Sample records for bottom water layer

  1. Numerical model for a watering plan to wash out organic matter from the municipal solid waste incinerator bottom ash layer in closed system disposal facilities.

    PubMed

    Ishii, Kazuei; Furuichi, Toru; Tanikawa, Noboru

    2009-02-01

    Bottom ash from municipal solid waste incineration (MSWI) is a main type of waste that is landfilled in Japan. The long-term elution of organic matter from the MSWI bottom ash layers is a concern because maintenance and operational costs of leachate treatment facilities are high. In closed system disposal facilities (CSDFs), which have a roof to prevent rainfall from infiltrating into the waste layers, water must be supplied artificially and its quantity can be controlled. However, the quantity of water needed and how to apply it (the intensity, period and frequency) have not been clearly defined. In order to discuss an effective watering plan, this study proposes a new washout model to clarify a fundamental mechanism of total organic carbon (TOC) elution behavior from MSWI bottom ash layers. The washout model considers three phases: solid, immobile water and mobile water. The parameters, including two mass transfer coefficients of the solid-immobile water phases and immobile-mobile water phases, were determined by one-dimensional column experiments for about 2 years. The intensity, period and frequency of watering and other factors were discussed based on a numerical analysis using the above parameters. As a result, our washout model explained adequately the elution behavior of TOC from the MSWI bottom ash layer before carbonation occurred (pH approximately 8.3). The determined parameters and numerical analysis suggested that there is a possibility that the minimum amount of water needed for washing out TOC per unit weight of MSWI bottom ash layer could be determined, which depends on the two mass transfer coefficients and the depth of the MSWI bottom ash layer. Knowledge about the fundamental mechanism of the elution behavior of TOC from the MSWI bottom ash layer before carbonation occurs, clarified by this study, will help an effective watering plan in CSDFs.

  2. Distribution of Arctic and Pacific copepods and their habitat in the northern Bering Sea and Chukchi Sea

    NASA Astrophysics Data System (ADS)

    Sasaki, H.; Matsuno, K.; Fujiwara, A.; Onuka, M.; Yamaguchi, A.; Ueno, H.; Watanuki, Y.; Kikuchi, T.

    2015-11-01

    The advection of warm Pacific water and the reduction of sea-ice extent in the western Arctic Ocean may influence the abundance and distribution of copepods, i.e., a key component in food webs. To understand the factors affecting abundance of copepods in the northern Bering Sea and Chukchi Sea, we constructed habitat models explaining the spatial patterns of the large and small Arctic copepods and the Pacific copepods, separately, using generalized additive models. Copepods were sampled by NORPAC net. Vertical profiles of density, temperature and salinity in the seawater were measured using CTD, and concentration of chlorophyll a in seawater was measured with a fluorometer. The timing of sea-ice retreat was determined using the satellite image. To quantify the structure of water masses, the magnitude of pycnocline and averaged density, temperature and salinity in upper and bottom layers were scored along three axes using principal component analysis (PCA). The structures of water masses indexed by the scores of PCAs were selected as explanatory variables in the best models. Large Arctic copepods were abundant in the water mass with high salinity water in bottom layer or with cold/low salinity water in upper layer and cold/high salinity water in bottom layer, and small Arctic copepods were abundant in the water mass with warm/saline water in upper layer and cold/high salinity water in bottom layers, while Pacific copepods were abundant in the water mass with warm/saline in upper layer and cold/high salinity water in bottom layer. All copepod groups were abundant in areas with deeper depth. Although chlorophyll a in upper and bottom layers were selected as explanatory variables in the best models, apparent trends were not observed. All copepod groups were abundant where the sea-ice retreated at earlier timing. Our study might indicate potential positive effects of the reduction of sea-ice extent on the distribution of all groups of copepods in the Arctic Ocean.

  3. Re-initiation of bottom water formation in the East Sea (Japan Sea) in a warming world.

    PubMed

    Yoon, Seung-Tae; Chang, Kyung-Il; Nam, SungHyun; Rho, TaeKeun; Kang, Dong-Jin; Lee, Tongsup; Park, Kyung-Ae; Lobanov, Vyacheslav; Kaplunenko, Dmitry; Tishchenko, Pavel; Kim, Kyung-Ryul

    2018-01-25

    The East Sea (Japan Sea), a small marginal sea in the northwestern Pacific, is ventilated deeply down to the bottom and sensitive to changing surface conditions. Addressing the response of this marginal sea to the hydrological cycle and atmospheric forcing would be helpful for better understanding present and future environmental changes in oceans at the global and regional scales. Here, we present an analysis of observations revealing a slowdown of the long-term deepening in water boundaries associated with changes of water formation rate. Our results indicate that bottom (central) water formation has been enhanced (reduced) with more (less) oxygen supply to the bottom (central) layer since the 2000s. This paper presents a new projection that allows a three-layered deep structure, which retains bottom water, at least until 2040, contrasting previous results. This projection considers recent increase of slope convections mainly due to the salt supply via air-sea freshwater exchange and sea ice formation and decrease of open-ocean convections evidenced by reduced mixed layer depth in the northern East Sea, resulting in more bottom water and less central water formations. Such vigorous changes in water formation and ventilation provide certain implications on future climate changes.

  4. Stable isotope evidence for the Bottom Convective Layer homogeneity in the Black Sea

    PubMed Central

    2014-01-01

    The Black Sea is the largest euxinic basin on the Earth. The anoxic zone consists of the upper part water mass stratified by density, and the lower water mass homogenized relative to density (depth >1750 m), named the Bottom Convective Layer. To assess homogeneity and possible exchange of matter across the upper and lower boundaries of the Bottom Convective Layer, new data on stable isotope composition of S, O and H were obtained. Samples were collected in August 2008 and March 2009 from two stations located in the eastern central part of the Black Sea. Distribution of δ18O and δD values of water for the entire water column did not vary seasonally. Appreciable differences were marked for δD value variation in the picnocline area (water depth 200-400 m) and in the BCL 5 m above the bottom that might be caused by penetration of intrusions with elevated portion of shelf modified Mediterranean Water. Observed linear relationship between δ18O (or δD) and salinity indicates that mixing water and salt occurs at the same time, and the deep water of the Black Sea has two end members: the high-salinity Mediterranean seawater and freshwater input. In the Bottom Convective Layer, the average δ34S (H2S) was -40.6 ± 0.5‰ and did not vary seasonally. At the bottom (depth > 2000 m), 34S depletion down to –41.0‰ was observed. Our δ34S (SO4) data are by 2-3‰ higher than those measured previously for the Bottom Convective Layer. Sulfate from the aerobic zone with δ34S (SO4) = +21‰ corresponds to ocean water sulfate and that has not been subjected to sulfate reduction. Average δ34S (SO4) values for depths > 1250 m were found to be +23.0 ± 0.2‰ (1σ). Sulfur isotope composition of sulfate does not change in the Bottom Convective Layer and on its upper and lower boundaries, and does not depend on the season of observation. PMID:24739078

  5. Observed bottom boundary layer transport and uplift on the continental shelf adjacent to a western boundary current

    NASA Astrophysics Data System (ADS)

    Schaeffer, A.; Roughan, M.; Wood, J. E.

    2014-08-01

    Western boundary currents strongly influence the dynamics on the adjacent continental shelf and in particular the cross-shelf transport and uplift through the bottom boundary layer. Four years of moored in situ observations on the narrow southeastern Australian shelf (in water depths of between 65 and 140 m) were used to investigate bottom cross-shelf transport, both upstream (30°S) and downstream (34°S) of the separation zone of the East Australian Current (EAC). Bottom transport was estimated and assessed against Ekman theory, showing consistent results for a number of different formulations of the boundary layer thickness. Net bottom cross-shelf transport was onshore at all locations. Ekman theory indicates that up to 64% of the transport variability is driven by the along-shelf bottom stress. Onshore transport in the bottom boundary layer was more intense and frequent upstream than downstream, occurring 64% of the time at 30°S. Wind-driven surface Ekman transport estimates did not balance the bottom cross-shelf flow. At both locations, strong variability was found in bottom water transport at periods of approximately 90-100 days. This corresponds with periodicity in EAC fluctuations and eddy shedding as evidenced from altimeter observations, highlighting the EAC as a driver of variability in the continental shelf waters. Ocean glider and HF radar observations were used to identify the bio-physical response to an EAC encroachment event, resulting in a strong onshore bottom flow, the uplift of cold slope water, and elevated coastal chlorophyll concentrations.

  6. Bottom-water observations in the Vema fracture zone

    NASA Astrophysics Data System (ADS)

    Eittreim, Stephen L.; Biscaye, Pierre E.; Jacobs, Stanley S.

    1983-03-01

    The Vema fracture zone trough, at 11°N between 41° and 45°E, is open to the west at the 5000-m level but is silled at the 4650-m level on the east where it intersects the axis of the Mid-Atlantic Ridge. The trough is filled with Antarctic Bottom Water (AABW) with a potential temperature of 1.32°C and salinity of 34.82 ppt. The bottom water is thermally well mixed in a nearly homogeneous layer about 700 m thick. The great thickness of this bottom layer, as compared with the bottom-water structure of the western Atlantic basin, may result from enhanced mixing induced by topographic constriction at the west end of the fracture zone trough. A benthic thermocline, with potential temperature gradients of about 1.2 mdeg m-1, is associated with an abrupt increase in turbidity with depth at about 1200 m above bottom. A transitional layer of more moderate temperature gradients, about 0.4 mdeg m-1, lies between the benthic thermocline above and the AABW below. The AABW layer whose depth-averaged suspended paniculate concentrations range from 8 to 19 μg L-1, is consistently higher in turbidity than the overlying waters. At the eastern end of the trough, 140 m below sill depth, very low northeastward current velocities, with maximums of 3 cm s-1, were recorded for an 11-day period.

  7. The Structure of Microbial Community and Degradation of Diatoms in the Deep Near-Bottom Layer of Lake Baikal

    PubMed Central

    Zakharova, Yulia R.; Galachyants, Yuri P.; Kurilkina, Maria I.; Likhoshvay, Alexander V.; Petrova, Darya P.; Shishlyannikov, Sergey M.; Ravin, Nikolai V.; Mardanov, Andrey V.; Beletsky, Alexey V.; Likhoshway, Yelena V.

    2013-01-01

    Insight into the role of bacteria in degradation of diatoms is important for understanding the factors and components of silica turnover in aquatic ecosystems. Using microscopic methods, it has been shown that the degree of diatom preservation and the numbers of diatom-associated bacteria in the surface layer of bottom sediments decrease with depth; in the near-bottom water layer, the majority of bacteria are associated with diatom cells, being located either on the cell surface or within the cell. The structure of microbial community in the near-bottom water layer has been characterized by pyrosequencing of the 16S rRNA gene, which has revealed 149 208 unique sequences. According to the results of metagenomic analysis, the community is dominated by representatives of Proteobacteria (41.9%), Actinobacteria (16%); then follow Acidobacteria (6.9%), Cyanobacteria (5%), Bacteroidetes (4.7%), Firmicutes (2.8%), Nitrospira (1.6%), and Verrucomicrobia (1%); other phylotypes account for less than 1% each. For 18.7% of the sequences, taxonomic identification has been possible only to the Bacteria domain level. Many bacteria identified to the genus level have close relatives occurring in other aquatic ecosystems and soils. The metagenome of the bacterial community from the near-bottom water layer also contains 16S rRNA gene sequences found in previously isolated bacterial strains possessing hydrolytic enzyme activity. These data show that potential degraders of diatoms occur among the vast variety of microorganisms in the near-bottom water of Lake Baikal. PMID:23560063

  8. Distribution of Arctic and Pacific copepods and their habitat in the northern Bering and Chukchi seas

    NASA Astrophysics Data System (ADS)

    Sasaki, Hiroko; Matsuno, Kohei; Fujiwara, Amane; Onuka, Misaki; Yamaguchi, Atsushi; Ueno, Hiromichi; Watanuki, Yutaka; Kikuchi, Takashi

    2016-08-01

    The advection of warm Pacific water and the reduction in sea ice in the western Arctic Ocean may influence the abundance and distribution of copepods, a key component of food webs. To quantify the factors affecting the abundance of copepods in the northern Bering and Chukchi seas, we constructed habitat models explaining the spatial patterns of large and small Arctic and Pacific copepods separately. Copepods were sampled using NORPAC (North Pacific Standard) nets. The structures of water masses indexed by principle component analysis scores, satellite-derived timing of sea ice retreat, bottom depth and chlorophyll a concentration were integrated into generalized additive models as explanatory variables. The adequate models for all copepods exhibited clear continuous relationships between the abundance of copepods and the indexed water masses. Large Arctic copepods were abundant at stations where the bottom layer was saline; however they were scarce at stations where warm fresh water formed the upper layer. Small Arctic copepods were abundant at stations where the upper layer was warm and saline and the bottom layer was cold and highly saline. In contrast, Pacific copepods were abundant at stations where the Pacific-origin water mass was predominant (i.e. a warm, saline upper layer and saline and a highly saline bottom layer). All copepod groups showed a positive relationship with early sea ice retreat. Early sea ice retreat has been reported to initiate spring blooms in open water, allowing copepods to utilize more food while maintaining their high activity in warm water without sea ice and cold water. This finding indicates that early sea ice retreat has positive effects on the abundance of all copepod groups in the northern Bering and Chukchi seas, suggesting a change from a pelagic-benthic-type ecosystem to a pelagic-pelagic type.

  9. Bottom-boundary-layer measurements on the continental shelf off the Ebro River, Spain

    USGS Publications Warehouse

    Cacchione, D.A.; Drake, D.E.; Losada, M.A.; Medina, R.

    1990-01-01

    Measurements of currents, waves and light transmission obtained with an instrumented bottom tripod (GEOPROBE) were used in conjunction with a theoretical bottom-boundary-layer model for waves and currents to investigate sediment transport on the continental shelf south of the Ebro River Delta, Spain. The current data show that over a 48-day period during the fall of 1984, the average transport at 1 m above the seabed was alongshelf and slightly offshore toward the south-southwest at about 2 cm/s. A weak storm passed through the region during this period and caused elevated wave and current speeds near the bed. The bottom-boundary-layer model predicted correspondingly higher combined wave and current bottom shear velocities at this time, but the GEOPROBE optical data indicate that little to no resuspension occurred. This result suggests that the fine-grained bottom sediment, which has a clay component of 80%, behaves cohesively and is more difficult to resuspend than noncohesive materials of similar size. Model computations also indicate that noncohesive very fine sand in shallow water (20 m deep) was resuspended and transported mainly as bedload during this storm. Fine-grained materials in shallow water that are resuspended and transported as suspended load into deeper water probably account for the slight increase in sediment concentration at the GEOPROBE sensors during the waning stages of the storm. The bottom-boundary-layer data suggest that the belt of fine-grained bottom sediment that extends along the shelf toward the southwest is deposited during prolonged periods of low energy and southwestward bottom flow. This pattern is augmented by enhanced resuspension and transport toward the southwest during storms. ?? 1990.

  10. A Study of Baroclinic Instability Induced Convergence Near the Bottom Using Water Age Simulations

    NASA Astrophysics Data System (ADS)

    Zhang, Wenxia; Hetland, Robert D.

    2018-03-01

    Baroclinic instability of lateral density gradients gives way to lateral buoyancy transport, which often results in convergence of buoyancy transport. Along a sloping bottom, the induced convergence can force upward extension of bottom water. Eddy transport induced convergence at the bottom and the consequent suspended layers of bottom properties are investigated using a three-dimensional idealized model. Motivated by the distinct characteristics of intrusions over the Texas-Louisiana shelf, a series of configurations are performed with the purpose of identifying parameter impacts on the intensity of eddy transport. This study uses the "horizontal slope Burger number" as the predominant parameter; the parameter is functioned with SH=SRi-1/2=δ/Ri to identify formation of baroclinic instability, where S is the slope Burger number, δ is the slope parameter, and Ri is the Richardson number, previously shown to be the parameter that predicts the intensity of baroclinic instability on the shelf. Intrusion spreads into the interior abutting a layer that is characterized by degraded vertical stratification; a thickening in the bottom boundary layer colocates with the intrusion, which usually thins at either edge of the intrusion because of a density barrier in association with concentrated isopycnals. The intensity of convergence degrades and bottom tracer fluxes reduce linearly with increased SH on logarithmic scales, and the characteristics of bottom boundary layer behavior and the reversal in alongshore current tend to vanish.

  11. Large Eddy Simulations of a Bottom Boundary Layer Under a Shallow Geostrophic Front

    NASA Astrophysics Data System (ADS)

    Bateman, S. P.; Simeonov, J.; Calantoni, J.

    2017-12-01

    The unstratified surf zone and the stratified shelf waters are often separated by dynamic fronts that can strongly impact the character of the Ekman bottom boundary layer. Here, we use large eddy simulations to study the turbulent bottom boundary layer associated with a geostrophic current on a stratified shelf of uniform depth. The simulations are initialized with a spatially uniform vertical shear that is in geostrophic balance with a pressure gradient due to a linear horizontal temperature variation. Superposed on the temperature front is a stable vertical temperature gradient. As turbulence develops near the bottom, the turbulence-induced mixing gradually erodes the initial uniform temperature stratification and a well-mixed layer grows in height until the turbulence becomes fully developed. The simulations provide the spatial distribution of the turbulent dissipation and the Reynolds stresses in the fully developed boundary layer. We vary the initial linear stratification and investigate its effect on the height of the bottom boundary layer and the turbulence statistics. The results are compared to previous models and simulations of stratified bottom Ekman layers.

  12. Development of the benethic nepheloid layer on the south Texas continental shelf, western Gulf of Mexico

    USGS Publications Warehouse

    Shideler, G.L.

    1981-01-01

    A monitoring study of suspended sediment on the South Texas Continental Shelf indicates that a turbid benthic nepheloid layer is regionally persistent. A sequence of quasi-synoptic measurements of the water column obtained during six cruises in an 18-month period indicates substantial spatial and temporal variability in nepheloidlayer characteristics. Regionally, the thickness of the shelf nepheloid layer increases both seaward and in a convergent alongshelf direction. Greatest thicknesses occur over a muddy substrate, indicating a causal relationship; maximum observed local thickness is 35 m which occurs along the southern shelf break. Analyses of suspended particulate matter in shelf bottom waters indicate mean concentrations ranging from 49 ?? 104 to 111 ?? 104 particle counts/cc; concentrations persistently increase shoreward throughout the region. Bottom particulate matter is predominantly composed of inorganic detritus. Admixtures of organic skeletal particles, primarily diatoms, are generally present but average less than 10% of the total particulate composition. Texturally, the particulate matter in bottom waters is predominantly poorly sorted sediment composed of very fine silt (3.9-7.8 ??m). The variability in nepheloid-layer characteristics indicates a highly dynamic shelf feature. The relationship of nepheloid-layer characteristics to hydrographic and substrate conditions suggests a conceptual model whereby nepheloid-layer development and maintenance are the results of the resuspension of sea-floor sediment. Bottom turbulence is attributed primarily to vertical shear and shoaling progressive internal waves generated by migrating shelf-water masses, especially oceanic frontal systems, and secondarily to shoaling surface gravity waves. ?? 1981.

  13. Sources, behaviors and degradation of dissolved organic matter in the East China Sea

    NASA Astrophysics Data System (ADS)

    Chen, Yan; Yang, Gui-Peng; Liu, Li; Zhang, Peng-Yan; Leng, Wei-Song

    2016-03-01

    Concentrations of dissolved organic carbon (DOC), dissolved inorganic nitrogen (DIN), dissolved organic nitrogen (DON) and its major compound classes-total hydrolysable amino acids (THAA) were measured at 4 cross-shelf transects of the East China Sea in July 2011. Surface concentrations of DOC, DIN, DON and THAA at the nearshore stations were mostly in excess of those found at the offshore sites, indicating either substantial autochthonous production or allochthonous inputs from the Changjiang River. The vertical distributions of DOC, DON and THAA showed similar trends with higher values in the surface layer, whereas the elevated concentrations of DIN were observed in the bottom layer. Major constituents of THAA presented in the study area were glycine, serine, alanine, glutamic acid, aspartic acid and valine. The mole percentages of neutral amino acids increased from surface water to bottom water, whereas acidic and hydroxy amino acids decreased with the water depth. Concentrations of DOC and THAA were negatively correlated to the ΔDIN values (the difference between the real concentration and theoretical concentration), respectively, indicating the coupling relation between dissolved organic matter (DOM) remineralization and nutrient regeneration in the water column. The C/N ratios in the water column exhibited different characteristics with elevated values appearing in the surface and bottom layers. Box and whisker plots showed that both degradation index (DI) values and THAA yields displayed a decreasing trend from the surface layer to the bottom layer, implying increasing degradation with the water depth. Our data revealed that glycine and alanine increased in relative abundance with decreasing DI, while tyrosine, valine, phenylalanine and isoleucine increased with increasing DI.

  14. Rapid Changes in Water Properties on a Shallow Reef in the Chesapeake Bay due to a Wind Driven Internal Seiche

    NASA Astrophysics Data System (ADS)

    Kilbourne, B.

    2016-12-01

    The Chesapeake Bay Interpretive Buoy System has collected oceanographic and meteorological observations in Chesapeake Bay from 2007 to the present. The relatively long and well resolved time series of wind, current, and salinity data provided by this array creates an opportunity to better understand the many finescale circulation pathways in Chesapeake Bay. The mean vertical structure of Chesapeake Bay is approximated by a three layer system: a well-mixed surface boundary layer from 1 to 8 m depth, a stratified transition layer from 8 to 15 m depth, and a well-mixed bottom boundary layer from 15 m to the bottom (typically < 30 m). The conditions in the surface and bottom boundary layers can be strikingly different with the bottom layer being saltier, lower in pH, and lower in dissolved oxygen than the surface layer. The Gooses Reef station of this array is located on `Gooses Reef', a shallow bar just 10 m in depth, dividing the Choptank River basin from the main channel of the Chesapeake Bay. This shallow bar provides habitat for oysters, a keystone species in the Chesapeake Bay, and is both commercially and ecologically critical to the region. These shallow habitats are threatened when anoxic (< 0.5 mg l-1 O2) conditions exist in the upper 10 m of the water column. The Gooses Reef station is unique in the array due to the addition of a bottom mounted sensor package; data from August 2012 show rapid changes in the salinity (11 to 17 PSU), dissolved oxygen (6 to 0.05 mg l-1) , and pH (8.3 to 7.7) at the bottom. Investigations of wind and current data before these rapid changes show along channel wind stress oscillations near the M2 tidal frequency. Current profiles from the buoy ADCP show low-frequency along-channel baroclinic oscillations. Observed currents appear to be an internal seiche, forced by resonance between the along-channel wind and diurnal tide. At the Gooses Reef bar, this internal seiche forced the bottom boundary layer up and over the bar, causing the sudden shift in water properties. These observations highlight the strong physical controls on local water conditions in the Chesapeake Bay and similar estuaries.

  15. Hydrochemistry of the Tumen River Estuary, Sea of Japan

    NASA Astrophysics Data System (ADS)

    Tishchenko, P. Ya.; Semkin, P. Yu.; Pavlova, G. Yu.; Tishchenko, P. P.; Lobanov, V. B.; Marjash, A. A.; Mikhailik, T. A.; Sagalaev, S. G.; Sergeev, A. F.; Tibenko, E. Yu.; Khodorenko, N. D.; Chichkin, R. V.; Shvetsova, M. G.; Shkirnikova, E. M.

    2018-03-01

    The hydrological and hydrochemical parameters of the Tumen River estuary were collected at 13 stations in May and October 2015. Vertical temperature, conductivity, dissolved oxygen, chlorophyll fluorescence, and turbidity profiles were obtained. Water was sampled from the surface and bottom layer. The water samples were analyzed for major ions, pH, salinity, concentrations of dissolved oxygen, major nutrients, dissolved organic carbon, humic matter, and δ18O and δD isotopes. This estuary is attributed to microtidal type with a flushing time of about 10 h. A phytoplakton bloom occurred in the top layer of the estuary. For surface horizons, the hydrochemical parameters show a linear correlation with salinity. In the bottom horizons, all these parameters, except for major ions and δ18O and δD isotopes, reveal substantial nonconservative behavior. The nonconservative behavior of the hydrochemical parameters in the bottom waters was mainly caused by degradation of the phytoplankton biomass at the water/sediment interface. Hypoxic conditions were established in the bottom waters of the estuary in May.

  16. Sound Propagation in Shallow Water with an Inhomogeneous GAS-Saturated Bottom

    NASA Astrophysics Data System (ADS)

    Grigor'ev, V. A.; Petnikov, V. G.; Roslyakov, A. G.; Terekhina, Ya. E.

    2018-05-01

    We present the methods and results of numerical experiments studying the low-frequency sound propagation in one of the areas of the Arctic shelf with a randomly inhomogeneous gas-saturated bottom. The characteristics of the upper layer of bottom sedimentary rocks (sediments) used in calculations were obtained during a 3D seismic survey and trial drilling of the seafloor. We demonstrate the possibilities of substituting in numerical simulation a real bottom with a fluid homogeneous half-space where the effective value of the sound speed is equal to the average sound speed in the bottom, with averaging along the sound propagation path to a sediment depth of 0.6 wavelength in the bottom. An original technique is proposed for estimating the sound speed propagation in an upper inhomogeneous sediment layer. The technique is based on measurements of acoustic wave attenuation in water during waveguide propagation.

  17. Migration of nitrate, nitrite, and ammonia through the municipal solid waste incinerator bottom ash layer in the simulated landfill.

    PubMed

    Yao, Jun; Chen, Luxi; Zhu, Huayue; Shen, Dongsheng; Qiu, Zhanhong

    2017-04-01

    Simulated landfill was operated for 508 days to investigate the effect of municipal solid waste incinerator (MSWI) bottom ash layer on the migration of nitrate, nitrite, and ammonia when it was used as the intermediate layer in the landfill. The result suggested that the MSWI bottom ash layer could capture the nitrate, nitrite, and ammonia from the leachate. The adsorption of the nitrate, nitrite, and ammonia on the MSWI bottom ash layer was saturated at the days 396, 34, and 97, respectively. Afterwards, the nitrogen species were desorbed from the MSWI bottom ash layer. Finally, the adsorption and desorption could reach the equilibrium. The amounts of adsorbed nitrate and nitrite on the MSWI bottom ash layer were 1685.09 and 7.48 mg, respectively, and the amount of the adsorbed and transformed ammonia was 13,773.19 mg, which was much higher than the desorbed. The water leaching test and synthetic precipitation leaching procedure (SPLP) results showed that the leachable nitrate, nitrite, and ammonia in the MSWI bottom ash were greatly increased after the landfill operation, suggesting that the adsorbed nitrogen could be finally leached out. Besides, the results also showed that MSWI bottom ash layer could affect the release of nitrate and ammonia at the initial stage of the landfill. However, it had little effect on the release of nitrite.

  18. Anoxic monimolimnia: Nutrients devious feeders or bombs ready to explode?

    NASA Astrophysics Data System (ADS)

    Gianni, Areti; Zacharias, Ierotheos

    2015-04-01

    Coastal regions are under strong human influence and its environmental impact is reflected into their water quality. Oligotrophic estuaries and coastal systems have changed in mesotrophic and/or eutrophic, shown an increase in toxic algal blooms, hypoxic/anoxic events, and massive mortalities of many aquatic and benthic organisms. In strongly stratified and productive water basins, bottom water dissolved oxygen is depleted due to the excessive organic matter decomposition in these depths. Distribution and recycling of nutrients in their water column is inextricably dependent on oxygenation and redox conditions. Bottom water anoxia accelerates PO43-, NH4+ and H2S recycling and accumulation from organic matter decomposition. The anoxic, H2S, PO43- and NH4+ rich bottom water constitutes a toxic layer, threatening the balance of the entire ecosystem. In permanently stratified water basins, storm events could result in stratification destruction and water column total mixing. The turnover brings large amounts of H2S to the surface resulting in low levels of oxygen and massive fish kills. PO43- and NH4+ are released to the interface and surface waters promoting algal blooms. Μore organic matter is produced fueling anoxia. The arising question is, whether the balance of an anoxic water ecosystem is under the threat of its hypolimnetic nutrient and sulfide load, only in the case of storm events and water column total mixing. In polymictic water basins it is clear that the accumulated, in the bottom layer, nutrients will supply surface waters, after the pycnocline overturn. Besides this mechanism of basins' water quality degradation is nowadays recognized as one of the biggest obstacles in eutrophic environments management and restoration efforts. The role of internal load, in permanently stratified water basins, is not so clear. In the present study the impact of storm events on water column stability and bottom water anoxia of meromictic coastal basins, is investigated. The importance of internal load is emerged, presenting the disturbance on the main nutrients, dissolved oxygen, hydrogen sulfide and chlorophyll distribution, caused by the total water column mixing. Additionally, the relationship between temporal nutrients variations in surface layers, of permanent anoxic coastal basins with a) changes on the physicochemical characteristics of their water column, b) changes on the bottom water phosphorus and nitrogen concentration and c) their effect on the basin's primary productivity, is sought. In order to achieve the objectives of this study, two different sets of Aitoliko basin's (western Greece) data were used. The first one includes measurements of physicochemical parameters, nutrients, chlorophyll and hydrogen sulfide, four days after a storm event and the consequent anoxic crisis in Aitoliko basin on 4th of December 2008. The second one contains respective data obtained from a biennial (May 2006-May 2008) basin's monitoring. The changes in the physical, chemical and biological characteristics, of Aitoliko basin water column, after its total mixing, highlighted the importance of the accumulated nutrients and sulfides in the bottom layer. In addition, turned out that bottom layer can supply with nutrients the surface waters, even during periods of high water column stratification. Small scale, subtle, changes in physicochemical and hydrological basin's characteristics promoted this supply, affecting both quantitative and qualitative the ecosystem's primary productivity and shifting its quality character.

  19. Distribution and transport of suspended particulate matter in Monterey Canyon, California

    USGS Publications Warehouse

    Xu, J. P.; Noble, M.; Eittreim, S.L.; Rosenfeld, L.K.; Schwing, F.B.; Pilskaln, C.H.

    2002-01-01

    From August 1993 to August 1994, six moorings that measure current, temperature, salinity, and water clarity were deployed along the axis of Monterey Canyon to study the circulation and transport of water and suspended particulate matter through the canyon system. The moorings occupied three sites that are morphologically different: a narrow transverse section (axis width 900 m) at 1450 m water depth, a wide transverse section at 2837 m, and a third site in the fan valley axis farther offshore at 3223 m that recorded for 3 yr. In addition, CTD/transmissometer casts were conducted within and near the Monterey Canyon during four cruises. Our data show a mainly biogenic, surface turbid layer, a limited intermediate nepheloid layer, and a bottom nepheloid layer. There is a consistent presence of a turbid layer within the canyon at a water depth of about 1500 m. Tidal flow dominates at all sites, but currents above the canyon rim and within the canyon appear to belong to two distinct dynamic systems. Bottom intensification of currents plays an important role in raising the near-bottom shear stress high enough that bottom sediments are often, if not always, resuspended. Mean flow pattern suggests a convergence zone between the narrow and wide site: the near-bed (100 m above bottom where the lowest current meter was located) mean transport is down-canyon at the 1450-m site, while the near-bottom transport at the 2837-m site is up-canyon, at a smaller magnitude. Transport at the 3223-m site is dominantly NNW, cross-canyon, with periods of up-canyon flow over 3 yr. A very high-turbidity event was recorded 100 m above the canyon bottom at the narrow site. The event started very abruptly and lasted more than a week. This event was not detected at either of the deeper sites. A canyon head flushing event is likely the cause. ?? 2002 Elsevier Science B.V. All rights reserved.

  20. Tracing groundwater input into Lake Vanda, Wright Valley, Antarctica using major ions, stable isotopes and noble gas

    NASA Astrophysics Data System (ADS)

    Dowling, C. B.; Poreda, R. J.; Snyder, G. T.

    2008-12-01

    The McMurdo Dry Valleys (MDV), Antarctica, is the largest ice-free region on Antarctica. Lake Vanda, located in central Wright Valley, is the deepest lake among the MDV lakes. It has a relatively fresh water layer above 50 m with a hypersaline calcium-chloride brine below (50-72 m). The Onyx River is the only stream input into Lake Vanda. It flows westward from the coastal Lower Wright Glacier and discharges into Lake Vanda. Suggested by the published literature and this study, there has been and may still be groundwater input into Lake Vanda. Stable isotopes, major ions, and noble gas data from this study coupled with previously published data indicate that the bottom waters of Lake Vanda have had significant contributions from a deep groundwater system. The dissolved gas of the bottom waters of Lake Vanda display solubility concentrations rather than the Ar-enriched dissolved gas seen in the Taylor Valley lakes (such as Lake Bonney). The isotopic data indicate that the bottom calcium-chloride-brine of Lake Vanda has undergone very little evaporation. The calcium-chloride chemistry of the groundwater that discharges into Lake Vanda most likely results from the chemical weathering and dissolution of cryogenic evaporites (antarcticite and gypsum) within the glacial sediments of Wright Valley. The high calcium concentrations of the brine have caused gypsum to precipitate on the lake bottom. Our work also supports previous physical and chemical observations suggesting that the upper portion actively circulates and the hypersaline bottom layer does not. The helium and calcium chloride values are concentrated at the bottom, with a very narrow transition layer between it and the above fresh water. If the freshwater layer did not actively circulate, then diffusion over time would have caused the helium and calcium chloride to slowly permeate upwards through the water column.

  1. Wind-induced flow velocity effects on nutrient concentrations at Eastern Bay of Lake Taihu, China.

    PubMed

    Jalil, Abdul; Li, Yiping; Du, Wei; Wang, Jianwei; Gao, Xiaomeng; Wang, Wencai; Acharya, Kumud

    2017-07-01

    Shallow lakes are highly sensitive to respond internal nutrient loading due to wind-induced flow velocity effects. Wind-induced flow velocity effects on nutrient suspension were investigated at a long narrow bay of large shallow Lake Taihu, the third largest freshwater lake in China. Wind-induced reverse/compensation flow and consistent flow field probabilities at vertical column of the water were measured. The probabilities between the wind field and the flow velocities provided a strong correlation at the surface (80.6%) and the bottom (65.1%) layers of water profile. Vertical flow velocity profile analysis provided the evidence of delay response time to wind field at the bottom layer of lake water. Strong wind field generated by the west (W) and west-north-west (WNW) winds produced displaced water movements in opposite directions to the prevailing flow field. An exponential correlation was observed between the current velocities of the surface and the bottom layers while considering wind speed as a control factor. A linear model was developed to correlate the wind field-induced flow velocity impacts on nutrient concentration at the surface and bottom layers. Results showed that dominant wind directions (ENE, E, and ESE) had a maximum nutrient resuspension contribution (nutrient resuspension potential) of 34.7 and 43.6% at the surface and the bottom profile layers, respectively. Total suspended solids (TSS), total nitrogen (TN), and total phosphorus (TP) average concentrations were 6.38, 1.5, and 0.03 mg/L during our field experiment at Eastern Bay of Lake Taihu. Overall, wind-induced low-to-moderate hydrodynamic disturbances contributed more in nutrient resuspension at Eastern Bay of Lake Taihu. The present study can be used to understand the linkage between wind-induced flow velocities and nutrient concentrations for shallow lakes (with uniform morphology and deep margins) water quality management and to develop further models.

  2. Abyssal Upwelling and Downwelling and the role of boundary layers

    NASA Astrophysics Data System (ADS)

    McDougall, T. J.; Ferrari, R. M.

    2016-02-01

    The bottom-intensified mixing activity arising from the interaction of internal tides with bottom topography implies that the dianeutral advection in the ocean interior is downwards, rather than upwards as is required by continuity. The upwelling of Bottom Water through density surfaces in the deep ocean is however possible because of the sloping nature of the sea floor. A budget study of the abyss (deeper than 2000m) will be described that shows that while the upwelling of Bottom Water might be 25 Sv, this is achieved by very strong upwelling in the bottom turbulent boundary layer (of thickness 50m) of 100 Sv and strong downwelling in the ocean interior of 75 Sv. This downwelling occurs within 10 degrees of longitude of the continental boundaries. This near-boundary confined strong upwelling and downwelling clearly has implications for the Stommel-Arons circulation.

  3. Observations of the R reflector and sediment interface reflection at the Shallow Water '06 Central Site.

    PubMed

    Choi, Jee Woong; Dahl, Peter H; Goff, John A

    2008-09-01

    Acoustic bottom-interacting measurements from the Shallow Water '06 experiment experiment (frequency range 1-20 kHz) are presented. These are co-located with coring and stratigraphic studies showing a thin (approximately 20 cm) higher sound speed layer overlaying a thicker (approximately 20 m) lower sound speed layer ending at a high-impedance reflector (R reflector). Reflections from the R reflector and analysis of the bottom reflection coefficient magnitude for the upper two sediment layers confirm both these features. Geoacoustic parameters are estimated, dispersion effects addressed, and forward modeling using the parabolic wave equation undertaken. The reflection coefficient measurements suggest a nonlinear attenuation law for the thin layer of sandy sediments.

  4. A Water Model Study on Mixing Behavior of the Two-Layered Bath in Bottom Blown Copper Smelting Furnace

    NASA Astrophysics Data System (ADS)

    Shui, Lang; Cui, Zhixiang; Ma, Xiaodong; Jiang, Xu; Chen, Mao; Xiang, Yong; Zhao, Baojun

    2018-05-01

    The bottom-blown copper smelting furnace is a novel copper smelter developed in recent years. Many advantages of this furnace have been found, related to bath mixing behavior under its specific gas injection scheme. This study aims to use an oil-water double-phased laboratory-scale model to investigate the impact of industry-adjustable variables on bath mixing time, including lower layer thickness, gas flow rate, upper layer thickness and upper layer viscosity. Based on experimental results, an overall empirical relationship of mixing time in terms of these variables has been correlated, which provides the methodology for industry to optimize mass transfer in the furnace.

  5. What Happens Where the Water and the Rock Touch in Small Space Bodies

    NASA Astrophysics Data System (ADS)

    Byrne, P. K.; Regensburger, P. V.; Klimczak, C.; Bohnenstiehl, D. R.; Dombard, A. J.; Hauck, S. A., II

    2017-12-01

    There are several small space bodies that go around bigger worlds that might have a layer of water under a layer of ice. Lots of study has been done to understand the outside ice layer of these small space bodies, because the ice can tells us important things about the big water layer under it. Some of these small space bodies are very interesting because the right things for life—water, hot rock, and food—might be at the bottom of the water layer, where it touches the top of the next layer down, which is made of rock. But it is very hard to understand what this rock at the bottom of the water is like, because we can't see it. So, we are imagining what this rock is like by thinking about what the rock is like under the water layer on our own world. If hot rock comes out of the rock layer through cracks under the water, the cold of the water makes the hot rock go very cold very fast, and it makes funny rolls as it does so. This might happen on some small space bodies that are hot enough on the inside to make hot rock. We know that on our own world the rock layer under the water is wet to as far down as cracks can go, so it makes sense that this is true for small space bodies, too. We did some thinking about numbers and found out that the cracks can go a few ten hundred steps into the rock layer on small space bodies, but for bigger (well, not quite so small) space bodies, the cracks can go at least tens of ten hundred steps into the rock layer. This means that water goes into the rock layer this much, too. But get this: some small bodies are not really that small—one of them is bigger than the first world from the Sun! And on a few of these big (small) bodies, the layer of water is so heavy that the bottom of that water is pushed together from all sides and turns into a type of hot ice. This means that, for these big (small) worlds, the water can't get into the rock layer through cracks (since there is a layer of hot ice in the way), and so these bodies are not such good places to think about where life might be.

  6. Depth investigation of rapid sand filters for drinking water production reveals strong stratification in nitrification biokinetic behavior.

    PubMed

    Tatari, K; Smets, B F; Albrechtsen, H-J

    2016-09-15

    The biokinetic behavior of NH4(+) removal was investigated at different depths of a rapid sand filter treating groundwater for drinking water preparation. Filter materials from the top, middle and bottom layers of a full-scale filter were exposed to various controlled NH4(+) loadings in a continuous-flow lab-scale assay. NH4(+) removal capacity, estimated from short term loading up-shifts, was at least 10 times higher in the top than in the middle and bottom filter layers, consistent with the stratification of Ammonium Oxidizing Bacteria (AOB). AOB density increased consistently with the NH4(+) removal rate, indicating their primarily role in nitrification under the imposed experimental conditions. The maximum AOB cell specific NH4(+) removal rate observed at the bottom was at least 3 times lower compared to the top and middle layers. Additionally, a significant up-shift capacity (4.6 and 3.5 times) was displayed from the top and middle layers, but not from the bottom layer at increased loading conditions. Hence, AOB with different physiological responses were active at the different depths. The biokinetic analysis predicted that despite the low NH4(+) removal capacity at the bottom layer, the entire filter is able to cope with a 4-fold instantaneous loading increase without compromising the effluent NH4(+). Ultimately, this filter up-shift capacity was limited by the density of AOB and their biokinetic behavior, both of which were strongly stratified. Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. SAR imaging and hydrodynamic analysis of ocean bottom topographic waves

    NASA Astrophysics Data System (ADS)

    Zheng, Quanan; Li, Li; Guo, Xiaogang; Ge, Yong; Zhu, Dayong; Li, Chunyan

    2006-09-01

    The satellite synthetic aperture radar (SAR) images display wave-like patterns of the ocean bottom topographic features at the south outlet of Taiwan Strait (TS). Field measurements indicate that the most TS water body is vertically stratified. However, SAR imaging models available were developed for homogeneous waters. Hence explaining SAR imaging mechanisms of bottom features in a stratified ocean is beyond the scope of those models. In order to explore these mechanisms and to determine the quantitative relations between the SAR imagery and the bottom features, a two-dimensional, three-layer ocean model with sinusoidal bottom topographic features is developed. Analytical solutions and inferences of the momentum equations of the ocean model lead to the following conditions. (1) In the lower layer, the topography-induced waves (topographic waves hereafter) exist in the form of stationary waves, which satisfy a lower boundary resonance condition σ = kC0, here σ is an angular frequency of the stationary waves, k is a wavenumber of bottom topographic corrugation, and C0 is a background current speed. (2) As internal waves, the topographic waves may propagate vertically to the upper layer with an unchanged wavenumber k, if a frequency relation N3 < σ < N2 is satisfied, here N2 and N3 are the Brunt-Wäisälä frequencies of middle layer and upper layer, respectively. (3) The topographic waves are extremely amplified if an upper layer resonance condition is satisfied. The SAR image of topographic waves is derived on the basis of current-modulated small wave spectra. The results indicate that the topographic waves on SAR images have the same wavelength of bottom topographic corrugation, and the imagery brightness peaks are either inphase or antiphase with respect to the topographic corrugation, depending on a sign of a coupling factor. These theoretical predictions are verified by field observations. The results of this study provide a physical basis for quantitative interpretation of SAR images of bottom topographic waves in the stratified ocean.

  8. High Energy Benthic Boundary Layer Experiment (HEBBLE): Preliminary program plan and conceptual design

    NASA Technical Reports Server (NTRS)

    Frewing, K.

    1980-01-01

    Deep sea processes of flow-sediment interaction, particularly the role of high energy ocean bottom current events in forming the seafloor topography, transporting material, and mixing the bottom of the water column are examined. A series of observations at and near the sea bottom, in water depths of 4 to 5 km, in areas of the western North Atlantic where high energy current events occur, include site surveys and physical reconnaissance to identify suitable areas and positions, and one or more six month experiments to investigate temporal and spatial variations of high energy events within the boundary layer and their interaction with the seabed. Descriptions of proposed HEBBLE activities are included, with emphasis on technology transfer to the oceanographic community through design, fabrication, testing, and operation of an instrumented ocean bottom lander.

  9. Elevated [CO2] mitigates the effect of surface drought by stimulating root growth to access sub-soil water.

    PubMed

    Uddin, Shihab; Löw, Markus; Parvin, Shahnaj; Fitzgerald, Glenn J; Tausz-Posch, Sabine; Armstrong, Roger; O'Leary, Garry; Tausz, Michael

    2018-01-01

    Through stimulation of root growth, increasing atmospheric CO2 concentration ([CO2]) may facilitate access of crops to sub-soil water, which could potentially prolong physiological activity in dryland environments, particularly because crops are more water use efficient under elevated [CO2] (e[CO2]). This study investigated the effect of drought in shallow soil versus sub-soil on agronomic and physiological responses of wheat to e[CO2] in a glasshouse experiment. Wheat (Triticum aestivum L. cv. Yitpi) was grown in split-columns with the top (0-30 cm) and bottom (31-60 cm; 'sub-soil') soil layer hydraulically separated by a wax-coated, root-penetrable layer under ambient [CO2] (a[CO2], ∼400 μmol mol-1) or e[CO2] (∼700 μmol mol-1) [CO2]. Drought was imposed from stem-elongation in either the top or bottom soil layer or both by withholding 33% of the irrigation, resulting in four water treatments (WW, WD, DW, DD; D = drought, W = well-watered, letters denote water treatment in top and bottom soil layer, respectively). Leaf gas exchange was measured weekly from stem-elongation until anthesis. Above-and belowground biomass, grain yield and yield components were evaluated at three developmental stages (stem-elongation, anthesis and maturity). Compared with a[CO2], net assimilation rate was higher and stomatal conductance was lower under e[CO2], resulting in greater intrinsic water use efficiency. Elevated [CO2] stimulated both above- and belowground biomass as well as grain yield, however, this stimulation was greater under well-watered (WW) than drought (DD) throughout the whole soil profile. Imposition of drought in either or both soil layers decreased aboveground biomass and grain yield under both [CO2] compared to the well-watered treatment. However, the greatest 'CO2 fertilisation effect' was observed when drought was imposed in the top soil layer only (DW), and this was associated with e[CO2]-stimulation of root growth especially in the well-watered bottom layer. We suggest that stimulation of belowground biomass under e[CO2] will allow better access to sub-soil water during grain filling period, when additional water is converted into additional yield with high efficiency in Mediterranean-type dryland agro-ecosystems. If sufficient water is available in the sub-soil, e[CO2] may help mitigating the effect of drying surface soil.

  10. The nepheloid bottom layer and water masses at the shelf break of the western Ross Sea

    NASA Astrophysics Data System (ADS)

    Capello, Marco; Budillon, Giorgio; Cutroneo, Laura; Tucci, Sergio

    2009-06-01

    In the austral summers of 2000/2001 and 2002/2003 the Italian CLIMA Project carried out two oceanographic cruises along the northwestern margin of the Ross Sea, where the Antarctic Bottom Water forms. Here there is an interaction between the water masses on the sea floor of the outer shelf and slope with a consequent evolution of benthic nepheloid layers and an increase in total particulate matter. We observed three different situations: (a) the presence of triads (bottom structures characterized by a concomitant jump in turbidity, temperature, and salinity data) and high re-suspension phenomena related to the presence of the Circumpolar Deep Water and its mixing with cold, salty shelf waters associated with gravity currents; (b) the absence of triads with high re-suspension, implying that when the gravity currents are no longer active the benthic nepheloid layer may persist until the suspended particles settle to the sea floor, suggesting that the turbidity data can be used to study recent gravity current events; and (c) the absence of turbidity and sediment re-suspension phenomena supports the theory that a steady situation had been re-established and the current interaction no longer occurred or had finished sometime before.

  11. Observations of near-bottom currents in Bornholm Basin, Slupsk Furrow and Gdansk Deep

    NASA Astrophysics Data System (ADS)

    Bulczak, A. I.; Rak, D.; Schmidt, B.; Beldowski, J.

    2016-06-01

    Dense bottom currents are responsible for transport of the salty inflow waters from the North Sea driving ventilation and renewal of Baltic deep waters. This study characterises dense currents in three deep locations of the Baltic Proper: Bornholm Basin (BB), Gdansk Basin (GB) and Slupsk Furrow (SF). These locations are of fundamental importance for the transport and pollution associated with chemical munitions deposited in BB and GB after 2nd World War. Of further importance the sub-basins are situated along the pathway of dense inflowing water.Current velocities were measured in the majority of the water column during regular cruises of r/v Oceania and r/v Baltica in 2001-2012 (38 cruises) by 307 kHz vessel mounted (VM), downlooking ADCP. Additionally, the high-resolution CTD and oxygen profiles were collected. Three moorings measured current velocity profiles in SF and GB over the summer 2012. In addition, temperature, salinity, oxygen and turbidity were measured at about 1 m above the bottom in GB. The results showed that mean current speed across the Baltic Proper was around 12 cm s-1 and the stronger flow was characteristic to the regions located above the sills, in the Bornholm and Slupsk Channels, reaching on average about 20 cm s-1. The results suggest that these regions are important for the inflow of saline waters into the eastern Baltic and are the areas of intense vertical mixing. The VM ADCP observations indicate that the average near-bottom flow across the basin can reach 35±6 cm s-1. The mooring observations also showed similar near-bottom flow velocities. However, they showed that the increased speed of the near-bottom layer occurred frequently in SF and GB during short time periods lasting for about few to several days or 10-20% of time. The observations showed that the bottom mixed layer occupies at least 10% of the water column and the turbulent mixing induced by near-bottom currents is likely to produce sediment resuspension and transport within the layer in all three sub-basins. The turbidity measurements, performed for 5-month-long time period over the summer 2012 in GB show that increased sediment resuspension is associated with a faster near-bottom flow.

  12. Bottom water circulation in Cascadia Basin

    NASA Astrophysics Data System (ADS)

    Hautala, Susan L.; Paul Johnson, H.; Hammond, Douglas E.

    2009-10-01

    A combination of beta spiral and minimum length inverse methods, along with a compilation of historical and recent high-resolution CTD data, are used to produce a quantitative estimate of the subthermocline circulation in Cascadia Basin. Flow in the North Pacific Deep Water, from 900-1900 m, is characterized by a basin-scale anticyclonic gyre. Below 2000 m, two water masses are present within the basin interior, distinguished by different potential temperature-salinity lines. These water masses, referred to as Cascadia Basin Bottom Water (CBBW) and Cascadia Basin Deep Water (CBDW), are separated by a transition zone at about 2400 m depth. Below the depth where it freely communicates with the broader North Pacific, Cascadia Basin is renewed by northward flow through deep gaps in the Blanco Fracture Zone that feeds the lower limb of a vertical circulation cell within the CBBW. Lower CBBW gradually warms and returns to the south at lighter density. Isopycnal layer renewal times, based on combined lateral and diapycnal advective fluxes, increase upwards from the bottom. The densest layer, existing in the southeast quadrant of the basin below ˜2850 m, has an advective flushing time of 0.6 years. The total volume flushing time for the entire CBBW is 2.4 years, corresponding to an average water parcel residence time of 4.7 years. Geothermal heating at the Cascadia Basin seafloor produces a characteristic bottom-intensified temperature anomaly and plays an important role in the conversion of cold bottom water to lighter density within the CBBW. Although covering only about 0.05% of the global seafloor, the combined effects of bottom heat flux and diapycnal mixing within Cascadia Basin provide about 2-3% of the total required global input to the upward branch of the global thermohaline circulation.

  13. Mass-physical properties of surficial sediments on the Rhoˆne continental margin: implications for the nepheloid benthic layer

    NASA Astrophysics Data System (ADS)

    Chassefiere, Bernard

    1990-09-01

    Mass-physical properties of the surficial (upper 5 m) sediments on the Gulf of Lions continental margin were analysed, from more than 100 short (1 m) and longer (5 m) cores obtained during several cruises. Data include water content, unit weight, Atterberg limits (liquid limit, plastic limit, plasticity index), shear strength and compression index, and are used to determine: first, the mass property distribution, according to the main parameters influencing mass-physical properties; the relationships between these properties and the nepheloid layer on the shelf. The shoreline (lagoons) and inner shelf are characterized by low density and shear strength and high water content deposits, due to electrochemical flocculation of the sediment. The outer shelf is blanketed by higher density and shear strength and lower water content deposits generated by normal settling of suspended particles. On the inner shelf, during river peak discharges, a short-term thin bottom layer of "yogurt-like" [ FASS (1985) Geomarine Letters, 4, 147-152; FASS (1986) Continental Shelf Research, 6, 189-208] fluid-mud (unit weight lower than 1.3 mg m -3) is supplied, by a bottom nepheloid layer. During stormy periods, this "yogurt-like" layer (about 10 cm thick) partly disappears by resuspension of suspended particulate matter; this is advected, in the bottom nepheloid layer, over the shelf and the canyons within the upper slope.

  14. Deep water characteristics and circulation in the South China Sea

    NASA Astrophysics Data System (ADS)

    Wang, Aimei; Du, Yan; Peng, Shiqiu; Liu, Kexiu; Huang, Rui Xin

    2018-04-01

    This study investigates the deep circulation in the South China Sea (SCS) using oceanographic observations combined with results from a bottom layer reduced gravity model. The SCS water, 2000 m below the surface, is quite different from that in the adjacent Pacific Ocean, and it is characterized by its low dissolved oxygen (DO), high temperature and low salinity. The horizontal distribution of deep water properties indicates a basin-scale cyclonic circulation driven by the Luzon overflow. The results of the bottom layer reduced gravity model are consistent with the existence of the cyclonic circulation in the deep SCS. The circulation is stronger at the northern/western boundary. After overflowing the sill of the Luzon Strait, the deep water moves broadly southwestward, constrained by the 3500 m isobath. The broadening of the southward flow is induced by the downwelling velocity in the interior of the deep basin. The main deep circulation bifurcates into two branches after the Zhongsha Islands. The southward branch continues flowing along the 3500 m isobath, and the eastward branch forms the sub-basin scale cyclonic circulation around the seamounts in the central deep SCS. The returning flow along the east boundary is fairly weak. The numerical experiments of the bottom layer reduced gravity model reveal the important roles of topography, bottom friction, and the upwelling/downwelling pattern in controlling the spatial structure, particularly the strong, deep western boundary current.

  15. Estimating Bottom Water Dissolved Oxygen in the Mississippi River Gulf Outlet and Gulf Intracoastal Waterway Resulting from Proposed Structures

    DTIC Science & Technology

    2008-09-01

    used in the analysis. The analytical approach assumes steady-state, summer conditions applied to a continuously stirred tank reactor ( CSTR ). CSTR ...constituent due to the fully mixed CSTR assumption. Thus, there is no spatial dimensionality. The DO CSTR model is solved using a spreadsheet...For this study, the CSTR represents the bottom meter of water along the reach of the channel being assessed. A unit bottom layer thickness of 1 m

  16. Deep sediment resuspension and thick nepheloid layer generation by open-ocean convection

    NASA Astrophysics Data System (ADS)

    Durrieu de Madron, X.; Ramondenc, S.; Berline, L.; Houpert, L.; Bosse, A.; Martini, S.; Guidi, L.; Conan, P.; Curtil, C.; Delsaut, N.; Kunesch, S.; Ghiglione, J. F.; Marsaleix, P.; Pujo-Pay, M.; Séverin, T.; Testor, P.; Tamburini, C.

    2017-03-01

    The Gulf of Lions in the northwestern Mediterranean is one of the few sites around the world ocean exhibiting deep open-ocean convection. Based on 6 year long (2009-2015) time series from a mooring in the convection region, shipborne measurements from repeated cruises, from 2012 to 2015, and glider measurements, we report evidence of bottom thick nepheloid layer formation, which is coincident with deep sediment resuspension induced by bottom-reaching convection events. This bottom nepheloid layer, which presents a maximum thickness of more than 2000 m in the center of the convection region, probably results from the action of cyclonic eddies that are formed during the convection period and can persist within their core while they travel through the basin. The residence time of this bottom nepheloid layer appears to be less than a year. In situ measurements of suspended particle size further indicate that the bottom nepheloid layer is primarily composed of aggregates between 100 and 1000 µm in diameter, probably constituted of fine silts. Bottom-reaching open ocean convection, as well as deep dense shelf water cascading that occurred concurrently some years, lead to recurring deep sediments resuspension episodes. They are key mechanisms that control the concentration and characteristics of the suspended particulate matter in the basin, and in turn affect the bathypelagic biological activity.

  17. Distribution of Different Biogeographical Tintinnids in Yellow Sea and Bohai Sea

    NASA Astrophysics Data System (ADS)

    Chen, Xue; Li, Haibo; Zhao, Yuan; Zhao, Li; Dong, Yi; Zhang, Wuchang; Xiao, Tian

    2018-04-01

    There were different biogeographical tintinnids in the oceans. Knowledge of their distribution pattern and mixing was important to the understanding of ecosystem functions. Yellow Sea (YS) and Bohai Sea (BS) were semi-enclosed seas influenced by warm water intrusion and YS cold bottom water. The occurrence of tintinnids in YS and BS during two cruises (summer and winter) were investigated to find out: i) whether warm-water tintinnids appeared in YS and BS; ii) whether boreal tintinnids appeared in high summer; iii) the core area of neritic tintinnids and iv) how these different biogeographical tintinnids mixed. Our results showed that tintinnid community was dominated by neritic tintinnid. We confirmed the occurrence of warm-water tintinnids in summer and winter. In summer, they intruded into BS and mainly distributed in the upper 20 m where Yellow Sea Surface Warm Water (YSSWW) developed. In winter, they were limited in the surface water of central deep region (bottom depth >50 m) of YS where were affected by Yellow Sea Warm Water (YSWW). Boreal tintinnids occurred in YS in high summer (August) and in winter, while they were not observed in BS. In summer, the highest abundance of boreal tintinnids occurred in Yellow Sea Bottom Cold Water, indicating the presence of an oversummering stock. In winter, they were concentrated in the north of YSWW. Vertically, neritic tintinnids abundance was high in the bottom layers. Horizontally, high neritic tintinnids abundance in bottom layers occurred along the 50 m isobath coinciding with the position of front systems. Front systems were the core distribution area of neritic tintinnids. High abundance areas of warm-water and boreal tintinnids were clearly separated vertically in summer, and horizontally in winter. High abundance of neritic tintinnids rarely overlapped with that of warm-water or boreal tintinnids.

  18. Trawling-induced daily sediment resuspension in the flank of a Mediterranean submarine canyon

    NASA Astrophysics Data System (ADS)

    Martín, Jacobo; Puig, Pere; Palanques, Albert; Ribó, Marta

    2014-06-01

    Commercial bottom trawling is one of the anthropogenic activities causing the biggest impact on the seafloor due to its recurrence and global distribution. In particular, trawling has been proposed as a major driver of sediment dynamics at depths below the reach of storm waves, but the issue is at present poorly documented with direct observations. This paper analyses changes in water turbidity in a tributary valley of the La Fonera (=Palamós) submarine canyon, whose flanks are routinely exploited by a local trawling fleet down to depths of 800 m. A string of turbidimeters was deployed at 980 m water depth inside the tributary for two consecutive years, 2010-2011. The second year, an ADCP profiled the currents 80 m above the seafloor. The results illustrate that near-bottom water turbidity at the study site is heavily dominated, both in its magnitude and temporal patterns, by trawling-induced sediment resuspension at the fishing ground. Resuspended sediments are channelised along the tributary in the form of sediment gravity flows, being recorded only during working days and working hours of the trawling fleet. These sediment gravity flows generate turbid plumes that extend to at least 100 m above the bottom, reaching suspended sediment concentrations up to 236 mg l-1 close to the seafloor (5 m above bottom). A few hours after the end of daily trawling activities, water turbidity progressively decreases but resuspended particles remain in suspension for several hours, developing bottom and intermediate nepheloid layers that reach background levels ˜2 mg l-1 before trawling activities resume. The presence of these nepheloid layers was recorded in a CTD+turbidimeter transect conducted across the fishing ground a few hours after the end of a working day. These results highlight that deep bottom trawling can effectively replace natural processes as the main driving force of sediment resuspension on continental slope regions and generate increased near-bottom water turbidity that propagates from fishing grounds to wider and deeper areas via sediment gravity flows and nepheloid layer development.

  19. Role of cold water and beta-effect in the formation of the East Korean Warm Current in the East/Japan Sea: a numerical experiment

    NASA Astrophysics Data System (ADS)

    Kim, Yong-Yub; Cho, Yang-Ki; Kim, Young Ho

    2018-06-01

    The contributions of bottom cold water and planetary β-effect to the formation of the East Korean Warm Current (EKWC), the western boundary current in the East/Japan Sea (EJS), were evaluated using an idealized three-dimensional numerical model. The model results suggest that the bottom cold water and, to a lesser extent, the planetary β-effect both contribute to the formation of the EKWC. The cold water functions as the bottom of the upper layer, to control the EKWC via conservation of potential vorticity. It is known that cold waters, such as the North Korean Cold Water and Korea Strait Bottom Cold Water often observed during summer along the southwestern coast of the EJS, originate from the winter convection in the northern area. Observational studies consistently show that the EKWC strengthens in summer when the cold water extends further south along the western boundary.

  20. 19. EMPTY SEDIMENTATION TANKS. TOP LAYER OF WATER FLOWS OVER ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    19. EMPTY SEDIMENTATION TANKS. TOP LAYER OF WATER FLOWS OVER TRIANGULATED CHANNELS AND OUT THE RAISED DUCTS TO FILTRATION PLANT. MOVEABLE BOARDS ON BOTTOM ASSIST IN REMOVING SLUDGE. VIEW LOOKING NORTHEAST. FILTER CONTROL BUILDING AT REAR. - F. E. Weymouth Filtration Plant, 700 North Moreno Avenue, La Verne, Los Angeles County, CA

  1. Design high water clearances for highway pavements : [executive summary].

    DOT National Transportation Integrated Search

    2008-01-01

    The majority of state roads in Florida are built using asphalt concrete surfaces. They are constructed in layers. The bottom layer consists of the native soil. The top layer is the surface course, or pavement. It is built upon one or more intermediat...

  2. An analytical two-flow model to simulate the distribution of irradiance in coastal waters with a wind-roughed surface and bottom reflectance

    NASA Astrophysics Data System (ADS)

    Ma, Wei-Ming

    1997-06-01

    An analytical two-flow model is derived from the radiative transfer equation to simulate the distribution of irradiance in coastal waters with a wind-roughed surface and bottom reflectance. The model utilizes unique boundary conditions, including the surface slope of the downwelling and upwelling irradiance as well as the influence of wind and bottom reflectance on simulated surface reflectance. The developed model provides a simple mathematical concept for understanding the irradiant light flux and associated processes in coastal or fresh water as well as turbid estuarine waters. The model is applied to data from the Banana River and coastal Atlantic Ocean water off the east coast of central Florida, USA. The two-flow irradiance model is capable of simulating realistic above-surface reflectance signatures under wind-roughened air-water surface given realistic input parameters including a specular flux conversion coefficient, absorption coefficient, backscattering coefficient, atmospheric visibility, bottom reflectance, and water depth. The root-mean-squared error of the calculated above-surface reflectances is approximately 3% in the Banana River and is less than 15% in coastal Atlantic Ocean off the east of Florida. Result of the subsurface reflectance sensitivity analysis indicates that the specular conversion coefficient is the most sensitive parameter in the model, followed by the beam attenuation coefficient, absorption coefficient, water depth, backscattering coefficient, specular irradiance, diffuse irradiance, bottom reflectance, and wind speed. On the other hand, result of the above-surface reflectance sensitivity analysis indicates that the wind speed is the most important parameter, followed by bottom reflectance, attenuation coefficient, water depth, conversion coefficient, specular irradiance, downwelling irradiance, absorption coefficient, and backscattering coefficient. Model results depend on the accuracy of these parameters to a large degree and more important the water depth and value of the bottom reflectance. The results of this work indicates little change of subsurface or in-water reflectances, due to variations of wind speed and observation angle. Simulations of the wind effect on the total downwelling irradiance from the two- flow model indicates that the total downwelling irradiance just below a wind-roughened water surface increases to about 1% of the total downwelling irradiance on a calm water surface when the sun is near zenith and increases to about 3% when the sun is near the horizon. This analytically based model, solved or developed utilizing the unique boundary conditions, can be applied to remote sensing of oceanic upper mixed layer dynamics, plant canopies, primary production, and shallow water environments with different bottom type reflectances. Future applications may include determining effects of sediment resuspension of bottom sediments in the bottom boundary layer on remotely sensed data.

  3. An analytical model of capped turbulent oscillatory bottom boundary layers

    NASA Astrophysics Data System (ADS)

    Shimizu, Kenji

    2010-03-01

    An analytical model of capped turbulent oscillatory bottom boundary layers (BBLs) is proposed using eddy viscosity of a quadratic form. The common definition of friction velocity based on maximum bottom shear stress is found unsatisfactory for BBLs under rotating flows, and a possible extension based on turbulent kinetic energy balance is proposed. The model solutions show that the flow may slip at the top of the boundary layer due to capping by the water surface or stratification, reducing the bottom shear stress, and that the Earth's rotation induces current and bottom shear stress components perpendicular to the interior flow with a phase lag (or lead). Comparisons with field and numerical experiments indicate that the model predicts the essential characteristics of the velocity profiles, although the agreement is rather qualitative due to assumptions of quadratic eddy viscosity with time-independent friction velocity and a well-mixed boundary layer. On the other hand, the predicted linear friction coefficients, phase lead, and veering angle at the bottom agreed with available data with an error of 3%-10%, 5°-10°, and 5°-10°, respectively. As an application of the model, the friction coefficients are used to calculate e-folding decay distances of progressive internal waves with a semidiurnal frequency.

  4. Looking into 'London'

    NASA Technical Reports Server (NTRS)

    2004-01-01

    This mosaic image from the microscopic imager on the Mars Exploration Rover Opportunity shows the rock abrasion tool target, 'London.' The image was taken by the Mars Exploration Rover Opportunity on its 149th sol on Mars (June 24, 2004). Scientists 'read' the geology of the image from bottom to top, with the youngest material pictured at the bottom of the image and the oldest material in the layers pictured at the top. Millimeter-scale layers run horizontally across the exposed surface, with two sliced sphere-like objects, or 'blueberries' on the upper left and upper right sides of the impression. This material is similar to the evaporative material found in 'Eagle Crater.' However, the intense review of these layers in Endurance Crater is, in essence, deepening the water story authored by ancient Mars.

    In Eagle Crater, the effects of water were traced down a matter of centimeters. Endurance Crater's depth has allowed the tracing of water's telltale marks up to meters. Another process that significantly affects martian terrain is muddying the water story a bit. Although it is clear that the layers in Endurance were affected by water, it is also evident that Aeolian, or wind, processes have contributed to the makeup of the crater.

  5. Short-term environmental impact of clam dredging in coastal waters (south of Portugal): chemical disturbance and subsequent recovery of seabed.

    PubMed

    Falcão, M; Gaspar, M B; Caetano, M; Santos, M N; Vale, C

    2003-12-01

    The physical and chemical changes in sediment and near bottom water caused by clam dredging were examined during July and September 1999, at two locations Vilamoura (VL) and Armona (AR), south coast of Portugal. Sediment cores and near bottom water were collected simultaneously before dredging (control samples) and within short time intervals (min-h) after dredging. After dredging operations, microphytobenthos coming from the path were accumulated in the re-worked sediment (ridge). Chlorophyll a in superficial sediment increased from 1.2 microg x g(-1) before dredging to 1.7 microg x g(-1) after dredging and these higher values remained for a few hours. However, the expected increase of chlorophyll a in near bottom water due to re-suspension was not observed. After sediment disturbance an instantaneous sorption of phosphorus onto iron oxides occurred in the upper sediment layers (from 2 to 3 micromol x g(-1) before dredging to 4-5 micromol x g(-1) after dredging). A microcosm experiment showed that after sediment disturbance HPO(4)(2-) dissolved in pore water decreased from 40 to 10 microM being simultaneously sorbed onto iron oxides formed in the top layer of sediment. The ammonium, nitrates, organic nitrogen, phosphate and silicate dissolved in pore water decreased immediately after dredging activity and simultaneously an increase in near bottom water was sporadically observed. Generally, the re-establishment of seabed was reached within a short time (min-h), at both stations (VL and AR).

  6. Contribution of topographically generated submesoscale turbulence to Southern Ocean overturning

    NASA Astrophysics Data System (ADS)

    Ruan, Xiaozhou; Thompson, Andrew F.; Flexas, Mar M.; Sprintall, Janet

    2017-11-01

    The ocean's global overturning circulation regulates the transport and storage of heat, carbon and nutrients. Upwelling across the Southern Ocean's Antarctic Circumpolar Current and into the mixed layer, coupled to water mass modification by surface buoyancy forcing, has been highlighted as a key process in the closure of the overturning circulation. Here, using twelve high-resolution hydrographic sections in southern Drake Passage, collected with autonomous ocean gliders, we show that Circumpolar Deep Water originating from the North Atlantic, known as Lower Circumpolar Deep Water, intersects sloping topography in narrow and strong boundary currents. Observations of strong lateral buoyancy gradients, enhanced bottom turbulence, thick bottom mixed layers and modified water masses are consistent with growing evidence that topographically generated submesoscale flows over continental slopes enhance near-bottom mixing, and that cross-density upwelling occurs preferentially over sloping topography. Interactions between narrow frontal currents and topography occur elsewhere along the path of the Antarctic Circumpolar Current, which leads us to propose that such interactions contribute significantly to the closure of the overturning in the Southern Ocean.

  7. Patchiness of phytoplankton and primary production in Liaodong Bay, China.

    PubMed

    Pei, Shaofeng; Laws, Edward A; Zhang, Haibo; Ye, Siyuan; Yuan, Hongming; Liu, Haiyue

    2017-01-01

    A comprehensive study of water quality, phytoplankton biomass, and photosynthetic rates in Liaodong Bay, China, during June and July of 2013 revealed two large patches of high biomass and production with dimensions on the order of 10 km. Nutrient concentrations were above growth-rate-saturating concentrations throughout the bay, with the possible exception of phosphate at some stations. The presence of the patches therefore appeared to reflect the distribution of water temperature and variation of light penetration restricted by water turbidity. There was no patch of high phytoplankton biomass or production in a third, linear patch of water with characteristics suitable for rapid phytoplankton growth; the absence of a bloom in that patch likely reflected the fact that the width of the patch was less than the critical size required to overcome losses of phytoplankton to turbulent diffusion. The bottom waters of virtually all of the eastern half of the bay were below the depth of the mixed layer, and the lowest bottom water oxygen concentrations, 3-5 mg L-1, were found in that part of the bay. The water column in much of the remainder of the bay was within the mixed layer, and oxygen concentrations in both surface and bottom waters exceeded 5 mg L-1.

  8. Patchiness of phytoplankton and primary production in Liaodong Bay, China

    PubMed Central

    Laws, Edward A.; Zhang, Haibo; Ye, Siyuan; Yuan, Hongming; Liu, Haiyue

    2017-01-01

    A comprehensive study of water quality, phytoplankton biomass, and photosynthetic rates in Liaodong Bay, China, during June and July of 2013 revealed two large patches of high biomass and production with dimensions on the order of 10 km. Nutrient concentrations were above growth-rate-saturating concentrations throughout the bay, with the possible exception of phosphate at some stations. The presence of the patches therefore appeared to reflect the distribution of water temperature and variation of light penetration restricted by water turbidity. There was no patch of high phytoplankton biomass or production in a third, linear patch of water with characteristics suitable for rapid phytoplankton growth; the absence of a bloom in that patch likely reflected the fact that the width of the patch was less than the critical size required to overcome losses of phytoplankton to turbulent diffusion. The bottom waters of virtually all of the eastern half of the bay were below the depth of the mixed layer, and the lowest bottom water oxygen concentrations, 3–5 mg L–1, were found in that part of the bay. The water column in much of the remainder of the bay was within the mixed layer, and oxygen concentrations in both surface and bottom waters exceeded 5 mg L–1. PMID:28235070

  9. Role of the bottom sediments immediately beneath the lake water-groundwater interface in the transport and removal of cyanobacteria, cyanophage, and dissolved organic carbon during natural lake-bank filtration at a kettle pond subject to harmful algal blooms

    NASA Astrophysics Data System (ADS)

    Harvey, R. W.; Metge, D. W.; LeBlanc, D. R.; Underwood, J. C.; Aiken, G.; McCobb, T. D.; Jasperse, J.

    2015-12-01

    Bank filtration has proven to be a sustainable, cost-effective method of removing cyanobacteria and their harmful toxins from surface water during filtration through bottom and aquifer sediments. The biologically active layer of sediments immediately beneath the sediment-water interface (colmation layer) is believed to be particularly important in this process. An in situ experiment was conducted that involved assessing the transport behaviors of bromide (conservative tracer), Synechococcus sp. IU625 (cyanobacterium, 2.6 ± 0.2 µm), AS-1 (tailed cyanophages, 110 nm long), MS2 (coliphages, 26 nm diameter), and carboxylate-modified microspheres (1.7 µm diameter) introduced to the colmation layer using a bag-and-barrel (Lee-type) seepage meter. The constituents were monitored as they advected through the colmation layer and underlying aquifer sediments at Ashumet Pond in Cape Cod, MA, a mesotrophic kettle pond that recharges a portion of a sole-source, drinking water aquifer. Because the pond DOC includes the various cyanotoxins produced during harmful algal bloom senescence, the DOC and aforementioned colloids were tracked concomitantly. The tracer test constituents were monitored as they advected across the pond water-groundwater interface and through the underlying aquifer sediments under natural-gradient conditions past push-points samplers placed at ~30-cm intervals along a 1.2-m-long, diagonally downward flow path. More than 99% of the microspheres, IU625, MS2, AS-1, and ~42% of the pond DOC were removed in the colmation layer (upper 25 cm of poorly sorted bottom sediments) at two test locations characterized by dissimilar seepage rates (1.7 vs. 0.26 m d-1). Retention profiles in recovered core material indicated that >82% of the attached IU625 were in the top 3 cm of bottom sediments. The colmation layer was also responsible for rapid changes in the character of the DOC and was more effective (by 3 orders of magnitude) at removing microspheres than was the underlying 30-cm-long segment of sediment. A follow-up study conducted the following year at the same location demonstrated that removal of the top 5 cm of sediment resulted in a six-fold decrease in the efficiency of the near-surface bottom sediments for filtering out Synechococcus, cyanophage, and well-characterized microspheres.

  10. Diurnal dynamics of the CO2 concentration in water of the coastal zone of lake Baikal in the ice period (testing of the DIEL - CO2 method for assessment of lake metabolic rate)

    NASA Astrophysics Data System (ADS)

    Panchenko, M. V.; Domysheva, V. M.; Pestunov, D. A.; Sakirko, M. V.; Ivanov, V. G.; Shamrin, A. M.

    2017-11-01

    Results of three long cycles of 24-hour measurements of the carbon dioxide content in the surface and bottom water in the ice period of 2014-2016 in the Baikal coastal zone are analyzed. The diurnal dynamics of the CO2 concentration in the subglacial water, in which photosynthesis plays the leading role, is described. It is found that, in comparison with the surface subglacial water (that is, directly adjacent to the ice bottom), the more pronounced diurnal rhythm of CO2 is observed in the bottom layer in all realizations. This rhythm is well correlated with pyranometer readings. The data on the diurnal dynamics of CO2 are used to estimate the gross primary production in the bottom water with the DIEL method based on the analysis of temporal variability of the carbon dioxide concentration in water in situ.

  11. Microbial processes in the Kanda Bay, a meromictic water body artifically separated from the White Sea.

    PubMed

    Savvichev, A S; Demidenko, N A; Krasnova, E D; Kalmatskaya, O V; Kharcheva, A N; Ivanov, M V

    2017-05-01

    Sings of meromixis are found by means of microbiological and biogeochemical investigations in the southernn part of the Kanda Bay, an artificial water body separated front the White Sea with a railway dam. The concentration of oxygen in the bottom layer attained 1.9 mmol/L, intensity of the process of microbial sulfate reduction, 3.0 μmol of sulfur/(L day). The concentration of dissolved methane, 3.7 μmol/L. Isotopic composition of carbon in methane (δ 13 C (CH 4 ) =-79.2‰) indicates to its microbial genesis. At present, Kanda Bay is a sole in Russia man-made marine water body for which there are data on the rate of microbial processes responsible for formation of bottom water layer containing hydrogen sulfide and methane.

  12. Acoustic measurements of the spatial and temporal structure of the near-bottom boundary layer in the 1990-1991 STRESS experiment

    NASA Astrophysics Data System (ADS)

    Lynch, James F.; Irish, James D.; Gross, Thomas F.; Wiberg, Patricia L.; Newhall, Arthur E.; Traykovski, Peter A.; Warren, Joseph D.

    1997-08-01

    As part of the 1990-1991 Sediment TRansport Events on Shelves and Slopes (STRESS) experiment, a 5 MHz Acoustic BackScatter System (ABSS) was deployed in 90 m of water to measure vertical profiles of near-bottom suspended sediment concentration. By looking at the vertical profile of concentration from 0 to 50 cm above bottom (cmab) with 1 cm vertical resolution, the ABSS was able to examine the detailed structure of the bottom boundary layer created by combined wave and current stresses. The acoustic profiles clearly showed the wave-current boundary layer, which extends to (order) 10 cmab. The profiles also showed evidence of an "intermediate" boundary layer, also influenced by combined wave and current stresses, just above the wave-current boundary layer. This paper examines the boundary-layer structure by comparing acoustic data obtained by the authors to a 1-D eddy viscosity model formulation. Specifically, these data are compared to a simple extension of the Grant-Glenn-Madsen model formulation. Also of interest is the appearance of apparently 3-D "advective plume" structures in these data. This is an interesting feature in a site which was initially chosen to be a good example of (temporally averaged) 1-D bottom boundary-layer dynamics. Computer modeling and sector-scanning sonar images are presented to justify the plausibility of observing 3-D structure at the STRESS site. 1997 Elsevier Science Ltd

  13. Under-ice melt ponds in the Arctic

    NASA Astrophysics Data System (ADS)

    Smith, Naomi; Flocco, Daniela; Feltham, Daniel

    2017-04-01

    In the summer months, melt water from the surface of the Arctic sea ice can percolate down through the ice and flow out of its base. This water is relatively warm and fresh compared to the ocean water beneath it, and so it floats between the ice and the oceanic mixed layer, forming pools of melt water called under-ice melt ponds. Double diffusion can lead to the formation of a sheet of ice, which is called a false bottom, at the interface between the fresh water and the ocean. These false bottoms isolate under-ice melt ponds from the ocean below, trapping the fresh water against the sea ice. These ponds and false bottoms have been estimated to cover between 5 and 40% of the base of the sea ice. [Notz et al. Journal of Geophysical Research 2003] We have developed a one-dimensional thermodynamic model of sea ice underlain by an under-ice melt pond and false bottom. Not only has this allowed us to simulate the evolution of under-ice melt ponds over time, identifying an alternative outcome than previously observed in the field, but sensitivity studies have helped us to estimate the impact that these pools of fresh water have on the mass-balance sea ice. We have also found evidence of a possible positive feedback cycle whereby increasingly less ice growth is seen due to the presence of under-ice melt ponds as the Arctic warms. Since the rate of basal ablation is affected by these phenomena, their presence alters the salt and freshwater fluxes from the sea ice into the ocean. We have coupled our under-ice melt pond model to a simple model of the oceanic mixed layer to determine how this affects mixed layer properties such as temperature, salinity, and depth. In turn, this changes the oceanic forcing reaching the sea ice.

  14. Resource-limited heterotrophic prokaryote production and its potential environmental impact associated with Mn nodule exploitation in the northeast equatorial pacific.

    PubMed

    Hyun, Jung-Ho

    2006-08-01

    Shipboard enrichment incubation experiments were performed to elucidate the limiting resources for heterotrophic prokaryotic production and to discuss the potential impact of bottom water and sediment discharges in relation to manganese (Mn) nodule exploitation on the heterotrophic prokaryotes in the oligotrophic northeast equatorial Pacific. Compared to an unamended control, the production of heterotrophic prokaryotes increased 25-fold in water samples supplemented with amino acids (i.e., organic carbon plus nitrogen), whereas the production increased five and two times, respectively, in samples supplemented with either glucose or ammonium alone. These results indicate that heterotrophic prokaryote production in the northeast equatorial Pacific was co-limited by the availability of dissolved organic carbon and inorganic nitrogen. In samples from the nutrient-depleted surface mixed layer (10-m depth), the addition of a slurry of bottom water and sediment doubled heterotrophic prokaryote production compared to an unamended control, whereas sonicating the slurry prior to addition quadrupled the production rate. However, little difference was observed between an unamended control and slurry-amended samples in the subsurface chlorophyll a (Chl a) maximum (SCM) layer. Thus, the impact of slurry discharge is more significant at the nutrient-depleted surface mixed layer than at the high-nutrient SCM layer. The greatly enhanced prokaryote production resulting from the addition of sonicated slurry further suggests that dissociated organic carbon may directly stimulate heterotrophic prokaryote production in the surface mixed layer. Overall, the results suggest that the surface discharge of bottom water and sediments during manganese nodule exploitation could have a significant environmental impact on the production of heterotrophic prokaryotes that are currently resource limited.

  15. Measurements in the bottom boundary layer on the Amazon subaqueous delta

    USGS Publications Warehouse

    Cacchione, D.A.; Drake, D.E.; Kayen, R.W.; Sternberg, R.W.; Kineke, G.C.; Tate, G.B.

    1995-01-01

    An instrumented bottom tripod (GEOPROBE) recorded flow and suspended sediment data in the bottom boundary layer above the lower foresets of the Amazon subaqueous delta in 65 m mean water depth in February, 1990. After about two weeks of operation the apparent seafloor at the tripod site rapidly elevated over a 14-hour period by about 44 cm. This sudden change, which was detected by an acoustic altimeter and which caused the loss of signals from the lowermost GEOPROBE current and optical sensors, is though to have been caused by the incursion of a dense bottom layer of fluid mud that migrated downslope from shallower sections of the foresets. The fluid-mud migration across the outer part of the foresets, if a repetitive and occasional process in this region, could be a major mechanism for episodic seaward growth of the delta. Current velocity profiles are used to estimate shear velocities, u*, and roughness lengths, zo, during the first two weeks of measurements. -from Authors

  16. Suspended Alexandrium spp. hypnozygote cysts in the Gulf of Maine

    NASA Astrophysics Data System (ADS)

    Kirn, Sarah L.; Townsend, David W.; Pettigrew, Neal R.

    2005-09-01

    The life cycle of dinoflagellates of the genus Alexandrium includes sexual reproduction followed by the formation of a dormant hypnozygote cyst, which serves as a resting stage. Negatively buoyant cysts purportedly fall to the benthos where they undergo a mandatory period of quiescence. Previous reports of cysts in the surficial sediments of the Gulf of Maine, where Alexandrium blooms are well documented, show a broad distribution of cysts, with highest concentrations generally in sediments below 100 m depth. We report here an exploration of cysts suspended in the water column, where they would be better positioned to inoculate springtime Alexandrium populations. During cruises in February, April, and June of 2000, water samples were collected at depths just off the bottom (within 5 m), at the top of the bottom nepheloid layer, and near the surface (1 m) and examined for cyst concentrations. Suspended cysts were found throughout the Gulf of Maine and westernmost Bay of Fundy. Planktonic cyst densities were generally greater in near-bottom and top of the bottom nepheloid layer samples than in near-surface water samples; densities were of the order of 10 2 cysts m -3 in surface waters, and 10 2-10 3 cysts m -3 at near-bottom depths. Temporally, they were most abundant in February and least abundant in April. Reports by earlier workers of cysts in the underlying sediments were on the order of 10 3 cysts cm -3. We present calculations that demonstrate the likelihood of cyst resuspension from bottom sediments forced by swell and tidal currents, and propose that such resuspended cysts are important in inoculating the seasonal bloom. We estimate that suspended cysts may contribute significantly to the annual vegetative cell population in the Gulf of Maine.

  17. Deriving depths of deep chlorophyll maximum and water inherent optical properties: A regional model

    NASA Astrophysics Data System (ADS)

    Xiu, Peng; Liu, Yuguang; Li, Gang; Xu, Qing; Zong, Haibo; Rong, Zengrui; Yin, Xiaobin; Chai, Fei

    2009-10-01

    The Bohai Sea is a semi-enclosed inland sea with case-2 waters near the coast. A comprehensive set of optical data was collected during three cruises in June, August, and September 2005 in the Bohai Sea. The vertical profile measurements, such as chlorophyll concentration, water turbidity, downwelling irradiance, and diffuse attenuation coefficient, showed that the Bohai Sea was vertically stratified with a relative clear upper layer superimposed on a turbid lower layer. The upper layer was found to correspond to the euphotic zone and the deep chlorophyll maximum (DCM) occurs at the base of this layer. By tuning a semi-analytical model (Lee et al., 1998, 1999) for the Bohai Sea, we developed a method to derive water inherent optical properties and the depth of DCM from above-surface measurements. Assuming a 'fake' bottom in the stratified water, this new method retrieves the 'fake' bottom depth, which is highly correlated with the DCM depth. The average relative error between derived and measured values is 33.9% for phytoplankton absorption at 440 nm, 25.6% for colored detrital matter (detritus plus gelbstoff) absorption at 440 nm, and 24.2% for the DCM depth. This modified method can retrieve water inherent optical properties and monitor the depth of DCM in the Bohai Sea, and the method is also applicable to other stratified waters.

  18. Low-Frequency Variability of the Yellow Sea Cold Water Mass Identified from the China Coastal Waters and Adjacent Seas Reanalysis

    DTIC Science & Technology

    2015-01-01

    the bottom of the central trough has a shape that resembles a saddle. In July, the cold water that has a temperature lower than 10∘C covers a third of...the YSCWM The YSCWM is a large water mass covering a third of the bottom layer at its largest extension. It has relatively stable properties with low...in the wind stress and heat fluxes. In summer, ENSO has the strongest influence on the YSCWM variability. ENSO may exert influence on the third mode

  19. A model experiment of liquefaction and fluid transport: quantifying the effect of permeability discontinuity

    NASA Astrophysics Data System (ADS)

    Yasuda, N.; Sumita, I.

    2013-12-01

    Model experiments of liquefaction of a water-saturated sand (quick sand) is commonly conducted in class and in public. Various phenomena caused by liquefaction are reproduced within a closed bottle containing push-pins (Nohguchi, 2004). Experiments for tilted and layered case have also been conducted (Peacock, 2006). However quantitative measurements of liquid transport in these experiments have rarely been made. Here we show that such measurements are possible by analyzing the video images taken during such experiments. In addition, we show that a simple physical model is capable of explaining the time scales needed to expel the interstitial liquid. An experimental cell (cross section 22.0 mm x 99.4 mm, height 107.6 mm) is filled with a granular matter and water. The lower 33.0 mm consists of a two-layered granular medium, the upper layer consists of fine particles and the lower layer consists of coarse particles, with particle sizes of 0.05 mm and 0.2 mm, respectively. Since permeability depends on the square of the particle size, the upper layer becomes a low-permeability layer. We liquefy the cell by an impulsive vibration and study how the liquid migrates afterwards. We also vary the particle size combinations (upper layer: 0.05-0.15 mm, lower layer: 0.15-0.6 mm) and the thickness ratio of the 2 layers, and study how the time scale of the liquid migration depends on these changeable parameters. In a two-layered medium, we find that the pore water which originated from the bottom layer temporary accumulates at the interface of the two layers, and then ascends through the upper layer in the form of horizontal sheet or vertical channels. We find that these two different discharge styles are controlled by the permeability ratio of the two layers. We study the temporal change of the thicknesses of the two layers and find that there are three stages; 1: the slope of the upper surface is leveled by the impulse, 2: the pore water is discharged from the bottom layer and accumulates at the interface, after which it migrates upwards, 3: water discharge ends, and particles settle. We measured the relaxation time needed for the discharge and compaction to end. Because low-permeability layer inhibits pore water from rising, longer time is needed for a two-layer case compared to the one-layer case. When the particle size of the upper layer is about 1/3 or smaller than that of the lower layer, relaxation time becomes independent of the bottom particle size. We modeled the relaxation time by introducing the effective permeability of two-layered medium, and find that it explains the measurements well. References Nohguchi, Y., 2004, ICTAM04 Proceedings, Warsaw, Poland. Peacock, D. C. P., 2006, J. Geosci.Ed, 54, 550

  20. Nanofiber based triple layer hydro-philic/-phobic membrane - a solution for pore wetting in membrane distillation

    PubMed Central

    Prince, J. A.; Rana, D.; Matsuura, T.; Ayyanar, N.; Shanmugasundaram, T. S.; Singh, G.

    2014-01-01

    The innovative design and synthesis of nanofiber based hydro-philic/phobic membranes with a thin hydro-phobic nanofiber layer on the top and a thin hydrophilic nanofiber layer on the bottom of the conventional casted micro-porous layer which opens up a solution for membrane pore wetting and improves the pure water flux in membrane distillation. PMID:25377488

  1. Experimental observation of standing interfacial waves induced by surface waves in muddy water

    NASA Astrophysics Data System (ADS)

    Maxeiner, Eric; Dalrymple, Robert A.

    2011-09-01

    A striking feature has been observed in a laboratory wave tank with a thin layer of clear water overlying a layer of mud. A piston-type wave maker is used to generate long monochromatic surface waves in a tank with a layer of kaolinite clay at the bottom. The wave action on the mud causes the clay particles to rise from the bottom into the water column, forming a lutocline. As the lutocline approaches the water surface, a set of standing interfacial waves form on the lutocline. The interfacial wave directions are oriented nearly orthogonal to the surface wave direction. The interfacial waves, which sometimes cover the entire length and width of the tank, are also temporally subharmonic as the phase of the interfacial wave alternates with each passing surface wave crest. These interfacial waves are the result of a resonant three-wave interaction involving the surface wave train and the two interfacial wave trains. The interfacial waves are only present when the lutocline is about 3 cm of the water surface and they can be sufficiently nonlinear as to exhibit superharmonics and a breaking-type of instability.

  2. Ocean-Science Mission Needs: Real-Time AUV Data for Command, Control, and Model Inputs

    NASA Technical Reports Server (NTRS)

    Carder, Kendall L.; Costello, D. K.; Warrior, H.; Langebrake, L. C.; Hou, W.; Patten, J. T.; Kaltenbacher, E.

    2001-01-01

    Predictive models for tides, hydrodynamics, and bio-optical properties affecting the visibility and buoyancy of coastal waters are needed to evaluate the safety of personnel and equipment engaged in maritime operations under potentially hazardous conditions. Predicted currents can be markedly different for two-layer systems affected by terrestrial runoff than for well-mixed conditions because the layering decouples the surface and bottom Ekman layers and rectifies the current response to oscillatory upwelling-and downwelling-favorable winds. Standard ocean models (e.g. Princeton Ocean Model) require initial-and boundary data on the physical and optical properties of the multilayered water column to provide accurate simulations of heat budgets and circulation. Two observational systems are designed to measure vertically structured conditions on the West Florida Shelf (WFS): a tethered buoy network and an autonomous underwater vehicle (AUV) observational system. The AUV system is described with a focus on the observational systems that challenge or limit the communications command and control network for various types of measurement programs. These include vertical oscillatory missions on shelf transects to observe the optical and hydrographic properties of the water column, and bottom-following missions for measuring the bottom albedo. Models of light propagation, absorption, and conversion to heat as well as determination of the buoyancy terms for physical models require these measurements. High data rates associated with video bottom imagery are the most challenging for the real-time, command and control communications system, but they are met through a combination of loss-less and lossy data-compression methods, depending upon the data-rate of the radio links.

  3. Theory of lidar method for measurement of the modulation transfer function of water layers.

    PubMed

    Dolin, Lev S

    2013-01-10

    We develop a method to evaluate the modulation transfer function (MTF) of a water layer from the characteristics of lidar signal backscattered by water volume. We propose several designs of a lidar system for remote measurement of the MTF and the procedure to determine optical properties of water using the measured MTF. We discuss a laser system for sea-bottom imaging that accounts for the influence of water slab on the image structure and allows for correction of image distortions caused by light scattering in water. © 2013 Optical Society of America

  4. Particle Mass in Deep-Water Benthic Nepheloid Layers: a Global Synthesis

    NASA Astrophysics Data System (ADS)

    Mishonov, A. V.; Gardner, W. D.; Richardson, M. J.

    2016-12-01

    The mass of particles in benthic nepheloid layers in the deep ocean is mapped using profiles of beam attenuation coefficient obtained with transmissometers interfaced with CTDs during WOCE, SAVE, JGOFS, CLIVAR-Repeat Hydrography, and other programs during the last four decades using data from over 8000 profiles from >70 cruises. We map the maximum concentration of particle mass near the seafloor and integrate the particle mass throughout the benthic nepheloid layer. In the Atlantic Ocean particle mass is greater in areas where eddy kinetic energy is high in overlying waters. Areas of high bottom particle concentrations and integrated benthic nepheloid layer particle loads include the western North Atlantic beneath the Gulf Stream meanders and eddies, Argentine Basin, parts of the Southern Ocean and areas around South Africa. Particle concentrations are low in most of the Pacific and tropical and subtropical Atlantic away from margins. This synthesis is useful for GEOTRACES and other global programs where knowing particle distribution is critical for understanding trace metal absorption, sediment-water exchange and near-bottom processes. Additionally, our synthesis provides baseline data to identify where mining of metal-rich nodules and metal sulfides on the seafloor may impact the benthic environment.

