Yeast Identification During Fermentation of Turkish Gemlik Olives.

PubMed

Mujdeci, Gamze; Arévalo-Villena, María; Ozbas, Z Yesim; Briones Pérez, Ana

2018-05-01

Naturally fermented black table olives of the Gemlik variety are one of the most consumed fermented products in Turkey. The objective of this work was to identify yeast strains isolated during their natural fermentation by using Restriction Fragments Lengths Polymorphism-Polimerase Chain Reaction (RFLP-PCR) and DNA sequencing methods. The study also focused on determining the effect of regional differences on yeast microflora of naturally fermented Gemlik olives. A total of 47 yeast strains belonging to 12 different species which had been previously isolated from the natural brine of Akhisar and Iznik-Gemlik cv. olives were characterized by molecular methods. Forty-two of the tested strains could be identified by RFLP-PCR to species level. These yeast species were determined as Candida mycetangi, Candida hellenica, Candida membranaefaciens, Candida famata, Candida pelliculosa, Saccharomyces cerevisiae, and Zygosaccharomyces mrakii. Five strains were identified by DNA sequencing. These strains belonged to three different species: Aureobasidium pullulans, Kloeckera apiculate, and Cryptococcus saitoi. The most frequent species were C. famata and C. pelliculosa in both regions. This work studies the yeasts from Turkish table olives which could prove to be of importance to the food industry in that area. On the other hand, it compares identification by molecular and classical biochemical methods and offers an idea about the differences between the ecosystems of Gemlik olives in the Akhisar (AO) and Iznik (IO) regions. The study could be useful in characterizing a very important product and, in this way, could help to promote its marketing. © 2018 Institute of Food Technologists®.

Evolution of potential ecological impacts of the bottom sediment from the Gulf of Gemlik; Marmara Sea, Turkey.

PubMed

Unlü, Selma; Alpar, Bedri

2009-12-01

The eastern and southern coasts of the Gulf of Gemlik, a resort in the Sea of Marmara, Turkey, are under the influence of rapid ecotourism development, direct domestic and industrial discharges via rivers and outfalls, surface run-off, drainage from ports and shipping. According to sediment quality criteria in use around the world, sediment quality in the gulf shows a broad spectrum. It is more related by direct input, rather than by the type of sediment, and excluding inner port and southern coasts, it does not exert adverse biological effects yet. The total PAH concentrations range from 51 to 13,482 ng/g dry weight with the mean value of 1,850 ng/g dry weight (n = 61). The elevated values of the total toxic Benzo[a]pyrene equivalency (TEQcarc), with a maximum of 1,838 ng/g dry weight, were found at the inner harbor of Gemlik, possibly posing hazard to benthic organisms. Among the different PAHs, the contribution to the total TEQcarc decreased as the following order: Benzo[a]pyrene (43.6%) > Benzo[k]fluoranthene (36.0%) > Indeno[1,2,3-cd]pyrene (35.1%) > Benzo[b]fluoranthene (20.0%) > Chrysene + Triphenylene (18.9%) > Benzo[a]anthracene (12.5%).

Late Glacial to Holocene evolution and sea-level history of Gulf of Gemlik, Sea of Marmara, Turkey

NASA Astrophysics Data System (ADS)

Sabuncu, Asen; Kadir Eriş, K.; Kaslilar, Ayse; Namık Çaǧatay, M.; Gasperini, Luca; Filikçi, Betül

2016-04-01

The Gulf of Gemlik is an E-W elongated trans-tensional basin with a maximum depth of 113 m, located on the middle strand of the North Anatolian Fault (NAF) in the south eastern part of the Sea of Marmara (SoM). While during the Holocene the sea level in the Gulf of Gemlik changed in tandem with the water level changes in the SoM, it may have been different in the late glacial when the Sea of Marmara was lacustrine. Beside the tectonic activity related to the NAFZ, eustatic sea level changes would have controlled the basin evolution and consequent sedimentary history during the different paleocanographic phases of the SoM. Considering the limited studies on the late glacial-Holocene stratigraph of the Gulf of Gemlik, this study aims to investigate the depositional units and their environments with respect to different allogenic and autogenic controls. For these purposes, we analyzed over 300 2 - 7 kHz bandwidth high-resolution gridded seismic sub-bottom CHIRP profiles together with 70 kHz high resolution multibeam bathymetry with backscatter data. Four seismic stratigraphic units were defined and correlated with chronstratigraphic units in five piston cores covering the last 15.8 ka BP according to radiocarbon ages (14C). The depth-scale accuracy of chronostratigraphic units in cores is of key importance for the precise calculation of sedimentation rates. Correlation between the seismic profiles and cores were made by matching Multi-Sensor Core-Logger (MSCL) data and seismic reflection coefficients and amplitudes for different stratigraphic units. The impedance data derived from the logger were used to generate a synthetic seismogram. We used an approach to display, estimate, and correct the depth-scale discrepancies due to oversampling affecting the upper part of sedimentary series during piston coring. The method is based on the resynchronization of synthetic seismograms computed from high-quality physical property logs to the corresponding CHIRP profiles. Each sequence boundary represented by different reflection coefficient and various amplitude values were mapped for the whole gulf area from the pseudo-3D seismic data. Isopach and isochron maps were generated using 2-D cubic B-spline interpolation method to reconstruct basin evolution models through late glacial to Holocene. Each map shows various depositional period with respect to water level changes that has been controlled by sea level fluctuations in the SoM. The seismic units labeled as Unit S1-S4 from top to bottom display different seismic facies and geometries. Unit S1 is a transgressive marine mud drape younger than 10.6 ka BP, which lacustrine sediments, Unit S2 is a parallel bedded mud drape in the basin and progradational clinoforms on the shelf edge. It is dated between 13.9-10.6 ka BP, Unit S3 is characterized by erosional gullies and a clinoform architecture indicating a deltaic system dated between 15.8-13.9 ka BP. Unit S4 represents mounded sediments that are truncated by erosional gullies and dated >15.8 ka BP. Key words: Gulf of Gemlik, Seismic Stratigraphy, Numerical Modelling, Late Pleistocene to Holocene

