

    2016-06-01

    Release of Ni(1+) ions from NiTi alloy into tissue environment, biological response on the surface of NiTi and the allergic reaction of atopic people towards Ni are challengeable issues for biomedical application. In this study, composite coatings of hydroxyapatite-silicon multi walled carbon nano-tubes with 20wt% Silicon and 1wt% multi walled carbon nano-tubes of HA were deposited on a NiTi substrate using electrophoretic methods. The SEM images of coated samples exhibit a continuous and compact morphology for hydroxyapatite-silicon and hydroxyapatite-silicon-multi walled carbon nano-tubes coatings. Nano-indentation analysis on different locations of coatings represents the highest elastic modulus (45.8GPa) for HA-Si-MWCNTs which is between the elastic modulus of NiTi substrate (66.5GPa) and bone tissue (≈30GPa). This results in decrease of stress gradient on coating-substrate-bone interfaces during performance. The results of nano-scratch analysis show the highest critical distance of delamination (2.5mm) and normal load before failure (837mN) as well as highest critical contact pressure for hydroxyapatite-silicon-multi walled carbon nano-tubes coating. The cell culture results show that human mesenchymal stem cells are able to adhere and proliferate on the pure hydroxyapatite and composite coatings. The presence of both silicon and multi walled carbon nano-tubes (CS3) in the hydroxyapatite coating induce more adherence of viable human mesenchymal stem cells in contrast to the HA coated samples with only silicon (CS2). These results make hydroxyapatite-silicon-multi walled carbon nano-tubes a promising composite coating for future bone implant application.

  15. Uptake of gaseous formaldehyde onto soil surfaces: a coated-wall flow tube study

    NASA Astrophysics Data System (ADS)

    Li, Guo; Su, Hang; Li, Xin; Meusel, Hannah; Kuhn, Uwe; Pöschl, Ulrich; Shao, Min; Cheng, Yafang

    2015-04-01

    Gaseous formaldehyde (HCHO) is an important intermediate molecule and source of HO2 radicals. However, discrepancies exist between model simulated and observed HCHO concentrations, suggesting missing sources or sinks in the HCHO budget. Multiphase processes on the surface of soil and airborne soil-derived particles have been suggested as an important mechanism for the production/removal of atmospheric trace gases and aerosols. In this work, the uptake of gaseous HCHO on soil surfaces were investigated through coated-wall flow tube experiments with HCHO concentration ranging from 10 to 40 ppbv. The results show that the adsorption of HCHO occurred on soil surfaces, and the uptake coefficient dropped gradually (i.e., by a factor of 5 after 1 hour) as the reactive surface sites were consumed. The HCHO uptake coefficient was found to be affected by the relative humidity (RH), decreasing from (2.4 ± 0.5) × 10-4 at 0% RH to (3.0 ± 0.08) × 10-5 at 70% RH, due to competition of water molecule absorption on the soil surface. A release of HCHO from reacted soil was also detected by applying zero air, suggesting the nature of reversible physical absorption and the existence of an equilibrium at the soil-gas interface. It implies that soil could be either a source or a sink for HCHO, depending on the ambient HCHO concentration. We also develop a Matlab program to calculate the uptake coefficient under laminar flow conditions based on the Cooney-Kim-Davis method.

  16. Resource recovery waste heat boiler upgrade

    SciTech Connect

    Kuten, P.; McClanahan, D.E.; Gehring, P.R.; Toto, M.L.; Davis, J.J.

    1996-09-01

    The waste heat boilers installed in a 360 TPD waste to energy plant were identified as the bottle neck for an effort to increase plant capacity. These boilers were successfully modified to accommodate the increase of plant capacity to 408 TPD, improve steam cycle performance and reduce boiler tube failures. The project demonstrated how engineering and operation can work together to identify problems and develop solutions that satisfy engineering, operation, and financial objectives. Plant checking and testing, design review and specification development, installation and operation results are presented.

  17. Bactericidal effects of silver plus titanium dioxide-coated endotracheal tubes on Pseudomonas aeruginosa and Staphylococcus aureus.

    PubMed

    Tarquinio, Keiko M; Kothurkar, Nikhil K; Goswami, Dharendra Y; Sanders, Ronald C; Zaritsky, Arno L; LeVine, Ann Marie

    2010-04-07

    Ventilator-associated pneumonia (VAP) is a nosocomial infection resulting in significant morbidity and mortality. Pseudomonas aeruginosa (P. aeruginosa) and Staphylococcus aureus (S. aureus) are pathogens associated with VAP. Silver (Ag) coating of endotracheal tubes (ETTs) reduces bacterial colonization, however titanium dioxide (TiO(2)) coating has not been studied. Five types of ETT coatings were applied over silica layer: Ag, solgel TiO(2), solgel TiO(2) with Ag, Degussa P25 TiO(2) (Degussa TiO(2)), and Degussa TiO(2) with Ag. After ETTs were incubated with P. aeruginosa or S. aureus; colonization was determined quantitatively. Pseudomonas aeruginosa and S. aureus grew for 5 days on standard ETTs. Compared to standard ETTs, P. aeruginosa growth was significantly inhibited by solgel TiO(2) with Ag at 24 hours, and by Degussa TiO(2) with Ag at 24 and 48 hours after inoculation. No significant difference in S. aureus growth was observed between the control and any of the five coatings for 5 days. In vitro, solgel TiO(2) with Ag and Degussa TiO(2) with Ag both attenuated P. aeruginosa growth, but demonstrated no effect on S. aureus colonization. Further studies using alternative coating and incorporating UV light exposure are needed to identify their potential utility in reducing VAP.

  18. T91 cladding tubes with and without modified FeCrAlY coatings exposed in LBE at different flow, stress and temperature conditions

    NASA Astrophysics Data System (ADS)

    Weisenburger, A.; Heinzel, A.; Müller, G.; Muscher, H.; Rousanov, A.

    2008-06-01

    Corrosion tests of 2000 h duration are conducted on tubes consisting of the steel T91 in liquid metal loops containing eutectic lead-bismuth melt with 10 -6 wt% oxygen in solution. The experiments include tests at temperatures of 480-600° C, at liquid metal flow velocities of 1, 2 and 3 m/s and under mechanical stress due to an internal pressure of 15 MPa. The surface of tubes exposed to 600 °C and to different flow velocities are coated with a FeCrAlY alloy to examine its suitability as a protective coating for high loaded parts like cladding tubes. The coating was remelted by an electron pulse of GESA to homogenize the coating and improve its bonding to the bulk material. In all of the tests no liquid metal attack was observed. As received steel specimens developed multilayer oxide scales of a thickness increasing with temperature and internal pressure, while coated tubes had a thin protective alumina scale. Flow velocities above 2 m/s permanently removed formed magnetite at 550 °C. No influence of the flow velocity was observed for the coated surfaces which keep their stable thin alumina scale. The internal pressure of 15 MPa caused a strain of 0.7% in the tube wall, which obviously increases iron diffusion and enhances magnetite formation.

  19. Boiler fuel economizers surpass savings projection

    SciTech Connect

    Not Available

    1984-03-01

    This paper describes three Kentube RETROMISER fuel economiser units chosen for their efficiency and compact size. Plant gas consumption was reduced by 50,000 cu. ft. the day the first unit went on-line. The energy management program is being conducted by Whitman's Chocolates in Pennsylvania with the goal of reducing the Btu's of energy used per pound of product produced. Engineers conducted a performance study of the plant and concluded that boiler fuel economizers could produce substantial savings by preheating the boiler's feedwater. The fuel economizer finned tubing offered greater heat transfer surface than bare tube of the same diameter and its continuously welded, helically wound fin gave outstanding thermal performance and continuous fin-to-tube contact for maximum heat transfer. Equally important was the unit's compact, cylindrical design, which allowed simple installation in the boiler room.

  20. Thermally-induced stresses in graphite-epoxy tubes coated with aluminum foil

    NASA Technical Reports Server (NTRS)

    Knott, Tamara W.; Hyer, M. W.

    1989-01-01

    Thermally-induced stresses in the foil, adhesive, and graphite-epoxy layers of composite tubes with aluminum foil bonded to the inner and outer surface are computed. The thermal effects are due to a temperature decrease from the processing temperature of the material to a temperature felt to represent the space environment, the intended operating environment of the tubes. Tubes fabricated from T300/934 and P75s/934 material systems are considered. The results indicate that the presence of the foil and adhesive have no detrimental effect on the stresses in the tube.

  1. 9. RW Meyer Sugar Mill: 18761889. Locomotivetype, firetube, portable boiler, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    9. RW Meyer Sugar Mill: 1876-1889. Locomotive-type, fire-tube, portable boiler, No. 1 model. Manufactured by Ames Iron Works, Oswego, New York, 1879. 120 lbs/sq. inch working pressure, 66 sq. ft. heating surface in tubes. View: from side. The boiler provided steam for steam engine which in turn powered the mill's centrifugals. The section on the left side included the firebox with its surrounding water-legs. The fluted chimney-type structure is the steam port, safety valve, and whistle. Column projecting from side was part of steam pressure and water gauge. Pipe running above boiler carried steam to the engine. Pipe running below boiler provided the boiler feed-water. Cylindrical section included 22 fire-tube surrounded by water. The far right ... - R. W. Meyer Sugar Mill, State Route 47, Kualapuu, Maui County, HI

  2. [Determination of trace barium in environmental samples by electric-heated AAS with lanthanum-coated graphite tube].

    PubMed

    Han, Hua-yun; Lin, Lin; Chen, Ke; Wang, Feng

    2002-02-01

    In this paper a new method was established for determination of trace barium in environmental samples by graphite furnace atomic absorption spectrometry. In the presence of matrix modifier magnesium nitrate, the matrix inference was eliminated efficiently. To avoid producing barium carbide, the graphite tubes were coated differently with lanthanum, zirconium, tungsten, molybdenum, and tantalum. Results showed that the tube with lanthanum was the best. The atomization temperature was diminished. The sensitivity was improved, and the tube with lanthanum gave the longest service life. So we used the tube to determine trace barium. The trace barium in Geodchemical Standard Reference Sample Soil-1 (GSS-1) was determined by the new method, the test results showed that the method was reliability and accurate. The method has been used for the determination of trace barium in environmental samples and in water of Yellow River. The detection limit for Ba was 2.1 x 10(-12) g and the relative standard deviation(RSD) was 5.4% for 15 ng.mL-1 Ba.

  3. Histomorphological researches on large porous hydroxyapatite cylinder tubes with polylactic acid surface coating in different nonskeletal sites in vivo.

    PubMed

    Zhang, Cong; Huang, Peng; Weng, Jie; Zhi, Wei; Hu, Yonghe; Feng, Huaizhi; Yao, Yimin; Li, Shuo; Xia, Tian

    2012-05-01

    Porous hydroxyapatite (HA) ceramic cylinder tubes coated with polylactic acid on the exposed surfaces were implanted in four nonskeletal sites (omentum, peritoneum, vastus lateralis, and side of femur). Six months postoperatively, proper amount of Chinese ink was injected to dye the implanting areas. Decalcified and nondecalcified sections were observed under inverted microscope. The results showed that the soft tissues around the HA cylinder tubes in peritoneum, vastus lateralis, and side of femur groups appeared visible black. Some small blacked vascular architectures were also discernible. However in omentum group, only small number of blacked vessels existed. Histological observations indicated that vascularization and ossification occurred in peritoneum, vastus lateralis, and side of femur groups. In omentum group, there was no any sign of vascularization and ossification. A conclusion could be made in this study that excepting bones and muscles, parietal peritoneum could serve as a potential spot for culturing histoengineering hydroxyapatite (HA)-polylactic acid (PLA) ceramic bone substitutes. Copyright © 2012 Wiley Periodicals, Inc.

  4. Electroplating of nanostructured polyaniline-polypyrrole composite coating in a stainless-steel tube for on-line in-tube solid phase microextraction.

    PubMed

    Asiabi, Hamid; Yamini, Yadollah; Seidi, Shahram; Esrafili, Ali; Rezaei, Fatemeh

    2015-06-05

    In this work, a novel and efficient on-line in-tube solid phase microextraction method followed by high performance liquid chromatography was developed for preconcentration and determination of trace amounts of parabens. A nanostructured polyaniline-polypyrrole composite was electrochemically deposited on the inner surface of a stainless steel tube and used as the extraction phase. Several important factors that influence the extraction efficiency, including type of solid-phase coating, extraction and desorption times, flow rates of the sample solution and eluent, pH, and ionic strength of the sample solution were investigated and optimized. Under the optimal conditions, the limits of detection were in the range of 0.02-0.04 μg L(-1). This method showed good linearity for parabens in the range of 0.07-50 μg L(-1), with coefficients of determination better than 0.998. The intra- and inter-assay precisions (RSD%, n=3) were in the range of 5.9-7.0% and 4.4-5.7% at three concentration levels of 2, 10, and 20 μg L(-1), respectively. The extraction recovery values for the spiked samples were in the acceptable range of 80.3-90.2%. The validated method was successfully applied for analysis of methyl-, ethyl-, and propyl parabens in some water, milk, and juice samples. Copyright © 2015 Elsevier B.V. All rights reserved.

  5. 32. INTERIOR BOILER HOUSE Above the two furnaces, one ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    32. INTERIOR - BOILER HOUSE Above the two furnaces, one of the boilers can be seen to the upper left. The large pipes in the foreground are all that remain of the distribution system. Most of the pipe and tubing have been stripped from the room and sold for scrap. - Hovden Cannery, 886 Cannery Row, Monterey, Monterey County, CA

  6. Technique development for modulus, microcracking, hermeticity, and coating evaluation capability characterization of SiC/SiC tubes

    SciTech Connect

    Hu, Xunxiang; Ang, Caen K.; Singh, Gyanender P.; Katoh, Yutai

    2016-08-01

    Driven by the need to enlarge the safety margins of nuclear fission reactors in accident scenarios, research and development of accident-tolerant fuel has become an important topic in the nuclear engineering and materials community. A continuous-fiber SiC/SiC composite is under consideration as a replacement for traditional zirconium alloy cladding owing to its high-temperature stability, chemical inertness, and exceptional irradiation resistance. An important task is the development of characterization techniques for SiC/SiC cladding, since traditional work using rectangular bars or disks cannot directly provide useful information on the properties of SiC/SiC composite tubes for fuel cladding applications. At Oak Ridge National Laboratory, experimental capabilities are under development to characterize the modulus, microcracking, and hermeticity of as-fabricated, as-irradiated SiC/SiC composite tubes. Resonant ultrasound spectroscopy has been validated as a promising technique to evaluate the elastic properties of SiC/SiC composite tubes and microcracking within the material. A similar technique, impulse excitation, is efficient in determining the basic mechanical properties of SiC bars prepared by chemical vapor deposition; it also has potential for application in studying the mechanical properties of SiC/SiC composite tubes. Complete evaluation of the quality of the developed coatings, a major mitigation strategy against gas permeation and hydrothermal corrosion, requires the deployment of various experimental techniques, such as scratch indentation, tensile pulling-off tests, and scanning electron microscopy. In addition, a comprehensive permeation test station is being established to assess the hermeticity of SiC/SiC composite tubes and to determine the H/D/He permeability of SiC/SiC composites. This report summarizes the current status of the development of these experimental capabilities.

  7. 34. TOP O THE BOILER SHOWING CONSTRUCTION DETAILS. NOTE THE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    34. TOP O THE BOILER SHOWING CONSTRUCTION DETAILS. NOTE THE 1/2-INCH ROUND IRON REINFORCING ROD AND GALVANIZED FARM FENCING IN THE RIGHT FOREGROUND. AND THE EXPANDED METAL LATH WITH CEMENT COATING IN THE CEILING ABOVE THE BOILER. - Moravian Pottery & Tile Works, Southwest side of State Route 313 (Swamp Road), Northwest of East Court Street, Doylestown, Bucks County, PA

  8. 34. (Credit JTL) Front (north side) of three water tube ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    34. (Credit JTL) Front (north side) of three water tube boilers built by the Heine Safety Boiler Co. of St. Louis, Missouri in 1917; rebuilt in 1938. Front doors opened on center boiler to show water header and inspection plugs for water tubes. Smaller doors beneath open into firebox; boilers presently equipped for gas firing. Operating pressure approx. 150 psi (saturated steam). - McNeil Street Pumping Station, McNeil Street & Cross Bayou, Shreveport, Caddo Parish, LA

  9. Preparation and evaluation of a novel molecularly imprinted polymer coating for selective extraction of indomethacin from biological samples by electrochemically controlled in-tube solid phase microextraction.

    PubMed

    Asiabi, Hamid; Yamini, Yadollah; Seidi, Shahram; Ghahramanifard, Fazel

    2016-03-24

    In the present work, an automated on-line electrochemically controlled in-tube solid-phase microextraction (EC-in-tube SPME) coupled with HPLC-UV was developed for the selective extraction and preconcentration of indomethacin as a model analyte in biological samples. Applying an electrical potential can improve the extraction efficiency and provide more convenient manipulation of different properties of the extraction system including selectivity, clean-up, rate, and efficiency. For more enhancement of the selectivity and applicability of this method, a novel molecularly imprinted polymer coated tube was prepared and applied for extraction of indomethacin. For this purpose, nanostructured copolymer coating consisting of polypyrrole doped with ethylene glycol dimethacrylate was prepared on the inner surface of a stainless-steel tube by electrochemical synthesis. The characteristics and application of the tubes were investigated. Electron microscopy provided a cross linked porous surface and the average thickness of the MIP coating was 45 μm. Compared with the non-imprinted polymer coated tubes, the special selectivity for indomethacin was discovered with the molecularly imprinted coated tube. Moreover, stable and reproducible responses were obtained without being considerably influenced by interferences commonly existing in biological samples. Under the optimal conditions, the limits of detection were in the range of 0.07-2.0 μg L(-1) in different matrices. This method showed good linearity for indomethacin in the range of 0.1-200 μg L(-1), with coefficients of determination better than 0.996. The inter- and intra-assay precisions (RSD%, n = 3) were respectively in the range of 3.5-8.4% and 2.3-7.6% at three concentration levels of 7, 70 and 150 μg L(-1). The results showed that the proposed method can be successfully applied for selective analysis of indomethacin in biological samples. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. Tritium permeation experiments using reduced activation ferritic/martensitic steel tube and erbium oxide coating

    SciTech Connect

    Takumi Chikada; Masashi Shimada; Robert Pawelko; Takayuki Terai; Takeo Muroga

    2013-09-01

    Low concentration tritium permeation experiments have been performed on uncoated F82H and Er2O3-coated tubular samples in the framework of the Japan-US TITAN collaborative program. Tritium permeability of the uncoated sample with 1.2 ppm tritium showed one order of magnitude lower than that with 100% deuterium. The permeability of the sample with 40 ppm tritium was more than twice higher than that of 1.2 ppm, indicating a surface contribution at the lower tritium concentration. The Er2O3-coated sample showed two orders of magnitude lower permeability than the uncoated sample, and lower permeability than that of the coated plate sample with 100% deuterium. It was also indicated that the memory effect of ion chambers in the primary and secondary circuits was caused by absorption of tritiated water vapor that was generated by isotope exchange reactions between tritium and surface water on the coating.

  11. Properties of Thick Sputtered Ta used for Protective Gun Tube Coatings

    SciTech Connect

    Matson, Dean W.; McClanahan, Edwin D.; Lee, Sabrina L.; Windover, Donald

    2001-10-01

    Thick tantalum coatings were deposited on the bore surfaces of 25 mm I.D. cylindrical gun steel substrates using a high-rate triode sputtering apparatus. Sputtering parameters affecting the tantalum phase and microstructure were investigated. Prior work has indicated that the sputtering gas species and substrate temperature during deposition affect the characteristics of the tantalum coatings. In the work presented here, we report on experimental studies aimed at evaluating additional phase and microstructural effects resulting from changes in sputtering gas species and substrate bias during the deposition. Tantalum deposits of 75 to 140 {mu}m thicknesses were evaluated using x-ray diffraction, optical microscopy, and microindentation hardness measurements. Coatings deposited using krypton gas, a 200 C substrate temperature, and 3.5 mTorr gas pressure also showed little variation when deposited at substrate biases ranging from 50 to 150 V. However, the tantalum coatings produced under similar conditions with an unbiased (floating) substrate were found to be the beta phase of the material and had a columnar microstructure. Beta-phase tantalum was produced at low substrate biases (from 0 to 50 V) when using Xe as the sputtering gas. Both phase and microstructure of the tantalum coating could be altered in mid-run by adjusting the sputtering parameters and appeared independent of the phase and microstructure of the underlying coating.

  12. Adsorption of Urinary Proteins on the Conventionally Used Urine Collection Tubes: Possible Effects on Urinary Proteome Analysis and Prevention of the Adsorption by Polymer Coating

    PubMed Central

    Kiyokawa, Iwao; Sogawa, Kazuyuki; Ise, Keiko; Iida, Fumie; Satoh, Mamoru; Miura, Toshihide; Kojima, Ryo; Katayama, Katsuhiro; Nomura, Fumio

    2011-01-01

    One possible factor determining recovery of trace amount of protein biomarker candidates during proteome analyses could be adsorption on urine tubes. This issue, however, has not been well addressed so far. Recently, a new technical device of surface coating by poly(2-methacryloyloxyethyl phosphorylcholine (MPC)-co-n-butyl methacrylate (BMA)) (poly(MPC-co-BMA)) has been developed mainly to prevent the adsorption of plasma proteins. We assessed whether conventionally used urine tubes adsorb trace amount of urinary proteins and, if any, whether the surface coating by poly(MPC-co-BMA) can minimize the adsorption. Proteinuric urine samples were kept in poly(MPC-co-BMA)-coated and noncoated urine tubes for 15 min and possibly adsorbed proteins and/or peptides onto urine tubes were analyzed by SDS-PAGE, 2-DE, and the MALDI-TOF MS. It was found that a number of proteins and/or peptides adsorb on the conventionally used urine tubes and that surface coating by poly(MPC-co-BMA) can minimize the adsorption without any significant effects on routine urinalysis test results. Although it remains to be clarified to what extent the protein adsorption can modify the results of urinary proteome analyses, one has to consider this possible adsorption of urinary proteins when searching for trace amounts of protein biomarkers in urine. PMID:22229090

  13. Inorganic-organic hybrid coating material for the online in-tube solid-phase microextraction of monohydroxy polycyclic aromatic hydrocarbons in urine.

    PubMed

    Wang, ShuLing; Xu, Hui

    2016-12-01

    An inorganic-organic hybrid nanocomposite (zinc oxide/polypyrrole) that represents a novel kind of coating for in-tube solid-phase microextraction is reported. The composite coating was prepared by a facile electrochemical polymerization strategy on the inner surface of a stainless-steel tube. Based on the coated tube, a novel online in-tube solid-phase microextraction with liquid chromatography and mass spectrometry method was developed and applied for the extraction of three monohydroxy polycyclic aromatic hydrocarbons in human urine. The coating displayed good extraction ability toward monohydroxy polycyclic aromatic hydrocarbons. In addition, long lifespan, excellent stability, and good compression resistance were also obtained for the coating. The experimental conditions affecting the extraction were optimized systematically. Under the optimal conditions, the limits of detection and quantification were in the range of 0.039-0.050 and 0.130-0.167 ng/mL, respectively. Good linearity (0.2-100 ng/mL) was obtained with correlation coefficients larger than 0.9967. The repeatability, expressed as relative standard deviation, ranged between 2.5% and 9.4%. The method offered the advantage of process simplicity, rapidity, automation, and sensitivity in the analysis of human urinary monohydroxy polycyclic aromatic hydrocarbons in two different cities of Hubei province. An acceptable recovery of monohydroxy polycyclic aromatic hydrocarbons (64-122%) represented the additional attractive features of the method in real urine analysis.

  14. Pollen tube contents initiate ovule enlargement and enhance seed coat development without fertilization

    PubMed Central

    Kasahara, Ryushiro D.; Notaguchi, Michitaka; Nagahara, Shiori; Suzuki, Takamasa; Susaki, Daichi; Honma, Yujiro; Maruyama, Daisuke; Higashiyama, Tetsuya

    2016-01-01

    In angiosperms, pollen tubes carry two sperm cells toward the egg and central cells to complete double fertilization. In animals, not only sperm but also seminal plasma is required for proper fertilization. However, little is known regarding the function of pollen tube content (PTC), which is analogous to seminal plasma. We report that the PTC plays a vital role in the prefertilization state and causes an enlargement of ovules without fertilization. We termed this phenomenon as pollen tube–dependent ovule enlargement morphology and placed it between pollen tube guidance and double fertilization. Additionally, PTC increases endosperm nuclei without fertilization when combined with autonomous endosperm mutants. This finding could be applied in agriculture, particularly in enhancing seed formation without fertilization in important crops. PMID:27819041

  15. Novel techniques and devices for in-situ film coatings of long, small diameter tubes or elliptical and other surface contours

    DOE PAGES

    Hershcovitch, Ady; Blaskiewicz, Michael; Brennan, Joseph Michael; ...

    2015-07-30

    In this study, devices and techniques that can, via physical vapor deposition,coat various surface contours or very long small aperture pipes, are described. Recently, a magnetron mole was developed in order to in-situ coat accelerator tube sections of the Brookhaven National Lab relativistic heavy ion collider that have 7.1 cm diameter with access points that are 500 m apart, for copper coat the accelerator vacuum tube in order to alleviate the problems of unacceptable ohmic heating and of electron clouds. A magnetron with a 50 cm long cathode was designed fabricated and successfully operated to copper coat a whole assemblymore » containing a full-size, stainless steel, cold bore, of the accelerator magnet tubing connected to two types bellows, to which two additional pipes made of accelerator tubing were connected. The magnetron is mounted on a carriage with spring loaded wheels that successfully crossed bellows and adjusted for variations in vacuum tube diameter, while keeping the magnetron centered. Electrical power and cooling water were fed through a cable bundle. The umbilical cabling system, which is enclosed in a flexible braided metal sleeve, is driven by a motorized spool. To increase cathode lifetime, movable magnet package was developed, and thickest possible cathode was made, with a rather challenging target to substrate distance of less than 1.5 cm. Optimized process to ensure excellent adhesion was developed. Coating thickness of 10 μm Cu passed all industrial tests and even exceeded maximum capability of a 12 kg pull test fixture. Room temperature radio frequency (RF) resistivity measurement indicated that 10 μm Cu coated stainless steel accelerator tube has conductivity close to copper tubing. Work is in progress to repeat the RF resistivity measurement at cryogenic temperatures. Over 20 years ago, a device using multi axis robotic manipulators controlling separate robotic assemblies resulted in nine-axes of motion combined with conformal

  16. Novel techniques and devices for in-situ film coatings of long, small diameter tubes or elliptical and other surface contours

    SciTech Connect

    Hershcovitch, Ady; Blaskiewicz, Michael; Brennan, Joseph Michael; Fischer, Wolfram; Liaw, Chong -Jer; Meng, Wuzhang; Todd, Robert; Custer, Art; Dingus, Aaron; Erikson, Mark; Jamshidi, Nader; Poole, Henry Joe

    2015-07-30

    In this study, devices and techniques that can, via physical vapor deposition,coat various surface contours or very long small aperture pipes, are described. Recently, a magnetron mole was developed in order to in-situ coat accelerator tube sections of the Brookhaven National Lab relativistic heavy ion collider that have 7.1 cm diameter with access points that are 500 m apart, for copper coat the accelerator vacuum tube in order to alleviate the problems of unacceptable ohmic heating and of electron clouds. A magnetron with a 50 cm long cathode was designed fabricated and successfully operated to copper coat a whole assembly containing a full-size, stainless steel, cold bore, of the accelerator magnet tubing connected to two types bellows, to which two additional pipes made of accelerator tubing were connected. The magnetron is mounted on a carriage with spring loaded wheels that successfully crossed bellows and adjusted for variations in vacuum tube diameter, while keeping the magnetron centered. Electrical power and cooling water were fed through a cable bundle. The umbilical cabling system, which is enclosed in a flexible braided metal sleeve, is driven by a motorized spool. To increase cathode lifetime, movable magnet package was developed, and thickest possible cathode was made, with a rather challenging target to substrate distance of less than 1.5 cm. Optimized process to ensure excellent adhesion was developed. Coating thickness of 10 μm Cu passed all industrial tests and even exceeded maximum capability of a 12 kg pull test fixture. Room temperature radio frequency (RF) resistivity measurement indicated that 10 μm Cu coated stainless steel accelerator tube has conductivity close to copper tubing. Work is in progress to repeat the RF resistivity measurement at cryogenic temperatures. Over 20 years ago, a device using multi axis robotic manipulators controlling separate robotic assemblies resulted in nine-axes of motion combined with conformal shape of the

  17. A Rule-Based Industrial Boiler Selection System

    NASA Astrophysics Data System (ADS)

    Tan, C. F.; Khalil, S. N.; Karjanto, J.; Tee, B. T.; Wahidin, L. S.; Chen, W.; Rauterberg, G. W. M.; Sivarao, S.; Lim, T. L.