  5. Anti-Fouling Double-Skinned Forward Osmosis Membrane with Zwitterionic Brush for Oily Wastewater Treatment.

    PubMed

    Ong, Chi Siang; Al-Anzi, Bader; Lau, Woei Jye; Goh, Pei Sean; Lai, Gwo Sung; Ismail, Ahmad Fauzi; Ong, Yue Seong

    2017-07-31

    Despite its attractive features for energy saving separation, the performance of forward osmosis (FO) has been restricted by internal concentration polarization and fast fouling propensity that occur in the membrane sublayer. These problems have significantly affected the membrane performance when treating highly contaminated oily wastewater. In this study, a novel double-skinned FO membrane with excellent anti-fouling properties has been developed for emulsified oil-water treatment. The double-skinned FO membrane comprises a fully porous sublayer sandwiched between a highly dense polyamide (PA) layer for salt rejection and a fairly loose dense bottom zwitterionic layer for emulsified oil particle removal. The top dense PA layer was synthesized via interfacial polymerization meanwhile the bottom layer was made up of a zwitterionic polyelectrolyte brush - (poly(3-(N-2-methacryloxyethyl-N,N-dimethyl) ammonatopropanesultone), abbreviated as PMAPS layer. The resultant double-skinned membrane exhibited a high water flux of 13.7 ± 0.3 L/m 2 .h and reverse salt transport of 1.6 ± 0.2 g/m 2 .h under FO mode using 2 M NaCl as the draw solution and emulsified oily solution as the feed. The double-skinned membrane outperforms the single-skinned membrane with much lower fouling propensity for emulsified oil-water separation.

  6. A Novel, Diazonium-Phenolic Resin Two-Layer Resist System Utilizing Photoinduced Interfacial Insolubilization

    NASA Astrophysics Data System (ADS)

    Uchino, Shou-ichi; Iwayanagi, Takao; Ueno, Takumi; Hashimoto, Michiaki; Nonogaki, Saburo

    1987-08-01

    This paper deals with a negative two-layer photoresist system utilizing a photoinduced insolubilization process at the interface. The bottom layer is a phenolic resin either with or without aromatic azide and the top layer is a photosensitive layer comprised of an aromatic diazonium compound and a water soluble polymer. Upon exposure to light, the diazo compound decomposes to cause insolubilization at the interface between the two layers. The system exhibits high contrast due to the combination of interfacial insolubilization and contrast enhancement by photobleaching of the diazonium compound. Patterns of 0.5 um lines and spaces are obtained using an i-line stepper and a resist system containing 4-diazo-N,N-dimethylaniline chloride zinc chloride in the top layer and 3-(4-azidostyry1)- 5,5-dimethyl- 2-cyclohexen-1-one in the bottom layer. Resists with varying spectral responses from mid-UV to g-line can be designed by selecting the kind of diazo compound used in the top layer.

  7. Temperature inverted haloclines provide winter warm-water refugia for manatees in southwest Florida

    USGS Publications Warehouse

    Stith, Bradley M.; Reid, James P.; Langtimm, Catherine A.; Swain, Eric D.; Doyle, Terry J.; Slone, Daniel H.; Decker, Jeremy D.; Soderqvist, Lars E.

    2010-01-01

    Florida manatees (Trichechus manatus latirostris) overwintering in the Ten Thousand Islands and western Everglades have no access to power plants or major artesian springs that provide warm-water refugia in other parts of Florida. Instead, hundreds of manatees aggregate at artificial canals, basins, and natural deep water sites that act as passive thermal refugia (PTR). Monitoring at two canal sites revealed temperature inverted haloclines, which provided warm salty bottom layers that generally remained above temperatures considered adverse for manatees. At the largest PTR, the warmer bottom layer disappeared unless significant salt stratification was maintained by upstream freshwater inflow over a persistent tidal wedge. A detailed three-dimensional hydrology model showed that salinity stratification inhibited vertical convection induced by atmospheric cooling. Management or creation of temperature inverted haloclines may be a feasible and desirable option for resource managers to provide passive thermal refugia for manatees and other temperature sensitive aquatic species.

  8. Layered Plant-Growth Media for Optimizing Gaseous, Liquid and Nutrient Requirements: Modeling, Design and Monitoring

    NASA Astrophysics Data System (ADS)

    Heinse, R.; Jones, S. B.; Bingham, G.; Bugbee, B.

    2006-12-01

    Rigorous management of restricted root zones utilizing coarse-textured porous media greatly benefits from optimizing the gas-water balance within plant-growth media. Geophysical techniques can help to quantify root- zone parameters like water content, air-filled porosity, temperature and nutrient concentration to better address the root systems performance. The efficiency of plant growth amid high root densities and limited volumes is critically linked to maintaining a favorable water content/air-filled porosity balance while considering adequate fluxes to replenish water at decreasing hydraulic conductivities during uptake. Volumes adjacent to roots also need to be optimized to provide adequate nutrients throughout the plant's life cycle while avoiding excessive salt concentrations. Our objectives were to (1) design and model an optimized root zone system using optimized porous media layers, (2) verify our design by monitoring the water content distribution and tracking nutrient release and transport, and (3) mimic water and nutrient uptake using plants or wicks to draw water from the root system. We developed a unique root-zone system using layered Ottawa sands promoting vertically uniform water contents and air-filled porosities. Watering was achieved by maintaining a shallow saturated layer at the bottom of the column and allowing capillarity to draw water upward, where coarser particle sizes formed the bottom layers with finer particles sizes forming the layers above. The depth of each layer was designed to optimize water content based on measurements and modeling of the wetting water retention curves. Layer boundaries were chosen to retain saturation between 50 and 85 percent. The saturation distribution was verified by dual-probe heat-pulse water-content sensors. The nutrient experiment involved embedding slow release fertilizer in the porous media in order to detect variations in electrical resistivity versus time during the release, diffusion and uptake of nutrients. The experiment required a specific geometry for the acquisition of ERT data using the heat-pulse water-content sensor's steel needles as electrodes. ERT data were analyzed using the sensed water contents and deriving pore-water resistivities using Archie's law. This design should provide a more optimal root-zone environment by maintaining a more uniform water content and on-demand supply of water than designs with one particle size at all column heights. The monitoring capability offers an effective means to describe the relationship between root-system performance and plant growth.

  9. On Suspended matter grain size in Baltic sea

    NASA Astrophysics Data System (ADS)

    Bubnova, Ekaterina; Sivkov, Vadim; Zubarevich, Victor

    2016-04-01

    Suspended matter grain size data were gathered during the 25th research vessel "Akademik Mstislav Keldysh" cruise (1991, September-October). Initial quantitative data were obtained with a use of the Coulter counter and subsequently modified into volume concentrations (mm3/l) for size intervals. More than 80 samples from 15 stations were analyzed (depth range 0-355 m). The main goal of research was to illustrate the spatial variability of suspended matter concentration and dispersion in Baltic Sea. The mutual feature of suspended matter grain size distribution is the logical rise of particle number along with descending of particle's size. Vertical variability of grain size distribution was defined by Baltic Sea hydrological structure, including upper mixed layer - from the surface to the thermocline - with 35 m thick, cold intermediate layer - from the thermocline to the halocline- and bottom layer, which lied under the halocline. Upper layer showed a rise in total suspended matter concentration (up to 0.6 mm3/l), while cold intermediate level consisted of far more clear water (up to 0.1 mm3/l). Such a difference is caused by the thermocline boarding role. Meanwhile, deep bottom water experienced surges in suspended matter concentration owing to the nepheloid layer presence and "liquid bottom" effect. Coastal waters appeared to have the highest amount of particles (up to 5.0 mm3/l). Suspended matter grain size distribution in the upper mixed layer revealed a peak of concentration at 7 μ, which can be due to autumn plankton bloom. Another feature in suspended matter grain size distribution appeared at the deep layer below halocline, where both O2 and H2S were observed and red/ox barrier is. The simultaneous presence of Fe and Mn (in solutions below red/ox barrier) and O2 leads to precipitation of oxyhydrates Fe and Mn and grain size distribution graph peaking at 4.5 μ.

  10. Diel Vertical Dynamics of Gelatinous Zooplankton (Cnidaria, Ctenophora and Thaliacea) in a Subtropical Stratified Ecosystem (South Brazilian Bight)

    PubMed Central

    Nogueira Júnior, Miodeli; Brandini, Frederico Pereira; Codina, Juan Carlos Ugaz

    2015-01-01

    The diel vertical dynamics of gelatinous zooplankton in physically stratified conditions over the 100-m isobath (~110 km offshore) in the South Brazilian Bight (26°45’S; 47°33’W) and the relationship to hydrography and food availability were analyzed by sampling every six hours over two consecutive days. Zooplankton samples were taken in three depth strata, following the vertical structure of the water column, with cold waters between 17 and 13.1°C, influenced by the South Atlantic Central Water (SACW) in the lower layer (>70 m); warm (>20°C) Tropical Water in the upper 40 m; and an intermediate thermocline with a deep chlorophyll-a maximum layer (0.3–0.6 mg m-3). Two distinct general patterns were observed, emphasizing the role of (i) physical and (ii) biological processes: (i) a strong influence of the vertical stratification, with most zooplankton absent or little abundant in the lower layer. The influence of the cold SACW on the bottom layer apparently restricted the vertical occupation of most species, which typically inhabit epipelagic warm waters. Even among migratory species, only a few (Aglaura hemistoma, Abylopsis tetragona eudoxids, Beroe sp., Thalia democratica, Salpa fusiformis) crossed the thermocline and reached the bottom layer. (ii) A general tendency of partial migrations, with variable intensity depending on the different species and developmental stages; populations tended to be more widely distributed through the water column during daylight, and to become more aggregated in the upper layer during the night, which can be explained based on the idea of the “hunger-satiation hypothesis”, maximizing feeding and minimizing the chances of being predated. PMID:26637179

  11. Diel Vertical Dynamics of Gelatinous Zooplankton (Cnidaria, Ctenophora and Thaliacea) in a Subtropical Stratified Ecosystem (South Brazilian Bight).

    PubMed

    Nogueira Júnior, Miodeli; Brandini, Frederico Pereira; Codina, Juan Carlos Ugaz

    2015-01-01

    The diel vertical dynamics of gelatinous zooplankton in physically stratified conditions over the 100-m isobath (~110 km offshore) in the South Brazilian Bight (26°45'S; 47°33'W) and the relationship to hydrography and food availability were analyzed by sampling every six hours over two consecutive days. Zooplankton samples were taken in three depth strata, following the vertical structure of the water column, with cold waters between 17 and 13.1°C, influenced by the South Atlantic Central Water (SACW) in the lower layer (>70 m); warm (>20°C) Tropical Water in the upper 40 m; and an intermediate thermocline with a deep chlorophyll-a maximum layer (0.3-0.6 mg m-3). Two distinct general patterns were observed, emphasizing the role of (i) physical and (ii) biological processes: (i) a strong influence of the vertical stratification, with most zooplankton absent or little abundant in the lower layer. The influence of the cold SACW on the bottom layer apparently restricted the vertical occupation of most species, which typically inhabit epipelagic warm waters. Even among migratory species, only a few (Aglaura hemistoma, Abylopsis tetragona eudoxids, Beroe sp., Thalia democratica, Salpa fusiformis) crossed the thermocline and reached the bottom layer. (ii) A general tendency of partial migrations, with variable intensity depending on the different species and developmental stages; populations tended to be more widely distributed through the water column during daylight, and to become more aggregated in the upper layer during the night, which can be explained based on the idea of the "hunger-satiation hypothesis", maximizing feeding and minimizing the chances of being predated.

  12. Application of the top specified boundary layer (TSBL) approximation to initial characterization of an inland aquifer mineralization: 2. Seepage of saltwater through semi-confining layers

    USGS Publications Warehouse

    Rubin, H.; Buddemeier, R.W.

    1998-01-01

    This paper presents a generalized basic study that addresses practical needs for an understanding of the major mechanisms involved in the mineralization of groundwater in the Great Bend Prairie aquifer in south- central Kansas. This Quaternary alluvial aquifer and associated surface waters are subject to contamination by saltwater, which in some areas seeps from the deeper Permian bedrock formation into the overlying freshwater aquifer through semiconfining layers. A simplified conceptual model is adopted. It incorporates the freshwater aquifer whose bottom is comprised of a semiconfining layer through which a hydrologically minor but geochemically important saline water discharge seeps into the aquifer. A hierarchy of approximate approaches is considered to analyze the mineralization processes taking place in the aquifer. The recently developed top specified boundary layer (TSBL) approach is very convenient to use for the initial characterization of these processes, and is further adapted to characterization of head-driven seepage through semi-confining layers. TSBL calculations indicate that the seeping saline water may create two distinct new zones in the aquifer: (1) a completely saline zone (CSZ) adjacent to the semiconfining bottom of the aquifer, and (2) a transition zone (TZ) which develops between the CSZ and the freshwater zone. Some possible scenarios associated with the various mineralization patterns are analyzed and discussed.

  13. Transient experiments with thermite melts for a core catcher concept based on water addition from below

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tromm, W.; Alsmeyer, H.

    1995-09-01

    A core catcher concept is proposed to be integrated into a new pressurized water reactor. The core catcher achieves coolability by spreading and fragmentation of the ex-vessel core melt based on a process of water inlet from the bottom through the melt. By highly effective heat removal that uses evaporating water in direct contact with the fragmented melt, the corium melt would solidify in a short time period, and long-term cooling could be maintained by continuous water evaporation from the flooded porous or fragmented corium bed. The key process for obtaining coolability is the coupling of the three effects: (a)more » water ingression from below and its evaporation, (b) break up and fragmentation of the corium layer, and (c) heat transfer and solidification of the let. These mechanisms are investigated in transient medium-scale experiments with thermite melts. The experimental setup represents a section of the proposed core catcher design. A thermite melt is located on the core catcher plate with a passive water supply from the bottom. After generation of the melt, the upper sacrificial layer is eroded until water penetrates into the melt for the bottom through plugs in the supporting plate. Fragmentation and fast solidification of the melt are observed, and long-term heat removal is guaranteed by the coolant water flooding the porous melt. Water inflow is sufficient to safely remove the decay heat in a comparable corium layer. The open porosity is created by the vapor streaming through the melt during the solidification process. Fracture of the solid by thermomechanical stresses is not observed. The experiments in their current stage show the principal feasibility of the proposed cooling concept and are used to prepare large-scale experiments to be performed in the modified BETA facility with sustained heating of the melt.« less

  14. Western Ross Sea continental slope gravity currents

    NASA Astrophysics Data System (ADS)

    Gordon, Arnold L.; Orsi, Alejandro H.; Muench, Robin; Huber, Bruce A.; Zambianchi, Enrico; Visbeck, Martin

    2009-06-01

    Antarctic Bottom Water of the world ocean is derived from dense Shelf Water that is carried downslope by gravity currents at specific sites along the Antarctic margins. Data gathered by the AnSlope and CLIMA programs reveal the presence of energetic gravity currents that are formed over the western continental slope of the Ross Sea when High Salinity Shelf Water exits the shelf through Drygalski Trough. Joides Trough, immediately to the east, offers an additional escape route for less saline Shelf Water, while the Glomar Challenger Trough still farther east is a major pathway for export of the once supercooled low-salinity Ice Shelf Water that forms under the Ross Ice Shelf. The Drygalski Trough gravity currents increase in thickness from ˜100 to ˜400 m on proceeding downslope from ˜600 m (the shelf break) to 1200 m (upper slope) sea floor depth, while turning sharply to the west in response to the Coriolis force during their descent. The mean current pathway trends ˜35° downslope from isobaths. Benthic-layer current and thickness are correlated with the bottom water salinity, which exerts the primary control over the benthic-layer density. A 1-year time series of bottom-water current and hydrographic properties obtained on the slope near the 1000 m isobath indicates episodic pulses of Shelf Water export through Drygalski Trough. These cold (<-1 °C), salty (>34.75) pulses correlate with strong downslope bottom flow. Extreme examples occurred during austral summer/fall 2003, comprising concentrated High Salinity Shelf Water (-1.9 °C; 34.79) and approaching 1.5 m s -1 at descent angles as large as ˜60° relative to the isobaths. Such events were most common during November-May, consistent with a northward shift in position of the dense Shelf Water during austral summer. The coldest, saltiest bottom water was measured from mid-April to mid-May 2003. The summer/fall export of High Salinity Shelf Water observed in 2004 was less than that seen in 2003. This difference, if real, may reflect the influence of the large iceberg C-19 over Drygalski Trough until its departure in mid-May 2003, when there was a marked decrease in the coldest, saltiest gravity current adjacent to Drygalski Trough. Northward transport of cold, saline, recently ventilated Antarctic Bottom Water observed in March 2004 off Cape Adare was ˜1.7 Sv, including ˜0.4 Sv of High Salinity Shelf Water.

  15. Depth evolution of the Meirama pit lake, A Coruña, NW Spain

    NASA Astrophysics Data System (ADS)

    Delgado, Jordi; Juncosa-Rivera, Ricardo; Cereijo-Arango, José Luis; García-Morrondo, David; Muñoz-Ibáñez, Andrea; Grande-García, Elisa; Rodríguez-Cedrún, Borja

    2016-04-01

    The Meirama pit lake is a water mass in the process of controlled flooding that, by the end of December 2015, can be described as a steadily stratified meromictic system. The deepest portion of the lake (monimolimnion) is isolated regarding the annual mixing dynamics (December/January) of the upper water body (mixolimnion), for which the depth of mixing is restricted to a water column of 35-40 m thick. Due to the contrasting flooding history (access of groundwater at the beginning and mixed access of stream/groundwater (being dominant the stream water) the deepest portion of the lake is separated from the upper, non-mixed layer by a marked chemocline. Strictly speaking, the monimolimnion of a meromictic lake extends to the waters located beneath the mixed lake layer. In the case of the Meirama Lake the monimolimnion is internally stratified and made of two major water bodies. From hereafter the deep and upper monimolimnion will be identified as bottom and middle sections of the lake while the mixolimnion is referred to as the surface layer. The general characteristics and evolution of the Meirama Lake have been reported elsewhere. In this work we focus on a summary description of the chemical evolution of the monimolimnion of the lake based on data gathered between 2009 and 2015 from the still on-going monitoring survey. The chemical evolution of the monimolimnion of the lake differs significantly from that of the mixolimnion. In general, surface water is sensible to seasonal fluctuations due to weather conditions, rainfall and biogeochemical processes. The middle and bottom sections are not sensible, in general, to this effects and their evolution obeys to a number of internal processes. In the case of temperature we observe a nearly constant gradient increase (0.001 °C/day) in the middle and deep lake waters up to the beginning of 2012, where it remains constant. The rise in temperature is likely due to the heat provided by groundwater seepage whose temperature is above that of the lake water at the corresponding depth. Likewise, electrical conductance shows a similar constant-rate increasing rate (0.223 and 0.115 S/cm-day in the bottom and middle sections, respectively) whose origin we also associate with groundwater seepage. Based on a wide number of parameters (O2, Cl, SO4, NO3, NO2, NH4, Fe, Mn…) we observe that the monimolimnion of the lake, either in its bottom or middle layer is a rather dynamic (transient) geochemical system.

  16. Life cycle assessment of disposal of residues from municipal solid waste incineration: recycling of bottom ash in road construction or landfilling in Denmark evaluated in the ROAD-RES model.

    PubMed

    Birgisdóttir, H; Bhander, G; Hauschild, M Z; Christensen, T H

    2007-01-01

    Two disposal methods for MSWI bottom ash were assessed in a new life cycle assessment (LCA) model for road construction and disposal of residues. The two scenarios evaluated in the model were: (i) landfilling of bottom ash in a coastal landfill in Denmark and (ii) recycling of bottom ash as subbase layer in an asphalted secondary road. The LCA included resource and energy consumption, and emissions associated with upgrading of bottom ash, transport, landfilling processes, incorporation of bottom ash in road, substitution of natural gravel as road construction material and leaching of heavy metals and salts from bottom ash in road as well as in landfill. Environmental impacts associated with emissions to air, fresh surface water, marine surface water, groundwater and soil were aggregated into 12 environmental impact categories: Global Warming, Photochemical Ozone Formation, Nutrient Enrichment, Acidification, Stratospheric Ozone Depletion, Human Toxicity via air/water/soil, Ecotoxicity in water/soil, and a new impact category, Stored Ecotoxicity to water/soil that accounts for the presence of heavy metals and very persistent organic compounds that in the long-term might leach. Leaching of heavy metals and salts from bottom ash was estimated from a series of laboratory leaching tests. For both scenarios, Ecotoxicity(water) was, when evaluated for the first 100 yr, the most important among the twelve impact categories involved in the assessment. Human Toxicity(soil) was also important, especially for the Road scenario. When the long-term leaching of heavy metals from bottom ash was evaluated, based on the total content of heavy metals in bottom ash, all impact categories became negligible compared to the potential Stored Ecotoxicity, which was two orders of magnitudes greater than Ecotoxicity(water). Copper was the constituent that gave the strongest contributions to the ecotoxicities. The most important resources consumed were clay as liner in landfill and the groundwater resource which was potentially spoiled due to leaching of salts from bottom ash in road. The difference in environmental impacts between landfilling and utilization of bottom ash in road was marginal when these alternatives were assessed in a life cycle perspective.

  17. The impact of surface chemistry on the performance of localized solar-driven evaporation system

    PubMed Central

    Yu, Shengtao; Zhang, Yao; Duan, Haoze; Liu, Yanming; Quan, Xiaojun; Tao, Peng; Shang, Wen; Wu, Jianbo; Song, Chengyi; Deng, Tao

    2015-01-01

    This report investigates the influence of surface chemistry (or wettability) on the evaporation performance of free-standing double-layered thin film on the surface of water. Such newly developed evaporation system is composed of top plasmonic light-to-heat conversion layer and bottom porous supporting layer. Under solar light illumination, the induced plasmonic heat will be localized within the film. By modulating the wettability of such evaporation system through the control of surface chemistry, the evaporation rates are differentiated between hydrophilized and hydrophobized anodic aluminum oxide membrane-based double layered thin films. Additionally, this work demonstrated that the evaporation rate mainly depends on the wettability of bottom supporting layer rather than that of top light-to-heat conversion layer. The findings in this study not only elucidate the role of surface chemistry of each layer of such double-layered evaporation system, but also provide additional design guidelines for such localized evaporation system in applications including desalination, distillation and power generation. PMID:26337561

  18. The impact of surface chemistry on the performance of localized solar-driven evaporation system.

    PubMed

    Yu, Shengtao; Zhang, Yao; Duan, Haoze; Liu, Yanming; Quan, Xiaojun; Tao, Peng; Shang, Wen; Wu, Jianbo; Song, Chengyi; Deng, Tao

    2015-09-04

    This report investigates the influence of surface chemistry (or wettability) on the evaporation performance of free-standing double-layered thin film on the surface of water. Such newly developed evaporation system is composed of top plasmonic light-to-heat conversion layer and bottom porous supporting layer. Under solar light illumination, the induced plasmonic heat will be localized within the film. By modulating the wettability of such evaporation system through the control of surface chemistry, the evaporation rates are differentiated between hydrophilized and hydrophobized anodic aluminum oxide membrane-based double layered thin films. Additionally, this work demonstrated that the evaporation rate mainly depends on the wettability of bottom supporting layer rather than that of top light-to-heat conversion layer. The findings in this study not only elucidate the role of surface chemistry of each layer of such double-layered evaporation system, but also provide additional design guidelines for such localized evaporation system in applications including desalination, distillation and power generation.

  19. The Deep Meridional Overturning Circulation in the Indian Ocean Inferred from the GECCO Synthesis

    NASA Astrophysics Data System (ADS)

    Wang, W.; Koehl, A.; Stammer, D.

    2012-04-01

    The meridional overturning circulation in the Indian Ocean and its temporal variability in the GECCO ocean synthesis are being investigated. An analysis of the integrated circulation in different layers suggests that, on time average, 2.1 Sv enter the Indian Ocean in the bottom layer (>3200m) from the south and that 12.3 Sv leave the Indian Ocean in the upper and intermediate layers (<1500m), composed of the up-welled bottom layer inflow water, augmented by 9.6 Sv Indonesian Throughflow (ITF) water. The GECCO time-mean results differ significantly from those obtained by box inverse models, which, being based on individual hydrographic sections, are susceptible to aliasing. The GECCO solution has a large seasonal variation in its meridional overturning caused by the seasonal reversal of monsoon-related wind stress forcing. Associated seasonal variations of the deep meridional overturning range from -7 Sv in boreal winter to 3 Sv in summer. In addition, the upper and bottom transports across 34°S section show pronounced interannual variability with roughly biennial variations superimposed by strong anomalies during each La Niña phase as well as the ITF, which mainly affect the upper layer transports. On decadal and longer timescale, the meridional overturning variability as well as long-term trends differ before and after 1980. Notably, our analysis shows a rather stable trend for the period 1960-1979 and significant changes in the upper and bottom layer for the period 1980-2001. By means of a multivariate EOF analysis, the importance of Ekman dynamics as driving forces of the deep meridional overturning of the Indian Ocean on the interannual timescale is highlighted. The leading modes of the zonal and meridional wind stress favour a basin-wide meridional overturning mode via Ekman upwelling or downwelling mostly in the central and eastern Indian Ocean. Moreover, tropical zonal wind stress along the equator and alongshore wind stress off the Sumatra-Java coast contributes to evolution of IOD events.

  20. Geoacoustic inversion with two source-receiver arrays in shallow water.

    PubMed

    Sukhovich, Alexey; Roux, Philippe; Wathelet, Marc

    2010-08-01

    A geoacoustic inversion scheme based on a double beamforming algorithm in shallow water is proposed and tested. Double beamforming allows identification of multi-reverberated eigenrays propagating between two vertical transducer arrays according to their emission and reception angles and arrival times. Analysis of eigenray intensities yields the bottom reflection coefficient as a function of angle of incidence. By fitting the experimental reflection coefficient with a theoretical prediction, values of the acoustic parameters of the waveguide bottom can be extracted. The procedure was initially tested in a small-scale tank experiment for a waveguide with a Plexiglas bottom. Inversion results for the speed of shear waves in Plexiglas are in good agreement with the table values. A similar analysis was applied to data collected during an at-sea experiment in shallow coastal waters of the Mediterranean. Bottom reflection coefficient was fitted with the theory in which bottom sediments are modeled as a multi-layered system. Retrieved bottom parameters are in quantitative agreement with those determined from a prior inversion scheme performed in the same area. The present study confirms the interest in processing source-receiver array data through the double beamforming algorithm, and indicates the potential for application of eigenray intensity analysis to geoacoustic inversion problems.

  1. [Characterization of Chromophoric dissolved organic matter (CDOM) in Zhoushan fishery using excitation-emission matrix spectroscopy (EEMs) and parallel factor analysis (PARAFAC)].

    PubMed

    Zhou, Qian-qian; Su, Rong-guo; Bai, Ying; Zhang, Chuan-song; Shi, Xiao-yong

    2015-01-01

    The composition, distribution characteristics and sources of chromophoric dissolved organic matter(CDOM) in Zhoushan Fishery in spring were evaluated by fluorescence excitation-emission matrix (EEM) combined with parallel factor analysis (EEMs-PARAFAC). Three humic-like components [C1 (330/420 nm)], C2 [(290) 365/440 nm] and C3 [(260) 370/490 nm)] and two protein-like components [C4(285/340 nm) and C5 (270/310 nm)] were identified by EEMs-PARAFAC. The horizontal distribution patterns of the five components were almost the same with only slight differences, showing decreasing trends with increasing distance from shore. In the surface and middle layers, the high value areas were located in the north of Hangzhou Bay estuary and the outlet of Xiazhimen channel, and the former's was higher in the surface layer while the latter's was higher in the middle layer. In the bottom layer, CDOM decreased gradiently from the inshore to offshore, with higher CDOM near Zhoushan Island. The distributions of fluorescence components showed an opposite trend with salinity, and no significant linear relationship with Chl-a concentration was found, which indicated that CDOM in the surface and middle layers were dominated by terrestrial input and human activities of Zhoushan Island and that of the bottom layer was attribute to human activities of Zhoushan Island. The vertical distribution of five fluorescent components along 30.5 degrees N transect showed a decreasing trend from the surface and middle layers to bottom layer with high values in inshore and offshore areas, which were correlated with the lower salinity and higher Chl-a concentration, respectively. On this transect, CDOM was mainly affected by Yangtze River input in coastal area but by bioactivities in offshore waters. Along the 30 degrees N transect, the vertical distribution patterns of CDOM were similar to those of 30.5 degrees N transect but there was a high value area in the bottom layer near the shore, attributing to the CDOM release from the marine sediment pore water to the water body because of physical force role like tidal, the underlying upwelling and so on. A strong correlation occurred between C1 and C3, C4, indicating that they had similar sources; a weak correlation was found between C1 and C2, C5, reflecting some differences among their sources. CDOM in Zhoushan Fishery in spring had low humification index (HIX) values, which reflected a low degree of humification, poor stability and a short resident time in the environment. For biological index (BIX), its higher values appeared in the offshore waters and the lower values occurred in the inshore area, reflecting a greater influence of human and biological activities, respectively.

  2. TUBEWALL: a passive solar thermo-siphoning, field-fabricated, water storage wall system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Moore, F.; Hemker, P.

    1980-01-01

    The basic component of TUBEWALL is a water-filled thin-wall cylindrical tube with an insulating foam vertical partition insert that divides the inside of the tube into a thin collector water compartment (solar side) and a larger storage water compartment (room side). The two compartments are connected at the top and bottom by means of circulation holes in the foam partition. When the sun strikes the solar side of the tube, the thin layer of collector water is heated, thermosiphons through the top opening in the partition into the larger storage compartment on the room side, and is replaced with coolmore » water drawn from the bottom of the storage through the bottom hole in the partition. Night back-siphonage is prevented by a thin flap valve over the top circulation hole. The tubes may by used between wall studs having a low-cost fiberglass/tedlar double glazing. The tubes can be covered on the room side with drywall and heat transferred to the living space by indirect radiation, and either natural air convection through top and bottom vent slots or by fan. Alternatively, the tubes can be left exposed for direct radiation.« less

  3. Experimental and Numerical Investigation of Internal Gravity Waves Excited by Turbulent Penetrative Convection in Water Around Its Density Maximum

    NASA Astrophysics Data System (ADS)

    Perrard, Stéphane; Le Bars, Michaël; Le Gal, Patrice

    This study is devoted to the experimental and numerical analysis of the excitation of gravity waves by turbulent convection. This situation is representative of many geophysical or astrophysical systems such as the convective bottom layer of the atmosphere that radiates internal waves in the stratosphere, or the interaction between the convective and the radiative zones in stars. In our experiments, we use water as a working fluid as it possesses the remarkable property of having a maximum density at 4 °C. Therefore, when establishing on a water layer a temperature gradient between 0 °C at the bottom and room temperature at the top, a turbulent convective region appears spontaneously under a stably stratified zone. In these conditions, gravity waves are excited by the convective fluid motions penetrating the stratified layer. Although this type of flow, called penetrative convection, has already been described, we present here the first velocity field measurement of wave emission and propagation. We show in particular that an intermediate layer that we call the buffer layer emerges between the convective and the stratified zones. In this buffer layer, the angle of propagation of the waves varies with the altitude since it is slaved to the Brunt-Väisälä frequency which evolves rapidly between the convective and the stratified layer. A minimum angle is reached at the end of the buffer layer. Then we observe that an angle of propagation is selected when the waves travel through the stratified layer. We expect this process of wave selection to take place in natural situations.

  4. The fast-ice growth and freezing of the bottom in the Braganzavagen Gulf (Van Mijenfjorden, Svalbard)

    NASA Astrophysics Data System (ADS)

    Bogorodsky, Petr; Marchenko, Aleksey; Pnyushkov, Andrey; Filchuk, Kirill; Morozov, Yevgenii; Ryzhov, Ivan

    2017-04-01

    The results of oceanographic and sea ice studies in the shallow Braganzavågen Gulf (Van Mijenfjorden, Svalbard) in March 2016 are presented. These studies are a continuation of observational efforts initiated by UNIS (Svalbard, Norway) in 2014. 2016 field campaign includes instrumental measurements of snow and ice properties in the fjord (e.g., ice thicknesses, temperatures, and salinities), as well as high-resolution CTD measurements within the under-ice water column. Collected observations were accompanied by freezing simulations of adjacent water and bottom ground layers performed with a one-dimensional thermodynamic model (Bogorodskii and Pnyushkov, 2015). The model uses two methods to reproduce phase transition areas - a "classic" (frontal) method for the fast ice, and transition in the continuous media (mushy zone) for the bottom sediments. Meteorological observations during the winter 2015-16 at Sveagruva (northwest coast) were used in these simulations as the atmospheric forcing. Numerical experiments were carried out for the initial salinity of 35 psu and 2 m water depth. The simulations start with the beginning of water freezing determined by a steady air temperature transition through the freezing point. The start of freezing was also verified by comparison with sea ice charts available for the Van Mijenfjorden for the period of simulations. Model simulations showed that the growth of sea ice in shallow (<1 m) areas of the basin significantly increases water salinity in the under-ice layer. For instance, at a 0.5 m depth the salinity in the under ice water layer exceeds 160 psu, which corresponds to the freezing temperature below -9C. In fact, the water salinity does not reach high values because of the horizontal mixing. However, available hydrological observations showed relatively small (0.2-0.5 m) amplitudes of tides - the major contributor to the horizontal exchange in this area. These small amplitudes likely suggest small advective salt fluxes induced by tides, and thus their little effect on the rate of ice formation at seasonal time scales. As expected, substantial water cooling in the under-ice layer leads to freezing of the bottom ground, mostly evident in areas with small depths. For example, during the cold season this freezing may be as large as 1 m at a fjord part with typical depths of 0.5 m. In general, the model shows a relativity good agreement with direct observations of fast ice properties. However, due to uncertainty in the thermodynamic properties of the ground, the quantitative description of the heat transfer processes in this layer is still incomplete and required additional clarification in the specially targeted field experiments.

  5. Structure of the shelf and slope waters of the Antarctic Seas

    NASA Astrophysics Data System (ADS)

    Artamonova, Ksenia; Antipov, Nikolay; Gangnus, Ivan; Maslennikov, Vyacheslav

    2015-04-01

    The main objective of present work is to consider characteristics of shelf and slope waters in the Commonwealth, Ross, Amundson and Bellingshausen Seas. Data of Russian surveys led during the Antarctic summer of 2006 - 2014 on RV "Academic Fedorov"and "Academic Treshnikov"was analyzed. Distribution of temperature, salinity, dissolved oxygen, silicate, phosphates and nitrates in the water masses of the Commonwealth and Amundsen seas was shown. Significant differences in the structures of the shelf and slope waters of the seas were observed. A water structure at the oceanological sections of the Commonwealth Sea was constituted by the Antarctic Surface Water (AASW) with enough high concentration of silicate, nitrate nitrogen and phosphates compare with other areas of the World Ocean; the Upper Circumpolar Deep Water (UCDW) characterized by a minimum of the oxygen content, and a maximum of nutrient concentrations; The Lower Circumpolar Deep Water (LCDW) primary characterized by a salinity maximum and a minimum of nutritive salts as well; and the Antarctic Bottom water (AABW). It was shown that the local cold, salt and dense Antarctic Shelf water (ASW) formed in the shelf area of the Commonwealth Sea. The characteristics of ASW were defined. The ASW mixed with the CDW and their mixture (The Bottom Water of the Prydz Bay (BWPB)) moved down along the slope, and reached the bottom.The characteristics of the BWPB were analyzed. The BWPB was defined by higher content of dissolved oxygen (more 5.5 ml/l) and lower contents of biogenic elements (silicon - low 120 µМ, phosphates - low 2.35 µМ and nitrates - low 29 µМ) in the bottom layer at the slope compared with the Circumpolar Deep Water (CDW) characteristics. Interannual variability of characteristics of the water masses was observed on the repeated oceanological section along 70° E in the Commonwealth Sea. It was shown that characteristics and structure of the BWPB undergo appreciable changes year by year. The coldest (-1,5°С) and less salted (34,54‰) BWPB was observed in 2005, and in 2006 the temperature and salinity of this water were increased (-0,6°С; 34,60‰ - 34,63‰), and the thickness of a layer was much less. In 2007 as capacity of the BWPB layer, and its thermohaline characteristics (-1,2°C, 34,56 ‰) have shown again active moving down near to a bottom of the Antarctic continental slope. A water structure at the oceanological sections in the eastern Ross, Amundson and Bellingshausen Seas was constituted by the two basic water masses - the AASW and the CDW. The CDW was presented by the UCDW and LCDW. The characteristics of the UCDW and the LCDW were defined. A significant difference of the structures of these seas from the Commonwealth Sea is a free entrance to the shelf area of the CDW therefore formation of the Antarctic Shelf Water here was represented impossible.

  6. Multicore runup simulation by under water avalanche using two-layer 1D shallow water equations

    NASA Astrophysics Data System (ADS)

    Bagustara, B. A. R. H.; Simanjuntak, C. A.; Gunawan, P. H.

    2018-03-01

    The increasing of layers in shallow water equations (SWE) produces more dynamic model than the one-layer SWE model. The two-layer 1D SWE model has different density for each layer. This model becomes more dynamic and natural, for instance in the ocean, the density of water will decreasing from the bottom to the surface. Here, the source-centered hydro-static reconstruction (SCHR) numerical scheme will be used to approximate the solution of two-layer 1D SWE model, since this scheme is proved to satisfy the mathematical properties for shallow water equation. Additionally in this paper, the algorithm of SCHR is adapted to the multicore architecture. The simulation of runup by under water avalanche is elaborated here. The results show that the runup is depend on the ratio of density of each layers. Moreover by using grid sizes Nx = 8000, the speedup and efficiency by 2 threads are obtained 1.74779 times and 87.3896 % respectively. Nevertheless, by 4 threads the speedup and efficiency are obtained 2.93132 times and 73.2830 % respectively by similar number of grid sizes Nx = 8000.

  7. Harvesting Water from Air: Using Anhydrous Salt with Sunlight.

    PubMed

    Li, Renyuan; Shi, Yusuf; Shi, Le; Alsaedi, Mossab; Wang, Peng

    2018-05-01

    Atmospheric water is an abundant alternative water resource, equivalent to 6 times the water in all rivers on Earth. This work screens 14 common anhydrous and hydrated salt couples in terms of their physical and chemical stability, water vapor harvesting, and release capacity under relevant application scenarios. Among the salts screened, copper chloride (CuCl 2 ), copper sulfate (CuSO 4 ), and magnesium sulfate (MgSO 4 ) distinguish themselves and are further made into bilayer water collection devices, with the top layer being the photothermal layer, while the bottom layer acts as a salt-loaded fibrous membrane. The water collection devices are capable of capturing water vapor out of the air with low relative humidity (down to 15%) and releasing water under regular and even weakened sunlight (i.e., 0.7 kW/m 2 ). The work shines light on the potential use of anhydrous salt toward producing drinking water in water scarce regions.

  8. Turbidity distribution in the Atlantic Ocean

    USGS Publications Warehouse

    Eittreim, S.; Thorndike, E.M.; Sullivan, L.

    1976-01-01

    The regional coverage of Lamont nephelometer data in the North and South Atlantic can be used to map seawater turbidity at all depths. At the level of the clearest water, in the mid-depth regions, the turbidity distribution primarily reflects the pattern of productivity in the surface waters. This suggests that the 'background' turbidity level in the oceans is largely a function of biogenic fallout. The bottom waters of the western Atlantic generally exhibit large increases in turbidity. The most intense benthic nepheloid layers are in the southwestern Argentine basin and northern North American basin; the lowest bottom water turbidity in the western Atlantic is in the equatorial regions. Both the Argentine and North American basin bottom waters appear to derive their high turbidity largely from local resuspension of terrigenous input in these basins. In contrast to the west, the eastern Atlantic basins show very low turbidities with the exception of three regions: the Mediterranean outflow area, the Cape basin, and the West European basin. ?? 1976.

  9. Warming of Water in a Glass

    ERIC Educational Resources Information Center

    Paulins, Paulis; Krauze, Armands; Ozolinsh, Maris; Muiznieks, Andris

    2016-01-01

    The article focuses on the process of water warming from 0 °C in a glass. An experiment is performed that analyzes the temperature in the top and bottom layers of water during warming. The experimental equipment is very simple and can be easily set up using devices available in schools. The temperature curves obtained from the experiment help us…

  10. Characterization and migration of oil and solids in oily sludge during centrifugation.

    PubMed

    Wang, Jun; Han, Xu; Huang, Qunxing; Ma, Zengyi; Chi, Yong; Yan, Jianhua

    2018-05-01

    The migration behaviors of oil, water and solids in sludge during centrifugation were elaborated. Size distribution, surface topography and lypohydrophilic properties were studied in detail. The average size of solids was 61 μm in original sludge, 31 μm in upper layer and 235 μm in bottom layer. The result shows that solvent is essential to separate oil phase into molecular light and weight fractions during centrifugation. With solvent/oil ratio increases from 1:2, 1:1, 2:1 to 5:1, molecular weight in upper layer decreases from 1044, 1043, 1020 to 846 combined with that in bottom layer increases. A model was proposed to calculate the oil residue content in solid phases after sedimentation. The findings of this paper provide information for optimizing the oil recovery and clean treatment.

  11. Piezoelectric Resonator with Two Layers

    NASA Technical Reports Server (NTRS)

    Stephanou, Philip J. (Inventor); Black, Justin P. (Inventor)

    2013-01-01

    A piezoelectric resonator device includes: a top electrode layer with a patterned structure, a top piezoelectric layer adjacent to the top layer, a middle metal layer adjacent to the top piezoelectric layer opposite the top layer, a bottom piezoelectric layer adjacent to the middle layer opposite the top piezoelectric layer, and a bottom electrode layer with a patterned structure and adjacent to the bottom piezoelectric layer opposite the middle layer. The top layer includes a first plurality of electrodes inter-digitated with a second plurality of electrodes. A first one of the electrodes in the top layer and a first one of the electrodes in the bottom layer are coupled to a first contact, and a second one of the electrodes in the top layer and a second one of the electrodes in the bottom layer are coupled to a second contact.

  12. Hydrography and bottom boundary layer dynamics: Influence on inner shelf sediment mobility, Long Bay, North Carolina

    USGS Publications Warehouse

    Davis, L.A.; Leonard, L.A.; Snedden, G.A.

    2008-01-01

    This study examined the hydrography and bottom boundary-layer dynamics of two typical storm events affecting coastal North Carolina (NC); a hurricane and the passages of two small consecutive extratropical storms during November 2005. Two upward-looking 1200-kHz Acoustic Doppler Current Profilers (ADCP) were deployed on the inner shelf in northern Long Bay, NC at water depths of less than 15 m. Both instruments profiled the overlying water column in 0.35 in bins beginning at a height of 1.35 in above the bottom (mab). Simultaneous measurements of wind speed and direction, wave and current parameters, and acoustic backscatter were coupled with output from a bottom boundary layer (bbl) model to describe the hydrography and boundary layer conditions during each event. The bbl model also was used to quantify sediment transport in the boundary layer during each storm. Both study sites exhibited similar temporal variations in wave and current magnitude, however, wave heights during the November event were higher than waves associated with the hurricane. Near-bottom mean and subtidal currents, however, were of greater magnitude during the hurricane. Peak depth-integrated suspended sediment transport during the November event exceeded transport associated with the hurricane by 25-70%. Substantial spatial variations in sediment transport existed throughout both events. During both events, along-shelf sediment transport exceeded across-shelf transport and was related to the magnitude and direction of subtidal currents. Given the variations in sediment type across the bay, complex shoreline configuration, and local bathymetry, the sediment transport rates reported here are very site specific. However, the general hydrography associated with the two storms is representative of conditions across northern Long Bay. Since the beaches in the study area undergo frequent renourishment to counter the effects of beach erosion, the results of this study also are relevant to coastal management decision-making. Specifically, these issues include 1) identification of municipalities that should share the cost for renourishment given the likelihood for significant along-shelf sand movement and 2) appropriate timing of sand placement with respect to local climatology and sea-turtle nesting restrictions.

  13. Effect of Mass Proportion of Municipal Solid Waste Incinerator Bottom Ash Layer to Municipal Solid Waste Layer on the Cu and Zn Discharge from Landfill.

    PubMed

    Kong, Qingna; Yao, Jun; Qiu, Zhanhong; Shen, Dongsheng

    2016-01-01

    Municipal solid waste incinerator (MSWI) bottom ash is often used as the protection layer for the geomembrane and intermediate layer in the landfill. In this study, three sets of simulated landfills with different mass proportion of MSWI bottom ash layer to municipal solid waste (MSW) layer were operated. Cu and Zn concentrations in the leachates and MSW were monitored to investigate the effect of MSWI bottom ash layer on the Cu and Zn discharge from the landfill. The results showed that the Zn discharge was dependent on the mass proportion of MSWI bottom ash layer. The pH of landfill was not notably increased when the mass proportion of MSWI bottom ash layer to MSW layer was 1 : 9, resulting in the enhancement of the Zn discharge. However, Zn discharge was mitigated when the mass proportion was 2 : 8, as the pH of landfill was notably promoted. The discharge of Cu was not dependent on the mass proportion, due to the great affinity of Cu to organic matter. Moreover, Cu and Zn contents of the sub-MSW layer increased due to the MSWI bottom ash layer. Therefore, the MSWI bottom ash layer can increase the potential environmental threat of the landfill.

  14. Linear shoaling of free-surface waves in multi-layer non-hydrostatic models

    NASA Astrophysics Data System (ADS)

    Bai, Yefei; Cheung, Kwok Fai

    2018-01-01

    The capability to describe shoaling over sloping bottom is fundamental to modeling of coastal wave transformation. The linear shoaling gradient provides a metric to measure this property in non-hydrostatic models with layer-integrated formulations. The governing equations in Boussinesq form facilitate derivation of the linear shoaling gradient, which is in the form of a [ 2 P + 2 , 2 P ] expansion of the water depth parameter kd with P equal to 1 for a one-layer model and (4 N - 4) for an N-layer model. The expansion reproduces the analytical solution from Airy wave theory at the shallow water limit and maintains a reasonable approximation up to kd = 1.2 and 2 for the one and two-layer models. Additional layers provide rapid and monotonic convergence of the shoaling gradient into deep water. Numerical experiments of wave propagation over a plane slope illustrate manifestation of the shoaling errors through the transformation processes from deep to shallow water. Even though outside the zone of active wave transformation, shoaling errors from deep to intermediate water are cumulative to produce appreciable impact to the wave amplitude in shallow water.

  15. Transport of Antarctic Bottom Water through passages in the East Azores Ridge (37° N) in the East Atlantic

    NASA Astrophysics Data System (ADS)

    Tarakanov, R. Yu.; Morozov, E. G.; Gritsenko, A. M.; Demidova, T. A.; Makarenko, N. I.

    2013-07-01

    The structure of northerly overflow of Antarctic Bottom Water (AABW) through passages in the East Azores Ridge (37° N) in the East Atlantic from the Madeira Basin to the Iberian Basin is studied on the basis of hydrographic measurements carried out by the Institute of Oceanology, Russian Academy of Sciences (RAS) in October 2011, historical World Ocean Data Base 2009, and recent data on the bottom topography. The overflow of the coldest layers of this water occurs through two passages with close depths at 16° W (Discovery Gap) and at 19°30' W (nameless Western Gap). It is shown that it is likely that the role of the latter passage in water transport was underestimated in earlier publications because the water (2.01°C) found in the region north of the Western Gap was cooler than in the region north of the Discovery Gap (2.03°C). In 2011, we found a decrease of 0.01°C in the AABW temperature near the bottom compared to previous measurements in 1982 (from 2.011°C to 2.002°C). Analysis of the historical database shows that this decrease is most likely caused by the cooling trend in the abyssal waters in the East Atlantic basins.

  16. Hysteretic growth and decay of a waterspout column

    NASA Astrophysics Data System (ADS)

    Naumov, Igor V.; Herrada, Miguel A.; Sharifullin, Bulat R.; Shtern, Vladimir N.

    2018-02-01

    This work explores a model waterspout: a flow of water and sunflower oil driven by the rotating lid in a sealed vertical cylindrical container. The experiments reveal the hysteretic growth and decay of a water column. The numerical simulations uncover vortex breakdown (VB) in the water and oil flows. As the rotation speeds up, (1) a VB water cell emerges near the bottom center, (2) it expands and occupies almost the entire water volume except a thin layer adjusted to the interface, (3) a VB oil cell emerges and disappears above the interface-axis intersection, (4) the interface rises near the axis, descends at the periphery, and shifts from the sidewall to the bottom, (5) the water touches the lid near the axis and forms a column, extending from the bottom up to the lid. As the rotation decelerates, the process reverses, but the flow states differ from those for the direct process at same rotation speeds. It is argued that the hysteresis is a capillary phenomenon and occurs because the interface-wall contact angle differs in the direct and reverse processes.

  17. Effect of the Discharge Water which Mixed Sewage Disposal Water with Seawater Desalting Treated Sewage for Bottom Sediment and Hypoxic Water Mass

    NASA Astrophysics Data System (ADS)

    Watanabe, Ryoichi; Yamasaki, Koreyoshi; Minagawa, Tomoko; Iyooka, Hiroki; Kitano, Yoshinori

    For every time in summer season, hypoxic water mass has formed at the inner part of Hakata Bay. Field observation study has carried out at the inner part of Hakata Bay since 2004 with the particular aim of tracking the movement of hypoxic water mass. Hypoxic water masses form the end of June to September on this area because the consumption of oxygen in bottom water layers exceeds the re-supply of oxygen from the atmosphere. Under such hypoxic conditions, the seawater desalination plant has begun to use in 2005. After seawater desalination plant operation starting, hypoxic water mass tends to improve. In this research, the authors show the following result. After seawater desalination plant has begun to operate, the hypoxia around the mixed discharge water outlet tends to be improved.

  18. Effect of Mass Proportion of Municipal Solid Waste Incinerator Bottom Ash Layer to Municipal Solid Waste Layer on the Cu and Zn Discharge from Landfill

    PubMed Central

    Kong, Qingna; Qiu, Zhanhong; Shen, Dongsheng

    2016-01-01

    Municipal solid waste incinerator (MSWI) bottom ash is often used as the protection layer for the geomembrane and intermediate layer in the landfill. In this study, three sets of simulated landfills with different mass proportion of MSWI bottom ash layer to municipal solid waste (MSW) layer were operated. Cu and Zn concentrations in the leachates and MSW were monitored to investigate the effect of MSWI bottom ash layer on the Cu and Zn discharge from the landfill. The results showed that the Zn discharge was dependent on the mass proportion of MSWI bottom ash layer. The pH of landfill was not notably increased when the mass proportion of MSWI bottom ash layer to MSW layer was 1 : 9, resulting in the enhancement of the Zn discharge. However, Zn discharge was mitigated when the mass proportion was 2 : 8, as the pH of landfill was notably promoted. The discharge of Cu was not dependent on the mass proportion, due to the great affinity of Cu to organic matter. Moreover, Cu and Zn contents of the sub-MSW layer increased due to the MSWI bottom ash layer. Therefore, the MSWI bottom ash layer can increase the potential environmental threat of the landfill. PMID:28044139

  19. A Multi-proxy Approach to Understanding the Diagenesis of Carbonates in Pennsylvanian Mudrocks in the Midland Basin

    NASA Astrophysics Data System (ADS)

    Reis, A.; McGlue, M. M.; Waite, L.; Erhardt, A. M.

    2017-12-01

    Diagenetic processes influenced by changing climate, eustatic fluctuations, and porewater evolution led to the formation and alteration of carbonate layers in the Pennsylvanian Wolfcamp D Formation of the Midland Basin. Preliminary evidence from bulk geochemistry, oxygen and carbon stable isotopes, and petrographic analysis of the carbonates recovered from two drill cores indicate multiple generations of diagenesis. High Mg calcite and dolomite layers predominantly occur in the fine grained intervals of both cores. Whereas there are less carbonate layers in the central basin core, more of the layers underwent diagenesis compared to the carbonates in the southern core. δ13CPDB values ranging from -6‰ to -4‰ and the presence of framboidal pyrite indicate initial dolomite precipitation occurring in the zone of bacterial sulfate reduction. Later stages alteration occurred following the burial diagenesis of clay, releasing Mg2+ and Fe2+ into the pore waters allowing ferroan dolomite rims to precipitate on the precursor iron-poor dolomite rhombs. δ13CPDB and δ18OPDBvalues from altered beds in the southern core show a positive 4-6‰ offset from the central basin beds. Petrographic analysis of the carbonate intervals shows a larger allochem size, and lower pyrite abundance in the southern core. These differences can be associated with a shorter source-to-sink distance and less frequent bottom water anoxia, leading to reduced rates of sulfate reduction. One possibility we will explore is if increased circulation due to the proximity of the southern core to the Sheffield Channel could stabilize the bottom water conditions in this region of the basin. In addition to dolomite precipitation and replacement, scanning electron microscopy reveals the replacement of silica cements by calcite, suggesting an increase in porewater pH during or following sulfate reduction coinciding with pyrite formation. Changing bottom water chemistry tied to fluctuations in sea-level through time led to porewater conditions favorable to several generations of post-depositional diagenesis.

  20. Electromagnetic Surveying in the Mangrove Lakes Region of Everglades National Park

    NASA Astrophysics Data System (ADS)

    Whitman, D.; Price, R.; Frankovich, T.; Fourqurean, J.

    2015-12-01

    The Mangrove Lakes are an interconnected set of shallow (~ 1m), brackish lake and creek systems on the southern margin of the Everglades adjacent to Florida Bay. Current efforts associated with the Comprehensive Everglades Restoration Plan (CERP) aim to increase freshwater flow into this region. This study describes preliminary results of geophysical surveys in the lakes conducted to assess changes in the groundwater chemistry as part of a larger hydrologic and geochemical study in the Everglades Lakes region. Marine geophysical profiles were conducted in Alligator Creek (West Lake) and McCormick Creek systems in May, 2014. Data included marine electromagnetic (EM) profiles and soundings, water depth measurements, surface water conductivity and salinity measurements. A GSSI Profiler EMP-400 multi-frequency EM conductivity meter continuously recorded in-phase and quadrature field components at 1, 8, and 15 KHz. The system was deployed in a flat bottomed plastic kayak towed behind a motorized skiff. Lake water depths were continuously measured with a sounder/chart plotter which was calibrated with periodic sounding rod measurements. At periodic intervals during the survey, the profiling was stopped and surface water conductivity, temperature and salinity are recorded with a portable YSI probe on the tow boat. Over 40,000 discrete 3-frequency EM measurements were collected. The data were inverted to 2-layer models representing the water layer thickness and conductivity and the lake bottom conductivity. At spot locations, models were constrained with water depth soundings and surface water conductivity measurements. At other locations along the profiles, the water depth and conductivity were allowed to be free, but the free models were generally consistent with the constrained models. Multilayer sub-bottom models were also explored but were found to be poorly constrained. In West Lake, sub-bottom conductivities decreased from 400 mS/m in the west to 200 mS/m in the east indicating a general W to E decrease in groundwater salinity. In the McCormick Creek system, sub-bottom conductivities increased from 200 mS/m at the north end of Seven Palm Lake to over 650 mS/m at the southern end of Monroe Lake indicating a general N to S increase in ground water salinity. Additional profiles are planned in August, 2015.

  1. Effects of the bottom boundary condition in numerical investigations of dense water cascading on a slope

    NASA Astrophysics Data System (ADS)

    Berntsen, Jarle; Alendal, Guttorm; Avlesen, Helge; Thiem, Øyvind

    2018-05-01

    The flow of dense water along continental slopes is considered. There is a large literature on the topic based on observations and laboratory experiments. In addition, there are many analytical and numerical studies of dense water flows. In particular, there is a sequence of numerical investigations using the dynamics of overflow mixing and entrainment (DOME) setup. In these papers, the sensitivity of the solutions to numerical parameters such as grid size and numerical viscosity coefficients and to the choices of methods and models is investigated. In earlier DOME studies, three different bottom boundary conditions and a range of vertical grid sizes are applied. In other parts of the literature on numerical studies of oceanic gravity currents, there are statements that appear to contradict choices made on bottom boundary conditions in some of the DOME papers. In the present study, we therefore address the effects of the bottom boundary condition and vertical resolution in numerical investigations of dense water cascading on a slope. The main finding of the present paper is that it is feasible to capture the bottom Ekman layer dynamics adequately and cost efficiently by using a terrain-following model system using a quadratic drag law with a drag coefficient computed to give near-bottom velocity profiles in agreement with the logarithmic law of the wall. Many studies of dense water flows are performed with a quadratic bottom drag law and a constant drag coefficient. It is shown that when using this bottom boundary condition, Ekman drainage will not be adequately represented. In other studies of gravity flow, a no-slip bottom boundary condition is applied. With no-slip and a very fine resolution near the seabed, the solutions are essentially equal to the solutions obtained with a quadratic drag law and a drag coefficient computed to produce velocity profiles matching the logarithmic law of the wall. However, with coarser resolution near the seabed, there may be a substantial artificial blocking effect when using no-slip.

  2. Subduction of a low-salinity water mass around the Xisha Islands in the South China Sea.

    PubMed

    Huang, Zhida; Zhuang, Wei; Liu, Hailong; Hu, Jianyu

    2018-02-15

    Based on three climatologically observed temperature and salinity datasets (i.e., GDEM-V3, SCSPOD14 and WOA13), this paper reports a low-salinity (~34.32) water mass in the subsurface-to-intermediate layer around the Xisha Islands in the South China Sea. This water mass mainly subducts from the surface layer into the intermediate layer, characterized by a relatively low potential vorticity tongue extending from the bottom of mixed layer to the thermocline, and accompanied by a thermocline ventilation in spring (especially in April). The potential dynamics are the joint effects of negative wind stress curl, and an anticyclonic eddy triggered by the inherent topographic effect of the Xisha Islands, reflecting that downward vertical motion dominates the subduction. Despite lacking of the homogenous temperature and density, the low-salinity water mass is to some extent similar to the classic mode water and can be regarded as a deformed mode water in the South China Sea.

  3. Wave friction factor rediscovered

    NASA Astrophysics Data System (ADS)

    Le Roux, J. P.

    2012-02-01

    The wave friction factor is commonly expressed as a function of the horizontal water particle semi-excursion ( A wb) at the top of the boundary layer. A wb, in turn, is normally derived from linear wave theory by {{U_{{wb}}/T_{{w}}}}{{2π }} , where U wb is the maximum water particle velocity measured at the top of the boundary layer and T w is the wave period. However, it is shown here that A wb determined in this way deviates drastically from its real value under both linear and non-linear waves. Three equations for smooth, transitional and rough boundary conditions, respectively, are proposed to solve this problem, all three being a function of U wb, T w, and δ, the thickness of the boundary layer. Because these variables can be determined theoretically for any bottom slope and water depth using the deepwater wave conditions, there is no need to physically measure them. Although differing substantially from many modern attempts to define the wave friction factor, the results coincide with equations proposed in the 1960s for either smooth or rough boundary conditions. The findings also confirm that the long-held notion of circular water particle motion down to the bottom in deepwater conditions is erroneous, the motion in fact being circular at the surface and elliptical at depth in both deep and shallow water conditions, with only horizontal motion at the top of the boundary layer. The new equations are incorporated in an updated version (WAVECALC II) of the Excel program published earlier in this journal by Le Roux et al. Geo-Mar Lett 30(5): 549-560, (2010).

  4. Pathways of basal meltwater from Antarctic ice shelves: A model study

    NASA Astrophysics Data System (ADS)

    Kusahara, Kazuya; Hasumi, Hiroyasu

    2014-09-01

    We investigate spreading pathways of basal meltwater released from all Antarctic ice shelves using a circumpolar coupled ice shelf-sea ice-ocean model that reproduces major features of the Southern Ocean circulation, including the Antarctic Circumpolar Current (ACC). Several independent virtual tracers are used to identify detailed pathways of basal meltwaters. The spreading pathways of the meltwater tracers depend on formation sites, because the meltwaters are transported by local ambient ocean circulation. Meltwaters from ice shelves in the Weddell and Amundsen-Bellingshausen Seas in surface/subsurface layers are effectively advected to lower latitudes with the ACC. Although a large portion of the basal meltwaters is present in surface and subsurface layers, a part of the basal meltwaters penetrates into the bottom layer through active dense water formation along the Antarctic coastal margins. The signals at the seafloor extend along the topography, showing a horizontal distribution similar to the observed spreading of Antarctic Bottom Water. Meltwaters originating from ice shelves in the Weddell and Ross Seas and in the Indian sector significantly contribute to the bottom signals. A series of numerical experiments in which thermodynamic interaction between the ice shelf and ocean is neglected regionally demonstrates that the basal meltwater of each ice shelf impacts sea ice and/or ocean thermohaline circulation in the Southern Ocean. This article was corrected on 10 OCT 2014. See the end of the full text for details.

  5. Inorganic and organic nitrogen uptake by phytoplankton and heterotrophic bacteria in the stratified Mid-Atlantic Bight

    NASA Astrophysics Data System (ADS)

    Bradley, Paul B.; Sanderson, Marta P.; Frischer, Marc E.; Brofft, Jennifer; Booth, Melissa G.; Kerkhof, Lee J.; Bronk, Deborah A.

    2010-08-01

    Little is known about the relative importance of inorganic and organic nitrogen (N) sources in fueling production of phytoplankton versus heterotrophic bacteria on the continental shelf. This issue was addressed during two diel experiments conducted in the Mid-Atlantic Bight at the Long-term Ecosystem Observatory, LEO-15, off southern New Jersey. Uptake of 15N-labeled ammonium (NH 4+), nitrate (NO 3-), and nitrite (NO 2-), and dual-labeled ( 15N and 13C) urea and dissolved free amino acids was measured in water taken from the surface and bottom mixed layers approximately every 4 h over two 24 h periods in July 2002. Two methods were used to quantify 15N uptake rates: (1) traditional filtration into various phytoplankton and bacterial size classes, and (2) flow cytometric (FCM) sorting of autotrophic cells based on the presence of chlorophyll autofluorescence. Due to a strong pycnocline, the nutrient composition was quite distinct between the surface and bottom mixed layers. Dissolved organic N (DON) comprised >99% of the total dissolved N (TDN) pool in surface waters, whereas the bottom-water TDN pool was roughly divided between NH 4+, NO 3-, and DON. Urea was the dominant N form used by all fractions at the surface, and although phytoplankton >3 μm was responsible for most of the urea uptake, bacterial use was detected using stable isotopes and also suggested by ureC sequence analysis. The majority of ureC sequences recovered from the 0.2-0.8 μm fraction belonged to members of the Alphaproteobacteria (46%), whereas those of the 0.8-3.0 μm size class consisted primarily of Cyanobacteria (70%). In contrast to the surface, N uptake in the bottom layer was dominated by NH 4+. The bacterial fraction was responsible for 20-49% of the size-fractionated NH 4+ and NO 3- uptake in surface samples and 36-93% at the bottom. These results suggest that organic N, such as urea, is a viable source of N nutrition to phytoplankton forced to compete with heterotrophic bacteria for limited inorganic N.

  6. Formation of Hydro-acoustic Waves in Dissipative Coupled Weakly Compressible Fluids

    NASA Astrophysics Data System (ADS)

    Abdolali, A.; Kirby, J. T., Jr.; Bellotti, G.

    2014-12-01

    Recent advances in deep sea measurement technology provide an increasing opportunity to detect and interpret hydro-acoustic waves as a component in improved Tsunami Early Warning Systems (TEWS). For the idealized case of a homogeneous water column above a moving but otherwise rigid bottom (in terms of assessing acoustic wave interaction), the description of the infinite family of acoustic modes is characterized by local water depth at source area; i.e. the period of the first acoustic mode is given by four times the required time for sound to travel from the seabed to the surface. Spreading off from earthquake zone, the dominant spectrum is filtered and enriched by seamounts and barriers. This study focuses on the characteristics of hydro-acoustic waves generated by sudden sea bottom motion in a weakly compressible fluid coupled with an underlying sedimentary layer, where the added complexity of the sediment layer rheology leads to both the lowering of dominant spectral peaks and wave attenuation across the full spectrum. To overcome the computational difficulties of three-dimensional models, we derive a depth integrated equation valid for varying water depth and sediment thickness. Damping behavior of the two layered system is initially taken into account by introducing the viscosity of fluid-like sedimentary layer. We show that low frequency pressure waves which are precursor components of tsunamis contain information of seafloor motion.

  7. Freshening by glacial meltwater enhances melting of ice shelves and reduces formation of Antarctic Bottom Water

    PubMed Central

    van Wijk, Esmee

    2018-01-01

    Strong heat loss and brine release during sea ice formation in coastal polynyas act to cool and salinify waters on the Antarctic continental shelf. Polynya activity thus both limits the ocean heat flux to the Antarctic Ice Sheet and promotes formation of Dense Shelf Water (DSW), the precursor to Antarctic Bottom Water. However, despite the presence of strong polynyas, DSW is not formed on the Sabrina Coast in East Antarctica and in the Amundsen Sea in West Antarctica. Using a simple ocean model driven by observed forcing, we show that freshwater input from basal melt of ice shelves partially offsets the salt flux by sea ice formation in polynyas found in both regions, preventing full-depth convection and formation of DSW. In the absence of deep convection, warm water that reaches the continental shelf in the bottom layer does not lose much heat to the atmosphere and is thus available to drive the rapid basal melt observed at the Totten Ice Shelf on the Sabrina Coast and at the Dotson and Getz ice shelves in the Amundsen Sea. Our results suggest that increased glacial meltwater input in a warming climate will both reduce Antarctic Bottom Water formation and trigger increased mass loss from the Antarctic Ice Sheet, with consequences for the global overturning circulation and sea level rise. PMID:29675467

  8. Freshening by glacial meltwater enhances melting of ice shelves and reduces formation of Antarctic Bottom Water.

    PubMed

    Silvano, Alessandro; Rintoul, Stephen Rich; Peña-Molino, Beatriz; Hobbs, William Richard; van Wijk, Esmee; Aoki, Shigeru; Tamura, Takeshi; Williams, Guy Darvall

    2018-04-01

    Strong heat loss and brine release during sea ice formation in coastal polynyas act to cool and salinify waters on the Antarctic continental shelf. Polynya activity thus both limits the ocean heat flux to the Antarctic Ice Sheet and promotes formation of Dense Shelf Water (DSW), the precursor to Antarctic Bottom Water. However, despite the presence of strong polynyas, DSW is not formed on the Sabrina Coast in East Antarctica and in the Amundsen Sea in West Antarctica. Using a simple ocean model driven by observed forcing, we show that freshwater input from basal melt of ice shelves partially offsets the salt flux by sea ice formation in polynyas found in both regions, preventing full-depth convection and formation of DSW. In the absence of deep convection, warm water that reaches the continental shelf in the bottom layer does not lose much heat to the atmosphere and is thus available to drive the rapid basal melt observed at the Totten Ice Shelf on the Sabrina Coast and at the Dotson and Getz ice shelves in the Amundsen Sea. Our results suggest that increased glacial meltwater input in a warming climate will both reduce Antarctic Bottom Water formation and trigger increased mass loss from the Antarctic Ice Sheet, with consequences for the global overturning circulation and sea level rise.

  9. SOFIA Science Imagery

    NASA Image and Video Library

    2017-09-14

    SCI2017_0003: The column of material at and just below the surface of dwarf planet Ceres (box) – the top layer contains anhydrous (dry) pyroxene dust accumulated from space mixed in with native hydrous (wet) dust, carbonates, and water ice. (Bottom) Cross section of Ceres showing the surface layers that are the subject of this study plus a watery mantle and a rocky-metallic core. Credit: Pierre Vernazza, LAM–CNRS/AMU

  10. Does deep ocean mixing drive upwelling or downwelling of abyssal waters?

    NASA Astrophysics Data System (ADS)

    Ferrari, R. M.; McDougall, T. J.; Mashayek, A.; Nikurashin, M.; Campin, J. M.

    2016-02-01

    It is generally understood that small-scale mixing, such as is caused by breaking internal waves, drives upwelling of the densest ocean waters that sink to the ocean bottom at high latitudes. However the observational evidence that the turbulent fluxes generated by small-scale mixing in the stratified ocean interior are more vigorous close to the ocean bottom than above implies that small-scale mixing converts light waters into denser ones, thus driving a net sinking of abyssal water. Using a combination of numerical models and observations, it will be shown that abyssal waters return to the surface along weakly stratified boundary layers, where the small-scale mixing of density decays to zero. The net ocean meridional overturning circulation is thus the small residual of a large sinking of waters, driven by small-scale mixing in the stratified interior, and a comparably large upwelling, driven by the reduced small-scale mixing along the ocean boundaries.

  11. Remote sensing of Earth terrain

    NASA Technical Reports Server (NTRS)

    Kong, Jin AU

    1987-01-01

    Earth terrain covers were modeled as random media characterized by different dielectric constants and correlation functions. In order to model sea ice with brine inclusions and vegetation with row structures, the random medium is assumed to be anisotropic. A three layer model is used to simulate a vegetation field or a snow covered ice field with the top layer being snow or leaves, the middle layer being ice or trunks, and the bottom layer being sea water or ground. The strong fluctuation theory with the distorted Born approximation is applied to the solution of the radar backscattering coefficients.

  12. Physical, chemical, and biological aspects of the Duwamish River Estuary, King County, Washington, 1963-67

    USGS Publications Warehouse

    Santos, John F.; Stoner, J.D.

    1972-01-01

    This report describes the significant results to 1967 of a comprehensive study that began in 1963 to evaluate what changes take place in an estuary as the loads .of raw and partially treated industrial and municipal wastes are replaced by effluent from a secondary treatment plant. The study area is the Duwamish River estuary, about 18.3 river kilometers long. At mean sea level the estuary has a water-surface area of about 1 square mile and a mean width of 440 feet. At the lowest and highest recorded tides, the volume of the estuary is about 205 and 592 million cubic feet, respectively. The estuary is well stratified (salt-wedge type) at fresh-water inflows greater than 1,000 cfs (cubic feet per second), but when inflow rates are less than 1,000 cfs the lower 5.6 kilometers of the estuary grades into the partly mixed type. The crosschannel salinity distribution is uniform for a given location and depth. Salinity migration is controlled by tides and fresh-water inflow. At fresh-water inflow rates greater than 1,000 cfs, water in the upper 8.4 kilometers of the estuary is always fresh regardless of tide. At inflow rates less than 600 cfs and tide heights greater than 10 feet; some salinity has been detected 16.1 kilometers above the mouth of the estuary. Studies using a fluorescent dye show that virtually no downward mixing into the salt wedge occurs; soluble pollutants introduced at the upper end of the estuary stay in the surface layer (5-15 ft thick). On the basis of dye studies when fresh-water inflow is less than 400 cfs, it is estimated that less than 10 percent of a pollutant will remain in the estuary a minimum of 7 days. Longitudinal dispersion coefficients for the surface layer have been determined to be on the order of 100-400 square feet per second. Four water-quality stations automatically monitor DO (dissolved oxygen), water temperature, pH, and specific conductance; at one station solar radiation also is measured. DO concentration in the surface layer decreases almost linearly in a downstream direction. Minimum DO concentration in the surface layer is usually greater than 4 rag/1 (milligrams per liter). The smallest DO values are consistently recorded in the bottom layer at the station 7.7 kilometers above the mouth; monthly means of less than 3 mg/1 of DO have occurred at this point. Manual sampling shows that the DO sag in the bottom layer oscillates between 7.7 and 10.4 kilometers above the mouth of the estuary. Multiple-regression analysis shows that the surface DO content can be estimated from the fresh-water inflow and water temperature. Tidal exchange and fresh-water inflow indirectly control the bottom DO content. Information available from previous studies failed to indicate a progressive decrease in DO content during the period 1949-56, but data from the present study suggest a slight general decrease in the annual minimum DO concentrations in both the upper and lower layers. Average nitrate concentration in fresh water at station 16.2 has increased progressively since 1964, by amounts greater than those which can be attributed to the Renton Treatment Plant, 4.3 kilometers upstream from station 16.2. The BOD (biochemical oxygen demand) in both surface and bottom layers is generally less than 4 rag/1 of oxygen, but values greater than 6 rag/1 have been measured during a period of phytoplankton bloom. Phytoplankton blooms can occur during periods of minimum tidal exchange and fresh-water inflows of less than 300 cfs if solar radiation and water temperature are optimum. Nutrients (nitrogen and phosphorus compounds) do not control the occurrence of a bloom, because sufficient quantities of these nutrients are always present. Nutrients in the treated effluent may increase the biomass of the bloom. Trace-element studies have not defined any role that these elements may play in algal growth. The inflowing fresh water contains principally calcium and bicarbonate and has a dissolved-solids content ra

  13. Global view of sea-ice production in polynyas and its linkage to dense/bottom water formation

    NASA Astrophysics Data System (ADS)

    Ohshima, Kay I.; Nihashi, Sohey; Iwamoto, Katsushi

    2016-12-01

    Global overturning circulation is driven by density differences. Saline water rejected during sea-ice formation in polynyas is the main source of dense water, and thus sea-ice production is a key factor in the overturning circulation. Due to difficulties associated with in situ observation, sea-ice production and its interannual variability have not been well understood until recently. Methods to estimate sea-ice production on large scales have been developed using heat flux calculations based on satellite microwave radiometer data. Using these methods, we present the mapping of sea-ice production with the same definition and scale globally, and review the polynya ice production and its relationship with dense/bottom water. The mapping demonstrates that ice production rate is high in Antarctic coastal polynyas, in contrast to Arctic coastal polynyas. This is consistent with the formation of Antarctic Bottom Water (AABW), the densest water mass which occupies the abyssal layer of the global ocean. The Ross Ice Shelf polynya has by far the highest ice production in the Southern Hemisphere. The Cape Darnley polynya (65°E-69°E) is found to be the second highest production area and recent observations revealed that this is the missing (fourth) source of AABW. In the region off the Mertz Glacier Tongue (MGT), the third source of AABW, sea-ice production decreased by as much as 40 %, due to the MGT calving in early 2010, resulting in a significant decrease in AABW production. The Okhotsk Northwestern polynya exhibits the highest ice production in the Northern Hemisphere, and the resultant dense water formation leads to overturning in the North Pacific, extending to the intermediate layer. Estimates of its ice production show a significant decrease over the past 30-50 years, likely causing the weakening of the North Pacific overturning. These regions demonstrate the strong linkage between variabilities of sea-ice production and bottom/intermediate water formation. The mapping has also provided surface boundary conditions and validation data of heat- and salt-flux associated with sea-ice formation/melting for various ocean and coupled models.

  14. Near-bottom energy cascade from subinertial flows to ocean mixing in the northeastern South China Sea

    NASA Astrophysics Data System (ADS)

    Zhang, Y.; Liu, Z.; Zhao, Y.; Wang, W.; Li, J.; Xu, J.

    2013-12-01

    The motions with different scales in the bottom boundary layer are potentially important in controlling the water mass transportation. Many physical processes are involved in transferring energy from mesoscale to small-scale motions. Recent studies suggest that subinertial flows should be taken into account in the parameterization of deep-ocean mixing besides topography and tidal forcing. Here, we present the current velocity data obtained from 2 moored downward-looking ADCPs (Acoustic Doppler Current Profiler) and 1 RCM (Recording Current Meter) moored near the bottom boundary layer at a water depth of about 2000 m in the northeastern South China Sea from 2012 to 2013. Specifically, they include an ADCP 1200 kHz deployed at 30 m, an ADCP 300 kHz deployed at 110 m, and a RCM deployed at 40 m above the seafloor. Subinertial flows were calculated from the moored current velocity data by low-pass filtering with a cutoff frequency of 0.3 cycles per day (the local inertial period is about 35 hours). The horizontal subinertial flows were quite strong with average values of 2-5 cm/s. The strong downward vertical velocity with average values of 1-2 cm/s was observed during times of weak subinertial flows. The vertical propagation during both the times of weak and strong subinertial flows can also be shown by vector spectra of horizontal near-inertial current velocity. Turbulent kinetic energy production rate estimated indirectly with the variances of ADCP velocities will be compared with the subinertial kinetic energy to detect the processes of energy cascade from mesoscale motions to small-scale oscillations. The results presented in this study can provide an observational evidence for such energy cascade near the bottom boundary layer in the deep South China Sea.

  15. On the penetration depth of the Antarctic Circumpolar Current

    NASA Astrophysics Data System (ADS)

    Tarakanov, R.

    2012-04-01

    The Antarctic Circumpolar Current (ACC) is a geostrophic current which encircles Antarctica from west to east. Thus this current is a buffer zone hindering the water exchange (by geostrophic currents) between high and mid-latitudes of the World Ocean in the Southern Hemisphere. The series of the transverse barriers (Phoenix Rift, Hero Ridge, and Shackleton and North Scotia ridges in the region of the Drake Passage and Scotia Sea, Mid-Atlatic Ridge in the Atlantic, Kerguelen Rise in the Indian Ocean, Macquarie Ridge south of New Zealand, and East Pacific Rise) limits the penetration depth of the ACC. The expedition studies of IO RAS in 2003-2011 were concentrated in the Drake Passage. Seven hydrographic sections across the passage and one survey in the central part of the passage were executed during this period. Velocity measurements (by LADCP) on these sections revealed the near-zero transport through the Drake Passage in the water layer 28.26>gamma_n>28.16 which is considered very low layer of circumpolar water and occupied near the bottom. This result, considering quasi-isopycnal spreading of water masses, leads to exclusion of this layer from the circumpolar flow. This conclusion is confirmed by analysis of the data of Russian sections, historical hydrographic database (WODB2009) in the Drake Passage and the Scotia Sea in combination with the satellite altimetry data and taking into account the bottom relief. It shows that the circulation in the aforesaid layer in the Drake Passage and the Scotia Sea is essentially across the ACC jets due to the presence of the Shackleton and North Scotia ridges although both of these ridges are permeable for this layer.

  16. Turning Ocean Mixing Upside Down

    NASA Astrophysics Data System (ADS)

    Ferrari, Raffaele; Mashayek, Ali; Campin, Jean-Michael; McDougall, Trevor; Nikurashin, Maxim

    2015-11-01

    It is generally understood that small-scale mixing, such as is caused by breaking internal waves, drives upwelling of the densest ocean waters that sink to the ocean bottom at high latitudes. However the observational evidence that small-scale mixing is more vigorous close to the ocean bottom than above implies that small-scale mixing converts light waters into denser ones, thus driving a net sinking of abyssal water. It is shown that abyssal waters return to the surface along weakly stratified boundary layers, where the small-scale mixing of density decays to zero. The net ocean meridional overturning circulation is thus the small residual of a large sinking of waters, driven by small-scale mixing in the stratified interior, and an equally large upwelling, driven by the reduced small-scale mixing along the ocean boundaries. Thus whether abyssal waters upwell or sink in the net cannot be inferred simply from the vertical profile of mixing intensity, but depends also on the ocean hypsometry, i.e. the shape of the bottom topography. The implications of this result for our understanding of the abyssal ocean circulation will be presented with a combination of numerical models and observations.

  17. Bottom RedOx Model (BROM v.1.1): a coupled benthic-pelagic model for simulation of water and sediment biogeochemistry

    NASA Astrophysics Data System (ADS)

    Yakushev, Evgeniy V.; Protsenko, Elizaveta A.; Bruggeman, Jorn; Wallhead, Philip; Pakhomova, Svetlana V.; Yakubov, Shamil Kh.; Bellerby, Richard G. J.; Couture, Raoul-Marie

    2017-02-01

    Interactions between seawater and benthic systems play an important role in global biogeochemical cycling. Benthic fluxes of some chemical elements (e.g., C, N, P, O, Si, Fe, Mn, S) alter the redox state and marine carbonate system (i.e., pH and carbonate saturation state), which in turn modulate the functioning of benthic and pelagic ecosystems. The redox state of the near-bottom layer in many regions can change with time, responding to the supply of organic matter, physical regime, and coastal discharge. We developed a model (BROM) to represent key biogeochemical processes in the water and sediments and to simulate changes occurring in the bottom boundary layer. BROM consists of a transport module (BROM-transport) and several biogeochemical modules that are fully compatible with the Framework for the Aquatic Biogeochemical Models, allowing independent coupling to hydrophysical models in 1-D, 2-D, or 3-D. We demonstrate that BROM is capable of simulating the seasonality in production and mineralization of organic matter as well as the mixing that leads to variations in redox conditions. BROM can be used for analyzing and interpreting data on sediment-water exchange, and for simulating the consequences of forcings such as climate change, external nutrient loading, ocean acidification, carbon storage leakage, and point-source metal pollution.

  18. Hydrocarbons in the Surface Layer of Bottom Sediments in the Northwestern Caspian Sea

    NASA Astrophysics Data System (ADS)

    Nemirovskaya, I. A.; Ostrovskaya, E. V.

    2018-03-01

    The paper presents research results on the concentrations and compositions of aliphatic and polycyclic aromatic hydrocarbons in the surface layer of bottom sediments in the Northwestern Caspian Sea (2014) and compares them to data for sediments of the Middle and Southern Caspian (2012-2013). The seepage of hydrocarbons out of the sediment mass, resulting in abnormally high concentrations of aliphatic hydrocarbons per dry weight (up to 468 μg/g), as well as within the Corg composition (up to 35.2%), is considered the main source of hydrocarbons in sediments in the surveyed area of the Northern Caspian. This is also confirmed by the absence of any correlation between the hydrocarbon and Corg distributions, as well as by the transformed oil composition of high-molecular alkanes. The distribution of markers within polycyclic aromatic hydrocarbons points to a mixed genesis—petrogenic and pyrogenic—with prevalence of the latter. Unlike the shallow-water northern part of the Caspian Sea, the content and composition of hydrocarbons in deep-seated sediments are affected by facial conditions of sedimentation and by matter exchange at the water-bottom interface. Therefore, despite high Corg concentrations (up to 9.9%), sediments in deep-water depressions are characterized by a quite low concentration of aliphatic hydrocarbons (52 μg/g on average; 0.2% of Corg) with prevailing natural allochthonous alkanes.

  19. The role of horizontal exchanges on ventilation of the benthic boundary layer on the Black Sea shelf

    NASA Astrophysics Data System (ADS)

    Shapiro, Georgy; Wobus, Fred

    2010-05-01

    The state of the benthic component of the shelf ecosystem is strongly influenced by availability of dissolved oxygen. The chemical structure of the Black Sea waters is largely determined by the location and the strength of the pycnocline. Due to similarity in the mechanisms of vertical exchanges the oxycline and the chemocline occur at the same depth intervals as the halocline and pycnocline (Özsoy and Ünlüata, 1997). As the data for dissolved oxygen on the shelf is relatively sparse we assume that much abundant data on physical parameters (temperature and salinity) can be used as proxy in determining the location of the oxycline and hence the spatial extent of near-bottom waters depleted in oxygen. When the waters of the benthic boundary layers below the pycnocline are ‘locked' i.e. unable to mix vertically with surface then the biological pump and supply of oxygen are suppressed. However, the locked water can, in principle, move ‘horizontally', predominantly along the constant density levels and get ventilated via isopycnal exchanges. The isopycnals in the Black Sea have generally a dome-like structure, so that the isopycnal movements across the shelf break can ventilate bottom shelf waters with water masses from upper parts of the water column in the deep sea. We use the intra- and inter-annual variations in the near-bottom temperature as indicators for variability of physical conditions in the benthic boundary layer on the shelf. The physical reason for this is that interannual variations in the near-bottom temperature are directly related with the volume of cold waters (Ivanov et al., 2000) which are formed on the shelf and then exported into the deep sea, so that variations in temperature may indicate changes in the intensity of horizontal exchanges. In this paper we identified areas on the Black Sea margin where bottom waters can not be mixed vertically (‘locked' waters) during the winter months and locations to which the locked waters can move ‘horizontally'. The potential energy approach was used to identify the spatial and temporal variability of the areas and volumes occupied by the locked waters. This approach allows to assess a relative strength of the ability of locked waters to mix vertically with oxygen rich surface waters as compared to ‘horizontal' exchanges with the deep sea along isopycnic surfaces. Analysis of interannual variability of temperature showed that the period 1965-1983 was a warm period when the ‘summer' season ( May to November) temperatures of the benthic waters were higher than the average; to the contrary the period 1983-2001 (i.e. up to end of available data sets) was a cold period. Correlations between various time series of hydrographical and meteorological parameters were calculated to establish the relative importance of vertical versus horizontal exchanges in ventilation of the locked water masses. A low correlation (R=0.24) was obtained between the variation of the winter sea surface temperature on the shelf and the ‘summer' temperatures of locked waters. A higher correlation (R=0.56) was found between the summer temperatures of the Cold Intermediate Waters below the seasonal pycnocline in the deep sea (density range sigma-theta= 14.2-14.8) and the ‘summer' temperatures of the ‘locked' waters in the benthic boundary layer on the shelf. Analysis shows that the isopycnic exchanges with the deep sea are more important for ventilation of the benthic boundary layer on the shelf than winter convection on the shelf itself. This work was made possible via support from EU FP6 SESAME and EU FP7 MyOcean projects and NERC PhD studentship. References Özsoy, E. and Ünlüata, Ü., 1997. Oceanography of the Black Sea: a review of some recent results. Earth-Sci. Rev., 42(4): 231-272. Ivanov, L.I., Belokopytov, V.N., Özsoy, E. and Samodurov, A., 2000. Ventilation of the Black Sea pycnocline on seasonal and interannual time scales. Mediterr. Mar. Sci., 1/2: 61-74.

  20. Modeling the formation of the quench product in municipal solid waste incineration (MSWI) bottom ash.

    PubMed

    Inkaew, Kanawut; Saffarzadeh, Amirhomayoun; Shimaoka, Takayuki

    2016-06-01

    This study investigated changes in bottom ash morphology and mineralogy under lab-scale quenching conditions. The main purpose was to clarify the mechanisms behind the formation of the quench product/layer around bottom ash particles. In the experiments, the unquenched bottom ashes were heated to 300°C for 1h, and were quenched by warm water (65°C) with different simulated conditions. After having filtered and dried, the ashes were analyzed by a combination of methodologies namely, particle size distribution analysis, intact particle and thin-section observation, X-ray diffractometry, and scanning electron microscope with energy dispersive X-ray spectroscopy. The results indicated that after quenching, the morphology and mineralogy of the bottom ash changed significantly. The freshly quenched bottom ash was dominated by a quench product that was characterized by amorphous and microcrystalline calcium-silicate-hydrate (CSH) phases. This product also enclosed tiny minerals, glasses, ceramics, metals, and organic materials. The dominant mineral phases produced by quenching process and detected by XRD were calcite, Friedel's salt, hydrocalumite and portlandite. The formation of quench product was controlled by the fine fraction of the bottom ash (particle size <0.425mm). From the observations, a conceptual model of the ash-water reactions and formation of the quench product in the bottom ash was proposed. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Effects of phenology, water availability and seed source on loblolly pine biomass partitioning and transpiration.

    PubMed

    Barnes, Andrew D

    2002-07-01

    One-year-old loblolly pine (Pinus taeda L.) seedlings from four seed sources (Arkansas, Georgia, Texas and Virginia) grown in 1-m-deep sand-filled pits in two water regimes (well-watered and drought) were studied, to gain insight into the process of seedling establishment. Whole-plant transpiration was measured biweekly from July to December. Whole-plant harvests were conducted at 6-week intervals from April to December. Whole-plant transpiration and transpiration per unit leaf and root area were affected by treatment, seedlot and phenology. Seedlings of the Arkansas seedlot maintained significantly higher transpiration rates per unit leaf and root area during drought than seedlings of the Virginia, Georgia or Texas seedlots, but did not accumulate greater biomass. The high transpiration rates of the Arkansas seedlings were attributed to their deep root systems. Allometric relationships indicated that, relative to the whole plant, biomass allocation to needles of drought-treated seedlings was enhanced during the summer (allometric ratio 1.09), whereas allocation to roots was enhanced in the spring and fall (allometric ratios of 1.13 and 1.09, respectively). Relative to the whole plant, biomass allocation to needles of well-watered seedlings was enhanced throughout the experiment (allometric ratio of 1.16 declining to 1.05), whereas the allometric ratio of root to total biomass was 0.89 or less throughout. Allometric relationships also indicated variation in biomass partitioning to roots in three soil layers (0-30, 30-60 and 60-100 cm), which differed among harvests in each soil layer. Root growth in both well-watered and drought-treated seedlings was concentrated in the top soil layer in the spring, shifted to the middle and bottom soil layers in the summer, and then increased in the top soil layer in the fall. Compared with well-watered seedlings, drought-treated seedlings had higher rates of root growth in the bottom soil layer in the fall, a characteristic that would confer tolerance to future periods of limited soil water availability. 2002 Heron Publishing--Victoria, Canada

  2. Global assessment of benthic nepheloid layers and linkage with upper ocean dynamics

    NASA Astrophysics Data System (ADS)

    Gardner, Wilford D.; Richardson, Mary Jo; Mishonov, Alexey V.

    2018-01-01

    Global maps of the maximum bottom concentration, thickness, and integrated particle mass in benthic nepheloid layers are published here to support collaborations to understand deep ocean sediment dynamics, linkage with upper ocean dynamics, and assessing the potential for scavenging of adsorption-prone elements near the deep ocean seafloor. Mapping the intensity of benthic particle concentrations from natural oceanic processes also provides a baseline that will aid in quantifying the industrial impact of current and future deep-sea mining. Benthic nepheloid layers have been mapped using 6,392 full-depth profiles made during 64 cruises using our transmissometers mounted on CTDs in multiple national/international programs including WOCE, SAVE, JGOFS, CLIVAR-Repeat Hydrography, and GO-SHIP during the last four decades. Intense benthic nepheloid layers are found in areas where eddy kinetic energy in overlying waters, mean kinetic energy 50 m above bottom (mab), and energy dissipation in the bottom boundary layer are near the highest values in the ocean. Areas of intense benthic nepheloid layers include the Western North Atlantic, Argentine Basin in the South Atlantic, parts of the Southern Ocean and areas around South Africa. Benthic nepheloid layers are weak or absent in most of the Pacific, Indian, and Atlantic basins away from continental margins. High surface eddy kinetic energy is associated with the Kuroshio Current east of Japan. Data south of the Kuroshio show weak nepheloid layers, but no transmissometer data exist beneath the Kuroshio, a deficiency that should be remedied to increase understanding of eddy dynamics in un-sampled and under-sampled oceanic areas.

  3. The deep meridional overturning circulation in the Indian Ocean inferred from the GECCO synthesis

    NASA Astrophysics Data System (ADS)

    Wang, Weiqiang; Köhl, Armin; Stammer, Detlef

    2012-11-01

    The deep time-varying meridional overturning circulation (MOC) in the Indian Ocean in the German “Estimating the Circulation and Climate of the Ocean” consortium efforts (GECCO) ocean synthesis is being investigated. An analysis of the integrated circulation suggests that, on time average, 2.1 Sv enter the Indian Ocean in the bottom layer (>3200 m) from the south and that 12.3 Sv leave the Indian Ocean in the upper and intermediate layers (<1500 m), composed of the up-welled bottom layer inflow water, augmented by 9.6 Sv Indonesian Throughflow (ITF) water. The GECCO time-mean results differ substantially from those obtained by inverse box models, which being based on individual hydrographic sections and due to the strong seasonal cycle are susceptible to aliasing. The GECCO solution shows a large seasonal variation in its deep MOC caused by the seasonal reversal of monsoon-related wind stress forcing. The associated seasonal variations of the deep MOC range from -7 Sv in boreal winter to 3 Sv in summer. In addition, the upper and bottom transports across the 34°S section show pronounced interannual variability with roughly biennial variations superimposed by strong anomalies during each La Niña phase as well as the ITF, which mainly affect the upper layer transports. On decadal and longer timescale, the meridional overturning variability as well as long-term trends differs before and after 1980. GECCO shows a stable trend for the period 1960-1979 and substantial changes in the upper and bottom layer for the period 1980-2001. By means of an extended EOF analysis, the importance of Ekman dynamics as driving forces of the deep MOC of the Indian Ocean on the interannual timescale is highlighted. The leading modes of the zonal and meridional wind stress favour a basin-wide meridional overturning mode via Ekman upwelling or downwelling mostly in the central and eastern Indian Ocean. Moreover, tropical zonal wind stress along the equator and alongshore wind stress off the Sumatra-Java coast contribute to the evolution of the Indian Ocean dipole (IOD) events.

  4. Extreme bottom velocities induced by wind wave and currents in the Gulf of Gdańsk

    NASA Astrophysics Data System (ADS)

    Cieślikiewicz, Witold; Dudkowska, Aleksandra; Gic-Grusza, Gabriela; Jędrasik, Jan

    2017-11-01

    The principal goal of this study is to get some preliminary insights about the intensity of water movement generated by wind waves, and due to the currents in the bottom waters of Gulf of Gdańsk, during severe storms. The Gulf of Gdańsk is located in the southern Baltic Sea. This paper presents the results of analysis of wave and current-induced velocities during extreme wind conditions, which are determined based on long-term historical records. The bottom velocity fields originated from wind wave and wind currents, during analysed extreme wind events, are computed independently of each other. The long-term wind wave parameters for the Baltic Sea region are derived from the 44-year hindcast wave database generated in the framework of the project HIPOCAS funded by the European Union. The output from the numerical wave model WAM provides the boundary conditions for the model SWAN operating in high-resolution grid covering the area of the Gulf of Gdańsk. Wind current velocities are calculated with the M3D hydrodynamic model developed in the Institute of Oceanography of the University of Gdańsk based on the POM model. The three dimensional current fields together with trajectories of particle tracers spreading out of bottom boundary layer are modelled, and the calculated fields of bottom velocities are presented in the form of 2D maps. During northerly winds, causing in the Gulf of Gdańsk extreme waves and most significant wind-driven circulation, the wave-induced bottom velocities are greater than velocities due to currents. The current velocities in the bottom layer appeared to be smaller by an order of magnitude than the wave-induced bottom orbital velocities. Namely, during most severe northerly storms analysed, current bottom velocities ranged about 0.1-0.15 m/s, while the root mean square of wave-induced near-seabed velocities reached maximum values of up to 1.4 m/s in the southern part of Gulf of Gdańsk.