Late glacial to Holocene water level and climate changes in the Gulf of Gemlik, Sea of Marmara: evidence from multi-proxy data

NASA Astrophysics Data System (ADS)

Filikci, Betül; Eriş, Kürşad Kadir; Çağatay, Namık; Sabuncu, Asen; Polonia, Alina

2017-10-01

Multi-proxy analyses of new piston core M13-08 together with seismic data from the Gulf of Gemlik provide a detailed record of paleoceanographic and paleoclimatic changes with special emphasis on the timing of the connections between the Sea of Marmara (SoM) and the Gulf of Gemlik during the late Pleistocene to Holocene. The deposition of a subaqueous delta sourced from the Armutlu River to the north is attributed to the lowstand lake level at -60 m in the gulf prior to 13.5 cal ka BP. On the basis of the seismic data, it is argued that the higher lake level (-60 m) in the gulf compared to the SoM level (-85 m) attests to its disconnection from the SoM during the late glacial period. Ponto-Caspian assemblages in the lacustrine sedimentary unit covering the time period between 13.5 and 12 cal ka BP represent a relict that was introduced into the gulf by a Black Sea outflow during the marine isotope stage 3 interstadial. Contrary to the findings of previous studies, the data suggest that such an outflow into the Gulf of Gemlik during the late glacial period could have occurred only if the SoM lake level (-85 m) was shallower than the sill depth (-55 m) of the gulf in the west. A robust age model of the core indicates the connection of the gulf with the marine SoM at 12 cal ka BP, consistent with the sill depth (-55 m) of the gulf on the global sea level curve. Strong evidence of a marine incursion into the gulf is well documented by the μ-XRF Sr/Ca data. The available profiles of elemental ratios in core M13-08, together with the age-depth model, imply that a warm and wet climate prevailed in the gulf during the early Holocene (12-10.1 cal ka BP), whereas the longest drought occurred during the middle Holocene (8.2-5.4 cal ka BP). The base of the main Holocene sapropel in the gulf is dated at 10.1 cal ka BP, i.e., 500 years younger than its equivalent in the SoM. The late Holocene is earmarked by warm and wet climate periods (5.0-4.2 and 4.2-2.7 cal ka BP) with some brief cold/dry periods (4.2 and 2.7-0.9 cal ka BP).

Assessment of phytoplankton and environmental variables for water quality and trophic state classification in the Gemlik Gulf, Marmara Sea (Turkey).

PubMed

Balci, Muharrem; Balkis, Neslihan

2017-02-15

Phytoplankton assemblages related to environmental factors and ecological status of the Gemlik Gulf were investigated between June 2010 and May 2011. A total 155 phytoplankton species were detected and 6 taxa (Amphisolenia laticincta, Archaeperidinium minutum, Cochlodinium sp., Gynogonadinium aequatoriale, Heterocapsa rotundata and Metaphalacroma sp.) were new records for the Turkish Seas. The lowest and highest total phytoplankton abundance among the sampling units (depths) was recorded in April 2011 (7.4×10 3 cellsL -1 ) and July 2010 (251.8×10 3 cellsL -1 ). Local small patches of visible red tide events were detected especially in the gulf, although a phytoplankton bloom was not observed. The water column was well stratified in the early autumn and well mixed in the early spring according to stratification index values. Surface nutrient concentrations increased especially at stations located inside of the gulf. The limiting effect of silicate was observed in early, mid-summer and early winter periods while the nitrogen was the limiting nutrient in the gulf during the whole sampling period. In the Gulf, low water quality-high mesotrophic and bad water quality-eutrophic status, high quality and low trophic level were generally detected according to Chl a, dissolved oxygen and trophic index. However, indices developed to determine the trophic level and water quality of the Mediterranean Sea can give unexpected results about the current environmental quality status when it is applied to the Marmara Sea which has limited photic zone by the halocline-pycnocline and thermocline. Copyright © 2016 Elsevier Ltd. All rights reserved.