    2015-09-01

    Boiler is a device used for generating the steam for power generation, process use or heating, and hot water for heating purposes. Steam boiler consists of the containing vessel and convection heating surfaces only, whereas a steam generator covers the whole unit, encompassing water wall tubes, super heaters, air heaters and economizers. The selection of the boiler is very important to the industry for conducting the operation system successfully. The selection criteria are based on rule based expert system and multi-criteria weighted average method. The developed system consists of Knowledge Acquisition Module, Boiler Selection Module, User Interface Module and Help Module. The system capable of selecting the suitable boiler based on criteria weighted. The main benefits from using the system is to reduce the complexity in the decision making for selecting the most appropriate boiler to palm oil process plant.

  18. Experimental studies on the enhanced flow boiling heat transfer and pressure drop of organic fluid with high saturation temperature in vertical porous coated tube

    NASA Astrophysics Data System (ADS)

    Yang, Dong; Shen, Zhi; Chen, Tingkuan; Zhou, Chenn Q.

    2013-07-01

    The characteristics of flow boiling heat transfer and pressure drop of organic fluid with high saturation temperature in a vertical porous coated tube are experimentally studied in this paper. The experiments are performed at evaporation pressure of 0.16-0.31MPa, mass flux of 390-790kg/m2s, and vapor quality of 0.06-0.58. The variations of heat transfer coefficient and pressure drop with vapor quality are measured and compared to the results of smooth tube. Boiling curves are generated at mass flux of 482 and 675kg/m2s. The experimental results indicate that the heat transfer coefficients of the porous tube are 1.8-3.5 times those of smooth tube, and that the frictional pressure drops of the porous tube are 1.1-2.9 times those of smooth tube. The correlations for heat transfer coefficient and frictional pressure drop are derived, in which the effect of fluid molecular weight is included. The experiments show that significant heat transfer enhancement is accompanied by a little pressure drop penalty, the application of the porous coated tube is promising in the process industries.

  19. Factors affecting stress assisted corrosion cracking of carbon steel under industrial boiler conditions

    NASA Astrophysics Data System (ADS)

    Yang, Dong

    Failure of carbon steel boiler tubes from waterside has been reported in the utility boilers and industrial boilers for a long time. In industrial boilers, most waterside tube cracks are found near heavy attachment welds on the outer surface and are typically blunt, with multiple bulbous features indicating a discontinuous growth. These types of tube failures are typically referred to as stress assisted corrosion (SAC). For recovery boilers in the pulp and paper industry, these failures are particularly important as any water leak inside the furnace can potentially lead to smelt-water explosion. Metal properties, environmental variables, and stress conditions are the major factors influencing SAC crack initation and propagation in carbon steel boiler tubes. Slow strain rate tests (SSRT) were conducted under boiler water conditions to study the effect of temperature, oxygen level, and stress conditions on crack initation and propagation on SA-210 carbon steel samples machined out of boiler tubes. Heat treatments were also performed to develop various grain size and carbon content on carbon steel samples, and SSRTs were conducted on these samples to examine the effect of microstructure features on SAC cracking. Mechanisms of SAC crack initation and propagation were proposed and validated based on interrupted slow strain tests (ISSRT). Water chemistry guidelines are provided to prevent SAC and fracture mechanics model is developed to predict SAC failure on industrial boiler tubes.

  20. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings. Final report

    SciTech Connect

    Van Weele, S.

    1991-08-01

    Fireside corrosion, caused by liquid alkali-iron trisulfates, has been an obstacle to higher steam temperatures and to efficient utilization of high-sulfur coals. Tests simulating the environment in the superheater bank of a pulverized-coal-fired boiler were conducted on several promising new alloys and claddings. Alloys were exposed to a variety of synthetic ash and simulated flue gas compositions at 650 and 700{degrees}C for times ranging up to 800 hours. Included in the testing program were new high-chromium/high-nickel alloys, modified commercial alloys, lean stainless steels (modified Type 316) clad with high-chromium/high-nickel alloys, and intermetallic aluminides. Thickness loss measurements indicated that resistance to attach improved with increasing chromium level. Silicon and aluminum were also helpful in resisting attack, while molybdenum was detrimental to the resistance of the alloys to attack. Three different attack modes were observed on the alloys tested. Alloys with low resistance to attack exhibited uniform wastage, while pitting was observed in more resistant alloys. In addition to surface fluxing by molten alkali-iron trisulfates, subsurface sulfur penetration and intergranular attack also occurred.

  1. Fireside corrosion testing of candidate superheater tube alloys, coatings, and claddings

    SciTech Connect

    Van Weele, S. )

    1991-08-01

    Fireside corrosion, caused by liquid alkali-iron trisulfates, has been an obstacle to higher steam temperatures and to efficient utilization of high-sulfur coals. Tests simulating the environment in the superheater bank of a pulverized-coal-fired boiler were conducted on several promising new alloys and claddings. Alloys were exposed to a variety of synthetic ash and simulated flue gas compositions at 650 and 700{degrees}C for times ranging up to 800 hours. Included in the testing program were new high-chromium/high-nickel alloys, modified commercial alloys, lean stainless steels (modified Type 316) clad with high-chromium/high-nickel alloys, and intermetallic aluminides. Thickness loss measurements indicated that resistance to attach improved with increasing chromium level. Silicon and aluminum were also helpful in resisting attack, while molybdenum was detrimental to the resistance of the alloys to attack. Three different attack modes were observed on the alloys tested. Alloys with low resistance to attack exhibited uniform wastage, while pitting was observed in more resistant alloys. In addition to surface fluxing by molten alkali-iron trisulfates, subsurface sulfur penetration and intergranular attack also occurred.

  2. Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semiannual technical progress report, August 14, 1996--January 14, 1997

    SciTech Connect

    Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1997-02-01

    Research is presently being conducted to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The research will be accomplished by producing model cermet composites using powder metallurgy and electrodeposition methods in which the effect of ceramic/metal combination for the erosion and corrosion resistance will be determined. These results will provide the basis for determining the optimum hard phase constituent size and volume percent in thermal spray coatings. Thermal spray coatings will be applied by our industrial sponsor and tested in our erosion and corrosion laboratories. In the first six months of this project, bulk powder processed Ni-Al{sub 2}O{sub 3} composites were produced at Idaho National Engineering Laboratory. The results of microstructural characterization of these alloys were presented in the first semiannual report. The composite samples contained 0, 21, 27, 37, and 45 volume percent Al{sub 2}O{sub 3} with an average particle size of 12 um. An increase in the volume fraction of alumina in the nickel matrix from 0 to 45% led to a significant increase in hardness of these composites.

  3. Uptake Study of Acetone On Ice Using A Vertical Coated Wall Flow Tube. Atmos Pheric Implications.

    NASA Astrophysics Data System (ADS)

    Peybernès, N.; Le Calvé, S.; Mirabel, Ph.

    The upper troposphere defines a region of the atmosphere (between 8 and 12 km) characterised by its low temperatures (-45 to -85 °C) and where cirrus clouds cover a substantial portion (~25 %) of the earth's surface . Some measurements in the upper troposphere showed the presence of high acetone concentrations (up to 3000 pptv) which lead to an enhanced abundance of HOX and likely modify the ozone cycles in this region of the atmosphere. The goal of this work is then to measure uptake coefficients of acetone on ice and to determine its surface coverage. The low pressure and low temperature flow tube (1-5 Torr) has been adapted to study the gas-ice interactions of atmospheric interest. By using this technique, it is possible to study kinetics of chemical reactions on ice which can be doped by adding chemical species 3, 4. This new set-up is coupled with a Mass Spectrometer which allows product identification and quantification. The vertical flow tube has a movable injector which permits to change the reaction distance and then the reaction time. The ice surface is prepared by totally wetting the inner wall of the flow tube with pure water which is then rapidly cooled down to ­20°C. The ice temperature is then regulated between -40°C and -80°C by circulating cool ethanol through a double jacket surrounding the flow tube. Our results permit to estimate the ratio of acetone molecules adsorbed by ice surface to the number of acetone molecules in the gas phase. One can then estimate the influence of its adsorption on ice on its atmospheric lifetime in the upper troposphere. 1Salomon et al., J. Geophys. Res. 102, 21411, (1997). 2S.A. Mckeen et al. Geophys. res. Lett. 24, 3177, (1997). 3 J.P.D. Abbatt et al., J. Geophys. Res. 97, 15819, (1992). 4 D.R. Hanson et al., J. Phys. Chem. 96, 2682, (1992).

  4. Heat-shrink tubing as a solid-phase microextraction coating for the enrichment and determination of phthalic acid esters.

    PubMed

    Luo, Xi; He, Chengxia; Zhang, Feifang; Wang, Hailong; Yang, Bingcheng; Liang, Xinmiao

    2014-12-01

    Heat-shrink tubing, which shrinks in one plane only (its diameter) when heated, commonly used for sealing protection in electrical engineering, was found to be able to function as a solid-phase microextraction coating. Its utility was demonstrated for the determination of phthalic acid esters in an aqueous solution combined with high-performance liquid chromatography equipped with a UV absorbance detector. The preparation procedure was rather simple and only ∼10 min was needed. The fiber cost is extremely low (∼10 cent each). The parameters affecting the extraction were optimized. Heat-shrink tubing fiber exhibited a significant enrichment effect for the three examined phthalic acid esters and up to 931-fold enrichment factor was obtained. The limit of detection was <10 μg/L for all analytes. The operation repeatability and fiber-to-fiber reproducibility were 1.2-8.3 and 5.4-9.1%, respectively. It was successfully applied for the analysis of bottled drinking water with recoveries ranging from 90.1-100.5%.

  5. Investigating the Inter-Tube Conduction Mechanism in Polycarbonate Nanocomposites Prepared with Conductive Polymer-Coated Carbon Nanotubes.

    PubMed

    Ventura, Isaac Aguilar; Zhou, Jian; Lubineau, Gilles

    2015-12-01

    A well-known strategy to improve the electrical conductivity of polymers is to dope them with high-aspect-ratio and conductive nanoparticles such as carbon nanotubes (CNTs). However, these nanocomposites also exhibit undesirable properties such as damage-sensitive and history-dependent conductivity because their macroscopic electrical conductivity is largely determined by the tunneling effect at the tube/tube interface. To reduce these issues, new nanocomposites have been developed with CNTs that have been coated with a conductive layer of poly(3,4-ethylenedioxythiophene)poly(styrenesulfonate) (PEDOT/PSS). It has been posited that the insulating region between the CNTs is replaced by a conductive polymer bridge; this has not been proven up to now. We propose here to investigate in-depth how the macroscopic conductivity of these materials is changing when (1) varying the frequency of the electrical loading (impedance spectroscopy), (2) varying the mechanical hydrostatic pressure, and (3) varying the voltage of the electrical loading. The response is systematically compared to the one of conventional carbon nanotube/polycarbonate (CNT/PC) nanocomposites so we can clarify how efficiently the tunneling effect is suppressed from these composites. The objective is to elucidate further the mechanism for conduction in such material formulations.

  6. Investigating the Inter-Tube Conduction Mechanism in Polycarbonate Nanocomposites Prepared with Conductive Polymer-Coated Carbon Nanotubes

    NASA Astrophysics Data System (ADS)

    Ventura, Isaac Aguilar; Zhou, Jian; Lubineau, Gilles

    2015-12-01

    A well-known strategy to improve the electrical conductivity of polymers is to dope them with high-aspect-ratio and conductive nanoparticles such as carbon nanotubes (CNTs). However, these nanocomposites also exhibit undesirable properties such as damage-sensitive and history-dependent conductivity because their macroscopic electrical conductivity is largely determined by the tunneling effect at the tube/tube interface. To reduce these issues, new nanocomposites have been developed with CNTs that have been coated with a conductive layer of poly(3,4-ethylenedioxythiophene)poly(styrenesulfonate) (PEDOT/PSS). It has been posited that the insulating region between the CNTs is replaced by a conductive polymer bridge; this has not been proven up to now. We propose here to investigate in-depth how the macroscopic conductivity of these materials is changing when (1) varying the frequency of the electrical loading (impedance spectroscopy), (2) varying the mechanical hydrostatic pressure, and (3) varying the voltage of the electrical loading. The response is systematically compared to the one of conventional carbon nanotube/polycarbonate (CNT/PC) nanocomposites so we can clarify how efficiently the tunneling effect is suppressed from these composites. The objective is to elucidate further the mechanism for conduction in such material formulations.

  7. Hydrogel Antimicrobial Capture Coatings for Endotracheal Tubes: A Pharmaceutical Strategy Designed to Prevent Ventilator-Associated Pneumonia.

    PubMed

    Jones, David S; McCoy, Colin P; Andrews, Gavin P; McCrory, Roisin M; Gorman, Sean P

    2015-08-03

    This paper presents a novel strategy for the prevention of ventilator-associated pneumonia that involves coating poly(vinyl chloride, PVC) endotracheal tubes (ET) with hydrogels that may be subsequently used to entrap nebulized antimicrobial solutions. Candidate hydrogels were prepared containing a range of ratios of hydroxyethyl methacrylate (HEMA) and methacrylic acid (MAA) from 100:0 to 70:30 using free radical polymerization and, when required, simultaneous attachment to PVC was performed. The mechanical properties, glass transition temperatures, swelling kinetics, uptake of gentamicin from an aqueous medium, and gentamicin release were characterized. Increasing the MAA content of the hydrogels significantly decreased the ultimate tensile strength, % elongation at break, Young's modulus, and increased the glass transition temperature, the swelling ratio, and gentamicin uptake. Microbial (Staphylococcus aureus and Pseudomonas aeruginosa) adherence to control (drug-free) hydrogels was observed; however, while adherence to gentamicin-containing p(HEMA) occurred, no adherence occurred to gentamicin-containing HEMA:MAA copolymers. Antimicrobial persistence of gentamicin-containing hydrogels was examined by determining the zone of inhibition against each microorganism on successive days. Hydrogel composition affected the observed antimicrobial persistence, with the hydrogel composed of 70:30 HEMA:MAA exhibiting >20 days persistence against S. aureus and P. aeruginosa, respectively. To simulate clinical use, the hydrogels (coated onto PVC) were first exposed to a nebulized solution of gentamicin (4 mL, 80 mg for 20 min), and then to nebulized bacteria (4 mL ca. 1×10(9) colony forming units mL(-1), 30 min). Viable bacteria were not observed on the gentamicin-treated p(HEMA: MAA) copolymers, whereas growth was observed on gentamicin-treated p(HEMA). In light of the excellent antimicrobial activity and physicochemical properties, p(HEMA: MAA) copolymers composed of

  8. Heat pipe waste heat recovery boilers

    NASA Astrophysics Data System (ADS)

    Littwin, D. A.; McCurley, J.

    The use of heat pipes as transport devices in waste heat recovery boilers is examined. Test results show that heat pipes can efficiently extract heat from the hot gas stream and transfer it inside the pressure vessel for the steam generation process. The benefits of incorporating heat pipes into the design of waste heat recovery boilers include a highly compact package, a significant reduction in thermally induced stresses, double isolation of the steam from the heat source, an extended surface for improved efficiency in heat extraction, improved circulation and stability in the boiling regime, easy cleaning, individually replaceable tubes, and low flue gas pressure drop.

  9. Bioactivity and electrochemical behavior of hydroxyapatite-silicon-multi walled carbon nano-tubes composite coatings synthesized by EPD on NiTi alloys in simulated body fluid.

    PubMed

    Khalili, V; Khalil-Allafi, J; Frenzel, J; Eggeler, G

    2017-02-01

    In order to improve the surface bioactivity of NiTi bone implant and corrosion resistance, hydroxyapatite coating with addition of 20wt% silicon, 1wt% multi walled carbon nano-tubes and both of them were deposited on a NiTi substrate using a cathodic electrophoretic method. The apatite formation ability was estimated using immersion test in the simulated body fluid for 10days. The SEM images of the surface of coatings after immersion in simulated body fluid show that the presence of silicon in the hydroxyapatite coatings accelerates in vitro growth of apatite layer on the coatings. The Open-circuit potential and electrochemical impedance spectroscopy were measured to evaluate the electrochemical behavior of the coatings in the simulated body fluid at 37°C. The results indicate that the compact structure of hydroxyapatite-20wt% silicon and hydroxyapatite-20wt% silicon-1wt% multi walled carbon nano-tubes coatings could efficiently increase the corrosion resistance of NiTi substrate.

  10. Comparative study of tube assembly in three-dimensional collagen matrix and on Matrigel coats.

    PubMed

    Montañez, Eloi; Casaroli-Marano, Ricardo P; Vilaró, Senén; Pagan, Roser

    2002-01-01

    This study compares phenotypic changes of human umbilical endothelial vein cells cultured in three-dimensional collagen matrixes in the presence of basic fibroblast growth factor or on Matrigel coats. Under both conditions, endothelial cells rapidly assembled into an irregular network of tubular structures with a high frequency of intercellular or lumen-like spaces. Tubular structures were characterized and compared by phase-contrast, confocal and electron microscopy. The dominant mechanism of lumen-like formation was highly model-dependent. Ultrastructural analyses of capillary-like structures and the mechanism of lumen-like formation indicated that the in vivo angiogenesis was better reproduced in the collagen model.

  11. 51. BOILER ROOM. SMALL BOILER ON LEFT OF UNKNOWN MANUFACTURE, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    51. BOILER ROOM. SMALL BOILER ON LEFT OF UNKNOWN MANUFACTURE, WITH INDUCTION MOTORS. HARTLEY BOILER, MONTGOMERY, ALABAMA, ON RIGHT. - Prattville Manufacturing Company, Number One, 242 South Court Street, Prattville, Autauga County, AL

  12. 33. BOILER HOUSE FURNACE AND BOILER Close view of ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    33. BOILER HOUSE - FURNACE AND BOILER Close view of the Dorward Engineering Company furnace and boiler which provided steam to the cooking retorts in the adjacent room. - Hovden Cannery, 886 Cannery Row, Monterey, Monterey County, CA

  13. Boiler control systems engineering

    SciTech Connect

    Gilman, J.

    2005-07-01

    The book provides in-depth coverage on how to safely and reliably control the firing of a boiler. Regardless of the capacity or fuel, certain fundamental control systems are required for boiler control. Large utility systems are more complex due to the number of burners and the overall capacity and equipment. This book covers engineering details on control systems and provides specific examples of boiler control including configuration and tuning. References to requirements are based on the 2004 NFPA 85 along with other ISA standards. Detailed chapters cover: Boiler fundamentals including piping and instrument diagrams (P&IDs) and a design basis checklist; Control of boilers, from strategies and bumpless transfer to interlock circuitry and final control elements; Furnace draft; Feedwater; Coal-fired boilers; Fuel and air control; Steam temperature; Burner management systems; Environment; and Control valve sizing. 2 apps.

  14. Boiler saves pollution problem

    SciTech Connect

    Kaiser, J.A.

    1981-02-01

    Monarch Furniture Industries, High Point, N.C. replaced their old locomotive-type boiler in 1978 with a multifuel boiler system from Energy Systems, Inc. of Chattanooga. The system burns the company's wood wastes, supplemented with low-cost coal in winter. It generates 17,250 lbs. per hour of steam, gives a much cleaner burn than the old boiler, and has a calculated payback period of 1.67 years.

  15. Expert systems optimize boiler performance, extend plant life

    SciTech Connect

    Sarunac, N.

    2006-10-15

    Slagging and fouling of furnaces and boilers' convective pass top the list of costly coal plant O & M problems. Although sootblowing is a tried and true solution, running sootblowers too often can erode boiler tubes. Lehigh University's Energy Research Center has developed an 'expert' sootblowing system that has outperformed experienced operators' 'seat of their pants' sootblowing procedures on two head-to-head field tests. 7 figs., 2 tabs.

  16. 17. Internal view of boiler in steam space above return ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    17. Internal view of boiler in steam space above return flues. View looks forward in ship toward fireboxes; tubes (flues) below carry hot combustion gases from return chamber to smoke chamber. From thence gasses flow through vertical pipe at left into steam stack, and eventually to ship's smokestack. Inclined and radiating straps are stays used to reinforce boiler plates against distortion under pressure. - Ferry TICONDEROGA, Route 7, Shelburne, Chittenden County, VT

  17. Improved Process control of wood waste fired boilers

    SciTech Connect

    Process Control Solutions, Inc.

    2004-01-30

    This project's principal aim was the conceptual and feasibility stage development of improved process control methods for wood-waste-fired water-tube boilers operating in industrial manufacturing applications (primarily pulp and paper). The specific objectives put forth in the original project proposal were as follows: (1) fully characterize the wood-waste boiler control inter-relationships and constraints through data collection and analysis; (2) design an improved control architecture; (3) develop and test an appropriate control and optimization algorithm; and (4) develop and test a procedure for reproducing the approach and deriving the benefits on similar pulp and paper wood-waste boilers. Detailed tasks were developed supporting these objectives.

  18. Compartment B3, boiler room; showing boiler facing of boiler #5 ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Compartment B-3, boiler room; showing boiler facing of boiler #5 aft to forward from passing room B-25. (030A) - USS Olympia, Penn's Landing, 211 South Columbus Boulevard, Philadelphia, Philadelphia County, PA

  19. Determination of zinc and copper in edible plants by nanometer silica coated, slotted quartz tube, flame atomic absorption spectrometry.

    PubMed

    Li, Shun-Xing; Zheng, Feng-Ying; Li, Yan-Cai; Cai, Tian-Shou; Zheng, Jian-Zhong

    2012-11-28

    Nanometer SiO(2) was coated onto the inner wall of a slotted quartz tube atomizer (STAT) and then was used as a new atomizer (NSC- STAT) for the determination of Zn and Cu by flame atomic absorption spectrometry (FAAS). Compared to conventional STAT-FAAS, the analytical performance of NSC-STAT-FAAS was improved as follows: (a) the linear range of calibration curves was expanded from 30.0-200.0 ng mL(-1) to 5.0-400.0 ng mL(-1) for Zn, and from 100.0-1000.0 ng mL(-1) to 50.0-2000.0 ng mL(-1) for Cu; and (b) the characteristic concentration was decreased from 6.0 ng mL(-1)/1% to 2.7 ng mL(-1)/1% for Zn and from 25.0 ng mL(-1)/1% to 10.1 ng mL(-1)/1% for Cu. NSC-STAT-FAAS was applied for the determination of Zn and Cu in edible plants, including herbal medicine, marine algae, tomato leaves (NIST 1573), and apple leaves (NIST 1515).

  20. Super Boiler: Packed Media/Transport Membrane Boiler Development and Demonstration

    SciTech Connect

    Liss, William E; Cygan, David F

    2013-04-17

    Gas Technology Institute (GTI) and Cleaver-Brooks developed a new gas-fired steam generation system the Super Boiler for increased energy efficiency, reduced equipment size, and reduced emissions. The system consists of a firetube boiler with a unique staged furnace design, a two-stage burner system with engineered internal recirculation and inter-stage cooling integral to the boiler, unique convective pass design with extended internal surfaces for enhanced heat transfer, and a novel integrated heat recovery system to extract maximum energy from the flue gas. With these combined innovations, the Super Boiler technical goals were set at 94% HHV fuel efficiency, operation on natural gas with <5 ppmv NOx (referenced to 3%O2), and 50% smaller than conventional boilers of similar steam output. To demonstrate these technical goals, the project culminated in the industrial demonstration of this new high-efficiency technology on a 300 HP boiler at Clement Pappas, a juice bottler located in Ontario, California. The Super Boiler combustion system is based on two stage combustion which combines air staging, internal flue gas recirculation, inter-stage cooling, and unique fuel-air mixing technology to achieve low emissions rather than external flue gas recirculation which is most commonly used today. The two-stage combustion provides lower emissions because of the integrated design of the boiler and combustion system which permit precise control of peak flame temperatures in both primary and secondary stages of combustion. To reduce equipment size, the Super Boiler's dual furnace design increases radiant heat transfer to the furnace walls, allowing shorter overall furnace length, and also employs convective tubes with extended surfaces that increase heat transfer by up to 18-fold compared to conventional bare tubes. In this way, a two-pass boiler can achieve the same efficiency as a traditional three or four-pass firetube boiler design. The Super Boiler is consequently up to

  1. Coatings.

    ERIC Educational Resources Information Center

    Anderson, Dennis G.

    1989-01-01

    This review covers analytical techniques applicable to the examination of coatings, raw materials, and substrates upon which coatings are placed. Techniques include chemical and electrochemical methods, chromatography, spectroscopy, thermal analysis, microscopy, and miscellaneous techniques. (MVL)

  2. Coatings.

    ERIC Educational Resources Information Center

    Anderson, Dennis G.

    1989-01-01

    This review covers analytical techniques applicable to the examination of coatings, raw materials, and substrates upon which coatings are placed. Techniques include chemical and electrochemical methods, chromatography, spectroscopy, thermal analysis, microscopy, and miscellaneous techniques. (MVL)

  3. 68. 1911 BOILER HOUSE LOOKING SOUTH. BOILERS ARE CA. 1945. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    68. 1911 BOILER HOUSE LOOKING SOUTH. BOILERS ARE CA. 1945. SPACE HEATING BOILER S REPLACED ORIGINAL 8 VERTICAL HIGH PRESSURE STEAM POWER BOILERS. THE ORIGINAL SHEET METAL FLUE IS IN THE UPPER CENTER. - Boston Manufacturing Company, 144-190 Moody Street, Waltham, Middlesex County, MA

  4. 39. (Credit JTL) Interior of boiler room looking east; boiler ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    39. (Credit JTL) Interior of boiler room looking east; boiler casing in background, boiler feedwater pumps and feedwater heater in middle ground; hot well on columns in left foreground. Steam lines from boilers to high service engines pass overhead. - McNeil Street Pumping Station, McNeil Street & Cross Bayou, Shreveport, Caddo Parish, LA

  5. Barrel calorimeters and computer solve boiler circulation problem

    SciTech Connect

    Godbey, J.W.; Ruggles, W.L.

    1997-12-01

    The specific design of water-tube fired boilers and waste-heat steam generators can sometimes actually impede circulation of the steam/water mix essential for proper tube cooling and overall operation. However, proving that and developing corrective measurements can be difficult. This situation can be dealt with using a combination of an antiquated but simple technology--barrel calorimeters--and a computer. The technique shows the effects of boiler load, steam drum water level and modifications to the steam drum primary baffle on tube top-dryness and, indirectly, circulation. The method was applied to up to 20 tubes simultaneously in a chemical plant boiler. The boiler involved was a 300 thousand pound per hour (Mlb/hr) gas-fired unit designed to operate at 335 psig and 600 F. During the first few months of operation, it experienced several incidents of sagging, ductile-swelling and thin-lipped ruptures in the front wall and roof tubes immediately above its burners. These phenomena were also accompanied by scale-related heat blistering of the furnace wall and screen tubes. Were two separate problems being experienced or were these different symptoms of a single problem?

  6. Drying Milk With Boiler Exhaust

    NASA Technical Reports Server (NTRS)

    Broussard, M. R.

    1984-01-01

    Considerable energy saved in powdered-milk industry. Only special requirement boiler fired with natural gas or other clean fuel. Boiler flue gas fed to spray drier where it directly contacts product to be dried. Additional heat supplied by auxillary combustor when boiler output is low. Approach adaptable to existing plants with minimal investment because most already equipped with natural-gas-fired boilers.

  7. Drying Milk With Boiler Exhaust

    NASA Technical Reports Server (NTRS)

    Broussard, M. R.

    1984-01-01

    Considerable energy saved in powdered-milk industry. Only special requirement boiler fired with natural gas or other clean fuel. Boiler flue gas fed to spray drier where it directly contacts product to be dried. Additional heat supplied by auxillary combustor when boiler output is low. Approach adaptable to existing plants with minimal investment because most already equipped with natural-gas-fired boilers.

  8. Hot Corrosion Behavior of Arc-Sprayed Highly Dense NiCr-Based Coatings in Chloride Salt Deposit

    NASA Astrophysics Data System (ADS)

    Qin, Enwei; Yin, Song; Ji, Hua; Huang, Qian; Liu, Zekun; Wu, Shuhui

    2017-03-01

    To make cities more environmentally friendly, combustible wastes tend to be incinerated in waste-to-energy power plant boilers. However, release of chlorine gas (Cl2) during incineration causes serious problems related to hot corrosion of boiler tubes and poses a safety threat for such plants. In this study, a pseudo-de Laval nozzle was employed in a twin-wire arc spray system to enhance the velocity of in-flight particles. Highly dense NiCr-based coatings were obtained using the modified nozzle gun. The coating morphology was characterized by optical microscopy and scanning electron microscopy, and hot corrosion testing was carried out in a synthetic molten chloride salt environment. Results showed that the dense NiCr-based coatings exhibited high resistance against corrosion by chlorine, which can be related to the typical splat lamellar microstructure and chemical composition as well as minor alloying elements such as Ti and Mo.