  5. The effect of under-ice melt ponds on their surroundings in the Arctic

    NASA Astrophysics Data System (ADS)

    Feltham, D. L.; Smith, N.; Flocco, D.

    2016-12-01

    In the summer months, melt water from the surface of the Arctic sea ice can percolate down through the ice and flow out of its base. This water is relatively warm and fresh compared to the ocean water beneath it, and so it floats between the ice and the oceanic mixed layer, forming pools of melt water called under-ice melt ponds. Sheets of ice, known as false bottoms, can subsequently form via double diffusion processes at the under-ice melt pond interface with the ocean, trapping the pond against the ice and completely isolating it from the ocean below. This has an insulating effect on the parent sea ice above the trapped pond, altering its rate of basal ablation. A one-dimensional, thermodynamic model of Arctic sea ice has been adapted to study the evolution of under-ice melt ponds and false bottoms over time. Comparing simulations of sea ice evolution with and without an under-ice melt pond provides a measure of how an under-ice melt pond affects the mass balance of the sea ice above it. Sensitivity studies testing the response of the model to a range of uncertain parameters have been performed, revealing some interesting implications of under-ice ponds during their life cycle. By changing the rate of basal ablation of the parent sea ice, and so the flux of fresh water and salt into the ocean, under-ice melt ponds affect the properties of the mixed layer beneath the sea ice. Our model of under-ice melt pond refreezing has been coupled to a simple oceanic mixed layer model to determine the effect on mixed layer depth, salinity and temperature.

  6. Tunnel barrier schottky

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chu, Rongming; Cao, Yu; Li, Zijian

    2018-02-20

    A diode includes: a semiconductor substrate; a cathode metal layer contacting a bottom of the substrate; a semiconductor drift layer on the substrate; a graded aluminum gallium nitride (AlGaN) semiconductor barrier layer on the drift layer and having a larger bandgap than the drift layer, the barrier layer having a top surface and a bottom surface between the drift layer and the top surface, the barrier layer having an increasing aluminum composition from the bottom surface to the top surface; and an anode metal layer directly contacting the top surface of the barrier layer.

  7. MEANS FOR SHIELDING AND COOLING REACTORS

    DOEpatents

    Wigner, E.P.; Ohlinger, L.A.; Young, G.J.; Weinberg, A.M.

    1959-02-10

    Reactors of the water-cooled type and a means for shielding such a rcactor to protect operating personnel from harmful radiation are discussed. In this reactor coolant tubes which contain the fissionable material extend vertically through a mass of moderator. Liquid coolant enters through the bottom of the coolant tubes and passes upwardly over the fissionable material. A shield tank is disposed over the top of the reactor and communicates through its bottom with the upper end of the coolant tubes. A hydrocarbon shielding fluid floats on the coolant within the shield tank. With this arrangements the upper face of the reactor can be opened to the atmosphere through the two superimposed liquid layers. A principal feature of the invention is that in the event radioactive fission products enter thc coolant stream. imposed layer of hydrocarbon reduces the intense radioactivity introduced into the layer over the reactors and permits removal of the offending fuel material by personnel shielded by the uncontaminated hydrocarbon layer.

  8. MODFLOW Ground-Water Model - User Guide to the Subsidence and Aquifer-System Compaction Package (SUB-WT) for Water-Table Aquifers

    USGS Publications Warehouse

    Leake, S.A.; Galloway, D.L.

    2007-01-01

    A new computer program was developed to simulate vertical compaction in models of regional ground-water flow. The program simulates ground-water storage changes and compaction in discontinuous interbeds or in extensive confining units, accounting for stress-dependent changes in storage properties. The new program is a package for MODFLOW, the U.S. Geological Survey modular finite-difference ground-water flow model. Several features of the program make it useful for application in shallow, unconfined flow systems. Geostatic stress can be treated as a function of water-table elevation, and compaction is a function of computed changes in effective stress at the bottom of a model layer. Thickness of compressible sediments in an unconfined model layer can vary in proportion to saturated thickness.

  9. Nuclear Fuel Traces Definition in Storage Ponds of Research VVR-2 and OR Reactors in NRC 'Kurchatov Institute'

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Stepanov, Alexey; Simirskii, Iurii; Stepanov, Vyacheslav

    2015-07-01

    The Gas Plant complex is the experimental base of the Institute of Nuclear Reactors, which is part of the Kurchatov Institute. In 1954 the commissioning of the first Soviet water-cooled water-moderated research reactor VVR-2 on enriched uranium, and until 1983 the complex operated two research water-cooled water-moderated reactors 3 MW (VVR-2) and 300 kW (OR) capacity, which were dismantled in connection with the overall upgrades of the complex. The complex has three storage ponds in the reactor building. They are sub-surface vessels filled with water (the volume of water in each is about 6 m{sup 3}). In 2007-2013 the spentmore » nuclear fuel from storages was removed for processing to 'Mayk'. Survey of Storage Ponds by Underwater Collimated Spectrometric System shows a considerable layer of slime on the bottom of ponds and traces of spent nuclear fuel in one of the storage. For determination qualitative and the quantitative composition of radionuclide we made complex α-, β-, γ- spectrometric research of water and bottom slimes from Gas Plant complex storage ponds. We found the spent nuclear fuel in water and bottom slime in all storage ponds. Specific activity of radionuclides in the bottom slime exceeded specific activity of radionuclides in the ponds water and was closed to levels of high radioactive waste. Analysis of the obtained data and data from earlier investigation of reactor MR storage ponds showed distinctions of specific activity of uranium and plutonium radionuclides. (authors)« less

  10. Convective instability of sludge storage under evaporation and solar radiation

    NASA Astrophysics Data System (ADS)

    Tsiberkin, Kirill; Tatyana, Lyubimova

    2014-05-01

    The sludge storages are an important part of production cycle at salt manufacturing, water supply, etc. A quality of water in the storage depends on mixing of pure water and settled sediment. One of the leading factors is thermal convection. There are two main mechanisms of the layer instability exist. First, it is instability of water due to evaporation from the free surface [1]. It cools the water from upside, increases the particles concentration and leads to the instability in the near-surface layer. Second, the sediment absorbs a solar radiation and heats the liquid from below making it unstable in the near-bottom area. We assume the initial state is the mechanical equilibrium. The water and sediment particles are motionless, the sediment forms a uniform sludge layer of thickness z0, there are no evaporation and heating by solar energy, and the temperature has a linear profile is determined by fixed upper and bottom temperatures of the layer. Taking into account the evaporation and solar radiation absorption, we obtain a non-stationary solution for the temperature using Fourier series method. The local temperature gradients increases rapidly with time, and local Rayleigh number can be estimated by thermal conduction length Lt: Raloc(z,t) = gβ(δT(z,t)/δz)L4t-/νΞ , Lt ~ √Ξt, (1) where g is gravity acceleration, β, ν and Ξ are thermal volume expansion coefficient, kinematic viscosity and thermal conductivity of the liquid, respectively. Raloc* reaches the critical value at finite time t* and water motion begins. The maximal power of solar radiation in visible band equals 230 Wt/m2 at the latitude of "Uralkalii" salt manufacturer (Berezniki, Perm Region, Russian Federation). We neglect IR and UV radiation because of its huge absorption by water [2]. The evaporation speed is found using results for shallow water reservoir [3] and meteorological data for Berezniki [4]. We get the t*~ 6 · 102 s (10 min) for the layer of 1 m depth and t*~ 2 · 103 s (40 min) for the layer of 10 m depth. Dynamic of the system is studied by the Galerkin-Kantorovich method. Using the follow basis along z-axis: wn = cosqnz - cotqnsinh qnz - cosh qnz + coth qnsinh qnz, tanqn = tanhqn, (2) tn = sinpnz, pn = π(2n - 1), n = 1,2,3 ..., 2 (3) we introduce an infinite family of low-mode approximations of the full model. We found the parameter deviations from initial state grow rapidly with Ra > 0 and oscillate with Ra < 0 at the lowest order. Here, Ra is defined by temperature difference between upper and bottom sides of the layer under pure evaporation. The lowest order model does not describe the system in full, because the unstable areas are localized within layer. The study was financially supported by the Russian Foundation for Basic Research (Grant 13-01-96040). [1] Berg J.C. Acrivos A., Boudart M. Advances in Chemical Engineering. Ed. by Drew T.B., Hoopes J.W. Vermeulen T. Academic Press, NY, 1966, V.6, pp. 61-124. [2] ASTM Standard G173-03, 2012, Standard Tables for Reference Solar Spectral Irradiances: Direct Normal and Hemispherical on 37° Tilted Surface, ASTM International, 2012. [3] Tanny J. et al. Evaporation from a small water reservoir: direct measurements and estimates. J. Hydrol., 2008, V.351, pp. 218-229. [4] Shklyaev V.A., Shklyaeva L.S. Climatic resources of Ural's Prikamye. Geographical Bull., Perm State University, 2006, V.2, pp. 76-89.

  11. Effects of sea water on elongated duration of ground motion as well as variation in its amplitude for offshore earthquakes

    NASA Astrophysics Data System (ADS)

    Todoriki, Masaru; Furumura, Takashi; Maeda, Takuto

    2017-01-01

    We investigated the effects of sea water on the propagation of seismic waves using a 3-D finite-difference-method simulation of seismic wave propagation following offshore earthquakes. When using a 1-D layered structure, the simulation results showed strong S- to P-wave conversion at the sea bottom; accordingly, S-wave energy was dramatically decreased by the sea water layer. This sea water de-amplification effect had strong frequency dependence, therefore resembling a low-pass filter in which the cut-off frequency and damping coefficients were defined by the thickness of the sea water layer. The sea water also acted to elongate the duration of Rayleigh wave packet. The importance of the sea water layer in modelling offshore earthquakes was further demonstrated by a simulation using a realistic 3-D velocity structure model with and without sea water for a shallow (h = 14 km) outer-rise Nankai Trough event, the 2004 SE Off Kii Peninsula earthquake (Mw = 7.2). Synthetic seismograms generated by the model when sea water was included were in accordance with observed seismograms for long-term longer period motions, particularly those in the shape of Rayleigh waves.

  12. Development of a three-dimensional, regional, coupled wave, current, and sediment-transport model

    USGS Publications Warehouse

    Warner, J.C.; Sherwood, C.R.; Signell, R.P.; Harris, C.K.; Arango, H.G.

    2008-01-01

    We are developing a three-dimensional numerical model that implements algorithms for sediment transport and evolution of bottom morphology in the coastal-circulation model Regional Ocean Modeling System (ROMS v3.0), and provides a two-way link between ROMS and the wave model Simulating Waves in the Nearshore (SWAN) via the Model-Coupling Toolkit. The coupled model is applicable for fluvial, estuarine, shelf, and nearshore (surfzone) environments. Three-dimensional radiation-stress terms have been included in the momentum equations, along with effects of a surface wave roller model. The sediment-transport algorithms are implemented for an unlimited number of user-defined non-cohesive sediment classes. Each class has attributes of grain diameter, density, settling velocity, critical stress threshold for erosion, and erodibility constant. Suspended-sediment transport in the water column is computed with the same advection-diffusion algorithm used for all passive tracers and an additional algorithm for vertical settling that is not limited by the CFL criterion. Erosion and deposition are based on flux formulations. A multi-level bed framework tracks the distribution of every size class in each layer and stores bulk properties including layer thickness, porosity, and mass, allowing computation of bed morphology and stratigraphy. Also tracked are bed-surface properties including active-layer thickness, ripple geometry, and bed roughness. Bedload transport is calculated for mobile sediment classes in the top layer. Bottom-boundary layer submodels parameterize wave-current interactions that enhance bottom stresses and thereby facilitate sediment transport and increase bottom drag, creating a feedback to the circulation. The model is demonstrated in a series of simple test cases and a realistic application in Massachusetts Bay. 

  13. Radionuclides and mercury in the salt lakes of the Crimea

    NASA Astrophysics Data System (ADS)

    Mirzoyeva, Natalya; Gulina, Larisa; Gulin, Sergey; Plotitsina, Olga; Stetsuk, Alexandra; Arkhipova, Svetlana; Korkishko, Nina; Eremin, Oleg

    2015-11-01

    90Sr concentrations, resulting from the Chernobyl NPP accident, were determined in the salt lakes of the Crimea (Lakes Kiyatskoe, Kirleutskoe, Kizil-Yar, Bakalskoe and Donuzlav), together with the redistribution between the components of the ecosystems. The content of mercury in the waters of the studied reservoirs was also established. Vertical distributions of natural radionuclide activities (238U, 232Th, 226Ra, 210Pb, 40K) and anthropogenic 137Cs concentrations (as radiotracers) were determined in the bottom sediments of the Koyashskoe salt lake (located in the south-eastern Crimea) to evaluate the longterm dynamics and biogeochemical processes. Radiochemical and chemical analysis was undertaken and radiotracer and statistical methods were applied to the analytical data. The highest concentrations of 90Sr in the water of Lake Kiyatskoe (350.5 and 98.0 Bq/m3) and Lake Kirleutskoe (121.3 Bq/m3) were due to the discharge of the Dnieper water from the North-Crimean Canal. The high content of mercury in Lake Kiyatskoe (363.2 ng/L) and in seawater near Lake Kizil-Yar (364 ng/L) exceeded the maximum permissible concentration (3.5 times the maximum). Natural radionuclides provide the main contribution to the total radioactivity (artificial and natural combined) in the bottom sediments of Lake Koyashskoe. The significant concentration of 210Pb in the upper layer of bottom sediments of the lake indicates an active inflow of its parent radionuclide—gaseous 222Rn from the lower layers of the bottom sediment. The average sedimentation rates in Lake Koyashskoe, determined using 210Pb and 137Cs data, were 0.117 and 0.109 cm per year, respectively.

  14. Coastal eutrophication thresholds: a matter of sediment microbial processes.

    PubMed

    Lehtoranta, Jouni; Ekholm, Petri; Pitkänen, Heikki

    2009-09-01

    In marine sediments, the major anaerobic mineralization processes are Fe(III) oxide reduction and sulfate reduction. In this article, we propose that the two alternative microbial mineralization pathways in sediments exert decisively different impacts on aquatic ecosystems. In systems where iron reduction dominates in the recently deposited sediment layers, the fraction of Fe(III) oxides that is dissolved to Fe(II) upon reduction will ultimately be transported to the oxic layer, where it will be reoxidized. Phosphorus, which is released from Fe(III) oxides and decomposing organic matter from the sediment, will be largely trapped by this newly formed Fe(III) oxide layer. Consequently, there are low concentrations of phosphorus in near-bottom and productive water layers and primary production tends to be limited by phosphorus (State 1). By contrast, in systems where sulfate reduction dominates, Fe(III) oxides are reduced by sulfides. This chemical reduction leads to the formation and permanent burial of iron as solid iron sulfides that are unable to capture phosphorus. In addition, the cycling of iron is blocked, and phosphorus is released to overlying water. Owing to the enrichment of phosphorus in water, the nitrogen : phosphorus ratio is lowered and nitrogen tends to limit algal growth, giving an advantage to nitrogen-fixing blue-green algae (State 2). A major factor causing a shift from State 1 to State 2 is an increase in the flux of labile organic carbon to the bottom sediments; upon accelerating eutrophication a critical point will be reached when the availability of Fe(III) oxides in sediments will be exhausted and sulfate reduction will become dominant. Because the reserves of Fe(III) oxides are replenished only slowly, reversal to State 1 may markedly exceed the time needed to reduce the flux of organic carbon to the sediment. A key factor affecting the sensitivity of a coastal system to such a regime shift is formed by the hydrodynamic alterations that decrease the transport of O2 to the near-bottom water, e.g., due to variations in salinity and temperature stratification.

  15. Role of mariculture in the loading and speciation of mercury at the coast of the East China Sea.

    PubMed

    Liang, Peng; Gao, Xuefei; You, Qiongzhi; Zhang, Jin; Cao, Yucheng; Zhang, Chan; Wong, Ming-Hung; Wu, Sheng-Chun

    2016-11-01

    The effects of mariculture on mercury (Hg) contamination and speciation in water, sediment and cultured fish in a typical mariculture zone located in Xiangshan bay, Zhejiang province, east China, were studied. Water, sediment and fish samples were collected from mariculture sites (MS) and from corresponding reference sites (RS) 2500 m away from the MS. The THg concentration in overlying water in Xiangshan bay reached as high as 16.6 ± 19.5 ng L -1 , indicating that anthropogenic sources in this bay may contribution on Hg contamination in overlying water. Mariculture activities resulted in an increase in THg concentration in water from surface and bottom layers, which may be attributed to the discharge of domestic sewage and the accumulation of unconsumed fish feed and fish excreta in the benthic environment. Methylmercury (MeHg) concentrations in the bottom layer of overlying water and top surface layer of porewater underneath MS were higher than at RS, implying that mariculture activities promote Hg methylation in the interface between sediments and water. In addition, the concentrations of MeHg in sediment and porewater were significantly higher in summer than winter. It was observed that THg and MeHg contents in the muscle of blackhead seabream (Acanthopagrus schlegelii) (fed by the trash fish) were significantly higher (p < 0.001) than those in red snapper (Lutjanus campechanus) or perch (Perca fluviatilis) (fed by pellet fish feed). The THg and MeHg concentrations in the fish meat were closely related to the feeding mode, which indicate that fish feed rather than environmental media is the major pathway for Hg accumulation in fish muscle. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. Field Test of a Hybrid Finite-Difference and Analytic Element Regional Model.

    PubMed

    Abrams, D B; Haitjema, H M; Feinstein, D T; Hunt, R J

    2016-01-01

    Regional finite-difference models often have cell sizes that are too large to sufficiently model well-stream interactions. Here, a steady-state hybrid model is applied whereby the upper layer or layers of a coarse MODFLOW model are replaced by the analytic element model GFLOW, which represents surface waters and wells as line and point sinks. The two models are coupled by transferring cell-by-cell leakage obtained from the original MODFLOW model to the bottom of the GFLOW model. A real-world test of the hybrid model approach is applied on a subdomain of an existing model of the Lake Michigan Basin. The original (coarse) MODFLOW model consists of six layers, the top four of which are aggregated into GFLOW as a single layer, while the bottom two layers remain part of MODFLOW in the hybrid model. The hybrid model and a refined "benchmark" MODFLOW model simulate similar baseflows. The hybrid and benchmark models also simulate similar baseflow reductions due to nearby pumping when the well is located within the layers represented by GFLOW. However, the benchmark model requires refinement of the model grid in the local area of interest, while the hybrid approach uses a gridless top layer and is thus unaffected by grid discretization errors. The hybrid approach is well suited to facilitate cost-effective retrofitting of existing coarse grid MODFLOW models commonly used for regional studies because it leverages the strengths of both finite-difference and analytic element methods for predictions in mildly heterogeneous systems that can be simulated with steady-state conditions. © 2015, National Ground Water Association.

  17. Turbulent properties of oceanic near-surface stable boundary layers subject to wind, fresh water, and thermal forcing.

    NASA Astrophysics Data System (ADS)

    St. Laurent, Louis; Clayson, Carol Anne

    2015-04-01

    The near-surface oceanic boundary layer is generally regarded as convectively unstable due to the effects of wind, evaporation, and cooling. However, stable conditions also occur often, when rain or low-winds and diurnal warming provide buoyancy to a thin surface layer. These conditions are prevalent in the tropical and subtropical latitude bands, and are underrepresented in model simulations. Here, we evaluate cases of oceanic stable boundary layers and their turbulent processes using a combination of measurements and process modeling. We focus on the temperature, salinity and density changes with depth from the surface to the upper thermocline, subject to the influence of turbulent processes causing mixing. The stabilizing effects of freshwater from rain as contrasted to conditions of high solar radiation and low winds will be shown, with observations providing surprising new insights into upper ocean mixing in these regimes. Previous observations of freshwater lenses have demonstrated a maximum of dissipation near the bottom of the stable layer; our observations provide a first demonstration of a similar maximum near the bottom of the solar heating-induced stable layer and a fresh-water induced barrier layer. Examples are drawn from recent studies in the tropical Atlantic and Indian oceans, where ocean gliders equipped with microstructure sensors were used to measure high resolution hydrographic properties and turbulence levels. The limitations of current mixing models will be demonstrated. Our findings suggest that parameterizations of near-surface mixing rates during stable stratification and low-wind conditions require considerable revision, in the direction of larger diffusivities.

  18. Results of the flowmeter-injection test in the Long Valley Exploratory Well (Phase II), Long Valley, California

    USGS Publications Warehouse

    Morin, R.H.; Sorey, M.L.; Jacobson, R.D.

    1993-01-01

    Bayboro Harbor and the Port of St. Petersburg, Florida, form a manmade basin adjacent to Tampa Bay that may supply turbid water to the bay and subsequently affect light penetration in water in the bay. To address concerns about the nature and extent of this potential problem, resuspension of bottom sediments, sedimentation, and tributary storm discharge in the basin were studied. Study results indicated that tidal currents, wind waves, and seiche motions do not resuspend bottom sediments. The maneuvering of a cruise ship in the port resuspended bottom sediments, but these sediments settled within 2 hours. Tidal currents and wave action were not large enough o prevent the resuspended sediments from settling in the basin. Analysis of bathymetric surveys of the port made in 1981, 1986, 1987, and 1989 indicates that the cruise ship has deepened the port along its route and that the displaced sediment has been deposited elsewhere within the port. The storm discharge from two tributaries and the effect of tributary storm runoff on the water quality of the harbor were studied during a storm on November 9, 1989. Booker Creek, which drains an urban watershed, was stratified with a thin layer of turbid freshwater flowing into the harbor over a layer of less turbid saltwater. Salt Creek, which primarily drains Lake Maggiore, was only partially stratified and was less turbid. The turbid water from the creeks increased the turbidity only slightly in the harbor, probably because of mixing with less turbid water and particle settling. Thus, the basin provides mixing and settling, which diminish and eliminate the potentially adverse effect on Tampa Bay from tributary storm runoff and large vessel traffic in the basin.

  19. `Log-Chipper' Turbulence in the Convective Boundary Layer.

    NASA Astrophysics Data System (ADS)

    Kimmel, Shari J.; Wyngaard, John C.; Otte, Martin J.

    2002-03-01

    Turbulent fluctuations of a conservative scalar in the atmospheric boundary layer (ABL) can be generated by a scalar flux at the surface, a scalar flux of entrainment at the ABL top, and the `chewing up' of scalar variations on the mesoscale. The first two have been previously studied, while the third is examined in this paper through large-eddy simulation (LES). The LES results show that the scalar fluctuations due to the breakdown of mesoscale variations in advected conservative scalar fields, which the authors call the `log-chipper' component of scalar fluctuations, are uniformly distributed through the depth of the convective ABL, unlike the top-down and bottom-up components.A similarity function, similar to those for the top-down and bottom-up scalars, is derived for the log-chipper scalar variance in the convective ABL and used to compare the relative importance of these three processes for generating scalar fluctuations. Representative mesoscale gradients for water vapor mixing ratio and potential temperature are computed from airplane measurements over both land and water. In situations where the entrainment and surface fluxes are sufficiently small, or the ABL depth, turbulence intensity, or the mesoscale scalar gradient is sufficiently large, the variance of the log-chipper scalar fluctuations in mid-ABL can be of the order of the variance of top-down and bottom-up scalars.

  20. Radiator Enhanced Geothermal System - A Revolutionary Method for Extracting Geothermal Energy

    NASA Astrophysics Data System (ADS)

    Karimi, S.; Marsh, B. D.; Hilpert, M.

    2017-12-01

    A new method of extracting geothermal energy, the Radiator Enhanced Geothermal System (RAD-EGS) has been developed. RAD-EGS attempts to mimic natural hydrothermal systems by 1) generating a vertical vane of artificially produced high porosity/permeability material deep in a hot sedimentary aquifer, 2) injecting water at surface temperatures to the bottom of the vane, where the rock is the hottest, 3) extracting super-heated water at the top of the vane. The novel RAD-EGS differs greatly from the currently available Enhanced Geothermal Systems in vane orientation, determined in the governing local crustal stress field by Shmax and Sl (meaning it is vertical), and in the vane location in a hot sedimentary aquifer, which naturally increases the longevity of the system. In this study, we explore several parameters regimes affecting the water temperature in the extraction well, keeping in mind that the minimum temperature of the extracted water has to be 150 °C in order for a geothermal system to be commercially viable. We used the COMSOL finite element package to simulate coupled heat and fluid transfer within the RAD-EGS model. The following geologic layers from top to bottom are accounted for in the model: i) confining upper layer, ii) hot sedimentary aquifer, and iii) underlying basement rock. The vane is placed vertically within the sedimentary aquifer. An injection well and an extraction well are also included in the simulation. We tested the model for a wide range of various parameters including background heat flux, thickness of geologic layers, geometric properties of the vane, diameter and location of the wells, fluid flow within the wells, regional hydraulic gradient, and permeability and porosity of the layers. The results show that among the aforementioned parameters, background heat flux and the depth of vane emplacement are highly significant in determining the level of commercial viability of the geothermal system. These results indicate that for the terrains with relatively high background heat flux or for vanes located in relatively deep layers, the RAD-EGS can produce economic geothermal energy for more than 40 years. Moreover, these simulations show that the geothermal vane design with the injection well at the bottom and production well at the top of the vane greatly contributes to the longevity of the system.

  1. Millennial-scale changes of surface and bottom water conditions in the northwestern Pacific during the last deglaciation

    NASA Astrophysics Data System (ADS)

    Kim, Sunghan; Khim, Boo-Keun; Ikehara, Ken; Itaki, Takuya; Shibahara, Akihiko; Yamamoto, Masanobu

    2017-07-01

    Changes in water column conditions in the northwestern Pacific during the last 23 ka were reconstructed using geochemical and isotope proxies and redox elemental compositions along with published data (alkenone sea surface temperature (SST) and benthic foraminiferal fauna) at core GH02-1030. Surface water primary productivity in terms of biogenic opal and TOC contents, which mainly represented export production of diatom, was closely related to alkenone (spring-summer) SST and the development of spring-summer mixed layer depth. The different variation patterns of nitrate and silicic acid utilization, estimated by bulk δ15N and δ30Sidiatom values, respectively, are most likely due to the water column denitrification influence on bulk δ15N. Dysoxic bottom water conditions occurred during the Bølling-Allerød (BA) and the Pre-Boreal (PB), which was evident by laminated sediments, abundant dysoxic benthic foraminifers, and increased redox elemental compositions. Although surface water productivity increased during the BA and PB, dysoxic bottom water conditions were caused by a combination of enhanced surface water productivity and reduced ventilation of North Pacific Intermediate Water (NPIW) in response to meltwater input from the high latitude areas. Based on records of core GH02-1030 and other cores in the northwestern Pacific, the Okhotsk Sea, and the Bering Sea, which are all proximal to the modern NPIW source region, dissolved oxygen concentrations of bottom water were more depleted during the BA than PB. Such difference was attributed to more sluggish NPIW ventilation due to more meltwater input during the BA than the PB. The opening or closure of the Bering Strait is critical to the direction of meltwater transport to the northwestern Pacific.

  2. The Sinking and Spreading of The Antarctic Deep Ice Shelf Water In The Ross Sea Studied By In Situ Observaions and Numerical Modeling

    NASA Astrophysics Data System (ADS)

    Rubino, A.; Budillon, G.; Pierini, S.; Spezie, G.

    The sinking and spreading of the Deep Ice Shelf Water (DISW) in the Ross Sea are analyzed using in situ observations and the results of a nonlinear, reduced-gravity, frontal layered numerical "plume" model which is able to simulate the motion of a bottom-arrested current over realistic topography. The model is forced by prescribing the thickness of the DISW vein as well as its density structure at the southern model boundary. The ambient temperature and salinity are imposed using hydrographic data acquired by the Italian PNRA-CLIMA project. In the model water of the quiescent ambient ocean is allowed to entrain in the active deep layer due to a simple param- eterization of turbulent mixing. The importance of forcing the model with a realistic ambient density is demonstrated by carrying out a numerical simulation in which the bottom active layer is forced using an idealized ambient density. In a more realis- tic simulation the path and the density structure of the DISW vein flowing over the Challenger Basin are obtained and are found to be in good agreement with data. The evolution of the deep current beyond the continental shelf is also simulated. It provides useful information on the water flow and mixing in a region of the Ross Sea where the paucity of experimental data does not allow for a detailed description of the deep ocean dynamics.

  3. Suspended particulate loads and transports in the nepheloid layer of the abyssal Atlantic Ocean

    USGS Publications Warehouse

    Biscaye, P.E.; Eittreim, S.L.

    1977-01-01

    Vertical profiles of light scattering from over 1000 L-DGO nephelometer stations in the Atlantic Ocean have been used to calculate mass concentrations of suspended particles based on a calibration from the western North American Basin. From these data are plotted the distributions of particulate concentrations at clear water and in the more turbid near-bottom water. Clear water is the broad minimum in concentration and light scattering that occurs at varying mid-depths in the water column. Concentrations at clear water are as much as one-to-two orders of magnitude lower than those in surface water but still reflect a similar geographic distribution: relatively higher concentrations at ocean margins, especially underneath upwelling areas, and the lowest concentrations underneath central gyre areas. These distributions within the clear water reflect surface-water biogenic productivity, lateral injection of particles from shelf areas and surface circulation patterns and require that the combination of downward vertical and horizontal transport processes of particles retain this pattern throughout the upper water column. Below clear water, the distribution of standing crops of suspended particulate concentrations in the lower water column are presented. The integration of mass of all particles per unit area (gross particulate standing crop) reflects a relative distribution similar to that at the surface and at clear water levels, superimposed on which is the strong imprint of boundary currents along the western margins of the Atlantic. Reducing the gross particulate standing crop by the integral of the concentration of clear water yields a net particulate standing crop. The distribution of this reflects primarily the interaction of circulating abyssal waters with the ocean bottom, i.e. a strong nepheloid layer which is coincident with western boundary currents and which diminishes in intensity equatorward. The resuspended particulate loads in the nepheloid layer of the basins west of the Mid-Atlantic Ridge, resulting from interaction of abyssal currents with the bottom, range from ??? 2 ?? 106 tons in the equatorial Guyana Basin to ??? 50 ?? 106 tons in the North American Basin. The total resuspended particulate load in the western basins (111 ?? 106 tons) is almost an order of magnitude greater than that in the basins east of the Mid-Atlantic Ridge (13 ?? 106 tons). The net northward flux of resuspended particles carried in the AABW drops from ??? 8 ?? 106 tons/year between the southern and northern ends of the Brazil Basin and remains ??? 1 ?? 106 tons/year across the Guyana Basin. ?? 1977.

  4. A numerical analysis of biogeochemical controls with physical modulation on hypoxia during summer in the Pearl River estuary

    NASA Astrophysics Data System (ADS)

    Wang, Bin; Hu, Jiatang; Li, Shiyu; Liu, Dehong

    2017-06-01

    A three-dimensional (3-D) physical-biogeochemical coupled model was applied to explore the mechanisms controlling the dissolved oxygen (DO) dynamics and bottom hypoxia during summer in the Pearl River estuary (PRE). By using the numerical oxygen tracers, we proposed a new method (namely the physical modulation method) to quantify the contributions of boundary conditions and each source and sink process occurring in local and adjacent waters to the DO conditions. A mass balance analysis of DO based on the physical modulation method indicated that the DO conditions at the bottom layer were mainly controlled by the source and sink processes, among which the sediment oxygen demand (SOD) at the water-sediment interface and the re-aeration at the air-sea interface were the two primary processes determining the spatial extent and duration of bottom hypoxia in the PRE. The SOD could cause a significant decrease in the bottom DO concentrations (averaged over July-August 2006) by over 4 mg L-1 on the shelf off the Modaomen sub-estuary, leading to the formation of a high-frequency zone of hypoxia (HFZ). However, the hypoxia that occurred in the HFZ was intermittent and distributed in a small area due to the combined effects of re-aeration and photosynthesis, which behaved as sources for DO and offset a portion of the DO consumed by SOD. The bottom DO concentrations to the west of the lower Lingdingyang Bay (i.e. the western shoal near Qi'ao Island) were also largely affected by high SOD, but there was no hypoxia occurring there because of the influence of re-aeration. Specifically, re-aeration could lead to an increase in the bottom DO concentrations by ˜ 4.8 mg L-1 to the west of the lower Lingdingyang Bay. The re-aeration led to a strong vertical DO gradient between the surface and the lower layers. As a result, the majority (˜ 89 %) of DO supplemented by re-aeration was transported to the lower layers through vertical diffusion and ˜ 28 % reached the bottom eventually. Additional numerical experiments showed that turning off re-aeration could lead to an expansion of the hypoxic area from 237 to 2203 km2 and result in persistent hypoxia (hypoxic frequency > 80 %) to the west of the lower Lingdingyang Bay. Compared to re-aeration and SOD, photosynthesis and water column respiration had relatively small impacts on the DO conditions; turning off these two processes increased the hypoxic area to 591 km2. In summary, our study explicitly elucidated the interactive impacts of physical and biogeochemical processes on the DO dynamics in the PRE, which is critical to understanding hypoxia in this shallow and river-dominated estuarine system.

  5. Optimization and evaluation of a bottom substrate denitrification tank for nitrate removal from a recirculating aquaculture system.

    PubMed

    Pungrasmi, Wiboonluk; Playchoom, Cholticha; Powtongsook, Sorawit

    2013-08-01

    A bottom substrate denitrification tank for a recirculating aquaculture system was developed. The laboratory scale denitrification tank was an 8 L tank (0.04 m2 tank surface area), packed to a depth of 5 cm with a bottom substrate for natural denitrifying bacteria. An aquarium pump was used for gentle water mixing in the tank; the dissolved oxygen in the water was maintained in aerobic conditions (e.g. > 2 mg/L) while anoxic conditions predominated only at the bottom substrate layer. The results showed that, among the four substrates tested (soil, sand, pumice stone and vermiculite), pumice was the most preferable material. Comparing carbon supplementation using methanol and molasses, methanol was chosen as the carbon source because it provided a higher denitrification rate than molasses. When methanol was applied at the optimal COD:N ratio of 5:1, a nitrate removal rate of 4591 +/- 133 mg-N/m2 tank bottom area/day was achieved. Finally, nitrate removal using an 80 L denitrification tank was evaluated with a 610 L recirculating tilapia culture system. Nitrate treatment was performed by batch transferring high nitrate water from the nitrification tank into the denitrification tank and mixing with methanol at a COD:N ratio of 5:1. The results from five batches of nitrate treatment revealed that nitrate was successfully removed from water without the accumulation of nitrite and ammonia. The average nitrate removal efficiency was 85.17% and the average denitrification rate of the denitrification tank was 6311 +/- 945 mg-N/m2 tank bottom area/day or 126 +/- 18 mg-N/L of pumice packing volume/day.

  6. Water turbidity optical meter using optical fiber array for topographical distribution analysis

    NASA Astrophysics Data System (ADS)

    Mutter, Kussay Nugamesh; Mat Jafri, Mohd Zubir; Yeoh, Stephenie

    2017-06-01

    This work is presenting an analysis study for using optical fiber array as turbidity meter and topographical distribution. Although many studies have been figure out of utilizing optical fibers as sensors for turbidity measurements, still the topographical map of suspended particles in water as rare as expected among all of works in literatures in this scope. The effect of suspended particles are highly affect the water quality which varies according to the source of these particles. A two dimensional array of optical fibers in a 1 litter rectangular plastic container with 2 cm cladding off sensing portion prepared to point out 632.8 nm laser power at each fiber location at the container center. The overall output map of the optical power were found in an inhomogeneous distribution such that the top to down layers of a present water sample show different magnitudes. Each sample prepared by mixing a distilled water with large grains sand, small grains sand, glucose and salt. All with different amount of concentration which measured by refractometer and turbidity meter. The measurements were done in different times i.e. from 10 min to 60 min. This is to let the heavy particles to move down and accumulate at the bottom of the container. The results were as expected which had a gradually topographical map from low power at top layers into high power at bottom layers. There are many applications can be implemented of this study such as transport vehicles fuel meter, to measure the purity of tanks, and monitoring the fluids quality in pipes.

  7. Bivalve grazing can shape phytoplankton communities

    USGS Publications Warehouse

    Lucas, Lisa; Cloern, James E.; Thompson, Janet K.; Stacey, Mark T.; Koseff, Jeffrey K.

    2016-01-01

    The ability of bivalve filter feeders to limit phytoplankton biomass in shallow waters is well-documented, but the role of bivalves in shaping phytoplankton communities is not. The coupled effect of bivalve grazing at the sediment-water interface and sinking of phytoplankton cells to that bottom filtration zone could influence the relative biomass of sinking (diatoms) and non-sinking phytoplankton. Simulations with a pseudo-2D numerical model showed that benthic filter feeding can interact with sinking to alter diatom:non-diatom ratios. Cases with the smallest proportion of diatom biomass were those with the fastest sinking speeds and strongest bivalve grazing rates. Hydrodynamics modulated the coupled sinking-grazing influence on phytoplankton communities. For example, in simulations with persistent stratification, the non-sinking forms accumulated in the surface layer away from bottom grazers while the sinking forms dropped out of the surface layer toward bottom grazers. Tidal-scale stratification also influenced vertical gradients of the two groups in opposite ways. The model was applied to Suisun Bay, a low-salinity habitat of the San Francisco Bay system that was transformed by the introduction of the exotic clam Potamocorbula amurensis. Simulation results for this Bay were similar to (but more muted than) those for generic habitats, indicating that P. amurensis grazing could have caused a disproportionate loss of diatoms after its introduction. Our model simulations suggest bivalve grazing affects both phytoplankton biomass and community composition in shallow waters. We view these results as hypotheses to be tested with experiments and more complex modeling approaches.

  8. Impacts of the Changjiang diluted water on sinking processes of particulate organic matters in the East China Sea

    NASA Astrophysics Data System (ADS)

    Sukigara, Chiho; Mino, Yoshihisa; Tripathy, Sarat Chandra; Ishizaka, Joji; Matsuno, Takeshi

    2017-12-01

    Intensive surveys with repeated CTD and microstructure turbulent observations, water and sediments sampling as well as onboard incubation and sediment trap experiments were conducted to reveal the nitrogen budget in the center of the East China Sea (ECS) during July 2010 and 2011. Low salinity water (Changjiang Diluted Water, CDW) covered the study area in 2010, but not in 2011. Higher chlorophyll a (chl. a) concentration, primary productivity, and downward particle flux in the upper layer were observed in 2010 than those in 2011. Existence of the CDW resulted in a steep pycnocline and an associated subsurface chl. a maximum (SCM) layer directly beneath the CDW. From chemical analyses of particulate carbon and nitrogen contents and isotope ratios, it became apparent that the particles sunk out the euphotic zone in 2010 was primarily originated in the CDW layer and secondly in the SCM layer. Whereas, in 2011, sinking particles were originated in the surface layer but a part of them were decomposed in the bottom of pycnocline. Our findings indicate that the CDW would supply particles into the deep layer and contribute to the downward transport of materials and the efficiency of biological pump in the ECS.

  9. Seepage from an arctic shallow marine gas hydrate reservoir is insensitive to momentary ocean warming

    PubMed Central

    Hong, Wei-Li; Torres, Marta E.; Carroll, JoLynn; Crémière, Antoine; Panieri, Giuliana; Yao, Haoyi; Serov, Pavel

    2017-01-01

    Arctic gas hydrate reservoirs located in shallow water and proximal to the sediment-water interface are thought to be sensitive to bottom water warming that may trigger gas hydrate dissociation and the release of methane. Here, we evaluate bottom water temperature as a potential driver for hydrate dissociation and methane release from a recently discovered, gas-hydrate-bearing system south of Spitsbergen (Storfjordrenna, ∼380 m water depth). Modelling of the non-steady-state porewater profiles and observations of distinct layers of methane-derived authigenic carbonate nodules in the sediments indicate centurial to millennial methane emissions in the region. Results of temperature modelling suggest limited impact of short-term warming on gas hydrates deeper than a few metres in the sediments. We conclude that the ongoing and past methane emission episodes at the investigated sites are likely due to the episodic ventilation of deep reservoirs rather than warming-induced gas hydrate dissociation in this shallow water seep site. PMID:28589962

  10. Seepage from an arctic shallow marine gas hydrate reservoir is insensitive to momentary ocean warming

    DOE PAGES

    Hong, Wei-Li; Torres, Marta E.; Carroll, JoLynn; ...

    2017-06-07

    Arctic gas hydrate reservoirs located in shallow water and proximal to the sediment-water interface are thought to be sensitive to bottom water warming that may trigger gas hydrate dissociation and the release of methane. Here, we evaluate bottom water temperature as a potential driver for hydrate dissociation and methane release from a recently discovered, gas-hydrate-bearing system south of Spitsbergen (Storfjordrenna, ~380m water depth). Modelling of the non-steady-state porewater profiles and observations of distinct layers of methane-derived authigenic carbonate nodules in the sediments indicate centurial to millennial methane emissions in the region. The results of temperature modelling suggest limited impact ofmore » short-term warming on gas hydrates deeper than a few metres in the sediments. We conclude that the ongoing and past methane emission episodes at the investigated sites are likely due to the episodic ventilation of deep reservoirs rather than warming-induced gas hydrate dissociation in this shallow water seep site.« less

  11. Seepage from an arctic shallow marine gas hydrate reservoir is insensitive to momentary ocean warming.

    PubMed

    Hong, Wei-Li; Torres, Marta E; Carroll, JoLynn; Crémière, Antoine; Panieri, Giuliana; Yao, Haoyi; Serov, Pavel

    2017-06-07

    Arctic gas hydrate reservoirs located in shallow water and proximal to the sediment-water interface are thought to be sensitive to bottom water warming that may trigger gas hydrate dissociation and the release of methane. Here, we evaluate bottom water temperature as a potential driver for hydrate dissociation and methane release from a recently discovered, gas-hydrate-bearing system south of Spitsbergen (Storfjordrenna, ∼380 m water depth). Modelling of the non-steady-state porewater profiles and observations of distinct layers of methane-derived authigenic carbonate nodules in the sediments indicate centurial to millennial methane emissions in the region. Results of temperature modelling suggest limited impact of short-term warming on gas hydrates deeper than a few metres in the sediments. We conclude that the ongoing and past methane emission episodes at the investigated sites are likely due to the episodic ventilation of deep reservoirs rather than warming-induced gas hydrate dissociation in this shallow water seep site.

  12. Seepage from an arctic shallow marine gas hydrate reservoir is insensitive to momentary ocean warming

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hong, Wei-Li; Torres, Marta E.; Carroll, JoLynn

    Arctic gas hydrate reservoirs located in shallow water and proximal to the sediment-water interface are thought to be sensitive to bottom water warming that may trigger gas hydrate dissociation and the release of methane. Here, we evaluate bottom water temperature as a potential driver for hydrate dissociation and methane release from a recently discovered, gas-hydrate-bearing system south of Spitsbergen (Storfjordrenna, ~380m water depth). Modelling of the non-steady-state porewater profiles and observations of distinct layers of methane-derived authigenic carbonate nodules in the sediments indicate centurial to millennial methane emissions in the region. The results of temperature modelling suggest limited impact ofmore » short-term warming on gas hydrates deeper than a few metres in the sediments. We conclude that the ongoing and past methane emission episodes at the investigated sites are likely due to the episodic ventilation of deep reservoirs rather than warming-induced gas hydrate dissociation in this shallow water seep site.« less

  13. BiVO4/WO3/SnO2 Double-Heterojunction Photoanode with Enhanced Charge Separation and Visible-Transparency for Bias-Free Solar Water-Splitting with a Perovskite Solar Cell.

    PubMed

    Baek, Ji Hyun; Kim, Byeong Jo; Han, Gill Sang; Hwang, Sung Won; Kim, Dong Rip; Cho, In Sun; Jung, Hyun Suk

    2017-01-18

    Coupling dissimilar oxides in heterostructures allows the engineering of interfacial, optical, charge separation/transport and transfer properties of photoanodes for photoelectrochemical (PEC) water splitting. Here, we demonstrate a double-heterojunction concept based on a BiVO 4 /WO 3 /SnO 2 triple-layer planar heterojunction (TPH) photoanode, which shows simultaneous improvements in the charge transport (∼93% at 1.23 V vs RHE) and transmittance at longer wavelengths (>500 nm). The TPH photoanode was prepared by a facile solution method: a porous SnO 2 film was first deposited on a fluorine-doped tin oxide (FTO)/glass substrate followed by WO 3 deposition, leading to the formation of a double layer of dense WO 3 and a WO 3 /SnO 2 mixture at the bottom. Subsequently, a BiVO 4 nanoparticle film was deposited by spin coating. Importantly, the WO 3 /(WO 3 +SnO 2 ) composite bottom layer forms a disordered heterojunction, enabling intimate contact, lower interfacial resistance, and efficient charge transport/transfer. In addition, the top BiVO 4 /WO 3 heterojunction layer improves light absorption and charge separation. The resultant TPH photoanode shows greatly improved internal quantum efficiency (∼80%) and PEC water oxidation performance (∼3.1 mA/cm 2 at 1.23 V vs RHE) compared to the previously reported BiVO 4 /WO 3 photoanodes. The PEC performance was further improved by a reactive-ion etching treatment and CoO x electrocatalyst deposition. Finally, we demonstrated a bias-free and stable solar water-splitting by constructing a tandem PEC device with a perovskite solar cell (STH ∼3.5%).

  14. Mine Safety Detection System (MSDS)

    DTIC Science & Technology

    2012-09-01

    that comes to rest on the bottom in either sea lane will represent a navigation obstacle resulting in lane closure until the wreck can be cleared...order in which the depth layers are searched follows a rational that emulates the analogy of “testing the waters before diving in”. As the oil

  15. Microphytobenthos production potential and contribution to bottom layer oxygen dynamics on the inner Louisiana continental shelf

    EPA Science Inventory

    To investigate the relative importance of microphytobenthos (MPB) oxygen (O2) production on a river-dominated shelf, we made sediment core incubation measurements of MPB O2 production and sediment O2 consumption, and compared these to water-column measures of primary production ...

  16. Anthropogenic CO2 in a dense water formation area of the Mediterranean Sea

    NASA Astrophysics Data System (ADS)

    Ingrosso, Gianmarco; Bensi, Manuel; Cardin, Vanessa; Giani, Michele

    2017-05-01

    There is growing evidence that the on-going ocean acidification of the Mediterranean Sea could be favoured by its active overturning circulation. The areas of dense water formation are, indeed, preferential sites for atmospheric carbon dioxide absorption and through them the ocean acidification process can quickly propagate into the deep layers. In this study we estimated the concentration of anthropogenic CO2 (Cant) in the dense water formation areas of the middle and southern Adriatic Sea. Using the composite tracer TrOCA (Tracer combining Oxygen, inorganic Carbon, and total Alkalinity) and carbonate chemistry data collected throughout March 2013, our results revealed that a massive amount of Cant has invaded all the identified water masses. High Cant concentration was detected at the bottom layer of the Pomo Pit (middle Adriatic, 96.8±9.7 μmol kg-1) and Southern Adriatic Pit (SAP, 85.2±9.4 μmol kg-1), associated respectively with the presence of North Adriatic Dense Water (NAdDW) and Adriatic Dense Water (AdDW). This anthropogenic contamination was clearly linked to the dense water formation events, which govern strong CO2 flux from the atmosphere to the sea and the sinking of dense, CO2-rich surface waters to the deep sea. However, a very high Cant level (94.5±12.5 μmol kg-1) was also estimated at the intermediate layer, as a consequence of a recent vertical mixing that determined the physical and biogeochemical modification of the water of Levantine origin (i.e. Modified Levantine Intermediate Water, MLIW) and favoured the atmospheric CO2 intrusion. The penetration of Cant in the Adriatic Sea determined a significant pH reduction since the pre-industrial era (- 0.139±0.019 pH units on average). This estimation was very similar to the global Mediterranean Sea acidification, but it was again more pronounced at the bottom of the Pomo Pit, within the layer occupied by NAdDW (- 0.157±0.018 pH units), and at the intermediate layer of the recently formed MLIW (- 0.143±0.020 pH units). Our results indicate that the Adriatic Sea could potentially be one of the Mediterranean regions most affected by the ocean acidification and also demonstrate its active role in sequestering and storing Cant.

  17. The tufas of Pyramid Lake, Nevada

    USGS Publications Warehouse

    Benson, Larry V.

    2004-01-01

    Pyramid Lake is the site of some of the Earth's most spectacular tufa deposits. The Tufas are composed of calcium carbonate (CaCO3). The large tufa mounds, reef- and sheet-like tufas formed within Pyramid Lake, between 26,000 and 13,000 years (yr) ago, when the lake was part of pluvial Lake Lahontan. The mounds are composed of large interlocking spheres that contain multiple generations of a crystalline (thinolite) variety of tufa. Over time many of the mounds have fallen apart, exposing an internal network of tubes. The tubular structures are thought to have been created when springs discharged from the bottom of Pyramid Lake, supplying calcium that combined with carbonate dissolved in lake water to form the mounds. The reef- and sheet-like deposits contain pillow and pendant forms made up of a branching variety of tufa that often grades into dense layers or nodules. Dense layers of tufa also coat cobbles and boulders that were deposited in near-shore shallow-water areas. The thickest tufa deposits formed at lake-bottom sites of ground-water discharge and at overflow elevations1 where the lake was held at near-constant levels for long periods of time.

  18. Estimating hydrodynamic roughness in a wave-dominated environment with a high-resolution acoustic Doppler profiler

    USGS Publications Warehouse

    Lacy, J.R.; Sherwood, C.R.; Wilson, D.J.; Chisholm, T.A.; Gelfenbaum, G.R.

    2005-01-01

    Hydrodynamic roughness is a critical parameter for characterizing bottom drag in boundary layers, and it varies both spatially and temporally due to variation in grain size, bedforms, and saltating sediment. In this paper we investigate temporal variability in hydrodynamic roughness using velocity profiles in the bottom boundary layer measured with a high-resolution acoustic Doppler profiler (PCADP). The data were collected on the ebb-tidal delta off Grays Harbor, Washington, in a mean water depth of 9 m. Significant wave height ranged from 0.5 to 3 m. Bottom roughness has rarely been determined from hydrodynamic measurements under conditions such as these, where energetic waves and medium-to-fine sand produce small bedforms. Friction velocity due to current u*c and apparent bottom roughness z0a were determined from the PCADP burst mean velocity profiles using the law of the wall. Bottom roughness kB was estimated by applying the Grant-Madsen model for wave-current interaction iteratively until the model u*c converged with values determined from the data. The resulting kB values ranged over 3 orders of magnitude (10-1 to 10-4 m) and varied inversely with wave orbital diameter. This range of kB influences predicted bottom shear stress considerably, suggesting that the use of time-varying bottom roughness could significantly improve the accuracy of sediment transport models. Bedform height was estimated from kB and is consistent with both ripple heights predicted by empirical models and bedforms in sonar images collected during the experiment. Copyright 2005 by the American Geophysical Union.

  19. Hybrid Dye-Sensitized Solar Cells Consisting of Double Titania Layers for Harvesting Light with Wide Range of Wavelengths

    NASA Astrophysics Data System (ADS)

    Sadamasu, Kengo; Inoue, Takafumi; Ogomi, Yuhei; Pandey, Shyam S.; Hayase, Shuzi

    2011-02-01

    We report a hybrid dye-sensitized solar cell consisting of double titania layers (top and bottom layers) stained with two dyes. A top layer fabricated on a glass was mechanically pressed with a bottom layer fabricated on a glass cloth. The glass cloth acts as a supporter of a porous titania layer as well as a holder of electrolyte. The incident photon to current efficiency (IPCE) curve had two peaks corresponding to those of the two dyes, which demonstrates that electrons are collected from both the top and bottom layers.

  20. Assimilation of altimeter data into a quasigeostrophic ocean model using optimal interpolation and eofs

    NASA Astrophysics Data System (ADS)

    Rienecker, M. M.; Adamec, D.

    1995-01-01

    An ensemble of fraternal-twin experiments is used to assess the utility of optimal interpolation and model-based vertical empirical orthogonal functions (eofs) of streamfunction variability to assimilate satellite altimeter data into ocean models. Simulated altimeter data are assimilated into a basin-wide 3-layer quasi-geostrophic model with a horizontal grid spacing of 15 km. The effects of bottom topography are included and the model is forced by a wind stress curl distribution which is constant in time. The simulated data are extracted, along altimeter tracks with spatial and temporal characteristics of Geosat, from a reference model ocean with a slightly different climatology from that generated by the model used for assimilation. The use of vertical eofs determined from the model-generated streamfunction variability is shown to be effective in aiding the model's dynamical extrapolation of the surface information throughout the rest of the water column. After a single repeat cycle (17 days), the analysis errors are reduced markedly from the initial level, by 52% in the surface layer, 41% in the second layer and 11% in the bottom layer. The largest differences between the assimilation analysis and the reference ocean are found in the nonlinear regime of the mid-latitude jet in all layers. After 100 days of assimilation, the error in the upper two layers has been reduced by over 50% and that in the bottom layer by 38%. The essence of the method is that the eofs capture the statistics of the dynamical balances in the model and ensure that this balance is not inappropriately disturbed during the assimilation process. This statistical balance includes any potential vorticity homogeneity which may be associated with the eddy stirring by mid-latitude surface jets.

  1. Droplet-Based Production of Liposomes

    NASA Technical Reports Server (NTRS)

    Ackley, Donald E.; Forster, Anita

    2009-01-01

    A process for making monodisperse liposomes having lipid bilayer membranes involves fewer, simpler process steps than do related prior methods. First, a microfluidic, cross junction droplet generator is used to produce vesicles comprising aqueous solution droplets contained in single layer lipid membranes. The vesicles are collected in a lipid-solvent mix that is at most partially soluble in water and is less dense than is water. A layer of water is dispensed on top of the solvent. By virtue of the difference in densities, the water sinks to the bottom and the solvent floats to the top. The vesicles, which have almost the same density as that of water, become exchanged into the water instead of floating to the top. As there are excess lipids in the solvent solution, in order for the vesicles to remain in the water, the addition of a second lipid layer to each vesicle is energetically favored. The resulting lipid bilayers present the hydrophilic ends of the lipid molecules to both the inner and outer membrane surfaces. If lipids of a second kind are dissolved in the solvent in sufficient excess before use, then asymmetric liposomes may be formed.

  2. Rapid electrostatics-assisted layer-by-layer assembly of near-infrared-active colloidal photonic crystals.

    PubMed

    Askar, Khalid; Leo, Sin-Yen; Xu, Can; Liu, Danielle; Jiang, Peng

    2016-11-15

    Here we report a rapid and scalable bottom-up technique for layer-by-layer (LBL) assembling near-infrared-active colloidal photonic crystals consisting of large (⩾1μm) silica microspheres. By combining a new electrostatics-assisted colloidal transferring approach with spontaneous colloidal crystallization at an air/water interface, we have demonstrated that the crystal transfer speed of traditional Langmuir-Blodgett-based colloidal assembly technologies can be enhanced by nearly 2 orders of magnitude. Importantly, the crystalline quality of the resultant photonic crystals is not compromised by this rapid colloidal assembly approach. They exhibit thickness-dependent near-infrared stop bands and well-defined Fabry-Perot fringes in the specular transmission and reflection spectra, which match well with the theoretical calculations using a scalar-wave approximation model and Fabry-Perot analysis. This simple yet scalable bottom-up technology can significantly improve the throughput in assembling large-area, multilayer colloidal crystals, which are of great technological importance in a variety of optical and non-optical applications ranging from all-optical integrated circuits to tissue engineering. Copyright © 2016 Elsevier Inc. All rights reserved.

  3. Using a hybrid model to predict solute transfer from initially saturated soil into surface runoff with controlled drainage water.

    PubMed

    Tong, Juxiu; Hu, Bill X; Yang, Jinzhong; Zhu, Yan

    2016-06-01

    The mixing layer theory is not suitable for predicting solute transfer from initially saturated soil to surface runoff water under controlled drainage conditions. By coupling the mixing layer theory model with the numerical model Hydrus-1D, a hybrid solute transfer model has been proposed to predict soil solute transfer from an initially saturated soil into surface water, under controlled drainage water conditions. The model can also consider the increasing ponding water conditions on soil surface before surface runoff. The data of solute concentration in surface runoff and drainage water from a sand experiment is used as the reference experiment. The parameters for the water flow and solute transfer model and mixing layer depth under controlled drainage water condition are identified. Based on these identified parameters, the model is applied to another initially saturated sand experiment with constant and time-increasing mixing layer depth after surface runoff, under the controlled drainage water condition with lower drainage height at the bottom. The simulation results agree well with the observed data. Study results suggest that the hybrid model can accurately simulate the solute transfer from initially saturated soil into surface runoff under controlled drainage water condition. And it has been found that the prediction with increasing mixing layer depth is better than that with the constant one in the experiment with lower drainage condition. Since lower drainage condition and deeper ponded water depth result in later runoff start time, more solute sources in the mixing layer are needed for the surface water, and larger change rate results in the increasing mixing layer depth.

  4. Etude du comportement hydrogeologique de couvertures avec effet de barriere capillaire faites entierement de materiaux miniers

    NASA Astrophysics Data System (ADS)

    Kalonji, Alex Kabambi

    The acid mining drainage (AMD) generating mine sites must be restored to limit their long-term contamination of the environment. At the end of mining operations, covers with capillary barrier effects (CCBE), generally made of natural materials soils, are used as an oxygen barrier to isolate the tailings that generate acid mining drainage (AMD) from their immediate environment. Due to economic and social acceptability contraints and to the environmental impact of stripping (footprint) of natural soil pits, mining companies are increasingly interested in using non-acid generating waste rock as a substitute for natural soils as base materials to form capillary break layers in covers. The overall objective of this study was to evaluate the hydrogeological behaviour of CCBE made entirely of mining materials (desulphurized tailings from a desulphurization process and non-acid generating waste rock). The specific objectives of this project were : 1) to characterize the hydrogeological properties of waste rock (with truncated size) and desulphurized tailings; 2) to evaluate in laboratory instrumented columns the effectiveness of CCBE made entirely of mining materials; 3) to simulate the column tests using a 1D numerical code to model the fluid (water and gas) flow in the unsaturated media; and 4) to validate with 2D numerical modeling the ability to restore LaRonde tailings impoundment (Agnico Eagle Mines Limited) using a CCBE made of low-sulfide tailings and non-acid generating waste rock. To achieve the objectives, samples of waste rock were collected from Bousquet waste rock pile and tailings from the ore concentration plant before being pumped to the tailings impoundment. Desulphurized tailings with less than 2% S were produced in order to construct a non-reactive CCBE. After the physical, chemical, mineralogical and hydrogeotechnical characterization of cover materials, laboratory physical models of CCBC in instrumented columns were performed. Three configurations were tested. The first two columns had a different waste rock grain size (0-20 mm and 0-50 mm) in their lower coarse layers, and the tailings were introduced at a high solid percent, approximatively 74% (simulating mechanical deposition). The third column also had waste rock with particle size 0-50 mm in its bottom coarse layer, but with tailings placed a lower solid percent, approximatively 55% (simulating hydraulic deposition). The particle size of the coarse waste rock in the top layers was set at 0-50 mm for all three columns. Several cycles of wetting drainage in the three columns were performed. The results of these laboratory investigations in terms of volumetric water content and suction profiles confirm the potential of non-acid generating waste rock to be used in the capillary break layers of CCBE. To assess the long-term performance, several scenarios of numerical modeling were performed using Vadose/W 2007 numerical codes, by Geoslope int. A variation of the depth of the water table and natural and extreme climatic conditions were considered in this parametric study. The results of these predictions confirmed the long-term effectiveness of covers with mine waste rock in capillary break layers. The effectiveness was evaluated in terms of oxygen flux at the interface between the moisture-retaining layer (MRL) and the bottom capillary break layer. Under natural and extreme climatic conditions (two months without infiltration), and a variation of the depth of the water table level from 2 to 6 m, cumulative oxygen flux over a one year period varied between 10.6 and 97.5 g/m 2/year. For extreme climatic conditions, and for the same variation of the depth of the water table, the oxygen flux varied between 14.3 and 117.9 g/m2/year. The highest oxygen flux (117 g/m2/year) was obtained for a water table depth of 6 m under extreme climatic conditions. The influence of the particle size contrast between the water retention layer and the bottom capillary break layer on the oxygen flux was further highlighted using relatively fine and coarse sand in the coarse bottom layer. The numerical modeling results obtained with the coarse sand were almost similar to those obtained with waste rock. In the absence of the strong contrast (when the relatively fine sand was used), the water retention layer was drained and the oxygen flux which reached at the bottom of this layer increased considerably. The water table depth, the grain size, and the hydraulic contrast between the MRL and the bottom capillary break layer (CBL) proved to be the key parameters of the simulated model. In field conditions, CCBE are often inclined, and that this inclination can affect the performance of the cover to control the migration of oxygen. 2D modeling was also performed. The numerical model was built to represent approximatively the case of one of the dams of LaRonde tailings impoundment. Preliminary results show that CCBE made entirely of mining materials are effective even when placed over slopes. The degree of saturation of the two slopes in the numerical model was higher than 85%. The influence of the slope has not significantly affected yet the performance of the cover for the model studied in this thesis. The cumulative oxygen flux over one year at the bottom of the MRL (for horizontal distance of 182 m of the numerical model) are 4031.3g (22.1 g/m2/year) and 4617.7g (25.3 g/m2/year) for natural and extreme climatic conditions respectively. This study confirms that waste rocks have good potential to be used as capillary break materials in the configuration of such CCBE. Thereby, it is suggested that the option of using only mining materials be included in the analysis of the optimal mode of mine reclamation. This project also suggests that good management of the tailings and waste rock produced during mining operations will provide the materials which could then be used to restore the site. More research is recommended to further investigate this reclamation option through field experimental cells. If further research validates the laboratory results at the intermediate scale, the use of mining materials would be considered as an effective option for CCBE used to control post-closure pollution. This scenario could reduce the construction costs while promoting the social acceptability of mining projects by reducing the use of natural soils.

  5. Linking interannual variability in shelf bottom water properties to the California Undercurrent and local processes in the Pacific Northwest

    NASA Astrophysics Data System (ADS)

    Stone, H. B.; Banas, N. S.; Hickey, B. M.; MacCready, P.

    2016-02-01

    The Pacific Northwest coast is an unusually productive area with a strong river influence and highly variable upwelling-favorable and downwelling-favorable winds, but recent trends in hypoxia and ocean acidification in this region are troubling to both scientists and the general public. A new ROMS hindcast model of this region makes possible a study of interannual variability. This study of the interannual temperature and salinity variability on the Pacific Northwest coast is conducted using a coastal hindcast model (43°N - 50°N) spanning 2002-2009 from the University of Washington Coastal Modeling Group, with a resolution of 1.5 km over the shelf and slope. Analysis of hindcast model results was used to assess the relative importance of source water variability, including the poleward California Undercurrent, local and remote wind forcing, winter wind-driven mixing, and river influence in explaining the interannual variations in the shelf bottom layer (40 - 80 m depth, 10 m thick) and over the slope (150 - 250 m depth, <100 km from shelf break) at each latitude within the model domain. Characterized through tracking of the fraction of Pacific Equatorial Water (PEW) relative to Pacific Subarctic Upper Water (PSUW) present on the slope, slope water properties at all latitudes varied little throughout the time series, with the largest variability due to patterns of large north-south advection of water masses over the slope. Over the time series, the standard deviation of slope temperature was 0.09 ˚C, while slope salinity standard deviation was 0.02 psu. Results suggest that shelf bottom water interannual variability is not driven primarily by interannual variability in slope water as shelf bottom water temperature and salinity vary nearly 10 times more than those over the slope. Instead, interannual variability in shelf bottom water properties is likely driven by other processes, such as local and remote wind forcing, and winter wind-driven mixing. The relative contributions of these processes to interannual variability in shelf bottom water properties will be addressed. Overall, these results highlight the importance of shelf processes relative to large-scale influences on the interannual timescale in particular. Implications for variability in hypoxia and ocean acidification impacts will be discussed.

  6. Dynamics of the Sediment Plume Over the Yangtze Bank in the Yellow and East China Seas

    NASA Astrophysics Data System (ADS)

    Luo, Zhifa; Zhu, Jianrong; Wu, Hui; Li, Xiangyu

    2017-12-01

    A distinct sediment plume exists over the Yangtze Bank in the Yellow and East China Seas (YECS) in winter, but it disappears in summer. Based on satellite color images, there are two controversial viewpoints about the formation mechanism for the sediment plume. One viewpoint is that the sediment plume forms because of cross-shelf sediment advection of highly turbid water along the Jiangsu coast. The other viewpoint is that the formation is caused by local bottom sediment resuspension and diffused to the surface layer through vertical turbulent mixing. The dynamic mechanism of the sediment plume formation has been unclear until now. This issue was explored by using a numerical sediment model in the present paper. Observed wave, current, and sediment data from 29 December 2016 to 16 January 2017 were collected near the Jiangsu coast and used to validate the model. The results indicated that the model can reproduce the hydrodynamic and sediment processes. Numerical experiments showed that the bottom sediment could be suspended by the bottom shear stress and diffuse to the surface layer by vertical mixing in winter; however, the upward diffusion is restricted by the strong stratification in summer. The sediment plume is generated locally due to bottom sediment resuspension primarily via tide-induced bottom shear stress rather than by cross-shelf sediment advection over the Yangtze Bank.

  7. [Earlier steps of the soil ecosystem evolution].

    PubMed

    Ponomarenko, A G

    2013-01-01

    Fossil soils are known since early Praecambrian, long before the occurrence of higher terrestrial plants on the Earth. Primeval biocoenoses on the land and in continental water bodies were floating and bottom prokaryotic mats and films which produced the majority of biomass and with regard to specific productivity were not inferior to any other photosynthetics. Before the occurrence of higher plants, erosion was very strong, resulting in flat relief, absence of permanent streams, domination of wandering rivers and surface runoff; all water bodies were muddy. When floods occurred, which was quite so often, clay particles of muddy water streams isolated bottom-mats from the light and then their considerable part perished. The result was not soil as a uniform bioinert body but rather a "puff pie" consisted of layers of unoxidized charred organic matter and clay prolayers. The burial of unoxidized organic matter contributed to enrichment of the atmosphere with oxygen. Worms and arthropods, which came out to the land and continental water bodies during Cambrian period, mixed up the organic matter with mineral components strengthening the process of soil forming considerably. Soils of the modern type appeared after higher plants expanded in Devonian and displaced bottom-mats in shallow waters. The soil fauna that existed at this time was not so different from the modern one with regard to its evolutionary level.

  8. The Bottom Boundary Layer.

    PubMed

    Trowbridge, John H; Lentz, Steven J

    2018-01-03

    The oceanic bottom boundary layer extracts energy and momentum from the overlying flow, mediates the fate of near-bottom substances, and generates bedforms that retard the flow and affect benthic processes. The bottom boundary layer is forced by winds, waves, tides, and buoyancy and is influenced by surface waves, internal waves, and stratification by heat, salt, and suspended sediments. This review focuses on the coastal ocean. The main points are that (a) classical turbulence concepts and modern turbulence parameterizations provide accurate representations of the structure and turbulent fluxes under conditions in which the underlying assumptions hold, (b) modern sensors and analyses enable high-quality direct or near-direct measurements of the turbulent fluxes and dissipation rates, and (c) the remaining challenges include the interaction of waves and currents with the erodible seabed, the impact of layer-scale two- and three-dimensional instabilities, and the role of the bottom boundary layer in shelf-slope exchange.

  9. The Bottom Boundary Layer

    NASA Astrophysics Data System (ADS)

    Trowbridge, John H.; Lentz, Steven J.

    2018-01-01

    The oceanic bottom boundary layer extracts energy and momentum from the overlying flow, mediates the fate of near-bottom substances, and generates bedforms that retard the flow and affect benthic processes. The bottom boundary layer is forced by winds, waves, tides, and buoyancy and is influenced by surface waves, internal waves, and stratification by heat, salt, and suspended sediments. This review focuses on the coastal ocean. The main points are that (a) classical turbulence concepts and modern turbulence parameterizations provide accurate representations of the structure and turbulent fluxes under conditions in which the underlying assumptions hold, (b) modern sensors and analyses enable high-quality direct or near-direct measurements of the turbulent fluxes and dissipation rates, and (c) the remaining challenges include the interaction of waves and currents with the erodible seabed, the impact of layer-scale two- and three-dimensional instabilities, and the role of the bottom boundary layer in shelf-slope exchange.

  10. Chembio extraction on a chip by nanoliter droplet ejection.

    PubMed

    Yu, Hongyu; Kwon, Jae Wan; Kim, Eun Sok

    2005-03-01

    This paper describes a novel liquid separation technique for chembio extraction by an ultrasonic nanoliter-liquid-droplet ejector built on a PZT sheet. This technique extracts material from an aqueous two-phase system (ATPS) in a precise amount through digital control of the number of nanoliter droplets, without any mixing between the two liquids in the ATPS. The ultrasonic droplet ejector uses an acoustic streaming effect produced by an acoustic beam focused on the liquid surface, and ejects liquid droplets only from the liquid surface without disturbing most of the liquid below the surface. This unique characteristic of the focused acoustic beam is perfect (1) for separating a top-layer liquid (from the bulk of liquid) that contains particles of interest or (2) for recovering a top-layer liquid that has different phase from a bottom-layer liquid. Three kinds of liquid extraction are demonstrated with the ultrasonic droplet ejector: (1) 16 microl of top layer in Dextran-polyethylene glycol-water ATPS (aqueous two-phase system) is recovered within 20 s; (2) micron sized particles that float on water surface are ejected out with water droplets; and (3) oil layer on top of water is separated out.

  11. Physical modelling of LNG rollover in a depressurized container filled with water

    NASA Astrophysics Data System (ADS)

    Maksim, Dadonau; Denissenko, Petr; Hubert, Antoine; Dembele, Siaka; Wen, Jennifer

    2015-11-01

    Stable density stratification of multi-component Liquefied Natural Gas causes it to form distinct layers, with upper layer having a higher fraction of the lighter components. Heat flux through the walls and base of the container results in buoyancy-driven convection accompanied by heat and mass transfer between the layers. The equilibration of densities of the top and bottom layers, normally caused by the preferential evaporation of Nitrogen, may induce an imbalance in the system and trigger a rapid mixing process, so-called rollover. Numerical simulation of the rollover is complicated and codes require validation. Physical modelling of the phenomenon has been performed in a water-filled depressurized vessel. Reducing gas pressure in the container to levels comparable to the hydrostatic pressure in the water column allows modelling of tens of meters industrial reservoirs using a 20 cm laboratory setup. Additionally, it allows to model superheating of the base fluid layer at temperatures close the room temperature. Flow visualizations and parametric studies are presented. Results are related to outcomes of numerical modelling.

  12. A Method for a Multi-Platform Approach to Generate Gridded Surface Evaporation

    NASA Astrophysics Data System (ADS)

    Badger, A.; Livneh, B.; Small, E. E.; Abolafia-Rosenzweig, R.

    2017-12-01

    Evapotranspiration is an integral component of the surface water balance. While there are many estimates of evapotranspiration, there are fewer estimates that partition evapotranspiration into evaporation and transpiration components. This study aims to generate a CONUS-scale, observationally-based soil evaporation dataset by using the time difference of surface soil moisture by Soil Moisture Active Passive (SMAP) satellite with adjustments for transpiration and a bottom flux out of the surface layer. In concert with SMAP, the Moderate-Resolution Imaging Spectroradiometer (MODIS) satellite, North American Land Data Assimilation Systems (NLDAS) and the Hydrus-1D model are used to fully analyze the surface water balance. A biome specific estimate of the total terrestrial ET is calculated through a variation of the Penman-Monteith equation with NLDAS forcing and NLDAS Noah Model output for meteorological variables. A root density restriction and SMAP-based soil moisture restriction are applied to obtain terrestrial transpiration estimates. By forcing Hydrus-1D with NLDAS meteorology and our terrestrial transpiration estimates, an estimate of the flux between the soil surface and root zone layers (qbot) will dictate the proportion of water that is available for soil evaporation. After constraining transpiration and the bottom flux from the surface layer, we estimate soil evaporation as the residual of the surface water balance. Application of this method at Fluxnet sites shows soil evaporation estimates of approximately 0­3 mm/day and less than ET estimates. Expanding this methodology to produce a gridded product for CONUS, and eventually a global-scale product, will enable a better understanding of water balance processes and contribute a dataset to validate land-surface model's surface flux processes.

  13. Bottom friction optimization for a better barotropic tide modelling

    NASA Astrophysics Data System (ADS)

    Boutet, Martial; Lathuilière, Cyril; Son Hoang, Hong; Baraille, Rémy

    2015-04-01

    At a regional scale, barotropic tides are the dominant source of variability of currents and water heights. A precise representation of these processes is essential because of their great impacts on human activities (submersion risks, marine renewable energies, ...). Identified sources of error for tide modelling at a regional scale are the followings: bathymetry, boundary forcing and dissipation due to bottom friction. Nevertheless, bathymetric databases are nowadays known with a good accuracy, especially over shelves, and global tide models performances are better than ever. The most promising improvement is thus the bottom friction representation. The method used to estimate bottom friction is the simultaneous perturbation stochastic approximation (SPSA) which consists in the approximation of the gradient based on a fixed number of cost function measurements, regardless of the dimension of the vector to be estimated. Indeed, each cost function measurement is obtained by randomly perturbing every component of the parameter vector. An important feature of SPSA is its relative ease of implementation. In particular, the method does not require the development of tangent linear and adjoint version of the circulation model. Experiments are carried out to estimate bottom friction with the HYbrid Coordinate Ocean Model (HYCOM) in barotropic mode (one isopycnal layer). The study area is the Northeastern Atlantic margin which is characterized by strong currents and an intense dissipation. Bottom friction is parameterized with a quadratic term and friction coefficient is computed with the water height and the bottom roughness. The latter parameter is the one to be estimated. Assimilated data are the available tide gauge observations. First, the bottom roughness is estimated taking into account bottom sediment natures and bathymetric ranges. Then, it is estimated with geographical degrees of freedom. Finally, the impact of the estimation of a mixed quadratic/linear friction is evaluated.

  14. Factors controlling bacteria and protists in selected Mazurian eutrophic lakes (North-Eastern Poland) during spring

    PubMed Central

    2013-01-01

    Background The bottom-up (food resources) and top-down (grazing pressure) controls, with other environmental parameters (water temperature, pH) are the main factors regulating the abundance and structure of microbial communities in aquatic ecosystems. It is still not definitively decided which of the two control mechanisms is more important. The significance of bottom-up versus top-down controls may alter with lake productivity and season. In oligo- and/or mesotrophic environments, the bottom-up control is mostly important in regulating bacterial abundances, while in eutrophic systems, the top-down control may be more significant. Results The abundance of bacteria, heterotrophic (HNF) and autotrophic (ANF) nanoflagellates and ciliates, as well as bacterial production (BP) and metabolically active cells of bacteria (CTC, NuCC, EST) were studied in eutrophic lakes (Mazurian Lake District, Poland) during spring. The studied lakes were characterized by high nanoflagellate (mean 17.36 ± 8.57 × 103 cells ml-1) and ciliate abundances (mean 59.9 ± 22.4 ind. ml-1) that were higher in the euphotic zone than in the bottom waters, with relatively low bacterial densities (4.76 ± 2.08 × 106 cells ml-1) that were lower in the euphotic zone compared to the profundal zone. Oligotrichida (Rimostrombidium spp.), Prostomatida (Urotricha spp.) and Scuticociliatida (Histiobalantium bodamicum) dominated in the euphotic zone, whereas oligotrichs Tintinnidium sp. and prostomatids Urotricha spp. were most numerous in the bottom waters. Among the staining methods used to examine bacterial cellular metabolic activity, the lowest percentage of active cells was recorded with the CTC (1.5–15.4%) and EST (2.7–14.2%) assay in contrast to the NuCC (28.8–97.3%) method. Conclusions In the euphotic zone, the bottom-up factors (TP and DOC concentrations) played a more important role than top-down control (grazing by protists) in regulating bacterial numbers and activity. None of the single analyzed factors controlled bacterial abundance in the bottom waters. The results of this study suggest that both control mechanisms, bottom-up and top-down, simultaneously regulated bacterial community and their activity in the profundal zone of the studied lakes during spring. In both lake water layers, food availability (algae, nanoflagellates) was probably the major factor determining ciliate abundance and their composition. In the bottom waters, both groups of protists appeared to be also influenced by oxygen, temperature, and total phosphorus. PMID:23566491

  15. Microplastics in the Baltic Sea water: fibers everywhere.

    NASA Astrophysics Data System (ADS)

    Khatmullina, Lilia; Bagaev, Andrey; Chubarenko, Irina

    2017-04-01

    Presence of thin synthetic fibres (microfibres, tens of micrometres in diameter) in the surface waters and sediments is documented in different studies; however, the data on their exact abundances in the marine environment are commonly not presented owing to the shortcomings of the sampling procedure and general absence of well-established methodology for microplastics data collection. Nevertheless, we made an attempt to qualitatively analyse the amounts of microplastic fibres in the water column of the Baltic Sea. Water samples acquired during 6 cruises over the Baltic Sea Proper in 2015-2016 were filtered using 174 μm filters, which were subsequently analysed by microscope. From the total of 95 examined filters, 63% contained fibres. They were identified by colour and the reaction to the mechanical action of a thin needle: justification of anthropogenic origin was considered to be enough; any questionable objects were discarded. Fibres comprise more than 90% of the whole microplastic particles found in the near-bottom layers in the coastal zone and around 24% of microplastics in the surface and intermediate waters, with mean concentrations of 0.71 and 0.07 fibres per litre, respectively. Although the methodology still requires a lot of enhancement, even the preliminary results indicate ubiquitous distribution of the microfibres in the water column of the Baltic Sea with surface and bottom layers revealing higher abundances of microfibres in comparison with intermediate layers, and open-sea waters being less contaminated than the coastal ones. Apart from enhancing the sampling technics, we consider that it is crucial to understand principal physical features of fibers behavior in the marine environment (e.g., settling, entrainment by currents), as it would provide an opportunity to parameterize their transport and further on to model distribution of fibers in the water column. The research is supported by the Russian Science Foundation grant number 15-17-10020.

  16. Dissolved methane in the residual basins of the Aral Sea

    NASA Astrophysics Data System (ADS)

    Izhitskaya, Elena; Zavialov, Peter; Egorov, Alexander

    2017-04-01

    The state of the Aral Sea has changed significantly since the second half of the 20th century. Due to the level decline the present-day sea consists of the several water bodies: the Large Aral Sea, the Small Aral Sea and Lake Tshchebas. Water balance peculiarities of each basin caused the differences in physical, chemical and biological structure of the ecosystem. Severe salinization of the Large Aral resulted in the increase of water stratification and formation of the anoxic conditions in the bottom layer. According to the field survey of 2002 [Zavialov et al., 2003; Friedrich, Oberhansli, 2004], hydrogen sulfide was detected in the bottom layer of the Large Aral Sea for the first time. Methane formation is the next reaction after sulfate reduction within process of sequential oxidation of organic matter [Break, 1974]. Thus, methane is an important indicator of biogeochemical processes in natural water environments. Besides due to high greenhouse activity of methane study of its emission to the atmosphere is essential for solution of climatological problems [Bazhin, 2000]. The presented study aims to the evaluation of methane dissolved in waters of the Aral region. Measurements of the gas concentration were carried out on surface and vertical profiles, as well as on point stations in 2012, 2013, 2015 and 2016 years in different parts of the sea. Water samples were analyzed by the head-space method with further gas chromatographic determination of methane concentration [Bolshakov, Egorov, 1987]. According to the obtained data, dissolved methane content in the surface waters of the residual basins of the Aral Sea ranges from 12 to 234 nM/l. One of the main results of the research is detection of intensive methane increase in the lower water layer of the Large Aral to 17014 nM/l in central part and to 147316 nM/l in the Chernyshev Bay.

  17. Properties of coarse particles in suspended particulate matter of the North Yellow Sea during summer

    NASA Astrophysics Data System (ADS)

    Zhang, Kainan; Wang, Zhenyan; Li, Wenjian; Yan, Jun

    2018-01-01

    Fine particles in seawater commonly form large porous aggregates. Aggregate density and settling velocity determine the behavior of this suspended particulate matter (SPM) within the water column. However, few studies of aggregate particles over a continental shelf have been undertaken. In our case study, properties of aggregate particles, including size and composition, over the continental shelf of the North Yellow Sea were investigated. During a scientific cruise in July 2016, in situ effective particle size distributions of SPM at 10 stations were measured, while temperature and turbidity measurements and samples of water were obtained from surface, middle, and bottom layers. Dispersed and inorganic particle size distributions were determined in the laboratory. The in situ SPM was divided into (1) small particles (<32 μm), (2) medium particles (32-256 μm) and (3) large particles (>256 μm). Large particles and medium particles dominated the total volume concentrations (VCs) of in situ SPM. After dispersion, the VCs of medium particles decreased to low values (<0.1 μL/L). The VCs of large particles in the surface and middle layers also decreased markedly, although they had higher peak values (0.1-1 μL/L). This suggests that almost all in situ medium particles and some large particles were aggregated, while other large particles were single particles. Correlation analysis showed that primary particles <32 μm influenced the formation of these aggregates. Microscopic examination revealed that these aggregates consisted of both organic and inorganic fine particles, while large particles were mucus-bound organic aggregates or individual plankton. The vertical distribution of coarser particles was clearly related to water stratification. Generally, medium aggregate particles were dominant in SPM of the bottom layer. A thermocline blocked resuspension of fine material into upper layers, yielding low VCs of medium-sized aggregate particles in the surface layer. Abundant large biogenic particles were present in both surface and middle layers.

  18. Bottom boundary layer forced by finite amplitude long and short surface waves motions

    NASA Astrophysics Data System (ADS)

    Elsafty, H.; Lynett, P.

    2018-04-01

    A multiple-scale perturbation approach is implemented to solve the Navier-Stokes equations while including bottom boundary layer effects under a single wave and under two interacting waves. In this approach, fluid velocities and the pressure field are decomposed into two components: a potential component and a rotational component. In this study, the two components are exist throughout the entire water column and each is scaled with appropriate length and time scales. A one-way coupling between the two components is implemented. The potential component is assumed to be known analytically or numerically a prior, and the rotational component is forced by the potential component. Through order of magnitude analysis, it is found that the leading-order coupling between the two components occurs through the vertical convective acceleration. It is shown that this coupling plays an important role in the bottom boundary layer behavior. Its effect on the results is discussed for different wave-forcing conditions: purely harmonic forcing and impurely harmonic forcing. The approach is then applied to derive the governing equations for the bottom boundary layer developed under two interacting wave motions. Both motions-the shorter and the longer wave-are decomposed into two components, potential and rotational, as it is done in the single wave. Test cases are presented wherein two different wave forcings are simulated: (1) two periodic oscillatory motions and (2) short waves interacting with a solitary wave. The analysis of the two periodic motions indicates that nonlinear effects in the rotational solution may be significant even though nonlinear effects are negligible in the potential forcing. The local differences in the rotational velocity due to the nonlinear vertical convection coupling term are found to be on the order of 30% of the maximum boundary layer velocity for the cases simulated in this paper. This difference is expected to increase with the increase in wave nonlinearity.

  19. Spin currents and spin-orbit torques in ferromagnetic trilayers.

    PubMed

    Baek, Seung-Heon C; Amin, Vivek P; Oh, Young-Wan; Go, Gyungchoon; Lee, Seung-Jae; Lee, Geun-Hee; Kim, Kab-Jin; Stiles, M D; Park, Byong-Guk; Lee, Kyung-Jin

    2018-06-01

    Magnetic torques generated through spin-orbit coupling 1-8 promise energy-efficient spintronic devices. For applications, it is important that these torques switch films with perpendicular magnetizations without an external magnetic field 9-14 . One suggested approach 15 to enable such switching uses magnetic trilayers in which the torque on the top magnetic layer can be manipulated by changing the magnetization of the bottom layer. Spin currents generated in the bottom magnetic layer or its interfaces transit the spacer layer and exert a torque on the top magnetization. Here we demonstrate field-free switching in such structures and show that its dependence on the bottom-layer magnetization is not consistent with the anticipated bulk effects 15 . We describe a mechanism for spin-current generation 16,17 at the interface between the bottom layer and the spacer layer, which gives torques that are consistent with the measured magnetization dependence. This other-layer-generated spin-orbit torque is relevant to energy-efficient control of spintronic devices.

  20. In situ nitrification rates and activity of present nitrifiers in the bottom water layer of two Baltic coastal zones affected by different riverine nutrient loads

    NASA Astrophysics Data System (ADS)

    Bartl, I.; Münster Happel, E.; Riemann, L.; Voss, M.

    2016-02-01

    Baltic coastal zones are among the most eutrophied in the world receiving high loads of nitrogen from riverine inputs. However, not only the loads but also the internal dynamics in coastal zones might have positive feedback on eutrophication through efficient remineralisation of organic material in the bottom water. Therefore, we studied nitrification, which is a vital remineralisation process, near the seafloor along with the community of nitrifying microorganisms. We hypothesize that a high nutrient and organic matter load leads to elevated ammonium concentrations in coastal waters and thus stimulates nitrification rates and alters the nitrifying community. Here we present results from 3 cruises combining nitrification rate measurements by 15N-incubations with sequence-based analyses of present and active nitrifiers in the bottom water of two sites in the Baltic Sea receiving different nutrient loads. The first results from the Bonus projects COCOA and BLUEPRINT indicate an increase of nitrification rates with depth as well as distance from the river mouth. In situ rates in the bottom water of the nutrient rich Vistula plume range from 53 to 197 nmol L-1 d-1 and from 10 to 646 nmol L-1 d-1 during winter and summer, respectively. In the nutrient poor Öre estuary rates increased significantly by 11 nmol L-1 d-1 from the river mouth to the outermost station. The relationship between nitrification rates, nitrifiers and trophic state of the coastal zone shall be discussed.

  1. Benthic nitrogen turnover processes in coastal sediments at the Danube Delta

    NASA Astrophysics Data System (ADS)

    Bratek, Alexander; Dähnke, Kirstin; Neumann, Andreas; Möbius, Jürgen; Graff, Florian

    2017-04-01

    The Black Sea Shelf has been exposed to strong anthropogenic pressures from intense fisheries and high nutrient inputs and eutrophication over the past decades. In the light of decreasing riverine nutrient loads and improving nutrient status in the water column, nutrient regeneration in sediments and biological N-turnover in the Danube Delta Front have an important effect on nutrient loads in the shelf region. In May 2016 we determined pore water nutrient profiles in the Danube River Delta-Black Sea transition zone, aiming to assess N-regeneration and elimination based on nutrient profiles and stable N- isotope changes (nitrate and ammonium) in surface water masses and in pore water. We aimed to investigate the magnitude and isotope values of sedimentary NH4+ and NO3- and their impact on the current N-budget in Black Sea Shelf water. Based on changes in the stable isotope ratios of NO3- and NH4+, we aimed to differentiate diffusion and active processing of ammonium as well as nitrate sources and sinks in bottom water. First results show that the concentration of NH4+ in pore water increases with depth, reaching up to 1500 µM in deeper sediment layers. We find indications for high fluxes of ammonium to the overlying water, while stable isotope profiles of ammonium suggest that further processing, apart from mere diffusion, acts on the pore water ammonium pool. Nitrate concentration and stable isotope profiles show rapid consumption in deeper anoxic sediment layers, but also suggest that nitrate regeneration in bottom water increases the dissolved nitrate pool. Overall, the isotope and concentration data of pore water ammonium clearly mirror a combination of turnover processes and diffusion.

  2. Device for thermal transfer and power generation

    DOEpatents

    Weaver, Stanton Earl [Northville, NY; Arik, Mehmet [Niskayuna, NY

    2011-04-19

    A system is provided. The system includes a device that includes top and bottom thermally conductive substrates positioned opposite to one another, wherein a top surface of the bottom thermally conductive substrate is substantially atomically flat and a thermal blocking layer disposed between the top and bottom thermally conductive substrates. The device also includes top and bottom electrodes separated from one another between the top and bottom thermally conductive substrates to define a tunneling path, wherein the top electrode is disposed on the thermal blocking layer and the bottom electrode is disposed on the bottom thermally conductive substrate.

  3. Nutrient Dynamics in the Northern South China Sea Shelf-sea (NoSoCS)

    NASA Astrophysics Data System (ADS)

    Wong, G. T.; Guo, X.

    2011-12-01

    The Northern South China Sea Shelf-sea (NoSoCS) is situated in the sub-tropics along the southern Chinese coast between the southern end of the Taiwan Strait and the Hainan Island. Samples were collected in four cross-shelf transects in summer, 2010 and two cross-shelf transects in winter, 2011 in this Shelf-sea. The shelf may be sub-divided into the inner shelf (<40 m, low water temperature, high chlorophyll concentration), the middle shelf (50-80 m), and the outer shelf (90-120 m, high water temperature, low nutrient and chlorophyll concentrations). The mixed layer depth and the top of the nutricline depth (at ~30 m in the summer and ~70 m in the winter) were shallower than the shelf break depth (~120 m) in both seasons. The relatively nutrient-rich upper nutricline water (>1 μM in NO3- and >0.1 μM in soluble reactive phosphate) stretched across the shelf at least to the middle shelf. Thus, vertical mixing, even to relatively shallow depths, on the shelf may supply nutrients to and play a critical role in determining the primary production in the mixed layer. At least three such processes were observed. Through the year, internal waves of various strengths generated at the Luzon Strait propagated westward along the bottom of the mixed layer and dissipated along the middle and outer shelf. The effects of these waves were especially conspicuous north of the Dongsha Atoll and their action enhances vertical mixing. In the summer, upwelling occurred in the inner/middle shelf off Dongshan in response to the along shore southwest monsoon and the topographic forcing by the ridge extending offshore from Dongshan to the Taiwan Bank. In the winter, surface cooling and the strong northeast monsoon led to complete overturn in the shelf. The maximum density, reaching 24.6, in the surface waters was found offshore in the inner and middle shelf. This density was equivalent to the density of the water at >100 m offshore. As a result, this dense water also appeared as a layer of bottom water that extended across the shelf to the shelf edge.

  4. Carbon budget of sea-ice algae in spring: Evidence of a significant transfer to zooplankton grazers

    NASA Astrophysics Data System (ADS)

    Michel, C.; Legendre, L.; Ingram, R. G.; Gosselin, M.; Levasseur, M.

    1996-08-01

    The fate of ice-bottom algae, before and after release from the first-year sea ice into the water column, was assessed during the period of ice-algal growth and decline in Resolute Passage (Canadian Arctic). During spring 1992 (from April to June), algae in the bottom ice layer and those suspended and sinking in the upper water column (top 15 m) were sampled approximately every 4 days. Ice-bottom chlorophyll a reached a maximum concentration of 160 mg m-2 in mid-May, after which it decreased to lower values. In the water column, chlorophyll a concentrations were low until the period of ice-algal decline (˜0.1 mg m-3), with most biomass in the <5-μm fraction. In both the suspended and sinking material, large increases of algal biomass occurred at the beginning of June, following the release of ice-algae into the water column. The input of ice-algal derived carbon to the upper water column and the proportions exported through sinking or remaining in suspension were assessed using a carbon budget for the two periods of ice-algal growth and decline. For each period the output terms closely balanced the input. The carbon budget showed that most of the biomass introduced into the upper water column remained suspended (>65% of total export) and that ice-algae were ingested by under-ice grazers after release from the ice. These results stress the importance of ice algae for pelagic consumers during the early stages of ice melt and show that the transfer of ice algae to higher trophic levels extends beyond the period of maximum algal production in the ice bottom.

  5. A Field Investigation of Water and Salt Movement in Permafrost and the Active Layer

    DTIC Science & Technology

    1993-02-01

    in the submerged continental shelves of the Arctic and Antarctic land masses where pore water salinities of shelf sediments may exceed that of the...thawed sediments would have wanned at all depths, and permafrost would have started to thaw from both the top and the bottom. Eventually, gas...exploration wells (Osterkamp at al., 1985). Destabilization of gas hydrates (by warming the sediments in the continental shelves) during periods of high

  6. Microbial community analysis and bioclogging identification in a Managed Artificial Recharge system.

    NASA Astrophysics Data System (ADS)

    Barba, Carme; Folch, Albert; Gaju, Núria; Martínez-Alonso, Maira; Grau, Alba; Sanchez-Vila, Xavier

    2015-04-01

    Managed Artificial Recharge (MAR) is a well-known technique that aims at increasing the aquifer resources while managing its quality. In order to increase water resources in the Barcelona conurbation, an area with significant quantitative and qualitative groundwater disturbances, a MAR facility was built in Sant Vicenç dels Horts, Catalonia, Spain. The system, constructed in 2009 consists of a sedimentation pond that pre-treats the water that is then diverted to the final recharge pond. The facility was originally aimed at increasing the availability of supply water during scarcity periods. Later, it was considered as a good test site to study best infiltration practices regarding water quality evolution. For this purpose, a reactive layer was installed in 2011 at the bottom of the pond. This was composed by organic compost and autochthonous material. Small proportions of iron oxides and clay were added to promote ionic adsorption and exchange. The objective of the layer was to boost microbial activity that would be structured in depth according to the presence of a marked redox profile, thus enhancing the reduction of all organic matter, including a number of recalcitrant compounds. In the last 3 years, site studies were focused on the layer's efficiency (i.e., percentage of organic pollutants degradation). It was found that degradation is occurring despite the infiltration rate has been significantly reduced. In our most recent work, we took a step further in the study of the processes occurring in the facility, and specifically with those related to the presence of the reactive layer. We focused on characterizing microbial communities in the system by combining the sampling of soil in the recharge pond bottom, water of the vadose zone, and groundwater in the aquifer zone from a series of nearby piezometers. Molecular techniques, such as Denaturing Gradient of Gel Electrophoresis (DGGE), were applied to the water and soil samples. This information was matched with physicochemical parameters of the water sampled in the existing piezometers, allowing relating them with different measured hydrogeological parameters (conductivity, dissolved oxygen, temperature and Eh). This information is an initial step to understand how the reactive layer induces microbiological activity and therefore degradation and bioclogging processes in the studied MAR system.