Holocene sedimentary processes in the Gemlik Gulf: a transtensional basin on the middle Strand of the North Anatolian Fault, Sea of Marmara

NASA Astrophysics Data System (ADS)

Özmaral, A.; Çagatay, M. N.; Imren, C.; Gasperini, L.; Henry, P.

2012-04-01

Gemlik Gulf is an oval-shaped transtensional basin with a maximum depth of 113 m, located on the middle strand of the North Anatolian Fault (NAF) in the eastern part of the Sea of Marmara (SOM). During the last glacial period until the Holocene marine transgression about 12 ka BP, the sea level was below the Çanakkale (Dardanelles) Strait's bedrock sill depth of -85 m, and the Gemlik Basin became a lake isolated lake from the rest of the Sea of Marmara "Lake" and the global ocean. The high resolution seismic profiles and the multi- beam bathymetric map of the basin show that the basin is characterized by NW-SE trending transtensional oblique faults, delta lobes of the Büyükdere (Kocadere) to the east and an erosional surface below an up to 15 m-thick Holocene mud drape. The Holocene mud drape was studied in up to 9.5 m-long gravity-piston and 0.84 m-long sediment/water interface cores located at -105 to -113 m in the basin's depocentre. The Holocene mud consists mainly of plastic gray green marine clayey mud that includes thick-red brown clay layers and a laminated organic-rich, dark olive green sapropel in the lower part, which was previously dated at 11.6-6.4 14Ckyr (uncalib) BP. Multi-proxy analyses of the Holocene mud drape in the sediment cores were carried out using Multisensor Core Logger, XRF Core Scanner equipped with digital X-Ray radiography, and laser particle size analyzer. Seismic-core correlation was made using seismic data of the chirp profiles at the core locations and the synthetic seismograms generated using the MSCL P-wave velocity and gamma density measurements. The long piston-gravity cores include five 20 to 100 mm-thick "red brown mud layers" in the top 2.5 m of the core. These layers have a sharp basal boundary and gradational upper boundary. The red brown layers consist of 55-75% clay-size material with an average grain size of 3-4 µm, and have relatively a high magnetic susceptibility. They are enriched in K, Fe, Ti and Zr that are the proxy of detrital mineral input, and depleted in Ca, Br, Fe and Mn. Manganese shows a sharp enrichment immediately below the base of the red brown layers. All these features strongly suggest that the red layers represent the distal edges mass flow deposits, possibly sourced from the delta to the east. The distinct Mn enrichments below the base of the red brown layers represent the diagenetic enrichment at the oxic/anoxic boundary near the seafloor, which was later covered by the mass flow deposit. C-14 and radionuclide datings of the mass flow layers and investigation of their possible relation to the past earthquakes are under progress.

Network analysis of the Viking Age in Ireland as portrayed in Cogadh Gaedhel re Gallaibh.

PubMed

Yose, Joseph; Kenna, Ralph; MacCarron, Máirín; MacCarron, Pádraig

2018-01-01

Cogadh Gaedhel re Gallaibh ('The War of the Gaedhil with the Gaill') is a medieval Irish text, telling how an army under the leadership of Brian Boru challenged Viking invaders and their allies in Ireland, culminating with the Battle of Clontarf in 1014. Brian's victory is widely remembered for breaking Viking power in Ireland, although much modern scholarship disputes traditional perceptions. Instead of an international conflict between Irish and Viking, interpretations based on revisionist scholarship consider it a domestic feud or civil war. Counter-revisionists challenge this view and a long-standing and lively debate continues. Here, we introduce quantitative measures to the discussions. We present statistical analyses of network data embedded in the text to position its sets of interactions on a spectrum from the domestic to the international. This delivers a picture that lies between antipodal traditional and revisionist extremes; hostilities recorded in the text are mostly between Irish and Viking-but internal conflict forms a significant proportion of the negative interactions too.

Elongation Of The North Anatolian Fault Zone in the Sea of Marmara

NASA Astrophysics Data System (ADS)

Kurtulus, C.; Canbay, M. M.

2003-04-01

The North Anatolian Fault Zone (NAFZ) is a 1500 km long, seismically active, right lateral strike sleep fault that accommodates the relative motion between the Anatolian and Pontide blocks. The Sea of Marmara is an intra-continental sea lying along the western part of the NAFZ. There are two major fault systems in the Sea of Marmara one of which consists of the east-west striking faults and the other one is made up of NE-SW-trending faults that dissect the first group. The east, middle and the south parts of the Sea of Marmara are interpreted as pull-apart basins characterized by shear stresses. The interpretation of the structural framework indicates that the northern strand of the NAFZ traverses the Gulf of Izmit and deep Marmara to bind the Gulf of Saros and the middle strand of it traverses the Gulf of Gemlik, Bandirma and the Gulf of Erdek.