  9. Hot Corrosion Behavior of Arc-Sprayed Highly Dense NiCr-Based Coatings in Chloride Salt Deposit

    NASA Astrophysics Data System (ADS)

    Qin, Enwei; Yin, Song; Ji, Hua; Huang, Qian; Liu, Zekun; Wu, Shuhui

    2017-04-01

    To make cities more environmentally friendly, combustible wastes tend to be incinerated in waste-to-energy power plant boilers. However, release of chlorine gas (Cl2) during incineration causes serious problems related to hot corrosion of boiler tubes and poses a safety threat for such plants. In this study, a pseudo-de Laval nozzle was employed in a twin-wire arc spray system to enhance the velocity of in-flight particles. Highly dense NiCr-based coatings were obtained using the modified nozzle gun. The coating morphology was characterized by optical microscopy and scanning electron microscopy, and hot corrosion testing was carried out in a synthetic molten chloride salt environment. Results showed that the dense NiCr-based coatings exhibited high resistance against corrosion by chlorine, which can be related to the typical splat lamellar microstructure and chemical composition as well as minor alloying elements such as Ti and Mo.

  10. Clean Firetube Boiler Waterside Heat Transfer Surfaces, Energy Tips: STEAM, Steam Tip Sheet #7 (Fact Sheet)

    SciTech Connect

    Not Available

    2012-04-01

    A steam energy tip sheet for the Advanced Manufacturing Office (AMO). The prevention of scale formation in firetube boilers can result in substantial energy savings. Scale deposits occur when calcium, magnesium, and silica, commonly found in most water supplies, react to form a continuous layer of material on the waterside of the boiler heat exchange tubes. Scale creates a problem because it typically possesses a thermal conductivity, an order of magnitude less than the corresponding value for bare steel. Even thin layers of scale serve as an effective insulator and retard heat transfer. The result is overheating of boiler tube metal, tube failures, and loss of energy efficiency. Fuel consumption may increase by up to 5% in firetube boilers because of scale. The boilers steam production may be reduced if the firing rate cannot be increased to compensate for the decrease in combustion efficiency. Energy losses as a function of scale thickness and composition are given. Any scale in a boiler is undesirable. The best way to deal with scale is not to let it form in the first place. Prevent scale formation by: (1) Pretreating of boiler makeup water (using water softeners, demineralizers, and reverse osmosis to remove scale-forming minerals); (2) Injecting chemicals into the boiler feedwater; and (3) Adopting proper boiler blowdown practices.

  11. Millwright Apprenticeship. Related Training Modules. 7.1-7.9 Boilers.

    ERIC Educational Resources Information Center

    Lane Community Coll., Eugene, OR.

    This packet, part of the instructional materials for the Oregon apprenticeship program for millwright training, contains nine modules covering boilers. The modules provide information on the following topics: fire and water tube types of boilers, construction, fittings, operation, cleaning, heat recovery systems, instruments and controls, and…

  12. 46 CFR 52.15-5 - Tube connections (modifies PWT-9 and PWT-11).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Tube connections (modifies PWT-9 and PWT-11). 52.15-5... BOILERS Requirements for Watertube Boilers § 52.15-5 Tube connections (modifies PWT-9 and PWT-11). (a) Tubes, pipe and nipples shall be attached to sheets, heads, headers, and fittings as indicated in...

  13. 46 CFR 52.15-5 - Tube connections (modifies PWT-9 and PWT-11).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 2 2012-10-01 2012-10-01 false Tube connections (modifies PWT-9 and PWT-11). 52.15-5... BOILERS Requirements for Watertube Boilers § 52.15-5 Tube connections (modifies PWT-9 and PWT-11). (a) Tubes, pipe and nipples shall be attached to sheets, heads, headers, and fittings as indicated in...

  14. 46 CFR 52.15-5 - Tube connections (modifies PWT-9 and PWT-11).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 2 2014-10-01 2014-10-01 false Tube connections (modifies PWT-9 and PWT-11). 52.15-5... BOILERS Requirements for Watertube Boilers § 52.15-5 Tube connections (modifies PWT-9 and PWT-11). (a) Tubes, pipe and nipples shall be attached to sheets, heads, headers, and fittings as indicated in...

  15. 46 CFR 52.15-5 - Tube connections (modifies PWT-9 and PWT-11).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 2 2011-10-01 2011-10-01 false Tube connections (modifies PWT-9 and PWT-11). 52.15-5... BOILERS Requirements for Watertube Boilers § 52.15-5 Tube connections (modifies PWT-9 and PWT-11). (a) Tubes, pipe and nipples shall be attached to sheets, heads, headers, and fittings as indicated in...

  16. 46 CFR 52.15-5 - Tube connections (modifies PWT-9 and PWT-11).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 2 2013-10-01 2013-10-01 false Tube connections (modifies PWT-9 and PWT-11). 52.15-5... BOILERS Requirements for Watertube Boilers § 52.15-5 Tube connections (modifies PWT-9 and PWT-11). (a) Tubes, pipe and nipples shall be attached to sheets, heads, headers, and fittings as indicated in...

  17. Guidelines on fossil boiler field welding

    SciTech Connect

    Stephenson, G.G. )

    1993-01-01

    Welding is a key maintenance activity in the repair and replacement of critical boiler pressure-part components. Unless trained welders use qualified procedures and documented practices, significant delays to outages may result from defective weld repairs, and future weld-related failures may cause costly outages. To address these issues, a comprehensive guideline on field-welding practices for fossil-fired boilers has been developed. It can assist utilities in establishing in-house welding programs. Welding practices used by utilities, boiler manufacturers, and repair organizations were critically reviewed and utilized in the preparation of a step-by-step guideline for repairs to, and replacement, of boiler tubes, headers, and drums. A set of Road Maps, and their accompanying written descriptions, guide the user through each step in every phase of the complete weld repair process. Additionally, the guideline discusses in detail: weld repair management, welder performance qualification and training, repair decision evaluation, defect removal and joint preparation, repair methods for thin and thick sections, welding procedure variables, materials and specifications, failure and root-cause analysis, inspection, and testing.

  18. Materials for the pulp and paper industry. Section 1: Development of materials for black liquor recovery boilers

    SciTech Connect

    Keiser, J.R.; Hubbard, C.R.; Payzant, E.A.

    1997-04-01

    Black liquor recovery boilers are essential components of kraft pulp and paper mills because they are a critical element of the system used to recover the pulping chemicals required in the kraft pulping process. In addition, the steam produced in these boilers is used to generate a significant portion of the electrical power used in the mill. Recovery boilers require the largest capital investment of any individual component of a paper mill, and these boilers are a major source of material problems in a mill. The walls and floors of these boilers are constructed of tube panels that circulate high pressure water. Molten salts (smelt) accumulate on the floor of recovery boilers, and leakage of water into the boiler can result in a violent explosion when the leaked water instantly vaporizes upon contacting the molten smelt. Because corrosion of the conventionally-used carbon steel tubing was found to be excessive in the lower section of recovery boilers, use of stainless steel/carbon steel co-extruded tubing was adopted for boiler walls to lessen corrosion and reduce the likelihood of smelt/water explosions. Eventually, this co-extruded or composite (as it is known in the industry) tubing was selected for use as a portion or all of the floor of recovery boilers, particularly those operating at pressures > 6.2 MPa (900 psi), because of the corrosion problems encountered in carbon steel floor tubes. Since neither the cause of the cracking nor an effective solution has been identified, this program was established to develop a thorough understanding of the degradation that occurs in the composite tubing used for walls and floors. This is being accomplished through a program that includes collection and review of technical reports, examination of unexposed and cracked tubes from boiler floors, computer modeling to predict residual stresses under operating conditions, and operation of laboratory tests to study corrosion, stress corrosion cracking, and thermal fatigue.

  19. Fluidized-bed boilers

    SciTech Connect

    Makansi, J.; Schwieger, B.

    1982-08-01

    Discusses atmospheric fluidized-bed (AFB) boilers with regard to designs available, manufacturers involved, and operating experience. Proven fuel flexibility and satisfactory SO/sub 2/ control without scrubbers make AFB boilers a viable option for industrial steam generation worldwide. Technical concepts on which AFB application is based are a departure from the more familiar methods of burning solid fuels. Behind US thrust for AFB development is the need to burn coal within pollution regulations.

  20. Oxide Dispersion Strengthened Iron Aluminide by CVD Coated Powders

    SciTech Connect

    Asit Biswas Andrew J. Sherman

    2006-09-25

    This I &I Category2 program developed chemical vapor deposition (CVD) of iron, aluminum and aluminum oxide coated iron powders and the availability of high temperature oxidation, corrosion and erosion resistant coating for future power generation equipment and can be used for retrofitting existing fossil-fired power plant equipment. This coating will provide enhanced life and performance of Coal-Fired Boilers components such as fire side corrosion on the outer diameter (OD) of the water wall and superheater tubing as well as on the inner diameter (ID) and OD of larger diameter headers. The program also developed a manufacturing route for readily available thermal spray powders for iron aluminide coating and fabrication of net shape component by powder metallurgy route using this CVD coated powders. This coating can also be applid on jet engine compressor blade and housing, industrial heat treating furnace fixtures, magnetic electronic parts, heating element, piping and tubing for fossil energy application and automotive application, chemical processing equipment , heat exchanger, and structural member of aircraft. The program also resulted in developing a new fabrication route of thermal spray coating and oxide dispersion strengthened (ODS) iron aluminide composites enabling more precise control over material microstructures.

  1. 4. INTERIOR, CENTRAL BOILER ROOM, LOWER LEVEL, BOILERS, FROM SOUTHWEST ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. INTERIOR, CENTRAL BOILER ROOM, LOWER LEVEL, BOILERS, FROM SOUTHWEST CORNER OF ROOM, LOOKING SOUTHEAST. - Oakland Naval Supply Center, Heating Plant, North of B Street & West of Third Street, Oakland, Alameda County, CA

  2. Interior view of boiler house looking south. Boiler units are ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Interior view of boiler house looking south. Boiler units are on left. - Burnsville Natural Gas Pumping Station, Saratoga Avenue between Little Kanawha River & C&O Railroad line, Burnsville, Braxton County, WV

  3. 42. BOILER HOUSE FOURTH FLOOR, FORCED DRAFT FANS ABOVE BOILERS ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    42. BOILER HOUSE FOURTH FLOOR, FORCED DRAFT FANS ABOVE BOILERS (SEE DRAWING Nos. 10 & 11 OF 13) - Delaware County Electric Company, Chester Station, Delaware River at South end of Ward Street, Chester, Delaware County, PA

  4. INTERIOR, SECOND LEVEL, SHOWING BOILERS. BOILER AT LEFT HAS REPLACED ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    INTERIOR, SECOND LEVEL, SHOWING BOILERS. BOILER AT LEFT HAS REPLACED BURNERS. CAMERA FACING NORTH. - New Haven Rail Yard, Central Steam Plant and Oil Storage, Vicinity of Union Avenue, New Haven, New Haven County, CT

  5. Metallurgical failures in fossil fired boilers

    SciTech Connect

    French, D.N.

    1983-01-01

    Forty case histories of boiler shut downs resulting from metallurgical failures are presented. Reasons for the failures are traced, and the fundamentals of elementary metallurgy are explained to help non-metallurgists understand these practical examples. The full range of expected tube failures is covered, including microstructural changes, high temperature and creep ruptures, corrosion caused by poor steam side chemistry, fuel ash corrosion, and weld problems. Cases that relate steam-side conditions with fireside oxidation, corrosion and creep failures are provided. The effects of misuse or thermal abuse are also presented. Finally, there is a discussion of boiler design in terms of how to avoid these problems, minimize service failures, and improve maintenance.

  6. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOEpatents

    Moore, Robert; Pickard, Paul S.; Parma, Jr., Edward J.; Vernon, Milton E.; Gelbard, Fred; Lenard, Roger X.

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  7. DETAIL OF BOILER, SHOWING (TOP TO BOTTOM) ENDS OF STEAM ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    DETAIL OF BOILER, SHOWING (TOP TO BOTTOM) ENDS OF STEAM CHAMBERS, DOORS GIVING ACCESS TO TUBING, AND SIX BURNERS, CAMERA FACING WEST. - New Haven Rail Yard, Central Steam Plant and Oil Storage, Vicinity of Union Avenue, New Haven, New Haven County, CT

  8. 1. EXTERIOR VIEW OF BOILER HOUSE FROM SOUTHWEST. THE BOILER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. EXTERIOR VIEW OF BOILER HOUSE FROM SOUTHWEST. THE BOILER HOUSE WAS USED FOR HEATING THE MILL; HYDRO-ELECTRIC POWER FOR PRODUCTION WAS PURCHASED FROM THE COLUMBUS LIGHT & POWER COMPANY. NORTH END OF 1924 MILL TO RIGHT, c. 1970 WINDOWLESS WEAVE ROOM ADDITION TO LEFT. - Stark Mill, Boiler House, 117 Corinth Road, Hogansville, Troup County, GA

  9. Super Boiler: First Generation, Ultra-High Efficiency Firetube Boiler

    SciTech Connect

    2006-06-01

    This factsheet describes a research project whose goal is to develop and demonstrate a first-generation ultra-high-efficiency, ultra-low emissions, compact gas-fired package boiler (Super Boiler), and formulate a long-range RD&D plan for advanced boiler technology out to the year 2020.

  10. Robotic weld overlay coatings for erosion control

    SciTech Connect

    Not Available

    1994-11-01

    The erosion of materials by the impact of solid particles has received increasing attention during the past twenty years. Recently, research has been initiated with the event of advanced coal conversion processes in which erosion plays an important role. The resulting damage, termed Solid Particle Erosion (SPE), is of concern primarily because of the significantly increased operating costs which result in material failures. Reduced power plant efficiency due to solid particle erosion of boiler tubes and waterfalls has led to various methods to combat SPE. One method is to apply coatings to the components subjected to erosive environments. Protective weld overlay coatings are particularly advantageous in terms of coating quality. The weld overlay coatings are essentially immune to spallation due to a strong metallurgical bond with the substrate material. By using powder mixtures, multiple alloys can be mixed in order to achieve the best performance in an erosive environment. However, a review of the literature revealed a lack of information on weld overlay coating performance in erosive environments which makes the selection of weld overlay alloys a difficult task. The objective of this project is to determine the effects of weld overlay coating composition and microstructure on erosion resistance. These results will lead to a better understanding of erosion mitigation in CFB`s.

  11. Robotic weld overlay coatings for erosion control

    NASA Astrophysics Data System (ADS)

    The erosion of materials by the impact of solid particles has received increasing attention during the past twenty years. Recently, research has been initiated with the event of advanced coal conversion processes in which erosion plays an important role. The resulting damage, termed Solid Particle Erosion (SPE), is of concern primarily because of the significantly increased operating costs which result in material failures. Reduced power plant efficiency due to solid particle erosion of boiler tubes and waterfalls has led to various methods to combat SPE. One method is to apply coatings to the components subjected to erosive environments. Protective weld overlay coatings are particularly advantageous in terms of coating quality. The weld overlay coatings are essentially immune to spallation due to a strong metallurgical bond with the substrate material. By using powder mixtures, multiple alloys can be mixed in order to achieve the best performance in an erosive environment. However, a review of the literature revealed a lack of information on weld overlay coating performance in erosive environments which makes the selection of weld overlay alloys a difficult task. The objective of this project is to determine the effects of weld overlay coating composition and microstructure on erosion resistance. These results will lead to a better understanding of erosion mitigation in CFB's.

  12. 11. RW Meyer Sugar Mill: 18761889. Locomotive=type, firetube, portable boiler, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    11. RW Meyer Sugar Mill: 1876-1889. Locomotive=type, fire-tube, portable boiler, model No. 1, Manufactured by Ames Iron Works, Oswego, New York, 1879. 120 lbs./sq. in. working pressure, 66 sq. ft. heating surface in tubes. View: the boiler provided steam for steam engine which in turn powered the centrifugals. View shows front fire box, end of boiler. Below fire-box,used for removing ashes, is a door. Circular openings at the rear of the fire-box are where fire-tubes connected with furnace. Column to right of fire-box carried pressure and water level gauges. Fluted chimney-type structure is steam-port, safety valve, and whistle. Weights originally sat on the arm extending from the top of the port and controlled the boiler pressure. - R. W. Meyer Sugar Mill, State Route 47, Kualapuu, Maui County, HI

  13. High Temperature Mechanical Properties of Free-Standing HVOF CoNiCrAlY Coatings by Lateral Compression of Circular Tube

    NASA Astrophysics Data System (ADS)

    Waki, Hiroyuki; Nakamura, Kyousuke; Yamaguchi, Itsuki; Kobayashi, Akira

    MCrAlY, M means Co and/or Ni, sprayed coating is used to protect a super alloy substrate from corrosion or oxidation in a gas turbine blade. However, the mechanical properties are not well-known, because there are few proper measurement methods for a thin coating at high temperature. Authors have developed the new easy method to measure the mechanical properties using the lateral compression of a circular tube. The method is useful to apply to a thin coating because it does not need chucking and manufacturing a test piece is very easy. The method is also easily applicable to high temperature measurement. In this study, high temperature mechanical properties, Young's modulus, bending strength and fracture strain, of CoNiCrAlY coatings by HVOF were systematically measured. The results obtained were as follows: Young's modulus and bending strength suddenly decreased beyond 400˜450°C. The Young's modulus and bending strength thermally treated at higher than 1050°C was significantly higher than that of virgin CoNiCrAlY coating. It was found that higher thermal treatment in atmosphere was the most effective in increasing the Young's modulus and bending strength. It was also found that the improvement of Young's modulus was primarily caused by not the effect of TGO but the sintering and diffusion of unfused particles. On the contrary, the fracture strain increased beyond 400°C differently from the bending strength. The fracture strains of CoNiCrAlY thermally treated in vacuum were higher than those of CoNiCrAlY treated in atmosphere. It was found that higher thermal treatment in vacuum was the most effective in increasing the fracture strain.

  14. In situ hydrothermal growth of polyaniline coating for in-tube solid-phase microextraction towards ultraviolet filters in environmental water samples.

    PubMed

    Bu, Yanan; Feng, Juanjuan; Wang, Xiuqin; Tian, Yu; Sun, Min; Luo, Chuannan

    2017-02-03

    A facile, low cost, sensitive and environmentally friendly polyaniline (PANI) coating was prepared onto the basalt fibers (BFs) by in situ hydrothermal growth method. PANI functionalized BFs were placed into a poly(ether ether ketone) (PEEK) tube as a fibers-in-tube solid-phase microextraction (SPME) device. The extraction and analysis processes were carried out by connecting it to high performance liquid chromatography (HPLC). Three ultraviolet filters including 2-hydroxy-4-methoxybenzophenone, phenyl salicylate and 2,4-dihydroxybenzophenone were employed as model analytes. Under the optimal extraction and desorption conditions, online in-tube SPME-HPLC analysis method was established and afforded satisfactory enrichment factors (1323-1555), wide linear ranges (0.06-100μgL(-1)) with correlation coefficients ranging from 0.9995 to 0.9999, low limits of detection (0.02-0.05μgL(-1)) and acceptable extraction repeatability (RSD<7.8%, n=6) and preparation repeatability (RSD<9.7%, n=3). The proposed method was successfully applied to the determination of the three ultraviolet filters in two environmental water samples. Copyright © 2016 Elsevier B.V. All rights reserved.

  15. Production of carbon nano-tubes via CCVD method and their corrosion protection performance in epoxy based coatings

    NASA Astrophysics Data System (ADS)

    Raza, M. A.; Ghauri, F. A.; Awan, M. S.; Farooq, A.; Ahmad, R.

    2016-08-01

    Good yield of carbon products was obtained by catalytic chemical vapor deposition (CCVD) technique using 100-500mg of ferrocene catalyst at temperature of 900 °C and acetylene flow rate of 150-200cc/min. The effects of amount of ferrocene, temperature and hydrocarbons precursors on the yield of carbon nanomaterial's was calculated and characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) andenergy- dispersive X-ray spectroscopy (EDS). Good yield of carbon nanomaterials primarily consisted of carbon nanotubes (CNTs) and carbon nanoparticles was obtained. CNTs obtained after purification were dispersed in epoxy resin to produce composite coatings which were coated on stainless steel 316L. The coated stainless steel samples’ corrosion behavior was studied using open circuit potential (OCP), cyclic polarization and electrochemical impedance spectroscopy (EIS) techniques. Results showed that epoxy coating containing 4 wt. % of CNTs offered improved corrosion resistance to stainless steel.

  16. Workshop proceedings: U-bend tube cracking in steam generators

    NASA Astrophysics Data System (ADS)

    Shoemaker, C. E.

    1981-06-01

    A design to reduce the rate of tube failure in high pressure feedwater heaters, a number of failed drawn and stress relieved Monel 400 U-bend tubes removed from three high pressure feedwater heaters was examined. Steam extracted from the turbine is used to preheat the boiler feedwater in fossil fuel fired steam plants to improve thermal efficiency. This is accomplished in a series of heaters between the condenser hot well and the boiler. The heaters closest to the boiler handle water at high pressure and temperature. Because of the severe service conditions, high pressure feedwater heaters are frequently tubed with drawn and stress relieved Monel 400.

  17. In-bed tube bank for a fluidized-bed combustor

    DOEpatents

    Hemenway, Jr., Lloyd F.

    1990-01-01

    An in-bed tube bank (10) for a fluidized bed combustor. The tube bank (10) of the present invention comprises one or more fluid communicating boiler tubes (30) which define a plurality of selectively spaced boiler tube sections (32). The tube sections (32) are substantially parallel to one another and aligned in a common plane. The tube bank (10) further comprises support members (34) for joining adjacent tube sections (32), the support members (34) engaging and extending along a selected length of the tube sections (32) and spanning the preselected space therebetween.

  18. Fluidized-bed boilers

    SciTech Connect

    Makansi, J.; Schwieger, B.

    1982-08-01

    This report reviews the current state of atmospheric fluidized-bed combustion. The fundamentals of fluidized-bed combustion and design considerations are first discussed. Tables provide details of manufacturers, worldwide, and of the boilers now installed. Eight plants in various countries and burning a variety of fuels, are described more fully.

  19. Optimising boiler performance.

    PubMed

    Mayoh, Paul

    2009-01-01

    Soaring fuel costs continue to put the squeeze on already tight health service budgets. Yet it is estimated that combining established good practice with improved technologies could save between 10% and 30% of fuel costs for boilers. Paul Mayoh, UK technical manager at Spirax Sarco, examines some of the practical measures that healthcare organisations can take to gain their share of these potential savings.

  20. Computer method for identification of boiler transfer functions

    NASA Technical Reports Server (NTRS)

    Miles, J. H.

    1971-01-01

    An iterative computer method is described for identifying boiler transfer functions using frequency response data. An objective penalized performance measure and a nonlinear minimization technique are used to cause the locus of points generated by a transfer function to resemble the locus of points obtained from frequency response measurements. Different transfer functions can be tried until a satisfactory empirical transfer function to the system is found. To illustrate the method, some examples and some results from a study of a set of data consisting of measurements of the inlet impedance of a single tube forced flow boiler with inserts are given.

  1. Preparing hydroxyapatite-silicon composite suspensions with homogeneous distribution of multi-walled carbon nano-tubes for electrophoretic coating of NiTi bone implant and their effect on the surface morphology

    NASA Astrophysics Data System (ADS)

    Khalili, Vida; Khalil-Allafi, Jafar; Xia, Wei; Parsa, Alireza B.; Frenzel, Jan; Somsen, Christoph; Eggeler, Gunther

    2016-03-01

    Preparing a stable suspension is a main step towards the electrophoretically depositing of homogeneous and dense composite coatings on NiTi for its biomedical application. In the present study, different composite suspensions of hydroxyapatite, silicon and multi-walled carbon nano-tubes were prepared using n-butanol and triethanolamine as media and dispersing agent, respectively. Multi-walled carbon nanotubes were first functionalized in the nitric acid vapor for 15 h at 175 °C, and then mixed into suspensions. Thermal desorption spectroscopy profiles indicate the formation of functional groups on multi-walled carbon nano-tubes. An excellent suspension stability can be achieved for different amounts of triethanolamine. The amount of triethanolamine can be increased by adding a second component to a stable hydroxyapatite suspension due to an electrostatic interaction between components in suspension. The stability of composite suspension is less than that of the hydroxyapatite suspension, due to density differences, which under the gravitational force promote the demixing. The scanning electron microscopy images of the coatings surface show that more dense coatings are developed on NiTi substrate using electrophoretic deposition and sintering at 850 °C in the simultaneous presence of silicon and multi-walled carbon nanotubes in the hydroxyapatite coatings. The atomic force microscopy results of the coatings surface represent that composite coatings of hydroxyapatite-20 wt.% silicon and hydroxyapatite-20 wt.% silicon-1 wt.% multi-walled carbon nano-tubes with low zeta potential have rougher surfaces.

  2. DLC coating of interior surfaces of steel tubes by low energy plasma source ion implantation and deposition

    NASA Astrophysics Data System (ADS)

    Baba, K.; Hatada, R.; Flege, S.; Ensinger, W.

    2014-08-01

    The plasma source ion implantation (PSII) process can be used for the treatment of the interior surfaces of tubes. Typically, this is done with higher ion energies of 10 keV or more. The resulting film thickness and the properties of the DLC film usually show a dependence on position, i.e. the distance from the edge of the tube. In order to investigate whether this effect is also present with lower energies (and if so, to what extent), deposition was carried out at negative pulse voltages of -5 kV. A diamond-like carbon (DLC) film was deposited by using acetylene as the plasma gas. The substrate consisted of stainless steel tubes with an inner diameter of 20 mm and a length of 100 and 200 mm, respectively. The distribution of the thickness, film composition, structure, surface morphology and friction coefficient as a function of the position inside the tube were investigated. The results of this low energy treatment were compared with investigations which employed higher ion energies.

  3. Development of Self-Powered Wireless-Ready High Temperature Electrochemical Sensors for In-Situ Corrosion Monitoring for Boiler Tubes in Next Generation Coal-based Power Systems

    SciTech Connect

    Liu, Xingbo

    2015-06-30

    The key innovation of this project is the synergy of the high temperature sensor technology based on the science of electrochemical measurement and state-of-the-art wireless communication technology. A novel self-powered wireless high temperature electrochemical sensor system has been developed for coal-fired boilers used for power generation. An initial prototype of the in-situ sensor demonstrated the capability of the wireless communication system in the laboratory and in a pilot plant (Industrial USC Boiler Setting) environment to acquire electrochemical potential and current signals during the corrosion process. Uniform and localized under-coal ash deposit corrosion behavior of Inconel 740 superalloy has been studied at different simulated coal ash hot corrosion environments using the developed sensor. Two typical potential noise patterns were found to correlate with the oxidation and sulfidation stages in the hot coal ash corrosion process. Two characteristic current noise patterns indicate the extent of the corrosion. There was a good correlation between the responses of electrochemical test data and the results from corroded surface analysis. Wireless electrochemical potential and current noise signals from a simulated coal ash hot corrosion process were concurrently transmitted and recorded. The results from the performance evaluation of the sensor confirm a high accuracy in the thermodynamic and kinetic response represented by the electrochemical noise and impedance test data.

  4. Study of the HVOF Ni-Based Coatings' Corrosion Resistance Applied on Municipal Solid-Waste Incinerators

    NASA Astrophysics Data System (ADS)

    Guilemany, J. M.; Torrell, M.; Miguel, J. R.

    2008-06-01

    Oxidation of exchanger steel tubes causes important problems in Municipal Solid-Waste Incinerator (MSWI) plants. The present paper shows a possible solution for this problem through High-Velocity Oxygen Fuel (HVOF) thermal spray coatings. A comparative study was carried out between powder and wire Ni-based thermal spray coatings (with the same composition). These optimized coatings were compared based on their microstructure, wear properties (ASTM G99-90, ASTM G65-91), and erosion-corrosion (E-C) resistance. An E-C test designed in the Thermal Spray Centre was performed to reproduce the mechanisms that take place in a boiler. Studying the results of this test, the wire HVT Inconel coating sprayed by propylene appears to be the best alternative. A commercial bulk material with a composition similar to Ni-based coatings was tested to find the products of the oxidation reactions. The protective mechanisms of these materials were assessed after studying the results obtained for HVOF coatings and the bulk material where the presence of nickel and chromium oxides as a corrosion product can be seen. Kinetic evolution of the Ni-based coatings can be studied by thermogravimetric analysis. The protection that Inconel coatings give to the tube through the difference of the gain mass can be seen. Ni-based HVOF coatings by both spray conditions are a promising alternative to MSWI protection against chlorine environments, and their structures have a very important role.

  5. Demonstration of coal reburning for cyclone boiler NO{sub x} control. Appendix, Book 1

    SciTech Connect

    Not Available

    1994-06-01

    Based on the industry need for a pilot-scale cyclone boiler simulator, Babcock Wilcox (B&W) designed, fabricated, and installed such a facility at its Alliance Research Center (ARC) in 1985. The project involved conversion of an existing pulverized coal-fired facility to be cyclone-firing capable. Additionally, convective section tube banks were installed in the upper furnace in order to simulate a typical boiler convection pass. The small boiler simulator (SBS) is designed to simulate most fireside aspects of full-size utility boilers such as combustion and flue gas emissions characteristics, fireside deposition, etc. Prior to the design of the pilot-scale cyclone boiler simulator, the various cyclone boiler types were reviewed in order to identify the inherent cyclone boiler design characteristics which are applicable to the majority of these boilers. The cyclone boiler characteristics that were reviewed include NO{sub x} emissions, furnace exit gas temperature (FEGT) carbon loss, and total furnace residence time. Previous pilot-scale cyclone-fired furnace experience identified the following concerns: (1) Operability of a small cyclone furnace (e.g., continuous slag tapping capability). (2) The optimum cyclone(s) configuration for the pilot-scale unit. (3) Compatibility of NO{sub x} levels, carbon burnout, cyclone ash carryover to the convection pass, cyclone temperature, furnace residence time, and FEGT.