  7. 3D LDV Measurements in Oscillatory Boundary Layers

    NASA Astrophysics Data System (ADS)

    Mier, J. M.; Garcia, M. H.

    2012-12-01

    The oscillatory boundary layer represents a particular case of unsteady wall-bounded flows in which fluid particles follow a periodic sinusoidal motion. Unlike steady boundary layer flows, the oscillatory flow regime and bed roughness character change in time along the period for every cycle, a characteristic that introduces a high degree of complexity in the analysis of these flows. Governing equations can be derived from the general Navier-Stokes equations for the motion of fluids, from which the exact solution for the laminar oscillatory boundary layer is obtained (also known as the 2nd Stokes problem). No exact solution exists for the turbulent case, thus, understanding of the main flow characteristics comes from experimental work. Several researchers have reported experimental work in oscillatory boundary layers since the 1960's; however, larger scale facilities and the development of newer measurement techniques with improved temporal and spatial resolution in recent years provides a unique opportunity to achieve a better understanding about this type of flows. Several experiments were performed in the Large Oscillatory Water and Sediment Tunnel (LOWST) facility at the Ven Te Chow Hydrosystems Laboratory, for a range of Reynolds wave numbers between 6x10^4 < Rew < 6x10^6 over a flat and smooth bottom. A 3D Laser Doppler Velocimetry (LDV) system was used to measure instantaneous flow velocities with a temporal resolution up to ~ 1,000 Hz. It was mounted on a 3-axis traverse with a spatial resolution of 0.01 mm in all three directions. The closest point to the bottom was measured at z = 0.2 mm (z+ ≈ 4), which allowed to capture boundary layer features with great detail. In order to achieve true 3D measurements, 2 probes were used on a perpendicular configuration, such that u and w components were measured from a probe on the side of the flume and v component was measured from a probe pointing down through and access window on top of the flume. The top probe was submerged in a water container, such that the focal length remained constant and coincidence in the measurement volume for all 3 components was maintained when traversing the probes along the measurement profiles. Results show the existence of high turbulence levels inside the boundary layer up to about 30 mm away from the bottom. The streamwise component u shows greater intensities closer to the bottom and ahead of the freestream velocity maximum. On the contrary, the vertical component w shows smaller values of turbulent intensity, located higher up in the profile and lagging with respect to the freestream velocity maximum. Meanwhile, the spanwise component v shows similar intensities than w, happening in phase with it, but distributed all along the boundary layer, overlapping the areas of greater intensity of u and w. In addition, wall shear stress and other turbulent magnitudes related to the boundary layer were analyzed from the experimental results obtained through this research.

  8. An Optimized Combined Wave and Current Bottom Boundary Layer Model for Arbitrary Bed Roughness

    DTIC Science & Technology

    2017-06-30

    Engineer Research and Development Center (ERDC), Coastal and Hydraulics Laboratory (CHL), Flood and Storm Protection Division (HF), Coastal ...ER D C/ CH L TR -1 7- 11 Coastal Inlets Research Program An Optimized Combined Wave and Current Bottom Boundary Layer Model for...client/default. Coastal Inlets Research Program ERDC/CHL TR-17-11 June 2017 An Optimized Combined Wave and Current Bottom Boundary Layer Model

  9. Thermal stability and specular reflection behaviour of CoNbZr-based bottom spin valves with nano-oxide layer

    NASA Astrophysics Data System (ADS)

    Kim, Jong Soo; Lee, Seong-Rae

    2004-06-01

    The thermal stability and specularity aspects of a CoNbZr-based bottom spin valve (SV) employing a nano-oxide layer (NOL) were investigated. The magnetoresistance (MR) ratio of the as-deposited CoNbZr-based bottom SV increased by 62% (from 6.3 to 10.2%) with incorporation of the NOL. The enhancement of the MR ratio was considered to be due to the specular effect ( increased from 0.722 to 1.363 cm) of the NOL. The MR ratio of a Ta-based bottom SV decreased by about 45% (from 6.9 to 3.8%) when the samples were annealed at 300 °C for 240 min. By contrast, the MR ratio of the CoNbZr-based bottom SV with NOL increase d by 14 % (from 10.2 to 11.7%). The root mean square roughness value of the CoNbZr layer (0.07 nm) was superior to that of the Ta layer (0.43 nm). Although Mn in IrMn diffused out to the surface through the active layers resulting in the formation of Mn oxide at the surface in the CoNbZr-based bottom SV, no trace of Mn was found in the active layers and no significant degradation occurred.

  10. Disposable sludge dewatering container and method

    DOEpatents

    Cole, Clifford M.

    1993-01-01

    A device and method for preparing sludge for disposal comprising a box with a thin layer of gravel on the bottom and a thin layer of sand on the gravel layer, an array of perforated piping deployed throughout the gravel layer, and a sump in the gravel layer below the perforated piping array. Standpipes connect the array and sump to an external ion exchanger/fine particulate filter and a pump. Sludge is deposited on the sand layer and dewatered using a pump connected to the piping array, topping up with more sludge as the aqueous component of the sludge is extracted. When the box is full and the free standing water content of the sludge is acceptable, the standpipes are cut and sealed and the lid secured to the box.

  11. In-situ falling-head test for hydraulic conductivity: Evaluation in layered sediments of an analysis derived for homogenous sediments

    NASA Astrophysics Data System (ADS)

    Burnette, Matthew C.; Genereux, David P.; Birgand, François

    2016-08-01

    The hydraulic conductivity (K) of streambeds is a critical variable controlling interaction of groundwater and surface water. The Hvorslev analysis for estimating K from falling-head test data has been widely used since the 1950s, but its performance in layered sandy sediments common in streams and lakes has not previously been examined. Our numerical simulations and laboratory experiments show that the Hvorslev analysis yields accurate K values in both homogenous sediment (for which the analysis was originally derived) and layered deposits with low-K sand over high-K sand. K from the Hvorslev analysis deviated significantly from true K only when two conditions were present together: (1) high-K sand was present over low-K sand, and (2) the bottom of the permeameter in which K was measured was at or very near the interface between high-K and low-K. When this combination of conditions exists, simulation and laboratory sand tank results show that in-situ Hvorslev K underestimates the true K of the sediment within a permeameter, because the falling-head test is affected by low-K sediment outside of (below the bottom of) the permeameter. In simulation results, the maximum underestimation (occurring when the bottom of the permeameter was at the interface of high K over low K) was by a factor of 0.91, 0.59, and 0.12 when the high-K to low-K ratio was 2, 10, and 100, respectively. In laboratory sand tank experiments, the underestimation was by a factor of about 0.83 when the high-K to low-K ratio was 2.3. Also, this underestimation of K by the Hvorslev analysis was about the same whether the underlying low-K layer was 2 cm or 174 cm thick (1% or 87% of the domain thickness). Numerical model simulations were useful in the interpretation of in-situ field K profiles at streambed sites with layering; specifically, scaling the model results to the maximum measured K at the top of the field K profiles helped constrain the likely ratio of high K to low K at field locations with layered heterogeneity. Vertical K values are important in field studies of groundwater-surface water interaction, and the Hvorslev analysis can be a useful tool, even in layered media, when applied carefully.

  12. Water-rich planets: How habitable is a water layer deeper than on Earth?

    NASA Astrophysics Data System (ADS)

    Noack, L.; Höning, D.; Rivoldini, A.; Heistracher, C.; Zimov, N.; Journaux, B.; Lammer, H.; Van Hoolst, T.; Bredehöft, J. H.

    2016-10-01

    Water is necessary for the origin and survival of life as we know it. In the search for life-friendly worlds, water-rich planets therefore are obvious candidates and have attracted increasing attention in recent years. The surface H2O layer on such planets (containing a liquid water ocean and possibly high-pressure ice below a specific depth) could potentially be hundreds of kilometres deep depending on the water content and the evolution of the proto-atmosphere. We study possible constraints for the habitability of deep water layers and introduce a new habitability classification relevant for water-rich planets (from Mars-size to super-Earth-size planets). A new ocean model has been developed that is coupled to a thermal evolution model of the mantle and core. Our interior structure model takes into account depth-dependent thermodynamic properties and the possible formation of high-pressure ice. We find that heat flowing out of the silicate mantle can melt an ice layer from below (in some cases episodically), depending mainly on the thickness of the ocean-ice shell, the mass of the planet, the surface temperature and the interior parameters (e.g. radioactive mantle heat sources). The high pressure at the bottom of deep water-ice layers could also impede volcanism at the water-mantle boundary for both stagnant lid and plate tectonics silicate shells. We conclude that water-rich planets with a deep ocean, a large planet mass, a high average density or a low surface temperature are likely less habitable than planets with an Earth-like ocean.

  13. Characterization of double diffusive convection step and heat budget in the deep Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Zhou, S.; Lu, Y.

    2013-12-01

    In this paper, we explore the hydrographic structure and heat budget in deep Canada Basin using data measured with McLane-Moored-Profilers (MMPs), bottom-pressure-recorders (BPRs), and conductivity-temperature-depth (CTD) profilers. From the bottom upward, a homogenous bottom layer and its overlaying double diffusive convection (DDC) steps are well identified at Mooring A (75oN, 150oW). We find that the deep water is in weak diapycnal mixing because the effective diffusivity of the bottom layer is ~1.8×10-5 m 2s-1 while that of the other steps is ~10-6 m 2s-1. The vertical heat flux through DDC steps is evaluated with different methods. We find that the heat flux (0.1-11 mWm-2) is much smaller than geothermal heating (~50 mWm-2), which suggests that the stack of DDC steps acts as a thermal barrier in the deep basin. Moreover, the temporal distributions of temperature and salinity differences across the interface are exponential, while those of heat flux and effective diffusivity are found to be approximately log-normal. Both are the result of strong intermittency. Between 2003 and 2011, temperature fluctuation close to the sea floor distributed asymmetrically and skewed towards positive values, which provides direct indication that geothermal heating is transferred into ocean. Both BPR and CTD data suggest that geothermal heating, not the warming of upper ocean, is the dominant mechanism responsible for the warming of deep water. As the DDC steps prevent the vertical heat transfer, geothermal heating will be unlikely to have significant effect on the middle and upper oceans.

  14. Characterization of double diffusive convection steps and heat budget in the deep Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Zhou, Sheng-Qi; Lu, Yuan-Zheng

    2013-12-01

    In this paper, we explore the hydrographic structure and heat budget in the deep Canada Basin by using data measured with McLane-Moored-Profilers (MMP), bottom pressure recorders (BPR), and conductivity-temperature-depth (CTD) profilers. Upward from the bottom, a homogeneous bottom layer and its overlaying double diffusive convection (DDC) steps are well identified at Mooring A (75°N,150°W). We find that the deep water is in weak diapycnal mixing because the effective diffusivity of the bottom layer is ˜1.8 × 10-5 m2s-1, while that of the other steps is ˜10-6 m2s-1. The vertical heat flux through the DDC steps is evaluated by using different methods. We find that the heat flux (0.1-11 mWm -2) is much smaller than geothermal heating (˜50 mWm -2). This suggests that the stack of DDC steps acts as a thermal barrier in the deep basin. Moreover, the temporal distributions of temperature and salinity differences across the interface are exponential, whereas those of heat flux and effective diffusivity are found to be approximately lognormal. Both are the result of strong intermittency. Between 2003 and 2011, temperature fluctuations close to the sea floor were distributed asymmetrically and skewed toward positive values, which provide a direct observation that geothermal heating was transferred into the ocean. Both BPR and CTD data suggest that geothermal heating and not the warming of the upper ocean is the dominant mechanism responsible for the warming of deep water. As the DDC steps prevent vertical heat transfer, geothermal heating is unlikely to have a significant effect on the middle and upper Arctic Ocean.

  15. Extraction of Seabed/Subsurface Features in a Potential CO2 Sequestration Site in the Southern Baltic Sea, Using Wavelet Transform of High-resolution Sub-Bottom Profiler Data

    NASA Astrophysics Data System (ADS)

    Tegowski, J.; Zajfert, G.

    2014-12-01

    Carbon Capture & Storage (CCS) efficiently prevents the release of anthropogenic CO2 into the atmosphere. We investigate a potential site in the Polish Sector of the Baltic Sea (B3 field site), consisting in a depleted oil and gas reservoir. An area ca. 30 x 8 km was surveyed along 138 acoustic transects, realised from R/V St. Barbara in 2012 and combining multibeam echosounder, sidescan sonar and sub-bottom profiler. Preparation of CCS sites requires accurate knowledge of the subsurface structure of the seafloor, in particular deposit compactness. Gas leaks in the water column were monitored, along with the structure of upper sediment layers. Our analyses show the shallow sub-seabed is layered, and quantified the spatial distribution of gas diffusion chimneys and seabed effusion craters. Remote detection of gas-containing surface sediments can be rather complex if bubbles are not emitted directly into the overlying water and thus detectable acoustically. The heterogeneity of gassy sediments makes conventional bottom sampling methods inefficient. Therefore, we propose a new approach to identification, mapping, and monitoring of potentially gassy surface sediments, based on wavelet analysis of echo signal envelopes of a chirp sub-bottom profiler (EdgeTech SB-0512). Each echo envelope was subjected to wavelet transformation, whose coefficients were used to calculate wavelet energies. The set of echo envelope parameters was input to fuzzy logic and c-means algorithms. The resulting classification highlights seafloor areas with different subsurface morphological features, which can indicate gassy sediments. This work has been conducted under EC FP7-CP-IP project No. 265847: Sub-seabed CO2 Storage: Impact on Marine Ecosystems (ECO2).

  16. Shear wave velocity and attenuation in the upper layer of ocean bottoms from long-range acoustic field measurements.

    PubMed

    Zhou, Ji-Xun; Zhang, Xue-Zhen

    2012-12-01

    Several physics-based seabed geoacoustic models (including the Biot theory) predict that compressional wave attenuation α(2) in sandy marine sediments approximately follows quadratic frequency dependence at low frequencies, i.e., α(2)≈kf(n) (dB/m), n=2. A recent paper on broadband geoacoustic inversions from low frequency (LF) field measurements, made at 20 locations around the world, has indicated that the frequency exponent of the effective sound attenuation n≈1.80 in a frequency band of 50-1000 Hz [Zhou et al., J. Acoust. Soc. Am. 125, 2847-2866 (2009)]. Carey and Pierce hypothesize that the discrepancy is due to the inversion models' neglect of shear wave effects [J. Acoust. Soc. Am. 124, EL271-EL277 (2008)]. The broadband geoacoustic inversions assume that the seabottom is an equivalent fluid and sound waves interact with the bottom at small grazing angles. The shear wave velocity and attenuation in the upper layer of ocean bottoms are estimated from the LF field-inverted effective bottom attenuations using a near-grazing bottom reflection expression for the equivalent fluid model, derived by Zhang and Tindle [J. Acoust. Soc. Am. 98, 3391-3396 (1995)]. The resultant shear wave velocity and attenuation are consistent with the SAX99 measurement at 25 Hz and 1000 Hz. The results are helpful for the analysis of shear wave effects on long-range sound propagation in shallow water.

  17. Effects of ecological engineered oxygenation on the bacterial community structure in an anoxic fjord in western Sweden

    PubMed Central

    Forth, Michael; Liljebladh, Bengt; Stigebrandt, Anders; Hall, Per O J; Treusch, Alexander H

    2015-01-01

    Oxygen-depleted bodies of water are becoming increasingly common in marine ecosystems. Solutions to reverse this trend are needed and under development, for example, by the Baltic deep-water OXygenation (BOX) project. In the framework of this project, the Swedish Byfjord was chosen for a pilot study, investigating the effects of an engineered oxygenation on long-term anoxic bottom waters. The strong stratification of the water column of the Byfjord was broken up by pumping surface water into the deeper layers, triggering several inflows of oxygen-rich water and increasing oxygen levels in the lower water column and the benthic zone up to 110 μmol l−1.We used molecular ecologic methods to study changes in bacterial community structure in response to the oxygenation in the Byfjord. Water column samples from before, during and after the oxygenation as well as from two nearby control fjords were analyzed. Our results showed a strong shift in bacterial community composition when the bottom water in the Byfjord became oxic. Initially dominant indicator species for oxygen minimum zones such as members of the SUP05 clade declined in abundance during the oxygenation event and nearly vanished after the oxygenation was accomplished. In contrast, aerobic species like SAR11 that initially were restricted to surface waters could later be detected deep into the water column. Overall, the bacterial community in the formerly anoxic bottom waters changed to a community structure similar to those found in oxic waters, showing that an engineered oxygenation of a large body of anoxic marine water is possible and emulates that of a natural oxygenation event. PMID:25238400

  18. Effects of ecological engineered oxygenation on the bacterial community structure in an anoxic fjord in western Sweden.

    PubMed

    Forth, Michael; Liljebladh, Bengt; Stigebrandt, Anders; Hall, Per O J; Treusch, Alexander H

    2015-03-01

    Oxygen-depleted bodies of water are becoming increasingly common in marine ecosystems. Solutions to reverse this trend are needed and under development, for example, by the Baltic deep-water OXygenation (BOX) project. In the framework of this project, the Swedish Byfjord was chosen for a pilot study, investigating the effects of an engineered oxygenation on long-term anoxic bottom waters. The strong stratification of the water column of the Byfjord was broken up by pumping surface water into the deeper layers, triggering several inflows of oxygen-rich water and increasing oxygen levels in the lower water column and the benthic zone up to 110 μmol l(-1).We used molecular ecologic methods to study changes in bacterial community structure in response to the oxygenation in the Byfjord. Water column samples from before, during and after the oxygenation as well as from two nearby control fjords were analyzed. Our results showed a strong shift in bacterial community composition when the bottom water in the Byfjord became oxic. Initially dominant indicator species for oxygen minimum zones such as members of the SUP05 clade declined in abundance during the oxygenation event and nearly vanished after the oxygenation was accomplished. In contrast, aerobic species like SAR11 that initially were restricted to surface waters could later be detected deep into the water column. Overall, the bacterial community in the formerly anoxic bottom waters changed to a community structure similar to those found in oxic waters, showing that an engineered oxygenation of a large body of anoxic marine water is possible and emulates that of a natural oxygenation event.

  19. Vertical nutrient fluxes, turbulence and the distribution of chlorophyll a in the north-eastern North Sea

    NASA Astrophysics Data System (ADS)

    Bendtsen, Jørgen; Richardson, Katherine

    2017-04-01

    During summer the northern North Sea is characterized by nutrient rich bottom water masses and nutrient poor surface layers. This explains the distribution of chlorophyll a in the water column where a subsurface maximum, referred to as the deep chlorophyll maximum (DCM), often is present during the growth season. Vertical transport of nutrients between bottom water masses and the well lit surface layer stimulates phytoplankton growth and this generally explains the location of the DCM. However, a more specific understanding of the interplay between vertical transports, nutrient fluxes and phytoplankton abundance is required for identifying the nature of the vertical transport processes, e.g the role of advection versus vertical turbulent diffusion or the role of localized mixing associated with mesoscale eddies. We present results from the VERMIX study in the north-eastern North Sea where nutrients, chlorophyll a and turbulence profiles were measured along five north-south directed transects in July 2016. A high-resolution sampling program, with horizontal distances of 1-10 km between CTD-stations, resolved the horizontal gradients of chlorophyll a across the steep bottom slope from the relatively shallow central North Sea ( 50-80 m) towards the deep Norwegian Trench (>700 m). Low oxygen concentrations in the bottom water masses above the slope indicated enhanced biological production where vertical mixing would stimulate phytoplankton growth around the DCM. Measurements of variable fluorescence (Fv/Fm) showed elevated values in the DCM which demonstrates a higher potential for electron transport in the Photosystem II in the phytoplankton cells, i.e. an indication of nutrient-rich conditions favorable for phytoplankton production. Profiles of the vertical shear and microstructure of temperature and salinity were measured by a VMP-250 turbulence profiler and the vertical diffusion of nutrients was calculated from the estimated vertical turbulent diffusivity and the distributions of nutrients. Results from the five transects and two time-series stations, where vertical profiles were made at hourly intervals, showed that vertical mixing processes above the slope increased the vertical transport of nutrients significantly and mixing above the slope can explain the hydrographic features and the distribution of the DCM in the area.

  20. Turbulence in the presence of internal waves in the bottom boundary layer of the California inner shelf

    NASA Astrophysics Data System (ADS)

    Allen, Rachel M.; Simeonov, Julian A.; Calantoni, Joseph; Stacey, Mark T.; Variano, Evan A.

    2018-05-01

    Turbulence measurements were collected in the bottom boundary layer of the California inner shelf near Point Sal, CA, for 2 months during summer 2015. The water column at Point Sal is stratified by temperature, and internal bores propagate through the region regularly. We collected velocity, temperature, and turbulence data on the inner shelf at a 30-m deep site. We estimated the turbulent shear production ( P), turbulent dissipation rate ( ɛ), and vertical diffusive transport ( T), to investigate the near-bed local turbulent kinetic energy (TKE) budget. We observed that the local TKE budget showed an approximate balance ( P ≈ ɛ) during the observational period, and that buoyancy generally did not affect the TKE balance. On a finer resolution timescale, we explored the balance between dissipation and models for production and observed that internal waves did not affect the balance in TKE at this depth.

  1. Spatial assessment of water quality using chemometrics in the Pearl River Estuary, China

    NASA Astrophysics Data System (ADS)

    Wu, Meilin; Wang, Youshao; Dong, Junde; Sun, Fulin; Wang, Yutu; Hong, Yiguo

    2017-03-01

    A cruise was commissioned in the summer of 2009 to evaluate water quality in the Pearl River Estuary (PRE). Chemometrics such as Principal Component Analysis (PCA), Cluster analysis (CA) and Self-Organizing Map (SOM) were employed to identify anthropogenic and natural influences on estuary water quality. The scores of stations in the surface layer in the first principal component (PC1) were related to NH4-N, PO4-P, NO2-N, NO3-N, TP, and Chlorophyll a while salinity, turbidity, and SiO3-Si in the second principal component (PC2). Similarly, the scores of stations in the bottom layers in PC1 were related to PO4-P, NO2-N, NO3-N, and TP, while salinity, Chlorophyll a, NH4-N, and SiO3-Si in PC2. Results of the PCA identified the spatial distribution of the surface and bottom water quality, namely the Guangzhou urban reach, Middle reach, and Lower reach of the estuary. Both cluster analysis and PCA produced the similar results. Self-organizing map delineated the Guangzhou urban reach of the Pearl River that was mainly influenced by human activities. The middle and lower reaches of the PRE were mainly influenced by the waters in the South China Sea. The information extracted by PCA, CA, and SOM would be very useful to regional agencies in developing a strategy to carry out scientific plans for resource use based on marine system functions.

  2. Water quality observations of ice-covered, stagnant, eutrophic water bodies and analysis of influence of ice-covered period on water quality

    NASA Astrophysics Data System (ADS)

    sugihara, K.; Nakatsugawa, M.

    2013-12-01

    The water quality characteristics of ice-covered, stagnant, eutrophic water bodies have not been clarified because of insufficient observations. It has been pointed out that climate change has been shortening the duration of ice-cover; however, the influence of climate change on water quality has not been clarified. This study clarifies the water quality characteristics of stagnant, eutrophic water bodies that freeze in winter, based on our surveys and simulations, and examines how climate change may influence those characteristics. We made fixed-point observation using self-registering equipment and vertical water sampling. Self-registering equipment measured water temperature and dissolved oxygen(DO).vertical water sampling analyzed biological oxygen demand(BOD), total nitrogen(T-N), nitrate nitrogen(NO3-N), nitrite nitrogen(NO2-N), ammonium nitrogen(NH4-N), total phosphorus(TP), orthophosphoric phosphorus(PO4-P) and chlorophyll-a(Chl-a). The survey found that climate-change-related increases in water temperature were suppressed by ice covering the water area, which also blocked oxygen supply. It was also clarified that the bottom sediment consumed oxygen and turned the water layers anaerobic beginning from the bottom layer, and that nutrient salts eluted from the bottom sediment. The eluted nutrient salts were stored in the water body until the ice melted. The ice-covered period of water bodies has been shortening, a finding based on the analysis of weather and water quality data from 1998 to 2008. Climate change was surveyed as having caused decreases in nutrient salts concentration because of the shortened ice-covered period. However, BOD in spring showed a tendency to increase because of the proliferation of phytoplankton that was promoted by the climate-change-related increase in water temperature. To forecast the water quality by using these findings, particularly the influence of climate change, we constructed a water quality simulation model that incorporates the freezing-over of water bodies. The constructed model shows good temporal and spatial reproducibility and enables water quality to be forecast throughout the year, including during the ice-covered period. The forecasts using the model agree well with the survey results of shortened ice period and climate-change-related increase in the BOD in spring. From the result of calculations and observations, it is suggested that water quality of spring has been deteriorate because of freezing period to be shortened due to temperature rising.

  3. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Werne, Roger W.; Sampayan, Stephen; Harris, John Richardson

    This patent document discloses high voltage switches that include one or more electrically floating conductor layers that are isolated from one another in the dielectric medium between the top and bottom switch electrodes. The presence of the one or more electrically floating conductor layers between the top and bottom switch electrodes allow the dielectric medium between the top and bottom switch electrodes to exhibit a higher breakdown voltage than the breakdown voltage when the one or more electrically floating conductor layers are not present between the top and bottom switch electrodes. This increased breakdown voltage in the presence of onemore » or more electrically floating conductor layers in a dielectric medium enables the switch to supply a higher voltage for various high voltage circuits and electric systems.« less

  4. Resistive heater geometry and regeneration method for a diesel particulate filter

    DOEpatents

    Phelps, Amanda [Malibu, CA; Kirby, Kevin W [Calabasas Hills, CA; Gregoir, Daniel J [Thousand Oaks, CA

    2011-10-25

    One embodiment of the invention includes a diesel particulate filter comprising a first face and a second face; a bottom electrode layer formed over the first face of the diesel particulate filter; a middle resistive layer formed over a portion of the bottom electrode layer; and a top electrode layer formed over a portion of the middle resistive layer.

  5. Flux of low salinity water from Aniva Bay (Sakhalin Island) to the southern Okhotsk Sea

    NASA Astrophysics Data System (ADS)

    Oguma, Sachiko; Ono, Tsuneo; Watanabe, Yutaka W.; Kasai, Hiromi; Watanabe, Shuichi; Nomura, Daiki; Mitsudera, Humio

    2011-01-01

    In this study, we examined the relationship between the low salinity water in the shelf region of the southern Okhotsk Sea which was seasonally sampled (0-200 m), and fluxes of low salinity water from Aniva Bay. To express the source of freshwater mixing in the surface layer, we applied normalized total alkalinity (NTA) and stable isotopes of seawater as chemical tracers. NTA-S diagrams indicate that NTA of low salinity water in the upper 30 m layer just off the Soya Warm Current is clearly higher than in the far offshore region in summer and autumn. Using NTA-S regression lines, we could deduce that the low salinity and high NTA water in the upper layer originates from Aniva Bay. For convenience, we defined this water as the Aniva Surface Water (ASW) with values S < 32, NTA > 2450 μmol kg -1. Formation and transport processes of ASW are discussed using historical data. The interaction between the maximum core of high NTA water on the bottom slope of eastern Aniva Bay and an anticyclonic eddy at the mouth of Aniva Bay are concluded to control ASW formation. Upwelling of the Cold Water Belt water at the tip of Cape Krillion is considered to cause ASW outflow from Aniva Bay.

  6. The Presence and Characterization of Antarctic Bottom Water Located Between the Mid-Atlantic Ridge and the Rio Grande Rise

    NASA Astrophysics Data System (ADS)

    Miller, R. H.; Reece, R.; Estep, J.; Christeson, G. L.; Acquisto, T. M.

    2016-12-01

    Circumpolar waters of widely varying properties enter South Atlantic Ocean circulation, interleaving their properties. Antarctic bottom water (ABW) flows northward into the South Atlantic at the eastern edge of the South American continent and around the Rio Grande Rise (RGR), a large aseismic ocean ridge in the deep water off the coast of Brazil. The majority of ABW transport occurs below depths of 3500 m, so very little is lost at the top of the RGR. In early 2016, the CREST (Crustal Reflectivity Experiment Southern Transect) expedition acquired multichannel seismic (MCS) and ocean bottom seismometer (OBS) datasets along a crustal segment in the South Atlantic, stretching from the Mid Atlantic Ridge (MAR) west to the RGR. During OBS recovery, a communications problem occurred in which the OBS received the transducer pulse from the ship, but the ship did not receive the OBS return pulse. The nine shallowest instruments, closest to the MAR, did not experience this problem, but all remaining instruments did. All instruments were extensively tested in the water column and in the lab and exhibited no malfunctions. We hypothesize that a deepwater layer of differing physical properties, located nearer the OBS than the boat, dispersed the return pulse resulting in the break in communications. ABW is a good candidate for a potential cold deepwater body in this region. We will examine multi-beam bathymetry returns and seismic reflection data for indications of reflections in the deepwater column. If observations support the presence of cold deepwater, we will fully characterize its properties and boundaries and determine if the characteristics match that of ABW. This study will characterize the behavior and nature of potential cold deepwater currents east of the Rio Grande Rise in an attempt to verify the presence of ABW. Information regarding the effects of differential water layering on acoustic communication with seafloor instruments could benefit future deployments to affected regions. Additionally, more insight into deep water ocean circulation could provide critical information for modeling with implications for chemical and heat exchange as well as ocean-climate interaction.

  7. Sci-Sat AM: Radiation Dosimetry and Practical Therapy Solutions - 01: Optimization of an organic field effect transistor for radiation dosimetry measurements

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Syme, Alasdair

    2016-08-15

    Purpose: To use Monte Carlo simulations to optimize the design of an organic field effect transistor (OFET) to maximize water-equivalence across the diagnostic and therapeutic photon energy ranges. Methods: DOSXYZnrc was used to simulate transport of mono-energetic photon beams through OFETs. Dose was scored in the dielectric region of devices and used for evaluating the response of the device relative to water. Two designs were considered: 1. a bottom-gate device on a substrate of polyethylene terephthalate (PET) with an aluminum gate, a dielectric layer of either PMMA or CYTOP (a fluorocarbon) and an organic semiconductor (pentacene). 2. a symmetric bilayermore » design was employed in which two polymer layers (PET and CYTOP) were deposited both below the gate and above the semiconductor to improve water-equivalence and reduce directional dependence. The relative thickness of the layers was optimized to maximize water-equivalence. Results: Without the bilayer, water-equivalence was diminished relative to OFETs with the symmetric bilayer at low photon energies (below 80 keV). The bilayer’s composition was designed to have one layer with an effective atomic number larger than that of water and the other with an effective atomic number lower than that of water. For the particular materials used in this study, a PET layer 0.1mm thick coupled with a CYTOP layer of 900 nm provided a device with a water-equivalence within 3% between 20 keV and 5 MeV. Conclusions: organic electronic devices hold tremendous potential as water-equivalent dosimeters that could be used in a wide range of applications without recalibration.« less

  8. Superheating of kerosene-surfactant-water interface formed in capillary

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kitamura, Y.; Huang, Q.; Takahashi, T.

    1993-03-01

    To provide fundamental information about the microexplosion of emulsified fuels, the effect of surfactants on the superheating of a kerosene-water interface was experimentally investigated. Surfactants such as Span 80, NPE[sub 2], NPE[sub 5], and NPE[sub 7.5] were used. The three-layer sample was prepared in a capillary; the bottom layer was kerosene, the middle layer was water, and the upper layer was kerosene. The surfactants were dissolved in the upper kerosene layer. The 30-40 samples were used to determine the superheating temperature distribution. The superheating temperature decreases with increasing concentration of surfactant and approaches a constant distribution over a critical concentration.more » The superheating temperature also depends on the hydrophilic group of NPE[sub x]. To explain such an effect, the authors assumed that the surfactant was absorbed on the interface and accelerated the nucleation rate. The authors suggest a modified nucleation rate which includes the surface coverage by a surfactant. The model predicts that the presence of surfactants reduces the superheating temperature and makes the distribution broader. The prediction from this model is in good agreement with the experimental data.« less

  9. Ikaite crystal distribution in Arctic winter sea ice and implications for CO2 system dynamics

    NASA Astrophysics Data System (ADS)

    Rysgaard, S.; Søgaard, D. H.; Cooper, M.; Pućko, M.; Lennert, K.; Papakyriakou, T. N.; Wang, F.; Geilfus, N. X.; Glud, R. N.; Ehn, J.; McGinnnis, D. F.; Attard, K.; Sievers, J.; Deming, J. W.; Barber, D.

    2012-12-01

    The precipitation of ikaite (CaCO3·6H2O) in polar sea ice is critical to the efficiency of the sea ice-driven carbon pump and potentially important to the global carbon cycle, yet the spatial and temporal occurrence of ikaite within the ice is poorly known. We report unique observations of ikaite in unmelted ice and vertical profiles of ikaite abundance and concentration in sea ice for the crucial season of winter. Ice was examined from two locations: a 1 m thick land-fast ice site and a 0.3 m thick polynya site, both in the Young Sound area (74° N, 20° W) of NE Greenland. Ikaite crystals, ranging in size from a few µm to 700 µm were observed to concentrate in the interstices between the ice platelets in both granular and columnar sea ice. In vertical sea-ice profiles from both locations, ikaite concentration determined from image analysis, decreased with depth from surfaceice values of 700-900 µmol kg-1 ice (~ 25 × 106 crystals kg-1) to bottom-layer values of 100-200 µmol kg-1 ice (1-7 × 106 kg-1), all of which are much higher (4-10 times) than those reported in the few previous studies. Direct measurements of total alkalinity (TA) in surface layers fell within the same range as ikaite concentration whereas TA concentrations in bottom layers were twice as high. This depth-related discrepancy suggests interior ice processes where ikaite crystals form in surface sea ice layers and partly dissolved in bottom layers. From these findings and model calculations we relate sea ice formation and melt to observed pCO2 conditions in polar surface waters, and hence, the air-sea CO2 flux.

  10. Probing the nanoscale with high-speed interferometry of an impacting drop

    NASA Astrophysics Data System (ADS)

    Thoroddsen, S. T.; Li, E. Q.; Vakarelski, I. U.; Langley, K.

    2017-02-01

    The simple phenomenon of a water drop falling onto a glass plate may seem like a trivial fluid mechanics problem. However, detailed imaging has shown that this process is highly complex and a small air-bubble is always entrapped under the drop when it makes contact with the solid. This bubble can interfere with the uniformity of spray coatings and degrade inkjet fabrication of displays etc. We will describe how we use high-speed interferometry at 5 million frames per second to understand the details of this process. As the impacting drop approaches the solid, the dynamics are characterized by a balance between the lubrication pressure in the thin air layer and the inertia of the bot-tom of the drop. This deforms the drop, forming a dimple at its bottom and making the drop touch the surface along a ring, thereby entrapping the air-layer, which is typically 1-3 μm thick. This air-layer can be highly compressed and the deceleration of the bottom of the drop can be as large as 300,000 g. We describe how the thickness evolution of the lubricating air-layer is extracted from following the interference fringes between frames. Two-color interferometry is also used to extract absolute layer thicknesses. Finally, we identify the effects of nanometric surface roughness on the first contact of the drop with the substrate. Here we need to resolve the 100 nm thickness changes occurring during 200 ns intervals, requiring these state of the art high-speed cameras. Surprisingly, we see a ring of micro-bubbles marking the first contact of the drop with the glass, only for microscope slides, which have a typical roughness of 20 nm, while such rings are absent for drop impacts onto molecularly smooth mica surfaces.

  11. Reflective properties of melt ponds on sea ice

    NASA Astrophysics Data System (ADS)

    Malinka, Aleksey; Zege, Eleonora; Istomina, Larysa; Heygster, Georg; Spreen, Gunnar; Perovich, Donald; Polashenski, Chris

    2018-06-01

    Melt ponds occupy a large part of the Arctic sea ice in summer and strongly affect the radiative budget of the atmosphere-ice-ocean system. In this study, the melt pond reflectance is considered in the framework of radiative transfer theory. The melt pond is modeled as a plane-parallel layer of pure water upon a layer of sea ice (the pond bottom). We consider pond reflection as comprising Fresnel reflection by the water surface and multiple reflections between the pond surface and its bottom, which is assumed to be Lambertian. In order to give a description of how to find the pond bottom albedo, we investigate the inherent optical properties of sea ice. Using the Wentzel-Kramers-Brillouin approximation approach to light scattering by non-spherical particles (brine inclusions) and Mie solution for spherical particles (air bubbles), we conclude that the transport scattering coefficient in sea ice is a spectrally independent value. Then, within the two-stream approximation of the radiative transfer theory, we show that the under-pond ice spectral albedo is determined by two independent scalar values: the transport scattering coefficient and ice layer thickness. Given the pond depth and bottom albedo values, the bidirectional reflectance factor (BRF) and albedo of a pond can be calculated with analytical formulas. Thus, the main reflective properties of the melt pond, including their spectral dependence, are determined by only three independent parameters: pond depth z, ice layer thickness H, and transport scattering coefficient of ice σt.The effects of the incident conditions and the atmosphere state are examined. It is clearly shown that atmospheric correction is necessary even for in situ measurements. The atmospheric correction procedure has been used in the model verification. The optical model developed is verified with data from in situ measurements made during three field campaigns performed on landfast and pack ice in the Arctic. The measured pond albedo spectra were fitted with the modeled spectra by varying the pond parameters (z, H, and σt). The coincidence of the measured and fitted spectra demonstrates good performance of the model: it is able to reproduce the albedo spectrum in the visible range with RMSD that does not exceed 1.5 % for a wide variety of melt pond types observed in the Arctic.

  12. Exact Solutions for Stationary and Unsteady Layered Convection of a Viscous Incompressible Fluid with the Specified Velocities at the Bottom

    NASA Astrophysics Data System (ADS)

    Prosviryakov, E. Yu; Spevak, L. F.

    2017-06-01

    The layered convective flow of a viscous incompressible fluid is considered with the specified velocities at the bottom of an infinite layer. A new exact stationary and nonstationary solution of the Oberbeck-Boussinesq system is presented. The account of fluid velocity at the bottom is characterized by the presence of two stagnant points, this being indicative of the nonmonotonic kinetic energy profile with two local extrema.

  13. Ferromagnetic resonance investigation in as-prepared NiFe/FeMn/NiFe trilayer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yuan, S. J.; Xu, K.; Yu, L. M.

    2007-06-01

    NiFe/FeMn/NiFe trilayer prepared by dc magnetron sputtering was systematically investigated by ferromagnetic resonance technique (FMR) at room temperature. For NiFe/FeMn/NiFe trilayer, there are two distinct resonance peaks both in in-plane and out-of-plane FMR spectra, which are attributed to the two NiFe layers, respectively. The isotropic in-plane resonance field shift is negative for the bottom NiFe layer, while positive for the top NiFe layer. And, such phenomena result from the negative interfacial perpendicular anisotropy at the bottom NiFe/FeMn interface and positive interfacial perpendicular anisotropy at the top FeMn/NiFe interface. The linewidth of the bottom NiFe layer is larger than that ofmore » the top NiFe layer, which might be related to the greater exchange coupling at the bottom NiFe/FeMn interface.« less

  14. Mobile Bay river plume mixing in the inner shelf

    NASA Astrophysics Data System (ADS)

    Parra, S. M.; Book, J. W.; Warner, S. J.; Moum, J.

    2017-12-01

    The microtidal region (0.5 m spring tides) of the inner shelf outside Mobile Bay presented a complex circulation pattern driven by the pulsed river discharge and winds. Currents, salinity, temperature, and turbulence profiles were measured for up to three weeks in April 2016 at six moorings outside Mobile Bay. Currents varied between locations and with depth. During neap and spring tides the currents were reliably >0.4 and <0.4 m/s, respectively. The outflow from Mobile Bay generated a complex density circulation, where two to three layers were normally present. Multiple density layers included a thicker brackish middle layer (5-10 m thickness), and a salty bottom layer (5-10 m thickness), with a thin ( 1-3 m) freshwater surface layer found intermittently. The multilayer currents were strongest at neap tides (>0.5 m/s) and toward deeper waters, concurrent with the strongest stratification. The possible flow drivers considered include tides, winds, inertial oscillations, waves, and stratification. Turbulent kinetic energy production and dissipation were calculated with multiple methods using data from bottom-mounted, upward-looking acoustic Doppler current profilers sampling at 1 Hz, and using data from line-moored chi-pod turbulent temperature microstructure instruments sampling at 100 Hz. This work explores different forcing mechanisms involved in modulating the circulation and turbulence in a multi-layered pulsed-river inner shelf region in the Gulf of Mexico.

  15. Preliminary study of sources and processes of enrichment of manganese in water from University of Rhode Island supply wells

    USGS Publications Warehouse

    Silvey, William Dudley; Johnston, Herbert E.

    1977-01-01

    Concentrations of dissolved manganese have increased from 0.0 to as much as 3.3 mg/liter over a period of years in closely spaced University of Rhode Island supply wells. The wells tap stratified glacial deposits and derive part of their water from infiltration from a nearby river-pond system. The principal sources of the manganese seem to be coatings of oxides and other forms of manganese on granular aquifer materials and organic-rich sediments on the bottom of the pond and river. Chemical analyses of water from an observation well screened from 3 to 5 feet below the pond bottom indicate that infiltration of water through organic-rich sediments on the pond bottom is the likely cause of manganese enrichment in the well supplies. After passing through the organic layer, the water contains concentrations of manganese as high as 1.2 mg/liter. Manganese in water in concentrations that do not cause unpleasant taste is not regarded to be toxicologically significant. However, concentrations in excess of a few tenths of a milligram per liter are undesirable in public supplies and in many industrial supplies. Brown and others (21970) note that waters containing manganese in concentrations less than 0.1 mg/liter seldom prove troublesome, but that those containing more than 0.5 mg/liter may form objectionable deposits on cooked food, laundry, and plumbing fixtures. The U.S. Public health Service (1962) recommends that the concentrations of manganese in drinking and culinary water not exceed 0.05 mg/liter. (Woodard-USGS)

  16. Collection, processing, and interpretation of ground-penetrating radar data to determine sediment thickness at selected locations in Deep Creek Lake, Garrett County, Maryland, 2007

    USGS Publications Warehouse

    Banks, William S.L.; Johnson, Carole D.

    2011-01-01

    This investigation focused on selected regions of the study area, particularly in the coves where sediment accumulations were presumed to be thickest. GPR was the most useful tool for interpreting sediment thickness, especially in these shallow coves. The radar profiles were interpreted for two surfaces of interest-the water bottom, which was defined as the "2007 horizon," and the interface between Lake sediments and the original Lake bottom, which was defined as the "1925 horizon"-corresponding to the year the Lake was impounded. The ground-penetrating radar data were interpreted on the basis of characteristics of the reflectors. The sediments that had accumulated in the impounded Lake were characterized by laminated, parallel reflections, whereas the subsurface below the original Lake bottom was characterized by more discontinuous and chaotic reflections, often with diffractions indicating cobbles or boulders. The reflectors were picked manually along the water bottom and along the interface between the Lake sediments and the pre-Lake sediments. A simple graphic approach was used to convert traveltimes to depth through water and depth through saturated sediments using velocities of the soundwaves through the water and the saturated sediments. Nineteen cross sections were processed and interpreted in 9 coves around Deep Creek Lake, and the difference between the 2007 horizon and the 1925 horizon was examined. In most areas, GPR data indicate a layer of sediment between 1 and 7 feet thick. When multiple cross sections from a single cove were compared, the cross sections indicated that sediment thickness decreased toward the center of the Lake.

  17. Doped bottom-contact organic field-effect transistors

    NASA Astrophysics Data System (ADS)

    Liu, Shiyi; Billig, Paul; Al-Shadeedi, Akram; Kaphle, Vikash; Lüssem, Björn

    2018-07-01

    The influence of doping on doped bottom-gate bottom-contact organic field-effect transistors (OFETs) is discussed. It is shown that the inclusion of a doped layer at the dielectric/organic semiconductor layer leads to a significant reduction in the contact resistances and a fine control of the threshold voltage. Through varying the thickness of the doped layer, a linear shift of threshold voltage V T from ‑3.1 to ‑0.22 V is observed for increasing thickness of doped layer. Meanwhile, the contact resistance at the source and drain electrode is reduced from 138.8 MΩ at V GS = ‑10 V for 3 nm to 0.3 MΩ for 7 nm thick doped layers. Furthermore, an increase of charge mobility is observed for increasing thickness of doped layer. Overall, it is shown that doping can minimize injection barriers in bottom-contact OFETs with channel lengths in the micro-meter regime, which has the potential to increase the performance of this technology further.

  18. Bedforms induced by solitary waves: laboratory studies on generation and migration rate

    NASA Astrophysics Data System (ADS)

    la Forgia, Giovanni; Adduce, Claudia; Falcini, Federico; Paola, Chris

    2017-04-01

    This study presents experiments on the formation of sandy bedforms, produced by surface solitary waves (SSWs) in shallow water conditions. The experiments were carried out in a 12.0 m long, 0.15 m wide and 0.5 m high flume, at Saint Anthony Falls Laboratory in Minneapolis. The tank is filled by fresh water and a removable gate, placed at the left hand-side of the tank, divides the flume in two regions: the lock region and the ambient fluid region. The standard lock-release method generates SSWs by producing a displacement between the free surfaces that are divided by the gate. Wave amplitude, wavelength, and celerity depend on the lock length and on the water level difference between the two regions. Natural sand particles (D50=0.64) are arranged on the bottom in order to form a horizontal flat layer with a thickness of 2 cm. A digital pressure gauge and a high-resolution acoustic velocimeter allowed us to measure, locally, both pressure and 3D water velocity induced on the bottom by each wave. Image analysis technique is then used to obtain the main wave features: amplitude, wavelength, and celerity. Dye is finally used as vertical tracer to mark the horizontal speed induced by the wave. For each experiment we generated 400 waves, having the same features and we analyzed their action on sand particles placed on the bottom. The stroke, induced by each wave, entails a shear stress on the sand particles, causing sediment transport in the direction of wave propagation. Immediately after the wave passage, a back flow occurs near the bottom. The horizontal pressure gradient and the velocity field induced by the wave cause the boundary layer separation and the consequent reverse flow. Depending on the wave features and on the water depth, the boundary shear stress induced by the reverse flow can exceed the critical value inducing the back motion of the sand particles. The experiments show that the particle back motion is localized at particular cross sections along the tank, where the wave steepening occur. For this reason, the pressure and velocity measures were collected in several cross sections along the tank. The propagation of consecutive waves with the same features induces the generation of erosion and accumulation zones, which slowly evolve in isometric bedforms.

  19. Geohydrology, water quality, and simulation of ground-water flow in the vicinity of a former waste-oil refinery near Westville, Indiana, 1997-2000

    USGS Publications Warehouse

    Duwelius, Richard F.; Yeskis, Douglas J.; Wilson, John T.; Robinson, Bret A.

    2002-01-01

    A three-dimensional, four layer groundwater- flow model was constructed and calibrated to match ground-water levels and streamflow measured during December 1997. The model was used to simulate possible mechanisms of contaminant release, the effect of increased pumpage from water-supply wells, and pumping at the leading edge of the plume as a possible means of remediation. Based on simulation of threewaste-oil lagoons, a vertical hydraulic conductivity of 0.2 feet per day was required to move contaminants into the bottom layer of the model at a constant leakage rate of about 98 gallons per minute. Simulations of a disposal well in layer 3 of the model indicated an injection rate of 50 gallons per minute was necessary to spread contaminants vertically in the aquifer. Simulated pumping rates of about 300 and 1,000 gallons per minute were required for watersupply wells at the Town of Westville and the Westville Correctional Facility to draw water from the plume of 1,4-dioxane. Simulated pumping from hypothetical wells at the leading edge of the plume indicated that three wells, each pumping 25 gallons per minute from model layer 3, would capture the plume of 1,4-dioxane.

  20. Sediment resuspension and bed armoring during high bottom stress events on the northern California inner continental shelf: measurements and predictions

    NASA Astrophysics Data System (ADS)

    Wiberg, Patricia L.; Drake, David E.; Cacchione, David A.

    1994-08-01

    Geoprobe bottom tripods were deployed during the winter of 1990-1991 on the northern California inner continental shelf as part of the STRESS field experiment. Transmissometer measurements of light beam attenuation were made at two levels and current velocity was measured at four levels in the bottom 1.2 m of water. Intervals of high measured bottom wave velocity were generally correlated with times of both high attenuation and high attenuation gradient in the bottom meter of the water column. Measured time series of light attenuation and attenuation gradient are compared to values computed using a modified version of the SMITH [(1977) The sea, Vol. 6, Wiley-Interscience, New York, pp. 539-577] steady wave-current bottom-boundary-layer model. Size-dependent transmissometer calibrations, which show significantly enhanced attenuation with decreasing grain size, are used to convert calculated suspended sediment concentration to light attenuation. The finest fractions of the bed, which are the most easily suspended and attenuate the most light, dominate the computed attenuation signal although they comprise only about 5-7% of the bed sediment. The calculations indicate that adjusting the value of the coefficient γ 0 in the expression for near-bed sediment concentration cannot in itself give both the correct magnitudes of light attenuation and attenuation gradient. To supply the volumes of fine sediment computed to be in suspension during peak events, even with values of γ 0 as low as 5 × 10 -5, requires suspension of particles from unreasonably large depths in the bed. A limit on the depth of sediment availability is proposed as a correction to suspended sediment calculations. With such a limit, reasonable attenuation values are computed with γ 0 ≈ 0.002. The effects of limiting availability and employing a higher γ 0 are to reduce the volume of the finest sediment in suspension and to increase the suspended volumes of the coarser fractions. As a consequence, the average size and settling velocity of suspended sediment increases as bottom shear stress increases, with accompanying increases in near-bed concentration gradients. Higher concentration gradients produce larger stratification effects, particularly near the top of the wave boundary layer at times when wave shear velocities are high and current shear velocities are low. These are the conditions under which maximum attenuation gradients are observed.

  1. Sediment resuspension and bed armoring during high bottom stress events on the northern California inner continental shelf: measurements and predictions

    USGS Publications Warehouse

    Wiberg, P.L.; Drake, D.E.; Cacchione, D.A.

    1994-01-01

    Geoprobe bottom tripods were deployed during the winter of 1990-1991 on the northern California inner continental shelf as part of the STRESS field experiment. Transmissometer measurements of light beam attenuation were made at two levels and current velocity was measured at four levels in the bottom 1.2 m of water. Intervals of high measured bottom wave velocity were generally correlated with times of both high attenuation and high attenuation gradient in the bottom meter of the water column. Measured time series of light attenuation and attenuation gradient are compared to values computed using a modified version of the Smith [(1977) The sea, Vol. 6, Wiley-Interscience, New York, pp. 539-577] steady wave-current bottom-boundary-layer model. Size-dependent transmissometer calibrations, which show significantly enhanced attenuation with decreasing grain size, are used to convert calculated suspended sediment concentration to light attenuation. The finest fractions of the bed, which are the most easily suspended and attenuate the most light, dominate the computed attenuation signal although they comprise only about 5-7% of the bed sediment. The calculations indicate that adjusting the value of the coefficient ??0 in the expression for near-bed sediment concentration cannot in itself give both the correct magnitudes of light attenuation and attenuation gradient. To supply the volumes of fine sediment computed to be in suspension during peak events, even with values of ??0 as low as 5 ?? 10-5, requires suspension of particles from unreasonably large depths in the bed. A limit on the depth of sediment availability is proposed as a correction to suspended sediment calculations. With such a limit, reasonable attenuation values are computed with ??0 ??? 0.002. The effects of limiting availability and employing a higher ??0 are to reduce the volume of the finest sediment in suspension and to increase the suspended volumes of the coarser fractions. As a consequence, the average size and settling velocity of suspended sediment increases as bottom shear stress increases, with accompanying increases in near-bed concentration gradients. Higher concentration gradients produce larger stratification effects, particularly near the top of the wave boundary layer at times when wave shear velocities are high and current shear velocities are low. These are the conditions under which maximum attenuation gradients are observed. ?? 1994.

  2. Modeling and Analysis of Target Echo and Clutter in Range-Dependent Bistatic Environments: FY12 Annual Report for ONR

    DTIC Science & Technology

    2012-09-30

    interface since it includes the phase. The effects of a low-speed resonant layer have been noticed before in regard to propagation. Hastrup [Has80... Hastrup . Some bottom-reflection loss anomalies near grazing and their effect on propagation in shallow water. In W. A. Kuperman and F. B. Jensen, editors

  3. New Experiments on Wave Physics with a Simply Modified Ripple Tank

    ERIC Educational Resources Information Center

    Logiurato, Fabrizio

    2014-01-01

    The ripple tank is one of the physics education devices most appreciated by teachers and students. It allows one to visualize various phenomena related to wave physics in an effective and enthralling way. Usually this apparatus consists of a tank with a transparent bottom that is filled with a thin layer of water. A source of light illuminates the…

  4. Nannofossils in upper quaternary bottom sediments of back-arc basins in the southwestern Pacific

    NASA Astrophysics Data System (ADS)

    Dmitrenko, O. B.

    2015-05-01

    The analysis of calcareous nannoplankton assemblages in bottom sediments sampled during Cruise 21 of the R/V Akademik Mstislav Keldysh in three areas located in back-arc basins of the southwestern Pacific (western Woodlark in the Solomon Sea, Manus in the Bismarck Sea, Central Lau) reveal that they belong to the Emiliania huxleyi Acme Zone, the most detailed one in the Gartner's scale of 1977. The content of coccoliths and their taxonomic composition indicate warm subtropical-tropical conditions. Long cores demonstrate a decrease in species diversity reflecting the transition from the cold late Pleistocene to the Holocene. The changes in species diversity and presence/absence of thermophilic representatives indicate transformation of depositional environments with unstable conditions in the water column and bottom layer, seismic activity, and widely developed processes of sediment redistribution and reworking.

  5. Under-ice melt ponds and the oceanic mixed layer

    NASA Astrophysics Data System (ADS)

    Flocco, D.; Smith, N.; Feltham, D. L.

    2017-12-01

    Under-ice melt ponds are pools of freshwater beneath the Arctic sea ice that form when melt from the surface of the sea ice percolates down through the porous sea ice. Through double diffusion, a sheet of ice can form at the interface between the ocean and the under-ice melt pond, completely isolating the pond from the mixed layer below and forming a false bottom to the sea ice. As such, they insulate the sea ice from the ocean below. It has been estimated that these ponds could cover between 5 and 40 % of the base of the Arctic sea ice, and so could have a notable impact on the mass balance of the sea ice. We have developed a one-dimensional model to calculate the thickness and thermodynamic properties of a slab of sea ice, an under-ice melt pond, and a false bottom, as these layers evolve. Through carrying out sensitivity studies, we have identified a number of interesting ways that under-ice melt ponds affect the ice above them and the rate of basal ablation. We found that they result in thicker sea ice above them, due to their insulation of the ice, and have found a possible positive feedback cycle in which less ice will be gained due to under-ice melt ponds as the Arctic becomes warmer. More recently, we have coupled this model to a simple Kraus-Turner type model of the oceanic mixed layer to investigate how these ponds affect the ocean water beneath them. Through altering basal ablation rates and ice thickness, they change the fresh water and salt fluxes into the mixed layer, as well as incoming radiation. Multi-year simulations have, in particular, shown how these effects work on longer time-scales.

  6. Origin and history of the Charleston Bump - Geological formations, currents, bottom conditions, and their relationship to wreckfish habitats on the Blake Plateau

    USGS Publications Warehouse

    Popenoe, P.; Manheim, F.T.

    2001-01-01

    The Charleston Bump is a structural and topographic high on the northern Blake Plateau that overlies a seaward offset of the edge of continental crust. The feature causes the bottom to shoal and deflects the Gulf Stream offshore, causing an intensification of bottom currents. The area has been swept by strong currents since late Cretaceous time, but the strongest currents have occurred in the Neogene (last ???25 million years). Nondepositional conditions prevail at present, but erosion of the bottom is checked where the bottom is armored by a hard surficial layer of phosphorite pavement. The phosphorite pavements were formed by re-cementation of eroded residues of phosphorite-rich sediments of early-Neogene age. In some places there are multiple pavements separated by poorly lithified sediments. Submersible observations indicate that the south, or current-facing flank of the Charleston Bump has several deep (>100 m) scour depressions, the southern flanks of which form cliffs characterized by ledges and overhangs. In other areas discrete layers of older Paleogene rocks have been partly eroded away, leaving cliff-like steps of 5 m or more relief. Conglomeratic phosphorite pavement layers up to 1 m thick armor most of the bottom. Where breached by scour, these pavements form both low-relief ledges and rock piles. These features form a reef-like environment of caves and overhangs utilized by wreckfish Polyprion americanus and barrelfish Hyperoglyphe perciformis as shelter from the current and as staging areas to prey on passing schools of squid. Wreckfish and other large fish were often localized in rugged bottom habitat, including caves and other shelter areas. We observed wreckfish darting from shelters to feed on passing schools of squid. Present and past observations, are consistent with the concept that impingement of the Gulf Stream at the Charleston Bump compresses midwater fauna from much thicker water layers, providing food for a flourishing big-fish fauna. During our dives we noted currents often exceeding 1 knot, and ranging to 2.4 knots. Evidence of fossil, manganese-iron-encrusted megaripples suggest even greater current regimes in the past. Investigation of the site of an earlier report of possible freshwater discharge failed to find any evidence of a closed sinkhole or freshwater discharge. Rather, we concluded that the apparent loss of buoyancy experienced by the submarine was probably caused by downward-directed eddy currents generated by currents sweeping across the pavement/void interface of a more than 100-m high cliff 3 km south of the reported location.

  7. Water in Inhomogeneous Nanoconfinement: Coexistence of Multilayered Liquid and Transition to Ice Nanoribbons.

    PubMed

    Qiu, Hu; Zeng, Xiao Cheng; Guo, Wanlin

    2015-10-27

    Phase behavior and the associated phase transition of water within inhomogeneous nanoconfinement are investigated using molecular dynamics simulations. The nanoconfinement is constructed by a flat bottom plate and a convex top plate. At 300 K, the confined water can be viewed as a coexistence of monolayer, bilayer, and trilayer liquid domains to accommodate the inhomogeneous confinement. With increasing liquid density, the confined water with uneven layers transforms separately into two-dimensional ice crystals with unchanged layer number and rhombic in-plane symmetry for oxygen atoms. The monolayer water undergoes the transition first into a puckered ice nanoribbon, and the bilayer water transforms into a rhombic ice nanoribbon next, followed by the transition of trilayer water into a trilayer ice nanoribbon. The sequential localized liquid-to-solid transition within the inhomogeneous confinement can also be achieved by gradually decreasing the temperature at low liquid densities. These findings of phase behaviors of water under the inhomogeneous nanoconfinement not only extend the phase diagram of confined water but also have implications for realistic nanofluidic systems and microporous materials.

  8. Sediment Transport over a Dredge Pit, Sandy Point Southeast, west flank of the Mississippi River during Summer Upcoast Currents: a Coupled Wave, Current and Sediment Numerical Model

    NASA Astrophysics Data System (ADS)

    Chaichitehrani, N.; Li, C.; Xu, K.; Bentley, S. J.; Miner, M. D.

    2017-12-01

    Sandy Point southeast, an elongated sand resource, was dredged in November 2012 to restore Pelican Island, Louisiana. Hydrodynamics and wave propagation patterns along with fluvial sediments from the Mississippi River influence the sediment and bottom boundary layer dynamics over Sandy Point. A state-of-the-art numerical model, Delft3D, was implemented to investigate current variations and wave transformation on Sandy Point as well as sediment transport pattern. Delft3d FLOW and WAVE modules were coupled and validated using WAVCIS and NDBC data. Sediment transport model was run by introducing both bed and river sediments, consisted of mainly mud and a small fraction of sand. A sediment transport model was evaluated for surface sediment concentration using data derived from satellite images. The model results were used to study sediment dynamics and bottom boundary layer characteristics focused on the Sandy Point area during summer. Two contrasting bathymetric configurations, with and without the Sandy Point dredge pit, were used to conduct an experiment on the sediment and bottom boundary layer dynamics. Preliminary model results showed that the presence of the Sandy Point pit has very limited effect on the hydrodynamics and wave pattern at the pit location. Sediments from the Mississippi River outlets, especially in the vicinity of the pit, get trapped in the pit under the easterly to the northeasterly upcoast current which prevails in August. We also examined the wave-induced sediment reworking and river-borne fluvial sediment over Sandy Point. The effect of wind induced orbital velocity increases the bottom shear stress compared to the time with no waves, relatively small wave heights (lower than 1.5 meters) along the deepest part of the pit (about 20 meters) causes little bottom sediment rework during this period. The results showed that in the summertime, river water is more likely the source of sedimentation in the pit.

  9. Ultra-high current density thin-film Si diode

    DOEpatents

    Wang; Qi

    2008-04-22

    A combination of a thin-film .mu.c-Si and a-Si:H containing diode structure characterized by an ultra-high current density that exceeds 1000 A/cm.sup.2, comprising: a substrate; a bottom metal layer disposed on the substrate; an n-layer of .mu.c-Si deposited the bottom metal layer; an i-layer of .mu.c-Si deposited on the n-layer; a buffer layer of a-Si:H deposited on the i-layer, a p-layer of .mu.c-Si deposited on the buffer layer; and a top metal layer deposited on the p-layer.

  10. Currents and water characteristics around the West Flower Garden Bank. [West Flower Garden Bank, coral reef, Texas continental shelf

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Horne, D.J.

    1986-01-01

    The West Flower Garden Bank is a coral reef on the Texas Continental shelf. The corals on the bank are vulnerable to sediment contamination and to excess turbidity in the overlying water column. Concern for the environmental impact on this and other banks in the region exposed to nearby hydrocarbon production prompted the Bureau of Land Management to fund a data collection effort on the Texas/Louisiana shelf which provided the data analyzed here. Data analyzed includes profiles of velocity, temperature and salinity taken around the Bank in Oct., 1980 and March, 1981. Fixed current meter moorings and a dye experimentmore » conducted in the bottom boundary layer provided additional input. The data reveals a very complicated flow regime around the bank, with some intensification of flow around and over the bank but no movement of water from the bottom of the surrounding shelf up onto the bank.« less

  11. Water vapour condensation in a partly closed structure. Comparison between results obtained with an inside wet or dry bottom wall

    NASA Astrophysics Data System (ADS)

    Batina, Jean; Peyrous, René

    2018-04-01

    We are interested in the determination of the more significant parameters acting on the water vapour condensation in a partly closed structure, submitted to external constraints (temperature and humidity), in view to recover the generated droplets as an additional source of potable water. External temperature variations, by inducing temperature differences between outside and inside of the structure, lead to convective movements and thermal variations inside this structure. Through an orifice, these movements permit a renewing of the humid inner air and can lead to the condensation of the water vapour initially contained in the inner air volume and/or on the walls. With the above hypotheses, and by using a numerical simulation [1] based on the ambient air characteristics and a finite volumes method, it appears that condensed water quantities are mainly depending on the boundary conditions imposed. These conditions are: 1) dimensions of the structure; 2) external temperature and relative hygrometry; 3) the phase φ (T/RH) linking thermal and hydrometric conditions; 4) the air renewing and its hygrometry for each phase; and 5) for each case, the fact that the inside bottom wall can be wet or dry. The resulting condensed water vapour quantities obtained, for the width section, point out clearly that they are very depending on this phase φ (T/RH) which appears as the more significant parameter and can be modified by the presence or not of a thin layer of water vapour on the inside bottom wall. Condensation phenomenon could be increased if φ could be optimized.

  12. Observational characteristics of the tropopause inversion layer derived from CHAMP/GRACE radio occultations and MOZAIC aircraft data

    NASA Astrophysics Data System (ADS)

    Schmidt, T.; Cammas, J.-P.; Smit, H. G. J.; Heise, S.; Wickert, J.; Haser, A.

    2010-12-01

    In this study we discuss characteristics of the Northern Hemisphere (NH) midlatitude (40°N-60°N) tropopause inversion layer (TIL) based on two data sets. First, temperature measurements from GPS radio occultation data (CHAMP and GRACE) for the time interval 2001-2009 are used to exhibit seasonal properties of the TIL bottom height defined here as the height of the squared buoyancy frequency minimum N2 below the thermal tropopause, the TIL maximum height as the height of the N2 maximum above the tropopause, and the TIL top height as the height of the temperature maximum above the tropopause. Mean values of the TIL bottom, TIL maximum, and TIL top heights relative to the thermal tropopause for the NH midlatitudes are (-2.08 ± 0.35) km, (0.52 ± 0.10) km and (2.10 ± 0.23) km, respectively. A seasonal cycle of the TIL bottom and TIL top height is observed with values closer to the thermal tropopause during summer. Secondly, high-resolution temperature and trace gas profile measurements on board commercial aircrafts (Measurement of Ozone and Water Vapor by Airbus In-Service Aircraft (MOZAIC) program) from 2001-2008 for the NH midlatitude (40°N-60°N) region are used to characterize the TIL as a mixing layer around the tropopause. Mean TIL bottom, TIL maximum, and TIL top heights based on the MOZAIC temperature (N2) measurements confirm the results from the GPS data, even though most of the MOZAIC profiles used here are available under cyclonic situations. Further, we demonstrate that the mixing ratio gradients of ozone (O3) and carbon monoxide (CO) are suitable parameters for characterizing the TIL structure.

  13. Observations of Antarctic Slope Current Transport and Dense Water Flow in the Northwestern Weddell Sea

    NASA Astrophysics Data System (ADS)

    Azaneu, M. V. C.; Heywood, K. J.; Queste, B. Y.; Thompson, A. F.

    2016-02-01

    In early 2012 the GENTOO project deployed three Seagliders in the northwest Weddell Sea, acquiring high temporal and spatial resolution measurements around Powell Basin for a period of 10 weeks. The Antarctic Slope Front and associated currents form a physical and dynamical barrier to the cross-slope exchange of properties, influencing local and global ocean dynamics. The Seaglider dataset comprises 1598 temperature and salinity profiles and is used to better understand cross-slope processes. From this dataset, 582 glider profiles with altimetric information at the east Antarctic Peninsula continental slope are used to investigate the properties and thickness of the dense bottom water spilling off the shelf. The dense water is identified mostly over the slope, between the 500 and 1000 m isobaths. The dense layer is thickest around ˜ 63.33 °S, along the 1000 m isobath, becoming thinner onshore and towards northern areas. We also evaluate with unprecedented resolution the along-stream velocity and potential vorticity fields along the 17 transects across the eastern Antarctic Peninsula shelf-break and the 4 transects that cross the South Orkney Islands plateau. Using an improved hydrodynamic flight model, we reference the geostrophic shear to the glider-derived depth-averaged currents corrected for tides. In the western Weddell Sea, the geostrophic velocities fields indicate the presence of a surprisingly weakened Antarctic Slope Current (ASC) around 63.5 °S, possibly indicative of high eddy activity in the area. ASC transport in this southernmost section is less than 0.2 Sv. In a more northerly section (˜ 63.1 °S), the ASC transport reaches 6 Sv. The transects west of the South Orkney Island indicate a northward flow, opposite to the previously assumed regime. The results also show intensified northward bottom flows close to the slope, which can be related to processes occurring in the bottom boundary layer. The potential vorticity fields are used to identify potential instability mechanisms contributing to the cross-slope exchange of water mass properties.

  14. On the formation of glide-snow avalanches

    NASA Astrophysics Data System (ADS)

    Mitterer, C.; Schweizer, J.

    2012-12-01

    On steep slopes the full snowpack can glide on the ground; tension cracks may open and eventually the slope may fail as a glide-snow avalanche. Due to their large mass they have considerable destructive potential. Glide-snow avalanches typically occur when the snow-soil interface is moist or wet so that basal friction is reduced. The occurrence, however, of glide cracks and their evolution to glide avalanches are still poorly understood. Consequently, glides are difficult to predict as (i) not all cracks develop into an avalanche, and (ii) for those that do, the time between crack opening and avalanche event might vary from hours to weeks - or on the other hand be so short that there is no warning at all by crack opening. To improve our understanding we monitored several slopes and related glide snow activity to meteorological data. In addition, we explored conditions that favor the formation of a thin wet basal snowpack layer with a physical-based model representing water and heat flux at the snow-soil interface. The statistical analyses revealed that glide-snow avalanche activity might be associated to an early season and a spring condition. While early season conditions tend to have warm and dry autumns followed by heavy snowfalls, spring conditions showed good agreement with increasing air temperature. The model indicates that energy (summer heat) stored in the ground might be sufficient to melt snow at the bottom of the snowpack. Due to capillary forces, water will rise for a few centimeters into the snowpack and thereby reduce friction at the interface. Alternatively, we demonstrate that also in the absence of melt water production at the bottom of the snowpack water may accumulate in the bottom layer due to an upward flux into the snowpack if a dry snowpack overlies a wet soil. The particular conditions that are obviously required at the snow-soil interface explain the strong winter-to-winter variations in snow gliding.

  15. Particle dynamics in the Eastern Mediterranean Sea: A synthesis based on light transmission, PMC, and POC archives (1991 2001)

    NASA Astrophysics Data System (ADS)

    Karageorgis, Aristomenis P.; Gardner, Wilford D.; Georgopoulos, Dimitris; Mishonov, Alexey V.; Krasakopoulou, Evangelia; Anagnostou, Christos

    2008-02-01

    During the last two decades light transmission (LT) data have been collected routinely in the Eastern Mediterranean Sea, within the framework of several research projects. A procedure was developed to obtain beam attenuation coefficient due to particles ( cp) at 660-670 nm adjusted for variations in mid-depth 'clear' water and instrumental drifts. Data from 3146 stations occupied between 1991 and 2001 were converted to a common format for the analysis of particulate matter (PM) temporal and spatial distribution patterns. The data were separated into 'wet' (December-May) and 'dry' (June-November) periods. The horizontal distribution of beam cp at various depths revealed clearly higher values in the surface nepheloid layer (SNL) in the vicinity of river mouths during the 'wet' period, whilst the increase was negligible during the 'dry' period. In contrast, the bottom nepheloid layer (BNL; 1-10 m above bottom) appeared to be turbid throughout the year, particularly on the continental shelves receiving riverine discharge. This feature is attributed to resuspension and advection of recently deposited bottom sediments due to waves and currents. However, the Eastern Mediterranean as a whole is impoverished in PM in the water column, particularly at depths >200 m. The behavior of surface-water cp revealed a strong relationship to mesoscale dynamic features. Cyclonic eddies, which upwell nutrient-rich waters toward the surface, favor primary production, which was identified as elevated beam cp values. Beam cp was correlated with PM concentration (PMC) and particulate organic carbon (POC) concentration obtained by bottle sampling. Although there were regional differences in the correlations, no significant seasonal variations were observed. Two generic equations were generated that can be used for a first-order estimate of PMC and POC from historical LT measurements conducted in the area, provided that data are handled according to the proposed methodology.

  16. Occurrence and distribution of bisphenol A and alkylphenols in the water of the Gulf of Gdansk (Southern Baltic).

    PubMed

    Staniszewska, Marta; Koniecko, Iga; Falkowska, Lucyna; Krzymyk, Ewelina

    2015-02-15

    In 2011-2012, the concentrations of bisphenol A (BPA), 4-tert-octylophenol (OP) and 4-nonylphenol (NP) in surface and near-bottom water of the Gulf of Gdansk, as well as inflowing rivers, were similar to those in other regions of Europe; BPA from <5.0 to 277.9 ng dm(-3), OP from <1.0 to 834.5 ng dm(-3), and NP from <4.0 to 228.6 ng dm(-3). The atmospheric transportation of phenol derivatives and their deposition into the water of the gulf was indicated by high enrichment factor values (EF) in the sea surface microlayer in relation to the sub-surface layer. The main route of BPA, OP and NP transportation into the waters of the Gulf of Gdansk is the River Vistula. In spring, significant amounts of bisphenol A and 4-nonylphenol were introduced to the coastal zone with meltwater. The main factors affecting the variability of BPA, OP and NP concentrations in surface and near-bottom water, particularly in summer, were increased tourism in the coastal region, water temperature and dissolved oxygen concentration. Copyright © 2014 Elsevier Ltd. All rights reserved.

  17. Dynamics of internal waves on the Southeast Florida shelf: Implications for cross-shelf exchange and turbulent mixing on a barrier reef system

    NASA Astrophysics Data System (ADS)

    Davis, Kristen Alexis

    The dynamics of internal waves shoaling on the Southeast Florida shelf and the resulting stratified turbulence in the shelf bottom boundary layer are investigated using observational studies completed during the summers of 2003-2005. This work is driven by a desire to understand the effects of internal wave-driven flow and the shoreward transport of cool, nutrient-rich water masses on cross-shelf exchange, vertical mixing, and mass transfer to benthic reef organisms. Shelf sea internal wave fields are typically highly variable and dominated by wind and tidal forces. However, this is not necessarily true for outer shelf regions or very narrow shelves where remote physical processes originating over the slope or deep ocean may exert a strong influence on the internal wave climate. During the summers of 2003 and 2004 observational studies were conducted to examine the effects of a western boundary current (the Florida Current), tides, and wind on the mean currents and internal wave field on the outer Southeast Florida shelf. We present evidence that suggests that the Florida Current plays as large a role in the determination of the high frequency internal wave field as tidal forces. These observations and analyses show that it is necessary to include the forcing from the Florida Current meanders and instabilities in order to predict accurately the episodic nature of the internal wave field on the Southeast Florida shelf. Deep ocean and continental shelf processes intersect at the shelf edge and influence the exchange of water masses and their associated characteristics including heat, nutrients, sediment, and larvae across the shelf. Thus, the dynamics of cross-shelf circulation have important consequences for organisms living on the shelf. In the second phase of this work, we investigate physical mechanisms controlling the exchange of water masses during the summer season across the Southeast Florida shelf. A time series of cross-shelf transport from May to August 2003 suggests that, during the summer months, instabilities in the Florida Current and nonlinear internal waves are the primary mechanisms driving cross-shelf transport on the outer shelf Surface tide, wind, and wave-driven transport were found to be small in comparison. Additionally, this data set highlights the importance of baroclinic processes to cross-shelf transport in this region. In the last phase of my research, I sought to investigate how boundary layer dynamics over a rough coral bed were modified by shoaling internal waves and to understand the implications for mixing and mass transfer to the bed. Results are presented from an observational study of the turbulent bottom boundary layer on the outer Southeast Florida shelf in July and August 2005. Turbulence in the reef bottom boundary layer is highly variable in time and is modified by near bed flow, shear, and stratification driven by shoaling internal waves. We examined turbulence in the bottom boundary layer during a typical internal wave event and found that in addition to the episodic onshore transport of cool, subthermocline water masses, with elevated nutrient concentrations, bottom-intensified currents from shoaling internal waves can increase turbulent dissipation and mixing in the reef bottom boundary layer. Additionally, we show that estimates of flux Richardson number, calculated directly from measurements of dissipation and buoyancy flux, support the dependence of R f on turbulent intensity, epsilon/nuN 2, a relationship that has only been previously shown in laboratory and numerical work. While the importance of surface gravity waves in generating turbulent mixing and controlling mass transfer on coral reefs has been well documented in the literature, this work represents the first time the appropriate field data have been collected for a detailed dynamic analysis of the physical effects and biological implications of internal waves on reef ecosystems. Results from these studies suggest that for reef communities exposed to continental shelf and slope processes, internal waves may play an important role in cross-shelf transport and mass transfer to benthic organisms and may be essential to modeling key biological processes, the connectivity of coral populations, or designing and managing marine reserves and fisheries.

  18. Denitrification potential in relation to lithology in five headwater riparian zones.

    PubMed

    Hill, Alan R; Vidon, Philippe G F; Langat, Jackson

    2004-01-01

    The influence of riparian zone lithology on nitrate dynamics is poorly understood. We investigated vertical variations in potential denitrification activity in relation to the lithology and stratigraphy of five headwater riparian zones on glacial till and outwash landscapes in southern Ontario, Canada. Conductive coarse sand and gravel layers occurred in four of the five riparian areas. These layers were thin and did not extend to the field-riparian perimeter in some riparian zones, which limited their role as conduits for ground water flow. We found widespread organic-rich layers at depths ranging from 40 to 300 cm that resulted from natural floodplain processes and the burial of surface soils by rapid valley-bottom sedimentation after European settlement. The organic matter content of these layers varied considerably from 2 to 5% (relic channel deposit) to 5 to 21% (buried soils) and 30 to 62% (buried peat). Denitrification potential (DNP) was measured by the acetylene block method in sediment slurries amended with nitrate. The highest DNP rates were usually found in the top 0- to 15-cm surface soil layer in all riparian zones. However, a steep decline in DNP with depth was often absent and high DNP activity occurred in the deep organic-rich layers. Water table variations in 2000-2002 indicated that ground water only interacted frequently with riparian surface soils between late March and May, whereas subsurface organic layers that sustain considerable DNP were below the water table for most of the year. These results suggest that riparian zones with organic deposits at depth may effectively remove nitrate from ground water even when the water table does not interact with organic-rich surface soil horizons.

  19. A multilayered water column in the Ediacaran Yangtze platform? Insights from carbonate and organic matter paired δ13C

    NASA Astrophysics Data System (ADS)

    Ader, M.; Macouin, M.; Trindade, R. I. F.; Hadrien, M.-H.; Yang, Z.; Sun, Z.; Besse, J.

    2009-10-01

    Large carbon isotope fluctuations have been systematically reported for Ediacaran carbonate rocks, the meaning of which remains controversial. In order to better understand the mechanisms behind such variations, we present new paired δ13C data on carbonates ( δ13C carb) and their associated organic matter ( δ13C org) from a shelf-margin section (Yangjiaping) of the Doushantuo Formation. In this section, the Doushantuo Formation starts with cap dolostones presenting δ13C carb values around - 5‰ and δ13C org values between - 30.3 and - 27.6‰. Up-section, phased variations in δ13C carb and δ13C org describe positive and negative excursions, while their difference (Δ 13C dol-org = δ13C carb - δ13C org) remains around + 29.2‰. These new data allow the first reconstruction of lateral variations of δ13C carb, δ13C org and Δ 13C carb-org for a shelf-to-basin cross-section of the Yangtze platform (South China) after integration with results reported previously for two other sections. Across the Yangtze platform, the isotope signals reveal strong lateral heterogeneities, with complex variations of δ13C carb and Δ 13C dol-org in the inner-shelf section, phased variations in the shelf-margin section with positive δ13C carb and Δ 13C dol-org close to 29‰, and dominantly negative δ13C carb with δ13C org as low as - 35‰ in the basin. These variations are incompatible with the idea that the δ13C carb can systematically be used as a proxy of ocean surface waters. Assuming that δ13C carb are acquired in bottom waters and/or upper sediments, we show that the heterogeneous δ13C carb and Δ 13C dol-org are compatible with a stratified water column composed of up to three layers: (i) an oxic surface layer, where dissolved inorganic carbon (DIC) is probably in isotope equilibrium with the atmosphere; (ii) an intermediate euxinic layer with a lower δ13C DIC due to organic matter oxidation by ongoing sulphate reduction; (iii) a bottom euxinic layer that seems to be restricted to the inner-shelf lagoonal facies, lacking sulphate, containing methane and with a higher δ13C DIC due to DIC production by methanogenesis. If our model holds true, it suggests that not only negative but also positive Ediacaran carbon isotope excursions may reflect ocean stratification, the positive excursion possibly recording a sulphate-free methanogenic layer at the bottom of restricted basins.

  20. Fate of Flumioxazin in Aquatic Plants: Two Algae (Pseudokirchneriella subcapitata, Synechococcus sp.), Duckweed (Lemna sp.), and Water Milfoil (Myriophyllum elatinoides).

    PubMed

    Ando, Daisuke; Fujisawa, Takuo; Katagi, Toshiyuki

    2017-10-11

    Flumioxazin separately 14 C-labeled at 1,2-positions of the tetrahydrophthalimide moiety or uniformly labeled at the phenyl ring was exposed to two algae and duckweed via the water layer and water milfoil via the water layer or bottom sediment for 14 days to investigate uptake and metabolic profiles in these aquatic plants. While 14 C-flumioxazin received immediate hydrolysis through maleimide ring opening and amide bond cleavage with its hydrolytic half-life of <1 day in both water and sediment, the 14 C-plant uptake was ≤4.7% of the applied radioactivity (%AR) with water exposure for all plants and 0.9%AR with sediment exposure for water milfoil. No 14 C-translocation between shoot/leaves and roots occurred in water milfoil. The components of 14 C residues in plants were common among the species, which were the above hydrolysates and their transformation products, that is, dicarboxylic acid derivative metabolized via hydroxylation at the double bond of the cyclohexene ring followed by sugar conjugation with its counterpart amine derivative via acid conjugations.

  1. Application To Bilayer System With Water-Soluble Contrast Enhancing Material

    NASA Astrophysics Data System (ADS)

    Yabuta, Mitsuo; Ito, Naoki; Yamazaki, Hiroyuki; Nakayama, Toshimasa

    1987-09-01

    We have developed ,a water-soluble contrast enhancing material, TAD-436 ( Tokyo Ohka. Anti-Defocus Material ) which is consisted of a water-soluble diazonium salt as bleaching compounds and a water-soluble anion type polymer as binder polymers. Needless to say that water is used as solvent in TAD; therefore, it can be spincoated directly on a positive photoresist layer of a quinonediazide-novolak resin type without causing intermixing and furtheremore the bilayer can be developed without stripping TAD immediately after exposure. TAD shows a satisfactory bleaching characteristics on g-line, increases r-value of underlying photoresist and reduces the thickness loss of photoresist layer in unexposed area. Application to bilayer system with TAD will raise the resolution of underlying photoresist and when the focus depth is changed it will make the change in the resist profile small. As the result of it, the notches in the resist patterns on steps is reduced, making the difference in the linewidth between the top and the bottom of steps small.

  2. Microfossils, a Key to Unravel Cold-Water Carbonate Mound Evolution through Time: Evidence from the Eastern Alboran Sea

    PubMed Central

    Stalder, Claudio; Vertino, Agostina; Rosso, Antonietta; Rüggeberg, Andres; Pirkenseer, Claudius; Spangenberg, Jorge E.; Spezzaferri, Silvia; Camozzi, Osvaldo; Rappo, Sacha; Hajdas, Irka

    2015-01-01

    Cold-water coral (CWC) ecosystems occur worldwide and play a major role in the ocean's carbonate budget and atmospheric CO2 balance since the Danian (~65 m.y. ago). However their temporal and spatial evolution against climatic and oceanographic variability is still unclear. For the first time, we combine the main macrofaunal components of a sediment core from a CWC mound of the Melilla Mounds Field in the Eastern Alboran Sea with the associated microfauna and we highlight the importance of foraminifera and ostracods as indicators of CWC mound evolution in the paleorecord. Abundances of macrofauna along the core reveal alternating periods dominated by distinct CWC taxa (mostly Lophelia pertusa, Madrepora oculata) that correspond to major shifts in foraminiferal and ostracod assemblages. The period dominated by M. oculata coincides with a period characterized by increased export of refractory organic matter to the seafloor and rather unstable oceanographic conditions at the benthic boundary layer with periodically decreased water energy and oxygenation, variable bottom water temperature/density and increased sediment flow. The microfaunal and geochemical data strongly suggest that M. oculata and in particular Dendrophylliidae show a higher tolerance to environmental changes than L. pertusa. Finally, we show evidence for sustained CWC growth during the Alleröd-Younger-Dryas in the Eastern Alboran Sea and that this period corresponds to stable benthic conditions with cold/dense and well oxygenated bottom waters, high fluxes of labile organic matter and relatively strong bottom currents PMID:26447699

  3. [Distributions and influencing factors of total dissolved inorganic antimony in the coastal area of Zhejiang and Fujian].

    PubMed

    Zhang, Xu-Zhou; Ren, Jing-Ling; Liu, Zong-Guang; Fan, Xiao-Peng; Liu, Cheng-Gang; Wu, Ying

    2014-02-01

    Antimony has been ubiquitously present in the aquatic environment as a toxic and rare metalloid element. The contamination of antimony and its compounds in the environment is increasingly severe, so it has been received extensive attention by the international scientific community. The cruise was carried out in the coastal area of Zhejiang and Fujian provinces in the East China Sea (ECS) in May 2008. The concentrations of total dissolved inorganic antimony (TDISb) were measured by Hydride Generation-Atomic Fluorescence (HG-AFS). The concentration ranges of TDISb in the surface and bottom layer were 0.68-5.64 nmol x L(-1) and 0.71-5.25 nmol x L(-1) with averages of 2.25 and 1.79 nmol x L(-1), respectively. The concentration of TDISb in the study area was lower than the environmental quality standards for surface water of China and drinking water standards of World Health Organization (about 41.08 nmol x L(-1)), indicating that it remained at the pristine level. The concentration of TDISb decreased gradually from the coastal area to the central ECS shelf with higher concentration in the surface layer than the bottom. Water mass mixing, adsorption/desorption behavior on the surface of the suspended particulate matters (SPM) and biological activities were the main influence factors of TDISb biogeochemistry in the study area.

  4. Turbulence-enhanced bottom melting of a horizontal glacier--lake interface

    NASA Astrophysics Data System (ADS)

    Keitzl, T.; Mellado, J. P.; Notz, D.

    2014-12-01

    We use laboratory tank experiments and direct numerical simulations to investigate the meltrates of a horizontal bottom glacier--lake interface as a function of lake temperature. Existing parameterisations of such meltrates are usually based on empirical fits to field observations. To understand the meltrates of an ice--water interface more systematically we study an idealised system in terms of its temperature-driven buoyancy forcing. In such systems, the meltrate can be expressed analytically for a stable stratification. Here we investigate the unstable case and present how the meltrate depends on the lake temperature when the water beneath the ice is overturning and turbulent. We use laboratory tank experiments and direct numerical simulations to study an idealised ice--water boundary. The laboratory tank experiments provide robust observation-based mean-temperature profiles. The numerical simulations provide the full three-dimensional structure of the turbulent flow down to scales not accessible in the laboratory, with a minimum 0.2mm gridspacing. Our laboratory mean-temperature profiles agree well with the numerical simulations and lend credibility to our numerical setup. The structure of the turbulent flow in our simulations is well described by two self-similar subregions, a diffusion-dominated inner layer close to the ice and a turbulence-dominated outer layer far from the ice. We provide an explicit expression for the parameterisation of the meltrate of a horizontal glacier--lake interface as a function of lake temperature.

  5. 21 CFR Appendix A to Part 74 - The Procedure for Determining Ether Soluble Material in D&C Red Nos. 6 and 7

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... throughout method.) Allow the funnel to stand until the layers have separated. Transfer the bottom (aqueous) layer to a 500 mL separatory funnel, add 100 mL of ether, stopper and shake for one minute. When the layers have separated, drain off the bottom layer into a waste beaker. Pour the ether layer in the 500 mL...

  6. Bottom-Water Conditions in a Marine Basin after the Cretaceous–Paleogene Impact Event: Timing the Recovery of Oxygen Levels and Productivity

    PubMed Central

    Sosa-Montes De Oca, Claudia; Martínez-Ruiz, Francisca; Rodríguez-Tovar, Francisco Javier

    2013-01-01

    An ultra-high-resolution analysis of major and trace element contents from the Cretaceous–Paleogene boundary interval in the Caravaca section, southeast Spain, reveals a quick recovery of depositional conditions after the impact event. Enrichment/depletion profiles of redox sensitive elements indicate significant geochemical anomalies just within the boundary ejecta layer, supporting an instantaneous recovery –some 102 years– of pre-impact conditions in terms of oxygenation. Geochemical redox proxies point to oxygen levels comparable to those at the end of the Cretaceous shortly after impact, which is further evidenced by the contemporary macrobenthic colonization of opportunistic tracemakers. Recovery of the oxygen conditions was therefore several orders shorter than traditional proposals (104–105 years), suggesting a probable rapid recovery of deep-sea ecosystems at bottom and in intermediate waters. PMID:24349232

  7. The vertical structure of the circulation and dynamics in Hudson Shelf Valley

    USGS Publications Warehouse

    Lentz, Steven J.; Butman, Bradford; Harris, Courtney K.

    2014-01-01

    Hudson Shelf Valley is a 20–30 m deep, 5–10 km wide v-shaped submarine valley that extends across the Middle Atlantic Bight continental shelf. The valley provides a conduit for cross-shelf exchange via along-valley currents of 0.5 m s−1 or more. Current profile, pressure, and density observations collected during the winter of 1999–2000 are used to examine the vertical structure and dynamics of the flow. Near-bottom along-valley currents having times scales of a few days are driven by cross-shelf pressure gradients setup by wind stresses, with eastward (westward) winds driving onshore (offshore) flow within the valley. The along-valley momentum balance in the bottom boundary layer is predominantly between the pressure gradient and bottom stress because the valley bathymetry limits current veering. Above the bottom boundary layer, the flow veers toward an along-shelf (cross-valley) orientation and a geostrophic balance with some contribution from the wind stress (surface Ekman layer). The vertical structure and strength of the along-valley current depends on the magnitude and direction of the wind stress. During offshore flows driven by westward winds, the near-bottom stratification within the valley increases resulting in a thinner bottom boundary layer and weaker offshore currents. Conversely, during onshore flows driven by eastward winds the near-bottom stratification decreases resulting in a thicker bottom boundary layer and stronger onshore currents. Consequently, for wind stress magnitudes exceeding 0.1 N m−2, onshore along-valley transport associated with eastward wind stress exceeds the offshore transport associated with westward wind stress of the same magnitude.

  8. Investigating the importance of sediment resuspension in Alexandrium fundyense cyst population dynamics in the Gulf of Maine

    USGS Publications Warehouse

    Butman, Bradford; Aretxabaleta, Alfredo L.; Dickhudt, Patrick J.; Dalyander, P. Soupy; Sherwood, Christopher R.; Anderson, Donald M.; Keafer, Bruce A.; Signell, Richard P.

    2014-01-01

    Cysts of Alexandrium fundyense, a dinoflagellate that causes toxic algal blooms in the Gulf of Maine, spend the winter as dormant cells in the upper layer of bottom sediment or the bottom nepheloid layer and germinate in spring to initiate new blooms. Erosion measurements were made on sediment cores collected at seven stations in the Gulf of Maine in the autumn of 2011 to explore if resuspension (by waves and currents) could change the distribution of over-wintering cysts from patterns observed in the previous autumn; or if resuspension could contribute cysts to the water column during spring when cysts are viable. The mass of sediment eroded from the core surface at 0.4 Pa ranged from 0.05 kg m−2 near Grand Manan Island, to 0.35 kg m−2 in northern Wilkinson Basin. The depth of sediment eroded ranged from about 0.05 mm at a station with sandy sediment at 70 m water depth on the western Maine shelf, to about 1.2 mm in clayey–silt sediment at 250 m water depth in northern Wilkinson Basin. The sediment erodibility measurements were used in a sediment-transport model forced with modeled waves and currents for the period October 1, 2010 to May 31, 2011 to predict resuspension and bed erosion. The simulated spatial distribution and variation of bottom shear stress was controlled by the strength of the semi-diurnal tidal currents, which decrease from east to west along the Maine coast, and oscillatory wave-induced currents, which are strongest in shallow water. Simulations showed occasional sediment resuspension along the central and western Maine coast associated with storms, steady resuspension on the eastern Maine shelf and in the Bay of Fundy associated with tidal currents, no resuspension in northern Wilkinson Basin, and very small resuspension in western Jordan Basin. The sediment response in the model depended primarily on the profile of sediment erodibility, strength and time history of bottom stress, consolidation time scale, and the current in the water column. Based on analysis of wave data from offshore buoys from 1996 to 2012, the number of wave events inducing a bottom shear stress large enough to resuspend sediment at 80 m ranged from 0 to 2 in spring (April and May) and 0 to 10 in winter (October through March). Wave-induced resuspension is unlikely in water greater than about 100 m deep. The observations and model results suggest that a millimeter or so of sediment and associated cysts may be mobilized in both winter and spring, and that the frequency of resuspension will vary interannually. Depending on cyst concentration in the sediment and the vertical distribution in the water column, these events could result in a concentration in the water column of at least 104 cysts m−3. In some years, resuspension events could episodically introduce cysts into the water column in spring, where germination is likely to be facilitated at the time of bloom formation. An assessment of the quantitative effects of cyst resuspension on bloom dynamics in any particular year requires more detailed investigation.

  9. Facile Fabrication of Composite Membranes with Dual Thermo- and pH-Responsive Characteristics.

    PubMed

    Ma, Bing; Ju, Xiao-Jie; Luo, Feng; Liu, Yu-Qiong; Wang, Yuan; Liu, Zhuang; Wang, Wei; Xie, Rui; Chu, Liang-Yin

    2017-04-26

    Facile fabrication of novel functional membranes with excellent dual thermo- and pH-responsive characteristics has been achieved by simply designing dual-layer composite membranes. pH-Responsive poly(styrene)-block-poly(4-vinylpyridine) (PS-b-P4VP) block copolymers and polystyrene blended with thermoresponsive poly(N-isopropylacrylamide) (PNIPAM) nanogels are respectively used to construct the top layer and bottom layer of composite membranes. The stretching/coiling conformation changes of the P4VP chains around the pK a (∼3.5-4.5) provide the composite membranes with extraordinary pH-responsive characteristics, and the volume phase transitions of PNIPAM nanogels at the pore/matrix interfaces in the bottom layer around the volume phase transition temperature (VPTT, ∼33 °C) provide the composite membranes with great thermoresponsive characteristics. The microstructures, permeability performances, and dual stimuli-responsive characteristics can be well tuned by adjusting the content of PNIPAM nanogels and the thickness of the PS-b-P4VP top layer. The water fluxes of the composite membranes can be changed in order of magnitude by changing the environment temperature and pH, and the dual thermo- and pH-responsive permeation performances of the composite membranes are satisfactorily reversible and reproducible. The membrane fabrication strategy in this work provides valuable guidance for further development of dual stimuli-responsive membranes or even multi stimuli-responsive membranes.