Volusia Blue Spring - A Hydrological Treasure

USGS Publications Warehouse

German, Edward R.

2008-01-01

Springs are natural openings in the ground through which water beneath the surface discharges into hydrologic features such as lakes, rivers, or the ocean. The beautiful springs and spring rivers are among Florida's most valued natural resources; their gemlike refreshing waters have been a focal point of life from prehistoric times to the present (2008). The steady flow of freshwater at a nearly constant water temperature attracted animals now long absent from Florida's landscape. Fossil remains and human artifacts, discovered by divers from many spring runs, attest to the importance of springs to the State's earliest inhabitants. Explorers of Florida, from Ponce de Leon to John and William Bartram and others, often mentioned the springs that were scattered across central and northern Florida. As colonists and settlers began to inhabit Florida, springs continued to be the focus of human activity, becoming sites of missions, towns, and steamboat landings.

Network analysis of the Viking Age in Ireland as portrayed in Cogadh Gaedhel re Gallaibh

PubMed Central

Yose, Joseph; MacCarron, Máirín; MacCarron, Pádraig

2018-01-01

Cogadh Gaedhel re Gallaibh (‘The War of the Gaedhil with the Gaill’) is a medieval Irish text, telling how an army under the leadership of Brian Boru challenged Viking invaders and their allies in Ireland, culminating with the Battle of Clontarf in 1014. Brian’s victory is widely remembered for breaking Viking power in Ireland, although much modern scholarship disputes traditional perceptions. Instead of an international conflict between Irish and Viking, interpretations based on revisionist scholarship consider it a domestic feud or civil war. Counter-revisionists challenge this view and a long-standing and lively debate continues. Here, we introduce quantitative measures to the discussions. We present statistical analyses of network data embedded in the text to position its sets of interactions on a spectrum from the domestic to the international. This delivers a picture that lies between antipodal traditional and revisionist extremes; hostilities recorded in the text are mostly between Irish and Viking—but internal conflict forms a significant proportion of the negative interactions too. PMID:29410814

Temporal evolution of anthropogenic pollution and environmental changes in a marine inlet: the example of Gemlik Gulf, Marmara Sea

NASA Astrophysics Data System (ADS)

Albut, Gülüm; Namık Cagatay, M.; Gungor, Nurdan; Gungor, Emin; Acar, Dursun; Balkıs, Nuray

2014-05-01

Marginal marine basins are particularly prone to anthropogenic pollution because of restricted water circulation and commonly high population density in their drainage basin. Gemlik Gulf is such a semi-enclosed inlet with maximum depth of 113 m in the eastern part of the Sea of Marmara, which is separated from the rest of the Marmara shelf by a -50 m deep sill. It is under anthropogenic risk from different industrial and municipal pollution sources in its drainage basin. Moreover, Gemlik Gulf, located on the middle branch of the North Anatolian fault (NAF), is under a future earthquake risk with a high possibility of pollution from disruption to industrial plants and municipal infrastucture, similar to the the one that occurred in the Ä°zmit Gulf during the 1999 Mw 7.4 Ä°zmit earthquake. In this study, we investigated the extent and temporal evolution of the heavy metal and organic pollution using a wide range of analyses of a 84 cm sediment/water interface long core from the central part of the basin, involving μ-XRF Core Scanner, Inductively Coupled Plasma-Mass Spectrometry (ICP-MS), Total Organic (TOC) and Inorganic Carbon (TIC), and mass spectrometric stable C and N isotopic and C and N elemental analyses. The chronology of the core was determined using radionuclide (210Pb and 137Cs) and AMS radiocarbon analysis. The core covers about last 800 years. The upper part of the core, representing the last 155 years, is gray mud grading into very dark grey mud in the top 84 cm. The 5-8 cm interval below sea floor (bsf) (AD 1985-1995) includes 3 white laminae consisting of coccolithophore Emiliania huxleyi and another carbonate rich layer deposited during AD 1855-1950. TOC values are commonly between 1.5 and 2.5 % below 12.5 cmbsf (AD 1965), but increases up to 4.25 % towards the core top. The core includes a mass flow unit, which is most probably triggered by the AD 1855 earthquake, and is characterized by high contents of Fe, Zr, low contents of Ca, Nb, La U, Th, Zn and Pb, Cu. Enrichment factor (EF) of Mo, obtained with respect to the average metal values of uncontaminated substratum in the core and normalisation to Al, increase sharply upwards starting from 15 cmbsf (AD 1955) to a maximum EF of 23. Such a dramatic Mo increase, together with a Mn depletion, indicates the establishment of bottom water anoxia in the Gulf at least since AD 1970. At around the same time increases started to be observed in concentrations of most metals and semi-metals such as Cd, Zn, Cu, Pb, U, S, Sb, with a maximum EF of 5.7, 2.1, 1.6, 1.6, 1.3, 3.2, 2.2, respectively. C/N ratio and δ13C reveals the cylicity in origin of organic matter changing from bottom to top of the core respectively as: terrestrial, a mixture of marine and terrestrial, terrestrial in the mass flow unit, mixed, marine and terrestrial in most recent sediments of last about 15 years. The organic matter of terrestrial origin as well as pollutants were transported by Kocadere and Karsak Creeks and Kocasu river. δ15N values range between 4 and 4.5 o during AD 1230-1540 and 2.5 and 3.1 o during AD 1540-1740 and between 3.7 and 5.6 o since AD 1855 to present. Assessment of δ15N data together with the TOC and TIC data suggest that denitrification process has been effective especially during the last 150 years, and least effective during AD 1540-1740 which includes the Late Maunder Minimum cold period.