  6. Antimicrobial activity of silica coated silicon nano-tubes (SCSNT) and silica coated silicon nano-particles (SCSNP) synthesized by gas phase condensation.

    PubMed

    Tank, Chiti; Raman, Sujatha; Karan, Sujoy; Gosavi, Suresh; Lalla, Niranjan P; Sathe, Vasant; Berndt, Richard; Gade, W N; Bhoraskar, S V; Mathe, Vikas L

    2013-06-01

    Silica-coated, silicon nanotubes (SCSNTs) and silica-coated, silicon nanoparticles (SCSNPs) have been synthesized by catalyst-free single-step gas phase condensation using the arc plasma process. Transmission electron microscopy and scanning tunneling microscopy showed that SCSNTs exhibited a wall thickness of less than 1 nm, with an average diameter of 14 nm and a length of several 100 nm. Both nano-structures had a high specific surface area. The present study has demonstrated cheaper, resistance-free and effective antibacterial activity in silica-coated silicon nano-structures, each for two Gram-positive and Gram-negative bacteria. The minimum inhibitory concentration (MIC) was estimated, using the optical densitometric technique, and by determining colony-forming units. The MIC was found to range in the order of micrograms, which is comparable to the reported MIC of metal oxides for these bacteria. SCSNTs were found to be more effective in limiting the growth of multidrug-resistant Staphylococcus aureus over SCSNPs at 10 μg/ml (IC 50 = 100 μg/ml).

  7. Design of Boiler Welding for Improvement of Lifetime and Cost Control

    PubMed Central

    Thong-On, Atcharawadi; Boonruang, Chatdanai

    2016-01-01

    Fe-2.25Cr-1Mo a widely used material for headers and steam tubes of boilers. Welding of steam tube to header is required for production of boiler. Heat affected zone of the weld can have poor mechanical properties and poor corrosion behavior leading to weld failure. The cost of material used for steam tube and header of boiler should be controlled. This study propose a new materials design for boiler welding to improve the lifetime and cost control, using tungsten inert gas (TIG) welding of Fe-2.25Cr-1Mo tube to carbon steel pipe with chromium-containing filler. The cost of production could be reduced by the use of low cost material such as carbon steel pipe for boiler header. The effect of chromium content on corrosion behavior of the weld was greater than that of the microstructure. The lifetime of the welded boiler can be increased by improvement of mechanical properties and corrosion behavior of the heat affected zone. PMID:28774014

  8. Design of Boiler Welding for Improvement of Lifetime and Cost Control.

    PubMed

    Thong-On, Atcharawadi; Boonruang, Chatdanai

    2016-11-03

    Fe-2.25Cr-1Mo a widely used material for headers and steam tubes of boilers. Welding of steam tube to header is required for production of boiler. Heat affected zone of the weld can have poor mechanical properties and poor corrosion behavior leading to weld failure. The cost of material used for steam tube and header of boiler should be controlled. This study propose a new materials design for boiler welding to improve the lifetime and cost control, using tungsten inert gas (TIG) welding of Fe-2.25Cr-1Mo tube to carbon steel pipe with chromium-containing filler. The cost of production could be reduced by the use of low cost material such as carbon steel pipe for boiler header. The effect of chromium content on corrosion behavior of the weld was greater than that of the microstructure. The lifetime of the welded boiler can be increased by improvement of mechanical properties and corrosion behavior of the heat affected zone.

  9. View north of tube bending shop in boilermakers department located ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View north of tube bending shop in boilermakers department located in southeast corner of the structural shop building (building 57). The computer controlled tube bender can be programmed to bend boiler tubing to nearly any required configuration - Naval Base Philadelphia-Philadelphia Naval Shipyard, Structure Shop, League Island, Philadelphia, Philadelphia County, PA

  10. 36. (Credit JTL) Detail of rear of Heine water tube ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    36. (Credit JTL) Detail of rear of Heine water tube boiler showing steam drum inspection manhole and blow-down valve. Note inspection plugs for water tubes in tube header below drum. - McNeil Street Pumping Station, McNeil Street & Cross Bayou, Shreveport, Caddo Parish, LA

  11. Structure and Performance of a 600MWe Supercritical CFB Boiler with Water Cooled Panels

    NASA Astrophysics Data System (ADS)

    Li, Y.; Nie, L.; Hu, X. K.; Yue, G. X.; Li, W. K.; We, Y. X.; Lu, J. F.; Che, D. F.

    The circulating fluidized bed (CFB) combustion technology is one of the approved clean combustion technologies, and the power supply efficiency can be improved combining with the supercritical technology. A 600MWe supercritical CFB boiler is introduced in this paper. This boiler is designed based on the success of 300 MWe CFB boilers, which has a single furnace with three cyclones without external heat exchangers. There are twin furnaces and twin air distributors in the boiler. The water walls of the twin furnace above dense bed combines to a common fence wall with some channels to balance the pressure of the two furnaces. The smooth tubes are adopted in membrane water wall with mixing header. Six cyclones are located beside the furnace as well as six loopseals and six external heat exchangers. The hydrodynamic characteristic of water wall is available with the modeling prediction. And the performance of the 600MWe supercritical CFB boiler is also investigated.

  12. Successful experience with limestone and other sorbents for combustion of biomass in fluid bed power boilers

    SciTech Connect

    Coe, D.R.

    1993-12-31

    This paper presents the theoretical and practical advantages of utilizing limestone and other sorbents during the combustion of various biomass fuels for the reduction of corrosion and erosion of boiler fireside tubing and refractory. Successful experiences using a small amount of limestone, dolomite, kaolin, or custom blends of aluminum and magnesium compounds in fluid bed boilers fired with biomass fuels will be discussed. Electric power boiler firing experience includes bubbling bed boilers as well as circulating fluid bed boilers in commercial service on biomass fuels. Forest sources of biomass fuels fired include wood chips, brush chips, sawmill waste wood, bark, and hog fuel. Agricultural sources of biomass fuels fired include grape vine prunings, bean straw, almond tree chips, walnut tree chips, and a variety of other agricultural waste fuels. Additionally, some urban sources of wood fuels have been commercially burned with the addition of limestone. Data presented includes qualitative and quantitative analyses of fuel, sorbent, and ash.

  13. Characterization and High-Temperature Erosion Behaviour of HVOF Thermal Spray Cermet Coatings

    NASA Astrophysics Data System (ADS)

    Kumar, Pardeep; Sidhu, Buta Singh

    2016-01-01

    High-velocity oxygen fuel (HVOF) thermal spray, carbide-cermet-based coatings are usually employed in high-temperature erosive and erosive-corrosive environments. Extensive literature is available on high-temperature erosion performance of HVOF coatings under moderate to low particle flux and velocities for application in boiler tubes. This research work presents the characterization and high-temperature erosion behaviour of Cr3C2-25NiCr and WC-10Co-4Cr HVOF-sprayed coatings. Coatings were formulated on the substrate steel of type AISI 304, commonly used for the fabrication of pulverized coal burner nozzles (PCBN). Erosion testing was carried out in high-temperature air-jet erosion tester after simulating the conditions akin to that prevailing in PCBN in the boiler furnace. The coatings were tested for erosion behaviour at different angles and temperatures by freezing other test parameters. Brittle erosion behaviour was depicted in erosion testing, and the coatings couldn't restrain the erodent attacks to protect the substrate. High particle velocity and high particle flux were attributed to be the reasons of extensive erosive weight loss of the coatings. The surface morphology of the eroded specimens was analysed from back-scattered electron images to depict the probable mechanism of material removal. The coatings were characterized with optical microscopy, SEM-EDS analysis, XRD analysis, micro-hardness testing, porosity measurements, surface roughness testing and bond strength testing. The work was undertaken to investigate the performance of the selected coatings in highly erosive environment, so as to envisage their application in PCBNs for protection against material degradation. The coatings could only sustain in oblique impact erosion at room temperature and depleted fully under all other conditions.

  14. Boiler modeling optimizes sootblowing

    SciTech Connect

    Piboontum, S.J.; Swift, S.M.; Conrad, R.S.

    2005-10-01

    Controlling the cleanliness and limiting the fouling and slagging of heat transfer surfaces are absolutely necessary to optimize boiler performance. The traditional way to clean heat-transfer surfaces is by sootblowing using air, steam, or water at regular intervals. But with the advent of fuel-switching strategies, such as switching to PRB coal to reduce a plant's emissions, the control of heating surface cleanliness has become more problematic for many owners of steam generators. Boiler modeling can help solve that problem. The article describes Babcock & Wilcox's Powerclean modeling system which consists of heating surface models that produce real-time cleanliness indexes. The Heat Transfer Manager (HTM) program is the core of the system, which can be used on any make or model of boiler. A case study is described to show how the system was successfully used at the 1,350 MW Unit 2 of the American Electric Power's Rockport Power Plant in Indiana. The unit fires a blend of eastern bituminous and Powder River Basin coal. 5 figs.

  15. Making Internal Molds Of Long, Curved Tubes

    NASA Technical Reports Server (NTRS)

    Burley, Richard K.

    1989-01-01

    Mold material carried to internal weld joint and removed after impression taken. Remotely operated device makes impression mold of interior surface of tube at weld joint. Mold provides indication of extent of mismatch between members at joint. Maneuvered to weld inspected through curved tube 3 in. in diameter by 50 in. long. Readily adapted to making molds to measure depth of corrosion in boiler tubes or other pipes.

  16. Making Internal Molds Of Long, Curved Tubes

    NASA Technical Reports Server (NTRS)

    Burley, Richard K.

    1989-01-01

    Mold material carried to internal weld joint and removed after impression taken. Remotely operated device makes impression mold of interior surface of tube at weld joint. Mold provides indication of extent of mismatch between members at joint. Maneuvered to weld inspected through curved tube 3 in. in diameter by 50 in. long. Readily adapted to making molds to measure depth of corrosion in boiler tubes or other pipes.

  17. Lead determination at ng/mL level by flame atomic absorption spectrometry using a tantalum coated slotted quartz tube atom trap.

    PubMed

    Demirtaş, İlknur; Bakırdere, Sezgin; Ataman, O Yavuz

    2015-06-01

    Flame atomic absorption spectrometry (FAAS) still keeps its importance despite the relatively low sensitivity; because it is a simple and economical technique for determination of metals. In recent years, atom traps have been developed to increase the sensitivity of FAAS. Although the detection limit of FAAS is only at the level of µg/mL, with the use of atom traps it can reach to ng/mL. Slotted quartz tube (SQT) is one of the atom traps used to improve sensitivity. In atom trapping mode of SQT, analyte is trapped on-line in SQT for few minutes using ordinary sample aspiration, followed by the introduction of a small volume of organic solvent to effect the revolatilization and atomization of analyte species resulting in a transient signal. This system is economical, commercially available and easy to use. In this study, a sensitive analytical method was developed for the determination of lead with the help of SQT atom trapping flame atomization (SQT-AT-FAAS). 574 Fold sensitivity enhancement was obtained at a sample suction rate of 3.9 mL/min for 5.0 min trapping period with respect to FAAS. Organic solvent was selected as 40 µL of methyl isobutyl ketone (MIBK). To obtain a further sensitivity enhancement inner surface of SQT was coated with several transition metals. The best sensitivity enhancement, 1650 fold enhancement, was obtained by the Ta-coated SQT-AT-FAAS. In addition, chemical nature of Pb species trapped on quartz and Ta surface, and the chemical nature of Ta on quartz surface were investigated by X-ray photoelectron spectroscopy (XPS) and Raman Spectroscopy. Raman spectrometric results indicate that tantalum is coated on SQT surface in the form of Ta2O5. XPS studies revealed that the oxidation state of Pb in species trapped on both bare and Ta coated SQT surfaces is +2. For the accuracy check, the analyses of standard reference material were performed by use of SCP SCIENCE EnviroMAT Low (EU-L-2) and results for Pb were to be in good agreement with

  18. Super Boiler 2nd Generation Technology for Watertube Boilers

    SciTech Connect

    Mr. David Cygan; Dr. Joseph Rabovitser

    2012-03-31

    This report describes Phase I of a proposed two phase project to develop and demonstrate an advanced industrial watertube boiler system with the capability of reaching 94% (HHV) fuel-to-steam efficiency and emissions below 2 ppmv NOx, 2 ppmv CO, and 1 ppmv VOC on natural gas fuel. The boiler design would have the capability to produce >1500 F, >1500 psig superheated steam, burn multiple fuels, and will be 50% smaller/lighter than currently available watertube boilers of similar capacity. This project is built upon the successful Super Boiler project at GTI. In that project that employed a unique two-staged intercooled combustion system and an innovative heat recovery system to reduce NOx to below 5 ppmv and demonstrated fuel-to-steam efficiency of 94% (HHV). This project was carried out under the leadership of GTI with project partners Cleaver-Brooks, Inc., Nebraska Boiler, a Division of Cleaver-Brooks, and Media and Process Technology Inc., and project advisors Georgia Institute of Technology, Alstom Power Inc., Pacific Northwest National Laboratory and Oak Ridge National Laboratory. Phase I of efforts focused on developing 2nd generation boiler concepts and performance modeling; incorporating multi-fuel (natural gas and oil) capabilities; assessing heat recovery, heat transfer and steam superheating approaches; and developing the overall conceptual engineering boiler design. Based on our analysis, the 2nd generation Industrial Watertube Boiler when developed and commercialized, could potentially save 265 trillion Btu and $1.6 billion in fuel costs across U.S. industry through increased efficiency. Its ultra-clean combustion could eliminate 57,000 tons of NOx, 460,000 tons of CO, and 8.8 million tons of CO2 annually from the atmosphere. Reduction in boiler size will bring cost-effective package boilers into a size range previously dominated by more expensive field-erected boilers, benefiting manufacturers and end users through lower capital costs.

  19. New technique of the local heat flux measurement in combustion chambers of steam boilers

    NASA Astrophysics Data System (ADS)

    Taler, Jan; Taler, Dawid; Sobota, Tomasz; Dzierwa, Piotr

    2011-12-01

    A new method for measurement of local heat flux to water-walls of steam boilers was developed. A flux meter tube was made from an eccentric tube of short length to which two longitudinal fins were attached. These two fins prevent the boiler setting from heating by a thermal radiation from the combustion chamber. The fins are not welded to the adjacent water-wall tubes, so that the temperature distribution in the heat flux meter is not influenced by neighbouring water-wall tubes. The thickness of the heat flux tube wall is larger on the fireside to obtain a greater distance between the thermocouples located inside the wall which increases the accuracy of heat flux determination. Based on the temperature measurements at selected points inside the heat flux meter, the heat flux absorbed by the water-wall, heat transfer coefficient on the inner tube surface and temperature of the water-steam mixture was determined.

  20. Interior view of boiler house looking north. Boiler units are ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Interior view of boiler house looking north. Boiler units are on right. HAER Engineer/Historian Donald C. Jackson on right is interviewing Garry Dobbins concerning operation of the facility. - Burnsville Natural Gas Pumping Station, Saratoga Avenue between Little Kanawha River & C&O Railroad line, Burnsville, Braxton County, WV

  1. Small boiler uses waste coal

    SciTech Connect

    Virr, M.J.

    2009-07-15

    Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

  2. Task 2: Materials for Advanced Boiler and Oxy-combustion Systems

    SciTech Connect

    Holcolm, Gordon R.; McGhee, Barry

    2009-05-01

    The PowerPoint presentation provides an overview of the tasks for the project: Characterize advanced boiler (oxy-fuel combustion, biomass co-fired) gas compositions and ash deposits; Generate critical data on the effects of environmental conditions; develop a unified test method with a view to future standardization; Generate critical data for coating systems for use in advanced boiler systems; Generate critical data for flue gas recycle piping materials for oxy-fuel systems; and, Compile materials performance data from laboratory and pilot plant exposures of candidate alloys for use in advanced boiler systems.

  3. Research on the Hydraulic Characteristics of a 600MW Supercritical Pressure CFB Boiler

    NASA Astrophysics Data System (ADS)

    Yang, D.; Pan, J.; Bi, Q. C.; Zhang, Y. J.; Jian, X. G.; Yu, L.

    Water wall design is a key technology of supercritical pressure CFB boiler. On account of the low heat flux and its homogeneous distribution in furnace, internally ribbed tubes with low mass flux and smooth tubes with moderate mass flux can be applied in the water wall of supercritical CFB boilers. An experimental research on the flow and heat transfer characteristics of internally ribbed tubes and smooth tubes with different inner diameters was conducted in the range of sub-critical and supercritical pressure. The departure from nucleate boiling (DNB) and dry-out boundary and the empirical correlations of heat transfer are obtained from the experiments. The mathematical model for predicting the circuit mass flux and grid pressure of a flow network system is based on the mass and momentum conservation equations and an iterative method is used to solve the nonlinear equations. Harbin Boiler Works has developed a 600MW supercritical CFB boiler with external heat exchangers and 6 separators. The mass flux and metal temperature distribution of water wall in the CFB boiler are calculated and the results show that the water wall can operate safely at BMCR and 75%BMCR load.

  4. Design and research of retrofitting PC boiler into CFB boiler

    SciTech Connect

    Chen, H.P.; Lu, J.D.; Huang, L.; Liu, H.; Lin, Z.; Liu, D.C.

    1997-12-31

    In China, there are a large number of aged pulverized coal (PC) boilers at aging utility power plants. Many of them are beyond their reasonable working life or in a condition of unreliable operation, low combustion efficiency, and serious air pollution. It is very important and urgent to retrofit the aged PC boilers, and repower the aging utility power plants in China. Circulating fluidized bed (CFB) boilers have been developed rapidly, and paid great attention to in China. There are many striking advantages to retrofit an aged boiler with a CFB boiler. The retrofitting is suitable to meet the needs of effective utilization of low-grade coal, reducing SO{sub 2} and NO{sub x} emissions and repowering an aging power plant. The cost is much lower than that of building a new CFB unit. The National Laboratory of Coal Combustion (NLCC) has always paid great attention to studying and developing CFB combustion technology in connection with Chinese national conditions, and has evolved distinguishing technology features of its own. This paper introduces a new design concept of retrofitting PC boiler into Pi ({Pi}-shaped) CFB boiler with downward exhaust cyclone, and relevant research work and results of design and calculation.

  5. Carbon granule probe microphone for leak detection. [recovery boilers

    NASA Technical Reports Server (NTRS)

    Parthasarathy, S. P. (Inventor)

    1985-01-01

    A microphone which is not subject to corrosion is provided by employing carbon granules to sense sound waves. The granules are packed into a ceramic tube and no diaphragm is used. A pair of electrodes is located in the tube adjacent the carbon granules and are coupled to a sensing circuit. Sound waves cause pressure changes on the carbon granules which results in a change in resistance in the electrical path between the electrodes. This change in resistance is detected by the sensing circuit. The microphone is suitable for use as a leak detection probe in recovery boilers, where it provides reliable operation without corrosion problems associated with conventional microphones.

  6. High-Temperature Graphitization Failure of Primary Superheater Tube

    NASA Astrophysics Data System (ADS)

    Ghosh, D.; Ray, S.; Roy, H.; Mandal, N.; Shukla, A. K.

    2015-12-01

    Failure of boiler tubes is the main cause of unit outages of the plant, which further affects the reliability, availability and safety of the unit. So failure analysis of boiler tubes is absolutely essential to predict the root cause of the failure and the steps are taken for future remedial action to prevent the failure in near future. This paper investigates the probable cause/causes of failure of the primary superheater tube in a thermal power plant boiler. Visual inspection, dimensional measurement, chemical analysis, metallographic examination and hardness measurement are conducted as the part of the investigative studies. Apart from these tests, mechanical testing and fractographic analysis are also conducted as supplements. Finally, it is concluded that the superheater tube is failed due to graphitization for prolonged exposure of the tube at higher temperature.

  7. 30 CFR 56.13030 - Boilers.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Boilers. 56.13030 Section 56.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Compressed Air and Boilers § 56.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges, pressure...

  8. 30 CFR 56.13030 - Boilers.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Boilers. 56.13030 Section 56.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Compressed Air and Boilers § 56.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges, pressure...

  9. 30 CFR 77.413 - Boilers.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Boilers. 77.413 Section 77.413 Mineral... Mechanical Equipment § 77.413 Boilers. (a) Boilers shall be equipped with guarded, well-maintained water... the gages shall be kept clean and free of scale and rust. (b) Boilers shall be equipped with...

  10. 30 CFR 77.413 - Boilers.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Boilers. 77.413 Section 77.413 Mineral... Mechanical Equipment § 77.413 Boilers. (a) Boilers shall be equipped with guarded, well-maintained water... the gages shall be kept clean and free of scale and rust. (b) Boilers shall be equipped with...

  11. 30 CFR 56.13030 - Boilers.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Boilers. 56.13030 Section 56.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Compressed Air and Boilers § 56.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges, pressure...

  12. 30 CFR 77.413 - Boilers.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Boilers. 77.413 Section 77.413 Mineral... Mechanical Equipment § 77.413 Boilers. (a) Boilers shall be equipped with guarded, well-maintained water... the gages shall be kept clean and free of scale and rust. (b) Boilers shall be equipped with...

  13. 49 CFR 230.47 - Boiler number.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 4 2013-10-01 2013-10-01 false Boiler number. 230.47 Section 230.47..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Steam Gauges § 230.47 Boiler number. (a) Generally. The builder's number of the boiler, if known,...

  14. 30 CFR 57.13030 - Boilers.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Boilers. 57.13030 Section 57.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Compressed Air and Boilers § 57.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges,...

  15. 49 CFR 230.47 - Boiler number.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 4 2012-10-01 2012-10-01 false Boiler number. 230.47 Section 230.47..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Steam Gauges § 230.47 Boiler number. (a) Generally. The builder's number of the boiler, if known,...

  16. 30 CFR 57.13030 - Boilers.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Boilers. 57.13030 Section 57.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Compressed Air and Boilers § 57.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges,...

  17. 30 CFR 56.13030 - Boilers.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Boilers. 56.13030 Section 56.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Compressed Air and Boilers § 56.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges, pressure...

  18. 30 CFR 56.13030 - Boilers.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Boilers. 56.13030 Section 56.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-SURFACE METAL AND NONMETAL MINES Compressed Air and Boilers § 56.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges, pressure...

  19. 30 CFR 57.13030 - Boilers.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Boilers. 57.13030 Section 57.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Compressed Air and Boilers § 57.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges,...

  20. 30 CFR 57.13030 - Boilers.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Boilers. 57.13030 Section 57.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Compressed Air and Boilers § 57.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges,...

  1. 30 CFR 77.413 - Boilers.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Boilers. 77.413 Section 77.413 Mineral... Mechanical Equipment § 77.413 Boilers. (a) Boilers shall be equipped with guarded, well-maintained water... the gages shall be kept clean and free of scale and rust. (b) Boilers shall be equipped with...

  2. 30 CFR 57.13030 - Boilers.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Boilers. 57.13030 Section 57.13030 Mineral... HEALTH SAFETY AND HEALTH STANDARDS-UNDERGROUND METAL AND NONMETAL MINES Compressed Air and Boilers § 57.13030 Boilers. (a) Fired pressure vessels (boilers) shall be equipped with water level gauges,...

  3. 30 CFR 77.413 - Boilers.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Boilers. 77.413 Section 77.413 Mineral... Mechanical Equipment § 77.413 Boilers. (a) Boilers shall be equipped with guarded, well-maintained water... the gages shall be kept clean and free of scale and rust. (b) Boilers shall be equipped with...

  4. 49 CFR 230.47 - Boiler number.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 4 2014-10-01 2014-10-01 false Boiler number. 230.47 Section 230.47..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Steam Gauges § 230.47 Boiler number. (a) Generally. The builder's number of the boiler, if known,...

  5. Tube support

    DOEpatents

    Mullinax, Jerry L.

    1988-01-01

    A tube support for supporting horizontal tubes from an inclined vertical support tube passing between the horizontal tubes. A support button is welded to the vertical support tube. Two clamping bars or plates, the lower edges of one bearing on the support button, are removably bolted to the inclined vertical tube. The clamping bars provide upper and lower surface support for the horizontal tubes.

  6. Evaluation of the Memory Effect on Gold-Coated Silica Adsorption Tubes Used for the Analysis of Gaseous Mercury by Cold Vapor Atomic Absorption Spectrometry

    PubMed Central

    Rahman, Mohammad Mahmudur; Brown, Richard J. C.; Yoon, Hye-On; Phan, Nhu-Thuc

    2013-01-01

    In an effort to reduce the experimental bias involved in the analysis of gaseous elemental mercury (Hgo), the blank response from gold-coated adsorption tubes has been investigated using cold vapor atomic absorption spectrometry (CVAAS). Our study has been compared with our recent investigation on memory effect in a cold vapour atomic fluorescence spectrometry (CVAFS). The pattern of blank responses was quantified after loading different amounts of mercury and after different time intervals of 1, 14, and 45 days. In case of the one day interval, the result of five to six instant blank heating cycles confirmed successful liberation of mercury following the second and third blank heating cycles. The results of 14 or 45 days generally suggest that liberation of excess mercury is affected by both the initial loading amount and the length of storage time prior to analysis. We have demonstrated a possibly effective way to reduce memory effects. Some similarities of these results with those from CVAFS experiment suggests that the blank response is caused by a combination of mercury absorbed within the bulk gold and micro- and nanoparticles liberated during heating and not from coabsorbing interfering gaseous species. PMID:23589708

  7. Evaluation of the memory effect on gold-coated silica adsorption tubes used for the analysis of gaseous mercury by cold vapor atomic absorption spectrometry.

    PubMed

    Rahman, Mohammad Mahmudur; Brown, Richard J C; Kim, Ki-Hyun; Yoon, Hye-On; Phan, Nhu-Thuc

    2013-01-01

    In an effort to reduce the experimental bias involved in the analysis of gaseous elemental mercury (Hg(o)), the blank response from gold-coated adsorption tubes has been investigated using cold vapor atomic absorption spectrometry (CVAAS). Our study has been compared with our recent investigation on memory effect in a cold vapour atomic fluorescence spectrometry (CVAFS). The pattern of blank responses was quantified after loading different amounts of mercury and after different time intervals of 1, 14, and 45 days. In case of the one day interval, the result of five to six instant blank heating cycles confirmed successful liberation of mercury following the second and third blank heating cycles. The results of 14 or 45 days generally suggest that liberation of excess mercury is affected by both the initial loading amount and the length of storage time prior to analysis. We have demonstrated a possibly effective way to reduce memory effects. Some similarities of these results with those from CVAFS experiment suggests that the blank response is caused by a combination of mercury absorbed within the bulk gold and micro- and nanoparticles liberated during heating and not from coabsorbing interfering gaseous species.

  8. Condensing economizers for small coal-fired boilers and furnaces

    SciTech Connect

    Butcher, T.A.; Litzke, W.

    1994-01-01

    Condensing economizers increase the thermal efficiency of boilers by recovering sensible and latent heat from exhaust gas. These economizers are currently being used commercially for this purpose in a wide range of applications. Performance is dependent upon application-specific factors affecting the utility of recovered heat. With the addition of a condensing economizer boiler efficiency improvements up to 10% are possible. Condensing economizers can also capture flue gas particulates. In this work, the potential use of condensing economizers for both efficiency improvement and control of particulate emissions from small, coal water slurry-fired boilers was evaluated. Analysis was done to predict heat transfer and particulate capture by mechanisms including: inertial impaction, interception, diffusion, thermophoretic forces, and condensation growth. Shell-and-tube geometries were considered with flue gas on the outside of Teflon-covered tubes. Experimental studies were done with both air- and water-cooled economizers refit to a small boiler. Two experimental arrangements were used including oil-firing with injection of flyash upstream of the economizer and direct coal water slurry firing. Firing rates ranged from 27 to 82 kW (92,000 to 280,000 Btu/hr). Inertial impaction was found to be the most important particulate capture mechanism and removal efficiencies to 95% were achieved. With the addition of water sprays directly on the first row of tubes, removal efficiencies increased to 98%. Use of these sprays adversely affects heat recovery. Primary benefits of the sprays are seen to be the addition of small impaction sites and future design improvements are suggested in which such small impactors are permanently added to the highest velocity regions of the economizer. Predicted effects of these added impactors on particulate removal and pressure drop are presented.

  9. Waste heat recovery boiler

    SciTech Connect

    Taiji Inui, H.; Makoto Sasaki, M.