  10. Propagation and Signal Modeling

    NASA Astrophysics Data System (ADS)

    Jensen, Finn B.

    The use of sound in the sea is ubiquitous: Apart from the military aspect of trying to detect an adversary’s mines and submarines, ship-mounted sonars measure water depth, ship speed, and the presence of fish shoals. Side-scan systems are used for mapping the bottom topography, sub-bottom profilers for getting information about the deeper layering, and other sonar systems for locating pipelines and cables on the seafloor. Sound is also used for navigating submerged vehicles, for underwater communications and for tracking marine mammals. Finally, in the realm of ‘acoustical oceanography’ and ‘ocean acoustic tomography,’ sound is used for measuring physical parameters of the ocean environment and for monitoring oceanic processes [1-6].

  11. Accurate ocean bottom seismometer positioning method inspired by multilateration technique

    USGS Publications Warehouse

    Benazzouz, Omar; Pinheiro, Luis M.; Matias, Luis M. A.; Afilhado, Alexandra; Herold, Daniel; Haines, Seth S.

    2018-01-01

    The positioning of ocean bottom seismometers (OBS) is a key step in the processing flow of OBS data, especially in the case of self popup types of OBS instruments. The use of first arrivals from airgun shots, rather than relying on the acoustic transponders mounted in the OBS, is becoming a trend and generally leads to more accurate positioning due to the statistics from a large number of shots. In this paper, a linearization of the OBS positioning problem via the multilateration technique is discussed. The discussed linear solution solves jointly for the average water layer velocity and the OBS position using only shot locations and first arrival times as input data.

  12. Unconsolidated sediments at the bottom of Lake Vostok from seismic data

    USGS Publications Warehouse

    Filina, I.; Lukin, V.; Masolov, V.; Blankenship, D.

    2007-01-01

    Seismic soundings of Lake Vostok have been performed by the Polar Marine Geological Research Expedition in collaboration with the Russian Antarctic Expedition since the early 1990s. The seismograms recorded show at least two relatively closely spaced reflections associated with the lake bottom. These were initially interpreted as boundaries of a layer of unconsolidated sediments at the bottom of the lake. A more recent interpretation suggests that the observed reflections are side echoes from the rough lake bottom, and that there are no unconsolidated sediments at the bottom of the lake. The major goal of this paper is to reveal the nature of those reflections by testing three hypotheses of their origin. The results show that some of the reflections, but not all of them, are consistent with the hypothesis of a non-flat lake bottom along the source-receiver line (2D case). The reflections were also evaluated as side echoes from an adjacent sloping interface, but these tests implied unreasonably steep slopes (at least 8 degrees) at the lake bottom. The hypothesis that is the most compatible with seismic data is the presence of a widespread layer of unconsolidated sediments at the bottom of Lake Vostok. The modeling suggests the presence of a two hundred meter thick sedimentary layer with a seismic velocity of 1700 -1900 m/sec in the southern and middle parts of the lake. The sedimentary layer thickens in the northern basin to ~350 m

  13. Application of Sub-Bottom Profiler to Study Riverbed Structure and Sediment Density

    NASA Astrophysics Data System (ADS)

    Rui, Wang; Changzheng, Li; Xiaofei, Yan

    2018-03-01

    In this pater, we present a study on the riverbed structure and sediment density in-situ test by using sub-bottom profiler. Compared with traditional direct observation methods, the sub-bottom profiler method based on sonar technology is non-contact, low-disturbance and high-efficient. We finish the investigation of several sections in Sanmenxia and Xiaolangdi reservoirs, which located on the main channel of lower reaches of Yellow River. Collected data show a detailed layered structure of the riverbed sediment which believed caused by sedimentary processes in different periods. Further more, we analyse the reflection coefficient of water-sediment interface and inverse the sediment density data from the raw wave record. The inversion method is based on the effective density fluid model and Kozeny-Carman formula. The comparison of the inversion results and sample tests shows that the in-situ test is reliable and useable.

  14. Structures of Xishan village landslide in Li County, Sichuan, China, inferred from high-frequency receiver functions of local earthquakes

    NASA Astrophysics Data System (ADS)

    Wei, Z.; Chu, R.

    2017-12-01

    Teleseismic receiver function methods are widely used to study the deep structural information beneath the seismic station. However, teleseismic waveforms are difficult to extract the high-frequency receiver function, which are insufficient to constrain the shallow structure because of the inelastic attenuation effect of the earth. In this study, using the local earthquake waveforms collected from 3 broadband stations deployed on the Xishan village landslide in Li County in Sichuan Province, we used the high-frequency receiver function method to study the shallow structure beneath the landslide. We developed the Vp-k (Vp/Vs) staking method of receiver functions, and combined with the H-k stacking and waveform inversion methods of receiver functions to invert the landslide's thickness, S-wave velocity and average Vp/Vs ratio beneath these stations, and compared the thickness with the borehole results. Our results show small-scale lateral variety of velocity structure, a 78-143m/s lower S-wave velocity in the bottom layer and 2.4-3.1 Vp/Vs ratio in the landslide. The observed high Vp/Vs ratio and low S-wave velocity in the bottom layer of the landslide are consistent with low electrical resistivity and water-rich in the bottom layer, suggesting a weak shear strength and potential danger zone in landslide h1. Our study suggest that the local earthquake receiver function can obtain the shallow velocity structural information and supply some seismic constrains for the landslide catastrophe mitigation.

  15. Distribution and geochemical composition of suspended particulate material in the shallow embayment of northern Thermaikos Gulf, Greece

    NASA Astrophysics Data System (ADS)

    Tsompanoglou, K.; Anagnostou, Ch.; Krasakopoulou, E.; Pagou, K.; Karageorgis, A. P.; Pavlidou, A.; Albanakis, K.; Tsirambides, A.

    2017-07-01

    The distribution and the chemical composition of Suspended Particulate Matter (SPM), in the northern Thermaikos Gulf, were studied during an annual experiment, carried out from June 2004 to June 2005. Water samples were collected at three depths (1 m below surface, 10 m depth, and 2 m above bottom) and filtered to obtain SPM, particulate organic carbon (POC), total particulate nitrogen (PNtot) and particulate phosphorus (PP) concentrations. SPM and POC concentrations exhibited strong spatial and temporal variations, related to the different environmental characteristics in the study area such as river network, biological productivity, anthropogenic interferences, wind regime, and resuspension of the bottom sediments. The highest SPM concentrations were recorded at the surface (mean = 1.45 ± 0.75 mg/l, maximum value = 11.60 mg/l) and close to the bottom (mean = 1.49 ± 0.67 mg/l, maximum value = 11.72 mg/l), creating surface and bottom nepheloid layers (SNL and BNL), respectively. The maximum values were recorded close to the river mouths; the rivers are identified as the major sources of SPM. The Axios and Aliakmon rivers supplied the gulf with particulate matter, during the entire sampling period. Chemical analysis has revealed the significant correlation among the elements Al, Si, Fe, Ti, K, V, Mg and Ba suggesting the presence of terrigenous aluminosilicate minerals. Silica and Ca have terrigenous origin, but also come from autochthonous biogenic fraction. Chromium, Ni and Co, are of natural origin and derived from mafic and ultramafic rocks of the Axios and Aliakmon watersheds. Copper and Zn are correlated with each other and their distributions follow that of POC; these two metals are derived from partially treated domestic and industrial effluents. The vertical distribution of organic matter implies increased primary production within the upper layer of the water column. Phosphorus is present mainly in an organic form. During the sampling period, the water column was well-oxygenated. Early diagenesis only affected the concentrations of Mn and to a lesser extent Fe in the recently deposited seabed sediment.

  16. Hydrographic survey in the dying Aral Sea

    NASA Astrophysics Data System (ADS)

    Zavialov, P. O.; Kostianoy, A. G.; Emelianov, S. V.; Ni, A. A.; Ishniyazov, D.; Khan, V. M.; Kudyshkin, T. V.

    2003-07-01

    We report the results of a hydrographic survey conducted in November, 2002, in the Uzbekistan part of the western basin of the dying Aral Sea. There were very few hydrographic measurements in this region since at least early 1990s. The salinity in the western deep basin of the Aral Sea varied from about 82 psu at the surface to over 94 psu at the bottom. The absolute lake surface level was about 30.5 m. Hence, the observed salinity values were much higher, and the level much lower, than expected according to earlier predictions. The density in the western basin exhibited an extremely strong stratification of ~11 kg/m3 per ~20 m in the bottom layer. The picnocline was accompanied by a temperature inversion whose magnitude was ~4°C. The observed density stratification effectively isolating the lower part of the water column from surface exchanges may be responsible for the increase of summer SSTs and evaporation rates reported in previous studies. We discovered the hydrogen sulphide contamination in the bottom layer whose upper limit was at the depth of approximately 22 m. Estimates suggest that the western basin salinization occurs not only because of the local evaporation, but also because of the assimilation of the saltier eastern basin water in the course of the interbasin exchange through the connecting channel. The satellite imagery analysis, in particular the Maximum Cross-Correlation method, suggests that the circulation pattern in the Aral Sea in its present limits is cyclonic under the eastern winds that are predominant in the region throughout the year.

  17. Modeling seasonal variability of carbonate system parameters at the sediment -water interface in the Baltic Sea (Gdansk Deep)

    NASA Astrophysics Data System (ADS)

    Protsenko, Elizaveta; Yakubov, Shamil; Lessin, Gennady; Yakushev, Evgeniy; Sokołowski, Adam

    2017-04-01

    A one-dimensional fully-coupled benthic pelagic biogeochemical model BROM (Bottom RedOx Model) was used for simulations of seasonal variability of biogeochemical parameters in the upper sediment, Bottom Boundary Layer and the water column in the Gdansk Deep of the Baltic Sea. This model represents key biogeochemical processes of transformation of C, N, P, Si, O, S, Mn, Fe and the processes of vertical transport in the water column and the sediments. The hydrophysical block of BROM was forced by the output calculated with model GETM (General Estuarine Transport Model). In this study we focused on parameters of carbonate system at Baltic Sea, and mainly on their distributions near the sea-water interface. For validating of BROM we used field data (concentrations of main nutrients at water column and porewater of upper sediment) from the Gulf of Gdansk. The model allowed us to simulate the baseline ranges of seasonal variability of pH, Alkalinity, TIC and calcite/aragonite saturation as well as vertical fluxes of carbon in a region potentially selected for the CCS storage. This work was supported by project EEA CO2MARINE and STEMM-CCS.

  18. Molten metal holder furnace and casting system incorporating the molten metal holder furnace

    DOEpatents

    Kinosz, Michael J.; Meyer, Thomas N.

    2003-02-11

    A bottom heated holder furnace (12) for containing a supply of molten metal includes a storage vessel (30) having sidewalls (32) and a bottom wall (34) defining a molten metal receiving chamber (36). A furnace insulating layer (42) lines the molten metal receiving chamber (36). A thermally conductive heat exchanger block (54) is located at the bottom of the molten metal receiving chamber (36) for heating the supply of molten metal. The heat exchanger block (54) includes a bottom face (65), side faces (66), and a top face (67). The heat exchanger block (54) includes a plurality of electrical heaters (70) extending therein and projecting outward from at least one of the faces of the heat exchanger block (54), and further extending through the furnace insulating layer (42) and one of the sidewalls (32) of the storage vessel (30) for connection to a source of electrical power. A sealing layer (50) covers the bottom face (65) and side faces (66) of the heat exchanger block (54) such that the heat exchanger block (54) is substantially separated from contact with the furnace insulating layer (42).

  19. A photofunctional bottom-up bis(dipyrrinato)zinc(II) complex nanosheet

    PubMed Central

    Sakamoto, Ryota; Hoshiko, Ken; Liu, Qian; Yagi, Toshiki; Nagayama, Tatsuhiro; Kusaka, Shinpei; Tsuchiya, Mizuho; Kitagawa, Yasutaka; Wong, Wai-Yeung; Nishihara, Hiroshi

    2015-01-01

    Two-dimensional polymeric nanosheets have recently gained much attention, particularly top-down nanosheets such as graphene and metal chalcogenides originating from bulk-layered mother materials. Although molecule-based bottom-up nanosheets manufactured directly from molecular components can exhibit greater structural diversity than top-down nanosheets, the bottom-up nanosheets reported thus far lack useful functionalities. Here we show the design and synthesis of a bottom-up nanosheet featuring a photoactive bis(dipyrrinato)zinc(II) complex motif. A liquid/liquid interfacial synthesis between a three-way dipyrrin ligand and zinc(II) ions results in a multi-layer nanosheet, whereas an air/liquid interfacial reaction produces a single-layer or few-layer nanosheet with domain sizes of >10 μm on one side. The bis(dipyrrinato)zinc(II) metal complex nanosheet is easy to deposit on various substrates using the Langmuir–Schäfer process. The nanosheet deposited on a transparent SnO2 electrode functions as a photoanode in a photoelectric conversion system, and is thus the first photofunctional bottom-up nanosheet. PMID:25831973

  20. [Distribution characteristics of dissolved oxygen and mechanism of hypoxia in the upper estuarine zone of the Daliaohe River].

    PubMed

    Yang, Li-Na; Li, Zheng-Yan; Zhang, Xue-Qing

    2011-01-01

    Based on field surveys in the upper estuarine zone of the Daliaohe River in Spring and Summer of 2009, the spatial and temporal distributions of dissolved oxygen were analyzed and the mechanism of hypoxia were preliminarily discussed. The results indicated that DO concentrations were higher in the river mouth and lower in the upper reaches, higher in surface layers and lower in bottom concerning its spatial distribution. For its temporal distribution, DO concentrations were higher in daytime and lower at night, higher in Spring and lower in Summer. The DO concentrations in the upper estuarine zone of the Daliaohe River in Summer ranged between 1.36-4.77 mg/L with an average of 3.44 mg/L. The concentrations in the lower reaches were higher with an average of 3.94 mg/L. A large hypoxia area was recorded in Summer in the upper reaches of the estuary starting from about 45 km away from the river gate with an average DO concentration of 2.33 mg/L and a minimum of 1.36 mg/L. The correlation analysis showed that DO concentration was significantly correlated with nutrients and permanganate index. Excessive discharge of nutrients and organic pollutants were, therefore, main factors causing hypoxia, and water column stratification due to temperature rise in Summer in surface layers led to further reduction of DO in bottom layers of the water.

  1. Observations of transitional tidal boundary layers and their impact on sediment transport in the Great Bay, NH

    NASA Astrophysics Data System (ADS)

    Koetje, K. M.; Foster, D. L.; Lippmann, T. C.

    2017-12-01

    Observations of the vertical structure of tidal flows obtained in 2016 and 2017 in the Great Bay Estuary, NH show evidence of transitional tidal boundary layers at deployment locations on shallow mudflats. High-resolution bottom boundary layer currents, hydrography, turbidity, and bed characteristics were observed with an acoustic Doppler current profiler (ADCP), an acoustic Doppler velocimeter (ADV), conductivity-depth-temperature (CTD) sensors, optical backscatter sensors, multibeam bathymetric surveys, and sediment grab samples and cores. Over the 2.5 m tidal range and at water depths ranging from 0.3 m to 1.5 m at mean lower low water, peak flows ranged from 10 cm/s to 30 cm/s and were primarily driven by the tides. A downward-looking ADCP captured the velocity profile over the lowest 1 m of the water column. Results consistently show a dual-log layer system, with evidence of a lower layer within 15 cm of the bed, another layer above approximately 30 cm from the bed, and a transitional region where the flow field rotates between that the two layers that can be as much as 180 degrees out of phase. CTD casts collected over a complete tidal cycle suggest that the weak thermohaline stratification is not responsible for development of the two layers. On the other hand, acoustic and optical backscatter measurements show spatial and temporal variability in suspended sediments that are dependant on tidal phase. Current work includes an examination of the relationship between sediment concentrations in the water column and velocity profile characteristics, along with an effort to quantify the impact of rotation and dual-log layers on bed stress.

  2. An Eulerian two-phase flow model for sediment transport under realistic surface waves

    NASA Astrophysics Data System (ADS)

    Hsu, T. J.; Kim, Y.; Cheng, Z.; Chauchat, J.

    2017-12-01

    Wave-driven sediment transport is of major importance in driving beach morphology. However, the complex mechanisms associated with unsteadiness, free-surface effects, and wave-breaking turbulence have not been fully understood. Particularly, most existing models for sediment transport adopt bottom boundary layer approximation that mimics the flow condition in oscillating water tunnel (U-tube). However, it is well-known that there are key differences in sediment transport when comparing to large wave flume datasets, although the number of wave flume experiments are relatively limited regardless of its importance. Thus, a numerical model which can resolve the entire water column from the bottom boundary layer to the free surface can be a powerful tool. This study reports an on-going effort to better understand and quantify sediment transport under shoaling and breaking surface waves through the creation of open-source numerical models in the OpenFOAM framework. An Eulerian two-phase flow model, SedFoam (Cheng et al., 2017, Coastal Eng.) is fully coupled with a volume-of-fluid solver, interFoam/waves2Foam (Jacobsen et al., 2011, Int. J. Num. Fluid). The fully coupled model, named SedWaveFoam, regards the air and water phases as two immiscible fluids with the interfaces evolution resolved, and the sediment particles as dispersed phase. We carried out model-data comparisons with the large wave flume sheet flow data for nonbreaking waves reported by Dohmen-Janssen and Hanes (2002, J. Geophysical Res.) and good agreements were obtained for sediment concentration and net transport rate. By further simulating a case without free-surface (mimic U-tube condition), the effects of free-surface, most notably the boundary layer streaming effect on total transport, can be quantified.

  3. Preparation of brightness stabilization agent for lignin containing pulp from biomass pyrolysis oils

    DOEpatents

    Agblevor, Foster A.; Besler-Guran, Serpil

    2001-01-01

    A process for producing a brightness stabilization mixture of water-soluble organic compounds from biomass pyrolysis oils comprising: a) size-reducing biomass material and pyrolyzing the size-reduced biomass material in a fluidized bed reactor; b) separating a char/ash component while maintaining char-pot temperatures to avoid condensation of pyrolysis vapors; c) condensing pyrolysis gases and vapors, and recovering pyrolysis oils by mixing the oils with acetone to obtain an oil-acetone mixture; d) evaporating acetone and recovering pyrolysis oils; e) extracting the pyrolysis oils with water to obtain a water extract; f) slurrying the water extract with carbon while stirring, and filtering the slurry to obtain a colorless filtrate; g) cooling the solution and stabilizing the solution against thermally-induced gelling and solidification by extraction with ethyl acetate to form an aqueous phase lower layer and an organic phase upper layer; h) discarding the upper organic layer and extracting the aqueous layer with ethyl acetate, and discarding the ethyl acetate fraction to obtain a brown-colored solution not susceptible to gelling or solidification upon heating; i) heating the solution to distill off water and other light components and concentrating a bottoms fraction comprising hydroxyacetaldehyde and other non-volatile components having high boiling points; and j) decolorizing the stabilized brown solution with activated carbon to obtain a colorless solution.

  4. Rare earth element association with foraminifera

    NASA Astrophysics Data System (ADS)

    Roberts, Natalie L.; Piotrowski, Alexander M.; Elderfield, Henry; Eglinton, Timothy I.; Lomas, Michael W.

    2012-10-01

    Neodymium isotopes are becoming widely used as a palaeoceanographic tool for reconstructing the source and flow direction of water masses. A new method using planktonic foraminifera which have not been chemically cleaned has proven to be a promising means of avoiding contamination of the deep ocean palaeoceanographic signal by detrital material. However, the exact mechanism by which the Nd isotope signal from bottom waters becomes associated with planktonic foraminifera, the spatial distribution of rare earth element (REE) concentrations within the shell, and the possible mobility of REE ions during changing redox conditions, have not been fully investigated. Here we present REE concentration and Nd isotope data from mixed species of planktonic foraminifera taken from plankton tows, sediment traps and a sediment core from the NW Atlantic. We used multiple geochemical techniques to evaluate how, where and when REEs become associated with planktonic foraminifera as they settle through the water column, reside at the surface and are buried in the sediment. Analyses of foraminifera shells from plankton tows and sediment traps between 200 and 2938 m water depth indicate that only ˜20% of their associated Nd is biogenically incorporated into the calcite structure. The remaining 80% is associated with authigenic metal oxides and organic matter, which form in the water column, and remain extraneous to the carbonate structure. Remineralisation of these organic and authigenic phases releases ions back into solution and creates new binding sites, allowing the Nd isotope ratio to undergo partial equilibration with the ambient seawater, as the foraminifera fall through the water column. Analyses of fossil foraminifera shells from sediment cores show that their REE concentrations increase by up to 10-fold at the sediment-water interface, and acquire an isotopic signature of bottom water. Adsorption and complexation of REE3+ ions between the inner layers of calcite contributes significantly to elevated REE concentrations in foraminifera. The most likely source of REE ions at this stage of enrichment is from bottom waters and from the remineralisation of oxide phases which are in chemical equilibrium with the bottom waters. As planktonic foraminifera are buried below the sediment-water interface redox-sensitive ion concentrations are adjusted within the shells depending on the pore-water oxygen concentration. The concentration of ions which are passively redox sensitive, such as REE3+ ions, is also controlled to some extent by this process. We infer that (a) the Nd isotope signature of bottom water is preserved in planktonic foraminifera and (b) that it relies on the limited mobility of particle reactive REE3+ ions, aided in some environments by micron-scale precipitation of MnCO3. This study indicates that there may be sedimentary environments under which the bottom water Nd isotope signature is not preserved by planktonic foraminifera. Tests to validate other core sites must be carried out before downcore records can be used to interpret palaeoceanographic changes.

  5. Vertical Structure of Ice Cloud Layers From CloudSat and CALIPSO Measurements and Comparison to NICAM Simulations

    NASA Technical Reports Server (NTRS)

    Ham, Seung-Hee; Sohn, Byung-Ju; Kato, Seiji; Satoh, Masaki

    2013-01-01

    The shape of the vertical profile of ice cloud layers is examined using 4 months of CloudSat and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) global measurements taken on January, April, July, and October 2007. Ice clouds are selected using temperature profiles when the cloud base is located above the 253K temperature level. The obtained ice water content (IWC), effective radius, or extinction coefficient profiles are normalized by their layer mean values and are expressed in the normalized vertical coordinate, which is defined as 0 and 1 at the cloud base and top heights, respectively. Both CloudSat and CALIPSO observations show that the maximum in the IWC and extinction profiles shifts toward the cloud bottom, as the cloud depth increases. In addition, clouds with a base reaching the surface in a high-latitude region show that the maximum peak of the IWC and extinction profiles occurs near the surface, which is presumably due to snow precipitation. CloudSat measurements show that the seasonal difference in normalized cloud vertical profiles is not significant, whereas the normalized cloud vertical profile significantly varies depending on the cloud type and the presence of precipitation. It is further examined if the 7 day Nonhydrostatic Icosahedral Atmospheric Model (NICAM) simulation results from 25 December 2006 to 1 January 2007 generate similar cloud profile shapes. NICAM IWC profiles also show maximum peaks near the cloud bottom for thick cloud layers and maximum peaks at the cloud bottom for low-level clouds near the surface. It is inferred that oversized snow particles in the NICAM cloud scheme produce a more vertically inhomogeneous IWC profile than observations due to quick sedimentation.

  6. A new multispectral imaging instrument for in-situ characterization of flocs and colloidal aggregates in natural waters

    NASA Astrophysics Data System (ADS)

    Bostater, Charles R.

    2016-05-01

    In-situ sampling, characterization and quantification of colloidal aggregates and flocs in ambient water is complex but needed in order to understand their role in development and maintenance of moving fluid muds, muck, bottom boundary lutocline layers and nephelometric interfaces in aquatic systems. These bottom boundary interfaces and associated processes contribute to sedimentation, particle deposition and resuspension of total particulate matter and associated nutrients. Increasing the scientific understanding of the above requires advances in environmental sensing instrumentation (passive and active) to successfully understand these aquatic interfaces. Standalone in-situ sensors that automatically perform multiple steps including sampling, separation, and detection have the potential to greatly advance analytical science. A new in-situ multispectral optical camera system for environmental monitoring and surveillance of delicate flocs and related aggregate structures is described. Results of the system show that flocs - 0.1 mm -10.2 mm diameter (mean diameter of 2.77 mm), with a variance of 5.952 mm and a median effective cross-section area of 30 mm2 can be measured using the passive multispectral optical imaging system. The system is lightweight, compact and suitable for shallow or deep water deployment. When combined with fixed station acoustic echogram instruments, nephelometric (turbidity) waves can be easily observed. Time sequential analysis of imagery allows the system to be used as an optical particle velocimetry system (OPVS). Initial shallow water testing resulted in Lagrangian particle velocities of 0.3 to 3 cm sec-1 to be measured. Similar results were obtained from an acoustic velocity current meter (MAVS3) and a Marsh McBirney 201D electromagnetic current meters. When combined with results from direct methods using sondes for estimating sediment mass fluxes, the combined systems provide data necessary for sediment and water quality modeling. The new optical sensor system will help address analytical needs reported in past studies and provides a new standard method and protocol for measuring the movement of sediment and particulates in the aquatic bottom boundary layers.

  7. Two-phase convection in Ganymede's high-pressure ice layer - Implications for its geological evolution

    NASA Astrophysics Data System (ADS)

    Kalousová, Klára; Sotin, Christophe; Choblet, Gaël; Tobie, Gabriel; Grasset, Olivier

    2018-01-01

    Ganymede, the largest moon in the solar system, has a fully differentiated interior with a layer of high-pressure (HP) ice between its deep ocean and silicate mantle. In this paper, we study the dynamics of this layer using a numerical model of two-phase ice-water mixture in two-dimensional Cartesian geometry. While focusing on the generation of water at the silicate/HP ice interface and its upward migration towards the ocean, we investigate the effect of bottom heat flux, the layer thickness, and the HP ice viscosity and permeability. Our results suggest that melt can be generated at the silicate/HP ice interface for small layer thickness ( ≲ 200 km) and high values of heat flux ( ≳ 20 mW m-2) and viscosity ( ≳ 1015 Pa s). Once generated, the water is transported through the layer by the upwelling plumes. Depending on the vigor of convection, it stays liquid or it may freeze before melting again as the plume reaches the temperate (partially molten) layer at the boundary with the ocean. The thickness of this layer as well as the amount of melt that is extracted from it is controlled by the permeability of the HP ice. This process constitutes a means of transporting volatiles and salts that might have dissolved into the melt present at the silicate/HP ice interface. As the moon cools down, the HP ice layer becomes less permeable because the heat flux from the silicates decreases and the HP ice layer thickens.

  8. Bi-layered nanocomposite bandages for controlling microbial infections and overproduction of matrix metalloproteinase activity.

    PubMed

    Anjana, J; Mohandas, Annapoorna; Seethalakshmy, S; Suresh, Maneesha K; Menon, Riju; Biswas, Raja; Jayakumar, R

    2018-04-15

    Chronic diabetic wounds is characterised by increased microbial contamination and overproduction of matrix metalloproteases that would degrade the extracellular matrix. A bi-layer bandage was developed, that promotes the inhibition of microbial infections and matrix metalloprotease (MMPs) activity. Bi-layer bandage containing benzalkonium chloride loaded gelatin nanoparticles (BZK GNPs) in chitosan-Hyaluronic acid (HA) as a bottom layer and sodium alendronate containing chitosan as top layer was developed. We hypothesized that the chitosan-gelatin top layer with sodium alendronate could inhibit the MMPs activity, whereas the chitosan-HA bottom layer with BZK GNPs (240±66nm) would enable the elimination of microbes. The porosity, swelling and degradation nature of the prepared Bi-layered bandage was studied. The bottom layer could degrade within 4days whereas the top layer remained upto 7days. The antimicrobial activity of the BZK NPs loaded bandage was determined using normal and clinical strains. Gelatin zymography shows that the proteolytic activity of MMP was inhibited by the bandage. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Interplay of water and reactive elements in oxidation of alumina-forming alloys.

    PubMed

    Mortazavi, N; Geers, C; Esmaily, M; Babic, V; Sattari, M; Lindgren, K; Malmberg, P; Jönsson, B; Halvarsson, M; Svensson, J E; Panas, I; Johansson, L G

    2018-06-11

    High-temperature alloys are crucial to many important technologies that underpin our civilization. All these materials rely on forming an external oxide layer (scale) for corrosion protection. Despite decades of research on oxide scale growth, many open questions remain, including the crucial role of the so-called reactive elements and water. Here, we reveal the hitherto unknown interplay between reactive elements and water during alumina scale growth, causing a metastable 'messy' nano-structured alumina layer to form. We propose that reactive-element-decorated, hydroxylated interfaces between alumina nanograins enable water to access an inner cathode in the bottom of the scale, at odds with the established scale growth scenario. As evidence, hydride-nanodomains and reactive element/hydrogen (deuterium) co-variation are observed in the alumina scale. The defect-rich alumina subsequently recrystallizes to form a protective scale. First-principles modelling is also performed to validate the RE effect. Our findings open up promising avenues in oxidation research and suggest ways to improve alloy properties.

  10. Improved Stability and Performance of Visible Photoelectrochemical Water Splitting on Solution-Processed Organic Semiconductor Thin Films by Ultrathin Metal Oxide Passivation

    DOE PAGES

    Wang, Lei; Yan, Danhua; Shaffer, David W.; ...

    2017-12-27

    Solution-processable organic semiconductors have potentials as visible photoelectrochemical (PEC) water splitting photoelectrodes due to their tunable small band gap and electronic energy levels, but they are typically limited by poor stability and photocatalytic activity. In this study, we demonstrate the direct visible PEC water oxidation on solution-processed organic semiconductor thin films with improved stability and performance by ultrathin metal oxide passivation layers. N-type fullerene-derivative thin films passivated by sub-2 nm ZnO via atomic layer deposition enabled the visible PEC water oxidation at wavelengths longer than 600 nm in harsh alkaline electrolyte environments with up to 30 μA/cm 2 photocurrents atmore » the thermodynamic water-oxidation equilibrium potential and the photoanode half-lifetime extended to ~1000 s. The systematic investigation reveals the enhanced water oxidation catalytic activity afforded by ZnO passivation and the charge tunneling governing the hole transfer through passivation layers. Further enhanced PEC performances were realized by improving the bottom ohmic contact to the organic semiconductor, achieving ~60 μA/cm 2 water oxidation photocurrent at the equilibrium potential, the highest values reported for organic semiconductor thin films to our knowledge. The improved stability and performance of passivated organic photoelectrodes and discovered design rationales provide useful guidelines for realizing the stable visible solar PEC water splitting based on organic semiconductor thin films.« less

  11. Improved Stability and Performance of Visible Photoelectrochemical Water Splitting on Solution-Processed Organic Semiconductor Thin Films by Ultrathin Metal Oxide Passivation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wang, Lei; Yan, Danhua; Shaffer, David W.

    Solution-processable organic semiconductors have potentials as visible photoelectrochemical (PEC) water splitting photoelectrodes due to their tunable small band gap and electronic energy levels, but they are typically limited by poor stability and photocatalytic activity. In this study, we demonstrate the direct visible PEC water oxidation on solution-processed organic semiconductor thin films with improved stability and performance by ultrathin metal oxide passivation layers. N-type fullerene-derivative thin films passivated by sub-2 nm ZnO via atomic layer deposition enabled the visible PEC water oxidation at wavelengths longer than 600 nm in harsh alkaline electrolyte environments with up to 30 μA/cm 2 photocurrents atmore » the thermodynamic water-oxidation equilibrium potential and the photoanode half-lifetime extended to ~1000 s. The systematic investigation reveals the enhanced water oxidation catalytic activity afforded by ZnO passivation and the charge tunneling governing the hole transfer through passivation layers. Further enhanced PEC performances were realized by improving the bottom ohmic contact to the organic semiconductor, achieving ~60 μA/cm 2 water oxidation photocurrent at the equilibrium potential, the highest values reported for organic semiconductor thin films to our knowledge. The improved stability and performance of passivated organic photoelectrodes and discovered design rationales provide useful guidelines for realizing the stable visible solar PEC water splitting based on organic semiconductor thin films.« less

  12. On influencing factors of hypoxia in waters adjacent to the Changjiang estuary

    NASA Astrophysics Data System (ADS)

    Luo, Xiaofan; Wei, Hao; Fan, Renfu; Liu, Zhe; Zhao, Liang; Lu, Youyu

    2018-01-01

    Based on observational data from ten cruises carried out in 2012 and 2013, the distribution of dissolved oxygen (DO) and the evolution of hypoxia (DO concentrations < 2.0 mg L-1) in waters adjacent to the Changjiang estuary are studied. The linkage between summer hypoxia and hydrodynamic conditions is explored. The results suggest that hypoxia frequently occurred from June to October to the south of the Changjiang estuary near the 30-50 m isobaths and was prone to happening under strong stratification without the presence of the Kuroshio Subsurface Water (KSW). Over the Changjiang Bank, hypoxia mainly occurred in July, August and September. Low-oxygen areas initially appeared under strong stratification induced by the spreading of the Changjiang Diluted Water (CDW), and developed into hypoxic zones due to lack of DO replenishment from the relatively DO-rich Yellow Sea Water and the KSW. The yearly evolution of hypoxia was influenced by shelf circulation especially the path of the KSW in the bottom layer of the water to the south of the Changjiang estuary, and the extension of the CDW in the surface layer over the Changjiang Bank.

  13. Observations of pockmark flow structure in Belfast Bay, Maine, Part 1: current-induced mixing

    USGS Publications Warehouse

    Fandel, Christina L.; Lippmann, Thomas C.; Irish, James D.; Brothers, Laura L.

    2017-01-01

    Field observations of current profiles and temperature, salinity, and density structure were used to examine vertical mixing within two pockmarks in Belfast Bay, Maine. The first is located in 21 m water depth (sea level to rim), nearly circular in shape with a 45 m rim diameter and 12 m rim-to-bottom relief. The second is located in 25 m water depth, more elongated in shape with an approximately 80 m (36 m) major (minor) axis length at the rim, and 17 m relief. Hourly averaged current profiles were acquired from bottom-mounted acoustic Doppler current profilers deployed on the rim and center of each pockmark over successive 42 h periods in July 2011. Conductivity–temperature–depth casts at the rim and center of each pockmark show warmer, fresher water in the upper water column, evidence of both active and fossil thermocline structure 5–8 m above the rim, and well-mixed water below the rim to the bottom. Vertical velocities show up- and down-welling events that extend into the depths of each pockmark. An observed temperature change at both the rim and center occurs coincident with an overturning event below the rim, and suggests active mixing of the water column into the depths of each pockmark. Vertical profiles of horizontal velocities show depth variation at both the center and rim consistent with turbulent logarithmic current boundary layers, and suggest that form drag may possibly be influencing the local flow regime. While resource limitations prevented observation of the current structure and water properties at a control site, the acquired data suggest that active mixing and overturning within the sampled pockmarks occur under typical benign conditions, and that current flows are influenced by upstream bathymetric irregularities induced by distant pockmarks.

  14. The effect of annealing on the MR and exchange bias characteristics in dual spin valve with nano-oxide layer

    NASA Astrophysics Data System (ADS)

    Jang, S. H.; Kang, T.; Kim, H. J.; Kim, K. Y.

    2002-02-01

    We investigated magnetoresistance (MR) and exchange bias properties by annealing in the dual spin valve (SV) with nano-oxide layer (NOL). By analyzing effects of NOL in top and bottom pinned simple SVs, MR enhancement effect of NOL inserted in the bottom pinned layer was higher than that of NOL in the top pinned layer with annealing. By the enhanced specular scattering of electrons by NOL, the MR ratio of dual SV with NOL was increased to 15.5-15.9% with an annealing of 200-250°C. Exchange coupling constant Jex was improved rapidly as 0.13-0.16 erg/cm 2 by annealing in the bottom pinned layer, whereas the effect of annealing was not large in the top pinned layer with Jex of about 0.09-0.116 erg/cm 2.

  15. Sediment size fractionation and focusing in the equatorial Pacific: Effect on 230Th normalization and paleoflux measurements

    NASA Astrophysics Data System (ADS)

    Lyle, Mitchell; Marcantonio, Franco; Moore, Willard S.; Murray, Richard W.; Huh, Chih-An; Finney, Bruce P.; Murray, David W.; Mix, Alan C.

    2014-07-01

    We use flux, dissolution, and excess 230Th data from the Joint Global Ocean Flux Study and Manganese Nodule Project equatorial Pacific study Site C to assess the extent of sediment focusing in the equatorial Pacific. Measured mass accumulation rates (MAR) from sediment cores were compared to reconstructed MAR by multiplying the particulate rain caught in sediment traps by the 230Th focusing factor and subtracting measured dissolution. CaCO3 MAR is severely overestimated when the 230Th focusing factor correction is large but is estimated correctly when the focusing factor is small. In contrast, Al fluxes in the sediment fine fraction are well matched when the focusing correction is used. Since CaCO3 is primarily a coarse sediment component, we propose that there is significant sorting of fine and coarse sediments during lateral sediment transport by weak currents. Because CaCO3 does not move with 230Th, normalization typically overcorrects the CaCO3 MAR; and because CaCO3 is 80% of the total sediment, 230Th normalization overestimates lateral sediment flux. Fluxes of 230Th in particulate rain caught in sediment traps agree with the water column production-sorption model, except within 500 m of the bottom. Near the bottom, 230Th flux measurements are as much as 3 times higher than model predictions. There is also evidence for lateral near-bottom 230Th transport in the bottom nepheloid layer since 230Th fluxes caught by near-bottom sediment traps are higher than predicted by resuspension of surface sediments alone. Resuspension and nepheloid layer transport under weak currents need to be better understood in order to use 230Th within a quantitative model of lateral sediment transport.

  16. Observations of the boiling process from a downward-facing torispherical surface: Confirmatory testing of the heavy water new production reactor flooded cavity design

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chu, T.Y.; Bentz, J.H.; Simpson, R.B.

    1995-06-01

    Reactor-scale ex-vessel boiling experiments were performed in the CYBL facility at Sandia National Laboratories. The boiling flow pattern outside the RPV bottom head shows a center pulsating region and an outer steady two-phase boundary layer region. The local heat transfer data can be correlated in terms of a modified Rohsenow correlation.

  17. Inversion of ocean-bottom seismometer (OBS) waveforms for oceanic crust structure: a synthetic study

    NASA Astrophysics Data System (ADS)

    Li, Xueyan; Wang, Yanbin; Chen, Yongshun John

    2016-08-01

    The waveform inversion method is applied—using synthetic ocean-bottom seismometer (OBS) data—to study oceanic crust structure. A niching genetic algorithm (NGA) is used to implement the inversion for the thickness and P-wave velocity of each layer, and to update the model by minimizing the objective function, which consists of the misfit and cross-correlation of observed and synthetic waveforms. The influence of specific NGA method parameters is discussed, and suitable values are presented. The NGA method works well for various observation systems, such as those with irregular and sparse distribution of receivers as well as single receiver systems. A strategy is proposed to accelerate the convergence rate by a factor of five with no increase in computational complexity; this is achieved using a first inversion with several generations to impose a restriction on the preset range of each parameter and then conducting a second inversion with the new range. Despite the successes of this method, its usage is limited. A shallow water layer is not favored because the direct wave in water will suppress the useful reflection signals from the crust. A more precise calculation of the air-gun source signal should be considered in order to better simulate waveforms generated in realistic situations; further studies are required to investigate this issue.

  18. Parameterized code SHARM-3D for radiative transfer over inhomogeneous surfaces.

    PubMed

    Lyapustin, Alexei; Wang, Yujie

    2005-12-10

    The code SHARM-3D, developed for fast and accurate simulations of the monochromatic radiance at the top of the atmosphere over spatially variable surfaces with Lambertian or anisotropic reflectance, is described. The atmosphere is assumed to be laterally uniform across the image and to consist of two layers with aerosols contained in the bottom layer. The SHARM-3D code performs simultaneous calculations for all specified incidence-view geometries and multiple wavelengths in one run. The numerical efficiency of the current version of code is close to its potential limit and is achieved by means of two innovations. The first is the development of a comprehensive precomputed lookup table of the three-dimensional atmospheric optical transfer function for various atmospheric conditions. The second is the use of a linear kernel model of the land surface bidirectional reflectance factor (BRF) in our algorithm that has led to a fully parameterized solution in terms of the surface BRF parameters. The code is also able to model inland lakes and rivers. The water pixels are described with the Nakajima-Tanaka BRF model of wind-roughened water surface with a Lambertian offset, which is designed to model approximately the reflectance of suspended matter and of a shallow lake or river bottom.

  19. Parameterized code SHARM-3D for radiative transfer over inhomogeneous surfaces

    NASA Astrophysics Data System (ADS)

    Lyapustin, Alexei; Wang, Yujie

    2005-12-01

    The code SHARM-3D, developed for fast and accurate simulations of the monochromatic radiance at the top of the atmosphere over spatially variable surfaces with Lambertian or anisotropic reflectance, is described. The atmosphere is assumed to be laterally uniform across the image and to consist of two layers with aerosols contained in the bottom layer. The SHARM-3D code performs simultaneous calculations for all specified incidence-view geometries and multiple wavelengths in one run. The numerical efficiency of the current version of code is close to its potential limit and is achieved by means of two innovations. The first is the development of a comprehensive precomputed lookup table of the three-dimensional atmospheric optical transfer function for various atmospheric conditions. The second is the use of a linear kernel model of the land surface bidirectional reflectance factor (BRF) in our algorithm that has led to a fully parameterized solution in terms of the surface BRF parameters. The code is also able to model inland lakes and rivers. The water pixels are described with the Nakajima-Tanaka BRF model of wind-roughened water surface with a Lambertian offset, which is designed to model approximately the reflectance of suspended matter and of a shallow lake or river bottom.

  20. The interplay between estuarine transport and biogeochemical processes in determining the nutrient conditions in bottom layers of non-tidal Gulf of Finland

    NASA Astrophysics Data System (ADS)

    Kõuts, Mariliis; Raudsepp, Urmas; Maljutenko, Ilja

    2017-04-01

    In coastal areas, especially estuaries, spatial distribution and seasonal cycling of chemical and biological variables is largely determined by local biogeochemical processes and water transport of different properties. In tidal estuaries, however, biogeochemical processes are affected by tides as frequent water exchange alters nutrient and oxygen concentrations. In wide and deep non-tidal estuary-type marginal seas spatial distribution and seasonal cycling are determined by the mixture of water transport and local biogeochemistry. The Baltic Sea is a stratified water basin where halocline divides the water column into two parts: upper layer, which is horizontally uniform in terms of distribution of chemical and biological parameters, and has clear seasonal cycle; and bottom part, where nutrient and oxygen dynamics is more complex. There water transport and sediment-water interface fluxes play a major role. Our prime focus is the Gulf of Finland in the Baltic Sea. It is a wide, non-tidal and stratified sub-basin known for its high nutrient concentrations and severe oxygen deficiency in summer. We modelled the Baltic Sea (including Gulf of Finland) using ERGOM, a biogeochemical model coupled with circulation model GETM. Seasonal cycling and water circulation were observed with a 40-year simulation from 1966 to 2006. Our results show that in shallow areas above halocline the seasonal cycle of phytoplankton, nutrients and oxygen concentrations is uniform in space. Water circulation does not create inhomogeneous distribution pattern of biogeochemical parameters and their seasonal cycle. The circulation in the Gulf of Finland is strongly modulated by the seasonality of estuarine transport. Below the halocline saline low-oxygen and nutrient-rich water is transported from the open Baltic Proper to the Gulf of Finland in spring and early summer. This results in the highest nutrient concentrations and the poorest oxygen conditions by the end of August. In the shallow area nutrients have high concentrations in March-April before the spring bloom of diatoms starts. Low oxygen and nutrient concentrations are observed at the end of August. There is a qualitative difference of nutrient dynamics between shallow and deep layers but quantification of the role of transport and local biogeochemical processes is still challenging.

  1. Enhanced particle fluxes and heterotrophic bacterial activities in Gulf of Mexico bottom waters following storm-induced sediment resuspension

    NASA Astrophysics Data System (ADS)

    Ziervogel, K.; Dike, C.; Asper, V.; Montoya, J.; Battles, J.; D`souza, N.; Passow, U.; Diercks, A.; Esch, M.; Joye, S.; Dewald, C.; Arnosti, C.

    2016-07-01

    Bottom nepheloid layers (BNLs) in the deep sea transport and remobilize considerable amounts of particulate matter, enhancing microbial cycling of organic matter in cold, deep water environments. We measured bacterial abundance, bacterial protein production, and activities of hydrolytic enzymes within and above a BNL that formed in the deep Mississippi Canyon, northern Gulf of Mexico, shortly after Hurricane Isaac had passed over the study area in late August 2012. The BNL was detected via beam attenuation in CTD casts over an area of at least 3.5 km2, extending up to 200 m above the seafloor at a water depth of 1500 m. A large fraction of the suspended matter in the BNL consisted of resuspended sediments, as indicated by high levels of lithogenic material collected in near-bottom sediment traps shortly before the start of our sampling campaign. Observations of suspended particle abundance and sizes throughout the water column, using a combined camera-CTD system (marine snow camera, MSC), revealed the presence of macroaggregates (>1 mm in diameter) within the BNL, indicating resuspension of canyon sediments. A distinct bacterial response to enhanced particle concentrations within the BNL was evident from the observation that the highest enzymatic activities (peptidase, β-glucosidase) and protein production (3H-leucine incorporation) were found within the most particle rich sections of the BNL. To investigate the effects of enhanced particle concentrations on bacterial activities in deep BNLs more directly, we conducted laboratory experiments with roller bottles filled with bottom water and amended with experimentally resuspended sediments from the study area. Macroaggregates formed within 1 day from resuspended sediments; by day 4 of the incubation bacterial cell numbers in treatments with resuspended sediments were more than twice as high as in those lacking sediment suspensions. Cell-specific enzymatic activities were also generally higher in the sediment-amended compared to the unamended treatments. The broader range and higher activities of polysaccharide hydrolases in the presence of resuspended sediments compared to the unamended water reflected enzymatic capabilities typical for benthic bacteria. Our data suggest that the formation of BNLs in the deep Gulf of Mexico can lead to transport of sedimentary organic matter into bottom waters, stimulating bacterial food web interactions. Such storm-induced resuspension may represent a possible mechanism for the redistribution of sedimented oil-fallout from the Deepwater Horizon spill in 2010.

  2. Sediment transport processes at the head of Halibut Canyon, Eastern Canada margin: An interplay between internal tides and dense shelf water cascading.

    NASA Astrophysics Data System (ADS)

    Puig, Pere; Greenan, Blair J. W.; Li, Michael Z.; Prescott, Robert H.; Piper, David J. W.

    2013-04-01

    To investigate the processes by which sediment is transported through a submarine canyon incised in a glaciated margin, the bottom boundary layer quadrapod RALPH was deployed at 276-m depth in the West Halibut Canyon (off Newfoundland) during winter 2008-2009. Two main sediment transport processes were identified throughout the deployment. Firstly, periodic increases of near-bottom suspended-sediment concentrations (SSC) were recorded associated with the up-canyon propagation of the semidiurnal internal tidal bore along the canyon axis, carrying fine sediment particles resuspended from deeper canyon regions. The recorded SSC peaks, lasting less than one hour, were observed sporadically and were linked to bottom intensified up-canyon flows concomitant with sharp drops in temperature. Secondly, sediment transport was also observed during events of intensified down-canyon current velocities that occurred during periods of sustained heat loss from surface waters, but were not associated with large storms. High-resolution velocity profiles throughout the water column during these events revealed that the highest current speeds (~1 m s-1) were centered several meters above the sea floor and corresponded to the region of maximum velocities of a gravity flow. Such flows had associated low SSC and cold water temperatures and have been interpreted as dense shelf water cascading events channelized along the canyon axis. Sediment transport during these events was largely restricted to bedload and saltation, producing winnowing of sands and fine sediments around larger gravel particles. Analysis of historical hydrographic data suggests that the origin of such gravity flows is not related to the formation of coastal dense waters advected towards the canyon head. Rather, the dense shelf waters appear to be generated around the outer shelf, where convection during winter is able to reach the sea floor and generate a pool of near-bottom dense water that cascades into the canyon during one or two tidal cycles. A similar transport mechanism can occur in other submarine canyons along the eastern Canadian margin, as well in other canyoned regions elsewhere, where winter convection generally reaches the shelf-edge.

  3. Magnetic Mineral diagenesis in changing water environments in the Black Sea since ˜41.6 ka

    NASA Astrophysics Data System (ADS)

    Liu, Jiabo; Nowaczyk, Norbert; Frank, Ute; Arz, Helge

    2017-04-01

    Magnetic mineral diagenesis plays a key role in the global iron cycle. To understand the authigenic magnetic mineral formation by diagenesis is also fundamentally important for the interpretation of environmental magnetic as well as paleomagnetic signals. Core MSM33-55-1, recovered from the SW Black Sea, was subjected to rock-magnetic and SEM studies. The results demonstrate that four different magnetic mineral assemblages associated to specific water conditions can be observed. Between ˜41.6 ka and ˜19 ka, magnetite and greigite are alternatively in dominance in the sediment. Due to low organic matter input during the late MIS 3 and the last glacial maximum (LGM), oxygenated bottom water in the Black Sea was favourable for preserving detrital magnetite. Greigite in this interval have irregular shapes and assemble in spots, which were formed in a micro environment with limited sulfate availability. Between ˜19 ka and ˜16.5 ka, black layers were deposited as a result of organic matter accumulation induced by productivity blooming and riverine discharge soaring after the LGM. Hence less oxygenated bottom water conditions developed, and more fine grained greigite was formed. After melt-water pulse (MWP) events (˜16.5 ka), both primary productivity and the sea level were continuously rising until ˜8.3 ka, leading to the depletion of oxygen in bottom water. In addition to greigite, pyrite was also formed and gradually in dominance as approaching the Holocene. The influx of salt water masses from the Mediterranean Sea after ˜8.3 ka contributed to the establishment of the anoxic Black Sea, which resulted in the formation of ubiquitous frambiods of pyrite. Additionally, bacterial magnetic minerals are likely present in the sediment younger than ˜8.3 ka as indicated by rock magnetic results. In this paper, four different magnetic mineral assemblages, reflecting gradual changes from an oxic to an anoix Black Sea, were identified, yielding insights into the relation between magnetic minerals diagenesis and bottom water conditions.

  4. Oceanographic controls over sediment water content: northern Bermuda rise

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Baker, M.; Laine, E.P.

    1985-01-01

    Cores taken from the plateaus of Northern Bermuda Rise show that the region is underlain at depths of 1-5 m by a 1-3 m thick layer of hemipelagic lutites with anomalously high water contents. The lack of visually apparent textural and lithological changes in this extremely fine grained sediment rule out these common causes for variation in water content. The water content averages 175% within this layer and 100% immediately above and below it. This is an increase of 9.5% in porosity. The high water content sediment is confined to a period between 12 and 16 ka. Current work onmore » the mineralogy of the sediments which comprise this layer suggest two oceanographic factors that may have influenced its formation. A meltwater spike associated with deglaciation may have altered the ecological conditions above the thermocline sufficiently to promote the increased production of radiolaria, resulting in the deposition of silica enriched sediment on the sea floor. A combination of textural and perhaps chemical factors caused by the silica enrichment may have influenced the increase in water content. Intensified bottom currents at this time also may have eroded smectite rich sediments from exposures of Neogene age and deposited them on the plateaus. An increase in smectite would increase the water content due to the extremely fine grain size and the chemistry of the clay. Thus, the lateral continuity and isochroniety of this layer, combined with its mineralogical characteristics suggests that oceanographic changes can influence water content and perhaps other geotechnical properties on a regional scale.« less

  5. Taking into Account Interelement Interference in X-Ray Fluorescence Analysis of Thin Two-Layer Ti/V Systems

    NASA Astrophysics Data System (ADS)

    Mashin, N. I.; Razuvaev, A. G.; Cherniaeva, E. A.; Gafarova, L. M.; Ershov, A. V.

    2018-03-01

    We propose a new method for determining the thickness of layers in x-ray fluorescence analysis of two-layer Ti/V systems, using easily fabricated standardized film layers obtained by sputter deposition of titanium on a polymer film substrate. We have calculated correction factors taking into account the level of attenuation for the intensity of the primary emission from the x-ray tube and the analytical line for the element of the bottom layer in the top layer, and the enhancement of the fluorescence intensity for the top layer by the emission of atoms in the bottom layer.

  6. Tsunami process: From upper mantle to atmosphere

    NASA Astrophysics Data System (ADS)

    Ershov, S.; Mikhaylovskaya, I.; Novik, O.

    Earthquakes in near sea regions and/or tsunamis are manifestations of powerful geodynamic processes beneath the Ocean floor (75 % of the Earth' surface). An effective monitoring of these large-scale processes is not possible without satellites as well as without understanding of physical nature of signals accompanying these processes, e.g. connection between parameters of a seismic excitation in ocean lithosphere and electromagnetic (EM) signals in atmosphere. Basing on the theory of elasticity, electrodynamics, fluid dynamics and geophysical data we formulate a nonlinear mathematical model of generation and propagation of seismo-EM signals in the basin of a marginal sea including transfer of seismic and EM energy from upper mantle to hydrosphere and EM emission into atmosphere up to ionosphere domain D. For a model basin approximately similar to the central part of the Sea of Japan, we calculate signals caused by moderate elastic displacements (EDs): the ampl of a few cm, the main freq. 0.01-10 Hz and duration up to 10 sec (by runs with different acceptable data) which are supposed to be arising at the moment t=0 at the bottom of the upper mantle layer M. The EM signal appears near the bottom of the conductive (0.02 S/m) layer M and reaches for the sea bottom by t=3.5 sec with the ampl. Of 50 pT. This signal propagate in sea water (4 S/m) rather slowly and seems to be "frozen": its front is located near the sea bottom and is replicating the bottom's configuration up to the moment (t=5.2 sec) of the seismic P wave (from M) arrival at the sea bottom. The EM field is generated in seismically disturbed sea water in presence of the geomagnetic field" a specific structure of a seismo-hydrodynamic flow, a spatial break of the diffusive magnetic field, joining of its contours, and other details of the seismo-hydro-EM tsunami process are shown to clear out the out the physical nature of its signals. By the moderate EDs (above), the magnetic signal (freq. 0.01-10 Hz, i.e. the same as the EDs' freq.) is of order of a few hundreds of pT at the ocean-atmosphere interface and of order of a few tens of hydrodynamic wave's amplitude far from the shore is too small (20 cm) and EM observations are needed to discover this threatening wave. The computed signals' characteristics are of orders observed. The recommendations for the EM monitoring (at a sea bottom, surface, and atmosphere) of seismic excitations in ocean lithosphere and tsunamis are given.

  7. Early transformation of the Mediterranean Outflow Water (MOW) in the Gulf Of Cádiz, SW Iberian Peninsula: pathways, mixing and temporal variability.

    NASA Astrophysics Data System (ADS)

    Sánchez Leal, Ricardo F.; Sánchez Garrido, José Carlos; Jesús Bellanco Esteban, María; Ruiz Villarreal, Manuel; González-Pola Muñiz, César

    2014-05-01

    The inverse estuarine circulation through the strait of Gibraltar is responsible for the overflow of dense, saline MOW towards the Atlantic basin. Initially as a gravity undercurrent, the MOW entrains large amounts of the overlying Eastern North Atlantic Central Water to become a multi-layered, buoyant plume at depths of 800-1300 m past Cape St. Vincent. Much of the entrainment occurs within 100 km of the Strait over a highly abrupt topography. In this work we analyze a repeated series of high-resolution CTD-LADCP observations along a number of standard sections crossing the early MOW. These data show that from the Strait of Gibraltar, the bottom-trapped flow bifurcates in the vicinity of the topographic features, diverting or rejoining the main MOW path as a function of the orientation of channels and valleys. As it turns anticyclonically, the undercurrent exhibits a cross-axis geostrophic gradient, with the margin closer to the slope being in near-geostrophic balance whereas the distal band is largely ageostrophic due to the flow curvature. Mixing is steered by the interplay of tidal stirring, bottom roughness, shear instability and double diffusion along the MOW path. Data also shows that seasonal variability is mostly related to the fluctuations in the overlying layer rather than to MOW dynamics. This is a contribution to INGRES3 project (Mediterranean outflow at Gibraltar, its influence on deep Mediterranean water ventilation and first transformation and coupling with North-Atlantic central waters in the Gulf of Cádiz, CTM2010_21229)

  8. Phylogenetic shifts of bacterioplankton community composition along the Pearl Estuary: the potential impact of hypoxia and nutrients

    PubMed Central

    Liu, Jiwen; Fu, Bingbing; Yang, Hongmei; Zhao, Meixun; He, Biyan; Zhang, Xiao-Hua

    2015-01-01

    The significance of salinity in shaping bacterial communities dwelling in estuarine areas has been well documented. However, the influences of other environmental factors such as dissolved oxygen and nutrients in determining distribution patterns of both individual taxa and bacterial communities inhabited local estuarine regions remain elusive. Here, bacterioplankton community structures of surface and bottom waters from eight sites along the Pearl Estuary were characterized with 16S rRNA gene pyrosequencing. The results showed significant differences of bacterioplankton community between freshwater and saltwater sites, and further between surface and bottom waters of saltwater sites. Synechococcus dominated the surface water of saltwater sites while Oceanospirillales, SAR11 and SAR406 were prevalent in the bottom water. Betaproteobacteria was abundant in freshwater sites, with no significant difference between water layers. Occurrence of phylogenetic shifts in taxa affiliated to the same clade was also detected. Dissolved oxygen explained most of the bacterial community variation in the redundancy analysis targeting only freshwater sites, whereas nutrients and salinity explained most of the variation across all samples in the Pearl Estuary. Methylophilales (mainly PE2 clade) was positively correlated to dissolved oxygen, whereas Rhodocyclales (mainly R.12up clade) was negatively correlated. Moreover, high nutrient inputs to the freshwater area of the Pearl Estuary have shifted the bacterial communities toward copiotrophic groups, such as Sphingomonadales. The present study demonstrated that the overall nutrients and freshwater hypoxia play important roles in determining bacterioplankton compositions and provided insights into the potential ecological roles of specific taxa in estuarine environments. PMID:25713564

  9. Study on of Seepage Flow Velocity in Sand Layer Profile as Affected by Water Depth and Slope Gradience

    NASA Astrophysics Data System (ADS)

    Han, Z.; Chen, X.

    2017-12-01

    BACKGROUND: The subsurface water flow velocity is of great significance in understanding the hydrodynamic characteristics of soil seepage and the influence of interaction between seepage flow and surface runoff on the soil erosion and sediment transport process. OBJECTIVE: To propose a visualized method and equipment for determining the seepage flow velocity and measuring the actual flow velocity and Darcy velocity as well as the relationship between them.METHOD: A transparent organic glass tank is used as the test soil tank, the white river sand is used as the seepage test material and the fluorescent dye is used as the indicator for tracing water flow, so as to determine the thickness and velocity of water flow in a visualized way. Water is supplied at the same flow rate (0.84 L h-1) to the three parts with an interval of 1m at the bottom of the soil tank and the pore water velocity and the thickness of each water layer are determined under four gradient conditions. The Darcy velocity of each layer is calculated according to the water supply flow and the discharge section area. The effective discharge flow pore is estimated according to the moisture content and porosity and then the relationship between Darcy velocity and the measured velocity is calculated based on the water supply flow and the water layer thickness, and finally the correctness of the calculation results is verified. RESULTS: According to the velocity calculation results, Darcy velocity increases significantly with the increase of gradient; in the sand layer profile, the flow velocity of pore water at different depths increases with the increase of gradient; under the condition of the same gradient, the lower sand layer has the maximum flow velocity of pore water. The air-filled porosity of sand layer determines the proportional relationship between Darcy velocity and pore flow velocity. CONCLUSIONS: The actual flow velocity and Darcy velocity can be measured by a visualized method and the relationship between Darcy velocity and pore velocity can be expressed well by the air-filled porosity of sand layer. The flow velocity measurement and test method adopted in the research is effective and feasible. IMPLICATIONS: The visualized flow velocity measurement method can be applied to simulate and measure the characteristics of subsurface water flow in the soil.

  10. Strained layer Fabry-Perot device

    DOEpatents

    Brennan, Thomas M.; Fritz, Ian J.; Hammons, Burrell E.

    1994-01-01

    An asymmetric Fabry-Perot reflectance modulator (AFPM) consists of an active region between top and bottom mirrors, the bottom mirror being affixed to a substrate by a buffer layer. The active region comprises a strained-layer region having a bandgap and thickness chosen for resonance at the Fabry-Perot frequency. The mirrors are lattice matched to the active region, and the buffer layer is lattice matched to the mirror at the interface. The device operates at wavelengths of commercially available semiconductor lasers.

  11. Experimental Study of the Morphology and Dynamics of Gas-Laden Layers Under the Anodes in an Air-Water Model of Aluminum Reduction Cells

    NASA Astrophysics Data System (ADS)

    Vékony, Klára; Kiss, László I.

    2012-10-01

    The bubble layer formed under an anode and the bubble-induced flow play a significant role in the aluminum electrolysis process. The bubbles covering the anode bottom reduce the efficient surface that can carry current. In our experiments, we filmed and studied the bubble layer under the anode in a real-size air-water electrolysis cell model. Three different flow regimes were found depending on the gas generation rate. The covering factor was found to be proportional to the gas generation rate and inversely proportional to the angle of inclination. A correlation between the average height of the entire bubble layer and the position under the anode was determined. From this correlation and the measured contact sizes, the volume of the accumulated gas was calculated. The sweeping effect of large bubbles was observed. Moreover, the small bubbles under the inner edge of the anode were observed to move backward as a result of the escape of huge gas pockets, which means large momentum transport occurs in the bath.

  12. Effects of shallow-layer reverberation on measurement of teleseismic P-wave travel times for ocean bottom seismograph data

    NASA Astrophysics Data System (ADS)

    Obayashi, Masayuki; Ishihara, Yasushi; Suetsugu, Daisuke

    2017-03-01

    We conducted synthetic experiments to evaluate the effects of shallow-layer reverberation in oceanic regions on P-wave travel times measured by waveform cross-correlation. Time shift due to waveform distortion by the reverberation was estimated as a function of period. Reverberations in the crystalline crust advance the P-waves by a frequency-independent time shift of about 0.3 s in oceans. Sediment does not affect the time shifts in the mid-ocean regions, but effects as large as -0.8 s or more occur where sediment thickness is greater than 600 m for periods longer than 15 s. The water layer causes time delays (+0.3 s) in the relatively shallow (<3500 m) water region for periods longer than 20 s. The time shift may influence mantle images obtained if the reverberation effects are not accounted for in seismic tomography. We propose a simple method to correct relative P-wave travel times at two sites for shallow-layer reverberation by the cross-convolution of the crustal responses at the two sites. [Figure not available: see fulltext. Caption: .

  13. Factors influencing release of phosphorus from sediments in a high productive polymictic lake system.

    PubMed

    Solim, S U; Wanganeo, A

    2009-01-01

    Phosphorus (P) release rates from bottom sediments are high (20.6 mg/m(2)/day) in Dal Lake (India), a polymictic hyper-eutrophic lake. These gross release rates occur over a period of 72 days during summer only. Likewise, a net internal load of 11.3 tons was obtained from mass balance estimates. Significant proportion i.e. approximately 80% of 287.3 tons/yr of nitrate nitrogen (NO(3)-N) load is either eliminated by denitrification or gets entrapped for a short period in high macrophyte biomass of 3.2 kg/m(2) f.w., which eventually get decomposed and nitrogen (N) is released back. These processes result in low lake water NO(3)-N concentrations which potentially influence sediment phosphorus (P) release. Especially, nitrate nitrogen (NO(3)-N) <500 microg/L in the lake waters were associated with high P concentrations. Phosphorus was also observed to increase significantly in relation to temperature and pH, and it seems likely that release of phosphorus and ammonical nitrogen (NH(4)-N) depend on decomposition of rich reserves of organic matter (893 tons d.w. in superficial 10-cm bottom sediment layer). Lake P concentrations were significantly predicted by a multivariate regression model developed for the lake. This study describes significance of various lake water variables in relation to P-release from bottom sediments.

  14. Weak wind-wave/tide interaction over fixed and moveable bottoms: a formulation and some preliminary results

    NASA Astrophysics Data System (ADS)

    Kagan, B. A.; Alvarez, O.; Izquierdo, A.

    2005-05-01

    The formulation of weak wind-wave/low-frequency current interaction is discussed comprehensively as applied to fixed- and moveable-bottom cases. It involves (1) a dependence of the drag coefficient on the ratio between wave and current bottom friction velocity amplitudes, (2) the resistance law for the oscillatory, rough, turbulent bottom boundary layer (BBL) which accounts for the usually neglected effects of rotation and the phase difference between the bottom stress and the friction-free current velocity, (3) the expression for the BBL depth in terms of the bottom Rossby number and (4) the bottom roughness predictor of Grant and Madsen (J. Geophys. Res., 87 (1982) 469) in the version of Tolman (J. Phys. Oceanogr., 24 (1994) 994). The formulation is implemented in the UCA (University of Cadiz) 2D nonlinear, high-resolution, hydrodynamic model and used to study the influence of wind-wave/tide interaction, bottom mobility and the improved flow-resistance description on the M 2 tidal dynamics of Cadiz Bay. The inclusion of either of the first two factors can cause the drag coefficient to increase significantly over its reference value. If the third factor is included, changes in the drag coefficient are quite moderate. This is because the effect of rotation is opposite in sign to the effect of phase difference, so that these effects taken together very nearly balance. The reason why bottom mobility has such an important influence on shallow-water tidal dynamics as wind-wave/tide interaction has, is the occurrence of the large irregular variations in the drag coefficient that accompany sediment motion.

  15. Hydrographic Conditions in the Gulf of Carpentaria During Australian Monsoon Experiment

    NASA Astrophysics Data System (ADS)

    Inoue, M.; Steinberg, C.; Wolanski, E.; Ridd, P.

    2002-12-01

    Gulf of Carpentaria located in the northern Australia, is a shallow wide basin with the deepest bottom depths of approximately 60 m. It is connected to Arafura Sea to the north and west, and to the Torres Strait to the east. Hydrographic surveys of the Gulf of Carpentaria were carried out in January and March, 1987 as part of Australian Monsoon Experiment. During the January survey, Tropical Cyclone (TC) Irma was formed in the Gulf of Carpentaria. An east-west CTD section at 13o52'S was occupied twice, one prior to and during, and the other after the formation of TC Irma. In addition, two post-Irma east-west sections were occupied at 12o40'S and 11o30'S. The pre-cyclone section indicates a well-defined stratified two-layer system, while the post-cyclone sections show deepening of the surface warm layer due to significant mixing by TC Irma. Overall, significant cooling of near surface warm water on the order of more than 1oC was observed. Significant heat loss estimated for the water column has presumably contributed toward the development of TC Irma. In February 1987, TC Jason was formed in the gulf. During the March survey, two east-west CTD sections were occupied at 11o30'S and 13o52'S. The March survey reveals notable warming of the bottom water. Detailed discussion of the CTD data from the two cruises will be presented.

  16. Water and sediment dynamics in the Red River mouth and adjacent coastal zone

    NASA Astrophysics Data System (ADS)

    van Maren, D. S.

    2007-02-01

    The coastline of the Red River Delta is characterized by alternating patterns of rapid accretion and severe erosion. The main branch of the Red River, the Ba Lat, is presently expanding seaward with a main depositional area several km downstream and offshore the Ba Lat River mouth. Sediment deposition rates are approximately 6 m in the past 50 years. Field measurements were done to determine the processes that regulate marine dispersal and deposition of sediment supplied by the Ba Lat. These measurements reveal that the waters surrounding the Ba Lat delta are strongly stratified with a pronounced southward-flowing surface layer. This southward-flowing surface layer is a coastal current which is generated by river plumes that flow into the coastal zone north of the Ba Lat. However, outflow of turbid river water is not continuous and most sediment enters the coastal zone when the alongshore surface velocities are low. As a consequence, most sediment settles from suspension close to the river mouth. In addition to the southward surface flow, the southward near-bottom currents are also stronger than northward currents. Contrasting with the residual flow near-surface, this southward flow component near-bottom is caused by tidal asymmetry. Because most sediment is supplied by the Ba Lat when wave heights are low, sediment is able to consolidate and therefore the long-term deposition is southward of, but still close to, the Ba Lat mouth.

  17. The Role of Rough Topography in Mediating Impacts of Bottom Drag in Eddying Ocean Circulation Models.

    PubMed

    Trossman, David S; Arbic, Brian K; Straub, David N; Richman, James G; Chassignet, Eric P; Wallcraft, Alan J; Xu, Xiaobiao

    2017-08-01

    Motivated by the substantial sensitivity of eddies in two-layer quasi-geostrophic (QG) turbulence models to the strength of bottom drag, this study explores the sensitivity of eddies in more realistic ocean general circulation model (OGCM) simulations to bottom drag strength. The OGCM results are interpreted using previous results from horizontally homogeneous, two-layer, flat-bottom, f-plane, doubly periodic QG turbulence simulations and new results from two-layer β -plane QG turbulence simulations run in a basin geometry with both flat and rough bottoms. Baroclinicity in all of the simulations varies greatly with drag strength, with weak drag corresponding to more barotropic flow and strong drag corresponding to more baroclinic flow. The sensitivity of the baroclinicity in the QG basin simulations to bottom drag is considerably reduced, however, when rough topography is used in lieu of a flat bottom. Rough topography reduces the sensitivity of the eddy kinetic energy amplitude and horizontal length scales in the QG basin simulations to bottom drag to an even greater degree. The OGCM simulation behavior is qualitatively similar to that in the QG rough bottom basin simulations in that baroclinicity is more sensitive to bottom drag strength than are eddy amplitudes or horizontal length scales. Rough topography therefore appears to mediate the sensitivity of eddies in models to the strength of bottom drag. The sensitivity of eddies to parameterized topographic internal lee wave drag, which has recently been introduced into some OGCMs, is also briefly discussed. Wave drag acts like a strong bottom drag in that it increases the baroclinicity of the flow, without strongly affecting eddy horizontal length scales.

  18. Hydrographic Variability off the Coast of Oman

    NASA Astrophysics Data System (ADS)

    Belabbassi, L.; Dimarco, S. F.; Jochens, A. E.; Al Gheilani, H.; Wang, Z.

    2010-12-01

    Data from hydrographic transects made in 2001 and 2002 and between 2007 and 2009 were obtained from the Oman Ministry of Fisheries Wealth. Property-depth plots of temperature, salinity, and dissolved oxygen were produced for all transects and in all months for which data were available. These were analyzed for temporal and spatial variability. For all transects, there exist large variability on various timescales, with strong spatial variability. Two common features that are seen in the hydrographic data sets are the Persian Gulf Water (PGW) and a layer of continuous low oxygen concentrations in the lower part of the water column. Plots of salinity produced for transects located in the northern part of the Gulf of Oman show a one-unit increase in salinity of the water at the bottom of deepest station during the months of August and September as compared to the other months. Similarly, cross-shelf contour plots of temperature shows an increase in water temperature near the bottom station during the months of August and September. These indicate the presence of the PGW outflow in the northern part of the Gulf of Oman. For dissolved oxygen distributions, hydrographic transects that did not extend far offshore show monthly differences in the presence of water with low oxygen concentrations. For transects that do extend far offshore and also show a layer of low oxygen water throughout the year, there is generally a monthly difference on whether this water is found close to the surface or deeper in the water column. The variability seen in the data could only be explained by comparing these data to data collected from the real time cable ocean observing system installed by Lighthouse R &D Enterprise in the Oman Sea and the Arabian Sea in 2005. The analysis of these data reveal that the variability observed is related to processes such as ocean conditions, monsoonal cycle, and extreme weather events.

  19. Simulation of annual biogeochemical cycles of nutrient balance, phytoplankton bloom(s), and DO in Puget Sound using an unstructured grid model

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Khangaonkar, Tarang; Sackmann, Brandon; Long, Wen

    2012-08-14

    Nutrient pollution from rivers, nonpoint source runoff, and nearly 100 wastewater discharges is a potential threat to the ecological health of Puget Sound with evidence of hypoxia in some basins. However, the relative contributions of loads entering Puget Sound from natural and anthropogenic sources, and the effects of exchange flow from the Pacific Ocean are not well understood. Development of a quantitative model of Puget Sound is thus presented to help improve our understanding of the annual biogeochemical cycles in this system using the unstructured grid Finite-Volume Coastal Ocean Model framework and the Integrated Compartment Model (CE-QUAL-ICM) water quality kinetics.more » Results based on 2006 data show that phytoplankton growth and die-off, succession between two species of algae, nutrient dynamics, and dissolved oxygen in Puget Sound are strongly tied to seasonal variation of temperature, solar radiation, and the annual exchange and flushing induced by upwelled Pacific Ocean waters. Concentrations in the mixed outflow surface layer occupying approximately 5–20 m of the upper water column show strong effects of eutrophication from natural and anthropogenic sources, spring and summer algae blooms, accompanied by depleted nutrients but high dissolved oxygen levels. The bottom layer reflects dissolved oxygen and nutrient concentrations of upwelled Pacific Ocean water modulated by mixing with biologically active surface outflow in the Strait of Juan de Fuca prior to entering Puget Sound over the Admiralty Inlet. The effect of reflux mixing at the Admiralty Inlet sill resulting in lower nutrient and higher dissolved oxygen levels in bottom waters of Puget Sound than the incoming upwelled Pacific Ocean water is reproduced. Finally, by late winter, with the reduction in algal activity, water column constituents of interest, were renewed and the system appeared to reset with cooler temperature, higher nutrient, and higher dissolved oxygen waters from the Pacific Ocean.« less

  20. Silicon micromachined broad band light source

    NASA Technical Reports Server (NTRS)

    George, Thomas (Inventor); Jones, Eric (Inventor); Tuma, Margaret L. (Inventor); Eastwood, Michael (Inventor); Hansler, Richard (Inventor)

    2004-01-01

    A micro electromechanical system (MEMS) broad band incandescent light source includes three layers: a top transmission window layer; a middle filament mount layer; and a bottom reflector layer. A tungsten filament with a spiral geometry is positioned over a hole in the middle layer. A portion of the broad band light from the heated filament is reflective off the bottom layer. Light from the filament and the reflected light of the filament are transmitted through the transmission window. The light source may operate at temperatures of 2500 K or above. The light source may be incorporated into an on board calibrator (OBC) for a spectrometer.

  1. Chemical composition of sediments from White Sea, Russian Arctic

    NASA Astrophysics Data System (ADS)

    Gamza, Olga; Shevchenko, Vladimir; Novigatsky, Aleksandr

    2010-05-01

    The White Sea, the only Russian inland sea, is located on the north of outlying districts of the European part of Russia, belongs to Arctic Ocean. Area of water of sea occupies about 90 tousend square kilometers. The sea can be divided into some general parts: neck, funnel, basin and 4 Bays: Dvina Bay, Kandalaksha Bay, Mezen Bay and Onega Bay. The purpose of this work was geochemical mapping of the surface sediments of this area. The main tasks were: compilation data base of element composition of the surface sediments, geochemical mapping of each element, research of the anormal concentration of elements on the surface. To detect the content of chemical elements several methods were used: atomic absorption spectrometry (P.P. Shirshov Institute of Oceanology); neutron activation analysis (Vernadsky Institute of Geochemistry and Analytical Chemistry), total and organic carbon analysis, photometric method to detection Si, Al, P (P.P. Shirshov Institute of Oceanology). Bulk composition is one of the fundamental characteristics of sediments and bottom deposites of modern basins. Coarse-grained sediments with portion of pelitic component <50% is spread on the shallow area (Kandalaksha Bay), in areas with high hydrodynamic activity of near-bottom water. Under the conditions of their low activity, fine-grained facies are common(>80%). Character of elements distribution correlates with facial distribution of sediments from White Sea. According to litologic description, bottom surface of Dvina Bay is practically everywhere covered by layer of fine-grained sand. In the border area between Dvina Bay and White Sea basin on terraced subwater slope aleurite politic silts are abundant. They tend to exhange down the slope to clay silts. In Onega Bay fractions of non-deposition are observed. They are characterized by wide spread of thin blanket poorgraded sediments, which are likely to be relic. Relief of Kandalakscha Bay bottom is presented as alternation of abyssal fosses (near 300 m) with silles and elevations (<20 m), and also numerous islands. Thus variety of sediment composition is observed here - from rules and gravels to fine-grained clay silts [1]. The map of distribution of chemical elements was created by using bulk composition data with the help of program ArcView. Mn distribution in sedimentation mass is largely determed by influence of redox diagenesis. Reactive form of Mn dominates over less moving, litogenic form in sedimation mass of White Sea. Litogenic form remains in sediment, reactive form moves into silt near-bottom water, resulting Mn migration both in sediment and near-bottom layer of marine water. Mn oxidizes on the contact with oxygen of marine water and alters into insoluble form MnO2, causing Mn enrichment of surface layer of sediments. Highly movable silt deposit MnO2 and enriched by Mn suspension are moved by underflow and accumulate in bottom depressions and in central part of the sea, which is quite wide from both places of original sedimentation and run off sources [2]. Thus, the interrelation between granulometric composition of sediment and materials concentration can be shown by the example of Mn. Local conditions, leading to accumulation of clastic components, are: 1. Rise of content in sand owning to separation of heavy minerals 2. Rise of content in surface, mainly sandy clay sediments owning to presence of concretions 3. Rise of content in lower bunches roof owning to diagenetic contraction. Authors thank academic Lisitsyn for encourage, Andrey Apletalin for valuable help, and everybody, who helped in field and laboratory research of the White sea sediments. Work was being done under the auspices of Russian foundation of basic research (grants 09-05-10081, 09-05-00658 and 08-05-00860), RSA presidiums program of 17 fundamental researches (project 17.1). References: 1.Kuzmina T., Lein A., Lutchsheva L., Murdmaa I., Novigatsky A., Shevchenko V. Chemical composition of White Sea's sediments // Litology and mineral deposits . 2009. - № 2. - P 115-132. 2.Nevessky E., Medvedev V. , Kalinenko V. White sea, sedimentation and holocoen developmental history. - Moscow.: Nauka, 1977. - 236 p. 3.White Sea and it water collection affected by climatic and antropogenic factors. / under the editorship of Terzhevik A., Filatov N. - Petrozavodsk.: Karelsky nauchny centr RAN, 2007. - 335p

  2. Propagation of inertial-gravity waves on an island shelf

    NASA Astrophysics Data System (ADS)

    Bondur, V. G.; Sabinin, K. D.; Grebenyuk, Yu. V.

    2015-09-01

    The propagation of inertial-gravity waves (IGV) at the boundary of the Pacific shelf near the island of Oahu (Hawaii), whose generation was studied in the first part of this work [1], is analyzed. It is shown that a significant role there is played by the plane oblique waves; whose characteristics were identified by the method of estimating 3D wave parameters for the cases when the measurements are available only for two verticals. It is established that along with the descending propagation of energy that is typical of IGVs, wave packets ascend from the bottom to the upper layers, which is caused by the emission of waves from intense jets of discharged waters flowing out of a diffusor located at the bottom.

  3. Deep-sea macroplankton distribution (at 400 to 2300 m) in the northwestern Mediterranean in relation to environmental factors

    NASA Astrophysics Data System (ADS)

    Cartes, J. E.; Fanelli, E.; López-Pérez, C.; Lebrato, M.

    2013-03-01

    Changes in the composition and biomass distribution of deep-living zooplankton over wide gradients of depth (400-2300 m) and longitude (~ 180 km) have been analyzed in the Balearic Basin (western Mediterranean), seeking the environmental variables responsible for these changes. Zooplankton tends to aggregate at different levels of the water column (forming Deep Scattering Layers, DSL) and in the Benthic Boundary Layer (BBL). Macrozooplankton biomass and composition were analyzed along a transect performed in July 2010 in midwater (between ~ 350 and 450 m) and near the bottom (at ~ 5-200 mab), over soundings of 450-2263 m, including the top of Valencia Seamount (at ~ 40° 25' N-02° 42' E, 1076 m). Zooplankton changed significantly in composition at the mesoscale (~ 180 km) in both the DSL and the BBL. Siphonophores and calanoid copepods were the most dominant deep zooplankton taxa, calanoids reaching higher abundance in the BBL (1761-5177 individuals/1000 m3) than in the DSL (1568-1743 individuals/1000 m3). There was a significant increase in near-bottom zooplankton biomass over the middle slope, at 1000-1300 m, linked to an increase in scyphozoans and siphonophores (Lensia spp. and Abylopsis tetragona) with peaks of 1.5-2.0 gWW/1000 m3. The peak of near-bottom zooplankton at 1000-1300 m coincided with the lowest temperatures (13.08 °C) and maximum O2 concentration (4.40 ml/l) near the bottom and below 1000 m with higher records in near-bottom turbidity. Gelatinous zooplankton are the main prey in the diet of the demersal fish Alepocephalus rostratus in the western Mediterranean, fish responsible for the peak of megafauna biomass reported at around 1200-1400 m in the deep Mediterranean and at similar depths in other oceanic areas (e.g. the NW Atlantic). We suggest that deep-sea environmental conditions can govern peaks of near-bottom zooplankton, as well as influence the structure of the demersal fish community.

  4. Water Redistribution, Temperature Change and CO2 Diffusion of Reconstruction Soil Profiles Filled with Gangue in Coal Mining Areas

    NASA Astrophysics Data System (ADS)

    Wang, S.; Zhan, H.; Chen, X.; Hu, Y.

    2017-12-01

    There were a great many projects of reconstruction soil profile filled with gangue to restore ecological environment and land resources in coal mining areas. A simulation experimental system in laboratory was designed for studying water transport and gas-heat diffusion of the reconstruction soil as to help the process of engineering and soil-ripening technology application. The system could be used for constantly measuring soil content, temperature and soil CO2 concentration by laid sensors and detectors in different depth of soil column. The results showed that soil water infiltration process was slowed down and the water-holding capacity of the upper soil was increased because of good water resistance from coal gangue layer. However, the water content of coal gangue layer, 10% approximately, was significantly lower than that of topsoil for the poor water-holding capacity of gangue. The temperature of coal gangue layer was also greater than that of soil layer and became easily sustainable temperature gradient under the condition with heating in reconstruction soil due to the higher thermal diffusivity from gangue, especially being plenty of temperature difference between gangue and soil layers. The effects of heated from below on topsoil was small, which it was mainly influenced from indoor temperature in the short run. In addition, the temperature changing curve of topsoil is similar with the temperature of laboratory and its biggest fluctuation range was for 2.89°. The effects of aerating CO2 from column bottom on CO2 concentration of topsoil soil was also very small, because gas transport from coal gangue layers to soil ones would easily be cut off as so to gas accumulated below the soil layer. The coal gangue could have a negative impact on microbial living environment to adjacent topsoil layers and declined microorganism activities. The effects of coal gangue on topsoil layer were brought down when the cove soil thickness was at 60 cm. And the influences gradually would be weakened with the thickness increasing.

  5. High-frequency internal waves and thick bottom mixed layers observed by gliders in the Gulf Stream

    NASA Astrophysics Data System (ADS)

    Todd, Robert E.

    2017-06-01

    Autonomous underwater gliders are conducting high-resolution surveys within the Gulf Stream along the U.S. East Coast. Glider surveys reveal two mechanisms by which energy is extracted from the Gulf Stream as it flows over the Blake Plateau, a portion of the outer continental shelf between Florida and North Carolina where bottom depths are less than 1000 m. Internal waves with vertical velocities exceeding 0.1 m s-1 and frequencies just below the local buoyancy frequency are routinely found over the Blake Plateau, particularly near the Charleston Bump, a prominent topographic feature. These waves are likely internal lee waves generated by the subinertial Gulf Stream flow over the irregular bathymetry of the outer continental shelf. Bottom mixed layers with O(100) m thickness are also frequently encountered; these thick bottom mixed layers likely form in the lee of topography due to enhanced turbulence generated by O(1) m s-1 near-bottom flows.

  6. Contrasting fates of organic matter in locations having different organic matter inputs and bottom water O2 concentrations

    NASA Astrophysics Data System (ADS)

    Mai-Thi, Ngoc-Nu; St-Onge, Guillaume; Tremblay, Luc

    2017-11-01

    The goals of this work were to study sedimentary organic matter (OM) composition and transformation since the end of the last deglaciation and to evaluate the influence of contrasting depositional conditions on these parameters. One station was located in the Lower St. Lawrence Estuary (LSLE) where the current bottom waters are hypoxic and receive terrigenous and marine OM. The other station, located in the Gulf of St. Lawrence (GSL), has more oxygenated bottom waters and almost only marine OM inputs. Analyses included enantiomers of amino acids (L and D-AA) and muramic acid that provide different markers of OM alteration state and reactivity and of bacterial contribution to OM composition and diagenesis. The markers clearly indicated the increase in OM alteration state with depth in the sediments of the LSLE and the GSL. The steady decrease in AA yields with depth confirmed the preferential degradation of AA compared to the rest of the OM. The OM in the surface sediment of the LSLE was less altered than that of the GSL and was enriched in bacterial biomass as indicated by much higher muramic acid yields. Results indicated that an important degradation of particulate organic matter occurs in the water column in the GSL, while it takes place mostly in the sediments in the LSLE. The presence of heterogeneous OM and hypoxic conditions in the LSLE likely reduce OM degradation rate in its deep water layer. However, the zone near the water-sediment interface is responsible for large variations in AA composition at both locations. A relatively new redox index, based on AA composition, was tested and appeared robust. This study highlights the importance of ambient conditions in determining the fate of OM and in the biogeochemical cycles of vital elements.

  7. Confinement induced ordering in dewetting of ultra-thin polymer bilayers on nanopatterned substrates.

    PubMed

    Bhandaru, Nandini; Das, Anuja; Mukherjee, Rabibrata

    2016-01-14

    We report the dewetting of a thin bilayer of polystyrene (PS) and poly(methylmethacrylate) (PMMA) on a topographically patterned nonwettable substrate comprising an array of pillars, arranged in a square lattice. With a gradual increase in the concentration of the PMMA solution (Cn-PMMA), the morphology of the bottom layer changes to: (1) an aligned array of spin dewetted droplets arranged along substrate grooves at very low Cn-PMMA; (2) an interconnected network of threads surrounding each pillar at intermediate Cn-PMMA; and (3) a continuous bottom layer at higher Cn-PMMA. On the other hand the morphology of the PS top layer depends largely on the nature of the pre-existing bottom layer, in addition to Cn-PS. An ordered array of PMMA core-PS shell droplets forms right after spin coating when both Cn-PMMA and Cn-PS are very low. Bilayers with all other initial configurations evolve during thermal annealing, resulting in a variety of ordered structures. Unique morphologies realized include laterally coexisting structures of the two polymers confined within the substrate grooves due to initial rupture of the bottom layer on the substrate followed by a squeezing flow of the top layer; an array of core-shell and single polymer droplets arranged in an alternating order etc., to highlight a few. Such structures cannot be fabricated by any stand-alone lithography technique. On the other hand, in some cases the partially dewetted bottom layer imparts stability to an intact top PS layer against dewetting. Apart from ordering, under certain specific conditions significant miniaturization and downsizing of dewetted feature periodicity and dimension as compared to dewetting of a single layer on a flat substrate is observed. With the help of a morphology phase diagram we show that ordering is achieved over a wide combination of Cn-PMMA and Cn-PS, though the morphology and dewetting pathway differs significantly with variation in the thickness of the individual layers.

  8. Changes in deep-sea fish and crustacean communities at 1000-2200 m in the Western Mediterranean after 25 years: Relation to hydro-climatic conditions

    NASA Astrophysics Data System (ADS)

    Cartes, J. E.; Maynou, F.; Fanelli, E.; López-Pérez, C.; Papiol, V.

    2015-03-01

    Long-term changes in the biomass, diversity and composition of deep-living fish and decapods from the Balearic Basin (western Mediterranean) have been compared between two periods, 1985-1992 vs. 2007-2012, based on 106 bottom trawls performed at 1000-2250 m. Relationships have been identified between the changes in community composition and the hydroclimatic conditions (e.g. NAO, temperature, salinity and dissolved O2) of the area. We found a generalized deepening of middle-slope communities (950-1250 m), especially among decapods, which is suggested (from GLM results) to have been a response to the long-term increase in salinity of the Levantine Intermediate Waters (LIW), located above the level sampled to ca. 700 m. Even more pronounced was the shallowing of all of the lower slope species (1600-2250 m), accompanied by a significant decrease of biomass from 1985-1992 to 2007-2012. This last tendency would be done to a combination of factors: long-term decrease of O2 in the bottom-boundary layer, greater degradation of POM arriving on the bottom due to temperature increase in the Western Mediterranean Deep Waters (WMDW) and probably a decrease of Chl a at the surface and, thus, of production. The influence of climatic oscillations (NAO) on differences found between 1985-1992 and 2007-2012 seems secondary, likely because the NAO did not show significant differences between the two periods. Some plankton-feeding species showed an increase of density during high/positive NAO (e.g. Alepocephalus rostratus), while some benthos feeders increased during low/negative NAO (e.g. Aristeus antennatus, mainly juveniles). The increase of rainfall and advective fluxes under low/negative NAO (i.e., in 2007-2012) may increase the formation of the nepheloid layer identified over 1200-1400 m in the area (Cartes et al., 2013a), linked to zooplankton aggregation in that depth range. Greater food availability could explain the generalized migration by both middle and lower slope species toward these intermediate depths that acquired greater trophic resources. Deep-sea Mediterranean fish and invertebrates, including important commercial species, seemed to undergo long-term changes in its distribution and biomass due to changes in hydro-climatic conditions, mainly a decrease of O2 in the bottom-boundary layer.

  9. Peclet number analysis of cross-flow in porous gas diffusion layer of polymer electrolyte membrane fuel cell (PEMFC).

    PubMed

    Suresh, P V; Jayanti, Sreenivas

    2016-10-01

    Adoption of hydrogen economy by means of using hydrogen fuel cells is one possible solution for energy crisis and climate change issues. Polymer electrolyte membrane (PEM) fuel cell, which is an important type of fuel cells, suffers from the problem of water management. Cross-flow is induced in some flow field designs to enhance the water removal. The presence of cross-flow in the serpentine and interdigitated flow fields makes them more effective in proper distribution of the reactants on the reaction layer and evacuation of water from the reaction layer than diffusion-based conventional parallel flow fields. However, too much of cross-flow leads to flow maldistribution in the channels, higher pressure drop, and membrane dehydration. In this study, an attempt has been made to quantify the amount of cross-flow required for effective distribution of reactants and removal of water in the gas diffusion layer. Unit cells containing two adjacent channels with gas diffusion layer (GDL) and catalyst layer at the bottom have been considered for the parallel, interdigitated, and serpentine flow patterns. Computational fluid dynamics-based simulations are carried out to study the reactant transport in under-the-rib area with cross-flow in the GDL. A new criterion based on the Peclet number is presented as a quantitative measure of cross-flow in the GDL. The study shows that a cross-flow Peclet number of the order of 2 is required for effective removal of water from the GDL. Estimates show that this much of cross-flow is not usually produced in the U-bends of Serpentine flow fields, making these areas prone to flooding.

  10. Two-layer anti-reflection strategies for implant applications

    NASA Astrophysics Data System (ADS)

    Guerrero, Douglas J.; Smith, Tamara; Kato, Masakazu; Kimura, Shigeo; Enomoto, Tomoyuki

    2006-03-01

    A two-layer bottom anti-reflective coating (BARC) concept in which a layer that develops slowly is coated on top of a bottom layer that develops more rapidly was demonstrated. Development rate control was achieved by selection of crosslinker amount and BARC curing conditions. A single-layer BARC was compared with the two-layer BARC concept. The single-layer BARC does not clear out of 200-nm deep vias. When the slower developing single-layer BARC was coated on top of the faster developing layer, the vias were cleared. Lithographic evaluation of the two-layer BARC concept shows the same resolution advantages as the single-layer system. Planarization properties of a two-layer BARC system are better than for a single-layer system, when comparing the same total nominal thicknesses.

  11. Observed salinity changes in the Alappuzha mud bank, southwest coast of India and its implication to hypothesis of mudbank formation

    NASA Astrophysics Data System (ADS)

    Muraleedharan, K. R.; Dinesh Kumar, P. K.; Prasanna Kumar, S.; Srijith, B.; John, Sebin; Naveen Kumar, K. R.

    2017-04-01

    Alappuzha mud bank draws special attention among the twenty-mud bank locations reported along the Kerala coast by its remoteness from riverine sources. Among several hypotheses proposed for the formation of mud bank, the subterranean hypothesis was most accepted because of the occurrence of low salinity in the bottom layers. The present study provides evidence to show that occurrence of low salinity waters near the bottom in the mud bank region is an artifact of measuring technique employed for the measurement of salinity. The usual technique of conductivity based salinity determination completely fails in the presence of water laden with high amount of suspended sediment. Laboratory experiments were conducted to determine the response of electrode and conductivity cell sensor types to determine the salinity using a range of suspended sediment in the water column. Actual sediment samples from the mud bank region were utilized for the above studies. Based on field observations and experiments, we conclude that the low salinity was the manifestation of the presence highly turbid fluid mud formation in the mud bank region rather than the influence of fresh water.