Sowing the Seeds of Planets? (Artist's Concept)

NASA Technical Reports Server (NTRS)

2005-01-01

[figure removed for brevity, see original site] Planet Clumps and Crystals around Brown Dwarfs

This artist's concept shows microscopic crystals in the dusty disk surrounding a brown dwarf, or 'failed star.' The crystals, made up of a green mineral found on Earth called olivine, are thought to help seed the formation of planets.

NASA's Spitzer Space Telescope detected the tiny crystals circling around five brown dwarfs, the cooler and smaller cousins of stars. Though crystallized minerals have been seen in space before -- in comets and around other stars -- the discovery represents the first time the little gem-like particles have been spotted around confirmed brown dwarfs.

Astronomers believe planets form out of disks of dust that circle young brown dwarfs and stars. Over time, the various minerals making up the disks crystallize and begin to clump together. Eventually, the clumps collide and stick, building up mass like snowmen until planets are born.

About the Graph: Planet Clumps and Crystals around Brown Dwarfs The graph of data from NASA's Spitzer Space Telescope shows the spectra (middle four lines) of dusty disks around four brown dwarfs, or 'failed stars,' located 520 light-years away in the Chamaeleon constellation. The data suggest that the dust in these disks is crystallizing and clumping together in what may be the birth of planets.

Spectra are created by breaking light apart into its basic components, like a prism turning sunlight into a rainbow. Their bumps represent the 'fingerprints' or signatures of different minerals.

Here, the light green vertical bands highlight the spectral fingerprints of crystals made up primarily of a green silicate mineral found on Earth called olivine. As the graph illustrates, three of the four brown dwarfs possess these microscopic gem-like particles. For comparison, the spectra of dust between stars (top) and the comet Hale-Bopp (bottom) are shown. The comet has the tiny crystals, whereas the interstellar dust does not.

The broadening of these spectral features or bumps -- seen here as you move down the graph - indicates silicate grains of increasing size.

Another analysis of this same data shows that some of the brown dwarfs' dusty disks flare in their outer regions, while others are flattened. This flattening is correlated with increasing grain size, and probably occurs because the heavier dust grains are settling downward.

Together, these observations - of crystals, growing dust grains and flattened disks - provide strong evidence that the dust around these brown dwarfs is evolving into what might become planets. Prior to the findings, these first steps of planet formation were seen only in disks around stars, the brighter and bigger cousins to brown dwarfs.

An Assessment of the Seismicity of the Bursa Region from a Temporary Seismic Network

NASA Astrophysics Data System (ADS)

Gok, Elcin; Polat, Orhan

2012-04-01

A temporary earthquake station network of 11 seismological recorders was operated in the Bursa region, south of the Marmara Sea in the northwest of Turkey, which is located at the southern strand of the North Anatolian Fault Zone (NAFZ). We located 384 earthquakes out of a total of 582 recorded events that span the study area between 28.50-30.00°E longitudes and 39.75-40.75°N latitudes. The depth of most events was found to be less than 29 km, and the magnitude interval ranges were between 0.3 ≤ ML ≤ 5.4, with RMS less than or equal to 0.2. Seismic activities were concentrated southeast of Uludag Mountain (UM), in the Kestel-Igdir area and along the Gemlik Fault (GF). In the study, we computed 10 focal mechanisms from temporary and permanents networks. The predominant feature of the computed focal mechanisms is the relatively widespread near horizontal northwest-southeast (NW-SE) T-axis orientation. These fault planes have been used to obtain the orientation and shape factor (R, magnitude stress ratio) of the principal stress tensors (σ1, σ2, σ3). The resulting stress tensors reveal σ1 closer to the vertical (oriented NE-SW) and σ2, σ3 horizontal with R = 0.5. These results confirm that Bursa and its vicinity could be defined by an extensional regime showing a primarily normal to oblique-slip motion character. It differs from what might be expected from the stress tensor inversion for the NAFZ. Different fault patterns related to structural heterogeneity from the north to the south in the study area caused a change in the stress regime from strike-slip to normal faulting.