    1984-08-21

    A waste heat recovery boiler for generating steam by utilizing a flue gas discharged from a gas turbine as a heat source comprises an economizer for preheating feedwater by the flue gas, an evaporator for evaporating the preheated feedwater, and a superheater for generating a steam for driving a steam prime mover by heating the evaporated feedwater. The economizer, the evaporator and the superheater are successively arranged in the direction from a downstream side to an upstream side of flue gas passage. The evaporator itself is divided into two sections and an apparatus for removing NO /SUB x/ is provided in a space between the divided two sections of the evaporator in the flue gas passage to remove NO /SUB x/ from the flue gas. An NO /SUB x/ concentration of a flue gas discharged from a combined cycle power plant including the gas turbine can be stably abated at any of full and partial loads.

  10. Guidelines on fossil boiler field welding. Final report

    SciTech Connect

    Stephenson, G.G.

    1993-01-01

    Welding is a key maintenance activity in the repair and replacement of critical boiler pressure-part components. Unless trained welders use qualified procedures and documented practices, significant delays to outages may result from defective weld repairs, and future weld-related failures may cause costly outages. To address these issues, a comprehensive guideline on field-welding practices for fossil-fired boilers has been developed. It can assist utilities in establishing in-house welding programs. Welding practices used by utilities, boiler manufacturers, and repair organizations were critically reviewed and utilized in the preparation of a step-by-step guideline for repairs to, and replacement, of boiler tubes, headers, and drums. A set of Road Maps, and their accompanying written descriptions, guide the user through each step in every phase of the complete weld repair process. Additionally, the guideline discusses in detail: weld repair management, welder performance qualification and training, repair decision evaluation, defect removal and joint preparation, repair methods for thin and thick sections, welding procedure variables, materials and specifications, failure and root-cause analysis, inspection, and testing.

  11. Ear Tubes

    MedlinePlus

    ... ENTCareers Marketplace Find an ENT Doctor Near You Ear Tubes Ear Tubes Patient Health Information News media ... and throat specialist) may be considered. What are ear tubes? Ear tubes are tiny cylinders placed through ...

  12. CFB boiler at Gardanne (France)

    SciTech Connect

    Jaud, P.; Jacquet, L.; Delot, P.; Bayle, F.

    1995-06-01

    Among the new Clean Coal Technologies, {open_quotes}Circulating Fluidized Bed{close_quotes} is one of the most promising. Today, the largest project in commissioning`s the 250 MWe Provence CFB boiler, located near MARSEILLE in the south of France. At such a size, the CFB technique has now reached a capacity corresponding to thermal power plants operated by utilities. This new unit is a very important step towards larger size i.e. 400 MWe and greater. The SO{sub 2} emissions of this CFB boiler are guaranteed to be less than 400 mg / Nm{sup 3} at 6% O{sub 2} with the ratio of Ca/S lower than 3 while total sulfur in local coal used can reach 3.68 %. The purpose of the Provence project was to replace the existing pulverized coal boiler unit 4, commissioned in 1967, of the Provence power plant, with a new CFB boiler while reusing most of the existing equipment. The new boiler has been ordered from GEC ALSTHOM STEIN INDUSTREE (GASI) by Electricite de France (EDF) on behalf of the SOPROLIF consortium. Architect Engineering and construction management was performed by EDF jointly with Charbonnages de France (CdF: the French Coal Board). The 250 MWe CFB boiler is of the superheat-reheat type. The first firing of the boiler is due in April 1995. The poster session will describe the progress in the construction of the plant and provides technical details of the new boiler and auxiliaries.

  13. Chemical corrosion potential in boilers

    SciTech Connect

    Bairr, D.L.; McDonough, C.J.

    1998-12-31

    Misuse or abuse of chelants has long been recognized as a potential corrosion problem in boilers. In recent years all polymer chemical treatment programs have been introduced and although they are much more benign even all polymer programs must be properly designed and controlled. Under extreme conditions a similar corrosion potential exists. This paper discusses the potential for chelant or polymer corrosion in boilers and the proper safeguards. Case histories are presented.

  14. Boiler-turbine life extension

    SciTech Connect

    Natzkov, S.; Nikolov, M.

    1995-12-01

    The design life of the main power equipment-boilers and turbines is about 105 working hours. The possibilities for life extension are after normatively regulated control tests. The diagnostics and methodology for Boilers and Turbines Elements Remaining Life Assessment using up to date computer programs, destructive and nondestructive control of metal of key elements of units equipment, metal creep and low cycle fatigue calculations. As well as data for most common damages and some technical decisions for elements life extension are presented.

  15. Combustion Characteristics of Oxy-fuel Burners for CO2 Capturing Boilers

    NASA Astrophysics Data System (ADS)

    Ahn, Joon; Kim, Hyouck Ju; Choi, Kyu Sung

    Oxy-fuel boilers have been developed to capture CO2 from the exhaust gas. A 50 kW class model burner has been developed and tested in a furnace type boiler. The burner has been scaled up to 0.5 and 3 MW class for fire-tube type boilers. The burners are commonly laid out in a coaxial type to effectively heat the combustion chamber of boilers. Burners are devised to support air and oxy-fuel combustion modes for the retrofitting scenario. FGR (flue gas recirculation) has been tried during the scale-up procedure. Oxy-fuel combustion yields stretched flame to uniformly heat the combustion chamber. It also provides the high CO2 concentration, which is over 90% in dry base. However, pure oxy-fuel combustion increases NO concentration, because of the reduced flow rate. The FGR can suppress the thermal NOx induced by the infiltration of the air.

  16. Superheater Corrosion In Biomass Boilers: Today's Science and Technology

    SciTech Connect

    Sharp, William

    2011-12-01

    This report broadens a previous review of published literature on corrosion of recovery boiler superheater tube materials to consider the performance of candidate materials at temperatures near the deposit melting temperature in advanced boilers firing coal, wood-based fuels, and waste materials as well as in gas turbine environments. Discussions of corrosion mechanisms focus on the reactions in fly ash deposits and combustion gases that can give corrosive materials access to the surface of a superheater tube. Setting the steam temperature of a biomass boiler is a compromise between wasting fuel energy, risking pluggage that will shut the unit down, and creating conditions that will cause rapid corrosion on the superheater tubes and replacement expenses. The most important corrosive species in biomass superheater corrosion are chlorine compounds and the most corrosion resistant alloys are typically FeCrNi alloys containing 20-28% Cr. Although most of these materials contain many other additional additions, there is no coherent theory of the alloying required to resist the combination of high temperature salt deposits and flue gases that are found in biomass boiler superheaters that may cause degradation of superheater tubes. After depletion of chromium by chromate formation or chromic acid volatilization exceeds a critical amount, the protective scale gives way to a thick layer of Fe{sub 2}O{sub 3} over an unprotective (FeCrNi){sub 3}O{sub 4} spinel. This oxide is not protective and can be penetrated by chlorine species that cause further acceleration of the corrosion rate by a mechanism called active oxidation. Active oxidation, cited as the cause of most biomass superheater corrosion under chloride ash deposits, does not occur in the absence of these alkali salts when the chloride is present as HCl gas. Although a deposit is more corrosive at temperatures where it is molten than at temperatures where it is frozen, increasing superheater tube temperatures through

  17. Development of combined low-emissions burner devices for low-power boilers

    NASA Astrophysics Data System (ADS)

    Roslyakov, P. V.; Proskurin, Yu. V.; Khokhlov, D. A.

    2017-08-01

    Low-power water boilers are widely used for autonomous heat supply in various industries. Firetube and water-tube boilers of domestic and foreign manufacturers are widely represented on the Russian market. However, even Russian boilers are supplied with licensed foreign burner devices, which reduce their competitiveness and complicate operating conditions. A task of developing efficient domestic low-emissions burner devices for low-power boilers is quite acute. A characteristic property of ignition and fuel combustion in such boilers is their flowing in constrained conditions due to small dimensions of combustion chambers and flame tubes. These processes differ significantly from those in open combustion chambers of high-duty power boilers, and they have not been sufficiently studied yet. The goals of this paper are studying the processes of ignition and combustion of gaseous and liquid fuels, heat and mass transfer and NO x emissions in constrained conditions, and the development of a modern combined low-emissions 2.2 MW burner device that provides efficient fuel combustion. A burner device computer model is developed and numerical studies of its operation on different types of fuel in a working load range from 40 to 100% of the nominal are carried out. The main features of ignition and combustion of gaseous and liquid fuels in constrained conditions of the flame tube at nominal and decreased loads are determined, which differ fundamentally from the similar processes in steam boiler furnaces. The influence of the burner devices design and operating conditions on the fuel underburning and NO x formation is determined. Based on the results of the design studies, a design of the new combined low-emissions burner device is proposed, which has several advantages over the prototype.

  18. Ash chemistry aspects of straw and coal-straw co-firing in utility boilers

    SciTech Connect

    Frandsen, F.J.; Nielsen, H.P.; Hansen, L.A.; Hansen, P.F.B.; Andersen, K.H.

    1998-12-31

    Deposits formed in straw-fired grate-boilers showed significant amounts of KCl (40--80% (w/w)) and KCl-coated Ca-Si-rich particles. CFB co-firing of straw and coal caused deposits in the convective pass containing predominantly K{sub 2}SO{sub 4} (50--60% (w/w)) with small amounts of KCl close to the metal surface. In pulverized coal-straw co-fired boilers, deposits almost free of KCl were found. Most of the potassium in these deposits is derived from K-Al-Si-rich fly ash particles and the rest occurs as K{sub 2}SO{sub 4}. The presence of K-Al-Si-rich fly ash particles indicates that solid residue quality and reuse of fly ash in cement and concrete production rather than deposit formation may be of concern when utilizing straw in pulverized fuel boilers. This paper provides a review of Danish experiences with high-temperature ash deposit formation in the following full-scale utility boilers: Slagelse CHP (31 MWth), Haslev CHP (23 MWth) and Rudkoebing CHP (10.7 MWth), all straw-fired grate-boilers; Grenaa CHP (80 MWth), a coal-straw co-fired Circulating Fluidized Bed (CFB) boiler; and the Midtkraft-Studstrup Power Station, Unit 1 (380 MWth), a coal-straw co-fired PF-boiler.

  19. 46 CFR 61.05-10 - Boilers in service.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 2 2012-10-01 2012-10-01 false Boilers in service. 61.05-10 Section 61.05-10 Shipping... INSPECTIONS Tests and Inspections of Boilers § 61.05-10 Boilers in service. (a) Each boiler, including superheater, reheater, economizer, auxiliary boiler, low-pressure heating boiler, and unfired steam...

  20. 46 CFR 61.05-10 - Boilers in service.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 2 2013-10-01 2013-10-01 false Boilers in service. 61.05-10 Section 61.05-10 Shipping... INSPECTIONS Tests and Inspections of Boilers § 61.05-10 Boilers in service. (a) Each boiler, including superheater, reheater, economizer, auxiliary boiler, low-pressure heating boiler, and unfired steam...

  1. 46 CFR 61.05-10 - Boilers in service.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 2 2011-10-01 2011-10-01 false Boilers in service. 61.05-10 Section 61.05-10 Shipping... INSPECTIONS Tests and Inspections of Boilers § 61.05-10 Boilers in service. (a) Each boiler, including superheater, reheater, economizer, auxiliary boiler, low-pressure heating boiler, and unfired steam...

  2. 46 CFR 61.05-10 - Boilers in service.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 2 2014-10-01 2014-10-01 false Boilers in service. 61.05-10 Section 61.05-10 Shipping... INSPECTIONS Tests and Inspections of Boilers § 61.05-10 Boilers in service. (a) Each boiler, including superheater, reheater, economizer, auxiliary boiler, low-pressure heating boiler, and unfired steam...

  3. 46 CFR 61.05-10 - Boilers in service.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boilers in service. 61.05-10 Section 61.05-10 Shipping... INSPECTIONS Tests and Inspections of Boilers § 61.05-10 Boilers in service. (a) Each boiler, including superheater, reheater, economizer, auxiliary boiler, low-pressure heating boiler, and unfired steam...

  4. Boiler using combustible fluid

    DOEpatents

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  5. INDUSTRIAL BOILER RETROFIT FOR NOX CONTROL: COMBINED SELECTIVE NONCATALYTIC REDUCTION AND SELECTIVE CATALYTIC REDUCTION

    EPA Science Inventory

    The paper describes retrofitting and testing a 590 kW (2 MBtu/hr), oil-fired, three-pass, fire-tube package boiler with a combined selective noncatalytic reduction (SNCR) and selective catalytic reduction (SCR) system. The system demonstrated 85% nitrogen oxides (NOx) reduction w...

  6. INDUSTRIAL BOILER RETROFIT FOR NOX CONTROL: COMBINED SELECTIVE NONCATALYTIC REDUCTION AND SELECTIVE CATALYTIC REDUCTION

    EPA Science Inventory

    The paper describes retrofitting and testing a 590 kW (2 MBtu/hr), oil-fired, three-pass, fire-tube package boiler with a combined selective noncatalytic reduction (SNCR) and selective catalytic reduction (SCR) system. The system demonstrated 85% nitrogen oxides (NOx) reduction w...

  7. Preventing acid phosphate attack in coordinated phosphate programs for high-pressure boilers

    SciTech Connect

    Hollander, O.

    1999-12-01

    Coordinated phosphate programs were introduced to maintain bulk water and underdeposit chemistries in a safe pH range. With the wide assortment of additives routinely employed in modern treatment programs, it is no longer a simple matter to control the treatment. The errors induced by the additives and impurities can lead to acid attack and boiler tube failure.

  8. 75 FR 65023 - Notice of Issuance of Final Determination Concerning Certain Heating Boilers

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-21

    ... H119218 Ms. Regina Vargo Greenberg Traurig, LLP 2101 L Street NW, Suite 1000 Washington, D.C. 20037 Re: U.S. Government Procurement; Heating Boilers Dear Ms. Vargo: This is in response to your letter, dated... Canadian supplier, and is assembled in Canada from U.S. origin stainless steel plates and tubes. The...

  9. Program to Train Boiler Operators Developed

    ERIC Educational Resources Information Center

    Chemical and Engineering News, 1978

    1978-01-01

    This program initiated by Nalco Chemical, a major supplier of chemicals for boiler feedwater treatment, uses texts, audiovisual aids, and hands-on experience and is designed to boost the efficiency of boiler operators. (BB)

  10. Boiler for generating high quality vapor

    NASA Technical Reports Server (NTRS)

    Gray, V. H.; Marto, P. J.; Joslyn, A. W.

    1972-01-01

    Boiler supplies vapor for use in turbines by imparting a high angular velocity to the liquid annulus in heated rotating drum. Drum boiler provides a sharp interface between boiling liquid and vapor, thereby, inhibiting the formation of unwanted liquid droplets.

  11. Program to Train Boiler Operators Developed

    ERIC Educational Resources Information Center

    Chemical and Engineering News, 1978

    1978-01-01

    This program initiated by Nalco Chemical, a major supplier of chemicals for boiler feedwater treatment, uses texts, audiovisual aids, and hands-on experience and is designed to boost the efficiency of boiler operators. (BB)

  12. New controls spark boiler efficiency

    SciTech Connect

    Engels, T. )

    1993-09-01

    Monsanto's NutraSweet plant in University Park, IL, produces aspartame, the patented NutraSweet artificial sweetener product. Until recently, boiler control was managed by a '60s-era Fireye jackshaft system in which air and natural gas were mechanically linked with an offset to compensate for oxygen trim. The interlocking devices on the Fireye system were becoming obsolete, and the boiler needed a new front end retrofitted for low emissions. In order to improve boiler control efficiency, we decided to modernize and automate the entire boiler control system. We replaced the original jackshaft system, and installed a Gordon-Piet burner system, including gas valves, air dampers, blowers, and burner. The upgrade challenges included developing a control strategy and selecting and implementing a process control system. Since our plant has standardized on the PROVOX process management information system from Fisher Controls (now Fisher-Rosemount Systems) to support most of our process, it was a natural and logical choice for boiler controls as well. 2 figs.

  13. 46 CFR 52.05-45 - Circumferential joints in pipes, tubes and headers (modifies PW-41).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 2 2014-10-01 2014-10-01 false Circumferential joints in pipes, tubes and headers... Circumferential joints in pipes, tubes and headers (modifies PW-41). (a) Circumferential welded joints of pipes, tubes and headers shall be as required by PW-41 of section I of the ASME Boiler and Pressure Vessel...

  14. 46 CFR 52.05-45 - Circumferential joints in pipes, tubes and headers (modifies PW-41).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 2 2011-10-01 2011-10-01 false Circumferential joints in pipes, tubes and headers... Circumferential joints in pipes, tubes and headers (modifies PW-41). (a) Circumferential welded joints of pipes, tubes and headers shall be as required by PW-41 of section I of the ASME Boiler and Pressure Vessel...

  15. 46 CFR 52.05-45 - Circumferential joints in pipes, tubes and headers (modifies PW-41).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Circumferential joints in pipes, tubes and headers... Circumferential joints in pipes, tubes and headers (modifies PW-41). (a) Circumferential welded joints of pipes, tubes and headers shall be as required by PW-41 of section I of the ASME Boiler and Pressure Vessel...

  16. 46 CFR 52.05-45 - Circumferential joints in pipes, tubes and headers (modifies PW-41).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 2 2013-10-01 2013-10-01 false Circumferential joints in pipes, tubes and headers... Circumferential joints in pipes, tubes and headers (modifies PW-41). (a) Circumferential welded joints of pipes, tubes and headers shall be as required by PW-41 of section I of the ASME Boiler and Pressure Vessel...

  17. 46 CFR 52.05-45 - Circumferential joints in pipes, tubes and headers (modifies PW-41).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 2 2012-10-01 2012-10-01 false Circumferential joints in pipes, tubes and headers... Circumferential joints in pipes, tubes and headers (modifies PW-41). (a) Circumferential welded joints of pipes, tubes and headers shall be as required by PW-41 of section I of the ASME Boiler and Pressure Vessel...

  18. Mesoporous titanium oxide with high-specific surface area as a coating for in-tube solid-phase microextraction combined with high-performance liquid chromatography for the analysis of polycyclic aromatic hydrocarbons.

    PubMed

    Wang, Xiuqin; Feng, Juanjuan; Bu, Yanan; Tian, Yu; Luo, Chuannan; Sun, Min

    2017-06-01

    Stainless-steel wires coated with mesoporous titanium oxide were placed into a polyether ether ketone tube for in-tube solid-phase microextraction, and the coating sorbent was characterized by X-ray diffraction and scanning electron microscopy. It was combined with high-performance liquid chromatography to build an online system. Using eight polycyclic aromatic hydrocarbons as the analytes, some conditions including sample flow rate, sample volume, organic solvent content, and desorption time were investigated. Under optimum conditions, an online analysis method was established and provided good linearity (0.03-30 μg/L), low detection limits (0.01-0.10 μg/L), and high enrichment factors (77.6-678). The method was applied to determine target analytes in river water and water sample of coal ash, and the recoveries are in the range of 80.6-106.6 and 80.9-103.5%, respectively. Compared with estrogens and plasticizers, extraction coating shows better extraction efficiency for polycyclic aromatic hydrocarbons. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. 29 CFR 1915.162 - Ship's boilers.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Ship's boilers. (a) Before work is performed in the fire, steam, or water spaces of a boiler where employees may be subject to injury from the direct escape of a high temperature medium such as steam, or... that employees are working in the boilers shall be hung in a conspicuous location in the engine...

  20. 29 CFR 1915.162 - Ship's boilers.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Ship's boilers. (a) Before work is performed in the fire, steam, or water spaces of a boiler where employees may be subject to injury from the direct escape of a high temperature medium such as steam, or... that employees are working in the boilers shall be hung in a conspicuous location in the engine...

  1. 29 CFR 1915.162 - Ship's boilers.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Ship's boilers. (a) Before work is performed in the fire, steam, or water spaces of a boiler where employees may be subject to injury from the direct escape of a high temperature medium such as steam, or... employees are working in the boilers shall be hung in a conspicuous location in the engine room. This...

  2. 29 CFR 1915.162 - Ship's boilers.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Ship's boilers. (a) Before work is performed in the fire, steam, or water spaces of a boiler where employees may be subject to injury from the direct escape of a high temperature medium such as steam, or... that employees are working in the boilers shall be hung in a conspicuous location in the engine...

  3. 29 CFR 1915.162 - Ship's boilers.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Ship's boilers. (a) Before work is performed in the fire, steam, or water spaces of a boiler where employees may be subject to injury from the direct escape of a high temperature medium such as steam, or... employees are working in the boilers shall be hung in a conspicuous location in the engine room. This...

  4. Sootblowing optimization for improved boiler performance

    DOEpatents

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J.

    2012-12-25

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  5. Sootblowing optimization for improved boiler performance

    DOEpatents

    James, John Robert; McDermott, John; Piche, Stephen; Pickard, Fred; Parikh, Neel J

    2013-07-30

    A sootblowing control system that uses predictive models to bridge the gap between sootblower operation and boiler performance goals. The system uses predictive modeling and heuristics (rules) associated with different zones in a boiler to determine an optimal sequence of sootblower operations and achieve boiler performance targets. The system performs the sootblower optimization while observing any operational constraints placed on the sootblowers.

  6. 49 CFR 230.47 - Boiler number.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Steam Gauges § 230.47 Boiler number. (a) Generally. The builder's number of the boiler, if known, shall... known or the name of the steam locomotive owner if a new number is assigned. Safety Relief Valves ...

  7. 49 CFR 230.47 - Boiler number.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Steam Gauges § 230.47 Boiler number. (a) Generally. The builder's number of the boiler, if known, shall... known or the name of the steam locomotive owner if a new number is assigned. Safety Relief Valves ...

  8. Improved Mechanical Seals For Tubes

    NASA Technical Reports Server (NTRS)

    Babel, Henry W.; Anderson, Raymond H.; Fuson, Phillip L.; Chickles, Colin D.; Jones, Cherie A.

    1996-01-01

    Improved tube-to-fitting seals made by application of soft metal pieces to either ends of tubes or to interior of fittings. Metal silver, gold, platinum, tin, or other easily malleable metal selected to be inert with fluid of use. Metal plated, evaporated, or sputter-deposited. Coat of soft metal thin, so no changes required in design or tolerances of standard fittings. Technique suitable for hydraulic or other fluid systems in which leakage from mechanically joined sections of tubes occur.

  9. Improved Mechanical Seals For Tubes

    NASA Technical Reports Server (NTRS)

    Babel, Henry W.; Anderson, Raymond H.; Fuson, Phillip L.; Chickles, Colin D.; Jones, Cherie A.

    1996-01-01

    Improved tube-to-fitting seals made by application of soft metal pieces to either ends of tubes or to interior of fittings. Metal silver, gold, platinum, tin, or other easily malleable metal selected to be inert with fluid of use. Metal plated, evaporated, or sputter-deposited. Coat of soft metal thin, so no changes required in design or tolerances of standard fittings. Technique suitable for hydraulic or other fluid systems in which leakage from mechanically joined sections of tubes occur.

  10. Alternate tube plugging criteria for steam generator tubes

    SciTech Connect

    Cueto-Felgueroso, C.; Aparicio, C.B.

    1997-02-01

    The tubing of the Steam Generators constitutes more than half of the reactor coolant pressure boundary. Specific requirements governing the maintenance of steam generator tubes integrity are set in Plant Technical Specifications and in Section XI of the ASME Boiler and Pressure Vessel Code. The operating experience of Steam Generator tubes of PWR plants has shown the existence of some types of degradatory processes. Every one of these has an specific cause and affects one or more zones of the tubes. In the case of Spanish Power Plants, and depending on the particular Plant considered, they should be mentioned the Primary Water Stress Corrosion Cracking (PWSCC) at the roll transition zone (RTZ), the Outside Diameter Stress Corrosion Cracking (ODSCC) at the Tube Support Plate (TSP) intersections and the fretting with the Anti-Vibration Bars (AVBs) or with the Support Plates in the preheater zone. The In-Service Inspections by Eddy Currents constitutes the standard method for assuring the SG tubes integrity and they permit the monitoring of the defects during the service life of the plant. When the degradation reaches a determined limit, called the plugging limit, the SG tube must be either repaired or retired from service by plugging. Customarily, the plugging limit is related to the depth of the defect. Such depth is typically 40% of the wall thickness of the tube and is applicable to any type of defect in the tube. In its origin, that limit was established for tubes thinned by wastage, which was the predominant degradation in the seventies. The application of this criterion for axial crack-like defects, as, for instance, those due to PWSCC in the roll transition zone, has lead to an excessive and unnecessary number of tubes being plugged. This has lead to the development of defect specific plugging criteria. Examples of the application of such criteria are discussed in the article.

  11. TUBE TESTER

    DOEpatents

    Gittings, H.T. Jr.; Kalbach, J.F.

    1958-01-14

    This patent relates to tube testing, and in particular describes a tube tester for automatic testing of a number of vacuum tubes while in service and as frequently as may be desired. In it broadest aspects the tube tester compares a particular tube with a standard tube tarough a difference amplifier. An unbalanced condition in the circuit of the latter produced by excessive deviation of the tube in its characteristics from standard actuates a switch mechanism stopping the testing cycle and indicating the defective tube.

  12. SNAP-8 refractory boiler development program

    NASA Technical Reports Server (NTRS)

    Fuller, R. A.

    1974-01-01

    Performance and endurance tests of the SNAP-8, SN-1 refractory metal boiler are described. The tests were successful and indicated that the boiler heat transfer area could be reduced significantly primarily because of the wetting characteristics of mercury on tantalum in a contaminant-free environment. A continuous endurance test of more than 10,000 hours was conducted without noticeable change in the thermal performance of the boiler. A conclusion of the metallographic examination of the boiler following the endurance test was that expected boiler life would be of the order of 40,000 hours at observed corrosion rates.

  13. Development of a reburning boiler process model

    SciTech Connect

    Wu, K.T.

    1992-01-30

    The overall objective of this program is to integrate EER's expertise in boiler reburning performance evaluation into a package of analytical computer tools. Specific objectives of the program are to develop a computational capability with the following features: (1) can be used to predict the impact of gas reburning application on thermal conditions in the boiler radiant furnace, and on overall boiler performance; (2) can estimate gas reburning NO{sub x} reduction effectiveness based on specific reburning configurations and furnace/boiler configurations; (3) can be used as an analytical tool to evaluate the impact of boiler process parameters (e.g., fuel switching and changes in boiler operating conditions) on boiler thermal performance; (4) is adaptable to most boiler designs (tangential and wall fire boilers) and a variety of fuels (solid, liquid, gaseous and slurried fuels); (5) is sufficiently user friendly to be exercisable by engineers with a reasonable knowledge of boilers, and with reasonable computer skills. Here, user friendly'' means that the user will be guided by computer codes during the course of setting up individual input files for the boiler performance model.

  14. Tube supports

    SciTech Connect

    Cannon, K.A.

    1989-01-10

    This patent describes an apparatus consisting of parallel tubes arranged in the form of a tube bundle having a first plurality of parallel tube rows with lanes between adjacent rows and a second plurality of parallel tube rows with lanes between adjacent rows and support structure for supporting the tubes. The support structure consists of at least a first baffle and a second baffle, wherein each baffle comprises an outer ring surrounding the tube bundle and at least one slat attached to the outer ring as a chord and extending through the tube bundle between adjacent rows in one of the parallel tube rows. At least one slat is characterized by corrugations or folds extending along its length for point contact with the tubes of the bundle, the slat in the first baffle extending in lanes between the first plurality of parallel tube rows, and the slat in the second baffle extending in lanes between the second plurality of parallel tube rows.

  15. Cleaning of boiler heating surfaces

    SciTech Connect

    Maidanik, M. N.; Vasil'ev, V. V.

    2006-09-15

    Basic methods and facilities for the external cleaning of the heating surfaces of boilers designed for the combustion of low-grade solid fuels are discussed. Water and steam blastings, which are the basic means of cleaning furnace shields, and semi-radiative and convective heating surfaces have the greatest range of application.

  16. Identification of boiler inlet transfer functions and estimation of system parameters

    NASA Technical Reports Server (NTRS)

    Miles, J. H.

    1972-01-01

    An iterative computer method is described for identifying boiler transfer functions using frequency response data. An objective penalized performance measure and a nonlinear minimization technique are used to cause the locus of points generated by a transfer function to resemble the locus of points obtained from frequency response measurements. Different transfer functions can be tried until a satisfactory empirical transfer function of the system is found. To illustrate the method, some examples and some results from a study of a set of data consisting of measurements of the inlet impedance of a single tube forced flow boiler with inserts are given.

  17. Optimization of creep properties of welded header-stub tube connection for lif extension

    SciTech Connect

    Ram, R.; Cunningham, G.; Roberts, B.

    1996-12-31

    The failure of boiler tubes is the predominant cause of boiler outages. From a life-extension point of view, the critical components are large diameter thick-wall high-temperature headers. The primary aim of this research is to numerically analyze the stresses in the boiler tube-header weld connection and study the behavior of the material as it creeps. The focus is on the initial thermoelastic stresses at the beginning of operation and the distribution of stresses after approximately twenty years of operation when the stresses have relaxed. The study calculates creep life fractions of the assembly after twenty years of service.

  18. 46 CFR 52.25-20 - Exhaust gas boilers.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 2 2012-10-01 2012-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING POWER BOILERS Other Boiler Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure...