  12. Platforms for hyperspectral imaging, in-situ optical and acoustical imaging in urbanized regions

    NASA Astrophysics Data System (ADS)

    Bostater, Charles R.; Oney, Taylor

    2016-10-01

    Hyperspectral measurements of the water surface of urban coastal waters are presented. Oblique bidirectional reflectance factor imagery was acquired made in a turbid coastal sub estuary of the Indian River Lagoon, Florida and along coastal surf zone waters of the nearby Atlantic Ocean. Imagery was also collected using a pushbroom hyperspectral imager mounted on a fixed platform with a calibrated circular mechatronic rotation stage. Oblique imagery of the shoreline and subsurface features clearly shows subsurface bottom features and rip current features within the surf zone water column. In-situ hyperspectral optical signatures were acquired from a vessel as a function of depth to determine the attenuation spectrum in Palm Bay. A unique stationary platform methodology to acquire subsurface acoustic images showing the presence of moving bottom boundary nephelometric layers passing through the acoustic fan beam. The acoustic fan beam imagery indicated the presence of oscillatory subsurface waves in the urbanized coastal estuary. Hyperspectral imaging using the fixed platform techniques are being used to collect hyperspectral bidirectional reflectance factor (BRF) measurements from locations at buildings and bridges in order to provide new opportunities to advance our scientific understanding of aquatic environments in urbanized regions.

  13. Bottom friction models for shallow water equations: Manning’s roughness coefficient and small-scale bottom heterogeneity

    NASA Astrophysics Data System (ADS)

    Dyakonova, Tatyana; Khoperskov, Alexander

    2018-03-01

    The correct description of the surface water dynamics in the model of shallow water requires accounting for friction. To simulate a channel flow in the Chezy model the constant Manning roughness coefficient is frequently used. The Manning coefficient nM is an integral parameter which accounts for a large number of physical factors determining the flow braking. We used computational simulations in a shallow water model to determine the relationship between the Manning coefficient and the parameters of small-scale perturbations of a bottom in a long channel. Comparing the transverse water velocity profiles in the channel obtained in the models with a perturbed bottom without bottom friction and with bottom friction on a smooth bottom, we constructed the dependence of nM on the amplitude and spatial scale of perturbation of the bottom relief.

  14. Deep and intermediate mediterranean water in the western Alboran Sea

    NASA Astrophysics Data System (ADS)

    Parrilla, Gregorio; Kinder, Thomas H.; Preller, Ruth H.

    1986-01-01

    Hydrographic and current meter data, obtained during June to October 1982, and numerical model experiments are used to study the distribution and flow of Mediterranean waters in the western Alboran Sea. The Intermediate Water is more pronounced in the northern three-fourths of the sea, but its distribution is patchy as manifested by variability of the temperature and salinity maxima at scales ≤10 km. Current meters in the lower Intermediate Water showed mean flow toward the Strait at 2 cm s -1. A reversal of this flow lasted about 2 weeks. A rough estimate of the mean westward Intermediate Water transport was 0.4 × 10 6 m 3 s -1, about one-third of the total outflow, so that the best estimates of the contributions of traditionally defined Intermediate Water and Deep Water account for only about one-half of the total outflow. The Deep Water was uplifted against the southern continental slope from Alboran Island (3°W) to the Strait. There was also a similar but much weaker banking against the Spanish slope, but a deep current record showed that the eastward recirculation implied by this banking is probably intermittent. Two-layer numerical model experiments simulated the Intermediate Water flow with a flat bottom and the Deep Water with realistic bottom topography. Both experiments replicated the major circulation features, and the Intermediate Water flow was concentrated in the north because of rotation and the Deep Water flow in the south because of topographic control.

  15. Effects of storm runoff on the thermal regime and water quality of a deep, stratified reservoir in a temperate monsoon zone, in Northwest China.

    PubMed

    Huang, Tinglin; Li, Xuan; Rijnaarts, Huub; Grotenhuis, Tim; Ma, Weixing; Sun, Xin; Xu, Jinlan

    2014-07-01

    Jinpen Reservoir is a deep, stratified reservoir in Shaanxi province, located in a warm temperate zone of Northwest China. Influenced by a temperate monsoon climate, more than 60% of the annual precipitation is concentrated from late summer to autumn (July-September). In recent years, extreme rainfall events occurred more frequently and strongly affected the thermal structure, mixing layer depth and evolution of stratification of Jinpen Reservoir. The reservoir's inflow volume increased sharply after heavy rainfall during the flooding season. Large volumes of inflow induced mixing of stratified water zones in early autumn and disturbed the stratification significantly. A temporary positive effect of such disturbance was the oxygenation of the water close to the bottom of the reservoir, leading to inhibition of the release of nutrients from sediments, especially phosphate. However, the massive inflow induced by storm runoff with increased oxygen-consuming substances led to an increase of the oxygen consumption rate. After the bottom water became anaerobic again, the bottom water quality would deteriorate due to the release of pollutants from sediments. Heavy rainfall events could lead to very high nutrient input into the reservoir due to massive erosion from the surrounding uninhabited steep mountains, and the particulate matter contributed to most nutrient inputs. Reasonably releasing density flow is an effective way to reduce the amounts of particulate associated pollutants entering the reservoir. Significant turbid density flow always followed high rainfall events in Jinpen Reservoir, which not only affected the reservoir water quality but also increased costs of the drinking water treatment plant. Understanding the effects of the storm runoff on the vertical distributions of water quality indicators could help water managers to select the proper position of the intake for the water plant in order to avoid high turbidity outflow. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. A layered abduction model of perception: Integrating bottom-up and top-down processing in a multi-sense agent

    NASA Technical Reports Server (NTRS)

    Josephson, John R.

    1989-01-01

    A layered-abduction model of perception is presented which unifies bottom-up and top-down processing in a single logical and information-processing framework. The process of interpreting the input from each sense is broken down into discrete layers of interpretation, where at each layer a best explanation hypothesis is formed of the data presented by the layer or layers below, with the help of information available laterally and from above. The formation of this hypothesis is treated as a problem of abductive inference, similar to diagnosis and theory formation. Thus this model brings a knowledge-based problem-solving approach to the analysis of perception, treating perception as a kind of compiled cognition. The bottom-up passing of information from layer to layer defines channels of information flow, which separate and converge in a specific way for any specific sense modality. Multi-modal perception occurs where channels converge from more than one sense. This model has not yet been implemented, though it is based on systems which have been successful in medical and mechanical diagnosis and medical test interpretation.

  17. Cyclotron Orbits of Composite Fermions in the Fractional Quantum Hall Regime

    NASA Astrophysics Data System (ADS)

    Jo, Insun; Deng, Hao; Liu, Yang; Pfeiffer, L. N.; West, K. W.; Baldwin, K. W.; Shayegan, M.

    2018-01-01

    We study a bilayer GaAs hole system that hosts two distinct many-body phases at low temperatures and high perpendicular magnetic fields. The higher-density (top) layer develops a Fermi sea of composite fermions (CFs) in its half-filled lowest Landau level, while the lower-density (bottom) layer forms a Wigner crystal (WC) as its filling becomes very small. Owing to the interlayer interaction, the CFs in the top layer feel the periodic Coulomb potential of the WC in the bottom layer. We measure the magnetoresistance of the top layer while changing the bottom-layer density. As the WC layer density increases, the resistance peaks separating the adjacent fractional quantum Hall states in the top layer change nonmonotonically and attain maximum values when the cyclotron orbit of the CFs encloses one WC lattice point. These features disappear at T =275 mK when the WC melts. The observation of such geometric resonance features is unprecedented and surprising as it implies that the CFs retain a well-defined cyclotron orbit and Fermi wave vector even deep in the fractional quantum Hall regime, far from half-filling.

  18. Swellable clay minerals in weathering products of volcanic sediments related to landslides by 2016 Kumamoto Earthquake

    NASA Astrophysics Data System (ADS)

    Isobe, H.; Torii, M.

    2016-12-01

    2016 Kumamoto Earthquake triggered numerous landslides in Aso caldera area, Japan and incurred heavy casualties. Landslides occurred not only on steep slopes at the caldera cliffs or the barranco but also on relatively gradual slopes at the side of the central cones in the Aso caldera. The Aso volcano is a volcanic complex with huge caldera formed by catastrophic eruption at approximately 90ka and central cones formed by subsequent activities to recent years. The central cones are volcanic peaks contain various rocks including basaltic, andesitic and rhoyolitic lavas and pyroclastic materials. In this study, we analyzed the samples collected from the bottom surface of landslides occurred at the gradual hillside on the western flank of the Aso central cones. The subsurface geology of the site is Takanoobane rhyolite lava, 51ka, covered by dark silty or pelitic tuffs and black soil strata including Kusasenri pumice layer, 31ka. The bottom plane of the landslides can be seen as flat surfaces at boundaries between units in the Kusasenri pumice or bottom of the Kusasenri pumice on the pelitic tuff with charcoaled plants. The Kusasenri pumice layer is a coarse grained and highly permeable but poorly continuous. X-ray diffraction analysis revealed that the main component of the samples is halloysite (10Å). Halloysite (10Å) is alteration product of fine grained volcanic ash, and swellable clay with interlayer water molecules which bring sticky and deformable characteristics. The landslides caused by 2016 Kumamoto Earthquake occurred without precipitation within a week. Strong earthquake may fluidize swellable clay layers in gradual slopes and triggered heavy landslides.

  19. Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution

    PubMed Central

    Tian, Bin; Tian, Bining; Smith, Bethany; Scott, M. C.; Lei, Qin; Hua, Ruinian; Liu, Yi

    2018-01-01

    Few-layer black phosphorus (BP) nanosheets were first reported as a 2D material for the application of field-effect transistors in 2014 and have stimulated intense activity among physicists, chemists, and material and biomedical scientists, driving research into novel synthetic techniques to produce BP nanosheets. At present, exfoliation is the main route toward few-layer BP nanosheets via employing bulk BP as raw material. However, this is a complicated and time-consuming process, which is difficult for the large-scale synthesis of BP nanosheets. Moreover, BP degrades rapidly when exfoliated to nanoscale dimensions, resulting in the rapid loss of semiconducting properties. Here, we report the direct wet-chemical synthesis of few-layer BP nanosheets in gram-scale quantities in a bottom-up approach based on common laboratory reagents at low temperature, showing excellent stability due to partial oxidation of surface. Solvent and temperature are two critical factors, controlling not only the formation of BP nanosheets but also the thickness. The as-prepared BP nanosheets can extract hydrogen from pure water (pH = 6.8), exhibiting more than 24-fold higher activity than the well-known C3N4 nanosheets. Our results reporting the ability to prepare few-layer BP nanosheets with a facile, scalable, low-cost approach take us a step closer to real-world applications of phosphorene including next-generation metal-free photocatalysts for photosynthesis. PMID:29563225

  20. Double-diffusive convection and baroclinic instability in a differentially heated and initially stratified rotating system: the barostrat instability

    NASA Astrophysics Data System (ADS)

    Vincze, Miklos; Borcia, Ion; Harlander, Uwe; Le Gal, Patrice

    2016-12-01

    A water-filled differentially heated rotating annulus with initially prepared stable vertical salinity profiles is studied in the laboratory. Based on two-dimensional horizontal particle image velocimetry data and infrared camera visualizations, we describe the appearance and the characteristics of the baroclinic instability in this original configuration. First, we show that when the salinity profile is linear and confined between two non-stratified layers at top and bottom, only two separate shallow fluid layers can be destabilized. These unstable layers appear nearby the top and the bottom of the tank with a stratified motionless zone between them. This laboratory arrangement is thus particularly interesting to model geophysical or astrophysical situations where stratified regions are often juxtaposed to convective ones. Then, for more general but stable initial density profiles, statistical measures are introduced to quantify the extent of the baroclinic instability at given depths and to analyze the connections between this depth-dependence and the vertical salinity profiles. We find that, although the presence of stable stratification generally hinders full-depth overturning, double-diffusive convection can lead to development of multicellular sideways convection in shallow layers and subsequently to a multilayered baroclinic instability. Therefore we conclude that by decreasing the characteristic vertical scale of the flow, stratification may even enhance the formation of cyclonic and anticyclonic eddies (and thus, mixing) in a local sense.

  1. Latest Data on Thermohaline Structure and Circulation of the Dying Aral Sea

    NASA Astrophysics Data System (ADS)

    Izhitsky, Alexander; Zavialov, Peter

    2010-05-01

    The results of the latest expedition of the Shirshov Institute to the Aral Sea are reported. The survey encompassed 15 field days in August, 2009. An interdisciplinary oceanographic study in the western basin of the sea was conducted during the expedition. Vertical profiles of temperature, salinity and fluorescence were obtained using a CTD profiler at 8 stations across the western basin. Two mooring stations equipped with current meters, one at the surface and one in the bottom layer at each station, as well as pressure gauges at the bottom, were deployed for 5 days in the deepest portion of the western basin. One of the stations was installed at the western slope of the basin, while the other one was positioned at the eastern slope. A portable automatic meteorological station, continuously recording the variability of wind and principal meteorological parameters, was installed near the mooring sites. The vertical structure of the themohaline fields exhibited a 3-layered pattern, with local salinity maxima in the upper mixed layer and at the bottom. The intermediate layer was characterized by a core of minimum salinity and temperature, also accompanied by maximum fluorescence. Such a pattern indicates that the signature of the denser, saltier water originating from the eastern basin is still evident, even though the eastern basin itself dried up almost completely during the summer of 2009. The surface salinity was around 136 ppt, which constituted a notable increase for about 20 ppt since the summer of 2008. Over the same period, sea level decreased by 164 cm since the summer of 2008. Analysis of the current measurements data along with the meteorological data records demonstrated that the mean basin-scale surface circulation of the Large Aral Sea is likely to have remained anticyclonic, whilst the near-bottom circulation appears to be cyclonic. The current velocity and level anomalies responded energetically to winds. Correlation analysis of the velocity series versus the wind stress allowed to quantify the response of the system to the wind forcing.

  2. Intergarted geophysical investigations by GPR and ERT on the largest rock fill dam in Europe: Monte Cotugno dam (Southern Italy)

    NASA Astrophysics Data System (ADS)

    Loperte, A.; Bavusi, M.; Cerverizzo, G.; Lapenna, V.; Soldovieri, F.

    2012-04-01

    This work is concerned with the first results of a survey based on the integration of geophysical techniques for the inspection of the Monte Cotugno dam, the largest rock fill dam in Europe. The Monte Cotugno dam, managed by National Irrigation Development and Agrarian Transformation in Puglia, Basilicata and Irpinia is located on the Sinni river (Basilicata District, South Italy) and represents the nodal point in the whole hydraulic system on the Ionic side of Italy; in fact, the dam allows harnessing of the Sinni river water for agricultural, industrial, drinking and domestic purposes. The dam is of the zoned type and consists of a central core in sandy silt and of gravelly-sandy shoulders; its water tightness is ensured by a bituminous conglomerate facing on the upstream side, welded at the bottom to the foundation sealing system. The latter is about 1,900m long and consist of a massive concrete cut-off wall based on the marly-clay formation, 300m long on the right and 600 m long on the left side. On the valley bottom it is made up of a reinforced concrete cut-off wall that is inserted in the marly-clay formation and is surmounted by an inspection and percolation water collection tunnel. The watertight face consists of a bottom levelling layer 7-8 cm thick in semi open-graded bituminous concrete, a 5 cm separation layer in dense-graded bituminous concrete, a drainage layer in very open-graded concrete varying in thickness from 10 to 16 cm from the top of the dam down, two 4-cm top layers in dense-graded bituminous concrete with stepped joints, a finishing sealing coat containing 1.5 kg/cm2 of asphalt. The shallowest part of this layering is started to show incipient small detachments due to thermal solicitations; these detachments represent a possible way for water infiltration in the dam. In this framework, it was decided to perform the identification, characterization and evaluation of the potential loss of water through small cracks in the bituminous concrete dam and then monitor these areas of infiltration. For such a task, the use of conventional geotechnical investigation methods was discarded since these techniques often requires invasive actions in the inner of the structure to be investigated (destructiveness) and only provide punctual information for small volumes. On the contrary, in this case, it was decided to use non-invasive sensing techniques, which make it possible to investigate and gain "global" information about all the structure without affecting its operability. In particular, Ground Penetrating Radar and Electrical Resistivity Tomography techniques have been exploited so to have possibility of quickly investigating large portions of dam with different spatial and resolution scales and without the need of destructive actions. The results of this survey well agree with direct surveys and the details of the survey and of the diagnostic results will be shown at the conference.

  3. Nuclear reactor with low-level core coolant intake

    DOEpatents

    Challberg, Roy C.; Townsend, Harold E.

    1993-01-01

    A natural-circulation boiling-water reactor has skirts extending downward from control rod guide tubes to about 10 centimeters from the reactor vessel bottom. The skirts define annular channels about control rod drive housings that extend through the reactor vessel bottom. Recirculating water is forced in through the low-level entrances to these channels, sweeping bottom water into the channels in the process. The sweeping action prevents cooler water from accumulating at the bottom. This in turn minimizes thermal shock to bottom-dwelling components as would occur when accumulated cool water is swept away and suddenly replaced by warmer water.

  4. Importance of the Colmation Layer in the Transport and Removal of Cyanobacteria, Viruses, and Dissolved Organic Carbon during Natural Lake-Bank Filtration.

    PubMed

    Harvey, Ronald W; Metge, David W; LeBlanc, Denis R; Underwood, Jen; Aiken, George R; Butler, Kenna; McCobb, Timothy D; Jasperse, Jay

    2015-09-01

    This study focused on the importance of the colmation layer in the removal of cyanobacteria, viruses, and dissolved organic carbon (DOC) during natural bank filtration. Injection-and-recovery studies were performed at two shallow (0.5 m deep), sandy, near-shore sites at the southern end of Ashumet Pond, a waste-impacted, kettle pond on Cape Cod, MA, that is subject to periodic blooms of cyanobacteria and continuously recharges a sole-source drinking-water aquifer. The experiment involved assessing the transport behaviors of bromide (conservative tracer), sp. IU625 (cyanobacterium, 2.6 ± 0.2 µm), AS-1 (tailed cyanophage, 110 nm long), MS2 (coliphage, 26 nm diameter), and carboxylate-modified microspheres (1.7 µm diameter) introduced to the colmation layer using a bag-and-barrel (Lee-type) seepage meter. The injectate constituents were tracked as they were advected across the pond water-groundwater interface and through the underlying aquifer sediments under natural-gradient conditions past push-point samplers placed at ∼30-cm intervals along a 1.2-m-long, diagonally downward flow path. More than 99% of the microspheres, IU625, MS2, AS-1, and ∼44% of the pond DOC were removed in the colmation layer (upper 25 cm of poorly sorted bottom sediments) at two test locations characterized by dissimilar seepage rates (1.7 vs. 0.26 m d). Retention profiles in recovered core material indicated that >82% of the attached IU625 were in the top 3 cm of bottom sediments. The colmation layer was also responsible for rapid changes in the character of the DOC and was more effective (by three orders of magnitude) at removing microspheres than was the underlying 20-cm-thick segment of sediment. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  5. Notable increases in nutrient concentrations in a shallow lake during seasonal ice growth.

    PubMed

    Fang, Yang; Changyou, Li; Leppäranta, Matti; Xiaonghong, Shi; Shengnan, Zhao; Chengfu, Zhang

    2016-12-01

    Nutrients may be eliminated from ice when liquid water is freezing, resulting in enhanced concentrations in the unfrozen water. The nutrients diluted from the ice may contribute to accumulated concentrations in sediment during winter and an increased risk of algae blooms during the following spring and summer. The objective of this study was to evaluate the influence of ice cover on nitrogen (N) and phosphorus (P) concentrations in the water and sediment of a shallow lake, through an examination of Ulansuhai Lake, northern China, from the period of open water to ice season in 2011-2013. The N and P concentrations were between two and five times higher, and between two and eight times higher, than in unfrozen lakes, respectively. As the ice thickness grew, contents of total N and total P showed C-shaped profiles in the ice, and were lower in the middle layer and higher in the bottom and surface layers. Most of the nutrients were released from the ice to liquid water. The results confirm that ice can cause the nutrient concentrations in water and sediment during winter to increase dramatically, thereby significantly impacting on processes in the water environment of shallow lakes.

  6. Characterization of a New Organosilicon Photoresist

    NASA Astrophysics Data System (ADS)

    Cunningham, Wells C.

    1987-08-01

    For a number of years, there has lo'ep. great interest in organometallic based photoresists for use as the top layer in multilevel resist schemes.-' In general, bilevel approaches to lithography are forced upon the industry as a means of planarizing topography for a subsequent patterning step. This pattern is initially defined by exposure and development of a thin top layer (0.3 to 0.5μm) over the thicker bottom layer (1.0 to 2.0μm). (See Figure 1). In a conventional bilevel approach, the chosen bottom layer is photoactive at a wavelength for which the top is relatively opaque. The top level acts as a portable conformable mask (PCM) for image transfer through the bottom layer after its exposure and wet development. By using a silicon containing photoresist on the top image transfer may be accomplished using an oxygen plasma instead of a second exposure and development. The PCM in this case acts as an etch mask by forming a silicon dioxide crust in the plasma which slows the etch rate of the top versus the bottom layer. A generic curve of etch rate of a photoresist versus percent silicon by weight is shown in Figure 2. The shape is similar over a wide range of organosilicon polymers.5,6

  7. Earth's crust model of the South-Okhotsk Basin by wide-angle OBS data

    NASA Astrophysics Data System (ADS)

    Kashubin, Sergey N.; Petrov, Oleg V.; Rybalka, Alexander V.; Milshtein, Evgenia D.; Shokalsky, Sergey P.; Verba, Mark L.; Petrov, Evgeniy O.

    2017-07-01

    Deep seismic studies of the Sea of Okhotsk region started in late 1950s. Since that time, wide-angle reflection and refraction data on more than two dozen profiles were acquired. Only five of those profiles either crossed or entered the deep-water area of the South-Okhotsk Basin (also known as the Kuril Basin or the South-Okhotsk Deep-Water Trough). Only P-waves were used to develop velocity-interface models in all the early research. Thus, all seismic and geodynamic models of the Okhotsk region were based only on the information on compressional waves. Nevertheless, the use of Vp/Vs ratio in addition to P-wave velocity allows discriminating felsic and mafic crustal layers with similar Vp values. In 2007 the Russian seismic service company Sevmorgeo acquired multi-component data with ocean bottom seismometers (OBS) along the 1700-km-long north-south 2-DV-M Profile. Only P-wave information was used previously to develop models for the entire profile. In this study, a multi-wave processing, analysis, and interpretation of the OBS data are presented for the 550-km-long southern segment of this Profile that crosses the deep-water South-Okhotsk Basin. Within this segment 50 seismometers were deployed with nominal OBS station spacing of 10-12 km. Shot point spacing was 250 m. Not only primary P-waves and S-waves but also multiples and P-S, S-P converted waves were analyzed in this study to constrain velocity-interface models by means of travel time forward modeling. In offshore deep seismic studies, thick water layer hinders an estimation of velocities in the sedimentary cover and in the upper consolidated crust. Primarily, this is due to the fact that refracted waves propagating in low-velocity solid upper layers interfere with high-amplitude direct water wave. However, in multi-component measurements with ocean bottom seismometers, it is possible to use converted and multiple waves for velocity estimations in these layers. Consequently, one can obtain P- and S-waves velocity models of the sedimentary strata and the upper consolidated crust. Velocity values in the upper consolidated crust beneath the South-Okhotsk Basin (Vp = 5.50-5.80 km/s, Vp/Vs = 1.74-1.76) allow interpretation of this 2.5-3.5-km-thick layer to be consistent with a felsic (granodioritic) crust. These results suggest that the Earth's crust in this region can be considered continental in nature, rather than previously accepted oceanic crust. Even though, the crust is thinned and stretched at this location.

  8. Study on wind wave variability by inhomogeneous currents in the closed seas

    NASA Astrophysics Data System (ADS)

    Bakhanov, Victor V.; Bogatov, Nikolai A.; Ermoshkin, Aleksei V.; Ivanov, Andrei Yu.; Kemarskaya, Olga N.; Titov, Victor I.

    2012-09-01

    Complex experiments were performed in the north-eastern part of the Black Sea and in the south-eastern part of the White Sea to study variability of the current fields and other characteristics of the sea, wind waves, and parameters of the near-surface atmospheric layer. Measurements were carried out from the onboard of the scientific research vessels by optical, radar and acoustic sensors. The heterogeneity of bottom topography in Black Sea had quasi-one-dimensional character. The case of the two-dimensionally heterogeneous relief of the bottom was investigated in the White Sea. The peculiarity of these experiments was simultaneous measurements from onboard of vessel synchronously with acquisitions of synthetic aperture radar (SAR) images of the Envisat and TerraSAR-X satellites. We have detected for the case of the quasi-one-dimensionally heterogeneous current a difference between the sea surface roughness above the shelf zone and the roughness at the deep bottom. We found that the inhomogeneities of the bottom topography can manifest as a change not only in the amplitude of different characteristics of surface wave and atmospheric near-water layer, but also in their frequency spectrum. In White Sea the special features of the flow of the powerful tidal current (up to 1 m/s) around the secluded underwater elevation and the spatial structure of surface anomalies in the field of these two-dimensional-heterogeneous currents are analyzed. The numerical simulation of the wind wave transformation in the field of two-dimensional- heterogeneous flows is carried out. The qualitative agreement of the calculation results with the experimental data is shown.

  9. Effects of beach morphology and waves on onshore larval transport

    NASA Astrophysics Data System (ADS)

    Fujimura, A.; Reniers, A.; Paris, C. B.; Shanks, A.; MacMahan, J.; Morgan, S.

    2015-12-01

    Larvae of intertidal species grow offshore, and migrate back to the shore when they are ready to settle on their adult substrates. In order to reach the habitat, they must cross the surf zone, which is characterized as a semi-permeable barrier. This is accomplished through physical forcing (i.e., waves and current) as well as their own behavior. Two possible scenarios of onshore larval transport are proposed: Negatively buoyant larvae stay in the bottom boundary layer because of turbulence-dependent sinking behavior, and are carried toward the shore by streaming of the bottom boundary layer; positively buoyant larvae move to the shore during onshore wind events, and sink to the bottom once they encounter high turbulence (i.e., surf zone edge), where they are carried by the bottom current toward the shore (Fujimura et al. 2014). Our biophysical Lagrangian particle tracking model helps to explain how beach morphology and wave conditions affect larval distribution patterns and abundance. Model results and field observations show that larval abundance in the surf zone is higher at mildly sloped, rip-channeled beaches than at steep pocket beaches. Beach attributes are broken up to examine which and how beach configuration factors affect larval abundance. Modeling with alongshore uniform beaches with variable slopes reveal that larval populations in the surf zone are negatively correlated with beach steepness. Alongshore variability enhances onshore larval transport because of increased cross-shore water exchange by rip currents. Wave groups produce transient rip currents and enhance cross-shore exchange. Effects of other wave components, such as wave height and breaking wave rollers are also considered.

  10. Polymeric waveguide array with 45 degree slopes fabricated by bottom side tilted exposure

    NASA Astrophysics Data System (ADS)

    Lin, Xiaohui; Dou, Xinyuan; Wang, Alan X.; Chen, Ray T.

    2011-01-01

    This paper demonstrated a practical fabrication process of polymeric waveguide array (12 channels) with 50μm(W)×50μm(H)×23mm(L) dimension and mirror embedded 45° degree slopes for vertical coupling purpose. The entire process contained three main parts: a SU8 pre-mold with 45° slope, a PDMS mold and the final waveguide array device. The key step of fabricating the pre-mold included a bottom side tilted exposure of SU8 photo resist. By placing the sample upside down, tilting by 58.7° and immersing into DI water, the ultraviolet (UV) beam that shined vertically was directed to go through from the bottom of the glass substrate into top side SU8 resist with 45° angle to form the surface. This method was able to guarantee no-gap contact between the mask pattern and the photo resist when exposing. By comparing the process complexity and achieved structure of the top and bottom side exposure, the later was proved to be a promising method for making high quality tilted structure without any tailing effect. The reversed PDMS mold was then fabricated on the SU8 pre-mold. The PDMS mold was used to imprint the cladding layer of the waveguide array. After metal deposition, core filling and top cladding layer coating, the final polymeric waveguide array device was achieved. For performance evaluation, 850nm laser beam from VCSEL was modulated to 10Gbps signals and vertically coupled into the waveguide array. The eye diagrams revealed high Q factor when transmitting signals along these waveguide array.

  11. Non-local rheology of stony debris flow propagating over a cohesionless sediment bed

    NASA Astrophysics Data System (ADS)

    Lanzoni, Stefano; Gregoretti, Carlo

    2016-04-01

    Velocity profiles of gravel-water mixtures observed in flume experiments often exhibit a double-slope behavior, with a lower narrower region where the velocity increases slowly, and an upper wider region often exhibiting a nearly linear behavior. Even though the flow can be classified within the grain-inertia regime, the overall profile seems to not conform to the power law (with exponent 1.5) distribution obtained by integrating along the normal to the flow the dispersive stresses envisaged by Bagnold (1954) in his pioneer work. Note that this formulation neglects the contribution to the velocity profile of the quasi-static (frictional) stresses that tend to dominate close to an erodible sediment bottom. The present work investigates the possibility to find out a uniformly valid distribution of shear stress from the bottom to the flow surface. To this aim we follow a heuristic coherence length approach (GDR-MIDI, 2004) similar to the mixing length procedure commonly used to study the atmospheric boundary layer over canopy (see, e.g., Harmann and Finnegan, 2007). A database built on 64 systematic debris flow experiments is used to disclose the general features of velocity profiles that establish within the body of almost steady water-sediment flows and the dependence of transport sediment volumetric concentration on the relevant parameters. The almost steady water-sediment flows considered in the study were generated by releasing a prescribed water discharge on a saturated layer of sediment (specifically, 3 mm gravel, 6 mm gravel, and 3 mm glass spheres) initially placed in a 10 m long and 0.2 m wide laboratory flume. The analysis clearly indicates that stony debris flow conditions characterized the experiments. The mixing length does not result constant, as required by a Bagnold-like profile, but varies gradually, from zero at the flow surface, to a finite value near the erodible bottom. We discuss this structure in terms of shear stress distribution along the normal to the flow, with particular attention to the role played by frictional stresses near to the movable bed over which the debris flow propagates.

  12. Selenium and trace element mobility affected by periodic displacement of stratification in the Great Salt Lake, Utah

    USGS Publications Warehouse

    Beisner, K.; Naftz, D.L.; Johnson, W.P.; Diaz, X.

    2009-01-01

    The Great Salt Lake (GSL) is a unique ecosystem in which trace element activity cannot be characterized by standard geochemical parameters due to the high salinity. Movement of selenium and other trace elements present in the lake bed sediments of GSL may occur due to periodic stratification displacement events or lake bed exposure. The water column of GSL is complicated by the presence of a chemocline persistent over annual to decadal time scales. The water below the chemocline is referred to as the deep brine layer (DBL), has a high salinity (16.5 to 22.9%) and is anoxic. The upper brine layer (UBL) resides above the chemocline, has lower salinity (12.6 to 14.7%) and is oxic. Displacement of the DBL may involve trace element movement within the water column due to changes in redox potential. Evidence of stratification displacement in the water column has been observed at two fixed stations on the lake by monitoring vertical water temperature profiles with horizontal and vertical velocity profiles. Stratification displacement events occur over periods of 12 to 24 h and are associated with strong wind events that can produce seiches within the water column. In addition to displacement events, the DBL shrinks and expands in response to changes in the lake surface area over a period of months. Laboratory tests simulating the observed sediment re-suspension were conducted over daily, weekly and monthly time scales to understand the effect of placing anoxic bottom sediments in contact with oxic water, and the associated effect of trace element desorption and (or) dissolution. Results from the laboratory simulations indicate that a small percentage (1%) of selenium associated with anoxic bottom sediments is periodically solubilized into the UBL where it potentially can be incorporated into the biota utilizing the oxic part of GSL.

  13. Fens, seasonal wetlands, and the unconfined pumice aquifer east of the Cascade Range, south-central Oregon

    NASA Astrophysics Data System (ADS)

    Cummings, M. L.; Large, A.; Mowbray, A.; Weatherford, J.; Webb, B.

    2013-12-01

    Fens and seasonal wetlands in the headwaters of the Klamath and Deschutes river basins in south-central Oregon are present in an area blanketed by 2 to 3 m of pumice during the Holocene eruption of Mount Mazama. The lower pumice unit, moderately sorted coarse pumice lapilli to blocks (0.3 to 0.7 cm), phenocrysts, and lithics is 1.5 to 2 m thick; the upper pumice unit, poorly sorted lapilli to blocks (0.2 to 6 cm), minor phenocrysts, and lithics is 1 m thick. Pumice is a perched, unconfined aquifer over low permeability bedrock or pre-eruption fine-grained sediment. Early landscape response included partial erosion of pumice from pre-eruption valleys followed by partial filling by alluvium: phenocryst- and lithic-rich sand grading upward to glassy silt with rounded pumice pebbles. Groundwater-fed wetlands, fens, associated with the unconfined pumice aquifer occur as areas of diffuse groundwater discharge through gently sloping, convex surfaces underlain by up to 1.4 m of peat. Locally, focused discharge through the confining peat layer feeds low discharge streams. Carnivorous plants (sundews and pitcher plants) may be present. The sharp contact between peat and underlying pumice is an erosion surface that cuts progressively deeper into the upper and lower pumice units downslope. At the base of the slope peat with fen discharge feeding surface flow, alluvium with no surface flow, or a subtle berm separating the slope underlain by peat from the valley bottom underlain by alluvium may be present. Distinct vegetation changes take place at this transition. The erosion surface that underlies the peat layer in the fen is at the surface on the opposing valley wall and progressively rises up through the lower and upper pumice units: iron staining and cementation of pumice is locally prominent. Up to 1.5 m difference in water table occurs between the fen and opposing valley wall. Water table in piezometers screened in peat is at the surface. Locally, water table screened in pumice below the peat confining layer is up to 24 cm above the surface. Electrical conductivity in groundwater from the unconfined pumice aquifer ranged between 20 and 45 μS/cm. Rarely, electrical conductivity greater than 250 μS/cm is measured. Hydrochemistry indicates these waters are distinctly different (Ca-bicarbonate, [Fe] up to 22 mg/l) from water commonly encountered in the unconfined pumice aquifer (Na-bicarbonate, [Fe] less than 0.07 mg/l). Seasonally elevated water tables are present where pre-eruption topography allows snowmelt to accumulate in the unconfined pumice aquifer in valley bottoms and upland surfaces. Differential hardness of volcanic bedrock units control distribution in valley bottoms; emplacement processes and weathering of flow tops control distribution in upland settings. In both settings the lower pumice unit is saturated, but the upper pumice unit may be absent or thin. Alluvium commonly overlies pumice in valley bottoms. The water table may fluctuate up to 1.5 m from the spring snowmelt to late summer. Electrical conductivity in the pumice aquifer ranges between 19 and 250 μS/cm and commonly increases at single sites as the dry season progresses.

  14. Southern Ocean bottom water characteristics in CMIP5 models

    NASA Astrophysics Data System (ADS)

    Heuzé, CéLine; Heywood, Karen J.; Stevens, David P.; Ridley, Jeff K.

    2013-04-01

    Southern Ocean deep water properties and formation processes in climate models are indicative of their capability to simulate future climate, heat and carbon uptake, and sea level rise. Southern Ocean temperature and density averaged over 1986-2005 from 15 CMIP5 (Coupled Model Intercomparison Project Phase 5) climate models are compared with an observed climatology, focusing on bottom water. Bottom properties are reasonably accurate for half the models. Ten models create dense water on the Antarctic shelf, but it mixes with lighter water and is not exported as bottom water as in reality. Instead, most models create deep water by open ocean deep convection, a process occurring rarely in reality. Models with extensive deep convection are those with strong seasonality in sea ice. Optimum bottom properties occur in models with deep convection in the Weddell and Ross Gyres. Bottom Water formation processes are poorly represented in ocean models and are a key challenge for improving climate predictions.

  15. WAVECALC: an Excel-VBA spreadsheet to model the characteristics of fully developed waves and their influence on bottom sediments in different water depths

    NASA Astrophysics Data System (ADS)

    Le Roux, Jacobus P.; Demirbilek, Zeki; Brodalka, Marysia; Flemming, Burghard W.

    2010-10-01

    The generation and growth of waves in deep water is controlled by winds blowing over the sea surface. In fully developed sea states, where winds and waves are in equilibrium, wave parameters may be calculated directly from the wind velocity. We provide an Excel spreadsheet to compute the wave period, length, height and celerity, as well as horizontal and vertical particle velocities for any water depth, bottom slope, and distance below the reference water level. The wave profile and propagation can also be visualized for any water depth, modeling the sea surface change from sinusoidal to trochoidal and finally cnoidal profiles into shallow water. Bedload entrainment is estimated under both the wave crest and the trough, using the horizontal water particle velocity at the top of the boundary layer. The calculations are programmed in an Excel file called WAVECALC, which is available online to authorized users. Although many of the recently published formulas are based on theoretical arguments, the values agree well with several existing theories and limited field and laboratory observations. WAVECALC is a user-friendly program intended for sedimentologists, coastal engineers and oceanographers, as well as marine ecologists and biologists. It provides a rapid means to calculate many wave characteristics required in coastal and shallow marine studies, and can also serve as an educational tool.

  16. Small scale patches of suspended matter and phytoplankton in the Elbe River estuary, German Bight and tidal flats

    NASA Technical Reports Server (NTRS)

    Doerffer, R.; Fischer, J.; Stoessel, M.; Brockmann, C.; Grassl, H.

    1989-01-01

    Landsat 5 TM measurements are found suitable for study of small scale features in coastal waters; three independent factors, namely suspended matter concentration, atmospheric scattering, and sea-surface temperature, were extracted from all seven TM channels on the basis of factor analysis. The distribution of suspended matter in near-surface water layer and sea surface temperature is observable with a spatial resolution of at least 120 x 120 sq m. The high correlation between water depth and suspended matter distribution established by ship-gathered data supports the presently hypothesized control by bottom topography and wind-modified tidal currents of eddy and front formation.

  17. The biomass of the deep-sea benthopelagic plankton

    NASA Astrophysics Data System (ADS)

    Wishner, K. F.

    1980-04-01

    Deep-sea benthopelagic plankton samples were collected with a specially designed opening-closing net system 10 to 100 m above the bottom in five different oceanic regions at depths from 1000 to 4700 m. Benthopelagic plankton biomasses decrease exponentially with depth. At 1000 m the biomass is about 1% that of the surface zooplankton, at 5000 m about 0.1%. Effects of differences in surface primary productivity on deep-sea plankton biomass are much less than the effect of depth and are detectable only in a few comparisons of extreme oceanic regions. The biomass at 10 m above the bottom is greater than that at 100 m above the bottom (in a three-sample comparison), which could be a consequence of an enriched near-bottom environment. The deep-sea plankton biomass in the Red Sea is anomalously low. This may be due to increased decomposition rates in the warm (22°C) deep Red Sea water, which prevent much detritus from reaching the deep sea. A model of organic carbon utilization in the benthic boundary layer (bottom 100 m), incorporating results from deep-sea sediment trap and respiration studies, indicates that the benthopelagic plankton use only a small amount of the organic carbon flux. A large fraction of the flux is unaccounted for by present estimates of benthic and benthopelagic respiration.

  18. Water mass dynamics shape Ross Sea protist communities in mesopelagic and bathypelagic layers

    NASA Astrophysics Data System (ADS)

    Zoccarato, Luca; Pallavicini, Alberto; Cerino, Federica; Fonda Umani, Serena; Celussi, Mauro

    2016-12-01

    Deep-sea environments host the largest pool of microbes and represent the last largely unexplored and poorly known ecosystems on Earth. The Ross Sea is characterized by unique oceanographic dynamics and harbors several water masses deeply involved in cooling and ventilation of deep oceans. In this study the V9 region of the 18S rDNA was targeted and sequenced with the Ion Torrent high-throughput sequencing technology to unveil differences in protist communities (>2 μm) correlated with biogeochemical properties of the water masses. The analyzed samples were significantly different in terms of environmental parameters and community composition outlining significant structuring effects of temperature and salinity. Overall, Alveolata (especially Dinophyta), Stramenopiles and Excavata groups dominated mesopelagic and bathypelagic layers, and protist communities were shaped according to the biogeochemistry of the water masses (advection effect and mixing events). Newly-formed High Salinity Shelf Water (HSSW) was characterized by high relative abundance of phototrophic organisms that bloom at the surface during the austral summer. Oxygen-depleted Circumpolar Deep Water (CDW) showed higher abundance of Excavata, common bacterivores in deep water masses. At the shelf-break, Antarctic Bottom Water (AABW), formed by the entrainment of shelf waters in CDW, maintained the eukaryotic genetic signature typical of both parental water masses.

  19. Selective Activation of the Deep Layers of the Human Primary Visual Cortex by Top-Down Feedback.

    PubMed

    Kok, Peter; Bains, Lauren J; van Mourik, Tim; Norris, David G; de Lange, Floris P

    2016-02-08

    In addition to bottom-up input, the visual cortex receives large amounts of feedback from other cortical areas [1-3]. One compelling example of feedback activation of early visual neurons in the absence of bottom-up input occurs during the famous Kanizsa illusion, where a triangular shape is perceived, even in regions of the image where there is no bottom-up visual evidence for it. This illusion increases the firing activity of neurons in the primary visual cortex with a receptive field on the illusory contour [4]. Feedback signals are largely segregated from feedforward signals within each cortical area, with feedforward signals arriving in the middle layer, while top-down feedback avoids the middle layers and predominantly targets deep and superficial layers [1, 2, 5, 6]. Therefore, the feedback-mediated activity increase in V1 during the perception of illusory shapes should lead to a specific laminar activity profile that is distinct from the activity elicited by bottom-up stimulation. Here, we used fMRI at high field (7 T) to empirically test this hypothesis, by probing the cortical response to illusory figures in human V1 at different cortical depths [7-14]. We found that, whereas bottom-up stimulation activated all cortical layers, feedback activity induced by illusory figures led to a selective activation of the deep layers of V1. These results demonstrate the potential for non-invasive recordings of neural activity with laminar specificity in humans and elucidate the role of top-down signals during perceptual processing. Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. Importance of the Gulf of Aqaba for the formation of bottom water in the Red Sea

    NASA Astrophysics Data System (ADS)

    Plähn, Olaf; Baschek, Burkard; Badewien, Thomas H.; Walter, Maren; Rhein, Monika

    2002-08-01

    Conductivity-temperature-depth tracer and direct current measurements collected in the northern Red Sea in February and March 1999 are used to study the formation of deep and bottom water in that region. Historical data showed that open ocean convection in the Red Sea can contribute to the renewal of intermediate or deep water but cannot ventilate the bottom water. The observations in 1999 showed no evidence for open ocean convection in the Red Sea during the winter 1998/1999. The overflow water from the Gulf of Aqaba was found to be the densest water mass in the northern Red Sea. An anomaly of the chlorofluorocarbon component CFC-12 observed in the Gulf of Aqaba and at the bottom of the Red Sea suggests a strong contribution of this water mass to the renewal of bottom water in the Red Sea. The CFC data obtained during this cruise are the first available for this region. Because of the new signal, it is possible for the first time to subdivide the deep water column into deep and bottom water in the northern Red Sea. The available data set also shows that the outflow water from the Gulf of Suez is not dense enough to reach down to the bottom of the Red Sea but was found about 250 m above the bottom.

  1. Plasmon resonance imaging apparatus having nano-lycurgus-cup arrays and methods of use

    DOEpatents

    Liu, Gang Logan; Gartia, Manas Ranjan; Hsiao, Austin Yin Kyai

    2016-10-11

    Apparatus and methods are disclosed that are configured to permit nanoplasmonic spectroscopy sensing in the form of colorimetric sensing. An example apparatus involves: (a) an array layer having a top surface and a bottom surface, wherein a plurality of nanoholes are defined in the top surface of the array layer, wherein the plurality of nanoholes each have at least one sidewall surface and a bottom surface, (b) a thin metal film disposed on the top surface of the array layer and on the bottom surface of each of the plurality of nanoholes, and (c) a plurality of nanoparticles disposed on the at least one sidewall surface of the plurality of nanoholes.

  2. Predicting redox conditions in groundwater at a regional scale

    USGS Publications Warehouse

    Tesoriero, Anthony J.; Terziotti, Silvia; Abrams, Daniel B.

    2015-01-01

    Defining the oxic-suboxic interface is often critical for determining pathways for nitrate transport in groundwater and to streams at the local scale. Defining this interface on a regional scale is complicated by the spatial variability of reaction rates. The probability of oxic groundwater in the Chesapeake Bay watershed was predicted by relating dissolved O2 concentrations in groundwater samples to indicators of residence time and/or electron donor availability using logistic regression. Variables that describe surficial geology, position in the flow system, and soil drainage were important predictors of oxic water. The probability of encountering oxic groundwater at a 30 m depth and the depth to the bottom of the oxic layer were predicted for the Chesapeake Bay watershed. The influence of depth to the bottom of the oxic layer on stream nitrate concentrations and time lags (i.e., time period between land application of nitrogen and its effect on streams) are illustrated using model simulations for hypothetical basins. Regional maps of the probability of oxic groundwater should prove useful as indicators of groundwater susceptibility and stream susceptibility to contaminant sources derived from groundwater.

  3. Role of indium tin oxide electrode on the microstructure of self-assembled WO3-BiVO4 hetero nanostructures

    NASA Astrophysics Data System (ADS)

    Song, Haili; Li, Chao; Van, Chien Nguyen; Dong, Wenxia; Qi, Ruijuan; Zhang, Yuanyuan; Huang, Rong; Chu, Ying-Hao; Duan, Chun-Gang

    2017-11-01

    Self-assembled WO3-BiVO4 nanostructured thin films were grown on a (001) yttrium stabilized zirconia (YSZ) substrate by the pulsed laser deposition method with and without the indium tin oxide (ITO) bottom electrode. Their microstructures including surface morphologies, crystalline phases, epitaxial relationships, interface structures, and composition distributions were investigated by scanning electron microscopy, high-resolution transmission electron microscopy, and X-ray energy dispersive spectroscopy. In both samples, WO3 formed nanopillars embedded into the monoclinic BiVO4 matrix with specific orientation relationships. In the sample with the ITO bottom electrode, an atomically sharp BiVO4/ITO interface was formed and the orthorhombic WO3 nanopillars were grown on a relaxed BiVO4 buffer layer with a mixed orthorhombic and hexagonal WO3 transition layer. In contrast, a thin amorphous layer appears at the interfaces between the thin film and the YSZ substrate in the sample without the ITO electrode. In addition, orthorhombic Bi2WO6 lamellar nanopillars were formed between WO3 and BiVO4 due to interdiffusion. Such a WO3-Bi2WO6-BiVO4 double heterojunction photoanode may promote the photo-generated charge separation and further improve the photoelectrochemical water splitting properties.

  4. Deformation localization forming and destruction over a decompression zone.

    NASA Astrophysics Data System (ADS)

    Turuntaev, Sergey; Kondratyev, Viktor

    2017-04-01

    Development of a hydrocarbon field is accompanied by deformation processes in the surrounding rocks. In particular, a subsidence of oil strata cap above a decompression zone near producing wells causes changes in the stress-strain state of the upper rocks. It was shown previously, that the stress spatial changes form a kind of arch structures. The shear displacements along the arch surfaces can occur, and these displacements can cause a collapse of casing or even man-made earthquakes. We present here the results of laboratory simulation of such a phenomenon. A laboratory setup was made in the form of narrow box 30x30x5 cm3 in size with a hole (0.6 cm in diameter) in its bottom. As a model of porous strata, a foam-rubber layer of 4.0 -10.5cm in thick was used, which was saturated with water. The foam was sealed to the bottom of the box; the upper part of the box was filled by the dry sand. The sand was separated from the foam by thin polyethylene film to prevent the sand wetting. For visualization the sand deformations, the front wall of the box was made transparent and the sand was marked by horizontal strips of the colored sand. In the experiments, the water was pumped out the foam layer through the bottom hole. After pumping-out 50 ml of the water, the localization of sand deformations above the sink hole became noticeable; after pumping-out 100 ml of the water, the localized deformation forms an arch. At the same time, there was no displacement on the upper surface of the sand. To amplify the localization effect, the foam was additionally squeezed locally. In this case, three surfaces of the localized deformation appeared in the sand. The vertical displacements decreased essentially with height, but they reached the upper layers of the sand. An influence of vibration on arches forming was investigated. Several types of vibrators were used, they were placed inside the sand or on the front side of the box. Resulting accelerations were measured by the accelerometers placed into the sand. It was found, that if the amplitudes of the accelerations are equal or greater than 0.37g, the localized deformation did not appear near the vibrator location, but arose at some distance from it. If the vibration amplitudes exceed the threshold value 0.39g everywhere in the sand, the deformation localization did not occur. When the vibrator is displaced from the center of the model, the localization vanished near its position.

  5. Implementation of the new hydrographic technologies for bottom topography and seafloor gas venting investigations in the russian northern seas

    NASA Astrophysics Data System (ADS)

    Koloskov, Evgenii

    2017-04-01

    The report examines modern hydrographic technologies for the Russian northern seas investigations. The new hydro acoustics methods for seabed study are discussed. It presents stages of seafloor relief studies in the Russian Arctic seas since the 1950s and the obtained results. At the beginning of the 21st century an entirely new phase of bathymetric investigations began with the use of Multibeam Echosounders (MB) and modern hydrographic software. The software tools to process and analyze the bathymetry, and more recently to characterize the seabed from the backscatter, are available in a majority of modern sonar systems. Besides the bathymetry and sonar data, modern MB can produce water column images. These hydrographic technologies provide the possibility to achieve a high level of the seafloor topography. The latest generation of hydrographic MB now has the ability to provide the water column images along with the seafloor. The gas seeps from multibeam water column data can be distantly discerned against the seabed relief background with the aid of the Fledermause software package ("FMMidwater" module). The ability to integrate the water column data with the seafoor and other information,in an integrated geospatial and temporal environment, enhanced the analysis and interpretation of the data which is essential for marine geological research and investigations. The modern hydrographic equipment presents the ability to integrate the MB digital relief models (DTM) and sub bottom profiler data. This provide the possibility to obtain not only the detailed seabed topography, but also the additional information concerning the structure of under bottom soil layers and presence of the endogenous objects in near bottom environment. The importance of the hydrographic software tools needed to process and analyze the bathymetry and water column data are emphasized. The practical importance of the water column and bottom profiler data processing for the submarine gas-hydrates survey is stated. The attention is paid to the implementation of the parametric sub bottom profilers - the low frequency sonar for the sea bottom vertical section investigation. The ability for the integrated presentation of the multibeam bathymetry and vertical curtains in the 3D environment are discussed. As an example of the modern swath survey results achieved with Kongsberg EM2040CD MB and hydrographic information technology QINSy/ Fledermause, are discussed and presented. This survey was performed for the RosNeft company in the Kara sea. Recommendations for the implementation of the multi beam echo sounder and parametric sub bottom profiler for the combined hydrographic and submarine gas-hydrates survey in the Russian northern seas are delivered.The gas-hydrate survey guidelines using MB and QINSy/Fledermause software are provided. The hydrographic software tools used to process and analyze the bathymetry can create the seafloor DTM with the high degree of resolution and provide 3D visualization.These new possibilities provide such realistic view of the sea bottom relief and environment that can be characterized as the marine landscapes. Thus it became possible to investigate the relief morphological peculiarities and obtain the information about the relief genesis. This opens the new opportunities for using the acoustic techniques for varies types of marine activity including the bottom environmental study. The appearance of the bottom thermokarst activity derived from the high resolution DTM generated from the real time MB data is presented. The bottom thermokarst provides the potential threat for underwater pipelines and other submarine communications. The arctic bottom relief peculiarities are also covered including grounded hummock traces and dome-shaped elevations. The investigation of such bottom land forms has become possible recently as the result of implementing the wide swath survey methods. Such unique relief features are in general related to seabed gas venting in the form of the submarine gas-hydrates seeps. The opportunities for investigation of the morphological relief peculiarities and getting the new information is mportant also for varies types of marine activity including the marine ecology study. The arctic sea specific microrelief images are provided to show the abnormality of the bottom surface. The main attention is paid to specific and bottom features such as trenches the grounded hummock traces and dome-shaped elevations of the Pingo-type-unique forms of microrelief usually confined to the bottom gas flow in the form of methane emissions. The attention is also paid to the consequences of the global climate change and its influence on the bottom sole. Key words: hydrographic technologies, hydro acoustics methods, swathe survey, sea bottom vertical section, submarine gas-hydrates, submarine permafrost, seafloor gas venting,multi beam echo sounder, parametric sub bottom profiler.

  6. Bacterial community structure across environmental gradients in permafrost thaw ponds: methanotroph-rich ecosystems

    PubMed Central

    Crevecoeur, Sophie; Vincent, Warwick F.; Comte, Jérôme; Lovejoy, Connie

    2015-01-01

    Permafrost thawing leads to the formation of thermokarst ponds that potentially emit CO2 and CH4 to the atmosphere. In the Nunavik subarctic region (northern Québec, Canada), these numerous, shallow ponds become well-stratified during summer. This creates a physico-chemical gradient of temperature and oxygen, with an upper oxic layer and a bottom low oxygen or anoxic layer. Our objective was to determine the influence of stratification and related limnological and landscape properties on the community structure of potentially active bacteria in these waters. Samples for RNA analysis were taken from ponds in three contrasting valleys across a gradient of permafrost degradation. A total of 1296 operational taxonomic units were identified by high throughput amplicon sequencing, targeting bacterial 16S rRNA that was reverse transcribed to cDNA. β-proteobacteria were the dominant group in all ponds, with highest representation by the genera Variovorax and Polynucleobacter. Methanotrophs were also among the most abundant sequences at most sites. They accounted for up to 27% of the total sequences (median of 4.9% for all samples), indicating the importance of methane as a bacterial energy source in these waters. Both oxygenic (cyanobacteria) and anoxygenic (Chlorobi) phototrophs were also well-represented, the latter in the low oxygen bottom waters. Ordination analyses showed that the communities clustered according to valley and depth, with significant effects attributed to dissolved oxygen, pH, dissolved organic carbon, and total suspended solids. These results indicate that the bacterial assemblages of permafrost thaw ponds are filtered by environmental gradients, and are complex consortia of functionally diverse taxa that likely affect the composition as well as magnitude of greenhouse gas emissions from these abundant waters. PMID:25926816

  7. Investigation of River Seismic Signal Induced by Sediment Transport and Water Flow: Controlled Dam Breaking Experiments

    NASA Astrophysics Data System (ADS)

    Chen, H. Y.; Chen, S. C.; Chao, W. A.

    2015-12-01

    Natural river's bedload often hard to measure, which leads numerous uncertainties for us to predict the landscape evolution. However, the measurement of bedload flux has its certain importance to estimate the river hazard. Thus, we use seismometer to receive the seismic signal induced by bedload for partially fill the gap of field measurement capabilities. Our research conducted a controlled dam breaking experiments at Landao River, Huisun Forest since it has advantage to well constraining the spatial and temporal variation of bedload transport. We set continuous bedload trap at downstream riverbed of dam to trap the transport bedload after dam breaking so as to analyze its grain size distribution and transport behavior. In the meantime we cooperate with two portable velocity seismometers (Guralp CMG6TD) along the river to explore the relationship between bedload transport and seismic signal. Bedload trap was divided into three layers, bottom, middle, and top respectively. After the experiment, we analyzed the grain size and found out the median particle size from bottom to top is 88.664mm, 129.601mm, and 214.801mm individually. The median particle size of top layer is similar with the upstream riverbed before the experiment which median particle size is 230.683mm. This phenomena indicated that as the river flow become stronger after dam breaking, the sediment size will thereupon become larger, which meant the sediment from upstream will be carried down by the water flow and turned into bedload. Furthermore, we may tell apart the seismic signal induced by water flow and bedload by means of two different position seismometers. Eventually, we may estimate the probable error band of bedload quantity via accurately control of water depth, time-lapse photography, 3D LiDAR and other hydrology parameters.

  8. The herbicide glyphosate and its metabolite AMPA in the Lavaux vineyard area, western Switzerland: proof of widespread export to surface waters. Part II: the role of infiltration and surface runoff.

    PubMed

    Daouk, Silwan; De Alencastro, Luiz F; Pfeifer, Hans-Rudolf

    2013-01-01

    Two parcels of the Lavaux vineyard area, western Switzerland, were studied to assess to which extent the widely used herbicide, glyphosate, and its metabolite aminomethylphosphonic acid (AMPA) were retained in the soil or exported to surface waters. They were equipped at their bottom with porous ceramic cups and runoff collectors, which allowed retrieving water samples for the growing seasons 2010 and 2011. The role of slope, soil properties and rainfall regime in their export was examined and the surface runoff/throughflows ratio was determined with a mass balance. Our results revealed elevated glyphosate and AMPA concentrations at 60 and 80 cm depth at parcel bottoms, suggesting their infiltration in the upper parts of the parcels and the presence of preferential flows in the studied parcels. Indeed, the succession of rainy days induced the gradual saturation of the soil porosity, leading to rapid infiltration through macropores, as well as surface runoff formation. Furthermore, the presence of more impervious weathered marls at 100 cm depth induced throughflows, the importance of which in the lateral transport of the herbicide molecules was determined by the slope steepness. Mobility of glyphosate and AMPA into the unsaturated zone was thus likely driven by precipitation regime and soil characteristics, such as slope, porosity structure and layer permeability discrepancy. Important rainfall events (>10 mm/day) were clearly exporting molecules from the soil top layer, as indicated by important concentrations in runoff samples. The mass balance showed that total loss (10-20%) mainly occurred through surface runoff (96%) and, to a minor extent, by throughflows in soils (4%), with subsequent exfiltration to surface waters.

  9. The frequency-domain approach for apparent density mapping

    NASA Astrophysics Data System (ADS)

    Tong, T.; Guo, L.

    2017-12-01

    Apparent density mapping is a technique to estimate density distribution in the subsurface layer from the observed gravity data. It has been widely applied for geologic mapping, tectonic study and mineral exploration for decades. Apparent density mapping usually models the density layer as a collection of vertical, juxtaposed prisms in both horizontal directions, whose top and bottom surfaces are assumed to be horizontal or variable-depth, and then inverts or deconvolves the gravity anomalies to determine the density of each prism. Conventionally, the frequency-domain approach, which assumes that both top and bottom surfaces of the layer are horizontal, is usually utilized for fast density mapping. However, such assumption is not always valid in the real world, since either the top surface or the bottom surface may be variable-depth. Here, we presented a frequency-domain approach for apparent density mapping, which permits both the top and bottom surfaces of the layer to be variable-depth. We first derived the formula for forward calculation of gravity anomalies caused by the density layer, whose top and bottom surfaces are variable-depth, and the formula for inversion of gravity anomalies for the density distribution. Then we proposed the procedure for density mapping based on both the formulas of inversion and forward calculation. We tested the approach on the synthetic data, which verified its effectiveness. We also tested the approach on the real Bouguer gravity anomalies data from the central South China. The top surface was assumed to be flat and was on the sea level, and the bottom surface was considered as the Moho surface. The result presented the crustal density distribution, which was coinciding well with the basic tectonic features in the study area.

  10. Plant pigment types, distributions, and influences on shallow water submerged aquatic vegetation mapping

    NASA Astrophysics Data System (ADS)

    Hall, Carlton R.; Bostater, Charles R., Jr.; Virnstein, Robert

    2004-11-01

    Development of robust protocols for use in mapping shallow water habitats using hyperspectral imagery requires knowledge of absorbing and scattering features present in the environment. These include, but are not limited to, water quality parameters, phytoplankton concentrations and species, submerged aquatic vegetation (SAV) species and densities, epiphytic growth on SAV, benthic microalgae and substrate reflectance characteristics. In the Indian River Lagoon, Fl. USA we conceptualize the system as having three possible basic layers, water column and SAV bed above the bottom. Each layer is occupied by plants with their associated light absorbing pigments that occur in varying proportions and concentrations. Phytoplankton communities are composed primarily of diatoms, dinoflagellates, and picoplanktonic cyanobacteria. SAV beds, including flowering plants and green, red, and brown macro-algae exist along density gradients ranging in coverage from 0-100%. SAV beds may be monotypic, or more typically, mixtures of the several species that may or may not be covered in epiphytes. Shallow water benthic substrates are colonized by periphyton communities that include diatoms, dinoflagellates, chlorophytes and cyanobacteria. Inflection spectra created form ASIA hyperspectral data display a combination of features related to water and select plant pigment absorption peaks.

  11. Alexandrium fundyense cyst viability and germling survival in light vs. dark at a constant low temperature

    NASA Astrophysics Data System (ADS)

    Vahtera, Emil; Crespo, Bibiana G.; McGillicuddy, Dennis J.; Olli, Kalle; Anderson, Donald M.

    2014-05-01

    Both observations and models suggest that large-scale coastal blooms of Alexandrium fundyense in the Gulf of Maine are seeded by deep-bottom cyst accumulation zones (“seed beds”) where cysts germinate from the sediment surface or the overlying near-bottom nepheloid layers at water depths exceeding 100 m. The germling cells and their vegetative progeny are assumed to be subject to mortality while in complete darkness, as they swim to illuminated surface waters. To test the validity of this assumption we conducted laboratory investigations of cyst viability and the survival of the germling cells and their vegetative progeny during prolonged exposure to darkness at a temperature of 6 °C, simulating the conditions in deep Gulf of Maine waters. We isolated cysts from bottom sediments collected in the Gulf of Maine under low red light and incubated them in 96-well tissue culture-plates in culture medium under a 10:14 h light:dark cycle and under complete darkness. Cyst viability was high, with excystment frequency reaching 90% in the illuminated treatment after 30 days and in the dark treatment after 50 days. Average germination rates were 0.062 and 0.038 d-1 for light and dark treatments, respectively. The dark treatment showed an approximately 2-week time lag in maximum germination rates compared to the light treatment. Survival of germlings was considerably lower in the dark treatment. In the light treatments, 47% of germinated cysts produced germlings that were able to survive for 7 days and produce vegetative progeny, i.e., there were live cells in the well along with an empty cyst at least once during the experiment. In the dark treatments 12% of the cysts produced germlings that were able to survive for the same length of time. When dark treatments are scaled to take into account non-darkness related mortality, approximately 28% of the cysts produced germlings that were able to survive for at least 7 days. Even though cysts are able to germinate in darkness, the lack of illumination considerably reduces survival rate of germling cells. In addition to viability of cysts in surface sediments and the near-bottom nepheloid layer, survivability of germling cells and their vegetative progeny at aphotic depths is an important consideration in assessing the quantitative role of deep-coastal cyst seed beds in bloom formation.

  12. A combined bottom-up/top-down approach to prepare a sterile injectable nanosuspension.

    PubMed

    Hu, Xi; Chen, Xi; Zhang, Ling; Lin, Xia; Zhang, Yu; Tang, Xing; Wang, Yanjiao

    2014-09-10

    To prepare a uniform nanosuspension of strongly hydrophobic riboflavin laurate (RFL) allowing sterile filtration, physical modification (bottom-up) was combined with high-pressure homogenization (top-down) method. Unlike other bottom-up approaches, physical modification with surfactants (TPGS and PL-100) by lyophilization controlled crystallization and compensated for the poor wettability of RFL. On one hand, crystal growth and aggregation during freezing was restricted by a stabilizer-layer adsorbed on the drug surface by hydrophobic interaction. On the other hand, subsequent crystallization of drug in the sublimation process was limited to the interstitial spaces between solvent crystals. After lyophilization, modified drug with a smaller particle size and better wettability was obtained. When adding surfactant solution, water molecules passed between the hydrophilic groups of surface active molecules and activated the polymer chains allowing them to stretch into water. The coarse suspension was crushed into a nanosuspension (MP=162 nm) by high-pressure homogenization. For long term stability, lyophilization was applied again to solidify the nanosuspension (sorbitol as cryoprotectant). A slight crystal growth to about 600 nm was obtained to allow slow release for a sustained effect after muscular administration. Moreover, no paw-licking responses and very slight muscular inflammation demonstrated the excellent biocompatibility of this long-acting RFL injection. Copyright © 2014 Elsevier B.V. All rights reserved.

  13. Shelf-Slope Exchanges near Submarine Canyons in the Southern Mid-Atlantic Bight

    NASA Astrophysics Data System (ADS)

    Wang, H.; Gong, D.

    2016-02-01

    Shelf-slope exchange processes are major physical drivers of biological productivity near the shelf-break. Observations from two Slocum ocean gliders in Fall 2013 are used to explore the driving mechanisms of cross-shelf-slope exchanges near Norfolk Canyon and Washington Canyon in the southern Mid-Atlantic Bight. Offshore excursion of bottom "cold pool" water, and shoreward intrusion of slope water at surface layer and thermocline depth occurred during northeasterly along-shelf winds. The saline intrusions of surface slope water resided between the cold pool and surface shelf water, and reached the bottom on the outer and mid-shelf, while the offshore excursion of cold pool water was found between the surface and intermediate slope-water over the canyon. Ekman transport calculation shows wind-driven cross-shelf transport can partially explain this interleaving pattern of intrusions. Scaling analysis of double diffusive processes demonstrate that they also likely played a role in the cross-shelf-slope exchange. A unique canyon upwelling event was captured in and around Washington Canyon during a period of southwesterly along-shelf wind and along-shelf flow to the northeast. The water mass distributions and isopycnal responses in both along-canyon and cross-canyon transects are consistent with scaling analysis and numerical studies of canyon upwelling. Temperature-Salinity properties of water masses in the canyon suggest active mixing between shelf and slope water masses near the canyon head. These results point to the importance of wind, double diffusion, and canyon topography on shelf-slope exchange in the MAB.

  14. Lattice-mismatched GaInP LED devices and methods of fabricating same

    DOEpatents

    Mascarenhas, Angelo; Steiner, Myles A; Bhusal, Lekhnath; Zhang, Yong

    2014-10-21

    A method (100) of fabricating an LED or the active regions of an LED and an LED (200). The method includes growing, depositing or otherwise providing a bottom cladding layer (208) of a selected semiconductor alloy with an adjusted bandgap provided by intentionally disordering the structure of the cladding layer (208). A first active layer (202) may be grown above the bottom cladding layer (208) wherein the first active layer (202) is fabricated of the same semiconductor alloy, with however, a partially ordered structure. The first active layer (202) will also be fabricated to include a selected n or p type doping. The method further includes growing a second active layer (204) above the first active layer (202) where the second active layer (204) Is fabricated from the same semiconductor alloy.

  15. Saltation movement of large spherical particles

    NASA Astrophysics Data System (ADS)

    Chara, Z.; Dolansky, J.; Kysela, B.

    2017-07-01

    The paper presents experimental and numerical investigations of the saltation motion of a large spherical particle in an open channel. The channel bottom was roughed by one layer of glass rods of diameter 6 mm. The plastic spheres of diameter 25.7 mm and density 1160 kgm-3 were fed into the water channel and theirs positions were viewed by a digital camera. Two light sheets were placed above and under the channel, so the flow was simultaneously lighted from the top and the bottom. Only particles centers of which moved through the light sheets were recorded. Using a 2D PIV method the trajectories of the spheres and the velocity maps of the channel flow were analyzed. The Lattice-Boldzmann Method (LBM) was used to simulate the particle motion.

  16. A simple method to model the reduced environment of lake bottom sapropel formation

    NASA Astrophysics Data System (ADS)

    Gaskova, Olga L.; Strakhovenko, Vera D.; Ermolaeva, Nadezhda I.; Zarubina, Eugene Yu.; Ovdina, Ekaterina A.

    2017-07-01

    The Kambala and Barchin brackish lakes (Baraba steppe, southern West Siberia) contain an organic-rich sapropel layer that was formed in oxygen-depleted waters. We measured the bulk sediment elemental composition, the water chemistry and determined the mineralogical composition and predominant biota species (Diatoms and Cyanobacteria in phytoplankton community respectively) in the lakes. The result indicates that the first lake has a siliceous type of sapropel and the second a carbonaceous one. A computer thermodynamic model was developed for chemical interaction in water-bottom sediment systems of the Kambala and Barchin Lakes. The surface sodium bicarbonate waters are supersaturated with respect to calcite, magnesite (or low Mg-calcite), quartz and chlorite with minor strontianite, apatite and goethite (pH 8.9-9.3, Eh 0.3 V). Nevertheless, it is shown that during sapropel deposition, deep silt waters should be anoxic (Eh<0 V). The virtual component CH2O has been used to create an anoxic environment suitable for pyrite formation due to the biotic community impact and abiotic reduction. Thermodynamic calculation has shown that silt water is not necessarily euxinic (anoxic and sulfidic). Depending on Eh, sulfate sulfur can dominate in solution, causing the formation of gypsum together with pyrite. An attempt was made to find a reason for solution supersaturation with respect to Ca and Mg ions due to their complexation with humic acids.

  17. Effect of sea level changes on the Quaternary emergent reef limestone near Sharm Abhur as revealed from geoelectrical soundings

    NASA Astrophysics Data System (ADS)

    El-Abd, Yakout; Awad, Morad

    The present paper deals with the study of shallow geological formations existing near Sharm Abhur at the Red Sea coast of Saudi Arabia. Fourteen vertical resistivity soundings (VES) have been conducted at different locations on both sides of the Sharm. Analysis of the data, together with the information obtained from three bore holes drilled in the area, were used to construct pseudo-, as well as true, resistivity sections. These were taken along and across the Sharm trend. The results show that the coralline limestone formation in the coastal plain near Sharm Abhur is subject to subsurface erosion and sea water invasion resulting in different layers of secondary product or diagenetically altered coralline limestone. Seepage of saline water through the Sharm basin was recognized. The basal layer feature along the sections is conformable with the general slope of the Sharm bottom.

  18. Velocity and bottom-stress measurements in the bottom boundary layer, outer Norton Sound, Alaska.

    USGS Publications Warehouse

    Cacchione, D.A.; Drake, D.E.; Wiberg, P.

    1982-01-01

    We have used long-term measurements of near-bottom velocities at four heights above the sea floor in Norton Sound, Alaska, to compute hourly values of shear velocity u., roughness and bottom-drag coefficient. Maximum sediment resuspension and transport, predicted for periods when the computed value of u. exceeds a critical level, occur during peak tidal currents associated with spring tides. The fortnightly variation in u. is correlated with a distinct nepheloid layer that intensifies and thickens during spring tides and diminishes and thins during neap tides. The passage of a storm near the end of the experiment caused significantly higher u. values than those found during fair weather.-from Authros

  19. Atomic layer deposition of Al{sub 2}O{sub 3} for single electron transistors utilizing Pt oxidation and reduction

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McConnell, Michael S., E-mail: mmcconn5@nd.edu; Schneider, Louisa C.; Karbasian, Golnaz

    This work describes the fabrication of single electron transistors using electron beam lithography and atomic layer deposition to form nanoscale tunnel transparent junctions of alumina (Al{sub 2}O{sub 3}) on platinum nanowires using either water or ozone as the oxygen precursor and trimethylaluminum as the aluminum precursor. Using room temperature, low frequency conductance measurements between the source and drain, it was found that devices fabricated using water had higher conductance than devices fabricated with ozone. Subsequent annealing caused both water- and ozone-based devices to increase in conductance by more than 2 orders of magnitude. Furthermore, comparison of devices at low temperaturesmore » (∼4 K) showed that annealed devices displayed much closer to the ideal behavior (i.e., constant differential conductance) outside of the Coulomb blockade region and that untreated devices showed nonlinear behavior outside of the Coulomb blockade region (i.e., an increase in differential conductance with source-drain voltage bias). Transmission electron microscopy cross-sectional images showed that annealing did not significantly change device geometry, but energy dispersive x-ray spectroscopy showed an unusually large amount of oxygen in the bottom platinum layer. This suggests that the atomic layer deposition process results in the formation of a thin platinum surface oxide, which either decomposes or is reduced during the anneal step, resulting in a tunnel barrier without the in-series native oxide contribution. Furthermore, the difference between ozone- and water-based devices suggests that ozone promotes atomic layer deposition nucleation by oxidizing the surface but that water relies on physisorption of the precursors. To test this theory, devices were exposed to forming gas at room temperature, which also reduces platinum oxide, and a decrease in resistance was observed, as expected.« less

  20. What Does a Multilayer Canopy Model Tell Us About Our Current Understanding of Snow-Canopy Unloading?

    NASA Astrophysics Data System (ADS)

    McGowan, L. E.; Paw U, K. T.; Dahlke, H. E.

    2017-12-01

    In the Western U.S., future water resources depend on the forested mountain snowpack. The variations in and estimates of forest mountain snow volume are vital to projecting annual water availability; yet, snow forest processes are not fully known. Most snow models calculate snow-canopy unloading based on time, temperature, Leaf Area Index (LAI), and/or wind speed. While models crudely consider the canopy shape via LAI, current models typically do not consider the vertical canopy structure or varied energetics within multiple canopy layers. Vertical canopy structure influences the spatiotemporal distribution of snow, and therefore ultimately determines the degree and extent by which snow alters both the surface energy balance and water availability. Within the canopy both the snowpack and energetic exposures to the snowpack (wind, shortwave and longwave radiation, turbulent heat fluxes etc.) vary widely in the vertical. The water and energy balance in each layer is dependent on all other layers. For example, increased snow canopy content in the top of the canopy will reduce available shortwave radiation at the bottom and snow unloading in a mid-layer can cascade and remove snow from all the lower layers. We examined vertical interactions and structures of the forest canopy on the impact of unloading utilizing the Advanced Canopy-Atmosphere-Soil-Algorithm (ACASA), a multilayer soil-vegetation-atmosphere numerical model based on higher-order closure of turbulence equations. Our results demonstrate how a multilayer model can be used to elucidate the physical processes of snow unloading, and could help researchers better parameterize unloading in snow-hydrology models.

  1. Improved Bilayer Resist System Using Contrast-Enhanced Lithography With Water-Soluble Photopolymer

    NASA Astrophysics Data System (ADS)

    Sasago, Masaru; Endo, Masayuki; Hirai, Yoshihiko; Ogawa, Kazufurni; Ishihara, Takeshi

    1986-07-01

    A new water-soluble contract enhanced material, WSP (Water-soluble Photopolymer), has been developed. The WSP is composed of a mainpolymer and a photobleachable reagents. The mainpolymer is a water-soluble polymer mixed with pullulan (refined through biotechnological process) and polyvinyl-pyrolidone (PVP). The photo-bleachable reagent is of a diazonium compound gorup. The introduction of the mainpolymer and photobleach-able reagent mixture has improved filmity, gas transparency, photobleaching characteristics and solubility in alkaline which are essential to the device fabrication. Submicron photoresist patterns are successfully fabricated by a simple sequence of photolithography process. The WSP layer has been applied to the bilayer resist system--deep-UV portable conformable masking (PCM)--that is not affected by VLSI's topography, and is able to fabricate highly accurate pattern. The aqueous developable layer, PMGI, with high organic solvent resistance is used in the bottom layer. Therefore, no interfacial mixing with conventional positive resist top layer is observed. Furthermore, deep-UV exposure method has been used for the KrF excimer laser optical system in order to increase high throughput. From the experiments, it has been confirmed that good resist transfer profile can be realized by the use of WSP, and that the submicron resist patterns with high aspect-ratio can be developed on the nonplaner wafer with steps of up to 41m by the combination of the WSP with the PCM system. By this technology, has been improved the weak point: variation in the line width due to the thickness of contrast-enhanced layer when the CEL technology is applied, and dependency of both the finished resist profile and the line-width accuracy on the thickness of the top layer resist when the PCM system is adopted.

  2. Series interconnected photovoltaic cells and method for making same

    DOEpatents

    Albright, S.P.; Chamberlin, R.R.; Thompson, R.A.

    1995-01-31

    A novel photovoltaic module and method for constructing the same are disclosed. The module includes a plurality of photovoltaic cells formed on a substrate and laterally separated by interconnection regions. Each cell includes a bottom electrode, a photoactive layer and a top electrode layer. Adjacent cells are connected in electrical series by way of a conductive-buffer line. The buffer line is also useful in protecting the bottom electrode against severing during downstream layer cutting processes. 11 figs.

  3. Development of water movement model as a module of moisture content simulation in static pile composting.

    PubMed

    Seng, Bunrith; Kaneko, Hidehiro; Hirayama, Kimiaki; Katayama-Hirayama, Keiko

    2012-01-01

    This paper presents a mathematical model of vertical water movement and a performance evaluation of the model in static pile composting operated with neither air supply nor turning. The vertical moisture content (MC) model was developed with consideration of evaporation (internal and external evaporation), diffusion (liquid and vapour diffusion) and percolation, whereas additional water from substrate decomposition and irrigation was not taken into account. The evaporation term in the model was established on the basis of reference evaporation of the materials at known temperature, MC and relative humidity of the air. Diffusion of water vapour was estimated as functions of relative humidity and temperature, whereas diffusion of liquid water was empirically obtained from experiment by adopting Fick's law. Percolation was estimated by following Darcy's law. The model was applied to a column of composting wood chips with an initial MC of 60%. The simulation program was run for four weeks with calculation span of 1 s. The simulated results were in reasonably good agreement with the experimental results. Only a top layer (less than 20 cm) had a considerable MC reduction; the deeper layers were comparable to the initial MC, and the bottom layer was higher than the initial MC. This model is a useful tool to estimate the MC profile throughout the composting period, and could be incorporated into biodegradation kinetic simulation of composting.

  4. Long-term performance and bacterial community dynamics in biocovers for mitigating methane and malodorous gases.

    PubMed

    Lee, Eun-Hee; Moon, Kyung-Eun; Cho, Kyung-Suk

    2017-01-20

    The long-term performance of lab-scale biocovers for the simulation of engineered landfill cover soils was evaluated. Methane (CH 4 ), trimethylamine (TMA), and dimethyl sulfide (DMS) were introduced into the biocovers as landfill gases for 134 days and the removal performance was evaluated. The biocover systems were capable of simultaneously removing methane, TMA, and DMS. Methane was mostly eliminated in the top layer of the systems, while TMA and DMS were removed in the bottom layer. Overall, the methane removal capacity and efficiency were 224.8±55.6g-CH 4 m -2 d -1 and 66.6±12.8%, respectively, whereas 100% removal efficiencies of both TMA and DMS were achieved. Using quantitative PCR and pyrosequencing assay, the bacterial and methanotrophic communities in the top and bottom layers were analyzed along with the removal performance of landfill gases in the biocovers. The top and bottom soil layers possessed distinct communities from the original inoculum, but their structure dynamics were different from each other. While the structures of the bacterial and methanotrophic communities showed little change in the top layer, both communities in the bottom layer were considerably shifted by adding TMA and DMA. These findings provide information that can extend the understanding of full-scale biocover performance in landfills. Copyright © 2016 Elsevier B.V. All rights reserved.

  5. Numerical simulations of the stratified oceanic bottom boundary layer

    NASA Astrophysics Data System (ADS)

    Taylor, John R.

    Numerical simulations are used to consider several problems relevant to the turbulent oceanic bottom boundary layer. In the first study, stratified open channel flow is considered with thermal boundary conditions chosen to approximate a shallow sea. Specifically, a constant heat flux is applied at the free surface and the lower wall is assumed to be adiabatic. When the surface heat flux is strong, turbulent upwellings of low speed fluid from near the lower wall are inhibited by the stable stratification. Subsequent studies consider a stratified bottom Ekman layer over a non-sloping lower wall. The influence of the free surface is removed by using an open boundary condition at the top of the computational domain. Particular attention is paid to the influence of the outer layer stratification on the boundary layer structure. When the density field is initialized with a linear profile, a turbulent mixed layer forms near the wall, which is separated from the outer layer by a strongly stable pycnocline. It is found that the bottom stress is not strongly affected by the outer layer stratification. However, stratification reduces turbulent transport to the outer layer and strongly limits the boundary layer height. The mean shear at the top of the boundary layer is enhanced when the outer layer is stratified, and this shear is strong enough to cause intermittent instabilities above the pycnocline. Turbulence-generated internal gravity waves are observed in the outer layer with a relatively narrow frequency range. An explanation for frequency content of these waves is proposed, starting with an observed broad-banded turbulent spectrum and invoking linear viscous decay to explain the preferential damping of low and high frequency waves. During the course of this work, an open-source computational fluid dynamics code has been developed with a number of advanced features including scalar advection, subgrid-scale models for large-eddy simulation, and distributed memory parallelism.

  6. Convection induced by selective absorption of radiation: A laboratory model of conditional instability

    NASA Astrophysics Data System (ADS)

    Krishnamurti, Ruby

    1998-01-01

    When there is internal heating in a fluid layer, convection can occur even if the static state is one of stable stratification. We have been investigating through laboratory experiments such a stably stratified layer of water which is heated above and cooled below. The water contains in dilute solution thymol blue (a pH indicator), which normally colors the water orange. It turns yellow if the pH is low, blue if the pH is high. A small DC voltage is applied across the layer, by using the bottom boundary as the positive electrode, the top boundary as the negative electrode. The hydroxyl ions formed near the bottom boundary cause the orange fluid to turn blue. The fluid layer is uniformly and steadily illuminated from above with light from a sodium vapor lamp. This radiation travels with negligible absorption through the orange fluid but is strongly absorbed by the blue fluid. The resultant warming of the blue fluid can lead to convective instability, with the blue fluid rising into warm upper layers, which it would continue to penetrate as long as it remains blue and as long as the radiative heating is sufficient to exceed the higher ambient temperatures above. This radiative heating occurs only in the blue rising flow; the sinking fluid is orange and is not heated. We have found that with a strongly stably stratified layer, convective plumes are unable to penetrate far and they remain shallow. However, for a weakly stratified layer, plumes grow tall and furthermore collect into a large convective cluster which persists as a steady coherent structure. The present paper deals also with the formulation of the governing equations to include the fluid-state-dependent heat source. A linear stability analysis shows that the critical Rayleigh number for onset of motion is drastically reduced. Furthermore, the cell size at onset is larger by a factor of √ 3/2 than in the classical Rayleigh-Benard convection problem. However, the laboratory fluid cells were much further broadened (by a factor of 8 or 10) when they penetrated into the stably stratified fluid above. In this case, the rising region is narrow and the sinking region is broad, so that downward vertical velocities are correspondingly small. In this way, the downwards-forced warm fluid has time to cool by conduction to the cold boundary. Steady finite amplitude solutions and their stability are analyzed and it is shown that there is a parameter range in which finite amplitude hexagonal cells are stable.

  7. Violent storms within the sea: Dense water formation episodes in the Mediterranean.

    NASA Astrophysics Data System (ADS)

    Salat, J.

    2009-09-01

    The Mediterranean is a semi enclosed basin which receives surface water from the Atlantic Ocean. Most of this water is returned into the Ocean with higher density, spreading at more than 1000 m depth (the rest is transported by the atmosphere and the rivers to the Ocean surface). In terms of water budget, the Mediterranean is considered an evaporation basin, but the loss of water is neither the only process that increases the water density nor it is a steady or uniform process. The factors affecting the water density, temperature and salinity, are driven by mass and heat exchanges with the atmosphere. Those exchanges may be by direct contact or mediated by the land. Therefore, changes in water density depend on the water circulation and local weather conditions, both with seasonal and geographical constraints. As the compressibility of water is very low, stratification is expected and horizontal motion is the predominant in the sea interior. Among the few processes that may introduce a vertical component in the water motion are surface heat loss or evaporation that increase the surface water density triggering convective cells. Such processes will be enhanced by surface cooling or by dry continental winds, and counterbalanced by rain, river runoff, solar heating and condensation. Therefore dense water formation are more likely to occur when sea surface temperature is higher than the surface air temperature. There are several scales of convective motions in the ocean, starting from the formation of the surface mixed layer during summer, by night cooling, breezes, and occasional wind storms. During autumn and winter, the vertical scale of the mixing is increasing by steps, through wind storms and progressive cooling, to easily reach the bottom over the continental shelves, typically not deeper than 150 m. However, as the Gibraltar sill is relatively shallow (~350 m) in relation to the average Mediterranean basin (2000-3000 m), the stratification of the deeper layers is weak. Therefore, where and when the surface layer becomes well mixed, typically in winter, in the northern regions, conditions are given (pre-conditioning phase) to the occurrence of dense water formation episodes. Those episodes require the participation of strong cold and dry winds which force an intense evaporation. In the NW Mediterranean, such forcing may act over the continental shelves, like that of the Gulf of Lions, or over deep open seas, typically the central part east of Catalonia and south of Provence. Over the shelf, surface water is expected to be fresher because of the runoff (e.g. the Rhône). Along the continental margin the water circulation, geostrophically adapted, is cyclonic and the stratification in the centre is lower, then density reached may be higher in the central part than on the shelf. However, cooling will be more effective over the shelf as the heat content of the water column is lower because it is much shorter. Once density over the shelf is high enough, the bottom water overflows and violently sinks along the slope in relatively narrow areas through what has been called a cascading event. In the central part, dense water formed sinks almost vertically in funnels not larger than a few kilometres in diameter, and is accompanied by a compensating rise of water from great depth on all sides. In such open sea winter convection events, the dense water can sink some 800 m within a matter of hours and may reach the bottom level, >2500 m deep, within a couple of days. Such short and violent episodes, cascading or open sea convection, of a few days' duration supply enough water to feed the lower layer to compensate the outflow through the Strait of Gibraltar for several weeks. The repeated events in some few points across the Mediterranean, like those above mentioned, are maintaining the Mediterranean circulation and the water exchanges with the Ocean. The overall amount of dense water formed however is highly variable from one year to another according to the forcings involved and perturbations of the water circulation.

  8. Freshwater and polynya components of the shelf-derived Arctic Ocean halocline in summer 2007 identified by stable oxygen isotopes

    NASA Astrophysics Data System (ADS)

    Bauch, D.; Rutgers van der Loeff, M.; Andersen, N.; Torres-Valdes, S.; Bakker, K.; Abrahamsen, E.

    2011-12-01

    With the aim of determining the origin of freshwater in the halocline, fractions of river water and sea-ice meltwater (or brine influence from sea-ice formation) in the upper 150 m were quantified by a combination of salinity and δ18O and nutrients in the Eurasian basins and the Makarov Basin. Our study indicates which layers of the Arctic Ocean halocline are primarily influenced by sea-ice formation in coastal polynyas and which are primarily influenced by sea-ice formation over the open ocean. With the ongoing changes in sea-ice coverage in the Arctic Ocean it can be expected that these processes will change in the immediate future and that the relative contributions to the halocline will change accordingly. Within the Eurasian Basin a west to east oriented front between net melting and production of sea-ice is observed. Outside the Atlantic regime dominated by net sea-ice melting, a pronounced layer influenced by brines released during sea-ice formation is present at about 30 to 50 m water depth with a maximum over the Lomonosov Ridge. The geographically distinct definition of this maximum demonstrates the rapid release and transport of signals from the shelf regions in discrete pulses within the Transpolar Drift. We use the ratio of sea-ice derived brine influence and river water to link the maximum in brine influence within the Transpolar Drift with a pulse of shelf waters from the Laptev Sea likely released in summer 2005. For a distinction of Atlantic and Pacific-derived contributions the initial phosphate corrected for mineralization with oxygen (PO*) and alternatively the nitrate to phosphate ratio (N/P) in each sample were used. While PO*-based assessments systematically underestimate the contribution of Pacific-derived waters, N/P-based calculations overestimate Pacific-derived waters within the Transpolar Drift due to denitrification in bottom sediments of the Laptev Sea. The extent of Pacific-derived water in the Arctic Ocean was approximately limited by the position of the Lomonosov Ridge in 2007. The ratio of sea-ice derived brine influence and river water is roughly constant within each layer of the Arctic Ocean halocline. The correlation between brine influence and river water reveals two clusters that can be assigned to the two main mechanisms of sea-ice formation within the Arctic Ocean. Over the open ocean or in polynyas at the continental slope sea-ice formation results in a linear correlation between brine influence and river water at salinities of ~ 32 to 34. In coastal polynyas in the shallow regions of the Laptev Sea and southern Kara Sea, sea-ice formation transports river water into the shelf's bottom layer due to the close proximity to the river mouths. This process results in a second linear correlation between brine influence and river water at salinities of ~ 30 to 32.

  9. A modified gradient approach for the growth of low-density InAs quantum dot molecules by molecular beam epitaxy

    NASA Astrophysics Data System (ADS)

    Sharma, Nandlal; Reuter, Dirk

    2017-11-01

    Two vertically stacked quantum dots that are electronically coupled, so called quantum dot molecules, are of great interest for the realization of solid state building blocks for quantum communication networks. We present a modified gradient approach to realize InAs quantum dot molecules with a low areal density so that single quantum dot molecules can be optically addressed. The individual quantum dot layers were prepared by solid source molecular beam epitaxy depositing InAs on GaAs(100). The bottom quantum dot layer has been grown without substrate rotation resulting in an In-gradient across the surface, which translated into a density gradient with low quantum dot density in a certain region of the wafer. For the top quantum dot layer, separated from the bottom quantum dot layer by a 6 nm thick GaAs barrier, various InAs amounts were deposited without an In-gradient. In spite of the absence of an In-gradient, a pronounced density gradient is observed for the top quantum dots. Even for an In-amount slightly below the critical thickness for a single dot layer, a density gradient in the top quantum dot layer, which seems to reproduce the density gradient in the bottom layer, is observed. For more or less In, respectively, deviations from this behavior occur. We suggest that the obvious influence of the bottom quantum dot layer on the growth of the top quantum dots is due to the strain field induced by the buried dots.

  10. Changes in quantity and spectroscopic properties of water-extractable organic matter during soil aquifer treatment.

    PubMed

    Xue, S; Zhao, Q L; Wei, L L; Ma, X P; Tie, M

    2013-01-01

    The aim of this study was to identify qualitative and quantitative changes in the character of water-extractable organic matter (WEOM) in soils as a consequence of soil aquifer treatment (SAT). Soil samples were obtained from a soil-column system with a 2-year operation, and divided into seven layers from top to bottom: CS1 (0-12.5 cm), CS2 (12.5-25 cm), CS3 (25-50 cm), CS4 (50-75 cm), CS5 (75-100 cm), CS6 (100-125 cm) and CS7 (125-150 cm). A sample of the original soil used to pack the columns was also analysed to determine the effects of SAT. Following 2 years of SAT operation, both soil organic carbon and water-extractable organic carbon were shown to accumulate in the top soil layer (0-12.5 cm), and to decrease in soil layers deeper than 12.5 cm. The WEOM in the top soil layer was characterized by low aromaticity index (AI), low emission humification index (HIX) and low fluorescence efficiency index (F(eff)). On the other hand, the WEOM in soil layers deeper than 12.5 cm had increased values of HIX and F(eff), as well as decreased AI values relative to the original soil before SAT. In all soil layers, the percentage of hydrophobic and transphilic fractions decreased, while that of the hydrophilic fraction increased, as a result of SAT. The production of the amide-2 functional groups was observed in the top soil layer. SAT operation also led to the enrichment of hydrocarbon and amide-1 functional groups, as well as the depletion of oxygen-containing functional groups in soil layers deeper than 12.5 cm.

  11. Coastal Microstructure: From Active Overturn to Fossil Turbulence

    NASA Astrophysics Data System (ADS)

    Tau Leung, Pak

    2011-11-01

    The Remote Anthropogenic Sensing Program was a five year effort (2001- 2005) to examine subsurface phenomena related to a sewage outfall off the coast of Oahu, Hawaii. This research has implications for basic ocean hydrodynamics, particularly for a greatly improved understanding of the evolution of turbulent patches. It was the first time a microstructure measurement was used to study such a buoyancy-driven turbulence generated by a sea-floor diffuser. In 2004, two stations were selected to represent the near field and ambient conditions. They have nearly identical bathymetrical and hydrographical features and provide an ideal environment for a control experiment. Repeated vertical microstructure measurements were performed at both stations for 20 days. A time series of physical parameters was collected and used for statistical analysis. After comparing the data from both stations, it can be concluded that the turbulent mixing generated by the diffuser contributes to the elevated dissipation rate observed in the pycnocline and bottom boundary layer. To further understand the mixing processes in both regions, data were plotted on a Hydrodynamic Phase Diagram. The overturning stages of the turbulent patches are identified by Hydrodynamic Phase Diagram. This technique provides detailed information on the evolution of the turbulent patches from active overturns to fossilized scalar microstructures in the water column. Results from this study offer new evidence to support the fossil turbulence theory. This study concluded that: 1. Field Data collected near a sea-floor outfall diffuser show that turbulent patches evolve from active (overturning) to fossil (buoyancy-inhibited) stages, consistent with the process of turbulent patch evolution proposed by fossil turbulence theory. 2. The data show that active (overturning) and fossil (buoyancy-inhibited) patches have smaller length scales than the active+fossil (intermediate) stage of patch evolution, consistent with fossil turbulence theory and with laboratory studies. 3. Compared to a far-field reference, elevated dissipation rates near the diffuser were found in the seasonal pycnocline as well as in the bottom boundary layer. 4. More than 90% of the turbulent patches observed in the water column were non- overturning (active+fossil and fossil). Such patches can provide significant mixing in the interior of the ocean, far from surface and bottom boundary layers.