Galactic Hearts of Glass

NASA Technical Reports Server (NTRS)

2006-01-01

[figure removed for brevity, see original site] Click on image for larger graph

This artist's concept shows delicate greenish crystals sprinkled throughout the violent core of a pair of colliding galaxies. The white spots represent a thriving population of stars of all sizes and ages. NASA's Spitzer Space Telescope detected more than 20 bright and dusty galactic mergers like the one depicted here, all teeming with the tiny gem-like crystals.

When galaxies collide, they trigger the birth of large numbers of massive stars. Astronomers believe these blazing hot stars act like furnaces to produce silicate crystals in the same way that glass is made from sand. The stars probably shed the crystals as they age, and as they blow apart in supernovae explosions.

At the same time the crystals are being churned out, they are also being destroyed. Fast-moving particles from supernova blasts easily convert silicates crystals back to their amorphous, or shapeless, form.

How is Spitzer seeing the crystals if they are rapidly disappearing? Astronomers say that, for a short period of time at the beginning of galactic mergers, massive stars might be producing silicate crystals faster than they are eliminating them. When our own galaxy merges with the Andromeda galaxy in a few billion years, a similar burst of massive stars and silicate crystals might occur.

Crystal Storm in Distant Galaxy The graph (see inset above) of infrared data from NASA's Spitzer Space Telescope tells astronomers that a distant galaxy called IRAS 08752+3915 is experiencing a storm of tiny crystals made up of silicates. The crystals are similar to the glass-like grains of sand found on Earth's many beaches.

The data were taken by Spitzer's infrared spectrograph, which splits light open to reveal its rainbow-like components. The resulting spectrum shown here reveals the signatures of both crystalline (green) and non-crystalline (brown) silicates.

Spitzer detected the same crystals in 20 additional galaxies, all belonging to a class called ultraluminous infrared galaxies. These extremely bright and dusty galaxies usually consist of two galaxies in the process of smashing into each other. Astronomers believe massive stars at the hearts of the galaxies are churning out clouds of silicate crystals. This phenomenon may represent a short-lived phase in the evolution of galactic mergers.

S/G-1: an ab initio force-field blending frozen Hermite Gaussian densities and distributed multipoles. Proof of concept and first applications to metal cations.

PubMed

Chaudret, Robin; Gresh, Nohad; Narth, Christophe; Lagardère, Louis; Darden, Thomas A; Cisneros, G Andrés; Piquemal, Jean-Philip

2014-09-04

We demonstrate as a proof of principle the capabilities of a novel hybrid MM'/MM polarizable force field to integrate short-range quantum effects in molecular mechanics (MM) through the use of Gaussian electrostatics. This lead to a further gain in accuracy in the representation of the first coordination shell of metal ions. It uses advanced electrostatics and couples two point dipole polarizable force fields, namely, the Gaussian electrostatic model (GEM), a model based on density fitting, which uses fitted electronic densities to evaluate nonbonded interactions, and SIBFA (sum of interactions between fragments ab initio computed), which resorts to distributed multipoles. To understand the benefits of the use of Gaussian electrostatics, we evaluate first the accuracy of GEM, which is a pure density-based Gaussian electrostatics model on a test Ca(II)-H2O complex. GEM is shown to further improve the agreement of MM polarization with ab initio reference results. Indeed, GEM introduces nonclassical effects by modeling the short-range quantum behavior of electric fields and therefore enables a straightforward (and selective) inclusion of the sole overlap-dependent exchange-polarization repulsive contribution by means of a Gaussian damping function acting on the GEM fields. The S/G-1 scheme is then introduced. Upon limiting the use of Gaussian electrostatics to metal centers only, it is shown to be able to capture the dominant quantum effects at play on the metal coordination sphere. S/G-1 is able to accurately reproduce ab initio total interaction energies within closed-shell metal complexes regarding each individual contribution including the separate contributions of induction, polarization, and charge-transfer. Applications of the method are provided for various systems including the HIV-1 NCp7-Zn(II) metalloprotein. S/G-1 is then extended to heavy metal complexes. Tested on Hg(II) water complexes, S/G-1 is shown to accurately model polarization up to quadrupolar response level. This opens up the possibility of embodying explicit scalar relativistic effects in molecular mechanics thanks to the direct transferability of ab initio pseudopotentials. Therefore, incorporating GEM-like electron density for a metal cation enable the introduction of nonambiguous short-range quantum effects within any point-dipole based polarizable force field without the need of an extensive parametrization.