  19. 46 CFR 52.25-20 - Exhaust gas boilers.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING POWER BOILERS Other Boiler Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure...

  20. 46 CFR 52.25-20 - Exhaust gas boilers.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 2 2011-10-01 2011-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING POWER BOILERS Other Boiler Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure...

  1. 46 CFR 52.25-20 - Exhaust gas boilers.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 2 2014-10-01 2014-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING POWER BOILERS Other Boiler Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure...

  2. 46 CFR 52.25-20 - Exhaust gas boilers.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 2 2013-10-01 2013-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING POWER BOILERS Other Boiler Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure...

  3. PREDICTION OF OXIDE SCALE EXFOLIATION IN STEAM TUBES

    SciTech Connect

    Sabau, Adrian S; Wright, Ian G

    2010-01-01

    Numerical simulation results are presented for the prediction of the likelihood of oxide scale exfoliation from superheater tubes. The scenarios considered involved alloys T22, TP347H, and TP347HFG subjected to a simplified operating cycle in a power plant generating supercritical steam. The states of stress and strain of the oxides grown in steam were based solely on modeling the various phenomena experienced by superheater tubes during boiler operation, current understanding of the oxidation behavior of each alloy in steam, and consideration of operating parameters such as heat flux, tube dimensions, and boiler duty cycle. Interpretation of the evolution of strain in these scales, and the approach to conditions where scale failure (hence exfoliation) is expected, makes use of the type of Exfoliation Diagrams that incorporate various cracking and exfoliation criteria appropriate for the system considered. In these diagrams, the strain accumulation with time in an oxide is represented by a strain trajectory derived from the net strain resulting from oxide growth, differences in coefficients of thermal expansion among the components, and relaxation due to creep. It was found that an oxide growing on a tube subjected to routine boiler load cycling conditions attained relatively low values of net strain, indicating that oxide failure would not be expected to occur during normal boiler operation. However, during a boiler shut-down event, strains sufficient to exceed the scale failure criteria were developed after times reasonably in accord with plant experience, with the scales on the ferritic steel failing in tension, and those on the austenitic steels in compression. The results presented illustrate that using this approach to track the state of strain in the oxide scale through all phases of boiler operation, including transitions from full-to-low load and shut-down events, offers the possibility of identifying the phase(s) of boiler operation during which oxide

  4. Protective coating for copper in aluminum heat exchangers

    NASA Technical Reports Server (NTRS)

    Avazian, R.

    1978-01-01

    Application of ultrathin layer of molybdenum disulfied coating to copper tubing permits utilization of tubing in cast-aluminum heat exchangers. Coating prevents formation of copper/aluminum eutectic, but does not impede heat transfer.

  5. Weldability of Fe-Al-Cr Overlay Coatings for CorrosionProtection in Oxidizing/Sulfidizing Environments

    SciTech Connect

    Regina, JR

    2003-03-04

    The effect of chromium additions to the weldability of Fe-Al based overlay claddings are currently being investigated for the corrosion protection of boiler tubes in Low NOx furnaces. The primary objective of this research is to identify weldable (crack-free) Fe-Al-Cr weld overlay coating compositions that provide corrosion resistance over long exposure times. During the current project phase, preliminary corrosion testing was conducted on several ternary Fe-Al-Cr alloys in two types of gaseous corrosion environments. These long-term corrosion tests were used to develop a target weld composition matrix and serve as a base line for future corrosion tests. Preliminary Fe-Al based welds with various aluminum concentrations and one ternary Fe-Al-Cr weld overlay were successfully deposited using a Gas Tungsten Arc Welding (GTAW) process and cracking susceptibility was evaluated on these coatings.

  6. High Temperature Corrosion Problem of Boiler Components in presence of Sulfur and Alkali based Fuels

    NASA Astrophysics Data System (ADS)

    Ghosh, Debashis; Mitra, Swapan Kumar

    2011-04-01

    Material degradation and ageing is of particular concern for fossil fuel fired power plant components. New techniques/approaches have been explored in recent years for Residual Life assessment of aged components and material degradation due to different damage mechanism like creep, fatigue, corrosion and erosion etc. Apart from the creep, the high temperature corrosion problem in a fossil fuel fired boiler is a matter of great concern if the fuel contains sulfur, chlorine sodium, potassium and vanadium etc. This paper discusses the material degradation due to high temperature corrosion in different critical components of boiler like water wall, superheater and reheater tubes and also remedial measures to avoid the premature failure. This paper also high lights the Residual Life Assessment (RLA) methodology of the components based on high temperature fireside corrosion. of different critical components of boiler.

  7. 5. North/northwest elevations of boiler stack and boiler room. Note ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. North/northwest elevations of boiler stack and boiler room. Note tires on roof to reduce impact of brick work falling from stack. - Lowe Mill, Eighth Avenue, Southwest, Huntsville, Madison County, AL

  8. BOILER HOUSE, 1948 ADDITION, INTERIOR, SECOND FLOOR, BOILER 1A. VACANT ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    BOILER HOUSE, 1948 ADDITION, INTERIOR, SECOND FLOOR, BOILER 1-A. VACANT SPACES WERE THE LOCATION OF A SUPPLEMENTAL OIL BURNER. VIEW FROM SOUTH - Lihue Plantation Company, Sugar Mill Building, Haleko Road, Lihue, Kauai County, HI

  9. LPT. Low power test (TAN641) interior. Boiler room with boilers ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    LPT. Low power test (TAN-641) interior. Boiler room with boilers installed. Photographer: Jack L. Anderson. Date: November 21, 1957. INEEL negative no. 57-5884 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

  10. Predictive modelling of boiler fouling. Final report.

    SciTech Connect

    Chatwani, A

    1990-12-31

    A spectral element method embodying Large Eddy Simulation based on Re- Normalization Group theory for simulating Sub Grid Scale viscosity was chosen for this work. This method is embodied in a computer code called NEKTON. NEKTON solves the unsteady, 2D or 3D,incompressible Navier Stokes equations by a spectral element method. The code was later extended to include the variable density and multiple reactive species effects at low Mach numbers, and to compute transport of large particles governed by inertia. Transport of small particles is computed by treating them as trace species. Code computations were performed for a number of test conditions typical of flow past a deep tube bank in a boiler. Results indicate qualitatively correct behavior. Predictions of deposition rates and deposit shape evolution also show correct qualitative behavior. These simulations are the first attempts to compute flow field results at realistic flow Reynolds numbers of the order of 10{sup 4}. Code validation was not done; comparison with experiment also could not be made as many phenomenological model parameters, e.g., sticking or erosion probabilities and their dependence on experimental conditions were not known. The predictions however demonstrate the capability to predict fouling from first principles. Further work is needed: use of large or massively parallel machine; code validation; parametric studies, etc.

  11. Final Report, Materials for Industrial Heat Recovery Systems, Tasks 3 and 4 Materials for Heat Recovery in Recovery Boilers

    SciTech Connect

    Keiser, James R.; Kish, Joseph R.; Singh, Preet M.; Sarma, Gorti B.; Yuan, Jerry; Gorog, J. Peter; Frederick, Laurie A.; Jette, Francois R.; Meisner, Roberta A.; Singbeil, Douglas L.

    2007-12-31

    The DOE-funded project on materials for industrial heat recovery systems included four research tasks: materials for aluminum melting furnace recuperator tubes, materials and operational changes to prevent cracking and corrosion of the co-extruded tubes that form primary air ports in black liquor recovery boilers, the cause of and means to prevent corrosion of carbon steel tubes in the mid-furnace area of recovery boilers, and materials and operational changes to prevent corrosion and cracking of recovery boiler superheater tubes. Results from studies on the latter two topics are given in this report while separate reports on results for the first two tasks have already been published. Accelerated, localized corrosion has been observed in the mid-furnace area of kraft recovery boilers. This corrosion of the carbon steel waterwall tubes is typically observed in the vicinity of the upper level of air ports where the stainless clad co-extruded wall tubes used in the lower portion of the boiler are welded to the carbon steel tubes that extend from this transition point or “cut line” to the top of the boiler. Corrosion patterns generally vary from one boiler to another depending on boiler design and operating parameters, but the corrosion is almost always found within a few meters of the cut line and often much closer than that. This localized corrosion results in tube wall thinning that can reach the level where the integrity of the tube is at risk. Collection and analysis of gas samples from various areas near the waterwall surface showed reducing and sulfidizing gases were present in the areas where corrosion was accelerated. However, collection of samples from the same areas at intervals over a two year period showed the gaseous environment in the mid-furnace section can cycle between oxidizing and reducing conditions. These fluctuations are thought to be due to gas flow instabilities and they result in an unstable or a less protective scale on the carbon steel

  12. Life assessment of boiler pressure parts. Volume 1, Executive summary: Final report

    SciTech Connect

    Grunloh, H.J.

    1993-11-01

    This project was initiated to satisfy the need within the power industry to assess the remaining life of components which operate for extensive periods at elevated temperatures in fossil-fired units. The objective of the project was to develop and validate an integrated methodology for the assessment of the remaining life of boiler pressure parts. The specific boiler parts to be covered were superheater and reheater tubes, superheater and reheater headers, and piping components -- all components operating at elevated temperature where creep is a consideration. For heavy section pressure retaining components (headers and pipes) in elevated temperature service, the life limiting damage mechanisms are generally associated with crack initiation and propagation involving both creep and fatigue. The life assessment methodology developed for these components has been incorporated into the computer code BLESS (Boiler Life Estimation and Simulation System). The dominant long-term failure mode for superheater and reheater tubes is creep-rupture. This phenomenon has been studied extensively and the means of measuring the extent of such damage to these tubes has been quantified by application of the techniques in the field, at two host utilities, and in the laboratory. Results include validation of oxide growth models, evaluation of the use of ultrasonic methods for measuring oxide and tube wall thickness, newly-developed creep-rupture life and creep strain rate models, optimal stress formulas for use in damage assessment and remaining life calculations, and an integrated application of inspection and calculational methods using simplified probabilistic techniques for component-wide evaluations.

  13. Fluidized bed boiler feed system

    DOEpatents

    Jones, Brian C.

    1981-01-01

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  14. Energy storage-boiler tank

    NASA Technical Reports Server (NTRS)

    Chubb, T. A.; Nemecek, J. J.; Simmons, D. E.

    1980-01-01

    Activities performed in an effort to demonstrate heat of fusion energy storage in containerized salts are reported. The properties and cycle life characteristics of a eutectic salt having a boiling point of about 385 C (NaCl, KCl, Mg Cl2) were determined. M-terphenyl was chosen as the heat transfer fluid. Compatibility studies were conducted and mild steel containers were selected. The design and fabrication of a 2MWh storage boiler tank are discussed.

  15. Boiler Stack Gas Heat Recovery

    DTIC Science & Technology

    1987-09-01

    Based upon "economic analysis of available options, three cost- effective methods of recovering waste heat were identified: the conventional economizer...upon economic analysis of available options, three cost- effective methods of Continued DO I IA.N1 1473 EDITION OF I NOV AS IS OBSOLETE S Y C O OF...energy loss in a boiler is attributable to the hot flue gas leaving the stack. Thus, the most effective method to save fuel is to recover as much

  16. Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers

    SciTech Connect

    Keiser, J.R.

    2001-10-22

    This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

  17. Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers

    SciTech Connect

    Keiser, J.R.

    2000-04-18

    This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

  18. 6. VIEW WESTINTERIOR OF BOILER SHOP SECTION OF THE BETHLEHEM ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    6. VIEW WEST-INTERIOR OF BOILER SHOP SECTION OF THE BETHLEHEM STEEL COMPANY SHIPYARD BLACKSMITH SHOP/BOILER SHOP. - Bethlehem Steel Company Shipyard, Blacksmith Shop-Boiler Shop, 1201-1321 Hudson Street, Hoboken, Hudson County, NJ

  19. 2. VIEW SOUTHWESTNORTH ELEVATION OF BOILER SHOP SECTION OF THE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. VIEW SOUTHWEST-NORTH ELEVATION OF BOILER SHOP SECTION OF THE BETHLEHEM STEEL COMPANY SHIPYARD BLACKSMITH SHOP/BOILER SHOP. - Bethlehem Steel Company Shipyard, Blacksmith Shop-Boiler Shop, 1201-1321 Hudson Street, Hoboken, Hudson County, NJ

  20. 7. VIEW EASTINTERIOR OF BOILER SHOP SECTION OF THE BETHLEHEM ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    7. VIEW EAST-INTERIOR OF BOILER SHOP SECTION OF THE BETHLEHEM STEEL COMPANY SHIPYARD BLACKSMITH SHOP/BOILER SHOP. - Bethlehem Steel Company Shipyard, Blacksmith Shop-Boiler Shop, 1201-1321 Hudson Street, Hoboken, Hudson County, NJ

  1. 12. Forward end of Boiler Room showing open firing doors ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    12. Forward end of Boiler Room showing open firing doors for boilers. Note ladderway retracted overhead by which firemen entered and left Boiler Room. Coal ejectors shown at extreme left of view. - Ferry TICONDEROGA, Route 7, Shelburne, Chittenden County, VT

  2. Looking east at the boiler water treatment tank located off ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking east at the boiler water treatment tank located off the west wall of the boiler house. - Wheeling-Pittsburgh Steel Corporation, Allenport Works, Boiler House, Route 88 on West bank of Monongahela River, Allenport, Washington County, PA

  3. Boiler Emission Compliance Survey, Norton AFB CA

    DTIC Science & Technology

    1989-08-01

    Norton AFB requested AFOEHL assistance to: (1) determine carbon monoxide emissions from each boiler as specified in 40 CFR 60, Appendix A, Reference...Method 10, and (2) determine the oxides of nitrogen emissions from each boiler as specified in 40 CFR 60, Appendix A, Reference Method 7, and for...additional information (3) determine perticulate emissions from each boiler as specified in 40 CFR 60, Appendix A, Reference Methods 1-5. B. Site Description A

  4. Comparative characteristic and erosion behavior of NiCr coatings deposited by various high-velocity oxyfuel spray processes

    NASA Astrophysics Data System (ADS)

    Sidhu, Hazoor Singh; Sidhu, Buta Singh; Prakash, S.

    2006-12-01

    The purpose of this study is to analyze and compare the mechanical properties and microstructure details at the interface of high-velocity oxyfuel (HVOF)-sprayed NiCr-coated boiler tube steels, namely ASTM-SA-210 grade A1, ASTM-SA213-T-11, and ASTM-SA213-T-22. Coatings were developed by two different techniques, and in these techniques liquefied petroleum gas was used as the fuel gas. First, the coatings were characterized by metallographic, scanning electron microscopy/energy-dispersive x-ray analysis, x-ray diffraction, surface roughness, and microhardness, and then were subjected to erosion testing. An attempt has been made to describe the transformations taking place during thermal spraying. It is concluded that the HVOF wire spraying process offers a technically viable and cost-effective alternative to HVOF powder spraying process for applications in an energy generation power plant with a point view of life enhancement and to minimize the tube failures because it gives a coating having better resistance to erosion.

  5. Characteristics of Krakow`s boiler population

    SciTech Connect

    Cyklis, P.; Kowalski, J.; Kroll, J.; Wlodkowski, A.; Zaczkowski, A.; Boron, J.; Butcher, T.

    1994-06-01

    In this paper the characteristics of the local boiler houses and the single-building boilers which are coal-fired are discussed. These sources are seen as particularly important for air quality in Krakow for two reasons. First, these sources have very high emission factors. Unlike the large power plants at Leg and Skawina these smaller boilers do not have high efficiency dust collectors. Also, because of the nature of the boilers they often have high emissions of volatile organics and CO. The second factor which makes these sources so important is their location--very close to residents.

  6. 46 CFR 52.25-5 - Miniature boilers (modifies PMB-1 through PMB-21).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... ENGINEERING POWER BOILERS Other Boiler Types § 52.25-5 Miniature boilers (modifies PMB-1 through PMB-21). Miniature boilers must meet the applicable provisions in this part for the boiler type involved and the...

  7. 46 CFR 52.25-5 - Miniature boilers (modifies PMB-1 through PMB-21).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... ENGINEERING POWER BOILERS Other Boiler Types § 52.25-5 Miniature boilers (modifies PMB-1 through PMB-21). Miniature boilers must meet the applicable provisions in this part for the boiler type involved and the...

  8. 46 CFR 52.25-5 - Miniature boilers (modifies PMB-1 through PMB-21).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... ENGINEERING POWER BOILERS Other Boiler Types § 52.25-5 Miniature boilers (modifies PMB-1 through PMB-21). Miniature boilers must meet the applicable provisions in this part for the boiler type involved and the...

  9. 46 CFR 52.25-5 - Miniature boilers (modifies PMB-1 through PMB-21).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... ENGINEERING POWER BOILERS Other Boiler Types § 52.25-5 Miniature boilers (modifies PMB-1 through PMB-21). Miniature boilers must meet the applicable provisions in this part for the boiler type involved and the...

  10. 46 CFR 52.25-5 - Miniature boilers (modifies PMB-1 through PMB-21).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... ENGINEERING POWER BOILERS Other Boiler Types § 52.25-5 Miniature boilers (modifies PMB-1 through PMB-21). Miniature boilers must meet the applicable provisions in this part for the boiler type involved and the...

  11. Feeding Tubes

    MedlinePlus

    ... Feeding Tubes Health Information Sheet Q & A with Experts Patient Stories Social Security Disability Application Process For Kids ... Feeding Tubes Health Information Sheet Q & A with Experts Patient Stories Social Security Disability Application Process For Kids ...

  12. Study of the possibility of thermal utilization of contaminated water in low-power boilers

    NASA Astrophysics Data System (ADS)

    Roslyakov, P. V.; Proskurin, Y. V.; Zaichenko, M. N.

    2017-09-01

    The utilization of water contaminated with oil products is a topical problem for thermal power plants and boiler houses. It is reasonable to use special water treatment equipment only for large power engineering and industry facilities. Thermal utilization of contaminated water in boiler furnaces is proposed as an alternative version of its utilization. Since there are hot-water fire-tube boilers at many enterprises, it is necessary to study the possibility of thermal utilization of water contaminated with oil products in their furnaces. The object of this study is a KV-GM-2.0 boiler with a heating power of 2 MW. The pressurized burner developed at the Moscow Power Engineering Institute, National Research University, was used as a burner device for supplying liquid fuel. The computational investigations were performed on the basis of the computer simulation of processes of liquid fuel atomization, mixing, ignition, and burnout; in addition, the formation of nitrogen oxides was simulated on the basis of ANSYS Fluent computational dynamics software packages, taking into account radiative and convective heat transfer. Analysis of the results of numerical experiments on the combined supply of crude oil and water contaminated with oil products has shown that the thermal utilization of contaminated water in fire-tube boilers cannot be recommended. The main causes here are the impingement of oil droplets on the walls of the flame tube, as well as the delay in combustion and increased emissions of nitrogen oxides. The thermal utilization of contaminated water combined with diesel fuel can be arranged provided that the water consumption is not more than 3%; however, this increases the emission of nitrogen oxides. The further increase in contaminated water consumption will lead to the reduction of the reliability of the combustion process.

  13. Numerical Calculation of Heat Transfer Distribution in a 600Mwe Supercritical Circulating Fluidized Bed Boiler

    NASA Astrophysics Data System (ADS)

    Li, Y.; Li, W. K.; Wu, Y. X.; Yang, H. R.; Nie, L.; Huo, S. S.

    The water wall heat transfer and heat flux distribution in a 600MWe supercritical CFB boiler with water-cooled panel in the furnace was numerically studied. The water wall was made of smooth tube membrane. The solid suspension density ρ, heat flux q and heat transfer coefficient K distribution in the furnace were predicted at rated boiler load (100%BMCR), 75% of turbine heat acceptance load (75% THA) and 50% THA. The results show that for a large-scale CFB boiler, the convection is the main part of heat transfer in the lower furnace, and radiation is the main in the upper lower. The ρ, q and K have the similar axial and radial distributions. Their radial distributions depend on the position of the water wall and boiler load, and show a peak value in the corner. The ρ is a sensitive to K. With increasing of the height in furnace, ρ decreases, thereby the q and K decrease. The radial distributions of q and K are similar at different height. The study shows that the three-dimensional model is valid to predict the heat transfer in the furnace of the 600MWe supercritical CFB boiler.

  14. Advancement of 10 t/h fluidized bed boiler burning Fujian anthracite with extremely low volatile[ity

    SciTech Connect

    Zhao, C.; Duan, Y.; Chen, X.; Wu, X.; Wu, S.; Wang, W.; Huang, C.

    1999-07-01

    The anthracite in Fujian Province, China with extremely low volatile content about 2--4% is very difficult to burn in grate firing boilers, and operation conditions are very poor, such as steam output well below the nominal capacity and very low burning-out rate. Burning Fujian anthracite in specially designed bubbling fluidized bed (BFB) boilers with capacities between 4 T/H and 20 T/H are still unsatisfactory. In order to increase boiler output and utilize local coal more efficiently, a 10 T/H BFB boiler burning Fujian anthracite was retrofitted with several special techniques, in terms of underbed feeding of recycling fly ash, vortexing secondary air injection, continuous bottom ash removal and adding immersed tube surface. The boiler performances before and after the retrofitting were measured and compared. The experimental results indicate that steam output of the boiler is boosted from 7--8 T/H to more than 14 T/H, unburned carbon content (UBC) in ash from the convective banks drops from 31.39% to 3.89%, UBC in ash from the multicyclone drops from 38.87% to 22.19%, and UBC in fly ash drops from 35.3% to 18.07%. The boiler thermal efficiency increases from 67.27% to 82.93%. Boiler operation becomes more stable. Particulate emission is substantially lessened because of separation by the vortexing secondary air. The retrofitting was completely successful. The technique used and experiences obtained in the retrofitting can be widely applied in industrial BFB boilers.

  15. Characteristics of a Modified Bell Jar Nozzle Designed for CFB Boilers

    NASA Astrophysics Data System (ADS)

    Huang, Z. M.; Yang, H. R.; Liu, Q.; Wang, Y.; Lu, J. F.; Yue, G. X.

    One of the most important factors for trouble free operation of CFB boilers is the pressure drop of the gas distributor. The pressure drop characteristic of the gas distributor depends on the nozzles used. A modified bell jar nozzle was designed and developed for use with large-scale industrial circulating fluidized bed (CFB) boilers. The nozzle consists of a vertically tapered tube with a larger end at the top, a float which is free to move within the tube and a cover with holes. The pressure drop characteristics of the nozzle were measured experimentally by using different floats and moving out the float respectively. The gas distributor equipped with the modified bell jar nozzle has a unique pressure drop characteristic. It has a higher resistance than other nozzles which results in the formation of an effective barrier against backflow at low boiler loads, which results from the pressure fluctuation caused by bubble burst and solids coming from the recycle system. In addition, it has a relatively low pressure drop at high or full boiler loads, which can greatly reduce the energy cost of the primary air fan.

  16. Boiler efficiency calculation for multiple fuel burning boilers

    SciTech Connect

    Khodabakhsh, F.; Munukutla, S.; Clary, A.T.

    1996-12-31

    A rigorous method based on the output/loss approach is developed for calculating the coal flow rate for multiple fuel burning boilers. It is assumed that the ultimate analyses of all the fuels are known. In addition, it is assumed that the flow rates of all the fuels with the exception of coal are known. The calculations are performed iteratively, with the first iteration taking into consideration coal as the only fuel. The results converge to the correct answer after a few number of iterations, typically four or five.

  17. Tracheostomy tubes.

    PubMed

    Hess, Dean R; Altobelli, Neila P

    2014-06-01

    Tracheostomy tubes are used to administer positive-pressure ventilation, to provide a patent airway, and to provide access to the lower respiratory tract for airway clearance. They are available in a variety of sizes and styles from several manufacturers. The dimensions of tracheostomy tubes are given by their inner diameter, outer diameter, length, and curvature. Differences in dimensions between tubes with the same inner diameter from different manufacturers are not commonly appreciated but may have important clinical implications. Tracheostomy tubes can be cuffed or uncuffed and may be fenestrated. Some tracheostomy tubes are designed with an inner cannula. It is important for clinicians caring for patients with a tracheostomy tube to appreciate the nuances of various tracheostomy tube designs and to select a tube that appropriately fits the patient. The optimal frequency of changing a chronic tracheostomy tube is controversial. Specialized teams may be useful in managing patients with a tracheostomy. Speech can be facilitated with a speaking valve in patients with a tracheostomy tube who are breathing spontaneously. In mechanically ventilated patients with a tracheostomy, a talking tracheostomy tube, a deflated cuff technique with a speaking valve, or a deflated cuff technique without a speaking valve can be used to facilitate speech. Copyright © 2014 by Daedalus Enterprises.

  18. 46 CFR 109.555 - Propulsion boilers.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Propulsion boilers. 109.555 Section 109.555 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS OPERATIONS Miscellaneous § 109.555 Propulsion boilers. The master or person in charge and the engineer in charge shall...

  19. Wood fueled boiler financial feasibility user's manual

    Treesearch

    Robert Govett; Scott Bowe; Terry Mace; Steve Hubbard; John (Rusty) Dramm; Richard Bergman

    2005-01-01

    “Wood Fueled Boiler Financial Feasibility” is a spreadsheet program designed for easy use on a personal computer. This program provides a starting point for interested parties to perform financial feasibility analysis of a steam boiler system for space heating or process heat. By allowing users to input the conditions applicable to their current or proposed fuel...

  20. 46 CFR 109.555 - Propulsion boilers.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Propulsion boilers. 109.555 Section 109.555 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS OPERATIONS Miscellaneous § 109.555 Propulsion boilers. The master or person in charge and the engineer in charge shall...

  1. 46 CFR 109.555 - Propulsion boilers.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 4 2013-10-01 2013-10-01 false Propulsion boilers. 109.555 Section 109.555 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS OPERATIONS Miscellaneous § 109.555 Propulsion boilers. The master or person in charge and the engineer in charge shall...

  2. 46 CFR 109.555 - Propulsion boilers.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Propulsion boilers. 109.555 Section 109.555 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS OPERATIONS Miscellaneous § 109.555 Propulsion boilers. The master or person in charge and the engineer in charge shall...

  3. 46 CFR 109.555 - Propulsion boilers.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Propulsion boilers. 109.555 Section 109.555 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) A-MOBILE OFFSHORE DRILLING UNITS OPERATIONS Miscellaneous § 109.555 Propulsion boilers. The master or person in charge and the engineer in charge shall...

  4. Baghouse cleans flyash from boiler exhaust

    SciTech Connect

    Not Available

    1981-02-01

    A large baghouse installation recently started up on the boilerhouse of the Avtex Fibers Inc. rayon plant in Front Royal, Virginia. The baghouse removes 99.7% of the flyash particulate from the combustion fumes of five coal-fired boilers. The boilers have a combined capacity of one million lb/h of steam. Emissions from the plant are well below EPA limitations.

  5. Latest Development of CFB Boilers in China

    NASA Astrophysics Data System (ADS)

    Yue, G. X.; Yang, H. R.; Lu, J. F.; Zhang, H.

    The circulating fluidized bed (CFB) coal-fired boiler has being rapidly developed in China since 1980s and becomes a key clean coal technology used in thermal and power generation. In this paper, the development history and development status of the CFB boiler in China are introduced. The development history of the CFB boiler in China is divided into four periods and the important features of each period are given. Some latest research activities and important results on CFB boilers, and the typical achievements and newest development of the CFB boiler in China are also introduced. In addition, a few challenges and development directions including the capacity scaling up, SO2 removal and energy saving are discussed.

  6. PAH emission from the industrial boilers.

    PubMed

    Li, C; Mi, H; Lee, W; You, W; Wang, Y

    1999-10-01

    Polycyclic aromatic hydrocarbons (PAHs) emitted from 25 industrial boilers were investigated. The fuels used for these 25 boilers included 21 heavy oil, two diesel, a co-combustion of heavy oil and natural gas (HO+NG) and a co-combustion of coke oven gas and blast furnace gas (COG+BFG) boilers. PAH samples from the stack flue gas (gas and particle phases) of these 25 boilers were collected by using a PAH stack sampling system. Twenty one individual PAHs were analyzed primarily by a gas chromatography/mass spectrometer (GC/MS). Total-PAH concentration in the flue gas of 83 measured data for these 25 boiler stacks ranged between 29.0 and 4250 microg/m(3) and averaged 488 microg/m(3). The average of PAH-homologue mass (F%) counted for the total-PAH mass was 54.7%, 9.47% and 15.3% for the 2-ring, 3-ring and 4-ring PAHs, respectively. The PAHs in the stack flue gas were dominant in the lower molecular weight PAHs. The emission factors (EFs) of total-PAHs were 13,300, 2920, 2880 and 208 microg/kg-fuel for the heavy oil, diesel, HO+NG and COG+BFG fueled-boiler, respectively. Nap was the most predominant PAH occurring in the stack flue gas. In addition, the EF of 21 individual PAHs in heavy-oil boiler were almost the highest among the four various fueled-boilers except for those of FL and BkF in the diesel boiler. Furthermore, the EF of total-PAHs or BaP for heavy oil were both one order of magnitude higher than that for the diesel-fueled boiler.