  12. Earth Observations taken by Expedition 38 Crewmember

    NASA Image and Video Library

    2014-02-14

    ISS038-E-047388 (14 Feb. 2014) --- As the International Space Station passed over the deserts of central Iran, including Kavir, one of the Expedition 38 crew members used a digital camera equipped with a 200mm lens to record this image featuring an unusual pattern of numerous parallel lines and sweeping curves. The lack of soil and vegetation allows the geological structure of the rocks to appear quite clearly. According to geologists, the patterns result from the gentle folding of numerous, thin, light and dark layers of rock. Later erosion by wind and water, say the scientists, cut a flat surface across the folds, not only exposing hundreds of layers but also showing the shapes of the folds. The dark water of a lake (image center) occupies a depression in a more easily eroded, S-shaped layer of rock. The irregular light-toned patch just left of the lake is a sand sheet thin enough to allow the underlying rock layers to be detected. A small river snakes across the bottom of the image. In this desert landscape there are no fields or roads to give a sense of scale. In fact, the image width represents a distance of 65 kilometers.

  13. Characteristics of the near-bottom suspended sediment field over the continental shelf off northern California based on optical attenuation measurements during STRESS and SMILE

    NASA Astrophysics Data System (ADS)

    Trowbridge, J. H.; Butman, B.; Limeburner, R.

    1994-08-01

    Time-series measurements of current velocity, optical attenuation and surface wave intensity obtained during the Sediment Transport Events on Shelves and Slopes (STRESS) experiments, combined with shipboard measurements of conductivity, temperature and optical attenuation obtained during the Shelf Mixed Layer Experiment (SMILE), provide a description of the sediment concentration field over the central and outer shelf off northern California. The questions addressed are: (1) existence and characteristics of bottom nepheloid layers and their relationship to bottom mixed layers; (2) characteristics of temporal fluctuations in sediment concentration and their relationship to waves and currents; (3) spatial scales over which suspended sediment concentrations vary horizontally; and (4) vertical distribution of suspended sediment.

  14. Biogeochemical and microbiological characteristic of the pockmark sediments, the Gdansk Deep, The Baltic Sea

    NASA Astrophysics Data System (ADS)

    Pimenov, Nikolay; Kanapatskiy, Timur; Sivkov, Vadim; Toshchakov, Stepan; Korzhenkov, Aleksei; Ulyanova, Marina

    2016-04-01

    Comparison of the biogeochemical and microbial features was done for the gas-bearing and background sediments as well as near-bottom water of the Gdansk Deep, The Baltic Sea. Data were received in October, 2015 during 64th cruise of the R/V Akademik Mstislav Keldysh. Gas-bearing sediments were sampled within the known pockmark (Gas-Point, depth 94 m). Background sediments area (BG-Point, depth 86 m) was located several km off the pockmark area. The sulphate concentration in the pore water of the surface sediment layer (0-5 cm) of Gas-Point was 9,7 mmol/l, and sharply decreased with depth (did not exceed 1 mmol/l deeper than 50 cm). The sulphate concentration decrease at BG-Point also took place but was not so considerable. Sulphate concentration decrease is typical for the organic rich sediments of the high productive areas, both as for the methane seep areas. Fast sulphate depletion occurs due to active processes of its microbial reduction by consortium of the sulphate-reduction bacteria, which may use low-molecular organic compounds or hydrogen, formed at the different stages of the organic matter destruction; as well as within the process of the anaerobic methane oxidation by consortium of the methane-trophic archaea and sulphate-reduction bacteria. Together with sulphate concentration decrease the methane content increase, typical for the marine sediments, occurred. At the Gas-Point the methane concentration varied within 10 μmol/dm3 in the surface layer till its maximum at sediment horizon of 65 cm (5 mmol/dm3), and decreased to 1.5 mmol/dm3 at depth of 300 cm. The BG-Point maximum values were defined at sediment horizon 6 cm (2,6 μmol/dm3). Methane sulfate transition zone at the Gas-Point sediments was at 25-35 cm depth; whereas it was not defined at the BG-Point mud. High methane concentration in the gas-bearing sediments results in the formation of the methane seep from the sediments to the near-bottom water. So the Gas-Point near-bottom waters were characterized by high methane concentration (0.36-0.50 μmol/l) even in the water 2-5 m above the bottom (0.08-0.28 μmol/l), whereas at the BG-Point sediments methane concentration in the near-bottom water was 0.06-0.08 μmol/l. In order to get insights into the structure of microbial community responsible for realization of these redox processes we performed microbial community profiling using high-throughput 16S amplicon sequencing. DNA was extracted from sediments and water column in pockmark and background zones. NGS libraries were prepared with fusion primers for V4 variable region (Caporaso et al., 2012) and sequenced on the MiSeq system. Results well correlated with new data obtained from the analysis of the intensity of microbial processes. The study was financed by the Russian Scientific Fund (grant 14-37-00047). Caporaso JG, Lauber CL, Walters WA, Berg-Lyons D, Huntley J, Fierer N, Owens SM, Betley J, Fraser L, Bauer M, Gormley N, Gilbert JA, Smith G, Knight R. Ultra-high-throughput microbial community analysis on the Illumina HiSeq and MiSeq platforms. ISME J. 2012 Aug;6(8):1621-4

  15. Improving organic tandem solar cells based on water-processed nanoparticles by quantitative 3D nanoimaging.

    PubMed

    Pedersen, E B L; Angmo, D; Dam, H F; Thydén, K T S; Andersen, T R; Skjønsfjell, E T B; Krebs, F C; Holler, M; Diaz, A; Guizar-Sicairos, M; Breiby, D W; Andreasen, J W

    2015-08-28

    Organic solar cells have great potential for upscaling due to roll-to-roll processing and a low energy payback time, making them an attractive sustainable energy source for the future. Active layers coated with water-dispersible Landfester particles enable greater control of the layer formation and easier access to the printing industry, which has reduced the use of organic solvents since the 1980s. Through ptychographic X-ray computed tomography (PXCT), we image quantitatively a roll-to-roll coated photovoltaic tandem stack consisting of one bulk heterojunction active layer and one Landfester particle active layer. We extract the layered morphology with structural and density information including the porosity present in the various layers and the silver electrode with high resolution in 3D. The Landfester particle layer is found to have an undesired morphology with negatively correlated top- and bottom interfaces, wide thickness distribution and only partial surface coverage causing electric short circuits through the layer. By top coating a polymer material onto the Landfester nanoparticles we eliminate the structural defects of the layer such as porosity and roughness, and achieve the increased performance larger than 1 V expected for a tandem cell. This study highlights that quantitative imaging of weakly scattering stacked layers of organic materials has become feasible by PXCT, and that this information cannot be obtained by other methods. In the present study, this technique specifically reveals the need to improve the coatability and layer formation of Landfester nanoparticles, thus allowing improved solar cells to be produced.

  16. Effects of bottom water dissolved oxygen variability on copper and lead fractionation in the sediments across the oxygen minimum zone, western continental margin of India.

    PubMed

    Chakraborty, Parthasarathi; Chakraborty, Sucharita; Jayachandran, Saranya; Madan, Ritu; Sarkar, Arindam; Linsy, P; Nath, B Nagender

    2016-10-01

    This study describes the effect of varying bottom-water oxygen concentration on geochemical fractionation (operational speciation) of Cu and Pb in the underneath sediments across the oxygen minimum zone (Arabian Sea) in the west coast of India. Both, Cu and Pb were redistributed among the different binding phases of the sediments with changing dissolved oxygen level (from oxic to hypoxic and close to suboxic) in the bottom water. The average lability of Cu-sediment complexes gradually decreased (i.e., stability increased) with the decreasing dissolved oxygen concentrations of the bottom water. Decreasing bottom-water oxygen concentration increased Cu association with sedimentary organic matter. However, Pb association with Fe/Mn-oxyhydroxide phases in the sediments gradually decreased with the decreasing dissolved oxygen concentration of the overlying bottom water (due to dissolution of Fe/Mn oxyhydroxide phase). The lability of Pb-sediment complexes increased with the decreasing bottom-water oxygen concentration. This study suggests that bottom-water oxygen concentration is one of the key factors governing stability and lability of Cu and Pb complexes in the underneath sediment. Sedimentary organic matter and Fe/Mn oxyhydroxide binding phases were the major hosting phases for Cu and Pb respectively in the study area. Increasing lability of Pb-complexes in bottom sediments may lead to positive benthic fluxes of Pb at low oxygen environment. Copyright © 2016 Elsevier B.V. All rights reserved.

  17. Convection in an ideal gas at high Rayleigh numbers.

    PubMed

    Tilgner, A

    2011-08-01

    Numerical simulations of convection in a layer filled with ideal gas are presented. The control parameters are chosen such that there is a significant variation of density of the gas in going from the bottom to the top of the layer. The relations between the Rayleigh, Peclet, and Nusselt numbers depend on the density stratification. It is proposed to use a data reduction which accounts for the variable density by introducing into the scaling laws an effective density. The relevant density is the geometric mean of the maximum and minimum densities in the layer. A good fit to the data is then obtained with power laws with the same exponent as for fluids in the Boussinesq limit. Two relations connect the top and bottom boundary layers: The kinetic energy densities computed from free fall velocities are equal at the top and bottom, and the products of free fall velocities and maximum horizontal velocities are equal for both boundaries.

  18. Fabrication of novel chitosan/PAN/magnetic ZSM-5 zeolite coated sponges for absorption of oil from water surfaces.

    PubMed

    Samadi, Saman; Yazd, Shabnam Sharif; Abdoli, Hossein; Jafari, Pooya; Aliabadi, Majid

    2017-12-01

    In the present study, the chitosan (bottom layer)/polyacrylonitrile (top layer, PAN) nanofibers were coated on the sponge surface. The synthesized magnetic Fe 3 O 4 - ZSM-5 nanozeolites have been loaded into the chitosan/PAN nanofibers to increase the performance of nanofibers toward absorption of lubricating oil, motor oil and pump oil from water surfaces. Scanning electron microscope (SEM), Transmission electron microscope (TEM) and X-ray diffraction (XRD) analysis were used to characterize the synthesized nanozeolites. The morphology and wettability of nanofibers were determined using SEM and water contact angle tests. The influence of Fe 3 O 4 - ZSM-5 nanozeolite content and chitosan/PAN/Fe 3 O 4 - ZSM-5 nanofiber thickness was evaluated on the potential of sponges for oils absorption. The maximum capacity of the chitosan/PAN/Fe 3 O 4 - ZSM-5 nanofibers coated sponges for absorption of motor oil, lubricating oil and pump oil was found to be 99.4, 95.3 and 88.1g/g, in Fe 3 O 4 - ZSM-5 2wt.% and nanofiber thickness of 12μm (chitosan layer of 2μm and PAN layer of 10μm). The reusability of nanofibrous sponges showed that the hydrophobic chitosan/PAN/Fe 3 O 4 - ZSM-5 nanofibers coated sponges can be easily reused in water-oil separation for many cycles. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Solar heating of a stratified ocean in the presence of a static ice cover

    NASA Astrophysics Data System (ADS)

    Perovich, Donald K.; Maykut, Gary A.

    1990-10-01

    Conductivity, temperature, and depth measurements were carried out in an isolated transverse lead in static, shorefast ice in Mould Bay, Prince Patrick Island, Northwest Territories, during a 3-week period at the height of the melt season. Currents beneath the ice appeared to be weak and largely tidal in nature. Initially, the water was vertically uniform and at the salinity-determined freezing point down to a depth of at least 20 m. By the end of the experiment the water column consisted of three distinct layers: a well-mixed, nearly fresh surface meltwater layer; a very stable half-meter-thick halocline centered somewhat below the bottom of the ice; and a thermally stratified layer of constant salinity extending down to at least 25 m. The halocline was characterized by a temperature maximum that was about 2°C warmer than the surrounding water. This temperature maximum in the pycnocline effectively trapped shortwave energy absorbed in the lower layer and prevented it from melting the overlying ice. Theoretical calculations demonstrate that the thermal structure observed beneath the pycnocline was controlled by the input of shortwave radiation and that vertical heat transport was largely the result of diffusive processes. The presence of leads drastically increases the amount of energy stored in the water. In regions where leads are common, it is likely that this energy will significantly accelerate the decay and removal of the ice once it becomes mobile and once the pycnocline is erased.

  20. Functionalization of a long period grating coated with gold nanoparticles for glyphosate detection

    NASA Astrophysics Data System (ADS)

    Heidemann, Bárbara R.; Pereira, Júlia C.; Chiamenti, Ismael; Oliveira, Marcela M.; Muller, Marcia; Fabris, José L.

    2017-04-01

    This work describes a method for producing a nanostructured fiber optic device for sensing of pesticides in water environment. The device consists of a long period grating with a coating of gold nanoparticles functionalized with cysteamine. The LPG shows attenuation bands near the phase matching turning point at the visible spectral range. A bottom-up production route was used to deposit gold nanoparticles on the fiber surface. Sensitivity to the refractive index of the external medium was measured before and after the layer deposition. Cysteamine was used as a ligand for glyphosate present in water at a concentration of 100 μM.

  1. Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution.

    PubMed

    Tian, Bin; Tian, Bining; Smith, Bethany; Scott, M C; Lei, Qin; Hua, Ruinian; Tian, Yue; Liu, Yi

    2018-04-24

    Few-layer black phosphorus (BP) nanosheets were first reported as a 2D material for the application of field-effect transistors in 2014 and have stimulated intense activity among physicists, chemists, and material and biomedical scientists, driving research into novel synthetic techniques to produce BP nanosheets. At present, exfoliation is the main route toward few-layer BP nanosheets via employing bulk BP as raw material. However, this is a complicated and time-consuming process, which is difficult for the large-scale synthesis of BP nanosheets. Moreover, BP degrades rapidly when exfoliated to nanoscale dimensions, resulting in the rapid loss of semiconducting properties. Here, we report the direct wet-chemical synthesis of few-layer BP nanosheets in gram-scale quantities in a bottom-up approach based on common laboratory reagents at low temperature, showing excellent stability due to partial oxidation of surface. Solvent and temperature are two critical factors, controlling not only the formation of BP nanosheets but also the thickness. The as-prepared BP nanosheets can extract hydrogen from pure water (pH = 6.8), exhibiting more than 24-fold higher activity than the well-known C 3 N 4 nanosheets. Our results reporting the ability to prepare few-layer BP nanosheets with a facile, scalable, low-cost approach take us a step closer to real-world applications of phosphorene including next-generation metal-free photocatalysts for photosynthesis. Copyright © 2018 the Author(s). Published by PNAS.

  2. An Analysis Model for Water Cone Subsidence in Bottom Water Drive Reservoirs

    NASA Astrophysics Data System (ADS)

    Wang, Jianjun; Xu, Hui; Wu, Shucheng; Yang, Chao; Kong, lingxiao; Zeng, Baoquan; Xu, Haixia; Qu, Tailai

    2017-12-01

    Water coning in bottom water drive reservoirs, which will result in earlier water breakthrough, rapid increase in water cut and low recovery level, has drawn tremendous attention in petroleum engineering field. As one simple and effective method to inhibit bottom water coning, shut-in coning control is usually preferred in oilfield to control the water cone and furthermore to enhance economic performance. However, most of the water coning researchers just have been done on investigation of the coning behavior as it grows up, the reported studies for water cone subsidence are very scarce. The goal of this work is to present an analytical model for water cone subsidence to analyze the subsidence of water cone when the well shut in. Based on Dupuit critical oil production rate formula, an analytical model is developed to estimate the initial water cone shape at the point of critical drawdown. Then, with the initial water cone shape equation, we propose an analysis model for water cone subsidence in bottom water reservoir reservoirs. Model analysis and several sensitivity studies are conducted. This work presents accurate and fast analytical model to perform the water cone subsidence in bottom water drive reservoirs. To consider the recent interests in development of bottom drive reservoirs, our approach provides a promising technique for better understanding the subsidence of water cone.

  3. Mud Banks along the southwest coast of India are not too muddy for plankton.

    PubMed

    Jyothibabu, R; Balachandran, K K; Jagadeesan, L; Karnan, C; Arunpandi, N; Naqvi, S W A; Pandiyarajan, R S

    2018-02-07

    Considering Alappuzha Mud Bank in the southern Kerala coast as a typical case of biologically productive Mud Banks that form along the southwest coast of India during the Southwest Monsoon (June - September), the present study addresses several pertinent missing links between the physical environment in Mud Banks and their influence on plankton stock. This study showed that very strong coastal upwelling prevails in the entire study domain during the Southwest Monsoon, which manifests itself in the form of significantly cool, hypoxic and nitrate-rich waters surfacing near the coast. The upwelled water persisting throughout the Southwest Monsoon period was found to have fuelled the exceptionally high phytoplankton stock in the entire study area, including the Mud Bank region. Having accepted that Mud Banks are special because of the calm sea surface conditions and relatively high turbidity level in the water column around them, the present study showed that except at points close to the sea bottom, turbidity level in the Alappuzha Mud Bank was below the critical level to inhibit the plankton stock. The suspended sediments that form in the Mud Bank occasionally could be attributed to the disturbance of the bottom fluid muddy layer and their vertical spurts.

  4. Two-phase convection in the high-pressure ice layer of the large icy moons: geodynamical implications

    NASA Astrophysics Data System (ADS)

    Kalousova, K.; Sotin, C.; Tobie, G.; Choblet, G.; Grasset, O.

    2015-12-01

    The H2O layers of large icy satellites such as Ganymede, Callisto, or Titan probably include a liquid water ocean sandwiched between the deep high-pressure ice layer and the outer ice I shell [1]. It has been recently suggested that the high-pressure ice layer could be decoupled from the silicate core by a salty liquid water layer [2]. However, it is not clear whether accumulation of liquids at the bottom of the high-pressure layer is possible due to positive buoyancy of water with respect to high-pressure ice. Numerical simulation of this two-phase (i.e. ice and water) problem is challenging, which explains why very few studies have self-consistently handled the presence and transport of liquids within the solid ice [e.g. 3]. While using a simplified description of water production and transport, it was recently showed in [4] that (i) a significant fraction of the high-pressure layer reaches the melting point and (ii) the melt generation and its extraction to the overlying ocean significantly influence the global thermal evolution and interior structure of the large icy moons.Here, we treat the high-pressure ice layer as a compressible mixture of solid ice and liquid water [5]. Several aspects are investigated: (i) the effect of the water formation on the vigor of solid-state convection and its influence on the amount of heat that is transferred from the silicate mantle to the ocean; (ii) the fate of liquids within the upper thermal boundary layer - whether they freeze or reach the ocean; and (iii) the effect of salts and volatile compounds (potentially released from the rocky core) on the melting/freezing processes. Investigation of these aspects will allow us to address the thermo-chemical evolution of the internal ocean which is crucial to evaluate the astrobiological potential of large icy moons. This work has been performed at the Jet Propulsion Laboratory, California Institute of Technology, under contract to NASA. [1] Hussmann et al. (2007), Treatise of Geophysics, 10.15, 509-539. [2] Vance et al. (2014), Planet. Space Sci., 96, 62-70. [3] Kalousova et al. (2014), J. Geophys. Res. Planets, 119(3), 532-549. [4] Tobie et al. (2014), AGU, P43C-3999. [5] Soucek et al. (2014), Geophys. Astro. Fluid, 108(6), 639-666.

  5. The Southern Ocean in the Coupled Model Intercomparison Project phase 5

    PubMed Central

    Meijers, A. J. S.

    2014-01-01

    The Southern Ocean is an important part of the global climate system, but its complex coupled nature makes both its present state and its response to projected future climate forcing difficult to model. Clear trends in wind, sea-ice extent and ocean properties emerged from multi-model intercomparison in the Coupled Model Intercomparison Project phase 3 (CMIP3). Here, we review recent analyses of the historical and projected wind, sea ice, circulation and bulk properties of the Southern Ocean in the updated Coupled Model Intercomparison Project phase 5 (CMIP5) ensemble. Improvements to the models include higher resolutions, more complex and better-tuned parametrizations of ocean mixing, and improved biogeochemical cycles and atmospheric chemistry. CMIP5 largely reproduces the findings of CMIP3, but with smaller inter-model spreads and biases. By the end of the twenty-first century, mid-latitude wind stresses increase and shift polewards. All water masses warm, and intermediate waters freshen, while bottom waters increase in salinity. Surface mixed layers shallow, warm and freshen, whereas sea ice decreases. The upper overturning circulation intensifies, whereas bottom water formation is reduced. Significant disagreement exists between models for the response of the Antarctic Circumpolar Current strength, for reasons that are as yet unclear. PMID:24891395

  6. Properties of the water column and bottom derived from Airborne Visible Infrared Imaging Spectrometer (AVIRIS) data

    NASA Astrophysics Data System (ADS)

    Lee, Zhongping; Carder, Kendall L.; Chen, Robert F.; Peacock, Thomas G.

    2001-06-01

    Using Airborne Visible Infrared Imaging Spectrometer (AVIRIS) data as an example, we show in this study that the properties of the water column and bottom of a large, shallow area can be adequately retrieved using a model-driven optimization technique. The simultaneously derived properties include bottom depth, bottom albedo, and water absorption and backscattering coefficients, which in turn could be used to derive concentrations of chlorophyll, dissolved organic matter, and suspended sediments in the water column. The derived bottom depths were compared with a bathymetry chart and a boat survey and were found to agree very well. Also, the derived bottom albedo image shows clear spatial patterns, with end-members consistent with sand and seagrass. The image of absorption and backscattering coefficients indicates that the water is quite horizontally mixed. Without bottom corrections, chlorophyll a retrievals were ˜50 mg m-3, while the retrievals after bottom corrections were tenfold less, approximating real values. These results suggest that the model and approach used work very well for the retrieval of subsurface properties of shallow-water environments even for rather turbid environments like Tampa Bay, Florida.

  7. Canary Current and North Equatorial Current from an inverse box model

    NASA Astrophysics Data System (ADS)

    HernáNdez-Guerra, Alonso; Fraile-Nuez, Eugenio; López-Laatzen, Federico; MartíNez, Antonio; Parrilla, Gregorio; VéLez-Belchí, Pedro

    2005-12-01

    The large-scale Canary Basin circulation is estimated from a box inverse model applied to hydrographic data from a quasi-synoptic survey carried out in September 2003. The cruise consisted of 76 full depth CTD and oxygen stations. Circulation is required to nearly conserve mass and anomalies of salinity and heat within layers bounded by neutral surfaces. It permits advective and diffusive exchange between layers and an adjustment of the Ekman transport and the freshwater flux divergences. The Canary Current at the thermocline layer transports a net mass of 4.7 ± 0.8 Sv southward north of the Canary Islands from the African coast to 19°W. It is divided into a northward circulation at a rate of 1.1 ± 0.5 Sv between the African coast and Lanzarote Island and a southward transport of 5.8 ± 0.6 Sv. It transports North Atlantic Central Water and organic matters advected offshore by the filaments protruding from the upwelling system off northwest Africa. At 24°N, the Canary Current feeds the North Equatorial Current that transports a mixture of North and South Atlantic Central Waters westward. In the intermediate layer a southwestward flow of 1.2 ± 1.1 Sv transports Mediterranean Water to the Subtropical Gyre, though the highest salt flux is transported by a meddy. Oxygen distribution and mass transport suggest a northeastward deep flow of a water mass colder than 2.2°C consisting of diluted Antarctic Bottom Water. The heat and freshwater divergences and the average dianeutral velocity and diffusion between the sections and the African coast are negligible.

  8. A new method for estimating the turbulent heat flux at the bottom of the daily mixed layer

    NASA Technical Reports Server (NTRS)

    Imawaki, Shiro; Niiler, Pearn P.; Gautier, Catherine H.; Knox, Robert A.; Halpern, David

    1988-01-01

    Temperature data in the mixed layer and net solar irradiance data at the sea surface are used to estimate the vertical turbulent heat flux at the bottom of the daily mixed layer. The method is applied to data obtained in the eastern tropical Pacific, where the daily cycle in the temperature field is confined to the upper 10-25 m. Equatorial turbulence measurements indicate that the turbulent heat flux is much greater during nighttime than daytime.

  9. Genomic analysis reveals a tight link between transcription factor dynamics and regulatory network architecture.

    PubMed

    Jothi, Raja; Balaji, S; Wuster, Arthur; Grochow, Joshua A; Gsponer, Jörg; Przytycka, Teresa M; Aravind, L; Babu, M Madan

    2009-01-01

    Although several studies have provided important insights into the general principles of biological networks, the link between network organization and the genome-scale dynamics of the underlying entities (genes, mRNAs, and proteins) and its role in systems behavior remain unclear. Here we show that transcription factor (TF) dynamics and regulatory network organization are tightly linked. By classifying TFs in the yeast regulatory network into three hierarchical layers (top, core, and bottom) and integrating diverse genome-scale datasets, we find that the TFs have static and dynamic properties that are similar within a layer and different across layers. At the protein level, the top-layer TFs are relatively abundant, long-lived, and noisy compared with the core- and bottom-layer TFs. Although variability in expression of top-layer TFs might confer a selective advantage, as this permits at least some members in a clonal cell population to initiate a response to changing conditions, tight regulation of the core- and bottom-layer TFs may minimize noise propagation and ensure fidelity in regulation. We propose that the interplay between network organization and TF dynamics could permit differential utilization of the same underlying network by distinct members of a clonal cell population.

  10. Crystal accumulation in the Hanford Waste Treatment Plant high level waste melter. Preliminary settling and resuspension testing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fox, K. M.; Fowley, M. D.; Miller, D. H.

    2016-05-01

    The full-scale, room-temperature Hanford Tank Waste Treatment and Immobilization Plant (WTP) High-Level Waste (HLW) melter riser test system was successfully operated with silicone oil and magnetite particles at a loading of 0.1 vol %. Design and construction of the system and instrumentation, and the selection and preparation of simulant materials, are briefly reviewed. Three experiments were completed. A prototypic pour rate was maintained, based on the volumetric flow rate. Settling and accumulation of magnetite particles were observed at the bottom of the riser and along the bottom of the throat after each experiment. The height of the accumulated layer atmore » the bottom of the riser, after the first pouring experiment, approximated the expected level given the solids loading of 0.1 vol %. More detailed observations of particle resuspension and settling were made during and after the third pouring experiment. The accumulated layer of particles at the bottom of the riser appeared to be unaffected after a pouring cycle of approximately 15 minutes at the prototypic flow rate. The accumulated layer of particles along the bottom of the throat was somewhat reduced after the same pouring cycle. Review of the time-lapse recording showed that some of the settling particles flow from the riser into the throat. This may result in a thicker than expected settled layer in the throat.« less

  11. Thin film encapsulation for flexible AM-OLED: a review

    NASA Astrophysics Data System (ADS)

    Park, Jin-Seong; Chae, Heeyeop; Chung, Ho Kyoon; In Lee, Sang

    2011-03-01

    Flexible organic light emitting diode (OLED) will be the ultimate display technology to customers and industries in the near future but the challenges are still being unveiled one by one. Thin-film encapsulation (TFE) technology is the most demanding requirement to prevent water and oxygen permeation into flexible OLED devices. As a polymer substrate does not offer the same barrier performance as glass, the TFE should be developed on both the bottom and top side of the device layers for sufficient lifetimes. This work provides a review of promising thin-film barrier technologies as well as the basic gas diffusion background. Topics include the significance of the device structure, permeation rate measurement, proposed permeation mechanism, and thin-film deposition technologies (Vitex system and atomic layer deposition (ALD)/molecular layer deposition (MLD)) for effective barrier films.

  12. Leaching of different elements from subbase layers of alternative aggregates in pavement constructions.

    PubMed

    Flyhammar, P; Bendz, D

    2006-09-01

    The objective of this study was to analyze the accumulated effects of leaching in two test roads were municipal solid waste incineration (MSWI) bottom ash and aggregate from a railway embankment, respectively, were used as subbase aggregates. Solid samples from the subbase and the subgrade were collected in trenches, which were excavated perpendicular to the road extension. The samples were analyzed with respect to pH, water content, electrical conductivity and extractable fractions of macro and trace constituents. To conclude, spatial distribution patterns of different constituents in subbase and subgrade layers confirms the existence of two major transport processes in a road with permeable shoulders: diffusion underneath surface asphalt layers driven by a concentration gradient directed horizontally towards the shoulder of the road where the dissolved elements are carried away by advection.

  13. Repair, Evaluation, Maintenance, and Rehabilitation Research Program. Underwater Repair of Concrete Damaged by Abrasion-Erosion

    DTIC Science & Technology

    1991-12-01

    and compatible placement tech- niques that can ensure successful and cost effective repairs of scour holes of different sizes and depths under water...bridge foundation in Japan. The valve was attached to the bottom of a pump line and was moved to cast concrete in successive layers at several locations...surfaces, reinforc- ing steel, and dowel bars in order to ensure successful and durable repairs. Thi. is ( specizlly important since it is not practical to

  14. Synthesis of bimetallic nanostructures by nanosecond laser ablation of multicomponent thin films in water

    NASA Astrophysics Data System (ADS)

    Nikov, R. G.; Nedyalkov, N. N.; Atanasov, P. A.; Karashanova, D. B.

    2018-03-01

    The paper presents results on nanosecond laser ablation of thin films immersed in a liquid. The thin films were prepared by consecutive deposition of layers of different metals by thermal evaporation (first layer) and classical on-axis pulsed laser deposition (second layer); Ni/Au, Ag/Au and Ni/Ag thin films were thus deposited on glass substrates. The as-prepared films were then placed at the bottom of a glass vessel filled with double distilled water and irradiated by nanosecond laser pulses delivered by a Nd:YAG laser system at λ = 355 nm. This resulted in the formation of colloids of the thin films’ material. We also compared the processes of ablation of a bulk target and a thin film in the liquid by irradiating a Au target and a Au thin film by the same laser wavelength and fluence (λ = 355 nm, F = 5 J/cm2). The optical properties of the colloids were evaluated by optical transmittance measurements in the UV– VIS spectral range. Transmission electron microscopy was employed to estimate the particles’ size distribution.

  15. Geophysical investigation to reveal the groundwater condition at new Borg El-Arab industrial city, Egypt

    NASA Astrophysics Data System (ADS)

    Basheer, Alhussein A.; Mansour, Khamis Q.; Abdalla, Mohammed A.

    2014-12-01

    New Borg El-Arab City, 60 km to the southwest of Alexandria City, is one of new industrial cities planned by the Egyptian Government through its program to transfer the population from the condensed Nile Delta to other places in Egypt. Because such a city includes airport, huge buildings, factories, and worker settlements, a careful geophysical study is planned to reveal the groundwater condition. This will help in defining the places of wells that are supposed to be drilled. Therefore more industrial and agricultural activities will be flourished. The present study embraces Vertical Electrical Soundings (VES'es) and Time Domain Electromagnetic sounding (TEM) to investigate the study area. The study aims to delineate the main subsurface conditions from the viewpoint of groundwater location, depth and water quality. Analysis and interpretation of the obtained results reveal that the subsurface consists of five geoelectrical layers with a gentle general slope toward the Mediterranean Sea. The third and the fourth layers in the succession are suggested to be the two water bearing formations of which the third layer is saturated with fresh water overlying saline water at the bottom of the fourth one. It is worth mentioning that the fresh water depth varies between 50 and 354 m under the ground surface. The thickness of the fresh water aquifer varies from 9.5 to 66 m; and the saline water depth varies between 116 and 384 m below the ground surface, the thickness of saline water aquifer differs from 34 to 90.5 m.

  16. Fruit position within the canopy affects kernel lipid composition of hazelnuts.

    PubMed

    Pannico, Antonio; Cirillo, Chiara; Giaccone, Matteo; Scognamiglio, Pasquale; Romano, Raffaele; Caporaso, Nicola; Sacchi, Raffaele; Basile, Boris

    2017-11-01

    The aim of this research was to study the variability in kernel composition within the canopy of hazelnut trees. Kernel fresh and dry weight increased linearly with fruit height above the ground. Fat content decreased, while protein and ash content increased, from the bottom to the top layers of the canopy. The level of unsaturation of fatty acids decreased from the bottom to the top of the canopy. Thus, the kernels located in the bottom layers of the canopy appear to be more interesting from a nutritional point of view, but their lipids may be more exposed to oxidation. The content of different phytosterols increased progressively from bottom to top canopy layers. Most of these effects correlated with the pattern in light distribution inside the canopy. The results of this study indicate that fruit position within the canopy is an important factor in determining hazelnut kernel growth and composition. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  17. Modelling of underwater light fields in turbid and eutrophic waters: application and validation with experimental data

    NASA Astrophysics Data System (ADS)

    Sundarabalan, B.; Shanmugam, P.

    2014-09-01

    A reliable radiative transfer model is an essential and indispensable tool for understanding of the radiative transfer processes in homogenous and layered waters, analyzing measurements made by radiance sensors and developing remote sensing algorithms to derive meaningful physical quantities and biogeochemical variables in turbid and productive coastal waters. Existing radiative transfer models have been designed to be applicable to either homogenous waters or inhomogeneous waters. To overcome such constraints associated with these models, this study presents a radiative transfer model that treats a homogenous layer as a diffuse part and an inhomogeneous layer as a direct part in the water column and combines these two parts appropriately in order to generate more reliable underwater light field data such as upwelling radiance (Lu), downwelling irradiance (Ed) and upwelling irradiance (Eu). The diffuse model assumes the inherent optical properties (IOPs) to be vertically continuous and the light fields to exponentially decrease with the depth, whereas the direct part considers the water column to be vertically inhomogeneous (layer-by-layer phenomena) with the vertically varying phase function. The surface and bottom boundary conditions, source function due to chlorophyll and solar incident geometry are also included in the present RT model. The performance of this model is assessed in a variety of waters (clear, turbid and eutrophic) using the measured radiometric data. The present model shows an advantage in terms of producing accurate Lu, Ed and Eu profiles (in spatial domain) in different waters determined by both homogenous and inhomogeneous conditions. The feasibility of predicting these underwater light fields based on the remotely estimated IOP data is also examined using the present RT model. For this application, vertical profiles of the water constituents and IOPs are estimated by empirical models based on our in-situ data. The present RT model generates Lu, Ed and Eu spectra closely consistent with the measured data. These results lead to a conclusion that the present RT model is a viable alternative to existing RT models and has an important implication for remote sensing of optically complex waters.

  18. Modelling of underwater light fields in turbid and eutrophic waters: application and validation with experimental data

    NASA Astrophysics Data System (ADS)

    Sundarabalan, B.; Shanmugam, P.

    2015-01-01

    A reliable radiative transfer (RT) model is an essential and indispensable tool for understanding the radiative transfer processes in homogenous and layered waters, analyzing measurements made by radiance sensors and developing remote-sensing algorithms to derive meaningful physical quantities and biogeochemical variables in turbid and productive coastal waters. Existing radiative transfer models have been designed to be applicable to either homogenous waters or inhomogeneous waters. To overcome such constraints associated with these models, this study presents a radiative transfer model that treats a homogenous layer as a diffuse part and an inhomogeneous layer as a direct part in the water column and combines these two parts appropriately in order to generate more reliable underwater light-field data such as upwelling radiance (Lu), downwelling irradiance (Ed) and upwelling irradiance (Eu). The diffuse model assumes the inherent optical properties (IOPs) to be vertically continuous and the light fields to exponentially decrease with depth, whereas the direct part considers the water column to be vertically inhomogeneous (layer-by-layer phenomena) with the vertically varying phase function. The surface and bottom boundary conditions, source function due to chlorophyll and solar incident geometry are also included in the present RT model. The performance of this model is assessed in a variety of waters (clear, turbid and eutrophic) using the measured radiometric data. The present model shows an advantage in terms of producing accurate Lu, Ed and Eu profiles (in spatial domain) in different waters determined by both homogenous and inhomogeneous conditions. The feasibility of predicting these underwater light fields based on the remotely estimated IOP data is also examined using the present RT model. For this application, vertical profiles of the water constituents and IOPs are estimated by empirical models based on our in situ data. The present RT model generates Lu, Ed and Eu spectra closely consistent with the measured data. These results lead to a conclusion that the present RT model is a viable alternative to existing RT models and has an important implication for remote sensing of optically complex waters.

  19. Monthly Variation of Taiwan Strait Through-flow Transports and Associated Water Masses

    NASA Astrophysics Data System (ADS)

    Jan, S.; Sheu, D.; Kuo, H.

    2005-05-01

    Through-flow transports and associated water masses are analyzed using current data measured by bottom-mounted and ship-board ADCP (1999-2001) across the central Taiwan Strait and strait-wide hydrographic data acquired from 79 CTD survey cruises (1986-2003). The East Asian monsoon, from southwest in July to August and northeast in October to March, controls the transport fluctuation which peaks in August (2.34 Sv northward), is hampered by the northeast monsoon after September and diminishes to the minimum (0.26 Sv southward) in December. The standard deviation of the calculated transport ranges from 0.56 to 1.05 Sv during northeast monsoon months and is relatively small in other months. A cluster analysis together with conventional T-S diagrams identifies the saline and warm Kuroshio Branch Water (KBW), the less saline South China Sea Surface Water (SCSSW), the brackish and cold China Coastal Water (CCW), the saline Subsurface Water (SW) (depth > 100 m) and the Diluted Coastal Water (DCW). The majority of the northward transport in summer carries the SCSSW to the East China Sea. Meanwhile, the DCW appears off the northwest bank of the strait and the SW resides in the bottom layer of a deep trench in the southeastern strait. The onset of the northeast monsoon in September drives the CCW from the Yangtze river mouth to the northern strait. In the southern strait, the northward-moving KBW replaces the SCSSW and meets the southward-intruding CCW in the middle strait during November to April.

  20. Measurement and simulation of top- and bottom-illuminated solar-blind AlGaN metal-semiconductor-metal photodetectors with high external quantum efficiencies

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brendel, Moritz, E-mail: moritz.brendel@fbh-berlin.de; Helbling, Markus; Knigge, Andrea

    2015-12-28

    A comprehensive study on top- and bottom-illuminated Al{sub 0.5}Ga{sub 0.5}N/AlN metal-semiconductor-metal (MSM) photodetectors having different AlGaN absorber layer thickness is presented. The measured external quantum efficiency (EQE) shows pronounced threshold and saturation behavior as a function of applied bias voltage up to 50 V reaching about 50% for 0.1 μm and 67% for 0.5 μm thick absorber layers under bottom illumination. All experimental findings are in very good accordance with two-dimensional drift-diffusion modeling results. By taking into account macroscopic polarization effects in the hexagonal metal-polar +c-plane AlGaN/AlN heterostructures, new insights into the general device functionality of AlGaN-based MSM photodetectors are obtained. The observedmore » threshold/saturation behavior is caused by a bias-dependent extraction of photoexcited holes from the Al{sub 0.5}Ga{sub 0.5}N/AlN interface. While present under bottom illumination for any AlGaN layer thickness, under top illumination this mechanism influences the EQE-bias characteristics only for thin layers.« less

  1. Holocene-Pleistocene Environmental Changes in Eastern Mediterranean Sediments: Foraminiferal and Geochemical Approach

    NASA Astrophysics Data System (ADS)

    Sinoussy Mohamed, K. S., Jr.; Ibrahim, M. I. A.; Moustafa, A. R.; Abd Elkarim, M. R.; Shreadah, M. M. A.

    2014-12-01

    The present study is based on gravity core sediment samples from the Eastern Mediterranean Sea located in 32° 20' 55" N and 31° 47' 79" E, in front of the Nile Delta Fan taken during METEOR cruise M70b (October 2006). The core is gravity one (St#822), 4.5 m long, and in 1089 m water depth. The study of benthic and planktic foraminifera is used to determine the microhabitat of the bottom sediments during warm and cold periods. Sapropels S1, S3 and S4 are encountered in the studied gravity core sample from the eastern Mediterranean. The sapropel layers S1, S3 and S4 were deposited during interglacial periods, characterized by a low foraminiferal numbers, reflecting eutrophic conditions. Glacial periods are characterized by high foraminiferal numbers due probably to an enhanced glacial productivity. Sapropel layers are distinguished by increase of Fe, TOC% (TOC%≥ 1.2%) and decrease of Ca concentrations as a result of the Blue Nile suspended particulate matter discharge during summer monsoon. Clay content increases at the sapropel depths that indicate an increase in the terrigenous input derived from the weathering of Ethiopian basalts. Temporal distribution of planktic and benthic foraminifera in the Nile deep sea fan sediments besides geochemical charcterization, palaeohydrological fluctuations, palaeoenvironment and microhabitat of foraminifera were reconstructed for the last 100000 years including glacial and interglacial periods. Formation of the Sapropel layers are synchronized with the decreasing of δ18O which means that the Mediterranean Sea received high amount of fresh water from the Nile river discharge. Clay content, TOC%, Ca-Fe cycles, oxygen and carbon isotopes and planktic foraminifera document the pluvial and arid periods throughout the 100000 years and define clearly the contributions of terrigenous and TOC% in the sapropel layers. Infauna/epifauna ratio and benthic foraminifera assemblages were used to reconstruct the microhabitat of the sea bottom during sapropel and cold periods.

  2. Self-oscillations in large storages of highly mineralized brines

    NASA Astrophysics Data System (ADS)

    Lyubimova, Tatyana; Lepikhin, Anatoly; Tsiberkin, Kirill; Parshakova, Yanina

    2014-05-01

    One of the stages of the production process at large enrichment plants is settling of aqueous solutions in large technological storages. The present work is devoted to the modeling of hydrodynamic regimes of large storage of highly mineralized brines. The density of brines in these objects depends not only on the content of dissolved macrocomponents, but also on the concentration of fine particulate matter. This leads to the need to consider the dynamics of the suspended sediment under significant density stratification, which greatly complicates the problem. Because of that it is important to develop hydrodynamical models of these objects. A peculiarity of these systems is the possibility of self-oscillatory regimes the mechanism of which is as follows. In warm sunny days, with high solar insolation, the heating of the sediments and bottom water takes place. The bottom water warming and the decrease of its density give rise to flow. The slurry particles composing the sediments are involved in the flow. The heated particles entrained by the flow transfer the heat to the surrounding liquid and increase the absorption of the solar radiation in the volume, which leads to equalization of temperature and convective flow damping. After the particle settling on the bottom the process is repeated. We study the stability of equilibrium of the horizontal liquid layer containing heavy insoluble particles in the presence of evaporation from the free surface and solar radiation absorption by insoluble particles. The time-dependent solution of heat transfer problem is obtained and used for estimate of time of instability onset. It is found that for the layer of saturated brines of potassium chloride of the thickness about 10 m the time for instability onset is about one hour. By using analytical estimates based on the empirical model of turbulence by Prandtl we confirmed the time for the onset of instability and obtained the estimates for the period of self-oscillations. Numerical simulation of the dynamics of suspended sediment in the storage is performed within the framework of two-dimensional unsteady approach taking into account the temperature jumps due to the water evaporation from the free surface and the radiation heating of the sediments. The dynamics of sediment in a rectangular cavity of the length 500 m and depth 10 m is considered. Initially, the water is assumed to be motionless and nonuniformly heated. The calculations show that in the first stage of the process the flows arise near the boundaries of the heated areas. Next, the large-scale vortices with the characteristic size equal to the depth of the storage are formed. The sediment located at the bottom sets into motion and only some portion of sediment located near the bottom remains motionless. Throughout several hours the mass fraction of the suspended particles in water increases, then the flow decays and the sedimentation of particles is observed. This work was supported by RFBR and Perm Region Government (grant 13-01-96040) and by President of Russian Federation (grant 4022.2014.1 for the support of Leading Scientific Schools).

  3. The long-term variability of chemical structure of deep-water basins of the Caspian Sea

    NASA Astrophysics Data System (ADS)

    Serebrennikova, Ekaterina

    2017-04-01

    The Caspian Sea is a unique water object: the biggest lake on Earth, so large that it actually functions as a sea, but totally isolated from the World Ocean and extremely responsive to the climatic changes. The Caspian Sea is characterized by periodical large-scale sea level oscillations - it is one of the manifestations of multidecadal climatic fluctuations on East European Plain. In order to monitor the environmental conditions staff of the Laboratory of Hydrochemistry of Russian Federal Research Institution of Fisheries and Oceanography (FSBSI "VNIRO") in collaboration with other russian scientific institutions conducts annual research cruises to the Caspian Sea. For the last 40 years natural and anthropogenic climatic changes caused a stable stratification of the water column in both Caspian basins and the nourishment depletion of the photic layer, created and annually aggravated by the biological pump. The data, collected in annual expeditions since 1995, shows the progressing hypoxia below the depth of 400 meters and the formation of hydrogen sulfidic contamination in bottom waters. The cumulative effect of natural variability and extremely intensive anthropogenic stress creates a very depressing environment for all the aquatics, from phytoplankton to unique commercial species. In the last 20 years the level of the Caspian Sea has lowered for 2,5 meters. This is a result of changes in the water balance of the Caspian Sea, that includes the decrease of freshwater income. In long-term perspective this leads to an increase in surface water density and in winter convection depth. However up until 2016 the stratification of the water column stayed stable, so the deep waters were isolated form the atmosphere. Annual monitoring since 1995 has shown gradual oxygen depletion and intensive accumulation of biogenic elements. In 2016 concentrations of phosphate and nitrate were the highest ever registered for the Caspian Sea. The analysis of the research conducted in last 4 years shows the increasing possibility of major change in the hydrological and chemical structure of the waters in both Caspian deep-water basins. In June 2016 oxygenated waters were registered at the bottom of the Middle Caspian Basin for the first time in the last 20 years. This allows us to conclude, that in winter 2015-2016 the environmental conditions created surface water, dense enough to reach the bottom of the basin cascading the continental slope. Based on data, collected over the last century, the sea level, critical for the major winter convection to occur, was calculated, and in 2015 the level of the Caspian Sea has reached this mark. If the sea level lowering continues we can expect an intensive convective deep-water ventilation caused by winter cascading. This can lead to fundamental shift in nourishment enriching mechanisms of the photic layer that can boost the primary production and have positive repercussions throughout all the food chains in Caspian ecosystem.

  4. Influence of nano-oxide layers on IrMn pinned bottom spin-valves at different positions

    NASA Astrophysics Data System (ADS)

    Qiu, J. J.; Li, K. B.; Luo, P.; Zheng, Y. K.; Wu, Y. H.

    2004-05-01

    The influence of nano-oxide layer (NOL) inserted at different positions on interlayer coupling (Hin), coercivity of free layer (Hcf), exchange bias (Hex) and MR ratio of IrMn pinned bottom type spin-valves (SV) were studied. Weak antiferromagnetic interlayer coupling was observed in NOL-added SV. The NOL inside pinned layer and after free layer can enhance the MR ratio remarkably. MR of SV with a structure Ta3/NiFe2/IrMn6/CoFe1/NOL/CoFe2.3/Cu2.2/CoFe2.3/AlO reached 18.2%. This is one of the best values ever reported for all-metal single spin-valves.

  5. A thickness-weighted average perspective of force balance in an idealized circumpolar current

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ringler, Todd Darwin; Saenz, Juan Antonio; Wolfram, Jr., Phillip Justin

    The exact, three-dimensional thickness-weighted averaged (TWA) Boussinesq equations are used to diagnose eddy-mean flow interaction in an idealized circumpolar current (ICC). The force exerted by mesoscale eddies on the TWA velocity is expressed as the divergence of the Eliassen-Palm flux tensor. Consistent with previous findings, the analysis indicates that the dynamically relevant definition of the ocean surface layer is comprised of the set of buoyancy coordinates that ever reside at the ocean surface at a given horizontal position. The surface layer is found to be a physically distinct object with a diabatic- and force-balance that is largely isolated from themore » underlying adiabatic region in the interior. Within the ICC surface layer, the TWA meridional velocity is southward/northward in the top/bottom half, and has a value near zero at the bottom. In the top half of the surface layer, the zonal forces due to wind stress and meridional advection of potential vorticity act to accelerate the TWA zonal velocity; equilibrium is obtained by eddies decelerating the zonal flow via a downward flux of eastward momentum that increases with depth. In the bottom half of the surface layer, the accelerating force of the wind stress is balanced by the eddy force and meridional advection of potential vorticity. The bottom of the surface layer coincides with the location where the zonal eddy force, meridional advection of potential vorticity and zonal wind stress force are all zero. The net meridional transport, S f, within the surface layer is a small residual of its southward and northward TWA meridional flows. Furthermore, the mean meridional gradient of surface-layer buoyancy is advected by S f to balance the surface buoyancy fluxs.« less

  6. A thickness-weighted average perspective of force balance in an idealized circumpolar current

    DOE PAGES

    Ringler, Todd Darwin; Saenz, Juan Antonio; Wolfram, Jr., Phillip Justin; ...

    2016-11-22

    The exact, three-dimensional thickness-weighted averaged (TWA) Boussinesq equations are used to diagnose eddy-mean flow interaction in an idealized circumpolar current (ICC). The force exerted by mesoscale eddies on the TWA velocity is expressed as the divergence of the Eliassen-Palm flux tensor. Consistent with previous findings, the analysis indicates that the dynamically relevant definition of the ocean surface layer is comprised of the set of buoyancy coordinates that ever reside at the ocean surface at a given horizontal position. The surface layer is found to be a physically distinct object with a diabatic- and force-balance that is largely isolated from themore » underlying adiabatic region in the interior. Within the ICC surface layer, the TWA meridional velocity is southward/northward in the top/bottom half, and has a value near zero at the bottom. In the top half of the surface layer, the zonal forces due to wind stress and meridional advection of potential vorticity act to accelerate the TWA zonal velocity; equilibrium is obtained by eddies decelerating the zonal flow via a downward flux of eastward momentum that increases with depth. In the bottom half of the surface layer, the accelerating force of the wind stress is balanced by the eddy force and meridional advection of potential vorticity. The bottom of the surface layer coincides with the location where the zonal eddy force, meridional advection of potential vorticity and zonal wind stress force are all zero. The net meridional transport, S f, within the surface layer is a small residual of its southward and northward TWA meridional flows. Furthermore, the mean meridional gradient of surface-layer buoyancy is advected by S f to balance the surface buoyancy fluxs.« less

  7. Properties of the Water Column and Bottom Derived from AVIRIS Data

    NASA Technical Reports Server (NTRS)

    Lee, Zhong-Ping; Carder, Kendall L.; Chen, F. Robert; Peacock, Thomas G.

    2001-01-01

    Using AVIRIS data as an example, we show in this study that the optical properties of the water column and bottom of a large, shallow area can be adequately retrieved using a model-driven optimization technique. The simultaneously derived properties include bottom depth, bottom albedo, and water absorption and backscattering coefficients, which in turn could be used to derive concentrations of chlorophyll, dissolved organic matter, and suspended sediments. The derived bottom depths were compared with a bathymetry chart and a boat survey and were found to agree very well. Also, the derived bottom-albedo image shows clear spatial patterns, with end members consistent with sand and seagrass. The image of absorption and backscattering coefficients indicates that the water is quite horizontally mixed. These results suggest that the model and approach used work very well for the retrieval of sub-surface properties of shallow-water environments even for rather turbid environments like Tampa Bay, Florida.

  8. A note on the effect of wind waves on vertical mixing in Franks Tract, Sacramento-San Joaquin Delta, California, USA

    USGS Publications Warehouse

    Thompson, Janet K.; Jones, Nicole L.; Stephen G. Monismith,

    2008-01-01

    A one-dimensional numerical model that simulates the effects of whitecapping waves was used to investigate the importance of whitecapping waves to vertical mixing at a 3-meter-deep site in Franks Tract in the Sacramento-San Joaquin Delta over an 11-day period. Locally-generated waves of mean period approximately 2 s were generated under strong wind conditions; significant wave heights ranged from 0 to 0.3 m. A surface turbulent kinetic energy flux was used to model whitecapping waves during periods when wind speeds > 5 m s-1 (62% of observations). The surface was modeled as a wind stress log-layer for the remaining 38% of the observations. The model results demonstrated that under moderate wind conditions (5–8 m s-1 at 10 m above water level), and hence moderate wave heights, whitecapping waves provided the dominant source of turbulent kinetic energy to only the top 10% of the water column. Under stronger wind (> 8 m s-1), and hence larger wave conditions, whitecapping waves provided the dominant source of turbulent kinetic energy over a larger portion of the water column; however, this region extended to the bottom half of the water column for only 7% of the observation period. The model results indicated that phytoplankton concentrations close to the bed were unlikely to be affected by the whitecapping of waves, and that the formation of concentration boundary layers due to benthic grazing was unlikely to be disrupted by whitecapping waves. Furthermore, vertical mixing of suspended sediment was unlikely to be affected by whitecapping waves under the conditions experienced during the 11-day experiment. Instead, the bed stress provided by tidal currents was the dominant source of turbulent kinetic energy over the bottom half of the water column for the majority of the 11-day period.

  9. New insights on the propagation of the Near Inertial Waves (NIW) governing the bottom dynamic of the Western Ionian Sea (Eastern Mediterranean Sea).

    NASA Astrophysics Data System (ADS)

    Lo Bue, N.; Artale, V.; Marullo, S.; Marinaro, G.; Embriaco, D.; Favali, P.; Beranzoli, L.

    2017-12-01

    The past general idea that the ocean-deep circulation is in quasi-stationary motion, has conditioned the observations of deep layers for a long time, excluding them from the majority of the surveys around the ocean world and influencing studies on the deep ocean processes. After the pioneering work of Munk (1966) highlighting the importance of bottom mixing processes, an underestimation of these issue has continued to persist for decades, due also to the difficulty to make reliable observations in the abyssal layers. The real awareness about the unsteady state of the abyssal layers has only risen recently and encourages us to wonder how the deep mechanisms can induce an internal instability and, consequently, affect the ocean circulation. The NIWs are characterized by a frequency near the inertial frequency f and can be generated by a variety of mechanisms, including wind, nonlinear interactions wave-shear flow and wave-topography, and geostrophic adjustments. NIWs represent one of the main high-frequency variabilities in the ocean, and they contain around half the kinetic energy observed in the oceans (Simmons et al. 2012) appearing as a prominent peak rising well above the Garrett & Munk (1975) continuum internal wave spectrum. As such, they upset the mixing processes in the upper ocean and they can interact strongly with mesoscale and sub-mesoscale motions. Likewise, NIWs likely affect the mixing of the deep ocean in ways that are just beginning to be understood. The analysis carried out on yearly time series collected by the bottom observatory SN1, the Western Ionian node of EMSO (European Multidisciplinary Seafloor and water column Observatory) Research Infrastructure, provides new important understanding on the role of the NIWs in the abyssal ocean. Also, this analysis is very useful to shed light on the possible mechanism that can trigger deep processes such as the abyssal vortex chains found by Rubino et al. (2012) in the Ionian abyssal plain of the Eastern Mediterranean (EM) basin. Finally, spectral analysis, including the Singular Spectrum Analysis (SSA) and Wavelet, allow us to explain how the NIWs can contributes to activate and increase the mixing in the bottom layers with significant impact on overall abyssal and deep circulation at local and regional scale (Mediterranean Sea).

  10. Change in Dense Shelf Water and Adélie Land Bottom Water Precipitated by Iceberg Calving

    NASA Astrophysics Data System (ADS)

    Snow, K.; Rintoul, S. R.; Sloyan, B. M.; Hogg, A. McC.

    2018-03-01

    Antarctic Bottom Water supplies the deep limb of the global overturning circulation and ventilates the abyssal ocean. Antarctic Bottom Water has warmed, freshened, and contracted in recent decades, but the causes remain poorly understood. We use unique multiyear observations from the continental shelf and deep ocean near the Mertz Polynya to examine the sensitivity of this bottom water formation region to changes on the continental shelf, including the calving of a large iceberg. Postcalving, the seasonal cycle of Dense Shelf Water (DSW) density almost halved in amplitude and the volume of DSW available for export reduced. In the deep ocean, the density and volume of Adélie Land Bottom Water decreased sharply after calving, while oxygen concentrations remained high, indicating continued ventilation by DSW. This natural experiment illustrates how local changes in forcing over the Antarctic continental shelf can drive large and rapid changes in the abyssal ocean.

  11. Augmenting two-dimensional hydrodynamic simulations with measured velocity data to identify flow paths as a function of depth on Upper St. Clair River in the Great Lakes basin

    USGS Publications Warehouse

    Holtschlag, D.J.; Koschik, J.A.

    2005-01-01

    Upper St. Clair River, which receives outflow from Lake Huron, is characterized by flow velocities that exceed 7 feet per second and significant channel curvature that creates complex flow patterns downstream from the Blue Water Bridge in the Port Huron, Michigan, and Sarnia, Ontario, area. Discrepancies were detected between depth-averaged velocities previously simulated by a two-dimensional (2D) hydrodynamic model and surface velocities determined from drifting buoy deployments. A detailed ADCP (acoustic Doppler current profiler) survey was done on Upper St. Clair River during July 1–3, 2003, to help resolve these discrepancies. As part of this study, a refined finite-element mesh of the hydrodynamic model used to identify source areas to public water intakes was developed for Upper St. Clair River. In addition, a numerical procedure was used to account for radial accelerations, which cause secondary flow patterns near channel bends. The refined model was recalibrated to better reproduce local velocities measured in the ADCP survey. ADCP data also were used to help resolve the remaining discrepancies between simulated and measured velocities and to describe variations in velocity with depth. Velocity data from ADCP surveys have significant local variability, and statistical processing is needed to compute reliable point estimates. In this study, velocity innovations were computed for seven depth layers posited within the river as the differences between measured and simulated velocities. For each layer, the spatial correlation of velocity innovations was characterized by use of variogram analysis. Results were used with kriging to compute expected innovations within each layer at applicable model nodes. Expected innovations were added to simulated velocities to form integrated velocities, which were used with reverse particle tracking to identify the expected flow path near a sewage outfall as a function of flow depth. Expected particle paths generated by use of the integrated velocities showed that surface velocities in the upper layers tended to originate nearer the Canadian shoreline than velocities near the channel bottom in the lower layers. Therefore, flow paths to U.S. public water intakes located on the river bottom are more likely to be in the United States than withdrawals near the water surface. Integrated velocities in the upper layers are generally consistent with the surface velocities indicated by drifting-buoy deployments. Information in the 2D hydrodynamic model and the ADCP measurements was insufficient to describe the vertical flow component. This limitation resulted in the inability to account for vertical movements on expected flow paths through Upper St. Clair River. A three dimensional hydrodynamic model would be needed to account for these effects.

  12. Convective Differentiation of the Earth's Mantle

    NASA Astrophysics Data System (ADS)

    Hansen, U.; Schmalzl, J.; Stemmer, K.

    2007-05-01

    The differentiation of the Earth is likely to be influenced by convective motions within the early mantle. Double- diffusive convection (d.d.c), driven by thermally and compositionally induced density differences is considered as a vital mechanism behind the dynamic differentiation of the early mantle.. We demonstrate that d.d.c can lead to layer formation on a planetary scale in the diffusive regime where composition stabilizes the system whil heat provides the destabilizing force. Choosing initial conditions in which a stable compositional gradient overlies a hot reservoir we mimic the situation of a planet in a phase after core formation. Differently from earlier studies we fixed the temperature rather than the heat flux at the lower boundary, resembling a more realistic condition for the core-mantle boundary. We have carried out extended series of numerical experiments, ranging from 2D calculations in constant viscosity fluids to fully 3D experiments in spherical geometry with strongly temperature dependent viscosity. The buoyancy ratio R and the Lewis number Le are the important dynamical parameters. In all scenarios we could identify a parameter regime where the non-layered initial structure developed into a state consisting of several, mostly two layers. Initially plumes from the bottom boundary homogenize a first layer which subsequently thickens. The bottom layer heats up and then convection is initiated in the top layer. This creates dynamically (i.e. without jump in the material behavior) a stack of separately convecting layers. The bottom layer is significantly thicker than the top layer. Strongly temperature dependent viscosity leads to a more complex evolution The formation of the bottom layer is followed by the generation of several layers on top. Finally the uppermost layer starts to convect. In general, the multilayer structure collapses into a two layer system. We employed a numerical technique, allowing for a diffusion free treatment of the compositional field. In each case a similar evolution has been observed. This indicates that a temporary formation of layered structures in planetary interiors is a typical phenomenon. Moreover, in this scenario, plate tectonics appears only in later stages of the evolution.

  13. Study on an undershot cross-flow water turbine

    NASA Astrophysics Data System (ADS)

    Nishi, Yasuyuki; Inagaki, Terumi; Li, Yanrong; Omiya, Ryota; Fukutomi, Junichiro

    2014-06-01

    This study aims to develop a water turbine suitable for ultra-low heads in open channels, with the end goal being the effective utilization of unutilized hydroelectric energy in agricultural water channels. We performed tests by applying a cross-flow runner to an open channel as an undershot water turbine while attempting to simplify the structure and eliminate the casing. We experimentally investigated the flow fields and performance of water turbines in states where the flow rate was constant for the undershot cross-flow water turbine mentioned above. In addition, we compared existing undershot water turbines with our undershot cross-flow water turbine after attaching a bottom plate to the runner. From the results, we were able to clarify the following. Although the effective head for cross-flow runners with no bottom plate was lower than those found in existing runners equipped with a bottom plate, the power output is greater in the high rotational speed range because of the high turbine efficiency. Also, the runner with no bottom plate differed from runners that had a bottom plate in that no water was being wound up by the blades or retained between the blades, and the former received twice the flow due to the flow-through effect. As a result, the turbine efficiency was greater for runners with no bottom plate in the full rotational speed range compared with that found in runners that had a bottom plate.

  14. Chemical data for bottom sediment, lake water, bottom-sediment pore water, and fish in Mountain Creek Lake, Dallas, Texas, 1994-96

    USGS Publications Warehouse

    Jones, S.A.; Van Metre, P.C.; Moring, J.B.; Braun, C.L.; Wilson, J.T.; Mahler, B.J.

    1997-01-01

    Mountain Creek Lake is a reservoir adjacent to two U.S. Department of the Navy facilities, the Naval Weapons Industrial Reserve Plant and the Naval Air Station in Dallas, Texas. A Resource Conservation and Recovery Act Facility Investigation found ground-water plumes containing chlorinated solvents on both facilities. These findings led to a U.S. Geological Survey study of Mountain Creek Lake adjacent to both facilities between June 1994 and August 1996. Bottom sediments, lake water, bottom-sediment pore water, and fish were collected for chemical analysis.

  15. Great differences in the critical erosion threshold between surface and subsurface sediments: A field investigation of an intertidal mudflat, Jiangsu, China

    NASA Astrophysics Data System (ADS)

    Shi, Benwei; Wang, Ya Ping; Wang, Li Hua; Li, Peng; Gao, Jianhua; Xing, Fei; Chen, Jing Dong

    2018-06-01

    Understanding of bottom sediment erodibility is necessary for the sustainable management and protection of coastlines, and is of great importance for numerical models of sediment dynamics and transport. To investigate the dependence of sediment erodibility on degree of consolidation, we measured turbidity, waves, tidal currents, intratidal bed-level changes, and sediment properties on an exposed macrotidal mudflat during a series of tidal cycles. We estimated the water content of surface sediments (in the uppermost 2 cm of sediment) and sub-surface sediments (at 2 cm below the sediment surface). Bed shear stress values due to currents (τc), waves (τw), and combined current-wave action (τcw) were calculated using a hydrodynamic model. In this study, we estimate the critical shear stress for erosion using two approaches and both of them give similar results. We found that the critical shear stress for erosion (τce) was 0.17-0.18 N/m2 in the uppermost 0-2 cm of sediment and 0.29 N/m2 in sub-surface sediment layers (depth, 2 cm), as determined by time series of τcw values and intratidal bed-level changes, and values of τce, obtained using the water content of bottom sediments, were 0.16 N/m2 in the uppermost 2 cm and 0.28 N/m2 in the sub-surface (depth, 2 cm) sediment. These results indicate that the value of τce for sub-surface sediments (depth, 2 cm) is much greater than that for the uppermost sediments (depth, 0-2 cm), and that the τce value is mainly related to the water content, which is determined by the extent of consolidation. Our results have implications for improving the predictive accuracy of models of sediment transport and morphological evolution, by introducing variable τce values for corresponding sediment layers, and can also provide a mechanistic understanding of bottom sediment erodibility at different sediment depths on intertidal mudflats, as related to differences in the consolidation time.

  16. Observations and simulations of the bottom nepheloid layer in the Lafourche Trough, Louisiana Continental Shelf

    NASA Astrophysics Data System (ADS)

    Jolliff, J.; Jarosz, E.; Penko, A.; Smith, T.

    2017-12-01

    The "Lafourche Trough" is a mud/silt -dominated, elongate seafloor depression located between transgressive sandy shoals approximately 50 km south of Cocodrie, Louisiana. These irregular bathymetric features are relicts of the abandoned Lafourche delta complex that still have an impact upon coupled sediment-hydrodynamic processes occurring today. Repeated optical and physical oceanographic surveys conducted during the spring of 2015 and winter 2017 reveal persistent bottom nepheloid layers (BNLs) characterized by extreme optical turbidity (beam attenuation 10 m-1, 532 nm). The manifestation and persistence of cohesive sediment BNLs in this area appears to result from a complex interplay between tidal currents, bathymetry, and frontal dynamics along the edge of the Mississippi River plume. Numerical experiments were performed using the Coupled Ocean Atmosphere Mesoscale Prediction System (COAMPS), an integrated air-sea-wave operational forecasting tool, that includes a simplified numerical sediment resuspension and transport scheme in order to simulate the nepheloid layer observations through the trough. The model results suggest that the wave-current bottom boundary layer is a critical factor in BNL development, and thusly, without wave model integration into COAMPS the system struggles to replicate the observations. Future modeling work will need to explore the potential suppression of physical mixing due to density perturbations along the BNL to fluid mud continuum within the bottom boundary layer.

  17. Double diffusion in the frontal zones of the Yellow and East China Seas in winter

    NASA Astrophysics Data System (ADS)

    Oh, K.; Lee, S.

    2017-12-01

    Where the cold, fresh water of the Yellow Sea (YS) and the warm, salty water of the East China Sea (ECS) meet, northern and southern fronts are formed in the southeastern YS and the northwestern ECS, respectively. Strong thermohaline fronts are formed on the northern front, and a strong thermocline and a temperature reversal phenomenon are represented in this front. To understand the water structure of this thermohaline zone, we examined double diffusion in the frontal zones in February 2003 using hydrographic data. In the northern front, the warm, salty Cheju Warm Current Water (CWCW) moved northwards along the bottom layer and the cold, fresh Yellow Sea Cold Water (YSCW) flowed southward in the upper layer. As a result, strong thermohaline fronts forms in the area where the two water masses met, and the slope was developed downward across the front. In this area, a strong thermocline and temperature reversal structures were present. The cold, fresh Korean Coastal Water (KCW) was also found in the upper layer near the thermocline, and has a low-temperature, low-salinity more than surrounding water. When cold, fresh water is located over warm, salty water, heat diffuses through the interface between the two water masses, and then the diffusive-convection can be expected to occur. On the other hand, when warm, salty water overlays cold, fresh water, heat in the upper layer is preferentially transferred downward, and the salt-fingering occurs. The diffusive-convection occurs predominantly in the northern thermohaline front, where the cold, fresh YSCW is situated above the warm, salty CWCW and has the effect of strengthening stratification, so that the water column maintains a physically stable structure. In addition, this phenomenon seems to play a role in maintaining the reversal structure. The salt-fingering occurs in upper layers of the northern front where the cold, fresh YSCW is located over the most cold, fresh KCW. Near the northern thermo-halocline zone, the salt-fingering occurs simultaneously with the diffusive-convection, because three water masses, YSCW, KCW and CWCW, interact in that area. Therefore, it can be seen that the water structure of the northern frontal zone in winter is influenced mainly by the cold, fresh YSCW, the most cold, fresh KCW, and the warm, salty CWCW.

  18. Geoacoustic inversion of a shallow fresh-water environment

    NASA Astrophysics Data System (ADS)

    Stotts, Steven A.; Knobles, David P.; Koch, Robert A.; Piper, James N.; Keller, Jason A.

    2003-10-01

    A recent experiment was conducted at The University of Texas/Applied Research Laboratories test station located at Lake Travis, Austin, TX. Implosive (light bulb), explosive (firecracker), and tonal sources were recorded on a dual receiver system located on the bottom next to a range-independent underwater river channel. Inversion results of the broadband time series obtained over ranges less than 1.5 km were used to predict measured transmission loss at several tonal frequencies in the band from 250-1000 Hz. The average water depth was approximately 38 m along the channel during the experiment. Sound speed profiles were calculated from recorded temperature readings measured as a function of depth. Implosive source spectrums were measured and used to evaluate a model/data correlation cost function in a simulated annealing algorithm. Comparisons of inversion results using both a normal mode and a ray-based plane wave reflection coefficient forward model [Stotts et al., J. Acoust. Soc. Am. (submitted)] are discussed. Predicted transmission loss based on the inversion results are compared to the measured transmission loss. Differences between fluid and elastic layer bottom models will also be presented.

  19. A preliminary study on puncture resistances of top and bottom layers of multi-layered needlepunched nonwoven geotextiles

    NASA Astrophysics Data System (ADS)

    Alan, G.; Tercan, M.

    2017-10-01

    Needlepunched nonwoven textiles are commonly used as geotextiles for various applications. Considering both environmental and economical benefits, utilization of recycled fibres in nonwoven geotextiles has become an attractive issue. Within this scope, the aim of this study is to evaluate the puncture resistance performances of top and bottom layers of multi-layered needle punched nonwovens made of recycled fibres to be used as membrane protective geotextiles by comparing them with those of made from polypropylene and polyester fibres. Puncture resistance results indicated that nonwovens made of recycled fibres demonstrated good performances at this preliminary stage.

  20. Current structure of strongly nonlinear interfacial solitary waves

    NASA Astrophysics Data System (ADS)

    Semin, Sergey; Kurkina, Oxana; Kurkin, Andrey; Talipova, Tatiana; Pelinovsky, Efim; Churaev, Egor

    2015-04-01

    The characteristics of highly nonlinear solitary internal waves (solitons) in two-layer flow are computed within the fully nonlinear Navier-Stokes equations with use of numerical model of the Massachusetts Institute of Technology (MITgcm). The verification and adaptation of the model is based on the data from laboratory experiments [Carr & Davies, 2006]. The present paper also compares the results of our calculations with the computations performed in the framework of the fully nonlinear Bergen Ocean Model [Thiem et al, 2011]. The comparison of the computed soliton parameters with the predictions of the weakly nonlinear theory based on the Gardner equation is given. The occurrence of reverse flow in the bottom layer directly behind the soliton is confirmed in numerical simulations. The trajectories of Lagrangian particles in the internal soliton on the surface, on the interface and near the bottom are computed. The results demonstrated completely different trajectories at different depths of the model area. Thus, in the surface layer is observed the largest displacement of Lagrangian particles, which can be more than two and a half times larger than the characteristic width of the soliton. Located at the initial moment along the middle pycnocline fluid particles move along the elongated vertical loop at a distance of not more than one third of the width of the solitary wave. In the bottom layer of the fluid moves in the opposite direction of propagation of the internal wave, but under the influence of the reverse flow, when the bulk of the velocity field of the soliton ceases to influence the trajectory, it moves in the opposite direction. The magnitude of displacement of fluid particles in the bottom layer is not more than the half-width of the solitary wave. 1. Carr, M., and Davies, P.A. The motion of an internal solitary wave of depression over a fixed bottom boundary in a shallow, two-layer fluid. Phys. Fluids, 2006, vol. 18, No. 1, 1 - 10. 2. Thiem, O., Carr, M., Berntsen, J., and Davies, P.A. Numerical simulation of internal solitary wave-induced reverse flow and associated vortices in a shallow, two-layer fluid benthic boundary layer. Ocean Dynamics, 2011, vol. 61, No. 6, 857 - 872.

  1. Unsaturated hydraulic behaviour of a permeable pavement: Laboratory investigation and numerical analysis by using the HYDRUS-2D model

    NASA Astrophysics Data System (ADS)

    Turco, Michele; Kodešová, Radka; Brunetti, Giuseppe; Nikodem, Antonín; Fér, Miroslav; Piro, Patrizia

    2017-11-01

    An adequate hydrological description of water flow in permeable pavement systems relies heavily on the knowledge of the unsaturated hydraulic properties of the construction materials. Although several modeling tools and many laboratory methods already exist in the literature to determine the hydraulic properties of soils, the importance of an accurate materials hydraulic description of the permeable pavement system, is increasingly recognized in the fields of urban hydrology. Thus, the aim of this study is to propose techniques/procedures on how to interpret water flow through the construction system using the HYDRUS model. The overall analysis includes experimental and mathematical procedures for model calibration and validation to assess the suitability of the HYDRUS-2D model to interpret the hydraulic behaviour of a lab-scale permeable pavement system. The system consists of three porous materials: a wear layer of porous concrete blocks, a bedding layers of fine gravel, and a sub-base layer of coarse gravel. The water regime in this system, i.e. outflow at the bottom and water contents in the middle of the bedding layer, was monitored during ten irrigation events of various durations and intensities. The hydraulic properties of porous concrete blocks and fine gravel described by the van Genuchten functions were measured using the clay tank and the multistep outflow experiments, respectively. Coarse gravel properties were set at literature values. In addition, some of the parameters (Ks of the concrete blocks layer, and α, n and Ks of the bedding layer) were optimized with the HYDRUS-2D model from water fluxes and soil water contents measured during irrigation events. The measured and modeled hydrographs were compared using the Nash-Sutcliffe efficiency (NSE) index (varied between 0.95 and 0.99) while the coefficient of determination R2 was used to assess the measured water content versus the modelled water content in the bedding layer (R2 = 0.81 ÷ 0.87) . The parameters were validated using the remaining sets of measurements resulting in NSE values greater than 0.90 (0.91 ÷ 0.99) and R2 between 0.63 and 0.91. Results have confirmed the applicability of HYDRUS-2D to describe correctly the hydraulic behaviour of the lab-scale system.

  2. Series interconnected photovoltaic cells and method for making same

    DOEpatents

    Albright, Scot P.; Chamberlin, Rhodes R.; Thompson, Roger A.

    1995-01-01

    A novel photovoltaic module (10) and method for constructing the same are disclosed. The module (10) includes a plurality of photovoltaic cells (12) formed on a substrate (14) and laterally separated by interconnection regions (15). Each cell (12) includes a bottom electrode (16), a photoactive layer (18) and a top electrode layer (20). Adjacent cells (12) are connected in electrical series by way of a conductive-buffer line (22). The buffer line (22) is also useful in protecting the bottom electrode (16) against severing during downstream layer cutting processes.

  3. 76 FR 14923 - Endangered and Threatened Species; Take of Anadromous Fish

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-18

    ... (i.e., surface and bottom water temperature, salinity, near bottom dissolved oxygen concentration...-water and bottom trawls) are adequately characterizing schools of hake. The IVC research would take...

  4. Characterization of bottom-sediment, water, and elutriate chemistry at selected stations at Reelfoot Lake, Tennessee

    USGS Publications Warehouse

    Broshears, R.E.

    1991-01-01

    To better-understand and predict the potential effect of dredging on water quality at Reelfoot Lake, chemical analyses were conducted on samples of lake water, bottom sediment, and elutriate water. Chemical analyses were conducted on samples of lake water, bottom sediment, and elutriate water collected at five stations in the lake during November 1988. Lake water was of the calcium magnesium bicarbonate type with an average dissolved-solids concentration of 120 milligrams per liter. Trace constituents were present in bottom sediments at concentrations representative of their average relative abundance in the earth?s crust. Elutriate waters prepared by mixing bottom sediment and lake water had suspended-solids concentrations as high as 2,000 milligrams per liter which exerted significant oxygen demand Trace constituents in the unfiltered elutriate waters were elevated with respect to lake water; elevated concentrations were attributable to the increased suspended-solids concentrations. Concentrations of total-recoverable copper, lead., and zinc in many elutriate waters exceeded U.S. Environmental Protection Agency?s water-quality criteria for the protection of freshwater aquatic life. The toxicity of elutriate waters, as measured by a 48-hour bioassay with Ceriodaphnia dubia, was low.

  5. Enhancement of polyethersulfone (PES) membrane performance by modification with rice husk nanosilica for removal of organic matter in water

    NASA Astrophysics Data System (ADS)

    Mulyati, S.; Armando, M. A.; Mawardi, H.; Azmi, F. A.; Pratiwi, W. P.; Fadzlina, A.; Akbar, R.; Syawaliah

    2018-03-01

    This paper reports the effects of rice husk nanosilica addition on the performance of polyethersulfone (PES) membrane. Polyethersulfone membrane (PES) was fabricated by using N-methyl-2-pyrolidone (NMP) as a solvent and rice husk nanosilica as a modifying agent. The influence of the rice husk nanosilica additive on the characteristics and performance of the membrane has been studied. Scanning Electron Microscopy (SEM) analysis confirmed that the manufactured membrane has an asymmetric morphological structure consisting of two layers. The upper part of the membrane is a thin layer, meanwhile in the bottom side is a porous layer. The addition of 5% nanosilica resulting a PES membrane to have a bigger porous than that of pristine PES. The pure water flux of nanosilica-modified membranes were greater in comparison to the pure water flux of unmodified PES membrane. The performance of all membranes were evaluated on humic acid removal. The highest selectivity was showcased by pure PES membrane. The introduction of rice husk nanosilica additive to the membrane declined the selectivity of the membrane to humic acid in the feed solution. This is caused by the pores enlargement and enhanced hydrophilicity of the membrane after modification with rice husk biosilica.

  6. Die singulation method and package formed thereby

    DOEpatents

    Anderson, Robert C [Tucson, AZ; Shul, Randy J [Albuquerque, NM; Clews, Peggy J [Tijeras, NM; Baker, Michael S [Albuquerque, NM; De Boer, Maarten P [Albuquerque, NM

    2012-08-07

    A method is disclosed for singulating die from a substrate having a sacrificial layer and one or more device layers, with a retainer being formed in the device layer(s) and anchored to the substrate. Deep Reactive Ion Etching (DRIE) etching of a trench through the substrate from the bottom side defines a shape for each die. A handle wafer is then attached to the bottom side of the substrate, and the sacrificial layer is etched to singulate the die and to form a frame from the retainer and the substrate. The frame and handle wafer, which retain the singulated die in place, can be attached together with a clamp or a clip and to form a package for the singulated die. One or more stops can be formed from the device layer(s) to limit a sliding motion of the singulated die.

  7. Habitability constraints on water-rich exoplanets

    NASA Astrophysics Data System (ADS)

    Noack, Lena; Höning, Dennis; Rivoldini, Attilio; Heistracher, Clemens; Zimov, Nastasia; Journaux, Baptiste; Lammer, Helmut; Van Hoolst, Tim; Hendrik Bredehöft, Jan

    2016-04-01

    This research addresses the characterization, modelling, thermal evolution and possible habitability of water-rich exoplanets. Water is necessary for the origin and survival of life as we know it. In the search for habitable worlds, water-rich planets therefore seem obvious candidates. The water layer on such planets could be hundreds of kilometers deep. Depending on the temperature profile and the pressure gradient, it is likely that at great depths a significant part of the water layer is solid high pressure ice. Whether the solid ice layer extends to the bottom of the water layer, or if a shallow lower ocean forms above the silicate mantle, depends amongst others on the thermal state of the planet. We therefore model the thermal evolution of water-rich planets with a 1D parameterized model. Depth-dependent profiles for thermodynamic properties as well as pressure and gravity are obtained by solving the Poisson equation for the gravity and the hydrostatic pressure equation for pre-defined mass and composition (in terms of iron, silicates and water) [1]. For density, equations of state are applied. For the simulation of the thermal evolution of water-rich planets, several parameters (as initial temperatures or layer thicknesses) are unknown. We therefore employ a quantitatve study with more than 20'000 simulations, where we investigated which parameters have the largest influence on the appearance of a lower ocean, i.e. the possible melting of high-pressure ice by heat flowing out of the silicate mantle [2]. We find that the surface temperature has the largest influence on the thickness of water layers, for which a lower ocean can still form between the high-pressure ice layer and the silicate mantle. For higher surface temperatures, not only entirely liquid oceans are possible for deeper water shells, also a liquid ocean can form under high-pressure ice layers of hundreds of kilometer thickness (for a 1 Earth-mass planet). Deeper down, the lower ocean can still appear episodically at the water-mantle boundary (WMB). We also investigated the main paramters influencing the existence of volcanic activity and silicate crust formation. Under deep water layers, the high pressure from the overlying water layer can inhibit melting in the mantle. The main parameters influencing the maximal water layer depth, for which melting is still possible, are indeed the parameters influencing the mantle energy budget, which are the amount of radioactive heat sources and the initial upper mantle temperature. Plate tectonics also has a strong influence on the existence of volcanism. Crustal parameters (initial thickness or heat sources enrichment factor) as well as the ice rheology (i.e. the isolating effect of the ice shell on the mantle) have only a small influence on melting processes in the interior and the formation of crust. [1] L. Noack, A. Rivoldini and T. Van Hoolst 2015: CHIC - Coupling Habitability, Interior and Crust: A new Code for Modeling the Thermal Evolution of Planets and Moons. INFOCOMP 2015, ISSN 2308-3484, ISBN 978-1-61208-416-9, pp. 84-90, IARIA, 2015. [2] L. Noack, D. Höning, A. Rivoldini, C. Heistracher, N. Zimov, B. Journaux, H. Lammer, T. Van Hoolst and J.H. Bredehöft: Water-rich planets: how habitable is a water layer deeper than on Earth? Submitted to Icarus.

  8. INDIVIDUAL TURBULENT CELL INTERACTION: BASIS FOR BOUNDARY LAYER ESTABLISHMENT

    EPA Science Inventory

    Boundary layers are important in determining the forces on objects in flowing fluids, mixing characteristics, and other phenomena. For example, benthic boundary layers are frequently active resuspension layers that determine bottom turbidity and transniissivity. Traditionally, bo...

  9. Columbia Bay, Alaska: an 'upside down' estuary

    USGS Publications Warehouse

    Walters, R.A.; Josberger, E.G.; Driedger, C.L.

    1988-01-01

    Circulation and water properties within Columbia Bay, Alaska, are dominated by the effects of Columbia Glacier at the head of the Bay. The basin between the glacier terminus and the terminal moraine (sill depth of about 22 m) responds as an 'upside down' estuary with the subglacial discharge of freshwater entering at the bottom of the basin. The intense vertical mixing caused by the bouyant plume of freshwater creates a homogeneous water mass that exchanges with the far-field water through either a two- or a three-layer flow. In general, the glacier acts as a large heat sink and creates a water mass which is cooler than that in fjords without tidewater glaciers. The predicted retreat of Columbia Glacier would create a 40 km long fjord that has characteristics in common with other fjords in Prince William Sound. ?? 1988.

  10. Imaging Reservoir Siltation and Quaternary Stratigraphy Beneath the Mactaquac Headpond by Acoustic and Ground Penetrating Radar Sub-bottom Imaging

    NASA Astrophysics Data System (ADS)

    Grace, M.; Butler, K. E.; Peter, S.; Yamazaki, G.; Haralampides, K.

    2016-12-01

    The Mactaquac Hydroelectric Generating Station, located on the Saint John River in New Brunswick, Canada, is approaching the end of its life due to deterioration of the concrete structures. As part of an aquatic ecosystem study, designed to support a decision on the future of the dam, sediment in the headpond, extending 80 km upriver, is being examined. The focus of this sub-study lies in (i) mapping the thickness of sediments that have accumulated since inundation in 1968, and (ii) imaging the deeper glacial and post-glacial stratigraphy. Acoustic sub-bottom profiling surveys were completed during 2014 and 2015. An initial 3.5 kHz chirp sonar survey proved ineffective, lacking in both resolution and depth of the penetration. A follow-up survey employing a boomer-based "Seistec" sediment profiler provided better results, resolving sediment layers as thin as 12 cm, and yielding coherent reflections from the deeper Quaternary sediments. Post-inundation sediments in the lowermost 25 km of the headpond, between the dam and Bear Island, are interpreted to average 26 cm in thickness with the thickest deposits (up to 65 cm) in deep water areas overlying the pre-inundation riverbed west of Snowshoe Island, and south and east of Bear Island. A recent coring program confirmed the presence of silty sediment and showed good correlation with the Seistec thickness estimates. In the 15 km stretch upriver of Bear Island to Nackawic, the presence of gas in the uppermost sediments severely limits sub-bottom penetration and our ability to interpret sediment thicknesses. Profiles acquired in the uppermost 40 km reach of the headpond, extending to Woodstock, show a strong, positive water bottom reflection and little to no sub-bottom penetration, indicating the absence of soft post-inundation sediment. Deeper reflections observed within 5 km of the dam reveal a buried channel cut into glacial till, extending up to 20 m below the water bottom. Channel fill includes a finely laminated unit interpreted to be glaciolacustrine clay-silt and a possible esker - similar to stratigraphy found 20 - 30 km downriver at Fredericton. Future plans include a small scale survey in late summer, 2016 to evaluate the suitability of waterborne ground penetrating radar (GPR) profiling as an alternative to acoustic profiling in areas of gas-charged sediment.

  11. Research on Hydrodynamic Interference Suppression of Bottom-Mounted Monitoring Platform with Fairing Structure

    NASA Astrophysics Data System (ADS)

    Wang, Zhen; Zheng, Yi; Mao, Yu-feng; Wang, Ya-zhou; Yu, Yan-ting; Liu, Hong-ning

    2018-03-01

    In the disturbance of unsteady flow field under the sea, the monitoring accuracy and precision of the bottom-mounted acoustic monitoring platform will decrease. In order to reduce the hydrodynamic interference, the platform wrapped with fairing structure and separated from the retrieval unit is described. The suppression effect evaluation based on the correlation theory of sound pressure and particle velocity for spherical wave in infinite homogeneous medium is proposed and the difference value between them is used to evaluate the hydrodynamic restraining performance of the bottom-mounted platform under far field condition. Through the sea test, it is indicated that the platform with sparse layers fairing structure (there are two layers for the fairing, in which the inside layer is 6-layers sparse metal net, and the outside layer is 1-layer polyester cloth, and then it takes sparse layers for short) has no attenuation in the sound pressure response to the sound source signal, but obvious suppression in the velocity response to the hydrodynamic noise. The effective frequency of the fairing structure is decreased below 10 Hz, and the noise magnitude is reduced by 10 dB. With the comparison of different fairing structures, it is concluded that the tighter fairing structure can enhance the performance of sound transmission and flow restraining.

  12. Importance of the colmation layer in the transport and removal of cyanobacteria, viruses, and dissolved organic carbon during natural lake-bank filtration

    USGS Publications Warehouse

    Harvey, Ronald W.; Metge, David W.; LeBlanc, Denis R.; Underwood, Jennifer C.; Aiken, George R.; Butler, Kenna D.; McCobb, Timothy D.; Jasperse, Jay

    2015-01-01

    This study focused on the importance of the colmation layer in the removal of cyanobacteria, viruses, and dissolved organic carbon (DOC) during natural bank filtration. Injection-and-recovery studies were performed at two shallow (0.5 m deep), sandy, near-shore sites at the southern end of Ashumet Pond, a waste-impacted, kettle pond on Cape Cod, MA, that is subject to periodic blooms of cyanobacteria and continuously recharges a sole-source drinking-water aquifer. The experiment involved assessing the transport behaviors of bromide (conservative tracer), Synechococcus sp. IU625 (cyanobacterium, 2.6 ± 0.2 µm), AS-1 (tailed cyanophage, 110 nm long), MS2 (coliphage, 26 nm diameter), and carboxylate-modified microspheres (1.7 µm diameter) introduced to the colmation layer using a bag-and-barrel (Lee-type) seepage meter. The injectate constituents were tracked as they were advected across the pond water–groundwater interface and through the underlying aquifer sediments under natural-gradient conditions past push-point samplers placed at ∼30-cm intervals along a 1.2-m-long, diagonally downward flow path. More than 99% of the microspheres, IU625, MS2, AS-1, and ∼44% of the pond DOC were removed in the colmation layer (upper 25 cm of poorly sorted bottom sediments) at two test locations characterized by dissimilar seepage rates (1.7 vs. 0.26 m d−1). Retention profiles in recovered core material indicated that >82% of the attached IU625 were in the top 3 cm of bottom sediments. The colmation layer was also responsible for rapid changes in the character of the DOC and was more effective (by three orders of magnitude) at removing microspheres than was the underlying 20-cm-thick segment of sediment.

  13. Remote sensing estimation of colored dissolved organic matter (CDOM) in optically shallow waters

    NASA Astrophysics Data System (ADS)

    Li, Jiwei; Yu, Qian; Tian, Yong Q.; Becker, Brian L.

    2017-06-01

    It is not well understood how bottom reflectance of optically shallow waters affects the algorithm performance of colored dissolved organic matters (CDOM) retrieval. This study proposes a new algorithm that considers bottom reflectance in estimating CDOM absorption from optically shallow inland or coastal waters. The field sampling was conducted during four research cruises within the Saginaw River, Kawkawlin River and Saginaw Bay of Lake Huron. A stratified field sampling campaign collected water samples, determined the depth at each sampling location and measured optical properties. The sampled CDOM absorption at 440 nm broadly ranged from 0.12 to 8.46 m-1. Field sample analysis revealed that bottom reflectance does significantly change water apparent optical properties. We developed a CDOM retrieval algorithm (Shallow water Bio-Optical Properties algorithm, SBOP) that effectively reduces uncertainty by considering bottom reflectance in shallow waters. By incorporating the bottom contribution in upwelling radiances, the SBOP algorithm was able to explain 74% of the variance of CDOM values (RMSE = 0.22 and R2 = 0.74). The bottom effect index (BEI) was introduced to efficiently separate optically shallow and optically deep waters. Based on the BEI, an adaptive approach was proposed that references the amount of bottom effect in order to identify the most suitable algorithm (optically shallow water algorithm [SBOP] or optically deep water algorithm [QAA-CDOM]) to improve CDOM estimation (RMSE = 0.22 and R2 = 0.81). Our results potentially help to advance the capability of remote sensing in monitoring carbon pools at the land-water interface.

  14. Dynamics of particle export on the Northwest Atlantic margin

    NASA Astrophysics Data System (ADS)

    Hwang, Jeomshik; Manganini, Steven J.; Montluçon, Daniel B.; Eglinton, Timothy I.

    2009-10-01

    The Northwest Atlantic margin is characterized by high biological productivity in shelf and slope surface waters. In addition to carbon supply to underlying sediments, the persistent, intermediate depth nepheloid layers emanating from the continental shelves, and bottom nepheloid layers maintained by strong bottom currents associated with the southward flowing Deep Western Boundary Current (DWBC), provide conduits for export of organic carbon over the margin and/or to the interior ocean. As a part of a project to understand dynamics of particulate organic carbon (POC) cycling in this region, we examined the bulk and molecular properties of time-series sediment trap samples obtained at 968 m, 1976 m, and 2938 m depths from a bottom-tethered mooring on the New England slope (water depth, 2988 m). Frequent occurrences of higher fluxes in deep relative to shallower sediment traps and low Δ 14C values of sinking POC together provide strong evidence for significant lateral transport of aged organic matter over the margin. Comparison of biogeochemical properties such as aluminum concentration and flux, and iron concentration between samples intercepted at different depths shows that particles collected by the deepest trap had more complex sources than the shallower ones. These data also suggest that at least two modes of lateral transport exist over the New England margin. Based on radiocarbon mass balance, about 30% (±10%) of sinking POC in all sediment traps is estimated to be derived from lateral transport of resuspended sediment. A strong correlation between Δ 14C values and aluminum concentrations suggests that the aged organic matter is associated with lithogenic particles. Our results suggest that lateral transport of organic matter, particularly that resulting from sediment resuspension, should be considered in addition to vertical supply of organic matter derived from primary production, in order to understand carbon cycling and export over continental margins.

  15. Numerical simulation of impurity transport in Lake Baikal during the summer period

    NASA Astrophysics Data System (ADS)

    Tsydenov, Bair O.

    2017-11-01

    The distributions of impurities obtained as a result of numerical modeling on the Srednyaya arm (Selenga River mouth)- Cape Golyi cross-section of Lake Baikal, Siberia, Russia, are presented. The data on the air temperature, relative humidity, atmospheric pressure, humidity, and cloudiness from the Babushkin meteorological station from 01.06.2016 to 30.06.2016 are used as the weather condition in the mathematical model. The results of simulation have shown that the impurities dissolved in water reach the bottom of the Selenga shallow basin of Lake Baikal. As the heat accumulation increases and the river waters warm up, the maximum concentrations of suspended substances tend to remain in the upper layers of the lake.

  16. Experimental study of a depth-encoding PET detector inserting horizontal-striped glass between crystal layers

    NASA Astrophysics Data System (ADS)

    Yang, J.; Kim, K. B.; Choi, Y.; Kang, J.

    2018-04-01

    A depth-encoding positron emission tomography (PET) detector inserting a horizontal-striped glass between pixilated scintillation crystal layers was developed and experimentally evaluated. The detector consists of 2-layers of 4×4 LYSO array arranged with a 3.37 mm pitch. Horizontal-striped glasses with 1×4 array with different thickness of 3, 4 and 5 mm were inserted between top- and bottom-crystal layers. Bottom surface of bottom-layer was optically coupled to a 4×4 GAPD array. Sixteen output signals from DOI-PET detector were multiplexed by modified resistive charge division (RCD) networks and multiplexed signals were fed into custom-made charge-sensitive preamplifiers. The four amplified signals were digitized and recorded by the custom-made DAQ system based on FPGA. The four digitized outputs were post-processed and converted to flood histograms for each interaction event. Experimental results revealed that all crystal pixels were clearly identified on the 2D flood histogram without overlapping. Patterns of the 2D flood histogram were constituted with arrangements of [bottom–top–bottom–top–\\ldots–top–bottom–top–bottom] crystal responses in X-direction. These could be achieved by employing horizontal-striped glass that controlled the extent of light dispersion towards the X-direction in crystal layers for generation of a different position mapping for each layer and the modified RCD network that controls degree of charge sharing in readout electronics for reduction of identification error. This study demonstrated the proposed DOI-PET detector can extract the 3D γ-ray interaction position without considerable performance degradation of PET detector from the 2D flood histogram.