Long term monitoring of the micro-seismicity along the Main Marmara Fault, Turkey using template matching

NASA Astrophysics Data System (ADS)

Matrullo, Emanuela; Lengliné, Olivier; Schmittbuhl, Jean; Karabulut, Hayrullah; Bouchon, Michel

2017-04-01

The Main Marmara Fault (MMF) represents a 150 km un-ruptured segment of the North Anatolian Fault located below the Marmara Sea. It poses a significant hazard for the large cities surrounding the region and in particular for the megalopolis of Istanbul. The seismic activity has been continuously monitored since 2007 by various seismic networks. For this purpose it represents an extraordinary natural laboratory to study in details the whole seismicity bringing insights into the geometry of the faults systems at depth and mechanical properties at various space-time scales. Waveform similarity-based analysis is performed on the continuous recordings to construct a refined catalog of earthquakes from 2009 to 2014. High-resolution relocation was applied using the double-difference algorithm, using cross-correlation differential travel-time data. Seismic moment magnitudes (Mw) have been computed combining the inversion of earthquake S-wave displacement spectra for the larger events and the estimation of the relative size of multiplets using the singular value decomposition (SVD) thanks the highly coherent waveforms. The obtained catalog of seismicity includes more than 15,000 events. The seismicity strongly varying along the strike and depth exhibits a complex structure that confirms the segmentation of the fault with different mechanical behavior (Schmittbuhl et al., GGG, 2016). In the central part of the Marmara Sea, seismicity is poor and scattered. To the east, in the Cinarcick basin, along the MMF, the seismicity is mainly located around 8-15 km in depth, except at both ends of this basin where the seismicity extends vertically up to surface. In the Yalova and Gemlik region (to the east not on the MMF) the seismicity is distributed over a wide range of depth (from surface to 15 km deep) and is characterized by several clusters vertically elongated. The spatio-temporal evolution of earthquake sequences, which repeatedly occur in specific sub-areas, and the seismic moment release reveals mainly typically two kinds of seismicity dynamics: swarm like episodes and mainshock-aftershock sequences. Similar features in the seismicity distribution are observed to the west, in the Tekirdag and Central Basin. These preliminary evidences, combined with the recent analysis on several long-lasting strike-slip seismic repeaters occurring below the Central Basin (Schmittbuhl et al., GRL, 2016) indicate the presence of both locked and creeping portions of the MMF. In the light of the accurate and extensive observations, several open questions emerge: What are the mechanisms responsible of these repeating earthquakes and of the earthquake swarms? What is the influence and the role of fluids in the generation of seismicity.

Towards Integrated Marmara Strong Motion Network

NASA Astrophysics Data System (ADS)

Durukal, E.; Erdik, M.; Safak, E.; Ansal, A.; Ozel, O.; Alcik, H.; Mert, A.; Kafadar, N.; Korkmaz, A.; Kurtulus, A.

2009-04-01

Istanbul has a 65% chance of having a magnitude 7 or above earthquake within the next 30 years. As part of the preparations for the future earthquake, strong motion networks have been installed in and around Istanbul. The Marmara Strong Motion Network, operated by the Department of Earthquake Engineering of Kandilli Observatory and Earthquake Research Institute, encompasses permanent systems outlined below. It is envisaged that the networks will be run by a single entity responsible for technical management and maintanence, as well as for data management, archiving and dissemination through dedicated web-based interfaces. • Istanbul Earthquake Rapid Response and Early Warning System - IERREWS (one hundred 18-bit accelerometers for rapid response; ten 24-bit accelerometers for early warning) • IGDAŞ Gas Shutoff Network (100 accelerometers to be installed in 2010 and integrated with IERREWS) • Structural Monitoring Arrays - Fatih Sultan Mehmet Suspension Bridge (1200m-long suspension bridge across the Bosphorus, five 3-component accelerometers + GPS sensors) - Hagia Sophia Array (1500-year-old historical edifice, 9 accelerometers) - Süleymaniye Mosque Array (450-year-old historical edifice,9 accelerometers) - Fatih Mosque Array (237-year-old historical edifice, 9 accelerometers) - Kanyon Building Array (high-rise office building, 5 accelerometers) - Isbank Tower Array (high-rise office building, 5 accelerometers) - ENRON Array (power generation facility, 4 acelerometers) - Mihrimah Sultan Mosque Array (450-year-old historical edifice,9 accelerometers + tiltmeters, to be installed in 2009) - Sultanahmet Mosque Array, (390-year-old historical edifice, 9 accelerometers + tiltmeters, to be installed in 2009) • Special Arrays - Atakoy Vertical Array (four 3-component accelerometers at 25, 50, 75, and 150 m depths) - Marmara Tube Tunnel (1400 m long submerged tunnel, 128 ch. accelerometric data, 24 ch. strain data, to be installed in 2010) - Air-Force Academy Array (72 ch. dense accelerometric array to be installed in 2010) - Gemlik Array (a dense basin array of 8 stations, to be installed in 2010) The objectives of these systems and networks are: (1) to produce rapid earthquake intensity, damage and loss assessment information after an earthquake (in the case of IERREWS), (2) to monitor conditions of structural systems, (3) to develop real-time data processing, analysis, and damage detection and location tools (in the case of structural networks) after an extreme event, (4) to assess spatial properties of strong ground motion and ground strain, and to characterise basin response (in the case of special arrays), (5) to investigate site response and wave propagation (in the case of vertical array). Ground motion data obtained from these strong motion networks have and are being used for investigations of attenuation, spatial variation (coherence), simulation benchmarking, source modeling, site response, seismic microzonation, system identification and structural model verification and structural health control. In addition to the systems and networks outlined above there are two temporary networks: KIMNET - a dense urban noise and microtremor network consisting of 50 broadband stations expected to be operational in mid 2009, and SOSEWIN - a 20-station, self-organizing structural integrated array at Ataköy in Istanbul.