  7. 40 CFR 65.149 - Boilers and process heaters.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... thermal units per hour) or greater. (ii) A boiler or process heater into which the vent stream is... 40 Protection of Environment 15 2010-07-01 2010-07-01 false Boilers and process heaters. 65.149... System or a Process § 65.149 Boilers and process heaters. (a) Boiler and process heater equipment...

  8. Looking east at the west wall of the boiler house, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking east at the west wall of the boiler house, boiler water treatment tank, and waste gas stack. Water tower is to the left of the boiler house. - Wheeling-Pittsburgh Steel Corporation, Allenport Works, Boiler House, Route 88 on West bank of Monongahela River, Allenport, Washington County, PA

  9. Retrofitted coal-fired firetube boiler and method employed therewith

    DOEpatents

    Wagoner, Charles L.; Foote, John P.

    1995-01-01

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler, the converted boiler including a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones.

  10. Retrofitted coal-fired firetube boiler and method employed therewith

    DOEpatents

    Wagoner, C.L.; Foote, J.P.

    1995-07-04

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler are disclosed. The converted boiler includes a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones. 19 figs.

  11. 24. VIEW OF FIRING AISLE OF EAST BOILER ROOM LOOKING ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    24. VIEW OF FIRING AISLE OF EAST BOILER ROOM LOOKING SOUTH. BOILERS 900 AND 901 ARE ON THE RIGHT, BOILERS 902, 903, AND 904 ARE ON THE LEFT. NOTE REMAINS OF THE LARRY CAR TRACK SYSTEM FOR TRANSFERRING COAL TO BOILER HOPPERS ABOVE THE AISLE. - New York, New Haven & Hartford Railroad, Cos Cob Power Plant, Sound Shore Drive, Greenwich, Fairfield County, CT

  12. 49 CFR 230.36 - Hydrostatic testing of boilers.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Hydrostatic testing of boilers. 230.36 Section 230... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Pressure Testing of Boilers § 230.36 Hydrostatic testing of boilers. (a) Time of test....

  13. 40 CFR 65.149 - Boilers and process heaters.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 15 2011-07-01 2011-07-01 false Boilers and process heaters. 65.149... System or a Process § 65.149 Boilers and process heaters. (a) Boiler and process heater equipment and operating requirements. (1) Owners or operators using boilers and process heaters to meet the 98...

  14. 46 CFR 61.05-15 - Boiler mountings and attachments.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 2 2011-10-01 2011-10-01 false Boiler mountings and attachments. 61.05-15 Section 61.05... TESTS AND INSPECTIONS Tests and Inspections of Boilers § 61.05-15 Boiler mountings and attachments. (a....05-10. (b) Each stud or bolt for each boiler mounting that paragraph (c) of this section requires...

  15. 49 CFR 230.36 - Hydrostatic testing of boilers.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 4 2012-10-01 2012-10-01 false Hydrostatic testing of boilers. 230.36 Section 230... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Pressure Testing of Boilers § 230.36 Hydrostatic testing of boilers. (a) Time of test....

  16. 49 CFR 230.30 - Lap-joint seam boilers.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 4 2014-10-01 2014-10-01 false Lap-joint seam boilers. 230.30 Section 230.30..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Inspection and Repair § 230.30 Lap-joint seam boilers. Every boiler having lap-joint longitudinal...

  17. 49 CFR 230.30 - Lap-joint seam boilers.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 4 2012-10-01 2012-10-01 false Lap-joint seam boilers. 230.30 Section 230.30..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Inspection and Repair § 230.30 Lap-joint seam boilers. Every boiler having lap-joint longitudinal...

  18. 46 CFR 61.05-15 - Boiler mountings and attachments.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 2 2014-10-01 2014-10-01 false Boiler mountings and attachments. 61.05-15 Section 61.05... TESTS AND INSPECTIONS Tests and Inspections of Boilers § 61.05-15 Boiler mountings and attachments. (a....05-10. (b) Each stud or bolt for each boiler mounting that paragraph (c) of this section requires...

  19. 49 CFR 230.30 - Lap-joint seam boilers.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 4 2013-10-01 2013-10-01 false Lap-joint seam boilers. 230.30 Section 230.30..., DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Inspection and Repair § 230.30 Lap-joint seam boilers. Every boiler having lap-joint longitudinal...

  20. 49 CFR 230.36 - Hydrostatic testing of boilers.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 4 2013-10-01 2013-10-01 false Hydrostatic testing of boilers. 230.36 Section 230... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Pressure Testing of Boilers § 230.36 Hydrostatic testing of boilers. (a) Time of test....

  1. 49 CFR 230.36 - Hydrostatic testing of boilers.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 4 2014-10-01 2014-10-01 false Hydrostatic testing of boilers. 230.36 Section 230... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Pressure Testing of Boilers § 230.36 Hydrostatic testing of boilers. (a) Time of test....

  2. 46 CFR 61.05-15 - Boiler mountings and attachments.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Boiler mountings and attachments. 61.05-15 Section 61.05... TESTS AND INSPECTIONS Tests and Inspections of Boilers § 61.05-15 Boiler mountings and attachments. (a....05-10. (b) Each stud or bolt for each boiler mounting that paragraph (c) of this section requires...

  3. 49 CFR 230.36 - Hydrostatic testing of boilers.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 4 2011-10-01 2011-10-01 false Hydrostatic testing of boilers. 230.36 Section 230... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION STEAM LOCOMOTIVE INSPECTION AND MAINTENANCE STANDARDS Boilers and Appurtenances Pressure Testing of Boilers § 230.36 Hydrostatic testing of boilers. (a) Time of test....

  4. 40 CFR 65.149 - Boilers and process heaters.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 16 2013-07-01 2013-07-01 false Boilers and process heaters. 65.149... System or a Process § 65.149 Boilers and process heaters. (a) Boiler and process heater equipment and operating requirements. (1) Owners or operators using boilers and process heaters to meet the 98...

  5. 40 CFR 65.149 - Boilers and process heaters.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 16 2014-07-01 2014-07-01 false Boilers and process heaters. 65.149... System or a Process § 65.149 Boilers and process heaters. (a) Boiler and process heater equipment and operating requirements. (1) Owners or operators using boilers and process heaters to meet the 98...

  6. 40 CFR 65.149 - Boilers and process heaters.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 16 2012-07-01 2012-07-01 false Boilers and process heaters. 65.149... System or a Process § 65.149 Boilers and process heaters. (a) Boiler and process heater equipment and operating requirements. (1) Owners or operators using boilers and process heaters to meet the 98...

  7. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding; Robert Hurt

    2003-12-31

    This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.

  8. Feeding tube insertion - gastrostomy

    MedlinePlus

    ... tube insertion; G-tube insertion; PEG tube insertion; Stomach tube insertion; Percutaneous endoscopic gastrostomy tube insertion ... and down the esophagus, which leads to the stomach. After the endoscopy tube is inserted, the skin ...

  9. The critical issues of Indian coal fired utility boiler operation

    SciTech Connect

    Sanyal, A.; Roy, C.

    1998-07-01

    The operational experience of 26 pulverized coal fired utility units--14 x 200/210 MW and 12 x 500 MW of 5 plants of National Thermal Power Corporation has been reviewed. The operational problems included--excessive superheater and reheater spray, high metal temperature, excessive tube failure, low life of grinding elements, clinkering/slagging despite using non-slagging coal and high back end temperature. As a result, the turbine heat rate increased by over 1% and the plant load factor was around 60%. A detailed investigation carried out by means of FrameTrack, a state of the art boiler model, revealed off design heat adsorption by both the radiant and convective zones due to the under size furnace design. This arose from the vendors' inadequate experience of the unique slow burning characteristics of inertinite rich and highly abrasive Indian coal. The grinding element material was modified and the heat transfer surfaces were adjusted in accordance with the heat adsorption profiles of the individual units to suit the individual coal quality. These resulted in significant improvement in the operation of the units with respect to the grinding element life, spray requirement, plant load factor and heat rate. Guidelines were devised for coal specific boiler design and bid evaluation protocol. These are of value to the owners and the vendors alike for future use.

  10. Critical issues of Indian coal fired utility boiler operation

    SciTech Connect

    Sanyal, A.; Roy, C.

    1998-04-01

    The operational experience of 26 pulverized coal fired utility units- 14 x 200/210 MW and 12 x 500 MW of 5 plants of National Thermal Power Corporation has been reviewed. The operational problems included - excessive superheater and reheater spray, high metal temperature, excessive tube failure, low life of grinding elements, clinkering/slagging despite using non-slagging coal and high back end temperature. As a result, the turbine heat rate increased by over 1% and the plant load factor was around 60%. A detailed investigation carried out by means of `FlameTrack`, a state of the art boiler model, revealed `off design` heat absorption by both the radiant and convective zones due to the under size furnace design. This arose from the vendors` inadequate experience of the unique `slow` burning characteristics of inertinite rich and highly abrasive Indian coal. The grinding element material was modified and the heat transfer surfaces were adjusted in accordance with the heat absorption profiles of the individual units to suit the individual coal quality. These resulted in significant improvement in the operation of the units with respect to the grinding element life, spray requirement, plant load factor and heat rate. Guidelines were devised for coal specific boiler design and bid evaluation protocol. These are of value to the owners and the vendors alike for future use.

  11. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect

    Mike Bockelie; Kevin Davis; Connie Senior Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-09-30

    This is the seventeenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. The SCR slipstream reactor was assembled and installed at Plant Gadsden this quarter. Safety equipment for ammonia had not been installed at the end of the quarter, but will be installed at the beginning of next quarter. The reactor will be started up next quarter. Four ECN corrosion probes were reinstalled at Gavin and collected corrosion data for approximately one month. Two additional probes were installed and removed after about 30 hours for future profilometry analysis. Preliminary analysis of the ECN probes, the KEMA coupons and the CFD modeling results all agree with the ultrasonic tube test measurements gathered by AEP personnel.

  12. Loss of feed flow, steam generator tube rupture and steam line break thermohydraulic experiments

    SciTech Connect

    Mendler, O J; Takeuchi, K; Young, M Y

    1986-10-01

    The Westinghouse Model Boiler No. 2 (MB-2) steam generator test model at the Engineering Test Facility in Tampa, Florida, was reinstrumented and modified for performing a series of tests simulating steam generator accident transients. The transients simulated were: loss of feed flow, steam generator tube rupture, and steam line break events. This document presents a description of (1) the model boiler and the associated test facility, (2) the tests performed, and (3) the analyses of the test results.

  13. Numerical Simulation in a Supercirtical CFB Boiler

    NASA Astrophysics Data System (ADS)

    Zhang, Yanjun; Gaol, Xiang; Luo, Zhongyang; Jiang, Xiaoguo

    The dimension of the hot circulation loop of the supercritical CFB boiler is large, and there are many unknowns and challenges that should be identified and resolved during the development. In order to realize a reasonable and reliable design of the hot circulation loop, numerical simulation of gas-solid flow in a supercritical CFB boiler was conducted by using FLUENT software. The working condition of hot circulation loop flow field, gas-solid flow affected by three unsymmetrical cyclones, air distribution and pressure drop in furnace were analyzed. The simulation results showed that the general arrangement of the 600MWe supercritical CFB boiler is reasonable.

  14. CONDENSING ECONOMIZERS FOR SMALL COAL-FIRED BOILERS AND FURNACES PROJECT REPORT - JANUARY 1994

    SciTech Connect

    BUTCHER,T.A.

    1994-01-04

    Condensing economizers increase the thermal efficiency of boilers by recovering sensible and latent heat from exhaust gas. These economizers are currently being used commercially for this purpose in a wide range of applications. Performance is dependent upon application-specific factors affecting the utility of recovered heat. With the addition of a condensing economizer boiler efficiency improvements up to 10% are possible. Condensing economizers can also capture flue gas particulates. In this work, the potential use of condensing economizers for both efficiency improvement and control of particulate emissions from small, coal water slurry-fired boilers was evaluated. Analysis was done to predict heat transfer and particulate capture by mechanisms including: inertial impaction, interception, diffusion, thermophoretic forces, and condensation growth. Shell-and-tube geometries were considered with flue gas on the outside of Teflon-covered tubes. Experimental studies were done with both air- and water-cooled economizers refit to a small boiler. Two experimental arrangements were used including oil-firing with injection of flyash upstream of the economizer and direct coal water slurry firing. Firing rates ranged from 27 to 82 kW (92,000 to 280,000 Btu/hr). Inertial impaction was found to be the most important particulate capture mechanism and removal efficiencies to 95% were achieved. With the addition of water sprays directly on the first row of tubes, removal efficiencies increased to 98%. Use of these sprays adversely affects heat recovery. Primary benefits of the sprays are seen to be the addition of small impaction sites and future design improvements are suggested in which such small impacts are permanently added to the highest velocity regions of the economizer. Predicted effects of these added impactors on particulate removal and pressure drop are presented.

  15. Advanced AN/TPQ-37 Transmitter Tube.

    DTIC Science & Technology

    1980-08-01

    TUBE ( TWT ) PPM FOCUSING OUTPUT VSWR HIGH POWER SAMARIUM COBALT RELIABILITY GRID PULSED ISOLATED ANODE OSMIUM-RUTHENIUM COATED CATHODE GAIN VARIATIONS...of the AN/TPQ- 37 transmitter tube. The task is to build and test two high power, PPM focused, grid pulsed Traveling Wave Tube ( TWT ) that meet the...requirements of Technical Guidelines MW-119B. The TWT will employ a M-type cathode for reduced temperature operation and extended life. Gain variations

  16. Cracking of Composite Modified Alloy 825 Primary Air Port Tubes

    SciTech Connect

    Kish, Joseph R.; Keiser, James R; Singbeil, Douglas; Willoughby, Adam W; Longmire, Hu Foster

    2007-04-01

    Twenty primary air ports fabricated from modified Alloy 825-based composite tubes underwent a metallurgical examination to document the mode and extent of cracking on the external fireside surface of a kraft recovery boiler. Collectively, the crack features found are most consistent with thermal fatigue, but corrosion fatigue cannot be ruled out. Regardless of the true cracking mechanism, temperature cycling is implicated as a critical factor for crack propagation. on the basis of the relative crack lengths observed, membrane welds and tube weld repairs, and their adjacent heat-affected zones, appear to be more susceptible to cracking than the cladding itself. This work suggests that mills should avoid boiler operating conditions that promote large temperature fluctuations, which can cause Alloy 825-based composite tubes to crack.

  17. Film Condensation of Steam on Externally Finned Horizontal Tubes.

    DTIC Science & Technology

    1985-03-01

    portion of the tube. Differential eguations were obtained for the height of condensate between fin bases, and tempera - ture distribution along the fin...boiler input power. A more detailed descrip- tion of the boiler power supply is provided by Poole (6]. The internal system pressure was measured manually ...0.2 K ir the steam tempera - ture, or an error of _ 1.0 mmHg in the system pressure would lead to an error of ± 1.2 percent in the non-condensing

  18. Gastrostomy Tube (G-Tube)

    MedlinePlus

    ... warmth at the tube site; discharge that's yellow, green, or foul-smelling; fever) excessive bleeding or drainage from the tube site severe abdominal pain persistent vomiting or diarrhea trouble passing gas or having a bowel movement pink-red tissue (called granulation tissue) coming out ...

  19. Exploiting the On-Campus Boiler House.

    ERIC Educational Resources Information Center

    Woods, Donald R.; And Others

    1986-01-01

    Shows how a university utility building ("boiler house") is used in a chemical engineering course for computer simulations, mathematical modeling and process problem exercises. Student projects involving the facility are also discussed. (JN)

  20. Exploiting the On-Campus Boiler House.

    ERIC Educational Resources Information Center

    Woods, Donald R.; And Others

    1986-01-01

    Shows how a university utility building ("boiler house") is used in a chemical engineering course for computer simulations, mathematical modeling and process problem exercises. Student projects involving the facility are also discussed. (JN)

  1. New thinking for the boiler room.

    PubMed

    Rose, Wayne

    2008-09-01

    Wayne Rose, marketing manager at integrated plant room manufacturer Armstrong Integrated Systems, explains how increasing use of off-site manufacture, the latest 3D modelling technology, and advances in control technology, are revolutionising boiler room design and construction.

  2. Boiler scale prevention employing an organic chelant

    DOEpatents

    Wallace, Steven L.; Griffin, Jr., Freddie; Tvedt, Jr., Thorwald J.

    1984-01-01

    An improved method of treating boiler water which employs an oxygen scavenging compound and a compound to control pH together with a chelating agent, wherein the chelating agent is hydroxyethylethylenediaminetriacetic acid.

  3. Alkali metal pool boiler life tests for a 25 kWe advanced Stirling conversion system

    NASA Technical Reports Server (NTRS)

    Anderson, W. G.; Rosenfeld, J. H.; Noble, J.

    1991-01-01

    The overall operating temperature and efficiency of solar-powered Stirling engines can be improved by adding an alkali metal pool boiler heat transport system to supply heat more uniformly to the heater head tubes. One issue with liquid metal pool boilers is unstable boiling. Stable boiling is obtained with an enhanced boiling surface containing nucleation sites that promote continuous boiling. Over longer time periods, it is possible that the boiling behavior of the system will change. An 800-h life test was conducted to verify that pool boiling with the chosen fluid/surface combination remains stable as the system ages. The apparatus uses NaK boiling on a - 100 + 140 stainless steel sintered porous layer, with the addition of a small amount of xenon. Pool boiling remained stable to the end of life test. The pool boiler life test included a total of 82 cold starts, to simulate startup each morning, and 60 warm restarts, to simulate cloud cover transients. The behavior of the cold and warm starts showed no significant changes during the life test. In the experiments, the fluid/surface combination provided stable, high-performance boiling at the operating temperature of 700 C. Based on these experiments, a pool boiler was designed for a full-scale 25-kWe Stirling system.

  4. Alkali metal pool boiler life tests for a 25 kWe advanced Stirling conversion system

    NASA Technical Reports Server (NTRS)

    Anderson, W. G.; Rosenfeld, J. H.; Noble, J.

    1991-01-01

    The overall operating temperature and efficiency of solar-powered Stirling engines can be improved by adding an alkali metal pool boiler heat transport system to supply heat more uniformly to the heater head tubes. One issue with liquid metal pool boilers is unstable boiling. Stable boiling is obtained with an enhanced boiling surface containing nucleation sites that promote continuous boiling. Over longer time periods, it is possible that the boiling behavior of the system will change. An 800-h life test was conducted to verify that pool boiling with the chosen fluid/surface combination remains stable as the system ages. The apparatus uses NaK boiling on a - 100 + 140 stainless steel sintered porous layer, with the addition of a small amount of xenon. Pool boiling remained stable to the end of life test. The pool boiler life test included a total of 82 cold starts, to simulate startup each morning, and 60 warm restarts, to simulate cloud cover transients. The behavior of the cold and warm starts showed no significant changes during the life test. In the experiments, the fluid/surface combination provided stable, high-performance boiling at the operating temperature of 700 C. Based on these experiments, a pool boiler was designed for a full-scale 25-kWe Stirling system.

  5. Boiler burden reduced at Bedford site.

    PubMed

    Horsley, Chris

    2011-10-01

    With the NHS aiming to reduce its 2007 carbon footprint by 10% by 2015, Chris Horsley, managing director of Babcock Wanson UK, a provider of industrial boilers and burners, thermal oxidisers, air treatment, water treatment, and associated services, looks at how one NHS Trust has approached the challenge, and considerably reduced its carbon emissions, by refurbishing its boiler house and moving from oil to gas-fired steam generation.

  6. Research and Development of Large Capacity CFB Boilers in TPRI

    NASA Astrophysics Data System (ADS)

    Xianbin, Sun; Minhua, Jiang

    This paper presents an overview of advancements of circulating fluidized bed (CFB) technology in Thermal Power Research Institute (TPRI),including technologies and configuration and progress of scaling up. For devoloping large CFB boiler, the CFB combustion test facilities have been established, the key technologies of large capacity CFB boiler have been research systematically, the 100MW ˜330MW CFB boiler have been developed and manufactured. The first domestically designed 100MW and 210MW CFB boiler have been put into commericial operation and have good operating performance. Domestic 330MW CFB boiler demonstration project also has been put into commericial operation,which is H type CFB boiler with Compact heat exchanger. This boiler is China's largest CFB boiler. The technical plan of domestic 600MW supercritical CFB boiler are also briefly introduced.

  7. Foster Wheeler compact CFB boiler with INTREX

    SciTech Connect

    Hyppaenen, T.; Rainio, A.; Kauppinen, K.V.O.; Stone, J.E.

    1997-12-31

    Foster Wheeler has introduced a new COMPACT Circulating Fluidized Bed (CFB) boiler design based on the rectangular hot solids separator. The Compact design also enables easy implementation of new designs for INTREX fluid bed heat exchangers. These new products result in many benefits which affect the boiler economy and operation. After initial development of the Compact CFB design it has been applied in demonstration and industrial scale units. The performance of Compact CFB has been proved to be equivalent to conventional Foster Wheeler CFB has been proved to be equivalent to conventional Foster Wheeler CFB boilers with high availability. Several new Foster Wheeler Compact boilers are being built or already in operation. Operational experiences from different units will be discussed in this paper. There are currently Compact units with 100--150 MW{sub e} capacity under construction. With the scale-up experience with conventional CFB boilers and proven design approach and scale-up steps, Foster Wheeler will have the ability to provide large Compact CFB boilers up to 400--600 MW{sub e} capacity.

  8. Assessment of physical workload in boiler operations.

    PubMed

    Rodrigues, Valéria Antônia Justino; Braga, Camila Soares; Campos, Julio César Costa; Souza, Amaury Paulo de; Minette, Luciano José; Sensato, Guilherme Luciano; Moraes, Angelo Casali de; Silva, Emília Pio da

    2012-01-01

    The use of boiler wood-fired is fairly common equipment utilized in steam generation for energy production in small industries. The boiler activities are considered dangerous and heavy, mainly due to risks of explosions and the lack of mechanization of the process. This study assessed the burden of physical labor that operators of boilers are subjected during the workday. Assessment of these conditions was carried out through quantitative and qualitative measurements. A heart rate monitor, a wet-bulb globe thermometer (WBGT), a tape-measure and a digital infrared camera were the instruments used to collect the quantitative data. The Nordic Questionnaire and the Painful Areas Diagram were used to relate the health problems of the boiler operator with activity. With study, was concluded that the boiler activity may cause pains in the body of intensity different, muscle fatigue and diseases due to excessive weight and the exposure to heat. The research contributed to improve the boiler operator's workplace and working conditions.

  9. Optimization of Drilling Parameters for Reducing the Burr Height in Machining the Silicon Carbide Particle (SiCp) Coated with Multi Wall Carbon Nano Tubes (MWCNT) Reinforced in Aluminum Alloy (A 356) Using Meta Modeling Approach

    NASA Astrophysics Data System (ADS)

    Sangeetha, M.; Prakash, S.

    2017-05-01

    This paper explains the optimization of drilling parameters using meta modeling approach to reduce the burr height while machining Silicon Carbide Particle (SiCp) coated with Multi Wall Carbon Nano Tubes (MWCNT) and reinforced in aluminum alloy (A 356). The specimen is prepared by the combination of sonication and stir casting processes. The volume fraction of MWCNT used is 1.5% and the volume fraction of SiCp is 10%. The combination of input parameters for drilling the holes is designed using Taguchi experimental design technique. The input parameters chosen for drilling operations are spindle speed, feed rate and drill diameter. The ranges of input parameters are listed in Table 1. The tools used for drilling operation are made up of solid carbide drill bit. Meta model is a mathematical and statistical model whose second-order model can be fitted by factorial design. The optimization model can be improved significantly by the second-order model compared to the first-order model. Twenty-seven holes are drilled using vertical machining center in the prepared specimen (A 356/MWCNT coated SiCp). Desirability function shows the optimized values of input parameters to obtain minimum burr height. Meta modeling approach is used to design a model using input parameters and output response burr height. The residuals plot shows the predicted values are closer to the measured values. This plot explains that the Meta model is adequately used to predict the burr height. The optimized values of input parameters for obtaining minimum burr height are the combination of high speed, low feed and low drill diameter. The minimum value of burr height observed in this experiment is 0.002mm and it is obtained in the optimized combination of N3, f1 and d1.

  10. {open_quotes}The next generations of Tampella Power`s CFB boilers{close_quotes}

    SciTech Connect

    Alliston, M.G.

    1995-12-31

    The next generation of Tampella Power Corporation`s CFB boilers is discussed in outline form. The following topics are outlined: CFB boiler advantages, CFB boiler fuel flexibility and CYMIC boiler construction.

  11. 75 FR 64250 - Certain Welded Carbon Steel Pipe and Tube From Turkey: Notice of Final Antidumping Duty...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-19

    ... this order, except for line pipe, oil country tubular goods, boiler tubing, cold- drawn or cold-rolled... International Trade Administration Certain Welded Carbon Steel Pipe and Tube From Turkey: Notice of Final... the preliminary results of the antidumping duty administrative review of certain welded carbon...

  12. Protective tubes for sodium heated water tubes

    DOEpatents

    Essebaggers, Jan

    1979-01-01

    A heat exchanger in which water tubes are heated by liquid sodium which minimizes the results of accidental contact between the water and the sodium caused by failure of one or more of the water tubes. A cylindrical protective tube envelopes each water tube and the sodium flows axially in the annular spaces between the protective tubes and the water tubes.

  13. Boiler materials for ultra supercritical coal power plants

    SciTech Connect

    Purgert, Robert; Shingledecker, John; Pschirer, James; Ganta, Reddy; Weitzel, Paul; Sarver, Jeff; Vitalis, Brian; Gagliano, Michael; Stanko, Greg; Tortorelli, Peter

    2015-12-29

    materials selection and application under a range of conditions prevailing in the boiler. A major effort involving eight tasks was completed in Phase 1. In a subsequent Phase 2 extension, the earlier defined tasks were extended to finish and enhance the Phase 1 activities. This extension included efforts in improved weld/weldment performance, development of longer-term material property databases, additional field (in-plant) corrosion testing, improved understanding of long-term oxidation kinetics and exfoliation, cyclic operation, and fabrication methods for waterwalls. In addition, preliminary work was undertaken to model an oxyfuel boiler to define local environments expected to occur and to study corrosion behavior of alloys under these conditions. This final technical report provides a comprehensive summary of all the work undertaken by the consortium and the research findings from all eight (8) technical tasks including A-USC boiler design and economics (Task 1), long-term materials properties (Task 2), steam- side oxidation (Task 3), Fireside Corrosion (Task 4), Welding (Task 5), Fabricability (Task 6), Coatings (Task 7), and Design Data and Rules (Task 8).

  14. 33. VIEW OF BASEMENT UNDER EAST BOILER ROOM LOOKING TOWARD ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    33. VIEW OF BASEMENT UNDER EAST BOILER ROOM LOOKING TOWARD WEST BOILER ROOM BASEMENT THROUGH THE ASH TRANSFER TUNNEL. ASH HOPPER FOR BOILER 900 IS ON THE RIGHT. NOTE THE TRACKS ALONG THE FLOOR OF THE TUNNEL. A SMALL ELECTRIC LOCOMOTIVE HAULED CARS FOR TRANSFERRING ASH FROM BOILERS TO DISPOSAL SITES OUTSIDE THE BUILDING. THIS SYSTEM BECAME OBSOLETE IN 1938 WHEN BOILERS IN THE WEST BOILER ROOM WERE REMOVED AND PULVERIZED COAL WAS ADOPTED AS THE FUEL. - New York, New Haven & Hartford Railroad, Cos Cob Power Plant, Sound Shore Drive, Greenwich, Fairfield County, CT

  15. Sodium reflux pool-boiler solar receiver on-sun test results

    SciTech Connect

    Andraka, C E; Moreno, J B; Diver, R B; Moss, T A

    1992-06-01

    The efficient operation of a Stirling engine requires the application of a high heat flux to the relatively small area occupied by the heater head tubes. Previous attempts to couple solar energy to Stirling engines generally involved directly illuminating the heater head tubes with concentrated sunlight. In this study, operation of a 75-kW{sub t} sodium reflux pool-boiler solar receiver has been demonstrated and its performance characterized on Sandia's nominal 75-kW{sub t} parabolic-dish concentrator, using a cold-water gas-gap calorimeter to simulate Stirling engine operation. The pool boiler (and more generally liquid-metal reflux receivers) supplies heat to the engine in the form of latent heat released from condensation of the metal vapor on the heater head tubes. The advantages of the pool boiler include uniform tube temperature, leading to longer life and higher temperature available to the engine, and decoupling of the design of the solar absorber from the engine heater head. The two-phase system allows high input thermal flux, reducing the receiver size and losses, therefore improving system efficiency. The receiver thermal efficiency was about 90% when operated at full power and 800{degree}C. Stable sodium boiling was promoted by the addition of 35 equally spaced artificial cavities in the wetted absorber surface. High incipient boiling superheats following cloud transients were suppressed passively by the addition of small amounts of xenon gas to the receiver volume. Stable boiling without excessive incipient boiling superheats was observed under all operating conditions. The receiver developed a leak during performance evaluation, terminating the testing after accumulating about 50 hours on sun. The receiver design is reported here along with test results including transient operations, steady-state performance evaluation, operation at various temperatures, infrared thermography, x-ray studies of the boiling behavior, and a postmortem analysis.