  17. Wrinkling of solidifying polymeric coatings

    NASA Astrophysics Data System (ADS)

    Basu, Soumendra Kumar

    2005-07-01

    In coatings, wrinkles are viewed as defects or as desired features for low gloss, and texture. In either case, discovering the origin of wrinkles and the conditions that lead to their formation is important. This research examines what wrinkling requires and proposes a mechanism to explain the observations. All curing wrinkling coatings contain multi-functional reactants. Upon curing, all develop a depth-wise gradient in solidification that result in a cross-linked elastic skin atop a viscous bottom layer. It is hypothesized that compressive stress develops in the skin when liquid below diffuses up into the skin. High enough compressive stress buckles the skin to produce wrinkles. The hypothesis is substantiated by experimental and theoretical evidences. Effects of various application and compositional parameters on wrinkle size in a liquid-applied acrylic coating and a powder-applied epoxy coating were examined. All three components, namely resin, cross-linker and catalyst blocked with at least equimolar volatile blocker, proved to be required for wrinkling. The wrinkling phenomenon was modeled with a theory that accounts for gradient generation, cross-linking reaction and skinning; predictions compared well with observations. Two-layer non-curing coatings that have a stiff elastic layer atop a complaint elastic bottom layer wrinkled when the top layer is compressed. The top layer was compressed by either moisture absorption or differential thermal expansion. Experimental observations compared well with predictions from a theory based on force balance in multilayer systems subjected to differential contraction or expansion. A model based on the Flory-Rehner free energy of a constrained cross-linked gel was constructed that predicts the compressive stress generated in a coating when it absorbs solvent. Linear stability analysis predicts that when a compressed elastic layer is attached atop a viscous layer, it is always unstable to buckles whose wavelength exceeds a critical value; more cross-linking and poor solvent produce higher wavelength, lower amplitude wrinkles. When a compressed elastic layer is attached atop an elastic layer and subjected to more than a critical compressive stress, it is unstable to intermediate wavelengths of buckling; better solvent, higher ratio of bottom-to-top layer thickness, and lower bottom layer modulus produce higher wavelength, higher amplitude wrinkles.

  18. Layered growth with bottom-spray granulation for spray deposition of drug.

    PubMed

    Er, Dawn Z L; Liew, Celine V; Heng, Paul W S

    2009-07-30

    The gap in scientific knowledge on bottom-spray fluidized bed granulation has emphasized the need for more studies in this area. This paper comparatively studied the applicability of a modified bottom-spray process and the conventional top-spray process for the spray deposition of a micronized drug during granulation. The differences in circulation pattern, mode of growth and resultant granule properties between the two processes were highlighted. The more ordered and consistent circulation pattern of particles in a bottom-spray fluidized bed was observed to give rise to layered granule growth. This resulted in better drug content uniformity among the granule batches and within a granule batch. The processes' sensitivities to wetting and feed material characteristics were also compared and found to differ markedly. Less robustness to differing process conditions was observed for the top-spray process. The resultant bottom-spray granules formed were observed to be less porous, more spherical and had good flow properties. The bottom-spray technique can thus be potentially applied for the spray deposition of drug during granulation and was observed to be a good alternative to the conventional technique for preparing granules.

  19. Directional bottom roughness associated with waves, currents, and ripples

    USGS Publications Warehouse

    Sherwood, Christopher R.; Rosati, Julie D.; Wang, Ping; Roberts, Tiffany M.

    2011-01-01

    Roughness lengths are used in wave-current bottom boundary layer models to parameterize drag associated with grain roughness, the effect of saltating grains during sediment transport, and small-scale bottom topography (ripples and biogenic features). We made field measurements of flow parameters and recorded sonar images of ripples at the boundary of a sorted-bedform at ~12-m depth on the inner shelf for a range of wave and current conditions over two months. We compared estimates of apparent bottom roughness inferred from the flow measurements with bottom roughness calculated using ripple geometry and the Madsen (1994) one-dimensional (vertical) wave-current bottom boundary layer model. One result of these comparisons was that the model over predicted roughness of flow from the dormant large ripples when waves were small. We developed a correction to the ripple-roughness model that incorporates an apparent ripple wavelength related to the combined wave-current flow direction. This correction provides a slight improvement for low-wave conditions, but does not address several other differences between observations and the modeled roughness.

  20. Influence of the extreme conditions on the water quality and material exchange flux in the Strait of Istanbul

    NASA Astrophysics Data System (ADS)

    Altıok, Hüsne; Aslan, Aslı; Övez, Süleyman; Demirel, Nazlı; Yüksek, Ahsen; Kıratlı, Nur; Taş, Seyfettin; Müftüoğlu, Ahmet Edip; Sur, Halil Ibrahim; Okuş, Erdoğan

    2014-11-01

    This study focuses on the influence of extreme hydrological events on the water quality of the Strait of Istanbul (Bosphorus), a stratified waterway, polluted by sewage outfalls and non-point sources. Monthly collected water quality parameters (nitrate + nitrite, ortho-phosphate, silicate, dissolved oxygen, total suspended solids, chlorophyll-a and fecal indicator bacteria (fecal coliform and enterococci)) were evaluated together with the hydrological data (salinity, temperature and current flow) for 1 year. Two blockage events, identified as extreme conditions, were detected during the study: a lower layer blockage in February 2003 and an upper layer blockage in October 2003. During the lower layer blockage, the volume fluxes of the upper layer significantly increased to 28,140 m3 s- 1 and the lower layer almost stopped flowing (19 m3 s- 1). The dissolved oxidative nitrogen, ortho-phosphate and silicate inputs outflowing from the Black Sea were 117, 17.6, and 309 tons which were 3, 2, and 4 times the average daily fluxes respectively, in addition to enhancement of fecal indicator bacteria contamination in the sea surface flow. During the upper layer blockage, the volume flux of the upper layer was 3837 m3 s- 1 and the counter flow reached 24,985 m3 s- 1 at the northern exit of the Strait of Istanbul resulting in 2.7 fold increase in the mean bottom flow. The daily exports of nutrients, total suspended solid and dissolved oxygen by the lower layer flow increased by at least 2 fold compared to the mass fluxes estimated from the seasonal/annual means of volume flux and concentrations. On the other hand, fecal indicator bacteria flux by the lower layer inflow to the Black Sea decreased by at least 2 fold compared to the mean daily flux. These results show that the material exchange between the Marmara and the Black seas becomes more important during blockage events.

  1. Experimental and theoretical modelling of sand-water-object interaction under nonlinear progressive waves

    NASA Astrophysics Data System (ADS)

    Testik, Firat Yener

    An experimental and theoretical study has been conducted to obtain a fundamental understanding of the dynamics of the sand, water and a solid object interaction as progressive gravity waves impinge on a sloping beach. Aside from obvious scientific interest, this exceedingly complex physical problem is important for naval applications, related to the behavior of disk/cylindrical shaped objects (mines) in the coastal waters. To address this problem, it was divided into a set of simpler basic problems. To begin, nonlinear progressive waves were investigated experimentally in a wave tank for the case of a rigid (impermeable) sloping bottom. Parameterizations for wave characteristics were proposed and compared with the experiments. In parallel, a numerical wave tank model (NWT) was calibrated using experimental data from a single run, and wave field in the wave tank was simulated numerically for the selected experiments. Subsequently, a layer of sand was placed on the slope and bottom topography evolution processes (ripple and sandbar dynamics, bottom topography relaxation under variable wave forcing, etc.) were investigated experimentally. Models for those processes were developed and verified by experimental measurements. Flow over a circular cylinder placed horizontally on a plane wall was also studied. The far-flow field of the cylinder placed in the wave tank was investigated experimentally and numerical results from the NWT simulations were compared with the experimental data. In the mean time, the near-flow velocity/vorticity field around a short cylinder under steady and oscillatory flow was studied in a towing tank. Horseshoe vortex formation and periodic shedding were documented and explained. With the understanding gained through the aforementioned studies, dynamics and burial/scour around the bottom objects in the wave tank were studied. Possible scenarios on the behavior of the disk-shaped objects were identified and explained. Scour around 3D cylindrical objects was investigated. Different scour regimes were identified experimentally and explained theoretically. Proper physical parameterizations on the time evolution and equilibrium scour characteristics were proposed and verified experimentally.

  2. Role of air on local water retention behavior in the shallow heterogeneous vadose zone

    NASA Astrophysics Data System (ADS)

    Sakaki, T.; Limsuwat, A.; Illangasekare, T. H.

    2009-12-01

    In the presence of a subsurface source, air flowing through the unsaturated soil can transport toxic vapor into subsurface structures due to pressure gradients created by, e.g., a pressure drop within the building. Development of dynamic air pathways in the subsurface are largely controlled by the geological heterogeneity and the spatial and temporal distribution of soil moisture. To better understand how these air pathways are developed, it is crucial to know how water is retained in heterogeneous medium at spatial resolutions that are finer than those adopted in typical hydrologic and soil physics applications. Although methods for soil water pressure measurement can be readily found in literature, a technique for measuring “air pressure” in wet soil is not well-established or documented. Hydrophobic porous ceramic cups have been used to measure non-wetting NAPL phase pressure in two-phase systems. However, our preliminary tests using the hydrophobic ceramic cups installed in highly wet soil showed that under conditions of fast drainage of the wetting fluid that is replaced by air, it typically took some time before the cups responded to register the air pressure. Therefore, an attempt was made to develop a more robust method where the time lag is minimized. The tested materials were; 1) ceramic porous cups, 2) sintered stainless steel cups, 3) porous glass discs, and 4) non-woven PTFE fabric. The ceramic cups, sintered stainless steel cups and sintered porous glass discs required hydrophobic treatment, whereas the non-woven PTFE fabric is hydrophobic by itself. To treat the ceramic porous cups, the method proposed by Parker and Lenhard [1988] was adopted. The sintered porous stainless steel cups and porous glass discs were treated by a commercially available water repellant compound. For those four materials, contact angle, water entry pressure, and time lag to respond to an imposed pressure were measured. The best performing material was then tested in a simple heterogeneous column. The column was packed using two sands to form three layers where the coarser sand was sandwitched by two layers of a finer sand. In each layer, soil moisture, water pressure and air pressure were monitored. The soil was initially saturated and suction at the bottom was gradually increased to induce wetting fluid drainage, and followed by a wetting cycle. In the drainage cycle, the coarse middle layer did not drain until air front reached the bottom of the top fine layer. Once the air front reached the fine-coarse interface, air was quickly pulled into the coarse layer. The results showed that the newly developed hydrophobic material showed very small time lag and captured the abrupt air pressure change in the wet soil. In the wetting cycle, we observed positive air pressure which indicated entrapment of air and its compression as wetting proceeded. This behavior cannot be evaluated properly without the rapid measurement of air pressure. The method is currently being applied in a large 2D vertical aquifer with a structured heterogeneity to investigate how air pathways are formed under various flux/temperature conditions at the soil surface.

  3. Predictions of High Strain Rate Failure Modes in Layered Aluminum Composites

    NASA Astrophysics Data System (ADS)

    Khanikar, Prasenjit; Zikry, M. A.

    2014-01-01

    A dislocation density-based crystalline plasticity formulation, specialized finite-element techniques, and rational crystallographic orientation relations were used to predict and characterize the failure modes associated with the high strain rate behavior of aluminum layered composites. Two alloy layers, a high strength alloy, aluminum 2195, and an aluminum alloy 2139, with high toughness, were modeled with representative microstructures that included precipitates, dispersed particles, and different grain boundary distributions. Different layer arrangements were investigated for high strain rate applications and the optimal arrangement was with the high toughness 2139 layer on the bottom, which provided extensive shear strain localization, and the high strength 2195 layer on the top for high strength resistance The layer thickness of the bottom high toughness layer also affected the bending behavior of the roll-bonded interface and the potential delamination of the layers. Shear strain localization, dynamic cracking, and delamination are the mutually competing failure mechanisms for the layered metallic composite, and control of these failure modes can be used to optimize behavior for high strain rate applications.

  4. A Physical Mechanism for the Asymmetry in Top-Down and Bottom-Up Diffusion.

    NASA Astrophysics Data System (ADS)

    Wyngaard, J. C.

    1987-04-01

    Recent large-eddy simulations of the vertical diffusion of a passive, conservative scalar through the convective boundary layer (CBL) show strikingly different eddy diffusivity profiles in the `top-down' and `bottom-up' cases. These results indicate that for a given turbulent velocity field and associated scalar flux, the mean change in scalar mixing ratio across the CBL is several times larger if the flux originates at the top of the boundary layer (i.e., in top-down diffusion) rather than at the bottom. The large-eddy simulation (LES) data show that this asymmetry is due to a breakdown of the eddy-diffusion concept.A simple updraft-downdraft model of the CBL reveals a physical mechanism that could cause this unexpected behavior. The large, positive skewness of the convectively driven vertical velocity gives an appreciably higher probability of downdrafts than updrafts; this excess probability of downdrafts, interacting with the time changes of the mean mixing ratio caused by the nonstationarity of the bottom-up and top-down diffusion processes, decreases the equilibrium value of mean mixing-ratio jump across the mixed layer in the bottom-up case and increases it in the top-down case. The resulting diffusion asymmetry agrees qualitatively with that found through LES.

  5. Barite, BIFs and bugs: evidence for the evolution of the Earth's early hydrosphere

    NASA Astrophysics Data System (ADS)

    Huston, David L.; Logan, Graham A.

    2004-03-01

    The presence of relatively abundant bedded sulfate deposits before 3.2 Ga and after 1.8 Ga, the peak in iron formation abundance between 3.2 and 1.8 Ga, and the aqueous geochemistry of sulfur and iron together suggest that the redox state and the abundances of sulfur and iron in the hydrosphere varied widely during the Archean and Proterozoic. We propose a layered hydrosphere prior to 3.2 Ga in which sulfate produced by atmospheric photolytic reactions was enriched in an upper layer, whereas the underlying layer was reduced and sulfur-poor. Between 3.2 and 2.4 Ga, sulfate reduction removed sulfate from the upper layer, producing broadly uniform, reduced, sulfur-poor and iron-rich oceans. As a result of increasing atmospheric oxygenation around 2.4 Ga, the flux of sulfate into the hydrosphere by oxidative weathering was greatly enhanced, producing layered oceans, with sulfate-enriched, iron-poor surface waters and reduced, sulfur-poor and iron-rich bottom waters. The rate at which this process proceeded varied between basins depending on the size and local environment of the basin. By 1.8 Ga, the hydrosphere was relatively sulfate-rich and iron-poor throughout. Variations in sulfur and iron abundances suggest that the redox state of the oceans was buffered by iron before 2.4 Ga and by sulfur after 1.8 Ga.

  6. Bio-Inspired Aquaporinz Containing Double-Skinned Forward Osmosis Membrane Synthesized through Layer-by-Layer Assembly

    PubMed Central

    Wang, Shuzheng; Cai, Jin; Ding, Wande; Xu, Zhinan; Wang, Zhining

    2015-01-01

    We demonstrated a novel AquaporinZ (AqpZ)-incorporated double-skinned forward osmosis (FO) membrane by layer-by-layer (LbL) assembly strategy. Positively charged poly(ethyleneimine) (PEI) and negatively charged poly(sodium 4-styrenesulfonate) (PSS) were alternately deposited on both the top and bottom surfaces of a hydrolyzed polyacrylonitrile (H-PAN) substrate. Subsequently, an AqpZ-embedded 1,2-dioleloyl-sn-glycero-3-phosphocholine (DOPC)/1,2-dioleoyl-3-trimethylammonium- propane (chloride salt) (DOTAP) supported lipid bilayer (SLB) was formed on PSS-terminated (T-PSS) membrane via vesicle rupture method. The morphology and structure of the biomimetic membranes were characterized by in situ atomic force microscopy (AFM), scanning electron microscope (SEM), Fourier transform infrared spectrometer using the attenuated total reflection technique (ATR-FTIR), and contact angle. Moreover, the FO performance of the resultant membrane was measured by using 2 M MgCl2 solution as draw solution and deionized (DI) water as feed solution, respectively. The membrane with a protein-to-lipid weight ratio (P/L) of 1/50 exhibits 13.2 L/m2h water flux and 3.2 g/m2h reversed flux by using FO mode, as well as 15.6 L/m2h water flux and 3.4 L/m2h reversed flux for PRO mode (the draw solution is placed against the active layer). It was also shown that the SLB layer of the double-skinned FO membrane can increase the surface hydrophilicity and reduce the surface roughness, which leads to an improved anti-fouling performance against humic acid foulant. The current work introduced a new method of fabricating high performance biomimetic FO membrane by combining AqpZ and a double-skinned structure based on LbL assembly. PMID:26266426

  7. Rapid fluctuations in the northern Baltic Sea H2S layer

    NASA Astrophysics Data System (ADS)

    Kankaanpää, Harri T.; Virtasalo, Joonas J.

    2017-12-01

    Hydrogen sulfide (H2S) is linked to water quality deterioration in the Baltic Sea, with widespread seafloor hypoxia. We examined the vertical and temporal variability of in situ [H2S], oxygen concentration ([O2]), temperature (T) and pH at weekly, hourly and minute intervals at 13 locations in the western Gulf of Finland in 2013-2014. The main target was the 60-100 m water depth range, containing 3.2-290 μM O2 and 6.3-22.6 μM H2S. Where gas was detected by acoustic surveys, the structure of the H2S layer was more complex compared to stations devoid of gas. Local minima and maxima in pH frequently occurred near the H2S upper boundary (redox transition zone). Except for the homogeneous, tranquil zone above the seafloor at some stations, substantial rapid changes in hydrographic conditions were common. Typically, a layer of marked temporal T variability was present atop or within the topmost H2S layers. The largest temporal changes over a weekly period were - 0.44 °C/- 10.8 μM H2S/- 0.12 pH units (at seafloor level), + 0.18 °C/+7.9 μM H2S between casts (1 h) and + 0.03 °C/- 2.5 μM H2S per minute (high resolution logging). Abrupt [H2S] changes were recorded at two stations with sediments containing free gas. The T and [H2S] changes were synchronous at several layers, reflecting water movement. We conclude that rapid changes occur in hydrographic conditions in the near-bottom H2S layer in the northern Baltic Sea, especially at locations where free gas is present in the underlying sediments.

  8. The formation of Greenland Sea Deep Water: double diffusion or deep convection?

    NASA Astrophysics Data System (ADS)

    Clarke, R. Allyn; Swift, James H.; Reid, Joseph L.; Koltermann, K. Peter

    1990-09-01

    An examination of the extensive hydrographic data sets collected by C.S.S. Hudson and F.S. Meteor in the Norwegian and Greenland Seas during February-June 1982 reveals property distributions and circulation patterns broadly similar to those seen in earlier data sets. These data sets, however, reveal the even stronger role played by topography, with evidence of separate circulation patterns and separate water masses in each of the deep basins. The high precision temperature, salinity and oxygen data obtained reveals significant differences in the deep and bottom waters found in the various basins of the Norwegian and Greenland Seas. A comparison of the 1982 data set with earlier sets shows that the renewal of Greenland Sea Deep Water must have taken place sometime over the last decade; however there is no evidence that deep convective renewal of any of the deep and bottom waters in this region was taking place at the time of the observations. The large-scale density fields, however, do suggest that deep convection to the bottom is most likely to occure in the Greenland Basin due to its deep cyclonic circulation. The hypothesis that Greenland Sea Deep Water (GSDW) is formed through dipycnal mixing processes acting on the warm salty core of Atlantic Water entering the Greenland Sea is examined. θ-S correlations and oxygen concentrations suggest that the salinity maxima in the Greenland Sea are the product of at least two separate mixing processes, not the hypothesized single mixing process leading to GSDW. A simple one-dimensional mixed layer model with ice growth and decay demonstrates that convective renewal of GSDW would have occurred within the Greenland Sea had the winter been a little more severe. The new GSDW produced would have only 0.003 less salt and less than 0.04 ml 1 -1 greater oxygen concentration than that already in the basin. Consequently, detection of whether new deep water has been produced following a winter cooling season could be difficult even with the best of modern accuracy.

  9. Mixing regime of the residual water basins of the Aral Sea

    NASA Astrophysics Data System (ADS)

    Izhitskiy, Alexander; Zavialov, Peter; Kirillin, Georgiy

    2017-04-01

    The Aral Sea, a terminal salt lake in western Central Asia situated at the border between Uzbekistan and Kazakhstan, was ranked as the fourth largest inland water body in the mid-20th century. However, in the early 1960s, the lake's volume started to decrease rapidly due to severe changes in the Aral's water balance. Thus, the present-day Aral Sea can be considered as a system of separate water bodies with a common origin but very different physical, chemical and biological features. Our previous studies showed that the Large Aral Sea and Lake Tshchebas transformed into hyperhaline water bodies, while the Small Aral Sea was a brackish basin with rather similar to the pre-desiccation environment. On the other hand, the Small Aral Sea and Lake Tshchebas exhibited a mixed vertical structure, whereas the Western Large Aral Sea (especially the Chernyshev Bay) was strongly stratified. The presented study is focused on the seasonal mixing regimes of the residual basins. Isolation of deep waters from the atmosphere together with low rates of photosynthesis produce deep anoxia observed in the Chernyshev Bay and in the Large Aral. The high amount of organic matter provides a rich source of nutrients for anoxic microorganisms favoring methanogenesis in the bottom layer of the basins. In the Small Aral, the water column remains well-oxygenated down to the bottom throughout most of the year and development of anoxia is unlikely. The mixing regimes of the recently formed residual lakes of the former Aral Sea will provide manifold effect on the ongoing development of the aquatic system in the following decades. The study is based on a field data collected during two surveys of Shirshov Institute of Oceanology to the Aral Sea, which took place in October, 2015 and June, 2016. In situ measurements including CTD profiling and water sampling were carried out in the northern extremity of the western Large Aral (the Chernyshev Bay), in Lake Tshchebas, and in the Small Aral Sea. Moreover, two thermistor chains equipped with the dissolved oxygen loggers and bottom current meters were installed in the Chernyshev Bay for the period between two surveys.

  10. Modification of deep waters in Marguerite Bay, western Antarctic Peninsula, caused by topographic overflows

    NASA Astrophysics Data System (ADS)

    Venables, Hugh J.; Meredith, Michael P.; Brearley, J. Alexander

    2017-05-01

    Circumpolar Deep Water (CDW) intrudes from the mid-layers of the Antarctic Circumpolar Current onto the shelf of the western Antarctic Peninsula, providing a source of heat and nutrients to the regional ocean. It is well known that CDW is modified as it flows across the shelf, but the mechanisms responsible for this are not fully known. Here, data from underwater gliders with high spatial resolution are used to demonstrate the importance of detailed bathymetry in inducing multiple local mixing events. Clear evidence for overflows is observed in the glider data as water flows along a deep channel with multiple transverse ridges. The ridges block the densest waters, with overflowing water descending several hundred metres to fill subsequent basins. This vertical flow leads to entrainment of overlying colder and fresher water in localised mixing events. Initially this process leads to an increase in bottom temperatures due to the temperature maximum waters descending to greater depths. After several ridges, however, the mixing is sufficient to remove the temperature maximum completely and the entrainment of colder thermocline waters to depth reduces the bottom temperature, to approximately the same as in the source region of Marguerite Trough. Similarly, it is shown that deep waters of Palmer Deep are warmer than at the same depth at the shelf break. The exact details of the transformations observed are heavily dependent on the local bathymetry and water column structure, but glacially-carved troughs and shallow sills are a common feature of the bathymetry of polar shelves, and these types of processes may be a factor in determining the hydrographic conditions close to the coast across a wider area.

  11. Phylogenetic composition and distribution of picoeukaryotes in the hypoxic northwestern coast of the Gulf of Mexico

    PubMed Central

    Rocke, Emma; Jing, Hongmei; Liu, Hongbin

    2013-01-01

    Coastal marine hypoxic, or low-oxygen, episodes are an increasing worldwide phenomenon, but its effect on the microbial community is virtually unknown by far. In this study, the community structure and phylogeny of picoeukaryotes in the Gulf of Mexico, which are exposed to severe hypoxia in these areas was explored through a clone library approach. Both oxic surface waters and suboxic bottom waters were collected in August 2010 from three representative stations on the inner Louisiana shelf near the Atchafalaya and Mississippi River plumes. The bottom waters of the two more western stations were much more hypoxic in comparison to those of the station closest to the Mississippi River plume, which were only moderately hypoxic. A phylogenetic analysis of a total 175 sequences, generated from six 18S rDNA clone libraries, demonstrated a clear dominance of parasitic dinoflagellates from Marine alveolate clades I and II in all hypoxic waters as well as in the surface layer at the more western station closest to the Atchafalaya River plume. Species diversity was significantly higher at the most hypoxic sites, and many novel species were present among the dinoflagellate and stramenopile clades. We concluded that hypoxia in the Gulf of Mexico causes a significant shift in picoeukaryote communities, and that hypoxia may cause a shift in microbial food webs from grazing to parasitism. PMID:23281331

  12. Variability of bed drag on cohesive beds under wave action

    USGS Publications Warehouse

    Safak, Ilgar

    2016-01-01

    Drag force at the bed acting on water flow is a major control on water circulation and sediment transport. Bed drag has been thoroughly studied in sandy waters, but less so in muddy coastal waters. The variation of bed drag on a muddy shelf is investigated here using field observations of currents, waves, and sediment concentration collected during moderate wind and wave events. To estimate bottom shear stress and the bed drag coefficient, an indirect empirical method of logarithmic fitting to current velocity profiles (log-law), a bottom boundary layer model for combined wave-current flow, and a direct method that uses turbulent fluctuations of velocity are used. The overestimation by the log-law is significantly reduced by taking turbulence suppression due to sediment-induced stratification into account. The best agreement between the model and the direct estimates is obtained by using a hydraulic roughness of 10 -4">−4 m in the model. Direct estimate of bed drag on the muddy bed is found to have a decreasing trend with increasing current speed, and is estimated to be around 0.0025 in conditions where wave-induced flow is relatively weak. Bed drag shows an increase (up to fourfold) with increasing wave energy. These findings can be used to test the bed drag parameterizations in hydrodynamic and sediment transport models and the skills of these models in predicting flows in muddy environments.

  13. Optimum concentration gradient of the electrocatalyst, Nafion® and poly(tetrafluoroethylene) in a membrane-electrode-assembly for enhanced performance of direct methanol fuel cells.

    PubMed

    Liu, Jing Hua; Jeon, Min Ku; Lee, Ki Rak; Woo, Seong Ihl

    2010-12-14

    A combinatorial library of membrane-electrode-assemblies (MEAs) which consisted of 27 different compositions was fabricated to optimize the multilayer structure of direct methanol fuel cells. Each spot consisted of three layers of ink and a gradient was generated by employing different concentrations of the three components (Pt catalyst, Nafion® and polytetrafluoroethylene (PTFE)) of each layer. For quick evaluation of the library, a high-throughput optical screening technique was employed for methanol electro-oxidation reaction (MOR) activity. The screening results revealed that gradient layers could lead to higher MOR activity than uniform layers. It was found that the MOR activity was higher when the concentrations of Pt catalyst and Nafion ionomer decreased downward from the top layer to the bottom layer. On the other hand, higher MOR activity was observed when PTFE concentration increased downward from the top to the bottom layer.

  14. Quality of water and chemistry of bottom sediment in the Rillito Creek basin, Tucson, Arizona, 1986-92

    USGS Publications Warehouse

    Tadayon, Saeid; Smith, C.F.

    1994-01-01

    Data were collected on physical properties and chemistry of 4 surface water, l4 ground water, and 4 bottom sediment sites in the Rillito Creek basin where artificial recharge of surface runoff is being considered. Concentrations of suspended sediment in streams generally increased with increases in streamflow and were higher during the summer. The surface water is a calcium and bicarbonate type, and the ground water is calcium sodium and bicarbonate type. Total trace ek=nents in surface water that exceeded the U.S. Environmental Protection Agency primary maximum contaminant levels for drinking-water standards were barium, beryllium, cadmium, chromium, lead, mercury and nickel. Most unfiltered samples for suspended gross alpha as uranium, and unadjusted gross alpha plus gross beta in surface water exceeded the U.S. Environmental Protection Agency and the State of Arizona drinking-water standards. Comparisons of trace- element concentrations in bottom sediment with those in soils of the western conterminous United States generally indicate similar concentrations for most of the trace elements, with the exceptions of scandium and tin. The maximum concentration of total nitrite plus nitrate as nitrogen in three ground- samples and total lead in one ground-water sample exceeded U.S. Environmental Protection Agency primary maximum contaminant levels for drinking- water standards, respectively. Seven organochlorine pesticides were detected in surface-water samples and nine in bottom-sediment samples. Three priority pollutants were detected in surface water, two were detected in ground water, and eleven were detected in bottom sediment. Low concentrations of oil and grease were detected in surface-water and bottom- sediment samples.

  15. Constraints on Thermochemical Convection of the Mantle from Plume-related Observations

    NASA Astrophysics Data System (ADS)

    Zhong, S.

    2005-05-01

    Although geochemical observations have long suggested a layered mantle with more enriched mantle material in the bottom layer to provide a significant amount of heat to the top layer, the nature of such a layering remains unclear. An important observation that has been used to argue against the conventional layered mantle model (i.e., the layering at the 670 km depth) was the plume heat flux [Davies, 1999]. Plume heat flux is estimated as ~ 3.5 TW, or 10% of the surface heat flux [Davies, 1988; Sleep, 1990]. In this study, we demonstrate with 3-D spherical models of mantle convection with depth- and temperature-dependent viscosity that observed plume heat flux, plume excess temperature (<350°C), and upper mantle temperature (~ 1300°C) can pose important constraints on the layered mantle convection. We show that for a purely thermal convection model (i.e., a whole mantle convection), the observations of plume heat flux, plume excess temperature, and upper mantle temperature can be simultaneously explained only when internal heating rate is about 65%. For smaller internal heating rate, plume heat flux and plume excess temperature would be too large, and upper mantle temperature would be too small, compared with the observed. This suggests that for a whole mantle convection the CMB heat flux needs to be > 10 TW. For a core with no significant heat producing elements, such large CMB heat flux may lead to too rapid cooling of the core or a too young inner core. A layered mantle convection may help reduce the CMB heat flux. For layered convection models, we found that the top layer needs to be ~70% internally heated to explain the upper mantle temperature and plume-related observations, and this required internal heating ratio is insensitive to the layer thickness for the bottom layer (we used ~600 km and 1100 km thicknesses). This result suggests that heat generation rate for the bottom layer cannot be significantly larger (< a factor of 2) than that for the top layer. thus challenging the conventional geochemical inference for an significantly enriched bottom layer. However, this is more consistent with recent estimate of the MORB source composition that increases heat producing element concentration by a factor of three compared with the previously proposed.

  16. Physically-based distributed hydrologic modeling of tropical catchments: Hypothesis testing on model formation and runoff generation

    NASA Astrophysics Data System (ADS)

    Abebe, N. A.; Ogden, F. L.

    2011-12-01

    Watersheds vary in their nature based on their geographic location, altitude, climate, geology, soils, and land use/land cover. These variations lead to differences in the conceptualization and formulation of hydrological models intended to represent the expected hydrological processes in a given catchment. Watersheds in the tropics are characterized by intensive and persistent biological activity and a large amount of rainfall. Our study focuses on the Agua Salud project catchments located in the Panama Canal Watershed, Panama, which have steep rolling topography, deep soils derived from weathered bedrock, and limited exposed bedrock. These catchments are also highly affected by soil cracks, decayed tree roots and animal burrows that form a network of preferential flow paths. One hypothesis is that these macropores conduct interflow during heavy rainfall, when a transient perched water table forms at a depth where the vertical hydraulic conductivity is significantly reduced near the bottom of the bioturbation layer. We have developed a physics-based, spatially distributed, multi-layered hydrologic model to simulate the dominant flow processes, including overland flow, channel flow, vertical matrix and non-Richards film flow, lateral downslope saturated matrix and non-Darcian pipe flow in the bioturbation layer and deep saturated groundwater flow. In our model formulation, we use the model to examine a variety of hydrological processes which we anticipate may occur. Emphasis is given to the modeling of the soil moisture dynamics in the bioturbation layer, development of lateral preferential flow and activation of the macropores and exchange of water at the interface between a bioturbation layer and a second layer below it. We consider interactions between surface water, ground water, channel water and perched water in the riparian zone cells with the aim of understanding likely runoff generation mechanisms. Results show that inclusion of as many different flow processes as possible during conceptualization and during model development helps to reject infeasible scenarios/hypotheses, and suggests further watershed-scale studies to improve our understanding of the hydrologic behavior of these poorly understood catchments.

  17. Use of weathered and fresh bottom ash mix layers as a subbase in road constructions: environmental behavior enhancement by means of a retaining barrier.

    PubMed

    Del Valle-Zermeño, R; Chimenos, J M; Giró-Paloma, J; Formosa, J

    2014-12-01

    The presence of neoformed cement-like phases during the weathering of non-stabilized freshly quenched bottom ash favors the development of a bound pavement material with improved mechanical properties. Use of weathered and freshly quenched bottom ash mix layers placed one over the other allowed the retention of leached heavy metals and metalloids by means of a reactive percolation barrier. The addition of 50% of weathered bottom ash to the total subbase content diminished the release of toxic species to below environmental regulatory limits. The mechanisms of retention and the different processes and factors responsible of leaching strongly depended on the contaminant under concern as well as on the chemical and physical factors. Thus, the immediate reuse of freshly quenched bottom ash as a subbase material in road constructions is possible, as both the mechanical properties and long-term leachability are enhanced. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. Nanometre-thick single-crystalline nanosheets grown at the water-air interface

    NASA Astrophysics Data System (ADS)

    Wang, Fei; Seo, Jung-Hun; Luo, Guangfu; Starr, Matthew B.; Li, Zhaodong; Geng, Dalong; Yin, Xin; Wang, Shaoyang; Fraser, Douglas G.; Morgan, Dane; Ma, Zhenqiang; Wang, Xudong

    2016-01-01

    To date, the preparation of free-standing 2D nanomaterials has been largely limited to the exfoliation of van der Waals solids. The lack of a robust mechanism for the bottom-up synthesis of 2D nanomaterials from non-layered materials has become an obstacle to further explore the physical properties and advanced applications of 2D nanomaterials. Here we demonstrate that surfactant monolayers can serve as soft templates guiding the nucleation and growth of 2D nanomaterials in large area beyond the limitation of van der Waals solids. One- to 2-nm-thick, single-crystalline free-standing ZnO nanosheets with sizes up to tens of micrometres are synthesized at the water-air interface. In this process, the packing density of surfactant monolayers adapts to the sub-phase metal ions and guides the epitaxial growth of nanosheets. It is thus named adaptive ionic layer epitaxy (AILE). The electronic properties of ZnO nanosheets and AILE of other materials are also investigated.

  19. Sediment dynamics in the Adriatic Sea investigated with coupled models

    USGS Publications Warehouse

    Sherwood, Christopher R.; Book, Jeffrey W.; Carniel, Sandro; Cavaleri, Luigi; Chiggiato, Jacopo; Das, Himangshu; Doyle, James D.; Harris, Courtney K.; Niedoroda, Alan W.; Perkins, Henry; Poulain, Pierre-Marie; Pullen, Julie; Reed, Christopher W.; Russo, Aniello; Sclavo, Mauro; Signell, Richard P.; Traykovski, Peter A.; Warner, John C.

    2004-01-01

    Several large research programs focused on the Adriatic Sea in winter 2002-2003, making it an exciting place for sediment dynamics modelers (Figure 1). Investigations of atmospheric forcing and oceanic response (including wave generation and propagation, water-mass formation, stratification, and circulation), suspended material, bottom boundary layer dynamics, bottom sediment, and small-scale stratigraphy were performed by European and North American researchers participating in several projects. The goal of EuroSTRATAFORM researchers is to improve our ability to understand and simulate the physical processes that deliver sediment to the marine environment and generate stratigraphic signatures. Scientists involved in the Po and Apennine Sediment Transport and Accumulation (PASTA) experiment benefited from other major research programs including ACE (Adriatic Circulation Experiment), DOLCE VITA (Dynamics of Localized Currents and Eddy Variability in the Adriatic), EACE (the Croatian East Adriatic Circulation Experiment project), WISE (West Istria Experiment), and ADRICOSM (Italian nowcasting and forecasting) studies.

  20. Tempo and scale of biogenic effects on high-frequency acoustic propagation near the marine sediment-water interface in shallow water

    NASA Astrophysics Data System (ADS)

    Jumars, Peter

    2003-04-01

    Organisms have natural scales, such as lifetimes, body sizes, frequencies of movement to new locations, and residence times of material in digestive systems, and each scale has potential implications for acoustic effects. The effects of groups of organisms, like organisms themselves, aggregate in space and time. This review, including an assortment of unpublished information, examines examples of such aggregations, many of them documented acoustically. Light synchronizes many activities. Macroscopic animals forage primarily under cover of darkness. This phasing applies both to animals that extend appendages above the sediment-water interface and to animals that leave the seabed at night. Whereas their bottom-modifying activities are concentrated in nocturnal or crepuscular fashion, the bottom-modifying activities of the visual feeders follow a different phasing and often dominate the rate of change in acoustic backscatter from the interface. Light also acts through its effects on primary production, often concentrated in a very thin surficial layer atop the seabed. The supersaturation of oxygen does, and microbubble nucleation may, result. Where tidal velocities are large, light-set patterns are often tidally modulated. Activities of animals living below the seabed, however, remain a mystery, whose primary hope for solution is acoustic. [Work supported by ONR and DEPSCoR.

  1. Direct molecular diffusion and micro-mixing for rapid dewatering of LiBr solution

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bigham, S; Isfahani, RN; Moghaddam, S

    2014-03-01

    A slow molecular diffusion rate often limits the desorption process of an absorbate molecule from a liquid absorbent. To enhance the desorption rate, the absorbent is often boiled to increase the liquid vapor interfacial area. However, the growth of bubbles generated during the nucleate boiling process still remains mass-diffusion limited. Here, it is shown that a desorption rate higher than that of boiling can be achieved, if the vapor absorbent interface is continuously replenished with the absorbate-rich solution to limit the concentration boundary layer growth. The study is conducted in a LiBr-water-solution, in which the water molecules' diffusion rate ismore » quite slow. The manipulation of the vapor solution interface concentration distribution is enabled by the mechanical confinement of the solution flow within microchannels, using a hydrophobic vapor-venting membrane and the implementation of microstructures on the flow channel's bottom wall. The microstructures stretch and fold the laminar streamlines within the solution film and produce vortices. The vortices continuously replace the concentrated solution at the vapor solution interface with the water-rich solution brought from the bottom and middle of the flow channel. The physics of the process is described using a combination of experimental and numerical studies. Published by Elsevier Ltd.« less

  2. Sense Things in the Big Deep Water Bring the Big Deep Water to Computers so People can understand the Deep Water all the Time without getting wet

    NASA Astrophysics Data System (ADS)

    Pelz, M.; Heesemann, M.; Scherwath, M.; Owens, D.; Hoeberechts, M.; Moran, K.

    2015-12-01

    Senses help us learn stuff about the world. We put sense things in, over, and under the water to help people understand water, ice, rocks, life and changes over time out there in the big water. Sense things are like our eyes and ears. We can use them to look up and down, right and left all of the time. We can also use them on top of or near the water to see wind and waves. As the water gets deep, we can use our sense things to see many a layer of different water that make up the big water. On the big water we watch ice grow and then go away again. We think our sense things will help us know if this is different from normal, because it could be bad for people soon if it is not normal. Our sense things let us hear big water animals talking low (but sometimes high). We can also see animals that live at the bottom of the big water and we take lots of pictures of them. Lots of the animals we see are soft and small or hard and small, but sometimes the really big ones are seen too. We also use our sense things on the bottom and sometimes feel the ground shaking. Sometimes, we get little pockets of bad smelling air going up, too. In other areas of the bottom, we feel hot hot water coming out of the rock making new rocks and we watch some animals even make houses and food out of the hot hot water that turns to rock as it cools. To take care of the sense things we use and control water cars and smaller water cars that can dive deep in the water away from the bigger water car. We like to put new things in the water and take things out of the water that need to be fixed at least once a year. Sense things are very cool because you can use the sense things with your computer too. We share everything for free on our computers, which your computer talks to and gets pictures and sounds for you. Sharing the facts from the sense things is the best part about having the sense things because we can get many new ideas about understanding the big water from anyone with a computer!

  3. Dredging Operations Technical Support Program: Engineering Design and Environmental Assessment of Dredged Material Overflow from Hydraulically Filled Hopper Barges in Mobile Bay, Alabama

    DTIC Science & Technology

    1990-09-01

    turbid estuarine habitats such as Mobile Bay are very tolerant of moderately high concentrations of suspended sediments and thin layers of sediment...GULF OF MEXIC BAYOU 4M 2CAE SI2LTK Fiur 3. DsrbuinoAedmnTyesi oie a fo IsphordingLT anCLmb190 PART III: DREDGING EQUIPMENT AND OPERATIONAL TECHNIQUES...increase in ambient turbidity was noted. Water samples were collected at surface, middepth, and bottom. The sampling boats proceeded across their

  4. PP and PS interferometric images of near-seafloor sediments

    USGS Publications Warehouse

    Haines, S.S.

    2011-01-01

    I present interferometric processing examples from an ocean-bottom cable OBC dataset collected at a water depth of 800 m in the Gulf of Mexico. Virtual source and receiver gathers created through cross-correlation of full wavefields show clear PP reflections and PS conversions from near-seafloor layers of interest. Virtual gathers from wavefield-separated data show improved PP and PS arrivals. PP and PS brute stacks from the wavefield-separated data compare favorably with images from a non-interferometric processing flow. ?? 2011 Society of Exploration Geophysicists.

  5. The role of Argopecten purpuratus shells structuring the soft bottom community in shallow waters of southern Peru

    NASA Astrophysics Data System (ADS)

    Lomovasky, Betina J.; Gamero, Patricia A.; Romero, Leonardo; Firstater, Fausto N.; Gamarra Salazar, Alex; Hidalgo, Fernando; Tarazona, Juan; Iribarne, Oscar O.

    2015-12-01

    Accumulation of Argopecten purpuratus shells often occurs after El Niño events in shallow waters of Independencia Bay (14°17‧S-76°10‧W; Pisco, Peru). Here we experimentally investigate the effects of their shell accumulation on macrobenthos assemblages in soft bottom, shallow areas of the bay. A field experiment (from May 2006 to May 2007), including four treatments with different coverage levels of empty shells of A. purpuratus, were randomly arranged in: (1) areas devoid of shells ("Empty" treatment: experimental control), (2) 50% of the plot area covered with shells haphazardly distributed over the bottom ("medium" treatment), (3) 100% of the plot area covered with shells, forming a 10 cm valve layer ("full" treatment) and (4) "natural control". We found a total of 124 taxa throughout the experiment. Polychaetes, crustaceans and mollusks were the most abundant groups in "natural controls", dominated by the gastropod Nassarius gayi and the polychaetes Prionospio peruana, Platynereis bicanaliculata and Mediomastus branchiferus. The abundance of individuals (N) and the species richness (S) were higher in the "medium" treatment, but only in one month under positive sea bottom thermal anomalies. Similarity analysis (Bray-Curtis) showed that "natural control", "empty" and "full" treatments were more similar among them than the "medium" treatment. Multidimensional analysis showed no clear species association among treatments and a higher grouping among the samplings of Jun-06, Aug-06 and Nov-06. Our results also showed that the commercial crab Romaleon polyodon and the polyplacophora Tonicia elegans were positively affected by shell accumulations ("medium" treatment), while the limpet Fissurella crassa was negatively affected. Our study shows that directly by changing habitat structure or indirectly by changing sediment characteristics, the addition of scallop shells to the soft bottom can modify the macrobenthic assemblage; however, the seasonal oceanographic variability (e.g. upwelling, El Niño) could have stronger effects controlling this system than the presence of the shells itself.

  6. Laser induced forward transfer of graphene

    NASA Astrophysics Data System (ADS)

    Smits, Edsger C. P.; Walter, Arnaud; de Leeuw, Dago M.; Asadi, Kamal

    2017-10-01

    Transfer of graphene and other two-dimensional materials is still a technical challenge. The 2D-materials are typically patterned after transfer, which leads to a major loss of material. Here, we present laser induced forward transfer of chemical vapor deposition grown graphene layers with well-defined shapes and geometries. The transfer is based on photo-decomposition of a triazene-based transfer layer that produces N2 gas, which propels a graphene layer from the donor to the acceptor substrate. The functionality of the graphene-metal junction was verified by realizing functional bottom contact bottom gate field-effect transistors.

  7. Influence of anomalous temperature dependence of water density on convection at lateral heating

    NASA Astrophysics Data System (ADS)

    Bukreev, V. I.; Gusev, A. V.

    2012-12-01

    The article provides results of experimental investigation of a fresh water motion in a flume with limited dimensions at lateral heating. The initial water temperature in the flume ranged from 0 to 22 °C. It is shown that there are qualitative changes of the motion picture in the vicinity of initial temperature in the flume equal to the one at which water has maximal density (approximately 4 °C). At an initial temperature in the flume exceeding or equal to 4 °C, the heated water propagates in the form of a relatively thin surface jet, and at jet reflection from the flume end walls the heated water is accumulated only in the upper layer. When the initial temperature in the flume is below 4 °C the convective instability develops. A part of the heated water sinks to the bottom. The paper provides respective illustrations and quantitative data on the distribution of temperature and velocity.

  8. Bottom depth and type for shallow waters: Hyperspectral observations from a blimp

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, ZhongPing; Carder, K.; Steward, R.

    1997-08-01

    In a study of a blimp transect over Tampa Bay (Florida), hyperspectral upwelling radiance over the sand and seagrass bottoms was measured. These measurements were converted to hyperspectral remote-sensing reflectances. Using a shallow-water remote-sensing-reflectance model, in-water optical properties, bottom depths and bottom albedos were derived analytically and simultaneously by an optimization procedure. In the process, curvatures of sand and seagrass albedos were used. Also used was a model of absorption spectrum of phytoplankton pigments. The derived bottom depths were compared with bathymetry charts and found to agree well. This study suggests that a low-flying blimp is a useful platform formore » the study and mapping of coastal water environments. The optical model as well as the data-reduction procedure used are practical for the retrieval of shallow water optical properties.« less

  9. Reducing the contact resistance in bottom-contact-type organic field-effect transitors using an AgO x interface layer

    NASA Astrophysics Data System (ADS)

    Minagawa, Masahiro; Kim, Yeongin; Claus, Martin; Bao, Zhenan

    2017-09-01

    Bottom-contact organic field-effect transistors (OFETs) are prepared by inserting an AgO x layer between a pentacene layer and the source-drain electrodes. The contact resistance in the device is ˜8.1 kΩ·cm with an AgO x layer oxidized for 60 s but reaches 116.9 kΩ·cm with a non-oxidized Ag electrode. The drain current and mobility in the OFETs with the AgO x layer increase with the oxidization time and then gradually plateau, and this trend strongly depends on the work function of the Ag surface. Further, the hole injection is enhanced by the presence of Ag2O but inhibited by the presence of AgO.

  10. Observations of Seafloor Roughness in a Tidally Modulated Inlet

    NASA Astrophysics Data System (ADS)

    Lippmann, T. C.; Hunt, J.

    2014-12-01

    The vertical structure of shallow water flows are influenced by the presence of a bottom boundary layer, which spans the water column for long period waves or mean flows. The nature of the boundary is determined in part by the roughness elements that make up the seafloor, and includes sometimes complex undulations associated with regular and irregular shaped bedforms whose scales range several orders of magnitude from orbital wave ripples (10-1 m) to mega-ripples (100 m) and even larger features (101-103) such as sand waves, bars, and dunes. Modeling efforts often parameterize the effects of roughness elements on flow fields, depending on the complexity of the boundary layer formulations. The problem is exacerbated by the transient nature of bedforms and their large spatial extent and variability. This is particularly important in high flow areas with large sediment transport, such as tidally dominated sandy inlets like New River Inlet, NC. Quantification of small scale seafloor variability over large spatial areas requires the use of mobile platforms that can measure with fine scale (order cm) accuracy in wide swaths. The problem is difficult in shallow water where waves and currents are large, and water clarity is often limited. In this work, we present results from bathymetric surveys obtained with the Coastal Bathymetry Survey System, a personal watercraft equipped with a Imagenex multibeam acoustic echosounder and Applanix POS-MV 320 GPS-aided inertial measurement unit. This system is able to measure shallow water seafloor bathymetry and backscatter intensity with very fine scale (10-1 m) resolution and over relatively large scales (103 m) in the presence of high waves and currents. Wavenumber spectra show that the noise floor of the resolved multibeam bathymetry is on the order of 2.5 - 5 cm in amplitude, depending on water depths ranging 2 - 6 m, and about 30 cm in wavelength. Seafloor roughness elements are estimated from wavenumber spectra across the inlet from bathymetric maps of the seafloor obtained with 10-25 cm horizontal resolution. Implications of the effects of the bottom variability on the vertical structure of the currents will be discussed. This work was supported by ONR and NOAA.

  11. Controlled metal-semiconductor sintering/alloying by one-directional reverse illumination

    DOEpatents

    Sopori, Bhushan L.

    1993-01-01

    Metal strips deposited on a top surface of a semiconductor substrate are sintered at one temperature simultaneously with alloying a metal layer on the bottom surface at a second, higher temperature. This simultaneous sintering of metal strips and alloying a metal layer on opposite surfaces of the substrate at different temperatures is accomplished by directing infrared radiation through the top surface to the interface of the bottom surface with the metal layer where the radiation is absorbed to create a primary hot zone with a temperature high enough to melt and alloy the metal layer with the bottom surface of the substrate. Secondary heat effects, including heat conducted through the substrate from the primary hot zone and heat created by infrared radiation reflected from the metal layer to the metal strips, as well as heat created from some primary absorption by the metal strips, combine to create secondary hot zones at the interfaces of the metal strips with the top surface of the substrate. These secondary hot zones are not as hot as the primary hot zone, but they are hot enough to sinter the metal strips to the substrate.

  12. Improved electrical performance and bias stability of solution-processed active bilayer structure of indium zinc oxide based TFT.

    PubMed

    Seo, Jin-Suk; Bae, Byeong-Soo

    2014-09-10

    We fabricated active single- and bilayer structure thin film transistors (TFTs) with aluminum or gallium doped (IZO:Al or IZO:Ga) and undoped indium zinc oxide (IZO) thin film layers using an aqueous solution process. The electrical performance and bias stability of these active single- and bilayer structure TFTs were investigated and compared to reveal the effects of Al/Gal doping and bilayer structure. The single-layer structure IZO TFT shows a high mobility of 19 cm(2)/V · s with a poor positive bias stability (PBS) of ΔVT + 3.4 V. However, Al/Ga doped in IZO TFT reduced mobility to 8.5-9.9 cm(2)/V · s but improved PBS to ΔVT + 1.6-1.7 V due to the reduction of oxygen vacancy. Thus, it is found the bilayer structure TFTs with a combination of bottom- and top-layer compositions modify both the mobility and bias stability of the TFTs to be optimized. The bilayer structure TFT with an IZO:X bottom layer possess high mobility and an IZO bottom layer improves the PBS.

  13. 2D and 3D Ground Penetrating Radar monitoring of a reinforced concrete asphalt plate affected by mechanical deformation.

    NASA Astrophysics Data System (ADS)

    Bavusi, M.; Dumoulin, J.; Loperte, A.; Rizzo, E.; Soldovieri, F.

    2012-04-01

    The main facility of Hydrogeosite Laboratory of the Italian National Research Council (Marsico Nuovo, CNR) is a 3m x 7m x 10m reinforced concrete pool filled by siliceous sand designed for hydrologic experiments. One of its peculiarities is the possibility to vary the water table depth by using a proper hydraulic system [1]. In the framework of the FP7 ISTIMES project (Integrated System for Transport Infrastructure surveillance and Monitoring by Electromagnetic Sensing), a 3m x 3m layered structure has been purposely built and placed in the pool of the Hydrogeosite Laboratory with the aim to carry out a long term monitoring, by using jointly several electromagnetic sensing technologies, during two different phases simulating the rising of the water table and a mechanical solicitation. Several layers composed the structure from the top to the bottom, such as: 5 cm of asphalt; 5-10 cm of reinforced concrete; 20-25 cm of conglomerate, 55 cm of sand. Moreover, in the sand layer, three (metallic and plastic) pipes of different size were buried to simulate utilities. Ground Penetrating Radar (GPR) surveys were performed by using a the GSSI SIR 3000 system equipped with 400 MHz and 1500 MHz central frequency antennas. Surveys carried out by means of 400 MHz antenna allowed to detect and localize the three pipes (one in plastic and two in metal) and to investigate the effects of the sand water content on their radar signature. Surveys carried out by using 1500 MHz antenna were focused to characterize the shallower layers of the structure. The Hydrogeosite experiment consisted in following stages: • Arising of a water table by infiltration from the bottom; • Water gravity infiltration condescendingly; • Infiltration by peristaltic pump in the very shallow layers of the structure; • Water table drawdown; • Mechanical structure deformation; • Asphalt plate restoration after mechanical solicitation. After each stage a series of GPR surveys was performed. Moreover, a zero setting acquisition was carried out before perturbing the plate. Described experience demonstrates the GPR is a reliable technique for the: • foundation soil characterization and monitoring • Reinforced structural elements monitoring • asphalt/reinforced concrete characterization and monitoring • detection of water infiltration, structural elements, defects • evaluation of restoration intervention. In fact, the GPR technique was able to investigate the layers beyond the asphalt and provides a spatial resolution complying with the needs of the technical problem at hand by use of different antennas. Moreover noticeable performances of this technique can be further improved by implementing 3D processing and MT inversion procedures in order to increase the amount of information by the survey [2]. Acknowledgements. The research leading to these results has received funding from the European Community's Seventh Framework Programme (FP7/2007-2013) under Grant Agreement n. 225663 Joint Call FP7-ICT-SEC-2007-1 [1] Lapenna, V.; Cuomo, V.; Rizzo, E.; Fiore, S.; Troisi, S.; Straface, S. (2006). A new Large Lab-scale Facility for Hydro-Geophysical Experiments: Hydrogeosite. American Geophysical Union, Fall Meeting 2006, abstract #H31B-1422 [2] Bavusi M., Soldovieri F., Di Napoli R., Loperte A., Di Cesare A., Ponzo F.C and Lapenna V. (2011). Ground penetrating radar and microwave tomography 3D applications for the deck evaluation of the Musmeci bridge in Potenza, Italy. J. Geophys. Eng. 8 S33 doi:10.1088/1742-2132/8/3/S04

  14. Bio-physical changes in the coastal ocean triggered by typhoon: A case of Typhoon Meari in summer 2011

    NASA Astrophysics Data System (ADS)

    Wu, Xiao; Wang, Houjie; Bi, Naishuang; Song, Zhenjie; Zang, Zhengchen; Kineke, Gail C.

    2016-12-01

    Based on the combination of synchronous satellite and in-situ observations, we here, for the first time, provide the compelling evidence of bio-physical response of coastal environment in the Bohai Sea (China) to the passage of Typhoon Meari over the northern Yellow Sea on June 26, 2011. Strong sustained winds induced a tongue-like intrusion of cool water from the northern Yellow Sea into the Bohai Sea, resulting in significant surface cooling and an anomalous increase in sea surface height along the coast of the western Bohai Sea. This, in return, produced downwelling and transport of the warm and nutrient-rich coastal water from the western coast to the central Bohai Sea, as driven by the barotropic pressure gradient force. In-situ observational data confirmed the cooling of both surface and bottom layers with salinity increase; however, the measured temperature increase by 2-3 °C, concomitant salinity decrease by 0.3 PSU and two-fold increase in chlorophyll-a in the middle layers suggested an influence from coastal downwelling. Ekman transport and typhoon-enhanced mixing redistributed the nutrients and thus resulted in higher chlorophyll-a concentrations in the upper layers.

  15. A layered microchip conductance detector with through-layer access to detection fields and high sensitivity to dielectric constant.

    PubMed

    Suganuma, Y; Dhirani, A-A

    2011-04-01

    The present study explores a novel apertured microchip conductance detector (AMCD) that is sensitive to dielectric constant. Fashioned on silicon oxide/silicon using optical microlithography, the detector has novel parallel-plate geometry with a top mesh electrode, a middle apertured insulator, and a bottom conducting electrode. This monolithic apertured architecture is planar and may be provided with a thin insulator layer enabling large capacitances, while the top mesh electrode and middle apertured-insulator enable access to regions of the capacitor where electric fields are strong. Hence, the detector is sensitive yet mechanically robust. To test its response, the AMCD was immersed in various solvents, namely water, methanol, acetonitrile, and hexanes. Its response was found to vary in proportion to the solvents' respective dielectric constants. The AMCD was also able to distinguish quantitatively the presence of various molecules in solution, including molecules with chromophores [such as acetylsalicylic acid (ASA)] in methanol and those without chrompohores [such as polyethylene glycol 200 Daltons (PEG200)] in methanol or water. The universal nature of dielectric constant and the microchip detector's sensitivity point to a wide range of potential applications. © 2011 American Institute of Physics

  16. Investigating Mars: Candor Chasma

    NASA Image and Video Library

    2018-01-11

    This image shows part of eastern Candor Chasma. At the top of the image is the steep cliff between the upper surface elevation and the depths of Candor Chasma. The bottom of the image is the cliff side of a large mesa. The two cliff faces have very different appearances. The cliff face between the top of the canyon and the bottom is likely layers of volcanic flows from the nearby Tharsis volcanoes. The mesa, however, is probably layers of sediments deposited in the canyon from wind, water and gravity driven erosion and deposition. These layered materials are much more easily eroded than the solid rock of the canyon sides. Candor Chasma is one of the largest canyons that make up Valles Marineris. It is approximately 810 km long (503 miles) and has is divided into two regions - eastern and western Candor. Candor is located south of Ophir Chasma and north of Melas Chasma. The border with Melas Chasma contains many large landslide deposits. The floor of Candor Chasma includes a variety of landforms, including layered deposits, dunes, landslide deposits and steep sided cliffs and mesas. Many forms of erosion have shaped Chandor Chasma. There is evidence of wind and water erosion, as well as significant gravity driven mass wasting (landslides). The Odyssey spacecraft has spent over 15 years in orbit around Mars, circling the planet more than 69000 times. It holds the record for longest working spacecraft at Mars. THEMIS, the IR/VIS camera system, has collected data for the entire mission and provides images covering all seasons and lighting conditions. Over the years many features of interest have received repeated imaging, building up a suite of images covering the entire feature. From the deepest chasma to the tallest volcano, individual dunes inside craters and dune fields that encircle the north pole, channels carved by water and lava, and a variety of other feature, THEMIS has imaged them all. For the next several months the image of the day will focus on the Tharsis volcanoes, the various chasmata of Valles Marineris, and the major dunes fields. We hope you enjoy these images! Orbit Number: 9540 Latitude: -6.76471 Longitude: 292.539 Instrument: VIS Captured: 2004-02-07 20:41 https://photojournal.jpl.nasa.gov/catalog/PIA22163

  17. Quality of water and chemistry of bottom sediment in the Rillito Creek basin, Tucson, Arizona, 1992-93

    USGS Publications Warehouse

    Tadayon, Saeid

    1995-01-01

    Physical and chemical data were collected from four surface-water sites, six ground-water sites, and two bottom-sediment sites during 1992-93. Specific conductance, hardness, alkalinity, and dissolved- solids concentrations generally were higher in ground water than in surface water. The median concentrations of dissolved major ions, with the exception of potassium, were higher in ground water than in surface water. In surface water and ground water, calcium was the dominant cation, and bicarbonate was the dominant anion. Concentrations of dissolved nitrite and nitrite plus nitrate in surface water and ground water did not exceed the U.S. Environmental Protection Agency maximum contaminant levels of 1 and 10 milligrams per liter for drinking water, respectively. Ammonium plus organic nitrogen in bottom sediment was detected at the highest concentration of any nitrogen species. Median values for most of the dissolved trace elements in surface water and ground water were below the detection levels. Dissolved trace elements in surface water and ground water did not exceed the U.S. Environmental Protection Agency maximum contaminant levels for drinking water. Trace-element concentrations in bottom sediment were similar to trace-element concentrations reported for soils of the western conterminous United States. Several organochlorine pesticides and priority pollutants were detected in surface-water and bottom-sediment samples; however, they did not exceed water-quality standards. Pesticides or priority pollutants were not detected in ground-water samples.

  18. Hydrological Changes in the Arctic in Response to a Changing Climate

    NASA Astrophysics Data System (ADS)

    Hinzman, L. D.; Kane, D. L.; McNamara, J. P.; Nolan, M. A.; Romanovsky, V. E.; Yang, D.; Yoshikawa, K.

    2003-12-01

    The broadest impacts of climate change to the terrestrial arctic regions will result through consequent effects of changing permafrost structure and extent. As the climate differentially warms in summer and winter, the permafrost will become warmer, the active layer (the layer of soil above the permafrost that annually experiences freeze and thaw) will become thicker, the lower boundary of permafrost will become shallower and permafrost extent will decrease in area. These simple structural changes will affect every aspect of the surface water and energy balances. As the active layer thickens, there is greater storage capacity for soil moisture and greater lags and decays are introduced into the hydrologic response times to precipitation. When the frozen ground is very close to the surface, the stream and river discharge peaks are higher and the base flow is lower. As permafrost becomes thinner, there can be more connections between surface and subsurface water. As permafrost extent decreases, there is more infiltration to groundwater. This has significant impacts on large and small scales. The timing of stream runoff will change, reducing the percentage of continental runoff released during the summer and increasing the proportion of winter runoff. This is already becoming evident in Siberian Rivers. As permafrost becomes thinner and is reduced in spatial extent, the proportions of groundwater in stream runoff will increase as the proportion of surface runoff decreases, increasing river alkalinity and electrical conductivity. This could impact mixing of fresh and saline waters, formation of the halocline and seawater chemistry. Other important impacts will occur due to changing basin geomorphology. Currently the drainage networks in arctic watersheds are quite immature as compared to the more well-developed stream networks of temperate regions. These stream channels are essentially frozen in place as the major flood events (predominantly snowmelt) occur when the soils and streambeds are frozen solid. As the active layer becomes thicker, there could be significantly increased sediment loads delivered to the ocean. Presently, most small streams (<=ssim1,000 km2) in the Arctic are completely frozen from the bed to the surface when spring melt is initiated. However, in lower reaches of the rivers there are places where the channel is deep enough to prevent complete winter freezing. Break-up of the rivers differs dramatically in these places where the ice is not frozen fast to the bottom. Huge ice chunks are lifted by the flowing water, chewing up channels bottoms and sides and introducing massive sediments to the spring runoff.

  19. Eddy Effects in the General Circulation, Spanning Mean Currents, Mesoscale Eddies, and Topographic Generation, Including Submesoscale Nests

    DTIC Science & Technology

    2013-09-30

    bottom form stress (pressure force) and bottom boundary layers – all the aspects associated with turbulent flows over steep topography in the presence of...filaments, and eddies; topographic current separation, form stress , and submesoscale vortex generation; Our work on isoneutral diffusion for tracers...Bump region, are due to the contribution of the bottom stress curl. Fig. 4 shows how the Gulf Stream path is directly linked to the Bottom Pressure

  20. A model to determine open or closed cellular convection

    NASA Technical Reports Server (NTRS)

    Helfand, H. M.; Kalnay, E.

    1981-01-01

    A simple mechanism is proposed to explain the observed presence in the atmosphere of open or closed cellular convection. If convection is produced by cooling concentrated near the top of the cloud layer, as in radiative cooling of stratus clouds, it develops strong descending currents which are compensated by weak ascent over most of the horizontal area, and closed cells result. Conversely, heating concentrated near the bottom of a layer, as when an air mass is heated by warm water, results in strong ascending currents compensated by weak descent over most of the area, or open cells. This mechanism is similar to the one suggested by Stommel (1962) to explain the smallness of the oceans' sinking regions. The mechanism is studied numerically by means of a two-dimensional, nonlinear Boussinesq model.

  1. Evolution of Nonlinear Internal Waves in China Seas

    NASA Technical Reports Server (NTRS)

    Liu, Antony K.; Hsu, Ming-K.; Liang, Nai K.

    1997-01-01

    Synthetic Aperture Radar (SAR) images from ERS-I have been used to study the characteristics of internal waves of Taiwan in the East China Sea, and east of Hainan Island in the South China Sea. Rank-ordered packets of internal solitons propagating shoreward from the edge of the continental shelf were observed in the SAR images. Based on the assumption of a semidiurnal tidal origin, the wave speed can be estimated and is consistent with the internal wave theory. By using the SAR images and hydrographic data, internal waves of elevation have been identified in shallow water due to a thicker mixed layer as compared with the bottom layer on the continental shelf. The generation mechanism includes the influences of the tide and the Kuroshio intrusion across the continental shelf for the formations of elevation internal waves. The effects of water depth on the evolution of solitons and wave packets are modeled by nonlinear Kortweg-deVries (KdV) type equation and linked to satellite image observations. The numerical calculations of internal wave evolution on the continental shelf have been performed and compared with the SAR observations. For a case of depression waves in deep water, the solitons first disintegrate into dispersive wave trains and then evolve to a packet of elevation waves in the shallow water area after they pass through a turning point of approximately equal layer depths has been observed in the SAR image and simulated by numerical model.

  2. Directional optical transmission through a sand layer: a preliminary laboratory experiment

    NASA Astrophysics Data System (ADS)

    Tian, Jia; Philpot, William D.

    2017-10-01

    Given the importance of penetration of light in the soil for seed germination, soil warming, and the photolytic degradation of pesticides, directional transmission of thin sand samples are studied in this paper under both dry and saturated conditions. The detector views upward through a glass-bottom sample holder, filled to 3 or 4 mm with a coarse, translucent, quartz sand sample. Transmission through the samples was measured as the illumination zenith angle moved from 0 to 70° in 5° intervals. In the most cases, transmission decreased monotonically, but slowly with increasing illumination angle at all wavelengths. A peak in transmission only appeared at 0° illumination for the low bulk density, dry sample at 3 mm depth. The 0° peak disappeared when the sample was wetted, when the bulk density increased, or when the depth of the sample increased, which indicates that the radiation transmitting through a sand layer can be diffused thoroughly with a millimeters-thin sand layer. For the saturated samples, water influences light transmission in contrasting ways in shorter and longer wavelength. Transmission increased in the VNIR when saturated relative to dry, while transmission decreased sharply after 1300 nm, with spectral absorption features characteristic of water absorption. In VNIR region, water absorption is low and the low relative index of refraction enhanced transmission through sand sample. In contrast, water absorption became dominant at longer wavelengths region leading to the strongly reduced transmission.

  3. Cascaded Ga1-xAlxAs/GaAs solar cell with graded i-region

    NASA Astrophysics Data System (ADS)

    Mil'shtein, Sam; Halilov, Samed

    2018-02-01

    In current study we designed p-i-n junction with extended intrinsic layer, where linearly graded Alx Ga1-x As presents variable energy gap so needed for effective harvesting of sun radiation. The design realization involves two regions of compositional structure in the stacking direction. The top AlxGa1-xAs layer of 1 um total thickness has stoichiometric structure x=0.3-0.2d, where depth d runs from 0 to 1 um, topmost 200 nm of which is Be-doped. Bottom AlxGa1-xAs layer of 3 um total thickness has a variable composition of x=0.133-0.033d, d runs from 1 to 4 um, the very bottom of which with 10 nm thickness is Si-doped. On the top surface, there is a 50 nm layer of p+ doped GaAs as a spacer for growing AuGe/Ni anode electrode of 20% surface area, the bottom is coated with AuGe/Ni cathode electrode. The designed cell demonstrates 89% fill factor and 30% conversion efficiency without anti-reflection coating.

  4. Structure of Subsurface Sediments in the Scan Basin (Scotia Sea)

    NASA Astrophysics Data System (ADS)

    Schreider, Al. A.; Schreider, A. A.; Sazhneva, A. E.; Galindo-Zaldivar, J.; Ruano, P.; Maldonado, A.; Martos-Martin, Y.; Lobo, F.

    2018-01-01

    The structure of sediments in the Scotia Sea is used as a basis for reconstructing the geological history of its bottom in the Late Quaternary. The Scan Basin is one of the main elements of the topography of the southern Scotia Sea. Its formation played a considerable role in the fragmentation of the continent, which included the Bruce and Discovery banks. The main parameters of the sediment layer in the Scan Basin have been reconstructed by the present time, but its top part has not been studied. In this work, we analyze the first data obtained on the R/V Gesperidas with the use of a TOPAS PS 18/40 high-resolution seismic profilograph in 2012. Three layers in the subsurface sediments on the bottom of the Scan Basin were specified for the first time. The mean periods of their deposition in the Late Quaternary were determined as 115000 years for the first, 76000 years for the second, and 59 000 years for the third layer from the surface of the bottom. The duration of the total accumulation period of the three layers is about 250000 years.

  5. Warmer, deeper, and greener mixed layers in the North Atlantic subpolar gyre over the last 50 years.

    PubMed

    Martinez, Elodie; Raitsos, Dionysios E; Antoine, David

    2016-02-01

    Shifts in global climate resonate in plankton dynamics, biogeochemical cycles, and marine food webs. We studied these linkages in the North Atlantic subpolar gyre (NASG), which hosts extensive phytoplankton blooms. We show that phytoplankton abundance increased since the 1960s in parallel to a deepening of the mixed layer and a strengthening of winds and heat losses from the ocean, as driven by the low frequency of the North Atlantic Oscillation (NAO). In parallel to these bottom-up processes, the top-down control of phytoplankton by copepods decreased over the same time period in the western NASG, following sea surface temperature changes typical of the Atlantic Multi-decadal Oscillation (AMO). While previous studies have hypothesized that climate-driven warming would facilitate seasonal stratification of surface waters and long-term phytoplankton increase in subpolar regions, here we show that deeper mixed layers in the NASG can be warmer and host a higher phytoplankton biomass. These results emphasize that different modes of climate variability regulate bottom-up (NAO control) and top-down (AMO control) forcing on phytoplankton at decadal timescales. As a consequence, different relationships between phytoplankton, zooplankton, and their physical environment appear subject to the disparate temporal scale of the observations (seasonal, interannual, or decadal). The prediction of phytoplankton response to climate change should be built upon what is learnt from observations at the longest timescales. © 2015 John Wiley & Sons Ltd.

  6. Current status of emerging hypoxia in a eutrophic estuary: The lower reach of the Pearl River Estuary, China

    NASA Astrophysics Data System (ADS)

    Qian, Wei; Gan, Jianping; Liu, Jinwen; He, Biyan; Lu, Zhongming; Guo, Xianghui; Wang, Deli; Guo, Liguo; Huang, Tao; Dai, Minhan

    2018-05-01

    We examine the current status of dissolved oxygen (DO) and its trend over the past 25 years in the lower Pearl River Estuary, a large eutrophic estuary located in Southern China and surrounded by large cities including Hong Kong, Shenzhen and Guangzhou. Monthly cruises conducted from April 2010 to March 2011 clearly show that DO depletion began to emerge in the bottom layer of the lower estuary off Hong Kong in June, and became fully developed in July and August when oxygen-deficient water occupied ∼1000 km2 before gradually becoming re-oxygenated in September and October. The development of the low oxygen zone was closely coupled with phytoplankton blooms in the surface water, which was supersaturated with respect to DO suggesting the importance of autochthonous organic matter in fueling bottom DO consumption after settling through the pycnocline. Long-term monitoring data collected in the study area adjacent to Hong Kong by the Hong Kong Environmental Protection Department showed a decreasing trend of ∼2 ± 0.9 μmol kg-1 yr-1 in the annual minimum DO concentration in bottom water over the past 25 years. Associated with the decrease in DO was an increase in the annual maximum surface concentration of dissolved inorganic nitrogen (DIN) at a rate of ∼1.4 ± 0.3 μmol kg-1 yr-1, suggesting again that eutrophication is the most plausible driver of oxygen deficiency in this region. Therefore, our monthly cruises, along with the decadal monitoring data, reveal a large low oxygen zone, likely developing into a large hypoxic zone driven primarily by anthropogenic eutrophication. This new development suggests environmental stressors such as eutrophication may have a cascading effect, with important and expensive consequences for the regional environment.

  7. Geothermal heating in the Panama Basin and its impact on water mass transformation

    NASA Astrophysics Data System (ADS)

    Banyte, D.; Morales Maqueda, M. A.; Hobbs, R. W.; Megann, A.; Smeed, D.

    2017-12-01

    Geothermal heating is a driving force of abyssal water transformation. To quantify its impact at the basin scale, a hydrographic survey of the Panama Basin was carried out in 2014-2015 as part of the international project OSCAR (Oceanographic and Seismic Characterisation of heat dissipation and alteration by hydrothermal fluids at an Axial Ridge). The study shows that about half of the water entering the basin, which is connected to the Pacific Ocean only through the a narrow passage part of the Ecuador Trench, is converted to lighter water within just 200 km downstream of the passage. Of the resulting water, a staggering 90% is transformed by geothermal heating inside the basin, welling up into the ocean interior from a bottom boundary layer (BBL) that can be up to 1000 m thick. The geothermal forcing leaves an imprint in temperature-salinity properties hundreds of meters above the thick BBL. We present a conceptual model of the abyssal water transformation in the basin that incorporates these processes.

  8. Shubnikov-de Haas oscillations of high mobility holes in monolayer and bilayer WSe2: spin-valley locking, effective mass, and inter-layer coupling

    NASA Astrophysics Data System (ADS)

    Fallahazad, Babak; Movva, Hema Chandra Prakash; Kim, Kyounghwan; Larentis, Stefano; Taniguchi, Takashi; Watanabe, Kenji; Banerjee, Sanjay K.; Tutuc, Emanuel

    We study the magnetotransport properties of high mobility holes in monolayer and bilayer WSe2, measured in dual-gated samples with top and bottom hexagonal boron-nitride dielectrics, and using platinum bottom contacts. Thanks to the Pt high work-function combined with the a high hole density induced electrostatically by an applied top gate bias, the contacts remain ohmic down to low (1.5 K) temperatures. The samples display well defined Shubnikov-de Haas (SdH) oscillations, and quantum Hall states (QHS) in high magnetic fields. In both mono and bilayer WSe2, the SdH oscillations and the QHSs occur predominantly at even filling factors, evincing a two-fold Landau level degeneracy consistent with spin-valley locking. The Fourier transform analysis of the SdH oscillations in dual-gated bilayer WSe2 reveal the presence of two subbands, each localized in the top or the bottom layer, as well as negative compressibility. From the temperature dependence of the SdH oscillation amplitude we determine a hole effective mass of 0.45me for both mono and bilayer WSe2. The top and bottom layer densities can be independently tuned using the top and bottom gates, respectively, evincing a weak interlayer coupling. This work has been supported by NRI-SWAN and Intel corporation.

  9. Characterization and Fate of Dissolved Organic Matter in the Lena Delta Region, Siberia

    NASA Astrophysics Data System (ADS)

    Goncalves-Araujo, R.; Stedmon, C. A.; Heim, B.; Dubinenkov, I.; Kraberg, A.; Moiseev, D.; Bracher, A.

    2016-02-01

    Connectivity between the terrestrial and marine environment in the Artic is changing as a result of climate change, influencing both freshwater budgets and the supply of carbon to the sea. This study characterizes the optical properties of dissolved organic matter (DOM) within the Lena Delta region and evaluates the behavior of DOM across the fresh water-marine gradient. Six fluorescent components (four humic-like; one marine humic-like; one protein-like) were identified by Parallel Factor Analysis (PARAFAC) with a clear dominance of allochthonous humic-like signals. Colored DOM (CDOM) and dissolved organic carbon (DOC) were highly correlated and had their distribution coupled with hydrographical conditions. Higher DOM concentration and degree of humification were associated with the low salinity waters of the Lena River. Values decreased towards the higher salinity Laptev Sea shelf waters. Results demonstrate different responses of DOM mixing in relation to the vertical structure of the water column, as reflecting the hydrographical dynamics in the region. Two mixing curves for DOM were apparent. In surface waters above the pycnocline there was a sharper decrease in DOM concentration in relation to salinity indicating removal. In the bottom water layer the DOM decrease within salinity was less. We propose there is a removal of DOM occurring primarily at the surface layer, which is likely driven by photodegradation and flocculation.

  10. Characteristics of Airborne Lidar Profiles of the Arctic Ocean

    NASA Astrophysics Data System (ADS)

    Churnside, J. H.; Marchbanks, R.

    2016-02-01

    In July, 2014, we flew the NOAA oceanographic lidar more than 6000 km over the Chukchi and Beaufort Seas around northern Alaska. The most obvious feature in the lidar returns was sea ice, which blocked any return from below and saturated our receivers. The flights were designed to measure profiles with varying degrees of ice cover, from open water to nearly completely covered water. Thin phytoplankton layers were also prevalent, both in open water and within the pack ice. These layers were generally deeper (20 m vs. 16 m averages) and stronger (27 times the background level vs. 9 times) in open water than in the ice. The average layer thicknesses were similar in open water and in the ice (3.8 m vs. 3.4 m). The diffuse attenuation coefficient measured by the lidar did not depend strongly on ice cover. It was generally higher near the coast than farther off shore. Fish were present in a few of the returns, but these were not very numerous. More common were the sediment plumes generated by gray whales feeding on crustaceans on the bottom. Data from these flights show a high level of spatial variability that is difficult to measure from a surface vessel and significant vertical structure that is impossible to obtain from satellite ocean-color instruments. One application of this type of lidar data is to estimate primary productivity in the Arctic Ocean. It is clear that productivity is increasing, largely as a result of decreased ice cover, but many details remain uncertain.

  11. Thermohaline variability in the Adriatic and Northern Ionian Seas observed from the Argo floats during 2010-2014

    NASA Astrophysics Data System (ADS)

    Kovačević, Vedrana; Ursella, Laura; Gačić, Miroslav; Notarstefano, Giulio; Menna, Milena; Bensi, Manuel; Civitarese, Giuseppe; Poulain, Pierre-Marie

    2015-04-01

    The Adriatic Sea is the northernmost basin of the Eastern Mediterranean Sea (EMed). At its southern end, the basin communicates with the adjacent Ionian Sea through the 80 km wide and 850 m deep Strait of Otranto. Due to the river discharge in the north and due to the strong winter cooling, the Adriatic is both a dilution basin and the dense water formation region. The basin-wide circulation is cyclonic. The circulation is however, energetic also at smaller spatial and temporal scales, and several circulation cells and mesoscale features are regularly observed equally along the littoral and in the open sea. The North Adriatic Dense Water (NAdDW) formed during winter is the densest water of the whole Mediterranean Sea (up to 1060 kg/m3). It flows as a density driven bottom current from the northern shelf toward south, filling the deep layers of the middle and southern Adriatic pits. The deep open-sea area of the South Adriatic Pit (SAP, 1200 m) feels the influence of a water mass exchange through the Strait of Otranto. Specifically, it receives salty and warm surface and Levantine Intermediate Waters from the Ionian Sea. Through the open-sea winter convection that homogenizes and ventilates 400-800 m thick upper water column, this salty water contributes to the formation of the Adriatic Deep Water (AdDW, 1029.17-1029.20 kg/m3), which is not as dense as the NAdDW. Both dense waters eventually mix and spill across the sill ventilating the deep and bottom layers of the Ionian Sea, and driving the deep thermohaline cell of the EMed. Thermohaline properties of the Adriatic Sea vary at wide spatial and temporal scales, and this in turn affects the properties of its dense waters. The long-term scales are of a particular interest, as they are often associated with the biogeochemical and biotic variability such as intrusion of alien species into the Adriatic Sea and interconnection with the adjacent Ionian basin. Due to the extremely variable meteo- and climatic conditions, the signal of the Adriatic dense waters can be fairly irregular and impulsive. Sporadic in-situ surveys by research vessels are not always sufficient to capture this irregularity and its consequences on the circulation. The Lagrangian platforms are disseminated within the whole Mediterranean through the international Argo program. They are a useful tool to assess some of the spatial and temporal variability in the two basins. Combining the information from the floats and in-situ CTD profiles from oceanographic campaigns, we picture the inter-annual variability of the thermohaline properties in general during 2010-2014. In addition, the peculiarities of the very dense water overflow that during 2012 spilled out form the Strait of Otranto into the Northern Ionian is evidenced. Also, by the remotely sensed sea surface topography, we depict the most prominent circulation features of the upper layer.

  12. Comparison of vapor concentrations of volatile organic compounds with ground-water concentrations of selected contaminants in sediments beneath the Sudbury River, Ashland, Massachusetts, 2000

    USGS Publications Warehouse

    Campbell, J.P.; Lyford, F.P.; Willey, Richard E.

    2002-01-01

    A mixed plume of contaminants in ground water, including volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs), and metals, near the former Nyanza property in Ashland, Massachusetts, discharges to the Sudbury River upstream and downstream of Mill Pond and a former mill raceway. Polyethylene-membrane vapor-diffusion (PVD) samplers were installed in river-bottom sediments to determine if PVD samplers provide an alternative to ground-water sampling from well points for identifying areas of detectable concentrations of contaminants in sediment pore water near the ground-water and surface-water interface. In August and September 2000, the PVD samplers were installed near well points at depths of 8 to 12 inches in both fine and coarse sediments, whereas the well points were installed at depths of 1 to 5 feet in coarse sediments only. Comparison between vapor and water samples at 29 locations upstream from Mill Pond show that VOC vapor concentrations from PVD samplers in coarse river-bottom sediments are more likely to correspond to ground-water concentrations from well points than PVD samplers installed in fine sediments. Significant correlations based on Kendall's Tau were shown between vapor and ground-water concentrations for trichloroethylene and chlorobenzene for PVD samplers installed in coarse sediments where the fine organic layer that separated the two sampling depths was 1 foot or less in thickness. VOC concentrations from vapor samples also were compared to VOC, SVOC, and metals concentrations from ground-water samples at 10 well points installed upstream and downstream from Mill Pond, and in the former mill raceway. Chlorobenzene vapor concentrations correlated significantly with ground-water concentrations for 5 VOCs, 2 SVOCs, and 10 metals. Trichloroethylene vapor concentrations did not correlate with any of the other ground-water constituents analyzed at the 10 well points. Chlorobenzene detected by use of PVD samplers appears to be a strong indicator of the presence of VOCs, SVOCs, and metals in ground water sampled from well points at this site. Results from PVD samplers indicate that contaminant concentrations in water from well points installed 1 to 5 ft below fine sediments may not reflect concentrations in pore water less than 1 foot below the river bottom. There is insufficient information available to determine if VOC concentrations detected in PVD samplers are useful for identifying detectable aqueous concentrations of SVOCs and metals in sediment pore water at this site. Samples of pore water from a similar depth as PVD samplers are needed for confirmation of this objective.

  13. Integrated hydrologic and hydrodynamic modeling to assess water exchange in a data-scarce reservoir

    NASA Astrophysics Data System (ADS)

    Wu, Binbin; Wang, Guoqiang; Wang, Zhonggen; Liu, Changming; Ma, Jianming

    2017-12-01

    Integrated hydrologic and hydrodynamic modeling is useful in evaluating hydrodynamic characteristics (e.g. water exchange processes) in data-scarce water bodies, however, most studies lack verification of the hydrologic model. Here, water exchange (represented by water age) was investigated through integrated hydrologic and hydrodynamic modeling of the Hongfeng Reservoir, a poorly gauged reservoir in southwest China. The performance of the hydrologic model and parameter replacement among sub-basins with hydrological similarity was verified by historical data. Results showed that hydrological similarity based on the hierarchical cluster analysis and topographic index probability density distribution was reliable with satisfactory performance of parameter replacement. The hydrodynamic model was verified using daily water levels and water temperatures from 2009 and 2010. The water exchange processes in the Hongfeng Reservoir are very complex with temporal, vertical, and spatial variations. The temporal water age was primarily controlled by the variable inflow and outflow, and the maximum and minimum ages for the site near the dam were 406.10 d (15th June) and 90.74 d (3rd August), respectively, in 2010. Distinct vertical differences in water age showed that surface flow, interflow, and underflow appeared alternately, depending on the season and water depth. The worst water exchange situation was found in the central areas of the North Lake with the highest water ages in the bottom on both 15th June and 3rd August, in 2010. Comparison of the spatial water ages revealed that the more favorable hydraulic conditions on 3rd August mainly improved the water exchange in the dam areas and most areas of the South Lake, but had little effect on the bottom layers of the other deepest areas in the South and North Lakes. The presented framework can be applied in other data-scarce waterbodies worldwide to provide better understanding of water exchange processes.

  14. Circulation exchange patterns in Sinclair Inlet, Washington

    USGS Publications Warehouse

    Noble, Marlene A.; Rosenberger, Kurt J.; Paulson, Anthony J.; Gartner, Anne L.

    2013-01-01

    In 1994, the U.S. Geological Survey (USGS), in cooperation with the U.S. Navy, deployed three sets of moorings in Sinclair Inlet, which is a relatively small embayment on the western side of Puget Sound (fig. 1). This inlet is home to the Puget Sound Naval Shipyard. One purpose of the measurement program was to determine the transport pathways and fate of contaminants known to be present in Sinclair Inlet. Extensive descriptions of the program and the resultant information about contaminant pathways have been reported in Gartner and others (1998). This report primarily focused on the bottom boundary layer and the potential for resuspension and transport of sediments on the seabed in Sinclair Inlet as a result of tides and waves. Recently (2013), interest in transport pathways for suspended and dissolved materials in Sinclair Inlet has been rekindled. In particular, the USGS scientists in Washington and California have been asked to reexamine the datasets collected in the earlier study to refine not only our understanding of transport pathways through the inlet, but to determine how those transport pathways are affected by subtidal currents, local wind stress, and fresh water inputs. Because the prior study focused on the bottom boundary layer and not the water column, a reanalysis of the datasets could increase our understanding of the dynamic forces that drive transport within and through the inlet. However, the early datasets are limited in scope and a comprehensive understanding of these transport processes may require more extensive datasets or the development of a detailed numerical model of transport processes for the inlet, or both.

  15. Spatial variation of biogenic sulfur in the south Yellow Sea and the East China Sea during summer and its contribution to atmospheric sulfate aerosol.

    PubMed

    Zhang, Sheng-Hui; Yang, Gui-Peng; Zhang, Hong-Hai; Yang, Jian

    2014-08-01

    Spatial distributions of biogenic sulfur compounds including dimethylsulfide (DMS), dissolved and particulate dimethylsulfoniopropionate (DMSPd and DMSPp) were investigated in the South Yellow Sea (SYS) and the East China Sea (ECS) in July 2011. The concentrations of DMS and DMSPp were significantly correlated with the levels of chlorophyll a in the surface water. Simultaneously, relatively high ratio values of DMSP/chlorophyll a and DMS/chlorophyll a occurred in the areas where the phytoplankton community was dominated by dinoflagellates. The DMSPp and chlorophyll a size-fractionation showed that larger nanoplankton (5-20 μm) was the most important producer of DMSPp in the study area. The vertical profiles of DMS and DMSP were characterized by a maximum at the upper layer and the bottom concentrations were also relatively higher compared with the overlying layer of the bottom. In addition, a positive linear correlation was observed between dissolved dimethylsulfoxide (DMSOd) and DMS concentrations in the surface waters. The sea-to-air fluxes of DMS in the study area were estimated to be from 0.03 to 102.35 μmol m(-2) d(-1) with a mean of 16.73 μmol m(-2) d(-1) and the contribution of biogenic non-sea-salt SO4(2-) (nss-SO4(2-)) to the measured total nss-SO4(2-) in the atmospheric aerosol over the study area varied from 1.42% to 30.98%, with an average of 8.2%. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. Spatial attenuation of different sound field components in a water layer and shallow-water sediments

    NASA Astrophysics Data System (ADS)

    Belov, A. I.; Kuznetsov, G. N.

    2017-11-01

    The paper presents the results of an experimental study of spatial attenuation of low-frequency vector-scalar sound fields in shallow water. The experiments employed a towed pneumatic cannon and spatially separated four-component vector-scalar receiver modules. Narrowband analysis of received signals made it possible to estimate the attenuation coefficients of the first three modes in the frequency of range of 26-182 Hz and calculate the frequency dependences of the sound absorption coefficients in the upper part of bottom sediments. We analyze the experimental and calculated (using acoustic calibration of the waveguide) laws of the drop in sound pressure and orthogonal vector projections of the oscillation velocity. It is shown that the vertical projection of the oscillation velocity vector decreases significantly faster than the sound pressure field.

  17. Classification of bottom composition and bathymetry of shallow waters by passive remote sensing

    NASA Astrophysics Data System (ADS)

    Spitzer, D.; Dirks, R. W. J.

    The use of remote sensing data in the development of algorithms to remove the influence of the watercolumn on upwelling optical signals when mapping the bottom depth and composition in shallow waters. Calculations relating the reflectance spectra to the parameters of the watercolumn and the diverse bottom types are performed and measurements of the underwater reflection coefficient of sandy, mud, and vegetation-type seabottoms are taken. The two-flow radiative transfer model is used. Reflectances within the spectral bands of the Landsat MSS, the Landsat TM, SPOT HVR, and the TIROS-N series AVHRR were computed in order to develop appropriate algorithms suitable for the bottom depth and type mapping. Bottom depth and features appear to be observable down to 3-20 m depending on the water composition and bottom type.

  18. Numerical investigation of split flows by gravity currents into two-layered stratified water bodies

    NASA Astrophysics Data System (ADS)

    Cortés, A.; Wells, M. G.; Fringer, O. B.; Arthur, R. S.; Rueda, F. J.

    2015-07-01

    The behavior of a two-dimensional (2-D) gravity current impinging upon a density step in a two-layered stratified basin is analyzed using a high-resolution Reynolds-Averaged Navier-Stokes model. The gravity current splits at the density step, and the portion of the buoyancy flux becoming an interflow is largely controlled by the vertical distribution of velocity and density within the gravity current and the magnitude of the density step between the two ambient layers. This is in agreement with recent laboratory observations. The strongest changes in the ambient density profiles occur as a result of the impingement of supercritical currents with strong density contrasts, for which a large portion of the gravity current detaches from the bottom and becomes an interflow. We characterize the current partition process in the simulated experiments using the densimetric Froude number of the current (Fr) across the density step (upstream and downstream). When underflows are formed, more supercritical currents are observed downstream of the density step compared to upstream (Fru < Frd), and thus, stronger mixing of the current with the ambient water downstream. However, when split flows and interflows are formed, smaller Fr values are identified after the current crosses the density step (Fru > Frd), which indicates lower mixing between the current and ambient water after the impingement due to the significant stripping of interfacial material at the density step.

  19. The deep-sea as a final global sink of semivolatile persistent organic pollutants? Part I: PCBs in surface and deep-sea dwelling fish of the north and south Atlantic and the Monterey Bay Canyon (California).

    PubMed

    Froescheis, O; Looser, R; Cailliet, G M; Jarman, W M; Ballschmiter, K

    2000-03-01

    The understanding of the global environmental multiphase distribution of persistent organic pollutants (POPs) as a result of the physico-chemical properties of the respective compounds is well established. We have analysed the results of a vertical transport of POPs from upper water layers (0-200 m) to the deepwater region (> 800 m) in terms of the contamination of the biophase in both water layers. The contents of persistent organochlorine compounds like polychlorinated biphenyls (PCBs) in fish living in the upper water layers of the North Atlantic and the South Atlantic, and at the continental shelf of California (Marine Sanctuary Monterey Bay and its deep-sea Canyon) are compared to the levels in deep-sea or bottom dwelling fish within the same geographic area. The deep-sea biota show significantly higher burdens as compared to surface-living species of the same region. There are also indications for recycling processes of POPs--in this case the PCBs--in the biophase of the abyss as well. It can be concluded that the bio- and geo phase of the deep-sea may act similarly as the upper horizons of forest and grasslands on the continents as an ultimate global sink for POPs in the marine environment.

  20. An analysis of dynamical factors influencing 2013 giant jellyfish bloom near Qinhuangdao in the Bohai Sea, China∗

    NASA Astrophysics Data System (ADS)

    Wu, Lingjuan; Wang, Jia; Gao, Song; Zheng, Xiangrong; Huang, Rui

    2017-02-01

    The explosive growth of Nemopilema nomurai occurred near the coastal waters of Qinhuangdao in July 2013. However, it did not take place in 2012. In this paper, the dynamical factors of wind, ocean current and sea temperature on giant jellyfish bloom in 2013 is analyzed by a comprehensive investigation. The numerical experiments are based on a numerical trajectory model of the jellyfish particles, which are released into the waters from Feiyan Shoal to New Yellow River Mouth, where is speculated as the most likely remote source of Qinhuangdao jellyfish bloom. The results show that in surface layer the jellyfish drift is jointly driven by the surface wind and surface current. For example, in northeastern Bohai Bay, the giant jellyfish moved northwestward in surface layer with influence of the westward wind and current anomalies during the second half of May in 2013, then approached the south of Jingtang Port by early June, and accumulated near Qinhuangdao in early July. The 2012 scenario during the same period was quite different. The jellyfish particles influencing waters near Qinhuangdao decreased with depth and there was few (no) particles influencing Qinhuangdao in middle (bottom) layer because the anticyclonic residual circulation weakened with depth in Bohai Bay. Besides, in the potential source waters of jellyfish, sea temperature in 2012 was more suitable for jellyfish bloom than that in 2013 if there was adequate bait. Hence, the specified direction of wind and current pattern in the Bohai Sea in surface layer (especially in the northeastern Bohai Bay during the second half of May) was more important for jellyfish bloom near Qinhuangdao than the sea temperature in the potential source.

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