Diamond formation through isochemical cooling of CHO fluids vs redox buffering: examples from Marange peridotitic and Zimmi eclogitic diamonds

NASA Astrophysics Data System (ADS)

Smit, Karen V.; Stachel, Thomas; Stern, Richard A.; Shirey, Steven B.; Steele, Andrew

2017-04-01

Traditional models for diamond formation within the lithospheric mantle invoke either carbonate reduction or methane oxidation. Both these mechanisms require some oxygen exchange with the surrounding wall-rock at the site of diamond precipitation. However, peridotite does not have sufficient buffering capacity to allow for diamond formation via these traditional models and instead peridotitic diamonds may form through isochemical cooling of H2O-rich CHO fluids [1]. Marange mixed-habit diamonds from eastern Zimbabwe provide the first natural confirmation of this new diamond growth model [2]. Although Marange diamonds do not contain any silicate or sulphide inclusions, they contain Ni-N-vacancy complexes detected through photoluminescence (PL) spectroscopy that suggest the source fluids equilibrated in the Ni-rich depleted peridotitic lithosphere. Cuboid sectors also contain abundant micro-inclusions of CH4, the first direct observation of reduced CH4-rich fluids that are thought to percolate through the lithospheric mantle [2]. In fluid inclusion-free diamonds, core-to-rim trends in δ13C and N content are used to infer the speciation of the diamond-forming fluid. Core to rim trends of increasing δ13C with decreasing N content are interpreted as diamond growth from oxidized CO2- or carbonate-bearing fluids. Diamond growth from reduced species should show the opposite trends - decreasing δ13C from core to rim with decreasing N content. Within the CH4-bearing growth sectors of Marange diamonds, however, such a 'reduced' trend is not observed. Rather, δ13C increases from core to rim within a homogeneously grown zone [2]. These contradictory observations can be explained through either mixing between CH4- and CO2-rich end-members of hydrous fluids [2] or through closed system precipitation from an already mixed CH4-CO2 H2O-maximum fluid with XCO2 (CO2/[CO2+CH4]) between 0.3 and 0.7 [3]. These results demonstrate that Marange diamonds precipitated from cooling CH4-CO2-bearing hydrous fluids rather than through redox buffering. As this growth mechanism applies to both the fluid-rich cuboid and gem-like octahedral sectors of Marange diamonds, a non-redox model for diamond formation from mixed CH4-CO2 fluids is indicated for a wider range of gem-quality peridotitic diamonds. Indeed, at the redox conditions of global diamond-bearing lithospheric mantle (FMQ -2 to -4; [4]), CHO fluids are strongly water-dominated and contain both CH4 and CO2 as dominant carbon species [5]. By contrast diamond formation in eclogitic assemblages, through either redox buffering or cooling of carbon-bearing fluids, is not as well constrained. Zimmi diamonds from the West African craton have eclogitic sulphide inclusions (with low Ni and high Re/Os) and formed at 650 Ma, overlapping with the timing of subduction [6]. In one Zimmi diamond, a core to rim trend of decreasing δ13C (-23.4 to -24.5 ) and N content is indicative of formation from reduced C2H6/CH4-rich fluids, likely derived from oceanic crust recycled during Neoproterozoic subduction. Unlike mixed CH4-CO2 fluids near the water maximum, isochemical cooling or ascent of such reduced CHO fluids is not effficient at diamond precipitation. Furthermore, measurable carbon isotopic variations in diamond are not predicted in this model and therefore cannot be reconciled with the ˜1 ‰ internal variation seen. Consequently, this Zimmi eclogitic diamond likely formed through redox buffering of reduced subduction-related fluids, infiltrating into sulphide-bearing eclogite. References 1. Luth and Stachel, 2014. CMP, 168, 1083 2. Smit et al., 2016. Lithos, 265, 68-81 3. Stachel et al., in review 4. Stagno et al., 2013. Nature, 493, 84-88 5. Zhang and Duan, 2009. GCA 73, 2089-2102 6. Smit et al., 2016. Precamb Res, 286, 152-166