  16. Sodium reflux pool-boiler solar receiver on-sun test results

    NASA Astrophysics Data System (ADS)

    Andraka, C. E.; Moreno, J. B.; Diver, R. B.; Moss, T. A.

    1992-06-01

    The efficient operation of a Stirling engine requires the application of a high heat flux to the relatively small area occupied by the heater head tubes. Previous attempts to couple solar energy to Stirling engines generally involved directly illuminating the heater head tubes with concentrated sunlight. In this study, operation of a 75-kW(sub t) sodium reflux pool-boiler solar receiver has been demonstrated and its performance characterized on Sandia's nominal 75-kW(sub t) parabolic-dish concentrator, using a cold-water gas-gap calorimeter to simulate Stirling engine operation. The pool boiler (and more generally liquid-metal reflux receivers) supplies heat to the engine in the form of latent heat released from condensation of the metal vapor on the heater head tubes. The advantages of the pool boiler include uniform tube temperature, leading to longer life and higher temperature available to the engine, and decoupling of the design of the solar absorber from the engine heater head. The two-phase system allows high input thermal flux, reducing the receiver size and losses, therefore improving system efficiency. The receiver thermal efficiency was about 90 percent when operated at full power and 800 C. Stable sodium boiling was promoted by the addition of 35 equally spaced artificial cavities in the wetted absorber surface. High incipient boiling superheats following cloud transients were suppressed passively by the addition of small amounts of xenon gas to the receiver volume. Stable boiling without excessive incipient boiling superheats was observed under all operating conditions. The receiver developed a leak during performance evaluation, terminating the testing after accumulating about 50 hours on sun. The receiver design is reported here along with test results including transient operations, steady-state performance evaluation, operation at various temperatures, infrared thermography, x-ray studies of the boiling behavior, and a postmortem analysis.

  17. Multiple tube premixing device

    DOEpatents

    Uhm, Jong Ho; Naidu, Balachandar; Ziminksy, Willy Steve; Kraemer, Gilbert Otto; Yilmaz, Ertan; Lacy, Benjamin; Stevenson, Christian; Felling, David

    2013-08-13

    The present application provides a premixer for a combustor. The premixer may include a fuel plenum with a number of fuel tubes and a burner tube with a number of air tubes. The fuel tubes extend about the air tubes.

  18. Multiple tube premixing device

    DOEpatents

    Uhm, Jong Ho; Varatharajan, Balachandar; Ziminsky, Willy Steve; Kraemer, Gilbert Otto; Yilmaz, Ertan; Lacy, Benjamin; Stevenson, Christian; Felling, David

    2012-12-11

    The present application provides a premixer for a combustor. The premixer may include a fuel plenum with a number of fuel tubes and a burner tube with a number of air tubes. The fuel tubes extend about the air tubes.

  19. Fe-Al Weld Overlay and High Velocity Oxy-Fuel Thermal Spray Coatings for Corrosion Protection of Waterwalls in Fossil Fired Plants with Low NOx Burners

    SciTech Connect

    Regina, J.R.

    2002-02-08

    Iron-aluminum-chromium coatings were investigated to determine the best candidates for coatings of boiler tubes in Low NOx fossil fueled power plants. Ten iron-aluminum-chromium weld claddings with aluminum concentrations up to 10wt% were tested in a variety of environments to evaluate their high temperature corrosion resistance. The weld overlay claddings also contained titanium additions to investigate any beneficial effects from these ternary and quaternary alloying additions. Several High-Velocity Oxy-Fuel (HVOF) thermal spray coatings with higher aluminum concentrations were investigated as well. Gaseous corrosion testing revealed that at least 10wt%Al is required for protection in the range of environments examined. Chromium additions were beneficial in all of the environments, but additions of titanium were beneficial only in sulfur rich atmospheres. Similar results were observed when weld claddings were in contact with corrosive slag while simultaneously, exposed to the corrosive environments. An aluminum concentration of 10wt% was required to prevent large amounts of corrosion to take place. Again chromium additions were beneficial with the greatest corrosion protection occurring for welds containing both 10wt%Al and 5wt%Cr. The exposed thermal spray coatings showed either significant cracking within the coating, considerable thickness loss, or corrosion products at the coating substrate interface. Therefore, the thermal spray coatings provided the substrate very little protection. Overall, it was concluded that of the coatings studied weld overlay coatings provide superior protection in these Low NOx environments; specifically, the ternary weld composition of 10wt%Al and 5wt%Cr provided the best corrosion protection in all of the environments tested.

  20. Neural network boiler optimization of efficiency, emission, and reliability with TVA Kingston Unit 3 low NOx optimization test results

    SciTech Connect

    Chang, P.S.; Poston, J.M.; Schroech, K.A.; Hou, H.S.

    1995-12-31

    Boiler performance optimization includes the preservation of efficiency, emission, capacity, and reliability. Competitive pressures require cost reduction and environmental compliance. It is a challenge for utility personnel to balance these requirements often demand tradeoffs. The Clean Air Act Amendment requires utilities to reduce NOx emission. NOx emission reduction has often been accomplished by installation of new low NOx burners. Boiler tuning for NOx control can be used as an alternative to low NOx burner installation. Specifically in tangentially-fired boilers, boiler tuning can be very effective in NOx reduction. A PC-based computer software program was developed to assist the tuning process. This software, System Optimization Analysis Program (SOAP), is a neural network based code which uses the self-adaptation learning process, with an adaptive filter added for data noise control. SOAP can use historical data as the knowledge base and provides a fast optimal solution to adaptive control problems. SOAP was tested at TVA`s Kingston Unit 3 tangentially coal-fired furnace for NOx reduction. With a well-organized test plan, the optimized solution was reached with 16 tests at each test series load level. SOAP will be used for other plant equipment or system optimization, such as pulverizer performance, combustion system optimization, compared thermal performance design, and boiler tube leak detection and allocation.

  1. Experience gained from shifting a PK-19 boiler to operate with increased superheating and with a load higher than its rated value

    NASA Astrophysics Data System (ADS)

    Kholshchev, V. V.

    2011-08-01

    Failures of steam superheater tubes occurred after the boiler was shifted to operate with a steam temperature of 540°C. The operation of the steam superheater became more reliable after it had been subjected to retrofitting. The modernization scheme is described. An estimate is given to the temperature operating conditions of tubes taking into account the thermal-hydraulic nonuniformity of their heating.

  2. Validation of Coal Combustion Model by Using Experimental Data of Utility Boilers

    NASA Astrophysics Data System (ADS)

    Yamamoto, Kenji; Taniguchi, Masayuki; Kobayashi, Hironobu; Sakata, Taro; Kudo, Kazuhiko

    Applicability of a coal combustion model was validated by comparing its predictions with experimental data of utility boilers. The coal combustion model had gasification and NOx reaction submodels and it was developed by using a small drop-tube-furnace (coal feed rate 0.6kg/h). A turbulence combustion simulation program was developed by introducing the coal combustion model. The program was validated by comparing its predictions with 23 sets of experimental results which contained different plant, load and coal data. The temperature difference between simulated and experimental results was within 30°C at the furnace exit. The decreasing characteristic of coal burnout with increasing load was well predicted. The NOx emission difference between simulated and experimental results was less than 15%. The coal combustion model was judged applicable to utility boilers.

  3. Fuel sulfur and boiler fouling

    SciTech Connect

    Litzke, W.; Celebi, Y.; Butcher, T.

    1995-04-01

    Fouling of the heat transfer surfaces of boilers and furnaces by `soot` leads to reduced efficiency and increased service requirements. The average level of annual efficiency reduction as a result of fouling if generally accepted as 2% per year. Improving the efficiency of equipment in the field may be the most important oil heat conservation opportunity at present. Improvements can be realized by reducing fouling rates, promoting lower firing rates in existing equipment, and enabling excess air levels to be set lower without raising concerns about increased service requirements. In spite of the importance of efficiency in the field there is very little data available on efficiency degradation rates with modern equipment, actual field operating conditions (excess air and smoke number settings) and service problems which affect efficiency. During 1993-94 field tests were initiated to obtain such data and to obtain information that would compliment existing and current laboratory work. Experimental work conducted on a bench scale level have included tests with various advanced burners, fuel types, and different operating conditions which have been done at the BNL Rapid Fouling Test Facility. This report will focus on the field study of fouling effects on ten residential heating service problems at each site are summarized. In addition, the technical difficulties involved with conducting such a field study shall also be discussed as the findings should serve to improve future work in this area.

  4. Minimization of the negative influence on the biosphere in heavy oil extraction and ecologically clean technology for the injection of the steam with supercritical parameters in oil strata on the basis of new ecologically clean tubing pipes with heat-resistant coatings

    NASA Astrophysics Data System (ADS)

    Komkov, M. A.; Moiseev, V. A.; Tarasov, V. A.; Timofeev, M. P.

    2015-12-01

    Some ecological problems related to heavy-oil extraction and ways for minimizing the negative impacts of this process on the biosphere are discussed. The ecological hazard of, for example, frequently used multistage hydraulic fracturing of formation is noted and the advantages and perspectives of superheated steam injection are considered. Steam generators of a new type and ecologically clean and costeffective insulating for tubing pipes (TPs) are necessary to develop the superheated steam injection method. The article is devoted to solving one of the most important and urgent tasks, i.e., the development and usage of lightweight, nonflammable, environmentally safe, and cost-effective insulating materials. It is shown that, for tubing shielding operating at temperatures up to 420°C, the most effective thermal insulation is a highly porous material based on basalt fiber. The process of filtration deposition of short basalt fibers with a bunch of alumina thermal insulation tubing pipe coatings in the form of cylinders and cylindrical shells from liquid pulp is substantiated. Based on the thermophysical characteristics of basalt fibers and on the technological features of manufacturing highly porous coating insulation, the thickness of a tubing pipe is determined. During the prolonged pumping of the air at an operating temperature of 400°C in the model sample of tubing pipes with insulation and a protective layer, we find that the surface temperature of the thermal barrier coating does not exceed 60°C. Introducing the described technology will considerably reduce the negative impact of heavy-oil extraction on the biosphere.

  5. Hot Corrosion at Air-Ports in Kraft Recovery Boilers

    SciTech Connect

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Russell, James H.

    2003-01-01

    Hot corrosion can occur on the cold-side of airports in Kraft recovery boilers. The primary corrosion mechanism involves the migration of sodium hydroxide and potassium hydroxide vapors through leaks in the furnace wall at the airports and their subsequent condensation. It has been reported that stainless steel is attacked much faster than carbon steel in composite tubes, and that carbon steel tubing, when used with a low-chromium refractory, does not exhibit this type of corrosion. For hot corrosion fluxing of metal oxides, either acidic or basic fluxing takes place, with a solubility minimum at the basicity of transition between the two reactions. For stainless steel, if the basicity of the fused salt is between the iron and chromium oxide solubility minima, then a synergistic effect can occur that leads to rapid corrosion. The products of one reaction are the reactants of the other, which eliminates the need for rate-controlling diffusion. This effect can explain why stainless steel is attacked more readily than carbon steel.

  6. 1. VIEW OS SOUTH FRONT OF BOILER HOUSE, WITH SCALE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. VIEW OS SOUTH FRONT OF BOILER HOUSE, WITH SCALE STICK, SHOWING HEAVY SCALES OFFICE TO LEFT, LOOKING NORTH - Marvine Colliery, Boiler House No. 2, West side Boulevard Avenue, between East Parker Street & Route 380, Scranton, Lackawanna County, PA

  7. 38. Photocopy of photograph. STEEL PLANT, BOILERS UNDER CONSTRUCTION IN ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    38. Photocopy of photograph. STEEL PLANT, BOILERS UNDER CONSTRUCTION IN BOILER PLANT LOCATED EAST OF MAIN STEEL PLANT, 1909. (From the Bethlehem Steel Corporation collection, Seattle, WA) - Irondale Iron & Steel Plant, Port Townsend, Jefferson County, WA

  8. Looking north at the stokers for boilers numbers 1 through ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking north at the stokers for boilers numbers 1 through 4. - Wheeling-Pittsburgh Steel Corporation, Allenport Works, Boiler House, Route 88 on West bank of Monongahela River, Allenport, Washington County, PA

  9. Looking south at the ash disposal hoppers for boilers numbers ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking south at the ash disposal hoppers for boilers numbers 1 through 6. - Wheeling-Pittsburgh Steel Corporation, Allenport Works, Boiler House, Route 88 on West bank of Monongahela River, Allenport, Washington County, PA

  10. 30. VIEW OF BASEMENT BELOW FIRING AISLE OF EAST BOILER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    30. VIEW OF BASEMENT BELOW FIRING AISLE OF EAST BOILER ROOM SHOWING BOILER FEED WATER PUMP. - New York, New Haven & Hartford Railroad, Cos Cob Power Plant, Sound Shore Drive, Greenwich, Fairfield County, CT

  11. Overview of Boiler House showing the Ibeam framework supporting the ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Overview of Boiler House showing the I-beam framework supporting the chimney, view facing southwest - Kahului Cannery, Plant No. 28, Boiler House, Sheet Metal and Electrical Shops, 120 Kane Street, Kahului, Maui County, HI

  12. 2. EAST SIDE; COAL ASH FROM BOILERS WAS BLOWN INTO ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    2. EAST SIDE; COAL ASH FROM BOILERS WAS BLOWN INTO TANK AT RIGHT, THEN DROPPED INTO RAIL CARS FOR REMOVAL - Rath Packing Company, Boiler Room, Sycamore Street between Elm & Eighteenth Streets, Waterloo, Black Hawk County, IA

  13. 3. GENERAL VIEW OF BOILER ROOM, LOOKING NORTH; CONTROL PANEL ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. GENERAL VIEW OF BOILER ROOM, LOOKING NORTH; CONTROL PANEL AT CENTER; BOXLIKE, RIVETED HOUSING AT TOP CENTER CONTAINED AUGER FOR COAL DISTRIBUTION SYSTEM - Rath Packing Company, Boiler Room, Sycamore Street between Elm & Eighteenth Streets, Waterloo, Black Hawk County, IA

  14. 4. STEAM PLANT MARINE BOILERS WEST OF STEAM PLANT AND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    4. STEAM PLANT MARINE BOILERS WEST OF STEAM PLANT AND SOUTH OF ORIGINAL STEAM PLANT BOILERS, FROM SOUTH. November 13, 1990 - Crosscut Steam Plant, North side Salt River near Mill Avenue & Washington Street, Tempe, Maricopa County, AZ

  15. 13. Interior, boiler house, at elev. 55' looking west at ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    13. Interior, boiler house, at elev. 55' looking west at retired 300 lb. boilers #11, 10, and 9. - Manchester Street Generating Station, Manchester Street Station, 460 Eddy Street, Providence, Providence County, RI

  16. 1. VIEW TO EAST, WITH BOILER HOUSE TO LEFT, FILTH ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. VIEW TO EAST, WITH BOILER HOUSE TO LEFT, FILTH HOIST HOUSE TO RIGHT, WITH ENGINE HOUSE AT RIGHT REAR. - Providence Sewage Treatment System, Ernest Street Pumping Station, Boiler House, Ernest Street & Allens Avenue, Providence, Providence County, RI

  17. 3. NORTH ELEVATION OF BOILER HOUSE; PARTIAL NORTH ELEVATION OF ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. NORTH ELEVATION OF BOILER HOUSE; PARTIAL NORTH ELEVATION OF ENGINE HOUSE, LEFT REAR. - Providence Sewage Treatment System, Ernest Street Pumping Station, Boiler House, Ernest Street & Allens Avenue, Providence, Providence County, RI

  18. 3. Partial view of SE sides of Boiler Building (left), ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    3. Partial view of SE sides of Boiler Building (left), Incineration Building (to right of stack) and Machine Shop (right). - Pacific Creosoting Plant, Boiler Building, 5350 Creosote Place, Northeast, Bremerton, Kitsap County, WA

  19. View of the rear of the electrical department & boiler ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View of the rear of the electrical department & boiler house, behind the upper shops - Johnson Steel Street Rail Company, Electrical Department & Boiler House, 525 Central Avenue, Johnstown, Cambria County, PA

  20. Looking south at boiler feedwater pumps (steam turbine pump on ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking south at boiler feedwater pumps (steam turbine pump on left, electric motor pump on right). - Wheeling-Pittsburgh Steel Corporation, Allenport Works, Boiler House, Route 88 on West bank of Monongahela River, Allenport, Washington County, PA

  1. 36. REDUCTION PLANT CLOSE VIEW OF FURNACE AND BOILER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    36. REDUCTION PLANT - CLOSE VIEW OF FURNACE AND BOILER Reduction Plant furnace and boiler used to provide heat for drying the fish and fish offal, in their conversion to meal. - Hovden Cannery, 886 Cannery Row, Monterey, Monterey County, CA

  2. Looking south at a chemical mixing tank for boiler feedwater. ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Looking south at a chemical mixing tank for boiler feedwater. - Wheeling-Pittsburgh Steel Corporation, Allenport Works, Boiler House, Route 88 on West bank of Monongahela River, Allenport, Washington County, PA

  3. Utilization of silt as CFB boiler fuel

    SciTech Connect

    Herb, B.; Tsao, T.R.; Bickley, D.

    1994-12-31

    Bituminous silt represents an enormous source of discarded energy that is polluting the environment. Although bituminous silt is a potential opportunity fuel for circulating fluidized bed (CFB) boilers, handling problems and uncertainties about the impact of this fuel on CFB boiler performance and operating economics have prevented its use. Under sponsorship of the Pennsylvania Energy Development Authority, five different technologies having the potential to process silt into CFB boiler fuel were evaluated. The technologies evaluated include: washing, pelletizing, thermal drying, mulling and flaking. The desired goal was to process the silt into a form that can be fed to CFB boilers using conventional coal handling equipment and combusted in an environmentally acceptable manner. Criteria were developed for the product characteristics that are desired and tests were run to evaluate the technical feasibility of each silt processing technology. Based on these test results, the design and cost bases for a commercial silt processing facility were developed for each technology capable of achieving the desired product characteristics. As a result of considering both engineering and economic factors, the technology that best meets the objectives for use of processed silt as CFB boiler fuel was selected for further demonstration testing. This paper will present the results of this project up through the selection of the best silt processing technology.

  4. Boiler MACT Technical Assistance (Fact Sheet)

    SciTech Connect

    Not Available

    2012-03-01

    Fact sheet describing the changes to Environmental Protection Act process standards. The DOE will offer technical assistance to ensure that major sources burning coal and oil have information on cost-effective, clean energy strategies for compliance, and to promote cleaner, more efficient boiler burning to cut harmful pollution and reduce operational costs. The U.S. Environmental Protection Agency (EPA) is expected to finalize the reconsideration process for its Clean Air Act pollution standards National Emissions Standards for Hazardous Air Pollutants for Major Sources: Industrial, Commercial, and Institutional Boilers and Process Heaters (known as Boiler Maximum Achievable Control Technology (MACT)), in Spring 2012. This rule applies to large and small boilers in a wide range of industrial facilities and institutions. The U.S. Department of Energy (DOE) will offer technical assistance to ensure that major sources burning coal or oil have information on cost-effective clean energy strategies for compliance, including combined heat and power, and to promote cleaner, more efficient boilers to cut harmful pollution and reduce operational costs.

  5. Boiler house modernization through shared savings program

    SciTech Connect

    Breault, R.W.

    1995-12-31

    Throughout Poland as well as the rest of Eastern Europe, communities and industries rely on small heat only boilers to provide district and process heat. Together these two sectors produce about 85,000 MW from boilers in the 2 to 35 MW size range. The bulk of these units were installed prior to 1992 and must be completely overhauled to meet the emission regulations which will be coming into effect on January 1, 1998. Since the only practical fuel is coal in most cases, these boilers must be either retrofit with emission control technology or be replaced entirely. The question that arises is how to accomplish this given the current tight control of capital in Poland and other East European countries. A solution that we have for this problem is shared savings. These boilers are typically operating with a quiet low efficiency as compared to western standards and with excessive manual labor. Installing modernization equipment to improve the efficiency and to automate the process provides savings. ECOGY provides the funds for the modernization to improve the efficiency, add automation and install emission control equipment. The savings that are generated during the operation of the modernized boiler system are split between the client company and ECOGY for a number of years and then the system is turned over in entirety to the client. Depending on the operating capacity, the shared savings agreement will usually span 6 to 10 years.

  6. Explosion in boiler closes Arkansas utility

    SciTech Connect

    Not Available

    1993-08-23

    A major boiler explosion Aug. 11 that seriously injured one worker at the Independence Unit 2 coal-fired powerplant in Newark, Ark., caused extensive damage that will keep the plant closed for several months. The plant is owned by Arkansas Power Light Co., Little Rock. Officials are still trying to determine cause and are assessing damage, though they expect the boiler can be repaired. Etienne Senac, plant manager, says the explosion [open quotes]puffed out[close quotes] but did not rupture the 271-ft-tall boiler and also buckled several buck stays, which hold the boiler to a steel superstructure. The accident took place at 8:30 a.m. as the 842-Mw unit was operating close to full capacity. Senac says the concussion knocked down workers standing 50 ft from the boiler. The explosion pushed ash and molten material out of the bottom of the unit, causing a small fire. One contract worker was seriously burned and hospitalized. Four AP L workers received minor burns.

  7. Design of a pool boiler heat transport system for a 25 kWe advanced Stirling conversion system

    NASA Technical Reports Server (NTRS)

    Anderson, W. G.; Rosenfeld, J. H.; Noble, J.; Kesseli, J.

    1991-01-01

    The overall operating temperature and efficiency of solar-powered Stirling engines can be improved by adding a heat transport system to more uniformly supply heat to the heater head tubes. One heat transport system with favorable characteristics is an alkali metal pool boiler. An alkali metal pool boiler heat transport system was designed for a 25-kW advanced Stirling conversion system (ASCS). Solar energy concentrated on the absorber dome boils a eutectic mixture of sodium and potassium. The alkali metal vapors condense on the heater head tubes, supplying the Stirling engine with a uniform heat flux at a constant temperature. Boiling stability is achieved with the use of an enhanced boiling surface and noncondensible gas.

  8. NOx Control for Utility Boiler OTR Compliance

    SciTech Connect

    Hamid Farzan; Jennifer L. Sivy

    2005-07-30

    Babcock & Wilcox Power Generation Group (B&W) and Fuel Tech, Inc. (Fuel Tech) teamed to evaluate an integrated solution for NO{sub x} control comprised of B&W's DRB-4Z{reg_sign} low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NO{sub x}OUT{reg_sign}, a selective non-catalytic reduction (SNCR) technology, capable of meeting a target emission limit of 0.15 lb NO{sub x}/10{sup 6} Btu. In a previous project sponsored by the U.S. Department of Energy (DOE), promising results were obtained with this technology from large-scale testing in B&W's 100-million Btu/hr Clean Environment Development Facility (CEDF) which simulates the conditions of large coal-fired utility boilers. Under the most challenging boiler temperatures at full load conditions, NO{sub x} emissions of 0.19 lb/10{sup 6} Btu were achieved firing Powder River Basin coal while controlling ammonia slip to less than 5 ppm. At a 40 million Btu/hr firing rate, NO{sub x} emissions were as low as 0.09 lb/10{sup 6} Btu. Improved performance with this system was proposed for this new program with injection at full load via a convective pass multiple nozzle lance (MNL) in front of the superheater tubes or in the convective tube bank. Convective pass lances represent the current state-of-the-art in SNCR and needed to be evaluated in order to assess the full potential of the combined technologies. The objective of the program was to achieve a NO{sub x} level below 0.15 lb/10{sup 6} Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B&W's DRB-4Z{reg_sign} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign} System. Commercial installations of B&W's low-NO{sub x} burner, in combination with overfire air ports using PRB coal, have demonstrated a NO{sub x} level of 0.15 to 0.2 lb/10{sup 6} Btu under staged combustion conditions. The proposed goal of the combustion system (no SNCR) for this project is a NO

  9. Coated particle waste form development

    SciTech Connect

    Oma, K.H.; Buckwalter, C.Q.; Chick, L.A.

    1981-12-01

    Coated particle waste forms have been developed as part of the multibarrier concept at Pacific Northwest Laboratory under the Alternative Waste Forms Program for the Department of Energy. Primary efforts were to coat simulated nuclear waste glass marbles and ceramic pellets with low-temperature pyrolytic carbon (LT-PyC) coatings via the process of chemical vapor deposition (CVD). Fluidized bed (FB) coaters, screw agitated coaters (SAC), and rotating tube coaters were used. Coating temperatures were reduced by using catalysts and plasma activation. In general, the LT-PyC coatings did not provide the expected high leach resistance as previously measured for carbon alone. The coatings were friable and often spalled off the substrate. A totally different concept, thermal spray coating, was investigated at PNL as an alternative to CVD coating. Flame spray, wire gun, and plasma gun systems were evaluated using glass, ceramic, and metallic coating materials. Metal plasma spray coatings (Al, Sn, Zn, Pb) provided a two to three orders-of-magnitude increase in chemical durability. Because the aluminum coatings were porous, the superior leach resistance must be due to either a chemical interaction or to a pH buffer effect. Because they are complex, coated waste form processes rank low in process feasibility. Of all the possible coated particle processes, plasma sprayed marbles have the best rating. Carbon coating of pellets by CVD ranked ninth when compared with ten other processes. The plasma-spray-coated marble process ranked sixth out of eleven processes.

  10. 40 CFR 63.988 - Incinerators, boilers, and process heaters.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... status requirements of 40 CFR part 265, subpart O; (ii) A boiler or process heater with a design heat... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Incinerators, boilers, and process... Routing to a Fuel Gas System or a Process § 63.988 Incinerators, boilers, and process heaters. (a...

  11. Biomass boiler conversion potential in the eastern United States

    Treesearch

    Charles D. Ray; Li Ma; Thomas Wilson; Daniel Wilson; Lew McCreery; Janice K. Wiedenbeck

    2013-01-01

    The U.S. is the world's leading consumer of primary energy. A large fraction of this energy is used in boiler installations to generate steam and hot water for heating applications. It is estimated there are total 163,000 industrial and commercial boilers in use in the United States of all sizes. This paper characterizes the commercial and industrial boilers in...

  12. 46 CFR 63.25-1 - Small automatic auxiliary boilers.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 2 2013-10-01 2013-10-01 false Small automatic auxiliary boilers. 63.25-1 Section 63.25-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING AUTOMATIC AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-1 Small automatic...

  13. 46 CFR 63.25-1 - Small automatic auxiliary boilers.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 2 2014-10-01 2014-10-01 false Small automatic auxiliary boilers. 63.25-1 Section 63.25-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING AUTOMATIC AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-1 Small automatic...

  14. 46 CFR 63.25-1 - Small automatic auxiliary boilers.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 2 2012-10-01 2012-10-01 false Small automatic auxiliary boilers. 63.25-1 Section 63.25-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING AUTOMATIC AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-1 Small automatic...

  15. 46 CFR 63.25-1 - Small automatic auxiliary boilers.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 2 2011-10-01 2011-10-01 false Small automatic auxiliary boilers. 63.25-1 Section 63.25-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING AUTOMATIC AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-1 Small automatic...

  16. 46 CFR 63.25-1 - Small automatic auxiliary boilers.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Small automatic auxiliary boilers. 63.25-1 Section 63.25-1 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING AUTOMATIC AUXILIARY BOILERS Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-1 Small automatic...

  17. Fluidized-bed boilers achieve commercial status worldwide

    SciTech Connect

    Schwieger, B.

    1985-02-01

    The author reviews the current status of commercial fluidized-bed boilers worldwide. Particular attention is given to circulating fluidised-bed systems. A number of detailed tables are presented providing details of manufacturers of afb boilers, and information on 88 installed boilers, their fuels, combustion systems and operational data. Less detailed information is given of a further 140 installations.

  18. 46 CFR 109.205 - Inspection of boilers and machinery.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 4 2012-10-01 2012-10-01 false Inspection of boilers and machinery. 109.205 Section 109... OPERATIONS Tests, Drills, and Inspections § 109.205 Inspection of boilers and machinery. The chief engineer or engineer in charge, before he assumes charge of the boilers and machinery of a unit shall inspect...

  19. 46 CFR 109.205 - Inspection of boilers and machinery.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 4 2011-10-01 2011-10-01 false Inspection of boilers and machinery. 109.205 Section 109... OPERATIONS Tests, Drills, and Inspections § 109.205 Inspection of boilers and machinery. The chief engineer or engineer in charge, before he assumes charge of the boilers and machinery of a unit shall inspect...

  20. 46 CFR 109.205 - Inspection of boilers and machinery.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 4 2014-10-01 2014-10-01 false Inspection of boilers and machinery. 109.205 Section 109... OPERATIONS Tests, Drills, and Inspections § 109.205 Inspection of boilers and machinery. The chief engineer or engineer in charge, before he assumes charge of the boilers and machinery of a unit shall inspect...